WorldWideScience

Sample records for stacking related structures

  1. NSF tandem stack support structure deflection characteristics

    International Nuclear Information System (INIS)

    Cook, J.

    1979-12-01

    Results are reported of load tests carried out on the glass legs of the insulating stack of the 30 MV tandem Van de Graaff accelerator now under construction at Daresbury Laboratory. The tests to investigate the vulnerability of the legs when subjected to tensile stresses were designed to; establish the angle of rotation of the pads from which the stresses in the glass legs may be calculated, proof-test the structure and at the same time reveal any asymmetry in pad rotations or deflections, and to confirm the validity of the computer design analysis. (UK)

  2. Precise stacking and bonding technology for RDDS structure

    International Nuclear Information System (INIS)

    Higo, T; Toge, N.; Suzuki, T.

    2000-01-01

    The X-band accelerating structures called RDDS1 (Rounded Dumped Detuned Structure) for the linear collider have been developed. The main body of RDDS1 was successfully fabricated in Japan (KEK, IHI). We established basic fabrication techniques through the development of prototype structures including RDDS1. The precise stacking and bonding technologies for RDDS structure are presented in this paper. (author)

  3. Manifold seal structure for fuel cell stack

    Science.gov (United States)

    Collins, William P.

    1988-01-01

    The seal between the sides of a fuel cell stack and the gas manifolds is improved by adding a mechanical interlock between the adhesive sealing strip and the abutting surface of the manifolds. The adhesive is a material which can flow to some extent when under compression, and the mechanical interlock is formed providing small openings in the portion of the manifold which abuts the adhesive strip. When the manifolds are pressed against the adhesive strips, the latter will flow into and through the manifold openings to form buttons or ribs which mechanically interlock with the manifolds. These buttons or ribs increase the bond between the manifolds and adhesive, which previously relied solely on the adhesive nature of the adhesive.

  4. 7. Data Structures: Lists, Queues, Stacks and Arrays

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 2; Issue 6. Algorithms - Data Structures: Lists, Queues, Stacks and Arrays. R K Shyamasundar ... Author Affiliations. R K Shyamasundar1. Computer Science Group, Tata Institute of Fundamental Research, Homi Bhabha Road, Mumbai 400 005, India ...

  5. 7. Data Structures: Lists, Queues, Stacks and Arrays

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 2; Issue 6. Algorithms - Data Structures: Lists, Queues, Stacks and Arrays. R K Shyamasundar. Series Article Volume 2 Issue 6 June 1997 pp 39-46. Fulltext. Click here to view fulltext PDF. Permanent link:

  6. Structure of a stacked anthraquinone–DNA complex

    Science.gov (United States)

    De Luchi, Daniela; Usón, Isabel; Wright, Glenford; Gouyette, Catherine; Subirana, Juan A.

    2010-01-01

    The crystal structure of the telomeric sequence d(UBrAGG) interacting with an anthraquinone derivative has been solved by MAD. In all previously studied complexes of intercalating drugs, the drug is usually sandwiched between two DNA base pairs. Instead, the present structure looks like a crystal of stacked anthraquinone molecules in which isolated base pairs are intercalated. Unusual base pairs are present in the structure, such as G·G and A·UBr reverse Watson–Crick base pairs. PMID:20823516

  7. Electronic structure of the rotation twin stacking fault in β-ZnS

    International Nuclear Information System (INIS)

    Northrup, J.E.; Cohen, M.L.

    1981-01-01

    The electronic structure of the rotation twin stacking fault in β-ZnS is calculated with the self-consistent pseudopotential method. The stacking fault creates a potential barrier of approx.0.07 eV and induces the localization of stacking-fault resonances near the top of the valence band. Stacking-fault states are also predicted to exist in the various gaps in the projected valence-band structure

  8. Anisotropic electrical conduction in relation to the stacking disorder in graphite

    International Nuclear Information System (INIS)

    Tsuzuku, T.

    1979-01-01

    The in-plane and c-axis conduction behaviours of Kish graphite and of hot-worked pyrolytic graphite are discussed in relation to their structural perfection, special interest being focused onto the stacking fault disorder which appears in the form of extended basal dislocation ribbons. Analysis of the two-dimensional magneto-conductivity indicates that the carrier density of faulted specimens increases slowly with temperature (T) even below the degeneracy point of the carrier system, whereas the unfaulted ones do not. the c-axis resistivity (psub(c)) has been found to decrease with diminishing stacking disorder for a well-defined specimen group not containing such irregularities as microcracks. This verifies the applicability of the band model to the intrinsic psub(c) 's, in connection with the success of Ono's theory accounting for the wide-range scattering of past data. The discrepancy still remaining between the theoretical and experimental psub(c) vs T relationship, as well as the increase of the in-plane conduction carrier density with temperature, seems to be removed by assuming thermal liberation of the localized Tamm-state electrons from the stacking fault planes. (author)

  9. Fine-scale structure of the mid-mantle characterised by global stacks of PP precursors

    Science.gov (United States)

    Bentham, H. L. M.; Rost, S.; Thorne, M. S.

    2017-08-01

    Subduction zones are likely a major source of compositional heterogeneities in the mantle, which may preserve a record of the subduction history and mantle convection processes. The fine-scale structure associated with mantle heterogeneities can be studied using the scattered seismic wavefield that arrives as coda to or as energy preceding many body wave arrivals. In this study we analyse precursors to PP by creating stacks recorded at globally distributed stations. We create stacks aligned on the PP arrival in 5° distance bins (with range 70-120°) from 600 earthquakes recorded at 193 stations stacking a total of 7320 seismic records. As the energy trailing the direct P arrival, the P coda, interferes with the PP precursors, we suppress the P coda by subtracting a best fitting exponential curve to this energy. The resultant stacks show that PP precursors related to scattering from heterogeneities in the mantle are present for all distances. Lateral variations are explored by producing two regional stacks across the Atlantic and Pacific hemispheres, but we find only negligible differences in the precursory signature between these two regions. The similarity of these two regions suggests that well mixed subducted material can survive at upper and mid-mantle depth. To describe the scattered wavefield in the mantle, we compare the global stacks to synthetic seismograms generated using a Monte Carlo phonon scattering technique. We propose a best-fitting layered heterogeneity model, BRT2017, characterised by a three layer mantle with a background heterogeneity strength (ɛ = 0.8%) and a depth-interval of increased heterogeneity strength (ɛ = 1%) between 1000 km and 1800 km. The scalelength of heterogeneity is found to be 8 km throughout the mantle. Since mantle heterogeneity of 8 km scale may be linked to subducted oceanic crust, the detection of increased heterogeneity at mid-mantle depths could be associated with stalled slabs due to increases in viscosity

  10. Structure of human telomeric RNA (TERRA): stacking of two G-quadruplex blocks in K(+) solution.

    Science.gov (United States)

    Martadinata, Herry; Phan, Anh Tuân

    2013-04-02

    Telomeric repeat-containing RNAs (TERRA) are transcription products of the telomeres. Human TERRA sequences containing UUAGGG repeats can form parallel-stranded G-quadruplexes. The stacking interaction of such structures was shown to be important for ligand targeting and higher-order arrangement of G-quadruplexes in long TERRA sequences. Here we report on the first high-resolution structure of a stacked G-quadruplex formed by the 10-nucleotide human TERRA sequence r(GGGUUAGGGU) in potassium solution. This structure comprises two dimeric three-layer parallel-stranded G-quadruplex blocks, which stack on each other at their 5'-ends. The adenine in each UUA loop is nearly coplanar with the 5'-end G-tetrad forming an A·(G·G·G·G)·A hexad, thereby increasing the stacking contacts between the two blocks. Interestingly, this stacking and loop conformation is different from all structures previously reported for the free human TERRA but resembles the structure previously determined for a complex between a human TERRA sequence and an acridine ligand. This stacking conformation is a potential target for drugs that recognize or induce the stacking interface.

  11. Effect of Additional Structure on Effective Stack Height of Gas Dispersion in Atmosphere

    Directory of Open Access Journals (Sweden)

    Takenobu Michioka

    2016-03-01

    Full Text Available Wind-tunnel experiments were conducted to evaluate the effect of additional structure (building, sea wall and banking on the effective stack height, which is usually used in safety analyses of nuclear power facilities in Japan. The effective stack heights were estimated with and without the additional structure in addition to the reactor building while varying several conditions such as the source height, the height of additional structure and the distance between the source position and the additional structure. When the source height is equivalent to the reactor building height, the additional structure enhances both the vertical and horizontal gas dispersion widths and decreases the ground gas concentration, and it means that the additional structure does not decrease the effective stack height. When the source height is larger than the reactor height, the additional structures might affect the effective stack height. As the distance between the source and the additional structure decreases, or as the height of the additional structure increases, the structure has a larger effect on the effective stack height.

  12. Influence of supramolecular structures in crystals on parallel stacking interactions between pyridine molecules.

    Science.gov (United States)

    Janjić, Goran V; Ninković, Dragan B; Zarić, Snezana D

    2013-08-01

    Parallel stacking interactions between pyridines in crystal structures and the influence of hydrogen bonding and supramolecular structures in crystals on the geometries of interactions were studied by analyzing data from the Cambridge Structural Database (CSD). In the CSD 66 contacts of pyridines have a parallel orientation of molecules and most of these pyridines simultaneously form hydrogen bonds (44 contacts). The geometries of stacked pyridines observed in crystal structures were compared with the geometries obtained by calculations and explained by supramolecular structures in crystals. The results show that the mean perpendicular distance (R) between pyridine rings with (3.48 Å) and without hydrogen bonds (3.62 Å) is larger than that calculated, because of the influence of supramolecular structures in crystals. The pyridines with hydrogen bonds show a pronounced preference for offsets of 1.25-1.75 Å, close to the position of the calculated minimum (1.80 Å). However, stacking interactions of pyridines without hydrogen bonds do not adopt values at or close to that of the calculated offset. This is because stacking interactions of pyridines without hydrogen bonds are less strong, and they are more susceptible to the influence of supramolecular structures in crystals. These results show that hydrogen bonding and supramolecular structures have an important influence on the geometries of stacked pyridines in crystals.

  13. Electronic structure of transferred graphene/h-BN van der Waals heterostructures with nonzero stacking angles by nano-ARPES.

    Science.gov (United States)

    Wang, Eryin; Chen, Guorui; Wan, Guoliang; Lu, Xiaobo; Chen, Chaoyu; Avila, Jose; Fedorov, Alexei V; Zhang, Guangyu; Asensio, Maria C; Zhang, Yuanbo; Zhou, Shuyun

    2016-11-09

    In van der Waals heterostructures, the periodic potential from the Moiré superlattice can be used as a control knob to modulate the electronic structure of the constituent materials. Here we present a nanoscale angle-resolved photoemission spectroscopy (nano-ARPES) study of transferred graphene/h-BN heterostructures with two different stacking angles of 2.4° and 4.3° respectively. Our measurements reveal six replicas of graphene Dirac cones at the superlattice Brillouin zone (SBZ) centers. The size of the SBZ and its relative rotation angle to the graphene BZ are in good agreement with Moiré superlattice period extracted from atomic force microscopy (AFM) measurements. Comparison to the epitaxial graphene/h-BN with 0° stacking angles suggests that the interaction between graphene and h-BN decreases with increasing stacking angle.

  14. Structural and quantum chemical analysis of exciton coupling in homo- and heteroaggregate stacks of merocyanines

    Science.gov (United States)

    Bialas, David; Zitzler-Kunkel, André; Kirchner, Eva; Schmidt, David; Würthner, Frank

    2016-01-01

    Exciton coupling is of fundamental importance and determines functional properties of organic dyes in (opto-)electronic and photovoltaic devices. Here we show that strong exciton coupling is not limited to the situation of equal chromophores as often assumed. Quadruple dye stacks were obtained from two bis(merocyanine) dyes with same or different chromophores, respectively, which dimerize in less-polar solvents resulting in the respective homo- and heteroaggregates. The structures of the quadruple dye stacks were assigned by NMR techniques and unambiguously confirmed by single-crystal X-ray analysis. The heteroaggregate stack formed from the bis(merocyanine) bearing two different chromophores exhibits remarkably different ultraviolet/vis absorption bands compared with those of the homoaggregate of the bis(merocyanine) comprising two identical chromophores. Quantum chemical analysis based on an extension of Kasha's exciton theory appropriately describes the absorption properties of both types of stacks revealing strong exciton coupling also between different chromophores within the heteroaggregate. PMID:27680284

  15. Reliability prediction of large fuel cell stack based on structure stress analysis

    Science.gov (United States)

    Liu, L. F.; Liu, B.; Wu, C. W.

    2017-09-01

    The aim of this paper is to improve the reliability of Proton Electrolyte Membrane Fuel Cell (PEMFC) stack by designing the clamping force and the thickness difference between the membrane electrode assembly (MEA) and the gasket. The stack reliability is directly determined by the component reliability, which is affected by the material property and contact stress. The component contact stress is a random variable because it is usually affected by many uncertain factors in the production and clamping process. We have investigated the influences of parameter variation coefficient on the probability distribution of contact stress using the equivalent stiffness model and the first-order second moment method. The optimal contact stress to make the component stay in the highest level reliability is obtained by the stress-strength interference model. To obtain the optimal contact stress between the contact components, the optimal thickness of the component and the stack clamping force are optimally designed. Finally, a detailed description is given how to design the MEA and gasket dimensions to obtain the highest stack reliability. This work can provide a valuable guidance in the design of stack structure for a high reliability of fuel cell stack.

  16. Structure for common access and support of fuel cell stacks

    Science.gov (United States)

    Walsh, Michael M.

    2000-01-01

    A structure provides common support and access to multiple fuel cells externally mounted thereto. The structure has openings leading to passages defined therein for providing the access. Various other fuel cell power system components are connected at the openings, such as reactant and coolant sources.

  17. Analysis of stacking overlap in nucleic acid structures: algorithm and application.

    Science.gov (United States)

    Pingali, Pavan Kumar; Halder, Sukanya; Mukherjee, Debasish; Basu, Sankar; Banerjee, Rahul; Choudhury, Devapriya; Bhattacharyya, Dhananjay

    2014-08-01

    RNA contains different secondary structural motifs like pseudo-helices, hairpin loops, internal loops, etc. in addition to anti-parallel double helices and random coils. The secondary structures are mainly stabilized by base-pairing and stacking interactions between the planar aromatic bases. The hydrogen bonding strength and geometries of base pairs are characterized by six intra-base pair parameters. Similarly, stacking can be represented by six local doublet parameters. These dinucleotide step parameters can describe the quality of stacking between Watson-Crick base pairs very effectively. However, it is quite difficult to understand the stacking pattern for dinucleotides consisting of non canonical base pairs from these parameters. Stacking interaction is a manifestation of the interaction between two aromatic bases or base pairs and thus can be estimated best by the overlap area between the planar aromatic moieties. We have calculated base pair overlap between two consecutive base pairs as the buried van der Waals surface between them. In general, overlap values show normal distribution for the Watson-Crick base pairs in most double helices within a range from 45 to 50 Å(2) irrespective of base sequence. The dinucleotide steps with non-canonical base pairs also are seen to have high overlap value, although their twist and few other parameters are rather unusual. We have analyzed hairpin loops of different length, bulges within double helical structures and pseudo-continuous helices using our algorithm. The overlap area analyses indicate good stacking between few looped out bases especially in GNRA tetraloop, which was difficult to quantitatively characterise from analysis of the base pair or dinucleotide step parameters. This parameter is also seen to be capable to distinguish pseudo-continuous helices from kinked helix junctions.

  18. Improved performance of the microbial electrolysis desalination and chemical-production cell using the stack structure.

    Science.gov (United States)

    Chen, Shanshan; Liu, Guangli; Zhang, Renduo; Qin, Bangyu; Luo, Yong; Hou, Yanping

    2012-07-01

    The microbial electrolysis desalination and chemical-production cell (MEDCC) is a device to desalinate seawater, and produce acid and alkali. The objective of this study was to enhance the desalination and chemical-production performance of the MEDCC using two types of stack structure. Experiments were conducted with different membrane spacings, numbers of desalination chambers and applied voltages. Results showed that the stack construction in the MEDCC enhanced the desalination and chemical-production rates. The maximal desalination rate of 0.58 ± 0.02 mmol/h, which was 43% higher than that in the MEDCC, was achieved in the four-desalination-chamber MEDCC with the AEM-CEM stack structure and the membrane spacing of 1.5mm. The maximal acid- and alkali-production rates of 0.079 ± 0.006 and 0.13 ± 0.02 mmol/h, which were 46% and 8% higher than that in the MEDCC, respectively, were achieved in the two-desalination-chamber MEDCC with the BPM-AEM-CEM stack structure and the membrane spacing of 3mm. Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. Structural color in porous, superhydrophilic, and self-cleaning SiO2/TiO2 Bragg stacks.

    Science.gov (United States)

    Wu, Zhizhong; Lee, Daeyeon; Rubner, Michael F; Cohen, Robert E

    2007-08-01

    Thin-film Bragg stacks exhibiting structural color have been fabricated by a layer-by-layer (LbL) deposition process involving the sequential adsorption of nanoparticles and polymers. High- and low-refractive-index regions of quarter-wave stacks were generated by calcining LbL-assembled multilayers containing TiO(2) and SiO(2) nanoparticles, respectively. The physical attributes of each region were characterized by a recently developed ellipsometric method. The structural color characteristics of the resultant nanoporous Bragg stacks could be precisely tuned in the visible region by varying the number of stacks and the thickness of the high- and low-refractive-index stacks. These Bragg stacks also exhibited potentially useful superhydrophilicity and self-cleaning properties.

  20. Structure of kaolinite and influence of stacking faults: reconciling theory and experiment using inelastic neutron scattering analysis.

    Science.gov (United States)

    White, Claire E; Kearley, Gordon J; Provis, John L; Riley, Daniel P

    2013-05-21

    The structure of kaolinite at the atomic level, including the effect of stacking faults, is investigated using inelastic neutron scattering (INS) spectroscopy and density functional theory (DFT) calculations. The vibrational dynamics of the standard crystal structure of kaolinite, calculated using DFT (VASP) with normal mode analysis, gives good agreement with the experimental INS data except for distinct discrepancies, especially for the low frequency modes (200-400 cm(-1)). By generating several types of stacking faults (shifts in the a,b plane for one kaolinite layer relative to the adjacent layer), it is seen that these low frequency modes are affected, specifically through the emergence of longer hydrogen bonds (O-H⋯O) in one of the models corresponding to a stacking fault of -0.3151a - 0.3151b. The small residual disagreement between observed and calculated INS is assigned to quantum effects (which are not taken into account in the DFT calculations), in the form of translational tunneling of the proton in the hydrogen bonds, which lead to a softening of the low frequency modes. DFT-based molecular dynamics simulations show that anharmonicity does not play an important role in the structural dynamics of kaolinite.

  1. Electronic States of High-k Oxides in Gate Stack Structures

    Science.gov (United States)

    Zhu, Chiyu

    In this dissertation, in-situ X-ray and ultraviolet photoemission spectroscopy have been employed to study the interface chemistry and electronic structure of potential high-k gate stack materials. In these gate stack materials, HfO2 and La2O3 are selected as high-k dielectrics, VO2 and ZnO serve as potential channel layer materials. The gate stack structures have been prepared using a reactive electron beam system and a plasma enhanced atomic layer deposition system. Three interrelated issues represent the central themes of the research: 1) the interface band alignment, 2) candidate high-k materials, and 3) band bending, internal electric fields, and charge transfer. 1) The most highlighted issue is the band alignment of specific high-k structures. Band alignment relationships were deduced by analysis of XPS and UPS spectra for three different structures: a) HfO2/VO2/SiO2/Si, b) HfO 2-La2O3/ZnO/SiO2/Si, and c) HfO 2/VO2/ HfO2/SiO2/Si. The valence band offset of HfO2/VO2, ZnO/SiO2 and HfO 2/SiO2 are determined to be 3.4 +/- 0.1, 1.5 +/- 0.1, and 0.7 +/- 0.1 eV. The valence band offset between HfO2-La2O3 and ZnO was almost negligible. Two band alignment models, the electron affinity model and the charge neutrality level model, are discussed. The results show the charge neutrality model is preferred to describe these structures. 2) High-k candidate materials were studied through comparison of pure Hf oxide, pure La oxide, and alloyed Hf-La oxide films. An issue with the application of pure HfO2 is crystallization which may increase the leakage current in gate stack structures. An issue with the application of pure La2O3 is the presence of carbon contamination in the film. Our study shows that the alloyed Hf-La oxide films exhibit an amorphous structure along with reduced carbon contamination. 3) Band bending and internal electric fields in the gate stack structure were observed by XPS and UPS and indicate the charge transfer during the growth and process. The oxygen

  2. Control of interfacial properties of Pr-oxide/Ge gate stack structure by introduction of nitrogen

    Science.gov (United States)

    Kato, Kimihiko; Kondo, Hiroki; Sakashita, Mitsuo; Nakatsuka, Osamu; Zaima, Shigeaki

    2011-06-01

    We have demonstrated the control of interfacial properties of Pr-oxide/Ge gate stack structure by the introduction of nitrogen. From C- V characteristics of Al/Pr-oxide/Ge 3N 4/Ge MOS capacitors, the interface state density decreases without the change of the accumulation capacitance after annealing. The TEM and TED measurements reveal that the crystallization of Pr-oxide is enhanced with annealing and the columnar structure of cubic-Pr 2O 3 is formed after annealing. From the depth profiles measured using XPS with Ar sputtering for the Pr-oxide/Ge 3N 4/Ge stack structure, the increase in the Ge component is not observed in a Pr-oxide film and near the interface between a Pr-oxide film and a Ge substrate. In addition, the N component segregates near the interface region, amorphous Pr-oxynitride (PrON) is formed at the interface. As a result, Pr-oxide/PrON/Ge stacked structure without the Ge-oxynitride interlayer is formed.

  3. Three-dimensional stacked structured ASIC devices and methods of fabrication thereof

    Science.gov (United States)

    Shinde, Subhash L.; Teifel, John; Flores, Richard S.; Jarecki Jr., Robert L.; Bauer, Todd

    2015-11-19

    A 3D stacked sASIC is provided that includes a plurality of 2D reconfigurable structured structured ASIC (sASIC) levels interconnected through hard-wired arrays of 3D vias. The 2D sASIC levels may contain logic, memory, analog functions, and device input/output pad circuitry. During fabrication, these 2D sASIC levels are stacked on top of each other and fused together with 3D metal vias. Such 3D vias may be fabricated as through-silicon vias (TSVs). They may connect to the back-side of the 2D sASIC level, or they may be connected to top metal pads on the front-side of the 2D sASIC level.

  4. Non-standard base pairing and stacked structures in methyl xanthine clusters

    Czech Academy of Sciences Publication Activity Database

    Callahan, M. P.; Gengeliczki, Z.; Svadlenak, N.; Valdes, Haydee; Hobza, Pavel; de Vries, M. S.

    2008-01-01

    Roč. 10, č. 19 (2008), s. 2819-2826 ISSN 1463-9076 R&D Projects: GA MŠk LC512 Grant - others:NSF(US) CHE-0615401 Institutional research plan: CEZ:AV0Z40550506 Keywords : non-standard base pairing * stacked structures * in methyl xanthine Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 4.064, year: 2008

  5. Application of Post-stack migration to seismic data associated with fault structures

    OpenAIRE

    Koduru Anitha; Mohanty P. R

    2015-01-01

    In hydrocarbon exploration, wave-equation migration techniques play an important role in imaging the complex geological structures. Usually, post-stack migration scheme is applied to the seismic data to improve the resolution with restoration of dipping reflectors to their true position. As a result, the migrated time sections are interpretable in terms of subsurface features. As a numerical study, three fault models are considered for the present study. First of all, ...

  6. Application of Post-stack migration to seismic data associated with fault structures

    Science.gov (United States)

    Koduru, Anitha; Mohanty, P. R.

    2015-06-01

    In hydrocarbon exploration, wave-equation migration techniques play an important role in imaging the complex geological structures. Usually, post-stack migration scheme is applied to the seismic data to improve the resolution with restoration of dipping reflectors to their true position. As a result, the migrated time sections are interpretable in terms of subsurface features. As a numerical study, three fault models are considered for the present study. First of all, synthetic time sections are generated corresponding to three models. Later, post stack migration schemes such as Gazdag(PS), Phase-shift with turning rays and reverse time migration (T-K) domain techniques are applied in order to judge the imaging accuracy, preservation of true amplitude and computational speed. All the three post stack time migrated sections delineate the structure with their throw.However, the reverse time migrations (T-K) clearly delineate the reflectors in restoring the throw properly with minimum computational time. In order to test the validity the numerical results, similar exercise has been undertaken using field seismic data of KG basin, India. The results indicates that the field migrated sections are imaged. But, the reverse time migration (T-K ) provides the best subsurface image with restoration of reflectors and collapse of diffracted events with least computational time. Gazdag (PS) and Phase-Shift with turning migrated section shows the reduction of amplitude whereas, the reverse time migration preserved the amplitude fully.

  7. The impact of sedimentary anisotropy on solute mixing in stacked scour-pool structures

    Science.gov (United States)

    Bennett, Jeremy P.; Haslauer, Claus P.; Cirpka, Olaf A.

    2017-04-01

    The spatial variability of hydraulic conductivity is known to have a strong impact on solute spreading and mixing. In most investigations, its local anisotropy has been neglected. Recent studies have shown that spatially varying orientation in sedimentary anisotropy can lead to twisting flow enhancing transverse mixing, but most of these studies used geologically implausible geometries. We use an object-based approach to generate stacked scour-pool structures with either isotropic or anisotropic filling which are typically reported in glacial outwash deposits. We analyze how spatially variable isotropic conductivity and variation of internal anisotropy in these features impacts transverse plume deformation and both longitudinal and transverse spreading and mixing. In five test cases, either the scalar values of conductivity or the spatial orientation of its anisotropy is varied between the scour-pool structures. Based on 100 random configurations, we compare the variability of velocity components, stretching and folding metrics, advective travel-time distributions, one and two-particle statistics in advective-dispersive transport, and the flux-related dilution indices for steady state advective-dispersive transport among the five test cases. Variation in the orientation of internal anisotropy causes strong variability in the lateral velocity components, which leads to deformation in transverse directions and enhances transverse mixing, whereas it hardly affects the variability of the longitudinal velocity component and thus longitudinal spreading and mixing. The latter is controlled by the spatial variability in the scalar values of hydraulic conductivity. Our results demonstrate that sedimentary anisotropy is important for transverse mixing, whereas it may be neglected when considering longitudinal spreading and mixing.

  8. Porous Structures in Stacked, Crumpled and Pillared Graphene-Based 3D Materials.

    Science.gov (United States)

    Guo, Fei; Creighton, Megan; Chen, Yantao; Hurt, Robert; Külaots, Indrek

    2014-01-01

    Graphene, an atomically thin material with the theoretical surface area of 2600 m 2 g -1 , has great potential in the fields of catalysis, separation, and gas storage if properly assembled into functional 3D materials at large scale. In ideal non-interacting ensembles of non-porous multilayer graphene plates, the surface area can be adequately estimated using the simple geometric law ~ 2600 m 2 g -1 /N, where N is the number of graphene sheets per plate. Some processing operations, however, lead to secondary plate-plate stacking, folding, crumpling or pillaring, which give rise to more complex structures. Here we show that bulk samples of multilayer graphene plates stack in an irregular fashion that preserves the 2600/N surface area and creates regular slot-like pores with sizes that are multiples of the unit plate thickness. In contrast, graphene oxide deposits into films with massive area loss (2600 to 40 m 2 g -1 ) due to nearly perfect alignment and stacking during the drying process. Pillaring graphene oxide sheets by co-deposition of colloidal-phase particle-based spacers has the potential to partially restore the large monolayer surface. Surface areas as high as 1000 m 2 g -1 are demonstrated here through colloidal-phase deposition of graphene oxide with water-dispersible aryl-sulfonated ultrafine carbon black as a pillaring agent.

  9. Lightweight Stacks of Direct Methanol Fuel Cells

    Science.gov (United States)

    Narayanan, Sekharipuram; Valdez, Thomas

    2004-01-01

    An improved design concept for direct methanol fuel cells makes it possible to construct fuel-cell stacks that can weigh as little as one-third as much as do conventional bipolar fuel-cell stacks of equal power. The structural-support components of the improved cells and stacks can be made of relatively inexpensive plastics. Moreover, in comparison with conventional bipolar fuel-cell stacks, the improved fuel-cell stacks can be assembled, disassembled, and diagnosed for malfunctions more easily. These improvements are expected to bring portable direct methanol fuel cells and stacks closer to commercialization. In a conventional bipolar fuel-cell stack, the cells are interspersed with bipolar plates (also called biplates), which are structural components that serve to interconnect the cells and distribute the reactants (methanol and air). The cells and biplates are sandwiched between metal end plates. Usually, the stack is held together under pressure by tie rods that clamp the end plates. The bipolar stack configuration offers the advantage of very low internal electrical resistance. However, when the power output of a stack is only a few watts, the very low internal resistance of a bipolar stack is not absolutely necessary for keeping the internal power loss acceptably low.

  10. Improved vertical MOSFET performance using an epitaxial channel and a stacked silicon-insulator structure

    International Nuclear Information System (INIS)

    Uchino, T; Gili, E; Ashburn, P; Tan, L; Buiu, O; Hall, S

    2012-01-01

    A vertical MOSFET (VMOST) incorporating an epitaxial channel and a drain junction in a stacked silicon-insulator structure is presented. In this device structure, an oxide layer near the drain junction edge (referred to as a junction stop) acts as a dopant diffusion barrier and consequently a shallow drain junction is formed to suppress short channel effects. To investigate the scalability of this device, a simulation study in the sub-100 nm regime calibrated to measured results on the fabricated devices is carried out. The use of an epitaxial channel delivers 50% higher drive current due to the higher mobility of the retrograde channel and the junction stop structure delivers improvements of threshold voltage roll-off and drain-induced barrier lowering compared with a conventional VMOST. (fast track communication)

  11. Stacking metal nano-patterns and fabrication of moth-eye structure

    Science.gov (United States)

    Taniguchi, Jun

    2018-01-01

    Nanoimprint lithography (NIL) can be used as a tool for three-dimensional nanoscale fabrication. In particular, complex metal pattern structures in polymer material are demanded as plasmonic effect devices and metamaterials. To fabricate of metallic color filter, we used silver ink and NIL techniques. Metallic color filter was composed of stacking of nanoscale silver disc patterns and polymer layers, thus, controlling of polymer layer thickness is necessary. To control of thickness of polymer layer, we used spin-coating of UV-curable polymer and NIL. As a result, ten stacking layers with 1000 nm layer thickness was obtained and red color was observed. Ultraviolet nanoimprint lithography (UV-NIL) is the most effective technique for mass fabrication of antireflection structure (ARS) films. For the use of ARS films in mobile phones and tablet PCs, which are touch-screen devices, it is important to protect the films from fingerprints and dust. In addition, as the nanoscale ARS that is touched by the hand is fragile, it is very important to obtain a high abrasion resistance. To solve these problems, a UV-curable epoxy resin has been developed that exhibits antifouling properties and high hardness. The high abrasion resistance ARS films are shown to withstand a load of 250 g/cm2 in the steel wool scratch test, and the reflectance is less than 0.4%.

  12. The stack: a new bacterial structure analyzed in the Antarctic bacterium Pseudomonas deceptionensis M1(T by transmission electron microscopy and tomography.

    Directory of Open Access Journals (Sweden)

    Lidia Delgado

    Full Text Available In recent years, improvements in transmission electron microscopy (TEM techniques and the use of tomography have provided a more accurate view of the complexity of the ultrastructure of prokaryotic cells. Cryoimmobilization of specimens by rapid cooling followed by freeze substitution (FS and sectioning, freeze fracture (FF and observation of replica, or cryoelectron microscopy of vitreous sections (CEMOVIS now allow visualization of biological samples close to their native state, enabling us to refine our knowledge of already known bacterial structures and to discover new ones. Application of these techniques to the new Antarctic cold-adapted bacterium Pseudomonasdeceptionensis M1(T has demonstrated the existence of a previously undescribed cytoplasmic structure that does not correspond to known bacterial inclusion bodies or membranous formations. This structure, which we term a "stack", was mainly visualized in slow growing cultures of P. deceptionensis M1(T and can be described as a set of stacked membranous discs usually arranged perpendicularly to the cell membrane, but not continuous with it, and found in variable number in different locations within the cell. Regardless of their position, stacks were mostly observed very close to DNA fibers. Stacks are not exclusive to P. deceptionensis M1(T and were also visualized in slow-growing cultures of other bacteria. This new structure deserves further study using cryoelectron tomography to refine its configuration and to establish whether its function could be related to chromosome dynamics.

  13. Optical and structural characterization of self-organized stacked GaN/AlN quantum dots

    International Nuclear Information System (INIS)

    Salviati, G; Rossi, F; Armani, N; Grillo, V; Martinez, O; Vinattieri, A; Damilano, B; Matsuse, A; Grandjean, N

    2004-01-01

    Self-organized GaN/AlN stacked quantum dots (QDs) have been studied by means of cathodoluminescence (CL), near field scanning optical microscopy (NSOM), photoluminescence, μ-Raman, and transmission electron microscopy. Assignment of the optical emissions was made on the basis of the structural parameters, power-dependent optical studies and depth-resolved CL. Power-dependent studies allowed us to distinguish between quantum confined and buffer emissions. On increasing the power injection conditions, a QD-size-dependent blue shift due to the screening of the internal electric fields was found together with a trend to saturation observed in the high injection limit. The possible evidence of excited states has also been shown by power-dependent photoluminescence and CL. Different blue shifts in specimens with different numbers of stacked layers suggested possible different residual strain values as confirmed by μ-Raman studies. Depth-resolved CL investigations performed at constant power injection per unit volume allowed us to distinguish between QD layers with different nominal GaN coverages and a linear dependence of peak energy versus GaN monolayer number has also been found. Adding 1 ML of GaN resulted in an average shift of about 150 meV. The existence of QDs with different size distributions along the growth axis was also found. The observations were confirmed by NSOM spectroscopy

  14. Stacking faults on (001) in transition-metal disilicides with the C11b structure

    International Nuclear Information System (INIS)

    Ito, K.; Nakamoto, T.; Inui, H.; Yamaguchi, M.

    1997-01-01

    Stacking faults on (001) in MoSi 2 and WSi 2 with the C11 b structure have been characterized by transmission electron microscopy (TEM), using their single crystals grown by the floating-zone method. Although WSi 2 contains a high density of stacking faults, only several faults are observed in MoSi 2 . For both crystals, (001) faults are characterized to be of the Frank-type in which two successive (001) Si layers are removed from the lattice, giving rise to a displacement vector parallel to [001]. When the displacement vector of faults is expressed in the form of R = 1/n[001], however, their n values are slightly deviated from the exact value of 3, because of dilatation of the lattice in the direction perpendicular to the fault, which is caused by the repulsive interaction between Mo (W) layers above and below the fault. Matching of experimental high-resolution TEM images with calculated ones indicates n values to be 3.12 ± 0.10 and 3.34 ± 0.10 for MoSi 2 and WSi 2 , respectively

  15. Stacking of aligned cell sheets for layer-by-layer control of complex tissue structure.

    Science.gov (United States)

    Williams, Corin; Xie, Angela W; Yamato, Masayuki; Okano, Teruo; Wong, Joyce Y

    2011-08-01

    Children suffering from congenital heart defects (CHD) often require vascular reconstruction. Pediatric patients would greatly benefit from a cell-based tissue engineered vascular patch (TEVP) that has potential for growth. As artery structure and function are intimately linked, mimicking native tissue organization is an important design consideration. In this study, we cultured human mesenchymal stem cell on patterned thermo-responsive substrates. Cell alignment improved over time up to 2 wk in culture when sheets were ready for harvest. We then used cell sheets as "functional units" to build complex tissue structures that mimic native vascular smooth muscle cell organization in the medial layer of the artery. Cell sheets could be stacked using a gelatin stamp such that individual sheets in the construct were well aligned with each other (mimic of circumferential orientation) or at angles with respect to each other (mimic of herringbone structure). Controlling tissue organization layer-by-layer will be a powerful approach to building tissues with well defined and complex structure. Copyright © 2011 Elsevier Ltd. All rights reserved.

  16. Novel variable structure control for the temperature of PEM fuel cell stack based on the dynamic thermal affine model

    International Nuclear Information System (INIS)

    Li Xi; Deng Zhonghua; Wei Dong; Xu Chunshan; Cao Guangyi

    2011-01-01

    Highlights: → The affine state space control-oriented model is designed and realized for the variant structure control (VSC) strategy. → The VSC with rapid-smooth reaching law and rapid-convergent sliding mode is presented for the PEMFC stack temperature. → Numerical results show that the method can control the operating temperature to reach the target value satisfactorily. - Abstract: Dynamic thermal management of proton exchange membrane fuel cell stack (PEMFC) is a very important aspect, which plays an important role on electro-reaction. Its variation also has a significant influence on the performance and lifespan of PEMFC stack. The temperature of stack should be controlled efficiently, which has great impacts on the performance of PEMFC due to the thermal variation. Based on the control-oriented dynamic thermal affine model identified by optimization algorithm, a novel variable structures control (VSC) with rapid-smooth reaching law (RSRL) and rapid-convergent sliding mode (FCSM) is presented for the temperature control system of PEMFC stack. Numerical test results show that the method can control the operating temperature to reach the target value satisfactorily, which proves the effectiveness and robustness of the algorithm.

  17. Structure of fault stackings of molecular layers X-M-X in CdI2 polytypic crystals

    International Nuclear Information System (INIS)

    Palosz, B.; Przedmojski, J.

    1984-01-01

    The arrangements of molecular layers I-Cd-I, which may be regarded as 'faulted' for CdI 2 polytypic crystals, are analyzed. Tentative classification of faults into those which are intermediate structure between the basic polytypes 2H and 4H and faults occurring between different blocks of pure structure 4 H is proposed. The connection between some growth parameters and the structure of faults in CdI 2 crystals grown from solutions is discussed. It is shown that the geometrical classification of stacking faults used for layered inorganic crystals is not appropriate for the description of the faults existing in polytypic crystals of MX 2 type. The effect of weak external electric and magnetic fields on the polytypic structure of CdI 2 is analyzed. The experiments performed for several hundred of polytypes of CdI 2 showed that the external fields may, in some conditions, affect the organization of the polytypic structure of crystals very strongly. In particular, it was found that the external fields may change the period of polytype cells and that the relative number of hexagonal and rhombohedral polytypes differ very strongly for crystals grown in the absence and in the presence of external electric and magnetic fields. (author)

  18. Transport in vertically stacked hetero-structures from 2D materials

    Science.gov (United States)

    Chen, Fan; Ilatikhameneh, Hesameddin; Tan, Yaohua; Valencia, Daniel; Klimeck, Gerhard; Rahman, Rajib

    2017-06-01

    In this work, the transport of tunnel field-effect transistor (TFET) based on vertically stacked hereto-structures from 2D transition metal dichalcogenide (TMD) materials is investigated by atomistic quantum transport simulations. WTe2-MoS2 combination was chosen due to the formation of a broken gap hetero-junction which is desirable for TFETs. There are two assumptions behind the MoS2-WTe2 hetero-junction tight binding (TB) model: 1) lattice registry. 2) The S - Te parameters being the average of the S - S and Te - Te parameters of bilayer MoS2 and WTe2. The computed TB bandstructure of the hetero-junction agrees well with the bandstructure obtained from density functional theory (DFT) in the energy range of interest for transport. NEGF (Non-Equilibrium Green’s Function) equations within the tight binding description is then utilized for device transfer characteristic calculation. Results show 1) energy filtering is the switching mechanism; 2) the length of the extension region is critical for device to turn off; 3) MoS2-WTe2 interlayer TFET can achieve a large on-current of 1000µA/µm with VDD = 0.3V, which suggests interlayer TFET can solve the low ON current problem of TFETs and can be a promising candidate for low power applications.

  19. Birnessite-type MnO2 nanosheets with layered structures under high pressure: elimination of crystalline stacking faults and oriented laminar assembly.

    Science.gov (United States)

    Sun, Yugang; Wang, Lin; Liu, Yuzi; Ren, Yang

    2015-01-21

    Squeezing out crystalline stacking faults: Birnessite-type δ-phase MnO2 microflowers containing interconnected ultrathin nanosheets are synthesized through a microwave-assisted hydrothermal process and exhibit a layered crystalline structure with significant stacking faults. Compressing these MnO2 nanosheets in a diamond anvil cell with high pressure up to tens of GPa effectively eliminates the crystalline stacking faults. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Effects of base mat flexibility and structure-soil-structure interaction on the seismic responses of a nuclear stack building

    International Nuclear Information System (INIS)

    Kabir, A.F.; Malik, L.E.; Maryak, M.E.

    1991-01-01

    A nuclear exhaust stack building was analyzed considering flexibility of the base mat and through-soil coupling with a nearby massive reactor building. The analysis indicated that the base mat flexibility and the proximity of the reactor building significantly affect the seismic responses of the stack building

  1. Crustal Structure and Subsidence of the Williston Basin: Evidence from Receiver Function Stacking and Gravity Modeling

    Science.gov (United States)

    Song, J.; Liu, K. H.; Yu, Y.; Mickus, K. L.; Gao, S. S.

    2017-12-01

    The Williston Basin of the northcentral United States and southern Canada is a typical intracratonic sag basin, with nearly continuous subsidence from the Cambrian to the Jurassic. A number of contrasting models on the subsidence mechanism of this approximately circular basin have been proposed. While in principle 3D variations of crustal thickness, layering, and Poisson's ratio can provide essential constraints on the models, thick layers of Phanerozoic sediment with up to 4.5 km thickness prevented reliable determinations of those crustal properties using active or passive source seismic techniques. Specifically, the strong reverberations of teleseismic P-to-S converted waves (a.k.a. receiver functions or RFs) from the Moho and intracrustal interfaces in the loose sedimentary layer can severely contaminate the RFs. Here we use RFs recorded by about 200 USArray and other stations in the Williston Basin and adjacent areas to obtain spatial distributions of the crustal properties. We have found that virtually all of the RFs recorded by stations in the Basin contain strong reverberations, which are effectively removed using a recently developed deconvolution-based filter (Yu et al., 2015, DOI: 10.1002/2014JB011610). A "double Moho" structure is clearly imaged beneath the Basin. The top interface has a depth of about 40 km beneath the Basin, and shallows gradually toward the east from the depocenter. It joins with the Moho beneath the western margin of the Superior Craton, where the crust is about 30 km thick. The bottom interface has a depth of 55 km beneath the Wyoming Craton, and deepens to about 70 km beneath the depocenter. Based on preliminary results of H-k stacking and gravity modeling, we interpret the layer between the two interfaces as a high density, probably eclogized layer. Continuous eclogitization from the Cambrian to the Jurassic resulted in the previously observed rates of subsidence being nearly linear rather than exponential.

  2. Fatigue Analysis of Proton Exchange Membrane Fuel Cell Stacks Based on Structural Stress Distribution

    Science.gov (United States)

    Wu, C. W.; Liu, B.; Wei, M. Y.; Liu, L. F.

    2017-05-01

    Proton exchange membrane fuel cell (PEMFC) stack usually undergoes various vibrations during packing, transportation and serving time, in particular for those used in the automobiles and portable equipment. Based on the Miner fatigue damage theory, the fatigue lives of the fuel cell components are first assessed. Then the component fatigue life contours of the stack are obtained under four working conditions, i.e. the three single-axial (in X-, Y- and Z-axis separately) and multi-axial random vibrations. Accordingly, the component damage under various vibrations is evaluated. The stress distribution on the gasket and PEM will greatly affect their fatigue lives. Finally, we compare the fatigue lives of 4-bolt- and 6-bolt-clamping stacks under the same total clamping force, and find that increasing the bolt number could improve the bolt fatigue lives.

  3. About zone structure of a stack of a cholesteric liquid crystal and isotropic medium layers

    International Nuclear Information System (INIS)

    Gevorgyan, A H; Harutyunyan, E M; Matinyan, G K; Harutyunyan, M Z

    2014-01-01

    The optical properties of a stack of metamaterial-based cholesteric liquid crystal (CLC) layers and isotropic medium layers are investigated. CLCs with two types of chiral nihility are defined. The peculiarities of the reflection spectra of this system are investigated and it is shown that the reflection spectra of the stacks of CLC layers of these two types differ from each other. The influence of: the CLC sublayer thicknesses; incidence angle; local dielectric (magnetic) anisotropy of the CLC layers; refraction indices and thicknesses of the isotropic media layers on the reflection spectra and other optical characteristics of the system is investigated.

  4. Miniaturized polymer electrolyte fuel cell (PEFC) stack using micro structured bipolar plate

    Energy Technology Data Exchange (ETDEWEB)

    Veziridis, Z.; Scherer, G.G.; Marmy, Ch.; Glaus, F. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    In Polymer Electrolyte Fuel Cell (PEFC) technology the reducing of volume and mass of the fuel cell stack and the improvement of catalyst utilization are of great interest. These parameters affect applicability and system cost. In this work we present an alternative way for reducing the stack volume by combining gas distribution and catalytic active area in one plate. Micro machined glassy carbon electrodes serve as support material for the platinum catalyst, as well as gas distributor at the same time. A comparison of these electrodes with conventional platinum-black gas diffusion electrodes under fuel cell conditions shows that the new system is a promising electrode type for enhanced power density and catalyst utilization. (author) 3 figs., 5 refs.

  5. Engineered Gd-Co based multilayer stack to enhanced magneto-caloric effect and relative cooling power

    Science.gov (United States)

    Tadout, M.; Lambert, C.-H.; El Hadri, M. S.; Mounkachi, O.; Benyoussef, A.; Hamedoun, M.; Benaissa, M.; Mangin, S.

    2018-02-01

    Magnetic refrigeration based on the magneto-caloric effect is one of the best alternatives to compete with vapor-compression technology. The viability of a magnetic refrigeration system for magnetic cooling can be tested by exploiting the materials in various forms, ranging from bulk to nanostructured materials. In order to achieve a wide refrigerating temperature range in magnetic refrigeration, we study in this paper a 100 nm-thick Gd-Co alloys-based multilayer stack. The stack is made of four individual Gd-Co alloy layers with different values of concentration and Curie temperature (TC). A magnetic entropy change associated with the second-order magnetic phase transition was determined from the magnetic isotherms. Moreover, the relative cooling power (RCP) of the studied Gd-Co-based multilayer is enhanced compared to the one of bulk Gd, and reaches a value of 200 J/kg. Such an enhancement of the RCP is not due to an enhanced maximum variation of entropy, but this is due to a much broader magnetic entropy peak. This study demonstrates the potential of nanostructured Gd-Co multilayer stack for magnetic cooling applications.

  6. Imaging the Structure of Grains, Grain Boundaries, and Stacking Sequences in Single and Multi-Layer Graphene

    Science.gov (United States)

    Muller, David

    2012-02-01

    Graphene can be produced by chemical vapor deposition (CVD) on copper substrates on up to meter scales [1, 2], making their polycrystallinity [3,4] almost unavoidable. By combining aberration-corrected scanning transmission electron microscopy and dark-field transmission electron microscopy, we image graphene grains and grain boundaries across six orders of magnitude. Atomic-resolution images of graphene grain boundaries reveal that different grains can stitch together via pentagon-heptagon pairs. We use diffraction-filtered electron imaging to map the shape and orientation of several hundred grains and boundaries over fields of view of a hundred microns. Single, double and multilayer graphene can be differentiated, and the stacking sequence and relative abundance of sequences can be directly imaged. These images reveal an intricate patchwork of grains with structural details depending strongly on growth conditions. The imaging techniques enabled studies of the structure, properties, and control of graphene grains and grain boundaries [5]. [4pt] [1] X. Li et al., Science 324, 1312 (2009).[0pt] [2] S. Bae et al., Nature Nanotechnol. 5, 574 (2010).[0pt] [3] J. M. Wofford, et al., Nano Lett., (2010).[0pt] [4] P. Y. Huang, et al., Nature 469, 389--392 (2011); arXiv:1009.4714, (2010)[0pt] [5] In collaboration with Pinshane Y. Huang, C. S. Ruiz-Vargas, A. M. van der Zande, A. W. Tsen, L. Brown, R. Hovden, F. Ghahari, W. S. Whitney, M.P. Levendorf, J. W. Kevek, S. Garg, J. S. Alden, C. J. Hustedt, Y. Zhu, N. Petrone, J. Hone, J. Park, P. L. McEuen

  7. Flat-Top and Stacking-Fault-Free GaAs-Related Nanopillars Grown on Si Substrates

    Directory of Open Access Journals (Sweden)

    Kouta Tateno

    2012-01-01

    Full Text Available The VLS (vapor-liquid-solid method is one of the promising techniques for growing vertical III-V compound semiconductor nanowires on Si for application to optoelectronic circuits. Heterostructures grown in the axial direction by the VLS method and in the radial direction by the general layer-by-layer growth method make it possible to fabricate complicated and functional three-dimensional structures in a bottom-up manner. We can grow some vertical heterostructure nanopillars with flat tops on Si(111 substrates, and we have obtained core-multishell Ga(InP/GaAs/GaP nanowires with flat tops and their air-gap structures by using selective wet etching. Simulations indicate that a high- factor of over 2000 can be achieved for this air-gap structure. From the GaAs growth experiments, we found that zincblende GaAs without any stacking faults can be grown after the GaP nanowire growth. Pillars containing a quantum dot and without stacking faults can be grown by using this method. We can also obtain flat-top pillars without removing the Au catalysts when using small Au particles.

  8. Algebraic stacks

    Indian Academy of Sciences (India)

    generally, any fiber product) is not uniquely defined: it is only defined up to unique isomorphism. ..... Fiber product. Given two morphisms f1 : F1 ! G, f2 : F2 ! G, we define a new stack. F1 آG F2 (with projections to F1 and F2) as follows. The objects are triples ًX1; X2; ق ..... In fact, any Artin stack F can be defined in this fashion.

  9. Relative stabilities and the spectral signatures of stacked and hydrogen-bonded dimers of serotonin

    Science.gov (United States)

    Dev, S.; Giri, K.; Majumder, M.; Sathyamurthy, N.

    2015-10-01

    The O-HṡṡṡN hydrogen-bonded dimer of serotonin is shown to be more stable than the stacked dimer in its ground electronic state, by using the Møller-Plesset second-order perturbation theory (MP2) and the 6-31g** basis set. The vertical excitation energy for the lowest π → π* transition for the monomer as well as the dimer is predicted by time-dependent density functional theory. The experimentally observed red shift of excitation wavelength on oligomerisation is explained in terms of the change in the HOMO-LUMO energy gap due to complex formation. The impact of dimer formation on the proton magnetic resonance spectrum of serotonin monomer is also examined.

  10. The ELSA - Flood - Stack: A reconstruction from the laminated sediments of Eifel Maar structures during the last 60 000 years

    Science.gov (United States)

    Brunck, Heiko; Sirocko, Frank; Albert, Johannes

    2016-04-01

    events from 60 000 years until present times and indicates variable periodicities of flood activity linked to predominant climatic and anthropogenic development. It turns out that low vegetation coverage related to Greenland Stadial phases or anthropogenic impact is the main cause for the development of flood layers in maar sediments, while precipitation plays only a secondary role. References Brunck, H., Albert, J., Sirocko, F., 2015 (in press). The ELSA - Flood - Stack: A reconstruction from the laminated sediments of Eifel Maar structures during the last 60 000 years. Global and Planetary Change, Elsevier. Sirocko, F., Knapp, H., Dreher, F., Förster, M., Albert, J., Brunck, H., Veres, D., Dietrich, S., Zech, M., Hambach, U., Röhner, M., Rudert, S., Schwibus, K., Adams, C., Sigl, P., 2015 (in press). The ELSA-Vegetation-Stack: Reconstruction of Landscape Evolution Zones (LEZ) from laminated Eifel maar sediments of the last 60 000 years. Global and Planetary Change, Elsevier.

  11. AB stacked few layer graphene growth by chemical vapor deposition on single crystal Rh(1 1 1) and electronic structure characterization

    Energy Technology Data Exchange (ETDEWEB)

    Kordatos, Apostolis [National Center for Scientific Research “Demokritos”, Athens, 15310 (Greece); Kelaidis, Nikolaos, E-mail: n.kelaidis@inn.demokritos.gr [National Center for Scientific Research “Demokritos”, Athens, 15310 (Greece); Giamini, Sigiava Aminalragia [National Center for Scientific Research “Demokritos”, Athens, 15310 (Greece); University of Athens, Department of Physics, Section of Solid State Physics, Athens, 15684 Greece (Greece); Marquez-Velasco, Jose [National Center for Scientific Research “Demokritos”, Athens, 15310 (Greece); National Technical University of Athens, Department of Physics, Athens, 15784 Greece (Greece); Xenogiannopoulou, Evangelia; Tsipas, Polychronis; Kordas, George; Dimoulas, Athanasios [National Center for Scientific Research “Demokritos”, Athens, 15310 (Greece)

    2016-04-30

    Highlights: • Growth of non-defective few layer graphene on Rh(1 1 1) substrates using an ambient- pressure CVD method. • Control of graphene stacking order via the cool-down rate. • Graphene is grown with a mainly AB-stacking geometry on single-crystalline Rhodium for a slow cool-down rate and non-AB for a very fast cool-down. • Good epitaxial orientation of the surface is presented through the RHEED data and confirmed with ARPES characterization for the lower cool-down rate, where graphene's ΓK direction a perfectly aligned with the ΓK direction of the Rh(1 1 1) single crystal. - Abstract: Graphene synthesis on single crystal Rh(1 1 1) catalytic substrates is performed by Chemical Vapor Deposition (CVD) at 1000 °C and atmospheric pressure. Raman analysis shows full substrate coverage with few layer graphene. It is found that the cool-down rate strongly affects the graphene stacking order. When lowered, the percentage of AB (Bernal) -stacked regions increases, leading to an almost full AB stacking order. When increased, the percentage of AB-stacked graphene regions decreases to a point where almost a full non AB-stacked graphene is grown. For a slow cool-down rate, graphene with AB stacking order and good epitaxial orientation with the substrate is achieved. This is indicated mainly by Raman characterization and confirmed by Reflection high-energy electron diffraction (RHEED) imaging. Additional Scanning Tunneling Microscopy (STM) topography data confirm that the grown graphene is mainly an AB-stacked structure. The electronic structure of the graphene/Rh(1 1 1) system is examined by Angle resolved Photo-Emission Spectroscopy (ARPES), where σ and π bands of graphene, are observed. Graphene's ΓK direction is aligned with the ΓK direction of the substrate, indicating no significant contribution from rotated domains.

  12. AB stacked few layer graphene growth by chemical vapor deposition on single crystal Rh(1 1 1) and electronic structure characterization

    International Nuclear Information System (INIS)

    Kordatos, Apostolis; Kelaidis, Nikolaos; Giamini, Sigiava Aminalragia; Marquez-Velasco, Jose; Xenogiannopoulou, Evangelia; Tsipas, Polychronis; Kordas, George; Dimoulas, Athanasios

    2016-01-01

    Highlights: • Growth of non-defective few layer graphene on Rh(1 1 1) substrates using an ambient- pressure CVD method. • Control of graphene stacking order via the cool-down rate. • Graphene is grown with a mainly AB-stacking geometry on single-crystalline Rhodium for a slow cool-down rate and non-AB for a very fast cool-down. • Good epitaxial orientation of the surface is presented through the RHEED data and confirmed with ARPES characterization for the lower cool-down rate, where graphene's ΓK direction a perfectly aligned with the ΓK direction of the Rh(1 1 1) single crystal. - Abstract: Graphene synthesis on single crystal Rh(1 1 1) catalytic substrates is performed by Chemical Vapor Deposition (CVD) at 1000 °C and atmospheric pressure. Raman analysis shows full substrate coverage with few layer graphene. It is found that the cool-down rate strongly affects the graphene stacking order. When lowered, the percentage of AB (Bernal) -stacked regions increases, leading to an almost full AB stacking order. When increased, the percentage of AB-stacked graphene regions decreases to a point where almost a full non AB-stacked graphene is grown. For a slow cool-down rate, graphene with AB stacking order and good epitaxial orientation with the substrate is achieved. This is indicated mainly by Raman characterization and confirmed by Reflection high-energy electron diffraction (RHEED) imaging. Additional Scanning Tunneling Microscopy (STM) topography data confirm that the grown graphene is mainly an AB-stacked structure. The electronic structure of the graphene/Rh(1 1 1) system is examined by Angle resolved Photo-Emission Spectroscopy (ARPES), where σ and π bands of graphene, are observed. Graphene's ΓK direction is aligned with the ΓK direction of the substrate, indicating no significant contribution from rotated domains.

  13. Stacking layered structure of polymer light emitting diodes prepared by evaporative spray deposition using ultradilute solution for improving carrier balance

    International Nuclear Information System (INIS)

    Aoki, Youichi; Shakutsui, Masato; Fujita, Katsuhiko

    2009-01-01

    Polymer light-emitting diodes (PLEDs) with staking layered structures are prepared by the evaporative spray deposition using ultradilute solution (ESDUS) method, which has enabled forming a polymer layer onto another polymer layer even if both polymers are soluble in a solvent used for the preparation. By this method, polymers having various HOMO and LUMO levels can be stacked as a hole transport layer, an emitting layer and an electron transport layer as commonly employed in small molecule-based organic light emitting diodes. Here we demonstrated that a PLED having a tri-layer structure using three kinds of polymers showed significant improvement in quantum efficiency compared with those having a single or bi-layer structure of corresponding polymers.

  14. Choice of Design Variables in the Stacking Sequence Optimization for Laminated Structures

    Science.gov (United States)

    Muc, A.

    2016-05-01

    A special type of new, continuous design variables is introduced in order to find optimum solutions for discrete fiber orientations. In the buckling analysis, as two or three different fiber orientations are considered, optimum solutions can be found in an analytical way. For a greater number of discrete fiber orientations, a special optimization algorithm based on the evolution strategy is used to solve the combinatorial optimization problems dealing with the optimum design of the laminate stacking sequence. The analysis is conducted with the example of simply supported rectangular multilayered composite plates subjected to buckling and the first-ply-failure constraints. The results demonstrate the effectiveness, simplicity, and advantages of the use of continuous design variables in the discrete optimization problem.

  15. Electrical characterization of 4H-SiC metal-oxide-semiconductor structure with Al2O3 stacking layers as dielectric

    Science.gov (United States)

    Chang, P. K.; Hwu, J. G.

    2018-02-01

    Interface defects and oxide bulk traps conventionally play important roles in the electrical performance of SiC MOS device. Introducing the Al2O3 stack grown by repeated anodization of Al films can notably lower the leakage current in comparison to the SiO2 structure, and enhance the minority carrier response at low frequency when the number of Al2O3 layers increase. In addition, the interface quality is not deteriorated by the stacking of Al2O3 layers because the stacked Al2O3 structure grown by anodization possesses good uniformity. In this work, the capacitance equivalent thickness (CET) of stacking Al2O3 will be up to 19.5 nm and the oxidation process can be carried out at room temperature. For the Al2O3 gate stack with CET 19.5 nm on n-SiC substrate, the leakage current at 2 V is 2.76 × 10-10 A/cm2, the interface trap density at the flatband voltage is 3.01 × 1011 eV-1 cm-2, and the effective breakdown field is 11.8 MV/cm. Frequency dispersion and breakdown characteristics may thus be improved as a result of the reduction in trap density. The Al2O3 stacking layers are capable of maintaining the leakage current as low as possible even after constant voltage stress test, which will further ameliorate reliability characteristics.

  16. Interface reactions at TiN/HfSiON gate stacks: Dependence on the electrode structure and deposition method

    Directory of Open Access Journals (Sweden)

    Shiniti Yoshida et al

    2007-01-01

    Full Text Available We systematically investigated intrinsic and extrinsic thermal reactions at TiN/HfSiON gate stacks. The formation of an ultrathin TiO2 interlayer was found to be an intrinsic reaction at the metal/insulator interface, but growth of SiO2 underlayers between HfSiON and Si substrates, which determines the electrical thickness of metal-oxide-semiconductor (MOS devices, depends on the structure and deposition method of the gate electrodes. Physical vapor deposition (PVD grown TiN electrodes covered with W overlayers exhibited excellent thermal stability at up to 1000 °C. Formation of ultrathin TiO2 interlayers reduced gate leakage current (Ig, and growth of the oxide underlayer was suppressed by less than a few angstroms even for 1000 °C annealing. In contrast, we found that halogen impurities within CVD-grown metal electrodes enhance interface SiO2 growth, resulting in deterioration of equivalent oxide thickness (EOT versus Ig characteristics of the gate stacks.

  17. Generating the Best Stacking Sequence Table for the Design of Blended Composite Structures

    NARCIS (Netherlands)

    Farzan Nasab, F.; Geijselaers, H. J.M.; Baran, I.; de Boer, A.

    2017-01-01

    In order to improve the ability of a large-scale light-weight composite structure to carry tensile or compressive loads, stiffeners are added to the structure. The stiffeners divide the structure into several smaller panels. For a composite structure to be manufacturable, it is necessary that plies

  18. Localized double-array stacking analysis of PcP: D″ and ULVZ structure beneath the Cocos plate, Mexico, central Pacific, and north Pacific

    Science.gov (United States)

    Hutko, Alexander R.; Lay, Thorne; Revenaugh, Justin

    2009-01-01

    A large, high quality P-wave data set comprising short-period and broadband signals sampling four separate regions in the lowermost mantle beneath the Cocos plate, Mexico, the central Pacific, and the north Pacific is analyzed using regional one-dimensional double-array stacking and modelling with reflectivity synthetics. A data-screening criterion retains only events with stable PcP energy in the final data stacks used for modelling and interpretation. This significantly improves the signal stacks relative to including unscreened observations, allows confident alignment on the PcP arrival and allows tight bounds to be placed on P-wave velocity structure above the core–mantle boundary (CMB). The PcP reflections under the Cocos plate are well modelled without any ultra-low velocity zone from 5 to 20°N. At latitudes from 15 to 20°N, we find evidence for two P-wave velocity discontinuities in the D″ region. The first is ∼182 km above the CMB with a δln Vp of +1.5%, near the same depth as a weaker discontinuity (<+0.5%) observed from 5 to 15°N in prior work. The other reflector is ∼454 km above the CMB, with a δln Vp of +0.4%; this appears to be a shallower continuation of the joint P- and S-wave discontinuity previously detected south of 15° N, which is presumed to be the perovskite to post-perovskite phase transition. The data stacks for paths bottoming below Mexico have PcP images that are well matched with the simple IASP91 structure, contradicting previous inferences of ULVZ presence in this region. These particular data are not very sensitive to any D″ discontinuities, and simply bound them to be <∼2%, if present. Data sampling the lowermost mantle beneath the central Pacific confirm the presence of a ∼15-km thick ultra-low velocity zone (ULVZ) just above the CMB, with δln Vp and δln Vs of around −3 to −4% and −4 to −8%, respectively. The ULVZ models predict previous S-wave data stacks well. The data for this region

  19. Tunnel magnetoresistance properties and annealing stability in perpendicular anisotropy MgO-based magnetic tunnel junctions with different stack structures

    Science.gov (United States)

    Mizunuma, K.; Ikeda, S.; Sato, H.; Yamanouchi, M.; Gan, H. D.; Miura, K.; Yamamoto, H.; Hayakawa, J.; Matsukura, F.; Ohno, H.

    2011-04-01

    We have investigated the effect of stack structures on tunnel magnetoresistance (TMR) properties in perpendicular anisotropy MgO-based magnetic tunnel junctions (p-MTJs) with CoFe/Pd multilayer and CoFeB insertion. By adopting Ta and Ru cap-layers, the TMR ratios of 113 and 106% are obtained at annealing temperature (Ta) of 325 °C, respectively. Particularly, the Ru cap-layer is effective in realizing a TMR ratio of 100% at Ta = 350 °C. By replacing (Co25Fe75)80B20 with (Co25Fe75)85B15, the TMR ratio increased quickly at low Ta, reaching a maximum of 120% at Ta = 300 °C.

  20. Stacking faults in Zr(Fe, Cr)2 Laves structured secondary phase particle in Zircaloy-4 alloy.

    Science.gov (United States)

    Liu, Chengze; Li, Geping; Yuan, Fusen; Han, Fuzhou; Zhang, Yingdong; Gu, Hengfei

    2018-02-01

    Stacking faults (SFs) in secondary phase particles (SPPs), which generally crystallize in the Laves phase in Zircaloy-4 (Zr-4) alloy, have been frequently observed by researchers. However, few investigations on the nano-scale structure of SFs have been carried out. In the present study, an SF containing C14 structured SPP, which located at grain boundaries (GBs) in the α-Zr matrix, was chosen to be investigated, for its particular substructure as well as location, aiming to reveal the nature of the SFs in the SPPs in Zr-4 alloy. It was indicated that the SFs in the C14 structured SPP actually existed in the local C36 structured Laves phase, for their similarities in crystallography. The C14 → C36 phase transformation, which was driven by synchroshearing among the (0001) basal planes, was the formation mechanism of the SFs in the SPPs. By analyzing the strained regions near the SPP, a model for understanding the driving force of the synchroshear was proposed: the interaction between SPP and GB resulted in the Zener pinning effect, leading to the shearing parallel to the (0001) basal planes of the C14 structured SPP, and the synchroshear was therefore activated.

  1. Tuning the magnetic properties of stripe domain structured CoFeB films using stack structure with spacer layer thickness dependent interlayer coupling

    Science.gov (United States)

    Das, Camelia; Alagarsamy, Perumal

    2018-02-01

    We report a novel approach for tuning the magnetic properties of stripe domain structured amorphous Co40Fe40B20 (CoFeB) films by using stack structured [CoFeB (100 nm)/Ta (z = 0-1.5 nm)]n= 0-4/CoFeB (100 nm) films with spacer layer thickness dependent interlayer coupling. All the as-deposited films deposited directly on thermally oxidized Si substrate at ambient temperature exhibit amorphous structure. Single-layer CoFeB (x = 100-300 nm) films display transcritical loops with high coercivity (HC > 4 kA/m) and large applied field required for magnetization saturation (HS > 40 kA/m) due to the formation of magnetic stripe domains induced by the stress quenched in during the preparation of the films at a high deposition rate to form amorphous structure. With increasing n, the number of CoFeB layers in stack structure increases providing an enhanced interlayer coupling and a better flux closure, which leads to a substantial drop in HC (∼1.8 kA/m) and changes the loop shape away from transcritical into soft magnetic type with reduced HS (∼10 kA/m) and increased remanence ratio (>75%). However, the improvement in magnetic properties strongly depends on the values of n and z. Temperature dependent M-H loops reveal a competition between interlayer coupling and interfacial strain, which provides unusual variation of HC(T), i.e., minimum in HC(T) vs T curve, depending on z and n. The observed results are explained on the basis of stress dependent stripe domains in single layer films and number of CoFeB layers and spacer layer thickness dependent interlayer coupling in stack structured films. It is revealed that the fabrication of stack of thick CoFeB films having stripe domains and separated by optimum z is an alternative approach to improve the magnetic properties of thick CoFeB films.

  2. Algebraic stacks

    Indian Academy of Sciences (India)

    truct the 'moduli stack', that captures all the information that we would like in a fine moduli space. ..... the fine moduli space), it has the property that for any family W of vector bundles (i.e. W is a vector bundle over B ...... the etale topology is finer: V is a 'small enough open subset' because the square root can be defined on it.

  3. Structural, chemical and electrical characterization of HfNO-HfTiO high-k dielectric stack

    Energy Technology Data Exchange (ETDEWEB)

    Mikhelashvili, Visorian; Eisenstein, Gadi [Electrical Engineering Dept., Technion (Israel); Paramasivam, Thangadurai; Kaplan, Wayne [Material Engineering Dept., Technion (Israel)

    2008-07-01

    We study the influence of annealing temperature on structural, compositional and electrical characteristics of a MOS structure with a high-k dielectric based on a 5 nm HfNO-HfTiO nanolaminate stack. A common feature of all samples independent on annealing temperature is the observation of two distinct 2-2.5 and 2.3-2.5 nm thick layers, respectively for transition (close to Si substrate) and top layers. The transition layer is amorphous, while in the top layer some crystalline inclusions embedded into the amorphous matrix are observed. EDS line-scans and XPS analysis showed that the transition layer is similar to metal-Si-O-N or metal-Si-O. The minimum values of quantum mechanical corrected effective oxide thickness close to 1.29 and 0.86 nm, respectively for structures with Au and Cr electrodes. A large reduction of leakage current density to 1.5 x 10{sup -8} and 2.9 x 10{sup -7} A/cm{sup 2}, respectively for Au and Cr gate electrodes at an electric fields of 2 MV/cm was observed with annealing temperature and breakdown electric field as high as 10-12 MV/cm, was measured independently of the electrodes type.

  4. Effect of test structure on electromigration characteristics in three-dimensional through silicon via stacked devices

    Science.gov (United States)

    Oba, Yoshiyuki; De Messemaeker, Joke; Tyrovouzi, Anna Maria; Miyamori, Yuichi; De Vos, Joeri; Wang, Teng; Beyer, Gerald; Beyne, Eric; De Wolf, Ingrid; Croes, Kristof

    2015-05-01

    Electromigration failure locations in three-dimensional (3D) interconnect structures with high-aspect-ratio through silicon vias, (TSVs, Φ5 × 50 µm2) connected to 40-µm-pitch CuSn solder joints have been identified using test structures which were designed to avoid failures in the back-end-of-line (BEOL). The resistance of the structures with the TSV and bump connections showed a continuous increase until failure. For the structures without a bump connection, where only TSV and re-distributed line (RDL) were the electrically connected, the resistance remained constant prior to the final failure. From cross-sectional analyses after the test, the failure locations were identified at the TSV bottom or at the bump bottom. The location of void formation was changed by applied current direction. The flux divergence generated by the barrier metal and the reservoir effect plays a crucial role in the void formation, and each failure mode is considered to have a different impact on the reliability performance.

  5. Geology Structure Identification Using Pre-Stack Depth Migration (PSDM Method of Tomography Result in North West Java Basin

    Directory of Open Access Journals (Sweden)

    Sudra Irawan

    2017-06-01

    Full Text Available North West Java Basin is a tertiary sedimentary basin which is located in the right of the western part of the Java island. North West Java Basin is geodynamic where currently located at the rear position of the path of the volcanic arc of Java that is the result of the India-Australia plate subduction to the south towards the Eurasian plate (Explanation of Sunda in the north. Geology structure observation is difficult to be conducted at Quaternary volcanicfield due to the classical problem at tropical region. In the study interpretation of fault structures can be done on a cross-section of Pre-Stack Depth Migration (PSDM used prayer namely Hardware Key Device, ie Central Processing Unit: RedHat Enterprise Linux AS 5.0, prayer Monitor 24-inch pieces, Server: SGI altix 450/SuSe Linux Enterprise Server 9.0, 32 GB, 32 X 2,6 GHz Procesor, network: Gigabyte 1 Gb/s, and the software used is paradigm, product: Seismic Processing and Imaging. The third fault obtained in this study in accordance with the geological information derived from previous research conducted by geologists. The second general direction is northwest-southeast direction represented by Baribis fault, fault-fault in the Valley Cimandiri and Gunung Walat. This direction is often known as the directions Meratus (Meratus Trend. Meratus directions interpreted as directions that follow the pattern of continuous arc Cretaceous age to Meratus in Kalimantan.

  6. On Stack Reconstruction Problem

    Directory of Open Access Journals (Sweden)

    V. D. Аkeliev

    2009-01-01

    Full Text Available The paper describes analytical investigations that study relation of fuel combustion regimes with concentration values of sulphur anhydride in flue gases and acid dew point. Coefficients of convective heat transfer at internal and external surfaces of stacks have been determined in the paper. The paper reveals the possibility to reconstruct stacks while using gas discharging channel made of composite material on the basis of glass-reinforced plastic which permits to reduce thermo-stressed actions on reinforced concrete and increase volume of released gases due to practically two-fold reduction of gas-dynamic pressure losses along the pipe length.

  7. Two-bit memory and quantized storage phenomenon in conventional MOS structures with double-stacked Pt-NCs in an HfAlO matrix.

    Science.gov (United States)

    Zhou, Guangdong; Wu, Bo; Liu, Xiaoqin; Li, Ping; Zhang, Shuangju; Sun, Bai; Zhou, Ankun

    2016-03-07

    A two-bit memory and quantized storage phenomenon are observed at room temperature for a device based on the traditional MOS structure with double-stacked Pt-nanocrystals (Pt-NCs). A 2.68 and 1.72 V flat band voltage shift (memory window) has been obtained when applying a ±7 V programming/erasing voltage to the structures with double-stacked Pt-NCs. The memory windows of 2.40 and 1.44 V can be retained after stress for 10(5) seconds, which correspond to 89.55% and 83.72% stored charges reserved. The quantized charge storage phenomenon characterized by current-voltage (J-V) hysteresis curves was detected at room temperature. The shrinkage of the memory window results from the decreasing tunneling probability, which strongly depends on the number of stacks. The traps, de-traps and quantum confinement effects of Pt-NCs may contribute to the improvement of dielectric characteristics and the two-bit memory behavior. The multi-bit memory and quantized storage behavior observed in the Pt-NCs stacks structure at room temperature might provide a feasible method for realizing the multi-bit storage in non-volatile flash memory devices.

  8. Supramolecular self-assembly of a coumarine-based acylthiourea synthon directed by π-stacking interactions: Crystal structure and Hirshfeld surface analysis

    Science.gov (United States)

    Saeed, Aamer; Ashraf, Saba; Flörke, Ulrich; Delgado Espinoza, Zuly Yuliana; Erben, Mauricio F.; Pérez, Hiram

    2016-05-01

    The structure of 1-(2-oxo-2H-chromene-3-carbonyl)-3-(2-methoxy-phenyl)thiourea (1) has been determined by single-crystal X-ray crystallography. This compound crystallizes in the monoclinic space group P21/c with a = 7.455 (2) Å, b = 12.744 (3) Å, c = 16.892 (4) Å, β = 90.203 (6)° and Z = 4. Both, the coumarin and the phenyl rings are nearly coplanar with the central 1-acylthiourea group, with the Cdbnd O and Cdbnd S bonds adopting an opposite orientation. Intramolecular N-H···O, C-H···O, and C-H···S hydrogen bonds are favored by the planar conformation. The molecules are packed through C-H···O, C-H···S and C-H···C hydrogen bonds, and two π···π interactions with offset arrangement. Inter-centroid distance of 3.490 (2) Å, slip angles of 18.5 and 20.9°, and vertical displacements of 1.10 and 1.24 Å are the stacking parameters corresponding to the stronger π···π interaction. Hirshfeld surface analysis was performed for visualizing, exploring and quantifying intermolecular interactions in the crystal lattice of compound 1, and compared with two closely related species. Shape index and Curvedness surfaces indicated π-stacking with different features in opposed sides of the molecule. Fingerprint plot showed C···C contacts with similar contributions to the crystal packing in comparison with those associated to hydrogen bonds. Enrichment ratios for H···H, O···H, S···H and C···C contacts revealed a high propensity to form in the crystal.

  9. Internal structure of the Supragetic Unit basement in the Serbian Carpathians and its significance for the late Early Cretaceous nappe-stacking

    Directory of Open Access Journals (Sweden)

    Krstekanić Nemanja

    2017-01-01

    Full Text Available Fault-related folds and hanging-wall structures reflect the geometry of the main thrusts in foldthrust belts. The results of the structural analysis of the Supragetic Unit metamorphic basement in eastern Serbia at map-, outcrop- and thin-section scale, and its importance for the late Early Cretaceous nappe-stacking are presented in this paper. The Supragetic Unit metamorphic basement includes various volcano-sedimentary rocks of Ordovician-Silurian protolith age. They were metamorphosed to the low greenschist facies with temperatures reaching 300-350°C and pressure reaching 0.3-0.5 GPa. The microscale studies show that quartz and albite demonstrate dominantly bulging and locally subgrain rotation recrystallisation, while chlorite, sericite and muscovite define spaced to continuous foliation recognised both at the outcrop- and the thin-section-scale. The statistical analysis based on the available map data shows low- to high-angle west-dipping foliation which is interpreted as an indicator of flat-ramp geometry of the Supragetic thrust, rather than east-vergent tight to isoclinal folding. At the thin-section scale ductile to semi-ductile C’-S structures indicate top to ESE thrusting. Subsequent kinking, recognised both at the outcrop- and the thin-section-scale, deform the older foliation. Those kink bands are the result of WNW-ESE to NW-SE compression and could represent the later stage of a continuous deformation event during which C’-S structures were formed. The youngest, brittle deformation is represented by subvertical joints with no offset recognised in thin-sections. The structural characteristics of the Supragetic Unit low-grade metamorphic basement in the studied areas, combined with tectonothermal events recognised elsewhere in Dacia mega-unit, could imply a possible initiation of the late Early Cretaceous nappe-stacking in the ductile to semi-ductile/semi-brittle domain. [Project of the Serbian Ministry of Education, Science and

  10. Effects of sub-domain structure on initial magnetization curve and domain size distribution of stacked media

    Energy Technology Data Exchange (ETDEWEB)

    Sato, S., E-mail: 231504@gmail.com; Kumagai, S.; Sugita, R.

    2015-03-01

    In this paper, in order to confirm the sub-domain structure in stacked media demagnetized with in-plane field, initial magnetization curves and magnetic domain size distribution were investigated. Both experimental and simulation results showed that an initial magnetization curve for the medium demagnetized with in-plane field (MDI) initially rose faster than that for the medium demagnetized with perpendicular field (MDP). It is inferred that this is because the MDI has a larger number of domain walls than the MDP due to the existence of the sub-domains, resulting in an increase in the probability of domain wall motion. Dispersion of domain size for the MDI was larger than that for the MDP. This is because sub-domains are formed not only inside the domain but also at the domain boundary region, and they change the position of the domain boundary to affect the domain size. - Highlights: • An initial magnetization curve for MDI initially rose faster than that for MDP. • Dispersion of domain size for the MDI was larger than that for the MDP. • Experimental and simulation results can be explained by existence of sub-domains.

  11. Photo-induced tunneling currents in MOS structures with various HfO2/SiO2 stacking dielectrics

    Directory of Open Access Journals (Sweden)

    Chin-Sheng Pang

    2014-04-01

    Full Text Available In this study, the current conduction mechanisms of structures with tandem high-k dielectric in illumination are discussed. Samples of Al/SiO2/Si (S, Al/HfO2/SiO2/Si (H, and Al/3HfO2/SiO2/Si (3H were examined. The significant observation of electron traps of sample H compares to sample S is found under the double bias capacitance-voltage (C-V measurements in illumination. Moreover, the photo absorption sensitivity of sample H is higher than S due to the formation of HfO2 dielectric layer, which leads to larger numbers of carriers crowded through the sweep of VG before the domination of tunneling current. Additionally, the HfO2 dielectric layer would block the electrons passing through oxide from valance band, which would result in less electron-hole (e−-h+ pairs recombination effect. Also, it was found that both of the samples S and H show perimeter dependency of positive bias currents due to strong fringing field effect in dark and illumination; while sample 3H shows area dependency of positive bias currents in strong illumination. The non-uniform tunneling current through thin dielectric and through HfO2 stacking layers are importance to MOS(p tunneling photo diodes.

  12. Absorption spectra of AA-stacked graphite

    International Nuclear Information System (INIS)

    Chiu, C W; Lee, S H; Chen, S C; Lin, M F; Shyu, F L

    2010-01-01

    AA-stacked graphite shows strong anisotropy in geometric structures and velocity matrix elements. However, the absorption spectra are isotropic for the polarization vector on the graphene plane. The spectra exhibit one prominent plateau at middle energy and one shoulder structure at lower energy. These structures directly reflect the unique geometric and band structures and provide sufficient information for experimental fitting of the intralayer and interlayer atomic interactions. On the other hand, monolayer graphene shows a sharp absorption peak but no shoulder structure; AA-stacked bilayer graphene has two absorption peaks at middle energy and abruptly vanishes at lower energy. Furthermore, the isotropic features are expected to exist in other graphene-related systems. The calculated results and the predicted atomic interactions could be verified by optical measurements.

  13. Reflector imaging by diffraction stacking with stacking velocity analysis; Jugo sokudo kaiseki wo tomonau sanran jugoho ni yoru hanshamen imaging

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J.; Rokugawa, S.; Kato, Y. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering; Yokota, T. [Japan National Oil Corp., Tokyo (Japan); Miyazaki, T. [Geological Survey of Japan, Tsukuba (Japan)

    1997-10-22

    Concerning seismic reflection survey for geometrical arrangement between pits, the scattering stacking method with stacking velocity analysis is compared with the CDP (common depth point horizontal stacking method). The advantages of the CDP supposedly include the following. Since it presumes an average velocity field, it can determine velocities having stacking effects. The method presumes stratification and, since such enables the division of huge quantities of observed data into smaller groups, more data can be calculated in a shorter time period. The method has disadvantages, attributable to its presuming an average velocity field, that accuracy in processing is lower when the velocity field contrast is higher, that accuracy in processing is low unless stratification is employed, and that velocities obtained from stacking velocity analysis are affected by dipped structures. Such shortcomings may be remedied in the scattering stacking method with stacking velocity analysis. Possibilities are that, as far as the horizontal reflection plane is concerned, it may yield stack records higher in S/N ratio than the CDP. Findings relative to dipped reflection planes will be introduced at the presentation. 6 refs., 12 figs.

  14. Density of oxidation-induced stacking faults in damaged silicon

    NARCIS (Netherlands)

    Kuper, F.G.; Hosson, J.Th.M. De; Verwey, J.F.

    1986-01-01

    A model for the relation between density and length of oxidation-induced stacking faults on damaged silicon surfaces is proposed, based on interactions of stacking faults with dislocations and neighboring stacking faults. The model agrees with experiments.

  15. Two-dimensional analytical model for hetero-junction double-gate tunnel field-effect transistor with a stacked gate-oxide structure

    Science.gov (United States)

    Xu, Hui Fang; Gui Guan, Bang

    2017-05-01

    A two-dimensional analytical model for hetero-junction double-gate tunnel FETs (DG TFETs) with a stacked gate-oxide structure is proposed in this paper. The effects of both the channel mobile charges and source/drain depletion regions on the channel potential profile are considered for the higher accuracy of the proposed model. Poisson’s equation is solved using the superposition principle and Fourier series solution to model the channel potential. The band-to-band tunneling generation rate is expressed as a function of the channel electric field derived from the channel potential and then integrated analytically to derive the drain current of the hetero-junction DG TFETs with a stacked gate-oxide structure using the shortest tunneling path. The effects of device parameters on the channel potential, drain current, and transconductance are investigated. Very good agreements are observed between the model calculations and the simulated results.

  16. Using post-breakdown conduction study in a MIS structure to better understand the resistive switching mechanism in an MIM stack

    International Nuclear Information System (INIS)

    Wu Xing; Pey, Kin-Leong; Raghavan, Nagarajan; Liu, Wen-Hu; Li Xiang; Bai Ping; Zhang Gang; Bosman, Michel

    2011-01-01

    We apply our understanding of the physics of failure in the post-breakdown regime of high-κ dielectric-based conventional logic transistors having a metal–insulator–semiconductor (MIS) structure to interpret the mechanism of resistive switching in resistive random-access memory (RRAM) technology metal–insulator–metal (MIM) stacks. Oxygen vacancies, gate metal migration and metal filament formation in the gate dielectric which constitute the chemistry of breakdown in the post-breakdown stage of logic gate stacks are attributed to be the mechanisms responsible for the SET process in RRAM technology. In this paper, we draw an analogy between the breakdown study in logic devices and filamentation physics in resistive non-volatile memory.

  17. CHSalign: A Web Server That Builds upon Junction-Explorer and RNAJAG for Pairwise Alignment of RNA Secondary Structures with Coaxial Helical Stacking.

    Directory of Open Access Journals (Sweden)

    Lei Hua

    Full Text Available RNA junctions are important structural elements of RNA molecules. They are formed when three or more helices come together in three-dimensional space. Recent studies have focused on the annotation and prediction of coaxial helical stacking (CHS motifs within junctions. Here we exploit such predictions to develop an efficient alignment tool to handle RNA secondary structures with CHS motifs. Specifically, we build upon our Junction-Explorer software for predicting coaxial stacking and RNAJAG for modelling junction topologies as tree graphs to incorporate constrained tree matching and dynamic programming algorithms into a new method, called CHSalign, for aligning the secondary structures of RNA molecules containing CHS motifs. Thus, CHSalign is intended to be an efficient alignment tool for RNAs containing similar junctions. Experimental results based on thousands of alignments demonstrate that CHSalign can align two RNA secondary structures containing CHS motifs more accurately than other RNA secondary structure alignment tools. CHSalign yields a high score when aligning two RNA secondary structures with similar CHS motifs or helical arrangement patterns, and a low score otherwise. This new method has been implemented in a web server, and the program is also made freely available, at http://bioinformatics.njit.edu/CHSalign/.

  18. Relative/Identical Semantic Structuralization

    Science.gov (United States)

    Stanley, George Edward

    1976-01-01

    Discusses the teaching of Afrikaans and English to speakers of Xhosa, with semantics as the point of focus. The purpose is to aid the teaching of Afrikaans and English by introducing componential analysis in order to compare the relative/identical aspects of semantic structuralization in these languages with those in Xhosa. (Author/RM)

  19. High-throughput computer method for 3D neuronal structure reconstruction from the image stack of the Drosophila brain and its applications.

    Directory of Open Access Journals (Sweden)

    Ping-Chang Lee

    Full Text Available Drosophila melanogaster is a well-studied model organism, especially in the field of neurophysiology and neural circuits. The brain of the Drosophila is small but complex, and the image of a single neuron in the brain can be acquired using confocal microscopy. Analyzing the Drosophila brain is an ideal start to understanding the neural structure. The most fundamental task in studying the neural network of Drosophila is to reconstruct neuronal structures from image stacks. Although the fruit fly brain is small, it contains approximately 100,000 neurons. It is impossible to trace all the neurons manually. This study presents a high-throughput algorithm for reconstructing the neuronal structures from 3D image stacks collected by a laser scanning confocal microscope. The proposed method reconstructs the neuronal structure by applying the shortest path graph algorithm. The vertices in the graph are certain points on the 2D skeletons of the neuron in the slices. These points are close to the 3D centerlines of the neuron branches. The accuracy of the algorithm was verified using the DIADEM data set. This method has been adopted as part of the protocol of the FlyCircuit Database, and was successfully applied to process more than 16,000 neurons. This study also shows that further analysis based on the reconstruction results can be performed to gather more information on the neural network.

  20. Consolidity: Stack-based systems change pathway theory elaborated

    Directory of Open Access Journals (Sweden)

    Hassen Taher Dorrah

    2014-06-01

    Full Text Available This paper presents an elaborated analysis for investigating the stack-based layering processes during the systems change pathway. The system change pathway is defined as the path resulting from the combinations of all successive changes induced on the system when subjected to varying environments, activities, events, or any excessive internal or external influences and happenings “on and above” its normal stands, situations or set-points during its course of life. The analysis is essentially based on the important overall system paradigm of “Time driven-event driven-parameters change”. Based on this paradigm, it is considered that any affected activity, event or varying environment is intelligently self-recorded inside the system through an incremental consolidity-scaled change in system parameters of the stack-based layering types. Various joint stack-based mathematical and graphical approaches supported by representable case studies are suggested for the identification, extraction, and processing of various stack-based systems changes layering of different classifications and categorizations. Moreover, some selected real life illustrative applications are provided to demonstrate the (infinite stack-based identification and recognition of the change pathway process in the areas of geology, archeology, life sciences, ecology, environmental science, engineering, materials, medicine, biology, sociology, humanities, and other important fields. These case studies and selected applications revealed that there are general similarities of the stack-based layering structures and formations among all the various research fields. Such general similarities clearly demonstrate the global concept of the “fractals-general stacking behavior” of real life systems during their change pathways. Therefore, it is recommended that concentrated efforts should be expedited toward building generic modular stack-based systems or blocks for the mathematical

  1. Structural context effects in the oxidation of 8-oxo-7,8-dihydro-2'-deoxyguanosine to hydantoin products: electrostatics, base stacking, and base pairing.

    Science.gov (United States)

    Fleming, Aaron M; Muller, James G; Dlouhy, Adrienne C; Burrows, Cynthia J

    2012-09-12

    8-Oxo-7,8-dihydroguanine (OG) is the most common base damage found in cells, where it resides in many structural contexts, including the nucleotide pool, single-stranded DNA at transcription forks and replication bubbles, and duplex DNA base-paired with either adenine (A) or cytosine (C). OG is prone to further oxidation to the highly mutagenic hydantoin products spiroiminodihydantoin (Sp) and 5-guanidinohydantoin (Gh) in a sharply pH-dependent fashion within nucleosides. In the present work, studies were conducted to determine how the structural context affects OG oxidation to the hydantoins. These studies revealed a trend in which the Sp yield was greatest in unencumbered contexts, such as nucleosides, while the Gh yield increased in oligodeoxynucleotide (ODN) contexts or at reduced pH. Oxidation of oligomers containing hydrogen-bond modulators (2,6-diaminopurine, N(4)-ethylcytidine) or alteration of the reaction conditions (pH, temperature, and salt) identify base stacking, electrostatics, and base pairing as the drivers of the key intermediate 5-hydroxy-8-oxo-7,8-dihydroguanine (5-HO-OG) partitioning along the two hydantoin pathways, allowing us to propose a mechanism for the observed base-pairing effects. Moreover, these structural effects cause an increase in the effective pK(a) of 5-HO-OG, following an increasing trend from 5.7 in nucleosides to 7.7 in a duplex bearing an OG·C base pair, which supports the context-dependent product yields. The high yield of Gh in ODNs underscores the importance of further study on this lesion. The structural context of OG also determined its relative reactivity toward oxidation, for which the OG·A base pair is ~2.5-fold more reactive than an OG·C base pair, and with the weak one-electron oxidant ferricyanide, the OG nucleoside reactivity is >6000-fold greater than that of OG·C in a duplex, leading to the conclusion that OG in the nucleoside pool should act as a protective agent for OG in the genome.

  2. Structural Context Effects in the Oxidation of 8-Oxo-7,8-dihydro-2’-deoxyguanosine to Hydantoin Products: Electrostatics, Base Stacking, and Base Pairing

    Science.gov (United States)

    Fleming, Aaron M.; Muller, James G.; Dlouhy, Adrienne C.; Burrows, Cynthia J.

    2012-01-01

    8-Oxo-7,8-dihydroguanine (OG) is the most common base damage found in the cell where it resides in many structural contexts including the nucleotide pool, single-stranded DNA at transcription forks and replication bubbles, and in duplex DNA base paired with either A or C. OG is prone to further oxidation to the highly mutagenic hydantoin products, spiroiminodihydantoin (Sp) and 5-guanidinohydantoin (Gh) in a sharply pH-dependent fashion within nucleosides. In the present work, studies were conducted to determine how the structural context affects OG oxidation to the hydantoins. These studies revealed a trend in which the Sp yield was greatest in unencumbered contexts, such as nucleosides, while the Gh yield increased in oligodeoxynucleotide (ODN) contexts or at reduced pH. Oxidation of oligomers containing hydrogen bond modulators (2,6-diaminopurine, N4-ethylcytidine) or alteration of the reaction conditions (pH, temperature, and salt) identify base stacking, electrostatics and base pairing as the drivers of the key intermediate 5-hydroxy-8-oxo-7,8-dihydroguanine (5-HO-OG) partitioning along the two hydantoin pathways, allowing us to propose a mechanism for the observed base pairing effects. Moreover, these structural effects cause an increase in the effective pKa of 5-HO-OG following an increasing trend from 5.7 in nucleosides to 7.7 in a duplex bearing an OG•C base pair, which supports the context-dependent product yields. The high yield of Gh in ODNs underscores the importance of further study on this lesion. The structural context of OG also determined its relative reactivity toward oxidation for which the OG•A base pair is ~2.5-fold more reactive than an OG•C base pair, and with the weak one-electron oxidant ferricyanide, the OG nucleoside reactivity is >6000-fold greater than that of OG•C in a duplex, leading to the conclusion that OG in the nucleoside pool should act as a protective agent for OG in the genome. PMID:22880947

  3. Multiple Segmentation of Image Stacks

    DEFF Research Database (Denmark)

    Smets, Jonathan; Jaeger, Manfred

    2014-01-01

    We propose a method for the simultaneous construction of multiple image segmentations by combining a recently proposed “convolution of mixtures of Gaussians” model with a multi-layer hidden Markov random field structure. The resulting method constructs for a single image several, alternative...... segmentations that capture different structural elements of the image. We also apply the method to collections of images with identical pixel dimensions, which we call image stacks. Here it turns out that the method is able to both identify groups of similar images in the stack, and to provide segmentations...

  4. Seismic and structural characterization of the fluid bypass system using 3D and partial stack seismic from passive margin: inside the plumbing system.

    Science.gov (United States)

    Iacopini, David; Maestrelli, Daniele; Jihad, Ali; Bond, Clare; Bonini, Marco

    2017-04-01

    In recent years enormous attention has been paid to the understanding of the process and mechanism controlling the gas seepage and more generally the fluid expulsion affecting the earth system from onshore to offshore environment. This is because of their demonstrated impact to our environment, climate change and during subsea drilling operation. Several example from active and paleo system has been so far characterized and proposed using subsurface exploration, geophysical and geochemical monitoring technology approaches with the aims to explore what trigger and drive the overpressure necessary maintain the fluid/gas/material expulsion and what are the structure that act as a gateway for gaseous fluid and unconsolidated rock. In this contribution we explore a series of fluid escape structure (ranging from seepage pipes to large blowout pipes structure of km length) using 3D and partial stack seismic data from two distinctive passive margin from the north sea (Loyal field, West Shetland) and the Equatorial Brazil (Ceara' Basin). We will focuses on the characterization of the plumbing system internal architecture and, for selected example, exploring the AVO response (using partial stack) of the internal fluid/unconsolidated rock. The detailed seismic mapping and seismic attributes analysis of the conduit system helped us to recover some detail from the signal response of the chimney internal structures. We observed: (1) small to medium seeps and pipes following structural or sedimentary discontinuities (2) large pipes (probably incipient mud volcanoes) and blowup structures propagating upward irrespective of pre-existing fault by hydraulic fracturing and assisted by the buoyancy of a fluidised and mobilised mud-hydrocarbon mixture. The reflector termination observed inside the main conduits, the distribution of stacked bright reflectors and the AVO analysis suggests an evolution of mechanisms (involving mixture of gas, fluid and probably mud) during pipe birth and

  5. Effect of Pr Valence State on Interfacial Structure and Electrical Properties of Pr Oxide/PrON/Ge Gate Stack Structure

    Science.gov (United States)

    Kato, Kimihiko; Sakashita, Mitsuo; Takeuchi, Wakana; Kondo, Hiroki; Nakatsuka, Osamu; Zaima, Shigeaki

    2011-04-01

    In this study, we investigated the valence state and chemical bonding state of Pr in a Pr oxide/PrON/Ge structure. We clarified the relationship between the valence state of Pr and the Pr oxide/Ge interfacial reaction using Pr oxide/Ge and Pr oxide/PrON/Ge samples. We found the formation of three Pr oxide phases in Pr oxide films; hexagonal Pr2O3 (h-Pr2O3) (Pr3+), cubic Pr2O3 (c-Pr2O3) (Pr3+), and c-PrO2 (Pr4+). We also investigated the effect of a nitride interlayer on the interfacial reaction in Pr oxide/Ge gate stacks. In a sample with a nitride interlayer (Pr oxide/PrON/Ge), metallic Pr-Pr bonds are also formed in the c-Pr2O3 film. After annealing in H2 ambient, the diffusion of Ge into Pr oxide is not observed in this sample. Pr-Pr bonds probably prevent the interfacial reaction and Ge oxide formation, considering that the oxygen chemical potential of this film is lower than that of a GeO2/Ge system. On the other hand, the rapid thermal oxidation (RTO) treatment terminates the O vacancies and defects in c-Pr2O3. As a result, c-PrO2 with tetravalent Pr is formed in the Pr oxide/PrON/Ge sample with RTO. In this sample, the leakage current density is effectively decreased in comparison with the sample without RTO. Hydrogen termination works effectively in Pr oxide/PrON/Ge samples with and without RTO, and we can achieve an interface state density of as low as 4 ×1011 eV-1·cm-2.

  6. Embedded LTPS flash cells with oxide-nitride-oxynitride stack structure for realization of multi-function mobile flat panel displays

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Sungwook; Kim, Jaehong; Son, Hyukjoo; Jang, Kyungsoo; Cho, Jaehyun; Kim, Kyunghae; Choi, Byoungdeog; Yi, Junsin [School of Information and Communication Engineering, Sungkyunkwan University, Suwon, 440-746 (Korea, Republic of)], E-mail: yi@yurim.skku.ac.kr

    2008-09-07

    In this paper, embedded flash (eFlash) cells were fabricated for realization of multi-functions, such as systems on panels (SOPs) and threshold voltage (V{sub TH}) stabilization of flat panel displays (FPDs). Fabrication was via low temperature polycrystalline silicon (LTPS) thin film transistor (TFT) technology and an oxide-nitride-oxynitride (ONOn) stack structure on glass. Poly-silicon (poly-Si) on glass, which was annealed via an excimer laser, has a very rough surface. To fabricate LTPS eFlash cells on glass with a very rough poly-Si surface, plasma-assisted oxynitridation was performed; nitrous oxide (N{sub 2}O) served as a reactive gas. LTPS eFlash cells have excellent TFT electrical properties, such as V{sub TH}, a high On/Off current ratio and a low sub-threshold swing (S). The results demonstrate that eFlash cells fabricated on glass with a rough silicon surface, via an ONOn stack structure, have switching characteristics suitable for data storage, such as a low operating voltage (<{+-}10 V) suitable for mobile FPDs, a threshold voltage window, {delta}V{sub TH}, which exceeds 2.3 V, between the programming and erasing (P/E) states, over a period of 10 years, and the capacity to retain the initial {delta}V{sub TH} over a period of 10{sup 5} P/E operations. (fast track communication)

  7. Simulating Small-Scale Object Stacking Using Stack Stability

    DEFF Research Database (Denmark)

    Kronborg Thomsen, Kasper; Kraus, Martin

    2015-01-01

    This paper presents an extension system to a closed-source, real-time physics engine for improving structured stacking behavior with small-scale objects such as wooden toy bricks. The proposed system was implemented and evaluated. The tests showed that the system is able to simulate several common...

  8. Rectangular groupoids and related structures.

    Science.gov (United States)

    Boykett, Tim

    2013-07-06

    The quasivariety of groupoids [Formula: see text] satisfying the implication [Formula: see text] generalises rectangular semigroups and central groupoids. We call them rectangular groupoids and find three combinatorial structures based upon arrays, matrices and graphs that are closely related. These generalise several groupoids of independent interest. The quasivariety generates the variety of all groupoids; they satisfy no nontrivial equations. We see some strong connections with isotopy, this being one of the classes of algebras (along with quasigroups) closed under isotopy. We investigate some constructions and show that a regular automorphism exists iff the groupoid is derived from a group via a Cayley graph construction.

  9. A series of Cd(II) complexes with π-π stacking and hydrogen bonding interactions: Structural diversities by varying the ligands

    International Nuclear Information System (INIS)

    Wang Xiuli; Zhang Jinxia; Liu Guocheng; Lin Hongyan

    2011-01-01

    Seven new Cd(II) complexes consisting of different phenanthroline derivatives and organic acid ligands, formulated as [Cd(PIP) 2 (dnba) 2 ] (1), [Cd(PIP)(ox)].H 2 O (2), [Cd(PIP)(1,4-bdc)(H 2 O)].4H 2 O (3), [Cd(3-PIP) 2 (H 2 O) 2 ].4H 2 O (4), [Cd 2 (3-PIP) 4 (4,4'-bpdc)(H 2 O) 2 ].5H 2 O (5), [Cd(3-PIP)(nip)(H 2 O)].H 2 O (6), [Cd 2 (TIP) 4 (4,4'-bpdc)(H 2 O) 2 ].3H 2 O (7) (PIP=2-phenylimidazo[4,5-f]1,10-phenanthroline, 3-PIP=2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline, TIP=2-(2-thienyl)imidazo[4,5-f]1,10-phenanthroline, Hdnba=3,5-dinitrobenzoic acid, H 2 ox=oxalic acid, 1,4-H 2 bdc=benzene-1,4-dicarboxylic acid, 4,4'-H 2 bpdc=biphenyl-4,4'-dicarboxylic acid, H 2 nip=5-nitroisophthalic acid) have been synthesized under hydrothermal conditions. Complexes 1 and 4 possess mononuclear structures; complexes 5 and 7 are isostructural and have dinuclear structures; complexes 2 and 3 feature 1D chain structures; complex 6 contains 1D double chain, which are further extended to a 3D supramolecular structure by π-π stacking and hydrogen bonding interactions. The N-donor ligands with extended π-system and organic acid ligands play a crucial role in the formation of the final supramolecular frameworks. Moreover, thermal properties and fluorescence of 1-7 are also investigated. -- Graphical abstract: Seven new supramolecular architectures have been successfully isolated under hydrothermal conditions by reactions of different phen derivatives and Cd(II) salts together with organic carboxylate anions auxiliary ligands. Display Omitted Research highlights: → Complexes 1-7 are 0D or 1D polymeric structure, the π-π stacking and H-bonding interactions extend the complexes into 3D supramolecular network. To our knowledge, systematic study on π-π stacking and H-bonding interactions in cadmium(II) complexes are still limited. → The structural differences among the title complexes indicate the importance of N-donor chelating ligands for the creation of molecular

  10. Hydrogen Embrittlement And Stacking-Fault Energies

    Science.gov (United States)

    Parr, R. A.; Johnson, M. H.; Davis, J. H.; Oh, T. K.

    1988-01-01

    Embrittlement in Ni/Cu alloys appears related to stacking-fault porbabilities. Report describes attempt to show a correlation between stacking-fault energy of different Ni/Cu alloys and susceptibility to hydrogen embrittlement. Correlation could lead to more fundamental understanding and method of predicting susceptibility of given Ni/Cu alloy form stacking-fault energies calculated from X-ray diffraction measurements.

  11. Effects of Gate Stack Structural and Process Defectivity on High-k Dielectric Dependence of NBTI Reliability in 32 nm Technology Node PMOSFETs

    Directory of Open Access Journals (Sweden)

    H. Hussin

    2014-01-01

    Full Text Available We present a simulation study on negative bias temperature instability (NBTI induced hole trapping in E′ center defects, which leads to depassivation of interface trap precursor in different geometrical structures of high-k PMOSFET gate stacks using the two-stage NBTI model. The resulting degradation is characterized based on the time evolution of the interface and hole trap densities, as well as the resulting threshold voltage shift. By varying the physical thicknesses of the interface silicon dioxide (SiO2 and hafnium oxide (HfO2 layers, we investigate how the variation in thickness affects hole trapping/detrapping at different stress temperatures. The results suggest that the degradations are highly dependent on the physical gate stack parameters for a given stress voltage and temperature. The degradation is more pronounced by 5% when the thicknesses of HfO2 are increased but is reduced by 11% when the SiO2 interface layer thickness is increased during lower stress voltage. However, at higher stress voltage, greater degradation is observed for a thicker SiO2 interface layer. In addition, the existence of different stress temperatures at which the degradation behavior differs implies that the hole trapping/detrapping event is thermally activated.

  12. Direct evidence of flat band voltage shift for TiN/LaO or ZrO/SiO2stack structure via work function depth profiling.

    Science.gov (United States)

    Heo, Sung; Park, Hyoungsun; Ko, Dong-Su; Kim, Yong Su; Kyoung, Yong Koo; Lee, Hyung-Ik; Cho, Eunae; Lee, Hyo Sug; Park, Gyung-Su; Shin, Jai Kwang; Lee, Dongjin; Lee, Jieun; Jung, Kyoungho; Jeong, Moonyoung; Yamada, Satoru; Kang, Hee Jae; Choi, Byoung-Deog

    2017-03-02

    We demonstrated that a flat band voltage (V FB ) shift could be controlled in TiN/(LaO or ZrO)/SiO 2 stack structures. The V FB shift described in term of metal diffusion into the TiN film and silicate formation in the inserted (LaO or ZrO)/SiO 2 interface layer. The metal doping and silicate formation confirmed by using transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) line profiling, respectively. The direct work function measurement technique allowed us to make direct estimate of a variety of flat band voltages (V FB ). As a function of composition ratio of La or Zr to Ti in the region of a TiN/(LaO or ZrO)/SiO 2 /Si stack, direct work function modulation driven by La and Zr doping was confirmed with the work functions obtained from the cutoff value of secondary electron emission by auger electron spectroscopy (AES). We also suggested an analytical method to determine the interface dipole via work function depth profiling.

  13. Effect of Thermal Budget on the Electrical Characterization of Atomic Layer Deposited HfSiO/TiN Gate Stack MOSCAP Structure.

    Directory of Open Access Journals (Sweden)

    Z N Khan

    Full Text Available Metal Oxide Semiconductor (MOS capacitors (MOSCAP have been instrumental in making CMOS nano-electronics realized for back-to-back technology nodes. High-k gate stacks including the desirable metal gate processing and its integration into CMOS technology remain an active research area projecting the solution to address the requirements of technology roadmaps. Screening, selection and deposition of high-k gate dielectrics, post-deposition thermal processing, choice of metal gate structure and its post-metal deposition annealing are important parameters to optimize the process and possibly address the energy efficiency of CMOS electronics at nano scales. Atomic layer deposition technique is used throughout this work because of its known deposition kinetics resulting in excellent electrical properties and conformal structure of the device. The dynamics of annealing greatly influence the electrical properties of the gate stack and consequently the reliability of the process as well as manufacturable device. Again, the choice of the annealing technique (migration of thermal flux into the layer, time-temperature cycle and sequence are key parameters influencing the device's output characteristics. This work presents a careful selection of annealing process parameters to provide sufficient thermal budget to Si MOSCAP with atomic layer deposited HfSiO high-k gate dielectric and TiN gate metal. The post-process annealing temperatures in the range of 600°C -1000°C with rapid dwell time provide a better trade-off between the desirable performance of Capacitance-Voltage hysteresis and the leakage current. The defect dynamics is thought to be responsible for the evolution of electrical characteristics in this Si MOSCAP structure specifically designed to tune the trade-off at low frequency for device application.

  14. Glassy carbon based supercapacitor stacks

    Energy Technology Data Exchange (ETDEWEB)

    Baertsch, M.; Braun, A.; Koetz, R.; Haas, O. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Considerable effort is being made to develop electrochemical double layer capacitors (EDLC) that store relatively large quantities of electrical energy and possess at the same time a high power density. Our previous work has shown that glassy carbon is suitable as a material for capacitor electrodes concerning low resistance and high capacity requirements. We present the development of bipolar electrochemical glassy carbon capacitor stacks of up to 3 V. Bipolar stacks are an efficient way to meet the high voltage and high power density requirements for traction applications. Impedance and cyclic voltammogram measurements are reported here and show the frequency response of a 1, 2, and 3 V stack. (author) 3 figs., 1 ref..

  15. Deploying OpenStack

    CERN Document Server

    Pepple, Ken

    2011-01-01

    OpenStack was created with the audacious goal of being the ubiquitous software choice for building public and private cloud infrastructures. In just over a year, it's become the most talked-about project in open source. This concise book introduces OpenStack's general design and primary software components in detail, and shows you how to start using it to build cloud infrastructures. If you're a developer, technologist, or system administrator familiar with cloud offerings such as Rackspace Cloud or Amazon Web Services, Deploying OpenStack shows you how to obtain and deploy OpenStack softwar

  16. OpenStack essentials

    CERN Document Server

    Radez, Dan

    2015-01-01

    If you need to get started with OpenStack or want to learn more, then this book is your perfect companion. If you're comfortable with the Linux command line, you'll gain confidence in using OpenStack.

  17. Mastering OpenStack

    CERN Document Server

    Khedher, Omar

    2015-01-01

    This book is intended for system administrators, cloud engineers, and system architects who want to deploy a cloud based on OpenStack in a mid- to large-sized IT infrastructure. If you have a fundamental understanding of cloud computing and OpenStack and want to expand your knowledge, then this book is an excellent checkpoint to move forward.

  18. Guanine base stacking in G-quadruplex nucleic acids

    Science.gov (United States)

    Lech, Christopher Jacques; Heddi, Brahim; Phan, Anh Tuân

    2013-01-01

    G-quadruplexes constitute a class of nucleic acid structures defined by stacked guanine tetrads (or G-tetrads) with guanine bases from neighboring tetrads stacking with one another within the G-tetrad core. Individual G-quadruplexes can also stack with one another at their G-tetrad interface leading to higher-order structures as observed in telomeric repeat-containing DNA and RNA. In this study, we investigate how guanine base stacking influences the stability of G-quadruplexes and their stacked higher-order structures. A structural survey of the Protein Data Bank is conducted to characterize experimentally observed guanine base stacking geometries within the core of G-quadruplexes and at the interface between stacked G-quadruplex structures. We couple this survey with a systematic computational examination of stacked G-tetrad energy landscapes using quantum mechanical computations. Energy calculations of stacked G-tetrads reveal large energy differences of up to 12 kcal/mol between experimentally observed geometries at the interface of stacked G-quadruplexes. Energy landscapes are also computed using an AMBER molecular mechanics description of stacking energy and are shown to agree quite well with quantum mechanical calculated landscapes. Molecular dynamics simulations provide a structural explanation for the experimentally observed preference of parallel G-quadruplexes to stack in a 5′–5′ manner based on different accessible tetrad stacking modes at the stacking interfaces of 5′–5′ and 3′–3′ stacked G-quadruplexes. PMID:23268444

  19. Relative role of transfer zones in controlling sequence stacking patterns and facies distribution: insights from the Fushan Depression, South China Sea

    Science.gov (United States)

    Liu, Entao; Wang, Hua; Li, Yuan; Huang, Chuanyan

    2015-04-01

    In sedimentary basins, a transfer zone can be defined as a coordinated system of deformational features which has good prospects for hydrocarbon exploration. Although the term 'transfer zone' has been widely applied to the study of extensional basins, little attention has been paid to its controlling effect on sequence tracking pattern and depositional facies distribution. Fushan Depression is a half-graben rift sub-basin, located in the southeast of the Beibuwan Basin, South China Sea. In this study, comparative analysis of seismic reflection, palaeogeomorphology, fault activity and depositional facies distribution in the southern slope indicates that three different types of sequence stacking patterns (i.e. multi-level step-fault belt in the western area, flexure slope belt in the central area, gentle slope belt in the eastern area) were developed along the southern slope, together with a large-scale transfer zone in the central area, at the intersection of the western and eastern fault systems. Further analysis shows that the transfer zone played an important role in the diversity of sequence stacking patterns in the southern slope by dividing the Fushan Depression into two non-interfering tectonic systems forming different sequence patterns, and leading to the formation of the flexure slope belt in the central area. The transfer zone had an important controlling effect on not only the diversity of sequence tracking patterns, but also the facies distribution on the relay ramp. During the high-stand stage, under the controlling effect of the transfer zone, the sediments contain a significant proportion of coarser material accumulated and distributed along the ramp axis. By contrast, during the low-stand stage, the transfer zone did not seem to contribute significantly to the low-stand fan distribution which was mainly controlled by the slope gradient (palaeogeomorphology). Therefore, analysis of the transfer zone can provide a new perspective for basin analysis

  20. Hybrid Tourism-Related Structures

    DEFF Research Database (Denmark)

    Pasgaard, Jens Christian

    2014-01-01

    This article is rooted in theories presented in the PhD dissertation Tourism and Strategic Planning (Pasgaard 2012) and features a number of much discussed concepts related to the complicated phenomenon of tourism and to the discipline of strategic urban planning. It is beyond the scope of this a...

  1. Photo-induced tunneling currents in MOS structures with various HfO2/SiO2 stacking dielectrics

    OpenAIRE

    Chin-Sheng Pang; Jenn-Gwo Hwu

    2014-01-01

    In this study, the current conduction mechanisms of structures with tandem high-k dielectric in illumination are discussed. Samples of Al/SiO2/Si (S), Al/HfO2/SiO2/Si (H), and Al/3HfO2/SiO2/Si (3H) were examined. The significant observation of electron traps of sample H compares to sample S is found under the double bias capacitance-voltage (C-V) measurements in illumination. Moreover, the photo absorption sensitivity of sample H is higher than S due to the formation of HfO2 dielectric layer,...

  2. Relating structure and dynamics in organisation models

    NARCIS (Netherlands)

    Jonkers, C.M.; Treur, J.

    2002-01-01

    To understand how an organisational structure relates to dynamics is an interesting fundamental challenge in the area of social modelling. Specifications of organisational structure usually have a diagrammatic form that abstracts from more detailed dynamics. Dynamic properties of agent systems,

  3. Structural color-tunable mesoporous bragg stack layers based on graft copolymer self-assembly for high-efficiency solid-state dye-sensitized solar cells

    Science.gov (United States)

    Lee, Chang Soo; Park, Jung Tae; Kim, Jong Hak

    2016-08-01

    We present a facile fabrication route for structural color-tunable mesoporous Bragg stack (BS) layers based on the self-assembly of a cost-effective graft copolymer. The mesoporous BS layers are prepared through the alternating deposition of organized mesoporous-TiO2 (OM-TiO2) and -SiO2 (OM-SiO2) films on the non-conducting side of the counter electrode in dye-sensitized solar cells (DSSCs). The OM layers with controlled porosity, pore size, and refractive index are templated with amphiphilic graft copolymers consisting of poly(vinyl chloride) backbones and poly(oxyethylene methacrylate) side chains, i.e., PVC-g-POEM. The morphology and properties of the structural color-tunable mesoporous BS-functionalized electrodes are characterized using energy filtered transmission electron microscopy (EF-TEM), field emission-scanning electron microscopy (FE-SEM), spectroscopic ellipsometry, and reflectance spectroscopy. The solid-state DSSCs (ssDSSCs) based on a structural color-tunable mesoporous BS counter electrode with a single-component solid electrolyte show an energy conversion efficiency (η) of 7.1%, which is much greater than that of conventional nanocrystalline TiO2-based cells and one of the highest values for N719 dye-based ssDSSCs. The enhancement of η is due to the enhancement of current density (Jsc), attributed to the improved light harvesting properties without considerable decrease in fill factor (FF) or open-circuit voltage (Voc), as confirmed by incident photon-to-electron conversion efficiency (IPCE) and electrochemical impedance spectroscopy (EIS).

  4. Highly Efficient, Durable Regenerative Solid Oxide Stack, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Precision Combustion, Inc. (PCI) proposes to develop a highly efficient regenerative solid oxide stack design. Novel structural elements allow direct internal...

  5. Study of Sn and Mg doping effects on TiO2/Ge stack structure by combinatorial synthesis

    Science.gov (United States)

    Nagata, Takahiro; Suzuki, Yoshihisa; Yamashita, Yoshiyuki; Ogura, Atsushi; Chikyow, Toyohiro

    2018-04-01

    The effects of Sn and Mg doping of a TiO2 film on a Ge substrate were investigated to improve leakage current properties and Ge diffusion into the TiO2 film. For systematic analysis, dopant-composition-spread TiO2 samples with dopant concentrations of up to 20.0 at. % were fabricated by RF sputtering and a combinatorial method. X-ray photoelectron spectroscopy revealed that the instability of Mg doping of TiO2 at dopant concentrations above 10.5 at. %. Both Sn and Mg dopants reduced Ge diffusion into TiO2. Sn doping enhanced the crystallization of the rutile phase, which is a high-dielectric-constant phase, although the Mg-doped TiO2 film indicated an amorphous structure. Sn-doping indicated systematic leakage current reduction with increasing dopant concentration. Doping at Sn concentrations higher than 16.8 at. % improved the leakage properties (˜10-7 A/cm2 at -3.0 V) and capacitance-voltage properties of metal-insulator-semiconductor (MIS) operation. The Sn doping of TiO2 may be useful for interface control and as a dielectric material for Ge-based MIS capacitors.

  6. Hybrid Tourism-Related Structures

    DEFF Research Database (Denmark)

    Pasgaard, Jens Christian

    2014-01-01

    This article is rooted in theories presented in the PhD dissertation Tourism and Strategic Planning (Pasgaard 2012) and features a number of much discussed concepts related to the complicated phenomenon of tourism and to the discipline of strategic urban planning. It is beyond the scope...... of this article to enter a detailed discussion of all mentioned concepts; however, it is important to set the stage by providing a few compressed notes on the overall approach to the phenomenon of tourism. Corresponding to the fluid transition between chores of everyday life and tourism behavior, the tourist...... space is not an unequivocal spatial specification. Rather, tourist space is a temporary condition, which depends on tourism activity and the mode of the observer. It is essential to understand and accept the liquidity of the tourism phenomenon and remember that tourism behavior and tourist space...

  7. Oxidation behavior of metallic interconnect in solid oxide fuel cell stack

    Science.gov (United States)

    Li, Jun; Zhang, Wenying; Yang, Jiajun; Yan, Dong; Pu, Jian; Chi, Bo; Jian, Li

    2017-06-01

    Oxidation behavior of integrated interconnect with bipolar plate and corrugated sheet made by ferrite steel SUS430 is investigated and compared in simulated environment and in a realistic stack. Electrical current is found to have a direction-related impact on the thickness of the Cr2O3/MnCr2O4 composite oxide scale. Oxide scale of the interconnect aged in the stack exhibits a dual-layered structure of a complex Mn-Cr oxide layer covered by iron oxide. The oxidation rates vary greatly depending on its local environment, with different thermal, electrical density, as well as gas composition conditions. By analyzing the thickness distribution of oxide scale and comparing them with the simulated test result, the oxidation behavior of interconnect in stack is described in high definition. ASR distribution is also conducted by calculation, which could help further understanding the behavior of stack degradation.

  8. Early Port-Related Structure Studies

    Science.gov (United States)

    McCarthy, Michael

    2013-12-01

    This paper examines three of Australia's earliest port-related structure studies. Excavations conducted in 1984 and 1994 in vastly different circumstances, with markedly different oceanographic conditions, progressing through quite different substrates, were joined with 1993-1994 overview of all the port structures along the coast of Western Australia. Providing a better appreciation of submerged port-related structure studies as a bona fide part of maritime archaeology, these three studies and have ramifications for future work both in Australia and overseas.

  9. Tunable infrared plasmonic devices using graphene/insulator stacks

    Science.gov (United States)

    Yan, Hugen; Li, Xuesong; Chandra, Bhupesh; Tulevski, George; Wu, Yanqing; Freitag, Marcus; Zhu, Wenjuan; Avouris, Phaedon; Xia, Fengnian

    2012-05-01

    The collective oscillation of carriers--the plasmon--in graphene has many desirable properties, including tunability and low loss. However, in single-layer graphene, the dependence on carrier concentration of both the plasmonic resonance frequency and magnitude is relatively weak, limiting its applications in photonics. Here, we demonstrate transparent photonic devices based on graphene/insulator stacks, which are formed by depositing alternating wafer-scale graphene sheets and thin insulating layers, then patterning them together into photonic-crystal-like structures. We show experimentally that the plasmon in such stacks is unambiguously non-classical. Compared with doping in single-layer graphene, distributing carriers into multiple graphene layers effectively enhances the plasmonic resonance frequency and magnitude, which is different from the effect in a conventional semiconductor superlattice and is a direct consequence of the unique carrier density scaling law of the plasmonic resonance of Dirac fermions. Using patterned graphene/insulator stacks, we demonstrate widely tunable far-infrared notch filters with 8.2 dB rejection ratios and terahertz linear polarizers with 9.5 dB extinction ratios. An unpatterned stack consisting of five graphene layers shields 97.5% of electromagnetic radiation at frequencies below 1.2 THz. This work could lead to the development of transparent mid- and far-infrared photonic devices such as detectors, modulators and three-dimensional metamaterial systems.

  10. Stack filter classifiers

    Energy Technology Data Exchange (ETDEWEB)

    Porter, Reid B [Los Alamos National Laboratory; Hush, Don [Los Alamos National Laboratory

    2009-01-01

    Just as linear models generalize the sample mean and weighted average, weighted order statistic models generalize the sample median and weighted median. This analogy can be continued informally to generalized additive modeels in the case of the mean, and Stack Filters in the case of the median. Both of these model classes have been extensively studied for signal and image processing but it is surprising to find that for pattern classification, their treatment has been significantly one sided. Generalized additive models are now a major tool in pattern classification and many different learning algorithms have been developed to fit model parameters to finite data. However Stack Filters remain largely confined to signal and image processing and learning algorithms for classification are yet to be seen. This paper is a step towards Stack Filter Classifiers and it shows that the approach is interesting from both a theoretical and a practical perspective.

  11. Laser pulse stacking method

    Science.gov (United States)

    Moses, E.I.

    1992-12-01

    A laser pulse stacking method is disclosed. A problem with the prior art has been the generation of a series of laser beam pulses where the outer and inner regions of the beams are generated so as to form radially non-synchronous pulses. Such pulses thus have a non-uniform cross-sectional area with respect to the outer and inner edges of the pulses. The present invention provides a solution by combining the temporally non-uniform pulses in a stacking effect to thus provide a more uniform temporal synchronism over the beam diameter. 2 figs.

  12. Design Handbook for a Stack Foundation

    OpenAIRE

    Tuominen, Vilma

    2011-01-01

    This thesis was made for Citec Engineering Oy Ab as a handbook and as a design tool for concrete structure designers. Handbook is about the Wärtsilä Power Plant stack structure, which is a base for about 40 meters high stack pipe. The purpose is to make a calculation base to support the design work, which helps the designer to check the right dimensions of the structure. Thesis is about to be for the concrete designers and also other designers and authorities. As an example I have used an...

  13. Superluminary relativity related to nuclear forces and structures

    International Nuclear Information System (INIS)

    Anastasovski, Petar K.

    1998-01-01

    The new Theory of Superluminary Relativity (SLR) presented and proposed here is based on the superluminary frame of reference transformation and on the modified principles of Special Relativity, General Relativity and Quantum Mass Theory. One of the main concepts of the SLR theory is application of Newton's law of universal gravitation to nuclear structures. The constant in the Newton's gravitational magnitudes for distances and masses characteristic for nuclear structures is defined and determined by the Quantum Mass Theory. The analysis is performed for a nucleus with two nucleons, that is for the deuteron nucleus. On the bases of the principles of Superluminary Relativity a new deuteron nucleus model is offered. (author)

  14. Structural Interpretation of the Large Slowdown of Water Dynamics at Stacked Phospholipid Membranes for Decreasing Hydration Level: All-Atom Molecular Dynamics

    Directory of Open Access Journals (Sweden)

    Carles Calero

    2016-04-01

    Full Text Available Hydration water determines the stability and function of phospholipid membranes as well as the interaction of membranes with other molecules. Experiments and simulations have shown that water dynamics slows down dramatically as the hydration decreases, suggesting that the interfacial water that dominates the average dynamics at low hydration is slower than water away from the membrane. Here, based on all-atom molecular dynamics simulations, we provide an interpretation of the slowdown of interfacial water in terms of the structure and dynamics of water–water and water–lipid hydrogen bonds (HBs. We calculate the rotational and translational slowdown of the dynamics of water confined in stacked phospholipid membranes at different levels of hydration, from completely hydrated to poorly hydrated membranes. For all hydrations, we analyze the distribution of HBs and find that water–lipids HBs last longer than water–water HBs and that at low hydration most of the water is in the interior of the membrane. We also show that water–water HBs become more persistent as the hydration is lowered. We attribute this effect (i to HBs between water molecules that form, in turn, persistent HBs with lipids; (ii to the hindering of the H-bonding switching between water molecules due to the lower water density at the interface; and (iii to the higher probability of water–lipid HBs as the hydration decreases. Our interpretation of the large dynamic slowdown in water under dehydration is potentially relevant in understanding membrane biophysics at different hydration levels.

  15. On the Relative Stability of Donor and Acceptor Stacks Against the Peierls Distortion in the Tetrathia- and Tetraselenafulvalenium Tetracyanoquinodimethanide Family of Organic Metals

    DEFF Research Database (Denmark)

    Andersen, Jan Rud; Taranko, A. R.; Tomkiewicz, Y.

    1987-01-01

    An organic conductor having a Peierls instability driven by donor stacks is considered. The compound is tetramethyltetraselenafulvalene-2,5-dimethyltetracyanoquinodimethane. Magnetic data confirm that the instability is donor driven. The influence of the unit cell size is examined. The unit cell...

  16. Safety Evaluation of Radioactive Material Transport Package under Stacking Test Condition

    International Nuclear Information System (INIS)

    Lee, Ju Chan; Seo, Ki Seog; Yoo, Seong Yeon

    2012-01-01

    Radioactive waste transport package was developed to transport eight drums of low and intermediate level waste(LILW) in accordance with the IAEA and domestic related regulations. The package is classified with industrial package IP-2. IP-2 package is required to undergo a free drop test and a stacking test. After free drop and stacking tests, it should prevent the loss or dispersal of radioactive contents, and loss of shielding integrity which would result in more than 20 % increase in the radiation level at any external surface of the package. The objective of this study is to establish the safety test method and procedure for stacking test and to prove the structural integrities of the IP-2 package. Stacking test and analysis were performed with a compressive load equal to five times the weight of the package for a period of 24 hours using a full scale model. Strains and displacements were measured at the corner fitting of the package during the stacking test. The measured strains and displacements were compared with the analysis results, and there were good agreements. It is very difficult to measure the deflection at the container base, so the maximum deflection of the container base was calculated by the analysis method. The maximum displacement at the corner fitting and deflection at the container base were less than their allowable values. Dimensions of the test model, thickness of shielding material and bolt torque were measured before and after the stacking test. Throughout the stacking test, it was found that there were no loss or dispersal of radioactive contents and no loss of shielding integrity. Thus, the package was shown to comply with the requirements to maintain structural integrity under the stacking condition.

  17. po_stack_movie

    DEFF Research Database (Denmark)

    2009-01-01

    po_stack® er et reolsystem, hvis enkle elementer giver stor flexibilitet, variation og skulpturel virkning. Elementerne stables og forskydes frit, så reolens rum kan vendes til begge sider, være åbne eller lukkede og farvekombineres ubegrænset. Reolen kan let ombygges, udvides eller opdeles, når ...

  18. Learning SaltStack

    CERN Document Server

    Myers, Colton

    2015-01-01

    If you are a system administrator who manages multiple servers, then you know how difficult it is to keep your infrastructure in line. If you've been searching for an easier way, this book is for you. No prior experience with SaltStack is required.

  19. Relating structure and dynamics in organisation models

    NARCIS (Netherlands)

    Jonker, C.M.; Treur, J.

    2003-01-01

    To understand how an organisational structure relates to dynamics is an interesting fundamental challenge in the area of social modelling. Specifications of organisational structure usually have a diagrammatic form that abstracts from more detailed dynamics. Dynamic properties of agent systems, on

  20. Quadratic forms and Clifford algebras on derived stacks

    OpenAIRE

    Vezzosi, Gabriele

    2013-01-01

    In this paper we present an approach to quadratic structures in derived algebraic geometry. We define derived n-shifted quadratic complexes, over derived affine stacks and over general derived stacks, and give several examples of those. We define the associated notion of derived Clifford algebra, in all these contexts, and compare it with its classical version, when they both apply. Finally, we prove three main existence results for derived shifted quadratic forms over derived stacks, define ...

  1. Numerical Simulation Study on Lateral Displacement of Pile Foundation and Construction Process under Stacking Loads

    Directory of Open Access Journals (Sweden)

    Yan-yan Cai

    2018-01-01

    Full Text Available Lateral displacement of pile foundation is crucial to the safety of an overall structure. In this study, a numerical simulation on the lateral displacement of pile foundation under stacking loads was conducted to determine its relation with different influencing factors. Simulation results demonstrated that stacking loads at the pile side mostly influence the lateral displacement of pile foundation. The lateral displacement of pile foundation increases by one order of magnitude when the stacking loads increase from 100 kPa to 300 kPa. Other influencing factors are less important than stacking loads. Lateral displacements of the pile body and at the pile top can be reduced effectively by increasing the deformation modulus of surface soil mass, reducing the thickness of soft soil, and expanding pile diameter. Our analysis indicates that a nonlinear relationship exists between the lateral displacement at the pile top and the pile diameter. The lateral resistance of the pile body can be enhanced by coupling the stacking load along piles and the axial force at the pile top. An actual large-scale engineering project was chosen to simulate the effects of postconstructed embankment on lateral displacement and axial force of bridge pile foundation under different construction conditions and to obtain the lateral displacement of the pile body and the negative frictional resistance caused by soft soil compression under stacking loads. On the basis of the calculated results, engineering safety and stability were evaluated, and a guide for the design and construction was proposed.

  2. Energy Expenditure of Sport Stacking

    Science.gov (United States)

    Murray, Steven R.; Udermann, Brian E.; Reineke, David M.; Battista, Rebecca A.

    2009-01-01

    Sport stacking is an activity taught in many physical education programs. The activity, although very popular, has been studied minimally, and the energy expenditure for sport stacking is unknown. Therefore, the purposes of this study were to determine the energy expenditure of sport stacking in elementary school children and to compare that value…

  3. OpenStack cloud security

    CERN Document Server

    Locati, Fabio Alessandro

    2015-01-01

    If you are an OpenStack administrator or developer, or wish to build solutions to protect your OpenStack environment, then this book is for you. Experience of Linux administration and familiarity with different OpenStack components is assumed.

  4. Studies on complex π-π and T-stacking features of imidazole and phenyl/p-halophenyl units in series of 5-amino-1-(phenyl/p-halophenyl)imidazole-4-carboxamides and their carbonitrile derivatives: Role of halogens in tuning of conformation

    Science.gov (United States)

    Das, Aniruddha

    2017-11-01

    5-amino-1-(phenyl/p-halophenyl)imidazole-4-carboxamides (N-phenyl AICA) (2a-e) and 5-amino-1-(phenyl/p-halophenyl)imidazole-4-carbonitriles (N-phenyl AICN) (3a-e) had been synthesized. X-ray crystallographic studies of 2a-e and 3a-e had been performed to identify any distinct change in stacking patterns in their crystal lattice. Single crystal X-ray diffraction studies of 2a-e revealed π-π stack formations with both imidazole and phenyl/p-halophenyl units in anti and syn parallel-displaced (PD)-type dispositions. No π-π stacking of imidazole occurred when the halogen substituent is bromo or iodo; π-π stacking in these cases occurred involving phenyl rings only. The presence of an additional T-stacking had been observed in crystal lattices of 3a-e. Vertical π-π stacking distances in anti-parallel PD-type arrangements as well as T-stacking distances had shown stacking distances short enough to impart stabilization whereas syn-parallel stacking arrangements had got much larger π-π stacking distances to belie any syn-parallel stacking stabilization. DFT studies had been pursued for quantifying the π-π stacking and T-stacking stabilization. The plotted curves for anti-parallel and T-stacked moieties had similarities to the 'Morse potential energy curve for diatomic molecule'. The minima of the curves corresponded to the most stable stacking distances and related energy values indicated stacking stabilization. Similar DFT studies on syn-parallel systems of 2b corresponded to no π-π stacking stabilization at all. Halogen-halogen interactions had also been observed to stabilize the compounds 2d, 2e and 3d. Nano-structural behaviour of the series of compounds 2a-e and 3a-e were thoroughly investigated.

  5. Highly Accurate CCSD(T) and DFT-SAPT Stabilization Energies of H-Bonded and Stacked Structures of the Uracil Dimer

    Czech Academy of Sciences Publication Activity Database

    Pitoňák, Michal; Riley, Kevin Eugene; Neogrady, P.; Hobza, Pavel

    2008-01-01

    Roč. 9, č. 12 (2008), s. 1636-1644 ISSN 1439-4235 R&D Projects: GA MŠk LC512 Grant - others:SRDA(SK) APVV-20-018405 Institutional research plan: CEZ:AV0Z40550506 Keywords : ab initio calculations * correlation energy * hydrogen bonds * nucleotides * stacking interactions Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.636, year: 2008

  6. Stack Caching Using Split Data Caches

    DEFF Research Database (Denmark)

    Nielsen, Carsten; Schoeberl, Martin

    2015-01-01

    In most embedded and general purpose architectures, stack data and non-stack data is cached together, meaning that writing to or loading from the stack may expel non-stack data from the data cache. Manipulation of the stack has a different memory access pattern than that of non-stack data, showing...... higher temporal and spatial locality. We propose caching stack and non-stack data separately and develop four different stack caches that allow this separation without requiring compiler support. These are the simple, window, and prefilling with and without tag stack caches. The performance of the stack...

  7. Contemporary sample stacking in analytical electrophoresis.

    Science.gov (United States)

    Malá, Zdena; Šlampová, Andrea; Křivánková, Ludmila; Gebauer, Petr; Boček, Petr

    2015-01-01

    This contribution is a methodological review of the publications about the topic from the last 2 years. Therefore, it is primarily organized according to the methods and procedures used in surveyed papers and the origin and type of sample and specification of analytes form the secondary structure. The introductory part about navigation in the architecture of stacking brings a brief characterization of the various stacking methods, with the description of mutual links to each other and important differences among them. The main body of the article brings a survey of publications organized according to main principles of stacking and then according to the origin and type of the sample. Provided that the paper cited gave explicitly the relevant data, information about the BGE(s) used, procedure, detector employed, and reached LOD and/or concentration effect is given. The papers where the procedure used is a combination of diverse fragments and parts of various stacking techniques are mentioned in a special section on combined techniques. The concluding remarks in the final part of the review evaluate present state of art and the trends of sample stacking in CE. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Calculation of AC losses in large HTS stacks and coils

    DEFF Research Database (Denmark)

    Zermeno, Victor; Abrahamsen, Asger Bech; Mijatovic, Nenad

    2012-01-01

    In this work, we present a homogenization method to model a stack of HTS tapes under AC applied transport current or magnetic field. The idea is to find an anisotropic bulk equivalent for the stack of tapes, where the internal alternating structures of insulating, metallic, superconducting and su...

  9. Direction dependent structures in general relativity

    International Nuclear Information System (INIS)

    Herberthson, M.

    1993-01-01

    This thesis deals with, within the theory of general relativity, asymptotic properties of certain types of space-times. Using conformal transformations, it is possible to describe asymptotic properties of a physical space-time in terms of the local behaviour of the new, rescaled space-time. One then uses so called direction dependent structures. We present two such structures and applications to them. One structure is used in the study of spacelike (or spatial) infinity. We discuss the asymptotic conditions on the gravitational and the electromagnetic field, especially the conditions put on directions corresponding to future and past null infinity. It is shown that these fields have desired physical properties. The other structure is used in connection with timelike infinity. Using this structure, we suggest a new definition of timelike infinity. This definition differs significantly from earlier definitions, and leads to the concept of asymptotically stationary space-times. We also suggest a definition of asymptotic flatness at future null infinity, and a definition of a black hole which is, in a sense, local. Both of these definitions fit nicely into the structure. (24 refs.)

  10. A novel configuration for direct internal reforming stacks

    Science.gov (United States)

    Fellows, Richard

    This paper presents a stack concept that can be applied to both molten carbonate fuel cell (MCFC) and solid oxide fuel cell (SOFC) internal reforming stacks. It employs anode recycle and allows the design of very simple system configurations, while giving enhanced efficiencies and high specific power densities. The recycle of anode exit gas to the anode inlet has previously been proposed as a means of preventing carbon deposition in direct internal reforming (DIR) stacks. When applied to a normal stack this reduces the Nernst voltages because the recycle stream is relatively depleted in hydrogen. In the concept proposed here, known as the `Smarter' stack, there are two anode exit streams, one of which is depleted, while the other is relatively undepleted. The depleted stream passes directly to the burner, and the undepleted stream is recycled to the stack inlet. By this means high Nernst voltages are achieved in the stack. The concept has been simulated and assessed for parallel-flow and cross-flow MCFC and SOFC stacks and graphs are presented showing temperature distributions. The `Smarter' stacks employ a high recycle rate resulting in a reduced natural gas concentration at the stack inlet, and this reduces or eliminates the unfavourable temperature dip. Catalyst grading can further improve the temperature distribution. The concept allows simple system configurations in which the need for fuel pre-heat is eliminated. Efficiencies are up to 10 percentage points higher than for conventional stacks with the same cell area and maximum stack temperature. The concept presented here was devised in a project part-funded by the EU, and has been adopted by the European Advanced DIR-MCFC development programme led by BCN.

  11. Enhanced photocatalytic activity over Cd0.5Zn0.5S with stacking fault structure combined with Cu2+ modified carbon nanotubes

    International Nuclear Information System (INIS)

    Gong, Beini; Lu, Yonghong; Wu, Pingxiao; Huang, Zhujian; Zhu, Yajie; Dang, Zhi; Zhu, Nengwu; Lu, Guining; Huang, Junyi

    2016-01-01

    Graphical abstract: - Highlights: • CdZnS with stacking faults was combined with Cu 2+ modified carbon nanotubes. • Stacking faults and carbon nanotubes (Cu) synergized to promote charge separation. • The composite exhibited enhanced photocatalytic performance. - Abstract: For enhanced photocatalytic performance of visible light responsive CdZnS, a series of Cd 0.5 Zn 0.5 S solid solutions were fabricated by different methods. It was found that the semiconductor obtained through the precipitation-hydrothermal method (CZS-PH) exhibited the highest photocatalytic hydrogen production rate of 2154 μmol h −1 g −1 . The enhanced photocatalytic hydrogen production of CZS-PH was probably due to stacking fault formation as well as narrow bandgap, a large surface area and a small crystallite size. Based on this, carbon nanotubes modified with Cu 2+ (CNTs (Cu)) were used as a cocatalyst for CZS-PH. The addition of CNTs (Cu) enhanced notably the absorption of the composites for visible light. The highest photocatalytic hydrogen production rate of the Cd 0.5 Zn 0.5 S-CNTs (Cu) composite was 2995 μmol h −1 g −1 with 1.0 wt.% of CNTs (Cu). The improvement of the photocatalytic activity by loading of CNTs (Cu) was not due to alteration of bandgap energy or surface area, and was probably attributed to suppression of the electron-hole recombination by the CNTs, with Cu 2+ anchored in the interface optimizing the photogenerated electron transfer pathway between the semiconductor and CNTs. We report here the successful combination of homojunction and heterojunction in CdZnS semiconductor, which resulted in promotion of charge separation and enhanced photocatalytic activity.

  12. Passive stack ventilation

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, J.; Parkins, L.; Shaw, P.; Watkins, R. [Databuild, Birmingham (United Kingdom)

    1994-12-31

    The adequate ventilation of houses is essential for both the occupants and the building fabric. As air-tightness standards increase, background infiltration levels decrease and extra ventilation has to be designed into the building. Passive stack ventilation has many advantages - particularly when employed in low cost housing schemes -but it is essential that it performs satisfactorily. This paper give the results from monitoring two passive stack ventilation schemes. One scheme was a retrofit into refurbished local authority houses in which a package of energy efficiency measures had been taken and condensation had been a problem. The other series of tests were conducted on a new installation in a Housing Association development. Nine houses were monitored each of which had at least two passive vents. The results show air flow rates by the passive ducts equivalent to approximately 1 room air change per hour. The air flow in the ducts was influenced by both, internal to external temperature difference and wind speed and direction. (author)

  13. Asymmetric Flexible Supercapacitor Stack

    Directory of Open Access Journals (Sweden)

    Leela Mohana Reddy A

    2008-01-01

    Full Text Available AbstractElectrical double layer supercapacitor is very significant in the field of electrical energy storage which can be the solution for the current revolution in the electronic devices like mobile phones, camera flashes which needs flexible and miniaturized energy storage device with all non-aqueous components. The multiwalled carbon nanotubes (MWNTs have been synthesized by catalytic chemical vapor deposition technique over hydrogen decrepitated Mischmetal (Mm based AB3alloy hydride. The polymer dispersed MWNTs have been obtained by insitu polymerization and the metal oxide/MWNTs were synthesized by sol-gel method. Morphological characterizations of polymer dispersed MWNTs have been carried out using scanning electron microscopy (SEM, transmission electron microscopy (TEM and HRTEM. An assymetric double supercapacitor stack has been fabricated using polymer/MWNTs and metal oxide/MWNTs coated over flexible carbon fabric as electrodes and nafion®membrane as a solid electrolyte. Electrochemical performance of the supercapacitor stack has been investigated using cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy.

  14. Preparative separation and structural identification of impurities of a new α2-Adrenoceptor agonist using stacking injection, LC-MSn and LC-SPE-NMR

    International Nuclear Information System (INIS)

    Cardoso, Josiane O.; Thomasi, Sérgio S.; Venâncio, Tiago; Oliveira, Regina V.; Pitta, Ivan R.; Lima, Maria do Carmo A. de

    2017-01-01

    Identifying impurities in drug substances has become one of the most important issues in pharmaceutical analysis since it can have a significant impact on the efficacy of new pharmaceutical products. Due to the purity requirements, in this paper a new synthetic α 2 -adrenoceptor agonist, called LPSF-PT-31, was purified and its impurities were characterized by liquid chromatography multistage mass spectrometry (LC-MS n ) and liquid chromatography-solid phase extraction-nuclear magnetic resonance (LC-SPE-NMR). The purification step was conducted using a semi-preparative liquid chromatography and stacked injections as a new approach to drug purification. As a result, a total yield of 75% of the pure LPSF-PT-31 and 2.9 L day - '1 in solvent reduction was obtained. The combination of semi-preparative stacking injection, LC-MS n , and LC-SPE-NMR, demonstrated to be efficient to purify active drugs and unambiguously identify its impurities. In addition, isolation and identification of drug impurities in the early stages of development can improve the synthetic pathway, preventing the formation of impurities or minimizing this formation to minimum levels. (author)

  15. Electrically tunable switching based on photonic-crystal waveguide loaded graphene stacks

    Science.gov (United States)

    Liu, Hanqing; Liu, Peiguo; Bian, Li-an; Liu, Chenxi; Zhou, Qihui; Dong, Yanfei

    2018-03-01

    Through applying gate voltage to tune the chemical potential of graphene, the relative permittivity of multilayer graphene/Al2O3 stack can be dynamically adjusted over a wide range. In this paper, we mainly design novel photonic-crystal waveguides based on graphene stacks including a side-coupled waveguide with two defect cavities as well as a two-channel multiport waveguide, and aim to modulate the propagation of incident light wave via controlling the permittivity of graphene stack. It is demonstrated according to simulations that tunable switching property can be achieved in our proposed structures, such as blue shift of resonant stopband, adjustable coupled-resonator-induced transparency, and tunability of output quantity. These results could be very instructive for the potential applications in high-density integrated optical devices, photoelectric transducer, and laser pulse limiters.

  16. A Software Managed Stack Cache for Real-Time Systems

    DEFF Research Database (Denmark)

    Jordan, Alexander; Abbaspourseyedi, Sahar; Schoeberl, Martin

    2016-01-01

    In a real-time system, the use of a scratchpad memory can mitigate the difficulties related to analyzing data caches, whose behavior is inherently hard to predict. We propose to use a scratchpad memory for stack allocated data. While statically allocating stack frames for individual functions to ...

  17. Efficient Context Switching for the Stack Cache: Implementation and Analysis

    DEFF Research Database (Denmark)

    Abbaspourseyedi, Sahar; Brandner, Florian; Naji, Amine

    2015-01-01

    , the analysis of the stack cache was limited to individual tasks, ignoring aspects related to multitasking. A major drawback of the original stack cache design is that, due to its simplicity, it cannot hold the data of multiple tasks at the same time. Consequently, the entire cache content needs to be saved...

  18. Instant BlueStacks

    CERN Document Server

    Judge, Gary

    2013-01-01

    Get to grips with a new technology, understand what it is and what it can do for you, and then get to work with the most important features and tasks. A fast-paced, example-based approach guide for learning BlueStacks.This book is for anyone with a Mac or PC who wants to run Android apps on their computer. Whether you want to play games that are freely available for Android but not your computer, or you want to try apps before you install them on a physical device or use it as a development tool, this book will show you how. No previous experience is needed as this is written in plain English

  19. California dreaming?[PEM stacks

    Energy Technology Data Exchange (ETDEWEB)

    Crosse, J.

    2002-06-01

    Hyundai's Santa Fe FCEV will be on sale by the end of 2002. Hyundai uses PEM stacks that are manufactured by International Fuel Cells (IFC), a division of United Technologies. Santa Fe is equipped with a 65 kW electric powertrain of Enova systems and Shell's new gasoline reformer called Hydrogen Source. Eugene Jang, Senior Engineer - Fuel Cell and Materials at Hyundai stated that the compressor related losses on IFC system are below 3%. The maximum speed offered by the vehicle is estimated as 123km/hr while the petrol equivalent fuel consumption is quoted between 5.6L/100 km and 4.8L/100 km. Santa Fe is a compact vehicle offering better steering response and a pleasant drive. (author)

  20. Crystal Structure of Three Compounds Related to Triphenylene and Tetracyanoquinodimethane

    DEFF Research Database (Denmark)

    Andresen, T.L.; Krebs, Frederik C; Larsen, M.

    1999-01-01

    The crystal structures of a charge-transfer complex of triphenylene with 1,3,5-tris(2,2-dicyanovinyl) benzene (1), a complex of 2,3,6,7,10,11-hexamethoxytriphenylene with 2,5-dichlorotetracyanoquinodimethane (2) and also 2,5-dichlorotetracyanoquinodimethane itself (3) have been determined. Compou...... = 83.73(3), gamma = 66.06(3)degrees. Compound 3 is monoclinic, space group I2/a (C2/c), with a = 13.692(3), b = 7.7183(15), c = 16.391(3) Angstrom, beta = 99.47(3)degrees. The structures of 1 and 2 consist of mixed stacks of donors and accepters. The structures of 2 and 3 both include 1...

  1. Temperature dependence of stacking faults in catalyst-free GaAs nanopillars.

    Science.gov (United States)

    Shapiro, Joshua N; Lin, Andrew; Ratsch, Christian; Huffaker, D L

    2013-11-29

    Impressive opto-electronic devices and transistors have recently been fabricated from GaAs nanopillars grown by catalyst-free selective-area epitaxy, but this growth technique has always resulted in high densities of stacking faults. A stacking fault occurs when atoms on the growing (111) surface occupy the sites of a hexagonal-close-pack (hcp) lattice instead of the normal face-centered-cubic (fcc) lattice sites. When stacking faults occur consecutively, the crystal structure is locally wurtzite instead of zinc-blende, and the resulting band offsets are known to negatively impact device performance. Here we present experimental and theoretical evidence that indicate stacking fault formation is related to the size of the critical nucleus, which is temperature dependent. The difference in energy between the hcp and fcc orientation of small nuclei is computed using density-function theory. The minimum energy difference of 0.22 eV is calculated for a nucleus with 21 atoms, so the population of nuclei in the hcp orientation is expected to decrease as the nucleus grows larger. The experiment shows that stacking fault occurrence is dramatically reduced from 22% to 3% by raising the growth temperature from 730 to 790 ° C. These data are interpreted using classical nucleation theory which dictates a larger critical nucleus at higher growth temperature.

  2. Synthesis of Structures Related to Antifreeze Glycoproteins

    OpenAIRE

    Fyrner, Timmy

    2005-01-01

    In this thesis, synthesis of structures related to antifreeze glycoproteins (AFGPs) are presented. Synthetic routes to a protected carbohydrate derivative, 2,3,4,6-tetra-O-benzyl-β-galactopyranosyl-(1→3)-2-deoxy-2-azido-4,6-di-O-benzyl-β-D-thio-1-galactopyranoside, and a tBu-Ala-Thr-Ala-Fmoc tripeptide, are described. These compounds are meant to be used in the assembly of AFGPs and analogues thereof. A Gal-GlcN disaccharide was synthesized via glycosylation between the donor, bromo-2-O-benzo...

  3. Coexistence of diode-like volatile and multilevel nonvolatile resistive switching in a ZrO2/TiO2 stack structure.

    Science.gov (United States)

    Li, Yingtao; Yuan, Peng; Fu, Liping; Li, Rongrong; Gao, Xiaoping; Tao, Chunlan

    2015-10-02

    Diode-like volatile resistive switching as well as nonvolatile resistive switching behaviors in a Cu/ZrO₂/TiO₂/Ti stack are investigated. Depending on the current compliance during the electroforming process, either volatile resistive switching or nonvolatile resistive switching is observed. With a lower current compliance (volatile resistive switching with a rectifying ratio over 10(6). The permanent transition from volatile to nonvolatile resistive switching can be obtained by applying a higher current compliance of 100 μA. Furthermore, by using different reset voltages, the Cu/ZrO₂/TiO₂/Ti device exhibits multilevel memory characteristics with high uniformity. The coexistence of nonvolatile multilevel memory and diode-like volatile resistive switching behaviors in the same Cu/ZrO₂/TiO₂/Ti device opens areas of applications in high-density storage, logic circuits, neural networks, and passive crossbar memory selectors.

  4. Assessing Elementary Algebra with STACK

    Science.gov (United States)

    Sangwin, Christopher J.

    2007-01-01

    This paper concerns computer aided assessment (CAA) of mathematics in which a computer algebra system (CAS) is used to help assess students' responses to elementary algebra questions. Using a methodology of documentary analysis, we examine what is taught in elementary algebra. The STACK CAA system, http://www.stack.bham.ac.uk/, which uses the CAS…

  5. HPC Software Stack Testing Framework

    Energy Technology Data Exchange (ETDEWEB)

    2017-07-27

    The HPC Software stack testing framework (hpcswtest) is used in the INL Scientific Computing Department to test the basic sanity and integrity of the HPC Software stack (Compilers, MPI, Numerical libraries and Applications) and to quickly discover hard failures, and as a by-product it will indirectly check the HPC infrastructure (network, PBS and licensing servers).

  6. The behaviour of stacking fault energy upon interstitial alloying.

    Science.gov (United States)

    Lee, Jee-Yong; Koo, Yang Mo; Lu, Song; Vitos, Levente; Kwon, Se Kyun

    2017-09-11

    Stacking fault energy is one of key parameters for understanding the mechanical properties of face-centered cubic materials. It is well known that the plastic deformation mechanism is closely related to the size of stacking fault energy. Although alloying is a conventional method to modify the physical parameter, the underlying microscopic mechanisms are not yet clearly established. Here, we propose a simple model for determining the effect of interstitial alloying on the stacking fault energy. We derive a volumetric behaviour of stacking fault energy from the harmonic approximation to the energy-lattice curve and relate it to the contents of interstitials. The stacking fault energy is found to change linearly with the interstitial content in the usual low concentration domain. This is in good agreement with previously reported experimental and theoretical data.

  7. A protein relational database and protein family knowledge bases to facilitate structure-based design analyses.

    Science.gov (United States)

    Mobilio, Dominick; Walker, Gary; Brooijmans, Natasja; Nilakantan, Ramaswamy; Denny, R Aldrin; Dejoannis, Jason; Feyfant, Eric; Kowticwar, Rupesh K; Mankala, Jyoti; Palli, Satish; Punyamantula, Sairam; Tatipally, Maneesh; John, Reji K; Humblet, Christine

    2010-08-01

    The Protein Data Bank is the most comprehensive source of experimental macromolecular structures. It can, however, be difficult at times to locate relevant structures with the Protein Data Bank search interface. This is particularly true when searching for complexes containing specific interactions between protein and ligand atoms. Moreover, searching within a family of proteins can be tedious. For example, one cannot search for some conserved residue as residue numbers vary across structures. We describe herein three databases, Protein Relational Database, Kinase Knowledge Base, and Matrix Metalloproteinase Knowledge Base, containing protein structures from the Protein Data Bank. In Protein Relational Database, atom-atom distances between protein and ligand have been precalculated allowing for millisecond retrieval based on atom identity and distance constraints. Ring centroids, centroid-centroid and centroid-atom distances and angles have also been included permitting queries for pi-stacking interactions and other structural motifs involving rings. Other geometric features can be searched through the inclusion of residue pair and triplet distances. In Kinase Knowledge Base and Matrix Metalloproteinase Knowledge Base, the catalytic domains have been aligned into common residue numbering schemes. Thus, by searching across Protein Relational Database and Kinase Knowledge Base, one can easily retrieve structures wherein, for example, a ligand of interest is making contact with the gatekeeper residue.

  8. Stacking faults and phase transformations in silicon nitride

    Science.gov (United States)

    Milhet, X.; Demenet, J.-L.; Rabier, J.

    1998-11-01

    From observations of extended dislocation nodes in β silicon nitride, possible stacking fault structures in the basal plane of this compound have been investigated. It has been found that stacking fault structure is locally analogous to α silicon nitride. A phase transformation α to β or β to α can also be achieved by cooperative shear of partial dislocations with 1/3<~ngle1bar{1}00rangle Burgers vectors.

  9. Occurrence and stability of lone pair–π stacking interactions between ribose and nucleobases in functional RNAs

    KAUST Repository

    Chawla, Mohit

    2017-08-18

    The specific folding pattern and function of RNA molecules lies in various weak interactions, in addition to the strong base-base pairing and stacking. One of these relatively weak interactions, characterized by the stacking of the O4′ atom of a ribose on top of the heterocycle ring of a nucleobase, has been known to occur but has largely been ignored in the description of RNA structures. We identified 2015 ribose–base stacking interactions in a high-resolution set of non-redundant RNA crystal structures. They are widespread in structured RNA molecules and are located in structural motifs other than regular stems. Over 50% of them involve an adenine, as we found ribose-adenine contacts to be recurring elements in A-minor motifs. Fewer than 50% of the interactions involve a ribose and a base of neighboring residues, while approximately 30% of them involve a ribose and a nucleobase at least four residues apart. Some of them establish inter-domain or inter-molecular contacts and often implicate functionally relevant nucleotides. In vacuo ribose-nucleobase stacking interaction energies were calculated by quantum mechanics methods. Finally, we found that lone pair–π stacking interactions also occur between ribose and aromatic amino acids in RNA–protein complexes.

  10. Interlayer vacancy defects in AA-stacked bilayer graphene: density functional theory predictions.

    Science.gov (United States)

    Vuong, A; Trevethan, T; Latham, C D; Ewels, C P; Erbahar, D; Briddon, P R; Rayson, M J; Heggie, M I

    2017-04-20

    AA-stacked graphite and closely related structures, where carbon atoms are located in registry in adjacent graphene layers, are a feature of graphitic systems including twisted and folded bilayer graphene, and turbostratic graphite. We present the results of ab initio density functional theory calculations performed to investigate the complexes that are formed from the binding of vacancy defects across neighbouring layers in AA-stacked bilayers. As with AB stacking, the carbon atoms surrounding lattice vacancies can form interlayer structures with sp 2 bonding that are lower in energy than in-plane reconstructions. The sp 2 interlayer bonding of adjacent multivacancy defects in registry creates a type of stable sp 2 bonded 'wormhole' or tunnel defect between the layers. We also identify a new class of 'mezzanine' structure characterised by sp 3 interlayer bonding, resembling a prismatic vacancy loop. The V 6 hexavacancy variant, where six sp 3 carbon atoms sit midway between two carbon layers and bond to both, is substantially more stable than any other vacancy aggregate in AA-stacked layers. Our focus is on vacancy generation and aggregation in the absence of extreme temperatures or intense beams.

  11. Interlayer vacancy defects in AA-stacked bilayer graphene: density functional theory predictions

    Science.gov (United States)

    Vuong, A.; Trevethan, T.; Latham, C. D.; Ewels, C. P.; Erbahar, D.; Briddon, P. R.; Rayson, M. J.; Heggie, M. I.

    2017-04-01

    AA-stacked graphite and closely related structures, where carbon atoms are located in registry in adjacent graphene layers, are a feature of graphitic systems including twisted and folded bilayer graphene, and turbostratic graphite. We present the results of ab initio density functional theory calculations performed to investigate the complexes that are formed from the binding of vacancy defects across neighbouring layers in AA-stacked bilayers. As with AB stacking, the carbon atoms surrounding lattice vacancies can form interlayer structures with sp 2 bonding that are lower in energy than in-plane reconstructions. The sp 2 interlayer bonding of adjacent multivacancy defects in registry creates a type of stable sp 2 bonded ‘wormhole’ or tunnel defect between the layers. We also identify a new class of ‘mezzanine’ structure characterised by sp 3 interlayer bonding, resembling a prismatic vacancy loop. The V 6 hexavacancy variant, where six sp 3 carbon atoms sit midway between two carbon layers and bond to both, is substantially more stable than any other vacancy aggregate in AA-stacked layers. Our focus is on vacancy generation and aggregation in the absence of extreme temperatures or intense beams.

  12. Deformation Induced Microtwins and Stacking Faults in Aluminum Single Crystal

    Science.gov (United States)

    Han, W. Z.; Cheng, G. M.; Li, S. X.; Wu, S. D.; Zhang, Z. F.

    2008-09-01

    Microtwins and stacking faults in plastically deformed aluminum single crystal were successfully observed by high-resolution transmission electron microscope. The occurrence of these microtwins and stacking faults is directly related to the specially designed crystallographic orientation, because they were not observed in pure aluminum single crystal or polycrystal before. Based on the new finding above, we propose a universal dislocation-based model to judge the preference or not for the nucleation of deformation twins and stacking faults in various face-centered-cubic metals in terms of the critical stress for dislocation glide or twinning by considering the intrinsic factors, such as stacking fault energy, crystallographic orientation, and grain size. The new finding of deformation induced microtwins and stacking faults in aluminum single crystal and the proposed model should be of interest to a broad community.

  13. Aging of nuclear safety related concrete structures

    International Nuclear Information System (INIS)

    Cerny, R.; Vydra, V.; Toman, J.; Vodak, F.

    1994-01-01

    An analysis of aging processes in nuclear-safety-related concrete structures (NSRCS) is presented. The major environmental stressor and aging factors affecting the performance of NSRCS are summarized, as are drying and plastic shrinkage, expansion of water during the freeze-thaw cycle, water passing through cracks dissolving or leaching the soluble calcium hydroxide, attack of acid rain and ground water, chemical reactions between particular aggregates and the alkaline solution within cement paste, reaction of calcium hydroxide in cement paste hydration products with atmospheric carbon dioxide, and physical radiation effects of neutrons and gamma radiation. The current methods for aging management in NSRCS are analyzed and evaluated. A new treatment is presented for the monitoring, evaluation and prediction of aging processes, consisting in a combination of theoretical methods, laboratory experiments, in-situ measurements and numerical simulations. 24 refs

  14. Stacking fault tetrahedron induced plasticity in copper single crystal

    International Nuclear Information System (INIS)

    Zhang, Liang; Lu, Cheng; Tieu, Kiet; Su, Lihong; Zhao, Xing; Pei, Linqing

    2017-01-01

    Stacking fault tetrahedron (SFT) is the most common type of vacancy clustered defects in fcc metals and alloys, and can play an important role in the mechanical properties of metallic materials. In this study, molecular dynamics (MD) simulations were carried out to investigate the incipience of plasticity and the underlying atomic mechanisms in copper single crystals with SFT. Different deformation mechanisms of SFT were reported due to the crystal orientations and loading directions (compression and tension). The results showed that the incipient plasticity in crystals with SFT resulted from the heterogeneous dislocation nucleation from SFT, so the stress required for plastic deformation was less than that needed for perfect single crystals. Three crystal orientations ([1 0 0], [1 1 0] and [1 1 1]) were specified in this study because they can represent most of the typical deformation mechanisms of SFT. MD simulations revealed that the structural transformation of SFT was frequent under the applied loading; a metastable SFT structure and the collapse of SFT were usually observed. The structural transformation resulted in a different reduction of yield stress in compression and tension, and also caused a decreased or reversed compression/tension asymmetry. Compressive stress can result in the unfaulting of Frank loop in some crystal orientations. According to the elastic theory of dislocation, the process of unfaulting was closely related to the size of the dislocation loop and the stacking fault energy.

  15. Environmental assessment of phosphogypsum stacks

    International Nuclear Information System (INIS)

    Odat, M.; Al-Attar, L.; Raja, G.; Abdul Ghany, B.

    2008-03-01

    Phosphogypsum is one of the most important by-products of phosphate fertilizer industry. It is kept in large stacks to the west of Homs city. Storing Phosphogypsum as open stacks exposed to various environmental effects, wind and rain, may cause pollution of the surrounding ecosystem (soil, plant, water and air). This study was carried out in order to assess the environmental impact of Phosphogypsum stacks on the surrounding ecosystem. The obtained results show that Phosphogypsum stacks did not increase the concentration of radionuclides, i.e. Radon-222 and Radium-226, the external exposed dose of gamma rays, as well as the concentration of heavy metals in the components of the ecosystem, soil, plant, water and air, as their concentrations did not exceed the permissible limits. However, the concentration of fluorine in the upper layer of soil, located to the east of the Phosphogypsum stacks, increased sufficiently, especially in the dry period of the year. Also, the concentration of fluoride in plants growing up near-by the Phosphogypsum stacks was too high, exceeded the permissible levels. This was reflected in poising plants and animals, feeding on the plants. Consequently, increasing the concentration of fluoride in soil and plants is the main impact of Phosphogypsum stacks on the surrounding ecosystem. Minimising this effect could be achieved by establishing a 50 meter wide protection zone surrounding the Phosphogypsum stacks, which has to be planted with non palatable trees, such as pine and cypress, forming wind barriers. Increasing the concentrations of heavy metals and fluoride in infiltrated water around the stacks was high; hence cautions must be taken to prevent its usage in any application or disposal in adjacent rivers and leaks.(author)

  16. Coexistence of diode-like volatile and multilevel nonvolatile resistive switching in a ZrO2/TiO2 stack structure

    International Nuclear Information System (INIS)

    Li, Yingtao; Yuan, Peng; Li, Rongrong; Tao, Chunlan; Fu, Liping; Gao, Xiaoping

    2015-01-01

    Diode-like volatile resistive switching as well as nonvolatile resistive switching behaviors in a Cu/ZrO 2 /TiO 2 /Ti stack are investigated. Depending on the current compliance during the electroforming process, either volatile resistive switching or nonvolatile resistive switching is observed. With a lower current compliance (<10 μA), the Cu/ZrO 2 /TiO 2 /Ti device exhibits diode-like volatile resistive switching with a rectifying ratio over 10 6 . The permanent transition from volatile to nonvolatile resistive switching can be obtained by applying a higher current compliance of 100 μA. Furthermore, by using different reset voltages, the Cu/ZrO 2 /TiO 2 /Ti device exhibits multilevel memory characteristics with high uniformity. The coexistence of nonvolatile multilevel memory and diode-like volatile resistive switching behaviors in the same Cu/ZrO 2 /TiO 2 /Ti device opens areas of applications in high-density storage, logic circuits, neural networks, and passive crossbar memory selectors. (fast track communication)

  17. PieceStack: Toward Better Understanding of Stacked Graphs.

    Science.gov (United States)

    Wu, Tongshuang; Wu, Yingcai; Shi, Conglei; Qu, Huamin; Cui, Weiwei

    2016-02-24

    Stacked graphs have been widely adopted in various fields, because they are capable of hierarchically visualizing a set of temporal sequences as well as their aggregation. However, because of visual illusion issues, connections between overly-detailed individual layers and overly-generalized aggregation are intercepted. Consequently, information in this area has yet to be fully excavated. Thus, we present PieceStack in this paper, to reveal the relevance of stacked graphs in understanding intrinsic details of their displayed shapes. This new visual analytic design interprets the ways through which aggregations are generated with individual layers by interactively splitting and re-constructing the stacked graphs. A clustering algorithm is designed to partition stacked graphs into sub-aggregated pieces based on trend similarities of layers. We then visualize the pieces with augmented encoding to help analysts decompose and explore the graphs with respect to their interests. Case studies and a user study are conducted to demonstrate the usefulness of our technique in understanding the formation of stacked graphs.

  18. Mixed Mechanism of Lubrication by Lipid Bilayer Stacks.

    Science.gov (United States)

    Boţan, Alexandru; Joly, Laurent; Fillot, Nicolas; Loison, Claire

    2015-11-10

    Although the key role of lipid bilayer stacks in biological lubrication is generally accepted, the mechanisms underlying their extreme efficiency remain elusive. In this article, we report molecular dynamics simulations of lipid bilayer stacks undergoing load and shear. When the hydration level is reduced, the velocity accommodation mechanism changes from viscous shear in hydration water to interlayer sliding in the bilayers. This enables stacks of hydrated lipid bilayers to act as efficient boundary lubricants for various hydration conditions, structures, and mechanical loads. We also propose an estimation for the friction coefficient; thanks to the strong hydration forces between lipid bilayers, the high local viscosity is not in contradiction with low friction coefficients.

  19. Optimized stacked RADFETs for milli-rad dose measurement

    International Nuclear Information System (INIS)

    O'Connell, B.; Lane, B.; Mohammadzadeh, A.

    1999-01-01

    This paper details the improvements in the design of stacked RADFETs for increased radiation sensitivity. The issues of high read-out voltage has been shown to be a draw-back. It is the body (bulk)effect factor that is responsible for the increased overall stack Threshold voltage (V T ), which is greater than the sum of the individual devices V T . From extensive process and device simulation and resultant circuit simulation, modified stack structures have been proposed and designed. New and exciting result of lower initial (pre-irradiation) output voltage as well as increased radiation sensitivity will be presented. (author)

  20. SEE on Different Layers of Stacked-SRAMs

    CERN Document Server

    Gupta, V; Tsiligiannis, G; Rousselet, M; Mohammadzadeh, A; Javanainen, A; Virtanen, A; Puchner, H; Saigné, F; Wrobel, F; Dilillo, L

    2015-01-01

    This paper presents heavy-ion and proton radiation test results of a 90 nm COTS SRAM with stacked structure. Radiation tests were made using high penetration heavy-ion cocktails at the HIF (Belgium) and at RADEF (Finland) as well as low energy protons at RADEF. The heavy-ion SEU cross-section showed an unusual profile with a peak at the lowest LET (heavy-ion with the highest penetration range). The discrepancy is due to the fact that the SRAM is constituted of two vertically stacked dice. The impact of proton testing on the response of both stacked dice is presented. The results are discussed and the SEU cross-sections of the upper and lower layers are compared. The impact of the stacked structure on the proton SEE rate is investigated.

  1. Density functional MO calculation for stacked DNA base-pairs with backbones.

    Science.gov (United States)

    Kurita, N; Kobayashi, K

    2000-05-01

    In order to elucidate the effect of the sugar and phosphate backbones on the stable structure and electronic properties of stacked DNA base-pairs, we performed ab initio molecular orbital (MO) calculations based on the density functional theory and Slater-type basis set. As a model cluster for stacked base-pairs, we employed three isomers for the dimer unit of stacked guanine-cytosine pairs composed with backbones as well as base-pairs. These structures were fully optimized and their electronic properties were self-consistently investigated. By including the backbones, the difference in total energy among the isomers was largely enhanced, while the trend in relative stability was not changed. The effect of backbones on the electronic properties is remarkable: the MOs with the character of the PO4 parts of backbones appear just below the highest-occupied MO. This result indicates that the PO4 parts might play a rule as a reaction site in chemical processes concerning DNA. Therefore, we conclude that the DNA backbones are indispensable for investigating the stability and electronic properties of the stacked DNA base-pairs.

  2. Multistage Force Amplification of Piezoelectric Stacks

    Science.gov (United States)

    Xu, Tian-Bing (Inventor); Siochi, Emilie J. (Inventor); Zuo, Lei (Inventor); Jiang, Xiaoning (Inventor); Kang, Jin Ho (Inventor)

    2015-01-01

    Embodiments of the disclosure include an apparatus and methods for using a piezoelectric device, that includes an outer flextensional casing, a first cell and a last cell serially coupled to each other and coupled to the outer flextensional casing such that each cell having a flextensional cell structure and each cell receives an input force and provides an output force that is amplified based on the input force. The apparatus further includes a piezoelectric stack coupled to each cell such that the piezoelectric stack of each cell provides piezoelectric energy based on the output force for each cell. Further, the last cell receives an input force that is the output force from the first cell and the last cell provides an output apparatus force In addition, the piezoelectric energy harvested is based on the output apparatus force. Moreover, the apparatus provides displacement based on the output apparatus force.

  3. Field-induced stacking transition of biofunctionalized trilayer graphene

    Energy Technology Data Exchange (ETDEWEB)

    Masato Nakano, C. [Flintridge Preparatory School, La Canada, California 91011 (United States); Sajib, Md Symon Jahan; Samieegohar, Mohammadreza; Wei, Tao [Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, Texas 77710 (United States)

    2016-02-01

    Trilayer graphene (TLG) is attracting a lot of attention as their stacking structures (i.e., rhombohedral vs. Bernal) drastically affect electronic and optical properties. Based on full-atom molecular dynamics simulations, we here predict electric field-induced rhombohedral-to-Bernal transition of TLG tethered with proteins. Furthermore, our simulations show that protein's electrophoretic mobility and diffusivity are enhanced on TLG surface. This phenomenon of controllable TLG stacking transition will contribute to various applications including biosensing.

  4. Stacking faults in a layered cobalt tellurium phosphate oxochloride

    Science.gov (United States)

    Zimmermann, Iwan; Johnsson, Mats

    2015-02-01

    The new compound Co2Te3(PO4)O6Cl was synthesized by chemical reactions in a sealed and evacuated silica tube. The crystal structure was solved from single crystal diffraction data and is made up by charge neutral layers. Within the layers two types of chains are made up by edge sharing [CoO6] and [CoO5Cl] polyhedra respectively. The chains are separated by tellurium oxide and phosphate building blocks. There are only weak Van der Waals interactions in between the layers and severe diffuse scattering is observed due to faulted stacking of the layers. Structure solutions in a P-1 triclinic cell and a larger monoclinic cell in P21/c are discussed and compared to a computer generated model. The reasons for the stacking faults may be due to that there are two positions available for each layer that results in similar connectivity to the next layer in addition to the relatively wide channels in between the layers that reduce the Van der Waals interactions in between them.

  5. Effects of combustible stacking in large compartments

    DEFF Research Database (Denmark)

    Gentili, Filippo; Giuliani, Luisa; Bontempi, Franco

    2013-01-01

    This paper focuses on the modelling of fire in case of various distributions of combustible materials in a large compartment. Large compartments often represent a challenge for structural fire safety, because of lack of prescriptive rules to follow and difficulties of taking into account the effect...... to different stacking configurations of the pallets with the avail of a CFD code. The results in term of temperatures of the hot gasses and of the steel elements composing the structural system are compared with simplified analytical model of localized and post-flashover fires, with the aim of highlighting...

  6. Crystal Structure of Three Compounds Related to Triphenylene and Tetracyanoquinodimethane

    DEFF Research Database (Denmark)

    Andresen, T.L.; Krebs, Frederik C; Larsen, M.

    1999-01-01

    The crystal structures of a charge-transfer complex of triphenylene with 1,3,5-tris(2,2-dicyanovinyl) benzene (1), a complex of 2,3,6,7,10,11-hexamethoxytriphenylene with 2,5-dichlorotetracyanoquinodimethane (2) and also 2,5-dichlorotetracyanoquinodimethane itself (3) have been determined. Compound...... = 83.73(3), gamma = 66.06(3)degrees. Compound 3 is monoclinic, space group I2/a (C2/c), with a = 13.692(3), b = 7.7183(15), c = 16.391(3) Angstrom, beta = 99.47(3)degrees. The structures of 1 and 2 consist of mixed stacks of donors and accepters. The structures of 2 and 3 both include 1......,2-dichlorobenzene solvent molecules. Weak hydrogen bonds are present in the structures of 1 and 2. Based on comparisons of bond lengths the electronic charge-transfer in 2 has been estimated to be about 0.3 e. The synthesis of 1,3,5-tris(2,2-dicyanovinyl) benzene is also reported....

  7. Engineering the hypersonic phononic band gap of hybrid Bragg stacks.

    Science.gov (United States)

    Schneider, Dirk; Liaqat, Faroha; El Boudouti, El Houssaine; El Hassouani, Youssef; Djafari-Rouhani, Bahram; Tremel, Wolfgang; Butt, Hans-Jürgen; Fytas, George

    2012-06-13

    We report on the full control of phononic band diagrams for periodic stacks of alternating layers of poly(methyl methacrylate) and porous silica combining Brillouin light scattering spectroscopy and theoretical calculations. These structures exhibit large and robust on-axis band gaps determined by the longitudinal sound velocities, densities, and spacing ratio. A facile tuning of the gap width is realized at oblique incidence utilizing the vector nature of the elastic wave propagation. Off-axis propagation involves sagittal waves in the individual layers, allowing access to shear moduli at nanoscale. The full theoretical description discerns the most important features of the hypersonic one-dimensional crystals forward to a detailed understanding, a precondition to engineer dispersion relations in such structures.

  8. Learning algorithms for stack filter classifiers

    Energy Technology Data Exchange (ETDEWEB)

    Porter, Reid B [Los Alamos National Laboratory; Hush, Don [Los Alamos National Laboratory; Zimmer, Beate G [TEXAS A& M

    2009-01-01

    Stack Filters define a large class of increasing filter that is used widely in image and signal processing. The motivations for using an increasing filter instead of an unconstrained filter have been described as: (1) fast and efficient implementation, (2) the relationship to mathematical morphology and (3) more precise estimation with finite sample data. This last motivation is related to methods developed in machine learning and the relationship was explored in an earlier paper. In this paper we investigate this relationship by applying Stack Filters directly to classification problems. This provides a new perspective on how monotonicity constraints can help control estimation and approximation errors, and also suggests several new learning algorithms for Boolean function classifiers when they are applied to real-valued inputs.

  9. System for inspection of stacked cargo containers

    Science.gov (United States)

    Derenzo, Stephen [Pinole, CA

    2011-08-16

    The present invention relates to a system for inspection of stacked cargo containers. One embodiment of the invention generally comprises a plurality of stacked cargo containers arranged in rows or tiers, each container having a top, a bottom a first side, a second side, a front end, and a back end; a plurality of spacers arranged in rows or tiers; one or more mobile inspection devices for inspecting the cargo containers, wherein the one or more inspection devices are removeably disposed within the spacers, the inspection means configured to move through the spacers to detect radiation within the containers. The invented system can also be configured to inspect the cargo containers for a variety of other potentially hazardous materials including but not limited to explosive and chemical threats.

  10. Radiation-Tolerant Intelligent Memory Stack - RTIMS

    Science.gov (United States)

    Ng, Tak-kwong; Herath, Jeffrey A.

    2011-01-01

    This innovation provides reconfigurable circuitry and 2-Gb of error-corrected or 1-Gb of triple-redundant digital memory in a small package. RTIMS uses circuit stacking of heterogeneous components and radiation shielding technologies. A reprogrammable field-programmable gate array (FPGA), six synchronous dynamic random access memories, linear regulator, and the radiation mitigation circuits are stacked into a module of 42.7 42.7 13 mm. Triple module redundancy, current limiting, configuration scrubbing, and single- event function interrupt detection are employed to mitigate radiation effects. The novel self-scrubbing and single event functional interrupt (SEFI) detection allows a relatively soft FPGA to become radiation tolerant without external scrubbing and monitoring hardware

  11. Thyristor stack for pulsed inductive plasma generation.

    Science.gov (United States)

    Teske, C; Jacoby, J; Schweizer, W; Wiechula, J

    2009-03-01

    A thyristor stack for pulsed inductive plasma generation has been developed and tested. The stack design includes a free wheeling diode assembly for current reversal. Triggering of the device is achieved by a high side biased, self supplied gate driver unit using gating energy derived from a local snubber network. The structure guarantees a hard firing gate pulse for the required high dI/dt application. A single fiber optic command is needed to achieve a simultaneous turn on of the thyristors. The stack assembly is used for switching a series resonant circuit with a ringing frequency of 30 kHz. In the prototype pulsed power system described here an inductive discharge has been generated with a pulse duration of 120 micros and a pulse energy of 50 J. A maximum power transfer efficiency of 84% and a peak power of 480 kW inside the discharge were achieved. System tests were performed with a purely inductive load and an inductively generated plasma acting as a load through transformer action at a voltage level of 4.1 kV, a peak current of 5 kA, and a current switching rate of 1 kA/micros.

  12. A Stack Cache for Real-Time Systems

    DEFF Research Database (Denmark)

    Schoeberl, Martin; Nielsen, Carsten

    2016-01-01

    Real-time systems need time-predictable computing platforms to allowfor static analysis of the worst-case execution time. Caches are important for good performance, but data caches arehard to analyze for the worst-case execution time. Stack allocated data has different properties related to local......Real-time systems need time-predictable computing platforms to allowfor static analysis of the worst-case execution time. Caches are important for good performance, but data caches arehard to analyze for the worst-case execution time. Stack allocated data has different properties related...... to locality, lifetime, and static analyzability of access addresses comparedto static or heap allocated data. Therefore, caching of stack allocateddata benefits from having its own cache. In this paper we present a cache architecture optimized for stack allocateddata. This cache is additional to the normal...

  13. Stacking dependence of carrier transport properties in multilayered black phosphorous.

    Science.gov (United States)

    Sengupta, A; Audiffred, M; Heine, T; Niehaus, T A

    2016-02-24

    We present the effect of different stacking orders on carrier transport properties of multi-layer black phosphorous. We consider three different stacking orders AAA, ABA and ACA, with increasing number of layers (from 2 to 6 layers). We employ a hierarchical approach in density functional theory (DFT), with structural simulations performed with generalized gradient approximation (GGA) and the bandstructure, carrier effective masses and optical properties evaluated with the meta-generalized gradient approximation (MGGA). The carrier transmission in the various black phosphorous sheets was carried out with the non-equilibrium green's function (NEGF) approach. The results show that ACA stacking has the highest electron and hole transmission probabilities. The results show tunability for a wide range of band-gaps, carrier effective masses and transmission with a great promise for lattice engineering (stacking order and layers) in black phosphorous.

  14. Enabling Quality Interfaces with Mask-Free Approach to Selective Growth of MoS 2 /Graphene Stacked Structures

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Rui [Department of Physics, Saint Louis University, 3511 Laclede Ave St. Louis MO 63103 USA; Moore, Logan [Department of Physics, Saint Louis University, 3511 Laclede Ave St. Louis MO 63103 USA; Ocola, Leonidas E. [Argonne National Laboratory, 9700 S. Cass Avenue Argonne IL 60439 USA; Kuljanishvili, Irma [Department of Physics, Saint Louis University, 3511 Laclede Ave St. Louis MO 63103 USA

    2016-06-20

    The mask-free patterning technique is employed to fabricate arrays of MoS2 and WS2 structures on silicon and graphene substrates with quality interfaces. By depositing precursor inks with the AFM cantilevers and subsequent heat treatment in the CVD furnace, it is demonstrated that MoS2 and WS2 structures can be formed on graphene surfaces at predefined device architectures.

  15. Parsing of the free energy of aromatic-aromatic stacking interactions in solution

    Energy Technology Data Exchange (ETDEWEB)

    Kostjukov, Viktor V.; Khomytova, Nina M. [Department of Physics, Sevastopol National Technical University, Sevastopol 99053, Crimea (Ukraine); Hernandez Santiago, Adrian A.; Tavera, Anna-Maria Cervantes; Alvarado, Julieta Salas [Faculty of Chemical Sciences, Autonomous University of Puebla, Puebla (Mexico); Evstigneev, Maxim P., E-mail: max_evstigneev@mail.ru [Department of Physics, Sevastopol National Technical University, Sevastopol 99053, Crimea (Ukraine)

    2011-10-15

    Graphical abstract: Highlights: > A protocol for decomposition of the free energy of aromatic stacking is developed. > The factors stabilizing/destabilizing stacking of aromatic molecules are defined. > Hydrophobic contribution is found to be dominant. - Abstract: We report an analysis of the energetics of aromatic-aromatic stacking interactions for 39 non-covalent reactions of self- and hetero-association of 12 aromatic molecules with different structures and charge states. A protocol for computation of the contributions to the total energy from various energetic terms has been developed and the results are consistent with experiment in 92% of all the systems studied. It is found that the contributions from hydrogen bonds and entropic factors are always unfavorable, whereas contributions from van-der-Waals, electrostatic and/or hydrophobic effects may lead to stabilizing or destabilizing factors depending on the system studied. The analysis carried out in this work provides an answer to the questions 'What forces stabilize/destabilize the stacking of aromatic molecules in aqueous-salt solution and what are their relative importance?'

  16. Parsing of the free energy of aromatic-aromatic stacking interactions in solution

    International Nuclear Information System (INIS)

    Kostjukov, Viktor V.; Khomytova, Nina M.; Hernandez Santiago, Adrian A.; Tavera, Anna-Maria Cervantes; Alvarado, Julieta Salas; Evstigneev, Maxim P.

    2011-01-01

    Graphical abstract: Highlights: → A protocol for decomposition of the free energy of aromatic stacking is developed. → The factors stabilizing/destabilizing stacking of aromatic molecules are defined. → Hydrophobic contribution is found to be dominant. - Abstract: We report an analysis of the energetics of aromatic-aromatic stacking interactions for 39 non-covalent reactions of self- and hetero-association of 12 aromatic molecules with different structures and charge states. A protocol for computation of the contributions to the total energy from various energetic terms has been developed and the results are consistent with experiment in 92% of all the systems studied. It is found that the contributions from hydrogen bonds and entropic factors are always unfavorable, whereas contributions from van-der-Waals, electrostatic and/or hydrophobic effects may lead to stabilizing or destabilizing factors depending on the system studied. The analysis carried out in this work provides an answer to the questions 'What forces stabilize/destabilize the stacking of aromatic molecules in aqueous-salt solution and what are their relative importance?'

  17. Time-predictable Stack Caching

    DEFF Research Database (Denmark)

    Abbaspourseyedi, Sahar

    completely. Thus, in systems with hard deadlines the worst-case execution time (WCET) of the real-time software running on them needs to be bounded. Modern architectures use features such as pipelining and caches for improving the average performance. These features, however, make the WCET analysis more...... addresses, provides an opportunity to predict and tighten the WCET of accesses to data in caches. In this thesis, we introduce the time-predictable stack cache design and implementation within a time-predictable processor. We introduce several optimizations to our design for tightening the WCET while...... keeping the timepredictability of the design intact. Moreover, we provide a solution for reducing the cost of context switching in a system using the stack cache. In design of these caches, we use custom hardware and compiler support for delivering time-predictable stack data accesses. Furthermore...

  18. Post-Stack Seismic Data Enhancement of Thrust-Belt Area, Sabah Basin

    Science.gov (United States)

    Latiff, A. H. Abdul; Jamaludin, S. N. F.; Zakariah, M. N. A.

    2016-02-01

    In this paper, an integrated post-stack seismic data processing and interpretation for a complex thrust-belt area was proposed. The sequence was suggested due to poor seismic data quality of the Sabah basin area that was obtained after a pre-stack data processing sequences. This basin consists of a complex geological setting such as thrust-belt with steep dip reflector which is the main features of the region. In this paper, we outlined several methods used in the seismic data processing and interpretation such as amplitude recovery and frequency filtering for enhancing seismic data quality, and relative acoustic impedance, structural smoothing and wavelet coherency were used for attribute analysis. The outcome from this research aims at illuminating the hidden structures such as proper beds termination and faults systems that was heavily affected by low signal-to-noise ratio.

  19. Stacking-dependent electronic property of trilayer graphene epitaxially grown on Ru(0001)

    Energy Technology Data Exchange (ETDEWEB)

    Que, Yande; Xiao, Wende, E-mail: wdxiao@iphy.ac.cn, E-mail: hjgao@iphy.ac.cn; Chen, Hui; Wang, Dongfei; Du, Shixuan; Gao, Hong-Jun, E-mail: wdxiao@iphy.ac.cn, E-mail: hjgao@iphy.ac.cn [Institute of Physics and University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190 (China)

    2015-12-28

    The growth, atomic structure, and electronic property of trilayer graphene (TLG) on Ru(0001) were studied by low temperature scanning tunneling microscopy and spectroscopy in combined with tight-binding approximation (TBA) calculations. TLG on Ru(0001) shows a flat surface with a hexagonal lattice due to the screening effect of the bottom two layers and the AB-stacking in the top two layers. The coexistence of AA- and AB-stacking in the bottom two layers leads to three different stacking orders of TLG, namely, ABA-, ABC-, and ABB-stacking. STS measurements combined with TBA calculations reveal that the density of states of TLG with ABC- and ABB-stacking is characterized by one and two sharp peaks near to the Fermi level, respectively, in contrast to the V-shaped feature of TLG with ABA-stacking. Our work demonstrates that TLG on Ru(0001) might be an ideal platform for exploring stacking-dependent electronic properties of graphene.

  20. Impact of process parameters on the structural and electrical properties of metal/PZT/Al2O3/silicon gate stack for non-volatile memory applications

    Science.gov (United States)

    Singh, Prashant; Jha, Rajesh Kumar; Singh, Rajat Kumar; Singh, B. R.

    2018-02-01

    In this paper, we present the structural and electrical properties of the Al2O3 buffer layer on non-volatile memory behavior using Metal/PZT/Al2O3/Silicon structures. Metal/PZT/Silicon and Metal/Al2O3/Silicon structures were also fabricated and characterized to obtain capacitance and leakage current parameters. Lead zirconate titanate (PZT::35:65) and Al2O3 films were deposited by sputtering on the silicon substrate. Memory window, PUND, endurance, breakdown voltage, effective charges, flat-band voltage and leakage current density parameters were measured and the effects of process parameters on the structural and electrical characteristics were investigated. X-ray data show dominant (110) tetragonal phase of the PZT film, which crystallizes at 500 °C. The sputtered Al2O3 film annealed at different temperatures show dominant (312) orientation and amorphous nature at 425 °C. Multiple angle laser ellipsometric analysis reveals the temperature dependence of PZT film refractive index and extinction coefficient. Electrical characterization shows the maximum memory window of 3.9 V and breakdown voltage of 25 V for the Metal/Ferroelectric/Silicon (MFeS) structures annealed at 500 °C. With 10 nm Al2O3 layer in the Metal/Ferroelectric/Insulator/Silicon (MFeIS) structure, the memory window and breakdown voltage was improved to 7.21 and 35 V, respectively. Such structures show high endurance with no significant reduction polarization charge for upto 2.2 × 109 iteration cycles.

  1. Discovering hierarchical structure in normal relational data

    DEFF Research Database (Denmark)

    Schmidt, Mikkel Nørgaard; Herlau, Tue; Mørup, Morten

    2014-01-01

    Hierarchical clustering is a widely used tool for structuring and visualizing complex data using similarity. Traditionally, hierarchical clustering is based on local heuristics that do not explicitly provide assessment of the statistical saliency of the extracted hierarchy. We propose a non......-parametric generative model for hierarchical clustering of similarity based on multifurcating Gibbs fragmentation trees. This allows us to infer and display the posterior distribution of hierarchical structures that comply with the data. We demonstrate the utility of our method on synthetic data and data of functional...

  2. Uniqueness of magnetotomography for fuel cells and fuel cell stacks

    International Nuclear Information System (INIS)

    Lustfeld, H; Hirschfeld, J; Reissel, M; Steffen, B

    2009-01-01

    The criterion for the applicability of any tomographic method is its ability to construct the desired inner structure of a system from external measurements, i.e. to solve the inverse problem. Magnetotomography applied to fuel cells and fuel cell stacks aims at determining the inner current densities from measurements of the external magnetic field. This is an interesting idea since in those systems the inner electric current densities are large, several hundred mA per cm 2 and therefore relatively high external magnetic fields can be expected. Still the question remains how uniquely the inverse problem can be solved. Here we present a proof that by exploiting Maxwell's equations extensively the inverse problem of magnetotomography becomes unique under rather mild assumptions and we show that these assumptions are fulfilled in fuel cells and fuel cell stacks. Moreover, our proof holds true for any other device fulfilling the assumptions listed here. Admittedly, our proof has one caveat: it does not contain an estimate of the precision requirements the measurements need to fulfil for enabling reconstruction of the inner current densities from external magnetic fields.

  3. Design Wave Height Related to Structure Lifetime

    DEFF Research Database (Denmark)

    Burcharth, H. F.; Liu, Z.

    1996-01-01

    the structure lifetime. This includes the statistical vagrancy of nature, sample variability and the uncertainty due to measurement or hindcast error. Moreover, based on the discussion on the statistical vagrancy of nature, a formula for the calculation of encounter probability is presented....

  4. Design Wave Height Related to Structure Lifetime

    DEFF Research Database (Denmark)

    Burcharth, H. F.; Liu, Z.

    1999-01-01

    the structure lifetime. This includes the statistical vagrancy of nature, sample variability and the uncertainty due to measurement or hindcast error. Moreover, based on the discussion on the statistical vagrancy of nature, a formula for the calculation of encounter probability is presented....

  5. Polyethylene glycols (PEG) and related structures

    DEFF Research Database (Denmark)

    Wenande, Emily; Kroigaard, Mogens; Mosbech, Holger

    2015-01-01

    We describe hypersensitivity to polyethylene glycols (PEGs), with cross-reactivity to a structural analog, polysorbate 80, in a 69-year-old patient with perioperative anaphylaxis and subsequent, severe anaphylactic reactions to unrelated medical products. PEGs and PEG analogs are prevalent...

  6. Assessing population structure: FST and related measures

    NARCIS (Netherlands)

    Meirmans, P.G.; Hedrick, P.W.

    2011-01-01

    Although FST is widely used as a measure of population structure, it has been criticized recently because of its dependency on within-population diversity. This dependency can lead to difficulties in interpretation and in the comparison of estimates among species or among loci and has led to the

  7. Synthesis, molecular and electronic structure of a stacked half-sandwich dititanium complex incorporating a cyclic p-faced bridging ligand

    Czech Academy of Sciences Publication Activity Database

    Gyepes, R.; Pinkas, Jiří; Císařová, I.; Kubišta, Jiří; Horáček, Michal; Mach, Karel

    2016-01-01

    Roč. 6, č. 96 (2016), s. 94149-94159 ISSN 2046-2069 R&D Projects: GA ČR(CZ) GAP207/12/2368 Institutional support: RVO:61388955 Keywords : atoms * carbon * electronic structure Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.108, year: 2016

  8. Pressurized electrolysis stack with thermal expansion capability

    Science.gov (United States)

    Bourgeois, Richard Scott

    2015-07-14

    The present techniques provide systems and methods for mounting an electrolyzer stack in an outer shell so as to allow for differential thermal expansion of the electrolyzer stack and shell. Generally, an electrolyzer stack may be formed from a material with a high coefficient of thermal expansion, while the shell may be formed from a material having a lower coefficient of thermal expansion. The differences between the coefficients of thermal expansion may lead to damage to the electrolyzer stack as the shell may restrain the thermal expansion of the electrolyzer stack. To allow for the differences in thermal expansion, the electrolyzer stack may be mounted within the shell leaving a space between the electrolyzer stack and shell. The space between the electrolyzer stack and the shell may be filled with a non-conductive fluid to further equalize pressure inside and outside of the electrolyzer stack.

  9. The Direct FuelCell™ stack engineering

    Science.gov (United States)

    Doyon, J.; Farooque, M.; Maru, H.

    FuelCell Energy (FCE) has developed power plants in the size range of 300 kW to 3 MW for distributed power generation. Field-testing of the sub-megawatt plants is underway. The FCE power plants are based on its Direct FuelCell™ (DFC) technology. This is so named because of its ability to generate electricity directly from a hydrocarbon fuel, such as natural gas, by reforming it inside the fuel cell stack itself. All FCE products use identical 8000 cm 2 cell design, approximately 350-400 cells per stack, external gas manifolds, and similar stack compression systems. The difference lies in the packaging of the stacks inside the stack module. The sub-megawatt system stack module contains a single horizontal stack whereas the MW-class stack module houses four identical vertical stacks. The commonality of the design, internal reforming features, and atmospheric operation simplify the system design, reduce cost, improve efficiency, increase reliability and maintainability. The product building-block stack design has been advanced through three full-size stack operations at company's headquarters in Danbury, CT. The initial proof-of-concept of the full-size stack design was verified in 1999, followed by a 1.5 year of endurance verification in 2000-2001, and currently a value-engineered stack version is in operation. This paper discusses the design features, important engineering solutions implemented, and test results of FCE's full-size DFC stacks.

  10. Introduction of a stack-phantom for PET

    International Nuclear Information System (INIS)

    Jonsson, C.; Schnell, P.O.; Jacobsson, H.; Engelin, L.; Danielsson, A.M.; Johansson, L.; Larsson, S.A.; Pagani, M.; Stone-Elander, S.

    2002-01-01

    Aim: We have previously developed a new flexible phantom system for SPECT, i.e. 'the stack phantom' (Eur. J. Nucl. Med. 27, No.2, 131-139, 2000). The unique feature of this phantom system is that it allows studies with, as well as without major degrading impacts from photon attenuation and Compton scattering. The specific aim of this work was to further develop the system with special reference to PET. Material and methods: The principle of the phantom concept is discrete sampling of 3D objects by a series of equidistant 2D planes. The 2D planes are a digitised set of 2D sections, representing the radioactivity distribution in the object of interest. Using a grey scale related to the radioactivity concentration, selected images are printed by radioactive ink on thin paper sheets and stacked into the 3D structure with low-density or with tissue equivalent material in between. Using positron emitting radionuclides, the paper sheets alone may not be sufficiently thick to avoid annihilation losses due to escaping positrons. In order to investigate the amount of additional material needed, a spot of radioactivity ( 18 F) was printed out and subsequently covered by adding thin plastic films (0.055mm) on both sides of the paper. Short PET scans (ECAT 921) were performed and the count-rate was registered after each additional layer of plastic cover. A first prototype, a cylindrical cold-spot phantom was constructed on the basis of these results. Nine identical sheets were printed out and first mounted in between 4 mm plates of polystyrene (density 1.04 g/cm 3 ). After a PET-scan, the paper sheets were re-mounted in between a low-density material (Divinycell, H30, density 0.03 g/cm 3 ) before repeating the PET scan. Results: For 18 F, the number of registered annihilation photons increased with increasing number of plastic sheets from 70% for the pure paper sheet to about 100% with 0.5 mm plastic cover on each side. PET of the low-density stacked cold spot phantom

  11. Time contour expression of limited range phenomena on stack chart; Jugo chart jo deno kyokuchi gensho jikan contour

    Energy Technology Data Exchange (ETDEWEB)

    Kametani, T.

    1997-05-27

    Time contour expression of limited range phenomena on stack chart is examined for further improvement on the result of the ultimate interpretation in the seismic reflection survey. The policy is made clear from the beginning that local phenomena are to be discussed, and data prior CMP stacking is interpreted in detail. For this purpose, it is effective to make use of the time contour expression in the midpoint-offset plane simultaneously with the CMP and COP panels. For the review of data prior to CMP stacking, it is convenient to use the CMP (CDP) stacking chart in which the data is arranged methodically. In this chart, all the channels which are crude data prior to stacking are plotted on midpoint-offset coordinates, which plane is called the MOD (Midpoint Offset Domain) panel. Various panels can be chosen unrestrictedly, and their mutual relations can be easily grasped. When data points are given a time axis, they can be expressed in a time contour. Studies are conducted about the underground structure, multiple reflection paths divided by it, and characteristics of detour reflection attributable to faults. 4 refs., 9 figs.

  12. Displacive phase transformations and generalized stacking faults

    Czech Academy of Sciences Publication Activity Database

    Paidar, Václav; Ostapovets, Andriy; Duparc, O. H.; Khalfallah, O.

    2012-01-01

    Roč. 122, č. 3 (2012), s. 490-492 ISSN 0587-4246. [International Symposium on Physics of Materials, ISPMA /12./. Praha, 04.09.2011-08.09.2011] R&D Projects: GA AV ČR IAA100100920 Institutional research plan: CEZ:AV0Z10100520 Keywords : ab-initio calculations * close-packed structures * generalized stacking faults * homogeneous deformation * lattice deformation * many-body potentials Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.531, year: 2012

  13. Collagen Structure of Tendon Relates to Function

    Directory of Open Access Journals (Sweden)

    Marco Franchi

    2007-01-01

    Full Text Available A tendon is a tough band of fibrous connective tissue that connects muscle to bone, designed to transmit forces and withstand tension during muscle contraction. Tendon may be surrounded by different structures: 1 fibrous sheaths or retinaculae; 2 reflection pulleys; 3 synovial sheaths; 4 peritendon sheaths; 5 tendon bursae. Tendons contain a few cells, mostly represented by tenoblasts along with endothelial cells and some chondrocytes; b proteoglycans (PGs, mainly decorin and hyaluronan, and c collagen, mostly type I. Tendon is a good example of a high ordered extracellular matrix in which collagen molecules assemble into filamentous collagen fibrils (formed by microfibrils which aggregate to form collagen fibers, the main structural components. It represents a multihierarchical structure as it contains collagen molecules arranged in fibrils then grouped in fibril bundles, fascicles and fiber bundles that are almost parallel to the long axis of the tendon, named as primary, secondary and tertiary bundles. Collagen fibrils in tendons show prevalently large diameter, a D-period of about 67 nm and appear built of collagen molecules lying at a slight angle (< 5°. Under polarized light microscopy the collagen fiber bundles appear crimped with alternative dark and light transverse bands. In recent studies tendon crimps observed via SEM and TEM show that the single collagen fibrils suddenly changing their direction contain knots. These knots of collagen fibrils inside each tendon crimp have been termed “fibrillar crimps”, and even if they show different aspects they all may fulfil the same functional role. As integral component of musculoskeletal system, the tendon acts to transmit muscle forces to the skeletal system. There is no complete understanding of the mechanisms in transmitting/absorbing tensional forces within the tendon; however it seems likely that a flattening of tendon crimps may occur at a first stage of tendon stretching

  14. Stack semantics of type theory

    DEFF Research Database (Denmark)

    Coquand, Thierry; Mannaa, Bassel; Ruch, Fabian

    2017-01-01

    We give a model of dependent type theory with one univalent universe and propositional truncation interpreting a type as a stack, generalizing the groupoid model of type theory. As an application, we show that countable choice cannot be proved in dependent type theory with one univalent universe...

  15. Multilayer Piezoelectric Stack Actuator Characterization

    Science.gov (United States)

    Sherrit, Stewart; Jones, Christopher M.; Aldrich, Jack B.; Blodget, Chad; Bao, Xioaqi; Badescu, Mircea; Bar-Cohen, Yoseph

    2008-01-01

    Future NASA missions are increasingly seeking to use actuators for precision positioning to accuracies of the order of fractions of a nanometer. For this purpose, multilayer piezoelectric stacks are being considered as actuators for driving these precision mechanisms. In this study, sets of commercial PZT stacks were tested in various AC and DC conditions at both nominal and extreme temperatures and voltages. AC signal testing included impedance, capacitance and dielectric loss factor of each actuator as a function of the small-signal driving sinusoidal frequency, and the ambient temperature. DC signal testing includes leakage current and displacement as a function of the applied DC voltage. The applied DC voltage was increased to over eight times the manufacturers' specifications to investigate the correlation between leakage current and breakdown voltage. Resonance characterization as a function of temperature was done over a temperature range of -180C to +200C which generally exceeded the manufacturers' specifications. In order to study the lifetime performance of these stacks, five actuators from one manufacturer were driven by a 60volt, 2 kHz sine-wave for ten billion cycles. The tests were performed using a Lab-View controlled automated data acquisition system that monitored the waveform of the stack electrical current and voltage. The measurements included the displacement, impedance, capacitance and leakage current and the analysis of the experimental results will be presented.

  16. Open stack thermal battery tests

    Energy Technology Data Exchange (ETDEWEB)

    Long, Kevin N. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Christine C. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Grillet, Anne M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Headley, Alexander J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Fenton, Kyle [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Wong, Dennis [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ingersoll, David [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-04-17

    We present selected results from a series of Open Stack thermal battery tests performed in FY14 and FY15 and discuss our findings. These tests were meant to provide validation data for the comprehensive thermal battery simulation tools currently under development in Sierra/Aria under known conditions compared with as-manufactured batteries. We are able to satisfy this original objective in the present study for some test conditions. Measurements from each test include: nominal stack pressure (axial stress) vs. time in the cold state and during battery ignition, battery voltage vs. time against a prescribed current draw with periodic pulses, and images transverse to the battery axis from which cell displacements are computed. Six battery configurations were evaluated: 3, 5, and 10 cell stacks sandwiched between 4 layers of the materials used for axial thermal insulation, either Fiberfrax Board or MinK. In addition to the results from 3, 5, and 10 cell stacks with either in-line Fiberfrax Board or MinK insulation, a series of cell-free “control” tests were performed that show the inherent settling and stress relaxation based on the interaction between the insulation and heat pellets alone.

  17. Adding large EM stack support

    KAUST Repository

    Holst, Glendon

    2016-12-01

    Serial section electron microscopy (SSEM) image stacks generated using high throughput microscopy techniques are an integral tool for investigating brain connectivity and cell morphology. FIB or 3View scanning electron microscopes easily generate gigabytes of data. In order to produce analyzable 3D dataset from the imaged volumes, efficient and reliable image segmentation is crucial. Classical manual approaches to segmentation are time consuming and labour intensive. Semiautomatic seeded watershed segmentation algorithms, such as those implemented by ilastik image processing software, are a very powerful alternative, substantially speeding up segmentation times. We have used ilastik effectively for small EM stacks – on a laptop, no less; however, ilastik was unable to carve the large EM stacks we needed to segment because its memory requirements grew too large – even for the biggest workstations we had available. For this reason, we refactored the carving module of ilastik to scale it up to large EM stacks on large workstations, and tested its efficiency. We modified the carving module, building on existing blockwise processing functionality to process data in manageable chunks that can fit within RAM (main memory). We review this refactoring work, highlighting the software architecture, design choices, modifications, and issues encountered.

  18. Discovering Multidimensional Structure in Relational Data

    DEFF Research Database (Denmark)

    Jensen, Mikael Rune; Holmgren, Thomas; Pedersen, Torben Bach

    2004-01-01

    tools are available. In this paper we present an approach for the automatic construction of multidimensional OLAP database schemas from existing relational OLTP databases, enabling easy OLAP design and analysis for most existing data sources. This is achieved through a set of practical and effective......On-Line Analytical Processing (OLAP) systems based on multidimensional databases are essential elements of decision support. However, most existing data is stored in “ordinary” relational OLTP databases, i.e., data has to be (re-) modeled as multidimensional cubes before the advantages of OLAP...... algorithms for discovering multidimensional schemas from relational databases. The algorithms take a wide range of available metadata into account in the discovery process, including functional and inclusion dependencies, and key and cardinality information....

  19. Discovering Multidimensional Structure in Relational Data

    DEFF Research Database (Denmark)

    Jensen, Mikael Rune; Holmgren, Thomas; Pedersen, Torben Bach

    2004-01-01

    On-Line Analytical Processing (OLAP) systems based on multidimensional databases are essential elements of decision support. However, most existing data is stored in “ordinary” relational OLTP databases, i.e., data has to be (re-) modeled as multidimensional cubes before the advantages of OLAP...... tools are available. In this paper we present an approach for the automatic construction of multidimensional OLAP database schemas from existing relational OLTP databases, enabling easy OLAP design and analysis for most existing data sources. This is achieved through a set of practical and effective...

  20. Probabilistic Relational Structures and Their Applications

    Science.gov (United States)

    Domotor, Zoltan

    The principal objects of the investigation reported were, first, to study qualitative probability relations on Boolean algebras, and secondly, to describe applications in the theories of probability logic, information, automata, and probabilistic measurement. The main contribution of this work is stated in 10 definitions and 20 theorems. The basic…

  1. Battery structures, self-organizing structures and related methods

    Science.gov (United States)

    Chiang, Yet-Ming [Framingham, MA; Moorehead, William Douglas [Virginia Beach, VA

    2012-06-26

    An energy storage device includes a first electrode comprising a first material and a second electrode comprising a second material, at least a portion of the first and second materials forming an interpenetrating network when dispersed in an electrolyte, the electrolyte, the first material and the second material are selected so that the first and second materials exert a repelling force on each other when combined. An electrochemical device, includes a first electrode in electrical communication with a first current collector; a second electrode in electrical communication with a second current collector; and an ionically conductive medium in ionic contact with said first and second electrodes, wherein at least a portion of the first and second electrodes form an interpenetrating network and wherein at least one of the first and second electrodes comprises an electrode structure providing two or more pathways to its current collector.

  2. Strontium titanate/silicon-based terahertz photonic crystal multilayer stack

    International Nuclear Information System (INIS)

    Xin, J.Z.; Jim, K.L.; Tsang, Y.H.; Chan, H.L.W.; Leung, C.W.; Yang, J.; Gong, X.J.; Chen, L.Q.; Gao, F.

    2012-01-01

    A one-dimensional photonic crystal working in the terahertz (THz) range was designed and implemented. To facilitate the design, the transmission properties of strontium titanate crystals were characterized by THz-time-domain spectroscopy. Relatively high refractive index (∝18.5) and transmission ratio (0.08) were observed between 0.2 to 1 THz. A stacked structure of (Si d Si /STO d STO ) N /Si d Si was then designed, with transmission spectra calculated by the transfer matrix method. The effects of the filling ratio (d STO /(d Si +d STO )), periodicity (d Si +d STO ) and the number of repeats N on the transmission of PC were investigated. The effect of introducing a defect layer was also studied. Based on these, Si/STO multilayers with STO defect thickness of 125 μm and 200 μm were measured. The shift of the defect mode was observed and compared with the calculations. (orig.)

  3. Structure of Leptin Receptor Related with Obesity

    DEFF Research Database (Denmark)

    Toleikis, Zigmantas

    of the receptor, while the D5 domain is the central leptin-binding domain, implicated in the first steps of activation. Both domains are characterized by a fibronectin type III fold and both contain a conserved WSXWS motif (X represents an unconserved amino acid residue), a distinct feature of the cytokine...... receptors. This motif is thought to play a major role in correct folding and activation of the receptor. The complex between leptin and the D5CA domain was analyzed using nuclear magnetic resonance spectroscopy and the amino acid residues implicated in the binding were determined. To investigate which parts...... interactions between the aromatic residues of the peptide. It may be speculated that these differences affect the ability of the full domains to form alternative structures around the WSXWS motif....

  4. Generalized Disjunctions in (Infinitary) Structural Consequence Relations

    Czech Academy of Sciences Publication Activity Database

    Cintula, Petr; Noguera, C.

    2012-01-01

    Roč. 18, č. 3 (2012), s. 442-443 ISSN 1079-8986. [Logic Colloquium 2011. 11.07.2011-16.07.2011, Barcelona] R&D Projects: GA MŠk(CZ) 1M0545 Institutional research plan: CEZ:AV0Z10300504 Keywords : Abstract Algebraic Logic * Generalized disjunction * Proof by cases properties * Consequence relations Subject RIV: BA - General Mathematics http://www.math.ucla.edu/~asl/bsl/1803- toc .htm

  5. Spectrally tunable linear polarization rotation using stacked metallic metamaterials

    Science.gov (United States)

    Romain, Xavier; Baida, Fadi I.; Boyer, Philippe

    2017-08-01

    We make a theoretical study of the transmission properties of a stack of metallic metamaterials and show that is able to achieve a perfect transmission selectively exhibiting broadband (Q {10}5) polarization rotation. We especially highlight how the arrangement of the stacked structure, as well as the metamaterial unit cell geometry, has a large influence on transmission in the spectral domain. For this purpose, we use an extended analytical Jones formalism that allows us to obtain a rigorous and analytical expression of the transmission. Such versatile structures could find potential applications in polarimetry or in the control of light polarization for THz waves.

  6. Comparison of strain fields in truncated and un-truncated quantum dots in stacked InAs/GaAs nanostructures with varying stacking periods

    CERN Document Server

    Shin, H; Yoo, Y H

    2003-01-01

    Strain fields in truncated and un-truncated InAs quantum dots with the same height and base length have been compared numerically when the dots are vertically stacked in a GaAs matrix at various stacking periods. The compressive hydrostatic strain in truncated dots decreases slightly as compared with the un-truncated dots without regard to the stacking period studied. However, the reduction in tensile biaxial strain, compressive radial strain and tensile axial strain was salient in the truncated dot and the reduction increased with decreasing stacking period. From such changes in strain, changes in the band gap and related properties are anticipated.

  7. Development and durability of SOFC stacks

    Energy Technology Data Exchange (ETDEWEB)

    Beeaff, D.; Dinesen, A.R.; Mikkelsen, Lars; Nielsen, Karsten A.; Solvang, M.; Hendriksen, Peter V.

    2004-12-01

    The present project is a part of the Danish SOFC programme, which has the overall aim of establishing a Danish production of SOFC - cells, stacks and systems for economical and environmentally friendly power production. The aim of the present project was to develop and demonstrate (on a small scale, few cells, few thousand hours) a durable, thermally cyclable stack with high performance at 750 deg. C. Good progress towards this target has been made and demonstrated at the level of stack-elements (one cell between two interconnects) or small stacks (3 5 cells). Three different stacks or stack-elements have been operated for periods exceeding 3000 hr. The work has covered development of stack-components (seals, interconnects, coatings, contact layers), establishment of procedures for stack assembly and initiation, and detailed electrical characterisation with the aims of identifying performance limiting factors as well as long term durability. Further, post test investigations have been carried out to identify possible degradation mechanisms. (BA)

  8. Atmospheric aerosol studies using the 'Gent' stacked filter unit and other aerosol collectors, with multi-elemental analysis of the samples by nuclear-related analytical techniques. Appendix 4

    International Nuclear Information System (INIS)

    Maenhaut, Willy; Francois, Filip; Cafmeyer, Jan; Okunade, Olusola

    1995-01-01

    Our research within the core programme of the Co-ordinated Research Programme (CRP) on Air Pollution is described. This included the analysis of the analytical quality control Nuclepore filter samples, work on the calibration of the PM10 inlet of the 'Gent' stacked filter unit (SFU) sampler, and an aerosol study with this SFU sampler at an urban residential site in Gent. The calibration of the Gent PM10 inlet was done through intercomparisons with commercially available PM10 samplers, and quite reasonable agreement was obtained. For the study at the urban residential site, a total of 118 SFU samples were collected. The samples were analyzed for the particulate mass, black carbon and up to 29 elements. The elements were measured by PIXE and short-irradiation INAA. Median atmospheric concentrations and enrichment factors were calculated for the fine and coarse size fractions, and average FINE/COARSE ratios were derived. The median concentrations were compared with those from a study, done at the same site in the fall of 1986. The levels of the automotive elements Pb and Br had decreased by a factor of about three relative to 1986, but most other elements exhibited very similar concentrations. A brief overview is given of the status in our various regional and global scale aerosol studies. Finally, our plans for future work are given. (author)

  9. Estimation of stacking fault and twin energies in transition metals

    International Nuclear Information System (INIS)

    Papon, Anne-Marie

    1979-01-01

    As twins and stacking faults play an important role in the plastic deformation of metals, the objective of this research thesis is, by using an as correct as possible description of band d state density, to assess the internal energy of twins and stacking faults in metals with a CFC, HC or CC crystal structure. If, in transition metals, cohesion mainly results from d electron attraction, other terms intervening in crystal equilibrium must also be taken into account. Thus, the author proposes a decomposition of cohesion energy. The geometry of twins and stacking faults in compact phases is defined, and energy calculations are presented and discussed. Alloying effects are then addressed, as well as a general comparison with available experimental results. After a geometric description of twins and stacking faults in CC structures, their energies are calculated for a Gaussian distribution of state density. For higher order moments, defect energy due to d orbital anisotropy is assessed, and then applied to energy and stability calculations in twins and stacking faults for various relaxed atomic configurations

  10. Terminology of the prostate and related structures.

    Science.gov (United States)

    Wendell-Smith, C

    2000-01-01

    The various studies of J.E. McNeal (1968ndash;1977) established with precision the different sites of predilection for prostatic carcinomas, benign prostatic hypertrophy (BPH), and inflammation, making the division of the prostate into right, left, and middle lobes and isthmus inadequate for their description. Unfortunately, his positional terms for the sites (peripheral, central, transition, and preprostatic) are not based on the usual parameters and cannot be directly related to those of other workers. Nevertheless, the International Federation of Associations of Anatomists' Federative Committee on Anatomical Terminology has made recommendations in Terminologia Anatomica, based on his findings but modified to take some account of those of Tisell and Salander (1975 Scand J Urol Nephrol 1975 9:185-191). The use of the term lobe is confined to the right and left lobes and the variable middle lobe. The term lobule is used for the subdivisions, which are named from the anatomical position. Thus each side has a superomedial, an anteromedial, an inferoposterior, and an inferolateral lobule. Also necessary to describe a site of predilection is a peri-urethral gland zone. In ultrasound diagnosis, the trapezoid area is important: its upper limit is the rectoperinealis, its anterior limit is the intermediate part of the urethra, its lower limit is the anoperinealis, and its posterior limit is the anorectal junction. Confusion at the bladder neck is resolved by recognizing that the position of the internal urethral orifice varies with functional state of the bladder: while it is filling the orifice lies above the base of the prostate; when voiding begins, the orifice descends to the base of the prostate; between the filling internal orifice and the emptying internal orifice is the bladder neck part of the urethra. Copyright 2000 Wiley-Liss, Inc.

  11. Communication: Thermodynamics of stacking disorder in ice nuclei

    Science.gov (United States)

    Quigley, D.

    2014-09-01

    A simple Ising-like model for the stacking thermodynamics of ice 1 is constructed for nuclei in supercooled water, and combined with classical nucleation theory. For relative stabilities of cubic and hexagonal ice I within the range of experimental estimates, this predicts critical nuclei are stacking disordered at strong sub-cooling, consistent with recent experiments. At higher temperatures nucleation of pure hexagonal ice is recovered. Lattice-switching Monte-Carlo is applied to accurately compute the relative stability of cubic and hexagonal ice for the popular mW model of water. Results demonstrate that this model fails to adequately capture the relative energetics of the two polytypes, leading to stacking disorder at all temperatures.

  12. Generalized uniform formulae for atmospheric dispersion of activities released from a ventilation stack or from a leaky reactor building

    International Nuclear Information System (INIS)

    Vlachovsky, K.; Veverka, O.; Valenta, V.

    1976-01-01

    Relations are given for the calculation of the atmospheric transport and dispersion of industrial gaseous wastes released from the stacks of factories, power plants and nuclear power plants. Modified formulae are derived for stack disposal from a small stack, also applicable in calculating the gaseous waste release from a leaky reactor. Uniform generalized formulae are presented serving the calculation of both high and short stack disposals as well as of reactor building leakages. (L.O.)

  13. Geometric Patterns for Neighboring Bases Near the Stacked State in Nucleic Acid Strands.

    Science.gov (United States)

    Sedova, Ada; Banavali, Nilesh K

    2017-03-14

    Structural variation in base stacking has been analyzed frequently in isolated double helical contexts for nucleic acids, but not as often in nonhelical geometries or in complex biomolecular environments. In this study, conformations of two neighboring bases near their stacked state in any environment are comprehensively characterized for single-strand dinucleotide (SSD) nucleic acid crystal structure conformations. An ensemble clustering method is used to identify a reduced set of representative stacking geometries based on pairwise distances between select atoms in consecutive bases, with multiple separable conformational clusters obtained for categories divided by nucleic acid type (DNA/RNA), SSD sequence, stacking face orientation, and the presence or absence of a protein environment. For both DNA and RNA, SSD conformations are observed that are either close to the A-form, or close to the B-form, or intermediate between the two forms, or further away from either form, illustrating the local structural heterogeneity near the stacked state. Among this large variety of distinct conformations, several common stacking patterns are observed between DNA and RNA, and between nucleic acids in isolation or in complex with proteins, suggesting that these might be stable stacking orientations. Noncanonical face/face orientations of the two bases are also observed for neighboring bases in the same strand, but their frequency is much lower, with multiple SSD sequences across categories showing no occurrences of such unusual stacked conformations. The resulting reduced set of stacking geometries is directly useful for stacking-energy comparisons between empirical force fields, prediction of plausible localized variations in single-strand structures near their canonical states, and identification of analogous stacking patterns in newly solved nucleic acid containing structures.

  14. Global assemblages and structural models of International Relations

    DEFF Research Database (Denmark)

    Corry, Olaf

    2014-01-01

    Rather than consigning assemblages to the micro-politics of international relations, the chapter argues that assemblages can also be seen to play a role in the ‘grand’ structures of international relations. Structural IR theory normally only considers how subjects are ordered – hierarchically......, anarchically, in core-periphery relations or in terms of networks. However, not only subjects but also assemblages – the bringing together of previously unconnected elements into novel constellations – play a critical role in structuring international relations. More specifically, one sub......-category of assemblages – those constructed as malleable and governable which I call ‘governance-objects’ – is central to structure in international relations. The chapter begins with standard definitions of what structures are – patterns of interaction between elements – and briefly covers the range of models currently...

  15. Study on the polarity, solubility, and stacking characteristics of asphaltenes

    KAUST Repository

    Zhang, Long-li

    2014-07-01

    The structure and transformation of fused aromatic ring system in asphaltenes play an important role in the character of asphaltenes, and in step affect the properties of heavy oils. Polarity, solubility and structural characteristics of asphaltenes derived from Tahe atmospheric residue (THAR) and Tuo-826 heavy crude oil (Tuo-826) were analyzed for study of their internal relationship. A fractionation method was used to separate the asphaltenes into four sub-fractions, based on their solubility in the mixed solvent, for the study of different structural and physical-chemical properties, such as polarity, solubility, morphology, stacking characteristics, and mean structural parameters. Transmission electron microscope (TEM) observation can present the intuitive morphology of asphaltene molecules, and shows that the structure of asphaltenes is in local order as well as long range disorder. The analysis results showed that n-heptane asphaltenes of THAR and Tuo-826 had larger dipole moment values, larger fused aromatic ring systems, larger mean number of stacking layers, and less interlayer spacing between stacking layers than the corresponding n-pentane asphaltenes. The sub-fractions that were inclined to precipitate from the mixture of n-heptane and tetrahydrofuran had larger polarity and less solubility. From the first sub-fraction to the fourth sub-fraction, polarity, mean stacking numbers, and average layer size from the TEM images follow a gradual decrease. The structural parameters derived from TEM images could reflect the largest fused aromatic ring system in asphaltene molecule, yet the parameters derived from 1H NMR data reflected the mean message of poly-aromatic ring systems. The structural parameters derived from TEM images were more consistent with the polarity variation of sub-fractions than those derived from 1H NMR data, which indicates that the largest fused aromatic ring system will play a more important role in the stacking characteristics of

  16. Generalized stacking fault energies of alloys.

    Science.gov (United States)

    Li, Wei; Lu, Song; Hu, Qing-Miao; Kwon, Se Kyun; Johansson, Börje; Vitos, Levente

    2014-07-02

    The generalized stacking fault energy (γ surface) provides fundamental physics for understanding the plastic deformation mechanisms. Using the ab initio exact muffin-tin orbitals method in combination with the coherent potential approximation, we calculate the γ surface for the disordered Cu-Al, Cu-Zn, Cu-Ga, Cu-Ni, Pd-Ag and Pd-Au alloys. Studying the effect of segregation of the solute to the stacking fault planes shows that only the local chemical composition affects the γ surface. The calculated alloying trends are discussed using the electronic band structure of the base and distorted alloys.Based on our γ surface results, we demonstrate that the previous revealed 'universal scaling law' between the intrinsic energy barriers (IEBs) is well obeyed in random solid solutions. This greatly simplifies the calculations of the twinning measure parameters or the critical twinning stress. Adopting two twinnability measure parameters derived from the IEBs, we find that in binary Cu alloys, Al, Zn and Ga increase the twinnability, while Ni decreases it. Aluminum and gallium yield similar effects on the twinnability.

  17. Solid Oxide Fuel Cell Stack Diagnostics

    DEFF Research Database (Denmark)

    Mosbæk, Rasmus Rode; Barfod, Rasmus Gottrup

    . An operating stack is subject to compositional gradients in the gaseous reactant streams, and temperature gradients across each cell and across the stack, which complicates detailed analysis. Several experimental stacks from Topsoe Fuel Cell A/S were characterized using Electrochemical Impedance Spectroscopy...... (EIS). The stack measurement geometry was optimized for EIS by careful selection of the placement of current feeds and voltage probes in order to minimize measurement errors. It was demonstrated that with the improved placement of current feeds and voltage probes it is possible to separate the loss...... in the hydrogen fuel gas supplied to the stack. EIS was used to examine the long-term behavior and monitor the evolution of the impedance of each of the repeating units and the whole stack. The observed impedance was analyzed in detail for one of the repeating units and the whole stack and the losses reported...

  18. Experimental 1 kW 20 cell PEFC stack

    Energy Technology Data Exchange (ETDEWEB)

    Buechi, F.N.; Marmy, C.A.; Scherer, G.G. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Ruge, M. [Swiss Federal Inst. of Technology (ETH), Zuerich (Switzerland)

    1999-08-01

    A 20-cell PEFC stack was designed and built. Resin impregnated graphite was used as bipolar plate material. The air cooling of the stack was optimized by introducing high surface structures into the open space of the cooling plates. At {eta} (H{sub 2} LHV) = 0.5 a power of 880 W was obtained under conditions of low gas-pressures of 1.15 bar{sub a}. The auxiliary power for process air supply and cooling at 880 W power is less than 7% of the power output, indicating that the described system may be operated at a high efficiency. (author) 5 figs., 2 refs.

  19. Cost Analysis of Direct Methanol Fuel Cell Stacks for Mass Production

    Directory of Open Access Journals (Sweden)

    Mauro Francesco Sgroi

    2016-11-01

    Full Text Available Fuel cells are very promising technologies for efficient electrical energy generation. The development of enhanced system components and new engineering solutions is fundamental for the large-scale deployment of these devices. Besides automotive and stationary applications, fuel cells can be widely used as auxiliary power units (APUs. The concept of a direct methanol fuel cell (DMFC is based on the direct feed of a methanol solution to the fuel cell anode, thus simplifying safety, delivery, and fuel distribution issues typical of conventional hydrogen-fed polymer electrolyte fuel cells (PEMFCs. In order to evaluate the feasibility of concrete application of DMFC devices, a cost analysis study was carried out in the present work. A 200 W-prototype developed in the framework of a European Project (DURAMET was selected as the model system. The DMFC stack had a modular structure allowing for a detailed evaluation of cost characteristics related to the specific components. A scale-down approach, focusing on the model device and projected to a mass production, was used. The data used in this analysis were obtained both from research laboratories and industry suppliers specialising in the manufacturing/production of specific stack components. This study demonstrates that mass production can give a concrete perspective for the large-scale diffusion of DMFCs as APUs. The results show that the cost derived for the DMFC stack is relatively close to that of competing technologies and that the introduction of innovative approaches can result in further cost savings.

  20. Magneto-optical properties of ABC-stacked trilayer graphene.

    Science.gov (United States)

    Lin, Yi-Ping; Lin, Chiun-Yan; Ho, Yen-Hung; Do, Thi-Nga; Lin, Ming-Fa

    2015-06-28

    The generalized tight-binding model is developed to investigate the magneto-optical absorption spectra of ABC-stacked trilayer graphene. The absorption peaks can be classified into nine categories of inter-Landau-level optical excitations, including three intra-group and six inter-group ones. Most of them belong to the twin-peak structures because of the asymmetric Landau level spectrum. The threshold absorption peak alone comes from a certain excitation channel, and its frequency is associated with a specific interlayer atomic interaction. The Landau-level anticrossings cause extra absorption peaks. Moreover, a simple relationship between the absorption frequency and the field strength is absent. The magneto-optical properties of ABC-stacked trilayer graphene are totally different from those of AAA- and ABA-stacked ones, such as the number, intensity and frequency of absorption peaks.

  1. π-Stacking interactions between G-quartets and circulenes: A ...

    Indian Academy of Sciences (India)

    Abstract. Structures of planar and bowl-shaped circulenes as well as their stacks with G-quartet (G4) have been investigated through dispersion-corrected Density Functional Theory (DFT-D). The binding energies are substantial ∼10 kcal/mol with d ∼3.5 Å between the stacking rings. The calculations show that G4 binds ...

  2. On the relationship between the irregular reflector and the data processing by stacking; Hanshamen keijo to jugo shori ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Matsushima, J.; Yokota, T.; Miyazaki, T. [Geological Survey of Japan, Tsukuba (Japan); Rokukawa, S. [The University of Tokyo, Tokyo (Japan). Faculty of Engineering

    1996-05-01

    An examination was made on the possibility of data processing by stacking with scattered waves assumed in a seismic exploration analysis (diffraction stacking method). In the examination, a CDP stacking method and the diffraction stacking method were compared through numerical experiments in the case of imaging a flat reflection surface and an irregular reflection surface. As a result, it was revealed that the CDP stacking method for stacking mirror reflection waves was merely a processing to raise S/N ratio while the diffraction stacking method for stacking with scattered waves assumed contained a migrational aspect as well as an aspect to raise S/N ratio. Consequently, it was shown that, if an oscillator was properly arranged, a structural imaging was possible not by the shape of a reflection surface but by the diffraction stacking method. Additionally, the diffraction stacking method revealed that the imaging effect varied by frequency with the stacking effect decreased at high frequencies, and that no stacking effect decreased at low frequencies but resolution lowered in horizontal direction. 4 refs., 8 figs.

  3. Nickel hydroxides and related materials: a review of their structures, synthesis and properties

    OpenAIRE

    Hall, David S.; Lockwood, David J.; Bock, Christina; MacDougall, Barry R.

    2015-01-01

    This review article summarizes the last few decades of research on nickel hydroxide, an important material in physics and chemistry, that has many applications in engineering including, significantly, batteries. First, the structures of the two known polymorphs, denoted as α-Ni(OH)2 and β-Ni(OH)2, are described. The various types of disorder, which are frequently present in nickel hydroxide materials, are discussed including hydration, stacking fault disorder, mechanical stresses and the inco...

  4. The interplay of structural and relational governance in innovation alliances

    NARCIS (Netherlands)

    Garbade, P.J.P.; Omta, S.W.F.; Fortuin, F.T.J.M.

    2016-01-01

    The present paper aims to extend the discussion in the governance literature about whether structural and relational governance mechanisms complement or substitute each other in innovation alliances. Where structural governance mechanisms refer to the division of tasks within the alliance and to

  5. Ion diffusion related to structure in molten salts

    International Nuclear Information System (INIS)

    Tosi, M.P.

    1996-08-01

    A model first developed by Zwanzig to derive transport coefficients in cold dense fluids directly from the Green-Kubo time correlation formulae allows one to relate macroscopic diffusion coefficients to the local fluid structure. Applications to various ionic diffusion processes in molten salts are reviewed. Consequences of partial structural quenching are also discussed. (author). 28 refs, 3 tabs

  6. Vertically stacked nanocellulose tactile sensor.

    Science.gov (United States)

    Jung, Minhyun; Kim, Kyungkwan; Kim, Bumjin; Lee, Kwang-Jae; Kang, Jae-Wook; Jeon, Sanghun

    2017-11-16

    Paper-based electronic devices are attracting considerable attention, because the paper platform has unique attributes such as flexibility and eco-friendliness. Here we report on what is claimed to be the firstly fully integrated vertically-stacked nanocellulose-based tactile sensor, which is capable of simultaneously sensing temperature and pressure. The pressure and temperature sensors are operated using different principles and are stacked vertically, thereby minimizing the interference effect. For the pressure sensor, which utilizes the piezoresistance principle under pressure, the conducting electrode was inkjet printed on the TEMPO-oxidized-nanocellulose patterned with micro-sized pyramids, and the counter electrode was placed on the nanocellulose film. The pressure sensor has a high sensitivity over a wide range (500 Pa-3 kPa) and a high durability of 10 4 loading/unloading cycles. The temperature sensor combines various materials such as poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS), silver nanoparticles (AgNPs) and carbon nanotubes (CNTs) to form a thermocouple on the upper nanocellulose layer. The thermoelectric-based temperature sensors generate a thermoelectric voltage output of 1.7 mV for a temperature difference of 125 K. Our 5 × 5 tactile sensor arrays show a fast response, negligible interference, and durable sensing performance.

  7. The measurement of power reactor stack releases under accident conditions

    International Nuclear Information System (INIS)

    Stroem, L.

    1989-01-01

    The performance of a typical Swedish monitor for ventilation stack radioactivity releases is examined critically with respect to accident generated radioactive particles. The conditions in the stack, particle character, and the monitor design are considered. A large LOCA outside the containment leads to high relative humidity, and high temperature, or mist in the stack. A small external LOCA results in a moderate increase in temperature and humidity, and condensing conditions only with reduced ventilation. Particle size and stickiness are estimated for different types of accident. A particle is sticky if it adheres after contact with a solid, smooth, dry, and clean surface. The monitor performance is concluded to be poor for large, sticky particles, like mist droplets. Dense aerosols, like fire smoke, will plug the sampling filter. Non-sticky particles are generally sampled with acceptable accuracy. (au)

  8. Generalized data stacking programming model with applications

    Directory of Open Access Journals (Sweden)

    Hala Samir Elhadidy

    2016-09-01

    Full Text Available Recent researches have shown that, everywhere in various sciences the systems are following stacked-based stored change behavior when subjected to events or varying environments “on and above” their normal situations. This paper presents a generalized data stack programming (GDSP model which is developed to describe the system changes under varying environment. These changes which are captured with different ways such as sensor reading are stored in matrices. Extraction algorithm and identification technique are proposed to extract the different layers between images and identify the stack class the object follows; respectively. The general multi-stacking network is presented including the interaction between various stack-based layering of some applications. The experiments prove that the concept of stack matrix gives average accuracy of 99.45%.

  9. Nickel hydroxides and related materials: a review of their structures, synthesis and properties

    Science.gov (United States)

    Hall, David S.; Lockwood, David J.; Bock, Christina; MacDougall, Barry R.

    2015-01-01

    This review article summarizes the last few decades of research on nickel hydroxide, an important material in physics and chemistry, that has many applications in engineering including, significantly, batteries. First, the structures of the two known polymorphs, denoted as α-Ni(OH)2 and β-Ni(OH)2, are described. The various types of disorder, which are frequently present in nickel hydroxide materials, are discussed including hydration, stacking fault disorder, mechanical stresses and the incorporation of ionic impurities. Several related materials are discussed, including intercalated α-derivatives and basic nickel salts. Next, a number of methods to prepare, or synthesize, nickel hydroxides are summarized, including chemical precipitation, electrochemical precipitation, sol–gel synthesis, chemical ageing, hydrothermal and solvothermal synthesis, electrochemical oxidation, microwave-assisted synthesis, and sonochemical methods. Finally, the known physical properties of the nickel hydroxides are reviewed, including their magnetic, vibrational, optical, electrical and mechanical properties. The last section in this paper is intended to serve as a summary of both the potentially useful properties of these materials and the methods for the identification and characterization of ‘unknown’ nickel hydroxide-based samples. PMID:25663812

  10. Sociology, social structure and health-related stigma.

    Science.gov (United States)

    Scambler, Graham

    2006-08-01

    There is a long and cross-disciplinary tradition of analysing chronic and disabling illness in terms of relations of stigma. The present paper offers a sociological approach which emphasizes: (a) the causal importance of social structures for grasping stigma relations; (b) the importance of understanding stigma relations in the context of wider societal change; and (c) the ways in which relations of stigma typically interact with other relations, such as those of class and command. It is suggested that consideration of specific and often condition-related strategies to reduce stigma might profitably be set in such a context.

  11. Flexural characteristics of a stack leg

    International Nuclear Information System (INIS)

    Cook, J.

    1979-06-01

    A 30 MV tandem Van de Graaff accelerator is at present under construction at Daresbury Laboratory. The insulating stack of the machine is of modular construction, each module being 860 mm in length. Each live section stack module contains 8 insulating legs mounted between bulkhead rings. The design, fabrication (from glass discs bonded to stainless steel discs using an epoxy film adhesive) and testing of the stack legs is described. (U.K.)

  12. Influence relative de la structure du texte sur la lisibilite (Relative Influence of the Structure of the Text on Readability).

    Science.gov (United States)

    Boyer, Jean-Yves

    A study investigated whether or not the global structure of a text influences its readability and how that influence might be related to the already recognized influences of vocabulary and sentence length. The subjects, 250 fourth-grade students in Quebec, each read four texts representing four different structures, four subjects, and two levels…

  13. Development of a Three Dimensional Neural Sensing Device by a Stacking Method

    Directory of Open Access Journals (Sweden)

    Chih-Wei Chang

    2010-04-01

    Full Text Available This study reports a new stacking method for assembling a 3-D microprobe array. To date, 3-D array structures have usually been assembled with vertical spacers, snap fasteners and a supporting platform. Such methods have achieved 3-D structures but suffer from complex assembly steps, vertical interconnection for 3-D signal transmission, low structure strength and large implantable opening. By applying the proposed stacking method, the previous techniques could be replaced by 2-D wire bonding. In this way, supporting platforms with slots and vertical spacers were no longer needed. Furthermore, ASIC chips can be substituted for the spacers in the stacked arrays to achieve system integration, design flexibility and volume usage efficiency. To avoid overflow of the adhesive fluid during assembly, an anti-overflow design which made use of capillary action force was applied in the stacking method as well. Moreover, presented stacking procedure consumes only 35 minutes in average for a 4 × 4 3-D microprobe array without requiring other specially made assembly tools. To summarize, the advantages of the proposed stacking method for 3-D array assembly include simplified assembly process, high structure strength, smaller opening area and integration ability with active circuits. This stacking assembly technique allows an alternative method to create 3-D structures from planar components.

  14. Plants with stacked genetically modified events: to assess or not to assess?

    DEFF Research Database (Denmark)

    Kok, Esther J.; Pedersen, Jan W.; Onori, Roberta

    2014-01-01

    of these differences relates to the so-called ‘stacked GM events’, that is, GMOs, plants so far, where new traits are combined by conventional crossing of different GM plants. This paper advocates rethinking the current food/feed safety assessment of stacked GM events in Europe based on an analysis of different...

  15. Principle of relative positioning of structures in the human body.

    Science.gov (United States)

    Meng, Buliang; Pang, Ailan; Li, Ming

    2013-03-25

    The arrangement of various biological structures should generally ensure the safety of crucial structures and increase their working efficiency; however, other principles governing the relative positions of structures in humans have not been reported. The present study therefore investigated other principles using nerves and their companion vessels in the human body as an example. Nerves and blood vessels usually travel together and in the most direct way towards their targets. Human embryology, histology, and gross anatomy suggest that there are many possible positions for these structures during development. However, for mechanical reasons, tougher or stronger structures should take priority. Nerves are tougher than most other structures, followed by arteries, veins, and lymphatic vessels. Nerves should therefore follow the most direct route, and be followed by the arteries, veins, and lymphatic vessels. This general principle should be applicable to all living things.

  16. Principle of relative positioning of structures in the human body☆

    Science.gov (United States)

    Meng, Buliang; Pang, Ailan; Li, Ming

    2013-01-01

    The arrangement of various biological structures should generally ensure the safety of crucial structures and increase their working efficiency; however, other principles governing the relative positions of structures in humans have not been reported. The present study therefore investigated other principles using nerves and their companion vessels in the human body as an example. Nerves and blood vessels usually travel together and in the most direct way towards their targets. Human embryology, histology, and gross anatomy suggest that there are many possible positions for these structures during development. However, for mechanical reasons, tougher or stronger structures should take priority. Nerves are tougher than most other structures, followed by arteries, veins, and lymphatic vessels. Nerves should therefore follow the most direct route, and be followed by the arteries, veins, and lymphatic vessels. This general principle should be applicable to all living things. PMID:25206733

  17. Simulation and Optimization of Air-Cooled PEMFC Stack for Lightweight Hybrid Vehicle Application

    Directory of Open Access Journals (Sweden)

    Jingming Liang

    2015-01-01

    Full Text Available A model of 2 kW air-cooled proton exchange membrane fuel cell (PEMFC stack has been built based upon the application of lightweight hybrid vehicle after analyzing the characteristics of heat transfer of the air-cooled stack. Different dissipating models of the air-cooled stack have been simulated and an optimal simulation model for air-cooled stack called convection heat transfer (CHT model has been figured out by applying the computational fluid dynamics (CFD software, based on which, the structure of the air-cooled stack has been optimized by adding irregular cooling fins at the end of the stack. According to the simulation result, the temperature of the stack has been equally distributed, reducing the cooling density and saving energy. Finally, the 2 kW hydrogen-air air-cooled PEMFC stack is manufactured and tested by comparing the simulation data which is to find out its operating regulations in order to further optimize its structure.

  18. Stacks of SPS Dipole Magnets

    CERN Multimedia

    1974-01-01

    Stacks of SPS Dipole Magnets ready for installation in the tunnel. The SPS uses a separated function lattice with dipoles for bending and quadrupoles for focusing. The 6.2 m long normal conducting dipoles are of H-type with coils that are bent-up at the ends. There are two types, B1 (total of 360) and B2 (384). Both are for a maximum field of 1.8 Tesla and have the same outer dimensions (450x800 mm2 vxh) but with different gaps (B1: 39x129 mm2, B2: 52x92 mm2) tailored to the beam size. The yoke, made of 1.5 mm thick laminations, consists of an upper and a lower half joined together in the median plane once the coils have been inserted.

  19. Stacked generalization: an introduction to super learning.

    Science.gov (United States)

    Naimi, Ashley I; Balzer, Laura B

    2018-04-10

    Stacked generalization is an ensemble method that allows researchers to combine several different prediction algorithms into one. Since its introduction in the early 1990s, the method has evolved several times into a host of methods among which is the "Super Learner". Super Learner uses V-fold cross-validation to build the optimal weighted combination of predictions from a library of candidate algorithms. Optimality is defined by a user-specified objective function, such as minimizing mean squared error or maximizing the area under the receiver operating characteristic curve. Although relatively simple in nature, use of Super Learner by epidemiologists has been hampered by limitations in understanding conceptual and technical details. We work step-by-step through two examples to illustrate concepts and address common concerns.

  20. Actuators Using Piezoelectric Stacks and Displacement Enhancers

    Science.gov (United States)

    Bar-Cohen, Yoseph; Sherrit, Stewart; Bao, Xiaoqi; Badescu, Mircea; Lee, Hyeong Jae; Walkenmeyer, Phillip; Lih, Shyh-Shiuh

    2015-01-01

    Actuators are used to drive all active mechanisms including machines, robots, and manipulators to name a few. The actuators are responsible for moving, manipulating, displacing, pushing and executing any action that is needed by the mechanism. There are many types and principles of actuation that are responsible for these movements ranging from electromagnetic, electroactive, thermo-mechanic, piezoelectric, electrostrictive etc. Actuators are readily available from commercial producers but there is a great need for reducing their size, increasing their efficiency and reducing their weight. Studies at JPL’s Non Destructive Evaluation and Advanced Actuators (NDEAA) Laboratory have been focused on the use of piezoelectric stacks and novel designs taking advantage of piezoelectric’s potential to provide high torque/force density actuation and high electromechanical conversion efficiency. The actuators/motors that have been developed and reviewed in this paper are operated by various horn configurations as well as the use of pre-stress flexures that make them thermally stable and increases their coupling efficiency. The use of monolithic designs that pre-stress the piezoelectric stack eliminates the use of compression stress bolt. These designs enable the embedding of developed solid-state motors/actuators in any structure with the only macroscopically moving parts are the rotor or the linear translator. Finite element modeling and design tools were used to determine the requirements and operation parameters and the results were used to simulate, design and fabricate novel actuators/motors. The developed actuators and performance will be described and discussed in this paper.

  1. Compact complex surfaces with geometric structures related to split quaternions

    International Nuclear Information System (INIS)

    Davidov, Johann; Grantcharov, Gueo; Mushkarov, Oleg; Yotov, Miroslav

    2012-01-01

    We study the problem of existence of geometric structures on compact complex surfaces that are related to split quaternions. These structures, called para-hypercomplex, para-hyperhermitian and para-hyperkähler, are analogs of the hypercomplex, hyperhermitian and hyperkähler structures in the definite case. We show that a compact 4-manifold carries a para-hyperkähler structure iff it has a metric of split signature together with two parallel, null, orthogonal, pointwise linearly independent vector fields. Every compact complex surface admitting a para-hyperhermitian structure has vanishing first Chern class and we show that, unlike the definite case, many of these surfaces carry infinite-dimensional families of such structures. We provide also compact examples of complex surfaces with para-hyperhermitian structures which are not locally conformally para-hyperkähler. Finally, we discuss the problem of non-existence of para-hyperhermitian structures on Inoue surfaces of type S 0 and provide a list of compact complex surfaces which could carry para-hypercomplex structures.

  2. Compact complex surfaces with geometric structures related to split quaternions

    Energy Technology Data Exchange (ETDEWEB)

    Davidov, Johann, E-mail: jtd@math.bas.bg [Institute of Mathematics and Informatics, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); ' L. Karavelov' Civil Engineering Higher School, 175 Suhodolska Str., 1373 Sofia (Bulgaria); Grantcharov, Gueo, E-mail: grantchg@fiu.edu [Department of Mathematics and Statistics, Florida International University, Miami, FL 33199 (United States); Mushkarov, Oleg, E-mail: muskarov@math.bas.bg [Institute of Mathematics and Informatics, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); Yotov, Miroslav, E-mail: yotovm@fiu.edu [Department of Mathematics and Statistics, Florida International University, Miami, FL 33199 (United States)

    2012-12-11

    We study the problem of existence of geometric structures on compact complex surfaces that are related to split quaternions. These structures, called para-hypercomplex, para-hyperhermitian and para-hyperkaehler, are analogs of the hypercomplex, hyperhermitian and hyperkaehler structures in the definite case. We show that a compact 4-manifold carries a para-hyperkaehler structure iff it has a metric of split signature together with two parallel, null, orthogonal, pointwise linearly independent vector fields. Every compact complex surface admitting a para-hyperhermitian structure has vanishing first Chern class and we show that, unlike the definite case, many of these surfaces carry infinite-dimensional families of such structures. We provide also compact examples of complex surfaces with para-hyperhermitian structures which are not locally conformally para-hyperkaehler. Finally, we discuss the problem of non-existence of para-hyperhermitian structures on Inoue surfaces of type S{sup 0} and provide a list of compact complex surfaces which could carry para-hypercomplex structures.

  3. Lithiation-induced shuffling of atomic stacks

    KAUST Repository

    Nie, Anmin

    2014-09-10

    In rechargeable lithium-ion batteries, understanding the atomic-scale mechanism of Li-induced structural evolution occurring at the host electrode materials provides essential knowledge for design of new high performance electrodes. Here, we report a new crystalline-crystalline phase transition mechanism in single-crystal Zn-Sb intermetallic nanowires upon lithiation. Using in situ transmission electron microscopy, we observed that stacks of atomic planes in an intermediate hexagonal (h-)LiZnSb phase are "shuffled" to accommodate the geometrical confinement stress arising from lamellar nanodomains intercalated by lithium ions. Such atomic rearrangement arises from the anisotropic lithium diffusion and is accompanied by appearance of partial dislocations. This transient structure mediates further phase transition from h-LiZnSb to cubic (c-)Li2ZnSb, which is associated with a nearly "zero-strain" coherent interface viewed along the [001]h/[111]c directions. This study provides new mechanistic insights into complex electrochemically driven crystalline-crystalline phase transitions in lithium-ion battery electrodes and represents a noble example of atomic-level structural and interfacial rearrangements.

  4. Stacking technology for a space constrained microsystem

    DEFF Research Database (Denmark)

    Heschel, Matthias; Kuhmann, Jochen Friedrich; Bouwstra, Siebe

    1998-01-01

    In this paper we present a stacking technology for an integrated packaging of an intelligent transducer which is formed by a micromachined silicon transducer and an integrated circuit chip. Transducer and circuitry are stacked on top of each other with an intermediate chip in between. The bonding...

  5. Vector Fields and Flows on Differentiable Stacks

    DEFF Research Database (Denmark)

    A. Hepworth, Richard

    2009-01-01

    This paper introduces the notions of vector field and flow on a general differentiable stack. Our main theorem states that the flow of a vector field on a compact proper differentiable stack exists and is unique up to a uniquely determined 2-cell. This extends the usual result on the existence...... of vector fields....

  6. 40 CFR 61.44 - Stack sampling.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Stack sampling. 61.44 Section 61.44 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL... Firing § 61.44 Stack sampling. (a) Sources subject to § 61.42(b) shall be continuously sampled, during...

  7. Learning OpenStack networking (Neutron)

    CERN Document Server

    Denton, James

    2014-01-01

    If you are an OpenStack-based cloud operator with experience in OpenStack Compute and nova-network but are new to Neutron networking, then this book is for you. Some networking experience is recommended, and a physical network infrastructure is required to provide connectivity to instances and other network resources configured in the book.

  8. Project W-420 stack monitoring system upgrades

    International Nuclear Information System (INIS)

    CARPENTER, K.E.

    1999-01-01

    This project will execute the design, procurement, construction, startup, and turnover activities for upgrades to the stack monitoring system on selected Tank Waste Remediation System (TWRS) ventilation systems. In this plan, the technical, schedule, and cost baselines are identified, and the roles and responsibilities of project participants are defined for managing the Stack Monitoring System Upgrades, Project W-420

  9. On the "stacking fault" in copper

    NARCIS (Netherlands)

    Fransens, J.R.; Pleiter, F

    2003-01-01

    The results of a perturbed gamma-gamma angular correlations experiment on In-111 implanted into a properly cut single crystal of copper show that the defect known in the literature as "stacking fault" is not a planar faulted loop but a stacking fault tetrahedron with a size of 10-50 Angstrom.

  10. Composition-structure-property relation of oxide glasses

    DEFF Research Database (Denmark)

    Hermansen, Christian

    also increases such properties. Yet, these rules are not strictly followed even for the simplest binary oxide glasses, such as alkali silicates, borates and phosphates. In this thesis it is argued that the missing link between composition and properties is the glass structure. Structural models...... are proposed based on topological selection rules and experimentally verified. The relation between structure and properties is evaluated using topological constraint theory, which in its essence is a theory that quantifies the two intuitions of the glass scientist. The end result is a quantitative model...

  11. Comparison of spatial harmonics in infinite and finite Bragg stacks for metamaterial homogenization

    DEFF Research Database (Denmark)

    Clausen, Niels Christian Jerichau; Arslanagic, Samel; Breinbjerg, Olav

    2014-01-01

    Metamaterial homogenization may be based on the dominance of a single Floquet-Bloch spatial harmonic in an infinite periodic structure - with the dominance quantified in terms of the relative magnitude of the associated spatial harmonic Poynting vector. For the corresponding finite structure...... the field is not quasi-periodic and cannot be expanded in Floquet-Bloch spatial harmonics; however, a set of pseudo spatial harmonics can be defined and the dominance of a single such harmonic likewise be used to determine whether the structure can be homogenized. For three different lossless Bragg stack...... configurations (one of which is magneto-dielectric), we show, using spectral representation, that the field in the finite structure can be accurately expanded in terms of these pseudo spatial harmonics and that the distribution of these agrees very well with the distribution of Floquet-Bloch spatial harmonics...

  12. Status of MCFC stack technology at IHI

    Energy Technology Data Exchange (ETDEWEB)

    Hosaka, M.; Morita, T.; Matsuyama, T.; Otsubo, M. [Ishikawajima-Harima Heavy Industries Co., Ltd., Tokyo (Japan)

    1996-12-31

    The molten carbonate fuel cell (MCFC) is a promising option for highly efficient power generation possible to enlarge. IHI has been studying parallel flow MCFC stacks with internal manifolds that have a large electrode area of 1m{sup 2}. IHI will make two 250 kW stacks for MW plant, and has begun to make cell components for the plant. To improve the stability of stack, soft corrugated plate used in the separator has been developed, and a way of gathering current from stacks has been studied. The DC output potential of the plant being very high, the design of electric insulation will be very important. A 20 kW short stack test was conducted in 1995 FY to certificate some of the improvements and components of the MW plant. These activities are presented below.

  13. One-Dimensional Stacking of Bifunctional Dithia- and Diselenadiazolyl Radicals : Preparation and Structural and Electronic Properties of 1,3-[(E2N2C)C6H4(CN2E2)] (E = S, Se)

    NARCIS (Netherlands)

    Andrews, M.P.; Douglass, D.C.; Fleming, R.M.; Glarum, S.H.; Haddon, R.C.; Marsh, P.; Oakley, R.T.; Palstra, T.T.M.; Schneemeyer, L.F.; Trucks, G.W.; Tycko, R.; Waszczak, J.V.; Young, K.M.; Zimmerman, N.M.; Cordes, A.W.

    1991-01-01

    The preparation and solid-state characterization of the 1,3-phenylene-bridged bis(dithiadiazolyl) and bis(diselenadiazolyl) diradicals 1,3-[(E2N2C)C6H4(CN2E2)] (E = S, Se) are reported. The isomorphous crystals of 1,3-[(E2N2C)C6H4(CN2E2)] so obtained are tetragonal, space group I41/a. Stacks of

  14. High Yield Chemical Vapor Deposition Growth of High Quality Large-Area AB Stacked Bilayer Graphene

    Science.gov (United States)

    Liu, Lixin; Zhou, Hailong; Cheng, Rui; Yu, Woo Jong; Liu, Yuan; Chen, Yu; Shaw, Jonathan; Zhong, Xing; Huang, Yu; Duan, Xiangfeng

    2012-01-01

    Bernal stacked (AB stacked) bilayer graphene is of significant interest for functional electronic and photonic devices due to the feasibility to continuously tune its band gap with a vertical electrical field. Mechanical exfoliation can be used to produce AB stacked bilayer graphene flakes but typically with the sizes limited to a few micrometers. Chemical vapor deposition (CVD) has been recently explored for the synthesis of bilayer graphene but usually with limited coverage and a mixture of AB and randomly stacked structures. Herein we report a rational approach to produce large-area high quality AB stacked bilayer graphene. We show that the self-limiting effect of graphene growth on Cu foil can be broken by using a high H2/CH4 ratio in a low pressure CVD process to enable the continued growth of bilayer graphene. A high temperature and low pressure nucleation step is found to be critical for the formation of bilayer graphene nuclei with high AB stacking ratio. A rational design of a two-step CVD process is developed for the growth of bilayer graphene with high AB stacking ratio (up to 90 %) and high coverage (up to 99 %). The electrical transport studies demonstrated that devices made of the as-grown bilayer graphene exhibit typical characteristics of AB stacked bilayer graphene with the highest carrier mobility exceeding 4,000 cm2/V·s at room temperature, comparable to that of the exfoliated bilayer graphene. PMID:22906199

  15. The impact of stack geometry and mean pressure on cold end temperature of stack in thermoacoustic refrigeration systems

    Science.gov (United States)

    Wantha, Channarong

    2018-02-01

    This paper reports on the experimental and simulation studies of the influence of stack geometries and different mean pressures on the cold end temperature of the stack in the thermoacoustic refrigeration system. The stack geometry was tested, including spiral stack, circular pore stack and pin array stack. The results of this study show that the mean pressure of the gas in the system has a significant impact on the cold end temperature of the stack. The mean pressure of the gas in the system corresponds to thermal penetration depth, which results in a better cold end temperature of the stack. The results also show that the cold end temperature of the pin array stack decreases more than that of the spiral stack and circular pore stack geometry by approximately 63% and 70%, respectively. In addition, the thermal area and viscous area of the stack are analyzed to explain the results of such temperatures of thermoacoustic stacks.

  16. The relation between forest structure and soil burn severity

    Science.gov (United States)

    Theresa B. Jain; Russell T. Graham; David S. Pilliod

    2006-01-01

    A study funded through National Fire Plan evaluates the relation between pre-wildfire forest structure and post-wildfire soil burn severity across three forest types: dry, moist, and cold forests. Over 73 wildfires were sampled in Idaho, Oregon, Montana, Colorado, and Utah, which burned between 2000 and 2003. Because of the study’s breadth, the results are applicable...

  17. Structure-rheology relations in sodium caseinate containing systems

    NARCIS (Netherlands)

    Ruis, H.G.M.

    2007-01-01

    The general aim of the work described in this thesis was to investigate structure-rheologyrelations for dairy related products, focusing on model systems containing sodium caseinate. The acid inducedgelationof sodium caseinate, of sodium caseinate

  18. Rain Sensor with Stacked Light Waveguide Having Tilted Air Gap

    Directory of Open Access Journals (Sweden)

    Kyoo Nam Choi

    2014-01-01

    Full Text Available Vehicle sensor to detect rain drop on and above waveguide utilizing light deflection and scattering was realized, keeping wide sensing coverage and sensitivity to detect mist accumulation. Proposed sensor structure under stacked light wave guide consisted of light blocking fixture surrounding photodetector and adjacent light source. Tilted air gap between stacked light waveguide and light blocking fixture played major role to increase sensitivity and to enhance linearity. This sensor structure eliminated complex collimating optics, while keeping wide sensing coverage using simple geometry. Detection algorithm based on time-to-intensity transformation process was used to convert raining intensity into countable raining process. Experimental result inside simulated rain chamber showed distinct different response between light rain and normal rain. Application as automobile rain sensor is expected.

  19. Structural studies of human glioma pathogenesis-related protein 1

    Energy Technology Data Exchange (ETDEWEB)

    Asojo, Oluwatoyin A., E-mail: oasojo@unmc.edu [College of Medicine, Nebraska Medical Center, Omaha, NE 68198-6495 (United States); Koski, Raymond A.; Bonafé, Nathalie [L2 Diagnostics LLC, 300 George Street, New Haven, CT 06511 (United States); College of Medicine, Nebraska Medical Center, Omaha, NE 68198-6495 (United States)

    2011-10-01

    Structural analysis of a truncated soluble domain of human glioma pathogenesis-related protein 1, a membrane protein implicated in the proliferation of aggressive brain cancer, is presented. Human glioma pathogenesis-related protein 1 (GLIPR1) is a membrane protein that is highly upregulated in brain cancers but is barely detectable in normal brain tissue. GLIPR1 is composed of a signal peptide that directs its secretion, a conserved cysteine-rich CAP (cysteine-rich secretory proteins, antigen 5 and pathogenesis-related 1 proteins) domain and a transmembrane domain. GLIPR1 is currently being investigated as a candidate for prostate cancer gene therapy and for glioblastoma targeted therapy. Crystal structures of a truncated soluble domain of the human GLIPR1 protein (sGLIPR1) solved by molecular replacement using a truncated polyalanine search model of the CAP domain of stecrisp, a snake-venom cysteine-rich secretory protein (CRISP), are presented. The correct molecular-replacement solution could only be obtained by removing all loops from the search model. The native structure was refined to 1.85 Å resolution and that of a Zn{sup 2+} complex was refined to 2.2 Å resolution. The latter structure revealed that the putative binding cavity coordinates Zn{sup 2+} similarly to snake-venom CRISPs, which are involved in Zn{sup 2+}-dependent mechanisms of inflammatory modulation. Both sGLIPR1 structures have extensive flexible loop/turn regions and unique charge distributions that were not observed in any of the previously reported CAP protein structures. A model is also proposed for the structure of full-length membrane-bound GLIPR1.

  20. Seismic fragility of ventilation stack of nuclear power plant

    International Nuclear Information System (INIS)

    Nefedov, S.S.; Yugai, T.Z.; Kalinkin, I.V.; Vizir, P.L.

    2003-01-01

    Fragility study of safety related elements is necessary step in seismic PSA of nuclear power plant (NPP). In present work fragility was analyzed after the example of the ventilation stack of NPP. Ventilation stack, considered in present work, is a separately erected construction with height of 100 m made of cast-in-place reinforced concrete. In accordance with IAEA terminology fragility of element is defined as conditional probability of its failure at given level of seismic loading. Failure of a ventilation stack was considered as development of the plastic hinge in some section of a shaft. Seismic ground acceleration a, which corresponds to failure, could be defined as limit seismic acceleration of ventilation stack [a]. Limit seismic acceleration [a] was considered as random value. Sources of its variation are connected with stochastic nature of factors determining it (properties of construction materials, soils etc.), and also with uncertainties of existing analytical techniques. Random value [a] was assumed to be distributed lognormally. Median m[a] and logarithmically standard deviation β of this distribution were defined by 'scaling method' developed by R.P. Kennedy et al. Using this values fragility curves were plotted for different levels of confidence probability. (author)

  1. Some important results from the air pollution distribution model STACKS (1988-1992)

    International Nuclear Information System (INIS)

    Erbrink, J.J.

    1993-01-01

    Attention is paid to the results of the study on the distribution of air pollutants by high chimney-stacks of electric power plants. An important product of the study is the integrated distribution model STACKS (Short Term Air-pollutant Concentrations Kema modelling System). The improvements and the extensions of STACKS are described in relation to the National Model, which has been used to estimate the environmental effects of individual chimney-stacks. The National Model shows unacceptable variations for high pollutant sources. Based on the results of STACKS revision of the National model has been taken into consideration. By means of the revised National Model a more realistic estimation of the environmental effects of electric power plants can be carried out

  2. Reliability of containment and safety-related structures

    International Nuclear Information System (INIS)

    Nessim, M.A.

    1995-09-01

    A research program on Reliability of Containment and Safety-related Structures has been developed and is described in this document. This program is designed to support AECB's regulatory activities aimed at ensuring the safety of these structures. These activities include evaluating submissions by operators and requesting special assessments when necessary. The results of the proposed research will also be useful in revising and enhancing the CSA design standards for containment and safety-related structures. The process of developing the research program started with an information collection and review phase. The sources of information included C-FER's previous work in the area, various recent research publications, regulatory documents and relevant design standards, and a detailed discussion with AECB staff. The second step was to outline the process of reliability evaluation, and identify the required models and parameters. Comparison between the required and available information was used to identify gaps in the state-of-the-art, and the research program was designed to fill these gaps. The program is organized in four major topics, namely: development of an approach for reliability analysis; compilation and development of the required analysis tools; application to specific problems related to design, assessment, maintenance and testing of structures; and testing and validation. It is suggested that the program should be supported by an on-going process of communication and consultation between AECB staff and industry experts. This will lend credibility to the results and facilitate their future application. (author). 1 fig

  3. Tunable electro-optic filter stack

    Energy Technology Data Exchange (ETDEWEB)

    Fontecchio, Adam K.; Shriyan, Sameet K.; Bellingham, Alyssa

    2017-09-05

    A holographic polymer dispersed liquid crystal (HPDLC) tunable filter exhibits switching times of no more than 20 microseconds. The HPDLC tunable filter can be utilized in a variety of applications. An HPDLC tunable filter stack can be utilized in a hyperspectral imaging system capable of spectrally multiplexing hyperspectral imaging data acquired while the hyperspectral imaging system is airborne. HPDLC tunable filter stacks can be utilized in high speed switchable optical shielding systems, for example as a coating for a visor or an aircraft canopy. These HPDLC tunable filter stacks can be fabricated using a spin coating apparatus and associated fabrication methods.

  4. Dynamical stability of slip-stacking particles

    Energy Technology Data Exchange (ETDEWEB)

    Eldred, Jeffrey; Zwaska, Robert

    2014-09-01

    We study the stability of particles in slip-stacking configuration, used to nearly double proton beam intensity at Fermilab. We introduce universal area factors to calculate the available phase space area for any set of beam parameters without individual simulation. We find perturbative solutions for stable particle trajectories. We establish Booster beam quality requirements to achieve 97% slip-stacking efficiency. We show that slip-stacking dynamics directly correspond to the driven pendulum and to the system of two standing-wave traps moving with respect to each other.

  5. Graphite structure and its relation to mechanical engineering design

    International Nuclear Information System (INIS)

    Brocklehurst, J.E.; Kelly, B.T.

    1980-01-01

    The inhomogeneous nature of polycrystalline graphite requires property measurements to be made over dimensions large enough to average the local variations in the structure. This is particularly true for mechanical integrity, and experimental data are presented which illustrate the importance of the real aggregate structure of graphite and the difficulties of interpreting strength data from different tests. The classical statistical treatments do not hold generally, and the problem of defining a failure criterion for graphite is discussed. It is suggested that the stress conditions in graphite components might be classified in terms of the dimensions and stress gradients related to the characteristic flaw size of the material as determined experimentally. (author)

  6. Stacking faults in austempered ductile iron

    Energy Technology Data Exchange (ETDEWEB)

    Hermida, J.D. [CNEA, San Martin (Argentina). Dept. de Materiales

    1996-06-01

    During last decade, Austempered Ductile Iron (ADI) has been successfully used as an acceptable replacement material for steel in many applications, due to the relatively high strength and reasonable ductility obtained. These properties are the result of the special microstructure exhibited by this material at the end of the upper bainite reaction: ferrite platelets surrounded by high carbon stabilized austenite. However, at the beginning of the austempering treatment, the existence of interdendritic low carbon austenite is revealed by its transformation to martensite when cooling the sample or during subsequent deformation. The completion of the upper bainite reaction is of decisive importance to mechanical properties because the remaining martensite reduces ductility. It was observed that the rate of the upper bainite reaction is governed by the carbon content difference between the low and high carbon austenites. The carbon content is obtained by the lattice parameter measurement, because there exists a known expression that relates both magnitudes. Several works have used X-ray diffraction to measure the lattice parameter and phase concentrations as a function of austempering time. In these works, the lattice parameters were obtained directly from the {l_brace}220{r_brace} and {l_brace}311{r_brace} peaks position. The purpose of this work is to show more precise lattice parameters measurement and, very closely related to this, the existence of stacking faults in austenite, even at times within the processing window.

  7. Air-Cooled Stack Freeze Tolerance Freeze Failure Modes and Freeze Tolerance Strategies for GenDriveTM Material Handling Application Systems and Stacks Final Scientific Report

    Energy Technology Data Exchange (ETDEWEB)

    Hancock, David, W.

    2012-02-14

    Air-cooled stack technology offers the potential for a simpler system architecture (versus liquid-cooled) for applications below 4 kilowatts. The combined cooling and cathode air allows for a reduction in part count and hence a lower cost solution. However, efficient heat rejection challenges escalate as power and ambient temperature increase. For applications in ambient temperatures below freezing, the air-cooled approach has additional challenges associated with not overcooling the fuel cell stack. The focus of this project was freeze tolerance while maintaining all other stack and system requirements. Through this project, Plug Power advanced the state of the art in technology for air-cooled PEM fuel cell stacks and related GenDrive material handling application fuel cell systems. This was accomplished through a collaborative work plan to improve freeze tolerance and mitigate freeze-thaw effect failure modes within innovative material handling equipment fuel cell systems designed for use in freezer forklift applications. Freeze tolerance remains an area where additional research and understanding can help fuel cells to become commercially viable. This project evaluated both stack level and system level solutions to improve fuel cell stack freeze tolerance. At this time, the most cost effective solutions are at the system level. The freeze mitigation strategies developed over the course of this project could be used to drive fuel cell commercialization. The fuel cell system studied in this project was Plug Power's commercially available GenDrive platform providing battery replacement for equipment in the material handling industry. The fuel cell stacks were Ballard's commercially available FCvelocity 9SSL (9SSL) liquid-cooled PEM fuel cell stack and FCvelocity 1020ACS (Mk1020) air-cooled PEM fuel cell stack.

  8. Structure-Based Alignment and Consensus Secondary Structures for Three HIV-Related RNA Genomes.

    Science.gov (United States)

    Lavender, Christopher A; Gorelick, Robert J; Weeks, Kevin M

    2015-05-01

    HIV and related primate lentiviruses possess single-stranded RNA genomes. Multiple regions of these genomes participate in critical steps in the viral replication cycle, and the functions of many RNA elements are dependent on the formation of defined structures. The structures of these elements are still not fully understood, and additional functional elements likely exist that have not been identified. In this work, we compared three full-length HIV-related viral genomes: HIV-1NL4-3, SIVcpz, and SIVmac (the latter two strains are progenitors for all HIV-1 and HIV-2 strains, respectively). Model-free RNA structure comparisons were performed using whole-genome structure information experimentally derived from nucleotide-resolution SHAPE reactivities. Consensus secondary structures were constructed for strongly correlated regions by taking into account both SHAPE probing structural data and nucleotide covariation information from structure-based alignments. In these consensus models, all known functional RNA elements were recapitulated with high accuracy. In addition, we identified multiple previously unannotated structural elements in the HIV-1 genome likely to function in translation, splicing and other replication cycle processes; these are compelling targets for future functional analyses. The structure-informed alignment strategy developed here will be broadly useful for efficient RNA motif discovery.

  9. Strontium titanate/silicon-based terahertz photonic crystal multilayer stack

    Energy Technology Data Exchange (ETDEWEB)

    Xin, J.Z.; Jim, K.L.; Tsang, Y.H.; Chan, H.L.W.; Leung, C.W. [Hong Kong Polytechnic University, Department of Applied Physics and Materials Research Centre, Kowloon, Hong Kong (China); Yang, J.; Gong, X.J.; Chen, L.Q.; Gao, F. [Chinese Academy of Sciences, Institute of Biomedical and Health Engineering, Shenzhen Institutes of Advanced Technology, Shenzhen (China)

    2012-04-15

    A one-dimensional photonic crystal working in the terahertz (THz) range was designed and implemented. To facilitate the design, the transmission properties of strontium titanate crystals were characterized by THz-time-domain spectroscopy. Relatively high refractive index ({proportional_to}18.5) and transmission ratio (0.08) were observed between 0.2 to 1 THz. A stacked structure of (Si d{sub Si}/STO d{sub STO}){sub N} /Si d{sub Si} was then designed, with transmission spectra calculated by the transfer matrix method. The effects of the filling ratio (d{sub STO}/(d{sub Si}+d{sub STO})), periodicity (d{sub Si}+d{sub STO}) and the number of repeats N on the transmission of PC were investigated. The effect of introducing a defect layer was also studied. Based on these, Si/STO multilayers with STO defect thickness of 125 {mu}m and 200 {mu}m were measured. The shift of the defect mode was observed and compared with the calculations. (orig.)

  10. Study of interfaces and band offsets in TiN/amorphous LaLuO3 gate stacks

    KAUST Repository

    Mitrovic, Ivona Z.

    2011-07-01

    TiN/LaLuO3 (LLO) gate stacks formed by molecular beam deposition have been investigated by X-ray photoelectron spectroscopy, medium energy ion scattering, spectroscopic ellipsometry, scanning transmission electron microscopy, electron energy loss spectroscopy and atomic force microscopy. The results indicate an amorphous structure for deposited LLO films. The band offset between the Fermi level of TiN and valence band of LLO is estimated to be 2.65 ± 0.05 eV. A weaker La-O-Lu bond and a prominent Ti2p sub-peak which relates to Ti bond to interstitial oxygen have been identified for an ultra-thin 1.7 nm TiN/3 nm LLO gate stack. The angle-dependent XPS analysis of Si2s spectra as well as shifts of La4d, La3d and Lu4d core levels suggests a silicate-type with Si-rich SiOx LLO/Si interface. Symmetrical valence and conduction band offsets for LLO to Si of 2.2 eV and the bandgap of 5.5 ± 0.1 eV have been derived from the measurements. The band alignment for ultra-thin TiN/LLO gate stack is affected by structural changes. Copyright © 2011 Published by Elsevier B.V. All rights reserved.

  11. Chemical and physical structures of proteinoids and related polyamino acids

    Science.gov (United States)

    Mita, Hajime; Kuwahara, Yusuke; Nomoto, Shinya

    Studies of polyamino acid formation pathways in the prebiotic condition are important for the study of the origins of life. Several pathways of prebiotic polyamino acid formation have been reported. Heating of monoammonium malate [1] and heating of amino acids in molten urea [2] are important pathways of the prebiotic peptide formation. The former case, globular structure called proteinoid microsphere is formed in aqueous conditions. The later case, polyamino acids are formed from unrestricted amino acid species. Heating of aqueous aspargine is also interesting pathway for the prebiotic polyamino acid formation, because polyamino acid formation proceeds in aqueous condition [3]. In this study, we analyzed the chemical structure of the proteinoids and related polyamino acids formed in the above three pathways using with mass spectrometer. In addition, their physical structures are analyzed by the electron and optical microscopes, in order to determine the self-organization abilities. We discuss the relation between the chemical and the physical structures for the origins of life. References [1] Harada, K., J. Org. Chem., 24, 1662 (1959), Fox, S. W., Harada, K., and Kendrick, J., Science, 129, 1221 (1959). [2] Terasaki, M., Nomoto, S., Mita, H., and Shimoyama, A., Chem. Lett., 480 (2002), Mita, H., Nomoto, S., Terasaki, M., Shimoyama, A., and Yamamoto, Y., Int. J. Astrobiol., 4, 145 (2005). [3] Kovacs, K and Nagy, H., Nature, 190, 531 (1961), Munegumi, T., Tanikawa, N., Mita, H. and Harada, K., Viva Origino, 22, 109 (1994).

  12. Labour-Related Structural Trends in South African Maize Production

    OpenAIRE

    Zyl, J. Van; Vink, Nick; Fenyes, T. I.

    1987-01-01

    The substitution of capital goods, including new technology, for land and labour has played an important role and has influenced the structure of Sout African agriculture. Farm labour-related trends in the summer rainfall grain-producing area of South Africa are considered. The amount of labour used, the remuneration of labour, the substitution of capital for labour and productivity trends are analyzed. Growth rates were obtained by fitting exponential functions with time as independent varia...

  13. Aquatic photochemical kinetics of benzotriazole and structurally related compounds

    OpenAIRE

    Janssen Elisabeth M. L.; Marron Emily; McNeill Kristopher

    2015-01-01

    Benzotriazole corrosion inhibitors are not completely removed during wastewater treatment and are frequently detected in surface waters. Here the photochemical kinetics of benzotriazoles and structurally related compounds were assessed for natural aqueous environments. The direct photochemical half lives during exposure to simulated sunlight ranged from 1.3 to 1.8 days for benzotriazole and its derivatives (4 methyl 5 methyl 4 hydroxy substituted benzotriazoles). Benzotriazole is more resis...

  14. Wearable solar cells by stacking textile electrodes.

    Science.gov (United States)

    Pan, Shaowu; Yang, Zhibin; Chen, Peining; Deng, Jue; Li, Houpu; Peng, Huisheng

    2014-06-10

    A new and general method to produce flexible, wearable dye-sensitized solar cell (DSC) textiles by the stacking of two textile electrodes has been developed. A metal-textile electrode that was made from micrometer-sized metal wires was used as a working electrode, while the textile counter electrode was woven from highly aligned carbon nanotube fibers with high mechanical strengths and electrical conductivities. The resulting DSC textile exhibited a high energy conversion efficiency that was well maintained under bending. Compared with the woven DSC textiles that are based on wire-shaped devices, this stacked DSC textile unexpectedly exhibited a unique deformation from a rectangle to a parallelogram, which is highly desired in portable electronics. This lightweight and wearable stacked DSC textile is superior to conventional planar DSCs because the energy conversion efficiency of the stacked DSC textile was independent of the angle of incident light. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. STACKING FAULT ENERGY IN HIGH MANGANESE ALLOYS

    Directory of Open Access Journals (Sweden)

    Eva Mazancová

    2009-04-01

    Full Text Available Stacking fault energy of high manganese alloys (marked as TWIP and TRIPLEX is an important parameter determining deformation mechanism type realized in above mentioned alloys. Stacking fault energy level can be asserted with a gliding of partial and/or full dislocations, b gliding mechanism and twinning deformation process in connection with increasing of fracture deformation level (deformation elongation and with increasing of simultaneously realized work hardening proces., c gliding mechanism and deformation induced e-martensite formation. In contribution calculated stacking fault energies are presented for various chemical compositions of high manganese alloys. Stacking fault energy dependences on manganese, carbon, iron and alluminium contents are presented. Results are confronted with some accessible papers.The aim of work is to deepen knowledge of presented data. The TWIP and TRIPLEX alloys can be held for promissing new automotive materials.

  16. Stack-Based Typed Assembly Language

    National Research Council Canada - National Science Library

    Morrisett, Greg

    1998-01-01

    .... This paper also formalizes the typing connection between CPS based compilation and stack based compilation and illustrates how STAL can formally model calling conventions by specifying them as formal translations of source function types to STAL types.

  17. Characterization of Piezoelectric Stacks for Space Applications

    Science.gov (United States)

    Sherrit, Stewart; Jones, Christopher; Aldrich, Jack; Blodget, Chad; Bao, Xiaoqi; Badescu, Mircea; Bar-Cohen, Yoseph

    2008-01-01

    Future NASA missions are increasingly seeking to actuate mechanisms to precision levels in the nanometer range and below. Co-fired multilayer piezoelectric stacks offer the required actuation precision that is needed for such mechanisms. To obtain performance statistics and determine reliability for extended use, sets of commercial PZT stacks were tested in various AC and DC conditions at both nominal and high temperatures and voltages. In order to study the lifetime performance of these stacks, five actuators were driven sinusoidally for up to ten billion cycles. An automated data acquisition system was developed and implemented to monitor each stack's electrical current and voltage waveforms over the life of the test. As part of the monitoring tests, the displacement, impedance, capacitance and leakage current were measured to assess the operation degradation. This paper presents some of the results of this effort.

  18. The stack on software and sovereignty

    CERN Document Server

    Bratton, Benjamin H

    2016-01-01

    A comprehensive political and design theory of planetary-scale computation proposing that The Stack -- an accidental megastructure -- is both a technological apparatus and a model for a new geopolitical architecture.

  19. Stacking for Cosmic Magnetism with SKA Surveys

    OpenAIRE

    Stil, J. M.; Keller, B. W.

    2015-01-01

    Stacking polarized radio emission in SKA surveys provides statistical information on large samples that is not accessible otherwise due to limitations in sensitivity, source statistics in small fields, and averaging over frequency (including Faraday synthesis). Polarization is a special case because one obvious source of stacking targets is the Stokes I source catalog, possibly in combination with external catalogs, for example an SKA HI survey or a non-radio survey. We point out the signific...

  20. Environmental Modeling Framework using Stacked Gaussian Processes

    OpenAIRE

    Abdelfatah, Kareem; Bao, Junshu; Terejanu, Gabriel

    2016-01-01

    A network of independently trained Gaussian processes (StackedGP) is introduced to obtain predictions of quantities of interest with quantified uncertainties. The main applications of the StackedGP framework are to integrate different datasets through model composition, enhance predictions of quantities of interest through a cascade of intermediate predictions, and to propagate uncertainties through emulated dynamical systems driven by uncertain forcing variables. By using analytical first an...

  1. Generalized data stacking programming model with applications

    OpenAIRE

    Hala Samir Elhadidy; Rawya Yehia Rizk; Hassen Taher Dorrah

    2016-01-01

    Recent researches have shown that, everywhere in various sciences the systems are following stacked-based stored change behavior when subjected to events or varying environments “on and above” their normal situations. This paper presents a generalized data stack programming (GDSP) model which is developed to describe the system changes under varying environment. These changes which are captured with different ways such as sensor reading are stored in matrices. Extraction algorithm and identif...

  2. Representations of stack triangulations in the plane

    OpenAIRE

    Selig, Thomas

    2013-01-01

    Stack triangulations appear as natural objects when defining an increasing family of triangulations by successive additions of vertices. We consider two different probability distributions for such objects. We represent, or "draw" these random stack triangulations in the plane $\\R^2$ and study the asymptotic properties of these drawings, viewed as random compact metric spaces. We also look at the occupation measure of the vertices, and show that for these two distributions it converges to som...

  3. Preparative separation and structural identification of impurities of a new α{sub 2}-Adrenoceptor agonist using stacking injection, LC-MS{sup n} and LC-SPE-NMR

    Energy Technology Data Exchange (ETDEWEB)

    Cardoso, Josiane O.; Thomasi, Sérgio S.; Venâncio, Tiago; Oliveira, Regina V., E-mail: oliveirarv@ufscar.br [Universidade Federal de São Carlos (UFSCar), SP (Brazil). Departamento de Química; Pitta, Ivan R.; Lima, Maria do Carmo A. de [Universidade Federal de Pernambuco (NUPIT/UFPE), Recife, PE (Brazil). Núcleo de Pesquisa em Inovação Tecnológica

    2017-07-01

    Identifying impurities in drug substances has become one of the most important issues in pharmaceutical analysis since it can have a significant impact on the efficacy of new pharmaceutical products. Due to the purity requirements, in this paper a new synthetic α{sub 2}-adrenoceptor agonist, called LPSF-PT-31, was purified and its impurities were characterized by liquid chromatography multistage mass spectrometry (LC-MS{sup n}) and liquid chromatography-solid phase extraction-nuclear magnetic resonance (LC-SPE-NMR). The purification step was conducted using a semi-preparative liquid chromatography and stacked injections as a new approach to drug purification. As a result, a total yield of 75% of the pure LPSF-PT-31 and 2.9 L day{sup -}'1 in solvent reduction was obtained. The combination of semi-preparative stacking injection, LC-MS{sup n}, and LC-SPE-NMR, demonstrated to be efficient to purify active drugs and unambiguously identify its impurities. In addition, isolation and identification of drug impurities in the early stages of development can improve the synthetic pathway, preventing the formation of impurities or minimizing this formation to minimum levels. (author)

  4. A Time-predictable Stack Cache

    DEFF Research Database (Denmark)

    Abbaspour, Sahar; Brandner, Florian; Schoeberl, Martin

    2013-01-01

    Real-time systems need time-predictable architectures to support static worst-case execution time (WCET) analysis. One architectural feature, the data cache, is hard to analyze when different data areas (e.g., heap allocated and stack allocated data) share the same cache. This sharing leads to le...... of a cache for stack allocated data. Our port of the LLVM C++ compiler supports the management of the stack cache. The combination of stack cache instructions and the hardware implementation of the stack cache is a further step towards timepredictable architectures.......Real-time systems need time-predictable architectures to support static worst-case execution time (WCET) analysis. One architectural feature, the data cache, is hard to analyze when different data areas (e.g., heap allocated and stack allocated data) share the same cache. This sharing leads to less...... precise results of the cache analysis part of the WCET analysis. Splitting the data cache for different data areas enables composable data cache analysis. The WCET analysis tool can analyze the accesses to these different data areas independently. In this paper we present the design and implementation...

  5. Detailed Electrochemical Characterisation of Large SOFC Stacks

    DEFF Research Database (Denmark)

    Mosbæk, Rasmus Rode; Hjelm, Johan; Barfod, R.

    2012-01-01

    As solid oxide fuel cell (SOFC) technology is moving closer to a commercial break through, lifetime limiting factors, determination of the limits of safe operation and methods to measure the “state-of-health” of operating cells and stacks are becoming of increasing interest. This requires applica...... out at a range of ac perturbation amplitudes in order to investigate linearity of the response and the signal-to-noise ratio. Separation of the measured impedance into series and polarisation resistances was possible....... to analyse in detail. Today one is forced to use mathematical modelling to extract information about existing gradients and cell resistances in operating stacks, as mature techniques for local probing are not available. This type of spatially resolved information is essential for model refinement...... and validation, and helps to further the technological stack development. Further, more detailed information obtained from operating stacks is essential for developing appropriate process monitoring and control protocols for stack and system developers. An experimental stack with low ohmic resistance from Topsoe...

  6. Tables of formulae for calculating the mechanics of stacks in gas-graphite reactors; Formulaire pour le calcul de la mecanique des empilements des reacteurs graphite-gaz

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1968-07-01

    This collection of formulae only gives, for nuclear graphite stacks. The mechanical effects due to the strains, thermal or not, of steel structures supporting or surrounding graphite blocks. Equations have been established by mean of experiments made at Chinon with large pile models. Thus, it is possible to calculate displacement, strain and stress in the EDF type stacks of horizontal triangular block lattice. (authors) [French] Le domaine de ce formulaire est strictement limite aux effets mecaniques, pour les empilements, des deformations, thermiques ou autres, des structures metalliques de soutien (aire - support et corset). On propose un ensemble de relations qui ont ete etablies a la suite des essais de CHINON sur des maquettes de grande taille. Ces relations permettent le calcul des mouvements, des deformations et des contraintes dans les empilements du type EDF, a reseau horizontal triangulaire regulier. (auteurs)

  7. Elucidation of Operon Structures across Closely Related Bacterial Genomes

    Science.gov (United States)

    Li, Guojun

    2014-01-01

    About half of the protein-coding genes in prokaryotic genomes are organized into operons to facilitate co-regulation during transcription. With the evolution of genomes, operon structures are undergoing changes which could coordinate diverse gene expression patterns in response to various stimuli during the life cycle of a bacterial cell. Here we developed a graph-based model to elucidate the diversity of operon structures across a set of closely related bacterial genomes. In the constructed graph, each node represents one orthologous gene group (OGG) and a pair of nodes will be connected if any two genes, from the corresponding two OGGs respectively, are located in the same operon as immediate neighbors in any of the considered genomes. Through identifying the connected components in the above graph, we found that genes in a connected component are likely to be functionally related and these identified components tend to form treelike topology, such as paths and stars, corresponding to different biological mechanisms in transcriptional regulation as follows. Specifically, (i) a path-structure component integrates genes encoding a protein complex, such as ribosome; and (ii) a star-structure component not only groups related genes together, but also reflects the key functional roles of the central node of this component, such as the ABC transporter with a transporter permease and substrate-binding proteins surrounding it. Most interestingly, the genes from organisms with highly diverse living environments, i.e., biomass degraders and animal pathogens of clostridia in our study, can be clearly classified into different topological groups on some connected components. PMID:24959722

  8. Elucidation of operon structures across closely related bacterial genomes.

    Science.gov (United States)

    Zhou, Chuan; Ma, Qin; Li, Guojun

    2014-01-01

    About half of the protein-coding genes in prokaryotic genomes are organized into operons to facilitate co-regulation during transcription. With the evolution of genomes, operon structures are undergoing changes which could coordinate diverse gene expression patterns in response to various stimuli during the life cycle of a bacterial cell. Here we developed a graph-based model to elucidate the diversity of operon structures across a set of closely related bacterial genomes. In the constructed graph, each node represents one orthologous gene group (OGG) and a pair of nodes will be connected if any two genes, from the corresponding two OGGs respectively, are located in the same operon as immediate neighbors in any of the considered genomes. Through identifying the connected components in the above graph, we found that genes in a connected component are likely to be functionally related and these identified components tend to form treelike topology, such as paths and stars, corresponding to different biological mechanisms in transcriptional regulation as follows. Specifically, (i) a path-structure component integrates genes encoding a protein complex, such as ribosome; and (ii) a star-structure component not only groups related genes together, but also reflects the key functional roles of the central node of this component, such as the ABC transporter with a transporter permease and substrate-binding proteins surrounding it. Most interestingly, the genes from organisms with highly diverse living environments, i.e., biomass degraders and animal pathogens of clostridia in our study, can be clearly classified into different topological groups on some connected components.

  9. Tables of formulae for calculating the mechanics of stacks in gas-graphite reactors

    International Nuclear Information System (INIS)

    1968-01-01

    This collection of formulae only gives, for nuclear graphite stacks. The mechanical effects due to the strains, thermal or not, of steel structures supporting or surrounding graphite blocks. Equations have been established by mean of experiments made at Chinon with large pile models. Thus, it is possible to calculate displacement, strain and stress in the EDF type stacks of horizontal triangular block lattice. (authors) [fr

  10. Parametric Sensitivity Tests- European PEM Fuel Cell Stack Test Procedures

    DEFF Research Database (Denmark)

    Araya, Samuel Simon; Andreasen, Søren Juhl; Kær, Søren Knudsen

    2014-01-01

    performed based on test procedures proposed by a European project, Stack-Test. The sensitivity of a Nafion-based low temperature PEMFC stack’s performance to parametric changes was the main objective of the tests. Four crucial parameters for fuel cell operation were chosen; relative humidity, temperature......, pressure, and stoichiometry at varying current density. Furthermore, procedures for polarization curve recording were also tested both in ascending and descending current directions....

  11. A new method to determine earthquake depth: stacking multiple-station autocorrelogram

    Science.gov (United States)

    Zhang, M.; Tian, D.; Wen, L.

    2013-12-01

    Accurate determination of source depth of the earthquakes in the crust is still challenging, because of our imperfect knowledge of velocity structure and unclear depth phase of the earthquakes. We develop a new method to determine earthquake source depth, based on stacking multiple-station autocorrelogram (SMAC). We determine source depth using both direct SH wave and its coda. In coda wave interferometry, the stacking of the cross-correlograms of two earthquake coda can be treated as the Green's function from one earthquake to the other. The stacking of the autocorrelograms of an earthquake coda can thus be treated as the Green's function from the earthquake to itself. By stacking autocorrelograms of SH wave coda recorded at each station, we retrieve the surface reflection from the source and back to the source, which is used to determine the source depth. In the stacking of direct wave autocorrelograms, the time difference between the surface reflection and the main wave would depend on source depth, Moho depth and epicentral distance. We derive travel time difference between the surface reflection and the main SH wave by grid-searching those parameters. The autocorrelograms are stacked along the theoretical travel times predicted based on each source depth, Moho depth and epicentral distance. The source depth in the set of the parameters that gives the most prominent stacking energy is regarded as the best-fitting source depth. We demonstrate the validity of SMAC in both synthetics and actual data for an earthquake occurring in Japan Island.

  12. Study on component interface evolution of a solid oxide fuel cell stack after long term operation

    Science.gov (United States)

    Yang, Jiajun; Huang, Wei; Wang, Xiaochun; Li, Jun; Yan, Dong; Pu, Jian; Chi, Bo; Li, Jian

    2018-05-01

    A 5-cell solid oxide fuel cell (SOFC) stack with external manifold structure is assembled and underwent a durability test with an output of 250 W for nearly 4400 h when current density and operating temperature are 355 mA/cm2 and 750 °C. Cells used in the stack are anode-supported cells (ASC) with yttria-stabilized zirconia (YSZ) electrolytes, Ni/YSZ hydrogen electrodes, and YSZ based composite cathode. The dimension of the cell is 150 × 150 mm (active area: 130 × 130 mm). Ceramic-glass sealant is used in the stack to keep the gas tightness between cells, interconnects and manifolds. Pure hydrogen and dry air are used as fuel and oxidant respectively. The stack has a maximum output of 340 W at 562 mA/cm2 current density at 750 °C. The stack shows a degradation of 1.5% per 1000 h during the test with 2 thermal cycles to room temperature. After the test, the stack was dissembled and examined. The relationship between microstructure changes of interfaces and degradation in the stack are discussed. The microstructure evolution of interfaces between electrode, contact material and current collector are unveiled and their relationship with the degradation is discussed.

  13. Structure-property relations in engineered semiconductor nanomaterials (Conference Presentation)

    Science.gov (United States)

    Hollingsworth, Jennifer A.; Htoon, Han

    2016-09-01

    Particle-size or `quantum-confinement' effects have been used for decades to tune semiconductor opto-electronic properties. More recently, particle size control as the primary means for properties control has been succeeded by nanoscale hetero-structuring. In this case, the nanosized particle is modified to include internal, nanoscale interfaces, generally defined by compositional variations that induce additional changes to semiconductor properties. These changes can entail enhancements to the size-induced properties as well as unexpected or `emergent' behaviors. Common structural motifs include enveloping a spherical semiconductor nanocrystal, i.e., a quantum dot, within a shell of a different composition. In this talk, I will discuss how solution-phase synthesis can be used to create these structures with precisely `engineered' complexity. Most notably, I will review our experiences with so-called `giant' quantum dots that, due to their internal nanoscale structure, exhibit a range of novel behaviors, including being non-blinking and non-photobleaching (Chen et al. J. Am. Chem. Soc. 2008, 130, 5026; Ghosh et al. J. Am. Chem. Soc. 2012, 134, 9634; Dennis et al. Nano Lett. 2012 12, 5545; Acharya et al. J. Am. Chem. Soc. 2015, 137, 3755), and remarkably efficient emitters of `multi-excitons' due to extreme suppression of Auger recombination (Mangum et al. Nanoscale 2014, 6, 3712; Gao et al. Adv. Optical Mater. 2015, 3, 39). I will discuss recent work extending non-blinking behavior to the blue/green and "dual-color" emission, and show how correlated optical/structural characterization can reveal new information regarding structure-property relations to guide new nanomaterials development (Orfield et al. ACS Nano, Article ASAP).

  14. Composition-Structure-Property Relations of Compressed Borosilicate Glasses

    Science.gov (United States)

    Svenson, Mouritz N.; Bechgaard, Tobias K.; Fuglsang, Søren D.; Pedersen, Rune H.; Tjell, Anders Ø.; Østergaard, Martin B.; Youngman, Randall E.; Mauro, John C.; Rzoska, Sylwester J.; Bockowski, Michal; Smedskjaer, Morten M.

    2014-08-01

    Hot isostatic compression is an interesting method for modifying the structure and properties of bulk inorganic glasses. However, the structural and topological origins of the pressure-induced changes in macroscopic properties are not yet well understood. In this study, we report on the pressure and composition dependences of density and micromechanical properties (hardness, crack resistance, and brittleness) of five soda-lime borosilicate glasses with constant modifier content, covering the extremes from Na-Ca borate to Na-Ca silicate end members. Compression experiments are performed at pressures ≤1.0 GPa at the glass transition temperature in order to allow processing of large samples with relevance for industrial applications. In line with previous reports, we find an increasing fraction of tetrahedral boron, density, and hardness but a decreasing crack resistance and brittleness upon isostatic compression. Interestingly, a strong linear correlation between plastic (irreversible) compressibility and initial trigonal boron content is demonstrated, as the trigonal boron units are the ones most disposed for structural and topological rearrangements upon network compaction. A linear correlation is also found between plastic compressibility and the relative change in hardness with pressure, which could indicate that the overall network densification is responsible for the increase in hardness. Finally, we find that the micromechanical properties exhibit significantly different composition dependences before and after pressurization. The findings have important implications for tailoring microscopic and macroscopic structures of glassy materials and thus their properties through the hot isostatic compression method.

  15. Black Hole Spectroscopy with Coherent Mode Stacking.

    Science.gov (United States)

    Yang, Huan; Yagi, Kent; Blackman, Jonathan; Lehner, Luis; Paschalidis, Vasileios; Pretorius, Frans; Yunes, Nicolás

    2017-04-21

    The measurement of multiple ringdown modes in gravitational waves from binary black hole mergers will allow for testing the fundamental properties of black holes in general relativity and to constrain modified theories of gravity. To enhance the ability of Advanced LIGO/Virgo to perform such tasks, we propose a coherent mode stacking method to search for a chosen target mode within a collection of multiple merger events. We first rescale each signal so that the target mode in each of them has the same frequency and then sum the waveforms constructively. A crucial element to realize this coherent superposition is to make use of a priori information extracted from the inspiral-merger phase of each event. To illustrate the method, we perform a study with simulated events targeting the ℓ=m=3 ringdown mode of the remnant black holes. We show that this method can significantly boost the signal-to-noise ratio of the collective target mode compared to that of the single loudest event. Using current estimates of merger rates, we show that it is likely that advanced-era detectors can measure this collective ringdown mode with one year of coincident data gathered at design sensitivity.

  16. ISINN-2. Neutron spectroscopy, nuclear structure and related topics

    International Nuclear Information System (INIS)

    1994-01-01

    The proceedings contain the materials presented at the Second International Seminar on Neutron-Nucleus Interactions (ISINN-2) dealing with the problems of neutron spectroscopy, nuclear structure and related topics. The Seminar took place in Dubna on April 26-28, 1994. Over 120 scientists from Belgium, Bulgaria, Czech Republic, Germany, Holland, Italy, Japan, Latvia, Mexico, Poland, Slovakia, Slovenia, Ukraine, US and about 10 Russian research institutes took part in the Seminar. The main problems discussed are the following: P-odd and P-even angular correlation and T-reversal invariance in neutron reactions, nuclear structure investigations by neutron capture, the mechanism of neutron reactions, nuclear fission processes, as well as neutron data for nuclear astrophysics

  17. ROR nuclear receptors: structures, related diseases, and drug discovery.

    Science.gov (United States)

    Zhang, Yan; Luo, Xiao-yu; Wu, Dong-hai; Xu, Yong

    2015-01-01

    Nuclear receptors (NRs) are ligand-regulated transcription factors that regulate metabolism, development and immunity. The NR superfamily is one of the major classes of drug targets for human diseases. Retinoic acid receptor-related orphan receptor (ROR) α, β and γ belong to the NR superfamily, and these receptors are still considered as 'orphan' receptors because the identification of their endogenous ligands has been controversial. Recent studies have demonstrated that these receptors are regulated by synthetic ligands, thus emerge as important drug targets for the treatment of multiple sclerosis, rheumatoid arthritis, psoriasis, etc. Studying the structural basis and ligand development of RORs will pave the way for a better understanding of the roles of these receptors in human diseases. Here, we review the structural basis, disease relevance, strategies for ligand identification, and current status of development of therapeutic ligands for RORs.

  18. Cross-cultural structures of concentric and diametric dualism in Lévi-Strauss' structural anthropology: structures of relation underlying the self and ego relation?

    Science.gov (United States)

    Downes, Paul

    2003-02-01

    The parallels between Jung's and Lévi-Strauss' concentric cross-cultural structures of the unconscious are highlighted. Lévi-Strauss' basic contrasts between concentric and diametric dualisms are developed into psychologically relevant differences regarding symmetry, connection and separation, and interaction between foreground and background structures respectively. These contrasts between concentric and diametric structures are applied as a common structural framework for understanding Jungian conceptions of the self, the ego and their relations, Freudian views of compensation and repetition in obsessional neurosis, and Winnicott's conception of a child's transitional object. Developing the contrasts between concentric and diametric structures reveals a compensatory relation between both structures. This supports an argument that concentric structures express the self and diametric structures express the ego in their mutual compensatory interrelation. Contrasting concentric with diametric structures challenges traditional Western logic, including Fordham's view that it is contradictory to treat the self as both centre and totality. It also develops an understanding of Jung's transcendent function which seeks to go beyond the ego-shadow opposition.

  19. Structure-function relations in physiology education: Where's the mechanism?

    Science.gov (United States)

    Lira, Matthew E; Gardner, Stephanie M

    2017-06-01

    Physiology demands systems thinking: reasoning within and between levels of biological organization and across different organ systems. Many physiological mechanisms explain how structures and their properties interact at one level of organization to produce emergent functions at a higher level of organization. Current physiology principles, such as structure-function relations, selectively neglect mechanisms by not mentioning this term explicitly. We explored how students characterized mechanisms and functions to shed light on how students make sense of these terms. Students characterized mechanisms as 1 ) processes that occur at levels of organization lower than that of functions; and 2 ) as detailed events with many steps involved. We also found that students produced more variability in how they characterized functions compared with mechanisms: students characterized functions in relation to multiple levels of organization and multiple definitions. We interpret these results as evidence that students see mechanisms as holding a more narrow definition than used in the biological sciences, and that students struggle to coordinate and distinguish mechanisms from functions due to cognitive processes germane to learning in many domains. We offer the instructional suggestion that we scaffold student learning by affording students opportunities to relate and also distinguish between these terms so central to understanding physiology. Copyright © 2017 the American Physiological Society.

  20. EU Relations with the BRICS: Strategic Partnership or Structural Disjunction?

    Directory of Open Access Journals (Sweden)

    Maria Raquel Freire

    2017-12-01

    Full Text Available The international system is characterized by increasingly interdependent and asymmetrical relations between the constellations of actors that compose it. While the state remains a central reference in international relations, multilevel and multidimensional relationships make the system very complex. The state, international organizations, non-state actors, club diplomacy and groups of states (e.g., the Group of 20 [G20] and the BRICS grouping of Brazil, Russia, India, China and South Africa all contribute to this complexity and make the global governance system increasingly multifaceted. In this context, this article examines the relationship between the European Union and the BRICS  – two very different actors, pursuing formal and informal integration processes, respectively – and assesses the possibilities and limits of cooperation. This article seeks to understand whether the EU – BRICS relationship reflects a strategic partnership or a structural disjuncture. It starts by discussing multilateralism as a cooperation-oriented but sometimes interest-driven tool in a diverse and multilevel governance system. It then analyses EU – BRICS relations, identifying the main drivers and highlighting how complex context both facilitates and hinders the constitution of this relationship. The article concludes that the EU – BRICS relationship is informed by asymmetries and ambivalence that reflect their different sizes, capacities and approaches. Moreover, although there is a shared understanding that cooperation might be beneficial, contradictory rules and perspectives on international order mean this potentially positive relationship is nevertheless embedded in fundamental structural constraints.

  1. [Structure analysis of disease-related proteins using vibrational spectroscopy].

    Science.gov (United States)

    Hiramatsu, Hirotsugu

    2014-01-01

    Analyses of the structure and properties of identified pathogenic proteins are important for elucidating the molecular basis of diseases and in drug discovery research. Vibrational spectroscopy has advantages over other techniques in terms of sensitivity of detection of structural changes. Spectral analysis, however, is complicated because the spectrum involves a substantial amount of information. This article includes examples of structural analysis of disease-related proteins using vibrational spectroscopy in combination with additional techniques that facilitate data acquisition and analysis. Residue-specific conformation analysis of an amyloid fibril was conducted using IR absorption spectroscopy in combination with (13)C-isotope labeling, linear dichroism measurement, and analysis of amide I band features. We reveal a pH-dependent property of the interacting segment of an amyloidogenic protein, β2-microglobulin, which causes dialysis-related amyloidosis. We also reveal the molecular mechanisms underlying pH-dependent sugar-binding activity of human galectin-1, which is involved in cell adhesion, using spectroscopic techniques including UV resonance Raman spectroscopy. The decreased activity at acidic pH was attributed to a conformational change in the sugar-binding pocket caused by protonation of His52 (pKa 6.3) and the cation-π interaction between Trp68 and the protonated His44 (pKa 5.7). In addition, we show that the peak positions of the Raman bands of the C4=C5 stretching mode at approximately 1600 cm(-1) and the Nπ-C2-Nτ bending mode at approximately 1405 cm(-1) serve as markers of the His side-chain structure. The Raman signal was enhanced 12 fold using a vertical flow apparatus.

  2. Electronic structure and superconductivity of FeSe-related superconductors.

    Science.gov (United States)

    Liu, Xu; Zhao, Lin; He, Shaolong; He, Junfeng; Liu, Defa; Mou, Daixiang; Shen, Bing; Hu, Yong; Huang, Jianwei; Zhou, X J

    2015-05-13

    FeSe superconductors and their related systems have attracted much attention in the study of iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a superconducting transition temperature (Tc) of ~8 K and it can be dramatically enhanced to 37 K at high pressure. On the other hand, its cousin system, FeTe, possesses a unique antiferromagnetic ground state but is non-superconducting. Substitution of Se with Te in the FeSe superconductor results in an enhancement of Tc up to 14.5 K and superconductivity can persist over a large composition range in the Fe(Se,Te) system. Intercalation of the FeSe superconductor leads to the discovery of the AxFe2-ySe2 (A = K, Cs and Tl) system that exhibits a Tc higher than 30 K and a unique electronic structure of the superconducting phase. A recent report of possible high temperature superconductivity in single-layer FeSe/SrTiO3 films with a Tc above 65 K has generated much excitement in the community. This pioneering work opens a door for interface superconductivity to explore for high Tc superconductors. The distinct electronic structure and superconducting gap, layer-dependent behavior and insulator-superconductor transition of the FeSe/SrTiO3 films provide critical information in understanding the superconductivity mechanism of iron-based superconductors. In this paper, we present a brief review of the investigation of the electronic structure and superconductivity of the FeSe superconductor and related systems, with a particular focus on the FeSe films.

  3. From Multi to Single Stack Automata

    Science.gov (United States)

    Atig, Mohamed Faouzi

    We investigate the issue of reducing the verification problem of multi-stack machines to the one for single-stack machines. For instance, elegant (and practically efficient) algorithms for bounded-context switch analysis of multi-pushdown systems have been recently defined based on reductions to the reachability problem of (single-stack) pushdown systems [10,18]. In this paper, we extend this view to both bounded-phase visibly pushdown automata (BVMPA) [16] and ordered multi-pushdown automata (OMPA) [1] by showing that each of their emptiness problem can be reduced to the one for a class of single-stack machines. For these reductions, we introduce effective generalized pushdown automata (EGPA) where operations on stacks are (1) pop the top symbol of the stack, and (2) push a word in some (effectively) given set of words L over the stack alphabet, assuming that L is in some class of languages for which checking whether L intersects regular languages is decidable. We show that the automata-based saturation procedure for computing the set of predecessors in standard pushdown automata can be extended to prove that for EGPA too the set of all predecessors of a regular set of configurations is an effectively constructible regular set. Our reductions from OMPA and BVMPA to EGPA, together with the reachability analysis procedure for EGPA, allow to provide conceptually simple algorithms for checking the emptiness problem for each of these models, and to significantly simplify the proofs for their 2ETIME upper bounds (matching their lower-bounds).

  4. Start-Stop Test Procedures on the PEMFC Stack Level

    DEFF Research Database (Denmark)

    Mitzel, Jens; Nygaard, Frederik; Veltzé, Sune

    The test is addressed to investigate the influence on stack durability of a long stop followed by a restart of a stack. Long stop should be defined as a stop in which the anodic compartment is fully filled by air due to stack leakages. In systems, leakage level of the stack is low and time to fil...

  5. Transistor memory devices with large memory windows, using multi-stacking of densely packed, hydrophobic charge trapping metal nanoparticle array.

    Science.gov (United States)

    Cho, Ikjun; Kim, Beom Joon; Ryu, Sook Won; Cho, Jeong Ho; Cho, Jinhan

    2014-12-19

    Organic field-effect transistor (OFET) memories have rapidly evolved from low-cost and flexible electronics with relatively low-memory capacities to memory devices that require high-capacity memory such as smart memory cards or solid-state hard drives. Here, we report the high-capacity OFET memories based on the multilayer stacking of densely packed hydrophobic metal NP layers in place of the traditional transistor memory systems based on a single charge trapping layer. We demonstrated that the memory performances of devices could be significantly enhanced by controlling the adsorption isotherm behavior, multilayer stacking structure and hydrophobicity of the metal NPs. For this study, tetraoctylammonium (TOA)-stabilized Au nanoparticles (TOA-Au(NPs)) were consecutively layer-by-layer (LbL) assembled with an amine-functionalized poly(amidoamine) dendrimer (PAD). The formed (PAD/TOA-Au(NP))(n) films were used as a multilayer stacked charge trapping layer at the interface between the tunneling dielectric layer and the SiO2 gate dielectric layer. For a single AuNP layer (i.e. PAD/TOA-Au(NP))1) with a number density of 1.82 × 10(12) cm(-2), the memory window of the OFET memory device was measured to be approximately 97 V. The multilayer stacked OFET memory devices prepared with four Au(NP) layers exhibited excellent programmable memory properties (i.e. a large memory window (ΔV(th)) exceeding 145 V, a fast switching speed (1 μs), a high program/erase (P/E) current ratio (greater than 10(6)) and good electrical reliability) during writing and erasing over a relatively short time scale under an operation voltage of 100 V applied at the gate.

  6. Transistor memory devices with large memory windows, using multi-stacking of densely packed, hydrophobic charge trapping metal nanoparticle array

    International Nuclear Information System (INIS)

    Cho, Ikjun; Cho, Jinhan; Kim, Beom Joon; Cho, Jeong Ho; Ryu, Sook Won

    2014-01-01

    Organic field-effect transistor (OFET) memories have rapidly evolved from low-cost and flexible electronics with relatively low-memory capacities to memory devices that require high-capacity memory such as smart memory cards or solid-state hard drives. Here, we report the high-capacity OFET memories based on the multilayer stacking of densely packed hydrophobic metal NP layers in place of the traditional transistor memory systems based on a single charge trapping layer. We demonstrated that the memory performances of devices could be significantly enhanced by controlling the adsorption isotherm behavior, multilayer stacking structure and hydrophobicity of the metal NPs. For this study, tetraoctylammonium (TOA)-stabilized Au nanoparticles (TOA-Au NPs ) were consecutively layer-by-layer (LbL) assembled with an amine-functionalized poly(amidoamine) dendrimer (PAD). The formed (PAD/TOA-Au NP ) n films were used as a multilayer stacked charge trapping layer at the interface between the tunneling dielectric layer and the SiO 2 gate dielectric layer. For a single Au NP layer (i.e. PAD/TOA-Au NP ) 1 ) with a number density of 1.82 × 10 12 cm −2 , the memory window of the OFET memory device was measured to be approximately 97 V. The multilayer stacked OFET memory devices prepared with four Au NP layers exhibited excellent programmable memory properties (i.e. a large memory window (ΔV th ) exceeding 145 V, a fast switching speed (1 μs), a high program/erase (P/E) current ratio (greater than 10 6 ) and good electrical reliability) during writing and erasing over a relatively short time scale under an operation voltage of 100 V applied at the gate. (paper)

  7. Measurement of local relative displacements in large structures

    DEFF Research Database (Denmark)

    Tesauro, Angelo; Eder, Martin Alexander; Nielsen, Magda

    2014-01-01

    in particular. The measurement of small local relative displacements in structures subjected to large global deformations is complex and hardly feasible with conventional measurement methods. Therefore, a Small Displacement Measurement System (SDMS) has been devised. The SDMS is based on stereo photogrammetry...... and capable of measuring 3D local displacements with a high degree of accuracy. In this article, the technique is used to measure local deformations in the vicinity of the adhesive trailing edge joint of a wind turbine rotor blade. The SDMS results correspond well with another independent measurement method....

  8. The structure of the pelagic food web in relation to water column structure in the Skagerrak

    DEFF Research Database (Denmark)

    Kiørboe, Thomas; Kaas, H.; Kruse, B.

    1990-01-01

    The distribution, composition and activity of phytoplankton, and accompanying changes in specific activities of bacterioplankton and copepods, were related to variations in the vertical structure of the water column along a transect through the Skagerrak in May 1987. The Skagerrak is characterized...

  9. Evolution of camalexin and structurally related indolic compounds.

    Science.gov (United States)

    Rauhut, Thomas; Glawischnig, Erich

    2009-01-01

    Structurally related secondary products are rather rarely shared by organisms from different kingdoms. Consequently, the evolution of biosynthetic pathways of defence metabolites between distantly related organisms has not been broadly investigated. Thiazolylindoles are found in Arabidopsis thaliana, as the phytoalexin camalexin, and in a Streptomyces strain, which synthesizes a tumour-inhibitory derivative, designated BE-10988. Camalexin originates from cysteine and tryptophan, which is converted to indole-3-acetaldoxime and subsequently dehydrated to indole-3-acetonitrile. The metabolic origin of BE-10988 was determined by retrobiosynthetic NMR analysis and incorporation studies with direct precursors. Like camalexin, it is derived from tryptophan and cysteine. However, as BE-10988 is synthesized via indole-3-pyruvic acid, not via indole-3-acetaldoxime, independent mechanisms of tryptophan modification have evolved.

  10. Graded Geometric Structures Underlying F-Theory Related Defect Theories

    Science.gov (United States)

    Oikonomou, V. K.

    2013-08-01

    In the context of F-theory, we study the related eight-dimensional super-Yang-Mills theory and reveal the underlying supersymmetric quantum mechanics algebra that the fermionic fields localized on the corresponding defect theory are related to. Particularly, the localized fermionic fields constitute a graded vector space, and in turn this graded space enriches the geometric structures that can be built on the initial eight-dimensional space. We construct the implied composite fiber bundles, which include the graded affine vector space and demonstrate that the composite sections of this fiber bundle are in one-to-one correspondence to the sections of the square root of the canonical bundle corresponding to the submanifold on which the zero modes are localized.

  11. Population structure of two black Venezuelan populations studied through their mating structure and other related variables.

    Science.gov (United States)

    Castro de Guerra, D; Arvelo, H; Pinto-Cisternas, J

    1999-01-01

    In order to obtain information about the population structure of two black Venezuelan populations with historical differences both in their origins and development, a variety of variables were utilized, especially on marital structure, including: frequency of surnames, isonymy, population genealogical consanguinity, multiple unions, and marital distances, all of which provided information and isolation, migration, endogamy, consanguinity, and patri-matrifocality. Results showed differences in the extent of isolation and endogamy, as well as differences in population structure, which can be directly related with historical conditions of each population. Results agree with those previously obtained with traditional genetic polymorphisms and with the historical information available. Thus, the usefulness of surnames for inferring about population structure is supported, as well as the usefulness of historical information for explaining genetic diversity.

  12. EmuStack: An OpenStack-Based DTN Network Emulation Platform (Extended Version

    Directory of Open Access Journals (Sweden)

    Haifeng Li

    2016-01-01

    Full Text Available With the advancement of computing and network virtualization technology, the networking research community shows great interest in network emulation. Compared with network simulation, network emulation can provide more relevant and comprehensive details. In this paper, EmuStack, a large-scale real-time emulation platform for Delay Tolerant Network (DTN, is proposed. EmuStack aims at empowering network emulation to become as simple as network simulation. Based on OpenStack, distributed synchronous emulation modules are developed to enable EmuStack to implement synchronous and dynamic, precise, and real-time network emulation. Meanwhile, the lightweight approach of using Docker container technology and network namespaces allows EmuStack to support a (up to hundreds of nodes large-scale topology with only several physical nodes. In addition, EmuStack integrates the Linux Traffic Control (TC tools with OpenStack for managing and emulating the virtual link characteristics which include variable bandwidth, delay, loss, jitter, reordering, and duplication. Finally, experiences with our initial implementation suggest the ability to run and debug experimental network protocol in real time. EmuStack environment would bring qualitative change in network research works.

  13. Universal Scaling Relations in Scale-Free Structure Formation

    Science.gov (United States)

    Guszejnov, Dávid; Hopkins, Philip F.; Grudić, Michael Y.

    2018-04-01

    A large number of astronomical phenomena exhibit remarkably similar scaling relations. The most well-known of these is the mass distribution dN/dM∝M-2 which (to first order) describes stars, protostellar cores, clumps, giant molecular clouds, star clusters and even dark matter halos. In this paper we propose that this ubiquity is not a coincidence and that it is the generic result of scale-free structure formation where the different scales are uncorrelated. We show that all such systems produce a mass function proportional to M-2 and a column density distribution with a power law tail of dA/d lnΣ∝Σ-1. In the case where structure formation is controlled by gravity the two-point correlation becomes ξ2D∝R-1. Furthermore, structures formed by such processes (e.g. young star clusters, DM halos) tend to a ρ∝R-3 density profile. We compare these predictions with observations, analytical fragmentation cascade models, semi-analytical models of gravito-turbulent fragmentation and detailed "full physics" hydrodynamical simulations. We find that these power-laws are good first order descriptions in all cases.

  14. Levitation characteristics of HTS tape stacks

    Energy Technology Data Exchange (ETDEWEB)

    Pokrovskiy, S. V.; Ermolaev, Y. S.; Rudnev, I. A. [National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Moscow (Russian Federation)

    2015-03-15

    Due to the considerable development of the technology of second generation high-temperature superconductors and a significant improvement in their mechanical and transport properties in the last few years it is possible to use HTS tapes in the magnetic levitation systems. The advantages of tapes on a metal substrate as compared with bulk YBCO material primarily in the strength, and the possibility of optimizing the convenience of manufacturing elements of levitation systems. In the present report presents the results of the magnetic levitation force measurements between the stack of HTS tapes containing of tapes and NdFeB permanent magnet in the FC and ZFC regimes. It was found a non- linear dependence of the levitation force from the height of the array of stack in both modes: linear growth at small thickness gives way to flattening and constant at large number of tapes in the stack. Established that the levitation force of stacks comparable to that of bulk samples. The numerical calculations using finite element method showed that without the screening of the applied field the levitation force of the bulk superconductor and the layered superconductor stack with a critical current of tapes increased by the filling factor is exactly the same, and taking into account the screening force slightly different.

  15. Forced Air-Breathing PEMFC Stacks

    Directory of Open Access Journals (Sweden)

    K. S. Dhathathreyan

    2012-01-01

    Full Text Available Air-breathing fuel cells have a great potential as power sources for various electronic devices. They differ from conventional fuel cells in which the cells take up oxygen from ambient air by active or passive methods. The air flow occurs through the channels due to concentration and temperature gradient between the cell and the ambient conditions. However developing a stack is very difficult as the individual cell performance may not be uniform. In order to make such a system more realistic, an open-cathode forced air-breathing stacks were developed by making appropriate channel dimensions for the air flow for uniform performance in a stack. At CFCT-ARCI (Centre for Fuel Cell Technology-ARC International we have developed forced air-breathing fuel cell stacks with varying capacity ranging from 50 watts to 1500 watts. The performance of the stack was analysed based on the air flow, humidity, stability, and so forth, The major advantage of the system is the reduced number of bipolar plates and thereby reduction in volume and weight. However, the thermal management is a challenge due to the non-availability of sufficient air flow to remove the heat from the system during continuous operation. These results will be discussed in this paper.

  16. Enhanced dynamical stability with harmonic slip stacking

    Directory of Open Access Journals (Sweden)

    Jeffrey Eldred

    2016-10-01

    Full Text Available We develop a configuration of radio-frequency (rf cavities to dramatically improve the performance of slip stacking. Slip stacking is an accumulation technique used at Fermilab to nearly double proton intensity by maintaining two beams of different momenta in the same storage ring. The two particle beams are longitudinally focused in the Recycler by two 53 MHz 100 kV rf cavities with a small frequency difference between them. We propose an additional 106 MHz 20 kV rf cavity with a frequency at the double the average of the upper and lower main rf frequencies. We show the harmonic rf cavity cancels out the resonances generated between the two main rf cavities and we derive the relationship between the harmonic rf voltage and the main rf voltage. We find the area factors that can be used to calculate the available phase space area for any set of beam parameters without individual simulation. We establish Booster beam quality requirements to achieve 99% slip stacking efficiency. We measure the longitudinal distribution of the Booster beam and use it to generate a realistic beam model for slip stacking simulation. We demonstrate that the harmonic rf cavity can not only reduce particle loss during slip stacking, but also reduce the final longitudinal emittance.

  17. Stacking fault domains as sources of a-type threading dislocations in III-nitride heterostructures

    Science.gov (United States)

    Smalc-Koziorowska, J.; Bazioti, C.; Albrecht, M.; Dimitrakopulos, G. P.

    2016-02-01

    A mechanism for the nucleation of a-type threading dislocation half-loops from basal stacking faults in wurtzite III-nitride heterostructures is presented. Transmission electron microscopy observations, in conjunction with topological and strain analysis, show that there are two possible configurations of closed domains comprising basal stacking faults of I1 type. It is shown that the lattice dislocation may emanate when the sphalerite structural units of the stacking faults in the closed domain are oriented in a parallel manner. The closed domain configurations do not introduce any shift on the basal planes, resulting in zero defect content along the growth direction. The stacking fault domains are hexagonal, with sides along the ⟨ 10 1 ¯ 0 ⟩ directions, and the threading dislocation half loops nucleate at the line nodes. The mechanism was found to be operational in multiple III-nitride systems.

  18. Micro-texture and Structure of High-pressure Quenched Graphite and Related Carbon Materials

    Science.gov (United States)

    Ohfuji, H.; Aibara, K.; Sumiya, H.; Irifune, T.

    2007-12-01

    There have been extensive studies in room-temperature compression of graphite and related carbon materials such as nanotubes and fullerene. Some reports claimed that the transformation of carbon hybridized state from sp2 to sp3 takes place under high pressure at room temperature, and the hardness of the quench products may be comparable to that of cubic diamond. Here, we investigated the micro-texture and structure involved in such high-pressure quenched carbon materials using high-resolution electron microscopy. High- pressure experiments were conducted on a variety of carbon materials including graphite (synthetic, highly- oriented sheet), single/multi-walled carbon nanotubes, amorphous carbons in a diamond anvil cell (DAC, with 250 μm culet non-beveled anvils) at room temperature. Pelletized sample was loaded into a 70 μm hall, drilled in a preindented Re gasket, without a pressure medium. The sample was compressed up to 70 ~ 90 GPa at room temperature, kept at the highest pressure at least overnight, and then decompressed. The pressure dependence of graphite E2g( G) Raman band at ~1580cm-1 was measured on compression and decompression. A1g( D) band, so called defect band at ~1350 cm-1, was also collected for the recovered products. The quenched materials were examined by high-resolution (HR) field emission (FE-) SEM and (HR)TEM. A focused ion beam (FIB) was employed to fabricate thin cross-sections of the samples. The most notable change in texture upon compression was observed in multi-walled carbon nanotube (MWNT); the elongated tubes were fragmented into short rods (ca. 100 - 300 nm in length and 80 - 100 nm in width, almost two times wider than that of the original MWNT). TEM observations showed that the short rod- shaped particles consist of piles of graphene shells (stacked walls of MWNT, characterized by (002) lattice fringes) which were significantly bent and fragmented. Some of those rod-shaped particles showed lattice fringes with an interlayer

  19. Graphene controlled H- and J-stacking of perylene dyes into highly stable supramolecular nanostructures for enhanced photocurrent generation

    DEFF Research Database (Denmark)

    Gan, Shiyu; Zhong, Lijie; Engelbrekt, Christian

    2014-01-01

    We report a new method for controlling H- and J-stacking in supramolecular self-assembly. Graphene nanosheets act as structure inducers to direct the self-assembly of a versatile organic dye, perylene into two distinct types of functional nanostructures, i.e. one-dimensional nanotubes via J-stack......-junction solar cells.......We report a new method for controlling H- and J-stacking in supramolecular self-assembly. Graphene nanosheets act as structure inducers to direct the self-assembly of a versatile organic dye, perylene into two distinct types of functional nanostructures, i.e. one-dimensional nanotubes via J......-stacking and two-dimensional branched nanobuds through H-stacking. Graphene integrated supramolecular nanocomposites are highly stable and show significant enhancement of photocurrent generation in these two configurations of photosensing devices, i.e. solid-state optoelectronic constructs and liquid...

  20. The Guadalquivir Diapiric Ridge: Deep Tectonics and Related Gas Structures

    Science.gov (United States)

    Fernández-Puga, M. C.; Somoza, L.; Pinheiro, L. M.; Magalhães, V.; Vázquez, J. T.; Díaz-del-Río, V.; Ivanov, M.

    Cooperation between the Spanish TASYO project during the cruises Tasyo/2000, Anastasya/99, Anastasya/00 and Anastasya/01 and the UNESCO-IOC Trainning Trough Research Programme during the TTR9, TTR10 and TTR-11 cruises have per- mitted to identify numerous structures related to hydrocarbon seepages in the Gulf of Cadiz, located between the Africa and Eurasia plate. The interpretation of multibeam bathymetry and a large database of reflection seismic profiles shows two important morphotectonics structures: the Cadiz Diapiric Ridge (CDR) and the Guadalquivir Di- apiric Ridge (GDR). The CDR is a diapiric elongate structure located between 400 and 700m water depth, with a N-S direction. The GDR is an elongated ridge, situated west- ward of this structure and located along the shelf and slope between 300-1100m depth. This highly deformed ridge, formed by several diapirs oriented in NE-SW direction, has been mapped using industrial multifold seismic, core logs, gravity cores, dredge samples and photographs, obtained during the ANASTASYA 01/09 cruise. This data has shown that it is composed of early-middle Miocene blue marls (Maldonado et al, 1999), mud breccias and calcarenites. In fact, this diapiric structure is associated with a complex tectono-sedimentary history related to along slope gravity gliding and tec- tonic compression westward the fronts of the deformed wedges of the SOlistostromic & cedil;allochtonous unitsT (Somoza et al., 1999). According to the observed and sampled structures along the GDR, this ridge can be divided in three areas: (a) The NE area is characterized by the existence of a series of wide single sub-circular mud volcanoes (Anastasya, Tarsis and Pipoca), surrounded by a ring shaped seafloor depression. Mud breccia has been collected from these mud volcanoes (ANAS00-TG5,TG6,TG7,TG8 and ANAS01-TG2); (b) a central sector with long rounded-like crater structures, of unknown origin, from which calcarenites were collected (ANAS01-DA13); and (c) a SW

  1. Crystallisation and structural studies of monodisperse nylon oligomers and related polymers

    International Nuclear Information System (INIS)

    Sikorski, P.T.

    2001-11-01

    Using electron and X-ray diffraction data, together with computerised molecular modeling, the structures of monodisperse nylon oligomers and related polymers have been investigated. Structural changes on heating were also studied. The molecules were crystallised from solution and their morphologies examined using optical and transmission electron microscopy. Lath-like lamellar crystals of the polyester poly-β-propiolactone were crystallised isothermally. The interpretation of the diffraction data with the use of molecular modeling led to the discovery of the new crystalline structure, the γ-structure. In the γ-structure, the polyester chain is in an all-trans conformation and the structure consists of a two-chain, basal-faced, orthorhombic unit cell. The setting angles, with respect to the a axis, are ± 51.5 deg for the corner and centre chains, respectively. The lamellae are 5 nm in thickness and the chains run orthogonal to the lamellar surface. The general fold direction is along the a-axis (long axis of the crystal) and the chain folds successively in the [110] and [11-bar0] directions. Three different nylon 4 6 oligomers were crystallised from solution using a range of crystallisation methods. The 4- and 8-amide molecules were found to form three-dimensional crystals, in which the crystal thickness was much greater than the molecular length. The structure was found to be different from the nylon 4 6 polymer reported previously. It was found that the type of hydrogen-bonded sheet formed by these molecules can influence the way in which these sheets stack to form crystals. In addition, a study of the 9-amide molecule showed that a particular type of hydrogen-bonded sheet, a-sheet, is preferred for nylon 4 6. This discovery suggests that an amide unit is found in the fold in the chain-folded nylon 4 6 polymer crystals, to allow the a-sheets to be formed. It is not a consequence of a need to form a stress-free fold. In the regular adjacent re-entry chain

  2. Mesoscale models for stacking faults, deformation twins and martensitic transformations: Linking atomistics to continuum

    Science.gov (United States)

    Kibey, Sandeep A.

    We present a hierarchical approach that spans multiple length scales to describe defect formation---in particular, formation of stacking faults (SFs) and deformation twins---in fcc crystals. We link the energy pathways (calculated here via ab initio density functional theory, DFT) associated with formation of stacking faults and twins to corresponding heterogeneous defect nucleation models (described through mesoscale dislocation mechanics). Through the generalized Peieirls-Nabarro model, we first correlate the width of intrinsic SFs in fcc alloy systems to their nucleation pathways called generalized stacking fault energies (GSFE). We then establish a qualitative dependence of twinning tendency in fee metals and alloys---specifically, in pure Cu and dilute Cu-xAl (x= 5.0 and 8.3 at.%)---on their twin-energy pathways called the generalized planar fault energies (GPFE). We also link the twinning behavior of Cu-Al alloys to their electronic structure by determining the effect of solute Al on the valence charge density redistribution at the SF through ab initio DFT. Further, while several efforts have been undertaken to incorporate twinning for predicting stress-strain response of fcc materials, a fundamental law for critical twinning stress has not yet emerged. We resolve this long-standing issue by linking quantitatively the twin-energy pathways (GPFE) obtained via ab initio DFT to heterogeneous, dislocation-based twin nucleation models. We establish an analytical expression that quantitatively predicts the critical twinning stress in fcc metals in agreement with experiments without requiring any empiricism at any length scale. Our theory connects twinning stress to twin-energy pathways and predicts a monotonic relation between stress and unstable twin stacking fault energy revealing the physics of twinning. We further demonstrate that the theory holds for fcc alloys as well. Our theory inherently accounts for directional nature of twinning which available

  3. Solid oxide fuel cell generator with removable modular fuel cell stack configurations

    Science.gov (United States)

    Gillett, J.E.; Dederer, J.T.; Zafred, P.R.; Collie, J.C.

    1998-04-21

    A high temperature solid oxide fuel cell generator produces electrical power from oxidation of hydrocarbon fuel gases such as natural gas, or conditioned fuel gases, such as carbon monoxide or hydrogen, with oxidant gases, such as air or oxygen. This electrochemical reaction occurs in a plurality of electrically connected solid oxide fuel cells bundled and arrayed in a unitary modular fuel cell stack disposed in a compartment in the generator container. The use of a unitary modular fuel cell stack in a generator is similar in concept to that of a removable battery. The fuel cell stack is provided in a pre-assembled self-supporting configuration where the fuel cells are mounted to a common structural base having surrounding side walls defining a chamber. Associated generator equipment may also be mounted to the fuel cell stack configuration to be integral therewith, such as a fuel and oxidant supply and distribution systems, fuel reformation systems, fuel cell support systems, combustion, exhaust and spent fuel recirculation systems, and the like. The pre-assembled self-supporting fuel cell stack arrangement allows for easier assembly, installation, maintenance, better structural support and longer life of the fuel cells contained in the fuel cell stack. 8 figs.

  4. Layer stackings and physical properties of mixed-layer structure phases. III. Preparation of mixed-layer structure phases of Re{sub X}Nb{sub 1-X}Se{sub 2} and Os{sub X}Nb{sub 1-X}Se{sub 2} and some electrical and magnetic properties

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, K.; Chijimatsu, Y.; Maeda, N.; Ikeuchi, T.; Onuma, E. [Okayama Univ. of Sci. (Japan). Lab. for Solid State Chem.

    1998-05-01

    The binary systems, ReSe{sub 2}-NbSe{sub 2} and OsSe{sub 2}-NbSe{sub 2}, are studied. Mixed-layer structure phases are found in Re{sub X}Nb{sub 1-X}Se{sub 2} of the composition range, 0.12{<=}X<0.45, and in Os{sub X}Nb{sub 1-X}Se{sub 2} of the composition range, 0.10{<=}X<0.33. The mixed-layer structures of both phases are constructed by random and mixed stacking of the 2H{sub b}-layers and 3R-layers. The WSe{sub 2}-type 2H{sub b} phases are found in Re{sub X}Nb{sub 1-X}Se{sub 2} of the composition range, 0.45{<=}X{<=}0.55, and in Os{sub X}Nb{sub 1-X}Se{sub 2} of the composition range, 0.33{<=}X{<=}0.35. A novel mixed-layer structure constructed with 1T-layers and 2H{sub b}-layers is found in Os{sub X}Nb{sub 1-X}Se{sub 2} of the composition range, 0.35{<=}X<0.60. The magnetic susceptibilities of the samples of the mixed-layer phases show a weak Pauli-paramagnetism. Both the paramagnetic moments and the electrical conductivities of both phases decrease as the composition X increases. The behaviors of the paramagnetic moment and the electrical conductivity of those phases offer us a good example of the number of conduction electrons and their effect. (orig.) 5 refs.

  5. Progress of MCFC stack technology at Toshiba

    Energy Technology Data Exchange (ETDEWEB)

    Hori, M.; Hayashi, T.; Shimizu, Y. [Toshiba Corp., Tokyo (Japan)

    1996-12-31

    Toshiba is working on the development of MCFC stack technology; improvement of cell characteristics, and establishment of separator technology. For the cell technology, Toshiba has concentrated on both the restraints of NiO cathode dissolution and electrolyte loss from cells, which are the critical issues to extend cell life in MCFC, and great progress has been made. On the other hand, recognizing that the separator is one of key elements in accomplishing reliable and cost-competitive MCFC stacks, Toshiba has been accelerating the technology establishment and verification of an advanced type separator. A sub-scale stack with such a separator was provided for an electric generating test, and has been operated for more than 10,000 hours. This paper presents several topics obtained through the technical activities in the MCFC field at Toshiba.

  6. Characterization of double Shockley-type stacking faults formed in lightly doped 4H-SiC epitaxial films

    Science.gov (United States)

    Yamashita, T.; Hayashi, S.; Naijo, T.; Momose, K.; Osawa, H.; Senzaki, J.; Kojima, K.; Kato, T.; Okumura, H.

    2018-05-01

    Double Shockley-type stacking faults (2SSFs) formed in 4H-SiC epitaxial films with a dopant concentration of 1.0 × 1016 cm-3 were characterized using grazing incident X-ray topography and high-resolution scanning transmission electron microscopy. The origins of 2SSFs were investigated, and it was found that 2SSFs in the epitaxial layer originated from narrow SFs with a double Shockley structure in the substrate. Partial dislocations formed between 4H-type and 2SSF were also characterized. The shapes of 2SSFs are related with Burgers vectors and core types of the two Shockley partial dislocations.

  7. Simple model of stacking-fault energies

    DEFF Research Database (Denmark)

    Stokbro, Kurt; Jacobsen, Lærke Wedel

    1993-01-01

    A simple model for the energetics of stacking faults in fcc metals is constructed. The model contains third-nearest-neighbor pairwise interactions and a term involving the fourth moment of the electronic density of states. The model is in excellent agreement with recently published local-density ......A simple model for the energetics of stacking faults in fcc metals is constructed. The model contains third-nearest-neighbor pairwise interactions and a term involving the fourth moment of the electronic density of states. The model is in excellent agreement with recently published local...

  8. Stacking-Based Visualization of Trajectory Attribute Data.

    Science.gov (United States)

    Tominski, C; Schumann, H; Andrienko, G; Andrienko, N

    2012-12-01

    Visualizing trajectory attribute data is challenging because it involves showing the trajectories in their spatio-temporal context as well as the attribute values associated with the individual points of trajectories. Previous work on trajectory visualization addresses selected aspects of this problem, but not all of them. We present a novel approach to visualizing trajectory attribute data. Our solution covers space, time, and attribute values. Based on an analysis of relevant visualization tasks, we designed the visualization solution around the principle of stacking trajectory bands. The core of our approach is a hybrid 2D/3D display. A 2D map serves as a reference for the spatial context, and the trajectories are visualized as stacked 3D trajectory bands along which attribute values are encoded by color. Time is integrated through appropriate ordering of bands and through a dynamic query mechanism that feeds temporally aggregated information to a circular time display. An additional 2D time graph shows temporal information in full detail by stacking 2D trajectory bands. Our solution is equipped with analytical and interactive mechanisms for selecting and ordering of trajectories, and adjusting the color mapping, as well as coordinated highlighting and dedicated 3D navigation. We demonstrate the usefulness of our novel visualization by three examples related to radiation surveillance, traffic analysis, and maritime navigation. User feedback obtained in a small experiment indicates that our hybrid 2D/3D solution can be operated quite well.

  9. Formation of stacking faults and the screw dislocation-driven growth: a case study of aluminum nitride nanowires.

    Science.gov (United States)

    Meng, Fei; Estruga, Marc; Forticaux, Audrey; Morin, Stephen A; Wu, Qiang; Hu, Zheng; Jin, Song

    2013-12-23

    Stacking faults are an important class of crystal defects commonly observed in nanostructures of close packed crystal structures. They can bridge the transition between hexagonal wurtzite (WZ) and cubic zinc blende (ZB) phases, with the most known example represented by the "nanowire (NW) twinning superlattice". Understanding the formation mechanisms of stacking faults is crucial to better control them and thus enhance the capability of tailoring physical properties of nanomaterials through defect engineering. Here we provide a different perspective to the formation of stacking faults associated with the screw dislocation-driven growth mechanism of nanomaterials. With the use of NWs of WZ aluminum nitride (AlN) grown by a high-temperature nitridation method as the model system, dislocation-driven growth was first confirmed by transmission electron microscopy (TEM). Meanwhile numerous stacking faults and associated partial dislocations were also observed and identified to be the Type I stacking faults and the Frank partial dislocations, respectively, using high-resolution TEM. In contrast, AlN NWs obtained by rapid quenching after growth displayed no stacking faults or partial dislocations; instead many of them had voids that were associated with the dislocation-driven growth. On the basis of these observations, we suggest a formation mechanism of stacking faults that originate from dislocation voids during the cooling process in the syntheses. Similar stacking fault features were also observed in other NWs with WZ structure, such as cadmium sulfide (CdS) and zinc oxide (ZnO).

  10. Entropy, related thermodynamic properties, and structure of methylisocyanate

    International Nuclear Information System (INIS)

    Davis, Phil S.; Kilpatrick, John E.

    2013-01-01

    Highlights: ► The thermodynamic properties of methylisocyanate have been determined by isothermal calorimetry from 15 to 298.15 K. ► The third law entropy has been compared with the entropy calculated by statistical thermodynamics. ► The comparisons are consistent with selected proposed molecular structures and vibrational frequencies. -- Abstract: The entropy and related thermodynamic properties of methylisocyanate, CH 3 NCO, have been determined by isothermal calorimetry. The entropy in the ideal gas state at 298.15 K and 1 atmosphere is S m o = 284.3 ± 0.6 J/K · mol. Other thermodynamic properties determined include: the heat capacity from 15 to 300 K, the temperature of fusion (T fus = 178.461 ± 0.024 K), the enthalpy of fusion (ΔH fus = 7455.2 ± 14.0 J/mol), the enthalpy of vaporization at 298.15 K (ΔH vap = 28768 ± 54 J/mol), and the vapor pressure from fusion to 300 K. Using statistical thermodynamics, the entropy in this same state has been calculated for various assumed structures for methylisocyante which have been proposed based on several spectroscopic and ab initio results. Comparisons between the experimental and calculated entropy have led to the following conclusions concerning historical differences among problematic structural properties: (1) The CNC/CNO angles can have the paired values of 140/180° or 135/173° respectively. It is not possible to distinguish between the two by this thermodynamic analysis. (2) The methyl group functions as a free rotor or near free rotor against the NCO rigid frame. The barrier to internal rotation is less than 2100 J/mol. (3) The CNC vibrational bending frequency is consistent with the more recently observed assignments at 165 and 172 cm −1 with some degree of anharmonicity or with a pure harmonic at about 158 cm −1

  11. Power station stack gas emissions

    International Nuclear Information System (INIS)

    Hunwick, Richard J.

    2006-01-01

    There are increasing awareness and pressure to reduce emissions of acid rain and photochemical smog. There is a need to produce new control system and equipment to capture those emissions. The most visible form of pollutions are the chimney smoke, dust and particles of fly ash from mineral matter in the fuel. Acid gases are hard on structures and objects containing limestone. Coal fired power generation is likely to be able to sustain its competitive advantage as a clean source of electricity in comparison with nuclear power and natural gas

  12. Stacking fault tetrahedra formation in the neighbourhood of grain boundaries

    CERN Document Server

    Samaras, M; Van Swygenhoven, H; Victoria, M

    2003-01-01

    Large scale molecular dynamics computer simulations are performed to study the role of the grain boundary (GB) during the cascade evolution in irradiated nanocrystalline Ni. At all primary knock-on atom (PKA) energies in cascades near GBs, the damage produced after cooling down is vacancy dominated. Truncated stacking fault tetrahedra (TSFTs) are easily formed at 10 keV and higher PKA energies. At the higher energies a complex partial dislocation network forms, consisting of TSFTs. The GB acts as an interstitial sink without undergoing major structural changes.

  13. Analyses of Large Coal-Based SOFCs for High Power Stack Block Development

    Energy Technology Data Exchange (ETDEWEB)

    Recknagle, Kurtis P; Koeppel, Brian J

    2010-10-01

    This report summarizes the numerical modeling and analytical efforts for SOFC stack development performed for the coal-based SOFC program. The stack modeling activities began in 2004, but this report focuses on the most relevant results obtained since August 2008. This includes the latter half of Phase-I and all of Phase-II activities under technical guidance of VPS and FCE. The models developed to predict the thermal-flow-electrochemical behaviors and thermal-mechanical responses of generic planar stacks and towers are described. The effects of cell geometry, fuel gas composition, on-cell reforming, operating conditions, cell performance, seal leak, voltage degradation, boundary conditions, and stack height are studied. The modeling activities to evaluate and achieve technical targets for large stack blocks are described, and results from the latest thermal-fluid-electrochemical and structural models are summarized. Modeling results for stack modifications such as scale-up and component thickness reduction to realize cost reduction are presented. Supporting modeling activities in the areas of cell fabrication and loss of contact are also described.

  14. AIC-based diffraction stacking for local earthquake locations at the Sumatran Fault (Indonesia)

    Science.gov (United States)

    Hendriyana, Andri; Bauer, Klaus; Muksin, Umar; Weber, Michael

    2018-05-01

    We present a new workflow for the localization of seismic events which is based on a diffraction stacking approach. In order to address the effects from complex source radiation patterns, we suggest to compute diffraction stacking from a characteristic function (CF) instead of stacking the original waveform data. A new CF, which is called in the following mAIC (modified from Akaike Information Criterion) is proposed. We demonstrate that both P- and S-wave onsets can be detected accurately. To avoid cross-talk between P and S waves due to inaccurate velocity models, we separate the P and S waves from the mAIC function by making use of polarization attributes. Then, the final image function is represented by the largest eigenvalue as a result of the covariance analysis between P- and S-image functions. Results from synthetic experiments show that the proposed diffraction stacking provides reliable results. The workflow of the diffraction stacking method was finally applied to local earthquake data from Sumatra, Indonesia. Recordings from a temporary network of 42 stations deployed for nine months around the Tarutung pull-apart basin were analysed. The seismic event locations resulting from the diffraction stacking method align along a segment of the Sumatran Fault. A more complex distribution of seismicity is imaged within and around the Tarutung basin. Two lineaments striking N-S were found in the centre of the Tarutung basin which support independent results from structural geology.

  15. Contemporary sample stacking in analytical electrophoresis

    Czech Academy of Sciences Publication Activity Database

    Šlampová, Andrea; Malá, Zdeňka; Pantůčková, Pavla; Gebauer, Petr; Boček, Petr

    2013-01-01

    Roč. 34, č. 1 (2013), s. 3-18 ISSN 0173-0835 R&D Projects: GA ČR GAP206/10/1219 Institutional support: RVO:68081715 Keywords : biological samples * stacking * trace analysis * zone electrophoresis Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 3.161, year: 2013

  16. SRS reactor stack plume marking tests

    International Nuclear Information System (INIS)

    Petry, S.F.

    1992-03-01

    Tests performed in 105-K in 1987 and 1988 demonstrated that the stack plume can successfully be made visible (i.e., marked) by introducing smoke into the stack breech. The ultimate objective of these tests is to provide a means during an emergency evacuation so that an evacuee can readily identify the stack plume and evacuate in the opposite direction, thus minimizing the potential of severe radiation exposure. The EPA has also requested DOE to arrange for more tests to settle a technical question involving the correct calculation of stack downwash. New test canisters were received in 1988 designed to produce more smoke per unit time; however, these canisters have not been evaluated, because normal ventilation conditions have not been reestablished in K Area. Meanwhile, both the authorization and procedure to conduct the tests have expired. The tests can be performed during normal reactor operation. It is recommended that appropriate authorization and procedure approval be obtained to resume testing after K Area restart

  17. Testing of Electrodes, Cells and Short Stacks

    DEFF Research Database (Denmark)

    Hauch, Anne; Mogensen, Mogens Bjerg

    2017-01-01

    The present contribution describes the electrochemical testing and characterization of electrodes, cells, and short stacks. To achieve the maximum insight and results from testing of electrodes and cells, it is obviously necessary to have a good understanding of the fundamental principles...

  18. Stack Gas Scrubber Makes the Grade

    Science.gov (United States)

    Chemical and Engineering News, 1975

    1975-01-01

    Describes a year long test of successful sulfur dioxide removal from stack gas with a calcium oxide slurry. Sludge disposal problems are discussed. Cost is estimated at 0.6 mill per kwh not including sludge removal. A flow diagram and equations are included. (GH)

  19. OpenStack Object Storage (Swift) essentials

    CERN Document Server

    Kapadia, Amar; Varma, Sreedhar

    2015-01-01

    If you are an IT administrator and you want to enter the world of cloud storage using OpenStack Swift, then this book is ideal for you. Basic knowledge of Linux and server technology is beneficial to get the most out of the book.

  20. Stacked spheres and lower bound theorem

    Indian Academy of Sciences (India)

    BASUDEB DATTA

    2011-11-20

    Nov 20, 2011 ... Preliminaries. Lower bound theorem. On going work. Definitions. An n-simplex is a convex hull of n + 1 affinely independent points. (called vertices) in some Euclidean space R. N . Stacked spheres and lower bound theorem. Basudeb Datta. Indian Institute of Science. 2 / 27 ...

  1. Contemporary sample stacking in analytical electrophoresis

    Czech Academy of Sciences Publication Activity Database

    Malá, Zdeňka; Šlampová, Andrea; Křivánková, Ludmila; Gebauer, Petr; Boček, Petr

    2015-01-01

    Roč. 36, č. 1 (2015), s. 15-35 ISSN 0173-0835 R&D Projects: GA ČR(CZ) GA13-05762S Institutional support: RVO:68081715 Keywords : biological samples * stacking * trace analysis * zone electrophoresis Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 2.482, year: 2015

  2. The data type variety of stack algebras

    NARCIS (Netherlands)

    Bergstra, J.A.; Tucker, J.V.

    1995-01-01

    We define and study the class of all stack algebras as the class of all minimal algebras in a variety defined by an infinite recursively enumerable set of equations. Among a number of results, we show that the initial model of the variety is computable, that its equational theory is decidable,

  3. Photoswitchable Intramolecular H-Stacking of Perylenebisimide

    NARCIS (Netherlands)

    Wang, Jiaobing; Kulago, Artem; Browne, Wesley R.; Feringa, Ben L.

    2010-01-01

    Dynamic control over the formation of H- or J-type aggregates of chromophores is of fundamental importance for developing responsive organic optoelectronic materials. In this study, the first example of photoswitching between a nonstacked and an intramolecularly H-stacked arrangement of

  4. 40 CFR 61.53 - Stack sampling.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Stack sampling. 61.53 Section 61.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL... sampling. (a) Mercury ore processing facility. (1) Unless a waiver of emission testing is obtained under...

  5. 40 CFR 61.33 - Stack sampling.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 8 2010-07-01 2010-07-01 false Stack sampling. 61.33 Section 61.33 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL... sampling. (a) Unless a waiver of emission testing is obtained under § 61.13, each owner or operator...

  6. OpenStack cloud computing cookbook

    CERN Document Server

    Jackson, Kevin

    2013-01-01

    A Cookbook full of practical and applicable recipes that will enable you to use the full capabilities of OpenStack like never before.This book is aimed at system administrators and technical architects moving from a virtualized environment to cloud environments with familiarity of cloud computing platforms. Knowledge of virtualization and managing linux environments is expected.

  7. Annex I.G. Demolition of the G1 stack at Marcoule by toppling

    International Nuclear Information System (INIS)

    2005-01-01

    The G1 stack at Marcoule was constructed during the first half of 1956 as a ventilation outlet for the G1 reactor, which is cooled by air. After the G1 reactor was decommissioned, the G1 stack served as a ventilation outlet for two new nuclear facilities on the site. Being no longer in compliance with regulations and having many inadequacies and uncertainties in terms of the prestressed concrete, the stack posed a potential damage risk in extreme wind or in the event of an earthquake. In 1994 it was decided that a new stack would be built to act as an outlet for the existing nuclear facilities, and that the old one would be demolished. The G1 stack was 100 m in height, 10 m in diameter and constructed with 24 vertically stacked concrete rings consisting of nine prefabricated sections, each 3.6 m in height. It was capped by a metal deflector (about 6 m in height and weighing 50 t). The inside consisted of nine semicircular tubes constructed of steel sheet metal weighing 120 t. The base of the stack consisted of the foundation, a plate and a base plate which were constructed at the site. The barrel sections were prefabricated. Construction lasted from January 1956 to June 1956. At the base, the cylindrical portion of the stack widened to form three feet extending to a depth of 7.5 m. The base plate of the stack was formed onsite to the height of 16.7 m and then prestressed using cables. A repair carried out in 1964 included adding a concrete lining of the initial rings of the cylinder up to a level of 22.1 m. Additional prestressing with the base plate and repair of the horizontal and vertical prestressing of the barrel were also carried out, leaving only 22 rings and 43 visible cables. The total mass of the stack was 2170 t, including: - Concrete: cylinder 800 t, base plate 1200 t; - Steel: internal structures 120 t, deflector 50 t. The main radiological risk was the presence of traces of tritium. The radioactive inventory for the entire stack was estimated in 2000

  8. Structure of some relative relation modules of finite p-groups

    International Nuclear Information System (INIS)

    Yamin, M.

    1990-06-01

    Let G be a finite p-group generated by (g i , 1 ≤ i ≤ d), G i the cyclic subgroup generated by g i , E the free product of the G i , 1 ≤ i ≤ d, and S the kernel of the natural epimorphism of E onto G. The largest elementary abelian p-quotient S-circumflex = S/S'S p , regarded as an IF p G-module via conjugation in E, is called a relative relation module of G. If d is the minimum number of generaters for G, the author has proved that S-circumflex is nonprojective and indecomposable. The aim of this paper is to give an alternative proof for the indecomposability of S-circumflex; the proof here is more informative as it deals with Loewy structure and generating sets of S-circumflex and other associated modules. (author). 9 refs

  9. The computational optimization of heat exchange efficiency in stack chimneys

    Energy Technology Data Exchange (ETDEWEB)

    Van Goch, T.A.J.

    2012-02-15

    stack chimney heat exchanger is used for heating or cooling applications, what is the expected performance and how do the design parameters relate to this performance'. Simulation models were developed in the BPS tool ESP-r. The most important design parameters and their relative influence on the performance indicators were analysed based on sensitivity analysis (SA). From this analysis general design guidelines were derived ('optimal set of design parameters'). A multi objective optimization of the design parameters was performed on the simulation models, using the responsive surface methods and artificial neural network capabilities of optimization environment ModEContier to speed up the iteration process. In this optimization, 'heat exchange in stack chimneys is optimized annually'. The uncertainty in the optimized results has been analysed using uncertainty analysis (UA). Finally, the appropriateness of deploying a complex, high resolution simulation has been evaluated by studying current modelling resolution selection methodology found in literature.

  10. Diffusion of Nickel into Ferritic Steel Interconnects of Solid Oxide Fuel/Electrolysis Stacks

    DEFF Research Database (Denmark)

    Molin, Sebastian; Chen, Ming; Bowen, Jacob R.

    2013-01-01

    diffusion of nickel from the Ni/YSZ electrode or the contact layer into the interconnect plate. Such diffusion can cause austenization of the ferritic structure and could possibly alter corrosion properties of the steel. Whereas this process has already been recognized by SOFC stack developers, only...... a limited number of studies have been devoted to the phenomenon. Here, diffusion of Ni into ferritic Crofer 22 APU steel is studied in a wet hydrogen atmosphere after 250 hours of exposure at 800 °C using Ni-plated (~ 10 micron thick coatings) sheet steel samples as a model system. Even after...... this relatively short time all the metallic nickel in the coating has reacted and formed solid solutions with iron and chromium. Diffusion of Ni into the steel causes formation of the austenite FCC phase. The microstructure and composition of the oxide scale formed on the sample surface after 250 hours is similar...

  11. Structural Relations among Negative Affect, Mate Value, and Mating Effort

    Directory of Open Access Journals (Sweden)

    Beth Randi Kirsner

    2009-07-01

    Full Text Available We compared the ability of models based on evolutionary economic theory and Life History (LH Theory to explain relations among self-reported negative affect, mate value, and mating effort. Method: Two hundred thirty-eight undergraduates provided multiple measures of these latent constructs, permitting us to test a priori predictions based on Kirsner, Figueredo, and Jacobs (2003. We compared the fit of the initial model to the fit of five alternative theory-driven models using nested model comparisons of Structural Equations Models. Rejecting less parsimonious and explanatory models eliminated the original model. Two equally parsimonious models explained the data pattern well. The first, based on evolutionary economic theory, specified that Negative Affect increases both Personal Mate Value and Mating Effort via the direct effects specified in the original model. The second, based on LH Theory, specified that Negative Affect, Personal Mate Value, and Mating Effort relate spuriously through a common latent construct, the LH Factor. The primary limitation of the present study is generalizability. We used self-reports taken from a young, university-based sample that included a spectrum of affective states. We cannot know how well these models generalize to an older population or to actual behavior. Both models predict the presence of a rich pattern of mate acquisition and retention behaviors, including an alarming set of behavioral tactics often not considered or targeted during treatment. Moreover, each model suggests a unique set of problems may arise after an effective intervention. We describe several ways to distinguish these models empirically.

  12. Electronic structure of magnesium diboride and related compounds

    Energy Technology Data Exchange (ETDEWEB)

    Paduani, C. [Departamento de Fisica, Universidade Federal de Santa Catarina, UFSC, Florianopolis, CEP 88040-900, SC (Brazil)

    2003-11-01

    The electronic structure of AlB{sub 2}-type diborides and related compounds has been investigated in first-principles calculations with the molecular cluster discrete variational method. For MgB{sub 2} was studied the effect of the lattice relaxation on the total density of states at the Fermi energy (N({epsilon}{sub F})). The results indicated that a contraction of about 2% in the lattice spacings a and c can lead to a slight increase of N({epsilon}{sub F}) for boron. In the MB{sub 2} diborides, M=Al, Ti, V, Cr, Zr, Nb, Mo and Ta, the largest contributions to N({epsilon}{sub F}) is observed for Cr, Mo and Nb. TiB{sub 2} possess the highest chemical stability in the series. The electronic specific heat coefficient {gamma} also is calculated for the diborides. The method is employed to obtain the partial B2p contribution to the total DOS at the Fermi level with the introduction of a monolayer of solute atoms as a substitution for Mg atoms of Na, Al, Ca, Ti, V, Cr, Zr, Nb, Mo and Ta in layered superstructures.. /M/B{sub 2}/Mg/B{sub 2}/.. A stronger covalent bonding between boron atoms is identified in these cases. (copyright 2003 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  13. RELATION STRUCTURE/SOLUBILITE AQUEUSE DE HAP PRIORITAIRES

    Directory of Open Access Journals (Sweden)

    I TOUHAMI

    2009-06-01

    Full Text Available Une relation structure/solubilité aqueuse des HAP retenus comme prioritaires par l’agence environnementale américaine (US-EPA a été recherchée enfavorisant l’approche hybride algorithme génétique/régression multilinéaire, les paramètres structuraux étant calculés avec lelogiciel DRAGON. Parmi la centaine de modèles à 2 régresseurs obtenus nous avons sélectionné celui qui présente les meilleures valeurs du paramètre de prédiction (Q2 et du coefficient dedétermination (R2 : logS = 23,624- 8,6316 VEA1– 11,145 Kp ; n=15; ES= 0,464 ; Q2(%=98,38; R2(%=98,90 ;F=544,19 ; P=0,000. La première  variable explicative (VEA1 est associée aux propriétés locales d’une molécule, alorsque la seconde reflète sa forme globale.

  14. Electronic structure of magnesium diboride and related compounds

    International Nuclear Information System (INIS)

    Paduani, C.

    2003-01-01

    The electronic structure of AlB 2 -type diborides and related compounds has been investigated in first-principles calculations with the molecular cluster discrete variational method. For MgB 2 was studied the effect of the lattice relaxation on the total density of states at the Fermi energy (N(ε F )). The results indicated that a contraction of about 2% in the lattice spacings a and c can lead to a slight increase of N(ε F ) for boron. In the MB 2 diborides, M=Al, Ti, V, Cr, Zr, Nb, Mo and Ta, the largest contributions to N(ε F ) is observed for Cr, Mo and Nb. TiB 2 possess the highest chemical stability in the series. The electronic specific heat coefficient γ also is calculated for the diborides. The method is employed to obtain the partial B2p contribution to the total DOS at the Fermi level with the introduction of a monolayer of solute atoms as a substitution for Mg atoms of Na, Al, Ca, Ti, V, Cr, Zr, Nb, Mo and Ta in layered superstructures.. /M/B 2 /Mg/B 2 /.. A stronger covalent bonding between boron atoms is identified in these cases. (copyright 2003 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  15. Design and experimental characterization of a 350 W High Temperature PEM fuel cell stack

    Directory of Open Access Journals (Sweden)

    Nicola Zuliani

    2011-01-01

    Full Text Available High Temperature Proton Exchange Membrane (HT PEM fuel cell based on polybenzimidazole (PBI polymer and phosphoric acid, can be operated at temperature between 120 °C and 180 °C. Reactants humidification is not required and CO content up to 2% in the fuel can be tolerated, affecting only marginally performance. This is what makes HT PEM very attractive, as low quality reformed hydrogen can be used and water management problems are avoided. Till nowadays, from experimental point of view, only few studies relate to the development and characterization of high temperature stacks. The aim of this work is to present the main design features and the performance curves of a 25 cells HT PEM stack based on PBI and phosphoric acid membranes. Performance curves refer to the stack operating with two type of fuels: pure hydrogen and a gas mixture simulating a typical steam reformer output. The stack voltage distribution analysis and the stack temperature distribution analysis suggest that cathode air could be used as coolant leading to a better thermal management. This could simplify stack design and system BOP, thus increasing system performance.

  16. Efficient thin-film stack characterization using parametric sensitivity analysis for spectroscopic ellipsometry in semiconductor device fabrication

    International Nuclear Information System (INIS)

    Likhachev, D.V.

    2015-01-01

    During semiconductor device fabrication, control of the layer thicknesses is an important task for in-line metrology since the correct thickness values are essential for proper device performance. At the present time, ellipsometry is widely used for routine process monitoring and process improvement as well as characterization of various materials in the modern nanoelectronic manufacturing. The wide recognition of this technique is based on its non-invasive, non-intrusive and non-destructive nature, high measurement precision, accuracy and speed, and versatility to characterize practically all types of materials used in modern semiconductor industry (dielectrics, semiconductors, metals, polymers, etc.). However, it requires the use of one of the multi-parameter non-linear optimization methods due to its indirect nature. This fact creates a big challenge for analysis of multilayered structures since the number of simultaneously determined model parameters, for instance, thin film thicknesses and model variables related to film optical properties, should be restricted due to parameter cross-correlations. In this paper, we use parametric sensitivity analysis to evaluate the importance of various model parameters and to suggest their optimal search ranges. In this work, the method is applied practically for analysis of a few structures with up to five-layered film stack. It demonstrates an evidence-based improvement in accuracy of multilayered thin-film thickness measurements which suggests that the proposed approach can be useful for industrial applications. - Highlights: • An improved method for multilayered thin-film stack characterization is proposed. • The screening-type technique based on so-called “elementary effects” was employed. • The model parameters were ranked according to relative importance for model output. • The method is tested using two examples of complex thin-film stack characterization. • The approach can be useful in many practical

  17. Project W-420 Stack Monitoring system upgrades conceptual design report

    Energy Technology Data Exchange (ETDEWEB)

    TUCK, J.A.

    1998-11-06

    This document describes the scope, justification, conceptual design, and performance of Project W-420 stack monitoring system upgrades on six NESHAP-designated, Hanford Tank Farms ventilation exhaust stacks.

  18. Heuristic Solution Approaches to the Double TSP with Multiple Stacks

    DEFF Research Database (Denmark)

    Petersen, Hanne Løhmann

    This paper introduces the Double Travelling Salesman Problem with Multiple Stacks and presents a three different metaheuristic approaches to its solution. The Double Travelling Salesman Problem with Multiple Stacks is concerned with finding the shortest route performing pickups and deliveries...

  19. Heuristic Solution Approaches to the Double TSP with Multiple Stacks

    DEFF Research Database (Denmark)

    Petersen, Hanne Løhmann

    2006-01-01

    This paper introduces the Double Travelling Salesman Problem with Multiple Stacks and presents a three different metaheuristic approaches to its solution. The Double Travelling Salesman Problem with Multiple Stacks is concerned with finding the shortest route performing pickups and deliveries...

  20. Relations between constructive peculiarities and structural behavior in Venice buildings

    Directory of Open Access Journals (Sweden)

    Doglioni, F.

    2012-12-01

    Full Text Available Here we are synthetically describing some constructive peculiarities of Venice civil buildings, analyzing the relation with the features of their structural decay and behavior in the long run. We suppose Venetian buildings, especially those parts which are conceived to suit the lagoon environment, to have undergone an evolution made of some adjustments, which were based on the observation of damages in previous buildings. That is we suppose ancient builders to rely on their awareness of the behavior of structures yet to come, and to be able to forecast it in part. This process brought some building contrivances to perfection, as exclusive and enduring features of Venice, overcoming changes in style and architectural layout, till they grew into essential elements of a whole and adaptable “device”. This writing is meant for a concise interpretation of this device, which is the result of some research works carried out at Venice IUAV University.

    En este texto, se describen sintéticamente algunas peculiaridades de la edificación residencial de Venecia, analizando su relación con el abanico de problemas estructurales que caracterizan el comportamiento estructural del edificio a lo largo del tiempo. Se aventura la hipótesis que las construcciones venecianas y, en particular, algunos de sus detalles, concebidos específicamente para la laguna donde se enclava, han sido objeto de una adaptación evolutiva a través de la observación de los problemas estructurales de los edificios precedentes. Los alarifes venecianos aprendieron a tener en cuenta el comportamiento estructural posterior del edificio, que previeron en cierta medida. Este proceso ha llevado a perfeccionar algunos detalles constructivos exclusivos de Venecia que han perdurado en el tiempo, que han resistido impertérritos a mutaciones de estilo y de configuración arquitectónica, hasta constituir elementos esenciales de un aparato indivisible y adaptable cuya interpretaci

  1. Production and Reliability Oriented SOFC Cell and Stack Design

    DEFF Research Database (Denmark)

    Hauth, Martin; Lawlor, Vincent; Cartellieri, Peter

    2017-01-01

    established. The probabilistic models were related to the experimentally obtained properties of base materials to establish a statistical relationship between the material properties and the most relevant load effects. Software algorithms for meta models that allow the detection of relationships between input...... in production, material and operating parameters for the optimization phase. A methodology for 3D description of spatial distribution of material properties based on a random field models was developed and validated by experiments. Homogenized material models on multiple levels of the SOFC stack were...

  2. DEVS Models of Palletized Ground Stacking in Storeyed Grain Warehouse

    Directory of Open Access Journals (Sweden)

    Hou Shu-Yi

    2016-01-01

    Full Text Available Processed grain stored in storeyed warehouse is generally stacked on the ground without pallets. However, in order to improve the storing way, we developed a new stacking method, palletized ground stacking. Simulation should be used to present this new storing way. DEVS provides a formalized way to describe the system model. In this paper, DEVS models of palletized ground stacking in storeyed grain warehouse are given and a simulation model is developed by AutoMod.

  3. Stacking faults in (Ga,Mn)As and uniaxial magnetocrystalline anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Maca, Frantisek; Masek, Jan; Kopecky, Milos; Kub, Jiri; Jungwirth, Tomas [Institute of Physics ASCR, Praha (Czech Republic)

    2011-07-01

    The high resolution X-ray difraction measurements of (Ga,Mn)As and (Ga,Mn)(As,P) epilayers showed a structural anisotropy in the form of stacking faults which are present in the (1-11) and (111) planes and absent in the (-111) and (1-11) planes. Our full-potential density functional calculations explain the energetic preference of substitutional Mn to decorate the stacking faults. This preference energy is comparable with the formation energy of the faults in a pure GaAs. We surmise that the enhanced Mn density along the common [1-10] direction of the stacking fault planes represents the micro-structural origin of the in-plane uniaxial magnetocrystalline anisotropy of these semiconductors.

  4. Vibration Attenuation by a Combination of a Piezoelectric Stack and a Permanent Magnet

    Directory of Open Access Journals (Sweden)

    A. Nandi

    2012-01-01

    Full Text Available The present work proposes a non-contact vibration attenuator made up of a permanent magnet mounted on a piezoelectric stack. Two such actuators are made to work simultaneously in a 'twin-actuator' configuration. It is conceived that a controlled change in the gap between the actuator and the structure is capable of attenuation of vibration of the structure. This appropriate change in gap is achieved by controlled motion of the piezoelectric stacks. It is shown that the actuator works as an active damper when the extension and contraction of the actuators are made proportional to the velocity of the beam. The resolution of extension of a piezoelectric stack is in the order of nanometers. Thus in the proposed actuator the force of actuation can be applied with great precision. This actuator is also attractive for its simple constructional feature.

  5. On Relations Between Dump Truck Efficiency and Service Facilities Structure

    OpenAIRE

    Savchenko, A.A.; Zubariev, M.S.

    2015-01-01

    International audience; The analysis of dump truck fleet of the open-pit mine, which possesses industrial real estates for technical maintenance and other operations, is provided. Several exploitation indexes are defined and analyzed subject to the corresponding mine. Basing on the provided analysis, factors and conditions, which define the production facility structure, are described. A list of production facility structures is provided. The influence of production facility structure on dump...

  6. Sport stacking motor intervention programme for children with ...

    African Journals Online (AJOL)

    The purpose of this study was to explore sport stacking as an alternative intervention approach with typically developing children and in addition to improve DCD. Sport stacking consists of participants stacking and unstacking 12 specially designed plastic cups in predetermined sequences in as little time as possible.

  7. Notes on G-theory of Deligne-Mumford stacks

    OpenAIRE

    Toen, B.

    1999-01-01

    Based on the methods used by the author to prove the Riemann-Roch formula for algebraic stacks, this paper contains a description of the rationnal G-theory of Deligne-Mumford stacks over general bases. We will use these results to study equivariant K-theory, and also to define new filtrations on K-theory of algebraic stacks.

  8. Industrial stacks design; Diseno de chimeneas industriales

    Energy Technology Data Exchange (ETDEWEB)

    Cacheux, Luis [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1986-12-31

    The Instituto de Investigaciones Electricas (IIE) though its Civil Works Department, develops, under contract with CFE`s Gerencia de Proyectos Termoelectricos (Management of Fossil Power Plant Projects), a series of methods for the design of stacks, which pretends to solve the a present day problem: the stack design of the fossil power plants that will go into operation during the next coming years in the country. [Espanol] El Instituto de Investigaciones Electricas (IIE), a traves del Departamento de Ingenieria Civil, desarrolla, bajo contrato con la Gerencia de Proyectos Termoelectricos, de la Comision Federal de Electricidad (CFE), un conjunto de metodos para el diseno de chimeneas, con el que se pretende resolver un problema inmediato: el diseno de las chimeneas de las centrales termoelectricas que entraran en operacion durante los proximos anos, en el pais.

  9. Annular feed air breathing fuel cell stack

    Science.gov (United States)

    Wilson, Mahlon S.

    1996-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  10. Development of on-site PAFC stacks

    Energy Technology Data Exchange (ETDEWEB)

    Hotta, K.; Matsumoto, Y. [Kansai Electric Power Co., Amagasaki (Japan); Horiuchi, H.; Ohtani, T. [Mitsubishi Electric Corp., Kobe (Japan)

    1996-12-31

    PAFC (Phosphoric Acid Fuel Cell) has been researched for commercial use and demonstration plants have been installed in various sites. However, PAFC don`t have a enough stability yet, so more research and development must be required in the future. Especially, cell stack needs a proper state of three phases (liquid, gas and solid) interface. It is very difficult technology to keep this condition for a long time. In the small size cell with the electrode area of 100 cm{sup 2}, gas flow and temperature distributions show uniformity. But in the large size cell with the electrode area of 4000 cm{sup 2}, the temperature distributions show non-uniformity. These distributions would cause to be shorten the cell life. Because these distributions make hot-spot and gas poverty in limited parts. So we inserted thermocouples in short-stack for measuring three-dimensional temperature distributions and observed effects of current density and gas utilization on temperature.

  11. Seismic (SSE) evaluation for the 291Z stack at the Hanford Site -- Addition of environmental monitoring penetrations

    International Nuclear Information System (INIS)

    Baxter, J.T.

    1994-01-01

    The purpose of this 291Z stack analysis is to determine the structural effects of chipping additional holes into the stacks concrete walls. The proposed holes are for new environmental monitoring sample probes to be installed at three different elevations. The approximate elevations proposed at this time are 50 ft, 135 ft and 175 ft. There will be four holes required at each of the elevations to support two sample probes extending across the diameter of the stack. A structural sensitivity study has been completed to assess the effect of the proposed holes on the baseline seismic qualification of the stack completed by URS/John A. Blume ampersand Associates, Engineers, San Francisco, California (URS/Blume) in August, 1988. Results of the sensitivity study indicate that the stack would still have adequate structural moment capacity if the new holes were drilled cutting the vertical strength reinforcing steel, or if existing penetrations added since original construction have inadvertently cut vertical rebars. For current and future modifications, no vertical rebar should be cut. A limited number of horizontal rebar, no more than 2, may be cut at the new hole locations without significantly influencing the stack structural shear capacity. New penetrations in the 291Z stack should not be located below elevation 47 ft., 4 in. due to rebar layout and the fact that maximum seismic structural loads occur below this elevation. No vertical rebar should be cut when chipping the new penetrations in the stack concrete wall for the environmental monitoring equipment. Wind load qualification was reviewed. Seismic loads govern over wind loads for all structural load cases; therefore no additional wind analyses are required

  12. CAM and stack air sampler design guide

    International Nuclear Information System (INIS)

    Phillips, T.D.

    1994-01-01

    About 128 air samplers and CAMs presently in service to detect and document potential radioactive release from 'H' and 'F' area tank farm ventilation stacks are scheduled for replacement and/or upgrade by Projects S-5764, S-2081, S-3603, and S-4516. The seven CAMs scheduled to be upgraded by Project S-4516 during 1995 are expected to provide valuable experience for the three remaining projects. The attached document provides design guidance for the standardized High Level Waste air sampling system

  13. Contemporary sample stacking in analytical electrophoresis

    Czech Academy of Sciences Publication Activity Database

    Malá, Zdeňka; Gebauer, Petr; Boček, Petr

    2011-01-01

    Roč. 32, č. 1 (2011), s. 116-126 ISSN 0173-0835 R&D Projects: GA ČR GA203/08/1536; GA ČR GAP206/10/1219; GA AV ČR IAA400310703 Institutional research plan: CEZ:AV0Z40310501 Keywords : biological samples * stacking * trace analysis * zone electrophoresis Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 3.303, year: 2011

  14. Stacked Switched Capacitor Energy Buffer Architecture

    OpenAIRE

    Chen, Minjie; Perreault, David J.; Afridi, Khurram

    2012-01-01

    Electrolytic capacitors are often used for energy buffering applications, including buffering between single-phase ac and dc. While these capacitors have high energy density compared to film and ceramic capacitors, their life is limited. This paper presents a stacked switched capacitor (SSC) energy buffer architecture and some of its topological embodiments, which when used with longer life film capacitors overcome this limitation while achieving effective energy densities comparable to elect...

  15. Holomorphic curves in exploded manifolds: Kuranishi structure

    OpenAIRE

    Parker, Brett

    2013-01-01

    This paper constructs a Kuranishi structure for the moduli stack of holomorphic curves in exploded manifolds. To avoid some technicalities of abstract Kuranishi structures, we embed our Kuranishi structure inside a moduli stack of curves. The construction also works for the moduli stack of holomorphic curves in any compact symplectic manifold.

  16. Electronic structure of palladium and its relation to uv spectroscopy

    DEFF Research Database (Denmark)

    Christensen, N.E.

    1976-01-01

    The electronic-energy-band structure of palladium has been calculated by means of the relativistic augmented-plane-wave method covering energies up to 30 eV above the Fermi level. The optical interband transitions producing structure in the dielectric function up to photon energies of 25 eV have ...

  17. Factors related to the capital structure of small new ventures

    NARCIS (Netherlands)

    Harms, Rainer; Breitenecker, R.; Schwartz, E.J.; Wdowiak, M.A.

    2012-01-01

    In the literature, there exists evidence on the capital structure determinants for small ventures, but empirical research for new ventures is limited. We seek to address this gap by presenting a confirmatory analysis of determinants of capital structure of a sample of small new ventures in Austria.

  18. When is stacking confusing? The impact of confusion on stacking in deep H I galaxy surveys

    Science.gov (United States)

    Jones, Michael G.; Haynes, Martha P.; Giovanelli, Riccardo; Papastergis, Emmanouil

    2016-01-01

    We present an analytic model to predict the H I mass contributed by confused sources to a stacked spectrum in a generic H I survey. Based on the ALFALFA (Arecibo Legacy Fast ALFA) correlation function, this model is in agreement with the estimates of confusion present in stacked Parkes telescope data, and was used to predict how confusion will limit stacking in the deepest Square Kilometre Array precursor H I surveys. Stacking with LADUMA (Looking At the Distant Universe with MeerKAT) and DINGO UDEEP (Deep Investigation of Neutral Gas Origins - Ultra Deep) data will only be mildly impacted by confusion if their target synthesized beam size of 10 arcsec can be achieved. Any beam size significantly above this will result in stacks that contain a mass in confused sources that is comparable to (or greater than) that which is detectable via stacking, at all redshifts. CHILES (COSMOS H I Large Extragalactic Survey) 5 arcsec resolution is more than adequate to prevent confusion influencing stacking of its data, throughout its bandpass range. FAST (Five hundred metre Aperture Spherical Telescope) will be the most impeded by confusion, with H I surveys likely becoming heavily confused much beyond z = 0.1. The largest uncertainties in our model are the redshift evolution of the H I density of the Universe and the H I correlation function. However, we argue that the two idealized cases we adopt should bracket the true evolution, and the qualitative conclusions are unchanged regardless of the model choice. The profile shape of the signal due to confusion (in the absence of any detection) was also modelled, revealing that it can take the form of a double Gaussian with a narrow and wide component.

  19. Electrochemical Detection in Stacked Paper Networks.

    Science.gov (United States)

    Liu, Xiyuan; Lillehoj, Peter B

    2015-08-01

    Paper-based electrochemical biosensors are a promising technology that enables rapid, quantitative measurements on an inexpensive platform. However, the control of liquids in paper networks is generally limited to a single sample delivery step. Here, we propose a simple method to automate the loading and delivery of liquid samples to sensing electrodes on paper networks by stacking multiple layers of paper. Using these stacked paper devices (SPDs), we demonstrate a unique strategy to fully immerse planar electrodes by aqueous liquids via capillary flow. Amperometric measurements of xanthine oxidase revealed that electrochemical sensors on four-layer SPDs generated detection signals up to 75% higher compared with those on single-layer paper devices. Furthermore, measurements could be performed with minimal user involvement and completed within 30 min. Due to its simplicity, enhanced automation, and capability for quantitative measurements, stacked paper electrochemical biosensors can be useful tools for point-of-care testing in resource-limited settings. © 2015 Society for Laboratory Automation and Screening.

  20. Relation between native ensembles and experimental structures of proteins

    DEFF Research Database (Denmark)

    Best, R. B.; Lindorff-Larsen, Kresten; DePristo, M. A.

    2006-01-01

    Different experimental structures of the same protein or of proteins with high sequence similarity contain many small variations. Here we construct ensembles of "high-sequence similarity Protein Data Bank" (HSP) structures and consider the extent to which such ensembles represent the structural...... Data Bank ensembles; moreover, we show that the effects of uncertainties in structure determination are insufficient to explain the results. These results highlight the importance of accounting for native-state protein dynamics in making comparisons with ensemble-averaged experimental data and suggest...... heterogeneity of the native state in solution. We find that different NMR measurements probing structure and dynamics of given proteins in solution, including order parameters, scalar couplings, and residual dipolar couplings, are remarkably well reproduced by their respective high-sequence similarity Protein...

  1. Nature of low dimensional structural modulations and relative phase stability in RexMo(W)1-xS2 transition metal dichalcogenide alloys

    KAUST Repository

    Sahu, R.

    2017-03-08

    We report on the various types of Peierls like two dimensional structural modulations and relative phase stability of 2H and 1T poly-types in the RexMo1-xS2 and RexW1-xS2 alloy system. Theoretical calculation predicts a polytype phase transition cross over at ∼50 at. % of Mo and W in ReS2 in both monolayer and bulk form, respectively. Experimentally, two different types of structural modulations at 50% and a modulation corresponding to trimerization at 75% alloy composition are observed for RexMo1-xS2 and only one type of modulation is observed at the 50% RexW1-xS2 alloy system. The 50% alloy system is found to be a suitable monolithic candidate for metal semiconductor transition with minute external perturbation. ReS2 is known to be in the 2D Peierls distorted 1Td structure and forms a chain like superstructure. Incorporation of Mo and W atoms into the ReS2 lattice modifies the metal-metal hybridization between the cations and influences the structural modulation and electronic properties of the system. The results offer yet another effective way to tune the electronic structure and poly-type phases of this class of materials other than intercalation, strain, and vertical stacking arrangement.

  2. Morphology of OLED Film Stacks Containing Solution-Processed Phosphorescent Dendrimers.

    Science.gov (United States)

    McEwan, Jake A; Clulow, Andrew J; Nelson, Andrew; Jansen-van Vuuren, Ross D; Burn, Paul L; Gentle, Ian R

    2018-01-31

    Organic light-emitting devices containing solution-processed emissive dendrimers can be highly efficient. The most efficient devices contain a blend of the light-emitting dendrimer in a host and one or more charge-transporting layers. Using neutron reflectometry measurements with in situ photoluminescence, we have investigated the structure of the as-formed film as well as the changes in film structure and dendrimer emission under thermal stress. It was found that the as-formed film stacks comprising poly(3,4-ethylenedioxythiophene):polystyrene sulfonate/host:dendrimer/1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene (where the host was deuterated 4,4'-N,N'-di(carbazolyl)biphenyl or tris(4-carbazol-9-ylphenyl)amine, the host:dendrimer layer was solution-processed, and the 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene evaporated) had well-defined interfaces, indicating good wetting of each of the layers by the subsequently deposited layer. Upon thermal annealing, there was no change in the poly(3,4-ethylenedioxythiophene):polystyrene sulfonate/host:dendrimer interface, but once the temperature reached above the T g of the host:dendrimer layer, it became a supercooled liquid into which 1,3,5-tris(N-phenylbenzimidazol-2-yl)benzene dissolved. When the film stacks were held at a temperature just above the onset of the diffusion process, they underwent an initial relatively fast diffusion process before reaching a quasi-stable state at that temperature.

  3. The structure of the pelagic food web in relation to water column structure in the Skagerrak

    DEFF Research Database (Denmark)

    Kiørboe, Thomas; Kaas, H.; Kruse, B.

    1990-01-01

    by a doming of the pycnocline, with a deep mixed layer along the periphery and a very shallow pycnocline in central parts. Average phytoplankton size increased with the depth of the upper mixed layer, and the central stratified area was characterized by small flagellates while large and chain-forming diatoms...... on particle surface area rather than particle volume or chl a, and showed a distributional pattern that was nearly the inverse of the distribution of copepod activity. That is, peak bacterial growth rates occurred in central, stratified parts and lower rates were found along the margin with a deep mixed layer....... Thus a 'microbial loop' type of food web seemed to be evolving in the central, strongly stratified parts of the Skagerrak, while a shorter 'classical' type of food web appeared to dominate along the margin. The relation between food web structure and vertical mixing processes observed on oceanwide...

  4. Improvements in or relating to the inspection of underwater structures

    International Nuclear Information System (INIS)

    Caldecourt, L.R.; Evans, G.V.; Parsons, T.V.

    1980-01-01

    A radiation detector is described, for use in the inspection of underwater structures, which is capable of withstanding high pressures and arduous marine conditions. The ingress of water into the body of the radiation detector tube is prevented by the use of a resilient waterproof compound. Marine structures incorporating such radiation detectors are described, whereby the presence or density of flowing cement grout in the legs of an offshore platform may be determined. (U.K.)

  5. About Hierarchical XML Structures, Replacement of Relational Data Structures in Construction and Implementation of ERP Systems

    Directory of Open Access Journals (Sweden)

    2007-01-01

    Full Text Available The projects essential objective is to develop a new ERP system, of homogeneous nature, based on XML structures, as a possible replacement for classic ERP systems. The criteria that guide the objective definition are modularity, portability and Web connectivity. This objective is connected to a series of secondary objectives, considering that the technological approach will be filtered through the economic, social and legislative environment for a validation-by-context study. Statistics and cybernetics are to be used for simulation purposes. The homogeneous approach is meant to provide strong modularity and portability, in relation with the n-tier principles, but the main advantage of the model is its opening to the semantic Web, based on a Small enterprise ontology defined with XML-driven languages. Shockwave solutions will be used for implementing client-oriented hypermedia elements and an XML Gate will be de-fined between black box modules, for a clear separation with obvious advantages. Security and the XMLTP project will be an important issue for XML transfers due to the conflict between the open architecture of the Web, the readability of XML data and the privacy elements which have to be preserved within a business environment. The projects finality is oriented on small business but the semantic Web perspective and the surprising new conflict between hierarchical/network data structures and relational ones will certainly widen its scope. The proposed model is meant to fulfill the IT compatibility requirements of the European environment, defined as a knowledge society. The paper is a brief of the contributions of the team re-search at the project type A applied to CNCSIS "Research on the Role of XML in Building Extensible and Homogeneous ERP Systems".

  6. Functional clustering in hippocampal cultures: relating network structure and dynamics

    International Nuclear Information System (INIS)

    Feldt, S; Dzakpasu, R; Olariu, E; Żochowski, M; Wang, J X; Shtrahman, E

    2010-01-01

    In this work we investigate the relationship between gross anatomic structural network properties, neuronal dynamics and the resultant functional structure in dissociated rat hippocampal cultures. Specifically, we studied cultures as they developed under two conditions: the first supporting glial cell growth (high glial group), and the second one inhibiting it (low glial group). We then compared structural network properties and the spatio-temporal activity patterns of the neurons. Differences in dynamics between the two groups could be linked to the impact of the glial network on the neuronal network as the cultures developed. We also implemented a recently developed algorithm called the functional clustering algorithm (FCA) to obtain the resulting functional network structure. We show that this new algorithm is useful for capturing changes in functional network structure as the networks evolve over time. The FCA detects changes in functional structure that are consistent with expected dynamical differences due to the impact of the glial network. Cultures in the high glial group show an increase in global synchronization as the cultures age, while those in the low glial group remain locally synchronized. We additionally use the FCA to quantify the amount of synchronization present in the cultures and show that the total level of synchronization in the high glial group is stronger than in the low glial group. These results indicate an interdependence between the glial and neuronal networks present in dissociated cultures

  7. Opposing effects of stacking faults and antisite domain boundaries on the conduction band edge in kesterite quaternary semiconductors

    Science.gov (United States)

    Park, Ji-Sang; Kim, Sunghyun; Walsh, Aron

    2018-01-01

    We investigated stability and the electronic structure of extended defects including antisite domain boundaries and stacking faults in the kesterite-structured semiconductors, Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe). Our hybrid density functional theory calculations show that stacking faults in CZTS and CZTSe induce a higher conduction band edge than the bulk counterparts, and thus the stacking faults act as electron barriers. Antisite domain boundaries, however, accumulate electrons as the conduction band edge is reduced in energy, having an opposite role. An Ising model was constructed to account for the stability of stacking faults, which shows the nearest-neighbor interaction is stronger in the case of the selenide.

  8. Evaluation of a stack: A concrete chimney with brick liner

    International Nuclear Information System (INIS)

    Joshi, J.R.; Amin, J.A.; Porthouse, R.A.

    1995-01-01

    A 200 ft. tall stack, consisting of a concrete chimney with an independent acid proof brick liner built in the 1950's, serving the Separations facility at the Savannah River Site (SRS), was evaluated for the performance category 3 (PC3) level of Natural Phenomena Hazards (NPH) effects. The inelastic energy absorption capacity of the concrete chimney was considered in the evaluation of the earthquake resistance, in particular, to compute the F μ factor. The calculated value of F μ exceeded 3.0, while the seismic demand for the PC3 level, using an F μ value of 1.5, was found to be less than the capacity of the concrete chimney. The capacity formulation of ACI 307 was modified to incorporate the effect of an after design opening on the tension side. There are considerable uncertainties in determining the earthquake resistance of the independent brick liner. The critical liner section, located at the bottom of the breeching opening, does not meet the current recommendations. A discussion is provided for the possible acceptable values for the ''Moment Reduction Factor'', R w or F μ for the liner. Comments are provided on the comparison of stack demands using response spectra (RS) versus time history (TH) analysis, with and without soil structure interaction (SSI) effects

  9. Interface band alignment in high-k gate stacks

    Science.gov (United States)

    Eric, Bersch; Hartlieb, P.

    2005-03-01

    In order to successfully implement alternate high-K dielectric materials into MOS structures, the interface properties of MOS gate stacks must be better understood. Dipoles that may form at the metal/dielectric and dielectric/semiconductor interfaces make the band offsets difficult to predict. We have measured the conduction and valence band densities of states for a variety MOS stacks using in situ using inverse photoemission (IPE) and photoemission spectroscopy (PES), respectively. Results obtained from clean and metallized (with Ru or Al) HfO2/Si, SiO2/Si and mixed silicate films will be presented. IPE indicates a shift of the conduction band minimum (CBM) to higher energy (i.e. away from EF) with increasing SiO2. The effect of metallization on the location of band edges depends upon the metal species. The addition of N to the dielectrics shifts the CBM in a way that is thickness dependent. Possible mechanisms for these observed effects will be discussed.

  10. The Subwavelength Optical Field Confinement in a Multilayered Microsphere with Quasiperiodic Spherical Stack

    Directory of Open Access Journals (Sweden)

    Gennadiy N. Burlak

    2008-01-01

    Full Text Available We study the frequency spectrum of nanoemitters placed in a microsphere with a quasiperiodic subwavelength spherical stack. The spectral evolution of transmittancy at the change of thickness of two-layer blocks, constructed following the Fibonacci sequence, is investigated. When the number of layers (Fibonacci order increases, the structure of spectrum acquires a fractal form. Our calculations show the radiation confinement and gigantic field enhancement, when the ratio of layers’ widths in twolayer blocks of the stack is close to the golden mean value.

  11. Synthesis and characterization of straight and stacked-sheet AlN nanowires with high purity

    International Nuclear Information System (INIS)

    Lei, M.; Yang, H.; Li, P.G.; Tang, W.H.

    2008-01-01

    Large-scale AlN nanowires with hexagonal crystal structure were synthesized by the direct nitridation method at high temperatures. The experimental results indicate that these single-crystalline AlN nanowires have high purity and consist of straight and stacked-sheet nanowires. It is found that straight AlN nanowire grows along [1, 1, -2, 0] direction, whereas the stacked-sheet nanowire with hexagonal cross section is along [0 0 0 1] direction. It is thought that vapor-solid (VS) mechanism should be responsible for the growth of AlN nanowires

  12. Species distribution modelling for plant communities: Stacked single species or multivariate modelling approaches?

    Science.gov (United States)

    Emilie B. Henderson; Janet L. Ohmann; Matthew J. Gregory; Heather M. Roberts; Harold S.J. Zald

    2014-01-01

    Landscape management and conservation planning require maps of vegetation composition and structure over large regions. Species distribution models (SDMs) are often used for individual species, but projects mapping multiple species are rarer. We compare maps of plant community composition assembled by stacking results from many SDMs with multivariate maps constructed...

  13. Optical necklaces generated by the diffraction on a stack of dielectric wedges

    Energy Technology Data Exchange (ETDEWEB)

    Izdebskaya, Yana [Nonlinear Physics Centre, Research School of Physical Sciences and Engineering, Australian National University, Canberra ACT 0200 (Australia); Department of Physics, V.I. Vernandsky Taurida National University, Simferopol 95007, Crimea (Ukraine)], E-mail: yvi124@rsphysse.anu.edu.au

    2008-05-19

    We demonstrate that the regular ring-shaped arrays of Gaussian beams, or optical necklaces, can be generated using diffraction on a stack of dielectric wedges. A condition for self-similarity and structural stability of the beams has been derived and shows good comparison with experimental data.

  14. Ab initio study of antiphase boundaries and stacking faults in L12 and DO22 compounds

    DEFF Research Database (Denmark)

    Rosengaard, N. M.; Skriver, Hans Lomholt

    1994-01-01

    We have performed ab initio calculations of the energies of antiphase boundaries as well as complex and superlattice intrinsic stacking faults in nine intermetallic compounds observed in the face-centered-cubic L1(2) and DO22 structures. The calculations were performed by means of a Green...

  15. HfO2/Pr2O3 gate dielectric stacks

    Science.gov (United States)

    Sidorov, F.; Molchanova, A.; Rogozhin, A.

    2016-12-01

    Electrical properties of MOS structures based on molecular beam epitaxy formed HfO2/Pr2O3 gate dielectric stacks have been studied by CV, GV and IV characteristics. Electrical properties of the structures with HfO2/Pr2O3 and PEALD HfO2 dielectric layers were compared. Higher gate leakage current and lower interface trap level density in the structure with HfO2/Pr2O3 dielectric layer was observed.

  16. Variable Geometry Aircraft Pylon Structure and Related Operation Techniques

    Science.gov (United States)

    Shah, Parthiv N. (Inventor)

    2014-01-01

    An aircraft control structure can be utilized for purposes of drag management, noise control, or aircraft flight maneuvering. The control structure includes a high pressure engine nozzle, such as a bypass nozzle or a core nozzle of a turbofan engine. The nozzle exhausts a high pressure fluid stream, which can be swirled using a deployable swirl vane architecture. The control structure also includes a variable geometry pylon configured to be coupled between the nozzle and the aircraft. The variable geometry pylon has a moveable pylon section that can be deployed into a deflected state to maintain or alter a swirling fluid stream (when the swirl vane architecture is deployed) for drag management purposes, or to assist in the performance of aircraft flight maneuvers.

  17. Parsimonious or Profligate: How Many and Which Discourse Structure Relations?

    Science.gov (United States)

    1992-08-01

    34* relation type: either additive or causal; "* pragmatic : specifying whether the relation conveys some illocutionary meaning; "* basic order...ARGUMENT - CLAIM is defined as follows: Name: NEGATIVE ARGUMENT - CLAIM Definition: causal, +basic-order, -+- pragmatic , -polarity Example: 1. Although it is...textual relations are used to form the discourse into a coherent whole, determining pronouns and other anaphora usage or linearizing sequences of topics

  18. State Confessional Relations: Problem of the Subject Structure

    OpenAIRE

    Alexandra A. Dorskaya

    2014-01-01

    In the article various existing definitions of the concept "state and confessional relations" are analyzed, also author's definition is offered. Three levels of the state and confessional relations are revealed: conceptual, legislative and administrative-managerial. In the article it is shown that in Russia a tradition of only two subjects of the state and confessional relations – government bodies and the religious organizations allocation exists. It is revealed that at the present stage man...

  19. High power multiple wavelength diode laser stack for DPSSL application without temperature control

    Science.gov (United States)

    Hou, Dong; Yin, Xia; Wang, Jingwei; Chen, Shi; Zhan, Yun; Li, Xiaoning; Fan, Yingmin; Liu, Xingsheng

    2018-02-01

    High power diode laser stack is widely used in pumping solid-state laser for years. Normally an integrated temperature control module is required for stabilizing the output power of solid-state laser, as the output power of the solid-state laser highly depends on the emission wavelength and the wavelength shift of diode lasers according to the temperature changes. However the temperature control module is inconvenient for this application, due to its large dimension, high electric power consumption and extra adding a complicated controlling system. Furthermore, it takes dozens of seconds to stabilize the output power when the laser system is turned on. In this work, a compact hard soldered high power conduction cooled diode laser stack with multiple wavelengths is developed for stabilizing the output power of solid-state laser in a certain temperature range. The stack consists of 5 laser bars with the pitch of 0.43mm. The peak output power of each bar in the diode laser stack reaches as much as 557W and the combined lasing wavelength spectrum profile spans 15nm. The solidstate laser, structured with multiple wavelength diode laser stacks, allows the ambient temperature change of 65°C without suddenly degrading the optical performance.

  20. Online estimation of internal stack temperatures in solid oxide fuel cell power generating units

    Science.gov (United States)

    Dolenc, B.; Vrečko, D.; Juričić, Ɖ.; Pohjoranta, A.; Pianese, C.

    2016-12-01

    Thermal stress is one of the main factors affecting the degradation rate of solid oxide fuel cell (SOFC) stacks. In order to mitigate the possibility of fatal thermal stress, stack temperatures and the corresponding thermal gradients need to be continuously controlled during operation. Due to the fact that in future commercial applications the use of temperature sensors embedded within the stack is impractical, the use of estimators appears to be a viable option. In this paper we present an efficient and consistent approach to data-driven design of the estimator for maximum and minimum stack temperatures intended (i) to be of high precision, (ii) to be simple to implement on conventional platforms like programmable logic controllers, and (iii) to maintain reliability in spite of degradation processes. By careful application of subspace identification, supported by physical arguments, we derive a simple estimator structure capable of producing estimates with 3% error irrespective of the evolving stack degradation. The degradation drift is handled without any explicit modelling. The approach is experimentally validated on a 10 kW SOFC system.

  1. Entropy and biological systems: experimentally-investigated entropy-driven stacking of plant photosynthetic membranes.

    Science.gov (United States)

    Jia, Husen; Liggins, John R; Chow, Wah Soon

    2014-02-24

    According to the Second Law of Thermodynamics, an overall increase of entropy contributes to the driving force for any physicochemical process, but entropy has seldom been investigated in biological systems. Here, for the first time, we apply Isothermal Titration Calorimetry (ITC) to investigate the Mg(2+)-induced spontaneous stacking of photosynthetic membranes isolated from spinach leaves. After subtracting a large endothermic interaction of MgCl₂ with membranes, unrelated to stacking, we demonstrate that the enthalpy change (heat change at constant pressure) is zero or marginally positive or negative. This first direct experimental evidence strongly suggests that an entropy increase significantly drives membrane stacking in this ordered biological structure. Possible mechanisms for the entropy increase include: (i) the attraction between discrete oppositely-charged areas, releasing counterions; (ii) the release of loosely-bound water molecules from the inter-membrane gap; (iii) the increased orientational freedom of previously-aligned water dipoles; and (iv) the lateral rearrangement of membrane components.

  2. Interface Optoelectronics Engineering for Mechanically Stacked Tandem Solar Cells Based on Perovskite and Silicon.

    Science.gov (United States)

    Kanda, Hiroyuki; Uzum, Abdullah; Nishino, Hitoshi; Umeyama, Tomokazu; Imahori, Hiroshi; Ishikawa, Yasuaki; Uraoka, Yukiharu; Ito, Seigo

    2016-12-14

    Engineering of photonics for antireflection and electronics for extraction of the hole using 2.5 nm of a thin Au layer have been performed for two- and four-terminal tandem solar cells using CH 3 NH 3 PbI 3 perovskite (top cell) and p-type single crystal silicon (c-Si) (bottom cell) by mechanically stacking. Highly transparent connection multilayers of evaporated-Au and sputtered-ITO films were fabricated at the interface to be a point-contact tunneling junction between the rough perovskite and flat silicon solar cells. The mechanically stacked tandem solar cell with an optimized tunneling junction structure was ⟨perovskite for the top cell/Au (2.5 nm)/ITO (154 nm) stacked-on ITO (108 nm)/c-Si for the bottom cell⟩. It was confirmed the best efficiency of 13.7% and 14.4% as two- and four-terminal devices, respectively.

  3. A polymer electrolyte fuel cell stack for stationary power generation from hydrogen fuel

    Energy Technology Data Exchange (ETDEWEB)

    Gottesfeld, S. [Los Alamos National Lab., NM (United States)

    1995-09-01

    The fuel cell is the most efficient device for the conversion of hydrogen fuel to electric power. As such, the fuel cell represents a key element in efforts to demonstrate and implement hydrogen fuel utilization for electric power generation. The low temperature, polymer electrolyte membrane fuel cell (PEMFC) has recently been identified as an attractive option for stationary power generation, based on the relatively simple and benign materials employed, the zero-emission character of the device, and the expected high power density, high reliability and low cost. However, a PEMFC stack fueled by hydrogen with the combined properties of low cost, high performance and high reliability has not yet been demonstrated. Demonstration of such a stack will remove a significant barrier to implementation of this advanced technology for electric power generation from hydrogen. Work done in the past at LANL on the development of components and materials, particularly on advanced membrane/electrode assemblies (MEAs), has contributed significantly to the capability to demonstrate in the foreseeable future a PEMFC stack with the combined characteristics described above. A joint effort between LANL and an industrial stack manufacturer will result in the demonstration of such a fuel cell stack for stationary power generation. The stack could operate on hydrogen fuel derived from either natural gas or from renewable sources. The technical plan includes collaboration with a stack manufacturer (CRADA). It stresses the special requirements from a PEMFC in stationary power generation, particularly maximization of the energy conversion efficiency, extension of useful life to the 10 hours time scale and tolerance to impurities from the reforming of natural gas.

  4. A new method for the characterisation and quantitative speciation of base metal smelter stack particulates.

    Science.gov (United States)

    Skeaff, James M; Thibault, Yves; Hardy, David J

    2011-06-01

    Base metal smelters may be a source of particulates containing metals of environmental concern released to the atmosphere. Knowledge of the quantitative chemical speciation of particulate releases from base metal smelters will be of value in smelter emission fingerprinting, site-specific risk assessments, predictions of the behaviour of smelter stack particulates released to the environment and in resolving liability issues related to current and historic releases. Accordingly, we have developed an innovative approach comprising bulk chemical analysis, a leaching procedure, X-ray diffraction analysis and scanning electron microscopy/electron probe microanalysis characterisation in a step-wise apportioning procedure to derive the quantitative speciation of particulate samples from the stacks of three copper smelters designated as A, B and C. For the A smelter stack particulates, the major calculated percentages were 29 CuSO(4), 20 ZnSO(4).H(2)O, 13 (Cu(0.94)Zn(0.06))(2)(AsO(4))(OH), 11 PbSO(4) and four As(2)O(3). For the B smelter stack particulates, the primary calculated percentages were 20 ZnSO(4).H(2)O, 20 PbSO(4), 12 CuSO(4) and nine As(2)O(3). Finally, we calculated that the C smelter stack particulates mostly comprised 34 ZnSO(4).H(2)O, 19 (Cu(0.84)Zn(0.16))(AsO(3)OH), 11 PbSO(4), 10 As(2)O(3) and nine Zn(3)(AsO(4))(2). Between 56% and 67% by weight of the smelter stack particulates, including the As, was soluble in water. For these and other operations, the data and approach may be useful in estimating metals partitioning among water, soil and sediment, as well as predictions of the effects of the stack particulates released to the environment.

  5. Protein quaternary structure and aggregation in relation to allergenicity

    NARCIS (Netherlands)

    Boxtel, van E.L.

    2007-01-01

    In order to induce systemic food allergic reactions in humans, proteins after digestion in the human gastro-intestinal tract should still be able to bind IgE. The aim of the work presented in this thesis was to determine the effects of heating on the structure and digestibility of cupin and prolamin

  6. Structural Relations among Spirituality, Religiosity, and Thriving in Adolescence

    Science.gov (United States)

    Dowling, Elizabeth M.; Gestsdottir, Steinunn; Anderson, Pamela M.; Von Eye, Alexander; Almerigi, Jason; Lerner, Richard M.

    2004-01-01

    Using the randomly selected subsample of 1,000 youth (472 boys, M age = 12.2 years, SD = 1.5; 528 girls, M age = 12.1 years, SD = 1.4) drawn by Dowling, Getsdottir, Anderson, von Eye, and Lerner (in press) from a Search Institute (1984) archival data set, Young Adolescents and Their Parents (YAP), this research employed structural equation…

  7. Website on Protein Interaction and Protein Structure Related Work

    Science.gov (United States)

    Samanta, Manoj; Liang, Shoudan; Biegel, Bryan (Technical Monitor)

    2003-01-01

    In today's world, three seemingly diverse fields - computer information technology, nanotechnology and biotechnology are joining forces to enlarge our scientific knowledge and solve complex technological problems. Our group is dedicated to conduct theoretical research exploring the challenges in this area. The major areas of research include: 1) Yeast Protein Interactions; 2) Protein Structures; and 3) Current Transport through Small Molecules.

  8. Relating methanogen community structure and anaerobic digester function.

    Science.gov (United States)

    Bocher, B T W; Cherukuri, K; Maki, J S; Johnson, M; Zitomer, D H

    2015-03-01

    Much remains unknown about the relationships between microbial community structure and anaerobic digester function. However, knowledge of links between community structure and function, such as specific methanogenic activity (SMA) and COD removal rate, are valuable to improve anaerobic bioprocesses. In this work, quantitative structure-activity relationships (QSARs) were developed using multiple linear regression (MLR) to predict SMA using methanogen community structure descriptors for 49 cultures. Community descriptors were DGGE demeaned standardized band intensities for amplicons of a methanogen functional gene (mcrA). First, predictive accuracy of MLR QSARs was assessed using cross validation with training (n = 30) and test sets (n = 19) for glucose and propionate SMA data. MLR equations correlating band intensities and SMA demonstrated good predictability for glucose (q(2) = 0.54) and propionate (q(2) = 0.53). Subsequently, data from all 49 cultures were used to develop QSARs to predict SMA values. Higher intensities of two bands were correlated with higher SMA values; high abundance of methanogens associated with these two bands should be encouraged to attain high SMA values. QSARs are helpful tools to identify key microorganisms or to study and improve many bioprocesses. Development of new, more robust QSARs is encouraged for anaerobic digestion or other bioprocesses, including nitrification, nitritation, denitrification, anaerobic ammonium oxidation, and enhanced biological phosphorus removal. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Structure-Function Relations in Physiology Education: Where's the Mechanism?

    Science.gov (United States)

    Lira, Matthew E.; Gardner, Stephanie M.

    2017-01-01

    Physiology demands systems thinking: reasoning within and between levels of biological organization and across different organ systems. Many physiological mechanisms explain how structures and their properties interact at one level of organization to produce emergent functions at a higher level of organization. Current physiology principles, such…

  10. AN ASSESSMENT OF STRUCTURAL TRAPS IN RELATION TO ...

    African Journals Online (AJOL)

    In this study, the stress conditions that resulted in the formation of these structural trapping elements are examined. This is to assess their capabilities for petroleum entrapment/retention. The normal faults generally have steep gradient planes, originate within the basement rocks and terminate below the unconformity surface ...

  11. Moisture barrier evaluation of SiO{sub x}/SiN{sub x} stacks on polyimide substrates using electrical calcium test

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Shiyu; Xue, Wei; Yu, Zhinong, E-mail: znyu@bit.edu.cn

    2015-04-01

    Electrical calcium (Ca) test was used to measure water vapor transmission rate (WVTR) through polyimide (PI) substrate with barrier films. The WVTR was obtained by measuring the resistance of the Ca as a function of time. Barrier films consisted of silicon oxide (SiO{sub x})/silicon nitride (SiN{sub x}) stacks were consecutively deposited onto the PI substrate at 350 °C by plasma-enhanced chemical vapor deposition. SiN{sub x} and SiO{sub x} films show great moisture impermeability while the SiN{sub x} film presented higher moisture resistance than the SiO{sub x} film. The sample of PI coated with SiO{sub x}/SiN{sub x} stacks was kept flat by stress compensation of SiN{sub x} film and SiO{sub x} film. The WVTR value of the optimum barrier structure (5 pairs of SiO{sub x}/SiN{sub x}) is 5.58 × 10{sup −6} g/(m{sup 2} day) under an electrical Ca test (25 °C, 40% relative humidity). After 500 times cyclic bending in a compressive mode, WVTR value keeps below 4.32 × 10{sup −5} g/(m{sup 2} day). The SiO{sub x}/SiN{sub x} barrier stacks presented on PI have a great potential for flexible electronics applications. - Highlights: • The electrical Ca test was used to measure water vapor transmission rate. • SiO{sub x}/SiN{sub x} stacks as diffusion barrier of water vapor are effective. • The optimum barrier structure is 5 pairs of SiO{sub x}/SiN{sub x}.

  12. Physical relativity. Space-time structure from a dynamical perspective

    Science.gov (United States)

    Brown, Harvey R.

    Physical Relativity explores the nature of the distinction at the heart of Einstein's 1905 formulation of his special theory of relativity: that between kinematics and dynamics. Einstein himself became increasingly uncomfortable with this distinction, and with the limitations of what he called the 'principle theory' approach inspired by the logic of thermodynamics. A handful of physicists and philosophers have over the last century likewise expressed doubts about Einstein's treatment of the relativistic behaviour of rigid bodies and clocks in motion in the kinematical part of his great paper, and suggested that the dynamical understanding of length contraction and time dilation intimated by the immediate precursors of Einstein is more fundamental. Harvey Brown both examines and extends these arguments (which support a more 'constructive' approach to relativistic effects in Einstein's terminology), after giving a careful analysis of key features of the pre-history of relativity theory. He argues furthermore that the geometrization of the theory by Minkowski in 1908 brought illumination, but not a causal explanation of relativistic effects. Finally, Brown tries to show that the dynamical interpretation of special relativity defended in the book is consistent with the role this theory must play as a limiting case of Einstein's 1915 theory of gravity: the general theory of relativity. Appearing in the centennial year of Einstein's celebrated paper on special relativity, Physical Relativity is an unusual, critical examination of the way Einstein formulated his theory. It also examines in detail certain specific historical and conceptual issues that have long given rise to debate in both special and general relativity theory, such as the conventionality of simultaneity, the principle of general covariance, and the consistency or otherwise of the special theory with quantum mechanics. Harvey Brown's new interpretation of relativity theory will interest anyone working on

  13. Improved Direct Methanol Fuel Cell Stack

    Science.gov (United States)

    Wilson, Mahlon S.; Ramsey, John C.

    2005-03-08

    A stack of direct methanol fuel cells exhibiting a circular footprint. A cathode and anode manifold, tie-bolt penetrations and tie-bolts are located within the circular footprint. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet and outlet cathode manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold, where the serpentine channels of the anode are orthogonal to the serpentine channels of the cathode. Located between the two plates is the fuel cell active region.

  14. Compliant Glass Seals for SOFC Stacks

    Energy Technology Data Exchange (ETDEWEB)

    Chou, Yeong -Shyung [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Choi, Jung-Pyung [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Xu, Wei [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Stephens, Elizabeth V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Koeppel, Brian J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Stevenson, Jeffry W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lara-Curzio, Edgar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2014-04-30

    This report summarizes results from experimental and modeling studies performed by participants in the Solid-State Energy Conversion Alliance (SECA) Core Technology Program, which indicate that compliant glass-based seals offer a number of potential advantages over conventional seals based on de-vitrifying glasses, including reduced stresses during stack operation and thermal cycling, and the ability to heal micro-damage induced during thermal cycling. The properties and composition of glasses developed and/or investigated in these studies are reported, along with results from long-term (up to 5,800h) evaluations of seals based on a compliant glass containing ceramic particles or ceramic fibers.

  15. Analysis of NSTX Upgrade OH Magnet and Center Stack

    Energy Technology Data Exchange (ETDEWEB)

    A. Zolfaghari, P. Titus, J. Chrzanowski, A. Salehzadeh, F. Dahlgren

    2010-11-30

    The new ohmic heating (OH) coil and center stack for the National Spherical Torus Experiment (NSTX) upgrade are required to meet cooling and structural requirements for operation at the enhanced 1 Tesla toroidal field and 2 MA plasma current. The OH coil is designed to be cooled in the time between discharges by water flowing in the center of the coil conductor. We performed resistive heating and thermal hydraulic analyses to optimize coolant channel size to keep the coil temperature below 100 C and meet the required 20 minute cooling time. Coupled electromagnetic, thermal and structural FEA analyses were performed to determine if the OH coil meets the requirements of the structural design criteria. Structural response of the OH coil to its self-field and the field from other coils was analyzed. A model was developed to analyze the thermal and electromagnetic interaction of centerstack components such as the OH coil, TF inner legs and the Bellville washer preload mechanism. Torsional loads from the TF interaction with the OH and poloidal fields are transferred through the TF flag extensions via a torque transfer coupling to the rest of the tokamak structure. A 3D FEA analysis was performed to qualify this design. The results of these analyses, which will be presented in this paper, have led to the design of OH coil and centerstack components that meet the requirements of the NSTX-upgrade structural design criteria.

  16. Refinement of numerical models and parametric study of SOFC stack performance

    Science.gov (United States)

    Burt, Andrew C.

    The presence of multiple air and fuel channels per fuel cell and the need to combine many cells in series result in complex steady-state temperature distributions within Solid Oxide Fuel Cell (SOFC) stacks. Flow distribution in these channels, when non-uniform, has a significant effect on cell and stack performance. Large SOFC stacks are very difficult to model using full 3-D CFD codes because of the resource requirements needed to solve for the many scales involved. Studies have shown that implementations based on Reduced Order Methods (ROM), if calibrated appropriately, can provide simulations of stacks consisting of more than 20 cells with reasonable computational effort. A pseudo 2-D SOFC stack model capable of studying co-flow and counter-flow cell geometries was developed by solving multiple 1-D SOFC single cell models in parallel on a Beowulf cluster. In order to study cross-flow geometries a novel Multi-Component Multi-Physics (MCMP) scheme was instantiated to produce a Reduced Order 3-D Fuel Cell Model. A C++ implementation of the MCMP scheme developed in this study utilized geometry, control volume, component, and model structures allowing each physical model to be solved only for those components for which it is relevant. Channel flow dynamics were solved using a 1-D flow model to reduce computational effort. A parametric study was conducted to study the influence of mass flow distribution, radiation, and stack size on fuel cell stack performance. Using the pseudo 2-D planar SOFC stack model with stacks of various sizes from 2 to 40 cells it was shown that, with adiabatic wall conditions, the asymmetry of the individual cell can produce a temperature distribution where high and low temperatures are found in the top and bottom cells, respectively. Heat transfer mechanisms such as radiation were found to affect the reduction of the temperature gradient near the top and bottom cell. Results from the reduced order 3-D fuel cell model showed that greater

  17. Using computational models to relate structural and functional brain connectivity

    Czech Academy of Sciences Publication Activity Database

    Hlinka, Jaroslav; Coombes, S.

    2012-01-01

    Roč. 36, č. 2 (2012), s. 2137-2145 ISSN 0953-816X R&D Projects: GA MŠk 7E08027 EU Projects: European Commission(XE) 200728 - BRAINSYNC Institutional research plan: CEZ:AV0Z10300504 Keywords : brain disease * computational modelling * functional connectivity * graph theory * structural connectivity Subject RIV: FH - Neurology Impact factor: 3.753, year: 2012

  18. Electrochemical study of two structurally related compounds and ...

    Indian Academy of Sciences (India)

    D Saritha

    2018-02-01

    Feb 1, 2018 ... for Li ion batteries J. Power Sources 168 509. 27. Wang X, Heier K R, Stern C L and Poeppelmeier K. R 1998 Crystal structure and raman spectroscopy of. FeVMoO7 and CrVMoO7 with Mo=O double bonds. Inorg. Chem. 37 3252. 28. MasquelierC,PadhiAK,NajundaswamyKSandGood- enough J B 1998 ...

  19. Structure-property relations in amorphous carbon for photovoltaics

    International Nuclear Information System (INIS)

    Risplendi, Francesca; Cicero, Giancarlo; Bernardi, Marco; Grossman, Jeffrey C.

    2014-01-01

    Carbon is emerging as a material with great potential for photovoltaics (PV). However, the amorphous form (a-C) has not been studied in detail as a PV material, even though it holds similarities with amorphous Silicon (a-Si) that is widely employed in efficient solar cells. In this work, we correlate the structure, bonding, stoichiometry, and hydrogen content of a-C with properties linked to PV performance such as the electronic structure and optical absorption. We employ first-principles molecular dynamics and density functional theory calculations to generate and analyze a set of a-C structures with a range of densities and hydrogen concentrations. We demonstrate that optical and electronic properties of interest in PV can be widely tuned by varying the density and hydrogen content. For example, sunlight absorption in a-C films can significantly exceed that of a same thickness of a-Si for a range of densities and H contents in a-C. Our results highlight promising features of a-C as the active layer material of thin-film solar cells.

  20. Structure of Clavicle In Relation to Weight Transmission

    Science.gov (United States)

    Routatal, Rohini V

    2015-01-01

    Aims and Objectives It is a known fact that weight of upper limb is transmitted to the axial skeleton through clavicle. The present study is an attempt to correlate pattern of compact and trabecular bone of clavicle as a weight transmitting bone. Materials and Methods Sixty clavicles were studied from right and left sides of 30 cadavers donated to the Anatomy department, Pramukhswami Medical College, Karamsad, India. The study was focused on the thickness of compact bone of clavicle and trabecular pattern of this bone. Results Cancellous bone: Cancellous bone near both ends of clavicle presented meshwork of thin bony plates. Between the conoid tubercle and area for attachment of costo-clavicular ligament, cancellous bone showed a definite pattern. Thickness of compact bone The compact bone was thicker between conoid tubercle and area for attachment of costo-clavicular ligament. At midshaft point thickness of compact bone was maximum. Conclusion The structure of clavicle between conoid tubercle and area for costoclavicular ligament showed thick compact bone and definite pattern of cancellous bone. This structure of clavicle between conoid tubercle and area for attachment of costo-clavicular ligament transmits weight from lateral to medial direction and this knowledge of clavicular structure will also be useful to orthopedic surgeons to deal with clavicular fractures and other abnormalities. PMID:26393112

  1. Sampled-time control of a microbial fuel cell stack

    Science.gov (United States)

    Boghani, Hitesh C.; Dinsdale, Richard M.; Guwy, Alan J.; Premier, Giuliano C.

    2017-07-01

    Research into microbial fuel cells (MFCs) has reached the point where cubic metre-scale systems and stacks are being built and tested. Apart from performance enhancement through catalysis, materials and design, an important research area for industrial applicability is stack control, which can enhance MFCs stack power output. An MFC stack is controlled using a sampled-time digital control strategy, which has the advantage of intermittent operation with consequent power saving, and when used in a hybrid series stack connectivity, can avoid voltage reversals. A MFC stack comprising four tubular MFCs was operated hydraulically in series. Each MFC was connected to an independent controller and the stack was connected electrically in series, creating a hybrid-series connectivity. The voltage of each MFC in the stack was controlled such that the overall series stack voltage generated was the algebraic sum (1.26 V) of the individual MFC voltages (0.32, 0.32, 0.32 and 0.3). The controllers were able to control the individual voltages to the point where 2.52 mA was drawn from the stack at a load of 499.9 Ω (delivering 3.18 mW). The controllers were able to reject the disturbances and perturbations caused by electrical loading, temperature and substrate concentration.

  2. Topography of neurovascular structures in relation to round window and how it relates to cochlear implantation.

    Science.gov (United States)

    Singla, Anjali; Gupta, Tulika; Sahni, Daisy; Gupta, Ashok Kumar; Aggarwal, Anjali

    2017-12-01

    The purpose of this investigation was to evaluate the distances and angles on basal turn of cochlea in relation to round window at which the jugular bulb, internal carotid artery and facial nerve are at maximal risk and their implications in cochlear implantation (CI). Fifty-four cadaveric temporal bones were microdissected to expose the basal turn of cochlea, the carotid canal, the facial canal and the jugular fossa. The points were marked on the basal turn of cochlea, where there was minimum distance of basal turn of cochlea from the roof of the jugular fossa (point a), carotid canal (point b) and facial canal (point c). The distances and angles of these points from the round window were measured. The points a, b and c were at mean (range) distances of 2.8 mm (1.3-4.1 mm), 8.4 mm (6.5-10.4 mm) and 16.4 mm (12.5-20.5 mm) and at mean angles of 30° (15°-45°), 111° (71°-136°) and 284° (255°-315°), respectively, from the round window. This study highlights that 2.8 ± 0.5 mm (30 ± 5.40), 8.4 ± 1 mm (111 ± 12.70) and 16.4 ± 1.7 mm (284 ± 13.5) from the round window are the high-risk points on the basal turn of the cochlea for the jugular bulb, internal carotid artery and facial nerve, respectively. A wide range found for each parameter indicates that it is mandatory to evaluate these distances in each CI patient on preoperative radiographs to avoid intraoperative injury to these vital structures.

  3. Frequency domain method for the stack of seismic and radar data

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, H.; Sato, M. [Tohoku University, Sendai (Japan); Xu, S.

    1997-10-22

    With relation to the stacking method of elastic wave and radar wave, the frequency domain stacking method using the Fourier conversion was proposed as a method for automatically removing errors in time correction leaving advantages of the conventional horizontal stacking method. Concerning an example of wave motion with the same wave form and time difference, as a result of the analysis conducted by this method, it was found that not only effects are kept of suppressing random noise and regular noise in the conventional horizontal stacking method, but the resolution in the original wave motion data is kept. In the example, amplitude of the noise was a half of the wave motion signal, but if it is more than 0.85 times of the wave motion signal, favorable result cannot be obtained in this method. In the analysis in the area where time correction is very difficult and the correction cannot be made completely, it is useful also for the time domain stacking method to acquire data on high resolution of elastic wave and radar wave. 4 refs., 2 figs.

  4. Relation between structure and organisation properties of new amphiphilic cyclodextrins

    International Nuclear Information System (INIS)

    Moutard, Stephane

    2003-01-01

    Since a number of years, special attention and efforts have been made to prepare amphiphilic cyclodextrins (CDs) with the objective to use them to obtain supramolecular assemblies as such or in the presence of preformed lipidic structures. The aim of these investigation is in both cases to combine the size specificity of cyclodextrins for guests and the transport properties of phospho-lipidic structures. The final objects could be of importance to transport or target biologically relevant molecules such as drugs using new galenic formulations. In a first step, a new family of amphiphilic CDs was prepared from a pure phospholipids (DMPE) onto cyclodextrins or methylated derivatives through a spacing arm. The afforded compounds (phospholipidyl-cyclodextrins) were fully characterized by high field NMR and high resolution mass spectrometry. The methylated derivatives were shown to self-organize in water with low CMC to form fluctuating micellar fibers retaining the inclusion capacity of the cyclodextrin cavities. The interactions of these compounds with membrane systems were investigated as black films using X-ray reflectivity and by evaluation of their detergent power towards model DMPC liposomes. Their ability to cross over the Blood Brain Barrier was evidenced by a new approach making use of novel immuno-enzymatic assays. In a second step, a new class of amphiphilic cyclodextrins was considered (peptidolipidyl-cyclodextrins). Although they are structurally similar to phospholipidyl-CDs, their preparation overcomes the tedious steps of the later and lead to a considerable versatility in terms of the number of possible molecules to be prepared. Moreover, the stability problems encountered with phospholipids are avoided. Several examples have been prepared, fully characterized and their organization properties investigated by the determination of CMC and by deuterium NMR on a pure and homogeneous mixed peptidolipidyl-CD / DMPC lamellar phase. This novel class of

  5. Physical relativity space-time structure from a dynamical perspective

    CERN Document Server

    Brown, Harvey R

    2005-01-01

    Physical Relativity explores the nature of the distinction at the heart of Einstein's 1905 formulation of his special theory of relativity: that between kinematics and dynamics. Einstein himself became increasingly uncomfortable with this distinction, and with the limitations of what he called the 'principle theory' approach inspired by the logic of thermodynamics. A handful of physicists and philosophers have over the last century likewise expressed doubts about Einstein'streatment of the relativistic behaviour of rigid bodies and clocks in motion in the kinematical part of his great paper, a

  6. AC impedance diagnosis of a 500 W PEM fuel cell stack . Part I: Stack impedance

    Science.gov (United States)

    Yuan, Xiaozi; Sun, Jian Colin; Blanco, Mauricio; Wang, Haijiang; Zhang, Jiujun; Wilkinson, David P.

    Diagnosis of stack performance is of importance to proton exchange membrane (PEM) fuel cell research. This paper presents the diagnostic testing results of a 500 W Ballard Mark V PEM fuel cell stack with an active area of 280 cm 2 by electrochemical impedance spectroscopy (EIS). The EIS was measured using a combination of a FuelCon test station, a TDI loadbank, and a Solartron 1260 Impedance/Gain-Phase Analyzer operating in the galvanostatic mode. The method described in this work can obtain the impedance spectra of fuel cells with a larger geometric surface area and power, which are normally difficult to measure due to the limitations on commercial load banks operating at high currents. By using this method, the effects of temperature, flow rate, and humidity on the stack impedance spectra were examined. The results of the electrochemical impedance analysis show that with increasing temperature, the charge transfer resistance decreases due to the slow oxygen reduction reaction (ORR) process at low temperature. If the stack is operated at a fixed air flow rate, a low frequency arc appears and grows with increasing current due to the shortage of air. The anode humidification cut-off does not affect the spectra compared to the cut-off for cathode humidification.

  7. Structures and related properties of helical, disulfide-stabilized peptides

    Energy Technology Data Exchange (ETDEWEB)

    Pagel, Mark D. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry

    1993-11-01

    The three dimensional structure of several peptides were determined by NMR spectroscopy and distance geometry calculations. Each peptide formed a predictable, rigid structure, consisting of an α-helix, a "scaffold" region which packed along one face of the helix, and two disulfide bridges which covalently connect the helix and scaffold regions. The peptide Apa-M5 was designed to constrain the M5 peptide from MLCK in a helical geometry using the apamin disulfide scaffold. This scaffold constrains the N- terminal end of the helix with two disulfide bridges and a reverse turn. Like the M5 peptide, Apa-M5 was found to bind calmodulin in a Ca2+-dependent 1:1 stoichiometry. However, the dissociation constant of the (Apa-M5)-calmodulin complex, 107 nM, was 100-fold higher than the dissociation constant of the M5-calmodulin complex. This difference was due to a putative steric overlap between the Apa-M5 scaffold and calmodulin. The peptide Apa-Cro was designed to replace the large structural protein matrix of λ Cro with the apamin disulfide scaffold. However, Apa-Cro did not bind the consensus DNA operator half-site of λ Cro, probably due to a steric overlap between the Apa-Cro disulfide framework and the DNA. The amino acid sequence of the scaffold-disulfide bridge arrangement of the peptide Max was derived from the core sequence of scyllatoxin, which contains an α-helix constrained at the C-terminal end by two disulfide bridges and a two-stranded βsheet scaffold. Max was shown to fold with >84% yield to form a predictable, stable structure that is similar to scyllatoxin. The folding and stability properties of Max make this scaffold and disulfide bridge arrangement an ideal candidate for the development of hybrid sequence peptides. The dynamics of a fraying C-terminal end of the helix of the peptide Apa-AlaN was determined by analysis of 15N NMR relaxation properties.

  8. Relation of plasma flow structures to passive particle tracer orbits

    Science.gov (United States)

    García, L.; Carreras, B. A.; Llerena, I.

    2017-11-01

    The properties of plasma flow topological structures are compared with those of passive tracer particles within a framework of the continuous random walk (CTRW) approach. Vortices may cause some of the trapping of particles, while large scale flows may carry them from vortex to vortex. The results indicate that most of the trappings that are completed during the calculation correspond to tracers trapped on broken filaments, including possible multiple trappings. The probability distribution function of the trapping times is then a function of the filament length, and has a lognormal character, like the distribution of filament lengths.

  9. An open-source wireless sensor stack: from Arduino to SDI-12 to Water One Flow

    Science.gov (United States)

    Hicks, S.; Damiano, S. G.; Smith, K. M.; Olexy, J.; Horsburgh, J. S.; Mayorga, E.; Aufdenkampe, A. K.

    2013-12-01

    Implementing a large-scale streaming environmental sensor network has previously been limited by the high cost of the datalogging and data communication infrastructure. The Christina River Basin Critical Zone Observatory (CRB-CZO) is overcoming the obstacles to large near-real-time data collection networks by using Arduino, an open source electronics platform, in combination with XBee ZigBee wireless radio modules. These extremely low-cost and easy-to-use open source electronics are at the heart of the new DIY movement and have provided solutions to countless projects by over half a million users worldwide. However, their use in environmental sensing is in its infancy. At present a primary limitation to widespread deployment of open-source electronics for environmental sensing is the lack of a simple, open-source software stack to manage streaming data from heterogeneous sensor networks. Here we present a functioning prototype software stack that receives sensor data over a self-meshing ZigBee wireless network from over a hundred sensors, stores the data locally and serves it on demand as a CUAHSI Water One Flow (WOF) web service. We highlight a few new, innovative components, including: (1) a versatile open data logger design based the Arduino electronics platform and ZigBee radios; (2) a software library implementing SDI-12 communication protocol between any Arduino platform and SDI12-enabled sensors without the need for additional hardware (https://github.com/StroudCenter/Arduino-SDI-12); and (3) 'midStream', a light-weight set of Python code that receives streaming sensor data, appends it with metadata on the fly by querying a relational database structured on an early version of the Observations Data Model version 2.0 (ODM2), and uses the WOFpy library to serve the data as WaterML via SOAP and REST web services.

  10. Stray field interaction of stacked amorphous tapes

    International Nuclear Information System (INIS)

    Guenther, Wulf; Flohrer, Sybille

    2008-01-01

    In this study, magnetic cores made of amorphous rectangular tape layers are investigated. The quality factor Q of the tape material decreases rapidly, however, when stacking at least two tape layers. The hysteresis loop becomes non-linear, and the coercivity increases. These effects are principally independent of the frequency and occur whether tape layers are insulated or not. The Kerr-microscopy was used to monitor local hysteresis loops by varying the distance of two tape layers. The magnetization direction of each magnetic domain is influenced by the anisotropy axis, the external magnetic field and the stray field of magnetic domains of the neighboring tape layers. We found that crossed easy axes (as the extreme case for inclined axes) of congruent domains retain the remagnetization and induce a plateau of the local loop. Summarizing local loops leads to the observed increase of coercivity and non-linearity of the inductively measured loop. A high Q-factor can be preserved if the easy axes of stacked tape layers are identical within the interaction range in the order of mm

  11. Annular feed air breathing fuel cell stack

    Science.gov (United States)

    Wilson, Mahlon S.; Neutzler, Jay K.

    1997-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  12. Stacking Analysis of Binary Systems with HAWC

    Science.gov (United States)

    Brisbois, Chad; HAWC Collaboration

    2017-01-01

    Detecting binary systems at TeV energies is an important problem because only a handful of such systems are currently known. The nature of such systems is typically thought to be composed of a compact object and a massive star. The TeV emission from these systems does not obviously correspond to emission in GeV or X-ray, where many binary systems have previously been found. This study focuses on a stacking method to detect TeV emission from LS 5039, a known TeV binary, to test its efficacy in HAWC data. Stacking is a widely employed method for increasing signal to noise ratio in optical astronomy, but has never been attempted previously with HAWC. HAWC is an ideal instrument to search for TeV binaries, because of its wide field of view and high uptime. Applying this method to the entire sky may allow HAWC to detect binary sources of very short or very long periods not sensitive to current analyses. NSF, DOE, Los Alamos, Michigan Tech, CONACyt, UNAM, BUAP.

  13. High performance zinc air fuel cell stack

    Science.gov (United States)

    Pei, Pucheng; Ma, Ze; Wang, Keliang; Wang, Xizhong; Song, Mancun; Xu, Huachi

    2014-03-01

    A zinc air fuel cell (ZAFC) stack with inexpensive manganese dioxide (MnO2) as the catalyst is designed, in which the circulation flowing potassium hydroxide (KOH) electrolyte carries the reaction product away and acts as a coolant. Experiments are carried out to investigate the characteristics of polarization, constant current discharge and dynamic response, as well as the factors affecting the performance and uniformity of individual cells in the stack. The results reveal that the peak power density can be as high as 435 mW cm-2 according to the area of the air cathode sheet, and the influence factors on cell performance and uniformity are cell locations, filled state of zinc pellets, contact resistance, flow rates of electrolyte and air. It is also shown that the time needed for voltages to reach steady state and that for current step-up or current step-down are both in milliseconds, indicating the ZAFC can be excellently applied to vehicles with rapid dynamic response demands.

  14. Computerized plutonium laboratory-stack monitoring system

    International Nuclear Information System (INIS)

    Stafford, R.G.; DeVore, R.K.

    1977-01-01

    The Los Alamos Scientific Laboratory has recently designed and constructed a Plutonium Research and Development Facility to meet design criteria imposed by the United States Energy Research and Development Administration. A primary objective of the design criteria is to assure environmental protection and to reliably monitor plutonium effluent via the ventilation exhaust systems. A state-of-the-art facility exhaust air monitoring system is described which establishes near ideal conditions for evaluating plutonium activity in the stack effluent. Total and static pressure sensing manifolds are incorporated to measure average velocity and integrated total discharge air volume. These data are logged at a computer which receives instrument data through a multiplex scanning system. A multipoint isokinetic sampling assembly with associated instrumentation is described. Continuous air monitors have been designed to sample from the isokinetic sampling assembly and transmit both instantaneous and integrated stack effluent concentration data to the computer and various cathode ray tube displays. The continuous air monitors also serve as room air monitors in the plutonium facility with the primary objective of timely evacuation of personnel if an above tolerance airborne plutonium concentration is detected. Several continuous air monitors are incorporated in the ventilation system to assist in identification of release problem areas

  15. Multi-channel temperature measurement system for automotive battery stack

    Science.gov (United States)

    Lewczuk, Radoslaw; Wojtkowski, Wojciech

    2017-08-01

    A multi-channel temperature measurement system for monitoring of automotive battery stack is presented in the paper. The presented system is a complete battery temperature measuring system for hybrid / electric vehicles that incorporates multi-channel temperature measurements with digital temperature sensors communicating through 1-Wire buses, individual 1-Wire bus for each sensor for parallel computing (parallel measurements instead of sequential), FPGA device which collects data from sensors and translates it for CAN bus frames. CAN bus is incorporated for communication with car Battery Management System and uses additional CAN bus controller which communicates with FPGA device through SPI bus. The described system can parallel measure up to 12 temperatures but can be easily extended in the future in case of additional needs. The structure of the system as well as particular devices are described in the paper. Selected results of experimental investigations which show proper operation of the system are presented as well.

  16. The importance of building downwash in assessing the need to heighten stacks of existing small and medium sized industries

    Energy Technology Data Exchange (ETDEWEB)

    Gomes, J.F.P. [Centro de Tecnologias Ambientais, ISQ - Inst. de Soldadura e Qualidade, Oeiras (Portugal); Duarte, R. [Escola Superior de Tecnologia - Inst. Politecnico de Setubal (Portugal)

    2004-07-01

    This extended abstract intends to share the authors experience on the modelling of atmospheric pollutant dispersal and on the importance of building downwash considerations when assessing the need to heighten stacks of small and medium sized industrial enterprises (SME's). In order to understand the reasons that make industrial companies, especially SME's, consider stack heightening, in section 2 the existing Portuguese legislation on air quality and the stack heightening rules are briefly commented. New legislation that ought to appear soon (new Portuguese Air Act) is also commented and compared critically with the existing one. Then, section 3 characterizes Portuguese industry in terms of the ambient quality problems related to stack height. The adequacy of the stack heightening legislation to the particularities of the Portuguese case is discussed. In section 4 the authors experience in the specific study of stack heightening is presented. The methodology considered in these studies is discussed and compared with the application of existing and soon to appear legislation on stack height calculation. Finally, section 5 presents the conclusions and the need for an increased awareness on the pollutant dispersal problem is discussed. (orig.)

  17. Plants with stacked genetically modified events: to assess or not to assess?

    Science.gov (United States)

    Kok, Esther J; Pedersen, Jan; Onori, Roberta; Sowa, Slawomir; Schauzu, Marianna; De Schrijver, Adinda; Teeri, Teemu H

    2014-02-01

    The principles for the safety assessment of genetically modified (GM) organisms (GMOs) are harmonised worldwide to a large extent. There are, however, still differences between the European GMO regulations and the GMO regulations as they have been formulated in other parts of the world. One of these differences relates to the so-called 'stacked GM events', that is, GMOs, plants so far, where new traits are combined by conventional crossing of different GM plants. This paper advocates rethinking the current food/feed safety assessment of stacked GM events in Europe based on an analysis of different aspects that currently form the rationale for the safety assessment of stacked GM events. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. ejIP: A TCP/IP Stack for Embedded Java

    DEFF Research Database (Denmark)

    Schoeberl, Martin

    2011-01-01

    To enable Java on resource constraint embedded devices, the whole system should be implemented in a single programming language to avoid overheads on language boundaries. However, most of the functionality that is dedicated to the operating system layer is usually written in C. In this paper we...... present the design and implementation of a network stack written entirely in Java. This implementation serves as an example how to implement system functions in a safe language and gives evidence that Java can be used for operating system related functionality. The described TCP/IP stack ejIP has already...... been successfully used in industrial projects on pure Java embedded systems....

  19. [Detection of recombinant-DNA in foods from stacked genetically modified plants].

    Science.gov (United States)

    Sorokina, E Iu; Chernyshova, O N

    2012-01-01

    A quantitative real-time multiplex polymerase chain reaction method was applied to the detection and quantification of MON863 and MON810 in stacked genetically modified maize MON 810xMON 863. The limit of detection was approximately 0,1%. The accuracy of the quantification, measured as bias from the accepted value and the relative repeatability standard deviation, which measures the intra-laboratory variability, were within 25% at each GM-level. A method verification has demonstrated that the MON 863 and the MON810 methods can be equally applied in quantification of the respective events in stacked MON810xMON 863.

  20. Multilayer Strip Dipole Antenna Using Stacking Technique and Its Application for Curved Surface

    Directory of Open Access Journals (Sweden)

    Charinsak Saetiaw

    2013-01-01

    Full Text Available This paper presents the design of multilayer strip dipole antenna by stacking a flexible copper-clad laminate utilized for curved surface on the cylindrical objects. The designed antenna will reduce the effects of curving based on relative lengths that are changed in each stacking flexible copper-clad laminate layer. Curving is different from each layer of the antenna, so the resonance frequency that resulted from an extended antenna provides better frequency response stability compared to modern antenna when it is curved or attached to cylindrical objects. The frequency of multilayer antenna is designed at 920 MHz for UHF RFID applications.

  1. Broadband infrared photoluminescence in silicon nanowires with high density stacking faults.

    Science.gov (United States)

    Li, Yang; Liu, Zhihong; Lu, Xiaoxiang; Su, Zhihua; Wang, Yanan; Liu, Rui; Wang, Dunwei; Jian, Jie; Lee, Joon Hwan; Wang, Haiyan; Yu, Qingkai; Bao, Jiming

    2015-02-07

    Making silicon an efficient light-emitting material is an important goal of silicon photonics. Here we report the observation of broadband sub-bandgap photoluminescence in silicon nanowires with a high density of stacking faults. The photoluminescence becomes stronger and exhibits a blue shift under higher laser powers. The super-linear dependence on excitation intensity indicates a strong competition between radiative and defect-related non-radiative channels, and the spectral blue shift is ascribed to the band filling effect in the heterostructures of wurtzite silicon and cubic silicon created by stacking faults.

  2. Description of gasket failure in a 7 cell PEMFC stack

    Energy Technology Data Exchange (ETDEWEB)

    Husar, Attila; Serra, Maria [Institut de Robotica i Informatica Industrial, Parc Tecnologic de Barcelona, Edifici U, C. Llorens i Artigas, 4-6, 2a Planta, 08028 Barcelona (Spain); Kunusch, Cristian [Laboratorio de Electronica Industrial Control e Instrumentacion, Facultad de Ingenieria, UNLP (Argentina)

    2007-06-10

    This article presents the data and the description of a fuel cell stack that failed due to gasket degradation. The fuel cell under study is a 7 cell stack. The unexpected change in several variables such as temperature, pressure and voltage indicated the possible failure of the stack. The stack was monitored over a 6 h period in which data was collected and consequently analyzed to conclude that the fuel cell stack failed due to a crossover leak on the anode inlet port located on the cathode side gasket of cell 2. This stack failure analysis revealed a series of indicators that could be used by a super visional controller in order to initiate a shutdown procedure. (author)

  3. Relating secondary structure to the mechanical properties of polypeptide hydrogels

    Science.gov (United States)

    Hagan, Sharon Anne

    Biomimetic hydrogels are being developed for use in medicine as drug delivery devices and tissue engineering matrices, and the mechanical properties of the materials play an important role in their performance. For example, in tissue engineering, gene expression and cell adhesion have been closely linked to the mechanical properties of the surrounding hydrogel matrix. In poly-L-lysine hydrogels, a five-fold increase in storage modulus, a 50% increase in equilibrium modulus, and a 62% decrease in swelling degree are shown to occur as the hydrogel network chains transition from an alpha-helix to a beta-sheet conformation. The manipulation of the network's mechanical behavior through changes in the secondary structure of the polymer chains offers an additional design variable in the development of biosynthetic materials. Analogous to poly-L-lysine, elastin-mimetic proteins based on the consensus repeat sequence of elastin (VPGVG) undergo a temperature-dependent secondary structure transition from a random coil to a beta-spiral. In this research, chemically-crosslinked poly[(VPGVG)4(VPGKG)] hydrogels are shown to possess temperature- and pH-dependent swelling. Following scaling law predictions (G ˜ φ2n), the hydrogels have been shown to behave as ideal elastic networks when the crosslink density is varied at synthesis (theory: n = 9/4, experimental: n = 2.0 +/- 0.1), and behave as flexible networks above and below their structural transition temperature of 35°C (theory: n = 1/3, experimental: n = 0.45 +/- 0.06). Evaluation of published data on elastin-mimetic hydrogels shows that the hydrogels behave as ideal elastic networks for all crosslinking techniques, crosslink spacings, and crosslink functionalities reported. As a contrast to chemically-crosslinked hydrogels, a novel elastin-mimetic triblock (EMT) copolymer was evaluated because of its potential use in cell encapsulation without potentially harmful side reactions. Unlike other thermally gelling copolymers

  4. Issues related to choosing a guard force structure

    International Nuclear Information System (INIS)

    Averbach, C.; Cusack, J.; Green, L.; Higinbotham, W.; Indusi, J.; Marcuse, W.; Weinstock, E.

    1975-01-01

    The establishment of a federal security force has been suggested as an additional step to protect nuclear material. The force would be given the responsibility for guarding nuclear facilities and shipments of nuclear materials. A study to identify the issues that are relevant to choosing between the private guard forces that are presently employed by industry or a guard force under federal authority is summarized. To examine the issues which would be relevant, three possible types of security force structures were selected for comparison: a federal force under central authority, a private guard force employed by or under contract to a facility, and a private arrangement to employ local police officers similar to the arrangement for armed guards at airports. The issues were divided into seven categories: (1) legal considerations, (2) liability, (3) staffing and operations, (4) costs, (5) relationship to off-site forces, (6) management and control, and (7) transportation. (U.S.)

  5. Graphene controlled H- and J-stacking of perylene dyes into highly stable supramolecular nanostructures for enhanced photocurrent generation

    Science.gov (United States)

    Gan, Shiyu; Zhong, Lijie; Engelbrekt, Christian; Zhang, Jingdong; Han, Dongxue; Ulstrup, Jens; Chi, Qijin; Niu, Li

    2014-08-01

    We report a new method for controlling H- and J-stacking in supramolecular self-assembly. Graphene nanosheets act as structure inducers to direct the self-assembly of a versatile organic dye, perylene into two distinct types of functional nanostructures, i.e. one-dimensional nanotubes via J-stacking and two-dimensional branched nanobuds through H-stacking. Graphene integrated supramolecular nanocomposites are highly stable and show significant enhancement of photocurrent generation in these two configurations of photosensing devices, i.e. solid-state optoelectronic constructs and liquid-junction solar cells.We report a new method for controlling H- and J-stacking in supramolecular self-assembly. Graphene nanosheets act as structure inducers to direct the self-assembly of a versatile organic dye, perylene into two distinct types of functional nanostructures, i.e. one-dimensional nanotubes via J-stacking and two-dimensional branched nanobuds through H-stacking. Graphene integrated supramolecular nanocomposites are highly stable and show significant enhancement of photocurrent generation in these two configurations of photosensing devices, i.e. solid-state optoelectronic constructs and liquid-junction solar cells. Electronic supplementary information (ESI) available: Material and methods, spectroscopic data, AFM and TEM images, materials functional tests and supplementary discussions. See DOI: 10.1039/c4nr02308k

  6. Use of impedance tagging to monitor fuel cell stack performance

    Science.gov (United States)

    Silva, Gregory

    Fuel cells are electrochemical device that are traditionally assembled in stacks to perform meaningful work. Monitoring the state of the stack is vitally important to ensure that it is operating efficiently and that constituent cells are not failing for one of a several common reasons including membrane dehydration, gas diffusion layer flooding, reactant starvation, and physical damage. Current state-of-the-art monitoring systems are costly and require at least one connection per cell on the stack, which introduces reliability concerns for stacks consisting of hundreds of cells. This thesis presents a novel approach for diagnosing problems in a fuel cell stack that attempts to reduce the cost and complexity of monitoring cells in a stack. The proposed solution modifies the electrochemical impedance spectroscopy (EIS) response of each cell in the stack by connecting an electrical tag in parallel with each cell. This approach allows the EIS response of the entire stack to identify and locate problems in the stack. Capacitors were chosen as tags because they do not interfere with normal stack operation and because they can generate distinct stack EIS responses. An experiment was performed in the Center for Automation Technologies an Systems (CATS) fuel cell laboratory at Rensselaer Polytechnic Institute (RPI) to perform EIS measurements on a single cell with and without capacitor tags to investigate the proposed solution. The EIS data collected from this experiment was used to create a fuel cell model to investigate the proposed solution under ideal conditions. This thesis found that, although the concept shows some promise in simulations, significant obstacles to implementing the proposed solution. Observed EIS response when the capacitor tags were connected did not match the expected EIS response. Constraints on the capacitor tags found by the model impose significant manufacturing challenges to the proposed solution. Further development of the proposed solution is

  7. Stacked Heterogeneous Neural Networks for Time Series Forecasting

    Directory of Open Access Journals (Sweden)

    Florin Leon

    2010-01-01

    Full Text Available A hybrid model for time series forecasting is proposed. It is a stacked neural network, containing one normal multilayer perceptron with bipolar sigmoid activation functions, and the other with an exponential activation function in the output layer. As shown by the case studies, the proposed stacked hybrid neural model performs well on a variety of benchmark time series. The combination of weights of the two stack components that leads to optimal performance is also studied.

  8. Status of Slip Stacking at Fermilab Main Injector

    CERN Document Server

    Seiya, Kiyomi; Chase, Brian; Dey, Joseph; Kourbanis, Ioanis; MacLachlan, James A; Meisner, Keith G; Pasquinelli, Ralph J; Reid, John; Rivetta, Claudio H; Steimel, Jim

    2005-01-01

    In order to increase proton intensity on anti proton production cycle of the Main Injector we are going to use the technique of 'slip stacking' and doing machine studies. In slip stacking, one bunch train is injected at slightly lower energy and second train is at slightly higher energy. Afterwards they are aligned longitudinally and captured with one rf bucket. This longitudinal stacking process is expected to double the bunch intensity. The required intensity for anti proton production is 8·1012

  9. A novel design for solid oxide fuel cell stacks

    Energy Technology Data Exchange (ETDEWEB)

    Al-Qattan, A.M.; Chmielewski, D.J.; Al-Hallaj, S.; Selman, J.R. [Illinois Inst. of Technology, Chicago, IL (United States). Dept. of Chemical and Environmental Engineering

    2004-01-01

    Conventional fuel cell stack designs suffer from severe spatial nonuniformity in both temperature and current density. Such variations are known to create damaging thermal stresses within the stack and thus, impact overall lifespan. In this work, we propose a novel stack design aimed at reducing spatial variations at the source. We propose a mechanism of distributed fuel feed in which the heat generation profile can be influenced directly. Simulation results are presented to illustrate the potential of the proposed scheme. (author)

  10. Development of the electric utility dispersed use PAFC stack

    Energy Technology Data Exchange (ETDEWEB)

    Horiuchi, Hiroshi; Kotani, Ikuo [Mitsubishi Electric Co., Kobe (Japan); Morotomi, Isamu [Kansai Electric Power Co., Hyogo (Japan)] [and others

    1996-12-31

    Kansai Electric Power Co. and Mitsubishi Electric Co. have been developing the electric utility dispersed use PAFC stack operated under the ambient pressure. The new cell design have been developed, so that the large scale cell (1 m{sup 2} size) was adopted for the stack. To confirm the performance and the stability of the 1 m{sup 2} scale cell design, the short stack study had been performed.

  11. Physical relativity: space-time structure from a dynamical perspective

    National Research Council Canada - National Science Library

    Brown, Harvey R

    2005-01-01

    ... relativity, there was nonetheless a vein of doubt running through his writings- culminating in his 1949 Autobiographical Notes- concerning the way he formulated the theory in 1905. It is clear, to me at least, that Einstein was fully conscious right from the beginning that there were two routes to relativistic kinematics, and that as time went on the appropriateness of the route he had chosen, which he felt he had to choose in 1905, was increasingly open to question. In his acclaimed 1982 scientific biogr...

  12. Bitopological spaces theory, relations with generalized algebraic structures and applications

    CERN Document Server

    Dvalishvili, Badri

    2005-01-01

    This monograph is the first and an initial introduction to the theory of bitopological spaces and its applications. In particular, different families of subsets of bitopological spaces are introduced and various relations between two topologies are analyzed on one and the same set; the theory of dimension of bitopological spaces and the theory of Baire bitopological spaces are constructed, and various classes of mappings of bitopological spaces are studied. The previously known results as well the results obtained in this monograph are applied in analysis, potential theory, general topology, a

  13. Extract relation between structures of proton and nuclei

    International Nuclear Information System (INIS)

    Gareev, E.A.; Gareeva, G.; )

    2001-01-01

    Full text: Schroedinger wrote that an interaction between microscopic physical objects is controlled by specific resonance laws. According to these laws, the difference between two eigenenergies (eigenfrequencies) in one system should be equal to each other: hv 1 -hv' 1 =hv 2 -hv' 2 , v 1 -v' 1 =v 2 -v' 2 . Therefore, the eigenfrequencies are additive. In other words, the resonance condition is formulated in the following way: oscillations participating in an interaction process should be constituents of the same frequency. Thus, we come to the conclusion: in a whole interacting self-consistent wave system the hierarchy of frequencies is established So, the sum of all partial frequencies is an integral of motion. Any interaction in a microscopic hierarchic wave system exhibits the resonance character. Due to the above-said the corresponding partial motions are determinate. As the resonance condition arises from the fundamental energy conservation law, the rhythms and synchronization of the majority of phenomena to be observed are the reflection of the universal property of self-organization of the Universe. The Huygens synchronization principle is substantiated at the microscopic level. We come to the conclusion that the proton stability can be explained by the assumption: channel motions in a proton are exactly synchronous. Therefore proton represent coherent synchronized states The aim this paper is to establish some bridge between structures of proton and nuclei as the further extension our phenomenological analysis. The parameter-free formula for spectra of nuclei has been obtained which establish some bridge between the structures of a proton and nuclei. The energies of nuclear states have been systematically analyzed by using all available experimental data. The interest of our results is not only in their closeness to the experimental data, but also in the derivation of formula from the fundamental law of Nature: the conservation law of energy

  14. Method for monitoring stack gases for uranium activity

    International Nuclear Information System (INIS)

    Beverly, C.R.; Ernstberger, H.G.

    1988-01-01

    A method for sampling stack gases emanating from the purge cascade of a gaseous diffusion cascade system utilized to enrich uranium for determining the presence and extent of uranium in the stack gases in the form of gaseous uranium hexafluoride, is described comprising the steps of removing a side stream of gases from the stack gases, contacting the side stream of the stack gases with a stream of air sufficiently saturated with moisture for reacting with and converting any gaseous uranium hexafluroide contracted thereby in the side stream of stack gases to particulate uranyl fluoride. Thereafter contacting the side stream of stack gases containing the particulate uranyl fluoride with moving filter means for continuously intercepting and conveying the intercepted particulate uranyl fluoride away from the side stream of stack gases, and continually scanning the moving filter means with radiation monitoring means for sensing the presence and extent of particulate uranyl fluoride on the moving filter means which is indicative of the extent of particulate uranyl fluoride in the side stream of stack gases which in turn is indicative of the presence and extent of uranium hexafluoride in the stack gases

  15. Design and development of an automated uranium pellet stacking system

    International Nuclear Information System (INIS)

    Reiss, B.S.; Nokleby, S.B.

    2010-01-01

    A novel design for an automated uranium pellet stacking system is presented. This system is designed as a drop-in solution to the current production line to enhance the fuel pellet stacking process. The three main goals of this system are to reduce worker exposure to radiation to as low as reasonable achievable (ALARA), improve product quality, and increase productivity. The proposed system will reduce the potential for human error. This single automated system will replace the two existing pellet stacking stations while increasing the total output, eliminating pellet stacking as a bottleneck in the fuel bundle assembly process. (author)

  16. The motive of the moduli stack of G-bundles over the universal curve

    Indian Academy of Sciences (India)

    E-mail: dvb@math.purdue.edu. MS received 11 April 2007; revised 27 January 2008. Abstract. We define relative motives in the sense of André. After associating a complex in the derived category of motives to an algebraic stack we study this complex in the case of the moduli of G-bundles varying over the moduli of curves.

  17. The SLUGGS survey: globular cluster stellar population trends from weak absorption lines in stacked spectra

    Science.gov (United States)

    Usher, Christopher; Forbes, Duncan A.; Brodie, Jean P.; Romanowsky, Aaron J.; Strader, Jay; Conroy, Charlie; Foster, Caroline; Pastorello, Nicola; Pota, Vincenzo; Arnold, Jacob A.

    2015-01-01

    As part of the SAGES Legacy Unifying Globulars and GalaxieS (SLUGGS) survey, we stack 1137 Keck DEIMOS (Deep Imaging Multi-Object Spectrograph) spectra of globular clusters from 10 galaxies to study their stellar populations in detail. The stacked spectra have median signal-to-noise ratios of ˜90 Å-1. Besides the calcium triplet, we study weaker sodium, magnesium, titanium and iron lines as well as the Hα and higher order Paschen hydrogen lines. In general, the stacked spectra are consistent with old ages and a Milky Way-like initial mass function. However, we see different metal line index strengths at fixed colour and magnitude, and differences in the calcium triplet-colour relation from galaxy to galaxy. We interpret this as strong evidence for variations in the globular cluster colour-metallicity relation between galaxies. Two possible explanations for the colour-metallicity relation variations are that the average ages of globular clusters vary from galaxy to galaxy or that the average abundances of light elements (i.e. He, C, N and O) differ between galaxies. Stacking spectra by magnitude, we see that the colours become redder and metal line indices stronger with brighter magnitudes. These trends are consistent with the previously reported `blue tilts' being mass-metallicity relations.

  18. Finite Element Analysis of Film Stack Architecture for Complementary Metal-Oxide-Semiconductor Image Sensors.

    Science.gov (United States)

    Wu, Kuo-Tsai; Hwang, Sheng-Jye; Lee, Huei-Huang

    2017-05-02

    Image sensors are the core components of computer, communication, and consumer electronic products. Complementary metal oxide semiconductor (CMOS) image sensors have become the mainstay of image-sensing developments, but are prone to leakage current. In this study, we simulate the CMOS image sensor (CIS) film stacking process by finite element analysis. To elucidate the relationship between the leakage current and stack architecture, we compare the simulated and measured leakage currents in the elements. Based on the analysis results, we further improve the performance by optimizing the architecture of the film stacks or changing the thin-film material. The material parameters are then corrected to improve the accuracy of the simulation results. The simulated and experimental results confirm a positive correlation between measured leakage current and stress. This trend is attributed to the structural defects induced by high stress, which generate leakage. Using this relationship, we can change the structure of the thin-film stack to reduce the leakage current and thereby improve the component life and reliability of the CIS components.

  19. A relational structure of voluntary visual-attention abilities

    Science.gov (United States)

    Skogsberg, KatieAnn; Grabowecky, Marcia; Wilt, Joshua; Revelle, William; Iordanescu, Lucica; Suzuki, Satoru

    2015-01-01

    Many studies have examined attention mechanisms involved in specific behavioral tasks (e.g., search, tracking, distractor inhibition). However, relatively little is known about the relationships among those attention mechanisms. Is there a fundamental attention faculty that makes a person superior or inferior at most types of attention tasks, or do relatively independent processes mediate different attention skills? We focused on individual differences in voluntary visual-attention abilities using a battery of eleven representative tasks. An application of parallel analysis, hierarchical-cluster analysis, and multidimensional scaling to the inter-task correlation matrix revealed four functional clusters, representing spatiotemporal attention, global attention, transient attention, and sustained attention, organized along two dimensions, one contrasting spatiotemporal and global attention and the other contrasting transient and sustained attention. Comparison with the neuroscience literature suggests that the spatiotemporal-global dimension corresponds to the dorsal frontoparietal circuit and the transient-sustained dimension corresponds to the ventral frontoparietal circuit, with distinct sub-regions mediating the separate clusters within each dimension. We also obtained highly specific patterns of gender difference, and of deficits for college students with elevated ADHD traits. These group differences suggest that different mechanisms of voluntary visual attention can be selectively strengthened or weakened based on genetic, experiential, and/or pathological factors. PMID:25867505

  20. [Relations of aqueduct with some structures of mesencephalon].

    Science.gov (United States)

    Stanković, Gordana; Nikolić, Valentina; Puskas, Nela; Filipović, Branislav; Puskas, Laslo; Krivokuća, Dragan

    2009-01-01

    Aqueductus mesencephali is the biggest part of the ventricular system and that is why it is the most common place of intraventricular obstruction of cerebrospinal fluid. This study was done in order to study topographic characteristics of aqueduct more thoroughly. Transversal sections of mesencephalon were made in three levels. The first section was made caudally immediately from the posterior commissure. The second section was made in the middle part of the superior colliculi, and the third section was made in the rostral parts of the caudal sections of the superior colliculi. Distances of the aqueduct from structures of mesencephalon, obtained on the second section, are: 1. The distance of the aqueduct from the superior colliculi - 6.96 mm; 2. The distance of the aqueduct from the red nucleus - 6.02 mm; 3. The distance of the aqueduct from the substantia nigra - 12.29 mm; 4. The distance of the aqueduct from the interpeduncular fossa - 10.22 mm. Knowledge of the anatomy of the aqueductus mesencephali is very important because of interpretation of patogenesis of hidrocefalus as well as of other syndromes that occure in some pathological processes in the system of ventricles.

  1. Structure-property relations in lanthanide borate glasses

    Science.gov (United States)

    Chakraborty, I. N.; Day, D. E.; Lapp, J. C.; Shelby, J. E.

    1985-01-01

    Glass formation in the system Ln2O3-B2O3 (Ln = Nd, Sm) was studied. Glasses could be formed in the range from 0 to 28 mol pct rare-earth oxide (Ln2O3), but liquid immiscibility in these systems limits the range of homogeneous glasses to 0 to 1.5 and 25 to 28 mol pct Ln2O3. The infrared spectra indicate that the rare-earth-rich glasses are structurally similar to rare-earth metaborates (LnB3O6) which contain (B3O6)-infinity chains. The variation in density, transformation temperature, thermal expansion coefficient, and transformation-range viscosity of these glasses with the size of the rare-earth ion is discussed. Glasses near the metaborate composition have a transformation temperature of about 700 C, which is high for binary borate glasses. Glasses could not be formed in the systems Eu2O3-, Gd2O3-, Ho2O3-, and Er2O3-B2O3, even by quenching at 1300 C/s. The sudden lack of glass formation in the system Ln2O3-B2O3 with Ln(3+) ions smaller than Sm(3+) is explained on the basis of the size effect of the Ln(3+) ion on the stability of (B3O6)-infinity chains in these metaborates.

  2. 2D-2D stacking of graphene-like g-C{sub 3}N{sub 4}/Ultrathin Bi{sub 4}O{sub 5}Br{sub 2} with matched energy band structure towards antibiotic removal

    Energy Technology Data Exchange (ETDEWEB)

    Ji, Mengxia; Di, Jun; Ge, Yuping; Xia, Jiexiang, E-mail: xjx@ujs.edu.cn; Li, Huaming, E-mail: lhm@ujs.edu.cn

    2017-08-15

    Highlights: • 2D-2D graphene-like g-C{sub 3}N{sub 4}/ultrathin Bi{sub 4}O{sub 5}Br{sub 2} materials have been prepared. • With matched energy band structure, the effective charge separation can be achieved. • The holes and O{sub 2}{sup −} are determined to be the main active species. - Abstract: A novel visible-light-driven 2D-2D graphene-like g-C{sub 3}N{sub 4}/ultrathin Bi{sub 4}O{sub 5}Br{sub 2} photocatalyst was prepared via a facile solvothermal method in the presence of reactable ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([C{sub 16}mim]Br) for the first time. FT-IR, XPS and TEM analysis results demonstrated the successful introduction of the 2D graphene-like g-C{sub 3}N{sub 4} material to the Bi{sub 4}O{sub 5}Br{sub 2} system. DRS and BET analysis results indicated the existence of the g-C{sub 3}N{sub 4} could lead to the broaden absorption edge and larger surface area of the ultrathin Bi{sub 4}O{sub 5}Br{sub 2} nanosheets. The electrochemical analysis implied a fast transfer of the interfacial electrons and low recombination rate of photogenerated charge carriers in g-C{sub 3}N{sub 4}/Bi{sub 4}O{sub 5}Br{sub 2}, which could be assigned to the sufficient and tight contact between ultrathin Bi{sub 4}O{sub 5}Br{sub 2} and graphene-like g-C{sub 3}N{sub 4}. The quinolone antibiotic ciprofloxacin (CIP) was chosen as the target pollutant to evaluate the photocatalytic performance of the as-prepared samples under visible light irradiation. 1 wt% g-C{sub 3}N{sub 4}/Bi{sub 4}O{sub 5}Br{sub 2} composite exhibited the highest photocatalytic degradation performance among all of the as-prepared photocatalysts. The enhancement of photocatalytic activity was attributed to the maximum contact between graphene-like g-C{sub 3}N{sub 4} and ultrathin Bi{sub 4}O{sub 5}Br{sub 2} material with matched energy band structure, which enable the efficient charge seperation. A possible photocatalytic mechanism also was proposed.

  3. Structural logical relations with case analysis and equality reasoning

    DEFF Research Database (Denmark)

    Rasmussen, Ulrik Terp; Filinski, Andrzej

    2013-01-01

    -style auxiliary assertion logic which is subsequently proved consistent via cut elimination. We demonstrate in this paper an application of the above methodology to proofs of observational equivalence between expressions in a simply typed lambda calculus with a call-by-name operational semantics. Our use case......Formalizing proofs by logical relations in the Twelf proof assistant is known to be notoriously difficult. However, as demonstrated by Schürmann and Sarnat [In Proc. of 23rd Symp. on Logic in Computer Science, 2008] such proofs can be represented and verified in Twelf if done so using a Gentzen...... requires the assertion logic to be extended with reasoning principles not present in the original presentation of the formalization method. We address this by generalizing the assertion logic to include dependent sorts, and demonstrate that the original cut elimination proof continues to apply without...

  4. [Impact of energy related pollutants on chromosome structure]: Progress report

    International Nuclear Information System (INIS)

    Rill, R.L.

    1986-01-01

    Studies of the structure of nucleosome cores using chymotrypsin as a probe of hydrophobic residues showed that only leu-20 of H3 was readily accessible. Primary sites of cleavage of H2a, H2b, and H4 were identified. Chymotrypsin removal of specific histone termini showed that removal of the amino-terminal plus the carboxy-terminal 13 residues of H2a caused little unfolding. Using carbon-13 NMR spectroscopic, about 10% of histone amino acid residues were found to be in termini that are highly mobile. The major mobile segments were amino terminal regions of H3 and H2a, plus a carboxy-terminal region of H2a. The histone variants and developmental changes during embryogenesis of sea urchin were characterized. The early histone gene organization in L. variegatus was characterized, a genomic library was cloned in lambda phage, and several histone gene clones were selected. The nucleosome core length DNA forms crystalline phases at physiological concentrations. Microscopic and NMR spectroscopic methods were used to identify crystalline phases and to establish phase diagrams for transitions between phases as functions of DNA concentration and temperature. The sequence specificities of binding of several polycyclic aromatic chemicals to early H3 and H2a genes were examined. Chemicals studied were the bis-(o-phenanthroline) Cu(I) complex, AAAF, benzopyrene dihydrodiol epoxide, methylene blue, and acridine orange A preliminary map of binding sites of CuOP, AAAF and BPDE in and near the H3 gene showed that several sequence regions were bound preferentially by two or more of these chemicals. CuOP appeared to exhibit the most specificity. 80 refs., 4 figs

  5. Development of "Purple Endosperm Rice" by Engineering Anthocyanin Biosynthesis in the Endosperm with a High-Efficiency Transgene Stacking System.

    Science.gov (United States)

    Zhu, Qinlong; Yu, Suize; Zeng, Dongchang; Liu, Hongmei; Wang, Huicong; Yang, Zhongfang; Xie, Xianrong; Shen, Rongxin; Tan, Jiantao; Li, Heying; Zhao, Xiucai; Zhang, Qunyu; Chen, Yuanling; Guo, Jingxing; Chen, Letian; Liu, Yao-Guang

    2017-07-05

    Anthocyanins have high antioxidant activities, and engineering of anthocyanin biosynthesis in staple crops, such as rice (Oryza sativa L.), could provide health-promoting foods for improving human health. However, engineering metabolic pathways for biofortification remains difficult, and previous attempts to engineer anthocyanin production in rice endosperm failed because of the sophisticated genetic regulatory network of its biosynthetic pathway. In this study, we developed a high-efficiency vector system for transgene stacking and used it to engineer anthocyanin biosynthesis in rice endosperm. We made a construct containing eight anthocyanin-related genes (two regulatory genes from maize and six structural genes from Coleus) driven by the endosperm-specific promoters,plus a selectable marker and a gene for marker excision. Transformation of rice with this construct generated a novel biofortified germplasm "Purple Endosperm Rice" (called "Zijingmi" in Chinese), which has high anthocyanin contents and antioxidant activity in the endosperm. This anthocyanin production results from expression of the transgenes and the resulting activation (or enhancement) of expression of 13 endogenous anthocyanin biosynthesis genes that are silenced or expressed at low levels in wild-type rice endosperm. This study provides an efficient, versatile toolkit for transgene stacking and demonstrates its use for successful engineering of a sophisticated biological pathway, suggesting the potential utility of this toolkit for synthetic biology and improvement of agronomic traits in plants. Copyright © 2017 The Author. Published by Elsevier Inc. All rights reserved.

  6. 2D-2D stacking of graphene-like g-C3N4/Ultrathin Bi4O5Br2 with matched energy band structure towards antibiotic removal

    Science.gov (United States)

    Ji, Mengxia; Di, Jun; Ge, Yuping; Xia, Jiexiang; Li, Huaming

    2017-08-01

    A novel visible-light-driven 2D-2D graphene-like g-C3N4/ultrathin Bi4O5Br2 photocatalyst was prepared via a facile solvothermal method in the presence of reactable ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([C16mim]Br) for the first time. FT-IR, XPS and TEM analysis results demonstrated the successful introduction of the 2D graphene-like g-C3N4 material to the Bi4O5Br2 system. DRS and BET analysis results indicated the existence of the g-C3N4 could lead to the broaden absorption edge and larger surface area of the ultrathin Bi4O5Br2 nanosheets. The electrochemical analysis implied a fast transfer of the interfacial electrons and low recombination rate of photogenerated charge carriers in g-C3N4/Bi4O5Br2, which could be assigned to the sufficient and tight contact between ultrathin Bi4O5Br2 and graphene-like g-C3N4. The quinolone antibiotic ciprofloxacin (CIP) was chosen as the target pollutant to evaluate the photocatalytic performance of the as-prepared samples under visible light irradiation. 1 wt% g-C3N4/Bi4O5Br2 composite exhibited the highest photocatalytic degradation performance among all of the as-prepared photocatalysts. The enhancement of photocatalytic activity was attributed to the maximum contact between graphene-like g-C3N4 and ultrathin Bi4O5Br2 material with matched energy band structure, which enable the efficient charge seperation. A possible photocatalytic mechanism also was proposed.

  7. Directive Stacked Patch Antenna for UWB Applications

    Directory of Open Access Journals (Sweden)

    Sharif I. Mitu Sheikh

    2013-01-01

    Full Text Available Directional ultrawideband (UWB antennas are popular in wireless signal-tracking and body-area networks. This paper presents a stacked microstrip antenna with an ultrawide impedance bandwidth of 114%, implemented by introducing defects on the radiating patches and the ground plane. The compact (20×34 mm antenna exhibits a directive radiation patterns for all frequencies of the 3–10.6 GHz band. The optimized reflection response and the radiation pattern are experimentally verified. The designed UWB antenna is used to maximize the received power of a software-defined radio (SDR platform. For an ultrawideband impulse radio system, this class of antennas is essential to improve the performance of the communication channels.

  8. ATLAS software stack on ARM64

    Science.gov (United States)

    Smith, Joshua Wyatt; Stewart, Graeme A.; Seuster, Rolf; Quadt, Arnulf; ATLAS Collaboration

    2017-10-01

    This paper reports on the port of the ATLAS software stack onto new prototype ARM64 servers. This included building the “external” packages that the ATLAS software relies on. Patches were needed to introduce this new architecture into the build as well as patches that correct for platform specific code that caused failures on non-x86 architectures. These patches were applied such that porting to further platforms will need no or only very little adjustments. A few additional modifications were needed to account for the different operating system, Ubuntu instead of Scientific Linux 6 / CentOS7. Selected results from the validation of the physics outputs on these ARM 64-bit servers will be shown. CPU, memory and IO intensive benchmarks using ATLAS specific environment and infrastructure have been performed, with a particular emphasis on the performance vs. energy consumption.

  9. ATLAS software stack on ARM64

    CERN Document Server

    AUTHOR|(INSPIRE)INSPIRE-00529764; The ATLAS collaboration; Stewart, Graeme; Seuster, Rolf; Quadt, Arnulf

    2017-01-01

    This paper reports on the port of the ATLAS software stack onto new prototype ARM64 servers. This included building the “external” packages that the ATLAS software relies on. Patches were needed to introduce this new architecture into the build as well as patches that correct for platform specific code that caused failures on non-x86 architectures. These patches were applied such that porting to further platforms will need no or only very little adjustments. A few additional modifications were needed to account for the different operating system, Ubuntu instead of Scientific Linux 6 / CentOS7. Selected results from the validation of the physics outputs on these ARM 64-bit servers will be shown. CPU, memory and IO intensive benchmarks using ATLAS specific environment and infrastructure have been performed, with a particular emphasis on the performance vs. energy consumption.

  10. Fast static field CIPT mapping of unpatterned MRAM film stacks

    Science.gov (United States)

    Kjaer, Daniel; Hansen, Ole; Hartmann Henrichsen, Henrik; Chenchen, Jacob Wang; Noergaard, Kristian; Folmer Nielsen, Peter; Hjorth Petersen, Dirch

    2015-04-01

    While investigating uniformity of magnetic tunnel junction (MTJ) stacks we find experimentally and analytically that variation in the resistance area product (RA) is more important to monitor as compared to the tunnel magnetoresistance (TMR), which is less sensitive to MTJ variability. The standard Current In-Plane Tunneling (CIPT) method measures both RA and TMR, but the usefulness for uniformity mapping, e.g. for tool optimization, is limited by excessive measurement time. Thus, we develop and demonstrate a fast complementary static magnetic field method focused only on measurement of RA. We compare the static field method to the standard CIPT method and find perfect agreement between the extracted RA values and measurement repeatability while the static field method is several times faster. The static field CIPT method is demonstrated for 200 mm wafer mapping showing radial as well as asymmetrical variations related to the MTJ deposition conditions.

  11. Sodium-Induced Reordering of Atomic Stacks in Black Phosphorus

    KAUST Repository

    Cheng, Yingchun

    2017-01-12

    While theoretical simulations predict contradictory results about how the intercalation of foreign metal atoms affects the order of atomic layers in black phosphorus (BP), no direct experimental visualization work has yet clarified this ambiguity. By in situ electrochemical sodiation of BP inside a high-resolution transmission electron microscope and first-principles calculations, we found that sodium intercalation induces a relative glide of/ ⟨010⟩ {001}, resulting in reordering of atomic stacks from AB to AC in BP. The observed local amorphization in our experiments is triggered by lattice constraints. We predict that intercalation of sodium or other metal atoms introduces n-type carriers in BP. This potentially opens a new field for two-dimensional electronics based on BP.

  12. The structure of executive functions and relations with early math learning

    NARCIS (Netherlands)

    van der Ven, S.H.G.

    2011-01-01

    In this dissertation, the relation between executive functions and mathematical skills in children was investigated. Two main aims were addressed: (1) unraveling the structure of executive functions, and (2) investigating the nature of the relations between executive functions and mathematics.

  13. The Gd{sub 14}Ag{sub 51} structure type and its relation to some complex amalgam structures

    Energy Technology Data Exchange (ETDEWEB)

    Tambornino, Frank; Sappl, Jonathan; Hoch, Constantin, E-mail: constantin.hoch@cup.uni-muenchen.de

    2015-01-05

    Highlights: • The Gd{sub 14}Ag{sub 51} structure type has been revisited on the basis of single crystal diffraction data. • Symmetry analysis from electron density and TEM shows the space group P6/m to be true. • Gd{sub 14}Ag{sub 51} shows good metallic behaviour. • Structure relations to alkali, alkaline-earth and rare-earth metal amalgams can be established. • Complexity values for the RE{sub 14}Ag{sub 51} structure family were calculated. - Abstract: A plethora of binary and ternary intermetallic compounds has been assigned to the Gd{sub 14}Ag{sub 51} structure type, crystallising in the hexagonal system (space group P6/m, a = 1264.30(18) pm, c = 933.58(11) pm for Gd{sub 14}Ag{sub 51}). Starting in the late 1960s, much work has been invested in the structural elucidation of these crystal structures. However, reliable single crystal data are scarce, and most structure type assignments have been performed merely on the basis of powder data. We have redetermined four representatives of the binary RE{sub 14}Ag{sub 51} structure type (RE = Y, Ce, Gd, Tb) with modern high-precision single crystal X-ray methods. The assignment of the Gd{sub 14}Ag{sub 51} structure type to space group P6/m was additionally verified by careful analysis of high resolution transmission electron micrographs. We emphasise the close relation of the Gd{sub 14}Ag{sub 51} structure type to the structures of some recently described amalgams of similar composition focussing on disorder phenomena and structural complexity. Furthermore, we provide detailed information on synthesis as well as electrical and magnetic properties for Gd{sub 14}Ag{sub 51}, the parent compound of this structure family.

  14. Application of Stacking Technique in ANA: Method and Practice with PKU Seismological Array

    Science.gov (United States)

    Liu, J.; Tang, Y.; Ning, J.; Chen, Y. J.

    2010-12-01

    Cross correlation of ambient noise records is now routinely used to get dispersion curve and then do seismic tomography; however little attention has been paid to array techniques. We will present a spacial-stacking method to get high resolution dispersion curves and show practices with the observation data of PKU seismological array. Experiential Green Functions are generally obtained by correlation between two stations, and then the dispersion curves are obtained from the analysis of FTAN. Popular method to get high resolution dispersion curves is using long time records. At the same time, if we want to get effectual signal, the distance between the two stations must be at least 3 times of the longest wavelength. So we need both long time records and appropriate spaced stations. Now we use a new method, special-stacking, which allows shorter observation period and utilizes observations of a group of closely distributed stations to get fine dispersion curves. We correlate observations of every station in the station group with those of a far station, and then stack them together. However we cannot just simply stack them unless the stations in the station group at a circle, of which the center is the far station owing to dispersion characteristics of the Rayleigh waves. Thus we do antidispersion on the observation data of every station in the array, then do stacking. We test the method using the theoretical seismic surface wave records which obtained by qseis06 compiled by Rongjiang Wang both with and without noise. For the cases of three imaginary stations (distance is 1 degree) have the same underground structure and without noise, result is that the center station had the same dispersion with and without spacial-stacking. Then we add noise to the theoretical records. The center station's dispersion curves obtained by our method are much closer to the dispersion curve without noise than contaminated ones. We can see that our method has improved the resolution of

  15. A new method for earthquake depth determination: stacking multiple-station autocorrelograms

    Science.gov (United States)

    Zhang, Miao; Tian, Dongdong; Wen, Lianxing

    2014-05-01

    Accurate determination of earthquake depth is important, but particularly challenging. We develop a new method to determine the earthquake source depth by stacking multiple-station autocorrelograms (SMAC) of seismic data. The basic concept of SMAC method is to enhance the coherent surface reflected energy by autocorrelation and stacking, and uses the surface reflected energy to determine the source depth. Autocorrelation effectively enhances the energy of the seismic phases related to the source depth, while stacking the autocorrelograms of array data further improves the signal-to-noise ratio of the energy. The procedures are applied using both the main SH waves and the coda. Using coda waves, the method extracts the two-way traveltime between the source and the surface by stacking the coda wave autocorrelations over an array of seismic observations. Using the main SH waves, SMAC explores the interference of the down-going Moho reflected SmS wave and up-going surface bounced Moho reflected sSmS wave by autocorrelation. The autocorrelograms are then stacked along theoretical differential sSmS-SmS traveltime predicted for all potential source depths, and the source depth is determined to be the one that produces the maximum stacking energy. Synthetic tests demonstrate the validity of the SMAC procedures. As an example of application, we apply the SMAC method to determine the source depth of an earthquake occurring in Japan Island. The procedures of using both main SH waves and their coda waves yield robust surface reflected energy and a consistent source depth. The error of the depth estimation is less than 1 km assuming an uncertainty of 10 per cent in the averaged crust velocity.

  16. Improved charge trapping flash device with Al2O3/HfSiO stack as blocking layer

    International Nuclear Information System (INIS)

    Zheng Zhi-Wei; Huo Zong-Liang; Zhu Chen-Xin; Xu Zhong-Guang; Liu Jing; Liu Ming

    2011-01-01

    In this paper, we investigate an Al 2 O 3 /HfSiO stack as the blocking layer of a metal—oxide—nitride—oxide—silicon-type (MONOS) memory capacitor. Compared with a memory capacitor with a single HfSiO layer as the blocking layer or an Al 2 O 3 /HfO 2 stack as the blocking layer, the sample with the Al 2 O 3 /HfSiO stack as the blocking layer shows high program/erase (P/E) speed and good data retention characteristics. These improved performances can be explained by energy band engineering. The experimental results demonstrate that the memory device with an Al 2 O 3 /HfSiO stack as the blocking layer has great potential for further high-performance nonvolatile memory applications. (interdisciplinary physics and related areas of science and technology)

  17. Doped penta-graphene and hydrogenation of its related structures: a structural and electronic DFT-D study.

    Science.gov (United States)

    Quijano-Briones, J J; Fernández-Escamilla, H N; Tlahuice-Flores, A

    2016-06-21

    The structure of penta-graphene (penta-C), an irregular pentagonal two-dimensional (2D) structure, has been predicted recently. In this communication we carried out a dispersion-corrected density functional theory (DFT-D) study of the penta-C doped with Si, Ge and Sn atoms and its related hydrogenated penta-C structures (H-penta-C-X). We predict various new structures as thermally stable based on Born-Oppenheimer molecular dynamics (BOMD) calculations. Moreover, their dynamical stability is attested by phonon dispersions spectra. In general, we found that the bandgap value of doped structures reduces, while H-penta-C-X show large bandgap values. This feature can be exploited for potential uses of hydrogenated doped-penta-C structures as dielectric layers in electronic devices.

  18. Related Structure Characters and Stability of Structural Defects in a Metallic Glass.

    Science.gov (United States)

    Niu, Xiaofeng; Feng, Shidong; Pan, Shaopeng

    2018-03-22

    Structural defects were investigated by a recently proposed structural parameter, quasi-nearest atom (QNA), in a modeled Zr 50 Cu 50 metallic glass through molecular dynamics simulations. More QNAs around an atom usually means that more defects are located near the atom. Structural analysis reveals that the spatial distribution of the numbers of QNAs displays to be clearly heterogeneous. Furthermore, QNA is closely correlated with cluster connections, especially four-atom cluster connections. Atoms with larger coordination numbers usually have less QNAs. When two atoms have the same coordination number, the atom with larger five-fold symmetry has less QNAs. The number of QNAs around an atom changes rather frequently and the change of QNAs might be correlated with the fast relaxation metallic glasses.

  19. Numeric Input Relations for Relational Learning with Applications to Community Structure Analysis

    DEFF Research Database (Denmark)

    Jiang, Jiuchuan; Jaeger, Manfred

    2015-01-01

    Most work in the area of statistical relational learning (SRL) is focussed on discrete data, even though a few approaches for hybrid SRL models have been proposed that combine numerical and discrete variables. In this paper we distinguish numerical random variables for which a probability...... distribution is defined by the model from numerical input variables that are only used for conditioning the distribution of discrete response variables. We show how numerical input relations can very easily be used in the Relational Bayesian Network framework, and that existing inference and learning methods...... use the augmented RBN framework to define probabilistic models for multi-relational (social) networks in which the probability of a link between two nodes depends on numeric latent feature vectors associated with the nodes. A generic learning procedure can be used to obtain a maximum-likelihood fit...

  20. Highly Conductive Transparent and Flexible Electrodes Including Double-Stacked Thin Metal Films for Transparent Flexible Electronics.

    Science.gov (United States)

    Han, Jun Hee; Kim, Do-Hong; Jeong, Eun Gyo; Lee, Tae-Woo; Lee, Myung Keun; Park, Jeong Woo; Lee, Hoseung; Choi, Kyung Cheol

    2017-05-17

    To keep pace with the era of transparent and deformable electronics, electrode functions should be improved. In this paper, an innovative structure is suggested to overcome the trade-off between optical and electrical properties that commonly arises with transparent electrodes. The structure of double-stacked metal films showed high conductivity (electronics are expected.

  1. Simultaneous stack-gas scrubbing and waste water treatment

    Science.gov (United States)

    Poradek, J. C.; Collins, D. D.

    1980-01-01

    Simultaneous treatment of wastewater and S02-laden stack gas make both treatments more efficient and economical. According to results of preliminary tests, solution generated by stack gas scrubbing cycle reduces bacterial content of wastewater. Both processess benefit by sharing concentrations of iron.

  2. Nature of Interlayer Binding and Stacking of sp–sp 2 Hybridized Carbon Layers: A Quantum Monte Carlo Study

    International Nuclear Information System (INIS)

    Shin, Hyeondeok; Lee, Hoonkyung; Heinonen, Olle; Benali, Anouar; Kwon, Yongkyung

    2017-01-01

    α-graphyne is a two-dimensional sheet of sp-sp2 hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that is different from that of graphene. Similar to graphene, α-graphyne can be stacked in bilayers with two stable configurations, but the different stackings have very different electronic structures: one is predicted to have gapless parabolic bands and the other a tunable bandgap which is attractive for applications. In order to realize applications, it is crucial to understand which stacking is more stable. This is difficult to model, as the stability is a result of weak interlayer van der Waals interactions which are not well captured by density functional theory (DFT). We have used quantum Monte Carlo simulations that accurately include van der Waals interactions to calculate the interlayer binding energy of bilayer graphyne and to determine its most stable stacking mode. Our results show that inter-layer bindings of sp- and sp2-bonded carbon networks are significantly underestimated in a Kohn-Sham DFT approach, even with an exchange-correlation potential corrected to include, in some approximation, van der Waals interactions. Finally, our quantum Monte Carlo calculations reveal that the interlayer binding energy difference between the two stacking modes is only 0.9(4) eV/atom. From this we conclude that the two stable stacking modes of bilayer α-graphyne are almost degenerate with each other, and both will occur with about the same probability at room temperature unless there is a synthesis path that prefers one stacking over the other.

  3. Stacking Faults and Polytypes for Layered Double Hydroxides: What Can We Learn from Simulated and Experimental X-ray Powder Diffraction Data?

    Science.gov (United States)

    Sławiński, Wojciech A; Sjåstad, Anja Olafsen; Fjellvåg, Helmer

    2016-12-19

    Layered double hydroxides (LDH) are a broad group of widely studied materials. The layered character of those materials and their high flexibility for accommodating different metals and anions make them technologically interesting. The general formula for the LDH compound is [M 1-x II M x III (OH) 2 ][A n- ] x/n ·mH 2 O, where M II is a divalent metal cation which can be substituted by M III trivalent cation, and A n- is a charge compensating anion located between positively charged layers. In this paper we present a comprehensive study on possible structural disorder in LDH. We show how X-ray powder diffraction (XRPD) can be used to reveal important features of the LDH crystal structure such as stacking faults, random interlayer shifts, anion-molecule orientation, crystal water content, distribution of interlayer distances, and also LDH slab thickness. All calculations were performed using the Discus package, which gives a better flexibility in defining stacking fault sequences, simulating and refining XRPD patterns, relative to DIFFaX, DIFFaX+, and FAULTS. Finally, we show how the modeling can be applied to two LDH samples: Ni 0.67 Cr 0.33 (OH) 2 (CO 3 ) 0.16 ·mH 2 O (3D structure) and Mg 0.67 Al 0.33 (OH) 2 (NO 3 ) 0.33 (2D layered structure).

  4. Stacking of purines in water: the role of dipolar interactions in caffeine.

    Science.gov (United States)

    Tavagnacco, L; Di Fonzo, S; D'Amico, F; Masciovecchio, C; Brady, J W; Cesàro, A

    2016-05-11

    During the last few decades it has been ascertained that base stacking is one of the major contributions stabilizing nucleic acid conformations. However, the understanding of the nature of the interactions involved in the stacking process remains under debate and it is a subject of theoretical and experimental studies. Structural similarity between purine bases (guanine and adenine) in DNA and the caffeine molecule makes caffeine an excellent model for the purine bases. The present study clearly shows that dipolar interactions play a fundamental role in determining stacking of purine molecules in solution. In order to reach this achievement, polarized ultraviolet Raman resonant scattering experiments have been carried out on caffeine aqueous solutions as a function of concentration and temperature. The investigation pointed out at the aggregation and solvation properties, particularly at elevated temperatures. Kubo-Anderson theory was used as a framework to investigate the non-coincidence effect (NCE) occurring in the totally symmetric breathing modes of the purine rings, and in the bending modes of the methyl groups of caffeine. The NCE concentration dependence shows that caffeine aggregation at 80 °C occurs by planar stacking of the hydrophobic faces. The data clearly indicate that dipolar interactions determine the reorientational motion of the molecules in solution and are the driving force for the stacking of caffeine. In parallel, the observed dephasing times imply a change in caffeine interactions as a function of temperature and concentration. A decrease, at low water content, of the dephasing time for the ring breathing vibration mode indicates that self-association alters the solvation structure that is detectable at low concentration. These results are in agreement with simulation predictions and serve as an important validation of the models used in those calculations.

  5. RNA structure probing : biochemical structure analysis of autoimmune-related RNA molecules

    NARCIS (Netherlands)

    Teunissen, A.W.M.

    1999-01-01

    Next to the well known messenger, ribosomal and transfer RNAs, a large number of small structural RNA molecules exist. These RNAs are bound to proteins, forming ribonucleoprotein particles (RNPs). RNPs are often targets for autoantibodies occurring in an autoimmune disease.Chapter 1 introduces

  6. Dynamic Model of High Temperature PEM Fuel Cell Stack Temperature

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2007-01-01

    The present work involves the development of a model for predicting the dynamic temperature of a high temperature PEM (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system consists of a prototype...... parts, where also the temperatures are measured. The heat balance of the system involves a fuel cell model to describe the heat added by the fuel cells when a current is drawn. Furthermore the model also predicts the temperatures, when heating the stack with external heating elements for start-up, heat...... the stack at a high stoichiometric air flow. This is possible because of the PBI fuel cell membranes used, and the very low pressure drop in the stack. The model consists of a discrete thermal model dividing the stack into three parts: inlet, middle and end and predicting the temperatures in these three...

  7. Direct methanol fuel cell stack based on MEMS technology

    Science.gov (United States)

    Zhang, Yufeng; Tang, Xiaochuan; Yuan, Zhenyu; Liu, Xiaowei

    2008-10-01

    This paper presents a design configuration of silicon-based micro direct methanol fuel cell (DMFC) stack in a planar array. The integrated series connection is oriented in a "flip-flop" configuration with electrical interconnections made by thin-film metal layers that coat the flow channels etched in the silicon substrate. The configuration features small connection space and low contact resistance. The MEMS fabrication process was utilized to fabricate the silicon plates of DMFC stack. This DMFC stack with an active area of 64mm x 11mm was characterized at room temperature and normal atmosphere. Experimental results show that the prototype stack is able to generate an open-circuit voltage of 2.7V and a maximum power density of 2.2mW/cm2, which demonstrate the feasibility of this new DMFC stack configuration.

  8. Physical Sciences Laboratory 1 Rooftop Stack Mixing Study

    Energy Technology Data Exchange (ETDEWEB)

    Flaherty, Julia E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Antonio, Ernest J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2016-09-30

    To address concerns about worker exposures on the Physical Science Laboratory (PSL) rooftop, a tracer study was conducted to measure gaseous tracer concentrations downwind of six stacks on the southern half of the PSL building (PSL-1). These concerns were raised, in part, due to the non-standard configuration of the stacks on this building. Five of the six stacks were only about 8 feet tall, with one shorter stack that was essentially level with the roof deck. These stacks were reconfigured in August 2016, and these exhaust points on PSL-1 are now 18 feet tall. This report describes the objectives of the tracer tests performed on PSL-1, provides an overview of how the tests were executed, and presents results of the tests. The tests on the PSL rooftop were a follow-on project from a similar study performed on the LSL-II ventilation exhaust (Flaherty and Antonio, 2016).

  9. Evaluation of field emission properties from multiple-stacked Si quantum dots

    International Nuclear Information System (INIS)

    Takeuchi, Daichi; Makihara, Katsunori; Ohta, Akio; Ikeda, Mitsuhisa; Miyazaki, Seiichi

    2016-01-01

    Multiple-stacked Si quantum dots (QDs) with ultrathin SiO 2 interlayers were formed on ultrathin SiO 2 layers by repeating a process sequence consisting of the formation of Si-QDs by low pressure chemical vapor deposition using a SiH 4 gas and the surface oxidation and subsequent surface modification by remote hydrogen and oxygen plasmas, respectively. To clarify the electron emission mechanism from multiple-stacked Si-QDs covered with an ultrathin Au top electrode, the energy distribution of the emitted electrons and its electric field dependence was measured using a hemispherical electron energy analyzer in an X-ray photoelectron spectroscopy system under DC bias application to the multiple-stacked Si-QD structure. At − 6 V and over, the energy distributions reached a peak at ~ 2.5 eV with a tail toward the higher energy side. While the electron emission intensity was increased exponentially with an increase in the applied DC bias, there was no significant increase in the emission peak energy. The observed emission characteristics can be interpreted in terms of field emissions from the second and/or third topmost Si-QDs resulting from the electric concentration there. - Highlights: • Electron field emission from 6-fold stack of Si-QDs has been evaluated. • AFM measurements show the local electron emission from individual Si-QDs. • Impact of applied bias on the electron emission energy distribution was investigated.

  10. Development and Characterization of an Electrically Rechargeable Zinc-Air Battery Stack

    Directory of Open Access Journals (Sweden)

    Hongyun Ma

    2014-10-01

    Full Text Available An electrically rechargeable zinc-air battery stack consisting of three single cells in series was designed using a novel structured bipolar plate with air-breathing holes. Alpha-MnO2 and LaNiO3 severed as the catalysts for the oxygen reduction reaction (ORR and oxygen evolution reaction (OER. The anodic and cathodic polarization and individual cell voltages were measured at constant charge-discharge (C-D current densities indicating a uniform voltage profile for each single cell. One hundred C-D cycles were carried out for the stack. The results showed that, over the initial 10 cycles, the average C-D voltage gap was about 0.94 V and the average energy efficiency reached 89.28% with current density charging at 15 mA·cm−2 and discharging at 25 mA·cm−2. The total increase in charging voltage over the 100 C-D cycles was ~1.56% demonstrating excellent stability performance. The stack performance degradation was analyzed by galvanostatic electrochemical impedance spectroscopy. The charge transfer resistance of ORR increased from 1.57 to 2.21 Ω and that of Zn/Zn2+ reaction increased from 0.21 to 0.34 Ω after 100 C-D cycles. The quantitative analysis guided the potential for the optimization of both positive and negative electrodes to improve the cycle life of the cell stack.

  11. Temperature-dependent stability of stacking faults in Al, Cu and Ni: first-principles analysis.

    Science.gov (United States)

    Bhogra, Meha; Ramamurty, U; Waghmare, Umesh V

    2014-09-24

    We present comparative analysis of microscopic mechanisms relevant to plastic deformation of the face-centered cubic (FCC) metals Al, Cu, and Ni, through determination of the temperature-dependent free energies of intrinsic and unstable stacking faults along [1 1̄ 0] and [1 2̄ 1] on the (1 1 1) plane using first-principles density-functional-theory-based calculations. We show that vibrational contribution results in significant decrease in the free energy of barriers and intrinsic stacking faults (ISFs) of Al, Cu, and Ni with temperature, confirming an important role of thermal fluctuations in the stability of stacking faults (SFs) and deformation at elevated temperatures. In contrast to Al and Ni, the vibrational spectrum of the unstable stacking fault (USF[1 2̄ 1]) in Cu reveals structural instabilities, indicating that the energy barrier (γusf) along the (1 1 1)[1 2̄ 1] slip system in Cu, determined by typical first-principles calculations, is an overestimate, and its commonly used interpretation as the energy release rate needed for dislocation nucleation, as proposed by Rice (1992 J. Mech. Phys. Solids 40 239), should be taken with caution.

  12. FERMI LAT STACKING ANALYSIS OF SWIFT LOCALIZED GRBs

    Energy Technology Data Exchange (ETDEWEB)

    Ackermann, M.; Buehler, R. [Deutsches Elektronen Synchrotron DESY, D-15738 Zeuthen (Germany); Ajello, M. [Department of Physics and Astronomy, Clemson University, Kinard Lab of Physics, Clemson, SC 29634-0978 (United States); Atwood, W. B. [Santa Cruz Institute for Particle Physics, Department of Physics and Department of Astronomy and Astrophysics, University of California at Santa Cruz, Santa Cruz, CA 95064 (United States); Axelsson, M. [Department of Physics, KTH Royal Institute of Technology, AlbaNova, SE-106 91 Stockholm (Sweden); Baldini, L. [Università di Pisa and Istituto Nazionale di Fisica Nucleare, Sezione di Pisa I-56127 Pisa (Italy); Barbiellini, G. [Istituto Nazionale di Fisica Nucleare, Sezione di Trieste, I-34127 Trieste (Italy); Bastieri, D.; Buson, S. [Istituto Nazionale di Fisica Nucleare, Sezione di Padova, I-35131 Padova (Italy); Bellazzini, R. [Istituto Nazionale di Fisica Nucleare, Sezione di Pisa, I-56127 Pisa (Italy); Bhat, P. N. [Center for Space Plasma and Aeronomic Research (CSPAR), University of Alabama in Huntsville, Huntsville, AL 35899 (United States); Bissaldi, E. [Istituto Nazionale di Fisica Nucleare, Sezione di Bari, 70126 Bari (Italy); Bonino, R. [Istituto Nazionale di Fisica Nucleare, Sezione di Torino, I-10125 Torino (Italy); Bottacini, E.; Caliandro, G. A.; Cameron, R. A. [W. W. Hansen Experimental Physics Laboratory, Kavli Institute for Particle Astrophysics and Cosmology, Department of Physics and SLAC National Accelerator Laboratory, Stanford University, Stanford, CA 94305 (United States); Brandt, T. J. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Bregeon, J. [Laboratoire Univers et Particules de Montpellier, Université Montpellier, CNRS/IN2P3, Montpellier (France); Bruel, P. [Laboratoire Leprince-Ringuet, École polytechnique, CNRS/IN2P3, Palaiseau (France); Anderson, B., E-mail: jchiang@slac.stanford.edu; and others

    2016-05-10

    We perform a comprehensive stacking analysis of data collected by the Fermi Large Area Telescope (LAT) of γ -ray bursts (GRBs) localized by the Swift spacecraft, which were not detected by the LAT but which fell within the instrument’s field of view at the time of trigger. We examine a total of 79 GRBs by comparing the observed counts over a range of time intervals to that expected from designated background orbits, as well as by using a joint likelihood technique to model the expected distribution of stacked counts. We find strong evidence for subthreshold emission at MeV to GeV energies using both techniques. This observed excess is detected during intervals that include and exceed the durations typically characterizing the prompt emission observed at keV energies and lasts at least 2700 s after the co-aligned burst trigger. By utilizing a novel cumulative likelihood analysis, we find that although a burst’s prompt γ -ray and afterglow X-ray flux both correlate with the strength of the subthreshold emission, the X-ray afterglow flux measured by Swift ’ s X-ray Telescope at 11 hr post trigger correlates far more significantly. Overall, the extended nature of the subthreshold emission and its connection to the burst’s afterglow brightness lend further support to the external forward shock origin of the late-time emission detected by the LAT. These results suggest that the extended high-energy emission observed by the LAT may be a relatively common feature but remains undetected in a majority of bursts owing to instrumental threshold effects.

  13. Raman study of self-assembled InAs/InP quantum wire stacks with varying spacer thickness

    Science.gov (United States)

    Angelova, T.; Cros, A.; Cantarero, A.; Fuster, D.; González, Y.; González, L.

    2008-08-01

    Self-assembled InAs/InP (001) quantum wire stacks have been investigated by means of Raman scattering. The characteristics of the observed vibrational modes show clear evidence of confinement and atomic intermixing between As and P atoms from the wire and the spacer. The change in the intermixing with spacer layer thickness and growth temperature is investigated. Likewise, the effect of annealing on the exchange of As and P atoms is also studied. Resonance effects in confined and interface phonons are discussed for excitation in the vicinity of the InAs E1 critical point. Finally, the energy of the interface modes is related to the structural characteristics of the wires by comparing the experimental data with a lattice dynamic calculation based on the dielectric continuum model.

  14. Structural Aging Program to evaluate continued performance of safety-related concrete structures in nuclear power plants

    International Nuclear Information System (INIS)

    Naus, D.J.; Oland, C.B.; Ellingwood, B.R.

    1994-01-01

    This report discusses the Structural Aging (SAG) Program which is being conducted at the Oak Ridge National Laboratory (ORNL) for the United States Nuclear Regulatory commission (USNRC). The SAG Program is addressing the aging management of safety-related concrete structures in nuclear power plants for the purpose of providing improved technical bases for their continued service. The program is organized into three technical tasks: Materials Property Data Base, Structural Component Assessment/Repair Technologies, and Quantitative Methodology for continued Service Determinations. Objectives and a summary of recent accomplishments under each of these tasks are presented

  15. Structural Aging Program approach to providing an improved basis for aging management of safety-related concrete structures

    International Nuclear Information System (INIS)

    Naus, D.J.; Oland, C.B.; Ellingwood, B.

    1993-01-01

    The Structural Aging (SAG) Program is being conducted at the Oak Ridge National Laboratory (ORNL) for the United States Nuclear Regulatory Commission (USNRC). The SAG Program is addressing the aging management of safety-related concrete structures in nuclear power plants for the purpose of providing improved technical bases for their continued service. The program is organized into four tasks: Program Management, Materials Property Data Base, Structural Component Assessment/Repair Technologies, and Quantitative Methodology for Continued Service Determinations. Objectives and a summary of recent accomplishments under each of these tasks are presented

  16. Structural aging program to evaluate continued performance of safety-related concrete structures in nuclear power plants

    International Nuclear Information System (INIS)

    Naus, D.J.; Oland, C.B.; Ellingwood, B.R.

    1994-01-01

    The Structural Aging (SAG) Program is being conducted at the Oak Ridge National Laboratory (ORNL) for the United States Nuclear Regulatory Commission (USNRC). The SAG Program is addressing the aging management of safety-related concrete structures in nuclear power plants for the purpose of providing improved technical bases for their continued service. The program is organized into three technical tasks: Materials Property Data Base, Structural Component Assessment/Repair Technologies, and Quantitative Methodology for Continued Service Determinations. Objectives and a summary of recent accomplishments under each of these tasks are presented. (Author)

  17. Stack: the data structure of all programmers | NDEEKOR | Global ...

    African Journals Online (AJOL)

    Global Journal of Pure and Applied Sciences. Journal Home · ABOUT THIS JOURNAL · Advanced Search · Current Issue · Archives · Journal Home > Vol 7, No 4 (2001) >. Log in or Register to get access to full text downloads. Username, Password, Remember me, or Register. DOWNLOAD FULL TEXT Open Access ...

  18. Assessment and management of aging of nuclear power plant safety-related structures

    International Nuclear Information System (INIS)

    Naus, D.J.; Graves, H.L. III; Ellingwood, B.R.

    2003-01-01

    Background information and data have been developed for improving existing and developing new methods to assist in quantifying the effects of age-related degradation on the performance of nuclear power plant (NPP) safety-related structures. Factors that can lead to age-related degradation of safety-related structures are identified and their manifestations described. Current regulatory testing and inspection requirements are reviewed and a summary of degradation experience presented. Techniques commonly used to inspect NPP concrete structures to assess and quantify age-related degradation are summarized. An approach for conduct of condition assessments of structures in NPPs is presented. Criteria, based primarily on visual indications, are provided for use in classification and assessment of concrete degradation. Materials and techniques for repair of degraded structures are noted and guidance provided on repair options available for various forms of degradation. A probabilistic methodology for condition assessment and reliability-based life prediction has been developed and applied to structures subject to combinations of structural load processes and to structural systems. The methodology has also been used to investigate optimization of in-service inspection and maintenance strategies to maintain failure probability below a specified target value as well as to minimize costs. Fragility assessments involving analytical solutions and finite-element methods have been utilized to predict the effect of aging degradation on structural component performance. (author)

  19. Interfacial interaction and glassy dynamics in stacked thin films of poly(methyl methacrylate)

    Science.gov (United States)

    Hayashi, Tatsuhiko; Segawa, Kenta; Sadakane, Koichiro; Fukao, Koji; Yamada, Norifumi L.

    2017-05-01

    Neutron reflectivity and dielectric permittivity of alternately stacked thin films of protonated and deuterated poly(methyl methacrylate) were measured to elucidate a correlation between the time evolution of the interfacial structure and the segmental dynamics in the stacked thin polymer films during isothermal annealing above the glass transition temperature. The roughness at the interface between two thin layers increases with the annealing time, whereas the relaxation rate and strength of the α-process decrease with an increase in the annealing time. A strong correlation between the time evolution of the interfacial structure and the dynamics of the α-process during annealing could be observed using neutron reflectivity and dielectric relaxation measurements.

  20. ATLAS software stack on ARM64

    CERN Document Server

    Smith, Joshua Wyatt; The ATLAS collaboration

    2016-01-01

    The ATLAS experiment explores new hardware and software platforms that, in the future, may be more suited to its data intensive workloads. One such alternative hardware platform is the ARM architecture, which is designed to be extremely power efficient and is found in most smartphones and tablets. CERN openlab recently installed a small cluster of ARM 64-bit evaluation prototype servers. Each server is based on a single-socket ARM 64-bit system on a chip, with 32 Cortex-A57 cores. In total, each server has 128 GB RAM connected with four fast memory channels. This paper reports on the port of the ATLAS software stack onto these new prototype ARM64 servers. This included building the "external" packages that the ATLAS software relies on. Patches were needed to introduce this new architecture into the build as well as patches that correct for platform specific code that caused failures on non-x86 architectures. These patches were applied such that porting to further platforms will need no or only very little adj...