WorldWideScience

Sample records for stabilize world oil

  1. The oil world war

    International Nuclear Information System (INIS)

    Lafargue, F.

    2008-01-01

    Since the beginning of the 21. century, a war has started between the USA, China and India. The USA, first oil consuming and importing country in the world, has now to take into account the increasing energy consumption of China and India. China is now, just behind Japan, the third oil importing country and India ranked number seven. From the Gulf of Guinea to the Arabic peninsula, from the Orenoque basin to the Caspian sea banks, Washington, Beijing and New Delhi covet the same oil fields. This rivalry exacerbates the political tensions in many regions of the Earth and already provokes a latent food crisis. This black gold war is changing the World's face and should provoke serious armed conflicts. (J.S.)

  2. World oil market simulation

    International Nuclear Information System (INIS)

    Baldwin, N.

    1992-01-01

    This paper presents a recursive simulation model of the world oil market - the World Oil Market Simulation Model (WOMS). The objective was to construct a computationally simple model which provides a transparent view of the workings of the oil market. In the event WOMS has a number of features which distinguish it from other published models: the effect of exchange rate movements is incorporated in the supply and demand functions; both demand and supply functions are dynamic; the non-OPEC supply functions account for the geological as well as the economic aspects of supply; oil prices can be determined either by OPEC setting prices (as normally included in this type of model) or by OPEC setting volumes and market forces determining the price; and consistency checks on consumers' and producers' behaviour are incorporated to confirm the plausibility of model projections. The paper commences with an outline of the model structure followed by an examination of the choice of the appropriate data. The main sections of the paper discuss the estimation of the demand and non-OPEC supply functions. Finally the modelling of OPEC's behaviour is addressed. Comparisons are made throughout with other published work. As the model was estimated using data covering 1960 to 1985, brief comments are also made comparing the events of 1986 with model determined values. (author)

  3. Oil price stability and free markets

    International Nuclear Information System (INIS)

    Yamani, A.Z.

    1992-01-01

    The oil industry, like any capital-intensive industry with long supply lead times, is prone to price instability. Free markets in oil reflect this inherent instability, for prices are efficient signallers of imbalances between supply and demand. Free markets are desirable in principle, but entirely free oil markets are unstable. Volatile oil prices are undesirable. This article advocates trading some market freedom for more price stability, since such a trade off will be beneficial to the world as a whole. (author)

  4. Toward Third World oil independence

    Energy Technology Data Exchange (ETDEWEB)

    Tanzer, M.

    1980-05-01

    This is an interview with Michael Tanzer, an oil economist and independent consultant on petroleum production and economic development. Mr. Tanzer discussed the role of non-OPEC developing countries in the world oil industry. In most of the developing countries there is a serious lack of capital for drilling and exploration. Multinational corporations not only have tremendous overall assets and capital but have created a mystique that they alone have the technology to explore and drill for oil. A holdover from the days of colonialism when knowledge of industry was kept outside these countries, oil companies have consciously resisted training people from Third World countries into higher-level jobs, according to Mr. Tanzer. Another deterrent to national petroleum development is pressure from international organizations, particularly the World Bank and International Monetary Fund. Their policies in the past have been not to fund energy development in the developing countries. Unfortunately too, as part of the whole picture, there are corrupt ruling groups in Third World countries that can be bought by the oil companies, whether explicitly or implicitly. (SAC)

  5. World resources of oil products

    International Nuclear Information System (INIS)

    Bonnaterre, Raymond

    2014-01-01

    In a first part, the author outlines that the issue of density of an oil product raises the question of the validity of a counting approach based on volumes. As oil industries produce always less heavy products and always more light products, this means that always less oil is needed to produce a gallon or a litre of fuel out of a refinery. The author comments the evolution of crude oil extraction. In a second part, he outlines that hydrocarbon productions become always more complex with respect to their origin. Thus, during gas extraction, humid gases are recovered which contain an important part of hydrocarbons similar to light oil. These aspects and the development of shale gas exploitation will make the USA the first oil producer in the world whereas they still have to import heavy oil to feed their refineries. He discusses the level of reserves and production costs with respect to the product type or its extraction location. He discusses the evolution of the estimates of world ultimately recoverable resources (synthesis processes excluded). He comments the level of condensate extraction ratio of the main shale gas fields in the USA and outlines the cost of natural gas imports for France. He outlines the importance of GTL (gas to liquid) processes, the increasing importance of bio-fuels (notably isobutanol biosynthesis and terpene biosynthesis). In the third part, the author states that the barrel price should keep on increasing and, in the fourth part, proposes a list of issues which will impact the future of the oil market

  6. Stabilizing and changing phenomenal worlds

    DEFF Research Database (Denmark)

    Brorson, Stig; Andersen, Hanne

    2001-01-01

    discuss the problem of how divergent thinking can emerge in a dogmatic atmosphere. We shall argue that in their accounts of the factors inducing changes of scientific phenomenal worlds Fleck and Kuhn offer substantially different approaches, and we shall discuss in which respects their approaches may......In the work of both Ludwik Fleck and Thomas Kuhn the scientific literature plays important roles for stability and change of scientific phenomenal worlds. In this article we shall introduce the analyses of scientific literature provided by Fleck and Kühn, respectively. From this background we shall...

  7. Angola: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports that prospects of Angola, free of political complications, are certain to bring a flurry of interest from oil firms and could mean an influx of foreign capital. Licensing will be under production-sharing terms, but incentives may be offered due to increased risks inherent in deeper water. Long term security and stability remain uncertain. In addition to Unita and previously communist MPLA, new factions from 16 years of civil war are gaining support and increasing possibilities for violence. Oil firms consider production-sharing terms high and current price cap clauses keep them from realizing benefits from price increases after contracts are signed. However, geology and exploration successes have overshadowed concerns

  8. Seychelles: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports on the small island group that was host to the first Indian Ocean Regional Seminar on Petroleum Exploration in mid-December. Efforts are under way to set up a regional system for cooperation in petroleum between countries in the region that hope to become oil producers. Offshore permits are held by Enterprise Oil and recently by Texaco. Ultamar Exploration Ltd. signed an eight-year offshore exploration contract becoming only the fourth company to attempt exploration off the archipelago

  9. Malaysia: World Oil Report 1991

    International Nuclear Information System (INIS)

    Khin, J.A.

    1991-01-01

    This paper reports that the Malaysian government announced tax incentives for fiscal year 1991/92 by cutting export duties on crude oil to encourage companies to develop more oil fields. The export duty exemption on cost recovery oil was increased from the current 20% to 50% on April 1, 1991. Nearly 115,200 sq mi of shallow-water acreage off Malaysia has been awarded to PS contractors, leaving only about five blocks remaining. Therefore, Petronas plans to award deeper water blocks (water depths of 655 ft or more) in the second half of this year, once terms are finalized. It is understood that these areas will be offshore of Sarawak and Sabah, covering in excess of 38,000 sq mi. Petronas the that there would be some improvement in the PSC terms for the deep-water areas

  10. Oxidative stability of fish oil blended with butter.

    Science.gov (United States)

    Shiota, M; Konishi, H; Tatsumi, K

    1999-09-01

    The oxidative stability of fish oil blended with milk products was evaluated. Oxidation of the oil blend was determined by peroxide value and rancimat test. Improved oxidative stability was observed for fish oil blended with butter. Unsalted and salted butters showed no difference in improvement of effect on oxidative stability of fish oil. No influence on oxidative stability for the fish oil was observed with butter oil, which was the oil fraction of butter. These studies suggested that the improved oxidative stability of fish oil-butter blend was due to the hydrophilic fraction of butter and that butter could improve the oxidative stability of polyunsaturated oils such as fish oil.

  11. Peru: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports on strong measures that are being taken to resuscitate Peru's hydrocarbon sector. The first step last August was the cutting of fuel subsidies in half. Then the administration issued tax vouchers to state utilities for the money they still owed national oil company Petroperu. A precursor to what are expected to be widespread changes to the existing petroleum legislation occurred last fall. As part of a package of fiscal reforms, the official base rate that the government paid Occidental Petroleum to produce crude for Petroperu was dropped. A new, free market rate was adopted, which was six times the old base rate

  12. World oil supply and demand'

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    Apart from a collapse of oil and gas consumption in the CIS, a strong increase in demand in the newly industrialized countries and an upward trend in the OECD countries are observed. Non-Opec supply continued to grow, with a production decline in Usa and Russia but a record production level in the North Sea and a remarkable revival in South America (Colombia, Argentina) and Africa (Congo, Angola). In Opec countries, the trend goes from supply control to development of production capacity. Situations in Saudi Arabia, Iran and Iraq are detailed

  13. Honduras: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports that after a lull last year, the Director General of Mines and Hydrocarbons the drilling is expected to resume this year with two onshore tests. Presumably, one of these will be a wildcat by Venezuela's Cambria Resources in the jungle area of the Mosquitia province along the Caribbean coast. Cambria Resources took over the Brus Laguna concession in this area from Bonavista Oil and Mining Corp. and finished a 348-mi seismic survey in 1989. Venezuela's PDVSA subsidiary, Maraven, also signed a deal in April to explore offshore this same area

  14. Stability in a changing world -

    DEFF Research Database (Denmark)

    Olivares, Ingrid; Svenning, J.-C.; van Bodegom, Peter M

    2016-01-01

    Are the hyperdiverse local forests of the western Amazon undergoing changes linked to global and local drivers such as climate change, or successional dynamics? We analyzed local climatic records to assess potential climatic changes in Yasuní National Park, Ecuador, and compared two censuses (1995...... dynamics in Yasuní contrast with recent findings from eastern Amazon, where environmental change is driving significant changes in ecosystem dynamics. Our findings suggest that until now, local forests in the northwest Amazon may have escaped pressure from climate change. The stability of this rich palm...

  15. Oman: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports that for the sixth consecutive year, Oman should retain its title as the biggest driller in the Middle East in 1991. An accelerated program in 1990 pushed production to an all-time record 700,000 bpd late in the year. Although not a member of Opec, Oman has cooperated with the group in restraining output as needed to support oil prices. Petroleum Development Oman (PDO), a partnership of the government (60%), Royal Dutch Shell (34%), Total (4%) and Partex (2%), remains by far the biggest producer. This year, PDO will begin work on its $500-million effort to boost production from its Lekhwair field from a current 24,000 bpd to 110,000 bpd by 1994. Last year, PDO also drilled 15 horizontal wells, most of which were successful in increasing per well production compared to conventional vertical holes. The horizontal program has been continued this year with two rings

  16. Oxidative stability of krill oil (Euphausia superba)

    DEFF Research Database (Denmark)

    Lu, Henna Fung Sieng; Jacobsen, Charlotte; Bruheim, I.

    conditions. These compounds include Strecker degradation compounds and pyrroles. Some of these compounds may have antioxidative effect. Commercial scale processing of krill prior to extraction may affect the oxidative stability of krill oil. Therefore, the main objective of this study was to compare lipid...... oxidation in krill oil produced in a commercial process and krill oil carefully extracted from frozen krill in the laboratory. Krill oil was incubated at different temperatures (20, 30 and 40 oC) for 1, 2, 3, 4 and 6 weeks, under conditions of constant stirring while being exposed to air. The oxidative......Krill oil has been reported in many studies to have high oxidative stability when evaluated by peroxide value (PV) and anisidine value (AV). However, recent studies have shown that other compounds than primary and secondary oxidation products are formed when krill oil is exposed to oxidative...

  17. Ecuador: World Oil Report 1991

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    This paper reports that there has been considerable turbulence in Ecuador's E and P sector over the last year. For instance, Energy Minister Diego Tramariz was replaced by the country's Congress after he raised subsidized fuel prices. Ecuadoran and U.S. environmentalists, meanwhile, raised a firestorm of controversy over the on-again, off- again development of Conoco's Block 16 in Yasuni National Park. Finally, Unocal and PetroCanada this spring terminated their respective drilling operations after fruitless multiwell efforts. New Energy Minister Donald Castillo certainly has his work cut out in attempting to maintain stability in upstream activity. To that end, Castillo has stated that one of his top priorities will be to maintain a good working relationship with foreign operators. He also expected a seventh round of exploratory blocks to be offered before summer's end to shore up activity. Castillo reiterated in public statements that he stands by the administration's existing energy policies, including development of Block 16

  18. Changes in the world market in oil and oil refinements

    International Nuclear Information System (INIS)

    Ristik, Julija

    1996-01-01

    Since 1980's the world market for crude oil and oil products has faced significant changes that are going to have a grate influence on the supply and consumption of crude oil derivatives in Macedonia. The knowledge of these changes would have a grate contribution in planning the future development of this part of the energetic system of Macedonia. The purpose of this paper (which is a short version of the introductory report for the ZEMAK session with a theme 'Energetic policy and development of energetics in Macedonia') is to present the actual situation on the market for crude oil products, as well as to give the main factors that would have influence on this market in the future. (author). 4 refs., 3 ills

  19. World oil price behavior during oil supply disruptions: what can we learn from the past

    Energy Technology Data Exchange (ETDEWEB)

    Birdsall, T.H.

    1980-08-01

    The purpose of this paper is to: (1) examine how world oil prices have behaved during past oil supply disruptions, (2) attempt to understand why world oil prices have behaved during disruptions as they have, and (3) see what history foretells, if anything, for the behavior of world oil prices during future oil supply disruptions.

  20. Oil Prophets: Looking at World Oil Studies Over Time

    Energy Technology Data Exchange (ETDEWEB)

    Andrews, Steve [Denver, CO (United States); Udall, Randy [Carbondale, CO (United States)

    2003-07-01

    Early reports of world oil assessments date back to the 1940s. In the intervening 60 years, the number of studies projecting Estimated Ultimately Recoverable (EUR) oil reached well over 50. A detailed search would undoubtedly lengthen the list that will be provided with this paper. How have their estimates fared? Given general agreement that we haven't yet reached the halfway point in eventual production, it's too early to offer definitive assessments. However, several factors stand out: The learning curve. It took over a decade of effort for projections to emerge that are in line with lower-end projections of more recent studies. The learning curve has flattened. For those individuals and groups who conducted multiple studies, their subsequent EUR numbers generally trend higher. The analyses lack a common definitional framework. Beyond crude oil, what liquids are included? Heavy oil and tar sands? Some or all gas liquids? Polar and deepwater oil? While the ability to locate, evaluate and extract oil in the field has drastically improved over time, analysts continue to be hampered by a lack of access to definitive data plus disagreements about assessment methodologies. Striving to determine how many petroleum liquids we have left is a useful exercise, but primarily as a means to help determine when daily worldwide production is likely to peak. To that end, a key point is that 'not all liquids resources are created equal'; many of the larger new fields are located in harsh and remote regions, in politically unstable environments, or require large energy inputs during extraction. Production rates and costs will vary dramatically. Since demand is somewhat fickle, identifying a year or range of years when liquids production will peak qualifies as part art, part science. That said, the paper will list estimates by 'oil prophets' as to when they project that petroleum liquids production will peak. The estimates range from 1995 to 2025. How

  1. Influence of microwaves on olive oil stability

    International Nuclear Information System (INIS)

    Farag, R.S.; El-Baroty, G.; Abd El-Aziz, N.; Basuny, A.M.

    1997-01-01

    The fruits of Picual and Shemlalli olive cultivars were exposed to microwaves generated from an oven at low and moderate power settings for 3, 6, 9 and 12 min. The physicochemical constants and fatty acid composition of the olive oil samples extracted from nonmicrowaved and microwaved fruits were determined. The data demonstrated that microwaves did not alter the values of the above mentioned parameters compared with the oil extracted from nonmicrowaved fruits. Quality assurance tests (acid, peroxide and TBA values) elucidated that microwaves generally increased the olive oil stability of Picual and Shemlalli cultivars during storage. In addition, microwaves generated from oven ot moderate power setting for 12 min. exhibited an antioxidant power on olive oil equivalent to that possessed by BHT at 200 ppm [es

  2. Models of oil spill dispersion stability

    International Nuclear Information System (INIS)

    Fingas, M.

    2009-01-01

    This paper summarized the theory of oil-in-water emulsion stability resulting in the resurfacing of oil spill dispersion. Since most emulsions are unstable, they will break down into their constituent parts because of the many forces and processes that act on them. These include gravitational forces; surfactant interchange with water and the subsequent surfactant loss to the water column; creaming; coalescence; flocculation; Ostwald ripening; and sedimentation. Gravitational separation is the most important force that contributes to the resurfacing of oil droplets from an oil-in-water emulsion. The paper presented a newly developed model that used 4 basic processes. Initial dispersion was an input, then the dispersion was distributed over the mixing depth, as predicted by the wave height. The droplets then rise to the surface according to Stokes' law. Oil on the surface from the rising oil and undispersed oil is redispersed. The droplets in the water column are subject to coalescence as governed by the Smoluchowski equation. The dispersion in the water column therefore decreases at an exponential rate with dispersion half-lives ranging from 120 to 250 minutes. Over 200 runs were performed using variations of the models. The study showed that the most important factor is the effectiveness of the initial dispersion and the the redispersion. Increased sea energy was found to increase the amount of coalescence that occurs, resulting in an increase in resurfacing. However, increased turbulence also caused redispersion, offsetting the effect of the recoalescence slightly. 17 refs., 5 tabs., 13 figs.

  3. Oxidative stability of diacylglycerol oil and butter blends containing diacylglycerols

    DEFF Research Database (Denmark)

    Kristensen, Janni Brogaard; Nielsen, Nina Skall; Jacobsen, Charlotte

    2006-01-01

    Diacylglycerol (DAG) oils produced from sunflower oil and traditional sunflower oil were stored for 20 wk at 38 degrees C, and their oxidative stability was measured. Moreover, two butter blends were produced containing 40 wt-% DAG oil made from sunflower oil or rapeseed oil, respectively, as well...... as two control butter blends with sunflower oil or rapeseed oil. Their oxidative stability during storage at 5 degrees C for up to 12 wk was examined by similar means as for the pure oils. The storage study of the oils indicated that the DAG oil was oxidatively less stable as compared to sunflower oil......, but that they had similar sensory quality. Storage of the butter blends revealed that blends with the two types of rapeseed oil (triacylglycerol (TAG) or DAG oil) were oxidatively more stable than the blends containing oils from sunflower. There was no unambiguous indication of DAG butter blends having a different...

  4. Stabilization of Model Crude Oil Emulsion using Different ...

    African Journals Online (AJOL)

    As part of an ongoing research into the stability of oil-field emulsions, model oil samples have been utilized to probe the effects of asphaltene interactions on crude oil/water emulsion stability. Asphaltenes were precipitated from treated Ondo State oil sand bitumen with n-hexane in a 40:1 solvent to bitumen ratio which was ...

  5. Proceedings of the CERI 2001 World Oil Conference. CD ed.

    International Nuclear Information System (INIS)

    2001-01-01

    The integration and expansion of world oil markets was the main topic of this conference which featured 23 presentations dealing with developments in the international energy sector. The conference was divided into 8 sessions entitled: (1) oil prices, (2) oil and politics, (3) global oil supply, (4) North American supply and markets, (5) global oil demand, (6) oil.com, (7) the business of the environment, and (8) oil and money. The outlook of world energy markets was reviewed with particular emphasis on prospects for oil supply and reserves. The current status of the petroleum industry in both OPEC and non-OPEC oil exporting countries was discussed with reference to exploration, production, reserves, and hydrocarbon potential. The environmental, and socio-economic challenges that both the upstream and downstream industry will face challenges in the next century were also described. refs., tabs., figs

  6. Reference data on world oil markets

    International Nuclear Information System (INIS)

    2005-01-01

    This paper makes a status of the 2004 activity of worldwide oil markets: oil demand, oil supplies (OPEC and non-OPEC countries, unused production capacities), formation of oil prices (role of stockpiles, role of terminal markets, impact of dollar rate), economic data: OPEC objectives, market vision, volatility of prices, supply and demand. (J.S.)

  7. Investigation of carrier oil stabilized iron oxide nanoparticles and its ...

    African Journals Online (AJOL)

    Iron oxide nanoparticles were synthesized by co-precipitation method. The polyunsaturated carrier oil (flaxseed oil) is used as a stabilizing agent for iron oxide nanoparticles. Kirby Bauer method was used to investigate the antibiotic sensitivity of carrier oil stabilized and uncoated SPIONs at 10 and 20 μg/L on Gram-positive ...

  8. World electricity generation, nuclear power, and oil markets

    International Nuclear Information System (INIS)

    1990-01-01

    Striking changes have characterized the world's production and use of energy over the past 15 years. Most prominent have been the wide price fluctuations, politicization of world oil prices and supply, along with profound changes in patterns of production and consumption. This report, based on a study by energy analysts at Science Concepts, Inc., in the United States, traces changes in world energy supply since 1973-74 - the time of the first oil ''price shocks''. In so doing, it identifies important lessons for the future. The study focused in particular on the role of the electric power sector because the growth in fuel use in it has been accomplished without oil. Instead, the growth has directly displaced oil. In the pre-1973 era, the world relied increasingly on oil for many energy applications, including the production of electricity. By 1973, more than on-fourth of the world's electricity was produced by burning oil. By 1987, however, despite a large increase in electric demand, the use of oil was reigned back to generating less than 10% of the world's electricity. Nuclear power played a major role in this turnaround. From 1973-87, analysts at Science Concepts found, nuclear power displaced the burning of 11.7 billion barrels of oil world-wide and avoided US $323 billion in oil purchases

  9. Neo-Liberal International Economy and World Oil Price

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jun Beom [Korea National Oil Corporation, Anyang (Korea)

    2001-06-01

    World oil price has been rapidly going up for almost 2 years. The recent high oil price, which has started from March 1999 about to close the 20th century, ended the period of the low oil price that had continued in 1990s and made the entry into the period of the high oil price as an established fact, so the oil consumers have taken it as the considerable economic impacts. The possibility of the world economic stagnation, which has been raised recently, seems to reconfirm the conventional wisdom that the world economic stagnation comes after the period of the high oil price as the Minister of Energy department, Abraham Spencer, mentioned in March. However, it is necessary to differently understand the recent high oil price because it occurred under the circumstance of neo-liberalism, a new international economic system.

  10. Present status on world alternative energy developments to oil

    International Nuclear Information System (INIS)

    Reddington, J.

    1980-01-01

    The IEA was established about five years ago in the OECD immediately after the oil crisis, and 20 countries have participated in it. Progress was observed in the control of the expansion of energy demand. The energy utilization in IEA member countries became efficient due to the contribution of new technologies, and owing to the improvement of productivity, the growth of energy consumption was less than 1% despite the GDP grew at the yearly rate of 2.5%. The expansion of the utilization of natural gas and coal is promising, but the projects of nuclear power generation are behind schedule. The short term prospect in petroleum market is discussed, and the price of crude oil tends to be stabilized. ''The prospect of energy in the world by 2000'' will be published by the IEA in the latter half of 1980. The scale of the development of nuclear power generation was reduced because the prediction of the rate of power generation growth was changed from 5.2% to 3.1%. The effect of new energy technologies on future energy market has been studied by the support of 15 countries, and it was recommended to give financial aid to heat pumps, coal liquefaction and the efficient recovery of oil and natural gas. Also the techniques for operating existing facilities under strict environment and safety regulations have been studied. (Kako, I.)

  11. The outlook for the world and Australian oil markets

    International Nuclear Information System (INIS)

    Donaldson, K.; Fok, G.

    1996-01-01

    Global demand for oil is projected to continue its upward trend to 2000-1, with growth in the transport sector expected to underpin future increases in oil consumption. World oil consumption is projected to be matched by global production, keeping the average annual oil price relatively stable. In many countries, the diversion of oil revenue to other projects is threatening to constrain increases in production capacity, particularly in the OPEC countries. The encouragement of foreign investment in state oil industries is a likely method of easing the constraint. Australian exploration activity is rising steadily with the prospect of stable oil prices, expanding gas markets and the incentives provided by a number of recent discoveries. While the geographical pattern of Australian production has now changed, with Western Australian production exceeding Victoria production, Australia is expected to maintain its position in the world oil market as a significant producer, importer and exporter. (author). 6 figs., 23 refs

  12. State of the art in oil market in the world

    International Nuclear Information System (INIS)

    Banks, F. E.

    2007-01-01

    Things move fast in the world of oil and unfortunately many events do not always receive an appropriate interpretation. The present update reviews the on-going oil peak debate, providing evidence against unjustified optimistic propositions, discussing the predictable shortage of energy materials and its influence on prices. Moreover, the return of OPEC to the oil market drivers seat and the irruption of state oil companies from exporting countries are also commented. (Author)

  13. Oil prices and the world business cycle: A causal investigation

    OpenAIRE

    Tapia, Jose

    2016-01-01

    Oil shocks have been often considered as exogenous factors responsible of economic downturns. In this paper the hypothesized exogeneity of oil prices is investigated by using running cross-correlations, distributed lag-regressions, Granger causality tests and VAR models applied to annual data 1960-2014 of oil prices and global economic activity—as measured by world GDP. Strong evidence is found that (a) the relation between oil prices and the global economy has significantly changed since th...

  14. Characterization of Oxidative Stability of Fish Oil- and Plant Oil-Enriched Skimmed Milk

    DEFF Research Database (Denmark)

    Saga, Linda C.; Kristinova, Vera; Kirkhus, Bente

    2013-01-01

    oil was added to fish oil in only 5 and 10 %, whereas no protective effect of camelina oil was observed when evaluated by these methods. Moreover, fish oil blended with oat oil conferred the lowest PV and lower amounts of volatile compounds during the storage period of 14 days at 4 °C. Surprisingly......The objective of this research was to determine the oxidative stability of fish oil blended with crude plant oils rich in naturally occurring antioxidants, camelina oil and oat oil, respectively, in bulk and after supplementation of 1 wt% of oil blends to skimmed milk emulsions. Ability of crude...

  15. Natural antioxidants in the stability of ray liver oil

    OpenAIRE

    Navarro-García, Gerardo; Gámez-Meza, Nohemí; Medina-Juárez, Luis Angel; Ortega-García, Jesús; Cota-Quiñones, Elizabeth; Ramirez-Suarez, Juan Carlos

    2016-01-01

    ABSTRACT: The effect of the addition of natural antioxidants on oxidative stability of ray ( Rhinoptera bonasus) liver oil was evaluated. Different concentrations of rosemary extract, α-tocopherol, and caffeic acid (w/w) were added to the oil. Afterwards, concentration of each antioxidant that gave the highest stability was used in an accelerated stability test (Schaal method). The protective effect was established by the retention in the oil of fatty acids eicosapentaenoic (EPA) and docosahe...

  16. Effect of citronella essential oil fractions as oil phase on emulsion stability

    Science.gov (United States)

    Septiyanti, Melati; Meliana, Yenny; Agustian, Egi

    2017-11-01

    The emulsion system consists of water, oil and surfactant. In order to create stable emulsion system, the composition and formulation between water phase, surfactant and oil phase are very important. Essential oil such as citronella oil has been known as active ingredient which has ability as insect repellent. This research studied the effect of citronella oil and its fraction as oil phase on emulsion stability. The cycle stability test was conducted to check the emulsion stability and it was monitored by pH, density, viscosity, particle size, refractive index, zeta potential, physical appearance and FTIR for 4 weeks. Citronellal fraction has better stability compared to citronella oil and rhodinol fraction with slight change of physical and chemical properties before and after the cycle stability test. However, it is need further study to enhance the stability of the emulsion stability for this formulation.

  17. Oil and the world economy: some possible futures.

    Science.gov (United States)

    Kumhof, Michael; Muir, Dirk

    2014-01-13

    This paper, using a six-region dynamic stochastic general equilibrium model of the world economy, assesses the output and current account implications of permanent oil supply shocks hitting the world economy. For modest-sized shocks and conventional production technologies, the effects are modest. But for larger shocks, for elasticities of substitution that decline as oil usage is reduced to a minimum, and for production functions in which oil acts as a critical enabler of technologies, output growth could drop significantly. Also, oil prices could become so high that smooth adjustment, as assumed in the model, may become very difficult.

  18. Improving oxidative stability of liquid fish oil supplements for pets

    DEFF Research Database (Denmark)

    Thomsen, Birgitte Raagaard; Griinari, Mikko; Jacobsen, Charlotte

    2017-01-01

    of fish oil by adding vegetable oils, mixed tocopherols and rosemary extract, and to formulate a commercial product according to the results obtained. The formulated product was evaluated against commercial fish oil products. An initial screening for antioxidative effect was performed by using Oxipres...... equipment. The effect of antioxidant and vegetable oil blends was examined in oils stored at 30 and 40°C by measuring peroxide value, volatile compounds with GC-MS and tocopherol content. Addition of vegetable oil and rosemary extract at high level (4000–6000 ppm) plus 600 ppm of mixed tocopherols increased...... oxidative stability to the same extent as 2000 ppm mixed tocopherols in Oxipres. Overall, oxidative stability of fish oil or fish oil + vegetable oil blends was improved the most by addition of 5000 ppm rosemary extract and 500 ppm mixed tocopherols. A commercial oil blend with composition optimized based...

  19. Stochastic Energy Deployment System (SEDS) World Oil Model (WOM)

    Energy Technology Data Exchange (ETDEWEB)

    2009-08-07

    The function of the World Oil Market Model (WOMM) is to calculate a world oil price. SEDS will set start and end dates for the forecast period, and a time increment (assumed to be 1 year in the initial version). The WOMM will then randomly select an Annual Energy Outlook (AEO) oil price case and calibrate itself to that case. As it steps through each year, the WOMM will generate a stochastic supply shock to OPEC output and accept a new estimate of U.S. petroleum demand from SEDS. The WOMM will then calculate a new oil market equilibrium for the current year. The world oil price at the new equilibrium will be sent back to SEDS. When the end year is reached, the process will begin again with the selection of a new AEO forecast. Iterations over forecasts will continue until SEDS has completed all its simulation runs.

  20. Oil and gas activities of the world bank

    Energy Technology Data Exchange (ETDEWEB)

    Hossein, R. [World Bank, Washington, DC (United States)

    1993-12-31

    The oil crisis of the 1970s profoundly challenged the economies of most developing countries. The crisis hit the the oil-importing countries severely, and many suffered deteriorating balances of payments and increasingly unmanageable import bills. It was in this context, in July 1977, that the World Bank`s Executive Directors approved an expanded program of lending to assist the Bank`s client countries in developing their own energy resources. In 1978, the Bonn Summit and the Secretary General of the United Nations endorsed the initiation of new approaches in the energy sector by the World Bank, particularly in financing oil exploration in countries that were significant oil importers. The new initiative led to a rapid expansion of the World Bank`s lending for oil and gas projects, which reached about $1 billion in 1983.

  1. Oil and gas activities of the world bank

    International Nuclear Information System (INIS)

    Hossein, R.

    1993-01-01

    The oil crisis of the 1970s profoundly challenged the economies of most developing countries. The crisis hit the the oil-importing countries severely, and many suffered deteriorating balances of payments and increasingly unmanageable import bills. It was in this context, in July 1977, that the World Bank's Executive Directors approved an expanded program of lending to assist the Bank's client countries in developing their own energy resources. In 1978, the Bonn Summit and the Secretary General of the United Nations endorsed the initiation of new approaches in the energy sector by the World Bank, particularly in financing oil exploration in countries that were significant oil importers. The new initiative led to a rapid expansion of the World Bank's lending for oil and gas projects, which reached about $1 billion in 1983

  2. Stability of traditionally processed vegetable oils and their blends ...

    African Journals Online (AJOL)

    The objective of the study was to investigate the stability of traditionally processed palm oil (PO), sunflower oil (SO) and sesame oil (SSO) and their blends as function of storage conditions by analysing their physicochemical properties which included acid value, saponification value, peroxide value, iodine value and ...

  3. World oil prices, precious metal prices and macroeconomy in Turkey

    International Nuclear Information System (INIS)

    Soytas, Ugur; Sari, Ramazan; Hammoudeh, Shawkat; Hacihasanoglu, Erk

    2009-01-01

    We examine the long- and short-run transmissions of information between the world oil price, Turkish interest rate, Turkish lira-US dollar exchange rate, and domestic spot gold and silver price. We find that the world oil price has no predictive power of the precious metal prices, the interest rate or the exchange rate market in Turkey. The results also show that the Turkish spot precious metals, exchange rate and bond markets do not also provide information that would help improve the forecasts of world oil prices in the long run. The findings suggest that domestic gold is also considered a safe haven in Turkey during devaluation of the Turkish lira, as it is globally. It is interesting to note that there does not seem to be any significant influence of developments in the world oil markets on Turkish markets in the short run either. However, transitory positive initial impacts of innovations in oil prices on gold and silver markets are observed. The short-run price transmissions between the world oil market and the Turkish precious metal markets have implications for policy makers in emerging markets and both local and global investors in the precious metals market and the oil market.

  4. Optimal Oil Production and the World Supply of Oil

    OpenAIRE

    Nikolay Aleksandrov; Raphael Espinoza; Lajos Gyurko

    2012-01-01

    We study the optimal oil extraction strategy and the value of an oil field using a multiple real option approach. The numerical method is flexible enough to solve a model with several state variables, to discuss the effect of risk aversion, and to take into account uncertainty in the size of reserves. Optimal extraction in the baseline model is found to be volatile. If the oil producer is risk averse, production is more stable, but spare capacity is much higher than what is typically observed...

  5. Ten-year retrospective: OPEC and the world oil market

    Energy Technology Data Exchange (ETDEWEB)

    Gately, D.

    1984-09-01

    This paper reviews the main events in the world oil market since 1973 and some major explanations as to what happened and why (Section I). Then there is a discussion of some projections for the next two decades and of some implications of various theories about OPEC's decisionmaking process (Section II). Section III summarizes what we have learned about modeling OPEC and the world oil market. This includes: the dominant theoretical approach based on the wealth-maximization model of Harold Hotelling (1931); the simulation approach most common in the applied literature, which envisages target-capacity-utilization pricing by OPEC; and the difficult problem of modeling price behavior during disruptions. Finally, Section IV discusses some important unresolved issues, both theoretical and empirical. A variety of contributions to the literature are considered, but the discussion pays special attention to two important recent works. One is the book OPEC Behavior and World Oil Prices (1982) (EAPA 9:3899) edited by James Griffin and David Teece, an important collection of papers on OPEC and world oil, prepared for a 1981 conference at the University of Houston. The other is the 1980 to 1981 world oil study by the Energy Modeling Forum of Stanford Univesity, which involved ten prominent models of the world oil market. 31 references.

  6. Stabilizing effect of epoxidized sunflower oil as a secondary stabilizer for Ca/Hg stabilized PVC

    Directory of Open Access Journals (Sweden)

    2008-01-01

    Full Text Available Unsaturated triglyceride oil sunflower was epoxidized and characterized by chemical and spectroscopic methods. Epoxidized sunflower oil (ESO was used as an organic thermal co-stabilizer for rigid poly(vinyl chloride (PVC in the presence of tricalcium dicitrate (Ca3(C6H5O72 and mercury (II acetate (Hg(CH3COO2. The thermo-oxidative degradation of PVC was studied in the presence of these ternary stabilizer systems at 170, 180, 190 and 200°C in N2 atmosphere. The effects of metal carboxylate combination Ca/Hg in the absence and in the presence of epoxidized sunflower oil on static heat treatment of PVC have been studied. The formation of polyene sequences was investigated by UV-visible and FT-IR spectroscopy and by comparing viscosity data obtained in the presence and in the absence of the additives. It was found that the additives retard the rate of degradation and reduce the extent of polymer chain scission associated with the thermal degradation of poly(vinyl chloride. Synergistic effects were found when stabilizer was blended in 50:50 weight ratios with either. It was found that ESO exerted a stabilizing effect on the degradation of PVC. The activation energy for degraded PVC in absence of stabilizers was 38.6 kJ•mol–1 and in the presence of Ca/Hg and Ca/Hg/ESO were 53.3 and 64.7 kJ•mol–1 respectively. In order of compare the efficiency of the epoxidized sunflower oil with these metal soap stabilizers, thermal stabilities were evaluated on the basis of evolved hydrogen chloride determined by conductometry technique and degree of discoloration are discussed.

  7. Alternative Methods of Frying and Antioxidant Stability in Soybean Oil

    OpenAIRE

    Probir Kumar Ghosh; Dipan Chatterjee; Paramita Bhattacharjee

    2012-01-01

    A study on shallow and parfrying in soybean oil as alternatives to deep frying and evaluation of stability of a formulated antioxidant administered to the oil was conducted. Potato wedges were deep, shallow and parfried in soybean oil for optimized time and temperature. A citric acid based antioxidant using BHT was formulated and administered to the oils before frying. The performance of antioxidant was assessed by studying its physicochemical properties and DPPH radical scavenging activity w...

  8. World resources of crude oil and natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Masters, C.D.; Root, D.H.; Attanasi, E.D. (Geological Survey, Reston, VA (United States))

    1991-01-01

    An abstract is given of a paper presented at the World Petroleum Congress 1991 on the world estimates of identified reserves and undiscovered resources for crude oil, natural gas and natural gas liquids. Data are presented for Canada, Mexico, USA, South America, Western Europe, Eastern Europe, USSR, Africa, Middle East, Asia/Oceania and Antartica. (UK).

  9. Oilseeds and vegetable oils in asia: a world of diversity

    Directory of Open Access Journals (Sweden)

    Mittaine Jean-François

    2016-11-01

    Full Text Available Out of the two dozen countries that constitute what is generally called “Asia”, some are the largest in the world while others are islands with smaller populations. When looking at oilseeds and vegetable oils in the region, one is faced with the same huge diversity which makes it complex to analyze, all the more that statistics are not easily available for many countries. Aside from the large differences in size, the region covers a wide spectrum of diversified climate environments. Asia is also mainly characterized by its huge population which has become largely urban, a key factor leading to the impressive growth of vegetable oil demand in the past 30 years. At an verage of 23.2 kg/year, Asian per capita consumption of oils and fats still remains slightly below the world average of 28.3 kg/capita/year. Therefore, although 53% of the world population is located in Asia, only 45% of world oils and fats is consumed in the region. As detailed in the paper, the world of Asian oilseeds and vegetable oils is highly concentrated on soybeans and palm oil. In spite of a large domestic production in China (12.3 MnT, soybeans are imported in huge quantities, mostly by China (78 MnT, 84% of the region’s imports where more than 28% of world soybeans production is being crushed. Palm oil, the second large commodity consumed in the region, is mainly produced within the region, mostly in Indonesia and Malaysia. So where is the “world of diversity”? Hidden behind those two dominant commodities, practically all of the ten oilseeds constituting the core of the world production are grown in significant quantities in the region while, for vegetable oils, all those of significant importance are produced within the region with the exception of olive oil. The main question that should be kept in mind when reviewing this large regional demand is under what condition will future vegetable oil production be able to meet the expected rise of per capita oils and

  10. Oil: lubricant of world-peace

    Energy Technology Data Exchange (ETDEWEB)

    1981-06-01

    On the Energy Forum 81 in Berlin on May 21, 1981, Sheikh Ahmed Zaki Yamani concentrated on the political and economic problems of safeguarding energy and on the relations between oil-producing, industrial and developing countries. At this event organized by BP Germany he found a conciliatory tone. The subsequent OPEC-conference in Geneva agreed with him.

  11. Influence of stability of polymer surfactant on oil displacement mechanism

    Science.gov (United States)

    Liu, Li; Li, Chengliang; Pi, Yanming; Wu, Di; He, Ying; Geng, Liang

    2018-02-01

    At present, most of the oilfields of China have entered the late stage of high water-cut development, and three oil recovery technique has become the leading technology for improving oil recovery. With the improvement of three oil recovery techniques, the polymer surfactant flooding technology has been widely promoted in oil fields in recent years. But in the actual field experiment, it has been found that the polymer surfactant has chromatographic separation at the extraction end, which indicates that the property of the polymer surfactant has changed during the displacement process. At present, there was few literature about how the stability of polymer surfactant affects the oil displacement mechanism. This paper used HuaDing-I polymer surfactant to conduct a micro photolithography glass flooding experiment, and then compared the oil displacement law of polymer surfactant before and after static setting. Finally, the influence law of stability of polymer surfactant on the oil displacement mechanism is obtained by comprehensive analysis.

  12. World oil and geopolitics to the year 2010

    Energy Technology Data Exchange (ETDEWEB)

    Amirahmadi, H.

    1995-12-31

    This paper focuses on the interplay of market forces and politics in the world oil market projected to the year 2010. It argues that world oil demand will increase considerably, with Asian demand growing the fastest. Given that the growth of oil supply of producers outside the Organization of the Petroleum Exporting Countries (OPEC) will be trivial, the call on OPEC oil will increase substantially. Yet, given their declining per-capita oil revenues, OPEC members may not be able to make timely investments in required upstream projects. If this happens, the supply constraint will lead to higher prices and intensified international competition for Arabian/Persian Gulf oil. Thus, foreign investment will be needed increasingly in OPEC states if prices are to remain stable. But geopolitical and institutional barriers to foreign investment in many OPEC members hinder foreign investment. It is imperative that major players in the world oil market cooperate to reduce such barriers in time to ensure that supply corresponds to rising demand. 22 refs., 8 figs., 10 tabs.

  13. Stability of avocado oil during heating: comparative study to olive oil

    OpenAIRE

    Berasategi, I. (Izaskun); Barriuso, B. (Blanca); Ansorena, D. (Diana); Astiasarán, I. (Iciar)

    2012-01-01

    The stability of the saponifiable and unsaponifiable fractions of avocado oil, under a drastic heating treatment, was studied and compared to that of olive oil. Avocado and olive oil were characterised and compared at time 0 h and after different times of heating process (180 °C). PUFA/SFA (0.61 at t = 0) and ω-6/ω-3 (14.05 at t = 0) were higher in avocado oil than in olive oil during the whole experiment. Avocado oil was richer than olive oil in total phytosterols at time 0 h (339.64; 228.27...

  14. Comparison of thermal stability of grape seed oil with virgin sesame oil

    OpenAIRE

    Marzieh; Peyman; Fayegh Moulodi

    2015-01-01

    Background: Heating causes extensive physical and chemical changes in oil and fats, which can change all physical and chemical characteristics and quality of oil during frying is so critical. This study was aimed to compare the thermal stability of virgin sesame oil and grape seed oil. Methods: The grape seed oil and virgin sesame oil were heated at 180 ° C for 8 hours. Every hour, a sample of the heated oils was taken to determine the changes in acid value, peroxide, anisidine and Totox. ...

  15. Peaking of world oil production: Impacts, mitigation, & risk management

    Energy Technology Data Exchange (ETDEWEB)

    Hirsch, R.L. (SAIC); Bezdek, Roger (MISI); Wendling, Robert (MISI)

    2005-02-01

    The peaking of world oil production presents the U.S. and the world with an unprecedented risk management problem. As peaking is approached, liquid fuel prices and price volatility will increase dramatically, and, without timely mitigation, the economic, social, and political costs will be unprecedented. Viable mitigation options exist on both the supply and demand sides, but to have substantial impact, they must be initiated more than a decade in advance of peaking.... The purpose of this analysis was to identify the critical issues surrounding the occurrence and mitigation of world oil production peaking. We simplified many of the complexities in an effort to provide a transparent analysis. Nevertheless, our study is neither simple nor brief. We recognize that when oil prices escalate dramatically, there will be demand and economic impacts that will alter our simplified assumptions. Consideration of those feedbacks will be a daunting task but one that should be undertaken. Our aim in this study is to-- • Summarize the difficulties of oil production forecasting; • Identify the fundamentals that show why world oil production peaking is such a unique challenge; • Show why mitigation will take a decade or more of intense effort; • Examine the potential economic effects of oil peaking; • Describe what might be accomplished under three example mitigation scenarios. • Stimulate serious discussion of the problem, suggest more definitive studies, and engender interest in timely action to mitigate its impacts.

  16. An investment cycle in world oil prices

    International Nuclear Information System (INIS)

    Adelman, M.A.

    1992-01-01

    The price of Persian Gulf petroleum emerged after World War II as the world price. Adjusted to 1990 price levels, it went from $22 in 1947 to a low of $3 in 1970, then a high of $56 in 1981, and a low of $15 in the first half of 1990. A cyclical model is often suggested to explain these extreme swings generated by the relation between market price and investment. 9 refs., 2 figs

  17. Comparison of thermal stability of grape seed oil with virgin sesame oil

    Directory of Open Access Journals (Sweden)

    Marzieh

    2015-11-01

    Full Text Available Background: Heating causes extensive physical and chemical changes in oil and fats, which can change all physical and chemical characteristics and quality of oil during frying is so critical. This study was aimed to compare the thermal stability of virgin sesame oil and grape seed oil. Methods: The grape seed oil and virgin sesame oil were heated at 180 ° C for 8 hours. Every hour, a sample of the heated oils was taken to determine the changes in acid value, peroxide, anisidine and Totox. Results: Heating the oil caused extensive chemical variations both oils. The acidity index increased over time (p<0.05, there were fluctuations inperoxide value, and anisidine and Totox values also increased during thermal processes (p<0.05. Conclusion: Grape seed oil showed more resistance to heat than sesame oil.

  18. World oil and gas markets in 2005

    International Nuclear Information System (INIS)

    2006-01-01

    In front of insufficient production capacities, the petroleum and gas spot prices have won historical records in 2005. This paper analyzes this situation using the highlights of this exceptional year and concerning the producing countries (political situation), the oil and gas markets (exchange rates, demand, production capacity), the European quotations of petroleum products (automotive and domestic fuels), and the prices of petroleum products in France. (J.S.)

  19. Stabilization of Fast Pyrolysis Oil: Post Processing Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.; Lee, Suh-Jane; Hart, Todd R.

    2012-03-01

    UOP LLC, a Honeywell Company, assembled a comprehensive team for a two-year project to demonstrate innovative methods for the stabilization of pyrolysis oil in accordance with DOE Funding Opportunity Announcement (FOA) DE-PS36-08GO98018, Biomass Fast Pyrolysis Oil (Bio-oil) Stabilization. In collaboration with NREL, PNNL, the USDA Agricultural Research Service (ARS), Pall Fuels and Chemicals, and Ensyn Corporation, UOP developed solutions to the key technical challenges outlined in the FOA. The UOP team proposed a multi-track technical approach for pyrolysis oil stabilization. Conceptually, methods for pyrolysis oil stabilization can be employed during one or both of two stages: (1) during the pyrolysis process (In Process); or (2) after condensation of the resulting vapor (Post-Process). Stabilization methods fall into two distinct classes: those that modify the chemical composition of the pyrolysis oil, making it less reactive; and those that remove destabilizing components from the pyrolysis oil. During the project, the team investigated methods from both classes that were suitable for application in each stage of the pyrolysis process. The post processing stabilization effort performed at PNNL is described in this report. The effort reported here was performed under a CRADA between PNNL and UOP, which was effective on March 13, 2009, for 2 years and was subsequently modified March 8, 2011, to extend the term to December 31, 2011.

  20. World oil prices: Up or down in 1995? and beyond?

    International Nuclear Information System (INIS)

    Browning, R.E.

    1994-01-01

    After a brief review of historical oil prices up to 1993-94, the factors influencing future prices are discussed. A survey of oil supply and demand over 1986-1993 shows oil demand has risen in Asia and fallen in the former Soviet Union and central/eastern Europe (FSU/CEE). Non-OPEC oil supply fell from 42.1 million bbl/d (MMBD) in 1986 to 40.6 MMBD in 1993, reflecting declines in Russian and U.S. production. Total OPEC production rose in the same period from 18.3 MMBD to 24.7 MMBD. OPEC production will continue to be dominant in determining prices, and demand in growing Asian economies and the FSU/CEE countries will be the most important and uncertain demand-side factor. If 7.5 MMBD of new OPEC capacity comes on stream by 2000 and OPEC production averages 31 MMBD in 2000, the utilization rate for OPEC oil at that time would be about the same as in 1973-79 and 1994. World oil production costs vary considerably by region, with the USA, North Sea, and Canada having relatively high costs; yet even in those regions, costs have been declining. A global weighted average cost based on 1993 production is $8-9/bbl. Fiscal and financial factors affecting oil prices include the need for oil revenue among oil producers. This need will put pressure on FSU economies to continue exports, although increases in such exports will require new infrastructure. In any case, the world oil market is likely to see a continuing trend to regarding oil as a commodity, which tends to reduce the control that physical participants exert on price-setting. Long-term real prices are not expected to rise but will likely remain volatile, cycling around $13/bbl. Spot prices in 1995 for West Texas Intermediate are forecast to be in the $16-20/bbl range. 4 figs., 4 tabs

  1. Oxidative stability of fish oil enriched drinking yoghurt

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall; Debnath, D.; Jacobsen, Charlotte

    2007-01-01

    The oxidative stability of fish oil enriched drinking yoghurt as well as the antioxidative effect of citric acid ester, vitamin K and disodium ethylenediaminetetraacetic acid (EDTA) were investigated by measuring peroxide value and volatile secondary oxidation products and by sensory analysis....... No oxidation was observed in yoghurt stored at 2 [degree sign]C for up to 19 days, with or without addition of citric acid ester. Fish oil enriched yoghurt was also very stable even when compared to yoghurt with added rapeseed oil or a mixture of rapeseed oil and fish oil stored for up to 29 days. The addition...

  2. World oil and agricultural commodity prices: Evidence from nonlinear causality

    International Nuclear Information System (INIS)

    Nazlioglu, Saban

    2011-01-01

    The increasing co-movements between the world oil and agricultural commodity prices have renewed interest in determining price transmission from oil prices to those of agricultural commodities. This study extends the literature on the oil-agricultural commodity prices nexus, which particularly concentrates on nonlinear causal relationships between the world oil and three key agricultural commodity prices (corn, soybeans, and wheat). To this end, the linear causality approach of Toda-Yamamoto and the nonparametric causality method of Diks-Panchenko are applied to the weekly data spanning from 1994 to 2010. The linear causality analysis indicates that the oil prices and the agricultural commodity prices do not influence each other, which supports evidence on the neutrality hypothesis. In contrast, the nonlinear causality analysis shows that: (i) there are nonlinear feedbacks between the oil and the agricultural prices, and (ii) there is a persistent unidirectional nonlinear causality running from the oil prices to the corn and to the soybeans prices. The findings from the nonlinear causality analysis therefore provide clues for better understanding the recent dynamics of the agricultural commodity prices and some policy implications for policy makers, farmers, and global investors. This study also suggests the directions for future studies. - Research highlights: → This study determines the price transmission mechanisms between the world oil and three key agricultural commodity prices (corn, soybeans, and wheat). → The linear and nonlinear cointegration and causality methods are carried out. → The linear causality analysis supports evidence on the neutrality hypothesis. → The nonlinear causality analysis shows that there is a persistent unidirectional causality from the oil prices to the corn and to the soybeans prices.

  3. Stability of traditionally processed vegetable oils and their blends ...

    African Journals Online (AJOL)

    ajol.info/index.php/ijbcs http://indexmedicus.afro.who.int. Stability of traditionally processed vegetable oils and their blends under different storage conditions. Faustine N. NGASSAPA1, Tupeligwe R. MWAISAKA2 and Stephen S. NYANDORO1*.

  4. Record world-wide oil spills in 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    Record world-wide oil spills in 1979 were reported by the U.K. Advisory Committee on Oil Pollution of the Sea (ACOPS), largely due to the 140 million gal Ixtoc I spill. Loss of life associated with oil production and transportation in 1979 was over 300, double the 1978 casualties. The French tanker Betelgeuse which exploded in Bantry Bay claimed 51 lives; the Independent collision in the Bosphorus claimed 40. In 1980, 100 lives were lost in the Ekofisk field in March. About 568 minor spillages were reported to the ACOPS, with on incident, the wreck of the Skopelas Sky off Cornwall involving 1000 tons of oil. Oil pollution has also increased in the Orkney and Shetland Islands. Seabird losses have caused considerable concern. ACOPS chairman Lord Ritchie-Calder has called for the European Community to strengthen its control over substandard vessels and to enforce more effectively existing international agreements, a move supported by IMCO.

  5. Near-term world oil markets : economics, politics and prices

    International Nuclear Information System (INIS)

    Dwarkin, J.

    2002-01-01

    This paper discusses the three main factors that will determine how OPEC oil production will impact on energy markets. OPEC reassured the market in September 2001, following the terrorist attack in New York that it would not cut oil production, but by December 2001, OPEC was threatening that it would cut production unless many key non-OPEC producers collaborated to shore up prices. On January 1, 2002, OPEC members went ahead with a quota reduction, based on pledges of cuts from the non-OPEC oil exporting countries. World economies, oil demand, and the path which the U.S. economy will take during 2002 is critical in determining what happens next in terms of oil production from OPEC. Another important factor is knowing whether non-OPEC producers will actually cut output to a significant extent. The most critical factor will be the response by OPEC members if non-OPEC exporting countries do not keep their promise

  6. Chemical monitoring of the World Prodigy oil spill

    International Nuclear Information System (INIS)

    Cobb, D.J.; Fluck, S.J.; Lake, J.L.

    1990-01-01

    This paper describes the chemical monitoring efforts of the U.S. EPA's Environmental Research Laboratory in Narragansett, RI (ERLN) following the grounding and subsequent release of oil from the tanker World Prodigy. Discussions of the sampling sites, and the sampling and analytical protocols employed are included. The results of the chemical analyses are presented and discussed, with particular emphasis placed on the temporal and vertical profiles of oil in the Bay. The aliphatic and aromatic composition of the spilled oil is also discussed. Finally, recommendations on the sampling plan, design, or implementation, or the chemical analysis are included

  7. Oil and gas financing by the World Bank

    International Nuclear Information System (INIS)

    Razavi, Hossein

    1995-01-01

    The World Bank has developed a flexible oil and gas programme that is structured to meet the changing needs of the sector as they arise. The Bank became prominent in the oil and gas sector after the oil crises of the 1970s, when it began assisting client countries in developing their indigenous energy resources. At the beginning, Bank lending concentrated on exploration and development of hydrocarbon resources where the level of lending expanded to US$1 billion in 1983. This rapid expansion caused some concern that Bank activities might preempt those of the private sector. In response, the Bank imposed in 1984 strict limitations on petroleum exploration and oil production lending. In combination with the perception that future oil demand would be weak, this caused the lending programme to fall off sharply (to US$300 million by 1986). By 1990, the Bank was again moving actively into hydrocarbon sector lending, but then the emphasis was on promoting private sector development and supporting the development of natural gas as a substitute for coal and oil. Bank lending to the sector has been on the increase since 1990; a lending level of about US$1 billion yearly is expected for the second half of the 1990s. In addition to its direct lending, the World Bank facilitates contributions by other financiers through its cofinancing and risk mitigation arrangements. (author)

  8. Stability of avocado oil during heating: comparative study to olive oil.

    Science.gov (United States)

    Berasategi, Izaskun; Barriuso, Blanca; Ansorena, Diana; Astiasarán, Iciar

    2012-05-01

    The stability of the saponifiable and unsaponifiable fractions of avocado oil, under a drastic heating treatment, was studied and compared to that of olive oil. Avocado and olive oil were characterised and compared at time 0h and after different times of heating process (180°C). PUFA/SFA (0.61 at t=0) and ω-6/ω-3 (14.05 at t=0) were higher in avocado oil than in olive oil during the whole experiment. Avocado oil was richer than olive oil in total phytosterols at time 0h (339.64; 228.27mg/100g) and at 9h (270.44; 210.30mg/100g) of heating. TBARs was higher in olive oil after 3h, reaching the maximum values in both oils at 6h of heating treatment. Vitamin E was higher in olive oil (35.52 vs. 24.5mg/100g) and it disappeared earlier in avocado oil (at 4 vs. 5h). The stability of avocado oil was similar to that of olive oil. Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. The relationship between SARA fractions and crude oil stability

    Directory of Open Access Journals (Sweden)

    Siavash Ashoori

    2017-03-01

    Full Text Available Asphaltene precipitation and deposition are drastic issues in the petroleum industry. Monitoring the asphaltene stability in crude oil is still a serious problem and has been subject of many studies. To investigate crude oil stability by saturate, aromatic, resin and asphaltene (SARA analysis seven types of crudes with different components were used. The applied methods for SARA quantification are IP-143 and ASTM D893-69 and the colloidal instability index (CII is computed from the SARA values as well. In comparison between CII results, the values of oil compositions demonstrated that the stability of asphaltenes in crude oils is a phenomenon that is related to all these components and it cannot be associated only with one of them, individually.

  10. Thermal stability of Vernonia galamensis seed oil

    Directory of Open Access Journals (Sweden)

    Benny M. Wamalwa

    2000-12-01

    Full Text Available The physicochemical changes of refined vernonia oil-RVO (which naturally contains epoxidized triglycerides upon heating was evaluated and is reported in this manuscript. A boiling point range of 183 °C to 190 °C (at 760 mm Hg for the vernonia oil was obtained using the Siwolobboff's method. The oil changed its physical appearance and consistency in the course of the heating. A homogenous free-flowing beige-sand shade refined vernonia oil at room temperature (25 °C was transformed irreversibly to an intense-brown shade, becoming increasingly more viscous with increase in temperature, and ceasing to flow momentarily at 188 °C. On cooling to room temperature, the oil solidified into a brown rubber-like elastic material. The oil also exhibited a reduction in its oxirane content from 1.39 plus or minus 0.004 equivalent HBr kg-l at 25 °C to 0.542 plus or minus 0.002 equivalent HBr kg-l at 70 °C. This signifies a 61% drop in oxirane content for the 45 °C temperature rise. These findings point towards a thermally driven polymerization and/or decomposition of the refined vernonia oil (RVO.

  11. World oil: the growing case for international policy

    International Nuclear Information System (INIS)

    Chapman, D.; Khanna, N.

    2000-01-01

    Can the economic theory of depletion be reconciled with low petroleum prices? This article uses a revision of the theory, which reflects demand functions that rise in response to increasing world population and income. The magnitude of producers' and consumers' surplus is estimated under both competitive and monopolistic assumptions; the result indicates a present value comparable to or in excess of today's gross world economic product. Game theory suggests a framework that explains the interaction between oil pricing and military policy, and the economic incentives that result in a general pattern of recent market equilibrium crude oil prices often fluctuating with a 15-20 US dollars per barrel range. The analysis concludes that the economic incentives for political instability in the Persian Gulf will increase, and more formal methods of setting the international framework for Persian Gulf oil may be expected. (author)

  12. 100 million refugees. The world stabilizes through population stability.

    Science.gov (United States)

    Sakaiya, T

    1993-09-01

    Global change has come about due to shifts in the business cycle, a new undeveloped paradigm to replace the Cold War, and a stabilization of expansion and development of modern industrial society. Japan has been transfixed with its own internal domestic affairs, but will feel the consequences of the Industrial Age nearing its end. Industrialization had relied on unlimited resources from the natural environment and the belief that a free-market economy would automatically lead to orderliness and a state of economic equilibrium. Population control has been an issue that has slid over the years as a priority status. In 1800, the population in developed countries was 4 times the population in developing countries; the reverse is becoming true. Mass migration was an unusual phenomena and not the problem it is today. There is a gap between population and productive capacity. Developed countries believed in humanitarian aid for refugees and impoverished peoples, but the numbers were unanticipated. There is no shame for war or civil unrest to drive boat people and hugh numbers to another country. The notion of nation state has changed. The boat people from Cuba were a beginning example of how governments were unconcerned about the loss of population. Afghanistan in 1979 was another example of refugees fleeing civil war. Iraq bombed the Kurds until there was no choice but to leave. Turkey was required to use troops to drive the Kurds back into Iraq. To increase aid indefinitely, or to send out more refugees than it takes in, or to use military forces to kill the invading refugees are not acceptable. An international framework with consensus from developed and developing countries is needed for dealing with mass migrations. Conventions adopted would have to be recognized as in each countries self-interest; disregard of the regulations would have to reflect significant disadvantages to a nation. Several issues are discussed as key in such a global framework: assuring

  13. World Economic Growth and Oil: a Producers' Perspective

    Science.gov (United States)

    Shihab-Eldin, Adnan

    2014-07-01

    This paper examines the following assertions: * A high share of oil price in GDP limits economic growth, * Oil Price shocks trigger recession, * These effects will be escalated by peaked oil supply and rising developing world demand and together with increasing contributions to climate change will result in a global emergency. The role of energy in societal development and economic growth, from primitive man through the industrial revolution and the oil age to the present and the evolution of energy intensity are described. The principle role of oil as a transport fuel and the possibilities of alternatives are examined. It is concluded that oil dependence will continue for the foreseeable future. The history of the industry, market behavior and its economic effects are presented to establish precedent and the assertions are then examined. It is shown that rising oil prices are an unavoidable consequence of economic growth, that they have stimulated efficient minimum functional use and made more difficult conventional and unconventional sources economic. It is then argued that potentially these additional resources eliminate the possibility of supply shortage and that diversification of supply lessens the possibility of shock, together rendering a global emergency less likely than could have been previously envisaged.

  14. Stability analysis of oil yield in oil palm (Elaeis guineensis) progenies in different environments.

    Science.gov (United States)

    Rafii, M Y; Jalani, B S; Rajanaidu, N; Kushairi, A; Puteh, A; Latif, M A

    2012-10-04

    We evaluated 38 dura x pisifera (DP) oil palm progenies in four locations in Malaysia for genotype by environment interaction and genotypic stability studies. The DP progenies derived from crosses between pisifera palms of AVROS, Serdang S27B, Serdang 29/36, and Lever Cameroon were chosen to be the males' parent and Deli dura palms designated as females' parent. All the locations differed in terms of soil physical and chemical properties, and the soil types ranged from coastal clay to inland soils. The genotype by environment interaction and stability of the individual genotypes were analyzed for oil yield trait using several stability techniques. A genotype by environment interaction was detected for oil yield and it had a larger variance component than genotypic variance (σ(2)(gl)/σ(2)(g) = 139.7%). Genotype by environment interaction of oil yield was largely explained by a non-linear relationship between genotypic and environmental values. Overall assessment of individual genotypic stability showed that seven genotypes were highly stable and had consistent performance over the environments for the oil yield trait [total individual genotype stability scored more than 10 and mean oil yielded above the average of the environment (genotype means are more than 34.37 kg·palm(-1)·year(-1))]. These genotypes will be useful for oil palm breeding and tissue culture programs for developing high oil yielding planting materials with stable performance.

  15. Stabilization of biomass-derived pyrolysis oils

    NARCIS (Netherlands)

    Venderbosch, R. H.; Ardiyanti, A. R.; Wildschut, J.; Oasmaa, A.; Heeres, H. J.

    BACKGROUND: Biomass is the only renewable feedstock containing carbon, and therefore the only alternative to fossil-derived crude oil derivatives. However, the main problems concerning the application of biomass for biofuels and bio-based chemicals are related to transport and handling, the limited

  16. on the oxidation stability of lubricating oil

    African Journals Online (AJOL)

    DJFLEX

    The internal combustion engine is a model oxidator, since it contains a hydrocarbon motor oil with air under agitation at high temperatures. In addition, metals such as copper, lead, nickel, chromium and iron, used for the manufacture of the engines, are effective oxidation catalysts which increases the rate of oxidation. The.

  17. Oxidative stability, thermal stability and acceptability of coconut oil flavored with essential oils from black pepper and ginger.

    Science.gov (United States)

    Chandran, Janu; Nayana, N; Roshini, N; Nisha, P

    2017-01-01

    The present study investigates the oxidative and thermal stability of flavoured oils developed by incorporating essential oils from black pepper and ginger to coconut oil (CNO) at concentrations of 0.1 and 1.0% (CNO P-0.1 , CNO P-1 , CNO G-0.1 , CNO G-1 ). The stability of oils were assessed in terms of free fatty acids, peroxide, p -anisidine, conjugated diene and triene values and compared with CNO without any additives and a positive control with synthetic antioxidant TBHQ (CNO T ). It was found that the stability of CNO P-1 and CNO G-1 were comparable with CNO T at both study conditions. The possibility of flavoured oil as a table top salad oil was explored by incorporating the same in vegetable salad and was found more acceptable than the control, on sensory evaluation. The synergetic effect of essential oil as a flavour enhancer and a powerful natural antioxidant that can slow down the oxidation of fats was established in the study.

  18. The impact of the Gulf crisis on world oil and OPEC

    International Nuclear Information System (INIS)

    Mabro, R.

    1994-01-01

    The 1990-91 Gulf conflict involved oil as a major factor or significant objective from the viewpoint of all countries involved. Low oil prices, favored by Kuwait, limited Iraqi revenues. Iraq pressed the Organization of Petroleum Exporting Countries (OPEC) to raise oil prices, leading to tensions with Kuwait, with which Iraq also had long-standing territorial claims. The desire to protect access to the world's largest oil supplies was a factor in the USA's rapid reaction to the Iraqi invasion of Kuwait in August 1990. The initial response was an embargo on exports from Iraq and occupied Kuwait; this removed from the world oil market an estimated 4.5-5 million bbl/d. Although the spot price of oil rose to $27/bbl two weeks after the invasion, the market had significant supply-side flexibility. Major increases in output from Saudi Arabia and the United Arab Emirates almost entirely compensated for the lost production, stopping the upward movement of oil prices. These peaked in September 1990, stabilized, and fell dramatically in January 1991. The fall was helped by speculator selloffs, the perception that Iraq would soon be defeated under the recently begun air attacks, and the USA decision to sell from its strategic reserves. One effect of the crisis was a disturbance of output distribution among OPEC members; the Saudis and Emirates were unwillling to give up higher output levels to accommodate the return of Kuwait, thus making OPEC production quotas more difficult to achieve. Another effect was an increase in the political dependence of the Arab Gulf countries on the Western powers, particularly the USA, as the only credible guarantor of regional security. This further inhibits moves by OPEC to control oil prices or production

  19. Stability studies on refined soybean oil stored in various conditions

    International Nuclear Information System (INIS)

    Arawande, J.O.; Amoo, I.A.

    2008-01-01

    The 12 months stability study of freshly produced refined soybean oil revealed that refined soybean oil stored in plastic containers in dark was more hydrolytically and oxidatively stable than that stored in other containers in light condition. There was no significant difference at P < 0.05 in free fatty acids and acid value of oil stored under light and dark conditions in tin and glass containers but there was significant difference at P < 0.05 in peroxide value of oil stored in light and dark conditions in all the storage containers. Light increased the degree of oxidative rancidity of refined soybean oil, the most in tin containers, followed by glass containers and the least in plastic containers. (author)

  20. A literature review of demand studies in world oil markets

    International Nuclear Information System (INIS)

    Atkins, F.; Tayyebi Jazayeri, S.M.

    2004-04-01

    The literature on world oil market demands was reviewed, summarized and organized into seven major groupings. The objective was to model economic behaviour before and after price shocks. In particular, the paper demonstrated how the price elasticity of demand in world oil markets is estimated. It also showed how the relationship between energy and oil consumption and income are estimated. The income elasticity of demand was also estimated, and empirical estimates of the elasticity of aggregate output regarding crude oil and energy prices were presented. The paper also referred to the transportation sector and estimates of the changing nature of seasonal factors. The review showed that there is much heterogeneity of econometric results. The literature showed that demand increased considerably in response to the price shocks of the 1970s, but these shocks were reversed in the 1980s when the increase in demand did not correspond with the decrease in price. Some of the literature is driven by the belief that there must be a stable, non-linear model that fits the data both before and after price shocks. The authors question whether this could be true and propose an alternative hypothesis that there is a different model that pertains to economic behaviour after price shocks. 15 refs., 7 tabs., 1 fig

  1. Outlook for world oil supply and demand through 1983

    Energy Technology Data Exchange (ETDEWEB)

    Brodman, J.; Moore, J.

    The relative favorable near-term outlook calls for declining world demand, continued growth in non-OPEC oil supplies, and a continued inventory surplus unless there is an unexpected supply surplus. The authors identify the Iran-Iraq conflict, Saudi Arabian price and production policies, inventory policies, economic recovery, and political developments in eastern Europe, Libya, and elsewhere in the Middle East as the major uncertainties that could affect this outlook. 2 figures, 4 tables.

  2. Comparison of soybean oils, gum, and defatted soy flour extract in stabilizing menhaden oil during heating.

    Science.gov (United States)

    Yue, X; Xu, Z; Prinyawiwatkul, W; Losso, J N; King, J M; Godber, J S

    2008-01-01

    Capabilities of crude soy oil, degummed oil, gum, and defatted soy flour extract in preventing the oxidation of menhaden oil and its omega-3 fatty acids, DHA (docosahexaenoic acid) and EPA (eicosapentaenoic acid), during heating were evaluated. The menhaden oil mixed with defatted soy flour extract demonstrated the greatest stability by producing the lowest TBA reactive oxidation products and retaining the highest concentrations of DHA and EPA after heating at 150 degrees C for 30 min. A range of 62.8% to 71.5% of DHA and 67.7% to 75.9% of EPA remained in the fish oil with defatted soy flour extract, while only 29.9% of DHA and 37.2% of EPA were retained in the fish oil with no addition. Stabilizing capability from highest to lowest was defatted flour extract > gum > degummed oil = crude oil. The defatted flour extract had the highest level of total phenolic content (11.3 microg catechin equivalent/g), while crude oil, degummed oil, and gum contained 7.1, 6.1, and 6.0 microg catechin equivalent/g, respectively. The level of isoflavones in the defatted soy flour extract was 55 mg/g, which was over 100 times higher than in the crude oil or gum. Although isoflavones were not detected in the degummed oil, it contained the highest level of tocopherols (414 mug/g), whereas the lowest level (215 microg/g) was found in the defatted flour extract. The order of free radical scavenging capability measured from high to low was the defatted soy flour extract, crude oil, degummed oil, and gum.

  3. Energetic dependency on the oil reserve- resources of crude oil in the world

    Directory of Open Access Journals (Sweden)

    Marína Sidorová

    2006-10-01

    Full Text Available Crude oil belongs to the most important energy resources nowadays., However its reserves are the smallest in comparison with other energy resources as coal, gas or uranium. The world oil consumption continuously increases and within 20-year period there could be about one third. So, the consumption of combustibles will probably increase and the reserves will decrease. Promising are new resources or a better utilization of primary sources. It´s a question of a short time when world scientists should think about this indisputably worldwide problem and would provide an equivalent substitution with an available ecological solution.

  4. Taxing the difference: World oil market projections 1994-2009

    International Nuclear Information System (INIS)

    Reinsch, A.E.; Considine, J.I.; MacKay, E.J.

    1994-01-01

    The likely impacts of key uncertainties affecting the oil market were assessed, and reference price path to aid industry and governments in their investment and policy decisions, was provided. The reference market outlook corresponded to an annual growth of around 1.5% and a price of $ 18.00 per barrel. The greatest weakness of the market projections were found to be the expected performance of petroleum product demand growth. There was strong evidence that governments of major oil consuming countries had taken action to weaken the response of petroleum product demand to declines in the crude price, by driving an ever increasing fiscal wedge between the crude price and the corresponding product prices.The outcome is an asymmetry in demand response to crude price movements. Incorporation of this asymmetry into the world oil market model could have some disturbing results: under the reference case market assumptions, continuation of this tax and pricing policy would not only eliminate the price gains projected, but move the oil price below current levels on a sustained basis. The study concluded that OPEC members and the governments of the major industrialized oil consuming countries should strive to reach an agreement to avoid catastrophic price instability. refs., tabs., figs

  5. Chemical and biological observations after the World Prodigy oil spill

    International Nuclear Information System (INIS)

    Pilson, M.E.Q.

    1990-01-01

    The Greek tanker World Prodigy ran aground on Brenton Reef, Rhode Island, in the afternoon of June 23, 1989, releasing 922 metric tons. This paper reports that the Coast Guard estimated that by the fourth day after the spill some 99% of the oil had disappeared, largely through evaporation. Oil that was dissolved in the water probably disappeared by microbial metabolism and photochemical oxidation at a rate of about 0.5 per day. Precautionary closures of the shell fish beds in the upper bay were lifted within about a week, and there was no evidence suggesting tainting of shellfish. Also, there was no evidence suggesting any tainting go finfish, and no evidence suggesting any mortality of free-swimming finfish. Retrospectively, it is evident that our knowledge of the fate and effects of the oil could have been greatly improved by sampling and analysis of the oil slick itself, by more analyses for oil in the water column, and by longer-term monitoring of the benthic animals in impacted areas

  6. Kolkhoung (Pistacia khinjuk Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability and Nutritional Value

    Directory of Open Access Journals (Sweden)

    Maryam Asnaashari

    2015-01-01

    Full Text Available In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high–performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well-balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation–sensitive oils to improve their shelf life.

  7. Stabilization of soybean oil during accelerated storage by essential oil of ferulago angulata boiss.

    Science.gov (United States)

    Sadeghi, Ehsan; Mahtabani, Aidin; Etminan, Alireza; Karami, Farahnaz

    2016-02-01

    This study has been considered effect of Ferulago angulata essential oil on stabilizing soybean oil during accelerated storage. The essential oil was extracted by Clevenger-type apparatus. For analysis of the essential oil, GC/MS was used. Main components of the essential oil were monoterpene and sesquiterpene hydrocarbons. The essential oil of F. angulata at four concentrations, i.e. 125 (SBO-125), 250 (SBO-250), 500 (SBO-500) and SBO-Mixture (60 ppm TBHQ +60 ppm essential oil) were added to preheated refined soybean oil. TBHQ was used at 120 ppm as standard besides the control. Antioxidant activity index (AAI), free fatty acid (FFA) content, peroxide value (PV) and p-anisidine value (p-AnV) were served for appreciation of efficacy of F. angulata in stabilization of soybean oil. Results from different tests showed that SBO-mixture had highest effect and followed by SBO-TBHQ, SBO-250, SBO-125, SBO-500 and Ctrl. These results reveal F. angulata is a strong antioxidant and can be used instead of synthetic antioxidant.

  8. Stability of cosmetic emulsion containing different amount of hemp oil.

    Science.gov (United States)

    Kowalska, M; Ziomek, M; Żbikowska, A

    2015-08-01

    The aim of the study was to determine the optimal conditions, that is the content of hemp oil and time of homogenization to obtain stable dispersion systems. For this purpose, six emulsions were prepared, their stability was examined empirically and the most correctly formulated emulsion composition was determined using a computer simulation. Variable parameters (oil content and homogenization time) were indicated by the optimization software based on Kleeman's method. Physical properties of the synthesized emulsions were studied by numerous techniques involving particle size analysis, optical microscopy, Turbiscan test and viscosity of emulsions. The emulsion containing 50 g of oil and being homogenized for 6 min had the highest stability. Empirically determined parameters proved to be consistent with the results obtained using the computer software. The computer simulation showed that the most stable emulsion should contain from 30 to 50 g of oil and should be homogenized for 2.5-6 min. The computer software based on Kleeman's method proved to be useful for quick optimization of the composition and production parameters of stable emulsion systems. Moreover, obtaining an emulsion system with proper stability justifies further research extended with sensory analysis, which will allow the application of such systems (containing hemp oil, beneficial for skin) in the cosmetic industry. © 2015 Society of Cosmetic Scientists and the Société Française de Cosmétologie.

  9. Formulation and stability of topical water in oil emulsion containing ...

    African Journals Online (AJOL)

    Purpose: To formulate the water in oil (W/O) emulsion of corn silk (CS) extract and to evaluate its stability at various storage conditions. Methods: Ethanol CS extract was prepared using maceration (cold) technique. A 4 % CS emulsion was prepared using varying concentrations of liquid paraffin, ABIL EM90 and water.

  10. Stress determination and geomechanical stability analysis of an oil ...

    Indian Academy of Sciences (India)

    In this paper, a numerical model using three-dimensional finite difference code FLAC3D is proposed for analysing the stability of an oil well drilled in four formations. Normalized Yielded Zone Area (NYZA, i.e., the ratio of surrounding yielded cross-sectional area to initial area of well) has been determined for different mud ...

  11. Stability of wheat germ oil obtained by supercritical carbon dioxide ...

    African Journals Online (AJOL)

    심정은

    For determination of stability, wheat germ oil obtained by ethanolysis reactants was characterized by ... extract non polar lipids with lipid soluble bioactive com- pounds from different sources (Esquivel et al., 1997; ... thin layer of cotton was placed at the bottom of the extraction vessel. Before plugging with cap another layer of ...

  12. Oil Extraction from “Morelos Rice” Bran: Kinetics and Raw Oil Stability

    Directory of Open Access Journals (Sweden)

    J. Zúñiga-Diaz

    2017-01-01

    Full Text Available “Morelos rice” is a variety of rice with certificate of denomination of origin. It is a large grain of opaque appearance and extra large size that is grown exclusively in Morelos state (Mexico. Thus, the quality and characteristics of its rice bran may affect the kinetic of the extraction process of its oil as well as its stability. Therefore, this work is oriented to determine the extraction kinetics of its oil and its oxidative stability. The latter one is obtained through the proposal of a method based on open-circuit potential measurements. The results showed that the rice bran has 21.44% of raw oil, with a chemical composition (based on fatty acids of 48.48% oleic acid, 35.26% linoleic acid, and 14.54% palmitic acid, as well as a free fatty acid content of 8.15%. A high percentage of its oil content can be recovered in a short time at room temperature, and its extraction kinetics is a function of both the washing and the diffusion of its oil. Under storage conditions the raw oil has a high stability, at least 8 months, and its oxidative stability was of 24, 9, and 7 hours at 50°C, 80°C, and 110°C, respectively.

  13. Big questions cloud Iraq's future role in world oil market

    International Nuclear Information System (INIS)

    Tippee, B.

    1992-01-01

    This paper reports that Iraq raises questions for the world oil market beyond those frequently asked about when and under what circumstances it will resume exports. Two wars since 1981 have obscured encouraging results from a 20 year exploration program that were only beginning to come to light when Iraq invaded Kuwait in August 1990. Those results indicate the country might someday be able to produce much more than the 3.2 million b/d it was flowing before a United Nations embargo blocked exports. If exploratory potential is anywhere near what officials asserted in the late 1980s, and if Iraq eventually turns hospitable to international capital, the country could become a world class opportunity for oil companies as well as an exporter with productive capacity approaching that of Saudi Arabia. But political conditions can change quickly. Under a new, secular regime, Iraq might welcome non-Iraqi oil companies and capital as essential to economic recovery. It's a prospect that warrants a new industry look at what the country has revealed about its geology and exploration history

  14. Chemical properties and oxidative stability of Arjan (Amygdalus reuteri) kernel oil as emerging edible oil.

    Science.gov (United States)

    Tavakoli, Javad; Emadi, Teymour; Hashemi, Seyed Mohammad Bagher; Mousavi Khaneghah, Amin; Munekata, Paulo Eduardo Sichetti; Lorenzo, Jose Manuel; Brnčić, Mladen; Barba, Francisco J

    2018-05-01

    The oxidative stability, as well as the chemical composition of Amygdalus reuteri kernel oil (ARKO), were evaluated and compared to those of Amygdalus scoparia kernel oil (ASKO) and extra virgin olive oil (EVOO) during and after holding in the oven (170 °C for 8 h). The oxidative stability analysis was carried out by measuring the changes in conjugated dienes, carbonyl and acid values as well as oil/oxidative stability index and their correlation with the antioxidant compounds (tocopherol, polyphenols, and sterol compounds). The oleic acid was determined as the predominant fatty acid of ARKO (65.5%). Calculated oxidizability value and an iodine value of ARKO, ASKO and EVOO were reported as 3.29 and 3.24, 2.00 and 100.0, 101.4 and 81.9, respectively. Due to the high wax content (4.5% and 3.3%, respectively), the saponification number of ARKO and ASKO (96.4 and 99.8, respectively) was lower than that of EVOO (169.7). ARKO had the highest oxidative stability, followed by ASKO and EVOO. Therefore, ARKO can be introduced as a new source of edible oil with high oxidative stability. Copyright © 2018. Published by Elsevier Ltd.

  15. Pollination networks of oil-flowers: a tiny world within the smallest of all worlds.

    Science.gov (United States)

    Bezerra, Elisângela L S; Machado, Isabel C; Mello, Marco A R

    2009-09-01

    1. In the Neotropics, most plants depend on animals for pollination. Solitary bees are the most important vectors, and among them members of the tribe Centridini depend on oil from flowers (mainly Malpighiaceae) to feed their larvae. This specialized relationship within 'the smallest of all worlds' (a whole pollination network) could result in a 'tiny world' different from the whole system. This 'tiny world' would have higher nestedness, shorter path lengths, lower modularity and higher resilience if compared with the whole pollination network. 2. In the present study, we contrasted a network of oil-flowers and their visitors from a Brazilian steppe ('caatinga') to whole pollination networks from all over the world. 3. A network approach was used to measure network structure and, finally, to test fragility. The oil-flower network studied was more nested (NODF = 0.84, N = 0.96) than all of the whole pollination networks studied. Average path lengths in the two-mode network were shorter (one node, both for bee and plant one-mode network projections) and modularity was lower (M = 0.22 and four modules) than in all of the whole pollination networks. Extinctions had no or small effects on the network structure, with an average change in nestedness smaller than 2% in most of the cases studied; and only two species caused coextinctions. The higher the degree of the removed species, the stronger the effect and the higher the probability of a decrease in nestedness. 4. We conclude that the oil-flower subweb is more cohesive and resilient than whole pollination networks. Therefore, the Malpighiaceae have a robust pollination service in the Neotropics. Our findings reinforce the hypothesis that each ecological service is in fact a mosaic of different subservices with a hierarchical structure ('webs within webs').

  16. Natural antioxidants in the stability of ray liver oil

    Directory of Open Access Journals (Sweden)

    Gerardo Navarro-García

    Full Text Available ABSTRACT: The effect of the addition of natural antioxidants on oxidative stability of ray ( Rhinoptera bonasus liver oil was evaluated. Different concentrations of rosemary extract, α-tocopherol, and caffeic acid (w/w were added to the oil. Afterwards, concentration of each antioxidant that gave the highest stability was used in an accelerated stability test (Schaal method. The protective effect was established by the retention in the oil of fatty acids eicosapentaenoic (EPA and docosahexaenoic (DHA, and concentration of volatile compounds. The best concentrations were: 2.5% of rosemary extract, 0.5% of α-tocopherol, and 0.06% of caffeic acid. Rosemary extract showed to be the product with the greatest ability to retard oxidation, followed by α-tocopherol, and caffeic acid. A high correlation between the peroxide value and the concentration of the 2-decenal, 1-penten-3-ol, and 2-octenal, was reported, suggesting that this can be used to assess the development of oxidative rancidity in the ray liver oil.

  17. Proceedings of the workshop on world oil supply-demand analysis

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, K.C. (ed.)

    1977-01-01

    Twelve papers and four panel discussions are included. A separate abstract was prepared for each paper. The panel discussions were on: technical and physical policy elements affecting world oil supply and demand; financial, tax, and tariff issues in world oil supply and demand; the world economy as influenced by world oil prices and availability; the use of models and analysis in the policy process. (DLC)

  18. Factors affecting world and Russian domestic oil prices: the domestic implications - a Russian perspective

    International Nuclear Information System (INIS)

    Khartukov, E.M.

    2001-01-01

    This paper modestly aims at answering two formally related but unnecessarily interconnected questions about international and Russian domestic pricing of crude oil. The first of them is what, in our opinion, chiefly determines price dynamics of the contemporary world oil market. And the second one is in which way (if at all) world oil price dynamics affect Russia's internal market. (author)

  19. The united states and the world oil security. US oil policy and production of a global collective good

    International Nuclear Information System (INIS)

    Noel, P.

    2004-07-01

    The aim of this paper is to define and discusses the part of the Unites States in the world oil system operating and more particularly the US oil security policy in the world policy. It refutes some established ideas as the necessity of the US military supremacy to provide the oil security, the necessity of ''agreements'' with oil exporting countries facing the US energy consumption increase or the limitation of the resources access to other countries. At the opposite the United States seem to invest in the production of a global public good in matter of energy security. In order to illustrate this opinion the author defines the problem of the US oil security in a world context. He analyzes then the US policies to show the impacts in the world oil security and studies the specific part of the military factor in the security policy. (A.L.B.)

  20. Oxidative stability of pullulan electrospun fibers containing fish oil

    DEFF Research Database (Denmark)

    García Moreno, Pedro Jesús; Damberg, Cecilie; Chronakis, Ioannis S.

    2017-01-01

    stability of fibers loaded with 10wt% fish oil (EE=88.5±0.7%) was significantly improved when adding δ-tocopherol (500ppm) and rosemary extract (500ppm) as antioxidants. However, higher concentration of antioxidants (2000ppm δ-tocopherol and 1000ppm rosemary extract) did not further improve the oxidative...... for fibers without and with antioxidants (500ppm of δ-tocopherol and 500ppm of rosemary extract). Practical applications: Encapsulation of omega-3 polyunsaturated fatty acids and addition of antioxidants are the most efficient strategies to protect these lipids against oxidation when incorporating them...... into food matrices. These results show the feasibility to encapsulate fish oil in pullulan ultra-thin fibers and to improve their oxidative stability by adding natural antioxidants such as δ-tocopherol and rosemary extract. Therefore, this study might open up new opportunities for further technological...

  1. World oil production. [Demand to overshadow supplies before year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Flower, A.R.

    1978-03-01

    The supply of oil will fail to meet increasing demand before the year 2000. As oil production inevitably levels off and then falls, alternative fuels will have to meet the demand for energy, which will continue to grow in the face of even vigorous attempts at conservation. The oil-importing countries have perhaps as few as five years or perhaps as many as 20 in which to accomplish a transition from dependence on oil to greater reliance on other fossil fuels, on nuclear energy and eventually on renewable energy sources. Because large investments and long lead times are required for developing new energy resources the effort must begin immediately. These are among the major conclusions of a two-year international study, the Workshop on Alternative Energy Strategies. The workshop participants came from the U.S., Canada, Mexico, Venezuela, the United Kingdom, France, West Germany, the Netherlands, Denmark, Sweden, Norway, Finland, Italy, Iran, and Japan. The workshop developed projections of energy supply and demand under various assumptions, notably concerning economic growth and the price of energy. Two basic scenarios were formulated, one assuming a high economic growth rate and high energy prices and the other a low growth rate and constant prices. The high-growth, high-price scenario assumed that economic growth in the non-Communist world would average 5.2% per year between 1976 and 1985 and 4% between 1985 and 2000, and that energy prices would remain constant (in real terms) until 1985 and increase 50% by 2000. The low-growth, constant-price scenario assumed that economic growth would average 3.4% per year until 1985 and then 2.8% until 2000, and that real energy prices would remain constant during the entire period. Within that framework energy-demand forecasts were prepared for the various regions for each fuel and were aggregated to project the total energy demand in 1985 and 2000.

  2. Modelling the world oil market: Assessment of a quarterly econometric model

    International Nuclear Information System (INIS)

    Dees, Stephane; Karadeloglou, Pavlos; Kaufmann, Robert K.; Sanchez, Marcelo

    2007-01-01

    This paper describes a structural econometric model of the world oil market that can be used to analyse oil market developments and risks. Oil demand depends on domestic economic activity and the real price of oil. Oil supply for non-OPEC producers, based on competitive behaviours, is constrained by geological and institutional conditions. Oil prices are determined by a 'price rule' that includes market conditions and OPEC behaviour. Policy simulations indicate that oil demand and non-OPEC supply are rather inelastic to changes in price, while OPEC decisions about quota and capacity utilisation have a significant, immediate impact on oil prices

  3. Effects of Resin Refining on the Chemical and Physical Stability of Sardine Oils

    OpenAIRE

    Irianto, Hari Eko

    2014-01-01

    The effect of resin refining on the stability of sardine oil was studied. Fish canning waste oil and fish meal processing waste oil were used in the experiment. The oils were refined by passing through the resin packed column at fish oil and resin ration of 1 : 1.            The fish oil stability was investigated using Schaal oven method by placing the oil in an oven at 63 ± 2oC and the sample was withdrawn after 0, 2, 4, 7 and 11 days. Resin refining improved fish oil quality as indicated b...

  4. Marine Lipids (Omega-3 Oil) - Stability of Oil and Enriched Products During Production and Storage

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall

    2015-01-01

    is prevented both during production and storage. In complex products, lipid oxidation and antioxidant mechanisms are very complex, due to the many factors that can influence the rate and extent of lipid oxidation. In order to obtain and maintain a good quality and oxidative stability of omega-3 oil...

  5. The World Oil Market: The Search for Balance in the New “Oil” Reality

    OpenAIRE

    Tatjiana A. Malova; Victoria I. Sisoeva

    2016-01-01

    The article provides an analysis of change of the world oil market in the face of new "oil" reality. Factors of formation of new "oil" reality in the global world defined. Scientific background and current state of research of the problem are described. It is shownthat in the Russian and foreign literature the considerable attention is paid to the analysis of dynamics of the quantitative variables characterizing fluctuations and shocks in the oil market. At the same time the search for balanc...

  6. Markets during world oil supply crises: an analysis of industry, consumer, and governmental response

    Energy Technology Data Exchange (ETDEWEB)

    Erfle, Stephen; Pound, John; Kalt, Joseph

    1981-04-01

    An analysis of the response of American markets to supply crises in world oil markets is presented. It addresses four main issues: the efficiency of the operation of American oil markets during oil supply crises; the problems of both economic efficiency and social equity which arise during the American adaptation process; the propriety of the Federal government's past policy responses to these problems; and the relationship between perceptions of the problems caused by world oil crises and the real economic natures of these problems. Specifically, Chapter 1 presents a theoretical discussion of the effects of a world supply disruption on the price level and supply availability of the world market oil to any consuming country including the US Chapter 2 provides a theoretical and empirical analysis of the efficiency of the adaptations of US oil product markets to higher world oil prices. Chapter 3 examines the responses of various groups of US oil firms to the alterations observed in world markets, while Chapter 4 presents a theoretical explanation for the price-lagging behavior exhibited by firms in the US oil industry. Chapter 5 addresses the nature of both real and imagined oil market problems in the US during periods of world oil market transition. (MCW)

  7. The integration of China into the world crude oil market since 1998

    International Nuclear Information System (INIS)

    Li, Raymond; Leung, Guy C.K.

    2011-01-01

    The integration of China into the world oil market is an important issue for at least two reasons. First, the influence of the country on the world oil market is dependent on the level of the integration. Second, integration into the world oil market means that China is opening itself up to potential disturbances in the world market and this leads to significant energy security concerns for the country. The aim of this paper is to investigate whether or not China is an integral part of the world oil market. By reviewing the relevant trade and pricing policies of the Chinese government as well as the behavior of the Chinese national oil companies, we find that China is actively engaging itself in the world oil market. Our time-series results show that the Chinese oil price is cointegrated with the major oil prices in the world and a high degree of co-movement between the prices is found. Causality between the price pairs is found to be bi-directional in most cases. The empirical results suggest that China is now an integral part of the world oil market. - Highlights: → Review of the oil trade and pricing policies of the Chinese government. → Review of the behavior of the Chinese national oil companies. → China is actively engaging itself in the world oil market. → Shipment data show that China can no longer be regarded as a separate market. → Strong co-movement between the Chinese oil price and the international oil prices.

  8. CEO's guide to world business costs : oil and gas equipment

    International Nuclear Information System (INIS)

    2004-01-01

    This paper presents the results of a detailed study of wellhead equipment manufacturing costs in 11 countries in North America, Europe and Asia-Pacific. According to the Economist Intelligence Unit (EIU), Canada has a 5 per cent cost advantage and will be the best country in the world to do business between 2004 to 2008 because of its foreign trade policies, high quality infrastructure and market opportunities within the North American marketplace. KPMG Consulting developed a web-based cost model that allows investors to examine the costs involved in setting up and operating a business in more than 120 cities in Canada, the United States, the United Kingdom, France, Germany, Italy, Iceland, Luxembourg, the Netherlands, Japan and Australia. According to the model, a comparison of annual costs for oil and gas wellhead equipment manufacturing was presented for the 11 countries with reference to revenues, costs, and profits before and after income tax. In addition, Canada's research and development (R and D) cost advantage compared to the United States was presented, with reference to tax credits, expenditures, salaries, contracts, capital equipment, volume-based tax credits, and research studies. This report also includes a brief summary of 3 oil and gas companies that came to Canada and prospered. tabs., figs

  9. Oxidative stability of biodiesel blends derived from waste frying oils

    Directory of Open Access Journals (Sweden)

    Michael Feroldi

    2017-07-01

    Full Text Available The high cost of biodiesel production is mainly linked to the price of raw material.This factor has favored the use of alternative fats and oils such as those used in frying. Since biodiesel can be obtained from several vegetable and animal raw materials, the physicochemical characteristics of the fuel may vary considerably. One of these characteristics is the fatty acid composition. It directly affects the oxidative stability of biodiesel, which can be impaired when the fuel undergoes exposure to sunlight, metals, oxygen and high temperatures. In order to improve the oxidative stability of biodiesels produced from waste frying oil some studies involving blends of different raw materials have been carried out. In this sense, this work aimed to assess the characteristics resulting from the blending of soybean waste frying oil with other waste biodiesels in what concerns to oxidation. The blends of fatty materials were obtained by means of a 2² factorial design. The induction periods of biodiesel blends were enough to meet the ASTM D6751 standard. Swine fat was responsible for the increase in the induction period values.

  10. A new method to determine oxidative stability of vegetable fats and oils at simulated frying temperature

    Directory of Open Access Journals (Sweden)

    Gertz Christian

    2001-01-01

    Full Text Available A new procedure at simulated frying conditions in our laboratory was developed to monitor frying stability of fats and oils. Water-conditioned silica was prepared and added to the fresh vegetable oil, which was heated for two hours at 170°C. The oil stability at frying temperature was then evaluated by determining the amount of formed dimeric triglycerides The results obtained showed that the stability of the vegetable oils at frying temperature could not be explained by the fatty acid composition alone. Corn oil was observed to be more stable than soybean oil, and rapeseed oil was better than olive oil. It was also observed that crude, non-refined oils were found to have a better heat stability than refin-ed oils. To estimate the effectiveness of synthetic and naturally occurring antioxidants, namely various tocopherols, tocopherol acetate and phytosterol fractions, phenolic compounds like quercetin, oryzanol, ferulic acid, gallates, BHT, BHA and other compounds like ascorbic acid 6-palmitate and squalene were added to refined sunflower and rape seed oil, and their oxidative stability at elevated temperature (OSET values determined. Both linoleic and oleic rich oils gave comparable results for the activity of the various compounds. alpha-tocopherol, tocopherol esters and BHA had low effects on oil stability at frying temperature, while ascorbyl palmitate and some phytosterol fractions were found to have the most stabilizing activity under frying conditions.

  11. Crude oil and finished fuel storage stability: An annotated review

    Energy Technology Data Exchange (ETDEWEB)

    Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

    1991-01-01

    A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

  12. The World Oil Market: The Search for Balance in the New “Oil” Reality

    Directory of Open Access Journals (Sweden)

    Tatjiana A. Malova

    2016-01-01

    Full Text Available The article provides an analysis of change of the world oil market in the face of new "oil" reality. Factors of formation of new "oil" reality in the global world defined. Scientific background and current state of research of the problem are described. It is shownthat in the Russian and foreign literature the considerable attention is paid to the analysis of dynamics of the quantitative variables characterizing fluctuations and shocks in the oil market. At the same time the search for balance in the new "oil" reality are not considerably investigated yet. The proposed approach allows toreveal the substance of the transformation of the world oil market, to assess the changes in the oil market with the development of rhenium in terms of efficiency and functioning of the mechanism, the prospects of price volatility in the oil market. The main directions of transformation of the oil market are follows. Development of a subject basis of the oil market due to changes of a role of the main market players whose structure includes the USA, Saudi Arabia, Russia now. The impact of regulatory factors complex in the oil market towards equilibrium, which include activity of OPEC, supply of shale oil, future market,activity of the uniform regulator and national regulators. Transformation of the oil market in the direction of perfection of the competitive relations, achievement of optimum market balance as a result of coordination and interaction of interests of participants of the global oil market.

  13. Crude oil and stock markets. Stability, instability, and bubbles

    International Nuclear Information System (INIS)

    Miller, J. Isaac; Ratti, Ronald A.

    2009-01-01

    We analyze the long-run relationship between the world price of crude oil and international stock markets over 1971:1-2008:3 using a cointegrated vector error correction model with additional regressors. Allowing for endogenously identified breaks in the cointegrating and error correction matrices, we find evidence for breaks after 1980:5, 1988:1, and 1999:9. There is a clear long-run relationship between these series for six OECD countries for 1971:1-1980.5 and 1988:2-1999.9, suggesting that stock market indices respond negatively to increases in the oil price in the long run. During 1980.6-1988.1, we find relationships that are not statistically significantly different from either zero or from the relationships of the previous period. The expected negative long-run relationship appears to disintegrate after 1999.9. This finding supports a conjecture of change in the relationship between real oil price and real stock prices in the last decade compared to earlier years, which may suggest the presence of several stock market bubbles and/or oil price bubbles since the turn of the century. (author)

  14. Controlling the frying stability of vegetable oils with tocopherols and phytosterols

    Science.gov (United States)

    Polyunsaturated vegetable oils are usually oxidatively stable for salad oils; however, in high stability applications such as frying, these oils are not resistant to the deteriorative processes of oxidation, hydrolysis and polymerization. To solve this problem in the past, oils were hydrogenated an...

  15. Physical and Oxidative Stability of Fish Oil-In-Water Emulsions Stabilized with Fish Protein Hydrolysates

    DEFF Research Database (Denmark)

    García Moreno, Pedro Jesús; Guadix, Antonio; Guadix, Emilia M.

    2016-01-01

    The emulsifying and antioxidant properties of fish protein hydrolysates (FPH) for the physical and oxidative stabilization of 5% (by weight) fish oil-in-water emulsions were investigated. Muscle proteins from sardine (Sardina pilchardus) and small-spotted catshark (Scyliorhinus canicula) were...... hydrolyzed to degrees of hydrolysis (DH) of 3-4-5-6% with subtilisin. Sardine hydrolysates with low DH, 3% and 4%, presented the most effective peptides to physically stabilize emulsions with smaller droplet size. This implied more protein adsorbed at the interface to act as physical barrier against......% yielded a physically stable emulsion with low concentration of unsaturated aldehydes. These results show the potential of FPH as alternative protein emulsifiers for the production of oxidatively stable fish oil-in-water emulsions....

  16. The Future of the Automobile in an Oil-Short World. Worldwatch Paper 32.

    Science.gov (United States)

    Brown, Lester R.; And Others

    Possible future roles and designs of cars are examined in light of depletion of the earth's oil reserves. A major problem with regard to the rapidly changing world oil outlook is that cars will be competing with more essential claiments for scarce oil supplies including food production, industrial power, home heating, and running trucks and…

  17. World Oil: Coping With the Dangers of Success. Worldwatch Paper 66.

    Science.gov (United States)

    Flavin, Christopher

    This publication examines various topics and issues related to the world oil situation. Major areas considered are: (1) the nature and consequences of the current oil glut; (2) a historical overview of the petroleum era (with analyses of the three time periods of 1900-1973, 1973-1979, and 1979-1981); (3) the geopolitics of oil (including data on…

  18. Marine Lipids (Omega-3 Oil) - Stability of Oil and Enriched Products During Production and Storage

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall

    2015-01-01

    off-flavours and gives rise to unhealthy compounds such as free radicals and reactive aldehydes. Necessary prerequisites for successful development of omega-3 enriched products are that the oil used for enrichment is of a high quality and low in oxidation products and that oxidation of the lipids...... oxidation. As processing will often cause extra oxidative stress to the omega-3 oil, extrinsic factors are especially important to consider during processing. Due to the complexity of multiphase foods, it is very difficult to predict the oxidative stability and therefore the behaviour and efficacy...... of antioxidants in omega-3 oil enriched products and optimal composition and processing conditions must be evaluated for each product....

  19. The dynamic stability of OPEC's oil price mechanism

    International Nuclear Information System (INIS)

    Hammoudeh, S.; Madan, V.

    1992-01-01

    This paper examines OPEC's long-lived mechanism which targets the oil price and adjusts the quality ceiling to meet the target. The stability of this controversial mechanism is compared to that of two alternatives: one requires quantity control without any price targeting and the other is a synthesis of quantity control and the OPEC mechanisms. All three mechanisms passed the stability test and the two alternatives give rise to some interesting policy implications. Practicality considerations which involve the availability of specific information make OPEC's mechanism the most appropriate in terms of achieved targeted revenues. The paper also offers a convergence strategy that speeds up the achievement of targeted revenues under OPEC's current mechanism. (author)

  20. Analysis of Saudi Arabia's behavior within OPEC and the world oil market

    International Nuclear Information System (INIS)

    Alkhathlan, Khalid; Gately, Dermot; Javid, Muhammad

    2014-01-01

    We analyze oil export behavior by Saudi Arabia and the Rest of OPEC since 1973. In the literature there has been a wide range of estimates of their correlation: from positive, to zero, to negative. We find that the correlation has varied over time, from moderately high (0.7) in normal periods, to negative during each of five interruptions; the average correlation has been 0.19. Saudi Arabia's oil market behavior depends upon circumstances, but its primary goal is the stability of OPEC and the world oil market. It will coordinate export reductions with the Rest of OPEC when faced with declining demand, but it will increase exports when faced with interruptions elsewhere in OPEC. Allowing for such differences provides evidence of intelligent, context-dependent consistency. But ignoring context – by wrongly assuming the same Saudi response in Normal periods and Interruptions – can lead to a conclusion of Saudi “inconsistency” because the difference in the responses has been obscured

  1. World oil demand's shift toward faster growing and less price-responsive products and regions

    International Nuclear Information System (INIS)

    Dargay, Joyce M.; Gately, Dermot

    2010-01-01

    Using data for 1971-2008, we estimate the effects of changes in price and income on world oil demand, disaggregated by product - transport oil, fuel oil (residual and heating oil), and other oil - for six groups of countries. Most of the demand reductions since 1973-74 were due to fuel-switching away from fuel oil, especially in the OECD; in addition, the collapse of the Former Soviet Union (FSU) reduced their oil consumption substantially. Demand for transport and other oil was much less price-responsive, and has grown almost as rapidly as income, especially outside the OECD and FSU. World oil demand has shifted toward products and regions that are faster growing and less price-responsive. In contrast to projections to 2030 of declining per-capita demand for the world as a whole - by the U.S. Department of Energy (DOE), International Energy Agency (IEA) and OPEC - we project modest growth. Our projections for total world demand in 2030 are at least 20% higher than projections by those three institutions, using similar assumptions about income growth and oil prices, because we project rest-of-world growth that is consistent with historical patterns, in contrast to the dramatic slowdowns which they project. (author)

  2. Effect of unsaponifiable matter extracted from Pistacia khinjuk fruit oil on the oxidative stability of olive oil.

    Science.gov (United States)

    Tavakoli, Javad; Estakhr, Parviz; Jelyani, Aniseh Zarei

    2017-08-01

    The present study was carried out to investigate the improvement of oxidative stability of refined olive oil using various concentrations of unsaponifiable matters extracted from Pistacia khinjuk fruit oil (UFO). For further elucidation of UFO antioxidative power, tertbutylhydroquinone (TBHQ) was used in an olive oil sample, too. Oxidative stability of olive oil samples without and with different levels of UFO (50, 100, 250, 500, 750 and 1000 ppm) and TBHQ (100 ppm) were studied via evaluation of conjugated diene value, carbonyl value, oil/oxidative stability index, acid value and total tocopherol (TT) contents through 8 h thermal process at 170 °C. Results obtained by oxidative stability assays revealed that the highest antioxidative activity of olive oil was obtained by 100 ppm of UFO, followed using 100, 250, 500, 750, and 1000 ppm of UFO and 100 ppm TBHQ, respectively. Evaluation of the relationship between oxidative stability indexes and TT changes indicated a strong correlation (R 2  = 0.9718) between mean relative resistance to oxidation and relative resistance to TT reduction during thermal process. By promotion of relative resistance to TT reduction, olive oil samples' relative resistance to oxidation was enhanced exponentially; implying importance of TT in promotion of oxidative stability of edible oils. The results obtained in this study showed that UFO has higher antioxidative activity compared to TBHQ; thus UFO can be considered as a natural antioxidant with ideal antioxidative activity.

  3. MATHEMATICAL MODEL OF POWER CONSUMPTION FOR SOME OIL PIPE-LINE SECTIONS WITH POOR OPERATIONAL STABILITY

    Directory of Open Access Journals (Sweden)

    J. N. Kolesnik

    2005-01-01

    Full Text Available Mathematical model of power consumption for technologically completed and non-completed oil pipe-line sections with poor operational stability has been developed on the basis of daily indices concerning oil transportation regimes. The model permits to take into account tendencies in power consumption under various time prediction cycles and ranges of oil freight turnover, changes in the bulk and characteristics of the transported oil, configuration and design parameters of oil pipe-line.

  4. Physical stability and clinical efficacy of Crocodylus niloticus oil lotion

    Directory of Open Access Journals (Sweden)

    Telanie Venter

    Full Text Available ABSTRACT The stability and the anti-ageing, skin hydrating and anti-erythema effects of a commercialized Crocodylus niloticus Laurenti, 1768, Crocodylidae, oil lotion was determined. The lotion was stored at controlled conditions over six months during which several stability tests were performed. For the clinical efficacy studies lotion was applied on volar forearm skin (female volunteers and compared to a liquid paraffin-containing reference product. Skin hydrating and anti-ageing effects were determined with a Corneometer®, Cutometer® and Visioscan®, following single (3 h and multiple applications (12 weeks. The Vapometer® and Mexameter® were utilized to determine this lotion's anti-erythema effects on sodium lauryl sulfate irritated skin. The lotion demonstrated good stability over 6 months. The reference product increased skin hydration and decreased skin wrinkles to a larger extent than the C. niloticus lotion after a single application, whereas the C. niloticus lotion decreased skin scaliness better than the reference product. During the long-term study, the reference product overall increased skin hydration more than the C. niloticus lotion, whereas C. niloticus lotion increased skin elasticity to a larger extent than the reference product. C. niloticus lotion increased skin wrinkles and decreased skin scaliness over 12 weeks. Compared to non-treated, irritated skin, C. niloticus lotion demonstrated some potential anti-inflammatory characteristics.

  5. Proceedings of the CERI 2002 World Oil Conference : Reading the Future. CD ed.

    International Nuclear Information System (INIS)

    2002-01-01

    The integration and expansion of world oil markets was the main topic of this conference which featured 18 presentations dealing with developments in the international energy sector. The conference provided an opportunity for participants to discuss issues regarding oil supply and demand, oil prices, OPEC's spare capacity, OPEC's view regarding increasing competition from Canada's oil sands, and what role non-conventional oil plays in today's marketplace. The conference was divided into 6 sessions entitled: (1) oil prices, business as usual, (2) world oil demand, the incredible shrinking market, (3) global oil supplies, (4) going offshore, (5) the politics of oil, and (6) the growing North American supply. The outlook of world energy markets was reviewed with particular emphasis on prospects for oil supply and reserves. Also, the current status of the petroleum industry in both OPEC and non-OPEC oil exporting countries was discussed with reference to exploration, production, reserves, and hydrocarbon potential as well as the environmental, and socio-economic challenges that the industry must face. refs., tabs., figs

  6. China's new oil import status underpins world's most dynamic petroleum scene

    International Nuclear Information System (INIS)

    Anon.

    1994-01-01

    China is poised to become a net importer of oil in 1994--95. That sets the stage for China importing more than 1 million b/d of crude oil and refined products on a net basis by the turn of the century. That development underpins a bigger story -- arguably the biggest story on the petroleum scene today. The turnabout that is seeing the world's fifth biggest oil producer go from significant oil exporter in recent years to major oil importer by the turn of the century points to several other truisms in the petroleum industry: That an oil demand surge in the Asia-Pacific region led by China will fuel overall world oil demand growth for years to come; that a refining and petrochemical boom in a country that accounts for about one fifth of the world's population has dramatic implications for those two industries; that privatization has gathered so much momentum in the global petroleum industry that even Communist China has embraced some form of it; that China's domestic crude supply shortfall is creating unprecedented opportunities for foreign upstream investors in one of the world's most prospective yet underexplored and underexploited regions; and that the same new openness that is distinguishing China's petroleum industry today is turning some of its state owned companies into major competitors to be reckoned with on the international scene, upstream and downstream. The paper discusses China's oil export/import balance, supply/demand outlook, policy changes, and new regulations governing export of crude oil and products

  7. Antioxidant Effect on Oxidation Stability of Blend Fish Oil Biodiesel with Vegetable Oil Biodiesel and Petroleum Diesel Fuel

    Directory of Open Access Journals (Sweden)

    M. Hossain

    2013-06-01

    Full Text Available Two different phenolic synthetic antioxidants were used to improve the oxidation stability of fish oil biodiesel blends with vegetable oil biodiesel and petroleum diesel. Butylhydroxytoluene (BHT most effective for improvement of the oxidation stability of petro diesel, whereas  tert-butylhydroquinone (TBHQ showed good performance in fish oil biodiesel. Fish oil/Rapeseed oil biodiesel mixed showed some acceptable results in higher concentration ofantioxidants. TBHQ showed better oxidation stability than BHT in B100 composition. In fish oil biodiesel/diesel mixed fuel, BHT was more effective antioxidant than TBHQ to increase oxidationstability because BHT is more soluble than TBHQ. The stability behavior of biodiesel/diesel blends with the employment of the modified Rancimat method (EN 15751. The performance ofantioxidants was evaluated for treating fish oil biodiesel/Rapeseed oil biodiesel for B100, and blends with two type diesel fuel (deep sulfurization diesel and automotive ultra-low sulfur or zero sulfur diesels. The examined blends were in proportions of 5, 10, 15, and 20% by volume of fish oilbiodiesel.

  8. Colleges Should Reimagine Themselves in an Oil-Scarce World

    Science.gov (United States)

    Carlson, Scott

    2008-01-01

    Some years ago, bringing up peak oil--the concept that oil production will crest and then decline, leading to all sorts of trouble in society--might have made one seem like the kind of person who frequents Web sites that sell survival books and freeze-dried food. Today such discussion has pretty much hit the mainstream. Last month The Wall Street…

  9. A unified world oil market: Regions in physical, economic, geographic, and political space

    International Nuclear Information System (INIS)

    Kaufmann, Robert K.; Banerjee, Shayan

    2014-01-01

    Although there is a general consensus that the market is unified, here we quantify the factors that create regions by analyzing the price relation between 33 crude oils. ADF statistics indicate that 447 of the 528 crude oil pairings cointegrate; 81 do not. The presence/absence of cointegration is analyzed using a logit model. The likelihood that the prices for two crude oils cointegrate depends on their physical characteristics (density and sulfur content), economic factors (country risk for the nation of origin), their geographic location (distance between supply ports), and political factors (OPEC membership). Over the sample period, the technology to refine heavy crude oils penetrates the market, and this reduces the price difference between heavy and light crude oils. The effect of country risk implies that crude oils from high risk nations are not perfect substitutes for crude oils of similar quality from low risk nations. Finally, crude oils from widely separated suppliers are more likely to cointegrate than crude oils from near-by nations, which suggests consumers diversify supply across transportation chokepoints. For this sample, these sources of regionalization add $0.20 per barrel to the $2.86 average price difference between crude oils in the same market. Together, these factors have important implications for the efficacy of policy aimed at reducing dependence on unreliable suppliers and the spill-over effects of holding inventories. - Highlights: • The world oil market is not completely unified. • Regions are defined by differences in API gravity and sulfur content. • Country risk regionalizes the world oil market. • Shipping chokepoints regionalize the world oil market. • Regionalization adds $0.20 to $2.86 price difference between oils in same market

  10. Oxidative Stability and Shelf Life of Foods Containing Oils and Fats

    DEFF Research Database (Denmark)

    Oxidative Stability and Shelf Life of Foods Containing Oils and Fats focuses on food stability and shelf life, both important factors in the improvement and development of food products. This book, relevant for professionals in the food and pet food industries, presents an evaluation of methods...... for studies on the oxidative stability and shelf life of bulk oils/fats, fried oils and foods, food emulsions, dried foods, meat and meat products, and seafood in food and pet food. Focuses on the application of various evaluation methods to studies of oxidative stability and shelf life in oils and fats...... and oils and fats-containing foods in the food and pet food industries. Discusses oxidative stability and shelf life of low-moisture (dry) food, including dry pet food. Discusses lipid co-oxidation with protein because a number of food products contain both lipids and proteins. Directed mainly toward...

  11. OPEC at middle age: facing an uncertain future in the world oil market economy

    International Nuclear Information System (INIS)

    1992-01-01

    International institutions, like individuals, groups, and even societies and cultures, pass through various stages in their development as they grow from youth through middle age into more experienced and mature members of the international community. OPEC, the Organization of Petroleum Exporting Countries, is no exception to this generally observable phenomenon on the world economic scene. It has clearly undergone a gradual process of growth over the past three decades or so since its establishment by five founding states in Baghdad in September 1960. OPEC's history since then could be characterized as being divided into three distinct developmental stages. The first decade, the 1960s, was a period of consolidation of OPEC's power over the oil companies and their control over the member countries'oil resources. The second decade - the 1970s - was a decade characterized by almost continuous and prolonged producer - consumer confrontation as well as revelation of some of the more basic cleavages within OPEC as an organization. This was followed by the decade of the 1980s -- a period of relative accommodation between producers and consumers in the interest of longer term market stability

  12. Role of modern climate and hydrology in world oil preservation

    Science.gov (United States)

    Szatmari, Peter

    1992-12-01

    The accumulation of oil requires a favorable source, a reservoir, good seal-rock quality, and suitably timed thermal history and structuring. The accumulated oil, especially its light fractions, may be subsequently removed by hydrologically controlled processes such as water washing, biodegradation, and tilting of the oil-water contact. These processes are dependent on the climate. In regions that have become increasingly cold or dry during late Cenozoic time, low rainfall, low ground-water flow rates, and low input of nutrients and microorganisms have protected the oil; in warm or temperate rainy climates, high flow rates and high input of nutrients and microorganisms have led to partial or total removal of oil. Thus, most of the rich (>500 000 barrels/day) oil provinces on land are in cold or dry regions, where water is recharged in highlands that receive little rain (sub-Saharan Africa, Brazil, India, and most of China, rich oil provinces on land (outside young deltas) are rare, and biodegradation is widespread.

  13. Roasting pumpkin seeds and changes in the composition and oxidative stability of cold-pressed oils.

    Science.gov (United States)

    Raczyk, Marianna; Siger, Aleksander; Radziejewska-Kubzdela, Elżbieta; Ratusz, Katarzyna; Rudzińska, Magdalena

    2017-01-01

    Pumpkin seed oil is valuable oil for its distinctive taste and aroma, as well as supposed health- promoting properties. The aim of this study was to investigate how roasting pumpkin seeds influences the physicochemical properties of cold-pressed oils. The fatty acid composition, content of phytosterols, carotenoids and tocopherols, oxidative stability and colour were determined in oils after cold pressing and storage for 3 months using GC-FID, GCxGC-ToFMS, HPLC, Rancimat and spectrophotometric methods. The results of this study indicate that the seed-roasting and storage process have no effect on the fatty acid composition of pumpkin seed oils, but does affect phytosterols and tocopherols. The carotenoid content decreased after storage. The colour of the roasted oil was darker and changed significantly during storage. Pumpkin oil obtained from roasted seeds shows better physicochemical properties and oxidative stability than oil from unroasted seeds.

  14. Analysis of fatty acid methyl esters and oxidative stability of seed purpose watermelon (Citrullus lanatus) genotypes for edible oil.

    Science.gov (United States)

    Mahla, H R; Rathore, S S; Venkatesan, K; Sharma, R

    2018-04-01

    World's vegetable oil demand is increasing day by day and oil seed supply is limited to a dozen oil seed crops on commercial scale. Efforts were made to explore the potential of water melon a traditionally grown native crop of Indian arid zone having oil content over 30% and seed yield potential of 500-600 kg per hectare under rainfed conditions. An analysis was carried out to explore the suitability of watermelon [ Citrullus lanatus (Thunb.)] oil for human consumption on the basis of fatty acid (FA) composition in selected genotypes. Total oil content ranged between 10.0 and 31.0%. Eleven FA were identified in seed oil. Linoleic, stearic, palmitic and oleic acid were found as major FA while myristic, heptadecanoic, arachidic, 9-hexadecenoic and 14-eicosenoic acid was present in traces. Linoleic acid single polyunsaturated FA contributor found in the range of 43.95% (WM-44) to 55.29% (WM-18). Saturated FA content ranged between 32.24 and 37.61%. Significant genetic variation was observed for mono-unsaturated FA. Metabolic capacity to inter-conversion of FA and nutritive value of watermelon oil was described on the basis of ratio of FA group. Total phenolics, antioxidant activity, peroxide value and oxidizability were also estimated along with oxidative stability of oil. Multivariate analysis showed that, oil content has positive correlation with linoleic acid. The Euclidean based UPGMA clustering revealed that genotypes WM-18 is most suitable for trait specific breeding program for high linoleic acid ( n -6), desaturation ratio and oleic desaturation ratio with higher oil content and lowest palmitic acid.

  15. The instability of world oil market and its impact on economic development: Indonesia's experience

    International Nuclear Information System (INIS)

    Patmosukismo, S.

    1991-01-01

    The world oil market has been characterized by fluctuating prices which have a direct impact on the world economy. If the world oil price rises in real terms, upstream activities become more attractive to producers, and if the price declines, downstream opportunities become more attractive. The world oil market is currently determined not only by producers and consumers, but also by the futures trade. In addition, the elasticity of oil prices has increased since the 1970s through competition among producers and competition from other energy sources. The Asia Pacific countries are experiencing rapid economic growth, and are thus heavily dependent on oil, but generally have small reserves. Their reserves/production ratio is ca 20 years, with a major share coming from China and Indonesia. The current situation of tight and inadequate supply may increase the region's dependence on Middle East sources. The effects of the three recent major oil crises on the Asia Pacific countries are reviewed and the role of oil and gas in Indonesia's economic development is described. Export earnings from oil and gas represent a major share of total Indonesian export revenues, and taxes and receipts from oil companies continue to be the largest receipts in Indonesian government revenues. Slow changes in the primary fuel mix and high growth in domestic consumption may turn Indonesia into a net oil importer before the year 2000. A major effort to decrease domestic oil consumption has been implemented by using natural gas and coal in the power generation sector. On the supply side, recoverable oil and gas reserves of 50 billion bbl and 200 trillion ft 3 respectively may be present but their development depends on the investment scheme of the continuing exploration program

  16. The Antioxidant Activity and Oxidative Stability of Cold-Pressed Oils

    OpenAIRE

    Prescha, Anna; Grajzer, Magdalena; Dedyk, Martyna; Grajeta, Halina

    2014-01-01

    In our study, we characterized the antioxidant activity and oxidative stability of cold-pressed macadamia, avocado, sesame, safflower, pumpkin, rose hip, Linola, flaxseed, walnut, hempseed, poppy, and milk thistle oils. The radical scavenging activity of the non-fractionated fresh oil, as well as the lipophilic and hydrophilic fractions of the oil was determined using a 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay. The fatty acid composition of the fresh and stored oils was analyzed by gas chro...

  17. Inferred demand and supply elasticities from a comparison of world oil models

    International Nuclear Information System (INIS)

    Huntington, H.G.

    1992-01-01

    This paper summarizes the responses of oil supply and demand to prices and income in 11 world oil models that were compared in a recent Energy Modeling Forum (EMF) study. In May 1989, the EMF commenced a study of international oil supplies and demands (hereafter, EMF-11) to compare alternative perspectives on supply and demand issues and how these developments influence the level and direction of world oil prices. In analysing these issues, the EMF-11 working group relied partly upon results from 11 world oil models, using standardized assumptions about oil prices and gross domestic product (GDP). During the study, inferred price elasticities of supply and demand were derived from a comparison of results across different oil price scenarios with the same GDP growth path. Inferred income elasticities of demand were derived from a comparison of results across different economic growth scenarios with the same oil price-path. Together, these estimates summarize several important relationships for understanding oil markets. The first section provides some background on the EMF study and on general trends in the scenarios of interest that help to understand the results. Following sections explain the derivation and qualifications of the inferred estimates, report the results and summarize the key conclusions. (author)

  18. Sterculia striata seed kernel oil: Characterization and thermal stability

    Directory of Open Access Journals (Sweden)

    Oliveira Cavalheiro, José Marcelino

    2008-06-01

    Full Text Available The objective of the present work was to characterize sterculia seed kernel oil. The chemical composition of the seeds, physicochemical properties as well as the fatty acid composition of the kernel oil was determined. The chemical composition of kernel flour presented about 25.8% lipid content. The physicochemical parameters such as acid, iodine, peroxide and saponification values were 0.82 (% as oleic acid, 69.2 (g iodine/100 g oil, 4.20 (m eq./kg and 136.1 (mg. KOH/g oil, respectively. With respect to fatty acid composition, the oil contained 36.2, 43.7 and 10.9% saturated, monounsaturated and polyunsaturated fatty acids, respectively. Palmitic acid (31.9%, oleic acid (41.7% and linoleic acid (10.73% were the principal saturated, monounsaturated and polyunsaturated fatty acids. Two cyclopropanoid fatty acids i.e. sterculic and malvalic acid were identified at a concentration of 5.3 and 2.3%, respectively. With regards to the thermal stability of the oil, a thermogravimetric analysis (TGA has shown that the oil was stable until about 284 °C, above that the oil started loosing mass, while a differential thermogravimetric analysis (DTGA revealed three stages of degradation with an increase in temperature. These stages corresponded to the degradation of polyunsaturated, monounsaturated and saturated fatty aids. The Differential Scanning Calorimetric (DSC analysis showed the existence of two exothermic events of energy transition, one of which is related to the oxidation reactions and another to the decomposition of the oil. Exothermic transitions in the oil were initiated at a temperature (Ti of 287.79 °C, and terminated at 347.81 °C, with an enthalpy variation of 11.69 joules.g–1 and at initial temperature (Ti of 384.87 °C, peak temperature (Tp 415.71 °C, final temperature (Tf 448.9 °C and an enthalpy of 200.83 Joules. G–1El objetivo de este trabajo fue la caracterización del aceite de almendra de la semilla de

  19. Oil palm genome sequence reveals divergence of interfertile species in old and new worlds

    Science.gov (United States)

    Singh, Rajinder; Ong-Abdullah, Meilina; Low, Eng-Ti Leslie; Manaf, Mohamad Arif Abdul; Rosli, Rozana; Nookiah, Rajanaidu; Ooi, Leslie Cheng-Li; Ooi, Siew–Eng; Chan, Kuang-Lim; Halim, Mohd Amin; Azizi, Norazah; Nagappan, Jayanthi; Bacher, Blaire; Lakey, Nathan; Smith, Steven W; He, Dong; Hogan, Michael; Budiman, Muhammad A; Lee, Ernest K; DeSalle, Rob; Kudrna, David; Goicoechea, Jose Louis; Wing, Rod; Wilson, Richard K; Fulton, Robert S; Ordway, Jared M; Martienssen, Robert A; Sambanthamurthi, Ravigadevi

    2013-01-01

    Oil palm is the most productive oil-bearing crop. Planted on only 5% of the total vegetable oil acreage, palm oil accounts for 33% of vegetable oil, and 45% of edible oil worldwide, but increased cultivation competes with dwindling rainforest reserves. We report the 1.8 gigabase (Gb) genome sequence of the African oil palm Elaeis guineensis, the predominant source of worldwide oil production. 1.535 Gb of assembled sequence and transcriptome data from 30 tissue types were used to predict at least 34,802 genes, including oil biosynthesis genes and homologues of WRINKLED1 (WRI1), and other transcriptional regulators1, which are highly expressed in the kernel. We also report the draft sequence of the S. American oil palm Elaeis oleifera, which has the same number of chromosomes (2n=32) and produces fertile interspecific hybrids with E. guineensis2, but appears to have diverged in the new world. Segmental duplications of chromosome arms define the palaeotetraploid origin of palm trees. The oil palm sequence enables the discovery of genes for important traits as well as somaclonal epigenetic alterations which restrict the use of clones in commercial plantings3, and thus helps achieve sustainability for biofuels and edible oils, reducing the rainforest footprint of this tropical plantation crop. PMID:23883927

  20. The social costs to the US of monopolization of the world oil market, 1972--1991

    International Nuclear Information System (INIS)

    Greene, D.L.; Leiby, P.N.

    1993-03-01

    The partial monopolization of the world oil market by the OPEC cartel has produced significant economic costs to the economies of the world. This paper reports estimates of the costs of monopolization of oil to the US over the period 1972--1991. Two fundamental assumptions of the analysis are, (1) that OPEC has acted as a monopoly, albeit with limited control, knowledge, and ability to act and, (2) that the US and other consuming nations could, through collective (social) action affect the cartel's ability to act as a monopoly. We measure total costs by comparing actual costs for the 1972--1991 period to a hypothetical ''more competitive'' world oil market scenario. By measuring past costs we avoid the enormous uncertainties about the future course of the world oil market and leave to the reader's judgment the issue of how much the future will be like the past. We note that total cost numbers cannot be used to determine the value of reducing US oil use by one barrel. They are useful for describing the overall size of the petroleum problem and are one important factor in deciding how much effort should be devoted to solving it. Monopoly pricing of oil transfers wealth from US oil consumers to foreign oil producers and, by increasing theeconomic scarcity of oil, reduces the economy's potential to produce. The actions of the OPEC cartel have also produced oil price shocks, both upward and downward, that generate additional costs because of the economy's inherent inability to adjust quickly to a large change in energy prices. Estimated total costs to the United States from these three sources for the 1972--1991 period are put at $4.1 trillion in 1990$($1.2 T wealth transfer, $0.8 T macroeconomic adjustment costs, $2.1 T potential GNP losses). The cost of the US's primary oil supply contingency program is small ($10 B) by comparison

  1. Charting the new world order: proceedings of the 15. CERI international oil and gas markets conference

    International Nuclear Information System (INIS)

    1996-10-01

    The 15th International Oil and Gas Markets Conference, organized by the Canadian Energy Research Institute (CERI) and held in Calgary, AB, provided a wide variety of opportunities for discussion of the global oil and gas market outlook, international oil and gas market strategies and corporate planning in the new world order, competition for investments, the re-emergence of the geopolitics of energy, energy in the Americas, international gas market strategies, and the financing of Canadian international operations. More than 100 delegates from around the world attended the conference to hear some 20 presentations. refs., tabs., figs

  2. A Study on the Determination of the World Crude Oil Price and Methods for Its Forecast

    Energy Technology Data Exchange (ETDEWEB)

    Kim, J.K. [Korea Energy Economics Institute, Euiwang (Korea)

    2001-11-01

    The primary purpose of this report is to provide the groundwork to develop the methods to forecast the world crude oil price. The methodology is used by both literature survey and empirical study. For this purpose, first of all, this report reviewed the present situation and the outlook of the world oil market based on oil demand, supply and prices. This analysis attempted to provide a deeper understanding to support the development of oil forecasting methods. The result of this review, in general, showed that the oil demand will be maintained annually at an average rate of around 2.4% under assumption that oil supply has no problem until 2020. The review showed that crude oil price will be a 3% increasing rate annually in the 1999 real term. This report used the contents of the summary review as reference data in order to link the KEEIOF model. In an effort to further investigate the contents of oil political economy, this report reviewed the articles of political economy about oil industry. It pointed out that the world oil industry is experiencing the change of restructuring oil industry after the Gulf War in 1990. The contents of restructuring oil industry are characterized by the 'open access' to resources not only in the Persian Gulf, but elsewhere in the world as well - especially the Caspian Sea Basin. In addition, the contents showed that the oil industries are shifted from government control to government and industry cooperation after the Gulf War. In order to examine the characters and the problems surrounding oil producing countries, this report described the model of OPEC behavior and strategy of oil management with political and military factors. Among examining the models of OPEC behavior, this report focused on hybrid model to explain OPEC behavior. In reviewing political and religious power structure in the Middle East, the report revealed that US emphasizes the importance of the Middle East for guaranteeing oil security. However, three

  3. Research on the Influence Factors of Emulsion Stability of Oil-in-water Drilling Fluid

    Science.gov (United States)

    Li, Xiaoxu; Sun, Yuxue; Chen, Xiangming; Wang, Zengkui; Xu, Jianjun

    2018-01-01

    The evaluation standard of emulsion stability of oil-in-water drilling fluid is determined in this paper, based on which an evaluation analysis is conducted for the influence factors of emulsion stability, including the addition of emulsifier, addition of stabilizer, stirring speed, weighing agent, clay, etc. to gain the corresponding regularity understanding.

  4. An empirical exploration of the world oil price under the target zone model

    International Nuclear Information System (INIS)

    Tang, Linghui; Hammoudeh, Shawkat

    2002-01-01

    This paper investigates the behavior of the world oil price based on the first-generation target zone model. Using anecdotal data during the period of 1988-1999, we found that OPEC has tried to maintain a weak target zone regime for the oil price. Our econometric tests suggest that the movement of the oil price is not only manipulated by actual and substantial interventions by OPEC but also tempered by market participants' expectations of interventions. As a consequence, the non-linear model based on the target zone theory has very good forecasting ability when the oil price approaches the upper or lower limit of the band

  5. An empirical exploration of the world oil price under the target zone model

    International Nuclear Information System (INIS)

    Linghui Tang; Shawkat Hammoudeh

    2002-01-01

    This paper investigates the behavior of the world oil price based on the first-generation target zone model. Using anecdotal data during the period of 1988-1999, we found that OPEC has tried to maintain a weak target zone regime for the oil price. Our econometric tests suggest that the movement of the oil price is not only manipulated by actual and substantial interventions by OPEC but also tempered by market participants' expectations of interventions. As a consequence, the non-linear model based on the target zone theory has very good forecasting ability when the oil price approaches the upper or lower limit of the band. (author)

  6. The Antioxidant Activity and Oxidative Stability of Cold-Pressed Oils.

    Science.gov (United States)

    Prescha, Anna; Grajzer, Magdalena; Dedyk, Martyna; Grajeta, Halina

    2014-01-01

    In our study, we characterized the antioxidant activity and oxidative stability of cold-pressed macadamia, avocado, sesame, safflower, pumpkin, rose hip, Linola, flaxseed, walnut, hempseed, poppy, and milk thistle oils. The radical scavenging activity of the non-fractionated fresh oil, as well as the lipophilic and hydrophilic fractions of the oil was determined using a 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay. The fatty acid composition of the fresh and stored oils was analyzed by gas chromatography. The acid value, peroxide value, p -anisidine value and conjugated diene and triene contents in the fresh oils, as well as in those stored throughout the whole period of their shelf life, were measured by CEN ISO methods. The antioxidant activity of the oils expressed as Trolox equivalent antioxidant capacity (TEAC), ranged from 0.17 to 2.32 mM. The lipophilic fractions of the oils were characterized by much higher antioxidant activity than the hydrophilic ones. There were no significant changes in fatty acid composition and only slight changes in the oxidative stability parameters of the oils during their shelf life. Through the assessment of the relationship between antiradical activity and the oxidative stability of oils, it is proposed that a DPPH assay predicts the formation of oxidation products in cold-pressed oils-however, the correlations differ in fractionated and nonfractionated oils.

  7. Response of the Polish Wheat Prices to the Worlds Crude Oil Prices

    Directory of Open Access Journals (Sweden)

    HAMULCZUK

    2012-07-01

    Full Text Available Agricultural commodities prices play crucial role both in farmers income determination and in price relationship establishment for the whole economy. Among the factors influencing the wheat prices, crude oil prices are considered as one of the most important. The aim of this paper was to assess the character of linkage between world crude oil prices and Polish wheat prices. Results of the research confirm the existence of such linkage although the nature and the strength of this relationship changes over time. However, the long-run relationships between the crude oil and Polish wheat prices were not proven. Moreover, growing impact of crude oil prices on Polish wheat prices over time was not detected. The results suggest that exchange rates may strongly influence wheat prices. This in turn may weaken response of Polish wheat prices in relation to world crude oil prices.

  8. Impacts of low oil price on China and the world natural gas industry chain

    Directory of Open Access Journals (Sweden)

    Yijun Liu

    2016-11-01

    Full Text Available Since the second half of 2014, the crude oil price has been in rapid decline, which poses profound impacts on the global natural gas industry chain. The issue started to surface in the oil and gas sector on how to survive in such a situation. In this paper, an overview was first made on the world natural gas industry chain experiencing from the high-oil-price period to the low-oil-price period, then the influences of low oil price on natural gas production patterns, prices and development prospects, etc., and finally discussion focus was put on the challenges and opportunities brought about by the sustained low oil price to the natural gas industry chain in present China. The results are concluded as follows. First, under such low oil price situation, oil and gas companies at present have to cut capital expenditure to such a degree that the oil and gas output will be both of particular concern in the future. Second, low oil price will compel the falls of global natural gas prices to different degrees, so natural gas economy will drop greatly compared with crude oil prices. Third, such a low oil price will exert more severe impact on the high-cost unconventional natural gas sector; as a result, many unconventional oil and gas companies have suffered frequent bankruptcy at abroad, while such companies in China are holding different attitudes towards unconventional natural gas. Fourth, the oil and gas M&A market remains a laggard due to many other reasons. Fifth, this drop in oil prices is just occurring at the time when natural gas is developing so rapidly in China, which will bring both challenges and opportunities to the industrial structural reform of natural gas in China.

  9. Containing IRAQ: World oil market projections, 1993-2008

    International Nuclear Information System (INIS)

    Reinsch, A.E.; Considine, J.I.

    1993-01-01

    The likely impact of key uncertainties affecting the oil market were assessed and a reference price path was provided upon which industry and governments could base their investment decisions and policy prescriptions. The reference case was based on a timely resurgence in Iraqi oil exports, which would result in a three percent inflation of oil price over the remainder of this decade. An alternative scenario was based on two assumptions: (1) Iraq failed to negotiate a re-entry into the export market until 1996; and (2) the other OPEC members increased their production roughly in line with anticipated market growth. An alternative scenario examined a situation in which Iraqi production and exports were brought back on stream much earlier than anticipated. This was the worst case scenario for OPEC since prices would have fallen rapidly to below $ 10.00 per barrel in 1994. The study concluded that any shift in the timing of a return to uninhibited Iraq oil sales would have long lasting and significant effects. tabs., figs., refs

  10. Thermal stability of Vernonia galamensis seed oil | Wamalwa ...

    African Journals Online (AJOL)

    ... vernonia oil at room temperature (25 °C) was transformed irreversibly to an intense?brown shade, becoming increasingly more viscous with increase in temperature, and ceasing to flow momentarily at 188 °C. On cooling to room temperature, the oil solidified into a brown rubber?like elastic material. The oil also exhibited ...

  11. Oil turbulence in the next decade. An essay on high oil prices in a supply-constrained world

    International Nuclear Information System (INIS)

    Jesse, J.H.; Van der Linde, C.

    2008-06-01

    A CIEP analysis of the recent development of demand and supply for crude oil indicates that the mismatch in supply and demand growth could cause tighter oil markets than we already experience today. In the World Energy Outlook 2007, the International Energy Agency (IEA) warned of a possible 'energy crunch'. But what was anticipated to happen in the first part of the next decade has been fast-forwarded to today, more than 5 years earlier, and could shake the very foundation of our energy systems if no action is undertaken. Without exaggeration, the recent developments in the international oil market are ground-breaking: a little over a year ago, in January 2007, the West Texas Intermediate crude oil price (WTI) traded for USD50 dollar a barrel. Within a year, the price doubled to USD100 per barrel in January 2008 and pushed through to over USD135 in June 2008, against the backdrop of the fresh market supposition about reaching a whopping USD200 per barrel in 2009. If this proves to be true, the world will not only have moved from an 'Oil Demand-led World' to an 'Oil Supply-constrained World' (since 2004) but, more importantly, will then also experience a radical change in the oil price formation. Until recently, the oil price was largely underpinned by the marginal cost of the last barrel needed to match demand, with some political and economic conjuncture mark-ups or -downs. As will be presented in this paper, the current high oil prices are still primarily driven by structural factors that can be well explained without resorting to blaming speculative investors playing the futures market or the low dollar. But if prices are heading towards USD200 a barrel in 12 months' time, or for that matter even to USD150 a barrel, other drivers will gain prominence over marginal costs as the main driver. In that case, OPEC will have accomplished a long-held wish: oil will then be priced at its real value in the Western world (for instance the economic value of mobility for

  12. A Model of the Dynamics of the Effect of World Crude Oil Price and World Rice Price on Indonesia’s Inflation Rate

    OpenAIRE

    P. Adam; U. Rianse; L. M. Harafah; E. Cahyono; M. Rafyi

    2016-01-01

    This study aims to investigate the dynamics of the effects of world crude oil prices and world rice prices on Indonesia’s inflation rate in the period between January 2004 and September 2015. Monthly time series data spanning from January 2004 to September 2015 are analyzed using difference equation model as the econometric tool. Test result shows that there existed a dynamic effect of world oil crude prices and world rice prices on inflation rate in Indonesia. The World crude oil prices posi...

  13. Oxidative stabilization of mixed mayonnaises made with linseed oil and saturated medium-chain triglyceride oil

    NARCIS (Netherlands)

    Raudsepp, P.; Brüggemann, D.A.; Lenferink, Aufrid T.M.; Otto, Cornelis; Andersen, M.L.

    2014-01-01

    Mayonnaises, made with either saturated medium chain triglyceride (MCT) oil or unsaturated purified linseed oil (LSO), were mixed. Raman confocal microspectrometry demonstrated that lipid droplets in mixed mayonnaise remained intact containing either MCT oil or LSO. Peroxide formation during storage

  14. Study of the oxidative stability of oils vegetables for production of Biodiesel

    Directory of Open Access Journals (Sweden)

    Marco Aurélio R Melo

    2014-04-01

    Full Text Available Biodiesel is technological and estrategical Brazilian oportunity once this country has abundant vegetable species which oils are extracted to produce this biofuel. Oleaginous viability depends on its technical, economical and social-environmental competitiviness. Fatty acid variety determines its thermal and oxidative stability, mainly polyunsaturated ones. In this point of view, this papers aims evaluate oxidative stability and resistence to thermal decomposition of pequi, buriti and macauba oils. These fatty acids profiles are in agreement with literature data. Comparing thermal and oxidative stability of these oils, it can be seen pequi oil is more easily to oxidate than buriti and macauba oils when PetroOXY and Rancimat methods are employed.

  15. Effect of natural polyphenol on the oxidative stability of pecan oil.

    Science.gov (United States)

    Zhang, Yuan-Yuan; Zhang, Fang; Thakur, Kiran; Ci, Ao-Te; Wang, Hao; Zhang, Jian-Guo; Wei, Zhao-Jun

    2017-10-05

    We evaluated the antioxidant activity of natural polyphenols which gives high oxidative stability to the pecan oil. The in vitro DPPH radical scavenging, reducing power and total antioxidant activity of tested antioxidants demonstrated that tannic acid displayed the highest DPPH scavenging activity and provided the largest reducing power. During storage of pecan oil, based on oxidative stability tests, we further evaluated the protective effect of polyphenols and synthetic antioxidants on the oxidative stability of pecan oil. The results showed that caffeic acid inhibited oxidation of pecan oil effectively. Sesamol and catechin showed slight improvement in oxidative stability, while ferulic acid, erucic acid and rutin had no effect. Taken together, compared with synthetic antioxidants (TBHQ, BHT, BHA), caffeic acid was observed to be stronger than BHT and BHA and was close to TBHQ. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Fabrication, stability and efficacy of dual-component antimicrobial nanoemulsions: essential oil (thyme oil) and cationic surfactant (lauric arginate).

    Science.gov (United States)

    Chang, Yuhua; McLandsborough, Lynne; McClements, David Julian

    2015-04-01

    The influence of a cationic surfactant (lauric arginate, LAE) on the physical properties and antimicrobial efficacy of thyme oil nanoemulsions was investigated. Nanoemulsions prepared from pure thyme oil were highly unstable due to Ostwald ripening, but they could be stabilized by adding a ripening inhibitor (corn oil) to the oil phase prior to homogenisation. The loading capacity and antimicrobial efficacy of thyme oil nanoemulsions were significantly increased by adding LAE. In the absence of LAE, at least 60 wt% corn oil had to be added to the lipid phase to inhibit Ostwald ripening; but in the presence of 0.1 wt% LAE, only 30 wt% corn oil was needed. LAE addition substantially increased the antimicrobial efficacy of the thyme oil nanoemulsions: 200 μg/ml thyme oil was needed to inhibit growth of a spoilage yeast (Zygosaccharomyces bailii) if LAE was added, whereas ⩾ 400 μg/ml was needed in the absence of LAE. Copyright © 2014 Elsevier Ltd. All rights reserved.

  17. Selective retardation of perfume oil evaporation from oil-in-water emulsions stabilized by either surfactant or nanoparticles.

    Science.gov (United States)

    Binks, Bernard P; Fletcher, Paul D I; Holt, Benjamin L; Beaussoubre, Pascal; Wong, Kenneth

    2010-12-07

    We have used dynamic headspace analysis to investigate the evaporation rates of perfume oils from stirred oil-in-water emulsions into a flowing gas stream. We compare the behavior of an oil of low water solubility (limonene) and one of high water solubility (benzyl acetate). It is shown how the evaporation of an oil of low water solubility is selectively retarded and how the retardation effect depends on the oil volume fraction in the emulsion. We compare how the evaporation retardation depends on the nature of the adsorbed film stabilizing the emulsion. Surfactant films are less effective than adsorbed films of nanoparticles, and the retardation can be further enhanced by compression of the adsorbed nanoparticle films by preshrinking the emulsion drops.

  18. Antibacterial activity and stability of microencapsulated lemon grass essential oil in feeds for broiler chickens

    OpenAIRE

    Assis, Yhago Patrycky Antunes Souza; Almeida, Anna Christina de; Nogueira, Wedson Carlos Lima; Souza, Cintya Neves de; Gonçalves, Samuel Ferreira; Silva, Flavio Emanuel Gomes; Santos, Vanessa Kelly Ferreira do Rosário; Martins, Ernane Ronie

    2017-01-01

    SUMMARY The antibacterial effect of microencapsulated lemon grass (Cymbopogon citratus) essential oil on strains of Escherichia coli (ATCC8739), Staphylococcus aureus (ATCC 6538) and Salmonella enterica subsp. enterica (ATCC 6017), and the stability of this oil in feeds for broiler chickens were evaluated. The Minimum Inhibitory Concentration (MIC) and Minimum Bactericidal Concentration (MBC) were determined by the macrodilution method, using the microencapsulated lemon grass essential oil at...

  19. Short-term thermal stability of transformer and motor oils at wide range of moisture contents

    Science.gov (United States)

    Volosnikov, D. V.; Povolotskiy, I. I.; Skripov, P. V.

    2018-01-01

    Method of controlled pulse heating of a wire probe was used for studying heat transfer and thermal stability of energy oils and motor oils in the presence of low quantities of moisture. The technique of two-pulse heating is the most suitable method for monitoring the actual state of oils. A distinct signal-response accompanying the appearance of moisture in the tested sample has been revealed.

  20. Oxidative stability during storage of structured lipids produced from fish oil and caprylic acid

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall; Xu, Xuebing; Timm Heinrich, Maike

    2004-01-01

    lipid (SFO), produced by enzymatic interesterification from the same oil and caprylic acid, was compared with the stability of FO. Oils were stored at 2degreesC for 11 wk followed by storage at 20degreesC for 6 wk. In addition, the antioxidative effect of adding the metal chelators EDTA or citric acid...

  1. Drought and heat stress effects on soybean fatty acid composition and oil stability

    Science.gov (United States)

    Previous studies have shown that oil concentration and fatty acid profile (composition) change with genotype, environment (mainly heat and drought), and geographical location. The changes in fatty acid composition under these conditions affect fatty acid stability, creating a challenge to oil proces...

  2. Characterization of constituents, quality and stability of pomegranate seed oil (Punica granatum L.

    Directory of Open Access Journals (Sweden)

    Illana Louise Pereira de MELO

    2016-03-01

    Full Text Available Abstract This study aimed to characterize pomegranate seed oil and evaluate its quality and stability parameters against those of linseed oil. The profile of fatty acids and phytosterols and the content of tocopherols were analyzed by gas chromatography and high performance liquid chromatography, respectively. The quality of both oils was assessed as recommended by the American Oil Chemists' Society (AOCS and stability was evaluated using 2,2-diphenyl-1-picrylhydrazyl (DPPH, β-carotene bleaching (coupled oxidation of β-carotene/linoleic acid and Rancimat® assays. While α-linolenic acid (52% was the most abundant fatty acid in linseed oil (LO, punicic acid (55% was highest in pomegranate seed oil (PSO. Tocopherols and phytosterols (175 and 539 mg/100 g, respectively were greater in PSO than in LO (51 and 328 mg/100 g, respectively. Both oils met quality standards. The β-carotene bleaching and the DPPH assays showed greater oxidative stability for PSO than for LO. The Rancimat® method, on the other hand, indicated low stability for both oils.

  3. Thermal stability of butter oils produced from sheep’s non-pasteurized and pasteurized milk

    Directory of Open Access Journals (Sweden)

    FLAVIA POP

    Full Text Available The physical and chemical characteristics and thermal stability of butter oil produced from non-pasteurized and pasteurized sheep’s milk were studied. Thermal stability of samples was estimated by using the accelerated shelf-life testing method. Samples were stored at 50, 60 and 70oC in the dark and the reaction was monitored by measuring peroxide, thiobarbituric acid and free fatty acid values. The peroxide and thiobarbituric acid values increased as the temperature increased. The increase of acid values of the two samples was not significant. A slight increase in free fatty acid value showed that hydrolytic reactions were not responsible for the deterioration of butter oil samples in thermal stability studies. When compared, butter oil produced from pasteurized sheep’s milk has higher thermal stability than butter oil produced from non-pasteurized sheep’s milk. Although butter oil produced from non-pasteurized milk was not exposed to any heat treatment, the shelf-life of this product was lower than the shelf-life of butter oil produced from pasteurized sheep’s milk. Therefore, heat treatment for pasteurization did not affect the thermal stability of butter oil.

  4. The Middle East: Its role in world oil. A survey of the issues

    International Nuclear Information System (INIS)

    Radetski, M.

    1992-01-01

    The importance of the Middle East oil resource base is exceptional, in quantitative as well as economic terms. A review is presented of this resource base, and the economic and political factors associated with it. In 1990 oil from the Middle East accounted for 27% of world output, and accounts for 65% of proven world oil reserves. The viability of OPEC's role in controlling market prices is discussed, and it is proposed that high prices such as those in the early 1980s are unlikely to re-occur, and that control of capacity to keep prices above competitive levels but not high enough to induce large scale expansion outside the region is the rational course of action. Political instability in the Middle East and its destabilizing impact on oil supply is discussed. 12 refs., 2 tabs

  5. Production, Characterization, and Stability of Orange or Eucalyptus Essential Oil/β-Cyclodextrin Inclusion Complex.

    Science.gov (United States)

    Kringel, Dianini Hüttner; Antunes, Mariana Dias; Klein, Bruna; Crizel, Rosane Lopes; Wagner, Roger; de Oliveira, Roberto Pedroso; Dias, Alvaro Renato Guerra; Zavareze, Elessandra da Rosa

    2017-11-01

    The aim of this study was to produce and characterize inclusion complexes (IC) between β-cyclodextrin (β-CD) and orange essential oil (OEO) or eucalyptus essential oil (EEO), and to compare these with their pure compounds and physical mixtures. The samples were evaluated by chemical composition, morphology, thermal stability, and volatile compounds by static headspace-gas chromatography (SH-GC). Comparing the free essential oil and physical mixture with the inclusion complex, of both essential oils (OEO and EEO), it was observed differences occurred in the chemical composition, thermal stability, and morphology. These differences show that there was the formation of the inclusion complex and demonstrate the necessity of the precipitation method used to guarantee the interaction between β-CD and essential oils. The slow loss of the volatile compounds from both essential oils, when complexed with β-CD, showed a higher stability when compared with their physical mixtures and free essential oils. Therefore, the results showed that the chemical composition, molecular size, and structure of the essential oils influence the characteristics of the inclusion complexes. The application of the β-CD in the formation of inclusion complexes with essential oils can expand the potential applications in foods. © 2017 Institute of Food Technologists®.

  6. Effect of extraction process on composition, oxidative stability and rheological properties of purslane seed oil.

    Science.gov (United States)

    Delfan-Hosseini, Sasan; Nayebzadeh, Kooshan; Mirmoghtadaie, Leila; Kavosi, Maryam; Hosseini, Seyede Marzieh

    2017-05-01

    Purslane seed oil could be considered as potential nutritious oil due to its desirable fatty acid composition and other biological active compounds. In this study the effect of three extraction procedure including solvent extraction, cold pressing and microwave pretreatment (MW) followed by cold pressing on oil yield, physicochemical properties, oxidative stability and rheological behaviors of oil was investigated. Solvent extracted oil had the highest extraction yield (72.31%). Pretreatment by microwave before cold press extraction resulted in an increase in extraction yield, total phenolic compound (TPC) and antioxidant activity. Cold press extracted oil had the lowest oxidative stability (4.64h). This property was greatly enhanced by microwave irradiation, so that the longest oxidative stability was found in MW-cold press extracted oil with 9.67h. Furthermore, all extracted oils demonstrated Newtonian flow behaviors. MW-cold press extracted oil had the greatest apparent viscosity and highest sensitivity to temperature changes (E a =29.18kJ/mol -1 ). Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Stability evaluation of quality parameters for palm oil products at low temperature storage.

    Science.gov (United States)

    Ramli, Nur Aainaa Syahirah; Mohd Noor, Mohd Azmil; Musa, Hajar; Ghazali, Razmah

    2017-12-18

    Palm oil is one of the major oils and fats produced and traded worldwide. The value of palm oil products is mainly influenced by their quality. According to ISO 17025:2005, accredited laboratories require a quality control procedure with respect to monitoring the validity of tests for determination of quality parameters. This includes the regular use of internal quality control using secondary reference materials. Unfortunately, palm oil reference materials are not currently available. To establish internal quality control samples, the stability of quality parameters needs to be evaluated. In the present study, the stability of quality parameters for palm oil products was examined over 10 months at low temperature storage (6 ± 2 °C). The palm oil products tested included crude palm oil (CPO); refined, bleached and deodorized (RBD) palm oil (RBDPO); RBD palm olein (RBDPOo); and RBD palm stearin (RBDPS). The quality parameters of the oils [i.e. moisture content, free fatty acid content (FFA), iodine value (IV), fatty acids composition (FAC) and slip melting point (SMP)] were determined prior to and throughout the storage period. The moisture, FFA, IV, FAC and SMP for palm oil products changed significantly (P  0.05). The stability study indicated that the quality of the palm oil products was stable within the specified limits throughout the storage period at low temperature. The storage conditions preserved the quality of palm oil products throughout the storage period. These findings qualify the use of the palm oil products CPO, RBDPO, RBDPOo and RBDPS as control samples in the validation of test results. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  8. Oxidative stability of fish oil-enriched mayonnaise-based salads

    DEFF Research Database (Denmark)

    Sørensen, Ann-Dorit Moltke; Nielsen, Nina Skall; Jacobsen, Charlotte

    2010-01-01

    The oxidative stability of fish oil-enriched mayonnaise-based salads and the influence of different vegetables in shrimp and tuna salads were evaluated. Moreover, the lipid oxidation in the presence of 1% oregano, rosemary, or thyme in fish oil-enriched tuna salad was assessed. The results obtained...... showed that the mayonnaise itself was more oxidatively stable without vegetables and tuna or shrimp, in spite of the higher oil content in mayonnaise (63 and 6.3% fish oil, respectively) compared to salads (∼24 and 2.4% fish oil, respectively). Surprisingly, the fish oil-enriched mayonnaise was only...... significantly different from the standard mayonnaise in the volatile concentration during the end of storage. In fish oil-enriched shrimp salad, asparagus had an anti-oxidative effect and shrimp a pro-oxidative effect, where the anti-oxidative effect of asparagus was strong enough to prevent the pro...

  9. Physicochemical properties and oxidative stability of bleached pomace-olive oil on Tunisian activated clays

    International Nuclear Information System (INIS)

    Jahouach, Wafa

    2002-01-01

    This work is a contribution to studying bleaching process, which is an important stage in refining of vegetable oils. This process permitted to reduce or convert undesired constituents to harmless ones from oils and fats. Virgin olive oil, considered as reference, and pomace-olive oil were bleached in optimal conditions using Tunisian activated clays ( collected from the South of Tunisia) which were prepared in our laboratory and compared with commercial bleaching earths. It was shown that activated Tunisian clays are characterized by a very important adsorptive capacity, which is similar to that of commercial ones. In addition, the study of physicochemical properties of bleached oils was considered. The fatty acid composition (GC), the triacylglycerol composition (HPLC), and oxidative stability (UV spectrometry) allowed to conclude that treated oils do not undergo considerable physicochemical alterations and their caracteristics remain in concordance with international standards relative to edible refined oils. (Author)

  10. Stress determination and geomechanical stability analysis of an oil ...

    Indian Academy of Sciences (India)

    of an oil well of Iran. AYUB ELYASI1,∗, KAMRAN GOSHTASBI1, OMID SAEIDI2 and. SEYED RAHMAN TORABI2. 1Faculty of Engineering, Tarbiat Modares University, .... So far as the depth of oil and gas exploration is concerned, the in situ stress orientations mani- .... As the real influence of the intermediate principal stress.

  11. Stability of wheat germ oil obtained by supercritical carbon dioxide ...

    African Journals Online (AJOL)

    심정은

    Wheat germ oil was extracted using an environmental friendly solvent, supercritical carbon dioxide (SC-. CO2) at a semi-batch flow ... With better refining technologies, these resources can be turned into value added products. ..... parameter determination of vegetable oil oxidation under rancimat test conditions (Reza et al., ...

  12. Stability of wheat germ oil obtained by supercritical carbon dioxide ...

    African Journals Online (AJOL)

    Wheat germ oil was extracted using an environmental friendly solvent, supercritical carbon dioxide (SCCO2) at a semi-batch flow extraction process. The supercritical carbon dioxide (SC-CO2) extraction was carried out to extract oil at temperature of 40°C and pressure of 25 MPa. Ethanolysis was performed with 1 ...

  13. Characterization of Thermal Stability of Synthetic and Semi-Synthetic Engine Oils

    Directory of Open Access Journals (Sweden)

    Anand Kumar Tripathi

    2015-03-01

    Full Text Available Engine oils undergo oxidative degradation and wears out during service. Hence it is important to characterize ageing of engine oils at different simulated conditions to evaluate the performance of existing oils and also design new formulations. This work focuses on characterizing the thermo-oxidative degradation of synthetic and semi-synthetic engine oils aged at 120, 149 and 200 °C. Apparent activation energy of decomposition of aged oils evaluated using the isoconversional Kissinger-Akahira-Sunose technique was used as a thermal stability marker. The temporal variation of stability at different ageing temperatures was corroborated with kinematic viscosity, oxidation, sulfation and nitration indices, total base number, antiwear additive content and molecular structure of the organic species present in the oils. At the lowest temperature employed, synthetic oil underwent higher rate of oxidation, while semi-synthetic oil was stable for longer time periods. At higher temperatures, the initial rate of change of average apparent activation energy of synthetic oil correlated well with a similar variation in oxidation number. A mixture of long chain linear, branched, and cyclic hydrocarbons were observed when semi-synthetic oil was degraded at higher temperatures.

  14. Bio-oil Stabilization by Hydrogenation over Reduced Metal Catalysts at Low Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Huamin; Lee, Suh-Jane; Olarte, Mariefel V.; Zacher, Alan H.

    2016-08-30

    Biomass fast pyrolysis integrated with bio-oil upgrading represents a very attractive approach for converting biomass to hydrocarbon transportation fuels. However, the thermal and chemical instability of bio-oils presents significant problems when they are being upgraded, and development of effective approaches for stabilizing bio-oils is critical to the success of the technology. Catalytic hydrogenation to remove reactive species in bio-oil has been considered as one of the most efficient ways to stabilize bio-oil. This paper provides a fundamental understanding of hydrogenation of actual bio-oils over a Ru/TiO2 catalyst under conditions relevant to practical bio-oil hydrotreating processes. Bio-oil feed stocks, bio-oils hydrogenated to different extents, and catalysts have been characterized to provide insights into the chemical and physical properties of these samples and to understand the correlation of the properties with the composition of the bio-oil and catalysts. The results indicated hydrogenation of various components of the bio-oil, including sugars, aldehydes, ketones, alkenes, aromatics, and carboxylic acids, over the Ru/TiO2 catalyst and 120 to 160oC. Hydrogenation of these species significantly changed the chemical and physical properties of the bio-oil and overall improved its thermal stability, especially by reducing the carbonyl content, which represented the content of the most reactive species (i.e., sugar, aldehydes, and ketones). The change of content of each component in response to increasing hydrogen additions suggests the following bio-oil hydrogenation reaction sequence: sugar conversion to sugar alcohols, followed by ketone and aldehyde conversion to alcohols, followed by alkene and aromatic hydrogenation, and then followed by carboxylic acid hydrogenation to alcohols. Hydrogenation of bio-oil samples with different sulfur contents or inorganic material contents suggested that sulfur poisoning of the reduced Ru metal catalysts was

  15. The world gets heavier : high prices and growing demand put global focus on unconventional oil

    International Nuclear Information System (INIS)

    Stonehouse, D.

    2008-01-01

    A global unconventional oil forecast was presented. Unconventional oil supplies are expected to account for approximately 40 per cent of global oil supplies by 2015. Ultra-heavy oil production is expected to grow from current levels of 1.9 million barrels per day to 4.7 million barrels per day over the next decade. Supplies will largely be developed in Alberta and Venezuela, although other basins are expected to also be exploited in the near future. Studies have suggested that oil sands production in Alberta will climb to nearly 6 million barrels per day of raw bitumen by 2018. However, rising costs associated with developing the oil sands are expected to impact on bitumen production levels. Venezuela's Orinoco belt is currently producing approximately 600,000 barrels of oil per day, and production partnerships are now in place to develop 9.1 billion barrels of proven reserves. Heavy oil resources in the Middle East are estimated at approximately 500 billion barrels. Explorers are now attempting to locate sweet spots in formations where the heavy oils can be produced. The United States has an estimated 6.1 billion barrels of bitumen in Utah and other western states. Technological innovations made in Alberta are now being used to develop tar sands in the western United States. Shale oil resources in the United States total approximately 2 trillion barrels. It was concluded that delays in large heavy oil projects may have significant impacts on supply growth over the next 5 years. A map of heavy oil resources around the world was included. 3 figs

  16. A Policy study on stabilization of heating oil supply and demand

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Bok Jae [Korea Energy Economics Institute, Euiwang (Korea)

    1999-03-01

    As a principal heating fuel for household and commercial sector, and a heat source fuel for industry, the heating oil shows its great demand intensively during a specific period (wintertime) due to its characteristics. It represents that the fluctuation of heating oil demand throughout the year is very extreme. Therefore, the stable supply of heating oil has been rising as an important task. It is desirable to develop and supply a new type of heating oil compounded of kerosene and gasoline with appropriate ratio for short- and mid-term to have a stable supply and demand of heating oil. For long-term prospect, it is desirable to supply petroleum products mixing gasoline and B-C oil as heating oil when it is equipped with combustion technology of boiler and distribution system. In this case, it is required to have investment on infrastructure for the supply of new heating oil (mixture of gasoline and B-C oil) and a proper preparatory period for the conversion of equipment (such as a boiler). The vitalization of storing oil is essential to stabilize the supply and demand of heating oil. In order to vitalize it, the price of heating oil should be determined by a market function reflecting the seasonal supply and demand circumstances. (author). 101 refs., 5 figs., 83 tabs.

  17. Stabilization and real world satellite problem. [transformations for stabilizing orbital equations

    Science.gov (United States)

    Velez, C. E.

    1975-01-01

    The use of transformations of orbital equations has been considered in connection with requirements for more accurate data. The reported investigation is concerned with an evaluation of the relative merits of such transformations. The formulations tested include the classical Cowell formulation, the time regularized formulation, stabilization by the use of integrals, and stabilization by the use of elements. It is found that irrespective of efficiency considerations, stabilizing transformation makes it possible to obtain precisions which are unattainable with the Cowell formulations.

  18. EIA model documentation: World oil refining logistics demand model,''WORLD'' reference manual

    International Nuclear Information System (INIS)

    1994-01-01

    This manual is intended primarily for use as a reference by analysts applying the WORLD model to regional studies. It also provides overview information on WORLD features of potential interest to managers and analysts. Broadly, the manual covers WORLD model features in progressively increasing detail. Section 2 provides an overview of the WORLD model, how it has evolved, what its design goals are, what it produces, and where it can be taken with further enhancements. Section 3 reviews model management covering data sources, managing over-optimization, calibration and seasonality, check-points for case construction and common errors. Section 4 describes in detail the WORLD system, including: data and program systems in overview; details of mainframe and PC program control and files;model generation, size management, debugging and error analysis; use with different optimizers; and reporting and results analysis. Section 5 provides a detailed description of every WORLD model data table, covering model controls, case and technology data. Section 6 goes into the details of WORLD matrix structure. It provides an overview, describes how regional definitions are controlled and defines the naming conventions for-all model rows, columns, right-hand sides, and bounds. It also includes a discussion of the formulation of product blending and specifications in WORLD. Several Appendices supplement the main sections

  19. Virtual learning : oil and gas training in the virtual world

    Energy Technology Data Exchange (ETDEWEB)

    Macedo, R.

    2006-07-15

    New software technologies may help to meet increased training demands in the booming oil and gas industry. Although not intended to take the place of hands-on training, a new 3-D simulation program designed by Terris Hill may help new employees demonstrate initial competency. The program outlines the basic training requirements of working on a service rig and was designed to look like many of today's video games. The software was patterned after one cycle of work on a particular job on a service rig. Workers navigate through the 3-D program, which was was built by animators and graphic artists and then tested by experts in the industry. Calgary-based 3D Internet is also developing technology to create training programs for workers in the oil and gas industry. In addition to interactive training programs, the company has constructed simulations, and has recently completed a project for a massive water treatment plant in Saudi Arabia. The company has also created a substation training program that includes voice-overs from actual field employees, as well as interactive knobs and gauges. Simulation training may benefit both employers and employees, as trainees can review procedures repeatedly without the dangers of personal injury or equipment failure. Entry modules can include helpful hints and guidelines while certification modules will grade for behaviour and quality of work performed without system help. However, although simulation technology may help the safety level and proficiency of workers, it represents only a fraction of what workers will need to know before working on an actual service rig. It was concluded that any move to incorporate new simulation training programs within current interactive training programs will need to be driven by industry. 4 figs.

  20. Analytical Characterization of Pure and Blended Watermelon (Citrullus lanatus oil: Impact of Blending on Oxidative Stability

    Directory of Open Access Journals (Sweden)

    Muhammad Waqar Azeem

    2015-06-01

    Full Text Available Analytical characterization of pure, blended watermelon (Citrulluslanatus oil and impact of blending on oxidative stability was investigated. Watermelon oil was added with mango (Mangiferaindica L. kernel oil at four different concentrations 5, 10, 15 and 20% (B1, B2, B3 and B4 and referenced with a control (100% watermelon oil. All the blends were stored in transparent PET bottles at ambient temperature (25-28oC for 3 months; storage stability was assessed at the interval of 1 month. Free fatty acid, unsaponifiable matter, saponification value, refractive index and iodine value of watermelon seed oil and mango kernel oil was 1.38%, 0.34%; 0.71%, 1.68%; 198, 193; 1.468, 1.457; 107.51, 54.62, respectively. The α tocopherol content of watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 127.49, 205.44, 135.24, 144.52, 156.81 and 169.34 mg/kg. δ tocopherol in watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 55.26, 34.81, 53.64, 51.27, 50.14 and 48.23 mg/kg. Concentration of linoleic acid decreased from 50.78% to 30.17% when 40% mango kernel oil was added to watermelon oil. Oleic acid increased from 22.89% in watermelon oil to 25.19%, 28.84% and 30.64% in B1, B2, B3 and B4. The increase in peroxide value of watermelon oil, B1, B2, B3 and B4 was 10.07, 9.56, 7.62, 5.17 and 2.87 (meqO2/kg in a time dependent manner. Induction period of pure watermelon oil was less than mango kernel oil and blends. These results suggest that chemical characteristics and oxidative stability of pure watermelon oil can be improved by blending with mango kernel oil.

  1. Analytical characterization of pure and blended watermelon (citrullus lanatus) oil: impact of blending on oxidative stability

    International Nuclear Information System (INIS)

    Azeem, M.W.; Nadeem, M.

    2015-01-01

    Analytical characterization of pure, blended watermelon (Citrulluslanatus) oil and impact of blending on oxidative stability was investigated. Watermelon oil was added with mango (Mangiferaindica L.) kernel oil at four different concentrations 5, 10, 15 and 20% (B 1, B2, B3 and B4) and referenced with a control (100% watermelon oil). All the blends were stored in transparent PET bottles at ambient temperature (25-28 degree C) for 3 months; storage stability was assessed at the interval of 1 month. Free fatty acid, unsaponifiable matter, saponification value, refractive index and iodine value of watermelon seed oil and mango kernel oil was 1.38%, 0.34%; 0.71%, 1.68%; 198, 193; 1.468, 1.457; 107.51, 54.62, respectively. The tocopherol content of watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 127.49, 205.44, 135.24, 144.52, 156.81 and 169.34 mg/kg. delta tocopherol in watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 55.26, 34.81, 53.64, 51.27, 50.14 and 48.23 mg/kg. Concentration of linoleic acid decreased from 50.78% to 30.17% when 40% mango kernel oil was added to watermelon oil. Oleic acid increased from 22.89% in watermelon oil to 25.19%, 28.84% and 30.64% in B1, B2, B3 and B4. The increase in peroxide value of watermelon oil, B1, B2, B3 and B4 was 10.07, 9.56, 7.62, 5.17 and 2.87 (meqO/sub 2//kg) in a time dependent manner. Induction period of pure watermelon oil was less than mango kernel oil and blends. These results suggest that chemical characteristics and oxidative stability of pure watermelon oil can be improved by blending with mango kernel oil. (author)

  2. Properties and stability of butter oil obtained from milk and yoghurt.

    Science.gov (United States)

    Kaya, A

    2000-04-01

    The physical and chemical characteristics and thermal stability of butter oil produced from cow's milk by two different methods were studied. Butter oil samples from cow's milk were made (i) directly from milk and (ii) from yoghurt. Samples were autoxidized at 60, 70 and 80 degrees C in the dark and the reaction monitored by peroxide, thiobarbituric acid and free fatty acid values. Peroxide and thiobarbituric acid values increased as the temperature increased. The increase of the acid value was not significant. The thermal stability was highest in butter oil produced from yoghurt. Oxidative changes compared to hydrolytic changes are of greater significance in the thermal stability of butter oil samples. Arrhenius parameters and activation energies were calculated for the peroxide value data. The percent loss of linolenic acid was about 3 times faster than that of linoleic acid.

  3. Thermo-Oxidative Stability Evaluation of Bullfrog (Rana catesbeiana Shaw) Oil.

    Science.gov (United States)

    Rutckeviski, Renata; Xavier-Júnior, Francisco H; Morais, Andreza R V; Alencar, Éverton N; Amaral-Machado, Lucas; Genre, Julieta; Gondim, Amanda D; Egito, Eryvaldo S T

    2017-04-10

    Bullfrog oil (BO), a natural product obtained from recycling of adipose tissue from the amphibian Rana catesbeiana Shaw, has been recently evaluated as a therapeutic activity ingredient. This work aimed to evaluate the long-term and accelerated thermal oxidative stabilities of this product, which is a promising raw material for emulsion technology development. BO was extracted from amphibian adipose tissue at 70 °C with a yield of 60% ± 0.9%. Its main fatty acid compounds were oleic (30.0%) and eicosapentaenoic (17.6%) acids. Using titration techniques, BO showed peroxide, acid, iodine and saponification indices of 1.92 mEq·O₂/kg, 2.95 mg·KOH/g oil, 104.2 g I₂/100 g oil and 171.2 mg·KOH/g oil, respectively. In order to improve the accelerated oxidative stability of BO, synthetic antioxidants butylhydroxytoluene (BHT) and buthylhydroxyanisole (BHA) were used. The addition of BHT increased the oxidation induction time compared to the pure oil, or the oil containing BHA. From the results, the best oil-antioxidant mixture and concentration to increase the oxidative stability and allow the oil to be a stable raw material for formulation purposes was derived.

  4. Thermal stability of corn oil flavoured with Thymus capitatus under heating and deep-frying conditions.

    Science.gov (United States)

    Karoui, Iness Jabri; Dhifi, Wissal; Jemia, Meriam Ben; Marzouk, Brahim

    2011-03-30

    The thermal stability of corn oil flavoured with thyme flowers was determined and compared with that of the original refined corn oil (control). The oxidative stability index (OSI) was measured and samples were exposed to heating (30 min at 150, 180 and 200 °C) and deep-frying (180 °C). Changes in peroxide value (PV), free fatty acid (FFA) content, specific absorptivity values (K(232) and K(270)), colour and chlorophyll, carotenoid and total phenol contents were monitored. The OSI and heating results showed that thyme incorporation was effective against thermal oxidation based on the increased induction time observed for the flavoured oil (6.48 vs 4.36 h), which was characterised by lower PV, FFA content, K(232) and K(270) than the control oil after heating from 25 to 200 °C, with higher red and yellow colour intensities and chlorophyll, carotenoid and total phenol contents. The deep-frying test showed the accelerated deterioration of both oils in the presence of French fries. Compared with the control oil, the thyme-flavoured oil showed improved thermal stability after heating. This could be attributed to the presence of thyme pigments and antioxidant compounds allowing extended oil thermal resistance. Copyright © 2011 Society of Chemical Industry.

  5. Thermo-Oxidative Stability Evaluation of Bullfrog (Rana catesbeiana Shaw Oil

    Directory of Open Access Journals (Sweden)

    Renata Rutckeviski

    2017-04-01

    Full Text Available Bullfrog oil (BO, a natural product obtained from recycling of adipose tissue from the amphibian Rana catesbeiana Shaw, has been recently evaluated as a therapeutic activity ingredient. This work aimed to evaluate the long-term and accelerated thermal oxidative stabilities of this product, which is a promising raw material for emulsion technology development. BO was extracted from amphibian adipose tissue at 70 °C with a yield of 60% ± 0.9%. Its main fatty acid compounds were oleic (30.0% and eicosapentaenoic (17.6% acids. Using titration techniques, BO showed peroxide, acid, iodine and saponification indices of 1.92 mEq·O2/kg, 2.95 mg·KOH/g oil, 104.2 g I2/100 g oil and 171.2 mg·KOH/g oil, respectively. In order to improve the accelerated oxidative stability of BO, synthetic antioxidants butylhydroxytoluene (BHT and buthylhydroxyanisole (BHA were used. The addition of BHT increased the oxidation induction time compared to the pure oil, or the oil containing BHA. From the results, the best oil-antioxidant mixture and concentration to increase the oxidative stability and allow the oil to be a stable raw material for formulation purposes was derived.

  6. Oil has its price. A qualitative outline of the world oil market

    International Nuclear Information System (INIS)

    Hers, J.S.; Touber, F.

    2007-09-01

    As the relevance of the oil price has been recognised since the early seventies of the last century one would expect that both monitoring and modelling practice of the international oil industry would be well developed and effective. The recent developments on the international oil market seem to have come as a surprise to many sector analysts however. This report seeks to review the structure of the international oil market in order to identify relevant drivers and internal dynamics of the international oil market. In addition several modelling approaches, as undertaken by institutions in this field, have been reviewed on the basis of this narrative and qualitative analysis. The analysis of the international oil market suggests that the role of OPEC policies has gained increasing importance, both due to the increasing dependence on OPEC production and increasing coherence of OPEC decision making. None of the models surveyed structures the international oil market as an oligopolistic or cartel-driven market however, but rather as a competitive market with OPEC either as a price-following or a price-setting marginal producer. The first approach seems adequate for the simulation of the international market structure over the nineties of the past century but seems problematic for the current and future term. The second approach reflects the recent trend of increasing OPEC pricing power but fails to present a transparent logic on the price-setting strategy of OPEC. On the basis of these notions it is suggested that future modelling practice should embed game theoretic considerations regarding the strategic behaviour of the large oil producers [nl

  7. Effect of ingredients on oxidative stability of fish oil-enriched drinking yoghurt

    DEFF Research Database (Denmark)

    Nielsen, Nina Skall; Klein, Anna; Jacobsen, Charlotte

    2009-01-01

    , pectin, citric acid or gluconodelta- lactone did not affect the oxidative stability of fish oil-enriched yoghurt emulsions. Furthermore, the fruit preparation and added sugar did not lead to increased antioxidative activity. It is concluded that yoghurt as the dairy component in the fish oil......The oxidative stabilities of fish oil-enriched milk and fish oil-enriched drinking yoghurt were compared by following the development of lipid oxidation in plain milk, plain yoghurt and yoghurt to which ingredients present in drinking yoghurt were added one by one. All samples were enriched with 1...... wt-% fish oil. After 3 weeks of storage, development of peroxide values, volatile secondary oxidation products and fishy offflavors were much more pronounced in the milk compared to any of the yoghurt samples, irrespective of any added ingredients used to prepare flavored drinking yoghurt. Thus...

  8. The social costs to the US of monopolization of the world oil market, 1972--1991

    Energy Technology Data Exchange (ETDEWEB)

    Greene, D.L.; Leiby, P.N.

    1993-03-01

    The partial monopolization of the world oil market by the OPEC cartel has produced significant economic costs to the economies of the world. This paper reports estimates of the costs of monopolization of oil to the US over the period 1972--1991. Two fundamental assumptions of the analysis are, (1) that OPEC has acted as a monopoly, albeit with limited control, knowledge, and ability to act and, (2) that the US and other consuming nations could, through collective (social) action affect the cartel's ability to act as a monopoly. We measure total costs by comparing actual costs for the 1972--1991 period to a hypothetical more competitive'' world oil market scenario. By measuring past costs we avoid the enormous uncertainties about the future course of the world oil market and leave to the reader's judgment the issue of how much the future will be like the past. We note that total cost numbers cannot be used to determine the value of reducing US oil use by one barrel. They are useful for describing the overall size of the petroleum problem and are one important factor in deciding how much effort should be devoted to solving it. Monopoly pricing of oil transfers wealth from US oil consumers to foreign oil producers and, by increasing theeconomic scarcity of oil, reduces the economy's potential to produce. The actions of the OPEC cartel have also produced oil price shocks, both upward and downward, that generate additional costs because of the economy's inherent inability to adjust quickly to a large change in energy prices. Estimated total costs to the United States from these three sources for the 1972--1991 period are put at $4.1 trillion in 1990$($1.2 T wealth transfer, $0.8 T macroeconomic adjustment costs, $2.1 T potential GNP losses). The cost of the US's primary oil supply contingency program is small ($10 B) by comparison.

  9. The Influence of Palm Oil Addition on Sunflower Halva Stability and Texture

    Directory of Open Access Journals (Sweden)

    Vlad Muresan

    2014-05-01

    Full Text Available Halva is one of the most popular food products of Middle Eastern and North African countries. Worldwide, the most known halva contains roasted sesame seeds, while usually in Eastern European countries the most appreciated is sunflower halva. However, even if sunflower halva is an appreciated product, it has currently a quality below the expectations of the new generation of consumers. Sunflower halva main issue is caused by the oil which separates at the surface during storage, determining a low commercial aspect of the product. Thus, the aim of this work was to assess the influence of palm oil addition on sunflower halva stability and texture. Five samples containing different oil percentages [w/w] (1%, 2%, 3%, 4%, 5% were prepared, as well as a control sample prepared using the standard recipe (no palm oil added. The texture of all samples was analyzed by an instrumental method, while the colloidal stability was determined by a gravimetric technique during 40 days of storage at two different temperatures (1-2ºC and 15-20ºC. After the storage test at 1-2oC, there were not significant differences between the samples, for all palm oil containing samples as well as for control the percentages of separated oil being below 0.6%. With respect to the control sample, the halva samples containing 1%, 4% and 5% of palm oil showed a decrease in their stability, while samples containing 2% and 3% showed an improved stability (3.44% and 1.78% of separated oil. During this study it was established that the sample containing 3% palm oil was the most favorable, regarding its textural properties, as well as its colloidal stability

  10. Transient Stability Improvement of IEEE 9 Bus System Using Power World Simulator

    Directory of Open Access Journals (Sweden)

    Kaur Ramandeep

    2016-01-01

    Full Text Available The improvement of transient stability of power system was one of the most challenging research areas in power engineer.The main aim of this paper was transient stability analysis and improvement of IEEE 9 bus system. These studies were computed using POWER WORLD SIMULATOR. The IEEE 9 bus system was modelled in power world simulator and load flow studies were performed to determine pre-fault conditions in the system using Newton-Raphson method. The transient stability analysis was carried out using Runga method during three-phase balanced fault. For the improvement transient stability, the general methods adopted were fast acting exciters, FACT devices and addition of parallel transmission line. These techniques play an important role in improving the transient stability, increasing transmission capacity and damping low frequency oscillations.

  11. Chemical stability of extra-virgin olive oil added with oregano essential oil.

    Science.gov (United States)

    Asensio, Claudia M; Nepote, Valeria; Grosso, Nelson R

    2011-09-01

    Extra virgin olive oil is highly consumed and well known for its nutritional and health benefits. However, it is fatty food highly susceptible to lipid oxidation. The objective of this study was to evaluate the preserving effect of oregano (Origanum vulgare L. spp vulgare called "oregano compacto") essential oil on physical and chemical properties in extra virgin olive oil during storage. Oregano essential oil composition was analyzed by GC-MS. This essential oil was added into extra virgin olive oil at 0.05%. The samples were stored in 3 different conditions: darkness, light exposure, and temperature (60 °C). Chemical indicators of lipid oxidation (peroxide value, p-anisidine value, conjugated dienes, free fatty acidity, and carotenoid and chlorophyll contents) were measured. High content in carvomenthol (22.52%), terpinolene (19.77%), thymol (13.51%), and γ-terpinene (10.30%) were detected in oregano essential oil. Olive oil samples without oregano essential oil stored at 60 °C and exposure at artificial light had the highest peroxide values during storage. Higher p-anisidine and K232 values after day 7 of storage were detected in temperature, darkness, and light exposure treatments. Light treatment was the main factor that degraded chlorophyll causing loss of color. The highest chlorophyll content (3.87 mg/kg) was observed in olive oil with essential oil at the end of storage. In general, olive oil samples added with oregano essential oil had lower peroxide, conjugated dienes, and p-anisidine values and higher chlorophyll and carotenoid contents during storage. Oregano essential oil retards lipid oxidation process in olive oil prolonging its shelf life. Oregano essential oil was and is used with the purpose of flavoring and aromatizing food. This essential oil due to its composition has shown antioxidant activity. Synthetic antioxidants such as butylated hydroxytoluene (BHT) and butylated hydroxyanisole (BHA) are thought to be promoters of carcinogenesis

  12. Improving oxidative stability of soya and sunflower oil using ...

    African Journals Online (AJOL)

    Rosmarinus officinallis) and tert- butyl-hydroquinone (TBHQ) as possible antioxidants in sunflower and soya oil. Upon addition of 200 ppm of dried leaf extract, acetone extract yielded protection of the samples against oxidation more efficiently as ...

  13. Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Robert C. [Iowa State Univ., Ames, IA (United States); Smith, Ryan [Iowa State Univ., Ames, IA (United States); Wright, Mark [Iowa State Univ., Ames, IA (United States); Elliott, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Resasco, Daniel [Univ. of Oklahoma, Norman, OK (United States); Crossley, Steven [Univ. of Oklahoma, Norman, OK (United States)

    2014-09-28

    This project is part of a collaboration effort between Iowa State University (ISU), University of Oklahoma (OK) and Pacific Northwest National Laboratory (PNNL). The purpose of this project is to stabilize bio-oil fractions and improve their suitability for insertion into petroleum refineries. Bio-oil from fast pyrolysis of biomass is a complex mixture of unstable organic compounds. These organic compounds react under standard room conditions resulting in increases in bio-oil viscosity and water content – both detrimental for bio-oil storage and transportation. This study employed fractionation and upgrading systems to improve the stability of bio-oil. The fractionation system consists of a series of condensers, and electrostatic precipitators designed to separate bio-oil into five fractions: soluble carbohydrates (SF1&2), clean phenolic oligomers (CPO) and middle fraction (SF3&4), light oxygenates (SF5). A two-stage upgrading process was designed to process bio-oil stage fractions into stable products that can be inserted into a refinery. In the upgrading system, heavy and middle bio-oil fractions were upgraded into stable oil via cracking and subsequent hydrodeoxygenation. The light oxygenate fraction was steam reformed to provide a portion of requisite hydrogen for hydroprocessing. Hydrotreating and hydrocracking employed hydrogen from natural gas, fuel gas and light oxygenates reforming. The finished products from this study consist of gasoline- and diesel-blend stock fuels.

  14. Studied on Virgin Coconut Oil (VCO) and Olive Oil (OO) as an Alternative for Stabilizer of Radiation Vulcanized Natural Rubber Latex (RVNRL) Preparation

    International Nuclear Information System (INIS)

    Syuhada Ramli; Sofian Ibrahim; Mohd Noorwadi Mat Lazim

    2016-01-01

    This paper presents the effects of virgin coconut oil (VCO) and olive oil (OO) as an alternative stabilizer in the radiation vulcanized natural rubber latex (RVNRL). Potassium laurite (KL) as a stabilizer considered as a control of RVNRL sample were compared to mixed ratio 1:1 KL: VCO and 1:1 KL: OO stabilizer formulation. Total solid content (TSC) and tensile strength (TS) results showed no significant different between the formulations. Mechanical stability time (MST) indicates higher stability of RVNRL with addition of VCO. The fatty acid composition in VCO indicate VCO was acting well as stabilizer for latex stabilizer formulation. (author)

  15. Water, oil, climate: a dried-up broken down world

    International Nuclear Information System (INIS)

    Gautier, C.; Fellous, J.L.

    2008-01-01

    Climate crisis, oil crisis, water crisis, food crisis: the 21. century has started badly. Climate is deteriorating under man's action and natural resources are drying up while demand is still on the rise under the double effect of demographic and economic growth. Even worse, tensions are working together and worsen each other in a climate of financial crisis. All warning lights are on the red and a huge challenge has been launched which involves all countries, developed and developing. Solutions are urgently needed, otherwise our civilization would be threatened. The reasoned use of technologies, but also the abatement of poverty and inequalities and the education of people are essential points to take up the challenge. The authors examine the interconnections between energy, water, food at the time of climate change and explore the possible alternative solutions. The lesson that should be learnt from their analysis is that everyone should contribute to the complex decisions that will have an impact on the future of humanity. (J.S.)

  16. Frying stability of rapeseed Kizakinonatane (Brassica napus) oil in comparison with canola oil.

    Science.gov (United States)

    Ma, Jin-Kui; Zhang, Han; Tsuchiya, Tomohiro; Akiyama, Yoshinobu; Chen, Jie-Yu

    2015-04-01

    This study was carried out to investigate the frying performance of Kizakinonatane (Brassica napus) oil during deep-fat frying of frozen French fries with/without replenishment. Commercial regular canola oil was used for comparison. The frying oils were used during intermittent frying of frozen French fries at 180, 200, and 220 ℃ for 7 h daily over four consecutive days. The Kizakinonatane oil exhibited lower levels of total polar compounds, carbonyl value, and viscosity as well as comparable color (optical density) values to that of the canola oil. The monounsaturated fatty acid/polyunsaturated fatty acid ratios were lower than that of canola oil, whereas the polyunsaturated fatty acid/saturated fatty acid ratios are higher than that of canola oil after heating. Results showed that fresh Kizakinonatane oil contains higher levels of acid value, viscosity, optical density values, tocopherols, and total phenolics contents than that of canola oil. Replenishment with fresh oil had significant effects on all chemical and physical parameters, except the acid value of the Kizakinonatane oil during frying processes. Based on the results, the Kizakinonatane oil is inherently suitable for preparing deep-fried foods at high temperatures. © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav.

  17. Decrease in oil prices: which consequences for the World economy and for France?

    International Nuclear Information System (INIS)

    Camatte, Hadrien; Darmet-Cucchiarini, Maxime; Gillet, Thomas; Masson, Emmanuelle; Meslin, Olivier; Padieu, Ysaline; Tavin, Alexandre

    2016-04-01

    Based of various statistics, this public publication first describes that, since summer 2014, oil price has been sharply decreasing (70 per cent) and keeping on decreasing due to a still abundant supply (with non conventional oil in the USA, and a still high production by OPEC countries) and a rather disappointing demand. It also outlines that production commitments stated by producers are still uncertain. This paper then notices that this oil price decrease could remain positive for World economy, but that some short term factors still impair these effects. This positive effect is indeed slow to appear in importing countries. Negative effects in exporting countries are emphasized by local economic policies. Moreover, there could be a transmission of this oil price decrease to the financial sphere, oil price decrease makes monetary policy more complex, and the USA are increasingly exposed to the energy sector activity. The third part shows that oil prices have positive effects on the French economy. They favour a wealth transfer from the rest of the world to the French economy, positively impacts companies margins and household purchase power on the short and medium terms, induces external effects as it also affects trade partners, and could result in an activity gain in the finance bill

  18. Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide

    Directory of Open Access Journals (Sweden)

    Xiaoma Fei

    2016-08-01

    Full Text Available A series of alkyl chain modified graphene oxides (AmGO with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13 and salt concentrations (from 0.1 to 1000 mM. In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.

  19. ON STABILITY OF THE OIL DISPLACEMENT FRONT UNDER CONDITIONS OF THERMOGAS IMPACT ON THE OIL BEARING LAYER

    Directory of Open Access Journals (Sweden)

    K. V. Dobrego

    2016-01-01

    Full Text Available The method of thermogas impact on the oil bearing layer is a perspective one to improve oil recovery. It is now under experimental implementation in Belarus. Stability of the thermal front and that of the oil displacement is a point of principle for the given technology. The article offers solution based on the method of small perturbations for the problem of the oil-displacement front stability under thermogas impact on the oil layer. The perturbation growth increment is shown to be quite different from that of the gas filtration combustion. Being determined by the perturbation wave number (or wave length, by difference in speed of the blowing filtration and that of the heat development front, by the ratios of densities, filtration coefficients, compressibility of the displacement agent and the displaced oil mass, and by other parameters. The author analyses the main parameters influencing the stability of the front. Recommendations are given on possible methods and procedures improving stability of the displacement front (neutralizing perturbation growth. The mechanisms of suppression or compensation of the front perturbation growth are as follows: the crude oil viscosity reduction and increase of that of the displacement agent, the displacement agent compressibility increase, increase of the thermogas impact heat-front width in the first instance at the expense of the temperature growth and alteration in the chemism (low temperature catalysts utilization, etc., reduction in speed of the front propagation and/or correspondingly of the displacement agent feed. Utilization of the gas or water-gas displacement agent as well as the agent impregnation with hydrophobic gases provides a relatively better stability of the front as compared to that employing water based compounds. Analytical data and derived recommendations are offered for utilization within the framework of general techniques and procedures of the thermogas impact process management

  20. Physical and antimicrobial properties of thyme oil emulsions stabilized by ovalbumin and gum arabic.

    Science.gov (United States)

    Niu, Fuge; Pan, Weichun; Su, Yujie; Yang, Yanjun

    2016-12-01

    Natural biopolymer stabilized oil-in-water emulsions were formulated using ovalbumin (OVA), gum arabic (GA) solutions and their complexes. The influence of interfacial structure of emulsion (OVA-GA bilayer and OVA/GA complexes emulsions) on the physical properties and antimicrobial activity of thyme oil (TO) emulsion against Escherichia coli (E. coli) was evaluated. The results revealed that the two types of emulsions with different oil phase compositions remained stable during a long storage period. The oil phase composition had an appreciable influence on the mean particle diameter and retention of the TO emulsions. The stable emulsion showed a higher minimum inhibitory concentration (MIC), and the TO emulsions showed an improved long-term antimicrobial activity compared to the pure thyme oil, especially complexes emulsion at pH 4.0. These results provided useful information for developing protection and delivery systems for essential oil using biopolymer. Copyright © 2016 Elsevier Ltd. All rights reserved.

  1. A comparison of two typical multicyclic models used to forecast the world's conventional oil production

    International Nuclear Information System (INIS)

    Wang Jianliang; Feng Lianyong; Zhao Lin; Snowden, Simon; Wang Xu

    2011-01-01

    This paper introduces two typical multicyclic models: the Hubbert model and the Generalized Weng model. The model-solving process of the two is expounded, and it provides the basis for an empirical analysis of the world's conventional oil production. The results for both show that the world's conventional oil (crude+NGLs) production will reach its peak in 2011 with a production of 30 billion barrels (Gb). In addition, the forecasting effects of these two models, given the same URR are compared, and the intrinsic characteristics of these two models are analyzed. This demonstrates that for specific criteria the multicyclic Generalized Weng model is an improvement on the multicyclic Hubbert model. Finally, based upon the resultant forecast for the world's conventional oil, some suggestions are proposed for China's policy makers. - Highlights: ► Hubbert model and Generalized Weng model are introduced and compared in this article. ► We conclude each model's characteristic and scopes and conditions of applicable. ► We get the same peak production and time of world's oil by applying two models. ► Multicyclic Generalized Weng model is proven slightly better than Hubbert model.

  2. Volatility spillover from world oil spot markets to aggregate and electricity stock index returns in Turkey

    International Nuclear Information System (INIS)

    Soytas, Ugur; Oran, Adil

    2011-01-01

    This study examines the inter-temporal links between world oil prices, ISE 100 and ISE electricity index returns unadjusted and adjusted for market effects. The traditional approaches could not detect a causal relationship running from oil returns to any of the stock returns. However, when we examine the causality using Cheung-Ng approach we discover that world oil prices Granger cause electricity index and adjusted electricity index returns in variance, but not the aggregate market index returns. Hence, our results show that the Cheung-Ng procedure with the use of disaggregated stock index returns can uncover new information that went unnoticed with the traditional causality tests using aggregated market indices. (author)

  3. Implementation of a World Wide Web server for the oil and gas industry

    International Nuclear Information System (INIS)

    Blaylock, R.E.; Martin, F.D.; Emery, R.

    1996-01-01

    The Gas and Oil Technology Exchange and Communication Highway (GO-TECH) provides an electronic information system for the petroleum community for exchanging ideas, data, and technology. The PC-based system fosters communication and discussion by linking the oil and gas producers with resource centers, government agencies, consulting firms, service companies, national laboratories, academic research groups, and universities throughout the world. The oil and gas producers can access the GO-TECH World Wide Web (WWW) home page through modem links, as well as through the Internet. Future GO-TECH applications will include the establishment of virtual corporations consisting of consortia of small companies, consultants, and service companies linked by electronic information systems. These virtual corporations will have the resources and expertise previously found only in major corporations

  4. Consuming the world's energy: Update series. Energy efficiency trends in oil countries

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-28

    This issue of Energy Detente addresses energy efficiency in selected oil producing countries over time and compare the varying effects of important crude oil price changes. As economies around the world heighten their benefits from conservation and efficient use of energy, oil producers will be crucial examples not only for their own sakes, but for consuming countries dependent upon their exports. In this sense, their potential for leadership and vision seems greater than ever. Specifically, 6 oil-exporting countries are featured: Australia, Kuwait, Indonesia, Nigeria, the United Kingdom, and Venezuela. This issue also presents the following: (1) the ED Refining Netback Data Series for the US Gulf and West Coasts, Rotterdam, and Singapore as of February 21, 1992; and (2) the ED Fuel Price/Tax Series for countries of the Eastern Hemisphere, February, 1992 edition.

  5. World crude oil and natural gas. A demand and supply model

    International Nuclear Information System (INIS)

    Krichene, Noureddine

    2002-01-01

    This paper examines world markets for crude oil and natural gas over the period 1918-1999; it analyzes the time-series properties of output and prices and estimates demand and supply elasticities during 1918-1973 and 1973-1999. Oil and gas prices were stable during the first period; they became volatile afterwards, reflecting deep changes in the market structure following the oil shock in 1973. Demand price elasticities were too low; however, demand income elasticities were high. Supply price elasticities were also too low. The elasticity estimates help to explain the market power of the oil producers and price volatility in response to shocks, and corroborate elasticity estimates in energy studies

  6. Low-Severity Hydroprocessing to Stabilize Bio-oil: TechnoEconomic Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Tews, Iva J.; Elliott, Douglas C.

    2014-08-31

    The impetus for this study was the suggestion that recent developments in fast pyrolysis (FP) bio-oil production had indicated instability of the bio-oil in storage which might lead to unacceptable viscosity increases. Commercial operation of FP in Finland began in 2014 and the distribution of the bio-oil to isolated users has been proposed as the long-term plan. Stability of the shipped bio-oil therefore became a concern. Experimental results at PNNL with low-severity hydroprocessing of bio-oil for stabilization has validated a process in which the stability of the bio-oil could be improved, as measured by viscosity increase following storage of the product at 80 °C for 24h. In the work reported here the assessed process configuration consists of fast pyrolysis followed by low temperature and pressure hydroprocessing to produce a stable fuel oil product. The product could then be stored for an extended period of time without significant viscosity increase. This work was carried out as part of a collaborative project between Technical Research Centre of Finland (VTT) and Pacific Northwest National Laboratory (PNNL). The public funding agents for the work were Tekes in Finland and the Bioenergy Technologies Office of the U.S. Department of Energy. The effort was proposed as an evaluation of the process developed in earlier collaboration and jointly invented by VTT and PNNL researchers.

  7. Antioxidant activity of rosemary essential oil fractions obtained by molecular distillation and their effect on oxidative stability of sunflower oil.

    Science.gov (United States)

    Mezza, Gabriela N; Borgarello, Ana V; Grosso, Nelson R; Fernandez, Héctor; Pramparo, María C; Gayol, María F

    2018-03-01

    The objective of this study was to evaluate the antioxidant activity of rosemary essential oil fractions obtained by molecular distillation (MD) and investigate their effect on the oxidative stability of sunflower oil. MD fractions were prepared in a series of low-pressure stages where rosemary essential oil was the first feed. Subsequently, a distillate (D1) and residue (R1) were obtained and the residue fraction from the previous stage used as the feed for the next. The residue fractions had the largest capacity to capture free radicals, and the lowest peroxide values, conjugated dienes and conjugated trienes. The antioxidant activity of the fractions was due to oxygenated monoterpenes, specifically α-terpineol and cis-sabinene hydrate. Oxidative stability results showed the residues (R1 and R4) and butylated hydroxytoluene had greater antioxidant activity than either the distillate fractions or original rosemary essential oil. The residue fractions obtained by short path MD of rosemary essential oil could be used as a natural antioxidants by the food industry. Copyright © 2017. Published by Elsevier Ltd.

  8. Studies on carotenoids and oxidative stability of winter squash seed and soybean oils

    Directory of Open Access Journals (Sweden)

    Helmy, H. E.

    1992-12-01

    Full Text Available Winter squash seed and soybean oils were extracted with commercial hexane. Carotenoids and other pigments m the oils were studied using spectrophotometric and thin layer chromatographic analysis. Three types of pigments were identified: carotenoids. mainly lutein and β-carotene, chlorophyll and some unidentified pigments. Carotenoids content were 70, 60, 0 ppm in crude, refined and bleached winter squash seed oil, and 80, 65, 0 ppm in crude, refined and bleached soybean oil respectively. Stability was evaluated for crude, refined and bleached winter squash seed and soybean oils and an 1:1 admixture. Mixing winter squash seed oil with soybean oil increased the stability of soybean oil. Crude oil showed greater stability than refined and bleached oils.

    Se han extraído con hexano comercial aceites de semilla de calabaza y de soja. Usando análisis espectrofotométrico y cromatografía en capa fina se han estudiado en estos aceites tres tipos de pigmentos: carotenoides, principalmente luteína y β-caroteno, clorofilas y otros no identificados. Los contenidos en carotenoides fueron 70, 60, 0 ppm en aceite de semilla de calabaza de invierno crudo, refinado y decolorado, y 80, 65, 0 ppm en aceite de soja crudo, refinado y decolorado respectivamente. Se ha evaluado la estabilidad de aceites de semilla de calabaza de invierno, soja y una mezcla 1:1 de ambos, en sus estados crudo, refinado y decolorado. La mezcla de semilla de calabaza de invierno con aceite de soja aumentó la estabilidad de este último. El aceite crudo mostró una mayor estabilidad que los aceites refinados y decolorados.

  9. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

    2016-04-25

    Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

  10. Effect of seed quality on oxidative stability of cold-pressed sunflower oil

    Directory of Open Access Journals (Sweden)

    Dimić Etelka B.

    2015-01-01

    Full Text Available The objective of this study was to investigate the impact of the storage time, content of the husk and impurities in the seed mass on the oxidative stability of the cold pressed sunflower oil. The oxidative stability of oil was analyzed by the RSM (Response Surface Methodology, where the response value (output of the model was the content of oxidation products measured via specific absorbance at 232 nm for conjugated dienes and 270 nm for conjugated trienes. Analyses were performed on the fresh oil samples and oil samples tempered under the Schaal-Oven’s test conditions (96 h at 63±2ºC. It was concluded that the seed storage time had significant impact on the primary (A1%232nm and secondary (A1%270nm oil oxidation products, both before (b1-p<0,001; b1-p=0,021 and after (b1-p=0,048; b1-p=0,033 the heating of oil. The content of impurities and husks in the seeds used for pressing also had an influence of the conjugated dienes and trienes contents in both, fresh and heated oil samples. However, their impact was not statistically significant. Interaction of seed storage time, the content of impurities and husks also exert some effect on the values of these quality parameters in the fresh oil as well as in the oil after the heat treatment, even though their influence is not significant. The obtained results have shown that the cold pressed sunflower oil had a good oxidative stability at temperatures up to 63±2ºC.

  11. "To change the world." Cairo conference reaches consensus on plan to stabilize world growth by 2015.

    Science.gov (United States)

    1994-12-01

    After 6 days of debate and 200 speakers during September 5-13, 1994, participants from 180 countries at the Cairo International Conference on Population and Development (ICPD) agreed on a strategy for curbing global population growth over the next 20 years. The objective was sustained economic growth and sustainable development. In his opening remarks, UN Secretary-General Boutros Boutros-Ghali said that the objective was to balance humanity and the environment with the means to sustain life, and that the efficacy of the world economic order depended to some extent on the ICPD. Participants were urged to use rigor, tolerance, and conscience in conference deliberations. Men and women should have the right and the means to choose their families' futures. The preamble stated that the ICPD would probably be the last opportunity in the twentieth century to address globally the issues relating to population and development. UN Population Fund Executive Director Nafis Sadik remarked that the ICPD had the potential to change the world. Egyptian President Mohamed Hosni Mubarak was elected president of the ICPD. Mubarak stated that solutions to population problems must go beyond demographic accounting and incorporate change in social, economic, and cultural conditions. Norway's Prime Minister Gro Harlem Brundtland stated that development in many countries never reached many women. She called it a hypocritical morality that allowed women to suffer and die from unwanted pregnancies, illegal abortions, and miserable living conditions. US Vice President Albert Gore called for comprehensive and holistic solutions. The essential features of social change would involve democracy, economic reform, low rates of inflation, low levels of corruption, sound environmental management, free and open markets, and access to developed country markets. Pakistan's Prime Minister Benazir urged the empowerment of women. Many expressed the concern about unsustainable consumption in industrialized

  12. Characterization of Whey Protein Oil-In-Water Emulsions with Different Oil Concentrations Stabilized by Ultra-High Pressure Homogenization

    Directory of Open Access Journals (Sweden)

    Essam Hebishy

    2017-02-01

    Full Text Available In this study, the effect of ultra-high-pressure homogenization (UHPH: 100 or 200 MPa at 25 °C, in comparison to colloid mill (CM: 5000 rpm at 20 °C and conventional homogenization (CH: 15 MPa at 60 °C, on the stability of oil-in-water emulsions with different oil concentrations (10, 30 or 50 g/100 g emulsified by whey protein isolate (4 g/100 g was investigated. Emulsions were characterized for their microstructure, rheological properties, surface protein concentration (SPC, stability to creaming and oxidative stability under light (2000 lux/m2. UHPH produced emulsions containing lipid droplets in the sub-micron range (100–200 nm and with low protein concentrations on droplet surfaces. Droplet size (d3.2, µm was increased in CH and UHPH emulsions by increasing the oil concentration. CM emulsions exhibited Newtonian flow behaviour at all oil concentrations studied; however, the rheological behaviour of CH and UHPH emulsions varied from Newtonian flow (n ≈ 1 to shear-thinning (n ˂ 1 and thixotropic behaviour in emulsions containing 50% oil. This was confirmed by the non-significant differences in the d4.3 (µm value between the top and bottom of emulsions in tubes left at room temperature for nine days and also by a low migration velocity measured with a Turbiscan LAB instrument. UHPH emulsions showed significantly lower oxidation rates during 10 days storage in comparison to CM and CH emulsions as confirmed by hydroperoxides and thiobarbituric acid-reactive substances (TBARS. UHPH emulsions treated at 100 MPa were less oxidized than those treated at 200 MPa. The results from this study suggest that UHPH treatment generates emulsions that have a higher stability to creaming and lipid oxidation compared to colloid mill and conventional treatments.

  13. Proceedings of the World Heavy Oil Congress : unconventional oil challenging conventional expectations

    International Nuclear Information System (INIS)

    2008-01-01

    This international technical and business conference provided a forum to promote heavy oil technology and foster relationships between supply and demand countries. The interactive forum between global industry professionals addressed technological, strategic and environmental challenges facing the unconventional oil industry, including seeking innovative, low cost technologies, driving high costs down; educating and leading the workforce to maintain high standards of production; and ensuring that the footprint on the land is as light as possible. It emphasized that as demand for the uses of heavy oil grows, so does the responsibility of managing sustainability not just from an environmental and social perspective, but also with respect to supply, including manpower and infrastructure. The technical conference featured sessions on advanced and enhanced processes; combustion processes; drilling and completions; geology and reservoir; heavy oil exploitation and development; mining, extraction and transportation; non thermal processes; production and operations; reservoir monitoring; SAGD processes; sustainable development; thermal processes; and, upgrading technology. All 124 presentations from the technical conference were catalogued separately for inclusion in this database. refs., tabs., figs

  14. World oil flow steady in 1992; stable market ahead for 1993

    International Nuclear Information System (INIS)

    Beck, R.J.

    1993-01-01

    World crude oil production in 1992 was virtually unchanged from 1991. Production last year averaged 59.96 million b/d, up only 17,000 b/d from 1991. Substantial production declines in the C.I.S. and U.S. were offset by increases among members of the Organization of Petroleum Exporting Countries and a number of other countries outside the OPEC sphere. Figures from the International Energy Agency (IEA) show world demand for petroleum products moved up 300,000 b/d to 66.9 million b/d. This included an addition to stocks of an estimated 1000,000 b/d. IEA predicts world demand will continue to rise in 1993 and OPEC output will advance to meet this higher level. Even though OPEC production is expected to be up for the year, seasonal swings in demand can cause price fluctuations. The paper describes OPEC production, non-OPEC production, oil prices, the world oil supply, Russian's decline, world demand, and the outlook for 1993

  15. Determination of the oxidation stability of biodiesel and oils by spectrofluorimetry and multivariate calibration.

    Science.gov (United States)

    Meira, Marilena; Quintella, Cristina M; Tanajura, Alessandra Dos Santos; da Silva, Humbervânia Reis Gonçalves; Fernando, Jaques D'Erasmo Santos; da Costa Neto, Pedro R; Pepe, Iuri M; Santos, Mariana Andrade; Nascimento, Luciana Lordelo

    2011-07-15

    Oxidation stability is an important quality parameter for biodiesel. In general, the methods used to evaluate the oxidation stability of oils and biodiesels are time-consuming. This work reports the use of spectrofluorimetry, a fast analytical technique, associated with multivariate data analysis as a powerful analytical tool to prediction of the oxidation stability. The prediction of the oxidation stability showed a good agreement with the results obtained by the EN14112 reference method Rancimat. The models presented high correlation (0.99276 and 0.97951) between real and predicted values. The R(2) values of 0.98557 and 0.95943 indicated the accuracy of the models to predict the oxidation stability of soy oil and soy biodiesel, respectively. The residual distribution does not follow a trend with respect to the predicted variables indicating the good quality of the fits. Copyright © 2011 Elsevier B.V. All rights reserved.

  16. Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing

    Energy Technology Data Exchange (ETDEWEB)

    Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B.; Burton, Sarah D.; Job, Heather M.; Lemmon, Teresa L.; Swita, Marie S.; Rotness, Leslie J.; Neuenschwander, Gary N.; Frye, John G.; Elliott, Douglas C.

    2015-10-15

    The use of fast pyrolysis as a potential renewable liquid transportation fuel alternative to crude oil depends on successful catalytic upgrading to produce a refinery-ready product with oxygen content and qualities (i.e. specific functional group or compound content) that is compatible with the product’s proposed insertion point. Catalytic upgrading of bio-oil requires high temperature and pressure, while similar to crude oil hydrotreating, is not as straightforward for the thermally unstable pyrolysis oil. For years, a two-temperature zone, downflow trickle bed reactor was the state-of-the art for continuous operation. However, pressure excursion due to plug formation still occurred, typically at the high temperature transition zone, leading to a process shutdown within 140 h. Recently, a bio-oil pre-treatment process, together with a robust commercial catalyst, was found to be enabling the continuous operation of the two-zone hydroprocessing system. Here, we report the results on pre-treating bio-oil at 413 K and 8.4 MPa of flowing H2 (500 L H2/L bio-oil, 0.5 L bio-oil/L catalyst bed) and the attempts to characterize this oil product to understand the chemistry which enabled the long-term processing of bio-oil.

  17. The chemical composition and the content of volatile oil: potential factors that can contribute to the oxidative stability of Nigella sativa L. crude oil.

    Science.gov (United States)

    Edris, Amr E

    2011-03-01

    The crude oil of Nigella sativa L. (Black cumin) has well-known nutraceutical and pharmaceutical properties. The oil is prone to rapid oxidative deterioration because of its high content of poly-unsaturated fatty acids. In the current investigation, different cold-pressed crude oils of N. sativa were examined for their composition of fatty acids and oxidative stability. The data obtained were correlated with the chemical composition and content of volatile oils, which correspond to each crude oil. Results indicated that different crude oils have the same fatty acid composition, and linoleic acid was the major constituent (60.0-61.7%). Though, the oxidative stability index of the crude oils was different ranging from 2.5 hr to 26.9 hr, as revealed by the Rancimate test at 100°C and airflow rate of 20 ml/min. The results showed that there is a straightforward correlation between the volatile oil content and the oxidative stability of the corresponding parent crude oil. In addition, high γ-terpinene content in the constitution of volatile oil can also be another contributing factor for enhancing the oxidative stability of the crude oil. The data presented here draw attention to some important factors that may guide the nutraceutical and food supplement processors in their screening for the highest quality of Nigella crude oils with maximum health benefits.

  18. Effect of rosemary extract and TBHQ on the stability of radish seed oil

    International Nuclear Information System (INIS)

    Gongling, Z.; Yancheng, G.

    2016-01-01

    The effects of rosemary extract (RE) and tert-Butylhydroquinone (TBHQ) on the storage stability of radish seed oil were studied according to the change of the acid value, peroxide value, tocopherol and sulforaphene in radish seed oil. The results showed that under conditions of accelerated oxidation by (60+-1) degree C, the storage stability of the radish seed oil with antioxidants could be significantly improved, among which TBHQ was better than RE. Besides, RE and TBHQ had a synergistic effect on antioxidation. The compound of 0.01% RE and 0.01% TBHQ had a better antioxidation effect than 0.07% RE and 0.02% TBHQ respectively, which recommended it can be a suitable antioxidant of radish seed oil. (author)

  19. Stabilization of Model Crude Oil Emulsion using Different ...

    African Journals Online (AJOL)

    MBI

    2015-12-31

    Dec 31, 2015 ... the invention of the internal combustion engine, the rise in commercial aviation and the increasing use of plastic. More than 4000 years ago, according to. Herodotus and Diodorus Siculus, asphalt was used in the construction of the walls and towers of. Babylon (Chisholm et al, 1911). There were oil pits.

  20. Stress determination and geomechanical stability analysis of an oil ...

    Indian Academy of Sciences (India)

    The geological history of this basin includes a long time subsidence and deposition which is interrupted by a short-term uplift. Its folding process began during Miocene and Pliocene anti- clines and continued until now, hence forming a long anticline (Mottiei 1995). These anticlines constitute most of oil traps in this basin.

  1. Interdependence between crude oil and world food prices: A detrended cross correlation analysis

    Science.gov (United States)

    Pal, Debdatta; Mitra, Subrata K.

    2018-02-01

    This article explores the changing interdependence between crude oil and world food prices at varying time scales using detrended cross correlation analysis that would answer whether the interdependence (if any) differed significantly between pre and post-crisis period. Unlike the previous studies that exogenously imposed break dates for dividing the time series into sub-samples, we tested whether the mean of the crude oil price changed over time to find evidence for structural changes in the crude oil price series and endogenously determine three break dates with minimum Bayesian information criterion scores. Accordingly, we divided the entire study period in four sample periods - January 1990 to October 1999, November 1999 to February 2005, March 2005 to September 2010, and October 2010 to July 2016, where the third sample period coincided with the period of food crisis and enabled us to compare the fuel-food interdependence across pre-crisis, during the crisis, and post-crisis periods. The results of the detrended cross correlation analysis extended corroborative evidence for increasing positive interdependence between the crude oil price and world food price index along with its sub-categories, namely dairy, cereals, vegetable oil, and sugar. The article ends with the implications of these results in the domain of food policy and the financial sector.

  2. Physical Stability of Oil in Water Emulsions in the Presence of Gamma Irradiated Gum Tragacanth

    DEFF Research Database (Denmark)

    Meybodi, Neda Mollakhalili; Mohammadifar, Mohammad Amin; Farhoodi, Mehdi

    2017-01-01

    Gum tragacanth (GT) exuded from an Iranian Astragalus species was γ-irradiated at 0, 0.75, 1.5, 3, 5, 7, 10 kGy and used to stabilize a model oil in water emulsion system. Stability and physicochemical properties of emulsion samples were investigated with respect to the effect of irradiation....... Emulsions were prepared by homogenizing 10% w/w sun flower oil with 90% w/w aqueous gum dispersions and stored quiescently at 25°C for 120 days. Results indicated that using 1.5 kGy irradiated GT was more effective in providing optimum values of apparent viscosity, number mean diameter, electrosteric...... repulsion and structure strength for getting maximum emulsion stability. GT significantly reduced the interfacial tension of the oil and water system, but no significant differences were observed among all irradiation treated and non-irradiated samples. This study revealed that, GT acts as a bifunctional...

  3. Effect of cinnamaldehyde on oxidative stability of several fats and oils at elevated temperatures

    Directory of Open Access Journals (Sweden)

    Tuğba İnanç Horuz

    2015-12-01

    Full Text Available Natural antioxidants recently have gained popularity since synthetic ones have toxic and carcinogenic effects. In the present study, effect of temperature (120, 150 and 180°C and cinnamaldehyde on oxidative stability of several oils (olive, hazelnut and palm oils and fats (milkfat and butter was examined. In order to compare the results with the synthetic antioxidant, butylated hydroxy toluene (BHT was used at a concentration of 200 ppm. This level is the legal maximum limit allowed. Experiments were conducted by using a PetroOxy device, a rapid small scale oxidation stability test. According to induction time values obtained by PetroOxy device, the stability of oils drastically decreased with increasing temperature. Cinnamaldehyde had no significant effect (p > 0.05 on all fat and oil samples compared to control (no antioxidant added and BHT added samples. BHT significantly increased induction times of all fat and oil samples at lower temperatures. However, it was not effective at 180°C (p < 0.05. It can be concluded that cinnamaldehyde could not be considered as a good alternative to BHT for preservation of fats and oils at high temperatures.

  4. Studies for the stabilization of coal-oil mixtures. Final report, August 1978-May 1981

    Energy Technology Data Exchange (ETDEWEB)

    Botsaris, G.D.; Glazman, Y.M.; Adams-Viola, M.

    1981-01-01

    A fundamental understanding of the stabilization of coal-oil mixtures (COM) was developed. Aggregation of the coal particles was determined to control both the sedimentation and rheological properties of the COM. Sedimentation stability of COM prepared with coal, 80% < 200 mesh, is achieved by particle aggregation, which leads to the formation of a network of particles throughout the oil. The wettability of coal powders was evaluated by the Pickering emulsion test and a spherical agglomeration test to assess its effect on the stability of various COM formulations. Sedimentation stability of hydrophilic coal-oil-water mixtures (COWM) involves the formation of water bridges between the coal particles, while less stabilization of oleophilic COWM is achieved by the formation of an emulsion. Anionic SAA were least sensitive to the coal type and enhanced the aggregation stability of the suspension. The effect of cationic SAA, nonionic SAA and polymer additives depended upon the specific chemical structure of the SAA, the water content of the COM and the type of coal. The sedimentation stability of ultrafine COM was not directly due to the fineness of the powder but due to the formation of a network of flocculated particles.

  5. Rheological properties and physical stability of ecological emulsions stabilized by a surfactant derived from cocoa oil and high pressure homogenization

    OpenAIRE

    Trujillo-Cayado, L. A.; Natera, A.; García, M. C.; Muñoz, J.; Alfaro, M. C.

    2015-01-01

    The goal of this work was to investigate the influence of the emulsification method on the rheological properties, droplet size distribution and physical stability of O/W green emulsions formulated with an eco-friendly surfactant derived from cocoa oil. The methodology used can be applied to other emulsions. Polyoxyethylene glycerol esters are non-ionic surfactants obtained from a renewable source which fulfill the environmental and toxicological requirements to be used as eco-fri...

  6. Effect of ripening inhibitor type on formation, stability, and antimicrobial activity of thyme oil nanoemulsion.

    Science.gov (United States)

    Ryu, Victor; McClements, David J; Corradini, Maria G; McLandsborough, Lynne

    2018-04-15

    The objective of this research was to study the impact of ripening inhibitor level and type on the formation, stability, and activity of antimicrobial thyme oil nanoemulsions formed by spontaneous emulsification. Oil-in-water antimicrobial nanoemulsions (10 wt%) were formed by titrating a mixture of essential oil, ripening inhibitor, and surfactant (Tween 80) into 5 mM sodium citrate buffer (pH 3.5). Stable nanoemulsions containing small droplets (d palm ≈ corn > canola > coconut which also depended on their ability to transfer hydrophobic antimicrobial constituents to the separated hydrophobic domain. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Oxidative stability of mayonnaise containing structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Jacobsen, Charlotte; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    Mayonnaise based on enzymatically produced specific structured lipid (SL) from sunflower oil and caprylic acid was compared with mayonnaise based on traditional sunflower oil (SO) or chemically randomized lipid (RL) with respect to their oxidative stability, sensory and rheological properties......, but was most likely influenced by the structure of the lipid, the lower tocopherol content and the higher initial levels of lipid hydroperoxides and secondary volatile oxidation compounds in the SL itself compared with the RL and traditional sunflower oil employed. EDTA was a strong antioxidant, while propyl...

  8. Distribution and quantitative assessment of world crude oil reserves and resources

    Science.gov (United States)

    Masters, Charles D.; Root, David H.; Dietzman, William D.

    1983-01-01

    World Demonstrated Reserves of crude oil are approximately 723 billion barrels of oil (BBO). Cumulative production is 445 BBO and annual production is 20 BBO. Demonstrated Reserves of crude-oil have declined over the past 10 years consistent with discoveries lagging production over the same period. The assessment of Undiscovered Resources shows a 90 percent probability that the amount discoverable lies between 321 and 1,417 BBO, 550 BBO being the most likely value. The most likely value for Ultimate recoverable resources is 1,718 BBO. The distribution of Ultimate Resources of crude oil will remain highly skewed toward the Middle East; no frontier areas that have potentials large enough to significantly affect present distribution are recognized. Rates of discovery have continued to decline over the past 20 years even though exploration activity has increased in recent years. Prudence dictates, therefore, that the low side of the assessment of Undiscovered Resources be responsibly considered and that alternate energy sources be a part of future planning. Extra-heavy oil and bitumen are assessed separately, with Reserves being figured as the annual productive capacity of installed facilities times 25 years. The annual production of extra-heavy oil is about 8 million barrels and of bitumen about 60 million barrels.

  9. New antioxidants and antioxidant systems for improvement of the stability of vegetable oils and fish oils

    Science.gov (United States)

    Most vegetable oils and fish oils contain polyunsaturated fatty acids ranging from 18 carbons with two to three double bonds, to 22 or 24 carbons, and up to six double bonds. Nutritional research over the years has indicated that individual fatty acids from the diet play a complex role in nutrition ...

  10. Oxidative stabilization of mixed mayonnaises made with linseed oil and saturated medium-chain triglyceride oil

    DEFF Research Database (Denmark)

    Raudsepp, Piret; Brüggemann, Dagmar A.; Lenferink, Aufried

    2014-01-01

    storage was lower in mixed mayonnaise compared to LSO mayonnaise, while in mixed oil mayonnaise the level of peroxides was constantly low. Mixed oil mayonnaise had a lower rate of oxygen consumption than mixed mayonnaise, LSO mayonnaise having the highest rate. The decay of water-soluble nitroxyl radicals...

  11. The effects of different extraction methods on composition and storage stability of sturgeon oil.

    Science.gov (United States)

    Hao, Shuxian; Wei, Ya; Li, Laihao; Yang, Xianqing; Cen, Jianwei; Huang, Hui; Lin, Wanling; Yuan, Xiaomin

    2015-04-15

    The objective of this study was to assess the effect of different extraction methods on oil yield, colour attributes, oxidative stability, fatty acids composition and production of volatile compounds in sturgeon oil during storage. The supercritical fluid extraction (SFE) method with carbon dioxide resulted in higher oil yields, better colour attributes, and higher oxidative stability compared to other traditional extraction methods such as enzymatic extraction, amino, and wet reduction. After storage at 4 °C for 33 days, the aldehyde content in oil extracted by the enzymatic extraction and wet reduction methods was twice as high as that obtained by the other methods. There was a significant reduction in the content of total acids in oils extracted by the enzymatic extraction and wet reduction methods (poil extracted by the amino method. The oil extracted by SFE exhibited higher UFA and lower SFA. Significant diffidence among PUFA with C above 20 was observed in oil extracted with SFE. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Effect of pretreatment on the proximate composition, physicochemical characteristics and stability of Moringa peregrina oil

    Directory of Open Access Journals (Sweden)

    H. A. Sulaiman

    2018-01-01

    Full Text Available The present research work was intended to study the influence of roasting and germination of the kernel seeds of Sudanese Moringa peregrina on the physicochemical characteristics and the oxidative stability of the extracted oil. Roasting was carried out at 180 ˚C for 25 minutes, whereas germination was done at ambient conditions in a wet jute bag for 5–7 days. The oil was extracted using n-hexane in a Soxhlet extraction apparatus. The results show that the oil contains α-tocopherols (152mg/kg and oleic acid (above 70% as the major tocols and fatty acids, respectively. Germination reduced the peroxide value and increased the acid value in a significant way (p < 0.05 whereas the opposite trend was noticed in the case of roasting. It is crucial to note that, with the exception of the acid value of the germinated sample, peroxide and acid values remained below one meq O2/Kg of oil and one mg KOH/g of oil, respectively. The oxidative stability of the oil from the roasted sample was increased almost by 80% compared to the raw one. Roasting of the kernels prior to oil extraction is imperative for improving its oxidation resistance and the physicochemical characteristics.

  13. Effect of pretreatment on the proximate composition, physicochemical characteristics and stability of Moringa peregrina oil

    International Nuclear Information System (INIS)

    Sulaiman, H.A.; Ahmad, E. E.M.; Mariod, A.A.; Mathäus, B.; Salaheldeen, M.

    2017-01-01

    The present research work was intended to study the influence of roasting and germination of the kernel seeds of Sudanese Moringa peregrina on the physicochemical characteristics and the oxidative stability of the extracted oil. Roasting was carried out at 180 °C for 25 minutes, whereas germination was done at ambient conditions in a wet jute bag for 5–7 days. The oil was extracted using n-hexane in a Soxhlet extraction apparatus. The results show that the oil contains α-tocopherols (152mg/kg) and oleic acid (above 70%) as the major tocols and fatty acids, respectively. Germination reduced the peroxide value and increased the acid value in a significant way (p < 0.05) whereas the opposite trend was noticed in the case of roasting. It is crucial to note that, with the exception of the acid value of the germinated sample, peroxide and acid values remained below one meq O2/Kg of oil and one mg KOH/g of oil, respectively. The oxidative stability of the oil from the roasted sample was increased almost by 80% compared to the raw one. Roasting of the kernels prior to oil extraction is imperative for improving its oxidation resistance and the physicochemical characteristics. [es

  14. United States foreign oil policy since World War 1 : for profits and security. 2 ed.

    Energy Technology Data Exchange (ETDEWEB)

    Randall, S.J.

    2005-07-01

    This book provided a historical context for United States global oil politics, with a focus on the goals, accomplishments and challenges of United States foreign oil policy, as well as on the relationship between the state and private sectors. This second edition has integrated developments in global politics since the end of the Cold War. It was suggested that many factors have provided the context for oil policy formation: a succession of crises in Iran since the 1950s; 2 wars in Iraq; U.S. intervention in Afghanistan; the threat of international terrorism since September 11, 2001; ongoing conflicts between Israel and the Arab nations in the Middle East; political instability in Saudi Arabia and in Venezuela and the trend towards trade and investment liberalization in Latin America in the 1990s. In addition, the emergence of oil sands reserves in Canada and other sources of non-conventional oil were discussed. Nationalism and oil policies in the Depression and World War 2 were examined. The structure of decision-making in oil policies was examined. Domestic and offshore resources were reviewed, and an outline of international agreements and relationships was presented. Issues concerning OPEC countries and the Iranian Revolution were examined. It was concluded that the United States has become more and not less vulnerable, despite its military strength. The author suggested that the main policy challenge to the United States may well be the tension between its commitment to Israel and its determination to avoid alienating the Arab oil-producing states. refs., tabs., figs.

  15. Identification of salivary proteins at oil-water interfaces stabilized by lysozyme and beta-lactoglobulin.

    Science.gov (United States)

    Silletti, Erika; Vitorino, Rui M P; Schipper, Raymond; Amado, Francisco M L; Vingerhoeds, Monique H

    2010-04-01

    In this research, we investigated the interaction occurring between oil-in-water emulsion droplets, stabilized by different emulsifiers, i.e. lysozyme and beta-lactoglobulin (beta-lg), and salivary proteins (SPs) with a molecular mass (M(r)) above about 10kDa. Different techniques, i.e. infrared spectroscopy, Western blotting, PAS staining and SDS-PAGE coupled to MS, were employed for this purpose. This study demonstrated the interaction between several salivary proteins and the emulsifiers at the oil-water interfaces. In particular, results show that the high M(r) mucin MUC5B was strongly bound to lysozyme stabilized emulsions, whereas beta-lg stabilized emulsions associated with MUC7 and, moderately, with MUC5B. Furthermore, we observed that salivary proteins in the range M(r) 10-100kDa associated differently with emulsion droplets. A large majority of SPs was found to interact with lysozyme stabilized emulsion droplets whilst in case of beta-lg stabilized emulsions, the SPs distribute more evenly between the fraction associated and non-associated with the droplets. A clear example is alpha-amylase (M(r) approximately 55kDa) which predominantly associates with lysozyme stabilized emulsion droplets, but not with beta-lg emulsion droplets. To conclude, our findings indicate that adsorption/association of salivary protein components onto the emulsion droplets is related to the type of emulsifying proteins at the oil-water interfaces and it is probably driven by the overall net charge at the droplet's oil-water interfaces, i.e. positive for lysozyme stabilized emulsions and negative for beta-lactoglobulin stabilized emulsion at neutral pH.

  16. Do emerging markets matter in the world oil pricing system? Evidence of imported crude by China and India

    International Nuclear Information System (INIS)

    Hong Li; Lin Xiaowen, Sharon

    2011-01-01

    This paper provides empirical evidence on the changing structure of world oil price system by identifying an additional driver-emerging market factor. We choose China and India as a representative of emerging markets to examine if the quantity of crude oil imported by China and India is significant in the existing oil pricing system (. Our data starts from January 2002 and ends in March 2010, which includes the oil shock of 2007-2008. We utilize cointegration and error correction model framework developed by and in the analysis. Our results indicate that demand from emerging markets has become a significant factor in the world oil pricing system since 2003. This result is significant as it lends empirical support to the widely held conjecture that the oil shock of 2007-2008 is a demand-led shock (). Our result also has significant policy implications that go beyond the oil shock. The emerging market factor is there to stay and reflects the changing power between emerging and developed economies in the world economic system as a result of decades of fast economic development in the former. It will certainly influence policy issues related to oil and beyond. - Highlights: → We test the existing oil price modelling with data from 2002-2010. → We find evidence of structural breaks in the world oil pricing model. → We find that emerging market factor is a new driver in the world oil pricing system since 2003. → The emerging market factor lends empirical support to 'consumption-led' conjecture of oil shock. → New factor reflects significant changes of oil demand landscape following shifting economic power.

  17. Influence ofTeucrium poliumL. essential oil on the oxidative stability of canola oil during storage.

    Science.gov (United States)

    Sayyad, Ruhollah; Farahmandfar, Reza

    2017-09-01

    The susceptibility of Teucrium polium essential oil (EO) as an antioxidant for canola oil was studied. Major compounds of the EO were 11-acetoxyeudesman-4-α-ol (26.3%) and α-bisabolol (24.6%). Different concentrations (200, 600 and 1200 ppm) of EO and synthetic antioxidant BHA (200 ppm) were added to canola oil and incubated for 60 days at room temperature. Acid value (AV), peroxide value (PV), carbonyl value (CV), iodine value (IV), total phenolics (TP), total polar compounds (TPC) and oxidative stability index (OSI) of canola oil were determined. Antioxidant capacity of the EO was measured by DPPH and β-carotene-linoleic acid assays. Results exhibited that DPPH and β-carotene-linoleic acid experiment detections on the EO were analogous in high concentrations to those detected on BHA. Moreover, incorporated EO samples had better AV, PV, CV, IV, TP and TPC than control. EO at concentration of 600 ppm indicated higher antioxidant activity in canola oil compared with BHA.

  18. Stability of canola oil encapsulated by co-extrusion technology: effect of quercetin addition to alginate shell or oil core.

    Science.gov (United States)

    Waterhouse, Geoffrey I N; Wang, Wei; Sun-Waterhouse, Dongxiao

    2014-01-01

    This study examines the co-extrusion encapsulation of canola oil by alginate, with an antioxidant (quercetin) incorporated either in the oil core or alginate shell. Optical and environmental scanning electron microscopy revealed spherical beads of diameter ∼350μm and wall thickness ∼65μm. Bead appearance, size, wall thickness and surface characteristics did not change appreciably after treatments at pH 3 for 2h, pH 6.5 for 2h or pH 6.5 for 1min then pH 3 for 2h, although the amounts of phenolics released from beads differed depending on the conditions. The quercetin addition approach strongly influenced the stability of canola oil during storage at 20 and 38°C. Quercetin in the core more effectively suppressed oil deterioration. Quercetin in shell caused a higher phenolic content after storage. FTIR and HPLC analyses were used to track changes in the chemical composition of the encapsulated oil beads during storage. Copyright © 2013 Elsevier Ltd. All rights reserved.

  19. Impact of fat and water crystallization on the stability of hydrogenated palm oil-in-water emulsions stabilized by a nonionic surfactant.

    Science.gov (United States)

    Thanasukarn, Parita; Pongsawatmanit, Rungnaphar; McClements, D Julian

    2006-05-17

    The influence of (0-40 wt %) sucrose and (0 and 150 mmol/kg) sodium chloride on the physical properties of 20 wt % hydrogenated palm oil-in-water emulsions stabilized by 2 wt % Tween 20 after crystallization of the oil phase only or both the oil and water phases has been examined. Emulsion stability was assessed by differential scanning calorimetry measurements of fat destabilization after cooling-heating cycles and by measurements of mean particle size, percent destabilized fat, and percent free oil obtained from gravitational separation after isothermal storage (at -40 to +37 degrees C). At storage temperatures where the oil phase was partially crystalline and the water was completely liquid, the emulsions were unstable to droplet coalescence and oiling off because of partial coalescence. Both NaCI and sucrose increased the extent of partial coalescence in the emulsions. At storage temperatures where both oil and water crystallized, the emulsions were completely destabilized. The stability of the emulsions to freezing and thawing could be improved somewhat by adding sucrose (>20 wt %). Emulsions stabilized by whey proteins were shown to have better freeze-thaw stability than those stabilized by Tween 20, especially in the presence of sucrose. These results may help formulate food emulsions with improved freeze-thaw stability.

  20. Oil and Beyond Expanding British Imperial Aspirations, Emerging Oil Capitalism, and the Challenge of Social Questions in the First World War

    NARCIS (Netherlands)

    Atabaki, Touraj; Ehsani, Kaveh; Bley, Helmut; Kremers, Anorthe

    2014-01-01

    With the onset of the First World War, the British state crafted a new strategy of shifting its industry, military and navel units from consuming coal to oil energy. This transition effectively turned Persian oil into a strategic military as well as economic resource of fundamental importance to the

  1. Assessing the effect of oil price on world food prices. Application of principal component analysis

    International Nuclear Information System (INIS)

    Esmaeili, Abdoulkarim; Shokoohi, Zainab

    2011-01-01

    The objective of this paper is to investigate the co-movement of food prices and the macroeconomic index, especially the oil price, by principal component analysis to further understand the influence of the macroeconomic index on food prices. We examined the food prices of seven major products: eggs, meat, milk, oilseeds, rice, sugar and wheat. The macroeconomic variables studied were crude oil prices, consumer price indexes, food production indexes and GDP around the world between 1961 and 2005. We use the Scree test and the proportion of variance method for determining the optimal number of common factors. The correlation coefficient between the extracted principal component and the macroeconomic index varies between 0.87 for the world GDP and 0.36 for the consumer price index. We find the food production index has the greatest influence on the macroeconomic index and that the oil price index has an influence on the food production index. Consequently, crude oil prices have an indirect effect on food prices. (author)

  2. Stability of the spreading in small-world network with predictive controller

    International Nuclear Information System (INIS)

    Bao, Z.J.; Jiang, Q.Y.; Yan, W.J.; Cao, Y.J.

    2010-01-01

    In this Letter, we apply the predictive control strategy to suppress the propagation of diseases or viruses in small-world network. The stability of small-world spreading model with predictive controller is investigated. The sufficient and necessary stability condition is given, which is closely related to the controller parameters and small-world rewiring probability p. Our simulations discover a phenomenon that, with the fixed predictive controller parameters, the spreading dynamics become more and more stable when p decreases from a larger value to a smaller one, and the suitable controller parameters can effectively suppress the spreading behaviors even when p varies within the whole spectrum, and the unsuitable controller parameters can lead to oscillation when p lies within a certain range.

  3. Characteristics, Composition and Oxidative Stability of Lannea microcarpa Seed and Seed Oil

    Directory of Open Access Journals (Sweden)

    Patrice Bazongo

    2014-02-01

    Full Text Available The proximate composition of seeds and main physicochemical properties and thermal stability of oil extracted from Lannea microcarpa seeds were evaluated. The percentage composition of the seeds was: ash (3.11%, crude oil (64.90%, protein (21.14%, total carbohydrate (10.85% and moisture (3.24%. Physicochemical properties of the oil were: refractive index, 1.473; melting point, 22.60°C; saponification value, 194.23 mg of KOH/g of oil; iodine value, 61.33 g of I2/100 g of oil; acid value, 1.21 mg of KOH/g of oil; peroxide value, 1.48 meq of O2/kg of oil and oxidative stability index, 43.20 h. Oleic (43.45%, palmitic (34.45%, linoleic (11.20% and stearic (8.35% acids were the most dominant fatty acids. Triacylglycerols with equivalent carbon number (ECN 48 and ECN 46 were dominant (46.96% and 37.31%, respectively. The major triacylglycerol constituents were palmitoyl diolein (POO (21.23%, followed by dipalmitoyl olein (POP (16.47%, palmitoyl linoleyl olein (PLO (12.03%, dipalmitoyl linolein (PLP (10.85% and dioleoyl linolein (LOO (9.30%. The total polyphenol and tocopherol contents were 1.39 mg GAE g−1 DW and 578.56 ppm, respectively. γ-Tocopherol was the major tocopherol (437.23 ppm. These analytical results indicated that the L. microcarpa seed oil could be used as a frying oil and in the cosmetic industry.

  4. Ceramic membrane fouling during ultrafiltration of oil/water emulsions: roles played by stabilization surfactants of oil droplets.

    Science.gov (United States)

    Lu, Dongwei; Zhang, Tao; Ma, Jun

    2015-04-07

    Oil/water (O/W) emulsion stabilized by surfactants is the part of oily wastewater that is most difficult to handle. Ceramic membrane ultrafiltration presently is an ideal process to treat O/W emulsions. However, little is known about the fouling mechanism of the ceramic membrane during O/W emulsion treatment. This paper investigated how stabilization surfactants of O/W emulsions influence the irreversible fouling of ceramic membranes during ultrafiltration. An unexpected phenomenon observed was that irreversible fouling was much less when the charge of the stabilization surfactant of O/W emulsions is opposite to the membrane. The less ceramic membrane fouling in this case was proposed to be due to a synergetic steric effect and demulsification effect which prevented the penetration of oil droplets into membrane pores and led to less pore blockage. This proposed mechanism was supported by cross section images of fouled and virgin ceramic membranes taken with scanning electron microscopy, regression results of classical fouling models, and analysis of organic components rejected by the membrane. Furthermore, this mechanism was also verified by the existence of a steric effect and demulsification effect. Our finding suggests that ceramic membrane oppositely charged to the stabilization surfactant should be applied in ultrafiltration of O/W emulsions to alleviate irreversible membrane fouling. It could be a useful rule for ceramic membrane ultrafiltration of oily wastewater.

  5. Ceramic membrane fouling during ultrafiltration of oil/water emulsions: Roles played by stabilization surfactants of oil droplets

    KAUST Repository

    Lu, Dongwei

    2015-04-07

    Oil/water (O/W) emulsion stabilized by surfactants is the part of oily wastewater that is most difficult to handle. Ceramic membrane ultrafiltration presently is an ideal process to treat O/W emulsions. However, little is known about the fouling mechanism of the ceramic membrane during O/W emulsion treatment. This paper investigated how stabilization surfactants of O/W emulsions influence the irreversible fouling of ceramic membranes during ultrafiltration. An unexpected phenomenon observed was that irreversible fouling was much less when the charge of the stabilization surfactant of O/W emulsions is opposite to the membrane. The less ceramic membrane fouling in this case was proposed to be due to a synergetic steric effect and demulsification effect which prevented the penetration of oil droplets into membrane pores and led to less pore blockage. This proposed mechanism was supported by cross section images of fouled and virgin ceramic membranes taken with scanning electron microscopy, regression results of classical fouling models, and analysis of organic components rejected by the membrane. Furthermore, this mechanism was also verified by the existence of a steric effect and demulsification effect. Our finding suggests that ceramic membrane oppositely charged to the stabilization surfactant should be applied in ultrafiltration of O/W emulsions to alleviate irreversible membrane fouling. It could be a useful rule for ceramic membrane ultrafiltration of oily wastewater. © 2015 American Chemical Society.

  6. Antioxidants stabilizing fish oils : effect of antioxidant, storage temperature and type of fish oil

    OpenAIRE

    Kasbo, Mari Kristine

    2012-01-01

    The aim of this study was to investigate four commercially available antioxidants in two fish oils. The antioxidants were investigated to see which one of them is most efficient in preventing oxidation. Antioxidants were added in three levels to find the optimal concentration. In addition a possible synergistic effect between the antioxidants was investigated. Two different oils with different concentration of EPA and DHA were added antioxidants. Four of the antioxidants were single antioxida...

  7. Chemical composition and oxidative stability of Tunisian monovarietal virgin olive oils with regard to fruit ripening.

    Science.gov (United States)

    Baccouri, Olfa; Guerfel, Mokhtar; Baccouri, Bechir; Cerretani, Lorenzo; Bendini, Alessandra; Lercker, Giovanni; Zarrouk, Mokhtar; Daoud Ben Miled, Douja

    2008-08-15

    The chemical composition of virgin olive oil may be influenced by genotype and different agronomic (i.e. fruit ripeness degree, water supply) and technological factors. This article reports the evaluation of the influence of the olive ripening stage on the quality indices, the major and the minor components and the oxidative stability of the two main monovarietal Tunisian cultivars (cvv. Chétoui and Chemlali) virgin olive oils. Moreover, the olives cv. Chétoui were tested in a rain-fed control and an irrigation regime. The oils sampled at five different ripeness stages were submitted to liquid chromatographic determination (HPLC-DAD/MSD) of their quali-quantitative phenolic and tocopherolic profiles. Moreover, the triacylglycerol and fatty acid compositions, and minor components such as squalene, pigments and their relation with the oil oxidative stability were evaluated. The tested oils showed very good correlation between the oxidative stability and the concentrations of total phenols, practically secoiridoids and α-tocopherol. Copyright © 2008 Elsevier Ltd. All rights reserved.

  8. Stabilized oil production conditions in the development equilibrium of a water-flooding reservoir

    Directory of Open Access Journals (Sweden)

    Renshi Nie

    2016-12-01

    Full Text Available Water injection can compensate for pressure depletion of production. This paper firstly investigated into the equilibrium issue among water influx, water injection and production. Equilibrium principle was elaborated through deduction of equilibrium equation and presentation of equilibrium curves with an “equilibrium point”. Influences of artificial controllable factors (e.g. well ratio of injection to production and total well number on equilibrium were particularly analyzed using field data. It was found that the influences were mainly reflected as the location move of equilibrium point with factor change. Then reservoir pressure maintenance level was especially introduced to reveal the variation law of liquid rate and oil rate with the rising of water cut. It was also found that, even if reservoir pressure kept constant, oil rate still inevitably declined. However, in the field, a stabilized oil rate was always pursued for development efficiency. Therefore, the equilibrium issue of stabilized oil production was studied deeply through probing into some effective measures to realize oil rate stability after the increase of water cut for the example reservoir. Successful example application indicated that the integrated approach was very practical and feasible, and hence could be used to the other similar reservoir.

  9. Gallic Acid Grafted Chitosan Has Enhanced Oxidative Stability in Bulk Oils.

    Science.gov (United States)

    Gim, Seo Yeong; Hong, Seungmi; Kim, Mi-Ja; Lee, JaeHwan

    2017-07-01

    Gallic acid (GA) was grafted in chitosan and the effects of GA grafted chitosan (GA-g-CS) on the oxidative stability in bulk oil was tested at 60 and 140 °C. To text oxidative stability in oils, headspace oxygen content, conjugated dienoic acid (CDA) value, p-anisidine value (p-AV), and acid value were determined. Chitosan itself did not show antioxidative or prooxidative effects in oils at 60 °C. However, GA-g-CS and GA acted as antioxidants at 60 °C. At 140 °C heating with moisture supplied condition, different results were observed. GA-g-CS acted as antioxidants based on the results of CDA and p-AV. However, chitosan showed the highest oxidative stability based on results of acid value and brown color formation at 140 °C. This could be due to reduction of moisture content by chitosan. GA was continuously released from GA-g-CS in bulk oil. This might have provided extra antioxidant activities to oils. © 2017 Institute of Food Technologists®.

  10. Oxidative stability and estimate of the shelf life of sacha inchi (Plukenetia volubilis L. oil

    Directory of Open Access Journals (Sweden)

    Gilbert Rodríguez

    2015-09-01

    Full Text Available Sacha inchi oil is rich in polyunsaturated fatty acids that may rust, limiting their shel flife. The Rancimat method is official, for evaluations of oxidative stability accelerated in oils. Industrially conventional techniques based on physical and chemical indicators are used; there are no studies of correlation between them and Rancimat. This work has for objective correlate the oxidative stability index (OSI Sacha inchi oil obtained by Rancimat at temperatures of 80°, 90°, 100° and 110 °C under an air flow of 15 L/h, with the values of physic-chemical indicators such as Index peroxide, p-anisidine, totox and density. Also estimated by mathematical extrapolation, the shelf life of sacha inchi oil to usual storage temperatures. OSI values were: 0.493 ± 0.01 h at 110 ºC, 1.590 ± 0.06 h at 100 ºC, 4.645 ± 0.1 h at 90 ºC and 20.512 ± 0.02 h at 80 ºC. High correlation has been established between values of OSI vs physicochemical quality indices (0.9322 < r < 0.9965. The activation energy was found 137.90 kJ/mol, which explains the high oxidative stability for the oil, estimating a lifetime of 3.29, 1.79 and 0.79 years at 20, 25 and 30 °C respectively.

  11. The world oil market is not one great pool: A reply to Rodriguez and Williams

    International Nuclear Information System (INIS)

    Weiner, R.J.

    1993-01-01

    In a paper by Rodriguez and Williams (Energy Studies Review, 1993), the case for a single-pool world oil market is put forward. Criticisms of the assumptions and conclusions are offered. To counter the paper's assumption that antitrust is the relevant metric for measuring the extent of geographic markets, it is argued that for energy security policy decisions, it is the economic market which matters. The paper does show that the world oil market is indeed unified in the long run, but this is not relevant to the short term, the relevant time-frame for energy security decisions. The paper's choice of spot market data for its cointegration analysis is also criticized by using several examples of pricing decisions that would not make sense in a unified world market but which do make sense in a regionalized market. It is also unclear how representative spot prices are of the oil market. Finally, the conclusions of the paper that favor policies focusing on secure vs insecure import sources and supplier diversification are seen as unsupported by the paper's statistical findings. 15 refs

  12. Oxidative stability of milk drinks containing structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    Milk drinks containing 5% traditional sunflower oil (SO), randomized lipid (RL) or specific structured lipid (SL) (both produced from SO and tricaprylin/caprylic acid) were compared with respect to their particle size, viscosity and oxidative stability during storage. Furthermore, the effect...

  13. Oxidative stability of structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    Traditional sunflower oil (SO), randomized lipid (RL) and specific structured lipid (SL), both produced from SO and tricaprylin/caprylic acid, respectively, were stored for up to 12 wk to compare their oxidative stabilities by chemical and sensory analyses. Furthermore, the effect of adding...

  14. Influence of Picual olive ripening on virgin olive oil alteration and stability during potato frying.

    Science.gov (United States)

    Olivero-David, Raul; Mena, Carmen; Pérez-Jimenez, M Angeles; Sastre, Blanca; Bastida, Sara; Márquez-Ruiz, Gloria; Sánchez-Muniz, Francisco J

    2014-12-03

    Ripening modifies oil attributes and composition. However, the influence of olive ripening on virgin olive oil (VOO) thermal oxidative stability on food-frying has not been studied yet. Oils from Picual olives of low (VOO1), medium (VOO2), and high (VOO3) ripeness were obtained, and their thermal oxidative stability during 40 potato-fryings was tested. Unused VOO1 showed higher antioxidant content and oxidative stability than VOO2 and VOO3. Polar compounds (PC), oligomers, and altered fatty acid methyl esters (polar-FAME) increased, whereas linoleic acid, polyphenols, and tocopherols decreased in the three VOOs through frying. The alteration was lower in VOO1, followed by VOO2 (0.105, 0.117, and 0.042 g/100 g oil less of PC, oligomers and polar-FAME per frying, respectively, in VOO1 than in VOO3). In conclusion, VOO obtained from low-ripeness Picual olives should be preferred when frying fresh-potatoes due to its higher thermal and oxidative stability, permitting a higher number of potato-frying uses.

  15. Differential scanning calorimetry thermal properties and oxidative stability indices of microwave heated extra virgin olive oils.

    Science.gov (United States)

    Chiavaro, Emma; Rodriguez-Estrada, Maria Teresa; Bendini, Alessandra; Rinaldi, Massimiliano; Cerretani, Lorenzo

    2011-01-30

    The use of differential scanning calorimetry (DSC) for assessing the deterioration effect of microwave heating on vegetable oils, and on olive oils in particular, has been partially explored in literature. The aim of this work was to evaluate the potential of DSC to discriminate among microwaved extra virgin olive oils (EvOo from different olive cultivar and origin), according to changes on thermal properties (upon cooling and heating) and traditional oxidative stability indices (peroxide, p-anisidine and TOTOX values). An elevated value of lipid oxidation was reached by the most unsaturated EvOo sample (9.5% of linoleic acid) at 6 min of microwave treatment. Free acidity significantly increased (0.42%) only for the oil sample with the highest water content (874 mg kg(-1) oil) at the longest time of treatment. Crystallisation enthalpies significantly decreased and the major exothermic peak shifted towards lower temperature, leading to enlargement of the transition range in all samples due to the formation of weak and mixed crystals among triacylglycerols and lipid degradation products. On the contrary, thermal properties upon heating appeared to similarly vary among samples. The analysis of DSC thermal properties upon cooling seemed to clearly discriminate among different EvOo samples after microwaving. The relation between changes of thermal properties and oxidation parameters should be further studied using additional oxidative stability indices on a larger set of oil samples, due to the complexity of EvOo composition. 2010 Society of Chemical Industry.

  16. Stabilization of heavy oil-water emulsions using a bio/chemical emulsifier mixture

    Energy Technology Data Exchange (ETDEWEB)

    Farahbakhsh, A.; Taghizadeh, M.; Movagharnejad, K. [Chemical Engineering Department, Babol University of Technology, Babol (Iran, Islamic Republic of); Yakhchali, B. [National Institute of Genetic Engineering and Biotechnology, Tehran (Iran, Islamic Republic of)

    2011-11-15

    In this study, the viscosity reduction of heavy oil has been investigated through the formation of oil-water emulsion using a bio/chemical emulsifier mixture. Four bioemulsifiers from indigenous Rhodococcus ergthropolis and Bacillus licheniformis strains were used to stabilize a highly-viscous oil-in-water emulsion. The Taguchi method with an L{sub 9} orthogonal array design was used to investigate the effect of various control factors on the formation of the oil/water emulsions. An emulsion with lowest viscosity was formed using ACO4 strain. The substantial stability of the oil-in-water emulsion allows the heavy oil to be transported practically over long distances or remain stationary for a considerable period of time prior to utilization. As the result of Taguchi analysis, the temperature and concentration of the emulsifier had a significant influence on viscosity reduction of the emulsion. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  17. The long-term supply/demand trend of world energy and the current oil situation in the Asia

    International Nuclear Information System (INIS)

    Okamoto, Hiroyuki

    1996-01-01

    Total world primary energy consumption excluding the FSU increased by 2.9% in 1995, which is somewhat above the 10 year average rate of 2.4%. This reflected strong economic growth in most parts of the world. The increase in demand confirmed the recovery of the link between the economic growth and consumption of primary energy, which broke down in the period of oil crises. Oil demand in the Asian Emerging Market Economies has continued to be very strong. Oil demand has doubled in a decade in this region and is now one sixth of world consumption. Malaysia was the fastest growing oil market in the world in 1995 at 15.5%. In volume terms, S. Korea grew the most in the world by 170,000 b/d, closely followed by China and India. Because of the fast growing oil demand, many energy economists expect a tight supply situation in the Asian oil market in the early 21st Century. However, recent technological developments would be able to supply crude oil appropriate for an increase in oil demand. (author)

  18. Uniform-sized silicone oil microemulsions: preparation, investigation of stability and deposition on hair surface.

    Science.gov (United States)

    Nazir, Habiba; Lv, Piping; Wang, Lianyan; Lian, Guoping; Zhu, Shiping; Ma, Guanghui

    2011-12-01

    Emulsions are commonly used in foods, pharmaceuticals and home-personal-care products. For emulsion based products, it is highly desirable to control the droplet size distribution to improve storage stability, appearance and in-use property. We report preparation of uniform-sized silicone oil microemulsions with different droplets diameters (1.4-40.0 μm) using SPG membrane emulsification technique. These microemulsions were then added into model shampoos and conditioners to investigate the effects of size, uniformity, and storage stability on silicone oil deposition on hair surface. We observed much improved storage stability of uniform-sized microemulsions when the droplets diameter was ≤22.7 μm. The uniform-sized microemulsion of 40.0 μm was less stable but still more stable than non-uniform sized microemulsions prepared by conventional homogenizer. The results clearly indicated that uniform-sized droplets enhanced the deposition of silicone oil on hair and deposition increased with decreasing droplet size. Hair switches washed with small uniform-sized droplets had lower values of coefficient of friction compared with those washed with larger uniform and non-uniform droplets. Moreover the addition of alginate thickener in the shampoos and conditioners further enhanced the deposition of silicone oil on hair. The good correlation between silicone oil droplets stability, deposition on hair and resultant friction of hair support that droplet size and uniformity are important factors for controlling the stability and deposition property of emulsion based products such as shampoo and conditioner. Copyright © 2011 Elsevier Inc. All rights reserved.

  19. Effect of Thymus vulgaris and Bunium persicum essential oils on the oxidative stability of virgin olive oil

    Directory of Open Access Journals (Sweden)

    M. Keramat

    2016-12-01

    Full Text Available Natural antioxidants are becoming a major focus because natural food ingredients are safer than synthetic types. The aim of this study was to investigate the protective effects of Thymus vulgaris and Bunium persicum essential oils (EO on the oxidation of virgin olive oil (VOO during accelerated storage. The antioxidant activities of EOs were compared with those of α-tocopherol and BHT. GC/MS analyses revealed that thymol (28.50%, p-cymene (27.14%, carvacrol (18.36%, and γ-terpinene (4.97% are the main components of T. vulgaris EO, while cuminaldehyde (32.81%, γ-terpinene (16.02% and p-cymene (14.07% are the main components of B. persicum EO. Both EOs provided protection for the VOO, inhibiting the formation of primary and secondary oxidation products although T. vulgaris EO showed greater protection against the oxidation process than B. persicum EO. The effect of T. vulgaris essential oil on the oxidation inhibition of VOO was similar to that of BHT. α-Tocopherol showed no measurable effect on improving the oxidative stability of VOO. This study suggests that T. vulgaris and B. persicum EOs can be used to improve the oxidative stability of VOO.

  20. Effect of Thymus vulgaris and Bunium persicum essential oils on the oxidative stability of virgin olive oil

    International Nuclear Information System (INIS)

    Keramat, M.; Golmakani, M.T.

    2016-01-01

    Natural antioxidants are becoming a major focus because natural food ingredients are safer than synthetic types. The aim of this study was to investigate the protective effects of Thymus vulgaris and Bunium persicum essential oils (EO) on the oxidation of virgin olive oil (VOO) during accelerated storage. The antioxidant activities of EOs were compared with those of α-tocopherol and BHT. GC/MS analyses revealed that thymol (28.50%), p-cymene (27.14%), carvacrol (18.36%), and γ-terpinene (4.97%) are the main components of T. vulgaris EO, while cuminaldehyde (32.81%), γ-terpinene (16.02%) and p-cymene (14.07%) are the main components of B. persicum EO. Both EOs provided protection for the VOO, inhibiting the formation of primary and secondary oxidation products although T. vulgaris EO showed greater protection against the oxidation process than B. persicum EO. The effect of T. vulgaris essential oil on the oxidation inhibition of VOO was similar to that of BHT. α-Tocopherol showed no measurable effect on improving the oxidative stability of VOO. This study suggests that T. vulgaris and B. persicum EOs can be used to improve the oxidative stability of VOO. [es

  1. Oxidative stability of structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    a commercial antioxidant blend Grindox 117 (propyl gallate/citric acid/ascorbyl palmitate) or gallic acid to the SL was investigated. The lipid type affected the oxidative stability: SL was less stable than SO and RL. The reduced stability was most likely caused by both the structure of the lipid...... and differences in production/purification, which caused lower tocopherol content and higher initial levels of primary and secondary oxidation products in SL compared with RL and SO. Grindox 117 and gallic acid did not exert a distinct antioxidative effect in the SL oil samples during storage......Traditional sunflower oil (SO), randomized lipid (RL) and specific structured lipid (SL), both produced from SO and tricaprylin/caprylic acid, respectively, were stored for up to 12 wk to compare their oxidative stabilities by chemical and sensory analyses. Furthermore, the effect of adding...

  2. Bio-Oil Separation and Stabilization by Supercritical Fluid Fractionation. 2014 Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Agblevor, Foster [Utah State Univ., Logan, UT (United States); Petkovic, Lucia [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bennion, Edward [Utah State Univ., Logan, UT (United States); Quinn, Jason [Utah State Univ., Logan, UT (United States); Moses, John [CF Technologies, Hyde Park, MA (United States); Newby, Deborah [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ginosar, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-03-01

    The objective of this project is to use supercritical fluids to separate and fractionate algal-based bio-oils into stable products that can be subsequently upgraded to produce drop-in renewable fuels. To accomplish this objective, algae was grown and thermochemically converted to bio-oils using hydrothermal liquefaction (HTL), pyrolysis, and catalytic pyrolysis. The bio-oils were separated into an extract and a raffinate using near-critical propane or carbon dioxide. The fractions were then subjected to thermal aging studies to determine if the extraction process had stabilized the products. It was found that the propane extract fraction was twice as stable as the parent catalytic pyrolysis bio-oils as measured by the change in viscosity after two weeks of accelerated aging at 80°C. Further, in-situ NMR aging studies found that the propane extract was chemically more stable than the parent bio-oil. Thus the milestone of stabilizing the product was met. A preliminary design of the extraction plant was prepared. The design was based on a depot scale plant processing 20,000,000 gallons per year of bio-oil. It was estimated that the capital costs for such a plant would be $8,700,000 with an operating cost of $3,500,000 per year. On a per gallon of product cost and a 10% annual rate of return, capital costs would represent $0.06 per gallon and operating costs would amount to $0.20 per gallon. Further, it was found that the energy required to run the process represented 6.2% of the energy available in the bio-oil, meeting the milestone of less than 20%. Life cycle analysis and greenhouse gas (GHG) emission analysis found that the energy for running the critical fluid separation process and the GHG emissions were minor compared to all the inputs to the overall well to pump system. For the well to pump system boundary, energetics in biofuel conversion are typically dominated by energy demands in the growth, dewater, and thermochemical process. Bio-oil stabilization by

  3. Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils. Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Huber, George W.; Upadhye, Aniruddha A.; Ford, David M.; Bhatia, Surita R.; Badger, Phillip C.

    2012-10-19

    This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8m were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments

  4. Formation and stability of oil-in-water nanoemulsions containing rice bran oil: in vitro and in vivo assessments

    Directory of Open Access Journals (Sweden)

    Rocha-Filho Pedro A

    2011-09-01

    Full Text Available Abstract Background Nanoemulsions have practical application in a multitude of commercial areas, such as the chemical, pharmaceutical and cosmetic industries. Cosmetic industries use rice bran oil in sunscreen formulations, anti ageing products and in treatments for skin diseases. The aim of this study was to create rice bran oil nanoemulsions using low energy emulsification methods and to evaluate their physical stability, irritation potential and moisturising activity on volunteers with normal and diseased skin types. Results The nanoemulsion developed by this phase diagram method was composed of 10% rice bran oil, 10% surfactants sorbitan oleate/PEG-30 castor oil, 0.05% antioxidant and 0.50% preservatives formulated in distilled water. The nanoemulsion was stable over the time course of this study. In vitro assays showed that this formulation has a low irritation potential, and when applied to human skin during in vivo studies, the nanoemulsion improved the skin's moisture and maintained normal skin pH values. Conclusion The results of irritation potential studies and in vivo assessments indicate that this nanoemulsion has potential to be a useful tool to treat skin diseases, such as atopic dermatitis and psoriasis.

  5. Bio-Oil Separation and Stabilization by Near-Critical Propane Fractionation

    Energy Technology Data Exchange (ETDEWEB)

    Ginosar, Daniel M.; Petkovic, Lucia M.; Agblevor, Foster A.

    2016-08-01

    Bio-oils produced by thermal process are promising sources of sustainable, low greenhouse gas alternative fuels. These thermal processes are also well suited to decentralized energy production due to low capital and operating costs. Algae feedstocks for bio-oil production are of particular interest, due in part to their high-energy growth yields. Further, algae can be grown in non-arable areas in fresh, brackish, salt water, or even waste water. Unfortunately, bio-oils produced by thermal processes present significant stability challenges. These oils have complex chemical compositions, are viscous, reactive, and thermally unstable. Further, the components within the oils are difficult to separate by fractional distillation. By far, the most effective separation and stabilization method has been solvent extraction. However, liquid phase extraction processes pose two main obstacles to commercialization; they require a significant amount of energy to remove and recover the solvent from the product, and they have a propensity for the solvent to become contaminated with minerals from the char and ash present in the original bio-oil. Separation and fractionation of thermally produced bio-oils using supercritical fluids (SCF) offers the advantages of liquid solvent extraction while drastically reducing energy demands and the predisposition to carry over solids into the extracted phase. SCFs are dense fluids with liquid-like solvent properties and gas-like transport properties. Further, SCF density and solvent strength can be tuned with minor adjustments in pressure, co-solvent addition, or gas anti-solvent addition. Catalytic pyrolysis oils were produced from Scenedesmus dimorphus algae using a fluid catalytic cracking catalyst. Bio-oil produced from catalytic fast pyrolysis (CFP) was separated using critical fluids. Propane extraction was performed at 65 °C at a fluid reduced pressure of 2.0 (85 bar) using an eight to one solvent to feed ratio by weight. Extraction of

  6. Modelling the effect of gas injections on the stability of asphaltene-containing crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, X.; Moorwood, T. [Infochem, Munich (Germany); Merino Garcia, D.; Pena Diez, J.L. [Repsol YPF, Madrid (Spain)

    2008-07-01

    In oil fields where asphaltene deposits occur, they present major remediation problems and can halt production due to flow blockage. Crude oils which precipitate asphaltenes generally contain both asphaltene molecules and lighter resin molecules. Resins are thought to solvate the asphaltene molecules, thus stabilizing the solution, while light gases have the opposite effect. In order to model asphaltene phase behaviour, it is important to understand the impact of adding gas to asphaltene-containing crudes. This study presented several experimental investigations of gas injection into asphaltene-containing crudes. The trends of asphaltene destabilization were discussed. The injection gases ranged from pure gases to a gas condensate. The data were modelled using a conventional equation of state together with an extra term that considered the association between asphaltene molecules and their solvation by resins. Since the model could simultaneously described the gas, oil and asphaltene phases, it was possible to calculate phase stability and phase equilibria. However, a different model had to be used to obtain the gas-oil equilibrium because the use of solubility parameters only allows the stability of the asphaltene phase to be calculated. The model correctly predicted that the gases will promote asphaltene precipitation. In its original form, the model tended to over-predict the trend. The optimal parameter values needed to represent all the available experimental data were determined. The extent to which the effect of gas injection on asphaltenes can be predicted was then discussed.

  7. Chemical quality and oxidative stability of extra virgin olive oils from San Juan province (Argentina).

    Science.gov (United States)

    Ceci, Liliana N; Mattar, Susana B; Carelli, Amalia A

    2017-10-01

    This study provides information about the chemical quality (quality indices, fatty acid profile, total polyphenols (PPs), tocopherols and pigments) and oxidative stability index (OSI) of virgin olive oils of Arbequina, Changlot Real and Coratina cultivars (San Juan province, Argentina). The influence of the cultivar and the effect of earlier harvest dates on the yields (OY), quality and OSI of the oils were also evaluated. All the oils were classified as extra virgin. The OY (L/100kg) averaged: Arbequina=13.2, Changlot Real=21.3, Coratina=18.3. The oleic acid (O) percentage, oleic to linoleic plus linolenic ratio [O/(L+Ln)], PPs and OSI were highly dependent on cultivar (Arbequinaoils (Arbequina: from 6.3-13.8h up to 10.6-19.0h, Changlot: from 6.0-12.1h up to 13.7-36.9h and Coratina: from 20.5-26.0h up to 24.6-42.4h) due to a more favorable O/(L+Ln) ratio and antioxidant composition. Regional producers are recommended to bring forward the harvest season to obtain oils with better chemical and nutritional quality, higher oxidative stability and a fatty acid profile according to the IOC trade standard. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Stabilization of Empty Fruit Bunch derived Bio-oil using Solvents

    Directory of Open Access Journals (Sweden)

    Chung Loong Yiin

    2016-03-01

    Full Text Available The intention of this research was to select the ideal condition for accelerated aging of bio-oil and the consequences of additive in stabilizing the bio-oil. The bio-oil was produced from the catalytic pyrolysis of empty fruit bunch. The optimum reaction conditions applied to obtain the utmost bio-oil yield were 5 wt% of H-Y catalyst at reaction temperature of 500 °C and nitrogen flow rate of 100 ml/min. A 10 wt% of solvents including acetone, ethanol, and ethyl acetate were used to study the bio-oil’s stability. All the test samples were subjected to accelerated aging at temperature of 80 oC for 7 days. The properties of samples used as the indicator of aging were viscosity and water content. The effectiveness of solvents increased in the following order: acetone, ethyl acetate, and 95 vol% ethanol. Based on the result of Gas chromatography-mass spectrometry (GC-MS, it could impede the chain of polymerization by converting the active units in the oligomer chain to inactive units. The solvent reacted to form low molecular weight products which resulted in lower viscosity and lessen the water content in bio-oil. Addition of 95 vol% ethanol also inhibited phase separation.

  9. Phenolic residues in spruce galactoglucomannans improve stabilization of oil-in-water emulsions.

    Science.gov (United States)

    Lehtonen, M; Merinen, M; Kilpeläinen, P O; Xu, C; Willför, S M; Mikkonen, K S

    2018-02-15

    Amphiphilic character of surfactants drives them at the interface of dispersed systems, such as emulsions. Hemicellulose-rich wood extracts contain assemblies (lignin-carbohydrate complexes, LCC) with natural amphiphilicity, which is expected to depend on their chemical composition resulting from the isolation method. Lignin-derived phenolic residues associated with hemicelluloses are hypothesized to contribute to emulsions' interfacial properties and stability. We investigated the role of phenolic residues in spruce hemicellulose extracts in the stabilization of oil-in-water emulsions by physical and chemical approach. Distribution and changes occurring in the phenolic residues at the droplet interface and in the continuous phase were studied during an accelerated storage test. Meanwhile, the physical stability and lipid oxidation in emulsions were monitored. Naturally associated lignin residues in GGM act as vehicles for anchoring these hemicelluloses into the oil droplet interface and further enable superior stabilization of emulsions. By adjusting the isolation method of GGM regarding their phenolic profile, their functionalities, especially interfacial behavior, can be altered. Retaining the native interactions of GGM and phenolic residues is suggested for efficient physical stabilization and extended protection against lipid oxidation. The results can be widely applied as guidelines in tailoring natural or synthetic amphiphilic compounds for interfacial stabilization. Copyright © 2017 Elsevier Inc. All rights reserved.

  10. A Systems Approach to Bio-Oil Stabilization - Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Robert C; Meyer, Terrence; Fox, Rodney; Submramaniam, Shankar; Shanks, Brent; Smith, Ryan G

    2011-12-23

    The objective of this project is to develop practical, cost effective methods for stabilizing biomass-derived fast pyrolysis oil for at least six months of storage under ambient conditions. The U.S. Department of Energy has targeted three strategies for stabilizing bio-oils: (1) reducing the oxygen content of the organic compounds comprising pyrolysis oil; (2) removal of carboxylic acid groups such that the total acid number (TAN) of the pyrolysis oil is dramatically reduced; and (3) reducing the charcoal content, which contains alkali metals known to catalyze reactions that increase the viscosity of bio-oil. Alkali and alkaline earth metals (AAEM), are known to catalyze decomposition reactions of biomass carbohydrates to produce light oxygenates that destabilize the resulting bio-oil. Methods envisioned to prevent the AAEM from reaction with the biomass carbohydrates include washing the AAEM out of the biomass with water or dilute acid or infusing an acid catalyst to passivate the AAEM. Infusion of acids into the feedstock to convert all of the AAEM to salts which are stable at pyrolysis temperatures proved to be a much more economically feasible process. Our results from pyrolyzing acid infused biomass showed increases in the yield of anhydrosugars by greater than 300% while greatly reducing the yield of light oxygenates that are known to destabilize bio-oil. Particulate matter can interfere with combustion or catalytic processing of either syngas or bio-oil. It also is thought to catalyze the polymerization of bio-oil, which increases the viscosity of bio-oil over time. High temperature bag houses, ceramic candle filters, and moving bed granular filters have been variously suggested for syngas cleaning at elevated temperatures. High temperature filtration of bio-oil vapors has also been suggested by the National Renewable Energy Laboratory although there remain technical challenges to this approach. The fast pyrolysis of biomass yields three main organic

  11. Effect of Grape Seed Proanthocyanidin-Gelatin Colloidal Complexes on Stability and in Vitro Digestion of Fish Oil Emulsions.

    Science.gov (United States)

    Su, Yu-Ru; Tsai, Yi-Chin; Hsu, Chun-Hua; Chao, An-Chong; Lin, Cheng-Wei; Tsai, Min-Lang; Mi, Fwu-Long

    2015-11-25

    The colloidal complexes composed of grape seed proanthocyanidin (GSP) and gelatin (GLT), as natural antioxidants to improve stability and inhibit lipid oxidation in menhaden fish oil emulsions, were evaluated. The interactions between GSP and GLT, and the chemical structures of GSP/GLT self-assembled colloidal complexes, were characterized by isothermal titration calorimetry (ITC), circular dichroism (CD), and Fourier transform infrared spectroscopic (FTIR) studies. Fish oil was emulsified with GLT to obtain an oil-in-water (o/w) emulsion. After formation of the emulsion, GLT was fixed by GSP to obtain the GSP/GLT colloidal complexes stabilized fish oil emulsion. Menhaden oil emulsified by GSP/GLT(0.4 wt %) colloidal complexes yielded an emulsion with smaller particles and higher emulsion stability as compared to its GLT emulsified counterpart. The GSP/GLT colloidal complexes inhibited the lipid oxidation in fish oil emulsions more effectively than free GLT because the emulsified fish oil was surrounded by the antioxidant GSP/GLT colloidal complexes. The digestion rate of the fish oil emulsified with the GSP/GLT colloidal complexes was reduced as compared to that emulsified with free GLT. The extent of free fatty acids released from the GSP/GLT complexes stabilized fish oil emulsions was 63.3% under simulated digestion condition, indicating that the fish oil emulsion was considerably hydrolyzed with lipase.

  12. Mechanisms of water-in-crude oil emulsion formation, stabilization and resolution by electrostatic means

    Energy Technology Data Exchange (ETDEWEB)

    Less, Simone

    2008-07-01

    Oil reserves are declining all over the world. Nevertheless the age of oil is probably bound to last for several years still, even though the growth of the world energy consumption will lead to a faster depletion than the one we are experiencing today. The possibility of avoiding new oil and energy crises will depend upon the oil industry's ability to find new fields and, above all, on mankind's ability to achieve an optimum exploitation of the currently available resources. The search of new fields is very expensive and the probability of finding new highly productive formations is small. The development of efficient technologies for oil extraction and processing to apply to existing fields is very important to extend their profitability. After being extracted, crude oil is a mixture of gases and liquids which need to be separated and purified, before being injected into their respective pipelines. In general, those operations are carried out on site. Since approximately 40% of the world production of oil comes from the sea (a percentage expected to increase in the next years), the need to economize on the space of the equipment is important. In addition, the growing attention to heavy and extra heavy oils raises a question on how they can be efficiently produced. In the light of this, the electrostatic separation (often denoted as electro coalescence) of crude oil emulsions is an important tool which, despite recent developments, still has a great potential. It is a cost-effective solution to guarantee the required export oil quality, and to increase the process efficiency on the platforms by allowing a quick discharge of the water in excess. This work was developed within the aims of the project 'Electro coalescence II - Criteria for an efficient process in real crude oil systems', the continuation of a former project in which the fundamental mechanisms active in the electro coalescence process were identified for model systems. The new

  13. Olive-oil nanocapsules stabilized by HSA: influence of processing variables on particle properties

    Energy Technology Data Exchange (ETDEWEB)

    Molina-Bolívar, J. A., E-mail: jmb@uma.es [University of Málaga, Department of Applied Physics II, Engineering School (Spain); Galisteo-González, F. [University of Granada, Department of Applied Physics (Spain)

    2015-10-15

    Liquid lipid nanocapsules (LLN) are considered to be promising drug carriers in the medical field. The size and the surface charge of these nanocarriers are of major importance, affecting their bioavailability and the in vivo behaviour after intravenous injection. This research provides a comprehensive study on the preparation of olive-oil nanocapsules stabilized with a human serum albumin shell (HSA). LLN were prepared by modified solvent-displacement method. Numerous experimental variables were examined in order to characterize their impact on LLN size, distribution, and electrophoretic mobility. Physicochemical parameters of LLN were controlled by adjusting the nanodroplet stabilizing shell of adsorbed protein molecules, which was affected by the oil:HSA ratio, pH, and ionic strength of aqueous medium. The stronger the repulsion between adsorbed HSA molecules, the smaller and more monodisperse the particles proved. Other process parameters, including the ethanol:acetone ratio, organic:aqueous phase ratio, speed of organic-phase injection, and stirring rate were examined to achieve optimum preparation conditions. LLN produced by our standardized formulation were in the range of 170–175 nm with low polydispersity index (<0.1). Long-term colloidal stability of samples was evaluated after 6 months of storage. Efficient incorporation of curcumin, a model for a water-insoluble drug, into olive-oil nanocapsules was achieved (90 %). Encapsulation of curcumin into LLN had a stabilizing effect with respect to drug photodecomposition compared to that of the free molecule in solution.

  14. Alteration of chemical composition and the oxidative stability of bleached pomace-olive oil on activated clays.

    Science.gov (United States)

    Jahouach, W; Essid, K; Trabelsi, M; Frikha, M H

    2006-09-20

    This work is a contribution to the study of the bleaching process, which is a very important stage in the refining process of vegetable oils and used to reduce or convert undesired constituents to harmless ones from fats and oils. The virgin olive oil, taken as reference, and the pomace-olive oil were bleached in the optimal conditions using Tunisian bleaching earths (South of Tunisia) which were activated in our laboratory and compared with commercial clays. It was shown that activated Tunisian clays are characterized by a very important adsorptive capacity, comparable to that of commercial clays. Also, the physicochemical stability of bleached oils was studied. The fatty acid composition (GC), the triacylglycerol composition (HPLC), and the oxidative stability (UV spectrometry) allowed us to conclude that oils, bleached with the Tunisian activated clays, do not undergo considerable physicochemical alterations and remain corresponding to the international standards for refined oils for human consumption.

  15. Physico-chemical change and heat stability of extra virgin olive oils flavoured by selected Tunisian aromatic plants.

    Science.gov (United States)

    Ayadi, M A; Grati-Kamoun, N; Attia, H

    2009-10-01

    Objectives of this work were studying physico-chemical change and heat stability of olive oils flavoured by selected Tunisian aromatic plants. Flavoured olive oils were prepared by maceration of fresh plant materials (rosemary, lavender, sage, menthe, basil, lemon and thyme) with olive oil at a 5% w/w level for 15 days. A sensorial evaluation was applied to select more appreciate flavoured olive oils by consumers. An oxidative procedure was applied to test the stability of selected flavoured olive oils: oils samples were kept in glass bottles and heated at 60 and 130 degrees C during 55 days and 6h, respectively. The resistance to oxidation of these selected flavoured oils was compared to a control samples by measuring PV, K232 and K270 values and change in chlorophyll, carotenes and polyphénols contents. Obtained results show that addition of aromatic plants causes a slight increase in free acidity and viscosity of aromatised olive oils. L*, b* and a* values show that addition of thyme cause a great change in olive oil colours. Heat stability results shows that from selected aromatic plants, rosemary was effectiveness against oxidation followed by thyme and lemon. However, olive oil flavoured with basil exhibit a similar behaviour versus thermal oxidation then the natural olive oil.

  16. Inflazione mondiale e politica nazionale di stabilità monetaria. (World inflation and domestic monetary stability

    Directory of Open Access Journals (Sweden)

    F.A. LUTZ

    2014-07-01

    Full Text Available Since the end of the Second World War the world economy has, apart from brief interludes of price stability, been in the grip of continuous inflation. No country seems to have managed to escape this world inflation entirely, although a few have made the very greatest efforts to do so. The present article considers why these efforts were in vain and if there really is no defence against “imported” world inflation. The author analyses the four types of policy for avoiding inflation - restrictive monetary and fiscal policy, export of capital, periodic changes in exchange parities and flexible exchange rates. The analysis suggests that the first two are least recommendable in the face of chronic balance of payments surpluses because they do not eradicate the surplus itself and can be sustained for only a relatively short period of time. The latter two do eliminate the external surplus, however, in the face of continuous world inflation, periodic  revaluation does so only temporarily while flexible rates represent a permanent solution. The author concludes that world inflation can be checked only if there is an international monetary order which keeps reserves so scarce that no country feels able to allow inflation to proceed.JEL: E31, E42, E52, E62

  17. Stability of transition to a world without nuclear weapons: Technical problems of verification

    International Nuclear Information System (INIS)

    Zhigalov, V.

    1998-01-01

    A serious psychological barrier to acceptance of the concept for achieving the nuclear-weapon-free world is fear of facing the prospect that one or more nations or extremist political groups might develop their own nuclear weapons. Actually this is a question of stability of the nuclear-weapon-free world. From this point of view the most effective system of verification is an absolute necessity. This system must ensure detection of so called undeclared nuclear activity at early stage. Scientists of Russian nuclear centers are working today on solving this problem. This paper is considered to be a comprehensive attempt to analyze the technical and organizational aspects of the problems of transition to a nuclear-weapons-free world, setting aside the difficulties of resolving purely political problems

  18. Effect of thermal aging on stability of transformer oil based temperature sensitive magnetic fluids

    Science.gov (United States)

    Kaur, Navjot; Chudasama, Bhupendra

    2018-04-01

    Synthesizing stable temperature sensitive magnetic fluids with tunable magnetic properties that can be used as coolant in transformers is of great interest, however not exploited commercially due to the lack of its stability at elevated temperatures in bulk quantities. The task is quite challenging as the performance parameters of magnetic fluids are strongly influenced by thermal aging. In this article, we report the effect of thermal aging on colloidal stability and magnetic properties of Mn1-xZnxFe2O4 magnetic fluids prepared in industrial grade transformer oil. As-synthesized magnetic fluids possess good dispersion stability and tunable magnetic properties. Effect of accelerated thermal aging on the dispersion stability and magnetic properties have been evaluated by photon correlation spectroscopy and vibration sample magnetometry, respectively. Magnetic fluids are stable under accelerated aging at elevated temperatures (from 50 °C to 125 °C), which is critical for their efficient performance in high power transformers.

  19. Impact of the Current Rise of World Oil Prices on the International Economy

    Science.gov (United States)

    1991-04-04

    Algeria and Egypt account for 80% of that production, the rest being contributed by Angola, Congo, - 11- Cameroun and Gabon. The big winners of the...the consuming nations of the South is not left to deteri- - 14 - orate. In the next 20 years 23, the world population will increase by about 2 billion...Oil : Choc. 18 Sept 1990, p.25 9 Alaerian Newspaper : EL MOUDJAHED La Hausse du Prix de Petrole - Source AFP - 4 Oct. 1990, p. 5 10, 12, 13 French

  20. USGS world petroleum assessment 2000; new estimates of undiscovered oil and natural gas, including reserve growth, outside the United States

    Science.gov (United States)

    ,

    2000-01-01

    Oil and natural gas account for approximately 63 percent of the world’s total energy consumption. The U.S. Geological Survey periodically estimates the amount of oil and gas remaining to be found in the world. Since 1981, each of the last four of these assessments has shown a slight increase in the combined volume of identified reserves and undiscovered resources. The latest assessment estimates the volume of technically recoverable conventional oil and gas that may be added to the world's reserves, exclusive of the United States, in the next 30 years. The USGS World Petroleum Assessment 2000 reports an increase in global petroleum resources, including a 20-percent increase in undiscovered oil and a 14-percent decrease in undiscovered natural gas compared to the previous assessment (table 1). These results have important implications for energy prices, policy, security, and the global resource balance.

  1. Review of the stability of biodiesel produced from less common vegetable oils of African origin

    Directory of Open Access Journals (Sweden)

    Thomas Kivevele

    2015-09-01

    Full Text Available The stability of biodiesel is dependent on storage conditions such as contact with ambient air and metals, exposure to sunlight and high temperature conditions which accelerate oxidation reactions. In addition, biodiesels are more susceptible to degradation when compared to fossil diesel because of the presence of unsaturated fatty acid chains which are prone to oxidation. The stability of biodiesel is categorised according to oxidation stability, storage stability and thermal stability. Oxidation instability can led to the formation of oxidation products such as aldehydes, alcohols, shorter chain carboxylic acids, insolubles, gums and sediments in the biodiesel. Thermal instability is concerned with the increased rate of oxidation at higher temperature, which in turn increases the weight of oil and fat due to the formation of insolubles. Storage stability is the ability of liquid fuel to resist change to its physical and chemical characteristics brought about by its interaction with its storage environment, such as contamination with metals. These fuel instabilities give rise to the formation of undesirable substances in biodiesel beyond acceptable limits as per global biodiesel standards such as those of the American Society for Testing and Materials (ASTM D6751 and European Standards (EN 14214. When such fuel is used in the engine, it impairs engine performance through fuel filter plugging, injector fouling, and deposit formation in the engine combustion chamber and various components of the fuel system. We review the stability of biodiesel made from less common vegetable oils of African origin and synthetic antioxidants used in improving the stability of produced biodiesels.

  2. Where in the World are Canadian Oil and Gas Companies? An Introduction to the Project

    Directory of Open Access Journals (Sweden)

    Niloo Hojjati

    2017-06-01

    Full Text Available In April 2013, The School of Public Policy formally launched the Extractive Resource Governance Program, a platform to harness Canadian and international research and technical expertise to assist resource-rich jurisdictions in establishing sustainable and mutually beneficial policies for governance of the extractive sector. The program delivers applied policy research, technical assistance and executive training programs to countries with emerging or established extractive resources, working in collaboration with governments, regulatory bodies, academia, civil society, and industry. Begun in 2011 as an internal research tool for the development of the Extractive Resource Governance Program, this project was conceived as a means to identify jurisdictions where Canadian companies had ongoing projects and activities around the world. This paper introduces the methodology used to answer the question: Where in the world are Canadian oil and gas companies? To answer this question, firm-level data from publicly traded Canadian companies were collected and analyzed culminating in the development of an online tool for public use. This paper accompanies an interactive website launched by The School’s Extractive Resource Governance Program and describes the data available online as well as in the annual reports released by The school. The website and annual reports allow interested users to geographically locate jurisdictions around the world where publicly traded Canadian oil and gas companies have activities, over time. The website is available at http://www.policyschool.ca/research-teaching/teachingtraining/extractive-resource-governance/ergp-map/. While Canada is a well-recognized oil and gas jurisdiction within its own borders, the extent of activity that Canadian companies undertake in the international arena is less well known. For instance, while Natural Resources Canada collects and publishes regular data on Canadian mining assets and

  3. The stability of water-in-crude and model oil emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, A.P.; Zaki, N.N.; Kilpatrick, P.K. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemical Engineering; Sjoblom, J. [Norwegian Univ. of Science and Technology, Trondheim (Norway). Dept. of Chemical Engineering, Ugelstad Laboratory

    2007-12-15

    Emulsions are among the most persistent problems faced by petroleum producers. Water is added at refineries to generate a large oil-water interfacial area to facilitate the extraction of salts from the crude oil. The produced emulsions do not readily resolve into neat crude and water phases, and some volume of the emulsion remains. This paper described the surface-active components in petroleum as well as methods of measuring emulsion stability. The stabilities of a variety of water-in-model oil and petroleum emulsions were measured using the critical electric field (CEF) technique. In this study, CEF was used to measure the stability of water-in-heptane-toluene-asphaltene emulsions. Results for emulsions with 60 and 30 per cent water were presented. The effect of interfacial film thickness was discussed and a kinetic model for interfacial film formation was presented. The importance of solvation of asphaltenes to emulsion stability was confirmed along with the importance of the state of asphaltene aggregation. It was shown that emulsion stability increased with the concentration of soluble asphaltenes near the point of precipitation. In order to calculate interfacial area and film thickness, optical microscopy was used to measure droplet size. Film thickness increased with asphaltene concentration up to the solubility limit. Increased concentration above that limit had little effect. CEF increased with interfacial film thickness up to a monolayer coverage of asphaltene aggregates, but film thickness had a much smaller effect above the monolayer. These results were used to develop correlations of the stability of water-in-crude oil emulsions. A strong correlation was found for CEF with the product of asphaltene concentration and the difference in hydrogen to carbon atomic ratios of the asphaltenes and petroleum solvent. The effects of asphaltene chemistry, solvency, and resin concentration on the adsorption and consolidation of emulsion stabilizing interfacial

  4. Characteristics and oxidative stability of bread fortified with encapsulated shrimp oil

    OpenAIRE

    Sirima Takeungwongtrakul; Soottawat Benjakul; Aran H-Kittikun

    2015-01-01

    Characteristics and oxidative stability of bread fortified with micro-encapsulated shrimp oil (MSO) were determined. The addition of MSO could improve the loaf volume of bread. Chewiness,gumminess and resilience of resulting bread were decreased. Bread crust and crumb showed higher redness and yellowness when MSO was incorporated (P<0.05). Microstructure study revealed that MSO remained intact with bread crumbs. The addition of MSO up to 3% had no adverse effect on bread quality and sensor...

  5. Determination of the oxidative stability by DSC of vegetable oils from the Amazonian area.

    Science.gov (United States)

    Pardauil, Juliana J R; Souza, Luiz K C; Molfetta, Fábio A; Zamian, José R; Rocha Filho, Geraldo N; da Costa, C E F

    2011-05-01

    Differential scanning calorimetry (DSC) and a Rancimat method apparatus were applied to evaluate the oxidative stability of buriti pulp oil (Mauritia flexuosa Mart), rubber seed oil (Hevea brasiliensis), and passion fruit oil (Passiflora edulis). The Rancimat measurements taken for the oxidative induction times were performed under isothermal conditions at 100°C and in an air atmosphere. The DSC technique involved the oxidation of oil samples in an oxygen-flow DSC cell. The DSC cell temperature was set at five different isothermal temperatures: 100, 110, 120, 130 and 140°C. During the oxidation reaction, an increase in heat was observed as a sharp exothermic curve. The value T(0) represents the oxidative induction time, which is determined from the downward extrapolated DSC oxidative curve verses the time axis. These curves indicate a good correlation between the DSC T(0) and oxidative stability index (OSI) values. The DSC method is useful because it consumes less time and less sample. Copyright © 2011 Elsevier Ltd. All rights reserved.

  6. Prosopis alba exudate gum as excipient for improving fish oil stability in alginate-chitosan beads.

    Science.gov (United States)

    Vasile, Franco Emanuel; Romero, Ana María; Judis, María Alicia; Mazzobre, María Florencia

    2016-01-01

    The aim of the present work was to employ an exudate gum obtained from a South American wild tree (Prosopis alba), as wall material component to enhance the oxidative stability of fish oil encapsulated in alginate-chitosan beads. For this purpose, beads were vacuum-dried and stored under controlled conditions. Oxidation products, fatty acid profiles and lipid health indices were measured during storage. Alginate-chitosan interactions and the effect of gum were manifested in the FT-IR spectra. The inclusion of the gum in the gelation media allowed decreasing the oxidative damage during storage in comparison to the free oil and alginate-chitosan beads. The gum also improved wall material properties, providing higher oil retention during the drying step and subsequent storage. Fatty acids quality and lipid health indices were widely preserved in beads containing the gum. Present results showed a positive influence of the gum on oil encapsulation and stability, being the main mechanism attributed to a physical barrier effect. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. The Stability of Lubricant Oil Acidity of Biogas Fuelled Engine due to Biogas Desulfurization

    Science.gov (United States)

    Gde Tirta Nindhia, Tjokorda; Wayan Surata, I.; Wardana, Ari

    2017-05-01

    This research is established for the purpose of the understanding the stability of the acidity of lubricant oil in biogas fuelled engine due to the absence of hydrogen sulfide (H2S). As was recognized that other than Methane (CH4), there are also other gas impurities in the biogas such as carbon dioxide (CO2), hydrogen sulfide (H2S), moisture (H2O) and ammonia (NH3). Due to H2S contents in the biogas fuel, the engine was found failure. This is caused by corrosion in the combustion chamber due to increase of lubricant acidity. To overcome this problem in practical, the lubricant is increased the pH to basic level with the hope will be decrease to normal value after several time use. Other method is by installing pH measurement sensor in the engine lubricant so that when lubricant is known turn to be acid, then lubricant replacement should be done. In this research, the effect of biogas desulfurization down to zero level to the acidity of lubricant oil in the four stroke engine was carried out with the hope that neutral lubrication oil to be available during running the engine. The result indicates that by eliminating H2S due desulfurization process, effect on stability and neutrality of pH lubricant. By this method the engine safety can be obtained without often replacement the lubricant oil.

  8. Rice bran stabilization and rice bran oil extraction using ohmic heating.

    Science.gov (United States)

    Lakkakula, N Rao; Lima, Marybeth; Walker, Terry

    2004-04-01

    Ohmic heating has been shown to increase the extraction yields of sucrose from sugar beets, apple juice from apples, beet dye from beet root, and soymilk from soybeans. Rice bran is a byproduct of the rice milling process that has economic potential by virtue of highly nutritious rice bran oil contained within the bran. In this study, ohmic heating was used to stabilize rice bran and to improve rice bran oil extraction yield as compared to microwave heating and a control (no heating). Results showed that ohmic heating is an effective method for rice bran stabilization with moisture addition. Free fatty acid concentration increased more slowly than the control for raw bran samples subjected to ohmic heating with no corresponding temperature rise, indicating that electricity has a non-thermal effect on lipase activity. Ohmic heating increased the total percent of lipids extracted from rice bran to a maximum of 92%, while 53% of total lipids were extracted from the control samples. Lowering the frequency of alternating current significantly increased the amount of oil extracted, probably due to electroporation. Ohmic heating was successfully applied to rice bran despite its high oil content. This could have important implications for the enhanced extraction of non-polar constituents.

  9. Effect of heating on oxidation stability and fatty acid composition of microwave roasted groundnut seed oil.

    Science.gov (United States)

    Abbas Ali, M; Anowarul Islam, M; Othman, Noor Hidayu; Noor, Ahmadilfitri Md

    2017-12-01

    The oxidative stability and fatty acid composition of groundnut seed oil (GSO) exposed to microwaves were evaluated during heating at 170 °C. During heating, the oxidative indices such as free fatty acid, peroxide value, p -anisidine value, TOTOX, thiobarbituric acid value, specific extinctions, and color value were increased. The increments were found to be higher in unroasted seed oils compared to roasted ones indicating lower release of lipid oxidation products in roasted GSO. After 9 h heating, the relative content of polyunsaturated fatty acid (PUFA) decreased to 89.53% and that of saturated fatty acid (SFA) increased to 117.46% in unroasted sample. The relative content of PUFA decreased to 92.05% and that of SFA increased to 105.76% in 7.5 min roasted sample after 9 h of heating. However, the roasting process slowed down the oxidative deterioration of PUFA. With increased heating times, an appreciable loss was more apparent in the triacylglycerol species OLL and OOL in unroasted samples compared to roasted ones. In FTIR, the peak intensities in unroasted samples were markedly changed in comparison with roasted samples during heating. The roasting of groundnut seed prior to the oil extraction reduced the oxidative degradation of oil samples; thereby increasing heat stability.

  10. Oxidative stability of pullulan nanofibers loaded with fish oil: effect of oil content and antioxidants addition

    DEFF Research Database (Denmark)

    García Moreno, Pedro Jesús; Damberg, C.; Stephansen, K.

    Electrospinning processing is a promising technique for the encapsulation of thermolabile bioactive compounds (e.g. fish oil) since it does not require the use of heat. Furthermore, the nano-microfibers (NMF) obtained present a reduced size, which makes them easier to disperse in food matrices...... compared to traditional encapsulates (e.g. microcapsules produced by spray-drying). Biopolymers such as proteins and polysaccharides are required for the production of food-grade NMF. In this sense, pullulan, which is a food-approved polysaccharide, is an interesting encapsulating material due to its high...

  11. Upgrading fuzzy logic by GA-PS to determine asphaltene stability in crude oil

    Directory of Open Access Journals (Sweden)

    Saeid Ahmadi

    2017-06-01

    Full Text Available Precipitation and deposition of asphaltene are undesirable phenomena that arise during petroleum production which give rise to a pronounced rate of increase in operational cost and adversely affect production rates as well. Hence, it is imperative to develop a mathematical model for the assessment of asphaltene stability in crude oil. In the present study, delta RI which constitutes the difference between refractive index of crude oil (RI and refractive index of crude oil at the onset of asphaltene precipitation (PRI is employed as the principal factor for determining the asphaltene stability of the region. Fuzzy logic is a potent tool capable of extracting the underlying dependency between SARA fractions (saturate, aromatic, resin, and asphaltene data and delta RI for the inexpensive and rapid diagnosis of asphaltene stability. In this study a novel strategy known as hybrid genetic algorithm-pattern search (GA-PS is suggested for the development of an optimal fuzzy logic model as a reliable alternative for the widely-applied subtractive clustering (SC method. While SC solely optimizes mean of input Gaussian membership functions (GMFs, GA-PS tool optimizes both mean and variance of input GMFs. Comparison between GA-PS and SC methods confirmed the capability of GA-PS for developing an optimal fuzzy logic model.

  12. Evaluation of Stability and In Vitro Security of Nanoemulsions Containing Eucalyptus globulus Oil

    Science.gov (United States)

    Quatrin, Priscilla Maciel; Sagrillo, Michele Rorato; Nascimento, Kátia

    2017-01-01

    Essential oil of Eucalyptus globulus presents several pharmacological properties. However, their therapeutic efficacy may be affected by limitations due to several conditions, rendering it difficult to obtain stable and effective pharmaceutical formulations. The use of nanotechnology is an alternative to improve their characteristics aiming to ensure their stability and effectiveness. Furthermore, studies about the possible toxic effects of nanostructures are necessary to evaluate safety when the formulation comes into contact with human cells. Hence, in this paper, we evaluate for the first time the stability and in vitro cytogenotoxicity of nanoemulsions containing Eucalyptus globulus in peripheral blood mononuclear cells. As a result, the stability study found that the best condition for storage up to 90 days was refrigeration (4°C); it was the condition that best preserved the nanometric features. The content of the major compounds of oil was maintained after nanoencapsulation and preserved over time. In tests to evaluate the safety of this formulation, we can conclude that, at a low concentration (approximately 0.1%), Eucalyptus globulus nanoemulsion did not cause toxicity in peripheral blood mononuclear cells and also showed a protective effect in cells against possible damage when compared to oil in free form. PMID:28691021

  13. Alkyl caffeates improve the antioxidant activity, antitumor property and oxidation stability of edible oil.

    Directory of Open Access Journals (Sweden)

    Jun Wang

    Full Text Available Caffeic acid (CA is distributed widely in nature and possesses strong antioxidant activity. However, CA has lower solubility in non-polar media, which limits its application in fat-soluble food. To increase the lipophilicity of natural antioxidant CA, a series of alkyl caffeates were synthesized and their antioxidant and antitumor activities were investigated. The antioxidant parameters, including the induction period, acid value and unsaturated fatty acid content, of the alkyl caffeates in edible oil were firstly investigated. The results indicated that alkyl caffeates had a lower DPPH IC₅₀ (14-23 µM compared to CA, dibutyl hydroxy toluene (BHT and Vitamin C (24-51 µM, and significantly inhibited four human cancer cells (SW620, SW480, SGC7901 and HepG2 with inhibition ratio of 71.4-78.0% by a MTT assay. With regard to the induction period and acid value assays, methyl and butyl caffeates had higher abilities than BHT to restrain the oxidation process and improve the stability of edible oil. The addition of ethyl caffeate to oil allowed maintenance of a higher unsaturated fatty acid methyl ester content (68.53% at high temperatures. Overall, the alkyl caffeats with short chain length (n<5 assessed better oxidative stability than those with long chain length. To date, this is the first report to the correlations among the antioxidant activity, anticancer activity and oxidative stability of alkyl caffeates.

  14. Olive-oil nanocapsules stabilized by HSA: influence of processing variables on particle properties

    Science.gov (United States)

    Molina-Bolívar, J. A.; Galisteo-González, F.

    2015-10-01

    Liquid lipid nanocapsules (LLN) are considered to be promising drug carriers in the medical field. The size and the surface charge of these nanocarriers are of major importance, affecting their bioavailability and the in vivo behaviour after intravenous injection. This research provides a comprehensive study on the preparation of olive-oil nanocapsules stabilized with a human serum albumin shell (HSA). LLN were prepared by modified solvent-displacement method. Numerous experimental variables were examined in order to characterize their impact on LLN size, distribution, and electrophoretic mobility. Physicochemical parameters of LLN were controlled by adjusting the nanodroplet stabilizing shell of adsorbed protein molecules, which was affected by the oil:HSA ratio, pH, and ionic strength of aqueous medium. The stronger the repulsion between adsorbed HSA molecules, the smaller and more monodisperse the particles proved. Other process parameters, including the ethanol:acetone ratio, organic:aqueous phase ratio, speed of organic-phase injection, and stirring rate were examined to achieve optimum preparation conditions. LLN produced by our standardized formulation were in the range of 170-175 nm with low polydispersity index (olive-oil nanocapsules was achieved (90 %). Encapsulation of curcumin into LLN had a stabilizing effect with respect to drug photodecomposition compared to that of the free molecule in solution.

  15. Evaluation of Stability and In Vitro Security of Nanoemulsions Containing Eucalyptus globulus Oil

    Directory of Open Access Journals (Sweden)

    Samantha Nunes de Godoi

    2017-01-01

    Full Text Available Essential oil of Eucalyptus globulus presents several pharmacological properties. However, their therapeutic efficacy may be affected by limitations due to several conditions, rendering it difficult to obtain stable and effective pharmaceutical formulations. The use of nanotechnology is an alternative to improve their characteristics aiming to ensure their stability and effectiveness. Furthermore, studies about the possible toxic effects of nanostructures are necessary to evaluate safety when the formulation comes into contact with human cells. Hence, in this paper, we evaluate for the first time the stability and in vitro cytogenotoxicity of nanoemulsions containing Eucalyptus globulus in peripheral blood mononuclear cells. As a result, the stability study found that the best condition for storage up to 90 days was refrigeration (4°C; it was the condition that best preserved the nanometric features. The content of the major compounds of oil was maintained after nanoencapsulation and preserved over time. In tests to evaluate the safety of this formulation, we can conclude that, at a low concentration (approximately 0.1%, Eucalyptus globulus nanoemulsion did not cause toxicity in peripheral blood mononuclear cells and also showed a protective effect in cells against possible damage when compared to oil in free form.

  16. Prevention of oil migration in palm mid fraction and palm olein using a stabilizer rich in behenic acid.

    Science.gov (United States)

    Peyronel, Fernanda; Campos, Rodrigo; Marangoni, Alejandro G

    2016-10-01

    Oil loss is a common problem in high oil volume fraction fat-structured foods, where trans fatty acids are absent and saturated fatty acids minimized. Usually a stabilizer "fat", rich in behenic and stearic acids is added to these products. This stabilizer significantly reduces oil migration and loss; however, the mechanism by which it exerts its effect is not known. Here we study the structure and oil loss characteristics of blends of palm mid fraction (PMF) and palm olein (PO) mixed with a commercial stabilizer of fully hydrogenated cottonseed and rapeseed oils added at 1.25, 3.5, and 7% (w/w) levels. The addition of as little as 1.25% stabilizer reduced oil migration from 13% to ~2% for the 80:20 PMF/PO blend and from 29% to ~3.5% for 20:80 PMF/PO blend after 14days of storage at 20°C, as judged from a filter paper assay. Polarized light microscopy results demonstrated that addition of stabilizer decreased fat crystal size and lead to the formation of a denser network with smaller pores. The rate of crystallization, determined by monitoring increases in solid fat content as function of time by pulsed NMR, increased upon addition of the stabilizer as indicated by decreases in the half-time of crystallization. Addition of stabilizer lead to an increase in the mechanical strength of the material, as indicated by increases in breaking force. Differential scanning calorimetry showed the formation of a new fraction, intermediate between the high melting fractions in both PMF and PO and the stabilizer upon incorporation of the stabilizer in the blends. We hypothesize that the stabilizer helps the formation of this new fraction which has a higher nucleation rate and thus forms a denser network of small crystals with an improved ability to bind and retain oil. Copyright © 2016. Published by Elsevier Ltd.

  17. Effect of carvacrol on the oxidative stability of palm oil during frying

    Directory of Open Access Journals (Sweden)

    İnanç, T.

    2014-12-01

    Full Text Available Fats and oils deteriorate physically and chemically at frying temperatures due to several reasons. The objective of this study was to assess the effect of carvacrol on the oxidative stability of palm oil during a repeated frying process. Potatoes were serially fried in carvacrol-added palm oil, BHT-added palm oil and a control oil (without any antioxidants. After each tenth frying cycle, several chemical analyses were carried out on collected samples to evaluate deterioration in the oils. The free fatty acid, para-anisidine, iodine, and total polar component values of the fresh oil were 0.080, 2.85, 57.1 and 7.5, respectively. These values changed to 0.165, 11.80, 46.7, 11.0, respectively for the control oil; 0.151, 11.28, 49.2 and 10.5 for BHT-added oil; 0.140, 7.19, 51.7, 10.0 for carvacrol-added oil after 40 frying cycles. The results revealed that the use of carvacrol could significantly improve the oxidative stability of palm oil when compared to the control samples. This effect was also comparable to BHT. Using carvacrol in frying oil slowed down the rate of the formation of conjugated dienes and trienes compared to the oil with BHT and the control. The frying process significantly changed the viscosity of the oil samples.Las grasas y aceites se deterioran física y químicamente a las temperaturas de fritura debido a diferentes razones. El objetivo de este estudio fue evaluar el efecto del carvacrol en la estabilidad oxidativa del aceite de palma durante el proceso de fritura repetida. Se sometió a fritura repetida patatas en el aceite de palma con carvacrol agregado, en aceite de palma con BHT agregado y en aceite control (sin antioxidante. Después de cada décimo ciclo de fritura, se realizaron diferentes análisis sobre las muestras recogidas para evaluar el deterioro de los aceites. Ácidos grasos libre, para-anisidina, índice de yodo y componentes polares totales del aceite fresco fueron: 0,080, 2,85, 57,1 y 7,5, respectivamente

  18. Encapsulation of fish oil in nanofibers by emulsion electrospinning: Physical characterization and oxidative stability

    DEFF Research Database (Denmark)

    García Moreno, Pedro Jesús; Boutrup Stephansen, Karen; van derKruijs, Jules

    2016-01-01

    The encapsulation of fish oil in poly(vinyl alcohol) (PVA) nanofibers by emulsion electrospinning was investigated. Independently of the emulsifier used, whey protein isolate (WPI) or fish protein hydrolysate (FPH), PVA concentration had a high influence on fiber morphology. Fibers without bead d...... presented a higher content of hydroperoxides and secondary oxidation products (e.g. 1-penten-3-ol, hexanal, octanal and nonanal) compared to emulsified and unprotected fish oil....... defects were only produced for solutions with 10.5% (w/w) PVA, which presented sufficient number of polymer chain entanglements. On the other hand, increasing oil load from 1.5 to 3% (w/w) resulted in fibers with larger diameters containing spindle-like enlargements interspersed. High omega-3...... encapsulation efficiency (92.4 ± 2.3%) was obtained for fibers produced from 10.5% (w/w) PVA-5% (w/w) emulsion blend stabilized with WPI, resulting in an oil load capacity of 11.3 ± 0.3%. Moreover, the encapsulated oil was randomly distributed as small droplets inside the fibers. However, the electrospun fibers...

  19. Whey protein/polysaccharide-stabilized oil powders for topical application-release and transdermal delivery of salicylic acid from oil powders compared to redispersed powders.

    Science.gov (United States)

    Kotzé, Magdalena; Otto, Anja; Jordaan, Anine; du Plessis, Jeanetta

    2015-08-01

    Oil-in-water (o/w) emulsions are commonly converted into solid-like powders in order to improve their physical and chemical stabilities. The aim of this study was to investigate whether whey protein/polysaccharide-stabilized o/w emulsions could be converted into stable oil powders by means of freeze-drying. Moreover, during this study, the effects of pH and polymer type on release and trans(dermal) delivery of salicylic acid, a model drug, from these oil powders were investigated and compared to those of the respective template emulsions and redispersed oil powders. Physical characterization of the various formulations was performed, such as droplet size analysis and oil leakage, and relationships drawn with regards to release and trans(dermal) delivery. The experimental outcomes revealed that the oil powders could be redispersed in water without changing the release characteristics of salicylic acid. pH and polymer type affected the release of salicylic acid from the oil powders, template emulsions, and redispersed powders similarly. Contrary, the transdermal delivery from the oil powders and from their respective redispersed oil powders was differently affected by pH and polymer type. It was hypothesized that the release had been influenced by the electrostatic interactions between salicylic acid and emulsifiers, whereas the transdermal performance could have been determined by the particle or aggregate sizes of the formulations.

  20. Characterisation of crude oil components, asphaltene aggregation and emulsion stability by means of near infrared spectroscopy and multivariate analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aske, Narve

    2002-06-01

    Effective separation of water-in-crude oil emulsions is a central challenge for the oil industry on the Norwegian Continental Shelf, especially with the future increase in subsea and even down-hole processing of well fluids. The mechanisms and properties governing emulsion stability are far from fully understood but the indigenous surface active crude oil components are believed to play a major role. In this work a thorough physico-chemical characterisation of a set of crude oils originating from a variety of production fields has been performed. Crude oil properties responsible for emulsion stability were identified by use of multivariate analysis techniques like partial least squares regression (PLS) and principal component analysis (PCA). Interfacial elasticity along with both asphaltene content and asphaltene aggregation state were found to be main contributors to emulsion stability. Information on a crude oils ability to form elastic crude oil-water interfaces was found to be especially crucial when discussing emulsion stability. However, measured values of interfacial elasticity were highly dependent on asphaltene aggregation state. Several experimental techniques was utilised and partly developed for the crude oil characterisation. A high-pressure liquid chromatography (HPLC) scheme was developed for SARA-fractionation of crude oils and an oscillating pendant drop tensiometer was used for characterisation of interfacial rheological properties. For emulsion stability a cell for determining the stability as a function of applied electric fields was used. In addition, near infrared spectroscopy (NIR) was used throughout the work both for chemical and physical characterisation of crude oils and model systems. High pressure NIR was used to study the aggregation of asphaltenes by pressure depletion. A new technique for detection of asphaltene aggregation onset pressures based on NIR combined with PCA was developed. It was also found that asphaltene aggregation is

  1. Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system.

    Science.gov (United States)

    Hădărugă, Daniel I; Hădărugă, Nicoleta G; Costescu, Corina I; David, Ioan; Gruia, Alexandra T

    2014-01-01

    Ocimum basilicum L. essential oil and its β-cyclodextrin (β-CD) complex have been investigated with respect to their stability against the degradative action of air/oxygen and temperature. This supramolecular system was obtained by a crystallization method in order to achieve the equilibrium of complexed-uncomplexed volatile compounds in an ethanol/water solution at 50 °C. Both the raw essential oil and its β-CD complex have been subjected to thermal and oxidative degradation conditions in order to evaluate the protective capacity of β-CD. The relative concentration of the O. basilicum L. essential oil compounds, as determined by GC-MS, varies accordingly with their sensitivity to the thermal and/or oxidative degradation conditions imposed. Furthermore, the relative concentration of the volatile O. basilicum L. compounds found in the β-CD complex is quite different in comparison with the raw material. An increase of the relative concentration of linalool oxide from 0.3% to 1.1%, in addition to many sesquiterpene oxides, has been observed. β-CD complexation of the O. basilicum essential oil modifies the relative concentration of the encapsulated volatile compounds. Thus, linalool was better encapsulated in β-CD, while methylchavicol (estragole) was encapsulated in β-CD at a concentration close to that of the raw essential oil. Higher relative concentrations from the degradation of the oxygenated compounds such as linalool oxide and aromadendren oxide were determined in the raw O. basilicum L. essential oil in comparison with the corresponding β-CD complex. For the first time, the protective capability of natural β-CD for labile basil essential oil compounds has been demonstrated.

  2. Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system

    Directory of Open Access Journals (Sweden)

    Daniel I. Hădărugă

    2014-11-01

    Full Text Available Ocimum basilicum L. essential oil and its β-cyclodextrin (β-CD complex have been investigated with respect to their stability against the degradative action of air/oxygen and temperature. This supramolecular system was obtained by a crystallization method in order to achieve the equilibrium of complexed–uncomplexed volatile compounds in an ethanol/water solution at 50 °C. Both the raw essential oil and its β-CD complex have been subjected to thermal and oxidative degradation conditions in order to evaluate the protective capacity of β-CD. The relative concentration of the O. basilicum L. essential oil compounds, as determined by GC–MS, varies accordingly with their sensitivity to the thermal and/or oxidative degradation conditions imposed. Furthermore, the relative concentration of the volatile O. basilicum L. compounds found in the β-CD complex is quite different in comparison with the raw material. An increase of the relative concentration of linalool oxide from 0.3% to 1.1%, in addition to many sesquiterpene oxides, has been observed. β-CD complexation of the O. basilicum essential oil modifies the relative concentration of the encapsulated volatile compounds. Thus, linalool was better encapsulated in β-CD, while methylchavicol (estragole was encapsulated in β-CD at a concentration close to that of the raw essential oil. Higher relative concentrations from the degradation of the oxygenated compounds such as linalool oxide and aromadendren oxide were determined in the raw O. basilicum L. essential oil in comparison with the corresponding β-CD complex. For the first time, the protective capability of natural β-CD for labile basil essential oil compounds has been demonstrated.

  3. Thermal and oxidative stability of the Ocimum basilicum L. essential oil/β-cyclodextrin supramolecular system

    Science.gov (United States)

    Hădărugă, Nicoleta G; Costescu, Corina I; David, Ioan; Gruia, Alexandra T

    2014-01-01

    Summary Ocimum basilicum L. essential oil and its β-cyclodextrin (β-CD) complex have been investigated with respect to their stability against the degradative action of air/oxygen and temperature. This supramolecular system was obtained by a crystallization method in order to achieve the equilibrium of complexed–uncomplexed volatile compounds in an ethanol/water solution at 50 °C. Both the raw essential oil and its β-CD complex have been subjected to thermal and oxidative degradation conditions in order to evaluate the protective capacity of β-CD. The relative concentration of the O. basilicum L. essential oil compounds, as determined by GC–MS, varies accordingly with their sensitivity to the thermal and/or oxidative degradation conditions imposed. Furthermore, the relative concentration of the volatile O. basilicum L. compounds found in the β-CD complex is quite different in comparison with the raw material. An increase of the relative concentration of linalool oxide from 0.3% to 1.1%, in addition to many sesquiterpene oxides, has been observed. β-CD complexation of the O. basilicum essential oil modifies the relative concentration of the encapsulated volatile compounds. Thus, linalool was better encapsulated in β-CD, while methylchavicol (estragole) was encapsulated in β-CD at a concentration close to that of the raw essential oil. Higher relative concentrations from the degradation of the oxygenated compounds such as linalool oxide and aromadendren oxide were determined in the raw O. basilicum L. essential oil in comparison with the corresponding β-CD complex. For the first time, the protective capability of natural β-CD for labile basil essential oil compounds has been demonstrated. PMID:25550747

  4. Water-in-oil Pickering emulsions stabilized by stearoylated microcrystalline cellulose.

    Science.gov (United States)

    Pang, Bo; Liu, Huan; Liu, Peiwen; Peng, Xinwen; Zhang, Kai

    2018-03-01

    Hydrophobic particles with static water contact angles larger than 90° are more like to stabilize W/O Pickering emulsions. In particular, high internal phase Pickering emulsions (HIPEs) are of great interest for diverse applications. However, W/O HIPEs have rarely been realized using sustainable biopolymers. Herein, we used stearoylated microcrystalline cellulose (SMCC) to stabilize W/O Pickering emulsions and especially, W/O HIPEs. Moreover, these W/O HIPEs can be further used as platforms for the preparation of porous materials, such as porous foams. Stearoylated microcrystalline cellulose (SMCC) was prepared by modifying MCC with stearoyl chloride under heterogeneous conditions. Using SMCC as emulsifiers, W/O medium and high internal phase Pickering emulsions (MIPEs and HIPEs) with various organic solvents as continuous phases were prepared using one-step and two-step methods, respectively. Polystyrene (PS) foams were prepared after polymerization of oil phase using HIPEs as templates and their oil/water separation capacity were studied. SMCC could efficiently stabilize W/O Pickering emulsions and HIPEs could only be prepared via the two-step method. The internal phase volume fraction of the SMCC-stabilized HIPEs reached as high as 89%. Diverse internal phase volume fractions led to distinct inner structures of foams with closed or open cells. These macroporous polystyrene (PS) foams demonstrated great potential for the effective absorption of organic solvents from underwater. Copyright © 2017 Elsevier Inc. All rights reserved.

  5. A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils

    Energy Technology Data Exchange (ETDEWEB)

    Diebold, J.P.

    1999-01-27

    Understanding the fundamental chemical and physical aging mechanisms is necessary to learn how to produce a bio-oil that is more stable during shipping and storage. This review provides a basis for this understanding and identifies possible future research paths to produce bio-oils with better storage stability.

  6. Effect of antioxidant tertiary butyl hydroquinone on the thermal and oxidative stability of sesame oil (sesamum indicum) by ultrasonic studies.

    Science.gov (United States)

    Prasad, N; Siddaramaiah, Basavarajaiah; Banu, Mujeeda

    2015-04-01

    The aim of the current investigation is to evaluate the efficiency of tertiary butyl hydroquinone (TBHQ) as an antioxidant in sesame oil (sesamum indicum) by density, viscosity and ultrasonic velocity. The effects of varying amounts of TBHQ on the oxidation stability of sesame oil have been investigated. The antioxidant incorporated sesame oil system and control edible oil were subjected to heating at 180 ± 5 °C continuously for a period of 4 h per day for consecutive 4 days. The parameters used to assess the thermal degradation and oxidation properties of the oils include ultrasonic velocity, viscosity, density and peroxide value. The fatty acid compositions of the oils were measured by gas chromatography. Adiabatic compressibility, intermolecular free length, relaxation time and acoustic impedance have been calculated from experimental data. Viscosity, density and ultrasonic velocity change in control oil is from 3.6553 × 10(-2) to 11.1729 × 10(-2) Nsm(-2), 912.59 to 940.31 kg/m(3) and 1,421 to 1,452 m/s respectively and in sesame oil with 200 ppm TBHQ is from 3.6793 × 10(-2) to 6.4842 × 10(-2) Nsm(-2), 913.78 to 922.45 kg/m(3) and 1,421 to 1,431 m/s respectively for 16 h of heat treated oil. The ultrasonic results obtained have shown reduction in thermal degradation and improvement in oxidation stability of antioxidant loaded oil in comparison to base oil. Hence, it can be recommended that sesame oil with 200 ppm TBHQ can be used for frying without adverse effect on physical properties. The ultrasonic velocity can be used for assessment of stability of frying oil.

  7. Effect of antioxidant butylated hydroxyl anisole on the thermal or oxidative stability of sunflower oil (Helianthus Annuus) by ultrasonic.

    Science.gov (United States)

    Murari, Satish Kumar; Shwetha, M V

    2016-01-01

    The aim of the current investigation was to evaluate the efficiency of butylated hydroxyl anisole (BHA) as an antioxidant in sunflower oil (Helianthus Annuus). The oxidation stability of sunflower oil have been investigated by the effects of varying amounts of BHA. The antioxidant incorporated sunflower oil system and control edible oil were subjected to heating at 180 ± 5 °C continuously for a period of 4 h per day for consecutive 4 days. The parameters used to assess the thermal degradation and oxidation properties of the oils include ultrasonic velocity, viscosity, density and peroxide value. The fatty acid compositions of the oils were measured by gas chromatography. Adiabatic compressibility, intermolecular free length, relaxation time and acoustic impedance have been calculated from experimental data. Viscosity, density and ultrasonic velocity change in control oil is from 3.72 × 10(-2) to 13.2 × 10(-2) Nsm - 2, 918 to 994 kg/m3 and 1412 to 1484 m/s respectively and in sunflower oil with 200 ppm BHA is from 3.88 × 10(-2) to 7.52 × 10(-2) Nsm - 2, 926 to 962 kg/m3 and 1418 to 1463 m/s respectively for 16 h of heat treated oil. The ultrasonic results obtained have shown reduction in thermal degradation and improvement in oxidation stability of antioxidant loaded oil in comparison to base oil. Hence, it can be recommended that sunflower oil with 200 ppm BHA can be used for frying without adverse effect on physical properties. The ultrasonic velocity can be used for assessment of stability of frying oil.

  8. [Stability of whole cell biocatalyst for biodiesel production from renewable oils].

    Science.gov (United States)

    Sun, Ting; Du, Wei; Liu, Dehua; Li, Wei; Zeng, Jing; Dai, Lingmei

    2009-09-01

    Lipase-mediated biodiesel production becomes increasingly important because of mild reaction conditions, pollution free during the process and easy product separation. Compared with traditional immobilized lipase, whole cell biocatalyst is promising for biodiesel production because it is easy to prepare and has higher enzyme activity recovery. Rhizopus oryzae IFO4697 can be used as the catalyst for biodiesel production. To further study the stability of the whole cell biocatalyst is extremely important for its further application on large scale. This paper focuses on the stability study of Rhizopus oryzae IFO4697 when used for the methanolysis of renewable oils for biodiesel production. The results showed that water content was important for achieving high catalytic activity and good stability of the biocatalyst. The optimum water content was found to be 5%-15%. Both particle size and desiccation methods showed no obvious effect on the stability of the biocatalyst. With GA cross-linking pretreatment, the stability of the biocatalyst could be improved significantly. When Rhizopus oryzae IFO4697 repeatedly used for next batch reaction, direct vacuum filtration was found to be a good way for the maintenance of good stability of the biocatalyst. Under the optimum reaction conditions, the methyl ester yield could keep over 80% during 20 repeated reaction batches.

  9. The potential applications in heavy oil EOR with the nanoparticle and surfactant stabilized solvent-based emulsion

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, F. [Texas A and M Univ., College Station, TX (United States)

    2010-07-01

    The main challenges in developing the heavy oil reservoirs in the Alaska North Slope (ANS) include technical challenges regarding thermal recovery; sand control and disposal; high asphaltene content; and low in-situ permeability. A chemical enhanced oil recovery method may be possible for these reservoirs. Solvent based emulsion flooding provides mobility control; oil viscosity reduction; and in-situ emulsification of heavy oil. This study evaluated the potential application of nano-particle-stabilized solvent based emulsion injection to enhance heavy oil recovery in the ANS. The optimized micro-emulsion composition was determined using laboratory tests such as phase behaviour scanning, rheology studies and interfacial tension measurements. The optimized nano-emulsions were used in core flooding experiments to verify the recovery efficiency. The study revealed that the potential use of this kind of emulsion flooding is a promising enhanced oil recovery process for some heavy oil reservoirs in Alaska, Canada and Venezuela. 4 refs., 2 tabs., 10 figs.

  10. Stabilization

    Directory of Open Access Journals (Sweden)

    Muhammad H. Al-Malack

    2016-07-01

    Full Text Available Fuel oil flyash (FFA produced in power and water desalination plants firing crude oils in the Kingdom of Saudi Arabia is being disposed in landfills, which increases the burden on the environment, therefore, FFA utilization must be encouraged. In the current research, the effect of adding FFA on the engineering properties of two indigenous soils, namely sand and marl, was investigated. FFA was added at concentrations of 5%, 10% and 15% to both soils with and without the addition of Portland cement. Mixtures of the stabilized soils were thoroughly evaluated using compaction, California Bearing Ratio (CBR, unconfined compressive strength (USC and durability tests. Results of these tests indicated that stabilized sand mixtures could not attain the ACI strength requirements. However, marl was found to satisfy the ACI strength requirement when only 5% of FFA was added together with 5% of cement. When the FFA was increased to 10% and 15%, the mixture’s strength was found to decrease to values below the ACI requirements. Results of the Toxicity Characteristics Leaching Procedure (TCLP, which was performed on samples that passed the ACI requirements, indicated that FFA must be cautiously used in soil stabilization.

  11. Classification and analysis of factors that affect stability of oil and gas enterprise staff

    Directory of Open Access Journals (Sweden)

    Zelinska Haluna Olexiivna

    2016-12-01

    Full Text Available The relevance of human resources as a strategic goal of sustainable development of oil and gas companies is determined. It is shown that the stability of staff, as the main component of the social components of sustainable enterprise development, research and evaluation needs in terms of an integrated system of factors influence the behavior of staff. Addressing issues related to the management personnel can be based classification study the factors affecting its stability in the formation of high quality human resources strategy. In particular noted that the needs of each employee should become an integral part of the concept of work and life balance. Analysis of the results of the study showed that in areas of oil and gas industry has a number of factors that negatively affect its operation and development, which are caused not only technical, technological and natural factors, but also due to neglect behavioral characteristics personnel. It is found that without understanding of the behavioral characteristics of staff and its values can`t implement a quality model of human resource management and provide optimal scenarios of oil companies in general.

  12. Development of cetyl dimethicone based water-in-oil emulsion containing botanicals: Physical characteristics and stability.

    Science.gov (United States)

    Waqas, Muhammad Khurram; Akhtar, Naveed; Shah, Pervaiz Akhtar; Danish, Muhammad Zeeshan; Shah, Arshad Ali; Braga, Valdir de Andrade; Khan, Barkat Ali

    2016-01-01

    The aim of current research was to develop a water-in-oil emulsion containing grape seed extract for application in cosmeceuticals. Finally grinded dried grape seeds powder was extracted with hydro alcoholic mixture. Emulsions consisting of different concentrations of cetyl dimethicone (Abile EM90), the nonionic emulsifier, liquid paraffin as oily phase and water as aqueous phase were developed. Color, odor, pH, viscosity, liquefaction, phase separation, centrifugation and thermal stability of the formulated emulsions were observed at various storage temperatures i.e. 8±0.5°C, 25±0.5°C, 40±0.5°C and 40°C±0.5°C with 70% RH. The stable formulation consist of 16% mineral oil, 4% of ABIL EM 90(®), 4% grape seeds extract, 1% rose oil and 75% distilled water. All the results derived from this study showed good stability over the three months study period which indicates w/o emulsion can be used as carrier of 4% grape seeds extract to enhance desired effects when applied topically.

  13. Effects of syringe material and silicone oil lubrication on the stability of pharmaceutical proteins.

    Science.gov (United States)

    Krayukhina, Elena; Tsumoto, Kouhei; Uchiyama, Susumu; Fukui, Kiichi

    2015-02-01

    Currently, polymer-based prefillable syringes are being promoted to the pharmaceutical market because they provide an increased break resistance relative to traditionally used glass syringes. Despite this significant advantage, the possibility that barrel material can affect the oligomeric state of the protein drug exists. The present study was designed to compare the effect of different syringe materials and silicone oil lubrication on the protein aggregation. The stability of a recombinant fusion protein, abatacept (Orencia), and a fully human recombinant immunoglobulin G1, adalimumab (Humira), was assessed in silicone oil-free (SOF) and silicone oil-lubricated 1-mL glass syringes and polymer-based syringes in accelerated stress study. Samples were subjected to agitation stress, and soluble aggregate levels were evaluated by size-exclusion chromatography and verified with analytical ultracentrifugation. In accordance with current regulatory expectations, the amounts of subvisible particles resulting from agitation stress were estimated using resonant mass measurement and dynamic flow-imaging analyses. The amount of aggregated protein and particle counts were similar between unlubricated polymer-based and glass syringes. The most significant protein loss was observed for lubricated glass syringes. These results suggest that newly developed SOF polymer-based syringes are capable of providing biopharmaceuticals with enhanced physical stability upon shipping and handling. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

  14. Physical Properties and Stabilization of Microcapsules Containing Thyme Oil by Complex Coacervation.

    Science.gov (United States)

    Shen, Lili; Chen, Jiaping; Bai, Youju; Ma, Zhican; Huang, Jing; Feng, Wu

    2016-09-01

    The aim of this study was to produce and characterize microcapsules of thyme oil and finally appraise the extent of stability improvement. The optimum process conditions obtained from orthogonal tests were as follows: ratio of core material to wall 0.5, temperature 40 °C, pH value 3.0 and time 20 min, where the practical encapsulation efficiency was 85.17±1.35%. The microcapsules belong to the nanometric range as the average particle diameter was 531.17±77.12 nm. The results from structural analysis indicated that no significant chemical bond occurred during the encapsulation process and the microcapsules remained stable when the encapsulation was conducted at a temperature below 53.1 °C. Especially, the retention rate of thyme oil in microcapsules remained 39.21% at 4 °C, 36.99% at 25 °C and 33.80% at 40 °C after 30 d of storage. Moreover, protection from light exposure presented a positive impact on the storage stability of thyme oil microcapsules. © 2016 Institute of Food Technologists®

  15. Stabilization of some vegetable oils by sugarcane leaf extract at ambient temperature

    International Nuclear Information System (INIS)

    Nadeem, M.; Azeem, M.W.

    2016-01-01

    The present was aimed to assess the antioxidant of ethanolic sugarcane leaf extract for the stabilisation of sunflower, (SFO), soybean and (SBO) canola oils (CO) at ambient temperature. SFO, SBO and CO were added with 600 ppm sugracane leaf extract, fielled in transparent PET bottles, stored at ambient temperature for 180 days, sampled at 0, 60, 120 and 180 days for the assessment of oxidative stability. Total phenolic content in sugracane leaf extract (SLE) was 724.3 (mg GAE/100g). 2,2, Diphenyl-2 picrylhydrazyl free radical scavenging activity of slewas 76% as compared to 88% butylated hydroxyl toluene. C18:1 in fresh, 6 months stored controls and SLE supplemented SFO were 46.12%, 42.59% and 47.15%, 40.29, 43.13%, respectively. C18:2 and 18.3 in fresh and 180 days stored control and SLE suplemented SBO were 51.19%, 45.61%, 48.97% and 6.19%, 3.37% and 5.67%, respectively. Similar trend was also recorded and canola oil. Induction period of supplemented vegetable oil was higher than the un-supplemented sample. Sensory characteristics of SLE supplemented vegetable oil were not different from the control. Sugarcane leaf extract can be used for the long term preservation of SFO, SBO and CO at ambient temperature. (author)

  16. Improving the stability of bioethanol / gas oil emulsions by a new additive

    Energy Technology Data Exchange (ETDEWEB)

    Hancsok, J.; Marsi, G.; Nagy, G. (Univ. of Pannonia, Veszprem (Hungary). Dept. of Hydrocarbon and Coal Processing), Email: hancsokj@almos.uni-pannon.hu

    2009-07-01

    The limit of application of bioethanol / gas oil emulsions is derived from their stability problems, which is effected by numerous factors (hydrocarbon composition of base gas oil, temperature, water content of bioethanol, presence of co-solvent and quality and quantity of applied additive). Therefore the aim of our research work was to prepare bioethanol / gas oil emulsions which are stable at low temperature (-15 deg C) and in presence of water (3.0-5.0 v / v %) by the application of originally structured additives, and co-solvents (fatty acid alkyl esters and different carbon number bioalcohols). We found that the application of 5 v / v % fatty-acid-methyl-ester as co-solvent bioethanol / gas oil emulsion containing 6 v / v % bioethanol could be produced which was stable at -15 deg C. By the application of originally structured additive (polyisobutene-succinic-acid based additives contained fatty-acid-methyl-ester as molecule-component) the emulsion was stable even when water content of the applied bioethanol was 5 v / v %. (orig.)

  17. Effect of date (Phoenix dactylifera L.) seed extract on stability of olive oil.

    Science.gov (United States)

    Özcan, Mehmet Musa; Al Juhaimi, Fahad

    2015-02-01

    In this study, the antioxidant effect of date (Phoenix dactylifera L., Arecaceae) seed extracts at different concentrations (0.5 %, 1.0 % and 1.5 %) on the oxidative stability of olive oil at 60 °C was determined. Butylated hydroxyanisole (BHA) was used as positive control in the experiment. All extracts exhibited antioxidant activity compared to BHA up to 21 days. When antioxidant effect of extract concentrations were compared with BHA, the effect of 0.5 % extract concentration was more remarkable for olive oil up to 21 days. After 14 days of assay, all of seed extracts was effective at 60 °C in comparison with control. On the other hand, an important increase was observed in both the peroxide and free fatty acidity values during the experiment period. It concluded that date seed extract could be used as a oxidative inhibitor agent in oil and oil products.

  18. Ten-year retrospective on OPEC and the world oil market

    Energy Technology Data Exchange (ETDEWEB)

    Gately, D.

    1983-01-01

    Following a review of the main events in the world oil market since 1973 and some of the major explanations of what happened and why, the author discusses projections for the next two decades and considers some implications of various theories of how decisions are made by OPEC. This includes the dominant theoretical approach that uses Hotelling's wealth-maximization model, the simulation approach of target-capacity-utilization pricing by OPEC, and the problem of modeling price behavior during disruptions. The final section discusses some of the important unresolved issues, such as supply and demand uncertainties, the best behavior for OPEC, and the dispute over OPEC's significance to events of the past decade. 31 references.

  19. World Energy Balance Outlook and OPEC Production Capacity: Implications for Global Oil Security

    Directory of Open Access Journals (Sweden)

    Azadeh M. Rouhani

    2012-07-01

    Full Text Available The imbalance between energy resource availability, demand, and production capacity, coupled with inherent economic and environmental uncertainties make strategic energy resources planning, management, and decision-making a challenging process. In this paper, a descriptive approach has been taken to synthesize the world’s energy portfolio and the global energy balance outlook in order to provide insights into the role of Organization of Petroleum Exporting Countries (OPEC in maintaining “stability” and “balance” of the world’s energy market. This synthesis illustrates that in the absence of stringent policies, i.e., if historical trends of the global energy production and consumption hold into the future, it is unlikely that non-conventional liquid fuels and renewable energy sources will play a dominant role in meeting global energy demand by 2030. This should be a source of major global concern as the world may be unprepared for an ultimate shift to other energy sources when the imminent peak oil production is reached. OPEC’s potential to impact the supply and price of oil could enable this organization to act as a facilitator or a barrier for energy transition policies, and to play a key role in the global energy security through cooperative or non-cooperative strategies. It is argued that, as the global energy portfolio becomes more balanced in the long run, OPEC may change its typical high oil price strategies to drive the market prices to lower equilibria, making alternative energy sources less competitive. Alternatively, OPEC can contribute to a cooperative portfolio management approach to help mitigate the gradually emerging energy crisis and global warming, facilitating a less turbulent energy transition path while there is time.

  20. Simulating the effect of hydrate dissociation on wellhead stability during oil and gas development in deepwater

    Science.gov (United States)

    Li, Qingchao; Cheng, Yuanfang; Zhang, Huaiwen; Yan, Chuanliang; Liu, Yuwen

    2018-02-01

    It is well known that methane hydrate has been identified as an alternative resource due to its massive reserves and clean property. However, hydrate dissociation during oil and gas development (OGD) process in deep water can affect the stability of subsea equipment and formation. Currently, there is a serious lack of studies over quantitative assessment on the effects of hydrate dissociation on wellhead stability. In order to solve this problem, ABAQUS finite element software was used to develop a model and to evaluate the behavior of wellhead caused by hydrate dissociation. The factors that affect the wellhead stability include dissociation range, depth of hydrate formation and mechanical properties of dissociated hydrate region. Based on these, series of simulations were carried out to determine the wellhead displacement. The results revealed that, continuous dissociation of hydrate in homogeneous and isotropic formations can causes the non-linear increment in vertical displacement of wellhead. The displacement of wellhead showed good agreement with the settlement of overlying formations under the same conditions. In addition, the shallower and thicker hydrate formation can aggravate the influence of hydrate dissociation on the wellhead stability. Further, it was observed that with the declining elastic modulus and Poisson's ratio, the wellhead displacement increases. Hence, these findings not only confirm the effect of hydrate dissociation on the wellhead stability, but also lend support to the actions, such as cooling the drilling fluid, which can reduce the hydrate dissociation range and further make deepwater operations safer and more efficient.

  1. Coriander seed oil methyl esters as biodiesel fuel: Unique fatty acid composition and excellent oxidative stability

    Energy Technology Data Exchange (ETDEWEB)

    Moser, Bryan R.; Vaughn, Steven F. [United States Department of Agriculture, Agricultural Research Service, National Center for Agricultural Utilization Research, 1815 N. University St, Peoria, IL 61604 (United States)

    2010-04-15

    Coriander (Coriandrum sativum L.) seed oil methyl esters were prepared and evaluated as an alternative biodiesel fuel and contained an unusual fatty acid hitherto unreported as the principle component in biodiesel fuels: petroselinic (6Z-octadecenoic; 68.5 wt%) acid. Most of the remaining fatty acid profile consisted of common 18 carbon constituents such as linoleic (9Z,12Z-octadeca-dienoic; 13.0 wt%), oleic (9Z-octadecenoic; 7.6 wt%) and stearic (octadecanoic; 3.1 wt%) acids. A standard transesterification procedure with methanol and sodium methoxide catalyst was used to provide C. sativum oil methyl esters (CSME). Acid-catalyzed pretreatment was necessary beforehand to reduce the acid value of the oil from 2.66 to 0.47 mg g{sup -1}. The derived cetane number, kinematic viscosity, and oxidative stability (Rancimat method) of CSME was 53.3, 4.21 mm{sup 2} s{sup -1} (40 C), and 14.6 h (110 C). The cold filter plugging and pour points were -15 C and -19 C, respectively. Other properties such as acid value, free and total glycerol content, iodine value, as well as sulfur and phosphorous contents were acceptable according to the biodiesel standards ASTM D6751 and EN 14214. Also reported are lubricity, heat of combustion, and Gardner color, along with a comparison of CSME to soybean oil methyl esters (SME). CSME exhibited higher oxidative stability, superior low temperature properties, and lower iodine value than SME. In summary, CSME has excellent fuel properties as a result of its unique fatty acid composition. (author)

  2. Coriander seed oil methyl esters as biodiesel fuel: Unique fatty acid composition and excellent oxidative stability

    International Nuclear Information System (INIS)

    Moser, Bryan R.; Vaughn, Steven F.

    2010-01-01

    Coriander (Coriandrum sativum L.) seed oil methyl esters were prepared and evaluated as an alternative biodiesel fuel and contained an unusual fatty acid hitherto unreported as the principle component in biodiesel fuels: petroselinic (6Z-octadecenoic; 68.5 wt%) acid. Most of the remaining fatty acid profile consisted of common 18 carbon constituents such as linoleic (9Z,12Z-octadeca-dienoic; 13.0 wt%), oleic (9Z-octadecenoic; 7.6 wt%) and stearic (octadecanoic; 3.1 wt%) acids. A standard transesterification procedure with methanol and sodium methoxide catalyst was used to provide C. sativum oil methyl esters (CSME). Acid-catalyzed pretreatment was necessary beforehand to reduce the acid value of the oil from 2.66 to 0.47 mg g -1 . The derived cetane number, kinematic viscosity, and oxidative stability (Rancimat method) of CSME was 53.3, 4.21 mm 2 s -1 (40 o C), and 14.6 h (110 o C). The cold filter plugging and pour points were -15 o C and -19 o C, respectively. Other properties such as acid value, free and total glycerol content, iodine value, as well as sulfur and phosphorous contents were acceptable according to the biodiesel standards ASTM D6751 and EN 14214. Also reported are lubricity, heat of combustion, and Gardner color, along with a comparison of CSME to soybean oil methyl esters (SME). CSME exhibited higher oxidative stability, superior low temperature properties, and lower iodine value than SME. In summary, CSME has excellent fuel properties as a result of its unique fatty acid composition.

  3. Oxidative stability of fish and algae oils containing long-chain polyunsaturated fatty acids in bulk and in oil-in-water emulsions

    DEFF Research Database (Denmark)

    Frankel, E.N.; Satue-Gracia, T.; Meyer, Anne Boye Strunge

    2002-01-01

    The oxidative stability of long-chain polyunsaturated fatty acid (PUFA) and docosahexaenoic acid (DHA)-containing fish and algae oils varies widely according to their fatty acid composition, the physical and colloidal states of the lipids, the contents of tocopherols and other antioxidants, and t...... high iron:EDTA ratios. Therefore, to be effective as a metal chelator, EDTA must be added at molar concentrations higher than that of iron to inhibit oxidation of foods containing long-chain PUFA from either fish or algae and fortified with iron.......The oxidative stability of long-chain polyunsaturated fatty acid (PUFA) and docosahexaenoic acid (DHA)-containing fish and algae oils varies widely according to their fatty acid composition, the physical and colloidal states of the lipids, the contents of tocopherols and other antioxidants......-chain PUFA-containing fish oils and DHA-containing algal oils. The relatively high oxidative stability of an algal oil containing 42% DHA was completely lost after chromatographic purification to remove tocopherols and other antioxidants. Therefore, this evidence does not support the claim that DHA-rich oils...

  4. Investigation of stability, consistency, and oil oxidation of emulsion filled gel prepared by inulin and rice bran oil using ultrasonic radiation.

    Science.gov (United States)

    Nourbehesht, Newsha; Shekarchizadeh, Hajar; Soltanizadeh, Nafiseh

    2018-04-01

    Inulin, rice bran oil and rosemary essential oil were used to produce high quality emulsion filled gel (EFG) using ultrasonic radiation. Response surface methodology was used to investigate the effects of oil content, inulin content and power of ultrasound on the stability and consistency of prepared EFG. The process conditions were optimized by conducting experiments at five different levels. Second order polynomial response surface equations were developed indicating the effect of variables on EFG stability and consistency. The oil content of 18%; inulin content of 44.6%; and power of ultrasound of 256 W were found to be the optimum conditions to achieve the best EFG stability and consistency. Microstructure and rheological properties of prepared EFG were investigated. Oil oxidation as a result of using ultrasonic radiation was also investigated. The increase of oxidation products and the decrease of total phenolic compounds as well as radical scavenging activity of antioxidant compounds showed the damaging effect of ultrasound on the oil quality of EFG. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Effect of heat-treatment with raw cotton seed oil on decay resistance and dimensional stability of Beech (Fagus orientalis

    Directory of Open Access Journals (Sweden)

    مریم قربانی

    2015-05-01

    Full Text Available This research was conducted to determine the effect of heat-treatment with raw cotton seed oil on decay resistance and dimensional stability of beech according to EN113 and ASTM-D1037 standards respectively. The heat treatment with raw cotton seed oil was carried out in the cylinder at the temperatures of 130 and 170oC for 30 and 60 minutes. Oil uptake, density, volumetric swelling, water absorption and weight loss exposed to decay were measured. Oil uptake at 30 and 60 min were determined 10.5 and 13.3 Kg/cm3 respectively. Oil-heat treated samples at 30min and 130°C indicated the maximum density with 87.7% increase. According to results, oil-heat treatment improved water repellency and dimensional stability. Water absorption in 130°C and 60 minutes decreased 76% in comparison with control. Decay resistance of oil soaked samples for 60minutes was 80.2% more than control samples. Oil-heat treatment compared with oil treatment improved decay resistance, this effect was significant at 30 min. The temperature rise of oil–heat treatment at 30 minutes improved decay resistance, but the improvement under same level of temperature with increase time was not significant.

  6. Characterizations of oil-in-water emulsion stabilized by different hydrophobic maize starches.

    Science.gov (United States)

    Ye, Fan; Miao, Ming; Jiang, Bo; Hamaker, Bruce R; Jin, Zhengyu; Zhang, Tao

    2017-06-15

    The molecular structure, rheological properties, microstructure and physical stability of oil-in-water emulsions using octenyl succinic-sugary maize soluble starch (OS-SMSS) were investigated and compared with two commercial OS-starches (HI-CAP 100 and Purity Gum 2000). The degree of substitution (DS), weight-average molecular weight (Mw) and z-root mean square radius of gyration (Rz) of OS-SMSS, HI-CAP 100 and Purity Gum 2000 were 0.0050, 223.4×10 5 g/mol and 38.8nm, 0.0037, 9.6×10 5 g/mol and 29.3nm, and 0.0031, 31.3×10 5 g/mol and 39.6nm, respectively. FT-IR spectra showed two new absorption bands at 1725 and 1570cm -1 from OS ester linkage in all tested samples. The emulsion with OS-SMSS exhibited a pseudoplastic behavior over the whole shear rate range, whereas other two emulsions showed a similar Newtonian fluid. All hydrophobic starch stabilized emulsions satisfied the Herschel-Bulkley model. All emulsions displayed storage modulus (G') was higher than loss modulus (G″), and only G' and G″ of OS-SMSS stabilized emulsion were independent of frequency. The volume-average droplet size (d 43 ) value of emulsions stabilized by three modified starches was 27.9, 15.2 and 24.4μm, respectively. During 4 weeks storage, lower change in d 43 of emulsion with OS-SMSS was observed. The above results with schematic models of emulsions suggested that an emulsion with high stability could be prepared using 3% of OS-SMSS due to the formation of high density and thick nanoparticle layer at the interface, indicating OS-SMSS was a Pickering emulsion stabilizer for good long-term stability. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Emulsification technique affects oxidative stability of fish oil-in-water emulsion

    DEFF Research Database (Denmark)

    Horn, Anna Frisenfeldt; Nielsen, Nina Skall; Jensen, Louise Helene Søgaard

    .g. homogenization pressure can affect how proteins locate themselves at the interface of an emulsion. The hypothesis is therefore that emulsions produced with different emulsification equipments differ in their oxidative stability due to differences in the behaviour of the proteins at the interface. The aim...... of this study was therefore to compare lipid oxidation in 10% fish oil-in-water emulsions prepared by two different kinds of high pressure homogenizers i.e. a microfluidizer and a two valve high pressure homogenizer. Emulsions were made with equal droplet sizes, and with either 1% sodium caseinate or 1% whey...

  8. Emulsification technique affects oxidative stability of fish oil-in-water emulsions

    DEFF Research Database (Denmark)

    Horn, Anna Frisenfeldt; Nielsen, Nina Skall; Jensen, Louise Helene Søgaard

    .g. homogenization pressure can affect how proteins locate themselves at the interface of an emulsion. The hypothesis is therefore that emulsions produced with different emulsification equipments differ in their oxidative stability due to differences in the behaviour of the proteins at the interface. The aim...... of this study was to compare lipid oxidation in 10% fish oil-in-water emulsions prepared by two different kinds of high pressure homogenizers i.e. a microfluidizer and a two valve high pressure homogenizer. Emulsions were made with equal droplet sizes, and with either 1% sodium caseinate or 1% whey protein...

  9. Oxidative stability of mayonnaise containing structured lipids produced from sunflower oil and caprylic acid

    DEFF Research Database (Denmark)

    Jacobsen, Charlotte; Xu, Xuebing; Nielsen, Nina Skall

    2003-01-01

    . Furthermore, the potential antioxidative effect of adding lactoferrin, propyl gallate or EDTA to the mayonnaise with SL was also investigated. Mayonnaise based on SL oxidized faster than mayonnaise based on RL or SO. The reduced oxidative stability in the SL mayonnaise could not be ascribed to a single factor...... gallate and lactoferrin did not exert any antioxidative effect in the SL mayonnaise......, but was most likely influenced by the structure of the lipid, the lower tocopherol content and the higher initial levels of lipid hydroperoxides and secondary volatile oxidation compounds in the SL itself compared with the RL and traditional sunflower oil employed. EDTA was a strong antioxidant, while propyl...

  10. Oxidative Stability and Sensory Attributes of Fermented Milk Product Fortified with Fish Oil and Marine Phospholipids

    DEFF Research Database (Denmark)

    Lu, Henna Fung Sieng; Thomsen, Birgitte Raagaard; Hyldig, Grethe

    2013-01-01

    Marine phospholipids (PL) are potential ingredients for food fortification due to its numerous advantages. The main objective of this study was to investigate whether a fermented milk product fortified with a mixture of marine PL and fish oil had better oxidative stability than a fermented milk...... of primary, secondary volatile oxidation products and tocopherol content upon 32 days storage at 2 °C and 28 days storage at 5 °C, respectively. Analyses of particle size distribution, viscosity and microbial growth were also performed. In addition, sensory attributes such as sour, fishy and rancid flavor...

  11. Fatty acid composition, oxidative stability, antioxidant and antiproliferative properties of selected cold-pressed grape seed oils and flours.

    Science.gov (United States)

    Lutterodt, Herman; Slavin, Margaret; Whent, Monica; Turner, Ellen; Yu, Liangli Lucy

    2011-09-15

    Cold-pressed chardonnay, muscadine, ruby red, and concord grape seed oils and their defatted flours were studied for their fatty acid composition, oxidative stability and antioxidant and antiproliferative activities. The phenolic profiles of the seed flours were also measured. The most abundant fatty acid in the oils was linoleic acid, ranging from 66.0g/100g of total fatty acids in ruby red seed oil to 75.3g/100g of total fatty acids in concord seed oil. The oils were also high in oleic acid and low in saturated fat. Ruby red grape seed oil recorded the highest oxidative stability index of 40h under the accelerated conditions. Total phenolic content (TPC) was up to 100 times lower in the oils than in the flours. Lutein, zeaxanthin, cryptoxanthin, β-carotene, and α-tocopherol levels were also measured. DPPH radical-scavenging capacity ranged from 0.07 to 2.22mmol trolox equivalents (TE)/g of oil and 11.8 to 15.0mmol TE/g of flour. Oxidative stability of menhaden fish oil containing extracts of the seed flours was extended by up to 137%. HPLC analysis was conducted to determine the levels of free soluble, soluble conjugated and insoluble bound phenolics in the seed flours. The phenolic compounds analyzed included catechin, epicatechin, epicatechin gallate, quercetin, gallic acid, and procyanidins B1 and B2. Antiproliferative activity was tested against HT-29 colon cancer cells. All of the seed flours and muscadine seed oil registered significant (Pseed oils and flours as dietary sources of natural antioxidants and antiproliferative agents for optimal health. Copyright © 2011 Elsevier Ltd. All rights reserved.

  12. Influence of spike lavender (Lavandula latifolia Med.) essential oil in the quality, stability and composition of soybean oil during microwave heating.

    Science.gov (United States)

    Rodrigues, Nuno; Malheiro, Ricardo; Casal, Susana; Asensio-S-Manzanera, M Carmen; Bento, Albino; Pereira, José Alberto

    2012-08-01

    Lipids oxidation is one of the main factors leading to quality losses in foods. Its prevention or delay could be obtained by the addition of antioxidants. In this sense the present work intend to monitor the protective effects of Lavandula latifolia essential oil during soybean oil microwave heating. To achieve the proposed goal quality parameters (free acidity, peroxide value, specific coefficients of extinction and ΔK), fatty acids profile, tocopherols and tocotrienols composition, antioxidant activity and oxidative stability were evaluated in soybean oil with and without spike lavender essential oils (EO) submitted to different microwave heating exposure times (1, 3, 5, 10 and 15 min; 1000 Watt) with a standard domestic microwave equipment. Microwave heating induced severe quality and composition losses, mainly above 3 min of microwave heating, regardless the sample tested. However, spike lavender EO addition counteracts the oxidation comparatively to control oils, by presenting enhanced values in quality parameters. A higher protection in unsaturated fatty acids loss was also observed as well as a higher antioxidant activity and oxidative stability. The microwave heating effects were clearly different in the samples with essential oils addition, allowing discrimination from plain soybean oils by a principal component analysis, being also capable to discriminate the different heating times tested within each sample. Copyright © 2012 Elsevier Ltd. All rights reserved.

  13. Effect of methanol extracts of rosemary and olive vegetable water on the stability of olive oil and sunflower oil

    Directory of Open Access Journals (Sweden)

    Gamel, T. H.

    1999-10-01

    Full Text Available Effect of methanol extracts of rosemary and olive vegetable water on the stability of olive oil and sunflower oil. Methanol phenolic extracts of dry rosemary leaves and olive vegetable water filtrate, in combination with BHA, were added to olive oil (blend of refined and virgin olive oil, 3 to 1 and to sunflower oil and their antioxidant effects under accelerated conditions were evaluated. Accelerated conditions included the oven test (at 63 °C and the conductivity method (Rancimat at 120 °C. Frying process at 180 °C was also applied. The methanol phenolic extracts and the BHA were added to each oil at the following concentrations: 200 ppm rosemary extract; 200 ppm olive vegetable water extract; 100 ppm rosemary extract + 100 ppm BHA; 100 ppm vegetable water extract + 100 ppm BHA and 200 ppm BHA. In general, antioxidant effect of phenolic additives of rosemary and of BHA was in the following order: 200 ppm rosemary extract > 100 ppm rosemary extract + 100 ppm BHA > and 200 ppm BHA. The addition of 200 ppm vegetable water extract and 100 ppm vegetable water extract + 100 ppm BHA exhibited similar antioxidant effect to that of 200 ppm BHA.

    Extractos metanólicos de fenoles de hojas secas de romero y filtrados de agua de vegetación de la aceituna, en combinación con BHA, se añadieron al aceite de oliva (mezcla de aceite de oliva refinado y virgen, 3 a 1 y al aceite de girasol, evaluándose sus efectos antioxidantes usando condiciones aceleradas. Estas condiciones incluyeron el test del horno de oxidación (a 63 °C y el método de conductividad (Rancimat a 120 °C. También se aplicó al proceso de fritura a 180 °C. Los extractos metanólicos de fenoles y el BHA se añadieron a cada aceite en las siguientes concentraciones: 200 ppm de extracto de romero, 200 ppm de extracto de agua de vegetación de la aceituna, 100 ppm de extracto de romero + 100 ppm de BHA, 100 ppm de extracto de agua de vegetación + 100 ppm de BHA y 200 ppm de BHA

  14. Effect of castor oil emulsion eyedrops on tear film composition and stability.

    Science.gov (United States)

    Maïssa, Cécile; Guillon, Michel; Simmons, Peter; Vehige, Joseph

    2010-04-01

    An emulsion eyedrop containing castor oil has been shown to modify the tear film lipid layer and increase tear film stability. The primary objectives of this investigation were to measure the prevalence of castor oil in the tear fluid over time and quantify the effects on the lipid layer. A secondary objective was to quantify the initial effects on ocular symptomatology. The investigation was an open label pilot study on 5 normal and 10 dry eye subjects. A single eyedrop (Castor oil emulsion, Allergan) was instilled in each eye; the tear film appearance and composition were monitored for 4h via in vivo visualisation using the Tearscope and post in vivo tear samples analysis by HPLC. Combined results for both normal and dry eye subjects showed that castor oil was detected up to 4h after a single eyedrop instillation and associated with an increase in the level of tear film lipid. The relative amount of various lipid families was also changed. An increase in tear lipid layer thickness was significant up to one hour post-instillation for the symptomatic sub-population. The changes in tear film characteristics were associated with significantly lower symptoms up to four hours post-instillation for the symptomatic sub-population. This pilot investigation showed that castor oil eyedrops achieved a residence time of at least four hours post-instillation, producing a more stable tear film and an associated significant decrease in ocular symptoms over the entire follow-up period for the symptomatic subjects. 2009 British Contact Lens Association. Published by Elsevier Ltd. All rights reserved.

  15. Where in the World are Canadian Oil and Gas Companies? 2011

    Directory of Open Access Journals (Sweden)

    Niloo Hojjati

    2017-06-01

    Full Text Available Canada is well recognized for its prominence as an oil and gas jurisdiction in regard to its resources within its own borders. However, there is little available analysis and information regarding the presence of Canadian companies in the international arena. Begun in 2011 as an internal research tool for the development of the Extractive Resource Governance Program, this project seeks to answer the vital question: Where in the world are Canadian oil and gas companies? To answer this question, firm-level data from publicly traded Canadian companies are collected and analyzed, culminating in the development of an online tool for public use. This map allows interested users to geographically locate jurisdictions around the world where publicly traded Canadian oil and gas (hereafter O&G companies have activities, over time. The map is available at http://www.policyschool.ca/ research-teaching/teaching-training/extractive-resource-governance/ergp-map/. This project, hereafter referred to as the WIW project, provides a measure that quantifies Canadian oil and gas activity around the world and identifies key jurisdictions that are of particular interest to Canadian O&G companies. The data collected holds value for various stakeholders such as governments, regulatory bodies, academia, civil society, and industry across the extractive resource spectrum. Prior to further discussion regarding the 2011 annual data results, it is valuable to provide a brief overview of the methodology used in the collection of data for this research project. The WIW project examines the global activities of Canadian O&G companies in 218 countries spanning seven international regions of analysis.1 The aim of the WIW project is to examine the international presence of Canadian companies in foreign countries. As such, it is important to note that this project does not provide information related to the activities of Canadian companies within Canada’s border, such as the

  16. Reference data on world oil markets; Reperes sur les marches petroliers mondiaux

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    This paper makes a status of the 2004 activity of worldwide oil markets: oil demand, oil supplies (OPEC and non-OPEC countries, unused production capacities), formation of oil prices (role of stockpiles, role of terminal markets, impact of dollar rate), economic data: OPEC objectives, market vision, volatility of prices, supply and demand. (J.S.)

  17. Study of Water-Oil Emulsion Breaking by Stabilized Solution Consisting of Anionic Surface Acting Agent - Soda Ash - Polymer (ASP)

    Science.gov (United States)

    Kulichkov, S. V.; Avtomonov, E. G.; Andreeva, L. V.; Solomennik, S. F.; Nikitina, A. V.

    2018-01-01

    The paper provides a laboratory research of breaking natural water-oil emulsions: - by non-stabilized ASP; by stabilized ASP; by mixture of stabilized and non-stabilized ASP in different proportions and production of refinery water of the required quality with the use of IronGuard 2495 as flocculant. Oil-in-water emulsion is stable. Classic methods are not suitable for residual water treatment: sediment gravity flow; filtration; centrifuge test. Microemulsion formed after ASP application has low boundary tension and high pH. It contributes to transfer of oil phase into a water one, forming oil-in-water emulsion. Alkaline condition has adverse effect on demulsifying ability of agents, flocculation and boundary tension. For breaking of water-oil emulsion at EBU before the interchanger water or water-oil emulsion from the wells that were not APS-treated in ratio of 1:9 shall be delivered. Residual water after EBU must be prepared in water tanks by dilution in great volume.

  18. Oxidative stability of cnicken thigh meat after treatment of abies alba essential oil

    Directory of Open Access Journals (Sweden)

    Adriana Pavelková

    2015-12-01

    Full Text Available In the present work, the effect of the Abies alba essential oil in two different concentrations on oxidative stability of chicken thigh muscles during chilled storage was investigated. In the experiment were chickens of hybrid combination Cobb 500 after 42 days of the fattening period slaughtered.  All the broiler chickens were fed with the same feed mixtures and were kept under the same conditions. The feed mixtures were produced without any antibiotic preparations and coccidiostatics. After slaughtering was dissection obtained fresh chicken thigh with skin from left half-carcass which were divided into five groups (n = 5: C - control air-packaged group; A1 - vacuum-packaged experimental group; A2 - vacuum-packaged experimental group with ethylenediaminetetraacetic acid (EDTA solution 1.50% w/w; A3 - vacuum-packaged experimental group with Abies alba oil 0.10% v/w and A4 - vacuum-packaged experimental group with Abies alba oil 0.20% v/w. The Abies alba essential oil was applicate on ground chicken things and immediately after dipping, each sample was packaged using a vacuum packaging machine and storage in refrigerate at 4 ±0.5 °C. Thiobarbituric acid (TBA value expressed in number of malondialdehyde was measured in the process of first storage day of 1st, 4th, 8th, 12th and 16th day after slaughtering and expressed on the amount of malondialdehyde (MDA in 1 kg sample. The treatments of chicken things with Abies alba essential oil show statistically significant differences between all testing groups and control group, where higher average value of MDA measured in thigh muscle of broiler chickens was in samples of control group (0.4380 mg.kg-1 compared to experimental groups A1 (0.124 mg.kg-1, A2 (0.086 mg.kg-1, A3 (0.082 mg.kg-1 and A4 (0.077 mg.kg-1 after 16-day of chilled storage. Experiment results show that the treatment of chicken thigh with Abies alba essential oil positively influenced on the reduction of oxidative processes in thigh

  19. Oxidative stability of chicken thigh meat after treatment of fennel and savory essential oils

    Directory of Open Access Journals (Sweden)

    Adriana Pavelková

    2016-05-01

    Full Text Available In the present work, the effect of the fennel and savory essential oils on oxidative stability of chicken thigh muscles during chilled storage was investigated. In the experiment were used chickens of hybrid combination Cobb 500 after 42 days of the fattening period. The obtained fresh chicken thigh with skin from left half-carcass were divided into five groups (n = 5: C - control air-packaged group; A1 - vacuum-packaged experimental group; A2 - vacuum-packaged experimental group with EDTA solution 1.50% w/w; A3 - vacuum-packaged experimental group with fennel (Foeniculum vulgare essential oil at concentrations 0.2% v/w and A4 - vacuum-packaged experimental group with savory (Satureja hortensis essential oil at concentration 0.2% v/w. The essential oils were applicate on surface chicken thighs. The chicken thighs were packaged using a vacuum packaging machine and stored in refrigerate at                 4 ±0.5 °C. The value of thiobarbituric acid (TBA expressed as amount of malondialdehyde (MDA in 1 kg sample was measured during storage in 1st, 4th, 8th, 12th and 16th day. The treatments of chicken thighs with fennel and savory essential oils show statistically significant differences between all testing groups and control group, where higher average value of MDA measured in thigh muscle of broiler chickens was in samples of control group                 (0.359 mg.kg-1 compared to experimental groups A1 (0.129 mg.kg-1, A2 (0.091 mg.kg-1, A3 (0.084 mg.kg-1 and A4 (0.089 mg.kg-1 after 16-day of chilled storage. Experiment results show that the treatment of chicken thigh with fennel and savory essential oils had positive influence on the reduction of oxidative processes in thigh muscles during chilling storage and use of essential oil is one of the options increase shelf life of fresh chicken meat.

  20. The effect of the volatility of the oil price in the actual world economy (1998 until 02/2008); A influencia da volatilidade dos precos do petroleo na atual economia mundial

    Energy Technology Data Exchange (ETDEWEB)

    Plaster, Vinicius Almeida [Universidade Vila-Velha, ES (Brazil). Relacoes Internacionais

    2008-07-01

    In the elapse of the X X century the world experienced different cycles of prices in the world's oil production. From the principle of the century until the years 70's there were times of relative stability, in the 70's nevertheless a little variation in the price took the world's economy into a huge recession. Since then the consume of oil, that were increasing, has suffered a shock and started to decrease. The stability just will return in the 90's , but it will not last for a long time, and not with the same level of prices of the time before crisis, but as sad before it do not last long, as we can see nowadays the quotation break new records every day , but one factor distinguish this new shock of prices, of the shock of the 70's. Distinct of that time, the global economy in the beginning of the X XI century live a period of economical stability that was not seen for a long time in history, with controlled inflation and decrease of the interests rates, therefore this article concludes that happened a maturation of global economy, and that due the previous shocks happened a diversification in relation of the previous excessive dependence of oil. (author)

  1. Chemical composition and oxidative stability of jussara (Euterpe edulis M.) oil extracted by cold and hot mechanical pressing

    International Nuclear Information System (INIS)

    Da Cunha, A.L.A.; Freitas, S.P.; Godoy, R.L.O.; Cabral, L.M.C.; Tonon, R.V.

    2017-01-01

    The aim of this work was to evaluate the effect of mechanical pressing on jussara oil yield, oxidative stability and carotenoid profile with or without heat application. Firstly, jussara pulp was centrifuged for juice extraction, and the resulting cake was dried until reaching 10% moisture content. Then, oil extraction was performed in an expeller press at 25 ºC (cold pressing) and at 50 ºC (hot pressing). The process performance was evaluated by the oil yield, and the crude jussara oil was characterized for fatty acid composition, acid value, carotenoid profile and oxidative stability. Jussara oil contained 74% unsaturated fatty acids, mainly oleic and linoleic acids (48% and 24%, respectively). The oil yield was almost twice as high for the hot process as compared to the cold one. Additionally, hot pressing resulted in 25% higher total carotenoid content as compared to cold pressing, with β-carotene as the most abundant one. Hot and cold pressing showed no difference in oil oxidative stability and fatty acid composition. [es

  2. Climate change, future Arctic Sea ice, and the competitiveness of European Arctic offshore oil and gas production on world markets.

    Science.gov (United States)

    Petrick, Sebastian; Riemann-Campe, Kathrin; Hoog, Sven; Growitsch, Christian; Schwind, Hannah; Gerdes, Rüdiger; Rehdanz, Katrin

    2017-12-01

    A significant share of the world's undiscovered oil and natural gas resources are assumed to lie under the seabed of the Arctic Ocean. Up until now, the exploitation of the resources especially under the European Arctic has largely been prevented by the challenges posed by sea ice coverage, harsh weather conditions, darkness, remoteness of the fields, and lack of infrastructure. Gradual warming has, however, improved the accessibility of the Arctic Ocean. We show for the most resource-abundant European Arctic Seas whether and how a climate induced reduction in sea ice might impact future accessibility of offshore natural gas and crude oil resources. Based on this analysis we show for a number of illustrative but representative locations which technology options exist based on a cost-minimization assessment. We find that under current hydrocarbon prices, oil and gas from the European offshore Arctic is not competitive on world markets.

  3. Influence of surfactant composition on physical and oxidative stability of Quillaja saponin-stabilized lipid particles with encapsulated ω-3 fish oil.

    Science.gov (United States)

    Salminen, Hanna; Aulbach, Susanne; Leuenberger, Bruno H; Tedeschi, Concetta; Weiss, Jochen

    2014-10-01

    The purpose of this study was to investigate the potential of a saponin-rich extract of Quillaja saponaria to replace bile salts in the surfactant formulations for stabilization of nanostructured lipid carriers (NLC). The influence of Quillaja extract and/or high-melting lecithin at different concentrations on physical and oxidative stability was evaluated in (i) NLC containing tristearin and ω-3 fish oil, (ii) ω-3 fish oil-in-water emulsion, and (iii) solid lipid nanoparticles (SLN) containing tristearin. Best physical, polymorphic and oxidative stability of NLC were achieved with a surfactant combination of 2.4% (w/w) Quillaja extract and 0.6% (w/w) high-melting lecithin. The results showed that encapsulation of ω-3 fish oil into NLC inhibited the formation of lipid hydroperoxides, propanal and hexanal by 72, 53 and 57%, respectively, compared to the fish oil-in-water emulsion prepared with the same surfactants. This indicated that the low oxidation observed in NLC cannot be due to potential antioxidative effects of the surfactant combination itself. Evidence is accumulating that tristearin is able to form a protective shell around the ω-3 fish oil, when crystallization is induced via high-melting phospholipids in the solidified interfacial layer. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Oxidative stability of biodiesels produced from vegetable oils having different degrees of unsaturation

    International Nuclear Information System (INIS)

    Pantoja, Samantha Siqueira; Conceição, Leyvison Rafael V. da; Costa, Carlos E.F. da; Zamian, José R.; Rocha Filho, Geraldo N. da

    2013-01-01

    Highlights: • We obtained biodiesel from açai, cupuaçu, passion fruit and linseed oil. • Determined the properties of biodiesel, such as kinematic viscosity, cold filter plugging point and oxidative stability. • Evaluated the influence of antioxidants on biodiesel. • The PG antioxidant was more efficient than BHA and TBHQ for the açaí biodiesel. - Abstract: In the present paper, methyl esters were obtained from the transesterification of cupuaçu fat lipids (Theobroma grandiflorum) (Willd. ex Spreng.) (K. Schum.), açaí (Euterpe oleracea), passion fruit (Passiflora edulis) and linseed (Linum usitatissimum L.) oils, using a basic catalyst. The triglycerides were characterized by their fatty acid composition, and the biodiesels were characterized according to standard methods. The critical properties, such as the cold filter plugging point, kinematic viscosity and oxidative stability, of the biodiesels were studied. The influence of butyl-hydroxyanisole (BHA), propyl gallate (PG) and tert-butyl hydroquinone (TBHQ) antioxidants on the açaí, passion fruit and linseed biodiesels was evaluated at concentrations from 500 to 4000 ppm. PG was found to be the most efficient antioxidant for the studied biodiesels

  5. Developing grey-box model to diagnose asphaltene stability in crude oils: Application of refractive index

    Directory of Open Access Journals (Sweden)

    Mahdi Zeinali Hasanvand

    2016-12-01

    Full Text Available Asphaltene precipitation can cause serious problems in petroleum industry while diagnosing the asphaltene stability conditions in crude oil system is still a challenge and has been subject of many investigations. To monitor and diagnose asphaltene stability, high performance intelligent approaches based bio-inspired science like artificial neural network which have been optimized by various optimization techniques have been carried out. The main purpose of the implemented optimization algorithms is to decide high accurate interconnected weights of proposed neural network model. The proposed intelligent approaches are examined by using extensive experimental data reported in open literature. Moreover, to highlight robustness and precision of the addressed approaches, two different regression models have been developed and results obtained from the aforementioned intelligent models and regression approaches are compared with the corresponding refractive index data measured in laboratory. Based on the results, hybrid of genetic algorithm and particle swarm optimization have high performance and average relative absolute deviation between the model outputs and the relevant experimental data was found to be less than 0.2%. Routs from this work indicate that implication of HGAPSO-ANN in monitoring refractive index can lead to more reliable estimation of addressed issue which can lead to design of more reliable phase behavior simulation and further plans of oil production.

  6. Evaluation of the oxidative stability of Chipotle chili (Capsicum annuum L. oleoresins in avocado oil

    Directory of Open Access Journals (Sweden)

    L. Cerecedo-Cruz

    2018-03-01

    Full Text Available Capsicum annuum L. (Chipotle chili is a natural source of bioactive metabolites with antioxidant properties. The objective of this research was to obtain and characterize the oxidative stability under storage of Chipotle chili oleoresins extracted with cold-pressed avocado oil. The most efficient conditions obtained to extract carotenoids and phenolic compounds were at 1:3 ratio (chipotle chili: avocado oil; w:v at room temperature in darkness during 48 h. At the end of the harshest conditions (45 °C, 30 days, the extracts were stable to lipid oxidation with a final Totox value of 27.34, a carotenoid preservation of 85.6%, antioxidant activity retention of 80.66% and a color change (ΔE of 1.783. The kinetic constants obtained were higher for peroxide formation than for carotenoid degradation. The oleoresins obtained could be considered an economic and sustainable alternative to extract carotenoids with good oxidation stability that could be used in foodstuffs.

  7. Effect of Leaves of Caesalpinia decapetala on Oxidative Stability of Oil-in-Water Emulsions

    Directory of Open Access Journals (Sweden)

    María Gabriela Gallego

    2017-03-01

    Full Text Available Caesalpinia decapetala (Roth Alston (Fabaceae (CD is used in folk medicine to prevent colds and treat bronchitis. This plant has antitumor and antioxidant activity. The antioxidant effects of an extract from Caesalpinia decapetala (Fabaceae were assessed by storage of model food oil-in-water emulsions with analysis of primary and secondary oxidation products. The antioxidant capacity of the plant extract was evaluated by the diphenylpicrylhydrazyl (DPPH, Trolox equivalent antioxidant capacity (TEAC, oxygen radical absorbance capacity (ORAC and ferric reducing antioxidant power (FRAP assays and by electron paramagnetic resonance (EPR spectroscopy. Lyophilized extracts of CD were added at concentrations of 0.002%, 0.02% and 0.2% into oil-in-water emulsions, which were stored for 30 days at 33 ± 1 °C, and then, oxidative stability was evaluated. The CD extract had high antioxidant activity (700 ± 70 µmol Trolox/g dry plant for the ORAC assay, mainly due to its phenolic components: gallic acid, quercetin, catechin, 4-hydroxybenzoic acid and p-coumaric acid. At a concentration of 0.2%, the extract significantly reduced the oxidative deterioration of oil-in-water emulsions. The results of the present study show the possibility of utilizing CD as a promising source of natural antioxidants for retarding lipid oxidation in the food and cosmetic industries.

  8. Process Optimization for Biodiesel Production from Corn Oil and Its Oxidative Stability

    Directory of Open Access Journals (Sweden)

    N. El Boulifi

    2010-01-01

    Full Text Available Response surface methodology (RSM based on central composite design (CCD was used to optimize biodiesel production process from corn oil. The process variables, temperature and catalyst concentration were found to have significant influence on biodiesel yield. The optimum combination derived via RSM for high corn oil methyl ester yield (99.48% was found to be 1.18% wt catalyst concentration at a reaction temperature of 55.6∘C. To determine how long biodiesel can safely be stored, it is desirable to have a measurement for the stability of the biodiesel against such oxidation. Storage time and oxygen availability have been considered as possible factors influencing oxidative instability. Biodiesel from corn oil was stored for a period of 30 months, and the physico-chemical parameters of samples were measured at regular interval of time. Results show that the acid value (AV, peroxide value (PV, and viscosity (ν increased while the iodine value (IV decreased. These parameters changed very significantly when the sample was stored under normal oxygen atmosphere. However, the ν, AV, and IV of the biodiesel sample which was stored under argon atmosphere were within the limit by the European specifications (EN 14214.

  9. Enhancing oxidative stability of sunflower oil during convective and microwave heating using grape seed extract.

    Science.gov (United States)

    Poiana, Mariana-Atena

    2012-01-01

    This study was performed to investigate the effectiveness of grape seed extract (GSE) compared to butylated hydroxytoluene (BHT) on retarding lipid oxidation of sunflower oil subjected to convection and microwave heating up to 240 min under simulated frying conditions. The progress of lipid oxidation was assessed in terms of peroxide value (PV), p-anisidine value (p-AV), conjugated dienes and trienes (CD, CT), inhibition of oil oxidation (IO) and TOTOX value. In addition, total phenolic content (TP) was evaluated in samples before and after heating in order to assess the changes in these compounds relative to the extent of lipid oxidation. The results of this study highlight that GSE showed a significantly inhibitory effect on lipid oxidation during both treatments, although to a different extent. This ability was dose-dependent; therefore, the extent of lipid oxidation was inversely related to GSE level. Convective heating, respective microwave exposure for 240 min of samples supplemented by GSE to a level of 1000 ppm, resulted in significant decreases of investigated indices relative to the control values as follows: PV (48%; 30%), p-AV (29%; 40%), CD (45%; 30%), CT (41%; 36%), TOTOX (35%; 37%). GSE to a level of 600-800 ppm inhibited the lipid oxidation in a similar manner to BHT. These results suggested that GSE can be used as a potential natural extract for improving oxidative stability of sunflower oil during thermal applications.

  10. Enhancing Oxidative Stability of Sunflower Oil during Convective and Microwave Heating Using Grape Seed Extract

    Directory of Open Access Journals (Sweden)

    Mariana-Atena Poiana

    2012-07-01

    Full Text Available This study was performed to investigate the effectiveness of grape seed extract (GSE compared to butylated hydroxytoluene (BHT on retarding lipid oxidation of sunflower oil subjected to convection and microwave heating up to 240 min under simulated frying conditions. The progress of lipid oxidation was assessed in terms of peroxide value (PV, p-anisidine value (p-AV, conjugated dienes and trienes (CD, CT, inhibition of oil oxidation (IO and TOTOX value. In addition, total phenolic content (TP was evaluated in samples before and after heating in order to assess the changes in these compounds relative to the extent of lipid oxidation. The results of this study highlight that GSE showed a significantly inhibitory effect on lipid oxidation during both treatments, although to a different extent. This ability was dose-dependent; therefore, the extent of lipid oxidation was inversely related to GSE level. Convective heating, respective microwave exposure for 240 min of samples supplemented by GSE to a level of 1000 ppm, resulted in significant decreases of investigated indices relative to the control values as follows: PV (48%; 30%, p-AV (29%; 40%, CD (45%; 30%, CT (41%; 36%, TOTOX (35%; 37%. GSE to a level of 600–800 ppm inhibited the lipid oxidation in a similar manner to BHT. These results suggested that GSE can be used as a potential natural extract for improving oxidative stability of sunflower oil during thermal applications.

  11. Improvement of the Physical and Oxidative Stability Characteristics of Ice Cream through Interesterified Moringa Oleifera Oil

    International Nuclear Information System (INIS)

    Nadeem, M.; Ullah, R.; Ullah, A.

    2016-01-01

    This study aimed to investigate the effect of high melting point interesterified M. oleifera oil (35.6 degree centigrade) with substantial amount of unsaturated fatty acids on physicochemical and oxidative stability characteristics of ice cream. Of the 10 percent fat in the ice cream, 30 percent was replaced by interesterified M. oleifera oil at three levels i.e. 10, 20 and 30 percent (T1, T2 and T3, respectively). Oleic acid increased from 26.55 percent to 31.69 percent, 36.94 percent and 42.15 percent in T1, T2 and T3 with no effect on melting time, compositional attributes and free fatty acid content of ice cream (P>0.05). Supplementation of ice cream with interesterified M. oleifera oil inhibited the autoxidation process in ice cream during 3 months storage period (P<0.05).The loss of oleic and linoleic acid in fresh and 3 months stored control and T2 was 26.55 percent, 24.15 percent, 26.39% percent and 1.93 percent, 1.24 percent and 1.79 percent, respectively. Peroxide value of three months stored control and T3 was 1.12 and 0.39 (meqO2/kg). The overall acceptability score of T2 was 80% of the total score (9). (author)

  12. Statistical characteristics and stability index (si) of large-sized landslide dams around the world

    International Nuclear Information System (INIS)

    Iqbal, J.; Dai, F.; Raja, I.A.

    2014-01-01

    In the last few decades, landslide dams have received greater attention of researchers, as they have caused loss to property and human lives. Over 261 large-sized landslide dams from different countries of the world with volume greater than 1 x 105 m have been reviewed for this study. The data collected for this study shows that 58% of the catastrophic landslides were triggered by earthquakes and 21 % by rainfall, revealing that earthquake and rainfall are the two major triggers, accounting for 75% of large-sized landslide dams. These land-slides were most frequent during last two decades (1990-2010) throughout the world. The mean landslide dam volume of the studied cases was 53.39 x 10 m with mean dam height of 71.98 m, while the mean lake volume was found to be 156.62 x 10 m. Failure of these large landslide dams pose a severe threat to the property and people living downstream, hence immediate attention is required to deal with this problem. A stability index (SI) has been derived on the basis on 59 large-sized landslide dams (out of the 261 dams) with complete parametric information. (author)

  13. British Gas drives for big role in world oil and gas

    International Nuclear Information System (INIS)

    Vielvoye, R.

    1991-01-01

    The metamorphosis of British Gas plc (BG) from a cash rich, state owned U.K. utility into a global oil and gas operator is turning the company into a major player on the world exploration and production scene. BG has set an ambitious goal of generating 40% of its revenue from E and P and 20% from its global gas operations by the end of the century. The remaining 40% will come from U.K. gas operations, which last year had revenues of Brit-pounds 7.6 billion ($12.7 billion) and accounted for 94% of the company's income compared with only 6% from E and P. To achieve its goal, the E and P division's revenues of Brit-pounds 622 million ($1.04 billion) must show at least a 10-fold increase during the next 8 years, while expansion of BG's gas business must be even more dramatic. With an operating budget of Brit-pounds 800 million ($1.34 billion) this year, excluding funds for acquisitions, BG is in an expansionist mood not seen in other large oil and gas companies since the late 1970s and early 1980s. E and P strategy gives priority to four core geographical areas of operation where development of reserves can lead to possible opportunities for the gas unit in gas distribution or power generation. The core areas are the U.K. continental shelf: Northwest Europe and the Soviet Union; the U.S., Canada, and Caribbean; and Pacific Rim

  14. EIA model documentation: World oil refining logistics demand model,``WORLD`` reference manual. Version 1.1

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-11

    This manual is intended primarily for use as a reference by analysts applying the WORLD model to regional studies. It also provides overview information on WORLD features of potential interest to managers and analysts. Broadly, the manual covers WORLD model features in progressively increasing detail. Section 2 provides an overview of the WORLD model, how it has evolved, what its design goals are, what it produces, and where it can be taken with further enhancements. Section 3 reviews model management covering data sources, managing over-optimization, calibration and seasonality, check-points for case construction and common errors. Section 4 describes in detail the WORLD system, including: data and program systems in overview; details of mainframe and PC program control and files;model generation, size management, debugging and error analysis; use with different optimizers; and reporting and results analysis. Section 5 provides a detailed description of every WORLD model data table, covering model controls, case and technology data. Section 6 goes into the details of WORLD matrix structure. It provides an overview, describes how regional definitions are controlled and defines the naming conventions for-all model rows, columns, right-hand sides, and bounds. It also includes a discussion of the formulation of product blending and specifications in WORLD. Several Appendices supplement the main sections.

  15. Oxidative stability of rice bran, corn, canola, sunflower and soybean oils d baking process and storage of bread

    Directory of Open Access Journals (Sweden)

    Najmeh Jahani

    2016-01-01

    Full Text Available Oxidation of bread lipids during baking and storage reduces the nutritional value of the product and leads to the formation of off-flavors and off-odors. In this research, oxidative stability of rice bran, corn, canola, sunflower and soybean oils during Brotchen bread baking process and storage was evaluated. Baking process caused a significant increase in oxidative indices such as peroxide, anisidine, Totox and thiobarbitoric acid values and free fatty acid content. However, storage of breads for 6 days in room temperature did not affect the value of the indices. Generaly, the value of the indices in bread containing rice bran oil was lower than those of the other breads, which indicated the higher oxidative stability of rice bran oil in baking process and storage. Pure oils treated in simulated baking process and storage had an oxidative quality similar to that of breads. This means that bread ingridients may not have an effect on oil oxidative stability. Bread containing rice bran oil gained also higher scores in sensory evaluation, which of course were in agree with its better oxidative status.

  16. Emulsion stability and properties of fish gelatin-based films as affected by palm oil and surfactants.

    Science.gov (United States)

    Nilsuwan, Krisana; Benjakul, Soottawat; Prodpran, Thummanoon

    2016-05-01

    Gelatin films exhibit the poor water vapour barrier properties. The use of palm oil, which is abundant and available in Thailand, can be a means to lower water vapour migration. To disperse oil in film-forming dispersion (FFD), a surfactant along with appropriate homogenization is required. The study aimed to investigate the influence of palm oil level and surfactants in the absence or presence of glycerol on characteristics of FFD and resulting gelatin films. Similar oil droplet sizes, both d32 and d43 values, of FFD containing soy lecithin were observed, regardless of palm oil level used (P > 0.05). FFD with Tween-20 had larger droplet size as the levels of oil increased (P palm oil level increased (P 0.05). FFD containing 500 or 750 g kg(-1) palm oil using soy lecithin as a surfactant in the presence of 300 g kg(-1) glycerol had the enhanced homogeneity and stability of oil droplets. The resulting gelatin film had the improved water vapour barrier properties. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

  17. Long term prospect of demand and supply of energy in the world-mainly on the crude oil market

    Energy Technology Data Exchange (ETDEWEB)

    Sagawa Naoto (The Inst. of Energy Economics, Tokyo, (Japan))

    1989-03-01

    At present, the world oil market is in the state of over supply, but concerning the long term prospect of oil price, there are a view, which is traditional, that the oil price goes up in 1990's and a view that the current over supply continues for a long time. In this article, a model predicting the world energy demand and supply is prepared and based upon this, a simulation of demand and supply is conducted. This model is conceptually divided into the following blocks, namely macroeconomy, energy demand, petrolium supply and price, coal supply and price, and natural gas supply and price. Main exogeneous variables are population, time trend, output of atomic power and hydroelectric power, oil production capability of OPEC, genuine amount of energy for exportation of the Communist circle, and distribution of energy source reserve, etc.. Main endogenous variables are economic growth rate, rate of inflation, price of the primary energy as well as that of the secondary energy, energy demand, and primary energy supply. As a result, in the year of 2,000, the crude oil price will be 20/bbl in case when a structural change takes place and 30/bbl in case of no such a change. 4 refs., 3 figs., 3 tabs.

  18. Chemical composition, oxidative stability and antioxidant capacity of oil extracted from roasted seeds of Sacha-inchi (Plukenetia volubilis L.).

    Science.gov (United States)

    Cisneros, Fausto H; Paredes, Daniel; Arana, Adrian; Cisneros-Zevallos, Luis

    2014-06-04

    The effect of roasting of Sacha-inchi (Plukenetia volubilis L.) seeds on the oxidative stability and composition of its oil was investigated. The seeds were subjected to light, medium and high roasting intensities. Oil samples were subjected to high-temperature storage at 60 °C for 30 days and evaluated for oxidation (peroxide value and p-anisidine), antioxidant activity (total phenols and DPPH assay), and composition (tocopherol content and fatty acid profile). Results showed that roasting partially increased oil oxidation and its antioxidant capacity, slightly decreased tocopherol content, and did not affect the fatty acid profile. During storage, oxidation increased for all oil samples, but at a slower rate for oils from roasted seeds, likely due to its higher antioxidant capacity. Also, tocopherol content decreased significantly, and a slight modification of the fatty acid profile suggested that α-linolenic acid oxidized more readily than other fatty acids present.

  19. Oxidative stability and alpha-tocopherol retention in soybean oil with lemon seed extract (Citrus limon) under thermoxidation.

    Science.gov (United States)

    Luzia, Débora Maria Moreno; Jorge, Neuza

    2009-11-01

    The synergistic effect of lemon seed extract with tert-butylhydroquinone (TBHQ) in soybean oil subjected to thermoxidation by Rancimat was investigated, and the influence of these antioxidants on a-tocopherol degradation in thermoxidized soybean oil. Control, LSE (2400 mg/kg Lemon Seed Extract), TBHQ (50 mg/kg), Mixture 1 (LSE + 50 mg/kg TBHQ) and Mixture 2 (LSE + 25 mg/kg TBHQ) were subjected to 180 degrees C for 20 h. Samples were taken at time 0, 5, 10, 15 and 20 h intervals and analysed for oxidative stability and alpha-tocopherol content. LSE and Mixtures 1 and 2 showed the capacity of retarding lipid oxidation when added to soya oil and also contributed to alpha-tocopherol retention in oil heated at high temperatures. However, Mixtures 1 and 2 added to the oil presented a greater antioxidant power, consequently proving the antioxidants synergistic effect.

  20. Application of the accelerated test Rancimat to evaluate oxidative stability of dried microencapsulated oils

    Directory of Open Access Journals (Sweden)

    Márquez-Ruiz, G.

    2000-08-01

    Full Text Available The objective of this work was to apply the oxidative test Rancimat to dried microencapsulated oils (DMO, with special emphasis on assessing the efficacy of natural antioxidants. DMO were prepared by freeze-drying emulsions containing sodium caseinate, lactose and fish or sunflower oils, with and without added the antioxidant mixture ALT (ascorbic acid, lecithin and tocopherol. Under the Rancimat working conditions selected for testing DMO (5 g sample, 100ºC and 20 L air/h, excellent repeatability was obtained. The antioxidant effect of ALT was much higher in bulk fish oil than in its counterpart DMO, either in Rancimat or at 30ºC in the dark. Further experiments using Rancimat showed that the moderate increase in stability of DMO added ALT was only attributable to tocopherol while the synergistic actions of lecithin and ascorbic acid were not observed, their action probably depending on their location and orientation in these complex lipid systems. This test enabled to compare monophasic (bulk oils and DMO-extracted oils and heterophasic lipidic systems (DMO and DMO devoid of the accessible, free oil fraction, thus offering a rapid means to examine the influence of oil distribution and partitioning of antioxidants on oxidative stability.El objetivo de este trabajo es la aplicación del test Rancimat a aceites microencapsulados, con especial interés en el estudio de la eficacia de antioxidantes naturales. Los aceites microencapsulados en matriz seca (DMO se prepararon mediante liofilización de emulsiones constituidas por caseinato sódico, lactosa y aceite de pescado o girasol, con o sin la mezcla antioxidante ALT (ácido ascórbico, lecitina y tocoferol. En las condiciones seleccionadas en Rancimat (5 g de muestra, 100ºC y 20 L/h aire se obtuvo excelente repetitividad. La mezcla ALT fue mucho más efectiva en el aceite de pescado que en su correspondiente DMO, tanto en Rancimat como a 30ºC en la oscuridad. Otros experimentos en

  1. Extracting oil palm crown from WorldView-2 satellite image

    Science.gov (United States)

    Korom, A.; Phua, M.-H.; Hirata, Y.; Matsuura, T.

    2014-02-01

    Oil palm (OP) is the most commercial crop in Malaysia. Estimating the crowns is important for biomass estimation from high resolution satellite (HRS) image. This study examined extraction of individual OP crown from a WorldView-2 image using twofold algorithms, i.e., masking of Non-OP pixels and detection of individual OP crown based on the watershed segmentation of greyscale images. The study site was located in Beluran district, central Sabah, where matured OPs with the age ranging from 15 to 25 years old have been planted. We examined two compound vegetation indices of (NDVI+1)*DVI and NDII for masking non-OP crown areas. Using kappa statistics, an optimal threshold value was set with the highest accuracy at 90.6% for differentiating OP crown areas from Non-OP areas. After the watershed segmentation of OP crown areas with additional post-procedures, about 77% of individual OP crowns were successfully detected in comparison to the manual based delineation. Shape and location of each crown segment was then assessed based on a modified version of the goodness measures of Möller et al which was 0.3, indicating an acceptable CSGM (combined segmentation goodness measures) agreements between the automated and manually delineated crowns (perfect case is '1').

  2. Extracting oil palm crown from WorldView-2 satellite image

    International Nuclear Information System (INIS)

    Korom, A; Phua, M-H; Hirata, Y; Matsuura, T

    2014-01-01

    Oil palm (OP) is the most commercial crop in Malaysia. Estimating the crowns is important for biomass estimation from high resolution satellite (HRS) image. This study examined extraction of individual OP crown from a WorldView-2 image using twofold algorithms, i.e., masking of Non-OP pixels and detection of individual OP crown based on the watershed segmentation of greyscale images. The study site was located in Beluran district, central Sabah, where matured OPs with the age ranging from 15 to 25 years old have been planted. We examined two compound vegetation indices of (NDVI+1)*DVI and NDII for masking non-OP crown areas. Using kappa statistics, an optimal threshold value was set with the highest accuracy at 90.6% for differentiating OP crown areas from Non-OP areas. After the watershed segmentation of OP crown areas with additional post-procedures, about 77% of individual OP crowns were successfully detected in comparison to the manual based delineation. Shape and location of each crown segment was then assessed based on a modified version of the goodness measures of Möller et al which was 0.3, indicating an acceptable CSGM (combined segmentation goodness measures) agreements between the automated and manually delineated crowns (perfect case is '1')

  3. Kaolinite and Silica Dispersions in Low-Salinity Environments: Impact on a Water-in-Crude Oil Emulsion Stability

    Directory of Open Access Journals (Sweden)

    Vladimir Alvarado

    2011-10-01

    Full Text Available This research aims at providing evidence of particle suspension contributions to emulsion stability, which has been cited as a contributing factor in crude oil recovery by low-salinity waterflooding. Kaolinite and silica particle dispersions were characterized as functions of brine salinity. A reference aqueous phase, representing reservoir brine, was used and then diluted with distilled water to obtain brines at 10 and 100 times lower Total Dissolved Solid (TDS. Scanning Electron Microscope (SEM and X-ray Diffraction (XRD were used to examine at the morphology and composition of clays. The zeta potential and particle size distribution were also measured. Emulsions were prepared by mixing a crude oil with brine, with and without dispersed particles to investigate emulsion stability. The clay zeta potential as a function of pH was used to investigate the effect of particle charge on emulsion stability. The stability was determined through bottle tests and optical microscopy. Results show that both kaolinite and silica promote emulsion stability. Also, kaolinite, roughly 1 mm in size, stabilizes emulsions better than larger clay particles. Silica particles of larger size (5 µm yielded more stable emulsions than smaller silica particles do. Test results show that clay particles with zero point of charge (ZPC at low pH become less effective at stabilizing emulsions, while silica stabilizes emulsions better at ZPC. These result shed light on emulsion stabilization in low-salinity waterflooding.

  4. Rheological properties and physical stability of ecological emulsions stabilized by a surfactant derived from cocoa oil and high pressure homogenization

    Directory of Open Access Journals (Sweden)

    Trujillo-Cayado, L. A.

    2015-09-01

    Full Text Available The goal of this work was to investigate the influence of the emulsification method on the rheological properties, droplet size distribution and physical stability of O/W green emulsions formulated with an eco-friendly surfactant derived from cocoa oil. The methodology used can be applied to other emulsions. Polyoxyethylene glycerol esters are non-ionic surfactants obtained from a renewable source which fulfill the environmental and toxicological requirements to be used as eco-friendly emulsifying agents. In the same way, N,NDimethyloctanamide and α-Pinene (solvents used as oil phase could be considered green solvents. Emulsions with submicron mean diameters and slight shear thinning behavior were obtained regardless of the homogenizer, pressure or number of passes used. All emulsions exhibited destabilization by creaming and a further coalescence process which was applied to the coarse emulsion prepared with a rotor-stator homogenizer. The emulsion obtained with high pressure at 15000 psi and 1-pass was the most stable.El objetivo de este trabajo fue estudiar la influencia del método de emulsificación sobre las propiedades reológicas, la distribución de tamaños de gota y la estabilidad física de emulsiones verdes O/W formuladas con un tensioactivo derivado del aceite de coco respetuoso con el medioambiente. La metodología empleada puede ser aplicada a cualquier otro tipo de emulsiones. Los ésteres polietoxilados de glicerina son tensioactivos no iónicos obtenidos de fuentes renovables que cumplen requisitos medioambientales y toxicológicos para ser usados como agentes emulsionantes ecológicos. Del mismo modo, la N,N-dimetil octanamida y el α-Pineno (disolventes usados como fase oleosa pueden ser considerados como disolventes verdes. Se han obtenido emulsiones con diámetros medio submicrónicos y comportamiento ligeramente pseudoplástico independientemente del equipo, la presión o el número de pasadas empleados. Todas las

  5. Water-in-oil emulsions prepared by peptide-silicone hybrid polymers as active interfacial modifier: effects of silicone oil species on dispersion stability of emulsions.

    Science.gov (United States)

    Sakai, Kenichi; Iijima, Satoshi; Ikeda, Ryosuke; Endo, Takeshi; Yamazaki, Takahiro; Yamashita, Yuji; Natsuisaka, Makoto; Sakai, Hideki; Abe, Masahiko; Sakamoto, Kazutami

    2013-01-01

    We have recently proposed a new general concept regarding amphiphilic materials that have been named as "active interfacial modifier (AIM)." In emulsion systems, an AIM is essentially insoluble in both water and organic solvents; however, it possesses moieties that are attracted to each of these immiscible liquid phases. Hence, an AIM practically stays just at the interface between the two phases and makes the resulting emulsion stable. In this study, the effects of silicone oil species on the dispersion stability of water-in-oil (W/O) emulsions in the presence of an AIM sample were evaluated in order to understand the destabilization mechanism in such emulsion systems. The AIM sample used in this study is an amphiphilic polymer consisting of a silicone backbone modified with hydrocarbon chains and hydrolyzed silk peptides. The Stokes equation predicts that the sedimentation velocity of water droplets dispersed in a continuous silicone oil phase simply depends on the expression (ρ - ρ₀)/η assuming that the droplet size is constant (where ρ is the density of the dispersed water phase, ρ₀ is the density of the continuous silicone oil phase, and η is the viscosity of the oil phase). The experimental results shown in this paper are consistent with the Stokes prediction: i.e., in the low-viscous genuine or quasi-Newtonian fluid region, the dispersion stability increases in the following order: dodecamethylpentasiloxane (DPS) D₅ > D₆. This indicates that our emulsion system experiences destabilization through sedimentation, but hardly any coalescence occurs owing to the presence of an additional third phase consisting of the AIM that stabilizes the silicone oil/water interface in the emulsions.

  6. Characteristics and oxidative stability of bread fortified with encapsulated shrimp oil

    Directory of Open Access Journals (Sweden)

    Sirima Takeungwongtrakul

    2015-12-01

    Full Text Available Characteristics and oxidative stability of bread fortified with micro-encapsulated shrimp oil (MSO were determined. The addition of MSO could improve the loaf volume of bread. Chewiness,gumminess and resilience of resulting bread were decreased. Bread crust and crumb showed higher redness and yellowness when MSO was incorporated (P<0.05. Microstructure study revealed that MSO remained intact with bread crumbs. The addition of MSO up to 3% had no adverse effect on bread quality and sensory acceptability. Oxidation took place in bread fortified with 5%MSO to a higher extent, compared with those with 1 or 3% MSO. Therefore, the bread could be fortified with MSO up to 3%.

  7. Effect of stabilizers, oil level and structure on the growth of Zygosaccharomyces bailii and on physical stability of model systems simulating acid sauces.

    Science.gov (United States)

    Zalazar, Aldana L; Gliemmo, María F; Campos, Carmen A

    2016-07-01

    The effect of xanthan gum, guar gum, oil and the structure promoted by these compounds on the growth of Zygosaccharomyces bailii and on physical stability of emulsified systems simulating acid sauces was studied. Furthermore, the effect of yeast growth on physical stability of emulsions was also evaluated. Yeast growth was evaluated by plate count and modeled by the modified Gompertz equation. Emulsions characteristics and their stability were determined by droplet size, zeta potential and rheological measurements. The latter was also used to evaluate structure's effect on yeast growth. Physical characteristics of emulsions depended on system composition. Yeasts slightly affected droplet size. Z. bailii growth was satisfactorily modeled by the modified Gompertz equation. The specific growth rate (μ m ) and the asymptotic value (A) obtained depended on xanthan gum, guar gum and oil content. Furthermore, the structure promoted by these compounds exerted a significant effect on growth. In general, an increase in the solid character and yield stress through the addition of xanthan gum promoted a decrease in A parameter. On the contrary, a decrease in the solid character through the addition of guar gum promoted an increase in the A parameter. The results obtained stressed that stabilizers, oil and their structuring ability play an important role on Z. bailii growth. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. World oil and gas exploration trends: A comparative study of national and U.S. private oil companies

    International Nuclear Information System (INIS)

    Ghouri, S.S.K.

    1991-01-01

    This study hypothesizes that private oil companies and state-owned, national oil companies (NOCs) have different objectives and priorities and thus that different behavioral models are needed to explain changes over time in the level of exploration by these two groups of companies. More specifically, exploration by private companies is expected to be more sensitive to changing oil prices than exploration by NOCs. The study develops three different sets of expected determinants of change over time in the level of exploration (for private companies, and two groups of NOCs-oil importers and non-OPEC oil exporters). In the private-sector model, exploration is driven by expected determinants of profitability, such as oil prices and exploration costs. The NOC models also include national-priority variables, such as import dependency. The study then tests these behavioral models by specifying and estimating econometric models for the period 1970-1988 for 11 companies from the three company groups. Three econometric models are used: static, Koyck distributed lag, and Almon polynomial distributed lag models. The study concludes on the basis of three comparisons that different behavioral models are needed to understand changes in the level of exploration by private companies and NOCs. First, the private-sector model is estimated for all companies. For private companies, the private-sector model works well, whereas for the NOCs it does not, presumably because important determinants of NOC exploration are excluded from the model. Second, when these excluded variables are included in the specification, regression results for the NOCs improve significantly. Third, the private companies have higher elasticities of exploration in both the short run and long run than the NOCs

  9. STUDY ON THE THERMAL STABILITY OF EPA AND DHA IN MUJAHIR (Oreochromis mossambicus FISH OIL

    Directory of Open Access Journals (Sweden)

    Ngatidjo Hadipranoto

    2010-06-01

    Full Text Available EPA (Eicosapentaenoic acid and DHA (Docosahexaenoic acid content in common fresh water fish : mujahir (Oreochromis mossambicus after indirect heating were analysed. The aims of this study were to determine the effect of indirect heating process and α-tocopherol additions on both fatty acid stability.Lipids content in the mujahir fillets were extracted by Folch method using chloroform-metanol (2:1 mixture. Fatty acids in fish oil were converted to fatty acid methyl esters and then injected into gas chromatography to determine the EPA and DHA concentration. Operating condition of gas chromatography were programmed as follows: injection port temperature at 270 oC, detector at 280 oC, initial column temperature at 200 oC, and the final at 280 oC, the carrier gas was helium with flow rate of 10 ml per minute and temperature of column was increased gradually at 10 oC per minute. The effect of α-tocopherol addition on the stability of EPA and DHA was studied by adding α-tocopherol at 50 to 200 mg per kilogram sample before indirect heating process was carried out.The analysis of mujahir fish oil showed that the content of EPA and DHA in 100 grams fresh sample was 105 and 406,5 mg respectivelly. Indirect heating caused the EPA and DHA content decreased significantly. The addition of α-tocopherol results in a positive corelation between α-tocopherol concentration added and the decrease of EPA and DHA content during the heating process.   Keywords: fatty acid, eicosapentaenoic acid, docosahexaenoic acid

  10. Combination of sodium caseinate and succinylated alginate improved stability of high fat fish oil-in-water emulsions

    DEFF Research Database (Denmark)

    Yesiltas, Betül; Sørensen, Ann-Dorit Moltke; García Moreno, Pedro Jesús

    2018-01-01

    Sodium caseinate (CAS) and commercial sodium alginate (CA), long chain modified alginate (LCMA) or short chain modified alginate (SCMA) were used in combination for emulsifying and stabilizing high fat (50–70%) fish oil-in-water emulsions. Physical (creaming, droplet size, viscosity and protein...

  11. Oxidative Stability of Granola Bars Enriched with Multilayered Fish Oil Emulsion in the Presence of Novel Brown Seaweed Based Antioxidants

    DEFF Research Database (Denmark)

    Hermund, Ditte Baun; Karadaǧ, Ayşe; Andersen, Ulf

    2016-01-01

    Fucus vesiculosus extracts that have both radical scavenging activity and metal chelating ability in vitro were used as natural antioxidant in granola bars enriched with fish oil emulsion by using primary and secondary emulsion systems stabilized by sodium caseinate alone and sodium caseinate...... were added to the granola bars especially in combination with acetone and ethanol extracts of Fucus vesiculosus....

  12. Effects of thermal processing on physicochemical properties and oxidative stability of Balanities aegyptiaca kernels and extracted oil

    Directory of Open Access Journals (Sweden)

    S. M.A. Elbadawi

    2017-03-01

    Full Text Available In the present study, the effects of roasting and boiling on the proximate composition of the kernels as well as the physicochemical properties and oxidative stabilities of the extracted oils of Balanites aegyptiaca were investigated. Roasting was performed at 180 ˚C for 15 minutes, whereas boiling of the kernels was carried out in tap water for one hour. The oils from raw and thermally processed samples were extracted using n-hexane in a Soxhlet extraction apparatus and characterized. The roasting significantly (p < 0.05 influenced the peroxide value and the oxidative stability of the extracted oil in a positive way; whereas boiling had the opposite effect. The oils were composed of linoleic, oleic, stearic, and palmitic acids as the major fatty acids (96% and contained predominantly α- and γ-tocopherols (ca. 400mg/kg. The study suggests that the oil from roasted kernels could be used as a natural antioxidant for enhancing the characteristics of other edible oils via blending.

  13. Effects of thermal processing on physicochemical properties and oxidative stability of Balanities aegyptiaca kernels and extracted oil

    International Nuclear Information System (INIS)

    Elbadawi, S.M.A.; Ahmad, E.E.M.; Mariod, A.A.; Mathäus, B.

    2017-01-01

    In the present study, the effects of roasting and boiling on the proximate composition of the kernels as well as the physicochemical properties and oxidative stabilities of the extracted oils of Balanites aegyptiaca were investigated. Roasting was performed at 180 °C for 15 minutes, whereas boiling of the kernels was carried out in tap water for one hour. The oils from raw and thermally processed samples were extracted using n-hexane in a Soxhlet extraction apparatus and characterized. The roasting significantly (p < 0.05) influenced the peroxide value and the oxidative stability of the extracted oil in a positive way; whereas boiling had the opposite effect. The oils were composed of linoleic, oleic, stearic, and palmitic acids as the major fatty acids (96%) and contained predominantly α- and γ-tocopherols (ca. 400mg/kg). The study suggests that the oil from roasted kernels could be used as a natural antioxidant for enhancing the characteristics of other edible oils via blending. [es

  14. Nanoencapsulation of chia seed oil with chia mucilage (Salvia hispanica L.) as wall material: Characterization and stability evaluation.

    Science.gov (United States)

    de Campo, Camila; Dos Santos, Priscilla Pereira; Costa, Tania Maria Haas; Paese, Karina; Guterres, Silvia Stanisçuaski; Rios, Alessandro de Oliveira; Flôres, Simone Hickmann

    2017-11-01

    In this study, chia seed oil was nanoencapsulated utilizing chia seed mucilage (CSM) as wall material. The viscosity, encapsulation efficiency, loading capacity, transmission electron microscopy, FT-IR spectroscopy and thermal properties of chia seed oil nanoparticles (CSO-NP) were performed after preparation. Particle size, zeta potential, span value, and pH of CSO-NP and oxidation stability of nanoencapsulated and unencapsulated oil were evaluated during 28days of storage at accelerated conditions (40°C). The CSO-NP showed spherical shape, an average size of 205±4.24nm and zeta potential of -11.58±1.87mV. The encapsulation efficiency (82.8%), loading capacity (35.38%) and FT-IR spectroscopy demonstrated the interaction between oil and mucilage. Furthermore, CSO-NP were thermally stable at temperatures up 300°C and nanoencapsulated oil showed higher stability against oxidation than unencapsulated oil. The results suggest that chia seed mucilage represents a promising alternative to substitute synthetic polymers in nanoencapsulation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. Universal Janus Filters for the Rapid Separation of Oil from Emulsions Stabilized by Ionic or Nonionic Surfactants.

    Science.gov (United States)

    Wang, Zijie; Lehtinen, Morgan; Liu, Guojun

    2017-10-09

    Existing Janus filters cannot separate oil from emulsions stabilized by nonionic surfactants. Reported herein are universal Janus filters that separate oil from emulsions stabilized by not only ionic but also nonionic surfactants. To prepare such a filter, poly(dimethyl siloxane) (PDMS) is grafted onto one side of a fabric. The other side is then grafted with a copolymer polysoap bearing pendant oligo(ethylene glycol) monolaurate (EL) chains. Upon contact with an emulsion, the grafted polysoap competes with free surfactants, ionic or nonionic, for adsorption onto the emulsified droplets, drawing them to the surfaces of the fabric fibers, and causes them to coalesce locally. The coalesced oil then migrates to the PDMS-coated side of the fabric and selectively permeates it. These novel filters possess enhanced versatility and showcase a new application for polysoaps. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Oil and the future: Taking bearings in the greenhouse in a post Brent Spar world

    Energy Technology Data Exchange (ETDEWEB)

    Leggett, J.

    1995-12-31

    The paper discusses future oil combustion. A greenhouse-related environmental driving-force seems set to emerge in the capital markets in the years ahead. This will severely compound other already serious environment-related financial problems blighting the oil-industry`s access to capital radar screen. The wise oil company is now, increasingly clearly, the company thinking about how to begin repositioning itself for the twenty-first century as a total energy company. 6 refs.

  17. Biscuits fortified with micro-encapsulated shrimp oil: characteristics and storage stability.

    Science.gov (United States)

    Takeungwongtrakul, Sirima; Benjakul, Soottawat

    2017-04-01

    Characteristics and storage stability of biscuits fortified with micro-encapsulated shrimp oil (MSO) were determined. The addition of MSO increased spread ratio, whilst decreased the thickness of biscuit. The highest hardness of biscuit was obtained with addition of 9 or 12% MSO. Biscuit surface showed higher redness and yellowness when MSO was incorporated ( p  < 0.05). The addition of MSO up to 6% had no adverse effect on biscuit quality and acceptability. When biscuits added with 6% MSO were stored under different illumination conditions (light and dark), lipid oxidation in all samples increased throughout the storage of 12 days. Light accelerated lipid oxidation of biscuits as evidenced by the increases in both peroxide values and abundance of volatile compounds. No marked change in EPA, DHA and astaxanthin contents were noticeable in biscuit fortified with MSO after 12 days of storage. Therefore, the biscuit could be fortified with MSO up to 6% and must be stored in dark to assure its oxidative stability.

  18. Correlating the chemical and physical properties of a set of heavy oils from around the world

    Energy Technology Data Exchange (ETDEWEB)

    Amy Hinkle; Eun-Jae Shin; Matthew W. Liberatore; Andrew M. Herring; Mike Batzle [Colorado School of Mines, Golden, CO (United States). Department of Geophysics

    2008-10-15

    Variations in the viscosity and other physical properties of heavy oils are poorly understood. The viscosities measured for different heavy oils can vary by orders of magnitude even at the same API gravity, which is the standard metric for lighter oils. Heavy oils are viscoelastic materials, and the shear modulus and the viscosity are coupled. Understanding what controls heavy oil viscosity will provide insight into what controls heavy oil shear modulus. Therefore, using rheology, ultrasonic measurements and molecular beam mass spectroscopy (MBMS) the physical and chemical properties of seven heavy oils from around the globe are explored. The viscoelastic nature of the oils is quantified as a function of temperature. Overall, the heavy oil samples show little correlation between the viscosity or shear modulus and the API gravity, separate resin content or separate asphaltene content as measured from SARA analysis. However, the total resin plus asphaltene content collapses the viscosity and modulus values to provide empirical relations between these quantities. Also, a partial least squares regression analysis provides tight correlations for the chemical signatures from the MBMS. The rapid and quantitative nature of the MBMS make it an attractive substitute for the inconsistencies endemic to SARA analysis. 24 refs., 11 figs., 1 tab.

  19. Sexual reproduction in species of the brown seaweed, Fucus, to assess damage and recovery from the World Prodigy oil spill

    International Nuclear Information System (INIS)

    Thursby, E.; Tagliabue, M.; Sheehan, C.; Steele, R.

    1990-01-01

    On Friday, June 23, 1989, the oil tanker World Prodigy ran aground on Brenton Reef off Newport, Rhode Island, USA, spilling No. 2 fuel oil into the mouth of Narragansett Bay. This paper reports that a shoreline survey of the intertidal and upper subtidal macroalgae was begun on June 24th as part of a larger effort to document the fate and effect of the oil. There was little evidence of necrotic tissue among the attached plants at most of the site visited. However, several species of the brown alga, Fucus, showed inhibition of sexual reproduction. Reproductive material of F. vesiculosus, F. spiralis or F. spiralis var. limitaneus was collected from various sites for later laboratory assessment of viability. Viability was determined by germination rate of embryos. Summer is not the optimal reproductive time for Fucus, and embryos of F. spiralis var. limitaneus never germinated at a rate greater than 25%, even from clean sites. Fucus spiralis plants were collected at Narragansett Pier, before arrival of oil from the spill. Embryos at this site had a germination rate of 63%. There was essentially no germination by either F. vesiculosus or F. spiralis at any oil sites visited during the first collections. However, by July 5th at some sites, and by July 13th at all sites, the germination rate of these two species averaged from 60 to 88%

  20. Stabilizing southeastern Europe, financial legacies and European lessons from the first world war

    Directory of Open Access Journals (Sweden)

    Lampe John R.

    2014-01-01

    Full Text Available This paper pays brief attention, although more than the recent flood of 1914 centenary books, to economic causes of the First World War before turning to it fateful economic consequences for Southeastern Europe. The Austrian lack of economic leverage over Serbia is cited as a reason for its resort to the military option. At the war’s end, the option of the victorious powers to provide significant economic relief to the region where the conflict had begun was not taken. After tracking the brief, limited assistance provided, the paper reviews to the massive economic problems confronting four of the five of independent states, neglecting Albania as a special case, that could now be called Southeastern Europe. First Greece and then Bulgaria faced forced inflow of refugees. Romania and the Yugoslav Kingdom faced the economic integration of large new, formerly Austro-Hungarian lands. All of them were left not only with war deaths and destruction but also with large war debts, or in Bulgaria’s case, reparations. The paper concentrates on the primary Western response to these four economies, an effort led by the Bank of England to replace immediate postwar inflation with the deflation needed to reestablish currencies with prewar convertibility to gold, now with Pound Sterling added to a gold reserve standard. Independent central banks, the major positive legacy of this initiative, were to lead the way. But the financial stability that all four economies did eventually achieve in the 1920s served only to reduce their war debts. Otherwise, maintaining the fixed and overvalued exchange rates restricted domestic credit, encouraged protective tariffs, and did not attract the foreign capital, especially new state loans, that this emphasis on a single, European financial framework had promised. A concluding section considers the lessons learned from a postwar period that promoted economic disintegration by the 1930s. Looking at the period since the end of

  1. New filtration systems for extra-virgin olive oil: effect on antioxidant compounds, oxidative stability, and physicochemical and sensory properties.

    Science.gov (United States)

    Lozano-Sánchez, Jesús; Cerretani, Lorenzo; Bendini, Alessandra; Gallina-Toschi, Tullia; Segura-Carretero, Antonio; Fernández-Gutiérrez, Alberto

    2012-04-11

    The purpose of this work was to evaluate some new filtration systems in relation to the quality of extra-virgin olive oil (EVOO). Filtration processes were undertaken using a polypropylene filter bag and two different inert gas flows as filter aids (argon and nitrogen). Qualitative and quantitative variations of the glyceride composition, antioxidant and pro-oxidant compounds, and water content were correlated with the oxidative stability to establish the effect on EVOO shelf life. The influence on physicochemical and sensorial properties was also evaluated. After filtration, the oxidative stability was reduced. The behavior of the polyphenols and water content on the filtration process could explain the lowest oxidative stability of filtered EVOO. Moreover, the results of the sensorial analysis confirmed that filtration using inert gases did not decrease the intensity of the main positive sensory attributes. The results could help olive-oil producers to improve EVOO quality and establish optimal storage conditions.

  2. Effect of Oregano Essential Oil (Origanum vulgare subsp. hirtum) on the Storage Stability and Quality Parameters of Ground Chicken Breast Meat

    OpenAIRE

    Al-Hijazeen, Marwan; Lee, Eun Joo; Mendonca, Aubrey; Ahn, Dong Uk

    2016-01-01

    A study was conducted to investigate the effect of oregano essential oil on the oxidative stability and color of raw and cooked chicken breast meats. Five treatments, including (1) control (none added); (2) 100 ppm oregano essential oil; (3) 300 ppm oregano essential oil; (4) 400 ppm oregano essential oil; and (5) 5 ppm butylated hydroxyanisole (BHA), were prepared with ground boneless, skinless chicken breast meat and used for both raw and cooked meat studies. For raw meat study, samples wer...

  3. Time-dependent stability of used engine oil degradation by cultures ...

    African Journals Online (AJOL)

    Pseudomonas fragi and Achromobacter aerogenes isolated from used engine oil polluted soils were grown in minimal salts medium (MSM) supplemented with used engine oil as sole carbon and energy source to evaluate their ability to biodegrade used engine oil. The two organisms utilized 73.3 and 80.0% of the oil with ...

  4. Rheological Properties of Nanoparticle Silica-Surfactant Stabilized Crude Oil Emulsions: Influence of Temperature, Nanoparticle Concentration and Water Volume Fraction"

    Science.gov (United States)

    Kinsey, Erin; Pales, Ashley; Li, Chunyan; Mu, Linlin; Bai, Lingyun; Clifford, Heather; Darnault, Christophe

    2016-04-01

    Oil in water emulsions occur during oil extraction due to the presence of water, naturally-occurring surface-active agents and mechanical mixing in pipelines or from oil spillage. Emulsions present difficulties for use of oil in fuel and their rheological properties are important to treat environmental impacts of spills. The objective of this study is to assess the rheological characteristics of oil in water emulsions stabilized by 5% NaCl brine, Tween 20 surfactant and silica nanoparticles to gain knowledge about the behavior of oil flow in pipelines and characterize them for environmental applications. Rheological behaviors such as shear rate, shear stress, and viscosity of Prudhoe Bay crude oil emulsions were analyzed with varying percent of water volume fractions (12.5, 25 and 50%), varying weight percent of silica nanoparticles (0.001, 0.01 and 0.1 weight %), with and without 2 CMC Tween 20 nonionic surfactant. Emulsions with varying water volume fractions were analyzed at 20, 40 and 60 degrees Celsius. Flow curve analysis of the emulsions was performed using an Anton-Paar rheometer. Preliminary findings indicate that increased temperature and increasing the concentration of nanoparticles both produced lower shear stress and that the addition of surfactant decreased the viscosity and shear stress of the emulsions.

  5. Spray dried microparticles of chia oil using emulsion stabilized by whey protein concentrate and pectin by electrostatic deposition.

    Science.gov (United States)

    Noello, C; Carvalho, A G S; Silva, V M; Hubinger, M D

    2016-11-01

    Chia seed oil has a high content of α-linolenic acid (60%) and linoleic acid (20%). Use of this oil in different products is limited due to its liquid state, and the presence of insaturation is a trigger for oxidation. In this context, to facilitate the incorporation of chia oil in food products and increase its protection against oxidation, the aim of this work was to produce chia oil microparticles by spray drying using emulsions stabilized by whey protein concentrate (ζ-potential +13.4 at pH3.8) and pectin (ζ-potential -40.4 at pH3.8) through the electrostatic layer-by-layer deposition technique and emulsions prepared with only whey protein concentrate. Emulsions stabilized by whey protein concentrate and stabilized by whey protein concentrate-pectin were prepared using maltodextrin (10 DE) and modified starch (Hi-Cap® 100). They were characterized in relation to stability, droplet size, ζ-Potential and optical microscopy. The microparticles were characterized in relation to moisture content, water activity, particle size, microstructure and oxidative stability by the Rancimat method. Emulsions stabilized by whey protein concentrate-pectin with added maltodextrin 10 DE and emulsions stabilized by whey protein concentrate with added modified starch (Hi-Cap® 100) were stable after 24h. Emulsions stabilized by whey protein concentrate and by whey protein concentrate-pectin showed droplets with mean diameter ranging from 0.80 to 1.31μm, respectively and ζ-potential varying from -6.9 to -27.43mV, respectively. After spray drying, the microparticles showed an mean diameter ranging from 7.00 to 9.00μm. All samples presented high encapsulation efficiency values, above 99%. Microparticles produced with modified starch showed a smoother spherical surface than particles with maltodextrin 10 DE, which presented a wrinkled surface. All microparticles exhibited higher oxidative stability than chia oil in pure form. Copyright © 2016 Elsevier Ltd. All rights reserved.

  6. Triacylglycerol composition, physico-chemical characteristics and oxidative stability of interesterified canola oil and fully hydrogenated cottonseed oil blends.

    Science.gov (United States)

    Imran, Muhammad; Nadeem, Muhammad

    2015-10-29

    Partial hydrogenation process is used worldwide to produce shortening, baking, and pastry margarines for food applications. However, demand for such products is decreased during last decade due to their possible links to consumer health and disease. This has raised the need to replace hydrogenation with alternative acceptable interesterification process which has advantage in context of modifying the physico-chemical properties of edible fat-based products. Therefore, the main mandate of research was the development of functional fat through chemical interesterification of canola oil (CaO) and fully hydrogenated cottonseed oil (FHCSO) mixtures. Blends were prepared in the proportions of 75:25 (T1), 50:50 (T2) and 25:75 (T3) of CaO:FHCSO (w/w). Interesterification was performed using sodium methoxide (0.2 %) as catalyst at 120 °C, under reduced pressure and constant agitation for 60 minutes. The non-interesterified and interesterified CaO:FHCSO blends were evaluated for triacylglycerol (TAG) composition, physico-chemical characteristics, oxidative stability and consumer acceptability at 0, 30 and 60 days of storage interval. The oleic acid (58.3 ± 0.6 %) was predominantly present in CaO while the contents of stearic acid (72 ± 0.8 %) were significantly higher in FHCSO. Maximum trisaturated (S3) contents (63.9 ± 0.5 %) were found in T3 while monounsaturated (S2U), diunsaturated (U2S) and triunsaturated (U3) contents were quite low in T2 and T3 before interesterification. A marked reduction in S3 and U3 contents with concomitant increase in S2U and U2S contents was observed for all CaO:FHCSO blends on interesterification. During storage, the changes in S3, S2U and U2S contents were not found significant (p ≥ 0.05). However, maximum decrease 13 %, 7.5 and 5.6 % in U3 contents for T1, T2 and T3 was noted after 60-days of interesterification, respectively. The Lovibond color R, melting point, refractive index, specific gravity, peroxide and free

  7. The future world oil market: state of nature or social contract?

    International Nuclear Information System (INIS)

    Noel, P.

    1999-10-01

    Mary Ann Tetreault develops a very interesting interpretation of the emerging new relationship between international oil companies and Middle East producing countries. The original intellectual tools she handles-concepts drawn from the European political philosophy tradition-allow her to argue as follows: (1) the oil market left to itself- whether participants are states or firms-behaves like a Hobbesian ''state of nature'' often resulting in a situation damaging to each participant; (2) to deal with it, the international oil community has historically relied on different types of organisations, but these social contracts or ''republics'' were inherently unstable since they rested on too narrowly defined interests; (3) the rationale behind the possible return of oil companies to the richest Middle East countries is the search for new ''international oil republics'' able to ''offer greater security and higher profits for all the good republicans among them''. (author)

  8. Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil

    Energy Technology Data Exchange (ETDEWEB)

    Sarin, Amit [Department of Applied Sciences, Amritsar College of Engineering and Technology, Manawala, Amritsar-143001, Punjab (India); Singh, N.P. [Punjab Technical University, Jalandhar (India); Sarin, Rakesh; Malhotra, R.K. [Indian Oil Corporation Ltd., R and D Centre, Sector-13, Faridabad-121007 (India)

    2010-12-15

    According to the proposed National Mission on Biodiesel in India, we have undertaken studies on the oxidative stability of biodiesel synthesized from tree borne non-edible oil seeds jatropha. Neat jatropha biodiesel exhibited oxidation stability of 3.95 h and research was conducted to investigate the influence of natural and synthetic antioxidants on the oxidation stability of jatropha methyl ester. Antioxidants namely {alpha}-tocopherol, tert-butylated hydroxytoluene, tert-butylated phenol derivative, octylated butylated diphenyl amine, and tert-butylhydroxquinone were doped to improve the oxidation stability. It was found that both types of antioxidants showed beneficial effects in increasing the oxidation stability of jatropha methyl ester, but comparatively, the synthetic antioxidants were found to be more effective. (author)

  9. Effect of fluorescent light on quality and stability of edible fats and oils

    International Nuclear Information System (INIS)

    Ahmed, T.; Atta, S.; Sohail, M.; Khan, A.R.; Akhter, S.

    2011-01-01

    Photo oxidative stress were applied to commonly consumed edible oil and fat i.e., animal fat (AF), vanaspati ghee (VG), sunflower oil (SFO), desi ghee (DG), rapeseed oil (RSO), soybean oil (SBO) as well as sea buckthorn seed oil (SB Seed oil) and sea buckthorn pulp oil (SB Pulp oil). The changes in their quality parameters i.e. free fatty acid (FFA), peroxide value (POV), beta-carotene and color (OD) were determined. Photo oxidative stress significantly (p < 0.05) increased the FFA, POV and OD, however, concentration of beta carotene decreased in all the samples with the increase in storage time. The Sea buckthorn oil was found to be more stable than other oils owing to the presence of tocopherol contents and beta-carotene. (author)

  10. Antioxidant activity for spice oils (1) anti oxidative stability of thyme and caraway oil extracts under UV-irradiation

    International Nuclear Information System (INIS)

    Atef Ghazy, M.; Shaker, E.S.

    2002-01-01

    The anti oxidative activity for some spice essential oils have been investigated using thiocyanate method and compared with common natural antioxidant. The antioxidant activity for nine spice oils has been measured at 500 ppm after 13 days. The most potent one was the lemon grass (99.8), followed by orange peel, thyme, and caraway. The activities for these four oils were higher than that for Alpha-tocopherol (87.7%). Petitgrain, and geranium oils have marched activity but less than that for Alpha-tocopherol. No obvious has been found for citronella. fennel, and cardamon oils. The aqueous, butanoic, methanolic and hexanoic extracts for thyme and caraway oil exhibit effective anti oxidative activities under UV irradiation (254 nm) for 6 and 10 hr compared with that for alpha-tocopherol. The anti oxidative effect of thyme and caraway oil extracts were found to be strong and stable towards UV-irradiation, and equal to that for Alpha-tocopherol. Thyme's aqueous and caraway's hexanal extracts were the most potent extracts under the same conditions

  11. Enhancing oxidative stability in heated oils using core/shell structures of collagen and α-tocopherol complex.

    Science.gov (United States)

    Gim, Seo Yeong; Hong, Seungmi; Kim, Jisu; Kwon, YongJun; Kim, Mi-Ja; Kim, GeunHyung; Lee, JaeHwan

    2017-11-15

    In this study, collagen mesh structure was prepared by carrying α-tocopherol in the form of core/shell complex. Antioxidant properties of α-tocopherol loaded carriers were tested in moisture added bulk oils at 140°C. From one gram of collagen core/shell complex, 138mg α-tocopherol was released in medium chain triacylglycerol (MCT). α-Tocopherol was substantially protected against heat treatment when α-tocopherol was complexed in collagen core/shell. Oxidative stability in bulk oil was significantly enhanced by added collagen mesh structure or collagen core/shell complex with α-tocopherol compared to that in control bulk oils (pshell with α-tocopherol (p>0.05). Results of DPPH loss in methanol demonstrated that collagen core/shell with α-tocopherol had significantly (pshell complex is a promising way to enhance the stability of α-tocopherol and oxidative stability in oil-rich foods prepared at high temperature. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Proceedings of the world heavy oil congress : 2009 business and technical conference

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    This international conference provided a forum for collaborative examination of issues facing the heavy oil industry. The complete heavy oil value chain was examined in order to define short-term and long-term challenges and supply solutions. Leading experts were linked with the latest technologies for the unconventional oil industry. Participants from Venezuela, Canada, China, Brazil, France, Italy, Mexico, Netherlands, Norway, Russia, the United Kingdom and the United States presented case studies and field results, along with numerical simulation and laboratory investigations. The topics ranged from innovative oil sands processing and upgrading technologies; reservoir exploitation strategies; produced water treatment; sand control; reservoir monitoring; cementing design; geomechanics; and recovery processes such as cold heavy oil production with sand (CHOPS), chemical flooding, steam assisted gravity drainage, in-situ combustion and toe-to-heel air injection (THAI). The technical conference featured sessions on drilling and completions; fuels and upgrading; thermal recovery operations; field development; enhanced oil recovery and emerging recovery technologies; reservoir characterization; oil and water treatment; processing and transportation; production facilities; upgrading technology; and production technology. All 100 papers from the technical sessions have been catalogued separately for inclusion in this database. refs., tabs., figs.

  13. Synergetic Use of Principal Component Analysis Applied to Normed Physicochemical Measurements and GC × GC-MS to Reveal the Stabilization Effect of Selected Essential Oils on Heated Rapeseed Oil.

    Science.gov (United States)

    Sghaier, Lilia; Cordella, Christophe B Y; Rutledge, Douglas N; Lefèvre, Fanny; Watiez, Mickaël; Breton, Sylvie; Sassiat, Patrick; Thiebaut, Didier; Vial, Jérôme

    2017-06-01

    Lipid oxidation leads to the formation of volatile compounds and very often to off-flavors. In the case of the heating of rapeseed oil, unpleasant odors, characterized as a fishy odor, are emitted. In this study, 2 different essential oils (coriander and nutmeg essential oils) were added to refined rapeseed oil as odor masking agents. The aim of this work was to determine a potential antioxidant effect of these essential oils on the thermal stability of rapeseed oil subject to heating cycles between room temperature and 180 °C. For this purpose, normed determinations of different parameters (peroxide value, anisidine value, and the content of total polar compounds, free fatty acids and tocopherols) were carried out to examine the differences between pure and degraded oil. No significant difference was observed between pure rapeseed oil and rapeseed oil with essential oils for each parameter separately. However, a stabilizing effect of the essential oils, with a higher effect for the nutmeg essential oil was highlighted by principal component analysis applied on physicochemical dataset. Moreover, the analysis of the volatile compounds performed by GC × GC showed a substantial loss of the volatile compounds of the essential oils from the first heating cycle. © 2017 Institute of Food Technologists®.

  14. Oxidative stability during storage of fish oil from filleting by-products of rainbow trout (Oncorhynchus mykiss) is largely independent of the processing and production temperature

    DEFF Research Database (Denmark)

    Honold, Philipp; Nouard, Marie-Louise; Jacobsen, Charlotte

    2016-01-01

    be used to produce high quality fish oil. In this study, the oxidative stability of fish oil produced from filleting by-products was evaluated. The oil was produced from conventional or organic fish (low and high omega-3 fatty acid content) at different temperatures (70 and 90°C). The oxidative stability......Rainbow trout (Oncorhynchus mykiss) is the main fish species produced in Danish fresh water farming. Large amounts of fileting by-products like heads, bones, tails (HBT), and intestines are produced when rainbow trout is processed to smoked rainbow trout filets. The filleting by-products can...... of the oil was tested during storage at two different temperatures (20 and 40°C). Results showed that omega-3 content of the fish oil influenced the oxidative stability, whereas the processing temperature during oil production played a minor role....

  15. Money matters. Financial world looks at oil companies with Argus eyes

    International Nuclear Information System (INIS)

    Van Gool, M.

    2008-01-01

    The financial markets foresee high risks in the energy sector for the big, private oil companies such as ExxonMobil, Shell and BP. It appears that these companies are undervalued, In contrast, financial backers are justifiably positive about companies providing services to the oil sector, such as Schlumberger and Halliburton, and 'utilities', such as Eon and EDF, which still have considerable room for growth, The relatively high valuation of state-controlled oil and gas companies such as Gazprom is somewhat more speculative

  16. Sensory and chemical stability in coated peanuts with the addition of essential oils and synthetic antioxidants

    Directory of Open Access Journals (Sweden)

    Olmedo, R. H.

    2012-03-01

    Full Text Available The objective of this work was to evaluate the antioxidant effect of essential oils on the oxidative stability of coated peanuts. Untreated coated peanuts (CP and treated coated peanuts with the addition of rosemary (CP-R, oregano (CP-O and laurel (CP-L essential oils and BHT (CPBHT were prepared. Peroxide values (PV and p-anisidine values (AV and the intensity ratings of sensory attributes by descriptive analysis were measured during 112 days of storage at room temperature (23°C. CP-BHT exhibited the lowest PV and AV increase. CP-R, CP-O and CP-L showed lower rates of increase in PV and AV than CP. The oxidized and cardboard flavor intensity ratings increased much more in CP during storage than the other studied products. CPBHT also showed the lowest increase in the intensity ratings of these sensory attributes. Three essential oils, namely, laurel, oregano and rosemary showed antioxidant activity and increased the shelf life of coated peanuts.

    El objetivo de este trabajo fue evaluar el efecto antioxidante de aceites esenciales sobre la estabilidad oxidativa en maní recubiertos. Se prepararon maníes recubiertos sin agregados (CP, y con el agregado de aceites esenciales de romero (CP-R, orégano (CP-O y laurel (CP-L y BHT (CPBHT. Se midieron, durante 112 días de almacenamiento, los valores de peróxidos (PV y p-anisidina (AV, y las intensidades de atributos sensoriales mediante análisis descriptivo. CP-BHT presentó el menor valor de PV y AV. CP-R, CP-O y CP-L tuvieron mayor PV y AV respecto a CP. Los valores de intensidad del sabor oxidado y cartón tuvieron un mayor incremento en CP durante el almacenamiento con respecto a los otros productos estudiados. La muestra CP-BHT también mostró los menores valores de intensidad de estos atributos sensoriales. Los aceites esenciales de laurel, orégano y romero presentaron actividad antioxidante e incrementaron la vida útil del maní recubierto.

  17. Oxidative stability of mayonnaise and milk drink produced with structured lipids based on fish oil and caprylic acid

    DEFF Research Database (Denmark)

    Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

    2004-01-01

    The oxidative stabilities of traditional fish oil (FO), randomized lipids (RFO), or specific structured lipids (SFO) produced from fish oil were compared when incorporated into either milk drink or mayonnaise. Furthermore, the effect of adding the potential antioxidants EDTA (240 mg...... not be ascribed to a single factor, but was most likely influenced by the structure of the lipids and differences in the processes used to produce and purify the lipids. In milk drinks based on SFO, EDTA slightly reduced oxidation, while lactoferrin did not exert a distinct antioxidative effect...

  18. Microencapsulation of borage oil with blends of milk protein, β-glucan and maltodextrin through spray drying: physicochemical characteristics and stability of the microcapsules.

    Science.gov (United States)

    Li, Ru-Yi; Shi, Yan

    2018-02-01

    Borage oil is a rich commercial source of γ-linolenic acid (18:3n-6). However, borage oil is rich in omega-6 polyunsaturated fatty acids and vulnerable to oxidation. Thus, selecting appropriate wall materials is critical to the encapsulation of borage oil. The present study investigated the influence of wall materials on the physicochemical characteristics and stability of microencapsulated borage oil by spray drying. Blends of milk protein [sodium caseinate (CAS) or whey protein concentrate], β-glucan (GLU) and maltodextrin (MD) were used as the wall materials for encapsulating borage oil. The microencapsulation of borage oil with different wall materials attained high encapsulation efficiencies. The microencapsulated borage oil prepared with CAS-MD achieved the optimal encapsulation efficiency of 96.62%. The oxidative stabilities of borage oil and microencapsulated borage oil were measured by accelerated storage test at 45 °C and 33% relative humidity for 30 days. The microencapsulated borage oil presented lower peroxide values than those of borage oil, and the microcapsules prepared with CAS-10GLU-MD (consisting of CAS 50 g kg -1 , GLU 100 g kg -1 and MD 475 g kg -1 of microencapsulation) conferred borage oil with high protection against lipid oxidation. The results of the present study demonstrate that the CAS-GLU-MD blend is appropriate for microencapsulating borage oil. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  19. Improving oxidative stability of olive oil: Incorporation of Spirulina and evaluation of its synergism with citric acid

    International Nuclear Information System (INIS)

    Alavi, N.; Golmakani, M.T.

    2017-01-01

    The effects of different Spirulina concentrations used alone and in combination with citric acid on the oxidative stability of olive oil were assessed. The amounts of primary and secondary oxidation products produced in Spirulina samples were lower than that of the control. The improved oxidative stability indices of Spirulina samples with and without citric acid were in the range of 85.20–94.47% and 258.10–260.21%, respectively. In comparison with the control, Spirulina samples manifested significantly higher carotenoid and chlorophyll contents at the beginning and end of the storage period. The presence of these bioactive compounds results from the presence of Spirulina in the medium and can thus retard the oxidation of olive oil. A higher oxidative stability was reached using BHT in comparison with Spirulina samples. Furthermore, no synergistic action was observed in possible connections between citric acid and Spirulina. In conclusion, Spirulina can enhance oxidative stability and improve the shelf life of olive oil. [es

  20. Chemical composition, antioxidant properties, and thermal stability of a phytochemical enriched oil from Acai (Euterpe oleracea Mart.).

    Science.gov (United States)

    Pacheco-Palencia, Lisbeth A; Mertens-Talcott, Susanne; Talcott, Stephen T

    2008-06-25

    Phenolic compounds present in crude oil extracts from acai fruit ( Euterpe oleracea) were identified for the first time. The stability of acai oil that contained three concentrations of phenolics was evaluated under short- and long-term storage for lipid oxidation and phenolic retention impacting antioxidant capacity. Similar to acai fruit itself, acai oil isolates contained phenolic acids such as vanillic acid (1,616 +/- 94 mg/kg), syringic acid (1,073 +/- 62 mg/kg), p-hydroxybenzoic acid (892 +/- 52 mg/kg), protocatechuic acid (630 +/- 36 mg/kg), and ferulic acid (101 +/- 5.9 mg/kg) at highly enriched concentrations in relation to acai pulp as well as (+)-catechin (66.7 +/- 4.8 mg/kg) and numerous procyanidin oligomers (3,102 +/- 130 mg/kg). Phenolic acids experienced up to 16% loss after 10 weeks of storage at 20 or 30 degrees C and up to 33% loss at 40 degrees C. Procyanidin oligomers degraded more extensively (23% at 20 degrees C, 39% at 30 degrees C, and 74% at 40 degrees C), in both high- and low-phenolic acai oils. The hydrophilic antioxidant capacity of acai oil isolates with the highest phenolic concentration was 21.5 +/- 1.7 micromol Trolox equivalents/g, and the total soluble phenolic content was 1252 +/- 11 mg gallic acid equivalents/kg, and each decreased by up to 30 and 40%, respectively, during long-term storage. The short-term heating stability at 150 and 170 degrees C for up to 20 min exhibited only minor losses (oil from acai fruit offers a promising alternative to traditional tropical oils for food, supplements, and cosmetic applications.

  1. The corbiculate bees arose from New World oil-collecting bees: implications for the origin of pollen baskets.

    Science.gov (United States)

    Martins, Aline C; Melo, Gabriel A R; Renner, Susanne S

    2014-11-01

    The economically most important group of bees is the "corbiculates", or pollen basket bees, some 890 species of honeybees (Apis), bumblebees (Bombus), stingless bees (Meliponini), and orchid bees (Euglossini). Molecular studies have indicated that the corbiculates are closest to the New World genera Centris, with 230 species, and Epicharis, with 35, albeit without resolving the precise relationships. Instead of concave baskets, these bees have hairy hind legs on which they transport pollen mixed with floral oil, collected with setae on the anterior and middle legs. We sampled two-thirds of all Epicharis, a third of all Centris, and representatives of the four lineages of corbiculates for four nuclear gene regions, obtaining a well-supported phylogeny that has the corbiculate bees nested inside the Centris/Epicharis clade. Fossil-calibrated molecular clocks, combined with a biogeographic reconstruction incorporating insights from the fossil record, indicate that the corbiculate clade arose in the New World and diverged from Centris 84 (72-95)mya. The ancestral state preceding corbiculae thus was a hairy hind leg, perhaps adapted for oil transport as in Epicharis and Centris bees. Its replacement by glabrous, concave baskets represents a key innovation, allowing efficient transport of plant resins and large pollen/nectar loads and freeing the corbiculate clade from dependence on oil-offering flowers. The transformation could have involved a novel function of Ubx, the gene known to change hairy into smooth pollen baskets in Apis and Bombus. Copyright © 2014 Elsevier Inc. All rights reserved.

  2. The end of oil: on the edge of a perilous new world

    National Research Council Canada - National Science Library

    Roberts, Paul

    2004-01-01

    ...; and a Western middle class that refuses to modify its energy-dependent lifestyle. But within thirty years, by even conservative estimates, we will have burned our way through most of the oil that is easily accessible...

  3. Destabilization, Propagation, and Generation of Surfactant-Stabilized Foam during Crude Oil Displacement in Heterogeneous Model Porous Media.

    Science.gov (United States)

    Xiao, Siyang; Zeng, Yongchao; Vavra, Eric D; He, Peng; Puerto, Maura; Hirasaki, George J; Biswal, Sibani L

    2018-01-23

    Foam flooding in porous media is of increasing interest due to its numerous applications such as enhanced oil recovery, aquifer remediation, and hydraulic fracturing. However, the mechanisms of oil-foam interactions have yet to be fully understood at the pore level. Here, we present three characteristic zones identified in experiments involving the displacement of crude oil from model porous media via surfactant-stabilized foam, and we describe a series of pore-level dynamics in these zones which were not observed in experiments involving paraffin oil. In the displacement front zone, foam coalesces upon initial contact with crude oil, which is known to destabilize the liquid lamellae of the foam. Directly upstream, a transition zone occurs where surface wettability is altered from oil-wet to water-wet. After this transition takes place, a strong foam bank zone exists where foam is generated within the porous media. We visualized each zone using a microfluidic platform, and we discuss the unique physicochemical phenomena that define each zone. In our analysis, we also provide an updated mechanistic understanding of the "smart rheology" of foam which builds upon simple "phase separation" observations in the literature.

  4. Stability, rheology and thermal analysis of functionalized alumina- thermal oil-based nanofluids for advanced cooling systems

    International Nuclear Information System (INIS)

    Ilyas, Suhaib Umer; Pendyala, Rajashekhar; Narahari, Marneni; Susin, Lim

    2017-01-01

    Highlights: • Alumina nanoparticles are functionalized with oleic acid. • Functionalization of alumina nanoparticles gives better dispersion in thermal oil. • Thermophysical properties of nanofluids are experimentally measured. • TGA confirms the improvement in life of nanofluids. - Abstract: Thermal oils are widely used as cooling media in heat transfer processes. However, their potential has not been utilised exquisitely in many applications due to low thermal properties. Thermal oil-based nanofluids are prepared by dispersing functionalized alumina with varying concentrations of 0.5–3 wt.% to enhance thermal properties of oil for advanced cooling systems. The oleic acid coated alumina is prepared and then dispersed in the oil to overcome the aggregation of nanoparticles in base fluid. The surface characterizations of functionalized nanoparticles are performed using different analysis such as XRD, EDS, SEM, TEM and FTIR. Dispersion behaviour and agglomeration studies are conducted at natural and functionalized conditions using different analysis to ensure long-term stability of nanofluids. In addition, rheological behaviour of non-Newtonian nanofluids is studied at high shear rates (100–2000 s −1 ). Effective densities and enhancement in thermal conductivities are measured for different nanofluids concentrations. Specific heat capacity is measured using Differential Scanning Calorimetry. The correlations are developed for thermophysical properties of nanofluids. Thermogravimetric analysis is performed with respect to temperature and time to exploit the effect of the addition of nanoparticles on the degradation of nanofluids. Significant improvement in the thermal properties of oil is observed using highly stable functionalized alumina nano-additives.

  5. Improvement of stability and carotenoids fraction of virgin olive oils by addition of microalgae Scenedesmus almeriensis extracts.

    Science.gov (United States)

    Limón, Piedad; Malheiro, Ricardo; Casal, Susana; Acién-Fernández, F Gabriel; Fernández-Sevilla, José M; Rodrigues, Nuno; Cruz, Rebeca; Bermejo, Ruperto; Pereira, José Alberto

    2015-05-15

    Humans are not capable of synthesizing carotenoids de novo and thus, their presence in human tissues is entirely of dietary origin. Consumption of essential carotenoids is reduced due to the lower intake of fruits and vegetables. Microalgae are a good source of carotenoids that can be exploited. In the present work, carotenoids rich extracts from Scenedesmus almeriensis were added to extra-virgin olive oils at different concentrations (0.1 and 0.21 mg/mL) in order to enhance the consumption of these bioactives. Extracts brought changes in olive oils color, turning them orange-reddish. Quality of olive oils was improved, since peroxidation was inhibited. Olive oils fatty acids and tocopherols were not affected. β-carotene and lutein contents increase considerably, as well as oxidative stability, improving olive oils shelf-life and nutritional value. Inclusion of S. almeriensis extracts is a good strategy to improve and enhance the consumption of carotenoids, since olive oil consumption is increasing. Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. Heating Quality and Stability of Aqueous Enzymatic Extraction of Fatty Acid-Balanced Oil in Comparison with Other Blended Oils

    Directory of Open Access Journals (Sweden)

    Yang Li

    2014-01-01

    Full Text Available The heating performance of enzyme-assisted aqueous processing-extracted blended oil (EAEPO, hexane-extracted blended oil (HEBO, and three kinds of blended oils was investigated by varying the heating times. Oil degradation was monitored by analysis of the acid value (AV, peroxide value (PV, p-anisidine value (p-AV, color, and trans-fatty acid composition. The fatty acid ratios of EAEPO, HEBO, and the three kinds of blended oils were very similar (0.27 : 1.03 : 0.96, 0.27 : 1.08 : 1.16, 0.27 : 0.65 : 0.8, 0.27 : 0.6 : 0.84, and 0.27 : 0.61 : 0.79, resp.. The AV and color increased in proportion to the heating time for all the oils. There was a rapid increase in the PV and p-AV of EAEPO and HEBO after heating for only 1 h, whereas the other three blended oils showed a rapid increase after heating for 2 h or 6 h. Despite the highest trans-fatty acid content found for HEBO, this content was relatively low and remained low up to a heating time of 8 h. It was found that after heating, a fatty acid ratio relatively close to its ideal value (0.27 : 0.48 : 0.49 was maintained by EAEPO, which indicates that EAEPO is tolerant to heat treatment and is suitable for maintaining a healthy diet.

  7. An innovative method for the solidification/stabilization of PAHs-contaminated soil using sulfonated oil.

    Science.gov (United States)

    Ma, Fujun; Wu, Bin; Zhang, Qian; Cui, Deshan; Liu, Qingbing; Peng, Changsheng; Li, Fasheng; Gu, Qingbao

    2018-02-15

    Stabilization/solidification (S/S) has been successfully employed in many superfund sites contaminated with organic materials. However, this method's long-term effectiveness has not been fully evaluated and the increase in soil volume following treatment is unfavorable to follow-up disposal. The present study developed a novel method for the S/S of PAHs-contaminated soil with the facilitation of sulfonated oil (SO). Adding SO significantly improved the unconfined compressive strength (UCS) values of Portland cement and activated carbon (PC-AC) treated soil samples, and the UCS values of the soil sample treated with 0.02% of SO were up to 2.3 times higher than without SO addition. When the soil was treated with PC-AC-SO, the PAHs leaching concentrations were 14%-25% of that in leachates of the control soil, and high molecular weight PAHs including benzo(a)pyrene were rarely leached. Freeze/thaw durability tests reveal that the leachability of PAHs was not influenced by freeze-thaw cycles. The UCS values of PC-AC-SO treated soil samples were 2.2-3.4 times greater than those of PC-AC treated soil samples after 12 freeze-thaw cycles. The PC-AC-SO treated soils resist disintegration better when compared to the PC-AC treated soils. The SEM micrographs reveal that the soils' compactness was significantly improved when treated with SO. Copyright © 2017 Elsevier B.V. All rights reserved.

  8. Amorphous nano-curcumin stabilized oil in water emulsion: Physico chemical characterization.

    Science.gov (United States)

    Aditya, N P; Hamilton, Ian E; Norton, Ian T

    2017-06-01

    Particle characteristics e.g. size and polymorphism are known to significantly affect the Pickering ability of the solid particles by influencing their interaction at the oil and water (O/W) interface. In this study, nano-sized amorphous curcumin particles were fabricated using nanonization technology to use them as Pickering particles. After nanonization, native crystalline curcumin particles were converted into amorphous, nanosized particles of ∼220nm. Amorphous nature of the particle was evident from the decreased melting point from 177±1°C (native curcumin) to 146±3°C (nanonized curcumin) and enthalpy from 27±2J/g to 3.5±1J/g. Interfacial tension (IFT) studies have shown a decrease in IFT at the O/W interface from ∼27mN/m to ∼15mN/m in the presence of amorphous curcumin particles in water phase compared to crystalline curcumin particles. Curcumin stabilized O/W emulsion has an initial droplet size of ∼1.2μm and they were stable for 30days at 4°C. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Effects of heating, aerial exposure and illumination on stability of fucoxanthin in canola oil.

    Science.gov (United States)

    Zhao, Dong; Kim, Sang-Min; Pan, Cheol-Ho; Chung, Donghwa

    2014-02-15

    The effects of heating, aerial exposure and illumination on the stability of fucoxanthin was investigated in canola oil. In the absence of air and light, the heating caused the degradation of total and all-trans fucoxanthin at all tested temperatures between 25 and 100 °C. The increase of heating temperature promoted the formation of 13-cis and 13'-cis and the degradation of 9'-cis. The degradation and formation reactions were found to follow simple first-order kinetics and to be energetically unfavorable, non-spontaneous processes. Arrhenius-type temperature dependence was observed for the degradation of total and all-trans fucoxanthin but not for the reactions of cis isomers. The aerial exposure promoted the oxidative fucoxanthin degradation at 25 °C, whilst illumination caused the initial formation of all-trans, with concurrent sudden degradation of 13-cis and 13'-cis, and the considerable formation of 9'-cis. The fucoxanthin degradation was synergistically promoted when exposed to both air and light. Copyright © 2013 Elsevier Ltd. All rights reserved.

  10. Wellbore Stability in Oil and Gas Drilling with Chemical-Mechanical Coupling

    Directory of Open Access Journals (Sweden)

    Chuanliang Yan

    2013-01-01

    Full Text Available Wellbore instability in oil and gas drilling is resulted from both mechanical and chemical factors. Hydration is produced in shale formation owing to the influence of the chemical property of drilling fluid. A new experimental method to measure diffusion coefficient of shale hydration is given, and the calculation method of experimental results is introduced. The diffusion coefficient of shale hydration is measured with the downhole temperature and pressure condition, then the penetration migrate law of drilling fluid filtrate around the wellbore is calculated. Furthermore, the changing rules of shale mechanical properties affected by hydration and water absorption are studied through experiments. The relationships between shale mechanical parameters and the water content are established. The wellbore stability model chemical-mechanical coupling is obtained based on the experimental results. Under the action of drilling fluid, hydration makes the shale formation softened and produced the swelling strain after drilling. This will lead to the collapse pressure increases after drilling. The study results provide a reference for studying hydration collapse period of shale.

  11. The struggle for energy. How the growing need for oil and gas will cause a world crisis

    International Nuclear Information System (INIS)

    Op het Veld, R.

    2008-07-01

    Due to the rapid and continued economic growth of China and India, energy demand is increasing rapidly. At the same time, the Western world is facing decreasing oil and gas reserves. As a result, it becomes increasingly dependent on the Middle East and countries such as Russia and Venezuela. Shell and ExxonMobil, who were once dominant oil giants, are losing territory to state energy companies such as Saudi Aramco and Gazprom. The author analyses all these developments, also based on a series of interviews with various experts from trade and industry and the government in the Netherlands and abroad. The author states that the only solution for the energy issue and the climate issue is the development of alternative energy sources. However, for the present this will not suffice to meet growing demand. The battle for energy ultimately paints a picture that is not rosy, involving a crisis and an increasing international rat race for energy. [mk] [nl

  12. Sectoral effects of a world oil-price shock: economy-wide linkages to the agricultural sector. Staff report

    International Nuclear Information System (INIS)

    Hanson, K.; Robinson, S.; Schluter, G.

    1991-10-01

    The effects of a world oil price shock on U.S. agriculture are analyzed in an economywide environment. The authors use an input-output model to analyze the direct and indirect cost linkages between energy and other sectors of the economy. Then, to allow sectoral output adjustment and the effects on the U.S. current account, they use the U.S. Department of Agriculture/Economic Research Service Computable General Equilibrium (CGE) model to analyze the sectoral effects under three different macro adjustment scenarios. The effects on agriculture are not limited to the direct and indirect energy costs. Exchange rate or foreign borrowing adjustments to higher oil import costs and government support programs for agriculture also matter

  13. The Influence of Chemically Modified Potato Maltodextrins on Stability and Rheological Properties of Model Oil-in-Water Emulsions

    Directory of Open Access Journals (Sweden)

    Karolina Pycia

    2018-01-01

    Full Text Available The aim of this study was to determine the effect of the maltodextrins prepared from chemically modified starches (crosslinked, stabilized, crosslinked and stabilized on the stability and rheological properties of model oil-in-water (o/w emulsions. Based on the obtained results, it was concluded that emulsion stability depended on hydrolysates dextrose equivalent (DE value. Maltodextrin with the lowest degree of depolymerization effectively stabilized the dispersed system, and the effectiveness of this action depended on the maltodextrin type and concentration. Addition of distarch phosphate-based maltodextrin stabilized emulsion at the lowest applied concentration, and the least effective was maltodextrin prepared from acetylated starch. Emulsions stabilized by maltodextrins (DE 6 prepared from distarch phosphate and acetylated distarch adipate showed the predominance of the elastic properties over the viscous ones. Only emulsion stabilized by maltodextrin prepared from distarch phosphate (E1412 revealed the properties of strong gel. Additionally, the decrease in emulsions G′ and G″ moduli values, combined with an increase in the value of DE maltodextrins, was observed.

  14. Effect of extraction methods on the stability of benniseed oil from ...

    African Journals Online (AJOL)

    , 3.06mg KOH/g and 6.02mg KOH/g for the oil expeller, mechanical press and solvent freshly extracted oil samples respectively. The corresponding peroxide values were 1.47mg eq/g, 2.14mg eq/g and 2.89mg eq/g. The FFA for the oils after 4 ...

  15. Effect of the phytochemicals curcumin, cinnamaldehyde, thymol and carvacrol on the oxidative stability of corn and palm oils at frying temperatures.

    Science.gov (United States)

    İnanç Horuz, Tuğba; Maskan, Medeni

    2015-12-01

    Several active components naturally available in plants are strongly considered as good antioxidants to retard the lipid oxidation. Response surface methodology was used to investigate the effects of frying temperature (150-180 °C) and concentration of four plant-based active components (60-350 mg/kg oil); curcumin, cinnamaldehyde, thymol and carvacrol on oxidative stability of corn and palm oils. According to induction time values, the stability of oils drastically decreased with increasing temperature. Curcumin and cinnamaldehyde showed no significant effect (p > 0.05) on both oils. Carvacrol significantly increased induction times of corn and palm oils, but thymol was effective in palm oil only (p frying experiment was carried out with only corn oil to confirm efficiency of carvacrol. The free fatty acid (%), peroxide value (meq/kg), para-anisidine, and total polar component values (%) of the fresh oil were 0.080, 2.55, 2.85, and 7.5, respectively. These values changed to 0.144, 1.47, 12.01, 10.0, respectively for the control oil; 0.138, 2.27, 11.49, 10.0 for BHT-added oil; 0.132, 1.42, 5.66, 9.5 for carvacrol-added oil after 30 frying cycles. Therefore, carvacrol could be considered as a good alternative to BHT for preservation of oils at frying temperatures.

  16. Oxidative Stability of Granola Bars Enriched with Multilayered Fish Oil Emulsion in the Presence of Novel Brown Seaweed Based Antioxidants.

    Science.gov (United States)

    Hermund, Ditte B; Karadağ, Ayşe; Andersen, Ulf; Jónsdóttir, Rósa; Kristinsson, Hordur G; Alasalvar, Cesarettin; Jacobsen, Charlotte

    2016-11-09

    Fucus vesiculosus extracts that have both radical scavenging activity and metal chelating ability in vitro were used as natural antioxidant in granola bars enriched with fish oil emulsion by using primary and secondary emulsion systems stabilized by sodium caseinate alone and sodium caseinate-chitosan. The bars were stored at 20 °C and evaluated over a period of 10 weeks by measuring the development of primary and secondary oxidation products. The samples prepared with secondary emulsion system developed less oxidation products probably due to increased interfacial layer thickness that would act as a barrier to the penetration and diffusion of molecular species that promote oxidation. The positive charge of oil droplets in the secondary emulsion may also inhibit iron-lipid interaction through electrostatic repulsion. Additional protection against lipid oxidation was obtained when fish oil emulsions were added to the granola bars especially in combination with acetone and ethanol extracts of Fucus vesiculosus.

  17. Geopolitics of oil markets

    International Nuclear Information System (INIS)

    Liscom, W.L.

    1991-01-01

    Geopolitics can inject a great deal of uncertainty and cause fundamental shifts in the overall direction of oil markets, which would otherwise act in a fairly predictable and stable manner. The Iraqi invasion of Kuwait and the response of the USA were definitely linked with oil, and the aftermath of the invasion left four geopolitical issues affecting world oil markets. The provision authorizing $1.6 billion in Iraqi oil exports under the United Nations sanctions was imposed with little concern about the potential impact of these exports on the oil market; Iraq could export as much as 1 million bbl/d and it is unlikely that exports would be stopped once the $1.6 billion limit is reached. By making up most of the supply shortfall during the Kuwait crisis, Saudi Arabia suddenly became the producer of over a third of OPEC oil supplies and now dominates OPEC. The Saudis have indicated it will swing production according to world demand, irrespective of what OPEC wants, so that world oil demand will return strongly and remain. Middle East politics in general will determine the stability of oil supplies in the region for many of the countries. A producer-consumer dialogue at the high governmental level has started, with a view to some type of multilateral understanding in the light of mutual interests in secure oil supplies. This is not likely to have a big impact on oil markets without participation and support from the USA. The recent changes in the Soviet Union have potential impacts in regard to the attraction of that market for Western investment, in particular to assist exports. The worldwide environmental movement will also play a geopolitical role in the world oil market due to its influence on oil taxation policies

  18. The future world oil market: state of nature or social contract?

    Energy Technology Data Exchange (ETDEWEB)

    Noel, P

    1999-10-01

    Mary Ann Tetreault develops a very interesting interpretation of the emerging new relationship between international oil companies and Middle East producing countries. The original intellectual tools she handles-concepts drawn from the European political philosophy tradition-allow her to argue as follows: (1) the oil market left to itself- whether participants are states or firms-behaves like a Hobbesian ''state of nature'' often resulting in a situation damaging to each participant; (2) to deal with it, the international oil community has historically relied on different types of organisations, but these social contracts or ''republics'' were inherently unstable since they rested on too narrowly defined interests; (3) the rationale behind the possible return of oil companies to the richest Middle East countries is the search for new ''international oil republics'' able to ''offer greater security and higher profits for all the good republicans among them''. (author)

  19. Physicochemical characteristics, thermal stability and antioxidant characteristics of Trichosanthes kirilowii maxim seed oil as affected by different extraction methods

    Directory of Open Access Journals (Sweden)

    Z. K. Hou

    2017-09-01

    Full Text Available In conducting this study, the extraction of Trichosanthes kirilowii maxim seed oils (TSO was carried out with the help of cold pressing (CP, hot pressing (HP and soxhlet extraction (SE. Investigation, together with comparison, was carried out with respect to the physicochemical properties, thermal stability and antioxidant action of TSO. The key ingredients in the seeds consisted of fat, fiber and protein. The physicochemical characteristics of the oils brought to light the fact that CPTSO possessed top oil quality. The findings also suggested that linoleic acid, punicic acid and oleic acid were the leading unsaturated fatty acids in TSO. It was also discovered that TSO had an almost identical chemical composition regardless of the extraction method was used. It was demonstrated by TG/DTG curves that both HPTSO and CPTSO had more thermal stability in comparison with SETSO. Furthermore, the antioxidant activity assessments emphasized that CPTSO had better radical scavenging potential. CP had the ability to deliver an extract with higher quality as well as antioxidant activity in comparison with HP and SE methods and can be taken into consideration as a more suitable method in order to attain high quality oil.

  20. Safety, Security, and Stability: The Role of Nuclear Control Regimes in a Proliferated World

    National Research Council Canada - National Science Library

    Collins, James

    1995-01-01

    ... with developing and deploying nuclear weapons. The US, in the past, has refused to provide technical assistance to enhance the safety, security, and stability of proliferating countries' nuclear arsenals-we believe this policy...

  1. Combination of sodium caseinate and succinylated alginate improved stability of high fat fish oil-in-water emulsions.

    Science.gov (United States)

    Yesiltas, Betül; Sørensen, Ann-Dorit Moltke; García-Moreno, Pedro J; Anankanbil, Sampson; Guo, Zheng; Jacobsen, Charlotte

    2018-07-30

    Sodium caseinate (CAS) and commercial sodium alginate (CA), long chain modified alginate (LCMA) or short chain modified alginate (SCMA) were used in combination for emulsifying and stabilizing high fat (50-70%) fish oil-in-water emulsions. Physical (creaming, droplet size, viscosity and protein determination) and oxidative (primary and secondary oxidation products) stabilities of the emulsions were studied during 12 days of storage. Creaming stability was higher for emulsions produced with alginates and CAS compared to emulsions prepared with only CAS. Combined use of CAS + LCMA performed better in terms of physical stability compared to emulsions produced with only CAS. However, the oxidative stability of this emulsion was inferior probably due to the presence of an unsaturated carbon chain in LCMA structure. CAS + SCMA emulsions not only showed better physical stability such as smaller droplet size, lower creaming and higher viscosity, but also had an improved oxidative stability than emulsions produced with only CAS. Copyright © 2018 Elsevier Ltd. All rights reserved.

  2. Elucidation of stabilizing oil-in-water Pickering emulsion with different modified maize starch-based nanoparticles.

    Science.gov (United States)

    Ye, Fan; Miao, Ming; Jiang, Bo; Campanella, Osvaldo H; Jin, Zhengyu; Zhang, Tao

    2017-08-15

    The aim of present study was to study the medium-chain triacylglycerol-in-water (O/W) Pickering emulsion stabilized using different modified starch-based nanoparticles (octenylsuccinylation treated soluble starch nanoparticle, OSA-SSNP, and insoluble starch nanoparticle, ISNP). The major factors for affecting the system stability, rheological behaviour and microstructure of the emulsions were also investigated. The parameters of the O/W emulsions stabilized by OSA-SSNP or ISNP were selected as follows: 3.0% of starch nanoparticles concentration, 50% of MCT fraction and 7.0 of system pH. The rheological properties indicated that both emulsions displayed shear-thinning behaviour as a non-Newtonian fluid. For OSA-SSNP, the viscosities of the emulsion were higher than those of ISNP throughout shear rate range for the same condition. The plot of droplet size distribution for emulsion stabilized OSA-SSNP appeared as a single narrow peak, whereas a broader droplet size distribution with bimodal pattern was observed for emulsion stabilized ISNP. The microscopy results showed that both OSA-SSNP and ISNP were adsorbed at oil-water interface to form a barrier film and retard the phase separation. When emulsion was stored for 30d, no phase separation was detected for O/W emulsion, revealing high stability of emulsion stabilized by both OSA-SSNP and ISNP. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. The domestic natural gas and oil initiative. Energy leadership in the world economy

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-01

    Two key overarching goals of this Initiative are enhancing the efficiency and competitiveness of U.S. industry and reducing the trends toward higher imports. These goals take into account new Federal policies that reflect economic needs, including economic growth, deficit reduction, job creation and security, and global competitiveness, as well as the need to preserve the environment, improve energy efficiency, and provide for national security. The success of this Initiative clearly requires coordinated strategies that range far beyond policies primarily directed at natural gas and oil supplies. Therefore, this Initiative proposes three major strategic activities: Strategic Activity 1 -- increase domestic natural gas and oil production and environmental protection by advancing and disseminating new exploration, production, and refining technologies; Strategic Activity 2 -- stimulate markets for natural gas and natural-gas-derived products, including their use as substitutes for imported oil where feasible; and Strategic Activity 3 -- ensure cost-effective environmental protection by streamlining and improving government communication, decision making, and regulation. Finally, the Initiative will reexamine the costs and benefits of increase oil imports through a broad new Department of Energy study. This study will form the basis for additional actions found to be warranted under the study.

  4. Effect of Gradual Heating and Fat/Oil Type on Fat Stability, Texture, Color, and Microstructure of Meat Batters.

    Science.gov (United States)

    Barbut, S; Youssef, M K

    2016-09-01

    The effects of endpoint cooking temperature (40, 50, 60, 70, 80, and 90 °C) on emulsion stability, texture, color, and microstructure of meat batters prepared with different fats/oils were studied. Canola oil treatments showed the highest cooking loss whereas hydrogenated palm oil provided the most stable meat batters. Rendered beef fat was less stable than regular beef fat. Increasing endpoint cooking temperatures resulted in a progressive reduction of water holding capacity in all treatments. As temperature was raised, meat batters showed higher hardness and cohesiveness values, but no appreciable changes in cohesiveness above 60 °C. Canola and hydrogenated palm oil treatments showed the highest hardness and chewiness values. Lightness (L(*) ) values of all meat batters increased significantly with increasing temperature from 40 to 60 or 70 °C; no major changes observed above 70 °C. Light microscopy revealed no substantial changes in the microstructure of all the stable meat batters cooked to between 50 and 70 °C. Heating to 90 °C changed the microstructure in all meat batters except the hydrogenated palm oil treatments, which still showed nonround fat particles and a less aggregated protein matrix. © 2016 Institute of Food Technologists®

  5. Bio-oil Hydrotreatment for Enhancing Solubility in Biodiesel and the Oxydation Stability of Resulting Blends

    Science.gov (United States)

    Botella, Lucía; Stankovikj, Filip; Sánchez, José L.; Gonzalo, Alberto; Arauzo, Jesús; Garcia-Pérez, Manuel

    2018-04-01

    The major challenge for the pyrolytic conversion of lignocellulosic materials into crude bio-oil is the poor quality of the final product. Several strategies (addition of solvents, production of emulsions, and extraction with biodiesel) have been studied to improve its fuel properties. The extraction with biodiesel is an interesting solution because it allows direct utilization of some bio-oil fractions as fuels. However, fraction extracted with biodiesel is typically between 10 and 18 wt. %. In this paper we studied mild hydrotreatment of pyrolysis oil to enhance its solubility in biodiesel. The study was conducted with BTG and Amaron oils hydrotreated at temperatures between 200 and 325 °C in the presence of Ru/C catalyst. Hydrotreated oils generated three phases: top oil (light hydrocarbons), middle aqueous phase and bottom heavy oil phase. Each of the phases was characterized and the content of acetic acid, phenols, aromatic compounds and linear alkane hydrocarbons quantified. The upgraded bio-oils were more soluble in biodiesel than the crude bio-oils, obtaining blends with up to 48 and 38 wt. % for the BTG and Amaron bio-oil, respectively. Some of the fuel properties of the resulting blends are also reported here.

  6. Thermal and physico-mechanical stability of recycled high density polyethylene reinforced with oil palm fibres

    Directory of Open Access Journals (Sweden)

    R.O. Medupin

    2017-12-01

    Full Text Available The impressive physical and mechanical properties achievable with organic fillers make them a good choice for polymer composite reinforcement. In this study, oil palm fibres (OPF, often hardly thought of as having any reasonable economic value in developing economy was used as reinforcing fillers in recycled high density polyethylene (rHDPE. Thermal behaviour, physical and mechanical stability of rHDPE filled with OPF have been studied. Fourier Transform Infrared Spectroscopy (FTIR results present band spectra characteristic of OH stretching vibration in the cellulose of the fibre material. The absorption bands of the spectra are attributed to the presence of stretching vibration of CO group mostly found in the form of hemicelluloses and lignin structure in the fibre. Upon examination of the test specimens produced through compression moulding technique, it was found that the addition of OPF (filler into rHDPE (matrix increased the composites’ water absorption rate linearly for the first 16 days of exposure to the water environment. Stability was achieved for all the materials after this period. Thermal studies of the various compositions (OPF/rHDPE: 5/95, 10/90, 15/85, 20/80 and 25/75 using derivative thermogravimetric analysis (DTGA showed two main degradation peaks at 490 °C and 380 °C. The mechanical study revealed that the composite with 20 wt% filler contents was the most eco-friendly and had the best mechanical properties while that with 25 wt% was the most thermally stable. This material was thermally stable up to approximately 330 °C. Microstructure examination of the different components of the composites further explains the reason for good physical and mechanical strength of the sample with 20 wt% filler. It can, therefore, be inferred from the results of the various analyses conducted that OPF is a good reinforcing phase for rHDPE and a potential material for construction and automotive industries.

  7. Assessment of the antioxidant activity of Bifurcaria bifurcata aqueous extract on canola oil. Effect of extract concentration on the oxidation stability and volatile compound generation during oil storage.

    Science.gov (United States)

    Agregán, Rubén; Lorenzo, José M; Munekata, Paulo E S; Dominguez, Ruben; Carballo, Javier; Franco, Daniel

    2017-09-01

    In this research the antioxidant activity of water extracts of Bifurcaria bifurcata (BBE) at different dose against butylated hydroxytoluene (BHT) was evaluated in canola oil. Water extracts were firstly characterized in terms of total solid and polyphenolic compound contents, and their antioxidant activity together with that of BHT was evaluated using several in vitro tests (DPPH, ABTS, ORAC and FRAP). Next, the progress of lipid oxidation was assessed in canola oil added with five BBE concentrations (200, 400, 600, 800 and 1000ppm) and two BHT concentrations (50 and 200ppm) using an accelerated oxidation test. The progress in lipid oxidation was monitored by assessing some chemical indices (peroxide value, p-anisidine value, and conjugated dienes) during oil storage and some volatile compounds at the end of the storage period. BBE showed a significant antioxidant effect, being this ability concentration-dependent. The extent of lipid oxidation was inversely related to BBE dose, specially with regard to primary oxidation products. At the highest level of BBE, significant decreases of primary and secondary oxidation products, with respect to the control, were obtained with reduction percentages of 71.53%, 72.78%, 68.17% and 71.3% for peroxides, conjugated dienes, p-anisidine and TOTOX values, respectively. A level of 600ppm or higher concentration of the extract inhibits the lipid oxidation in a similar way than BHT at 200ppm. Regarding the inhibition of the formation of volatile compounds, both BBE and BHT strongly inhibited the formation of volatiles during oil storage, being this inhibition similar for all the concentrations of BBE and BHT essayed. Overall, results indicated that BBE can be used as a potential natural additive for improving oxidative stability of canola oil. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. World

    Science.gov (United States)

    Kilinc, M.; Beringer, J.; Hutley, L.; Kurioka, K.; Wood, S.; D'Argent, N.; Martin, D.; McHugh, I.; Tapper, N.; McGuire, D.

    2009-04-01

    Natural forests store vast amounts of carbon in the terrestrial biosphere, and play an important role in the global carbon cycle. Given the significance of natural forests, there is a lack of carbon accounting of primary forests that are undisturbed by human activities. One reason for this lack of interest stems from ecological orthodoxy that suggests that primary forests should be close to dynamic equilibrium, in that Net Ecosystem Production (NEP) approaches zero. However, recent results from the northern hemisphere and tropics, using eddy covariance flux towers, indicate that primary forests are a greater sink than first thought. The role of evergreen primary forests in Australian carbon balance studies remain uncertain and hence may function differently to their deciduous counterparts in the Northern Hemisphere. In order to address the lack of baseline carbon accounts, an undisturbed, 300 year old Mountain Ash (Eucalyptus regnans) ecosystem, located in the Central Highlands of Victoria (Australia) was selected as a permanent study site to investigate carbon and water budgets over diurnal, seasonal and annual cycles. Mountain Ash trees are the world's tallest angiosperms (flowering plants), and one of the largest carbon reservoirs in the biosphere, with an estimated 1900 tC ha-1. A 110 m tall micrometeorological tower that includes eddy covariance instrumentation was installed in August 2005. An independent biometric approach quantifying the annual net gain or loss of carbon was also made within close proximity to the flux tower. Analysis of NEP in 2006 suggests that the ecosystem acted as a carbon sink of 2.5 tC ha-1 yr-1. Woody and soil biomass increment for the same year was estimated to be 2.8 tC ha-1yr-1, in which nearly half of the biomass production was partitioned into the aboveground woody tissue. These results indicate that temperate primary forests act as carbon sinks, and are able to maintain their carbon sink status due to their uneven stand

  9. Impact of Environmental Stresses on Orange Oil-in-Water Emulsions Stabilized by Sucrose Monopalmitate and Lysolecithin.

    Science.gov (United States)

    McClements, David Julian; Decker, Eric Andrew; Choi, Seung Jun

    2014-04-09

    The food and beverage industry is trying to replace synthetic functional ingredients with more "label-friendly" ingredients in many commercial products. This study therefore examined the influence of environmental stresses on the stability of emulsions stabilized by a combination of lysolecithin and sucrose monopalmitate (SMP). Orange oil-in-water emulsions (5% (w/w) oil) stabilized by SMP (1%) and lysolecithin (0-0.5%) were prepared using high-pressure homogenization (pH 3). In the absence of lysolecithin, all emulsions were highly unstable to droplet aggregation, which was attributed to low droplet charge (weak electrostatic repulsion) and small SMP headgroup size (weak steric repulsion). Incorporation of 0.1-0.5% lysolecithin into the emulsions greatly improved their stability to droplet aggregation, which was mainly attributed to the increase in negative charge on the droplets (strong electrostatic repulsion). The addition of high levels of salt (NaCl) to the emulsions promoted droplet aggregation and creaming. Emulsions containing 0.5% lysolecithin were stable to heating (30-90 °C) in the absence of salt, but exhibited droplet aggregation and creaming when held at high (>50 °C) temperatures in the presence of 300 mM salt. This study has implications for the development of emulsion-based delivery systems for use in food and beverage products.

  10. Impact of Endogenous Phenolics in Canola Oil on the Oxidative Stability of Oil-in-Water Emulsions

    DEFF Research Database (Denmark)

    Sørensen, Ann-Dorit Moltke; Friel, James; Moser, Jill

    , the effect of these endogenous antioxidants on lipid oxidation in o/w emulsion is yet unknown. Hence, the aim of this study was to evaluate the effect of the endogenous phenolics in Canola oil on lipid oxidation in o/w emulsion. For this purpose individual phenolics were extracted from defatted grinded...... Value (PV) and secondary volatile oxidation products by headspace GC supported by evaluation of the properties of the extracts and corresponding phenolic standards in 3 different in vitro antioxidant assays....... antioxidants will result in increased shelf life and thereby increased quality of the food products. Besides tocopherols, Canola oil contains different compounds with antioxidative properties. These compounds are Sinapic acid, Sinapine and Canolol; all belonging to the group of phenolic compounds. However...

  11. Effect of cumin essential oil usage on fermentation quality, aerobic stability and in vitro digetibility of alfalfa silage.

    Science.gov (United States)

    Turan, Aslı; Önenç, Sibel Soycan

    2018-03-02

    This study was carried out to determine the effects of cumin essential oil on the silage fermentation, aerobic stability and in vitro digestibility of alfalfa silages. Alfalfa was harvested at early bloom (5 th cutting) stage in October and wilted for about 3 hours. The research was carried out at three groups which were the control group where no additive control was done (CON), cumin essential oil (CMN3) with 300 mg/kg and CMN5 with 500 mg/kg cumin essential oil addition. Alfalfa was ensiled in plastic bags. The packages were stored at 8±2 °C under laboratory conditions. All groups were sampled for physical, chemical and microbiological analysis 120th day after ensiling. At the end of the ensiling period, all silages were subjected to an aerobic stability test for 7 days. In addition, enzimatic solubility of organic matter (ESOM), metabolizable energy (ME) and relative feed value (RFV) of these silages were determined. pH level decreased in the cumin groups compared to CON (P<0.05), thus inhibiting proteolytic enzymes from breaking down proteins into ammonia. In addition, it increased ESOM amount, and concordantly provided an increase of ME contents. Similarly, dry matter intake (DMI) and RFV ratio increased. After opening the silage, it kept its aerobic stability for three days. Cumin essential oil improved fermentation, and affected chemical and microbiological characteristics of silages. Especially the addition of 300 mg/kg cumin provided cell wall fractionation through stimulating the activities of enzymes responsible. It also increased the number and activity of lactic acid bacteri (LAB) through providing a development of LAB.

  12. The end of oil: on the edge of a perilous new world

    National Research Council Canada - National Science Library

    Roberts, Paul

    2004-01-01

    Petroleum is now so deeply entrenched in our economy, our politics, and our personal expectations that even modest efforts to phase it out are fought tooth and nail by the most powerful forces in the world...

  13. World oil and gas markets in 2005; Les marches petroliers et gaziers mondiaux en 2005

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-01-15

    In front of insufficient production capacities, the petroleum and gas spot prices have won historical records in 2005. This paper analyzes this situation using the highlights of this exceptional year and concerning the producing countries (political situation), the oil and gas markets (exchange rates, demand, production capacity), the European quotations of petroleum products (automotive and domestic fuels), and the prices of petroleum products in France. (J.S.)

  14. Green synthesis of stabilized spherical shaped gold nanoparticles using novel aqueous Elaeis guineensis (oil palm) leaves extract

    Science.gov (United States)

    Ahmad, Tausif; Bustam, Mohamad Azmi; Irfan, Muhammad; Moniruzzaman, Muhammad; Anwaar Asghar, Hafiz Muhammad; Bhattacharjee, Sekhar

    2018-05-01

    In the last decade, development of bioinspired protocols to synthesize gold nanoparticles (AuNPs) using plants and their extracts have been dealt by researchers due to their low cost, renewability and non-toxic features. A simple, cheap and ecofriendly method is reported to synthesize stabilized AuNPs of size 35-75 nm at room temperature using aqueous Elaeis guineensis (oil palm) leaves extract without addition of any external agent. Oil palm leaves mediated AuNPs were characterized using FTIR, UV-vis spectrophotometer, EDAX, XPS, FESEM, TEM, DLS and TGA. FTIR spectra results revealed contribution of phenolic, carboxylic, amines and amides in reduction of trivalent gold ions and stabilization of formed gold atoms. Reaction solution color change and UV-vis spectra confirmed reduction of gold ions to generate gold atoms. Reaction mechanism explained the role of phenolic compounds in reduction reaction using FTIR and UV-vis spectra results. EDAX and XPS results further validated the formation of metallic gold particles through bioreduction of gold ions. Crystal structure of metallic gold particles was confirmed through XRD peaks indexing to (111), (200), (220) and (311) planes. TEM and FESEM particles size measurements exhibited the formation of nanostructured AuNPs. Synthesis of well scattered and spherical shaped AuNPs was revealed through FESEM and TEM images. The excellent stability of AuNPs was shown through high negative zeta potential value (-14.7 ± 4.68 mV) and uniform dispersion in aqueous media. Our results disclosed the excellent potential of Elaeis guineensis (oil palm) leaves as reducing and stabilizing agents in green synthesis of well scattered spherical shaped AuNPs, which can be employed as strong candidates in medical drug delivery and industrial applications.

  15. Effect of recovery methods on the oxidative and physical stability of oil body emulsions

    NARCIS (Netherlands)

    Karkani, O.A.; Nenadis, N.; Nikiforidis, K.; Kiosseoglou, V.

    2013-01-01

    Three natural oil body emulsions of a similar fat content (similar to 5%), but differing in their protein composition were obtained from an aqueous maize germ extract. The first was prepared by concentrating the aqueous oil body extract with ultrafiltration to a fat content of similar to 5%. The

  16. Oxidative stability and non-enzymatic browning reactions in Antarctic krill oil (Euphausia superba)

    DEFF Research Database (Denmark)

    Lu, Henna Fung Sieng; Bruheim, Inge; Jacobsen, Charlotte

    2014-01-01

    Antarctic krill oil has gained much consideration recently due to its rich content of eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) in the form of phospholipids and its powerful antioxidant known as astaxanthin. To secure these valuable bioactive nutrients in krill oil, a gentle...

  17. Application of Used Engine Oil in Soil-Cement Stabilization | Obeta ...

    African Journals Online (AJOL)

    A lot of studies has shown that the addition of oils to some soils at 3% and 6% contaminations by dry weight resulted in an increase in the unsoaked California bearing ratio (CBR) of the soil. This paper presents the result of investigating the applicability of used engine oil at 3% contamination as a means of reuse in the ...

  18. Stability to oxidation of spray-dried fish oil powder microencapsulated using milk ingredients

    DEFF Research Database (Denmark)

    Keogh, M.K.; O'Kennedy, B.T.; Kelly, J.

    2001-01-01

    Microencapsulation of fish oil was achieved by spray-drying homogenized emulsions of fish oil using 3 different types of casein as emulsifier and lactose as filler. As the degree of aggregation of the casein emulsifier increased, the vacuole volume of the microencapsulated powders decreased...

  19. Response of salt marshes to oiling from the Deepwater Horizon spill: Implications for plant growth, soil surface-erosion, and shoreline stability.

    Science.gov (United States)

    Lin, Qianxin; Mendelssohn, Irving A; Graham, Sean A; Hou, Aixin; Fleeger, John W; Deis, Donald R

    2016-07-01

    We investigated the initial impacts and post spill recovery of salt marshes over a 3.5-year period along northern Barataria Bay, LA, USA exposed to varying degrees of Deepwater Horizon oiling to determine the effects on shoreline-stabilizing vegetation and soil processes. In moderately oiled marshes, surface soil total petroleum hydrocarbon concentrations were ~70mgg(-1) nine months after the spill. Though initial impacts of moderate oiling were evident, Spartina alterniflora and Juncus roemerianus aboveground biomass and total live belowground biomass were equivalent to reference marshes within 24-30months post spill. In contrast, heavily oiled marsh plants did not fully recover from oiling with surface soil total petroleum hydrocarbon concentrations that exceeded 500mgg(-1) nine months after oiling. Initially, heavy oiling resulted in near complete plant mortality, and subsequent recovery of live aboveground biomass was only 50% of reference marshes 42months after the spill. Heavy oiling also changed the vegetation structure of shoreline marshes from a mixed Spartina-Juncus community to predominantly Spartina; live Spartina aboveground biomass recovered within 2-3years, however, Juncus showed no recovery. In addition, live belowground biomass (0-12cm) in heavily oiled marshes was reduced by 76% three and a half years after the spill. Detrimental effects of heavy oiling on marsh plants also corresponded with significantly lower soil shear strength, lower sedimentation rates, and higher vertical soil-surface erosion rates, thus potentially affecting shoreline salt marsh stability. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. Some Qualitative and Rheological Properties of Virgin Olive Oil- Apple Vinegar Salad Dressing Stabilized With Xanthan Gum.

    Science.gov (United States)

    Abedinzadeh, Solmaz; Torbati, Mohammadali; Azadmard-Damirchi, Sodeif

    2016-12-01

    Purpose: Lipid oxidation and rheological properties are the main qualitative parameters determined in food emulsions. Salad dressings are food emulsions important in our daily diet, but conventional salad dressings have high amounts of cholesterol and saturated fatty acids because of egg yolk in their formulations. There are many studies on the modification of salad dressing formulations to replace egg yolk and saturated fats. The present study describes new formulation of salad dressing with olive oil and apple vinegar to produce a functional food product. Methods: This study investigated the qualitative properties, oxidative stability, rheological behavior and microstructure of the salad dressing without egg yolk. Oil-in-water emulsions were prepared with virgin olive oil and apple vinegar stabilized with various percentages of xanthan (T1: 0.25%, T2: 0.5%. T3: 0.75%). Samples were stored at refrigerator for 90 days and experiments were performed at production day and during storage. Results: The obtained results showed that peroxide value was increased for all samples during storage, but it was at an acceptable level. Fatty acid changes were not significant during storage. Droplet size was reduced by increasing xanthan gum. T2 had the best rheological properties during storage. Generally, T2 and T3 had higher scores and were more acceptable in organoleptic assay. Conclusion: Obtained results showed that T 2 had suitable qualitative and rheological properties and can be a proper egg yolk free salad dressing to introduce to the market.

  1. Influence of the Rancimat parameters on the determination of oxidative stability index of Sesamum Indicum L. Oil

    Directory of Open Access Journals (Sweden)

    Eudes Villanueva López

    2013-09-01

    Full Text Available The objective of this research was to determine the oxidative stability index (OSI in virgin oil seed Sesamum indicum L. (Sesame previously extracted by cold pressing, clarified by centrifugation and stored under nitrogen atmosphere and cooling on. The OSI was determined by accelerated Rancimat test, it was used for 3.0 ± 0.1 g of sample temperature parameters (110, 130 and 150 °C and air flow (15, 20 and 25 L/h. Applying the Rancimat test, it was found by ANOVA (p < 0.05 that the influence of temperature on the OSI was highly significant, whereas the only air flow was significant. By extrapolation method, values were calculated at usual temperatures OSI oil storage (25 °C to give stability times 214, 242 and 222 days, also the activation energy of the oxidation reaction of sesame oil for different air flows, is 97.28, 98.79 and 96.86 kJ / mol for 15, 20 and 25 L/h respectively.

  2. Some Qualitative and Rheological Properties of Virgin Olive Oil- Apple Vinegar Salad Dressing Stabilized With Xanthan Gum

    Directory of Open Access Journals (Sweden)

    Solmaz Abedinzadeh

    2016-12-01

    Full Text Available Purpose: Lipid oxidation and rheological properties are the main qualitative parameters determined in food emulsions. Salad dressings are food emulsions important in our daily diet, but conventional salad dressings have high amounts of cholesterol and saturated fatty acids because of egg yolk in their formulations. There are many studies on the modification of salad dressing formulations to replace egg yolk and saturated fats. The present study describes new formulation of salad dressing with olive oil and apple vinegar to produce a functional food product. Methods: This study investigated the qualitative properties, oxidative stability, rheological behavior and microstructure of the salad dressing without egg yolk. Oil-in-water emulsions were prepared with virgin olive oil and apple vinegar stabilized with various percentages of xanthan (T1: 0.25%, T2: 0.5%. T3: 0.75%. Samples were stored at refrigerator for 90 days and experiments were performed at production day and during storage. Results: The obtained results showed that peroxide value was increased for all samples during storage, but it was at an acceptable level. Fatty acid changes were not significant during storage. Droplet size was reduced by increasing xanthan gum. T2 had the best rheological properties during storage. Generally, T2 and T3 had higher scores and were more acceptable in organoleptic assay. Conclusion: Obtained results showed that T2 had suitable qualitative and rheological properties and can be a proper egg yolk free salad dressing to introduce to the market.

  3. Wheat bran extracts: a potent source of natural antioxidants for the stabilization of canola oil

    Directory of Open Access Journals (Sweden)

    Shahid Chatha, Shahzad Ali

    2011-06-01

    Full Text Available In the present work, the antioxidant activity of different solvent extracts of wheat (var. Inqalab 91 bran was evaluated following different antioxidant assays using canola oil as the oxidation substrate. The bran samples were extracted with 80% and 100% methanol and acetone. A preliminary assessment of the antioxidant activity of the 80 and 100% acetone and methanolic extracts of wheat bran was done by the measurement of % inhibition of peroxidation in a linoleic acid system, total phenolic contents (TPC and bleachability of β-carotene in the linoleic acid system. Additionally, the canola oil samples were stabilized with crude concentrated extracts and subjected to ambient aging (6 months. The extent of oxidative deterioration was followed by the measurement of peroxide-, p-anisidine-, conjugated dienes-, and trienes- values. The results of ambient stored samples revealed a significant improvement in these oxidation parameters. The overall order of antioxidant activity of the extracts as determined by various antioxidant assays was determined to be; 80% methanolic extract > 100% methanolic extract > 80% acetone extracts . 100% acetone extract. The results of the present comprehensive analysis demonstrate that extracts of the wheat bran indigenous to Pakistan are a viable source of natural antioxidants and might be exploited for commercial and neutraceutical applications.

    En el presente trabajo la actividad antioxidante de diferentes extractos obtenidos con disolventes del salvado de trigo (var. Inqalab 91 fue evaluada mediante diferentes ensayos antioxidantes y aceite de canola como substrato de oxidación. Las muestras de salvado fueron extraídas con metanol y acetona al 80% y al 100%. La evaluación preliminar de la actividad antioxidante de los extractos de metanol y de acetona al 80% y 100% fue hecha mediante la medida del % de inhibición de la peroxidación en un sistema con ácido linoleico, el contenido total de fenoles

  4. The world energy demand in 2006: Confirmed increase in energy consumptions in a context of soaring crude oil prices; but economic growth is twice faster - June, 10 2007

    International Nuclear Information System (INIS)

    Chateau, Bertrand

    2007-01-01

    Confirmed increase in energy consumptions in a context of soaring crude oil prices; but economic growth is twice faster. According to the latest estimates by Enerdata, The world energy demand growth remains sustained in 2006, but twice slower than the GDP's growth, probably due to high energy prices on the international market. Oil: The oil demand, very captive, confirms once again its low elasticity to prices. 71% of the world oil product demand is concentrated on transport and petro-chemical sectors (77% in Europe, +13 points since 1990; 89% in North America). Gas/Electricity: Gas demand growth in 2006 is driven by Asia and the CIS, obvious price effects in the European Union. The CIS regains its position in the world production growth (22% in 2006 against 13% in 2005 and 33% in 2004). The power generation growth is more and more dominated by China and other Asian countries. The world electricity demand increases in the same proportions as in 2005 and 2004: 4%/year. Coal: Coal accounts for half of the world increase in energy consumption in 2006. China still accounts for 72% of the coal consumption, India for 10%, the rest of Asia 8% the rest of the world 10%. (authors)

  5. The tocol content of crude palm oil based on the level ripeness and their relationship to the quality and their stability

    Science.gov (United States)

    Rangkuti, I. U. P.; Julianti, E.; Elisabeth, J.

    2018-02-01

    Palm oil contain tocol and betacarotene which has an antioxidant function to protect the oil from oxidation processPalm oil comes from different maturity have not been specifically determined their tocol and betacarotene content, and their relation to quality and stability. The purpose of this research was to find the content of tokol and betacarotene in palm oil which comes from different maturity and to determine its stability of quality. The level of maturity was fraction 1 (unripe), fraction 2 and fraction 3 (ripe), fraction 4 (over-ripe).The result showed that palm oil which comes from different level of maturity from fraction 1, 2, 3 and 4 contained different amount of tocol and betacarotene. The quality of crude palm oil which were analysed by the value deteoriation of bleachability index (DOBI) had closed relationship to the number of beta-carotene in the palm oil. The color stability and oxidation were different in every level of maturity. The level of maturity which had the best quality and its stability was fraction 3. The tokol and betacarotene compound were 346 ppm and 727 ppm respectively, while the DOBI value was 2,75.

  6. Contribution of the Ratio of Tocopherol Homologs to the Oxidative Stability of Commercial Vegetable Oils

    Directory of Open Access Journals (Sweden)

    Mathias Zaunschirm

    2018-01-01

    Full Text Available The antioxidant activity of tocopherols in vegetable oils was shown to chiefly depend on the amount and the tocopherol homolog present. However, the most effective ratio of tocopherol homologs with regard to the antioxidant capacity has not been elucidated so far. The present study analyzed the effect of different tocopherol concentrations, homologs and ratios of homologs on markers of lipid oxidation in the most commonly consumed vegetable oils (canola, sunflower, soybean oil stored in a 12 h light/dark cycle at 22 ± 2 °C for 56 days under retail/household conditions. After 56 days of storage, the α-tocopherol-rich canola and sunflower oil showed the strongest rise in lipid peroxides, yielding 25.1 ± 0.03 meq O2/kg (+25.3-fold and 24.7 ± 0.05 meq O2/kg (+25.0-fold, respectively. ESR experiments, excluding effects of the oils’ matrices and other minor constituents, confirmed that a food representative tocopherol ratio of (γ + δ/α = 4.77, as represented in soybean oil, led to a more pronounced delay of lipid oxidation than a lower ratio in canola (1.39 and sunflower oil (0.06. An optimum (γ + δ/α -tocopherol ratio contributing to the oxidative quality of vegetable oils extending their shelf life has to be investigated.

  7. Chemical characterization and oxidative stability of seeds and oil of sesame grown in Morocco

    Directory of Open Access Journals (Sweden)

    S. Gharby

    2017-04-01

    Full Text Available The objective of this research work was to determine the characteristic features of the oil content and composition of nutrients of sesame seeds grown in Morocco. Characteristic features of the seed oil revealed a high degree of unsaturation and as determined by gas chromatography reported herein, the major unsaturated fatty acids were linoleic acid (46.9% followed by oleic acid (37.4%, while the main saturated fatty acid was palmitic acid (9.1%. Sesame seed oil was also found to be rich in tocopherols with a predominance of γ-tocopherol (90.5%. The phytosterol marker β-sitosterol accounted for 59.9% of total sterols contained in sesame seed oil. This oil, therefore, has a potential for its use in human nutrition or industrial applications. Compositional analysis revealed that the sesame seeds contained considerable amounts of protein (22% and high amounts of lipids (52%. Nutrient information reported herein illustrates the benefits to public health for consumers of these plant seeds. In terms of oil, sesame seed oil may be considered as a valuable source for new multi-purpose products as industrial, cosmetic, and pharmaceutical uses.

  8. Physicochemical characterization and oxidative stability of fish oil-loaded electrosprayed capsules: Combined use of whey protein and carbohydrates as wall materials

    DEFF Research Database (Denmark)

    García Moreno, Pedro Jesús; Pelayo, Andres; Yu, Sen

    2018-01-01

    The encapsulation of fish oil in electrosprayed capsules using whey protein and carbohydrates (pullulan and dextran or glucose syrup) mixtures as glassy wall materials was studied. Capsules with fish oil emulsified by using only a rotor-stator emulsification exhibited higher oxidative stability.......9 ± 0.4 meq/kg oil and 1-penten-3-ol of 1161.0 ± 222.0 ng/g oil). This finding may be attributed to differences in oxygen permeability between both types of capsules. These results indicated the potential of both combinations of whey protein, pullulan, and dextran or glucose syrup as shell materials...

  9. OPEC and the world oil prices: Is the genie back in the bottle

    International Nuclear Information System (INIS)

    Griffin, J.M.

    1992-01-01

    After reviewing and analyzing OPEC's behavior in the past two decades, a simulation model is employed to explore plausible paths for oil prices. OPEC's members are subdivided into analytically convenient maximizing groups. Lener index analysis is applied to measure observed market power and the potential monopoly power for the cartel core. Price paths for the 1990s under alternative OPEC configurations are presented, and it is suggested that the return to monopolization is large. Price levels of the 1970s were not sustainable even with a perfectly disciplined cartel core. Long run supply and demand elasticities were much greater than OPEC expected. Even though cheating contributed to OPEC's predicament in the 1980s, the primary determinant of oil price decline was external market forces. Future price instability is possible for both political and economic reasons, with a likely scenario of prices oscillating around the cartel core's optimum price path that features prices in the present range rising moderately. 8 refs., 6 tabs., 3 figs

  10. Trace Mineral Sources and Rosemary Oil in the Diet of Brown Laying Hens: Egg Quality and Lipid Stability

    Directory of Open Access Journals (Sweden)

    NR Batista

    Full Text Available ABSTRACT Two experiments were carried out to evaluate the effects of rosemary oil (RO and trace mineral sources (MS on the internal quality and lipid stability of brown layer eggs. The treatments consisted of diets supplemented with two trace mineral sources (inorganic or organic and three levels (0, 100, or 200 mg kg-1 of rosemary oil (RO, and three egg storage times. Eggs were stored at a controlled temperature (CT; 25.0ºC in Experiment I and under refrigeration (RT; 5.0ºC in Experiment II. The following parameters were analyzed on days 0 (fresh, 15 and 30 of storage: malonaldehyde level (MDA, egg weight (EW, Haugh unit (HU, yolk index (YI, albumen and yolk pH, raw yolk color (RYC, and egg weight loss. Data were analyzed according to completely randomized design in a 2x3x3 factorial arrangement (MS x RO x storage time. In Experiment I, there was an interaction between treatments for EW, HU and ALBp. Dietary OTM inclusion improved the results for all analyzed variables. The addition of 200 mg kg-1 RO reduced MDA and increased HU, YI and RYC. In experiment II, 200 mg kg-1 of RO in the diet improved HU. The internal quality of eggs stored both at CT and under RT is adversely affected by increasing storage periods, but this effect can be minimized by the dietary supplementation of OTM and 200 mg kg-1 rosemary oil. The lipid stability of eggs stored at CT improves with the supplementation of OTM and 200 mg kg-1 rosemary oil, but not of eggs stored under refrigeration.

  11. Stability of the graviton Bose–Einstein condensate in the brane-world

    Directory of Open Access Journals (Sweden)

    Roberto Casadio

    2016-12-01

    Full Text Available We consider a solution of the effective four-dimensional Einstein equations, obtained from the general relativistic Schwarzschild metric through the principle of Minimal Geometric Deformation (MGD. Since the brane tension can, in general, introduce new singularities on a relativistic Eötvös brane model in the MGD framework, we require the absence of observed singularities, in order to constrain the brane tension. We then study the corresponding Bose–Einstein condensate (BEC gravitational system and determine the critical stability region of BEC MGD stellar configurations. Finally, the critical stellar densities are shown to be related with critical points of the information entropy.

  12. Stability of the graviton Bose–Einstein condensate in the brane-world

    Energy Technology Data Exchange (ETDEWEB)

    Casadio, Roberto, E-mail: casadio@bo.infn.it [Dipartimento di Fisica e Astronomia, Università di Bologna, via Irnerio 46, 40126 Bologna (Italy); INFN, Sezione di Bologna, viale B. Pichat 6, 40127 Bologna (Italy); Rocha, Roldão da, E-mail: roldao.rocha@ufabc.edu.br [CMCC, Universidade Federal do ABC, 09210-580, Santo André, SP (Brazil)

    2016-12-10

    We consider a solution of the effective four-dimensional Einstein equations, obtained from the general relativistic Schwarzschild metric through the principle of Minimal Geometric Deformation (MGD). Since the brane tension can, in general, introduce new singularities on a relativistic Eötvös brane model in the MGD framework, we require the absence of observed singularities, in order to constrain the brane tension. We then study the corresponding Bose–Einstein condensate (BEC) gravitational system and determine the critical stability region of BEC MGD stellar configurations. Finally, the critical stellar densities are shown to be related with critical points of the information entropy.

  13. Effects of fish oil type, lipid antioxidants and presence of rapeseed oil on oxidative flavour stability of fish oil enriched milk

    DEFF Research Database (Denmark)

    Bruni Let, Mette; Jacobsen, Charlotte; Meyer, Anne S.

    2004-01-01

    mixture were oxidatively stable during 11 d at 2 øC. Thus, no additional inhibitory effect of the added antioxidants was observed. The peroxide value and concentrations of five selected volatiles derived from n- 3 PUFA degradation in rapeseed:fish oil mixture emulsions were not significantly different...

  14. Evaluation of antioxidant properties of Za'atar (Thymbra spicata) essential oils as natural antioxidant for stability of palm olein during deep-fat frying process.

    Science.gov (United States)

    Maskan, Medeni; Horuz, Erhan

    2017-06-01

    The yield of Za'atar ( Thymbra spicata ) essential oils were found to be 2.5-3.4% at extraction process temperatures of 100-175 °C. The essential oils contained 79.5-86.2% carvacrol. Effects of BHT and Za'atar essential oil on stability of palm olein during deep-fat frying of potato slices were studied at 180 °C. Changes in peroxide, para-anisidine, iodine values, free fatty acid and color were determined. Za'atar essential oil and BHT reduced free fatty acid content of olein from 0.27 to 0.21% (oleic acid) after 50 frying cycles. Antioxidant addition did not change the peroxide value of oil. Frying decreased Hunter L value and increased a , b , and total color difference values of used oils. The P -anisidine value changed from 15 to 33 for control oil during frying. BHT and Za'atar essential oil reduced this value to 28. The iodine values of olein reduced from an initial value of 54.5 to 45, 49 and 49 for control, BHT and Za'atar essential oil added frying oils, respectively. Za'atar essential oils could be used for preserving palm olein during deep-fat frying process.

  15. Chemical Characterization and Oxidative Stability of Medium- and Long-Chain Fatty Acid Profiles in Tree-Borne Seed Oils

    Directory of Open Access Journals (Sweden)

    Da-Som Kim

    2018-01-01

    Full Text Available This study was undertaken to evaluate chemical characteristics and oxidative stability of tree-borne seed oils. A total of 15 different fatty acids were identified in six tree-borne seed oils, which included seven types of saturated fatty acids, four types of monounsaturated fatty acids, and four types of polyunsaturated fatty acids. Japanese camphor tree (JCT had a high content of medium-chain fatty acids (97.94 ± 0.04%, in which fatty acid composition was distinct from those of the other five plant seed oils. Overall, contents of tocopherols, a type of fat-soluble vitamin, ranged between 3.82 ± 0.04 mg/100 g and 101.98 ± 1.34 mg/100 g, respectively. Phytosterol contents ranged from 117.77 ± 1.32 mg/100 g to 479.45 ± 4.27 mg/100 g, respectively. Of all tree-borne seed oils, β-sitosterol was the phytosterol at the highest concentration. Contents of unsaponifiables were between 0.13 ± 0.08 and 2.01 ± 0.02, and values of acid, peroxide, and p-anisidine were between 0.79 ± 0.01 and 38.94 ± 0.24 mg KOH/g, 3.53 ± 0.21 and 127.67 ± 1.79 meq/kg, and 2.07 ± 0.51 and 9.67 ± 0.25, respectively. Oxidative stability of tree-borne seed oils was assessed through measurement of oxidation-induction periods. These results should serve as a foundation to identify the potential of tree-borne seed oils in industrial application as well as in providing fundamental data.

  16. NEMS International Energy Module, model documentation report: World Oil Market, Petroleum Products Supply and Oxygenates Supply components

    Energy Technology Data Exchange (ETDEWEB)

    1994-04-04

    The Energy Information Administration (EIA) is developing the National Energy Modeling System (NEMS) to enhance its energy forecasting capabilities and to provide the Department of Energy with a comprehensive framework for analyzing alternative energy` futures. NEMS is designed with a multi-level modular structure that represents specific energy supply activities, conversion processes, and demand sectors as a series of self-contained units which are linked by an integrating mechanism. The NEMS International Energy Module (IEM) computes world oil prices and the resulting patterns of international trade in crude oil and refined products. This report is a reference document for energy analysts, model users, and the public that is intended to meet EIA`s legal obligation to provide adequate documentation for all statistical and forecast reports (Public Law 93-275, section 57(b)(1). Its purpose is to describe the structure of the IEM. Actual operation of the model is not discussed here. The report contains four sections summarizing the overall structure of the IEM and its interface with other NEMS modules, mathematical specifications of behavioral relationships, and data sources and estimation methods. Following a general description of the function and rationale of its key components, system and equation level information sufficient to permit independent evaluation of the model`s technical details is presented.

  17. Degradation and stabilization of coal derived liquid. (IV). ; Effect of alcohol on coloration of coal derived light oil. Sekitan ekikayu no anteika. (IV). ; Sekitan ekikayu no chakushoku yokusei ni oyobosu alcohol no tenka koka

    Energy Technology Data Exchange (ETDEWEB)

    Ukegawa, K.; Matsumura, A.; Kondo, T. (National Research Institute for Pollution and Resources, Tsukuba (Japan)); TAhara, N. (Nitto Denko Corp., Osaka (Japan)); Nakamura, E. (New Energy and Industrial Technology Development Organization, Tokyo (Japan)); Niki, E. (The University of Tokyo, Tokyo (Japan). Research Center for ADvanced Science and Technology)

    1990-01-20

    In order to improve the color stability of a coal derived light oil, the effect of hydrotreating and various additives has been studied. The color stability has been evaluated through measuring changes in absorbance by flow-cell spectrophotometer. Following results have been obtained: The color stabilities of hydrotreated coal derived light oils were improved remarkably with increasing hydrotreating temperature and pressure. Mild hydrotreating made the color stability of the coal derived light oil much better than the fuel oil, even though the nitrogen removal was very small. Phenolic compounds additives could not improve the color stability of the coal derived light oil. Alcohol, especially methanol, made the coloration rate of the coal derived light oil small to a great extent, on account of hydrogen bonding between methanol and nitrogen compounds in the fuel oil. 4 refs., 4 figs., 3 tabs.

  18. The last oil century? The truth about world reserves - a geologist's viewpoint; Le dernier siecle du petrole? La verite sur les reserves mondiales - le point de vue d'un geologue

    Energy Technology Data Exchange (ETDEWEB)

    Mathieu, Yves

    2010-11-01

    Will the 21. century be the on of world oil reserves exhaustion? This fear of an oil-less world is shared by all: politicians, oil company heads, scientific experts, economists and, above all, by consumers. The author, a geologist and renowned expert of the domain, answers this vital question and presents the real situation of oil reserves country by country. He also evaluates the potentialities offered by non-conventional oils (heavy crudes, tar sands and oil shales) as well as by this desertic and hostile area considered as the new energy eldorado: the Arctic. This specialist's book, accessible to everyone, approaches in a didactic way the different economical and political stakes linked with world oil reserves. This analysis raises the issue: how long could we count on oil at accessible cost to cover our energy needs? (J.S.)

  19. Ecology and Evolution in the RNA World Dynamics and Stability of Prebiotic Replicator Systems

    Directory of Open Access Journals (Sweden)

    András Szilágyi

    2017-11-01

    Full Text Available As of today, the most credible scientific paradigm pertaining to the origin of life on Earth is undoubtedly the RNA World scenario. It is built on the assumption that catalytically active replicators (most probably RNA-like macromolecules may have been responsible for booting up life almost four billion years ago. The many different incarnations of nucleotide sequence (string replicator models proposed recently are all attempts to explain on this basis how the genetic information transfer and the functional diversity of prebiotic replicator systems may have emerged, persisted and evolved into the first living cell. We have postulated three necessary conditions for an RNA World model system to be a dynamically feasible representation of prebiotic chemical evolution: (1 it must maintain and transfer a sufficient diversity of information reliably and indefinitely, (2 it must be ecologically stable and (3 it must be evolutionarily stable. In this review, we discuss the best-known prebiotic scenarios and the corresponding models of string-replicator dynamics and assess them against these criteria. We suggest that the most popular of prebiotic replicator systems, the hypercycle, is probably the worst performer in almost all of these respects, whereas a few other model concepts (parabolic replicator, open chaotic flows, stochastic corrector, metabolically coupled replicator system are promising candidates for development into coherent models that may become experimentally accessible in the future.

  20. Effect of Echinophora platyloba DC. essential oil and lycopene on the stability of pasteurized cream obtained from cow milk.

    Science.gov (United States)

    Ehsani, Ali; Hashemi, Mohammad; Hosseini Jazani, Nima; Aliakbarlu, Javad; Shokri, Sajad; Naghibi, Seyedeh Samane

    2016-01-01

    The present study was carried out to enhance shelf life of pasteurized cream using Echinophora platyloba essential oil (EEO) and lycopene. For this purpose, two concentrations of EEO (0.10% and 0.50%) and lycopene (20 and 50 ppm) alone and together as combinations were added in pasteurized creams and analyzed for microbial characteristics, sensorial properties and lipid stability during storage at 4 ˚C and 25 ˚C for 14 days. Results of microbial and chemical analyses of experimental pasteurized creams showed that pasteurized creams treated with combinations of the EEO and lycopene in their higher concentrations had the best microbial and chemical properties and the most stability than control during storage (p butter and cream.

  1. Thermal stability and fracture toughness of epoxy resins modified with epoxidized castor oil and Al2O3 nanoparticles

    International Nuclear Information System (INIS)

    Zhu, Lin; Jin, Fanlong; Park, Soojin

    2012-01-01

    This study examined the effects of the epoxidized castor oil (ECO) and Al 2 O 3 content on the thermal stability and fracture toughness of the diglycidylether of bisphenol-A (DGEBA)/ECO/Al 2 O 3 ternary composites using a range of techniques. The thermal stability of the composites was decreased by the addition of ECO and Al 2 O 3 nanoparticles. The fracture toughness of the composites was improved significantly by the addition of ECO and Al 2 O 3 nanoparticles. The composite containing 3 wt % Al 2 O 3 nanoparticles showed the maximum flexural strength. Scanning electron microscopy (SEM) revealed tortuous cracks in the DGEBA/ECO/Al 2 O 3 composites, which prevented deformation and crack propagation

  2. Influence of asphaltene aggregation and pressure on crude oil emulsion stability

    Energy Technology Data Exchange (ETDEWEB)

    Auflem, Inge Harald

    2002-07-01

    Water-in-crude oil emulsions stabilised by various surface-active components are one of the major problems in relation to petroleum production. This thesis presents results from high-pressure separation experiments on ''live'' crude oil and model oil emulsions, as well as studies of Interactions between various indigenous stabilising materials in crude oil. A high-pressure separation rig was used to study the influence of gas and gas bubbles on the separation of water-in-crude oil emulsions. The results were interpreted as a flotation effect from rising gas bubbles, which led to increased separation efficiency. The separation properties of a ''live'' crude oil were compared to crude oil samples recombined with various gases. The results showed that water-in-oil emulsions produced from the ''live'' crude oil samples, generally separated faster and more complete, than emulsions based on recombined samples of the same crude oil. Adsorption of asphaltenes and resins onto a hydrophilic surface from solutions with varying aromatic/aliphatic character was investigated by a quarts crystal microbalance. The results showed that asphaltenes adsorbed to a larger degree than the resins. The resins were unable to desorb pre-adsorbed asphaltenes from the surface, and neither did they adsorb onto the asphaltene-coated surface. In solutions of both of resins and asphaltenes the two constituents associated in bulk liquid and adsorbed to the surface in the form of mixed aggregates. Near infrared spectroscopy and pulsed field gradient spin echo nuclear magnetic resonance were used to study asphaltene aggregation and the influence of various amphiphiles on the asphaltene aggregate size. The results showed Interactions between the asphaltenes and various chemicals, which were proposed to be due to acid-base interactions. Among the chemicals used were various naphthenic acids. Synthesised monodisperse acids gave a reduction of

  3. Stability of potato chip fried in vegetable oils with different degree of unsaturation. Effect of ascorbyl palmitate during storage

    Directory of Open Access Journals (Sweden)

    Torres, R.

    2002-06-01

    Full Text Available Four vegetable oils with different polyunsaturated/saturated fatty acid ratio (P/S: 5.2 for sunflower oil, 3.,4 for canola rapeseed oil, 0.4 for a blend of palm oleic and canola rapeseed oil (80:20, and 0.3 for palm olein were assayed for stability of crisps fried in these oils during storage at 60º C. The action of ascorbyl palmitate with special attention to its synergistic effect on the natural antioxidants was also tested. by addition to the fried potatoes. The evolution of the oxidative stability was measured through peroxide value, quantitation of tocopherols and tocotrienols, and induction time (IT by means of Rancimat. Oil degradation during frying was very low as both polar compound percentages and natural antioxidant had similar levels to those present in refined oils. Evolution of analytical parameters during storage results indicated that oil unsaturation degree or P/S had a much more importance on stability of the product than had the content and type of natural antioxidants and the addition of AP. Nevertheless, addition of AP to the fried potatoes had a significant effect resulting in higher retention of natural antioxidants, higher IT and lower PV at any storage timeSe estudia la evolución de la oxidación a 60º C en patatas fritas con cuatro aceites vegetales de distinta relación ácidos grasos poliinsaturados/saturados (P/S: 5,4 para el aceite de girasol, 3,4 para el aceite de canola, 0,4 para una mezcla de oleína de palma (80 % y aceite de canola (20 % y 0,3 para la oleína de palma. Se estudia igualmente la influencia de la adición de palmitato de ascorbilo (AP durante la conservación del producto frito con especial atención a su efecto sinergista sobre los antioxidantes naturales. La evolución de la oxidación en lotes de patatas, con y sin adición de AP, se determinó mediante las siguientes determinaciones analíticas: índice de peróxidos (PV, cuantificación de tocoferoles y tocotrienoles, y periodos de

  4. Combined effect of carnosol, rosmarinic acid and thymol on the oxidative stability of soybean oil using a simplex centroid mixture design.

    Science.gov (United States)

    Saoudi, Salma; Chammem, Nadia; Sifaoui, Ines; Jiménez, Ignacio A; Lorenzo-Morales, Jacob; Piñero, José E; Bouassida-Beji, Maha; Hamdi, Moktar; L Bazzocchi, Isabel

    2017-08-01

    Oxidation taking place during the use of oil leads to the deterioration of both nutritional and sensorial qualities. Natural antioxidants from herbs and plants are rich in phenolic compounds and could therefore be more efficient than synthetic ones in preventing lipid oxidation reactions. This study was aimed at the valorization of Tunisian aromatic plants and their active compounds as new sources of natural antioxidant preventing oil oxidation. Carnosol, rosmarinic acid and thymol were isolated from Rosmarinus officinalis and Thymus capitatus by column chromatography and were analyzed by nuclear magnetic resonance. Their antioxidant activities were measured by DPPH, ABTS and FRAP assays. These active compounds were added to soybean oil in different proportions using a simplex-centroid mixture design. Antioxidant activity and oxidative stability of oils were determined before and after 20 days of accelerated oxidation at 60 °C. Results showed that bioactive compounds are effective in maintaining oxidative stability of soybean oil. However, the binary interaction of rosmarinic acid and thymol caused a reduction in antioxidant activity and oxidative stability of soybean oil. Optimum conditions for maximum antioxidant activity and oxidative stability were found to be an equal ternary mixture of carnosol, rosmarinic acid and thymol. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  5. Changes in Marsh Vegetation, Stability and Dissolved Organic Carbon in Barataria Bay Marshes Following the Deepwater Horizon Oil Spill

    Science.gov (United States)

    Holloway, J. M.; Aiken, G.; Kokaly, R. F.; Heckman, D.; Butler, K.; Mills, C. T.; Hoefen, T. M.; Piazza, S.

    2010-12-01

    Coastal wetlands in Southern Louisiana were contaminated by the release of record volumes of oil between April and July 2010. Barataria Bay was extensively impacted, resulting in the oiling and dieback of marsh grasses along a discontinuous margin up to 30m into the marshes. Shoreline stability and biogeochemistry have been monitored over three site visits between between July 10 and August 25, 2010. Initial observations in early July were that grasses, dominantly shape Spartina alterniflora and shape Juncus roemerianus, were bent over under the weight of a thick oil coating. The bent-over grasses were broken off along some reaches, leaving a stubbled shoreline more susceptible to erosion. Repeated site visits in mid and late August found visible erosion along some of the effected shorelines. Water samples were collected from the shoreline marsh remnants and from visibly unaffected marshes to characterize dissolved organic carbon (DOC) and total dissolved nitrogen (TDN). In spite of visible oil sheens in unfiltered water from contaminated shorelines and no visible sign of impact on vegetation in the “control” sites with no visible oil on vegetation, DOC concentrations were similar in impacted and visibly unimpacted sites in Barataria Bay. Subsequent samples in mid- and late-August had increased DOC concentrations relative to previous sample events regardless of whether the site was visibly impacted. There was a general increase in specific UV absorbance (SUVA), an index of aromaticity, with increasing DOC concentrations, either due to seasonal effects or continued dissolution of petroleum compounds. Further chemical characterization using fluorescence and gas chromatography will be used to confirm the presence of petroleum compounds. The ratio of DOC to TDN also increased over time, which may have implications for vegetation regrowth and plant community structure, including the shift of grass species dominating effected marshes. These initial findings suggest

  6. Oxidative stability of chicken’s breast after vacuum packaging, EDTA, sage and rosemary essential oils treatment

    Directory of Open Access Journals (Sweden)

    Adriana Pavelková

    2016-07-01

    Full Text Available In the present work, the effect of the sage and rosemary essential oils on oxidative stability of chicken breast muscles during chilled storage was investigated. In the experiment were chickens of hybrid combination Cobb 500 after 42 days of the fattening period slaughtered.  All the broiler chickens were fed with the same feed mixtures and were kept under the same conditions. The feed mixtures were produced without any antibiotic preparations and coccidiostats. After slaughtering was dissection obtained fresh chicken breast with skin from left half-carcass, which were divided into five groups (n = 5: C - control air-packaged group; A1 - vacuum-packaged experimental group; A2 - vacuum-packaged experimental group with EDTA solution 1.50% w/w; A3 - vacuum-packaged experimental group with Salvia officinalis L. oil 2.0% v/w and A4 - vacuum-packaged experimental group with Rosmarinus officinalis L. essential oil 2.0% v/w. The sage and rosemary essential oils were applicate on surface chicken breasts and immediately after dipping, each sample was packaged using a vacuum packaging machine and storage in refrigerate at 4  ±0.5 °C. The value of thiobarbituric acid (TBA expressed as amount of malondialdehyde (MDA in 1 kg sample was measured during storage in 1st, 4th, 8th, 12th and 16th day. The treatments of chicken breasts with sage and rosemary essential oils show statistically significant differences between all testing groups and control group, where higher average value of MDA measured in breast muscle of broiler chickens was in samples of control group (0.396 mg.kg-1 compared to experimental groups A1 (0.060 mg.kg-1, A2 (0.052 mg.kg-1, A3 (0.042 mg.kg-1 and A4 (0.041 mg.kg-1 after 16-day of chilled storage. The results of experiment showed that the treatment of chicken breast with sage and rosemary essential oils had positive effect on the decrease of oxidative processes in breast muscles during chilling storage and use of plant essential oils

  7. The oil industry in 2007

    International Nuclear Information System (INIS)

    2008-01-01

    The various contributions present and comment many data about the evolutions of different parts of the oil industry until 2007: world oil and gas markets, worldwide oil exploration and production, oil exploration and production in France, oil and oil-related industry in France, hydrocarbon supplies, oil refining in France, fuel quality, substitution fuels, inner transportation of oil products, storage of oil products, consumption of oil products, taxing of oils products, price of oil products, distribution of oil products

  8. Introduction and development of soil thermal stabilization technologies at the objects of oil pumping station-2 (OPS-2 of "Kuyumba - Tayshet" trunk oil pipeline

    Directory of Open Access Journals (Sweden)

    Sapsay Aleksey Nikolaevich

    2014-09-01

    Full Text Available The article deals with the questions of designing the foundations for the Oil Pumping Station-2 site of "Kuyumba - Tayshet" trunk oil pipeline. The problems of choice and grounds for technical solutions are considered basing on the results of complex thermotechnical calculations. The construction territory of OPS-2 site of "Kuyumba - Tayshet" trunk oil pipeline is characterized by complex engineering and geocryological conditions: 1 presence of permafrost soil on 80 % of the site area; 2 absence of sufficiently widespread rocky soils under designed buildings and constructions; 3 transition of loamy grounds into yield during thawing. The buildings and facilities are designed on the basis of pile foundation type with high rigid foundation grill. The piles’ diameter is 325 mm and 426 mm, the total length of piles is 9-12 m. The full designed vertical loading, transferred to the pile, is ranging from 10.6 to 50.4 tf. According to the results of the calculations, in order to provide the necessary bearing capacity of piles, securing the perception of transmitted designed loadings, the equivalent temperature of the soil along the side surface of piles ( e should not be higher than -0,5 °C. Taking into account that the soil temperatures on the projected site mainly range from -0.1 to -0.3 °C, in order to lower their temperatures to the calculated values ventilated underground areas are arranged under the buildings and facilities and seasonally active cooling devices (soil thermal stabilizers are installed. Assembly technique and construction of ventilated underground areas with application of soil thermal stabilizers were developed earlier while designing the pipeline system "Zapolyarye - Oil Pumping Station Purpe". For confirmation of the accepted decisions forecasting thermotechnical calculations were performed with the use of a special computer program TermoStab 67-87, which allows simulating the changes of temperature regimes of the permafrost

  9. Effects of low energy radiations on the stability of red palm oil

    International Nuclear Information System (INIS)

    Dzulkefly, K.; Zarida, Z.; Hamdan, S.

    1999-01-01

    Red palm oil (R-PO) is a new generation of cooking oil in which the carotenes are retained in the refined oil. In this study, the oxidative effects of low energy radiations (sunlight and ultra-violet radiation) on RPO were investigated. The red palm oil was exposed to sunlight and ultra-violet (UV) radiation for various time intervals. The concentrations of carotene, peroxide value (PV), conjugated diene value (CD) and free fatty acid (FFA) content were measured. The irradiation was also performed in the presence of antioxidant butylated hydroxytoluene (BHT). Results showed that carotene contents were significantly reduced as the irradiation doses increase. The destruction of carotenes were 23.9 % and 24.1 % respectively under sunlight and UV radiation after 5 hours exposure. Measurements of PV, CD and FFA have indicated that both UV and sunlight radiations caused deterioration of red palm oil. In the presence of antioxidant, the extent of deterioration of RPO and the destruction of carotene were suppressed. This study has shown that the natural antioxidant (carotenes and tocopherols) did not give complete protection to RPO against oxidative deterioration induced by low energy radiations. Additional antioxidant (BHT) was needed to suppress the oxidative deterioration of RPO. (Author)

  10. Oxidative stability of lard and sunflower oil supplemented with coffee extracts under storage conditions

    Directory of Open Access Journals (Sweden)

    Budryn, Grażyna

    2011-06-01

    Full Text Available The oxidative stability of sunflower oil and lard supplemented with water extracts of green and roasted, Arabica and Robusta coffee beans was estimated. A decrease in the rate of fat oxidation reactions during the storage of samples for 12 weeks at ambient temperature which resulted from the addition of coffee extracts was evaluated using standard chemical methods such as the determination of peroxide and p-anisidine value and the assays of conjugated dienes and trienes as well as physical methods such as the determination of thermal profile by DSC. The sensory properties of all fat samples were also determined. These measurements showed that 0.1% water coffee extracts in fats decreased (p < 0.05 the quantities assayed by the chemical methods as compared to the control samples and approximately halved the rate of fat oxidation. In addition, the thermal profile analysis revealed that supplementing with coffee extracts reduced the extent of negative changes in the thermal properties of fats. The effectiveness of the tested coffee extracts decreased in the order: green Robusta > green Arabica > roasted Robusta > roasted Arabica.

    La estabilidad oxidativa de manteca y aceite de girasol suplementados con extractos acuosos de granos de café verde o tostado Arábica y Robusta fue estimada. Un descenso en la velocidad de las reacciones de oxidación de la grasa durante el almacenamiento de las muestras durante 12 semana a temperatura ambiente, que resulto de la adición de los extractos de café, fue evaluada usando métodos químicos estándares tales como la determinación de peróxidos y el índice de paranisidina y ensayos de dienos y trienos conjugados, así como métodos físicos tales como la determinación del perfil térmico por DSC. También las propiedades sensoriales de todas las grasas fueron estimadas. Estas medidas mostraron que extractos acuosos de café al 0.1% en la grasa decrecieron (p < 0.05 los valores obtenidos por los m

  11. Effects of Conventional Heating on the Stability of Major Olive Oil Phenolic Compounds by Tandem Mass Spectrometry and Isotope Dilution Assay

    Directory of Open Access Journals (Sweden)

    Giovanni Sindona

    2010-12-01

    Full Text Available The quality of olive oils is sensorially tested by accurate and well established methods. It enables the classification of the pressed oils into the classes of extra virgin oil, virgin oil and lampant oil. Nonetheless, it would be convenient to have analytical methods for screening oils or supporting sensorial analysis using a reliable independent approach based on exploitation of mass spectrometric methodologies. A number of methods have been proposed to evaluate deficiencies of extra virgin olive oils resulting from inappropriate technological treatments, such as high or low temperature deodoration, and home cooking processes. The quality and nutraceutical value of extra virgin olive oil (EVOO can be related to the antioxidant property of its phenolic compounds. Olive oil is a source of at least 30 phenolic compounds, such as oleuropein, oleocanthal, hydroxytyrosol, and tyrosol, all acting as strong antioxidants, radical scavengers and NSAI-like drugs. We now report the efficacy of MRM tandem mass spectrometry, assisted by the isotope dilution assay, in the evaluation of the thermal stability of selected active principles of extra virgin olive oil.

  12. Effects of conventional heating on the stability of major olive oil phenolic compounds by tandem mass spectrometry and isotope dilution assay.

    Science.gov (United States)

    Attya, Mohamed; Benabdelkamel, Hicham; Perri, Enzo; Russo, Anna; Sindona, Giovanni

    2010-12-01

    The quality of olive oils is sensorially tested by accurate and well established methods. It enables the classification of the pressed oils into the classes of extra virgin oil, virgin oil and lampant oil. Nonetheless, it would be convenient to have analytical methods for screening oils or supporting sensorial analysis using a reliable independent approach based on exploitation of mass spectrometric methodologies. A number of methods have been proposed to evaluate deficiencies of extra virgin olive oils resulting from inappropriate technological treatments, such as high or low temperature deodoration, and home cooking processes. The quality and nutraceutical value of extra virgin olive oil (EVOO) can be related to the antioxidant property of its phenolic compounds. Olive oil is a source of at least 30 phenolic compounds, such as oleuropein, oleocanthal, hydroxytyrosol, and tyrosol, all acting as strong antioxidants, radical scavengers and NSAI-like drugs. We now report the efficacy of MRM tandem mass spectrometry, assisted by the isotope dilution assay, in the evaluation of the thermal stability of selected active principles of extra virgin olive oil.

  13. Relations between interfacial properties and heavy crude oil emulsions stability; Relations entre les proprietes interfaciales et la stabilite des emulsions de brut lourd

    Energy Technology Data Exchange (ETDEWEB)

    Hoebler-Poteau, S.

    2006-02-15

    Oil in water emulsions are currently being investigated to facilitate the transport of viscous heavy oils. The behavior of these emulsions is largely controlled by oil / water interfaces. The surface-active components of crude oil such as asphaltenes and naphthenic acids compete among themselves at these interfaces and also with possibly added synthetic surfactant emulsifier.Here, we present a study of dynamic interfacial tension and rheology of interfaces between water and a model oil (toluene) in which asphaltenes and other surface active molecules from crude oil are dissolved. We show that different parameters such as aging of the interface, asphaltenes concentration, the pH and salinity of the aqueous phase have a strong influence on interfacial properties of asphaltenes at the oil/water interface. Several micro-pipette experiments, in which micrometric drops have been manipulated, are described as well as small angle neutron scattering measurements. The influence of lower molecular weight surface-active species, such as the natural naphthenic acids contained in maltenes (crude oil without asphaltenes) has been investigated, and an interaction between asphaltenes and maltenes which facilitates molecular arrangement at the interface was detected. The microscopic properties of the different interfaces and the stability of the corresponding emulsions are determined to be correlated.The results obtained on model emulsions and model oil/water interfaces were found to be helpful in order to explain and predict the behavior of heavy crude oil emulsions. (author)

  14. Oil Bodies Extracted from High-Fat and Low-Fat Soybeans: Stability and Composition During Storage.

    Science.gov (United States)

    Wang, Qiu Ling; Li Cui, Chun; Jiang, Lian Zhou; Liu, Yue; Liang, Xin Ting; Hou, Jun Cai

    2017-06-01

    Soybeans contain oil bodies (OBs) that encapsulate triacylglycerols (TAGs) with a phospholipid monolayer carrying scattered proteins. In nature, soybean OBs can form natural emulsions in aqueous media and may serve as natural, minimally processed, stable, and pre-emulsified oil for addition into appropriate food systems. In this study, OBs were obtained by aqueous extraction from the mature seeds of 2 soybean crop cultivars, high-fat soybean and low-fat soybeans. The compositions of the extracted OBs were analyzed during storage at room temperature up to 14 d (pH = 7). The oxidative stability of these OBs, stored at 60 °C, was evaluated by measuring the presence of primary (lipid hydroperoxides) and secondary lipid oxidation products (malondialdehyde) by determining the standard peroxide value (PV) and thiobarbituric acid-reactive substances (TBARS) value. During storage, the contents of unsaturated fatty acids, phospholipids, and tocopherols declined in both OBs, while their mean particle diameters (d 32 ) and ζ-potentials increased. The changes in PV and TBARS values exhibited a similar trend for both OBs, but the OBs from low-fat soybeans had significantly lower PV and higher TBARS values than the OBs from high-fat soybean cultivars (P soybean cultivars had good stability during storage. © 2017 Institute of Food Technologists®.

  15. Effect of direct adding oregano essential oil (Origanum syriacum L. on quality and stability of chicken meat patties

    Directory of Open Access Journals (Sweden)

    Marwan AL-HIJAZEEN

    2017-09-01

    Full Text Available Abstract Evaluate of Origanum syriacum L. essential oil grown in Jordan, and other comparable antioxidant on TBARS, total carbonyl, color values, and sensory attributes of raw chicken meat was investigated. Six treatments were prepared: (1 control (no additive; (2 100 ppm oregano essential oil (OE; (3 150 ppm OE; (4 300 ppm L-ascorbic acid (E-300; (5 5 and 14 ppm butylatedhydroxyanisole (BHA/E-320 for both breast and thigh meat respectively, and 6 150 ppm Sodium nitrite (E-250, were prepared using ground chicken meat. Generally, OE at level of 150 ppm was the most effective decreasing TBARS, and total carbonyl values compared to the other treatments. Furthermore, it showed better color values (L* and a* in term of meat color stability. However, OE and E-250 also showed the highest significant values among the other treatments. Sensory evaluation results showed that adding OE at level of 150 ppm and 100 ppm were the best values maintaining meat storage stability. Therefore, it can be recommended that OE at level of 150 ppm could be an excellent replacement to the synthetic antioxidant in the future of uncured, natural fresh meat products, and raw meat prepared for processing.

  16. Highly efficient separation of surfactant stabilized water-in-oil emulsion based on surface energy gradient and flame retardancy.

    Science.gov (United States)

    Long, Mengying; Peng, Shan; Deng, Wanshun; Miao, Xinrui; Wen, Ni; Zhou, Qiannan; Deng, Wenli

    2018-06-15

    Surface energy gradient would generate an imbalance force to drive tiny water droplets in dry air from the hydrophilic bumps to superhydrophobic domains, which has found on the Stenocara beetle's back. Inspired by this phenomenon, we introduced a pristine superhydrophilic filter paper on the lower surface energy superhydrophobic filter paper. ZnSn(OH) 6 particles and polydimethylsiloxane were mixed to prepare the superhydrophobic coating, and the coating was spray-coated on the poly(dialkyldimethylammonium chloride) covered filter paper to separate the span 80 stabilized water-in-isooctane emulsion. A pristine filter paper was added on the superhydrophobic filter paper to fabricate another membrane for separation. The results revealed that with a pristine filter paper, the membrane performed higher efficiency and more recyclability, and it could separate the emulsions with higher surfactant concentrations. The stabilized water droplets passed the superamphiphilic surface, and hindered by the superhydrophobic surface, generating a surface energy gradient for better separation. In addition, the superhydrophobic membrane could be protected from fire to some degree due to the introduced ZnSn(OH) 6 particles with excellent flame retardancy. This easy and efficient approach via simply bringing in pristine superhydrophilic membrane has great potential applications for water-in-oil emulsion separation or oil purification. Copyright © 2018 Elsevier Inc. All rights reserved.

  17. Oxidative stability of fish oil supplemented with carnosic acid compared with synthetic antioxidants during long-term storage.

    Science.gov (United States)

    Wang, Hua; Liu, Fang; Yang, Lei; Zu, Yuangang; Wang, Han; Qu, Shengzhuo; Zhang, Ying

    2011-09-01

    The effects of carnosic acid (CA) of different concentrations (0.1, 0.2, and 0.3mg/g) and synthetic antioxidants on oxidative stability in fish oil stored for 66days at different temperatures (30 and 4°C) were compared. The investigation focused on the increase in peroxide and conjugated diene values, as well as free fatty acid and thiobarbituric acid-reactive substances. The changes in trans fatty acid and aldehyde compound contents were investigated by Fourier transform infrared spectroscopy, while the changes in polyunsaturated fatty acid content were monitored by gas chromatography-mass spectrometry. The results show that the three CA concentrations were more effective in restraining fish oil oxidation, in which a dose-response relationship was observed. The antioxidant activity of CA was stronger than that of vitamin E, but still weaker than that of tertiary-butyl hydroquinone. Fish oil supplemented with 0.2mg/g CA exhibited favourable antioxidant effects and is preferable for effectively avoiding oxidation. Copyright © 2011 Elsevier Ltd. All rights reserved.

  18. Oil refining in a CO2 constrained world: Effects of carbon pricing on refineries globally

    International Nuclear Information System (INIS)

    Abdul-Manan, Amir F.N.; Arfaj, Abdullah; Babiker, Hassan

    2017-01-01

    Six aggregated refinery linear programming (LP) models were developed to represent actual refineries in North America, Latin America, Europe (including the CIS), Middle East, Asia (excluding China) and China. The models were used to conduct regional comparative assessments and to evaluate the effects of carbon pricing on refinery operations globally. We found that the average refinery energy efficiencies for the regions were estimated to range from 92.2% to 95.2%. The well-to-refinery gate carbon intensities for gasoline, diesel and jet fuels were estimated to be 17.1 (16.4–19.4), 13.3 (12.5–14.2) and 10.1 (9.6–10.8) gCO2eq/MJ, respectively. If refineries are forced to at least meet the 2014 regional volume demands for oil products, pricing CO 2 would not have an impact on either refinery productions, efficiency or emissions. If refineries are allowed to re-optimize production slates to reduce CO 2 emissions, refineries would opt to increase gasoline yield at the expense of diesel. This is counter intuitive since gasoline has a higher carbon intensity than diesel. The refinery bias against dieselization creates a supply preference toward a less efficient transportation end use. Here, we argue that if carbon pricing is not administered properly, this can lead to emissions leakage from refineries to the road transport sector. - Highlights: • Investigate actual refinery productions in 6 regions globally. • Refineries already operate at the most efficient levels. • Complex refineries tolerate higher CO 2 prices better. • Carbon pricing induces bias against dieselization. • Identify potential emissions leakage.

  19. Development of a method for the characterization of the oxidation stability of domestic heating oil and domestic heating oil with alternative components using chemiluminescence; Entwicklung einer Analysemethode zur Charakterisierung der Oxidationsstabilitaet von Heizoel EL und Heizoel EL A mittels Chemilumineszenz

    Energy Technology Data Exchange (ETDEWEB)

    Koch, Winfried; Lukito, Jayadi; Schloss, Heide vom [Oel-Waerme-Institut gGmbH (OWI), Aachen-Herzogenrath (Germany)

    2013-04-15

    The project's aim was to develop a process that serves to determine the oxidation stability of heating oil - FAME-/ heating oil - vegetable oil-blends clearly. Due to a directed energy input by means of the process of chemiluminescence, statements about the storage stability and the thermal stability of blends can be made. During the process the ageing of blend components and of the heating oil are taken into consideration. As a result, ageing processes and products of pure heating oil as well as biogenic components can be determined. It was shown that the process is applicable to blends up to an admixture of at least 20 % (V/V) of biogenic components, whereby blends with higher admixture shares can be analyzed as well. According to DIN SPEC 51603 - 6 'Heating Oil Alternative' the admixture of FAME is limited to 20 %(V/V) and the admixture of vegetable oil to 5 % (V/V) because of the distillation range. On the basis of these investigations it could be shown how oxidation products influence the signal process of the chemiluminescence radiation and how they can be correlated by a measurable physical value. Moreover, a new evaluation criterion has been developed. By means of this criterion a good reproducibility - regarding the determination of the oxidation stability according to the chemiluminescence methodology for non-aged fuels - can be achieved. The fuel characteristic decrease in the stability of the tested fuels can be represented only partially by the chemiluminescence process, as the measured values are subject to fluctuations. (orig.)

  20. The effect of pan frying on thermooxidative stability of refined rapeseed oil and professional blend.

    Science.gov (United States)

    Aniołowska, Magda; Zahran, Hamdy; Kita, Agnieszka

    2016-01-01

    The pan fryings of frozen pre-fried French fries in refined rapeseed oil (RO) and professional blend (PB) were of 8 h duration. Initially, while fresh, and after every 1 h of frying, the oils were analyzed for acid and anisidine values, colour, refractive index, fatty acid composition (by GC), polar fraction content and composition (by high pressure size exclusion chromatography). Additionally the fat content and fatty acid composition of French fries were determined. Hydrolytic and oxidative changes in the frying media varied with oil composition and increased with frying time. The pace of oxidation in RO was three times higher than in PB. The loss of polyunsaturated fatty acids (sum of C18:2 and C18:3) after 8 h of frying was 7 % in PB and 20 % in RO. The polar fraction content was two times lower in PB, but did not exceed 25 % in either of the frying media. The predominant fraction in RO was oxidized triacylglycerols, while in PB - diacylglycerols. During frying the proportions of triacylglycerol polymers and dimers increased in both oils, reaching 32 % in RO and 23 % in PB.

  1. The Effectiveness of Rambutan (Nephelium lappaceum L.) Extract in Stabilization of Sunflower Oil under Accelerated Conditions.

    Science.gov (United States)

    Mei, Winne Sia Chiaw; Ismail, Amin; Esa, Norhaizan Mohd; Akowuah, Gabriel Akyirem; Wai, Ho Chun; Seng, Yim Hip

    2014-05-09

    The oxidative properties of sunflower oil supplemented with rambutan extract, (crude extract and its fractionated fraction, SF II) in comparison with synthetic antioxidant were investigated. The supplemented sunflower oils were stored under accelerated conditions for 24 days at 60 °C. For every 6-day interval, the oxidative properties of the supplemented sunflower oil were evaluated based on the following tests, namely peroxide value, p-anisidine value, Thiobarbituric Acid Reactive Substances (TBARS) assay, iodine value and free fatty acids. The total oxidation (TOTOX) values were also calculated based on the peroxide values and p-anisidine values. Rambutan extract is a potential source of antioxidant. The oxidative activities of the extracts at all concentrations were significantly (p < 0.05) higher than the control. Generally, the partially fractionated fraction was more effective than the crude extract. With a 2-year storage period at ambient temperature, the fractionated fraction of the extract, SF II at 300 ppm, was observed to work more effectively than the synthetic antioxidant, t-Tocopherol, and it possessed a protective effect comparable with butylatedhydrioxynanisole (BHA). Therefore, rambutan extract could be used as a potential alternative source of antioxidant in the oil industry or other fat-based products to delay lipid oxidation.

  2. The Effectiveness of Rambutan (Nephelium lappaceum L. Extract in Stabilization of Sunflower Oil under Accelerated Conditions

    Directory of Open Access Journals (Sweden)

    Winne Sia Chiaw Mei

    2014-05-01

    Full Text Available The oxidative properties of sunflower oil supplemented with rambutan extract, (crude extract and its fractionated fraction, SF II in comparison with synthetic antioxidant were investigated. The supplemented sunflower oils were stored under accelerated conditions for 24 days at 60 °C. For every 6-day interval, the oxidative properties of the supplemented sunflower oil were evaluated based on the following tests, namely peroxide value, p-anisidine value, Thiobarbituric Acid Reactive Substances (TBARS assay, iodine value and free fatty acids. The total oxidation (TOTOX values were also calculated based on the peroxide values and p-anisidine values. Rambutan extract is a potential source of antioxidant. The oxidative activities of the extracts at all concentrations were significantly (p < 0.05 higher than the control. Generally, the partially fractionated fraction was more effective than the crude extract. With a 2-year storage period at ambient temperature, the fractionated fraction of the extract, SF II at 300 ppm, was observed to work more effectively than the synthetic antioxidant, t-Tocopherol, and it possessed a protective effect comparable with butylatedhydrioxynanisole (BHA. Therefore, rambutan extract could be used as a potential alternative source of antioxidant in the oil industry or other fat-based products to delay lipid oxidation.

  3. Coriander Seed Oil Methyl Esters as Biodiesel Fuel: Unique Fatty Acid Composition and Excellent Oxidative Stability

    Science.gov (United States)

    Coriander (Coriandrum sativum L.) seed oil methyl esters were prepared and evaluated as an alternative biodiesel fuel and contained an unusual fatty acid (FA) hitherto unreported as the principle component in biodiesel fuels: petroselinic (6Z-octadecenoic; 68.5 wt %) acid. Most of the remaining FA...

  4. Gas chromatography analysis of blackcurrant oil in relation to its stability

    Czech Academy of Sciences Publication Activity Database

    Stránský, Karel; Zarevúcka, Marie; Wimmer, Zdeněk

    2005-01-01

    Roč. 92, - (2005), 569-573 ISSN 0308-8146 R&D Projects: GA MŠk 1P04OCD13.10 Institutional research plan: CEZ:AV0Z4055905 Keywords : blackcurrant oil * Ribes nigrum * triacylglycerol Subject RIV: CC - Organic Chemistry Impact factor: 1.811, year: 2005

  5. Antioxidative effects of stabilized and unstabilized defatted rice bran methanolic extracts on the stability of rice bran oil under accelerated conditions

    Directory of Open Access Journals (Sweden)

    Adam Mariod, Abdalbasit

    2010-12-01

    Full Text Available The present research assessed the antioxidant activity against the synthetic 1, 1-diphenyl-2-picrylhydrazyl radical, and β-carotene–linoleic acid assay of the methanolic extracts of defatted rice bran from stabilized and unstabilized rice bran. The effects of the extracts (0.1 and 0.25% w/w on the oxidative stability of refined-bleached rice bran oil were determined and compared with those of BHA (synthetic antioxidant. The study was carried out over a 168 hr period at 70°C and the progression of oxidation was measured by peroxide value, p-anisidine value, and thiobarbituric acid-reactive substances (TBARS. The relative % of residual α-tocopherol and γ-oryzanol of the rice bran oil containing methanolic extracts of stabilized and unstabilized defatted rice bran during storage at 70°C were studied.

    La presente investigación evalúa la actividad antioxidante mediante el radical sintético 1,1-difenil-2-picrilhidrazil y el ensayo β-caroteno–ácido linoleico de extractos metanólicos de salvado de arroz desengrasado procedente de salvado de arroz estabilizado y no-estabilizado. El efecto de los extractos (0.1 y 0.25% w/w sobre la estabilidad oxidativa del aceite refinado de salvado de arroz fue determinado y comparado con el del BHA (antioxidante sintético. El estudio fue llevado a cabo durante un periodo de 168 hr a 70°C y la progresión de la oxidación fue medida mediante el valor de peróxidos, valor de p-anisidine y substancias reactivas del ácido tiobarbitúrico (TBARS. El porcentaje relativo del α-tocoferol y γ-orizanol residual en el aceite de germen de arroz conteniendo extracto metanólico de germen de arroz desengrasado estabilizado y no estabilizado durante el almacenamiento a 70°C fueron estudiados.

  6. Volatile constituents and oxidative stability of virgin olive oils: influence of the kneading of olive-paste.

    Directory of Open Access Journals (Sweden)

    Lercker, G.

    1999-12-01

    Full Text Available Olive crushing, olive-paste kneading and separation of the oil the most important technological steps in olive oil production since they directly influence the future quality of the product. The contact between the oil and the olive-paste increases lipolysis and lipid oxidation, which are mainly due to the highly-active lipases present in the paste and the lipoxygenase action, respectively. The choice of the technological parameters is directly related to the oil future stability and its organoleptic characteristics. This study confirms and emphasizes the fact that the oxidative degradation, simultaneously with the well-known formation of the flavor compounds, is related to the time required for the separation of the oil-water emulsion. Loss of the natural antioxidants (minor polar components by an oxidative effect was demonstrated to be also influenced by the time required for oil separation.

    La molienda de aceitunas, el batido de la pasta y la separación del aceite de oliva producen una serie de transformaciones en las características del aceite que posteriormente será extraído. Es sabido que la formación de distintos componentes del aroma del aceite derivan de reacciones oxidativas enzimáticas. El contacto entre el aceite y la pasta de aceitunas incrementa la lipolisis y la oxidación lipídica, debido a un incremento de la actividad de las lipasas presentes en la pasta y a una acción lipoxigenásica respectivamente. La elección de los parámetros tecnológicos está en relación directa con la futura estabilidad y las características organolépticas del aceite. En este trabajo se confirma la formación de tales compuestos evidenciándose la degradación oxidativa del aceite en relación al tiempo de batido empleado. Se demuestra también una pérdida de antioxidantes (componentes polares menores por efectos oxidativos en modo proporcional al tiempo de batido.

  7. Omega-3 fatty acids and oxidative stability of ice cream supplemented with olein fraction of chia (Salvia hispanica L.) oil.

    Science.gov (United States)

    Ullah, Rahman; Nadeem, Muhammad; Imran, Muhammad

    2017-02-07

    Chia (Salvia hispanica L.) has been regarded as good source of polyunsaturated omega-3 fatty acids with cardiac, hepatic, hypotensive, antiallergic and antidiabetic role. Concentration of omega-3 fatty acids in chia oil can be enhanced by fractionation. Olein/low melting fraction of chia oil has higher concentration of omega-3 fatty acids. Therefore, main objective of current investigation was determination of various concentration effect of olein fraction of chia oil on omega-3 fatty acids, oxidative stability and sensory characteristics of ice cream. Ice cream samples were prepared by partially replacing the milk fat with olein fraction of chia oil at 5, 10, 15 and 20% concentrations (T 1 , T 2 , T 3 and T 4 ), respectively. Ice cream prepared from 100% milk fat was kept as control. Ice cream samples stored at -18 °C for 60 days were analysed at 0, 30 and 60 days of the storage period. Fatty acid profile, total phenolic contents, total flavonoids, free fatty acids, peroxide value, anisidine value and sensory characteristics of ice cream samples was studied. Concentration of α-linolenic acid, eicosapentaenoic acid, docosapentaenoic acid and docosahexaenoic acid in T 4 was 13.24, 0.58, 0.42 and 0.31%, respectively. Total phenolic contents of control, T 1 , T 2 , T 3 and T 4 were recorded 0.12, 1.65, 3.17, 5.19 and 7.48 mg GAE/mL, respectively. Total flavonoid content of control, T 1 , T 2 , T 3 and T 4 were found 0.08, 0.64, 1.87, 3.16 and 4.29 mg Quercetin Equivalent/mL. 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging activity of control, T 1 , T 2 , T 3 and T 4 was noted 5.61, 17.43, 36.84, 51.17 and 74.91%, respectively. After 60 days of storage period, the highest peroxide value of 1.84 (MeqO 2 /kg) was observed in T 4 , which was much less than allowable limit of 10 (MeqO 2 /kg). Flavour score was non-significant after 30 days of storage period. Supplementation of ice cream with olein fraction of chia oil enhanced the concentration of

  8. Physical and Oxidative Stability of Flaxseed Oil-in-Water Emulsions Fabricated from Sunflower Lecithins: Impact of Blending Lecithins with Different Phospholipid Profiles.

    Science.gov (United States)

    Liang, Li; Chen, Fang; Wang, Xingguo; Jin, Qingzhe; Decker, Eric Andrew; McClements, David Julian

    2017-06-14

    There is great interest in the formulation of plant-based foods enriched with nutrients that promote health, such as polyunsaturated fatty acids. This study evaluated the impact of sunflower phospholipid type on the formation and stability of flaxseed oil-in-water emulsions. Two sunflower lecithins (Sunlipon 50 and 90) with different phosphatidylcholine (PC) levels (59 and 90%, respectively) were used in varying ratios to form emulsions. Emulsion droplet size, charge, appearance, microstructure, and oxidation were measured during storage at 55 °C in the dark. The physical and chemical stability increased as the PC content of the lecithin blends decreased. The oxidative stability of emulsions formulated using Sunlipon 50 was better than emulsions formulated using synthetic surfactants (SDS or Tween 20). The results are interpreted in terms of the impact of emulsifier type on the colloidal interactions between oil droplets and on the molecular interactions between pro-oxidants and oil droplet surfaces.

  9. Role of Endogenous and Exogenous Tocopherols in the Lipid Stability of Marine Oil Systems: A Review

    Directory of Open Access Journals (Sweden)

    Guadalupe Miroslava Suárez-Jiménez

    2016-11-01

    Full Text Available In marine organisms primarily intended for human consumption, the quality of the muscle and the extracted oils may be affected by lipid oxidation during storage, even at low temperatures. This has led to a search for alternatives to maintain quality. In this sense, antioxidant compounds have been used to prevent such lipid deterioration. Among the most used compounds are tocopherols, which, due to their natural origin, have become an excellent alternative to prevent or retard lipid oxidation and maintain the quality of marine products. Tocopherols as antioxidants have been studied both exogenously and endogenously. Exogenous tocopherols are often used by incorporating them into plastic packaging films or adding them directly to fish oil. It has been observed that exogenous tocopherols incorporated in low concentrations maintain the quality of both muscle and the extracted oils during food storage. However, it has been reported that tocopherols applied at higher concentrations act as a prooxidant molecule, probably because their reactions with singlet oxygen may generate free radicals and cause the oxidation of polyunsaturated fatty acids in fish oils. However, when tocopherols are included in a fish diet (endogenous tocopherols, the antioxidant effect on the muscle lipids is more effective due to their incorporation into the membrane lipids, which can help extend the shelf life of seafood by reducing the lipid deterioration that occurs due to antioxidant synergy with other phenolic compounds used supplements in fish muscle. This review focuses on the most important studies in this field and highlights the potential of using tocopherols as antioxidants in marine oils.

  10. Nonconformities in real-world fatal crashes--electronic stability control and seat belt reminders.

    Science.gov (United States)

    Lie, Anders

    2012-01-01

    Many new safety systems are entering the market. Vision Zero is a safety strategy aiming at the elimination of fatalities and impairing injuries by the use of a holistic model for safe traffic to develop a safe system. The aim of this article is to analyze fatalities in modern cars with respect to the Vision Zero model with special respect to electronic stability control (ESC) systems and modern seat belt reminders (SBRs). The model is used to identify and understand cases where cars with ESC systems lost control and where occupants were unbelted in a seat with seat belt reminders under normal driving conditions. The model for safe traffic was used to analyze in-depth studies of fatal crashes with respect to seat belt use and loss of control. Vehicles from 2003 and later in crashes from January 2004 to mid-2010 were analyzed. The data were analyzed case by case. Cars that were equipped with ESC systems and lost control and occupants not using the seat belt in a seat with a seat belt reminder were considered as nonconformities. A total of 138 fatal crashes involving 152 fatally injured occupants were analyzed. Cars with ESC systems had fewer loss-of-control-relevant cases than cars without ESC systems. Thirteen percent of the ESC-equipped vehicles had loss-of-control-relevant crashes and 36 percent of the cars without ESC systems had loss-of-control-relevant crashes. The analysis indicates that only one car of the 9 equipped with ESC that lost control did it on a road surface with relevant friction when driving within the speed restriction of the road. In seats with seat belt reminders that are in accordance with the European New Car Assessment Programme's (Euro NCAP) protocol, 93 percent of the occupants were using a seat belt. In seats without reminders this number was 74 percent. This study shows that ESC systems result in a very significant reduction in fatal crashes, especially under normal driving conditions. Under extreme driving conditions such as speeding

  11. apllication of lyapunov's second method in the stability analysis of oil ...

    African Journals Online (AJOL)

    NIJOTECH

    linear) is to evaluate its dynamic stability. For non-linear systems, several methods have already been developed for this purpose. They are Nyquist's, Popov's and Lyapunov's methods. [1]. Among those methods, Lyapunov's method (second.

  12. Investigation of Dispersion, Stability, and Tribological Performance of Oil-Based Aluminum Oxide Nanofluids

    Science.gov (United States)

    2012-01-01

    laboratories used strictly, quality controlled nanofluids in the NIST RM 8012 and IRMM- 304 . The NIST RM 8012 nanofluid is an aqueous solution that contains...30 nm citrate-stabilized gold nanoparticles. The IRMM- 304 is a 40 nm diameter silica nanofluid with sodium hydroxide as a stabilizer. There was...process. A ball-on-flat friction tester was used with a 2 mm steel ball and an AISI 1045 steel flat. The maximum contact pressure was 1 GPa, and

  13. Genotype X environment interactions and stability of soybean for ...

    African Journals Online (AJOL)

    Soybean Glycine max (L.) Merrill] is the world's leading source of oil and protein. It has the highest protein content of all food crops and is second only to groundnut in terms of oil content among food legumes. Study on genotype x enviroment interaction (GE) and stability of twenty soybean [Glycine max (L.) Merrill] genotypes ...

  14. Bio-lubricants derived from waste cooking oil with improved oxidation stability and low-temperature properties.

    Science.gov (United States)

    Li, Weimin; Wang, Xiaobo

    2015-01-01

    Waste cooking oil (WCO) was chemically modified via epoxidation using H2O2 followed by transesterification with methanol and branched alcohols (isooctanol, isotridecanol and isooctadecanol) to produce bio-lubricants with improved oxidative stability and low temperature properties. Physicochemical properties of synthesized bio-lubricants such as pour point (PP), cloud point (CP), viscosity, viscosity index (VI), oxidative stability, and corrosion resistant property were determined according to standard methods. The synthesized bio-lubricants showed improved low temperature flow performances compared with WCO, which can be attributing to the introduction of branched chains in their molecular structures. What's more, the oxidation stability of the WCO showed more than 10 folds improvement due to the elimination of -C=C-bonds in the WCO molecule. Tribological performances of these bio-lubricants were also investigated using four-ball friction and wear tester. Experimental results showed that derivatives of WCO exhibited favorable physicochemical properties and tribological performances which making them good candidates in formulating eco-friendly lubricants.

  15. Oxidative stability of soybean oil added to coffee husk extract (Coffea arabica L. under accelerated storage conditions

    Directory of Open Access Journals (Sweden)

    Elisa Franco RIBEIRO

    Full Text Available Abstract Several plants have been studied as potential sources of natural antioxidants for use in the food industry, especially polyphenols. The aim of this study was to evaluate the effects of hydroalcoholic extract from coffee husk on the oxidative stability of soybean oil when stored in an oven. Samples were maintained at a temperature of 60 °C and their oxidative stability was evaluated once every 5 days for a period of 20 days through the Rancimat equipament and analysis of peroxide value, conjugated dienes and tocopherols retention. The oxidation rate in terms of mass gain was evaluated once every 24 hours for a period of 24 days. Although the antioxidant TBHQ showed a better efficiency in the inhibition of oxidation, coffee husk extract showed a synergistic effect when used with the synthetic, delaying the appearance of degradation products. In addition, the freeze-dried extract showed the ability to reduce the mass-gain rate when used alone as well as when used in combination with the synthetic antioxidant butyl hydroxyanisole (BHA, noting a synergistic effect on oxidative stability between the extract and the BHA. Therefore, coffee husk extract could be considered a source of natural antioxidants for synthetic antioxidants substitution.

  16. Cadmium sulfide quantum dots stabilized by castor oil and ricinoleic acid