WorldWideScience

Sample records for stable atmospheric surface

  1. Exploring Scintillometry in the Stable Atmospheric Surface Layer

    NARCIS (Netherlands)

    Hartogensis, O.K.

    2006-01-01

    The main objective of this thesis is to investigate observation methods of heat and momentum exchange and key variables that characterise turbulence in the atmospheric stable surface layer (SSL), a layer defined as the lower part of the stable boundary layer (SBL) where surface fluxes do not change

  2. Variance Method to Determine Turbulent Fluxes of Momentum And Sensible Heat in The Stable Atmospheric Surface Layer

    NARCIS (Netherlands)

    Debruin, H.A.R.; Hartogensis, O.K.

    2005-01-01

    Evidence is presented that in the stable atmospheric surface layer turbulent fluxes of heat and momentum can be determined from the standard deviations of longitudinal wind velocity and temperature, ¿u and ¿T respectively, measured at a single level. An attractive aspect of this method is that it

  3. Modelling stable atmospheric boundary layers over snow

    NARCIS (Netherlands)

    Sterk, H.A.M.

    2015-01-01

    Thesis entitled:

    Modelling Stable Atmospheric Boundary Layers over Snow

    H.A.M. Sterk

    Wageningen, 29th of April, 2015

    Summary

    The emphasis of this thesis is on the understanding and forecasting of the Stable Boundary Layer (SBL) over snow-covered surfaces. SBLs

  4. Modelling stable atmospheric boundary layers over snow

    NARCIS (Netherlands)

    Sterk, H.A.M.

    2015-01-01

    Thesis entitled: Modelling Stable Atmospheric Boundary Layers over Snow H.A.M. Sterk Wageningen, 29th of April, 2015 Summary The emphasis of this thesis is on the understanding and forecasting of the Stable Boundary Layer (SBL) over snow-covered surfaces. SBLs typically form at night and in polar

  5. Pluto's surface composition and atmosphere

    Science.gov (United States)

    Young, L. A.; Gladstone, R.; Summers, M. E.; Strobel, D. F.; Kammer, J.; Hinson, D. P.; Grundy, W. M.; Cruikshank, D. P.; Protopapa, S.; Schmitt, B.; Stern, A.; Weaver, H. A., Jr.; Olkin, C.; Ennico Smith, K.

    2017-12-01

    New Horizons studied Pluto's N2-dominated neutral atmosphere through radio (at 4.2 cm with the REX radio experiment), solar and stellar occultations and airglow (at 52-187 nm with the Alice ultraviolet spectrograph), and imaging (with the LORRI and MVIC visible-wavelength cameras). It studied the plasma environment and solar wind interaction with in situ instruments (PEPPSI and SWAP). Contemporaneous observations of Pluto's atmosphere from Earth included a ground-based stellar occultation and ALMA observations of gaseous CO and HCN. Joint analysis of these datasets reveal a variable boundary layer; a stable lower atmosphere; radiative heating and cooling; haze production and hydrocarbon chemistry; diffusive equilibrium; and slower-than-expected escape. New Horizons studied Pluto's surface composition with the LEISA near-infrared spectral imager from 1.25 to 2.5 micron. Additional compositional information at higher spatial resolution came from the MVIC 4-channel color imager, which included a channel centered at 0.89 micron specifically designed to detect solid CH4. These instruments allow mapping of the volatiles N2, CO, and CH4, the surface expression of the H2O bedrock, and the dark, reddish material presumed to be tholins. These observations reveal a large equatorial basin (informally named Sptunik Planitia), filled with N2 ice with minor amounts of CO and CH4, surrounded by hills of CH4 and H2O ice. Broadly speaking, composition outside of Sptunik Planitia follows latitudinal banding, with dark, mainly volatile free terrains near the equator, with N2, CO, and CH4 at mid-northern latitudes, and mainly CH4 at high northern latitudes. Deviations from these broad trends are seen, and point to complex surface-atmosphere interactions at diurnal, seasonal, perennial, and million-year timescales.

  6. Are Vicinal Metal Surfaces Stable?

    DEFF Research Database (Denmark)

    Frenken, J. W. M.; Stoltze, Per

    1999-01-01

    We use effective medium theory to demonstrate that the energies of many metal surfaces are lowered when these surfaces are replaced by facets with lower-index orientations. This implies that the low-temperature equilibrium shapes of many metal crystals should be heavily faceted. The predicted...... instability of vicinal metal surfaces is at variance with the almost generally observed stability of these surfaces. We argue that the unstable orientations undergo a defaceting transition at relatively low temperatures, driven by the high vibrational entropy of steps....

  7. Improved Atmospheric Stable Boundary Layer Formulations for Navy Seasonal Forecasting

    Science.gov (United States)

    2012-09-30

    Long-term goals are to develop methods, descriptions and parameterizations that will alleviate long-standing problems in basically all large-scale numerical atmospheric models in dealing with statically stable and/or very stable conditions, and to implement these for Navy extended forecasting

  8. Modelling land surface - atmosphere interactions

    DEFF Research Database (Denmark)

    Rasmussen, Søren Højmark

    The study is investigates modelling of land surfaceatmosphere interactions in context of fully coupled climatehydrological model. With a special focus of under what condition a fully coupled model system is needed. Regional climate model inter-comparison projects as ENSEMBLES have shown bias...

  9. Surface enrichment of Pt in stable Pt-Ir nano-alloy particles on MgAl 2 O 4 spinel in oxidizing atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Li, Weizhen; Nie, Lei; Chen, Ying; Kovarik, Libor; Liu, Jun; Wang, Yong

    2017-04-01

    With the capability of MgAl2O4 spinel {111} nano-facets in stabilizing small Rh, Ir and Pt particles, bimetallic Ir-Pt catalysts on the same support were investigated, aiming at further lowering the catalyst cost by substituting expensive Pt with cheaper Ir in the bulk. Small Pt-Ir nano-alloy particles (< 2nm) were successfully stabilized on the spinel {111} nano-facets as expected. Interestingly, methanol oxidative dehydrogenation (ODH) rate on the surface Pt atoms increases with oxidizing aging but decreases upon reducing treatment, where Ir is almost inactive under the same reaction conditions. Up to three times enhancement in Pt exposure was achieved when the sample was oxidized at 800 °C in air for 1 week and subsequently reduced by H2 for 2 h, demonstrating successful surface enrichment of Pt on Pt-Ir nano-alloy particles. A dynamic stabilization mechanism involving wetting\

  10. Modelling land surface - atmosphere interactions

    DEFF Research Database (Denmark)

    Rasmussen, Søren Højmark

    related to inaccurate land surface modelling, e.g. enhanced warm bias in warm dry summer months. Coupling the regional climate model to a hydrological model shows the potential of improving the surface flux simulations in dry periods and the 2 m air temperature in general. In the dry periods......The study is investigates modelling of land surfaceatmosphere interactions in context of fully coupled climatehydrological model. With a special focus of under what condition a fully coupled model system is needed. Regional climate model inter-comparison projects as ENSEMBLES have shown bias...

  11. Stable isotope composition of atmospheric carbon monoxide. A modelling study

    International Nuclear Information System (INIS)

    Gromov, Sergey S.

    2014-01-01

    This study aims at an improved understanding of the stable carbon and oxygen isotope composition of the carbon monoxide (CO) in the global atmosphere by means of numerical simulations. At first, a new kinetic chemistry tagging technique for the most complete parameterisation of isotope effects has been introduced into the Modular Earth Submodel System (MESSy) framework. Incorporated into the ECHAM/MESSy Atmospheric Chemistry (EMAC) general circulation model, an explicit treatment of the isotope effects on the global scale is now possible. The expanded model system has been applied to simulate the chemical system containing up to five isotopologues of all carbon- and oxygen-bearing species, which ultimately determine the δ 13 C, δ 18 O and Δ 17 O isotopic signatures of atmospheric CO. As model input, a new stable isotope-inclusive emission inventory for the relevant trace gases has been compiled. The uncertainties of the emission estimates and of the resulting simulated mixing and isotope ratios have been analysed. The simulated CO mixing and stable isotope ratios have been compared to in-situ measurements from ground-based observatories and from the civil-aircraft-mounted CARIBIC-1 measurement platform. The systematically underestimated 13 CO/ 12 CO ratios of earlier, simplified modelling studies can now be partly explained. The EMAC simulations do not support the inferences of those studies, which suggest for CO a reduced input of the highly depleted in 13 C methane oxidation source. In particular, a high average yield of 0.94 CO per reacted methane (CH 4 ) molecule is simulated in the troposphere, to a large extent due to the competition between the deposition and convective transport processes affecting the CH 4 to CO reaction chain intermediates. None of the other factors, assumed or disregarded in previous studies, however hypothesised to have the potential in enriching tropospheric CO in 13 C, were found significant when explicitly simulated. The

  12. Stable atmospheric methane in the 2000s: key-role of emissions from natural wetlands

    OpenAIRE

    I. Pison; B. Ringeval; P. Bousquet; C. Prigent; F. Papa

    2013-01-01

    Two atmospheric inversions (one fine-resolved and one process-discriminating) and a process-based model for land surface exchanges are brought together to analyze the variations of methane emissions from 1990 to 2009. A focus is put on the role of natural wetlands and on the years 2000–2006, a period of stable atmospheric concentrations. From 1990 to 2000, the two inversions agree on the time-phasing of global emission anomalies. The process-discriminating inversion further indicates...

  13. Preparation of stable silica surfaces for surface forces measurement

    Science.gov (United States)

    Ren, Huai-Yin; Mizukami, Masashi; Kurihara, Kazue

    2017-09-01

    A surface forces apparatus (SFA) measures the forces between two surfaces as a function of the surface separation distance. It is regarded as an essential tool for studying the interactions between two surfaces. However, sample surfaces used for the conventional SFA measurements have been mostly limited to thin (ca. 2-3 μm) micas, which are coated with silver layers (ca. 50 nm) on their back, due to the requirement of the distance determination by transmission mode optical interferometry called FECO (fringes of equal chromatic order). The FECO method has the advantage of determining the absolute distance, so it should be important to increase the availability of samples other than mica, which is chemically nonreactive and also requires significant efforts for cleaving. Recently, silica sheets have been occasionally used in place of mica, which increases the possibility of surface modification. However, in this case, the silver layer side of the sheet is glued on a cylindrical quartz disc using epoxy resin, which is not stable in organic solvents and can be easily swollen or dissolved. The preparation of substrates more stable under severe conditions, such as in organic solvents, is necessary for extending application of the measurement. In this study, we report an easy method for preparing stable silica layers of ca. 2 μm in thickness deposited on gold layers (41 nm)/silica discs by sputtering, then annealed to enhance the stability. The obtained silica layers were stable and showed no swelling in organic solvents such as ethanol and toluene.

  14. Fractionation of Stable Isotopes in Atmospheric Aerosol Reactions

    DEFF Research Database (Denmark)

    Meusinger, Carl

    Aerosols - particles suspended in air - are the single largest uncertainty in our current understanding of Earth's climate. They also affect human health, infrastructure and ecosystems. Aerosols are emitted either directly into the atmosphere or are formed there for instance in response to chemical...... reactions and undergo complex chemical and physical changes during their lifetimes. In order to assess processes that form and alter aerosols, information provided by stable isotopes can be used to help constrain estimates on the strength of aerosol sources and sinks. This thesis studies (mass......-independent) fractionation processes of stable isotopes of C, N, O and S in order to investigate three different systems related to aerosols: 1. Post-depositional processes of nitrate in snow that obscure nitrate ice core records 2. Formation and aging of secondary organic aerosol generated by ozonolysis of X...

  15. Microwave generation of stable atmospheric-pressure fireballs in air

    Science.gov (United States)

    Stephan, Karl D.

    2006-11-01

    The generation of stable buoyant fireballs in a microwave cavity in air at atmospheric pressure without the use of vaporized solids is described. These fireballs have some of the characteristics of ball lightning and resemble those reported by Dikhtyar and Jerby [Phys. Rev. Lett. 96, 045002 (2006)], although of a different color, and do not require the presence of molten or vaporized material. Mechanisms of microwave plasma formation and fluid dynamics can account for the observed behavior of the fireballs, which do not appear to meet the accepted definition of dusty plasmas in this case. Relevance to models of ball lightning and industrial applications are discussed.

  16. Changes in calcification of coccoliths under stable atmospheric CO2

    DEFF Research Database (Denmark)

    Berger, C.; Meier, K. J. S.; Kinkel, H.

    2014-01-01

    The response of coccolithophore calcification to ocean acidification has been studied in culture experiments as well as in present and past oceans. The response, however, is different between species and strains, and for the relatively small carbonate chemistry changes observed in natural...... North Atlantic Ocean. The pre-industrial Holocene, with its predominantly stable atmospheric CO2, provides the conditions for such a comprehensive analysis. For an analysis on changes in major components of Holocene coccolithophores under natural conditions, the family Noelaerhabdaceae was selected...

  17. Structure of stable degeneration of K3 surfaces into pairs of rational elliptic surfaces

    OpenAIRE

    Kimura, Yusuke

    2018-01-01

    F-theory/heterotic duality is formulated in the stable degeneration limit of a K3 fibration on the F-theory side. In this note, we analyze the structure of the stable degeneration limit. We discuss whether stable degeneration exists for pairs of rational elliptic surfaces. We demonstrate that, when two rational elliptic surfaces have an identical complex structure, stable degeneration always exists. We provide an equation that systematically describes the stable degeneration of a K3 surface i...

  18. Stable pair invariants of surfaces and Seiberg-Witten invariants

    NARCIS (Netherlands)

    Kool, M.

    2016-01-01

    The moduli space of stable pairs on a local surface X = KS is in general non-compact. The action of C ∗ on the fibres of X induces an action on the moduli space and the stable pair invariants of X are defined by the virtual localization formula. We study the contribution to these invariants of

  19. Highly stable superhydrophobic surfaces under flow conditions

    Science.gov (United States)

    Lee, Moonchan; Yim, Changyong; Jeon, Sangmin

    2015-01-01

    We synthesized hydrophobic anodic aluminum oxide nanostructures with pore diameters of 35, 50, 65, and 80 nm directly on quartz crystal microresonators, and the stability of the resulting superhydrophobicity was investigated under flow conditions by measuring changes in the resonance frequency and dissipation factor. When the quartz substrates were immersed in water, their hydrophobic surfaces did not wet due to the presence of an air interlayer. The air interlayer was gradually replaced by water over time, which caused decreases in the resonance frequency (i.e., increases in mass) and increases in the dissipation factor (i.e., increases in viscous damping). Although the water contact angles of the nanostructures increased with increasing pore size, the stability of their superhydrophobicity increased with decreasing pore size under both static conditions (without flow) and dynamic conditions (with flow); this increase can be attributed to an increase in the solid surface area that interacts with the air layer above the nanopores as the pore size decreases. Further, the effects of increasing the flow rate on the stability of the superhydrophobicity were quantitatively determined.

  20. Surface-atmosphere decoupling limits accumulation at Summit, Greenland.

    Science.gov (United States)

    Berkelhammer, Max; Noone, David C; Steen-Larsen, Hans Christian; Bailey, Adriana; Cox, Christopher J; O'Neill, Michael S; Schneider, David; Steffen, Konrad; White, James W C

    2016-04-01

    Despite rapid melting in the coastal regions of the Greenland Ice Sheet, a significant area (~40%) of the ice sheet rarely experiences surface melting. In these regions, the controls on annual accumulation are poorly constrained owing to surface conditions (for example, surface clouds, blowing snow, and surface inversions), which render moisture flux estimates from myriad approaches (that is, eddy covariance, remote sensing, and direct observations) highly uncertain. Accumulation is partially determined by the temperature dependence of saturation vapor pressure, which influences the maximum humidity of air parcels reaching the ice sheet interior. However, independent proxies for surface temperature and accumulation from ice cores show that the response of accumulation to temperature is variable and not generally consistent with a purely thermodynamic control. Using three years of stable water vapor isotope profiles from a high altitude site on the Greenland Ice Sheet, we show that as the boundary layer becomes increasingly stable, a decoupling between the ice sheet and atmosphere occurs. The limited interaction between the ice sheet surface and free tropospheric air reduces the capacity for surface condensation to achieve the rate set by the humidity of the air parcels reaching interior Greenland. The isolation of the surface also acts to recycle sublimated moisture by recondensing it onto fog particles, which returns the moisture back to the surface through gravitational settling. The observations highlight a unique mechanism by which ice sheet mass is conserved, which has implications for understanding both past and future changes in accumulation rate and the isotopic signal in ice cores from Greenland.

  1. Surface Modification of Polyethylene Films using Atmospheric

    African Journals Online (AJOL)

    Dr A.B.Ahmed

    ABSTRACT. An atmospheric-pressure plasma jet (APPJ) is used to increase the wettability of polyethylene polymer films. Reduction in contact angle from 94.32 to 58.33 degrees was measured for treatment times of 1 - 5 seconds. Contact angle reductions of PE as a function of treatment time with APPJ and PE surface at ...

  2. Surface modification of polyethylene films using atmospheric ...

    African Journals Online (AJOL)

    An atmospheric-pressure plasma jet (APPJ) is used to increase the wettability of polyethylene polymer films. Reduction in contact angle from 94.32 to 58.33 degrees was measured for treatment times of 1 - 5 seconds. Contact angle reductions of PE as a function of treatment time with APPJ and PE surface at various oxygen ...

  3. Acoustic tomography in the atmospheric surface layer

    Directory of Open Access Journals (Sweden)

    A. Ziemann

    Full Text Available Acoustic tomography is presented as a technique for remote monitoring of meteorological quantities. This method and a special algorithm of analysis can directly produce area-averaged values of meteorological parameters. As a result consistent data will be obtained for validation of numerical atmospheric micro-scale models. Such a measuring system can complement conventional point measurements over different surfaces. The procedure of acoustic tomography uses the horizontal propagation of sound waves in the atmospheric surface layer. Therefore, to provide a general overview of sound propagation under various atmospheric conditions a two-dimensional ray-tracing model according to a modified version of Snell's law is used. The state of the crossed atmosphere can be estimated from measurements of acoustic travel time between sources and receivers at different points. Derivation of area-averaged values of the sound speed and furthermore of air temperature results from the inversion of travel time values for all acoustic paths. Thereby, the applied straight ray two-dimensional tomographic model using SIRT (simultaneous iterative reconstruction technique is characterised as a method with small computational requirements, satisfactory convergence and stability properties as well as simple handling, especially, during online evaluation.

    Key words. Meteorology and atmospheric dynamics (turbulence; instruments and techniques.

  4. The stable moduli space of Riemann surfaces: Mumford's conjecture

    DEFF Research Database (Denmark)

    Madsen, I.; Weiss, Michael

    2007-01-01

    , one may replace the stable moduli space of Riemann surfaces by $B\\Gamma_{\\infty}$, where $\\Gamma_\\infty$ is the group of isotopy classes of automorphisms of a smooth oriented connected surface of ``large'' genus. Tillmann's theorem that the plus construction makes $B\\Gamma_{\\infty}$ into an infinite...

  5. Stable isotope ratio measurements in atmospheric sulfate studies

    Energy Technology Data Exchange (ETDEWEB)

    Cunningham, P.T.; Holt, B.D.

    1976-01-01

    The isotopic composition of atmospheric sulfate has been determined by a number of workers and the results interpreted in terms of contributing sources and mechanisms of origin. A correlation between the /sup 18/O enrichment of atmospheric water and airborne particulate sulfate has been observed. Laboratory preparations of sulfate made from sulfur dioxide by two sets of sequential reactions, hydrolysis followed by oxidation and oxidation followed by hydrolysis, yielded products of distinguishable oxygen-isotope composition. Oxygen isotopic analysis of simultaneously collected field samples of ambient sulfate, sulfur dioxide, and water vapor indicated seasonal trends for all of the major constituents of atmospheric sulfation processes. Some isotopic data were also obtained on precipitation and precipitation sulfates. Field results suggest that ambient sulfates collected in the area of Argonne correpond more closely in oxygen isotope composition to a sulfate molecule containing two oxygens originating from sulfur dioxide, one oxygen from air and one oxygen from condensed-phased atmospheric water, SO/sub s/O/sub s/O/sub cw/O/sup 2 -//sub a/, than to the molecule SO/sub s/O/sub s/O/sub wv/O/sup 2//sub a/ in which one oxygen originates from vapor-phase atmospheric water.

  6. Stable isotope ratio measurements in atmospheric sulfate studies

    International Nuclear Information System (INIS)

    Cunningham, P.T.; Holt, B.D.

    1976-01-01

    The isotopic composition of atmospheric sulfate has been determined by a number of workers and the results interpreted in terms of contributing sources and mechanisms of origin. A correlation between the 18 O enrichment of atmospheric water and airborne particulate sulfate has been observed. Laboratory preparations of sulfate made from sulfur dioxide by two sets of sequential reactions, hydrolysis followed by oxidation and oxidation followed by hydrolysis, yielded products of distinguishable oxygen-isotope composition. Oxygen isotopic analysis of simultaneously collected field samples of ambient sulfate, sulfur dioxide, and water vapor indicated seasonal trends for all of the major constituents of atmospheric sulfation processes. Some isotopic data were also obtained on precipitation and precipitation sulfates. Field results suggest that ambient sulfates collected in the area of Argonne correpond more closely in oxygen isotope composition to a sulfate molecule containing two oxygens originating from sulfur dioxide, one oxygen from air and one oxygen from condensed-phased atmospheric water, SO/sub s/O/sub s/O/sub cw/O 2- /sub a/, than to the molecule SO/sub s/O/sub s/O/sub wv/O 2 /sub a/ in which one oxygen originates from vapor-phase atmospheric water

  7. Fractionation of Stable Isotopes in Atmospheric Aerosol Reactions

    DEFF Research Database (Denmark)

    Meusinger, Carl

    reactions and undergo complex chemical and physical changes during their lifetimes. In order to assess processes that form and alter aerosols, information provided by stable isotopes can be used to help constrain estimates on the strength of aerosol sources and sinks. This thesis studies (mass......-independent) fractionation processes of stable isotopes of C, N, O and S in order to investigate three different systems related to aerosols: 1. Post-depositional processes of nitrate in snow that obscure nitrate ice core records 2. Formation and aging of secondary organic aerosol generated by ozonolysis of X...... as required. The kndings provide important results for the studies' respective felds, including a description of the isotopic fractionation and quantum yield of nitrate photolysis in snow, equilibrium fractionation in secondary organic aerosol and fractionation constants of different oxidation pathways of SO2....

  8. Comparing Stable Water Isotope Variation in Atmospheric Moisture Observed over Coastal Water and Forests

    Science.gov (United States)

    Lai, C. T.; Rambo, J. P.; Welp, L. R.; Bible, K.; Hollinger, D. Y.

    2014-12-01

    Stable oxygen (δ18O) and hydrogen (δD) isotopologues of atmospheric moisture are strongly influenced by large-scale synoptic weather cycles, surface evapotranspiration and boundary layer mixing. Atmospheric water isotope variation has been shown to empirically relate to relative humidity (Rh) of near surface moisture, and to a less degree, air temperature. Continuous δ18O and δD measurements are becoming more available, providing new opportunities to investigate processes that control isotope variability. This study shows the comparison of δ18O and δD measured at a continental location and over coastal waters for 3 seasons (spring to fall, 2014). The surface moisture isotope measurements were made using two LGR spectroscopy water vapor isotope analyzers (Los Gatos Research Inc.), one operated in an old-growth coniferous forest at Wind River field station, WA (45.8205°N, 121.9519°W), and another sampling marine air over seawater at the Scripps Pier in San Diego, CA (32.8654°N, 117.2536°W), USA. Isotope variations were measured at 1Hz and data were reported as hourly averages with an overall accuracy of ±0.1‰ for δ18O, ±0.5‰ for δ2H. Day-to-day variations in δ18O and δD are shown strongly influenced by synoptic weather events at both locations. Boundary layer mixing between surface moisture and the dry air entrained from the free troposphere exerts a midday maximum and a consistent diel pattern in deuterium excess (dx). At the forest site, surface moisture also interacts with leaf water through transpiration during the day and re-equilibration at night. The latter occurs by retro-diffusion of atmospheric H2O molecules into leaf intercellular space, which becomes intensified as Rh increaes after nightfall, and continues until sunrise, to counter-balance the evaporative isotopic enrichment in leaf water on a daily basis. These vegetation effects lead to negative dx values consistently observed at nighttime in this continental location that were not

  9. Stable Atmospheric Boundary Layer Experiment in Spain (SABLES 98) : a report

    NARCIS (Netherlands)

    Cuxart, J.; Yague, C.; Morales, G.; Terradelles, E.; Orbe, J.; Calvo, J.; Vilu-Guerau, de J.; Soler, M.R.; Infante, C.; Buenestado, P.; Espinalt, A.; Jorgensem, H.E.

    2000-01-01

    This paper describes the Stable Atmospheric Boundary Layer Experiment in Spain (SABLES 98), which took place over the northern Spanish plateau comprising relatively flat grassland, in September 1998. The main objectives of the campaign were to study the properties of the mid-latitude stable boundary

  10. Stable atmospheric boundary-layer experiment in Spain (SABLES 98): A report

    DEFF Research Database (Denmark)

    Cuxart, J.; Yague, C.; Morales, G.

    2000-01-01

    This paper describes the Stable Atmospheric Boundary Layer Experiment in Spain (SABLES 98), which took place over the northern Spanish plateau comprising relatively flat grassland, in September 1998. The main objectives of the campaign were to study the properties of the mid-latitude stable...

  11. Carbon and Oxygen Stable Isotope Measurements of Martian Atmospheric CO2 by the Phoenix Lander

    Science.gov (United States)

    Niles, Paul B.; Boynton, W. V.; Hoffman, J. H.; Ming, D. W.; Hamara, D.

    2010-01-01

    Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars [1]. The isotopic composition of the martian atmosphere has been measured using a number of different methods (Table 1), however a precise value (isotopic composition of martian atmospheric CO2 to within 0.5%. The mass spectrometer is a miniature instrument intended to measure both the martian atmosphere as well as gases evolved from heating martian soils.

  12. Long-term stable surface modification of DLC coatings

    Directory of Open Access Journals (Sweden)

    Gotzmann Gaby

    2017-09-01

    Full Text Available The use of coatings based on diamond like carbon (DLC for medical applications was established during the last years. Main advantages of these coatings are its high hardness, good wear and friction behavior and its biocompatibility. Using low-energy electron-beam treatment, we addressed the surface modification of DLC coatings. The aim was to generate new biofunctional surface characteristics that are long-term stable.

  13. Lateral Dispersion of Pollutants in a Very Stable Atmosphere - The Effect of Meandering

    DEFF Research Database (Denmark)

    Kristensen, Leif; Jensen, Niels Otto; Lundtang Petersen, Erik

    1981-01-01

    A model based on single particle diffusion is introduced to account for the effect of “meandering” on lateral plume dispersion in a very stable atmosphere. It is assumed that small scale atmospheric turbulence is absent, so that only large horizontal eddies are effective. A formula for the lateral....... Meteorological data from Risø and the small island Sprogø have been analysed in order to identify all situations in which the atmosphere is so stable that small scale turbulence cannot exist. The purpose is to see in how many of these situations meandering is also absent. The results show that, as a rule...

  14. Macromolecular surface design: photopatterning of functional stable nitrile oxides.

    Science.gov (United States)

    Altintas, Ozcan; Glassner, Mathias; Rodriguez-Emmenegger, Cesar; Welle, Alexander; Trouillet, Vanessa; Barner-Kowollik, Christopher

    2015-05-04

    The efficient trapping of photogenerated thioaldehydes with functional shelf-stable nitrile oxides in a 1,3-dipolar cycloaddition is a novel and versatile photochemical strategy for polymer end-group functionalization and surface modification under mild and equimolar conditions. The modular ligation in solution was followed in detail by electrospray ionization mass spectrometry (ESI-MS). X-ray photoelectron spectroscopy (XPS) was employed to analyze the functionalized surfaces, whereas time-of-flight secondary-ion mass spectrometry (ToF-SIMS) confirmed the spatial control of the surface functionalization using a micropatterned shadow mask. Polymer brushes were grown from the surface in a spatially confined regime by surface-initiated atom transfer radical polymerization (SI-ATRP) as confirmed by TOF-SIMS, XPS as well as ellipsometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Stable water isotope and surface heat flux simulation using ISOLSM: Evaluation against in-situ measurements

    KAUST Repository

    Cai, Mick Y.

    2015-04-01

    The stable isotopes of water are useful tracers of water sources and hydrological processes. Stable water isotope-enabled land surface modeling is a relatively new approach for characterizing the hydrological cycle, providing spatial and temporal variability for a number of hydrological processes. At the land surface, the integration of stable water isotopes with other meteorological measurements can assist in constraining surface heat flux estimates and discriminate between evaporation (E) and transpiration (T). However, research in this area has traditionally been limited by a lack of continuous in-situ isotopic observations. Here, the National Centre for Atmospheric Research stable isotope-enabled Land Surface Model (ISOLSM) is used to simulate the water and energy fluxes and stable water isotope variations. The model was run for a period of one month with meteorological data collected from a coastal sub-tropical site near Sydney, Australia. The modeled energy fluxes (latent heat and sensible heat) agreed reasonably well with eddy covariance observations, indicating that ISOLSM has the capacity to reproduce observed flux behavior. Comparison of modeled isotopic compositions of evapotranspiration (ET) against in-situ Fourier Transform Infrared spectroscopy (FTIR) measured bulk water vapor isotopic data (10. m above the ground), however, showed differences in magnitude and temporal patterns. The disparity is due to a small contribution from local ET fluxes to atmospheric boundary layer water vapor (~1% based on calculations using ideal gas law) relative to that advected from the ocean for this particular site. Using ISOLSM simulation, the ET was partitioned into E and T with 70% being T. We also identified that soil water from different soil layers affected T and E differently based on the simulated soil isotopic patterns, which reflects the internal working of ISOLSM. These results highlighted the capacity of using the isotope-enabled models to discriminate

  16. Structure of stable degeneration of K3 surfaces into pairs of rational elliptic surfaces

    Science.gov (United States)

    Kimura, Yusuke

    2018-03-01

    F-theory/heterotic duality is formulated in the stable degeneration limit of a K3 fibration on the F-theory side. In this note, we analyze the structure of the stable degeneration limit. We discuss whether stable degeneration exists for pairs of rational elliptic surfaces. We demonstrate that, when two rational elliptic surfaces have an identical complex structure, stable degeneration always exists. We provide an equation that systematically describes the stable degeneration of a K3 surface into a pair of isomorphic rational elliptic surfaces. When two rational elliptic surfaces have different complex structures, whether their sum glued along a smooth fiber admits deformation to a K3 surface can be determined by studying the structure of the K3 lattice. We investigate the lattice theoretic condition to determine whether a deformation to a K3 surface exists for pairs of extremal rational elliptic surfaces. In addition, we discuss the configurations of singular fibers under stable degeneration. The sum of two isomorphic rational elliptic surfaces glued together admits a deformation to a K3 surface, the singular fibers of which are twice that of the rational elliptic surface. For special situations, singular fibers of the resulting K3 surface collide and they are enhanced to a fiber of another type. Some K3 surfaces become attractive in these situations. We determine the complex structures and the Weierstrass forms of these attractive K3 surfaces. We also deduce the gauge groups in F-theory compactifications on these attractive K3 surfaces times a K3. E 6, E 7, E 8, SU(5), and SO(10) gauge groups arise in these compactifications.

  17. Titan Coupled Surface/Atmosphere Retrievals

    Science.gov (United States)

    West, R. A.; Pitman, K. M.

    2009-05-01

    Titan's thick haze obscures its surface at visible wavelengths and hinders surface photometric studies in the near-infrared. The large vertical extent of the haze produces two effects which require radiative transfer analysis beyond the capability of plane-parallel multi-scatter models. Haze aerosols extend to altitudes above 500 km and require a spherical-shell RT algorithm close to the limb or terminator. Even near nadir viewing, horizontal scattering at spatial scales less than a few hundred km requires a code capable of simulating the adjacency effect. The adjacency effect will reduce contrast more for small spatial scales than for large spatial scales, and the amount of contrast reduction depends on many factors (haze optical thickness, vertical distribution, single scattering albedo, scattering geometry, spatial scale). Titan's haze is strongly forward scattering even near 1-µm wavelength and many RT codes do a poor job. Fortunately the problem is more tractable at longer wavelengths. We show how data from the Cassini VIMS and ISS instruments can be used to understand surface contrast and atmospheric haze properties.

  18. Atmosphere-surface interactions over polar oceans and heterogeneous surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Vihma, T.

    1995-12-31

    Processes of interaction between the atmospheric boundary layer and the planetary surface have been studied with special emphasis on polar ocean surfaces: the open ocean, leads, polynyas and sea ice. The local exchange of momentum, heat and moisture has been studied experimentally both in the Weddell Sea and in the Greenland Sea. Exchange processes over heterogeneous surfaces are addressed by modelling studies. Over a homogeneous surface, the local turbulent fluxes can be reasonably well estimated using an iterative flux-profile scheme based on the Monin-Obukhov similarity theory. In the Greenland Sea, the near-surface air temperature and the generally small turbulent fluxes over the open ocean were affected by the sea surface temperature fronts. Over the sea ice cover in the Weddell Sea, the turbulent sensible heat flux was generally downwards, and together with an upward oceanic heat flux through the ice it compensated the heat loss from the surface via long-wave radiation. The wind dominated on time scales of days, while the current became important on longer time scales. The drift dynamics showed apparent spatial differences between the eastern and western regions, as well as between the Antarctic Circumpolar Current and the rest of the Weddell Sea. Inertial motion was present in regions of low ice concentration. The surface heterogeneity, arising e.g. from roughness or temperature distribution, poses a problem for the parameterization of surface exchange processes in large-scale models. In the case of neutral flow over a heterogeneous terrain, an effective roughness length can be used to parameterize the roughness effects

  19. Studying biosphere-atmosphere exchange of CO2 through Carbon-13 stable isotopes

    NARCIS (Netherlands)

    Velde, van der I.R.

    2015-01-01

    Summary Thesis ‘Studying biosphere-atmosphere exchange of CO2 through carbon-13 stable isotopes’ Ivar van der Velde Making predictions of future climate is difficult, mainly due to large uncertainties in the carbon cycle. The rate at which carbon is stored in the oceans and terrestrial

  20. Studying biosphere-atmosphere exchange of CO2 through Carbon-13 stable isotopes

    NARCIS (Netherlands)

    Velde, van der I.R.

    2015-01-01

    Summary Thesis ‘Studying biosphere-atmosphere exchange of CO2 through

    carbon-13 stable isotopes’

    Ivar van der Velde

    Making predictions of future climate is difficult, mainly due to large uncertainties in the carbon cycle. The rate at which carbon is stored in the oceans and

  1. Stable atmospheric methane in the 2000s: key-role of emissions from natural wetlands

    Science.gov (United States)

    Pison, I.; Ringeval, B.; Bousquet, P.; Prigent, C.; Papa, F.

    2013-12-01

    Two atmospheric inversions (one fine-resolved and one process-discriminating) and a process-based model for land surface exchanges are brought together to analyse the variations of methane emissions from 1990 to 2009. A focus is put on the role of natural wetlands and on the years 2000-2006, a period of stable atmospheric concentrations. From 1990 to 2000, the top-down and bottom-up visions agree on the time-phasing of global total and wetland emission anomalies. The process-discriminating inversion indicates that wetlands dominate the time-variability of methane emissions (90% of the total variability). The contribution of tropical wetlands to the anomalies is found to be large, especially during the post-Pinatubo years (global negative anomalies with minima between -41 and -19 Tg yr-1 in 1992) and during the alternate 1997-1998 El-Niño/1998-1999 La-Niña (maximal anomalies in tropical regions between +16 and +22 Tg yr-1 for the inversions and anomalies due to tropical wetlands between +12 and +17 Tg yr-1 for the process-based model). Between 2000 and 2006, during the stagnation of methane concentrations in the atmosphere, the top-down and bottom-up approaches agree on the fact that South America is the main region contributing to anomalies in natural wetland emissions, but they disagree on the sign and magnitude of the flux trend in the Amazon basin. A negative trend (-3.9 ± 1.3 Tg yr-1) is inferred by the process-discriminating inversion whereas a positive trend (+1.3 ± 0.3 Tg yr-1) is found by the process model. Although processed-based models have their own caveats and may not take into account all processes, the positive trend found by the B-U approach is considered more likely because it is a robust feature of the process-based model, consistent with analysed precipitations and the satellite-derived extent of inundated areas. On the contrary, the surface-data based inversions lack constraints for South America. This result suggests the need for a re

  2. Is bicarbonate stable in and on the calcite surface?

    Science.gov (United States)

    Andersson, M. P.; Rodriguez-Blanco, J. D.; Stipp, S. L. S.

    2016-03-01

    We have used density functional theory with the COSMO-RS implicit solvent model to predict the pKa for the deprotonation of bicarbonate to carbonate, i.e. HCO3- CO32- + H+, when HCO3- is included in, and adsorbed on, a calcite surface. We have used cluster models (80-100 atoms) to represent the flat {10.4} surface, acute steps, obtuse steps, two types of kinks on the acute step and two types of kinks on the obtuse steps. Based on the predicted pKa values, which range from -6.0 to 2.4 depending on the surface site, we conclude that bicarbonate deprotonates to carbonate when it is in calcite even when pH in solution is very low. This is true for all surface sites, even for solutions where 2.4 < pH < 6.35, where H2CO30 is the dominant dissolved species. When bicarbonate is adsorbed on calcite, the predicted pKa for deprotonation is 7.5, which is ∼3 pH units lower than in aqueous solution, 10.35. This means that adsorbed carbonate is stable even when the concentration of dissolved CO32- is several orders of magnitude lower. This has a significant effect on surface charge and thus the behaviour of the calcite surface. Our results help explain the potential determining behaviour of the carbonate species in calcite-water systems, particularly in the pH range where the bicarbonate species dominates in water and where the carbonate species dominates at the surface, i.e. when 7.5 < pH < 10.35. Our atomic scale data for the various calcite surface sites provide the needed input to improve and constrain surface complexation modelling and are especially useful for predicting behaviour in systems where experiments are difficult or impossible, such as at high temperature and pressure.

  3. Taking the atmosphere's pulse: The application of GC-IRMS to stable isotopes in atmospheric trace gases

    International Nuclear Information System (INIS)

    Lowe, D.C.; Ferretti, D.J.; Francey, R.J.; Allison, C.E.

    2001-01-01

    Since the industrial revolution, the abundance of many atmospheric trace gases has changed significantly. This is of concern because many of these trace species play a fundamental role in determining physical and chemical properties of the atmosphere important for maintaining life on earth. The impacts of the changes have been studied by a combination of analytical and theoretical modelling techniques. Stable isotope measurements made by conventional dual inlet IRMS for example, have provided valuable constraints on the budgets and removal mechanisms of key atmospheric trace gases. Unfortunately, in most cases, the application of these methods has been limited, because large air samples and cumbersome off line processing techniques are required to pre-concentrate enough gas for analysis. GC-IRMS offers a very attractive alternative because it combines on line processing with air sample size requirements typically 1000 times less than used in conventional techniques. In this article we focus on the requirements imposed on GC-IRMS by some of the current applications in atmospheric trace gas research. In addition, we examine some of the analytical and calibration aspects of the method applied to this kind of work. We finish with a summary of some of the comparative advantages and disadvantages of the GC-IRMS technique and some suggestions for future research using the method applied to specific atmospheric trace gases. (author)

  4. Atmosphere-surface interactions on Venus and implications for atmospheric evolution

    International Nuclear Information System (INIS)

    Khodakovsky, I.L.

    1982-01-01

    The physico-chemical processes controlling the Venusian tropospheric chemical composition surface rock mineral assemblages and volatile element distribution in the atmosphere and planetary crust is considered. (author)

  5. Preliminary Interpretations of Atmospheric Stable Isotopes and Argon from Mars Science Laboratory (SAM)

    Science.gov (United States)

    Jones, J. H.; Niles, P. B.; Webster, C. R.; Mahaffy, P. R.; Flesch, G. J.; Christensen, L. E.; Leshin, L. A.; Franz, H.; Wong, M.; Atreya, S. K.; hide

    2013-01-01

    Given the broad agreement between C, H, and O isotopic ratios in the modern atmosphere and the ALH 84001 meteorite, it is possible that these reservoirs were established after early atmospheric loss prior to 4 Ga. The preservation of these signals over this long period of history can be explained in several slightly different ways: 1) C, O, and H have remained static in the atmosphere and have not exchanged with the surface over the past 4 Ga; 2) C, O, and H in the atmosphere have potentially varied widely over history but have been continually buffered by larger reservoirs in the crust which have remained unchanged over the past 4 Ga. This second possibility allows for potentially large variations in atmospheric pressure to occur as CO2 is recycled back into the atmosphere from crustal reservoirs or degassed from the mantle.

  6. Process Model for Studying Regional 13C Stable Isotope Exchange between Vegetation and Atmosphere

    Science.gov (United States)

    Chen, J. M.; Chen, B.; Huang, L.; Tans, P.; Worthy, D.; Ishizawa, M.; Chan, D.

    2007-12-01

    The variation of the stable isotope 13CO2 in the air in exchange with land ecosystems results from fractionation processes in both plants and soil during photosynthesis and respiration. Its diurnal and seasonal variations therefore contain information on the carbon cycle. We developed a model (BEPS-iso) to simulate its exchange between vegetation and the atmosphere. To be useful for regional carbon cycle studies, the model has the following characteristics: (i) it considers the turbulent mixing in the vertical profile from the soil surface to the top of the planetary boundary layer (PBL); (ii) it scales individual leaf photosynthetic discrimination to the whole canopy through the separation of sunlit and shaded leaf groups; (iii) through simulating leaf-level photosynthetic processes, it has the capacity to mechanistically examine isotope discrimination resulting from meteorological forcings, such as radiation, precipitation and humidity; and (iv) through complete modeling of radiation, energy and water fluxes, it also simulates soil moisture and temperature needed for estimating ecosystem respiration and the 13C signal from the soil. After validation using flask data acquired at 20 m level on a tower near Fraserdale, Ontario, Canada, during intensive campaigns (1998-2000), the model has been used for several purposes: (i) to investigate the diurnal and seasonal variations in the disequilibrium in 13C fractionation between ecosystem respiration and photosynthesis, which is an important step in using 13C measurements to separate these carbon cycle components; (ii) to quantify the 13C rectification in the PBL, which differs significantly from CO2 rectification because of the diurnal and seasonal disequilibriums; and (iii) to model the 13C spatial and temporal variations over the global land surface for the purpose of CO2 inversion using 13C as an additional constraint.

  7. A First Look at Carbon and Oxygen Stable Isotope Measurements of Martian Atmospheric C02 by the Phoenix Lander

    Science.gov (United States)

    Niles, P.B.; Ming, D.W.; Boynton, W.V.; Hamara, D.; Hoffman, J.H.

    2009-01-01

    Precise stable isotope measurements of the CO2 in the martian atmosphere have the potential to provide important constraints for our understanding of the history of volatiles, the carbon cycle, current atmospheric processes, and the degree of water/rock interaction on Mars. The isotopic composition of the martian atmosphere has been measured using a number of different methods (Table 1), however a precise value (isotope fractionations under martian surface conditions. The Thermal Evolved Gas Analyzer (TEGA) instrument on the Mars Phoenix Lander included a magnetic sector mass spectrometer (EGA) which had the goal of measuring the isotopic composition of martian atmospheric CO2 to within 0.5%. The mass spectrometer is a miniature magnetic sector instrument intended to measure both the martian atmosphere as well as gases evolved from heating martian soils. Ions produced in the ion source are drawn out by a high voltage and focused by a magnetic field onto a set of collector slits. Four specific trajectories are selected to cover the mass ranges, 0.7 - 4, 7 - 35, 14 - 70, and 28 - 140 Da. Using four channels reduces the magnitude of the mass scan and provides simultaneous coverage of the mass ranges. Channel electron multiplier (CEM) detectors that operate in the pulse counting mode detect the ion beams.

  8. In-induced stable ordering of stepped Si(553) surface

    Science.gov (United States)

    Chauhan, Amit Kumar Singh; Niazi, Asad; Nair, Lekha; Gupta, Govind

    2015-05-01

    The growth mechanism and adsorbate-induced surface morphology of metal atoms on semiconducting surfaces crucially determines the electronic and physicochemical properties of these metal/semiconductor systems. In this study, we investigate the kinetically controlled growth of indium (In) atoms on the high index stepped Si(553)-7 × 7 surface and the thermal stability of various novel In-induced superstructural phases formed during adsorption/desorption process. Auger electron spectroscopy analysis reveals that In adsorption at room temperature (RT) and at 350 °C, with a controlled incident flux of 0.0016 ML/s, proceeds in the Stranski-Krastanov growth mode where two dimensional (2D)/three dimensional (3D) islands are formed on top of two complete monolayers. At higher substrate temperature up to 450 °C, the growth of In atoms occurs in the form of islands on the bare Si(553) surface, and In coverage is limited to the sub-monolayer regime. During the thermal desorption of the RT grown In/Si(553) system, the In clusters rearrange themselves and an unusual "cluster to layer" transformation occurs on top of the stable monolayer. In situ low energy electron diffraction analysis during adsorption and desorption shows the development of various coverage and temperature dependent In-induced superstructural phases on Si(553) surface, such as: (8 × 2) after annealing at 520 °C with coverage 0.5 ML, (8 × 4) after annealing at 580 °C (∼1 ML coverage) and (553)-7 × 1 + (111)-√3 × √3-R30° at 0.3 ML (630 °C). These adsorbate-induced superstructural phases could potentially be utilized as templates for pattern assisted growth of various exotic 1D/2D structures for optoelectronics and photovoltaic applications.

  9. Numerical study of aircraft wake vortex evolution near ground in stable atmospheric boundary layer

    Directory of Open Access Journals (Sweden)

    Mengda LIN

    2017-12-01

    Full Text Available The evolutions of aircraft wake vortices near ground in stable atmospheric boundary layer are studied by Large Eddy Simulation (LES. The sensitivity of vortex evolution to the Monin-Obukhov (M-O scale is studied for the first time. The results indicate that increasing stability leads to longer lifetimes of upwind vortices, while downwind vortices will decay faster due to a stronger crosswind shear under stable conditions. Based on these results, an empirical model of the vortex lifetime as a function of 10-m-high crosswind and the M-O scale is summarized. This model can provide an estimate of the upper boundary of the vortex lifetime according to the real-time crosswind and atmospheric stability. In addition, the lateral translation of vortices is also inspected. The results show that vortices can travel a furthest distance of 722 m in the currently-studied parameter range. This result is meaningful to safety analysis of airports that have parallel runways. Keywords: Aerodynamics, Aircraft, Aircraft wake vortex, Large eddy simulation, Stable atmosphere boundary layer

  10. Extraction of 10–30-Day Stable Components from a Boreal Atmosphere during ENSO Phases

    Directory of Open Access Journals (Sweden)

    Kuo Wang

    2015-01-01

    Full Text Available Distinguishing the predictable 10–30-day stable components (STs in the actual atmosphere has been important in atmospheric science research. In this study, a new method for extracting 10–30-day STs was developed with the use of historical observations. We extracted and analyzed 10–30-day STs via statistical extrapolation tests. The results show that the STs are maintained uniformly at the intraseasonal time scale; the overall trends in the atmospheric motion are revealed. Comparisons between pentad-by-pentad changes in the explained variances of the 10–30-day STs under ENSO phases show that the explained variance transmission attenuation trends for El Niño and La Niña years are weaker and more continuous than those of neutral years. Data for 10–30-day STs can remain continuous and stable from one month to the next. The proposed method and results present a new means of extracting predictable STs from the atmosphere using historical data.

  11. Method for determination of stable carbon isotope ratio of methylnitrophenols in atmospheric particulate matter

    Directory of Open Access Journals (Sweden)

    S. Moukhtar

    2011-11-01

    Full Text Available A technique for the measurement of the stable isotope ratio of methylnitrophenols in atmospheric particulate matter is presented. Atmospheric samples from rural and suburban areas were collected for evaluation of the procedure. Particulate matter was collected on quartz fibre filters using dichotomous high volume air samplers. Methylnitrophenols were extracted from the filters using acetonitrile. The sample was then purified using a combination of high-performance liquid chromatography and solid phase extraction. The final solution was then divided into two aliquots. To one aliquot, a derivatising agent, Bis(trimethylsilyltrifluoroacetamide, was added for Gas Chromatography-Mass Spectrometry analysis. The second half of the sample was stored in a refrigerator. For samples with concentrations exceeding 1 ng μl−1, the second half of the sample was used for measurement of stable carbon isotope ratios by Gas Chromatography-Isotope Ratio Mass Spectrometry.

    The procedure described in this paper provides a method for the analysis of methylnitrophenols in atmospheric particulate matter at concentrations as low as 0.3 pg m−3 and for stable isotope ratios with an accuracy of better than ±0.5‰ for concentrations exceeding 100 pg m−3.

    In all atmospheric particulate matter samples analysed, 2-methyl-4-nitrophenol was found to be the most abundant methylnitrophenol, with concentrations ranging from the low pg m−3 range in rural areas to more than 200 pg m−3 in some samples from a suburban location.

  12. In-induced stable ordering of stepped Si(553) surface

    Energy Technology Data Exchange (ETDEWEB)

    Chauhan, Amit Kumar Singh [Physics of Energy Harvesting, (CSIR-NPL) , Dr. K.S. KrishnanRoad, New Delhi -110012 (India); Department of Physics, JMI, New Delhi 110025 (India); Niazi, Asad; Nair, Lekha [Department of Physics, JMI, New Delhi 110025 (India); Gupta, Govind, E-mail: govind@nplindia.org [Physics of Energy Harvesting, (CSIR-NPL) , Dr. K.S. KrishnanRoad, New Delhi -110012 (India)

    2015-05-15

    Highlights: • Control growth of In on step Si(553) & thermal stability of novel superstructure. • Influence of temperature on growth modes (SK,VB) under different growth conditions. • In-induced superstructure: (8 × 2), (8 × 4), mixed (553)-7 × 1 + (111)√3 × √3R30° phases. - Abstract: The growth mechanism and adsorbate-induced surface morphology of metal atoms on semiconducting surfaces crucially determines the electronic and physicochemical properties of these metal/semiconductor systems. In this study, we investigate the kinetically controlled growth of indium (In) atoms on the high index stepped Si(553)-7 × 7 surface and the thermal stability of various novel In-induced superstructural phases formed during adsorption/desorption process. Auger electron spectroscopy analysis reveals that In adsorption at room temperature (RT) and at 350 °C, with a controlled incident flux of 0.0016 ML/s, proceeds in the Stranski–Krastanov growth mode where two dimensional (2D)/three dimensional (3D) islands are formed on top of two complete monolayers. At higher substrate temperature up to 450 °C, the growth of In atoms occurs in the form of islands on the bare Si(553) surface, and In coverage is limited to the sub-monolayer regime. During the thermal desorption of the RT grown In/Si(553) system, the In clusters rearrange themselves and an unusual “cluster to layer” transformation occurs on top of the stable monolayer. In situ low energy electron diffraction analysis during adsorption and desorption shows the development of various coverage and temperature dependent In-induced superstructural phases on Si(553) surface, such as: (8 × 2) after annealing at 520 °C with coverage 0.5 ML, (8 × 4) after annealing at 580 °C (∼1 ML coverage) and (553)-7 × 1 + (111)-√3 × √3-R30° at 0.3 ML (630 °C). These adsorbate-induced superstructural phases could potentially be utilized as templates for pattern assisted growth of various exotic 1D/2D structures for

  13. Using stable isotopes to resolve eco-hydrological dynamics of soil-plant-atmosphere feedbacks

    Science.gov (United States)

    Dubbert, M.; Piayda, A.; Kübert, A.; Cuntz, M.; Werner, C.

    2016-12-01

    Water is the main driver of ecosystem productivity in most terrestrial ecosystems worldwide. Extreme events are predicted to increase in frequency in many regions and dynamic responses in soil-vegetation-atmosphere feedbacks play a privotal role in understanding the ecosystem water balance and functioning. In this regard, more interdisciplinary approaches, bridging hydrology, ecophysiology and atmospheric sciences are needed and particularly water stable isotopes are a powerful tracer of water transfer in soils and at the soil-plant interface (Werner and Dubbert 2016). Here, we present observations 2 different ecosystems. Water fluxes, atmospheric concentrations and their isotopic compositions were measured using laser spectroscopy. Soil moisture and its isotopic composition in several depths as well as further water sources in the ecosystem were monitored throughout the year. Using these isotopic approaches we disentangled soil-plant-atmosphere feedback processes controlling the ecosystem water cycle including vegetation effects on soil water infiltration and distribution, event water use of vegetation and soil fluxes, vegetational soil water uptake depths plasticity and partitioning of ecosystem water fluxes. In this regard, we review current strategies of ET partitioning and highlight pitfalls in the presented strategies (Dubbert et al. 2013, Dubbert et al.2014a). We demonstrate that vegetation strongly influenced water cycling, altering infiltration and distribution of precipitation. In conclusion, application of stable water isotope tracers delivers a process based understanding of interactions between soil, understorey and trees governing ecosystem water cycling necessary for prediction of climate change impact on ecosystem productivity and vulnerability. ReferencesDubbert, M. et al. (2013): Partitioning evapotranspiration - Testing the Craig and Gordon model with field measurements of oxygen isotope ratios of evaporative fluxes. Journal of Hydrology Dubbert

  14. Preface: GEWEX Atmospheric Boundary-layer Study (GABLS) on Stable Boundary Layers

    NARCIS (Netherlands)

    Holtslag, A.A.M.

    2006-01-01

    The Global Energy and Water Cycle Experiment (GEWEX) is a program initiated by the World Climate Research Programme (WCRP) to observe, understand and model the hydrological cycle and the related energy fluxes in the atmosphere, at the land surface and in the upper oceans. Consequently the

  15. Study of stable atmospheric boundary layer characterization over highveld region of South Africa

    CSIR Research Space (South Africa)

    Luhunga, P

    2011-09-01

    Full Text Available : Earth and Environmental Science 13 (2010) 012012 doi:10.1088/1755-1315/13/1/012012 Businger JA, Wyngaard JC, Uzumi Y and EF Bradley, 1971, Flux-profile relationship in the atmospheric surface layer, J Atm Sci, 28, 181-189. Kolmogorov AN, 1941... ATMOSPHERIC BOUNDARY LAYER CHARACTERIZATION OVER HIGHVELD REGION OF SOUTH AFRICA Philbert Luhunga1, 2, 3, George Djolov1, Venkataraman Sivakumar1,4,5 1 University of Pretoria, Department of Geography Geoinformatics and Meterology, Lynnwood road, 0001...

  16. Stable isotope characterization of pan-derived and directly sampled atmospheric water vapour

    International Nuclear Information System (INIS)

    Maric, R.; St. Amour, N.A.; Gibson, J.J.; Edwards, T.W.D.

    2002-01-01

    Isotopic characterization of atmospheric water vapour, δ A , and its temporal variability are important prerequisites for quantifying water balance of surface reservoirs and partitioning of evaporation and transpiration fluxes using isotope techniques. Here we present results from a detailed comparison of several methods for determining δ A in field situations, (i) by back-calculation from isotopic and micrometeorological monitoring of a steady-state terminal reservoir (standard Class-A evaporation pan) using boundary-layer mass transfer models [1], (ii) through direct (cryogenic) sampling of ambient atmospheric moisture, and (iii) using the precipitation-equilibrium approximation (i.e., δ A =δ P - ε*)

  17. Lidar Observation of Aerosol and Temperature Stratification over Urban Area During the Formation of a Stable Atmospheric PBL

    Science.gov (United States)

    Kolev, I.; Parvanov, O.; Kaprielov, B.; Mitev, V.; Simeonov, V.; Grigorov, I.

    1992-01-01

    In recent years, the processes in the atmospheric planetary boundary layer (PBL) over urban areas were intensely investigated, due to ecological problems related to the air, soil, and water pollution. New pollution sources in new residential districts, when in contradiction to the microclimate and topography requirements of that region, create a number of considerable hazards and problems. The present study is a continuation of our preceding investigations and aims at revealing the aerosol structure and stratification during the transition after sunset as measured by two lidars. Such observation of the nocturnal, stable PBL formation over an urban area in Bulgaria has not been reported before. The lidars' high time and spatial resolutions allow the changes of the internal structure of the PBL's part located above the surface layer to be observed.

  18. Formation of oxygen complexes in controlled atmosphere at surface ...

    Indian Academy of Sciences (India)

    The effects of boron and phosphorus incorporation in phenolic resin precursor to the oxidation resistance of glassy carbon have been studied. In order to reveal the nature and composition of the oxygen complexes formed at the surface of doped glassy carbon, under controlled atmosphere, the surface of the samples was ...

  19. Effect of surface morphology on atmospheric corrosion behaviour of ...

    Indian Academy of Sciences (India)

    Co18Si1B14 ribbon, was evaluated. The wheel side surface of the ribbon was more corroded than the air side surface, due to the higher density of air pockets present. The phases present in atmospheric rust were analysed by X-ray diffraction ...

  20. Observations of the atmospheric surface layer parameters over a ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    1999-08-11

    Aug 11, 1999 ... This paper discusses the observations of the Atmospheric Surface Layer (ASL) parameters dur- ing the solar eclipse of August 11th, 1999. Intensive surface layer experiments were conducted at. Ahmedabad (23◦21 N, 72◦36 E), the western part of India, which was close to the totality path. This rare event ...

  1. Formation of oxygen complexes in controlled atmosphere at surface ...

    Indian Academy of Sciences (India)

    Abstract. The effects of boron and phosphorus incorporation in phenolic resin precursor to the oxidation resistance of glassy carbon have been studied. In order to reveal the nature and composition of the oxygen complexes formed at the surface of doped glassy carbon, under controlled atmosphere, the surface of the ...

  2. Martian thermal tides from the surface to the atmosphere

    Science.gov (United States)

    Holstein-Rathlou, C.; Withers, P.

    2017-12-01

    The presence of observational platforms both in orbit and on the surface of Mars today provides a unique opportunity to simultaneously study the effects of thermal tides at the surface, above that surface location and in the atmosphere. Thermal tides are an important aspect of the atmospheric dynamics on Mars and the unique opportunity to unify landed and orbital measurements can provide a comprehensive understanding of thermal tides. Ideally, pressure measurements from the Curiosity lander and atmospheric temperature profiles from the Mars Climate Sounder (MCS) onboard Mars Reconnaissance Orbiter provide a complimentary pair of surface and atmospheric observations to study. However, the unique landing site of Curiosity, in Gale crater, introduces several complicating factors to the analysis of tidal behavior, two of which are crater circulation and the impact of the dichotomy boundary topography. In order to achieve a baseline understanding of thermal tidal behavior another complimentary pair of observations is necessary. For this purpose, the equatorial and relatively topographically flat landing site of the Viking 1 (VIK1) lander, along with its lengthy record of surface pressures, is the candidate surface dataset. There are no concurrent atmospheric observational data, so atmospheric profiles were obtained from the Mars Climate Database to ensure maximum coverage in space and time. 2-dimensional Fourier analysis in local time and longitude has yielded amplitude and phases for the four major tidal modes on Mars (diurnal and semidiurnal migrating tides, DK1 and DK2). We will present current results regarding amplitude and phase dependence on season and altitude at the VIK1 landing site. These results will (in time) be tied to tidal amplitude and phase behavior from observed MCS atmospheric temperature profiles from "appropriately quiet" Mars years (years without major dust storms). The understanding gathered from this approach will then allow us to return to the

  3. Nanocapillary Atmospheric Pressure Plasma Jet: A Tool for Ultrafine Maskless Surface Modification at Atmospheric Pressure.

    Science.gov (United States)

    Motrescu, Iuliana; Nagatsu, Masaaki

    2016-05-18

    With respect to microsized surface functionalization techniques we proposed the use of a maskless, versatile, simple tool, represented by a nano- or microcapillary atmospheric pressure plasma jet for producing microsized controlled etching, chemical vapor deposition, and chemical modification patterns on polymeric surfaces. In this work we show the possibility of size-controlled surface amination, and we discuss it as a function of different processing parameters. Moreover, we prove the successful connection of labeled sugar chains on the functionalized microscale patterns, indicating the possibility to use ultrafine capillary atmospheric pressure plasma jets as versatile tools for biosensing, tissue engineering, and related biomedical applications.

  4. Observations. Surface and Atmospheric Climate Change. Chapter 3

    Energy Technology Data Exchange (ETDEWEB)

    Trenberth, K.E.; Jones, P.D.; Ambenje, P.; Bojariu, R.; Easterling, D.; Klein Tank, A.; Parker, D.; Rahimzadeh, F.; Renwick, J.A.; Rusticucci, M.; Soden, B.; Zhai, P.

    2007-09-15

    This chapter assesses the observed changes in surface and atmospheric climate, placing new observations and new analyses made during the past six years (since the Third Assessment Report TAR) in the context of the previous instrumental record. In previous IPCC reports, palaeo-observations from proxy data for the pre-instrumental past and observations from the ocean and ice domains were included within the same chapter. This helped the overall assessment of the consistency among the various variables and their synthesis into a coherent picture of change. A short synthesis and scrutiny of the consistency of all the observations is included here (see Section 3.9). In the TAR, surface temperature trends were examined from 1860 to 2000 globally, for 1901 to 2000 as maps and for three sub-periods (1910-1945, 1946-1975 and 1976-2000). The first and third sub-periods had rising temperatures, while the second sub-period had relatively stable global mean temperatures. The 1976 divide is the date of a widely acknowledged 'climate shift' and seems to mark a time when global mean temperatures began a discernible upward trend that has been at least partly attributed to increases in greenhouse gas concentrations in the atmosphere. The picture prior to 1976 has essentially not changed and is therefore not repeated in detail here. However, it is more convenient to document the sub-period after 1979, rather than 1976, owing to the availability of increased and improved satellite data since then (in particular Television InfraRed Observation Satellite (TIROS) Operational Vertical Sounder (TOVS) data) in association with the Global Weather Experiment (GWE) of 1979. The post-1979 period allows, for the first time, a global perspective on many fields of variables, such as precipitation, that was not previously available. The availability of high-quality data has led to a focus on the post-1978 period, although physically this new regime seems to have begun in 1976

  5. Stable Boundary Layer Issues

    NARCIS (Netherlands)

    Steeneveld, G.J.

    2012-01-01

    Understanding and prediction of the stable atmospheric boundary layer is a challenging task. Many physical processes are relevant in the stable boundary layer, i.e. turbulence, radiation, land surface coupling, orographic turbulent and gravity wave drag, and land surface heterogeneity. The

  6. Surface cleaning of metal wire by atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Nakamura, T.; Buttapeng, C.; Furuya, S.; Harada, N.

    2009-01-01

    In this study, the possible application of atmospheric pressure dielectric barrier discharge plasma for the annealing of metallic wire is examined and presented. The main purpose of the current study is to examine the surface cleaning effect for a cylindrical object by atmospheric pressure plasma. The experimental setup consists of a gas tank, plasma reactor, and power supply with control panel. The gas assists in the generation of plasma. Copper wire was used as an experimental cylindrical object. This copper wire was irradiated with the plasma, and the cleaning effect was confirmed. The result showed that it is possible to remove the tarnish which exists on the copper wire surface. The experiment reveals that atmospheric pressure plasma is usable for the surface cleaning of metal wire. However, it is necessary to examine the method for preventing oxidization of the copper wire.

  7. Surface Modification of Nonwoven fabrics by Atmospheric Brush Plasma

    Science.gov (United States)

    Oksuz, Lutfi; Uygun, Emre; Bozduman, Ferhat; Yurdabak Karaca, Gozde; Asan, Orkun Nuri; Uygun Oksuz, Aysegul

    2017-10-01

    Polypropylene nonwoven fabrics (PPNF) are used in disposable absorbent articles, such as diapers, feminine care products, wipes. PPNF need to be wettable by water or aqueous-based liquid. Plasma surface treatment/modification has turned out to be a well-accepted method since it offers superior surface property enhancement than other chemical methods. The cold plasma brush can most efficiently use the discharge power as well as the plasma gas for material and surface treatment. The very low power consumption of such an atmospheric argon plasma brush provides many unique advantages in practical application. The purpose of this study was to reveal the effectiveness of non-thermal atmospheric plasma brush in surface wettability and modification of two different nonwoven surfaces.

  8. Advection of pollutants by internal solitary waves in oceanic and atmospheric stable stratifications

    Directory of Open Access Journals (Sweden)

    G. W. Haarlemmer

    1998-01-01

    Full Text Available When a pollutant is released into the ocean or atmosphere under turbulent conditions, even a steady release is captured by large eddies resulting in localized patches of high concentration of the pollutant. If such a cloud of pollutant subsequently enters a stable stratification-either a pycnocline or thermocline-then internal waves are excited. Since large solitary internal waves have a recirculating core, pollutants may be trapped in the sclitary wave, and advected large distances through the waveguide provided by the stratification. This paper addresses the mechanisms, through computer and physical simulation, by which a localized release of a dense pollutant results in solitary waves that trap the pollutant or disperse the pollutant faster than in the absence of the waves.

  9. Improving Hydrophobicity of Glass Surface Using Dielectric Barrier Discharge Treatment in Atmospheric Air

    International Nuclear Information System (INIS)

    Fang Zhi; Qiu Yuchang; Wang Hui; Kuffel, E

    2007-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in industrial applications, especially in material surface treatment. In this paper, the treatment of a glass surface for improving hydrophobicity using the non-thermal plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure in ambient air is conducted, and the surface properties of the glass before and after the DBD treatment are studied by using contact angle measurement, surface resistance measurement and wet flashover voltage tests. The effects of the applied voltage and time duration of DBD on the surface modification are studied, and the optimal conditions for the treatment are obtained. It is found that a layer of hydrophobic coating is formed on the glass surface after spraying a thin layer of silicone oil and undergoing the DBD treatment, and the improvement of hydrophobicity depends on DBD voltage and treating time. It seems that there exists an optimum treating time for a certain applied voltage of DBD during the surface treatment. The test results of thermal aging and chemical aging show that the hydrophobic layer has quite stable characteristics. The interaction mechanism between the DBD plasma and the glass surface is discussed. It is concluded that CH 3 and large molecule radicals can react with the radicals in the glass surface to replace OH, and the hydrophobicity of the glass surface is improved accordingly

  10. Noble Gas Surface Flux Simulations And Atmospheric Transport

    Energy Technology Data Exchange (ETDEWEB)

    Carrigan, Charles R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Sun, Yunwei [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Simpson, Matthew D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-09-30

    Signatures from underground nuclear explosions or UNEs are strongly influenced by the containment regime surrounding them. The degree of gas leakage from the detonation cavity to the surface obviously affects the magnitude of surface fluxes of radioxenon that might be detected during the course of a Comprehensive Test Ban Treaty On-Site Inspection. In turn, the magnitude of surface fluxes will influence the downwind detectability of the radioxenon atmospheric signature from the event. Less obvious is the influence that leakage rates have on the evolution of radioxenon isotopes in the cavity or the downwind radioisotopic measurements that might be made. The objective of this letter report is to summarize our attempt to better understand how containment conditions affect both the detection and interpretation of radioxenon signatures obtained from sampling at the ground surface near an event as well as at greater distances in the atmosphere. In the discussion that follows, we make no attempt to consider other sources of radioactive noble gases such as natural backgrounds or atmospheric contamination and, for simplicity, only focus on detonation-produced radioxenon gases. Summarizing our simulations, they show that the decay of radioxenon isotopes (e.g., Xe-133, Xe-131m, Xe-133m and Xe-135) and their migration to the surface following a UNE means that the possibility of detecting these gases exists within a window of opportunity. In some cases, seeps or venting of detonation gases may allow significant quantities to reach the surface and be released into the atmosphere immediately following a UNE. In other release scenarios – the ones we consider here – hours to days may be required for gases to reach the surface at detectable levels. These release models are most likely more characteristic of “fully contained” events that lack prompt venting, but which still leak gas slowly across the surface for periods of months.

  11. Microwave Investigation of the Mars Atmosphere and Surface

    Science.gov (United States)

    Gulkis, S.; Forget, F.; Janssen, M.; Riley, A. L.; Hartogh, P.; Clancy, T.; Allen, M.; Frerking, M.

    2000-01-01

    The Microwave Investigation of the Mars Atmosphere and Surface Experiment (MIMAS) is designed to address two major scientific goals: 1) To understand the three dimensional general circulation of the Martian atmosphere, and 2) To understand the hydrologic cycle of water on Mars, including the time-variable sources, sinks, and atmospheric transport of water vapor. The proposed instrument is a submillimeter wave, heterodyne receiver, with both continuum and very high spectral resolution capability. A small reflector antenna will be used to feed the receiver. Instrument heritage comes from the MIRO receiver, currently under design for the ESA Rosetta Mission, and from SWAS, a NASA astrophysics mission. The instrument will be able to measure atmospheric spectral lines from both water and carbon monoxide and use these lines as tracers of atmospheric winds. Measurement objectives of MIMAS are to measure surface temperature, atmospheric temperature from the surface up to an altitude of 60 km or more, the distribution of CO and H2O in the atmosphere, and certain wind fields (zonal and meridional). The global distribution of CO, as well as temperature distributions, will be used as input data for GCMs (general circulation models). Water vapor profiles will be used to understand the sources and sinks of water on Mars and to understand how it is transported globally by the general circulation. Zonal and meridional wind fields will provide further tests of the GCMs. An important aspect of this experiment is that the temperature and humidity measurements are insensitive to dust and ice condensates thereby making the measurement capability independent of the presence of dust clouds and ice particles. Temperature measurements derived from the data can be used in conjunction with infrared measurements to determine dust profiles.

  12. Whirlwinds and hairpins in the atmospheric surface layer

    NARCIS (Netherlands)

    Oncley, Steven P.; Hartogensis, O.K.; Tong, Chenning

    2016-01-01

    Vortices in the atmospheric surface layer are characterized using observations at unprecedented resolution from a fixed array of 31 turbulence sensors. During the day, these vortices likely are dust devils, though no visual observations are available for confirmation. At night, hairpin vortices

  13. The determination of turbulent structures in the atmospheric surface layer

    NARCIS (Netherlands)

    Schols, J.L.J.

    1984-01-01

    The turbulent flow in the atmospheric surface layer (ASL) contains turbulent structures, which are defined as spatially coherent, organized flow motions. 'Organized' means that characteristic patterns, observed at a point in space, occur almost simultaneously in more than one turbulence signal and

  14. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    Energy Technology Data Exchange (ETDEWEB)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  15. Handel's Maser-Soliton Theory of ball lightning: The creation of stable three-dimensional cavitons by an atmospheric maser within an open resonator

    Science.gov (United States)

    Carlson, Glenn Andrew

    This dissertation develops details of Handel's Maser-Soliton Theory of ball lightning. The atmosphere between a thundercloud and the Earth's surface is modeled as an idealized stable open resonator with water vapor as the active medium and the thundercloud and Earth's surface as reflecting surfaces. The stable resonator generates a maser beam that narrows to the beam waist at the Earth's surface, which is assumed to be planar. Two candidate rotational transitions are identified within the ν1ν 2ν3 = 010 vibrational band of water having wavelengths of 13.9 cm and 1.12 cm, and relevant spectroscopic parameters are retrieved from the HITRAN 2008 molecular spectroscopic database. The maser is modeled as a continuously pumped four-level maser that includes the effects of nonradiative relaxation due to molecular collisions and of microwave absorption in atmospheric oxygen. Since maser spiking is highly unlikely to occur due to the high rate of collisional relaxation at normal atmospheric pressure, the electrical breakdown of air must be achieved by the steady state output of the atmospheric maser. A parametric analysis is performed to relate the size of the atmospheric maser to the pumping rate needed to create a steady state population inversion sufficient to generate maser radiation intense enough at the beam waist to result in the electrical breakdown of air. The analysis suggests that electric field intensities at the beam waist sufficient to cause electrical breakdown of air could only be created through huge pumping rates (˜105 to 107 times the critical pumping rate) and only for the most highly curved clouds (g ≈ 0) that give the narrowest beam waists.

  16. Atmospheric moisture supersaturatons in the near-surface atmosphere of Dome C, Antarctic Plateau

    Science.gov (United States)

    Genthon, Christophe; Piard, Luc; Vignon, Etienne; Madeleine, Jean-Baptiste; Casado, Mathieu; Gallée, Hubert

    2017-04-01

    Moisture supersaturations occur at the top of the troposphere where cirrus clouds form, but is comparatively unusual near the surface where the air is generally warmer and laden with liquid and/or ice condensation nuclei. One exception is the surface of the high antarctic plateau. This study presents one year of atmospheric moisture measurement at the surface of Dome C on the East Antarctic plateau. The measurements are obtained using commercial hygrometry sensors adapted to allow air sampling without affecting the moisture content even in case of supersaturation. Supersaturation is found to be very frequent. Common unadapted hygrometry sensors generally fail to report supersaturation, and most reports of atmospheric moisture on the antarctic plateau are thus likely biased low. The measurements are compared with results from 2 models with cold microphysics parametrizations: the European Center for Medium-range Weather Forecasts through its operational analyses, and the Model Atmosphérique Régional. As in the observations, supersaturation is frequent in the models but the statistical distribution differs both between models and observations and between the 2 models, leaving much room for model improvement. The representation of supersaturations is not critical for the estimations of surface sublimation since they are more frequent as temperature is lower i.e. as moisture quantities and water fluxes are small. However, ignoring near-surface supersaturation may be a more serious issue for the modeling of fog and when considering water isotopes, a tracer of phase change and temperature, largely used to reconstruct past climates and environments from ice cores. Because observations are easier in the surface atmosphere, longer and more continuous in situ observation series of atmospheric supersaturation can be obtained than higher in the atmosphere to test parameterizations of cold microphysics, such as those used in the formation of high altitude cirrus clouds in

  17. The role of snow-surface coupling, radiation, and turbulent mixing in modeling a stable boundary layer over Arctic sea ice

    NARCIS (Netherlands)

    Sterk, H.A.M.; Steeneveld, G.J.; Holtslag, A.A.M.

    2013-01-01

    To enhance the understanding of the impact of small-scale processes in the polar climate, this study focuses on the relative role of snow-surface coupling, radiation and turbulent mixing in an Arctic stable boundary layer. We extend the GABLS1 (GEWEX Atmospheric Boundary-Layer Study 1) model

  18. Atmospheric moisture supersaturation in the near-surface atmosphere at Dome C, Antarctic Plateau

    Science.gov (United States)

    Genthon, Christophe; Piard, Luc; Vignon, Etienne; Madeleine, Jean-Baptiste; Casado, Mathieu; Gallée, Hubert

    2017-01-01

    Supersaturation often occurs at the top of the troposphere where cirrus clouds form, but is comparatively unusual near the surface where the air is generally warmer and laden with liquid and/or ice condensation nuclei. One exception is the surface of the high Antarctic Plateau. One year of atmospheric moisture measurement at the surface of Dome C on the East Antarctic Plateau is presented. The measurements are obtained using commercial hygrometry sensors modified to allow air sampling without affecting the moisture content, even in the case of supersaturation. Supersaturation is found to be very frequent. Common unadapted hygrometry sensors generally fail to report supersaturation, and most reports of atmospheric moisture on the Antarctic Plateau are thus likely biased low. The measurements are compared with results from two models implementing cold microphysics parameterizations: the European Center for Medium-range Weather Forecasts through its operational analyses, and the Model Atmosphérique Régional. As in the observations, supersaturation is frequent in the models but the statistical distribution differs both between models and observations and between the two models, leaving much room for model improvement. This is unlikely to strongly affect estimations of surface sublimation because supersaturation is more frequent as temperature is lower, and moisture quantities and thus water fluxes are small anyway. Ignoring supersaturation may be a more serious issue when considering water isotopes, a tracer of phase change and temperature, largely used to reconstruct past climates and environments from ice cores. Because observations are easier in the surface atmosphere, longer and more continuous in situ observation series of atmospheric supersaturation can be obtained than higher in the atmosphere to test parameterizations of cold microphysics, such as those used in the formation of high-altitude cirrus clouds in meteorological and climate models.

  19. Hydrophilic Surface Modification of PDMS Using Atmospheric RF Plasma

    International Nuclear Information System (INIS)

    Hong, Sung M; Kim, Seong H; Kim, Jeong H; Hwang, Hak I

    2006-01-01

    Control of surface properties in microfluidics systems is an indispensable prerequisite for the success of bioanalytical applications. Poly(dimethylsiloxane) (PDMS) microfluidic devices are hampered from unwanted adsorption of biomolecules and the lack of methods to control electroosmotic flow(EOF). Among the various methods of hydrophilic treatment, a new cleaner technology was chosen to treat PDMS. By using atmospheric RF plasma, hydrophilic surfaces can be created. Thus, analysis was conducted with AFM, XPS, and contact angle before and after plasma treatment. Constructing hydrophilic surfaces without changing the true character of that surface has previously been costly and time consuming. But by using atmospheric plasma cost and time are both greatly reduced. There are many other benefits of hydrophilic surface treatment, including the capability to increase adhesion and capillary effects, etc. Also, with hydrophilic treatment of the micro channels on the PDMS surface, surface tension is reduced thus allowing fluids to move easily along those channels. However, the most important aim is to increase the capillary effects without any deposition or chemical treatment

  20. Is bicarbonate stable in and on the calcite surface?

    DEFF Research Database (Denmark)

    Andersson, Martin Peter; Rodriguez Blanco, Juan Diego; Stipp, Susan Louise Svane

    2016-01-01

    We have used density functional theory with the COSMO-RS implicit solvent model to predict the pKa for the deprotonation of bicarbonate to carbonate, i.e. HCO3− CO32− + H+, when HCO3− is included in, and adsorbed on, a calcite surface. We have used cluster models (80–100 atoms) to represent...... the flat {10.4} surface, acute steps, obtuse steps, two types of kinks on the acute step and two types of kinks on the obtuse steps. Based on the predicted pKa values, which range from −6.0 to 2.4 depending on the surface site, we conclude that bicarbonate deprotonates to carbonate when it is in calcite...... even when pH in solution is very low. This is true for all surface sites, even for solutions where 2.4 bicarbonate is adsorbed on calcite, the predicted pKa for deprotonation is 7.5, which is ∼3 pH units lower than in aqueous solution...

  1. Contamination of Teflon surfaces by PCBs in the atmosphere

    Science.gov (United States)

    Murphy, Thomas J.; Sweet, Clyde W.

    Collection of a valid precipitation sample involves careful attention to all aspects of the sampling and analysis process. Difficulties in obtaining low field blanks were experienced for a collector used in a project to determine precipitation inputs to Green Bay of Lake Michigan. The cause of high field blanks was found to be PCBs scavenged from the atmosphere and adsorbed on the Teflon™ surface of the sampler. These PCBs were extracted from the collector surface by the methanol used as a rinse solvent. The amounts of PCBs on the surface were found to be a factor of 20-50 higher than the amounts in a typical precipitation sample. After rinsing the Teflon surface several times with methanol, additional PCBs could be obtained by rinsing the surface with hexane or dichloromethane.

  2. Thermodynamics of Minerals Stable Near the Earth's Surface

    International Nuclear Information System (INIS)

    Navrotsky, Alexandra

    2003-01-01

    OAK B262 Research and Education Activities We are working on developing calorimetric techniques for sulfide minerals. We have completed calorimetric studies of (Na, K, H3O) jarosites, of Na and K jarosite -alunite solid solutions, and of Cr6+ - containing jarosites. We are now working on phases containing As and Pb. These studies are important to issues of heavy metal pollution in the environment. A number of postdocs, graduate students, and undergrads have participated in the research. We have active collaboration with Dirk Baron, faculty at California State University, Bakersfield. In a collaboration with Peter Burns, Notre Dame University, we are working on thermochemistry of U6+ minerals. Navrotsky has participated in a number of national workshops that are helping to define the interfaces between nanotechnology and earth/environmental science. Major Findings Our first finding on uranyl minerals shows that studtite, a phase containing structural peroxide ion, is thermodynamically unstable in the absence of a source of aqueous peroxide ion but is thermodynamically stable in contact with a solution containing peroxide concentrations expected for the radiolysis of water in contact with spent nuclear fuel. This work is in press in Science. We have a consistent thermodynamic data set for the (Na, K, H3O) (Al, Fe) jarosite, alunite minerals and for Cr6+ substituting for S6+ in jarosite. The latter phases represent one of the few solid sinks for trapping toxic Cr6+ in groundwater. Contributions within Discipline Better understanding of thermodynamic driving for and constraints on geochemical and environmental processes

  3. Thermochemistry of minerals stable near the earth's surface

    International Nuclear Information System (INIS)

    1990-01-01

    The present proposal continues the evolution, of changing emphasis from silicate melts to glass and toward crystalline minerals stable in the shallow crustal environment, particularly amphiholes, micas, and related hydrous phases adding zeolites and carbonates to our areas of interest. This is made possible both by recent advances in our high-temperature calorimetric techniques and by an interest in extending our ideas about the systematics of ionic substitutions to more complex structures. The proposal presents the following: (a) a listing of papers, theses, and abstracts in the past 3 years supported by the present grant, (b) a summary of work on glasses containing highly charged cations and on some related crystalline phases, with proposed new directions, (c) a discussion of advances in calorimetric methods and what new possibilities they open, (d) completed and planned work on amphiboles, micas, and clays, (e) completed and proposed work on amorpous low temperature materials, (f) proposed work on zeolites, and (g) proposed work on carbonates and (h) a discussion of the energy relevance of the above projects. This is followed by the required forms, budget pages, and CV. 34 refs., 5 figs., 1 tab

  4. Atmospherically stable nanoscale zero-valent iron particles formed under controlled air contact: characteristics and reactivity.

    Science.gov (United States)

    Kim, Hong-Seok; Ahn, Jun-Young; Hwang, Kyung-Yup; Kim, Il-Kyu; Hwang, Inseong

    2010-03-01

    Atmospherically stable NZVI (nanoscale zero-valent iron) particles were produced by modifying shell layers of Fe(H2) NZVI particles (RNIP-10DS) by using a controlled air contact method. Shell-modified NZVI particles were resistant to rapid aerial oxidation and were shown to have TCE degradation rate constants that were equivalent to 78% of those of pristine NZVI particles. Fe(H2) NZVI particles that were vigorously contacted with air (rapidly oxidized) showed a substantially compromised reactivity. Aging of shell-modified particles in water for one day resulted in a rate increase of 54%, implying that depassivation of the shell would play an important role in enhancing reactivity. Aging of shell-modified particles in air led to rate decreases by 14% and 46% in cases of one week and two months of aging, respectively. A series of instrumental analyses using transmission electron microscopy, X-ray diffractography, X-ray photoelectron spectroscopy, and X-ray absorption near-edge structure showed that the shells of modified NZVI particles primarily consisted of magnetite (Fe(3)O(4)). Analyses also implied that the new magnetite layer produced during shell modification was protective against shell passivation. Aging of shell-modified particles in water yielded another major mineral phase, goethite (alpha-FeOOH), whereas aging in air produced additional shell phases such as wustite (FeO), hematite (alpha-Fe(2)O(3)), and maghemite (gamma-Fe(2)O(3)).

  5. Impacts of Cosmic Dust on Planetary Atmospheres and Surfaces

    Science.gov (United States)

    Plane, John M. C.; Flynn, George J.; Määttänen, Anni; Moores, John E.; Poppe, Andrew R.; Carrillo-Sanchez, Juan Diego; Listowski, Constantino

    2018-02-01

    Recent advances in interplanetary dust modelling provide much improved estimates of the fluxes of cosmic dust particles into planetary (and lunar) atmospheres throughout the solar system. Combining the dust particle size and velocity distributions with new chemical ablation models enables the injection rates of individual elements to be predicted as a function of location and time. This information is essential for understanding a variety of atmospheric impacts, including: the formation of layers of metal atoms and ions; meteoric smoke particles and ice cloud nucleation; perturbations to atmospheric gas-phase chemistry; and the effects of the surface deposition of micrometeorites and cosmic spherules. There is discussion of impacts on all the planets, as well as on Pluto, Triton and Titan.

  6. Surface modification of polyester synthetic leather with tetramethylsilane by atmospheric pressure plasma

    International Nuclear Information System (INIS)

    Kan, C.W.; Kwong, C.H.; Ng, S.P.

    2015-01-01

    Highlights: • Atmospheric pressure plasma treatment improved surface performance of polyester synthetic leather with tetramethylsilane. • XPS and FTIR confirmed the deposition of organosilanes on the sample's surface. • Contact angle increases to 138° after plasma treatment. - Abstract: Much works have been done on synthetic materials but scarcely on synthetic leather owing to its surface structures in terms of porosity and roughness. This paper examines the use of atmospheric pressure plasma (APP) treatment for improving the surface performance of polyester synthetic leather by use of a precursor, tetramethylsilane (TMS). Plasma deposition is regarded as an effective, simple and single-step method with low pollution. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) confirm the deposition of organosilanes on the sample's surface. The results showed that under a particular combination of treatment parameters, a hydrophobic surface was achieved on the APP treated sample with sessile drop static contact angle of 138°. The hydrophobic surface is stable without hydrophilic recovery 30 days after plasma treatment

  7. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    2012-01-01

    Efficiency of atmospheric pressure plasma treatment can be highly enhanced by simultaneous high power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above ∼140 dB can reduce the thickness of a boundary gas layer between the plasma...... arc at atmospheric pressure to study adhesion improvement. The effect of ultrasonic irradiation with the frequency diapason between 20 and 40 kHz at the SPL of ∼150 dB was investigated. After the plasma treatment without ultrasonic irradiation, the wettability was significantly improved....... The ultrasonic irradiation during the plasma treatment consistently enhanced the treatment efficiency. The principal effect of ultrasonic irradiation can be attributed to enhancing surface oxidation during plasma treatment. In addition, ultrasonic irradiation can suppress arcing, and the uniformity...

  8. Atmospheric Water Harvesting: Role of Surface Wettability and Edge Effect

    KAUST Repository

    Jin, Yong

    2017-06-23

    Atmospheric water is emerging as an important potable water source. The present work experimentally and theoretically investigates water condensation and collection on flat surfaces with contrasting contact angles and contact angle hysteresis (CAH) to elucidate their roles on water mass collection efficiency. The experimental results indicate that a hydrophilic surface promotes nucleation and individual droplets growth, and a surface with a low CAH tends to let a smaller droplet to slide down, but the overall water mass collection efficiency is independent of both surface contact angle and CAH. The experimental results agree well with our theoretical calculations. During water condensation, a balance has to be struck between single droplet growth and droplet density on a surface so as to maintain a constant water droplet surface coverage ratio, which renders the role of both surface wettability and hysteresis insignificant to the ultimate water mass collection. Moreover, water droplets on the edges of a surface grow much faster than those on the non-edge areas and thus dominate the contribution to the water mass collection by the entire surface, directly pointing out the very important role of edge effect on water condensation and collection.

  9. Atmospheric pressure plasma surface modification of carbon fibres

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Løgstrup Andersen, Tom; Michelsen, Poul

    2008-01-01

    Carbon fibres are continuously treated with dielectric barrier discharge plasma at atmospheric pressure in various gas conditions for adhesion improvement in mind. An x-ray photoelectron spectroscopic analysis indicated that oxygen is effectively introduced onto the carbon fibre surfaces by He, He....../O2 and Ar plasma treatments, mainly attributed to an increase in the density of the C-O single bond at the carbon fibre surfaces. The O/C ratio increased to 0.182 after 1-s He plasma treatment, and remained approximately constant after longer treatment. After exposure in an ambient air at room...

  10. Stable isotope labeling of oligosaccharide cell surface antigens

    Energy Technology Data Exchange (ETDEWEB)

    Unkefer, C.J.; Silks, L.A. III; Martinez, R.A. [and others

    1998-12-31

    The overall goal of this Laboratory Directed Research and Development (LDRD) project was to develop new methods for synthesis of {sup 13}C-labeled oligosaccharides that are required for nuclear magnetic resonance (NMR) studies of their solution conformation. Oligosaccharides are components of the cell`s outer surface and are involved in important processes such as cell-cell recognition and adhesion. Recently, Danishefsky and coworkers at Slone-Kettering Cancer Center developed a method for the solid-phase chemical synthesis of oligosaccharides. The specific goal of this LDRD project was to prepare uniform {sup 13}C-labeled aldohexose precursors required for the solid-phase synthesis of the Lewis blood-group antigenic determinants. We report the synthesis of {sup 13}C-labeled D-glucal, D-galactal and Fucosyl precursors. We have been collaborating with the Danishefsky group on the synthesis of the Lewis oligosaccharides and the NMR analysis of their solution conformation.

  11. Ultrasound enhanced plasma surface modification at atmospheric pressure

    DEFF Research Database (Denmark)

    Kusano, Yukihiro; Singh, Shailendra Vikram; Norrman, Kion

    irradiation, the water contact angle dropped markedly, and tended to decrease furthermore at higher power. The ultrasonic irradiation during the plasma treatment consistently improved the wettability. Oxygen containing polar functional groups were introduced at the surface by the plasma treatment......Atmospheric pressure plasma treatment can be highly enhanced by simultaneous high-power ultrasonic irradiation onto the treating surface. It is because ultrasonic waves with a sound pressure level (SPL) above approximately 140 dB can reduce the thickness of a boundary gas layer between the plasma...... are separated using a polyethylene film. The gliding arc was extended by a high speed air flow into ambient air, directed the polyester surface at an angle of approximately 30o. The ultrasonic waves were introduced vertically to the surface. After the plasma treatment using each plasma source without ultrasonic...

  12. Historical (1850–2010 mercury stable isotope inventory from anthropogenic sources to the atmosphere

    Directory of Open Access Journals (Sweden)

    Ruoyu Sun

    2016-02-01

    Full Text Available Abstract Mercury (Hg stable isotopes provide a new tool to trace the biogeochemical cycle of Hg. An inventory of the isotopic composition of historical anthropogenic Hg emissions is important to understand sources and post-emission transformations of Hg. We build on existing global inventories of anthropogenic Hg emissions to the atmosphere to develop the first corresponding historical Hg isotope inventories for total Hg (THg and three Hg species: gaseous elemental Hg (GEM, gaseous oxidized Hg (GOM and particulate-bound Hg (PBM. We compile δ202Hg and Δ199Hg of major Hg emissions source materials. Where possible, δ202Hg and Δ199Hg values in emissions are corrected for the mass dependent Hg isotope fractionation during industrial processing. The framework and Hg isotope inventories can be updated and improved as new data become available. Simulated THg emissions from all sectors between 1850s and 2010s generally show an increasing trend (−1.1‰ to −0.7‰ for δ202Hg, and a stable trend (−0.02‰ to −0.04‰ for Δ199Hg. Δ200Hg are near-zero in source materials and therefore emissions. The δ202Hg trend generally reflects a shift of historically dominant Hg emissions from 19th century Hg mining and liquid Hg0 uses in Au/Ag refining to 20th century coal combustion and non-ferrous metal production. The historical δ202Hg and Δ199Hg curves of GEM closely follow those of THg. The δ202Hg curves of GOM and PBM show no trends. Δ199Hg values for both GOM and PBM decrease from the 1850s to 1950s by ∼0.1‰, and then gradually rebound towards the 2010s. Our updated δ202Hg values (−0.76 ± 0.11 ‰, 1SD, n=9 of bulk emissions from passively degassing volcanoes overlap with δ202Hg of present-day anthropogenic THg emissions.

  13. Surface treatment of polyethylene terephthalate film using atmospheric pressure glow discharge in air

    International Nuclear Information System (INIS)

    Fang Zhi; Qiu Yuchang; Wang Hui

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted. The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the surface oxygen content of PET surface increases to 39%, and the water contact angle decreases to 19 degree, respectively. (authors)

  14. Apparatus and method for atmospheric pressure reactive atom plasma processing for shaping of damage free surfaces

    Science.gov (United States)

    Carr,; Jeffrey, W [Livermore, CA

    2009-03-31

    Fabrication apparatus and methods are disclosed for shaping and finishing difficult materials with no subsurface damage. The apparatus and methods use an atmospheric pressure mixed gas plasma discharge as a sub-aperture polisher of, for example, fused silica and single crystal silicon, silicon carbide and other materials. In one example, workpiece material is removed at the atomic level through reaction with fluorine atoms. In this example, these reactive species are produced by a noble gas plasma from trace constituent fluorocarbons or other fluorine containing gases added to the host argon matrix. The products of the reaction are gas phase compounds that flow from the surface of the workpiece, exposing fresh material to the etchant without condensation and redeposition on the newly created surface. The discharge provides a stable and predictable distribution of reactive species permitting the generation of a predetermined surface by translating the plasma across the workpiece along a calculated path.

  15. The Analyses of Turbulence Characteristics in the Atmospheric Surface Layer Using Arbitrary-Order Hilbert Spectra

    Science.gov (United States)

    Wei, W.; Schmitt, F. G.; Huang, Y. X.; Zhang, H. S.

    2016-05-01

    Turbulent characteristics in the atmospheric surface layer are investigated using a data-driven method, Hilbert spectral analysis. The results from empirical mode decomposition display a set of intrinsic mode functions whose characteristic scales suggest a dyadic filter-bank property. It can be concluded from the joint probability density function of the intrinsic mode functions that the turbulent properties are totally different under different stratifications: the amplitudes (or energies) are arranged according to the stability parameter [InlineEquation not available: see fulltext.] for stable conditions, but tend to cluster randomly for unstable cases. The intermittency analyses reveal that second-order Hilbert marginal spectra display a power-law behaviour in the inertial subrange, and that the scaling exponent functions deviate from the theoretical values due to the strong intermittency in the stable boundary layer.

  16. Helium atmospheric pressure plasma jets touching dielectric and metal surfaces

    Science.gov (United States)

    Norberg, Seth A.; Johnsen, Eric; Kushner, Mark J.

    2015-07-01

    Atmospheric pressure plasma jets (APPJs) are being investigated in the context plasma medicine and biotechnology applications, and surface functionalization. The composition of the surface being treated ranges from plastics, liquids, and biological tissue, to metals. The dielectric constant of these materials ranges from as low as 1.5 for plastics to near 80 for liquids, and essentially infinite for metals. The electrical properties of the surface are not independent variables as the permittivity of the material being treated has an effect on the dynamics of the incident APPJ. In this paper, results are discussed from a computational investigation of the interaction of an APPJ incident onto materials of varying permittivity, and their impact on the discharge dynamics of the plasma jet. The computer model used in this investigation solves Poisson's equation, transport equations for charged and neutral species, the electron energy equation, and the Navier-Stokes equations for the neutral gas flow. The APPJ is sustained in He/O2 = 99.8/0.2 flowing into humid air, and is directed onto dielectric surfaces in contact with ground with dielectric constants ranging from 2 to 80, and a grounded metal surface. Low values of relative permittivity encourage propagation of the electric field into the treated material and formation and propagation of a surface ionization wave. High values of relative permittivity promote the restrike of the ionization wave and the formation of a conduction channel between the plasma discharge and the treated surface. The distribution of space charge surrounding the APPJ is discussed.

  17. Influences of the cold atmospheric plasma jet treatment on the properties of the demineralized dentin surfaces

    Science.gov (United States)

    Xiaoming, ZHU; Heng, GUO; Jianfeng, ZHOU; Xiaofei, ZHANG; Jian, CHEN; Jing, LI; Heping, LI; Jianguo, TAN

    2018-04-01

    Improvement of the bonding strength and durability between the dentin surface and the composite resin is a challenging job in dentistry. In this paper, a radio-frequency atmospheric-pressure glow discharge (RF-APGD) plasma jet is employed for the treatment of the acid-etched dentin surfaces used for the composite restoration. The properties of the plasma treated dentin surfaces and the resin-dentin interfaces are analyzed using the x-ray photoemission spectroscopy, contact angle goniometer, scanning electron microscope and microtensile tester. The experimental results show that, due to the abundant chemically reactive species existing in the RF-APGD plasma jet under a stable and low energy input operating mode, the contact angle of the plasma-treated dentin surfaces decreases to a stable level with the increase of the atomic percentage of oxygen in the specimens; the formation of the long resin tags in the scattered clusters and the hybrid layers at the resin-dentin interfaces significantly improve the bonding strength and durability. These results indicate that the RF-APGD plasma jet is an effective tool for modifying the chemical properties of the dentin surfaces, and for improving the immediate bonding strength and the durability of the resin-dentin bonding in dentistry.

  18. Atmospheres – Through Projections on a Living Surface

    DEFF Research Database (Denmark)

    Steijn, Arthur

    2013-01-01

    of space, liveness and atmosphere. With the development of this model I wish to contribute to the on-going development of the use of video projections and motion graphics as important visual, spatial and narrative elements within the field of spatial experience design, e.g. in performance, exhibition...... design and events. The model is being designed with two purposes in mind. One is a tool for analyzing empirical examples or cases where video projections are used in spatial experience design. The second is to create a tool that can be useful in actual design processes. In this paper I describe a case...... where video projection on a living surface was part of an experimental dance performance. Based on this case I incorporate descriptions derived from the field of aesthetics, specifically atmospheres understood as a concept of new aesthetics as described by philosopher Gernot Böhme.2 Finally I look...

  19. Averaging of diffusing contaminant concentrations in atmosphere surface layer

    International Nuclear Information System (INIS)

    Ivanov, E.A.; Ramzina, T.V.

    1985-01-01

    Calculations permitting to average concentration fields of diffusing radioactive contaminant coming from the NPP exhaust stack in the atmospheric surface layer are given. Formulae of contaminant concentration field calculation are presented; it depends on the average wind direction value (THETA) for time(T) and stability of this direction (σsub(tgTHETA) or σsub(THETA)). Probability of wind direction deviation from the average value for time T is satisfactory described by the Gauss law. With instability increase in the atmosphere σ increases, when wind velocity increasing the values of σ decreases for all types of temperature gradients. Nonuniformity of σ value dependence on averaging time T is underlined, that requires accurate choice of σsub(tgTHETA) and σsub(THETA) parameters in calculations

  20. Atmospheric teleconnection influence on North American land surface phenology

    Science.gov (United States)

    Dannenberg, Matthew P.; Wise, Erika K.; Janko, Mark; Hwang, Taehee; Kolby Smith, W.

    2018-03-01

    Short-term forecasts of vegetation activity are currently not well constrained due largely to our lack of understanding of coupled climate-vegetation dynamics mediated by complex interactions between atmospheric teleconnection patterns. Using ecoregion-scale estimates of North American vegetation activity inferred from remote sensing (1982-2015), we examined seasonal and spatial relationships between land surface phenology and the atmospheric components of five teleconnection patterns over the tropical Pacific, north Pacific, and north Atlantic. Using a set of regression experiments, we also tested for interactions among these teleconnection patterns and assessed predictability of vegetation activity solely based on knowledge of atmospheric teleconnection indices. Autumn-to-winter composites of the Southern Oscillation Index (SOI) were strongly correlated with start of growing season timing, especially in the Pacific Northwest. The two leading modes of north Pacific variability (the Pacific-North American, PNA, and West Pacific patterns) were significantly correlated with start of growing season timing across much of southern Canada and the upper Great Lakes. Regression models based on these Pacific teleconnections were skillful predictors of spring phenology across an east-west swath of temperate and boreal North America, between 40°N-60°N. While the North Atlantic Oscillation (NAO) was not strongly correlated with start of growing season timing on its own, we found compelling evidence of widespread NAO-SOI and NAO-PNA interaction effects. These results suggest that knowledge of atmospheric conditions over the Pacific and Atlantic Oceans increases the predictability of North American spring phenology. A more robust consideration of the complexity of the atmospheric circulation system, including interactions across multiple ocean basins, is an important step towards accurate forecasts of vegetation activity.

  1. Land-Surface-Atmosphere Coupling in Observations and Models

    Directory of Open Access Journals (Sweden)

    Alan K Betts

    2009-07-01

    Full Text Available The diurnal cycle and the daily mean at the land-surface result from the coupling of many physical processes. The framework of this review is largely conceptual; looking for relationships and information in the coupling of processes in models and observations. Starting from the surface energy balance, the role of the surface and cloud albedos in the shortwave and longwave fluxes is discussed. A long-wave radiative scaling of the diurnal temperature range and the night-time boundary layer is summarized. Several aspects of the local surface energy partition are presented: the role of soilwater availability and clouds; vector methods for understanding mixed layer evolution, and the coupling between surface and boundary layer that determines the lifting condensation level. Moving to larger scales, evaporation-precipitation feedback in models is discussed; and the coupling of column water vapor, clouds and precipitation to vertical motion and moisture convergence over the Amazon. The final topic is a comparison of the ratio of surface shortwave cloud forcing to the diabatic precipitation forcing of the atmosphere in ERA-40 with observations.

  2. A new first-order turbulence mixing model for the stable atmospheric boundary-layer: development and testing in large-eddy and single column models

    Science.gov (United States)

    Huang, J.; Bou-Zeid, E.; Golaz, J.

    2011-12-01

    Parameterization of the stably-stratified atmospheric boundary-layer is of crucial importance to different aspects of numerical weather prediction at regional scales and climate modeling at global scales, such as land-surface temperature forecasts, fog and frost prediction, and polar climate. It is well-known that most operational climate models require excessive turbulence mixing of the stable boundary-layer to prevent decoupling of the atmospheric component from the land component under strong stability, but the performance of such a model is unlikely to be satisfactory under weakly and moderately stable conditions. In this study we develop and test a general turbulence mixing model of the stable boundary-layer which works under different stabilities and for steady as well as unsteady conditions. A-priori large-eddy simulation (LES) tests are presented to motivate and verify the new parameterization. Subsequently, an assessment of this model using the GFDL single-column model (SCM) is performed. Idealized test cases including continuously varying stability, as well as stability discontinuity, are used to test the new SCM against LES results. A good match of mean and flux profiles is found when the new parameterization is used, while other traditional first-order turbulence models using the concept of stability function perform poorly. SCM spatial resolution is also found to have little impact on the performance of the new turbulence closure, but temporal resolution is important and a numerical stability criterion based on the model time step is presented.

  3. Modeling land-surface/atmosphere dynamics for CHAMMP

    International Nuclear Information System (INIS)

    Gutowski, W.J. Jr.

    1993-01-01

    Project progress is described on a DOE CHAMP project to model the land-surface/atmosphere coupling in a heterogeneous environment. This work is a collaboration between scientists at Iowa State University and the University of New Hampshire. Work has proceeded in two areas: baseline model coupling and data base development for model validation. The core model elements (land model, atmosphere model) have been ported to the Principal Investigator's computing system and baseline coupling has commenced. The initial target data base is the set of observations from the FIFE field campaign, which is in the process of being acquired. For the remainder of the project period, additional data from the region surrounding the FIFE site and from other field campaigns will be acquired to determine how to best extrapolate results from the initial target region to the rest of the globe. In addition, variants of the coupled model will be used to perform experiments examining resolution requirements and coupling strategies for land-atmosphere coupling in a heterogeneous environment

  4. Large-eddy simulation of stable atmospheric boundary layers to develop better turbulence closures for climate and weather models

    Science.gov (United States)

    Bou-Zeid, Elie; Huang, Jing; Golaz, Jean-Christophe

    2011-11-01

    A disconnect remains between our improved physical understanding of boundary layers stabilized by buoyancy and how we parameterize them in coarse atmospheric models. Most operational climate models require excessive turbulence mixing in such conditions to prevent decoupling of the atmospheric component from the land component, but the performance of such a model is unlikely to be satisfactory under weakly and moderately stable conditions. Using Large-eddy simulation, we revisit some of the basic challenges in parameterizing stable atmospheric boundary layers: eddy-viscosity closure is found to be more reliable due to an improved alignment of vertical Reynolds stresses and mean strains under stable conditions, but the dependence of the magnitude of the eddy viscosity on stability is not well represented by several models tested here. Thus, we propose a new closure that reproduces the different stability regimes better. Subsequently, tests of this model in the GFDL's single-column model (SCM) are found to yield good agreement with LES results in idealized steady-stability cases, as well as in cases with gradual and sharp changes of stability with time.

  5. Surface layer conditions of the atmosphere over western Bay of Bengal during Monex

    Digital Repository Service at National Institute of Oceanography (India)

    Anto, A.F.; Rao, L.V.G.; Somayajulu, Y.K.

    Based on surface meteorological data and wave data collected from 2 stations in the western Bay of Bengal in July 1979, surface layer (SL) conditions of the atmosphere for different situations of surface circulations and the associated sea surface...

  6. Surface Treatment of PET Nonwovens with Atmospheric Plasma

    International Nuclear Information System (INIS)

    Li Shufang

    2013-01-01

    In this study, polyethylene-terephthalate (PET) nonwovens are treated using an atmospheric plasma and the effects of the treatment time, treatment power and discharge distance on the ability of water-penetration into the nonwovens are investigated. The result indicates that the method can improve the wettability of PET nonwovens remarkably, but the aging decay of the sample's wettability is found to be notable as a function of the storage time after treatment due to the internal rotation of the single bond of surface macromolecules. As shown by SEM and XPS analysis, the etching and surface reaction are significant, and water-penetration weight is found to increase remarkably with the increasing power. This variation can be attributed to momentum transfer and enhanced higher-energy particle excitation.

  7. The groundwater-land-surface-atmosphere connection: soil moisture effects on the atmospheric boundary layer in fully-coupled simulations

    Energy Technology Data Exchange (ETDEWEB)

    Maxwell, R M; Chow, F K; Kollet, S J

    2007-02-02

    This study combines a variably-saturated groundwater flow model and a mesoscale atmospheric model to examine the effects of soil moisture heterogeneity on atmospheric boundary layer processes. This parallel, integrated model can represent spatial variations in land-surface forcing driven by three-dimensional (3D) atmospheric and subsurface components. The development of atmospheric flow is studied in a series of idealized test cases with different initial soil moisture distributions generated by an offline spin-up procedure or interpolated from a coarse-resolution dataset. These test cases are performed with both the fully-coupled model (which includes 3D groundwater flow and surface water routing) and the uncoupled atmospheric model. The effects of the different soil moisture initializations and lateral subsurface and surface water flow are seen in the differences in atmospheric evolution over a 36-hour period. The fully-coupled model maintains a realistic topographically-driven soil moisture distribution, while the uncoupled atmospheric model does not. Furthermore, the coupled model shows spatial and temporal correlations between surface and lower atmospheric variables and water table depth. These correlations are particularly strong during times when the land surface temperatures trigger shifts in wind behavior, such as during early morning surface heating.

  8. Constraining Agricultural Irrigation Surface Energy Budget Feedbacks in Atmospheric Models

    Science.gov (United States)

    Aufforth, M. E.; Desai, A. R.; Suyker, A.

    2017-12-01

    The expansion and modernization of irrigation increased the relevance of knowing the effects it has on regional weather and climate feedbacks. We conducted a set of observationally-constrained simulations determining the result irrigation exhibits on the surface energy budget, the atmospheric boundary layer, and regional precipitation feedbacks. Eddy covariance flux tower observations were analyzed from two irrigated and one rain-fed corn/soybean rotation sites located near Mead, Nebraska. The evaluated time period covered the summer growing months of June, July, and August (JJA) during the years when corn grew at all three sites. As a product of higher continuous surface moisture availability, the irrigated crops had significantly higher amounts of energy partitioned towards latent heating than the non-irrigated site. The daily average peak of latent heating at the rain-fed site occurred before the irrigated sites and was approximately 45 W/m2 lower. Land surface models were evaluated on their ability to reproduce these effects, including those used in numerical weather prediction and those used in agricultural carbon cycle projection. Model structure, mechanisms, and parameters that best represent irrigation-surface energy impacts will be compared and discussed.

  9. RF atmospheric plasma jet surface treatment of paper

    Science.gov (United States)

    Pawlat, Joanna; Terebun, Piotr; Kwiatkowski, Michał; Diatczyk, Jaroslaw

    2016-09-01

    A radio frequency RF atmospheric pressure plasma jet was used to enhance the wettability of cellulose-based paper of 90 g m-2 and 160 g m-2 grammage as a perspective platform for antibiotic sensitivity tests. Helium and argon were the carrier gases for oxygen and nitrogen; pure water and rapeseed oil were used for goniometric tests. The influence of the flow rate and gas type, the power of the discharge, and distance from the nozzle was examined. The surface structure was observed using an optical microscope. Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectra were investigated in order to determine whether cellulose degradation processes occurred. The RF plasma jet allowed us to decrease the surface contact angle without drastic changes in other features of the tested material. Experiments confirmed the significant influence of the distance between the treated sample and reactor nozzle, especially for treatment times longer than 15 s due to the greater concentration of reactive species at the surface of the sample, which decreases with distance—and their accumulation effect with time. The increase of discharge power plays an important role in decreasing the surface contact angle for times longer than 10 s. Higher power had a positive effect on the amount of generated active particles and facilitated the ignition of discharge. However, a too high value can cause a rise in temperature of the material and heat-caused damage.

  10. Systematic screening of different surface modifiers for the production of physically stable nanosuspensions.

    Science.gov (United States)

    Lestari, Maria L A D; Müller, Rainer H; Möschwitzer, Jan P

    2015-03-01

    The role of a surface modifier is important in the formation of stable nanosuspensions. In this study, a simple and systematic screening method for selecting optimum surface modifiers was performed by utilizing a low-energy wet ball milling method. Nine surface modifiers from different classes with different stabilization mechanisms were applied on six different models of active pharmaceutical ingredients (API). Particle size analysis showed that at concentration five times higher than the critical micelle concentration, SDS and sodium cholate (anionic surfactant) showed the highest percent success to produce stable nanosuspensions with particle size smaller than 250 nm. Similar findings were also shown by poloxamer 188 (nonionic surfactant) and hydroxypropylmethylcellulose E5 (polymeric stabilizer) at concentration 1% (w/v) and 0.8% (w/v), respectively. In addition, combinations of anionic surfactant and nonionic surfactant as well as combinations of anionic surfactant and polymeric stabilizer showed high percent success in the formation of stable nanosuspensions. In general, no correlation can be found between the physicochemical characteristics of the model API (molecular weight, melting point, log P, pKa, and crystallinity) with its feasibility to be nanosized. The concentration and the principle of stabilization of surface modifier determine the formation of stable nanosuspensions. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

  11. Covalent and stable CuAAC modification of silicon surfaces for control of cell adhesion

    DEFF Research Database (Denmark)

    Vutti, Surendra; Buch-Månson, Nina; Schoffelen, Sanne

    2015-01-01

    Stable primary functionalization of metal surfaces plays a significant role in reliable secondary attachment of complex functional molecules used for the interfacing of metal objects and nanomaterials with biological systems. In principle, this can be achieved through chemical reactions either in...

  12. Surface Characterization for Land-Atmosphere Studies of CLASIC

    Science.gov (United States)

    Jackson, T. J.; Kustas, W.; Torn, M. S.; Meyers, T.; Prueger, J.; Fischer, M. L.; Avissar, R.; Yueh, S.; Anderson, M.; Miller, M.

    2006-12-01

    The Cloud and Land Surface Interaction Campaign will focus on interactions between the land surface, convective boundary layer, and cumulus clouds. It will take place in the Southern Great Plains (SGP) area of the U.S, specifically within the US DOE ARM Climate Research Facility. The intensive observing period will be June of 2007, which typically covers the winter wheat harvest in the region. This region has been the focus of several related experiments that include SGP97, SGP99, and SMEX03. For the land surface, some of the specific science questions include 1) how do spatial variations in land cover along this trajectory modulate the cloud structure and the low-level water vapor budget, 2) what are the relationships between land surface characteristics (i.e., soil texture, vegetation type and fractional cover) and states (particularly soil moisture and surface temperature) and the resulting impact of the surface energy balance on boundary layer and cloud structure and dynamics and aerosol loading; and 3) what is the interplay between cumulus cloud development and surface energy balance partitioning between latent and sensible heat, and implications for the carbon flux? Most of these objectives will require flux and state measurements throughout the dominant land covers and distributed over the geographic domain. These observations would allow determining the level of up- scaling/aggregation required in order to understand the impact of landscape changes affecting energy balance/flux partitioning and impact on cloud/atmospheric dynamics. Specific contributions that are planned to be added to CLASIC include continuous tower-based monitoring of surface fluxes for key land cover types prior to, during, and post-IOP, replicate towers to quantify flux variance within each land cover, boundary layer properties and fluxes from a helicopter-based system, airplane- and satellite-based flux products throughout the region, aircraft- and tower-based concentration data for

  13. Measurement of atmospheric surface layer turbulence using unmanned aerial vehicles

    Science.gov (United States)

    Bailey, Sean; Canter, Caleb

    2017-11-01

    We describe measurements of the turbulence within the atmospheric surface layer using highly instrumented and autonomous unmanned aerial vehicles (UAVs). Results from the CLOUDMAP measurement campaign in Stillwater Oklahoma are presented including turbulence statistics measured during the transition from stably stratified to convective conditions. The measurements were made using pre-fabricated fixed-wing remote-control aircraft adapted to fly autonomously and carry multi-hole pressure probes, pressure, temperature and humidity sensors. Two aircraft were flown simultaneously, with one flying a flight path intended to profile the boundary layer up to 100 m and the other flying at a constant fixed altitude of 50 m. The evolution of various turbulent statistics was determined from these flights, including Reynolds stresses, correlations, spectra and structure functions. These results were compared to those measured by a sonic anemometer located on a 7.5 m tower. This work was supported by the National Science Foundation through Grant #CBET-1351411 and by National Science Foundation award #1539070, Collaboration Leading Operational UAS Development for Meteorology and Atmospheric Physics (CLOUDMAP).

  14. Surface wave propagation characteristics in atmospheric pressure plasma column

    International Nuclear Information System (INIS)

    Pencheva, M; Benova, E; Zhelyazkov, I

    2007-01-01

    In the typical experiments of surface wave sustained plasma columns at atmospheric pressure the ratio of collision to wave frequency (ν/ω) is much greater than unity. Therefore, one might expect that the usual analysis of the wave dispersion relation, performed under the assumption ν/ω = 0, cannot give adequate description of the wave propagation characteristics. In order to study these characteristics we have analyzed the wave dispersion relationship for arbitrary ν/ω. Our analysis includes phase and wave dispersion curves, attenuation coefficient, and wave phase and group velocities. The numerical results show that a turning back point appears in the phase diagram, after which a region of backward wave propagation exists. The experimentally observed plasma column is only in a region where wave propagation coefficient is higher than the attenuation coefficient. At the plasma column end the electron density is much higher than that corresponding to the turning back point and the resonance

  15. Atmospheric pressure dielectric barrier discharges for sterilization and surface treatment

    Energy Technology Data Exchange (ETDEWEB)

    Chin, O. H.; Lai, C. K.; Choo, C. Y.; Wong, C. S.; Nor, R. M. [Plasma Technology Research Centre, Physics Department, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Thong, K. L. [Microbiology Division, Institute of Biological Sciences, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-04-24

    Atmospheric pressure non-thermal dielectric barrier discharges can be generated in different configurations for different applications. For sterilization, a parallel-plate electrode configuration with glass dielectric that discharges in air was used. Gram-negative bacteria (Escherichia coli and Salmonella enteritidis) and Gram-positive bacteria (Bacillus cereus) were successfully inactivated using sinusoidal high voltage of ∼15 kVp-p at 8.5 kHz. In the surface treatment, a hemisphere and disc electrode arrangement that allowed a plasma jet to be extruded under controlled nitrogen gas flow (at 9.2 kHz, 20 kVp-p) was applied to enhance the wettability of PET (Mylar) film.

  16. Surface-Atmosphere Moisture Coupling in Eurasian Frozen Ground Regions

    Science.gov (United States)

    Frauenfeld, O. W.; Ford, T.

    2014-12-01

    Permafrost represents an impermeable barrier to moisture, resulting in a saturated or near-saturated surface layer during the warm season in many continuous and discontinuous permafrost zones. These surface conditions could lead to enhanced convection and precipitation during the warm season, and significant local recycling of moisture. In areas underlain by sporadic or isolated permafrost, or in seasonally frozen areas, the moisture can drain away more readily, resulting in much drier soil conditions. As climate change causes frozen ground degradation, this will thus also alter the patterns of atmospheric convection, moisture recycling, and the hydrologic cycle in high-latitude land areas. In this study, we analyze evaporative fraction (EF) as a proxy for evapotranspiration, and precipitation from the Modern-Era Retrospective analysis for Research and Applications (MERRA-land) reanalysis dataset. We focus on 1979-2012 and document patterns and changes in EF over the Eurasian high latitudes. We find strong, positive April EF trends over the study period, particularly in the Lena River Basin, 80% of which is underlain by continuous permafrost. In fact, these significant positive trends in spring EF are strongest over continuous permafrost across the Eurasian high latitudes, but negative for sporadic and isolated permafrost. In addition, we find a strong, statistically significant relationship between EF anomalies and the probability of subsequent precipitation over the Lena Basin during April. This association therefore suggests a potential land-atmosphere coupling between frozen ground and precipitation. As the permafrost and seasonally frozen ground distribution changes in the future, this will likely have repercussions for the Arctic hydrologic cycle.

  17. Sterilization of Surfaces with a Handheld Atmospheric Pressure Plasma

    Science.gov (United States)

    Hicks, Robert; Habib, Sara; Chan, Wai; Gonzalez, Eleazar; Tijerina, A.; Sloan, Mark

    2009-10-01

    Low temperature, atmospheric pressure plasmas have shown great promise for decontaminating the surfaces of materials and equipment. In this study, an atmospheric pressure, oxygen and argon plasma was investigated for the destruction of viruses, bacteria, and spores. The plasma was operated at an argon flow rate of 30 L/min, an oxygen flow rate of 20 mL/min, a power density of 101.0 W/cm^3 (beam area = 5.1 cm^2), and at a distance from the surface of 7.1 mm. An average 6log10 reduction of viable spores was obtained after only 45 seconds of exposure to the reactive gas. By contrast, it takes more than 35 minutes at 121^oC to sterilize anthrax in an autoclave. The plasma properties were investigated by numerical modeling and chemical titration with nitric oxide. The numerical model included a detailed reaction mechanism for the discharge as well as for the afterglow. It was predicted that at a delivered power density of 29.3 W/cm^3, 30 L/min argon, and 0.01 volume% O2, the plasma generated 1.9 x 10^14 cm-3 O atoms, 1.6 x 10^12 cm-3 ozone, 9.3 x 10^13 cm-3 O2(^1δg), and 2.9 x 10^12 cm-3 O2(^1σ^+g) at 1 cm downstream of the source. The O atom density measured by chemical titration with NO was 6.0 x 10^14 cm-3 at the same conditions. It is believe that the oxygen atoms and the O2(^1δg) metastables were responsible for killing the anthrax and other microorganisms.

  18. Investigation of atmospheric dielectric barrier discharge and its application to surface modification of textile material

    International Nuclear Information System (INIS)

    Xiaoliang Tang; Gao Qiu; Hankun Xie; Xianping Feng

    2005-01-01

    The dielectric barrier discharge (DBD) is characterized by the presence of at least one insulating layer in contact with the discharge between two planar or cylindrical electrodes connected to an ac power supply. In this paper, the spectral lines of plasma emission at atmospheric pressure were recorded by using a grating spectrograph, and all signals will be directly and immediately sent to the computer for data processing and analysis during the experiments. The spectrum lines of nitrogen, helium and argon plasma emission at atmospheric pressure were separately recorded and qualitatively analyzed using spectral diagnosis equipment of atmospheric pressure DBD plasma. The spectrum lines of the second positive system of nitrogen (c 3 π μ → B 3 Π g ), two characteristic spectrum lines of helium (3 1 P 1 → 2 1 S 0 , 3 3 D → 3 3 P), and all of neutral argon atom spectrum lines in the range 680 to 780 nm are recognized. For controlling the process of material surface modification promptly, the electron temperature of DBD plasma is quantitatively analyzed using relative intensity of argon spectrum lines. The relationships among the plasma parameters, such as discharge current and discharge power measured by Lissajous figure of the oscilloscope, were analyzed by using improved DBD equipment. The variation of plasma discharge current following the change of discharge gaps indicates an existence of critical gap distance. When the gap between electrodes is less than that the critical gap, a quasi-stable atmospheric pressure DBD plasma source can be achieved after carefully controlled discharge voltage and current. The experimental results indicate that a critical discharge gap is an important parameter to improve the quality of materials processing. The result is of great importance to DBD at atmospheric pressure and its application to materials processing. (author)

  19. Surface modification with a remote atmospheric pressure plasma: dc glow discharge and surface streamer regime

    International Nuclear Information System (INIS)

    Temmerman, Eef; Akishev, Yuri; Trushkin, Nikolay; Leys, Christophe; Verschuren, Jo

    2005-01-01

    A remote atmospheric pressure discharge working with ambient air is used for the near room temperature treatment of polymer foils and textiles of varying thickness. The envisaged plasma effect is an increase in the surface energy of the treated material, leading, e.g., to a better wettability or adhesion. Changes in wettability are examined by measuring the contact angle or the liquid absorptive capacity. Two regimes of the remote atmospheric pressure discharge are investigated: the glow regime and the streamer regime. These regimes differ mainly in power density and in the details of the electrode design. The results show that this kind of discharge makes up a convenient non-thermal plasma source to be integrated into a treatment installation working at atmospheric pressure

  20. The exchange of acetaldehyde between plants and the atmosphere: Stable carbon isotope and flux measurements

    Science.gov (United States)

    Jardine, Kolby Jeremiah

    The exchange of acetaldehyde between plant canopies and the atmosphere may significantly influence regional atmospheric chemistry and plant metabolism. While plants are known to both produce and consume acetaldehyde, the exchange of this compound with forested ecosystems is complicated by physical, biological, and chemical processes that range from being poorly understood to completely unknown. This precludes a quantitative understanding of acetaldehyde exchange rates between the atmosphere and the biosphere. In this study, the processes controlling the exchange of acetaldehyde with plant canopies was investigated using concentration, flux, and natural abundance 13C measurements of gas phase acetaldehyde from individual plants, soils, and entire ecosystems. Although previously only considered important in anoxic tissues, it was discovered that acetaldehyde is produced and consumed in leaves through ethanolic fermentation coupled to the pyruvate dehydrogenase bypass system under normal aerobic conditions. These coupled pathways determine the acetaldehyde compensation point, a major factor controlling its exchange with the atmosphere. Carbon isotope analysis suggests a new pathway for acetaldehyde production from plants under stress involving the peroxidation of membrane fatty acids. This pathway may be a major source of acetaldehyde to the atmosphere from plants under biotic and abiotic stresses. Plant stomata were found to be the dominant pathway for the exchange of acetaldehyde with the atmosphere with stomatal conductance influencing both emission and uptake fluxes. In addition, increasing temperature and solar radiation was found to increase the compensation point by increasing the rates of acetaldehyde production relative to consumption. Under ambient conditions, bare soil was neutral to the exchange of acetaldehyde while senescing and decaying leaves were found to be strong source of acetaldehyde to the atmosphere due to increased decomposition processes and

  1. A Study of stable Atmospheric Boundary Layer over highveld South Africa

    Energy Technology Data Exchange (ETDEWEB)

    Luhunga, P; Djolov, G [University of Pretoria (South Africa); Esau, I, E-mail: george.djolov@up.ac.z

    2010-08-15

    The study is part of the South African - Norwegian Programme for Research and Co-operation Phase II 'Analysis and Possibility for Control of Atmospheric Boundary Layer Processes to Facilitate Adaptation to Environmental Changes'. The research strategy of the project is based on 4 legged approach. 1) Application and further development of contemporary atmospheric boundary layer theory. 2) Use of modeling based on large eddy simulation techniques. 3) Experimental investigation of turbulent fluxes. 4) Training and developing academics capable of dealing with the present and new challenges. The paper presents some preliminary results on the micrometeorological variability of the basic meteorological parameters and turbulent fluxes.

  2. NOAA Climate Data Record (CDR) of Ocean Near Surface Atmospheric Properties, Version 2

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Ocean Surface Bundle (OSB) Climate Data Record (CDR) consist of three parts: sea surface temperature; near-surface wind speed, air temperature, and specific...

  3. Impacts of Ocean Waves on the Atmospheric Surface Layer: Simulations and Observations

    National Research Council Canada - National Science Library

    Sullivan, Peter P; McWilliams, James C; Melville, W. K

    2008-01-01

    ... planetary boundary layers (PBL). Efforts were focused on the effects of surface gravity waves on the near-surface dynamics, surface fluxes, and coupling between the atmospheric and oceanic PBLs...

  4. Surface treatment of silica nanoparticles for stable and charge-controlled colloidal silica

    Science.gov (United States)

    Kim, Kyoung-Min; Kim, Hye Min; Lee, Won-Jae; Lee, Chang-Woo; Kim, Tae-il; Lee, Jong-Kwon; Jeong, Jayoung; Paek, Seung-Min; Oh, Jae-Min

    2014-01-01

    An attempt was made to control the surface charge of colloidal silica nanoparticles with 20 nm and 100 nm diameters. Untreated silica nanoparticles were determined to be highly negatively charged and have stable hydrodynamic sizes in a wide pH range. To change the surface to a positively charged form, various coating agents, such as amine containing molecules, multivalent metal cation, or amino acids, were used to treat the colloidal silica nanoparticles. Molecules with chelating amine sites were determined to have high affinity with the silica surface to make agglomerations or gel-like networks. Amino acid coatings resulted in relatively stable silica colloids with a modified surface charge. Three amino acid moiety coatings (L-serine, L-histidine, and L-arginine) exhibited surface charge modifying efficacy of L-histidine > L-arginine > L-serine and hydrodynamic size preservation efficacy of L-serine > L-arginine > L-histidine. The time dependent change in L-arginine coated colloidal silica was investigated by measuring the pattern of the backscattered light in a Turbiscan™. The results indicated that both the 20 nm and 100 nm L-arginine coated silica samples were fairly stable in terms of colloidal homogeneity, showing only slight coalescence and sedimentation. PMID:25565824

  5. TGP, an extremely stable, non-aggregating fluorescent protein created by structure-guided surface engineering

    OpenAIRE

    Close, Devin W.; Don Paul, Craig; Langan, Patricia S.; Wilce, Matthew C.J.; Traore, Daouda A.K.; Halfmann, Randal; Rocha, Reginaldo C.; Waldo, Geoffery S.; Payne, Riley J.; Rucker, Joseph B.; Prescott, Mark; Bradbury, Andrew R.M.

    2015-01-01

    In this paper we describe the engineering and X-ray crystal structure of Thermal Green Protein (TGP), an extremely stable, highly soluble, non-aggregating green fluorescent protein. TGP is a soluble variant of the fluorescent protein eCGP123, which despite being highly stable, has proven to be aggregation-prone. The X-ray crystal structure of eCGP123, also determined within the context of this paper, was used to carry out rational surface engineering to improve its solubility, leading to TGP....

  6. A land surface scheme for atmospheric and hydrologic models: SEWAB (Surface Energy and Water Balance)

    Energy Technology Data Exchange (ETDEWEB)

    Mengelkamp, H.T.; Warrach, K.; Raschke, E. [GKSS-Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Atmosphaerenphysik

    1997-12-31

    A soil-vegetation-atmosphere-transfer scheme is presented here which solves the coupled system of the Surface Energy and Water Balance (SEWAB) equations considering partly vegetated surfaces. It is based on the one-layer concept for vegetation. In the soil the diffusion equations for heat and moisture are solved on a multi-layer grid. SEWAB has been developed to serve as a land-surface scheme for atmospheric circulation models. Being forced with atmospheric data from either simulations or measurements it calculates surface and subsurface runoff that can serve as input to hydrologic models. The model has been validated with field data from the FIFE experiment and has participated in the PILPS project for intercomparison of land-surface parameterization schemes. From these experiments we feel that SEWAB reasonably well partitions the radiation and precipitation into sensible and latent heat fluxes as well as into runoff and soil moisture Storage. (orig.) [Deutsch] Ein Landoberflaechenschema wird vorgestellt, das den Transport von Waerme und Wasser zwischen dem Erdboden, der Vegetation und der Atmosphaere unter Beruecksichtigung von teilweise bewachsenem Boden beschreibt. Im Erdboden werden die Diffusionsgleichungen fuer Waerme und Feuchte auf einem Gitter mit mehreren Schichten geloest. Das Schema SEWAB (Surface Energy and Water Balance) beschreibt die Landoberflaechenprozesse in atmosphaerischen Modellen und berechnet den Oberflaechenabfluss und den Basisabfluss, die als Eingabedaten fuer hydrologische Modelle genutzt werden koennen. Das Modell wurde mit Daten des FIFE-Experiments kalibriert und hat an Vergleichsexperimenten fuer Landoberflaechen-Schemata im Rahmen des PILPS-Projektes teilgenommen. Dabei hat sich gezeigt, dass die Aufteilung der einfallenden Strahlung und des Niederschlages in den sensiblen und latenten Waermefluss und auch in Abfluss und Speicherung der Bodenfeuchte in SEWAB den beobachteten Daten recht gut entspricht. (orig.)

  7. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Sugiyama, Y.; Hosseini, S.H.R.; Akiyama, H.; Lukeš, Petr; Akiyama, M.

    2016-01-01

    Roč. 49, č. 41 (2016), č. článku 415202. ISSN 0022-3727 Institutional support: RVO:61389021 Keywords : water surface * spectroscopy * high-speed photography * pulsed plasma discharge * Atmospheric-pressure plasmas * electric discharges * liquids * water Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.588, year: 2016 http://iopscience.iop.org/article/10.1088/0022-3727/49/41/415202

  8. Design and Fabrication of a Hybrid Superhydrophobic-Hydrophilic Surface That Exhibits Stable Dropwise Condensation.

    Science.gov (United States)

    Mondal, Bikash; Mac Giolla Eain, Marc; Xu, QianFeng; Egan, Vanessa M; Punch, Jeff; Lyons, Alan M

    2015-10-28

    Condensation of water vapor is an essential process in power generation, water collection, and thermal management. Dropwise condensation, where condensed droplets are removed from the surface before coalescing into a film, has been shown to increase the heat transfer efficiency and water collection ability of many surfaces. Numerous efforts have been made to create surfaces which can promote dropwise condensation, including superhydrophobic surfaces on which water droplets are highly mobile. However, the challenge with using such surfaces in condensing environments is that hydrophobic coatings can degrade and/or water droplets on superhydrophobic surfaces transition from the mobile Cassie to the wetted Wenzel state over time and condensation shifts to a less-effective filmwise mechanism. To meet the need for a heat-transfer surface that can maintain stable dropwise condensation, we designed and fabricated a hybrid superhydrophobic-hydrophilic surface. An array of hydrophilic needles, thermally connected to a heat sink, was forced through a robust superhydrophobic polymer film. Condensation occurs preferentially on the needle surface due to differences in wettability and temperature. As the droplet grows, the liquid drop on the needle remains in the Cassie state and does not wet the underlying superhydrophobic surface. The water collection rate on this surface was studied using different surface tilt angles, needle array pitch values, and needle heights. Water condensation rates on the hybrid surface were shown to be 4 times greater than for a planar copper surface and twice as large for silanized silicon or superhydrophobic surfaces without hydrophilic features. A convection-conduction heat transfer model was developed; predicted water condensation rates were in good agreement with experimental observations. This type of hybrid superhydrophobic-hydrophilic surface with a larger array of needles is low-cost, robust, and scalable and so could be used for heat

  9. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    OpenAIRE

    B. Xiang; D. D. Nelson; J. B. McManus; M. S. Zahniser; R. Wehr; S. C. Wofsy

    2014-01-01

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known...

  10. Recent advances in understanding atmospheric CO based on stable isotope measurements

    Science.gov (United States)

    Popa, Maria Elena; Naus, Stijn; Ferrero Lopez, Noelia; Vijverberg, Sem; de Leeuw, Selma; Röckmann, Thomas

    2017-04-01

    Carbon monoxide (CO) plays an important role for atmospheric chemistry and for carbon cycling in the atmosphere. Via its reaction with the OH radical it influences concentrations of many other trace gases, it is an important precursor for O3 formation, and its oxidation leads to the formation of about 1 Pg C per year of CO2. The natural and anthropogenic sources of CO are subject to relatively large temporal changes due to natural variability (e.g. biomass burning), industrial activity and mitigation measures (e.g. fossil fuel burning), variations in precursor compounds (e.g. CH4 and VOC) and variations in the abundance of the OH radical in the atmosphere, which are difficult to quantify. Isotope measurements can be used to distinguish between the effects of individual sources and sinks to put tighter constrains on its budget, but the isotopic characterization of the CO sources is in many cases still based on a few relatively old measurements that did not allow to account for dependence on parameters. We will present an update of the isotopic composition of several sources and removal processes of CO that have been carried out in the past years with the automated continuous-flow IRMS system at Utrecht University. This includes: - the previously unknown isotopic composition of direct biogenic CO emissions - a surprisingly large variability in the isotopic composition of CO emitted by different vehicles and single vehicles under various driving conditions - previously very poorly investigated signatures, like the fractionation in the removal of CO by soils, and its interaction with CO that is simultaneously emitted from soil. These results from process specific investigations will be linked to recent atmospheric measurements at various locations.

  11. Xe anions in stable Mg-Xe compounds: the mechanism of missing Xe in earth atmosphere

    OpenAIRE

    Miao, Mao-sheng

    2013-01-01

    The reactivity of noble gas elements is important for both fundamental chemistry and geological science. The discovery of the oxidation of Xe extended the doctrinal boundary of chemistry that a complete shell is inert to reaction. The oxidations of Xe by various geological substances have been researched in order to explain the missing Xe in earth atmosphere. Among many proposals, the chemistry mechanisms are straightforward as they identify chemical processes that can capture Xe in earth int...

  12. Quantification of Gaseous Elemental Mercury Dry Deposition to Environmental Surfaces using Mercury Stable Isotopes in a Controlled Environment

    Science.gov (United States)

    Rutter, A. P.; Schauer, J. J.; Shafer, M. M.; Olson, M.; Robinson, M.; Vanderveer, P.; Creswell, J. E.; Parman, A.; Mallek, J.; Gorski, P.

    2009-12-01

    atmospheric turbulence and wind speed. GEM enriched in stable isotope 198 (GEM-198) was released into the room from source at elevated but environmentally relevant concentrations of GEM-198 for several days. Uptake of GEM-198 from deciduous and conifer trees, grass turf, 3 types of soil, sand, concrete, asphalt, and adsorbent coated deposition coupons were quantified over several days. Exposures were conducted between 10oC and 30oC, in dark and light conditions. Mercury was recovered from the samples using acidic digestions and surface leaches, and then analyzed for the content of GEM-198 by high resolution ICPMS. Experimental results demonstrated that uptake by White Ash, White Spruce, and Kentucky bluegrass were significantly higher than uptakes measured for two Wisconsin soils, peat, sand, concrete and asphalt at all of the conditions studied. Deposition resistances for surface transfer processes for were calculated for each of the substrates across the conditions studied for use in atmospheric model simulations.

  13. Stable Carbon Isotope Ratios in Atmospheric VOC across the Asian Summer Monsoon Anticyclone obtained during the OMO-ASIA campaign

    Science.gov (United States)

    Krebsbach, Marc; Koppmann, Ralf; Meisehen, Thomas

    2017-04-01

    The automated high volume air sampling system (MIRAH) has been deployed during the atmospheric measurement campaign OMO-ASIA (Oxidation Mechanism Observations) with the German High Altitude - Long-range research aircraft (HALO) in July and August 2015. The intensive measurement period with base stations in Paphos (Cyprus) and Gan (Maldives) focussed on oxidation processes and air pollution chemistry downwind of the South Asia summer monsoon anticyclone, a pivot area critical for air quality and climate change, both regionally and worldwide. The measurement region covered the Eastern Mediterranean region, the Arabian Peninsula, Egypt, and the Arabian Sea. In total 194 air samples were collected on 17 flights in a height region from 3 km up to 15 km. The air samples were analysed for stable carbon isotope ratios in VOC with GC-C-IRMS in the laboratory afterwards. We determined stable carbon isotope ratios and mixing ratios of several aldehydes, ketones, alcohols, and aromatics. The large extent of the investigated area allowed for encountering air masses with different origin, characteristic, and atmospheric processing, e.g. Mediterranean air masses, crossing of polluted filaments and remnants of the Asian monsoon outflow, split of the Asian monsoon anticyclone. In this presentation we will show first results and interpretations supported by HYSPLIT backward trajectories.

  14. Experimental and numerical study of atmospheric turbulence and dispersion in stable conditions and in near field at a complex site

    International Nuclear Information System (INIS)

    Wei, Xiao

    2016-01-01

    An experimental program has been designed in order to study pollutants dispersion at a complex site with a focus on stable conditions, which are still challenging for numerical modelling. This experimental program is being conducted at the SIRTA site in a southern suburb of Paris and consists in measuring, in near field, the turbulence and the pollutants dispersion. The aim of this program is to characterize the fine structure of turbulence and associated dispersion through high temporal and spatial resolution measurements. Then, these measurements allow to validate and improve the performance of CFD simulation for turbulence and dispersion in a heterogeneous field. The instrumental set up includes 12 ultrasonic anemometers measuring continuously wind velocity and temperature at 10 Hz, and 6 photo-ionization detectors (PIDs) measuring gas concentration at 50 Hz during tracer tests. Intensive observations periods (IOPs) with gas releases have been performed since March 2012.First of all, a detailed study of flow on the site is made, because it must be characterised and properly simulated before attempting to simulate the pollutants dispersion. This study is based on two years of continuous measurements and on measurements performed during IOPs. Turbulence strong anisotropy in the surface layer is characterized by calculating variances, integral length scales and power spectra of the three wind velocity components. Propagation of turbulent structures between sensors has been characterized with velocity correlations. Energy spectra show several slopes in different frequency regions. Also, data analyses show impact of terrain heterogeneity on the measurements. The forest to the north of experimental field modifies wind velocity and direction for a large northerly sector. It induces a strong directional wind shear and a wind deceleration below the forest height. Numerical simulations are carried out using the CFD code Code-Saturne in RANS mode with a standard κ

  15. Experimental and numerical study of atmospheric turbulence and dispersion in stable conditions and in near field at a complex site

    International Nuclear Information System (INIS)

    Wei, Xiao

    2016-01-01

    An experimental program has been designed in order to study pollutants dispersion at a complex site with a focus on stable conditions, which are still challenging for numerical modelling. This experimental program is being conducted at the SIRTA site in a southern suburb of Paris and consists in measuring, in near field, the turbulence and the pollutants dispersion. The aim of this program is to characterize the fine structure of turbulence and associated dispersion through high temporal and spatial resolution measurements. Then, these measurements allow to validate and improve the performance of CFD simulation for turbulence and dispersion in a heterogeneous field. The instrumental set up includes 12 ultrasonic anemometers measuring continuously wind velocity and temperature at 10 Hz, and 6 photo-ionization detectors (PIDs) measuring gas concentration at 50 Hz during tracer tests. Intensive observations periods (IOPs) with gas releases have been performed since March 2012. First of all, a detailed study of flow on the site is made, because it must be characterised and properly simulated before attempting to simulate the pollutants dispersion. This study is based on two years of continuous measurements and on measurements performed during IOPs. Turbulence strong anisotropy in the surface layer is characterized by calculating variances, integral length scales and power spectra of the three wind velocity components. Propagation of turbulent structures between sensors has been characterized with velocity correlations. Energy spectra show several slopes in different frequency regions. Also, data analyses show impact of terrain heterogeneity on the measurements. The forest to the north of the experimental field modifies wind velocity and direction for a large northerly sector. It induces a strong directional wind shear and a wind deceleration below the forest height. Numerical simulations are carried out using the CFD code, Code-Saturne, in RANS mode with a standard k

  16. Fabrication and characterization of stable superhydrophobic surface with good friction-reducing performance on Al foil

    Energy Technology Data Exchange (ETDEWEB)

    Li, Peipei [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China); Chen, Xinhua, E-mail: xuc0374@hotmail.com [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang 461000 (China); Yang, Guangbin; Yu, Laigui [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China); Zhang, Pingyu, E-mail: pingyu@henu.edu.cn [Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004 (China)

    2014-05-01

    Graphical abstract: A lotus-leaf-like hierarchical structure was successfully created on Al foil by a facile three-step solution–immersion method. As-obtained etched-immersed Al/STA rough surface contains interconnected convex–concave micro-structure and uniformly distributed nano-sheets that endow the surface with excellent superhydrophobicity (WCA: 164.2°; WSA: below 5°). Besides, the as-prepared etched-immersed Al/STA superhydrophobic surface on Al foil exhibits good friction-reducing ability and stable superhydrophobicity. - Highlights: • A stable superhydrophobic surface was created on aluminum foil by a facile three-step solution–immersion method. • A lotus-leaf-like hierarchical structure consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets has been constructed on the aluminum surface. • The superhydrophobic surfaces on aluminum substrate showing effective friction-reducing performance and self-cleaning ability. - Abstract: A lotus-leaf-like hierarchical structure with superhydrophobicity was created on Al foil by a facile three-step solution–immersion method involving etching in hydrochloric acid solution and immersing in hot water as well as surface-modification by stearic acid (denoted as STA). As-prepared etched-immersed Al/STA rough surface was characterized by means of scanning electron microscopy and X-ray photoelectron spectroscopy. Moreover, the water contact angles and water sliding angles of as-prepared etched-immersed Al/STA rough surface were measured, and the friction-reducing performance and self-cleaning ability of the as-prepared surface were also evaluated. Results indicate that the etched-immersed Al/STA rough surface consists of interconnected convex–concave micro-structure and uniformly distributed nano-sheets. Besides, it exhibits stable superhydrophobicity and good friction-reducing ability. Namely, it has a contact angle of water as high as 164.2° and a water sliding

  17. ultra-Stable Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (5STAR)

    Science.gov (United States)

    Dunagan, S. E.; Johnson, R. R.; Redemann, J.; Holben, B. N.; Schmid, B.; Flynn, C. J.; Fahey, L.; LeBlanc, S. E.; Liss, J.; Kacenelenbogen, M. S.; Segal-Rosenhaimer, M.; Shinozuka, Y.; Dahlgren, R. P.; Pistone, K.; Karol, Y.

    2017-12-01

    The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with diffraction spectroscopy to improve knowledge of atmospheric constituents and their links to air pollution and climate. Direct beam hyperspectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. Hyperspectral cloud-transmitted radiance measurements enable the retrieval of cloud properties from below clouds. These measurements tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/ sky-scanning optical head with optical fiber signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical tracking head, and future detector evolution. 4STAR has supported a broad range of flight experiments since it was first flown in 2010. This experience provides the basis for a series of improvements directed toward reducing measurement uncertainty and calibration complexity, and expanding future measurement capabilities, to be incorporated into a new 5STAR instrument. A 9-channel photodiode radiometer with AERONET-matched bandpass filters will be incorporated to improve calibration stability. A wide dynamic range tracking camera will provide a high precision solar position tracking signal as well as an image of sky conditions around the solar axis. An ultrasonic window cleaning system design will be tested. A UV spectrometer tailored for formaldehyde and SO2 gas retrievals will be added to the spectrometer enclosure. Finally, expansion capability for a 4 channel polarized radiometer to measure the Stokes polarization vector of sky light will be incorporated. This paper presents initial progress on this next-generation 5STAR instrument. Keywords: atmosphere; climate; pollution; radiometry; technology; hyperspectral; fiber optic

  18. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity.

    Science.gov (United States)

    Wong, Tak-Sing; Kang, Sung Hoon; Tang, Sindy K Y; Smythe, Elizabeth J; Hatton, Benjamin D; Grinthal, Alison; Aizenberg, Joanna

    2011-09-21

    Creating a robust synthetic surface that repels various liquids would have broad technological implications for areas ranging from biomedical devices and fuel transport to architecture but has proved extremely challenging. Inspirations from natural nonwetting structures, particularly the leaves of the lotus, have led to the development of liquid-repellent microtextured surfaces that rely on the formation of a stable air-liquid interface. Despite over a decade of intense research, these surfaces are, however, still plagued with problems that restrict their practical applications: limited oleophobicity with high contact angle hysteresis, failure under pressure and upon physical damage, inability to self-heal and high production cost. To address these challenges, here we report a strategy to create self-healing, slippery liquid-infused porous surface(s) (SLIPS) with exceptional liquid- and ice-repellency, pressure stability and enhanced optical transparency. Our approach-inspired by Nepenthes pitcher plants-is conceptually different from the lotus effect, because we use nano/microstructured substrates to lock in place the infused lubricating fluid. We define the requirements for which the lubricant forms a stable, defect-free and inert 'slippery' interface. This surface outperforms its natural counterparts and state-of-the-art synthetic liquid-repellent surfaces in its capability to repel various simple and complex liquids (water, hydrocarbons, crude oil and blood), maintain low contact angle hysteresis (<2.5°), quickly restore liquid-repellency after physical damage (within 0.1-1 s), resist ice adhesion, and function at high pressures (up to about 680 atm). We show that these properties are insensitive to the precise geometry of the underlying substrate, making our approach applicable to various inexpensive, low-surface-energy structured materials (such as porous Teflon membrane). We envision that these slippery surfaces will be useful in fluid handling and

  19. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    OpenAIRE

    B. Xiang; D. D. Nelson; J. B. McManus; M. S. Zahniser; R. A. Wehr; S. C. Wofsy

    2014-01-01

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 μmol mol−1, or ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell wi...

  20. Airborne spectral measurements of surface-atmosphere anisotropy for several surfaces and ecosystems over southern Africa

    Science.gov (United States)

    Gatebe, Charles K.; King, Michael D.; Platnick, Steve; Arnold, G. Thomas; Vermote, Eric F.; Schmid, Beat

    2003-07-01

    The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft during the Southern Africa Regional Science Initiative 2000 (SAFARI 2000) dry season campaign and obtained measurements of bidirectional reflectance distribution function (BRDF) for a variety of natural surfaces and ecosystems in southern Africa. To measure the BRDF of the surface-atmosphere system, the University of Washington CV-580 banked at a roll angle of ˜20° and flew circles about 3 km in diameter above the surface, taking approximately 2 min. Multiple circular orbits were acquired over selected surfaces so that average BRDFs could be acquired, smoothing out small-scale surface and atmospheric inhomogeneities. In this paper, we present results of BRDFs taken over two Earth Observing System (EOS) validation sites: Skukuza tower, South Africa (25.0°S, 31.5°E) and Mongu tower, Zambia (15.4°S, 23.3°E). Additional sites are discussed and include the Maun tower, Botswana (20.0°S, 23.6°E), Sua Pan, Botswana (20.6°S, 25.9°E), Etosha Pan, Namibia (19.0°S, 16.0°E), and marine stratocumulus clouds off the west coast of Namibia (20.5°S, 13.1°E). Results clearly show anisotropy in reflected solar radiation over the various surfaces types: savanna, salt pans, and cloud. The greatest anisotropy is observed over marine stratus clouds, which exhibit strong forward scattering as well as important water cloud scattering features such as the rainbow and glory. The BRDF over savanna is characterized by a distinct backscattering peak in the principal plane and shows directional and spectral variations. Over the pans, the BRDF is more enhanced in the backscattering plane than forward scattering plane and shows little directional variation.

  1. Cost-effective fabrication of thermal- and chemical-stable ZIF-9 nanocrystals at ammonia atmosphere

    Science.gov (United States)

    Ebrahimi, Arash; Mansournia, Mohammadreza

    2017-12-01

    In this study, room temperature synthesis of zeolitic imidazolate framework-9 (ZIF-9) nanocrystals is reported for the first time at ammonia atmosphere in the absence of any organic additive. High thermal stability of the as-fabricated ZIF-9 up to 300 °C is illustrated by TG and XRD data. Also, the chemical resistance of product to harsh and severe solvothermal conditions introduces it to be an objective as potential material in many applications. Besides, the modest microporosity of the as-obtained ZIF-9 materials attracts more attentions for further investigation compared to those fabricated in organic solvents. By and large, the represented low-cost and room temperature synthetic method can be applicable in the large scale preparation of ZIF-9 for potentially practical utilization.

  2. Formation of hydrophobic coating on glass surface using atmospheric pressure non-thermal plasma in ambient air

    International Nuclear Information System (INIS)

    Fang, Z; Qiu, Y; Kuffel, E

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in material surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of a glass surface for improving hydrophobicity using a non-thermal plasma generated by a dielectric barrier corona discharge (DBCD) with a needle array-to-plane electrode arrangement in atmospheric air is conducted, and the surface properties of the glass before and after the DBCD treatment are studied using contact angle measurement, surface resistance measurement and the wet flashover voltage test. The effects of the plasma dose (the product of average discharge power and treatment time) of DBCD on the surface modification are studied, and the mechanism of interaction between the plasma and glass surface is discussed. It is found that a layer of hydrophobic coating is formed on the glass surface through DBCD treatment, and the improvement of hydrophobicity depends on the plasma dose of the DBCD. It seems that there is an optimum plasma dose for the surface treatment. The test results of thermal ageing and chemical ageing show that the hydrophobic layer has quite stable characteristics

  3. Complementary nature of surface and atmospheric parameters associated with Haiti earthquake of 12 January 2010

    Directory of Open Access Journals (Sweden)

    Ramesh P. Singh

    2010-06-01

    Full Text Available The present paper describes surface (surface air temperature and atmospheric parameters (relative humidity, surface latent heat flux over the epicenter (18°27´25´´ N 72°31´59´´ W of Haiti earthquake of 12 January 2010. Our analysis shows pronounced changes in surface and atmospheric parameters few days prior to the main earthquake event. Changes in relative humidity are found from the surface up to an altitude of 500 hPa clearly show atmospheric perturbations associated with the earthquake event. The purpose of this paper is to show complementary nature of the changes observed in surface, atmospheric and meteorological parameters. The total ozone concentration is found to be lowest on the day of earthquake and afterwards found to be increased within a week of earthquake. The present results show existence of coupling between lithosphere-atmosphere associated with the deadly Haiti earthquake.

  4. Variations in stable hydrogen and oxygen isotopes in atmospheric water vapor in the marine boundary layer across a wide latitude range.

    Science.gov (United States)

    Liu, Jingfeng; Xiao, Cunde; Ding, Minghu; Ren, Jiawen

    2014-11-01

    The newly-developed cavity ring-down laser absorption spectroscopy analyzer with special calibration protocols has enabled the direct measurement of atmospheric vapor isotopes at high spatial and temporal resolution. This paper presents real-time hydrogen and oxygen stable isotope data for atmospheric water vapor above the sea surface, over a wide range of latitudes spanning from 38°N to 69°S. Our results showed relatively higher values of δ(18)O and δ(2)H in the subtropical regions than those in the tropical and high latitude regions, and also a notable decreasing trend in the Antarctic coastal region. By combining the hydrogen and oxygen isotope data with meteoric water line and backward trajectory model analysis, we explored the kinetic fractionation caused by subsiding air masses and related saturated vapor pressure in the subtropics, and the evaporation-driven kinetic fractionation in the Antarctic region. Simultaneous observations of meteorological and marine variables were used to interpret the isotopic composition characteristics and influential factors, indicating that d-excess is negatively correlated with humidity across a wide range of latitudes and weather conditions worldwide. Coincident with previous studies, d-excess is also positively correlated with sea surface temperature and air temperature (Tair), with greater sensitivity to Tair. Thus, atmospheric vapor isotopes measured with high accuracy and good spatial-temporal resolution could act as informative tracers for exploring the water cycle at different regional scales. Such monitoring efforts should be undertaken over a longer time period and in different regions of the world. Copyright © 2014. Published by Elsevier B.V.

  5. Experimental and numerical investigations of stable crack growth of axial surface flaws in a pressure vessel

    International Nuclear Information System (INIS)

    Brocks, W.; Krafka, H.; Mueller, W.; Wobst, K.

    1988-01-01

    In connection with the problem of the transferability of parameters obtained experimentally with the help of fracture-mechanical test specimens and used for the initiation and the stable propagation of cracks in cases of pulsating stress and of the elasto-plastic behaviour of construction components, a pressure vessel with an inside diameter of 1500 mm, a cylindrical length of 3000 mm and a wall thickness of 40 mm was hydraulically loaded with the help of internal pressure in the first stage, to attain an average crack growth of 1 mm at Δ a ≅, the loading taking place at about 21deg C. This stress-free annealed vessel exhibited an axial semielliptical vibration-induced surface crack about 181 mm long and 20 mm deep, as a test defect, in a welded circular blank made of the steel 20MnMoNi 55. The fractographic analysis of the first stable crack revealed that its growth rate of Δa was highest in the area of transition from the weak to the strong bend of the crack front (55deg m /σ v (average principal stress: σ m , Mises' reference stress: σ v v). A comparison of the experimental with the numerical results from the first stable crack shows that the local stable crack growth Δa cannot be calculated solely with reference to J, because Δa appears to depend essentially on the quotient σ m /σ v . (orig./MM) [de

  6. Decomposing Shortwave Top-of-Atmosphere Radiative Flux Variability in Terms of Surface and Atmospheric Contributions Using CERES Observations

    Science.gov (United States)

    Loeb, N. G.; Wong, T.; Wang, H.

    2017-12-01

    Earth's climate is determined by the exchange of radiant energy between the Sun, Earth and space. The absorbed solar radiation (ASR) fuels the climate system, providing the energy required for atmospheric and oceanic motions, while the system cools by emitting outgoing longwave (LW) radiation to space. A central objective of the Clouds and the Earth's Radiant Energy System (CERES) is to produce a long-term global climate data record of Earth's radiation budget along with the associated atmospheric and surface properties that influence it. CERES data products utilize a number of data sources, including broadband radiometers measuring incoming and reflected solar radiation and OLR, polar orbiting and geostationary spectral imagers, meteorological, aerosol and ozone assimilation data, and snow/sea-ice maps based on microwave radiometer data. Here we use simple diagnostic model of Earth's albedo and CERES Energy Balanced and Filled (EBAF) Ed4.0 data for March 2000-February 2016 to quantify interannual variations in SW TOA flux associated with surface albedo and atmospheric reflectance and transmittance variations. Surface albedo variations account for <0.5% of the total SW TOA flux variance over the tropics and 4% globally. Variations in atmospheric reflectance and transmittance account for virtually all of the total SW TOA flux variance over the tropics and only 81% globally. The remaining 15% of the global SW TOA flux variance is explained by the co-variance of surface albedo and atmospheric reflectance/transmittance. Equatorward of 60-degree latitude, the atmospheric contribution exceeds that of the surface by at least an order-of-magnitude. In contrast, the surface and atmospheric variations contribute equally poleward of 60S and surface variations account for twice as much as the atmosphere poleward of 60N. However, as much as 40% of the total SW TOA flux variance poleward of 60N is explained by the covariance of surface albedo and atmospheric reflectance

  7. Land Surface Model (LSM 1.0) for Ecological, Hydrological, Atmospheric Studies

    Data.gov (United States)

    National Aeronautics and Space Administration — The NCAR LSM 1.0 is a land surface model developed to examine biogeophysical and biogeochemical land-atmosphere interactions, especially the effects of land surfaces...

  8. Temporal and Spatial Variabilities of Japan Sea Surface Temperature and Atmospheric Forcings

    National Research Council Canada - National Science Library

    Chu, Peter C; Chen, Yuchun; Lu, Shihua

    1998-01-01

    ...) and surface air temperature (SAT) data during 1982-1994 and the National Center for Atmospheric Research surface wind stress curl data during 1982-1989 to investigate the Japan Sea SST temporal and spatial variabilities...

  9. Effect of surface texture and structure on the development of stable fluvial armors

    Science.gov (United States)

    Bertin, Stephane; Friedrich, Heide

    2018-04-01

    Stable fluvial armors are found in river systems under conditions of partial sediment transport and limited sediment supply, a common occurrence in nature. Stable armoring is also readily recreated in experimental flumes. Initially, this bed stabilizing phenomenon was examined for different flow discharges and solely related to surface coarsening and bedload transport reduction. The models developed suggest a specific armor composition (i.e., texture) dependent on the parent bed material and formative discharge. Following developments in topographic remote sensing, recent research suggests that armor structure is an important control on bed stability and roughness. In this paper, replicated flume runs during which digital elevation models (DEMs) were collected from both exposed and flooded gravel beds are used to interpret armoring manifestations and to assess their replicability. A range of methodologies was used for the analysis, providing information on (i) surface grain size and orientation, (ii) bed-elevation distributions, (iii) the spatial coherence of the elevations at the grain-scale, (iv) surface slope and aspect, (v) grain imbrication and (vi) the spatial variability in DEM properties. The bed-surface topography was found to be more responsive than bed-material size to changes in flow strength. Our experimental results also provide convincing evidence that gravel-beds' response to water-work during parallel degradation is unique (i.e., replicable) given the formative parameters. Based on this finding, relationships between the armors' properties and formative parameters are proposed, and are supported by adding extensive data from previous research.

  10. Surface Pressure Measurements of Atmospheric Tides Using Smartphones

    Science.gov (United States)

    Price, Colin; Maor, Ron

    2017-04-01

    Similar to the oceans, the atmosphere also has tides that are measured in variations of atmospheric pressure. However, unlike the gravitational tides in the oceans, the atmospheric tides are caused primarily in the troposphere and stratosphere when the atmosphere is periodically heated by the sun, due to tropospheric absorption by water vapor and stratospheric absorption by ozone. Due to the forcing being always on the day side of the globe, the tides migrate around the globe following the sun (migrating tides) with a dominant periodicity of 12 hours (and less so at 24 hours). In recent years smartphones have been equipped with sensitive, cheap and reliable pressure sensors that can easily detect these atmospheric tides. By 2020 it is expected that there will be more than 6 billion smartphones globally, each measuring continuously atmospheric pressure at 1Hz temporal resolution. In this presentation we will present some control experiments we have performed with smartphones to monitor atmospheric tides, while also using random pressure data from more than 50,000 daily users via the WeatherSignal application. We conclude that smartphones are a useful tool for studying atmospheric tides on local and global scales.

  11. Aspects of the atmospheric surface layers on Mars and Earth

    DEFF Research Database (Denmark)

    Larsen, Søren Ejling; Ejsing Jørgensen, Hans; Landberg, L.

    2002-01-01

    and mean flow on Mars is found to obey the same scaling laws as on Earth. The largest micrometeorological differences between the two atmospheres are associated with the low air density of the Martian atmosphere. Together with the virtual absence of water vapour, it reduces the importance...

  12. Indoor and outdoor urban atmospheric CO2: Stable carbon isotope constraints on mixing and mass balance

    International Nuclear Information System (INIS)

    Yanes, Yurena; Yapp, Crayton J.

    2010-01-01

    suggests that the intercept of a mixing line defined by two data points (CO 2 input from the local ventilation system and CO 2 in the ambient air of the room) could be a reasonable estimate of the average δ 13 C value of the CO 2 exhaled by the human occupants. Thus, such indoor spaces appear to constitute effective 'sample vessels' for collection of CO 2 that can be used to determine the average proportions of C 3 and C 4 -derived C in the diets of the occupants. For the various groups occupying the rooms sampled in this study, C 4 -derived C appears to have constituted ∼40% of the average diet. The average concentration of outdoor Dallas atmospheric CO 2 was ∼17 ppm higher than the average of CO 2 concentrations measured on the same campus 10 a ago. In addition, Dallas outdoor CO 2 concentrations at both times were higher than the contemporaneous global atmospheric CO 2 concentrations. This observation, plus the fact that the increase of ∼17 ppm in the average concentration of Dallas outdoor CO 2 was comparable to the global increase of ∼18 ppm over the same 10-a interval, is consistent with a significant role for urban CO 2 'factories' in the global atmospheric CO 2 budget.

  13. Atmospheric plasma inactivation of foodborne pathogens on fresh produce surfaces.

    Science.gov (United States)

    Critzer, Faith J; Kelly-Wintenberg, Kimberly; South, Suzanne L; Golden, David A

    2007-10-01

    A study was conducted to determine the effect of one atmosphere uniform glow discharge plasma (OAUGDP) on inactivation of Escherichia coli O157:H7, Salmonella, and Listeria monocytogenes on apples, cantaloupe, and lettuce, respectively. A five-strain mixture of cultured test organisms was washed, suspended in phosphate buffer, and spot inoculated onto produce (7 log CFU per sample). Samples were exposed inside a chamber affixed to the OAUGDP blower unit operated at a power of 9 kV and frequency of 6 kHz. This configuration allows the sample to be placed outside of the plasma generation unit while allowing airflow to carry the antimicrobial active species, including ozone and nitric oxide, onto the food sample. Cantaloupe and lettuce samples were exposed for 1, 3, and 5 min, while apple samples were exposed for 30 s, 1 min, and 2 min. After exposure, samples were pummeled in 0.1% peptone water-2% Tween 80, diluted, and plated in duplicate onto selective media and tryptic soy agar and incubated as follows: E. coli O157:H7 (modified eosin methylene blue) and Salmonella (xylose lysine tergitol-4) for 48 h at 37 degrees C, and L. monocytogenes (modified Oxford medium) at 48 h for 32 degrees C. E. coli O157:H7 populations were reduced by >1 log after 30-s and 1-min exposures and >2 log after a 2-min exposure. Salmonella populations were reduced by >2 log after 1 min. Three- and 5-min exposure times resulted in >3-log reduction. L. monocytogenes populations were reduced by 1 log after 1 min of exposure. Three- and 5-min exposure times resulted in >3- and >5-log reductions, respectively. This process has the capability of serving as a novel, nonthermal processing technology to be used for reducing microbial populations on produce surfaces.

  14. Abdominal muscle EMG-activity during bridge exercises on stable and unstable surfaces.

    Science.gov (United States)

    Czaprowski, Dariusz; Afeltowicz, Anna; Gębicka, Anna; Pawłowska, Paulina; Kędra, Agnieszka; Barrios, Carlos; Hadała, Michał

    2014-08-01

    To assess abdominal muscles (AM) activity during prone, side, and supine bridge on stable and unstable surfaces (BOSU, Swiss Ball). Prospective comparison study. Research laboratory. Thirty-three healthy volunteers from a university population. Surface electromyography of the rectus abdominis (RA), the external oblique (EO) and the internal oblique with the transversus abdominis (IO-TA). The AM exhibited the highest activity during prone bridge on a Swiss Ball (RA, EO, IO-TA 44.7 ± 19.2, 54.7 ± 22.9, 36.8 ± 18.6 in % of MVC, respectively). The lowest activity was observed during supine bridge on a stable surface and a BOSU (under 5.0). The lowest ratio analyzed on the basis of the relation of EO and IO-TA activity to RA was obtained during prone bridge on the Swiss Ball (1.4 ± 0.7 for EO, 0.9 ± 0.5 for IO-TA). The highest ratio was obtained during prone bridge on stable surface and supine bridges. The highest level of activity in the abdominal muscles is achieved during prone bridge on a Swiss Ball. However, this exercise provided the lowest activity of the EO and IO-TA in relation to RA. It is essential to conduct further studies verifying the usefulness of using Swiss Ball during core stability training. Copyright © 2013 Elsevier Ltd. All rights reserved.

  15. Development and field testing of a rapid and ultra-stable atmospheric carbon dioxide spectrometer

    Science.gov (United States)

    Xiang, B.; Nelson, D. D.; McManus, J. B.; Zahniser, M. S.; Wehr, R. A.; Wofsy, S. C.

    2014-12-01

    We present field test results for a new spectroscopic instrument to measure atmospheric carbon dioxide (CO2) with high precision (0.02 μmol mol-1, or ppm at 1 Hz) and demonstrate high stability (within 0.1 ppm over more than 8 months), without the need for hourly, daily, or even monthly calibration against high-pressure gas cylinders. The technical novelty of this instrument (ABsolute Carbon dioxide, ABC) is the spectral null method using an internal quartz reference cell with known CO2 column density. Compared to a previously described prototype, the field instrument has better stability and benefits from more precise thermal control of the optics and more accurate pressure measurements in the sample cell (at the mTorr level). The instrument has been deployed at a long-term ecological research site (the Harvard Forest, USA), where it has measured for 8 months without on-site calibration and with minimal maintenance, showing drift bounds of less than 0.1 ppm. Field measurements agree well with those of a commercially available cavity ring-down CO2 instrument (Picarro G2301) run with a standard calibration protocol. This field test demonstrates that ABC is capable of performing high-accuracy, unattended, continuous field measurements with minimal use of reference gas cylinders.

  16. Stable isotopes in atmospheric water vapor and applications to the hydrologic cycle

    Science.gov (United States)

    Galewsky, Joseph; Steen-Larsen, Hans Christian; Field, Robert D.; Worden, John; Risi, Camille; Schneider, Matthias

    2016-12-01

    The measurement and simulation of water vapor isotopic composition has matured rapidly over the last decade, with long-term data sets and comprehensive modeling capabilities now available. Theories for water vapor isotopic composition have been developed by extending the theories that have been used for the isotopic composition of precipitation to include a more nuanced understanding of evaporation, large-scale mixing, deep convection, and kinetic fractionation. The technologies for in situ and remote sensing measurements of water vapor isotopic composition have developed especially rapidly over the last decade, with discrete water vapor sampling methods, based on mass spectroscopy, giving way to laser spectroscopic methods and satellite- and ground-based infrared absorption techniques. The simulation of water vapor isotopic composition has evolved from General Circulation Model (GCM) methods for simulating precipitation isotopic composition to sophisticated isotope-enabled microphysics schemes using higher-order moments for water and ice size distributions. The incorporation of isotopes into GCMs has enabled more detailed diagnostics of the water cycle and has led to improvements in its simulation. The combination of improved measurement and modeling of water vapor isotopic composition opens the door to new advances in our understanding of the atmospheric water cycle, in processes ranging from the marine boundary layer, through deep convection and tropospheric mixing, and into the water cycle of the stratosphere. Finally, studies of the processes governing modern water vapor isotopic composition provide an improved framework for the interpretation of paleoclimate proxy records of the hydrological cycle.

  17. Response of stable carbon isotope in epilithic mosses to atmospheric nitrogen deposition

    Energy Technology Data Exchange (ETDEWEB)

    Liu Xueyan, E-mail: liuxueyan@vip.skleg.c [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Xiao Huayun; Liu Congqiang [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Li Youyi; Xiao Hongwei; Wang Yanli [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Graduate University of Chinese Academy of Sciences, Yuquanlu, Beijing 100049 (China)

    2010-06-15

    Epilithic mosses are characterized by insulation from substratum N and hence meet their N demand only by deposited N. This study investigated tissue C, total Chl and delta{sup 13}C of epilithic mosses along 2 transects across Guiyang urban (SW China), aiming at testing their responses to N deposition. Tissue C and total Chl decreased from the urban to rural, but delta{sup 13}C{sub moss} became less negative. With measurements of atmospheric CO{sub 2} and delta{sup 13}CO{sub 2}, elevated N deposition was inferred as a primary factor for changes in moss C and isotopic signatures. Correlations between total Chl, tissue C and N signals indicated a nutritional effect on C fixation of epilithic mosses, but the response of delta{sup 13}C{sub moss} to N deposition could not be clearly differentiated from effects of other factors. Collective evidences suggest that C signals of epilithic mosses are useful proxies for N deposition but further works on physiological mechanisms are still needed. - Photosynthetic {sup 13}C discrimination of bryophytes might increase with elevated N deposition.

  18. Atmospheric and surface properties of Mars obtained by infrared spectroscopy on Mariner 9

    Science.gov (United States)

    Conrath, B.; Curran, R.; Hanel, R.; Kunde, V.; Maguire, W.; Pearl, J.; Pirraglia, J.; Welker, J.; Burke, T.

    1973-01-01

    The infrared spectroscopy experiment on Mariner 9 obtained data over much of Mars. Interpretation of the thermal emission of Mars in terms of atmospheric temperatures, wind fields and dynamics, surface temperatures, surface pressure and topography, mineral composition, and minor atmospheric constituents including isotopic ratios, as well as a search for unexpected phenomena are reported.

  19. Graphical surface-vegetation-atmosphere transfer (SVAT) model as a pedagogical and research tool

    OpenAIRE

    Gillies, Robert R.; Carlson, Toby N.; Ripley, David A.J.

    1998-01-01

    This paper considers, by example, the use of a Surface-Atmosphere-Vegetation-Transfer (SVAT), Atmospheric Boundary Layer (ABL) model designed as a pedagogical tool. The goal of the computer software and the approach is to improve the efficiency and effectiveness of communicating often complex and mathematical based disciplines (e.g., micrometeorology, land surface processes) to the non-specialist interested in studying problems involving interactions between vegetation and the atmosphere and,...

  20. Formation of stable direct current microhollow cathode discharge by venturi gas flow system for remote plasma source in atmosphere

    International Nuclear Information System (INIS)

    Park, Ki Wan; Lee, Tae Il; Hwang, Hyeon Seok; Noh, Joo Hyon; Baik, Hong Koo; Song, Kie Moon

    2008-01-01

    We introduce a microhollow cathode configuration with venturi gas flow to ambient air in order to obtain glow discharge at atmospheric pressure. Stable microhollow cathode discharge was formed in a 200 μm diameter at 9 mA and the optimum value of gas velocityxdiameter for hollow cathode effect was obtained in our system. In order to confirm hollow cathode effect, we measured the enhancement of E/N strength for 200 μm (0.31 m 2 /s) and 500 μm (0.78 m 2 /s) air discharge at 8 mA under the velocity of 156 m/s. As a result, an increase of 46.7% in E/N strength of the discharge of 200 μm hole was obtained compare to that of 500 μm

  1. A Carbon Source Apportionment Shift in Mexico City Atmospheric Particles During 2003-2004 as Determined with Stable Carbon Isotopes

    Science.gov (United States)

    Lopez-Veneroni, D. G.; Vega, E.

    2013-05-01

    The stable carbon isotope composition of atmospheric particles (PM2.5) was measured at La Merced (MER), a commercial site in the eastern sector, and at Xalostoc (XAL) an industrial site in the NE sector of Mexico City, during three sampling periods in autumn 2003, and spring and autumn 2004. At each site and sampling campaign particle samples were collected daily with minivol samplers during two week periods. Ancillary data included organic and elemental carbon, trace elements and ionic species. This data base was complement with air quality data from the RAMA (Automatic Atmospheric Monitoring Network). In general, particle concentrations, ionic species and some air quality species showed higher concentrations in autumn and lowest values in spring. Moreover, the concentrations of these chemical species were highest at XAL compared to MER. The stable carbon isotope composition of PM2.5 during autumn 2003 and spring 2004 had and average value of -26.04 (± 1.54) ‰ vs. PDB. Differences in the isotopic composition between the two sites were non significant. The average δ13C during these seasons were 1 ‰ lighter relative to data collected previously at these sites during 2000 and 2001, and is consistent with a predominant source of hydrocarbon combustion. In autumn 2004, however, average δ13C at XAL and MER increased to -22.8 (± 0.9) and -20.6 (± 3.1) ‰, respectively. Organic carbon concentrations during this period increased concomitantly at these sites. The shift in the isotopic composition in ambient particles suggests a predominance of soil-derived carbon during this period. The possible causes and implications of this are discussed.

  2. Surface modification of polylactic acid films by atmospheric pressure plasma treatment

    Science.gov (United States)

    Kudryavtseva, V. L.; Zhuravlev, M. V.; Tverdokhlebov, S. I.

    2017-09-01

    A new approach for the modification of polylactic acid (PLA) materials using atmospheric pressure plasma (APP) is described. PLA films plasma exposure time was 20, 60, 120 s. The surface morphology and wettability of the obtained PLA films were investigated by atomic force microscopy (AFM) and the sitting drop method. The atmospheric pressure plasma increased the roughness and surface energy of PLA film. The wettability of PLA has been improved with the application of an atmospheric plasma surface treatment. It was shown that it is possible to obtain PLA films with various surface relief and tunable wettability. Additionally, we demonstrated that the use of cold atmospheric pressure plasma for surface activation allows for the immobilization of bioactive compounds like hyaluronic acid (HA) on the surface of obtained films. It was shown that composite PLA-HA films have an increased long-term hydrophilicity of the films surface.

  3. Stable Titania Nanostructures on Stainless Steel Coronary Stent Surface for Enhanced Corrosion Resistance and Endothelialization.

    Science.gov (United States)

    Mohan, Chandini C; Cherian, Aleena Mary; Kurup, Sujish; Joseph, John; Nair, Manitha B; Vijayakumar, Maniyal; Nair, Shantikumar V; Menon, Deepthy

    2017-06-01

    Stainless steel (SS) coronary stents continue to present risk of in-stent restenosis that impact its long term safety and efficacy. The present work focuses on developing a drug-free and polymer-less surface on coronary stents by utilizing a titania (TiO 2 ) nanotexturing approach through hydrothermal processing, that will offer improved stent performance in vivo. Mechanically stable and durable nanotextured coatings are obtained on SS stents that also offer good corrosion resistance. In vitro vascular cell (endothelial and smooth muscle cells) studies on surface modified SS show preferential rapid endothelialization with enhanced nitric oxide production and reduce smooth muscle cell proliferation, in comparison to unmodified SS. In vivo evaluation of the nanotextured stents after subcutaneous implantation in rabbits show reduced irritability and minimal localized inflammatory response. These beneficial effects suggest that the stable, easily scalable titania nanosurface modification strategy on coronary stent surfaces can be a much cheaper alternative to drug eluting stents in addressing in-stent restenosis. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Assessing the Impact of Sublimation on the Stable Water Isotope Signal of Surface Ice

    Science.gov (United States)

    Dennis, D. P.; Ehrenfeucht, S.; Marchant, D. R.

    2017-12-01

    Sublimation is often a significant, if not the dominant, mechanism for ablation in polar and high elevation glacial systems. Previous field studies on firn and ice have suggested that sublimation can enrich the stable water isotope (δD and δ18O) signatures of these exposed materials. Several additional studies have attempted to replicate this effect through laboratory experiments. However, neither the magnitude of alteration caused by sublimation nor the maximum depth at which ice is affected are well-constrained. The effect of sublimation-induced alteration on the original meteoric signal relative to other post-depositional processes is additionally unknown. Here, we present the results of an experimental study on the effect of sublimation on stable water isotope ratios in surface ice. Using high-resolution data, we attempt to assess the suitability of δD and δ18O in near-surface and exposed ice for use as paleoclimate proxies. This type of analysis is particularly useful for future studies of ice from hyper-arid polar regions like the Antarctic McMurdo Dry Valleys, and may be extended to icy planetary bodies, including surface ice on Mars.

  5. Airborne Spectral Measurements of Surface-Atmosphere Anisotropy for Several Surfaces and Ecosystem over Southern Africa

    Science.gov (United States)

    Gatebe, C. K.; King, M. D.; Tsay, S.; Arnold, G. T.; Li, J. Y.

    2001-12-01

    The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft and took measurements on 23 flights between August 15 and September 16. On 12 of those flights, BRF measurements were obtained over different natural surfaces and ecosystem in southern Africa. The BRF measurements were done to characterize surface anisotropy in support of SAFARI 2000 science objectives principally to validate products from NASA's EOS satellites, and to parameterize and validate BRF models. In this paper we present results of BRFs taken over two EOS validation sites: Skukuza tower, South Africa (25.0 oS, 31.5 oE) and Mongu tower, Zambia (15.4 oS, 23.3 oE). Additional sites are also considered and include, Maun tower, Botswana (20.0 oS, 23.5 oE), Sowa Pan, Botswana (20.6 oS, 26.2 oE) and Etosha Pan, Namibia (19.0 oS, 16.0 oE). The CAR is capable of measuring scattered light in fourteen spectral bands. The scan mirror, rotating at 100 rpm, directs the light into a Dall-Kirkham telescope where the beam is split into nine paths. Eight light beams pass through beam splitters, dichroics, and lenses to individual detectors (0.34-1.27 μ m), and finally are registered by eight data channels. They are sampled simultaneously and continuously. The ninth beam passes through a spinning filter wheel to an InSb detector cooled by a Stirling cycle cooler. Signals registered by the ninth data channel are selected from among six spectral channels (1.55-2.30 μ m). The filter wheel can either cycle through all six spectral bands at a prescribed interval (usually changing filter every fifth scan line), or lock onto any one of the six spectral bands and sample it continuously. To measure the BRF of the surface-atmosphere system, the University of Washington CV-580 had to bank at a comfortable roll angle of ~20 o and fly in a circle about 3 km in diameter above the surface for roughly two minutes. Replicated observations (multiple circular orbits) were

  6. Surface oceanographic fronts influencing deep-sea biological activity: Using fish stable isotopes as ecological tracers

    Science.gov (United States)

    Louzao, Maite; Navarro, Joan; Delgado-Huertas, Antonio; de Sola, Luis Gil; Forero, Manuela G.

    2017-06-01

    Ecotones can be described as transition zones between neighbouring ecological systems that can be shaped by environmental gradients over a range of space and time scales. In the marine environment, the detection of ecotones is complex given the highly dynamic nature of marine systems and the paucity of empirical data over ocean-basin scales. One approach to overcome these limitations is to use stable isotopes from animal tissues since they can track spatial oceanographic variability across marine systems and, in turn, can be used as ecological tracers. Here, we analysed stable isotopes of deep-sea fishes to assess the presence of ecological discontinuities across the western Mediterranean. We were specifically interested in exploring the connection between deep-sea biological activity and particular oceanographic features (i.e., surface fronts) occurring in the pelagic domain. We collected samples for three different abundant deep-sea species in May 2004 from an experimental oceanographic trawling cruise (MEDITS): the Mictophydae jewel lanternfish Lampanyctus crocodilus and two species of the Gadidae family, the silvery pout Gadiculus argenteus and the blue whiting Micromesistius poutassou. The experimental survey occurred along the Iberian continental shelf and the upper and middle slopes, from the Strait of Gibraltar in the SW to the Cape Creus in the NE. The three deep-sea species were highly abundant throughout the study area and they showed geographic variation in their isotopic values, with decreasing values from north to south disrupted by an important change point around the Vera Gulf. Isotopic latitudinal gradients were explained by pelagic oceanographic conditions along the study area and confirm the existence of an ecotone at the Vera Gulf. This area could be considered as an oceanographic boundary where waters of Atlantic origin meet Mediterranean surface waters forming important frontal structures such as the Almeria-Oran front. In fact, our results

  7. Hydrophobic and Metallophobic Surfaces: Highly Stable Non-wetting Inorganic Surfaces Based on Lanthanum Phosphate Nanorods.

    Science.gov (United States)

    Sankar, Sasidharan; Nair, Balagopal N; Suzuki, Takehiro; Anilkumar, Gopinathan M; Padmanabhan, Moothetty; Hareesh, Unnikrishnan Nair S; Warrier, Krishna G

    2016-03-09

    Metal oxides, in general, are known to exhibit significant wettability towards water molecules because of the high feasibility of synergetic hydrogen-bonding interactions possible at the solid-water interface. Here we show that the nano sized phosphates of rare earth materials (Rare Earth Phosphates, REPs), LaPO4 in particular, exhibit without any chemical modification, unique combination of intrinsic properties including remarkable hydrophobicity that could be retained even after exposure to extreme temperatures and harsh hydrothermal conditions. Transparent nanocoatings of LaPO4 as well as mixture of other REPs on glass surfaces are shown to display notable hydrophobicity with water contact angle (WCA) value of 120° while sintered and polished monoliths manifested WCA greater than 105°. Significantly, these materials in the form of coatings and monoliths also exhibit complete non-wettability and inertness towards molten metals like Ag, Zn, and Al well above their melting points. These properties, coupled with their excellent chemical and thermal stability, ease of processing, machinability and their versatile photo-physical and emission properties, render LaPO4 and other REP ceramics utility in diverse applications.

  8. Polyaniline hybridized surface defective ZnO nanorods with long-term stable photoelectrochemical activity

    International Nuclear Information System (INIS)

    Bera, Susanta; Khan, Hasmat; Biswas, Indranil; Jana, Sunirmal

    2016-01-01

    Highlights: • Polyaniline (PANI) hybridized ZnO nanorods was synthesized by solution method. • Surface defects were found in the nanorods. • The hybrid material exhibited an enhancement in visible light absorption. • A long-term stable photoelectrochemical activity of the material was found. • Advancement in the properties would be PANI hybridization and surface defects. - Abstract: We report surfactant/template free precursor solution based synthesis of polyaniline (PANI) hybridized surface defective ZnO nanorods by a two-step process. Initially, ZnO nanorods have been prepared at 95 °C, followed by hybridization (coating) of PANI onto the ZnO via in situ polymerization of aniline monomer, forming ZnO-PANI nanohybrid (ZP). The structural properties of ZP have been analyzed by X-ray diffraction (XRD) and transmission electron microscopic (TEM) studies. The presence of surface defects especially the oxygen vacancies in ZnO has been characterized by photoluminescence emission, high resolution TEM, X-ray photoelectron spectroscopy (XPS) and micro-Raman spectral measurements. The chemical interaction of PANI with ZnO has been examined by Fourier transform infrared (FTIR) and XPS analyses. A significant enhancement in visible absorption of ZP sample is found as evidenced from UV–vis diffused reflectance spectral study. BET nitrogen adsorption-desorption isotherm shows an improved textural property (pore size, pore volume) of ZP. Moreover, a long-term stable photoelectrochemical activity (PEC) of ZP is found compare to pristine ZnO. The synergic effect of PANI hybridization and the presence of surface defects in ZnO NRs can enhance the PEC by prolonging the recombination rate of photogenerated charge carriers. The effect can also provide large number of active sites to make electrolyte diffusion and mass transportation easier in the nanohybrid. This simple synthesis strategy can be adopted for PANI hybridization with different metal oxide semiconductors

  9. Polyaniline hybridized surface defective ZnO nanorods with long-term stable photoelectrochemical activity

    Energy Technology Data Exchange (ETDEWEB)

    Bera, Susanta; Khan, Hasmat [Sol-Gel Division, CSIR-Central Glass and Ceramic Research Institute (CSIR-CGCRI), 196 Raja S.C. Mullick Road, P.O. Jadavpur University, Kolkata 700 032, West Bengal (India); Biswas, Indranil [Materials Characterization and Instrumentation Division, CSIR-Central Glass and Ceramic Research Institute (CSIR-CGCRI), 196 Raja S.C. Mullick Road, P.O. Jadavpur University, Kolkata 700 032, West Bengal (India); Jana, Sunirmal, E-mail: sjana@cgcri.res.in [Sol-Gel Division, CSIR-Central Glass and Ceramic Research Institute (CSIR-CGCRI), 196 Raja S.C. Mullick Road, P.O. Jadavpur University, Kolkata 700 032, West Bengal (India)

    2016-10-15

    Highlights: • Polyaniline (PANI) hybridized ZnO nanorods was synthesized by solution method. • Surface defects were found in the nanorods. • The hybrid material exhibited an enhancement in visible light absorption. • A long-term stable photoelectrochemical activity of the material was found. • Advancement in the properties would be PANI hybridization and surface defects. - Abstract: We report surfactant/template free precursor solution based synthesis of polyaniline (PANI) hybridized surface defective ZnO nanorods by a two-step process. Initially, ZnO nanorods have been prepared at 95 °C, followed by hybridization (coating) of PANI onto the ZnO via in situ polymerization of aniline monomer, forming ZnO-PANI nanohybrid (ZP). The structural properties of ZP have been analyzed by X-ray diffraction (XRD) and transmission electron microscopic (TEM) studies. The presence of surface defects especially the oxygen vacancies in ZnO has been characterized by photoluminescence emission, high resolution TEM, X-ray photoelectron spectroscopy (XPS) and micro-Raman spectral measurements. The chemical interaction of PANI with ZnO has been examined by Fourier transform infrared (FTIR) and XPS analyses. A significant enhancement in visible absorption of ZP sample is found as evidenced from UV–vis diffused reflectance spectral study. BET nitrogen adsorption-desorption isotherm shows an improved textural property (pore size, pore volume) of ZP. Moreover, a long-term stable photoelectrochemical activity (PEC) of ZP is found compare to pristine ZnO. The synergic effect of PANI hybridization and the presence of surface defects in ZnO NRs can enhance the PEC by prolonging the recombination rate of photogenerated charge carriers. The effect can also provide large number of active sites to make electrolyte diffusion and mass transportation easier in the nanohybrid. This simple synthesis strategy can be adopted for PANI hybridization with different metal oxide semiconductors

  10. Investigation of Atmospheric Pressure Plasma Discharge and Its Application to Surface Modification of Blood-Filtering Material

    Science.gov (United States)

    Tang, Xiaoliang; Feng, Xianping; Qiu, Gao; Yan, Yonghui; Shi, Yuncheng

    2004-10-01

    Melt-blown polybutylene terephthalate (PBT) nonwoven materials treated by using plasma is regarded as one of the excellent materials to filter white blood cells (WBC) from blood. In this paper, dielectric barrier discharge (DBD) plasma source at an improved quasi-stable atmospheric pressure is achieved when discharge voltage, discharge current, and gap between the electrodes are carefully controlled. This plasma source has been used to modify the surface of PBT melt-blown nonwoven materials. Experimental results indicate that both the wettability and permeation of treated PBT melt-blown nonwoven materials are greatly improved.

  11. Investigation of atmospheric pressure plasma discharge and its application to surface modification of blood-filtering material

    International Nuclear Information System (INIS)

    Tang Xiaoliang; Qiu Gao; Yan Yonghui; Shi Yuncheng

    2004-01-01

    Melt-blown polybutylene terephthalate (PBT) nonwoven materials treated by using plasma is regarded as one of the excellent materials to filter white blood cells (WBC) from blood. In this paper, dielectric barrier discharge (DBD) plasma source at an improved quasi-stable atmospheric pressure is achieved when discharge voltage, discharge current, and gap between the electrodes are carefully controlled. This plasma source has been used to modify the surface of PBT melt-blown nonwoven materials. Experimental results indicate that both the wettability and permeation of treated PBT melt-blown nonwoven materials are greatly improved. (authors)

  12. Investigation of Titan's surface and atmosphere photometric functions using the Cassini/VIMS instrument

    Science.gov (United States)

    Cornet, Thomas; Altobelli, Nicolas; Rodriguez, Sébastien; Maltagliati, Luca; Le Mouélic, Stéphane; Sotin, Christophe; Brown, Robert; Barnes, Jason; Buratti, Bonnie; Baines, Kevin; Clark, Roger; Nicholson, Phillip

    2015-04-01

    After 106 flybys spread over 10 years, the Cassini Visual and Infrared Mapping Spectrometer (VIMS) instrument acquired 33151 hyperspectral cubes pointing at the surface of Titan on the dayside. Despite this huge amount of data available for surface studies, and due to the strong influence of the atmosphere (methane absorption and haze scattering), Titan's surface is only visible with VIMS in 7 spectral atmospheric windows centred at 0.93, 1.08, 1.27, 1.59, 2.01, 2.7-2.8 and 5 microns. Atmospheric scattering and absorption effects dominate Titan's spectrum at wavelengths shorter than 3 microns, while the 5 micron window, almost insensitive to the haze scattering, only presents a reduced atmospheric absorption contribution to the signal recorded by VIMS. In all cases, the recorded I/F represents an apparent albedo, which depends on the atmospheric contributions and the surface photometry at each wavelength. We therefore aim to determine real albedo values for Titan's surface by finding photometric functions for the surface and the atmosphere that could be used as a basis for empirical corrections or Radiative Transfer calculations. After updating the navigation of the VIMS archive, we decomposed the entire VIMS data set into a MySQL relational database gathering the viewing geometry, location, time (season) and I/F (for pure atmosphere and surface-atmosphere images) for each pixel of the 33151 individual VIMS cubes. We then isolated all the VIMS pixels where Titan's surface has been repeatedly imaged at low phase angles (< 20 degrees) in order to characterize phase curves for the surface at 5 microns and for the atmosphere. Among these, the T88 flyby appears noteworthy, with a "Emergence-Phase Function (EPF)"-type observation: 25 cubes acquired during the same flyby, over the same area (close to Tortola Facula, in relatively dark terrains), at a constant incidence and with varying emergence and phase (from 0 to 60 degrees) angles. The data clearly exhibit an increase

  13. Surface conductivity dependent dynamic behaviour of an ultrafine atmospheric pressure plasma jet for microscale surface processing

    Energy Technology Data Exchange (ETDEWEB)

    Abuzairi, Tomy [Graduate School of Science and Technology, Shizuoka University, Hamamatsu 432-8561 (Japan); Department of Electrical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424 (Indonesia); Okada, Mitsuru [Department of Engineering, Shizuoka University, Hamamatsu 432-8561 (Japan); Bhattacharjee, Sudeep [Department of Physics, Indian Institute of Technology, Kanpur 208016 (India); Nagatsu, Masaaki, E-mail: nagatsu.masaaki@shizuoka.ac.jp [Graduate School of Science and Technology, Shizuoka University, Hamamatsu 432-8561 (Japan); Department of Engineering, Shizuoka University, Hamamatsu 432-8561 (Japan); Research Institute of Electronics, Shizuoka University, Hamamatsu 432-8561 (Japan)

    2016-12-30

    Highlights: • Spatio-temporal behaviors of capillary APPJs are studied for various substrates. • Plasma irradiation area depended on the substrate conductivity and permittivity. • Surface irradiation area was significantly broadened in polymer-like substrate. • Effect of applying a substrate bias on the APPJ irradiation area was investigated. - Abstract: An experimental study on the dynamic behaviour of microcapillary atmospheric pressure plasma jets (APPJs) with 5 μm tip size for surfaces of different conductivity is reported. Electrical and spatio-temporal characteristics of the APPJs are monitored using high voltage probe, current monitor and high speed intensified charge couple device camera. From these experimental results, we presented a simple model to understand the electrical discharge characteristics of the capillary APPJs with double electrodes, and estimated the velocity of the ionization fronts in the jet and the electron density to be 3.5–4.2 km/s and 2–7 × 10{sup 17} m{sup −3}. By analyzing the dynamics of the microcapillary APPJs for different substrate materials, it was found that the surface irradiation area strongly depended on the substrate conductivity and permittivity, especially in the case of polymer-like substrate, surface irradiation area was significantly broadened probably due to the repelling behaviour of the plasma jets from the accumulated electrical charges on the polymer surface. The effect of applying a substrate bias in the range from −900 V to +900 V on the plasma irradiation onto the substrates was also investigated. From the knowledge of the present results, it is helpful for choosing the substrate materials for microscale surface modification.

  14. Atmospheric-pressure plasma activation and surface characterization on polyethylene membrane separator

    Science.gov (United States)

    Tseng, Yu-Chien; Li, Hsiao-Ling; Huang, Chun

    2017-01-01

    The surface hydrophilic activation of a polyethylene membrane separator was achieved using an atmospheric-pressure plasma jet. The surface of the atmospheric-pressure-plasma-treated membrane separator was found to be highly hydrophilic realized by adjusting the plasma power input. The variations in membrane separator chemical structure were confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. Chemical analysis showed newly formed carbonyl-containing groups and high surface concentrations of oxygen-containing species on the atmospheric-pressure-plasma-treated polymeric separator surface. It also showed that surface hydrophilicity primarily increased from the polar component after atmospheric-pressure plasma treatment. The surface and pore structures of the polyethylene membrane separator were examined by scanning electron microscopy, revealing a slight alteration in the pore structure. As a result of the incorporation of polar functionalities by atmospheric-pressure plasma activation, the electrolyte uptake and electrochemical impedance of the atmospheric-pressure-plasma-treated membrane separator improved. The investigational results show that the separator surface can be controlled by atmospheric-pressure plasma surface treatment to tailor the hydrophilicity and enhance the electrochemical performance of lithium ion batteries.

  15. High-performance heterogeneous catalysis with surface-exposed stable metal nanoparticles.

    Science.gov (United States)

    Huang, Ning; Xu, Yanhong; Jiang, Donglin

    2014-11-27

    Protection of metal nanoparticles from agglomeration is critical for their functions and applications. The conventional method for enhancing their stability is to cover them with passivation layers to prevent direct contact. However, the presence of a protective shell blocks exposure of the metal species to reactants, thereby significantly impeding the nanoparticles' utility as catalysts. Here, we report that metal nanoparticles can be prepared and used in a surface-exposed state that renders them inherently catalytically active. This strategy is realised by spatial confinement and electronic stabilisation with a dual-module mesoporous and microporous three-dimensional π-network in which surface-exposed nanoparticles are crystallised upon in situ reduction. The uncovered palladium nanoparticles serve as heterogeneous catalysts that are exceptionally active in water, catalyse unreactive aryl chlorides for straightforward carbon-carbon bond formation and are stable for repeated use in various types of cross couplings. Therefore, our results open new perspectives in developing practical heterogeneous catalysts.

  16. Electrostatic powder spraying process for the fabrication of stable superhydrophobic surfaces

    Science.gov (United States)

    Gu, Guotuan; Tian, Yuping; Li, Zhantie; Lu, Dongfang

    2011-03-01

    Nano-sized Al2O3 particles were modified by heptadecafluorodecyl trimethoxysilane and 2,3-epoxy propoxy propyl trimethoxysilicane to make it both hydrophobic and reactive. The reactive nano-particles were mixed with polyester resin containing curing agents and electrostatic sprayed on stainless steel substrates to obtain stable superhydrophobic coatings after curing. The water contact angle (WCA) on the hybrid coating is influenced by the content of Al2O3 particles in the coating. As the Al2O3 concentration in the coating was increased from 0% to 8%, WCA increased from 68° to 165°. Surface topography of the coatings was examined using scanning electron microscopy (SEM). Nano-particles covered on the coating surface formed continuous film with greatly enhanced roughness, which was found to be responsible for the superhydrophobicity. The method is simple and cost effective and can be used for preparing self-cleaning superhydrophobic coating on large areas.

  17. Geologic investigations of Australian earthquakes: Paleoseismicity and the recurrence of surface faulting in the stable regions of continents

    Science.gov (United States)

    Machette, Michael; Crone, Anthony

    1993-01-01

    Earthquakes that occur in the stable regions of continents are very rare compared to those that occur along plate margins, such as the San Andreas fault system of western California. Worldwide, only 11 historic earthquakes in stable continental regions are known to have produced surface ruptures. Five of these have occurred in Australia since 1968 (see map, next page).

  18. DC superimposed AC high voltage: A new strategy for transferring stable He atmospheric pressure cold plasma bullets through long dielectric tubes

    Science.gov (United States)

    Siadati, S. N.; Sohbatzadeh, F.; Valinataj Omran, Azadeh

    2017-06-01

    This study developed a stable transfer of He atmospheric pressure cold plasma bullets in a large dielectric tube with a length of 70 cm and an inner diameter of 0.4-1.6 cm. DC superimposed AC voltage was used for this purpose. The DC component of the applied voltage generated corona ionization through the tube, which helped in the ignition and transfer of the plasma as a pre-ionization background. The bullets followed the frequency of the AC component; therefore, very high applied energy was not required to ignite this large-scale plasma. To our knowledge, this is the first time such a complex waveform has been reported for the transfer of a plasma bullet. The characteristics of the transferring plasma bullet, such as the power, charge, propagation speed, resistance, AC electrical field (EF) of the plasma, and electrostatic field on the tube surface, were measured. The influence of the tube diameter on these characteristics was investigated. The results showed that the power applied, charge, and power deposited on the target increased as the tube diameter increased. Less plasma resistance and radiation were observed using larger diameters. The root mean square (RMS) values of the axial AC EF of the bullet along the jet axis were higher for the larger diameters, but no special relation between the propagation speed, radial AC EF, and static surface field and tube diameter was observed.

  19. A stable isotope record of late Cenozoic surface uplift of southern Alaska

    Science.gov (United States)

    Bill, Nicholas S.; Mix, Hari T.; Clark, Peter U.; Reilly, Sean P.; Jensen, Britta J. L.; Benowitz, Jeffrey A.

    2018-01-01

    Although the timing of an acceleration in late-Cenozoic exhumation of southern Alaska is reasonably well constrained as beginning ∼5-∼6 Ma, the surface uplift history of this region remains poorly understood. To assess the extent of surface uplift relative to rapid exhumation, we developed a stable isotope record using the hydrogen isotope composition (δD) of paleo-meteoric water over the last ∼7 Ma from interior basins of Alaska and Yukon Territory. Our record, which is derived from authigenic clays (δDclay) in silicic tephras, documents a ∼50-60‰ increase in δD values from the late Miocene (∼6-∼7 Ma) through the Plio-Pleistocene transition (∼2-∼3 Ma), followed by near-constant values over at least the last ∼2 Ma. Although this enrichment trend is opposite that of a Rayleigh distillation model typically associated with surface uplift, we suggest that it is consistent with indirect effects of surface uplift on interior Alaska, including changes in aridity, moisture source, and seasonality of moisture. We conclude that the δDclay record documents the creation of a topographic barrier and the associated changes to the climate of interior Alaska and Yukon Territory.

  20. Characteristics of the surface source of radioactive atmospheric aerosols in the 30km Chernobyl zone

    International Nuclear Information System (INIS)

    Garger, E.; Gurgula, B.; Kashpur, V.; Kostezh, A.

    1993-01-01

    Territory contaminated by radionuclides around Chernobyl Nuclear Power Plant is the surface source of radioactive atmospheric aerosols due to the natural wind resuspension and ''technogenic'' activity. The present work is devoted to characterizing this source. Measurements of the spacial distribution of soil contamination, atmospheric dry deposition, volume concentration of radioactive aerosols and their variability in space and time, distribution of the radioactivity according to the size of aerosol particles, and size distribution of ''hot'' particles in the surface layer of the atmosphere were taken and the power of the surface source of the radioactivity aerosol was estimated. (author)

  1. Evolving research directions in Surface Ocean-Lower Atmosphere (SOLAS) science

    OpenAIRE

    Law, CS; Brévière, E; De Leeuw, G; Garçon, V; Guieu, C; Kieber, DJ; Kontradowitz, S; Paulmier, A; Quinn, PK; Saltzman, ES; Stefels, J; Von Glasow, R

    2013-01-01

    This review focuses on critical issues in ocean-atmosphere exchange that will be addressed by new research strategies developed by the international Surface Ocean-Lower Atmosphere Study (SOLAS) research community. Eastern boundary upwelling systems are important sites for CO 2 and trace gas emission to the atmosphere, and the proposed research will examine how heterotrophic processes in the underlying oxygen-deficient waters interact with the climate system. The second regional research focu...

  2. SAFARI 2000 Surface Atmospheric Radiative Transfer (SMART), Dry Season 2000

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: Surface-sensing Measurements for Radiative Transfer (SMART) and Chemical, Optical, and Microphysical Measurements of In-situ Troposphere (COMMIT) consist...

  3. Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling

    Directory of Open Access Journals (Sweden)

    J. M. F. Martins

    2009-11-01

    Full Text Available The nitrogen (δ15N and triple oxygen (δ17O and δ18O isotopic composition of nitrate (NO3 was measured year-round in the atmosphere and snow pits at Dome C, Antarctica (DC, 75.1° S, 123.3° E, and in surface snow on a transect between DC and the coast. Comparison to the isotopic signal in atmospheric NO3 shows that snow NO3 is significantly enriched in δ15N by >200‰ and depleted in δ18O by <40‰. Post-depositional fractionation in Δ17O(NO3 is small, potentially allowing reconstruction of past shifts in tropospheric oxidation pathways from ice cores. Assuming a Rayleigh-type process we find fractionation constants ε of −60±15‰, 8±2‰ and 1±1‰, for δ15N, δ18O and Δ17O, respectively. A photolysis model yields an upper limit for the photolytic fractionation constant 15ε of δ15N, consistent with lab and field measurements, and demonstrates a high sensitivity of 15ε to the incident actinic flux spectrum. The photolytic 15ε is process-specific and therefore applies to any snow covered location. Previously published 15ε values are not representative for conditions at the Earth surface, but apply only to the UV lamp used in the reported experiment (Blunier et al., 2005; Jacobi et al., 2006. Depletion of oxygen stable isotopes is attributed to photolysis followed by isotopic exchange with water and hydroxyl radicals. Conversely, 15N enrichment of the NO3 fraction in the snow implies 15N depletion of emissions. Indeed, δ15N in atmospheric NO3 shows a strong decrease from background levels (4±7‰ to −35‰ in spring followed by recovery during summer, consistent with significant snowpack

  4. Evaluation of gas emission from closed mines surface to atmosphere

    OpenAIRE

    Pokryszka, Zbigniew; Tauziède, Christian

    2000-01-01

    International audience; The closed mines are likely to release into atmosphere polluting or/and dangerous gases. The detection and hazard evaluation of those emissions are a complex problem. In order to quantify and qualify these gas emissions and check gas migrations special measuring methods are required. The research done at INERIS resulted in a reliable and appropriate methodology using a flux chamber. This methodology is intended for detecting, quantifying and qualifying gas discharges, ...

  5. Investigations of radioactive contamination of 'underlying surface - atmosphere' system

    International Nuclear Information System (INIS)

    Osintsev, A.Yu.; Panin, M.S.; Artem'ev, O.I.; Gaziev, Ya.I.

    2008-01-01

    In article the results of carried out field investigations of radionuclide compositions and dispersed characteristics of anthropogenic dust lifting products and organized on radioactive 'spot' on the Semipalatinsk Test Site fires are presented. Investigations were made for the purpose of parameters refinement and improvement of physico-mathematical models of air environmental pollution with aerosuspensions and aerosols from different sources them intensive entrance in the atmosphere

  6. Cosmic rays intensity and atmosphere humidity at near earth surface

    Science.gov (United States)

    Oskomov, V. V.; Sedov, A. N.; Saduyev, N. O.; Kalikulov, O. A.; Naurzbayeva, A. Zh; Alimgazinova, N. Sh; Kenzhina, I. E.

    2016-08-01

    Experimental studies of estimation the mutual influence of humidity and flux of cosmic rays in first approximation were carried out. Normalized cross-correlation function of time series of neutron monitors count rate and level of relative atmosphere humidity near cosmic rays registration point is studied. Corrected and uncorrected on pressure minute and hour data of 6NM64 neutron monitor count rate were used for the study. Neutron monitor is located in Al-Farabi Kazakh National University, at an altitude of 850 m above sea level. Also, data from NM64 neutron monitor of Tien Shan mountain research station of Institute of Ionosphere, located at an altitude of 3340 m above sea level were used. Uncorrected on pressure cosmic rays intensity better reflects the changes in relative atmosphere humidity. Average and sometimes strong relationship is often observed by time changes of atmosphere humidity near the point of cosmic rays detection and their intensity: the value of normalized cross-correlation function of respective signals, even in case of their long duration and a large number of data (eg, for minute changes at intervals of up to several months) covers 0.5 - 0.75 range, sometimes falling to ∼⃒ 0.4.

  7. Dissolved inorganic carbon and stable carbon isotopic evolution of neutral mine drainage interacting with atmospheric CO2(g).

    Science.gov (United States)

    Abongwa, Pride Tamasang; Atekwana, Eliot Anong; Puckette, James

    2016-03-01

    We investigated the spatial variations in the concentrations of dissolved inorganic carbon (DIC), the stable carbon isotopic composition (δ(13)C) of DIC and the δ(13)C of carbonate precipitated from neutral mine drainage interacting with the atmospheric CO2(g). We assessed the chemical, DIC and δ(13)CDIC evolution of the mine drainage and the δ(13)C evolution of carbonate precipitates for a distance of 562 m from the end of an 8 km tunnel that drains a mine. Our results show that as the mine drainage interacts with atmospheric CO2(g) the outgassing of CO2 due to the high initial partial pressure of CO2 (pCO2) causes the DIC to evolve under kinetic conditions followed by equilibration and then under equilibrium conditions. The carbonate evolution was characterized by spatial increases in pH, decreasing concentrations of Ca(2+) and DIC and by the precipitation of carbonate. The δ(13)CDIC showed a larger enrichment from the tunnel exit to 38 m, moderate continuous enrichment to 318 m and almost no enrichment to 562 m. On the other hand, the δ(13)C of the carbonate precipitates also showed large enrichment from the tunnel exit to 38 m, moderate enrichment to 318 m after which the δ(13)C remained nearly constant. The enrichment in the δ(13)C of the DIC and the carbonate precipitates from 0 to 38 m from kinetic fractionation caused by CO2(g) outgassing was followed by a mix of kinetic fractionation and equilibrium fractionation controlled by carbon exchange between DIC and atmospheric CO2(g) to 318 m and then by equilibrium fractionation from 318 to 562 m. From the carbonate evolution in this neutral mine drainage, we estimated that 20% of the carbon was lost via CO2 outgassing, 12% was sequestered in sediments in the drainage ponds from calcite precipitation and the remainder 68% was exported to the local stream. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. Tracing the Sources of Atmospheric Phosphorus Deposition to a Tropical Rain Forest in Panama Using Stable Oxygen Isotopes.

    Science.gov (United States)

    Gross, A; Turner, B L; Goren, T; Berry, A; Angert, A

    2016-02-02

    Atmospheric dust deposition can be a significant source of phosphorus (P) in some tropical forests, so information on the origins and solubility of atmospheric P is needed to understand and predict patterns of forest productivity under future climate scenarios. We characterized atmospheric dust P across a seasonal cycle in a tropical lowland rain forest on Barro Colorado Nature Monument (BCNM), Republic of Panama. We traced P sources by combining remote sensing imagery with the first measurements of stable oxygen isotopes in soluble inorganic phosphate (δ(18)OP) in dust. In addition, we measured soluble inorganic and organic P concentrations in fine (1 μm) aerosol fractions and used this data to estimate the contribution of P inputs from dust deposition to the forest P budget. Aerosol dry mass was greater in the dry season (December to April, 5.6-15.7 μg m(-3)) than the wet season (May to November, 3.1-7.1 μg m(-3)). In contrast, soluble P concentrations in the aerosols were lower in the dry season (980-1880 μg P g(-1)) than the wet season (1170-3380 μg P g(-1)). The δ(18)OP of dry-season aerosols resembled that of nearby forest soils (∼19.5‰), suggesting a local origin. In the wet season, when the Trans-Atlantic Saharan dust belt moves north close to Panama, the δ(18)OP of aerosols was considerably lower (∼15.5‰), suggesting a significant contribution of long-distance dust P transport. Using satellite retrieved aerosol optical depth (AOD) and the P concentrations in aerosols we sampled in periods when Saharan dust was evident we estimate that the monthly P input from long distance dust transport during the period with highest Saharan dust deposition is 88 ± 31 g P ha(-1) month(-1), equivalent to between 10 and 29% of the P in monthly litter fall in nearby forests. These findings have important implications for our understanding of modern nutrient budgets and the productivity of tropical forests in the region under future climate scenarios.

  9. Comparison of weak-wind characteristics across different Surface Types in stable stratification

    Science.gov (United States)

    Freundorfer, Anita; Rehberg, Ingo; Thomas, Christoph

    2017-04-01

    Atmospheric transport in weak winds and very stable conditions is often characterized by phenomena collectively referred to as submeso motions since their time and spatial scales exceed those of turbulence, but are smaller than synoptic motions. Evidence is mounting that submeso motions invalidate models for turbulent dispersion and diffusion since their physics are not captured by current similarity theories. Typical phenomena in the weak-wind stable boundary layer include meandering motions, quasi two-dimensional pancake-vortices or wavelike motions. These motions may be subject to non-local forcing and sensitive to small topographic undulations. The invalidity of Taylor's hypothesis of frozen turbulence for submeso motions requires the use of sensor networks to provide observations in both time and space domains simultaneously. We present the results from the series of Advanced Resolution Canopy Flow Observations (ARCFLO) experiments using a sensor network consisting of 12 sonic anemometers and 12 thermohygrometers. The objective of ARCFLO was to observe the flow and the turbulent and submeso transport at a high spatial and temporal resolution at 4 different sites in the Pacific Northwest, USA. These sites represented a variable degree of terrain complexity (flat to mountainous) and vegetation architecture (grass to forest, open to dense). In our study, a distinct weak-wind regime was identified for each site using the threshold velocity at which the friction velocity becomes dependent upon the mean horizontal wind speed. Here we used the scalar mean of the wind speed because the friction velocity showed a clearer dependence on the scalar mean compared to the vector mean of the wind velocity. It was found that the critical speed for the weak wind regime is higher in denser vegetation. For an open agricultural area (Botany and Plant Pathology Farm) we found a critical wind speed of v_crit= (0.24±0.05) ms-1 while for a very dense forest (Mary's River Douglas Fir

  10. Geo-ecology of surface atmosphere of Tomsk and methodology for the ecological risk calculation

    Science.gov (United States)

    Ivanova, E. V.; Anisimov, M. V.; Kuznetsova, U. N.; Taldonova, N. V.; Petrova, A. V.

    2018-01-01

    The present study presents new methodological approach of environmental assessment of surface atmosphere layer based on principles of non equilibrium dynamics. The role of natural and technogenic factors in forming areas of dust and airborne pollution is determined. The results of the study of ecological risk from atmosphere chemical pollution of the town are presented.

  11. Evolving research directions in Surface Ocean-Lower Atmosphere (SOLAS) science

    NARCIS (Netherlands)

    Law, Cliff S.; Breviere, Emilie; de Leeuw, Gerrit; Garcon, Veronique; Guieu, Cecile; Kieber, David J.; Kontradowitz, Stefan; Paulmier, Aurelien; Quinn, Patricia K.; Saltzman, Eric S.; Stefels, Jacqueline; von Glasow, Roland

    2013-01-01

    This review focuses on critical issues in ocean-atmosphere exchange that will be addressed by new research strategies developed by the international Surface Ocean-Lower Atmosphere Study (SOLAS) research community. Eastern boundary upwelling systems are important sites for CO2 and trace gas emission

  12. Atmospheric components of the surface energy budget over young sea ice: Results from the N-ICE2015 campaign

    Science.gov (United States)

    Walden, Von P.; Hudson, Stephen R.; Cohen, Lana; Murphy, Sarah Y.; Granskog, Mats A.

    2017-08-01

    The Norwegian young sea ice campaign obtained the first measurements of the surface energy budget over young, thin Arctic sea ice through the seasonal transition from winter to summer. This campaign was the first of its kind in the North Atlantic sector of the Arctic. This study describes the atmospheric and surface conditions and the radiative and turbulent heat fluxes over young, thin sea ice. The shortwave albedo of the snow surface ranged from about 0.85 in winter to 0.72-0.80 in early summer. The near-surface atmosphere was typically stable in winter, unstable in spring, and near neutral in summer once the surface skin temperature reached 0°C. The daily average radiative and turbulent heat fluxes typically sum to negative values (-40 to 0 W m-2) in winter but then transition toward positive values of up to nearly +60 W m-2 as solar radiation contributes significantly to the surface energy budget. The sensible heat flux typically ranges from +20-30 W m-2 in winter (into the surface) to negative values between 0 and -20 W m-2 in spring and summer. A winter case study highlights the significant effect of synoptic storms and demonstrates the complex interplay of wind, clouds, and heat and moisture advection on the surface energy components over sea ice in winter. A spring case study contrasts a rare period of 24 h of clear-sky conditions with typical overcast conditions and highlights the impact of clouds on the surface radiation and energy budgets over young, thin sea ice.

  13. TGP, an extremely stable, non-aggregating fluorescent protein created by structure-guided surface engineering

    Science.gov (United States)

    Close, Devin W.; Don Paul, Craig; Langan, Patricia S.; Wilce, Matthew C.J.; Traore, Daouda A.K.; Halfmann, Randal; Rocha, Reginaldo C.; Waldo, Geoffery S.; Payne, Riley J.; Rucker, Joseph B.; Prescott, Mark; Bradbury, Andrew R.M.

    2014-01-01

    In this paper we describe the engineering and X-ray crystal structure of Thermal Green Protein (TGP), an extremely stable, highly soluble, non-aggregating green fluorescent protein. TGP is a soluble variant of the fluorescent protein eCGP123, which despite being highly stable, has proven to be aggregation-prone. The X-ray crystal structure of eCGP123, also determined within the context of this paper, was used to carry out rational surface engineering to improve its solubility, leading to TGP. The approach involved simultaneously eliminating crystal lattice contacts while increasing the overall negative charge of the protein. Despite intentional disruption of lattice contacts and introduction of high entropy glutamate side chains, TGP crystallized readily in a number of different conditions and the X-ray crystal structure of TGP was determined to 1.9 Å resolution. The structural reasons for the enhanced stability of TGP and eCGP123 are discussed. We demonstrate the utility of using TGP as a fusion partner in various assays and significantly, in amyloid assays in which the standard fluorescent protein, EGFP, is undesirable because of aberrant oligomerization. PMID:25287913

  14. Thermal green protein, an extremely stable, nonaggregating fluorescent protein created by structure-guided surface engineering.

    Science.gov (United States)

    Close, Devin W; Paul, Craig Don; Langan, Patricia S; Wilce, Matthew C J; Traore, Daouda A K; Halfmann, Randal; Rocha, Reginaldo C; Waldo, Geoffery S; Payne, Riley J; Rucker, Joseph B; Prescott, Mark; Bradbury, Andrew R M

    2015-07-01

    In this article, we describe the engineering and X-ray crystal structure of Thermal Green Protein (TGP), an extremely stable, highly soluble, non-aggregating green fluorescent protein. TGP is a soluble variant of the fluorescent protein eCGP123, which despite being highly stable, has proven to be aggregation-prone. The X-ray crystal structure of eCGP123, also determined within the context of this paper, was used to carry out rational surface engineering to improve its solubility, leading to TGP. The approach involved simultaneously eliminating crystal lattice contacts while increasing the overall negative charge of the protein. Despite intentional disruption of lattice contacts and introduction of high entropy glutamate side chains, TGP crystallized readily in a number of different conditions and the X-ray crystal structure of TGP was determined to 1.9 Å resolution. The structural reasons for the enhanced stability of TGP and eCGP123 are discussed. We demonstrate the utility of using TGP as a fusion partner in various assays and significantly, in amyloid assays in which the standard fluorescent protein, EGFP, is undesirable because of aberrant oligomerization. © 2014 Wiley Periodicals, Inc.

  15. Land Surface Model (LSM 1.0) for Ecological, Hydrological, Atmospheric Studies

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: The NCAR LSM 1.0 is a land surface model developed to examine biogeophysical and biogeochemical land-atmosphere interactions, especially the effects of...

  16. Surface-nitriding treatment of steels using microwave-induced nitrogen plasma at atmospheric pressure

    International Nuclear Information System (INIS)

    Sato, Shigeo; Arai, Yuuki; Yamashita, Noboru; Kojyo, Atsushi; Kodama, Kenji; Ohtsu, Naofumi; Okamoto, Yukio; Wagatsuma, Kazuaki

    2012-01-01

    A rapid surface-nitriding system using microwave-induced nitrogen plasma at atmospheric pressure was developed for modifying iron and steel surfaces. Since the conventional plasma nitriding technique requires a low-pressure atmosphere in the treatment chamber, the population of excited nitrogen molecules in the plasma is limited. Accordingly, several hours are required for nitriding treatment. By contrast, the developed nitriding system can use atmospheric-pressure plasma through application of the Okamoto cavity for excitation of nitrogen plasma. The high population of excited nitrogen molecules induced by the atmospheric-pressure plasma allowed the formation of a nitriding layer that was several micrometers thick within 1 min and produced an expanded austenite iron phase with a high nitrogen concentration close to the solubility limit on the iron substrate. In addition, the nitriding treatment on high-chromium steel was performed by introducing a reducing gas such as NH 3 and H 2 into the treatment chamber. While the nitriding reaction did not proceed in a simple N 2 atmosphere due to surface oxidation, the surface reduction induced by the NH 3 or H 2 gas promoted the nitriding reaction at the surface. These nitriding phenomena characteristics of the atmospheric-pressure plasma are discussed in this paper based on the effects of the specimen temperature and plasma atmosphere on the thickness, the chemical states, and the nitride compounds of the nitrided layer as investigated by X-ray diffraction, glow-discharge optical emission spectroscopy, and X-ray photoelectron spectroscopy.

  17. SAFARI 2000 Surface Atmospheric Radiative Transfer (SMART), Dry Season 2000

    Data.gov (United States)

    National Aeronautics and Space Administration — Surface-sensing Measurements for Radiative Transfer (SMART) and Chemical, Optical, and Microphysical Measurements of In-situ Troposphere (COMMIT) consist of a suite...

  18. Turbulent characteristics of a semiarid atmospheric surface layer from cup anemometers – effects of soil tillage treatment (Northern Spain

    Directory of Open Access Journals (Sweden)

    S. Yahaya

    Full Text Available This paper deals with the characteristics of turbulent flow over two agricultural plots with various tillage treatments in a fallow, semiarid area (Central Aragon, Spain. The main dynamic characteristics of the Atmospheric Surface Layer (ASL measured over the experimental site (friction velocity, roughness length, etc., and energy budget, have been presented previously (Frangi and Richard, 2000. The current study is based on experimental measurements performed with cup anemometers located in the vicinity of the ground at 5 different levels (from 0.25 to 4 m and sampled at 1 Hz. It reveals that the horizontal wind variance, the Eulerian integral scales, the frequency range of turbulence and the turbulent kinetic energy dissipation rate are affected by the surface roughness. In the vicinity of the ground surface, the horizontal wind variance logarithmically increases with height, directly in relation to the friction velocity and the roughness length scale. It was found that the time integral scale (and subsequently the length integral scale increased with the surface roughness and decreased with the anemometer height. These variations imply some shifts in the meteorological spectral gap and some variations of the spectral peak length scale. The turbulent energy dissipation rate, affected by the soil roughness, shows a z-less stratification behaviour under stable conditions. In addition to the characterization of the studied ASL, this paper intends to show which turbulence characteristics, and under what conditions, are accessible through the cup anemometer.

    Key words. Meteorology and atmospheric dynamics (climatology, turbulence, instruments and techniques

  19. Turbulent characteristics of a semiarid atmospheric surface layer from cup anemometers – effects of soil tillage treatment (Northern Spain

    Directory of Open Access Journals (Sweden)

    S. Yahaya

    2003-10-01

    Full Text Available This paper deals with the characteristics of turbulent flow over two agricultural plots with various tillage treatments in a fallow, semiarid area (Central Aragon, Spain. The main dynamic characteristics of the Atmospheric Surface Layer (ASL measured over the experimental site (friction velocity, roughness length, etc., and energy budget, have been presented previously (Frangi and Richard, 2000. The current study is based on experimental measurements performed with cup anemometers located in the vicinity of the ground at 5 different levels (from 0.25 to 4 m and sampled at 1 Hz. It reveals that the horizontal wind variance, the Eulerian integral scales, the frequency range of turbulence and the turbulent kinetic energy dissipation rate are affected by the surface roughness. In the vicinity of the ground surface, the horizontal wind variance logarithmically increases with height, directly in relation to the friction velocity and the roughness length scale. It was found that the time integral scale (and subsequently the length integral scale increased with the surface roughness and decreased with the anemometer height. These variations imply some shifts in the meteorological spectral gap and some variations of the spectral peak length scale. The turbulent energy dissipation rate, affected by the soil roughness, shows a z-less stratification behaviour under stable conditions. In addition to the characterization of the studied ASL, this paper intends to show which turbulence characteristics, and under what conditions, are accessible through the cup anemometer.Key words. Meteorology and atmospheric dynamics (climatology, turbulence, instruments and techniques

  20. Mapping Precipitation Patterns from the Stable Isotopic Composition of Surface Waters: Olympic Peninsula, Washington State

    Science.gov (United States)

    Anders, A. M.; Brandon, M. T.

    2008-12-01

    Available data indicate that large and persistent precipitation gradients are tied to topography at scales down to a few kilometers, but precipitation patterns in the majority of mountain ranges are poorly constrained at scales less than tens of kilometers. A lack of knowledge of precipitation patterns hampers efforts to understand the processes of orographic precipitation and identify the relationships between geomorphic evolution and climate. A new method for mapping precipitation using the stable isotopic composition of surface waters is tested in the Olympic Mountains of Washington State. Measured δD and δ18O of 97 samples of surface water are linearly related and nearly inseparable from the global meteoric water line. A linear orographic precipitation model extended to include in effects of isotopic fractionation via Rayleigh distillation predicts precipitation patterns and isotopic composition of surface water. Seven parameters relating to the climate and isotopic composition of source water are used. A constrained random search identifies the best-fitting parameter set. Confidence intervals for parameter values are defined and precipitation patterns are determined. Average errors for the best-fitting model are 4.8 permil in δD. The difference between the best fitting model and other models within the 95% confidence interval was less than 20%. An independent high-resolution precipitation climatology documents precipitation gradients similar in shape and magnitude to the model derived from surface water isotopic composition. This technique could be extended to other mountain ranges, providing an economical and fast assessment of precipitation patterns requiring minimal field work.

  1. A review of measurement and modelling results of particle atmosphere-surface exchange

    DEFF Research Database (Denmark)

    Pryor, Sara; Gallagher, M.; Sievering, H.

    2008-01-01

    Atmosphere-surface exchange represents one mechanism by which atmospheric particle mass and number size distributions are modified. Deposition velocities (upsilon(d)) exhibit a pronounced dependence on surface type, due in part to turbulence structure (as manifest in friction velocity), with minima...... approaches and innovations in experimental approaches, and synthesize common conclusions of experimental and modelling studies. We end by proposing a number of research avenues that should be pursued in to facilitate further insights and development of improved numerical models of atmospheric particles....

  2. Competing Atmospheric and Surface-Driven Impacts of Absorbing Aerosols on the East Asian Summer Monsoon

    Science.gov (United States)

    Persad, G.; Paynter, D.; Ming, Y.; Ramaswamy, V.

    2015-12-01

    Absorbing aerosols, by attenuating shortwave radiation within the atmosphere and reemitting it as longwave radiation, redistribute energy both vertically within the surface-atmosphere column and horizontally between polluted and unpolluted regions. East Asia has the largest concentrations of anthropogenic absorbing aerosols globally, and these, along with the region's scattering aerosols, have both reduced the amount of solar radiation reaching the Earth's surface regionally ("solar dimming") and increased shortwave absorption within the atmosphere, particularly during the peak months of the East Asian Summer Monsoon (EASM). We here analyze how atmospheric absorption and surface solar dimming compete in driving the response of EASM circulation to anthropogenic absorbing aerosols, which dominates, and why—issues of particular importance for predicting how the EASM will respond to projected changes in absorbing and scattering aerosol emissions in the future. We probe these questions in a state-of-the-art general circulation model (GCM) using a combination of realistic and idealized aerosol perturbations that allow us to analyze the relative influence of absorbing aerosols' atmospheric and surface-driven impacts on EASM circulation. In combination, our results make clear that, although absorption-driven dimming has a less detrimental effect on EASM circulation than purely scattering-driven dimming, aerosol absorption is still a net impairment to EASM strength when both its atmospheric and surface effects are considered. Because atmospheric heating is not efficiently conveyed to the surface, the surface dimming and associated cooling from even a pure absorber is sufficient to counteract its atmospheric heating, resulting in a net reduction in EASM strength. These findings elevate the current understanding of the impacts of aerosol absorption on the EASM, improving our ability to diagnose EASM responses to current and future regional changes in aerosol emissions.

  3. Cleaning of niobium surface by plasma of diffuse discharge at atmospheric pressure

    Science.gov (United States)

    Tarasenko, V. F.; Erofeev, M. V.; Shulepov, M. A.; Ripenko, V. S.

    2017-07-01

    Elements composition of niobium surface before and after plasma treatment by runaway electron preionized diffuse discharge was investigated in atmospheric pressure nitrogen flow by means of an Auger electron spectroscopy. Surface characterizations obtained from Auger spectra show that plasma treatment by diffuse discharge after exposure of 120000 pulses provides ultrafine surface cleaning from carbon contamination. Moreover, the surface free energy of the treated specimens increased up to 3 times, that improve its adhesion property.

  4. Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

    Science.gov (United States)

    Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

    2000-01-01

    We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

  5. No difference in 1RM strength and muscle activation during the barbell chest press on a stable and unstable surface.

    Science.gov (United States)

    Goodman, Craig A; Pearce, Alan J; Nicholes, Caleb J; Gatt, Brad M; Fairweather, Ian H

    2008-01-01

    Exercise or Swiss balls are increasingly being used with conventional resistance exercises. There is little evidence supporting the efficacy of this approach compared to traditional resistance training on a stable surface. Previous studies have shown that force output may be reduced with no change in muscle electromyography (EMG) activity while others have shown increased muscle EMG activity when performing resistance exercises on an unstable surface. This study compared 1RM strength, and upper body and trunk muscle EMG activity during the barbell chest press exercise on a stable (flat bench) and unstable surface (exercise ball). After familiarization, 13 subjects underwent testing for 1RM strength for the barbell chest press on both a stable bench and an exercise ball, each separated by at least 7 days. Surface EMG was recorded for 5 upper body muscles and one trunk muscle from which average root mean square of the muscle activity was calculated for the whole 1RM lift and the concentric and eccentric phases. Elbow angle during each lift was recorded to examine any range-of-motion differences between the two surfaces. The results show that there was no difference in 1RM strength or muscle EMG activity for the stable and unstable surfaces. In addition, there was no difference in elbow range-of-motion between the two surfaces. Taken together, these results indicate that there is no reduction in 1RM strength or any differences in muscle EMG activity for the barbell chest press exercise on an unstable exercise ball when compared to a stable flat surface. Moreover, these results do not support the notion that resistance exercises performed on an exercise ball are more efficacious than traditional stable exercises.

  6. Decontamination of radionuclide strontium polluted the analog instruments surface by high stable foam

    International Nuclear Information System (INIS)

    Zhu Gaolong; Chen Shuai; Lin Xiaoyan; Luo Xuegang

    2014-01-01

    Decontamination of the radionuclide strontium polluted the analog instruments surface radionuclide strontium by foam, where the high stable foam detergent was prepared by Sodium dodecylbenzene sulfonate (SDBS) as a foaming agent and hydroxyethyl cellulose (HEC) as a foam stabilizer. The effects of adding a foam stabilizer hydroxyethyl cellulose (HEC) on foam stability and the volume of drainage liquid were discussed and contact time, foaming agent concentration, temperature, humidity on foam decontamination efficiency of the analog instruments surface by radionuclide strontium were observed. The results show that there has been a significant increase of foam stability with the increase of HEC addition, the volume of drainage liquid was decrease from 7.8 g to 0 g and the half decay time of foam was extended from 305 seconds to 1050 seconds after the HEC addition increase from 0 % to 3%. The half decay time increase with the continue to increase of HEC addition but decrease of the foamability. The foam drainage speed up with the increase of temperture, the foam will burst rapidly when the temperture is higer than 600 ℃. The high table foam has a effective decontamination efficiency between 88%∼95%. contact time, foaming agent concentration, humidity do not much affect on the foam decontamination. In order to reduce the affect of volume of drainage liquid on the precision instrument, the contact time should control in 3 min. (authors)

  7. Surface and top-of-atmosphere radiative feedback kernels for CESM-CAM5

    Science.gov (United States)

    Pendergrass, Angeline G.; Conley, Andrew; Vitt, Francis M.

    2018-02-01

    Radiative kernels at the top of the atmosphere are useful for decomposing changes in atmospheric radiative fluxes due to feedbacks from atmosphere and surface temperature, water vapor, and surface albedo. Here we describe and validate radiative kernels calculated with the large-ensemble version of CAM5, CESM1.1.2, at the top of the atmosphere and the surface. Estimates of the radiative forcing from greenhouse gases and aerosols in RCP8.5 in the CESM large-ensemble simulations are also diagnosed. As an application, feedbacks are calculated for the CESM large ensemble. The kernels are freely available at https://doi.org/10.5065/D6F47MT6" target="_blank">https://doi.org/10.5065/D6F47MT6, and accompanying software can be downloaded from https://github.com/apendergrass/cam5-kernels" target="_blank">https://github.com/apendergrass/cam5-kernels.

  8. Atmospheric Transference of the Toxic Burden of Atmosphere-Surface Exchangeable Pollutants to the Great Lakes Region

    Science.gov (United States)

    Kumar, A.; Perlinger, J. A.; Giang, A.; Zhang, H.; Selin, N. E.; Wu, S.

    2016-12-01

    Toxic pollutants that share certain chemical properties undergo repeated emission and deposition between Earth's surfaces and the atmosphere. Following their emission through anthropogenic activities, they are transported locally, regionally or globally through the atmosphere, are deposited, and impact local ecosystems, in some cases as a result of bioaccumulation in food webs. We call them atmosphere-surface exchangeable pollutants or "ASEPs", wherein this group is comprised of thousands of chemicals. We are studying potential future contamination in the Great Lakes region by modeling scenarios of the future for three compounds/compound classes, mercury, polychlorinated biphenyl compounds, and polycyclic aromatic hydrocarbons. In this presentation we focus on mercury and future scenarios of contamination of the Great Lake region. The atmospheric transport of mercury under specific scenarios will be discussed. The global 3-D chemical transport model GEOS-Chem has been applied to estimate future atmospheric concentrations and deposition rates of mercury in the Great Lakes region for selected future scenarios of emissions and climate. We find that, assuming no changes in climate, annual mean net deposition flux of mercury to the Great Lakes Region may increase by approximately 50% over 2005 levels by 2050, without global or regional policies addressing mercury, air pollution, and climate. In contrast, we project that the combination of global and North American action on mercury could lead to a 21% reduction in deposition from 2005 levels by 2050. US action alone results in a projected 18% reduction over 2005 levels by 2050. We also find that, assuming no changes in anthropogenic emissions, climate change and biomass burning emissions would, respectively, cause annual mean net deposition flux of mercury to the Great Lakes Region to increase by approximately 5% and decrease by approximately 2% over 2000 levels by 2050.

  9. Effect of surface morphology on atmospheric corrosion behaviour of ...

    Indian Academy of Sciences (India)

    Wintec

    adverse effect of quenched-in defects on the corrosion resistance of Fe34Ni36Cr10P14B6 amorphous alloy has been reported by some investigators (Gravano et al 1992). The inferior corrosion resistance of the wheel side surface has been attributed to higher concentration of quenched- in defects due to higher cooling rate ...

  10. Atmospheric correction for sea surface temperature retrieval from ...

    Indian Academy of Sciences (India)

    The interpretation and validation of satellite measure- ments of SST from both polar-orbiting and geo- stationary satellites is affected by the presence of the oceanic skin layer (see, e.g., Katsaros 1980;. Keywords. Retrieval; sea surface temperature; Kalpana satellite; TRMM/TMI; water vapour fields. J. Earth Syst. Sci. 120, No.

  11. Heterogeneous Reactions of Polycyclic Aromatic Hydrocarbons on Atmospheric and Terrestrial Surfaces

    Science.gov (United States)

    Simonich, S. L.

    2014-12-01

    The heterogeneous reactions of five higher molecular weight polycyclic aromatic hydrocarbons (PAHs), benzo[a]pyrene-d12 (BaP-d12), benzo(k)fluoranthene-d12 (BkF-d12), benzo[g,h,i]perylene-d12 (BghiP-d12), dibenzo(a,i)pyrene-d14 (DBaiP-d14), and dibenzo[a,l]pyrene (DalP), with NO2, NO3/N2O5, O3, and OH radicals were investigated in a 7000 L indoor Teflon chamber. Quartz fiber filters (QFF) were used as the reaction surface and substrate and the analyses of parent PAHs and Nitro-PAH (NPAH) products was conducted using electron impact gas chromatographic mass spectrometry (GC/MS) and negative chemical ionization GC/MS. In parallel to the laboratory experiments, a theoretical study was conducted to assist in determining the formation of NPAH isomers based on the OH-radical initiated reaction. The thermodynamic stability of OH-PAH intermediates was used to indicate the position of highest electron density and the most stable NPAH products were synthesized to confirm their identity. NO2 and NO3/N2O5 were the most effective oxidizing agents in transforming PAHs deposited on filters to NPAHs, under the experimental conditions. Reaction of BaP-d12, BkF-d12 and BghiP-d12 resulted in the formation of several mono-nitro PAH isomer product, while the reaction of DalP and DaiP-d14 resulted in the formation of only one mono-nitro PAH isomer product. The direct-acting mutagenicity of the products increased the most after NO3/N2O5 exposure, particularly for BkF-d12 in which the formation of dinitro- PAHs was observed. In addition, the degradation of particulate matter (PM)-bound PAHs by heterogeneous reaction with OH radicals, O3, NO3/N2O5 was also studied. Ambient PM samples collected from Beijing, China and Riverside, California were exposed in an indoor chamber under simulated trans-Pacific atmospheric transport conditions and the formation of NPAHs was studied. NPAHs were most effectively formed during the NO3/N2O5 exposure and, for all exposures, there was no significant

  12. Amplification of surface temperature trends and variability in thetropical atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Santer, B.D.; Wigley, T.M.L.; Mears, C.; Wentz, F.J.; Klein,S.A.; Seidel, D.J.; Taylor, K.E.; Thorne, P.W.; Wehner, M.F.; Gleckler,P.J.; Boyle, J.S.; Collins, W.D.; Dixon, K.W.; Doutriaux, C.; Free, M.; Fu, Q.; Hansen, J.E.; Jones, G.S.; Ruedy, R.; Karl, T.R.; Lanzante, J.R.; Meehl, G.A.; Ramaswamy, V.; Russell, G.; Schmidt, G.A.

    2005-08-11

    The month-to-month variability of tropical temperatures is larger in the troposphere than at the Earth's surface. This amplification behavior is similar in a range of observations and climate model simulations, and is consistent with basic theory. On multi-decadal timescales, tropospheric amplification of surface warming is a robust feature of model simulations, but occurs in only one observational dataset. Other observations show weak or even negative amplification. These results suggest that either different physical mechanisms control amplification processes on monthly and decadal timescales, and models fail to capture such behavior, or (more plausibly) that residual errors in several observational datasets used here affect their representation of long-term trends.

  13. Modeling Turbulence Generation in the Atmospheric Surface and Boundary Layers

    Science.gov (United States)

    2015-10-01

    ZT ). The initial acceleration of the rising buoyant air will be a = g∆T/TA. This is simply Archimedes ’ principle applied to the buoyant air. The... applications . 1 Various rules are employed to model C2n in the surface layer, but a key question is how to extend this estimation technique into the lower...in terms of wind turbulence the structure of the fluctuations produces a Reynolds stress tensor whose principle axes are not equal, meaning that at the

  14. Surface kinetics for catalytic combustion of hydrogen-air mixtures on platinum at atmospheric pressure in stagnation flows

    Science.gov (United States)

    Ikeda, H.; Sato, J.; Williams, F. A.

    1995-03-01

    Experimental studies of the combustion of premixed hydrogen-air mixtures impinging on the surface of a heated platinum plate at normal atmospheric pressure were performed and employed to draw inferences concerning surface reaction mechanisms and rate parameters applicable under practical conditions of catalytic combustion. Plate and gas temperatures were measured by thermocouples, and concentration profiles of major stable species in the gas were measured by gas-chromatographic analyses of samples withdrawn by quartz probes. In addition, ignition and extinction phenomena were recorded and interpreted with the aid of a heat balance at the surface and a previous flow-field analysis of the stagnation-point boundary layer. From the experimental and theoretical results, conclusions were drawn concerning the surface chemical-kinetic mechanisms and values of the elementary rate parameters that are consistent with the observations. In particular, the activation energy for the surface oxidation step H + OH → H 2O is found to be appreciably less at these high surface coverages than in the low-coverage limit.

  15. Atmospheric pressure plasma surface modification of titanium for high temperature adhesive bonding

    NARCIS (Netherlands)

    Akram, M.; Jansen, K.M.B.; Ernst, L.J.; Bhowmik, S.

    2011-01-01

    In this investigation surface treatment of titanium is carried out by plasma ion implantation under atmospheric pressure plasma in order to increase the adhesive bond strength. Prior to the plasma treatment, titanium surfaces were mechanically treated by sand blasting. It is observed that the

  16. Study of surface an atmospheric pollution in radioiodine from Hospitals

    International Nuclear Information System (INIS)

    Gomez Palacios, M.; Cuetos Menendez, A.

    1999-01-01

    In hospitals environment, the radioactive iodine surface contamination is one of the most important incident from the point of view of radiation protection. Among this kind of incidents we can consider vomit or urine spillage from ''131 I therapy or spillage of liquids contaminated with ''125 I from RIA laboratories. We have studied the dynamic of the contamination flow from the contaminated surface to the indoor air, using total activity in the spill, indoor air renewal rate, and resuspension rate as parameters. We describe a method to estimate the resuspension rate, assuming that this parameter is usually unknown, and its results for the following cases: urine or water, on paper-covered or uncovered plastic surface. By using the experimental results, we have studied the indoor air contamination evolution with time, as a function of both initial activity, and indoor air renewal rate. The maximum value of indoor air contamination is not dependent on the initial activity value. The resuspension process is slower in the case of urine spillage that in watery leakage. The use of porous paper may establish the difference between keeping and indoor air contamination below derived air concentration limit (CDAC), or clearly above DAC for may days. The indoor air contamination dependence from the air renewal rate, shows the convenience of high air renewal rate in places where contamination from ''131 I therapy were possible, and how although this factor is not so critical, it should be taken into account in RIA laboratories. (Author) 6 refs

  17. Stable Isotope Data

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Tissue samples (skin, bone, blood, muscle) are analyzed for stable carbon, stable nitrogen, and stable sulfur analysis. Many samples are used in their entirety for...

  18. Source apportionment of atmospheric ammonia before, during, and after the 2014 APEC summit in Beijing using stable nitrogen isotope signatures

    Directory of Open Access Journals (Sweden)

    Y. Chang

    2016-09-01

    Full Text Available Stable nitrogen isotope composition (δ15N offers new opportunities to address the long-standing and ongoing controversy regarding the origins of ambient ammonia (NH3, a vital precursor of PM2.5 (particulate matters with aerodynamic diameter equal or less than 2.5 µm inorganic components, in the urban atmosphere. In this study, the δ15N values of NH3 samples collected from various sources were constrained using a novel and robust chemical method coupled with standard elemental analysis procedures. Independent of the wide variation in mass concentrations (ranging from 33 (vehicle to over 6000 (human excreta µg m−3, different NH3 sources have generally different δ15N values (ranging from −52.0 to −9.6 ‰. Significantly high δ15N values are seen as a characteristic feature of all vehicle-derived NH3 samples (−14.2 ± 2.8 ‰, which can be distinguished from other sources emitted at environmental temperature (−29.1 ± 1.7, −37.8 ± 3.6, and −50.0 ± 1.8 ‰ for livestock, waste, and fertilizer, respectively. The isotope δ15N signatures for a range of NH3 emission sources were used to evaluate the contributions of the different sources within measured ambient NH3 in Beijing, using an isotope mixing model (IsoSource. The method was used to quantify the sources of ambient NH3 before, during and after the 2014 Asia-Pacific Economic Cooperation (APEC summit, when a set of stringent air quality control measures were implemented. Results show that the average NH3 concentrations (the overall contributions of traffic, waste, livestock, and fertilizer during the three periods were 9.1 (20.3, 28.3, 23.6, and 27.7 %, 7.3 (8.8, 24.9, 14.3, and 52.0 %, and 12.7 (29.4, 23.6, 31.7, and 15.4 % µg m−3, respectively, representing a 20.0 % decrease first and then a 74.5 % increase in overall NH3 mass concentrations. During (after the summit, the contributions of traffic, waste, livestock, and fertilizer

  19. The theory of the interaction of atmospheric aerosol with underlying surface

    International Nuclear Information System (INIS)

    Buikov, M.V.

    1993-01-01

    The interaction of wind with underlying surfaces through resuspension makes a great contribution to the total amount of atmospheric aerosols. The dry deposition process results in cleaning of the atmosphere and contamination of near-surface air layers of soil and vegetation. This paper examines the theory leading to an exact solution of the problem of turbulent transportation of pollution taking into account resuspension and dry-deposition. This may be useful for the interpretation of observational data and for the improvement of calculation methods to describe aerosol exchange at surfaces in air. (author)

  20. Air/surface exchange processes of mercury and their linkage to atmospheric pools

    International Nuclear Information System (INIS)

    Bahlmann, Enno; Ebinghaus, Ralf

    2001-01-01

    The atmospheric mercury cycle is strongly linked to the terrestrial, aquatic and biologic cycle of mercury via air/surface exchange processes. In order to quantify mercury fluxes from and to the atmosphere to predict local and regional source contributions the methods for flux measurements as well as the physicochemical factors controlling air/surface exchange processes must be assessed. We will describe methods for the determination of mercury and mercury species in ambient air which are basic for investigation of air/surface exchange processes. Further on we will describe approaches for studying the physicochemical factors controlling this processes by using a new laboratory flux measurement system. (author)

  1. Hydrophilic surface modification of coronary stent using an atmospheric pressure plasma jet for endothelialization.

    Science.gov (United States)

    Shim, Jae Won; Bae, In-Ho; Park, Dae Sung; Lee, So-Youn; Jang, Eun-Jae; Lim, Kyung-Seob; Park, Jun-Kyu; Kim, Ju Han; Jeong, Myung Ho

    2018-03-01

    The first two authors contributed equally to this study. Bioactivity and cell adhesion properties are major factors for fabricating medical devices such as coronary stents. The aim of this study was to evaluate the advantages of atmospheric-pressure plasma jet in enhancing the biocompatibility and endothelial cell-favorites. The experimental objects were divided into before and after atmospheric-pressure plasma jet treatment with the ratio of nitrogen:argon = 3:1, which is similar to air. The treated surfaces were basically characterized by means of a contact angle analyzer for the activation property on their surfaces. The effect of atmospheric-pressure plasma jet on cellular response was examined by endothelial cell adhesion and XTT analysis. It was difficult to detect any changeable morphology after atmospheric-pressure plasma jet treatment on the surface. The roughness was increased after atmospheric-pressure plasma jet treatment compared to nonatmospheric-pressure plasma jet treatment (86.781 and 7.964 nm, respectively). The X-ray photoelectron spectroscopy results showed that the surface concentration of the C-O groups increased slightly from 6% to 8% after plasma activation. The contact angle dramatically decreased in the atmospheric-pressure plasma jet treated group (22.6 ± 15.26°) compared to the nonatmospheric-pressure plasma jet treated group (72.4 ± 15.26°) ( n = 10, p atmospheric-pressure plasma jet on endothelial cell migration and proliferation was 85.2% ± 12.01% and 34.2% ± 2.68%, respectively, at 7 days, compared to the nonatmospheric-pressure plasma jet treated group (58.2% ± 11.44% in migration, n = 10, p atmospheric-pressure plasma jet method. Moreover, the atmospheric-pressure plasma jet might affect re-endothelialization after stenting.

  2. Stable water isotopes in the coupled atmosphere–land surface model ECHAM5-JSBACH

    Directory of Open Access Journals (Sweden)

    B. Haese

    2013-09-01

    Full Text Available In this study we present first results of a new model development, ECHAM5-JSBACH-wiso, where we have incorporated the stable water isotopes H218O and HDO as tracers in the hydrological cycle of the coupled atmosphere–land surface model ECHAM5-JSBACH. The ECHAM5-JSBACH-wiso model was run under present-day climate conditions at two different resolutions (T31L19, T63L31. A comparison between ECHAM5-JSBACH-wiso and ECHAM5-wiso shows that the coupling has a strong impact on the simulated temperature and soil wetness. Caused by these changes of temperature and the hydrological cycle, the δ18O in precipitation also shows variations from −4‰ up to 4‰. One of the strongest anomalies is shown over northeast Asia where, due to an increase of temperature, the δ18O in precipitation increases as well. In order to analyze the sensitivity of the fractionation processes over land, we compare a set of simulations with various implementations of these processes over the land surface. The simulations allow us to distinguish between no fractionation, fractionation included in the evaporation flux (from bare soil and also fractionation included in both evaporation and transpiration (from water transport through plants fluxes. While the isotopic composition of the soil water may change for δ18O by up to +8&permil:, the simulated δ18O in precipitation shows only slight differences on the order of ±1‰. The simulated isotopic composition of precipitation fits well with the available observations from the GNIP (Global Network of Isotopes in Precipitation database.

  3. Short-term temperature-dependent air-surface exchange and atmospheric concentrations of polychlorinated naphthalenes and organochlorine pesticides

    Energy Technology Data Exchange (ETDEWEB)

    Lee, R.G.M.; Burnett, V.; Harner, T.; Jones, K.C.

    2000-02-01

    Atmospheric concentrations of five organochlorine (OC) pesticides, some of which have been banned for a number of years, and polychlorinated naphthalenes (PCNs) were measured at a U.K. site over periods of 6 h for 7 days resulting in 28 samples. Mean concentrations of the pesticides were {alpha}-HCH 90 pg m{sup {minus}3}, {gamma}-HCH 500, {rho},{rho}{prime}-DDE 8, dieldrin 63, endrin 22, and HCB 39. PCN mean homologue concentrations were {sub 3}CNs 67 pg m{sup {minus}3}, {sub 4}CNs 78, {sub 5}CNs 5, {sub 6}CNs 0.6, {sub 7}CNs 0.6, and {Sigma}PCNs 152. TEQ concentrations for those PCNs ascribed TEF values ranged between 0.36 and 3.6 fg m{sup {minus}3} which corresponds to {approximately}3.0--30% of the TEQ concentrations of PCDD/Fs at the same site. All the compounds measured, except HCB, exhibited a strong temperature-dependent diurnal cycling. Results from Clausius-Clapeyron plots show that pesticide concentrations were controlled by temperature-driven air-surface recycling throughout the first 5 days when stable atmospheric conditions were dominant, while during the last 2 days advection became more influential as more unstable and cooler weather started to influence the site. PCN concentrations were controlled primarily by a mixture of recycling and advection throughout the first 5 days and then by advection in the final 2 days, suggesting that there are ongoing emissions from diffuse point sources of PCNs into the U.K. atmosphere. This study provides further evidence of the rapid air-surface exchange of semivolatile organic compounds (SOCs) and shows how different factors alone or in combination can produce rapid changes in the atmospheric concentrations of past and present SOCs.

  4. Intercomparison of oceanic and atmospheric forced and coupled mesoscale simulations Part I: Surface fluxes

    Directory of Open Access Journals (Sweden)

    P. Josse

    1999-04-01

    Full Text Available A mesoscale non-hydrostatic atmospheric model has been coupled with a mesoscale oceanic model. The case study is a four-day simulation of a strong storm event observed during the SEMAPHORE experiment over a 500 × 500 km2 domain. This domain encompasses a thermohaline front associated with the Azores current. In order to analyze the effect of mesoscale coupling, three simulations are compared: the first one with the atmospheric model forced by realistic sea surface temperature analyses; the second one with the ocean model forced by atmospheric fields, derived from weather forecast re-analyses; the third one with the models being coupled. For these three simulations the surface fluxes were computed with the same bulk parametrization. All three simulations succeed well in representing the main oceanic or atmospheric features observed during the storm. Comparison of surface fields with in situ observations reveals that the winds of the fine mesh atmospheric model are more realistic than those of the weather forecast re-analyses. The low-level winds simulated with the atmospheric model in the forced and coupled simulations are appreciably stronger than the re-analyzed winds. They also generate stronger fluxes. The coupled simulation has the strongest surface heat fluxes: the difference in the net heat budget with the oceanic forced simulation reaches on average 50 Wm-2 over the simulation period. Sea surface-temperature cooling is too weak in both simulations, but is improved in the coupled run and matches better the cooling observed with drifters. The spatial distributions of sea surface-temperature cooling and surface fluxes are strongly inhomogeneous over the simulation domain. The amplitude of the flux variation is maximum in the coupled run. Moreover the weak correlation between the cooling and heat flux patterns indicates that the surface fluxes are not responsible for the whole cooling and suggests that the response of the ocean mixed layer

  5. Intercomparison of oceanic and atmospheric forced and coupled mesoscale simulations Part I: Surface fluxes

    Directory of Open Access Journals (Sweden)

    H. Giordani

    Full Text Available A mesoscale non-hydrostatic atmospheric model has been coupled with a mesoscale oceanic model. The case study is a four-day simulation of a strong storm event observed during the SEMAPHORE experiment over a 500 × 500 km2 domain. This domain encompasses a thermohaline front associated with the Azores current. In order to analyze the effect of mesoscale coupling, three simulations are compared: the first one with the atmospheric model forced by realistic sea surface temperature analyses; the second one with the ocean model forced by atmospheric fields, derived from weather forecast re-analyses; the third one with the models being coupled. For these three simulations the surface fluxes were computed with the same bulk parametrization. All three simulations succeed well in representing the main oceanic or atmospheric features observed during the storm. Comparison of surface fields with in situ observations reveals that the winds of the fine mesh atmospheric model are more realistic than those of the weather forecast re-analyses. The low-level winds simulated with the atmospheric model in the forced and coupled simulations are appreciably stronger than the re-analyzed winds. They also generate stronger fluxes. The coupled simulation has the strongest surface heat fluxes: the difference in the net heat budget with the oceanic forced simulation reaches on average 50 Wm-2 over the simulation period. Sea surface-temperature cooling is too weak in both simulations, but is improved in the coupled run and matches better the cooling observed with drifters. The spatial distributions of sea surface-temperature cooling and surface fluxes are strongly inhomogeneous over the simulation domain. The amplitude of the flux variation is maximum in the coupled run. Moreover the weak correlation between the cooling and heat flux patterns indicates that the surface fluxes are not responsible for the whole cooling and suggests that the response of the ocean mixed layer

  6. Studying Titan's surface photometry in the 5 microns atmospheric window with the Cassini/VIMS instrument

    Science.gov (United States)

    Cornet, T.; Altobelli, N.; Sotin, C.; Le Mouelic, S.; Rodriguez, S.; Philippe, S.; Brown, R. H.; Barnes, J. W.; Buratti, B. J.; Baines, K. H.; Clark, R. N.; Nicholson, P. D.

    2014-12-01

    Due to the influence of methane gas and a thick aerosols haze in the atmosphere, Titan's surface is only visible in 7 spectral atmospheric windows centered at 0.93, 1.08, 1.27, 1.59, 2.01, 2.7-2.8 and 5 microns with the Cassini Visual and Infrared Mapping Spectrometer (VIMS). The 5 microns atmospheric window constitutes the only one being almost insensitive to the haze scattering and which presents only a reduced atmospheric absorption contribution to the signal recorded by the instrument. Despite these advantages leading to the almost direct view of the surface, the 5 microns window is also the noisiest spectral window of the entire VIMS spectrum (an effect highly dependent on the time exposure used for the observations), and it is not totally free from atmospheric contributions, enough to keep "artefacts" in mosaics of several thousands of cubes due to atmospheric and surface photometric effects amplified by the very heterogeneous viewing conditions between each Titan flyby. At first order, a lambertian surface photometry at 5 microns has been used as an initial parameter in order to estimate atmospheric opacity and surface photometry in all VIMS atmospheric windows and to determine the albedo of the surface, yet unknown, both using radiative transfer codes on single cubes or empirical techniques on global hyperspectral mosaics. Other studies suggested that Titan's surface photometry would not be uniquely lambertian but would also contain anisotropic lunar-like contributions. In the present work, we aim at constraining accurately the surface photometry of Titan and residual atmospheric absorption effects in this 5 microns window using a comprehensive study of relevant sites located at various latitudes. Those include bright and dark (dunes) terrains, 5-microns bright terrains (Hotei Regio and Tui Regio), the Huygens Landing Site and high latitudes polar lakes and seas. The VIMS 2004 to 2014 database, composed of more than 40,000 hyperspectral cubes acquired on

  7. Study on the surface oxidation resistance of uranium metal in the atmosphere of carbon monoxide

    International Nuclear Information System (INIS)

    Wang Xiaolin; Fu Yibei; Xie Renshou

    1999-01-01

    The surface reactions of different layers on uranium metal with carbon monoxide at 25, 80 and 200 degree C are studied by X-ray photoelectron spectroscopy (XPS). The experimental results show that the carbon monoxide is adsorbed on the surface oxide layer of uranium and interacted each other. The content of oxygen in the surface oxide and O/U ratio are decreased with increasing the exposure of carbon monoxide to the surface layer. The effect of reduction on the metal surface is more obviously with a higher temperature and increasing of layer thickness. The investigation indicates the uranium metal has resistance to further oxidation in the atmosphere of carbon monoxide

  8. Lessons Learned from AIRS: Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels

    Science.gov (United States)

    Susskind, Joel

    2011-01-01

    This slide presentation reviews the use of shortwave channels available to the Atmospheric Infrared Sounder (AIRS) to improve the determination of surface and atmospheric temperatures. The AIRS instrument is compared with the Infrared Atmospheric Sounding Interferometer (IASI) on-board the MetOp-A satellite. The objectives of the AIRS/AMSU were to (1) provide real time observations to improve numerical weather prediction via data assimilation, (2) Provide observations to measure and explain interannual variability and trends and (3) Use of AIRS product error estimates allows for QC optimized for each application. Successive versions in the AIRS retrieval methodology have shown significant improvement.

  9. Atmospheric impacts on climatic variability of surface incident solar radiation

    Directory of Open Access Journals (Sweden)

    K. C. Wang

    2012-10-01

    Full Text Available The Earth's climate is driven by surface incident solar radiation (Rs. Direct measurements have shown that Rs has undergone significant decadal variations. However, a large fraction of the global land surface is not covered by these observations. Satellite-derived Rs has a good global coverage but is of low accuracy in its depiction of decadal variability. This paper shows that daily to decadal variations of Rs, from both aerosols and cloud properties, can be accurately estimated using globally available measurements of Sunshine Duration (SunDu. In particular, SunDu shows that since the late 1980's Rs has brightened over Europe due to decreases in aerosols but dimmed over China due to their increases. We found that variation of cloud cover determines Rs at a monthly scale but that aerosols determine the variability of Rs at a decadal time scale, in particular, over Europe and China. Because of its global availability and long-term history, SunDu can provide an accurate and continuous proxy record of Rs, filling in values for the blank areas that are not covered by direct measurements. Compared to its direct measurement, Rs from SunDu appears to be less sensitive to instrument replacement and calibration, and shows that the widely reported sharp increase in Rs during the early 1990s in China was a result of instrument replacement. By merging direct measurements collected by Global Energy Budget Archive with those derived from SunDu, we obtained a good coverage of Rs over the Northern Hemisphere. From this data, the average increase of Rs from 1982 to 2008 is estimated to be 0.87 W m−2 per decade.

  10. Adhesion enhancement of Al coatings on carbon/epoxy composite surfaces by atmospheric plasma

    International Nuclear Information System (INIS)

    Coulon, J.F.; Tournerie, N.; Maillard, H.

    2013-01-01

    Adhesion strengths between aluminium thin film coatings and manufactured carbon/epoxy composite surfaces were measured by assessing fracture tensile strengths using pull-off tests. The effect of the substrate roughness (nm to μm) of these composite surfaces on adhesion was studied by examining the surface free energies and adhesion strengths. The adhesion strengths of the coatings varied significantly. To improve the coating adhesion, each composite surface was treated with atmospheric plasma prior to deposition, which resulted in an increase in the surface free energy from approximately 40 mJ/m 2 to 70 mJ/m 2 because the plasma pretreatment led to the formation of hydrophilic C-O and C=O bonds on the composite surfaces, as demonstrated by X-ray photoelectron spectroscopy analyses. The adhesion strengths of the coatings were enhanced for all surface roughnesses studied. In our study, the effect of mechanical adhesion due to roughness was separated from the effect of modifying the chemical bonds with plasma activation. The adhesion ability of the pure resin was relatively weak. Increasing the surface roughness largely improved the adhesion of the resin surface. Plasma treatment of the pure resin also increased the surface adhesion. Our study shows that plasma activation effectively enhances the adhesion of manufactured composites, even when the surface roughness is on the order of microns. The ageing of the surface activation was also investigated, and the results demonstrate that atmospheric plasma has potential for use in the pretreatment of composite materials.

  11. Seasonal features of atmospheric surface-layer characteristics over a tropical coastal station in Southern India

    International Nuclear Information System (INIS)

    Hari Prasad, K.B.R.R.; Srinivas, C.V.; Baskaran, R.; Venkatraman, B.

    2016-01-01

    Dispersion of air-borne effluents occurs in the atmospheric boundary layer (ABL) where turbulence is the main physical processes. In the surface layer of ABL, the mechanical (shear) generation of turbulence exceeds the buoyant generation or consumption of turbulence. In this layer, under steady state and horizontally homogeneous conditions various forces in the governing equation can be neglected and one can apply Monin-Obukhov Similarity Theory (MOST) to estimate the turbulent fluxes and other surface layer variables. Understanding the turbulent characteristics of the surface layer is vital for modeling of turbulent diffusion in regional numerical weather and pollution dispersion models. The objective of this study is to verify the validity of the MOST at the coastal site Kalpakkam under various atmospheric stability conditions with respect to different seasons for modeling atmospheric dispersion of radioactive effluents

  12. Using of standard marine radar for determination of a water surface and an atmosphere near-surface layer parameters

    Science.gov (United States)

    Bogatov, Nikolay A.; Bakhanov, Victor V.; Ermoshkin, Aleksei V.; Kazakov, Vasily I.; Kemarskaya, Olga N.; Titov, Victor I.; Troitskaya, Yulia I.

    2014-10-01

    At present time radar methods of the seas and oceans diagnostics are actively developing. Using of the radar stations based on satellites and planes allows to receive information on a sea surface and a atmosphere near-surface layer with coverage of big water surface areas independently of day time. The developed methods of satellite radio images processing can be applied to marine radar stations. In Institute of Applied Physics RAS works on sea surface diagnostics systems development on the basis of standard marine radar are actively conducted. Despite smaller coverage of the territory in comparison with satellite data, marine radar have possibility to record spatially temporary radar images and to receive information on a surrounding situation quickly. This work deals with results of the researches which were conducted within the international expedition in the Atlantic Ocean in the autumn of 2012 on a route Rotterdam (Netherlands) - Ushuaya (Argentina) - Antarctica — Ushuaya. During this expedition a complex measurements of a sea surface, a atmosphere near-surface layer parameters and subsurface currents in the wide range of hydroweather conditions, including the storm were carried out. The system developed in IAP RAS on the basis of a marine radar ICOM MR-1200RII and the ADC (Analog Digital Converter) block for data recording on the personal computer was used. Display of a non-uniform near-surface current on sea surface radar images in storm conditions is shown. By means of the high-speed anemometer and meteorological station the measurements of the atmosphere parameters were carried out. Comparison of the anemometer data with calculated from radar images is carried out. Dependence of radar cross section from wind speed in the wide range of wind speeds, including storm conditions is investigated. Possibility of marine radar using for surface waves intensity and ice situation estimates also as icebergs detection is shown.

  13. Improved adhesion of Ag NPs to the polyethylene terephthalate surface via atmospheric plasma treatment and surface functionalization

    Science.gov (United States)

    Shen, Tao; Liu, Yong; Zhu, Yan; Yang, De-Quan; Sacher, Edward

    2017-07-01

    Ag nanoparticles (NPs) have been widely applied, as important antibacterial materials, on textile and polymer surfaces. However, their adhesion to nonreactive polymer surfaces is generally too weak for many applications. Here, we propose a two-step process, atmospheric plasma treatment followed by a surface chemical modification process, which enhances their adhesion to polyethylene terephthalate (PET) surfaces. We found that, compared to either plasma treatments or surface chemical functionalizations, alone, this combination greatly enhanced their adhesion. The plasma treatment resulted in an increase of active sites (sbnd OH, sbnd CHdbnd O and COOH) at the PET surface, permitting increased bonding to 3-aminopropyltriethoxysilane (APTES), whose sbnd NH2 groups were then able to form a bonding complex with the Ag NPs.

  14. Hydrophobic and superhydrophobic surfaces fabricated using atmospheric pressure cold plasma technology: A review.

    Science.gov (United States)

    Dimitrakellis, Panagiotis; Gogolides, Evangelos

    2018-03-29

    Hydrophobic surfaces are often used to reduce wetting of surfaces by water. In particular, superhydrophobic surfaces are highly desired for several applications due to their exceptional properties such as self-cleaning, anti-icing, anti-friction and others. Such surfaces can be prepared via numerous methods including plasma technology, a dry technique with low environmental impact. Atmospheric pressure plasma (APP) has recently attracted significant attention as lower-cost alternative to low-pressure plasmas, and as a candidate for continuous rather than batch processing. Although there are many reviews on water-repellent surfaces, and a few reviews on APP technology, there are hardly any review works on APP processing for hydrophobic and superhydrohobic surface fabrication, a topic of high importance in nanotechnology and interface science. Herein, we critically review the advances on hydrophobic and superhydrophobic surface fabrication using APP technology, trying also to give some perspectives in the field. After a short introduction to superhydrophobicity of nanostructured surfaces and to APPs we focus this review on three different aspects: (1) The atmospheric plasma reactor technology used for fabrication of (super)hydrophobic surfaces. (2) The APP process for hydrophobic surface preparation. The hydrophobic surface preparation processes are categorized methodologically as: a) activation, b) grafting, c) polymerization, d) roughening and hydrophobization. Each category includes subcategories related to different precursors used. (3) One of the most important sections of this review concerns superhydrophobic surfaces fabricated using APP. These are methodologically characterized as follows: a) single step processes where micro-nano textured topography and low surface energy coating are created at the same time, or b) multiple step processes, where these steps occur sequentially in or out of the plasma. We end the review with some perspectives in the field. We

  15. The Role of Atmospheric Pressure on Surface Thermal Inertia for Early Mars Climate Modeling

    Science.gov (United States)

    Mischna, M.; Piqueux, S.

    2017-12-01

    On rocky bodies such as Mars, diurnal surface temperatures are controlled by the surface thermal inertia, which is a measure of the ability of the surface to store heat during the day and re-radiate it at night. Thermal inertia is a compound function of the near-surface regolith thermal conductivity, density and specific heat, with the regolith thermal conductivity being strongly controlled by the atmospheric pressure. For Mars, current best maps of global thermal inertia are derived from the Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) spacecraft using bolometric brightness temperatures of the surface. Thermal inertia is widely used in the atmospheric modeling community to determine surface temperatures and to establish lower boundary conditions for the atmosphere. Infrared radiation emitted from the surface is key in regulating lower atmospheric temperatures and driving overall global circulation. An accurate map of surface thermal inertia is thus required to produce reasonable results of the present-day atmosphere using numerical Mars climate models. Not surprisingly, thermal inertia is also a necessary input into climate models of early Mars, which assume a thicker atmosphere, by as much as one to two orders of magnitude above the present-day 6 mb mean value. Early Mars climate models broadly, but incorrectly, assume the present day thermal inertia surface distribution. Here, we demonstrate that, on early Mars, when pressures were larger than today's, the surface layer thermal inertia was globally higher because of the increased thermal conductivity driven by the higher gas pressure in interstitial pore spaces within the soil. Larger thermal inertia reduces the diurnal range of surface temperature and will affect the size and timing of the modeled seasonal polar ice caps. Additionally, it will globally alter the frequency of when surface temperatures are modeled to exceed the liquid water melting point, and so results may

  16. Use of Atmospheric-Pressure Plasma Jet for Polymer Surface Modification: An Overview

    Energy Technology Data Exchange (ETDEWEB)

    Kuettner, Lindsey A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-03-16

    Atmospheric-pressure plasma jets (APPJs) are playing an increasingly important role in materials processing procedures. Plasma treatment is a useful tool to modify surface properties of materials, especially polymers. Plasma reacts with polymer surfaces in numerous ways thus the type of process gas and plasma conditions must be explored for chosen substrates and materials to maximize desired properties. This report discusses plasma treatments and looks further into atmospheric-pressure plasma jets and the effects of gases and plasma conditions. Following the short literature review, a general overview of the future work and research at Los Alamos National Laboratory (LANL) is discussed.

  17. Interactions between surface waters in King George Island, Antarctica - a stable isotope perspective

    Science.gov (United States)

    Perşoiu, Aurel; Bădăluşă, Carmen

    2017-04-01

    In this paper we present a first study of the isotopic composition of surface waters in the southern peninsulas (Barton, Fildes, Weaver and Potter) of King George Island, Antarctica. We have collected > 200 samples of snow and snowmelt, water (lake, river and spring), ice (glacier ice and permafrost) from the four peninsulas in February 2016 and analyzed them for their oxygen and hydrogen stable isotopic composition. Samples from lake water (50+) indicate a clear west-east depletion trend, suggesting a rain-out process as air masses are moving westward (and are progressively depleted in heavy isotopes) from their origin in the Drake Passage. In both Fildes and Barton Peninsulas, permafrost samples have the heaviest isotopic composition, most probably due to preferential incorporation of heavy isotopes in the ice during freezing (and no fractionation during melting). As permafrost melts, the resulting water mixes with isotopically lighter infiltrated snowmelt, and thus the groundwater has a lower isotopic composition. Further, lake and river (the later fed by lakes) water has the lightest isotopic composition, being derived mostly from the melting of light snow and glacier ice. It seems feasible to separate isotopically water in lakes/rivers (largely fed by melting multi-year glaciers and snow) and water from melting of snow/ground ice This preliminary study suggests that it is possible to separate various water sources in the southern peninsulas of King George Island, and this separation could be used to study permafrost degradation, as well as feeding and migration patterns in the bird fauna, with implications for protection purposes. Acknowledgments. The National Institute of Research and Development for Biological Sciences (Bucharest, Romania) and the Korean polar institute financially supported fieldwork in King George Island. We thank the personal at King Sejong (South Korea), Belingshaussen (Russia) and Carlini (Argentina) stations in King George Island for

  18. New insights to the use of ethanol in automotive fuels: a stable isotopic tracer for fossil- and bio-fuel combustion inputs to the atmosphere.

    Science.gov (United States)

    Giebel, Brian M; Swart, Peter K; Riemer, Daniel D

    2011-08-01

    Ethanol is currently receiving increased attention because of its use as a biofuel or fuel additive and because of its influence on air quality. We used stable isotopic ratio measurements of (13)C/(12)C in ethanol emitted from vehicles and a small group of tropical plants to establish ethanol's δ(13)C end-member signatures. Ethanol emitted in exhaust is distinctly different from that emitted by tropical plants and can serve as a unique stable isotopic tracer for transportation-related inputs to the atmosphere. Ethanol's unique isotopic signature in fuel is related to corn, a C4 plant and the primary source of ethanol in the U.S. We estimated a kinetic isotope effect (KIE) for ethanol's oxidative loss in the atmosphere and used previous assumptions with respect to the fractionation that may occur during wet and dry deposition. A small number of interpretive model calculations were used for source apportionment of ethanol and to understand the associated effects resulting from atmospheric removal. The models incorporated our end-member signatures and ambient measurements of ethanol, known or estimated source strengths and removal magnitudes, and estimated KIEs associated with atmospheric removal processes for ethanol. We compared transportation-related ethanol signatures to those from biogenic sources and used a set of ambient measurements to apportion each source contribution in Miami, Florida-a moderately polluted, but well ventilated urban location.

  19. Perchlorate formation on Mars through surface radiolysis-initiated atmospheric chemistry: A potential mechanism

    Science.gov (United States)

    Wilson, Eric H.; Atreya, Sushil K.; Kaiser, Ralf I.; Mahaffy, Paul R.

    2016-08-01

    Recent observations of the Martian surface by the Phoenix lander and the Sample Analysis at Mars indicate the presence of perchlorate (ClO4-). The abundance and isotopic composition of these perchlorates suggest that the mechanisms responsible for their formation in the Martian environment may be unique in our solar system. With this in mind, we propose a potential mechanism for the production of Martian perchlorate: the radiolysis of the Martian surface by galactic cosmic rays, followed by the sublimation of chlorine oxides into the atmosphere and their subsequent synthesis to form perchloric acid (HClO4) in the atmosphere, and the surface deposition and subsequent mineralization of HClO4 in the regolith to form surface perchlorates. To evaluate the viability of this mechanism, we employ a one-dimensional chemical model, examining chlorine chemistry in the context of Martian atmospheric chemistry. Considering the chlorine oxide, OClO, we find that an OClO flux as low as 3.2 × 107 molecules cm-2 s-1 sublimated into the atmosphere from the surface could produce sufficient HClO4 to explain the perchlorate concentration on Mars, assuming an accumulation depth of 30 cm and integrated over the Amazonian period. Radiolysis provides an efficient pathway for the oxidation of chlorine, bypassing the efficient Cl/HCl recycling mechanism that characterizes HClO4 formation mechanisms proposed for the Earth but not Mars.

  20. Numerical investigation with a coupled single-column lake-atmosphere model: using the Alpert-Stein factor separation methodology to assess the sensitivity of surface interactions

    Science.gov (United States)

    Goyette, Stéphane

    2017-04-01

    A coupled single-column atmosphere-lake model, along with the Stein-Alpert factor separation methodology, is used to explore some of the non-linear interactions in the vertical dimension between the lower atmosphere and the deep-Lake Geneva, Switzerland, during three selected periods in 1990. The first from the end of April to the end of May when Lake Geneva was building its stratification, the second from mid-August to mid-September during stable stratification, and the third from the end of November to the end of December during destratification. It is recognized that the large thermal inertia of Lake Geneva reduces the surface annual and diurnal temperature variations for neighbouring regions. However, the question of how the open water and the overlying atmosphere interact and which of these "factors" has the most influence needs much attention. The sole presence of the lake is shown to be a major feature with regard to the surface energy budget components whose contributions counteract those of the lower atmosphere, thus supporting the fact that Lake Geneva acts as a damping factor to the regional climate system. It is also shown that not only did the presence of the lake and the overlying atmosphere independently modulate the surface energy budget, but also the synergistic nonlinear interaction among them, either positive or negative, was often found non-negligible. Moreover, some processes may turn out to be important on short time scales while being negligible on the long term.

  1. Effects of shrub and tree cover increase on the near-surface atmosphere in northern Fennoscandia

    Science.gov (United States)

    Rydsaa, Johanne H.; Stordal, Frode; Bryn, Anders; Tallaksen, Lena M.

    2017-09-01

    Increased shrub and tree cover in high latitudes is a widely observed response to climate change that can lead to positive feedbacks to the regional climate. In this study we evaluate the sensitivity of the near-surface atmosphere to a potential increase in shrub and tree cover in the northern Fennoscandia region. We have applied the Weather Research and Forecasting (WRF) model with the Noah-UA land surface module in evaluating biophysical effects of increased shrub cover on the near-surface atmosphere at a fine resolution (5.4 km × 5.4 km). Perturbation experiments are performed in which we prescribe a gradual increase in taller vegetation in the alpine shrub and tree cover according to empirically established bioclimatic zones within the study region. We focus on the spring and summer atmospheric response. To evaluate the sensitivity of the atmospheric response to inter-annual variability in climate, simulations were conducted for two contrasting years, one warm and one cold. We find that shrub and tree cover increase leads to a general increase in near-surface temperatures, with the highest influence seen during the snowmelt season and a more moderate effect during summer. We find that the warming effect is stronger in taller vegetation types, with more complex canopies leading to decreases in the surface albedo. Counteracting effects include increased evapotranspiration, which can lead to increased cloud cover, precipitation, and snow cover. We find that the strength of the atmospheric feedback is sensitive to snow cover variations and to a lesser extent to summer temperatures. Our results show that the positive feedback to high-latitude warming induced by increased shrub and tree cover is a robust feature across inter-annual differences in meteorological conditions and will likely play an important role in land-atmosphere feedback processes in the future.

  2. The surface tension of aqueous solutions of some atmospheric water-soluble organic compounds

    Science.gov (United States)

    Tuckermann, Rudolf; Cammenga, Heiko K.

    The surface tensions of aqueous solutions of levoglucosan, 3-hydroxybutanoic acid, 3-hydroxybenzoic acid, azelaic acid, pinonic acid, and humic acid have been measured. These compounds are suggested as model substances for the water-soluble organic compounds (WSOC) in atmospheric aerosols and droplets which may play an important role in the aerosol cycle because of their surface-active potentials. The reductions in surface tension induced by single and mixed WSOC in aqueous solution of pure water is remarkable. However, the results of this investigation cannot explain the strong reduction in surface tension in real cloud and fog water samples at concentrations of WSOC below 1 mg/mL.

  3. ANALYTICAL SOLUTION FOR WAVES IN PLANETS WITH ATMOSPHERIC SUPERROTATION. II. LAMB, SURFACE, AND CENTRIFUGAL WAVES

    Energy Technology Data Exchange (ETDEWEB)

    Peralta, J.; López-Valverde, M. A. [Instituto de Astrofísica de Andalucía (CSIC), Glorieta de la Astronomía, 18008 Granada (Spain); Imamura, T. [Institute of Space and Astronautical Science-Japan Aerospace Exploration Agency 3-1-1, Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Read, P. L. [Clarendon Laboratory, Department of Physics, University of Oxford, Parks Road, Oxford (United Kingdom); Luz, D. [Centro de Astronomia e Astrofísica da Universidade de Lisboa (CAAUL), Observatório Astronómico de Lisboa, Tapada da Ajuda, 1349-018 Lisboa (Portugal); Piccialli, A., E-mail: peralta@iaa.es [LATMOS, UVSQ, 11 bd dAlembert, 78280 Guyancourt (France)

    2014-07-01

    This paper is the second in a two-part study devoted to developing tools for a systematic classification of the wide variety of atmospheric waves expected on slowly rotating planets with atmospheric superrotation. Starting with the primitive equations for a cyclostrophic regime, we have deduced the analytical solution for the possible waves, simultaneously including the effect of the metric terms for the centrifugal force and the meridional shear of the background wind. In those cases where the conditions for the method of the multiple scales in height are met, these wave solutions are also valid when vertical shear of the background wind is present. A total of six types of waves have been found and their properties were characterized in terms of the corresponding dispersion relations and wave structures. In this second part, we study the waves' solutions when several atmospheric approximations are applied: Lamb, surface, and centrifugal waves. Lamb and surface waves are found to be quite similar to those in a geostrophic regime. By contrast, centrifugal waves turn out to be a special case of Rossby waves that arise in atmospheres in cyclostrophic balance. Finally, we use our results to identify the nature of the waves behind atmospheric periodicities found in polar and lower latitudes of Venus's atmosphere.

  4. Study on the surface oxidation of uranium in different gaseous atmospheres

    International Nuclear Information System (INIS)

    Wang Xiaoling; Fu Yibei; Xie Renshou

    1996-03-01

    The studying for the surface oxidation of uranium and oxide by X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), secondary ion mass spectroscopy (SIMS), and the surface oxidation of uranium in different gaseous atmospheres such as O 2 , H 2 , CO, CO 2 , H 2 O(v) and air were reviewed. The surface oxidation of uranium is greatly influenced by a number of parameters including atmospheric temperature, pressure, diffusion of adsorbed gas atoms through the oxide layer, surface and interface chemical component, and defect structure and electron nature of the oxide layer. The initial oxidation mechanism and kinetics have been discussed. Suggestions for future work have also been presented. (32 refs., 7 figs., 5 tabs.)

  5. Calculation of the vibration properties of the Pd/Au (111 ordered surface alloy in its stable domain

    Directory of Open Access Journals (Sweden)

    Tigrine R.

    2012-06-01

    Full Text Available In the present paper, a calculation is presented for the vibration properties of the ordered surface alloy alloy Au(111 − (√3×√3R30° − Pd, which is a stable system in the temperature range of 500K to 600K. This surface alloy is formed by depositing Pd atoms onto the Au(111surface, and annealing at higher temperatures. The matching theory is applied to calculate the surface phonons and local vibration densities of states (LDOS for the clean Au (111 surface, and for the Au(111 − (√3×√3R30° − Pd surface alloy. Our theoretical results for the surface phonon branches of the clean Au (111 surface compare favorably with previous ab initio results and experimental data. In contrast, there are no previous results for the vibrational LDOS for the atomic Au site in a clean Au (111 surface, or results for the surface phonons and vibration spectra for the surface alloy. The surface phonons are calculated for the clean Au (111 surface and the ordered surface alloy along three directions of high symmetry, namely, ΓΜ¯, MML:MK¯ $overline {Gamma {m M}} ,{m{ }}overline {{m{MK}}} $ , and KΓ¯ $overline {KGamma } $ . The phonon branches are strongly modified from the Au (111 surface to the surface alloy. In particular a remarkable change takes place for the LDOS between the clean Au (111 surface and the surface alloy, which may find its origin in the charge transfer from Au atoms to Pd atoms.

  6. Influence of atmospheric pressure plasma treatment on surface properties of PBO fiber

    International Nuclear Information System (INIS)

    Zhang Ruiyun; Pan Xianlin; Jiang Muwen; Peng Shujing; Qiu Yiping

    2012-01-01

    Highlights: ► PBO fibers were treated with atmospheric pressure plasmas. ► When 1% of oxygen was added to the plasma, IFSS increased 130%. ► Increased moisture regain could enhance plasma treatment effect on improving IFSS with long treatment time. - Abstract: In order to improve the interfacial adhesion property between PBO fiber and epoxy, the surface modification effects of PBO fiber treated by atmospheric pressure plasma jet (APPJ) in different time, atmosphere and moisture regain (MR) were investigated. The fiber surface morphology, functional groups, surface wettability for control and plasma treated samples were analyzed by scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and water contact angle measurements, respectively. Meanwhile, the fiber interfacial shear strength (IFSS), representing adhesion property in epoxy, was tested using micro-bond pull-out test, and single fiber tensile strength was also tested to evaluate the mechanical performance loss of fibers caused by plasma treatment. The results indicated that the fiber surface was etched during the plasma treatments, the fiber surface wettability and the IFSS between fiber and epoxy had much improvement due to the increasing of surface energy after plasma treatment, the contact angle decreased with the treatment time increasing, and the IFSS was improved by about 130%. The processing atmosphere could influence IFSS significantly, and moisture regains (MR) of fibers also played a positive role on improving IFSS but not so markedly. XPS analysis showed that the oxygen content on fiber surface increased after treatment, and C=O, O-C=O groups were introduced on fiber surface. On the other hand, the observed loss of fiber tensile strength caused by plasma treatment was not so remarkable to affect the overall performance of composite materials.

  7. Doppler lidar investigation of wind turbine wake characteristics and atmospheric turbulence under different surface roughness.

    Science.gov (United States)

    Zhai, Xiaochun; Wu, Songhua; Liu, Bingyi

    2017-06-12

    Four field experiments based on Pulsed Coherent Doppler Lidar with different surface roughness have been carried out in 2013-2015 to study the turbulent wind field in the vicinity of operating wind turbine in the onshore and offshore wind parks. The turbulence characteristics in ambient atmosphere and wake area was analyzed using transverse structure function based on Plane Position Indicator scanning mode. An automatic wake processing procedure was developed to determine the wake velocity deficit by considering the effect of ambient velocity disturbance and wake meandering with the mean wind direction. It is found that the turbine wake obviously enhances the atmospheric turbulence mixing, and the difference in the correlation of turbulence parameters under different surface roughness is significant. The dependence of wake parameters including the wake velocity deficit and wake length on wind velocity and turbulence intensity are analyzed and compared with other studies, which validates the empirical model and simulation of a turbine wake for various atmosphere conditions.

  8. Modeling Plant-Atmosphere Interactions and Ramifications on the Surface Energy Balance in Arctic Ecosystems

    Science.gov (United States)

    Linn, R.; Cunningham, P.; Wilson, C. J.

    2011-12-01

    There is broad recognition that the melting of the permafrost in arctic landscapes could have pronounced global climatological impacts. The evolution of the permafrost and its impacts on the carbon and water balances is directly related to balances in the surface energy budget. There are a number of factors that are expected to impact the net heat flux at the surface of the soil including regional atmospheric conditions. However, ultimately this surface energy balance is controlled by local processes including evaporation from the surface, transpiration from vegetation as well as radiative and convective heat transfer. These four processes are directly impacted by coupling between the vegetation and atmosphere, and thus depend heavily upon the horizontal and vertical vegetation structure. If shrubs replace grasses in the arctic ecosystem there will be net shifts in the heat transfer to the ground. For example, the solar radiation that is absorbed by shrubs is separated from the soil by a stem space through which winds blow. In order for the energy to reach the soil it must warm the air and then warm the soil, however some of the warm air is mixed into the atmosphere and diffused. This structural feature can act in a fashion similar to a closed canopy forest, which frequently have cooler temperatures below the canopy than nearby grasslands An atmospheric hydrodynamics model, HIGRAD, has been enhanced to simulate complex, three-dimensional plant-atmosphere interactions at extremely high resolution (~0.1 m in all three directions). The model represents the transport of momentum, heat, moisture, and CO2 and their exchange between the vegetation and surrounding air. HIGRAD was used to simulate coupled atmosphere/vegetation systems representative of heterogeneous shrub and tussock grass surrounding a thermokarst. In these simulations shrubs, uneven grasses, and a thermokarst depression are explicitly resolved, and atmospheric conditions are similar to those of summer

  9. Fully Integrated Atmospheric, Surface, and Subsurface Model of the California Basin

    Science.gov (United States)

    Davison, J. H.; Hwang, H. T.; Sudicky, E. A.; Mallia, D. V.; Lin, J. C.

    2016-12-01

    The recent drought in the Western United States has crippled agriculture in California's Central Valley. Farmers, facing reduced surface water flow, have turned to groundwater as their primary solution to the water crisis. However, the unsustainable pumping rates seen throughout California have drastically decreased the surface and subsurface water levels. For this reason, we developed a coupled subsurface, surface, and atmospheric model for the entire California Basin that captures the feedbacks between the three domains at an extremely high spatial and temporal resolution. Our coupled model framework integrates HydroGeoSphere (HGS), a fully implicit three-dimensional control-volume finite element surface and variably saturated subsurface model with evapotranspiration process, to Weather Research and Forecasting (WRF), a three-dimensional mesoscale nonhydrostatic atmospheric model. HGS replaces the land surface component within WRF, and provides WRF with the actual evapotranspiration (AET) and soil saturation. In return, WRF provides HGS with the potential evapotranspiration (PET) and precipitation fluxes. The flexible coupling technique allows HGS and WRF to have unique meshing and projection characteristics and links the domains based on their geographic coordinates (i.e., latitude and longitude). The California Basin model successfully simulated similar drawdown rates to the Gravity Recovery and Climate Experiment (GRACE) and replicated the Klamath and Sacramento River hydrographs. Furthermore, our simulation results reproduced field measured precipitation and evapotranspiration. Currently, our coupled California Basin model is the most complete water resource simulator because we combine the surface, subsurface, and atmosphere into a single domain.

  10. Use of Ensemble Numerical Weather Prediction Data for Inversely Determining Atmospheric Refractivity in Surface Ducting Conditions

    Science.gov (United States)

    Greenway, D. P.; Hackett, E.

    2017-12-01

    Under certain atmospheric refractivity conditions, propagated electromagnetic waves (EM) can become trapped between the surface and the bottom of the atmosphere's mixed layer, which is referred to as surface duct propagation. Being able to predict the presence of these surface ducts can reap many benefits to users and developers of sensing technologies and communication systems because they significantly influence the performance of these systems. However, the ability to directly measure or model a surface ducting layer is challenging due to the high spatial resolution and large spatial coverage needed to make accurate refractivity estimates for EM propagation; thus, inverse methods have become an increasingly popular way of determining atmospheric refractivity. This study uses data from the Coupled Ocean/Atmosphere Mesoscale Prediction System developed by the Naval Research Laboratory and instrumented helicopter (helo) measurements taken during the Wallops Island Field Experiment to evaluate the use of ensemble forecasts in refractivity inversions. Helo measurements and ensemble forecasts are optimized to a parametric refractivity model, and three experiments are performed to evaluate whether incorporation of ensemble forecast data aids in more timely and accurate inverse solutions using genetic algorithms. The results suggest that using optimized ensemble members as an initial population for the genetic algorithms generally enhances the accuracy and speed of the inverse solution; however, use of the ensemble data to restrict parameter search space yields mixed results. Inaccurate results are related to parameterization of the ensemble members' refractivity profile and the subsequent extraction of the parameter ranges to limit the search space.

  11. Low-temperature hydrogenation of diamond nanoparticles using diffuse coplanar surface barrier discharge at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Kromka, Alexander; Čech, J.; Kozak, Halyna; Artemenko, Anna; Ižák, Tibor; Čermák, Jan; Rezek, Bohuslav; Černák, M.

    2015-01-01

    Roč. 252, č. 11 (2015), s. 2602-2607 ISSN 0370-1972 R&D Projects: GA ČR(CZ) GBP108/12/G108 Institutional support: RVO:68378271 Keywords : atmospheric plasma * diamond nanoparticles * diffuse coplanar surface barrier discharge * FTIR * XPS Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.522, year: 2015

  12. Out of Thin Air: Microbial Utilization of Atmospheric Gaseous Organics in the Surface Ocean

    KAUST Repository

    Arrieta, Jesus

    2016-01-20

    Volatile and semi-volatile gas-phase organic carbon (GOC) is a largely neglected component of the global carbon cycle, with poorly resolved pools and fluxes of natural and anthropogenic GOC in the biosphere. Substantial amounts of atmospheric GOC are exchanged with the surface ocean, and subsequent utilization of specific GOC compounds by surface ocean microbial communities has been demonstrated. Yet, the final fate of the bulk of the atmospheric GOC entering the surface ocean is unknown. Our data show experimental evidence of efficient use of atmospheric GOC by marine prokaryotes at different locations in the NE Subtropical Atlantic, the Arctic Ocean and the Mediterranean Sea. We estimate that between 2 and 27% of the prokaryotic carbon demand was supported by GOC with a major fraction of GOC inputs being consumed within the mixed layer. The role of the atmosphere as a key vector of organic carbon subsidizing marine microbial metabolism is a novel link yet to be incorporated into the microbial ecology of the surface ocean as well as into the global carbon budget.

  13. Atmospheric moisture's influence on fire behavior: surface moisture and plume dynamics.

    Science.gov (United States)

    Brian E. Potter; Joseph J. Charney; Lesley A. Fusina

    2006-01-01

    Nine measures of atmospheric surface moisture are tested for statistical relationships with fire size and number of fires using data from the Great Lakes region of the United States. The measures include relative humidity, water vapor mixing ratio, mixing ratio deficit, vapor pressure, vapor pressure deficit, dew point temperature, dew point depression, wet bulb...

  14. Oxygen Plasma Treatment of Rubber Surface by the Atmospheric Pressure Cold Plasma Torch

    DEFF Research Database (Denmark)

    Lee, Bong-ju; Kusano, Yukihiro; Kato, Nobuko

    1997-01-01

    A new application of the atmospheric cold plasma torch has been investigated. Namely, the surface treatment of an air-exposed vulcanized rubber compound. The effect of plasma treatment was evaluated by the bondability of the treated rubber compound with another rubber compound using a polyurethane...

  15. Which Surface Atmospheric Variable Drives the Seasonal Cycle of Sea Surface Temperature over the Global Ocean?

    Science.gov (United States)

    2009-03-03

    Hydrographic Clima - tology (PHC) to keep the evaporation-precipitation balance on track in the model. The PHC climatology is chosen for its...give similar SSTs [Kara et al, 2008]. [66] As explained in the text, some corrections are applied to the atmospheric forcing from ERA-40. A clima

  16. Land-atmosphere interactions due to anthropogenic and natural changes in the land surface: A numerical modeling study

    Science.gov (United States)

    Yang, Zhao

    Alterations to the land surface can be attributed to both human activity and natural variability. Human activities, such as urbanization and irrigation, can change the conditions of the land surface by altering albedo, soil moisture, aerodynamic roughness length, the partitioning of net radiation into sensible and latent heat, and other surface characteristics. On the other hand, natural variability, manifested through changes in atmospheric circulation, can also induce land surface changes. These regional scale land surface changes, induced either by humans or natural variability, can effectively modify atmospheric conditions through land-atmosphere interactions. However, only in recent decades have numerical models begun to include representations of the critical processes driving changes at the land surface, and their associated effects on the overlying atmosphere. In this work we explore three mechanisms by which changes to the land surface - both anthropogenic and naturally induced - impact the overlying atmosphere and affect regional hydroclimate. (Abstract shortened by ProQuest.).

  17. Study, using stable isotopes, of flow distribution, surface-groundwater relations and evapotranspiration in the Okavango Swamp, Botswana

    International Nuclear Information System (INIS)

    Dincer, T.; Hutton, L.G.; Kupee, B.B.J.

    1979-01-01

    Stable isotope data collected in the Okavango Delta have confirmed that the central distributary system is more active at present than the peripheral systems. The data also show that there is no groundwater outflow at the western and southern margins of the delta. A salinity-isotope model of the deltaic swamp has been developed to study the relation between the salinity and isotopic composition of the swamp waters. An attempt has been made to separate the atmospheric losses from the swamp into its evapotranspiration components. The results indicate that in winter, when high water levels prevail, these losses are almost entirely due to evaporation whilst in summer, when the water levels are low, evaporation and transpiration contribute almost equally to the total atmospheric losses. (author)

  18. Stepping towards new parameterizations for non-canonical atmospheric surface-layer conditions

    Science.gov (United States)

    Calaf, M.; Margairaz, F.; Pardyjak, E.

    2017-12-01

    Representing land-atmosphere exchange processes as a lower boundary condition remains a challenge. This is partially a result of the fact that land-surface heterogeneity exists at all spatial scales and its variability does not "average" out with decreasing scales. Such variability need not rapidly blend away from the boundary thereby impacting the near-surface region of the atmosphere. Traditionally, momentum and energy fluxes linking the land surface to the flow in NWP models have been parameterized using atmospheric surface layer (ASL) similarity theory. There is ample evidence that such representation is acceptable for stationary and planar-homogeneous flows in the absence of subsidence. However, heterogeneity remains a ubiquitous feature eliciting appreciable deviations when using ASL similarity theory, especially in scalars such moisture and air temperature whose blending is less efficient when compared to momentum. The focus of this project is to quantify the effect of surface thermal heterogeneity with scales Ο(1/10) the height of the atmospheric boundary layer and characterized by uniform roughness. Such near-canonical cases describe inhomogeneous scalar transport in an otherwise planar homogeneous flow when thermal stratification is weak or absent. In this work we present a large-eddy simulation study that characterizes the effect of surface thermal heterogeneities on the atmospheric flow using the concept of dispersive fluxes. Results illustrate a regime in which the flow is mostly driven by the surface thermal heterogeneities, in which the contribution of the dispersive fluxes can account for up to 40% of the total sensible heat flux. Results also illustrate an alternative regime in which the effect of the surface thermal heterogeneities is quickly blended, and the dispersive fluxes provide instead a quantification of the flow spatial heterogeneities produced by coherent turbulent structures result of the surface shear stress. A threshold flow

  19. Coupled atmosphere and land-surface assimilation of surface observations with a single column model and ensemble data assimilation

    Science.gov (United States)

    Rostkier-Edelstein, Dorita; Hacker, Joshua P.; Snyder, Chris

    2014-05-01

    Numerical weather prediction and data assimilation models are composed of coupled atmosphere and land-surface (LS) components. If possible, the assimilation procedure should be coupled so that observed information in one module is used to correct fields in the coupled module. There have been some attempts in this direction using optimal interpolation, nudging and 2/3DVAR data assimilation techniques. Aside from satellite remote sensed observations, reference height in-situ observations of temperature and moisture have been used in these studies. Among other problems, difficulties in coupled atmosphere and LS assimilation arise as a result of the different time scales characteristic of each component and the unsteady correlation between these components under varying flow conditions. Ensemble data-assimilation techniques rely on flow dependent observations-model covariances. Provided that correlations and covariances between land and atmosphere can be adequately simulated and sampled, ensemble data assimilation should enable appropriate assimilation of observations simultaneously into the atmospheric and LS states. Our aim is to explore assimilation of reference height in-situ temperature and moisture observations into the coupled atmosphere-LS modules(simultaneously) in NCAR's WRF-ARW model using the NCAR's DART ensemble data-assimilation system. Observing system simulation experiments (OSSEs) are performed using the single column model (SCM) version of WRF. Numerical experiments during a warm season are centered on an atmospheric and soil column in the South Great Plains. Synthetic observations are derived from "truth" WRF-SCM runs for a given date,initialized and forced using North American Regional Reanalyses (NARR). WRF-SCM atmospheric and LS ensembles are created by mixing the atmospheric and soil NARR profile centered on a given date with that from another day (randomly chosen from the same season) with weights drawn from a logit-normal distribution. Three

  20. The Effect of Bond Albedo on Venus' Atmospheric and Surface Temperatures

    Science.gov (United States)

    Bullock, M. A.; Limaye, S. S.; Grinspoon, D. H.; Way, M.

    2017-12-01

    In spite of Venus' high planetary albedo, sufficient solar energy reaches the surface to drive a powerful greenhouse effect. The surface temperature is three times higher than it would be without an atmosphere. However, the details of the energy balance within Venus' atmosphere are poorly understood. Half of the solar energy absorbed within the clouds, where most of the solar energy is absorbed, is due to an unknown agent. One of the challenges of modeling Venus' atmosphere has been to account for all the sources of opacity sufficient to generate a globally averaged surface temperature of 735 K, when only 2% of the incoming solar energy is deposited at the surface. The wavelength and spherically integrated albedo, or Bond albedo, has typically been cited as between 0.7 and 0.82 (Colin 1983). Yet, recent photometry of Venus at extended phase angles between 2 and 179° indicate a Bond albedo of 0.90 (Mallama et al., 2006). The authors note an increase in cloud top brightness at phase angles right). Venus surface temperature as Bond Albedo changes. Radiative-convective equilibrium models predict the correct globally averaged surface temperature at a=0.81. Calculations here show that a Bond albedo of a=0.9 would yield a surface temperature of 666.4 K, about 70 K too low, unless there is additional thermal absorption within the atmosphere that is not understood. Colin, L.,, Venus, University of Arizona Press, Tucson, 1983, pp 10-26. Mallama, A., et al., 2006. Icarus. 182, 10-22.

  1. Improved adhesion of Ag NPs to the polyethylene terephthalate surface via atmospheric plasma treatment and surface functionalization

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Tao [Faculty of Materials Science and Engineering, Kunming University of Science and Technology, 253 Xuefu Rd, Kunming, Yunnan, 650093 (China); Liu, Yong [Faculty of Materials Science and Engineering, Kunming University of Science and Technology, 253 Xuefu Rd, Kunming, Yunnan, 650093 (China); Solmont Technology Wuxi Co., Ltd. 228 Linghu Blvd. Tianan Tech Park, A1-602, Xinwu District, Wuxi, Jiangsu 214135 (China); Zhu, Yan, E-mail: zhuyan@kmust.edu.cn [Faculty of Materials Science and Engineering, Kunming University of Science and Technology, 253 Xuefu Rd, Kunming, Yunnan, 650093 (China); Yang, De-Quan, E-mail: dequan.yang@gmail.com [Faculty of Materials Science and Engineering, Kunming University of Science and Technology, 253 Xuefu Rd, Kunming, Yunnan, 650093 (China); Solmont Technology Wuxi Co., Ltd. 228 Linghu Blvd. Tianan Tech Park, A1-602, Xinwu District, Wuxi, Jiangsu 214135 (China); Sacher, Edward [Regroupement Québécois de Matériaux de Pointe, Department of Engineering Physics, École Polytechnique de Montréal, Case Postale 6079, succursale Centre-Ville, Montréal, Québec H3C 3A7 (Canada)

    2017-07-31

    Highlights: • A two-step process has been developed to enhance the adhesion of immobilized Ag NPs to the PET surface. • The method is simple, easy to use and low-cost for mass production. • The increased density of active sites (−OH, −CH=O and COOH) at the PET surface, after plasma treatment, permits increased reaction with 3-aminopropyltriethoxysilane (APTES). • The presence of APTES with high surface density permits −NH{sub 2}-Ag complex formation, increasing the adhesion of the Ag NPs. - Abstract: Ag nanoparticles (NPs) have been widely applied, as important antibacterial materials, on textile and polymer surfaces. However, their adhesion to nonreactive polymer surfaces is generally too weak for many applications. Here, we propose a two-step process, atmospheric plasma treatment followed by a surface chemical modification process, which enhances their adhesion to polyethylene terephthalate (PET) surfaces. We found that, compared to either plasma treatments or surface chemical functionalizations, alone, this combination greatly enhanced their adhesion. The plasma treatment resulted in an increase of active sites (−OH, −CH=O and COOH) at the PET surface, permitting increased bonding to 3-aminopropyltriethoxysilane (APTES), whose −NH{sub 2} groups were then able to form a bonding complex with the Ag NPs.

  2. A stable high-order perturbation of surfaces method for numerical simulation of diffraction problems in triply layered media

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Youngjoon, E-mail: hongy@uic.edu; Nicholls, David P., E-mail: davidn@uic.edu

    2017-02-01

    The accurate numerical simulation of linear waves interacting with periodic layered media is a crucial capability in engineering applications. In this contribution we study the stable and high-order accurate numerical simulation of the interaction of linear, time-harmonic waves with a periodic, triply layered medium with irregular interfaces. In contrast with volumetric approaches, High-Order Perturbation of Surfaces (HOPS) algorithms are inexpensive interfacial methods which rapidly and recursively estimate scattering returns by perturbation of the interface shape. In comparison with Boundary Integral/Element Methods, the stable HOPS algorithm we describe here does not require specialized quadrature rules, periodization strategies, or the solution of dense non-symmetric positive definite linear systems. In addition, the algorithm is provably stable as opposed to other classical HOPS approaches. With numerical experiments we show the remarkable efficiency, fidelity, and accuracy one can achieve with an implementation of this algorithm.

  3. Athletes trained using stable compared to unstable surfaces exhibit distinct postural control profiles when assessed by traditional and nonlinear measures.

    Science.gov (United States)

    Powell, Douglas W; Williams, D S Blaise

    2015-12-01

    Athletes are assumed to exhibit better balance than non-athletes; however, few studies have examined the role of different types of sports on balance measures. Two athlete groups that experience divergent sport-specific balance training are stable- (i.e. basketball) and unstable-surface athletes (i.e. surfers). The purpose of this study was to quantify the effect of stable- compared to unstable-surface sports on postural stability. Eight non-athletes (NON), eight stable-surface athletes (SSA) and eight unstable-surface athletes (USA) performed five 20-s quiet standing trials while ground reaction forces were recorded. Approximate entropy (ApEn), total excursion and root mean square distances (RMS) of the center of pressure position were calculated. Univariate ANOVAs with post hoc tests were conducted for each variable. ApEn values were lower in SSA compared to NON in the ML direction (p=0.012) and USA had lower ApEn values compared to SSA in the AP direction (p=0.036). The USA had smaller AP RMS compared to SSA (p=0.002) while the USA had greater ML RMS (p=0.008) and resultant RMS values compared to SSA (p=0.025). These data suggest that USA and SSA may exhibit direction-specific differences in balance strategy due to feedback paradigm. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Surface chemical changes of atmospheric pressure plasma treated rabbit fibres important for felting process

    International Nuclear Information System (INIS)

    Štěpánová, Vlasta; Slavíček, Pavel; Stupavská, Monika; Jurmanová, Jana; Černák, Mirko

    2015-01-01

    Graphical abstract: - Highlights: • Rabbit fibres plasma treatment is an effective method for fibres modification. • Atmospheric pressure plasma treatment is able to affect fibres properties. • Surface changes on fibres after plasma treatment were analysed via SEM, ATR-FTIR, XPS. • Significant increase of fibres wettability after plasma treatment was observed. • Plasma treatment at atmospheric pressure can replace the chemical treatment of fibres. - Abstract: We introduce the atmospheric pressure plasma treatment as a suitable procedure for in-line industrial application of rabbit fibres pre-treatment. Changes of rabbit fibre properties due to the plasma treatment were studied in order to develop new technology of plasma-based treatment before felting. Diffuse Coplanar Surface Barrier Discharge (DCSBD) in ambient air at atmospheric pressure was used for plasma treatment. Scanning electron microscopy was used for determination of the fibres morphology before and after plasma treatment. X-ray photoelectron spectroscopy and attenuated total reflectance-Fourier transform infrared spectroscopy were used for evaluation of reactive groups. The concentration of carbon decreased and conversely the concentration of nitrogen and oxygen increased after plasma treatment. Aging effect of plasma treated fibres was also investigated. Using Washburn method the significant increase of fibres wettability was observed after plasma treatment. New approach of pre-treatment of fibres before felting using plasma was developed. Plasma treatment of fibres at atmospheric pressure can replace the chemical method which consists of application of strong acids on fibres.

  5. Lavoisier: A Low Altitude Balloon Network for Probing the Deep Atmosphere and Surface of Venus

    Science.gov (United States)

    Chaasefiere, E.; Berthelier, J. J.; Bertaux, J.-L.; Quemerais, E.; Pommereau, J.-P.; Rannou, P.; Raulin, F.; Coll, P.; Coscia, D.; Jambon, A.; hide

    2005-01-01

    The in-situ exploration of the low atmosphere and surface of Venus is clearly the next step of Venus exploration. Understanding the geochemistry of the low atmosphere, interacting with rocks, and the way the integrated Venus system evolved, under the combined effects of inner planet cooling and intense atmospheric greenhouse, is a major challenge of modern planetology. Due to the dense atmosphere (95 bars at the surface), balloon platforms offer an interesting means to transport and land in-situ measurement instruments. Due to the large Archimede force, a 2 cubic meter He-pressurized balloon floating at 10 km altitude may carry up to 60 kg of payload. LAVOISIER is a project submitted to ESA in 2000, in the follow up and spirit of the balloon deployed at cloud level by the Russian Vega mission in 1986. It is composed of a descent probe, for detailed noble gas and atmosphere composition analysis, and of a network of 3 balloons for geochemical and geophysical investigations at local, regional and global scales.

  6. Surface chemical changes of atmospheric pressure plasma treated rabbit fibres important for felting process

    Energy Technology Data Exchange (ETDEWEB)

    Štěpánová, Vlasta, E-mail: vstepanova@mail.muni.cz [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Slavíček, Pavel; Stupavská, Monika; Jurmanová, Jana [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Černák, Mirko [Department of Physical Electronics, Faculty of Science Masaryk University, Kotlářská 2, 611 37 Brno (Czech Republic); Department of Experimental Physics, Faculty of Mathematics, Physics and Informatics, Comenius University, Mlynská dolina F2, 842 48 Bratislava (Slovakia)

    2015-11-15

    Graphical abstract: - Highlights: • Rabbit fibres plasma treatment is an effective method for fibres modification. • Atmospheric pressure plasma treatment is able to affect fibres properties. • Surface changes on fibres after plasma treatment were analysed via SEM, ATR-FTIR, XPS. • Significant increase of fibres wettability after plasma treatment was observed. • Plasma treatment at atmospheric pressure can replace the chemical treatment of fibres. - Abstract: We introduce the atmospheric pressure plasma treatment as a suitable procedure for in-line industrial application of rabbit fibres pre-treatment. Changes of rabbit fibre properties due to the plasma treatment were studied in order to develop new technology of plasma-based treatment before felting. Diffuse Coplanar Surface Barrier Discharge (DCSBD) in ambient air at atmospheric pressure was used for plasma treatment. Scanning electron microscopy was used for determination of the fibres morphology before and after plasma treatment. X-ray photoelectron spectroscopy and attenuated total reflectance-Fourier transform infrared spectroscopy were used for evaluation of reactive groups. The concentration of carbon decreased and conversely the concentration of nitrogen and oxygen increased after plasma treatment. Aging effect of plasma treated fibres was also investigated. Using Washburn method the significant increase of fibres wettability was observed after plasma treatment. New approach of pre-treatment of fibres before felting using plasma was developed. Plasma treatment of fibres at atmospheric pressure can replace the chemical method which consists of application of strong acids on fibres.

  7. Io meteorology - How atmospheric pressure is controlled locally by volcanos and surface frosts

    Science.gov (United States)

    Ingersoll, Andrew P.

    1989-01-01

    The present modification of the Ingersoll et al. (1985) hydrodynamic model of the SO2 gas sublimation-driven flow from the day to the night side of Io includes the effects of nonuniform surface properties noted in observational studies. Calculations are conducted for atmospheric pressures, horizontal winds, sublimation rates, and condensation rates for such surface conditions as patchy and continuous frost cover, volcanic venting, surface temperature discontinuities, subsurface cold trapping, and the propagation of insolation into the frost. While pressure is found to follow local vapor pressure away from the plumes, it becomes higher inside them.

  8. Surface modification of nanofibrillated cellulose films by atmospheric pressure dielectric barrier discharge

    DEFF Research Database (Denmark)

    Siró, Istvan; Kusano, Yukihiro; Norrman, Kion

    2013-01-01

    of atmospheric pressure plasma treatment, the water contact angle of NFC films increased and the values were comparable with those of PLA films. On the other hand, surface chemical characterization revealed inhomogeneity of the plasma treatment and limited improvement in adhesion between NFC and PLA films......A dielectric barrier discharge in a gas mixture of tetrafluoromethane (CF4) and O2 was used for tailoring the surface properties of nanofibrillated cellulose (NFC) films. The surface chemical composition of plasma-modified NFC was characterized by means of X-ray photoelectron spectroscopy and time....... Further research in this direction is required in order to enhance the uniformity of the plasma treatment results....

  9. Atmospheric-Pressure Plasma Jet Surface Treatment for Use in Improving Adhesion

    Energy Technology Data Exchange (ETDEWEB)

    Kuettner, Lindsey Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2017-09-06

    Atmospheric-pressure plasma jets (APPJs) are a method of plasma treatment that plays an important role in material processing and modifying surface properties of materials, especially polymers. Gas plasmas react with polymer surfaces in numerous ways such as oxidation, radical formation, degradation, and promotion of cross-linking. Because of this, gas and plasma conditions can be explored for chosen processes to maximize desired properties. The purpose of this study is to investigate plasma parameters in order to modify surface properties for improved adhesion between aluminum and epoxy substrates using two types of adhesives. The background, results to date, and future work will be discussed.

  10. Production of stable superhydrophilic surfaces on 316L steel by simultaneous laser texturing and SiO2 deposition

    Science.gov (United States)

    Rajab, Fatema H.; Liu, Zhu; Li, Lin

    2018-01-01

    Superhydrophilic surfaces with liquid contact angles of less than 5 ° have attracted much interest in practical applications including self-cleaning, cell manipulation, adhesion enhancement, anti-fogging, fluid flow control and evaporative cooling. Standard laser metal texturing method often result in unstable wetting characteristics, i.e. changing from super hydrophilic to hydrophobic in a few days or weeks. In this paper, a simple one step method is reported for fabricating a stable superhydrophilic metallic surface that lasted for at least 6 months. Here, 316L stainless steel substrates were textured using a nanosecond laser with in-situ SiO2 deposition. Morphology and chemistry of laser-textured surfaces were characterised using SEM, XRD, XPS and an optical 3D profiler. Static wettability analysis was carried out over a period of 6 months after the laser treatment. The effect of surface roughness on wettability was also studied. Results showed that the wettability of the textured surfaces could be controlled by changing the scanning speed of laser beam and number of passes. The main reason for the realisation of the stable superhydrophilic surface is the combination of the melted glass particles mainly Si and O with that of stainless steel in the micro-textured patterns. This study presents a useful method

  11. Soil surface acidity plays a determining role in the atmospheric-terrestrial exchange of nitrous acid.

    Science.gov (United States)

    Donaldson, Melissa A; Bish, David L; Raff, Jonathan D

    2014-12-30

    Nitrous acid (HONO) is an important hydroxyl (OH) radical source that is formed on both ground and aerosol surfaces in the well-mixed boundary layer. Recent studies report the release of HONO from nonacidic soils, although it is unclear how soil that is more basic than the pKa of HONO (∼ 3) is capable of protonating soil nitrite to serve as an atmospheric HONO source. Here, we used a coated-wall flow tube and chemical ionization mass spectrometry (CIMS) to study the pH dependence of HONO uptake onto agricultural soil and model substrates under atmospherically relevant conditions (1 atm and 30% relative humidity). Experiments measuring the evolution of HONO from pH-adjusted surfaces treated with nitrite and potentiometric titrations of the substrates show, to our knowledge for the first time, that surface acidity rather than bulk aqueous pH determines HONO uptake and desorption efficiency on soil, in a process controlled by amphoteric aluminum and iron (hydr)oxides present. The results have important implications for predicting when soil nitrite, whether microbially derived or atmospherically deposited, will act as a net source or sink of atmospheric HONO. This process represents an unrecognized mechanism of HONO release from soil that will contribute to HONO emissions throughout the day.

  12. Facile Fabrication and Characterization of a PDMS-Derived Candle Soot Coated Stable Biocompatible Superhydrophobic and Superhemophobic Surface.

    Science.gov (United States)

    Iqbal, R; Majhy, B; Sen, A K

    2017-09-13

    We report a simple, inexpensive, rapid, and one-step method for the fabrication of a stable and biocompatible superhydrophobic and superhemophobic surface. The proposed surface comprises candle soot particles embedded in a mixture of PDMS+n-hexane serving as the base material. The mechanism responsible for the superhydrophobic behavior of the surface is explained, and the surface is characterized based on its morphology and elemental composition, wetting properties, mechanical and chemical stability, and biocompatibility. The effect of %n-hexane in PDMS, the thickness of the PDMS+n-hexane layer (in terms of spin coating speed) and sooting time on the wetting property of the surface is studied. The proposed surface exhibits nanoscale surface asperities (average roughness of 187 nm), chemical compositions of soot particles, very high water and blood repellency along with excellent mechanical and chemical stability and excellent biocompatibility against blood sample and biological cells. The water contact angle and roll-off angle is measured as 160° ± 1° and 2°, respectively, and the blood contact angle is found to be 154° ± 1°, which indicates that the surface is superhydrophobic and superhemophobic. The proposed superhydrophobic and superhemophobic surface offers significantly improved (>40%) cell viability as compared to glass and PDMS surfaces.

  13. NPP/VIIRS Atmospherically Corrected Surface Reflectance 6-Min L2 Swath 375m, 750m NRT

    Data.gov (United States)

    National Aeronautics and Space Administration — The VNP09_NRT is a Near Real Time (NRT) S-NPP/VIIRS 375 m, 750 m Atmospherically Corrected Surface Reflectance product. The NPP/VIIRS surface reflectance products...

  14. Venus surface peeking through the atmosphere - gaining a global perspective on the surface composition through near infrared observations

    Science.gov (United States)

    Helbert, J.; Dyar, M. D.; Maturilli, A.; D'Amore, M.; Ferrari, S.; Mueller, N. T.; Smrekar, S. E.

    2017-12-01

    Venus is the most Earth-like of the terrestrial planets, though very little is known about its surface composition. Thanks to recent advances in laboratory spectroscopy and spectral analysis techniques, this is about to change. Although the atmosphere prohibits observations of the surface with traditional imaging techniques over much of the EM spectral range, five transparent windows between 0.86 µm and 1.18 µm occur in the atmosphere's CO2 spectrum. New high temperature laboratory spectra from the Planetary Spectroscopy Laboratory at DLR show that spectra in these windows are highly diagnostic for surface mineralogy [1]. The Venus Emissivity Mapper (VEM) [2] builds on these recent advances. It is proposed for NASA's Venus Origins Explorer where a radar will provided the needed high-resolution altimetry and ESA's EnVision would provide stereo topography instead. VEM is the first flight instrument specially designed to focus solely on mapping Venus' surface using the windows around 1 µm. Operating in situ from Venus orbit, VEM will provide a global map of composition as well as redox state of the surface, enabling a comprehensive picture of surface-atmosphere interaction on Venus. VEM will return a complex data set containing surface, atmospheric, cloud, and scattering information. Total planned data volume for a typical mission scenario exceeds 1TB. Classical analysis techniques have been successfully used for VIRTIS on Venus Express [3-5] and could be employed with the VEM data. However, application of machine learning approaches to this rich dataset is vastly more efficient, as has already been confirmed with laboratory data. Binary classifiers [6] demonstrate that at current best estimate errors, basalt spectra are confidently discriminated from basaltic andesites, andesites, and rhyolite/granite. Applying the approach of self-organizing maps to the increasingly large set of laboratory measurements allows searching for additional mineralogical indicators

  15. Fourier transform spectrometers for remote sensing of planetary atmospheres and surfaces

    Science.gov (United States)

    Shakun, Alexey; Korablev, Oleg; Moshkin, Boris; Grigoriev, Alexey; Ignatiev, Nikolay; Maslov, Igor; Sazonov, Oleg; Patsaev, Dmitry; Kungurov, Andrey; Santos-Skripko, Alexander; Zharkov, Alexander; Stupin, Igor; Merzlyakov, Dmitry; Makarov, Vladislav; Martinovich, Fedor; Nikolskiy, Yuri; Shashkin, Victor

    2017-12-01

    In planetary research, Fourier transform infrared spectrometers (FTIR) solve a number of important scientific goals related both to the atmosphere and to the surface sounding. For remote orbital measurements, these goals are the thermal sounding of the atmosphere using, in particular, the 15-µm CO2 band, sensitive detections of minor gaseous species and aerosol characterization. FTIR can address similar atmospheric science goals when observing from a planetary surface allowing for better-resolved boundary layer and achieving greater accuracy (longer integration) for minor species detection. For studies of planetary surfaces, characterization of mineralogical composition in a wide IR range including sensitive measurements of hydration of the soil on airless bodies can be done. We outline a family of FTIR instruments dedicated to studies of Mars and the Moon. TIRVIM is a channel of ACS on ExoMars TGO (in orbit around Mars since October 2016). It is a 2-inch interferometer for nadir and solar occultation measurements of Mars' atmosphere. It covers a spectral range of 1.7-17 µm with spectral resolution up to 0.13 cm-1. LUMIS is a similar instrument for Luna-Resource Orbiter (Luna-26) Roscosmos mission dedicated to the search for hydration of the lunar regolith in the 6-µm band. The spectral range of LUMIS is broad (1.7-17 µm), but its sensitivity is optimized for the 4-8 µm region. The spectral resolution is 50 cm-1. We also describe recent developments focused on technical solutions for miniaturized FTIR instruments with a very high spectral resolution (0.05 cm-1 and higher). The prototype targets measurements of minor atmospheric species from the surface of Mars using the Sun tracking. One important task is to provide a high precision of interferometer's mirror movement. Another task is the development of a precise two-coordinate mechanism to seek for and follow the Sun.

  16. Stable, metastable and unstable solutions of a spin-1 Ising system based on the free energy surfaces

    Science.gov (United States)

    Keskİin, Mustafa; Özgan, Şükrü

    1990-04-01

    Stable, metastable and unstable solutions of a spin-1 Ising model with bilinear and biquadratic interactions are found by using the free energy surfaces. The free energy expression is obtained in the lowest approximation of the cluster variation method. All these solutions are shown in the two-dimensional phase space, especially the unstable solutions which in some cases are difficult to illustrate in the two-dimensional phase space, found by Keskin et al. recently.

  17. Effects of Near-Surface Atmospheric Stability and Moisture on Wildfire Behavior and Consequences for Haines Index

    Science.gov (United States)

    Ruiyu Sun; Mary Ann Jenkins

    2003-01-01

    Since the 1950s, extensive research has been conducted to investigate the relationship between near-surface atmospheric conditions and large wildfire growth and occurrence. Observational studies have demonstrated that near-surface dryness (e-g., Fahnestock 1965) and atmospheric instability (e-g., Brotak and Reifsnyder 1977) are correlated with large wildfire growth and...

  18. Nocturnal surface ozone enhancement over Portugal during winter: Influence of different atmospheric conditions

    KAUST Repository

    Kulkarni, Pavan S.

    2016-09-24

    Four distinct nocturnal surface ozone (NSO) enhancement events were observed, with NSO concentration exceeding 80μg/m3, at multiple ozone (O3) monitoring stations (32 sites) in January, November and December between year 2000–2010, in Portugal. The reasonable explanation for the observed bimodal pattern of surface ozone with enhanced NSO concentration during nighttime has to be transport processes, as the surface ozone production ceases at nighttime. Simultaneous measurements of O3 at multiple stations during the study period in Portugal suggest that horizontal advection alone cannot explain the observed NSO enhancement. Thus, detailed analysis of the atmospheric conditions, simulated with the Weather Research and Forecasting (WRF) model, were performed to evaluate the atmospheric mechanisms responsible for NSO enhancement in the region. Simulations revealed that each event occurred as a result of one or the combination of different atmospheric processes such as, passage of a cold front followed by a subsidence zone; passage of a moving surface trough, with associated strong horizontal wind speed and vertical shear; combination of vertical and horizontal transport at the synoptic scale; formation of a low level jet with associated vertical mixing below the jet stream. The study confirmed that large-scale flow pattern resulting in enhanced vertical mixing in the nocturnal boundary layer, plays a key role in the NSO enhancement events, which frequently occur over Portugal during winter months. © 2016 Elsevier Ltd

  19. A Study of Atmospheric Plasma Treatment on Surface Energetics of Carbon Fibers

    International Nuclear Information System (INIS)

    Park, Soo Jin; Chang, Yong Hwan; Moon, Cheol Whan; Suh, Dong Hack; Im, Seung Soon; Kim, Yeong Cheol

    2010-01-01

    In this study, the atmospheric plasma treatment with He/O 2 was conducted to modify the surface chemistry of carbon fibers. The effects of plasma treatment parameters on the surface energetics of carbon fibers were experimentally investigated with respect to gas flow ratio, power intensity, and treatment time. Surface characteristics of the carbon fibers were determined by X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), Fourier transform infrared (FT-IR), Zeta-potential, and contact angle measurements. The results indicated that oxygen plasma treatment led to a large amount of reactive functional groups onto the fiber surface, and these groups can form together as physical intermolecular bonding to improve the surface wettability with a hydrophilic polymer matrix

  20. Bombs and Flares at the Surface and Lower Atmosphere of the Sun

    Energy Technology Data Exchange (ETDEWEB)

    Hansteen, V. H.; Pereira, T. M. D.; Carlsson, M.; Van der Voort, L. Rouppe [Institute of Theoretical Astrophysics, University of Oslo, Norway, PB 1029 Blindern, NO-0315 Oslo (Norway); Archontis, V. [School of Mathematics and Statistics, St. Andrews University, St. Andrews, KY169SS (United Kingdom); Leenaarts, J. [Institute for Solar Physics, Dept. of Astronomy, Stockholm University, Roslagstullbacken 21 SE-10691 Stockholm (Sweden)

    2017-04-10

    A spectacular manifestation of solar activity is the appearance of transient brightenings in the far wings of the H α line, known as Ellerman bombs (EBs). Recent observations obtained by the Interface Region Imaging Spectrograph have revealed another type of plasma “bombs” (UV bursts) with high temperatures of perhaps up to 8 × 10{sup 4} K within the cooler lower solar atmosphere. Realistic numerical modeling showing such events is needed to explain their nature. Here, we report on 3D radiative magnetohydrodynamic simulations of magnetic flux emergence in the solar atmosphere. We find that ubiquitous reconnection between emerging bipolar magnetic fields can trigger EBs in the photosphere, UV bursts in the mid/low chromosphere and small (nano-/micro-) flares (10{sup 6} K) in the upper chromosphere. These results provide new insights into the emergence and build up of the coronal magnetic field and the dynamics and heating of the solar surface and lower atmosphere.

  1. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Mamede, Anne-Sophie, E-mail: anne-sophie.mamede@ensc-lille.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Nuns, Nicolas, E-mail: nicolas.nuns@univ-lille1.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Cristol, Anne-Lise, E-mail: anne-lise.cristol@ec-lille.fr [University Lille, CNRS, Centrale Lille, Arts et Métiers Paris Tech, FRE 3723 – LML – Laboratoire de Mécanique de Lille, F-59000 Lille (France); Cantrel, Laurent, E-mail: laurent.cantrel@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); Souvi, Sidi, E-mail: sidi.souvi@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); and others

    2016-04-30

    Graphical abstract: - Highlights: • Mutitechnique characterisation of oxidised 304L. • Oxidation at high temperature under steam and air conditions of 304L stainless steel. • Chromium and manganese oxides formed in the outer layer. • Oxide profiles differ in air or steam atmosphere. - Abstract: In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8–12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe{sub 2}O{sub 3} oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  2. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    International Nuclear Information System (INIS)

    Mamede, Anne-Sophie; Nuns, Nicolas; Cristol, Anne-Lise; Cantrel, Laurent; Souvi, Sidi

    2016-01-01

    Graphical abstract: - Highlights: • Mutitechnique characterisation of oxidised 304L. • Oxidation at high temperature under steam and air conditions of 304L stainless steel. • Chromium and manganese oxides formed in the outer layer. • Oxide profiles differ in air or steam atmosphere. - Abstract: In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8–12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe 2 O 3 oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  3. Assessment of the relation between atmospheric precipitation and rainwater runoff for various urban surfaces

    Directory of Open Access Journals (Sweden)

    Romaniak Alicja

    2017-03-01

    Full Text Available The relation between the diurnal sum of atmospheric precipitation and the diurnal volume of rainwater runoff from four experimental hardened surfaces was the subject of a pilot study conducted within the area of the Departmental Agro- and Hydrometeorology Observatory in Wrocław. The selection and the structure of the experimental surfaces were preceded with an inventory-taking of the coverage of hardened surfaces within a Wrocław housing estate with high-rise multifamily buildings. That estate was the second location, next to the area of the Observatory, at which the study presented here was conducted. The surfaces included in the experiment were roof surfaces P1 and P2 covered with heat-sealable roll roofing, surface APB made of gravel-filled openwork concrete plates, and tarmac surface AS. The pilot study was conducted during the period from April to November, 2014. During that period, depending on the type of experimental surface, from 81 to 87 days with atmospheric precipitation were analysed. The mean values of the rainwater runoff coefficients for the eightmonth period were 0.77, 0.77, 0.33 and 0.67 for surfaces P1, P2, APB and AS, respectively. The range of variability of mean values of the coefficients of rainwater runoff from the experimental surfaces in a month is presented by the following relation: APB > P1 > AS > P2. The study did not reveal any direct effect of the number of rainfall days in a month on the value of the coefficient of determination describing the correlation between the diurnal sums of precipitation and the diurnal volumes of rainwater runoff.

  4. Surface treatment of aramid fiber by air dielectric barrier discharge plasma at atmospheric pressure

    International Nuclear Information System (INIS)

    Jia Caixia; Chen Ping; Liu Wei; Li Bin; Wang Qian

    2011-01-01

    Aramid fiber samples are treated by air dielectric barrier discharge (DBD) plasma at atmospheric pressure; the plasma treatment time is investigated as the major parameter. The effects of this treatment on the fiber surface physical and chemical properties are studied by using surface characterization techniques. Scanning electron microscopy (SEM) is performed to determine the surface morphology changes, X-ray photoelectron spectroscopy (XPS) is analyzed to reveal the surface chemical composition variations and dynamic contact angle analysis (DCAA) is used to examine the changes of the fiber surface wettability. In addition, the wetting behavior of a kind of thermoplastic resin, poly(phthalazinone ether sulfone ketone) (PPESK), on aramid fiber surface is also observed by SEM photos. The study shows that there seems to be an optimum treatment condition for surface modification of aramid fiber by the air DBD plasma. In this paper, after the 12 s, 27.6 W/cm 3 plasma treatment the aramid fiber surface roughness is significantly improved, some new oxygen-containing groups such as C-O, C=O and O=C-O are generated on the fiber surface and the fiber surface wettability is greatly enhanced, which results in the better wetting behavior of PPESK resin on the plasma-treated aramid fiber.

  5. Surface modification of polytetrafluoroethylene film using the atmospheric pressure glow discharge in air

    International Nuclear Information System (INIS)

    Fang, Z; Qiu, Y; Luo, Y

    2003-01-01

    The atmospheric pressure glow discharge (APGD) is more promising in industrial applications compared with glow discharges in a gas other than air or in low-pressure air, which needs an expensive vacuum system. In this paper, the APGD and dielectric barrier discharge (DBD) are generated in atmospheric air using a power-frequency voltage source, and the transition from DBD to APGD is achieved by varying the electrode arrangement. The differences between their discharge characteristics are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena. The effects of APGD and DBD on polytetrafluoroethylene (PTFE) surface modification are studied. The surface properties are characterized by contact angle measurement, x-ray photoelectron spectroscopy and scanning electron microscopy. It is found that the APGD and DBD treatments modify the PTFE surface in both morphology and composition. APGD is more effective in PTFE surface modification than DBD as it can modify the surface more uniformly, implant more oxygen atoms into the surface and make the contact angle decline to a lower level. The experimental results are discussed

  6. Screening models for releases of radionuclides to atmosphere, surface water, and ground -- Work sheets

    International Nuclear Information System (INIS)

    1996-01-01

    Three levels of screening for the atmospheric transport pathways and two levels for surface water are presented. The ground has only one screening level. Level 1 is the simplest approach and incorporates a high degree of conservatism. The estimate of the effective dose for this level assumes a concentration based upon the radionuclide concentration at the point of emission to the environment, i.e., at the stack for atmospheric emissions, at the end of the effluent pipe for liquid effluent releases, and at a well because of the buried radioactive material. Levels 2 and 3 are presented for atmospheric releases, and Level 2 for surface water releases only and are more detailed and correspondingly less conservative. Level 2 screening accounts for dispersion in the atmosphere and in surface waters and combines all recognized pathways into the screening factor. For the atmospheric pathway, Level 3 screening includes more definitive pathways analysis. Should the user be found in compliance on the basis of Level 1 screening, no further calculations are required. If the user fails Level 1, the user proceeds to the next level and checks for compliance. This process is repeated until the user passes screening (is in compliance) or no further screening levels exist. If the user fails the final level, professional assistance should be obtained in environmental radiological assessment. Work sheets are designed to lead the user through screening in a step-by-step manner until compliance is demonstrated or it is determined that more sophisticated methods or expertise are needed. Flow diagrams are provided as a guide to identify key steps in the screening process

  7. Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels

    Science.gov (United States)

    Susskind,Joel

    2009-01-01

    AIRS was launched on EOS Aqua on May 4, 2002, together with AMSU-A and HSB, to form a next generation polar orbiting infrared and microwave atmospheric sounding system. AIRS is a grating spectrometer with a number of linear arrays of detectors with each detector sensitive to outgoing radiation in a characteristic frequency v(sub i) with a spectral band pass delta v(sub i) of roughly v(sub i) /1200. AIRS contains 2378 spectral channels covering portions of the spectral region 650 cm(exp -1) (15.38 gm) - 2665 cm(exp -1)' (3.752 micrometers). These spectral regions contain significant absorption features from two CO2 absorption bands, the 15 micrometer (longwave) CO2 band, and the 4.3 micrometer (shortwave) CO, absorption band. There are also two atmospheric window regions, the 12 micrometerm - 8 micrometer (longwave) window, and the 4.17 micrometer - 3.75 micrometer (shortwave) window. Historically, determination of surface and atmospheric temperatures from satellite observations was performed using primarily observations in the longwave window and CO2 absorption regions. One reason for this was concerns about the effects, during the day, of reflected sunlight and non-Local Thermodynamic Equilibrium (non-LTE) on the observed radiances in the shortwave portion of the spectrum. According to cloud clearing theory, more accurate soundings of both surface skin and atmospheric temperatures can be obtained under partial cloud cover conditions if one uses the longwave channels to determine cloud cleared radiances R(sub i) for all channels, and uses R(sub i) only from shortwave channels in the determination of surface and atmospheric temperatures. This procedure is now being used by the AIRS Science Team in preparation for the AIRS Version 6 Retrieval Algorithm. This paper describes how the effects on the radiances of solar radiation reflected by clouds and the Earth's surface, and also of non-LTE, are accounted for in the analysis of the data. Results are presented for both

  8. Long-Term Stable Surface Treatments on CdTe and CdZnTe Radiation Detectors

    Science.gov (United States)

    Pekarek, Jakub; Belas, Eduard; Zazvorka, Jakub

    2017-04-01

    The spectral resolution and charge collection efficiency (CCE) of cadmium telluride (CdTe) and cadmium zinc telluride (CZT) room-temperature x-ray and gamma-ray detectors are often limited by high surface leakage current due to conducting surface species created during detector fabrication. Surface treatments play a major role in reduction of this surface leakage current. The effect of various types of surface etching and passivation on the leakage current and thereby the spectral energy resolution, CCE, and internal electric field profile of CdTe/CZT detectors has been studied. The main aim of this work is preparation of long-term stable detectors with strongly reduced leakage current. The time stability of the current-voltage characteristic and spectral resolution was investigated during 21 days and 1 year, respectively, after performing surface treatments. Our results suggest that the optimal detector preparation method is chemomechanical polishing in bromine-ethylene glycol solution followed by chemical etching in bromine-methanol solution then surface passivation in potassium hydroxide or ammonium fluoride (NH4F/H2O2). Detectors prepared using this optimal treatment exhibited low leakage current, high spectral resolution, and long-term stability compared with those subjected to other surface preparation methods.

  9. Reaction Mechanisms on Multiwell Potential Energy Surfaces in Combustion (and Atmospheric) Chemistry

    International Nuclear Information System (INIS)

    Osborn, David L.

    2017-01-01

    Chemical reactions occurring on a potential energy surface with multiple wells are ubiquitous in low temperature combustion and the oxidation of volatile organic compounds in earth’s atmosphere. The rich variety of structural isomerizations that compete with collisional stabilization make characterizing such complex-forming reactions challenging. This review describes recent experimental and theoretical advances that deliver increasingly complete views of their reaction mechanisms. New methods for creating reactive intermediates coupled with multiplexed measurements provide many experimental observables simultaneously. Automated methods to explore potential energy surfaces can uncover hidden reactive pathways, while master equation methods enable a holistic treatment of both sequential and well-skipping pathways. Our ability to probe and understand nonequilibrium effects and reaction sequences is increasing. These advances provide the fundamental science base for predictive models of combustion and the atmosphere that are crucial to address global challenges.

  10. Reaction Mechanisms on Multiwell Potential Energy Surfaces in Combustion (and Atmospheric) Chemistry

    Science.gov (United States)

    Osborn, David L.

    2017-05-01

    Chemical reactions occurring on a potential energy surface with multiple wells are ubiquitous in low-temperature combustion and in the oxidation of volatile organic compounds in Earth's atmosphere. The rich variety of structural isomerizations that compete with collisional stabilization makes characterizing such complex-forming reactions challenging. This review describes recent experimental and theoretical advances that deliver increasingly complete views of their reaction mechanisms. New methods for creating reactive intermediates coupled with multiplexed measurements provide many experimental observables simultaneously. Automated methods to explore potential energy surfaces can uncover hidden reactive pathways, and master equation methods enable a holistic treatment of both sequential and well-skipping pathways. Our ability to probe and understand nonequilibrium effects and reaction sequences is increasing. These advances provide the fundamental science base for predictive models of combustion and the atmosphere that are crucial to address global challenges.

  11. Atmospheres and surfaces of small bodies and dwarf planets in the Kuiper Belt

    Directory of Open Access Journals (Sweden)

    Schaller E.L.

    2010-12-01

    Full Text Available Kuiper Belt Objects (KBOs are icy relics orbiting the sun beyond Neptune left over from the planetary accretion disk. These bodies act as unique tracers of the chemical, thermal, and dynamical history of our solar system. Over 1000 Kuiper Belt Objects (KBOs and centaurs (objects with perihelia between the giant planets have been discovered over the past two decades. While the vast majority of these objects are small ( 6-meter telescopes, have allowed for the first detailed studies of their surfaces and atmospheres. Visible and near-infrared spectroscopy of KBOs and centaurs has revealed a great diversity of surface compositions. Only the largest and coldest objects are capable of retaining volatile ices and atmospheres. Knowledge of the dynamics, physical properties, and collisional history of objects in the Kuiper belt is important for understanding solar system formation and evolution.

  12. Improved atmospheric effects elimination method for pBRDF models of painted surfaces.

    Science.gov (United States)

    Zhang, Ying; Zhang, Yi; Zhao, Huijie; Wang, Zeying

    2017-07-10

    A method for eliminating atmospheric effects in polarimetric imaging remote sensing detection was developed by combining the shadowing method and radiative transfer (RT) model. First, a polarized bidirectional reflectance distribution function (pBRDF) model of painted surfaces was constructed. Using the resulting polarimetric radiance composition, the atmospheric effects elimination method was developed and compared to Shell's method. Experiments were performed using a liquid-crystal-variable-retarder-based imaging polarimeter to obtain the surface pBRDFs. The proposed method showed better performance under different weather conditions than Shell's method. Furthermore, the error was below 4.8% in the proposed method (6.8% in Shell's method), indicating improved quantitative accuracy of the target physical parameters in remote sensing.

  13. Study on the surface reaction of uranium metal in hydrogen atmosphere with XPS

    International Nuclear Information System (INIS)

    Wang Xiaolin; Fu Yibei; Xie Renshou; Zuo Changming; Zhao Chunpei; Chen Hong

    1998-01-01

    The surface reactions of uranium metal in hydrogen atmosphere at 25 degree C and 200 degree C and effects of temperature and carbon monoxide to the hydriding reaction have been studied by X-ray photoelectron spectroscopy (XPS). The reaction between H 2 and uranium metal at 25 degree C leads to the further oxidation of surface layer of metal due to traces of water vapor. At 200 degree C, it may lead to the hydriding reaction of uranium and the hydriding increases with increasing exposure to H 2 in the initial stages. The U4f 7/2 binding energy of UH 3 has been found to be 378.6 eV. Investigation indicates carbon monoxide inhibits both the hydriding reaction and oxidation on the condition of H 2 -CO atmosphere

  14. A Software Tool for Atmospheric Correction and Surface Temperature Estimation of Landsat Infrared Thermal Data

    Directory of Open Access Journals (Sweden)

    Benjamin Tardy

    2016-08-01

    Full Text Available Land surface temperature (LST is an important variable involved in the Earth’s surface energy and water budgets and a key component in many aspects of environmental research. The Landsat program, jointly carried out by NASA and the USGS, has been recording thermal infrared data for the past 40 years. Nevertheless, LST data products for Landsat remain unavailable. The atmospheric correction (AC method commonly used for mono-window Landsat thermal data requires detailed information concerning the vertical structure (temperature, pressure and the composition (water vapor, ozone of the atmosphere. For a given coordinate, this information is generally obtained through either radio-sounding or atmospheric model simulations and is passed to the radiative transfer model (RTM to estimate the local atmospheric correction parameters. Although this approach yields accurate LST data, results are relevant only near this given coordinate. To meet the scientific community’s demand for high-resolution LST maps, we developed a new software tool dedicated to processing Landsat thermal data. The proposed tool improves on the commonly-used AC algorithm by incorporating spatial variations occurring in the Earth’s atmosphere composition. The ERA-Interim dataset (ECMWFmeteorological organization was used to retrieve vertical atmospheric conditions, which are available at a global scale with a resolution of 0.125 degrees and a temporal resolution of 6 h. A temporal and spatial linear interpolation of meteorological variables was performed to match the acquisition dates and coordinates of the Landsat images. The atmospheric correction parameters were then estimated on the basis of this reconstructed atmospheric grid using the commercial RTMsoftware MODTRAN. The needed surface emissivity was derived from the common vegetation index NDVI, obtained from the red and near-infrared (NIR bands of the same Landsat image. This permitted an estimation of LST for the entire

  15. Atmospheric pressure surface sampling/ionization techniques for direct coupling of planar separations with mass spectrometry.

    Science.gov (United States)

    Pasilis, Sofie P; Van Berkel, Gary J

    2010-06-18

    Planar separations, which include thin layer chromatography and gel electrophoresis, are in widespread use as important and powerful tools for conducting separations of complex mixtures. To increase the utility of planar separations, new methods are needed that allow in situ characterization of the individual components of the separated mixtures. A large number of atmospheric pressure surface sampling and ionization techniques for use with mass spectrometry have emerged in the past several years, and several have been investigated as a means for mass spectrometric read-out of planar separations. In this article, we review the atmospheric pressure surface sampling and ionization techniques that have been used for the read-out of planar separation media. For each technique, we briefly explain the operational basics and discuss the analyte type for which it is appropriate and some specific applications from the literature. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  16. Beam steering mechanism for earthcare atmospheric lidar instrument ATLID: an ultra-stable piezoelectric tip tilt mechanism

    Science.gov (United States)

    Prevost, E.; Pain, T.; Weickman, A.; Belmana, S.; Bourgain, F.; Sosnicki, O.; Claeyssen, F.

    2017-09-01

    ATLID (ATmospheric LIDar) is one of the four instruments of EarthCARE satellite, it shall determine vertical profiles of cloud and aerosol physical parameters such as altitude, optical depth, backscatter ratio and depolarisation ratio. The BSA (Beam Steering Assembly), included in emission path, aims at deviating a pulsed high energy UV laser beam to compensate the pointing misalignment between the emission and reception paths of ATLID [1]. It requires a very high stability and high resolution.

  17. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    Science.gov (United States)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  18. Fluxes of nitrates between snow surfaces and the atmosphere in the European high Arctic

    Directory of Open Access Journals (Sweden)

    H. J. Beine

    2003-01-01

    Full Text Available Measurements of atmospheric and snow mixing ratios of nitrates and nitrites and their fluxes above the snow surface were made during two intensive campaigns during spring time 2001 at Ny-Ålesund, Svalbard as part of the EU project  "`The NItrogen Cycle and Effects on the oxidation of atmospheric trace species at high latitudes' (NICE. At this coastal site close to the unseasonably unfrozen fjord, of the measured nitrogen species, only HNO3 showed a significant flux on to the snow surface; a mean deposition of -8.7 nmol h-1 m-2 was observed in late April / early May 2001. These fluxes may be due to the reaction of HNO3 with sea salt, and especially NaCl, or may be simply uptake of HNO3 by ice, which is alkaline because of the sea salt in our marine environment. During snowfall periods dry deposition of HNO3 may contribute up to 10% of the N budget in the snow; however, the main source for N is wet deposition in falling snow. The surface snow at Ny-Ålesund showed very complex stratigraphy; the NO3- mixing ratio in snow varied between 65 and 520 ng g-1, the total NO3- content of the snowpack was on the order of 2700 ng cm-2. In comparison the atmospheric boundary layer column showed a NO3- content of only 8 ng cm-2. The limited exchange, however, between the snow and the atmosphere was attributed to low mobility of NO3- in the observed snow. Contrary to other Arctic sites (i.e. Alert, Nunavut or Summit, Greenland deposition of sea salt and crustal aerosols in this marine environment made the surface snow alkaline; snow NO3- was associated with heavier cations and was not readily available for physical exchange or photochemical reactions.

  19. Long wave dispersion relations for surface waves in a magnetically structured atmosphere

    International Nuclear Information System (INIS)

    Rae, I.C.; Roberts, B.

    1983-01-01

    A means of obtaining approximate dispersion relations for long wavelength magnetoacoustic surface waves propagating in a magnetically structured atmosphere is presented. A general dispersion relation applying to a wide range of magnetic profiles is obtained, and illustrated for the special cases of a single interface and a magnetic slab. In the slab geometry, for example, the dispersion relation contains both the even (sausage) and odd (kink) modes in one formalism

  20. Surface analysis of 316 stainless steel treated with cold atmospheric plasma

    Science.gov (United States)

    Williams, David F.; Kellar, Ewen J. C.; Jesson, David A.; Watts, John F.

    2017-05-01

    The surface of 316 stainless steel has been modified using cold atmospheric plasma (CAP) to increase the surface free energy (by cleaning the and chemically activating the surface)IN preparation for subsequent processes such as painting, coating or adhesive bonding. The analyses carried out, on CAP treated 316 stainless steel surfaces, includes X-ray photoelectron spectroscopy (XPS), imaging XPS (iXPS), and surface free energy (SFE) analysis using contact angle measurements. The CAP treatment is shown to increase the SFE of as-received 316 stainless steel from ∼39 mJ m-1 to >72 mJ m-1 after a short exposure to the plasma torch. This was found to correlate to a reduction in adventitious carbon, as determined by XPS analysis of the surface. The reduction from ∼90 at% to ∼30% and ∼39 at%, after being plasma treated for 5 min and 15 s respectively, shows that the process is relatively quick at changing the surface. It is suggested that the mechanism that causes the increase in surface free energy is chain scission of the hydrocarbon contamination triggered by free electrons in the plasma plume followed by chemical functionalisation of the metal oxide surface and some of the remaining carbon contamination layer.

  1. Acoustic-gravity waves generated by atmospheric and near-surface sources

    Science.gov (United States)

    Kunitsyn, Viacheslav E.; Kholodov, Alexander S.; Krysanov, Boris Yu.; Andreeva, Elena S.; Nesterov, Ivan A.; Vorontsov, Artem M.

    2013-04-01

    Numerical simulation of the acoustic-gravity waves (AGW) generated by long-period oscillations of the Earth's (oceanic) surface, earthquakes, explosions, thermal heating, seiches, and tsunami is carried out. Wavelike disturbances are quite frequent phenomena in the atmosphere and ionosphere. These events can be caused by the impacts from space and atmosphere, by oscillations of the Earth'as surface and other near-surface events. These wavelike phenomena in the atmosphere and ionosphere appear as the alternating areas of enhanced and depleted density (in the atmosphere) or electron concentration (in the ionosphere). In the paper, AGW with typical frequencies of a few hertz - millihertz are analyzed. AGW are often observed after the atmospheric perturbations, during the earthquakes, and some time (a few days to hours) in advance of the earthquakes. Numerical simulation of the generation of AGW by long-period oscillations of the Earth's and oceanic surface, earthquakes, explosions, thermal heating, seiches, and tsunami is carried out. The AGW generated by the near-surface phenomena within a few hertz-millihertz frequency range build up at the mid-atmospheric and ionospheric altitudes, where they assume their typical spatial scales of the order of a few hundred kilometers. Oscillations of the ionospheric plasma within a few hertz-millihertz frequency range generate electromagnetic waves with corresponding frequencies as well as travelling ionospheric irregularities (TIDs). Such structures can be successfully monitored using satellite radio tomography (RT) techniques. For the purposes of RT diagnostics, 150/400 MHz transmissions from low-orbiting navigational satellites flying in polar orbits at the altitudes of about 1000 km as well as 1.2-1.5 GHz signals form high-orbiting (orbital altitudes about 20000 km) navigation systems like GPS/GLONASS are used. The results of experimental studies on generation of wavelike disturbances by particle precipitation are presented

  2. Oxygen Plasma Treatment of Rubber Surface by the Atmospheric Pressure Cold Plasma Torch

    DEFF Research Database (Denmark)

    Lee, Bong-ju; Kusano, Yukihiro; Kato, Nobuko

    1997-01-01

    adhesive. The adhesion property was improved by treatment of the rubber compound with plasma containing oxygen radicals. Physical and chemical changes of the rubber surface as a result of the plasma treatment were analyzed by field emission scanning electron microscopy (FE-SEM) and fourier transform......A new application of the atmospheric cold plasma torch has been investigated. Namely, the surface treatment of an air-exposed vulcanized rubber compound. The effect of plasma treatment was evaluated by the bondability of the treated rubber compound with another rubber compound using a polyurethane...

  3. Research on the surface chemical behavior of uranium metal in hydrogen atmosphere by XPS

    International Nuclear Information System (INIS)

    Fu Xiaoguo; Wang Xiaolin; Yu Yong; Zhao Zhengping

    2001-01-01

    The surface chemical behavior clean uranium metal in hydrogen atmosphere at 100 and 200 degree C is studied by X-ray photoelectron spectroscopy (XPS), respectively. It leads to hydriding reaction when the hydrogen exposure is 12.0 Pa·s, and the U4f 7/2 binding energy of UH 3 is found to be 378.7 eV. The higher temperature (200 degree C) is beneficial to UH 3 formation at the same hydrogen exposures. XPS elemental depth profiles indicate that the distribution of uranium surface layer is UO 2 , UH 3 and U after exposure to 174.2 Pa·s hydrogen

  4. Perspectives of methods of laser monitoring of the atmosphere and sea surface

    Science.gov (United States)

    Pashayev, Arif; Tunaboylu, Bahadir; Usta, Metin; Sadixov, Ilham; Allahverdiyev, Kerim

    2016-01-01

    Laser monitoring (remote sensing) may be considered as the science of collecting and interpreting information about the atmosphere, earth and sea using sensors on earth, on platforms in our atmosphere (airplanes, balloons) or in space (satellites) without being in direct physical contact with them. Remote sensing by LIDARs (Light Identification Detection and Ranging) has wide applications as technique to probe the Earth's atmosphere, ocean and land surfaces. LIDARs are widely used to get knowledge of spatial and temporal variations in meteorological quantities (e.g. temperature, humidity, clouds and aerosol properties) and to monitor the changes in these quantities on different timescales. Subject of the present work is quite wide. It is rather difficult to perform analysis and to provide full knowledge about existing information. In the present work, in addition to the literature data, the information will be provided also about KA-09 aerosol LIDAR developed at the Marmara Research Centre of TÜBITAK (Turkish Scientific and technological Research Council) and also about KA-14 LIDAR developed at the National Aviation Academy of Azerbaijan for remote sensing of contaminations on water surfaces taking place during oil-gas production. The main goal of this paper is to give students insight in different remote sensing instruments and techniques (including their perspectives) that are used for the derivation of meteorological quantities and obtaining the information about water surface.

  5. Radioisotope Stirling Engine Powered Airship for Atmospheric and Surface Exploration of Titan

    Science.gov (United States)

    Colozza, Anthony J.; Cataldo, Robert L.

    2014-01-01

    The feasibility of an advanced Stirling radioisotope generator (ASRG) powered airship for the near surface exploration of Titan was evaluated. The analysis did not consider the complete mission only the operation of the airship within the atmosphere of Titan. The baseline airship utilized two ASRG systems with a total of four general-purpose heat source (GPHS) blocks. Hydrogen gas was used to provide lift. The ASRG systems, airship electronics and controls and the science payload were contained in a payload enclosure. This enclosure was separated into two sections, one for the ASRG systems and the other for the electronics and payload. Each section operated at atmospheric pressure but at different temperatures. The propulsion system consisted of an electric motor driving a propeller. An analysis was set up to size the airship that could operate near the surface of Titan based on the available power from the ASRGs. The atmospheric conditions on Titan were modeled and used in the analysis. The analysis was an iterative process between sizing the airship to carry a specified payload and the power required to operate the electronics, payload and cooling system as well as provide power to the propulsion system to overcome the drag on the airship. A baseline configuration was determined that could meet the power requirements and operate near the Titan surface. From this baseline design additional trades were made to see how other factors affected the design such as the flight altitude and payload mass and volume.

  6. Effect of atmospheric oxidative plasma treatments on polypropylenic fibers surface: Characterization and reaction mechanisms

    International Nuclear Information System (INIS)

    Nisticò, Roberto; Magnacca, Giuliana; Faga, Maria Giulia; Gautier, Giovanna; D’Angelo, Domenico; Ciancio, Emanuele; Lamberti, Roberta; Martorana, Selanna

    2013-01-01

    Atmospheric pressure plasma-dielectric barrier discharge (APP-DBD, open chamber configuration) was used to functionalize polypropylene (PP) fibers surface in order to generate oxidized-reactive groups such as hydroperoxides, alcohols and carbonyl species (i.e. ketones and others). Such a species increased the surface polarity, without causing material degradation. Three different types of plasma mixture (He, He/O 2 , He/O 2 /H 2 O) under three different values of applied power (750, 1050, 1400 W) were investigated. The formed plasma species (O 2 + , O single atom and OH radical) and their distribution were monitored via optical emission spectrometry (OES) measurements, and the plasma effects on PP surface species formation were followed by X-ray photoemission spectroscopy (XPS). Results allowed to better understand the reaction pathways between plasma phase and PP fibers. In fact, two reaction mechanisms were proposed, the first one concerning the plasma phase reactions and the second one involving material surface modifications.

  7. Application of a novel atmospheric pressure plasma fluidized bed in the powder surface modification

    International Nuclear Information System (INIS)

    Chen Guangliang; Chen Shihua; Zhou Mingyan; Feng Wenran; Gu Weichao; Yang Size

    2006-01-01

    A novel atmospheric pressure plasma fluidized bed (APPFB) with one liquid electrode was designed, and its preliminary discharge characteristics were studied. The glow discharge in the APPFB was generated by applying a low power with helium (He) gas, and the plasma gas temperature was no higher than 320 K when the applied power was lower than 11 W. The plasma optical emission spectrum (OES) of the gas mixture consisting of He and hexamethyldisiloxane (HMDSO) was recorded by a UV-visible monochromator. The calcium carbonate powders were modified by APPFB using HMDSO in the He plasma. The powder surface energy was decreased greatly by coating an organosilicon polymer onto the powder surface. This surface modification process changed the wettability of the powder from super-hydrophilicity to super-hydrophobicity, and the contact angle of water on the modified powders surface was greater than 160 0

  8. Study on surface modification of polymer films by using atmospheric plasma jet source

    International Nuclear Information System (INIS)

    Takemura, Yuichiro; Hara, Tamio; Yamaguchi, Naohiro

    2008-01-01

    Reactive gas plasma treatments of poly(ethylene terephthalate) (PET) and polyimide (Kapton) have been performed using an atmospheric plasmas jet source. Characteristics of surface modification have been examined by changing the distance between the plasma jet source and the treated sample, and by changing the working gas spaces. Simultaneously, each plasma jet source has been investigated by space-resolving spectroscopy in the UV/visible region. Polymer surfaces have been analyzed by X-ray photoelectron spectroscopy (XPS). A marked improvement in the hydrophilicity of the polymer surfaces has been made by using N 2 or O 2 plasma jet source with a very short exposure time of about 0.01 s, whereas the less improvement has been obtained using on air plasma jet source because of NO x compound production. Changes in the chemical states of C of the polymer surfaces have been observed in XPS spectra after N 2 plasma jet spraying. (author)

  9. Atmospheric deposition and storm induced runoff of heavy metals from different impermeable urban surfaces.

    Science.gov (United States)

    Wicke, Daniel; Cochrane, Thomas A; O'Sullivan, Aisling D

    2012-01-01

    Contaminants deposited on impermeable surfaces migrate to stormwater following rainfall events, but accurately quantifying their spatial and temporal yields useful for mitigation purposes is challenging. To overcome limitations in current sampling methods, a system was developed for rapid quantification of contaminant build-up and wash-off dynamics from different impervious surfaces. Thin boards constructed of concrete and two types of asphalt were deployed at different locations of a large carpark to capture spatially distributed contaminants from dry atmospheric deposition over specified periods of time. Following experimental exposure time, the boards were then placed under a rainfall simulator in the laboratory to generate contaminant runoff under controlled conditions. Single parameter effects including surface roughness and material composition, number of antecedent dry days, rain intensity, and water quality on contaminant build-up and wash-off yields could be investigated. The method was applied to quantify spatial differences in deposition rates of contaminants (TSS, zinc, copper and lead) at two locations varying in their distance to vehicle traffic. Results showed that boards exposed at an unused part of the carpark >50 m from vehicular traffic captured similar amounts of contaminants compared with boards that were exposed directly adjacent to the access route, indicating substantial atmospheric contaminant transport. Furthermore, differences in contaminant accumulation as a function of surface composition were observed. Runoff from asphalt boards yielded higher zinc loads compared with concrete surfaces, whereas runoff from concrete surfaces resulted in higher TSS concentrations attributed to its smoother surfaces. The application of this method enables relationships between individual contaminant behaviour and specific catchment characteristics to be investigated and provides a technique to derive site-specific build-up and wash-off functions required

  10. Plasma surface treatment of Cu by nanosecond-pulse diffuse discharges in atmospheric air

    Science.gov (United States)

    Cheng, ZHANG; Jintao, QIU; Fei, KONG; Xingmin, HOU; Zhi, FANG; Yu, YIN; Tao, SHAO

    2018-01-01

    Nanosecond-pulse diffuse discharges could provide high-density plasma and high-energy electrons at atmospheric pressure. In this paper, the surface treatment of Cu by nanosecond-pulse diffuse discharges is conducted in atmospheric air. Factors influencing the water contact angle (WCA), chemical composition and microhardness, such as the gap spacing and treatment time, are investigated. The results show that after the plasma surface treatment, the WCA considerably decreases from 87° to 42.3°, and the surface energy increases from 20.46 mJ m-2 to 66.28 mJ m-2. Results of energy dispersive x-ray analysis show that the concentration of carbon decreases, but the concentrations of oxygen and nitrogen increase significantly. Moreover, the microhardness increases by approximately 30% after the plasma treatment. The aforementioned changes on the Cu surface indicate the plasma surface treatment enhances the hydrophilicity and microhardness, and it cleans the carbon and achieves oxidization on the Cu surface. Furthermore, by increasing the gap spacing and treatment time, better treatment effects can be obtained. The microhardness in the case of a 2.5 cm gap is higher than that in the case of a 3 cm gap. More oxygen and nitrogen species appear on the Cu surface for the 2.5 cm gap treatment than for the 3 cm gap treatment. The WCA significantly decreases with the treatment time when it is no longer than 90 s, and then it reaches saturation. In addition, more oxygen-containing and nitrogen-containing groups appear after extended plasma treatment time. They contribute to the improvement of the hydrophilicity and oxidation on the Cu surface.

  11. ERA-40-aided assessment of the atmospheric influence on satellite retrieval of Adriatic Sea surface temperature

    Science.gov (United States)

    Tomažić, Igor; Kuzmić, Milivoj

    2009-06-01

    The aim of this work is assessment of regional atmospheric influence on satellite derivation of Adriatic Sea surface temperature (SST). To this end the European Centre for Medium-Range Weather Forecast (ECMWF) ERA-40 reanalysis dataset has been employed to provide the temperature and humidity profiles and surface data, while the RTTOV 8.7 radiative transfer model was used to calculate the top-of-atmosphere brightness temperatures for the advanced very high-resolution radiometer (AVHRR) channels. Ten ERA-40 grid points over the Adriatic Sea were used in the analysis, providing 29,590, 00 UTC and 12 UTC, clear-sky profiles. Climatological analysis of the ERA-40 profiles demonstrated distinct seasonal variability over the Adriatic Sea. Seasonality noted in the temperature and specific humidity profiles also evinced in the atmospheric transmittance, thermal channels temperature deficit, and derived γ and ρ parameters. A multivariate analysis was applied to relate the simulated top-of-atmosphere brightness temperatures to the Adriatic SSTs in order to generate exploratory sets of SST retrieval coefficients. All derived coefficient sets exhibited smaller noise amplification factor than the global counterpart. A test comparison of satellite-derived SST with an 11-month in situ SST series showed than locally derived coefficients provide smaller scatter (improved precision), and skin-centred bias that requires additional adjustment. Almost identical SST residual and error metric was obtained with seasonally adjusted classical split-window coefficients and with coefficients explicitly accommodating water-vapor dependence. Comparison with data reinforces the notion that the atmosphere over the Adriatic may exhibit variability that cannot be fully accommodated by globally adjusted correction.

  12. Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air

    International Nuclear Information System (INIS)

    Yang Guoqing; Zhang Guanjun; Zhang Wenyuan

    2011-01-01

    Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectric barrier discharge generator in atmospheric air. The electrical parameters including discharging power, peak and density of micro-discharge current were calculated, and the electron energy was estimated. Surface treatment experiments of polytetrafluoroethylene films were conducted for both different applied voltages and different treating durations. Results show that the surface energy of polytetrafluoroethylene film could be improved to 40 mJ/m 2 or more by plasma treatment. Surface roughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that there are chemical etching and implantation of polar oxygen groups in the sample surface treating process, resulting in the improvement of the sample surface energy. Compared with an AC source of 50 Hz, the dielectric barrier discharges generated by a repetitive pulsed source could provide higher peak power, lower mean power, larger micro-discharge current density and higher electron energy. Therefore, with the same applied peak voltage and treating duration, the improvement of polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective, and the plasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thus feasible and applicable.

  13. Stable Isotopes of Ice on the Surface of Taylor Glacier, Antarctica, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains Oxygen and Deuterium isotope ratios for approximately 980 sites on the surface of the ablation zone of Taylor Glacier, Antarctica. The data...

  14. Highly stable surface modification of hypercrosslinked monolithic capillary columns and their application in hydrophilic interaction chromatography.

    Science.gov (United States)

    Škeříková, Veronika; Urban, Jiří

    2013-09-01

    A two-step surface modification of poly(styrene-co-vinylbenzyl chloride-co-divinylbenzene) monolithic stationary phases, including hypercrosslinking and thermally initiated surface grafting of [2-(methacryloyloxy)ethyl]dimethyl(3-sulfopropyl)ammonium hydroxide, has been used to prepare capillary columns for the isocratic separation of small polar compounds in hydrophilic interaction chromatography (HILIC). The prepared monolithic columns provided a dual retention mechanism, combining RP and hydrophilic interaction chromatography, controlled by the composition of the mobile phase. By the optimization of the surface grafting reaction using response surface methodology, we have found that the grafting time is the main synergistic effect controlling the retention of polar compounds in HILIC. The prepared monolithic columns achieved long column lifetimes and did not lose their separation power following >10,000 injections. Finally, hypercrosslinked columns have been used in the 1- and 2D LC of phenolic compounds. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Stable isotope evidence for an atmospheric origin of desert nitrate deposits in northern Chile and southern California, U.S.A.

    Science.gov (United States)

    Böhlke, J.K.; Ericksen, G.E.; Revesz, K.

    1997-01-01

    Natural surficial accumulations of nitrate-rich salts in the Atacama Desert, northern Chile, and in the Death Valley region of the Mojave Desert, southern California, are well known, but despite many geologic and geochemical studies, the origins of the nitrates have remained controversial. N and O isotopes in nitrate, and S isotopes in coexisting soluble sulfate, were measured to determine if some proposed N sources could be supported or rejected, and to determine if the isotopic signature of these natural deposits could be used to distinguish them from various types of anthropogenic nitrate contamination that might be found in desert groundwaters. High-grade caliche-type nitrate deposits from both localities have ??15N values that range from -5 to +5???, but are mostly near 0???. Values of ??15N near 0??? are consistent with either bulk atmospheric N deposition or microbial N fixation as major sources of the N in the deposits. ??18O values of those desert nitrates with ??15N near 0??? range from about +31 to + 50??? (V-SMOW), significantly higher than that of atmospheric O2 (+ 23.5???). Such high values of ??18O are considered unlikely to result entirely from nitrification of reduced N, but rather resemble those of modern atmospheric nitrate in precipitation from some other localities. Assuming that limited modern atmospheric isotope data are applicable to the deposits, and allowing for nitrification of co-deposited ammonium, it is estimated that the fraction of the nitrate in the deposits that could be accounted for isotopically by atmospheric N deposition may be at least 20% and possibly as much as 100%. ??34S values are less diagnostic but could also be consistent with atmospheric components in some of the soluble sulfates associated with the deposits. The stable isotope data support the hypothesis that some high-grade caliche-type nitrate-rich salt deposits in some of the Earth's hyperarid deserts represent long-term accumulations of atmospheric deposition

  16. Fabrication of Water Jet Resistant and Thermally Stable Superhydrophobic Surfaces by Spray Coating of Candle Soot Dispersion.

    Science.gov (United States)

    Qahtan, Talal F; Gondal, Mohammed A; Alade, Ibrahim O; Dastageer, Mohammed A

    2017-08-08

    A facile synthesis method for highly stable carbon nanoparticle (CNP) dispersion in acetone by incomplete combustion of paraffin candle flame is presented. The synthesized CNP dispersion is the mixture of graphitic and amorphous carbon nanoparticles of the size range of 20-50 nm and manifested the mesoporosity with an average pore size of 7 nm and a BET surface area of 366 m 2 g -1 . As an application of this material, the carbon nanoparticle dispersion was spray coated (spray-based coating) on a glass surface to fabricate superhydrophobic (water contact angle > 150° and sliding angle fabricated from direct candle flame soot deposition (candle-based coating). This study proved that water jet resistant and thermally stable superhydrophobic surfaces can be easily fabricated by simple spray coating of CNP dispersion gathered from incomplete combustion of paraffin candle flame and this technique can be used for different applications with the potential for the large scale fabrication.

  17. Multi-station synthesis of early twentieth century surface atmospheric electricity measurements for upper tropospheric properties

    Directory of Open Access Journals (Sweden)

    R. G. Harrison

    2007-07-01

    Full Text Available The vertical columnar current density in the global atmospheric electrical circuit depends on the local columnar resistance. A simple model for the columnar resistance is suggested, which separates the local boundary layer component from the upper troposphere cosmic ray component, and calculates the boundary layer component from a surface measurement of air conductivity. This theory is shown to provide reasonable agreement with observations. One application of the simple columnar model theory is to provide a basis for the synthesis of surface atmospheric electrical measurements made simultaneously at several European sites. Assuming the ionospheric potential to be common above all the sites, the theoretical air-earth current density present in the absence of a boundary layer columnar resistance can be found by extrapolation. This is denoted the free troposphere limit air-earth current density, J0. Using early surface data from 1909 when no ionospheric potential data are available for corroboration, J0 is found to be ~6 pA m−2, although this is subject to uncertainties in the data and limitations in the theory. Later (1966–1971 European balloon and surface data give J0=2.4 pA m−2.

  18. Impact of Urban Surface Roughness Length Parameterization Scheme on Urban Atmospheric Environment Simulation

    Directory of Open Access Journals (Sweden)

    Meichun Cao

    2014-01-01

    Full Text Available In this paper, the impact of urban surface roughness length z0 parameterization scheme on the atmospheric environment simulation over Beijing has been investigated through two sets of numerical experiments using the Weather Research and Forecasting model coupled with the Urban Canopy Model. For the control experiment (CTL, the urban surface z0 parameterization scheme used in UCM is the model default one. For another experiment (EXP, a newly developed urban surface z0 parameterization scheme is adopted, which takes into account the comprehensive effects of urban morphology. The comparison of the two sets of simulation results shows that all the roughness parameters computed from the EXP run are larger than those in the CTL run. The increased roughness parameters in the EXP run result in strengthened drag and blocking effects exerted by buildings, which lead to enhanced friction velocity, weakened wind speed in daytime, and boosted turbulent kinetic energy after sunset. Thermal variables (sensible heat flux and temperature are much less sensitive to z0 variations. In contrast with the CTL run, the EXP run reasonably simulates the observed nocturnal low-level jet. Besides, the EXP run-simulated land surface-atmosphere momentum and heat exchanges are also in better agreement with the observation.

  19. Our contaminated atmosphere: The danger of climate change, phases 1 and 2. [effect of atmospheric particulate matter on surface temperature and earth's radiation budget

    Science.gov (United States)

    Cimorelli, A. J.; House, F. B.

    1974-01-01

    The effects of increased concentrations of atmospheric particulate matter on average surface temperature and on the components of the earth's radiation budget are studied. An atmospheric model which couples particulate loading to surface temperature and to changes in the earth's radiation budget was used. A determination of the feasibility of using satellites to monitor the effect of increased atmospheric particulate concentrations is performed. It was found that: (1) a change in man-made particulate loading of a factor of 4 is sufficient to initiate an ice age; (2) variations in the global and hemispheric weighted averages of surface temperature, reflected radiant fluz and emitted radiant flux are nonlinear functions of particulate loading; and (3) a black satellite sphere meets the requirement of night time measurement sensitivity, but not the required day time sensitivity. A nonblack, spherical radiometer whose external optical properties are sensitive to either the reflected radiant fluz or the emitted radiant flux meets the observational sensitivity requirements.

  20. MSATT Workshop on Innovative Instrumentation for the In Situ Study of Atmosphere-Surface Interactions on Mars

    Science.gov (United States)

    Fegley, Bruce, Jr. (Editor); Waenke, Heinrich (Editor)

    1992-01-01

    Papers accepted for the Mars Surface and Atmosphere Through Time (MSATT) Workshop on Innovative Instruments for the In Situ Study of Atmosphere-Surface Interaction of Mars, 8-9 Oct. 1992 in Mainz, Germany are included. Topics covered include: a backscatter Moessbauer spectrometer (BaMS) for use on Mars; database of proposed payloads and instruments for SEI missions; determination of martian soil mineralogy and water content using the Thermal Analyzer for Planetary Soils (TAPS); in situ identification of the martian surface material and its interaction with the martian atmosphere using DTA/GC; mass spectrometer-pyrolysis experiment for atmospheric and soil sample analysis on the surface of Mars; and optical luminescence spectroscopy as a probe of the surface mineralogy of Mars.

  1. Surface treatment of a titanium implant using low temperature atmospheric pressure plasmas

    Science.gov (United States)

    Lee, Hyun-Young; Tang, Tianyu; Ok, Jung-Woo; Kim, Dong-Hyun; Lee, Ho-Jun; Lee, Hae June

    2015-09-01

    During the last two decades, atmospheric pressure plasmas(APP) are widely used in diverse fields of biomedical applications, reduction of pollutants, and surface treatment of materials. Applications of APP to titanium surface of dental implants is steadily increasing as it renders surfaces wettability and modifies the oxide layer of titanium that hinders the interaction with cells and proteins. In this study, we have treated the titanium surfaces of screw-shaped implant samples using a plasma jet which is composed of a ceramic coaxial tube of dielectrics, a stainless steel inner electrode, and a coper tube outer electrode. The plasma ignition occurred with Ar gas flow between two coaxial metal electrodes and a sinusoidal bias voltage of 3 kV with a frequency of 20 kHz. Titanium materials used in this study are screw-shaped implants of which diameter and length are 5 mm and 13 mm, respectively. Samples were mounted at a distance of 5 mm below the plasma source, and the plasma treatment time was set to 3 min. The wettability of titanium surface was measured by the moving speed of water on its surface, which is enhanced by plasma treatment. The surface roughness was also measured by atomic force microscopy. The optimal condition for wettability change is discussed.

  2. Stability of Atmospheric-Pressure Plasma Induced Changes on Polycarbonate Surfaces

    Science.gov (United States)

    Sharma, Rajesh; Holcomb, Edward; Trigwell, Steve

    2006-01-01

    Polycarbonate films are subjected to plasma treatment in a number of applications such as improving adhesion between polycarbonate and silicon alloy in protective and optical coatings. The changes in surface chemistry due to plasma treatment have tendency to revert back. Thus stability of the plasma induced changes on polymer surfaces over desired time period is very important. The objective of this study was to examine the effect of ageing on atmospheric pressure helium-plasma treated polycarbonate (PC) sample as a function of treatment time. The ageing effects were studied over a period of 10 days. The samples were plasma treated for 0.5, 2, 5 and 10 minutes. Contact angle measurements were made to study surface energy changes. Modification of surface chemical structure was examined using, X-ray Photoelectron Spectroscopy (XPS). Contact angle measurements on untreated and plasma treated surfaces were made immediately, 24, 48, 72 and 96 hrs after treatment. Contact angle decreased from 93 deg for untreated sample to 30 deg for sample plasma treated for 10 minutes. After 10 days the contact angles for the 10 minute plasma treated sample increased to 67 deg, but it never reverted back to that of untreated surface. Similarly the O/C ratio increased from 0.136 for untreated sample to 0.321 for 10 minute plasma treated sample indication increase in surface energy.

  3. Fabrication of stable and durable superhydrophobic surface on copper substrates for oil-water separation and ice-over delay.

    Science.gov (United States)

    Guo, Jie; Yang, Fuchao; Guo, Zhiguang

    2016-03-15

    We report a simple and rapid method to fabricate superhydrophobic films on copper substrates via Fe(3+) etching and octadecanethiol (ODT) modification. The etching process can be as short as 5 min and the ODT treatment only takes several seconds. In addition, the whole process is quite flexible in reaction time. The superhydrophobicity of as-prepared surfaces is mechanically durable and chemically stable, which have great performance in oil-water separation and ice-over resistance. Copyright © 2015 Elsevier Inc. All rights reserved.

  4. Ion beam induced surface pattern formation and stable travelling wave solutions.

    Science.gov (United States)

    Numazawa, Satoshi; Smith, Roger

    2013-03-06

    The formation of ripple structures on ion bombarded semiconductor surfaces is examined theoretically. Previous models are discussed and a new nonlinear model is formulated, based on the infinitesimal local atomic relocation induced by elastic nuclear collisions in the early stages of collision cascades and an associated density change in the near surface region. Within this framework ripple structures are shown to form without the necessity to invoke surface diffusion or large sputtering as important mechanisms. The model can also be extended to the case where sputtering is important, and it is shown that in this case certain 'magic' angles can occur at which the ripple patterns are most clearly defined. The results are in very good agreement with experimental observations.

  5. IR and UV laser-induced morphological changes in silicon surface under oxygen atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez-Jarquin, J.; Fernandez-Guasti, M.; Haro-Poniatowski, E.; Hernandez-Pozos, J.L. [Laboratorio de Optica Cuantica, Departamento de Fisica, Universidad Autonoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco No. 186, Col. Vicentina, C.P. 09340, Mexico D.F. (Mexico)

    2005-08-01

    We irradiated silicon (100) wafers with IR (1064 nm) and UV (355 nm) nanosecond laser pulses with energy densities within the ablation regime and used scanning electron microscopy to analyze the morphological changes induced on the Si surface. The changes in the wafer morphology depend both on the incident radiation wavelength and the environmental atmosphere. We have patterned Si surfaces with a single focused laser spot and, in doing the experiments with IR or UV this reveals significant differences in the initial surface cracking and pattern formation, however if the experiment is carried out in O{sub 2} the final result is an array of microcones. We also employed a random scanning technique to irradiate the silicon wafer over large areas, in this case the microstructure patterns consist of a ''semi-ordered'' array of micron-sized cones. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Aluminum metal surface cleaning and activation by atmospheric-pressure remote plasma

    Energy Technology Data Exchange (ETDEWEB)

    Muñoz, J., E-mail: jmespadero@uco.es; Bravo, J.A.; Calzada, M.D.

    2017-06-15

    Highlights: • Atmospheric-pressure postdischarges have been applied on aluminium surfaces. • The outer hydrocarbon layer is reduced by the action of the postdischarge. • The treatment promotes the appearance of hydrophilic OH radicals in the surface. • Effectivity for distances up to 5 cm allows for treating irregular surfaces. • Ageing in air due to the disappearance of OH radicals has been reported. - Abstract: The use of the remote plasma (postdischarge) of argon and argon-nitrogen microwave plasmas for cleaning and activating the surface of metallic commercial aluminum samples has been studied. The influence of the nitrogen content and the distance between the treated samples and the end of the discharge on the hydrophilicity and the surface energy has been analyzed by means of the sessile drop technique and the Owens-Wendt method. A significant increase in the hydrophilicity has been noted in the treated samples, together with an increase in the surface energy from values around 37 mJ/m{sup 2} to 77 mJ/m{sup 2}. Such increase weakly depends on the nitrogen content of the discharge, and the effectivity of the treatment extends to distances up to 5 cm from the end of the discharge, much longer than those reported in other plasma-based treatments. The analysis of the treated samples using X-ray photoelectron spectroscopy reveals that such increase in the surface energy takes place due to a reduction of the carbon content and an increase in the amount of OH radicals in the surface. These radicals tend to disappear within 24–48 h after the treatment when the samples are stored in contact with ambient air, resulting in the ageing of the treated surface and a partial retrieval of the hydrophobicity of the surface.

  7. Translation of Land Surface Model Accuracy and Uncertainty into Coupled Land-Atmosphere Prediction

    Science.gov (United States)

    Santanello, Joseph A.; Kumar, Sujay; Peters-Lidard, Christa D.; Harrison, Kenneth W.; Zhou, Shuija

    2012-01-01

    Land-atmosphere (L-A) Interactions playa critical role in determining the diurnal evolution of both planetary boundary layer (PBL) and land surface heat and moisture budgets, as well as controlling feedbacks with clouds and precipitation that lead to the persistence of dry and wet regimes. Recent efforts to quantify the strength of L-A coupling in prediction models have produced diagnostics that integrate across both the land and PBL components of the system. In this study, we examine the impact of improved specification of land surface states, anomalies, and fluxes on coupled WRF forecasts during the summers of extreme dry (2006) and wet (2007) land surface conditions in the U.S. Southern Great Plains. The improved land initialization and surface flux parameterizations are obtained through the use of a new optimization and uncertainty estimation module in NASA's Land Information System (US-OPT/UE), whereby parameter sets are calibrated in the Noah land surface model and classified according to a land cover and soil type mapping of the observation sites to the full model domain. The impact of calibrated parameters on the a) spinup of the land surface used as initial conditions, and b) heat and moisture states and fluxes of the coupled WRF Simulations are then assessed in terms of ambient weather and land-atmosphere coupling along with measures of uncertainty propagation into the forecasts. In addition, the sensitivity of this approach to the period of calibration (dry, wet, average) is investigated. Finally, tradeoffs of computational tractability and scientific validity, and the potential for combining this approach with satellite remote sensing data are also discussed.

  8. Surface modification of polyimide (PI) film using water cathode atmospheric pressure glow discharge plasma

    International Nuclear Information System (INIS)

    Zheng Peichao; Liu Keming; Wang Jinmei; Dai Yu; Yu Bin; Zhou Xianju; Hao Honggang; Luo Yuan

    2012-01-01

    Highlights: ► Equipment called water cathode atmospheric pressure glow discharge was used to improve the hydrophilicity of polyimide films. ► The data shows good homogeneity and the variation trends of contact angles are different for polar and non-polar testing liquids. ► The thickness of liquid layer plays an important role in plasma processing and directly affects the treatment effect. ► Surface hydrophilicity after plasma treatment is improved partly due to the increase in the roughness. ► The hydrophilicity of polyimide films is still better than untreated ones after long-term storage. - Abstract: The industrial use of polyimide film is limited because of undesirable properties such as poor wettability. In the present paper, a new kind of equipment called water cathode atmospheric pressure glow discharge was used to improve the surface properties of polyimide films and made them useful to technical applications. The changes in hydrophilicity of modified polyimide film surfaces were investigated by contact angle, surface energy and water content measurements as a function of treatment time. The results obtained show good treatment homogeneity and that the variation trends of contact angles are different for polar and non-polar testing liquids, while surface energy and water content are significantly enhanced with the increase of treatment time until they achieve saturated values after 60 s plasma treatment. Also, the thickness of liquid layer plays an important role in plasma processing and directly affects the treatment effect. Changes in morphology of polyimide films were analyzed by atomic force microscope and the results indicate that surface hydrophilicity after plasma treatment are improved partly due to the increase in the roughness. In addition, polyimide films treated by plasma are subjected to an ageing process to determine the durability of plasma treatment. It is found that the hydrophilicity is still better than untreated ones though the

  9. Properties of the surface snow in Princess Elizabeth Land, East Antarctica - climate and non-climate dependent variability of the surface mass balance and stable water isotopic composition

    Science.gov (United States)

    Vladimirova, D.; Ekaykin, A.; Lipenkov, V.; Popov, S. V.; Petit, J. R.; Masson-Delmotte, V.

    2017-12-01

    Glaciological and meteorological observations conducted during the past four decades in Princess Elizabeth Land, East Antarctica, are compiled. The database is used to investigate spatial patterns of surface snow isotopic composition and surface mass balance, including detailed information near subglacial lake Vostok. We show diverse relationships between snow isotopic composition and surface temperature. In the most inland part (elevation 3200-3400 m a.s.l.), surface snow isotopic composition varies independently from surface temperature, and is closely related to the distance to the open water source (with a slope of 0.98±0.17 ‰ per 100 km). Surface mass balance values are higher along the ice sheet slope, and relatively evenly distributed inland. The minimum values of snow isotopic composition and surface mass balance are identified in an area XX km southwestward from Vostok station. The spatial distribution of deuterium excess delineates regions influenced by the Indian Ocean and Pacific Ocean air masses, with Vostok area being situated close to their boundary. Anomalously high deuterium excess values are observed near Dome A, suggesting high kinetic fractionation for its moisture source, or specifically high post-deposition artifacts. The dataset is available for further studies such as the assessment of skills of general circulation or regional atmospheric models, and the search for the oldest ice.

  10. An atmospheric turbulence power factor to improve the estimation of surface deformation and atmosphere phase screen using SAR interferometry

    Science.gov (United States)

    Mulder, G.; van Leijen, F. J.; Barkmeijer, J.; Haan, de, S.; Hanssen, R. F.

    2017-12-01

    Differential atmospheric delays in (time series) InSAR data are still a main cause for uncertainties and errors in deformation estimates. Particularly when deformation signals cannot be parameterized with steady-state models, it is hard to distinguish spatial anomalies due to deformation or atmosphere, often occurring at the same spatial scales. Most approaches for atmospheric mitigation are based on the assumption that the atmospheric signal can be `averaged out' by using tens of SAR acquisitions. Implicitly, this also assumes that the magnitude of the atmospheric signal is rather constant over time. The analysis of the atmospheric phase screen related to a wide range of weather events has shown that the atmospheric signal due to turbulent mixing always follows a distinct multi-scale power-law behavior, where a single power factor can be used to differentiate various weather types. In this study we estimate and use this power factor to optimally weight the InSAR observations in a time-series based on atmospheric turbulence. Our method uses the phase variation in interferograms on different length scales to characterize the turbulence with one turbulence power factor, following Kolmogorov turbulence theory. This is done by fitting a -5/3 to -8/3 power function through the power spectrum of our data, which gives an indication of the total turbulence strength in the whole image. The strength of this method is that the power factor metric is robust for most wide- and small-scale deformations and can be summarized with a single number for each interferogram. We show how the application of power law scaling is beneficial both for optimal deformation signal estimation as well as atmospheric phase screen estimation to operationally assimilate InSAR atmospheric data in weather models.

  11. The relationship between sea surface temperature anomalies and atmospheric circulation in general circulation model experiments

    International Nuclear Information System (INIS)

    Kharin, V.V.

    1994-01-01

    Several multi-year integrations of the Hamburg version of the ECMWF/T21 general circulation model driven by the sea surface temperature (SST) observed in the period 1970-1988 were examined to study the extratropical response of the atmospheric circulation to SST anomalies in the Northern Hemisphere in winter. In the first 19-years run SST anomalies were prescribed globally (GAGO run), and in two others SST variability was limited to extratropical regions (MOGA run) and to tropics (TOGA run), respectively. A canonical correlation analysis was applied to the monthly means to find the best correlated patterns of SST anomalies in the Atlantic and Pacific Oceans and the Northern Hemisphere atmospheric flow. Contrary to expectation, the extratropical response in the GAGO run is not equal to the linear combination of the responses in the MOGA and TOGA runs. In the GAGO integration with globally prescribed SST the best correlated atmospheric pattern is global and is characterized by dipole structures of the same polarity in the North Atlantic and the North Pacific sectors. In the MOGA and TOGA experiments the atmospheric response is more local with main centers in the North Atlantic and North Pacific, respectively. The atmospheric modes found by the CCA were compared with the normal modes of the barotropic vorticity equation linearized about the 500 mb winter climate of the control integration driven by the climatological SST. The normal modes with smallest eigenvalues are similar to the canonical patterns of 500 mb geopotential height. The corresponding eigenvectors of the adjoint operator, which represent an external forcing optimal for exciting normal modes, have a longitudinal structure with maxima in regions characterized by enhanced high frequency baroclinic activity over both oceans. It was suggested that variability of storm tracks could play an important role in variability of the barotropic normal modes. (orig.)

  12. Seasonal variability in bacterial and fungal diversity of the near-surface atmosphere.

    Science.gov (United States)

    Bowers, Robert M; Clements, Nicholas; Emerson, Joanne B; Wiedinmyer, Christine; Hannigan, Michael P; Fierer, Noah

    2013-01-01

    Bacteria and fungi are ubiquitous throughout the Earth's lower atmosphere where they often represent an important component of atmospheric aerosols with the potential to impact human health and atmospheric dynamics. However, the diversity, composition, and spatiotemporal dynamics of these airborne microbes remain poorly understood. We performed a comprehensive analysis of airborne microbes across two aerosol size fractions at urban and rural sites in the Colorado Front Range over a 14-month period. Coarse (PM10-2.5) and fine (PM2.5) particulate matter samples were collected at weekly intervals with both bacterial and fungal diversity assessed via high-throughput sequencing. The diversity and composition of the airborne communities varied across the sites, between the two size fractions, and over time. Bacteria were the dominant type of bioaerosol in the collected air samples, while fungi and plants (pollen) made up the remainder, with the relative abundances of fungi peaking during the spring and summer months. As bacteria made up the majority of bioaerosol particles, we analyzed the bacterial communities in greater detail using a bacterial-specific 16S rRNA gene sequencing approach. Overall, bacterial taxonomic richness and the relative abundances of specific bacterial taxa exhibited significant patterns of seasonality. Likewise, airborne bacterial communities varied significantly between sites and across aerosol size fractions. Source-tracking analyses indicate that soils and leaves represented important sources of bacteria to the near-surface atmosphere across all locations with cow fecal bacteria also representing an important source of bioaerosols at the more rural sites during early fall and early spring. Together, these data suggest that a complex set of environmental factors, including changes in atmospheric conditions and shifts in the relative importance of available microbial sources, act to control the composition of microbial bioaerosols in rural and

  13. Development of an Organosilicon-Based Superhydrophobic/Icephobic Surface Using an Atmospheric Pressure Plasma Jet =

    Science.gov (United States)

    Asadollahi, Siavash

    During the past few decades, plasma-based surface treatment methods have gained a lot of interest in various applications such as thin film deposition, surface etching, surface activation and/or cleaning, etc. Generally, in plasma-based surface treatment methods, high-energy plasma-generated species are utilized to modify the surface structure or the chemical composition of a substrate. Unique physical and chemical characteristics of the plasma along with the high controllability of the process makes plasma treatment approaches very attractive in several industries. Plasma-based treatment methods are currently being used or investigated for a number of practical applications, such as adhesion promotion in auto industry, wound management and cancer treatment in biomedical industry, and coating development in aerospace industry. In this study, a two-step procedure is proposed for the development of superhydrophobic/icephobic coatings based on atmospheric-pressure plasma treatment of aluminum substrates using air and nitrogen plasma. The effects of plasma parameters on various surface properties are studied in order to identify the optimum conditions for maximum coating efficiency against icing and wetting. In the first step, the interactions between air or nitrogen plasma and the aluminum surface are studied. It is shown that by reducing jet-to-substrate distance, air plasma treatment, unlike nitrogen plasma treatment, is capable of creating micro-porous micro-roughened structures on the surface, some of which bear a significant resemblance to the features observed in laser ablation of metals with short and ultra-short laser pulses. The formation of such structures in plasma treatment is attributed to a transportation of energy from the jet to the surface over a very short period of time, in the range of picoseconds to microseconds. This energy transfer is shown to occur through a streamer discharge from the rotating arc source in the jet body to a close proximity of

  14. SURFACE CHEMISTRY AND PARTICLE SHAPE: PROCESSES FOR THE EVOLUTION OF AEROSOLS IN TITAN's ATMOSPHERE

    International Nuclear Information System (INIS)

    Lavvas, P.; Imanaka, H.; Sander, M.; Kraft, M.

    2011-01-01

    We use a stochastic approach in order to investigate the production and evolution of aerosols in Titan's atmosphere. The simulation initiates from the benzene molecules observed in the thermosphere and follows their evolution to larger aromatic structures through reaction with gas-phase radical species. Aromatics are allowed to collide and provide the first primary particles, which further grow to aggregates through coagulation. We also consider for the first time the contribution of heterogenous processes at the surface of the particles, which are described by the deposition of the formed aromatic structures on the surface of the particles, and also through the chemical reaction with radical species. Our results demonstrate that the evolution of aerosols in terms of size, shape, and density is a result of competing processes between surface growth, coagulation, and sedimentation. Furthermore, our simulations clearly demonstrate the presence of a spherical growth region in the upper atmosphere followed by a transition to an aggregate growth region below. The transition altitude ranges between 500 and 600 km based on the parameters of the simulation.

  15. Surface analysis of 316 stainless steel treated with cold atmospheric plasma

    Energy Technology Data Exchange (ETDEWEB)

    Williams, David F., E-mail: david.williams@surrey.ac.uk [Department of Mechanical Engineering Sciences, University Of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); TWI Ltd Granta Park Great Abington, Cambridge CB21 6AL (United Kingdom); Kellar, Ewen J.C. [TWI Ltd Granta Park Great Abington, Cambridge CB21 6AL (United Kingdom); Jesson, David A.; Watts, John F. [Department of Mechanical Engineering Sciences, University Of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

    2017-05-01

    Highlights: • Reduction in carbon contamination from ∼80 at.% to 40 at.% after 15 s treatment. • Associated carbon thickness reduction from 4.5 nm to 0.5 nm. • Area treated by torch has a diameter of 11 mm measured using imaging XPS. - Abstract: The surface of 316 stainless steel has been modified using cold atmospheric plasma (CAP) to increase the surface free energy (by cleaning the and chemically activating the surface)IN preparation for subsequent processes such as painting, coating or adhesive bonding. The analyses carried out, on CAP treated 316 stainless steel surfaces, includes X-ray photoelectron spectroscopy (XPS), imaging XPS (iXPS), and surface free energy (SFE) analysis using contact angle measurements. The CAP treatment is shown to increase the SFE of as-received 316 stainless steel from ∼39 mJ m{sup −1} to >72 mJ m{sup −1} after a short exposure to the plasma torch. This was found to correlate to a reduction in adventitious carbon, as determined by XPS analysis of the surface. The reduction from ∼90 at% to ∼30% and ∼39 at%, after being plasma treated for 5 min and 15 s respectively, shows that the process is relatively quick at changing the surface. It is suggested that the mechanism that causes the increase in surface free energy is chain scission of the hydrocarbon contamination triggered by free electrons in the plasma plume followed by chemical functionalisation of the metal oxide surface and some of the remaining carbon contamination layer.

  16. Preparation of Stable Superhydrophobic Coatings on Wood Substrate Surfaces via Mussel-Inspired Polydopamine and Electroless Deposition Methods

    Directory of Open Access Journals (Sweden)

    Kaili Wang

    2017-06-01

    Full Text Available Mussel-inspired polydopamine (PDA chemistry and electroless deposition approaches were used to prepare stable superhydrophobic coatings on wood surfaces. The as-formed PDA coating on a wood surface exhibited a hierarchical micro/nano roughness structure, and functioned as an “adhesive layer” between the substrate and a metallic film by the metal chelating ability of the catechol moieties on PDA, allowing for the formation of a well-developed micro/nanostructure hierarchical roughness. Additionally, the coating acted as a stable bridge between the substrate and hydrophobic groups. The morphology and chemical components of the prepared superhydrophobic wood surfaces were characterized by scanning electron microscopy (SEM, Fourier transform infrared (FT-IR spectroscopy, and X-ray photoelectron spectroscopy (XPS. The PDA and octadecylamine (OA modified surface showed excellent superhydrophobicity with a water contact angle (CA of about 153° and a rolling angle (RA of about 9°. The CA further increased to about 157° and RA reduced to about 5° with the Cu metallization. The superhydrophobic material exhibited outstanding stability in harsh conditions including ultraviolet aging, ultrasonic washing, strong acid-base and organic solvent immersion, and high-temperature water boiling. The results suggested that the PDA/OA layers were good enough to confer robust, degradation-resistant superhydrophobicity on wood substrates. The Cu metallization was likely unnecessary to provide significant improvements in superhydrophobic property. However, due to the amazing adhesive capacity of PDA, the electroless deposition technique may allow for a wide range of potential applications in biomimetic materials.

  17. A stable fused bicyclic disilene as a model for silicon surface.

    Science.gov (United States)

    Kobayashi, Hideki; Iwamoto, Takeaki; Kira, Mitsuo

    2005-11-09

    We synthesized the first fused bicyclic disilene 1 representing topologically a partial structure of the Si(001) surface up to the third layer. In the solid state, the five-membered rings adopt the envelope conformation, and the Si=Si double bond in 1 exists in the slightly cis-bent form (bent angle theta is 3.6 degrees ) compared to that of the highly cis-bent dimer on the Si(001) surface. Highly symmetric 1H NMR spectral pattern of 1 remains even at -80 degrees C, indicating the facile ring flipping of the bicyclic skeleton in solution. While syn-adduct was obtained in the reaction of 1 with water, anti-addition of chlorine atoms across the Si=Si double bond in 1 was observed in the reaction with carbon tetrachloride. The structural characteristics of the 9,10-phenanthrenequinone adduct 7 are in good accord with those of the proposed structure of the 9,10-phenanthrenequinone molecule adsorbed on the Si(001) surface.

  18. Friction and Adhesion Forces of Bacillus thuringiensis Spores on Planar Surfaces in Atmospheric Systems

    Energy Technology Data Exchange (ETDEWEB)

    Kweon, Hyojin [Georgia Inst. of Technology, Atlanta, GA (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2011-11-07

    The kinetic friction force and the adhesion force of Bacillus thuringiensis spores on planar surfaces in atmospheric systems were studied using atomic force microscopy. The influence of relative humidity (RH) on these forces varied for different surface properties including hydrophobicity, roughness, and surface charge. The friction force of the spore was greater on a rougher surface than on mica, which is atomically flat. As RH increases, the friction force of the spores decreases on mica whereas it increases on rough surfaces. The influence of RH on the interaction forces between hydrophobic surfaces is not as strong as for hydrophilic surfaces. The friction force of the spore is linear to the sum of the adhesion force and normal load on the hydrophobic surface. In conclusion, the poorly defined surface structure of the spore and the adsorption of contaminants from the surrounding atmosphere are believed to cause a discrepancy between the calculated and measured adhesion forces.

  19. Simulating carbon exchange using a regional atmospheric model coupled to an advanced land-surface model

    Directory of Open Access Journals (Sweden)

    H. W. Ter Maat

    2010-08-01

    Full Text Available This paper is a case study to investigate what the main controlling factors are that determine atmospheric carbon dioxide content for a region in the centre of The Netherlands. We use the Regional Atmospheric Modelling System (RAMS, coupled with a land surface scheme simulating carbon, heat and momentum fluxes (SWAPS-C, and including also submodels for urban and marine fluxes, which in principle should include the dominant mechanisms and should be able to capture the relevant dynamics of the system. To validate the model, observations are used that were taken during an intensive observational campaign in central Netherlands in summer 2002. These include flux-tower observations and aircraft observations of vertical profiles and spatial fluxes of various variables.

    The simulations performed with the coupled regional model (RAMS-SWAPS-C are in good qualitative agreement with the observations. The station validation of the model demonstrates that the incoming shortwave radiation and surface fluxes of water and CO2 are well simulated. The comparison against aircraft data shows that the regional meteorology (i.e. wind, temperature is captured well by the model. Comparing spatially explicitly simulated fluxes with aircraft observed fluxes we conclude that in general latent heat fluxes are underestimated by the model compared to the observations but that the latter exhibit large variability within all flights. Sensitivity experiments demonstrate the relevance of the urban emissions of carbon dioxide for the carbon balance in this particular region. The same tests also show the relation between uncertainties in surface fluxes and those in atmospheric concentrations.

  20. Stabilization of atmospheric carbon dioxide via zero emissions—An alternative way to a stable global environment. Part 1: Examination of the traditional stabilization concept

    Science.gov (United States)

    MATSUNO, Taroh; MARUYAMA, Koki; TSUTSUI, Junichi

    2012-01-01

    The concept of “stabilization” of atmospheric CO2 concentration is re-examined in connection with climate-change mitigation strategies. A new “zero-emissions stabilization (Z-stabilization)” is proposed, where CO2 emissions are reduced to zero at some time and thereafter the concentration is decreased by natural removal processes, eventually reaching an equilibrated stable state. Simplified climate experiments show that, under Z-stabilization, considerably larger emissions are permissible in the near future compared with traditional stabilization, with the same constraint on temperature rise. Over longer time scales, the concentration and temperature decrease close to their equilibrium values, much lower than those under traditional stabilization. The smaller temperature rise at final state is essential to avoid longer-term risk of sea level rise, a significant concern under traditional stabilization. Because of these advantages a Z-stabilization pathway can be a candidate of practical mitigation strategies as treated in Part 2. PMID:22850727

  1. Stabilization of atmospheric carbon dioxide via zero emissions--an alternative way to a stable global environment. Part 1: examination of the traditional stabilization concept.

    Science.gov (United States)

    Matsuno, Taroh; Maruyama, Koki; Tsutsui, Junichi

    2012-01-01

    The concept of "stabilization" of atmospheric CO(2) concentration is re-examined in connection with climate-change mitigation strategies. A new "zero-emissions stabilization (Z-stabilization)" is proposed, where CO(2) emissions are reduced to zero at some time and thereafter the concentration is decreased by natural removal processes, eventually reaching an equilibrated stable state. Simplified climate experiments show that, under Z-stabilization, considerably larger emissions are permissible in the near future compared with traditional stabilization, with the same constraint on temperature rise. Over longer time scales, the concentration and temperature decrease close to their equilibrium values, much lower than those under traditional stabilization. The smaller temperature rise at final state is essential to avoid longer-term risk of sea level rise, a significant concern under traditional stabilization. Because of these advantages a Z-stabilization pathway can be a candidate of practical mitigation strategies as treated in Part 2.

  2. Comparing atmosphere-land surface feedbacks from models within the tropics (CALM). Part 1: Evaluation of CMIP5 GCMs to simulate the land surface-atmosphere feedback

    Science.gov (United States)

    Williams, C.; Allan, R.; Kniveton, D.

    2012-04-01

    Man-made transformations to the environment, and in particular the land surface, are having a large impact on the distribution (in both time and space) of rainfall, upon which all life is reliant. From global changes in the composition of the atmosphere, through the emission of greenhouse gases and aerosols, to more localised land use and land cover changes due to an expanding population with an increasing ecological footprint, human activity has a considerable impact on the processes controlling rainfall. This is of particular importance for environmentally vulnerable regions such as many of those in the tropics. Here, widespread poverty, an extensive disease burden and pockets of political instability has resulted in a low resilience and limited adaptative capacity to climate related shocks and stresses. Recently, the 5th Climate Modelling Intercomparison Project (CMIP5) has run a number of state-of-the-art climate models using various present-day and future emission scenarios of greenhouse gases, and therefore provides an unprecedented amount of simulated model data. This paper presents the results of the first stage of a larger project, aiming to further our understanding of how the interactions between tropical rainfall and the land surface are represented in some of the latest climate model simulations. Focusing on precipitation, soil moisture and near-surface temperature, this paper compares the data from all of these models, as well as blended observational-satellite data, to see how the interactions between rainfall and the land surface differs (or agrees) between the models and reality. Firstly, in an analysis of the processes from the "observed" data, the results suggest a strong positive relationship between precipitation and soil moisture at both daily and seasonal timescales. There is a weaker and negative relationship between precipitation and temperature, and likewise between soil moisture and temperature. For all variables, the correlations are

  3. Arctic Radiation Measurement in Column: Atmosphere-Surface (ARMCAS) MODIS Airborne Simulator (MAS) Level-1B Data Products

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of the Arctic Radiation Measurement in Column: Atmosphere-Surface (ARMCAS) experiment was to detect and differentiate between clouds, ice, and snow...

  4. Assessing the near surface sensitivity of SCIAMACHY atmospheric CO2 retrieved using (FSI WFM-DOAS

    Directory of Open Access Journals (Sweden)

    N. Vinnichenko

    2007-07-01

    Full Text Available Satellite observations of atmospheric CO2 offer the potential to identify regional carbon surface sources and sinks and to investigate carbon cycle processes. The extent to which satellite measurements are useful however, depends on the near surface sensitivity of the chosen sensor. In this paper, the capability of the SCIAMACHY instrument on board ENVISAT, to observe lower tropospheric and surface CO2 variability is examined. To achieve this, atmospheric CO2 retrieved from SCIAMACHY near infrared (NIR spectral measurements, using the Full Spectral Initiation (FSI WFM-DOAS algorithm, is compared to in-situ aircraft observations over Siberia and additionally to tower and surface CO2 data over Mongolia, Europe and North America. Preliminary validation of daily averaged SCIAMACHY/FSI CO2 against ground based Fourier Transform Spectrometer (FTS column measurements made at Park Falls, reveal a negative bias of about −2.0% for collocated measurements within ±1.0° of the site. However, at this spatial threshold SCIAMACHY can only capture the variability of the FTS observations at monthly timescales. To observe day to day variability of the FTS observations, the collocation limits must be increased. Furthermore, comparisons to in-situ CO2 observations demonstrate that SCIAMACHY is capable of observing a seasonal signal that is representative of lower tropospheric variability on (at least monthly timescales. Out of seventeen time series comparisons, eleven have correlation coefficients of 0.7 or more, and have similar seasonal cycle amplitudes. Additional evidence of the near surface sensitivity of SCIAMACHY, is provided through the significant correlation of FSI derived CO2 with MODIS vegetation indices at over twenty selected locations in the United States. The SCIAMACHY/MODIS comparison reveals that at many of the sites, the amount of CO2 variability is coincident with the amount of vegetation activity. The presented analysis suggests that

  5. Seasonality of stable isotope composition of atmospheric water input at the southern slopes of Mt. Kilimanjaro, Tanzania

    Science.gov (United States)

    Otte, Insa; Detsch, Florian; Gutlein, Adrian; Scholl, Martha A.; Kiese, Ralf; Appelhans, Tim; Nauss, Thomas

    2017-01-01

    To understand the moisture regime at the southern slopes of Mt. Kilimanjaro, we analysed the isotopic variability of oxygen (δ18O) and hydrogen (δD) of rainfall, throughfall, and fog from a total of 2,140 samples collected weekly over 2 years at 9 study sites along an elevation transect ranging from 950 to 3,880 m above sea level. Precipitation in the Kilimanjaro tropical rainforests consists of a combination of rainfall, throughfall, and fog. We defined local meteoric water lines for all 3 precipitation types individually and the overall precipitation, δDprec = 7.45 (±0.05) × δ18Oprec + 13.61 (±0.20), n = 2,140, R2 = .91, p research site. We found an altitude effect of δ18Orain = −0.11‰ × 100 m−1, which varied according to precipitation type and season. The relatively weak isotope or altitude gradient may reveal 2 different moisture sources in the research area: (a) local moisture recycling and (b) regional moisture sources. Generally, the seasonality of δ18Orain values follows the bimodal rainfall distribution under the influences of south- and north-easterly trade winds. These seasonal patterns of isotopic composition were linked to different regional moisture sources by analysing Hybrid Single Particle Lagrangian Integrated Trajectory backward trajectories. Seasonality of dexcess values revealed evidence of enhanced moisture recycling after the onset of the rainy seasons. This comprehensive dataset is essential for further research using stable isotopes as a hydrological tracer of sources of precipitation that contribute to water resources of the Kilimanjaro region.

  6. Progress in Understanding Land-Surface-Atmosphere Coupling from LBA Research

    Directory of Open Access Journals (Sweden)

    Alan K Betts

    2010-06-01

    Full Text Available LBA research has deepened our understanding of the role of soil water storage, clouds and aerosols in land-atmosphere coupling. We show how the reformulation of cloud forcing in terms of an effective cloud albedo per unit area of surface gives a useful measure of the role of clouds in the surface energy budget over the Amazon. We show that the diurnal temperature range has a quasi-linear relation to the daily mean longwave cooling; and to effective cloud albedo because of the tight coupling between the near-surface climate, the boundary layer and the cloud field. The coupling of surface and atmospheric processes is critical to the seasonal cycle: deep forest rooting systems make water available throughout the year, whereas in the dry season the shortwave cloud forcing is reduced by regional scale subsidence, so that more light is available for photosynthesis. At sites with an annual precipitation above 1900 mm and a dry season length less than 4 months, evaporation rates increased in the dry season, coincident with increased radiation. In contrast, ecosystems with precipitation less than 1700 mm and a longer dry season showed clear evidence of reduced evaporation in the dry season coming from water stress. In all these sites, the seasonal variation of the effective cloud albedo is a major factor in determining the surface available energy. Dry season fires add substantial aerosol to the atmosphere. Aerosol scattering and absorption both reduce the total downward surface radiative flux, but increase the diffuse/direct flux ratio, which increases photosynthetic efficiency. Convective plumes produced by fires enhance the vertical transport of aerosols over the Amazon, and effectively inject smoke aerosol and gases directly into the middle troposphere with substantial impacts on mid- tropospheric dispersion. In the rainy season in Rondônia, convection in low-level westerly flows with low aerosol content resembles oceanic convection with

  7. Influence of different land surfaces on atmospheric conditions measured by a wireless sensor network

    Science.gov (United States)

    Lengfeld, Katharina; Ament, Felix

    2010-05-01

    Atmospheric conditions close to the surface, like temperature, wind speed and humidity, vary on small scales because of surface heterogeneities. Therefore, the traditional measuring approach of using a single, highly accurate station is of limited representativeness for a larger domain, because it is not able to determine these small scale variabilities. However, both the variability and the domain averages are important information for the development and validation of atmospheric models and soil-vegetation-atmosphere-transfer (SVAT) schemes. Due to progress in microelectronics it is possible to construct networks of comparably cheap meteorological stations with moderate accuracy. Such a network provides data in high spatial and temporal resolution. The EPFL Lausanne developed such a network called SensorScope, consisting of low cost autonomous stations. Each station observes air and surface temperature, humidity, wind direction and speed, incoming solar radiation, precipitations, soil moisture and soil temperature and sends the data via radio communication to a base station. This base station forwards the collected data via GSM/GPRS to a central server. Within the FLUXPAT project in August 2009 we deployed 15 stations as a twin transect near Jülich, Germany. One aim of this first experiment was to test the quality of the low cost sensors by comparing them to more accurate reference measurements. It turned out, that although the network is not highly accurate, the measurements are consistent. Consequently an analysis of the pattern of atmospheric conditions is feasible. For example, we detect a variability of ± 0.5K in the mean temperature at a distance of only 2.3 km. The transect covers different types of vegetation and a small river. Therefore, we analyzed the influence of different land surfaces and the distance to the river on meteorological conditions. On the one hand, some results meet our expectations, e.g. the relative humidity decreases with increasing

  8. Study on the reforming of alcohols in a surface wave discharge (SWD) at atmospheric pressure

    International Nuclear Information System (INIS)

    Jimenez, M; Yubero, C; Calzada, M D

    2008-01-01

    Surface wave plasma at atmospheric pressure has been used to produce the decomposition of the alcohol molecules introduced into it, in order to obtain hydrogen. Four alcohols, methanol, ethanol, propanol and butanol, have been used for this purpose. Optical emission spectroscopy was the tool used to analyse the radiation emitted by the plasma. Hydrogen atoms and other species such as C 2 and CH in alcohols have been detected but no CO molecular bands. Also, a mass spectrometer has been used in order to detect molecular hydrogen production in methanol decomposition

  9. The spatiotemporal dynamics of microbes in the near-surface atmosphere

    Science.gov (United States)

    Bowers, Robert Michael

    With this dissertation, I present four culture independent studies examining the spatiotemporal distributions of microbial communities in the near-surface atmosphere. The goals of this dissertation work were to examine the biogeographical patterns that airborne microbes exhibit over a variety of spatiotemporal scales, and to determine the likely sources of bacteria to the near-surface environment. First I explored the short-term (two-week) changes in microbial community structure (bacteria, fungi and pollen) of the near surface atmosphere at the high elevation research site, Storm Peak Laboratory, located in northern Colorado, USA. This study revealed that the nearsurface atmosphere is abundant with microbes, and that the airborne communities are composed of taxa that are typical of cold environments. Additionally, the bacteria identified in the air samples showed high sequence similarity to bacterial lineages possessing the ice nucleating phenotype, suggesting the possibility of bacterial induced cloud formation. Second, I examined the spatial diversity of airborne bacterial communities across the three dominant land-use types of the Colorado Front Range: forests, suburban areas, and agricultural sites. The airborne communities exhibited significant community level shifts across the three land-use types, however the differences could not be attributed to the prevailing meteorological conditions, suggesting that the characteristics of the local terrestrial surfaces have a greater influence on the airborne communities than the prevailing meteorology. Overall, the airborne communities above the three land-use types appeared to be unique to potential source environments, however the taxa driving the land-use patterns were related to those taxa that were indicative of either soils or leaf surfaces. Third, I carried out a seasonal (summer and winter) study of the airborne bacterial communities of the Great Lakes region of the USA. The bacterial communities inhabiting

  10. Investigation of surface treatment of conductive wire in cylindrical atmospheric pressure plasmas

    International Nuclear Information System (INIS)

    Ye Rubin; Kagohashi, Tsutomu; Zheng Wei

    2009-01-01

    Polyethylene insulated electric wire was treated in He and Ar dielectric barrier discharge atmospheric pressure plasmas generated in a quartz tube wound with tubular electrodes. The wire was put penetrating through the high voltage and the grounded electrodes, improving the discharge and facilitating uniform surface treatment. In this work, the influences of conductivity of the wire on the effects of surface treatment and discharge behavior were investigated. Surface properties of the wire samples were analyzed by means of surface energy measurement and X-ray photoelectron spectroscopy. In order to reveal the mechanism for treating the conductive wire, I-V discharge waveforms were measured and time-resolved plasma images were taken. It was demonstrated that the conductive wire was involved in the discharge process, reducing the breakdown voltage significantly and enhancing the discharge. It shows that the discharge mode was strongly dependent on the conductivity of a wire. Intensive surface discharges developed along the conductive wire were found to be mainly responsible for noticeable improvement in the treatment effect.

  11. Influence of radioactivity on surface charging and aggregation kinetics of particles in the atmosphere.

    Science.gov (United States)

    Kim, Yong-Ha; Yiacoumi, Sotira; Lee, Ida; McFarlane, Joanna; Tsouris, Costas

    2014-01-01

    Radioactivity can influence surface interactions, but its effects on particle aggregation kinetics have not been included in transport modeling of radioactive particles. In this research, experimental and theoretical studies have been performed to investigate the influence of radioactivity on surface charging and aggregation kinetics of radioactive particles in the atmosphere. Radioactivity-induced charging mechanisms have been investigated at the microscopic level, and heterogeneous surface potential caused by radioactivity is reported. The radioactivity-induced surface charging is highly influenced by several parameters, such as rate and type of radioactive decay. A population balance model, including interparticle forces, has been employed to study the effects of radioactivity on particle aggregation kinetics in air. It has been found that radioactivity can hinder aggregation of particles because of similar surface charging caused by the decay process. Experimental and theoretical studies provide useful insights into the understanding of transport characteristics of radioactive particles emitted from severe nuclear events, such as the recent accident of Fukushima or deliberate explosions of radiological devices.

  12. Hydrophilic film polymerized on the inner surface of PMMA tube by an atmospheric pressure plasma jet

    Science.gov (United States)

    Yin, Mengmeng; Huang, Jun; Yu, Jinsong; Chen, Guangliang; Qu, Shanqing

    2017-07-01

    Polymethyl methacrylate (PMMA) tube is widely used in biomedical and mechanical engineering fields. However, it is hampered for some special applications as the inner surface of PMMA tube exhibts a hydrophobic characteristic. The aim of this work is to explore the hydrophilic modification of the inner surface of the PMMA tubes using an atmospheric pressure plasma jet (APPJ) system that incorporates the acylic acid monomer (AA). Polar groups were grafted onto the inner surface of PMMA tube via the reactive radicals (•OH, •H, •O) generated in the Ar/O2/AA plasma, which were observed by the optical emission spectroscopy (OES). The deposition of the PAA thin layer on the PMMA surface was verified through the ATR-FTIR spectra, which clearly showed the strengthened stretching vibration of the carbonyl group (C=O) at 1700 cm-1. The XPS data show that the carbon ratios of C-OH/R and COOH/R groups increased from 9.50% and 0.07% to 13.49% and 17.07% respectively when a discharge power of 50 W was used in the APPJ system. As a result, the static water contat angle (WCA) of the modified inner surface of PMMA tube decreased from 100° to 48°. Furthermore, the biocompatibility of the APP modified PMMA tubes was illustrated by the study of the adhesion of the cultured MC3T3-E1 osteocyte cells, which exhibted a significantly enhanced adhesion density.

  13. Atmospherically derived organic surface films along an urban-rural gradient.

    Science.gov (United States)

    Gingrich, S E; Diamond, M L; Stern, G A; McCarry, B E

    2001-10-15

    Atmospherically derived organic films have been found on an impervious surface along an urban-rural gradient in the Toronto, Ontario, Canada area. Film thickness and concentrations, expressed on an aerial basis, of sigman-alkanes, sigmaPCB, sigmaPAH, and sigmaOC (organochlorine) pesticides decrease along this gradient, coincident with lower atmospheric emissions (PCB and PAH) and less accumulation in thinner rural films (OC pesticides). For PCBs and some OC pesticides, patterns of chemical abundance also shift, indicating a "fresh" pattern near emission sources (downtown) versus aged patterns at rural locations that are indicative of atmospheric transport. Plant-derived n-alkane concentrations were greater at urban than rural sites, and we hypothesize greater urban plant wax production and erosion due to air pollution. As expected, along the urban-rural gradient the concentration of particle-phase PAH decreased more rapidly than that of gas-phase compounds, but unexpectedly the contribution of alkylated PAH increased from urban to rural locations. Distances over which concentrations decline by 63% vary from 50 km for persistent gas-phase compounds (e.g., P1,2CB) to 10-20 km for reactive gas-phase compounds (e.g., naphthalene, fluoranthene) to particle-phase compounds (e.g., P6-10CB, benzo[b]fluoranthene, benzo[e]pyrene).

  14. HTO transfer from contaminated surfaces to the atmosphere: a database for model validation

    International Nuclear Information System (INIS)

    Davis, P.A.; Amiro, B.D.; Workman, W.J.G.; Corbett, B.J.

    1996-12-01

    This report comprises a detailed database that can be used to validate models of the emission of tritiated water vapour (HTO) from natural contaminated surfaces to the atmosphere. The data were collected in 1992 July during an intensive field study based on the flux-gradient method of micrometeorology. The measurements were made over a wetland area at the Chalk River Laboratories, and over a grassed field near the Pickering Nuclear Generating Station. The study sites, the sampling protocols and the analytical techniques are described in detail, and the measured fluxes are presented. The report also contains a detailed listing of HTO concentrations in air at two heights, HTO concentrations in the source compartments (soil, surface water and vegetation), supporting meteorological data, and various vegetation and soil properties. The uncertainties in all of the measured data are estimated. (author). 15 refs., 23 tabs., 9 figs

  15. Surface Stress with Non-stationary Weak Winds and Stable Stratification

    Science.gov (United States)

    Mahrt, L.; Thomas, Christoph K.

    2016-04-01

    The behaviour of turbulent transport in the weak-wind, stably-stratified, boundary layer over land is examined in terms of the non-stationarity of the wind field using measurements from three field programs. These field programs include towers ranging from 12 to 20 m in height and an extensive horizontal network of sonic anemometers. The relationship of the friction velocity to the stratification and non-stationary submeso motions is investigated from several points of view and nominally quantified. The relationship of the turbulence to the stratification is less systematic than expected partly due to enhancement of the turbulence by submeso motions. Cause and effect relationships are difficult to isolate because the non-stationary momentum flux significantly modifies the profile of the non-stationary mean flow. The link between the turbulence and accelerations at the surface is examined in terms of the changing vertical structure of the wind profile and sudden increases in the downward transport of momentum.

  16. A novel metamaterial filter with stable passband performance based on frequency selective surface

    Directory of Open Access Journals (Sweden)

    C. Y. Fang

    2014-07-01

    Full Text Available In this paper, a novel metamaterial filter based on frequency selective surface (FSS is proposed. Using the mode matching method, we theoretically studied the transmission performance of the structure. Results show that, by rotating its neighboring elements 90 degree, the novel filter has a better stability to angle of incidence than traditional structures for TE and TM polarization. As the incident angles vary from 0 to 50 degrees, the metamaterial filter exhibits a transmittance higher than 0.98 and the center frequency slightly shifts downward (from 10 GHz to 0.96 GHz for TE polarization. For TM polarization, a transmittance of 0.98 is achieved and the center frequency retains 0.96 GHz with the varying of the incident angles. Furthermore, an experimental prototype fabricated was tested in a microwave chamber, and the measured results show good agreement with the simulated ones.

  17. Observation of Stable Low Surface Resistance in Large-Grain Niobium SRF Cavities

    Energy Technology Data Exchange (ETDEWEB)

    Geng, Rongli [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Huang, Shichun [Institute of Modern Physics (IMP)/Chinese Academy of Sciences (CAS), Lanzhou (China)

    2016-05-01

    Low surface resistance, or high unloaded quality factor (Q0), superconducting radio frequency (SRF) cavities are being pursued actively nowadays as their application in large-scale CW SRF accelerators can save capital and operational cost in cryogenics. There are different options in realization of such cavities. One of them is the large-grain (LG) niobium cavity. In this contribution, we present new experimental results in evaluation of LG niobium cavities cooled down in the presence of an external magnetic field. High Q0 values are achieved even with an ambient magnetic field of up to 100 mG. More over, it is observed that these high Q0 values are super-robust against repeated quench, literally not affected at all after the cavity being deliberately quenched for hundreds of times in the presence of an ambient magnetic field of up to 200 mG.

  18. Chemically immobilised carbon nanotubes on silicon: Stable surfaces for aqueous electrochemistry

    International Nuclear Information System (INIS)

    Flavel, Benjamin S.; Garrett, David J.; Lehr, Joshua; Shapter, Joseph G.; Downard, Alison J.

    2010-01-01

    Diazonium ion chemistry has been used to electrochemically graft aminophenyl layers onto p-type silicon (1 0 0) substrates. A condensation reaction was used to immobilise single-walled carbon nanotubes with high carboxylic acid functionality directly to this layer. Electrochemical monitoring of the aminophenyl groups confirmed the formation of an amide linkage between the single-walled carbon nanotubes and the aminophenyl layer. The carbon nanotube electrode showed high stability and good electrochemical performance in aqueous solution. At moderate scan rates the Ru(NH 3 ) 6 +3/+2 couple exhibited quasi-reversible electron transfer kinetics with a standard heterogenous rate constant of 1.2 x 10 -3 cm s -1 at the covalently-linked carbon nanotube surface. The electrode thus combines the advantages of a silicon substrate for easy integration into sophisticated electrical and electronic devices, carbon nanotubes for desirable electrochemical properties, and stability in aqueous medium for future applications in environmental sensing.

  19. An efficient physically based parameterization to derive surface solar irradiance based on satellite atmospheric products

    Science.gov (United States)

    Qin, Jun; Tang, Wenjun; Yang, Kun; Lu, Ning; Niu, Xiaolei; Liang, Shunlin

    2015-05-01

    Surface solar irradiance (SSI) is required in a wide range of scientific researches and practical applications. Many parameterization schemes are developed to estimate it using routinely measured meteorological variables, since SSI is directly measured at a very limited number of stations. Even so, meteorological stations are still sparse, especially in remote areas. Remote sensing can be used to map spatiotemporally continuous SSI. Considering the huge amount of satellite data, coarse-resolution SSI has been estimated for reducing the computational burden when the estimation is based on a complex radiative transfer model. On the other hand, many empirical relationships are used to enhance the retrieval efficiency, but the accuracy cannot be guaranteed out of regions where they are locally calibrated. In this study, an efficient physically based parameterization is proposed to balance computational efficiency and retrieval accuracy for SSI estimation. In this parameterization, the transmittances for gases, aerosols, and clouds are all handled in full band form and the multiple reflections between the atmosphere and surface are explicitly taken into account. The newly proposed parameterization is applied to estimate SSI with both Moderate Resolution Imaging Spectroradiometer (MODIS) atmospheric and land products as inputs. These retrievals are validated against in situ measurements at the Surface Radiation Budget Network and at the North China Plain on an instantaneous basis, and moreover, they are validated and compared with Global Energy and Water Exchanges-Surface Radiation Budget and International Satellite Cloud Climatology Project-flux data SSI estimates at radiation stations of China Meteorological Administration on a daily mean basis. The estimation results indicates that the newly proposed SSI estimation scheme can effectively retrieve SSI based on MODIS products with mean root-mean-square errors of about 100 Wm- 1 and 35 Wm- 1 on an instantaneous and daily

  20. Development of Innovative Technology to Provide Low-Cost Surface Atmospheric Observations

    Science.gov (United States)

    Kucera, Paul; Steinson, Martin

    2016-04-01

    Accurate and reliable real-time monitoring and dissemination of observations of surface weather conditions is critical for a variety of societal applications. Applications that provide local and regional information about temperature, precipitation, moisture, and winds, for example, are important for agriculture, water resource monitoring, health, and monitoring of hazard weather conditions. In many regions in Africa (and other global locations), surface weather stations are sparsely located and/or of poor quality. Existing stations have often been sited incorrectly, not well-maintained, and have limited communications established at the site for real-time monitoring. The US National Weather Service (NWS) International Activities Office (IAO) in partnership with University Corporation for Atmospheric Research (UCAR)/National Center for Atmospheric Research (NCAR) and funded by the United States Agency for International Development (USAID) Office of Foreign Disaster Assistance (OFDA) has started an initiative to develop and deploy low-cost weather instrumentation in sparsely observed regions of the world. The goal is to provide observations for environmental monitoring, and early warning alert systems that can be deployed at weather services in developing countries. Instrumentation is being designed using innovative new technologies such as 3D printers, Raspberry Pi computing systems, and wireless communications. The initial effort is focused on designing a surface network using GIS-based tools, deploying an initial network in Zambia, and providing training to Zambia Meteorological Department (ZMD) staff. The presentation will provide an overview of the project concepts, design of the low cost instrumentation, and initial experiences deploying a surface network deployment in Zambia.

  1. Retrieving 4-dimensional atmospheric boundary layer structure from surface observations and profiles over a single station

    Energy Technology Data Exchange (ETDEWEB)

    Pu, Zhaoxia [Univ. of Utah, Salt Lake City, UT (United States)

    2015-10-06

    Most routine measurements from climate study facilities, such as the Department of Energy’s ARM SGP site, come from individual sites over a long period of time. While single-station data are very useful for many studies, it is challenging to obtain 3-dimensional spatial structures of atmospheric boundary layers that include prominent signatures of deep convection from these data. The principal objective of this project is to create realistic estimates of high-resolution (~ 1km × 1km horizontal grids) atmospheric boundary layer structure and the characteristics of precipitating convection. These characteristics include updraft and downdraft cumulus mass fluxes and cold pool properties over a region the size of a GCM grid column from analyses that assimilate surface mesonet observations of wind, temperature, and water vapor mixing ratio and available profiling data from single or multiple surface stations. The ultimate goal of the project is to enhance our understanding of the properties of mesoscale convective systems and also to improve their representation in analysis and numerical simulations. During the proposed period (09/15/2011–09/14/2014) and the no-cost extension period (09/15/2014–09/14/2015), significant accomplishments have been achieved relating to the stated goals. Efforts have been extended to various research and applications. Results have been published in professional journals and presented in related science team meetings and conferences. These are summarized in the report.

  2. Development of Innovative Technology to Provide Low-Cost Surface Atmospheric Observations in Data Sparse Regions

    Science.gov (United States)

    Kucera, Paul; Steinson, Martin

    2017-04-01

    Accurate and reliable real-time monitoring and dissemination of observations of surface weather conditions is critical for a variety of societal applications. Applications that provide local and regional information about temperature, precipitation, moisture, and winds, for example, are important for agriculture, water resource monitoring, health, and monitoring of hazard weather conditions. In many regions of the World, surface weather stations are sparsely located and/or of poor quality. Existing stations have often been sited incorrectly, not well-maintained, and have limited communications established at the site for real-time monitoring. The University Corporation for Atmospheric Research (UCAR)/National Center for Atmospheric Research (NCAR), with support from USAID, has started an initiative to develop and deploy low-cost weather instrumentation in sparsely observed regions of the world. The project is focused on improving weather observations for environmental monitoring and early warning alert systems on a regional to global scale. Instrumentation that has been developed use innovative new technologies such as 3D printers, Raspberry Pi computing systems, and wireless communications. The goal of the project is to make the weather station designs, software, and processing tools an open community resource. The weather stations can be built locally by agencies, through educational institutions, and residential communities as a citizen effort to augment existing networks to improve detection of natural hazards for disaster risk reduction. The presentation will provide an overview of the open source weather station technology and evaluation of sensor observations for the initial networks that have been deployed in Africa.

  3. Airborne Measurement of Insolation Impact on the Atmospheric Surface Boundary Layer

    Science.gov (United States)

    Jacob, Jamey; Chilson, Phil; Houston, Adam; Detweiler, Carrick; Bailey, Sean; Cloud-Map Team

    2017-11-01

    Atmospheric surface boundary layer measurements of wind and thermodynamic parameters are conducted during variable insolation conditions, including the 2017 eclipse, using an unmanned aircraft system. It is well known that the air temperatures can drop significantly during a total solar eclipse as has been previously observed. In past eclipses, these observations have primarily been made on the ground. We present results from airborne measurements of the near surface boundary layer using a small unmanned aircraft with high temporal resolution wind and thermodynamic observations. Questions that motivate the study include: How does the temperature within the lower atmospheric boundary vary during an eclipse? What impact does the immediate removal of radiative heating on the ground have on the lower ABL? Do local wind patterns change during an eclipse event and if so why? Will there be a manifestation of the nocturnal boundary layer wind maximum? Comparisons are made with the DOE ARM SGP site that experiences a lower but still significant insolation. Supported by the National Science Foundation under Award Number 1539070.

  4. Land surface and atmospheric conditions associated with heat waves in the South Central United States

    Science.gov (United States)

    Lee, Eungul; Bieda, Rahama; Shanmugasundaram, Jothiganesh; Richter, Heather

    2017-04-01

    Exposure to extreme heat was reconstructed based on regional land-atmosphere processes from 1979 to 2010 in the South Central U.S. The study region surrounds the Chickasaw Nation (CN), a predominantly Native American population with a highly prevalent burden of climate-sensitive chronic diseases. Land surface and atmospheric conditions for summer heat waves were analyzed during spring (March-April-May, MAM) and summer (June-July-August, JJA) based on the Climate and Ocean: Variability, Predictability, and Change maximum temperature definition for heat wave frequency (HWF). The spatial-temporal pattern of HWF was determined using empirical orthogonal function (EOF) analysis and the corresponding principle component time series of the first EOF of HWF. Statistically significant analyses of observed conditions indicated that sensible heat increased and latent heat fluxes decreased with high HWF in the South Central U.S. The largest positive correlations of sensible heat flux to HWF and the largest negative correlations of latent heat flux to HWF were specifically observed over the CN. This is a significantly different energy transfer regime due to less available soil moisture during the antecedent MAM and JJA. The higher sensible heat from dry soil could cause significant warming from the near surface (> 2.0°C) to the lower troposphere (> 1.5°C), and accumulated boundary layer heat could induce the significant patterns of higher geopotential height and enhance anticyclonic circulations (negative vorticity anomaly) at the midtroposphere. Results suggested a positive land-atmosphere feedback associated with heat waves and called attention to the need for region-specific climate adaptation planning.

  5. In vitro characterization of two different atmospheric plasma jet chemical functionalizations of titanium surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Mussano, F., E-mail: federico.mussano@unito.it [CIR Dental School, Department of Surgical Sciences UNITO, via Nizza 230, 10126, Turin (Italy); Genova, T. [CIR Dental School, Department of Surgical Sciences UNITO, via Nizza 230, 10126, Turin (Italy); Department of Life Sciences and Systems Biology, UNITO, via Accademia Albertina 13, 10123, Turin (Italy); Verga Falzacappa, E. [Department of Molecular Science and Nanosystems, UNIVE, Via Torino 155, 30170, Venezia (Italy); Nadir srl, Via Torino 155, 30170 Venezia (Italy); Scopece, P. [Nadir srl, Via Torino 155, 30170 Venezia (Italy); Munaron, L. [Department of Life Sciences and Systems Biology, UNITO, via Accademia Albertina 13, 10123, Turin (Italy); Centre for Nanostructured Interfaces and Surfaces (NIS) (Italy); Rivolo, P.; Mandracci, P. [Politecnico di Torino, Department of Applied Science and Technology, Materials and Microsoystems Laboratory (ChiLab), Corso Duca degli Abruzzi 24, 10129, Torino (Italy); Benedetti, A. [Department of Molecular Science and Nanosystems, UNIVE, Via Torino 155, 30170, Venezia (Italy); Carossa, S. [CIR Dental School, Department of Surgical Sciences UNITO, via Nizza 230, 10126, Turin (Italy); Patelli, A. [Department of Physics and Astronomy, UNIPD, via Marzolo 8, 35122 Padova (Italy)

    2017-07-01

    Highlights: • NH{sub 2}-Ti and COOH/R-Ti obtained via atmospheric plasma jet RF-APPJ portable equipment. • Higher quantity of adsorbed proteins and improved cell adhesion on treated surfaces. • More tapered and elongated cells on NH{sub 2}-Ti compared to COOH/R-Ti. • Higher osteocalcin expression on NH{sub 2}-Ti. - Abstract: Plasma surface activation and plasma polymers deposition are promising technologies capable to modulate biologically relevant surface features of biomaterials. The purpose of this study was to evaluate the biological effects of two different surface modifications, i.e. amine (NH{sub 2}-Ti) and carboxylic/esteric (COOH/R-Ti) functionalities obtained from 3-aminopropyltriethoxysilane (3-APTES) and methylmethacrylate (MMA) precursors, respectively, through an atmospheric plasma jet RF-APPJ portable equipment. The coatings were characterized by Scanning Electron Microscopy, FT-IR spectroscopy, XPS and surface energy calculations. Stability in water and after UV sterilization were also verified. The pre-osteoblastic murine cell line MC3T3-E1 was used to perform the in-vitro tests. The treated samples showed a higher quantity of adsorbed proteins and improved osteoblast cells adhesion on the surfaces compared to the pristine titanium, in particular the COOH/R-Ti led to a nearly two-fold improvement. Cell proliferation on coated samples was initially (at 24 h) lower than on titanium control, while, at 48 h, COOH/R-Ti reached the proliferation rate of pristine titanium. Cells grown on NH{sub 2}-Ti were more tapered and elongated in shape with lower areas than on COOH/R-Ti enriched surfaces. Finally, NH{sub 2}-Ti significantly enhanced osteocalcin production, starting from 14 days, while COOH/R-Ti had this effect only from 21 days. Notably, NH{sub 2}-Ti was more efficient than COOH/R-Ti at 21 days. The amine functionality elicited the most relevant osteogenic effect in terms of osteocalcin expression, thus establishing an interesting correlation

  6. Stable isotopes in the atmospheric marine boundary layer water vapour over the Atlantic Ocean, 2012–2015

    Science.gov (United States)

    Benetti, Marion; Steen-Larsen, Hans Christian; Reverdin, Gilles; Sveinbjörnsdóttir, Árný Erla; Aloisi, Giovanni; Berkelhammer, Max B.; Bourlès, Bernard; Bourras, Denis; de Coetlogon, Gaëlle; Cosgrove, Ann; Faber, Anne-Katrine; Grelet, Jacques; Hansen, Steffen Bo; Johnson, Rod; Legoff, Hervé; Martin, Nicolas; Peters, Andrew J.; Popp, Trevor James; Reynaud, Thierry; Winther, Malte

    2017-01-01

    The water vapour isotopic composition (1H216O, H218O and 1H2H16O) of the Atlantic marine boundary layer has been measured from 5 research vessels between 2012 and 2015. Using laser spectroscopy analysers, measurements have been carried out continuously on samples collected 10–20 meter above sea level. All the datasets have been carefully calibrated against the international VSMOW-SLAP scale following the same protocol to build a homogeneous dataset covering the Atlantic Ocean between 4°S to 63°N. In addition, standard meteorological variables have been measured continuously, including sea surface temperatures using calibrated Thermo-Salinograph for most cruises. All calibrated observations are provided with 15-minute resolution. We also provide 6-hourly data to allow easier comparisons with simulations from the isotope-enabled Global Circulation Models. In addition, backwards trajectories from the HYSPLIT model are supplied every 6-hours for the position of our measurements. PMID:28094798

  7. Surface transport and stable trapping of particles and cells by an optical waveguide loop.

    Science.gov (United States)

    Hellesø, Olav Gaute; Løvhaugen, Pål; Subramanian, Ananth Z; Wilkinson, James S; Ahluwalia, Balpreet Singh

    2012-09-21

    Waveguide trapping has emerged as a useful technique for parallel and planar transport of particles and biological cells and can be integrated with lab-on-a-chip applications. However, particles trapped on waveguides are continuously propelled forward along the surface of the waveguide. This limits the practical usability of the waveguide trapping technique with other functions (e.g. analysis, imaging) that require particles to be stationary during diagnosis. In this paper, an optical waveguide loop with an intentional gap at the centre is proposed to hold propelled particles and cells. The waveguide acts as a conveyor belt to transport and deliver the particles/cells towards the gap. At the gap, the diverging light fields hold the particles at a fixed position. The proposed waveguide design is numerically studied and experimentally implemented. The optical forces on the particle at the gap are calculated using the finite element method. Experimentally, the method is used to transport and trap micro-particles and red blood cells at the gap with varying separations. The waveguides are only 180 nm thick and thus could be integrated with other functions on the chip, e.g. microfluidics or optical detection, to make an on-chip system for single cell analysis and to study the interaction between cells.

  8. CONDITIONS FOR STABLE CHIP BREAKING AND PROVISION OF MACHINED SURFACE QUALITY WHILE TURNING WITH ASYMMETRIC TOOL VIBRATIONS

    Directory of Open Access Journals (Sweden)

    V. K. Sheleh

    2015-01-01

    Full Text Available The paper considers a process of turning structural steel with asymmetric tool vibrations directed along feeding. Asymmetric vibrations characterized by asymmetry coefficient of vibration cycle, their frequency and amplitude are additionally transferred to the tool in the turning process with the purpose to crush chips. Conditions of stable chip breaking and obtaining optimum dimensions of chip elements have been determined in the paper. In order to reduce a negative impact of the vibration amplitude on a cutting process and quality of the machined surfaces machining must be carried out with its minimum value. In this case certain ratio of the tool vibration frequency to the work-piece rotation speed has been ensured in the paper. A formula has been obtained for calculation of this ratio with due account of the expected length of chip elements and coefficient of vibration cycle asymmetry.Influence of the asymmetric coefficient of the tool vibration cycle on roughness of the machined surfaces and cutting tool wear has been determined in the paper. According to the results pertaining to machining of work-pieces made of 45 and ШХ15 steel the paper presents mathematical relationships of machined surface roughness with cutting modes and asymmetry coefficient of tool vibration cycle. Tool feeding being one of the cutting modes exerts the most significant impact on the roughness value and increase of the tool feeding entails increase in roughness. Reduction in coefficient of vibration cycle asymmetry contributes to surface roughness reduction. However, the cutting tool wear occurs more intensive. Coefficient of the vibration cycle asymmetry must be increased in order to reduce wear rate. Therefore, the choice of the coefficient of the vibration cycle asymmetry is based on the parameters of surface roughness which must be obtained after machining and intensity of tool wear rate.The paper considers a process of turning structural steel with asymmetric

  9. Relation between the Atmospheric Boundary Layer and Impact Factors under Severe Surface Thermal Conditions

    Directory of Open Access Journals (Sweden)

    Yinhuan Ao

    2017-01-01

    Full Text Available This paper reported a comprehensive analysis on the diurnal variation of the Atmospheric Boundary Layer (ABL in summer of Badain Jaran Desert and discussed deeply the effect of surface thermal to ABL, including the Difference in Surface-Air Temperature (DSAT, net radiation, and sensible heat, based on limited GPS radiosonde and surface observation data during two intense observation periods of experiments. The results showed that (1 affected by topography of the Tibetan Plateau, the climate provided favorable external conditions for the development of Convective Boundary Layer (CBL, (2 deep CBL showed a diurnal variation of three- to five-layer structure in clear days and five-layer ABL structure often occurred about sunset or sunrise, (3 the diurnal variation of DSAT influenced thickness of ABL through changes of turbulent heat flux, (4 integral value of sensible heat which rapidly converted by surface net radiation had a significant influence on the growth of CBL throughout daytime. The cumulative effect of thick RML dominated the role after CBL got through SBL in the development stage, especially in late summer, and (5 the development of CBL was promoted and accelerated by the variation of wind field and distribution of warm advection in high and low altitude.

  10. Prolonged silicon carbide integrated circuit operation in Venus surface atmospheric conditions

    Directory of Open Access Journals (Sweden)

    Philip G. Neudeck

    2016-12-01

    Full Text Available The prolonged operation of semiconductor integrated circuits (ICs needed for long-duration exploration of the surface of Venus has proven insurmountably challenging to date due to the ∼ 460 °C, ∼ 9.4 MPa caustic environment. Past and planned Venus landers have been limited to a few hours of surface operation, even when IC electronics needed for basic lander operation are protected with heavily cumbersome pressure vessels and cooling measures. Here we demonstrate vastly longer (weeks electrical operation of two silicon carbide (4H-SiC junction field effect transistor (JFET ring oscillator ICs tested with chips directly exposed (no cooling and no protective chip packaging to a high-fidelity physical and chemical reproduction of Venus’ surface atmosphere. This represents more than 100-fold extension of demonstrated Venus environment electronics durability. With further technology maturation, such SiC IC electronics could drastically improve Venus lander designs and mission concepts, fundamentally enabling long-duration enhanced missions to the surface of Venus.

  11. Time-resolved PIV measurements of the atmospheric boundary layer over wind-driven surface waves

    Science.gov (United States)

    Markfort, Corey; Stegmeir, Matt

    2017-11-01

    Complex interactions at the air-water interface result in two-way coupling between wind-driven surface waves and the atmospheric boundary layer (ABL). Turbulence generated at the surface plays an important role in aquatic ecology and biogeochemistry, exchange of gases such as oxygen and carbon dioxide, and it is important for the transfer of energy and controlling evaporation. Energy transferred from the ABL promotes the generation and maintenance of waves. A fraction of the energy is transferred to the surface mixed layer through the generation of turbulence. Energy is also transferred back to the ABL by waves. There is a need to quantify the details of the coupled boundary layers of the air-water system to better understand how turbulence plays a role in the interactions. We employ time-resolved PIV to measure the detailed structure of the air and water boundary layers under varying wind and wave conditions in the newly developed IIHR Boundary-Layer Wind-Wave Tunnel. The facility combines a 30-m long recirculating water channel with an open-return boundary layer wind tunnel. A thick turbulent boundary layer is developed in the 1 m high air channel, over the water surface, allowing for the study of boundary layer turbulence interacting with a wind-driven wave field.

  12. The Impact of Wind Speed Changes on the Surface Stress in the Weak-wind Stable Boundary Layer

    Science.gov (United States)

    Thomas, C. K.

    2015-12-01

    The behaviour of turbulent transport in the weak-wind stably stratified boundary layer is examined in terms of the non-stationarity of the wind field based upon field observations. Extensive sonic anemometer measurements from horizontal networks and vertical towers ranging from 12 to 20 m height were collected from three field programs in moderately sloped terrain with a varying degree of surface heterogeneity, namely the Shallow Cold Pool (SCP) and the Flow Over Snow Surfaces (FLOSS) II experiments in Colorado (USA), and the Advanced Canopy Resolution Experiment (ARCFLO) in Oregon (USA). The relationship of the friction velocity to the stratification and small non-stationary submeso motions is studied from several points of view and nominally quantified. The relationship of the turbulence to the stratification is less systematic than expected due to the important submeso-scale motions. Consequently, the roles of the wind speed and stratification are not adequately accommodated by a single non-dimensional combination, such as the bulk Richardson number. Howver, cause and effect relationships are difficult to isolate because the non-stationary momentum flux significantly modifies the profile of the non-stationary mean flow. The link between the turbulence and accelerations at the surface is examined in terms of the changing vertical structure of the wind profile and sudden increases of downward transport of momentum. The latter may be significant in explaining the small-scale weak turbulence during stable stratification and deviations from conventional flux-profile relationships.

  13. In vitro characterization of two different atmospheric plasma jet chemical functionalizations of titanium surfaces

    Science.gov (United States)

    Mussano, F.; Genova, T.; Verga Falzacappa, E.; Scopece, P.; Munaron, L.; Rivolo, P.; Mandracci, P.; Benedetti, A.; Carossa, S.; Patelli, A.

    2017-07-01

    Plasma surface activation and plasma polymers deposition are promising technologies capable to modulate biologically relevant surface features of biomaterials. The purpose of this study was to evaluate the biological effects of two different surface modifications, i.e. amine (NH2-Ti) and carboxylic/esteric (COOH/R-Ti) functionalities obtained from 3-aminopropyltriethoxysilane (3-APTES) and methylmethacrylate (MMA) precursors, respectively, through an atmospheric plasma jet RF-APPJ portable equipment. The coatings were characterized by Scanning Electron Microscopy, FT-IR spectroscopy, XPS and surface energy calculations. Stability in water and after UV sterilization were also verified. The pre-osteoblastic murine cell line MC3T3-E1 was used to perform the in-vitro tests. The treated samples showed a higher quantity of adsorbed proteins and improved osteoblast cells adhesion on the surfaces compared to the pristine titanium, in particular the COOH/R-Ti led to a nearly two-fold improvement. Cell proliferation on coated samples was initially (at 24 h) lower than on titanium control, while, at 48 h, COOH/R-Ti reached the proliferation rate of pristine titanium. Cells grown on NH2-Ti were more tapered and elongated in shape with lower areas than on COOH/R-Ti enriched surfaces. Finally, NH2-Ti significantly enhanced osteocalcin production, starting from 14 days, while COOH/R-Ti had this effect only from 21 days. Notably, NH2-Ti was more efficient than COOH/R-Ti at 21 days. The amine functionality elicited the most relevant osteogenic effect in terms of osteocalcin expression, thus establishing an interesting correlation between early cell morphology and later differentiation stages. Taken together, these data encourage the use of the functionalization procedures here reported in further studies.

  14. Low temperature atmospheric microplasma jet array for uniform treatment of polymer surface for flexible electronics

    Science.gov (United States)

    Wang, Tao; Wang, Xiaolin; Yang, Bin; Chen, Xiang; Yang, Chunsheng; Liu, Jingquan

    2017-07-01

    In this paper, the uniformity of polymer film etching by an atmospheric pressure He/O2 microplasma jet array (μPJA) is first investigated with different applied voltage. Plasma characteristics of μPJA were recorded by optical discharge images. Morphologies and chemical compositions of polymer film etched by μPJA were analyzed by optical microscopy, scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDS) and x-ray photoelectron spectroscopy (XPS). By increasing the applied voltage from 8.5 kV to 16.4 kV, the non-uniformity of the luminous intensity of the plasma jets increases. It is interesting that the plasma treated regions are actually composed of an etched region and modification region, with distinct morphologies and chemical compositions. The diameters of the etched parylene-C film show the increase of non-uniformity with higher applied voltage. SEM results show that the non-uniformity of surface morphologies of both the modification regions and etched regions increases with the increase of applied voltage. EDS and XPS results also present the significant effect of higher applied voltage on the non-uniformity of surface chemical compositions of both modification and etched regions. The Coulomb interaction of the streamer heads and the hydrodynamic interaction between the plasma jets and the surrounding air are considered to be responsible for this phenomenon. The results shown in this work can help improve the processing quality of polymer film etched by an atmospheric pressure microplasma jet array and two applications are demonstrated to illustrate the uniform downstream surface treatment.

  15. Atmospheric Compensation and Surface Temperature and Emissivity Retrieval with LWIR Hyperspectral Imagery

    Science.gov (United States)

    Pieper, Michael

    Accurate estimation or retrieval of surface emissivity spectra from long-wave infrared (LWIR) or Thermal Infrared (TIR) hyperspectral imaging data acquired by airborne or space-borne sensors is necessary for many scientific and defense applications. The at-aperture radiance measured by the sensor is a function of the ground emissivity and temperature, modified by the atmosphere. Thus the emissivity retrieval process consists of two interwoven steps: atmospheric compensation (AC) to retrieve the ground radiance from the measured at-aperture radiance and temperature-emissivity separation (TES) to separate the temperature and emissivity from the ground radiance. In-scene AC (ISAC) algorithms use blackbody-like materials in the scene, which have a linear relationship between their ground radiances and at-aperture radiances determined by the atmospheric transmission and upwelling radiance. Using a clear reference channel to estimate the ground radiance, a linear fitting of the at-aperture radiance and estimated ground radiance is done to estimate the atmospheric parameters. TES algorithms for hyperspectral imaging data assume that the emissivity spectra for solids are smooth compared to the sharp features added by the atmosphere. The ground temperature and emissivity are found by finding the temperature that provides the smoothest emissivity estimate. In this thesis we develop models to investigate the sensitivity of AC and TES to the basic assumptions enabling their performance. ISAC assumes that there are perfect blackbody pixels in a scene and that there is a clear channel, which is never the case. The developed ISAC model explains how the quality of blackbody-like pixels affect the shape of atmospheric estimates and the clear channel assumption affects their magnitude. Emissivity spectra for solids usually have some roughness. The TES model identifies four sources of error: the smoothing error of the emissivity spectrum, the emissivity error from using the incorrect

  16. Gemini NorthNIRI Spectra of Pluto and Charon: Simultaneous Analysis of the Surface and Atmosphere

    Science.gov (United States)

    Cook, Jason C.; Cruikshank, Dale P.; Young, Leslie A.

    2014-01-01

    94035We report on our analysis of blended Pluto and Charon spectra over the wavelength range 1.4 to 2.5 m as obtained by the NIRI instrument on Gemini North on June 25-28, 2004. The data have a resolving power () around 1500 and a SNR around 200 per pixel. The observed blended spectra are compared to models that combine absorption from the solid ice on the surface using Hapke theory, and absorption from the gaseous atmosphere. We assume the spectrum is a combination of several spatially separate spectral units: a CH4-rich ice unit, a volatile unit (an intimate mixture of N2, CH4 and CO), and a Charon unit (H2O, ammonia hydrate and kaolinite). We test for the presence of hydrocarbons (i.e. C2H6) and nitriles (i.e. HCN) and examine cases where additional ices are present as either pure separate spatial units, mixed with the CH4-rich unit or part of the volatile unit. We conclude that 2-4 of Plutos surface is covered with pure-C2H6 and our identification of C2H6 is significantly strengthened when absorption due to gaseous CH4 is included. The inclusion of Plutos atmosphere demonstrates that low-resolution, high-SNR observations are capable of detecting Plutos atmosphere during a time when Plutos atmosphere may have been undergoing rapid changes (1988-2002) and no high-resolution spectra were obtained. In particular, we identify features at 1.665 and 2.317 m as the Q-branch of the 23 and 3+4 bands of gaseous CH4, respectively. The later band is also evident in many previously published spectra of Pluto. Our analysis finds it is unnecessary to include 13CO to explain the depth of the 2.405 m, which has been previously suggested to be a spectral blended with C2H6, but we cannot definitively rule out its presence. Funding for this work (Cook) has been provided by a NASA-PATM grant.

  17. Fabricating a Homogeneously Alloyed AuAg Shell on Au Nanorods to Achieve Strong, Stable, and Tunable Surface Plasmon Resonances

    KAUST Repository

    Huang, Jianfeng

    2015-08-13

    Colloidal metal nanocrystals with strong, stable, and tunable localized surface plasmon resonances (SPRs) can be useful in a corrosive environment for many applications including field-enhanced spectroscopies, plasmon-mediated catalysis, etc. Here, a new synthetic strategy is reported that enables the epitaxial growth of a homogeneously alloyed AuAg shell on Au nanorod seeds, circumventing the phase segregation of Au and Ag encountered in conventional synthesis. The resulting core–shell structured bimetallic nanorods (AuNR@AuAg) have well-mixed Au and Ag atoms in their shell without discernible domains. This degree of mixing allows AuNR@AuAg to combine the high stability of Au with the superior plasmonic activity of Ag, thus outperforming seemingly similar nanostructures with monometallic shells (e.g., Ag-coated Au NRs (AuNR@Ag) and Au-coated Au NRs (AuNR@Au)). AuNR@AuAg is comparable to AuNR@Ag in plasmonic activity, but that it is markedly more stable toward oxidative treatment. Specifically, AuNR@AuAg and AuNR@Ag exhibit similarly strong signals in surface-enhanced Raman spectroscopy that are some 30-fold higher than that of AuNR@Au. When incubated with a H2O2 solution (0.5 m), the plasmonic activity of AuNR@Ag immediately and severely decayed, whereas AuNR@AuAg retained its activity intact. Moreover, the longitudinal SPR frequency of AuNR@AuAg can be tuned throughout the red wavelengths (≈620–690 nm) by controlling the thickness of the AuAg alloy shell. The synthetic strategy is versatile to fabricate AuAg alloyed shells on different shaped Au, with prospects for new possibilities in the synthesis and application of plasmonic nanocrystals.

  18. Algorithm for Recovery of Integrated Water Vapor Content in the Atmosphere over Land Surfaces Based on Satellite Spectroradiometer Data

    Science.gov (United States)

    Lisenko, S. A.

    2017-05-01

    An algorithm is proposed for making charts of the distribution of water vapor in the atmosphere based on multispectral images of the earth by the Ocean and Land Color Instrument (OLCI) on board of the European research satellite Sentinel-3. The algorithm is based on multiple regression fits of the spectral brightness coefficients at the upper boundary of the atmosphere, the geometric parameters of the satellite location (solar and viewing angles), and the total water vapor content in the atmosphere. A regression equation is derived from experimental data on the variation in the optical characteristics of the atmosphere and underlying surface, together with Monte-Carlo calculations of the radiative transfer characteristics. The equation includes the brightness coefficients in the near IR channels of the OLCI for the absorption bands of water vapor and oxygen, as well as for the transparency windows of the atmosphere. Together these make it possible to eliminate the effect of the reflection spectrum of the underlying surface and air pressure on the accuracy of the measurements. The algorithm is tested using data from a prototype OLCI, the medium resolution imaging spectrometer (MERIS). A sample chart of the distribution of water vapor in the atmosphere over Eastern Europe is constructed without using subsatellite data and digital models of the surface relief. The water vapor contents in the atmosphere determined using MERIS images and data provided by earthbound measurements with the aerosol robotic network (AERONET) are compared with a mean square deviation of 1.24 kg/m2.

  19. Arctic summertime measurements of ammonia in the near-surface atmosphere

    Science.gov (United States)

    Moravek, A.; Murphy, J. G.; Wentworth, G.; Croft, B.; Martin, R.

    2016-12-01

    Measurements of gas-phase ammonia (NH3) in the summertime Arctic are rare, despite the impact NH3 can have on new particle formation rates and nitrogen deposition. The presence of NH3 can also increase the ratio of particulate-phase ammonium (NH4+) to non-sea salt sulphate (nss-SO42-) which decreases particle acidity. Known regional sources of NH3in the Arctic summertime include migratory seabird colonies and northern wildfires, whereas the Arctic Ocean is a net sink. In the summer of 2016, high time resolution measurements were collected in the Arctic to improve our understanding of the sources, sinks and impacts of ammonia in this remote region. A four week study was conducted at Alert, Canada (82.5º N, 62.3 º W) from June 23 to July 19, 2016 to examine the magnitude and sources of NH3 and SO42-. The Ambient Ion Monitor-Ion Chromatography system (AIM-IC) provided on-line, hourly averaged measurements of NH3, NH4+, SO42- and Na+. Measurements of NH3 ranged between 50 and 700 pptv (campaign mean of 240 pptv), consistent with previous studies in the summertime Arctic boundary layer. Levels of NH4+ and nss-SO42- were near or below detection limits ( 20 ng m-3) for the majority of the study. Tundra and lake samples were collected to investigate whether these could be important local sources of NH3 at Alert. These surface samples were analyzed for NH4+, pH and temperature and a compensation point (χ) for each sample was calculated to determine if these surface reservoirs can act as net NH3 sources. Precipitation samples were also collected throughout the study to better constrain our understanding of wet NH4+deposition in the summertime Arctic. From mid-July through August, 2016, NH3 was measured continuously using a laser spectroscopy technique onboard the Canadian Coast Guard Ship Amundsen in the eastern Arctic Ocean. Ocean-atmosphere exchange of NH3 was quantified using measurements of sea surface marine NH4+ concentrations. In addition, wet deposition of

  20. Investigation of the electron emission properties of silver: From exposed to ambient atmosphere Ag surface to ion-cleaned Ag surface

    Energy Technology Data Exchange (ETDEWEB)

    Gineste, T., E-mail: Thomas.Gineste@onera.fr [ONERA The French Aerospace Lab, 31055 Toulouse (France); Belhaj, M. [ONERA The French Aerospace Lab, 31055 Toulouse (France); Teyssedre, G. [LAPLACE - Laboratoire Plasma et Conversion d’Energie -UMR 5213, Université Paul Sabatier - 118, route de Narbonne, 31062 Toulouse Cedex (France); Puech, J. [CNES, 18 Avenue Edouard Belin 31055 Toulouse Cédex 9 (France)

    2015-12-30

    Highlights: • We investigated the electron emission yield of an air exposed Ag to a cleaned Ag. • Air exposed Ag sample was cleaned by ion Ar etching. • Surface composition was determined by AES. • Electron emission yield was related to surface composition evolution. • Natural contamination hugely influence electron properties of Ag sample. - Abstract: Electron emission properties of materials are highly dependent to the surface and the first nanometres subsurface. Technical materials, i.e. used within applications are ordinarily exposed to atmosphere, which interacts with the surface. The contamination layer building up at the surface of materials and/or oxidation layer affects dramatically the electron emission proprieties. In this paper, starting from 99.99% pure silver sample, exposed 4 years to ambient atmosphere, we monitored the variations of the electron emission properties and the surface composition during step by step ion etching procedure.

  1. Interaction of Convective Organization and Monsoon Precipitation, Atmosphere, Surface and Sea (INCOMPASS)

    Science.gov (United States)

    Turner, A. G.; Bhat, G. S.; Evans, J. G.; Madan, R.; Marsham, J. H.; Martin, G.; Mitra, A. K.; Mrudula, G.; Parker, D. J.; Pattnaik, S.; Rajagopal, E. N.; Taylor, C.; Tripathi, S. N.

    2016-12-01

    INCOMPASS will build on a field and aircraft measurement campaign from the 2016 monsoon onset to better understand and predict monsoon rainfall. The monsoon supplies the majority of water in South Asia, however modelling and forecasting the monsoon from days to the season ahead is limited by large model errors that develop quickly. Likely problems lie in physical parametrizations such as convection, the boundary layer and land surface. At the same time, lack of detailed observations prevents more thorough understanding of monsoon circulation and its interaction with the land surface; a process governed by boundary layer and convective cloud dynamics. From May to July 2016, INCOMPASS used a modified BAe-146 jet aircraft operated by the UK Facility for Airborne Atmospheric Measurements (FAAM), for the first project of this scale in India. The India and UK team flew around 100 hours of science sorties from bases in northern and southern India. Flights from Lucknow in the northern plains took measurements to the west and southeast to allow sampling of the complete contrast from dry desert air to the humid environment over the north Bay of Bengal. These routes were repeated in the pre-monsoon and monsoon phases, measuring contrasting surface and boundary layer structures. In addition, flights from the southern base in Bengaluru measured contrasts from the Arabian Sea, across the intense rains of the Western Ghats mountains, over the rain shadow in southeast India and over the southern Bay of Bengal. Flight planning was performed with the aid of forecasts from a new UK Met Office 4km limited area model. INCOMPASS also installed a network of surface flux towers, as well as operating a cloud-base ceilometer and performing intensive radiosonde launches from a supersite in Kanpur. This presentation will outline preliminary results from the field campaign including new observations of the surface, boundary layer structure and atmospheric profiles together with detailed

  2. The impact of changes in parameterizations of surface drag and vertical diffusion on the large-scale circulation in the Community Atmosphere Model (CAM5)

    Science.gov (United States)

    Lindvall, Jenny; Svensson, Gunilla; Caballero, Rodrigo

    2017-06-01

    Simulations with the Community Atmosphere Model version 5 (CAM5) are used to analyze the sensitivity of the large-scale circulation to changes in parameterizations of orographic surface drag and vertical diffusion. Many GCMs and NWP models use enhanced turbulent mixing in stable conditions to improve simulations, while CAM5 cuts off all turbulence at high stabilities and instead employs a strong orographic surface stress parameterization, known as turbulent mountain stress (TMS). TMS completely dominates the surface stress over land and reduces the near-surface wind speeds compared to simulations without TMS. It is found that TMS is generally beneficial for the large-scale circulation as it improves zonal wind speeds, Arctic sea level pressure and zonal anomalies of the 500-hPa stream function, compared to ERA-Interim. It also alleviates atmospheric blocking frequency biases in the Northern Hemisphere. Using a scheme that instead allows for a modest increase of turbulent diffusion at higher stabilities only in the planetary boundary layer (PBL) appears to in some aspects have a similar, although much smaller, beneficial effect as TMS. Enhanced mixing throughout the atmospheric column, however, degrades the CAM5 simulation. Evaluating the simulations in comparison with detailed measurements at two locations reveals that TMS is detrimental for the PBL at the flat grassland ARM Southern Great Plains site, giving too strong wind turning and too deep PBLs. At the Sodankylä forest site, the effect of TMS is smaller due to the larger local vegetation roughness. At both sites, all simulations substantially overestimate the boundary layer ageostrophic flow.

  3. The effects of large-scale atmospheric flows on berylium-7 activity concentration in surface air.

    Science.gov (United States)

    Arkian, Foroozan; Meshkatee, Amir-Hussain; Bidokhti, Ali Akbar

    2010-09-01

    Understanding the exchange mechanism between stratosphere and troposphere is one of the most important concerns of meteorologists and climatologists for decades. Different methods are being adopted to study those mechanisms. One of those methods is the study upon the tropospheric concentration of conserve or passive entities with stratospheric origin. One of those passive entities is (7)Be that is produced upon the incident of cosmic rays on light atmospheric nuclei in the stratosphere. The availability of 5 years observations of (7)Be concentration in surface air in Tehran (35 degrees 41(') N, 51 degrees 18(') E) encouraged us to investigate meteorological condition effect on the surface concentration of (7)Be. Also, the intention was to see if there was any intrusion of stratospheric air into the troposphere at the time of high surface concentration of (7)Be and scavenging mechanism when the concentration was low. During the course of this study, it has been found that (7)Be concentration is high whenever there is a jet stream over Tehran. Since high-level jet streams normally form near tropopause folding, it could be interpreted as a sign of the intrusion of stratospheric air into the troposphere. It was also found that high concentration of (7)Be in the Tehran surface air in summer is associated with an upper ridge on 500 hPa surface located east of the city, and low concentration in winter is associated with an upper trough. The latter normally is seen whenever there is precipitation that suggests wet scavenging could be the reason for that observed low concentration.

  4. Saturn's Titan: Surface change, ammonia, and implications for atmospheric and tectonic activity

    Science.gov (United States)

    Nelson, R.M.; Kamp, L.W.; Matson, D.L.; Irwin, P.G.J.; Baines, K.H.; Boryta, M.D.; Leader, F.E.; Jaumann, R.; Smythe, W.D.; Sotin, Christophe; Clark, R.N.; Cruikshank, D.P.; Drossart, P.; Pearl, J.C.; Hapke, B.W.; Lunine, J.; Combes, M.; Bellucci, G.; Bibring, J.-P.; Capaccioni, F.; Cerroni, P.; Coradini, A.; Formisano, V.; Filacchione, G.; Langevin, R.Y.; McCord, T.B.; Mennella, V.; Nicholson, P.D.; Sicardy, B.

    2009-01-01

    Titan is known to have a young surface. Here we present evidence from the Cassini Visual and Infrared Mapping Spectrometer that it is currently geologically active. We report that changes in the near-infrared reflectance of a 73,000 km2 area on Titan (latitude 26° S, longitude 78° W) occurred between July 2004 and March of 2006. The reflectance of the area increased by a factor of two between July 2004 and March–April 2005; it then returned to the July 2004 level by November 2005. By late December 2005 the reflectance had surged upward again, establishing a new maximum. Thereafter, it trended downward for the next three months. Detailed spectrophotometric analyses suggest these changes happen at or very near the surface. The spectral differences between the region and its surroundings rule out changes in the distribution of the ices of reasonably expected materials such as H2O, CO2, and CH4 as possible causes. Remarkably, the change is spectrally consistent with the deposition and removal of NH3 frost over a water ice substrate. NH3 has been proposed as a constituent of Titan's interior and has never been reported on the surface. The detection of NH3 frost on the surface might possibly be explained by episodic effusive events occur which bring juvenile ammonia from the interior to the surface. If so, its decomposition would feed nitrogen to the atmosphere now and in the future. The lateral extent of the region exceeds that of active areas on the Earth (Hawaii) or Io (Loki).

  5. Causes of plasma column contraction in surface-wave-driven discharges in argon at atmospheric pressure

    Science.gov (United States)

    Ridenti, Marco Antonio; de Amorim, Jayr; Dal Pino, Arnaldo; Guerra, Vasco; Petrov, George

    2018-01-01

    In this work we compute the main features of a surface-wave-driven plasma in argon at atmospheric pressure in view of a better understanding of the contraction phenomenon. We include the detailed chemical kinetics dynamics of Ar and solve the mass conservation equations of the relevant neutral excited and charged species. The gas temperature radial profile is calculated by means of the thermal diffusion equation. The electric field radial profile is calculated directly from the numerical solution of the Maxwell equations assuming the surface wave to be propagating in the TM00 mode. The problem is considered to be radially symmetrical, the axial variations are neglected, and the equations are solved in a self-consistent fashion. We probe the model results considering three scenarios: (i) the electron energy distribution function (EEDF) is calculated by means of the Boltzmann equation; (ii) the EEDF is considered to be Maxwellian; (iii) the dissociative recombination is excluded from the chemical kinetics dynamics, but the nonequilibrium EEDF is preserved. From this analysis, the dissociative recombination is shown to be the leading mechanism in the constriction of surface-wave plasmas. The results are compared with mass spectrometry measurements of the radial density profile of the ions Ar+ and Ar2+. An explanation is proposed for the trends seen by Thomson scattering diagnostics that shows a substantial increase of electron temperature towards the plasma borders where the electron density is small.

  6. Surface air pollution with oxidized tritium during its momentary fallout with atmospheric precipitations

    International Nuclear Information System (INIS)

    Vorontsov, A.I.; Koloskov, I.A.; Nekozyrev, A.F.; Pastukhov, B.V.

    1976-01-01

    Regularities of the behaviour of tritium fallen out to the surface of the Earth as a result of peaceful thermonuclear explosions and the operation of atomic power plants were studied. With this purpose in view determined was the velocity of the decnatural ontamination of the soil-vegetation cover contaminated with tritium oxide due to evapouration, in connection with the density of the area contamination and the tritium content in the near-ground layer of iar. The study was carried out by modelling a single fallout of tritium oxide with atmospheric precipita--tions in different seasons of the year. Fallouts were simulated by applying tritiated water to experimental plots located in the forest-and-steppe zone. It has been found out that the intensive evapouration of tritium occurs during the first day after the contamination. The content of oxidized tritium in the near-ground layer of air is determined by the density of the contamination of the upper layer of soil, depends on the size of the contaminated territory and meteorological conditions. A model of the moving out of oxidized tritium into the atmosphere is obtained after it has fallen out to the ground; this model quantitatively describes the process of its evapouration into the near-ground layer of air

  7. Modelling of contamination of surface atmosphere for deflation of Cesium-137 on contaminated territories

    International Nuclear Information System (INIS)

    Bogdanov, A.P.; Zhmura, G.M.

    1994-01-01

    Presence of Cesium 137 in near land air is caused at the contaminated territories by 'local' dusting and transport of the dust from the zone of strong contamination. For large distance is it caused by resuspension of radioactive dust from the surface in the given region. In accordance with the models of dusting round square sources based on Gauss statistical model of dissemination of admixtures in the atmosphere, the contaminated areas of european part of the former of USSR with the density of contamination over 1 Ci/km 2 with Cesium 137 were represented by 30 round square sources covering the main spots of contamination. The results of calculation of contamination of the atmosphere for several cities of Belarus, Russia and Ukraine, where there are the permanent points of observation for the content of radionuclides in the air, have shown that the proposed model of dusting sources describes the contamination of near land air with Cesium 137 reasonably well. 7 refs., 3 tabs

  8. Extended verification of the model of dynamic near-surface layer of the atmosphere

    Science.gov (United States)

    Polnikov, V. G.

    2013-07-01

    This paper formulates the most general principles for verifying models of the dynamic near-water layer of the atmosphere (DNWLA) and performs an advanced verification of the model proposed by the author earlier [6]. Based on empirical wave spectra from the studies by Donelan [15], Elfouhaily [14], and Kudryavtsev [13] and well-known empirical laws describing the wave-age dependence of the friction coefficient, we adjusted the original version of the model. It was shown that the improvement of model reliability is most dependent on the adequacy of the parameterization of the tangential portion of the total momentum flux to the wavy surface. Then the new version of the model was verified on the basis of field data from two different groups of authors. It was found that the new version of the model is consistent with empirical data with an error not exceeding the measurement error of near-water layer parameters.

  9. Deriving aerosol properties from measurements of the Atmosphere-Surface Radiation Automatic Instrument (ASRAI)

    Science.gov (United States)

    Xu, Hua; Li, Donghui; Li, Zhengqiang; Zheng, Xiaobing; Li, Xin; Xie, Yisong; Liu, Enchao

    2015-10-01

    The Atmosphere-surface Radiation Automatic Instrument (ASRAI) is a newly developed hyper-spectral apparatus by Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences (AIOFM, CAS), measuring total spectral irradiance, diffuse spectral irradiance of atmosphere and reflected radiance of the land surface for the purpose of in-situ calibration. The instrument applies VIS-SWIR spectrum (0.4~1.0 μm) with an averaged spectral resolution of 0.004 μm. The goal of this paper is to describe a method of deriving both aerosol optical depth (AOD) and aerosol modes from irradiance measurements under free cloudy conditions. The total columnar amounts of water vapor and oxygen are first inferred from solar transmitted irradiance at strong absorption wavelength. The AOD together with total columnar amounts of ozone and nitrogen dioxide are determined by a nonlinear least distance fitting method. Moreover, it is able to infer aerosol modes from the spectral dependency of AOD because different aerosol modes have their inherent spectral extinction characteristics. With assumption that the real aerosol is an idea of "external mixing" of four basic components, dust-like, water-soluble, oceanic and soot, the percentage of volume concentration of each component can be retrieved. A spectrum matching technology based on Euclidean-distance method is adopted to find the most approximate combination of components. The volume concentration ratios of four basic components are in accordance with our prior knowledge of regional aerosol climatology. Another advantage is that the retrievals would facilitate the TOA simulation when applying 6S model for satellite calibration.

  10. Atmospheric river impacts on Greenland Ice Sheet surface melt and mass balance

    Science.gov (United States)

    Mattingly, K.; Mote, T. L.

    2017-12-01

    Mass loss from the Greenland Ice Sheet (GrIS) has accelerated during the early part of the 21st Century. Several episodes of widespread GrIS melt in recent years have coincided with intense poleward moisture transport by atmospheric rivers (ARs), suggesting that variability in the frequency and intensity of these events may be an important driver of the surface mass balance (SMB) of the GrIS. ARs may contribute to GrIS surface melt through the greenhouse effect of water vapor, the radiative effects of clouds, condensational latent heating within poleward-advected air masses, and the energy provided by liquid precipitation. However, ARs may also provide significant positive contributions to GrIS SMB through enhanced snow accumulation. Prior research on the role of ARs in Arctic climate has consisted of case studies of ARs associated with major GrIS melt events or examined the effects of poleward moisture flux on Arctic sea ice. In this study, a long-term (1979-2016) record of intense moisture transport events affecting Greenland is compiled using a conventional AR identification algorithm as well as a self-organizing map (SOM) classification applied to integrated water vapor transport (IVT) data from several atmospheric reanalysis datasets. An analysis of AR effects on GrIS melt and SMB is then performed with GrIS surface melt data from passive microwave satellite observations and the Modèle Atmosphérique Régional (MAR) regional climate model. Results show that meltwater production is above normal during and after AR impact days throughout the GrIS during all seasons, with surface melt enhanced most by strong (> 85th percentile IVT) and extreme (> 95th percentile IVT) ARs. This relationship holds at the seasonal scale, as the total amount of water vapor transported to the GrIS by ARs is significantly greater during above-normal melt seasons. ARs exert a more complex influence on SMB. Normal (< 85th percentile IVT) ARs generally do not have a substantial impact on

  11. Aerosol model development for environmental monitoring in the coastal atmosphere surface layer

    Science.gov (United States)

    Kaloshin, Gennady A.; Matvienko, Gennady G.

    2007-06-01

    Extinction of radiation in the marine boundary layer is dominated by scattering and absorption due to atmospheric aerosol. It is known, that the extinction of optical radiation visible and near IR spectra in the marine surface layer is determined mainly by scattering and absorption atmospheric aerosol. It influences on a dependence of spectral transmission and extinction both natural, and artificial light that is of interest for a wide range of problems, in particular for radiating problems at studying laws of climate formation, and for lines of the applications connected to the forecast of a signal power in coastal conditions at an estimation of EO systems characteristics. This is important to optical retrievals from satellite, remote sensing at environmental monitoring, backscatter of light to space (including climate forcing), cloud properties etc. In unpolluted regions the greatest effects on near shore scattering extinction will be a result of sea-salt from breaking waves and variations in relative humidity. The role of breaking waves appears to be modulated by wind, tide, swell, wave spectra and coastal conditions. These influences will be superimposed upon aerosol generated by open ocean sea-salt aerosol that varies with wind speed. The focus of our study is the extinction and optical effects due to aerosol in a specific coastal region. This involves linking coastal physical properties to oceanic and meteorological parameters in order to develop predictive algorithms that describe 3-D aerosol structure and variability. The aerosol microphysical model of the marine and coastal atmosphere surface layer is considered. The model distinctive feature is parameterization of amplitude and width of the modes as functions of fetch and wind speed. In the paper the dN/dr behavior depending at change meteorological parameters, heights above sea level, fetch, wind speed and RH is show. On the basis of the developed model with usage of Mie theory for spheres the

  12. Chemical characterization of surface snow in Istanbul (NW Turkey) and their association with atmospheric circulations.

    Science.gov (United States)

    Baysal, Asli; Baltaci, Hakki; Ozbek, Nil; Destanoglu, Orhan; Ustabasi, Gul Sirin; Gumus, Gulcin

    2017-06-01

    The understanding of the impurities in natural snow is important in realizing its atmospheric quality, soil characteristics, and the pollution caused to the environment. Knowledge of the occurrence of major ions and trace metals in the snow in the megacity of Istanbul is very limited. This manuscript attempts to understand the origin of major soluble ions (fluoride, acetate, formate, chlorite, chloride, nitrite, chlorate, bromide, nitrate, sulfate, phosphate, and perchlorate) and some trace metals (Fe, Mn, Cd, Co, Ni, Pb, Zn, Cu) in winter surface snow, collected in Istanbul, Turkey. The sampling of the surface snow was conducted after each precipitation during the winter of 2015-2016 at three sites in the city. Besides the statistical evaluation of the major ions, and some trace metal concentrations, the chemical variations along with atmospheric circulations, which are important modification mechanisms that influence the concentrations, were investigated in the study. At examined locations and times, 12 major anions were investigated and in these anions fluoride, chlorite, chlorate, bromide, and perchlorate in the snow samples were below the detection limit; only SO 4 2- , NO 3 - , and CI - were found to be in the range of 1.11-17.90, 0.75-4.52, and 0.19-3.01 mg/L. Also, according to the trace element determination, the concentration was found to be 29.2-53.7, 2.0-16.1, 1.0-2.2, 50.1-71.1, 24.2-35.2, ND-7.9, 43.2-106.6, and 3.0-17.7 μg/L for Fe, Mn, Cd, Co, Ni, Pb, Zn, and Cu, respectively. The major anions and investigated trace elements here originated mainly from anthropogenic and atmospheric circulation and mainly influenced by northerly and southerly circulation patterns. While the main limitations in the present study may be the low number of samples that may not be entirely representative, accurately reflect identification, or support other previously observed local measurements, we believe that the type of data presented in this study has the potential

  13. Planetary Atmosphere and Surfaces Chamber (PASC: A Platform to Address Various Challenges in Astrobiology

    Directory of Open Access Journals (Sweden)

    Eva Mateo-Marti

    2014-08-01

    Full Text Available The study of planetary environments of astrobiological interest has become a major challenge. Because of the obvious technical and economical limitations on in situ planetary exploration, laboratory simulations are one of the most feasible research options to make advances both in planetary science and in developing a consistent description of the origin of life. With this objective in mind, we applied vacuum technology to the design of versatile vacuum chambers devoted to the simulation of planetary atmospheres’ conditions. These vacuum chambers are able to simulate atmospheres and surface temperatures representative of the majority of planetary objects, and they are especially appropriate for studying the physical, chemical and biological changes induced in a particular sample by in situ irradiation or physical parameters in a controlled environment. Vacuum chambers are a promising potential tool in several scientific and technological fields, such as engineering, chemistry, geology and biology. They also offer the possibility of discriminating between the effects of individual physical parameters and selected combinations thereof. The implementation of our vacuum chambers in combination with analytical techniques was specifically developed to make feasible the in situ physico-chemical characterization of samples. Many wide-ranging applications in astrobiology are detailed herein to provide an understanding of the potential and flexibility of these experimental systems. Instruments and engineering technology for space applications could take advantage of our environment-simulation chambers for sensor calibration. Our systems also provide the opportunity to gain a greater understanding of the chemical reactivity of molecules on surfaces under different environments, thereby leading to a greater understanding of interface processes in prebiotic chemical reactions and facilitating studies of UV photostability and photochemistry on surfaces

  14. Atmospheric summer teleconnections and Greenland Ice Sheet surface mass variations: insights from MERRA-2

    International Nuclear Information System (INIS)

    Lim, Young-Kwon; Schubert, Siegfried D; Molod, Andrea M; Cullather, Richard I; Zhao, Bin; Nowicki, Sophie M J; Lee, Jae N; Velicogna, Isabella

    2016-01-01

    The relationship between leading atmospheric teleconnection patterns and Greenland Ice Sheet (GrIS) temperature, precipitation, and surface mass balance (SMB) are investigated for the last 36 summers (1979–2014) based on Modern-Era Retrospective analysis for Research and Applications version 2 reanalyses. The results indicate that the negative phase of both the North Atlantic Oscillation (NAO) and Arctic Oscillation, associated with warm and dry conditions for the GrIS, lead to SMB decreases within 0–1 months. Furthermore, the positive phase of the East Atlantic (EA) pattern often lags the negative NAO, reflecting a dynamical linkage between these modes that acts to further enhance the warm and dry conditions over the GrIS, leading to a favorable environment for enhanced surface mass loss. The development of a strong negative NAO in combination with a strong positive EA in recent years leads to significantly larger GrIS warming compared to when the negative NAO occurs in combination with a negative or weak positive EA (0.69 K versus 0.13 K anomaly). During 2009 and 2011, weakened (as compared to conditions during the severe surface melt cases of 2010 and 2012) local high pressure blocking produced colder northerly flow over the GrIS inhibiting warming despite the occurrence of a strong negative NAO, reflecting an important role for the EA during those years. In particular, the EA acts with the NAO to enhance warming in 2010 and 2012, and weaken high pressure blocking in 2009 and 2011. In general, high pressure blocking primarily impacts the western areas of the GrIS via advective temperature increases, while changes in net surface radiative fluxes account for both western and eastern GrIS temperature changes. (letter)

  15. The impact of non-stationary flows on the surface stress in the weak-wind stable boundary layer

    Science.gov (United States)

    Thomas, Christoph; Mahrt, Larry

    2016-04-01

    The behaviour of turbulent transport in the weak-wind stably stratified boundary layer is examined in terms of the non-stationarity of the wind field based upon field observations. Extensive sonic anemometer measurements from horizontal networks and vertical towers ranging from 12 to 20 m height and innovative fiber-optic distributed temperature sensing observations were collected from three field programs in moderately sloped terrain with a varying degree of surface heterogeneity, namely the Shallow Cold Pool (SCP) and the Flow Over Snow Surfaces (FLOSS) II experiments in Colorado (USA), and the Advanced Canopy Resolution Experiment (ARCFLO) in Oregon (USA). The relationship of the friction velocity to the stratification and small non-stationary submeso motions is studied from several points of view and nominally quantified. The relationship of the turbulence to the stratification is less systematic than expected due to the important submeso-scale motions. Consequently, the roles of the wind speed and stratification are not adequately accommodated by a single non-dimensional combination, such as the bulk Richardson number. However, cause and effect relationships are difficult to isolate because the non-stationary momentum flux significantly modifies the profile of the non-stationary mean flow. The link between the turbulence and accelerations at the surface is examined in terms of the changing vertical structure of the wind profile and sudden increases of downward transport of momentum. The latter may be significant in explaining the small-scale weak turbulence during stable stratification and deviations from conventional flux-profile relationships. Contrary to expectations, the vertical coherence was strongest for weakest winds and declined fast with increasing velocities, which suggests that submeso-scale motions are much deeper than previously thought.

  16. Marinobacter sp. from marine sediments produce highly stable surface-active agents for combatting marine oil spills.

    Science.gov (United States)

    Raddadi, Noura; Giacomucci, Lucia; Totaro, Grazia; Fava, Fabio

    2017-11-02

    The application of chemical dispersants as a response to marine oil spills is raising concerns related to their potential toxicity also towards microbes involved in oil biodegradation. Hence, oil spills occurring under marine environments necessitate the application of biodispersants that are highly active, stable and effective under marine environment context. Biosurfactants from marine bacteria could be good candidates for the development of biodispersant formulations effective in marine environment. This study aimed at establishing a collection of marine bacteria able to produce surface-active compounds and evaluating the activity and stability of the produced compounds under conditions mimicking those found under marine environment context. A total of 43 different isolates were obtained from harbor sediments. Twenty-six of them produced mainly bioemulsifiers when glucose was used as carbon source and 16 were biosurfactant/bioemulsifiers producers after growth in the presence of soybean oil. Sequencing of 16S rRNA gene classified most isolates into the genus Marinobacter. The produced emulsions were shown to be stable up to 30 months monitoring period, in the presence of 300 g/l NaCl, at 4 °C and after high temperature treatment (120 °C for 20 min). The partially purified compounds obtained after growth on soybean oil-based media exhibited low toxicity towards V. fischeri and high capability to disperse crude oil on synthetic marine water. To the best of our knowledge, stability characterization of bioemulsifiers/biosurfactants from the non-pathogenic marine bacterium Marinobacter has not been previously reported. The produced compounds were shown to have potential for different applications including the environmental sector. Indeed, their high stability in the presence of high salt concentration and low temperature, conditions characterizing the marine environment, the capability to disperse crude oil and the low ecotoxicity makes them interesting for

  17. Stable isotope ratios of the atmospheric CH{sub 4}, CO{sub 2} and N{sub 2}O in Tokai-mura

    Energy Technology Data Exchange (ETDEWEB)

    Porntepkasemsan, Boonsom; Andoh, Mariko A.; Amano, Hikaru [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2000-11-01

    This report presents the results and interpretation of stable isotope ratios of the atmospheric CH{sub 4}, CO{sub 2} and N{sub 2}O from a variety of sources in Tokai-mura. The seasonal changes of {delta}{sup 13}CH{sub 4}, {delta}{sup 13}CO{sub 2} and {delta}{sup 15}N{sub 2}O were determined under in-situ conditions in four sampling sites and one control site. Such measurements are expected to provide a useful means of estimating the transport mechanisms of the three trace gases in the environment. These isotopic signatures were analyzed by Isotope Ratio Mass Spectrometer (IRMS, Micromass Isoprime). Our data showed the significant seasonal fluctuation in the Hosoura rice paddy during the entire growing season in 1999. Possible causes for the variation are postulated. Additional measurements on soil properties and on organic {delta}{sup 13}C in rice plant are suggested. Cited outstanding original papers are summarized in the references. (author)

  18. WIND SPEED AND ATMOSPHERIC STABILITY TRENDS FOR SELECTED UNITED STATES SURFACE STATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Buckley, R; Allen H. Weber, A

    2006-11-01

    Recently it has been suggested that global warming and a decrease in mean wind speeds over most land masses are related. Decreases in near surface wind speeds have been reported by previous investigators looking at records with time spans of 15 to 30 years. This study focuses on United States (US) surface stations that have little or no location change since the late 1940s or the 1950s--a time range of up to 58 years. Data were selected from 62 stations (24 of which had not changed location) and separated into ten groups for analysis. The group's annual averages of temperature, wind speed, and percentage of Pasquill-Gifford (PG) stability categories were fitted with linear least squares regression lines. The results showed that the temperatures have increased for eight of the ten groups as expected. Wind speeds have decreased for nine of the ten groups. The mean slope of the wind speed trend lines for stations within the coterminous US was -0.77 m s{sup -1} per century. The percentage frequency of occurrence for the neutral (D) PG stability category decreased, while that for the unstable (B) and the stable (F) categories increased in almost all cases except for the group of stations located in Alaska.

  19. Observations of atmospheric methane and its stable isotope ratio (δ13C) over the East Arctic seas from the ship cruises in the autumn of 2016

    Science.gov (United States)

    Pankratova, Natalia; Skorokhod, Andrey; Belikov, Igor; Semiletov, Igor; Berezina, Elena

    2017-04-01

    Methane (CH4) is the third most important greenhouse gas after water vapor and carbon dioxide (CO2) which has an integral radiative effect on the contemporary terrestrial climatic system. The methane radiative effect is 20 times as strong as carbon dioxide per unit mole. Taking into account the characteristic life time of the greenhouse gases molecules in the atmosphere, the methane global warming potential at the 100-year time interval is 20 times higher than the CO2 potential. Atmospheric CH4 mixing ratio and the changes in the methane 13C:12C ratio (reported the changes relative to a reference ratio and denoted as δ13C-CH4 and reported , in units of per mil) were measured from aboard the research vessel Akademik M.A. Lavrentiev from September to November 2016 in the Laptev, East Siberian and Chukchi Seas and as well as the North Pacific and the Sea of Japan. The measurements were made performed using a Cavity-Ring-Down Spectrometer (CRDS) from Picarro™ (model G2132-i). Together with methane concentrations of other trace gases (CO2, NO, NO2, O3) were measured. Air was sampled from an inlet at the front of the deck at 11 meters above sea level. A significant increase in methane concentration over the shelf areas of the Arctic seas and in the deltas of the large Siberian rivers is revealed in the expeditions. The measurements have confirmed the possibility of the formation of extreme methane concentrations (above 3 ppm) in the air over the areas of methane seeps of the Eastern shelf of the Arctic Ocean. The present study allowed to identify the sources of atmospheric methane in the Arctic. The measurements were compared with the surface methane data from the NOAA/ESRL arctic sites and the Tiksi station located on the shore of the Laptev Sea.

  20. Effects of core strength training using stable versus unstable surfaces on physical fitness in adolescents: a randomized controlled trial.

    Science.gov (United States)

    Granacher, Urs; Schellbach, Jörg; Klein, Katja; Prieske, Olaf; Baeyens, Jean-Pierre; Muehlbauer, Thomas

    2014-01-01

    It has been demonstrated that core strength training is an effective means to enhance trunk muscle strength (TMS) and proxies of physical fitness in youth. Of note, cross-sectional studies revealed that the inclusion of unstable elements in core strengthening exercises produced increases in trunk muscle activity and thus provide potential extra training stimuli for performance enhancement. Thus, utilizing unstable surfaces during core strength training may even produce larger performance gains. However, the effects of core strength training using unstable surfaces are unresolved in youth. This randomized controlled study specifically investigated the effects of core strength training performed on stable surfaces (CSTS) compared to unstable surfaces (CSTU) on physical fitness in school-aged children. Twenty-seven (14 girls, 13 boys) healthy subjects (mean age: 14 ± 1 years, age range: 13-15 years) were randomly assigned to a CSTS (n = 13) or a CSTU (n = 14) group. Both training programs lasted 6 weeks (2 sessions/week) and included frontal, dorsal, and lateral core exercises. During CSTU, these exercises were conducted on unstable surfaces (e.g., TOGU© DYNAIR CUSSIONS, THERA-BAND© STABILITY TRAINER). Significant main effects of Time (pre vs. post) were observed for the TMS tests (8-22%, f = 0.47-0.76), the jumping sideways test (4-5%, f = 1.07), and the Y balance test (2-3%, f = 0.46-0.49). Trends towards significance were found for the standing long jump test (1-3%, f = 0.39) and the stand-and-reach test (0-2%, f = 0.39). We could not detect any significant main effects of Group. Significant Time x Group interactions were detected for the stand-and-reach test in favour of the CSTU group (2%, f = 0.54). Core strength training resulted in significant increases in proxies of physical fitness in adolescents. However, CSTU as compared to CSTS had only limited additional effects (i.e., stand-and-reach test). Consequently, if the

  1. Surface Decontamination of Chemical Agent Surrogates Using an Atmospheric Pressure Air Flow Plasma Jet

    Science.gov (United States)

    Li, Zhanguo; Li, Ying; Cao, Peng; Zhao, Hongjie

    2013-07-01

    An atmospheric pressure dielectric barrier discharge (DBD) plasma jet generator using air flow as the feedstock gas was applied to decontaminate the chemical agent surrogates on the surface of aluminum, stainless steel or iron plate painted with alkyd or PVC. The experimental results of material decontamination show that the residual chemical agent on the material is lower than the permissible value of the National Military Standard of China. In order to test the corrosion effect of the plasma jet on different material surfaces in the decontamination process, corrosion tests for the materials of polymethyl methacrylate, neoprene, polyvinyl chloride (PVC), polyethylene (PE), phenolic resin, iron plate painted with alkyd, stainless steel, aluminum, etc. were carried out, and relevant parameters were examined, including etiolation index, chromatism, loss of gloss, corrosion form, etc. The results show that the plasma jet is slightly corrosive for part of the materials, but their performances are not affected. A portable calculator, computer display, mainboard, circuit board of radiogram, and a hygrometer could work normally after being treated by the plasma jet.

  2. Surface Decontamination of Chemical Agent Surrogates Using an Atmospheric Pressure Air Flow Plasma Jet

    International Nuclear Information System (INIS)

    Li Zhanguo; Li Ying; Cao Peng; Zhao Hongjie

    2013-01-01

    An atmospheric pressure dielectric barrier discharge (DBD) plasma jet generator using air flow as the feedstock gas was applied to decontaminate the chemical agent surrogates on the surface of aluminum, stainless steel or iron plate painted with alkyd or PVC. The experimental results of material decontamination show that the residual chemical agent on the material is lower than the permissible value of the National Military Standard of China. In order to test the corrosion effect of the plasma jet on different material surfaces in the decontamination process, corrosion tests for the materials of polymethyl methacrylate, neoprene, polyvinyl chloride (PVC), polyethylene (PE), phenolic resin, iron plate painted with alkyd, stainless steel, aluminum, etc. were carried out, and relevant parameters were examined, including etiolation index, chromatism, loss of gloss, corrosion form, etc. The results show that the plasma jet is slightly corrosive for part of the materials, but their performances are not affected. A portable calculator, computer display, mainboard, circuit board of radiogram, and a hygrometer could work normally after being treated by the plasma jet

  3. Cell treatment and surface functionalization using a miniature atmospheric pressure glow discharge plasma torch

    International Nuclear Information System (INIS)

    Yonson, S; Coulombe, S; Leveille, V; Leask, R L

    2006-01-01

    A miniature atmospheric pressure glow discharge plasma torch was used to detach cells from a polystyrene Petri dish. The detached cells were successfully transplanted to a second dish and a proliferation assay showed the transplanted cells continued to grow. Propidium iodide diffused into the cells, suggesting that the cell membrane had been permeabilized, yet the cells remained viable 24 h after treatment. In separate experiments, hydrophobic, bacteriological grade polystyrene Petri dishes were functionalized. The plasma treatment reduced the contact angle from 93 0 to 35 0 , and promoted cell adhesion. Two different torch nozzles, 500 μm and 150 μm in internal diameter, were used in the surface functionalization experiments. The width of the tracks functionalized by the torch, as visualized by cell adhesion, was approximately twice the inside diameter of the nozzle. These results indicate that the miniature plasma torch could be used in biological micropatterning, as it does not use chemicals like the present photolithographic techniques. Due to its small size and manouvrability, the torch also has the ability to pattern complex 3D surfaces

  4. Gamma-ray and neutron spectroscopy of planetary surfaces and atmospheres

    International Nuclear Information System (INIS)

    Reedy, R.C.

    1987-01-01

    The neutrons and gamma rays escaping from a planet can be used to map the concentrations of various elements in its surface. In a planet, the high-energy particles in the galactic cosmic rays induce a cascade of particles that includes many neutrons. The γ rays are made by the decay of the naturally-occurring radioelements and by nuclear excitations induced by cosmic-ray particles and their secondaries (especially neutron capture or inelastic scattering reactions). After a short history of planetary γ-ray and neutron spectroscopy, the γ-ray spectrometer and active neutron detection system planned for the Mars Observer Mission are presented. The results of laboratory experiments that simulate the cosmic-ray bombardments of planetary surfaces and the status of the theoretical calculations for the processes that make and transport neutrons and γ rays will be reviewed. Studies of Mars, including its atmosphere, are emphasized, as are new ideas, concepts, and problems that have arisen over the last decade, such as Doppler broadening and peaks from neutron scattering with germanium nuclei in a γ-ray spectrometer. 23 refs., 1 fig

  5. Quantitative measurements of ground state atomic oxygen in atmospheric pressure surface micro-discharge array

    Science.gov (United States)

    Li, D.; Kong, M. G.; Britun, N.; Snyders, R.; Leys, C.; Nikiforov, A.

    2017-06-01

    The generation of atomic oxygen in an array of surface micro-discharge, working in atmospheric pressure He/O2 or Ar/O2 mixtures, is investigated. The absolute atomic oxygen density and its temporal and spatial dynamics are studied by means of two-photon absorption laser-induced fluorescence. A high density of atomic oxygen is detected in the He/O2 mixture with up to 10% O2 content in the feed gas, whereas the atomic oxygen concentration in the Ar/O2 mixture stays below the detection limit of 1013 cm-3. The measured O density near the electrode under the optimal conditions in He/1.75% O2 gas is 4.26  ×  1015 cm-3. The existence of the ground state O (2p 4 3 P) species has been proven in the discharge at a distance up to 12 mm away from the electrodes. Dissociative reactions of the singlet O2 with O3 and deep vacuum ultraviolet radiation, including the radiation of excimer \\text{He}2\\ast , are proposed to be responsible for O (2p 4 3 P) production in the far afterglow. A capability of the surface micro-discharge array delivering atomic oxygen to long distances over a large area is considered very interesting for various biomedical applications.

  6. Full Coupling Between the Atmosphere, Surface, and Subsurface for Integrated Hydrologic Simulation

    Science.gov (United States)

    Davison, Jason Hamilton; Hwang, Hyoun-Tae; Sudicky, Edward A.; Mallia, Derek V.; Lin, John C.

    2018-01-01

    An ever increasing community of earth system modelers is incorporating new physical processes into numerical models. This trend is facilitated by advancements in computational resources, improvements in simulation skill, and the desire to build numerical simulators that represent the water cycle with greater fidelity. In this quest to develop a state-of-the-art water cycle model, we coupled HydroGeoSphere (HGS), a 3-D control-volume finite element surface and variably saturated subsurface flow model that includes evapotranspiration processes, to the Weather Research and Forecasting (WRF) Model, a 3-D finite difference nonhydrostatic mesoscale atmospheric model. The two-way coupled model, referred to as HGS-WRF, exchanges the actual evapotranspiration fluxes and soil saturations calculated by HGS to WRF; conversely, the potential evapotranspiration and precipitation fluxes from WRF are passed to HGS. The flexible HGS-WRF coupling method allows for unique meshes used by each model, while maintaining mass and energy conservation between the domains. Furthermore, the HGS-WRF coupling implements a subtime stepping algorithm to minimize computational expense. As a demonstration of HGS-WRF's capabilities, we applied it to the California Basin and found a strong connection between the depth to the groundwater table and the latent heat fluxes across the land surface.

  7. Elimination of diazinon insecticide from cucumber surface by atmospheric pressure air-dielectric barrier discharge plasma.

    Science.gov (United States)

    Dorraki, Naghme; Mahdavi, Vahideh; Ghomi, Hamid; Ghasempour, Alireza

    2016-12-06

    The food industry is in a constant search for new technologies to improve the commercial sterilization process of agricultural commodities. Plasma treatment may offer a novel and efficient method for pesticide removal from agricultural product surfaces. To study the proposed technique of plasma food treatment, the degradation behavior of diazinon insecticide by air-dielectric barrier discharge (DBD) plasma was investigated. The authors studied the effect of different plasma powers and treatment times on pesticide concentration in liquid form and coated on the surface of cucumbers, where the diazinon residue was analyzed with mass spectroscopy gas chromatography. Our results suggest that atmospheric pressure air-DBD plasma is potentially effective for the degradation of diazinon insecticide, and mainly depends on related operating parameters, including plasma treatment time, discharge power, and pesticide concentrations. Based on the interaction between reactive oxygen species and electrons in the plasma with the diazinon molecule, two degradation pathway of diazinon during plasma treatment are proposed. It was also found that produced organophosphate pesticides are harmless and less hazardous compounds than diazinon.

  8. A modified surface-resistance approach for representing bare-soil evaporation: wind tunnel experiments under various atmospheric conditions

    International Nuclear Information System (INIS)

    Yamanaka, T.; Takeda, A.; Sugita, F.

    1997-01-01

    A physically based (i.e., nonempirical) representation of surface-moisture availability is proposed, and its applicability is investigated. This method is based on the surface-resistance approaches, and it uses the depth of evaporating surface rather than the water content of the surface soil as the determining factor of surface-moisture availability. A simple energy-balance model including this representation is developed and tested against wind tunnel experiments under various atmospheric conditions. This model can estimate not only the latent heat flux but also the depth of the evaporating surface simultaneously by solving the inverse problem of energy balance at both the soil surface and the evaporating surface. It was found that the depth of the evaporating surface and the latent heat flux estimated by the model agreed well with those observed. The agreements were commonly found out under different atmospheric conditions. The only limitation of this representation is that it is not valid under conditions of drastic change in the radiation input, owing to the influence of transient phase transition of water in the dry surface layer. The main advantage of the approach proposed is that it can determine the surface moisture availability on the basis of the basic properties of soils instead of empirical fitting, although further investigations on its practical use are needed

  9. Comparison of hamstring and quadriceps femoris electromyographic activity between men and women during a single-limb squat on both a stable and labile surface.

    Science.gov (United States)

    Youdas, James W; Hollman, John H; Hitchcock, James R; Hoyme, Gregory J; Johnsen, Jeremiah J

    2007-02-01

    The purpose of this study was to determine if women are quadriceps dominant and men are hamstring dominant during the performance of a partial single-leg squat (SLS) on both a stable and labile ground surface against body weight resistance. Thirty healthy participants (15 men and 15 women) performed an SLS on both a stable surface and a 6.4-cm-thick vinyl pad. Surface electromyographic (EMG) recordings were obtained from the quadriceps femoris and hamstring muscles during the extension phase of the SLS. Statistical analysis revealed that women produced 14% more EMG activity (p = 0.04) in their quadriceps than the men during the SLS on a stable surface, whereas the men generated 18% more EMG activity (p = 0.04) in their hamstrings than the women during the SLS on a labile surface. Additionally, we found a statistically significant sex effect (p = 0.048) for the hamstring/quadriceps (H/Q) EMG ratio, which was 2.25 and 0.62, respectively, for men and women on the stable surface and 2.52 and 0.71, respectively, on the labile surface. We concluded that women are quadriceps dominant and men are hamstring dominant during the performance of SLS against body weight resistance on either a stable or labile surface condition. During an SLS, men showed an H/Q ratio approximately 3.5 times larger than their female counterparts, suggesting that men activate their hamstrings more effectively than women during an SLS. According to our data, the SLS may not be an ideal exercise for activating the hamstring muscles in women without additional neuromuscular training techniques, because women are quadriceps dominant during the SLS.

  10. XPS study on the surface reaction of uranium metal in H2 and H2-CO atmospheres

    International Nuclear Information System (INIS)

    Wang Xiaolin; Fu Yibei; Xie Renshou

    1996-04-01

    The surface reactions of uranium metal in H 2 and H 2 -CO atmospheres and the effects of temperature and CO on the hydriding reaction have been studied by X-ray photoelectron spectroscopy (XPS). The reaction between commercial H 2 and uranium metal at 25 degree C leads mainly to the further oxidation of surface layer of metal due to traces of water vapour. At 200 degree C, it may lead to the hydriding reaction of uranium and the hydriding increases with increasing the exposure of H 2 . Investigation indicates CO inhibits both the hydriding reaction and oxidation on the condition of H 2 -CO atmospheres. (13 refs., 10 figs.)

  11. Cold atmospheric plasma (CAP) surface nanomodified 3D printed polylactic acid (PLA) scaffolds for bone regeneration.

    Science.gov (United States)

    Wang, Mian; Favi, Pelagie; Cheng, Xiaoqian; Golshan, Negar H; Ziemer, Katherine S; Keidar, Michael; Webster, Thomas J

    2016-12-01

    Three-dimensional (3D) printing is a new fabrication method for tissue engineering which can precisely control scaffold architecture at the micron-scale. However, scaffolds not only need 3D biocompatible structures that mimic the micron structure of natural tissues, they also require mimicking of the nano-scale extracellular matrix properties of the tissue they intend to replace. In order to achieve this, the objective of the present in vitro study was to use cold atmospheric plasma (CAP) as a quick and inexpensive way to modify the nano-scale roughness and chemical composition of a 3D printed scaffold surface. Water contact angles of a normal 3D printed poly-lactic-acid (PLA) scaffold dramatically dropped after CAP treatment from 70±2° to 24±2°. In addition, the nano-scale surface roughness (Rq) of the untreated 3D PLA scaffolds drastically increased (up to 250%) after 1, 3, and 5min of CAP treatment from 1.20nm to 10.50nm, 22.90nm, and 27.60nm, respectively. X-ray photoelectron spectroscopy (XPS) analysis showed that the ratio of oxygen to carbon significantly increased after CAP treatment, which indicated that the CAP treatment of PLA not only changed nano-scale roughness but also chemistry. Both changes in hydrophilicity and nano-scale roughness demonstrated a very efficient plasma treatment, which in turn significantly promoted both osteoblast (bone forming cells) and mesenchymal stem cell attachment and proliferation. These promising results suggest that CAP surface modification may have potential applications for enhancing 3D printed PLA bone tissue engineering materials (and all 3D printed materials) in a quick and an inexpensive manner and, thus, should be further studied. Three-dimensional (3D) printing is a new fabrication method for tissue engineering which can precisely control scaffold architecture at the micron-scale. Although their success is related to their ability to exactly mimic the structure of natural tissues and control mechanical

  12. Updating representation of land surface-atmosphere feedbacks in airborne campaign modeling analysis

    Science.gov (United States)

    Huang, M.; Carmichael, G. R.; Crawford, J. H.; Chan, S.; Xu, X.; Fisher, J. A.

    2017-12-01

    An updated modeling system to support airborne field campaigns is being built at NASA Ames Pleiades, with focus on adjusting the representation of land surface-atmosphere feedbacks. The main updates, referring to previous experiences with ARCTAS-CARB and CalNex in the western US to study air pollution inflows, include: 1) migrating the WRF (Weather Research and Forecasting) coupled land surface model from Noah to improved/more complex models especially Noah-MP and Rapid Update Cycle; 2) enabling the WRF land initialization with suitably spun-up land model output; 3) incorporating satellite land cover, vegetation dynamics, and soil moisture data (i.e., assimilating Soil Moisture Active Passive data using the ensemble Kalman filter approach) into WRF. Examples are given of comparing the model fields with available aircraft observations during spring-summer 2016 field campaigns taken place at the eastern side of continents (KORUS-AQ in South Korea and ACT-America in the eastern US), the air pollution export regions. Under fair weather and stormy conditions, air pollution vertical distributions and column amounts, as well as the impact from land surface, are compared. These help identify challenges and opportunities for LEO/GEO satellite remote sensing and modeling of air quality in the northern hemisphere. Finally, we briefly show applications of this system on simulating Australian conditions, which would explore the needs for further development of the observing system in the southern hemisphere and inform the Clean Air and Urban Landscapes (https://www.nespurban.edu.au) modelers.

  13. Dry deposition of submicron atmospheric aerosol over water surfaces in motion

    International Nuclear Information System (INIS)

    Calec, Nevenick

    2013-01-01

    Whether by chronic or accidental releases, the impact of a nuclear installation on the environment mainly depends on atmospheric transfers; and as the accidents at Chernobyl and Fukushima show, affect the contamination of surfaces and impacts in the medium and long-term on the environment and the population. In this context, this work focuses on the characterization and modeling of dry deposition of submicron aerosols on liquid surfaces in motion such as rivers. Unlike wet deposition which is conditioned by washout and rainout (rain and clouds), dry deposition is a phenomenon that depends entirely on the characteristics of aerosols, receiving surfaces, and air flow. In practice, the evaluation of dry deposition is based on the estimation of flux modeling as the product of particle concentration and deposition velocity which can vary over several orders of magnitude depending on the receiving surfaces (forest, snow, urban, grassland..). This topic is motivated by the virtual non-existence of studies on the mechanisms of dry deposition on continental water systems such as rivers; and respect for submicron aerosols. They have the lowest deposition efficiencies and filtration and the longer residence time in the atmosphere. In addition, they are potentially the most dangerous to living beings because they can penetrate deeper into the airway. Due to the lack of data on the dry deposition of submicron aerosols on a liquid surface in motion, the approach was based on two axes: 1) the acquisition of experimental deposition velocities and 2) the analysis and interpretation of results through modeling. The experiments were performed with uranine aerosols released into the IOA wind tunnel (Interface Ocean Atmosphere) of the Institute for Research on Non Equilibrium Phenomena which is configured to study the coupling between the air flow and water. These experiments have given many dry deposition velocities for different configurations characterized according to wind

  14. Dry deposition of submicron atmospheric aerosol over water surfaces in motion

    International Nuclear Information System (INIS)

    Nevenick, Calec

    2013-01-01

    Whether by chronic or accidental releases, the impact of a nuclear installation on the environment mainly depends on atmospheric transfers; and as the accidents at Chernobyl and Fukushima show, affect the contamination of surfaces and impacts in the medium and long-term on the environment and the population. In this context, this work focuses on the characterization and modeling of dry deposition of submicron aerosols on liquid surfaces in motion such as rivers. Unlike wet deposition which is conditioned by washout and rainout (rain and clouds), dry deposition is a phenomenon that depends entirely on the characteristics of aerosols, receiving surfaces, and air flow. In practice, the evaluation of dry deposition is based on the estimation of flux modeling as the product of particle concentration and deposition velocity which can vary over several orders of magnitude depending on the receiving surfaces (forest, snow, urban, grassland...). This topic is motivated by the virtual non-existence of studies on the mechanisms of dry deposition on continental water systems such as rivers; and respect for submicron aerosols. They have the lowest deposition efficiencies and filtration and the longer residence time in the atmosphere. In addition, they are potentially the most dangerous to living beings because they can penetrate deeper into the airway. Due to the lack of data on the dry deposition of submicron aerosols on a liquid surface in motion, the approach was based on two axes: 1) the acquisition of experimental deposition velocities and 2) the analysis and interpretation of results through modeling. The experiments were performed with uranine aerosols released into the IOA wind tunnel (Interface Ocean Atmosphere) of the Institute for Research on Non Equilibrium Phenomena which is configured to study the coupling between the air flow and water. These experiments have given many dry deposition velocities for different configurations characterized according to wind

  15. Effect of Built-Up Edge Formation during Stable State of Wear in AISI 304 Stainless Steel on Machining Performance and Surface Integrity of the Machined Part.

    Science.gov (United States)

    Ahmed, Yassmin Seid; Fox-Rabinovich, German; Paiva, Jose Mario; Wagg, Terry; Veldhuis, Stephen Clarence

    2017-10-25

    During machining of stainless steels at low cutting -speeds, workpiece material tends to adhere to the cutting tool at the tool-chip interface, forming built-up edge (BUE). BUE has a great importance in machining processes; it can significantly modify the phenomenon in the cutting zone, directly affecting the workpiece surface integrity, cutting tool forces, and chip formation. The American Iron and Steel Institute (AISI) 304 stainless steel has a high tendency to form an unstable BUE, leading to deterioration of the surface quality. Therefore, it is necessary to understand the nature of the surface integrity induced during machining operations. Although many reports have been published on the effect of tool wear during machining of AISI 304 stainless steel on surface integrity, studies on the influence of the BUE phenomenon in the stable state of wear have not been investigated so far. The main goal of the present work is to investigate the close link between the BUE formation, surface integrity and cutting forces in the stable sate of wear for uncoated cutting tool during the cutting tests of AISI 304 stainless steel. The cutting parameters were chosen to induce BUE formation during machining. X-ray diffraction (XRD) method was used for measuring superficial residual stresses of the machined surface through the stable state of wear in the cutting and feed directions. In addition, surface roughness of the machined surface was investigated using the Alicona microscope and Scanning Electron Microscopy (SEM) was used to reveal the surface distortions created during the cutting process, combined with chip undersurface analyses. The investigated BUE formation during the stable state of wear showed that the BUE can cause a significant improvement in the surface integrity and cutting forces. Moreover, it can be used to compensate for tool wear through changing the tool geometry, leading to the protection of the cutting tool from wear.

  16. Effect of Built-Up Edge Formation during Stable State of Wear in AISI 304 Stainless Steel on Machining Performance and Surface Integrity of the Machined Part

    Science.gov (United States)

    Fox-Rabinovich, German; Wagg, Terry

    2017-01-01

    During machining of stainless steels at low cutting -speeds, workpiece material tends to adhere to the cutting tool at the tool–chip interface, forming built-up edge (BUE). BUE has a great importance in machining processes; it can significantly modify the phenomenon in the cutting zone, directly affecting the workpiece surface integrity, cutting tool forces, and chip formation. The American Iron and Steel Institute (AISI) 304 stainless steel has a high tendency to form an unstable BUE, leading to deterioration of the surface quality. Therefore, it is necessary to understand the nature of the surface integrity induced during machining operations. Although many reports have been published on the effect of tool wear during machining of AISI 304 stainless steel on surface integrity, studies on the influence of the BUE phenomenon in the stable state of wear have not been investigated so far. The main goal of the present work is to investigate the close link between the BUE formation, surface integrity and cutting forces in the stable sate of wear for uncoated cutting tool during the cutting tests of AISI 304 stainless steel. The cutting parameters were chosen to induce BUE formation during machining. X-ray diffraction (XRD) method was used for measuring superficial residual stresses of the machined surface through the stable state of wear in the cutting and feed directions. In addition, surface roughness of the machined surface was investigated using the Alicona microscope and Scanning Electron Microscopy (SEM) was used to reveal the surface distortions created during the cutting process, combined with chip undersurface analyses. The investigated BUE formation during the stable state of wear showed that the BUE can cause a significant improvement in the surface integrity and cutting forces. Moreover, it can be used to compensate for tool wear through changing the tool geometry, leading to the protection of the cutting tool from wear. PMID:29068405

  17. Effect of Built-Up Edge Formation during Stable State of Wear in AISI 304 Stainless Steel on Machining Performance and Surface Integrity of the Machined Part

    Directory of Open Access Journals (Sweden)

    Yassmin Seid Ahmed

    2017-10-01

    Full Text Available During machining of stainless steels at low cutting -speeds, workpiece material tends to adhere to the cutting tool at the tool–chip interface, forming built-up edge (BUE. BUE has a great importance in machining processes; it can significantly modify the phenomenon in the cutting zone, directly affecting the workpiece surface integrity, cutting tool forces, and chip formation. The American Iron and Steel Institute (AISI 304 stainless steel has a high tendency to form an unstable BUE, leading to deterioration of the surface quality. Therefore, it is necessary to understand the nature of the surface integrity induced during machining operations. Although many reports have been published on the effect of tool wear during machining of AISI 304 stainless steel on surface integrity, studies on the influence of the BUE phenomenon in the stable state of wear have not been investigated so far. The main goal of the present work is to investigate the close link between the BUE formation, surface integrity and cutting forces in the stable sate of wear for uncoated cutting tool during the cutting tests of AISI 304 stainless steel. The cutting parameters were chosen to induce BUE formation during machining. X-ray diffraction (XRD method was used for measuring superficial residual stresses of the machined surface through the stable state of wear in the cutting and feed directions. In addition, surface roughness of the machined surface was investigated using the Alicona microscope and Scanning Electron Microscopy (SEM was used to reveal the surface distortions created during the cutting process, combined with chip undersurface analyses. The investigated BUE formation during the stable state of wear showed that the BUE can cause a significant improvement in the surface integrity and cutting forces. Moreover, it can be used to compensate for tool wear through changing the tool geometry, leading to the protection of the cutting tool from wear.

  18. The O and H stable isotope composition of freshwaters in the British Isles. 2. Surface waters and groundwater

    Directory of Open Access Journals (Sweden)

    W. G. Darling

    2003-01-01

    Full Text Available The utility of stable isotopes as tracers of the water molecule has a long pedigree. The study reported here is part of an attempt to establish a comprehensive isotopic 'baseline' for the British Isles as background data for a range of applications. Part 1 of this study (Darling and Talbot, 2003 considered the isotopic composition of rainfall in Britain and Ireland. The present paper is concerned with the composition of surface waters and groundwater. In isotopic terms, surface waters (other than some upland streams are poorly characterised in the British Isles; their potential variability has yet to be widely used as an aid in hydrological research. In what may be the first study of a major British river, a monthly isotopic record of the upper River Thames during 1998 was obtained. This shows high damping of the isotopic variation compared to that in rainfall over most of the year, though significant fluctuations were seen for the autumn months. Smaller rivers such as the Stour and Darent show a more subdued response to the balance between runoff and baseflow. The relationship between the isotopic composition of rainfall and groundwater is also considered. From a limited database, it appears that whereas Chalk groundwater is a representative mixture of weighted average annual rainfall, for Triassic sandstone groundwater there is a seasonal selection of rainfall biased towards isotopically-depleted winter recharge. This may be primarily the result of physical differences between the infiltration characteristics of rock types, though other factors (vegetation, glacial history could be involved. In the main, however, groundwaters appear to be representative of bulk rainfall within an error band of 0.5‰ δ18O. Contour maps of the δ18O and δ2H content of recent groundwaters in the British Isles show a fundamental SW-NE depletion effect modified by topography. The range of measured values, while much smaller than those for rainfall, still covers

  19. Land Surface Temperature and Emissivity Separation from Cross-Track Infrared Sounder Data with Atmospheric Reanalysis Data and ISSTES Algorithm

    Directory of Open Access Journals (Sweden)

    Yu-Ze Zhang

    2017-01-01

    Full Text Available The Cross-track Infrared Sounder (CrIS is one of the most advanced hyperspectral instruments and has been used for various atmospheric applications such as atmospheric retrievals and weather forecast modeling. However, because of the specific design purpose of CrIS, little attention has been paid to retrieving land surface parameters from CrIS data. To take full advantage of the rich spectral information in CrIS data to improve the land surface retrievals, particularly the acquisition of a continuous Land Surface Emissivity (LSE spectrum, this paper attempts to simultaneously retrieve a continuous LSE spectrum and the Land Surface Temperature (LST from CrIS data with the atmospheric reanalysis data and the Iterative Spectrally Smooth Temperature and Emissivity Separation (ISSTES algorithm. The results show that the accuracy of the retrieved LSEs and LST is comparable with the current land products. The overall differences of the LST and LSE retrievals are approximately 1.3 K and 1.48%, respectively. However, the LSEs in our study can be provided as a continuum spectrum instead of the single-channel values in traditional products. The retrieved LST and LSEs now can be better used to further analyze the surface properties or improve the retrieval of atmospheric parameters.

  20. Chemically stable Au nanorods as probes for sensitive surface enhanced scattering (SERS) analysis of blue BIC ballpoint pens

    Science.gov (United States)

    Alyami, Abeer; Saviello, Daniela; McAuliffe, Micheal A. P.; Cucciniello, Raffaele; Mirabile, Antonio; Proto, Antonio; Lewis, Liam; Iacopino, Daniela

    2017-08-01

    Au nanorods were used as an alternative to commonly used Ag nanoparticles as Surface Enhanced Raman Scattering (SERS) probes for identification of dye composition of blue BIC ballpoint pens. When used in combination with Thin Layer Chromatography (TLC), Au nanorod colloids allowed identification of the major dye components of the BIC pen ink, otherwise not identifiable by normal Raman spectroscopy. Thanks to their enhanced chemical stability compared to Ag colloids, Au nanorods provided stable and reproducible SERS signals and allowed easy identification of phthalocyanine and triarylene dyes in the pen ink mixture. These findings were supported by FTIR and MALDI analyses, also performed on the pen ink. Furthermore, the self-assembly of Au nanorods into large area ordered superstructures allowed identification of BIC pen traces. SERS spectra of good intensity and high reproducibility were obtained using Au nanorod vertical arrays, due to the high density of hot spots and morphological reproducibility of these superstructures. These results open the way to the employment of SERS for fast screening analysis and for quantitative analysis of pens and faded pens which are relevant for the fields of forensic and art conservation sciences.

  1. Stable phase CdS nanoparticles for optoelectronics: a study on surface morphology, structural and optical characterization

    Directory of Open Access Journals (Sweden)

    Kumar Suresh

    2016-06-01

    Full Text Available This work presents a study on the surface morphology, structure and optical behavior of stable phase cadmium sulphide (CdS nanoparticles synthesized via co-precipitation technique. Scanning electron microscopy (SEM analysis has been employed to study a cluster formation in the aggregated nanoparticles. An image analysis approach using ImageJ has been used to measure the size of nanoparticles from the SEM micrographs. Fourier transform infrared spectroscopic (FT-IR analysis identified absorption peaks of Cd–S stretching along with moisture content. X-ray diffraction (XRD analysis showed that CdS nanoparticles crystallized in wurtzite structure with a preferential orientation along (0 0 2 plane. The particle size, microstrain and lattice constants have been evaluated using XRD data. The lattice parameters of these nanoparticles were found to be shorter than the bulk value which led to lattice contraction. The optical absorption study showed a blue shift in the fundamental absorption edge indicating a quantum size effect.

  2. Aspects on interactions between mid- to high latitude atmospheric circulation and some surface processes

    International Nuclear Information System (INIS)

    Byrkjedal, Oeyvind

    2006-01-01

    The Arctic is a hot topic in Climate Research. A large number of signs of a warming Arctic Climate have been identified the latest years. This is of major concern in light of the increasing atmospheric content of greenhouse gases. The climate research community projects future warming of the climate in the high latitudes as a response to increased amounts of anthropogenic release of greenhouse gases since the pre-industrial era. The overall objectives of this work has been to study the mid- and high latitude climate and climate variability, and to evaluate how well some climate processes that contribute to determine the Arctic climate and variability are represented and simulated in climate models. A new data set of storm tracks trajectories and statistics over the Northern Hemisphere for the period 1948-2002 has been developed. The variability of the cyclones extending to the Nordic Seas is studied in particular, and it is found that both the number of storms and their intensity exhibits a strong decadal and interannual variability. The ocean volume transports into and out of the Nordic Seas shows a relatively close relation to the wintertime cyclone intensity and cyclone count. To have confidence in future projections of climate, it is necessary to evaluate how the model behaves in a climate regime different from modern day. To do this two model simulations of the last glacial maximum (LGM) was performed. The reconstructions of sea surface temperatures in the Nordic Seas in LGM differ from perennial sea ice cover to having open ocean during the summer. The large scale atmospheric circulation patterns of the two different climate reconstructions are studied. It is found that the perennial sea ice cover produces a circulation pattern which may be too zonal to support the existence of the large north Eurasian ice sheets. In the case with seasonally open ocean the air masses carries larger amounts of heat and moisture towards the ice sheets and represents a larger

  3. Study of Near-Surface Models in Large-Eddy Simulations of a Neutrally Stratified Atmospheric Boundary Layer

    Science.gov (United States)

    Senocak, I.; Ackerman, A. S.; Kirkpatrick, M. P.; Stevens, D. E.; Mansour, N. N.

    2004-01-01

    Large-eddy simulation (LES) is a widely used technique in armospheric modeling research. In LES, large, unsteady, three dimensional structures are resolved and small structures that are not resolved on the computational grid are modeled. A filtering operation is applied to distinguish between resolved and unresolved scales. We present two near-surface models that have found use in atmospheric modeling. We also suggest a simpler eddy viscosity model that adopts Prandtl's mixing length model (Prandtl 1925) in the vicinity of the surface and blends with the dynamic Smagotinsky model (Germano et al, 1991) away from the surface. We evaluate the performance of these surface models by simulating a neutraly stratified atmospheric boundary layer.

  4. Exploring the Interactions among Beetle-induced Changes in Catchment-scale Ecohydrology, Land Surface Fluxes and the Lower Atmosphere with a Coupled Hydrology-Atmospheric Model.

    Science.gov (United States)

    Forrester, M. M.; Maxwell, R. M.; Bearup, L. A.; Gochis, D.; Porter, A.

    2015-12-01

    The mountain pine beetle has dramatically altered ecohydrologic processes of lodgepole pine forests in western North America, having caused one of the largest insect-driven tree mortalities in recorded history. Documented and modeled responses to forest mortality include cessation of overstory transpiration, local increases in soil moisture, changes in snow accumulation and ablation, differences in groundwater and runoff contributions to streamflow, changes in sensible and latent heat partitioning, and higher surface temperatures and ground evaporation. However, the scale-sensitivity, spatial variability and interdependence of these responses, and the simultaneous process of forest recovery, mean that watershed response to infestation is often inconsistent and damped at large scales, making it difficult to capture individual hydrologic and energy components of disturbance. This study resolves complicated feedbacks from disturbance at the land surface to responses in the atmosphere with the use of the physically-based, integrated hydrologic model ParFlow, coupled to the Weather Research and Forecasting (WRF) atmospheric model. The model domain, constructed at 1-km resolution, encompasses a 25,200 square kilometer region over a Rocky Mountain headwaters catchment in Colorado. Land use and vegetation parameters within WRF were adjusted in a detailed ensemble approach to reflect beetle-induced reductions in stomatal conductivity and LAI. Results show spatially variable but generally increased soil moisture and water yield with infestation. Subsequent disturbance of the sensible and latent heat balance propagates into the atmosphere, influencing atmospheric moisture, stability and even precipitation. This work presents the applicability of a deterministic, integrated climate-hydrologic model to identify complicated physical interactions occurring with forest disturbance, which may not be discernable with simpler models or observations.

  5. Large eddies modulating flux convergence and divergence in a disturbed unstable atmospheric surface layer

    Science.gov (United States)

    Gao, Zhongming; Liu, Heping; Russell, Eric S.; Huang, Jianping; Foken, Thomas; Oncley, Steven P.

    2016-02-01

    The effects of large eddies on turbulence structures and flux transport were studied using data collected over a flat cotton field during the Energy Balance Experiment 2000 in the San Joaquin Valley of California in August 2000. Flux convergence (FC; larger fluxes at 8.7 m than 2.7 m) and divergence (FD) in latent heat flux (LE) were observed in a disturbed, unstable atmospheric surface layer, and their magnitudes largely departed from the prediction of Monin-Obukhov similarity theory. From our wavelet analysis, it was identified that large eddies affected turbulence structures, scalar distribution, and flux transport differently at 8.7 m and 2.7 m under the FC and FD conditions. Using the ensemble empirical mode decomposition, time series data were decomposed into large eddies and small-scale background turbulence, the time-domain characteristics of large eddies were examined, and the flux contribution by large eddies was also determined quantitatively. The results suggest that large eddies over the frequency range of 0.002 Hz < f < 0.02 Hz (predominantly 300-400 m) enhanced the vertical velocity spectra more significantly at 8.7 m than 2.7 m, leading to an increased magnitude of the cospectra and thus LE at 8.7 m. In the FD case, however, these large eddies were not present and even suppressed in the vertical velocity spectra at 8.7 m. Consequently, the cospectra divergence over the low-frequency ranges primarily caused the LE divergence. This work implies that large eddies may either improve or degrade the surface energy balance closure by increasing or decreasing turbulent fluxes, respectively.

  6. Do organic surface films on sea salt aerosols influence atmospheric chemistry? ─ a model study

    Directory of Open Access Journals (Sweden)

    R. von Glasow

    2007-11-01

    Full Text Available Organic material from the ocean's surface can be incorporated into sea salt aerosol particles often producing a surface film on the aerosol. Such an organic coating can reduce the mass transfer between the gas phase and the aerosol phase influencing sea salt chemistry in the marine atmosphere. To investigate these effects and their importance for the marine boundary layer (MBL we used the one-dimensional numerical model MISTRA. We considered the uncertainties regarding the magnitude of uptake reduction, the concentrations of organic compounds in sea salt aerosols and the oxidation rate of the organics to analyse the possible influence of organic surfactants on gas and liquid phase chemistry with a special focus on halogen chemistry. By assuming destruction rates for the organic coating based on laboratory measurements we get a rapid destruction of the organic monolayer within the first meters of the MBL. Larger organic initial concentrations lead to a longer lifetime of the coating but lead also to an unrealistically strong decrease of O3 concentrations as the organic film is destroyed by reaction with O3. The lifetime of the film is increased by assuming smaller reactive uptake coefficients for O3 or by assuming that a part of the organic surfactants react with OH. With regard to tropospheric chemistry we found that gas phase concentrations for chlorine and bromine species decreased due to the decreased mass transfer between gas phase and aerosol phase. Aqueous phase chlorine concentrations also decreased but aqueous phase bromine concentrations increased. Differences for gas phase concentrations are in general smaller than for liquid phase concentrations. The effect on gas phase NO2 or NO is very small (reduction less than 5% whereas liquid phase NO2 concentrations increased in some cases by nearly 100%. We list suggestions for further laboratory studies which are needed for improved model studies.

  7. Profiling of aerosol concentrations, particle size distributions and relative humidity in the atmospheric surface layer over the North Sea

    NARCIS (Netherlands)

    Leeuw, G. de

    1990-01-01

    Results are presented from measurements in the lower 15 m of the marine atmospheric surface layer. The paper is focussed on the comparison of the profile data obtained with the Rotorod and the optical scatterometer. These instruments are based on different physical principles. Results show that

  8. Observational Characterization of the Downward Atmospheric Longwave Radiation at the Surface in the City of São Paulo

    NARCIS (Netherlands)

    Wilde Barbaro, E.; Oliveira, A.P.; Soares, J.; Codato, G.; Ferreira, M.J.; Mlakar, P.; Boznar, M.Z.; Escobedo, J.

    2010-01-01

    This work describes the seasonal and diurnal variations of downward longwave atmospheric irradiance (LW) at the surface in São Paulo, Brazil, using 5-min-averaged values of LW, air temperature, relative humidity, and solar radiation observed continuously and simultaneously from 1997 to 2006 on a

  9. Inter-annual variabilities in biogeophysical feedback of terrestrial ecosystem to atmosphere using a land surface model

    Science.gov (United States)

    Seo, C.; Hong, S.; Jeong, H. M.; Jeon, J.

    2017-12-01

    Biogeophysical processes of terrestrial ecosystem such as water vapor and energy flux are the key features to understand ecological feedback to atmospheric processes and thus role of terrestrial ecosystem in climate system. For example, it has been recently known that the ecological feedback through water vapor and energy flux results in regulating regional weathers and climates which is one of the fundamental functions of terrestrial ecosystem. In regional scale, water vapor flux has been known to give negative feedback to atmospheric warming, while energy flux from the surface has been known to positive feedback. In this study, we explored the inter-annual variabilities in these two biogeophysical features to see how the climate regulating functions of terrestrial ecosystem have been changed with climate change. We selected a land surface model involving vegetation dynamics that is forced by atmospheric data from NASA including precipitation, temperature, wind, surface pressure, humidity, and incoming radiations. From the land surface model, we simulated 60-year water vapor and energy fluxes from 1961 to 2010, and calculates feedbacks of terrestrial ecosystem as in radiation amount into atmosphere. Then, we analyzed the inter-annual variabilities in the feedbacks. The results showed that some mid-latitude areas showing very high variabilities in precipitation showed higher positive feedback and/or lower negative feedback. These results suggest deterioration of the biogeophyisical factor of climate regulating function over those regions.

  10. Reviews and syntheses : An empirical spatiotemporal description of the global surface-atmosphere carbon fluxes: Opportunities and data limitations

    NARCIS (Netherlands)

    Zscheischler, Jakob; Mahecha, Miguel D.; Avitabile, Valerio; Calle, Leonardo; Carvalhais, Nuno; Ciais, Philippe; Gans, Fabian; Gruber, Nicolas; Hartmann, Jens; Herold, Martin; Ichii, Kazuhito; Jung, Martin; Landschützer, Peter; Laruelle, Goulven G.; Lauerwald, Ronny; Papale, Dario; Peylin, Philippe; Poulter, Benjamin; Ray, Deepak; Regnier, Pierre; Rödenbeck, Christian; Roman-Cuesta, Rosa M.; Schwalm, Christopher R.; Tramontana, Gianluca; Tyukavina, Alexandra; Valentini, Riccardo; Van Der Werf, Guido; West, Tristram O.; Wolf, Julie E.; Reichstein, Markus

    2017-01-01

    Understanding the global carbon (C) cycle is of crucial importance to map current and future climate dynamics relative to global environmental change. A full characterization of C cycling requires detailed information on spatiotemporal patterns of surface-atmosphere fluxes. However, relevant C cycle

  11. Contribution of seasonal sub-Antarctic surface water variability to millennial-scale changes in atmospheric CO2 over the last deglaciation and Marine Isotope Stage 3

    Science.gov (United States)

    Gottschalk, Julia; Skinner, Luke C.; Waelbroeck, Claire

    2015-02-01

    The Southern Ocean is thought to have played a key role in past atmospheric carbon dioxide (CO2,atm) changes. Three main factors are understood to control the Southern Ocean's influence on CO2,atm, via their impact on surface ocean pCO2 and therefore regional ocean-atmosphere CO2 fluxes: 1) the efficiency of air-sea gas exchange, which may be attenuated by seasonal- or annual sea-ice coverage or the development of a shallow pycnocline; 2) the supply of CO2-rich water masses from the sub-surface and the deep ocean, which is associated with turbulent mixing and surface buoyancy- and/or wind forcing; and 3) biological carbon fixation, which depends on nutrient availability and is therefore influenced by dust deposition and/or upwelling. In order to investigate the possible contributions of these processes to millennial-scale CO2,atm variations during the last glacial and deglacial periods, we make use of planktonic foraminifer census counts and stable oxygen- and carbon isotope measurements in the planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma (sinistral) from marine sediment core MD07-3076Q in the sub-Antarctic Atlantic. These data are interpreted on the basis of a comparison of core-top and modern seawater isotope data, which permits an assessment of the seasonal biases and geochemical controls on the stable isotopic compositions of G. bulloides and N. pachyderma (s.). Based on a comparison of our down-core results with similar data from the Southeast Atlantic (Cape Basin) we infer past basin-wide changes in the surface hydrography of the sub-Antarctic Atlantic. We find that millennial-scale rises in CO2,atm over the last 70 ka are consistently linked with evidence for increased spring upwelling, and enhanced summer air-sea exchange in the sub-Antarctic Atlantic. Parallel evidence for increased summer export production would suggest that seasonal changes in upwelling and air-sea exchange exerted a dominant influence on surface pCO2 in

  12. Preface paper to the Semi-Arid Land-Surface-Atmosphere (SALSA) Program special issue

    Science.gov (United States)

    Goodrich, D.C.; Chehbouni, A.; Goff, B.; MacNish, B.; Maddock, T.; Moran, S.; Shuttleworth, W.J.; Williams, D.G.; Watts, C.; Hipps, L.H.; Cooper, D.I.; Schieldge, J.; Kerr, Y.H.; Arias, H.; Kirkland, M.; Carlos, R.; Cayrol, P.; Kepner, W.; Jones, B.; Avissar, R.; Begue, A.; Bonnefond, J.-M.; Boulet, G.; Branan, B.; Brunel, J.P.; Chen, L.C.; Clarke, T.; Davis, M.R.; DeBruin, H.; Dedieu, G.; Elguero, E.; Eichinger, W.E.; Everitt, J.; Garatuza-Payan, J.; Gempko, V.L.; Gupta, H.; Harlow, C.; Hartogensis, O.; Helfert, M.; Holifield, C.; Hymer, D.; Kahle, A.; Keefer, T.; Krishnamoorthy, S.; Lhomme, J.-P.; Lagouarde, J.-P.; Lo, Seen D.; Luquet, D.; Marsett, R.; Monteny, B.; Ni, W.; Nouvellon, Y.; Pinker, R.; Peters, C.; Pool, D.; Qi, J.; Rambal, S.; Rodriguez, J.; Santiago, F.; Sano, E.; Schaeffer, S.M.; Schulte, M.; Scott, R.; Shao, X.; Snyder, K.A.; Sorooshian, S.; Unkrich, C.L.; Whitaker, M.; Yucel, I.

    2000-01-01

    The Semi-Arid Land-Surface-Atmosphere Program (SALSA) is a multi-agency, multi-national research effort that seeks to evaluate the consequences of natural and human-induced environmental change in semi-arid regions. The ultimate goal of SALSA is to advance scientific understanding of the semi-arid portion of the hydrosphere-biosphere interface in order to provide reliable information for environmental decision making. SALSA approaches this goal through a program of long-term, integrated observations, process research, modeling, assessment, and information management that is sustained by cooperation among scientists and information users. In this preface to the SALSA special issue, general program background information and the critical nature of semi-arid regions is presented. A brief description of the Upper San Pedro River Basin, the initial location for focused SALSA research follows. Several overarching research objectives under which much of the interdisciplinary research contained in the special issue was undertaken are discussed. Principal methods, primary research sites and data collection used by numerous investigators during 1997-1999 are then presented. Scientists from about 20 US, five European (four French and one Dutch), and three Mexican agencies and institutions have collaborated closely to make the research leading to this special issue a reality. The SALSA Program has served as a model of interagency cooperation by breaking new ground in the approach to large scale interdisciplinary science with relatively limited resources.

  13. A stable metal-organic framework with suitable pore sizes and rich uncoordinated nitrogen atoms on the internal surface of micropores for highly efficient CO2 capture

    NARCIS (Netherlands)

    Bao, S.J.; Krishna, R.; He, Y.B.; Qin, J.S.; Su, Z.M.; Li, S.L.; Xie, W.; Du, D.Y.; He, W.W.; Zhang, S.R.; Lan, Y.Q.

    2015-01-01

    An air-stable tetrazolate-containing framework, [ZN(2)L(2)]center dot 2DMF (NENU-520, H2L = 4-(1H-tetrazole-5-yl) biphenyl-4-carboxylic acid), with uncoordinated N atoms on its internal surface was solvothermally synthesized and structurally characterized. This metal-organic framework (MOF)

  14. Generalised coexistence of a low work function and a stable surface : CaAl4 and BaAuIn3

    NARCIS (Netherlands)

    Uijttewaal, M. A.; de Wijs, G. A.; de Groot, R. A.

    2006-01-01

    Cathodes are used in many devices ranging from microwave ovens to organic light-emitting diodes (OLEDs). Crucial materials properties are a low work function (Phi) and a (relatively) stable surface. The relation between the two was not clear for more-complex metals. Our previous paper [M.A.

  15. All-Weather Sounding of Moisture and Temperature From Microwave Sensors Using a Coupled Surface/Atmosphere Inversion Algorithm

    Science.gov (United States)

    Boukabara, S. A.; Garrett, K.

    2014-12-01

    A one-dimensional variational retrieval system has been developed, capable of producing temperature and water vapor profiles in clear, cloudy and precipitating conditions. The algorithm, known as the Microwave Integrated Retrieval System (MiRS), is currently running operationally at the National Oceanic and Atmospheric Administration (NOAA) National Environmental Satellite Data and Information Service (NESDIS), and is applied to a variety of data from the AMSU-A/MHS sensors on board the NOAA-18, NOAA-19, and MetOp-A/B polar satellite platforms, as well as SSMI/S on board both DMSP F-16 and F18, and from the NPP ATMS sensor. MiRS inverts microwave brightness temperatures into atmospheric temperature and water vapor profiles, along with hydrometeors and surface parameters, simultaneously. This atmosphere/surface coupled inversion allows for more accurate retrievals in the lower tropospheric layers by accounting for the surface emissivity impact on the measurements. It also allows the inversion of the soundings in all-weather conditions thanks to the incorporation of the hydrometeors parameters in the inverted state vector as well as to the inclusion of the emissivity in the same state vector, which is accounted for dynamically for the highly variable surface conditions found under precipitating atmospheres. The inversion is constrained in precipitating conditions by the inclusion of covariances for hydrometeors, to take advantage of the natural correlations that exist between temperature and water vapor with liquid and ice cloud along with rain water. In this study, we present a full assessment of temperature and water vapor retrieval performances in all-weather conditions and over all surface types (ocean, sea-ice, land, and snow) using matchups with radiosonde as well as Numerical Weather Prediction and other satellite retrieval algorithms as references. An emphasis is placed on retrievals in cloudy and precipitating atmospheres, including extreme weather events

  16. Measurements of mercury in the near-surface layer of the atmosphere of the Russian Arctic.

    Science.gov (United States)

    Golubeva, N; Burtseva, L; Matishov, G

    2003-05-01

    A series of measurements of gaseous elemental mercury concentrations in near-surface air of the Russian Arctic Region were carried out from 1994 to 1997. The measurements were conducted in Murmansk at a stationary site in April-May 1994, on a cruise in Motovsky Bay and Kola Bay during May-June 1996, and along the Russian Northern Sea Route in April-May 1997 on board the nuclear icebreaker 'Soviet Union'. Silver absorption was used for trapping of mercury and the mass of mercury was determined by cold vapour atomic absorption spectrophotometery. Detection limits were approximately 0.3 ng/m(3) (+/- error 46%). Sixty samples were selected and analysed. Sample volumes were 2.2 m(3) ashore, and up to 6.6 m(3) over water. The meteorological conditions, including a wind speed and direction, during the sampling period were typical of the spring-summer period of year, and therefore the concentrations of atmospheric mercury are regarded as representative for this season. The mean concentrations of mercury ranged from 2.2 ng/m(3) for Murmansk city, 1.7 ng/m(3) for Kola Bay, 1.6 ng/m(3) for Motovsky Bay, 1.1 ng/m(3) for the eastern part of the Barents Sea and 0.7 ng/m(3) for the western part of the Kara Sea. The levels of mercury in Murmansk, and over Kola and Motovsky Bays were associated with a primary direction of a near-surface wind from the nearest sources of mercury emission located in the Russian North region. These are the non-ferrous metallurgical plants in Nickel in the case of Motovsky Bay and Murmansk garbage-disposal plant, for sampling points in Murmansk and over Kola Bay. These concentrations of mercury, measured in the spring-summer season, in near-surface air of the Russian North, are more than two-fold lower than the concentrations that are typical of continental background regions in western Russia, and are comparable to the concentrations measured in the Arctic regions of other countries.

  17. Long-term Impacts of Hurricane Wilma on Land Surface-Atmosphere Exchanges

    Science.gov (United States)

    Fuentes, J. D.; Dowell, K. K.; Engel, V. C.; Smith, T. J.

    2008-05-01

    In October 2005, Hurricane Wilma made landfall along the mangrove forests of western Everglades National Park, Florida, USA. Damage from the storm varied with distance from landfall and included widespread mortality and extensive defoliation. Large sediment deposition events were recorded in the interior marshes, with erosion taking place along the coastal margins. Wilma made landfall near a 30 m flux tower where eddy-covariance measurements of ecosystem-level carbon and energy fluxes started in 2003. Repairs to the structure were completed in 2006, enabling comparisons of surface fluxes before and after the storm. One year after the hurricane, both the average and daily integrated CO2 fluxes are consistently lower than the pre-storm values. The storm's impact on standing live biomass and the slow recovery of leaf area appear to have resulted in decreased photosynthetic uptake capacity. Nighttime respiratory CO2 fluxes above the canopy are unchanged from pre-storm values. During some periods, daily integrated fluxes show the forest as a net source of CO2 to the atmosphere. Soil CO2 fluxes are not measured directly, but daytime soil temperatures and vertical heat fluxes have shown consistently higher values after the storm. Nighttime soil temperatures values have been slightly lower. These stronger diurnal soil temperature fluctuations indicate enhanced radiative fluxes at the soil surface, possibly as a result of the reduced leaf area. The increases in daytime soil temperatures are presumably leading to higher below-ground respiration rates and, along with the reduced photosynthetic capacity, contributing to the lower net CO2 assimilation rates. This hypothesis is supported by nearby measurements of declining surface elevations of the organic soils which have been correlated with mangrove mortality in impacted areas. Both sensible and latent heat fluxes above the canopy are found to be reduced following the hurricane, and soil heat storage is higher. Together

  18. Solid organic matter in the atmosphere and on the surface of outer Solar System bodies.

    Science.gov (United States)

    Khare, B N; Bakes, E L; Cruikshank, D; McKay, C P

    2001-01-01

    Many bodies in the outer Solar System display the presence of low albedo materials. These materials, evident on the surface of asteroids, comets, Kuiper Belt objects and their intermediate evolutionary step, Centaurs, are related to macromolecular carbon bearing materials such as polycyclic aromatic hydrocarbons and organic materials such as methanol and related light hydrocarbons, embedded in a dark, refractory, photoprocessed matrix. Many planetary rings and satellites around the outer gaseous planets display such component materials. One example, Saturn's largest satellite, Titan, whose atmosphere is comprised of around 90% molecular nitrogen N2 and less than 10% methane CH4, displays this kind of low reflectivity material in its atmospheric haze. These materials were first recorded during the Voyager 1 and 2 flybys of Titan and showed up as an optically thick pinkish orange haze layer. These materials are broadly classified into a chemical group whose laboratory analogs are termed "tholins", after the Greek word for "muddy". Their analogs are produced in the laboratory via the irradiation of gas mixtures and ice mixtures by radiation simulating Solar ultraviolet (UV) photons or keV charged particles simulating particles trapped in Saturn's magnetosphere. Fair analogs of Titan tholin are produced by bombarding a 9:1 mixture of N2:CH4 with charged particles and its match to observations of both the spectrum and scattering properties of the Titan haze is very good over a wide range of wavelengths. In this paper, we describe the historical background of laboratory research on this kind of organic matter and how our laboratory investigations of Titan tholin compare. We comment on the probable existence of polycyclic aromatic hydrocarbons in the Titan Haze and how biological and nonbiological racemic amino acids produced from the acid hydrolysis of Titan tholins make these complex organic compounds prime candidates in the evolution of terrestrial life and

  19. Quantification of long-term wastewater fluxes at the surface water/groundwater-interface: an integrative model perspective using stable isotopes and acesulfame.

    Science.gov (United States)

    Engelhardt, I; Barth, J A C; Bol, R; Schulz, M; Ternes, T A; Schüth, C; van Geldern, R

    2014-01-01

    The suitability of acesulfame to trace wastewater-related surface water fluxes from streams into the hyporheic and riparian zones over long-term periods was investigated. The transport behavior of acesulfame was compared with the transport of water stable isotopes (δ(18)O or δ(2)H). A calibrated model based on a joint inversion of temperature, acesulfame, and piezometric pressure heads was employed in a model validation using data sets of acesulfame and water stable isotopes collected over 5months in a stream and groundwater. The spatial distribution of fresh water within the groundwater resulting from surface water infiltration was estimated by computing groundwater ages and compared with the predicted acesulfame plume obtained after 153day simulation time. Both, surface water ratios calculated with a mixing equation from water stable isotopes and simulated acesulfame mass fluxes, were investigated for their ability to estimate the contribution of wastewater-related surface water inflow within groundwater. The results of this study point to limitations for the application of acesulfame to trace surface water-groundwater interactions properly. Acesulfame completely missed the wastewater-related surface water volumes that still remained in the hyporheic zone under stream-gaining conditions. In contrast, under stream-losing conditions, which developed after periods of stagnating hydraulic exchange, acesulfame based predictions lead to an overestimation of the surface water volume of up to 25% in the riparian zone. If slow seepage velocities prevail a proportion of acesulfame might be stored in smaller pores, while when released under fast flowing water conditions it will travel further downstream with the groundwater flow direction. Therefore, under such conditions acesulfame can be a less-ideal tracer in the hyporheic and riparian zones and additional monitoring with other environmental tracers such as water stable isotopes is highly recommended. © 2013 Elsevier

  20. Near 7-day response of ocean bottom pressure to atmospheric surface pressure and winds in the northern South China Sea

    Science.gov (United States)

    Zhang, Kun; Zhu, Xiao-Hua; Zhao, Ruixiang

    2018-02-01

    Ocean bottom pressures, observed by five pressure-recording inverted echo sounders (PIESs) from October 2012 to July 2014, exhibit strong near 7-day variability in the northern South China Sea (SCS) where long-term in situ bottom pressure observations are quite sparse. This variability was strongest in October 2013 during the near two years observation period. By joint analysis with European Center for Medium-Range Weather Forecasts (ECMWF) data, it is shown that the near 7-day ocean bottom pressure variability is closely related to the local atmospheric surface pressure and winds. Within a period band near 7 days, there are high coherences, exceeding 95% significance level, of observed ocean bottom pressure with local atmospheric surface pressure and with both zonal and meridional components of the wind. Ekman pumping/suction caused by the meridional component of the wind in particular, is suggested as one driving mechanism. A Kelvin wave response to the near 7-day oscillation would propagate down along the continental slope, observed at the Qui Nhon in the Vietnam. By multiple and partial coherence analyses, we find that local atmospheric surface pressure and Ekman pumping/suction show nearly equal influence on ocean bottom pressure variability at near 7-day periods. A schematic diagram representing an idealized model gives us a possible mechanism to explain the relationship between ocean bottom pressure and local atmospheric forcing at near 7-day periods in the northern SCS.

  1. Vertical variability of seawater DMS in the South Pacific Ocean and its implication for atmospheric and surface seawater DMS.

    Science.gov (United States)

    Lee, Gangwoong; Park, Jooyoung; Jang, Yuwoon; Lee, Meehye; Kim, Kyung-Ryul; Oh, Jae-Ryoung; Kim, Dongseon; Yi, Hi-Il; Kim, Tong-Yup

    2010-02-01

    Shipboard measurements of atmospheric dimethylsulfide (DMS) and sea surface water DMS were performed aboard the R/V Onnuri across the South Pacific from Santiago, Chile to Fiji in February 2000. Hydrographic profiles of DMS, dissolved dimethylsulfoniopropionate (DMSP(d)), and particulate DMSP(p) in the upper 200m were obtained at 16 stations along the track. Atmospheric and sea surface water DMS concentrations ranged from 3 to 442pptv and from 0.1 to 19.9nM, respectively; the mean values of 61pptv and 2.1nM, respectively, were comparable to those from previous studies in the South Pacific. The South Pacific Gyre was distinguished by longitudinal-vertical distributions of DMS, DMSP(d), and DMSP(p), which was thought to be associated with the characteristic modification of biological activities that occurs mainly due to significant change in water temperature. The averaged DMS maximum appeared at 40m depth, whereas DMSP(p) and DMSP(d) maxima coincided with that of dissolved oxygen content at 60-80m. The sea-to-air fluxes of DMS were estimated to be 0.4-11.3micromold(-1)m(-2) (mean=2.8micromold(-1)m(-2)). A fairly good correlation between atmospheric DMS and sea-to-air DMS flux indicated that atmospheric DMS concentration was more sensitive to change in physical parameters than its photochemical removal process or surface seawater DMS concentrations.

  2. Forecasting of aerosol extinction of the sea and coastal atmosphere surface layer

    Science.gov (United States)

    Kaloshin, G. A.

    2010-04-01

    The focus of our study is the extinction and optical effects due to aerosol in a specific coastal region. The aerosol microphysical model of the marine and coastal atmosphere surface layer is considered. The model is made on the basis of the long-term experimental data received at researches of aerosol sizes distribution function (dN/dr) in the band particles sizes in 0.01 - 100 μk. The model is developed by present time for the band of heights is 0 - 25 m. Bands of wind speed is 3 - 18 km/s, sizes fetch is up to 120 km, RH = 40 - 98 %. Key feature of model is parameterization of amplitude and width of the modes as functions of fetch and wind speed. In the paper the dN/dr behavior depending at change meteorological parameters, heights above sea level, fetch (X), wind speed (U) and RH is show. On the basis of the developed model with usage of Mie theory for spheres the description of last version of developed code MaexPro (Marine Aerosol Extinction Profiles) for spectral profiles of aerosol extinction coefficients α(λ) calculations in the wavelength band, equal λ = 0.2 - 12 μm is presented. The received results are compared models NAN and ANAM. Also α(λ) profiles for various wind modes (combinations X and U) calculated by MaexPro code are given. The calculated spectrums of α(λ) profiles are compared with experimental data of α(λ) received by a transmission method in various geographical areas.

  3. Trends in the chemistry of atmospheric deposition and surface waters in the Lake Maggiore catchment

    Directory of Open Access Journals (Sweden)

    M. Rogora

    2001-01-01

    Full Text Available The Lake Maggiore catchment is the area of Italy most affected by acid deposition. Trend analysis was performed on long-term (15-30 years series of chemical analyses of atmospheric deposition, four small rivers draining forested catchments and four high mountain lakes. An improvement in the quality of atmospheric deposition was detected, due to decreasing sulphate concentration and increasing pH. Similar trends were also found in high mountain lakes and in small rivers. Atmospheric deposition, however, is still providing a large and steady flux of nitrogen compounds (nitrate and ammonium which is causing increasing nitrogen saturation in forest ecosystems and increasing nitrate levels in rivers. Besides atmospheric deposition, an important factor controlling water acidification and recovery is the weathering of rocks and soils which may be influenced by climate warming. A further factor is the episodic deposition of Saharan calcareous dust which contributes significantly to base cation deposition. Keywords: trend, atmospheric deposition, nitrogen, stream water chemistry.

  4. Organic and inorganic markers and stable C-, N-isotopic compositions of tropical coastal aerosols from megacity Mumbai: sources of organic aerosols and atmospheric processing

    Directory of Open Access Journals (Sweden)

    S. G. Aggarwal

    2013-05-01

    Full Text Available To better understand the sources of PM10 samples in Mumbai, India, aerosol chemical composition, i.e., total carbon (TC, organic carbon (OC, elemental carbon (EC, water-soluble organic carbon (WSOC, and inorganic ions were studied together with specific markers such as methanesulfonate (MSA, oxalic acid (C2, azelaic acid (C9, and levoglucosan. The results revealed that biofuel/biomass burning and fossil fuel combustion are the major sources of the Mumbai aerosols. Nitrogen-isotopic (δ15N composition of aerosol total nitrogen, which ranged from 18.1 to 25.4‰, also suggests that biofuel/biomass burning is a predominate source in both the summer and winter seasons. Aerosol mass concentrations of major species increased 3–4 times in winter compared to summer, indicating enhanced emission from these sources in the winter season. Photochemical production tracers, C2 diacid and nssSO42−, do not show diurnal changes. Concentrations of C2 diacid and WSOC show a strong correlation (r2 = 0.95. In addition, WSOC to OC (or TC ratios remain almost constant for daytime (0.37 ± 0.06 (0.28 ± 0.04 and nighttime (0.38 ± 0.07 (0.28 ± 0.06, suggesting that mixing of fresh secondary organic aerosols is not significant and the Mumbai aerosols are photochemically well processed. Concentrations of MSA and C9 diacid present a positive correlation (r2 = 0.75, indicating a marine influence on Mumbai aerosols in addition to local/regional influence. Backward air mass trajectory analyses further suggested that the Mumbai aerosols are largely influenced by long-range continental and regional transport. Stable C-isotopic ratios (δ13C of TC ranged from −27.0 to −25.4‰, with slightly lower average (−26.5 ± 0.3‰ in summer than in winter (−25.9 ± 0.3‰. Positive correlation between WSOC/TC ratios and δ13C values suggested that the relative increment in 13C of wintertime TC may be caused by prolonged photochemical processing of organic

  5. Variability in the combustion-derived fraction of urban humidity in Salt Lake City winter estimated from stable water vapor isotopes and its relationship to atmospheric stability and inversion structure

    Science.gov (United States)

    Fiorella, R.; Bares, R.; Lin, J. C.; Strong, C.; Bowen, G. J.

    2017-12-01

    Water released from the combustion of fossil fuels, while a negligible part of the global hydrological cycle, may be a significant contributor to urban humidity as fossil fuel emissions are strongly concentrated in space and time. The fraction of urban humidity comprised of combustion-derived vapor (CDV) cannot be observed through humidity measurements alone. However, the distinct stable isotopic composition of CDV, which arises from the reaction of 18O-enriched atmospheric O2 with 2H-depleted organic molecules, represents a promising method to apportion observed humidity between CDV and advected vapor. We apply stable water vapor isotopes to investigate variability in CDV amount and its relationship to atmospheric conditions in Salt Lake City, Utah. The Salt Lake Valley experiences several periods of atmospheric stratification during winter known as cold air pools, during which concentrations of CDV and pollutants can be markedly elevated due to reduced atmospheric mixing. Therefore, the SLV during winter is an ideal place to investigate variability in CDV fraction across a spectrum of boundary layer conditions, ranging from well-mixed to very stable. We present water vapor isotope data from four winters (2013-2017) from the top of a 30 m building on the University of Utah (U of U) Campus. Additionally, we present water vapor isotope data from the summit of Hidden Peak from the 2016-2017 winter, 25 km SE and 2000 m above the U of U site. The Hidden Peak site is consistently above the cold air pool emplaced in the SLV during stable events. We find the expression of the CDV signal in the valley is related to the atmospheric structure of the cold air pools in the SLV, and that the fraction of CDV inferred in the valley is likely related to the mixing height within the cold air pool. Furthermore, we find that patterns between the Hidden Peak and U of U sites during inversion events may record the large-scale atmospheric dynamics promoting emplacement of the cold air

  6. Seasonal Variations of the Earth's Gravitational Field: An Analysis of Atmospheric Pressure, Ocean Tidal, and Surface Water Excitation

    Science.gov (United States)

    Dong, D,; Gross, R.S.; Dickey, J.

    1996-01-01

    Monthly mean gravitational field parameters (denoted here as C(sub even)) that represent linear combinations of the primarily even degree zonal spherical harmonic coefficients of the Earth's gravitational field have been recovered using LAGEOS I data and are compared with those derived from gridded global surface pressure data of the National meteorological center (NMC) spanning 1983-1992. The effect of equilibrium ocean tides and surface water variations are also considered. Atmospheric pressure and surface water fluctuations are shown to be the dominant cause of observed annual C(sub even) variations. Closure with observations is seen at the 1sigma level when atmospheric pressure, ocean tide and surface water effects are include. Equilibrium ocean tides are shown to be the main source of excitation at the semiannual period with closure at the 1sigma level seen when both atmospheric pressure and ocean tide effects are included. The inverted barometer (IB) case is shown to give the best agreement with the observation series. The potential of the observed C(sub even) variations for monitoring mass variations in the polar regions of the Earth and the effect of the land-ocean mask in the IB calculation are discussed.

  7. Hydrogeochemistry and stable isotopes of ground and surface waters from two adjacent closed basins, Atacama Desert, northern Chile

    Science.gov (United States)

    Alpers, Charles N.; Whittemore, D.O.

    1990-01-01

    The geochemistry and stable isotopes of groundwaters, surface waters, and precipitation indicate different sources of some dissolved constituents, but a common source of recharge and other constituents in two adjacent closed basins in the Atacama Desert region of northern Chile (24??15???-24??45???S). Waters from artesian wells, trenches, and ephemeral streams in the Punta Negra Basin are characterized by concentrations of Na>Ca>Mg and Cl ???SO4, with TDS Mg ??? Ca and SO4 > Cl, with TDS also Mg ??? Ca and SO4 > Cl, but with TDS up to 40 g/l. The deep mine waters have pH between 3.2 and 3.9, and are high in dissolved CO2 (??13 C = -4.8%PDB), indicating probable interaction with oxidizing sulfides. The deep mine waters have ??18O values of ???-1.8%.compared with values < -3.5??? for other Hamburgo Basin waters; thus the mine waters may represent a mixture of meteoric waters with deeper "metamorphic" waters, which had interacted with rocks and exchanged oxygen isotopes at elevated temperatures. Alternatively, the deep mine waters may represent fossil meteoric waters which evolved isotopically along an evaporative trend starting from values quite depleted in ??18O and ??Dd relative to either precipitation or shallow groundwaters. High I/Br ratios in the Hamburgo Basin waters and La Escondida mine waters are consistent with regionally high I in surficial deposits in the Atacama Desert region and may represent dissolution of a wind-blown evaporite component. Rain and snow collected during June 1984, indicate systematic ??18O and ??D fractionation with increasing elevation between 3150 and 4180 m a.s.l. (-0.21??.??18O and -1.7??.??D per 100 m). Excluding the deep mine waters from La Escondida, the waters from the Hamburgo and Punta Negra Basins have similar ??D and ??18O values and together show a distinct evaporative trend (??D = 5.0 ??18O - 20.2). Snowmelt from the central Andes Cordillera to the east is the most likely source of recharge to both basins. Some of the

  8. Experimental Research on Water Boiling Heat Transfer on Horizontal Copper Rod Surface at Sub-Atmospheric Pressure

    Directory of Open Access Journals (Sweden)

    Li-Hua Yu

    2015-09-01

    Full Text Available In recent years, water (R718 as a kind of natural refrigerant—which is environmentally-friendly, safe and cheap—has been reconsidered by scholars. The systems of using water as the refrigerant, such as water vapor compression refrigeration and heat pump systems run at sub-atmospheric pressure. So, the research on water boiling heat transfer at sub-atmospheric pressure has been an important issue. There are many research papers on the evaporation of water, but there is a lack of data on the characteristics at sub-atmospheric pressures, especially lower than 3 kPa (the saturation temperature is 24 °C. In this paper, the experimental research on water boiling heat transfer on a horizontal copper rod surface at 1.8–3.3 kPa is presented. Regression equations of the boiling heat transfer coefficient are obtained based on the experimental data, which are convenient for practical application.

  9. Untangling the Chemical Evolution of Titan's Atmosphere and Surface -- From Homogeneous to Heterogeneous Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kaiser, Ralf I.; Maksyutenko, Pavlo; Ennis, Courtney; Zhang, Fangtong; Gu, Xibin; Krishtal, Sergey P.; Mebel, Alexander M.; Kostko, Oleg; Ahmed, Musahid

    2010-03-16

    The arrival of the Cassini-Huygens probe at Saturn's moon Titan - the only Solar System body besides Earth and Venus with a solid surface and a thick atmosphere with a pressure of 1.4 atm at surface level - in 2004 opened up a new chapter in the history of Solar System exploration. The mission revealed Titan as a world with striking Earth-like landscapes involving hydrocarbon lakes and seas as well as sand dunes and lava-like features interspersed with craters and icy mountains of hitherto unknown chemical composition. The discovery of a dynamic atmosphere and active weather system illustrates further the similarities between Titan and Earth. The aerosol-based haze layers, which give Titan its orange-brownish color, are not only Titan's most prominent optically visible features, but also play a crucial role in determining Titan's thermal structure and chemistry. These smog-like haze layers are thought to be very similar to those that were present in Earth's atmosphere before life developed more than 3.8 billion years ago, absorbing the destructive ultraviolet radiation from the Sun, thus acting as 'prebiotic ozone' to preserve astrobiologically important molecules on Titan. Compared to Earth, Titan's low surface temperature of 94 K and the absence of liquid water preclude the evolution of biological chemistry as we know it. Exactly because of these low temperatures, Titan provides us with a unique prebiotic 'atmospheric laboratory' yielding vital clues - at the frozen stage - on the likely chemical composition of the atmosphere of the primitive Earth. However, the underlying chemical processes, which initiate the haze formation from simple molecules, have been not understood well to date.

  10. Momentum and buoyancy transfer in atmospheric turbulent boundary layer over wavy water surface – Part 1: Harmonic wave

    Directory of Open Access Journals (Sweden)

    Yu. I. Troitskaya

    2013-10-01

    Full Text Available The surface-drag and mass-transfer coefficients are determined within a self-consistent problem of wave-induced perturbations and mean fields of velocity and density in the air, using a quasi-linear model based on the Reynolds equations with down-gradient turbulence closure. Investigation of a harmonic wave propagating along the wind has disclosed that the surface drag is generally larger for shorter waves. This effect is more pronounced in the unstable and neutral stratification. The stable stratification suppresses turbulence, which leads to weakening of the momentum and mass transfer.

  11. NOAA Climate Data Record (CDR) of Ocean Near Surface Atmospheric Properties, Version 1 (Version Superseded)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Please note, this dataset has been superseded by a newer version (see below). Users should not use this version except in rare cases (e.g., when reproducing previous...

  12. Atmospheric response to multidecadal sea surface temperature variability in the Pacific Ocean (IPV) and the North Atlantic Ocean (AMV)

    Science.gov (United States)

    Elsbury, D.; Peings, Y.; Magnusdottir, G.

    2017-12-01

    Multidecadal modes of sea surface temperature (SST) variability in the Pacific and Atlantic Oceans act as forcing fields in a series of atmospheric global climate model (AGCM) simulations. These modes, Interdecadal Pacific Variability (IPV) and Atlantic Multidecadal Variability (AMV), are important regulators of global temperature, precipitation, extreme climate events (droughts and temperature extremes), and have recently been implicated as playing an important role in the global warming hiatus. Despite a growing recognition of the importance of these climate modes, the most fundamental atmospheric and climatic responses to the long-term internal variability and interplay of these two ocean basins is not well understood. In a series of 200-yr experiments using the Whole Atmosphere Community Climate Model (WACCM), the atmosphere is forced by the 9 different combinations of the AMV and IPV states (neutral, positive, negative) using a single polarity from each the IPV and the AMV, and different combinations. The atmospheric response associated with each combination of SST anomalies is investigated, with a focus on modes of variability such as the North Atlantic Oscillation (NAO) and associated temperature/precipitation variability. Of particular interest is the response related to forcing from the tropical Pacific, the stratospheric response and associated stratosphere-troposphere interactions, and the response of extreme weather events in both winter and summer. These results yield a more complete understanding of climate predictability associated with each basin at multidecadal time scales, and how their respective influences interfere with each other.

  13. Surface-atmosphere interactions with coupled within-canopy aerodynamic resistance and canopy reflection.

    Science.gov (United States)

    Timmermans, J.; van der Tol, C.; Verhoef, W.; Su, Z.

    2009-04-01

    Models that describe the exchange of CO2 and H2O between the surface and atmosphere use bulk-parametrization of the within-canopy aerodynamic resistance and leaf area density (eq. LAI). This bulk parametrization is based on the Monin-Obukhov Similarity (MOS) theory. The MOS theory however breaks down for sparse canopies and it cannot couple profiles in the leaf density to profiles in the within-canopy aerodynamic resistance. The objective of this research is to create a simple model that is able to couple the within-canopy aerodynamic resistance and canopy reflection for different levels in the canopy. This model should be able to represent the canopy using as fewer parameters as possible, in order to facilitate inversion of remote sensing imagery. A virtual canopy was simulated using an L-systems approach, Lindenmayer 1968. The L-system approach was chosen because it describes the canopy with fractals. It therefore needs very little inputs to simulate a virtual canopy. A vertical profile of leaf density was calculated for 60 levels from this virtual canopy. The within-canopy aerodynamic resistance was modeled from the vertical leaf density profile using foliage drag coefficient, Massman 1997. A modified version of the SCOPE (Soil Canopy Observations and Photosynthesis) model was used to calculate the H2O and CO2 fluxes using the vertical profiles of leaf density and within-canopy aerodynamic resistance. The simulated fluxes are compared with field measurements over a vineyard and a forested area. The field measurements in both areas are acquired using the same setup: a basic flux tower in addition with an eddy-covariance setup. We present in this article the methodology and the results, as a proof of concept. references Massman, W.J., An Analytical One-Dimensional Model of Momentum Transfer by vegetation of arbitrary structure, Boundary-Layer Meteorology, 1997, 83, 407-421 Lindenmayer, A., Mathematical Models for Cellular Interactions in Development, Journal of

  14. Simultaneous and long-lasting hydrophilization of inner and outer wall surfaces of polytetrafluoroethylene tubes by transferring atmospheric pressure plasmas

    International Nuclear Information System (INIS)

    Chen, Faze; Song, Jinlong; Huang, Shuai; Xu, Wenji; Sun, Jing; Liu, Xin; Xu, Sihao; Xia, Guangqing; Yang, Dezheng

    2016-01-01

    Plasma hydrophilization is a general method to increase the surface free energy of materials. However, only a few works about plasma modification focus on the hydrophilization of tube inner and outer walls. In this paper, we realize simultaneous and long-lasting plasma hydrophilization on the inner and outer walls of polytetrafluoroethylene (PTFE) tubes by atmospheric pressure plasmas (APPs). Specifically, an Ar atmospheric pressure plasma jet (APPJ) is used to modify the PTFE tube’s outer wall and meanwhile to induce transferred He APP inside the PTFE tube to modify its inner wall surface. The optical emission spectrum (OES) shows that the plasmas contain many chemically active species, which are known as enablers for various applications. Water contact angle (WCA) measurements, x-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) are used to characterize the plasma hydrophilization. Results demonstrate that the wettability of the tube walls are well improved due to the replacement of the surface fluorine by oxygen and the change of surface roughness. The obtained hydrophilicity decreases slowly during more than 180 d aging, indicating a long-lasting hydrophilization. The results presented here clearly demonstrate the great potential of transferring APPs for surface modification of the tube’s inner and outer walls simultaneously. (paper)

  15. Exploration of surface hydrophilic properties on AISI 304 stainless steel and silicon wafer against aging after atmospheric pressure plasma treatment

    Science.gov (United States)

    Chuang, Shang-I.; Duh, Jenq-Gong

    2014-11-01

    The aim of this work is to seek the enhanced surface hydrophilic properties on AISI 304 stainless steel and silicon wafer after atmospheric pressure plasma treatment using a specifically designed atmospheric pressure plasma jet. The aging tendency of surface hydrophilic property under air is highlighted. It is concluded that both of the silicon wafer and stainless steel treated with plasma generated from supply gas of argon 15 slm mixed with oxygen 40 sccm shows a better tendency on remaining high water contact angle as compared to that with pure argon and nitrogen addition. Additional peaks of O I (777, 844 nm), O II (408 nm) are detected by optical emission spectroscope indicating the presence of the oxygen radicals and ionic species, which interact with surfaces and thus contribute to low water contact angle (WCA) surfaces. Moreover, the result acquired from X-ray photoelectron spectroscopy (XPS) indicates that the increase in the oxygen-related bonding exhibits a better contribution on remaining high surface energy over a period of time.

  16. Surface modification of the titanium implant using TEA CO 2 laser pulses in controllable gas atmospheres - Comparative study

    Science.gov (United States)

    Ciganovic, J.; Stasic, J.; Gakovic, B.; Momcilovic, M.; Milovanovic, D.; Bokorov, M.; Trtica, M.

    2012-01-01

    Interaction of a TEA CO2 laser, operating at 10.6 μm wavelength and pulse duration of 100 ns (FWHM), with a titanium implant in various gas atmospheres was studied. The Ti implant surface modification was typically studied at the moderate laser beam energy density/fluence of 28 J/cm2 in the surrounding of air, N2, O2 or He. The energy absorbed from the TEA CO2 laser beam is partially converted to thermal energy, which generates a series of effects, such as melting, vaporization of the molten material, shock waves, etc. The following titanium implant surface changes and phenomena were observed, depending on the gas used: (i) creation of cone-like surface structures in the atmospheres of air, N2 and O2, and dominant micro-holes/pores in He ambient; (ii) hydrodynamic features, most prominent in air; (iii) formation of titanium nitride and titanium oxide layers, and (iv) occurrence of plasma in front of the implant. It can be concluded from this study that the reported laser fluence and gas ambiences can effectively be applied for enhancing the titanium implant roughness and creation of titanium oxides and nitrides on the strictly localized surface area. The appearance of plasma in front of the implants indicates relatively high temperatures created above the surface. This offers a sterilizing effect, facilitating contaminant-free conditions.

  17. Oxygen and silicon stable isotopes of diatom silica. Reconstructing changes in surface water hydrography and silicic acid utilization in the late Pleistocene subarctic Pacific

    International Nuclear Information System (INIS)

    Maier, Edith

    2014-01-01

    Deglacial variations in upper ocean nutrient dynamics and stratification in high latitudes, as well as associated changes in thermohaline overturning circulation, are thought to have played a key role in changing atmospheric CO 2 concentrations. This thesis examines the relationship between past changes in subarctic Pacific upper ocean stratification and nutrient (silicic acid) utilization, using oxygen and silicon stable isotopes of diatom silica, for the first time at millennial-scale resolution and analyzed with a new and efficient instrumentation set-up. The isotopic data, presented in three manuscripts, show a consistent picture of millennial-scale variability in upper ocean stratification and silicic acid utilization during the last ∝50 ka BP, e.g. indicating that the subarctic Pacific was a source region for atmospheric CO 2 during the last deglaciation (late Heinrich Stadial 1 and the Boelling/Alleroed). The presented results demonstrate the high potential of combined diatom oxygen and silicon stable isotope analysis especially for, but not restricted to, marine regions characterized by a low biogenic carbonate content like the subarctic Pacific and the Southern Ocean.

  18. Oxygen and silicon stable isotopes of diatom silica. Reconstructing changes in surface water hydrography and silicic acid utilization in the late Pleistocene subarctic Pacific

    Energy Technology Data Exchange (ETDEWEB)

    Maier, Edith

    2014-03-05

    Deglacial variations in upper ocean nutrient dynamics and stratification in high latitudes, as well as associated changes in thermohaline overturning circulation, are thought to have played a key role in changing atmospheric CO{sub 2} concentrations. This thesis examines the relationship between past changes in subarctic Pacific upper ocean stratification and nutrient (silicic acid) utilization, using oxygen and silicon stable isotopes of diatom silica, for the first time at millennial-scale resolution and analyzed with a new and efficient instrumentation set-up. The isotopic data, presented in three manuscripts, show a consistent picture of millennial-scale variability in upper ocean stratification and silicic acid utilization during the last ∝50 ka BP, e.g. indicating that the subarctic Pacific was a source region for atmospheric CO{sub 2} during the last deglaciation (late Heinrich Stadial 1 and the Boelling/Alleroed). The presented results demonstrate the high potential of combined diatom oxygen and silicon stable isotope analysis especially for, but not restricted to, marine regions characterized by a low biogenic carbonate content like the subarctic Pacific and the Southern Ocean.

  19. Surface energy balances of three general circulation models: Current climate and response to increasing atmospheric CO2

    International Nuclear Information System (INIS)

    Gutowski, W.J.; Gutzler, D.S.; Portman, D.; Wang, W.C.

    1988-04-01

    The surface energy balance simulated by state-of-the-art general circulation models at GFDL, GISS and NCAR for climates with current levels of atmospheric CO 2 concentration (control climate) and with twice the current levels. The work is part of an effort sponsored by the US Department of Energy to assess climate simulations produced by these models. The surface energy balance enables us to diagnose differences between models in surface temperature climatology and sensitivity to doubling CO 2 in terms of the processes that control surface temperature. Our analysis compares the simulated balances by averaging the fields of interest over a hierarchy of spatial domains ranging from the entire globe down to regions a few hundred kilometers across

  20. Relative Influence of Initial Surface and Atmospheric Conditions on Seasonal Water and Energy Balances

    Science.gov (United States)

    Oglesby, Robert J.; Marshall, Susan; Roads, John O.; Robertson, Franklin R.; Goodman, H. Michael (Technical Monitor)

    2001-01-01

    We constructed and analyzed wet and dry soil moisture composites for the mid-latitude GCIP region of the central US using long climate model simulations made with the NCAR CCM3 and reanalysis products from NCEP. Using the diagnostic composites as a guide, we have completed a series of predictability experiments in which we imposed soil water initial conditions in CCM3 for the GCIP region for June 1 from anomalously wet and dry years, with atmospheric initial conditions taken from June 1 of a year with 'near-normal' soil water, and initial soil water from the near-normal year and atmospheric initial conditions from the wet and dry years. Preliminary results indicate that the initial state of the atmosphere is more important than the initial state of soil water determining the subsequent late spring and summer evolution of sod water over the GCIP region. Surprisingly, neither the composites or the predictability experiments yielded a strong influence of soil moisture on the atmosphere. To explore this further, we have made runs with extreme dry soil moisture initial anomalies imposed over the GCIP region (the soil close to being completely dry). These runs did yield a very strong effect on the atmosphere that persisted for at least three months. We conclude that the magnitude of the initial soil moisture anomaly is crucial, at least in CCM3, and are currently investigating whether a threshold exists, below which little impact is seen. In a complementary study, we compared the impact of the initial condition of snow cover versus the initial atmospheric state over the western US (corresponding to the westward extension of the GAPP program follow-on to GCIP). In this case, the initial prescription of snow cover is far more important than the initial atmospheric state in determining the subsequent evolution of snow cover. We are currently working to understand the very different soil water and snow cover results.

  1. Thermal and induced flow characteristics of radio frequency surface dielectric barrier discharge plasma actuation at atmospheric pressure

    International Nuclear Information System (INIS)

    Wang Wei-long; Li Jun; Song Hui-min; Jin Di; Jia Min; Wu Yun

    2017-01-01

    Thermal and induced flow velocity characteristics of radio frequency (RF) surface dielectric barrier discharge (SDBD) plasma actuation are experimentally investigated in this paper. The spatial and temporal distributions of the dielectric surface temperature are measured with the infrared thermography at atmospheric pressure. In the spanwise direction, the highest dielectric surface temperature is acquired at the center of the high voltage electrode, while it reduces gradually along the chordwise direction. The maximum temperature of the dielectric surface raises rapidly once discharge begins. After several seconds (typically 100 s), the temperature reaches equilibrium among the actuator’s surface, plasma, and surrounding air. The maximum dielectric surface temperature is higher than that powered by an AC power supply in dozens of kHz. Influences of the duty cycle and the input frequency on the thermal characteristics are analyzed. When the duty cycle increases, the maximum dielectric surface temperature increases linearly. However, the maximum dielectric surface temperature increases nonlinearly when the input frequency varies from 0.47 MHz to 1.61 MHz. The induced flow velocity of the RF SDBD actuator is 0.25 m/s. (paper)

  2. Surface modification of polyester fabrics by atmospheric-pressure air/He plasma for color strength and adhesion enhancement

    Science.gov (United States)

    Zhang, Chunming; Zhao, Meihua; Wang, Libing; Qu, Lijun; Men, Yajing

    2017-04-01

    Surface properties of water-based pigmented inks for ink-jet printed polyester fabrics were modified with atmospheric-pressure air/He plasma to improve the color strength and pigment adhesion of the treated surfaces. The influence of various parameters, including the surface morphology, chemical compositions, surface energy and dynamic contact angles of the control and plasma treated samples was studied. Color strength and edge definition were used to evaluate the ink-jet printing performance of fabrics. The change in pigment adhesion to polyester fibers was analyzed by SEM (scanning electron microscopy). AFM (Atomic force microscope) and XPS (X-ray photoelectron spectroscopy) analyses indicated the increase in surface roughness and the oxygen-containing polar groups(Cdbnd O, Csbnd OH and COOH) reinforced the fixation of pigments on the fiber surface. The result from this study suggested that the improved pigment color yield was clearly affected by alteration of pigment adhesion enhanced by plasma surface modification. Polyester fabrics exhibited better surface property and ink-jet printing performance after the air/He mixture plasma treatment comparing with those after air plasma treatment.

  3. Hydrophilic property of 316L stainless steel after treatment by atmospheric pressure corona streamer plasma using surface-sensitive analyses

    Energy Technology Data Exchange (ETDEWEB)

    Al-Hamarneh, Ibrahim, E-mail: hamarnehibrahim@yahoo.com [Department of Physics, Faculty of Science, Al-Balqa Applied University, Salt 19117 (Jordan); Pedrow, Patrick [School of Electrical Engineering and Computer Science, Washington State University, Pullman, WA 99164 (United States); Eskhan, Asma; Abu-Lail, Nehal [Gene and Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164 (United States)

    2012-10-15

    Highlights: Black-Right-Pointing-Pointer Surface hydrophilic property of surgical-grade 316L stainless steel was enhanced by Ar-O{sub 2} corona streamer plasma treatment. Black-Right-Pointing-Pointer Hydrophilicity, surface morphology, roughness, and chemical composition before and after plasma treatment were evaluated. Black-Right-Pointing-Pointer Contact angle measurements and surface-sensitive analyses techniques, including XPS and AFM, were carried out. Black-Right-Pointing-Pointer Optimum plasma treatment conditions of the SS 316L surface were determined. - Abstract: Surgical-grade 316L stainless steel (SS 316L) had its surface hydrophilic property enhanced by processing in a corona streamer plasma reactor using O{sub 2} gas mixed with Ar at atmospheric pressure. Reactor excitation was 60 Hz ac high-voltage (0-10 kV{sub RMS}) applied to a multi-needle-to-grounded screen electrode configuration. The treated surface was characterized with a contact angle tester. Surface free energy (SFE) for the treated stainless steel increased measurably compared to the untreated surface. The Ar-O{sub 2} plasma was more effective in enhancing the SFE than Ar-only plasma. Optimum conditions for the plasma treatment system used in this study were obtained. X-ray photoelectron spectroscopy (XPS) characterization of the chemical composition of the treated surfaces confirms the existence of new oxygen-containing functional groups contributing to the change in the hydrophilic nature of the surface. These new functional groups were generated by surface reactions caused by reactive oxidation of substrate species. Atomic force microscopy (AFM) images were generated to investigate morphological and roughness changes on the plasma treated surfaces. The aging effect in air after treatment was also studied.

  4. Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

    Directory of Open Access Journals (Sweden)

    I. Leifer

    2018-03-01

    Full Text Available Methane (CH4 inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne–surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL and combines downwind trace gas concentration anomaly (plume above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX – the Alpha Jet Atmospheric eXperiment and mobile surface (collected by AMOG – the AutoMObile trace Gas – Surveyor data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV floor into the Sierra Nevada (0.1–2.2 km altitude, validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10–20 km downwind, highlighting the importance of the experimental design.

  5. Simultaneous observation of seasonal variations of beryllium-7 and typical POPs in near-surface atmospheric aerosols in Guangzhou, China

    Science.gov (United States)

    Pan, Jing; Yang, Yong-Liang; Zhang, Gan; Shi, Jing-Lei; Zhu, Xiao-Hua; Li, Yong; Yu, Han-Qing

    2011-07-01

    Near-surface atmospheric aerosol samples were collected at the sampling frequency of 2-3 d per week for one year from August 2006 to August 2007 at a low latitude station in Tianhe District, Guangzhou, Guangdong Province of southern China. The samples were analyzed for cosmogenic nuclide 7Be and persistent organic pollutants, i.e. organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs). The annual average 7Be concentration was 2.59 mBq m -3, with the maximum occurred in May (8.45 mBq m -3) and minimum in late August and early September (0.07 mBq m -3). Winter and spring were the seasons in which the 7Be concentrations were high while summer and autumn were the lower 7Be seasons. Spring peaks in 7Be in the near-surface atmospheric aerosols may have associated with the "spring leak maximum" episode. The annual average ∑OCPs concentration was 345.6 pg m -3, ∑ 33PCBs 317.6 pg m -3, and ∑ 31PBDEs 609.0 pg m -3. The variation trends in the time-series of 7Be, OCPs, PCBs, and PBDEs in near-surface atmospheric aerosol showed both common features and differences. Significant correlations ( R2 = 0.957 and 0.811. respectively, p = 0.01) were observed between the monthly average 7Be concentrations and those of ∑PCBs and ∑PBDEs in summer, autumn, and early winter. The difference between the seasonal variation features of OCPs and PCBs (and PBDEs) could be attributed to the different source functions and physical-chemical properties which could control the behaviors of these compounds in air-aerosol partitions as well as atmospheric transport.

  6. Numerical Experiments on the Computation of Ground Surface Temperature in an Atmospheric Circulation Model

    Science.gov (United States)

    computation of the ground surface temperature. It is hoped that this discussion will contribute to the improvement of the accuracy of computed ground surface temperature in the simulation of climatic changes .

  7. Reviews and syntheses: An empirical spatiotemporal description of the global surface-atmosphere carbon fluxes: opportunities and data limitations

    Science.gov (United States)

    Zscheischler, Jakob; Mahecha, Miguel D.; Avitabile, Valerio; Calle, Leonardo; Carvalhais, Nuno; Ciais, Philippe; Gans, Fabian; Gruber, Nicolas; Hartmann, Jens; Herold, Martin; Ichii, Kazuhito; Jung, Martin; Landschützer, Peter; Laruelle, Goulven G.; Lauerwald, Ronny; Papale, Dario; Peylin, Philippe; Poulter, Benjamin; Ray, Deepak; Regnier, Pierre; Rödenbeck, Christian; Roman-Cuesta, Rosa M.; Schwalm, Christopher; Tramontana, Gianluca; Tyukavina, Alexandra; Valentini, Riccardo; van der Werf, Guido; West, Tristram O.; Wolf, Julie E.; Reichstein, Markus

    2017-08-01

    Understanding the global carbon (C) cycle is of crucial importance to map current and future climate dynamics relative to global environmental change. A full characterization of C cycling requires detailed information on spatiotemporal patterns of surface-atmosphere fluxes. However, relevant C cycle observations are highly variable in their coverage and reporting standards. Especially problematic is the lack of integration of the carbon dioxide (CO2) exchange of the ocean, inland freshwaters and the land surface with the atmosphere. Here we adopt a data-driven approach to synthesize a wide range of observation-based spatially explicit surface-atmosphere CO2 fluxes from 2001 to 2010, to identify the state of today's observational opportunities and data limitations. The considered fluxes include net exchange of open oceans, continental shelves, estuaries, rivers, and lakes, as well as CO2 fluxes related to net ecosystem productivity, fire emissions, loss of tropical aboveground C, harvested wood and crops, as well as fossil fuel and cement emissions. Spatially explicit CO2 fluxes are obtained through geostatistical and/or remote-sensing-based upscaling, thereby minimizing biophysical or biogeochemical assumptions encoded in process-based models. We estimate a bottom-up net C exchange (NCE) between the surface (land, ocean, and coastal areas) and the atmosphere. Though we provide also global estimates, the primary goal of this study is to identify key uncertainties and observational shortcomings that need to be prioritized in the expansion of in situ observatories. Uncertainties for NCE and its components are derived using resampling. In many regions, our NCE estimates agree well with independent estimates from other sources such as process-based models and atmospheric inversions. This holds for Europe (mean ± 1 SD: 0.8 ± 0.1 PgC yr-1, positive numbers are sources to the atmosphere), Russia (0.1 ± 0.4 PgC yr-1), East Asia (1.6 ± 0.3 PgC yr-1), South Asia (0.3 ± 0

  8. Simulation of trace metals and PAH atmospheric pollution over Greater Paris: Concentrations and deposition on urban surfaces

    Science.gov (United States)

    Thouron, L.; Seigneur, C.; Kim, Y.; Legorgeu, C.; Roustan, Y.; Bruge, B.

    2017-10-01

    Urban areas can be subject not only to poor air quality, but also to contamination of other environmental media by air pollutants. Here, we address the potential transfer of selected air pollutants (two metals and three PAH) to urban surfaces. To that end, we simulate meteorology and air pollution from Europe to a Paris suburban neighborhood, using a four-level one-way nesting approach. The meteorological and air quality simulations use urban canopy sub-models in order to better represent the effect of the urban morphology on the air flow, atmospheric dispersion, and deposition of air pollutants to urban surfaces. This modeling approach allows us to distinguish air pollutant deposition among various urban surfaces (roofs, roads, and walls). Meteorological model performance is satisfactory, showing improved results compared to earlier simulations, although precipitation amounts a