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Sample records for stabilized solar pond

  1. Stabilization of mixed waste - Rocky Flats solar ponds

    International Nuclear Information System (INIS)

    Bittner, T.A.; Mathew, S.A.; Henderson, W.C.

    1993-01-01

    Among the wastes that require disposal as part of the Department of Energy's (DOE's) Environmental Restoration Program are large amounts of contaminated sludge and inorganic wastes. Halliburton NUS Corporation was awarded a contract by EG ampersand G Rocky Flats in March 1991 to stabilize mixed waste sludge contained in five solar evaporator ponds and to reprocess billets of solidified waste called Pondcrete and Saltcrete at DOE's Rocky Flats Plant. The scope of the project consists of waste characterization and treatability studies for process development, followed by design, construction and operation of various process trains to remediate different waste forms ranging from solid Pondcrete/Saltcrete blocks to aqueous brine solutions. One of the significant advances made was the development of a durable and certifiable stabilization formulation capable of treating concentrated nitrate solution wastes. The project uses high-volume grout mixing and pumping technologies with process control techniques that accommodate the heterogeneity of the wastes. To comply with all relevant environmental regulations and to provide a safe working atmosphere for plant personnel, Halliburton NUS designed process trains such that all emissions were eliminated during the remediation process. Personnel protection equipment requirements have been downgraded due to safeguards incorporated in the design. The technical and regulatory issues that were encountered would be typical of stabilization efforts underway at other DOE sites. Thus the lessons learned and concepts developed can be expected to have widespread application

  2. Stability considerations and a double-diffusive convection model for solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Lin, E.I.H.; Sha, W.T.; Soo, S.L.

    1979-04-01

    A brief survey is made on the basic principles, current designs and economic advantages of salinity-gradient solar ponds as solar collectors and reservoirs. Solar ponds are well-suited for various AIPH (agricultural and industrial process heat) applications, and as annual storage devices for space heating and cooling. The benefit of an efficient pond is demonstrated via a preliminary economic analysis which suggests the idea of energy farming as a profitable alternative for land usage in the face of rising fuel cost. The economy and reliability of solar-pond operation depend crucially on the stability of the nonconvective gradient zone against disturbances such as generated by a severe weather condition. Attention is focused on the subject of stability, and pertinent existing results are summarized and discussed. Details of the derivation of three-dimensional stability criteria for thermohaline convection with linear gradients are presented. Ten key questions pertaining to stability are posed, whose answers must be sought through extensive analytical and numerical studies. Possible methods of approach toward enhancing solar-pond stability are also discussed. For the numerical studies of pond behavior and stability characteristics, a double-diffusive convection model is proposed. The model can be constructed by extending the three-dimensional thermohydrodynamic computer code COMMIX-SA, following the necessary steps outlined; computational plans are described. Similarities exist between the halothermocline and the thermocline storage systems, and an extended COMMIX-SA will be a valuable tool for the investigation of both.

  3. A THEORETICAL AND NUMERICAL STUDY OF THERMOSOLUTAL CONVECTION: STABILITY OF A SALINITY GRADIENT SOLAR POND

    Directory of Open Access Journals (Sweden)

    Djamel Kalache

    2011-01-01

    Full Text Available A theoretical and numerical study of the effect of thermodiffusion on the stability of a gradient layer is presented. It intends to clarify the mechanisms of fluid dynamics and the processes which occur in a salinity gradient solar pond. A mathematical modelling is developed to describe the thermodiffusion contribution on the solar pond where thermal, radiative, and massive fluxes are coupled in the double diffusion. More realistic boundary conditions for temperature and concentration profiles are used. Our results are compared with those obtained experimentally by authors without extracting the heat flux from the storage zone. We have considered the stability analysis of the equilibrium solution. We assumed that the perturbation of quantities such as velocity, temperature, and concentration are infinitesimal. Linearized equations satisfying appropriate prescribed boundary conditions are then obtained and expanded into polynomials form. The Galerkin method along with a symbolic algebra code (Maple are used to solve these equations. The effect of the separation coefficient y is analyzed in the positive and negative case. We have also numerically compared the critical Rayleigh numbers for the onset of convection with those obtained by the linear stability analysis for Le = 100, µa = 0.8, and f = 0.5.

  4. A Two-Dimensional Numerical Study of Hydrodynamic, Heat and Mass Transfer and Stability in a Salt Gradient Solar Pond

    Directory of Open Access Journals (Sweden)

    Ali Ben Moussa

    2012-10-01

    Full Text Available In this work, the problem of hydrodynamic, heat and mass transfer and stability in a salt gradient solar pond has been numerically studied by means of computational fluid dynamics in transient regime. The body of the simulated pond is an enclosure of height H and length L wherein an artificial salinity gradient is created in order to suppress convective motions induced by solar radiation absorption and to stabilize the solar pond during the period of operation. Here we show the distribution of velocity, temperature and salt concentration fields during energy collection and storage in a solar pond filled with water and constituted by three different salinity zones. The bottom of the pond is blackened and the free-surface is subjected to heat losses by convection, evaporation and radiation while the vertical walls are adiabatic and impermeable. The governing equations of continuity, momentum, thermal energy and mass transfer are discretized by finite–volume method in transient regime. Velocity vector fields show the presence of thin convective cells in the upper convective zone (UCZ and large convective cells in the lower convective zone (LCZ. This study shows the importance of buoyancy ratio in the decrease of temperature in the UCZ and in the preservation of high temperature in the LCZ. It shows also the importance of the thickness of Non-Convective Zone (NCZ in the reduction of the upwards heat losses.

  5. Microbiology of solar salt ponds

    Science.gov (United States)

    Javor, B.

    1985-01-01

    Solar salt ponds are shallow ponds of brines that range in salinity from that of normal seawater (3.4 percent) through NaCl saturation. Some salterns evaporate brines to the potash stage of concentration (bitterns). All the brines (except the bitterns, which are devoid of life) harbor high concentrations of microorganisms. The high concentrations of microorganisms and their adaptation to life in the salt pond are discussed.

  6. Solar pond conception - experimental and theoretical studies

    Energy Technology Data Exchange (ETDEWEB)

    Kurt, Huseyin [Zonguldak Karaelmas Univ., Technical Education Faculty, Karabuk (Turkey); Halici, Fethi [Sakarya Univ., Mechanical Engineering Dept., Adapazari (Turkey); Binark, A. Korhan [Marmara Univ., Technical Education Faculty, Istanbul (Turkey)

    2000-07-01

    A one dimensional transient mathematical model for predicting the thermal performance of the salt gradient solar pond is developed and presented. In this paper, the natural solar ponds and different artificial solar pond systems found in the literature are introduced. Necessary modifications are made on the experimental stand located in Istanbul Technical University, the experimental stand is introduced and natural phenomena produced in the pond by the different solar pond variations under natural conditions are observed. In the theoretical work based on a one dimensional unsteady state heat conduction model with internal heat generation, the energy and mass balance equations for the upper convective zone, the non-convective zone and the lower convective zone, all of which form the solar pond, are written in terms of differential equations. These equations are solved analytically and numerically. The results obtained from the analysis are compared with the experimental results. The temperature and the concentration profiles are separately presented in the figures. (Author)

  7. Solar pond for heating anaerobic digesters

    International Nuclear Information System (INIS)

    Song Kehui; Li Shensheng

    1991-10-01

    A theoretical analysis and numerical results calculated for solar pond heating anaerobic digesters in Beijing area in China are presented. The effect of temperature rise is evident and rather steady. 3 refs, 1 fig., 1 tab

  8. Solar pond design for Arabian Gulf conditions

    Energy Technology Data Exchange (ETDEWEB)

    Hassab, M.A.; Tag, I.A.; Jassim, I.A.; Al-Juburi, F.Y.

    1987-01-01

    Collection and storage of solar energy in salt gradient solar ponds under conditions of high ambient and ground temperatures and all year-round sunny weather are investigated theoretically. A transient model based on measured local environmental conditions is developed to predict solar transmission, temperature distribution and salt distribution inside the pond for any day of the year. In the model the effects of heat dissipation into the ground, bottom reflection, pond dimensions, load extraction and variation of the pond's physical properties with temperature and concentration are investigated. The generated non-linear coupled system of heat and salt concentration equations for the composite media, considered to have isothermal boundary conditions, is solved numerically using the implicit finite-difference scheme.

  9. Investigation of turbidity effect on exergetic performance of solar ponds

    International Nuclear Information System (INIS)

    Atiz, Ayhan; Bozkurt, Ismail; Karakilcik, Mehmet; Dincer, Ibrahim

    2014-01-01

    Highlights: • A comprehensive experimental work on a turbidity of the solar pond. • Percentage transmission evaluation of the turbid and clean salty water of the zones. • Exergy analysis of the inner zones for turbid and clean salty water. • Turbidity effect on exergy efficiencies of the solar pond. • The thermal performance assessment by comparing the exergetic efficiencies of the solar pond. - Abstract: The present paper undertakes a study on the exergetic performance assessment of a solar pond and experimental investigation of turbidity effect on the system performance. There are various types of solar energy applications including solar ponds. One of significant parameters to consider in the assessment of solar pond performance is turbidity which is caused by dirty over time (e.g., insects, leaf, dust and wind bringing parts fall down). Thus, the turbidity in the salty water decreases solar energy transmission through the zones. In this study, the samples are taken from the three zones of the solar pond and analyzed using a spectrometer for three months. The transmission aspects of the solar pond are investigated under calm and turbidity currents to help distinguish the efficiencies. Furthermore, the maximum exergy efficiencies are found to be 28.40% for the calm case and 22.27% with turbidity effects for the month of August, respectively. As a result, it is confirmed that the solar pond performance is greatly affected by the turbidity effect

  10. Dewatering and RCRA partial closure action on solar evaporation ponds, Rocky Flats Plant, Golden, Colorado

    International Nuclear Information System (INIS)

    1991-06-01

    The Department of Energy (DOE) has prepared an Environmental Assessment (DOE/EA-0487) on its proposal to partially close five solar evaporation ponds at the Rocky Flats Plant (RFP) pursuant to the requirements of the Resource Conservation and Recovery Act (RCRA). This proposal would be known as a RCRA partial closure and would be accomplished by dewatering the ponds, where necessary, and converting any remaining sludge or evaporator concentrate to a solid wasteform (pondcrete and saltcrete). The pond sites would be stabilized to prevent erosion or other disturbance to the soil and to prevent infiltration of rain or snowmelt. The solid wasteform would be transported offsite for disposal. The five solar ponds (designated 207-A, 207-B (north, center, and south), and 207-C), are the only solar evaporation ponds that exist at the RFP. A finding of no significant impact is included

  11. Heat recovery from ground below the solar pond

    NARCIS (Netherlands)

    Ganguly, S.; Date, Abhijit; Akbarzadeh, Aliakbar

    2017-01-01

    The method of heat recovery from the ground below solar ponds is investigated in the present brief note. Solar ponds lose considerable amount of heat from its bottom to the ground due to temperature gradient between them. This waste heat from ground, which is at different temperature at different

  12. Modeling Nitrogen Decrease in Water Lettuce Ponds from Waste Stabilization Ponds

    Science.gov (United States)

    Putri, Gitta Agnes; Sunarsih

    2018-02-01

    This paper presents about the dynamic modeling of the Water Lettuce ponds as a form of improvement from the Water Hyacinth ponds. The purpose of this paper is to predict nitrogen decrease and nitrogen transformation in Water Lettuce ponds integrated with Waste Stabilization Ponds. The model consists of 4 mass balances, namely Dissolved Organic Nitrogen (DON), Particulate Organic Nitrogen (PON), ammonium (NH4+), Nitrate and Nitrite (NOx). The process of nitrogen transformation which considered in a Water Lettuce ponds, namely hydrolysis, mineralization, nitrification, denitrification, plant and bacterial uptake processes. Numerical simulations are performed by giving the values of parameters and the initial values of nitrogen compounds based on a review of previous studies. Numerical results show that the rate of change in the concentration of nitrogen compounds in the integration ponds of waste stabilization and water lettuce decreases and reaches stable at different times.

  13. EXPERIMENTAL INVESTIGATION OF SOLAR POND PERFORMANCE IN KARABUK ENVIRONMENT

    Directory of Open Access Journals (Sweden)

    Mehmet ÖZKAYMAK

    2004-01-01

    Full Text Available The solar energy, one of the alternative energy sources, can be economically and cheaply and efficiently collected with solar ponds. In this study, varying concentrations of sodium carbonate dilution in the solar pond in terms of heat storage performance has been examined. Experiment apparatus has been located Zonguldak Karaelmas University Karabük Technical Education Faculty. Five experiments with different density levels have been done and the changes in the temperature and density have been presented graphically within the solar pond. The experiments show that the temperature difference between the bottom and top level of solar pond is max. 21 °C and the highest temperature in lower convective zone (LCZ has been measured as 49 °C.

  14. Observations of the transmittance in two solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Almanza, R.; Bryant, M.C.

    1983-11-01

    A NaCl salt gradient solar pond has been in continuous operation at the University of New Mexico since the fall of 1975; a smaller pond, using KNO/sub 3/ to produce the salinity gradient, was commissioned in the fall of 1981. The distribution of absorbed radiation in the ponds is of key importance in the determination of their efficiencies for collecting and storing solar energy. The absorption coefficient of light in an aqueous solution is very dependent upon wavelength; the spectral distribution of sunlight shifts toward the blue and the amount of solar energy absorbed per unit length of path declines with depth of penetration. The presence of suspended solids and bioforms further complicate the transmittance of sun light through the pond, specially since this contamination tends to vary strongly with depth. Because of its importance to the phytoplankton population , considerable work has been done by oceanographers on the absorption and scattering of light for different wavelengths. However, in a solar pond the big question is the amount of energy reaching the lower convective layer (storage). Several attempts have been made to measure the transmittance in solar ponds, mainly NaCl but the problem is to find a temperature-insensitive submersible pyranometer. Convenient formulas have been offered for the attenuation of solar radiation in pond water by considering it to be divided into spectral bands, or by fitting simple analytical functions, or specifying the extintion coefficient. (For the first method, it is necessary to know the absorption and scattering of light for different lambda.) In this paper some measurements of transmittance in the UNM ponds, are presented thereby exhibiting a simple procedure which may be of interest to others in this field.

  15. A Closer Look on Spatiotemporal Variations of Dissolved Oxygen in Waste Stabilization Ponds Using Mixed Models

    Directory of Open Access Journals (Sweden)

    Long Ho

    2018-02-01

    Full Text Available Dissolved oxygen is an essential controlling factor in the performance of facultative and maturation ponds since both take many advantages of algal photosynthetic oxygenation. The rate of this photosynthesis strongly depends on the time during the day and the location in a pond system, whose roles have been overlooked in previous guidelines of pond operation and maintenance (O&M. To elucidate these influences, a linear mixed effect model (LMM was built on the data collected from three intensive sampling campaigns in a waste stabilization pond in Cuenca, Ecuador. Within two parallel lines of facultative and maturation ponds, nine locations were sampled at two depths in each pond. In general, the output of the mixed model indicated high spatial autocorrelations of data and wide spatiotemporal variations of the oxygen level among and within the ponds. Particularly, different ponds showed different patterns of oxygen dynamics, which were associated with many factors including flow behavior, sludge accumulation, algal distribution, influent fluctuation, and pond function. Moreover, a substantial temporal change in the oxygen level between day and night, from zero to above 20 mg O2·L−1, was observed. Algal photosynthetic activity appeared to be the main reason for these variations in the model, as it was facilitated by intensive solar radiation at high altitude. Since these diurnal and spatial patterns can supply a large amount of useful information on pond performance, insightful recommendations on dissolved oxygen (DO monitoring and regulations were delivered. More importantly, as a mixed model showed high predictive performance, i.e., high goodness-of-fit (R2 of 0.94, low values of mean absolute error, we recommended this advanced statistical technique as an effective tool for dealing with high autocorrelation of data in pond systems.

  16. Heating an aquaculture pond with a solar pool blanket

    Energy Technology Data Exchange (ETDEWEB)

    Wisely, B; Holliday, J E; MacDonald, R E

    1982-01-01

    A floating solar blanket of laminated bubble plastic was used to heat a 0.11 ha seawater pond of 1.3 m depth. The covered pond maintained daily temperatures 6 to 9/sup 0/C above two controls. Local air temperatures averaged 14 to 19/sup 0/C. Oysters, prawns, seasquirts, and fish in the covered pond all survived. After three weeks, the blanket separated. This was the result of pond temperatures exceeding 30/sup 0/C, the maximum manufacturer's specification. Floating blankets fabricated to higher specifications would be useful for maintaining above-ambient temperatures in small ponds or tanks in temporary situations during cold winter months and might have a more permanent use.

  17. Waste Stabilization Ponds and Aerated Lagoons Performance in Removal of Wastewater Indicator Microorganisms

    Directory of Open Access Journals (Sweden)

    Seyed ali Ghasemi

    2013-08-01

    Full Text Available In this work, the performance of two treatment plants in the City of Mashhad, one with an aerated lagoons system and the other one with waste stabilization ponds system were evaluated in regard to their efficiency in reduction of pathogenic microorganisms. For this purpose, over a period of one year (with 15-days intervals, samples were taken from the influent and effluent (prior to disinfection unit of the above mentioned treatment plants. The samples then were analyzed for parameters such as temperature, pH, density of total coliforms (TC and fecal coliforms (FC, dissolved oxygen and total suspended solids concentration. The results indicated that the aerated lagoons system was much more efficient in removal of indicator bacteria than the waste stabilization ponds during autumn and winter periods. However during the summer months, the waste stabilization ponds showed a higher efficiency in this regard. In general, the waste stabilization ponds system reduced the density of TC and FC by 0.21-2.15 log10 and 0.20-2.33 log10, respectively. In contrast, the levels of reduction in aerated lagoons system were in the range of 0.29-2.03 log10 for TC and 0.42-2.40 log10 for FC. Results indicated that solar intensity, pH and dissolved oxygen concentration were found to be the most significant parameters that reduced the microorganisms population in waste stabilization ponds, While, in the aerated lagoons system, the dissolved oxygen concentration in aerated basin and solar intensity play the most important role. In general, without receiving an adequate disinfection, the effluent from waste stabilization ponds and aerated lagoons cannot provide the microbiological standards required for irrigation of agricultural crops.

  18. Greenhouse heating with a fresh water floating collector solar pond

    International Nuclear Information System (INIS)

    Arbel, A.; Sokolov, M.

    1991-01-01

    The fresh water floating collector solar pond was investigated both experimentally and theoretically in a previous work, and it is now matched, by simulation, with the heat load requirements of a greenhouse. Results of the simulation indicate that such a pond is a potential energy source for greenhouse heating. This is especially true when the material properties are such that solar absorption and storage are enhanced. This paper reports that to demonstrate this point, three sets of collectors constructed with materials of different physical (radiation) properties were tested. One set is constructed of common materials which are readily available and are normally used as covers for greenhouses. The second set made of improved materials which are also available but have a smaller long-wave transmittance. The last set made of ideal material which additionally possesses selective radiation absorption properties. Collectors made of ideal materials make a superior solar pond; thus, manufacturing films with improved properties should become a worthwhile challenge for the agricultural polyethylene-films industry. Preliminary economic studies indicate that even with the low oil (<$20/Bbl) prices which exist between 1986-1989, the fresh water floating collectors solar pond provides an economically attractive alternative to the conventional oil-burning heating system. This is especially true in mild climate areas and when the large initial investment is justified by long-term greenhouse utilization planning

  19. Performance of municipal waste stabilization ponds in the Canadian Arctic

    DEFF Research Database (Denmark)

    Ragush, Colin M.; Schmidt, Jordan J.; Krkosek, Wendy H.

    2015-01-01

    The majority of small remote communities in the Canadian arctic territory of Nunavut utilize waste stabilization ponds (WSPs) for municipal wastewater treatment because of their relatively low capital and operational costs, and minimal complexity. New national effluent quality regulations have be...

  20. Performance Of The Akosombo Waste Stabilization Ponds In Ghana ...

    African Journals Online (AJOL)

    A study was conducted to determine the treatment performance of the Akosombo waste stabilization ponds and the effect of seasonal changes on the final effluent quality. The waste water quality parameters ... Une étude était entreprise pour déterminer le résultat de traitement de bassins de stabilisation du déchet d' ...

  1. On the addition of heat to solar pond from external sources

    NARCIS (Netherlands)

    Ganguly, S.; Jain, Ravi; Date, Abhijit; Akbarzadeh, Aliakbar

    2017-01-01

    This brief note addresses the method of adding heat to a solar pond from an external source which is used to enhance the performance of a solar pond. Heat energy collected by Evacuated Tube Solar Collectors (ETSC) is transferred by circulating fluid from the Lower Convective Zone (LCZ) of a solar

  2. The effect of sunny area ratios on the thermal performance of solar ponds

    International Nuclear Information System (INIS)

    Bozkurt, Ismail; Karakilcik, Mehmet

    2015-01-01

    Highlights: • The effect of sunny area ratio on model solar ponds in different geometries. • The sunny area ratio was calculated for 8 different cases. • The efficiency of the model solar pond was determined for 8 different cases. • The energy efficiencies of the solar pond are affected by the sizes of the solar pond, strongly. • The results help to select the sizes of the solar pond before construction. - Abstract: In this study, we investigated the effect of the sunny area ratios on thermal efficiency of model solar pond for different cases in Adiyaman, Turkey. For this purpose, we modeled the solar ponds to compute theoretical sunny area ratios of the zones and temperature distributions in order to find the performance of the model solar ponds. Incorporating the finite difference approach, one and two dimensional heat balances were written for inner zones and insulation side walls. Through, careful determination of the dimensions, insulation parameter and incoming solar radiation reaching the storage zone increased the efficiency of the solar pond. The efficiencies of the model solar pond were determined for case1a–2a–3a–4a to be maximum 14.93%, 20.42%, 23.51% and 27.84%, and for case1b–2b–3b–4b to be maximum 12.65%, 16.76%, 21.37% and 23.30% in August, respectively. With the increase of the sunny area ratio, the performance of the solar pond significantly increased. However, with the increasing rate of the surface area, performance increase rate decreased gradually. The results provide a strong perspective to determine the dimensions of the solar pond before starting the project of a solar pond

  3. A mathematical procedure to estimate solar absorptance of shallow water ponds

    International Nuclear Information System (INIS)

    Wu Hongbo; Tang Runsheng; Li Zhimin; Zhong Hao

    2009-01-01

    In this article, a mathematical procedure is developed for estimating solar absorption of shallow water ponds with different pond floor based on the fact that the solar radiation trapped inside the water layer undergoes multiplicative reflection and absorption and on that the solar absorption of water is selective. Theoretical model indicates that the solar absorption of a water pond is related to the reflectivity of the pond floor, the solar spectrum and the water depth. To validate the mathematical model, a concrete water pond measuring 3 x 3 x 0.24 m was constructed. Experimental results indicate that solar reflectivity calculated based on the mathematical model proposed in this work were in good agreement with those measured. For water ponds with a water-permeable floor, such as concrete floor, theoretical calculations of the solar absorptance of a water pond should be done based on the reflectivity of full wet floor, whereas for water ponds with a non-water-permeable floor, theoretical calculations should be done based on the fact that solar reflection on the floor is neither perfect specular reflection nor prefect isotropic diffuse reflection. Results of numerical calculation show that theoretical calculations of solar absorption of a water pond by dividing solar spectrum into six bands were pretty agreement with those by dividing solar spectrum into 20 bands.

  4. Using nanofluids in enhancing the performance of a novel two-layer solar pond

    International Nuclear Information System (INIS)

    Al-Nimr, Moh'd A.; Al-Dafaie, Ameer Mohammed Abbas

    2014-01-01

    A novel two-layer nanofluid solar pond is introduced. A mathematical model that describes the thermal performance of the pond has been developed and solved. The upper layer of the pond is made of mineral oil and the lower layer is made of nanofluid. Nanofluid is known to be an excellent solar radiation absorber, and this has been tested and verified using the mathematical model. Using nanofluid will increase the extinction coefficient of the lower layer and consequently will improve the thermal efficiency and the storage capacity of the pond. The effects of other parameters have been also investigated. - Highlights: • A novel two-layer solar pond is discussed. • Nanofluid as thermal energy storage is used in this pond. • A mathematical model is developed to predict the performance of the pond. • The mathematical model is solved using Green's function. • The pond is simulated for different values of governing parameter

  5. Renewable water: Direct contact membrane distillation coupled with solar ponds

    International Nuclear Information System (INIS)

    Suárez, Francisco; Ruskowitz, Jeffrey A.; Tyler, Scott W.; Childress, Amy E.

    2015-01-01

    Highlights: • Experimental investigation of direct contact membrane distillation driven by solar ponds. • The DCMD/SGSP system treats ∼6 times the water flow treated by an AGMD/SGSP system. • Half of the energy extracted from the SGSP was used to transport water across the membrane. • Reducing heat losses through the DCMD/SGSP system would yield higher water fluxes. - Abstract: Desalination powered by renewable energy sources is an attractive solution to address the worldwide water-shortage problem without contributing significant to greenhouse gas emissions. A promising system for renewable energy desalination is the utilization of low-temperature direct contact membrane distillation (DCMD) driven by a thermal solar energy system, such as a salt-gradient solar pond (SGSP). This investigation presents the first experimental study of fresh water production in a coupled DCMD/SGSP system. The objectives of this work are to determine the experimental fresh water production rates and the energetic requirements of the different components of the system. From the laboratory results, it was found that the coupled DCMD/SGSP system treats approximately six times the water flow treated by a similar system that consisted of an air–gap membrane distillation unit driven by an SGSP. In terms of the energetic requirements, approximately 70% of the heat extracted from the SGSP was utilized to drive thermal desalination and the rest was lost in different locations of the system. In the membrane module, only half of the useful heat was actually used to transport water across the membrane and the remainder was lost by conduction in the membrane. It was also found that by reducing heat losses throughout the system would yield higher water fluxes, pointing out the need to improve the efficiency throughout the DCMD/SGSP coupled system. Therefore, further investigation of membrane properties, insulation of the system, or optimal design of the solar pond must be addressed in

  6. A comparison between evaporation ponds and evaporation surfaces as a source of the concentrated salt brine for salt gradient maintenance at Tajoura solar pond

    International Nuclear Information System (INIS)

    Ramadan, Abdulghani M.; Agha, Khairy R.; Abughres, M.

    2012-01-01

    One of the main problems that negatively affect the operation of salt gradient solar ponds and influence its thermal stability is the maintenance of salt gradient profile. Evaporation pond (EP) is designed to generate the salt which lost upward salt diffusion from the lower convective zone (LCZ) of the solar pond. Another attractive method is the evaporation surface facility (ES). Regions with moderate to high precipitation favor Evaporation Surface over Evaporation Ponds. Dry climates will generally favor Evaporation Ponds for the brine re-concentration. In previous studies [1-3], the authors have shown that the (EP) of Tajoura's Experimental Solar Pond (TESP) is under sized and can provide only about 30% of the salt required by a Salt Gradient Solar Pond (SGSP). The anticipated size of (EP) was estimated and presented in those studies under different design conditions, including Summer, Autumn and Spring designs, while the winter design was excluded due to the low rates of net evaporation during the winter season. In addition, the results presented were predicted for the first three years of operation. The daily variations of brine concentration in the (EP) of (TESP) and those based on different designs were predicted and discussed under different scenarios. The quantities of brine provided by the evaporation pond and that required by SGSP were predicted for both cases of surface water flushing (fresh water and sea-water) under the different design conditions as shown in Table 1. This paper investigates the differences between (EP) and (ES) both as a source for salt brine generation by evaporation. The effect of (EP) depth on the area ratio and daily variations of salt concentrations for three years of operation is shown. Results show that evaporation can be a reasonable method for salt brine generation. Reducing the depth of (EP) improves the capability of (EP) for brine re-concentration. It also increases the (EP) surface area for the same quantity of

  7. An experimental and theoretical investigation of novel configurations of solar ponds for use in Iraq.

    OpenAIRE

    Sayer, Asaad Hameed

    2017-01-01

    Solar energy is likely to be the energy of the future; solar ponds, especially salinity gradient solar ponds (SGSPs), facilitate simple and cost-effective thermal energy storage. Research on maximising their potential is of particular relevance to developing countries, which often have an abundance of solar energy and a critical need for increased power supplies. For this research, a theoretical model for heat transfer in a SGSP was developed to study the energy balance in the three separate ...

  8. Facultative Stabilization Pond: Measuring Biological Oxygen Demand using Mathematical Approaches

    Science.gov (United States)

    Wira S, Ihsan; Sunarsih, Sunarsih

    2018-02-01

    Pollution is a man-made phenomenon. Some pollutants which discharged directly to the environment could create serious pollution problems. Untreated wastewater will cause contamination and even pollution on the water body. Biological Oxygen Demand (BOD) is the amount of oxygen required for the oxidation by bacteria. The higher the BOD concentration, the greater the organic matter would be. The purpose of this study was to predict the value of BOD contained in wastewater. Mathematical modeling methods were chosen in this study to depict and predict the BOD values contained in facultative wastewater stabilization ponds. Measurements of sampling data were carried out to validate the model. The results of this study indicated that a mathematical approach can be applied to predict the BOD contained in the facultative wastewater stabilization ponds. The model was validated using Absolute Means Error with 10% tolerance limit, and AME for model was 7.38% (< 10%), so the model is valid. Furthermore, a mathematical approach can also be applied to illustrate and predict the contents of wastewater.

  9. EXPERIMENTAL INVESTIGATION OF HEAT STORAGE CHARACTERISTIC OF UREA AND BORAX SALT GRADIENT SOLAR PONDS

    Directory of Open Access Journals (Sweden)

    Hüseyin KURT

    2006-03-01

    Full Text Available Salt gradient solar ponds are simple and low cost solar energy system for collecting and storing solar energy. In this study, heat storage characteristic of urea and borax solutions in the solar pond were examined experimentally. Establishing density gradients in different concentration, variations in the temperature and density profiles were observed in four different experiments. Maximum storage temperatures were measured as 28ºC and 36 ºC for the ponds with urea and borax solution, respectively. The temperature difference between the bottom and the surface of the pond were measured as 13 ºC for urea and 17 ºC for borax- solutions. According to these results, heat storage characteristic of the solar pond with borax solution was found to be better than urea solution.

  10. Design and Application of a Solar Mobile Pond Aquaculture Water Quality-Regulation Machine Based in Bream Pond Aquaculture.

    Science.gov (United States)

    Liu, Xingguo; Xu, Hao; Ma, Zhuojun; Zhang, Yongjun; Tian, Changfeng; Cheng, Guofeng; Zou, Haisheng; Lu, Shimin; Liu, Shijing; Tang, Rong

    2016-01-01

    Bream pond aquaculture plays a very important role in China's aquaculture industry and is the main source of aquatic products. To regulate and control pond water quality and sediment, a movable solar pond aquaculture water quality regulation machine (SMWM) was designed and used. This machine is solar-powered and moves on water, and its primary components are a solar power supply device, a sediment lifting device, a mechanism for walking on the water's surface and a control system. The solar power supply device provides power for the machine, and the water walking mechanism drives the machine's motion on the water. The sediment lifting device orbits the main section of the machine and affects a large area of the pond. Tests of the machine's mechanical properties revealed that the minimum illumination necessary for the SMWM to function is 13,000 Lx and that its stable speed on the water is 0.02-0.03 m/s. For an illumination of 13,000-52,500 Lx, the sediment lifting device runs at 0.13-0.35 m/s, and its water delivery capacity is 110-208 m(3)/h. The sediment lifting device is able to fold away, and the angle of the suction chamber can be adjusted, making the machine work well in ponds at different water depths from 0.5 m to 2 m. The optimal distance from the sediment lifting device to the bottom of the pond is 10-15 cm. In addition, adjusting the length of the connecting rod and the direction of the traction rope allows the SMWM to work in a pond water area greater than 80%. The analysis of water quality in Wuchang bream (Parabramis pekinensis) and silver carp (Hypophthalmichthys molitrix) culture ponds using the SMWM resulted in decreased NH3(+)-N and available phosphorus concentrations and increased TP concentrations. The TN content and the amount of available phosphorus in the sediment were reduced. In addition, the fish production showed that the SMWM enhanced the yields of Wuchang bream and silver carp by more than 30% and 24%, respectively. These results

  11. Performance investigation of a salt gradient solar pond coupled with desalination facility near the Dead Sea

    International Nuclear Information System (INIS)

    Saleh, A.; Qudeiri, J.A.; Al-Nimr, M.A.

    2011-01-01

    Solar ponds provide the most convenient and least expensive option for heat storage for daily and seasonal cycles. This is particularly important for a desalination facility, if steady and constant water production is required. If, in addition to high storage capacity, other favorable conditions exist, the salt gradient solar ponds (SGSPs) are expected to be able to carry the entire load of a large-scale flash desalination plants without dependence upon supplementary sources. This paper presents a performance investigation of a SGSP coupled with desalination plant under Jordanian climatic conditions. This is particularly convenient in the Dead Sea region characterized by high solar radiation intensities, high ambient temperature most of the year, and by the availability of high concentration brine. It was found that a 3000 m 2 solar pond installed near the Dead Sea is able to provide an annual average production rate of 4.3 L min -1 distilled water compared with 3.3 L min -1 that would be produced by El Paso solar pond, which has the same surface area. Based on this study, solar ponds appear to be a feasible and an appropriate technology for water desalination near the Dead Sea in Jordan. -- Research highlights: → A performance investigation of a solar pond coupled with desalination plant. → Dead Sea area is characterized by availability of high solar radiation and brine. → The Dead Sea solar pond can provide production rate of 4.3 L min -1 . → El Paso solar pond has production rate of 3.32 L min -1 . The improvement is about 30%. → The solar pond with desalination investigated showed to be a feasible technology.

  12. Passive flow heat exchanger simulation for power generation from solar pond using thermoelectric generators

    Science.gov (United States)

    Baharin, Nuraida'Aadilia; Arzami, Amir Afiq; Singh, Baljit; Remeli, Muhammad Fairuz; Tan, Lippong; Oberoi, Amandeep

    2017-04-01

    In this study, a thermoelectric generator heat exchanger system was designed and simulated for electricity generation from solar pond. A thermoelectric generator heat exchanger was studied by using Computational Fluid Dynamics to simulate flow and heat transfer. A thermoelectric generator heat exchanger designed for passive in-pond flow used in solar pond for electrical power generation. A simple analysis simulation was developed to obtain the amount of electricity generated at different conditions for hot temperatures of a solar pond at different flow rates. Results indicated that the system is capable of producing electricity. This study and design provides an alternative way to generate electricity from solar pond in tropical countries like Malaysia for possible renewable energy applications.

  13. Sulfur bacteria in wastewater stabilization ponds periodically affected by the ‘red-water’ phenomenon

    NARCIS (Netherlands)

    Belila, A.; Abbas, B.; Fazaa, I.; Saidi, N.; Snoussi, M.; Hassen, A.; Muyzer, G.

    2012-01-01

    Several wastewater stabilization ponds (WSP) in Tunisia suffer periodically from the ‘red-water’ phenomenon due to blooming of purple sulfur bacteria, indicating that sulfur cycle is one of the main element cycles in these ponds. In this study, we investigated the microbial diversity of the El

  14. Sulfur bacteria in wastewater stabilization ponds periodically affected by the 'red-water' phenomenon

    NARCIS (Netherlands)

    Belila, A.; Abbas, B.; Fazaa, I.; Saidi, N.; Snoussi, M.; Hassen, A.; Muyzer, G.

    2013-01-01

    Several wastewater stabilization ponds (WSP) in Tunisia suffer periodically from the ‘red-water’ phenomenon due to blooming of purple sulfur bacteria, indicating that sulfur cycle is one of the main element cycles in these ponds. In this study, we investigated the microbial diversity of the El

  15. Solar Pond Potential as A New Renewable Energy in South Sulawesi

    Science.gov (United States)

    Fadliah Baso, Nur; Chaerah Gunadin, Indar; Yusran

    2018-03-01

    Renewable energy sources need to be developed to maintain the electric energy availability by utilizing oceanic energy, namely solar pond energy. This energy is highly influenced by several factors including salinity, air temperature and solar radiation. This study was focused on finding the potential of solar pond in South Sulawesi, a region with fairly high solar radiation and abundant salt water raw materials availability. The method used in this study was analyzing the values from the mathematic models of daily horizontal solar radiation, air temperature, wind speed, relative humidity and atmospheric pressure for the last 22 years which were finalized using MATLAB. The findings of this study will show the areas with good potentials to apply solar pond in South Sulawesi that can be utilized in various fields including power generator, industrial heating process, desalination and heating for biomass conversion.

  16. Assessment of waste stabilization ponds (WSP) efficiency on ...

    African Journals Online (AJOL)

    This stage is essential for polishing water and nutrient as well as pathogen removal. There is need of frequent awareness campaign to a community for the reuse of wastewater for agriculture and its possible impacts. Ponds should be modified and addition of maturation ponds constructed. Further studies are required for ...

  17. Environmental sampling program for a solar evaporation pond for liquid radioactive wastes

    International Nuclear Information System (INIS)

    Romero, R.; Gunderson, T.C.; Talley, A.D.

    1980-04-01

    Los Alamos Scientific Laboratory (LASL) is evaluating solar evaporation as a method for disposal of liquid radioactive wastes. This report describes a sampling program designed to monitor possible escape of radioactivity to the environment from a solar evaporation pond prototype constructed at LASL. Background radioactivity levels at the pond site were determined from soil and vegetation analyses before construction. When the pond is operative, the sampling program will qualitatively and quantitatively detect the transport of radioactivity to the soil, air, and vegetation in the vicinity. Possible correlation of meteorological data with sampling results is being investigated and measures to control export of radioactivity by biological vectors are being assessed

  18. Use of clays as liners in solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Gerardo [Facultad de Ingenieria, Universidad Anahuac Mexico Norte, Huixquilucan, Edo. de Mexico 52786 (Mexico); Almanza, Rafael [Instituto de Ingenieria, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, Mexico D.F. 04510 (Mexico)

    2009-06-15

    An alternative to synthetic materials for use in solar pond liners is to select clayey soils as hydraulic barriers. This option reduces the cost of construction and the risk of contamination of subsoil and groundwater by hot brines. This paper deals with the physical, chemical and hydraulic properties of different soils tested mainly as compacted clay liners. The underdeveloped nations have the option to use this type of liner, but before doing so several tests are recommended, including those for soil and water composition, permeability, plasticity and X-ray diffraction analysis. In this investigation the following samples are analyzed: native clayey soils with illite, montmorillonite and halloysite, treated and non-treated bentonites in powder and granulated form, a mixture of zeolite and sodium bentonite, and industrial minerals composed largely of halloysite, kaolinite and attapulgite selected clays. Neutral salt aqueous solutions (NaCl and KCl) at different concentrations and under temperature gradients were used for compatibility testing conducted on these specimens. Experiment setup and particular testing procedures are also discussed. (author)

  19. Disinfection of stabilization pond effluent by peracetic acid and sodium hypochlorite

    Directory of Open Access Journals (Sweden)

    Negar Rezania

    2013-01-01

    Conclusions: The study demonstrated that application of combined PAA and NaOCl in disinfecting the effluent of the stabilization pond will promote the efficiency of disinfection process in inactivating the coliform group bacteria and fecal streptococci.

  20. Further contributions to the understanding of nitrogen removal in waste stabilization ponds.

    Science.gov (United States)

    Bastos, R K X; Rios, E N; Sánchez, I A

    2018-06-01

    A set of experiments were conducted in Brazil in a pilot-scale waste stabilization pond (WSP) system (a four-maturation-pond series) treating an upflow anaerobic sludge blanket (UASB) reactor effluent. Over a year and a half the pond series was monitored under two flow rate conditions, hence also different hydraulic retention times and surface loading rates. On-site and laboratory trials were carried out to assess: (i) ammonia losses by volatilization using acrylic capture chambers placed at the surface of the ponds; (ii) organic nitrogen sedimentation rates using metal buckets placed at the bottom of the ponds for collecting settled particulate matter; (iii) nitrogen removal by algal uptake based on the nitrogen content of the suspended particulate matter in samples from the ponds' water column. In addition, nitrification and denitrification rates were measured in laboratory-based experiments using pond water and sediment samples. The pond system achieved high nitrogen removal (69% total nitrogen and 92% ammonia removal). The average total nitrogen removal rates varied from 10,098 to 3,849 g N/ha·d in the first and the last ponds, respectively, with the following fractions associated with the various removal pathways: (i) 23.5-45.6% sedimentation of organic nitrogen; (ii) 13.1-27.8% algal uptake; (iii) 1.2-3.1% ammonia volatilization; and (iv) 0.15-0.34% nitrification-denitrification.

  1. Regional applicability and potential of salt-gradient solar ponds in the United States. Volume 2: Detailed report

    Science.gov (United States)

    Lin, E. I. H.

    1982-03-01

    A comprehensive assessment of the regional applicability and potential of salt-gradient solar ponds in the United States is provided. The assessment is focused on the general characteristics of twelve defined geographic regions. Natural resources essential to solar ponds are surveyed. Meteorological and hydrogeological conditions affecting pond performance are examined. Potentially favorable pond sites are identified. Regional thermal and electrical energy output from solar ponds is calculated. Selected pond design cases are studied. Five major potential market sectors are evaluated in terms of technical and energy-consumption characteristics, and solar-pond applicability and potential. Relevant pond system data and financial factors are analyzed. Solar-pond energy costs are compared with conventional energy costs. The assessment concludes that, excepting Alaska, ponds are applicable in all regions for at least two market sectors. Total solar pond energy supply potential in the five market sectors examined is estimated to be 8.94 quads/yr by the year 2000, approximately 7.2% of the projected total national energy demand.

  2. Study for reclamation of land occupied by solar evaporation pond at UCIL, Bhopal, India.

    Science.gov (United States)

    George, K V; Patil, M R; Swaminathan, R

    2001-12-01

    Solar Evaporation Ponds (SEP) were used by Union Carbide India Limited (UCIL), Bhopal for storage of wastewater containing high concentrations of inorganic chemicals especially chlorides. Area occupied by the SEPs had to be recovered due to closure of the plant. A prerequisite to the reclamation of the SEP area is a study of adjoining soil and groundwater, which may be contaminated due to possible leakage in the pond. Surface soil, subsurface soil and groundwater samples were collected and analysed. The electrical conductivity method was employed inside the pond to test for leak in the geo-membrane liner. This was further confirmed by physically checking the liners. Based on the wet period, total rainfall and evaporation rate of the region, drying of remaining wastewater by spreading in dry ponds followed by pond dismantling was scheduled.

  3. Thermal Desalination using MEMS and Salinity-Gradient Solar Pond Technology

    Science.gov (United States)

    Lu, H.; Walton, J. C.; Hein, H.

    2002-08-01

    MEMS (multi-effect, multi-stage) flash desalination (distillation) driven by thermal energy derived from a salinity-gradient solar pond is investigated in this study for the purpose of improving the thermodynamic efficiency and economics of this technology. Three major tasks are performed: (1) a MEMS unit is tested under various operating conditions at the El Paso Solar Pond site; (2) the operation and maintenance procedures of the salinity-gradient solar pond coupled with the MEMS operation is studied; and (3) previous test data on a 24-stage, falling-film flash distillation unit (known as the Spinflash) is analyzed and compared with the performance of the MEMS unit. The data and information obtained from this investigation is applicable to a variety of thermal desalination processes using other solar options and/or waste heat.

  4. Solar pond-based rural development programme for selected coastal regions - A concept

    Digital Repository Service at National Institute of Oceanography (India)

    Gopinathan, C.K.

    is expected to aid speedy development of selected coastal areas. The programme involves design and construction of a solar pond in which brine in the lower layer is heated to 85 degrees C by solar radiation and is used as the heat source for a closed cycle...

  5. Importance of waste stabilization ponds and wastewater irrigation in the generation of vector mosquitoes in Pakistan

    DEFF Research Database (Denmark)

    Mukhtar, Muhammad; Ensink, Jeroen; Van der Hoek, Wim

    2006-01-01

    The objective of the current study was to investigate the role of waste stabilization ponds (WSP) and wastewater-irrigated sites for the production of mosquitoes of medical importance. Mosquito larvae were collected fortnightly from July 2001 to June 2002 in Faisalabad, Pakistan. In total, 3......,132 water samples from WSP and irrigated areas yielded 606,053 Culex larvae of five species. In addition, 107,113 anophelines, representing eight species were collected. Anopheles subpictus (Grassi) and Culex mosquitoes, especially Culex quinquefasciatus (Say) and Culex tritaeniorhynchus (Giles), showed...... an overwhelming preference for anaerobic ponds, which receive untreated wastewater. Facultative ponds generated lower numbers of both Anopheles and Culex mosquitoes, whereas the last ponds in the series, the maturation ponds, were the least productive for both mosquito genera. An. subpictus and Anopheles...

  6. Comparative productivity of distillation and reverse osmosis desalination using energy from solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Tleimat, B.W.; Howe, E.D.

    1982-11-01

    This paper presents comparative analyses of two methods for producing desalted water using the heat collected by a solar pond - the first by distillation, and the second by reverse osmosis. The distillation scheme uses a multiple-effect distiller supplied with steam generated in a flash boiler using heat from a solar pond. Solar pond water passes through a heat exchanger in the water system ahead of the flash boiler. The second scheme uses a similar arrangement to generate hydrocarbon vapor which drives a Rankine cycle engine. This engine produces mechanical/ electrical power for the RO plant. The analyses use two pond water temperatures -82.2/sup 0/C (180/sup 0/F) and 71.1/sup 0/C (160/sup 0/F) -- which seem to cover the range expected from salt-gradient ponds. In each case, the pond water temperature drops by 5.56/sup 0/C (10/sup 0/F) while passing through the vapor generator system. Results of these analyses show that, based on the assumptions made, desalted water could be produced by distillation at productivity rates much greater than those estimated for the RO plant.

  7. Comparative productivity of distillation and reverse osmosis desalination using energy from solar ponds

    Energy Technology Data Exchange (ETDEWEB)

    Tleimat, B.W.; Howe, E.D.

    1982-11-01

    This paper presents comparative analyses of two methods for producing desalted water using the heat collected by a solar pond - the first by distillation, and the second by reverse osmosis. The distillation scheme uses a multiple-effect distiller supplied with steam generated in a flash boiler using heat from a solar pond. Solar pond water passes through a heat exchanger in the water system ahead of the flash boiler. The second scheme uses a similar arrangement to generate hydrocarbon vapor which drives a Rankine cycle engine. This engine produces mechanical/ electrical power for the RO plant. The analyses use two pond water temperatures 82.2/sup 0/C (180/sup 0/F) and 71.1/sup 0/C (160/sup 0/F) - which seem to cover the range expected from salt-gradient ponds. In each case, the pond water temperature drops by 5.56/sup 0/C (10/sup 0/F) while passing through the vapor generator system. Results of these analyses show that, based on the assumptions made, desalted water could be produced by distillation at productivity rates much greater than those estimated for the RO plant.

  8. CFD analysis of sludge accumulation and hydraulic performance of a waste stabilization pond.

    Science.gov (United States)

    Alvarado, Andres; Sanchez, Esteban; Durazno, Galo; Vesvikar, Mehul; Nopens, Ingmar

    2012-01-01

    Sludge management in waste stabilization ponds (WSPs) is essential for safeguarding the system performance. Sludge accumulation patterns in WSPs are strongly influenced by the pond hydrodynamics. CFD modeling was applied to study the relation between velocity profiles and sludge deposition during 10 years of operation of the Ucubamba WSP in Cuenca (Ecuador). One tracer experiment was performed and three sludge accumulation scenarios based on bathymetric surveys were simulated. A residence time distribution (RTD) analysis illustrated the decrease of residence times due to sludge deposition. Sludge accumulation rates were calculated. The influence of flow pattern on the sludge deposition was studied, enabling better planning of future pond operation and desludging.

  9. Thermal performance of a single-basin solar still integrated with a shallow solar pond

    International Nuclear Information System (INIS)

    El-Sebaii, A.A.; Ramadan, M.R.I.; Aboul-Enein, S.; Salem, N.

    2008-01-01

    In an attempt to improve the daily productivity of the single effect solar stills, a single-slope single-basin solar still integrated with a shallow solar pond (SSP) was studied to perform solar distillation at a relatively high temperature. The energy balance equations of various elements of the considered system were formulated and solved analytically. Suitable computer programs were prepared for optimizing and predicting the thermal performance of the considered system. Numerical calculations were carried out on typical summer and winter days in Tanta (latitude 30 deg. 47'N) for different thicknesses and mass flow rates of the flowing water to study the effect of these parameters on the daily productivity and efficiency of the system. To validate the proposed theoretical model, comparisons between calculated and measured results were carried out. Good agreement has been achieved. The year-round performances of the still with and without the SSP were also investigated. The optimum values of the flowing water thickness and the mass flow rate for this typical configuration of the SSP-active solar still were obtained as 0.03 m and 0.0009 kg/s. The annual average values of the daily productivity P-bar d and efficiency η-bar d of the still with the SSP were found to be higher than those obtained without the SSP by 52.36% and 43.80%, respectively

  10. Thermal performance of a single-basin solar still integrated with a shallow solar pond

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A.; Ramadan, M.R.I.; Aboul-Enein, S.; Salem, N. [Department of Physics, Faculty of Science, Tanta University, Tanta (Egypt)

    2008-10-15

    In an attempt to improve the daily productivity of the single effect solar stills, a single-slope single-basin solar still integrated with a shallow solar pond (SSP) was studied to perform solar distillation at a relatively high temperature. The energy balance equations of various elements of the considered system were formulated and solved analytically. Suitable computer programs were prepared for optimizing and predicting the thermal performance of the considered system. Numerical calculations were carried out on typical summer and winter days in Tanta (latitude 30 47'N) for different thicknesses and mass flow rates of the flowing water to study the effect of these parameters on the daily productivity and efficiency of the system. To validate the proposed theoretical model, comparisons between calculated and measured results were carried out. Good agreement has been achieved. The year-round performances of the still with and without the SSP were also investigated. The optimum values of the flowing water thickness and the mass flow rate for this typical configuration of the SSP-active solar still were obtained as 0.03 m and 0.0009 kg/s. The annual average values of the daily productivity anti P{sub d} and efficiency anti {eta}{sub d} of the still with the SSP were found to be higher than those obtained without the SSP by 52.36% and 43.80%, respectively. (author)

  11. Experimental and numerical analysis of sodium-carbonate salt gradient solar-pond performance under simulated solar-radiation

    Energy Technology Data Exchange (ETDEWEB)

    Kurt, Hueseyin; Ozkaymak, Mehmet [Zonguldak Karaelmas University, Technical Education Faculty, 78200 Karabuk (Turkey); Binark, A. Korhan [Marmara University, Technical Education Faculty, 34722 Kuyubasi-Istanbul (Turkey)

    2006-04-01

    The objective of this study is to investigate experimentally and theoretically whether sodium carbonate (Na{sub 2}CO{sub 3}) salt is suitable for establishing a salinity gradient in a salt-gradient solar-pond (SGSP). For this purpose, a small-scale prismatic solar-pond was constructed. Experiments were conducted in the laboratory under the incident radiation from two halogen-lamps acting as a solar simulator. Furthermore, a one-dimensional transient mathematical model that describes the heat and mass transfer behaviour of the SGSP was developed. The differential equations obtained were solved numerically using a finite-difference method. It was found from the experiments that the density gradient, achieved using sodium carbonate salt, can suppress convection from the bottom to the surface of the pond. (author)

  12. Experimental and numerical analysis of sodium-carbonate salt gradient solar-pond performance under simulated solar-radiation

    International Nuclear Information System (INIS)

    Kurt, Hueseyin; Ozkaymak, Mehmet; Binark, A. Korhan

    2006-01-01

    The objective of this study is to investigate experimentally and theoretically whether sodium carbonate (Na 2 CO 3 ) salt is suitable for establishing a salinity gradient in a salt-gradient solar-pond (SGSP). For this purpose, a small-scale prismatic solar-pond was constructed. Experiments were conducted in the laboratory under the incident radiation from two halogen-lamps acting as a solar simulator. Furthermore, a one-dimensional transient mathematical model that describes the heat and mass transfer behaviour of the SGSP was developed. The differential equations obtained were solved numerically using a finite-difference method. It was found from the experiments that the density gradient, achieved using sodium carbonate salt, can suppress convection from the bottom to the surface of the pond

  13. A First Approach to Natural Thermoventilation of Residential Buildings through Ventilation Chimneys Supplied by Solar Ponds

    Directory of Open Access Journals (Sweden)

    Ferdinando Salata

    2015-07-01

    Full Text Available The exploitation of natural ventilation is a good solution to improve buildings from an energetic point of view and to fulfill the requirements demanded by the thermohygrometric comfort and the air quality in enclosed spaces. Some past researches demonstrated how some devices, useful to this purpose, follow the principles of solar chimneys and are able to move air masses while exploiting the Archimedes thrust. The natural ventilation must be supplied by a flow moving upward, generated by a heat source performing at temperatures slightly higher than the one present in the environment. To have a minimum energetic effect, the heat can be extracted from solar ponds; solar ponds are able to collect and store solar energy in the geographical regions characterized by sufficient values of solar radiation. Thus it is possible, in summer, to provoke a nocturnal natural ventilation useful for the air change in indoor spaces (in those climatic areas where, during the night, there is a temperature gradient.

  14. The removal of ammonia from sanitary landfill leachate using a series of shallow waste stabilization ponds.

    Science.gov (United States)

    Leite, V D; Pearson, H W; de Sousa, J T; Lopes, W S; de Luna, M L D

    2011-01-01

    This study evaluated the efficiency of a shallow (0.5 m deep) waste stabilization pond series to remove high concentrations of ammonia from sanitary landfill leachate. The pond system was located at EXTRABES, Campina Grande, Paraiba, Northeast Brazil. The pond series was fed with sanitary landfill leachate transported by road tanker to the experimental site from the sanitary landfill of the City of Joao Pessoa, Paraiba. The ammoniacal-N surface loading on the first pond of the series was equivalent to 364 kg ha(-1) d(-1) and the COD surface loading equivalent to 3,690 kg ha(-1) d(-1). The maximum mean ammonia removal efficiency was 99.5% achieved by the third pond in the series which had an effluent concentration of 5.3 mg L(-1) ammoniacal-N for an accumulative HRT of 39.5 days. The removal process was mainly attributed to ammonia volatilization (stripping) from the pond surfaces as a result of high surface pH values and water temperatures of 22-26°C. Shallow pond systems would appear to be a promising technology for stripping ammonia from landfill leachate under tropical conditions.

  15. Cadmium tolerance and antibiotic resistance in Escherichia coli isolated from waste stabilization ponds.

    Science.gov (United States)

    Patra, Sova; Das, T K; Avila, C; Cabello, V; Castillo, F; Sarkar, D; Lahiri, Susmita; Jana, B B

    2012-04-01

    The incidence pattern of cadmium tolerance and antibiotics resistance by Escherichia coli was examined periodically from the samples of water, sludge and intestine of fish raised in waste stabilization ponds in a sewage treatment plant. Samples of water and sludge were collected from all the selected ponds and were monitored for total counts of fecal coliform (FC), total coliform (TC) and the population of Escherichia coli, which was also obtained from the intestine of fishes. Total counts of both FC and TC as well as counts of E. coli were markedly reduced from the facultative pond to the last maturation pond. Tolerance limit to cadmium by E. coli tended to decline as the distance of the sewage effluent from the source increased; the effective lethal concentration of cadmium ranged from 0.1 mM in split chamber to 0.05 mM in first maturation pond. E. coli isolated from water, sludge and fish gut were sensitive to seven out of ten antibiotics tested. It appears that holistic functions mediated through the mutualistic growth of micro algae and heterotrophic bacteria in the waste stabilization ponds were responsible for the promotion of water quality and significant reduction of coliform along the sewage effluent gradient.

  16. Wastewater stabilization ponds - an appropriate technology for sewage treatment and refuse

    International Nuclear Information System (INIS)

    Aziz, J.A.

    1999-01-01

    Treatment of wastewater is imperative to protect human health and environmental quality. To this effect, the chosen technology should be cost effective, simple and easy to operate and maintain. Wastewater stabilization ponds offer one such technology and their use should be promoted in countries with scarcity of water so as to reuse the treated effluents in irrigation. Long term, pilot scale investigations on the performance of wastewater stabilization ponds have been undertaken at the Institute of Environmental Engineering and Research, Lahore to develop design criteria for their local use. This paper discuss the types and operation of waste stabilization ponds and the extent of their application in Pakistan. The need for users' education for effective operation of this simple facility is also emphasized. (author)

  17. Experimental and comparative study of the effect of paraffin oil and covering for solar ponds without saline water

    Energy Technology Data Exchange (ETDEWEB)

    Spyridonos, A V; Anagnostatos, G S; Novakovic, M M

    1989-01-01

    The effect of a superficial layer of paraffin or a plastic covering on the thermal storage efficiency of three kinds of non-saline solar pond has been investigated. Four small scale ponds were used for experimental measurements. These were: (1) a reference pond; (2) a pond divided horizontally into compartments separated by plastic sheets; (3) a pond with a superficial layer of paraffin and (4) a pond filled with hollow plastic cubes. Comparisons were made between these four ponds with and without plastic coverings, and with a layer of paraffin in addition on ponds 2 and 4. The rise in mean temperature of each pond during a number of heating cycles has been studied. A difference in mean temperature of the order of 10 to 20/sup 0/C was observed in each case between the beginning and end of the heating period and the temperature at the bottom of the pond after heating was in the range 30 to 50/sup 0/C. The results for these experimental ponds may be of use in the choice of full-size shallow ponds and may also give important indications for ponds of much greater depth.

  18. Thermal behavior of laboratory models of honeycomb-covered solar ponds

    Science.gov (United States)

    Lin, E. I. H.

    1983-01-01

    Laboratory experiments were conducted to provide insight into the technical feasibility of honeycomb-covered solar ponds. Cooling tests using honeycomb panels of various materials and geometries showed that a 5.7-cm-thick one-tier panel insulated as effectively as a 10-cm fiberglass slab. Heating tests demonstrated that a model pond covered with a polycarbonate panel boiled upon 16 hours of continuous exposure to a 150-W spotlight. Analysis of the experimental data indicates positively that honeycomb-covered solar ponds can be expected to perform satisfactorily, and that larger-scale outdoor tests should be conducted to provide a more realistic assessment and a more refined performance estimate.

  19. Evaluation of remedial alternatives for the Solar Ponds Plume, Rocky Flats Environmental Technology Site

    International Nuclear Information System (INIS)

    Hranac, K.C.

    1998-01-01

    This paper describes the process used to select a remedial alternative for handling contaminated groundwater emanating from the Solar Evaporation Ponds (Solar Ponds) at the Rocky Flats Environmental Technology Site (RFETS) and prevent it from reaching the nearest surface water body, North Walnut Creek. Preliminary results of field investigations conducted to provide additional information for the alternatives analysis are also presented. The contaminated groundwater is referred to as the Solar Ponds Plume (SPP). The primary contaminants in the SPP are nitrate and uranium; however, some metals exceed the site action levels at several locations and volatile organic compounds, originating from other sources, also have been detected. Currently the SPP, local surface water runoff, and infiltrated precipitation are collected by a trench system located downgradient of the Solar Ponds and pumped to three storage tanks. The water (two to three million gallons annually) is then pumped to an on-site treatment plant for evaporation at an approximate cost of $7.57 per liter

  20. Operational Limitations of Arctic Waste Stabilization Ponds: Insights from Modeling Oxygen Dynamics and Carbon Removal

    DEFF Research Database (Denmark)

    Ragush, Colin M.; Gentleman, Wendy C.; Hansen, Lisbeth Truelstrup

    2018-01-01

    Presented here is a mechanistic model of the biological dynamics of the photic zone of a single-cell arctic waste stabilization pond (WSP) for the prediction of oxygen concentration and the removal of oxygen-demanding substances. The model is an exploratory model to assess the limiting environmen...

  1. Rapid Sand Filtration for Best Practical Treatment of Domestic Wastewater Stabilization Pond Effluent

    Science.gov (United States)

    Boatright, D. T.; Lawrence, C. H.

    1977-01-01

    The technical and economic feasibility of constructing and operating a rapid sand filtration sewage treatment system as an adjunct to a waste water stabilization pond is investigated. The study concludes that such units are within the technical and economic constraints of a small community and comply with the EPA criteria. (BT)

  2. Thermal performance of shallow solar pond under open cycle continuous flow heating mode for heat extraction

    Energy Technology Data Exchange (ETDEWEB)

    El-Sebaii, A.A. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)]. E-mail: aasebaii@yahoo.com; Aboul-Enein, S. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Ramadan, M.R.I. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt); Khallaf, A.M. [Department of Physics, Faculty of Science, Tanta University, Tanta 31527 (Egypt)

    2006-05-15

    The thermal performance of a shallow solar pond (SSP) under an open cycle continuous flow heating mode for heat extraction has been investigated. A serpentine heat exchanger (HE), either welded to the absorber plate or immersed in the pond water, has been used for extracting the heat. Suitable computer programs have been developed based on analytical solutions of the energy balance equations for the various elements of the SSP in the presence of the HE. Numerical calculations have been performed to study the effect of different operational and configurational parameters on the pond performance. In order to improve the pond performance, optimization of the various dimensions of the pond with the HE has been performed. The effects of the design parameters of the HE's tube, i.e. length L{sub he}, diameter D and mass flow rate m-bar {sub f} of the fluid flowing through the HE, on the pond performance have been investigated. The outlet temperature of the HE's fluid T{sub fo} is found to increase with increase of the HE length L{sub he}, and it decreases with increase of the mass flow rate of the HE's fluid m-bar {sub f} up to typical values for these parameters. Typical values for L{sub he} and m-bar {sub f} are found to be 4m and 0.004kg/s beyond which the change in T{sub fo} becomes insignificant. Experiments have been performed for the pond under different operational conditions with a HE welded to the absorber plate. To validate the proposed mathematical models, comparisons between experimental and theoretical results have been performed. Good agreement has been achieved.

  3. EVALUATING THE ECOLOGICAL RESILIENT DRIVEN PERFORMANCE OF A TROPICAL WASTE STABILIZATION POND SYSTEM USING ECOLOGICAL SIGNATURE OF BIOLOGICAL INTEGRITY

    OpenAIRE

    Susmita Lahiri Ganguly; Dipanwita Sarkar Paria; B. B. Jana

    2015-01-01

    Using ecological signature of biological integrity as a measure of performance, the reclamation efficiency of waste stabilization ponds was evaluated over a period of four years in a tropical sewage treatment plant – cum fish culture consisting of two anaerobic, two facultative and four maturation ponds located serially across the sewage effluent gradient. The four maturation ponds were used for batch culture of fish. Samples of surface and bottom water as well as surface sediment were collec...

  4. Power generation enhancement in a salinity-gradient solar pond power plant using thermoelectric generator

    International Nuclear Information System (INIS)

    Ziapour, Behrooz M.; Saadat, Mohammad; Palideh, Vahid; Afzal, Sadegh

    2017-01-01

    Highlights: • Thermoelectric generator was used and simulated within a salinity-gradient solar pond power plant. • Results showed that the thermoelectric generator can be able to enhance the power plant efficiency. • Results showed that the presented models can be able to produce generation even in the cold months. • The optimum size of area of solar pond based on its effect on efficiency is 50,000 m 2 . - Abstract: Salinity-gradient solar pond (SGSP) has been a reliable supply of heat source for power generation when it has been integrated with low temperature thermodynamics cycles like organic Rankine cycle (ORC). Also, thermoelectric generator (TEG) plays a critical role in the production of electricity from renewable energy sources. This paper investigates the potential of thermoelectric generator as a power generation system using heat from SGSP. In this work, thermoelectric generator was used instead of condenser of ORC with the purpose of improving the performance of system. Two new models of SGSP have been presented as: (1) SGSP using TEG in condenser of ORC without heat exchanger and (2) SGSP using TEG in condenser of ORC with heat exchanger. These proposed systems was evaluated through computer simulations. The ambient conditions were collected from beach of Urmia lake in IRAN. Simulation results indicated that, for identical conditions, the model 1 has higher performance than other model 2. For models 1 and 2 in T LCZ = 90 °C, the overall thermal efficiency of the solar pond power plant, were obtained 0.21% and 0.2% more than ORC without TEG, respectively.

  5. Species dispersal rates alter diversity and ecosystem stability in pond metacommunities.

    Science.gov (United States)

    Howeth, Jennifer G; Leibold, Mathew A

    2010-09-01

    Metacommunity theory suggests that relationships between diversity and ecosystem stability can be determined by the rate of species dispersal among local communities. The predicted relationships, however, may depend upon the relative strength of local environmental processes and disturbance. Here we evaluate the role of dispersal frequency and local predation perturbations in affecting patterns of diversity and stability in pond plankton metacommunities. Pond metacommunities were composed of three mesocosm communities: one of the three communities maintained constant "press" predation from a selective predator, bluegill sunfish (Lepomis macrochirus); the second community maintained "press" conditions without predation; and the third community experienced recurrent "pulsed" predation from bluegill sunfish. The triads of pond communities were connected at either no, low (0.7%/d), or high (20%/d) planktonic dispersal. Richness and composition of zooplankton and stability of plankton biomass and ecosystem productivity were measured at local and regional spatial scales. Dispersal significantly affected diversity such that local and regional biotas at the low dispersal rate maintained the greatest number of species. The unimodal local dispersal-diversity relationship was predator-dependent, however, as selective press predation excluded species regardless of dispersal. Further, there was no effect of dispersal on beta diversity because predation generated local conditions that selected for distinct community assemblages. Spatial and temporal ecosystem stability responded to dispersal frequency but not predation. Low dispersal destabilized the spatial stability of producer biomass but stabilized temporal ecosystem productivity. The results indicate that selective predation can prevent species augmentation from mass effects but has no apparent influence on stability. Dispersal rates, in contrast, can have significant effects on both species diversity and ecosystem

  6. Removal Efficiency of Linear Alkyl Benzene Sulfonate (LAS in Yazd Stabilization Pond

    Directory of Open Access Journals (Sweden)

    Asghar Ebrahimi

    2011-01-01

    Full Text Available Surfactants are organic chemicals with wide applications as detergents. Linear alkyl benzene sulfonate (LAS is an anionic surfactant most commonly used. Discharge of raw or treated wastewater containing this chemical into the environment causes major public health problems. In this study, 64 samples were taken from the effluent of Yazd Wastewater  Treatment Plant over a period of one year. The samples were analyzed according to standard methods. The results obtained from the samples taken in different seasons showed that the highest efficiency of anionic surfactant removal was achieved in the summer in the secondary facultative stabilization pond. The least efficiency was observed in the autumn in samples from the anaerobic stabilization pond. It was also found that treated wastewater discharged into surface waters, reused for agricultural irrigation, or discharged into absorbent wells had significant differences with Pvalue

  7. Solar-thermal-energy collection/storage-pond system

    Science.gov (United States)

    Blahnik, D.E.

    1982-03-25

    A solar thermal energy collection and storage system is disclosed. Water is contained, and the water surface is exposed directly to the sun. The central part of an impermeable membrane is positioned below the water's surface and above its bottom with a first side of the membrane pointing generally upward in its central portion. The perimeter part of the membrane is placed to create a watertight boundary separating the water into a first volume which is directly exposable to the sun and which touches the membranes first side, and a second volumn which touches the membranes second side. A salt is dissolved in the first water volume.

  8. Combined effect of bottom reflectivity and water turbidity on steady state thermal efficiency of salt gradient solar pond

    International Nuclear Information System (INIS)

    Husain, M.; Patil, P.S.; Patil, S.R.; Samdarshi, S.K.

    2004-01-01

    In salt gradient solar ponds, the clarity of water and absorptivity of the bottom are important concerns. However, both are practically difficult to maintain beyond a certain limit. The reflectivity of the bottom causes the loss of a fraction of the incident radiation flux, resulting in lower absorption of flux in the pond. Turbidity hinders the propagation of radiation. Thereby it decreases the flux reaching the storage zone. Both these factors lower the efficiency of the pond significantly. However, the same turbidity also prevents the loss of radiation reflected from the bottom. Hence, the combined effect is compensatory to some extent. The present work is an analysis of the combined effect of the bottom's reflectivity and water turbidity on the steady state efficiency of solar ponds. It is found that in the case of a reflective bottom, turbidity, within certain limits, improves the efficiency of pond. This is apparently contradictory to the conventional beliefs about the pond. Nevertheless, this conclusion is of practical importance for design and maintenance of solar ponds

  9. Nile tilapia culture on domestic effluent treated in stabilization ponds.

    Directory of Open Access Journals (Sweden)

    Clovis Matheus Pereira

    2009-03-01

    Full Text Available The performance and filet quality of tilapias (Oreochromis niloticus culture in effluent stabilization lagoons was tested at the densities of 3 fish/m2 (T3, 7 fish/m2 (T2 and 7 fish/m2 in clean water + diet (T1 with 3 repetitions in tanks of 2.57m2 and 0.60m of water column with supplemental aeration. Fish culture in clean water plus diet (T1 presented the highest growth. The higher density T3 (7/m2 compared to T2 (3/m2 did not result in any difference of total production (p > 0.05 but this was compensated by the increased individual fish growth rate at lower density. The conditions that sustain fish survival culture with ETE effluent were attested by the high survival (> 90% under both treatments, but only 10% of the water samples from T2 and T3 N-total ammonium was favorable for fish growth (< 2.0mg/L. The rearing system improved the effluent quality, reducing the total organic nitrogen and the solids in suspension. The faecal coliforms, Salmonella sp. and Staphylococcus aureus from the effluent and fish were verified to be within the standards laid down by the World Health Organization (WHO.

  10. Different methods for modeling absorption heat transformer powered by solar pond

    International Nuclear Information System (INIS)

    Sencan, Arzu; Kizilkan, Onder; Bezir, Nalan C.; Kalogirou, Soteris A.

    2007-01-01

    Solar ponds are a type of solar collector used for storing solar energy at temperature below 90 o C. Absorption heat transformers (AHTs) are devices used to increase the temperature of moderately warm fluid to a more useful temperature level. In this study, a theoretical modelling of an absorption heat transformer for the temperature range obtained from an experimental solar pond with dimensions 3.5 x 3.5 x 2 m is presented. The working fluid pair in the absorption heat transformer is aqueous ternary hydroxide fluid consisting of sodium, potassium and caesium hydroxides in the proportions 40:36:24 (NaOH:KOH:CsOH). Different methods such as linear regression (LR), pace regression (PR), sequential minimal optimization (SMO), M5 model tree, M5' rules, decision table and back propagation neural network (BPNN) are used for modelling the absorption heat transformer. The best results were obtained by the back propagation neural network model. A new formulation based on the BPNN is presented to determine the flow ratio (FR) and the coefficient of performance (COP) of the absorption heat transformer. The BPNN procedure is more accurate and requires significantly less computation time than the other methods

  11. The survey of biological absorption of hexavalent chromium from aqueous solutions by Wastewater stabilization pond algae

    Directory of Open Access Journals (Sweden)

    Mohammad Nourisepehr

    2016-06-01

    Full Text Available Background: Contamination of aquatic habitats due to toxicity and accumulation of heavy metals leading to serious damage to organisms and their advance to the food chain. Chrome is one of these heavy metals for the three and six-valence oxides used in industry. Health risks such as carcinogenic hexavalent chromium have been For this reason, removal and reduction of environment is essential. Target of this study hexavalent chromium biosorption by waste stabilization pond algae is of the aquatic environment. Methods: This study was a fundamental applied; In this batch reactor, variables Was investigated pH(3,5,7,9,11, Contact time(30,60,120,180,240,300min, The concentration of hexavalent chromium(0.5,1,5mg And the concentration of algae(0.25, 0.5, 1, 3g. Liquid mixed municipal wastewater treatment stabilization pond was used for insemination. For the investigate the effects of variables pH, contact time, the concentration of hexavalent chromium values in a 250 ml Erlenmeyer flask prepared and various amounts of dried algae (0.25-0.5-1- 3 g were added to it. Then became the shakers. After mixing, the filter paper was passed. The lab temperature was centrifuged for min10-5 rpm 2700 rpm. Then it was read at a wavelength absorbed by 540 nm. . Then collected was data to Excel and SPSS software. Finally was used for hexavalent chromium adsorption isotherm model equation of Langmuir and Freundlich. Results: This study shows that PH, contact time, the concentration of hexavalent chromium and chromium concentrations of algae optimal absorption by algae concentrations, respectively, in5 mg / l, min 120, 0.5 mg / l and is 1gr. Average maximum absorption of chromium Wastewater stabilization ponds by algae 97/2%, respectively. Correlation coefficients absorption curves of these models showed that Cr (VI adsorption isotherm on wastewater stabilization pond algae follows (= R.  Conclusion: The results showed that wastewater stabilization pond algae as a

  12. Natural heat storage in a brine-filled solar pond in the Tully Valley of central New York

    Science.gov (United States)

    Hayhurst, Brett; Kappel, William M.

    2014-01-01

    The Tully Valley, located in southern Onondaga County, New York, has a long history of unusual natural hydrogeologic phenomena including mudboils (Kappel, 2009), landslides (Tamulonis and others, 2009; Pair and others, 2000), landsurface subsidence (Hackett and others, 2009; Kappel, 2009), and a brine-filled sinkhole or “Solar pond” (fig. 1), which is documented in this report. A solar pond is a pool of salty water (brine) which stores the sun’s energy in the form of heat. The saltwater naturally forms distinct layers with increasing density between transitional zones (haloclines) of rapidly changing specific conductance with depth. In a typical solar pond, the top layer has a low salt content and is often times referred to as the upper convective zone (Lu and others, 2002). The bottom layer is a concentrated brine that is either convective or temperature stratified dependent on the surrounding environment. Solar insolation is absorbed and stored in the lower, denser brine while the overlying halocline acts as an insulating layer and prevents heat from moving upwards from the lower zone (Lu and others, 2002). In the case of the Tully Valley solar pond, water within the pond can be over 90 degrees Fahrenheit (°F) in late summer and early fall. The purpose of this report is to summarize observations at the Tully Valley brine-filled sinkhole and provide supplemental climate data which might affect the pond salinity gradients insolation (solar energy).

  13. Development of a small-scale solar pond technology testbed for education purposes

    International Nuclear Information System (INIS)

    Rahmat, I.; Shazi, M.; Farizal, M.; Nor Azli; Fakhruldin M Hashim

    2006-01-01

    The search for clean energy sources that do not pollute have led researchers to test their ideas on a multitude of possible technology avenues. A number of these solutions rely on the sun. however, the initial financial investment required is great. These solutions, such as solar water heaters, depend on an insulated water tank to store the captured energy. A more effective device could be used to both capture and store copious amounts of sunlight energy, allowing almost continuous use even at night. Solar ponds show great promise in fulfilling this requirement. The one currently in operation at Universiti Teknologi PETRONAS is of the non-convecting type. It uses concentrated brine in the depths of the pond to capture solar energy. The energy is then trapped by the presence of a non-saline top layer, which insulates from convection heat losses. This phenomenon manifests itself as a rise in temperature of the brine. In this manner, thermal energy is contained in the pond, which can serve as the heat source for any appropriate power cycle or used for heating purposes. To make the technology feasible for education purposes it is imperative that its cost is lowered. The system is not dug out of the ground but uses a commercial bathtub to simulate the body of water. This method also greatly simplifies fabrication and maintenance. With this rudimentary setup, the highest temperature reached so far is 54 o C, achieved in a water depth of only 0.28 m. The next step is to increase the water depth, search for the most cost-effective side insulation and continue research into the appropriate energy extraction system to match the output and size of the solar pond. The main intent of this project is to educate students on this concept and develop it into an effective technology demonstrator. By keeping the cost low it can be turned into a viable secondary school Living Skills project to educate them on the potential of solar energy and the existence of alternative solutions in

  14. The stability of the water column in french ponds (limousin region by the calculation of the wedderburn number

    Directory of Open Access Journals (Sweden)

    TOUCHART L.

    2014-03-01

    Full Text Available Oxygenation and biological life in lakes, reservoirs and ponds depend on the stability of the water column and on the rhythms of stratification and mixing periods. Slight thermal stratification in ponds often is regarded as the same as instability in shallow lakes. Nevertheless fetch in ponds is very short, what reduces the mixing. Wedderburn number (quotient of the buoyancy by the mixing is used to quantify the stability in shallow water bodies. We calculate it for some ponds in French region Limousin, due to original hourly water temperature measurements in all depths and wind data of Météofrance stations. First results show that very high values (above 10 are frequent in summer and spring period (during 41% of the total time of 2 336 hours from May to July in three ponds. That is why we may consider Limousin ponds as stable stratified bodies of water despite their shallowness. Continuous measurements allow to calculate the diurnal cycle and other time scales of the Wedderburn number, with periods of weakening, when air temperatures and surface water temperatures decrease, wind speed increases and when the wind blows in the same direction with the length of the pond. The most complex variable is the depth of the thermocline; a light increase of the breeze thickens the upper warm layer and strengthens the stability, but an important increase of the wind tends to destroy the stratification.

  15. Site-Specific Research Conducted in Support of the Salton Sea Solar Pond Project - FY 1982 Report

    Science.gov (United States)

    French, R. L.; Marsh, H. E.; Roschke, E. J.; Wu, Y. C.

    1984-01-01

    The design and operation of a salt-gradient solar pond power plant at the Salton Sea presents problems not encountered at small research ponds that were built in the United States. The specific characteristics of the Salton Sea site and the desire to construct the pond using the local clay as a sealant represent major deviations from previous solar pond experience. The site-specific research in support of the plant design is described. The research activity included validation of the spectrophotometric light transmission measurement technique, a search for options for clarifying the turbid and colored water of the Salton Sea, development of water clarification specifications in terms common to industry practice, quantification of gas production from microbiological reactions in the ground, a determination of the combined effects of temperature and salinity on the permeation of the local clays, and a preliminary evaluation of material corrosion.

  16. EFFECTIVENESS OF WASTE STABILIZATION PONDS IN REMOVAL OF LINEAR ALKYL BENZENE SALFONATE (LAS

    Directory of Open Access Journals (Sweden)

    Ahmed. M. Abdel-Rahman

    2013-06-01

    Full Text Available Detergents contain synthetic or organic surface active agents called surfactants, which are derived from petroleum product precursors. They have the common property of lowering the surface tensions of water thus allowing dirt or grease adhered to various articles to be washed off. Linear alkyl benzene sulfonate (LAS is a most commonly used anionic surfactant. Discharge of raw or treated wastewater containing this chemical substance into the environment causes major public health and enviromental problems. In this study, samples were taken from raw wastewater and effluents of treatment ponds of Elzaraby waste stabilization ponds over a period of one year. The treated effluent is either discharged into surface waters or re-used in agricultural irrigation. The samples were analyzed according to the standard methods. The results obtained from the samples taken in different seasons showed that the highest overall removal efficiency of LAS was achieved in summer season (77%, and the least efficiency was observed in Winter season (55%, while the maximum overall efficiency of BOD5 was in summer (88% and minimum efficiency was (73% in winter season. The Dissolved oxygen concentrations along the pond series (DO ranged from 0.18 to 4.8 mg/l.

  17. Application of waste stabilization pond's effluent on cultivation of roses (rosa damascena mill)

    International Nuclear Information System (INIS)

    Khan, M.A.; Shaukat, S.; Shahzad, A.; Ahmed, W.

    2011-01-01

    The study focuses on the use of Waste Stabilization Ponds (WSP) effluent for irrigation and also aims to compare the efficiency of effluent with the Hoagland solution. Results revealed that the number of flowers, size of flower and the petals per flower increased by the use of both Hoagland solution and treated effluent while the height of plant and the fresh weight of flowers were increased significantly by the Hoagland solution only. Moreover, the leaves showed high concentration of reducing and non-reducing sugars as compared to flowers whereas, only the leaves of plants which were treated by the ponds effluent had low content of reducing sugars as compared to leaves of untreated plants serving as controls. The variation in chlorophyll content was similar to that of reducing and non-reducing sugars. In addition, leaves of plants that were treated by pond's effluent showed highest concentration of total phenol content. It is concluded that treated effluent is as effective as Hoagland for the irrigation of rose. Additionally, the use of treated effluent for irrigation reduces the demand of fresh water and the use of inorganic fertilizers for the commercial production of roses. (author)

  18. EFFECTIVENESS OF WASTE STABILIZATION PONDS IN REMOVAL OF LINEAR ALKYL BENZENE SALFONATE (LAS

    Directory of Open Access Journals (Sweden)

    Ahmed. M. Abdel-Rahman

    2013-01-01

    Full Text Available Detergents contain synthetic or organic surface active agents called surfactants, which are derived from petroleum product precursors. They have the common property of lowering the surface tensions of water thus allowing dirt or grease adhered to various articles to be washed off. Linear alkyl benzene sulfonate (LAS is a most commonly used anionic surfactant. Discharge of raw or treated wastewater containing this chemical substance into the environment causes major public health and enviromental problems. In this study, samples were taken from raw wastewater and effluents of treatment ponds of Elzaraby waste stabilization ponds over a period of one year. The treated effluent is either discharged into surface waters or re-used in agricultural irrigation. The samples were analyzed according to the standard methods. The results obtained from the samples taken in different seasons showed that the highest overall removal efficiency of LAS was achieved in summer season (77%, and the least efficiency was observed in Winter season (55%, while the maximum overall efficiency of BOD5 was in summer (88% and minimum efficiency was (73% in winter season. The Dissolved oxygen concentrations along the pond series (DO ranged from 0.18 to 4.8 mg/l.

  19. Solar Pond devices: free energy or bioreactors for Artemia biomass production?

    Science.gov (United States)

    Gouveia, Luisa; Sousa, João; Marques, Ana; Tavares, Célia; Giestas, Margarida

    2009-08-01

    The recent exponential growth in industrial aquaculture has led to a huge increase in Artemia biomass production in order to meet increased fish production needs. The present study explores the potential use of salt gradient solar ponds (SGSPs) for production of Artemia nauplii. An SGSP is a basin of water where solar energy is trapped and collected via an artificially imposed gradient. Three zones can be identified in an SGSP: upper and lower zones, which are both convective, and a middle zone, which is intended to be non-convective. The latter acts as a transparent insulation layer and allows for storage of solar energy at the bottom, where it is available for use. The combination of salt, temperature and high transparency could make SGSPs promising bioreactors for the production of Artemia nauplii. Using particle image velocymetry (PIV) and Shadowgraph visualisation techniques, the behaviour of Artemia nauplii under critical cultivation parameters (namely, salinity, temperature and light) was monitored to determine movement velocity, and how movement of Artemia affects the salt gradient. It was observed that Artemia nauplii constantly follow light, irrespective of adverse salinity and/or temperature conditions. However, despite the substantial displacement of Artemia following the light source, the salt gradient is not disrupted. The suitability of SGSPs as bioreactors for Artemia biomass production was then tested. The results were disappointing, probably due to the lack of sufficient O(2) for Artemia survival and growth. Follow-up trials were conducted aimed at using the SGSP as a green and economically attractive energy source to induce faster hatching of cysts and improved Artemia nauplii growth. The results of these trials, and a case study of Artemia nauplii production using an SGSP, are presented. The authors constructed a Solar Pond device, which they suggest as a novel way of supplying thermal energy for Artemia biomass production in an aquaculture

  20. Achievement report for fiscal 1999 on project for supporting the formation of energy/environmental technology verification project. International joint verification research project (Study on an optimum heat and electricity supply system using a solar pond); 1999 nendo solar pond ni okeru saiteki netsuden kyokyu system no kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report covers the outcome of survey and research jointly conducted by a Russian research organization and a Japanese committee of experts. Concerning the present trend and the future outlook of the solar pond technology across the world, feasibility studies of Australia, America, Malaysia, Italy, etc., are presented. It is reported that a solar pond may be able to compete with other profitable power generation systems in terms of cost if advantageous siting conditions are available; that solar ponds are already in presence in Israel, America, Australia, India, etc.; but that none of them is commercially active on a large scale. In the evaluation of solar pond feasibility, various findings are obtained on solar pond performance characteristics through the examination of solar pond operating data supplied from the University of Texas, America. The findings are used in the evaluation of the siting cost in case one is to be installed in Russia and Japan. (NEDO)

  1. Algal Growth and Waste Stabilization Ponds Performance Efficiency in a Sub-Tropical Climate

    International Nuclear Information System (INIS)

    Alamgir, A.; Khan, M. A.; Shaukat, S. S.

    2016-01-01

    Both irrigation and potable water are in diminutive supply in most of the developing countries particularly those situated in tropical and subtropical regions where, often untreated wastewater is utilized for the purpose of irrigation. Treated wastewater has proved to be a potential asset serving as an alternate source for the expansion of irrigated agriculture. Waste stabilization ponds (WSP) are considered as less costly and effective substitute for the wastewater water treatment in tropics. The principle of wastewater treatment in waste stabilization pond is based on the symbiotic relationship between bacteria and various algal species. In this study, an attempt was made to relate algal growth and different extrinsic factors using multiple regression models. The predominant algal species found in WSP systems were Chlorella, Euglena, Oscillatoria and Scenedesmus. The growth of individual algal species and overall algal growth was principally governed by temperature, total sunshine hours and Total Kjeldhal Nitrogen (TKN). The study suggested that algal bacterial symbiotic relationship works well and the dissolved oxygen production through algal photosynthesis was optimum to decompose heavy organic load resulting in oxygen-rich effluent (liquid fertilizer) which could be successfully exploited for unrestricted irrigation. (author)

  2. Egg production and hatching success of Paracartia grani (Copepoda, Calanoida, Acartiidae) in two hypersaline ponds of a Tunisian Solar Saltern

    Science.gov (United States)

    Annabi-Trabelsi, Neila; Rebai, Rayda Kobbi; Ali, Mohammad; Subrahmanyam, M. N. V.; Belmonte, Genuario; Ayadi, Habib

    2018-04-01

    Reproductive traits of Paracartia grani [percentage of spawning females, egg production rate (EPR), and hatching success (HS)] were investigated for the first time at high salinities (39-121 psu) to examine the impact of such a particular situation. The study was done in two hypersaline ponds [A1 (39-46 psu) and C31 (70-121 psu)] in Sfax Solar Saltern, central-eastern coast of Tunisia. These ponds also differed in terms of the composition and concentrations of nutritional parameters. The EPR differed significantly between the ponds (ANOVA, F = 29.45, p eggs female- 1 day- 1 (7 December 2009) and 14 ± 1 eggs female- 1 day- 1 (19 January 2010) with an average of 13.3 ± 0.44 eggs female- 1 day- 1. HS after 48 h of incubation were significantly higher than those after 24 h. The mean values of HS after 48 h were 42.72 ± 2.58% at pond A1 and 41.67 ± 3.92% at pond C31. The two peaks of HS (after 48 h) were observed at 15 °C in pond A1 (21 December 2009, 45.18% nauplii eggs- 1) and in C31 (4 January 2010, 48.78%) at the same temperature. This study confirms that a broad salinity tolerance allows P. grani to settle itself in environments, which are normally hostile to the development of other Acartiidae.

  3. Stability of Polymer Solar Cells

    DEFF Research Database (Denmark)

    Jørgensen, Mikkel; Norrman, Kion; Gevorgyan, Suren

    2012-01-01

    Organic photovoltaics (OPVs) evolve in an exponential manner in the two key areas of efficiency and stability. The power conversion efficiency (PCE) has in the last decade been increased by almost a factor of ten approaching 10%. A main concern has been the stability that was previously measured ...

  4. Disinfection and removal of human pathogenic bacteria in arctic waste stabilization ponds

    DEFF Research Database (Denmark)

    Huang, Yannan; Hansen, Lisbeth Truelstrup; Ragush, Colin M.

    2017-01-01

    Wastewater stabilization ponds (WSPs) are commonly used to treat municipal wastewater in Arctic Canada. The biological treatment in the WSPs is strongly influenced by climatic conditions. Currently, there is limited information about the removal of fecal and pathogenic bacteria during the short...... cool summer treatment season. With relevance to public health, the objectives of this paper were to determine if treatment in arctic WSPs resulted in the disinfection (i.e., removal of fecal indicator bacteria, Escherichia coli) and removal of selected human bacterial pathogens from the treated...... treatment of the wastewater with a 2–3 Log removal of generic indicator E. coli. The bacterial pathogens Salmonella spp., pathogenic E. coli, and Listeria monocytogenes, but not Campylobacter spp. and Helicobacter pylori, were detected in the untreated and treated wastewater, indicating that human...

  5. EVALUATING THE ECOLOGICAL RESILIENT DRIVEN PERFORMANCE OF A TROPICAL WASTE STABILIZATION POND SYSTEM USING ECOLOGICAL SIGNATURE OF BIOLOGICAL INTEGRITY

    Directory of Open Access Journals (Sweden)

    Susmita Lahiri Ganguly

    2015-06-01

    Full Text Available Using ecological signature of biological integrity as a measure of performance, the reclamation efficiency of waste stabilization ponds was evaluated over a period of four years in a tropical sewage treatment plant – cum fish culture consisting of two anaerobic, two facultative and four maturation ponds located serially across the sewage effluent gradient. The four maturation ponds were used for batch culture of fish. Samples of surface and bottom water as well as surface sediment were collected twice a month from different ponds of the system and examined for some nutrient cycling bacteria, primary production, chlorophyll content of micro-algae, phytoplankton, zooplankton abundance, fish growth and water quality parameters. Computation of ecological signature using aerobic mineralization index for heterotrophic and ammonifying bacteria revealed steady increase across the sewage effluent gradient. The heterotrophic and ammonifying bacterial populations appeared to have a direct function with the concentrations of chemical oxygen demand of water. The sum of total scores for different optimal conditions for fish growth increased as a function of the distance from the source of effluent implying that ecological resilience of the waste stabilization ponds has been accomplished by the sedimentation, chelation, and biological functional attributes mediated through redundancy of different subsystems, self- purification capacity of the system as a whole.

  6. Two-step upflow anaerobic sludge bed system for sewage treatment under subtropical conditions with posttreatment in waste stabilization ponds

    NARCIS (Netherlands)

    Seghezzo, L.; Trupiano, A.P.; Liberal, V.; Todd, P.G.; Figueroa, M.E.; Gutierrez, M.A.; Silva Wilches, Da A.C.; Iribarnegaray, M.; Guerra, R.G.; Arena, A.; Cuevas, C.M.; Zeeman, G.; Lettinga, G.

    2003-01-01

    A pilot-scale sewage treatment system consisting of two upflow anaerobic sludge bed (UASB) reactors followed by five waste stabilization ponds (WSPs) in series was studied under subtropical conditions. The first UASB reactor started up in only 1 mo (stable operation, high chemical oxygen demand

  7. Comparing the Efficiency of Stabilization Ponds and Subsurface Constructed Wetland in Domestic Sewage Treatment in City of Yazd

    Directory of Open Access Journals (Sweden)

    hadi Eslami

    2016-01-01

    Full Text Available Wastewater is one of the most important contributors to water pollution on the one hand, while it has the potential to serve as an alternative source of water if subjected to proper treatment, on the other. The present study was designed to compare the removal efficiencies of stabilization ponds and subsurface constructed wetlands in the treatment of urban wastewater in Yazd. For this purpose, 72 samples were collected at the inlet and outlet of a constructed wetland as well as 72 from the inlet and outlet of stabilization ponds over a period of one year. The samples were subjected to identical tests and the results were compared. The removal efficiencies for BOD5, COD, TSS, NH4-N, NO3-N, and PO4 in the stabilization ponds were 79.7, 79.6, 44.4, 57, 0, and 42.5 percent, respectively. The same parameters for the constructed wetland system were 80.7, 81.5, 77.7, 9.9, 34, and 59.4, respectively. Moreover, BOD5, COD, TSS, and PO4 removal efficiencies were higher in autumn and summer. From these results, it may be concluded that constructed wetlands are more commercially viable than stabilization ponds both in terms of performance and cost-effectiveness.

  8. Performance study of a laboratory model shallow solar pond with and without single transparent glass cover for solar thermal energy conversion applications.

    Science.gov (United States)

    Ganesh, S; Arumugam, S

    2016-12-01

    The thermal performance of a shallow solar pond with and without the single transparent glass cover has been investigated experimentally. This experiment has been performed during the summer season of 2014 under the operational condition for five different storage volumes of water upto a maximum of 10liter. The pond performance is investigated in terms of the rate of energy collected and its collection efficiency. A Low Density Polyethylene (LDPE) black sheet liner of 200μm thickness was laid on all the interior sides of the pond for solar energy absorption. A clear transparent PVC plastic sheet of 150μm thickness was laid over the water surface as evaporation suppressing membrane. Calibrated Copper constantan thermocouples were used to measure the temperatures of the system. A highest temperature of 81.5°C has been achieved for the stored volume of 2liter of water, when the pond was used with a single transparent glass cover of 5mm thickness. When the shallow solar pond was used without the transparent glass cover the system attained a maximum temperature of 62°C for the same stored volume of 2liter. A comparison between the two conditions of with and without the transparent glass cover, on the thermal performance of the SSP has been reported. A shallow solar pond system of the present type could be used us a source of warm water, of desired temperature, below 10°C which are required for the domestic and industrial utilities. The global warming is increased day by day; inorder to reduce global warming a typical method of small scale shallow solar pond has been used to absorb the radiation from the sun to convert it to useful heat energy by the source of water. The SSP is an eco friendly way to generate energy without polluting our environment and in an environment safety manner. Based on environmental safety this study has experimentally investigated the thermal performance of the shallow solar pond. Copyright © 2016 Elsevier Inc. All rights reserved.

  9. Duckweed based wastewater stabilization ponds for wastewater treatment (a low cost technology for small urban areas in Zimbabwe)

    Science.gov (United States)

    Dalu, J. M.; Ndamba, J.

    A three-year investigation into the potential use of duckweed based wastewater stabilizations ponds for wastewater treatment was carried out at two small urban areas in Zimbabwe. The study hoped to contribute towards improved environmental management through improving the quality of effluent being discharged into natural waterways. This was to be achieved through the development and facilitation of the use of duckweed based wastewater stabilizations ponds. The study was carried out at Nemanwa and Gutu Growth Points both with a total population of 23 000. The two centers, like more than 70% of Zimbabwe’s small urban areas, relied on algae based ponds for domestic wastewater treatment. The final effluent is used to irrigate gum plantations before finding its way into the nearest streams. Baseline wastewater quality information was collected on a monthly basis for three months after which duckweed ( Lemna minor) was introduced into the maturation ponds to at least 50% pond surface cover. The influent and effluent was then monitored on a monthly basis for chemical, physical and bacteriological parameters as stipulated in the Zimbabwe Water (Waste and Effluent Disposal) regulations of 2000. After five months, the range of parameters tested for was narrowed to include only those that sometimes surpassed the limits. These included: phosphates, nitrates, pH, biological oxygen demand, iron, conductivity, chemical oxygen demand, turbidity, total dissolved solids and total suspended solids. Significant reductions to within permissible limits were obtained for most of the above-mentioned parameters except for phosphates, chemical and biological oxygen demand and turbidity. However, in these cases, more than 60% reductions were observed when the influent and effluent levels were compared. It is our belief that duckweed based waste stabilization ponds can now be used successfully for the treatment of domestic wastewater in small urban areas of Zimbabwe.

  10. The Distribution of Microalgae in a Stabilization Pond System of a Domestic Wastewater Treatment Plant in a Tropical Environment (Case Study: Bojongsoang Wastewater Treatment Plant

    Directory of Open Access Journals (Sweden)

    Herto Dwi Ariesyady

    2016-02-01

    Full Text Available The Bojongsoang Wastewater Treatment Plant (WWTP serves to treat domestic wastewater originating from Bandung City, West Java, Indonesia. An abundant amount of nutrients as a result of waste decomposition increases the number of microalgae populations present in the pond of the wastewater treatment plant, thereby causing a population explosion of microalgae, also called algal blooming. In a stabilization pond system, the presence of algal blooming is not desirable because it can decrease wastewater treatment performance. More knowledge about the relationship between the nutrients concentration and algae blooming conditions, such as microalgae diversity, is needed to control and maintain the performance of the wastewater treatment plant. Therefore this study was conducted, in order to reveal the diversity of microalgae in the stabilization pond system and its relationship with the water characteristics of the comprising ponds. The results showed that the water quality in the stabilization pond system of Bojongsoang WWTP supported rapid growth of microalgae, where most rapid microbial growth occurred in the anaerobic pond. The microalgae diversity in the stabilization ponds was very high, with various morphologies, probably affiliated with blue-green algae, green algae, cryptophytes, dinoflagellates and diatoms. This study has successfully produced information on microalgae diversity and abundance profiles in a stabilization pond system.

  11. Stability Analysis of a Run-of-River Diversion Hydropower Plant with Surge Tank and Spillway in the Head Pond

    Directory of Open Access Journals (Sweden)

    José Ignacio Sarasúa

    2014-01-01

    Full Text Available Run-of-river hydropower plants usually lack significant storage capacity; therefore, the more adequate control strategy would consist of keeping a constant water level at the intake pond in order to harness the maximum amount of energy from the river flow or to reduce the surface flooded in the head pond. In this paper, a standard PI control system of a run-of-river diversion hydropower plant with surge tank and a spillway in the head pond that evacuates part of the river flow plant is studied. A stability analysis based on the Routh-Hurwitz criterion is carried out and a practical criterion for tuning the gains of the PI controller is proposed. Conclusions about the head pond and surge tank areas are drawn from the stability analysis. Finally, this criterion is applied to a real hydropower plant in design state; the importance of considering the spillway dimensions and turbine characteristic curves for adequate tuning of the controller gains is highlighted.

  12. The removal of thermo-tolerant coliform bacteria by immobilized waste stabilization pond algae.

    Science.gov (United States)

    Pearson, H W; Marcon, A E; Melo, H N

    2011-01-01

    This study investigated the potential of laboratory- scale columns of immobilized micro-algae to disinfect effluents using thermo-tolerant coliforms (TTC) as a model system. Cells of a Chlorella species isolated from a waste stabilization pond complex in Northeast Brazil were immobilized in calcium alginate, packed into glass columns and incubated in contact with TTC suspensions for up to 24 hours. Five to six log removals of TTC were achieved in 6 hours and 11 log removals in 12 hours contact time. The results were similar under artificial light and shaded sunlight. However little or no TTC removal occurred in the light in columns of alginate beads without immobilized algae present or when the immobilized algae were incubated in the dark suggesting that the presence of both algae and light were necessary for TTC decay. There was a positive correlation between K(b) values for TTC and increasing pH in the effluent from the immobilized algal columns within the range pH 7.2 and 8.9. The potential of immobilized algal technology for wastewater disinfection may warrant further investigation.

  13. Modeling Nitrogen Dynamics in a Waste Stabilization Pond System Using Flexible Modeling Environment with MCMC.

    Science.gov (United States)

    Mukhtar, Hussnain; Lin, Yu-Pin; Shipin, Oleg V; Petway, Joy R

    2017-07-12

    This study presents an approach for obtaining realization sets of parameters for nitrogen removal in a pilot-scale waste stabilization pond (WSP) system. The proposed approach was designed for optimal parameterization, local sensitivity analysis, and global uncertainty analysis of a dynamic simulation model for the WSP by using the R software package Flexible Modeling Environment (R-FME) with the Markov chain Monte Carlo (MCMC) method. Additionally, generalized likelihood uncertainty estimation (GLUE) was integrated into the FME to evaluate the major parameters that affect the simulation outputs in the study WSP. Comprehensive modeling analysis was used to simulate and assess nine parameters and concentrations of ON-N, NH₃-N and NO₃-N. Results indicate that the integrated FME-GLUE-based model, with good Nash-Sutcliffe coefficients (0.53-0.69) and correlation coefficients (0.76-0.83), successfully simulates the concentrations of ON-N, NH₃-N and NO₃-N. Moreover, the Arrhenius constant was the only parameter sensitive to model performances of ON-N and NH₃-N simulations. However, Nitrosomonas growth rate, the denitrification constant, and the maximum growth rate at 20 °C were sensitive to ON-N and NO₃-N simulation, which was measured using global sensitivity.

  14. Stability Issues on Perovskite Solar Cells

    Directory of Open Access Journals (Sweden)

    Xing Zhao

    2015-11-01

    Full Text Available Organo lead halide perovskite materials like methylammonium lead iodide (CH3NH3PbI3 and formamidinium lead iodide (HC(NH22PbI3 show superb opto-electronic properties. Based on these perovskite light absorbers, power conversion efficiencies of the perovskite solar cells employing hole transporting layers have increased from 9.7% to 20.1% within just three years. Thus, it is apparent that perovskite solar cell is a promising next generation photovoltaic technology. However, the unstable nature of perovskite was observed when exposing it to continuous illumination, moisture and high temperature, impeding the commercial development in the long run and thus becoming the main issue that needs to be solved urgently. Here, we discuss the factors affecting instability of perovskite and give some perspectives about further enhancement of stability of perovskite solar cell.

  15. Halite depositional facies in a solar salt pond: A key to interpreting physical energy and water depth in ancient deposits?

    Science.gov (United States)

    Robertson Handford, C.

    1990-08-01

    Subaqueous deposits of aragonite, gypsum, and halite are accumulating in shallow solar salt ponds constructed in the Pekelmeer, a sea-level sauna on Bonaire, Netherlands Antilles. Several halite facies are deposited in the crystallizer ponds in response to differences in water depth and wave energy. Cumulate halite, which originates as floating rafts, is present only along the protected, upwind margins of ponds where low-energy conditions foster their formation and preservation. Cornet crystals with peculiar mushroom- and mortarboard-shaped caps precipitate in centimetre-deep brine sheets within a couple of metres of the upwind or low-energy margins. Downwind from these margins, cornet and chevron halite precipitate on the pond floors in water depths ranging from a few centimetres to ˜60 cm. Halite pisoids with radial-concentric structure are precipitated in the swash zone along downwind high-energy shorelines where they form pebbly beaches. This study suggests that primary halite facies are energy and/or depth dependent and that some primary features, if preserved in ancient halite deposits, can be used to infer physical energy conditions, subenvironments such as low- to high-energy shorelines, and extremely shallow water depths in ancient evaporite basins.

  16. Olive mill wastewater stabilization in open-air ponds: impact on clay-sandy soil.

    Science.gov (United States)

    Jarboui, Raja; Sellami, Fatma; Kharroubi, Adel; Gharsallah, Néji; Ammar, Emna

    2008-11-01

    The aim of this work was to study the natural biodegradation of the stored olive mill wastewater (OMW) in ponds and the infiltration as well as the impact on soil of the effluent in the evaporation pond used for the storage over the past eight years. For this, two approaches were considered. First, a laboratory-scale column was used for the infiltration of OMW through soil (clay and sand) to predict the effect of the clayey soil in reducing OMW pollution. Second, the ponds including the effluent annually stored and having this clayey structure were investigated. At the laboratory-scale, a modification of OMW contents was noticed, with the elimination of 95% of total suspended solids (TSS), 60% of chemical oxygen demand (COD), 40% of total organic carbon (TOC), 50% of total P, 50% of phenols and 40% of minerals (K+, Mg++ and Na+). The experimented soil was able to restrain the considerable effects of OMW pollution. In the ponds, the granulometric characteristics, the physico-chemical and the biological parameters of the soil profile from the contaminated pond were compared to those of a control soil, located near the contaminated pond. Property modifications of the contaminated soil were noted, especially pH, electrical conductivity, COD and microflora. These changes can be explained by the infiltration of OMW constituents, which were noticed in the soil layers, especially phenolic compounds that have a negative effect on the ground water.

  17. Removal of Chromium and Cadmium from Wastewater in Waste Stabilization Ponds, Yazd-Iran

    Directory of Open Access Journals (Sweden)

    Mohammad Reza Samaei

    2016-04-01

    Full Text Available Background: Heavy metals have destructive and irreversible effects on the human, plants and animals. Some industries in Yazd enter industrial wastewater to municipal wastewater collection system. This can lead to high levels of heavy metals in wastewater and in turn in the wastewater treatment plant effluent. Methods: This study was carried out during four months from December 22, 2009 to May 20, 2010. The experiment was performed on the inflow, outlet of anaerobic pond and first and second facultative ponds of wastewater treatment plant and then transferred to the laboratory and measured by atomic absorption spectroscopy. Results: The results of the experiments showed that the average cadmium concentrations in the inflow, anaerobic pond outlet, and first and second facultative pond outlet were 0.0066, 0.0087, 0.0076, and 0.0083μg/l, respectively. The average amounts of chromium in the inflow, anaerobic pond outlet, and first and second facultative pond outlet were 0.0076, 0.0065, 0.0043, and 0.0056 μg/l, respectively. Cadmium concentration in the effluent was higher than standard. Conclusion: The comparison of the obtained data with Iranian standards for wastewater treatment for reuse in irrigation shows that the cadmium concentration exceeded the standard and the chromium concentration was lower than the standard. Therefore, it is not suitable for reuse in the crop farms and aquatic life

  18. Rocky Flats Solar Evaporation Ponds RCRA hybrid-closure case study

    International Nuclear Information System (INIS)

    Ogg, R.T.; Everett, L.G.; Cullen, S.J.

    1994-01-01

    The Solar Evaporation Ponds (SEP)/Operable Unit 4 (OU 4), located at the Rocky Flats Plant (RFP) sixteen miles northwest of Denver, Colorado, is currently undergoing remediation/Resource Conservation and Recovery Act (RCRA) closure in accordance with the Rocky Flats Interagency Agreement (IAG) signed by the US Department of Energy (DOE), US Environmental Protection Agency (EPA) and Colorado Department of Health (CDH) on January 22, 1991. Based on the ''Phase 1'' (source and soils) RCRA Facility Investigation/Remedial Investigation (RFM data and interpretations), the DOE and EG and G Rocky Flats, Inc. (EG and G) have selected a permanent surface engineered/isolation barrier as the technological option for remediation of the SEP. The DOE and EG and G will utilize all natural materials to create an ''impermeable'' barrier/structure to isolate the waste being left in place from impacting human health and the environment for a minimum of 1,000 years. Their rationale for utilizing natural materials is two fold; (1) optimize long term performance of the barrier and; (2) design a structure which will be near maintenance free (passive remediation) for 1,000 years. The DOE and EG and G have taken a proactive approach in providing post closure performance assessment for this RCRA closure action. An integrated monitoring system has been designed which will include monitoring the engineered barrier, vadose zone and ground water systems. Rocky Flats will integrate instrumentation into the permanent engineered barrier which will provide early warning of potential liquid migration through the barrier and into the waste zone

  19. Stability and Degradation of Polymer Solar cells

    DEFF Research Database (Denmark)

    Norrman, Kion

    The current state-of-the-art allows for roll-to-roll manufacture of polymer solar cells in high volume with stability and efficiency sufficient to grant success in low-energy applications. However, further improvement is needed for the successful application of the devices in real life applications....... This is obtained by detailed knowledge of the degradation mechanisms. Methods to compare and standardize device stability are urgently needed. Methodologies to study failure mechanism that are based on physical processes (e.g. morphological changes) are well-established. However, methodologies to study chemical...... degradation mechanisms are currently scarce. An overview of known degradation mechanisms will be presented and discussed in relation to state-of-the-art methodologies to study failure mechanisms with focus on chemical degradation....

  20. Temporal stability of Escherichia coli concentration patterns in two irrigation ponds in Maryland

    Science.gov (United States)

    Fecal contamination of water sources is an important water quality issue for agricultural irrigation ponds. Escherichia coli is a common microbial indicator used to evaluate recreational and irrigation water quality. We hypothesized that there is a temporally stable pattern of E.coli concentrations ...

  1. Effect of operational variables on nitrogen transformations in duckweed stabilization ponds

    NARCIS (Netherlands)

    Caicedo Berjarano, J.R.

    2005-01-01

    There is an urgent need to develop and improve low cost technologies for wastewater treatment that are within the economic and technological capabilities of developing countries. Simultaneously treating wastewater and producing duckweed in a pond system is therefore an attractive option to

  2. Effect of solar radiation on the lipid characterization of biomass cultivated in high-rate algal ponds using domestic sewage.

    Science.gov (United States)

    Assemany, Paula Peixoto; Calijuri, Maria Lúcia; Santiago, Anibal da Fonseca; do Couto, Eduardo de Aguiar; Leite, Mauricio de Oliveira; Sierra, Jose Jovanny Bermudez

    2014-01-01

    The objective of this paper is to compare the lipid content and composition ofbiomass produced by a consortium of microalgae and bacteria, cultivated under different solar radiation intensities and tropical conditions in pilot-scale high-rate ponds (HRPs) using domestic sewage as culture medium. The treatment system consisted of an upflow anaerobic sludge blanket reactor followed by UV disinfection and six HRPs covered with shading screens that blocked 9%, 18%, 30%, 60% and 80% of the solar radiation. The total lipid content does not vary significantly among the units, showing a medium value of 9.5%. The results show that blocking over 30% of the solar radiation has a negative effect on the lipid productivity. The units with no shading and with 30% and 60% of solar radiation blocking have statistically significant lipid productivities, varying from 0.92 to 0.96 gm(-2) day(-1). Besides radiation, other variables such as volatile suspended solids and chlorophyll-a are able to explain the lipid accumulation. The lipid profile has a predominance of C16, C18:1 and C18:3 acids. The unsaturation of fatty acids increases with the reduction in solar radiation. On the other hand, the effect of polyunsaturation is not observed, which is probably due to the presence of a complex and diverse biomass.

  3. Removal of 226Ra from tailings pond effluents and stabilization of uranium mine tailings. Bench and pilot scale studies

    International Nuclear Information System (INIS)

    Schmidtke, N.W.; Averill, D.; Bryant, D.N.; Wilkinson, P.; Schmidt, J.W.

    1978-01-01

    Increased world demand for uranium has resulted in recent expansion of Canadian uranium mining operations. Problems have been identified with the discharge of radionuclides such as 226 Ra from tailings pond effluents and with the stabilization of mine tailings. At Environment Canada's Wastewater Technology Centre (WTC) two projects were undertaken in cooperation with the Canadian Uranium Mining Industry and other federal government agencies to address these problems. The first project reports on the progress of bench and pilot scale process simulations for the development of a data base for the design of a full scale mechanical physical/chemical 226 Ra removal waste treatment system with an effluent target level of 10 pCi 226 Ra total per litre. The second project addresses problems of the leachability of radionuclides and the stabilization of both uranium mine tailings and BaRaSO 4 sediments from the treatment of acid seepages

  4. Performance evaluation of cement-stabilized pond ash-rice husk ash-clay mixture as a highway construction material

    Directory of Open Access Journals (Sweden)

    Deepak Gupta

    2017-02-01

    Full Text Available This paper reports the results of an investigation carried out on clay soil stabilized with pond ash (PA, rice husk ash (RHA and cement. Modified Proctor compaction tests were performed in order to investigate the compaction behavior of clay, and California bearing ratio (CBR tests were performed to determine the strength characteristics of clay. For evaluation purpose, the specimens containing different amounts of admixtures were prepared. Clay was replaced with PA and RHA at a dosage of 30%–45% and 5%–20%, respectively. The influence of stabilizer types and dosages on mechanical properties of clay was evaluated. In order to study the surface morphology and crystallization characteristics of the soil samples, scanning electron microscopy (SEM and X-ray diffraction (XRD analyses were carried out, respectively. The results obtained indicated a decrease in the maximum dry density (MDD and a simultaneous increase in the optimum moisture content (OMC with the addition of PA and RHA. Multiple linear regression analysis (MLRA showed that the predicted values of CBR tests are in good agreement with the experimental values. Developed stabilized soil mixtures showed satisfactory strength and can be used for construction of embankments and stabilization of sub-grade soil. The use of locally available soils, PA, RHA, and cement in the production of stabilized soils for such applications can provide sustainability for the local construction industry.

  5. Calculation of heat balance considering the reflection, refraction of incident ray and salt diffusion on solar pad; Hikari no hansha kussetsu oyobi shio no kakusan wo koryoshita solar pond no netsukeisan

    Energy Technology Data Exchange (ETDEWEB)

    Kanayama, K; Li, X; Baba, H; Endo, N [Kitami Institute of Technology, (Japan)

    1997-11-25

    In calculating heat balance of solar pond, calculation was made considering things except quality of the incident ray and physical properties of pond water which were conventionally considered. The real optical path length was determined from the reflection ratio of ray on the water surface based on the refraction ratio of pond water and the locus of water transmitted ray in order to calculate a total transmission rate. The rate of absorption of monochromatic lights composing of solar light in their going through the media is different by wavelength, and therefore, calculation was made in each monochromatic light. As to four kinds of salt water solution, NaCl, KCl, MgCl2 and CaCl2, these phenomena seen in solar pond are taken in, and a total transmission rate based on reality can be calculated by the wavelength integration method. Moreover, in the salt gradient layer, there are gradients in both concentration and temperature, and thermal physical values of each layer change. Accordingly, mass transfer and thermal transfer by both gradients were considered at the same time. An analytic solution was introduced which analyzes salt diffusion in the temperature field in the gradient layer and determines the concentration distribution. By these, concentration and physical values of each layer were calculated according to phenomena, and thermal balance of each layer of the solar pond was able to be accurately calculated. 6 refs., 5 figs., 2 tabs.

  6. Effects of Environmental Factors on the Disinfection Performance of a Wastewater Stabilization Pond Operated in a Temperate Climate

    Directory of Open Access Journals (Sweden)

    Lei Liu

    2015-12-01

    Full Text Available Treatment in a wastewater stabilization pond (WSP relies on natural purification processes, which can be sensitive to both location and climate. This study investigated the effects of three environmental factors, pH, dissolved oxygen (DO and temperature, on disinfection efficiency in a WSP system consisting of three facultative cells, and operated in a temperate climate region, in Eastern Ontario, Canada. Indicator organism (Escherichia coli (E. coli removal in WSP systems is driven by a combination of different factors. Elevated pH and DO concentrations, which are attributed to the presence of algae, are important factors for effective disinfection. Therefore, the presence of algae in natural wastewater treatment systems can contribute appreciably to disinfection. Consequently, based on algal concentrations, removal efficiencies of pathogenic microorganisms during wastewater treatment over the course of a year can be highly variable, where higher removal efficiencies would be expected in summer and fall seasons.

  7. Stability and degradation mechanisms in organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Ecker, Bernhard

    2012-04-26

    This thesis deals with stability improvements and the investigation of degradation mechanisms in organic solar cells. Organic solar cells have been in the focus of extensive academic research for over almost two decades and are currently entering the market in small scale applications. For successful large scale applications, next to the improvement of the power conversion efficiency, the stability of organic solar cells has to be increased. This thesis is dedicated to the investigation of novel materials and architectures to study stability-related issues and degradation mechanisms in order to contribute to the basic understanding of the working principles of organic solar cells. Here, impedance spectroscopy, a frequency domain technique, is used to gain information about stability and degradation mechanisms in organic solar cells. In combination with systematic variations in the preparation of solar cells, impedance spectroscopy gives the possibility to differentiate between interface and bulk dominated effects. Additionally, impedance spectroscopy gives access to the dielectric properties of the device, such as capacitance. This offers among other things the opportunity to probe the charge carrier concentration and the density of states. Another powerful way of evaluation is the combination of experimentally obtained impedance spectra with equivalent circuit modelling. The thesis presents results on novel materials and solar cell architectures for efficient hole and electron extraction. This indicates the importance of knowledge over interlayers and interfaces for improving both the efficiency and stability of organic solar cells.

  8. Nitrate pollution of groundwater around a sewage stabilization pond, Kerala India

    International Nuclear Information System (INIS)

    Vasu, K.; Shahul Hameed, A.; Velayudhan, K.T.; Jacob, S.; Mathew, M.

    1998-01-01

    An investigation was carried out to determine the influence of the sewage stabilisation pont of the Calicut Medical College on the quality of water in the open dug wells which are situated in and around the stabilisation pond. The study revealed that domestic wells are becoming increasingly polluted with nitrate in spite of heavy rainfall in the region. The level of nitrate in the observation wells was found to be vary widely during different seasons: from 1.1 to 49.8, 0.7 to 19.5 and from 2.1 to 38.3 mg/l during pre-monsoon, monsoon and post-monsoon periods, respectively. One well had nitrate exceeding the maximum permissible limit specified for drinking water by Bureau of Indian Standards. The problem is more pronounced in summer when the level of nitrate is observed to be on the higher side. (author)

  9. Effect of low quality effluent from wastewater stabilization ponds to receiving bodies, case of Kilombero sugar ponds and Ruaha river, Tanzania.

    Science.gov (United States)

    Machibya, Magayane; Mwanuzi, Fredrick

    2006-06-01

    A study was conducted in a sewage system at Kilombero Sugar Company to review its design, configuration, effectiveness and the quality of influent and effluent discharged into the Ruaha river (receiving body). The concern was that, the water in the river, after effluent has joined the river, is used as drinking water by villages located downstream of the river. Strategic sampling at the inlet of the oxidation pond, at the outlet and in the river before and after the effluent has joined the receiving body (river) was undertaken. Samples from each of these locations were taken three times, in the morning, noon and evening. The sample were then analysed in the laboratory using standard methods of water quality analysis. The results showed that the configuration and or the layout of the oxidation ponds (treatment plant) were not in accordance with the acceptable standards. Thus, the BOD5 of the effluent discharged into the receiving body (Ruaha River) was in the order of 41 mg/l and therefore not meeting several standards as set out both by Tanzanian and international water authorities. The Tanzanian water authorities, for example, requires that the BOD5 of the effluent discharged into receiving bodies be not more that 30 mg/l while the World Health Organization (WHO) requires that the effluent quality ranges between 10 - 30 mg/l. The paper concludes that proper design of treatment plants (oxidation ponds) is of outmost importance especially for factories, industries, camps etc located in rural developing countries where drinking water from receiving bodies like rivers and lakes is consumed without thorough treatment. The paper further pinpoint that both owners of treatment plants and water authorities should establish monitoring/management plan such that treatment plants (oxidation ponds) could be reviewed regarding the change on quantity of influent caused by population increase.

  10. Effect of Low Quality Effluent from Wastewater Stabilization Ponds to Receiving Bodies, Case of Kilombero Sugar Ponds and Ruaha River, Tanzania

    Directory of Open Access Journals (Sweden)

    Fredrick Mwanuzi

    2006-06-01

    Full Text Available A study was conducted in a sewage system at Kilombero Sugar Company to review its design, configuration, effectiveness and the quality of influent and effluent discharged into the Ruaha river (receiving body. The concern was that, the water in the river, after effluent has joined the river, is used as drinking water by villages located downstream of the river. Strategic sampling at the inlet of the oxidation pond, at the outlet and in the river before and after the effluent has joined the receiving body (river was undertaken. Samples from each of these locations were taken three times, in the morning, noon and evening. The sample were then analysed in the laboratory using standard methods of water quality analysis. The results showed that the configuration and or the layout of the oxidation ponds (treatment plant were not in accordance with the acceptable standards. Thus, the BOD5 of the effluent discharged into the receiving body (Ruaha River was in the order of 41 mg/l and therefore not meeting several standards as set out both by Tanzanian and international water authorities. The Tanzanian water authorities, for example, requires that the BOD5 of the effluent discharged into receiving bodies be not more that 30 mg/l while the World Health Organization (WHO requires that the effluent quality ranges between 10 – 30 mg/l. The paper concludes that proper design of treatment plants (oxidation ponds is of outmost importance especially for factories, industries, camps etc located in rural developing countries where drinking water from receiving bodies like rivers and lakes is consumed without thorough treatment. The paper further pinpoint that both owners of treatment plants and water authorities should establish monitoring/management plan such that treatment plants (oxidation ponds could be reviewed regarding the change on quantity of influent caused by population increase.

  11. Solarelastic Stability of Solar Sail Structures

    Data.gov (United States)

    National Aeronautics and Space Administration — In order to avoid an unintended failure in proposed Solar Sail spacecraft due to solarelastic interactions it is important to develop an analytical framework for...

  12. Stability and Degradation of Organic and Polymer Solar Cells

    DEFF Research Database (Denmark)

    Organic photovoltaics (OPV) are a new generation of solar cells with the potential to offer very short energy pay back times, mechanical flexibility and significantly lower production costs compared to traditional crystalline photovoltaic systems. A weakness of OPV is their comparative instability...... during operation and this is a critical area of research towards the successful development and commercialization of these 3rd generation solar cells. Covering both small molecule and polymer solar cells, Stability and Degradation of Organic and Polymer Solar Cells summarizes the state of the art...... understanding of stability and provides a detailed analysis of the mechanisms by which degradation occurs. Following an introductory chapter which compares different photovoltaic technologies, the book focuses on OPV degradation, discussing the origin and characterization of the instability and describing...

  13. Long term optical stability of fluorescent solar concentrator plates

    NARCIS (Netherlands)

    Slooff, L.H.; Bakker, N.J.; Sommeling, P.M.; Büchtemann, A.; Wedel, A.; Sark, W.G.J.H.M. van

    2014-01-01

    Fluorescent solar concentrators offer an alternative approach for low-cost photovoltaic energy conversion. For successful application, not only the power conversion efficiency and cost are important, but also lifetime or stability of the devices. As today’s concentrator is made of polymer sheets

  14. Long-term optical stability of fluorescent solar concentrator plates

    NARCIS (Netherlands)

    Slooff, Lenneke H.; Bakker, Nicolaas J.; Sommeling, Paul M.; Büchtemann, Andreas; Wedel, Armin; Van Sark, Wilfried G J H M

    2014-01-01

    Fluorescent solar concentrators offer an alternative approach for low-cost photovoltaic energy conversion. For successful application, not only the power conversion efficiency and cost are important, but also lifetime or stability of the devices. As today's concentrator is made of polymer sheets

  15. Pointing stability of Hinode and requirements for the next Solar mission Solar-C

    Science.gov (United States)

    Katsukawa, Y.; Masada, Y.; Shimizu, T.; Sakai, S.; Ichimoto, K.

    2017-11-01

    It is essential to achieve fine pointing stability in a space mission aiming for high resolutional observations. In a future Japanese solar mission SOLAR-C, which is a successor of the HINODE (SOLAR-B) mission, we set targets of angular resolution better than 0.1 arcsec in the visible light and better than 0.2 - 0.5 arcsec in EUV and X-rays. These resolutions are twice to five times better than those of corresponding instruments onboard HINODE. To identify critical items to achieve the requirements of the pointing stability in SOLAR-C, we assessed in-flight performance of the pointing stability of HINODE that achieved the highest pointing stability in Japanese space missions. We realized that one of the critical items that have to be improved in SOLAR-C is performance of the attitude stability near the upper limit of the frequency range of the attitude control system. The stability of 0.1 arcsec (3σ) is required in the EUV and X-ray telescopes of SOLAR-C while the HINODE performance is slightly worse than the requirement. The visible light telescope of HINODE is equipped with an image stabilization system inside the telescope, which achieved the stability of 0.03 arcsec (3σ) by suppressing the attitude jitter in the frequency range lower than 10 Hz. For further improvement, it is expected to suppress disturbances induced by resonance between the telescope structures and disturbances of momentum wheels and mechanical gyros in the frequency range higher than 100 Hz.

  16. Evaluation of waste stabilization ponds effluent efficiency on the growth and nutritive characteristics of cluster beans (cyamopsis tetragonoloba l.) taub

    International Nuclear Information System (INIS)

    Khan, M.; Shaukat, S.S.; Alamgir, A.; Hasan, S.A.

    2014-01-01

    South Asian countries including Pakistan are facing chronic shortage of water supply which is anticipated to be aggravated in future. These countries are agribased where the continued water supply is crucial for sustainable economy. One of the possible alternatives to overcome the problems of water scarcity is the used of treated wastewater which is gaining much importance even in the western world. The treated wastewater can be used as a liquid fertilizer which could provide dual benefits both in terms of saving of fresh water as well as inorganic fertilizers. The potential of treated effluent from waste stabilization ponds (WSP) and equivalent basal fertilizer on growth and nutritive quality of cluster beans (Cyamopsis tetragonoloba L.) Taub. was investigated under field conditions. Treated effluent significantly increased fresh weight of leaves and stems. Dry weight of stem was also significantly higher with the treatment of WSP effluent as compared to the use of basal fertilizer and fresh water. Fresh and dry fruit weights, number of seeds per fruit and fruit length were also significantly increased in WSP effluent treatment as compared to other two treatments. Treatment with WSP effluent also improved the nutritive characteristics such as crude proteins and total carbohydrates. However, total fat and ash content percentage of Cyamopsis tetragonoloba remained unaltered. The application of WSP effluent also increased NPK and organic matter content of the soil after harvesting the crop which would be helpful for succeeding crop. The study demonstrated that treated effluent can be successfully used for unrestricted irrigation in the water deficient areas of Pakistan thereby saving huge quantities of fresh water. (author)

  17. Effects of Organic Load, pH, and EC Variations of Raw Wastewater and Weather Condition on the Efficiency of Yazd Stabilization Ponds

    Directory of Open Access Journals (Sweden)

    Seyed Alireza Mozaheb

    2009-06-01

    Full Text Available This study investigates the effects of organic load, pH, and EC variations of raw wastewater as well as the effect of weather condition on organic removal in Yazd wastewater Stabilization Ponds (2007. During the course of this study, composite samples were collected from the inlet and outlet of the anaerobic pond and the final effluent to measure such quality parameters as BOD5, COD, TSS, EC, and pH.  BOD5, COD, TSS, and Fecal coliform removal efficiencies in the final effluent were found to be 64.9%, 44.9 %, 62.6 %, and 99.96%, respectively. No intestinal nematode egg was observed. Comparison of BOD5 and COD concentrations in the filtered and non-filtered samples showed that 52% of the BOD5 and 57% of the COD in the final effluent, respectively, were due to the presence of algal mass and organic suspended solids in the non-filtered samples. The results showed that variations in organic load, pH, EC as well as seasonal weather variations had no effects on organic removal and that the removal of BOD5 was almost constant. Effluent EC was higher than influent EC. This phenomenon can be related to the evaporation rate in wastewater stabilization ponds. The survey of algae in the final effluent showed that the major species of algae were Phytoconis, Chlorella, and Anabaena.

  18. Recent progress in stabilizing hybrid perovskites for solar cell applications

    Science.gov (United States)

    Chen, Jianqing; Cai, Xin; Yang, Donghui; Song, Dan; Wang, Jiajia; Jiang, Jinghua; Ma, Aibin; Lv, Shiquan; Hu, Michael Z.; Ni, Chaoying

    2017-07-01

    Hybrid inorganic-organic perovskites have quickly evolved as a promising group of materials for solar cells and optoelectronic applications mainly owing to the inexpensive materials, relatively simple and versatile fabrication and high power conversion efficiency (PCE). The certified energy conversion efficiency for perovskite solar cell (PSC) has reached above 20%, which is compatible to the current best for commercial applications. However, long-term stabilities of the materials and devices remain to be the biggest challenging issue for realistic implementation of the PSCs. This article discusses the key issues related to the stability of perovskite absorbing layer including crystal structural stability, chemical stability under moisture, oxygen, illumination and interface reaction, effects of electron-transporting materials (ETM), hole-transporting materials (HTM), contact electrodes, ion migration and preparation conditions. Towards the end, prospective strategies for improving the stability of PSCs are also briefly discussed and summarized. We focus on recent understanding of the stability of materials and devices and our perspectives about the strategies for the stability improvement.

  19. Attitude Dynamics and Stability of a Simple Solar Photon Thruster

    Directory of Open Access Journals (Sweden)

    Anna D. Guerman

    2013-01-01

    Full Text Available This paper is dedicated to the development of a model of the attitude dynamics for a nonideal Simple Solar Photon Thruster (SSPT and to the analysis of sailcraft motions with respect to their centre of mass. Derivation of the expressions for force and torque due to solar radiation that is valid for the case, when there is a misalignment of the SSPT axis with the sun direction, is followed by study of sailcraft dynamics and stability properties. Analysis of stability shows that an ideally reflecting sail is unstable, while for a sailcraft with nonideal collector, the symmetry axis is stable with respect to the Sun direction for large variety of system parameters. The motion around symmetry axis is always unstable and requires an active stabilizer.

  20. Solar Dynamic Power System Stability Analysis and Control

    Science.gov (United States)

    Momoh, James A.; Wang, Yanchun

    1996-01-01

    The objective of this research is to conduct dynamic analysis, control design, and control performance test of solar power system. Solar power system consists of generation system and distribution network system. A bench mark system is used in this research, which includes a generator with excitation system and governor, an ac/dc converter, six DDCU's and forty-eight loads. A detailed model is used for modeling generator. Excitation system is represented by a third order model. DDCU is represented by a seventh order system. The load is modeled by the combination of constant power and constant impedance. Eigen-analysis and eigen-sensitivity analysis are used for system dynamic analysis. The effects of excitation system, governor, ac/dc converter control, and the type of load on system stability are discussed. In order to improve system transient stability, nonlinear ac/dc converter control is introduced. The direct linearization method is used for control design. The dynamic analysis results show that these controls affect system stability in different ways. The parameter coordination of controllers are recommended based on the dynamic analysis. It is concluded from the present studies that system stability is improved by the coordination of control parameters and the nonlinear ac/dc converter control stabilize system oscillation caused by the load change and system fault efficiently.

  1. Applying Nyquist's method for stability determination to solar wind observations

    Science.gov (United States)

    Klein, Kristopher G.; Kasper, Justin C.; Korreck, K. E.; Stevens, Michael L.

    2017-10-01

    The role instabilities play in governing the evolution of solar and astrophysical plasmas is a matter of considerable scientific interest. The large number of sources of free energy accessible to such nearly collisionless plasmas makes general modeling of unstable behavior, accounting for the temperatures, densities, anisotropies, and relative drifts of a large number of populations, analytically difficult. We therefore seek a general method of stability determination that may be automated for future analysis of solar wind observations. This work describes an efficient application of the Nyquist instability method to the Vlasov dispersion relation appropriate for hot, collisionless, magnetized plasmas, including the solar wind. The algorithm recovers the familiar proton temperature anisotropy instabilities, as well as instabilities that had been previously identified using fits extracted from in situ observations in Gary et al. (2016). Future proposed applications of this method are discussed.

  2. Response surface methodology modeling to improve degradation of Chlorpyrifos in agriculture runoff using TiO2 solar photocatalytic in a raceway pond reactor.

    Science.gov (United States)

    Amiri, Hoda; Nabizadeh, Ramin; Silva Martinez, Susana; Jamaleddin Shahtaheri, Seyed; Yaghmaeian, Kamyar; Badiei, Alireza; Nazmara, Shahrokh; Naddafi, Kazem

    2018-01-01

    This paper deals with the use of a raceway pond reactor (RPR) as an alternative photoreactor for solar photocatalytic applications. Raceway pond reactors are common low-cost reactors which can treat large volumes of water. The experiments were carried out with TiO 2 in the agriculture effluent spiked with Chlorpyrifos (CPF) at circumneutral pH. The Response Surface Methodology (RSM) was used to find the optimum process parameters to maximize CPF oxidation from the mathematical model equations developed in this study using R software. By ANOVA, p-value of lack of fit > 0.05 indicated that, the equation was well-fitted. The theoretical efficiency of CPF removal, under the optimum oxidation conditions with UV solar energy of around 697 ± 5.33 lux, was 84.01%, which is in close agreement with the mean experimental value (80 ± 1.42%) confirming that the response model was suitable for the optimization. As far as the authors know, this is the first study of CPF removal using RPR in agriculture runoff at circumneutral pH. Copyright © 2017. Published by Elsevier Inc.

  3. Dye-sensitized solar cells and solar module using polymer electrolytes: Stability and performance investigations

    Directory of Open Access Journals (Sweden)

    Jilian Nei de Freitas

    2006-01-01

    Full Text Available We present recent results on solid-state dye-sensitized solar cell research using a polymer electrolyte based on a poly(ethylene oxide derivative. The stability and performance of the devices have been improved by a modification in the method of assembly of the cells and by the addition of plasticizers in the electrolyte. After 30 days of solar irradiation (100 mW cm-2 no changes in the cell's efficiency were observed using this new method. The effect of the active area size on cell performance and the first results obtained for the first solar module composed of 4.5 cm2 solid-state solar cells are also presented.

  4. Olive mill wastewater evaporation management using PCA method Case study of natural degradation in stabilization ponds (Sfax, Tunisia).

    Science.gov (United States)

    Jarboui, Raja; Sellami, Fatma; Azri, Chafai; Gharsallah, Néji; Ammar, Emna

    2010-04-15

    Olive mill wastewater (OMW) evaporation ponds management was investigated in five serial evaporation open-air multiponds of 50 ha located in Sfax (Tunisia). Physico-chemical parameters and microbial flora evolution were considered. Empirical models describing the OMW characteristic changes with the operation time were established and Principal Component Analysis (PCA) described the correlation between physico-chemical and biological parameters. COD, BOD, total solids, polyphenols and electrical conductivity exhibited first-order models. Four groups exhibited high correlations. The first included temperature, density, COD, TSS, TS, BOD, VS, TOC, TKN, polyphenols and minerals. The second group was made up of yeasts and moulds. The third group was established with phenolic compounds, total sugars, fats, total phosphorous, NH(4)(+) and pH. The fourth group was constituted by exclusively aerobic bacteria. Bacterial-growth toxic effect was exhibited by high organic load, ash content and polyphenols, whereas moulds and yeasts were more adapted to OMW. During the storage, all the third group parameter values decreased and were inversely related to the others. In the last pond, COD, BOD, TS and TSS rates were reduced by 40%, 50%, 50% and 75% respectively. The evaporation and the biological activity were the main processes acting, predicting the OMW behavior during evaporation in air-open ponds. 2009 Elsevier B.V. All rights reserved.

  5. High stability of benzotriazole and benzodithiophene containing medium band-gap polymer solar cell

    DEFF Research Database (Denmark)

    Unay, Hande; dos Reis Benatto, Gisele A.; Beliatis, Michail J.

    2018-01-01

    The improvement of polymer solar cell stability is a challenge for the scientists and has significant implications commercially. In this study, we investigated the stability of a novel P-SBTBDT active material applied in an inverted type solar cell. Detailed stability experiments comprising shelf......-in phase with T50 from 700 to 840 h, with some P-SBTBDT solar cells did not reach T50 in the time span of the test. Degradation tests on the P-SBTBDT solar cells which were carried out under natural solar light indicated that T40 was reached after 840 h. The results of dark, light, damp and dry stability...

  6. Photo stability Assessment in Amorphous-Silicon Solar Cells

    International Nuclear Information System (INIS)

    Gandia, J. J.; Carabe, J.; Fabero, F.; Jimenez, R.; Rivero, J. M.

    1999-01-01

    The present status of amorphous-silicon-solar-cell research and development at CIEMAT requires the possibility to characterise the devices prepared from the point of view of their stability against sunlight exposure. Therefore a set of tools providing such a capacity has been developed. Together with an introduction to photovoltaic applications of amorphous silicon and to the photodegradation problem, the present work describes the process of setting up these tools. An indoor controlled photodegradation facility has been designed and built, and a procedure has been developed for the measurement of J-V characterisation in well established conditions. This method is suitable for all kinds of solar cells, even for those for which no model is still available. The photodegradation and characterisation of some cells has allowed to validate both the new testing facility and method. (Author) 14 refs

  7. Frozen ponds

    DEFF Research Database (Denmark)

    Langer, M; Westermann, S.; Anthony, K. Walter

    2015-01-01

    to a warming climate are complex and only poorly understood. Small waterbodies have been attracting an increasing amount of attention since recent studies demonstrated that ponds can make a significant contribution to the CO2 and CH4emissions of tundra ecosystems. Waterbodies also have a marked effect...... on the thermal state of the surrounding permafrost; during the freezing period they prolong the period of time during which thawed soil material is available for microbial decomposition.  This study presents net CH4 production rates during the freezing period from ponds within a typical lowland tundra landscape...

  8. Production, characterization and stability of organic solar cell devices

    Energy Technology Data Exchange (ETDEWEB)

    Gevorgyan, S A

    2010-01-15

    Despite the fact that the field of organic photovoltaics (OPVs) is in a rapid progress, organic solar cells continue taking backstage roll in the growing markets of various solar technologies. The main challenge of the field is to develop devices that would possess all the optimal properties required for efficient, stable and cheap solar cells, i.e. devices that can deliver high photoconversion efficiencies and long lifetimes and can be efficiently produced in large scales using roll-to-roll coating technologies. This dissertation is primarily devoted to the issues of photoconversion efficiency and device lifetimes. In particular, descriptions of some practical approaches for different device designs and processing of active layer for typical small scale OPV devices were presented. The emphasis was put on some optimizing techniques for processing of active layer that can significantly improve the device photoconversion efficiency. The techniques were further applied for manufacturing and characterization of solar cell devices based on various materials. In particular, a number of thermocleavable polymers were studied and devices based on such materials were produced and characterized. The applicability of such materials in photovoltaic devices was shown and further challenges were discussed. Another task of this work was to manufacture and study inverted device structures and compare their properties with normal structure based devices. Device based on both structure were successfully produced with same level of performance in terms of photoconversion efficiency, yet with totally different stability performance. As another task, metal oxides, such as MoO{sub 3} or V{sub 2}O{sub 5} were studied in solar cell devices as buffer layers instead of PEDOT:PSS. Although the device efficiencies obtained with metal oxides were inferior to PEDOT based device, it was shown that such materials can possibly improve the device efficiency if the processing of the layers is

  9. Pathogens and fecal indicators in waste stabilization pond systems with direct reuse for irrigation: Fate and transport in water, soil and crops

    Energy Technology Data Exchange (ETDEWEB)

    Verbyla, M.E., E-mail: verbylam@mail.usf.edu [Department of Civil and Environmental Engineering, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL (United States); Iriarte, M.M.; Mercado Guzmán, A.; Coronado, O.; Almanza, M. [Centro de Aguas y Saneamiento Ambiental, Universidad Mayor de San Simón, Cochabamba (Bolivia, Plurinational State of); Mihelcic, J.R. [Department of Civil and Environmental Engineering, University of South Florida, 4202 E. Fowler Avenue, Tampa, FL (United States)

    2016-05-01

    Wastewater use for irrigation is expanding globally, and information about the fate and transport of pathogens in wastewater systems is needed to complete microbial risk assessments and develop policies to protect public health. The lack of maintenance for wastewater treatment facilities in low-income areas and developing countries results in sludge accumulation and compromised performance over time, creating uncertainty about the contamination of soil and crops. The fate and transport of pathogens and fecal indicators was evaluated in waste stabilization ponds with direct reuse for irrigation, using two systems in Bolivia as case studies. Results were compared with models from the literature that have been recommended for design. The removal of Escherichia coli in both systems was adequately predicted by a previously-published dispersed flow model, despite more than 10 years of sludge accumulation. However, a design equation for helminth egg removal overestimated the observed removal, suggesting that this equation may not be appropriate for systems with accumulated sludge. To assess the contamination of soil and crops, ratios were calculated of the pathogen and fecal indicator concentrations in soil or on crops to their respective concentrations in irrigation water (termed soil-water and crop-water ratios). Ratios were similar within each group of microorganisms but differed between microorganism groups, and were generally below 0.1 mL g{sup −1} for coliphage, between 1 and 100 mL g{sup −1} for Giardia and Cryptosporidium, and between 100 and 1000 mL g{sup −1} for helminth eggs. This information can be used for microbial risk assessments to develop safe water reuse policies in support of the United Nations' 2030 Sustainable Development Agenda. - Highlights: • Study of health risks from reclaimed wastewater irrigation from aging pond systems • Coliphages, protozoan parasites, and helminths were measured in water/soil/crops. • Sludge accumulation in

  10. Pathogens and fecal indicators in waste stabilization pond systems with direct reuse for irrigation: Fate and transport in water, soil and crops

    International Nuclear Information System (INIS)

    Verbyla, M.E.; Iriarte, M.M.; Mercado Guzmán, A.; Coronado, O.; Almanza, M.; Mihelcic, J.R.

    2016-01-01

    Wastewater use for irrigation is expanding globally, and information about the fate and transport of pathogens in wastewater systems is needed to complete microbial risk assessments and develop policies to protect public health. The lack of maintenance for wastewater treatment facilities in low-income areas and developing countries results in sludge accumulation and compromised performance over time, creating uncertainty about the contamination of soil and crops. The fate and transport of pathogens and fecal indicators was evaluated in waste stabilization ponds with direct reuse for irrigation, using two systems in Bolivia as case studies. Results were compared with models from the literature that have been recommended for design. The removal of Escherichia coli in both systems was adequately predicted by a previously-published dispersed flow model, despite more than 10 years of sludge accumulation. However, a design equation for helminth egg removal overestimated the observed removal, suggesting that this equation may not be appropriate for systems with accumulated sludge. To assess the contamination of soil and crops, ratios were calculated of the pathogen and fecal indicator concentrations in soil or on crops to their respective concentrations in irrigation water (termed soil-water and crop-water ratios). Ratios were similar within each group of microorganisms but differed between microorganism groups, and were generally below 0.1 mL g"−"1 for coliphage, between 1 and 100 mL g"−"1 for Giardia and Cryptosporidium, and between 100 and 1000 mL g"−"1 for helminth eggs. This information can be used for microbial risk assessments to develop safe water reuse policies in support of the United Nations' 2030 Sustainable Development Agenda. - Highlights: • Study of health risks from reclaimed wastewater irrigation from aging pond systems • Coliphages, protozoan parasites, and helminths were measured in water/soil/crops. • Sludge accumulation in ponds may limit

  11. Remoción de formas parasitarias intestinales en una laguna facultativa de estabilización en Lima, Perú Removal of intestinal parasitic forms in a facultative stabilization pond in Lima, Peru

    Directory of Open Access Journals (Sweden)

    José O. Iannacone

    2002-12-01

    Full Text Available The effectiveness of a waste stabilization pond, to remove intestinal helminth eggs and protozoan cysts was studied in San Martin de Porres, Lima, Peru. From September to October 2000 four collections of samples were performed from raw domestic wastewater and from contends of primary, secondary and tertiary ponds. A comparative study of performance of the concentrations methods of Ritchie and Faust was also done. The overall average removal of parasitic forms was as follow: 69.37% from raw water and primary pond; 48.34% from primary to secondary pond; 85.45% from secondary to tertiary pond and 97.69% from raw water to tertiary pond. There was no significant difference in the quantitative performance of Ritchic and Faust methods. Giardia duodenalis (Lambl, 1859 Alexeieff, 1914, Entamoeba coli (Gras, 1879 Casagrandi & Barbagallo, 1895 and Ascaris lumbricoides (Linnaeus, 1758 were detected with both methods. Three other parasites were detected only by Ritchie method: Taenia sp., Rodentolepis nana (von Siebold, 1852 Spasskii, 1954 and Trichuris trichiura (Linnaeus, 1771 Stiles, 1901 and only Faust detected Isospora belli Wenyon, 1923. Overall number of protozoa cysts was higher than the number of helminth eggs. At the end, wastewater had a concentration of 1.5 parasitic forms L¹ what is considered inappropríate for ultimate use in agriculture by current standards.

  12. Stability of tailings ponds in the mining district of Mazarron (SE Spain): potential risks for the Moreras Rambla; Estudio de estabilidad en depositos de lodos del Distrito Minero de Mazarron (SE Espana): Riesgos potenciales sobre la Rambla de Las Moreras

    Energy Technology Data Exchange (ETDEWEB)

    Acosta, J. A.; Martinez-Martinez, S.; Martinez-Pagan, P.; Zornoza, R.; Carmona, D. M.; Faz, A.

    2011-07-01

    We have used geochemical, geophysical and geotechnical techniques to identify and quantify the environmental risks of the San Cristobal and Las Moreras tailing ponds, which have been left since the closing down of Pb-Zn mining activities in a semi-arid Mediterranean area. The results show that the tailings ponds present a potential risk to nearby ecosystems because of their high acidity, high salinity and high concentrations of metals, especially Pb and Zn contain. If the pond dams were to fail or if erosion carried dry sludge to the surrounding areas, the result would be pollution, acidification, salinization, compaction and nutrient depletion of the soil, thus reducing the biodiversity of the area. Geoelectrical tomography has shown the depth of the deposits, their volume and the geomorphology of the basement. The profiles reveal that in none of the pseudo-sections are there any regions betraying cracks that might affect the stability of the structures. In fact, geotechnical studies indicate that on a large scale both ponds are stable. Nevertheless, if we contemplate circular rupture and seismic action in the San Cristobal pond, the safety factor values become critical. It is recommended, therefore, that periodic inspections should be carried out to assess moisture, upsurges and settlements in the dam. To reduce erosion of the surface sludge in the tailing ponds we suggest the application of alkaline and organic remediation so as to improve their geochemical characteristics and encourage the establishment of natural vegetation. (Author) 48 refs.

  13. A rational approach for evaluation and screening of treatment and disposal options for the solar pond sludges at Rocky Flats

    International Nuclear Information System (INIS)

    Dickerson, K.S.

    1995-01-01

    This document consists of information about the treatment options for the sludge that is located in the evaporation ponds at the Rocky Flats Plant. The sludges are mixed low-level radioactive wastes whose composition and character were variable. Sludges similar to these are typically treated prior to ultimate disposal. Disposal of treated sludges includes both on-site and off-site options. The rational approach described in this paper is useful for technology evaluation and screening because it provides a format for developing objectives, listing alternatives, and weighing the alternatives against the objectives and against each other

  14. A rational approach for evaluation and screening of treatment and disposal options for the solar pond sludges at Rocky Flats

    Energy Technology Data Exchange (ETDEWEB)

    Dickerson, K.S.

    1995-12-31

    This document consists of information about the treatment options for the sludge that is located in the evaporation ponds at the Rocky Flats Plant. The sludges are mixed low-level radioactive wastes whose composition and character were variable. Sludges similar to these are typically treated prior to ultimate disposal. Disposal of treated sludges includes both on-site and off-site options. The rational approach described in this paper is useful for technology evaluation and screening because it provides a format for developing objectives, listing alternatives, and weighing the alternatives against the objectives and against each other.

  15. Thermal evolutions of two kinds of melt pond with different salinity

    Science.gov (United States)

    Kim, Joo-Hong; Wilkinson, Jeremy; Moon, Woosok; Hwang, Byongjun; Granskog, Mats

    2016-04-01

    Melt ponds are water pools on sea ice. Their formation reduces ice surface albedo and alter surface energy balance, by which the ice melting and freezing processes are regulated. Thus, better understanding of their radiative characteristics has been vital to improve the simulation of melting/freezing of sea ice in numerical models. A melt pond would preserve nearly fresh water if it formed on multi-year ice and no flooding of sea water occurred, whereas a melt pond would contain more salty water if it formed on thinner and porous first-year ice, if there were an inflow of sea water by streams or cracks. One would expect that the fluid dynamic/thermodynamic properties (e.g., turbulence, stability, etc.) of pond water are influenced by the salinity, so that the response of pond water to any heat input (e.g., shortwave radiation) would be different. Therefore, better understanding of the salinity-dependent thermal evolution also has significant potential to improve the numerical simulation of the sea ice melting/freezing response to radiative thermal forcing. To observe and understand the salinity-dependent thermal evolution, two ice mass balance buoys (IMBs) were deployed in two kinds (fresh and salty) of melt pond on a same ice floe on 13 August 2015 during Araon Arctic cruise. The thermistor chain, extending from the air through the pond and ice into the sea water, was deployed through a drilled borehole inside the pond. Besides, the IMBs were also accompanied with three broadband solar radiation sensors (two (up and down) in the air over melt pond and one upward-looking under sea ice) to measure the net shortwave radiation at the pond surface and the penetrating solar radiation through ice. Also, the web camera was installed to observe any updates in the conditions of equipment and surrounding environment (e.g., weather, surface state, etc.). On the date of deployment, the fresh pond had salinity of 2.3 psu, light blue color, lots of slush ice particles which

  16. Toxigenic Vibrio cholerae O1 in vegetables and fish raised in wastewater irrigated fields and stabilization ponds during a non-cholera outbreak period in Morogoro, Tanzania

    DEFF Research Database (Denmark)

    Hounmanou, Yaovi M G; Mdegela, Robinson H; Dougnon, Tamègnon V

    2016-01-01

    gene (tcpA) and the haemolysin gene (hlyA). RESULTS: The prevalence of V. cholerae in wastewater, vegetables and fish was 36.7, 21.7 and 23.3 %, respectively. Two isolates from fish gills were V. cholerae O1 and tested positive for ctx and tcpA. One of these contained in addition the hlyA gene while......BACKGROUND: Cholera, one of the world's deadliest infectious diseases, remains rampant and frequent in Tanzania and thus hinders existing control measures. The present study was undertaken to evaluate the occurrence of toxigenic Vibrio cholerae O1 in wastewater, fish and vegetables during a non......-outbreak period in Morogoro, Tanzania. METHODS: From October 2014 to February 2015, 60 wastewater samples, 60 fish samples from sewage stabilization ponds and 60 wastewater irrigated vegetable samples were collected. Samples were cultured for identification of V. cholerae using conventional bacteriological...

  17. Stability of perovskite solar cells on flexible substrates

    Science.gov (United States)

    Tam, Ho Won; Chen, Wei; Liu, Fangzhou; He, Yanling; Leung, Tik Lun; Wang, Yushu; Wong, Man Kwong; Djurišić, Aleksandra B.; Ng, Alan Man Ching; He, Zhubing; Chan, Wai Kin; Tang, Jinyao

    2018-02-01

    Perovskite solar cells are emerging photovoltaic technology with potential for low cost, high efficiency devices. Currently, flexible devices efficiencies over 15% have been achieved. Flexible devices are of significant interest for achieving very low production cost via roll-to-roll processing. However, the stability of perovskite devices remains a significant challenge. Unlike glass substrate which has negligible water vapor transmission rate (WVTR), polymeric flexible film substrates suffer from high moisture permeability. As PET and PEN flexible substrates exhibit higher water permeability then glass, transparent flexible backside encapsulation should be used to maximize light harvesting in perovskite layer while WVTR should be low enough. Wide band gap materials are transparent in the visible spectral range low temperature processable and can be a moisture barrier. For flexible substrates, approaches like atomic layer deposition (ALD) and low temperature solution processing could be used for metal oxide deposition. In this work, ALD SnO2, TiO2, Al2O3 and solution processed spin-on-glass was used as the barrier layer on the polymeric side of indium tin oxide (ITO) coated PEN substrates. The UV-Vis transmission spectra of the prepared substrates were investigated. Perovskite solar cells will be fabricated and stability of the devices were encapsulated with copolymer films on the top side and tested under standard ISOS-L-1 protocol and then compared to the commercial unmodified ITO/PET or ITO/PEN substrates. In addition, devices with copolymer films laminated on both sides successfully surviving more than 300 hours upon continuous AM1.5G illumination were demonstrated.

  18. Environmental stability study of holographic solar spectrum splitting materials

    Science.gov (United States)

    Chrysler, Benjamin D.; Ayala Pelaez, Silvana; Wu, Yuechen; Vorndran, Shelby D.; Kostuk, Raymond K.

    2016-09-01

    In this study the impact of outdoor temperature variations and solar illumination exposure on spectral filter material and holographic optical elements is examined. Although holographic components have been shown to be useful for solar spectrum splitting designs, relatively little quantitative data exist to demonstrate the extent to which these materials can withstand outdoor conditions. As researchers seek to investigate practical spectrum splitting designs, the environmental stability of holographic materials should be considered as an important factor. In the experiment presented, two holographic materials, Covestro Bayfol HX photopolymer and dichromated gelatin, and 3M reflective polymer filter materials are exposed to outdoor conditions for a period of several months. The environmental effect on absorption, spectral and angular bandwidth, peak efficiency, and Bragg matching conditions for the holograms are examined. Spectral bandwidth and transmittance of the 3M reflective filter material are also monitored. Holographic gratings are recorded, measured, and mounted on glass substrates and then sealed with a glass cover plate. The test samples are then mounted on a photovoltaic panel to simulate realistic temperature conditions and placed at an outdoor test facility in Tucson, Arizona. A duplicate set of holograms and 3M filter material is stored as a control group and periodically compared over the test period.

  19. A new hybrid ocean thermal energy conversion–Offshore solar pond (OTEC–OSP) design: a cost optimization approach

    NARCIS (Netherlands)

    Straatman, P.J.T.; van Sark, W.G.J.H.M.

    2008-01-01

    Solar thermal electricity (STE) generation offers an excellent opportunity to supply electricity with a non-CO2 emitting technology. However, present costs hamper widespread deployment and therefore research and development efforts are concentrated on accelerated cost reductions and efficiency

  20. Removal of fecal indicators and pathogens in a waste stabilization pond system treating municipal wastewater in India.

    Science.gov (United States)

    Tyagi, Vinay Kumar; Kazmi, A A; Chopra, A K

    2008-11-01

    This study assess the removal of fecal indicators (i.e., total coliforms, fecal coliforms, E. coli, fecal streptococci, and pathogens [Salmonella sp. and helminth eggs]) in a full-scale facultative and maturation pond system with primary screening and manual grit removal facility. The capacity of the plant is 6 ML/d. The results showed that the system was able to remove approximately 2.0 to 3.5 log units of fecal indicators and almost 100% of helminth eggs. Meanwhile, Salmonella was not eliminated significantly, as only 1.26 log units removal was found. Removal efficiency of fecal indicator bacteria was reported maximum during summers (3.4 to 4.0 log units) and minimum (1.9 to 2.0 log units) in winters. Further efforts were made to seek the correlation between key physicochemical wastewater quality parameters (biochemical oxygen demand, turbidity, and suspended solids) and indicator microorganisms (total coliforms, fecal coliforms, and fecal streptococci). Among all these parameters, suspended solids showed the highest correlation coefficient (r2) with total coliforms (0.79), fecal coliforms (0.78), and fecal streptococci (0.75). These correlations manifest that the improvement of microbiological quality of wastewater is strongly linked to the removal of suspended solids.

  1. Quality assurance project plan for the Chestnut Ridge Fly Ash Pond Stabilization Project at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    International Nuclear Information System (INIS)

    1996-07-01

    The Chestnut Ridge Fly Ash Pond Stabilization (CRFAPS) Project will stabilize a 19-m-high (62-ft-high) earthen embankment across Upper McCoy Branch situated along the southern slope of Chestnut Ridge. This task will be accomplished by raising the crest of the embankment, reinforcing the face of the embankment, removing trees from the face and top of the embankment, and repairing the emergency spillway. The primary responsibilities of the team members are: Lockheed Martin Energy Systems, Inc., (Energy Systems) will be responsible for project integration, technical support, Title 3 field support, environmental oversight, and quality assurance (QA) oversight of the project; Foster Wheeler Environmental Corporation (FWENC) will be responsible for design and home office Title 3 support; MK-Ferguson of Oak Ridge Company (MK-F) will be responsible for health and safety, construction, and procurement of construction materials. Each of the team members has a QA program approved by the US Department of Energy (DOE) Oak Ridge Operations. This project-specific QA project plan (QAPP), which is applicable to all project activities, identifies and integrates the specific QA requirements from the participant's QA programs that are necessary for this project

  2. Biogeochemical ecology of aquaculture ponds

    International Nuclear Information System (INIS)

    Weisburd, R.S.J.

    1988-01-01

    Two methods to determine rates of organic matter production and consumption were applied in shrimp aquaculture ponds. Several questions were posed: can net rates of organic matter production and consumption be determined accurately through application of dissolved inorganic carbon (DIC) mass balance in a pond with high advective through-put? Are organically loaded aquaculture ponds autotrophic? How do rates of organic production vary temporally? Are there diurnal changes in respiration rates? Four marine ponds in Hawaii have been evaluated for a 53 day period through the use of geochemical mass balances. All fluxes of DIC into and out of the ponds were considered. DIC was calculated from hourly pH measurements and weekly alkalinity measurements. Average uptake of DIC from the pond water, equivalent to net community production, revealed net autotrophy in all cases. Hourly and longer period variations in organic matter production rates were examined. The daily cycle dominated the variation in rates of net community production. Maximal rates of net community production were maintained for four to six hours starting in mid-morning. Respiration rates decreased rapidly during the night in two of the ponds and remained essentially constant in the others. A similar pattern of decreasing respiration at night was seen in freshwater shrimp ponds which were studied with incubations. A new method involving isotope dilution of 14 C-labeled DIC was used to measure respiration rates in light and dark bottles. This method is an inexpensive and convenient procedure which should also be useful in other environments. The incubations demonstrated that plankton respiration rates peak at or soon after solar noon and vary over the course of the day by about a factor of two

  3. Waste Stabilisation Ponds

    OpenAIRE

    Von Sperling, Marcos

    2007-01-01

    "Waste Stabilisation Ponds is the third volume in the series Biological Wastewater Treatment. The major variants of pond systems are fully covered, namely: facultative ponds anaerobic ponds aerated lagoons maturation ponds The book presents in a clear and informative way the main concepts, working principles, expected removal efficiencies, design criteria, design examples, construction aspects, operational guidelines and sludge managment for pond systems. About the series: The series is...

  4. Long-term cover design for low-level radioactive and hazardous waste sites as applied to the Rocky Flats Environmental Technology Site solar evaporation ponds

    International Nuclear Information System (INIS)

    Stenseng, S.E.; Nixon, P.A.

    1996-01-01

    The US Department of Energy (DOE) operated five lined solar evaporation ponds (SEPs) at the Rocky Flats Environmental Technology Site (RFETS) in Jefferson County, Colorado from 1953 until 1986. The SEPs were used primarily to store and evaporate low-level radioactive and hazardous process wastes. Operation of the SEPs has resulted in contamination of the surrounding soils, and may also provide a source of groundwater contamination. The DOE proposes to close the SEPs by consolidating the contaminated material beneath an engineered cover. The primary objective of the closure of such hazardous and radioactive sites is to limit the exposure of the general public to the contaminants for time periods ranging from 100 to 10,000 years. The goal of the SEPs engineered cover is to isolate hazardous and low-level radioactive soils for a minimum of 1,000 years. Since there is currently no existing regulatory design guidance for a 1,000-year engineered cover, the proposed design of the SEPs engineered cover is based on research and testing that has been conducted for many years at various DOE facilities in the US. This paper discusses the main design theories of the proposed engineered cover for the closure of the SEPs, and how the research and test results of these other programs have been used to arrive at the final cover configuration, the material selections, the component layering, layer thicknesses, and the balance and interaction between components to establish an overall effective cover system

  5. A theoretical study of a direct contact membrane distillation system coupled to a salt-gradient solar pond for terminal lakes reclamation.

    Science.gov (United States)

    Suárez, Francisco; Tyler, Scott W; Childress, Amy E

    2010-08-01

    Terminal lakes are water bodies that are located in closed watersheds with the only output of water occurring through evaporation or infiltration. The majority of these lakes, which are commonly located in the desert and influenced by human activities, are increasing in salinity. Treatment options are limited, due to energy costs, and many of these lakes provide an excellent opportunity to test solar-powered desalination systems. This paper theoretically investigates utilization of direct contact membrane distillation (DCMD) coupled to a salt-gradient solar pond (SGSP) for sustainable freshwater production at terminal lakes. A model for heat and mass transport in the DCMD module and a thermal model for an SGSP were developed and coupled to evaluate the feasibility of freshwater production. The construction of an SGSP outside and inside of a terminal lake was studied. As results showed that freshwater flows are on the same order of magnitude as evaporation, these systems will only be successful if the SGSP is constructed inside the terminal lake so that there is little or no net increase in surface area. For the study site of this investigation, water production on the order of 2.7 x 10(-3) m(3) d(-1) per m(2) of SGSP is possible. The major advantages of this system are that renewable thermal energy is used so that little electrical energy is required, the coupled system requires low maintenance, and the terminal lake provides a source of salts to create the stratification in the SGSP. (c) 2010 Elsevier Ltd. All rights reserved.

  6. Western Wind and Solar Integration Study Phase 3 – Frequency Response and Transient Stability

    Energy Technology Data Exchange (ETDEWEB)

    Miller, N. W. [GE Energy Management, Schenectady, NY (United States); Shao, M. [GE Energy Management, Schenectady, NY (United States); Pajic, S. [GE Energy Management, Schenectady, NY (United States); D' Aquila, R. [GE Energy Management, Schenectady, NY (United States)

    2014-12-01

    Power system operators and utilities worldwide have concerns about the impact of high-penetration wind and solar generation on electric grid reliability (EirGrid 2011b, Hydro-Quebec 2006, ERCOT 2010). The stability of North American grids under these conditions is a particular concern and possible impediment to reaching future renewable energy goals. Phase 3 of the Western Wind and Solar Integration Study (WWSIS-3) considers a 33% wind and solar annual energy penetration level that results in substantial changes to the characteristics of the bulk power system, including different power flow patterns, different commitment and dispatch of existing synchronous generation, and different dynamic behavior of wind and solar generation. WWSIS-3 evaluates two specific aspects of fundamental frequency system stability: frequency response and transient stability.

  7. Enhancing Stability of Perovskite Solar Cells to Moisture by the Facile Hydrophobic Passivation.

    Science.gov (United States)

    Hwang, Insung; Jeong, Inyoung; Lee, Jinwoo; Ko, Min Jae; Yong, Kijung

    2015-08-12

    In this study, a novel and facile passivation process for a perovskite solar cell is reported. Poor stability in ambient atmosphere, which is the most critical demerit of a perovskite solar cell, is overcome by a simple passivation process using a hydrophobic polymer layer. Teflon, the hydrophobic polymer, is deposited on the top of a perovskite solar cell by a spin-coating method. With the hydrophobic passivation, the perovskite solar cell shows negligible degradation after a 30 day storage in ambient atmosphere. Suppressed degradation of the perovskite film is proved in various ways: X-ray diffraction, light absorption spectrum, and quartz crystal microbalance. This simple but effective passivation process suggests new kind of approach to enhance stability of perovskite solar cells to moisture.

  8. Lake or Pond WBID

    Data.gov (United States)

    Vermont Center for Geographic Information — The VT DEC (Vermont Department of Environmental Conservation) manages an inventory of lake and pond information. The "Lakes and Ponds Inventory" stores the Water...

  9. A generic interface to reduce the efficiency-stability-cost gap of perovskite solar cells

    Science.gov (United States)

    Hou, Yi; Du, Xiaoyan; Scheiner, Simon; McMeekin, David P.; Wang, Zhiping; Li, Ning; Killian, Manuela S.; Chen, Haiwei; Richter, Moses; Levchuk, Ievgen; Schrenker, Nadine; Spiecker, Erdmann; Stubhan, Tobias; Luechinger, Norman A.; Hirsch, Andreas; Schmuki, Patrik; Steinrück, Hans-Peter; Fink, Rainer H.; Halik, Marcus; Snaith, Henry J.; Brabec, Christoph J.

    2017-12-01

    A major bottleneck delaying the further commercialization of thin-film solar cells based on hybrid organohalide lead perovskites is interface loss in state-of-the-art devices. We present a generic interface architecture that combines solution-processed, reliable, and cost-efficient hole-transporting materials without compromising efficiency, stability, or scalability of perovskite solar cells. Tantalum-doped tungsten oxide (Ta-WOx)/conjugated polymer multilayers offer a surprisingly small interface barrier and form quasi-ohmic contacts universally with various scalable conjugated polymers. In a simple device with regular planar architecture and a self-assembled monolayer, Ta-WOx-doped interface-based perovskite solar cells achieve maximum efficiencies of 21.2% and offer more than 1000 hours of light stability. By eliminating additional ionic dopants, these findings open up the entire class of organics as scalable hole-transporting materials for perovskite solar cells.

  10. Treatment of pond sludge at the Rocky Flats Plant

    International Nuclear Information System (INIS)

    Wienand, J.; Tyler, R.; Baldwin, C.

    1992-01-01

    The treatment of low-level radioactive/hazardous materials sludges from five inactive solar evaporation settling ponds at the Rocky Flats Plant is discussed. The paper presents information on the following topics: history of the ponds; previous pond cleanout activities; current approach to the problem with respect to water management, sludge management, regulatory actions, and disposal; and future processing technology needs in the areas of polymer solidification, microwave solidification, joule-heated glass melters, and advanced technology incineration

  11. Technical manual for calculating cooling pond performance

    International Nuclear Information System (INIS)

    Krstulovich, S.F.

    1988-01-01

    This manual is produced in response to a growing number of requests for a technical aid to explain methods for simulating cooling pond performance. As such, it is a compilation of reports, charts and graphs developed through the years for use in analyzing situations. Section II contains a report summarizing the factors affecting cooling pond performance and lists statistical parameters used in developing performance simulations. Section III contains the graphs of simulated cooling pond performance on an hourly basis for various combinations of criteria (wind, solar, depth, air temperature and humidity) developed from the report in Section II. Section IV contains correspondence describing how to develop further data from the graphs in Section III, as well as mathematical models for the system of performance calculation. Section V contains the formulas used to simulate cooling pond performances in a cascade arrangement, such as the Fermilab Main Ring ponds. Section VI contains the calculations currently in use to evaluate the Main Ring pond performance based on current flows and Watts loadings. Section VII contains the overall site drawing of the Main Ring cooling ponds with thermal analysis and physical data

  12. Adaptive image stabilization of solar observations: A review

    International Nuclear Information System (INIS)

    Von Der Luhe, O.

    1985-01-01

    The purpose of this contribution is to review recent developments of active wave front correction techniques for solar imaging. Experience has shown, that image motion control significantly improves the resolution of typical long exposure applications such as spectrograms and spectroheliograms. Basic IM control systems need only simple technology and, in most cases, are easily implemented in most existing telescopes. Spot trackers are on their way to being routineously used

  13. Solar radiation pressure application for orbital motion stabilization near the Sun-Earth collinear libration point

    Science.gov (United States)

    Polyakhova, Elena; Shmyrov, Alexander; Shmyrov, Vasily

    2018-05-01

    Orbital maneuvering in a neighborhood of the collinear libration point L1 of Sun-Earth system has specific properties, primarily associated with the instability L1. For a long stay in this area of space the stabilization problem of orbital motion requires a solution. Numerical experiments have shown that for stabilization of motion it is requires very small control influence in comparison with the gravitational forces. On the other hand, the stabilization time is quite long - months, and possibly years. This makes it highly desirable to use solar pressure forces. In this paper we illustrate the solar sail possibilities for solving of stabilization problem in a neighborhood L1 with use of the model example.

  14. Superior stability for perovskite solar cells with 20% efficiency using vacuum co-evaporation.

    Science.gov (United States)

    Zhu, Xuejie; Yang, Dong; Yang, Ruixia; Yang, Bin; Yang, Zhou; Ren, Xiaodong; Zhang, Jian; Niu, Jinzhi; Feng, Jiangshan; Liu, Shengzhong Frank

    2017-08-31

    Chemical composition and film quality are two key figures of merit for large-area high-efficiency perovskite solar cells. To date, all studies on mixed perovskites have used solution-processing, which results in imperfect surface coverage and pin-holes generated during solvent evaporation, execrably influencing the stability and efficiency of perovskite solar cells. Herein, we report our development using a vacuum co-evaporation deposition method to fabricate pin-hole-free cesium (Cs)-substituted perovskite films with complete surface coverage. Apart from the simplified procedure, the present method also promises tunable band gap, reduced trap-state density and longer carrier lifetime, leading to solar cell efficiency as high as 20.13%, which is among the highest reported for planar perovskite solar cells. The splendid performance is attributed to superior merits of the Cs-substituted perovskite film including tunable band gap, reduced trap-state density and longer carrier lifetime. Moreover, the Cs-substituted perovskite device without encapsulation exhibits significantly higher stability in ambient air compared with the single-component counterpart. When the Cs-substituted perovskite solar cells are stored in dark for one year, the PCE remains at 19.25%, degrading only 4.37% of the initial efficiency. The excellent stability originates from reduced lattice constant and relaxed strain in perovskite lattice by incorporating Cs cations into the crystal lattice, as demonstrated by the positive peak shifts and reduced peak width in X-ray diffraction analysis.

  15. The color of melt ponds on Arctic sea ice

    Science.gov (United States)

    Lu, Peng; Leppäranta, Matti; Cheng, Bin; Li, Zhijun; Istomina, Larysa; Heygster, Georg

    2018-04-01

    Pond color, which creates the visual appearance of melt ponds on Arctic sea ice in summer, is quantitatively investigated using a two-stream radiative transfer model for ponded sea ice. The upwelling irradiance from the pond surface is determined and then its spectrum is transformed into RGB (red, green, blue) color space using a colorimetric method. The dependence of pond color on various factors such as water and ice properties and incident solar radiation is investigated. The results reveal that increasing underlying ice thickness Hi enhances both the green and blue intensities of pond color, whereas the red intensity is mostly sensitive to Hi for thin ice (Hi 1.5 m), similar to the behavior of melt-pond albedo. The distribution of the incident solar spectrum F0 with wavelength affects the pond color rather than its intensity. The pond color changes from dark blue to brighter blue with increasing scattering in ice, and the influence of absorption in ice on pond color is limited. The pond color reproduced by the model agrees with field observations for Arctic sea ice in summer, which supports the validity of this study. More importantly, the pond color has been confirmed to contain information about meltwater and underlying ice, and therefore it can be used as an index to retrieve Hi and Hp. Retrievals of Hi for thin ice (Hi measurements than retrievals for thick ice, but those of Hp are not good. The analysis of pond color is a new potential method to obtain thin ice thickness in summer, although more validation data and improvements to the radiative transfer model will be needed in future.

  16. Mechanical stability of roll-to-roll printed solar cells under cyclic bending and torsion

    DEFF Research Database (Denmark)

    Finn, Mickey; Martens, Christian James; Zaretski, Aliaksandr V.

    2018-01-01

    The ability of printed organic solar cells (OSCs) to survive repeated mechanical deformation is critical to large-scale implementation. This paper reports an investigation into the mechanical stability of OSCs through bending and torsion testing of whole printed modules. Two types of modules...

  17. Stability studies and degradation analysis of plastic solar cell materials by FTIR spectroscopy

    NARCIS (Netherlands)

    Neugebauer, H.; Brabec, C.J.; Hummelen, J.C.; Janssen, R.A.J.; Sariciftci, N.S.

    1999-01-01

    Results of controlled degradation experiments performed with the individual components and with the actual mixture used in plastic solar cells are shown. A testing procedure for the stability and for degradation effects under illumination in controlled atmosphere using FTIR-ATR spectroscopy is

  18. Recent Advances in Heliogyro Solar Sail Structural Dynamics, Stability, and Control Research

    Science.gov (United States)

    Wilkie, W. Keats; Warren, Jerry E.; Horta, Lucas G.; Lyle, Karen H.; Juang, Jer-Nan; Gibbs, S. Chad; Dowell, Earl H.; Guerrant, Daniel V.; Lawrence, Dale

    2015-01-01

    Results from recent NASA sponsored research on the structural dynamics, stability, and control characteristics of heliogyro solar sails are summarized. Specific areas under investigation include coupled nonlinear finite element analysis of heliogyro membrane blade with solar radiation pressure effects, system identification of spinning membrane structures, and solarelastic stability analysis of heliogyro solar sails, including stability during blade deployment. Recent results from terrestrial 1-g blade dynamics and control experiments on "rope ladder" membrane blade analogs, and small-scale in vacuo system identification experiments with hanging and spinning high-aspect ratio membranes will also be presented. A low-cost, rideshare payload heliogyro technology demonstration mission concept is used as a mission context for these heliogyro structural dynamics and solarelasticity investigations, and is also described. Blade torsional dynamic response and control are also shown to be significantly improved through the use of edge stiffening structural features or inclusion of modest tip masses to increase centrifugal stiffening of the blade structure. An output-only system identification procedure suitable for on-orbit blade dynamics investigations is also developed and validated using ground tests of spinning sub-scale heliogyro blade models. Overall, analytical and experimental investigations to date indicate no intractable stability or control issues for the heliogyro solar sail concept.

  19. Stability of organic molecules against shocks in the young Solar nebula

    NARCIS (Netherlands)

    Kamp, Inga; Milosavljevic, Milica; Stempels, E

    2009-01-01

    One of the fundamental astrobiology questions is how life has formed in our Solar System. In this context the formation and stability of abiotic organic molecules such as CH(4), formic acid and amino acids, is important for understanding how organic material has formed and survived shocks and

  20. Thermal Stability-Enhanced and High-Efficiency Planar Perovskite Solar Cells with Interface Passivation.

    Science.gov (United States)

    Zhang, Weihai; Xiong, Juan; Jiang, Li; Wang, Jianying; Mei, Tao; Wang, Xianbao; Gu, Haoshuang; Daoud, Walid A; Li, Jinhua

    2017-11-08

    As the electron transport layer (ETL) of perovskite solar cells, oxide semiconductor zinc oxide (ZnO) has been attracting great attention due to its relatively high mobility, optical transparency, low-temperature fabrication, and good environment stability. However, the nature of ZnO will react with the patron on methylamine, which would deteriorate the performance of cells. Although many methods, including high-temperature annealing, doping, and surface modification, have been studied to improve the efficiency and stability of perovskite solar cells with ZnO ETL, devices remain relatively low in efficiency and stability. Herein, we adopted a novel multistep annealing method to deposit a porous PbI 2 film and improved the quality and uniformity of perovskite films. The cells with ZnO ETL were fabricated at the temperature of perovskite film. Interestingly, the PCE of PCBM-passivated cells could reach nearly 19.1%. To our best knowledge, this is the highest PCE value of ZnO-based perovskite solar cells until now. More importantly, PCBM modification could effectively suppress the decomposition of MAPbI 3 and improve the thermal stability of cells. Therefore, the ZnO is a promising candidate of electron transport material for perovskite solar cells in future applications.

  1. Photochemical stability of π-conjugated polymers for polymer solar cells: a rule of thumb

    DEFF Research Database (Denmark)

    Manceau, Matthieu; Bundgaard, Eva; Carlé, Jon Eggert

    2011-01-01

    A comparative photochemical stability study of a wide range of π-conjugated polymers relevant to polymer solar cells is presented. The behavior of each material has been investigated under simulated sunlight (1 sun, 1000 W m−2, AM 1.5G) and ambient atmosphere. Degradation was monitored during age...... ageing combining UV-visible and infrared spectroscopies. From the comparison of the collected data, the influence of the polymer chemical structure on its stability has been discussed. General rules relative to the polymer structure–stability relationship are proposed....

  2. Stability of electric characteristics of solar cells for continuous power supply

    Directory of Open Access Journals (Sweden)

    Stojanović Nebojša M.

    2015-01-01

    Full Text Available This paper investigates the output characteristics of photovoltaic solar cells working in hostile working conditions. Examined cells, produced by different innovative procedures, are available in the market. The goal was to investigate stability of electric characteristics of solar cells, which are used today in photovoltaic solar modules for charging rechargeable batteries which, coupled with batteries, supply various electronic systems such as radio repeaters on mountains tops, airplanes, mobile communication stations and other remote facilities. Charging of rechargeable batteries requires up to 25 % higher voltage compared to nominal output voltage of the battery. This paper presents results of research of solar cells, which also apply to cases in which continuous power supply is required. [Projekat Ministarstva nauke Republike Srbije, br. III 171007

  3. The nekhoroshev theorem and long-term stabilities in the solar system

    Directory of Open Access Journals (Sweden)

    Guzzo M.

    2015-01-01

    Full Text Available The Nekhoroshev theorem has been often indicated in the last decades as the reference theorem for explaining the dynamics of several systems which are stable in the long-term. The Solar System dynamics provides a wide range of possible and useful applications. In fact, despite the complicated models which are used to numerically integrate realistic Solar System dynamics as accurately as possible, when the integrated solutions are chaotic the reliability of the numerical integrations is limited, and a theoretical long-term stability analysis is required. After the first formulation of Nekhoroshev’s theorem in 1977, many theoretical improvements have been achieved. On the one hand, alternative proofs of the theorem itself led to consistent improvements of the stability estimates; on the other hand, the extensions which were necessary to apply the theorem to the systems of interest for Solar System Dynamics, in particular concerning the removal of degeneracies and the implementation of computer assisted proofs, have been developed. In this review paper we discuss some of the motivations and the results which have made Nekhoroshev’s theorem a reference stability result for many applications in the Solar System dynamics.

  4. Hydrophobic Polystyrene Passivation Layer for Simultaneously Improved Efficiency and Stability in Perovskite Solar Cells.

    Science.gov (United States)

    Li, Minghua; Yan, Xiaoqin; Kang, Zhuo; Huan, Yahuan; Li, Yong; Zhang, Ruxiao; Zhang, Yue

    2018-06-06

    The major restraint for the commercialization of the high-performance hybrid metal halide perovskite solar cells is the long-term stability, especially at the infirm interface between the perovskite film and organic charge-transfer layer. Recently, engineering the interface between the perovskite and spiro-OMeTAD becomes an effective strategy to simultaneously improve the efficiency and stability in the perovskite solar cells. In this work, we demonstrated that introducing an interfacial polystyrene layer between the perovskite film and spiro-OMeTAD layer can effectively improve the perovskite solar cells photovoltaic performance. The inserted polystyrene layer can passivate the interface traps and defects effectively and decrease the nonradiative recombination, leading to enhanced photoluminescence intensity and carrier lifetime, without compromising the carrier extraction and transfer. Under the optimized condition, the perovskite solar cells with the polystyrene layer achieve an enhanced average power efficiency of about 19.61% (20.46% of the best efficiency) from about 17.63% with negligible current density-voltage hysteresis. Moreover, the optimized perovskite solar cells with the hydrophobic polystyrene layer can maintain about 85% initial efficiency after 2 months storage in open air conditions without encapsulation.

  5. Degradation and stability of R2R manufactured polymer solar cells

    DEFF Research Database (Denmark)

    Norrman, Kion; Krebs, Frederik C

    2009-01-01

    Polymer solar cells have many advantages such as light weight, flexibility, environmental friendliness, low thermal budget, low cost and most notably very fast modes of production by printing techniques. Production experiments have shown that it is highly feasible with existing technology to mass...... produce polymer solar cells at a very low cost. We have employed state-of-the-art analytical techniques to address the challenging issues of degradation and stability of R2R manufactured devices. We have specifically studied the relative effect of oxygen and water on the operational devices in regard...

  6. Developing Ecological Models on Carbon and Nitrogen in Secondary Facultative Ponds

    Directory of Open Access Journals (Sweden)

    Aponte-Reyes Alexander

    2014-07-01

    Full Text Available Ecological models formulated for TOC, CO2, NH4+, NO3- and NTK, based in literature reviewed and field work were obtained monitoring three facultative secondary stabilization ponds, FSSP, pilots: conventional pond, CP, baffled pond, BP, and baffled-meshed pond, BMP. Models were sensitive to flow inlet, solar radiation, pH and oxygen content; the sensitive parameters in Carbon Model were KCOT Ba, umax Ba, umax Al, K1OX, VAl, R1DCH4, YBh. The sensitive parameters in the Nitrogen model were KCOT Ba, umax Ba, umax Al, VAl, KOPH, KOPA, r4An. The test t–paired showed a good simulating of Carbon model refers to TOC in FSSP; on the other side, the Nitrogen model showed a good simulating of NH4+. Different topological models modify ecosystem ecology forcing different transformation pathways of Nitrogen; equal transformations of the Carbon BMP topology could be achieved using lower volumes, however, a calibration for a new model would be required. Carbon and Nitrogen models developed could be coupled to hydrodynamics models for better modeling of FSSP.

  7. Analysis to long-term stability of solar cables; Untersuchungen zur Langzeitstabilitaet von Solarleitungen

    Energy Technology Data Exchange (ETDEWEB)

    Funtan, P.

    2005-07-01

    For the moment it is not possible to say anything about the long-term stability of solar cables. Own experiences shows, that the rubber solar cable H07 RN-F (of one manufacturer) is not qualified for installations, longer than 10 years. The outer isolation of the cable first shows embrittlements and later deep cracks. Microscopically analysis confirms this. Measurements of temperature in typical installation areas of solar cables also shows, that the influence of temperature, regarding aging plays not the most important role, when the cable is installed in a sun protected position. Up to now the reason of the cable destruction is not definitely clarified. Chemically analysis of a damaged and an intact part of the cable, which was installed inside of a module junction box (reduced humility), shows no differences in the chemical consistence. It seems, that it is a combinated effect of temperature and humidity. Further analysis will be performed. (orig.)

  8. Regional Climate Impacts of Stabilizing Global Warming at 1.5 K Using Solar Geoengineering

    Science.gov (United States)

    Jones, Anthony C.; Hawcroft, Matthew K.; Haywood, James M.; Jones, Andy; Guo, Xiaoran; Moore, John C.

    2018-02-01

    The 2015 Paris Agreement aims to limit global warming to well below 2 K above preindustrial levels, and to pursue efforts to limit global warming to 1.5 K, in order to avert dangerous climate change. However, current greenhouse gas emissions targets are more compatible with scenarios exhibiting end-of-century global warming of 2.6-3.1 K, in clear contradiction to the 1.5 K target. In this study, we use a global climate model to investigate the climatic impacts of using solar geoengineering by stratospheric aerosol injection to stabilize global-mean temperature at 1.5 K for the duration of the 21st century against three scenarios spanning the range of plausible greenhouse gas mitigation pathways (RCP2.6, RCP4.5, and RCP8.5). In addition to stabilizing global mean temperature and offsetting both Arctic sea-ice loss and thermosteric sea-level rise, we find that solar geoengineering could effectively counteract enhancements to the frequency of extreme storms in the North Atlantic and heatwaves in Europe, but would be less effective at counteracting hydrological changes in the Amazon basin and North Atlantic storm track displacement. In summary, solar geoengineering may reduce global mean impacts but is an imperfect solution at the regional level, where the effects of climate change are experienced. Our results should galvanize research into the regionality of climate responses to solar geoengineering.

  9. Research Update: Strategies for improving the stability of perovskite solar cells

    Directory of Open Access Journals (Sweden)

    Severin N. Habisreutinger

    2016-09-01

    Full Text Available The power-conversion efficiency of perovskite solar cells has soared up to 22.1% earlier this year. Within merely five years, the perovskite solar cell can now compete on efficiency with inorganic thin-film technologies, making it the most promising of the new, emerging photovoltaic solar cell technologies. The next grand challenge is now the aspect of stability. The hydrophilicity and volatility of the organic methylammonium makes the work-horse material methylammonium lead iodide vulnerable to degradation through humidity and heat. Additionally, ultraviolet radiation and oxygen constitute stressors which can deteriorate the device performance. There are two fundamental strategies to increasing the device stability: developing protective layers around the vulnerable perovskite absorber and developing a more resilient perovskite absorber. The most important reports in literature are summarized and analyzed here, letting us conclude that any long-term stability, on par with that of inorganic thin-film technologies, is only possible with a more resilient perovskite incorporated in a highly protective device design.

  10. Par Pond water balance

    International Nuclear Information System (INIS)

    Hiergesell, R.A.; Dixon, K.L.

    1996-06-01

    A water budget for the Par Pond hydrologic system was established in order to estimate the rate of groundwater influx to Par Pond. This estimate will be used in modeling exercises to predict Par Pond reservoir elevation and spillway discharge in the scenario where Savannah River water is no longer pumped and discharged into Par Pond. The principal of conservation of mass was used to develop the water budget, where water inflow was set equal to water outflow. Components of the water budget were identified, and the flux associated with each was determined. The water budget was considered balanced when inflow and outflow summed to zero. The results of this study suggest that Par Pond gains water from the groundwater system in the upper reaches of the reservoir, but looses water to the groundwater system near the dam. The rate of flux of groundwater from the water table aquifer into Par Pond was determined to be 13 cfs. The rate of flux from Par Pond to the water table aquifer near the dam was determined to be 7 cfs

  11. Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20%

    Science.gov (United States)

    Arora, Neha; Dar, M. Ibrahim; Hinderhofer, Alexander; Pellet, Norman; Schreiber, Frank; Zakeeruddin, Shaik Mohammed; Grätzel, Michael

    2017-11-01

    Perovskite solar cells (PSCs) with efficiencies greater than 20% have been realized only with expensive organic hole-transporting materials. We demonstrate PSCs that achieve stabilized efficiencies exceeding 20% with copper(I) thiocyanate (CuSCN) as the hole extraction layer. A fast solvent removal method enabled the creation of compact, highly conformal CuSCN layers that facilitate rapid carrier extraction and collection. The PSCs showed high thermal stability under long-term heating, although their operational stability was poor. This instability originated from potential-induced degradation of the CuSCN/Au contact. The addition of a conductive reduced graphene oxide spacer layer between CuSCN and gold allowed PSCs to retain >95% of their initial efficiency after aging at a maximum power point for 1000 hours under full solar intensity at 60°C. Under both continuous full-sun illumination and thermal stress, CuSCN-based devices surpassed the stability of spiro-OMeTAD-based PSCs.

  12. Wide band gap solar cells with high stabilized performance. Annual technical report, 15 July 1995--15 July 1996

    Energy Technology Data Exchange (ETDEWEB)

    Wronski, C R; Collins, R W; Fujiwara, H [Pennsylvania State Univ., University Park, PA (United States); and others

    1997-01-01

    This report describes work on an improved understanding of stability in materials and silicon solar cells. Topics include novel intrinsic materials optimization; solar cells optimized for p- and i-layer performance; novel p-type materials; interfaces; and device modeling.

  13. Validation Hydrodynamic Models of Three Topological Models of Secondary Facultative Ponds

    OpenAIRE

    Aponte-Reyes Alxander

    2014-01-01

    A methodology was developed to analyze boundary conditions, the size of the mesh and the turbulence of a mathematical model of CFD, which could explain hydrodynamic behavior on facultative stabilization ponds, FSP, built to pilot scale: conventional pond, CP, baffled pond, BP, and baffled-mesh pond, BMP. Models dispersion studies were performed in field for validation, taking samples into and out of the FSP, the information was used to carry out CFD model simulations of the three topologies. ...

  14. The Colloidal Stabilization of Quantum Dots: Towards Manufacturable, Efficient Solution-Processed Solar Cells

    Science.gov (United States)

    Rollny, Lisa

    Understanding colloidal stabilization can influence the design of optoelectronic devices and enable improvements to their performance and stability. For photovoltaics, important characteristics of the active layer material are high conductivity along with a minimum of recombination centers. In order to capitalize on the benefits of solution-processed materials, it is important to minimize the number of processing steps: ideally, to achieve a low-cost solution, materials would be deposited using a single process step compatible with roll-to-roll manufacturing. Prior to this work, the highest-performing colloidal quantum dots (CQD) solar cells have relied on several deposition steps that are repeated in a layer-by-layer (LBL) fashion. The purpose of these process steps has been to remove the long insulating ligands used in synthesis and replace them with short ligands that allow electrical conduction. The large number of steps combined, typically implemented via spin coating, leads to inefficient materials utilization and fails to show a path to a manufacturable solution. In this work, the first CQD solar cells were designed, built, and characterized combining state-of-art performance with scalable manufacture. Firstly, I report the first automated CQD synthesis to result in CQDs that form high-performance CQD solar cells. I analyze the CQD synthesis and by separating it into two phases---nucleation and growth phase---my insights are used to create higher-quality CQDs exhibiting enhanced monodispersity. I then proceed to develop a CQD ink: a CQD solution ready for direct deposition to form a semiconducting film exhibiting low trap state density. In early trials the CQD ink showed only limited power conversion efficiencies of 2%. I designed a new ink strategy, which I term cleavable hemiketal ligands. This novel two-component ligand strategy enables the combination of colloidal stabilization (via this longer two-component ligand) and cleavability (enabling excellent

  15. Estimation of Melt Ponds over Arctic Sea Ice using MODIS Surface Reflectance Data

    Science.gov (United States)

    Ding, Y.; Cheng, X.; Liu, J.

    2017-12-01

    Melt ponds over Arctic sea ice is one of the main factors affecting variability of surface albedo, increasing absorption of solar radiation and further melting of snow and ice. In recent years, a large number of melt ponds have been observed during the melt season in Arctic. Moreover, some studies have suggested that late spring to mid summer melt ponds information promises to improve the prediction skill of seasonal Arctic sea ice minimum. In the study, we extract the melt pond fraction over Arctic sea ice since 2000 using three bands MODIS weekly surface reflectance data by considering the difference of spectral reflectance in ponds, ice and open water. The preliminary comparison shows our derived Arctic-wide melt ponds are in good agreement with that derived by the University of Hamburg, especially at the pond distribution. We analyze seasonal evolution, interannual variability and trend of the melt ponds, as well as the changes of onset and re-freezing. The melt pond fraction shows an asymmetrical growth and decay pattern. The observed melt ponds fraction is almost within 25% in early May and increases rapidly in June and July with a high fraction of more than 40% in the east of Greenland and Beaufort Sea. A significant increasing trend in the melt pond fraction is observed for the period of 2000-2017. The relationship between melt pond fraction and sea ice extent will be also discussed. Key Words: melt ponds, sea ice, Arctic

  16. Performance and stability of P3HT/PCBM bulk heterojunction organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Yumnam, Nivedita; Bom, Sidhant; Wagner, Veit [School of Engineering and Science, Jacobs University Bremen, Campus Ring 1, 28759 Bremen (Germany)

    2011-07-01

    Organic photovoltaic cells are promising candidates for large-area, low-cost production of solar cells. However, the low stability in conjunction with their medium performance is one of the major drawbacks in comparison to their inorganic counterparts. In this investigation environmental conditions for degradation of bulk heterojunction P3HT/PCBM solar cells are systematically analyzed over a period of one week. Devices were prepared by spin coating from different compositions of P3HT and PCBM in Chlorobenzene (C{sub 6}H{sub 5}Cl). Performance parameters, efficiency and I-V characteristics were determined in a N{sub 2} glove box showing optimized efficiency for a 1:1 ratio. Degradation behavior in N{sub 2} atmosphere, vacuum and solvent-enriched atmosphere (Chlorobenzene) showed best results for vacuum stored solar cells while for solvent-enriched atmosphere rapid degradation was observed. Remarkable degradation (open-circuit voltage and short-circuit current reduced to 90% and 60% after one week) was also found for N{sub 2} atmosphere of the glove box used for the solar cell production. Residual solvent vapor left dispersed in the atmosphere of the glovebox after the spin coating process is identified as an important parameter of this degradation.

  17. Stability of zinc phthalocyanine and fullerene C{sub 60} organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Lessmann, Rudolf

    2010-05-10

    Organic solar cells promise electricity generation at very low cost, and higher installation flexibility as compared to inorganic solar cells. The lower cost is achieved by cheaper semiconductors and easier manufacturing processes. The flexibility is naturally given by these ultra-thin, amorphous layers. Also the power conversion efficiency can be high enough for many applications. The organic molecules have to withstand the constant excitation by photons, transport of energy in form of excitons and charge. A small but significant amount of these photons has energy over the absorption gap, the excess of energy must be released without breaking the molecular bonds. In consequence, the solar cells can also heat up to temperatures at above 80 C. The objective of this work is to answer the question if the small molecules organic solar cells can be stable enough to operate under a very long time. The stability of organic doped layers in an organic solar cell is also addressed. This work starts with a general introduction followed by the description of the experimental procedures. The aging experiments of the solar cell were done with a self developed equipment. The fabrication of this equipment (a set of measurement boxes) was necessary to maintain the conditions, under which a solar cell can be aged, as constant as possible. The measurement boxes were used to control the electrical load of the cell, its temperature, the illumination intensity, and its electric connection to the I vs. V measurement equipment. A software package was also developed to control the equipment and to facilitate the work and visualization of the high volume of collected data. The model solar cells chosen for the aging experiments were donor-acceptor heterojunctions devices formed with the well-known materials C{sub 60} and ZnPc. Two basic different structures were analyzed, because they offered reasonable performance and potentially long lifetime: the flat heterojunction (FHJ) and the mixed

  18. Designing of new structure PID controller of boost converter for solar photovoltaic stability

    Science.gov (United States)

    Shabrina, Hanifati Nur; Setiawan, Eko Adhi; Sabirin, Chip Rinaldi

    2017-03-01

    Nowadays, the utilization of renewable energy as the source on distributed generation system is increasing. It aims to reduce reliance and power losses from utility grid and improve power stability in near loads. One example of renewable energy technology that have been highly proven on the market is solar photovoltaic (PV). This technology converts photon from sunlight into electricity. However, the fluctuation of solar radiation that often occurs become the main problem for this system. Due to this condition, the power conversion is needed to convert the change frequently in photovoltaic panel into a stable voltage to the system. Developing control of boost converter has important role to keep ability of system stabilization. A conventional PID (Proportional, Integral, Derivative) control is mostly used to achieve this goal. In this research, a design of new structure PID controller of boost converter is offered to better optimize system stability comparing to the conventional PID. Parameters obtained from this PID structure have been successfully yield a stable boost converter output at 200 V with 10% overshoot, 1.5 seconds of settling time, and 1.5% of steady-state error.

  19. An inter-laboratory stability study of roll-to-roll coated flexible polymer solar modules

    DEFF Research Database (Denmark)

    Gevorgyan, Suren; Medford, Andrew James; Bundgaard, Eva

    2011-01-01

    A large number of flexible polymer solar modules comprising 16 serially connected individual cells was prepared at the experimental workshop at Risø DTU. The photoactive layer was prepared from several varieties of P3HT (Merck, Plextronics, BASF and Risø DTU) and two varieties of ZnO (nanoparticu......A large number of flexible polymer solar modules comprising 16 serially connected individual cells was prepared at the experimental workshop at Risø DTU. The photoactive layer was prepared from several varieties of P3HT (Merck, Plextronics, BASF and Risø DTU) and two varieties of Zn......O (nanoparticulate, thin film) were employed as electron transport layers. The devices were all tested at Risø DTU and the functional devices were subjected to an inter-laboratory study involving the performance and the stability of modules over time in the dark, under light soaking and outdoor conditions. 24...

  20. Film Grain-Size Related Long-Term Stability of Inverted Perovskite Solar Cells.

    Science.gov (United States)

    Chiang, Chien-Hung; Wu, Chun-Guey

    2016-09-22

    The power conversion efficiency (PCE) of the perovskite solar cell is high enough to be commercially viable. The next important issue is the stability of the device. This article discusses the effect of the perovskite grain-size on the long-term stability of inverted perovskite solar cells. Perovskite films composed of various sizes of grains were prepared by controlling the solvent annealing time. The grain-size related stability of the inverted cells was investigated both in ambient atmosphere at relative humidity of approximately 30-40 % and in a nitrogen filled glove box (H 2 Operovskite film having the grain size larger than 1 μm (D-10) decreases less than 10 % with storage in a glove box and less than 15 % when it was stored under an ambient atmosphere for 30 days. However, the cell using the perovskite film composed of small (∼100 nm) perovskite grains (D-0) exhibits complete loss of PCE after storage under the ambient atmosphere for only 15 days and a PCE loss of up to 70 % with storage in the glove box for 30 days. These results suggest that, even under H 2 O-free conditions, the chemical- and thermal-induced production of pin holes at the grain boundaries of the perovskite film could be the reason for long-term instability of inverted perovskite solar cells. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Photocharge accumulation and recombination in perovskite solar cells regarding device performance and stability

    Science.gov (United States)

    Li, Yusheng; Li, Yiming; Shi, Jiangjian; Li, Hongshi; Zhang, Huiyin; Wu, Jionghua; Li, Dongmei; Luo, Yanhong; Wu, Huijue; Meng, Qingbo

    2018-01-01

    Photocharge accumulation and recombination in perovskite solar cells have been systematically investigated in this paper by electrochemical spectroscopy and transient photocurrent/photovoltage methods. It is found that the non-equilibrium photocharges stored in the selective charge transport layers follow a backward recombination mechanism. That is, the photocharges are first captured by the interface defects corresponding to the fast photovoltage decay, while the bulk charge recombination instead of the diffusion process dominates the slow photovoltage decay process. Further investigation reveals that the device degradation preferentially takes place at the interface under working conditions, which thus can confirm the importance of interface engineering to enhance the device stability.

  2. Film thickness and chemical processing effects on the stability of cadmium telluride solar cells

    International Nuclear Information System (INIS)

    Albin, D.S.; Demtsu, S.H.; McMahon, T.J.

    2006-01-01

    The performance and stability of CdS/CdTe solar cells as a function of layer thickness, back contact etch, and oxygen during the CdCl 2 anneal was determined. Multiple linear regression models were used to analyze the statistical significance of various first order effects and interactions. With stress, all devices showed a reduction in open-circuit voltage (V oc ) and fill factor (FF) characteristic of increased recombination. Devices using thinner CdS were vulnerable to shunt formation. Oxygen during the CdCl 2 anneal minimizes this effect. A thermodynamic model involving the formation of Cu-oxide is presented to explain the latter

  3. Analytical Prediction of the Spin Stabilized Satellite's Attitude Using The Solar Radiation Torque

    International Nuclear Information System (INIS)

    Motta, G B; Carvalho, M V; Zanardi, M C

    2013-01-01

    The aim of this paper is to present an analytical solution for the spin motion equations of spin-stabilized satellite considering only the influence of solar radiation torque. The theory uses a cylindrical satellite on a circular orbit and considers that the satellite is always illuminated. The average components of this torque were determined over an orbital period. These components are substituted in the spin motion equations in order to get an analytical solution for the right ascension and declination of the satellite spin axis. The time evolution for the pointing deviation of the spin axis was also analyzed. These solutions were numerically implemented and compared with real data of the Brazilian Satellite of Data Collection – SCD1 an SCD2. The results show that the theory has consistency and can be applied to predict the spin motion of spin-stabilized artificial satellites

  4. A Deeper Understanding of Stability in the Solar Wind: Applying Nyquist's Instability Criterion to Wind Faraday Cup Data

    Science.gov (United States)

    Alterman, B. L.; Klein, K. G.; Verscharen, D.; Stevens, M. L.; Kasper, J. C.

    2017-12-01

    Long duration, in situ data sets enable large-scale statistical analysis of free-energy-driven instabilities in the solar wind. The plasma beta and temperature anisotropy plane provides a well-defined parameter space in which a single-fluid plasma's stability can be represented. Because this reduced parameter space can only represent instability thresholds due to the free energy of one ion species - typically the bulk protons - the true impact of instabilities on the solar wind is under estimated. Nyquist's instability criterion allows us to systematically account for other sources of free energy including beams, drifts, and additional temperature anisotropies. Utilizing over 20 years of Wind Faraday cup and magnetic field observations, we have resolved the bulk parameters for three ion populations: the bulk protons, beam protons, and alpha particles. Applying Nyquist's criterion, we calculate the number of linearly growing modes supported by each spectrum and provide a more nuanced consideration of solar wind stability. Using collisional age measurements, we predict the stability of the solar wind close to the sun. Accounting for the free-energy from the three most common ion populations in the solar wind, our approach provides a more complete characterization of solar wind stability.

  5. Stability of dye-sensitized solar cells under extended thermal stress.

    Science.gov (United States)

    Yadav, Surendra K; Ravishankar, Sandheep; Pescetelli, Sara; Agresti, Antonio; Fabregat-Santiago, Francisco; Di Carlo, Aldo

    2017-08-23

    In the last few decades, dye-sensitized solar cell (DSC) technology has been demonstrated to be a promising candidate for low cost energy production due to cost-effective materials and fabrication processes. Arguably, DSC stability is the biggest challenge for making this technology appealing for industrial exploitation. This work provides further insight into the stability of DSCs by considering specific dye-electrolyte systems characterized by Raman and impedance spectroscopy analysis. In particular, two ruthenium-based dyes, Z907 and Ru505, and two commercially available electrolytes, namely, the high stability electrolyte (HSE) and solvent-free Livion 12 (L-12), were tested. After 4700 h of thermal stress at 85 °C, the least stable device composed of Z907/HSE showed an efficiency degradation rate of ∼14%/1000 h, while the Ru505/L-12 system retained 96% of its initial efficiency by losing ∼1% each 1000 h. The present results show a viable route to stabilize the DSC technology under prolonged annealing conditions complying with the IEC standard requirements.

  6. 100 °C Thermal Stability of Printable Perovskite Solar Cells Using Porous Carbon Counter Electrodes.

    Science.gov (United States)

    Baranwal, Ajay K; Kanaya, Shusaku; Peiris, T A Nirmal; Mizuta, Gai; Nishina, Tomoya; Kanda, Hiroyuki; Miyasaka, Tsutomu; Segawa, Hiroshi; Ito, Seigo

    2016-09-22

    Many efforts have been made towards improving perovskite (PVK) solar cell stability, but their thermal stability, particularly at 85 °C (IEC 61646 climate chamber tests), remains a challenge. Outdoors, the installed solar cell temperature can reach up to 85 °C, especially in desert regions, providing sufficient motivation to study the effect of temperature stress at or above this temperature (e.g., 100 °C) to confirm the commercial viability of PVK solar cells for industrial companies. In this work, a three-layer printable HTM-free CH 3 NH 3 PbI 3 PVK solar cell with a mesoporous carbon back contact and UV-curable sealant was fabricated and tested for thermal stability over 1500 h at 100 °C. Interestingly, the position of the UV-curing glue was found to drastically affect the device stability. The side-sealed cells show high PCE stability and represent a large step toward commercialization of next generation organic-inorganic lead halide PVK solar cells. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. A new photocrosslinkable oligothiophene for organic solar cells with enhanced stability

    Energy Technology Data Exchange (ETDEWEB)

    Lanzi, Massimiliano, E-mail: massimiliano.lanzi@unibo.it [Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale Risorgimento 4, 40136 Bologna (Italy); Salatelli, Elisabetta; Di-Nicola, Francesco Paolo; Zuppiroli, Luca [Department of Industrial Chemistry “Toso Montanari”, University of Bologna, Viale Risorgimento 4, 40136 Bologna (Italy); Pierini, Filippo [Department of Mechanics and Physics of Fluids, Institute of Fundamental Technological Research, Polish Academy of Sciences, ul. Pawinskiego 5B, 02-106 Warsaw (Poland)

    2017-01-15

    A novel thiophenic tetramer containing a cinnamate group in the side chain with a functionalization degree of 50% is reported. The tetramer was obtained by means of a simple and straightforward procedure involving the functionalization of a p-methoxyphenoxy substituted thiophenic precursor, which led to a soluble product with a good yield. The oligomer was fully characterized from a structural and chemical point of view and employed for the fabrication of small molecule organic solar cells exploiting the bulk heterojunction (BHJ) architecture. The presence of an UV-light sensitive group in the tetramer allowed the photocrosslinking of tetramer/PCBM blends, giving high values of photocurrent and conversion efficiency for the exposed samples. Moreover, the UV-treated devices showed improved stability, even upon heating for three days at 130 °C, thus confirming that photocrosslinking can strongly reduce phase segregation under severe operational conditions. - Graphical abstract: 3D-visualization of a T4CIN/PCBM layer portion. - Highlights: • A photocrosslinkable thiophenic electron-donor oligomer has been synthesized. • It has been characterized and used to prepare BHJ SMO Solar Cells. • Cells electrical performances and thermal stabilities have been evaluated. • A comparison between UV-cured and pristine cells has been made.

  8. Cooling pond fog studies

    International Nuclear Information System (INIS)

    Hicks, B.B.

    1978-01-01

    The Fog Excess Water Index (FEWI) method of fog prediction has been verified by the use of data obtained at the Dresden cooling pond during 1976 and 1977 and by a reanalysis of observations made in conjunction with a study of cooling pond simulators during 1974. For applications in which the method is applied to measurements or estimates of bulk water temperature, a critical value of about 0.7 mb appears to be most appropriate. The present analyses confirm the earlier finding that wind speed plays little part in determining the susceptibility for fog generation

  9. Decontamination and decommissioning of the BORAX-V leach pond. Final report

    International Nuclear Information System (INIS)

    Smith, D.L.

    1985-01-01

    This report describes the decontamination and decommissioning (D and D) of the BORAX-V leach pond located at the Idaho National Engineering Laboratory (INEL). The leach pond became radioactively contaminated from the periodic discharge of low-level liquid waste during operation of the Boiling Water Reactor Experiments (BORAX) from 1954 to 1964. This report describes work performed to accomplish the D and D objectives of stabilizing the leach pond and preventing the spread of contamination. D and D of the BORAX-V leach pond consisted to backfilling the pond with clean soil, grading and seeding the area, and erecting a permanent marker to identify very low-level subsurface contamination

  10. Renewable energy for the aeration of wastewater ponds.

    Science.gov (United States)

    Hobus, I; Hegemann, W

    2003-01-01

    The application of a decentralised renewable energy supply for the aeration of wastewater ponds, and the influence of an unsteady oxygen supply on the specific conversion rate and biocoenose was investigated. With the discontinuous aeration the specific conversion rate is increased as compared to facultative ponds. The estimation of the microorganisms consortia was done with in situ hybridisation techniques. A significant shift in the bacteria population with the chosen specific probes for anaerobic, sulphate reducing and nitrifying bacteria could not be detected. Wastewater ponds have sufficient buffer volume to compensate for the fluctuating energy supply. But the efficiency of the energy supply of a photovoltaic plant decreases in shallow lakes (d photovoltaic and wind power plant, energy management, aeration system and wastewater pond, a simulation model was developed and tested. The application of renewable energy for the aeration of wastewater ponds is a useful alternative for the redevelopment of overloaded ponds as well as the construction of new wastewater ponds, especially in areas with an inadequate central electricity grid and a high availability of wind and solar energy.

  11. Solar-blind wurtzite MgZnO alloy films stabilized by Be doping

    International Nuclear Information System (INIS)

    Su, Longxing; Zhu, Yuan; Zhang, Quanlin; Chen, Mingming; Ji, Xu; Wu, Tianzhun; Gui, Xuchun; Xiang, Rong; Tang, Zikang; Pan, Bicai

    2013-01-01

    Mg x Zn 1−x O alloy films were deposited on c-plane sapphire substrates by radio frequency plasma-assisted molecular beam epitaxy (rf-PMBE). The phase segregation occurred when x was larger than 33%. Be doping was found experimentally able to stabilize the high-Mg-content MgZnO alloy. By alloying 1–2% Be into MgZnO, the band gap of as-prepared quaternary alloys can be raised to the solar-blind range (4.5 eV). Calculated formation energy of the alloys based on first principle reveals that a small amount of Be incorporation can reduce the formation energy of high-Mg-content MgZnO alloys and results in a more stable system, which justifies our experimental observations. (paper)

  12. Effects of Annealing Conditions on Mixed Lead Halide Perovskite Solar Cells and Their Thermal Stability Investigation.

    Science.gov (United States)

    Yang, Haifeng; Zhang, Jincheng; Zhang, Chunfu; Chang, Jingjing; Lin, Zhenhua; Chen, Dazheng; Xi, He; Hao, Yue

    2017-07-21

    In this work, efficient mixed organic cation and mixed halide (MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃) perovskite solar cells are demonstrated by optimizing annealing conditions. AFM, XRD and PL measurements show that there is a better perovskite film quality for the annealing condition at 100 °C for 30 min. The corresponding device exhibits an optimized PCE of 16.76% with V OC of 1.02 V, J SC of 21.55 mA/cm² and FF of 76.27%. More importantly, the mixed lead halide perovskite MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃ can significantly increase the thermal stability of perovskite film. After being heated at 80 °C for 24 h, the PCE of the MA 0.7 FA 0.3 Pb(I 0.9 Br 0.1 )₃ device still remains at 70.00% of its initial value, which is much better than the control MAPbI₃ device, where only 46.50% of its initial value could be preserved. We also successfully fabricated high-performance flexible mixed lead halide perovskite solar cells based on PEN substrates.

  13. Outdoor Operational Stability of Indium-Free Flexible Polymer Solar Modules Over 1 Year Studied in India, Holland, and Denmark

    DEFF Research Database (Denmark)

    Angmo, Dechan; Sommeling, Paul M.; Gupta, Ritu

    2014-01-01

    We present an outdoor interlaboratory stability study of fully printed and coated indium-tin-oxide (ITO)-free polymer solar cell modules in JNCASR Bangalore (India), ECN (Holland), and DTU (Denmark) carried over more than 1 year. The modules comprising a fully printed and coated stack (Ag grid...

  14. A roll-to-roll process to flexible polymer solar cells: model studies, manufacture and operational stability studies

    DEFF Research Database (Denmark)

    Krebs, Frederik C; Gevorgyan, Suren; Alstrup, Jan

    2009-01-01

    An inverted polymer solar cell geometry comprising a total of five layers was optimized using laboratory scale cells and the operational stability was studied under model atmospheres. The device geometry was substrate-ITO-ZnO-(active layer)-PEDOT:PSS-silver with P3HT-PCBM as the active layer. The...

  15. Solar India - 82: national solar energy convention

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    This document is the proceedings of the Solar India - 82 conference, which was held 17-19 December 1982. The papers are organized into functional groupings which include: (1) solar radiation, (2) flat plate solar collectors and solar water heaters, (3) solar concentrators, (4) solar air heaters and dryers, (5) solar ponds and energy storage, (6) solar cookers, (7) solar stills, (8) selective coatings, (9) photovoltaics, (10) space heating and cooling, (11) bio-energy, and (12) miscellaneous papers. The vast majority of the papers describe work carried out in India, the vast majority of the papers also contain relatively readable abstracts.

  16. Interface engineering of perovskite solar cells with multifunctional polymer interlayer toward improved performance and stability

    Science.gov (United States)

    Huang, Li-Bo; Su, Pei-Yang; Liu, Jun-Min; Huang, Jian-Feng; Chen, Yi-Fan; Qin, Su; Guo, Jing; Xu, Yao-Wei; Su, Cheng-Yong

    2018-02-01

    This work proposes a new perovskite solar cell structure by inserting a polymer interlayer between perovskite and hole transporting material (HTM) to minimize the interface losses via interface engineering. The multifunctional interlayers improve the photovoltaic efficiency and device stability by shielding perovskite from moisture, suppressing charge combination, and promoting hole transport. The five different polymer layers are utilized to investigate the relationships of polymer structure, layer morphology and cell performance systematically. It is found that a reliable power conversion efficiency exceeding 19.0% is realized based on P3HT/spiro-OMeTAD composite structure, surpassing that of pure spiro-OMeTAD (15.0%). Moreover, the device with P3HT interlayer shows more brilliant long-term stability than that without interlayer when exposed into moisture. The enhanced device performance based on P3HT interlayer compared with the other polymers can be ascribed to the long hydrophobic alkyl chains and the small molecule monomers of P3HT, which contribute to self-assembly of the polymers into insulating layers and formation of the efficient π-π stacking in polymer/spiro-OMeTAD interface simultaneously. This study provides a practical route for the integration of a new class of easily-accessible, solution-processed interfacial polymer materials for high-performance and long-time stable PSC.

  17. Stable amorphous semiconductors for solar cells. Final report; Stabile amorphe Halbleiterfilme fuer Solarzellen. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Fuhs, W.; Lips, K.; Mell, H.; Stachowitz, R.; Will, S.; Ulber, I.

    1997-12-31

    This study was founded on the preceding projects. The main objective was the preparation and characterization of stable amorphous silicon films (a-Si:H) by plasma enhanced chemical vapor deposition (PECVD). For this purpose the deposition conditions were varied in a wide range. The main effort was on the change of the reactor geometry and the increase of the substrate temperature to values beyond 250 C. Comparative studies of the film stability were carried out using different degradation techniques. The electronic and structural properties of the films were investigated with the aim to find correlations between the stability and other film properties. Information on the defect density was obtained from electron spin resonance (ESR), photothermal deflection spectroscopy (PDS) and photocurrent spectroscopy (CPM). The influence of native and light-induced defects on the recombination kinetics was studied using both films and solar cells. The techniques mainly used for that were steady-state and frequency-resolved photoluminescence spectroscopy (FRS) and electrically detected magnetic resonance (EDMR). The results of these studies were published in international journals and presented at international conferences. (orig.) [Deutsch] Das Vorhaben baute auf den vorangegangenen Projekten auf. Wichtigstes Ziel war die Herstellung und Charakterisierung stabiler amorpher Siliziumfilme (a-Si:H) durch Plasmadeposition. Dazu wurden die Depositionsbedingungen in einem weiten Bereich variiert. Im Vordergrund standen dabei die Aenderung der Reaktorgeometrie und die Erhoehung der Substrattemperatur auf Werte oberhalb von 250 C. Die Stabilitaet der Filme wurde mit verschiedenen Degradationsverfahren vergleichend geprueft. Die Filme wurden hinsichtlich ihrer elektronischen und strukturellen Eigenschaften mit dem Ziel untersucht, einen Zusammenhang zwischen der Stabilitaet und anderen Probeneigenschaften aufzufinden. Als Messverfahren fuer die Defektdichte standen

  18. VIIRS Reflective Solar Band Radiometric and Stability Evaluation Using Deep Convective Clouds

    Science.gov (United States)

    Chang, Tiejun; Xiong, Xiaoxiong; Mu, Qiaozhen

    2016-01-01

    This work takes advantage of the stable distribution of deep convective cloud (DCC) reflectance measurements to assess the calibration stability and detector difference in Visible Infrared Imaging Radiometer Suite (VIIRS) reflective bands. VIIRS Sensor Data Records (SDRs) from February 2012 to June 2015 are utilized to analyze the long-term trending, detector difference, and half angle mirror (HAM) side difference. VIIRS has two thermal emissive bands with coverage crossing 11 microns for DCC pixel identification. The comparison of the results of these two processing bands is one of the indicators of analysis reliability. The long-term stability analysis shows downward trends (up to approximately 0.4 per year) for the visible and near-infrared bands and upward trends (up to 0.5per year) for the short- and mid-wave infrared bands. The detector difference for each band is calculated as the difference relative to the average reflectance overall detectors. Except for the slightly greater than 1 difference in the two bands at 1610 nm, the detector difference is less than1 for other solar reflective bands. The detector differences show increasing trends for some short-wave bands with center wavelengths from 400 to 600 nm and remain unchanged for the bands with longer center wavelengths. The HAM side difference is insignificant and stable. Those short-wave bands from 400 to 600 nm also have relatively larger HAM side difference, up to 0.25.Comparing the striped images from SDR and the smooth images after the correction validates the analyses of detector difference and HAM side difference. These analyses are very helpful for VIIRS calibration improvement and thus enhance product quality

  19. Integrated Application of the UASB Reactor and Ponds for Domestic Sewage Treatment in Tropical Regions

    NARCIS (Netherlands)

    Cavalcanti, P.F.F.

    2003-01-01

    Waste stabilization ponds are widely applied for domestic sewage treatment in Brazil. The main objective of conventional waste stabilisation ponds (WSP's) is, nomen est omen , to remove the organic material from wastewater. To achieve this objective, a quite long liquid retention time (

  20. Procedures and practices for evaluating thin-film solar cell stability

    NARCIS (Netherlands)

    Roesch, R; Faber, T; von Hauff, E.L.; Brown, T. M.; Lira-Cantu, M.; Hoppe, H.

    2015-01-01

    During the last few decades, and in some cases only the last few years, novel thin-film photovoltaic (PV) technologies such as dye-sensitized solar cells (DSSC), organic solar cells (OPV), and, more recently, perovskite-based solar cells (PSC) have been growing in maturity with respect to device

  1. Polymer materials for roll coated solar cells: strategies tom improve performance and stability

    DEFF Research Database (Denmark)

    Heckler, Ilona Maria

    Solar cells are among the renewable energy technologies with a large potential in terms of solar energy availability. The solar cells based on conjugated polymers belong to the third generation of this technology and their attractive features include a fast and cheap solution‐processed production...

  2. The Pond Is Our Laboratory

    Science.gov (United States)

    Marchewka, Barbara Turco

    1978-01-01

    This science teacher's laboratory is a pond within walking distance of his school that provides a stimulating environment for exploring the natural world. With simple materials students practice making careful observations, taking measurements and compiling and graphing information for their science studies. They also extend their pond experiences…

  3. Dynamic voltage stability of a distribution system with high penetration of grid-connected photovoltaic type solar generators

    Directory of Open Access Journals (Sweden)

    Zetty Adibah Kamaruzzaman

    2016-06-01

    Full Text Available This paper presents the impact of grid-connected photovoltaic (PV generator on dynamic voltage stability of a power distribution system by considering solar intermittency, PV penetration level, and contingencies such as line outage and load increase. The IEEE 13 node test feeder is used as a test system, and a solar PV of 0.48 kV/0.5 MVA is integrated into the test system. Test results show that system voltage is stable at high PV penetration levels. Increase in load causes voltage instability, in which voltage drops below its allowable operating limit. Thus, increase in PV penetration level does not improve system voltage stability because the system experiences voltage collapse during line outage.

  4. Enhanced planar perovskite solar cell efficiency and stability using a perovskite/PCBM heterojunction formed in one step.

    Science.gov (United States)

    Zhou, Long; Chang, Jingjing; Liu, Ziye; Sun, Xu; Lin, Zhenhua; Chen, Dazheng; Zhang, Chunfu; Zhang, Jincheng; Hao, Yue

    2018-02-08

    Perovskite/PCBM heterojunctions are efficient for fabricating perovskite solar cells with high performance and long-term stability. In this study, an efficient perovskite/PCBM heterojunction was formed via conventional sequential deposition and one-step formation processes. Compared with conventional deposition, the one-step process was more facile, and produced a perovskite thin film of substantially improved quality due to fullerene passivation. Moreover, the resulting perovskite/PCBM heterojunction exhibited more efficient carrier transfer and extraction, and reduced carrier recombination. The perovskite solar cell device based on one-step perovskite/PCBM heterojunction formation exhibited a higher maximum PCE of 17.8% compared with that from the conventional method (13.7%). The device also showed exceptional stability, retaining 83% of initial PCE after 60 days of storage under ambient conditions.

  5. A Review on Current Status of Stability and Knowledge on Liquid Electrolyte-Based Dye-Sensitized Solar Cells

    Directory of Open Access Journals (Sweden)

    Frédéric Sauvage

    2014-01-01

    Full Text Available The purpose of this review is to gather the current background in materials development and provide the reader with an accurate image of today’s knowledge regarding the stability of dye-sensitized solar cells. This contribution highlights the literature from the 1970s to the present day on nanostructured TiO2, dye, Pt counter electrode, and liquid electrolyte for which this review is focused on.

  6. Description of work for 216-U-Pond cone penetrometer demonstration

    International Nuclear Information System (INIS)

    Kelty, G.G.

    1993-01-01

    This description of work details the Proposed field activities associated with Cone Penetrometer (CPT) work at the 216-U-10 Pond (U-10 Pond) in the 200 West Area and will serve as a field guide for those performing the work. The U-10 Pond was constructed in 1944 to receive low-level liquid effluent from the various chemical reprocessing facilities within the 200 West Area. The U-10 Pond covered 30 acres and received approximately 4.3 x 10 10 gal of contaminated liquid. Sampling conducted in 1980 indicated that the most significant radionuclides were 90 Sr, 137 Cs, plutonium, and uranium (DOE-RL 1993). The pond was deactivated and stabilized in 1985 with clean fill dirt. The thickness of the stabilization cover is variable across the former pond and ranges between 2 ft near the pond margins and delta area to 8 feet in the deepest section of the pond. The purpose of this work is to establish the extent of contamination beneath the U-10 pond

  7. Geohydrology and limnology of Walden Pond, Concord, Massachusetts

    Science.gov (United States)

    Colman, John A.; Friesz, Paul J.

    2001-01-01

    nitrogen inputs (858 kilograms per year) were dominated (30 percent) by plume water from the septic leach field and, possibly, by swimmers (34 percent). Phosphorus inputs (32 kilograms per year) were dominated by atmospheric dry deposition, background ground water, and estimated swimmer inputs. Swimmer inputs may represent more than 50 percent of the phosphorus load during the summer. The septic-system plume did not contribute phosphorus, but increased the nitrogen to phosphorus ratio for inputs from 41 to 59, on an atom-to-atom basis. The ratio of nitrogen to phosphorus in input loads and within the lake indicated algal growth would be strongly phosphorus limited. Nitrogen supply in excess of plant requirements may mitigate against nitrogen fixing organisms including undesirable blooms of cyanobacteria. Based on areal nutrient loading, Walden Pond is a mesotrophic lake. Hypolimnetic oxygen demand of Walden Pond has increased since a profile was measured in 1939. Currently (1999), the entire hypolimnion of Walden Pond becomes devoid of dissolved oxygen before fall turnover in late November; whereas historical data indicated dissolved oxygen likely remained in the hypolimnion during 1939. The complete depletion of dissolved oxygen likely causes release of phosphorus from the sediments. Walden Pond contains a large population of the deep-growing benthic macro alga Nitella, which has been hypothesized to promote water clarity in other clear-water lakes by sequestering nutrients and keeping large areas of the sediment surface oxygenated. Loss of Nitella populations in other lakes has correlated with a decline in water quality. Although the Nitella standing crop is large in Walden Pond, Nitella still appears to be controlled by nutrient availability. Decreasing phosphorus inputs to Walden Pond, by amounts under anthropogenic control would likely contribute to the stability of the Nitella population in the metalimnion, may reverse oxygen depletion in the hypolimnion, and decreas

  8. The Salt-Gradient Solar Pond.

    Science.gov (United States)

    1983-02-01

    X rGP)**2H1*(DEFH+X1 UP)(i... X CP( *(E-’PfH+XTGP]/lo) 10851) y 1000)i(IC tZE*X~GT*0.) 109001 11110 D( I )= (,,+* IELT *PtH1 ( 2) 2/ .o+4LX ) ( I.’(Q...2.*LLX**2)( I.-(0*DRbT)/(DELX 12100 _. D *42)) +PhI()+((* iELT )/(2.*(.ELA*42) ))PHI(T-1)+(EELT/2.. -1 2 3 0 9 ... . . .... ---(1 I

  9. DYNAMIC STABILITY OF THE SOLAR SYSTEM: STATISTICALLY INCONCLUSIVE RESULTS FROM ENSEMBLE INTEGRATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Zeebe, Richard E., E-mail: zeebe@soest.hawaii.edu [School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, 1000 Pope Road, MSB 629, Honolulu, HI 96822 (United States)

    2015-01-01

    Due to the chaotic nature of the solar system, the question of its long-term stability can only be answered in a statistical sense, for instance, based on numerical ensemble integrations of nearby orbits. Destabilization of the inner planets, leading to close encounters and/or collisions can be initiated through a large increase in Mercury's eccentricity, with a currently assumed likelihood of ∼1%. However, little is known at present about the robustness of this number. Here I report ensemble integrations of the full equations of motion of the eight planets and Pluto over 5 Gyr, including contributions from general relativity. The results show that different numerical algorithms lead to statistically different results for the evolution of Mercury's eccentricity (e{sub M}). For instance, starting at present initial conditions (e{sub M}≃0.21), Mercury's maximum eccentricity achieved over 5 Gyr is, on average, significantly higher in symplectic ensemble integrations using heliocentric rather than Jacobi coordinates and stricter error control. In contrast, starting at a possible future configuration (e{sub M}≃0.53), Mercury's maximum eccentricity achieved over the subsequent 500 Myr is, on average, significantly lower using heliocentric rather than Jacobi coordinates. For example, the probability for e{sub M} to increase beyond 0.53 over 500 Myr is >90% (Jacobi) versus only 40%-55% (heliocentric). This poses a dilemma because the physical evolution of the real system—and its probabilistic behavior—cannot depend on the coordinate system or the numerical algorithm chosen to describe it. Some tests of the numerical algorithms suggest that symplectic integrators using heliocentric coordinates underestimate the odds for destabilization of Mercury's orbit at high initial e{sub M}.

  10. Solar Spots - Activities to Introduce Solar Energy into the K-8 Curricula.

    Science.gov (United States)

    Longe, Karen M.; McClelland, Michael J.

    Following an introduction to solar technology which reviews solar heating and cooling, passive solar systems (direct gain systems, thermal storage walls, sun spaces, roof ponds, and convection loops), active solar systems, solar electricity (photovoltaic and solar thermal conversion systems), wind energy, and biomass, activities to introduce solar…

  11. Critical analysis of stability and performance of organometal halide perovskite solar cells via various fabrication method (Review

    Directory of Open Access Journals (Sweden)

    Suhaimi Suriati

    2017-01-01

    Full Text Available Organometal halide perovskite solar cells (Omh-PSCs have attracted attention due to its unique electrical and optical properties. Ideally, the Omh-PSCs should remain free from degradation under normal operating conditions for several years, preferably tens of years. In order to produce high power conversion efficiency with low potential of degradation, different fabrication methods have been developed. The reported stability of perovskite films can vary significantly and reported to decay substantially up to 20% of its original performance. A thorough understanding of fabrication process upon the stability of the device is regarded as crucial to pave the way for future endeavors. This review summarized and highlighted the recent research of fabrication methods that gave an impact to the stability of perovskite devices.

  12. A dissipative model of solar system and stability of stationary rotations

    Science.gov (United States)

    Vilke, V. G.

    2009-04-01

    In classical model of Solar system the planets are represented by the material points cooperating under the law of universal gravitation. This model remains fair if planet to consider as absolutely rigid spheres with spherical distribution of density. The gravitational potential of such body coincides with potential of a material point, and rotation of each sphere concerning his centre of mass occurs to constant angular velocity. The motion of the centers of mass of spherical planets identically to motion in the appropriate problem of points. Let's notice, that forms of planets of Solar system are close to spherical as dominant forces at formation of planets are gravitational forces to which forces of molecular interaction in substance of a planet counteract. The model of the isolated Solar system submitted in a not indignant condition by homogeneous viscoelastic spheres is considered. Under action of own rotation and tidal gravitational forces the spherical planet changes the shape: there is "flattening" of a planet in a direction of a vector of its angular velocity and formation of tidal bulgs on the lines connecting the centre of a planet with the centers of other planets. From a variational principle of Hamilton the full system of the equations describing movements of the centers of mass of planets, rotations of systems of coordinates, by integrated image connected with planets, and deformations of planets be relative these of systems of coordinates has been obtained. It is supposed, that tidal gravitational, centrifugal and elastic forces result in small change of the spherical form of a planet. In system there are small parameters - inversely proportional of the Young modules of materials of the planets, providing small deformations of planets at influence on them of the centrifugal forces produced by own rotation of planets, and the small tidal deformations arising under influence of gradients of gravitational forces. The method of division of movements

  13. Optimizing P3HT/PCBM/MWCNT films for increased stability in polymer bulk heterojunction solar cells

    International Nuclear Information System (INIS)

    Singh, Vinamrita; Arora, Swati; Arora, Manoj; Sharma, Vishal; Tandon, R.P.

    2014-01-01

    The effect of multi-walled carbon nanotubes on the properties of P3HT:PCBM based solar cells has been studied. The concentration of MWCNT was optimized at 0.2% and the concentration of P3HT:PCBM was increased from 20mg/ml to 30mg/ml to obtain highest efficiency. An increase in charge carrier mobility was also observed, which is attributed to high charge transport properties of MWCNT. The active layer was optically stable with respect to absorption, whereas the emission spectra revealed an increase in charge recombination with time. The solar cells doped with MWCNT exhibited increased stability as compared to undoped cells. - Highlights: • MWCNT doped P3HT:PCBM based solar cells are optimized for increased efficiency. • Degradation studies showed that MWCNT stabilizes the cell performance. • Mobility and basic device characteristics decreased with time. • Photoluminescence studies with time showed an increase in charge recombination. • Degradation for devices kept in air is faster as compared to the samples in vacuum

  14. Optimizing P3HT/PCBM/MWCNT films for increased stability in polymer bulk heterojunction solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Vinamrita [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Arora, Swati, E-mail: drswatia@yahoo.com [Department of Physics, Zakir Husain Delhi College, University of Delhi, Delhi 110002 (India); Arora, Manoj [Department of Physics, Ramjas College, University of Delhi, Delhi 110007 (India); Sharma, Vishal; Tandon, R.P. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

    2014-08-22

    The effect of multi-walled carbon nanotubes on the properties of P3HT:PCBM based solar cells has been studied. The concentration of MWCNT was optimized at 0.2% and the concentration of P3HT:PCBM was increased from 20mg/ml to 30mg/ml to obtain highest efficiency. An increase in charge carrier mobility was also observed, which is attributed to high charge transport properties of MWCNT. The active layer was optically stable with respect to absorption, whereas the emission spectra revealed an increase in charge recombination with time. The solar cells doped with MWCNT exhibited increased stability as compared to undoped cells. - Highlights: • MWCNT doped P3HT:PCBM based solar cells are optimized for increased efficiency. • Degradation studies showed that MWCNT stabilizes the cell performance. • Mobility and basic device characteristics decreased with time. • Photoluminescence studies with time showed an increase in charge recombination. • Degradation for devices kept in air is faster as compared to the samples in vacuum.

  15. Arctic melt ponds and energy balance in the climate system

    Science.gov (United States)

    Sudakov, Ivan

    2017-02-01

    Elements of Earth's cryosphere, such as the summer Arctic sea ice pack, are melting at precipitous rates that have far outpaced the projections of large scale climate models. Understanding key processes, such as the evolution of melt ponds that form atop Arctic sea ice and control its optical properties, is crucial to improving climate projections. These types of critical phenomena in the cryosphere are of increasing interest as the climate system warms, and are crucial for predicting its stability. In this paper, we consider how geometrical properties of melt ponds can influence ice-albedo feedback and how it can influence the equilibria in the energy balance of the planet.

  16. Diffusion of single oxidation pond

    Directory of Open Access Journals (Sweden)

    Song Ruo-Yuan

    2016-01-01

    Full Text Available The hydraulic characteristic of an oxidation pond was studied by the tracer experiment, and an empirical formula of Peclet number was obtained, which can be well applied to the model of plug flow reactor with longitudinal diffusion.

  17. Par Pond vegetation status 1996

    International Nuclear Information System (INIS)

    Mackey, H.E. Jr.; Riley, R.S.

    1996-12-01

    The water level of Par Pond was lowered approximately 20 feet in mid-1991 in order to protect downstream residents from possible dam failure suggested by subsidence on the downstream slope of the dam and to repair the dam. This lowering exposed both emergent and nonemergent macrophyte beds to drying conditions resulting in extensive losses. A survey of the newly emergent, shoreline aquatic plant communities of Par Pond began in June 1995, three months after the refilling of Par Pond to approximately 200 feet above mean sea level. These surveys continued in July, September, and late October, 1995, and into the early spring and late summer of 1996. Communities similar to the pre-drawdown, Par Pond aquatic plant communities continue to become re-established. Emergent beds of maidencane, lotus, waterlily, watershield, and Pontederia are extensive and well developed. Measures of percent cover, width of beds, and estimates of area of coverage with satellite data indicate regrowth within two years of from 40 to 60% of levels prior to the draw down. Cattail occurrence continued to increase during the summer of 1996, especially in the former warm arm of Par Pond, but large beds common to Par Pond prior to the draw down still have not formed. Lotus has invaded and occupies many of the areas formerly dominated by cattail beds. To track the continued development of macrophytes in Par Pond, future surveys through the summer and early fall of 1997, along with the evaluation of satellite data to map the extent of the macrophyte beds of Par Pond, are planned

  18. 2101-M pond closure plan

    International Nuclear Information System (INIS)

    1993-06-01

    This document describes activities for the closure of a surface impoundment (2101-M Pond) at the Hanford Site. The 2101-H Pond was initially constructed in 1953 to serve as a drainage collection area for the 2101-H Building. (Until the Basalt Waste Isolation Project (BWIP) Laboratory was constructed in the 2101-M Building in 1979--1981, the only source contributing discharge to the pond was condensate water from the 2101-H Building heating, ventilation, and air conditioning (HVAC) system. The drains for the BWIP Laboratory rooms were plumbed into a 4-in., cast-iron, low-pressure drain pipe that carries waste water from the HVAC system to the pond. During the active life of the BWIP Laboratory, solutions of dissolved barium in groundwater samples were discharged to the 2101-M Pond via the laboratory drains. As a result of the discharges, a Part A permit application was initially submitted to the Washington State Department of Ecology (Ecology) in August 1986 which designates the 2101-M Pond as a surface impoundment

  19. Enhanced thermal stability of a polymer solar cell blend induced by electron beam irradiation in the transmission electron microscope

    Energy Technology Data Exchange (ETDEWEB)

    Bäcke, Olof, E-mail: obacke@chalmers.se [Department of Applied Physics, Chalmers University of Technology, 41296 Göteborg (Sweden); Lindqvist, Camilla; Diaz de Zerio Mendaza, Amaia [Department of Chemistry and Chemical Engineering, Chalmers University of Technology, 41296 Göteborg (Sweden); Gustafsson, Stefan [Department of Applied Physics, Chalmers University of Technology, 41296 Göteborg (Sweden); Wang, Ergang; Andersson, Mats R.; Müller, Christian [Department of Chemistry and Chemical Engineering, Chalmers University of Technology, 41296 Göteborg (Sweden); Kristiansen, Per Magnus [Institute of Polymer Nanotechnology (INKA), FHNW University of Applied Science and Arts Northwestern Switzerland, 5210 Windisch (Switzerland); Laboratory for Micro- and Nanotechnology, Paul Scherrer Institute, 5232 Villigen (Switzerland); Olsson, Eva, E-mail: eva.olsson@chalmers.se [Department of Applied Physics, Chalmers University of Technology, 41296 Göteborg (Sweden)

    2017-05-15

    We show by in situ microscopy that the effects of electron beam irradiation during transmission electron microscopy can be used to lock microstructural features and enhance the structural thermal stability of a nanostructured polymer:fullerene blend. Polymer:fullerene bulk-heterojunction thin films show great promise for use as active layers in organic solar cells but their low thermal stability is a hindrance. Lack of thermal stability complicates manufacturing and influences the lifetime of devices. To investigate how electron irradiation affects the thermal stability of polymer:fullerene films, a model bulk-heterojunction film based on a thiophene-quinoxaline copolymer and a fullerene derivative was heat-treated in-situ in a transmission electron microscope. In areas of the film that exposed to the electron beam the nanostructure of the film remained stable, while the nanostructure in areas not exposed to the electron beam underwent large phase separation and nucleation of fullerene crystals. UV–vis spectroscopy shows that the polymer:fullerene films are stable for electron doses up to 2000 kGy. - Highlights: • Thermal stability of a polymer: fullerne blend is increased using electron irradiation. • Using in-situ transmission electron microscopy the nanostructure is studied. • Electron irradiation stops phase separation between the polymer and fullerene. • Electron irradiation quenches the formation and nucleation of fullerene crystals.

  20. Toward Improved Lifetimes of Organic Solar Cells under Thermal Stress: Substrate-Dependent Morphological Stability of PCDTBT:PCBM Films and Devices.

    Science.gov (United States)

    Li, Zhe; Ho Chiu, Kar; Shahid Ashraf, Raja; Fearn, Sarah; Dattani, Rajeev; Cheng Wong, Him; Tan, Ching-Hong; Wu, Jiaying; Cabral, João T; Durrant, James R

    2015-10-15

    Morphological stability is a key requirement for outdoor operation of organic solar cells. We demonstrate that morphological stability and lifetime of polymer/fullerene based solar cells under thermal stress depend strongly on the substrate interface on which the active layer is deposited. In particular, we find that the stability of benchmark PCDTBT/PCBM solar cells under modest thermal stress is substantially increased in inverted solar cells employing a ZnO substrate compared to conventional devices employing a PSS substrate. This improved stability is observed to correlate with PCBM nucleation at the 50 nm scale, which is shown to be strongly influenced by different substrate interfaces. Employing this approach, we demonstrate remarkable thermal stability for inverted PCDTBT:PC70BM devices on ZnO substrates, with negligible (humidity exposure as widely reported previously, can also demonstrate enhanced morphological stability. As such we show that the choice of suitable substrate interfaces may be a key factor in achieving prolonged lifetimes for organic solar cells under thermal stress conditions.

  1. Improved Efficiency and Stability of Perovskite Solar Cells Induced by CO Functionalized Hydrophobic Ammonium-Based Additives.

    Science.gov (United States)

    Wu, Zhifang; Raga, Sonia R; Juarez-Perez, Emilio J; Yao, Xuyang; Jiang, Yan; Ono, Luis K; Ning, Zhijun; Tian, He; Qi, Yabing

    2018-01-01

    Because of the rapid rise of the efficiency, perovskite solar cells are currently considered as the most promising next-generation photovoltaic technology. Much effort has been made to improve the efficiency and stability of perovskite solar cells. Here, it is demonstrated that the addition of a novel organic cation of 2-(6-bromo-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)ethan-1-ammonium iodide (2-NAM), which has strong Lewis acid and base interaction (between CO and Pb) with perovskite, can effectively increase crystalline grain size and reduce charge carrier recombination of the double cation FA 0.83 MA 0.17 PbI 2.51 Br 0.49 perovskite film, thus boosting the efficiency from 17.1 ± 0.8% to 18.6 ± 0.9% for the 0.1 cm 2 cell and from 15.5 ± 0.5% to 16.5 ± 0.6% for the 1.0 cm 2 cell. The champion cell shows efficiencies of 20.0% and 17.6% with active areas of 0.1 and 1.0 cm 2 , respectively. Moreover, the hysteresis behavior is suppressed and the stability is improved. The result provides a promising route to further elevate efficiency and stability of perovskite solar cells by the fine tuning of triple organic cations. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Orbit Stability of OSIRIS-REx in the Vicinity of Bennu Using a High-Fidelity Solar Radiation Model

    Science.gov (United States)

    Williams, Trevor; Hughes, Kyle; Mashiku, Alinda; Longuski, James

    2015-01-01

    The OSIRIS-REx mission (Origins Spectral Interpretation Resource Identification Security Regolith EXPlorer) is an asteroid sample return mission to Bennu (RQ36) that is scheduled to launch in 2016. The planned science operations precluding the small retrieval involve operations in terminator orbits (orbit plane is perpendicular to the sun). Over longer durations the solar radiation pressure (SRP) perturbs the orbit causing it to precess. Our work involves: modeling high fidelity SRP model to capture the perturbations during attitude changes; design a stable orbit from the high fidelity models to analyze the stability over time.

  3. Edge sealing for low cost stability enhancement of roll-to-roll processed flexible polymer solar cell modules

    DEFF Research Database (Denmark)

    Tanenbaum, David M.; Dam, Henrik Friis; Rösch, R.

    2012-01-01

    Fully roll-to-roll processed polymer solar cell modules were prepared, characterized, and laminated. Cell modules were cut from the roll and matched pairs were selected, one module with exposed cut edges, the other laminated again with the same materials and adhesive sealing fully around the cut...... edges. The edge sealing rim was 10 mm wide. Cell modules were characterized by periodic measurements of IV curves over extended periods in a variety of conditions, as well as by a variety of spatial imaging techniques. Data show significant stability benefits of the edge sealing process. The results...

  4. Crosslinked Remote-Doped Hole-Extracting Contacts Enhance Stability under Accelerated Lifetime Testing in Perovskite Solar Cells.

    Science.gov (United States)

    Xu, Jixian; Voznyy, Oleksandr; Comin, Riccardo; Gong, Xiwen; Walters, Grant; Liu, Min; Kanjanaboos, Pongsakorn; Lan, Xinzheng; Sargent, Edward H

    2016-04-13

    A crosslinked hole-extracting electrical contact is reported, which simultaneously improves the stability and lowers the hysteresis of perovskite solar cells. Polymerizable monomers and crosslinking processes are developed to obviate in situ degradation of the under lying perovskite. The crosslinked material is band-aligned with perovskite. The required free carrier density is induced by a high-work-function metal oxide layer atop the device, following a remote-doping strategy. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells

    DEFF Research Database (Denmark)

    Heckler, Ilona Maria; Kesters, Jurgen; Defour, Maxime

    2016-01-01

    ]thiazole (TzTz) acceptor units, were selected toward effective device scalability by roll-coating. The influence of the partial exchange (5% or 10%) of the solubilizing 2-hexyldecyloxy by alternative 2-phenylethoxy groups on efficiency and stability was investigated. With an increasing 2-phenylethoxy ratio...... studies under constant sun irradiance showed a diminishing initial degradation rate for the BT-based devices upon including the alternative side chains, whereas the (more stable) TzTz-based devices degraded at a faster rate from the start of the experiment upon partly exchanging the side chains. No clear......The stability of polymer solar cells (PSCs) can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyl)dialkoxybenzene donor and benzo[c][1,2,5]thiadiazole (BT) or thiazolo[5,4-d...

  6. Blogging from North Pond

    Science.gov (United States)

    Marziali, C. G.; Edwards, K. J.

    2009-12-01

    Sea going research expeditions provide an ideal opportunity for outreach through blogs: the finite duration limits the author's commitment; scientists are usually in a remote location with fewer distractions; and fieldwork is visual and interesting to describe. Over four weeks this winter, Katrina Edwards of USC authored a blog about her deep-sea drilling expedition to North Pond, a depression in the ocean crust in the mid-Atlantic. She emailed daily dispatches and photos to USC Media Relations, which maintained a (still accessible) blog. Written for the general public, the blog quickly attracted interest from lay readers as well as from media organizations. Scientific American carried the blog on its web site, and the National Science Foundation linked to it in its "Science 360" electronic news digest. The blog also led to a Q&A with Edwards in the widely-read "Behind the Scenes" feature of LiveScience. Interest from science bloggers and National Geographic towards the end suggests that the blog could have expanded its reach given more time: expeditions lasting between six weeks and three months, such as occur during ocean drilling expeditions, would appear to be ideal candidates for a blog. Most importantly, the blog educated readers about the importance to planetary life of what Edwards calls the "intraterrestrials": the countless microbes that inhabit the oceanic crust and influence major chemical and biological cycles. Considering that the subjects of the expedition were invisible critters in a pitch-dark place, the blog shows what can be accomplished by scientists and institutions committed to public outreach.

  7. Operation of roof pond systems, considering its advantages and disadvantages

    Energy Technology Data Exchange (ETDEWEB)

    Noohi, Samira; Rezaei, Davood [Faculty of engineering, Zanjan University (Iran, Islamic Republic of)], email: noohi.sam@gmail.com, email: d_rezaei@znu.ac.ir

    2011-07-01

    With the coming shortage of fossil fuels it is important to develop energy efficient buildings to reduce both energy consumption and pollution at the same time. The roof pond system is a passive solar system which gathers heat from the sun and can distribute it to the living space to cool it or heat it by changing the operating cycle. Although not recent, this method has not been widely implemented due to certain limitations and the aim of this paper is to assess the different advantages and disadvantages of this system over other passive solar heating systems. This study showed that a roof pond has a low impact on the building, provides controllable energy delivery and variations in indoor temperature are low; however it requires an active solar system as a backup and vegetation can limit sunlight penetration. This study highlighted that the efficiency of the roof system pond depends on climate conditions and that it is best suited to lower latitude and low humidity areas.

  8. The Function of TiO2 with Respect to Sensitizer Stability in Nanocrystalline Dye Solar Cells

    Directory of Open Access Journals (Sweden)

    A. Barkschat

    2008-01-01

    Full Text Available Dyes of characteristically different composition have been tested with respect to long-term stability in operating standardized dye sensitized cells during a time period of up to 3600 hours. Selective solar illumination, the use of graded filters, and imaging of photocurrents revealed that degradation is linked to the density of photocurrent passed. Photoelectrochemical degradation was observed with all sensitizers investigated. Sensitization was less efficient and sensitizers were less photostable with nanostructured ZnO compared to nanostructured TiO2. The best performance was confirmed for cis-RuII(dcbpyH22(NCS2 on TiO2. However, it was 7–10 times less stable under other identical conditions on ZnO. Stability is favored by carboxylate anchoring and metal-centred electron transfer. In presence of TiO2, it is enhanced by formation of a stabilizing charge-transfer complex between oxidized Ru dye and back-bonding interfacial Ti3+ states. This is considered to be the main reason for the ongoing use of expensive Ru complexes in combination with TiO2. The local surface chemistry of the nanocrystalline TiO2 turned out to be a crucial factor for sensitizer stability and requires further investigation.

  9. Enhanced thermal stability of a polymer solar cell blend induced by electron beam irradiation in the transmission electron microscope.

    Science.gov (United States)

    Bäcke, Olof; Lindqvist, Camilla; de Zerio Mendaza, Amaia Diaz; Gustafsson, Stefan; Wang, Ergang; Andersson, Mats R; Müller, Christian; Kristiansen, Per Magnus; Olsson, Eva

    2017-05-01

    We show by in situ microscopy that the effects of electron beam irradiation during transmission electron microscopy can be used to lock microstructural features and enhance the structural thermal stability of a nanostructured polymer:fullerene blend. Polymer:fullerene bulk-heterojunction thin films show great promise for use as active layers in organic solar cells but their low thermal stability is a hindrance. Lack of thermal stability complicates manufacturing and influences the lifetime of devices. To investigate how electron irradiation affects the thermal stability of polymer:fullerene films, a model bulk-heterojunction film based on a thiophene-quinoxaline copolymer and a fullerene derivative was heat-treated in-situ in a transmission electron microscope. In areas of the film that exposed to the electron beam the nanostructure of the film remained stable, while the nanostructure in areas not exposed to the electron beam underwent large phase separation and nucleation of fullerene crystals. UV-vis spectroscopy shows that the polymer:fullerene films are stable for electron doses up to 2000kGy. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Stability issues of conjugated polymer / fullerene solar cells from a chemical viewpoint

    NARCIS (Netherlands)

    Hummelen, J.C.; Knol, J.; Sánchez, L.

    2001-01-01

    The efficiency of energy conversion and the stability or lifetime of ‘plastic’ photovoltaic cells, based on conjugated polymer/ fullerene blends, are the two main issues to be improved for this type of devices. The stability of these PV cells depends potentially on a large number of factors. A brief

  11. An evaluation of a solar radiation/delta-T method for estimating Pasquill-Gifford (P-G) stability categories

    Energy Technology Data Exchange (ETDEWEB)

    Coulter, C.T. [Environmental Protection Agency, Research Triangle Park, NC (United States)

    1994-12-31

    There has been a continuing need to develop robust methods for determining Pasquill-Gifford (P-G) stability categories using solely on-site meteorological instrumentation. The Revised EPA Guideline on Air Quality Models recommends several such methods. Experience with these suggests that, since they rely on turbulence measurements, they can be unduly influenced by local effects such as mesoscale circulation (e.g., upslope/downslope flows, land/sea breeze), wakes from tree barriers or buildings, etc. to such an extent as to diminish their practical usefulness. In the following discussion, a methodology is proposed for estimating P-G stability categories that employs on-site meteorological measurements (10m wind speed coupled with solar radiation during the day and temperature difference, {Delta}T, at night) in lieu of cloud cover and ceiling height observations. The proposed method was adapted from Bowen and is herein referred to as the solar radiation/delta-T (SRDT) method. To evaluate the method, an attempt was made to acquire data bases from diverse geographical areas. Data bases with {Delta}T measurements from 2-10m above ground level were of primary interest for characterizing the boundary layer; other intervals were considered for evaluation, as available. To document the consequence of implementing the method in practical applications, an analysis was needed of the effect on design concentration ratios.

  12. The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells.

    Science.gov (United States)

    Heckler, Ilona M; Kesters, Jurgen; Defour, Maxime; Madsen, Morten V; Penxten, Huguette; D'Haen, Jan; Van Mele, Bruno; Maes, Wouter; Bundgaard, Eva

    2016-03-09

    The stability of polymer solar cells (PSCs) can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyl)dialkoxybenzene donor and benzo[ c ][1,2,5]thiadiazole (BT) or thiazolo[5,4- d ]thiazole (TzTz) acceptor units, were selected toward effective device scalability by roll-coating. The influence of the partial exchange (5% or 10%) of the solubilizing 2-hexyldecyloxy by alternative 2-phenylethoxy groups on efficiency and stability was investigated. With an increasing 2-phenylethoxy ratio, a decrease in solar cell efficiency was observed for the BT-based series, whereas the efficiencies for the devices based on the TzTz polymers remained approximately the same. The photochemical degradation rate for PSCs based on the TzTz polymers decreased with an increasing 2-phenylethoxy ratio. Lifetime studies under constant sun irradiance showed a diminishing initial degradation rate for the BT-based devices upon including the alternative side chains, whereas the (more stable) TzTz-based devices degraded at a faster rate from the start of the experiment upon partly exchanging the side chains. No clear trends in the degradation behavior, linked to the copolymer structural changes, could be established at this point, evidencing the complex interplay of events determining PSCs' lifetime.

  13. The Influence of Conjugated Polymer Side Chain Manipulation on the Efficiency and Stability of Polymer Solar Cells

    Directory of Open Access Journals (Sweden)

    Ilona M. Heckler

    2016-03-01

    Full Text Available The stability of polymer solar cells (PSCs can be influenced by the introduction of particular moieties on the conjugated polymer side chains. In this study, two series of donor-acceptor copolymers, based on bis(thienyldialkoxybenzene donor and benzo[c][1,2,5]thiadiazole (BT or thiazolo[5,4-d]thiazole (TzTz acceptor units, were selected toward effective device scalability by roll-coating. The influence of the partial exchange (5% or 10% of the solubilizing 2-hexyldecyloxy by alternative 2-phenylethoxy groups on efficiency and stability was investigated. With an increasing 2-phenylethoxy ratio, a decrease in solar cell efficiency was observed for the BT-based series, whereas the efficiencies for the devices based on the TzTz polymers remained approximately the same. The photochemical degradation rate for PSCs based on the TzTz polymers decreased with an increasing 2-phenylethoxy ratio. Lifetime studies under constant sun irradiance showed a diminishing initial degradation rate for the BT-based devices upon including the alternative side chains, whereas the (more stable TzTz-based devices degraded at a faster rate from the start of the experiment upon partly exchanging the side chains. No clear trends in the degradation behavior, linked to the copolymer structural changes, could be established at this point, evidencing the complex interplay of events determining PSCs’ lifetime.

  14. Flexible high power-per-weight perovskite solar cells with chromium oxide-metal contacts for improved stability in air

    Science.gov (United States)

    Kaltenbrunner, Martin; Adam, Getachew; Głowacki, Eric Daniel; Drack, Michael; Schwödiauer, Reinhard; Leonat, Lucia; Apaydin, Dogukan Hazar; Groiss, Heiko; Scharber, Markus Clark; White, Matthew Schuette; Sariciftci, Niyazi Serdar; Bauer, Siegfried

    2015-10-01

    Photovoltaic technology requires light-absorbing materials that are highly efficient, lightweight, low cost and stable during operation. Organolead halide perovskites constitute a highly promising class of materials, but suffer limited stability under ambient conditions without heavy and costly encapsulation. Here, we report ultrathin (3 μm), highly flexible perovskite solar cells with stabilized 12% efficiency and a power-per-weight as high as 23 W g-1. To facilitate air-stable operation, we introduce a chromium oxide-chromium interlayer that effectively protects the metal top contacts from reactions with the perovskite. The use of a transparent polymer electrode treated with dimethylsulphoxide as the bottom layer allows the deposition--from solution at low temperature--of pinhole-free perovskite films at high yield on arbitrary substrates, including thin plastic foils. These ultra-lightweight solar cells are successfully used to power aviation models. Potential future applications include unmanned aerial vehicles--from airplanes to quadcopters and weather balloons--for environmental and industrial monitoring, rescue and emergency response, and tactical security applications.

  15. Light and Electrically Induced Phase Segregation and Its Impact on the Stability of Quadruple Cation High Bandgap Perovskite Solar Cells.

    Science.gov (United States)

    Duong, The; Mulmudi, Hemant Kumar; Wu, YiLiang; Fu, Xiao; Shen, Heping; Peng, Jun; Wu, Nandi; Nguyen, Hieu T; Macdonald, Daniel; Lockrey, Mark; White, Thomas P; Weber, Klaus; Catchpole, Kylie

    2017-08-16

    Perovskite material with a bandgap of 1.7-1.8 eV is highly desirable for the top cell in a tandem configuration with a lower bandgap bottom cell, such as a silicon cell. This can be achieved by alloying iodide and bromide anions, but light-induced phase-segregation phenomena are often observed in perovskite films of this kind, with implications for solar cell efficiency. Here, we investigate light-induced phase segregation inside quadruple-cation perovskite material in a complete cell structure and find that the magnitude of this phenomenon is dependent on the operating condition of the solar cell. Under short-circuit and even maximum power point conditions, phase segregation is found to be negligible compared to the magnitude of segregation under open-circuit conditions. In accordance with the finding, perovskite cells based on quadruple-cation perovskite with 1.73 eV bandgap retain 94% of the original efficiency after 12 h operation at the maximum power point, while the cell only retains 82% of the original efficiency after 12 h operation at the open-circuit condition. This result highlights the need to have standard methods including light/dark and bias condition for testing the stability of perovskite solar cells. Additionally, phase segregation is observed when the cell was forward biased at 1.2 V in the dark, which indicates that photoexcitation is not required to induce phase segregation.

  16. Dual-Function Au@Y2O3:Eu3+ Smart Film for Enhanced Power Conversion Efficiency and Long-Term Stability of Perovskite Solar Cells.

    Science.gov (United States)

    Kim, Chang Woo; Eom, Tae Young; Yang, In Seok; Kim, Byung Su; Lee, Wan In; Kang, Yong Soo; Kang, Young Soo

    2017-07-28

    In the present study, a dual-functional smart film combining the effects of wavelength conversion and amplification of the converted wave by the localized surface plasmon resonance has been investigated for a perovskite solar cell. This dual-functional film, composed of Au nanoparticles coated on the surface of Y 2 O 3 :Eu 3+ phosphor (Au@Y 2 O 3 :Eu 3+ ) nanoparticle monolayer, enhances the solar energy conversion efficiency to electrical energy and long-term stability of photovoltaic cells. Coupling between the Y 2 O 3 :Eu 3+ phosphor monolayer and ultraviolet solar light induces the latter to be converted into visible light with a quantum yield above 80%. Concurrently, the Au nanoparticle monolayer on the phosphor nanoparticle monolayer amplifies the converted visible light by up to 170%. This synergy leads to an increased solar light energy conversion efficiency of perovskite solar cells. Simultaneously, the dual-function film suppresses the photodegradation of perovskite by UV light, resulting in long-term stability. Introducing the hybrid smart Au@Y 2 O 3 :Eu 3+ film in perovskite solar cells increases their overall solar-to-electrical energy conversion efficiency to 16.1% and enhances long-term stability, as compared to the value of 15.2% for standard perovskite solar cells. The synergism between the wavelength conversion effect of the phosphor nanoparticle monolayer and the wave amplification by the localized surface plasmon resonance of the Au nanoparticle monolayer in a perovskite solar cell is comparatively investigated, providing a viable strategy of broadening the solar spectrum utilization.

  17. 216-B-3 expansion ponds closure plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-10-01

    This document describes the activities for clean closure under the Resource Conservation and Recovery Act of 1976 (RCRA) of the 216-B-3 Expansion Ponds. The 216-B-3 Expansion Ponds are operated by the US Department of Energy, Richland Operations Office (DOE-RL) and co-operated by Westinghouse Hanford Company (Westinghouse Hanford). The 216-B-3 Expansion Ponds consists of a series of three earthen, unlined, interconnected ponds that receive waste water from various 200 East Area operating facilities. The 3A, 3B, and 3C ponds are referred to as Expansion Ponds because they expanded the capability of the B Pond System. Waste water (primarily cooling water, steam condensate, and sanitary water) from various 200 East Area facilities is discharged to the Bypass pipe (Project X-009). Water discharged to the Bypass pipe flows directly into the 216-B-3C Pond. The ponds were operated in a cascade mode, where the Main Pond overflowed into the 3A Pond and the 3A Pond overflowed into the 3C Pond. The 3B Pond has not received waste water since May 1985; however, when in operation, the 3B Pond received overflow from the 3A Pond. In the past, waste water discharges to the Expansion Ponds had the potential to have contained mixed waste (radioactive waste and dangerous waste). The radioactive portion of mixed waste has been interpreted by the US Department of Energy (DOE) to be regulated under the Atomic Energy Act of 1954; the dangerous waste portion of mixed waste is regulated under RCRA.

  18. 216-B-3 expansion ponds closure plan

    International Nuclear Information System (INIS)

    1994-10-01

    This document describes the activities for clean closure under the Resource Conservation and Recovery Act of 1976 (RCRA) of the 216-B-3 Expansion Ponds. The 216-B-3 Expansion Ponds are operated by the US Department of Energy, Richland Operations Office (DOE-RL) and co-operated by Westinghouse Hanford Company (Westinghouse Hanford). The 216-B-3 Expansion Ponds consists of a series of three earthen, unlined, interconnected ponds that receive waste water from various 200 East Area operating facilities. The 3A, 3B, and 3C ponds are referred to as Expansion Ponds because they expanded the capability of the B Pond System. Waste water (primarily cooling water, steam condensate, and sanitary water) from various 200 East Area facilities is discharged to the Bypass pipe (Project X-009). Water discharged to the Bypass pipe flows directly into the 216-B-3C Pond. The ponds were operated in a cascade mode, where the Main Pond overflowed into the 3A Pond and the 3A Pond overflowed into the 3C Pond. The 3B Pond has not received waste water since May 1985; however, when in operation, the 3B Pond received overflow from the 3A Pond. In the past, waste water discharges to the Expansion Ponds had the potential to have contained mixed waste (radioactive waste and dangerous waste). The radioactive portion of mixed waste has been interpreted by the US Department of Energy (DOE) to be regulated under the Atomic Energy Act of 1954; the dangerous waste portion of mixed waste is regulated under RCRA

  19. Flocculation of retention pond water

    International Nuclear Information System (INIS)

    Hart, B.T.; McGregor, R.J.

    1982-05-01

    An integral part of the water management strategy proposed by Ranger Uranium Mining Pty. Ltd. involves the collection of runoff water in a series of retention ponds. This water will subsequently be used in the uranium milling plant or released to Magela Creek. Runoff water collected during the wet season caused a section of Magela Creek to become turbid when it was released. The eroded material causing the turbidity was very highly dispersed and showed little tendency to sediment out in the retention ponds. Results of a preliminary study to determine the feasibility of clarifying retention pond water by flocculation with alum are presented. A concentration of 30 Mg/L alum reduced turbidity from an initial 340 NTU to less than 30 NTU in four hours

  20. Improving the Operational Stability of PBDTTTz-4 Polymer Solar Cells Modules by Electrode Modification

    DEFF Research Database (Denmark)

    Roth, Bérenger; Benatto, Gisele Alves dos Reis; Corazza, Michael

    2016-01-01

    PBDTTTz-4 is employed in the ambient manufacturing of fully Roll-to-Roll organic solar cell modules. Modules are manufactured using a novel silver nanowire electrode or a previously reported carbon electrode. The average PCE of carbon modules (3.07%) and AgNW modules (1.46%) shows that PBDTTTz-4...

  1. Stability and photodegradation mechanisms of conjugated polymer/fullerene plastic solar cells

    NARCIS (Netherlands)

    Neugebauer, H.; Brabec, C.; Hummelen, J.C.; Sariciftci, N.S.

    2000-01-01

    Degradation studies of poly(2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylene-vinylene) (MDMO-PPV), fullerenes ((6,6)-phenyl C-61-butyric acid methyl ester (PCBM) and C-60), and mixtures, which are the photoactive components in plastic solar cells, are shown. The degradation processes of the

  2. Shelf life stability comparison in air for solution processed pristine PDPP3T polymer and doped spiro-OMeTAD as hole transport layer for perovskite solar cell

    Directory of Open Access Journals (Sweden)

    Ashish Dubey

    2016-06-01

    Full Text Available This data in brief includes forward and reverse scanned current density–voltage (J–V characteristics of perovskite solar cells with PDPP3T and spiro-OMeTAD as HTL, stability testing conditions of perovskite solar cell shelf life in air for both PDPP3T and spiro-OMeTAD as HTL as per the description in Ref. [1], and individual J–V performance parameters acquired with increasing time exposed in ambient air are shown for both type of devices using PDPP3T and spiro-OMeTAD as HTL. The data collected in this study compares the device stability with time for both PDPP3T and spiro-OMeTAD based perovskite solar cells and is directly related to our research article “solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation” [2].

  3. Improving the long-term stability of PBDTTPD polymer solar cells through material purification aimed at removing organic impurities

    KAUST Repository

    Mateker, William R.; Douglas, Jessica D.; Cabanetos, Clement; Sachs-Quintana, I. T.; Bartelt, Jonathan A.; Hoke, Eric T.; El Labban, Abdulrahman; Beaujuge, Pierre; Frechet, Jean; McGehee, Michael D.

    2013-01-01

    While bulk heterojunction (BHJ) solar cells fabricated from high M n PBDTTPD achieve power conversion efficiencies (PCE) as high as 7.3%, the short-circuit current density (JSC) of these devices can drop by 20% after seven days of storage in the dark and under inert conditions. This degradation is characterized by the appearance of S-shape features in the reverse bias region of current-voltage (J-V) curves that increase in amplitude over time. Conversely, BHJ solar cells fabricated from low Mn PBDTTPD do not develop S-shaped J-V curves. However, S-shapes identical to those observed in high Mn PBDTTPD solar cells can be induced in low M n devices through intentional contamination with the TPD monomer. Furthermore, when high Mn PBDTTPD is purified via size exclusion chromatography (SEC) to reduce the content of low molecular weight species, the JSC of polymer devices is significantly more stable over time. After 111 days of storage in the dark under inert conditions, the J-V curves do not develop S-shapes and the JSC degrades by only 6%. The S-shape degradation feature, symptomatic of low device lifetimes, appears to be linked to the presence of low molecular weight contaminants, which may be trapped within samples of high Mn polymer that have not been purified by SEC. Although these impurities do not affect initial device PCE, they significantly reduce device lifetime, and solar cell stability is improved by increasing the purity of the polymer materials. © 2013 The Royal Society of Chemistry.

  4. Par Pond Fish, Water, and Sediment Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Paller, M.H. [Westinghouse Savannah River Company, AIKEN, SC (United States); Wike, L.D.

    1996-06-01

    The objectives of this report are to describe the Par Pond fish community and the impact of the drawdown and refill on the community, describe contaminant levels in Par Pond fish, sediments, and water and indicate how contaminant concentrations and distributions were affected by the drawdown and refill, and predict possible effects of future water level fluctuations in Par Pond.

  5. Par Pond Fish, Water, and Sediment Chemistry

    International Nuclear Information System (INIS)

    Paller, M.H.; Wike, L.D.

    1996-06-01

    The objectives of this report are to describe the Par Pond fish community and the impact of the drawdown and refill on the community, describe contaminant levels in Par Pond fish, sediments, and water and indicate how contaminant concentrations and distributions were affected by the drawdown and refill, and predict possible effects of future water level fluctuations in Par Pond

  6. Master plan for remediation of the Sillamaee tailings pond and technical design project

    International Nuclear Information System (INIS)

    Kaasik, T.

    2000-01-01

    Remediation of the Sillamaee radioactive tailings pond is a priority in the Estonian National Environmental Plan. The Sillamaee plant has processed metal ores by hydrometallurgical methods since 1946. Processing continued until 1990, but in the 1970s, production of rare earths and rare metals was introduced and continues today at a smaller scale. The tailings pond contains residues from these operations. The environmental problems associated with the tailings pond are the stability of the dam and the release of contaminants. In order to deal with these two issues effectively, a master plan was drawn up. The master plan covers the period from 1997 to 2008 and was compiled with the cooperation of the Silmet Group and the Sillamaee International Expert Reference Group (SIERG). The master plan sets up a systematic approach for the overall tailings pond remediation, including drying its interior, reshaping and covering the surface, minimizing water flow through the tailings, and ensuring long-term dam stability

  7. Stability assessment on a 3% bilayer PbS/ZnO quantum dot heterojunction solar cell

    Energy Technology Data Exchange (ETDEWEB)

    Luther, Joseph M.; Lloyd, Matthew T.; Beard, Matthew C. [National Renewable Energy Laboratory, Golden, CO (United States); Gao, Jianbo [National Renewable Energy Laboratory, Golden, CO (United States); University of Toledo, Toledo, OH (United States); Semonin, Octavi E.; Nozik, Arthur J. [National Renewable Energy Laboratory, Golden, CO (United States); University of Colorado, Boulder, CO (United States)

    2010-09-01

    We provide the first NREL-certified efficiency measurement on an all-inorganic, solution-processed, nanocrystal solar cell. The 3% efficient device is composed of ZnO nanocrystals and 1.3 eV PbS quantum dots with gold as the top contact. This configuration yields a stable device, retaining 95% of the starting efficiency after a 1000-hour light soak in air without encapsulation. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  8. Liner used in tailings ponds

    International Nuclear Information System (INIS)

    Dinchak, W.G.

    1984-01-01

    A composite liner has been developed for use in hazardous waste impoundments and in tailings ponds where uranium is involved. The liner offers a high degree of reliability against seepage, is durable, and provides a firm working surface. The advantages of the liner are discussed

  9. Concentrated Brine Treatment using New Energy in Coal Mine Evaporation Ponds

    Science.gov (United States)

    Li, Ting; Li, Jingfeng

    2017-12-01

    Recently, more and more coal mine water is being advanced treated and reused in China. The concentrated brine that results from advanced treatment methods can only be evaporated in an evaporation pond. Because of limited treatment capabilities and winter freezing, evaporation ponds often overflow, causing environment contamination. In this paper, based on analysis of brine water quality and economic-technical feasibility, we present a suitable treatment method for brine in evaporation ponds as electrodialysis using solar energy. In addition, we propose a new system to treat brine in coal mine evaporation ponds, which is powered by solar and wind. The operating efficiency of this treatment system proposed in this paper can meet the concentrated brine treatment demands in most coal mines in western mining areas of China and it places the photovoltaic power generation plates on the surface of the evaporation pond on a fixed floating island, which reduces any risk associated with land acquisition. This system can enhance brine treatment efficiency, requires a reduced evaporation pond area, increases the utilization of coal mine water, and minimizes the risk of environment contamination.

  10. Advanced controls for stability assessment of solar dynamics space power generation

    Science.gov (United States)

    Momoh, James A.; Anwah, Nnamdi A.

    1995-01-01

    In support of the power requirements for the Space Station Alpha (SSA), a joint program by the U.S. and Russia for a permanently manned space station to be launched into orbit by 1998, a robust control scheme is needed to assure the stability of the rotating machines that will be integrated into the power subsystem. A framework design and systems studies for modeling and analysis is presented. It employs classical d-q axes machine model with voltage/frequency dependent loads. To guarantee that design requirements and necessary trade studies are done, a functional analysis tool CORE is used for the study. This provides us with different control options for stability assessment. Initial studies and recommendations using advanced simulation tools are also presented. The benefits of the stability/control scheme for evaluating future designs and power management are discussed.

  11. Stabilization

    Directory of Open Access Journals (Sweden)

    Muhammad H. Al-Malack

    2016-07-01

    Full Text Available Fuel oil flyash (FFA produced in power and water desalination plants firing crude oils in the Kingdom of Saudi Arabia is being disposed in landfills, which increases the burden on the environment, therefore, FFA utilization must be encouraged. In the current research, the effect of adding FFA on the engineering properties of two indigenous soils, namely sand and marl, was investigated. FFA was added at concentrations of 5%, 10% and 15% to both soils with and without the addition of Portland cement. Mixtures of the stabilized soils were thoroughly evaluated using compaction, California Bearing Ratio (CBR, unconfined compressive strength (USC and durability tests. Results of these tests indicated that stabilized sand mixtures could not attain the ACI strength requirements. However, marl was found to satisfy the ACI strength requirement when only 5% of FFA was added together with 5% of cement. When the FFA was increased to 10% and 15%, the mixture’s strength was found to decrease to values below the ACI requirements. Results of the Toxicity Characteristics Leaching Procedure (TCLP, which was performed on samples that passed the ACI requirements, indicated that FFA must be cautiously used in soil stabilization.

  12. A temperature rise equation for predicting environmental impact and performance of cooling ponds

    Energy Technology Data Exchange (ETDEWEB)

    Serag-Eldin, M.A. [American Univ. in Cairo, Cairo (Egypt). Dept. of Mechanical Engineering

    2009-07-01

    Cooling ponds are used to cool the condenser water used in large central air-conditioning systems. However, larger cooling loads can often increase pond surface evaporation rates. A temperature-rise energy equation was developed to predict temperature rises in cooling ponds subjected to heating loads. The equation was designed to reduce the need for detailed meteorological data as well as to determine the required surface area and depth of the pond for any given design criteria. Energy equations in the presence and absence of cooling loads were subtracted from each other to determine increases in pond temperature resulting from the cooling load. The energy equations include solar radiation, radiation exchange with sky and surroundings, heat convection from the surface, evaporative cooling, heat conducted to the walls, and rate of change of water temperature. Results of the study suggested that the environmental impact and performance of the cooling pond is a function of temperature only. It was concluded that with the aid of the calculated flow field and temperature distribution, the method can be used to position sprays in order to produce near-uniform pond temperatures. 10 refs., 12 figs.

  13. Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells

    KAUST Repository

    Rumer, Joseph W.; Ashraf, Raja S.; Eisenmenger, Nancy D.; Huang, Zhenggang; Meager, Iain; Nielsen, Christian B.; Schroeder, Bob C.; Chabinyc, Michael L.; McCulloch, Iain

    2015-01-01

    A bis-azide-based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency-boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Dual Function Additives: A Small Molecule Crosslinker for Enhanced Efficiency and Stability in Organic Solar Cells

    KAUST Repository

    Rumer, Joseph W.

    2015-02-01

    A bis-azide-based small molecule crosslinker is synthesized and evaluated as both a stabilizing and efficiency-boosting additive in bulk heterojunction organic photovoltaic cells. Activated by a noninvasive and scalable solution processing technique, polymer:fullerene blends exhibit improved thermal stability with suppressed polymer skin formation at the cathode and frustrated fullerene aggregation on ageing, with initial efficiency increased from 6% to 7%. © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Double perovskites overtaking the single perovskites: A set of new solar harvesting materials with much higher stability and efficiency

    Science.gov (United States)

    Kangsabanik, Jiban; Sugathan, Vipinraj; Yadav, Anuradha; Yella, Aswani; Alam, Aftab

    2018-05-01

    Solar energy plays an important role in substituting the ever declining source of fossil fuel energy. Finding novel materials for solar cell applications is an integral part of photovoltaic research. Hybrid lead halide perovskites are one of, if not the most, well sought material in the photovoltaic research community. Its unique intrinsic properties, flexible synthesis techniques, and device fabrication architecture made the community highly buoyant over the past few years. Yet, there are two fundamental issues that still remain a concern, i.e., the stability in external environment and the toxicity due to Pb. This led to a search for alternative materials. More recently, double perovskite [A2B B'X6 (X =Cl, Br, I)] materials have emerged as a promising choice. Few experimental synthesis and high throughput computational studies have been carried out to check for promising candidates of this class. The main outcome from these studies, however, can essentially be summarized into two categories: (i) either they have an indirect band gap or (ii) a direct but large optical band gap, which is not suitable for solar devices. Here we propose a large set of stable double perovskite materials, Cs2B B 'X6 (X =Cl, Br, I), which show indirect to direct band gap transition via small Pb+2 doping at both B and B'sites. This is done by careful band (orbital) engineering using first-principles calculations. This kind of doping has helped to change the topology of the band structure, triggering an indirect to direct transition that is optically allowed. It also reduces the band gap significantly, bringing it well into the visible region. We also simulated the optical absorption spectra of these systems and found a comparable/higher absorption coefficient and solar efficiency with respect to the state of the art photovoltaic absorber material CH3NH3PbI3 . A number of materials Cs2(B0.75Pb0.25) (B0.75'Pb0.25) X6 (for various combinations of B ,B ', and X ) are found to be promising

  16. Stability of Cu(In,Ga)Se2 solar cells: A literature review

    NARCIS (Netherlands)

    Theelen, M.; Daume, F.

    2016-01-01

    As Cu(In,Ga)Se2 (CIGS) photovoltaic (PV) technology matures to production on an industrial scale, its long-term stability becomes increasingly important: The electric yield and thus the revenue of a PV system depend on both the initial conversion efficiency as well as its development over time.

  17. Understanding the biological activity of high rate algae ponds through the calculation of oxygen balances.

    Science.gov (United States)

    Arbib, Zouhayr; de Godos Crespo, Ignacio; Corona, Enrique Lara; Rogalla, Frank

    2017-06-01

    Microalgae culture in high rate algae ponds (HRAP) is an environmentally friendly technology for wastewater treatment. However, for the implementation of these systems, a better understanding of the oxygenation potential and the influence of climate conditions is required. In this work, the rates of oxygen production, consumption, and exchange with the atmosphere were calculated under varying conditions of solar irradiance and dilution rate during six months of operation in a real scale unit. This analysis allowed determining the biological response of these dynamic systems. The rates of oxygen consumption measured were considerably higher than the values calculated based on the organic loading rate. The response to light intensity in terms of oxygen production in the bioreactor was described with one of the models proposed for microalgae culture in dense concentrations. This model is based on the availability of light inside the culture and the specific response of microalgae to this parameter. The specific response to solar radiation intensity showed a reasonable stability in spite of the fluctuations due to meteorological conditions. The methodology developed is a useful tool for optimization and prediction of the performance of these systems.

  18. Thermally reactive Thiazolo[5,4-d]thiazole based copolymers for high photochemical stability in polymer solar cells

    DEFF Research Database (Denmark)

    Helgesen, Martin; Vesterager Madsen, Morten; Andreasen, Birgitta

    2011-01-01

    New thermally reactive copolymers based on dithienylthiazolo[5,4-d]thiazole (DTZ) and silolodithiophene (SDT) have been synthesized and explored in bulk heterojunction solar cells as mixtures with [6,6]-phenyl-C61-butyric acid methyl ester (PCBM). In thin films the polymers had optical band gaps...... in the range of 1.64-1.80 eV. For solubility the polymers have incorporated alkyl groups on the SDT unit and thermally removable ester groups on the DTZ unit that can be eliminated around 200 °C for improved photochemical stability in thin films. The bulkiness of the alkyl chains on the SDT unit proved...... to be very significant in terms of photovoltaic performance of the polymer:PCBM solar cells. Polymers based on 4,4-dihexyl-4H-silolo[3,2-b:4,5-b′]dithiophene reached power conversion efficiencies (PCEs) up to 1.45% but changing the alkyl groups to more bulky ethylhexyl chains reduced the PCE to 1.17%. More...

  19. Effect of a cathode buffer layer on the stability of organic solar cells

    International Nuclear Information System (INIS)

    Wang, Danbei; Zeng, Wenjin; Chen, Shilin; Su, Xiaodan; Wang, Jin; Zhang, Hongmei

    2015-01-01

    We present the effect of a cathode buffer layer on the performance and stability of organic photovoltaics (OPVs) based on a blend of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM). Six kinds of cathode buffer layers, i.e. lithium fluoride, sodium chloride, NaCl/Mg, tris-(8-hydroxy-quinoline) aluminum, bathocuproine and 1,3,5-tris(2-N-phenylbenzimidazolyl)benzene, were inserted between the photoactive layer and an Al cathode, which played a dominant role in the device’s performance. Devices with the cathode buffer layers above exhibited improved performance. The degradation of these devices with encapsulation was further investigated in an inert atmosphere. The results indicated that devices with inorganic cathode buffer layers exhibited better stability than those with organic cathode buffer layers. (paper)

  20. Round-Robin Studies on Roll-Processed ITO-free Organic Tandem Solar Cells Combined with Inter-Laboratory Stability Studies

    DEFF Research Database (Denmark)

    Livi, Francesco; Søndergaard, Roar R.; Andersen, Thomas Rieks

    2015-01-01

    Roll-processed, indium tin oxide (ITO)-free, flexible, organic tandem solar cells and modules have been realized and used in round-robin studies as well as in parallel inter-laboratory stability studies. The tandem cells/modules show no significant difference in comparison to their single...

  1. New Low-Bandgap Materials with Good Stabilities and Efficiencies Comparable to P3HT in R2R-Coated Solar Cells

    DEFF Research Database (Denmark)

    Søndergaard, Roar; Manceau, Matthieu; Jørgensen, Mikkel

    2012-01-01

    Roll-to-roll coated organic solar cells of two new polymers processed in ambient conditions show good photochemical stabilities, and their efficiencies are comparable to similar roll-to-roll coated P3HT cells. Optimal blend compositions are achieved by the use of differentially pumped slot die...

  2. Stabilization of molten salt materials using metal chlorides for solar thermal storage.

    Science.gov (United States)

    Dunlop, T O; Jarvis, D J; Voice, W E; Sullivan, J H

    2018-05-29

    The effect of a variety of metal-chlorides additions on the melting behavior and thermal stability of commercially available salts was investigated. Ternary salts comprised of KNO 3, NaNO 2, and NaNO 3 were produced with additions of a variety of chlorides (KCl, LiCl, CaCl 2 , ZnCl 2 , NaCl and MgCl 2 ). Thermogravimetric analysis and weight loss experiments showed that the quaternary salt containing a 5 wt% addition of LiCl and KCl led to an increase in short term thermal stability compared to the ternary control salts. These additions allowed the salts to remain stable up to a temperature of 630 °C. Long term weight loss experiments showed an upper stability increase of 50 °C. A 5 wt% LiCl addition resulted in a weight loss of only 25% after 30 hours in comparison to a 61% loss for control ternary salts. Calorimetry showed that LiCl additions allow partial melting at 80 °C, in comparison to the 142 °C of ternary salts. This drop in melting point, combined with increased stability, provided a molten working range increase of almost 100 °C in total, in comparison to the control ternary salts. XRD analysis showed the oxidation effect of decomposing salts and the additional phase created with LiCl additions to allow melting point changes to occur.

  3. A comparative study of fluorine substituents for enhanced stability of flexible and ITO-free high-performance polymer solar cells

    DEFF Research Database (Denmark)

    Carlé, Jon Eggert; Helgesen, Martin; Zawacka, Natalia Klaudia

    2014-01-01

    lifetime in flexible large area roll-coated bulk heterojunction solar cells. The two polymer series have different side chains on the BDT unit, namely 2-hexyldecyloxy (BDTHDO) (P1-P3) or 2-hexyldecylthiophene (BDT THD) (P4-P6). The photochemical stability clearly shows that the stability enhances along...... with the number of fluorine atoms incorporated on the polymer backbone. Fabrication of the polymer solar cells based on the materials was carried out in ambient atmosphere on a roll coating/printing machine employing flexible and indium-tin-oxide-free plastic substrates. Solar cells based on the P4-P6 series...... in the performance followed by a much slower decay rate, still retaining 40-55% of their initial performance after 250 h of testing under ISOS-L-1 conditions. © 2014 Wiley Periodicals, Inc....

  4. Solution processed transition metal oxide anode buffer layers for efficiency and stability enhancement of polymer solar cells

    Science.gov (United States)

    Ameen, M. Yoosuf; Shamjid, P.; Abhijith, T.; Reddy, V. S.

    2018-01-01

    Polymer solar cells were fabricated with solution-processed transition metal oxides, MoO3 and V2O5 as anode buffer layers (ABLs). The optimized device with V2O5 ABL exhibited considerably higher power conversion efficiency (PCE) compared to the devices based on MoO3 and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) ABLs. The space charge limited current measurements and impedance spectroscopy results of hole-only devices revealed that V2O5 provided a very low charge transfer resistance and high hole mobility, facilitating efficient hole transfer from the active layer to the ITO anode. More importantly, incorporation of V2O5 as ABL resulted in substantial improvement in device stability compared to MoO3 and PEDOT:PSS based devices. Unencapsulated PEDOT:PSS-based devices stored at a relative humidity of 45% have shown complete failure within 96 h. Whereas, MoO3 and V2O5 based devices stored in similar conditions retained 22% and 80% of their initial PCEs after 96 h. Significantly higher stability of the V2O5-based device is ascribed to the reduction in degradation of the anode/active layer interface, as evident from the electrical measurements.

  5. Stability of CIGS Solar Cells and Component Materials Evaluated by a Step-Stress Accelerated Degradation Test Method: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Pern, F. J.; Noufi, R.

    2012-10-01

    A step-stress accelerated degradation testing (SSADT) method was employed for the first time to evaluate the stability of CuInGaSe2 (CIGS) solar cells and device component materials in four Al-framed test structures encapsulated with an edge sealant and three kinds of backsheet or moisture barrier film for moisture ingress control. The SSADT exposure used a 15oC and then a 15% relative humidity (RH) increment step, beginning from 40oC/40%RH (T/RH = 40/40) to 85oC/70%RH (85/70) as of the moment. The voluminous data acquired and processed as of total DH = 3956 h with 85/70 = 704 h produced the following results. The best CIGS solar cells in sample Set-1 with a moisture-permeable TPT backsheet showed essentially identical I-V degradation trend regardless of the Al-doped ZnO (AZO) layer thickness ranging from standard 0.12 μm to 0.50 μm on the cells. No clear 'stepwise' feature in the I-V parameter degradation curves corresponding to the SSADT T/RH/time profile was observed. Irregularity in I-V performance degradation pattern was observed with some cells showing early degradation at low T/RH < 55/55 and some showing large Voc, FF, and efficiency degradation due to increased series Rs (ohm-cm2) at T/RH ≥ 70/70. Results of (electrochemical) impedance spectroscopy (ECIS) analysis indicate degradation of the CIGS solar cells corresponded to increased series resistance Rs (ohm) and degraded parallel (minority carrier diffusion/recombination) resistance Rp, capacitance C, overall time constant Rp*C, and 'capacitor quality' factor (CPE-P), which were related to the cells? p-n junction properties. Heating at 85/70 appeared to benefit the CIGS solar cells as indicated by the largely recovered CPE-P factor. Device component materials, Mo on soda lime glass (Mo/SLG), bilayer ZnO (BZO), AlNi grid contact, and CdS/CIGS/Mo/SLG in test structures with TPT showed notable to significant degradation at T/RH ≥ 70/70. At T/RH = 85/70, substantial blistering of

  6. Structurally stabilized mesoporous TiO2 nanofibres for efficient dye-sensitized solar cells

    Directory of Open Access Journals (Sweden)

    Fargol Hasani Bijarbooneh

    2013-09-01

    Full Text Available One-dimensional (1D TiO2 nanostructures are very desirable for providing fascinating properties and features, such as high electron mobility, quantum confinement effects, and high specific surface area. Herein, 1D mesoporous TiO2 nanofibres were prepared using the electrospinning method to verify their potential for use as the photoelectrode of dye-sensitized solar cells (DSSCs. The 1D mesoporous nanofibres, 300 nm in diameter and 10-20 μm in length, were aggregated from anatase nanoparticles 20-30 nm in size. The employment of these novel 1D mesoporous nanofibres significantly improved dye loading and light scattering of the DSSC photoanode, and resulted in conversion cell efficiency of 8.14%, corresponding to an ∼35% enhancement over the Degussa P25 reference photoanode.

  7. Solid polymeric electrolyte based dye-sensitized solar cell with improved stability

    Science.gov (United States)

    Prasad, Narottam; Kumar, Manish; Patel, K. R.; Roy, M. S.

    2018-05-01

    The impact of polymeric electrolyte was investigated over the performance of dye-sensitized solar cell made with Rose Bengal as sensitizer. Further, the selective influence of TiCl4 treatment and pre-sensitizer deoxycholic acid on nc-TiO2 photoanode was determined in terms of improvement in conversion efficiency of the cell. It is found that the effect of TiCl4 treatment was comparatively more than pre-sensitization with de-oxy cholic acid towards improving the efficiency of the cell. The conversion efficiency on TiCl4 treatment was 0.2% whereas on pre-sensitization with deoxy chollic acid it was 0.1%. The combined effect of both TiCl4 treatment & pre-sensitization with deoxycholic acid leads conversion efficiency to 0.33%.

  8. The Ruminant and the Pond

    OpenAIRE

    Lajarin-Encina, Aitor

    2015-01-01

    The Ruminant and the Pond presents a group of paintings and a film that explore contemporary psycho-social conditions through fictional narratives. Paintings and film explore territories of thinking and emotion engaging the audience in subjective digressions related to ideas of artificiality, relativeness, absurdity, futility or alienation in relation to intersubjective reality perception, production and representation. At the same time the project delves in the specific relationship existin...

  9. Effects of pond draining on biodiversity and water quality of farm ponds.

    Science.gov (United States)

    Usio, Nisikawa; Imada, Miho; Nakagawa, Megumi; Akasaka, Munemitsu; Takamura, Noriko

    2013-12-01

    Farm ponds have high conservation value because they contribute significantly to regional biodiversity and ecosystem services. In Japan pond draining is a traditional management method that is widely believed to improve water quality and eradicate invasive fish. In addition, fishing by means of pond draining has significant cultural value for local people, serving as a social event. However, there is a widespread belief that pond draining reduces freshwater biodiversity through the extirpation of aquatic animals, but scientific evaluation of the effectiveness of pond draining is lacking. We conducted a large-scale field study to evaluate the effects of pond draining on invasive animal control, water quality, and aquatic biodiversity relative to different pond-management practices, pond physicochemistry, and surrounding land use. The results of boosted regression-tree models and analyses of similarity showed that pond draining had little effect on invasive fish control, water quality, or aquatic biodiversity. Draining even facilitated the colonization of farm ponds by invasive red swamp crayfish (Procambarus clarkii), which in turn may have detrimental effects on the biodiversity and water quality of farm ponds. Our results highlight the need for reconsidering current pond management and developing management plans with respect to multifunctionality of such ponds. Efectos del Drenado de Estanques sobre la Biodiversidad y la Calidad del Agua en Estanques de Cultivo. © 2013 Society for Conservation Biology.

  10. Theoretical study on thermal stability of molten salt for solar thermal power

    International Nuclear Information System (INIS)

    Wei, Xiaolan; Peng, Qiang; Ding, Jing; Yang, Xiaoxi; Yang, Jianping; Long, Bin

    2013-01-01

    Molten salt (HTS) composed of 53% KNO 3 , 40% NaNO 2 and 7 wt.% NaNO 3 has been used as heat transfer media and thermal storage fluid in the solar thermal power, but thermal decomposition will occur at higher temperature because of the oxidation of nitrite to nitrate in the air. In this paper, the reaction mechanism of NO 2 − oxidation is researched by quantum mechanical method. The results show that two components of the transition state (O 2 NO 2 − ) and intermediate ([NO 4 − ]) are found in the reaction. This reaction is an exothermic reaction and the activation barrier is 94.0 kJ mol −1 . The energy difference of this reaction is very large, so the reaction rate is very slow. -- Highlights: ► The mechanism of the oxidation of nitrite salt in HTS is explained. ► Two components of the transition state (O 2 NO 2 − ) and intermediate ([NO 4 − ]) are found. ► The activation barrier of the nitrite oxidation is determined

  11. Microbial population responses in three stratified Antarctic meltwater ponds during the autumn freeze

    DEFF Research Database (Denmark)

    Safi, Karl; Hawes, Ian; Sorrell, Brian Keith

    2012-01-01

    The planktonic microbial communities of three meltwater ponds, located on the McMurdo Ice Shelf, were investigated from the end of January 2008 to early April, during which almost the entire pond volumes froze. The ponds were comprised of an upper mixed layer overlying a salt-stabilized density g...... for increasing heterotrophy within the remaining microbial communities, although all components of the food web eventually decline as the final freeze approaches....... role of autotrophic and heterotrophic microplankton within the ponds. The results showed that microbial groups responded to the onset of winter by declining in abundance, though an exception was the appearance of filamentous cyanobacteria in the water column in March. As freezing progressed, autotrophs...... declined more rapidly than heterotrophs and grazing rates and abundances of mixotrophic and heterotrophic organisms increased. Grazing pressure on bacteria and picophytoplankton also increased, in part explaining their decline over time. The results indicate that stressors imposed during freezing select...

  12. Geomembrane selection criteria for uranium tailings ponds

    International Nuclear Information System (INIS)

    Mitchell, D.H.; Cuello, R.

    1986-09-01

    The selection criteria, particularly those involving chemical compatibility, of geomembranes to be used in ponds at uranium mill operations are discussed. The principal functional criteria which a geomembrane must meet for this application are: (1) a specified service life and (2) low permeability. Chemical compatibility with the waste is essential in meeting these functional criteria. In two different types of aging tests using simulated acidic uranium mill waste, degradation of chemical and physical properties were examined in geomembranes of high-density polyethylene, polyvinyl chloride, and chlorosulfonated polyethylene. Compatibility tests according to the National Sanitation Foundation procedures are recommended to ascertain the stability of certain physical properties of the proposed geomembrane. Actual experience with a specific geomembrane in an identical application is probably the best method to assure compatibility; however, this experience is frequently not available. Experience with a geomembrane in similar applications is valuable in the selection process, however, small differences in either the geomembrane formulation or the waste composition may result in large differences in performance of the geomembrane. It is likely that many geomembranes have acceptable chemical stability for typical uranium mill applications, therefore, additional factors in the selection processes will include seaming characteristics, mechanical properties, site characteristics, and costs

  13. Stability and Performance of CsPbI2Br Thin Films and Solar Cell Devices.

    Science.gov (United States)

    Mariotti, Silvia; Hutter, Oliver S; Phillips, Laurie J; Yates, Peter J; Kundu, Biswajit; Durose, Ken

    2018-01-31

    In this manuscript, the inorganic perovskite CsPbI 2 Br is investigated as a photovoltaic material that offers higher stability than the organic-inorganic hybrid perovskite materials. It is demonstrated that CsPbI 2 Br does not irreversibly degrade to its component salts as in the case of methylammonium lead iodide but instead is induced (by water vapor) to transform from its metastable brown cubic (1.92 eV band gap) phase to a yellow phase having a higher band gap (2.85 eV). This is easily reversed by heating to 350 °C in a dry environment. Similarly, exposure of unencapsulated photovoltaic devices to water vapor causes current (J SC ) loss as the absorber transforms to its more transparent (yellow) form, but this is also reversible by moderate heating, with over 100% recovery of the original device performance. NMR and thermal analysis show that the high band gap yellow phase does not contain detectable levels of water, implying that water induces the transformation but is not incorporated as a major component. Performances of devices with best efficiencies of 9.08% (V OC = 1.05 V, J SC = 12.7 mA cm -2 and FF = 68.4%) using a device structure comprising glass/ITO/c-TiO 2 /CsPbI 2 Br/Spiro-OMeTAD/Au are presented, and further results demonstrating the dependence of the performance on the preparation temperature of the solution processed CsPbI 2 Br films are shown. We conclude that encapsulation of CsPbI 2 Br to exclude water vapor should be sufficient to stabilize the cubic brown phase, making the material of interest for use in practical PV devices.

  14. uG-LilyPond - Floating Plant Pond for Microgravity, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed μG-LilyPond is an autonomous environmentally controlled floating plant cultivation system for use in microgravity. The μG-LilyPond concept expands the...

  15. South Bay Salt Pond Tidal Marsh Restoration at Pond A17 Project

    Science.gov (United States)

    Information about the SFBWQP South Bay Salt Pond Tidal Marsh Restoration at Pond A17 Project, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  16. Stability and sealing of PEC solar cells; Stabilitet og forsegling af PEC solceller

    Energy Technology Data Exchange (ETDEWEB)

    Lauritzen, H.

    2009-06-15

    A requirement for success of the DSC technology on the market for building-integrated PV is visually attractive DSC panels holding a lifetime comparable to alternative facade materials and delivering electricity at reasonable prices. This project concerns the stability and durability of the DSC panel as these are decisive factors for the lifetime of the panels and the price of the produced electricity. The largest challenge of the DSC sealing is the high-performing well-documented - but also aggressive and volatile - iodine/triiodide electrolyte. The heat-sensitive Ru-dyes represent another challenge, as the dye should not be exposed to temperatures above approx. 100 deg. C during the sealing process. Despite the fact that less aggressive electrolytes and more stable dyes are highly focused R and D tasks, the work in the actual project has been carried out according to a 'worst case' strategy, i.e. the search has been for a sealing which is compatible with the iodine/triiodide electrolyte and the Ru-dyes. The rationale behind this strategy is the demanding lifetime requirement s for building-integrated products, which requires the ultimate sealing. In addition to the focus on the DSC sealing, work has been dedicated to the development of a more encapsulation-friendly electrolyte, in which the electrolyte's volatile component has been replaced by an ionic liquid. The ultimate result of the project is an improved polymer edge sealing for DSC cells. The sealant is - contrary to Surlyn and Bynel - stable in contact with the aggressive iodine/ triiodide electrolyte. The sealing is formed by lamination at elevated temperature and under controlled conditions. The robustness and capacity of the sealing process need to be further improved in order to fulfill the laboratories ambitions with regard to volume production of DSC cells and modules. Furthermore should the new sealing be compared both stability-wise and cost-wise with the lead-free solder glass

  17. Photo-stability study of a solution-processed small molecule solar cell system: correlation between molecular conformation and degradation.

    Science.gov (United States)

    Newman, Michael J; Speller, Emily M; Barbé, Jérémy; Luke, Joel; Li, Meng; Li, Zhe; Wang, Zhao-Kui; Jain, Sagar M; Kim, Ji-Seon; Lee, Harrison Ka Hin; Tsoi, Wing Chung

    2018-01-01

    Solution-processed organic small molecule solar cells (SMSCs) have achieved efficiency over 11%. However, very few studies have focused on their stability under illumination and the origin of the degradation during the so-called burn-in period. Here, we studied the burn-in period of a solution-processed SMSC using benzodithiophene terthiophene rhodamine:[6,6]-phenyl C 71 butyric acid methyl ester (BTR:PC 71 BM) with increasing solvent vapour annealing time applied to the active layer, controlling the crystallisation of the BTR phase. We find that the burn-in behaviour is strongly correlated to the crystallinity of BTR. To look at the possible degradation mechanisms, we studied the fresh and photo-aged blend films with grazing incidence X-ray diffraction, UV-vis absorbance, Raman spectroscopy and photoluminescence (PL) spectroscopy. Although the crystallinity of BTR affects the performance drop during the burn-in period, the degradation is found not to originate from the crystallinity changes of the BTR phase, but correlates with changes in molecular conformation - rotation of the thiophene side chains, as resolved by Raman spectroscopy which could be correlated to slight photobleaching and changes in PL spectra.

  18. Stabilized efficiency of stacked a-Si solar cell; Sekisogata a-Si taiyo denchi no anteika koritsu

    Energy Technology Data Exchange (ETDEWEB)

    Takahisa, K; Kojima, T; Nakamura, K; Koyanagi, T; Yanagisawa, T [Electrotechnical Laboratory, Tsukuba (Japan)

    1997-11-25

    Different types of tests combining light and temperature were carried out in a laboratory on predicting long-term performance of stacked amorphous silicon solar cells. Cell terminals were left open, xenon was used as an irradiation light source, and cell temperature was controlled within {+-} 2 degC of the setting. The result of the experiment may be summarized as follows: with regard to the deterioration characteristics, the speed in which the efficiency changes reached a maximum within 10 hours, and thereafter the change has slowed down gradually in the case of temperature at 50 degC; in the case of 25 degC, the maximization is reached between 500 and 1000 hours; the stabilization efficiency turns out to be a pessimistic value according to the saturated value derived from an experimental expression, hence the value would have to be expressed by specifying cell temperatures, light intensities and elapsed time; the minimum value of seasonal variation may be estimated at about 85% as a pessimistic value; for recovery characteristics, the saturated value for the recovery tends to become lower as the lower the value immediately before the recovery; and if the light intensity is varied, the deterioration characteristic shifts to that at an individual light intensity. 4 refs., 11 figs., 2 tabs.

  19. Carbon-Based CsPbBr3 Perovskite Solar Cells: All-Ambient Processes and High Thermal Stability.

    Science.gov (United States)

    Chang, Xiaowen; Li, Weiping; Zhu, Liqun; Liu, Huicong; Geng, Huifang; Xiang, Sisi; Liu, Jiaming; Chen, Haining

    2016-12-14

    The device instability has been an important issue for hybrid organic-inorganic halide perovskite solar cells (PSCs). This work intends to address this issue by exploiting inorganic perovskite (CsPbBr 3 ) as light absorber, accompanied by replacing organic hole transport materials (HTM) and the metal electrode with a carbon electrode. All the fabrication processes (including those for CsPbBr 3 and the carbon electrode) in the PSCs are conducted in ambient atmosphere. Through a systematical optimization on the fabrication processes of CsPbBr 3 film, carbon-based PSCs (C-PSCs) obtained the highest power conversion efficiency (PCE) of about 5.0%, a relatively high value for inorganic perovskite-based PSCs. More importantly, after storage for 250 h at 80 °C, only 11.7% loss in PCE is observed for CsPbBr 3 C-PSCs, significantly lower than that for popular CH 3 NH 3 PbI 3 C-PSCs (59.0%) and other reported PSCs, which indicated a promising thermal stability of CsPbBr 3 C-PSCs.

  20. Growth, etching, and stability of sputtered ZnO:Al for thin-film silicon solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Owen, Jorj Ian

    2011-07-01

    Aluminum-doped zinc oxide (ZnO:Al) can fulfill many requirements in thin-film solar cells, acting as (1) a transparent contact through which the incident light is transmitted, (2) part of the back reflector, and (3) a source of light scattering. Magnetron sputtered ZnO:Al thin-films are highly transparent, conductive, and are typically texturized by post-deposition etching in a dilute hydrochloric acid (HCl) solution to achieve light scattering. The ZnO:Al thin-film electronic and optical properties, as well as the surface texture after etching, depend on the deposition conditions and the post-deposition treatments. Despite having been used in thin-film solar cells for more than a decade, many aspects regarding the growth, effects of heat treatments, environmental stability, and etching of sputtered ZnO:Al are not fully understood. This work endeavors to further the understanding of ZnO:Al for the purpose improving silicon thin-film solar cell efficiency and reducing ZnO:Al production costs. With regard to the growth of ZnO:Al, the influence of various deposition conditions on the resultant electrical and structural properties and their evolution with film thickness were studied. The surface electrical properties extracted from a multilayer model show that while carrier concentration of the surface layer saturates already at film thickness of 100 nm, the surface mobility continues to increases with film thickness, and it is concluded that electronic transport across grain boundaries limits mobility in ZnO:Al thin films. ZnO:Al deposited onto a previously etched ZnO:Al surface grows epitaxially, preserving both the original orientation and grain structure. Further, it is determined that a typical ZnO:Al used in thin-film silicon solar cells grows Zn-terminated on glass substrates. Concerning the affects of heat treatments and stability, it is demonstrated that a layer of amorphous silicon can protect ZnO:Al from degradation during annealing, and the mobility of Zn

  1. Stability enhancement of P3HT:PCBM polymer solar cells using thermally evaporated MoO3 anode buffer layer

    Science.gov (United States)

    Ameen, M. Yoosuf; Shamjid, P.; Abhijith, T.; Radhakrishnan, Thulasi; Reddy, V. S.

    2018-02-01

    Polymer solar cells have been fabricated with thermally evaporated MoO3 as anode buffer layer (ABL). The stability of MoO3 and PEDOT:PSS based devices was examined under different test conditions. The MoO3 based device exhibited a slightly better efficiency and significantly higher stability compared to PEDOT:PSS based device. At a relative humidity of 45% the unencapsulated PEDOT:PSS based device degraded completely within 96 h. On the other hand, MoO3 based device retained more than 60% of its initial efficiency after 96 h. The reason behind stability enhancement was investigated by measuring time-evolution of reflectance and hole-current. Experimental results revealed that the stability enhancement for MoO3 based device originates from the reduction in degradation of anode/active layer interface.

  2. Solar engineering 1994

    International Nuclear Information System (INIS)

    Klett, D.E.; Hogan, R.E.; Tanaka, Tadayoshi

    1994-01-01

    This volume of 83 papers constitutes the Proceedings of the 1994 International Solar Energy Conference held March 27--30, 1994 in San Francisco, California. The Conference was jointly sponsored by the Solar Energy Division of the American Society of Mechanical Engineers, The Japan Society of Mechanical Engineers and the Japan Solar Energy Society. This is the fourth cooperation between ASME, JSME and JSES in cosponsoring the International Solar Energy Conference. The papers cover a wide range of solar technologies from low temperature solar ponds and desalinization to high temperature concentrators for space applications and central receivers for terrestrial power generation. Other topics covered include solar detoxification of hazardous waste, dish Stirling systems, solar cooling, photovoltaics, building energy analysis and conservation, simulation, and testing and measurement techniques. All papers were indexed separately for the data base

  3. Flexible ITO-free organic solar cells applying aqueous solution-processed V2O5 hole transport layer: An outdoor stability study

    Directory of Open Access Journals (Sweden)

    F. Anderson S. Lima

    2016-02-01

    Full Text Available Solution processable semiconductor oxides have opened a new paradigm for the enhancement of the lifetime of thin film solar cells. Their fabrication by low-cost and environmentally friendly solution-processable methods makes them ideal barrier (hole and electron transport layers. In this work, we fabricate flexible ITO-free organic solar cells (OPV by printing methods applying an aqueous solution-processed V2O5 as the hole transport layer (HTL and compared them to devices applying PEDOT:PSS. The transparent conducting electrode was PET/Ag/PEDOT/ZnO, and the OPV configuration was PET/Ag/PEDOT/ZnO/P3HT:PC60BM/HTL/Ag. Outdoor stability analyses carried out for more than 900 h revealed higher stability for devices fabricated with the aqueous solution-processed V2O5.

  4. Triple-junction thin-film silicon solar cell fabricated on periodically textured substrate with a stabilized efficiency of 13.6%

    Science.gov (United States)

    Sai, Hitoshi; Matsui, Takuya; Koida, Takashi; Matsubara, Koji; Kondo, Michio; Sugiyama, Shuichiro; Katayama, Hirotaka; Takeuchi, Yoshiaki; Yoshida, Isao

    2015-05-01

    We report a high-efficiency triple-junction thin-film silicon solar cell fabricated with the so-called substrate configuration. It was verified whether the design criteria for developing single-junction microcrystalline silicon (μc-Si:H) solar cells are applicable to multijunction solar cells. Furthermore, a notably high short-circuit current density of 32.9 mA/cm2 was achieved in a single-junction μc-Si:H cell fabricated on a periodically textured substrate with a high-mobility front transparent contacting layer. These technologies were also combined into a-Si:H/μc-Si:H/μc-Si:H triple-junction cells, and a world record stabilized efficiency of 13.6% was achieved.

  5. 100-D Ponds closure plan. Revision 1

    International Nuclear Information System (INIS)

    Petersen, S.W.

    1997-09-01

    The 100-D Ponds is a Treatment, Storage, and Disposal (TSD) unit on the Hanford Facility that received both dangerous and nonregulated waste. This Closure Plan (Rev. 1) for the 100-D Ponds TSD unit consists of a RCRA Part A Dangerous Waste Permit Application (Rev. 3), a RCRA Closure Plan, and supporting information contained in the appendices to the plan. The closure plan consists of eight chapters containing facility description, process information, waste characteristics, and groundwater monitoring data. There are also chapters containing the closure strategy and performance standards. The strategy for the closure of the 100-D Ponds TSD unit is clean closure. Appendices A and B of the closure plan demonstrate that soil and groundwater beneath 100-D Ponds are below cleanup limits. All dangerous wastes or dangerous waste constituents or residues associated with the operation of the ponds have been removed, therefore, human health and the environment are protected. Discharges to the 100-D Ponds, which are located in the 100-DR-1 operable unit, were discontinued in June 1994. Contaminated sediment was removed from the ponds in August 1996. Subsequent sampling and analysis demonstrated that there is no contamination remaining in the ponds, therefore, this closure plan is a demonstration of clean closure

  6. Aquatic studies of Gable Mountain Pond

    International Nuclear Information System (INIS)

    Cushing, C.E.; Watson, D.G.

    1974-12-01

    Studies of the biotic and abiotic components of the Gable Mountain Pond (HAPO cooling water disposal pond) ecosystem were undertaken to determine if there was a potential problem for off-site transfer of radioactivity to man originating with the aquatic food web. Most of the 137 Cs in the pond is associated with the sediments which are probably the main source of 137 Cs for uptake by the biota. Generally, highest concentrations of 137 Cs and other radioisotopes were found in the upper two inches of sediments in the northwest end of the pond and in the deeper areas along the long-axis of the pond. Native goldfish had maximum and average 137 Cs concentrations of about 340 and 170 pCi/g dry wt, respectively. Algae, macrophytes, and detritus comprised the main food items of the goldfish, and the 137 Cs levels in the plants were usually higher than the 137 Cs concentration in the fish. The 137 Cs concentrations of wild experimental ducks restricted to Gable Mountain Pond were approximately the same as resident coots, but significantly higher than transient wild ducks. Neither the goldfish nor the waterfowl inhabiting the pond attained concentrations of 137 Cs exceeding acceptable limits. Sediment, however, could be a source of high concentrations of radioactivity or radioactive contamination concern if the concentration of radiocontaminants increased and/or the pond dries up, and the contaminated sediments become windborne. (U.S.)

  7. Par Pond vegetation status Summer 1995 -- Summary

    International Nuclear Information System (INIS)

    Mackey, H.E. Jr.; Riley, R.S.

    1996-01-01

    The water level of Par Pond was lowered approximately 20 feet in mid-1991 in order to protect downstream residents from possible dam failure suggested by subsidence on the downstream slope of the dam and to repair the dam. This lowering exposed both emergent and nonemergent macrophyte beds to drying conditions resulting in extensive losses. A survey of the newly emergent, shoreline aquatic plant communities of Par Pond began in June 1995, three months after the refilling of Par Pond to approximately 200 feet above mean sea level. These surveys continued in July, September, and late October, 1995. Communities similar to the pre-drawdown, Par Pond aquatic plant communities are becoming re-established. Emergent beds of maidencane, lotus, waterlily, and watershield are extensive and well developed. Cattail occurrence continued to increase during the summer, but large beds common to Par Pond prior to the drawdown have not formed. Estimates from SPOT HRV, remote sensing satellite data indicated that as much as 120 hectares of emergent wetlands vegetation may have been present along the Par Pond shoreline by early October, 1995. To track the continued development of macrophytes in Par Pond, future surveys throughout 1996 and 1997, along with the continued evaluation of satellite data to map the areal extent of the macrophyte beds of Par Pond, are planned

  8. Organic matter decomposition in simulated aquaculture ponds

    NARCIS (Netherlands)

    Torres Beristain, B.

    2005-01-01

    Different kinds of organic and inorganic compounds (e.g. formulated food, manures, fertilizers) are added to aquaculture ponds to increase fish production. However, a large part of these inputs are not utilized by the fish and are decomposed inside the pond. The microbiological decomposition of the

  9. Sunlight inactivation of Escherichia coli in waste stabilization microcosms in a sahelian region (Ouagadougou, Burkina Faso).

    Science.gov (United States)

    Maïga, Ynoussa; Denyigba, Kokou; Wethe, Joseph; Ouattara, Aboubakar Sidiki

    2009-02-09

    Experiments on sunlight inactivation of Escherichia coli were conducted from November 2006 to June 2007 in eight outdoors microcosms with different depths filled with maturation pond wastewater in order to determine pond depth influence on sunlight inactivation of E. coli. The long-term aim was to maximize sunlight inactivation of waterborne pathogens in waste stabilization ponds (WSPs) in sahelian regions where number of sunny days enable longer exposure of wastewater to sunlight. The inactivation was followed during daylight from 8.00 h to 17.00 h and during the night. Sunlight inactivation rates (K(S)), as a function of cumulative global solar radiation (insolation), were 16 and 24 times higher than the corresponding dark inactivation (K(D)) rates, respectively in cold and warm season. In warm season, E. coli was inactivated far more rapidly. Inactivation of E. coli follows the evolution of radiation during the day. In shallow depth microcosms, E. coli was inactivated far more rapidly than in high depth microcosms. The physical chemical parameters [pH, dissolved oxygen (DO)] of microcosms water were higher in shallow depth microcosms than in high depth microcosms suggesting a synergistic effect of sunlight and these parameters to damage E. coli. To increase the efficiency of the elimination of waterborne bacteria, the use of maturation ponds with intermediate depths (0.4m) would be advisable in view of the high temperatures and thus evaporation recorded in sahelian regions.

  10. Heterostructured TiO2/NiTiO3 Nanorod Arrays for Inorganic Sensitized Solar Cells with Significantly Enhanced Photovoltaic Performance and Stability.

    Science.gov (United States)

    Li, Yue-Ying; Wang, Jian-Gan; Sun, Huan-Huan; Wei, Bingqing

    2018-04-11

    Organic dyes used in the conventional dye-sensitized solar cells (DSSCs) suffer from poor light stability and high cost. In this work, we demonstrate a new inorganic sensitized solar cell based on ordered one-dimensional semiconductor nanorod arrays of TiO 2 /NiTiO 3 (NTO) heterostructures prepared via a facile two-step hydrothermal approach. The semiconductor heterostructure arrays are highly desirable and promising for DSSCs because of their direct charge transport capability and slow charge recombination rate. The low-cost NTO inorganic semiconductor possesses an appropriate band gap that matches well with TiO 2 , which behaves like a "dye" to enable efficient light harvesting and fast electron-hole separation. The solar cells constructed by the ordered TiO 2 /NTO heterostructure photoanodes show a significantly improved power conversion efficiency, high fill factor, and more promising, outstanding life stability. The present work will open up an avenue to design heterostructured inorganics for high-performance solar cells.

  11. Pond of Illusion: Interacting through Mixed Reality

    DEFF Research Database (Denmark)

    Nobel-Jørgensen, Morten; Nielsen, Jannik Boll; Larsen, Anders Boesen Lindbo

    2013-01-01

    Pond of Illusion is a mixed reality installation where a virtual space (the pond) is injected between two real spaces. The users are in either of the real spaces, and they can see each other through windows in the virtual space as illustrated in Figure 1(left). The installation attracts people...... to a large display in either of the real spaces by allowing them to feed virtual fish swimming in the pond. Figure 1(middle) shows how a Microsoft Kinect mounted on top of the display is used for detecting throw motions, which triggers virtual breadcrumbs to be thrown into the pond for feeding the nearby...... fish. Of course, the fish may not be available because they are busy eating what people have thrown into the pond from the other side....

  12. Intermediate pond sizes contain the highest density, richness, and diversity of pond-breeding amphibians.

    Directory of Open Access Journals (Sweden)

    Raymond D Semlitsch

    Full Text Available We present data on amphibian density, species richness, and diversity from a 7140-ha area consisting of 200 ponds in the Midwestern U.S. that represents most of the possible lentic aquatic breeding habitats common in this region. Our study includes all possible breeding sites with natural and anthropogenic disturbance processes that can be missing from studies where sampling intensity is low, sample area is small, or partial disturbance gradients are sampled. We tested whether pond area was a significant predictor of density, species richness, and diversity of amphibians and if values peaked at intermediate pond areas. We found that in all cases a quadratic model fit our data significantly better than a linear model. Because small ponds have a high probability of pond drying and large ponds have a high probability of fish colonization and accumulation of invertebrate predators, drying and predation may be two mechanisms driving the peak of density and diversity towards intermediate values of pond size. We also found that not all intermediate sized ponds produced many larvae; in fact, some had low amphibian density, richness, and diversity. Further analyses of the subset of ponds represented in the peak of the area distribution showed that fish, hydroperiod, invertebrate density, and canopy are additional factors that drive density, richness and diversity of ponds up or down, when extremely small or large ponds are eliminated. Our results indicate that fishless ponds at intermediate sizes are more diverse, produce more larvae, and have greater potential to recruit juveniles into adult populations of most species sampled. Further, hylid and chorus frogs are found predictably more often in ephemeral ponds whereas bullfrogs, green frogs, and cricket frogs are found most often in permanent ponds with fish. Our data increase understanding of what factors structure and maintain amphibian diversity across large landscapes.

  13. A Simple Power Management Scheme with Enhanced Stability for a Solar PV/Wind/Fuel Cell/Grid Fed Hybrid Power Supply Designed for Industrial Loads

    Directory of Open Access Journals (Sweden)

    S. Saravanan

    2014-01-01

    Full Text Available This paper proposes a new power conditioner topology with an intelligent power management controller that integrates multiple renewable energy sources such as solar energy, wind energy, and fuel cell energy with battery and AC grid supply as backup to make the best use of their operating characteristics with better reliability than that could be obtained by single renewable energy source based power supply. The proposed embedded controller is programmed to perform MPPT for solar PV panel and WTG, SOC estimation and battery, maintaining a constant voltage at PCC and power flow control by regulating the reference currents of the controller in an instantaneous basis. The instantaneous variation in reference currents of the controller enhances the controller response as it accommodates the effect of continuously varying solar insolation and wind speed in the power management. It also prioritizes the sources for consumption to achieve maximum usage of green energy than grid energy. The simulation results of the proposed power management system with real-time solar radiation and wind velocity data collected from solar centre, KEC, and experimental results for a sporadically varying load demand are presented in this paper and the results are encouraging from reliability and stability perspectives.

  14. Poly(4-Vinylpyridine)-Based Interfacial Passivation to Enhance Voltage and Moisture Stability of Lead Halide Perovskite Solar Cells.

    Science.gov (United States)

    Chaudhary, Bhumika; Kulkarni, Ashish; Jena, Ajay Kumar; Ikegami, Masashi; Udagawa, Yosuke; Kunugita, Hideyuki; Ema, Kazuhiro; Miyasaka, Tsutomu

    2017-06-09

    It is well known that the surface trap states and electronic disorders in the solution-processed CH 3 NH 3 PbI 3 perovskite film affect the solar cell performance significantly and moisture sensitivity of photoactive perovskite material limits its practical applications. Herein, we show the surface modification of a perovskite film with a solution-processable hydrophobic polymer (poly(4-vinylpyridine), PVP), which passivates the undercoordinated lead (Pb) atoms (on the surface of perovskite) by its pyridine Lewis base side chains and thereby eliminates surface-trap states and non-radiative recombination. Moreover, it acts as an electron barrier between the perovskite and hole-transport layer (HTL) to reduce interfacial charge recombination, which led to improvement in open-circuit voltage (V oc ) by 120 to 160 mV whereas the standard cell fabricated in same conditions showed V oc as low as 0.9 V owing to dominating interfacial recombination processes. Consequently, the power conversion efficiency (PCE) increased by 3 to 5 % in the polymer-modified devices (PCE=15 %) with V oc more than 1.05 V and hysteresis-less J-V curves. Advantageously, hydrophobicity of the polymer chain was found to protect the perovskite surface from moisture and improved stability of the non-encapsulated cells, which retained their device performance up to 30 days of exposure to open atmosphere (50 % humidity). © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. CO₂ efflux from shrimp ponds in Indonesia.

    Science.gov (United States)

    Sidik, Frida; Lovelock, Catherine E

    2013-01-01

    The conversion of mangrove forest to aquaculture ponds has been increasing in recent decades. One of major concerns of this habitat loss is the release of stored 'blue' carbon from mangrove soils to the atmosphere. In this study, we assessed carbon dioxide (CO₂) efflux from soil in intensive shrimp ponds in Bali, Indonesia. We measured CO₂ efflux from the floors and walls of shrimp ponds. Rates of CO₂ efflux within shrimp ponds were 4.37 kg CO₂ m⁻² y⁻¹ from the walls and 1.60 kg CO₂ m⁻² y⁻¹ from the floors. Combining our findings with published data of aquaculture land use in Indonesia, we estimated that shrimp ponds in this region result in CO₂ emissions to the atmosphere between 5.76 and 13.95 Tg y⁻¹. The results indicate that conversion of mangrove forests to aquaculture ponds contributes to greenhouse gas emissions that are comparable to peat forest conversion to other land uses in Indonesia. Higher magnitudes of CO₂ emission may be released to atmosphere where ponds are constructed in newly cleared mangrove forests. This study indicates the need for incentives that can meet the target of aquaculture industry without expanding the converted mangrove areas, which will lead to increased CO₂ released to atmosphere.

  16. CO₂ efflux from shrimp ponds in Indonesia.

    Directory of Open Access Journals (Sweden)

    Frida Sidik

    Full Text Available The conversion of mangrove forest to aquaculture ponds has been increasing in recent decades. One of major concerns of this habitat loss is the release of stored 'blue' carbon from mangrove soils to the atmosphere. In this study, we assessed carbon dioxide (CO₂ efflux from soil in intensive shrimp ponds in Bali, Indonesia. We measured CO₂ efflux from the floors and walls of shrimp ponds. Rates of CO₂ efflux within shrimp ponds were 4.37 kg CO₂ m⁻² y⁻¹ from the walls and 1.60 kg CO₂ m⁻² y⁻¹ from the floors. Combining our findings with published data of aquaculture land use in Indonesia, we estimated that shrimp ponds in this region result in CO₂ emissions to the atmosphere between 5.76 and 13.95 Tg y⁻¹. The results indicate that conversion of mangrove forests to aquaculture ponds contributes to greenhouse gas emissions that are comparable to peat forest conversion to other land uses in Indonesia. Higher magnitudes of CO₂ emission may be released to atmosphere where ponds are constructed in newly cleared mangrove forests. This study indicates the need for incentives that can meet the target of aquaculture industry without expanding the converted mangrove areas, which will lead to increased CO₂ released to atmosphere.

  17. Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light

    International Nuclear Information System (INIS)

    Wang, Yunming; Tang, Bingtao; Zhang, Shufen

    2014-01-01

    Graphical abstract: Organic shape-stabilized solar thermal energy storage materials (OCSPCMs) with broadband harvesting for visible light were obtained by crosslinking and color matching, which provided a new platform for improving the efficiency of solar radiation utilization. - Highlights: • Novel phase change materials (OCSPCMs) were obtained by crosslinking and color matching. • The η of the OCSPCM was higher than 0.74 (visible light from 400 nm to 700 nm). • The phase change latent heats of the OCSPCMs were more than 120 J/g. • The OCSPCM has excellent form-stable effect during phase change process. - Abstract: Broadband visible sunlight usage and shape-stabilized effect were achieved using organic, cross-linking, and shape-stabilized phase-changed materials (OCSPCMs) with broadband visible light absorption, which were obtained by cross-linking reticulation and color matching (yellow, red, and blue) according to solar irradiation energy density. The obtained OCSPCMs exhibited excellent form-stable phase-change energy storage and broadband visible light-harvesting. Under broadband irradiation (from 400 nm to 700 nm), the light-to-heat conversion and the thermal energy storage efficiency (η > 0.74) of the OCSPCMs were significantly improved upon solar irradiation by color matching compared with those of OCSPCMs with single-band selective absorption of visible light (yellow, red, or blue). Differential scanning calorimetric results indicated that the phase change temperatures and latent heats of OCSPCMs ranged from 32.6 °C to 60.2 °C and from 120.1 J/g to 132.7 J/g, respectively. The novel materials show a reversible (more than 200 cycles) phase transition via ON/OFF switching of visible light irradiation

  18. Spatial Atmospheric Pressure Atomic Layer Deposition of Tin Oxide as an Impermeable Electron Extraction Layer for Perovskite Solar Cells with Enhanced Thermal Stability.

    Science.gov (United States)

    Hoffmann, Lukas; Brinkmann, Kai O; Malerczyk, Jessica; Rogalla, Detlef; Becker, Tim; Theirich, Detlef; Shutsko, Ivan; Görrn, Patrick; Riedl, Thomas

    2018-02-14

    Despite the notable success of hybrid halide perovskite-based solar cells, their long-term stability is still a key-issue. Aside from optimizing the photoactive perovskite, the cell design states a powerful lever to improve stability under various stress conditions. Dedicated electrically conductive diffusion barriers inside the cell stack, that counteract the ingress of moisture and prevent the migration of corrosive halogen species, can substantially improve ambient and thermal stability. Although atomic layer deposition (ALD) is excellently suited to prepare such functional layers, ALD suffers from the requirement of vacuum and only allows for a very limited throughput. Here, we demonstrate for the first time spatial ALD-grown SnO x at atmospheric pressure as impermeable electron extraction layers for perovskite solar cells. We achieve optical transmittance and electrical conductivity similar to those in SnO x grown by conventional vacuum-based ALD. A low deposition temperature of 80 °C and a high substrate speed of 2.4 m min -1 yield SnO x layers with a low water vapor transmission rate of ∼10 -4 gm -2 day -1 (at 60 °C/60% RH). Thereby, in perovskite solar cells, dense hybrid Al:ZnO/SnO x electron extraction layers are created that are the key for stable cell characteristics beyond 1000 h in ambient air and over 3000 h at 60 °C. Most notably, our work of introducing spatial ALD at atmospheric pressure paves the way to the future roll-to-roll manufacturing of stable perovskite solar cells.

  19. ANL-W 779 pond seepage test

    International Nuclear Information System (INIS)

    Braun, D.R.

    1992-11-01

    The ANL-W 779 sanitary wastewater treatment ponds are located on the Idaho National Engineering Laboratory (INEL), north of the Argonne National Laboratory -- West (ANL-W) site A seepage test was performed for two Argonne National Laboratory -- West (ANL-W) sanitary wastewater treatment ponds, Facility 779. Seepage rates were measured to determine if the ponds are a wastewater land application facility. The common industry standard for wastewater land application facilities is a field-measured seepage rate of one quarter inch per day or greater

  20. 100-D Ponds groundwater quality assessment

    International Nuclear Information System (INIS)

    Hartman, M.J.

    1996-01-01

    The 100-D Ponds facility is regulated under the Resource Conservation and Recovery Act of 1976. The pH of groundwater in a downgradient well is statistically different than local background, triggering an assessment of groundwater contamination under 40 CFR 265.93. Results of a similar assessment, conducted in 1993, show that the elevated pH is caused by the presence of alkaline ash sediments beneath the ponds, which are not part of the RCRA unit. The 100-D Ponds should remain in indicator evaluation monitoring

  1. WWER-type NPP spray ponds screen

    International Nuclear Information System (INIS)

    Nikolova, M.; Jordanov, M.; Denev, J.; Markov, D.

    2003-01-01

    The objective of this study is to develop a protection screen of WWER-type NPP spray ponds. The screen design is to ensure reduction of the water droplets blown by the wind and, if possible, their return back to the spray ponds. The cooling capacity of the ponds is not to be changed below the design level for safety reasons. Computational fluid dynamics analysis is used to assess the influence of each design variant on the behavior of the water droplets distribution. Two variants are presented here. The one with plants is found not feasible. The second variant, with steel screen and terrain profile modification is selected for implementation. (author)

  2. Assessment of stability of the response versus scan angle for the S-NPP VIIRS reflective solar bands using pseudo-invariant desert and Dome C sites

    Science.gov (United States)

    Wu, Aisheng; Xiong, Xiaoxiong J.; Cao, Changyong

    2017-09-01

    The Visible Infrared Imaging Radiometer Suite (VIIRS) on the Suomi NPP (National Polar-orbiting Partnership) satellite has been in operation for over five years. VIIRS has 22 bands with a spectral range from 0.4 μm to 2.2 μm for the reflective solar bands (RSB). The Earth view swath covers a distance of 3000 km over scan angles of +/- 56.0° off nadir. The on-board calibration of the RSB relies on a solar diffuser (SD) located at a fixed scan angle and a solar diffuser stability monitor (SDSM). The response versus scan angle (RVS) was characterized prelaunch in ambient conditions and is currently used to determine the on-orbit response for all scan angles relative to the SD scan angle. Since the RVS is vitally important to the quality of calibrated level 1B products, it is important to monitor its on-orbit stability, particularly at the short wavelengths (blue) where the most degradation occurs. In this study, the RVS stability is examined based on reflectance trends collected at various scan angles over the selected pseudo-invariant desert sites in Northern Africa and the Dome C snow site in Antarctica. These trends are corrected by the site dependent BRDF (bi-directional reflectance function) model to reduce seasonally related fluctuations. The BRDF corrected trends are examined so any systematic drifts in the scan angle direction would indicate a potential change in RVS. The results of this study provide useful information on VIIRS RVS on-orbit stability performance.

  3. An automatic energy-saving and thermal monitoring/controlling system for a pond

    Directory of Open Access Journals (Sweden)

    Cheng Ching-Chien

    2017-01-01

    Full Text Available Because of low temperatures and oxygen in cold water, fish will die when cold currents arrive. This will cause tremendous loss of money. In order reduce the cooling of the pond, an automatic thermal detecting and cold-roofing system using a wind-proofing device, heaters, and thermal detectors is proposed. To reduce heat loss due to thermal convection above the pond surface, a motor-driven wind-proofing device automatically controlled by a PLC controller is adopted. Here, the wind-proofing device, thermal detectors, and heating system are connected to the PLC controller. The PLC will also be connected to the PC interface. The temperature thresholds used to trigger the heater and the wind proofing device can be set at the PC interface. Two options for manipulating the heating and the automatic heating can be selected. The related wind-proofing area and the number of heaters will be determined according to the current temperature. Moreover, the PLC can be wirelessly connected to the server PC in the control room. The pond keeper can monitor everything online and control the pond water's temperature. With this, the problem of fish dying in a cold wave can be solved. Consequently, to reduce the electrical exhaust when heating up the pond water, green energy, solar energy and wind energy, is used.

  4. Percolation blockage: A process that enables melt pond formation on first year Arctic sea ice

    Science.gov (United States)

    Polashenski, Chris; Golden, Kenneth M.; Perovich, Donald K.; Skyllingstad, Eric; Arnsten, Alexandra; Stwertka, Carolyn; Wright, Nicholas

    2017-01-01

    Melt pond formation atop Arctic sea ice is a primary control of shortwave energy balance in the Arctic Ocean. During late spring and summer, the ponds determine sea ice albedo and how much solar radiation is transmitted into the upper ocean through the sea ice. The initial formation of ponds requires that melt water be retained above sea level on the ice surface. Both theory and observations, however, show that first year sea ice is so highly porous prior to the formation of melt ponds that multiday retention of water above hydraulic equilibrium should not be possible. Here we present results of percolation experiments that identify and directly demonstrate a mechanism allowing melt pond formation. The infiltration of fresh water into the pore structure of sea ice is responsible for blocking percolation pathways with ice, sealing the ice against water percolation, and allowing water to pool above sea level. We demonstrate that this mechanism is dependent on fresh water availability, known to be predominantly from snowmelt, and ice temperature at melt onset. We argue that the blockage process has the potential to exert significant control over interannual variability in ice albedo. Finally, we suggest that incorporating the mechanism into models would enhance their physical realism. Full treatment would be complex. We provide a simple temperature threshold-based scheme that may be used to incorporate percolation blockage behavior into existing model frameworks.

  5. Identification and characterization of bacteria in a selenium-contaminated hypersaline evaporation pond.

    Science.gov (United States)

    de Souza, M P; Amini, A; Dojka, M A; Pickering, I J; Dawson, S C; Pace, N R; Terry , N

    2001-09-01

    Solar evaporation ponds are commonly used to reduce the volume of seleniferous agricultural drainage water in the San Joaquin Valley, Calif. These hypersaline ponds pose an environmental health hazard because they are heavily contaminated with selenium (Se), mainly in the form of selenate. Se in the ponds may be removed by microbial Se volatilization, a bioremediation process whereby toxic, bioavailable selenate is converted to relatively nontoxic dimethylselenide gas. In order to identify microbes that may be used for Se bioremediation, a 16S ribosomal DNA phylogenetic analysis of an aerobic hypersaline pond in the San Joaquin Valley showed that a previously unaffiliated group of uncultured bacteria (belonging to the order Cytophagales) was dominant, followed by a group of cultured gamma-Proteobacteria which was closely related to Halomonas species. Se K-edge X-ray absorption spectroscopy of selenate-treated bacterial isolates showed that they accumulated a mixture of predominantly selenate and a selenomethionine-like species, consistent with the idea that selenate was assimilated via the S assimilation pathway. One of these bacterial isolates (Halomonas-like strain MPD-51) was the best candidate for the bioremediation of hypersaline evaporation ponds contaminated with high Se concentrations because it tolerated 2 M selenate and 32.5% NaCl, grew rapidly in media containing selenate, and accumulated and volatilized Se at high rates (1.65 microg of Se g of protein(-1) x h(-1)), compared to other cultured bacterial isolates.

  6. Stability of templated and nanoparticles dye-sensitized solar cells: photovoltaic and electrochemical investigation of degradation mechanisms at the photoelectrode interface

    International Nuclear Information System (INIS)

    Dewalque, Jennifer; Nguyen, Ngoc Duy; Colson, Pierre; Krins, Natacha; Cloots, Rudi; Henrist, Catherine

    2014-01-01

    Graphical abstract: Highly porous templated TiO 2 films are promising alternative to nanoparticle layers for dye-sensitized solar cell applications. However, the increase of the electron transfer surface could promote detrimental side reactions and accelerate cell degradation upon ageing. Therefore, stability of templated cells under UV exposure, visible light soaking and thermal stress was studied in comparison to nanoparticle cells. -- Highlights: •Stability of templated and nanoparticle dye-sensitized solar cells is compared. •Templated cells are more sensitive to UV degradation than nanoparticle cells. •Templated cells are as stable as nanoparticle cells under light soaking. •Templated cells are more stable than nanoparticle cells under thermal stress. •Templated cells present better overall performances than nanoparticle cells. -- Abstract: A key issue in the commercialization of dye-sensitized solar cells is to maintain high efficiency and long lifetime. As reported in the literature, dye-sensitized solar cells are stable under visible light soaking but thermal stress and UV exposure lead to efficiency degradation. However, all the stability studies published so far have been performed on cells whose TiO 2 electrodes were prepared by tape casting or screen printing of nanoparticle pastes/inks. The present study concerns cells based on highly porous templated TiO 2 electrodes, whose larger surface area could enhance the negative effects of thermal stress, light soaking and UV exposure. The long-term stability of these cells is compared with a classical nanoparticle-based cell using current-voltage measurements (I-V curves) and electrochemical impedance spectroscopy. Due to their higher active interface, templated cells are more sensitive than nanoparticle cells to UV illumination, although this can be easily solved in both cases by the use of a UV filter. The templated cells are as stable as the nanoparticle cells under visible light soaking (UV

  7. Zr-doped TiO2 nanoparticles synthesized via a sol-gel route and their application in dye-sensitized solar cells for thermo-stabilization

    Science.gov (United States)

    Pasche, Anastasia; Grohe, Bernd; Mittler, Silvia; Charpentier, Paul A.

    2017-06-01

    Dye-sensitized solar cells (DSSCs) are regarded as one of the most promising solar cells amongst third-generation photovoltaic technologies, particularly due to their low cost, easy preparation, and minor environmental impact compared to earlier-generation devices. However, they have been challenged by thermal energy losses and low cell efficiencies. This work examined the incorporation of zirconium (Zr) into the crystal lattice of titania nanoparticles (nTiO2) for subsequent fabrication into the photo anode of the DSSCs. The results showed that Zr doping of nTiO2 inhibited the anatase-rutile phase transition. Higher calcination temperatures gave increased titania crystallinity, and stabilized the nTiO2 aggregate pore structure and specific surface area, consequently improving the DSSC device performance. A doping concentration of 5 mol % Zr into the nTiO2 demonstrated the best resistance against thermal degradation, achieving an optimized retention of specific surface area. Solar simulation confirmed the results, indicating better heat stability, although lowering the DSSC efficiencies.

  8. South Bay Salt Pond Mercury Studies Project

    Science.gov (United States)

    Information about the SFBWQP South Bay Salt Pond Mercury Studies Project, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  9. Musculoskeletal disorder survey for pond workers

    Science.gov (United States)

    Maryani, A.; Partiwi, S. G.; Dewi, H. N. F.

    2018-04-01

    Mucsuloskeletal disorder will affect worker performance and become serious injury when ignored, so that workers cannot work normally. Therefore, an effective strategy plan is needed to reduce the risk of musculoskeletal disorder. A pond worker is profession with high risk of physical complain. Four main activities are ponds preparation, seed distribution, pond maintenance, and harvesting. The methods employed in this current musculoskeletal disorder survey are questionnaire and interview. The result from 73 questionnaires shown that most of pond workers were working for 7 days a week. Prevalence physical complain are on neck, shoulders, upper back, lower back, and knees. The level of perceived complaint is moderate pain. However, most of them do not contact therapists or physicians. Therefore it is necessary to improve the working methods to be able to reduce physical complains due to musculoskeletal disorder.

  10. Pond and Irrigation Model (PIM): a tool for simultaneously evaluating pond water availability and crop irrigation demand

    Science.gov (United States)

    Ying Ouyang; Gary Feng; Theodor D. Leininger; John Read; Johnie N. Jenkins

    2018-01-01

    Agricultural ponds are an important alternative source of water for crop irrigation to conserve surface and ground water resources. In recent years more such ponds have been constructed in Mississippi and around the world. There is currently, however, a lack of a tool to simultaneously estimate crop irrigation demand and pond water availability. In this study, a Pond-...

  11. Wintertime Emissions from Produced Water Ponds

    Science.gov (United States)

    Evans, J.; Lyman, S.; Mansfield, M. L.

    2013-12-01

    Every year oil and gas drilling in the U.S. generates billions of barrels of produced water (water brought to the surface during oil or gas production). Efficiently disposing of produced water presents a constant financial challenge for producers. The most noticeable disposal method in eastern Utah's Uintah Basin is the use of evaporation ponds. There are 427 acres of produced water ponds in the Uintah Basin, and these were used to evaporate more than 5 million barrels of produced water in 2012, 6% of all produced water in the Basin. Ozone concentrations exceeding EPA standards have been observed in the Uintah Basin during winter inversion conditions, with daily maximum 8 hour average concentrations at some research sites exceeding 150 parts per billion. Produced water contains ozone-forming volatile organic compounds (VOC) which escape into the atmosphere as the water is evaporated, potentially contributing to air quality problems. No peer-reviewed study of VOC emissions from produced water ponds has been reported, and filling this gap is essential for the development of accurate emissions inventories for the Uintah Basin and other air sheds with oil and gas production. Methane, carbon dioxide, and VOC emissions were measured at three separate pond facilities in the Uintah Basin in February and March of 2013 using a dynamic flux chamber. Pond emissions vary with meteorological conditions, so measurements of VOC emissions were collected during winter to obtain data relevant to periods of high ozone production. Much of the pond area at evaporation facilities was frozen during the study period, but areas that actively received water from trucks remained unfrozen. These areas accounted for 99.2% of total emissions but only 9.5% of the total pond area on average. Ice and snow on frozen ponds served as a cap, prohibiting VOC from being emitted into the atmosphere. Emissions of benzene, toluene, and other aromatic VOCs averaged over 150 mg m-2 h-1 from unfrozen pond

  12. UHS, Ultimate Heat Sink Cooling Pond Analysis

    International Nuclear Information System (INIS)

    Codell, R.; Nuttle, W.K.

    1998-01-01

    1 - Description of program or function: Three programs model performance of an ultimate heat sink cooling pond. National Weather Service data is read and analyzed to predict periods of lowest cooling performance and highest evaporative loss. The data is compared to local site data for significant differences. Then the maximum pond temperature is predicted. Five programs model performance of an ultimate heat sink spray pond. The cooling performance, evaporative water loss, and drift water loss as a function of wind speed are estimated for a spray field. These estimates are used in conjunction with National Weather Service data to predict periods of lowest cooling performance and highest evaporative loss. This data is compared to local site data for significant differences. Then the maximum pond temperature is predicted. 2 - Method of solution: The transfer of heat and water vapor is modeled using an equilibrium temperature procedure for an UHS cooling pond. The UHS spray pond model considers heat, mass, and momentum transfer from a single water drop with the surrounding air, and modification of the surrounding air resulting from the heat, mass, and momentum transfer from many drops in different parts of a spray field. 3 - Restrictions on the complexity of the problem: The program SPRCO uses RANF, a uniform random number generator which is an intrinsic function on the CDC. All programs except COMET use the NAMELIST statement, which is non standard. Otherwise these programs conform to the ANSI Fortran 77 standard. The meteorological data scanning procedure requires tens of years of recorded data to be effective. The models and methods, provided as useful tool for UHS analyses of cooling ponds and spray ponds, are intended as guidelines only. Use of these methods does not automatically assure NRC approval, nor are they required procedures for nuclear-power-plant licensing

  13. Hydrodynamic evaluation of a full-scale facultative pond by computational fluid dynamics (CFD) and field measurements.

    Science.gov (United States)

    Passos, Ricardo Gomes; von Sperling, Marcos; Ribeiro, Thiago Bressani

    2014-01-01

    Knowledge of the hydraulic behaviour is very important in the characterization of a stabilization pond, since pond hydrodynamics plays a fundamental role in treatment efficiency. An advanced hydrodynamics characterization may be achieved by carrying out measurements with tracers, dyes and drogues or using mathematical simulation employing computational fluid dynamics (CFD). The current study involved experimental determinations and mathematical simulations of a full-scale facultative pond in Brazil. A 3D CFD model showed major flow lines, degree of dispersion, dead zones and short circuit regions in the pond. Drogue tracking, wind measurements and dye dispersion were also used in order to obtain information about the actual flow in the pond and as a means of assessing the performance of the CFD model. The drogue, designed and built as part of this research, and which included a geographical positioning system (GPS), presented very satisfactory results. The CFD modelling has proven to be very useful in the evaluation of the hydrodynamic conditions of the facultative pond. A virtual tracer test allowed an estimation of the real mean hydraulic retention time and mixing conditions in the pond. The computational model in CFD corresponded well to what was verified in the field.

  14. Enhanced photovoltaic performance and long-term stability of dye-sensitized solar cells by incorporating SiO{sub 2} nanoparticles in binary ionic liquid electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hsin-Fang; Wu, Jhih-Lin; Hsu, Po-Ya [Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China); Tung, Yung-Liang [Energy and Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu 30013, Taiwan, ROC (China); Ouyang, Fan-Yi [Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China); Kai, Ji-Jung, E-mail: jjkai@ess.nthu.edu.tw [Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan, ROC (China)

    2013-02-01

    Hydrophilic SiO{sub 2} nanoparticles in a binary ionic liquid (bi-IL) consisting of 1-propyl-3-methylimidazolium iodide (PMII) and 1-ethyl-3-methyl-imidazolium dicyanimide (EMIDCA) facilitated electron transfer and solidified the electrolyte for a dye-sensitized solar cell (DSC). We investigated the dependence of charge transport and photovoltaic performance on the composition of bi-IL electrolytes with varied ratio of SiO{sub 2} nanoparticles. The electrochemical impedance spectra revealed a decreased resistance to charge transfer at the Pt counter electrode (R{sub ct1}) when SiO{sub 2} (up to 2.0 wt.%) was added, improving the photovoltaic parameters. The DSC based on a TiO{sub 2} nanocrystalline film (thickness 14.2 μm) with a composite ionic gel electrolyte of EMIDCA/PMII bi-IL (33 vol.% of EMIDCA) incorporating SiO{sub 2} (2 wt.%) exhibited a power conversion efficiency of 5.28% under simulated solar illumination (AM 1.5 G, 100 mW cm{sup −} {sup 2}). The durability of DSC with a SiO{sub 2} solidified electrolyte was superior to that of a liquid one, exhibiting good stability at 60 °C in darkness during an accelerated test for 1000 h. - Highlights: ► SiO{sub 2} nanoparticles were introduced in a binary ionic liquid electrolyte. ► Effect of various ratios of SiO{sub 2} nanoparticles in gel electrolytes was studied. ► Mechanism of charge transfer with addition of SiO{sub 2} nanoparticles was discussed. ► An enhanced solar to electric energy conversion efficiency of 5.28% was achieved. ► Thermal stability of a quasi-solid state dye-sensitized solar cell was improved.

  15. The film thickness dependent thermal stability of Al{sub 2}O{sub 3}:Ag thin films as high-temperature solar selective absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Xiao Xiudi; Xu Gang, E-mail: xiudixiao@163.com; Xiong Bin; Chen Deming; Miao Lei [Chinese Academy of Sciences, Key Laboratory of Renewable Energy and Gas Hydrates, Guangzhou Institute of Energy Conversion (China)

    2012-03-15

    The monolayer Al{sub 2}O{sub 3}:Ag thin films were prepared by magnetron sputtering. The microstructure and optical properties of thin film after annealing at 700 Degree-Sign C in air were characterized by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and spectrophotometer. It revealed that the particle shape, size, and distribution across the film were greatly changed before and after annealing. The surface plasmon resonance absorption and thermal stability of the film were found to be strongly dependent on the film thickness, which was believed to be associated with the evolution process of particle diffusion, agglomeration, and evaporation during annealing at high temperature. When the film thickness was smaller than 90 nm, the film SPR absorption can be attenuated until extinct with increasing annealing time due to the evaporation of Ag particles. While the film thickness was larger than 120 nm, the absorption can keep constant even after annealing for 64 h due to the agglomeration of Ag particles. On the base of film thickness results, the multilayer Al{sub 2}O{sub 3}:Ag solar selective thin films were prepared and the thermal stability test illustrated that the solar selectivity of multilayer films with absorbing layer thickness larger than 120 nm did not degrade after annealing at 500 Degree-Sign C for 70 h in air. It can be concluded that film thickness is an important factor to control the thermal stability of Al{sub 2}O{sub 3}:Ag thin films as high-temperature solar selective absorbers.

  16. Avaliação de métodos espectrofotométricos para determinação de proteína em amostras de lagoas de estabilização Evaluation of spectrophotometric methods for protein determination in waste stabilization ponds sample

    Directory of Open Access Journals (Sweden)

    Adriana Cristina Poli Miwa

    2008-06-01

    Full Text Available Esta pesquisa teve como objetivo principal comparar cinco métodos espectrofotométricos para determinação de proteínas em amostras provenientes de estações de tratamento de efluentes sanitários. O intuito foi definir uma metodologia de aplicação rápida, fácil e confiável para este tipo de amostra. As lagoas de estabilização, como sistemas de tratamento biológico, têm como principais constituintes proteínas, carboidratos e lipídeos, mas também apresentam muitos compostos interferentes, como por exemplo, uréia, detergentes e compostos fenólicos, que podem prejudicar a quantificação de tais parâmetros. Os métodos analisados foram Lowry, Biureto, Bradford e Ácido bicinconínico. O método de Lowry mostrou-se mais adequado às características da amostra, com boa reprodutibilidade, reagente específico, custo moderado e ausência de substancias interferentes.This research had as main objective to compare five spectrophotometric methods for protein determination in samples proceeding from sanitary effluent of treatment plant. Intention was to define a methodology that is of fast and easy and reliable application for this type of sample. The stabilization ponds, as systems of biological treatment, have as main constituent proteins, carbohydrates and lipids, but also they present many interfering composites, for example, phenolic urea, detergents and composites, that can harm the quantification of such parameters. The analyzed methods had been Lowry, Biuret, Bradford and Acid bicinconinic. The method of Lowry revealed more adequate to the characteristics of the sample, with good reproducibility, specific reagent, moderate cost and absence of interfering substance.

  17. Eficiência da interação biodigestor e lagoas de estabilização na remoção de poluentes em dejetos de suínos Efficiency of biodigester and stabilization pond interaction in removal of swine manure pollutants

    Directory of Open Access Journals (Sweden)

    Marcelo Vivan

    2010-03-01

    Full Text Available A suinocultura é considerada atividade de alto poder poluidor, face ao elevado número de contaminantes nos seus efluentes, maximizado com o modelo de criação intensiva. Com o objetivo de contribuir para a reversão deste quadro, o presente trabalho teve a finalidade de avaliar o desempenho de um sistema de tratamento composto de um biodigestor e lagoas de estabilização (lagoa anaeróbia, uma facultativa e duas lagoas de maturação ligadas em série alimentadas com lodo proveniente de uma estação de tratamento de dejetos de suínos. O sistema mostrou-se eficiente para estabilização do resíduo, principalmente da carga orgânica; no entanto, apresenta algumas limitações para redução de nutrientes, sobretudo do nitrogênio, pela contribuição de volatilização de amônia.Swine production is considered an activity with a high environmental impact, due to the presence of a high number of contaminants in the effluents that come out from the piggery. In this study the feasibility of a combined process biodigestor and stabilization ponds (anaerobic, facultative and maturation connected in sequence fed with sludge from a swine manure treatment unit was evaluated. The system showed itsetf as efficient in the removal of organic matter, however it presented some limitations in removing nutrients, especially nitrogen, mainly due to the contribution of volatilization of ammonia.

  18. Modelling radiative transfer through ponded first-year Arctic sea ice with a plane-parallel model

    Science.gov (United States)

    Taskjelle, Torbjørn; Hudson, Stephen R.; Granskog, Mats A.; Hamre, Børge

    2017-09-01

    Under-ice irradiance measurements were done on ponded first-year pack ice along three transects during the ICE12 expedition north of Svalbard. Bulk transmittances (400-900 nm) were found to be on average 0.15-0.20 under bare ice, and 0.39-0.46 under ponded ice. Radiative transfer modelling was done with a plane-parallel model. While simulated transmittances deviate significantly from measured transmittances close to the edge of ponds, spatially averaged bulk transmittances agree well. That is, transect-average bulk transmittances, calculated using typical simulated transmittances for ponded and bare ice weighted by the fractional coverage of the two surface types, are in good agreement with the measured values. Radiative heating rates calculated from model output indicates that about 20 % of the incident solar energy is absorbed in bare ice, and 50 % in ponded ice (35 % in pond itself, 15 % in the underlying ice). This large difference is due to the highly scattering surface scattering layer (SSL) increasing the albedo of the bare ice.

  19. Modelling radiative transfer through ponded first-year Arctic sea ice with a plane-parallel model

    Directory of Open Access Journals (Sweden)

    T. Taskjelle

    2017-09-01

    Full Text Available Under-ice irradiance measurements were done on ponded first-year pack ice along three transects during the ICE12 expedition north of Svalbard. Bulk transmittances (400–900 nm were found to be on average 0.15–0.20 under bare ice, and 0.39–0.46 under ponded ice. Radiative transfer modelling was done with a plane-parallel model. While simulated transmittances deviate significantly from measured transmittances close to the edge of ponds, spatially averaged bulk transmittances agree well. That is, transect-average bulk transmittances, calculated using typical simulated transmittances for ponded and bare ice weighted by the fractional coverage of the two surface types, are in good agreement with the measured values. Radiative heating rates calculated from model output indicates that about 20 % of the incident solar energy is absorbed in bare ice, and 50 % in ponded ice (35 % in pond itself, 15 % in the underlying ice. This large difference is due to the highly scattering surface scattering layer (SSL increasing the albedo of the bare ice.

  20. Technology demonstration assessment report for X-701B Holding Pond

    International Nuclear Information System (INIS)

    1992-07-01

    This Technology Demonstration Assessment Report (TDAR) was developed to evaluate and recommend the most feasible approach for cleanup of contaminated Minford soils below the X-701B Holding Pond and to summarize closure activities at the Portsmouth Gaseous Diffusion Plant (PORTS)X-701B Holding Pond(X-701B)site. In this TDAR, the recommended alternative and the activities for closure of the X-701B site are discussed. Four treatment technologies chosen for the TD, along with a contingent design, were evaluated to determine which approach would be appropriate for final closure of X-701B. These technologies address removal of soil contamination from the vadose zone and the saturated zone. The four technologies plus the Contingent Design evaluated were: In situ Soil Mixing with Solidification/Stabilization; In situ Soil Mixing with Isothermal Vapor Extraction; In situ Soil Mixing with Thermally Enhanced Vapor Extraction; In situ Soil Mixing with Peroxidation Destruction; and Contingent Closure. These technologies were evaluated according to their performance, reliability, implementability, safety, waste minimization, cost, and implementation time. Based on these criteria, a preferred treatment approach was recommended. The goal of the treatment approach is to apply the most appropriate technology demonstrated at X-231 B in order to reduce Volatile Organic Compounds (VOCs) in the saturated Minford soils directly beneath the X-701B Holding Pond. The closure schedule will include bid and award of two construction contracts, mobilization and demobilization, soil treatment, cap design, and cap construction. The total time required for soil treatment will be established based on actual performance of the soil treatment approach in the field

  1. Effect of the Side Chains and Anode Material on Thermal Stability and Performance of Bulk-Heterojunction Solar Cells Using DPP(TBFu2 Derivatives as Donor Materials

    Directory of Open Access Journals (Sweden)

    Alexander Kovalenko

    2015-01-01

    Full Text Available An optimized fabrication of bulk-heterojunction solar cells (BHJ SCs based on previously reported diketopyrrolopyrrole donor, ethyl-hexylated DPP(TBFu2, as well as two new DPP(TBFu2 derivatives with ethyl-hexyl acetate and diethyl acetal solubilizing side-chains and PC60BM as an acceptor is demonstrated. Slow gradual annealing of the solar cell causing the effective donor-acceptor reorganization, and as a result higher power conversion efficiency (PCE, is described. By replacing a hole transporting layer PEDOT:PSS with MoO3 we obtained higher PCE values as well as higher thermal stability of the anode contact interface. DPP(TBFu2 derivative containing ethyl-hexyl acetate solubilizing side-chains possessed the best as-cast self-assembly and high crystallinity. However, the presence of ethyl-hexyl acetate and diethyl acetal electrophilic side-chains stabilizes HOMO energy of isolated DPP(TBFu2 donors with respect to the ethyl-hexylated one, according to cyclic voltammetry.

  2. Fast Crystallization and improved Stability of Perovskite Solar Cells with Zn 2 SnO 4 Electron Transporting Layer: Interface Matters

    KAUST Repository

    Bera, Ashok

    2015-12-03

    Here we report that mesoporous ternary oxide Zn2SnO4 can significantly promotes the crystallization of hybrid perovskite layers and serves as an efficient electron transporting material in perovskite solar cells. Such devices exhibit an energy conversion efficiency of 13.34%, which is even higher than that achieved with the commonly used TiO2 in the similar experimental conditions (9.1%). Simple one-step spin coating of CH3NH3PbI3−xClx on Zn2SnO4 is found to lead to rapidly crystalized bilayer perovskite structure without any solvent engineering. Furthermore, ultrafast transient absorption measurement reveals efficient charge transfer at the Zn2SnO4/perovskite interface. Most importantly, solar cells with Zn2SnO4 as the electron-transporting material exhibit negligible electrical hysteresis and exceptionally high stability without encapsulation for over one month. Besides underscoring Zn2SnO4 as a highly promising electron transporting material for perovskite solar cells, our results demonstrate the significant role of interfaces on improving the perovskite crystallization and photovoltaic performance.

  3. Models and observations of Arctic melt ponds

    Science.gov (United States)

    Golden, K. M.

    2016-12-01

    During the Arctic melt season, the sea ice surface undergoes a striking transformation from vast expanses of snow covered ice to complex mosaics of ice and melt ponds. Sea ice albedo, a key parameter in climate modeling, is largely determined by the complex evolution of melt pond configurations. In fact, ice-albedo feedback has played a significant role in the recent declines of the summer Arctic sea ice pack. However, understanding melt pond evolution remains a challenge to improving climate projections. It has been found that as the ponds grow and coalesce, the fractal dimension of their boundaries undergoes a transition from 1 to about 2, around a critical length scale of 100 square meters in area. As the ponds evolve they take complex, self-similar shapes with boundaries resembling space-filling curves. I will outline how mathematical models of composite materials and statistical physics, such as percolation and Ising models, are being used to describe this evolution and predict key geometrical parameters that agree very closely with observations.

  4. Solar thermal technology report, FY 1981. Volume 1: Executive summary

    Science.gov (United States)

    1982-01-01

    The activities of the Department of Energy's Solar Thermal Technology Program are discussed. Highlights of technical activities and brief descriptions of each technology are given. Solar thermal conversion concepts are discussed in detail, particularily concentrating collectors and salt-gradient solar ponds.

  5. Effect of a bentonite/soil mixture as a barrier for uranium ponds

    International Nuclear Information System (INIS)

    Osmanlioglu, A.E.

    2002-01-01

    Uranium mill tailings need safe management as they contain long-lived uranium and its daughters. Chemical treatment applied on these tailings to neutralize the acid solution and to stabilize the remaining radioactive elements. Then they are stored in ponds. These ponds are used for the accumulation of the solids and evaporation of the liquids. Sometimes the liquid returned to the plant for reuse. These applications are used to isolate the tailings from the environment. The purpose of this laboratory test is; initially to determine the effectiveness of bentonite/soil mixture as a barrier for uranium ponds. In this study, two experimental ponds equipped; with different two barriers in laboratory. Dimension of this container is; 120 cm in length, 100 cm in width and 100cm in depth. Sampling pipes were placed at different places of the container. First pond includes ordinary soil; second pond includes soil/bentonite mixture. Uranium mill tailing ponds were placed at the surfaces of these two systems. Uranium solution was prepared by using natural uranium ore. The solution was put into these ponds. These test carried out more than for 10 months. Passed solution was collected by sampling pipes and recorded. Amounts of passed solution were determined according to the location of discharge pipes. At the last stage of these tests, sampling from the different parts o the system has been carried out by small holes, which were opened from the surface by special sampling device. By this way, migration information about the upper parts of the sampling pipes has been received. Behaviour of uranium radionuclides and the effectiveness of the bentonite/soil mixture were experimentally determined. Bentonite/soil mixture layer has better ability to restrain the migration of uranium radionuclides. The performance of the ponds at the natural soil can be improved simply by mixing with bentonite during construction. Bentonite/soil mixture includes 5% bentonite, 95% ordinary soil in weight

  6. N-type polymers as electron extraction layers in hybrid perovskite solar cells with improved ambient stability

    NARCIS (Netherlands)

    Shao, S.; Chen, Z.; Fang, H. -H.; ten Brink, G. H.; Bartesaghi, D.; Adjokatse, S.; Koster, L. J. A.; Kooi, B. J.; Facchetti, A.; Loi, M. A.

    2016-01-01

    We studied three n-type polymers of the naphthalenediimide-bithiophene family as electron extraction layers (EELs) in hybrid perovskite solar cells. The recombination mechanism in these devices is found to be heavily influenced by the EEL transport properties. The maximum efficiency of the devices

  7. Accumulation of Pollutants in Highway Detention Ponds

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby

    single rain event. From the hindcast results it is possible to calculate mean water and pollutant loads. This method is commonly used in urban drainage systems for capacity analysis or for prediction of CSO's. The challenge is to develop a simplified and still accurate description of flow and transport......This PhD study deals with issues related to water and pollutant transport from highway surfaces caused by rain. It is essential in the study to apply methods and models in which improvements in relation to removal of pollutants can be identified and to be able to predict the yearly discharges....... Measurements of water and pollutant transport are carried out in different highway systems. A geometrically well-defined test pond is established, wherein the deposition of particulate matter can be measured. The result from the test pond is transferred to real detention ponds in which the three...

  8. Fate of Pyrethroids in Farmland Ponds

    DEFF Research Database (Denmark)

    Mogensen, B. B.; Sørensen, P. B.; Stuer-Lauridsen, F.

    Pyrethroids constitute a group of widely used insecticides, which are toxic to aquatic organisms. This report presents the results from a 2-year study of the fate of pyrethroids in ponds, i.e. their distribution in the water column, the sediment and the surface microlayer respectively. The measur......Pyrethroids constitute a group of widely used insecticides, which are toxic to aquatic organisms. This report presents the results from a 2-year study of the fate of pyrethroids in ponds, i.e. their distribution in the water column, the sediment and the surface microlayer respectively...

  9. Pond dyes are Culex mosquito oviposition attractants

    Directory of Open Access Journals (Sweden)

    Natali Ortiz Perea

    2017-05-01

    Full Text Available Background British mosquito population distribution, abundance, species composition and potential for mosquito disease transmission are intimately linked to the physical environment. The presence of ponds and water storage can significantly increase the density of particular mosquito species in the garden. Culex pipiens is the mosquito most commonly found in UK gardens and a potential vector of West Nile Virus WNV, although the current risk of transmission is low. However any factors that significantly change the distribution and population of C. pipiens are likely to impact subsequent risk of disease transmission. Pond dyes are used to control algal growth and improve aesthetics of still water reflecting surrounding planting. However, it is well documented that females of some species of mosquito prefer to lay eggs in dark water and/or containers of different colours and we predict that dyed ponds will be attractive to Culex mosquitoes. Methods Black pond dye was used in oviposition choice tests using wild-caught gravid C. pipiens. Larvae from wild-caught C. pipiens were also reared in the pond dye to determine whether it had any impact on survival. An emergence trap caught any adults that emerged from the water. Water butts (80 L were positioned around university glasshouses and woodland and treated with black pond dye or left undyed. Weekly sampling over a six month period through summer and autumn was performed to quantified numbers of larvae and pupae in each treatment and habitat. Results Gravid female Culex mosquitoes preferred to lay eggs in dyed water. This was highly significant in tests conducted under laboratory conditions and in a semi-field choice test. Despite this, survivorship in black dyed water was significantly reduced compared to undyed water. Seasonal analysis of wild larval and pupal numbers in two habitats with and without dye showed no impact of dye but a significant impact of season and habitat. Mosquitoes were more

  10. Solar Thermal Utilization: Past, Present and Future

    Science.gov (United States)

    2010-09-01

    SO•C NON-FOCUSSING FLAT PLATE / (FPC) 100- 150•C For low temperature 50- 200•C COMPOUND applications PARABOLIC EVACUATED CONCENTRATOR ~ (ETC...2030 Ø 200GW BY 2050 Ø 20 MILLION SQ.METER SOLAR THERMAL COLLECTORS (20GW power) Ø 20 MILLION SOLAR LIGHTS LAUNCHING OF SOLAR INDIA SOLAR THERMAL...Temperature (20oC- 80oC) NALSUN ApplicationsThermal Conversion range SOLAR ENERGY COLLECTORS 40- GO•C UNGLAZED COLLECTORS 60- 90•C SOLAR POND 60

  11. variation of some waste stabilization pond parameters with shape

    African Journals Online (AJOL)

    solids, oxygen demand and nutrient environment. ... quality guidelines both at low cost and with ... are not the best option for less developed ... Many models by Polprasert and Others, 1983; ... quality, design and dynamic, temperature profile, .... The variance determination represents and includes all points in the curve.

  12. Sea Ice Melt Pond Data from the Canadian Arctic

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set contains observations of albedo, depth, and physical characteristics of melt ponds on sea ice, taken during the summer of 1994. The melt ponds studied...

  13. Valuing Multiple Benefits, and the Public Perception of SUDS Ponds

    Directory of Open Access Journals (Sweden)

    Joy Jarvie

    2017-02-01

    Full Text Available Understanding how the public perceive and value ponds is fundamental to appreciate the synergy between Sustainable urban Drainage (SUDS ponds and the multiple benefits they provide. This paper investigates this, through the application of a structured postal and online survey, for a case study area of Edinburgh, in the UK. It compares man-made ponds (including SUDS, and ponds with natural origins. The results from Whole Life Cost show that the benefits (based on Contingent Valuation exceed the CAPEX and OPEX costs for three of five artificial ponds studied. Benefits from natural (reference ponds exceed the replacement costs for a pond with the same surface area/catchment. This paper highlights the importance of monetising the multiple benefits from ponds.

  14. Study on the chemical stability of catalyst counter electrodes for dye-sensitized solar cells using a simple X-ray photoelectron spectroscopy-based method

    Science.gov (United States)

    Yun, Dong-Jin; Kim, Jungmin; Chung, Jongwon; Park, SungHoon; Baek, WoonJoong; Kim, Yongsu; Kim, Seongheon; Kwon, Young-Nam; Chung, JaeGwan; Kyoung, Yongkoo; Kim, Ki-Hong; Heo, Sung

    2014-12-01

    Since the chemical/electrical stability and catalytic activity are essential conditions for catalyst counter electrodes (CCEs) in dye-sensitized solar cells (DSSCs), a simple dipping method is employed for evaluating the chemical stability of CCE candidates in an iodine-based liquid electrolyte (I-electrolyte). The chemical stabilities and transition mechanisms of the CCEs are successfully analyzed by studying the chemical transitions in X-ray photoelectron spectroscopy (XPS) core levels after dipping in the I-electrolyte. All films including the Pt film undergo degradation depending on the type of material. While dipping in the I-electrolyte, Cu and Au films scarcely dissolves as their respective metal sulfides, and the Al film gradually loss its metallic properties owing to Al2O3 growth. On the other hand, a previously unknown transition mechanism of organic conducting CCEs is determined based on the proposed method. Compared to the other metal films, the poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) and multi wall carbon nanotube (MWCNT)/PEDOT:PSS films undergo an entirely unique transition mechanism, which results from the chemical adsorption of organic molecules onto PEDOT:PSS molecules in the I-electrolyte. Consequently, these chemical structure transitions correspond well to the degrees of alternation in the electrical properties of DSSCs with all the investigated CCEs.

  15. Photovoltaic performance and stability of fullerene/cerium oxide double electron transport layer superior to single one in p-i-n perovskite solar cells

    Science.gov (United States)

    Xing, Zhou; Li, Shu-Hui; Wu, Bao-Shan; Wang, Xin; Wang, Lu-Yao; Wang, Tan; Liu, Hao-Ran; Zhang, Mei-Lin; Yun, Da-Qin; Deng, Lin-Long; Xie, Su-Yuan; Huang, Rong-Bin; Zheng, Lan-Sun

    2018-06-01

    Interface engineering that involves in the metal cathodes and the electron transport layers (ETLs) facilitates the simultaneous improvement of device performances and stability in perovskite solar cells (PSCs). Herein, low-temperature solution-processed cerium oxide (CeOx) films are prepared by a facile sol-gel method and employed as the interface layers between [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) and an Ag back contact to form PC61BM/CeOx double ETLs. The introduction of CeOx enables electron extraction to the Ag electrode and protects the underlying perovskite layer and thus improves the device performance and stability of the p-i-n PSCs. The p-i-n PSCs with double PC61BM/CeOx ETLs demonstrate a maximum power conversion efficiency (PCE) of 17.35%, which is superior to those of the devices with either PC61BM or CeOx single ETLs. Moreover, PC61BM/CeOx devices exhibit excellent stability in light soaking, which is mainly due to the chemically stable CeOx interlayer. The results indicate that CeOx is a promising interface modification layer for stable high-efficiency PSCs.

  16. Revealing the influence of Cyano in Anchoring Groups of Organic Dyes on Adsorption Stability and Photovoltaic Properties for Dye-Sensitized Solar Cells.

    Science.gov (United States)

    Chen, Wei-Chieh; Nachimuthu, Santhanamoorthi; Jiang, Jyh-Chiang

    2017-07-10

    Determining an ideal adsorption configuration for a dye on the semiconductor surface is an important task in improving the overall efficiency of dye-sensitized solar cells. Here, we present a detailed investigation of different adsorption configurations of designed model dyes on TiO 2 anatase (101) surface using first principles methods. Particularly, we aimed to investigate the influence of cyano group in the anchoring part of dye on its adsorption stability and the overall photovoltaic properties such as open circuit voltage, electron injection ability to the surface. Our results indicate that the inclusion of cyano group increases the stability of adsorption only when it adsorbs via CN with the surface and it decreases the photovoltaic properties when it does not involve in binding. In addition, we also considered full dyes based on the results of model dyes and investigated the different strength of acceptor abilities on stability and electron injection ability. Among the various adsorption configurations considered here, the bidentate bridging mode (A3) is more appropriate one which has higher electron injection ability, larger V OC value and more importantly it has higher dye loading on the surface.

  17. EVALUACIÓN DE ALTERNATIVAS PARA CLIMATIZACIÓN DE ESTANQUES CON ENERGÍA SOLAR PARA CULTIVO DE TILAPIA ROJA (Oreochromis sp), LOCALIZADOS EN LA ZONA FRÍA DEL VALLE DEL CAUCA, COLOMBIA EVALUATION OF ALTERNATIVES FOR AIR CONDITIONING OF PONDS WITH SOLAR ENERGY FOR CULTIVATION OF RED TILAPIA (Oreochromis sp), LOCATED IN THE COLD AREA OF THE CAUCA VALLEY, COLOMBIA

    OpenAIRE

    Francisco Javier Borja Gallardo; Luis Octavio González Salcedo; Victoria Eugenia Quintero de Vallejo

    2006-01-01

    La investigación fue desarrollada para que la tilapia roja (Oreochromis sp), especie de pez mÁs producida en Colombia, pueda ser explotada en lugares donde las condiciones óptimas para su normal desarrollo no son las adecuadas, como son las regiones altas con temperaturas por debajo de los 24 °C, aplicando metodologías relacionadas con el aprovechamiento de la energía solar. Las técnicas evaluadas fueron: climatización por medio de colectores solares, climatización por medio de manta térmica,...

  18. Engineering of Porphyrin Molecules for Use as Effective Cathode Interfacial Modifiers in Organic Solar Cells of Enhanced Efficiency and Stability.

    Science.gov (United States)

    Tountas, Marinos; Verykios, Apostolis; Polydorou, Ermioni; Kaltzoglou, Andreas; Soultati, Anastasia; Balis, Nikolaos; Angaridis, Panagiotis A; Papadakis, Michael; Nikolaou, Vasilis; Auras, Florian; Palilis, Leonidas C; Tsikritzis, Dimitris; Evangelou, Evangelos K; Gardelis, Spyros; Koutsoureli, Matroni; Papaioannou, George; Petsalakis, Ioannis D; Kennou, Stella; Davazoglou, Dimitris; Argitis, Panagiotis; Falaras, Polycarpos; Coutsolelos, Athanassios G; Vasilopoulou, Maria

    2018-06-06

    In the present work, we effectively modify the TiO 2 electron transport layer of organic solar cells with an inverted architecture using appropriately engineered porphyrin molecules. The results show that the optimized porphyrin modifier bearing two carboxylic acids as the anchoring groups and a triazine electron-withdrawing spacer significantly reduces the work function of TiO 2 , thereby reducing the electron extraction barrier. Moreover, the lower surface energy of the porphyrin-modified substrate results in better physical compatibility between the latter and the photoactive blend. Upon employing porphyrin-modified TiO 2 electron transport layers in PTB7:PC 71 BM-based organic solar cells we obtained an improved average power conversion efficiency up to 8.73%. Importantly, porphyrin modification significantly increased the lifetime of the devices, which retained 80% of their initial efficiency after 500 h of storage in the dark. Because of its simplicity and efficacy, this approach should give tantalizing glimpses and generate an impact into the potential of porphyrins to facilitate electron transfer in organic solar cells and related devices.

  19. The refreezing of melt ponds on Arctic sea ice

    Science.gov (United States)

    Flocco, Daniela; Feltham, Daniel L.; Bailey, Eleanor; Schroeder, David

    2015-02-01

    The presence of melt ponds on the surface of Arctic sea ice significantly reduces its albedo, inducing a positive feedback leading to sea ice thinning. While the role of melt ponds in enhancing the summer melt of sea ice is well known, their impact on suppressing winter freezing of sea ice has, hitherto, received less attention. Melt ponds freeze by forming an ice lid at the upper surface, which insulates them from the atmosphere and traps pond water between the underlying sea ice and the ice lid. The pond water is a store of latent heat, which is released during refreezing. Until a pond freezes completely, there can be minimal ice growth at the base of the underlying sea ice. In this work, we present a model of the refreezing of a melt pond that includes the heat and salt balances in the ice lid, trapped pond, and underlying sea ice. The model uses a two-stream radiation model to account for radiative scattering at phase boundaries. Simulations and related sensitivity studies suggest that trapped pond water may survive for over a month. We focus on the role that pond salinity has on delaying the refreezing process and retarding basal sea ice growth. We estimate that for a typical sea ice pond coverage in autumn, excluding the impact of trapped ponds in models overestimates ice growth by up to 265 million km3, an overestimate of 26%.

  20. Heavy metal composition in stormwater and retention in ponds dependent on pond age, design and catchment type

    DEFF Research Database (Denmark)

    Egemose, Sara; Sønderup, Melanie J.; Grudinina, Anna

    2015-01-01

    Heavy metals have toxic effects on flora and fauna in the aquatic environments and are of great concern in stormwater. Heavy metal runoff was studied in 37 stormwater ponds in Denmark with varying heavy metal load, catchment type and pond design. The studied metals were Cu, Cr, Cd, Pb, Ni and Zn...... difficult to retain. The removal efficiency in the ponds varied considerably, with the highest retention of Pb, Ni and Zn due to higher particulate fraction. The retention increased with increased pond volume-to-reduced catchment area ratio. In addition, the pond age affected the efficiency; whereas ponds...... less than 1-2 years efficiently removed all metals, 30-40-year-old ponds only removed Pb, Ni and Zn, but steeply decreasing over the years. Physical parameters such as pond size, age and sedimentation patterns were found to play a more significant role in the removal compared with chemical parameters...

  1. EVALUACIÓN DE ALTERNATIVAS PARA CLIMATIZACIÓN DE ESTANQUES CON ENERGÍA SOLAR PARA CULTIVO DE TILAPIA ROJA (Oreochromis sp, LOCALIZADOS EN LA ZONA FRÍA DEL VALLE DEL CAUCA, COLOMBIA EVALUATION OF ALTERNATIVES FOR AIR CONDITIONING OF PONDS WITH SOLAR ENERGY FOR CULTIVATION OF RED TILAPIA (Oreochromis sp, LOCATED IN THE COLD AREA OF THE CAUCA VALLEY, COLOMBIA

    Directory of Open Access Journals (Sweden)

    Francisco Javier Borja Gallardo

    2006-06-01

    Full Text Available La investigación fue desarrollada para que la tilapia roja (Oreochromis sp, especie de pez mÁs producida en Colombia, pueda ser explotada en lugares donde las condiciones óptimas para su normal desarrollo no son las adecuadas, como son las regiones altas con temperaturas por debajo de los 24 °C, aplicando metodologías relacionadas con el aprovechamiento de la energía solar. Las técnicas evaluadas fueron: climatización por medio de colectores solares, climatización por medio de manta térmica, climatización por medio de mangueras térmicas y climatización por medio de resistencias eléctricas. Se analizaron factores como funcionalidad, mantenimiento, limitaciones organizativas, espaciales, y costos.The research was developed so that the red tilapia (Oreochromis sp, fish species that more taken place in Colombia can be exploited in regions where the good conditions for its normal development are not the appropriate ones as in the high regions with temperatures below the 24 °C, applying methodologies related with the use of the solar energy. The evaluated methodologies were: air conditioning by means of solar collectors, air conditioning by means of thermal blanket, air conditioning by means of thermal hoses and air conditioning by means of electric resistances. Factors like functionality, maintenance, organizational and space limitations, and costs were analized.

  2. Characterisation of potential aquaculture pond effluents, and ...

    African Journals Online (AJOL)

    Conventional treatment of effluents from these small-scale, low-volume operations, which discharge relatively dilute effluents infrequently, might not be cost-effective. Keywords: aquaculture–environment interaction, earthen ponds, effluent characterisation, K-means clustering, t ilapia, water quality. African Journal of Aquatic ...

  3. Aquatic Habitats: Exploring Desktop Ponds. Teacher's Guide.

    Science.gov (United States)

    Barrett, Katharine; Willard, Carolyn

    This book, for grades 2-6, is designed to provide students with a highly motivating and unique opportunity to investigate an aquatic habitat. Students set up, observe, study, and reflect upon their own "desktop ponds." Accessible plants and small animals used in these activities include Elodea, Tubifex worms, snails, mosquito larvae, and fish.…

  4. Interconnected ponds operation for flood hazard distribution

    Science.gov (United States)

    Putra, S. S.; Ridwan, B. W.

    2016-05-01

    The climatic anomaly, which comes with extreme rainfall, will increase the flood hazard in an area within a short period of time. The river capacity in discharging the flood is not continuous along the river stretch and sensitive to the flood peak. This paper contains the alternatives on how to locate the flood retention pond that are physically feasible to reduce the flood peak. The flood ponds were designed based on flood curve number criteria (TR-55, USDA) with the aim of rapid flood peak capturing and gradual flood retuning back to the river. As a case study, the hydrologic condition of upper Ciliwung river basin with several presumed flood pond locations was conceptually designed. A fundamental tank model that reproducing the operation of interconnected ponds was elaborated to achieve the designed flood discharge that will flows to the downstream area. The flood hazard distribution status, as the model performance criteria, will be computed within Ciliwung river reach in Manggarai Sluice Gate spot. The predicted hazard reduction with the operation of the interconnected retention area result had been bench marked with the normal flow condition.

  5. Scenario evaluation of open pond microalgae production

    NARCIS (Netherlands)

    Slegers, P.M.; Lösing, M.B.; Wijffels, R.H.; Straten, van G.; Boxtel, van A.J.B.

    2013-01-01

    To evaluate microalgae production in large scale open ponds under different climatologic conditions, a model-based framework is used to study the effect of light conditions, water temperature and reactor design on trends in algae productivity. Scenario analyses have been done for two algae species

  6. A stability study of polymer solar cells using conjugated polymers with different donor or acceptor side chain patterns

    DEFF Research Database (Denmark)

    Heckler, Ilona Maria; Kesters, Jurgen; Defour, Maxime

    2016-01-01

    -phenylethyl group. It is shown that the exchange of the hexyl chain on the DTBT moiety has a negative impact on the stability of the polymer as well as on the performance of the resulting PSCs. On the other hand, partial exchange of the 2-hexyldecyl side chain of the BDT unit by a 2-hydroxyethyl group results......)benzo[c][1,2,5]thiadiazole (DTBT), specifically selected because of its suitability for roll-coating in the ambient environment, is investigated in terms of operational stability via partial exchange (5 or 10%) of the alkyl side chain on either the donor or the acceptor monomer with a 2-hydroxyethyl or 2...

  7. Room-Temperature Atomic Layer Deposition of Al2 O3 : Impact on Efficiency, Stability and Surface Properties in Perovskite Solar Cells.

    Science.gov (United States)

    Kot, Malgorzata; Das, Chittaranjan; Wang, Zhiping; Henkel, Karsten; Rouissi, Zied; Wojciechowski, Konrad; Snaith, Henry J; Schmeisser, Dieter

    2016-12-20

    In this work, solar cells with a freshly made CH 3 NH 3 PbI 3 perovskite film showed a power conversion efficiency (PCE) of 15.4 % whereas the one with 50 days aged perovskite film only 6.1 %. However, when the aged perovskite was covered with a layer of Al 2 O 3 deposited by atomic layer deposition (ALD) at room temperature (RT), the PCE value was clearly enhanced. X-ray photoelectron spectroscopy study showed that the ALD precursors are chemically active only at the perovskite surface and passivate it. Moreover, the RT-ALD-Al 2 O 3 -covered perovskite films showed enhanced ambient air stability. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Solar Thermochemical Fuel Production via a Novel Low Pressure, Magnetically Stabilized, Non-volatile Iron Oxide Looping Process (University of Florida)

    Energy Technology Data Exchange (ETDEWEB)

    Hahn, David W.

    2018-03-29

    The UF Solar Fuels team has developed a modular reactor at the 10kW scale for the thermochemical conversion of H2O and CO2 to H2 and CO, respectively, using concentrated solar energy to drive high-temperature redox reactions. Various materials, including ferrites, doped and mixed metal ferrites, and ceria, were investigated and reported on. Ceria was chosen as the reactive material, with thermogravimetric and bench-scale analysis concurring with literature review and pointing towards reasonable kinetics and stability at temperatures on the order of 1500 °C. A combined radiation, conduction, and species reaction/mass transport model was developed, utilizing Monte Carlo ray tracing, Lattice Boltzmann, and random walk particle tracking for the respective components to direct development and optimization of the reactor. With experimental data used for reaction rates, the model showed a path to efficiencies >20%, which could be market competitive with current PV-hydrolysis hydrogen generation systems. Economic analysis of a larger-scale plant (100kW modular system with cost performed at 500 modules) has been performed, assuming 0.5% and 10% internal rate of return. Without compression costs, H2 production cost using this is technology at $12/kg H2 and $17/kg H2 for realized efficiencies of 20% and 15%, respectively. An interaction of ceria and alumina, with the formation of CeAlO3 occurring at ~1700 °C, had been reported in the literature, but the UF Solar Fuels team observed and reported on it at a large scale, confirming its presence as an engineering consideration when working ceria and alumina at extreme temperatures. CeAlO3 could be being produced at lower temperatures due to the oxidation and reducing environments or due to local hotspots in the reactor. A solar thermogravimeter was developed, to take advantage of the high heating rates available at the UF Solar Simulator Facility to allow investigation of species evolution and material stability in extreme

  9. A Biopolymer Heparin Sodium Interlayer Anchoring TiO2 and MAPbI3 Enhances Trap Passivation and Device Stability in Perovskite Solar Cells.

    Science.gov (United States)

    You, Shuai; Wang, Hui; Bi, Shiqing; Zhou, Jiyu; Qin, Liang; Qiu, Xiaohui; Zhao, Zhiqiang; Xu, Yun; Zhang, Yuan; Shi, Xinghua; Zhou, Huiqiong; Tang, Zhiyong

    2018-04-18

    Traps in the photoactive layer or interface can critically influence photovoltaic device characteristics and stabilities. Here, traps passivation and retardation on device degradation for methylammonium lead trihalide (MAPbI 3 ) perovskite solar cells enabled by a biopolymer heparin sodium (HS) interfacial layer is investigated. The incorporated HS boosts the power conversion efficiency from 17.2 to 20.1% with suppressed hysteresis and Shockley-Read-Hall recombination, which originates primarily from the passivation of traps near the interface between the perovskites and the TiO 2 cathode. The incorporation of an HS interfacial layer also leads to a considerable retardation of device degradation, by which 85% of the initial performance is maintained after 70 d storage in ambient environment. Aided by density functional theory calculations, it is found that the passivation of MAPbI 3 and TiO 2 surfaces by HS occurs through the interactions of the functional groups (COO - , SO 3 - , or Na + ) in HS with undersaturated Pb and I ions in MAPbI 3 and Ti 4+ in TiO 2 . This work demonstrates a highly viable and facile interface strategy using biomaterials to afford high-performance and stable perovskite solar cells. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Highly active GaN-stabilized Ta{sub 3}N{sub 5} thin-film photoanode for solar water oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Miao; Hisatomi, Takashi; Sasaki, Yutaka; Nakabayashi, Mamiko; Shibata, Naoya; Nishiyama, Hiroshi; Katayama, Masao; Yamada, Taro; Domen, Kazunari [School of Engineering, the University of Tokyo (Japan); Japan Technological Research Association of Artificial Photosynthetic Chemical Process, Tokyo (Japan); Suzuki, Sayaka; Teshima, Katsuya [Faculty of Engineering, Shinshu University, Nagano (Japan)

    2017-04-18

    Ta{sub 3}N{sub 5} is a very promising photocatalyst for solar water splitting because of its wide spectrum solar energy utilization up to 600 nm and suitable energy band position straddling the water splitting redox reactions. However, its development has long been impeded by poor compatibility with electrolytes. Herein, we demonstrate a simple sputtering-nitridation process to fabricate high-performance Ta{sub 3}N{sub 5} film photoanodes owing to successful synthesis of the vital TaO{sub δ} precursors. An effective GaN coating strategy is developed to remarkably stabilize Ta{sub 3}N{sub 5} by forming a crystalline nitride-on-nitride structure with an improved nitride/electrolyte interface. A stable, high photocurrent density of 8 mA cm{sup -2} was obtained with a CoPi/GaN/Ta{sub 3}N{sub 5} photoanode at 1.2 V{sub RHE} under simulated sunlight, with O{sub 2} and H{sub 2} generated at a Faraday efficiency of unity over 12 h. Our vapor-phase deposition method can be used to fabricate high-performance (oxy)nitrides for practical photoelectrochemical applications. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

  11. Basal-topographic control of stationary ponds on a continuously moving landslide

    Science.gov (United States)

    Coe, J.A.; McKenna, J.P.; Godt, J.W.; Baum, R.L.

    2009-01-01

    The Slumgullion landslide in the San Juan Mountains of southwestern Colorado has been moving for at least the last few hundred years and has multiple ponds on its surface. We have studied eight ponds during 30 trips to the landslide between July 1998 and July 2007. During each trip, we have made observations on the variability in pond locations and water levels, taken ground-based photographs to document pond water with respect to moving landslide material and vegetation, conducted Global Positioning System surveys of the elevations of water levels and mapped pond sediments on the landslide surface. Additionally, we have used stereo aerial photographs taken in October 1939, October 1940 and July 2000 to measure topographic profiles of the eight pond locations, as well as a longitudinal profile along the approximate centerline of the landslide, to examine topographic changes over a 60- to 61-year period of time. Results from field observations, analyses of photographs, mapping and measurements indicate that all pond locations have remained spatially stationary for 60-300 years while landslide material moves through these locations. Water levels during the observation period were sensitive to changes in the local, spring-fed, stream network, and to periodic filling of pond locations by sediment from floods, hyperconcentrated flows, mud flows and debris flows. For pond locations to remain stationary, the locations must mimic depressions along the basal surface of the landslide. The existence of such depressions indicates that the topography of the basal landslide surface is irregular. These results suggest that, for translational landslides that have moved distances larger than the dimensions of the largest basal topographic irregularities (about 200 m at Slumgullion), landslide surface morphology can be used as a guide to the morphology of the basal slip surface. Because basal slip surface morphology can affect landslide stability, kinematic models and stability

  12. Microbial activities and communities in oil sands tailings ponds

    Energy Technology Data Exchange (ETDEWEB)

    Gieg, Lisa; Ramos, Esther; Clothier, Lindsay; Bordenave, Sylvain; Lin, Shiping; Voordouw, Gerrit; Dong, Xiaoli; Sensen, Christoph [University of Calgary (Canada)

    2011-07-01

    This paper discusses how the microbial communities and their activity play a vital role in tailings ponds. The ponds contain microorganisms along with metals, hydrocarbon diluent, naphthenic acid and others. The ponds play an important role in mining operations because they store bitumen extraction waste and also allow water to be re-used in the bitumen extraction process. Pond management presents a few challenges that include, among others, gas emissions and the presence of toxic and corrosive acids. Microbial activities and communities help in managing these ponds. Microbial activity measurement in active and inactive ponds is described and analyzed and the results are presented. The conditions for reducing sulfate, nitrate and iron are also presented. From the results it can be concluded that naphthenic acids can potentially serve as substrates for anaerobic populations in tailings ponds.

  13. Heavy metals, PAHs and toxicity in stormwater wet detention ponds

    DEFF Research Database (Denmark)

    Wium-Andersen, Tove; Nielsen, Asbjørn Haaning; Hvitved-Jacobsen, Thorkild

    2011-01-01

    Concentrations of 6 different heavy metals and total Polycyclic Aromatic Hydrocarbons (PAH) were determined in stormwater runoff and in the pond water of two Danish wet detention ponds. The pond water samples were analyzed for toxic effects, using the algae Selenastrum capricornutum as a test...... organism. Stormwater and pond water from a catchment with light industry showed high levels of heavy metals, especially zinc and copper. The pond water showed high toxic effects and copper were found to be the main toxicant. Additionally, a large part of the copper was suspected to be complex bound......, reducing the potential toxicity of the metal. Another catchment (residential) produced stormwater and pond water with moderate concentration of heavy metals. The pond water occasionally showed toxic effects but no correlation between heavy metals and toxicity was identified. PAHs concentrations were...

  14. Functional solid additive modified PEDOT:PSS as an anode buffer layer for enhanced photovoltaic performance and stability in polymer solar cells

    Science.gov (United States)

    Xu, Binrui; Gopalan, Sai-Anand; Gopalan, Anantha-Iyengar; Muthuchamy, Nallal; Lee, Kwang-Pill; Lee, Jae-Sung; Jiang, Yu; Lee, Sang-Won; Kim, Sae-Wan; Kim, Ju-Seong; Jeong, Hyun-Min; Kwon, Jin-Beon; Bae, Jin-Hyuk; Kang, Shin-Won

    2017-01-01

    Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is most commonly used as an anode buffer layer in bulk-heterojunction (BHJ) polymer solar cells (PSCs). However, its hygroscopic and acidic nature contributes to the insufficient electrical conductivity, air stability and restricted photovoltaic (PV) performance for the fabricated PSCs. In this study, a new multifunctional additive, 2,3-dihydroxypyridine (DOH), has been used in the PEDOT: PSS buffer layer to obtain modified properties for PEDOT: PSS@DOH and achieve high PV performances. The electrical conductivity of PEDOT:PSS@DOH films was markedly improved compared with that of PEDOT:PSS. The PEDOT:PSS@DOH film exhibited excellent optical characteristics, appropriate work function alignment, and good surface properties in BHJ-PSCs. When a poly(3-hexylthiohpene):[6,6]-phenyl C61-butyric acid methyl ester blend system was applied as the photoactive layer, the power conversion efficiency of the resulting PSCs with PEDOT:PSS@DOH(1.0%) reached 3.49%, outperforming pristine PEDOT:PSS, exhibiting a power conversion enhancement of 20%. The device fabricated using PEDOT:PSS@DOH (1.0 wt%) also exhibited improved thermal and air stability. Our results also confirm that DOH, a basic pyridine derivative, facilitates adequate hydrogen bonding interactions with the sulfonic acid groups of PSS, induces the conformational transformation of PEDOT chains and contributes to the phase separation between PEDOT and PSS chains. PMID:28338088

  15. Core/Shell Structured TiO2/CdS Electrode to Enhance the Light Stability of Perovskite Solar Cells.

    Science.gov (United States)

    Hwang, Insung; Baek, Minki; Yong, Kijung

    2015-12-23

    In this work, enhanced light stability of perovskite solar cell (PSC) achieved by the introduction of a core/shell-structured CdS/TiO2 electrode and the related mechanism are reported. By a simple solution-based process (SILAR), a uniform CdS shell was coated onto the surface of a TiO2 layer, suppressing the activation of intrinsic trap sites originating from the oxygen vacancies of the TiO2 layer. As a result, the proposed CdS-PSC exhibited highly improved light stability, maintaining nearly 80% of the initial efficiency after 12 h of full sunlight illumination. From the X-ray diffraction analyses, it is suggested that the degradation of the efficiency of PSC during illumination occurs regardless of the decomposition of the perovskite absorber. Considering the light-soaking profiles of the encapsulated cells and the OCVD characteristics, it is likely that the CdS shell had efficiently suppressed the undesirable electron kinetics, such as trapping at the surface defects of the TiO2 and preventing the resultant charge losses by recombination. This study suggests that further complementary research on various effective methods for passivation of the TiO2 layer would be highly meaningful, leading to insight into the fabrication of PSCs stable to UV-light for a long time.

  16. High-stability Ti{sup 4+} precursor for the TiO{sub 2} compact layer of dye-sensitized solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Yi, Qinghua; Cong, Shan; Wang, Hao; Wang, Yun; Dai, Xiao; Zhao, Jie; Sun, Yinghui; Lou, Yanhui; Zou, Guifu, E-mail: zouguifu@suda.edu.cn

    2015-11-30

    Graphical abstract: - Highlights: • We developed an aqueous polymer-assisted deposition method to improve the chemical stability of the TiCl{sub 4} aqueous solution. • The Ti{sup 4+} is encapsulated by the polymer can maintain their initial performances for several months. • The film is dense, smooth and uniform, preparing by this method. • The power conversion efficiency of the DSSC based on P-TiO{sub 2} compact film is about 12.5% higher than that based on H-TiO{sub 2}. - Abstract: A compact layer (blocking layer) can effectively block the direct contact between the fluorine-doped tin oxide (FTO) glass substrate and electrolyte in dye-sensitized solar cells (DSSCs). The TiCl{sub 4} hydrolysis has been widely adopted for preparing the TiO{sub 2} compact layer (H-TiO{sub 2}). However, the TiCl{sub 4} aqueous solution is unstable for its high reactivity. To improve the chemical stability of TiCl{sub 4} aqueous solution, the Ti{sup 4+} is encapsulated by the polymer, polyethyleneimine (PEI). Experimentals show that the Ti-PEI precursor solution can maintain their initial performances for several months. The resulting TiO{sub 2} film (P-TiO{sub 2}) grown by the Ti-PEI precursor is dense, smooth and uniform without any visible and detectable cracks or voids. The P-TiO{sub 2} compact layer is even denser than the H-TiO{sub 2} compact layer, suggesting reducing the electron recombination and prolonging the electron lifetime in dye-sensitized solar cells. Indeed, the electron lifetime of the DSSC based on the P-TiO{sub 2} is 13.15 ms, which is longer than the 10.83 ms based on H-TiO{sub 2}. Meanwhile, the power conversion efficiency of the DSSC based on P-TiO{sub 2} compact film is about 12.5% higher than that based on H-TiO{sub 2}. Therefore, this encapsulation technology can not only improve the stability of the metal ions solution but also meet a large-scale fabrication demand of the TiO{sub 2} compact layer in future DSSCs.

  17. Solar sail deployment experiment

    OpenAIRE

    Shimose, Shigeru; 下瀬 滋

    2006-01-01

    Solar Sail move by receiving momentum of photons in sunlight. This paper presents results of some Spin-Stabilized Solar Sail deployment experiment. ISAS has successfully deployed, for the first time in the world, the polyimide Solar Sail taking advantage of centrifugal force in space. Based on this result, the new deployment mechanism is being developed which retracts the 50 m diameter sail.

  18. Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer

    KAUST Repository

    Guarnera, Simone; Abate, Antonio; Zhang, Wei; Foster, Jamie M.; Richardson, Giles; Petrozza, Annamaria; Snaith, Henry J.

    2015-01-01

    © 2015 American Chemical Society. Hybrid perovskites represent a new paradigm for photovoltaics, which have the potential to overcome the performance limits of current technologies and achieve low cost and high versatility. However, an efficiency drop is often observed within the first few hundred hours of device operation, which could become an important issue. Here, we demonstrate that the electrode's metal migrating through the hole transporting material (HTM) layer and eventually contacting the perovskite is in part responsible for this early device degradation. We show that depositing the HTM within an insulating mesoporous "buffer layer" comprised of Al2O3 nanoparticles prevents the metal electrode migration while allowing for precise control of the HTM thickness. This enables an improvement in the solar cell fill factor and prevents degradation of the device after 350 h of operation. (Graph Presented).

  19. New iridium complex as additive to the spiro-OMeTAD in perovskite solar cells with enhanced stability

    Directory of Open Access Journals (Sweden)

    Laura Badia

    2014-08-01

    Full Text Available A new iridium complex, IrCp*Cl(PyPyz[TFSI], has been synthesized and used as additive for the hole transporter material, spiro-OMeTAD, in perovskite solar cells. The cells prepared with this Ir additive present higher efficiency than reference cells, and similar to cells prepared with Co additive. We have determined that the presence of metal complexes as additives decreases the recombination rate, as it has been observed by impedance spectroscopy. Very interestingly, while the efficiency after 3 months decreases by 22% and 70% for reference cell and cell with Co additive, respectively, the efficiency of devices containing the Ir additive is only decreased by a 4%.

  20. Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al 2 O 3 Buffer Layer

    KAUST Repository

    Guarnera, Simone

    2015-02-05

    © 2015 American Chemical Society. Hybrid perovskites represent a new paradigm for photovoltaics, which have the potential to overcome the performance limits of current technologies and achieve low cost and high versatility. However, an efficiency drop is often observed within the first few hundred hours of device operation, which could become an important issue. Here, we demonstrate that the electrode\\'s metal migrating through the hole transporting material (HTM) layer and eventually contacting the perovskite is in part responsible for this early device degradation. We show that depositing the HTM within an insulating mesoporous "buffer layer" comprised of Al2O3 nanoparticles prevents the metal electrode migration while allowing for precise control of the HTM thickness. This enables an improvement in the solar cell fill factor and prevents degradation of the device after 350 h of operation. (Graph Presented).

  1. Par Pond refill water quality sampling

    International Nuclear Information System (INIS)

    Koch, J.W. II; Martin, F.D.; Westbury, H.M.

    1996-08-01

    This study was designed to document anoxia and its cause in the event that the anoxia caused a fish kill. However, no fish kill was observed during this study, and dissolved oxygen and nutrient concentrations generally remained within the range expected for southeastern reservoirs. Par Pond water quality monitoring will continue during the second summer after refill as the aquatic macrophytes become reestablished and nutrients in the sediments are released to the water column

  2. Engineered design of SSC cooling ponds

    International Nuclear Information System (INIS)

    Bear, J.B.

    1993-05-01

    The cooling requirements of the SSC are significant and adequate cooling water systems to meet these requirements are critical to the project's successful operation. The use of adequately designed cooling ponds will provide reliable cooling for operation while also meeting environmental goals of the project to maintain streamflow and flood peaks to preconstruction levels as well as other streamflow and water quality requirements of the Texas Water Commission and the Environmental Protection Agency

  3. Holocene closure of Lib Pond, Marshall Islands.

    Directory of Open Access Journals (Sweden)

    Conor L Myhrvold

    Full Text Available Well-preserved sediment from closed water bodies of atolls such as Lib Pond are rare opportunities to reconstruct the past regional climate, which pieced together across a latitude and longitude range identify the range of movement patterns of wider scale climate phenomena such as the Intertropical Convergence Zone (ITCZ and El Niño Southern Oscillation (ENSO. We conducted the first physico-chemical survey of Lib Pond, a shallow, closed-water saline lake located on remote and difficult to access Lib Island in the Marshall Islands at 8° 18' 48.99″ N, 167 22' 51.90″ E in the Pacific Ocean, in July 2009. We performed a bathymetric survey, recorded salinity, dissolved oxygen, pH, and temperature profiles, monitored the tidal variability, and conducted a vegetation survey surrounding the lake. From bathymetric data we calculated the lake volume, which we used to estimate the lake's salt budget, and ultimately the residence time of water in the lake basin. We took a series of sediment cores from the lake, cores which indicate Lib Island's changing environment and climate. Radiocarbon measurements determined sediment age, and reveal significant mixing over the last 2 ka of deposition. We conclude that prior to 3 ka, Lib Island was an atoll with a central lagoon connected to the open ocean, which was then closed off from the open ocean to form the brackish system that exists today. We predict that the sediment accumulation in Lib Pond evident today will continue. As seawater is inhibited from exchanging with fresh water, Lib Pond will become a shallower lake with increasingly fresh water.

  4. Holocene closure of Lib Pond, Marshall Islands.

    Science.gov (United States)

    Myhrvold, Conor L; Janny, Fran; Nelson, Daniel; Ladd, S Nemiah; Atwood, Alyssa; Sachs, Julian P

    2014-01-01

    Well-preserved sediment from closed water bodies of atolls such as Lib Pond are rare opportunities to reconstruct the past regional climate, which pieced together across a latitude and longitude range identify the range of movement patterns of wider scale climate phenomena such as the Intertropical Convergence Zone (ITCZ) and El Niño Southern Oscillation (ENSO). We conducted the first physico-chemical survey of Lib Pond, a shallow, closed-water saline lake located on remote and difficult to access Lib Island in the Marshall Islands at 8° 18' 48.99″ N, 167 22' 51.90″ E in the Pacific Ocean, in July 2009. We performed a bathymetric survey, recorded salinity, dissolved oxygen, pH, and temperature profiles, monitored the tidal variability, and conducted a vegetation survey surrounding the lake. From bathymetric data we calculated the lake volume, which we used to estimate the lake's salt budget, and ultimately the residence time of water in the lake basin. We took a series of sediment cores from the lake, cores which indicate Lib Island's changing environment and climate. Radiocarbon measurements determined sediment age, and reveal significant mixing over the last 2 ka of deposition. We conclude that prior to 3 ka, Lib Island was an atoll with a central lagoon connected to the open ocean, which was then closed off from the open ocean to form the brackish system that exists today. We predict that the sediment accumulation in Lib Pond evident today will continue. As seawater is inhibited from exchanging with fresh water, Lib Pond will become a shallower lake with increasingly fresh water.

  5. Changes in tundra pond limnology: re-sampling Alaskan ponds after 40 years.

    Science.gov (United States)

    Lougheed, Vanessa L; Butler, Malcolm G; McEwen, Daniel C; Hobbie, John E

    2011-09-01

    The arctic tundra ponds at the International Biological Program (IBP) site in Barrow, AK, were studied extensively in the 1970s; however, very little aquatic research has been conducted there for over three decades. Due to the rapid climate changes already occurring in northern Alaska, identifying any changes in the ponds' structure and function over the past 30-40 years can help identify any potential climate-related impacts. Current research on the IBP ponds has revealed significant changes in the physical, chemical, and biological characteristics of these ponds over time. These changes include increased water temperatures, increased water column nutrient concentrations, the presence of at least one new chironomid species, and increased macrophyte cover. However, we have also observed significant annual variation in many measured variables and caution that this variation must be taken into account when attempting to make statements about longer-term change. The Barrow IBP tundra ponds represent one of the very few locations in the Arctic where long-term data are available on freshwater ecosystem structure and function. Continued monitoring and protection of these invaluable sites is required to help understand the implications of climate change on freshwater ecosystems in the Arctic.

  6. Beaver ponds increase methylmercury concentrations in Canadian shield streams along vegetation and pond-age gradients.

    Science.gov (United States)

    Roy, Virginie; Amyot, Marc; Carignan, Richard

    2009-08-01

    Beaver impoundments flood forested areas and may be important production sites for methylmercury (MeHg) because of the resulting enhanced microbial activity and oxygen depletion. The influence of 17 beaver impoundments on streamwater chemistry (total mercury (THg), MeHg, nutrients, cations, and anions)] was investigated by sampling sites located along vegetation and pond-age gradients in southwestern Quebec (Canada). Recently inundated beaver ponds (beaver ponds as suggested by depletions of dissolved oxygen, sulfate and nitrite-nitrate concentrations, and increases in nutrients (e.g., dissolved organic carbon, total phosphorus, and total nitrogen) in outlets compared to inlets. Acidic waters at coniferous sites may have stimulated more MeHg production than in mixed woodland regions. Lower methylation efficiencies in older ponds (> 20 years old) may be due to the degradation of less labile organic matter as ponds age. Beavers actively alter watersheds by building impoundments, and our findings indicate that this landscape disturbance may be a significant source of MeHg to downstream water bodies.

  7. Mechanisms for parasites removal in a waste stabilisation pond.

    Science.gov (United States)

    Reinoso, Roberto; Blanco, Saúl; Torres-Villamizar, Linda A; Bécares, Eloy

    2011-04-01

    A waste stabilisation pond (WSP) system formed by two anaerobic ponds, a facultative pond and a maturation pond was studied from December 2003 to September 2004 in north-western Spain in order to evaluate its efficiency in the removal of faecal indicator bacteria (total coliforms, Escherichia coli, faecal streptococci), coliphages, helminth eggs and protozoan (oo)cysts (Cryptosporidium and Giardia). Furthermore, sediment samples were collected from the bottom of the ponds to assess the settling rates and thus determine the main pathogen removal mechanisms in the WSPs system. The overall removal ranged from 1.4 log units for coliphages in the cold period to 5.0 log units for E. coli in the hot period. Cryptosporidium oocysts were reduced by an average of 96%, Giardia cysts by 98% and helminth eggs by 100%. The anaerobic ponds showed significantly higher surface removal rates (4.6, 5.2 and 3.7 log (oo)cysts/eggs removed m(-2) day(-1), respectively) than facultative and maturation ponds. Sunlight and water physicochemical conditions were the main factors influencing C. parvum oocysts removal both in the anaerobic and maturation ponds, whereas other factors like predation or natural mortality were more important in the facultative pond. Sedimentation, the most commonly proposed mechanism for cyst removal had, therefore, a negligible influence in the studied ponds.

  8. Integrated MoSe2 with n+p-Si photocathodes for solar water splitting with high efficiency and stability

    Science.gov (United States)

    Huang, Guanping; Mao, Jie; Fan, Ronglei; Yin, Zhihao; Wu, Xi; Jie, Jiansheng; Kang, Zhenhui; Shen, Mingrong

    2018-01-01

    Many earth-abundant transition metal dichalcogenides (TMDs) have been employed as catalysts for H2 evolution reaction (HER); however, their impactful integration onto photocathodes for photoelectrochemical (PEC) HER is less developed. In this study, we directly sputtered a MoSe2 catalyst onto an n+p-Si photocathode for efficient and stable PEC-HER. An onset potential of 0.4 V vs. RHE, a saturated photocurrent of 29.3 mA/cm2, a fill factor of 0.32, and an energy conversion efficiency of 3.8% were obtained under 100 mA/cm2 Xe lamp illumination. Such superior PEC properties were ascribed to the nearly vertically standing two dimensional MoSe2 rough surface layer and the sharp interface between Si and MoSe2 with small charge transfer resistance. The balance between the reflectivity of the electrode surface and the absorptivity of MoSe2 was also discussed. In addition, the MoSe2 layer can protect the n+p-Si photocathode with a 120 h stability due to its initial growth on Si with high flatness and compactness. This study provides a path to the effective and scalable growth of TMDs onto the Si photocathode aiming for high efficiency and stability.

  9. Rapid surface-water volume estimations in beaver ponds

    Science.gov (United States)

    Karran, Daniel J.; Westbrook, Cherie J.; Wheaton, Joseph M.; Johnston, Carol A.; Bedard-Haughn, Angela

    2017-02-01

    Beaver ponds are surface-water features that are transient through space and time. Such qualities complicate the inclusion of beaver ponds in local and regional water balances, and in hydrological models, as reliable estimates of surface-water storage are difficult to acquire without time- and labour-intensive topographic surveys. A simpler approach to overcome this challenge is needed, given the abundance of the beaver ponds in North America, Eurasia, and southern South America. We investigated whether simple morphometric characteristics derived from readily available aerial imagery or quickly measured field attributes of beaver ponds can be used to approximate surface-water storage among the range of environmental settings in which beaver ponds are found. Studied were a total of 40 beaver ponds from four different sites in North and South America. The simplified volume-area-depth (V-A-h) approach, originally developed for prairie potholes, was tested. With only two measurements of pond depth and corresponding surface area, this method estimated surface-water storage in beaver ponds within 5 % on average. Beaver pond morphometry was characterized by a median basin coefficient of 0.91, and dam length and pond surface area were strongly correlated with beaver pond storage capacity, regardless of geographic setting. These attributes provide a means for coarsely estimating surface-water storage capacity in beaver ponds. Overall, this research demonstrates that reliable estimates of surface-water storage in beaver ponds only requires simple measurements derived from aerial imagery and/or brief visits to the field. Future research efforts should be directed at incorporating these simple methods into both broader beaver-related tools and catchment-scale hydrological models.

  10. Development of shrimp in small ponds

    Directory of Open Access Journals (Sweden)

    Armando Adolfo Ortega Salas

    2014-06-01

    Full Text Available Development of white shrimp Litopenaeus vannamei in small ponds ( 6 m3 in fresh water (2-3‰ and seawater; ponds 3.66 x 1.65 x 1.0 m; availability of fresh water, sea water, aeration and drainage. Two cycles of three months each were made. The postlarvae were acclimated to seawater fresh water in four days. Four hundred postlarvas/m3 were seeded in freshwater pond and 500 in the pool of seawater. First, a culture of Daphnia magna in the freshwater pond, also appeared chyronomid larvae; Artemia cysts were seeded in sea water as a dietary supplement. The shrimp were fed Camaronina (25% protein at libitum, daily; is offered on a tray of food; the temperature ranged between 27 and 30° C, oxygen 4.26 ± 1.43 mg / L , pH between 7 and 8 . Detritus siphoned every third day. Water changes between 10 and 20% are often performed. The feed conversion rate (FCR was 1:1.3 . The shrimp were measured in length and weight to calculate weekly growth by Bertalanffy model. Survival in the first cycle was 95.8 , and 97.9% for the second cycle. In seawater parameters of the population of the first cycle were k = 0.0301, L ∞ = 322.16 and t0 = -0.8852, the second cycle of k = 0.0203, L ∞ = 294.42 and t0 = -5.3771. The biomass of 27 kg was obtained for the first cycle and 16 kg for the second cycle. Freshwater population parameters of the first cycle were k = 0.0957, L ∞ = 146.98 and t0 = - 0.93; in the second cycle of k = 0.0172 , L ∞ = 367.82 and t0 = - 4.60. The biomass of 26 kg was obtained for the first cycle and 16 kg for the second cycle. The results indicate a rapid growth during the first 10 weeks. In small ponds can be handled well aseptic conditions without disease problems, good crop was obtained.

  11. Remediation of the low-level radioactive waste tailing pond at Kowary, Poland

    International Nuclear Information System (INIS)

    Goerner, R.; Hartsch, J.; Koszela, J.; Krzyskow, A.; Machniewicz, B.; Sennewald, R.; Sowa, J.

    2002-03-01

    The last remaining uranium mining tailing pond in Poland, situated at Kowary, was the subject of the Kowary Tailing Pond Remediation Programme financed by Polish public bodies (70%) and by the European Commission (30%) within the framework of its programme of co-operation on radioactive waste issues with candidate countries. The EC-part of the project comprised investigations of the site, project management duties and large-scale civil works following the initial remediation planning performed by the Wroclaw University of Technology (WUT) in 1998-2000. The EC-part was contracted to G.E.O.S. Freiberg Ingenieurgesellschaft mbH following an Open Call for Tender launched by the European Commission in 1999. The following general tasks were performed in close co-operation with WUT, with the construction works subcontracted to local companies, as proposed in the Terms of Reference (TOR) of the EC-part: review of General Remediation Plan (GRP), technical design of the pond cover, construction work: internal drainage system, pond cover and site reclamation. From the information in the TOR, the following aims of remediation were defined: minimise the detrimental impact of the tailing pond on the environment, provide long-term stability of the slopes surrounding the pond, ensure the remediated site is in harmony with the surrounding natural scenery. Based on the experience gathered in similar projects, which had been running under PHARE-MCE or which belonged to the WISMUT-remediation programme in Germany, cost efficient remediation solutions were designed in close co-operation with all involved parties. They were delineated in the detailed planning documents approved in the overall remediation programme managed by WUT. The planned remediation works were prepared and performed successfully according to Polish law and in agreement with the competent local authorities. The aims of remediation were met. However, some additional tasks have been recommended in zones adjacent to the

  12. Site-specific health and safety plan 100-D Pond remediation project

    International Nuclear Information System (INIS)

    Hobbs, B.J.

    1996-06-01

    The 100-D Ponds are located north of the northern perimeter fence of the 100-D Area. The ponds were excavated in a preexisting basin that had been used for disposal of coal ash. There are two ponds, one used as a settling pond and the other a percolation pond. Liquid effluent from the 100-D process sewers was discharged to the ponds from 1977 through 1987; after 1987 the ponds received backwash and rinsate from the 100-D water treatment facilities. All discharges to the ponds ceased in June 1994, and the ponds were allowed to dry up

  13. Geochemistry of the Upper Parana River floodplain. Study of the Garcas Pond and Patos Pond

    International Nuclear Information System (INIS)

    Marcelo Bevilacqua Remor; Silvio Cesar Sampaio; Marcio Antonio Vilas Boas; Ralpho Rinaldo dos Reis

    2015-01-01

    The aim of this study was to investigate the temporal evolution of the supply of chemical elements to the Upper Parana River floodplain and identify trends in the geochemistry of its drainage basin. The primary factor that regulates the supply of chemical elements of the Upper Parana River floodplain is the flood pulse, which can be magnified by the El Nino-Southern Oscillation. Garcas Pond is affected by agriculture, urbanization, discharge of industrial effluents and hydroelectric power production activities. Patos Pond is affected by sugarcane burning, gold mining, agriculture and urbanization. (author)

  14. The western pond turtle: Habitat and history. Final report

    International Nuclear Information System (INIS)

    Holland, D.C.

    1994-08-01

    The western pond turtle is known from many areas of Oregon. The majority of sightings and other records occur in the major drainages of the Klamath, Rogue, Umpqua, Willamette and Columbia River systems. A brief overview is presented of the evolution of the Willamette-Puget Sound hydrographic basin. A synopsis is also presented of the natural history of the western pond turtle, as well as, the status of this turtle in the Willamette drainage basin. The reproductive ecology and molecular genetics of the western pond turtle are discussed. Aquatic movements and overwintering of the western pond turtle are evaluated. The effect of introduced turtle species on the status of the western pond turtle was investigated in a central California Pond. Experiments were performed to determine if this turtle could be translocated as a mitigation strategy

  15. Bioaccumulation of heavy metals in two wet retention ponds

    DEFF Research Database (Denmark)

    Søberg, Laila C.; Vollertsen, Jes; Blecken, Godecke-Tobias

    2016-01-01

    Metal accumulation in stormwater ponds may contaminate the inhabiting fauna, thus jeopardizing their ecosystem servicing function. We evaluated bioaccumulation of metals in natural fauna and caged mussel indicator organisms in two wet retention ponds. Mussel cages were distributed throughout...... the ponds to detect bioaccumulation gradients and obtain a time-integrated measure of metal bioavailability. We further investigated if sediment metal concentrations correlate with those in the fauna and mussels. Metal concentrations in the fauna tended to be higher in the ponds than in a reference lake......, but statistical significance was only shown for Cu. Positive correlations were found for some metals in fauna and sediment. Sediment metal concentrations in one pond decreased from inlet to outlet while no gradients were observed in the mussels in either pond. These findings indicate that metal accumulation...

  16. Relationship Between Accumulation and Influx of Pollutants in Highway Ponds

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby; Larsen, Torben; Rasmussen, Michael R.

    The paper discusses the long term mass balance of pollutants in highway ponds. The accumulations of five polycyclic aromatic hydrocarbons (PAHs) and six heavy metals have been measured in eight Danish detention ponds, which receive runoff from highways only. For each pollutant the accumulation has...... been compared to the long-term influx, estimated from short-term measurements of concentrations in highway runoff. The results show that a large proportion of the incoming heavy metals in short-term runoff events has accumulated in the ponds. This is not the case for the toxic organic compounds....... The results also show that the accumulation rates for the heavy metals depend significantly on the relative pond area (pond area divided by catchment area). The conclusion is that the mass balances of heavy metals and PAHs in highway ponds can be estimated with acceptable accuracy from a combination of short...

  17. Samples of Asteroid Surface Ponded Deposits in Chondritic Meteorites

    Science.gov (United States)

    Zolensky, M. E.; Lee, R.; Le, L.

    2004-01-01

    One of the many unexpected observations of asteroid 433 Eros by the Near Earth Asteroid Rendezvous (NEAR) mission was the many ponds of fine-grained materials [1-3]. The ponds have smooth surfaces, and define equipotential surfaces up to 10's of meters in diameter [4]. The ponds have a uniformly sub-cm grain size and appear to be cohesive or indurated to some degree, as revealed by slumping. The ponds appear to be concentrated within 30 degrees of the equator of Eros, where gravity is lowest. There is some insight into the mineralogy and composition of the ponds surfaces from NEAR spectroscopy [2,4,5,6]. Compared to the bulk asteroid, ponds: (1) are distinctly bluer (high 550/760 nm ratio), (2) have a deeper 1um mafic band, (3) have reflectance elevated by 5%.

  18. Simple intervention to reduce mosquito breeding in waste stabilisation ponds

    DEFF Research Database (Denmark)

    Ensink, Jeroen H J; Mukhtar, Muhammad; van der Hoek, Wim

    2007-01-01

    Waste stabilisation ponds (WSP) are the preferred method for treatment of urban wastewater in low-income countries but, especially in arid regions, the pond systems can be important breeding sites for mosquitoes of medical importance. In a WSP system in Faisalabad, Pakistan, we assessed the impact...... of simple environmental interventions on mosquito occurrence and abundance. Reducing the amount of floating matter in the ponds, eliminating emergent vegetation and repairing cracks in the cement structure reduced the number of mosquito-positive samples in the intervention ponds to almost zero, whereas...... the control ponds had a significant number of positive samples. This suggests that a combination of simple low-cost interventions is a feasible environmental management strategy for vector control in WSP systems that are located in areas where medically important mosquitoes may breed in the shallow ponds....

  19. Relations between Structure, Activity and Stability in C3N4 Based Photocatalysts Used for Solar Hydrogen Production

    Directory of Open Access Journals (Sweden)

    Ramesh P. Sivasankaran

    2018-01-01

    Full Text Available Solar hydrogen production from water could be a sustainable and environmentally friendly alternative to fossil energy carriers, yet so far photocatalysts active and stable enough for large-scale applications are not available, calling for advanced research efforts. In this work, H2 evolution rates of up to 1968 and 5188 μmol h−1 g−1 were obtained from aqueous solutions of triethanolamine (TEOA and oxalic acid (OA, respectively, by irradiating composites of AgIn5S8 (AIS, mesoporous C3N4 (CN, surface area >150 m2/g and ≤2 wt.% in-situ photodeposited Pt nanoparticles (NPs with UV-vis (≥300 nm and pure visible light (≥420 nm. Structural properties and electron transport in these materials were analyzed by XRD, STEM-HAADF, XPS, UV-vis-DRS, ATR-IR, photoluminescence and in situ-EPR spectroscopy. Initial H2 formation rates were highest for Pt/CN, yet with TEOA this catalyst deactivated by inclusion of Pt NPs in the matrix of CN (most pronounced at λ ≥ 300 nm while it remained active with OA, since in this case Pt NPs were enriched on the outermost surface of CN. In Pt/AIS-CN catalysts, Pt NPs were preferentially deposited on the surface of the AIS phase which prevents them from inclusion in the CN phase but reduces simultaneously the initial H2 evolution rate. This suggests that AIS hinders transport of separated electrons from the CN conduction band to Pt NPs but retains the latter accessible by protons to produce H2.

  20. Effect of hole-transporting materials on the photovoltaic performance and stability of all-ambient-processed perovskite solar cells

    Institute of Scientific and Technical Information of China (English)

    Nanaji Islavath; S Saroja; K Srinivas Reddy; P C Harikesh; G Veerappan; Shrikant V Joshi; Easwaramoorthi Ramasamy

    2017-01-01

    High-efficiency perovskite solar cells (PSCs) reported hitherto have been mostly prepared in a moisture and oxygen-free glove-box atmosphere,which hampers upscaling and real-time performance assessment of this exciting photovoltaic technology.In this work,we have systematically studied the feasibility of allambient-processing of PSCs and evaluated their photovoltaic performance.It has been shown that phasepure crystalline tetragonal MAPbI3 perovskite films are instantly formed in ambient air at room temperature by a two-step spin coating process,undermining the need for dry atmosphere and post-annealing.All-ambient-processed PSCs with a configuration of FTO/TiO2/MAPbI3/Spiro-OMeTAD/Au achieve opencircuit voltage (990 mV) and short-circuit current density (20.31 mA/cm2) comparable to those of best reported glove-box processed devices.Nevertheless,device power conversion efficiency is still constrained at 5% by the unusually low fill-factor of 0.25.Dark current-voltage characteristics reveal poor conductivity of hole-transporting layer caused by lack of oxidized spiro-OMeTAD species,resulting in high seriesresistance and decreased fill-factor,The study also establishes that the above limitations can be readily overcome by employing an inorganic p-type semiconductor,copper thiocyanate,as ambient-processable hole-transporting layer to yield a fill-factor of 0.54 and a power conversion efficiency of 7.19%.The present findings can have important implications in industrially viable fabrication of large-area PSCs.

  1. Ni-doped α-Fe 2 O 3 as electron transporting material for planar heterojunction perovskite solar cells with improved efficiency, reduced hysteresis and ultraviolet stability

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Ying; Liu, Tao; Wang, Ning; Luo, Qiang; Lin, Hong; Li, Jianbao; Jiang, Qinglong; Wu, Lili; Guo, Zhanhu

    2017-08-01

    We report on high-efficiency planar heterojunction perovskite solar cells (PSCs) employing Ni-doped alpha-Fe2O3 as electron-transporting layer (ETL). The suitable addition of nickel (Ni) dopant could enhance the electron conductivity as well as induce downward shift of the conduction band minimum for alpha-Fe2O3, which facilitate electrons injection and transfer from the conduction band of the perovskite. As a consequence, a substantial reduction in the charge accumulation at the perovskite/ETL interface makes the device much less sensitive to scanning rate and direction, i.e., lower hysteresis. With a reverse scan for the optimized PSC under standard AM-1.5 sunlight illumination, it generates a competitive power conversion efficiency (PCE) of 14.2% with a large short circuit current (J(sc)) of 22.35 mA/cm(2), an open circuit photovoltage (V-oc) of 0.92 V and a fill factor (FF) of 69.1%. Due to the small J-V hysteresis behavior, a higher stabilized PCE up to 11.6% near the maximum power point can be reached for the device fabricated with 4 mol% Ni-doped alpha-Fe2O3 ETL compared with the undoped alpha-Fe2O3 based cell (9.2%). Furthermore, a good stability of devices with exposure to ambient air and high levels of ultraviolet (UV)-light can be achieved. Overall, our results demonstrate that the simple solution-processed Ni-doped alpha-Fe2O3 can be a good candidate of the n-type collection layer for commercialization of PSCs.

  2. Surface Grafting of Ru(II) Diazonium-Based Sensitizers on Metal Oxides Enhances Alkaline Stability for Solar Energy Conversion.

    Science.gov (United States)

    Bangle, Rachel; Sampaio, Renato N; Troian-Gautier, Ludovic; Meyer, Gerald J

    2018-01-24

    The electrografting of [Ru(ttt)(tpy-C 6 H 4 -N 2 + )] 3+ , where "ttt" is 4,4',4″-tri-tert-butyl-2,2':6',2″-terpyridine, was investigated on several wide band gap metal oxide surfaces (TiO 2 , SnO 2 , ZrO 2 , ZnO, In 2 O 3 :Sn) and compared to structurally analogous sensitizers that differed only by the anchoring group, i.e., -PO 3 H 2 and -COOH. An optimized procedure for diazonium electrografting to semiconductor metal oxides is presented that allowed surface coverages that ranged between 4.7 × 10 -8 and 10.6 × 10 -8 mol cm -2 depending on the nature of the metal oxide. FTIR analysis showed the disappearance of the diazonium stretch at 2266 cm -1 after electrografting. XPS analysis revealed a characteristic peak of Ru 3d at 285 eV as well as a peak at 531.6 eV that was attributed to O 1s in Ti-O-C bonds. Photocurrents were measured to assess electron injection efficiency of these modified surfaces. The electrografted sensitizers exhibited excellent stability across a range of pHs spanning from 1 to 14, where classical binding groups such as carboxylic and phosphonic derivatives were hydrolyzed.

  3. Transition in the fractal geometry of Arctic melt ponds

    Directory of Open Access Journals (Sweden)

    C. Hohenegger

    2012-10-01

    Full Text Available During the Arctic melt season, the sea ice surface undergoes a remarkable transformation from vast expanses of snow covered ice to complex mosaics of ice and melt ponds. Sea ice albedo, a key parameter in climate modeling, is determined by the complex evolution of melt pond configurations. In fact, ice–albedo feedback has played a major role in the recent declines of the summer Arctic sea ice pack. However, understanding melt pond evolution remains a significant challenge to improving climate projections. By analyzing area–perimeter data from hundreds of thousands of melt ponds, we find here an unexpected separation of scales, where pond fractal dimension D transitions from 1 to 2 around a critical length scale of 100 m2 in area. Pond complexity increases rapidly through the transition as smaller ponds coalesce to form large connected regions, and reaches a maximum for ponds larger than 1000 m2, whose boundaries resemble space-filling curves, with D ≈ 2. These universal features of Arctic melt pond evolution are similar to phase transitions in statistical physics. The results impact sea ice albedo, the transmitted radiation fields under melting sea ice, the heat balance of sea ice and the upper ocean, and biological productivity such as under ice phytoplankton blooms.

  4. Avifauna of waste ponds ERDA Hanford Reservation, Benton County, Washington

    International Nuclear Information System (INIS)

    Fitzner, R.E.; Rickard, W.H.

    1975-06-01

    The presence of small ponds on the Hanford 200 Area plateau provides attractive habitats for birds. During a 29-month period, 126 bird species were observed utilizing these ponds, their associated vegetation, and air space. Waterfowls are the important agents of dispersal of radionuclides from waste ponds based on food habits, abundance, migratory habits, and importance as food in the diet of people. Abundance, long residence time, and food habits identify the American coot as the single most important species to be considered in the biological dispersal of radionuclides from waste ponds. (U.S.)

  5. Full-energy-chain analysis of greenhouse gas emissions for solar thermal electric power generation systems

    International Nuclear Information System (INIS)

    Norton, B.; Lawson, W.R.

    1997-01-01

    Technical attributes and environmental impacts of solar thermal options for centralized electricity generation are discussed. In particular, the full-energy-chain, including embodied energy and energy production, is considered in relation to greenhouse gas emission arising from solar thermal electricity generation. Central receiver, parabolic dish, parabolic trough and solar pond systems are considered. (author)

  6. Improving the efficiency and environmental stability of inverted planar perovskite solar cells via silver-doped nickel oxide hole-transporting layer

    Science.gov (United States)

    Wei, Ying; Yao, Kai; Wang, Xiaofeng; Jiang, Yihua; Liu, Xueyuan; Zhou, Naigen; Li, Fan

    2018-01-01

    In this paper, we demonstrate the high-performance inverted planar heterojunction perovskite solar cells (PeSCs) based on the novel inorganic hole-transporting layer (HTL) of silver (Ag)-doped NiOx (Ag:NiOx). Density-functional theory (DFT) calculation reveals that Ag prefers to occupy the substitutional Ni site (AgNi) and behaves as an acceptor in NiO lattice. Compared with the pristine NiOx films, appropriate Ag doping can increase the optical transparency, work function, electrical conductivity and hole mobility of NiOx films. Moreover, the CH3NH3PbI3 perovskite films grown on Ag:NiOx exhibit better crystallinity, higher coverage and smoother surface with densely packed larger grains than those grown on the pristine NiOx film. Consequently, the Ag:NiOx HTL boosts the efficiency of the inverted planar heterojunction PeSCs from 13.46% (for the pristine NiOx-based device) to 16.86% (for the 2 at.% Ag:NiOx-based device). Furthermore, the environmental stability of PeSCs based on Ag:NiOx HTL is dramatically improved compared to devices based on organic HTLs and pristine NiOx HTLs. This work provides a simple and effective HTL material system for high-efficient and stable PeSCs.

  7. Incorporating C60 as Nucleation Sites Optimizing PbI2 Films To Achieve Perovskite Solar Cells Showing Excellent Efficiency and Stability via Vapor-Assisted Deposition Method.

    Science.gov (United States)

    Chen, Hai-Bin; Ding, Xi-Hong; Pan, Xu; Hayat, Tasawar; Alsaedi, Ahmed; Ding, Yong; Dai, Song-Yuan

    2018-01-24

    To achieve high-quality perovskite solar cells (PSCs), the morphology and carrier transportation of perovskite films need to be optimized. Herein, C 60 is employed as nucleation sites in PbI 2 precursor solution to optimize the morphology of perovskite films via vapor-assisted deposition process. Accompanying the homogeneous nucleation of PbI 2 , the incorporation of C 60 as heterogeneous nucleation sites can lower the nucleation free energy of PbI 2 , which facilitates the diffusion and reaction between PbI 2 and organic source. Meanwhile, C 60 could enhance carrier transportation and reduce charge recombination in the perovskite layer due to its high electron mobility and conductivity. In addition, the grain sizes of perovskite get larger with C 60 optimizing, which can reduce the grain boundaries and voids in perovskite and prevent the corrosion because of moisture. As a result, we obtain PSCs with a power conversion efficiency (PCE) of 18.33% and excellent stability. The PCEs of unsealed devices drop less than 10% in a dehumidification cabinet after 100 days and remain at 75% of the initial PCE during exposure to ambient air (humidity > 60% RH, temperature > 30 °C) for 30 days.

  8. Co-sensitization of ZnO by CdS quantum dots in natural dye-sensitized solar cells with polymeric electrolytes to improve the cell stability

    Energy Technology Data Exchange (ETDEWEB)

    Junhom, W.; Magaraphan, R. [Polymer Processing and Polymer Nanomaterials Research Unit, Petroleum and Petrochemical College, Chulalongkorn University, Bangkok (Thailand)

    2015-05-22

    The CdS quantum dots (QDs) were deposited on ZnO layer by chemical bath deposition method to absorb light in the shorter wavelength region and used as photoanode in the dye sensitized solar cell (DSSCs) with natural dye extracted from Noni leaves. Microstructures of CdS-ZnO from various dipping time were characterized by XRD, FE-SEM and EDX. The results showed that the CdS is hexagonal structure and the amount of CdS increases when the dipping time increases. The maximal conversion efficiency of 0.292% was achieved by the DSSCs based on CdS QDs-sensitized ZnO film obtained from 9 min-dipping time. Furthermore, the stability of DSSCs was improved by using polymeric electrolyte. Poly (acrylic acid) (PAA) and Polyacrylamide (PAM) were introduced to CdS QDs-sensitized ZnO film from 9 min-dipping time. Each polymeric electrolyte was prepared by swelling from 0.1-2.0 %w in H2O. The maximal conversion efficiency of 0.207% was achieved for DSSCs based on CdS QDs-sensitized ZnO film with PAM 1.0% and the conversion efficiency was decreased 25% when it was left for1 hr.

  9. Synthesis of hierarchical ZnV2O6 nanosheets with enhanced activity and stability for visible light driven CO2 reduction to solar fuels

    Science.gov (United States)

    Bafaqeer, Abdullah; Tahir, Muhammad; Amin, Nor Aishah Saidina

    2018-03-01

    Hierarchical nanostructures have lately garnered enormous attention because of their remarkable performances in energy storage and catalysis applications. In this study, novel hierarchical ZnV2O6 nanosheets, formulated by one-step solvothermal method, for enhanced photocatalytic CO2 reduction with H2O to solar fuels has been investigated. The structure and properties of the catalysts were characterized by XRD, FESEM, TEM, BET, UV-vis, Raman and PL spectroscopy. The hierarchical ZnV2O6 nanosheets show excellent performance towards photoreduction of CO2 with H2O to CH3OH, CH3COOH and HCOOH under visible light. The main product yield, CH3OH of 3253.84 μmol g-cat-1 was obtained over ZnV2O6, 3.4 times the amount of CH3OH produced over the ZnO/V2O5 composite (945.28 μmol g-cat-1). In addition, CH3OH selectivity of 39.96% achieved over ZnO/V2O5, increased to 48.78% in ZnV2O6 nanosheets. This significant improvement in photo-activity over ZnV2O6 structure was due to hierarchical structure with enhanced charge separation by V2O5. The obtained ZnV2O6 hierarchical nanosheets exhibited excellent photocatalytic stability for selective CH3OH production.

  10. Enhanced efficiency and air-stability of NiOX-based perovskite solar cells via PCBM electron transport layer modification with Triton X-100.

    Science.gov (United States)

    Lee, Kisu; Ryu, Jaehoon; Yu, Haejun; Yun, Juyoung; Lee, Jungsup; Jang, Jyongsik

    2017-11-02

    We modified phenyl-C61-butyric acid methyl ester (PCBM) for use as a stable, efficient electron transport layer (ETL) in inverted perovskite solar cells (PSCs). PCBM containing a surfactant Triton X-100 acts as the ETL and NiO X nanocrystals act as a hole transport layer (HTL). Atomic force microscopy and scanning electron microscopy images showed that surfactant-modified PCBM (s-PCBM) forms a high-quality, uniform, and dense ETL on the rough perovskite layer. This layer effectively blocks holes and reduces interfacial recombination. Steady-state photoluminescence and electrochemical impedance spectroscopy analyses confirmed that Triton X-100 improved the electron extraction performance of PCBM. When the s-PCBM ETL was used, the average power conversion efficiency increased from 10.76% to 15.68%. This improvement was primarily caused by the increases in the open-circuit voltage and fill factor. s-PCBM-based PSCs also showed good air-stability, retaining 83.8% of their initial performance after 800 h under ambient conditions.

  11. International experience in tailings pond remediation

    International Nuclear Information System (INIS)

    Robertson, A.MacG.

    2001-01-01

    Tailings pond remediation is required primarily on mine closure. While mining is an ancient industry, requirement for mine facility remediation is a comparatively new development. Requirement for remediation has come about partly as a result of mans awareness of the environmental impacts of mining and his desire to minimize this, partly, as a result of the ever-increasing scale and production rates of tailings generation and the resulting increased environmental impacts and safety risks. The paper starts with a review of the evolution of mans intolerance of environmental impacts from tailings production and the assignment of liability to remediate such impacts. Many of the tailings ponds currently undergoing remediation were designed and constructed using methods and technology that would be considered inappropriate for new impoundments being designed and developed today. The paper reviews the history of tailings impoundment design and construction practice and the resulting inherent deficiencies that must be remediated. Current practices and future trends in tailings pond remediation are reviewed. The evolution of regulatory requirements is not only in terms of technical and safety criteria, but also in terms of financial and political risk. Perhaps the most substantive driver of risk management is today the requirement for corporate governance at mining company board level and oversight of new project development in the underdeveloped countries by the large financial institutions responsible for funding projects. Embarrassment in the public eye and punishment in the stock markets for poor environmental and safety performance is driving the need for efficient and effective risk management of potential impacts and the remediation to avoid these. A basis for practical risk management is described. (orig.)

  12. International experience in tailings pond remediation

    Energy Technology Data Exchange (ETDEWEB)

    MacG. Robertson, A. [Robertson GeoConsultants Ltd., Vancouver (Canada)

    2001-07-01

    Tailings pond remediation is required primarily on mine closure. While mining is an ancient industry, requirement for mine facility remediation is a comparatively new development. Requirement for remediation has come about partly as a result of mans awareness of the environmental impacts of mining and his desire to minimize this, partly, as a result of the ever-increasing scale and production rates of tailings generation and the resulting increased environmental impacts and safety risks. The paper starts with a review of the evolution of mans intolerance of environmental impacts from tailings production and the assignment of liability to remediate such impacts. Many of the tailings ponds currently undergoing remediation were designed and constructed using methods and technology that would be considered inappropriate for new impoundments being designed and developed today. The paper reviews the history of tailings impoundment design and construction practice and the resulting inherent deficiencies that must be remediated. Current practices and future trends in tailings pond remediation are reviewed. The evolution of regulatory requirements is not only in terms of technical and safety criteria, but also in terms of financial and political risk. Perhaps the most substantive driver of risk management is today the requirement for corporate governance at mining company board level and oversight of new project development in the underdeveloped countries by the large financial institutions responsible for funding projects. Embarrassment in the public eye and punishment in the stock markets for poor environmental and safety performance is driving the need for efficient and effective risk management of potential impacts and the remediation to avoid these. A basis for practical risk management is described. (orig.)

  13. Comparison of phytoplankton communities in catfish split-pond aquaculture systems with conventional ponds

    Science.gov (United States)

    There has been a growing interest and use of variations of partitioned aquaculture systems (PAS) in recent years by the southeastern United States of America farmed catfish industry. Split-pond systems, one type of PAS, are designed to better manage fish waste byproducts (e.g., ammonia) and dissolv...

  14. Thermal performance experiments on ultimate heat sinks, spray ponds, and cooling ponds

    International Nuclear Information System (INIS)

    Hadlock, R.K.

    1976-12-01

    A program of measurement on a Battelle-Northwest (BNW) spray pond has been completed to prove an integrated instrumentation system for application in future field experiments. The measurement programs in the field will produce data of relevance to the design and understanding of performance for ultimate heat sinks as components of emergency core cooling systems. In the absence of active emergency cooling systems, the data will be obtained on analog systems--prime candidates among these are the naturally-occurring hot ponds at Yellowstone National Park and man-made hot cooling ponds at Savannah River National Laboratory as well as spray ponds at various industrial facilities. The proof experiment has provided data that not only illustrate the effectiveness of the instrumentation system but also display interesting site-specific heat transfer processes. The data to be obtained in the field will also be site specific but must be of generic applicability in modeling for design and performance purposes. The integrated instrumentation system will evolve, through modest modifications and substantial supplementation, to provide the requisite data for the more demanding situation of work in and about hot water

  15. Phyllosphere mycobiota on garden ponds plants

    Directory of Open Access Journals (Sweden)

    Maria Kowalik

    2013-12-01

    Full Text Available Investigations were conducted on calamus, common cattail, soft rush, yellow iris and white water lily plants in twenty ponds in Malopolska and Podkarpacie Regions. Mycobiota existing in the phyllosphere caused discolouring and necroses of leaves and shoots. 88 species of mycobiota were identified and isolated from the diseased tissues. Dominant were Alternaria alternata, Epicoccum nigrum and Isaria farinosa. Fungi of genera: Aspergillus, Botrytis, Chaetomium, Cladosporium, Fusarium, Ilyonectria, Mortierella, Mucor, Penicillium, Phialophora, Phoma, Pleustomophora, Sordaria, Trichoderma and Umbelopsis were also numerous. The monophagous and the polyphagous were identified.

  16. Comparison between field data and ultimate heat-sink cooling-pond and spray-pond models

    International Nuclear Information System (INIS)

    Codell, R.

    1982-09-01

    Two previously published reports, NUREG-0693 and NUREG-0733, presented models and methods by which ultimate heat sink cooling ponds and spray ponds used for safety-related water supplies in nuclear power plants could be analyzed for design-basis conditions of heat load and meteorology. These models were only partially verified with field data. The present report compares the NRC models to data collected for NRC by Battelle Pacific Northwest Laboratories on the performance of small geothermally heated ponds and spray ponds. These comparisons generally support the conclusion that the NRC models are useful tools in predicting ultimate heat sink performance

  17. 216-T-4 interim stabilization final report

    International Nuclear Information System (INIS)

    Smith, D.L.

    1996-01-01

    This report provides a general description of the activities performed for the interim stabilization of the 216-T-4-1 ditch, 216-T-4-2 ditch, and 216-T-4-2 pond. Interim stabilization was required to reduce the amount of surface-contaminated acres and to minimize the migration of radioactive contamination. Work associated with the 216-T4-1 ditch and 216-T-4-2 pond was performed by the Radiation Area Remedial Action (RARA) Project. Work associated with the 216-T-4-2 ditch was done concurrently but was funded by Westinghouse Hanford Company (WHC) Tank Waste Remediation Systems (TWRS)

  18. Solar Still Coupled With Solar Collector and Storage Tank

    OpenAIRE

    Rajesh, A. M.; Bharath, K. N.

    2010-01-01

    Acute shortage of good, clean drinking water is a major problem for most developing countries of the world. In most cases, ponds, streams, wells and rivers are often polluted that they are unsafe for direct use as drinking water >.Often water sources are brackish and or contain harmful bacteria. Therefore cannot be used for drinking .In addition there are many coastal locations where sea water is abundant but potable water is not available. Solar distillation is one of the important methods o...

  19. PERFORMANCES OF TIGER SHRIMP CULTURE IN ENVIRONMENTALLY FRIENDLY PONDS

    Directory of Open Access Journals (Sweden)

    Taufik Ahmad

    2016-10-01

    Full Text Available Mangrove ecosystem plays an obvious role in maintaining the biological balance in the coastal environment where shrimp ponds are usually constructed. The removal of mangroves around shrimp ponds has frequently brought about harvest failure. The study evaluated the performance of tiger shrimp culture in ponds provided with water from a water body where there was mangrove vegetation (hereafter mangrove reservoir. Twelve ponds, each measuring 2,500 m2, were filled with seawater from the mangrove reservoir until the water depth of 100 cm and then stocked with 20-40 PL/m2. In the first six ponds, the bottom water was released into the reservoir when the water depth reached 140 cm and then the water depth was maintained at 100 cm. In the second six ponds, the water was released from the ponds until the water depth reached 60 cm and then refilled with reservoir water until a depth of 100 cm. Both treatment ponds received water from the reservoir which also received the wastewater. The feeds for the shrimps were broadcast into the ponds twice a day to meet the 3% shrimp biomass requirement, which adjusted every other week through sampling. The result showed that mangrove  vegetation is capable of removing excessive nutrients, up to 70% for NO3- N and NH4 +-N, reducing PO4 =-P fluctuation, and producing bioactive  compounds. In the second treatment ponds, shrimp mortality started to occur in day 28 and most died by day 54 after stocking due to white spot disease outbreak. Mass mortality took place 54 days after stocking in two out of six of the first treatment ponds.

  20. First description of underwater acoustic diversity in three temperate ponds

    Directory of Open Access Journals (Sweden)

    Camille Desjonquères

    2015-11-01

    Full Text Available The past decade has produced an increased ecological interest in sonic environments, or soundscapes. However, despite this rise in interest and technological improvements that allow for long-term acoustic surveys in various environments, some habitats’ soundscapes remain to be explored. Ponds, and more generally freshwater habitats, are one of these acoustically unexplored environments. Here we undertook the first long term acoustic monitoring of three temperate ponds in France. By aural and visual inspection of a selection of recordings, we identified 48 different sound types, and according to the rarefaction curves we calculated, more sound types are likely present in one of the three ponds. The richness of sound types varied significantly across ponds. Surprisingly, there was no pond-to-pond daily consistency of sound type richness variation; each pond had its own daily patterns of activity. We also explored the possibility of using six acoustic diversity indices to conduct rapid biodiversity assessments in temperate ponds. We found that all indices were sensitive to the background noise as estimated through correlations with the signal-to-noise ratio (SNR. However, we determined that the AR index could be a good candidate to measure acoustic diversities using partial correlations with the SNR as a control variable. Yet, research is still required to automatically compute the SNR in order to apply this index on a large data set of recordings. The results showed that these three temperate ponds host a high level of acoustic diversity in which the soundscapes were variable not only between but also within the ponds. The sources producing this diversity of sounds and the drivers of difference in daily song type richness variation both require further investigation. Such research would yield insights into the biodiversity and ecology of temperate ponds.

  1. Examining Water Quality Variations of Tidal Pond System

    Science.gov (United States)

    Chui, T. F. M.; Cui, W.

    2014-12-01

    Brackish tidal shrimp ponds, traditionally referred to as gei wais, have been constructed along coastal areas in many parts of the world. The regular exchange of pond water with the surrounding coastal environment is important as it brings shrimp larvae and nutrients, etc. into and out of the pond. Such a water exchange can reduce the quality of the receiving waters; though there are opposing views recently because farming practices are becoming more sustainable while other sources of pollutions in the surroundings are increasing. This project monitors the water quality of a tidal shrimp pond and its receiving water at high temporal resolution. The pond is located within the wetland complex of Mai Po Nature Reserve in Hong Kong, China. Water quality parameters (i.e., dissolved oxygen, temperature, salinity, pH, water depth and chlorophyll) were recorded at 15-minute interval from December 2013 to March 2014 within the pond and also at its receiving water which is a water channel within a mangrove forest. Data reveals both daily and fortnightly fluctuations. Daily variations in mangrove correspond to both tidal flushing and insolation, whereas those within the pond correspond mainly to insolation. For example, dissolved oxygen in mangrove shows two peaks daily which correlate with tidal elevation, and that within the pond shows only one peak which correlates with sunlight. Dissolved oxygen within the pond also shows a fortnightly pattern that corresponds to the schedule of water exchange. Such high temporal resolution of monitoring reveals the two-way water quality influences between the pond and the mangrove. It sheds insights that can possibly lead to refinement of water exchange practice and water sampling schedule given the temporal variations of the water quality both inside and outside the pond. It thus enables us to take a step closer in adopting more sustainable farming practices despite increasing pollution in the surrounding areas.

  2. Capturing temporal and spatial variability in the chemistry of shallow permafrost ponds

    Science.gov (United States)

    Morison, Matthew Q.; Macrae, Merrin L.; Petrone, Richard M.; Fishback, LeeAnn

    2017-12-01

    Across the circumpolar north, the fate of small freshwater ponds and lakes (mediated by processes within ponds. This work demonstrates the importance of understanding hydrologically driven chemodynamics in permafrost ponds on multiple scales (seasonal and event scale).

  3. Cu/sub x/S-CdS thin film solar cells - aftertreatment and stability. Cu/sub x/S-CdS Duennschicht-Solarzellen - Untersuchungen ueber die Nachbehandlung und die Stabilitaet

    Energy Technology Data Exchange (ETDEWEB)

    Pfisterer, F

    1987-02-19

    The performance of Cu/sub x/S-CdS thin film solar cells can be improved significantly by a secondary treatment of the Cu layer. The physical mechanisms underlying the aftertreatment process were investigated both experimentally and theoretically. A historical review is followed by an outline of the technology and theory of these solar cells (material properties, process engineering, photovoltaic properties) and a description of Cu aftertreatment and H glowing (experimental set-up, surface potential shift, electron beam scanning). Capacity measurements in this type of thin film cell are described (space charge profile, electrolytic decomposition, copper depletion between the contact web). Aftertreatment of the copper layer enhances the solar cell efficiency, stability, and productivity, makes the immersion process less tedious, and corrects the stoichiometry. (HWJ).

  4. The critical role of islands for waterbird breeding and foraging habitat in managed ponds of the South Bay Salt Pond Restoration Project, South San Francisco Bay, California

    Science.gov (United States)

    Ackerman, Joshua T.; Hartman, C. Alex; Herzog, Mark P.; Smith, Lacy M.; Moskal, Stacy M.; De La Cruz, Susan E. W.; Yee, Julie L.; Takekawa, John Y.

    2014-01-01

    The South Bay Salt Pond Restoration Project aims to restore 50–90 percent of former salt evaporation ponds into tidal marsh in South San Francisco Bay, California. However, large numbers of waterbirds use these ponds annually as nesting and foraging habitat. Islands within ponds are particularly important habitat for nesting, foraging, and roosting waterbirds. To maintain current waterbird populations, the South Bay Salt Pond Restoration Project plans to create new islands within former salt ponds in South San Francisco Bay. In a series of studies, we investigated pond and individual island attributes that are most beneficial to nesting, foraging, and roosting waterbirds.

  5. Naphtha evaporation from oil sands tailings ponds

    Energy Technology Data Exchange (ETDEWEB)

    Kasperski, K.; Munoz, V.; Mikula, R. [Natural Resources Canada, Devon, AB (Canada). CANMET Western Research Centre

    2010-07-01

    The environmental impacts of volatile organic compounds (VOCs) from oil sands tailings ponds must be considered when evaluating new oil sands mining and extraction operations. Studies have suggested that only 40 percent of the solvent sent to tailings ponds is available to the environment, while the rest is irreversibly trapped. The recovery of hydrocarbons from oil sands froth process water is low. This PowerPoint presentation discussed a method of distinguishing between water and hydrocarbons at low temperatures. Samples were heated to 246 degrees C at 15 degrees C and held for 10 minutes. Heating was then resumed at 750 degrees C and held for 10 minutes in a pyrolysis phase, then cooled and reheated with an oxygen addition. The method demonstrated that the diluent distribution between the solids and water phases is misinterpreted as diluent that will evaporate, and diluent that will not evaporate. The study concluded by suggesting that the definition of recoverable and unrecoverable hydrocarbon should be re-termed as easily recoverable, and difficult to recover. tabs., figs.

  6. Spray pond design for nuclear power plants

    International Nuclear Information System (INIS)

    Codell, R.B.; Asce, A.M.

    1986-01-01

    This paper presents a complex methodology for assessing the performance of spray ponds in ultimate heat sink service at nuclear power plants. A spray pond performance model, developed in the companion paper, is used in conjunction with on-site and off-site meteorological data to predict the highest temperature and greatest 30 day water loss which can reasonable be expected to occur during the lifetime of the plant. The performance model for heat and mass transfer is used to develop an efficient phenomenological model used to scan the long-term meteorological records. Refined estimates of temperature or water loss may then be based on more complicated models if necessary. Short-term onsite data are correlated to the long-term off-site data to formulate correction factors for the difference in location. Cumulative distribution functions for temperature and water loss are determined from the long-term meteorological records to predict the occurrence of these quantities which are less severe that the peak. The methodology is demonstrated using data and parameters from the Palo Verde nuclear plant as an example

  7. 2101-M Pond hydrogeologic characterization report

    Energy Technology Data Exchange (ETDEWEB)

    Chamness, M.A.; Luttrell, S.P.; Bates, D.J.; Martin, W.J.

    1990-09-01

    This report documents information collected by the Pacific Northwest Laboratory {sup (a)} at the request of Westinghouse Hanford Company. Presented in this report is the interpretation of the hydrogeologic environment at the 2101-M Pond, located in the 200-East Area of the Hanford Site. This information and its accompanying interpretation were derived from sampling and testing activities associated with the installation of four ground-water monitoring wells, in addition to data gathered from several previously existing wells. The new monitoring wells were installed as part of a groundwater monitoring program initiated in 1988. The four new monitoring wells were installed around the 2101-M Pond between May 23 and August 27, 1988. Geologic sampling, aquifer testing, and initial ground-water sampling were performed during the installation of these wells. Laboratory analyses of the sediment samples for particle size, calcium carbonate content, and selected natural and contaminant constituents were performed. A full year of quarterly ground-water sampling and the first statistical analysis of background and downgradient data have also been performed. 112 refs., 49 figs., 18 tabs.

  8. Pond bank access as an approach for managing toxic cyanobacteria in beef cattle pasture drinking water ponds.

    Science.gov (United States)

    Wilson, Alan E; Chislock, Michael F; Yang, Zhen; Barros, Mário U G; Roberts, John F

    2018-03-25

    Forty-one livestock drinking water ponds in Alabama beef cattle pastures during were surveyed during the late summer to generally understand water quality patterns in these important water resources. Since livestock drinking water ponds are prone to excess nutrients that typically lead to eutrophication, which can promote blooms of toxigenic phytoplankton such as cyanobacteria, we also assessed the threat of exposure to the hepatotoxin, microcystin. Eighty percent of the ponds studied contained measurable microcystin, while three of these ponds had concentrations above human drinking water thresholds set by the US Environmental Protection Agency (i.e., 0.3 μg/L). Water quality patterns in the livestock drinking water ponds contrasted sharply with patterns typically observed for temperate freshwater lakes and reservoirs. Namely, we found several non-linear relationships between phytoplankton abundance (measured as chlorophyll) and nutrients or total suspended solids. Livestock had direct access to all the study ponds. Consequently, the proportion of inorganic suspended solids (e.g., sediment) increased with higher concentrations of total suspended solids, which underlies these patterns. Unimodal relationships were also observed between microcystin and phytoplankton abundance or nutrients. Euglenoids were abundant in the four ponds with chlorophyll concentrations > 250 μg/L (and dominated three of these ponds), which could explain why ponds with high chlorophyll concentrations would have low microcystin concentrations. Based on observations made during sampling events and available water quality data, livestock-mediated bioturbation is causing elevated total suspended solids that lead to reduced phytoplankton abundance and microcystin despite high concentrations of nutrients, such as phosphorus and nitrogen. Thus, livestock could be used to manage algal blooms, including toxic secondary metabolites, in their drinking water ponds by allowing them to walk in the

  9. Biological removal of algae in an integrated pond system

    CSIR Research Space (South Africa)

    Meiring, PGJ

    1995-01-01

    Full Text Available A system of oxidation ponds in series with a biological trickling filter is described. It was known that this arrangement was incapable of reducing effectively the levels of algae present in the pond liquid even though nitrification was effected...

  10. Modeling the summertime evolution of sea-ice melt ponds

    DEFF Research Database (Denmark)

    Lüthje, Mikael; Feltham, D.L.; Taylor, P.D.

    2006-01-01

    We present a mathematical model describing the summer melting of sea ice. We simulate the evolution of melt ponds and determine area coverage and total surface ablation. The model predictions are tested for sensitivity to the melt rate of unponded ice, enhanced melt rate beneath the melt ponds...

  11. Arthropod fauna of the University of Nigeria, Nsukka, Sewage pond ...

    African Journals Online (AJOL)

    A survey of arthropod fauna of the University of Nigeria Nsukka sewage pond was carried out within May and June 2011. The aim was to determine the various arthropod species and its abundance in the sewage pond. The analysis was carried out by two methods, physico-chemical analysis and arthropod faunal studies.

  12. Feeding selectivity of wild and pond-cultured Nile tilapia ...

    African Journals Online (AJOL)

    A comparison of feeding selectivity of wild and pond-cultured Nile tilapia Oreochromis niloticus was conducted in 2008. Water and fish samples were collected in Shirati Bay, Lake Victoria, and from fish ponds in Tarime district using a La Motte water sampler and seine nets, respectively. Cyanophytes were abundant and ...

  13. Effects of riparian buffers on hydrology of northern seasonal ponds

    Science.gov (United States)

    Randall K. Kolka; Brian J. Palik; Daniel P. Tersteeg; James C. Bell

    2011-01-01

    Although seasonal ponds are common in northern, glaciated, forested landscapes, forest management guidelines are generally lacking for these systems. The objective of this study was to determine the effect of riparian buffer type on seasonal pond hydrology following harvest of the adjacent upland forest. A replicated block design consisting of four buffer treatments...

  14. Fertilization of Earth Ponds. II: Effects on Plankton Communities ...

    African Journals Online (AJOL)

    A study of the effects of slurry inorganic and organic of fertilizers on the production of phyto-and zooplankton in earth ponds was conducted in Central Scotland, U.K. over a period of one year. For the inorganic fertilization, replicate ponds were treated with low and high phosphorus (LP, HP), high phosphorus and nitrogen ...

  15. Mathematical modeling of dissolved oxygen in fish ponds ...

    African Journals Online (AJOL)

    Mathematical modeling of dissolved oxygen in fish ponds. WJS Mwegoha, ME Kaseva, SMM Sabai. Abstract. A mathematical model was developed to predict the effects of wind speed, light, pH, Temperature, dissolved carbon dioxide and chemical oxygen demand (COD) on Dissolved Oxygen (DO) in fish ponds. The effects ...

  16. Conception and methodology of a prospective safety report for uranium mills tailings ponds

    International Nuclear Information System (INIS)

    Weiss, D.; Larue, J.; Fischer- Appelt, K.

    2006-01-01

    transport of contaminants into the underground. - Conclusions. Based on the results of the safety analysis it can be estimated that some kind of in-situ remediation represents the best suited option. Due to the system stabilizing features the spar cover must be preserved. The seepage water flowing out at the main dam has to be collected. The tailings pond should be replanted. The surface of the pond should be adopted to the former site morphology. (authors)

  17. Conception and methodology of a prospective safety report for uranium mills tailings ponds

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, D.; Larue, J.; Fischer- Appelt, K. [Gesellschaft fuer Anlagen- und Reaktorsicherheit mbH (GRS), Koln (Germany)

    2006-07-01

    vertical transport of contaminants into the underground. - Conclusions. Based on the results of the safety analysis it can be estimated that some kind of in-situ remediation represents the best suited option. Due to the system stabilizing features the spar cover must be preserved. The seepage water flowing out at the main dam has to be collected. The tailings pond should be replanted. The surface of the pond should be adopted to the former site morphology. (authors)

  18. Remediation of the low-level radioactive waste tailing pond in Kowary

    International Nuclear Information System (INIS)

    Waclawek, Z.

    1999-01-01

    The town of Kowary was the centre of uranium mining activities in Poland. The headquarters of the uranium mining company ZPR-1 (Zaklady Przemyslowe R-1) were located there, as it was the only uranium processing plant in Poland. Mining in Uranium in Poland ceased in 1963, but processing of low-grade dumps was continued in Kowary until 1972. As a result of these processing activities, a significant volume of wastes was produced and the tailings pond in Kowary was constructed to accommodate these wastes. The tailings pond covers an area of 1,3 ha. It is a hydrotechnical construction closed on three sides by a dam, which has been modified a number of times over the years. It is now 300 m long (the sum of the three sides)m with a maximum height of 12 m, and is at the limits of the geotechnical stability. As a result of the uranium processing activities, the tailings pond was filled with about 2,5 x 10 5 t of disposed fine-grained gneisses and schists containing about 4,5 t of uranium and about 440 GBq of radium (from processing of uranium ores). A prompt remedial action in this case is particularly necessary because the tailings pond is located in a steep mountainous valley where the local climate involves rapid summer rains with heavy erosion. The nearest buildings in the town of Kowary are located literally at the foot of the 12 m high dam and private gardens extend onto the dam slope. The urgency has recently been demonstrated during the flood of summer 1997 when the base of the dam eroded. In the early seventies, Wroclaw University of Technology (WUT) received, by a governmental decision, ownership of both the area and the facilities of the former uranium mining company ZPR-1. Subsequently, the company Hydromet, Ltd., owned by WUT, has continued to use the existing chemical plant for the various experimental processes of rare (radioactive) metals, chemical production and galvanic processes. As a result, 30 t of mixed heavy metals and 300 t of the remnants from the

  19. Walden Pond, Massachusetts: Environmental Setting and Current Investigations

    Science.gov (United States)

    Colman, John A.; Waldron, Marcus C.

    1998-01-01

    Introduction Walden Pond, in Concord, Massachusetts, is famous among lakes because of its unique social history. Walden was the setting for American naturalist Henry David Thoreau's well-known essay 'Walden; or, Life in the Woods,' first published in 1854. Thoreau lived and wrote at Walden Pond from July 1845 to September 1847. In 'Walden,' Thoreau combined highly admired writing on Transcendental philosophy with pioneering observations of aquatic ecology and physical aspects of limnology, the study of lakes. Because Thoreau also defended so effectively the value of living close to nature in the Walden woods, the pond is considered by many to be the birthplace of the American conservation movement. Visitors come from all over the world to the pond, which has been designated a National Historic Landmark, and its fame has resulted in a major fund drive to preserve the surrounding woods. Walden Pond has no surfacewater inflow or outflow, and much of its ground-water contributing area likely is preserved within the Walden Pond Reservation area (fig. 1). Only 15 miles from Boston, the pond is unusually clear and pristine for an urban-area lake. However, point sources of nutrients near the pond, and a large annual visitor attendance, concentrated during the summer when the swimming beach (fig. 2) is open, may contribute a nutrient load sufficient to change the pond environment. The occurrence of nuisance algal species, a recent beach closing, and an awareness of water-quality problems suffered by other ponds in the region raise concerns about the risk of ecological change at Walden Pond. Despite the role of Walden Pond as a cultural and environmental icon, little is known about the pond's ecological features, such as its internal nutrient cycling or the structure of its food web, nor have consistent measurements been made to determine whether these features are changing or are stable. Production rates of aquatic plants in lakes and ponds naturally undergo a slow increase

  20. The evaporation from ponds in the French Midwest

    Directory of Open Access Journals (Sweden)

    Mohammad AL DOMANY

    2013-12-01

    Full Text Available This research shows the results of a study about evaporation in five ponds in the Midwest of France. To realize this study we used climate data from the meteorological station of the Limoges-Bellegarde airport and the data of a weather station installed by us near one of the ponds. We used eight different methods to calculate the evaporation rate and we modified the Penman-Monteith method by replacing the air temperature by water temperature. To understand the role of ponds in water loss through evaporation, we proposed a hypothesis that says : if the pond did not exist, what results would we get? Based on this hypothesis we calculated the potential evapotranspiration rate taking into account the percentage of interception by vegetation. In conclusion, this study indicates that the ponds in the French Midwest present a gain of water

  1. Cyanobacterial and microcystins dynamics following the application of hydrogen peroxide to waste stabilisation ponds

    Science.gov (United States)

    Barrington, D. J.; Ghadouani, A.; Ivey, G. N.

    2013-06-01

    Cyanobacteria and cyanotoxins are a risk to human and ecological health, and a hindrance to biological wastewater treatment. This study investigated the use of hydrogen peroxide (H2O2) for the removal of cyanobacteria and cyanotoxins from within waste stabilization ponds (WSPs). The daily dynamics of cyanobacteria and microcystins (commonly occurring cyanotoxins) were examined following the addition of H2O2 to wastewater within both the laboratory and at the full scale within a maturation WSP, the final pond in a wastewater treatment plant. Hydrogen peroxide treatment at concentrations ≥ 0.1 mg H2O2 μg-1 total phytoplankton chlorophyll a led to the lysis of cyanobacteria, in turn releasing intracellular microcystins to the dissolved state. In the full-scale trial, dissolved microcystins were then degraded to negligible concentrations by H2O2 and environmental processes within five days. A shift in the phytoplankton assemblage towards beneficial Chlorophyta species was also observed within days of H2O2 addition. However, within weeks, the Chlorophyta population was significantly reduced by the re-establishment of toxic cyanobacterial species. This re-establishment was likely due to the inflow of cyanobacteria from ponds earlier in the treatment train, suggesting that whilst H2O2 may be a suitable short-term management technique, it must be coupled with control over inflows if it is to improve WSP performance in the longer term.

  2. Cyanobacterial and microcystins dynamics following the application of hydrogen peroxide to waste stabilisation ponds

    Directory of Open Access Journals (Sweden)

    D. J. Barrington

    2013-06-01

    Full Text Available Cyanobacteria and cyanotoxins are a risk to human and ecological health, and a hindrance to biological wastewater treatment. This study investigated the use of hydrogen peroxide (H2O2 for the removal of cyanobacteria and cyanotoxins from within waste stabilization ponds (WSPs. The daily dynamics of cyanobacteria and microcystins (commonly occurring cyanotoxins were examined following the addition of H2O2 to wastewater within both the laboratory and at the full scale within a maturation WSP, the final pond in a wastewater treatment plant. Hydrogen peroxide treatment at concentrations ≥ 0.1 mg H2O2 μg−1 total phytoplankton chlorophyll a led to the lysis of cyanobacteria, in turn releasing intracellular microcystins to the dissolved state. In the full-scale trial, dissolved microcystins were then degraded to negligible concentrations by H2O2 and environmental processes within five days. A shift in the phytoplankton assemblage towards beneficial Chlorophyta species was also observed within days of H2O2 addition. However, within weeks, the Chlorophyta population was significantly reduced by the re-establishment of toxic cyanobacterial species. This re-establishment was likely due to the inflow of cyanobacteria from ponds earlier in the treatment train, suggesting that whilst H2O2 may be a suitable short-term management technique, it must be coupled with control over inflows if it is to improve WSP performance in the longer term.

  3. Vanishing Ponds and Regional Water Resources in Taoyuan, Taiwan

    Directory of Open Access Journals (Sweden)

    Yuei-An Liou

    2015-01-01

    Full Text Available Taiwan has a Subtropic to Tropical climate, but its precipitation varies widely in response to seasonal effects and weather events such as Typhoon and Meiyu systems. Precipitation must be held back in reservoirs to provide and regulate sufficient water supply. Balancing the irregular precipitation and increasing water demands generates tremendous pressure on water resources management for the water stored in the Shihmen Reservoir, which is the major unitary water supply system in the Greater Taoyuan Area. Such pressure will be significantly enlarged due to the huge 17 billion USD Taoyuan Aerotropolis Project. In earlier days many small artificial ponds (a common terminology in this article, including irrigation ponds, fishery ponds and others, were built to cope with water shortages in Taoyuan County. These small storage ponds provided a solution that resolved seasonal precipitation shortages. Unfortunately, these ponds have been vanishing one after another one due to regional industrialization and urbanization in recent decades and less than 40% of them still remain today. There is great urgency and importance to investigating the link between vanishing ponds and water resources management. Remote sensing technology was used in this study to monitor the environmental consequences in the Taoyuan area by conducting multi-temporal analysis on the changes in water bodies, i.e., ponds. SPOT satellite images taken in 1993, 2003, and 2010 were utilized to analyze and assess the importance of small-scale ponds as water conservation facilities. It was found that, during the seventeen years from 1993 - 2010, the number of irrigation ponds decreased by 35.94%. These ponds can reduce the burden on the major reservoir and increase the water recycling rate if they are properly conserved. They can also improve rainfall interception and surface detention capabilities, and provide another planning advantage for regional water management.

  4. Emissions from Produced Water Treatment Ponds, Uintah Basin, Utah, USA

    Science.gov (United States)

    Mansfield, M. L.; Lyman, S. N.; Tran, H.; O'Neil, T.; Anderson, R.

    2015-12-01

    An aqueous phase, known as "produced water," usually accompanies the hydrocarbon fluid phases that are extracted from Earth's crust during oil and natural gas extraction. Produced water contains dissolved and suspended organics and other contaminants and hence cannot be discharged directly into the hydrosphere. One common disposal method is to discharge produced water into open-pit evaporation ponds. Spent hydraulic fracturing fluids are also often discharged into the same ponds. It is obvious to anyone with a healthy olfactory system that such ponds emit volatile organics to the atmosphere, but very little work has been done to characterize such emissions. Because oil, gas, and water phases are often in contact in geologic formations, we can expect that more highly soluble compounds (e.g., salts, alcohols, carbonyls, carboxyls, BTEX, etc.) partition preferentially into produced water. However, as the water in the ponds age, many physical, chemical, and biological processes alter the composition of the water, and therefore the composition and strength of volatile organic emissions. For example, some ponds are aerated to hasten evaporation, which also promotes oxidation of organics dissolved in the water. Some ponds are treated with microbes to promote bio-oxidation. In other words, emissions from ponds are expected to be a complex function of the composition of the water as it first enters the pond, and also of the age of the water and of its treatment history. We have conducted many measurements of emissions from produced water ponds in the Uintah Basin of eastern Utah, both by flux chamber and by evacuated canister sampling with inverse modeling. These measurements include fluxes of CO2, CH4, methanol, and many other volatile organic gases. We have also measured chemical compositions and microbial content of water in the ponds. Results of these measurements will be reported.

  5. Characterizing bacterial communities in tilapia pond surface sediment and their responses to pond differences and temporal variations.

    Science.gov (United States)

    Fan, Limin; Barry, Kamira; Hu, Gengdong; Meng, Shunlong; Song, Chao; Qiu, Liping; Zheng, Yao; Wu, Wei; Qu, Jianhong; Chen, Jiazhang; Xu, Pao

    2017-01-01

    Bacterial community compositions in the surface sediment of tilapia ponds and their responses to pond characteristics or seasonal variations were investigated. For that, three ponds with different stocking densities were selected to collect the samples. And the method of Illumina high-throughput sequencing was used to amplify the bacterial 16S rRNA genes. A total of 662, 876 valid reads and 5649 operational taxonomic units were obtained. Further analysis showed that the dominant phyla in all three ponds were Proteobacteria, Bacteroidetes, Chloroflexi, and Acidobacteria. The phyla Planctomycetes, Firmicutes, Chlorobi, and Spirochaetae were also relatively abundant. Among the eight phyla, the abundances of only Proteobacteria, Bacteroidetes, Firmicutes, and Spirochaetae were affected by seasonal variations, while seven of these (with the exception of Acidobacteria) were affected by pond differences. A comprehensive analysis of the richness and diversity of the bacterial 16S rRNA gene, and of the similarity in bacterial community composition in sediment also showed that the communities in tilapia pond sediment were shaped more by pond differences than by seasonal variations. Linear discriminant analysis further indicated that the influences of pond characteristics on sediment bacterial communities might be related to feed coefficients and stocking densities of genetically improved farmed tilapia (GIFT).

  6. Par Pond phytoplankton in association with refilling of the pond: Final Report for sampling from February 1995 -- September 1996

    International Nuclear Information System (INIS)

    Wilde, E.W.; Johnson, M.A.; Cody, W.C.

    1996-01-01

    This report describes the results of phytoplankton analyses from Par Pond samples collected between February 1995 and September 1996. The principal objective of the study was to determine the effect of refilling of Par Pond following repair of the dam on the phytoplankton community. Algal blooms are often responsible for fish kills and other detrimental effects in ponds and lakes, and it was postulated that decaying vegetation from formerly exposed sediments might trigger algal blooms that could result in fish kills in Par Pond following the refill. Sporadic algal blooms involving blue-green algae were detected, especially during the summer of 1996. However, the data derived from the study demonstrates that overall, the refilling effort caused no significant negative impact to the pond attributable to phytoplankton dynamics

  7. Par Pond phytoplankton in association with refilling of the pond: Final Report for sampling from February 1995 -- September 1996

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, E.W.; Johnson, M.A.; Cody, W.C.

    1996-12-31

    This report describes the results of phytoplankton analyses from Par Pond samples collected between February 1995 and September 1996. The principal objective of the study was to determine the effect of refilling of Par Pond following repair of the dam on the phytoplankton community. Algal blooms are often responsible for fish kills and other detrimental effects in ponds and lakes, and it was postulated that decaying vegetation from formerly exposed sediments might trigger algal blooms that could result in fish kills in Par Pond following the refill. Sporadic algal blooms involving blue-green algae were detected, especially during the summer of 1996. However, the data derived from the study demonstrates that overall, the refilling effort caused no significant negative impact to the pond attributable to phytoplankton dynamics.

  8. Results of submerged sediment core sampling and analysis on Par Pond, Pond C, and L Lake: July 1995

    International Nuclear Information System (INIS)

    Koch, J.W. II; Martin, F.D.; Friday, G.P.

    1996-06-01

    Sediment cores from shallow and deep water locations in Par Pond, Pond C, and L Lake were collected and analyzed in 1995 for radioactive and nonradioactive constituents. This core analysis was conducted to develop a defensible characterization of contaminants found in the sediments of Par Pond, Pond C, and L Lake. Mercury was the only nonradiological constituent with a nonestimated quantity that was detected above the U.S Environmental Protection Agency Region IV potential contaminants of concern screening criteria. It was detected at a depth of 0.3--0.6 meters (1.0--2.0 feet) at one location in L Lake. Cesium-137, promethium-146, plutonium-238, and zirconium-95 had significantly higher concentrations in Par Pond sediments than in sediments from the reference sites. Cobalt-60, cesium-137, plutonium-238, plutonium-239/240, and strontium-90 had significantly higher concentrations in L-Lake sediments than sediments from the reference sites

  9. Interactions between piscivores, zooplanktivores and zooplankton in submerged macrophytes : Preliminary observations from enclosure and pond experiments

    DEFF Research Database (Denmark)

    Jacobsen, Lene; Perrow, M.R.; Landkildehus, F.

    1997-01-01

    behavioural changes of zooplanktivores has received little attention, even though this may be an important mechanism in enhancing the stability of submerged macrophytes in shallow lakes. Preliminary observations from an unreplicated large-scale field enclosure experiment and a replicated pond experiment...... and the presence of zooplanktivores typically changed the habitat selection of cladoceran zooplankton. In the case of piscivore/zooplanktivore interactions, the risk of predation was enough to generate clear responses even where the losses to predation were low. However, only in the enclosure experiment...

  10. Data validation report for the 100-D Ponds Operable Unit: 100-D ponds sampling

    International Nuclear Information System (INIS)

    Stankovich, M.T.

    1994-01-01

    Westinghouse-Hanford has requested that 100 percent of the Sample Delivery Groups be validated for the 100-D Ponds Operable Unit Sampling Investigation. Therefore the data from the chemical analysis of all 30 samples from this sampling event and their related quality assurance samples were reviewed and validated to verify that reported sample results were of sufficient quality to support decisions regarding remedial actions performed at this site

  11. QUALITATIVE COMPOSITION OF PHYTOPLANKTONS IN DIFFERENTLY MANURED CARP PONDS

    Directory of Open Access Journals (Sweden)

    Ljubica Debeljak

    1997-04-01

    Full Text Available Researches on qualitative composition of phytoplanktons in differently manured fish-ponds "Jelas" were carried out in 1996. The carp fingerling from larve to its second month was nurtured in three fish-ponds (A,B,C with the plantation of larves of 1,000,000 ind.ha-1. Larves and carp fry were nurtured by trouvit and wheat flour. The fish-pond A was controlled but not manured; the fish-pond B was fertilized by the total of 200 kg.ha-1 NPK (15:15:15 and the fish-pond C was fertilized by the total of 75 l.ha-1 of UAN and 75 kg.l-1 of NP (12:52. All fish-ponds had similar water chemism. In the qualitative composition of phytoplanktons there were stated 93 kinds, members of systematic groups Cyanophyta (10%, Euglenophyta (16.2%, Pyrrophyta (2%, Chrysophyta (39.4% and Chlorophyta (32%. All fish-ponds had similar qualitative composition of phytoplanktons with the flora similarity quotient from 65.5% to 72%.

  12. Ecological behavior of plutonium and americium in a freshwater pond

    International Nuclear Information System (INIS)

    Emery, R.M.; Klopfer, D.C.; Garland, T.R.; Weimer, W.C.

    1976-01-01

    A plutonium (Pu) processing waste pond on the Hanford Reservation has been studied since mid-1973 to characterize the pond's limnology and determine the ecological behavior of transuranics in this ecosystem. This ultra-eutrophic pond has a water inflow rate of 10 m 3 /min, of which 95% leaves the pond by percolation. Macrophytes (mainly Potamogeton), algae (mainly Cladophora), benthic invertebrates (mainly dipteran and odonate larvae, hemipterans, amphipods and gastropods) and goldfish are the major biotic components of the system. Sediments appear to be the principal repository of Pu and Am, having mean concentrations for 238 Pu, 239 240 Pu and 241 Am of 112, 121 and 71 pCi/g (dry), respectively. Mean ratios of isotopes in the sediments are 0.85 for 238 Pu to 239 240 Pu, and 0.49 for 241 Am to 239 240 Pu. Algal floc (decomposing algal material) is the major concentrator of Pu and Am in the pond having mean concentrations of 238 Pu of 986 pCi/g, for 239 240 Pu of 615 pCi/g, and for 241 Am of 256 pCi/g. Watercress (Rorippa) had Pu levels about equal to those of the sediments, while dragonfly larvae (Libellula) and snails (Lymnaea) along with watercress had Am levels approximating those of the sediments. The remaining biota had Pu and Am levels which were generally well below those of the sediments.Preliminary in situ experiments indicate that goldfish reach an equilibrium level for Pu of about 15 pCi/g within a few days of exposure to the pond, after which they may remain active in the pond for many months without further accumulation. Experimental goldfish established ratios of 238 Pu to 239 240 Pu and 241 Am to 239 240 Pu that were similar to all other pond biota within 2 weeks of pond residence, suggesting a common source of biologically available Pu and Am

  13. Monthly and diurnal variations of limnological conditions of two ponds

    Directory of Open Access Journals (Sweden)

    AKM Fazlur Rahaman

    2017-06-01

    Full Text Available A study on monthly and diurnal changes of limnological conditions of two ponds was conducted in the Bangladesh Agricultural University campus, Mymensingh. The research work was performed by studying the limnological parameters such as transparency, temperature, dissolved oxygen, free carbon dioxide, pH, total alkalinity, nitrate-nitrogen, phosphate-phosphorus and plankton. Diurnal variations of physico-chemical factors were studied fortnightly at 6 hrs intervals at 6 a.m., 12 noon, 6 p.m. and 12 midnight. The amounts of transparency, dissolved oxygen and pH were higher during winter months than in summer months in both the ponds. Transparency, water temperature, total alkalinity, NO3-N and PO4-P were higher during summer months than in winter months in both the ponds. But the amount of free carbon dioxide was higher during winter months than in summer months in pond 1 while in pond 2 the amount of free carbon dioxide was higher during summer months than in winter months. Qualitative and quantitative monthly variations of phytoplankton and zooplankton were observed in both the ponds during the study period. The highest amount of dissolved oxygen, pH and total alkalinity were recorded at 6 p.m. and the lowest amounts of those at 6 a.m. in both the ponds. The highest temperature was recorded at 12 noon and the lowest at 12 midnight. But the highest amount of free carbon dioxide was recorded at 6 a.m. and the lowest at 6 p.m. in both the ponds. All the factors showed appreciable diel variations throughout the study period, which indicate that the ponds are productive.

  14. Groundwater impact assessment report for the 100-D Ponds

    International Nuclear Information System (INIS)

    Alexander, D.J.

    1993-07-01

    The 183-D Water Treatment Facility (WTF) discharges effluent to the 120-0-1 Ponds (100-D Ponds) located north of the 100-D Area perimeter fence. This report satisfies one of the requirements of the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-17-00B as agreed by the US Department of Energy, Washington State Department of Ecology, and the US Environmental Protection Agency. Tri-Party Agreement Milestone M-17-00B includes a requirement to assess impacts to groundwater from disposal of the 183-D WTF effluent to the 100-D Ponds. In addition, the 100-D Ponds are a Resource Conservation and Recovery Act of 1976 treatment, storage, and disposal facility covered by the 100-D Ponds Closure Plan (DOE-RL 1993a). There is evidence of groundwater contamination, primarily nitrate, tritium, and chromium, in the unconfined aquifer beneath the 100-D Area and 100 Areas in general. The contaminant plumes are area wide and are a result of past-practice reactor and disposal operations in the 100-D Area currently being investigated as part of the 100-DR-1 and 100-HR-3 Operable Units (DOE-RL 1992b, 1992a). Based on current effluent conditions, continued operation of the 100-D Ponds will not adversely affect the groundwater quality in the 100-D Area. Monitoring wells near the pond have slightly higher alkaline pH values than wells in the rest of the area. Concentrations of known contaminants in these wells are lower than ambient 100-D Area groundwater conditions and exhibit a localized dilution effect associated with discharges to the pond. Hydraulic impact to the local groundwater system from these discharges is minor. The groundwater monitoring well network for the 100-D Ponds is adequate

  15. A review of virus removal in wastewater treatment pond systems.

    Science.gov (United States)

    Verbyla, Matthew E; Mihelcic, James R

    2015-03-15

    Wastewater treatment ponds (lagoons) are one of the most common types of technologies used for wastewater management worldwide, especially in small cities and towns. They are particularly well-suited for systems where the effluent is reused for irrigation. However, the efficiency of virus removal in wastewater treatment pond systems is not very well understood. The main objective of this paper is to critically review the major findings related to virus removal in wastewater treatment pond systems and to statistically analyze results reported in the literature from field studies on virus removal in these systems. A comprehensive analysis of virus removal reported in the literature from 71 different wastewater treatment pond systems reveals only a weak to moderate correlation of virus removal with theoretical hydraulic retention time. On average, one log10 reduction of viruses was achieved for every 14.5-20.9 days of retention, but the 95th percentile value of the data analyzed was 54 days. The mechanisms responsible for virus removal in wastewater treatment ponds were also reviewed. One recent finding is that sedimentation may not be a significant virus removal mechanism in some wastewater ponds. Recent research has also revealed that direct and indirect sunlight-mediated mechanisms are not only dependent on pond water chemistry and optics, but also on the characteristics of the virus and its genome. MS2 coliphage is considered to be the best surrogate for studying sunlight disinfection in ponds. The interaction of viruses with particles, with other microorganisms, and with macroinvertebrates in wastewater treatment ponds has not been extensively studied. It is also unclear whether virus internalization by higher trophic-level organisms has a protective or a detrimental effect on virus viability and transport in pond systems. Similarly, the impact of virus-particle associations on sunlight disinfection in ponds is not well understood. Future research should focus on

  16. FROM PONDS TO MAN-MADE SEAS IN RUSSIA

    Directory of Open Access Journals (Sweden)

    Sergey Gorshkov

    2013-01-01

    Full Text Available Russia has more than 2200 reservoirs and large ponds. As time went by, ponds lost their importance in some aspects of human life, while newly created man-made seas impacted the nature and the people in two ways. The costs involved in designing, constructing, and operating the artificial seas, especially on the plains, have been too high to consider them as an undisputed achievement of the Soviet scientists transforming the nature. This paper discusses the problem of ponds and man-made seas in Russia.

  17. Report on the methylmercury situation in Par Pond. Final report

    International Nuclear Information System (INIS)

    Schindler, J.E.; Williams, D.J.; Alberts, J.J.

    1975-06-01

    Studies are reported on the methylation and accumulation of mercury in fish populations of the pond. Results showed that the majority of the mercury in the fish muscles was in the methyl mercury form. Very low concentrations of mercury were found in the pond sediments. Physiological methylation of the mercury could not be demonstrated by in vivo or in vitro techniques. Organic ligand methylation and reduction of the mercury was shown to be a possible mechanism to account for both the mercury distribution in the pond and the concentrations of methylmercury in the fish. Recommendations are made for remedial treatments to eliminate the mercury problem. (HLW)

  18. Limnological database for Par Pond: 1959 to 1980

    International Nuclear Information System (INIS)

    Tilly, L.J.

    1981-03-01

    A limnological database for Par Pond, a cooling reservoir for hot reactor effluent water at the Savannah River Plant, is described. The data are derived from a combination of research and monitoring efforts on Par Pond since 1959. The approximately 24,000-byte database provides water quality, primary productivity, and flow data from a number of different stations, depths, and times during the 22-year history of the Par Pond impoundment. The data have been organized to permit an interpretation of the effects of twenty years of cooling system operations on the structure and function of an aquatic ecosystem

  19. Greenhouse Gas Exchange in Small Arctic Thaw Ponds

    Science.gov (United States)

    Laurion, I.; Bégin, P. N.; Bouchard, F.; Preskienis, V.

    2014-12-01

    Arctic lakes and ponds can represent up to one quarter of the land surface in permafrost landscapes, particularly in lowland tundra landscapes characterized by ice wedge organic polygons. Thaw ponds can be defined as the aquatic ecosystems associated to thawing of organic soils, either resulting from active layer processes and located above low-center peat polygons (hereafter low-center polygonal or LCP ponds), or resulting from thermokarst slumping above melting ice wedges linked to the accelerated degradation of permafrost (hereafter ice-wedge trough or IWT ponds). These ponds can merge together forming larger water bodies, but with relatively stable shores (hereafter merged polygonal or MPG ponds), and with limnological characteristics similar to LCP ponds. These aquatic systems are very small and shallow, and present a different physical structure than the larger thermokarst lakes, generated after years of development and land subsidence. In a glacier valley on Bylot Island, Nunavut, Canada, thermokarst and kettle lakes together represent 29% of the aquatic area, with a thermal profile resembling those of more standard arctic lakes (mixed epilimnion). The IWT ponds (44% of the area) are stratified for a large fraction of the summer despite their shallowness, while LCP and MPG ponds (27% of the area) show a more homogeneous water column. This will affect gas exchange in these diverse aquatic systems, in addition to their unique microbiota and organic carbon lability that control the production and consumption rates of greenhouse gases. The stratification in IWT ponds generates hypoxic conditions at the bottom, and together with the larger availability of organic carbon, stimulates methanogenesis and limits the mitigating action of methanotrophs. Overall, thaw ponds are largely supersaturated in methane, with IWT ponds dominating the emissions in this landscape (92% of total aquatic emissions estimated for the same valley), and they present large variations in

  20. Role of rainwater induced subsurface flow in water-level dynamics and thermoerosion of shallow thermokarst ponds on the Northeastern Qinghai-Tibet Plateau

    Science.gov (United States)

    Pan, X.; Yu, Q.; You, Y.

    2014-12-01

    Understanding hydrological and thermal regimes of thermokarst lakes is of great importance for predicting their responses to climate change. However, mechanism of water-level dynamics and associated thermal effects on thermoerosion of thermokarst lakes are still not well understood on the Qinghai-Tibet Plateau (QTP). In this study, we investigate two typical shallow thermokarst ponds (namely small lakes) in a warm permafrost region with thick active layer on the northeastern QTP through quantifying water budget. Results demonstrate that, rainfall induced subsurface lateral flow dominates pond water-level regime. Annual variation of pond water-level relies on areal water budget of surrounding active layer, particularly the high variable of precipitation. Besides, it is worth noting the extraordinary warming during the late ice-cover period, because marked air gap between upper ice-cover and underlying water, led by the upward thawing of thick ice-cover, might result in greenhouse-like condition due to the unique weather that strong solar radiation and little snowpack. This hydrological mechanism also exerts evident impacts on thermal regime and thermoerosion of the shallow thermokarst ponds, and they are closely related to retreat of thermokarst pondshore and underlying permafrost degradation. These findings imply a localized model addressing the unique hydrological and thermal regimes of thermokarst lakes would be essential to study the evolution of these shallow rainwater dominated thermokarst ponds on the QTP.

  1. Elimination and accumulation of polycyclic aromatic hydrocarbons (PAHs) in urban stormwater wet detention ponds

    DEFF Research Database (Denmark)

    Istenič, Daria; Arias, Carlos Alberto; Matamoros, Victor

    2011-01-01

    The concentrations of polycyclic aromatic hydrocarbons (PAHs) in water and sediments of seven wet detention ponds receiving urban stormwater were investigated. The ponds comprised traditional wet detention ponds with a permanent wet volume and a storage volume as well as ponds that were expanded...

  2. Degradation of CIGS solar cells

    NARCIS (Netherlands)

    Theelen, M.J.

    2015-01-01

    Thin film CIGS solar cells and individual layers within these solar cells have been tested in order to assess their long term stability. Alongside with the execution of standard tests, in which elevated temperatures and humidity levels are used, the solar cells have also been exposed to a

  3. Dye stability and performances of dye-sensitized solar cells with different nitrogen additives at elevated temperatures - Can sterically hindered pyridines prevent dye degradation?

    Energy Technology Data Exchange (ETDEWEB)

    Tuyet Nguyen, Phuong; Lund, Torben [Department of Science, Systems and Models, Roskilde University, 4000 Roskilde (Denmark); Rand Andersen, Anders [University of Southern Denmark, Institute of Sensors, Signals and Electrotechnics (SENSE), Niels Bohrs Alle 1, 5230 Odense M (Denmark); Danish Technological Institute, Plastics Technology, Gregersensvej 2630 Taastrup (Denmark); Morten Skou, Eivind [University of Southern Denmark, Department of Chemical Engineering, Biotechnology and Enviromental Technology, Niels Bohrs Alle 1, 5230 Odense M (Denmark)

    2010-10-15

    The homogeneous kinetics of the nucleophilic substitution reactions between the ruthenium dye N719 and eight pyridines and 1-methylbenzimidazole have been investigated in 3-methoxypropionitrile at 100 C. The half lives of N719 with the additives 4-tert-butylpyridine (0.5 M) and 1-methylbenzimidazole (0.5 M) were 57 and 160 h, respectively. Sterically hindered pyridines like 2,6-lutidine did not react with N719. The efficiencies of dye-sensitized solar cells (DSC, area=8.0 cm{sup 2}) prepared with 1-methylbenzimidazole (MBI), 4-tert-butylpyridine (4-TBP), 2,6-lutidine and without any additive were 7.1%, 6.2%, 6.0% and 4.8%, respectively. The cells were stored in dark at 85 C and their I-V curves and impedance spectra were measured at regular time intervals. The N719 dye degradation in the cells were monitored by a new dye extraction protocol combined with analysis of the dye extract by HPLC coupled to mass spectrometry. After 300 h storage in dark at 85 C 40% of the initial amount of N719 dye was degraded in DSC cells prepared with MBI and the efficiency was decreased to 40% of its initial value. DSC cells prepared with 2,6-lutidine or no additives showed smaller thermal dye and efficiency stability at elevated temperatures than DSC cells prepared with the none sterically hindered additives MBI and 4-TBP. In the cells prepared with 2,6-lutidine or no additive higher contents of the iodo products [RuL{sub 2}(NCS)(iodide)]{sup +} and [RuL{sub 2}(3-MPN)(iodide)]{sup +} were found than in cells prepared with 4-TBP and MBI. It is suggested that sterically hindered pyridines have smaller complexation constants with I{sub 3}{sup -} than unsterically hindered additives. This may explain the observed faster nucleophilic substitution rates of uncomplexed I{sub 3}{sup -} with N719 in DSC cells prepared with sterically hindered pyridines. The EIS analysis showed that the lifetime of the injected electrons in the TiO{sub 2}{tau}{sub eff} is reduced by a thermally induced change

  4. Bacterial flora of pond reared Penaeus indicus (Milne Edwards)

    Digital Repository Service at National Institute of Oceanography (India)

    Singh, I.S.B.; Lakshmanaperumalsamy, P.; Chandramohan, D.

    The population size, generic diversity and potential to produce hydrolytic enzymes of heterotrophic bacteria associated with pond reared Penaeus indicus was worked out following standard bacteriological procedures. Chitinoclastic vibrios were found...

  5. The Effects of Species Interaction and Pond Stocking Density on ...

    African Journals Online (AJOL)

    Burchell) and Heterobranchus bidorsalis (Geoffrey Saint-Hilaire) and pond stocking density on the culture of tilapia species which display different parental care strategies. In the presence of catfishes, the maternal mouth-brooder O. niloticus ...

  6. MALLARD REPRODUCTIVE TESTING IN A POND ENVIRONMENT: A PRELIMINARY STUDY

    Science.gov (United States)

    A 2-year preliminary study was conducted on mallard ducks to determine the feasibility of using outdoor pond enclosures for reproductive studies and to evaluate the effects of the insecticide chlorpyrifos on mallard reproduction. No significant reproductive effects were observed ...

  7. Supraglacial Ponds Regulate Runoff From Himalayan Debris-Covered Glaciers

    Science.gov (United States)

    Irvine-Fynn, Tristram D. L.; Porter, Philip R.; Rowan, Ann V.; Quincey, Duncan J.; Gibson, Morgan J.; Bridge, Jonathan W.; Watson, C. Scott; Hubbard, Alun; Glasser, Neil F.

    2017-12-01

    Meltwater and runoff from glaciers in High Mountain Asia is a vital freshwater resource for one-fifth of the Earth's population. Between 13% and 36% of the region's glacierized areas exhibit surface debris cover and associated supraglacial ponds whose hydrological buffering roles remain unconstrained. We present a high-resolution meltwater hydrograph from the extensively debris-covered Khumbu Glacier, Nepal, spanning a 7 month period in 2014. Supraglacial ponds and accompanying debris cover modulate proglacial discharge by acting as transient and evolving reservoirs. Diurnally, the supraglacial pond system may store >23% of observed mean daily discharge, with mean recession constants ranging from 31 to 108 h. Given projections of increased debris cover and supraglacial pond extent across High Mountain Asia, we conclude that runoff regimes may become progressively buffered by the presence of supraglacial reservoirs. Incorporation of these processes is critical to improve predictions of the region's freshwater resource availability and cascading environmental effects downstream.

  8. Western Pond Turtle Observations - Region 1 [ds313

    Data.gov (United States)

    California Natural Resource Agency — This dataset was developed in an effort to compile Western Pond Turtle (Clemmys marmorata) observations in CDFG Region 1. Steve Burton (CDFG Staff Environmental...

  9. VT Northern Forest Lands - Lakes and Ponds area polygons

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) These data identify shorelines of lakes and ponds ten (10) acres and larger. The shorelines are classified according to their development status....

  10. Removal of Heavy Metals and PAH in Highway Detention Ponds

    DEFF Research Database (Denmark)

    Bentzen, Thomas Ruby; Larsen, Torben; Thorndahl, Søren Liedtke

    2005-01-01

    , which has been designed according to standard design criteria for several decades. The study will focus on heavy metals (Cd, Cr, Cu, Pb and Zn) and polyaromatic hydrocarbons (PAH). The long-term simulation of input of flow and pollution to the ponds will be a hind cast based on time series of historical......The paper presents some of the first results from a study of the removal of pollutants in highway detention ponds in Denmark. The objective of the study is to set up a procedure for long-term modelling of discharges of pollutants to the environment from the many Danish highway detention ponds...... rainfalls. The modelling will take place in a special version of the MIKE URBAN. The modelling is calibrated and validated on measurements from selected highway catchments. The removal of pollutants in the ponds is studied by local measurements in combination with CFD modelling using the MIKE 21 and MIKE 3...

  11. South Bay Salt Pond Tidal Wetland Restoration Phase II Planning

    Science.gov (United States)

    Information about the SFBWQP South Bay Salt Pond Tidal Wetland Restoration Phase II Planning project, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic re

  12. South Bay Salt Pond Restoration, Phase II at Ravenswood

    Science.gov (United States)

    Information about the South Bay Salt Pond Restoration Project: Phase II Construction at Ravenswood, part of an EPA competitive grant program to improve SF Bay water quality focused on restoring impaired waters and enhancing aquatic resources.

  13. Approximate computation of hydrothermal conditions of nuclear reactor spray ponds

    International Nuclear Information System (INIS)

    Yarkho, A.A.; Borshchev, V.A.

    1990-01-01

    An algorithm is presented for determining the evaporation numbers of nuclear reactor spray ponds which provide necessary reactor cooling during its normal operation under given meteorological conditions with account of restrictions on the cooled water temperature at the reactor entrance

  14. Beyond Historical Fiction: Speare's "The Witch of Blackbird Pond."

    Science.gov (United States)

    Thuente, Mary Helen

    1985-01-01

    Reviews "The Witch of Blackbird Pond" by E. Speare to show how the full narrative power of the novel derives from the author's successful integration of two separate narrative genres: historical fiction and the folktale. (EL)

  15. Algoflora of oxbow ponds transformed with beavers' activity

    OpenAIRE

    Макаревич, Т. А.; Белоус, В. В.; Гурчунова, Т. А.

    2016-01-01

    Algoflora of oxbow ponds transformed with beaver activity is characterized by high species richness and taxonomic diversity, high periphyton importance in the formation of algoflora compared with phytoplankton, prevalence of periphytic and benthic algae over typically planktonic forms

  16. VT Northern Forest Lands - Lakes and Ponds boundary lines

    Data.gov (United States)

    Vermont Center for Geographic Information — (Link to Metadata) These data identify shorelines of lakes and ponds ten (10) acres and larger. The shorelines are classified according to their development status....

  17. The Belmont Valley integrated algae pond system in retrospect

    African Journals Online (AJOL)

    2013-03-26

    Mar 26, 2013 ... ness amongst all stakeholders including the public at large, the three spheres of ...... (2011) Algae biofuel from wastewater treatment high rate algal ponds. .... and OELMÜLLER R (2002) Photosynthetic electron transport.

  18. The use of polyurethane as encapsulating method for polymer solar cells—An inter laboratory study on outdoor stability in 8 countries

    DEFF Research Database (Denmark)

    Søndergaard, Roar; Makris, Theodoros; Lianos, Panagiotis

    2012-01-01

    A new encapsulation method for organic solar cells has been tested on flexible solar modules and cells embedded in polyurethane, sandwiched between a tempered glass plate and a polycarbonate plate. Panels, each containing 10 organic solar modules/cells, were fabricated and installed for outdoor...... exposure in eight different countries for 4½ months. In order to minimize potential deviations in procedures and equipment, one person was responsible for the fabrication, installation and initial and final IV-measurements of the panels using the same equipment for all measurements and calibrations...

  19. Can terraced pond wetland systems improve urban watershed water quality?

    Science.gov (United States)

    Li, S.; Ho, M.; Flanagan, N. E.; Richardson, C. J.

    2017-12-01

    Properly built constructed wetlands are a more economic and efficient way of wastewater treatment compared with traditional methods, although their mechanisms are far from completely understood. As part of the Stream and Wetland Assessment Management Park (SWAMP), which is aimed to improve the water quality of downstream and thereby enhance watershed ecosystem services, a terraced three-pond wetland system was created near Duke University in 2014. This project is expected to promote the retention and settling of pollutants and sediment before runoffs enter downstream flow. The goal of this study is to examine: (1) whether a terraced pond wetland system improves water quality, during both baseline (low flow) and storm events (high flow), which increases pollutant inputs; and (2) how this system functions to remove pollutants, namely what components of this system (plant, soil or water) increase or decrease the level of pollutants. By analyzing a dataset consisting of more than four-year monthly samplings from Pond 1 (first pond in the system) and Pond 3 (last pond in the system), we found that the pond system has reduced total suspended solids (TSS) but only when elevated inputs occur. Dissolved oxygen (DO) is closely related to temperature and macrophytes growth; whereas acidity (pH), total nitrogen (TN), and total phosphorus (TP) did not show retention in the early stages of the system development. This system reaches its optimum for reducing TSS at the second pond, but the third pond has important effects on DO, pH, TN and TP. A monitoring in 2017 shows this pond system significantly reduces TSS while increasing dissolved oxygen and neutralizing pH after a storm event; although greater variations incurred within the system as time progresses after storm, overall retention function remained valid. Retention of the pollutants is primarily accomplished by the settling process, which occurs in stilled waterbody of the ponds and by the filtration of macrophytes. We

  20. Discussing implications of fast depleting rural ponds on the globally threatened wetland winter migratory bird in Haryana: a Case Study of Nigdu village pond in Karnal District

    Directory of Open Access Journals (Sweden)

    Rohtash Chand Gupta

    2013-05-01

    Full Text Available The Nigdu-Sarovar is located in Nilokheri block in Karnal district in Haryana (29°50′N 76°55′E. The duration of observations span over seven years (September, 2005 to March, 2012. The recording of wetland winter visitor birds during 2005-08 in winter season included atleast 58 species of birds belonging to 10 orders and 18 families. It is important to mention that 29 species of wetland birds were winter migratory, 17 residents, 9 local migratory and three species of wetland birds like Lesser-whistling Duck Dendrocygna javanica, Pheasant-tailed Jacana Hydrophasianus chirurgus and Blue-cheeked Bee-eater Merops persicus were summer migratory. The special features of 2005-06 winter was the huge populations of birds like Northern Shoveller Anas clypeata, Northern Pintail Anas acuta, Common Teal Anas crecca, Spot-billed Duck Anas poecilorhynchus, Common Pochard Aythya ferina, Bar-headed Goose Anser indicus, Greylag Goose Anser anser, Gadwall Anas strepera, Great Cormorant Phalacrocorax carbo, Mallard Anas platyrhynchos and Common Redshank Tringa totanus etc.In successive years, the scenario was more or less a substantial one depicting stability with respect to diversity of birds, number of birds upto the year of 2008. The popular birds included Painted Stork Mycteria leucocephala, Openbill Stork Anastomus oscitans, White-necked Stork Ciconia episcopus, Black-necked Stork Ephippiorhynchus asiaticus, Eurasian Spoonbill Platalea leucorodia, Spotted Greenshank Tringa guttifer and Kentish Plover Charadrius alexandrines. The sharp decline in winter migratory birds at “Nigdu-Sarovar” started in the year of 2008 when the pond was leased out for FISH-FARMING as per the policies of Govt. of Haryana. Fish Farming based deepening of the pond by excavation of bottom resulting in total decimation of rooted, floating, submerged and ejecting plants along with its subsidiary fauna, Zooplanktons, phytoplankton etc. The age old structural regime of the pond

  1. Convergent Diversity and Trait Composition in Temporary Streams and Ponds

    Science.gov (United States)

    2016-05-19

    ilarities ( PERMANOVA , Adonis function) test on the traits × site matrix. Adonis can be used to test for similar means (centroids) of groups. A...al. 2006). Third, we tested for differences in mean trait distanc- es using PERMANOVA (adonis function) on the distance matrices ran with 999...P = 0.001; ponds: P = 0.015). Mean taxonomic dissimilarities showed significant differences between ponds and streams ( PERMANOVA : R2 = 0.40, P

  2. Homestead fish pond and the environment in Nigeria

    OpenAIRE

    Okaeme, A.N.

    1999-01-01

    Homestead fish culture is a recent innovation for mass production of fish at backyard in Nigeria. The processes of pond construction often have resulted in soil disturbances, vegetation losses, and creation of new aquatic environment. The paper discusses homestead ponds in Nigeria, their potential impact on the environment which includes erosion, over flooding, pest and disease, accident risk, undesired fossil fuel production, vegetation destruction and fish genetic conservation, strategies f...

  3. Seasonal dynamics of fish assemblage in a pond canal

    Czech Academy of Sciences Publication Activity Database

    Musil, J.; Adámek, Zdeněk; Baranyi, Ch.

    2007-01-01

    Roč. 15, č. 3-4 (2007), s. 217-226 ISSN 0967-6120. [New Challenges in Pond Aquaculture. České Budějovice, 26.04.2005-28.04.2005] Institutional research plan: CEZ:AV0Z60930519 Keywords : fish assemblage * pond canal * species richness * seasonal dynamics * alien species Subject RIV: GL - Fishing Impact factor: 0.828, year: 2007

  4. Seasonality of dipteran-mediated methylmercury flux from ponds.

    Science.gov (United States)

    Chumchal, Matthew M; Drenner, Ray W; Hall, MacGregor N; Polk, D Kirkland; Williams, Edward B; Ortega-Rodriguez, Celeste L; Kennedy, James H

    2018-03-12

    Methylmercury (MeHg) is an aquatic contaminant that can be transferred to terrestrial predators by emergent aquatic insects. We assessed the effects of month and pond permanence on dipteran-mediated MeHg flux (calculated as emergent dipteran biomass × dipteran MeHg concentration) in 10 experimental ponds. Emergent dipterans were collected weekly from permanent ponds with bluegill (Lepomis macrochirus; n = 5) and semipermanent ponds without fish (n = 5) over a 7-mo period (February-August, 2015). We detected a significant effect of month on MeHg flux from 6 dipteran taxa and aggregate MeHg flux, with the highest MeHg flux from herbivorous/detritivorous chironomid midges and predatory midges in March; biting midges, phantom midges and herbivorous/detritivorous orthoclad midges in April; and mosquitoes in August. Aggregate dipteran-mediated MeHg flux peaked in April and then declined throughout the remainder of the summer. We did not detect a significant main effect of pond permanence or a significant month × pond permanence interaction effect on MeHg flux for any of the taxa examined in the present study or for aggregate MeHg flux. Given their ubiquity in aquatic systems and their importance in food webs at the land-water interface, dipterans are important taxa that should not be overlooked as a part of the Hg cycle. Environ Toxicol Chem 2018;9999:1-6. © 2018 SETAC. © 2018 SETAC.

  5. Distribution of transuranic elements in a freshwater pond ecosystem

    International Nuclear Information System (INIS)

    Emery, R.M.; Klopfer, D.C.

    1975-05-01

    Preliminary results are reported from a study initiated on the Hanford Reservation concerning the ecological behavior of 238 Pu, 239 Pu, 240 Pu, and 241 Am in a freshwater environment. This study involves a waste pond which has been receiving Pu processing wastes for about 30 years. The pond has a sufficiently established ecosystem to provide an excellent location for limnological characterization. In addition, the ecological distribution of Pu and Am was investigated. The pond is also highly enriched with nutrients, thus supporting a high level of algal and macrophyte production. Seston (30 percent diatoms) appears to be the principal concentrators of Pu transuranics in the pond system. The major sink for Pu and Am in this system is the sediments. Organic floc, overlaying the pond sediments, is also a major concentrator of transuranics in this system []Aside from the seston and floc, no other ecological components of the pond appear to have concentrations significantly greater than those of the sediment. Dragonfly, larvae, watercress, and snails show concentrations which approximate those of the sediments but nearly all other food web components have levels of Pu and Am which are lower than those of the sediments, thus, Pu and Am seem to be relatively immobile in the aquatic ecosystem. (CH)

  6. Enhancing Ecoefficiency in Shrimp Farming through Interconnected Ponds

    Directory of Open Access Journals (Sweden)

    Ramón Héctor Barraza-Guardado

    2015-01-01

    Full Text Available The future development of shrimp farming needs to improve its ecoefficiency. The purpose of this study was to evaluate water quality, flows, and nitrogen balance and production parameters on a farm with interconnected pond design to improve the efficiency of the semi-intensive culture of Litopenaeus vannamei ponds. The study was conducted in 21 commercial culture ponds during 180 days at densities of 30–35 ind m−2 and daily water exchange <2%. Our study provides evidence that by interconnecting ponds nutrient recycling is favored by promoting the growth of primary producers of the pond as chlorophyll a. Based on the mass balance and flow of nutrients this culture system reduces the flow of solid, particulate organic matter, and nitrogen compounds to the environment and significantly increases the efficiency of water (5 to 6.5 m3 kg−1 cycle−1, when compared with traditional culture systems. With this culture system it is possible to recover up to 34% of the total nitrogen entering the system, with production in excess of 4,000 kg ha−1 shrimp. We believe that the production system with interconnected ponds is a technically feasible model to improve ecoefficiency production of shrimp farming.

  7. Continuous Hydrologic and Water Quality Monitoring of Vernal Ponds.

    Science.gov (United States)

    Mina, Odette; Gall, Heather E; Chandler, Joseph W; Harper, Jeremy; Taylor, Malcolm

    2017-11-13

    Vernal ponds, also referred to as vernal pools, provide critical ecosystem services and habitat for a variety of threatened and endangered species. However, they are vulnerable parts of the landscapes that are often poorly understood and understudied. Land use and management practices, as well as climate change are thought to be a contribution to the global amphibian decline. However, more research is needed to understand the extent of these impacts. Here, we present methodology for characterizing a vernal pond's morphology and detail a monitoring station that can be used to collect water quantity and quality data over the duration of a vernal pond's hydroperiod. We provide methodology for how to conduct field surveys to characterize the morphology and develop stage-storage curves for a vernal pond. Additionally, we provide methodology for monitoring the water level, temperature, pH, oxidation-reduction potential, dissolved oxygen, and electrical conductivity of water in a vernal pond, as well as monitoring rainfall data. This information can be used to better quantify the ecosystem services that vernal ponds provide and the impacts of anthropogenic activities on their ability to provide these services.

  8. Modeling a ponded infiltration experiment at Yucca Mountain, NV

    International Nuclear Information System (INIS)

    Hudson, D.B.; Guertal, W.R.; Flint, A.L.

    1994-01-01

    Yucca Mountain, Nevada is being evaluated as a potential site for a geologic repository for high level radioactive waste. As part of the site characterization activities at Yucca Mountain, a field-scale ponded infiltration experiment was done to help characterize the hydraulic and infiltration properties of a layered dessert alluvium deposit. Calcium carbonate accumulation and cementation, heterogeneous layered profiles, high evapotranspiration, low precipitation, and rocky soil make the surface difficult to characterize.The effects of the strong morphological horizonation on the infiltration processes, the suitability of measured hydraulic properties, and the usefulness of ponded infiltration experiments in site characterization work were of interest. One-dimensional and two-dimensional radial flow numerical models were used to help interpret the results of the ponding experiment. The objective of this study was to evaluate the results of a ponded infiltration experiment done around borehole UE25 UZN number-sign 85 (N85) at Yucca Mountain, NV. The effects of morphological horizons on the infiltration processes, lateral flow, and measured soil hydaulic properties were studied. The evaluation was done by numerically modeling the results of a field ponded infiltration experiment. A comparison the experimental results and the modeled results was used to qualitatively indicate the degree to which infiltration processes and the hydaulic properties are understood. Results of the field characterization, soil characterization, borehole geophysics, and the ponding experiment are presented in a companion paper

  9. 2101-M pond closure plan. Volume 1, Revision 2

    Energy Technology Data Exchange (ETDEWEB)

    Izatt, R. D.; Lerch, R. E.

    1993-06-01

    This document describes activities for the closure of a surface impoundment (2101-M Pond) at the Hanford Site. The 2101-H Pond was initially constructed in 1953 to serve as a drainage collection area for the 2101-H Building. (Until the Basalt Waste Isolation Project (BWIP) Laboratory was constructed in the 2101-M Building in 1979--1981, the only source contributing discharge to the pond was condensate water from the 2101-H Building heating, ventilation, and air conditioning (HVAC) system. The drains for the BWIP Laboratory rooms were plumbed into a 4-in., cast-iron, low-pressure drain pipe that carries waste water from the HVAC system to the pond. During the active life of the BWIP Laboratory, solutions of dissolved barium in groundwater samples were discharged to the 2101-M Pond via the laboratory drains. As a result of the discharges, a Part A permit application was initially submitted to the Washington State Department of Ecology (Ecology) in August 1986 which designates the 2101-M Pond as a surface impoundment.

  10. Sediment remediation of the Hespeler Mill Pond, Cambridge, Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Angeloni, D.; Eby, M.; Jarvis, S.; Martin, P. [Univ. of Guelph, School of Engineering, Guelph, Ontario (Canada)]. E-mail: danielle.angeloni@earthtech.ca

    2002-06-15

    'Full text:' Low dissolved oxygen levels and large accumulated sediment remediation alternatives were examined to assemble the Hespeler Mill Pond, Cambridge (HMP) into a healthier and more desirable recreational area in the City of Cambridge. The theory that a large amount of sediment has been deposited into the HMP from the Speed River upstream over a number of years predicts the depressed oxygen levels, high nutrient-loading rates and the odour problems in the summer months. The initial phase in the remediation plan for this project involved extensive background research and investigation. The focus was on determining the characteristics of the sediment and the history of the pond, to ultimately decide if the sediment was the source of the issues. Dissolved oxygen field tests and sediment sampling were conducted to get information on the magnitude of the problem and the environmental hazards potentially present in the pond. The pond was modelled utilising the Streeter-Phelps oxygen-sag model to predict the oxygen deficit. Biochemical Oxygen Demand (BOD{sub 5}) testing was completed to determine the oxygen demand in the pond. These tests were conducted by using water samples obtained from various sample points at the pond. The proposed solution is a combined dredging and aeration approach. Mechanical dredging using a clamshell bucket and the installation of aerators is expected to solve the dissolved oxygen and water quality issues. (author)

  11. Integrated oil sands tailings pond water treatment

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Z. [Saskatchewan Research Council, Saskatoon, SK (Canada)

    2010-07-01

    This PowerPoint presentation discussed research currently being conducted to treat oil sands tailings pond water (TPW). The treatment of TPW is challenged by the high level of naphthenic acids (NAs), the slow settling rate of fine particulate materials, and the complex chemistry of the water. The treatment process consisted of bioflocculation, sludge blanket assisted clarification, ozonation, and oil sands coke assisted hybrid biodegradation. The aggregation and adsorption process bound small particles and cells together while also ensuring the passive uptake of pollutants using microbial masses. The mixed liquor then passed through a sludge blanket to ensure enhanced particle capture. An ozonation process was used to increase the biodegradability of the TPW as well as to increase the biodegradability of the residual NAs after ozonation. The process used a hybrid bioreactor that consisted of both suspended and fixed microbial communities. The coke served as a biofilm carrier for the waste. Further studies are being conducted to investigate the efficiency and capability of the process. tabs., figs.

  12. Lowering resistance of the Hoyle Pond Mine

    Energy Technology Data Exchange (ETDEWEB)

    Desjardins, M. [Goldcorp Canada Ltd., Porcupine Gold Mines, Hoyle Pond Mine, Timmins, ON (Canada)

    2010-07-01

    The Hoyle Pond underground mine is located in the Porcupine Gold Camp, east of Timmins, Ontario. Various mining methods are used to excavate the gold, each with different ventilation requirements in terms of layout and volume. The mine was originally designed as a shallow mine but is planning to reach a depth of 2500 m. This paper described the events that lead to the high system pressures encountered at the mine, and the measures taken to reduce them. New surface fans and a new fresh air raise (FAR) were commissioned in 2005. The old FAR had to be sealed as soon as the new fans were in place in order to prevent short-circuiting. As a result, the mine resistance curve steepened considerably. The total pressure at the fan increased from 1500 Pa to 3000 Pa. As such, only 1 surface fan could operate at any give time, providing only half the possible volume of air. The challenge was to reduce the mine's resistance while getting the desired volume of air down to to the mining faces at depth. The solutions were to install booster fans and initiate a raise-bore program that would link the 450 m level to 900 m level. These measures twinned the existing fresh air circuit and resulted in a lowering of the overall mine resistance curve. 1 ref., 9 figs.

  13. Analysis of Geological, Mechanical and Characteristics of Aggregates Used in Tailings Ponds

    Directory of Open Access Journals (Sweden)

    G. Ertugrul

    2017-01-01

    Full Text Available Increasing social demand, economic developments, consumption fluctuations, urbanization, industrialization, modernization, population growth and technical needs have resulted due toincrease in the production of natural resources throughout the world. However, there is a less importance focused on the environmental regulations. Waste water is one of the environmental problemsthatmining activities may cause. It contains a lot of solid and liquid contaminants.Aggregatesare found among the most abundant ones in natural resources. They are obtained from river basins, sea and lake edges, quarries and industries as by products and waste. During mining activities or terminated mining activities, these materials are used in the creation of stability, impermeability and settlement of tailings dam. In this paper, construction of tailings pond by using aggregates are given in detail together with their classification, particle stability, particle shape, particle size, particle texture, covered in minerals of particle, particle porosity and trending to chemical reactivity of aggregates.

  14. Solar Indices - Solar Flares

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Collection includes a variety of indices related to solar activity contributed by a number of national and private solar observatories located worldwide. This...

  15. Solar Indices - Solar Ultraviolet

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Collection includes a variety of indices related to solar activity contributed by a number of national and private solar observatories located worldwide. This...

  16. Solar Indices - Solar Corona

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Collection includes a variety of indices related to solar activity contributed by a number of national and private solar observatories located worldwide. This...

  17. Solar Indices - Solar Irradiance

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Collection includes a variety of indices related to solar activity contributed by a number of national and private solar observatories located worldwide. This...

  18. Advancement in solar evaporation techniques for volume reduction of chemical effluents

    Energy Technology Data Exchange (ETDEWEB)

    Parakasamurthy, K S [Nuclear Fuel Complex, Hyderabad (India); Pande, D P [Process Engineering and Systems Development Division, Bhabha Atomic Research Centre, Mumbai (India)

    1994-06-01

    A typical example of advancement of a unit operation for the given requirement is described. The solar evaporation ponds (SEP) have technical and economic advantages compared to other evaporation methods for concentrating chemical effluents. The operation of SEP is strongly dependent on the environmental and site conditions. Tropical conditions with high solar incidence, good wind speed along with hot and dry weather provide suitable climate for efficient operation of solar evaporation ponds. The particular site selected for the ponds at Nuclear Fuel Complex (NFC) has a rocky terrain with murrum over sheet with very low water table and small velocity of groundwater. During the past twenty five years extensive theoretical and experimental investigations have been carried out for advancement of solar evaporation technique. (author). 7 refs.

  19. Advancement in solar evaporation techniques for volume reduction of chemical effluents

    International Nuclear Information System (INIS)

    Parakasamurthy, K.S.; Pande, D.P.

    1994-01-01

    A typical example of advancement of a unit operation for the given requirement is described. The solar evaporation ponds (SEP) have technical and economic advantages compared to other evaporation methods for concentrating chemical effluents. The operation of SEP is strongly dependent on the environmental and site conditions. Tropical conditions with high solar incidence, good wind speed along with hot and dry weather provide suitable climate for efficient operation of solar evaporation ponds. The particular site selected for the ponds at Nuclear Fuel Complex (NFC) has a rocky terrain with murrum over sheet with very low water table and small velocity of groundwater. During the past twenty five years extensive theoretical and experimental investigations have been carried out for advancement of solar evaporation technique. (author)

  20. Pond-aquifer flow and water availability in the vicinity of two coastal area seepage ponds, Glynn and Bulloch Counties, Georgia

    Science.gov (United States)

    Clarke, John S.; Rumman, Malek Abu

    2005-01-01

    Pond-aquifer flow and water availability at excavated seepage pond sites in Glynn County and in southern Bulloch County, Georgia, were evaluated to determine their potential as sources of water supply for irrigation. Excavated seepage ponds derive water primarily from ground water seeping into the pond, in a manner similar to a dug well completed in a surficial aquifer. The availability of water from seepage ponds is controlled by the permeability of surficial deposits, the amount of precipitation recharging the ground-water system, and the volume of water stored in the pond. The viability of seepage ponds as supplies for irrigation is limited by low seepage rates and high dependence on climatic conditions. Ponds will not refill unless there is adequate precipitation to recharge the surficial aquifer, which subsequently drains (seeps) into the pond. Ground-water seepage was estimated using a water-budget approach that utilized on-site climatic and hydrologic measurements, computing pond-volume changes during pond pumping tests, and by digital simulation using steady-state and transient ground-water flow models. From August 1999 to May 2000, the Glynn County pond was mostly losing water (as indicated by negative net seepage); whereas from October 2000 to June 2001, the Bulloch County pond was mostly gaining water. At both sites, most ground-water seepage entered the pond following major rainfall events that provided recharge to the surficial aquifer. Net ground-water seepage, estimated using water-budget analysis and simulation, ranged from -11.5 to 15 gallons per minute (gal/min) at the Glynn County pond site and from -55 to 31 gal/min at the Bulloch County pond site. Simulated values during pumping tests indicate that groundwater seepage to both ponds increases with decreased pond stage. At the Glynn County pond, simulated net ground-water seepage varied between 7.8 gal/min at the beginning of the test (high pond stage and low hydraulic gradient) and 103 gal

  1. Spatial modeling of limnological parameters in a solar saltwork of northeastern Brazil

    Directory of Open Access Journals (Sweden)

    Diógenes Félix da Silva Costa

    2015-03-01

    Full Text Available AimIn this research, we aimed to model limnological parameters in the Salina Unidos (Macau-Brazil using GIS technology. We hypothesized that in solar saltworks, the geochemical characteristics of the brines (i.e. the strong solution of salts vary considerably through the salt ponds circuit, in which drastic changes can damage the entire salt production.MethodsGeochemical parameters were monitored in seven sampling points distributed along the salt ponds circuit, during a complete cycle of salt production, i.e., from January to December 2007. The open source software Spring 5.1.6 was used to build, store, analyze and model the spatial distribution of the parameters.ResultsWe identified a spatial gradient of the salinity and temperature, with values increasing from evaporation ponds to concentration ponds, showing a relationship with the salt production. The parameters, depth, dissolved oxygen concentrations and total dissolved reactive phosphorus showed a decrease from the evaporation ponds towards the concentration ponds. Among the dissolved inorganic nitrogen forms analyzed (NH3-, NO2- and NO3-, nitrate was the predominant, namely in the concentration ponds, where it reached the highest concentrations. The concentration of chlorophyll awas higher in the initial and intermediate evaporation ponds, showing a distinct dynamics of in relation to other environmental variables.ConclusionsThe increased concentration of the analyzed limnological parameters, from the evaporation ponds towards the concentration ponds, evidenced a heterogeneous distribution varying significantly with season. The geochemical spatialization of brine, as illustrated by GIS approach, is very important for the conservation of these environments because this spatial heterogeneity can provide a high diversity of habitat types. This spatial analysis proved to be a practical tool for an adequate management of solar saltworks considering the environmental (ecosystem and the socio

  2. Thermal effects on cavity stability of chromium- and neodymium-doped gadolinium scandium gallium garnet laser under solar-simulator pumping

    Science.gov (United States)

    Kim, Kyong H.; Venable, Demetrius D.; Brown, Lamarr A.; Lee, Ja H.

    1991-01-01

    Results are presented on testing a Cr- and Nd-codoped Gd-Sc-Ga-garnet (Cr:Nd:GSGG) crystal and a Nd:YAG crystal (both of 3.2 mm diam and 76-mm long) for pulsed and CW laser operations using a flashlamp and solar simulator as pumping sources. Results from experiments with the flashlamp show that, at pulse lengths of 0.11, 0.28, and 0.90 ms, the slope efficiency of the Cd:Nd:GSGG crystal was higher than that of the Nd:YAG crystal and increased with pulse width. With the solar simulator, however, the CW laser operation of the Cr:Nd:GSGG crystal was limited to intensities not greater than 1500 solar constants, while the Nd:YAG laser successfully performed for all pump beam intensities available. It was found that the exposure for several minutes of the Cr:Nd:GSGG crystal to pump beam intensity of 3000 solar constants led to its damage by thermal cracking, indicating that a better solar-pumped CW laser performance may be difficult to realize with rod geometry.

  3. Evaluation of relocation of unionid mussels into artificial ponds

    Science.gov (United States)

    Newton, T.J.; Monroe, E.M.; Kenyon, R.; Gutreuter, S.; Welke, K.I.; Thiel, P.A.

    2001-01-01

    Relocation of unionid mussels into refuges (e.g., hatchery ponds) has been suggested as a management tool to protect these animals from the threat of zebra mussel (Dreissena polymorpha) invasion. To evaluate the efficacy of relocation, we experimentally relocated 768 mussels, representing 5 species (Leptodea fragilis, Obliquaria reflexa, Fusconaia flava, Amblema plicata, and Quadrula quadrula) into an earthen pond at a National Fish Hatchery or back into the river. In both locations, mussels were placed into 1 of 4 treatments (mesh bags, corrals, and buried or suspended substrate-filled trays). Mussels were examined annually for survival, growth (shell length and wet mass), and physiological condition (glycogen concentration in foot and mantle and tissue condition index) for 36 mo in the pond or 40 mo in the river. We observed significant differences in mortality rates between locations (mortality was 4 times greater in the pond than in the river), among treatments (lowest mortality in the suspended trays), and among species (lower mortality in the amblemines than lamp-silines). Overall survival in both locations averaged 80% the 1st year; survival in the pond decreased dramatically after that. Although length and weight varied between locations and over time, these changes were small, suggesting that their utility as short-term measures of well being in long-lived unionids is questionable. Mussels relocated to the pond were in poor physiological condition relative to those in the river, but the magnitude of these differences was small compared to the inherent variability in physiological condition of reference mussels. These data suggest that relocation of unionids into artificial ponds is a high-risk conservation strategy; alternatives such as introduction of infected host fish, identification of mussel beds at greatest risk from zebra mussels, and a critical, large-scale assessment of the factors contributing to their decline should be explored.

  4. Par Pond vegetation status Summer 1995 -- June survey descriptive summary

    International Nuclear Information System (INIS)

    Mackey, H.E. Jr.; Riley, R.S.

    1995-06-01

    The water level of Par Pond was lowered approximately 20 feet in mid-1991 in order to protect downstream residents from possible dam failure suggested by subsidence on the downstream slope of the dam and to repair the dam. This lowering exposed both emergent and nonemergent macrophyte beds to drying conditions resulting in extensive losses. A survey of the shoreline aquatic plant communities in June 1995, three months after the refilling of Par Pond to approximately 200 feet above mean sea level, indicated that much of the original plant communities and the intermediate shoreline communities present on the exposed sediments have been lost. The extensive old-field and emergent marsh communities that were present on the exposed shoreline during the drawdown have been flooded and much of the pre-drawdown Par Pond aquatic plant communities have not had sufficient time for re-establishment. The shoreline does, however, have extensive beds of maidencane which extend from the shoreline margin to areas as deep as 2 and perhaps 3 meters. Scattered individual plants of lotus and watershield are common and may indicate likely directions of future wetland development in Par Pond. In addition, within isolated coves, which apparently received ground water seepage and/or stream surface flows during the period of the Par Pond draw down, extensive beds of waterlilies and spike rush are common. Invasion of willow and red maple occurred along the lake shoreline as well. Although not absent from this survey, evidence of the extensive redevelopment of the large cattail and eel grass beds was not observed in this first survey of Par Pond. Future surveys during the growing seasons of 1995, 1996, and 1997 along with the evaluation of satellite date to map the areal extent of the macrophyte beds of Par Pond are planned

  5. Distribution of transuranic elements in a freshwater pond ecosystem

    International Nuclear Information System (INIS)

    Emery, R.M.; Klopfer, D.C.

    1976-01-01

    During the past two years a unique study has been initiated on the Hanford Reservation concerning the ecological behavior of plutonium and americium in a freshwater environment. This study involves a waste pond which has been receiving occasional low-level plutonium processing wastes for about 30 years. The pond has a sufficiently established ecosystem to provide an excellent location for limnological characterization. In addition, the ecological distribution of plutonium and americium is being investigated. The purpose of this work is to explain plutonium and americium concentrations at specific ecological sites, important export routes out of the pond, and potential pathways to man. The pond is also highly enriched with nutrients, thus supporting a high level of algal and macrophyte production. Seston (30 percent diatoms) appears to be the principal concentrator of transuranics in the pond system. The major sink for plutonium and americium in this system is the sediments. Organic floc, overlaying the pond sediments, is also a major concentrator of transuranics in this system. Aside from the seston and floc, no other ecological components of the pond appear to have concentrations significantly greater than those of the sediment. Dragonfly larvae, watercress, and snails show concentrations which approximate those of the sediments but nearly all other food web components have levels of plutonium and americium which are lower than those of the sediments. Thus, plutonium and americium seem to be relatively immobile in the aquatic ecosystem. However, the role of algae as a potential mechanism for the long-range ecological transport of plutonium and americium will receive additional attention

  6. Arctic sea ice melt pond fractal dimension - explained

    Science.gov (United States)

    Popovic, Predrag

    As Arctic sea ice starts to melt in the summer, pools of melt water quickly form on its surface, significantly changing its albedo, and impacting its subsequent evolution. These melt ponds often form complex geometric shapes. One characteristic of their shape, the fractal dimension of the pond boundaries, D, when plotted as a function of pond size, has been shown to transition between the two fundamental limits of D = 1 and D = 2 at some critical pond size. Here, we provide an explanation for this behavior. First, using aerial photographs, we show how this fractal transition curve changes with time, and show that there is a qualitative difference in the pond shape as ice transitions from impermeable to permeable. Namely, while ice is impermeable, maximum fractal dimension is less than 2, whereas after it becomes permeable, maximum fractal dimension becomes very close to 2. We then show how the fractal dimension of a collection of overlapping circles placed randomly on a plane also transitions from D = 1 to D = 2 at a size equal to the average size of a single circle. We, therefore, conclude that this transition is a simple geometric consequence of regular shapes connecting. The one physical parameter that can be extracted from the fractal transition curve is the length scale at which transition occurs. We provide a possible explanation for this length scale by noting that the flexural wavelength of the ice poses a fundamental limit on the size of melt ponds on permeable ice. If this is true, melt ponds could be used as a proxy for ice thickness.

  7. Polycyclic aromatic hydrocarbon contamination in stormwater detention pond sediments in coastal South Carolina.

    Science.gov (United States)

    Weinstein, John E; Crawford, Kevin D; Garner, Thomas R

    2010-03-01

    The purpose of this study was to characterize the polycyclic aromatic hydrocarbon (PAH) contamination in the sediments of stormwater detention ponds in coastal South Carolina. Levels of the sum of PAH analytes were significantly higher in the sediments of commercial ponds compared to that of reference, golf course, low-density residential, and high-density residential ponds. Isomer ratio analysis suggested that the predominant source of PAHs were pyrogenic; however, many ponds had a PAH signature consistent with mixed uncombusted and combusted PAH sources. PAH levels in these sediments could be modeled using both pond drainage area and pond surface area. These results demonstrate that the sediment from most commercial ponds, and a few residential and golf course ponds, were moderately contaminated with PAHs. PAH levels in these contaminated ponds exceeded between 42% and 75% of the ecological screening values for individual PAH analytes established by US EPA Region IV, suggesting that they may pose a toxicological risk to wildlife.

  8. The laboratory environmental algae pond simulator (LEAPS) photobioreactor: Validation using outdoor pond cultures of Chlorella sorokiniana and Nannochloropsis salina

    Energy Technology Data Exchange (ETDEWEB)

    Huesemann, M.; Williams, P.; Edmundson, S.; Chen, P.; Kruk, R.; Cullinan, V.; Crowe, B.; Lundquist, T.

    2017-09-01

    A bench-scale photobioreactor system, termed Laboratory Environmental Algae Pond Simulator (LEAPS), was designed and constructed to simulate outdoor pond cultivation for a wide range of geographical locations and seasons. The LEAPS consists of six well-mixed glass column photobioreactors sparged with CO2-enriched air to maintain a set-point pH, illuminated from above by a programmable multicolor LED lighting (0 to 2,500 µmol/m2-sec), and submerged in a temperature controlled water-bath (-2 °C to >60 °C). Measured incident light intensities and water temperatures deviated from the respective light and temperature set-points on average only 2.3% and 0.9%, demonstrating accurate simulation of light and temperature conditions measured in outdoor ponds. In order to determine whether microalgae strains cultured in the LEAPS exhibit the same linear phase biomass productivity as in outdoor ponds, Chlorella sorokiniana and Nannochloropsis salina were cultured in the LEAPS bioreactors using light and temperature scripts measured previously in the respective outdoor pond studies. For Chlorella sorokiniana, the summer season biomass productivity in the LEAPS was 6.6% and 11.3% lower than in the respective outdoor ponds in Rimrock, Arizona, and Delhi, California; however, these differences were not statistically significant. For Nannochloropsis salina, the winter season biomass productivity in the LEAPS was statistically significantly higher (15.2%) during the 27 day experimental period than in the respective outdoor ponds in Tucson, Arizona. However, when considering only the first 14 days, the LEAPS biomass productivity was only 9.2% higher than in the outdoor ponds, a difference shown to be not statistically significant. Potential reasons for the positive or negative divergence in LEAPS performance, relative to outdoor ponds, are discussed. To demonstrate the utility of the LEAPS in predicting productivity, two other strains – Scenedesmus obliquus and Stichococcus minor

  9. Photochemical stability of conjugated polymers, electron acceptors and blends for polymer solar cells resolved in terms of film thickness and absorbance

    DEFF Research Database (Denmark)

    Tromholt, Thomas; Vesterager Madsen, Morten; Carlé, Jon Eggert

    2012-01-01

    Photochemical degradation at 1 sun under AM1.5G illumination was performed on six conjugated polymers and five different electron acceptors. Additionally, the respective polymer:PC60BM and P3HT:electron acceptor blends were studied, and all degradations were resolved in terms of film thickness...... within each material group were found to vary for both the pure polymers and the blends. The stability ranking between the materials of the pure polymers was found to be similar to the ranking for their respective blends, implying that the photochemical stability of a pure polymer is a good measure...... of its associated blend stability. Different electron acceptors were found to stabilize P3HT decreasingly with decreasing donor–acceptor LUMO–LUMO gap. Destabilization of P3HT was observed in the case of the electron acceptor ICBA. Additionally, the decreased stabilization of P3HT by high LUMO electron...

  10. Microstructure and thermal stability of Cu/Zr0.3Al0.7N/Zr0.2Al0.8N/Al34O60N6 cermet-based solar selective absorbing coatings

    Science.gov (United States)

    Meng, Jian-ping; Guo, Rui-rui; Li, Hu; Zhao, Lu-ming; Liu, Xiao-peng; Li, Zhou

    2018-05-01

    Solar selective absorbing coatings play a valuable role in photo-thermal conversion for high efficiency concentrating solar power systems (CSP). In this paper, a novel Cu/Zr0.3Al0.7N/Zr0.2Al0.8N/Al34O60N6 cermet-based solar selective absorbing coating was successfully deposited by ion beam assisted deposition. The optical properties, microstructure and element distribution in depth were investigated by spectroscopic ellipsometry, UV-vis-NIR spectrophotometer, transmission electron microscope (TEM) and Auger electron spectroscopy (AES), respectively. A high absorptance of 0.953 and a low thermal emittance of 0.079 at 400 °C are obtained by the integral computation according to the whole reflectance from 300 nm to 28,800 nm. After annealing treatment at 400 °C (in vacuum) for 192 h, the deposited coating exhibits the high thermal stability. Whereas, the photothermal conversion efficiency decreases from 12.10 to 6.86 due to the emittance increase after annealing at 600 °C for 192 h. Meanwhile, the nitrogen atom in the Zr0.3Al0.7N sub-layer diffuses toward the adjacent sub-layer due to the spinodal decomposition of metastable c-ZrAlN and the phase transition from c-AlN to h-AlN, which leads to the composition of the Zr0.3Al0.7N sub-layer deviates the initial design. This phenomenon has a guide effect for the thermal-stability improvement of cermet coatings. Additionally, a serious diffusion between copper and silicon substrate also contributes to the emittance increase.

  11. Influences of radiation on carp from farm ponds in Fukushima

    International Nuclear Information System (INIS)

    Suzuki, Yuzuru

    2015-01-01

    A massive release of artificial radionuclides from the Fukushima Dai-ichi Nuclear Power Plant caused radioactive contamination of farms as well as of aquatic products. Carp in small ponds in the highly radiocontaminated area of Iitate Village, Fukushima Prefecture, have been confined to the ponds since the accident, and it is thought that the carp may have suffered health issues as a result. Therefore, I investigated the health condition of the carp in order to elucidate the effects of radiation. Blood neutrophil, monocyte and lymphocyte counts in the carp from three ponds in Fukushima were lower than those in carp from a non-polluted pond in Tochigi Prefecture. Histological observations indicated abnormal hyperplasia of macrophages in the spleen, kidney, liver and pancreas of carp in Fukushima. Although there are likely to have been deleterious effects on carp health due to the radiation in Fukushima, this has not yet been confirmed because only one control pond was available for comparison, and I was not able to find any symptoms in the carp that correlated with internal cesium concentration. Further research is now being conducted to investigate the effects of radiation on carp

  12. PRACTICAL SOLUTIONS FOR ECOLOGICAL RECONSTRUCTION OF GERAI POND

    Directory of Open Access Journals (Sweden)

    Alexandru Dimache

    2012-06-01

    Full Text Available Gerai Pond is one of the last natural wetlands along the Danube, being connected to natural flooding regime of the Danube and is situated at the confluence of the Danube River, between Gârcov and Islaz localities, in Olt County. Aquatic vegetation characteristic is a favorable habitat for two species of conservation concern that nest along the Danube: red duck and pygmy cormorant. During 1961-1970, Gerai Pond has changed radically due to impoundment and draining under the program of drainage and flood meadow regulate of the Danube. These works of land reclamation for decreasing surface lakes and wetlands and water stagnation period, had reduced the breeding areas of the two species mentioned above. Ecological reconstruction of Gerai Pond project was conducted by Technical University of Civil Engineering of Bucharest in collaboration with E.P.A. Olt and W.W.F.-Romania. The project was based on a hydrological study (which included a component related to flooding for the area analyzed, study in which were highlighted the areas which have water access to and from the Pond, surfaces and volumes of water corresponding to different rates, the optimal level of water for restoration of the nesting area. Based on this study were identified the areas of artificial feed-water discharge to and from the Danube. This paper presents the possible solutions for ecological reconstruction of Gerai Pond, identified in the project.

  13. Par Pond vegetation status Summer 1995 -- September survey descriptive summary

    International Nuclear Information System (INIS)

    Mackey, H.E. Jr.; Riley, R.S.

    1995-09-01

    The water level of Par Pond was lowered approximately 20 feet in mid-1991 in order to protect downstream residents from possible dam failure suggested by subsidence on the downstream slope of the dam and to repair the dam. This lowering exposed both emergent and nonemergent macrophyte beds to drying conditions resulting in extensive losses. A survey of the emergent shoreline aquatic plant communities began in June 1995, three months after the refilling of Par Pond to approximately 200 feet above mean sea level and continued with this mid-September survey. Communities similar to the pre-drawdown Par Pond aquatic plant communities are becoming re-established; especially, beds of maidencane, lotus, waterlily, and watershield are now extensive and well established. Cattail occurrence continues to increase, but large beds common to Par Pond prior to the drawdown have not formed. Future surveys during the late growing seasons of 1995, and throughout 1996 and 1997, along with the evaluation of satellite data to map the areal extent of the macrophyte beds of Par Pond, are planned

  14. Par Pond vegetation status Summer 1995 -- October survey descriptive summary

    International Nuclear Information System (INIS)

    Mackey, H.E. Jr.; Riley, R.S.

    1995-11-01

    The water level of Par Pond was lowered approximately 20 feet in mid-1991 in order to protect downstream residents from possible dam failure suggested by subsidence on the downstream slope of the dam and to repair the dam. This lowering exposed both emergent and nonemergent macrophyte beds to drying conditions resulting in extensive losses. A survey of the emergent shoreline aquatic plant communities began in June 1995, three months after the refilling of Par Pond to approximately 200 feet above mean sea level and continued with this late October survey. Communities similar to the pre-drawdown Par Pond aquatic plant communities are becoming re-established; especially, beds of maiden cane, lotus, waterlily, and watershield are now extensive and well established. Cattail occurrence continues to increase, but large beds common to Par Pond prior to the drawdown have not formed. Future surveys throughout 1996 and 1997, along with the continued evaluation of satellite data to map the areal extent of the macrophyte beds of Par Pond, are planned

  15. Revegetation of flue gas desulfurization sludge pond disposal sites

    International Nuclear Information System (INIS)

    Artiola, J.F.

    1994-12-01

    A comprehensive search of published literature was conducted to summarize research undertaken to date on revegetation of flue gas desulfurization (FGD) waste disposal ponds. A review of the physical and chemical properties of FGD sludges and wastes with similar characteristics is also included in order to determine the advantages and limitations of FGD sludge for plant growth. No specific guidelines have been developed for the revegetation of FGD sludge disposal sites. Survey studies showed that the wide-ranging composition of FGD wastes was determined primarily by the sulfur dioxide and other flue gas scrubbing processes used at powerplants. Sulfate rich (>90%CaSO 4 ) FGD sludges are physically and chemically more stable, and thus more amenable to revegetation. Because of lack of macronutrients and extremely limited microbial activity, FBD sludge ponds presented a poor plant growth environment without amendment. Studies showed the natural process of inoculation of the FGD sludge with soil microbes that promote plant growth be can after disposal but proceeded slowly. Revegetation studies reviewed showed that FGD sludges amended with soils supported a wider variety of plant species better and longer than abandoned FGD ponds. Two major types of plants have been successful in revegetation of FGD waste ponds and similar wastes: salt-tolerant plants and aquatic plants. A comprehensive list of plant species with potential for regetation of FGD sludge disposal pond sites is presented along with successful revegetation techniques

  16. Prediction of local effects of proposed cooling ponds

    International Nuclear Information System (INIS)

    Hicks, B.B.

    1978-01-01

    A Fog Excess Water (FEW) Index has been shown to provide a good measure of the likelihood for steam fog to occur at specific cooling pond installations. The FEW Index is derived from the assumption that the surface boundary layer over a cooling pond will be strongly convective, and that highly efficient vertical transport mechanisms will result in a thorough mixing of air saturated at surface temperature with ambient air aloft. Available data support this assumption. An extension of this approach can be used to derive a simple indicator for use in predicting the formation of rime ice in the immediate downwind environs of a cooling pond. In this case, it is supposed that rime ice will be deposited whenever steam fog and sub-freezing surface temperatures are predicted. This provides a convenient method for interpreting pre-existing meteorological information in order to assess possible icing effects while in the early design stages of the planning process. However, it remains necessary to derive accurate predictions of the cooling pond water surface temperature. Once a suitable and proven procedure for this purpose has been demonstrated, it is then a simple matter to employ the FEW Index in evaluations of the relative merits of alternative cooling pond designs, with the purpose of minimizing overall environmental impact

  17. Thermal performance measurements on ultimate heat sinks--cooling ponds

    International Nuclear Information System (INIS)

    Hadlock, R.K.; Abbey, O.B.

    1977-12-01

    The primary objective of the studies described is to obtain the requisite data, with respect to modeling requirements, to characterize thermal performance of heat sinks for nuclear facilities existing at elevated water temperatures in result of experiencing a genuinely large heat load and responding to meteorological influence. The data should reflect thermal performance for combinations leading to worst-case meteorological influence. A geothermal water retention basin has been chosen as the site for the first measurement program and data have been obtained in the first of several experiments scheduled to be performed there. These data illustrate the thermal and water budgets during episodes of cooling from an initially high pond water bulk temperature. Monitoring proceeded while the pond experienced only meteorological and seepage influence. The data are discussed and are presented as a data volume which may be used for calculation purposes. Suggestions for future measurement programs are stated with the intent to maintain and improve relevance to nuclear ultimate heat sinks while continuing to examine the performance of the analog geothermal pond. It is further suggested that the geothermal pond, with some modification, may be a suitable site for spray pond measurements

  18. Floating Solar Photovoltaics Gaining Ground | State, Local, and Tribal

    Science.gov (United States)

    flotovoltaics (a trademarked term) or floating solar, represent an emerging application in which PV panels are , including efficiency gains (due to water cooling the panels), reductions in unwanted algae growth, slower 994 panels floating on 130 foam-filled pontoons atop the winery's irrigation pond and an additional

  19. Flexible ITO-free organic solar cells applying aqueous solution-processed V2O5 hole transport layer: An outdoor stability study

    DEFF Research Database (Denmark)

    Lima, F. Anderson S.; Beliatis, Michail J.; Roth, Bérenger

    2016-01-01

    Solution processable semiconductor oxides have opened a new paradigm for theenhancement of the lifetime of thin film solar cells. Their fabrication by low-costand environmentally friendly solution-processable methods makes them ideal barrier(hole and electron) transport layers. In this work, we f...

  20. A Robust CuCr2O4/SiO2 Composite Photothermal Material with Underwater Black Property and Extremely High Thermal Stability for Solar-Driven Water Evaporation

    KAUST Repository

    Shi, Yusuf

    2017-12-27

    The design and fabrication of efficient photothermal materials is the key issue in solar-driven water evaporation. In this work, a robust CuCr2O4/SiO2 composite membrane with outstanding solar-driven water evaporation performance (1.32 kg m−2 h−1) under one sun irradiation is rationally designed and synthesized by using quartz glass fibrous membrane as supporting matrix and stable CuCr2O4 particles as the active light absorber. Instead of coating a separate layer on top of the support, the CuCr2O4 particles are evenly distributed inside the matrix, which endows the membrane with great mechanical strength and excellent wear and abrasion resistance. The highly porous composite survives 6 atm pressure and retains its performance even after 75% of the membrane is removed by sandpaper. This work also looks into a generally overlooked aspect of wet versus dry state of photothermal material and its implications. Interestingly, the composite possesses a gray color with a high reflectance in dry state but turns into deep black with a low reflectance in wet state due to the decreased subsurface scattering and strong NIR light absorbance of water in wet state. This composite material also possesses excellent thermal stability and thermal shock resistance, making it able to be easily recovered by calcination in air or direct burning in fire for contaminants removal. The results demonstrate that this composite is a competitive photothermal material for practical solar distillation and indicate that the optical properties of material in wet state are more relevant to photothermal material screening and optimization for solar distillation.