Oxidative stability of krill oil (Euphausia superba)

DEFF Research Database (Denmark)

Lu, Henna Fung Sieng; Jacobsen, Charlotte; Bruheim, I.

Krill oil has been reported in many studies to have high oxidative stability when evaluated by peroxide value (PV) and anisidine value (AV). However, recent studies have shown that other compounds than primary and secondary oxidation products are formed when krill oil is exposed to oxidative...... conditions. These compounds include Strecker degradation compounds and pyrroles. Some of these compounds may have antioxidative effect. Commercial scale processing of krill prior to extraction may affect the oxidative stability of krill oil. Therefore, the main objective of this study was to compare lipid...... oxidation in krill oil produced in a commercial process and krill oil carefully extracted from frozen krill in the laboratory. Krill oil was incubated at different temperatures (20, 30 and 40 oC) for 1, 2, 3, 4 and 6 weeks, under conditions of constant stirring while being exposed to air. The oxidative...

Natural phenolics greatly increase flax (Linum usitatissimum) oil stability.

Science.gov (United States)

Hasiewicz-Derkacz, Karolina; Kulma, Anna; Czuj, Tadeusz; Prescha, Anna; Żuk, Magdalena; Grajzer, Magdalena; Łukaszewicz, Marcin; Szopa, Jan

2015-06-30

Flaxseed oil is characterized by high content of essential polyunsaturated fatty acids (PUFA) promoted as a human dietary supplement protecting against atherosclerosis. The disadvantage of the high PUFA content in flax oil is high susceptibility to oxidation, which can result in carcinogenic compound formation. Linola flax cultivar is characterized by high linoleic acid content in comparison to traditional flax cultivars rich in linolenic acid. The changes in fatty acid proportions increase oxidative stability of Linola oil and broaden its use as an edible oil for cooking. However one of investigated transgenic lines has high ALA content making it suitable as omega-3 source. Protection of PUFA oxidation is a critical factor in oil quality. The aim of this study was to investigate the impact of phenylpropanoid contents on the oil properties important during the whole technological process from seed storage to grinding and oil pressing, which may influence health benefits as well as shelf-life, and to establish guidelines for the selection of new cultivars. The composition of oils was determined by chromatographic (GS-FID and LC-PDA-MS) methods. Antioxidant properties of secondary metabolites were analyzed by DPPH method. The stability of oils was investigated: a) during regular storage by measuring acid value peroxide value p-anisidine value malondialdehyde, conjugated dienes and trienes; b) by using accelerated rancidity tests by TBARS reaction; c) by thermoanalytical - differential scanning calorimetry (DSC). In one approach, in order to increase oil stability, exogenous substances added are mainly lipid soluble antioxidants from the isoprenoid pathway, such as tocopherol and carotene. The other approach is based on transgenic plant generation that accumulates water soluble compounds. Increased accumulation of phenolic compounds in flax seeds was achieved by three different strategies that modify genes coding for enzymes from the phenylpropanoid pathway. The three

Reserve growth of the world's giant oil fields

Science.gov (United States)

Klett, T.R.; Schmoker, J.W.

2005-01-01

Analysis of estimated total recoverable oil volume (field size) of 186 well-known giant oil fields of the world (>0.5 billion bbl of oil, discovered prior to 1981), exclusive of the United States and Canada, demonstrates general increases in field sizes through time. Field sizes were analyzed as a group and within subgroups of the Organization of Petroleum Exporting Countries (OPEC) and non-OPEC countries. From 1981 through 1996, the estimated volume of oil in the 186 fields for which adequate data were available increased from 617 billion to 777 billion bbl of oil (26%). Processes other than new field discoveries added an estimated 160 billion bbl of oil to known reserves in this subset of the world's oil fields. Although methods for estimating field sizes vary among countries, estimated sizes of the giant oil fields of the world increased, probably for many of the same reasons that estimated sizes of oil fields in the United States increased over the same time period. Estimated volumes in OPEC fields increased from a total of 550 billion to 668 billion bbl of oil and volumes in non-OPEC fields increased from 67 billion to 109 billion bbl of oil. In terms of percent change, non-OPEC field sizes increased more than OPEC field sizes (63% versus 22%). The changes in estimated total recoverable oil volumes that occurred within three 5-year increments between 1981 and 1996 were all positive. Between 1981 and 1986, the increase in estimated total recoverable oil volume within the 186 giant oil fields was 11 billion bbl of oil; between 1986 and 1991, the increase was 120 billion bbl of oil; and between 1991 and 1996, the increase was 29 billion bbl of oil. Fields in both OPEC and non-OPEC countries followed trends of substantial reserve growth.

Stability analysis of oil yield in oil palm (Elaeis guineensis) progenies in different environments.

Science.gov (United States)

Rafii, M Y; Jalani, B S; Rajanaidu, N; Kushairi, A; Puteh, A; Latif, M A

2012-10-04

We evaluated 38 dura x pisifera (DP) oil palm progenies in four locations in Malaysia for genotype by environment interaction and genotypic stability studies. The DP progenies derived from crosses between pisifera palms of AVROS, Serdang S27B, Serdang 29/36, and Lever Cameroon were chosen to be the males' parent and Deli dura palms designated as females' parent. All the locations differed in terms of soil physical and chemical properties, and the soil types ranged from coastal clay to inland soils. The genotype by environment interaction and stability of the individual genotypes were analyzed for oil yield trait using several stability techniques. A genotype by environment interaction was detected for oil yield and it had a larger variance component than genotypic variance (σ(2)(gl)/σ(2)(g) = 139.7%). Genotype by environment interaction of oil yield was largely explained by a non-linear relationship between genotypic and environmental values. Overall assessment of individual genotypic stability showed that seven genotypes were highly stable and had consistent performance over the environments for the oil yield trait [total individual genotype stability scored more than 10 and mean oil yielded above the average of the environment (genotype means are more than 34.37 kg·palm(-1)·year(-1))]. These genotypes will be useful for oil palm breeding and tissue culture programs for developing high oil yielding planting materials with stable performance.

Oil and the world economy: some possible futures.

Science.gov (United States)

Kumhof, Michael; Muir, Dirk

2014-01-13

This paper, using a six-region dynamic stochastic general equilibrium model of the world economy, assesses the output and current account implications of permanent oil supply shocks hitting the world economy. For modest-sized shocks and conventional production technologies, the effects are modest. But for larger shocks, for elasticities of substitution that decline as oil usage is reduced to a minimum, and for production functions in which oil acts as a critical enabler of technologies, output growth could drop significantly. Also, oil prices could become so high that smooth adjustment, as assumed in the model, may become very difficult.

The integration of China into the world crude oil market since 1998

International Nuclear Information System (INIS)

Li, Raymond; Leung, Guy C.K.

2011-01-01

The integration of China into the world oil market is an important issue for at least two reasons. First, the influence of the country on the world oil market is dependent on the level of the integration. Second, integration into the world oil market means that China is opening itself up to potential disturbances in the world market and this leads to significant energy security concerns for the country. The aim of this paper is to investigate whether or not China is an integral part of the world oil market. By reviewing the relevant trade and pricing policies of the Chinese government as well as the behavior of the Chinese national oil companies, we find that China is actively engaging itself in the world oil market. Our time-series results show that the Chinese oil price is cointegrated with the major oil prices in the world and a high degree of co-movement between the prices is found. Causality between the price pairs is found to be bi-directional in most cases. The empirical results suggest that China is now an integral part of the world oil market. - Highlights: → Review of the oil trade and pricing policies of the Chinese government. → Review of the behavior of the Chinese national oil companies. → China is actively engaging itself in the world oil market. → Shipment data show that China can no longer be regarded as a separate market. → Strong co-movement between the Chinese oil price and the international oil prices.

Dominant Middle East oil reserves critically important to world supply

International Nuclear Information System (INIS)

Riva, J.P. Jr.

1991-01-01

This paper reports that the location production, and transportation of the 60 million bbl of oil consumed in the world each day is of vital importance to relations between nations, as well as to their economic wellbeing. Oil has frequently been a decisive factor in the determination of foreign policy. The war in the Persian Gulf, while a dramatic example of the critical importance of oil, is just the latest of a long line of oil-influenced diplomatic/military incidents, which may be expected to continue. Assuming that the world's remaining oil was evenly distributed and demand did not grow, if exploration and development proceeded as efficiently as they have in the U.S., world oil production could be sustained at around current levels to about the middle of the next century. It then would begin a long decline in response to a depleting resource base. However, the world's remaining oil is very unevenly distributed. It is located primarily in the Eastern Hemisphere, mostly in the Persian Gulf, and much is controlled by the Organization of Petroleum Exporting Countries. Scientific resource assessments indicate that about half of the world's remaining conventionally recoverable crude oil resource occurs in the Persian Gulf area. In terms of proved reserves (known recoverable oil), the Persian Gulf portion increase to almost two-thirds

Stabilizing effect of epoxidized sunflower oil as a secondary stabilizer for Ca/Hg stabilized PVC

Directory of Open Access Journals (Sweden)

2008-01-01

Full Text Available Unsaturated triglyceride oil sunflower was epoxidized and characterized by chemical and spectroscopic methods. Epoxidized sunflower oil (ESO was used as an organic thermal co-stabilizer for rigid poly(vinyl chloride (PVC in the presence of tricalcium dicitrate (Ca3(C6H5O72 and mercury (II acetate (Hg(CH3COO2. The thermo-oxidative degradation of PVC was studied in the presence of these ternary stabilizer systems at 170, 180, 190 and 200°C in N2 atmosphere. The effects of metal carboxylate combination Ca/Hg in the absence and in the presence of epoxidized sunflower oil on static heat treatment of PVC have been studied. The formation of polyene sequences was investigated by UV-visible and FT-IR spectroscopy and by comparing viscosity data obtained in the presence and in the absence of the additives. It was found that the additives retard the rate of degradation and reduce the extent of polymer chain scission associated with the thermal degradation of poly(vinyl chloride. Synergistic effects were found when stabilizer was blended in 50:50 weight ratios with either. It was found that ESO exerted a stabilizing effect on the degradation of PVC. The activation energy for degraded PVC in absence of stabilizers was 38.6 kJ•mol–1 and in the presence of Ca/Hg and Ca/Hg/ESO were 53.3 and 64.7 kJ•mol–1 respectively. In order of compare the efficiency of the epoxidized sunflower oil with these metal soap stabilizers, thermal stabilities were evaluated on the basis of evolved hydrogen chloride determined by conductometry technique and degree of discoloration are discussed.

Oxidative stability of pullulan electrospun fibers containing fish oil

DEFF Research Database (Denmark)

García Moreno, Pedro Jesús; Damberg, Cecilie; Chronakis, Ioannis S.

2017-01-01

The effect of oil content and addition of natural antioxidants on the morphology and oxidative stability of pullulan ultra-thin fibers loaded with fish oil and obtained by electrospinning was investigated. Pullulan sub-micron fibers containing 10 and 30wt% fish oil were prepared and both presented...... into food matrices. These results show the feasibility to encapsulate fish oil in pullulan ultra-thin fibers and to improve their oxidative stability by adding natural antioxidants such as δ-tocopherol and rosemary extract. Therefore, this study might open up new opportunities for further technological...... development in the production of omega-3 nanodelivery systems, which have potential applications in different types of fortified foods. Encapsulation of fish oil in electrospun pullulan fibers stabilized by natural antioxidants....

Oil Prophets: Looking at World Oil Studies Over Time

Energy Technology Data Exchange (ETDEWEB)

Andrews, Steve [Denver, CO (United States); Udall, Randy [Carbondale, CO (United States)

2003-07-01

Early reports of world oil assessments date back to the 1940s. In the intervening 60 years, the number of studies projecting Estimated Ultimately Recoverable (EUR) oil reached well over 50. A detailed search would undoubtedly lengthen the list that will be provided with this paper. How have their estimates fared? Given general agreement that we haven't yet reached the halfway point in eventual production, it's too early to offer definitive assessments. However, several factors stand out: The learning curve. It took over a decade of effort for projections to emerge that are in line with lower-end projections of more recent studies. The learning curve has flattened. For those individuals and groups who conducted multiple studies, their subsequent EUR numbers generally trend higher. The analyses lack a common definitional framework. Beyond crude oil, what liquids are included? Heavy oil and tar sands? Some or all gas liquids? Polar and deepwater oil? While the ability to locate, evaluate and extract oil in the field has drastically improved over time, analysts continue to be hampered by a lack of access to definitive data plus disagreements about assessment methodologies. Striving to determine how many petroleum liquids we have left is a useful exercise, but primarily as a means to help determine when daily worldwide production is likely to peak. To that end, a key point is that 'not all liquids resources are created equal'; many of the larger new fields are located in harsh and remote regions, in politically unstable environments, or require large energy inputs during extraction. Production rates and costs will vary dramatically. Since demand is somewhat fickle, identifying a year or range of years when liquids production will peak qualifies as part art, part science. That said, the paper will list estimates by 'oil prophets' as to when they project that petroleum liquids production will peak. The estimates range from 1995 to 2025. How have their estimates fared

Oilseeds and vegetable oils in asia: a world of diversity

Directory of Open Access Journals (Sweden)

Mittaine Jean-François

2016-11-01

Full Text Available Out of the two dozen countries that constitute what is generally called “Asia”, some are the largest in the world while others are islands with smaller populations. When looking at oilseeds and vegetable oils in the region, one is faced with the same huge diversity which makes it complex to analyze, all the more that statistics are not easily available for many countries. Aside from the large differences in size, the region covers a wide spectrum of diversified climate environments. Asia is also mainly characterized by its huge population which has become largely urban, a key factor leading to the impressive growth of vegetable oil demand in the past 30 years. At an verage of 23.2 kg/year, Asian per capita consumption of oils and fats still remains slightly below the world average of 28.3 kg/capita/year. Therefore, although 53% of the world population is located in Asia, only 45% of world oils and fats is consumed in the region. As detailed in the paper, the world of Asian oilseeds and vegetable oils is highly concentrated on soybeans and palm oil. In spite of a large domestic production in China (12.3 MnT, soybeans are imported in huge quantities, mostly by China (78 MnT, 84% of the region’s imports where more than 28% of world soybeans production is being crushed. Palm oil, the second large commodity consumed in the region, is mainly produced within the region, mostly in Indonesia and Malaysia. So where is the “world of diversity”? Hidden behind those two dominant commodities, practically all of the ten oilseeds constituting the core of the world production are grown in significant quantities in the region while, for vegetable oils, all those of significant importance are produced within the region with the exception of olive oil. The main question that should be kept in mind when reviewing this large regional demand is under what condition will future vegetable oil production be able to meet the expected rise of per capita oils and

World oil prices, precious metal prices and macroeconomy in Turkey

International Nuclear Information System (INIS)

Soytas, Ugur; Sari, Ramazan; Hammoudeh, Shawkat; Hacihasanoglu, Erk

2009-01-01

We examine the long- and short-run transmissions of information between the world oil price, Turkish interest rate, Turkish lira-US dollar exchange rate, and domestic spot gold and silver price. We find that the world oil price has no predictive power of the precious metal prices, the interest rate or the exchange rate market in Turkey. The results also show that the Turkish spot precious metals, exchange rate and bond markets do not also provide information that would help improve the forecasts of world oil prices in the long run. The findings suggest that domestic gold is also considered a safe haven in Turkey during devaluation of the Turkish lira, as it is globally. It is interesting to note that there does not seem to be any significant influence of developments in the world oil markets on Turkish markets in the short run either. However, transitory positive initial impacts of innovations in oil prices on gold and silver markets are observed. The short-run price transmissions between the world oil market and the Turkish precious metal markets have implications for policy makers in emerging markets and both local and global investors in the precious metals market and the oil market.

THE WORLD OIL MARKET – STATISTICAL ANALYSIS

Directory of Open Access Journals (Sweden)

Alexandru AnaMaria

2009-05-01

Full Text Available For some countries the oil is the main source of income, while for others it represents the main raw material for energetic needs. Thus, the oil price has major influence on their economies and it is important for them that it stabilizes at a level profit

Oil Prophets: Looking at World Oil Studies Over Time

Energy Technology Data Exchange (ETDEWEB)

Andrews, Steve [Denver, CO (United States); Udall, Randy [Carbondale, CO (United States)

2003-07-01

Early reports of world oil assessments date back to the 1940s. In the intervening 60 years, the number of studies projecting Estimated Ultimately Recoverable (EUR) oil reached well over 50. A detailed search would undoubtedly lengthen the list that will be provided with this paper. How have their estimates fared? Given general agreement that we haven't yet reached the halfway point in eventual production, it's too early to offer definitive assessments. However, several factors stand out: The learning curve. It took over a decade of effort for projections to emerge that are in line with lower-end projections of more recent studies. The learning curve has flattened. For those individuals and groups who conducted multiple studies, their subsequent EUR numbers generally trend higher. The analyses lack a common definitional framework. Beyond crude oil, what liquids are included? Heavy oil and tar sands? Some or all gas liquids? Polar and deepwater oil? While the ability to locate, evaluate and extract oil in the field has drastically improved over time, analysts continue to be hampered by a lack of access to definitive data plus disagreements about assessment methodologies. Striving to determine how many petroleum liquids we have left is a useful exercise, but primarily as a means to help determine when daily worldwide production is likely to peak. To that end, a key point is that 'not all liquids resources are created equal'; many of the larger new fields are located in harsh and remote regions, in politically unstable environments, or require large energy inputs during extraction. Production rates and costs will vary dramatically. Since demand is somewhat fickle, identifying a year or range of years when liquids production will peak qualifies as part art, part science. That said, the paper will list estimates by 'oil prophets' as to when they project that petroleum liquids production will peak. The estimates range from 1995 to 2025. How

Chemical properties and oxidative stability of Arjan (Amygdalus reuteri) kernel oil as emerging edible oil.

Science.gov (United States)

Tavakoli, Javad; Emadi, Teymour; Hashemi, Seyed Mohammad Bagher; Mousavi Khaneghah, Amin; Munekata, Paulo Eduardo Sichetti; Lorenzo, Jose Manuel; Brnčić, Mladen; Barba, Francisco J

2018-05-01

The oxidative stability, as well as the chemical composition of Amygdalus reuteri kernel oil (ARKO), were evaluated and compared to those of Amygdalus scoparia kernel oil (ASKO) and extra virgin olive oil (EVOO) during and after holding in the oven (170 °C for 8 h). The oxidative stability analysis was carried out by measuring the changes in conjugated dienes, carbonyl and acid values as well as oil/oxidative stability index and their correlation with the antioxidant compounds (tocopherol, polyphenols, and sterol compounds). The oleic acid was determined as the predominant fatty acid of ARKO (65.5%). Calculated oxidizability value and an iodine value of ARKO, ASKO and EVOO were reported as 3.29 and 3.24, 2.00 and 100.0, 101.4 and 81.9, respectively. Due to the high wax content (4.5% and 3.3%, respectively), the saponification number of ARKO and ASKO (96.4 and 99.8, respectively) was lower than that of EVOO (169.7). ARKO had the highest oxidative stability, followed by ASKO and EVOO. Therefore, ARKO can be introduced as a new source of edible oil with high oxidative stability. Copyright © 2018. Published by Elsevier Ltd.

The relationship between SARA fractions and crude oil stability

Directory of Open Access Journals (Sweden)

Siavash Ashoori

2017-03-01

Full Text Available Asphaltene precipitation and deposition are drastic issues in the petroleum industry. Monitoring the asphaltene stability in crude oil is still a serious problem and has been subject of many studies. To investigate crude oil stability by saturate, aromatic, resin and asphaltene (SARA analysis seven types of crudes with different components were used. The applied methods for SARA quantification are IP-143 and ASTM D893-69 and the colloidal instability index (CII is computed from the SARA values as well. In comparison between CII results, the values of oil compositions demonstrated that the stability of asphaltenes in crude oils is a phenomenon that is related to all these components and it cannot be associated only with one of them, individually.

Investigation of carrier oil stabilized iron oxide nanoparticles and its ...

African Journals Online (AJOL)

Iron oxide nanoparticles were synthesized by co-precipitation method. The polyunsaturated carrier oil (flaxseed oil) is used as a stabilizing agent for iron oxide nanoparticles. Kirby Bauer method was used to investigate the antibiotic sensitivity of carrier oil stabilized and uncoated SPIONs at 10 and 20 μg/L on Gram-positive ...

The outlook for the world and Australian oil markets

International Nuclear Information System (INIS)

Donaldson, K.; Fok, G.

1996-01-01

Global demand for oil is projected to continue its upward trend to 2000-1, with growth in the transport sector expected to underpin future increases in oil consumption. World oil consumption is projected to be matched by global production, keeping the average annual oil price relatively stable. In many countries, the diversion of oil revenue to other projects is threatening to constrain increases in production capacity, particularly in the OPEC countries. The encouragement of foreign investment in state oil industries is a likely method of easing the constraint. Australian exploration activity is rising steadily with the prospect of stable oil prices, expanding gas markets and the incentives provided by a number of recent discoveries. While the geographical pattern of Australian production has now changed, with Western Australian production exceeding Victoria production, Australia is expected to maintain its position in the world oil market as a significant producer, importer and exporter. (author). 6 figs., 23 refs

Analysis of Saudi Arabia's behavior within OPEC and the world oil market

International Nuclear Information System (INIS)

Alkhathlan, Khalid; Gately, Dermot; Javid, Muhammad

2014-01-01

We analyze oil export behavior by Saudi Arabia and the Rest of OPEC since 1973. In the literature there has been a wide range of estimates of their correlation: from positive, to zero, to negative. We find that the correlation has varied over time, from moderately high (0.7) in normal periods, to negative during each of five interruptions; the average correlation has been 0.19. Saudi Arabia's oil market behavior depends upon circumstances, but its primary goal is the stability of OPEC and the world oil market. It will coordinate export reductions with the Rest of OPEC when faced with declining demand, but it will increase exports when faced with interruptions elsewhere in OPEC. Allowing for such differences provides evidence of intelligent, context-dependent consistency. But ignoring context – by wrongly assuming the same Saudi response in Normal periods and Interruptions – can lead to a conclusion of Saudi “inconsistency” because the difference in the responses has been obscured

Effect of unsaponifiable matter extracted from Pistacia khinjuk fruit oil on the oxidative stability of olive oil.

Science.gov (United States)

Tavakoli, Javad; Estakhr, Parviz; Jelyani, Aniseh Zarei

2017-08-01

The present study was carried out to investigate the improvement of oxidative stability of refined olive oil using various concentrations of unsaponifiable matters extracted from Pistacia khinjuk fruit oil (UFO). For further elucidation of UFO antioxidative power, tertbutylhydroquinone (TBHQ) was used in an olive oil sample, too. Oxidative stability of olive oil samples without and with different levels of UFO (50, 100, 250, 500, 750 and 1000 ppm) and TBHQ (100 ppm) were studied via evaluation of conjugated diene value, carbonyl value, oil/oxidative stability index, acid value and total tocopherol (TT) contents through 8 h thermal process at 170 °C. Results obtained by oxidative stability assays revealed that the highest antioxidative activity of olive oil was obtained by 100 ppm of UFO, followed using 100, 250, 500, 750, and 1000 ppm of UFO and 100 ppm TBHQ, respectively. Evaluation of the relationship between oxidative stability indexes and TT changes indicated a strong correlation (R 2  = 0.9718) between mean relative resistance to oxidation and relative resistance to TT reduction during thermal process. By promotion of relative resistance to TT reduction, olive oil samples' relative resistance to oxidation was enhanced exponentially; implying importance of TT in promotion of oxidative stability of edible oils. The results obtained in this study showed that UFO has higher antioxidative activity compared to TBHQ; thus UFO can be considered as a natural antioxidant with ideal antioxidative activity.

World oil flow slips in 1991 amid Mideast, U.S.S.R. woes

International Nuclear Information System (INIS)

Beck, R.J.

1992-01-01

World crude oil production slipped 0.9% in 1991 to average 59,964 million b/d. This paper reports that production declines related to war damage in Kuwait, United Nations sanctions on exports from Iraq, and oil sector woes in the crumbling U.S.S.R. were almost offset by higher production from other members of the Organization of Petroleum Exporting Countries. OPEC crude production rose 0.6% in 1991 to average 23.425 million b/d, and non-OPEC output fell 1.9% to average 36.539 million b/d in 1991. Excluding the U.S.S.R., non-OPEC production moved up 1.5% to average 26.239 million b/d. World demand inched up about 200,000 b/d, estimates International Energy Agency, and IEA data show about 300,000 b/d was added to stocks in 1991. World crude prices started 1991 at their highest level, then fell off to average $17.82/bbl, down 16.5% from 1990 levels. Meantime, a slight increase in demand is predicted for 1992, and price stability again hinges on OPEC's ability to limit production

Stability Proxies for Water-in-Oil Emulsions and Implications in Aqueous-based Enhanced Oil Recovery

Directory of Open Access Journals (Sweden)

Mehrnoosh Moradi

2011-07-01

Full Text Available Several researchers have proposed that mobility control mechanisms can positively contribute to oil recovery in the case of emulsions generated in Enhanced-Oil Recovery (EOR operations. Chemical EOR techniques that use alkaline components or/and surfactants are known to produce undesirable emulsions that create operational problems and are difficult to break. Other water-based methods have been less studied in this sense. EOR processes such as polymer flooding and LoSalTM injection require adjustments of water chemistry, mainly by lowering the ionic strength of the solution or by decreasing hardness. The decreased ionic strength of EOR solutions can give rise to more stable water-in-oil emulsions, which are speculated to improve mobility ratio between the injectant and the displaced oil. The first step toward understanding the connection between the emulsions and EOR mechanisms is to show that EOR conditions, such as salinity and hardness requirements, among others, are conducive to stabilizing emulsions. In order to do this, adequate stability proxies are required. This paper reviews commonly used emulsion stability proxies and explains the advantages and disadvantage of methods reviewed. This paper also reviews aqueous-based EOR processes with focus on heavy oil to contextualize in-situ emulsion stabilization conditions. This context sets the basis for comparison of emulsion stability proxies.

Oxidative Stability of Nano-Microstructures containing fish oil

DEFF Research Database (Denmark)

García Moreno, Pedro Jesús; Özdemir, N.; Boutrup Stephansen, Karen

investigated. For that purpose, three different biopolymers namely pullulan, dextran and whey protein concentrate (WPC) were evaluated as encapsulating materials. First, the influence of biopolymer concentration on the physical properties (e.g. viscosity, conductivity and surface tension) of the biopolymer...... solutions and on the morphology of NMS was assayed. Secondly, the oxidative stability of the biopolymer solutions containing emulsified fish oil during storage (14 days at 40 °C) and of NMS loaded with fish oil (e.g. pullulan fibers and dextran and WPC capsules) was determined. Finally, to improve...... the oxidative status of the NMS, pullulan fibers, dextran capsules and WPC capsules were produced by adding neat fish oil instead of emulsified fish oil to the biopolymer solutions. These latter NMS presented a higher oxidative stability, which may be due to a better entrapment of the fish oil into biopolymer...

Oxidative Stability and Shelf Life of Foods Containing Oils and Fats

DEFF Research Database (Denmark)

and oils and fats-containing foods in the food and pet food industries. Discusses oxidative stability and shelf life of low-moisture (dry) food, including dry pet food. Discusses lipid co-oxidation with protein because a number of food products contain both lipids and proteins. Directed mainly toward......Oxidative Stability and Shelf Life of Foods Containing Oils and Fats focuses on food stability and shelf life, both important factors in the improvement and development of food products. This book, relevant for professionals in the food and pet food industries, presents an evaluation of methods...... for studies on the oxidative stability and shelf life of bulk oils/fats, fried oils and foods, food emulsions, dried foods, meat and meat products, and seafood in food and pet food. Focuses on the application of various evaluation methods to studies of oxidative stability and shelf life in oils and fats...

Proceedings of the CERI 2001 World Oil Conference. CD ed.

International Nuclear Information System (INIS)

2001-01-01

The integration and expansion of world oil markets was the main topic of this conference which featured 23 presentations dealing with developments in the international energy sector. The conference was divided into 8 sessions entitled: (1) oil prices, (2) oil and politics, (3) global oil supply, (4) North American supply and markets, (5) global oil demand, (6) oil.com, (7) the business of the environment, and (8) oil and money. The outlook of world energy markets was reviewed with particular emphasis on prospects for oil supply and reserves. The current status of the petroleum industry in both OPEC and non-OPEC oil exporting countries was discussed with reference to exploration, production, reserves, and hydrocarbon potential. The environmental, and socio-economic challenges that both the upstream and downstream industry will face challenges in the next century were also described. refs., tabs., figs

Changes in the world market in oil and oil refinements

International Nuclear Information System (INIS)

Ristik, Julija

1996-01-01

Since 1980's the world market for crude oil and oil products has faced significant changes that are going to have a grate influence on the supply and consumption of crude oil derivatives in Macedonia. The knowledge of these changes would have a grate contribution in planning the future development of this part of the energetic system of Macedonia. The purpose of this paper (which is a short version of the introductory report for the ZEMAK session with a theme 'Energetic policy and development of energetics in Macedonia') is to present the actual situation on the market for crude oil products, as well as to give the main factors that would have influence on this market in the future. (author). 4 refs., 3 ills

Stabilization of soybean oil during accelerated storage by essential oil of ferulago angulata boiss.

Science.gov (United States)

Sadeghi, Ehsan; Mahtabani, Aidin; Etminan, Alireza; Karami, Farahnaz

2016-02-01

This study has been considered effect of Ferulago angulata essential oil on stabilizing soybean oil during accelerated storage. The essential oil was extracted by Clevenger-type apparatus. For analysis of the essential oil, GC/MS was used. Main components of the essential oil were monoterpene and sesquiterpene hydrocarbons. The essential oil of F. angulata at four concentrations, i.e. 125 (SBO-125), 250 (SBO-250), 500 (SBO-500) and SBO-Mixture (60 ppm TBHQ +60 ppm essential oil) were added to preheated refined soybean oil. TBHQ was used at 120 ppm as standard besides the control. Antioxidant activity index (AAI), free fatty acid (FFA) content, peroxide value (PV) and p-anisidine value (p-AnV) were served for appreciation of efficacy of F. angulata in stabilization of soybean oil. Results from different tests showed that SBO-mixture had highest effect and followed by SBO-TBHQ, SBO-250, SBO-125, SBO-500 and Ctrl. These results reveal F. angulata is a strong antioxidant and can be used instead of synthetic antioxidant.

Oxidative stability of diacylglycerol oil and butter blends containing diacylglycerols

DEFF Research Database (Denmark)

Kristensen, Janni Brogaard; Nielsen, Nina Skall; Jacobsen, Charlotte

2006-01-01

Diacylglycerol (DAG) oils produced from sunflower oil and traditional sunflower oil were stored for 20 wk at 38 degrees C, and their oxidative stability was measured. Moreover, two butter blends were produced containing 40 wt-% DAG oil made from sunflower oil or rapeseed oil, respectively, as well...... as two control butter blends with sunflower oil or rapeseed oil. Their oxidative stability during storage at 5 degrees C for up to 12 wk was examined by similar means as for the pure oils. The storage study of the oils indicated that the DAG oil was oxidatively less stable as compared to sunflower oil......, but that they had similar sensory quality. Storage of the butter blends revealed that blends with the two types of rapeseed oil (triacylglycerol (TAG) or DAG oil) were oxidatively more stable than the blends containing oils from sunflower. There was no unambiguous indication of DAG butter blends having a different...

Peaking of world oil production: Impacts, mitigation, & risk management

Energy Technology Data Exchange (ETDEWEB)

Hirsch, R.L. (SAIC); Bezdek, Roger (MISI); Wendling, Robert (MISI)

2005-02-01

The peaking of world oil production presents the U.S. and the world with an unprecedented risk management problem. As peaking is approached, liquid fuel prices and price volatility will increase dramatically, and, without timely mitigation, the economic, social, and political costs will be unprecedented. Viable mitigation options exist on both the supply and demand sides, but to have substantial impact, they must be initiated more than a decade in advance of peaking.... The purpose of this analysis was to identify the critical issues surrounding the occurrence and mitigation of world oil production peaking. We simplified many of the complexities in an effort to provide a transparent analysis. Nevertheless, our study is neither simple nor brief. We recognize that when oil prices escalate dramatically, there will be demand and economic impacts that will alter our simplified assumptions. Consideration of those feedbacks will be a daunting task but one that should be undertaken. Our aim in this study is to-- • Summarize the difficulties of oil production forecasting; • Identify the fundamentals that show why world oil production peaking is such a unique challenge; • Show why mitigation will take a decade or more of intense effort; • Examine the potential economic effects of oil peaking; • Describe what might be accomplished under three example mitigation scenarios. • Stimulate serious discussion of the problem, suggest more definitive studies, and engender interest in timely action to mitigate its impacts.

The hydrocarbon era, world population growth and oil use -- a continuing geological challenge

International Nuclear Information System (INIS)

Townes, H.L.

1993-01-01

The world's use of oil, the relationship of world population growth to this use, and what the energy situation might be in the future is a challenge to the geologist. The earth's population doubled between 1930 and 1975 and a comparison of world petroleum use and population growth show similar upward curves. Of the annual fossil fuel resources used in the world, crude oil supplies over 40 percent of the total resources. Petroleum is a finite resource and a projection of world oil production indicates it will peak early in the 21st century. Assuming an ultimate recovery range of 2600 to 3000 billion barrels of oil, 750 billion barrels have already been produced, there are 1000 billion barrels in proven reserves, and 1000 billion barrels remaining to be discovered. The challenge to the geologist will be to find these hidden oil reserves. Recovering this 1000 billion barrels of new oil reserves will require large capital expenditures and, currently, only 60 percent of the capital needed to discover this oil is being spent. With the world's demand for oil increasing, world-wide exploration expenditures are actually decreasing. Simple economics indicates that the reason for this drop in expenditures is that the price of oil is too low to encourage investment. Low oil prices also discourage investment in the development of alternative fuels. There is plenty of oil now, but the world must look to the future and realize present usage rate cannot continue forever. 23 refs., 10 figs

The united states and the world oil security. US oil policy and production of a global collective good

International Nuclear Information System (INIS)

Noel, P.

2004-07-01

The aim of this paper is to define and discusses the part of the Unites States in the world oil system operating and more particularly the US oil security policy in the world policy. It refutes some established ideas as the necessity of the US military supremacy to provide the oil security, the necessity of ''agreements'' with oil exporting countries facing the US energy consumption increase or the limitation of the resources access to other countries. At the opposite the United States seem to invest in the production of a global public good in matter of energy security. In order to illustrate this opinion the author defines the problem of the US oil security in a world context. He analyzes then the US policies to show the impacts in the world oil security and studies the specific part of the military factor in the security policy. (A.L.B.)

Antioxidant Effect on Oxidation Stability of Blend Fish Oil Biodiesel with Vegetable Oil Biodiesel and Petroleum Diesel Fuel

Directory of Open Access Journals (Sweden)

M. Hossain

2013-06-01

Full Text Available Two different phenolic synthetic antioxidants were used to improve the oxidation stability of fish oil biodiesel blends with vegetable oil biodiesel and petroleum diesel. Butylhydroxytoluene (BHT most effective for improvement of the oxidation stability of petro diesel, whereas  tert-butylhydroquinone (TBHQ showed good performance in fish oil biodiesel. Fish oil/Rapeseed oil biodiesel mixed showed some acceptable results in higher concentration ofantioxidants. TBHQ showed better oxidation stability than BHT in B100 composition. In fish oil biodiesel/diesel mixed fuel, BHT was more effective antioxidant than TBHQ to increase oxidationstability because BHT is more soluble than TBHQ. The stability behavior of biodiesel/diesel blends with the employment of the modified Rancimat method (EN 15751. The performance ofantioxidants was evaluated for treating fish oil biodiesel/Rapeseed oil biodiesel for B100, and blends with two type diesel fuel (deep sulfurization diesel and automotive ultra-low sulfur or zero sulfur diesels. The examined blends were in proportions of 5, 10, 15, and 20% by volume of fish oilbiodiesel.

Oil-in-Water Emulsions Stabilized by Saponified Epoxidized Soybean Oil-Grafted Hydroxyethyl Cellulose.

Science.gov (United States)

Huang, Xujuan; Li, Qiaoguang; Liu, He; Shang, Shibin; Shen, Minggui; Song, Jie

2017-05-03

An oil-in-water emulsion stabilized by saponified epoxidized soybean oil-grafted hydroxyethyl cellulose (H-ESO-HEC) was investigated. By using an ultrasonic method, oil-in-water emulsions were prepared by blending 50 wt % soybean oil and 50 wt % H-ESO-HEC aqueous suspensions. The influence of H-ESO-HEC concentrations on the properties of oil-in-water emulsions was examined. The H-ESO-HEC concentrations in the aqueous phase varied from 0.02 to 0.40 wt %. When the H-ESO-HEC concentration was 0.4 wt %, the emulsion remained stable for >80 days. The mean droplet sizes of the emulsions decreased by increasing the H-ESO-HEC concentration and extending the ultrasonic time. The adsorption amounts of H-ESO-HEC at the oil-water interface increased when the H-ESO-HEC concentrations in the aqueous phase increased. The rheological property revealed that the apparent viscosity of the H-ESO-HEC-stabilized oil-in-water emulsions increased when the H-ESO-HEC concentrations increased. Steady flow curves indicated an interfacial film formation in the emulsions. The evolution of G', G″, and tan η indicated the predominantly elastic behaviors of all the emulsions.

Markets during world oil supply crises: an analysis of industry, consumer, and governmental response

Energy Technology Data Exchange (ETDEWEB)

Erfle, Stephen; Pound, John; Kalt, Joseph

1981-04-01

An analysis of the response of American markets to supply crises in world oil markets is presented. It addresses four main issues: the efficiency of the operation of American oil markets during oil supply crises; the problems of both economic efficiency and social equity which arise during the American adaptation process; the propriety of the Federal government's past policy responses to these problems; and the relationship between perceptions of the problems caused by world oil crises and the real economic natures of these problems. Specifically, Chapter 1 presents a theoretical discussion of the effects of a world supply disruption on the price level and supply availability of the world market oil to any consuming country including the US Chapter 2 provides a theoretical and empirical analysis of the efficiency of the adaptations of US oil product markets to higher world oil prices. Chapter 3 examines the responses of various groups of US oil firms to the alterations observed in world markets, while Chapter 4 presents a theoretical explanation for the price-lagging behavior exhibited by firms in the US oil industry. Chapter 5 addresses the nature of both real and imagined oil market problems in the US during periods of world oil market transition. (MCW)

Oil, Security, and the Post-9/11 World

National Research Council Canada - National Science Library

Hermsmeyer, Gregory

2002-01-01

The September 11, 2001, terrorist attacks did not directly threaten world oil supplies, but they exposed the long-term danger of relying on an energy source found chiefly in one of the world's most explosive regions...

Present status on world alternative energy developments to oil

International Nuclear Information System (INIS)

Reddington, J.

1980-01-01

The IEA was established about five years ago in the OECD immediately after the oil crisis, and 20 countries have participated in it. Progress was observed in the control of the expansion of energy demand. The energy utilization in IEA member countries became efficient due to the contribution of new technologies, and owing to the improvement of productivity, the growth of energy consumption was less than 1% despite the GDP grew at the yearly rate of 2.5%. The expansion of the utilization of natural gas and coal is promising, but the projects of nuclear power generation are behind schedule. The short term prospect in petroleum market is discussed, and the price of crude oil tends to be stabilized. ''The prospect of energy in the world by 2000'' will be published by the IEA in the latter half of 1980. The scale of the development of nuclear power generation was reduced because the prediction of the rate of power generation growth was changed from 5.2% to 3.1%. The effect of new energy technologies on future energy market has been studied by the support of 15 countries, and it was recommended to give financial aid to heat pumps, coal liquefaction and the efficient recovery of oil and natural gas. Also the techniques for operating existing facilities under strict environment and safety regulations have been studied. (Kako, I.)

Comparison of Oxidation Stability and Quenchant Cooling Curve Performance of Soybean Oil and Palm Oil

Science.gov (United States)

Said, Diego; Belinato, Gabriela; Sarmiento, Gustavo S.; Otero, Rosa L. Simencio; Totten, George E.; Gastón, Analía; Canale, Lauralice C. F.

2013-07-01

The potential use of vegetable oil-derived industrial oils continues to be of great interest because vegetable oils are relatively non-toxic, biodegradable, and they are a renewable basestock alternative to petroleum oil. However, the fatty ester components containing conjugated double bonds of the triglyceride structure of vegetable oils typically produce considerably poorer thermal-oxidative stability than that achievable with petroleum basestocks under typical use conditions. Typically, these conditions involve furnace loads of hot steel (850 °C), which are rapidly immersed and cooled to bath temperatures of approximately 50-60 °C. This is especially true when a vegetable oil is held in an open tank with agitation and exposed to air at elevated temperatures for extended periods of time (months or years). This paper will describe the thermal-oxidative stability and quenching performance of soybean oil and palm oil and the resulting impact on the heat transfer coefficient. These results are compared to typical fully formulated, commercially available accelerated (fast) and an unaccelerated (slow) petroleum oil-based quenchants.

Oil markets and prices: the Brent market and the formation of world oil prices

International Nuclear Information System (INIS)

Horsnell, Paul; Mabro, Robert.

1993-01-01

The purpose of this book is to enhance our understanding of the complex working of the world petroleum market and of the formation of oil prices in international trade. It devotes particular attention to the Brent market which involves spot, physical forward and futures trading of a blend of North Sea crudes known as Brent which has become one of the most important markers for world oil prices. Because the Brent market is central the research presented here examines its relationship to the constellation of other oil markets: those which deal on a spot basis with the main export crude of Africa, the Gulf, the Far East and the North Sea, the market for Dubai, another marker crude, and that for West Texas Intermediate (WTI). Finally an analysis of pricing mechanisms used by OPEC and many non-OPEC exporting countries for their oil sales under term contracts and which use Brent prices as one of their references complete this study on oil markets and prices. (author)

Kolkhoung (Pistacia khinjuk Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability and Nutritional Value

Directory of Open Access Journals (Sweden)

Maryam Asnaashari

2015-01-01

Full Text Available In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high–performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well-balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation–sensitive oils to improve their shelf life.

Angola: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that prospects of Angola, free of political complications, are certain to bring a flurry of interest from oil firms and could mean an influx of foreign capital. Licensing will be under production-sharing terms, but incentives may be offered due to increased risks inherent in deeper water. Long term security and stability remain uncertain. In addition to Unita and previously communist MPLA, new factions from 16 years of civil war are gaining support and increasing possibilities for violence. Oil firms consider production-sharing terms high and current price cap clauses keep them from realizing benefits from price increases after contracts are signed. However, geology and exploration successes have overshadowed concerns

Kolkhoung (Pistacia khinjuk) Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability 
and Nutritional Value.

Science.gov (United States)

Asnaashari, Maryam; Hashemi, Seyed Mohammad Bagher; Mehr, Hamed Mahdavian; Yousefabad, Seyed Hossein Asadi

2015-03-01

In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high-performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel) and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well--balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation-sensitive oils to improve their shelf life.

Improving oxidative stability of liquid fish oil supplements for pets

DEFF Research Database (Denmark)

Thomsen, Birgitte Raagaard; Griinari, Mikko; Jacobsen, Charlotte

2017-01-01

oxidative stability to the same extent as 2000 ppm mixed tocopherols in Oxipres. Overall, oxidative stability of fish oil or fish oil + vegetable oil blends was improved the most by addition of 5000 ppm rosemary extract and 500 ppm mixed tocopherols. A commercial oil blend with composition optimized based...... of fish oil by adding vegetable oils, mixed tocopherols and rosemary extract, and to formulate a commercial product according to the results obtained. The formulated product was evaluated against commercial fish oil products. An initial screening for antioxidative effect was performed by using Oxipres...... equipment. The effect of antioxidant and vegetable oil blends was examined in oils stored at 30 and 40°C by measuring peroxide value, volatile compounds with GC-MS and tocopherol content. Addition of vegetable oil and rosemary extract at high level (4000–6000 ppm) plus 600 ppm of mixed tocopherols increased...

Future Oil and Gas Resources of the World: A Coming Supply Crisis?

Science.gov (United States)

Ahlbrandt, T. S.

2002-05-01

Is the world running out of oil? Where will future oil and gas supplies come from? To help answer these questions, the U.S. Geological Survey completed in 2000 a new assessment of the undiscovered conventional oil and gas resources and potential additions to reserves from field growth. One hundred and twenty-eight provinces were assessed in a 100 man-year effort from 1995-2000. The assessed provinces included 76 priority provinces containing 95 percent of the world's discovered oil and gas and an additional 52 "boutique" provinces, many of which may be highly prospective. Total Petroleum Systems (TPS) were identified and described for each of these provinces along with associated Assessment Units (AU) that are the basic units for assessing undiscovered petroleum. The assessment process coupled geologic analysis with a probabilistic methodology to estimate remaining potential. Within the 128 assessed provinces, were 159 TPS and 274 AU. For these provinces, the endowment of recoverable oil, which includes cumulative production, remaining reserves, reserve growth, and undiscovered resources is estimated at about 3 trillion barrels of oil (TBO). The natural gas endowment is estimated at 2.6 trillion barrels of oil equivalent (TBOE). Oil reserves are currently 1.1 TBO; world consumption is about .028 TBO per year. Natural gas reserves are about .8 TBOE; world consumption is about .014 TBOE. Thus, without any additional discoveries of oil, gas or natural gas liquids, we have about 2 TBOE of proved petroleum reserves. Of the oil and gas endowment of about 5.6 TBOE, we estimate that the world has consumed about 1 TBOE, or 18 percent leaving about 82 percent of endowment to be utilized or found. Half of the world's undiscovered potential is offshore. Arctic basins with about 25 percent of undiscovered petroleum resources make up the next great frontier. An additional 279 provinces contain some oil and gas and, if considered, would increase the oil and gas endowment

Stability of traditionally processed vegetable oils and their blends ...

African Journals Online (AJOL)

The objective of the study was to investigate the stability of traditionally processed palm oil (PO), sunflower oil (SO) and sesame oil (SSO) and their blends as function of storage conditions by analysing their physicochemical properties which included acid value, saponification value, peroxide value, iodine value and ...

China's new oil import status underpins world's most dynamic petroleum scene

International Nuclear Information System (INIS)

Anon.

1994-01-01

China is poised to become a net importer of oil in 1994--95. That sets the stage for China importing more than 1 million b/d of crude oil and refined products on a net basis by the turn of the century. That development underpins a bigger story -- arguably the biggest story on the petroleum scene today. The turnabout that is seeing the world's fifth biggest oil producer go from significant oil exporter in recent years to major oil importer by the turn of the century points to several other truisms in the petroleum industry: That an oil demand surge in the Asia-Pacific region led by China will fuel overall world oil demand growth for years to come; that a refining and petrochemical boom in a country that accounts for about one fifth of the world's population has dramatic implications for those two industries; that privatization has gathered so much momentum in the global petroleum industry that even Communist China has embraced some form of it; that China's domestic crude supply shortfall is creating unprecedented opportunities for foreign upstream investors in one of the world's most prospective yet underexplored and underexploited regions; and that the same new openness that is distinguishing China's petroleum industry today is turning some of its state owned companies into major competitors to be reckoned with on the international scene, upstream and downstream. The paper discusses China's oil export/import balance, supply/demand outlook, policy changes, and new regulations governing export of crude oil and products

Energetic dependency on the oil reserve- resources of crude oil in the world

Directory of Open Access Journals (Sweden)

Marína Sidorová

2006-10-01

Full Text Available Crude oil belongs to the most important energy resources nowadays., However its reserves are the smallest in comparison with other energy resources as coal, gas or uranium. The world oil consumption continuously increases and within 20-year period there could be about one third. So, the consumption of combustibles will probably increase and the reserves will decrease. Promising are new resources or a better utilization of primary sources. It´s a question of a short time when world scientists should think about this indisputably worldwide problem and would provide an equivalent substitution with an available ecological solution.

World oil: the growing case for international policy

International Nuclear Information System (INIS)

Chapman, D.; Khanna, N.

2000-01-01

Can the economic theory of depletion be reconciled with low petroleum prices? This article uses a revision of the theory, which reflects demand functions that rise in response to increasing world population and income. The magnitude of producers' and consumers' surplus is estimated under both competitive and monopolistic assumptions; the result indicates a present value comparable to or in excess of today's gross world economic product. Game theory suggests a framework that explains the interaction between oil pricing and military policy, and the economic incentives that result in a general pattern of recent market equilibrium crude oil prices often fluctuating with a 15-20 US dollars per barrel range. The analysis concludes that the economic incentives for political instability in the Persian Gulf will increase, and more formal methods of setting the international framework for Persian Gulf oil may be expected. (author)

Study of the oxidative stability of oils vegetables for production of Biodiesel

Directory of Open Access Journals (Sweden)

Marco Aurélio R Melo

2014-04-01

Full Text Available Biodiesel is technological and estrategical Brazilian oportunity once this country has abundant vegetable species which oils are extracted to produce this biofuel. Oleaginous viability depends on its technical, economical and social-environmental competitiviness. Fatty acid variety determines its thermal and oxidative stability, mainly polyunsaturated ones. In this point of view, this papers aims evaluate oxidative stability and resistence to thermal decomposition of pequi, buriti and macauba oils. These fatty acids profiles are in agreement with literature data. Comparing thermal and oxidative stability of these oils, it can be seen pequi oil is more easily to oxidate than buriti and macauba oils when PetroOXY and Rancimat methods are employed.

Is the world oil market 'one great pool'? A test

International Nuclear Information System (INIS)

Rodriguez, A.E.; Williams, M.D.

1993-01-01

In a recent paper (Weiner, 1991) it was argued that crude oil markets are regionalized, thus challenging the assertion that the world oil market is homogeneous. This argument bears on the effectiveness of various energy policies. It is argued that these policies should be analyzed using constructs such as antitrust markets, rather than in relation to an ad-hoc definition of regionalization like that used by Weiner. Regionalization and geographic antitrust markets, empirics, and policy implications of regional markets are discussed. By drawing clear parallels between the concept of regionalization and antitrust markets, it is shown that: due to Wiener's flawed methodological and empirical approach, it is not clear that crude oil markets are, in fact, regional; and policies that appear at first glance to require regional markets to be effective, may be explained even in a unified world market. Strong evidence is found in support of a unified world oil market. Some policy implications in the area of import taxes are discussed. 35 refs., 1 tab

Oxidative stability of fish oil enriched drinking yoghurt

DEFF Research Database (Denmark)

Nielsen, Nina Skall; Debnath, D.; Jacobsen, Charlotte

2007-01-01

The oxidative stability of fish oil enriched drinking yoghurt as well as the antioxidative effect of citric acid ester, vitamin K and disodium ethylenediaminetetraacetic acid (EDTA) were investigated by measuring peroxide value and volatile secondary oxidation products and by sensory analysis....... No oxidation was observed in yoghurt stored at 2 [degree sign]C for up to 19 days, with or without addition of citric acid ester. Fish oil enriched yoghurt was also very stable even when compared to yoghurt with added rapeseed oil or a mixture of rapeseed oil and fish oil stored for up to 29 days. The addition...

Effects of processing techniques on oxidative stability of Prunus pedunculatus seed oil

Directory of Open Access Journals (Sweden)

J. Yan

2017-09-01

Full Text Available This paper investigated the effects of Prunus pedunculatus (P. pedunculatus seed pre-treatment, including microwaving (M, roasting (R, steaming (S and roasting plus steaming (RS on crude oil quality in terms of yield, color change, fatty acid composition, and oxidative stability. The results showed an increase in monounsaturated fatty acid content and oxidative stability of the oils obtained from different processing treatments compared to the oil obtained from raw seeds (RW without processing. The oils, obtained from pretreated seeds, had higher conjugated diene (CD and 2-thiobarbituric acid (2-TBA values, compared to that obtained from RW when stored in a Schaal oven at 65 °C for 168 h. However, polyphenol and tocopherol contents decreased in all oil samples, processed or unprocessed. The effect of pre-treating the seeds was more prominent in the oil sample obtained through the RS technique, and showed higher oxidative stability than the other processed oils and the oil from RW.

Oil turbulence in the next decade. An essay on high oil prices in a supply-constrained world

International Nuclear Information System (INIS)

Jesse, J.H.; Van der Linde, C.

2008-06-01

A CIEP analysis of the recent development of demand and supply for crude oil indicates that the mismatch in supply and demand growth could cause tighter oil markets than we already experience today. In the World Energy Outlook 2007, the International Energy Agency (IEA) warned of a possible 'energy crunch'. But what was anticipated to happen in the first part of the next decade has been fast-forwarded to today, more than 5 years earlier, and could shake the very foundation of our energy systems if no action is undertaken. Without exaggeration, the recent developments in the international oil market are ground-breaking: a little over a year ago, in January 2007, the West Texas Intermediate crude oil price (WTI) traded for USD50 dollar a barrel. Within a year, the price doubled to USD100 per barrel in January 2008 and pushed through to over USD135 in June 2008, against the backdrop of the fresh market supposition about reaching a whopping USD200 per barrel in 2009. If this proves to be true, the world will not only have moved from an 'Oil Demand-led World' to an 'Oil Supply-constrained World' (since 2004) but, more importantly, will then also experience a radical change in the oil price formation. Until recently, the oil price was largely underpinned by the marginal cost of the last barrel needed to match demand, with some political and economic conjuncture mark-ups or -downs. As will be presented in this paper, the current high oil prices are still primarily driven by structural factors that can be well explained without resorting to blaming speculative investors playing the futures market or the low dollar. But if prices are heading towards USD200 a barrel in 12 months' time, or for that matter even to USD150 a barrel, other drivers will gain prominence over marginal costs as the main driver. In that case, OPEC will have accomplished a long-held wish: oil will then be priced at its real value in the Western world (for instance the economic value of mobility for

Oil and gas financing by the World Bank

International Nuclear Information System (INIS)

Razavi, Hossein

1995-01-01

The World Bank has developed a flexible oil and gas programme that is structured to meet the changing needs of the sector as they arise. The Bank became prominent in the oil and gas sector after the oil crises of the 1970s, when it began assisting client countries in developing their indigenous energy resources. At the beginning, Bank lending concentrated on exploration and development of hydrocarbon resources where the level of lending expanded to US$1 billion in 1983. This rapid expansion caused some concern that Bank activities might preempt those of the private sector. In response, the Bank imposed in 1984 strict limitations on petroleum exploration and oil production lending. In combination with the perception that future oil demand would be weak, this caused the lending programme to fall off sharply (to US$300 million by 1986). By 1990, the Bank was again moving actively into hydrocarbon sector lending, but then the emphasis was on promoting private sector development and supporting the development of natural gas as a substitute for coal and oil. Bank lending to the sector has been on the increase since 1990; a lending level of about US$1 billion yearly is expected for the second half of the 1990s. In addition to its direct lending, the World Bank facilitates contributions by other financiers through its cofinancing and risk mitigation arrangements. (author)

One-day stability test for distillate fuel oils

Energy Technology Data Exchange (ETDEWEB)

Gyrath, F W; Dunn, Jr, F R; Smith, Jr, A C

1958-08-01

A one-day stability test is described. One liter of oil was placed in a glass bottle along with several steel strips, the bottle was purged with oxygen, sealed, and placed in an oven at 100/sup 0/C (212/sup 0/F) for 24 hours. At the end of the test, the oil was cooled and filtered, and the sediment on the filter was dried and weighed. The results of the one-day test were correlated with the results of storage tests in which oil samples were stored for six months at 29.4/sup 0/C (85/sup 0/F) in 30-gallon steel drums or in glass bottles containing steel strips. At the end of storage, sediment was measured by filtering and weighing. The one-day stability test was also compared with storage in 100-barrel tanks at ambient temperature. The one-day stability test was in good agreement with the storage tests, and could be used to predict the amount of sediment that would be formed in storage.

Physical and oxidative stability of fish oil-in-water emulsions stabilized with beta-lactoglobulin and pectin.

Science.gov (United States)

Katsuda, Marly S; McClements, D J; Miglioranza, Lucia H S; Decker, Eric A

2008-07-23

The oxidation of fatty acids can be inhibited by engineering the surface of oil-in-water emulsion droplets to decrease interactions between aqueous phase prooxidants and lipids. The objective of this research was to evaluate whether emulsions stabilized by a multilayer emulsifier systems consisting of beta-lactoglobulin and citrus or sugar beet pectin could produce fish oil-in-water emulsions that had good physical and oxidative stability. Sugar beet pectin was compared to citrus pectin because the sugar beet pectin contains the known antioxidant, ferulic acid. A primary Menhaden oil-in-water emulsion was prepared with beta-lactoglobulin upon which the pectins were electrostatically deposited at pH 3.5. Emulsions prepared with 1% oil, 0.05% beta-lactoglobulin, and 0.06% pectins were physically stable for up to 16 days. As determined by monitoring lipid hydroperoxide and headspace propanal formation, emulsions prepared with the multilayer system of beta-lactoglobulin and citrus pectin were more stable than emulsions stabilized with beta-lactoglobulin alone. Emulsions prepared with the multilayer system of beta-lactoglobulin and sugar beet pectin were less stable than emulsions stabilized with beta-lactoglobulin alone despite the presence of ferulic acid in the sugar beet pectin. The lower oxidative stability of the emulsions with the sugar beet pectin could be due to its higher iron and copper concentrations which would produce oxidative stress that would overcome the antioxidant capacity of ferulic acid. These data suggest that the oxidative stability of oil-in-water emulsions containing omega-3 fatty acids could be improved by the use of multilayer emulsion systems containing pectins with low metal concentrations.

Influence of stability of polymer surfactant on oil displacement mechanism

Science.gov (United States)

Liu, Li; Li, Chengliang; Pi, Yanming; Wu, Di; He, Ying; Geng, Liang

2018-02-01

At present, most of the oilfields of China have entered the late stage of high water-cut development, and three oil recovery technique has become the leading technology for improving oil recovery. With the improvement of three oil recovery techniques, the polymer surfactant flooding technology has been widely promoted in oil fields in recent years. But in the actual field experiment, it has been found that the polymer surfactant has chromatographic separation at the extraction end, which indicates that the property of the polymer surfactant has changed during the displacement process. At present, there was few literature about how the stability of polymer surfactant affects the oil displacement mechanism. This paper used HuaDing-I polymer surfactant to conduct a micro photolithography glass flooding experiment, and then compared the oil displacement law of polymer surfactant before and after static setting. Finally, the influence law of stability of polymer surfactant on the oil displacement mechanism is obtained by comprehensive analysis.

Characterization of constituents, quality and stability of pomegranate seed oil (Punica granatum L.

Directory of Open Access Journals (Sweden)

Illana Louise Pereira de MELO

2016-03-01

Full Text Available Abstract This study aimed to characterize pomegranate seed oil and evaluate its quality and stability parameters against those of linseed oil. The profile of fatty acids and phytosterols and the content of tocopherols were analyzed by gas chromatography and high performance liquid chromatography, respectively. The quality of both oils was assessed as recommended by the American Oil Chemists' Society (AOCS and stability was evaluated using 2,2-diphenyl-1-picrylhydrazyl (DPPH, β-carotene bleaching (coupled oxidation of β-carotene/linoleic acid and Rancimat® assays. While α-linolenic acid (52% was the most abundant fatty acid in linseed oil (LO, punicic acid (55% was highest in pomegranate seed oil (PSO. Tocopherols and phytosterols (175 and 539 mg/100 g, respectively were greater in PSO than in LO (51 and 328 mg/100 g, respectively. Both oils met quality standards. The β-carotene bleaching and the DPPH assays showed greater oxidative stability for PSO than for LO. The Rancimat® method, on the other hand, indicated low stability for both oils.

Proceedings of the CERI 2002 World Oil Conference : Reading the Future. CD ed.

International Nuclear Information System (INIS)

2002-01-01

The integration and expansion of world oil markets was the main topic of this conference which featured 18 presentations dealing with developments in the international energy sector. The conference provided an opportunity for participants to discuss issues regarding oil supply and demand, oil prices, OPEC's spare capacity, OPEC's view regarding increasing competition from Canada's oil sands, and what role non-conventional oil plays in today's marketplace. The conference was divided into 6 sessions entitled: (1) oil prices, business as usual, (2) world oil demand, the incredible shrinking market, (3) global oil supplies, (4) going offshore, (5) the politics of oil, and (6) the growing North American supply. The outlook of world energy markets was reviewed with particular emphasis on prospects for oil supply and reserves. Also, the current status of the petroleum industry in both OPEC and non-OPEC oil exporting countries was discussed with reference to exploration, production, reserves, and hydrocarbon potential as well as the environmental, and socio-economic challenges that the industry must face. refs., tabs., figs

World oil demand's shift toward faster growing and less price-responsive products and regions

International Nuclear Information System (INIS)

Dargay, Joyce M.; Gately, Dermot

2010-01-01

Using data for 1971-2008, we estimate the effects of changes in price and income on world oil demand, disaggregated by product - transport oil, fuel oil (residual and heating oil), and other oil - for six groups of countries. Most of the demand reductions since 1973-74 were due to fuel-switching away from fuel oil, especially in the OECD; in addition, the collapse of the Former Soviet Union (FSU) reduced their oil consumption substantially. Demand for transport and other oil was much less price-responsive, and has grown almost as rapidly as income, especially outside the OECD and FSU. World oil demand has shifted toward products and regions that are faster growing and less price-responsive. In contrast to projections to 2030 of declining per-capita demand for the world as a whole - by the U.S. Department of Energy (DOE), International Energy Agency (IEA) and OPEC - we project modest growth. Our projections for total world demand in 2030 are at least 20% higher than projections by those three institutions, using similar assumptions about income growth and oil prices, because we project rest-of-world growth that is consistent with historical patterns, in contrast to the dramatic slowdowns which they project. (author)

World oil and agricultural commodity prices: Evidence from nonlinear causality

International Nuclear Information System (INIS)

Nazlioglu, Saban

2011-01-01

The increasing co-movements between the world oil and agricultural commodity prices have renewed interest in determining price transmission from oil prices to those of agricultural commodities. This study extends the literature on the oil-agricultural commodity prices nexus, which particularly concentrates on nonlinear causal relationships between the world oil and three key agricultural commodity prices (corn, soybeans, and wheat). To this end, the linear causality approach of Toda-Yamamoto and the nonparametric causality method of Diks-Panchenko are applied to the weekly data spanning from 1994 to 2010. The linear causality analysis indicates that the oil prices and the agricultural commodity prices do not influence each other, which supports evidence on the neutrality hypothesis. In contrast, the nonlinear causality analysis shows that: (i) there are nonlinear feedbacks between the oil and the agricultural prices, and (ii) there is a persistent unidirectional nonlinear causality running from the oil prices to the corn and to the soybeans prices. The findings from the nonlinear causality analysis therefore provide clues for better understanding the recent dynamics of the agricultural commodity prices and some policy implications for policy makers, farmers, and global investors. This study also suggests the directions for future studies. - Research highlights: → This study determines the price transmission mechanisms between the world oil and three key agricultural commodity prices (corn, soybeans, and wheat). → The linear and nonlinear cointegration and causality methods are carried out. → The linear causality analysis supports evidence on the neutrality hypothesis. → The nonlinear causality analysis shows that there is a persistent unidirectional causality from the oil prices to the corn and to the soybeans prices.

The oil world war; La guerre mondiale du petrole

Energy Technology Data Exchange (ETDEWEB)

Lafargue, F

2008-07-01

Since the beginning of the 21. century, a war has started between the USA, China and India. The USA, first oil consuming and importing country in the world, has now to take into account the increasing energy consumption of China and India. China is now, just behind Japan, the third oil importing country and India ranked number seven. From the Gulf of Guinea to the Arabic peninsula, from the Orenoque basin to the Caspian sea banks, Washington, Beijing and New Delhi covet the same oil fields. This rivalry exacerbates the political tensions in many regions of the Earth and already provokes a latent food crisis. This black gold war is changing the World's face and should provoke serious armed conflicts. (J.S.)

The relationship between fatty acid compositions and thermal stability of extra virgin olive oils

OpenAIRE

Fayegh Moulodi; Peyman Qajarbeigi; Ashraf Haj Hosseini Babaei; Asghar Mohammadpoor Asl

2014-01-01

Background: Fatty acids are one of the most important compounds in edible oils. Further, the stability of oils depends on the composition of fatty acids. So, this study was conducted to investigate the effect of fatty acid composition on the oxidative stability of extra virgin olive oils during the heating process. Methods: In total, eight samples of extra virgin olive oil were studied. To evaluate their thermal stability, the oils were heated at 120 ° C for 4 h and sampling was carried o...

World oil flow steady in 1992; stable market ahead for 1993

International Nuclear Information System (INIS)

Beck, R.J.

1993-01-01

World crude oil production in 1992 was virtually unchanged from 1991. Production last year averaged 59.96 million b/d, up only 17,000 b/d from 1991. Substantial production declines in the C.I.S. and U.S. were offset by increases among members of the Organization of Petroleum Exporting Countries and a number of other countries outside the OPEC sphere. Figures from the International Energy Agency (IEA) show world demand for petroleum products moved up 300,000 b/d to 66.9 million b/d. This included an addition to stocks of an estimated 1000,000 b/d. IEA predicts world demand will continue to rise in 1993 and OPEC output will advance to meet this higher level. Even though OPEC production is expected to be up for the year, seasonal swings in demand can cause price fluctuations. The paper describes OPEC production, non-OPEC production, oil prices, the world oil supply, Russian's decline, world demand, and the outlook for 1993

Controlling the frying stability of vegetable oils with tocopherols and phytosterols

Science.gov (United States)

Polyunsaturated vegetable oils are usually oxidatively stable for salad oils; however, in high stability applications such as frying, these oils are not resistant to the deteriorative processes of oxidation, hydrolysis and polymerization. To solve this problem in the past, oils were hydrogenated an...

Addition of Fish Oil to Cream Cheese Affects Lipid Oxidation, Sensory Stability and Microstructure

Directory of Open Access Journals (Sweden)

Andy Horsewell

2012-11-01

Full Text Available The objective of this study was to investigate the differences in the oxidative stability during storage of fish oil enriched cream cheeses when fish oil was added either as neat oil or pre-emulsified oil with sodium caseinate, whey protein isolate, or a combination of milk proteins and phospholipids as emulsifier. Results showed that the addition of fish oil decreased the oxidative stability of cream cheeses regardless of the addition method, especially when the cheese was stored longer than five weeks. The oxidative stability of fish oil enriched cream cheeses was highest when fish oil was added as neat oil or in a delivery emulsion prepared with a combination of milk proteins and phospholipids. Adding the fish oil in a delivery emulsion prepared with whey protein or caseinate resulted in a less oxidative stable product. It was furthermore shown that the microstructure of the cream cheeses was affected by fish oil addition, and it was suggested that the change in microstructure was partly responsible for the oxidative stability of the cream cheeses.

World oil prices flat to declining

International Nuclear Information System (INIS)

Adelman, M.A.

1993-01-01

A forecast is presented of the likely trends in world oil prices over the short to medium term. A historical background is presented of the OPEC cartel and its role in influencing oil prices. The incentives and disincentives for OPEC to raise prices, and the tensions within the cartel are explored. Slower demand growth and the expansion of natural gas are expected to put downward pressure on oil prices, which are currently artificially high. The impacts of high taxes on development and exploration are examined, and it is shown that state ownership poses an obstacle to improved performance. Threats of price decline are expected to continue to lead to threats of hasty, or even violent action on the part of OPEC members, as happened in 1990. Privatization and tax codes designed to skim rent are positive trends

Oxidative stability, chemical composition and organoleptic properties of seinat (Cucumis melo var. tibish) seed oil blends with peanut oil from China.

Science.gov (United States)

Siddeeg, Azhari; Xia, Wenshui

2015-12-01

Seinat seed oil was blended with peanut oil for the enhancement of stability and chemical characteristics of the blend. The physicochemical properties (relative density, refractive index, free fatty acids, saponification value, iodine value and peroxide value) of seinat seed and peanut oil blends in ratios 95:5, 85:15, 30:70 and 50:50 proportions were evaluated, as well as oxidative stability index, deferential scanning calorimetric (DSC) characteristics and tocopherols content. Results of oil blend showed that there was no negative effect by the addition of seinat seed oil to peanut oil and also had decreased percentages of all saturated fatty acids except stearic acid, conversely, increased the levels of unsaturated fatty acids. As for the sensory evaluation, the panelist results showed that seinat seed oil blends had no significant differences (p blending of seinat seed oil with peanut oil had also increased the stability and tocopherols content. As Sudan is the first producer of seinat oil, blending of seinat seed oil with traditional oil like quality, and may decrease the consumption of other expensive edible oils.

World resources of crude oil and natural gas

Energy Technology Data Exchange (ETDEWEB)

Masters, C.D.; Root, D.H.; Attanasi, E.D. (Geological Survey, Reston, VA (United States))

1991-01-01

An abstract is given of a paper presented at the World Petroleum Congress 1991 on the world estimates of identified reserves and undiscovered resources for crude oil, natural gas and natural gas liquids. Data are presented for Canada, Mexico, USA, South America, Western Europe, Eastern Europe, USSR, Africa, Middle East, Asia/Oceania and Antartica. (UK).

Influence of microwaves on olive oil stability

International Nuclear Information System (INIS)

Farag, R.S.; El-Baroty, G.; Abd El-Aziz, N.; Basuny, A.M.

1997-01-01

The fruits of Picual and Shemlalli olive cultivars were exposed to microwaves generated from an oven at low and moderate power settings for 3, 6, 9 and 12 min. The physicochemical constants and fatty acid composition of the olive oil samples extracted from nonmicrowaved and microwaved fruits were determined. The data demonstrated that microwaves did not alter the values of the above mentioned parameters compared with the oil extracted from nonmicrowaved fruits. Quality assurance tests (acid, peroxide and TBA values) elucidated that microwaves generally increased the olive oil stability of Picual and Shemlalli cultivars during storage. In addition, microwaves generated from oven ot moderate power setting for 12 min. exhibited an antioxidant power on olive oil equivalent to that possessed by BHT at 200 ppm [es

Inferred demand and supply elasticities from a comparison of world oil models

International Nuclear Information System (INIS)

Huntington, H.G.

1992-01-01

This paper summarizes the responses of oil supply and demand to prices and income in 11 world oil models that were compared in a recent Energy Modeling Forum (EMF) study. In May 1989, the EMF commenced a study of international oil supplies and demands (hereafter, EMF-11) to compare alternative perspectives on supply and demand issues and how these developments influence the level and direction of world oil prices. In analysing these issues, the EMF-11 working group relied partly upon results from 11 world oil models, using standardized assumptions about oil prices and gross domestic product (GDP). During the study, inferred price elasticities of supply and demand were derived from a comparison of results across different oil price scenarios with the same GDP growth path. Inferred income elasticities of demand were derived from a comparison of results across different economic growth scenarios with the same oil price-path. Together, these estimates summarize several important relationships for understanding oil markets. The first section provides some background on the EMF study and on general trends in the scenarios of interest that help to understand the results. Following sections explain the derivation and qualifications of the inferred estimates, report the results and summarize the key conclusions. (author)

Oxidative stability of fish oil-enriched mayonnaise-based salads

DEFF Research Database (Denmark)

Sørensen, Ann-Dorit Moltke; Nielsen, Nina Skall; Jacobsen, Charlotte

2010-01-01

The oxidative stability of fish oil-enriched mayonnaise-based salads and the influence of different vegetables in shrimp and tuna salads were evaluated. Moreover, the lipid oxidation in the presence of 1% oregano, rosemary, or thyme in fish oil-enriched tuna salad was assessed. The results obtain......-oxidative effect of shrimp. The effect of ingredients in tuna salads was inconclusive, possibly due to a high content of volatiles in the vegetables themselves. However, the addition of spices increased the oxidative stability of tuna salad (oregano>rosemary>thyme)....

The Influence of Palm Oil Addition on Sunflower Halva Stability and Texture

Directory of Open Access Journals (Sweden)

Vlad Muresan

2014-05-01

Full Text Available Halva is one of the most popular food products of Middle Eastern and North African countries. Worldwide, the most known halva contains roasted sesame seeds, while usually in Eastern European countries the most appreciated is sunflower halva. However, even if sunflower halva is an appreciated product, it has currently a quality below the expectations of the new generation of consumers. Sunflower halva main issue is caused by the oil which separates at the surface during storage, determining a low commercial aspect of the product. Thus, the aim of this work was to assess the influence of palm oil addition on sunflower halva stability and texture. Five samples containing different oil percentages [w/w] (1%, 2%, 3%, 4%, 5% were prepared, as well as a control sample prepared using the standard recipe (no palm oil added. The texture of all samples was analyzed by an instrumental method, while the colloidal stability was determined by a gravimetric technique during 40 days of storage at two different temperatures (1-2ºC and 15-20ºC. After the storage test at 1-2oC, there were not significant differences between the samples, for all palm oil containing samples as well as for control the percentages of separated oil being below 0.6%. With respect to the control sample, the halva samples containing 1%, 4% and 5% of palm oil showed a decrease in their stability, while samples containing 2% and 3% showed an improved stability (3.44% and 1.78% of separated oil. During this study it was established that the sample containing 3% palm oil was the most favorable, regarding its textural properties, as well as its colloidal stability. 

Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide

Directory of Open Access Journals (Sweden)

Xiaoma Fei

2016-08-01

Full Text Available A series of alkyl chain modified graphene oxides (AmGO with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13 and salt concentrations (from 0.1 to 1000 mM. In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.

State of the art in oil market in the world

International Nuclear Information System (INIS)

Banks, F. E.

2007-01-01

Things move fast in the world of oil and unfortunately many events do not always receive an appropriate interpretation. The present update reviews the on-going oil peak debate, providing evidence against unjustified optimistic propositions, discussing the predictable shortage of energy materials and its influence on prices. Moreover, the return of OPEC to the oil market drivers seat and the irruption of state oil companies from exporting countries are also commented. (Author)

A new method to determine oxidative stability of vegetable fats and oils at simulated frying temperature

Directory of Open Access Journals (Sweden)

Gertz Christian

2001-01-01

Full Text Available A new procedure at simulated frying conditions in our laboratory was developed to monitor frying stability of fats and oils. Water-conditioned silica was prepared and added to the fresh vegetable oil, which was heated for two hours at 170°C. The oil stability at frying temperature was then evaluated by determining the amount of formed dimeric triglycerides The results obtained showed that the stability of the vegetable oils at frying temperature could not be explained by the fatty acid composition alone. Corn oil was observed to be more stable than soybean oil, and rapeseed oil was better than olive oil. It was also observed that crude, non-refined oils were found to have a better heat stability than refin-ed oils. To estimate the effectiveness of synthetic and naturally occurring antioxidants, namely various tocopherols, tocopherol acetate and phytosterol fractions, phenolic compounds like quercetin, oryzanol, ferulic acid, gallates, BHT, BHA and other compounds like ascorbic acid 6-palmitate and squalene were added to refined sunflower and rape seed oil, and their oxidative stability at elevated temperature (OSET values determined. Both linoleic and oleic rich oils gave comparable results for the activity of the various compounds. alpha-tocopherol, tocopherol esters and BHA had low effects on oil stability at frying temperature, while ascorbyl palmitate and some phytosterol fractions were found to have the most stabilizing activity under frying conditions.

Gallic Acid Grafted Chitosan Has Enhanced Oxidative Stability in Bulk Oils.

Science.gov (United States)

Gim, Seo Yeong; Hong, Seungmi; Kim, Mi-Ja; Lee, JaeHwan

2017-07-01

Gallic acid (GA) was grafted in chitosan and the effects of GA grafted chitosan (GA-g-CS) on the oxidative stability in bulk oil was tested at 60 and 140 °C. To text oxidative stability in oils, headspace oxygen content, conjugated dienoic acid (CDA) value, p-anisidine value (p-AV), and acid value were determined. Chitosan itself did not show antioxidative or prooxidative effects in oils at 60 °C. However, GA-g-CS and GA acted as antioxidants at 60 °C. At 140 °C heating with moisture supplied condition, different results were observed. GA-g-CS acted as antioxidants based on the results of CDA and p-AV. However, chitosan showed the highest oxidative stability based on results of acid value and brown color formation at 140 °C. This could be due to reduction of moisture content by chitosan. GA was continuously released from GA-g-CS in bulk oil. This might have provided extra antioxidant activities to oils. © 2017 Institute of Food Technologists®.

A Systems Approach to Bio-Oil Stabilization - Final Technical Report

Energy Technology Data Exchange (ETDEWEB)

Brown, Robert C; Meyer, Terrence; Fox, Rodney; Submramaniam, Shankar; Shanks, Brent; Smith, Ryan G

2011-12-23

The objective of this project is to develop practical, cost effective methods for stabilizing biomass-derived fast pyrolysis oil for at least six months of storage under ambient conditions. The U.S. Department of Energy has targeted three strategies for stabilizing bio-oils: (1) reducing the oxygen content of the organic compounds comprising pyrolysis oil; (2) removal of carboxylic acid groups such that the total acid number (TAN) of the pyrolysis oil is dramatically reduced; and (3) reducing the charcoal content, which contains alkali metals known to catalyze reactions that increase the viscosity of bio-oil. Alkali and alkaline earth metals (AAEM), are known to catalyze decomposition reactions of biomass carbohydrates to produce light oxygenates that destabilize the resulting bio-oil. Methods envisioned to prevent the AAEM from reaction with the biomass carbohydrates include washing the AAEM out of the biomass with water or dilute acid or infusing an acid catalyst to passivate the AAEM. Infusion of acids into the feedstock to convert all of the AAEM to salts which are stable at pyrolysis temperatures proved to be a much more economically feasible process. Our results from pyrolyzing acid infused biomass showed increases in the yield of anhydrosugars by greater than 300% while greatly reducing the yield of light oxygenates that are known to destabilize bio-oil. Particulate matter can interfere with combustion or catalytic processing of either syngas or bio-oil. It also is thought to catalyze the polymerization of bio-oil, which increases the viscosity of bio-oil over time. High temperature bag houses, ceramic candle filters, and moving bed granular filters have been variously suggested for syngas cleaning at elevated temperatures. High temperature filtration of bio-oil vapors has also been suggested by the National Renewable Energy Laboratory although there remain technical challenges to this approach. The fast pyrolysis of biomass yields three main organic

Pollination networks of oil-flowers: a tiny world within the smallest of all worlds.

Science.gov (United States)

Bezerra, Elisângela L S; Machado, Isabel C; Mello, Marco A R

2009-09-01

1. In the Neotropics, most plants depend on animals for pollination. Solitary bees are the most important vectors, and among them members of the tribe Centridini depend on oil from flowers (mainly Malpighiaceae) to feed their larvae. This specialized relationship within 'the smallest of all worlds' (a whole pollination network) could result in a 'tiny world' different from the whole system. This 'tiny world' would have higher nestedness, shorter path lengths, lower modularity and higher resilience if compared with the whole pollination network. 2. In the present study, we contrasted a network of oil-flowers and their visitors from a Brazilian steppe ('caatinga') to whole pollination networks from all over the world. 3. A network approach was used to measure network structure and, finally, to test fragility. The oil-flower network studied was more nested (NODF = 0.84, N = 0.96) than all of the whole pollination networks studied. Average path lengths in the two-mode network were shorter (one node, both for bee and plant one-mode network projections) and modularity was lower (M = 0.22 and four modules) than in all of the whole pollination networks. Extinctions had no or small effects on the network structure, with an average change in nestedness smaller than 2% in most of the cases studied; and only two species caused coextinctions. The higher the degree of the removed species, the stronger the effect and the higher the probability of a decrease in nestedness. 4. We conclude that the oil-flower subweb is more cohesive and resilient than whole pollination networks. Therefore, the Malpighiaceae have a robust pollination service in the Neotropics. Our findings reinforce the hypothesis that each ecological service is in fact a mosaic of different subservices with a hierarchical structure ('webs within webs').

Thermal stability of butter oils produced from sheep’s non-pasteurized and pasteurized milk

Directory of Open Access Journals (Sweden)

FLAVIA POP

Full Text Available The physical and chemical characteristics and thermal stability of butter oil produced from non-pasteurized and pasteurized sheep’s milk were studied. Thermal stability of samples was estimated by using the accelerated shelf-life testing method. Samples were stored at 50, 60 and 70oC in the dark and the reaction was monitored by measuring peroxide, thiobarbituric acid and free fatty acid values. The peroxide and thiobarbituric acid values increased as the temperature increased. The increase of acid values of the two samples was not significant. A slight increase in free fatty acid value showed that hydrolytic reactions were not responsible for the deterioration of butter oil samples in thermal stability studies. When compared, butter oil produced from pasteurized sheep’s milk has higher thermal stability than butter oil produced from non-pasteurized sheep’s milk. Although butter oil produced from non-pasteurized milk was not exposed to any heat treatment, the shelf-life of this product was lower than the shelf-life of butter oil produced from pasteurized sheep’s milk. Therefore, heat treatment for pasteurization did not affect the thermal stability of butter oil.

Bio-oil Stabilization by Hydrogenation over Reduced Metal Catalysts at Low Temperatures

Energy Technology Data Exchange (ETDEWEB)

Wang, Huamin; Lee, Suh-Jane; Olarte, Mariefel V.; Zacher, Alan H.

2016-08-30

Biomass fast pyrolysis integrated with bio-oil upgrading represents a very attractive approach for converting biomass to hydrocarbon transportation fuels. However, the thermal and chemical instability of bio-oils presents significant problems when they are being upgraded, and development of effective approaches for stabilizing bio-oils is critical to the success of the technology. Catalytic hydrogenation to remove reactive species in bio-oil has been considered as one of the most efficient ways to stabilize bio-oil. This paper provides a fundamental understanding of hydrogenation of actual bio-oils over a Ru/TiO2 catalyst under conditions relevant to practical bio-oil hydrotreating processes. Bio-oil feed stocks, bio-oils hydrogenated to different extents, and catalysts have been characterized to provide insights into the chemical and physical properties of these samples and to understand the correlation of the properties with the composition of the bio-oil and catalysts. The results indicated hydrogenation of various components of the bio-oil, including sugars, aldehydes, ketones, alkenes, aromatics, and carboxylic acids, over the Ru/TiO2 catalyst and 120 to 160oC. Hydrogenation of these species significantly changed the chemical and physical properties of the bio-oil and overall improved its thermal stability, especially by reducing the carbonyl content, which represented the content of the most reactive species (i.e., sugar, aldehydes, and ketones). The change of content of each component in response to increasing hydrogen additions suggests the following bio-oil hydrogenation reaction sequence: sugar conversion to sugar alcohols, followed by ketone and aldehyde conversion to alcohols, followed by alkene and aromatic hydrogenation, and then followed by carboxylic acid hydrogenation to alcohols. Hydrogenation of bio-oil samples with different sulfur contents or inorganic material contents suggested that sulfur poisoning of the reduced Ru metal catalysts was

Characterization of Thermal Stability of Synthetic and Semi-Synthetic Engine Oils

Directory of Open Access Journals (Sweden)

Anand Kumar Tripathi

2015-03-01

Full Text Available Engine oils undergo oxidative degradation and wears out during service. Hence it is important to characterize ageing of engine oils at different simulated conditions to evaluate the performance of existing oils and also design new formulations. This work focuses on characterizing the thermo-oxidative degradation of synthetic and semi-synthetic engine oils aged at 120, 149 and 200 °C. Apparent activation energy of decomposition of aged oils evaluated using the isoconversional Kissinger-Akahira-Sunose technique was used as a thermal stability marker. The temporal variation of stability at different ageing temperatures was corroborated with kinematic viscosity, oxidation, sulfation and nitration indices, total base number, antiwear additive content and molecular structure of the organic species present in the oils. At the lowest temperature employed, synthetic oil underwent higher rate of oxidation, while semi-synthetic oil was stable for longer time periods. At higher temperatures, the initial rate of change of average apparent activation energy of synthetic oil correlated well with a similar variation in oxidation number. A mixture of long chain linear, branched, and cyclic hydrocarbons were observed when semi-synthetic oil was degraded at higher temperatures.

ON STABILITY OF THE OIL DISPLACEMENT FRONT UNDER CONDITIONS OF THERMOGAS IMPACT ON THE OIL BEARING LAYER

Directory of Open Access Journals (Sweden)

K. V. Dobrego

2016-01-01

Full Text Available The method of thermogas impact on the oil bearing layer is a perspective one to improve oil recovery. It is now under experimental implementation in Belarus. Stability of the thermal front and that of the oil displacement is a point of principle for the given technology. The article offers solution based on the method of small perturbations for the problem of the oil-displacement front stability under thermogas impact on the oil layer. The perturbation growth increment is shown to be quite different from that of the gas filtration combustion. Being determined by the perturbation wave number (or wave length, by difference in speed of the blowing filtration and that of the heat development front, by the ratios of densities, filtration coefficients, compressibility of the displacement agent and the displaced oil mass, and by other parameters. The author analyses the main parameters influencing the stability of the front. Recommendations are given on possible methods and procedures improving stability of the displacement front (neutralizing perturbation growth. The mechanisms of suppression or compensation of the front perturbation growth are as follows: the crude oil viscosity reduction and increase of that of the displacement agent, the displacement agent compressibility increase, increase of the thermogas impact heat-front width in the first instance at the expense of the temperature growth and alteration in the chemism (low temperature catalysts utilization, etc., reduction in speed of the front propagation and/or correspondingly of the displacement agent feed. Utilization of the gas or water-gas displacement agent as well as the agent impregnation with hydrophobic gases provides a relatively better stability of the front as compared to that employing water based compounds. Analytical data and derived recommendations are offered for utilization within the framework of general techniques and procedures of the thermogas impact process management

The use of stability indices in predicting asphaltene problems in upstream and downstream oil operations

Energy Technology Data Exchange (ETDEWEB)

Asomaning, S. [Baker Petrolite, Sugar Land, TX (United States)

2003-07-01

A series of test methods have been developed to determine the stability of asphaltenes in crude oils. They were developed due to the high cost of remediating asphaltene deposition in offshore operations. This study described the characteristics of the Oliensis Spot Test, two saturates, aromatics, resins and asphaltenes (SARA)-based screens (the Colloidal Instability Index and Asphaltene-Resin ratio), a solvent titration method with near infrared radiation (NIR) solids detection, and live oil depressurization. Each method is used to predict the stability of asphaltenes in crude oils with different API gravity. A complete description of the test methods was provided along with experimental data. The effectiveness of the different tests in predicting the stability of asphaltenes in crude oils was also assessed. Results indicate that the prediction of a crude oil's tendency towards asphaltene precipitation was more accurate with the Colloidal Instability Index and the solvent titration method. Live oil depressurization proved to be very effective in predicting the stability of asphaltenes for light oils, where most stability tests fail. tabs., figs.

Modelling the world oil market: Assessment of a quarterly econometric model

International Nuclear Information System (INIS)

Dees, Stephane; Karadeloglou, Pavlos; Kaufmann, Robert K.; Sanchez, Marcelo

2007-01-01

This paper describes a structural econometric model of the world oil market that can be used to analyse oil market developments and risks. Oil demand depends on domestic economic activity and the real price of oil. Oil supply for non-OPEC producers, based on competitive behaviours, is constrained by geological and institutional conditions. Oil prices are determined by a 'price rule' that includes market conditions and OPEC behaviour. Policy simulations indicate that oil demand and non-OPEC supply are rather inelastic to changes in price, while OPEC decisions about quota and capacity utilisation have a significant, immediate impact on oil prices

Stabilization of Bio-Oil Fractions for Insertion into Petroleum Refineries

Energy Technology Data Exchange (ETDEWEB)

Brown, Robert C. [Iowa State Univ., Ames, IA (United States); Smith, Ryan [Iowa State Univ., Ames, IA (United States); Wright, Mark [Iowa State Univ., Ames, IA (United States); Elliott, Douglas [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Resasco, Daniel [Univ. of Oklahoma, Norman, OK (United States); Crossley, Steven [Univ. of Oklahoma, Norman, OK (United States)

2014-09-28

This project is part of a collaboration effort between Iowa State University (ISU), University of Oklahoma (OK) and Pacific Northwest National Laboratory (PNNL). The purpose of this project is to stabilize bio-oil fractions and improve their suitability for insertion into petroleum refineries. Bio-oil from fast pyrolysis of biomass is a complex mixture of unstable organic compounds. These organic compounds react under standard room conditions resulting in increases in bio-oil viscosity and water content – both detrimental for bio-oil storage and transportation. This study employed fractionation and upgrading systems to improve the stability of bio-oil. The fractionation system consists of a series of condensers, and electrostatic precipitators designed to separate bio-oil into five fractions: soluble carbohydrates (SF1&2), clean phenolic oligomers (CPO) and middle fraction (SF3&4), light oxygenates (SF5). A two-stage upgrading process was designed to process bio-oil stage fractions into stable products that can be inserted into a refinery. In the upgrading system, heavy and middle bio-oil fractions were upgraded into stable oil via cracking and subsequent hydrodeoxygenation. The light oxygenate fraction was steam reformed to provide a portion of requisite hydrogen for hydroprocessing. Hydrotreating and hydrocracking employed hydrogen from natural gas, fuel gas and light oxygenates reforming. The finished products from this study consist of gasoline- and diesel-blend stock fuels.

Proceedings of the world heavy oil congress 2011

International Nuclear Information System (INIS)

2011-01-01

The World Heavy Oil Congress 2011 took place March 2011 in Edmonton, Alberta, Canada. This congress is an international gathering of heavy oil experts and professionals which takes place every 18 months to discuss issues and opportunities facing the heavy oil industry in terms of commercial, technical, regulatory and geo-political areas. Innovative solutions for improving performance, reducing costs and mitigating environmental impacts are presented. Hundreds of presentations were made, courses were delivered, and over 100 companies from 30 countries exhibited. The congress had support from various companies and government entities.This conference featured 133 papers, all of have been catalogued separately for inclusion in this database.

Future role of Gulf oil in world energy demand

International Nuclear Information System (INIS)

Eltony, M.N.

1998-01-01

The view that there will be a growing dependence on oil from the Gulf countries is shared by a great number of oil market analysts. This view is based on the fact that Gulf countries dominate the global oil reserves. Energy analyst argue that as the world demand for oil continues to grow driven largely by the growth in developing countries' consumption coupled with constrained non-OPEC supply, the end result will be that the call on Gulf oil will grow substantially. In summary, this paper has challenged the view of growing dependence on oil from the Gulf using available information in conjunction with reasonable and fairly plausible arguments. The aim was to point out to the GCC member counties the danger of relying on these views in shaping their economic policies and in setting their oil market strategies. They may run the ultimate risk of being left with huge oil reserves that no one wants. (orig.)

The stability of the international oil trade network from short-term and long-term perspectives

Science.gov (United States)

Sun, Qingru; Gao, Xiangyun; Zhong, Weiqiong; Liu, Nairong

2017-09-01

To examine the stability of the international oil trade network and explore the influence of countries and trade relationships on the trade stability, we construct weighted and unweighted international oil trade networks based on complex network theory using oil trading data between countries from 1996 to 2014. We analyze the stability of international oil trade network (IOTN) from short-term and long-term aspects. From the short-term perspective, we find that the trade volumes play an important role on the stability. Moreover, the weighted IOTN is stable; however, the unweighted networks can better reflect the actual evolution of IOTN. From the long-term perspective, we identify trade relationships that are maintained during the whole sample period to reveal the situation of the whole international oil trade. We provide a way to quantitatively measure the stability of complex network from short-term and long-term perspectives, which can be applied to measure and analyze trade stability of other goods or services.

Maillard-Reaction-Functionalized Egg Ovalbumin Stabilizes Oil Nanoemulsions.

Science.gov (United States)

Liu, Gang; Yuan, Dan; Wang, Qi; Li, Wanrong; Cai, Jie; Li, Shuyi; Lamikanra, Olusola; Qin, Xinguang

2018-04-25

Egg white proteins are an excellent source of nutrition, with high biological and technological values. However, their limited functional properties prevent their widespread industrial applications. In this study, the ovalbumin functionality was improved via glycation by Maillard reaction with d-lactose. The free amino groups and sodium dodecyl sulfate-polyacrylamide gel electrophoresis profile were determined, confirming that glycation occurred between ovalbumin and lactose. The emulsification of the conjugate was 2.69-fold higher than that of ovalbumin at pH 7.0 after glycation. The thermal stability also improved remarkably. The glycated protein products were used to form an oil-water nanoemulsion for polymethoxyflavone-rich aged orange peel oil. The resulting nanoemulsion showed good pH, thermal, and storage stabilities.

World oil demand's shift toward faster growing and less price-responsive products and regions

Energy Technology Data Exchange (ETDEWEB)

Dargay, Joyce M. [Institute for Transport Studies, University of Leeds, Leeds LS2 9JT (United Kingdom); Gately, Dermot [Dept. of Economics, New York University, 19W. 4 St., New York, NY 10012 (United States)

2010-10-15

Using data for 1971-2008, we estimate the effects of changes in price and income on world oil demand, disaggregated by product - transport oil, fuel oil (residual and heating oil), and other oil - for six groups of countries. Most of the demand reductions since 1973-74 were due to fuel-switching away from fuel oil, especially in the OECD; in addition, the collapse of the Former Soviet Union (FSU) reduced their oil consumption substantially. Demand for transport and other oil was much less price-responsive, and has grown almost as rapidly as income, especially outside the OECD and FSU. World oil demand has shifted toward products and regions that are faster growing and less price-responsive. In contrast to projections to 2030 of declining per-capita demand for the world as a whole - by the U.S. Department of Energy (DOE), International Energy Agency (IEA) and OPEC - we project modest growth. Our projections for total world demand in 2030 are at least 20% higher than projections by those three institutions, using similar assumptions about income growth and oil prices, because we project rest-of-world growth that is consistent with historical patterns, in contrast to the dramatic slowdowns which they project. (author)

33 CFR 155.240 - Damage stability information for oil tankers and offshore oil barges.

Science.gov (United States)

2010-07-01

... GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) POLLUTION OIL OR HAZARDOUS MATERIAL POLLUTION... that their vessels have prearranged, prompt access to computerized, shore-based damage stability and...

World Oil: Coping With the Dangers of Success. Worldwatch Paper 66.

Science.gov (United States)

Flavin, Christopher

This publication examines various topics and issues related to the world oil situation. Major areas considered are: (1) the nature and consequences of the current oil glut; (2) a historical overview of the petroleum era (with analyses of the three time periods of 1900-1973, 1973-1979, and 1979-1981); (3) the geopolitics of oil (including data on…

The relationship between fatty acid compositions and thermal stability of extra virgin olive oils

Directory of Open Access Journals (Sweden)

Fayegh Moulodi

2014-11-01

Full Text Available Background: Fatty acids are one of the most important compounds in edible oils. Further, the stability of oils depends on the composition of fatty acids. So, this study was conducted to investigate the effect of fatty acid composition on the oxidative stability of extra virgin olive oils during the heating process. Methods: In total, eight samples of extra virgin olive oil were studied. To evaluate their thermal stability, the oils were heated at 120 ° C for 4 h and sampling was carried out in 2-hour intervals. Then, fatty acid composition, peroxide value, anisidine value and totox value were evaluated according to Iranian national standards. Results: Results showed a significantly direct correlation between Palmitoleic acid and Totox index in the second (r=0.786 and fourth hours (r=0.762, and between linoleic and Totox index in the second (r=0.643 and fourth hours (r=0.786. However, there was a significantly inverse relationship between oleic acid and Totox index in the fourth hour (r=-0.833. Conclusion: Result indicated that linoleic and Palmitoleic acids had a reducing effect on thermal stability of extra virgin olive oil after the second hour. But, Oleic acid caused a positive effect on thermal stability after the fourth hour. Thus, it is concluded that unsaturated fatty acids especially oleic acid affect the thermal stability at final hours.

Factors affecting world and Russian domestic oil prices: the domestic implications - a Russian perspective

International Nuclear Information System (INIS)

Khartukov, E.M.

2001-01-01

This paper modestly aims at answering two formally related but unnecessarily interconnected questions about international and Russian domestic pricing of crude oil. The first of them is what, in our opinion, chiefly determines price dynamics of the contemporary world oil market. And the second one is in which way (if at all) world oil price dynamics affect Russia's internal market. (author)

A unified world oil market: Regions in physical, economic, geographic, and political space

International Nuclear Information System (INIS)

Kaufmann, Robert K.; Banerjee, Shayan

2014-01-01

Although there is a general consensus that the market is unified, here we quantify the factors that create regions by analyzing the price relation between 33 crude oils. ADF statistics indicate that 447 of the 528 crude oil pairings cointegrate; 81 do not. The presence/absence of cointegration is analyzed using a logit model. The likelihood that the prices for two crude oils cointegrate depends on their physical characteristics (density and sulfur content), economic factors (country risk for the nation of origin), their geographic location (distance between supply ports), and political factors (OPEC membership). Over the sample period, the technology to refine heavy crude oils penetrates the market, and this reduces the price difference between heavy and light crude oils. The effect of country risk implies that crude oils from high risk nations are not perfect substitutes for crude oils of similar quality from low risk nations. Finally, crude oils from widely separated suppliers are more likely to cointegrate than crude oils from near-by nations, which suggests consumers diversify supply across transportation chokepoints. For this sample, these sources of regionalization add $0.20 per barrel to the $2.86 average price difference between crude oils in the same market. Together, these factors have important implications for the efficacy of policy aimed at reducing dependence on unreliable suppliers and the spill-over effects of holding inventories. - Highlights: • The world oil market is not completely unified. • Regions are defined by differences in API gravity and sulfur content. • Country risk regionalizes the world oil market. • Shipping chokepoints regionalize the world oil market. • Regionalization adds $0.20 to $2.86 price difference between oils in same market

The World Oil Market: The Search for Balance in the New “Oil” Reality

Directory of Open Access Journals (Sweden)

Tatjiana A. Malova

2016-01-01

Full Text Available The article provides an analysis of change of the world oil market in the face of new "oil" reality. Factors of formation of new "oil" reality in the global world defined. Scientific background and current state of research of the problem are described. It is shownthat in the Russian and foreign literature the considerable attention is paid to the analysis of dynamics of the quantitative variables characterizing fluctuations and shocks in the oil market. At the same time the search for balance in the new "oil" reality are not considerably investigated yet. The proposed approach allows toreveal the substance of the transformation of the world oil market, to assess the changes in the oil market with the development of rhenium in terms of efficiency and functioning of the mechanism, the prospects of price volatility in the oil market. The main directions of transformation of the oil market are follows. Development of a subject basis of the oil market due to changes of a role of the main market players whose structure includes the USA, Saudi Arabia, Russia now. The impact of regulatory factors complex in the oil market towards equilibrium, which include activity of OPEC, supply of shale oil, future market,activity of the uniform regulator and national regulators. Transformation of the oil market in the direction of perfection of the competitive relations, achievement of optimum market balance as a result of coordination and interaction of interests of participants of the global oil market.

A Study on the Determination of the World Crude Oil Price and Methods for Its Forecast

Energy Technology Data Exchange (ETDEWEB)

Kim, J.K. [Korea Energy Economics Institute, Euiwang (Korea)

2001-11-01

The primary purpose of this report is to provide the groundwork to develop the methods to forecast the world crude oil price. The methodology is used by both literature survey and empirical study. For this purpose, first of all, this report reviewed the present situation and the outlook of the world oil market based on oil demand, supply and prices. This analysis attempted to provide a deeper understanding to support the development of oil forecasting methods. The result of this review, in general, showed that the oil demand will be maintained annually at an average rate of around 2.4% under assumption that oil supply has no problem until 2020. The review showed that crude oil price will be a 3% increasing rate annually in the 1999 real term. This report used the contents of the summary review as reference data in order to link the KEEIOF model. In an effort to further investigate the contents of oil political economy, this report reviewed the articles of political economy about oil industry. It pointed out that the world oil industry is experiencing the change of restructuring oil industry after the Gulf War in 1990. The contents of restructuring oil industry are characterized by the 'open access' to resources not only in the Persian Gulf, but elsewhere in the world as well - especially the Caspian Sea Basin. In addition, the contents showed that the oil industries are shifted from government control to government and industry cooperation after the Gulf War. In order to examine the characters and the problems surrounding oil producing countries, this report described the model of OPEC behavior and strategy of oil management with political and military factors. Among examining the models of OPEC behavior, this report focused on hybrid model to explain OPEC behavior. In reviewing political and religious power structure in the Middle East, the report revealed that US emphasizes the importance of the Middle East for guaranteeing oil security. However, three

The instability of world oil market and its impact on economic development: Indonesia's experience

International Nuclear Information System (INIS)

Patmosukismo, S.

1991-01-01

The world oil market has been characterized by fluctuating prices which have a direct impact on the world economy. If the world oil price rises in real terms, upstream activities become more attractive to producers, and if the price declines, downstream opportunities become more attractive. The world oil market is currently determined not only by producers and consumers, but also by the futures trade. In addition, the elasticity of oil prices has increased since the 1970s through competition among producers and competition from other energy sources. The Asia Pacific countries are experiencing rapid economic growth, and are thus heavily dependent on oil, but generally have small reserves. Their reserves/production ratio is ca 20 years, with a major share coming from China and Indonesia. The current situation of tight and inadequate supply may increase the region's dependence on Middle East sources. The effects of the three recent major oil crises on the Asia Pacific countries are reviewed and the role of oil and gas in Indonesia's economic development is described. Export earnings from oil and gas represent a major share of total Indonesian export revenues, and taxes and receipts from oil companies continue to be the largest receipts in Indonesian government revenues. Slow changes in the primary fuel mix and high growth in domestic consumption may turn Indonesia into a net oil importer before the year 2000. A major effort to decrease domestic oil consumption has been implemented by using natural gas and coal in the power generation sector. On the supply side, recoverable oil and gas reserves of 50 billion bbl and 200 trillion ft 3 respectively may be present but their development depends on the investment scheme of the continuing exploration program

The effect of the volatility of the oil price in the actual world economy (1998 until 02/2008); A influencia da volatilidade dos precos do petroleo na atual economia mundial

Energy Technology Data Exchange (ETDEWEB)

Plaster, Vinicius Almeida [Universidade Vila-Velha, ES (Brazil). Relacoes Internacionais

2008-07-01

In the elapse of the X X century the world experienced different cycles of prices in the world's oil production. From the principle of the century until the years 70's there were times of relative stability, in the 70's nevertheless a little variation in the price took the world's economy into a huge recession. Since then the consume of oil, that were increasing, has suffered a shock and started to decrease. The stability just will return in the 90's , but it will not last for a long time, and not with the same level of prices of the time before crisis, but as sad before it do not last long, as we can see nowadays the quotation break new records every day , but one factor distinguish this new shock of prices, of the shock of the 70's. Distinct of that time, the global economy in the beginning of the X XI century live a period of economical stability that was not seen for a long time in history, with controlled inflation and decrease of the interests rates, therefore this article concludes that happened a maturation of global economy, and that due the previous shocks happened a diversification in relation of the previous excessive dependence of oil. (author)

The long-term supply/demand trend of world energy and the current oil situation in the Asia

International Nuclear Information System (INIS)

Okamoto, Hiroyuki

1996-01-01

Total world primary energy consumption excluding the FSU increased by 2.9% in 1995, which is somewhat above the 10 year average rate of 2.4%. This reflected strong economic growth in most parts of the world. The increase in demand confirmed the recovery of the link between the economic growth and consumption of primary energy, which broke down in the period of oil crises. Oil demand in the Asian Emerging Market Economies has continued to be very strong. Oil demand has doubled in a decade in this region and is now one sixth of world consumption. Malaysia was the fastest growing oil market in the world in 1995 at 15.5%. In volume terms, S. Korea grew the most in the world by 170,000 b/d, closely followed by China and India. Because of the fast growing oil demand, many energy economists expect a tight supply situation in the Asian oil market in the early 21st Century. However, recent technological developments would be able to supply crude oil appropriate for an increase in oil demand. (author)

Effect of seed quality on oxidative stability of cold-pressed sunflower oil

Directory of Open Access Journals (Sweden)

Dimić Etelka B.

2015-01-01

Full Text Available The objective of this study was to investigate the impact of the storage time, content of the husk and impurities in the seed mass on the oxidative stability of the cold pressed sunflower oil. The oxidative stability of oil was analyzed by the RSM (Response Surface Methodology, where the response value (output of the model was the content of oxidation products measured via specific absorbance at 232 nm for conjugated dienes and 270 nm for conjugated trienes. Analyses were performed on the fresh oil samples and oil samples tempered under the Schaal-Oven’s test conditions (96 h at 63±2ºC. It was concluded that the seed storage time had significant impact on the primary (A1%232nm and secondary (A1%270nm oil oxidation products, both before (b1-p<0,001; b1-p=0,021 and after (b1-p=0,048; b1-p=0,033 the heating of oil. The content of impurities and husks in the seeds used for pressing also had an influence of the conjugated dienes and trienes contents in both, fresh and heated oil samples. However, their impact was not statistically significant. Interaction of seed storage time, the content of impurities and husks also exert some effect on the values of these quality parameters in the fresh oil as well as in the oil after the heat treatment, even though their influence is not significant. The obtained results have shown that the cold pressed sunflower oil had a good oxidative stability at temperatures up to 63±2ºC.

Effect of ingredients on oxidative stability of fish oil-enriched drinking yoghurt

DEFF Research Database (Denmark)

Nielsen, Nina Skall; Klein, Anna; Jacobsen, Charlotte

2009-01-01

, pectin, citric acid or gluconodelta- lactone did not affect the oxidative stability of fish oil-enriched yoghurt emulsions. Furthermore, the fruit preparation and added sugar did not lead to increased antioxidative activity. It is concluded that yoghurt as the dairy component in the fish oil......The oxidative stabilities of fish oil-enriched milk and fish oil-enriched drinking yoghurt were compared by following the development of lipid oxidation in plain milk, plain yoghurt and yoghurt to which ingredients present in drinking yoghurt were added one by one. All samples were enriched with 1...... wt-% fish oil. After 3 weeks of storage, development of peroxide values, volatile secondary oxidation products and fishy offflavors were much more pronounced in the milk compared to any of the yoghurt samples, irrespective of any added ingredients used to prepare flavored drinking yoghurt. Thus...

Investigation of stability, consistency, and oil oxidation of emulsion filled gel prepared by inulin and rice bran oil using ultrasonic radiation.

Science.gov (United States)

Nourbehesht, Newsha; Shekarchizadeh, Hajar; Soltanizadeh, Nafiseh

2018-04-01

Inulin, rice bran oil and rosemary essential oil were used to produce high quality emulsion filled gel (EFG) using ultrasonic radiation. Response surface methodology was used to investigate the effects of oil content, inulin content and power of ultrasound on the stability and consistency of prepared EFG. The process conditions were optimized by conducting experiments at five different levels. Second order polynomial response surface equations were developed indicating the effect of variables on EFG stability and consistency. The oil content of 18%; inulin content of 44.6%; and power of ultrasound of 256 W were found to be the optimum conditions to achieve the best EFG stability and consistency. Microstructure and rheological properties of prepared EFG were investigated. Oil oxidation as a result of using ultrasonic radiation was also investigated. The increase of oxidation products and the decrease of total phenolic compounds as well as radical scavenging activity of antioxidant compounds showed the damaging effect of ultrasound on the oil quality of EFG. Copyright © 2017 Elsevier B.V. All rights reserved.

Stabilization of heavy oil-water emulsions using a bio/chemical emulsifier mixture

Energy Technology Data Exchange (ETDEWEB)

Farahbakhsh, A.; Taghizadeh, M.; Movagharnejad, K. [Chemical Engineering Department, Babol University of Technology, Babol (Iran, Islamic Republic of); Yakhchali, B. [National Institute of Genetic Engineering and Biotechnology, Tehran (Iran, Islamic Republic of)

2011-11-15

In this study, the viscosity reduction of heavy oil has been investigated through the formation of oil-water emulsion using a bio/chemical emulsifier mixture. Four bioemulsifiers from indigenous Rhodococcus ergthropolis and Bacillus licheniformis strains were used to stabilize a highly-viscous oil-in-water emulsion. The Taguchi method with an L{sub 9} orthogonal array design was used to investigate the effect of various control factors on the formation of the oil/water emulsions. An emulsion with lowest viscosity was formed using ACO4 strain. The substantial stability of the oil-in-water emulsion allows the heavy oil to be transported practically over long distances or remain stationary for a considerable period of time prior to utilization. As the result of Taguchi analysis, the temperature and concentration of the emulsifier had a significant influence on viscosity reduction of the emulsion. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Stability evaluation of quality parameters for palm oil products at low temperature storage.

Science.gov (United States)

Ramli, Nur Aainaa Syahirah; Mohd Noor, Mohd Azmil; Musa, Hajar; Ghazali, Razmah

2018-07-01

Palm oil is one of the major oils and fats produced and traded worldwide. The value of palm oil products is mainly influenced by their quality. According to ISO 17025:2005, accredited laboratories require a quality control procedure with respect to monitoring the validity of tests for determination of quality parameters. This includes the regular use of internal quality control using secondary reference materials. Unfortunately, palm oil reference materials are not currently available. To establish internal quality control samples, the stability of quality parameters needs to be evaluated. In the present study, the stability of quality parameters for palm oil products was examined over 10 months at low temperature storage (6 ± 2 °C). The palm oil products tested included crude palm oil (CPO); refined, bleached and deodorized (RBD) palm oil (RBDPO); RBD palm olein (RBDPOo); and RBD palm stearin (RBDPS). The quality parameters of the oils [i.e. moisture content, free fatty acid content (FFA), iodine value (IV), fatty acids composition (FAC) and slip melting point (SMP)] were determined prior to and throughout the storage period. The moisture, FFA, IV, FAC and SMP for palm oil products changed significantly (P  0.05). The stability study indicated that the quality of the palm oil products was stable within the specified limits throughout the storage period at low temperature. The storage conditions preserved the quality of palm oil products throughout the storage period. These findings qualify the use of the palm oil products CPO, RBDPO, RBDPOo and RBDPS as control samples in the validation of test results. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

NARCIS (Netherlands)

Krebs, T.; Schroën, C.G.P.H.; Boom, R.M.

2011-01-01

The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend

Modulation and Stabilization of Silk Fibroin-Coated Oil-in-Water Emulsions

Directory of Open Access Journals (Sweden)

Zhong-Min Chen

2009-01-01

Full Text Available The purpose of this study is to prepare and characterize stable oil-in-water emulsions containing droplets coated with silk fibroin. Silk fibroin, a native edible fibrous protein originating from silkworm cocoons, was used to prepare 10 % (by mass corn oil-in-water emulsions at ambient temperature (pH=7.0, 10 mM phosphate buffer. Emulsions with relatively small mean particle diameter (d32=0.47 μm and extremely good creaming stability (>7 days could be produced at silk fibroin concentration of 1 % (by mass. The influence of pH (2–8, thermal processing (60–90 °C, 20 min, and concentration of salt (c(NaCl=0–250 mM on the properties and stability of the emulsions was analyzed using ζ-potential, particle size, and creaming stability measurements. The isoelectric point of droplets stabilized with silk fibroin was pH~4. The emulsions were stable to droplet flocculation and creaming at any pH except intermediate value (pH=4.0 when stored at room temperature, which was attributed to their relatively low ζ-potential. Their ζ-potential went from around 25 to –35 mV as the pH was increased from 2 to 8. The emulsions were also stable to thermal treatment (60 and 90 °C for 20 min, pH=3 and 7, with a slight decrease in the magnitude of ζ-potential at temperatures exceeding 60 °C. The emulsions were unstable to aggregation and creaming even at relatively low salt concentrations (c(NaCl=0–250 mM, pH=3 and 7 as a result of electrostatic screening effects. These results suggest that bulk oil stabilized with silk fibroin has improved physical stability and may provide a new way of creating functional oil products and delivery systems.

World oil prices: Up or down in 1995? and beyond?

International Nuclear Information System (INIS)

Browning, R.E.

1994-01-01

After a brief review of historical oil prices up to 1993-94, the factors influencing future prices are discussed. A survey of oil supply and demand over 1986-1993 shows oil demand has risen in Asia and fallen in the former Soviet Union and central/eastern Europe (FSU/CEE). Non-OPEC oil supply fell from 42.1 million bbl/d (MMBD) in 1986 to 40.6 MMBD in 1993, reflecting declines in Russian and U.S. production. Total OPEC production rose in the same period from 18.3 MMBD to 24.7 MMBD. OPEC production will continue to be dominant in determining prices, and demand in growing Asian economies and the FSU/CEE countries will be the most important and uncertain demand-side factor. If 7.5 MMBD of new OPEC capacity comes on stream by 2000 and OPEC production averages 31 MMBD in 2000, the utilization rate for OPEC oil at that time would be about the same as in 1973-79 and 1994. World oil production costs vary considerably by region, with the USA, North Sea, and Canada having relatively high costs; yet even in those regions, costs have been declining. A global weighted average cost based on 1993 production is $8-9/bbl. Fiscal and financial factors affecting oil prices include the need for oil revenue among oil producers. This need will put pressure on FSU economies to continue exports, although increases in such exports will require new infrastructure. In any case, the world oil market is likely to see a continuing trend to regarding oil as a commodity, which tends to reduce the control that physical participants exert on price-setting. Long-term real prices are not expected to rise but will likely remain volatile, cycling around $13/bbl. Spot prices in 1995 for West Texas Intermediate are forecast to be in the $16-20/bbl range. 4 figs., 4 tabs

Bio-Oil Separation and Stabilization by Supercritical Fluid Fractionation. 2014 Final Report

Energy Technology Data Exchange (ETDEWEB)

Agblevor, Foster [Utah State Univ., Logan, UT (United States); Petkovic, Lucia [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bennion, Edward [Utah State Univ., Logan, UT (United States); Quinn, Jason [Utah State Univ., Logan, UT (United States); Moses, John [CF Technologies, Hyde Park, MA (United States); Newby, Deborah [Idaho National Lab. (INL), Idaho Falls, ID (United States); Ginosar, Daniel [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2014-03-01

The objective of this project is to use supercritical fluids to separate and fractionate algal-based bio-oils into stable products that can be subsequently upgraded to produce drop-in renewable fuels. To accomplish this objective, algae was grown and thermochemically converted to bio-oils using hydrothermal liquefaction (HTL), pyrolysis, and catalytic pyrolysis. The bio-oils were separated into an extract and a raffinate using near-critical propane or carbon dioxide. The fractions were then subjected to thermal aging studies to determine if the extraction process had stabilized the products. It was found that the propane extract fraction was twice as stable as the parent catalytic pyrolysis bio-oils as measured by the change in viscosity after two weeks of accelerated aging at 80°C. Further, in-situ NMR aging studies found that the propane extract was chemically more stable than the parent bio-oil. Thus the milestone of stabilizing the product was met. A preliminary design of the extraction plant was prepared. The design was based on a depot scale plant processing 20,000,000 gallons per year of bio-oil. It was estimated that the capital costs for such a plant would be $8,700,000 with an operating cost of $3,500,000 per year. On a per gallon of product cost and a 10% annual rate of return, capital costs would represent $0.06 per gallon and operating costs would amount to $0.20 per gallon. Further, it was found that the energy required to run the process represented 6.2% of the energy available in the bio-oil, meeting the milestone of less than 20%. Life cycle analysis and greenhouse gas (GHG) emission analysis found that the energy for running the critical fluid separation process and the GHG emissions were minor compared to all the inputs to the overall well to pump system. For the well to pump system boundary, energetics in biofuel conversion are typically dominated by energy demands in the growth, dewater, and thermochemical process. Bio-oil stabilization by

Production, Characterization, and Stability of Orange or Eucalyptus Essential Oil/β-Cyclodextrin Inclusion Complex.

Science.gov (United States)

Kringel, Dianini Hüttner; Antunes, Mariana Dias; Klein, Bruna; Crizel, Rosane Lopes; Wagner, Roger; de Oliveira, Roberto Pedroso; Dias, Alvaro Renato Guerra; Zavareze, Elessandra da Rosa

2017-11-01

The aim of this study was to produce and characterize inclusion complexes (IC) between β-cyclodextrin (β-CD) and orange essential oil (OEO) or eucalyptus essential oil (EEO), and to compare these with their pure compounds and physical mixtures. The samples were evaluated by chemical composition, morphology, thermal stability, and volatile compounds by static headspace-gas chromatography (SH-GC). Comparing the free essential oil and physical mixture with the inclusion complex, of both essential oils (OEO and EEO), it was observed differences occurred in the chemical composition, thermal stability, and morphology. These differences show that there was the formation of the inclusion complex and demonstrate the necessity of the precipitation method used to guarantee the interaction between β-CD and essential oils. The slow loss of the volatile compounds from both essential oils, when complexed with β-CD, showed a higher stability when compared with their physical mixtures and free essential oils. Therefore, the results showed that the chemical composition, molecular size, and structure of the essential oils influence the characteristics of the inclusion complexes. The application of the β-CD in the formation of inclusion complexes with essential oils can expand the potential applications in foods. © 2017 Institute of Food Technologists®.

Proceedings of the CERI 2003 World Oil Conference : What lies beneath? CD-ROM ed.

International Nuclear Information System (INIS)

2003-01-01

The 22 presentations at this conference reflected recent developments in the international petroleum industry with particular focus on the outlook of world energy markets and prospects for oil supply and reserves. Topics of discussion included the industry structure, development and operating costs, international spending, the expansion of world oil markets, market access, as well as new technology development and application. The papers also covered environmental issues such as climate change and the responsible use of water. The conference provided an opportunity for participants to discuss issues regarding oil supply and demand, oil prices, Canada's oil sands, and what role non-conventional oil plays in the current marketplace. The conference was divided into 7 sessions entitled: (1) outlook for oil prices, (2) global oil supplies, (3) oil and money, (4) downstream issues, (5) markets for Canadian bitumen and synthetics, (6) Canada's east coast, and (7) the geopolitical landscape. Three papers were indexed separately for inclusion in the database. tabs., figs

Effects of fish oil type, lipid antioxidants and presence of rapeseed oil on oxidative flavour stability of fish oil enriched milk

DEFF Research Database (Denmark)

Bruni Let, Mette; Jacobsen, Charlotte; Meyer, Anne S.

2004-01-01

As a part of our ongoing experiments on optimization of the oxidative stability of fish oils in genuine food systems, this study investigated the oxidative deterioration of fish oil enriched milk emulsions during cold storage. The experimental data showed that addition of rapeseed oil to fish oil...... (1:1) prior to emulsification into milk significantly protected the emulsions against oxidative deterioration. Addition of propyl gallate and a citric acid ester to the fish oil prior to emulsification also protected the fish oil enriched milk during storage. Emulsions containing a rapeseed:fish oil...... mixture were oxidatively stable during 11 d at 2 øC. Thus, no additional inhibitory effect of the added antioxidants was observed. The peroxide value and concentrations of five selected volatiles derived from n- 3 PUFA degradation in rapeseed:fish oil mixture emulsions were not significantly different...

Evaluation of Antioxidant Activity and Cytotoxicity of Cumin Seed Oil Nanoemulsion Stabilized by Sodium Caseinate- Guar Gum

Directory of Open Access Journals (Sweden)

Parastoo Farshi 1, Mahnaz Tabibiazar 2 * , Marjan Ghorbani 3, Hamed Hamishehkar 3

2017-12-01

Full Text Available Background: The objective of this study was to prepare the sodium caseinate- guar gum stabilized nanoemulsion of cumin seed oil (Cumminum cyminum using ultrasonication method. Meanwhile, the effect of nanoemulsification on the antioxidant and cytotoxicity of the cumin seed oil was evaluated. Method: The effect of concentration of sodium casienate and guar gum was investigated on droplet size, thermal and oxidative stability of cumin seed oil nanoemulsion using TBARS and z-average measurements, the antioxidant activity was evaluated by DPPH scavenging and iron reducing power measurements. The biocompatibility and the cytotoxicity of the cumin seed oil nanoemulsion were evaluated by MTT assay test and compared with cumin seed oil and cumin seed oil free-nanoemulsion. Results: GC–MS analysis indicated 15 compounds in the cumin seed oil. The nanoemulsions were stabilized by sodium caseinate-guar gum complex. The minimum and stable droplets (155 ± 8 nm of nanoemulsion were formulated when the concentration of essential oil in oil phase was 30 % (w/w. DPPH radical scavenging ability, iron reducing power and cytotoxicity of nanoemulsified cumin seed oil were significantly higher than cumin seed oil (p<0.05 Conclusion: In this study, cumin seed oil nanoemulsion was prepared and stabilized by sodium caseinate- guar gum. The aforementioned nanoemulsion had good stability even after 60 days storage at 4ºC. Antioxidant and cytotoxicity of cumin seed oil were increased by nanoemulsification. It can be concluded that cumin seed oil nanoemulsion has the potential to use as natural preservative and anticancer product in food industry.

Stability studies on refined soybean oil stored in various conditions

International Nuclear Information System (INIS)

Arawande, J.O.; Amoo, I.A.

2008-01-01

The 12 months stability study of freshly produced refined soybean oil revealed that refined soybean oil stored in plastic containers in dark was more hydrolytically and oxidatively stable than that stored in other containers in light condition. There was no significant difference at P < 0.05 in free fatty acids and acid value of oil stored under light and dark conditions in tin and glass containers but there was significant difference at P < 0.05 in peroxide value of oil stored in light and dark conditions in all the storage containers. Light increased the degree of oxidative rancidity of refined soybean oil, the most in tin containers, followed by glass containers and the least in plastic containers. (author)

Dispersion Stability of O/W Emulsions with Different Oil Contents Under Various Freezing and Thawing Conditions.

Science.gov (United States)

Katsuki, Kazutaka; Miyagawa, Yayoi; Nakagawa, Kyuya; Adachi, Shuji

2017-07-01

Freezing and thawing of oil-in-water (O/W) emulsion-type foods bring about oil-water separation and deterioration; hence, the effects of freezing and thawing conditions on the destabilization of O/W emulsions were examined. The freezing rate and thawing temperature hardly affected the stability of the O/W emulsion. O/W emulsions having different oil fractions were stored at temperatures ranging from -30 to -20 °C and then thawed. The stability after thawing depended on the storage temperature, irrespective of the oil fraction of the emulsion. A good correlation was found between the time at which the stability began to decrease and the time taken for the oil to crystalize. These results indicated that the dominant cause for the destabilization of the O/W emulsion during freezing and thawing is the crystallization of the oil phase and that the effects of the freezing and thawing rates on the stability are insignificant. © 2017 Institute of Food Technologists®.

Studied on Virgin Coconut Oil (VCO) and Olive Oil (OO) as an Alternative for Stabilizer of Radiation Vulcanized Natural Rubber Latex (RVNRL) Preparation

International Nuclear Information System (INIS)

Syuhada Ramli; Sofian Ibrahim; Mohd Noorwadi Mat Lazim

2016-01-01

This paper presents the effects of virgin coconut oil (VCO) and olive oil (OO) as an alternative stabilizer in the radiation vulcanized natural rubber latex (RVNRL). Potassium laurite (KL) as a stabilizer considered as a control of RVNRL sample were compared to mixed ratio 1:1 KL: VCO and 1:1 KL: OO stabilizer formulation. Total solid content (TSC) and tensile strength (TS) results showed no significant different between the formulations. Mechanical stability time (MST) indicates higher stability of RVNRL with addition of VCO. The fatty acid composition in VCO indicate VCO was acting well as stabilizer for latex stabilizer formulation. (author)

Near-term world oil markets : economics, politics and prices

International Nuclear Information System (INIS)

Dwarkin, J.

2002-01-01

This paper discusses the three main factors that will determine how OPEC oil production will impact on energy markets. OPEC reassured the market in September 2001, following the terrorist attack in New York that it would not cut oil production, but by December 2001, OPEC was threatening that it would cut production unless many key non-OPEC producers collaborated to shore up prices. On January 1, 2002, OPEC members went ahead with a quota reduction, based on pledges of cuts from the non-OPEC oil exporting countries. World economies, oil demand, and the path which the U.S. economy will take during 2002 is critical in determining what happens next in terms of oil production from OPEC. Another important factor is knowing whether non-OPEC producers will actually cut output to a significant extent. The most critical factor will be the response by OPEC members if non-OPEC exporting countries do not keep their promise

Stabilization of Empty Fruit Bunch derived Bio-oil using Solvents

Directory of Open Access Journals (Sweden)

Chung Loong Yiin

2016-03-01

Full Text Available The intention of this research was to select the ideal condition for accelerated aging of bio-oil and the consequences of additive in stabilizing the bio-oil. The bio-oil was produced from the catalytic pyrolysis of empty fruit bunch. The optimum reaction conditions applied to obtain the utmost bio-oil yield were 5 wt% of H-Y catalyst at reaction temperature of 500 °C and nitrogen flow rate of 100 ml/min. A 10 wt% of solvents including acetone, ethanol, and ethyl acetate were used to study the bio-oil’s stability. All the test samples were subjected to accelerated aging at temperature of 80 oC for 7 days. The properties of samples used as the indicator of aging were viscosity and water content. The effectiveness of solvents increased in the following order: acetone, ethyl acetate, and 95 vol% ethanol. Based on the result of Gas chromatography-mass spectrometry (GC-MS, it could impede the chain of polymerization by converting the active units in the oligomer chain to inactive units. The solvent reacted to form low molecular weight products which resulted in lower viscosity and lessen the water content in bio-oil. Addition of 95 vol% ethanol also inhibited phase separation.

Bio-Oil Separation and Stabilization by Near-Critical Propane Fractionation

Energy Technology Data Exchange (ETDEWEB)

Ginosar, Daniel M.; Petkovic, Lucia M.; Agblevor, Foster A.

2016-08-01

Bio-oils produced by thermal process are promising sources of sustainable, low greenhouse gas alternative fuels. These thermal processes are also well suited to decentralized energy production due to low capital and operating costs. Algae feedstocks for bio-oil production are of particular interest, due in part to their high-energy growth yields. Further, algae can be grown in non-arable areas in fresh, brackish, salt water, or even waste water. Unfortunately, bio-oils produced by thermal processes present significant stability challenges. These oils have complex chemical compositions, are viscous, reactive, and thermally unstable. Further, the components within the oils are difficult to separate by fractional distillation. By far, the most effective separation and stabilization method has been solvent extraction. However, liquid phase extraction processes pose two main obstacles to commercialization; they require a significant amount of energy to remove and recover the solvent from the product, and they have a propensity for the solvent to become contaminated with minerals from the char and ash present in the original bio-oil. Separation and fractionation of thermally produced bio-oils using supercritical fluids (SCF) offers the advantages of liquid solvent extraction while drastically reducing energy demands and the predisposition to carry over solids into the extracted phase. SCFs are dense fluids with liquid-like solvent properties and gas-like transport properties. Further, SCF density and solvent strength can be tuned with minor adjustments in pressure, co-solvent addition, or gas anti-solvent addition. Catalytic pyrolysis oils were produced from Scenedesmus dimorphus algae using a fluid catalytic cracking catalyst. Bio-oil produced from catalytic fast pyrolysis (CFP) was separated using critical fluids. Propane extraction was performed at 65 °C at a fluid reduced pressure of 2.0 (85 bar) using an eight to one solvent to feed ratio by weight. Extraction of

Effect of rosemary extract and TBHQ on the stability of radish seed oil

International Nuclear Information System (INIS)

Gongling, Z.; Yancheng, G.

2016-01-01

The effects of rosemary extract (RE) and tert-Butylhydroquinone (TBHQ) on the storage stability of radish seed oil were studied according to the change of the acid value, peroxide value, tocopherol and sulforaphene in radish seed oil. The results showed that under conditions of accelerated oxidation by (60+-1) degree C, the storage stability of the radish seed oil with antioxidants could be significantly improved, among which TBHQ was better than RE. Besides, RE and TBHQ had a synergistic effect on antioxidation. The compound of 0.01% RE and 0.01% TBHQ had a better antioxidation effect than 0.07% RE and 0.02% TBHQ respectively, which recommended it can be a suitable antioxidant of radish seed oil. (author)

Stability of compounded trilostane suspension in cod liver oil.

Science.gov (United States)

Crosby, Jesse; Brown, Stacy

2017-10-01

Trilostane is a synthetic steroid analog used to treat canine hyperadrenocorticism. For small dogs, the dose found in commercially available dosage forms of trilostane is sometimes too high. Compounding trilostane in a liquid diluent provides an option for more precise dosing and adjustments, and can be easier to administer, versus a tablet or capsule. Trilostane suspends well in cod liver oil, which is generally palatable to dogs. The stability of a compounded trilostane suspension in cod liver oil stored at room temperature was investigated for 90 days. Compounded trilostane retained stability, defined as maintaining 90-105% labeled value, for 60 days when stored in amber glass bottles. However, drug potency fell >10% below the labeled value when stored in amber plastic bottles after 7 days. Copyright © 2017 Elsevier Ltd. All rights reserved.

Study of chemical stability of lemon oil components in sodium caseinate-lactose glycoconjugate-stabilized oil-in-water emulsions using solid-phase microextraction-gas chromatography.

Science.gov (United States)

Sabik, Hassan; Achouri, Allaoua; Alfaro, Maria; Pelletier, Marylène; Belanger, Denis; Britten, Michel; Fustier, Patrick

2014-07-25

A headspace solid-phase microextraction (HS-SPME) combined with gas chromatography-mass spectrometry (GC/MS) method was developed to quantify lemon oil components and their degradation products in oil-in-water (O/W) emulsions prepared with sodium caseinate-heated-lactose (NaC-T + Lact) glycoconjugates as wall materials at two pH values (3.0 and 6.8). NaC-T + Lact conjugates had a significantly lower solubility at both pHs. Hydrolysis prior to glycation enhanced the solubility of glycoconjugates. Glycation with lactose did not improve the emulsion activity of NaC, while caseinate glycoconjugates showed much stronger antioxidant activity than the NaC-control sample. This might be due to the presence of melanoidins formed between the sugar and amino acid compounds as supported by the increase in browning intensity. Among the SPME-fibres tested, carboxen/polydimethylsiloxane (CAR/PDMS) provided better results in terms of sensitivity and selectivity for oil lemon components and their degradation products. Storage studies of these emulsions demonstrated that glycated NaC-T + Lact showed protection against peroxidation compared to the control. However, acidic pH conditions altered their stability over storage time. The major off-flavor components (α-terpineol and carvone) were inhibited in emulsions stabilized with glycated NaC, particularly at pH 6.8. The use of NaC-T + Lact conjugates showed improved encapsulation efficiency and stability and could be used as potential food ingredient-emulsifiers for stabilising citrus oils against oxidative degradation in food and beverage applications.

Studies on carotenoids and oxidative stability of winter squash seed and soybean oils

Directory of Open Access Journals (Sweden)

Helmy, H. E.

1992-12-01

Full Text Available Winter squash seed and soybean oils were extracted with commercial hexane. Carotenoids and other pigments m the oils were studied using spectrophotometric and thin layer chromatographic analysis. Three types of pigments were identified: carotenoids. mainly lutein and β-carotene, chlorophyll and some unidentified pigments. Carotenoids content were 70, 60, 0 ppm in crude, refined and bleached winter squash seed oil, and 80, 65, 0 ppm in crude, refined and bleached soybean oil respectively. Stability was evaluated for crude, refined and bleached winter squash seed and soybean oils and an 1:1 admixture. Mixing winter squash seed oil with soybean oil increased the stability of soybean oil. Crude oil showed greater stability than refined and bleached oils.

Se han extraído con hexano comercial aceites de semilla de calabaza y de soja. Usando análisis espectrofotométrico y cromatografía en capa fina se han estudiado en estos aceites tres tipos de pigmentos: carotenoides, principalmente luteína y β-caroteno, clorofilas y otros no identificados. Los contenidos en carotenoides fueron 70, 60, 0 ppm en aceite de semilla de calabaza de invierno crudo, refinado y decolorado, y 80, 65, 0 ppm en aceite de soja crudo, refinado y decolorado respectivamente. Se ha evaluado la estabilidad de aceites de semilla de calabaza de invierno, soja y una mezcla 1:1 de ambos, en sus estados crudo, refinado y decolorado. La mezcla de semilla de calabaza de invierno con aceite de soja aumentó la estabilidad de este último. El aceite crudo mostró una mayor estabilidad que los aceites refinados y decolorados.

Russian oil prices: courting the world market

International Nuclear Information System (INIS)

Khartukov, E.M.

1995-01-01

The export and oil pricing of Russian crude was discussed. Russian crude and oil product exports are not yet wholly competitive with world oil markets. It was suggested that to do so, would be neither desirable nor actually possible at present. The reason for this is related to Russia's export duties regime and Russia's trade with its neighbouring countries which include the former Soviet republics. In the first half of 1995, the average border price of crude destined for those countries was US$75.04/tonne as opposed to US$114.77/tonne for crude exported to 'far-abroad', hard-currency markets. A breakdown of Russia's export duties for liquid fuels and a typical breakdown of export and domestic prices for Russian oil was provided. Russian crude is considerably under-priced mainly because of the poor state of the national refining industry which is in need of radical modernization. It was suggested that instead of globalization, it would be more appropriate to redirect the priorities of Russian energy policy towards defining optimal use of Russia's available energy potential, and rationalizing its domestic price structure first, which is the root cause of the national price problem. 5 refs., 5 tabs., 2 figs

Evaluation of stability and viscosity measurement of emulsion from oil from production in northern oilfield in Thailand

Science.gov (United States)

Juntarasakul, O.; Maneeintr, K.

2018-04-01

Emulsion is normally present in oil due to the mixing occurring during oil recovery. The formation of emulsion can cause some problems in production and transportation. Viscosity and stability of emulsion play a key roles in oil transportation and separation to meet sales specification. Therefore, the aims of this research are to measure the viscosity of oil an emulsion and to evaluate the stability of emulsion of light oil from Fang oilfield in Thailand. The parameters of this study are temperature, shear rate and water cut ranging from 50 to 80 °C, 3.75 to 70 s-1 and 0 to 60%, respectively. These effects of parameters on viscosity and stability of emulsion are required for the design of the process and to increase oil production with various conditions. The results shows that viscosity decreases as temperature and shear rate increase. In contrast, viscosity becomes higher when water cut is lower. Furthermore, droplet sizes of water-in-oil emulsion at different conditions are investigated the stability of emulsion. The droplet sizes become smaller when high shear rate is applied and emulsion becomes more stable. Furthermore, correlations are developed to predict the viscosity and stability of the oil and emulsion from Thailand.

A literature review of demand studies in world oil markets

International Nuclear Information System (INIS)

Atkins, F.; Tayyebi Jazayeri, S.M.

2004-04-01

The literature on world oil market demands was reviewed, summarized and organized into seven major groupings. The objective was to model economic behaviour before and after price shocks. In particular, the paper demonstrated how the price elasticity of demand in world oil markets is estimated. It also showed how the relationship between energy and oil consumption and income are estimated. The income elasticity of demand was also estimated, and empirical estimates of the elasticity of aggregate output regarding crude oil and energy prices were presented. The paper also referred to the transportation sector and estimates of the changing nature of seasonal factors. The review showed that there is much heterogeneity of econometric results. The literature showed that demand increased considerably in response to the price shocks of the 1970s, but these shocks were reversed in the 1980s when the increase in demand did not correspond with the decrease in price. Some of the literature is driven by the belief that there must be a stable, non-linear model that fits the data both before and after price shocks. The authors question whether this could be true and propose an alternative hypothesis that there is a different model that pertains to economic behaviour after price shocks. 15 refs., 7 tabs., 1 fig

Characterization of Whey Protein Oil-In-Water Emulsions with Different Oil Concentrations Stabilized by Ultra-High Pressure Homogenization

Directory of Open Access Journals (Sweden)

Essam Hebishy

2017-02-01

Full Text Available In this study, the effect of ultra-high-pressure homogenization (UHPH: 100 or 200 MPa at 25 °C, in comparison to colloid mill (CM: 5000 rpm at 20 °C and conventional homogenization (CH: 15 MPa at 60 °C, on the stability of oil-in-water emulsions with different oil concentrations (10, 30 or 50 g/100 g emulsified by whey protein isolate (4 g/100 g was investigated. Emulsions were characterized for their microstructure, rheological properties, surface protein concentration (SPC, stability to creaming and oxidative stability under light (2000 lux/m2. UHPH produced emulsions containing lipid droplets in the sub-micron range (100–200 nm and with low protein concentrations on droplet surfaces. Droplet size (d3.2, µm was increased in CH and UHPH emulsions by increasing the oil concentration. CM emulsions exhibited Newtonian flow behaviour at all oil concentrations studied; however, the rheological behaviour of CH and UHPH emulsions varied from Newtonian flow (n ≈ 1 to shear-thinning (n ˂ 1 and thixotropic behaviour in emulsions containing 50% oil. This was confirmed by the non-significant differences in the d4.3 (µm value between the top and bottom of emulsions in tubes left at room temperature for nine days and also by a low migration velocity measured with a Turbiscan LAB instrument. UHPH emulsions showed significantly lower oxidation rates during 10 days storage in comparison to CM and CH emulsions as confirmed by hydroperoxides and thiobarbituric acid-reactive substances (TBARS. UHPH emulsions treated at 100 MPa were less oxidized than those treated at 200 MPa. The results from this study suggest that UHPH treatment generates emulsions that have a higher stability to creaming and lipid oxidation compared to colloid mill and conventional treatments.

Big questions cloud Iraq's future role in world oil market

International Nuclear Information System (INIS)

Tippee, B.

1992-01-01

This paper reports that Iraq raises questions for the world oil market beyond those frequently asked about when and under what circumstances it will resume exports. Two wars since 1981 have obscured encouraging results from a 20 year exploration program that were only beginning to come to light when Iraq invaded Kuwait in August 1990. Those results indicate the country might someday be able to produce much more than the 3.2 million b/d it was flowing before a United Nations embargo blocked exports. If exploratory potential is anywhere near what officials asserted in the late 1980s, and if Iraq eventually turns hospitable to international capital, the country could become a world class opportunity for oil companies as well as an exporter with productive capacity approaching that of Saudi Arabia. But political conditions can change quickly. Under a new, secular regime, Iraq might welcome non-Iraqi oil companies and capital as essential to economic recovery. It's a prospect that warrants a new industry look at what the country has revealed about its geology and exploration history

The Future of the Automobile in an Oil-Short World. Worldwatch Paper 32.

Science.gov (United States)

Brown, Lester R.; And Others

Possible future roles and designs of cars are examined in light of depletion of the earth's oil reserves. A major problem with regard to the rapidly changing world oil outlook is that cars will be competing with more essential claiments for scarce oil supplies including food production, industrial power, home heating, and running trucks and…

Studies for the stabilization of coal-oil mixtures. Final report, August 1978-May 1981

Energy Technology Data Exchange (ETDEWEB)

Botsaris, G.D.; Glazman, Y.M.; Adams-Viola, M.

1981-01-01

A fundamental understanding of the stabilization of coal-oil mixtures (COM) was developed. Aggregation of the coal particles was determined to control both the sedimentation and rheological properties of the COM. Sedimentation stability of COM prepared with coal, 80% < 200 mesh, is achieved by particle aggregation, which leads to the formation of a network of particles throughout the oil. The wettability of coal powders was evaluated by the Pickering emulsion test and a spherical agglomeration test to assess its effect on the stability of various COM formulations. Sedimentation stability of hydrophilic coal-oil-water mixtures (COWM) involves the formation of water bridges between the coal particles, while less stabilization of oleophilic COWM is achieved by the formation of an emulsion. Anionic SAA were least sensitive to the coal type and enhanced the aggregation stability of the suspension. The effect of cationic SAA, nonionic SAA and polymer additives depended upon the specific chemical structure of the SAA, the water content of the COM and the type of coal. The sedimentation stability of ultrafine COM was not directly due to the fineness of the powder but due to the formation of a network of flocculated particles.

Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oil

Energy Technology Data Exchange (ETDEWEB)

Gangwal, Santosh [Southern Research, Durham, NC (United States); Meng, Jiajia [Southern Research, Durham, NC (United States); McCabe, Kevin [Southern Research, Durham, NC (United States); Larson, Eric [Princeton Univ., NJ (United States). Princeton Environmental Inst.; Mastro, Kelly [Southern Research, Durham, NC (United States)

2016-04-25

Southern Research (SR) in cooperation with U.S. Department of Energy (DOE), Bioenergy Technology Office (BETO), investigated a biomass liquefaction process for economic production of stabilized refinery-ready bio-oil. The project was awarded by DOE under a Funding Opportunity Announcement (DE-FOA-0000686) for Bio-oil Stabilization and Commoditization that intended to evaluate the feasibility of using bio-oil as a potential feedstock in an existing petroleum refinery. SR investigated Topic Area 1 of the FOA at Technology Readiness Level 2-3 to develop thermochemical liquefaction technologies for producing a bio-oil feedstock from high-impact biomass that can be utilized within a petroleum refinery. Bio-oil obtained from fast pyrolysis of biomass is a green intermediate that can be further upgraded into a biofuel for blending in a petroleum refinery using a hydro-deoxygenation (HDO) route. Co-processing pyrolysis bio-oil in a petroleum refinery is an attractive approach to leverage the refinery’s existing capital. However, the petroleum industry is reluctant to accept pyrolysis bio-oil because of a lack of a standard definition for an acceptable bio-oil feedstock in existing refinery processes. Also per BETO’s multiyear program plan, fast pyrolysis-based bio-fuel is presently not cost competitive with petroleum-based transportation fuels. SR aims to develop and demonstrate a cost-effective low-severity thermal liquefaction and hydrodeoxygenation (HDO) process to convert woody biomass to stabilized bio-oils that can be directly blended with hydrotreater input streams in a petroleum refinery for production of gasoline and/or diesel range hydrocarbons. The specific project objectives are to demonstrate the processes at laboratory scale, characterize the bio-oil product and develop a plan in partnership with a refinery company to move the technology towards commercialization.

The status of world oil depletion at the end of 1995

International Nuclear Information System (INIS)

Campbell, C.J.

1996-01-01

An assessment is made of the reserves of conventional and non-conventional oil in the world as of the end of 1995. This takes into account the impacts of new discovery and advances in technology to make plausible estimates. Care is taken to clearly define conventional and non-conventional oil and whether or not natural gas liquids are included. (Author)

World crude oil and natural gas. A demand and supply model

International Nuclear Information System (INIS)

Krichene, Noureddine

2002-01-01

This paper examines world markets for crude oil and natural gas over the period 1918-1999; it analyzes the time-series properties of output and prices and estimates demand and supply elasticities during 1918-1973 and 1973-1999. Oil and gas prices were stable during the first period; they became volatile afterwards, reflecting deep changes in the market structure following the oil shock in 1973. Demand price elasticities were too low; however, demand income elasticities were high. Supply price elasticities were also too low. The elasticity estimates help to explain the market power of the oil producers and price volatility in response to shocks, and corroborate elasticity estimates in energy studies

Physicochemical properties of peanut oil-based diacylglycerol and their derived oil-in-water emulsions stabilized by sodium caseinate.

Science.gov (United States)

Long, Zhao; Zhao, Mouming; Liu, Ning; Liu, Daolin; Sun-Waterhouse, Dongxiao; Zhao, Qiangzhong

2015-10-01

High purity peanut oil-based diacylglycerol (PO-DAG) (94.95 wt%) was prepared via enzymatic glycerolysis from peanut oil (PO). The resulting dominance of DAGs was proven to greatly influence the properties of corresponding fresh or frozen-thawed emulsions. Stable fresh oil-in-water emulsions were produced using either PO-DAG or PO, with stability enhanced by increased concentrations of Na-CN. The lower equilibrium interfacial tension along with greater negative ζ-potential of PO revealed that Na-CN was preferentially adsorbed to the PO interface. Adding 0.05 mol/L NaCl to the PO emulsions minimized depletion flocculation caused by the unadsorbed Na-CN, but further NaCl addition increased oil droplet size and concomitant coalescence. For the PO-DAG emulsions, adding 0.2 mol/L NaCl did not significantly (p>0.05) affect their ζ-potential but adding 0.05 or 0.1 mol/L NaCl lowered ζ-potential, although NaCl at these concentrations increased oil droplet size and coalescence. Freezing-thawing process considerably weakened the stability of PO-DAG emulsions. Copyright © 2015 Elsevier Ltd. All rights reserved.

The PTRC : a world leader in enhanced heavy oil recovery

Energy Technology Data Exchange (ETDEWEB)

Kristoff, B.; Knudsen, R.; Asghari, K. [Petroleum Technology Research Centre, Regina, SK (Canada); Pappas, E.S. [Saskatchewan Research Council, Saskatoon, SK (Canada)

2006-07-01

The Petroleum Technology Research Centre (PTRC) fosters knowledge and progressive technologies to enhance the recovery of petroleum. This paper discussed the PTRC's leadership in enhanced heavy oil recovery, with particular reference to core research program such as heavy oil (post) cold flow; enhanced waterflooding; miscible/immiscible solvent injection; and near-wellbore conformance control. Other projects that were presented included a joint implementation of vapour extraction project (JIVE); and the IEA greenhouse gas (GHG) Weyburn-Midale carbon dioxide monitoring and storage project. The JIVE project will develop, demonstrate and evaluate solvent vapour extraction processes for enhanced oil recovery in heavy oil reservoirs. The GHG Weyburn-Midale project, launched in 2000, studies carbon dioxide injection and storage in partially depleted oil reservoirs. It was concluded that the PTRC continues to develop technologies to meet the world's energy requirements while mitigating both immediate and long-term environmental impacts. 4 figs.

Status of Oil and Natural Gas in the World and Turkey, and Studies conducted at ITU

International Nuclear Information System (INIS)

Onur, Mustafa

2006-01-01

Energy and its appropriate deployment are the most critical of all wealth generating activities, and they are the most important modern indicators of the wealth and poverty of nations. Humankind and energy will merge in an unbreakable bond for the entire future of humankind. Without dispute, the petroleum and natural gas industry is the world's largest energy sector and the second largest of the world's industries. Today, oil and gas account for 61 percent (39% oil and 24% natural gas) of the world's energy consumption. Including coal's 30 percent share, the hydrocarbon mix comprises more than 90 percent of the world's needs. Since the 19th century, the petroleum industry, including exploration, production, transportation (marine+pipeline), refinery, and marketing, have caused world changes, determined destiny of humankind, and generated immense wealth for both producers and users. It is also an accepted fact that the oil and natural gas will continue to be dominating energy sources, particularly as transportation fuels, for the world's energy needs, and will continue to cause world changes during the 21st century, at least for the next 25 years. Regarding Turkey's role in petroleum and natural gas, the figures are as follows: At the end of 2005, the proved oil and natural gas reserves of Turkey are reported as 1.2 million barrels (∼165.4 million tonnes) and 14.3 billion m 3 , respectively. When these figures are compared with the corresponding world's proved oil and natural gas reserves, which are 1.2 trillion barrels and 179.5 trillion m 3 , respectively, it is clear that Turkey's oil and natural gas reserves comprises only a very small portion of the world's corresponding reserves. Approximately only 8% and 3% of Turkey's oil and natural gas consumption are produced from domestic sources. At the end of 2005, Turkey's oil and natural gas productions from its domestic sources are 17 million barrels When considering the current high oil and natural gas prices (�

The Middle East: Its role in world oil. A survey of the issues

International Nuclear Information System (INIS)

Radetski, M.

1992-01-01

The importance of the Middle East oil resource base is exceptional, in quantitative as well as economic terms. A review is presented of this resource base, and the economic and political factors associated with it. In 1990 oil from the Middle East accounted for 27% of world output, and accounts for 65% of proven world oil reserves. The viability of OPEC's role in controlling market prices is discussed, and it is proposed that high prices such as those in the early 1980s are unlikely to re-occur, and that control of capacity to keep prices above competitive levels but not high enough to induce large scale expansion outside the region is the rational course of action. Political instability in the Middle East and its destabilizing impact on oil supply is discussed. 12 refs., 2 tabs

Oxidative stability during storage of structured lipids produced from fish oil and caprylic acid

DEFF Research Database (Denmark)

Nielsen, Nina Skall; Xu, Xuebing; Timm Heinrich, Maike

2004-01-01

Structured lipids produced by enzymatic or chemical methods for different applications have been receiving considerable attention. The oxidative stability of a randomized structured lipid (RFO), produced by chemical interesterification from fish oil (FO) and tricaprylin, and a specific structured...... lipid (SFO), produced by enzymatic interesterification from the same oil and caprylic acid, was compared with the stability of FO. Oils were stored at 2degreesC for 11 wk followed by storage at 20degreesC for 6 wk. In addition, the antioxidative effect of adding the metal chelators EDTA or citric acid...

Characteristics, Composition and Oxidative Stability of Lannea microcarpa Seed and Seed Oil

Directory of Open Access Journals (Sweden)

Patrice Bazongo

2014-02-01

Full Text Available The proximate composition of seeds and main physicochemical properties and thermal stability of oil extracted from Lannea microcarpa seeds were evaluated. The percentage composition of the seeds was: ash (3.11%, crude oil (64.90%, protein (21.14%, total carbohydrate (10.85% and moisture (3.24%. Physicochemical properties of the oil were: refractive index, 1.473; melting point, 22.60°C; saponification value, 194.23 mg of KOH/g of oil; iodine value, 61.33 g of I2/100 g of oil; acid value, 1.21 mg of KOH/g of oil; peroxide value, 1.48 meq of O2/kg of oil and oxidative stability index, 43.20 h. Oleic (43.45%, palmitic (34.45%, linoleic (11.20% and stearic (8.35% acids were the most dominant fatty acids. Triacylglycerols with equivalent carbon number (ECN 48 and ECN 46 were dominant (46.96% and 37.31%, respectively. The major triacylglycerol constituents were palmitoyl diolein (POO (21.23%, followed by dipalmitoyl olein (POP (16.47%, palmitoyl linoleyl olein (PLO (12.03%, dipalmitoyl linolein (PLP (10.85% and dioleoyl linolein (LOO (9.30%. The total polyphenol and tocopherol contents were 1.39 mg GAE g−1 DW and 578.56 ppm, respectively. γ-Tocopherol was the major tocopherol (437.23 ppm. These analytical results indicated that the L. microcarpa seed oil could be used as a frying oil and in the cosmetic industry.

Do emerging markets matter in the world oil pricing system? Evidence of imported crude by China and India

International Nuclear Information System (INIS)

Hong Li; Lin Xiaowen, Sharon

2011-01-01

This paper provides empirical evidence on the changing structure of world oil price system by identifying an additional driver-emerging market factor. We choose China and India as a representative of emerging markets to examine if the quantity of crude oil imported by China and India is significant in the existing oil pricing system (. Our data starts from January 2002 and ends in March 2010, which includes the oil shock of 2007-2008. We utilize cointegration and error correction model framework developed by and in the analysis. Our results indicate that demand from emerging markets has become a significant factor in the world oil pricing system since 2003. This result is significant as it lends empirical support to the widely held conjecture that the oil shock of 2007-2008 is a demand-led shock (). Our result also has significant policy implications that go beyond the oil shock. The emerging market factor is there to stay and reflects the changing power between emerging and developed economies in the world economic system as a result of decades of fast economic development in the former. It will certainly influence policy issues related to oil and beyond. - Highlights: → We test the existing oil price modelling with data from 2002-2010. → We find evidence of structural breaks in the world oil pricing model. → We find that emerging market factor is a new driver in the world oil pricing system since 2003. → The emerging market factor lends empirical support to 'consumption-led' conjecture of oil shock. → New factor reflects significant changes of oil demand landscape following shifting economic power.

Geopolitics of oil markets

International Nuclear Information System (INIS)

Liscom, W.L.

1991-01-01

Geopolitics can inject a great deal of uncertainty and cause fundamental shifts in the overall direction of oil markets, which would otherwise act in a fairly predictable and stable manner. The Iraqi invasion of Kuwait and the response of the USA were definitely linked with oil, and the aftermath of the invasion left four geopolitical issues affecting world oil markets. The provision authorizing $1.6 billion in Iraqi oil exports under the United Nations sanctions was imposed with little concern about the potential impact of these exports on the oil market; Iraq could export as much as 1 million bbl/d and it is unlikely that exports would be stopped once the $1.6 billion limit is reached. By making up most of the supply shortfall during the Kuwait crisis, Saudi Arabia suddenly became the producer of over a third of OPEC oil supplies and now dominates OPEC. The Saudis have indicated it will swing production according to world demand, irrespective of what OPEC wants, so that world oil demand will return strongly and remain. Middle East politics in general will determine the stability of oil supplies in the region for many of the countries. A producer-consumer dialogue at the high governmental level has started, with a view to some type of multilateral understanding in the light of mutual interests in secure oil supplies. This is not likely to have a big impact on oil markets without participation and support from the USA. The recent changes in the Soviet Union have potential impacts in regard to the attraction of that market for Western investment, in particular to assist exports. The worldwide environmental movement will also play a geopolitical role in the world oil market due to its influence on oil taxation policies

Adaptability and phenotypic stability of soybean cultivars for grain yield and oil content.

Science.gov (United States)

Silva, K B; Bruzi, A T; Zuffo, A M; Zambiazzi, E V; Soares, I O; de Rezende, P M; Fronza, V; Vilela, G D L; Botelho, F B S; Teixeira, C M; de O Coelho, M A

2016-04-25

The aim of this study was to verify the adaptability and stability of soybean cultivars with regards to yield and oil content. Data of soybean yield and oil content were used from experiments set up in six environments in the 2011/12 and 2012/13 crop seasons in the municipalities of Patos de Minas, Uberaba, Lavras, and São Gotardo, Minas Gerais, Brazil, testing 36 commercial soybean cultivars of both conventional and transgenic varieties. The Wricke method and GGE biplot analysis were used to evaluate adaptability and stability of these cultivars. Large variations were observed in grain yield in relation to the different environments studied, showing that these materials are adaptable. The cultivars exhibited significant differences in oil content. The cultivars BRSGO204 (Goiânia) and BRSMG (Garantia) exhibited the greatest average grain yield in the different environments studied, and the cultivar BRSMG 760 SRR had the greatest oil content among the cultivars evaluated. Ecovalence was adopted to identify the most stable cultivars, and the estimates were nearly uniform both for grain yield and oil content, showing a variation of 0.07 and 0.01%, respectively. The GGE biplot was efficient at identifying cultivars with high adaptability and phenotype stability.

Roasting pumpkin seeds and changes in the composition and oxidative stability of cold-pressed oils.

Science.gov (United States)

Raczyk, Marianna; Siger, Aleksander; Radziejewska-Kubzdela, Elżbieta; Ratusz, Katarzyna; Rudzińska, Magdalena

2017-01-01

Pumpkin seed oil is valuable oil for its distinctive taste and aroma, as well as supposed health- promoting properties. The aim of this study was to investigate how roasting pumpkin seeds influences the physicochemical properties of cold-pressed oils. The fatty acid composition, content of phytosterols, carotenoids and tocopherols, oxidative stability and colour were determined in oils after cold pressing and storage for 3 months using GC-FID, GCxGC-ToFMS, HPLC, Rancimat and spectrophotometric methods. The results of this study indicate that the seed-roasting and storage process have no effect on the fatty acid composition of pumpkin seed oils, but does affect phytosterols and tocopherols. The carotenoid content decreased after storage. The colour of the roasted oil was darker and changed significantly during storage. Pumpkin oil obtained from roasted seeds shows better physicochemical properties and oxidative stability than oil from unroasted seeds.

Selective retardation of perfume oil evaporation from oil-in-water emulsions stabilized by either surfactant or nanoparticles.

Science.gov (United States)

Binks, Bernard P; Fletcher, Paul D I; Holt, Benjamin L; Beaussoubre, Pascal; Wong, Kenneth

2010-12-07

We have used dynamic headspace analysis to investigate the evaporation rates of perfume oils from stirred oil-in-water emulsions into a flowing gas stream. We compare the behavior of an oil of low water solubility (limonene) and one of high water solubility (benzyl acetate). It is shown how the evaporation of an oil of low water solubility is selectively retarded and how the retardation effect depends on the oil volume fraction in the emulsion. We compare how the evaporation retardation depends on the nature of the adsorbed film stabilizing the emulsion. Surfactant films are less effective than adsorbed films of nanoparticles, and the retardation can be further enhanced by compression of the adsorbed nanoparticle films by preshrinking the emulsion drops.

The social costs to the US of monopolization of the world oil market, 1972--1991

International Nuclear Information System (INIS)

Greene, D.L.; Leiby, P.N.

1993-03-01

The partial monopolization of the world oil market by the OPEC cartel has produced significant economic costs to the economies of the world. This paper reports estimates of the costs of monopolization of oil to the US over the period 1972--1991. Two fundamental assumptions of the analysis are, (1) that OPEC has acted as a monopoly, albeit with limited control, knowledge, and ability to act and, (2) that the US and other consuming nations could, through collective (social) action affect the cartel's ability to act as a monopoly. We measure total costs by comparing actual costs for the 1972--1991 period to a hypothetical ''more competitive'' world oil market scenario. By measuring past costs we avoid the enormous uncertainties about the future course of the world oil market and leave to the reader's judgment the issue of how much the future will be like the past. We note that total cost numbers cannot be used to determine the value of reducing US oil use by one barrel. They are useful for describing the overall size of the petroleum problem and are one important factor in deciding how much effort should be devoted to solving it. Monopoly pricing of oil transfers wealth from US oil consumers to foreign oil producers and, by increasing theeconomic scarcity of oil, reduces the economy's potential to produce. The actions of the OPEC cartel have also produced oil price shocks, both upward and downward, that generate additional costs because of the economy's inherent inability to adjust quickly to a large change in energy prices. Estimated total costs to the United States from these three sources for the 1972--1991 period are put at $4.1 trillion in 1990$($1.2 T wealth transfer, $0.8 T macroeconomic adjustment costs, $2.1 T potential GNP losses). The cost of the US's primary oil supply contingency program is small ($10 B) by comparison

The relationship between oil price shocks and China's macro-economy. An empirical analysis

International Nuclear Information System (INIS)

Du, Limin; Yanan, He; Wei; Chu

2010-01-01

This paper investigates the relationship between the world oil price and China's macro-economy based on a monthly time series from 1995:1 to 2008:12, using the method of multivariate vector autoregression (VAR). The results show that the world oil price affects the economic growth and inflation of China significantly, and the impact is non-linear. On the other hand, China's economic activity fails to affect the world oil price, which means that the world oil price is still exogenous with respect to China's macro-economy in time series sense, and China has not yet had an oil pricing power in the world oil markets. The structural stability tests demonstrate that there is a structural break in the VAR model because of the reforms of China's oil pricing mechanism, thus it is more appropriate to break the whole sample into different sub-samples for the estimation of the model. (author)

Effect of Opuntia ficus-indica flowers maceration on quality and on heat stability of olive oil.

Science.gov (United States)

Ammar, Imène; BenAmira, Amal; Khemakem, Ibtihel; Attia, Hamadi; Ennouri, Monia

2017-05-01

This study was focused on the evaluation of the quality and the oxidative stability of olive oil added with Opuntia ficus - indica flowers. Two different amounts of O. ficus - indica flowers were considered 5 and 15% (w/w). The olive oils were evaluated towards their quality, fatty acids profile, total phenol contents and thermal properties by differential scanning calorimetry. The oxidative stability was also monitored by employing the Rancimat and the oven test based on accelerating the oxidation process during storage. The addition of O. ficus - indica flowers induced an increase in free acidity values and a variation in fatty acids profile of olive oils but values remained under the limits required for an extra-virgin olive oil. The obtained olive oils were nutritionally enriched due to the increase in their phenols content. The oxidative stability was generally improved, mainly in olive oil enriched with 5% Opuntia ficus - indica flowers. These findings proved that this enriched olive oil could be considered as a product with a greater added value.

Uniform-sized silicone oil microemulsions: preparation, investigation of stability and deposition on hair surface.

Science.gov (United States)

Nazir, Habiba; Lv, Piping; Wang, Lianyan; Lian, Guoping; Zhu, Shiping; Ma, Guanghui

2011-12-01

Emulsions are commonly used in foods, pharmaceuticals and home-personal-care products. For emulsion based products, it is highly desirable to control the droplet size distribution to improve storage stability, appearance and in-use property. We report preparation of uniform-sized silicone oil microemulsions with different droplets diameters (1.4-40.0 μm) using SPG membrane emulsification technique. These microemulsions were then added into model shampoos and conditioners to investigate the effects of size, uniformity, and storage stability on silicone oil deposition on hair surface. We observed much improved storage stability of uniform-sized microemulsions when the droplets diameter was ≤22.7 μm. The uniform-sized microemulsion of 40.0 μm was less stable but still more stable than non-uniform sized microemulsions prepared by conventional homogenizer. The results clearly indicated that uniform-sized droplets enhanced the deposition of silicone oil on hair and deposition increased with decreasing droplet size. Hair switches washed with small uniform-sized droplets had lower values of coefficient of friction compared with those washed with larger uniform and non-uniform droplets. Moreover the addition of alginate thickener in the shampoos and conditioners further enhanced the deposition of silicone oil on hair. The good correlation between silicone oil droplets stability, deposition on hair and resultant friction of hair support that droplet size and uniformity are important factors for controlling the stability and deposition property of emulsion based products such as shampoo and conditioner. Copyright © 2011 Elsevier Inc. All rights reserved.

World crude oil and natural gas: a demand and supply model

International Nuclear Information System (INIS)

Krichene, N.

2002-01-01

This paper examines world markets for crude oil and natural gas over the period 1918-1999; it analyzes the time-series properties of output and prices and estimates demand and supply elasticities during 1918-1973 and 1973-1999. Oil and gas prices were stable during the first period; they became volatile afterwards, reflecting deep changes in the market structure following the oil shock in 1973. Demand price elasticities were too low; however, demand income elasticities were high. Supply price elasticities were also too low. The elasticity estimates help to explain the market power of the oil producers and price volatility in response to shocks, and corroborate elasticity estimates in energy studies. (author)

Physicochemical Properties and Storage Stability of Microencapsulated DHA-Rich Oil with Different Wall Materials.

Science.gov (United States)

Chen, Wuxi; Wang, Haijun; Zhang, Ke; Gao, Feng; Chen, Shulin; Li, Demao

2016-08-01

This study aimed to evaluate the physicochemical properties and storage stability of microencapsulated DHA-rich oil spray dried with different wall materials: model 1 (modified starch, gum arabic, and maltodextrin), model 2 (soy protein isolate, gum arabic, and maltodextrin), and model 3 (casein, glucose, and lactose). The results indicated that model 3 exhibited the highest microencapsulation efficiency (98.66 %) and emulsion stability (>99 %), with a moisture content and mean particle size of 1.663 % and 14.173 μm, respectively. Differential scanning calorimetry analysis indicated that the Tm of DHA-rich oil microcapsules was high, suggesting that the entire structure of the microcapsules remained stable during thermal processing. A thermogravimetric analysis curve showed that the product lost 5 % of its weight at 172 °C and the wall material started to degrade at 236 °C. The peroxide value of microencapsulated DHA-rich oil remained at one ninth after accelerated oxidation at 45 °C for 8 weeks to that of the unencapsulated DHA-rich oil, thus revealing the promising oxidation stability of DHA-rich oil in microcapsules.

An oil demand and supply model incorporating monetary policy

International Nuclear Information System (INIS)

Askari, Hossein; Krichene, Noureddine

2010-01-01

Oil price inflation may have had a significant role in pushing the world economy into its worst post-war recession during 2008-2009. Reserve currency central banks pursued an overly expansionary monetary policy during 2001-2009, in the form of low or negative real interest rates and accompanied by a rapidly falling US dollar, while paying inadequate attention to the destabilizing effects on oil markets. In this paper, we show that monetary policy variables, namely key interest rates and the US dollar exchange rate, had a powerful effect on oil markets. World oil demand was significantly influenced by interest and dollar exchange rates, while oil supply was rigid. Oil demand and supply have very low price elasticity and this characteristic makes oil prices highly volatile and subject to wider fluctuations than the prices of other commodities. Aggressive monetary policy would stimulate oil demand, however, it would be met with rigid oil supply and would turn inflationary and disruptive to economic growth if there was little excess capacity in oil output. We argue that a measure of stability in oil markets cannot be achieved unless monetary policy is restrained and real interest rates become significantly positive. Monetary tightening during 1979-1982 might imply that monetary policy has to be restrained for a long period and with high interest rates in order to bring stability back to oil markets. (author)

Implementation of a World Wide Web server for the oil and gas industry

International Nuclear Information System (INIS)

Blaylock, R.E.; Martin, F.D.; Emery, R.

1996-01-01

The Gas and Oil Technology Exchange and Communication Highway (GO-TECH) provides an electronic information system for the petroleum community for exchanging ideas, data, and technology. The PC-based system fosters communication and discussion by linking the oil and gas producers with resource centers, government agencies, consulting firms, service companies, national laboratories, academic research groups, and universities throughout the world. The oil and gas producers can access the GO-TECH World Wide Web (WWW) home page through modem links, as well as through the Internet. Future GO-TECH applications will include the establishment of virtual corporations consisting of consortia of small companies, consultants, and service companies linked by electronic information systems. These virtual corporations will have the resources and expertise previously found only in major corporations

OPEC at middle age: facing an uncertain future in the world oil market economy

International Nuclear Information System (INIS)

1992-01-01

International institutions, like individuals, groups, and even societies and cultures, pass through various stages in their development as they grow from youth through middle age into more experienced and mature members of the international community. OPEC, the Organization of Petroleum Exporting Countries, is no exception to this generally observable phenomenon on the world economic scene. It has clearly undergone a gradual process of growth over the past three decades or so since its establishment by five founding states in Baghdad in September 1960. OPEC's history since then could be characterized as being divided into three distinct developmental stages. The first decade, the 1960s, was a period of consolidation of OPEC's power over the oil companies and their control over the member countries'oil resources. The second decade - the 1970s - was a decade characterized by almost continuous and prolonged producer - consumer confrontation as well as revelation of some of the more basic cleavages within OPEC as an organization. This was followed by the decade of the 1980s -- a period of relative accommodation between producers and consumers in the interest of longer term market stability

Potential oil yield, fatty acid composition, and oxidation stability of the hempseed oil from four Cannabis sativa L. cultivars.

Science.gov (United States)

Da Porto, Carla; Decorti, Deborah; Natolino, Andrea

2015-03-01

The cultivation of four industrial hemp cultivars (Felina 32, Chamaeleon, Uso31, and Finola) was investigated for oil production in the north-east of Italy along two years. The oils of all cultivars resulted in rich amount of linoleic acid (ω-6) and α-linolenic acid (ω-3). Felina 32 and Chamaeleon oils exhibited the highest amount of linoleic acid (59%) and α-linolenic acid (18%). Finola and Uso31 oils resulted in the richest of γ-linolenic acid (5-6%). All hempseed oils presented high oxidation stability and an acceptable initial quality. It is suggested that these oils can be used to produce EFA dietary supplements high in ω-6 and ω-3 of vegetal origin.

Antioxidant activity of rosemary essential oil fractions obtained by molecular distillation and their effect on oxidative stability of sunflower oil.

Science.gov (United States)

Mezza, Gabriela N; Borgarello, Ana V; Grosso, Nelson R; Fernandez, Héctor; Pramparo, María C; Gayol, María F

2018-03-01

The objective of this study was to evaluate the antioxidant activity of rosemary essential oil fractions obtained by molecular distillation (MD) and investigate their effect on the oxidative stability of sunflower oil. MD fractions were prepared in a series of low-pressure stages where rosemary essential oil was the first feed. Subsequently, a distillate (D1) and residue (R1) were obtained and the residue fraction from the previous stage used as the feed for the next. The residue fractions had the largest capacity to capture free radicals, and the lowest peroxide values, conjugated dienes and conjugated trienes. The antioxidant activity of the fractions was due to oxygenated monoterpenes, specifically α-terpineol and cis-sabinene hydrate. Oxidative stability results showed the residues (R1 and R4) and butylated hydroxytoluene had greater antioxidant activity than either the distillate fractions or original rosemary essential oil. The residue fractions obtained by short path MD of rosemary essential oil could be used as a natural antioxidants by the food industry. Copyright © 2017. Published by Elsevier Ltd.

A variant of the Hubbert curve for world oil production forecasts

International Nuclear Information System (INIS)

Maggio, G.; Cacciola, G.

2009-01-01

In recent years, the economic and political aspects of energy problems have prompted many researchers and analysts to focus their attention on the Hubbert Peak Theory with the aim of forecasting future trends in world oil production. In this paper, a model that attempts to contribute in this regard is presented; it is based on a variant of the well-known Hubbert curve. In addition, the sum of multiple-Hubbert curves (two cycles) is used to provide a better fit for the historical data on oil production (crude and natural gas liquid (NGL)). Taking into consideration three possible scenarios for oil reserves, this approach allowed us to forecast when peak oil production, referring to crude oil and NGL, should occur. In particular, by assuming a range of 2250-3000 gigabarrels (Gb) for ultimately recoverable conventional oil, our predictions foresee a peak between 2009 and 2021 at 29.3-32.1 Gb/year.

A comparison of two typical multicyclic models used to forecast the world's conventional oil production

International Nuclear Information System (INIS)

Wang Jianliang; Feng Lianyong; Zhao Lin; Snowden, Simon; Wang Xu

2011-01-01

This paper introduces two typical multicyclic models: the Hubbert model and the Generalized Weng model. The model-solving process of the two is expounded, and it provides the basis for an empirical analysis of the world's conventional oil production. The results for both show that the world's conventional oil (crude+NGLs) production will reach its peak in 2011 with a production of 30 billion barrels (Gb). In addition, the forecasting effects of these two models, given the same URR are compared, and the intrinsic characteristics of these two models are analyzed. This demonstrates that for specific criteria the multicyclic Generalized Weng model is an improvement on the multicyclic Hubbert model. Finally, based upon the resultant forecast for the world's conventional oil, some suggestions are proposed for China's policy makers. - Highlights: ► Hubbert model and Generalized Weng model are introduced and compared in this article. ► We conclude each model's characteristic and scopes and conditions of applicable. ► We get the same peak production and time of world's oil by applying two models. ► Multicyclic Generalized Weng model is proven slightly better than Hubbert model.

Drought and heat stress effects on soybean fatty acid composition and oil stability

Science.gov (United States)

Previous studies have shown that oil concentration and fatty acid profile (composition) change with genotype, environment (mainly heat and drought), and geographical location. The changes in fatty acid composition under these conditions affect fatty acid stability, creating a challenge to oil proces...

Decrease in oil prices: which consequences for the World economy and for France?

International Nuclear Information System (INIS)

Camatte, Hadrien; Darmet-Cucchiarini, Maxime; Gillet, Thomas; Masson, Emmanuelle; Meslin, Olivier; Padieu, Ysaline; Tavin, Alexandre

2016-04-01

Based of various statistics, this public publication first describes that, since summer 2014, oil price has been sharply decreasing (70 per cent) and keeping on decreasing due to a still abundant supply (with non conventional oil in the USA, and a still high production by OPEC countries) and a rather disappointing demand. It also outlines that production commitments stated by producers are still uncertain. This paper then notices that this oil price decrease could remain positive for World economy, but that some short term factors still impair these effects. This positive effect is indeed slow to appear in importing countries. Negative effects in exporting countries are emphasized by local economic policies. Moreover, there could be a transmission of this oil price decrease to the financial sphere, oil price decrease makes monetary policy more complex, and the USA are increasingly exposed to the energy sector activity. The third part shows that oil prices have positive effects on the French economy. They favour a wealth transfer from the rest of the world to the French economy, positively impacts companies margins and household purchase power on the short and medium terms, induces external effects as it also affects trade partners, and could result in an activity gain in the finance bill

Analysis of fatty acid methyl esters and oxidative stability of seed purpose watermelon (Citrullus lanatus) genotypes for edible oil.

Science.gov (United States)

Mahla, H R; Rathore, S S; Venkatesan, K; Sharma, R

2018-04-01

World's vegetable oil demand is increasing day by day and oil seed supply is limited to a dozen oil seed crops on commercial scale. Efforts were made to explore the potential of water melon a traditionally grown native crop of Indian arid zone having oil content over 30% and seed yield potential of 500-600 kg per hectare under rainfed conditions. An analysis was carried out to explore the suitability of watermelon [ Citrullus lanatus (Thunb.)] oil for human consumption on the basis of fatty acid (FA) composition in selected genotypes. Total oil content ranged between 10.0 and 31.0%. Eleven FA were identified in seed oil. Linoleic, stearic, palmitic and oleic acid were found as major FA while myristic, heptadecanoic, arachidic, 9-hexadecenoic and 14-eicosenoic acid was present in traces. Linoleic acid single polyunsaturated FA contributor found in the range of 43.95% (WM-44) to 55.29% (WM-18). Saturated FA content ranged between 32.24 and 37.61%. Significant genetic variation was observed for mono-unsaturated FA. Metabolic capacity to inter-conversion of FA and nutritive value of watermelon oil was described on the basis of ratio of FA group. Total phenolics, antioxidant activity, peroxide value and oxidizability were also estimated along with oxidative stability of oil. Multivariate analysis showed that, oil content has positive correlation with linoleic acid. The Euclidean based UPGMA clustering revealed that genotypes WM-18 is most suitable for trait specific breeding program for high linoleic acid ( n -6), desaturation ratio and oleic desaturation ratio with higher oil content and lowest palmitic acid.

Thermal stability evaluation of palm oil as energy transport media

International Nuclear Information System (INIS)

Wan Nik, W.B.; Ani, F.N.; Masjuki, H.H.

2005-01-01

The thermal stability of palm oil as energy transport media in a hydraulic system was studied. The oils were aged by circulating the oil in an open loop hydraulic system at an isothermal condition of 55 deg. C for 600 h. The thermal behavior and kinetic parameters of fresh and degraded palm oil, with and without oxidation inhibitor, were studied using the dynamic heating rate mode of a thermogravimetric analyser (TGA). Viscometric properties, total acid number and iodine value analyses were used to complement the TGA data. The thermodynamic parameter of activation energy of the samples was determined by direct Arrhenius plot and integral methods. The results may have important applications in the development of palm oil based hydraulic fluid. The results were compared with commercial vegetable based hydraulic fluid. The use of F10 and L135 additives was found to suppress significantly the increase of acid level and viscosity of the fluid

Oxidative stability of biodiesel blends derived from waste frying oils

Directory of Open Access Journals (Sweden)

Michael Feroldi

2017-07-01

Full Text Available The high cost of biodiesel production is mainly linked to the price of raw material.This factor has favored the use of alternative fats and oils such as those used in frying. Since biodiesel can be obtained from several vegetable and animal raw materials, the physicochemical characteristics of the fuel may vary considerably. One of these characteristics is the fatty acid composition. It directly affects the oxidative stability of biodiesel, which can be impaired when the fuel undergoes exposure to sunlight, metals, oxygen and high temperatures. In order to improve the oxidative stability of biodiesels produced from waste frying oil some studies involving blends of different raw materials have been carried out. In this sense, this work aimed to assess the characteristics resulting from the blending of soybean waste frying oil with other waste biodiesels in what concerns to oxidation. The blends of fatty materials were obtained by means of a 2² factorial design. The induction periods of biodiesel blends were enough to meet the ASTM D6751 standard. Swine fat was responsible for the increase in the induction period values.

Relevance of Linear Stability Results to Enhanced Oil Recovery

Science.gov (United States)

Ding, Xueru; Daripa, Prabir

2012-11-01

How relevant can the results based on linear stability theory for any problem for that matter be to full scale simulation results? Put it differently, is the optimal design of a system based on linear stability results is optimal or even near optimal for the complex nonlinear system with certain objectives of interest in mind? We will address these issues in the context of enhanced oil recovery by chemical flooding. This will be based on an ongoing work. Supported by Qatar National Research Fund (a member of the Qatar Foundation).

Taxing the difference: World oil market projections 1994-2009

International Nuclear Information System (INIS)

Reinsch, A.E.; Considine, J.I.; MacKay, E.J.

1994-01-01

The likely impacts of key uncertainties affecting the oil market were assessed, and reference price path to aid industry and governments in their investment and policy decisions, was provided. The reference market outlook corresponded to an annual growth of around 1.5% and a price of $ 18.00 per barrel. The greatest weakness of the market projections were found to be the expected performance of petroleum product demand growth. There was strong evidence that governments of major oil consuming countries had taken action to weaken the response of petroleum product demand to declines in the crude price, by driving an ever increasing fiscal wedge between the crude price and the corresponding product prices.The outcome is an asymmetry in demand response to crude price movements. Incorporation of this asymmetry into the world oil market model could have some disturbing results: under the reference case market assumptions, continuation of this tax and pricing policy would not only eliminate the price gains projected, but move the oil price below current levels on a sustained basis. The study concluded that OPEC members and the governments of the major industrialized oil consuming countries should strive to reach an agreement to avoid catastrophic price instability. refs., tabs., figs

Oil cartel and international financial stability

Energy Technology Data Exchange (ETDEWEB)

McKenzie, G

1976-06-01

For many years there has existed a debate among economists as to whether the problems of unemployment, inflation, and international economic adjustment are largely financial in nature or whether they are ''real''; i.e., arising from dislocations in commodity and labor markets. The correct position is that they are a bit of both. This is the viewpoint that provides the background for this paper, which examines the consequences of the recent petroleum price increases imposed by the major oil-exporting countries. On the one hand, the ''real'' implications are fairly obvious. First, petroleum products are used either directly or as fuels in virtually every commodity-production process. Higher input costs are therefore bound to lead to increased prices for most other commodities. Second, higher petroleum prices will lead (and are leading) to the use and/or search for viable substitutes. However, there have been several important financial implications as well. First, there has been a dramatic change in the pattern of domestic and international financial flows resulting from the rapid accumulation of new wealth by the oil-exporting countries. Second, there has been an important change in the nature of these flows with significant implications for the stability of domestic commodity and foreign exchange markets. This paper emphasizes the interaction of ''real'' and financial variables that has taken place as a result of the actions of the oil exporters.

Seed-specific RNAi in safflower generates a superhigh oleic oil with extended oxidative stability.

Science.gov (United States)

Wood, Craig C; Okada, Shoko; Taylor, Matthew C; Menon, Amratha; Mathew, Anu; Cullerne, Darren; Stephen, Stuart J; Allen, Robert S; Zhou, Xue-Rong; Liu, Qing; Oakeshott, John G; Singh, Surinder P; Green, Allan G

2018-03-06

Vegetable oils extracted from oilseeds are an important component of foods, but are also used in a range of high value oleochemical applications. Despite being biodegradable, nontoxic and renewable current plant oils suffer from the presence of residual polyunsaturated fatty acids that are prone to free radical formation that limit their oxidative stability, and consequently shelf life and functionality. Many decades of plant breeding have been successful in raising the oleic content to ~90%, but have come at the expense of overall field performance, including poor yields. Here, we engineer superhigh oleic (SHO) safflower producing a seed oil with 93% oleic generated from seed produced in multisite field trials spanning five generations. SHO safflower oil is the result of seed-specific hairpin-based RNA interference of two safflower lipid biosynthetic genes, FAD2.2 and FATB, producing seed oil containing less than 1.5% polyunsaturates and only 4% saturates but with no impact on lipid profiles of leaves and roots. Transgenic SHO events were compared to non-GM safflower in multisite trial plots with a wide range of growing season conditions, which showed no evidence of impact on seed yield. The oxidative stability of the field-grown SHO oil produced from various sites was 50 h at 110°C compared to 13 h for conventional ~80% oleic safflower oils. SHO safflower produces a uniquely stable vegetable oil across different field conditions that can provide the scale of production that is required for meeting the global demands for high stability oils in food and the oleochemical industry. © 2018 The Authors. Plant Biotechnology Journal published by Society for Experimental Biology and The Association of Applied Biologists and John Wiley & Sons Ltd.

Oil sands development in a carbon constrained world

Energy Technology Data Exchange (ETDEWEB)

McDougall, J. [Alberta Research Council, Devon, AB (Canada)

2006-07-01

The challenges facing oilsands development in Alberta were discussed in this PowerPoint presentation. In 2005, 71 per cent of Alberta's export value was derived from energy and mining. The author addressed the issue that resource based economies have rarely succeeded in the long term. He then demonstrated how such economies could capture value from technology. The primary focus was on the goal to develop and adapt greenhouse gas (GHG) transformational technologies that will break the link between hydrocarbon energy use and GHG emissions. The role of oil sands in this endeavour was also discussed. Alberta's oil sands are the world's largest hydrocarbon resource, with 315 b bbls proven reserves, and 2.5 t bbls potential reserves. As an important economic driver for Alberta, oil sands production is expected to grow significantly in the next 2 decades. Since bitumen production is more energy intensive than conventional oil, the industry is faced with the challenge of sustainable development. Concentrated GHG emissions create opportunities to proceed with long-term oil sands development with a sustainable level of GHG emissions, but technology and infrastructure are needed to take advantage of them. Current carbon dioxide (CO{sub 2}) storage projects in Alberta were highlighted. The economic potential of geological storage of CO{sub 2} through acid gas injection or deep disposal was discussed in terms of enhanced oil recovery, enhanced coalbed methane recovery, enhanced gas recovery and cost avoidance of CO{sub 2} per tonne. It was emphasized that a long-term vision and commitment is needed to balance with short term problems solving and longer-term strategic agendas. tabs., figs.

On the stabilizing role of species diffusion in chemical enhanced oil recovery

Science.gov (United States)

Daripa, Prabir; Gin, Craig

2015-11-01

In this talk, the speaker will discuss a problem on the stability analysis related to the effect of species diffusion on stabilization of fingering in a Hele-Shaw model of chemical enhanced oil recovery. The formulation of the problem is motivated by a specific design principle of the immiscible interfaces in the hope that this will lead to significant stabilization of interfacial instabilities, there by improving oil recovery in the context of porous media flow. Testing the merits of this hypothesis poses some challenges which will be discussed along with some numerical results based on current formulation of this problem. Several open problems in this context will be discussed. This work is currently under progress. Supported by the grant NPRP 08-777-1-141 from the Qatar National Research Fund (a member of The Qatar Foundation).

Study of Water-Oil Emulsion Breaking by Stabilized Solution Consisting of Anionic Surface Acting Agent - Soda Ash - Polymer (ASP)

Science.gov (United States)

Kulichkov, S. V.; Avtomonov, E. G.; Andreeva, L. V.; Solomennik, S. F.; Nikitina, A. V.

2018-01-01

The paper provides a laboratory research of breaking natural water-oil emulsions: - by non-stabilized ASP; by stabilized ASP; by mixture of stabilized and non-stabilized ASP in different proportions and production of refinery water of the required quality with the use of IronGuard 2495 as flocculant. Oil-in-water emulsion is stable. Classic methods are not suitable for residual water treatment: sediment gravity flow; filtration; centrifuge test. Microemulsion formed after ASP application has low boundary tension and high pH. It contributes to transfer of oil phase into a water one, forming oil-in-water emulsion. Alkaline condition has adverse effect on demulsifying ability of agents, flocculation and boundary tension. For breaking of water-oil emulsion at EBU before the interchanger water or water-oil emulsion from the wells that were not APS-treated in ratio of 1:9 shall be delivered. Residual water after EBU must be prepared in water tanks by dilution in great volume.

Transient Stability Improvement of IEEE 9 Bus System Using Power World Simulator

Directory of Open Access Journals (Sweden)

Kaur Ramandeep

2016-01-01

Full Text Available The improvement of transient stability of power system was one of the most challenging research areas in power engineer.The main aim of this paper was transient stability analysis and improvement of IEEE 9 bus system. These studies were computed using POWER WORLD SIMULATOR. The IEEE 9 bus system was modelled in power world simulator and load flow studies were performed to determine pre-fault conditions in the system using Newton-Raphson method. The transient stability analysis was carried out using Runga method during three-phase balanced fault. For the improvement transient stability, the general methods adopted were fast acting exciters, FACT devices and addition of parallel transmission line. These techniques play an important role in improving the transient stability, increasing transmission capacity and damping low frequency oscillations.

Assessing the effect of oil price on world food prices: Application of principal component analysis

International Nuclear Information System (INIS)

Esmaeili, Abdoulkarim; Shokoohi, Zainab

2011-01-01

The objective of this paper is to investigate the co-movement of food prices and the macroeconomic index, especially the oil price, by principal component analysis to further understand the influence of the macroeconomic index on food prices. We examined the food prices of seven major products: eggs, meat, milk, oilseeds, rice, sugar and wheat. The macroeconomic variables studied were crude oil prices, consumer price indexes, food production indexes and GDP around the world between 1961 and 2005. We use the Scree test and the proportion of variance method for determining the optimal number of common factors. The correlation coefficient between the extracted principal component and the macroeconomic index varies between 0.87 for the world GDP and 0.36 for the consumer price index. We find the food production index has the greatest influence on the macroeconomic index and that the oil price index has an influence on the food production index. Consequently, crude oil prices have an indirect effect on food prices. - Research Highlights: →We investigate the co-movement of food prices and the macroeconomic index. →The crude oil price has indirect effect on the world GDP via its impacts on food production index. →The food production index is the source of causation for CPI and GDP is affected by CPI. →The results confirm an indirect effect among oil price, food price principal component.

From rocks to oil : researchers become the first in the world to determine the age of oil

Energy Technology Data Exchange (ETDEWEB)

Crawshaw, C

2005-06-10

This article discussed the discovery of a method to accurately determine the age of oil. The discovery was made by two geologists at the University of Alberta, and provides critical information about the formation of oil which will help to better understand oil deposits. The scientists have suggested that the giant oil sand deposits in Alberta were formed 112 million years ago and not 60 million years ago as was previously thought. They used isotopes of rhenium and osmium, elements found in trace amounts in oil, to pinpoint when oil formed in the Western Canada Sedimentary Basin (WCSB), which contains much of the world's oil sands. It was previously thought that the time at which oil was produced from a rock and migrated as fluid could be deduced from looking at geologic relationships. This is the first time that a direct determination using any isotopic method has be applied to determine age. The research findings are expected to change the way geologists understand the evolution of the basin. It was concluded that while the discovery answers some questions about hydrocarbons, many others remain. However, the presence of an absolute number will help geologists to re-evaluate other knowledge. 1 fig.

Water-in-oil Pickering emulsions stabilized by stearoylated microcrystalline cellulose.

Science.gov (United States)

Pang, Bo; Liu, Huan; Liu, Peiwen; Peng, Xinwen; Zhang, Kai

2018-03-01

Hydrophobic particles with static water contact angles larger than 90° are more like to stabilize W/O Pickering emulsions. In particular, high internal phase Pickering emulsions (HIPEs) are of great interest for diverse applications. However, W/O HIPEs have rarely been realized using sustainable biopolymers. Herein, we used stearoylated microcrystalline cellulose (SMCC) to stabilize W/O Pickering emulsions and especially, W/O HIPEs. Moreover, these W/O HIPEs can be further used as platforms for the preparation of porous materials, such as porous foams. Stearoylated microcrystalline cellulose (SMCC) was prepared by modifying MCC with stearoyl chloride under heterogeneous conditions. Using SMCC as emulsifiers, W/O medium and high internal phase Pickering emulsions (MIPEs and HIPEs) with various organic solvents as continuous phases were prepared using one-step and two-step methods, respectively. Polystyrene (PS) foams were prepared after polymerization of oil phase using HIPEs as templates and their oil/water separation capacity were studied. SMCC could efficiently stabilize W/O Pickering emulsions and HIPEs could only be prepared via the two-step method. The internal phase volume fraction of the SMCC-stabilized HIPEs reached as high as 89%. Diverse internal phase volume fractions led to distinct inner structures of foams with closed or open cells. These macroporous polystyrene (PS) foams demonstrated great potential for the effective absorption of organic solvents from underwater. Copyright © 2017 Elsevier Inc. All rights reserved.

Analytical characterization of pure and blended watermelon (citrullus lanatus) oil: impact of blending on oxidative stability

International Nuclear Information System (INIS)

Azeem, M.W.; Nadeem, M.

2015-01-01

Analytical characterization of pure, blended watermelon (Citrulluslanatus) oil and impact of blending on oxidative stability was investigated. Watermelon oil was added with mango (Mangiferaindica L.) kernel oil at four different concentrations 5, 10, 15 and 20% (B 1, B2, B3 and B4) and referenced with a control (100% watermelon oil). All the blends were stored in transparent PET bottles at ambient temperature (25-28 degree C) for 3 months; storage stability was assessed at the interval of 1 month. Free fatty acid, unsaponifiable matter, saponification value, refractive index and iodine value of watermelon seed oil and mango kernel oil was 1.38%, 0.34%; 0.71%, 1.68%; 198, 193; 1.468, 1.457; 107.51, 54.62, respectively. The tocopherol content of watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 127.49, 205.44, 135.24, 144.52, 156.81 and 169.34 mg/kg. delta tocopherol in watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 55.26, 34.81, 53.64, 51.27, 50.14 and 48.23 mg/kg. Concentration of linoleic acid decreased from 50.78% to 30.17% when 40% mango kernel oil was added to watermelon oil. Oleic acid increased from 22.89% in watermelon oil to 25.19%, 28.84% and 30.64% in B1, B2, B3 and B4. The increase in peroxide value of watermelon oil, B1, B2, B3 and B4 was 10.07, 9.56, 7.62, 5.17 and 2.87 (meqO/sub 2//kg) in a time dependent manner. Induction period of pure watermelon oil was less than mango kernel oil and blends. These results suggest that chemical characteristics and oxidative stability of pure watermelon oil can be improved by blending with mango kernel oil. (author)

Analytical Characterization of Pure and Blended Watermelon (Citrullus lanatus oil: Impact of Blending on Oxidative Stability

Directory of Open Access Journals (Sweden)

Muhammad Waqar Azeem

2015-06-01

Full Text Available Analytical characterization of pure, blended watermelon (Citrulluslanatus oil and impact of blending on oxidative stability was investigated. Watermelon oil was added with mango (Mangiferaindica L. kernel oil at four different concentrations 5, 10, 15 and 20% (B1, B2, B3 and B4 and referenced with a control (100% watermelon oil. All the blends were stored in transparent PET bottles at ambient temperature (25-28oC for 3 months; storage stability was assessed at the interval of 1 month. Free fatty acid, unsaponifiable matter, saponification value, refractive index and iodine value of watermelon seed oil and mango kernel oil was 1.38%, 0.34%; 0.71%, 1.68%; 198, 193; 1.468, 1.457; 107.51, 54.62, respectively. The α tocopherol content of watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 127.49, 205.44, 135.24, 144.52, 156.81 and 169.34 mg/kg. δ tocopherol in watermelon oil, mango kernel oil, B1, B2, B3 and B4 was 55.26, 34.81, 53.64, 51.27, 50.14 and 48.23 mg/kg. Concentration of linoleic acid decreased from 50.78% to 30.17% when 40% mango kernel oil was added to watermelon oil. Oleic acid increased from 22.89% in watermelon oil to 25.19%, 28.84% and 30.64% in B1, B2, B3 and B4. The increase in peroxide value of watermelon oil, B1, B2, B3 and B4 was 10.07, 9.56, 7.62, 5.17 and 2.87 (meqO2/kg in a time dependent manner. Induction period of pure watermelon oil was less than mango kernel oil and blends. These results suggest that chemical characteristics and oxidative stability of pure watermelon oil can be improved by blending with mango kernel oil.

Oil and Beyond Expanding British Imperial Aspirations, Emerging Oil Capitalism, and the Challenge of Social Questions in the First World War

NARCIS (Netherlands)

Atabaki, Touraj; Ehsani, Kaveh; Bley, Helmut; Kremers, Anorthe

2014-01-01

With the onset of the First World War, the British state crafted a new strategy of shifting its industry, military and navel units from consuming coal to oil energy. This transition effectively turned Persian oil into a strategic military as well as economic resource of fundamental importance to the

The dynamic stability of OPEC's oil price mechanism

International Nuclear Information System (INIS)

Hammoudeh, S.; Madan, V.

1992-01-01

This paper examines OPEC's long-lived mechanism which targets the oil price and adjusts the quality ceiling to meet the target. The stability of this controversial mechanism is compared to that of two alternatives: one requires quantity control without any price targeting and the other is a synthesis of quantity control and the OPEC mechanisms. All three mechanisms passed the stability test and the two alternatives give rise to some interesting policy implications. Practicality considerations which involve the availability of specific information make OPEC's mechanism the most appropriate in terms of achieved targeted revenues. The paper also offers a convergence strategy that speeds up the achievement of targeted revenues under OPEC's current mechanism. (author)

Physical and oxidative stability of high fat fish oil-in-water emulsions stabilized with combinations of sodium caseinate and sodium alginate

DEFF Research Database (Denmark)

Yesiltas, Betül; García Moreno, Pedro Jesús; Sørensen, Ann-Dorit Moltke

2017-01-01

.2 ratio NaCas:NaAlg by Box-Behnken's design, the formulae 70%-1.4%-1.2 was decided due to high fish oil content's decreasing effect on droplet size and peroxide value. Practical applications: Physically and oxidatively stable high fat (50-70%) omega-3 delivery fish oil-in-water emulsions are of high......A systematic study was carried out in order to evaluate the physical and oxidative stability of high fat omega-3 delivery fish oil-in-water emulsions stabilized with combinations of sodium caseinate (NaCas) and sodium alginate (NaAlg). The influence of 3 factors related to emulsion composition...... (fish oil content: 50, 60 and 70%; total amount of NaCas and NaAlg: 1.4, 2.1 and 2.8 %; and ratio NaCas:NaAlg: 0.4, 1.2 and 2) on physical (droplet size, viscosity and zeta potential) and oxidative (primary and secondary oxidation products) parameters was evaluated. It was possible to produce emulsions...

MATHEMATICAL MODEL OF POWER CONSUMPTION FOR SOME OIL PIPE-LINE SECTIONS WITH POOR OPERATIONAL STABILITY

Directory of Open Access Journals (Sweden)

J. N. Kolesnik

2005-01-01

Full Text Available Mathematical model of power consumption for technologically completed and non-completed oil pipe-line sections with poor operational stability has been developed on the basis of daily indices concerning oil transportation regimes. The model permits to take into account tendencies in power consumption under various time prediction cycles and ranges of oil freight turnover, changes in the bulk and characteristics of the transported oil, configuration and design parameters of oil pipe-line.

A Policy study on stabilization of heating oil supply and demand

Energy Technology Data Exchange (ETDEWEB)

Lee, Bok Jae [Korea Energy Economics Institute, Euiwang (Korea)

1999-03-01

As a principal heating fuel for household and commercial sector, and a heat source fuel for industry, the heating oil shows its great demand intensively during a specific period (wintertime) due to its characteristics. It represents that the fluctuation of heating oil demand throughout the year is very extreme. Therefore, the stable supply of heating oil has been rising as an important task. It is desirable to develop and supply a new type of heating oil compounded of kerosene and gasoline with appropriate ratio for short- and mid-term to have a stable supply and demand of heating oil. For long-term prospect, it is desirable to supply petroleum products mixing gasoline and B-C oil as heating oil when it is equipped with combustion technology of boiler and distribution system. In this case, it is required to have investment on infrastructure for the supply of new heating oil (mixture of gasoline and B-C oil) and a proper preparatory period for the conversion of equipment (such as a boiler). The vitalization of storing oil is essential to stabilize the supply and demand of heating oil. In order to vitalize it, the price of heating oil should be determined by a market function reflecting the seasonal supply and demand circumstances. (author). 101 refs., 5 figs., 83 tabs.

The price of crude oil

International Nuclear Information System (INIS)

Bakhtiari, A.M.S.

1999-01-01

The price of crude oil is among the most important prices quoted daily across the world - which is not surprising, since crude oil is the most widely used source of energy worldwide, as well as being a unique commodity. When petroleum burst onto the world stage in 1859, its price first went through some initial gyrations (1860-70), before settling in the $1.00 - 2.00 per barrel range (barring a few exceptions) for a full century. Then, the price underwent two 'shocks' (1973 and 1980), followed by the 'counter-shock' of 1986. Thereafter, the price entered the relative stability of the $15 - 20 /b consensus, where it lingered until recently. Some day, there is bound to be a fresh paradigm of 'insufficient oil reserves', thus ushering in a new era for oil prices. Taking into consideration available data on reserves and expert analysis, it would seem that that day may be years rather than decades away

Soviet woes, Middle East crisis cut first half world crude oil production

International Nuclear Information System (INIS)

Beck, R.J.

1991-01-01

This paper reports that the Persian Gulf crisis and the faltering Soviet oil industry spawned a 2.8% dive in world oil production during first half 1991 compared with the same period a year ago. Total world flow averaged 59.781 million b/d, down 1.728 million b/d from first half 1990. First half Soviet production fell 1.13 million b/d from a year ago to 10.6 million b/d. Production among members of the Organization of Petroleum Exporting Countries in the first half averaged 22.927 million b/d, down 1.099 million b/d. Non-OPEC production averaged 36.854 million b/d, down from the 1990 first half average of 37.483 million b/d. OPEC's share of total world production fell to 38.4% for first half 1991 from 39.1% for first half last year. In 1979 OPEC production was 49.1% of total world production. OPEC's share dropped to 29.9% of the world total in 1985 and had been moving back up since then. OPEC set new production quotas totaling 22.31 million b/d, reflecting the curtailment of production from Kuwait and Iraq. Production in the first half of 1991 was 2.8% above quota

Stability of the spreading in small-world network with predictive controller

International Nuclear Information System (INIS)

Bao, Z.J.; Jiang, Q.Y.; Yan, W.J.; Cao, Y.J.

2010-01-01

In this Letter, we apply the predictive control strategy to suppress the propagation of diseases or viruses in small-world network. The stability of small-world spreading model with predictive controller is investigated. The sufficient and necessary stability condition is given, which is closely related to the controller parameters and small-world rewiring probability p. Our simulations discover a phenomenon that, with the fixed predictive controller parameters, the spreading dynamics become more and more stable when p decreases from a larger value to a smaller one, and the suitable controller parameters can effectively suppress the spreading behaviors even when p varies within the whole spectrum, and the unsuitable controller parameters can lead to oscillation when p lies within a certain range.

Interdependence between crude oil and world food prices: A detrended cross correlation analysis

Science.gov (United States)

Pal, Debdatta; Mitra, Subrata K.

2018-02-01

This article explores the changing interdependence between crude oil and world food prices at varying time scales using detrended cross correlation analysis that would answer whether the interdependence (if any) differed significantly between pre and post-crisis period. Unlike the previous studies that exogenously imposed break dates for dividing the time series into sub-samples, we tested whether the mean of the crude oil price changed over time to find evidence for structural changes in the crude oil price series and endogenously determine three break dates with minimum Bayesian information criterion scores. Accordingly, we divided the entire study period in four sample periods - January 1990 to October 1999, November 1999 to February 2005, March 2005 to September 2010, and October 2010 to July 2016, where the third sample period coincided with the period of food crisis and enabled us to compare the fuel-food interdependence across pre-crisis, during the crisis, and post-crisis periods. The results of the detrended cross correlation analysis extended corroborative evidence for increasing positive interdependence between the crude oil price and world food price index along with its sub-categories, namely dairy, cereals, vegetable oil, and sugar. The article ends with the implications of these results in the domain of food policy and the financial sector.

Effect of Thymus vulgaris and Bunium persicum essential oils on the oxidative stability of virgin olive oil

International Nuclear Information System (INIS)

Keramat, M.; Golmakani, M.T.

2016-01-01

Natural antioxidants are becoming a major focus because natural food ingredients are safer than synthetic types. The aim of this study was to investigate the protective effects of Thymus vulgaris and Bunium persicum essential oils (EO) on the oxidation of virgin olive oil (VOO) during accelerated storage. The antioxidant activities of EOs were compared with those of α-tocopherol and BHT. GC/MS analyses revealed that thymol (28.50%), p-cymene (27.14%), carvacrol (18.36%), and γ-terpinene (4.97%) are the main components of T. vulgaris EO, while cuminaldehyde (32.81%), γ-terpinene (16.02%) and p-cymene (14.07%) are the main components of B. persicum EO. Both EOs provided protection for the VOO, inhibiting the formation of primary and secondary oxidation products although T. vulgaris EO showed greater protection against the oxidation process than B. persicum EO. The effect of T. vulgaris essential oil on the oxidation inhibition of VOO was similar to that of BHT. α-Tocopherol showed no measurable effect on improving the oxidative stability of VOO. This study suggests that T. vulgaris and B. persicum EOs can be used to improve the oxidative stability of VOO. [es

Where in the World are Canadian Oil and Gas Companies? 2012

Directory of Open Access Journals (Sweden)

Niloo Hojjati

2017-06-01

Full Text Available Begun in 2011 as an internal research tool for the development of the Extractive Resource Governance Program, this study seeks to answer the vital question: Where in the world are Canadian oil and gas companies? To answer this question, we extract firm-level information from publicly traded Canadian companies in order to establish the location of their activities around the globe.1 The data collected in the “Where in the World” (hereafter WIW project are presented through a publicly accessible interactive world map, which allows users to explore a specific country or region over time. This map can be accessed online at http://www.policyschool.ca/research-teaching/teaching-training/extractiveresource-governance/ergp-map/. For background information regarding the WIW project, including an extensive overview of the methodology, please refer to http://www.policyschool.ca/wp-content/uploads/2017/06/Where-in-the-WorldHojjati-Horsfield-Jordison-final.pdf. For a summarized overview of the annual data gathered in 2011, please refer to http://www.policyschool.ca/wp-content/ uploads/2017/06/2011-Where-in-the-World-Hojjati-Horsfield-Jordison-final.pdf. This report, as in the earlier report in this series, presents an extensive account of the global presence of Canadian oil and gas (hereafter O&G companies in the 2012 year of study.2 In total, 228 Canadian O&G companies conducted operations in 85 countries in 2012, extending their presence to every region of the world. While North America continued to serve as the primary destination for Canadian exploration and production activities, the role of Canadian O&G service companies increased significantly in the Middle Eastern oil and gas industry, particularly in the United Arab Emirates, Saudi Arabia, Kuwait, and Oman. This report begins with a regional overview of the international activities of Canadian exploration and production (E&P companies, followed by a summary of the level of activities on a

Chemical composition and oxidative stability of jussara (Euterpe edulis M.) oil extracted by cold and hot mechanical pressing

International Nuclear Information System (INIS)

Da Cunha, A.L.A.; Freitas, S.P.; Godoy, R.L.O.; Cabral, L.M.C.; Tonon, R.V.

2017-01-01

The aim of this work was to evaluate the effect of mechanical pressing on jussara oil yield, oxidative stability and carotenoid profile with or without heat application. Firstly, jussara pulp was centrifuged for juice extraction, and the resulting cake was dried until reaching 10% moisture content. Then, oil extraction was performed in an expeller press at 25 ºC (cold pressing) and at 50 ºC (hot pressing). The process performance was evaluated by the oil yield, and the crude jussara oil was characterized for fatty acid composition, acid value, carotenoid profile and oxidative stability. Jussara oil contained 74% unsaturated fatty acids, mainly oleic and linoleic acids (48% and 24%, respectively). The oil yield was almost twice as high for the hot process as compared to the cold one. Additionally, hot pressing resulted in 25% higher total carotenoid content as compared to cold pressing, with β-carotene as the most abundant one. Hot and cold pressing showed no difference in oil oxidative stability and fatty acid composition. [es

Influence of spike lavender (Lavandula latifolia Med.) essential oil in the quality, stability and composition of soybean oil during microwave heating.

Science.gov (United States)

Rodrigues, Nuno; Malheiro, Ricardo; Casal, Susana; Asensio-S-Manzanera, M Carmen; Bento, Albino; Pereira, José Alberto

2012-08-01

Lipids oxidation is one of the main factors leading to quality losses in foods. Its prevention or delay could be obtained by the addition of antioxidants. In this sense the present work intend to monitor the protective effects of Lavandula latifolia essential oil during soybean oil microwave heating. To achieve the proposed goal quality parameters (free acidity, peroxide value, specific coefficients of extinction and ΔK), fatty acids profile, tocopherols and tocotrienols composition, antioxidant activity and oxidative stability were evaluated in soybean oil with and without spike lavender essential oils (EO) submitted to different microwave heating exposure times (1, 3, 5, 10 and 15 min; 1000 Watt) with a standard domestic microwave equipment. Microwave heating induced severe quality and composition losses, mainly above 3 min of microwave heating, regardless the sample tested. However, spike lavender EO addition counteracts the oxidation comparatively to control oils, by presenting enhanced values in quality parameters. A higher protection in unsaturated fatty acids loss was also observed as well as a higher antioxidant activity and oxidative stability. The microwave heating effects were clearly different in the samples with essential oils addition, allowing discrimination from plain soybean oils by a principal component analysis, being also capable to discriminate the different heating times tested within each sample. Copyright © 2012 Elsevier Ltd. All rights reserved.

Charting the new world order: proceedings of the 15. CERI international oil and gas markets conference

International Nuclear Information System (INIS)

1996-10-01

The 15th International Oil and Gas Markets Conference, organized by the Canadian Energy Research Institute (CERI) and held in Calgary, AB, provided a wide variety of opportunities for discussion of the global oil and gas market outlook, international oil and gas market strategies and corporate planning in the new world order, competition for investments, the re-emergence of the geopolitics of energy, energy in the Americas, international gas market strategies, and the financing of Canadian international operations. More than 100 delegates from around the world attended the conference to hear some 20 presentations. refs., tabs., figs

Formulating orange oil-in-water beverage emulsions for effective delivery of bioactives: Improvements in chemical stability, antioxidant activity and gastrointestinal fate of lycopene using carrier oils.

Science.gov (United States)

Meroni, Erika; Raikos, Vassilios

2018-04-01

The influence of carrier oil type on the chemical stability, antioxidant properties and bioaccessibility of lycopene in orange oil-in-water beverage emulsions was investigated. The emulsions were formulated with orange oil (A), which was partially (50%) replaced with tributyrin (B) or corn oil (C) because of their distinctively different fatty acid composition. The addition of corn oil enhanced the physical stability of the beverage during chilled storage by inhibiting Ostwald ripening. The formation of oxidation products was insignificant after storage for 28 days at 4 °C, regardless the type of added oil. Lycopene was more susceptible to chemical degradation in the presence of unsaturated, long chain triglycerides and the retention followed the order: A (87.94%), B (64.41%) and C (57.39%). Interestingly, bioaccessibility of lycopene was significantly lower for emulsions formulated with 50% corn oil as opposed to 100% orange oil as indicated by the simulated in vitro gastric digestion model. Copyright © 2018 Elsevier Ltd. All rights reserved.

Crude oil and stock markets. Stability, instability, and bubbles

International Nuclear Information System (INIS)

Miller, J. Isaac; Ratti, Ronald A.

2009-01-01

We analyze the long-run relationship between the world price of crude oil and international stock markets over 1971:1-2008:3 using a cointegrated vector error correction model with additional regressors. Allowing for endogenously identified breaks in the cointegrating and error correction matrices, we find evidence for breaks after 1980:5, 1988:1, and 1999:9. There is a clear long-run relationship between these series for six OECD countries for 1971:1-1980.5 and 1988:2-1999.9, suggesting that stock market indices respond negatively to increases in the oil price in the long run. During 1980.6-1988.1, we find relationships that are not statistically significantly different from either zero or from the relationships of the previous period. The expected negative long-run relationship appears to disintegrate after 1999.9. This finding supports a conjecture of change in the relationship between real oil price and real stock prices in the last decade compared to earlier years, which may suggest the presence of several stock market bubbles and/or oil price bubbles since the turn of the century. (author)

Low-shear rheology and sedimentation stability of coal-oil dispersions

Energy Technology Data Exchange (ETDEWEB)

Rutter, P. R.; Davies, J. M.; Jones, T. E.R.

1984-10-15

Stable coal-oil mixtures can be prepared by grinding coal particles in fuel oil. These products have been prepared by the British Petroleum Company plc and are referred to as Coal-Oil Dispersions (COD). One of the major problems associated with the production of DOD is the rapid assessment of the length of time the coal particles are likely to remain in suspension under a particular set of storage conditions. This paper describes a number of measurements of the low-shear rheology and sedimentation stability of a series of CODs prepared by grinding two types of coal in two different fuel oils. The results suggest that two types of COD are possible. One type exhibits complex rheological properties at low shear rates and does not produce a coal sediment, even after prolonged storage at 80/sup 0/C under dynamic conditions. The other exhibits near Newtonian behaviour and appears to form a sedimented layer of coal during storage.

An empirical exploration of the world oil price under the target zone model

International Nuclear Information System (INIS)

Linghui Tang; Shawkat Hammoudeh

2002-01-01

This paper investigates the behavior of the world oil price based on the first-generation target zone model. Using anecdotal data during the period of 1988-1999, we found that OPEC has tried to maintain a weak target zone regime for the oil price. Our econometric tests suggest that the movement of the oil price is not only manipulated by actual and substantial interventions by OPEC but also tempered by market participants' expectations of interventions. As a consequence, the non-linear model based on the target zone theory has very good forecasting ability when the oil price approaches the upper or lower limit of the band. (author)

An empirical exploration of the world oil price under the target zone model

International Nuclear Information System (INIS)

Tang, Linghui; Hammoudeh, Shawkat

2002-01-01

This paper investigates the behavior of the world oil price based on the first-generation target zone model. Using anecdotal data during the period of 1988-1999, we found that OPEC has tried to maintain a weak target zone regime for the oil price. Our econometric tests suggest that the movement of the oil price is not only manipulated by actual and substantial interventions by OPEC but also tempered by market participants' expectations of interventions. As a consequence, the non-linear model based on the target zone theory has very good forecasting ability when the oil price approaches the upper or lower limit of the band

Stability of a neural network model with small-world connections

International Nuclear Information System (INIS)

Li Chunguang; Chen Guanrong

2003-01-01

Small-world networks are highly clustered networks with small distances among the nodes. There are many biological neural networks that present this kind of connection. There are no special weightings in the connections of most existing small-world network models. However, this kind of simply connected model cannot characterize biological neural networks, in which there are different weights in synaptic connections. In this paper, we present a neural network model with weighted small-world connections and further investigate the stability of this model

Characterisation of crude oil components, asphaltene aggregation and emulsion stability by means of near infrared spectroscopy and multivariate analysis

Energy Technology Data Exchange (ETDEWEB)

Aske, Narve

2002-06-01

Effective separation of water-in-crude oil emulsions is a central challenge for the oil industry on the Norwegian Continental Shelf, especially with the future increase in subsea and even down-hole processing of well fluids. The mechanisms and properties governing emulsion stability are far from fully understood but the indigenous surface active crude oil components are believed to play a major role. In this work a thorough physico-chemical characterisation of a set of crude oils originating from a variety of production fields has been performed. Crude oil properties responsible for emulsion stability were identified by use of multivariate analysis techniques like partial least squares regression (PLS) and principal component analysis (PCA). Interfacial elasticity along with both asphaltene content and asphaltene aggregation state were found to be main contributors to emulsion stability. Information on a crude oils ability to form elastic crude oil-water interfaces was found to be especially crucial when discussing emulsion stability. However, measured values of interfacial elasticity were highly dependent on asphaltene aggregation state. Several experimental techniques was utilised and partly developed for the crude oil characterisation. A high-pressure liquid chromatography (HPLC) scheme was developed for SARA-fractionation of crude oils and an oscillating pendant drop tensiometer was used for characterisation of interfacial rheological properties. For emulsion stability a cell for determining the stability as a function of applied electric fields was used. In addition, near infrared spectroscopy (NIR) was used throughout the work both for chemical and physical characterisation of crude oils and model systems. High pressure NIR was used to study the aggregation of asphaltenes by pressure depletion. A new technique for detection of asphaltene aggregation onset pressures based on NIR combined with PCA was developed. It was also found that asphaltene aggregation is

Diagnosis of asphaltene stability in crude oil through “two parameters” SVM model

DEFF Research Database (Denmark)

Chamkalani, Ali; Mohammadi, Amir H.; Eslamimanesh, Ali

2012-01-01

Asphaltene precipitation/deposition and its imposing difficulties are drastic issues in petroleum industry. Monitoring the asphaltene stability conditions in crude oil systems is still a challenge and has been subject of many studies. In this work, the Refractive Index (RI) of several oil samples...... and previously-presented empirical correlations available in open literature. © 2012 Elsevier Ltd....

Ceramic membrane fouling during ultrafiltration of oil/water emulsions: roles played by stabilization surfactants of oil droplets.

Science.gov (United States)

Lu, Dongwei; Zhang, Tao; Ma, Jun

2015-04-07

Oil/water (O/W) emulsion stabilized by surfactants is the part of oily wastewater that is most difficult to handle. Ceramic membrane ultrafiltration presently is an ideal process to treat O/W emulsions. However, little is known about the fouling mechanism of the ceramic membrane during O/W emulsion treatment. This paper investigated how stabilization surfactants of O/W emulsions influence the irreversible fouling of ceramic membranes during ultrafiltration. An unexpected phenomenon observed was that irreversible fouling was much less when the charge of the stabilization surfactant of O/W emulsions is opposite to the membrane. The less ceramic membrane fouling in this case was proposed to be due to a synergetic steric effect and demulsification effect which prevented the penetration of oil droplets into membrane pores and led to less pore blockage. This proposed mechanism was supported by cross section images of fouled and virgin ceramic membranes taken with scanning electron microscopy, regression results of classical fouling models, and analysis of organic components rejected by the membrane. Furthermore, this mechanism was also verified by the existence of a steric effect and demulsification effect. Our finding suggests that ceramic membrane oppositely charged to the stabilization surfactant should be applied in ultrafiltration of O/W emulsions to alleviate irreversible membrane fouling. It could be a useful rule for ceramic membrane ultrafiltration of oily wastewater.

Ceramic membrane fouling during ultrafiltration of oil/water emulsions: Roles played by stabilization surfactants of oil droplets

KAUST Repository

Lu, Dongwei

2015-04-07

Oil/water (O/W) emulsion stabilized by surfactants is the part of oily wastewater that is most difficult to handle. Ceramic membrane ultrafiltration presently is an ideal process to treat O/W emulsions. However, little is known about the fouling mechanism of the ceramic membrane during O/W emulsion treatment. This paper investigated how stabilization surfactants of O/W emulsions influence the irreversible fouling of ceramic membranes during ultrafiltration. An unexpected phenomenon observed was that irreversible fouling was much less when the charge of the stabilization surfactant of O/W emulsions is opposite to the membrane. The less ceramic membrane fouling in this case was proposed to be due to a synergetic steric effect and demulsification effect which prevented the penetration of oil droplets into membrane pores and led to less pore blockage. This proposed mechanism was supported by cross section images of fouled and virgin ceramic membranes taken with scanning electron microscopy, regression results of classical fouling models, and analysis of organic components rejected by the membrane. Furthermore, this mechanism was also verified by the existence of a steric effect and demulsification effect. Our finding suggests that ceramic membrane oppositely charged to the stabilization surfactant should be applied in ultrafiltration of O/W emulsions to alleviate irreversible membrane fouling. It could be a useful rule for ceramic membrane ultrafiltration of oily wastewater. © 2015 American Chemical Society.

Formulation and stability of topical water in oil emulsion containing ...

African Journals Online (AJOL)

Purpose: To formulate the water in oil (W/O) emulsion of corn silk (CS) extract and to evaluate its stability at various storage conditions. Methods: Ethanol CS extract was prepared using maceration (cold) technique. A 4 % CS emulsion was prepared using varying concentrations of liquid paraffin, ABIL EM90 and water.

Consuming the world's energy: Update series. Energy efficiency trends in oil countries

International Nuclear Information System (INIS)

Anon.

1992-01-01

This issue of Energy Detente addresses energy efficiency in selected oil producing countries over time and compare the varying effects of important crude oil price changes. As economies around the world heighten their benefits from conservation and efficient use of energy, oil producers will be crucial examples not only for their own sakes, but for consuming countries dependent upon their exports. In this sense, their potential for leadership and vision seems greater than ever. Specifically, 6 oil-exporting countries are featured: Australia, Kuwait, Indonesia, Nigeria, the United Kingdom, and Venezuela. This issue also presents the following: (1) the ED Refining Netback Data Series for the US Gulf and West Coasts, Rotterdam, and Singapore as of February 21, 1992; and (2) the ED Fuel Price/Tax Series for countries of the Eastern Hemisphere, February, 1992 edition

Elevating bioavailability of cyclosporine a via encapsulation in artificial oil bodies stabilized by caleosin.

Science.gov (United States)

Chen, Miles C M; Wang, Jui-Ling; Tzen, Jason T C

2005-01-01

To elevate its bioavailability via oral administration, cyclosporine A (CsA), a hydrophobic drug, was either incorporated into olive oil directly or encapsulated in artificial oil bodies (AOBs) constituted with olive oil and phospholipid in the presence or absence of recombinant caleosin purified from Escherichia coli. The bioavailabilities of CsA in these formulations were assessed in Wistar rats in comparison with the commercial formulation, Sandimmun Neoral. Among these tests, CsA-loaded AOBs stabilized by the recombinant caleosin exhibited better bioavailability than the commercial formulation and possessed the highest maximum whole blood concentration (C(max)), 1247.4 +/- 106.8 ng/mL, in the experimental animals 4.3 +/- 0.7 h (t(max)) after oral administration. C(max) and the area under the plasma concentration-time curve (AUC(0-24)) were individually increased by 50.8% and 71.3% in the rats fed with caleosin-stabilized AOBs when compared with those fed with the reference Sandimmun Neoral. The results suggest that constitution of AOBs stabilized by caleosin may be a suitable technique to encapsulate hydrophobic drugs for oral administration.

Oxidative stability of rice bran, corn, canola, sunflower and soybean oils d baking process and storage of bread

Directory of Open Access Journals (Sweden)

Najmeh Jahani

2016-01-01

Full Text Available Oxidation of bread lipids during baking and storage reduces the nutritional value of the product and leads to the formation of off-flavors and off-odors. In this research, oxidative stability of rice bran, corn, canola, sunflower and soybean oils during Brotchen bread baking process and storage was evaluated. Baking process caused a significant increase in oxidative indices such as peroxide, anisidine, Totox and thiobarbitoric acid values and free fatty acid content. However, storage of breads for 6 days in room temperature did not affect the value of the indices. Generaly, the value of the indices in bread containing rice bran oil was lower than those of the other breads, which indicated the higher oxidative stability of rice bran oil in baking process and storage. Pure oils treated in simulated baking process and storage had an oxidative quality similar to that of breads. This means that bread ingridients may not have an effect on oil oxidative stability. Bread containing rice bran oil gained also higher scores in sensory evaluation, which of course were in agree with its better oxidative status.

Antioxidant capacity of cinnamon extract for palm oil stability.

Science.gov (United States)

Shahid, Muhammad Zia; Saima, Hafiza; Yasmin, Adeela; Nadeem, Muhammad Tahir; Imran, Muhammad; Afzaal, Muhammad

2018-05-16

Spices and their bioactive components are more promising attractions for their inclusion in diet-based regimes to improve human health. These are sources of natural antioxidants and play an important role in the chemoprevention of diseases and aging. The aim of the current study was to explore the antioxidant potential of cinnamon; a widely used spice throughout the world. The current research was aimed to investigate the antioxidant potential of cinnamon extract. For the purpose, cinnamon sticks were procured from local super market, while palm oil was obtained from local oil industry. The resultant extract was analyzed for its antioxidant activity through total phenolic content (TPC), free radical scavenging activity (DPPH assay), and total antioxidant activity was measured by ferric reducing antioxidant power (FRAP) test. The shelf life of palm oil was checked by adding cinnamon extract in oil at different levels i.e. , 0.05, 0.10, 0.15, 0.20 and 0.25%, to compare the antioxidant potential of the extract whereas, T o acted as control and T BHA @ 0.1% was used as synthetic antioxidant in the oil samples. The oil samples were analyzed for rancidity check during storage (after every seven days for a storage period of four weeks). The results indicated that total phenolic contents (TPC); 1,1-diphenyl-2-picrylhydrazyl (DPPH) and ferric reducing antioxidant power (FRAP) values of cinnamon extract were as 355.01 ± 8.34 gallic acid equivalent per gram (mg GAE/g), 90.18 ± 2.12 (%) and 132.82 ± 3.12 (μmol/g), respectively. The oxidative parameters for treatments i.e., T o , T BHA , T 1 , T 2 , T 3 , T 4 , T 5 were recorded as peroxide value (2.61 ± 0.07, 2.42 ± 0.08, 2.57 ± 0.05, 2.56 ± 0.03, 2.54 ± 0.02, 2.54 ± 0.01, 2.46 ± 0.06 meq/kg, respectively), free fatty acids (0.601 ± 0.05, 0.522 ± 0.02, 0.580 ± 0.07, 0.572 ± 0.03, 0.56 ± 00.07, 0.552 ± 0.03, 0.536 ± 0.05%, respectively), TBA

Volatility spillover from world oil spot markets to aggregate and electricity stock index returns in Turkey

International Nuclear Information System (INIS)

Soytas, Ugur; Oran, Adil

2011-01-01

This study examines the inter-temporal links between world oil prices, ISE 100 and ISE electricity index returns unadjusted and adjusted for market effects. The traditional approaches could not detect a causal relationship running from oil returns to any of the stock returns. However, when we examine the causality using Cheung-Ng approach we discover that world oil prices Granger cause electricity index and adjusted electricity index returns in variance, but not the aggregate market index returns. Hence, our results show that the Cheung-Ng procedure with the use of disaggregated stock index returns can uncover new information that went unnoticed with the traditional causality tests using aggregated market indices. (author)

Stability of wheat germ oil obtained by supercritical carbon dioxide ...

African Journals Online (AJOL)

심정은

For determination of stability, wheat germ oil obtained by ethanolysis reactants was characterized by ... extract non polar lipids with lipid soluble bioactive com- pounds from different sources (Esquivel et al., 1997; ... thin layer of cotton was placed at the bottom of the extraction vessel. Before plugging with cap another layer of ...

On the future role of Gulf oil in meeting world energy demand

International Nuclear Information System (INIS)

Nagy Eltony, M.

1996-01-01

The validity of the view of a growing dependence of the world on oil from the Persian Gulf, and the resulting implications for the economies of the Gulf countries were examined. The prevailing view in the countries of the Persian Gulf is that the demand for oil will continue to rise, resulting in the inevitable increase in prices which will in turn alleviate the budget deficit problems currently encountered by most of the countries of the Gulf Cooperation Council (GCC) states. The author argues that the implication of this view is that GCC countries are failing to address the fundamental structural problems within their economies, and raise questions that tend to undermine this hypothesis of continuing dependence on Gulf oil by the rest of the world. Some of these factors are growing reliance on electricity and natural gas, environmental concerns, development of alternative fuels, political instability in the Gulf states and the potential interruption in supply, all of which tend to accelerate the trend towards reduced demand for Gulf oil. The following have been recommended as ways of avoiding the ultimate risk of huge unwanted oil reserves: diversification of the economies of GCC countries; reduced spending and increased investment in developing further capacity from non-GCC sources through cooperation and joint ventures between developing countries and international companies; a more active role in worldwide decisions relating to environmental concerns; and finally, a systematic monitoring and evaluation of the likely impacts of new developments in all areas of alternative energy. 17 refs

Oxidative stability and estimate of the shelf life of sacha inchi (Plukenetia volubilis L. oil

Directory of Open Access Journals (Sweden)

Gilbert Rodríguez

2015-09-01

Full Text Available Sacha inchi oil is rich in polyunsaturated fatty acids that may rust, limiting their shel flife. The Rancimat method is official, for evaluations of oxidative stability accelerated in oils. Industrially conventional techniques based on physical and chemical indicators are used; there are no studies of correlation between them and Rancimat. This work has for objective correlate the oxidative stability index (OSI Sacha inchi oil obtained by Rancimat at temperatures of 80°, 90°, 100° and 110 °C under an air flow of 15 L/h, with the values of physic-chemical indicators such as Index peroxide, p-anisidine, totox and density. Also estimated by mathematical extrapolation, the shelf life of sacha inchi oil to usual storage temperatures. OSI values were: 0.493 ± 0.01 h at 110 ºC, 1.590 ± 0.06 h at 100 ºC, 4.645 ± 0.1 h at 90 ºC and 20.512 ± 0.02 h at 80 ºC. High correlation has been established between values of OSI vs physicochemical quality indices (0.9322 < r < 0.9965. The activation energy was found 137.90 kJ/mol, which explains the high oxidative stability for the oil, estimating a lifetime of 3.29, 1.79 and 0.79 years at 20, 25 and 30 °C respectively.

Spatial undergrowth species composition in oil palm (Elaeis guineensis Jacq.) in West Sumatra

OpenAIRE

Germer, Jörn Uwe

2003-01-01

The area planted to oil palm expanded during the last decades substantially, making it become the world's second most important oil crop. Despite its economic significance the oil palm remains remarkably unknown. Little attention is paid also to the oil palm undergrowth, though important in stabilizing the agro-ecosystem in plantations. Comprehensive knowledge of undergrowth species adapted to specific ecological niches in oil palm plantations is essential to investigate their function in ...

Olive-oil nanocapsules stabilized by HSA: influence of processing variables on particle properties

Energy Technology Data Exchange (ETDEWEB)

Molina-Bolívar, J. A., E-mail: jmb@uma.es [University of Málaga, Department of Applied Physics II, Engineering School (Spain); Galisteo-González, F. [University of Granada, Department of Applied Physics (Spain)

2015-10-15

Liquid lipid nanocapsules (LLN) are considered to be promising drug carriers in the medical field. The size and the surface charge of these nanocarriers are of major importance, affecting their bioavailability and the in vivo behaviour after intravenous injection. This research provides a comprehensive study on the preparation of olive-oil nanocapsules stabilized with a human serum albumin shell (HSA). LLN were prepared by modified solvent-displacement method. Numerous experimental variables were examined in order to characterize their impact on LLN size, distribution, and electrophoretic mobility. Physicochemical parameters of LLN were controlled by adjusting the nanodroplet stabilizing shell of adsorbed protein molecules, which was affected by the oil:HSA ratio, pH, and ionic strength of aqueous medium. The stronger the repulsion between adsorbed HSA molecules, the smaller and more monodisperse the particles proved. Other process parameters, including the ethanol:acetone ratio, organic:aqueous phase ratio, speed of organic-phase injection, and stirring rate were examined to achieve optimum preparation conditions. LLN produced by our standardized formulation were in the range of 170–175 nm with low polydispersity index (<0.1). Long-term colloidal stability of samples was evaluated after 6 months of storage. Efficient incorporation of curcumin, a model for a water-insoluble drug, into olive-oil nanocapsules was achieved (90 %). Encapsulation of curcumin into LLN had a stabilizing effect with respect to drug photodecomposition compared to that of the free molecule in solution.

Effect of pretreatment on the proximate composition, physicochemical characteristics and stability of Moringa peregrina oil

International Nuclear Information System (INIS)

Sulaiman, H.A.; Ahmad, E. E.M.; Mariod, A.A.; Mathäus, B.; Salaheldeen, M.

2017-01-01

The present research work was intended to study the influence of roasting and germination of the kernel seeds of Sudanese Moringa peregrina on the physicochemical characteristics and the oxidative stability of the extracted oil. Roasting was carried out at 180 °C for 25 minutes, whereas germination was done at ambient conditions in a wet jute bag for 5–7 days. The oil was extracted using n-hexane in a Soxhlet extraction apparatus. The results show that the oil contains α-tocopherols (152mg/kg) and oleic acid (above 70%) as the major tocols and fatty acids, respectively. Germination reduced the peroxide value and increased the acid value in a significant way (p < 0.05) whereas the opposite trend was noticed in the case of roasting. It is crucial to note that, with the exception of the acid value of the germinated sample, peroxide and acid values remained below one meq O2/Kg of oil and one mg KOH/g of oil, respectively. The oxidative stability of the oil from the roasted sample was increased almost by 80% compared to the raw one. Roasting of the kernels prior to oil extraction is imperative for improving its oxidation resistance and the physicochemical characteristics. [es

Effect of pretreatment on the proximate composition, physicochemical characteristics and stability of Moringa peregrina oil

Directory of Open Access Journals (Sweden)

H. A. Sulaiman

2018-01-01

Full Text Available The present research work was intended to study the influence of roasting and germination of the kernel seeds of Sudanese Moringa peregrina on the physicochemical characteristics and the oxidative stability of the extracted oil. Roasting was carried out at 180 ˚C for 25 minutes, whereas germination was done at ambient conditions in a wet jute bag for 5–7 days. The oil was extracted using n-hexane in a Soxhlet extraction apparatus. The results show that the oil contains α-tocopherols (152mg/kg and oleic acid (above 70% as the major tocols and fatty acids, respectively. Germination reduced the peroxide value and increased the acid value in a significant way (p < 0.05 whereas the opposite trend was noticed in the case of roasting. It is crucial to note that, with the exception of the acid value of the germinated sample, peroxide and acid values remained below one meq O2/Kg of oil and one mg KOH/g of oil, respectively. The oxidative stability of the oil from the roasted sample was increased almost by 80% compared to the raw one. Roasting of the kernels prior to oil extraction is imperative for improving its oxidation resistance and the physicochemical characteristics.

Distribution and quantitative assessment of world crude oil reserves and resources

Science.gov (United States)

Masters, Charles D.; Root, David H.; Dietzman, William D.

1983-01-01

World Demonstrated Reserves of crude oil are approximately 723 billion barrels of oil (BBO). Cumulative production is 445 BBO and annual production is 20 BBO. Demonstrated Reserves of crude-oil have declined over the past 10 years consistent with discoveries lagging production over the same period. The assessment of Undiscovered Resources shows a 90 percent probability that the amount discoverable lies between 321 and 1,417 BBO, 550 BBO being the most likely value. The most likely value for Ultimate recoverable resources is 1,718 BBO. The distribution of Ultimate Resources of crude oil will remain highly skewed toward the Middle East; no frontier areas that have potentials large enough to significantly affect present distribution are recognized. Rates of discovery have continued to decline over the past 20 years even though exploration activity has increased in recent years. Prudence dictates, therefore, that the low side of the assessment of Undiscovered Resources be responsibly considered and that alternate energy sources be a part of future planning. Extra-heavy oil and bitumen are assessed separately, with Reserves being figured as the annual productive capacity of installed facilities times 25 years. The annual production of extra-heavy oil is about 8 million barrels and of bitumen about 60 million barrels.

Oxidative stability of structured lipids produced from sunflower oil and caprylic acid

DEFF Research Database (Denmark)

Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

2003-01-01

Traditional sunflower oil (SO), randomized lipid (RL) and specific structured lipid (SL), both produced from SO and tricaprylin/caprylic acid, respectively, were stored for up to 12 wk to compare their oxidative stabilities by chemical and sensory analyses. Furthermore, the effect of adding...... a commercial antioxidant blend Grindox 117 (propyl gallate/citric acid/ascorbyl palmitate) or gallic acid to the SL was investigated. The lipid type affected the oxidative stability: SL was less stable than SO and RL. The reduced stability was most likely caused by both the structure of the lipid...

The world oil market is not one great pool: A reply to Rodriguez and Williams

International Nuclear Information System (INIS)

Weiner, R.J.

1993-01-01

In a paper by Rodriguez and Williams (Energy Studies Review, 1993), the case for a single-pool world oil market is put forward. Criticisms of the assumptions and conclusions are offered. To counter the paper's assumption that antitrust is the relevant metric for measuring the extent of geographic markets, it is argued that for energy security policy decisions, it is the economic market which matters. The paper does show that the world oil market is indeed unified in the long run, but this is not relevant to the short term, the relevant time-frame for energy security decisions. The paper's choice of spot market data for its cointegration analysis is also criticized by using several examples of pricing decisions that would not make sense in a unified world market but which do make sense in a regionalized market. It is also unclear how representative spot prices are of the oil market. Finally, the conclusions of the paper that favor policies focusing on secure vs insecure import sources and supplier diversification are seen as unsupported by the paper's statistical findings. 15 refs

Improving oxidative stability of olive oil: Incorporation of Spirulina and evaluation of its synergism with citric acid

International Nuclear Information System (INIS)

Alavi, N.; Golmakani, M.T.

2017-01-01

The effects of different Spirulina concentrations used alone and in combination with citric acid on the oxidative stability of olive oil were assessed. The amounts of primary and secondary oxidation products produced in Spirulina samples were lower than that of the control. The improved oxidative stability indices of Spirulina samples with and without citric acid were in the range of 85.20–94.47% and 258.10–260.21%, respectively. In comparison with the control, Spirulina samples manifested significantly higher carotenoid and chlorophyll contents at the beginning and end of the storage period. The presence of these bioactive compounds results from the presence of Spirulina in the medium and can thus retard the oxidation of olive oil. A higher oxidative stability was reached using BHT in comparison with Spirulina samples. Furthermore, no synergistic action was observed in possible connections between citric acid and Spirulina. In conclusion, Spirulina can enhance oxidative stability and improve the shelf life of olive oil. [es

Effects of thermal processing on physicochemical properties and oxidative stability of Balanities aegyptiaca kernels and extracted oil

International Nuclear Information System (INIS)

Elbadawi, S.M.A.; Ahmad, E.E.M.; Mariod, A.A.; Mathäus, B.

2017-01-01

In the present study, the effects of roasting and boiling on the proximate composition of the kernels as well as the physicochemical properties and oxidative stabilities of the extracted oils of Balanites aegyptiaca were investigated. Roasting was performed at 180 °C for 15 minutes, whereas boiling of the kernels was carried out in tap water for one hour. The oils from raw and thermally processed samples were extracted using n-hexane in a Soxhlet extraction apparatus and characterized. The roasting significantly (p < 0.05) influenced the peroxide value and the oxidative stability of the extracted oil in a positive way; whereas boiling had the opposite effect. The oils were composed of linoleic, oleic, stearic, and palmitic acids as the major fatty acids (96%) and contained predominantly α- and γ-tocopherols (ca. 400mg/kg). The study suggests that the oil from roasted kernels could be used as a natural antioxidant for enhancing the characteristics of other edible oils via blending. [es

Spray dried microparticles of chia oil using emulsion stabilized by whey protein concentrate and pectin by electrostatic deposition.

Science.gov (United States)

Noello, C; Carvalho, A G S; Silva, V M; Hubinger, M D

2016-11-01

Chia seed oil has a high content of α-linolenic acid (60%) and linoleic acid (20%). Use of this oil in different products is limited due to its liquid state, and the presence of insaturation is a trigger for oxidation. In this context, to facilitate the incorporation of chia oil in food products and increase its protection against oxidation, the aim of this work was to produce chia oil microparticles by spray drying using emulsions stabilized by whey protein concentrate (ζ-potential +13.4 at pH3.8) and pectin (ζ-potential -40.4 at pH3.8) through the electrostatic layer-by-layer deposition technique and emulsions prepared with only whey protein concentrate. Emulsions stabilized by whey protein concentrate and stabilized by whey protein concentrate-pectin were prepared using maltodextrin (10 DE) and modified starch (Hi-Cap® 100). They were characterized in relation to stability, droplet size, ζ-Potential and optical microscopy. The microparticles were characterized in relation to moisture content, water activity, particle size, microstructure and oxidative stability by the Rancimat method. Emulsions stabilized by whey protein concentrate-pectin with added maltodextrin 10 DE and emulsions stabilized by whey protein concentrate with added modified starch (Hi-Cap® 100) were stable after 24h. Emulsions stabilized by whey protein concentrate and by whey protein concentrate-pectin showed droplets with mean diameter ranging from 0.80 to 1.31μm, respectively and ζ-potential varying from -6.9 to -27.43mV, respectively. After spray drying, the microparticles showed an mean diameter ranging from 7.00 to 9.00μm. All samples presented high encapsulation efficiency values, above 99%. Microparticles produced with modified starch showed a smoother spherical surface than particles with maltodextrin 10 DE, which presented a wrinkled surface. All microparticles exhibited higher oxidative stability than chia oil in pure form. Copyright © 2016 Elsevier Ltd. All rights reserved.

Liquid Crystal Formation from Sunflower Oil: Long Term Stability Studies.

Science.gov (United States)

da Rocha-Filho, Pedro Alves; Maruno, Mônica; Ferrari, Márcio; Topan, José Fernando

2016-06-09

The Brazilian biodiversity offers a multiplicity of raw materials with great potential in cosmetics industry applications. Some vegetable oils and fatty esters increase skin hydration by occlusivity, keeping the skin hydrated and with a shiny appearance. Sunflower (Helianthus annus L.) oil is widely employed in cosmetic emulsions in the form of soaps, creams, moisturizers and skin cleansers due to the presence of polyphenols and its high vitamin E content. Liquid crystals are systems with many applications in both pharmaceutical and cosmetic formulations and are easily detected by microscopy under polarized light due to their birefringence properties. The aim of this research was to develop emulsions from natural sunflower oil for topical uses. Sunflower oil (75.0% w/w) was combined with liquid vaseline (25.0% w/w) employing a natural self-emulsifying base (SEB) derivative. The high temperature of the emulsification process did not influence the antioxidant properties of sunflower oil. Fatty esters were added to cosmetic formulations and extended stability tests were performed to characterize the emulsions. Fatty esters like cetyl palmitate and cetyl ester increase the formation of anisotropic structures. O/W emulsions showed acidic pH values and pseudoplastic behavior. The presence of a lamellar phase was observed after a period of 90 days under different storage conditions.

In-situ stabilization of the Geiger (C and M Oil) Superfund Site

International Nuclear Information System (INIS)

Andromalos, K.B.; Ameel, M.E.

1994-01-01

The Geiger (C and M Oil) Superfund Site is the first US Army Corps of Engineers managed soil remediation project which utilized the in-situ stabilization/solidification technique to remediate the soil. This project involved the remediation of approximately 23,000 cubic yards of contaminated soil. Contaminants of concern included chromium, lead, PCB'S, toluene, benzene, and other organic compounds. Clean-up criteria for the stabilized material was equal to the National Primary Drinking Water Regulations, when tested using the TCLP leachate extraction method. Chromium, lead, and toluene were the main contaminants of concern, with TCLP clean-up goals of 150, 15 and 1,000 parts per billion (ppb), respectively. This National Priorities List (NPL) site is located near Charleston, SC and was an abandoned old waste oil facility that utilized unlined shallow trenches for the storage of waste oil. This paper summarizes the initial testing programs and the final production work at the site. Extensive testing was performed throughout all phases of the project. This testing was performed for the purpose of mix optimization, quality assurance, and verification testing. Specific parameters tested included: TCLP testing of organics, metals and PCBs, permeability testing, and unconfirmed compression strength

Comparison of the effects of semi-refined rice oil and soybean oil on meat oxidative stability, carcass yield, metabolism, and performance of broilers

Directory of Open Access Journals (Sweden)

ML de Moraes

2009-09-01

Full Text Available Two experiments (EXP 1 and EXP 2 were conducted to compare soybean oil (SO and semi-refined rice oil (RBO added to broilers diets. In EXP 1, 400 male Ross x Ross 308 broilers were reared in battery cages, and their performance was evaluated. A metabolism assay was performed. In EXP 2, 1344 broilers from the same strain were reared in floor pens with rice husks litter. In addition to performance, carcass yield and meat oxidative stability were evaluated. In both EXP, birds were distributed in a 2x4 factorial arrangement, with two types of oils (SO or RBO and four oil inclusion levels (1%, 2.5%, 4%, or 5.5%. Two periods were considered: starter (1 to 21 days of age and grower (22 to 42 days. In both EXP, oil type had no influence on starter performance. Although treatments promoted similar in weight gain (WG and feed intake (FI, grower birds fed RBO had better feed conversion (FCR in EXP 2, but not in EXP1. In both trials, increasing dietary oil levels negatively influenced FI and positively FCR. Weight gain was similar among all treatments in EXP 1, whereas in EXP 2, WG was higher when 4 and 5.5% oil was included in the feed. RBO presented 94% fat metabolizability, and crude energy and metabolizable energy levels of 9.260 and 8.714 kcal/kg, respectively. Carcass yield was not influenced by oil type; however, oil inclusion level negatively affected breast yield. The experimental treatments had no effect on meat oxidative stability. RBO can be used as an alternative to soybean oil in broilers diets.

Influence of Surfactant Structure on the Stability of Water-in-Oil Emulsions under High-Temperature High-Salinity Conditions

Directory of Open Access Journals (Sweden)

Abdelhalim I. A. Mohamed

2017-01-01

Full Text Available Emulsified water-in-oil (W/O systems are extensively used in the oil industry for water control and acid stimulation. Emulsifiers are commonly utilized to emulsify a water-soluble material to form W/O emulsion. The selection of a particular surfactant for such jobs is critical and certainly expensive. In this work, the impact of surfactant structure on the stability of W/O emulsions is investigated using the hydrophilic-lipophilic balance (HLB of the surfactant. Different commercial surfactants were evaluated for use as emulsifiers for W/O systems at high-temperature (up to 120°C high-salinity (221,673 ppm HTHS conditions. Diverse surfactants were examined including ethoxylates, polyethylene glycols, fluorinated surfactants, and amides. Both commercial Diesel and waste oil are used for the oleic phase to prepare the emulsified system. Waste oil has shown higher stability (less separation in comparison with Diesel. This work has successfully identified stable emulsified W/O systems that can tolerate HTHS environments using HLB approach. Amine Acetate family shows higher stability in comparison with Glycol Ether family and at even lower concentration. New insights into structure-surfactant stability relationship, beyond the HLB approach, are provided for surfactant selection.

International oil market: instability and restructuring

Energy Technology Data Exchange (ETDEWEB)

Ayoub, A

1988-12-01

The three phenomena which today dominate the international oil market are: 1. the downward price trend since 1981 and the uncertainty about medium and long term price evolution; 2. chronic price instability in the short term; 3. the trend toward new forms of vertical integration and concentration which are now stabilizing a market confronted by a weakening OPEC and free markets which are volatile. The new market restructuring the present period for the international oil sector as a transition period, with the following characteristics: 1. an evident convergence in the motivations of the major oil companies and of a number of OPEC countries, to see a certain stability restored in the oil market based on vertical integration and concentration; 2. markets cannot be stabilized by political agreements between the states, but only by reciprocal financial implications and participations between companies according to the rules of the business world; 3. the market as a whole will still continue for a certain time to be governed by the OPEC-free market pair, with alternating domination by one or the other according to the economic situation. Nevertheless, the longer the market continues to be unstable, the more the trend toward concentration and integration will intensify.

Effect of Thymus vulgaris L. Essential Oil on Oxidative Stability of Virgin Olive Oil and Its Synergy with Citric Acid

Directory of Open Access Journals (Sweden)

Malihe Keramat

2017-09-01

Full Text Available Background: Since usage of synthetic antioxidants has been under question due to their toxicity and possible carcinogenicity, there is still interest in developing plant-derived natural antioxidants, especially from edible plants. This study investigated the effect of Thymus vulgaris L. essential oil on virgin olive oil oxidation in comparison with tocopheryl acetate and butylated hydroxytoluene (BHT. Furthermore, the synergistic activities of citric acid with natural and synthetic antioxidants were determined. Methods: T. vulgaris essential oil was added to the virgin olive oil at a concentration of 1000 ppm. The BHT and tocopheryl acetate were added to the virgin olive oil at 100 ppm concentration. Virgin olive oil samples were stored at 60°C for 16 days. The peroxide value, p-anisidine value, K232, and K268 values were measured every 4 days. Changes in chlorophyll and carotenoid contents of virgin olive oil samples were determined at the beginning and end of storage period. Results: T. vulgaris essential oil significantly reduced the peroxide value, p-anisidine value, K232, and K268 values of virgin olive oil. The effect of T.vulgaris essential oil on retarding virgin olive oil oxidation was similar to the effect of BHT. By comparison, tocopheryl acetate was less effective in reducing the oxidation of virgin olive oil. Furthermore, T. vulgaris essential oil could preserve chlorophyll and carotenoid of virgin olive oil during storage period. Conclusion: T. vulgaris essential oil can be applied to increase the oxidative stability of virgin olive oil, and can protect the chlorophyll and carotenoid of virgin olive oil.

Oil palm genome sequence reveals divergence of interfertile species in old and new worlds

Science.gov (United States)

Singh, Rajinder; Ong-Abdullah, Meilina; Low, Eng-Ti Leslie; Manaf, Mohamad Arif Abdul; Rosli, Rozana; Nookiah, Rajanaidu; Ooi, Leslie Cheng-Li; Ooi, Siew–Eng; Chan, Kuang-Lim; Halim, Mohd Amin; Azizi, Norazah; Nagappan, Jayanthi; Bacher, Blaire; Lakey, Nathan; Smith, Steven W; He, Dong; Hogan, Michael; Budiman, Muhammad A; Lee, Ernest K; DeSalle, Rob; Kudrna, David; Goicoechea, Jose Louis; Wing, Rod; Wilson, Richard K; Fulton, Robert S; Ordway, Jared M; Martienssen, Robert A; Sambanthamurthi, Ravigadevi

2013-01-01

Oil palm is the most productive oil-bearing crop. Planted on only 5% of the total vegetable oil acreage, palm oil accounts for 33% of vegetable oil, and 45% of edible oil worldwide, but increased cultivation competes with dwindling rainforest reserves. We report the 1.8 gigabase (Gb) genome sequence of the African oil palm Elaeis guineensis, the predominant source of worldwide oil production. 1.535 Gb of assembled sequence and transcriptome data from 30 tissue types were used to predict at least 34,802 genes, including oil biosynthesis genes and homologues of WRINKLED1 (WRI1), and other transcriptional regulators1, which are highly expressed in the kernel. We also report the draft sequence of the S. American oil palm Elaeis oleifera, which has the same number of chromosomes (2n=32) and produces fertile interspecific hybrids with E. guineensis2, but appears to have diverged in the new world. Segmental duplications of chromosome arms define the palaeotetraploid origin of palm trees. The oil palm sequence enables the discovery of genes for important traits as well as somaclonal epigenetic alterations which restrict the use of clones in commercial plantings3, and thus helps achieve sustainability for biofuels and edible oils, reducing the rainforest footprint of this tropical plantation crop. PMID:23883927

Physicochemical properties and oxidative stability of bleached pomace-olive oil on Tunisian activated clays

International Nuclear Information System (INIS)

Jahouach, Wafa

2002-01-01

This work is a contribution to studying bleaching process, which is an important stage in refining of vegetable oils. This process permitted to reduce or convert undesired constituents to harmless ones from oils and fats. Virgin olive oil, considered as reference, and pomace-olive oil were bleached in optimal conditions using Tunisian activated clays ( collected from the South of Tunisia) which were prepared in our laboratory and compared with commercial bleaching earths. It was shown that activated Tunisian clays are characterized by a very important adsorptive capacity, which is similar to that of commercial ones. In addition, the study of physicochemical properties of bleached oils was considered. The fatty acid composition (GC), the triacylglycerol composition (HPLC), and oxidative stability (UV spectrometry) allowed to conclude that treated oils do not undergo considerable physicochemical alterations and their caracteristics remain in concordance with international standards relative to edible refined oils. (Author)

Influence of degradation rate of oil on its radiation stability

International Nuclear Information System (INIS)

Hajiyeva, S.R.; Samadova, A.A.; Mustafayev, I.I; Guliyeva, N.K.; Melikova, S.Z.

2015-01-01

Regularities of radiation-chemical transformations of heavy fractions of Surakhani oil fields of Azerbaijan taken from the surface of the basin were studied. Studies were conducted at the range of absorbed doses of γ-radiation 3,8 - 109,5 kGy at dose rate of P=0,21 Gy/s. It was established radiation-chemical yields of gases obtained within the radiolysis of oil fractions and determined structural-group composition of the components. The research results will allow evaluating the possibility of applying radiation-chemical technology in purification of water from degraded oil products.In terms of negative impact on the environment, the oil industry is in one of the first places among the leading sectors of the economy. The problem of water pollution with oil and oil products are becoming more urgent each year. The last accidents (in the Gulf of Mexico, on Amur, in Azerbaijan) clearly show the need for application of new methods of water purification from oil /1/. Oil and oil products fall into the body of water in different ways: with storm water, within pipeline accidents, dumping of industrial sewage, etc. According to experts, each year about 10 million tons of oil and oil products get in the world ocean /2/. Only Azerbaijan dumps more than 500 mln m3 of normative-treated water in the Caspian Sea every year, as a result of which the sea gets more than 3 thousand tons of oil products, 25 tons of phenols, 28 thousand tons of suspended materials, 520 thousand tons of synthetic surfactant /3/. Within the ingress of oil on the surface of water objects the greatest danger is its spread to large areas, leading to disruption of ecological balance in the environment. Oil consisting of mainly hydrocarbon molecules, insoluble in water, spreads on the surface of the water during a disaster. Under the action of waves and current, the oil patch divided into many parts. Volatile fractions evaporate in the first hours of the accident; further processes occurring within the

Viscosity of the oil-in-water Pickering emulsion stabilized by surfactant-polymer and nanoparticle-surfactant-polymer system

Science.gov (United States)

Sharma, Tushar; Kumar, G. Suresh; Chon, Bo Hyun; Sangwai, Jitendra S.

2014-11-01

Information on the viscosity of Pickering emulsion is required for their successful application in upstream oil and gas industry to understand their stability at extreme environment. In this work, a novel formulation of oil-in-water (o/w) Pickering emulsion stabilized using nanoparticle-surfactant-polymer (polyacrylamide) system as formulated in our earlier work (Sharma et al., Journal of Industrial and Engineering Chemistry, 2014) is investigated for rheological stability at high pressure and high temperature (HPHT) conditions using a controlled-strain rheometer. The nanoparticle (SiO2 and clay) concentration is varied from 1.0 to 5.0 wt%. The results are compared with the rheological behavior of simple o/w emulsion stabilized by surfactant-polymer system. Both the emulsions exhibit non-Newtonian shear thinning behavior. A positive shift in this behavior is observed for surfactant-polymer stabilized emulsion at high pressure conditions. Yield stress is observed to increase with pressure for surfactant-polymer emulsion. In addition, increase in temperature has an adverse effect on the viscosity of emulsion stabilized by surfactant-polymer system. In case of nanoparticle-surfactant-polymer stabilized o/w emulsion system, the viscosity and yield stress are predominantly constant for varying pressure and temperature conditions. The viscosity data for both o/w emulsion systems are fitted by the Herschel-Bulkley model and found to be satisfactory. In general, the study indicates that the Pickering emulsion stabilized by nanoparticle-surfactant-polymer system shows improved and stable rheological properties as compared to conventional emulsion stabilized by surfactant-polymer system indicating their successful application for HPHT environment in upstream oil and gas industry.

COMPARISON OF PHYSICAL STABILITY PROPERTIES OF POMEGRANATE SEED OIL NANOEMULSION DOSAGE FORMS WITH LONG-CHAIN TRIGLYCERIDE AND MEDIUM-CHAIN TRIGLYCERIDE AS THE OIL PHASE

Directory of Open Access Journals (Sweden)

Sri Hartanti Yuliani

2016-08-01

Full Text Available Pomegranate seed oil has antioxidant, anti-inflammatory, and chemo preventive activities. Pomegranate seed oil is lipophilic substance suitable to be prepared in emulsion dosage forms. Long-chain triglyceride (LCT and medium-chain triglyceride (MCT are commonly used as oil phase in emulsion dosage forms. This research aimed to compare the use of LCT and MCT in the Nano emulsion formula of pomegranate seed oil dosage forms. Formulation of pomegranate seed oil Nano emulsion was conducted using high energy emulsification. Parameters observed were pH, Nano emulsion type, percent transmittance, viscosity, turbidity, and droplet size before and after 3 cycles of freeze-thaw. The result showed that there was no significant difference between physical properties of pomegranate oil Nano emulsion with LCT as oil phase and pomegranate oil Nano emulsion with MCT as oil phase. Moreover, physical stability of pomegranate oil Nano emulsion with LCT as oil phase was better than pomegranate oil Nano emulsion with MCT as oil phase.

Storage stability of screwpress-extracted oils and residual meals from CELSS candidate oilseed crops

Science.gov (United States)

Stephens, S. D.; Watkins, B. A.; Nielsen, S. S.

1997-01-01

The efficacy of using screwpress extraction for oil was studied with three Controlled Ecological Life-Support System (CELSS) candidate oilseed crops (soybean, peanut, and canola), since use of volatile organic solvents for oil extraction likely would be impractical in a closed system. Low oil yields from initial work indicated that a modification of the process is necessary to increase extraction efficiency. The extracted oil from each crop was tested for stability and sensory characteristics. When stored at 23 degC, canola oil and meal were least stable to oxidative rancidity, whereas peanut oil and meal were least stable to hydrolytic rancidity. When stored at 65 degC, soybean oil and canola meal were least stable to oxidative rancidity, whereas peanut oil and meal were least stable to hydrolytic rancidity. Sensory evaluation of the extracted oils used in bread and salad dressing indicated that flavor, odor intensity, acceptability, and overall preference may be of concern for screwpress-extracted canola oil when it is used in an unrefined form. Overall results with screwpress-extracted crude oils indicated that soybean oil may be more stable and acceptable than canola or peanut under typical storage conditions.

Oxidative stability of mayonnaise containing structured lipids produced from sunflower oil and caprylic acid

DEFF Research Database (Denmark)

Jacobsen, Charlotte; Xu, Xuebing; Nielsen, Nina Skall

2003-01-01

Mayonnaise based on enzymatically produced specific structured lipid (SL) from sunflower oil and caprylic acid was compared with mayonnaise based on traditional sunflower oil (SO) or chemically randomized lipid (RL) with respect to their oxidative stability, sensory and rheological properties......, but was most likely influenced by the structure of the lipid, the lower tocopherol content and the higher initial levels of lipid hydroperoxides and secondary volatile oxidation compounds in the SL itself compared with the RL and traditional sunflower oil employed. EDTA was a strong antioxidant, while propyl...

Are high oil prices a threat for the price stability?

International Nuclear Information System (INIS)

Mollerus, A.

2000-01-01

The high price for oil and the decreased value of the Euro increase the risks for the stability of prices. Still, the prospects for inflation are favorable for the Euro zone. Less favorable are the consequences for the Netherlands, while the inflation difference with the Euro zone appears to become bigger, in particular as a result of the new Tax regulations in the Netherlands

Dynamics of world oil crops market

Directory of Open Access Journals (Sweden)

Knežević Marija

2012-01-01

Full Text Available According to the harvested area, oil crops are the second most important crops after cereals. Soybean is the most important oil crop in terms of production and trade of oilseeds and meals, and second most important in terms of production and trade of vegetable oils after palm oil. Dynamics of prices of derived oil crop products in the international market is conditioned by the relationship between supply and demand in the overall market of oil crops. The substitution of animal fats with vegetable oils in human nutrition, the expansion of biodiesel industry and intensification of livestock production have led to increased demand for oil crops. The objective of this paper was to identify trends in production, consumption and trade of soybeans, rapeseed and sunflower and their derived products.

Synergetic Use of Principal Component Analysis Applied to Normed Physicochemical Measurements and GC × GC-MS to Reveal the Stabilization Effect of Selected Essential Oils on Heated Rapeseed Oil.

Science.gov (United States)

Sghaier, Lilia; Cordella, Christophe B Y; Rutledge, Douglas N; Lefèvre, Fanny; Watiez, Mickaël; Breton, Sylvie; Sassiat, Patrick; Thiebaut, Didier; Vial, Jérôme

2017-06-01

Lipid oxidation leads to the formation of volatile compounds and very often to off-flavors. In the case of the heating of rapeseed oil, unpleasant odors, characterized as a fishy odor, are emitted. In this study, 2 different essential oils (coriander and nutmeg essential oils) were added to refined rapeseed oil as odor masking agents. The aim of this work was to determine a potential antioxidant effect of these essential oils on the thermal stability of rapeseed oil subject to heating cycles between room temperature and 180 °C. For this purpose, normed determinations of different parameters (peroxide value, anisidine value, and the content of total polar compounds, free fatty acids and tocopherols) were carried out to examine the differences between pure and degraded oil. No significant difference was observed between pure rapeseed oil and rapeseed oil with essential oils for each parameter separately. However, a stabilizing effect of the essential oils, with a higher effect for the nutmeg essential oil was highlighted by principal component analysis applied on physicochemical dataset. Moreover, the analysis of the volatile compounds performed by GC × GC showed a substantial loss of the volatile compounds of the essential oils from the first heating cycle. © 2017 Institute of Food Technologists®.

Impact of the Sea Empress oil spill on lysosomal stability in mussel blood cells.

Science.gov (United States)

Fernley, P W; Moore, M N; Lowe, D M; Donkin, P; Evans, S

2000-01-01

Coastal zones are among the most productive and vulnerable areas on the planet. An example of impact on these fragile environments was shown in the case of the "Sea Empress" oil tanker, which ran aground in the Bristol Channel in 1996, spilling 72,000 tons of "Forties" crude oil. The objective was to investigate the sub-lethal cellular pathology and tissue hydrocarbon contamination in marine mussel populations, 4 months after the initial spill, using the neutral red retention (NRR) assay for lysosomal stability in blood cells. NRR was reduced in mussels, and indicative of cell injury, from the two sites closest to the spill in comparison with more distant and reference sites. Lysosomal stability was inversely correlated with polycyclic aromatic hydrocarbon concentrations in mussel tissues. Reduced lysosomal stability has previously been shown to contribute to impaired immunocompetence and to autophagic loss of body tissues. The use of this type of technique is discussed in the context of cost-effective, ecotoxicological tools for Integrated Coastal Zone Management.

Impact of the Sea Empress oil spill on lysosomal stability in mussel blood cells

International Nuclear Information System (INIS)

Fernley, P.W.; Lowe, D.M.; Donkin, P.; Evans, S.

2000-01-01

Coastal zones are among the most productive and vulnerable areas on the planet. An example of impact on these fragile environments was shown in the case of the Sea Empress oil tanker, which ran aground in the Bristol Channel in 1996, spilling 72,000 tonnes of Forties crude oil. The objective was to investigate the sub-lethal cellular pathology and tissue hydrocarbon contamination in marine mussel populations, 4 months after the initial spill, using the neutral red retention (NRR) assay for lysosomal stability in blood cells. NRR was reduced in mussels, and indicative of cell injury, from the two sites closest to the spill in comparison with more distant and reference sites. Lysosomal stability was inversely correlated with polycyclic aromatic hydrocarbon concentrations in mussel tissues. Reduced lysosomal stability has previously been shown to contribute to impaired immunocompetence and to autophagic loss of body tissues. The use of this type of technique is discussed in the context of cost-effective, ecotoxicological tools for Integrated Coastal Zone Management. (Author)

Impact of the Sea Empress oil spill on lysosomal stability in mussel blood cells

Energy Technology Data Exchange (ETDEWEB)

Fernley, P.W.; Lowe, D.M.; Donkin, P.; Evans, S. [Plymouth Marine Lab. (United Kingdom). Centre for Coastal and Marine Sciences; Moore, M.N. [Plymouth Marine Lab. (United Kingdom). Centre for Coastal and Marine Sciences; UNIDO, SES/PEM, Vienna International Centre (Austria)

2000-07-01

Coastal zones are among the most productive and vulnerable areas on the planet. An example of impact on these fragile environments was shown in the case of the Sea Empress oil tanker, which ran aground in the Bristol Channel in 1996, spilling 72,000 tonnes of Forties crude oil. The objective was to investigate the sub-lethal cellular pathology and tissue hydrocarbon contamination in marine mussel populations, 4 months after the initial spill, using the neutral red retention (NRR) assay for lysosomal stability in blood cells. NRR was reduced in mussels, and indicative of cell injury, from the two sites closest to the spill in comparison with more distant and reference sites. Lysosomal stability was inversely correlated with polycyclic aromatic hydrocarbon concentrations in mussel tissues. Reduced lysosomal stability has previously been shown to contribute to impaired immunocompetence and to autophagic loss of body tissues. The use of this type of technique is discussed in the context of cost-effective, ecotoxicological tools for Integrated Coastal Zone Management. (Author)

USSR: World Oil Report 1991

International Nuclear Information System (INIS)

Hovring, M.

1991-01-01

This paper reports that due to its lack of technology, the Soviet Union will have to double the number of wells it drills in the next five years in order to maintain today's oil output. It has been estimated that more than 11,000 new wells will have to be drilled in 1992 because of the declines in reserves and productivity per well. The only problem with this is that the USSR does not have the required funds at present. The Soviet Government has agreed to a 25-billion-rouble ($46 billion) cash injection for the oil industry to halt declining production. The USSR will need to find major new deposits to develop. There is oil in the exceptionally difficult geological conditions in Soviet central Asia and northern Siberia. However, the oil is located in hundreds of small fields. The only solution is to let international oil companies take part in development of production of these fields in order to raise the standard of technology employed

World oil and gas resources: status and outlook - A rational attempt at an emotional issue

International Nuclear Information System (INIS)

Burri, P.

2008-01-01

This paper examines the status of world oil and gas resources and attempts to provide a rational view of the situation and the prospects available. The author states that only about a quarter of the world's estimated ultimately recoverable oil resources and one eighth of the ultimate gas resources have been produced until today. Further, the author is of the opinion that very significant reserve additions are to be expected not only from the still existing exploration frontiers (e.g. deep water and Arctic fields) but even more so from new hydrocarbon detection tools, advanced recovery technology and from unconventional oil and gas resources. The price situation is discussed as are various developments that not only have a negative but also a positive impact on supplies. Reserves and unconventional resources are discussed, particularly from the pricing point of view. The effect of pricing on consumption is examined, as are new technologies for recovery and the potential available for future exploration

World oil and gas resources: status and outlook - A rational attempt at an emotional issue

Energy Technology Data Exchange (ETDEWEB)

Burri, P.

2008-07-01

This paper examines the status of world oil and gas resources and attempts to provide a rational view of the situation and the prospects available. The author states that only about a quarter of the world's estimated ultimately recoverable oil resources and one eighth of the ultimate gas resources have been produced until today. Further, the author is of the opinion that very significant reserve additions are to be expected not only from the still existing exploration frontiers (e.g. deep water and Arctic fields) but even more so from new hydrocarbon detection tools, advanced recovery technology and from unconventional oil and gas resources. The price situation is discussed as are various developments that not only have a negative but also a positive impact on supplies. Reserves and unconventional resources are discussed, particularly from the pricing point of view. The effect of pricing on consumption is examined, as are new technologies for recovery and the potential available for future exploration

Effect of carvacrol on the oxidative stability of palm oil during frying

Directory of Open Access Journals (Sweden)

İnanç, T.

2014-12-01

Full Text Available Fats and oils deteriorate physically and chemically at frying temperatures due to several reasons. The objective of this study was to assess the effect of carvacrol on the oxidative stability of palm oil during a repeated frying process. Potatoes were serially fried in carvacrol-added palm oil, BHT-added palm oil and a control oil (without any antioxidants. After each tenth frying cycle, several chemical analyses were carried out on collected samples to evaluate deterioration in the oils. The free fatty acid, para-anisidine, iodine, and total polar component values of the fresh oil were 0.080, 2.85, 57.1 and 7.5, respectively. These values changed to 0.165, 11.80, 46.7, 11.0, respectively for the control oil; 0.151, 11.28, 49.2 and 10.5 for BHT-added oil; 0.140, 7.19, 51.7, 10.0 for carvacrol-added oil after 40 frying cycles. The results revealed that the use of carvacrol could significantly improve the oxidative stability of palm oil when compared to the control samples. This effect was also comparable to BHT. Using carvacrol in frying oil slowed down the rate of the formation of conjugated dienes and trienes compared to the oil with BHT and the control. The frying process significantly changed the viscosity of the oil samples.Las grasas y aceites se deterioran física y químicamente a las temperaturas de fritura debido a diferentes razones. El objetivo de este estudio fue evaluar el efecto del carvacrol en la estabilidad oxidativa del aceite de palma durante el proceso de fritura repetida. Se sometió a fritura repetida patatas en el aceite de palma con carvacrol agregado, en aceite de palma con BHT agregado y en aceite control (sin antioxidante. Después de cada décimo ciclo de fritura, se realizaron diferentes análisis sobre las muestras recogidas para evaluar el deterioro de los aceites. Ácidos grasos libre, para-anisidina, índice de yodo y componentes polares totales del aceite fresco fueron: 0,080, 2,85, 57,1 y 7,5, respectivamente

Oil and international security: old and new issues

International Nuclear Information System (INIS)

Noel, P.

1998-09-01

This paper questions the effectiveness of the link between international oil and (inter)national security. First, it explains an acknowledge the rise and decline of the traditional case of this link: the threat that so called ''oil dependence'' inflicts upon the national economy, hence the problem it raises for government. The reason for that decline is looked for in the emergence of multiple forms of competition in oil and energy markets, making the ''oil weapon'' less credible and its use less desirable and less possible. In oil like in any other commodity, the normal situation is the competition between suppliers for access to markets. For all basic economics tells us and experience has confirmed, analyses and policies (at least in France) are still strongly influenced by the ''oil security'' thinking shaped in the eve of the 1970 crises. Yet, those fallacies may be the strongest obstacle to the acknowledgment of the real oil security issues we face. The main one is the possible political destabilization of the Middle East due to oil competition between its members in an increasingly competitive world market. The consequences on regional antagonisms of the come back of Iraqi oil to the market on one hand, the internal stability of Iran and Saudi Arabia in a situation of lasting low oil revenues on the other hand, are reviewed as the main possible factors of regional destabilization in a context of strong competition in the world oil market. A large scale political burst with major oil producers concerned would certainly hurt developed and developing economy. That leads us to this paradoxical situation: the very cause of the decline of the traditional oil dependence issue is, due to Middle East situation, the main cause of possible destabilization of world oil market today. (author)

Local stability and Hopf bifurcation in small-world delayed networks

International Nuclear Information System (INIS)

Li Chunguang; Chen Guanrong

2004-01-01

The notion of small-world networks, recently introduced by Watts and Strogatz, has attracted increasing interest in studying the interesting properties of complex networks. Notice that, a signal or influence travelling on a small-world network often is associated with time-delay features, which are very common in biological and physical networks. Also, the interactions within nodes in a small-world network are often nonlinear. In this paper, we consider a small-world networks model with nonlinear interactions and time delays, which was recently considered by Yang. By choosing the nonlinear interaction strength as a bifurcation parameter, we prove that Hopf bifurcation occurs. We determine the stability of the bifurcating periodic solutions and the direction of the Hopf bifurcation by applying the normal form theory and the center manifold theorem. Finally, we show a numerical example to verify the theoretical analysis

Local stability and Hopf bifurcation in small-world delayed networks

Energy Technology Data Exchange (ETDEWEB)

Li Chunguang E-mail: cgli@uestc.edu.cn; Chen Guanrong E-mail: gchen@ee.cityu.edu.hk

2004-04-01

The notion of small-world networks, recently introduced by Watts and Strogatz, has attracted increasing interest in studying the interesting properties of complex networks. Notice that, a signal or influence travelling on a small-world network often is associated with time-delay features, which are very common in biological and physical networks. Also, the interactions within nodes in a small-world network are often nonlinear. In this paper, we consider a small-world networks model with nonlinear interactions and time delays, which was recently considered by Yang. By choosing the nonlinear interaction strength as a bifurcation parameter, we prove that Hopf bifurcation occurs. We determine the stability of the bifurcating periodic solutions and the direction of the Hopf bifurcation by applying the normal form theory and the center manifold theorem. Finally, we show a numerical example to verify the theoretical analysis.

Combined effect of carnosol, rosmarinic acid and thymol on the oxidative stability of soybean oil using a simplex centroid mixture design.

Science.gov (United States)

Saoudi, Salma; Chammem, Nadia; Sifaoui, Ines; Jiménez, Ignacio A; Lorenzo-Morales, Jacob; Piñero, José E; Bouassida-Beji, Maha; Hamdi, Moktar; L Bazzocchi, Isabel

2017-08-01

Oxidation taking place during the use of oil leads to the deterioration of both nutritional and sensorial qualities. Natural antioxidants from herbs and plants are rich in phenolic compounds and could therefore be more efficient than synthetic ones in preventing lipid oxidation reactions. This study was aimed at the valorization of Tunisian aromatic plants and their active compounds as new sources of natural antioxidant preventing oil oxidation. Carnosol, rosmarinic acid and thymol were isolated from Rosmarinus officinalis and Thymus capitatus by column chromatography and were analyzed by nuclear magnetic resonance. Their antioxidant activities were measured by DPPH, ABTS and FRAP assays. These active compounds were added to soybean oil in different proportions using a simplex-centroid mixture design. Antioxidant activity and oxidative stability of oils were determined before and after 20 days of accelerated oxidation at 60 °C. Results showed that bioactive compounds are effective in maintaining oxidative stability of soybean oil. However, the binary interaction of rosmarinic acid and thymol caused a reduction in antioxidant activity and oxidative stability of soybean oil. Optimum conditions for maximum antioxidant activity and oxidative stability were found to be an equal ternary mixture of carnosol, rosmarinic acid and thymol. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

The geopolitics of $10 oil

International Nuclear Information System (INIS)

Anon.

1998-01-01

The market and the geopolitical implications of the possibility of $10 a barrel becoming the norm for oil prices in 1999 are examined. The low price will present budgetary difficulties for all the world's major oil producing countries with the exception of Brunei. In some countries, such as Nigeria and Venezuela, general financial and economic reform will become inevitable with the pressure for political reform to follow. If energy development is to continue in the Caspian region in a low price era, long term political stability will be necessary and a move towards democracy from the present autocracies may be necessary to achieve this. In the Middle East, countries are facing the erosion of their core financial base. Depressed oil prices could force Gulf States, which in the past have depended on their oil revenues alone, to introduce taxation as an alternative source of income. Hitherto, oil has meant power in political as well as in energy terms, but the diminished value of oil in a world where their are alternative energy sources will reduce the importance, even of key regions such as the Middle East. The power of OPEC is threatened by its failure to bring about the massive co-ordinated production cutbacks which alone might turn the market around. The beneficiaries of cheap oil will be the consuming nations, particularly those of East Asia where the pace of economic recovery will be speeded up. (UK)

Reference data on world oil markets

International Nuclear Information System (INIS)

2005-01-01

This paper makes a status of the 2004 activity of worldwide oil markets: oil demand, oil supplies (OPEC and non-OPEC countries, unused production capacities), formation of oil prices (role of stockpiles, role of terminal markets, impact of dollar rate), economic data: OPEC objectives, market vision, volatility of prices, supply and demand. (J.S.)

Oxidative stability of soybean oil in oleosomes as affected by pH and iron.

Science.gov (United States)

Kapchie, Virginie N; Yao, Linxing; Hauck, Catherine C; Wang, Tong; Murphy, Patricia A

2013-12-01

The oxidative stability of oil in soybean oleosomes, isolated using the Enzyme-Assisted Aqueous Extraction Process (EAEP), was evaluated. The effects of ferric chloride, at two concentration levels (100 and 500 μM), on lipid oxidation, was examined under pH 2 and 7. The peroxide value (PV) and thiobarbituric acid-reactive substance (TBARS) value of oil, in oleosome suspensions stored at 60 °C, were measured over a 12 day period. The presence of ferric chloride significantly (Poil in the isolated oleosome, as measured by the PV and TBARS. Greater lipid oxidation occurred under an acidic pH. In the pH 7 samples, the positively charged transition metals were strongly attracted to the negatively charged droplets. However, the low ζ-potential and the high creaming rate at this pH, may have limited the oxidation. Freezing, freeze-drying or heating of oleosomes have an insignificant impact on the oxidative stability of oil in isolated soybean oleosomes. Manufacturers should be cautious when adding oleosomes as ingredients in food systems containing transition metal ions. Published by Elsevier Ltd.

Oil and Labour: The Pivotal Position of Persian Oil in The First World War and the Question of Transnational Labour Dependency

NARCIS (Netherlands)

Atabaki, T.; De Vito, Christian G.; Gerritsen, Anne

2017-01-01

Atabaki examines the conceptualization, articulation, and implementation of the Oil Company’s shifting labour policy against the background of greater global geopolitical shifts during the First World War. The chapter especially addresses the spatiality of labour recruitment across the Persian

A rapid method for evaluation of the oxidation stability of castor oil FAME: influence of antioxidant type and concentration

Energy Technology Data Exchange (ETDEWEB)

Araujo, Susana V.; Luna, F. Murilo T.; Rola, Estelio M. Jr.; Azevedo, Diana C.S.; Cavalcante, Celio L. Jr. [Universidade Federal do Ceara, Departamento de Engenharia Quimica, Grupo de Pesquisa em Separacoes por Adsorcao - GPSA, Campus do Pici, 709, Fortaleza, CE, 60.455-900 (Brazil)

2009-10-15

The oxidation stability of castor oil fatty methyl ester (FAME), doped with four different phenolic antioxidants, was evaluated using a rapid method of thermal and air-contact degradation. The methodology is based on the induction times observed when the samples are contacted with pure oxygen at elevated pressures and temperatures. The results indicate different performances of the antioxidants as well as synergisms between antioxidants and biodiesel. In general, the addition of antioxidants increased from 6-15 times the stability of castor oil FAME., with BHA (butylated hydroxyanisol) showing the best results for improving antioxidation in castor oil biodiesel. (author)

Economics of Russian oil production

International Nuclear Information System (INIS)

Gubenko, I.

1993-01-01

The main technical indicators of oil production in Russia are presented from the year 1988, when the current decline in oil production started. In 1992, only 9 new oil deposits were put into production, and average well productivity dropped to 12.4 tonnes/d. The number of idle wells reached 31,934 as compared to 8,714 in 1988. The share of low productivity deposits in 1993 was 49.7%. In the first five months of 1993, the number of new wells put into operation failed to offset the shutdown of old wells. Although the number of workovers grew by 32%, this work was insufficient to stabilize oil production. The decline in production is due to the general state of economic stability and endless reorganizations in the economy, and to the lack of sufficient investment in the industry. Oil-producing enterprises have lacked funds due to systematic and growing indebtedness of buyers of crude. This overdue indebtedness reached 393 billion rubles by the beginning of 1993. Although domestic oil prices increased sharply in 1991-92, the volume of production in real terms has dropped by nearly a third. Oil is sold at different prices to different categories of buyers. Prices include expenses, profit from which a 32% profits tax is paid, excise taxes, and payments to a centralized price-regulation fund. From the industry point of view, certain reforms are necessary to reconstruct and develop the industry. These include ensuring payments to oil producers, gradual transfer of Russian prices to world levels, lowering taxes, and adoption and refinement of a law on oil. 1 fig., 7 tabs

Chemical quality and oxidative stability of extra virgin olive oils from San Juan province (Argentina).

Science.gov (United States)

Ceci, Liliana N; Mattar, Susana B; Carelli, Amalia A

2017-10-01

This study provides information about the chemical quality (quality indices, fatty acid profile, total polyphenols (PPs), tocopherols and pigments) and oxidative stability index (OSI) of virgin olive oils of Arbequina, Changlot Real and Coratina cultivars (San Juan province, Argentina). The influence of the cultivar and the effect of earlier harvest dates on the yields (OY), quality and OSI of the oils were also evaluated. All the oils were classified as extra virgin. The OY (L/100kg) averaged: Arbequina=13.2, Changlot Real=21.3, Coratina=18.3. The oleic acid (O) percentage, oleic to linoleic plus linolenic ratio [O/(L+Ln)], PPs and OSI were highly dependent on cultivar (Arbequinaoils (Arbequina: from 6.3-13.8h up to 10.6-19.0h, Changlot: from 6.0-12.1h up to 13.7-36.9h and Coratina: from 20.5-26.0h up to 24.6-42.4h) due to a more favorable O/(L+Ln) ratio and antioxidant composition. Regional producers are recommended to bring forward the harvest season to obtain oils with better chemical and nutritional quality, higher oxidative stability and a fatty acid profile according to the IOC trade standard. Copyright © 2017 Elsevier Ltd. All rights reserved.

Oil crisis and the emerging world order

Energy Technology Data Exchange (ETDEWEB)

Baumgartner, T. (Univ. of Quebec, Montreal); Burns, T.R.; Deville, P.

1977-08-01

The paper outlines a conceptual framework for understanding and analyzing the structuring of an institutional order. Particular attention is given to developments that make institution restructuring likely--for instance power shifts which favor actors with a different vision or model of an appropriate institutional order. The framework is applied in a brief historical study of the development of post-World War II international economic institutions and current developments associated with the ''oil crisis.'' This conceptual framework and historical investigation provides a basis on which to formulate propositions, indicating potential sources of conflict and cooperating and certain ambiguities and dynamics of current institution restructuring in the international system. The paper concludes by outlining several action guidelines for structuring new global cultural forces and institutional forms related to bringing about a New International Economic Order. 43 references.

Development and stability evaluation of water-in-edible oils emulsions formulated with the incorporation of hydrophilic Hibiscus sabdariffa extract.

Science.gov (United States)

Pimentel-Moral, Sandra; Rodríguez-Pérez, Celia; Segura-Carretero, Antonio; Martínez-Férez, Antonio

2018-09-15

New functional oils (extra virgin olive oil, EVOO and sunflower oil, SO) containing antioxidants from Hibiscus sabdariffa extract were developed by W/O emulsion. Their physical and chemical stability was measured over time. The lowest coalescence rate was obtained with 8 and 12 wt% surfactant amount for EVOO and SO emulsions, respectively. Before the evaluation of the oxidative stability, an optimization of phenolic compounds extraction from emulsions by multi-response surface methodology was performed. EVOO emulsions were chemically more stable over time than SO emulsions in terms of total phenolic content (TPC), antioxidant activity and chemical composition measured by HPLC-ESI.TOF-MS. TPC significantly increased (from 2.02 ± 0.07 to 2.71 ± 0.06 mg Eq GAE/g extract) and the antioxidant activity measured by TEAC remained constant for 1 month of storage. Thus, W/O emulsion technology has proven to be a potential method to vehiculize and stabilize bioactive compounds from H. sabdariffa into edible oils. Copyright © 2018 Elsevier Ltd. All rights reserved.

Oxidative stability of pullulan nanofibers loaded with fish oil: effect of oil content and antioxidants addition

DEFF Research Database (Denmark)

García Moreno, Pedro Jesús; Damberg, C.; Stephansen, K.

Electrospinning processing is a promising technique for the encapsulation of thermolabile bioactive compounds (e.g. fish oil) since it does not require the use of heat. Furthermore, the nano-microfibers (NMF) obtained present a reduced size, which makes them easier to disperse in food matrices...... compared to traditional encapsulates (e.g. microcapsules produced by spray-drying). Biopolymers such as proteins and polysaccharides are required for the production of food-grade NMF. In this sense, pullulan, which is a food-approved polysaccharide, is an interesting encapsulating material due to its high...... electrospinnability and low oxygen permeability. In light of the above, the aim of this work was to investigate the oxidative stability of omega-3 enriched pullulan NMF. First, the influence of fish oil content (10-20-30 %) on the properties of the electrospinning solutions (e.g. viscosity, conductivity and surface...

A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils

Energy Technology Data Exchange (ETDEWEB)

Diebold, J.P.

1999-01-27

Understanding the fundamental chemical and physical aging mechanisms is necessary to learn how to produce a bio-oil that is more stable during shipping and storage. This review provides a basis for this understanding and identifies possible future research paths to produce bio-oils with better storage stability.

Effect of heat-treatment with raw cotton seed oil on decay resistance and dimensional stability of Beech (Fagus orientalis

Directory of Open Access Journals (Sweden)

مریم قربانی

2015-05-01

Full Text Available This research was conducted to determine the effect of heat-treatment with raw cotton seed oil on decay resistance and dimensional stability of beech according to EN113 and ASTM-D1037 standards respectively. The heat treatment with raw cotton seed oil was carried out in the cylinder at the temperatures of 130 and 170oC for 30 and 60 minutes. Oil uptake, density, volumetric swelling, water absorption and weight loss exposed to decay were measured. Oil uptake at 30 and 60 min were determined 10.5 and 13.3 Kg/cm3 respectively. Oil-heat treated samples at 30min and 130°C indicated the maximum density with 87.7% increase. According to results, oil-heat treatment improved water repellency and dimensional stability. Water absorption in 130°C and 60 minutes decreased 76% in comparison with control. Decay resistance of oil soaked samples for 60minutes was 80.2% more than control samples. Oil-heat treatment compared with oil treatment improved decay resistance, this effect was significant at 30 min. The temperature rise of oil–heat treatment at 30 minutes improved decay resistance, but the improvement under same level of temperature with increase time was not significant.

The world energy demand in 2007: How high oil prices impact the global energy demand? June 9, 2008

International Nuclear Information System (INIS)

2008-01-01

How high oil prices impact the global energy demand? The growth of energy demand continued to accelerate in 2007 despite soaring prices, to reach 2,8 % (+ 0,3 point compared to 2006). This evolution results from two diverging trends: a shrink in energy consumption in most of OECD countries, except North America, and a strong increase in emerging countries. Within the OECD, two contrasting trends can be reported, that compensate each other partially: the reduction of energy consumption in Japan (-0.8%) and in Europe (-1.2%), particularly significant in the EU-15 (-1.9%); the increase of energy consumption in North America (+2%). Globally, the OECD overall consumption continued to increase slightly (+0.5%), while electricity increased faster (2,1%) and fuels remained stable. Elsewhere, the strong energy demand growth remained very dynamic (+5% for the total demand, 8% for electricity only), driven by China (+7.3%). The world oil demand increased by 1% only, but the demand has focused even more on captive end usages, transports and petrochemistry. The world gasoline and diesel demand increased by around 5,7% in 2007, and represents 53% of the total oil products demand in 2007 (51% in 2006). If gasoline and diesel consumption remained quasi-stable within OECD countries, the growth has been extremely strong in the emerging countries, despite booming oil prices. There are mainly two factors explaining this evolution where both oil demand and oil prices increased: Weak elasticity-prices to the demand in transport and petrochemistry sectors Disconnection of domestic fuel prices in major emerging countries (China, India, Latin America) compared to world oil market prices Another striking point is that world crude oil and condensate production remained almost stable in 2007, hence the entire demand growth was supported by destocking. During the same period, the OPEC production decreased by 1%, mainly due to the production decrease in Saudi Arabia, that is probably more

Formation and stability of oil-in-water nanoemulsions containing rice bran oil: in vitro and in vivo assessments

Directory of Open Access Journals (Sweden)

Rocha-Filho Pedro A

2011-09-01

Full Text Available Abstract Background Nanoemulsions have practical application in a multitude of commercial areas, such as the chemical, pharmaceutical and cosmetic industries. Cosmetic industries use rice bran oil in sunscreen formulations, anti ageing products and in treatments for skin diseases. The aim of this study was to create rice bran oil nanoemulsions using low energy emulsification methods and to evaluate their physical stability, irritation potential and moisturising activity on volunteers with normal and diseased skin types. Results The nanoemulsion developed by this phase diagram method was composed of 10% rice bran oil, 10% surfactants sorbitan oleate/PEG-30 castor oil, 0.05% antioxidant and 0.50% preservatives formulated in distilled water. The nanoemulsion was stable over the time course of this study. In vitro assays showed that this formulation has a low irritation potential, and when applied to human skin during in vivo studies, the nanoemulsion improved the skin's moisture and maintained normal skin pH values. Conclusion The results of irritation potential studies and in vivo assessments indicate that this nanoemulsion has potential to be a useful tool to treat skin diseases, such as atopic dermatitis and psoriasis.

Review of the stability of biodiesel produced from less common vegetable oils of African origin

Directory of Open Access Journals (Sweden)

Thomas Kivevele

2015-09-01

Full Text Available The stability of biodiesel is dependent on storage conditions such as contact with ambient air and metals, exposure to sunlight and high temperature conditions which accelerate oxidation reactions. In addition, biodiesels are more susceptible to degradation when compared to fossil diesel because of the presence of unsaturated fatty acid chains which are prone to oxidation. The stability of biodiesel is categorised according to oxidation stability, storage stability and thermal stability. Oxidation instability can led to the formation of oxidation products such as aldehydes, alcohols, shorter chain carboxylic acids, insolubles, gums and sediments in the biodiesel. Thermal instability is concerned with the increased rate of oxidation at higher temperature, which in turn increases the weight of oil and fat due to the formation of insolubles. Storage stability is the ability of liquid fuel to resist change to its physical and chemical characteristics brought about by its interaction with its storage environment, such as contamination with metals. These fuel instabilities give rise to the formation of undesirable substances in biodiesel beyond acceptable limits as per global biodiesel standards such as those of the American Society for Testing and Materials (ASTM D6751 and European Standards (EN 14214. When such fuel is used in the engine, it impairs engine performance through fuel filter plugging, injector fouling, and deposit formation in the engine combustion chamber and various components of the fuel system. We review the stability of biodiesel made from less common vegetable oils of African origin and synthetic antioxidants used in improving the stability of produced biodiesels.

Alkyl Caffeates Improve the Antioxidant Activity, Antitumor Property and Oxidation Stability of Edible Oil

Science.gov (United States)

Wang, Jun; Gu, Shuang-Shuang; Pang, Na; Wang, Fang-Qin; Pang, Fei; Cui, Hong-Sheng; Wu, Xiang-Yang; Wu, Fu-An

2014-01-01

Caffeic acid (CA) is distributed widely in nature and possesses strong antioxidant activity. However, CA has lower solubility in non-polar media, which limits its application in fat-soluble food. To increase the lipophilicity of natural antioxidant CA, a series of alkyl caffeates were synthesized and their antioxidant and antitumor activities were investigated. The antioxidant parameters, including the induction period, acid value and unsaturated fatty acid content, of the alkyl caffeates in edible oil were firstly investigated. The results indicated that alkyl caffeates had a lower DPPH IC50 (14–23 µM) compared to CA, dibutyl hydroxy toluene (BHT) and Vitamin C (24–51 µM), and significantly inhibited four human cancer cells (SW620, SW480, SGC7901 and HepG2) with inhibition ratio of 71.4–78.0% by a MTT assay. With regard to the induction period and acid value assays, methyl and butyl caffeates had higher abilities than BHT to restrain the oxidation process and improve the stability of edible oil. The addition of ethyl caffeate to oil allowed maintenance of a higher unsaturated fatty acid methyl ester content (68.53%) at high temperatures. Overall, the alkyl caffeats with short chain length (n<5) assessed better oxidative stability than those with long chain length. To date, this is the first report to the correlations among the antioxidant activity, anticancer activity and oxidative stability of alkyl caffeates. PMID:24760050

Alkyl caffeates improve the antioxidant activity, antitumor property and oxidation stability of edible oil.

Directory of Open Access Journals (Sweden)

Jun Wang

Full Text Available Caffeic acid (CA is distributed widely in nature and possesses strong antioxidant activity. However, CA has lower solubility in non-polar media, which limits its application in fat-soluble food. To increase the lipophilicity of natural antioxidant CA, a series of alkyl caffeates were synthesized and their antioxidant and antitumor activities were investigated. The antioxidant parameters, including the induction period, acid value and unsaturated fatty acid content, of the alkyl caffeates in edible oil were firstly investigated. The results indicated that alkyl caffeates had a lower DPPH IC₅₀ (14-23 µM compared to CA, dibutyl hydroxy toluene (BHT and Vitamin C (24-51 µM, and significantly inhibited four human cancer cells (SW620, SW480, SGC7901 and HepG2 with inhibition ratio of 71.4-78.0% by a MTT assay. With regard to the induction period and acid value assays, methyl and butyl caffeates had higher abilities than BHT to restrain the oxidation process and improve the stability of edible oil. The addition of ethyl caffeate to oil allowed maintenance of a higher unsaturated fatty acid methyl ester content (68.53% at high temperatures. Overall, the alkyl caffeats with short chain length (n<5 assessed better oxidative stability than those with long chain length. To date, this is the first report to the correlations among the antioxidant activity, anticancer activity and oxidative stability of alkyl caffeates.

Planning Oil Prices In The World Market And Preventive Policies In Energy Sector Of Iran

International Nuclear Information System (INIS)

Raees Dana, Fariborz

1999-01-01

The planning of oil prices in the world can not be analyzed by means of the market-competition theory or the game theory. The current prices seem to be influenced greatly by large energy consuming industries of developed countries, oil producing corporations and cartels, and oil productions outside of OPEC. There is a lack of necessary long term policies and planning so that drastic changes in market prices can be avoided. The goal of this paper is to suggest new policies by means of discussing in following issues: 1.Initiating some form of a financial support for OPEC with the necessary follow up. 2. Utilization of oil income in sectors organized to have the least susceptibility against income loss and the lowest impact on other sectors. 3. Reducing of oil production level in the local and global framework and starting in industrialization process. 4. Replacement of oil with natural gas at a faster rate. 5. improving the oil industry infrastructure for lowering production costs and increasing variety in products in light of country economic policies and occupational strategies. 6. Imposing self-reliance on development of oil-production technology

The world energy demand in 2005: confirmed increase in energy consumptions, despite soaring crude oil prices

International Nuclear Information System (INIS)

Chateau, Bertrand

2006-01-01

The world energy demand growth remains strong: 2004 experienced the highest growth since 19987, and brent prices had moderate impact in 2005: Very strong rise of energy consumptions despite high oil prices, Economic situation still favorable, Evolutions principally due to China. 2005 world energy consumption: 11,4 Gtoe: Asia accounts for 35% of the world energy consumption, China's weight (15%) continues to increase by one point every year (+5 points since 2000). Asia increases its pressure on the world energy growth in 2005: China accounts for almost half of the world energy consumption increase in 2005, the whole Asia accounts for 70%; The European consumption growth represents less than 5% of China's Growth; The American energy consumption decreases for the first time. 2005 world consumption by energy: With an increasing market share by 0,7 points, coal penetration increases; The oil market has lost 0,4 point, with an accelerating relative decrease; The relative weight of gas remains stable, with 21%. Energy efficiency and energy intensity of GDP: Slow-down of the world energy intensity decrease since 2001, whereas the economic growth is faster, due to changes in trends in China (increase in the recent years). Increase less sharp in China in 2005 (price effect). Energy intensity trends of GDP: Fast decrease in CIS since the recovery of the economic growth; Slow-down of the decrease in EU since 2000 and recovery in 2005 whereas the decrease has accelerated in the USA. Since 2000, the energy consumption increases less rapidly than the GDP almost everywhere, except for the Middle East. Projections until 2020: China and India could represent one third of the world energy growth, the whole of Asia more than 50%; Growth prospects for energy demand are low in the EU and CIS; America would account for 20% of the world energy growth (8% USA); In the rest of the world, high growth in Africa and in the Middle East. Gas could cover more than 40% of the world energy

世界油气资源形势分析%The Analysis of World Oil and Gas Resources Situation

Institute of Scientific and Technical Information of China (English)

张所续

2013-01-01

World primary energy consumption grew by 1.8% in 2012,well below that of the past decade ,which was 2 .6%.And the proportion of oil ,natural gas was 33 .1%,23 .9%,respectively . There was a continuous decline in oil shares .World oil reserves increased slightly by 0.9%,while natural gas reserves declined by0 .3 %.The strong growth of unconventional oil and gas produc-tion,including shale gas and tight oil ,will have a significant impact on the global energy landscape . According to 2013 World Energy Reserves Statistical Yearbook released by BP , production and consumption of the world 's oil and natural gas,etc.were analyzed,and the situation was discussed .%2012年世界一次能源消费量增长1．8％，远低于过去十年2．6％的平均增速；其中石油、天然气所占比重分别为33．1％、239．％，石油份额连续下滑。世界石油储量微增0．9％，天然气储量减少0．3％，随着页岩气、致密油等非常规油气产量的强劲增长将对全球能源格局产生重大影响。根据BP发布的2013年世界能源统计年鉴，对世界石油和天然气的储量、产量、消费量等情况进行分析，并展开形势研判。

Classification and analysis of factors that affect stability of oil and gas enterprise staff

Directory of Open Access Journals (Sweden)

Zelinska Haluna Olexiivna

2016-12-01

Full Text Available The relevance of human resources as a strategic goal of sustainable development of oil and gas companies is determined. It is shown that the stability of staff, as the main component of the social components of sustainable enterprise development, research and evaluation needs in terms of an integrated system of factors influence the behavior of staff. Addressing issues related to the management personnel can be based classification study the factors affecting its stability in the formation of high quality human resources strategy. In particular noted that the needs of each employee should become an integral part of the concept of work and life balance. Analysis of the results of the study showed that in areas of oil and gas industry has a number of factors that negatively affect its operation and development, which are caused not only technical, technological and natural factors, but also due to neglect behavioral characteristics personnel. It is found that without understanding of the behavioral characteristics of staff and its values can`t implement a quality model of human resource management and provide optimal scenarios of oil companies in general.

Oxidative stability of mayonnaise and milk drink produced with structured lipids based on fish oil and caprylic acid

DEFF Research Database (Denmark)

Timm Heinrich, Maike; Xu, Xuebing; Nielsen, Nina Skall

2004-01-01

The oxidative stabilities of traditional fish oil (FO), randomized lipids (RFO), or specific structured lipids (SFO) produced from fish oil were compared when incorporated into either milk drink or mayonnaise. Furthermore, the effect of adding the potential antioxidants EDTA (240 mg...... not be ascribed to a single factor, but was most likely influenced by the structure of the lipids and differences in the processes used to produce and purify the lipids. In milk drinks based on SFO, EDTA slightly reduced oxidation, while lactoferrin did not exert a distinct antioxidative effect....../kg) or lactoferrin (1000 mg/kg) to the milk drink based on SFO was investigated. The lipid type significantly affected the oxidative stability of both mayonnaises and milk drinks: The oxidative stability decreased in the order RFO>FO>SFO. The reduced oxidative stability in the SFO food emulsions could...

Foam-oil interaction in porous media: implications for foam assisted enhanced oil recovery.

Science.gov (United States)

Farajzadeh, R; Andrianov, A; Krastev, R; Hirasaki, G J; Rossen, W R

2012-11-15

The efficiency of a foam displacement process in enhanced oil recovery (EOR) depends largely on the stability of foam films in the presence of oil. Experimental studies have demonstrated the detrimental impact of oil on foam stability. This paper reviews the mechanisms and theories (disjoining pressure, coalescence and drainage, entering and spreading of oil, oil emulsification, pinch-off, etc.) suggested in the literature to explain the impact of oil on foam stability in the bulk and porous media. Moreover, we describe the existing approaches to foam modeling in porous media and the ways these models describe the oil effect on foam propagation in porous media. Further, we present various ideas on an improvement of foam stability and longevity in the presence of oil. The outstanding questions regarding foam-oil interactions and modeling of these interactions are pointed out. Copyright © 2012 Elsevier B.V. All rights reserved.

Crude oil and finished fuel storage stability: An annotated review

Energy Technology Data Exchange (ETDEWEB)

Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

1991-01-01

A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

Improving the clean-up efficiency of field soil contaminated with diesel oil by the application of stabilizers.

Science.gov (United States)

Chang, Yoon-Young; Roh, Hoon; Yang, Jae-Kyu

2013-01-01

Fenton-like oxidation in the presence of stabilizers has been applied in batch and column reactors to treat field soils contaminated with diesel oil. Citrates, ethylene diamine tetra-acetic acid (EDTA), ethylene diamine disuccinic acid (EDDS) and phosphates were assessed as stabilizers. The stability of hydrogen peroxide in the soil was evaluated by varying the concentration of each stabilizer and hydrogen peroxide. In a batch test, the residual concentration of hydrogen peroxide was shown to be directly related to the concentration of these stabilizers. Citrate showed the greatest stabilizing effect of the four stabilizers for hydrogen peroxide and 0.05 M was selected as the optimum dosage. In order to investigate the effect of stabilizer on the efficiency of removal of total petroleum hydrocarbons (TPH) in a column reactor, 30 mL of each stabilizer solution at pH 3 and containing 15% hydrogen peroxide was injected. The batch result confirmed that the greatest TPH removal took place in the presence of citrate in a column reactor. The order of TPH removal in the presence of stabilizers was: citrate > H3PO4 > EDDS > EDTA. TPH removal was affected by the concentration of stabilizer and the initial concentration of TPH. When 0.05 M citrate solution containing 15% hydrogen peroxide was applied to four field soils and an artificially contaminated soil, similar or better TPH removal was observed in the field soils compared to the artificially contaminated soil. This result suggests that Fenton-like oxidation with stabilizer can be effective in restoring field soils contaminated with diesel oil.

Where in the World are Canadian Oil and Gas Companies? 2013

Directory of Open Access Journals (Sweden)

Niloo Hojjati

2017-06-01

Full Text Available Begun in 2011 as an internal research tool for the development of the Extractive Resource Governance Program, this project seeks to answer the vital question: Where in the world are Canadian oil and gas companies? To answer this question, we extract firm-level information for publicly traded Canadian companies in order to establish the location of their activities around the globe.1 The data collected in the “Where in the World” (hereafter WIW project are presented through a publicly accessible interactive world map, which allows users to explore a specific country or region over time. This map can be accessed online at http://www.policyschool.ca/research-teaching/teaching-training/ extractive-resource-governance/ergp-map/. For further information regarding the WIW project, including a comprehensive overview of the methodology, please refer to http://www.policyschool.ca/wp-content/uploads/2017/06/Where-in-theWorld-Hojjati-Horsfield-Jordison-final.pdf. In addition, summary reports of the annual data collection for the 2011 and 2012 years of analysis are also available at http://www.policyschool.ca/wp-content/uploads/2017/06/2011-Where-in-theWorld-Hojjati-Horsfield-Jordison-final.pdf and http://www.policyschool.ca/wpcontent/uploads/2017/06/2012-Where-in-the-World-Hojjati-final.pdf. This report, as in the earlier reports in this series, provides an account of emerging trends and highlights variations in the level of global activities of Canadian oil and gas companies (hereafter O&G for the 2013 year of study.2 In 2013, a total of 226 Canadian O&G companies engaged in global exploration and service activities in 99 countries worldwide. The Middle East and Europe experienced the greatest increase in the concentration of Canadian exploration and production (E&P companies. Meanwhile, the international presence of Canadian O&G service companies continued to grow in several countries, including Colombia, Mexico, and the United Kingdom. This report

Emulsion stability and properties of fish gelatin-based films as affected by palm oil and surfactants.

Science.gov (United States)

Nilsuwan, Krisana; Benjakul, Soottawat; Prodpran, Thummanoon

2016-05-01

Gelatin films exhibit the poor water vapour barrier properties. The use of palm oil, which is abundant and available in Thailand, can be a means to lower water vapour migration. To disperse oil in film-forming dispersion (FFD), a surfactant along with appropriate homogenization is required. The study aimed to investigate the influence of palm oil level and surfactants in the absence or presence of glycerol on characteristics of FFD and resulting gelatin films. Similar oil droplet sizes, both d32 and d43 values, of FFD containing soy lecithin were observed, regardless of palm oil level used (P > 0.05). FFD with Tween-20 had larger droplet size as the levels of oil increased (P palm oil level increased (P 0.05). FFD containing 500 or 750 g kg(-1) palm oil using soy lecithin as a surfactant in the presence of 300 g kg(-1) glycerol had the enhanced homogeneity and stability of oil droplets. The resulting gelatin film had the improved water vapour barrier properties. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

Physical Stability of Oil in Water Emulsions in the Presence of Gamma Irradiated Gum Tragacanth

DEFF Research Database (Denmark)

Meybodi, Neda Mollakhalili; Mohammadifar, Mohammad Amin; Farhoodi, Mehdi

2017-01-01

Gum tragacanth (GT) exuded from an Iranian Astragalus species was γ-irradiated at 0, 0.75, 1.5, 3, 5, 7, 10 kGy and used to stabilize a model oil in water emulsion system. Stability and physicochemical properties of emulsion samples were investigated with respect to the effect of irradiation...... treatment on functional properties of gum tragacanth. Particle size distribution, interfacial tension, zeta potential, steady shear and oscillatory rheological measurements were used to characterize and evaluate the emulsion samples and obtain more information about the possible stability mechanism...

The Stability of Lubricant Oil Acidity of Biogas Fuelled Engine due to Biogas Desulfurization

Science.gov (United States)

Gde Tirta Nindhia, Tjokorda; Wayan Surata, I.; Wardana, Ari

2017-05-01

This research is established for the purpose of the understanding the stability of the acidity of lubricant oil in biogas fuelled engine due to the absence of hydrogen sulfide (H2S). As was recognized that other than Methane (CH4), there are also other gas impurities in the biogas such as carbon dioxide (CO2), hydrogen sulfide (H2S), moisture (H2O) and ammonia (NH3). Due to H2S contents in the biogas fuel, the engine was found failure. This is caused by corrosion in the combustion chamber due to increase of lubricant acidity. To overcome this problem in practical, the lubricant is increased the pH to basic level with the hope will be decrease to normal value after several time use. Other method is by installing pH measurement sensor in the engine lubricant so that when lubricant is known turn to be acid, then lubricant replacement should be done. In this research, the effect of biogas desulfurization down to zero level to the acidity of lubricant oil in the four stroke engine was carried out with the hope that neutral lubrication oil to be available during running the engine. The result indicates that by eliminating H2S due desulfurization process, effect on stability and neutrality of pH lubricant. By this method the engine safety can be obtained without often replacement the lubricant oil.

Evaluation of antioxidants stability by thermal analysis and its protective effect in heated edible vegetable oil

Directory of Open Access Journals (Sweden)

Seme Youssef Reda

2011-06-01

Full Text Available In this work, through the use of thermal analysis techniques, the thermal stabilities of some antioxidants were investigated, in order to evaluate their resistance to thermal oxidation in oils, by heating canola vegetable oil, and to suggest that antioxidants would be more appropriate to increase the resistance of vegetable oils in the thermal degradation process in frying. The techniques used were: Thermal Gravimetric (TG and Differential Scanning Calorimetry (DSC analyses, as well as an allusion to a possible protective action of the vegetable oils, based on the thermal oxidation of canola vegetable oil in the laboratory under constant heating at 180 ºC/8 hours for 10 days. The studied antioxidants were: ascorbic acid, sorbic acid, citric acid, sodium erythorbate, BHT (3,5-di-tert-butyl-4-hydroxytoluene, BHA (2, 3-tert-butyl-4-methoxyphenol, TBHQ (tertiary butyl hydroquinone, PG (propyl gallate - described as antioxidants by ANVISA and the FDA; and also the phytic acid antioxidant and the SAIB (sucrose acetate isobutyrate additive, which is used in the food industry, in order to test its behavior as an antioxidant in vegetable oil. The following antioxidants: citric acid, sodium erythorbate, BHA, BHT, TBHQ and sorbic acid decompose at temperatures below 180 ºC, and therefore, have little protective action in vegetable oils undergoing frying processes. The antioxidants below: phytic acid, ascorbic acid and PG, are the most resistant and begin their decomposition processes at temperatures between 180 and 200 ºC. The thermal analytical techniques have also shown that the SAIB antioxidant is the most resistant to oxidative action, and it can be a useful choice in the thermal decomposition prevention of edible oils, improving stability regarding oxidative processes.

Geothermal energy in the world energy scenario

International Nuclear Information System (INIS)

Barbier, E.

1989-01-01

This paper reports on the world energy consumption between 1960 and 1984 from primary energy sources (coal, natural gas, oil, hydropower, nuclear energy) and the same in percentages from 1925. This highlights the diminishing role of coal and the increased consumption of gas and oil. The latter has stabilized around 42% of the total after the drop in demand resulting from the oil crisis of 1973. The world energy consumption has then been divided into industrialized and developing countries. It appears that the latter, with a population equal to 68% of the total world population, consumed 23% of the world energy in 1982. Furthermore, the consumption figures show that the demand for domestic energy is much smaller in developing countries, and it is well-known that domestic energy consumed is one of the parameters used to assess standard of living. The total installed electric capacity throughout the world is then reported, divided between developed and developing countries, showing that the latter consumed 11% of all the electricity generated in the world in 1981. The world installed electric power of geothermal origin at the end of 1985 is shown, along with estimates for 1990. Geothermal energy represents 0.2% of the world electric power. This is obviously a small figure and indicates that geothermal energy plays a minor role on the world energy scene. However, if we distinguish between industrialized and developing countries, we can observe that, with their currently limited electrical consumption but good geothermal prospects, the developing countries could achieve quite a significant contribution to their total electric energy from that of geothermal origin, increasing at the moment from 3 to 19%. Finally, a comparison is made between electricity generating costs of different sources, showing that geothermal energy is competitive. A table illustrates the world evolution in installed geothermal capacity from 1950 to 1985. The non-electric uses of geothermal energy

The potential applications in heavy oil EOR with the nanoparticle and surfactant stabilized solvent-based emulsion

Energy Technology Data Exchange (ETDEWEB)

Qiu, F. [Texas A and M Univ., College Station, TX (United States)

2010-07-01

The main challenges in developing the heavy oil reservoirs in the Alaska North Slope (ANS) include technical challenges regarding thermal recovery; sand control and disposal; high asphaltene content; and low in-situ permeability. A chemical enhanced oil recovery method may be possible for these reservoirs. Solvent based emulsion flooding provides mobility control; oil viscosity reduction; and in-situ emulsification of heavy oil. This study evaluated the potential application of nano-particle-stabilized solvent based emulsion injection to enhance heavy oil recovery in the ANS. The optimized micro-emulsion composition was determined using laboratory tests such as phase behaviour scanning, rheology studies and interfacial tension measurements. The optimized nano-emulsions were used in core flooding experiments to verify the recovery efficiency. The study revealed that the potential use of this kind of emulsion flooding is a promising enhanced oil recovery process for some heavy oil reservoirs in Alaska, Canada and Venezuela. 4 refs., 2 tabs., 10 figs.

Cognitive factors in subjective stabilization of the visual world.

Science.gov (United States)

Bridgeman, B

1981-08-01

If an eye movement signal is fed through a galvanic mirror, to move a projected image which a subject is inspecting, prominent objects in the image may seem to jiggle or jump with the the eye when the gain is just below the threshold for detecting a jump of the entire image (Brune and Lücking 1969). We have refined and extended this observation with both naive and practiced subjects, finding results which contradict all of the current theories about the mechanism of stabilization of the visual world and suggest that cognitive factors in perception important influences on the stabilization process. Using this method with a paired photocell system to detect horizontal eye movements, some subjects saw a prominent object in the display jump slightly while the rest of the scene remained stable. The task was done first with landscape slides, then repeated with Escher prints where two sets of alternating figures completely filled the image. Subjects could concentrate on one set of forms as the "figure" and the other as the "ground", and reverse the two at will. In a majority of practiced subjects and in smaller proportion of naive subjects, motion of part of the "figure" was seen regardless of which alternative set of forms constituted it. Reversibility of the effect controlled for influence of object size, brightness, etc. in inducing the selective jump. These and related observations show that cognitive or attentional variables are as important as image properties or gain alone in determining subjective stabilization of the visual world, though current theories (inflow, outflow, cancellation, etc.) consider image position to be simple variable. Another experiment showed that image movement on the retina during saccades cannot explain saccadic suppression of displacement.

Kaolinite and Silica Dispersions in Low-Salinity Environments: Impact on a Water-in-Crude Oil Emulsion Stability

Directory of Open Access Journals (Sweden)

Vladimir Alvarado

2011-10-01

Full Text Available This research aims at providing evidence of particle suspension contributions to emulsion stability, which has been cited as a contributing factor in crude oil recovery by low-salinity waterflooding. Kaolinite and silica particle dispersions were characterized as functions of brine salinity. A reference aqueous phase, representing reservoir brine, was used and then diluted with distilled water to obtain brines at 10 and 100 times lower Total Dissolved Solid (TDS. Scanning Electron Microscope (SEM and X-ray Diffraction (XRD were used to examine at the morphology and composition of clays. The zeta potential and particle size distribution were also measured. Emulsions were prepared by mixing a crude oil with brine, with and without dispersed particles to investigate emulsion stability. The clay zeta potential as a function of pH was used to investigate the effect of particle charge on emulsion stability. The stability was determined through bottle tests and optical microscopy. Results show that both kaolinite and silica promote emulsion stability. Also, kaolinite, roughly 1 mm in size, stabilizes emulsions better than larger clay particles. Silica particles of larger size (5 µm yielded more stable emulsions than smaller silica particles do. Test results show that clay particles with zero point of charge (ZPC at low pH become less effective at stabilizing emulsions, while silica stabilizes emulsions better at ZPC. These result shed light on emulsion stabilization in low-salinity waterflooding.

Guatemala: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that government officials have been working on changes to the hydrocarbon law to make it easier for operators to explore. In a reform effort, Minister of Energy and Mines Carlos Hutarte brought a new staff dedicated to spurring oil development into office with him. This includes the Directorate of Hydrocarbons, which held a three-day seminar in Dallas, Texas, to acquaint U.S. firms with new policies. Only one company, Basic Resources International, has been operating in Guatemala over the last year. The firm drilled three onshore wells in 1990 for 16,499 ft, including one oil producer. Two further onshore wells are slated this year. Oil production from 14 active wells out of 16 capable averaged 3,943 bpd, up 8.4% from 1989. Reserves are 191 MMbbl

HOW PROPERTIES OF EDIBLE OILS ARE IMPROVED BY ESSENTIAL OILS

Directory of Open Access Journals (Sweden)

SONIA AMARIEI

2016-10-01

Full Text Available The main aim of the present paper is to find out whether the addition of essential oils determines better oxidation stability and positive change of sensory and hedonic perception of edible oils. The oxidation stability of sunflower, corn and grape seed oils was analyzed in the presence of antioxidants in essential oils of rosemary (Rosmarinus officinalis, thyme (Thymus vulgaris and basil (Ocimum basilicum during storage, under conditions of accelerated oxidative processes (4 days, at 60 °C. The total phenolic compounds of these essential oils were determined by the Folin-Ciocalteu method. The DPPH method was used to evaluate the antioxidant capacity of basil, rosemary and thyme essential oils in comparison with known synthetic antioxidant L(+-ascorbic acid. The addition of essential oils to edible oils, the amounts proposed in analyses, determines a favorable influence on their oxidation stability as well as their taste. The influence of addition of essential oils on the taste of edible oils was studied in two products consumed mainly at breakfast, bread and spinach leaves. The results recommend the use of these plant extracts as additives in edible oils rather than synthetic antioxidants.

Organizing the collection and automated processing of information about oil pollution of the world's oceans

Energy Technology Data Exchange (ETDEWEB)

Mikhaylov, V.A.; Surago, A.V.

1983-01-01

A system is examined for collecting, testing, storing and processing of data about pollution of the world's ocean by oil within the MOK-VMO test project on a computer (EVM). Forms for recording the results of observations and analysis in the form of an observation log for each form of oil pollution are cited. A description is given of the operation of the system.

Giant Oil Fields - The Highway to Oil: Giant Oil Fields and their Importance for Future Oil Production

International Nuclear Information System (INIS)

Robelius, Fredrik

2007-01-01

Since the 1950s, oil has been the dominant source of energy in the world. The cheap supply of oil has been the engine for economic growth in the western world. Since future oil demand is expected to increase, the question to what extent future production will be available is important. The belief in a soon peak production of oil is fueled by increasing oil prices. However, the reliability of the oil price as a single parameter can be questioned, as earlier times of high prices have occurred without having anything to do with a lack of oil. Instead, giant oil fields, the largest oil fields in the world, can be used as a parameter. A giant oil field contains at least 500 million barrels of recoverable oil. Only 507, or 1 % of the total number of fields, are giants. Their contribution is striking: over 60 % of the 2005 production and about 65 % of the global ultimate recoverable reserve (URR). However, giant fields are something of the past since a majority of the largest giant fields are over 50 years old and the discovery trend of less giant fields with smaller volumes is clear. A large number of the largest giant fields are found in the countries surrounding the Persian Gulf. The domination of giant fields in global oil production confirms a concept where they govern future production. A model, based on past annual production and URR, has been developed to forecast future production from giant fields. The results, in combination with forecasts on new field developments, heavy oil and oil sand, are used to predict future oil production. In all scenarios, peak oil occurs at about the same time as the giant fields peak. The worst-case scenario sees a peak in 2008 and the best-case scenario, following a 1.4 % demand growth, peaks in 2018

Prospects for world oil supply

International Nuclear Information System (INIS)

Esser, R.W.

1991-01-01

Surprises lie ahead for world oil supplies, which are expected to increase rapidly throughout the 1990s before leveling off by the end of the century. The extent of this increase could be the major surprise of the decade. Large increases in the capacity in Gulf countries accompanied by smaller increases in the non-Middle East OPEC countries will be augmented by a gradual increase in non-OPEC capacity into the late 1990s. By 2000, declining capacity in the latter two areas will offset continued capacity increases in the Gulf countries. Overall capacity in the non-OPEC countries (excluding China, Eastern Europe, and the Soviet Union), is expected to increase by 1.1 million BOPD from the low point in the early 1990s to a mid 1990s peak. The increase will be led by a large increase in capacity from the United Kingdom and smaller contributions from the non-Middle East OPEC countries and Mexico. In the forecast, emphasis has been placed on a detailed evaluation of recent significant discoveries made in non-OPEC countries and non-Middle East OPEC countries since 1983, which when taken together, are expected to add 8 million BOPD new capacity as soon as 1995. These discoveries have taken place in both existing and evolving exploration hotspots that are expected to receive increasing industry emphasis in the 1990s

Value of Canadian oil sands... to the United States

International Nuclear Information System (INIS)

Pugliaresi, Lucian

2011-01-01

Since the beginning of the recession in late 2007, the American economy has been subject to great change, affecting the way energy is produced and consumed. The structure of oil imports and exports has changed significantly and U.S. imports are now primarily from Canada. The current study shows how and why the U.S. has become dependent on imports of oil from the Canadian oil sands. Oil from Canadian oil sands is transported to different Petroleum Administration for Defense Districts (PADD) via the Keystone pipeline. As imports from Canada increased, the U.S. refinery sector was restructured. Small refineries were closed while larger refineries were expanded and investment was made to increase their processing capacity. The increased import and processing of oil from the Canadian oil sands led to an advantageous decrease in oil prices. If the Keystone XL project were to be approved, the pipeline would increase the area with access to the means of transporting oil, allowing the increasing demand for oil to be met and, potentially, stabilizing world oil prices.

World commitment to reduce carbon dioxide emissions

International Nuclear Information System (INIS)

Burge, R.

1991-01-01

A meeting of energy experts in Toronto, sponsored by the Canadian World Energy Council (CANWEC), to examine the implications of sustainable development for the energy industry, is reported. Canada, according to the World Resources Institute, ranks second only to the Arab oil producers as the world's worst energy hog. Although it contributes only 2% of total world greenhouse gases, its per capita emissions rank higher than even the United States, and this despite the fact that over 75% of its electrical energy is produced by hydro and nuclear power. Its intentions to stabilize CO 2 emissions by 2000 have already been signalled. Although arguments on the supply side strategies of clean coal and nuclear power were presented at the CANWEC meeting, the accent was firmly on demand side management, through energy conservation and efficiency, to meet the challenge of global warming. (author)

World oil market fundamentals - Part One: The near term outlook

International Nuclear Information System (INIS)

Dwarkin, J.; Morton, K.; Datta, R.

1998-03-01

Potential implications of a number of uncertainties currently affecting the world oil market are assessed. The influence of the interplay of geopolitical events on demand and supply, inventories, prices and price trends are reviewed. Reference prices which industry and governments can use for investment and policy evaluations are provided. In this volume, the emphasis is on near term developments, with a review of the uncertainties surrounding these projections. Three different scenarios are postulated for the near term, each one taking into account different levels of Iraqi exports during the period which would effect available inventories, and hence price. Depending on which of the three scenarios actually comes to pass, unless refiners are prepared to build up inventories well beyond seasonal norms, or producers shut in, the prevailing view is that oil prices will be under severe pressure during most of 1998 and 1999. Over the longer term, however, the analysis suggests that an average real value of US$18.00 - $18.50 per barrel remains a reasonable expectation as a sustainable price. 34 refs., tabs., figs

Malaysia: World Oil Report 1991

International Nuclear Information System (INIS)

Khin, J.A.

1991-01-01

This paper reports that the Malaysian government announced tax incentives for fiscal year 1991/92 by cutting export duties on crude oil to encourage companies to develop more oil fields. The export duty exemption on cost recovery oil was increased from the current 20% to 50% on April 1, 1991. Nearly 115,200 sq mi of shallow-water acreage off Malaysia has been awarded to PS contractors, leaving only about five blocks remaining. Therefore, Petronas plans to award deeper water blocks (water depths of 655 ft or more) in the second half of this year, once terms are finalized. It is understood that these areas will be offshore of Sarawak and Sabah, covering in excess of 38,000 sq mi. Petronas the that there would be some improvement in the PSC terms for the deep-water areas

Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing

Energy Technology Data Exchange (ETDEWEB)

Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B.; Burton, Sarah D.; Job, Heather M.; Lemmon, Teresa L.; Swita, Marie S.; Rotness, Leslie J.; Neuenschwander, Gary N.; Frye, John G.; Elliott, Douglas C.

2015-10-15

The use of fast pyrolysis as a potential renewable liquid transportation fuel alternative to crude oil depends on successful catalytic upgrading to produce a refinery-ready product with oxygen content and qualities (i.e. specific functional group or compound content) that is compatible with the product’s proposed insertion point. Catalytic upgrading of bio-oil requires high temperature and pressure, while similar to crude oil hydrotreating, is not as straightforward for the thermally unstable pyrolysis oil. For years, a two-temperature zone, downflow trickle bed reactor was the state-of-the art for continuous operation. However, pressure excursion due to plug formation still occurred, typically at the high temperature transition zone, leading to a process shutdown within 140 h. Recently, a bio-oil pre-treatment process, together with a robust commercial catalyst, was found to be enabling the continuous operation of the two-zone hydroprocessing system. Here, we report the results on pre-treating bio-oil at 413 K and 8.4 MPa of flowing H2 (500 L H2/L bio-oil, 0.5 L bio-oil/L catalyst bed) and the attempts to characterize this oil product to understand the chemistry which enabled the long-term processing of bio-oil.

Influence of the Rancimat parameters on the determination of oxidative stability index of Sesamum Indicum L. Oil

Directory of Open Access Journals (Sweden)

Eudes Villanueva López

2013-09-01

Full Text Available The objective of this research was to determine the oxidative stability index (OSI in virgin oil seed Sesamum indicum L. (Sesame previously extracted by cold pressing, clarified by centrifugation and stored under nitrogen atmosphere and cooling on. The OSI was determined by accelerated Rancimat test, it was used for 3.0 ± 0.1 g of sample temperature parameters (110, 130 and 150 °C and air flow (15, 20 and 25 L/h. Applying the Rancimat test, it was found by ANOVA (p < 0.05 that the influence of temperature on the OSI was highly significant, whereas the only air flow was significant. By extrapolation method, values were calculated at usual temperatures OSI oil storage (25 °C to give stability times 214, 242 and 222 days, also the activation energy of the oxidation reaction of sesame oil for different air flows, is 97.28, 98.79 and 96.86 kJ / mol for 15, 20 and 25 L/h respectively.

Effect of spray-drying with organic solvents on the encapsulation, release and stability of fish oil.

Science.gov (United States)

Encina, Cristian; Márquez-Ruiz, Gloria; Holgado, Francisca; Giménez, Begoña; Vergara, Cristina; Robert, Paz

2018-10-15

Fish-oil (FO) was encapsulated with hydroxypropylcelullose (HPC) by conventional spray-drying with water (FO-water) and solvent spray-drying with ethanol (FO-EtOH), methanol (FO-MeOH) and acetone (FO-Acet) in order to study the effect of the solvent on the encapsulation efficiency (EE), microparticle properties and stability of FO during storage at 40 °C. Results showed that FO-Acet presented the highest EE of FO (92.0%), followed by FO-EtOH (80.4%), FO-MeOH (75.0%) and FO-water (71.1%). A decrease of the dielectric constant increased the EE of FO, promoting triglyceride-polymer interactions instead of oil-in-water emulsion retention. FO release profile in aqueous model was similar for all FO-microparticles, releasing only the surface FO, according to Higuchi model. Oxidative stability of FO significantly improved by spray-drying with MeOH, both in surface and encapsulated oil fractions. In conclusion, encapsulation of FO by solvent spray-drying can be proposed as an alternative technology for encapsulation of hydrophobic molecules. Copyright © 2018 Elsevier Ltd. All rights reserved.

Effect of high hydrostatic pressure and high dynamic pressure on stability and rheological properties of model oil-in-water emulsions

Science.gov (United States)

Bigikocin, Erman; Mert, Behic; Alpas, Hami

2011-09-01

Both static and dynamic high pressure applications provide interesting modifications in food structures which lead to new product formulations. In this study, the effects of two different treatments, high hydrostatic pressure (HHP) and high dynamic pressure (HDP), on oil-in-water emulsions were identified and compared. Microfluidization was selected from among the HDP homogenization techniques. The performance of each process was analyzed in terms of rheological modifications and emulsion stability improvements compared with the coarse emulsions. The stability of the emulsions was determined comparatively by using an analytical photo-centrifuge device employing novel analysis technology. Whey protein isolate (WPI) in combination with a food polysaccharide (xanthan gum, guar gum or locust bean gum) were used as emulsifying and stabilizing ingredients. The effective disruption of oil droplets and the degradation of polysaccharides by the shear forces under high pressure in HDP microfluidization yielded finer emulsions with lower viscosities, leading to distinctive improvements in emulsion stability. On the other hand, improvements in stability obtained with HHP treatment were due to the thickening of the emulsions mainly induced by protein unfolding. The corresponding increases in viscosity were intensified in emulsion formulations containing higher oil content. Apart from these, HHP treatment was found to be relatively more contributive to the enhancements in viscoelastic properties.

Natural and synthetic antioxidants: Influence on the oxidative stability of biodiesel synthesized from non-edible oil

Energy Technology Data Exchange (ETDEWEB)

Sarin, Amit [Department of Applied Sciences, Amritsar College of Engineering and Technology, Manawala, Amritsar-143001, Punjab (India); Singh, N.P. [Punjab Technical University, Jalandhar (India); Sarin, Rakesh; Malhotra, R.K. [Indian Oil Corporation Ltd., R and D Centre, Sector-13, Faridabad-121007 (India)

2010-12-15

According to the proposed National Mission on Biodiesel in India, we have undertaken studies on the oxidative stability of biodiesel synthesized from tree borne non-edible oil seeds jatropha. Neat jatropha biodiesel exhibited oxidation stability of 3.95 h and research was conducted to investigate the influence of natural and synthetic antioxidants on the oxidation stability of jatropha methyl ester. Antioxidants namely {alpha}-tocopherol, tert-butylated hydroxytoluene, tert-butylated phenol derivative, octylated butylated diphenyl amine, and tert-butylhydroxquinone were doped to improve the oxidation stability. It was found that both types of antioxidants showed beneficial effects in increasing the oxidation stability of jatropha methyl ester, but comparatively, the synthetic antioxidants were found to be more effective. (author)

Structure-activity relationships between sterols and their thermal stability in oil matrix.

Science.gov (United States)

Hu, Yinzhou; Xu, Junli; Huang, Weisu; Zhao, Yajing; Li, Maiquan; Wang, Mengmeng; Zheng, Lufei; Lu, Baiyi

2018-08-30

Structure-activity relationships between 20 sterols and their thermal stabilities were studied in a model oil system. All sterol degradations were found to be consistent with a first-order kinetic model with determination of coefficient (R 2 ) higher than 0.9444. The number of double bonds in the sterol structure was negatively correlated with the thermal stability of sterol, whereas the length of the branch chain was positively correlated with the thermal stability of sterol. A quantitative structure-activity relationship (QSAR) model to predict thermal stability of sterol was developed by using partial least squares regression (PLSR) combined with genetic algorithm (GA). A regression model was built with R 2 of 0.806. Almost all sterol degradation constants can be predicted accurately with R 2 of cross-validation equals to 0.680. Four important variables were selected in optimal QSAR model and the selected variables were observed to be related with information indices, RDF descriptors, and 3D-MoRSE descriptors. Copyright © 2018 Elsevier Ltd. All rights reserved.

Drewry: Mideast in firm control of world oil supplies for 1990s

International Nuclear Information System (INIS)

Anon.

1993-01-01

Surging economic growth in the Far East will push up world crude oil demand steadily in the 1990s despite the current economic downturn. It will fall to members of the Organization of Petroleum Exporting Countries to meet that increased demand, given the expected decline in non-OPEC production. And because OPEC members in the Persian Gulf region are best positioned to meet the increase, the balance of power in oil markets will shift even more in favor of the Middle East. Seaborne oil exports from the Middle East will jump almost 30% by 1997 from 1991 levels. There will be a worldwide rise of 16% in the volume of seaborne crude oil trade, with a 29% hike in movements of refined products by tanker. Those are among the findings of a report by Drewry Shipping Consultants Ltd., London. Drewry said, It is expected that 1992 will be a low point in non-OPEC output and that production levels will recover steadily from 1993 onward, although not rapidly enough to match the anticipated rise in demand. Drewry estimates non-OPEC production in 1997 at 37.1 million b/d vs. 38.1 million b/d in 1991. With non-OPEC production falling by 2.6% between 1991 and 1997, OPEC producers will have the scope to increase their output by almost 32% over the same period

Panama: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that Texaco signed a contract to explore 1.1 million acres in Blocks 1 and 2, on and offshore the northwestern coast. The firm has not revealed any plans beyond conducting a preliminary analysis. No drilling was reported last year. Switzerland-based Idria Oil and Gas, which drilled and abandoned three offshore wells with oil and gas shows in 1989, the it has no plans for 1991. However, the firm the it may drill three wells in 1992

Seychelles: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports on the small island group that was host to the first Indian Ocean Regional Seminar on Petroleum Exploration in mid-December. Efforts are under way to set up a regional system for cooperation in petroleum between countries in the region that hope to become oil producers. Offshore permits are held by Enterprise Oil and recently by Texaco. Ultamar Exploration Ltd. signed an eight-year offshore exploration contract becoming only the fourth company to attempt exploration off the archipelago

Brazil: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that Brazil's state oil company Petrobras has racked up a significant period of achievement over the last 12 months. Average daily oil production hit a new high. A small portion of deepwater giant Marlim field came onstream. Risk contracts ended, and the firm assumed all responsibility for exploration activity in Brazil. Furthermore, Santos basin proved to be the nation's most recent oil province after two discoveries. Last, but not least, Petrobras assumed a dominant position worldwide in development of new deepwater technology, as evidenced by papers presented at the 1991 Offshore Technology Conference. What is remarkable is that all this was achieved while the company was experiencing political turmoil. Last Oct. 19, Petrobras President Luis Octavio Motta Veiga resigned in a dispute with the Ministry of Economy (MOE) over refined product pricing levels. His replacement, interestingly enough, was the 36-year-old executive secretary of the MOE, Eduardo de Freitas Teixeira. His term at Petrobras lasted less than six months

Rheological behavior of water-in-oil emulsions stabilized by hydrophobic bentonite particles.

Science.gov (United States)

Binks, Bernard P; Clint, John H; Whitby, Catherine P

2005-06-07

A study of the rheological behavior of water-in-oil emulsions stabilized by hydrophobic bentonite particles is described. Concentrated emulsions were prepared and diluted at constant particle concentration to investigate the effect of drop volume fraction on the viscosity and viscoelastic response of the emulsions. The influence of the structure of the hydrophobic clay particles in the oil has also been studied by using oils in which the clay swells to very different extents. Emulsions prepared from isopropyl myristate, in which the particles do not swell, are increasingly flocculated as the drop volume fraction increases and the viscosity of the emulsions increases accordingly. The concentrated emulsions are viscoelastic and the elastic storage and viscous loss moduli also increase with increasing drop volume fraction. Emulsions prepared from toluene, in which the clay particles swell to form tactoids, are highly structured due to the formation of an integrated network of clay tactoids and drops, and the moduli of the emulsions are significantly larger than those of the emulsions prepared from isopropyl myristate.

Stabilization of azadirachtin A in neem formulations: effect of some solid carriers, neem oil, and stabilizers.

Science.gov (United States)

Kumar, J; Parmar, B S

1999-04-01

Formulation of azadirachtin A on attapulgite, kaolinite, fuller's earth, hydrated calcium silicate, and fly ash revealed that it degraded to the tune of 70-95% on different solid carriers as compared to 56% in neem oil, during the 14 day heat storage studies at 54 +/- 1 degrees C in the laboratory. The degradation was reduced by 26-60% on different carriers by employing either anthraquinone or epichlorohydrin as stabilizer. Pyrogallol and hydroquinone enhanced the degradation. The cation exchange capacity and surface area of the carriers revealed a significant negative correlation with t(1/2) of azadirachtin A.

The comparative efficacy of stabilized stannous fluoride dentifrice, peroxide/baking soda dentifrice and essential oil mouthrinse for the prevention of gingivitis.

Science.gov (United States)

Beiswanger, B B; McClanahan, S F; Bartizek, R D; Lanzalaco, A C; Bacca, L A; White, D J

1997-01-01

This double-blind parallel-design clinical study compared the efficacy of a stabilized stannous fluoride dentifrice (Crest Plus Gum Care), baking soda and peroxide (NaF) dentifrice (Mentadent), and essential oil mouthrinse (Listerine) to a conventional NaF dentifrice (Crest) for the control of plaque, gingivitis and gingival bleeding over six months. Following an initial baseline examination and stratification, subjects received a complete oral prophylaxis and were distributed assigned test products. Following three and six months, subjects re-visited the clinic for examinations. Evaluations at baseline and at 3 and 6 months included soft tissue status. Löe-Silness gingivitis/gingival bleeding, Silness-Löe plaque and dental stain. Results subsequent to six months of product use were as follows: At six months, the stabilized stannous fluoride dentifrice was observed to produce statistically significant 17.5% reductions in gingivitis and 27.5% reductions in gingival bleeding relative to the NaF dentifrice. The combination of sodium fluoride dentifrice and essential oil mouthrinse produced statistically significant reductions of 7.4% in gingivitis and 10.8% in plaque as compared with the NaF dentifrice. The stabilized stannous fluoride dentifrice produced statistically significant reductions in both gingivitis (10.8%) and gingival bleeding (23.0%) relative to the combination of sodium fluoride dentifrice and essential oil mouthrinse. The baking soda and peroxide (NaF) dentifrice did not provide reductions in gingivitis, plaque or gingival bleeding as compared with the conventional NaF dentifrice. The stabilized stannous fluoride dentifrice provided statistically significant reductions in gingivitis as compared with the baking soda and peroxide dentifrice following six months of use, and both the essential oil mouthrinse and stabilized stannous fluoride dentifrice provided statistically significant reductions in gingivitis as compared with the baking soda and

Long storage stability of biodiesel from vegetable and used frying oils

Energy Technology Data Exchange (ETDEWEB)

Abderrahim Bouaid; Mercedes Martinez; Jose Aracil [Complutense University, Madrid (Spain). Department of Chemical Engineering

2007-11-15

Biodiesel is defined as the mono-alkyl esters of vegetable oils. Production of biodiesel has grown tremendously in European Union in the last years. Though the commercial prospects for biodiesel have also grown, there remains some concern with respect to its resistance to oxidative degradation during storage. Due to the chemical structure of biodiesel the presence of the double bond in the molecule produce a high level of reactivity with the oxygen, especially when it placed in contact with air. Consequently, storage of biodiesel over extended periods may lead to degradation of fuel properties that can compromise fuel quality. This study used samples of biodiesel prepared by the process of transesterification from different vegetable oils: high oleic sunflower oil (HOSO), high and low erucic Brassica carinata oil (HEBO and LEBO) respectively and used frying oil (UFO). These biodiesels, produced from different sources, were used to determine the effects of long storage under different conditions on oxidation stability. Samples were stored in white (exposed) and amber (not exposed) glass containers at room temperature. The study was conducted for a period of 30-months. At regular intervals, samples were taken to measure the following physicochemical quality parameters: acid value (AV), peroxide value (PV), viscosity {nu}, iodine value (IV) and insoluble impurities (II). Results showed that AV, PV, {nu} and II increased, while IV decreased with increasing storage time of biodiesel samples. However, slight differences were found between biodiesel samples exposed and not exposed to daylight before a storage time of 12 months. But after this period the differences were significant. 22 refs., 5 figs., 3 tabs.

A look at one of the world`s largest apron feeder drives - Alberta Oil Sands Project

Energy Technology Data Exchange (ETDEWEB)

Persson, O. [Hagglunds Drives Canada Inc., Vancouver, BC (Canada)

1999-10-01

Various types of equipment to transport tar sands to processing plants are discussed, with special attention to the advantages of hydraulic direct drives over conventional electro-mechanical drives. A hydraulic direct drive such as the Hagglund Drive has exceptional starting torque capacity due to the high torque capability of the hydraulic motor. As such, it can be particularly useful in applications where shock loads occur with some frequency, or where many starts and stops are needed. Application of the Hagglund drive to power one of the world`s largest apron feeders in the Alberta Oil Sands is described as an illustration of the exceptional reliability, productivity and performance of this equipment. It has about one five-hundredth of the inertia of an equivalent high speed drive with gear reducer, a feature which is particularly significant in the case of feeders which are known to suffer much downtime due to chain related problems. These types of drives have also been used to great advantage in the process industries like pulp and paper, chemical, rubber and plastics, recycling and steel. 1 tab., 1 fig.

Transglutaminase catalyzed cross-linking of sodium caseinate improves oxidative stability of flaxseed oil emulsion.

Science.gov (United States)

Ma, Hairan; Forssell, Pirkko; Kylli, Petri; Lampi, Anna-Maija; Buchert, Johanna; Boer, Harry; Partanen, Riitta

2012-06-20

Sodium caseinate was modified by transglutaminase catalyzed cross-linking reaction prior to the emulsification process in order to study the effect of cross-linking on the oxidative stability of protein stabilized emulsions. The extent of the cross-linking catalyzed by different dosages of transglutaminase was investigated by following the ammonia production during the reaction and using SDS-PAGE gel. O/W emulsions prepared with the cross-linked and non-cross-linked sodium caseinates were stored for 30 days under the same conditions. Peroxide value measurement, oxygen consumption measurement, and headspace gas chromatography analysis were used to study the oxidative stability of the emulsions. The emulsion made of the cross-linked sodium caseinate showed an improved oxidative stability with reduced formation of fatty acid hydroperoxides and volatiles and a longer period of low rate oxygen consumption. The improving effect of transglutaminase catalyzed cross-linking could be most likely attributed to the enhanced physical stability of the interfacial protein layer against competitive adsorption by oil oxidation products.

Tunisia: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports on more attractive E and P terms, and the Abiod Chalk oil play which means busier exploration in Tunisia. E and P agreement terms and conditions have been liberalized in the face of declining oil and gas production, thus encouraging development of smaller, previously marginal prospects. Ownership and acreage changes may have significant impact in the next few years as Texaco, under a farm-in, has acquired 60% and operatorship of Conquest Exploration's El Jem onshore block and Samedan acquired large acreage interests from Royal Dutch Shell

CHEMICAL STABILITY OF COTTONSEED AND GROUNDNUT OIL USED FOR FRYING BHAJIAS AND ITS SENSORY QUALITIES

Directory of Open Access Journals (Sweden)

Ashima Gupta

2014-12-01

Full Text Available Deep fried snacks, which evolved as snacks between meals include bhajia, samosa, etc are very popular in India and commercially exploited on a wide scale.Cottonseed and Groundnut oil frequently used in Gujarat for cooking purpose studied for its intermittent frying stability. Indian fried snack popularly known as ‘Bhajia’ fried for 5 min at an interval of 1 h; 5 times a day for 5 consecutive days and studied for its various sensory attributes using 9-point hedonic scale. Standard AOCS and AOAC methods were used to determine the quality of oil. Peroxide and p-anisidine values of both oils increased significantly p<0.001 during the 25 h of intermittent frying. Iodine value of cottonseed oil did not decrease throughout the intermittent frying period. Polar components increased 257.5% in cottonseed oil (CSO and 142.9% in groundnut oil (GNO.The saturated and monounsaturated fatty acid content increased significantly with the increase in frying hours.No significant change was seen in linoleic/palmitic acid ratio of both the oils during bhajias frying. The sensory qualities of bhajia fried at different intervals did not change significantly for various attributes namely flavor, taste, crispness, greasiness, odor, color, appearance and overall acceptability.

Oxidative stability of biodiesels produced from vegetable oils having different degrees of unsaturation

International Nuclear Information System (INIS)

Pantoja, Samantha Siqueira; Conceição, Leyvison Rafael V. da; Costa, Carlos E.F. da; Zamian, José R.; Rocha Filho, Geraldo N. da

2013-01-01

Highlights: • We obtained biodiesel from açai, cupuaçu, passion fruit and linseed oil. • Determined the properties of biodiesel, such as kinematic viscosity, cold filter plugging point and oxidative stability. • Evaluated the influence of antioxidants on biodiesel. • The PG antioxidant was more efficient than BHA and TBHQ for the açaí biodiesel. - Abstract: In the present paper, methyl esters were obtained from the transesterification of cupuaçu fat lipids (Theobroma grandiflorum) (Willd. ex Spreng.) (K. Schum.), açaí (Euterpe oleracea), passion fruit (Passiflora edulis) and linseed (Linum usitatissimum L.) oils, using a basic catalyst. The triglycerides were characterized by their fatty acid composition, and the biodiesels were characterized according to standard methods. The critical properties, such as the cold filter plugging point, kinematic viscosity and oxidative stability, of the biodiesels were studied. The influence of butyl-hydroxyanisole (BHA), propyl gallate (PG) and tert-butyl hydroquinone (TBHQ) antioxidants on the açaí, passion fruit and linseed biodiesels was evaluated at concentrations from 500 to 4000 ppm. PG was found to be the most efficient antioxidant for the studied biodiesels

Influence of the type of cellulosic derivatives on the texture, and oxidative and thermal stability of soybean oil oleogel

International Nuclear Information System (INIS)

Totosaus, A.; Gonzalez-Gonzalez, R.; Fragoso, M.

2016-01-01

The use oleogels (defined as edible oils entrapped in a three-dimensional network employing a self-assembled structuring agent) has recently been proposed to replace saturated fat or trans-fats in foods. In this work the effects of different cellulose derivative mixtures (Avicel, ethyl cellulose and a-cellulose) on lipid stability, glass transition temperature and the texture of soybean oil oleogels were determined by employing a mixture design approach. Avicel affected lipid stability, increasing the oxidative rancidity and peroxide values of oleogels. Oleogels with higher proportions of Avicel also presented higher transition temperatures. A higher percent of ethyl cellulose and a-cellulose in the oleogel mixture resulted in a more stable system with lower oil rancidity and lower glass transition temperatures. In addition, Avicel resulted in a softer and less tacky texture, an important characteristic to consider for food applications. [es

Peak Oil, threat or energy worlds' phantasm?

International Nuclear Information System (INIS)

Favennec, Jean-Pierre

2011-01-01

The concept of Peak Oil is based on the work of King Hubbert, a petroleum geologist who worked for Shell in the USA in the 1960's. Based on the fact that discoveries in America reached a maximum in the 1930's, he announced that American production would reach a maximum in 1969, which did actually occur. Geologists members of the Association for the Study of Peak Oil have extrapolated this result to a worldwide scale and, since oil discoveries reached a peak in the 1960's, argued that production will peak in the very near future. It is clear that hydrocarbon reserves are finite and therefore exhaustible. But little is known regarding the level of ultimate (i.e. total existing) reserves. There are probably very large reserves of non conventional oil in addition to the reserves of conventional oil. An increasing number of specialists put maximum production at less than 100 Mb/d more for geopolitical than physical reasons. Attainable peak production will probably vary from year to year and will depend on how crude oil prices develop

Where in the World are Canadian Oil and Gas Companies? 2011

Directory of Open Access Journals (Sweden)

Niloo Hojjati

2017-06-01

Full Text Available Canada is well recognized for its prominence as an oil and gas jurisdiction in regard to its resources within its own borders. However, there is little available analysis and information regarding the presence of Canadian companies in the international arena. Begun in 2011 as an internal research tool for the development of the Extractive Resource Governance Program, this project seeks to answer the vital question: Where in the world are Canadian oil and gas companies? To answer this question, firm-level data from publicly traded Canadian companies are collected and analyzed, culminating in the development of an online tool for public use. This map allows interested users to geographically locate jurisdictions around the world where publicly traded Canadian oil and gas (hereafter O&G companies have activities, over time. The map is available at http://www.policyschool.ca/ research-teaching/teaching-training/extractive-resource-governance/ergp-map/. This project, hereafter referred to as the WIW project, provides a measure that quantifies Canadian oil and gas activity around the world and identifies key jurisdictions that are of particular interest to Canadian O&G companies. The data collected holds value for various stakeholders such as governments, regulatory bodies, academia, civil society, and industry across the extractive resource spectrum. Prior to further discussion regarding the 2011 annual data results, it is valuable to provide a brief overview of the methodology used in the collection of data for this research project. The WIW project examines the global activities of Canadian O&G companies in 218 countries spanning seven international regions of analysis.1 The aim of the WIW project is to examine the international presence of Canadian companies in foreign countries. As such, it is important to note that this project does not provide information related to the activities of Canadian companies within Canada’s border, such as the

Stability of cardamom (Elettaria cardamomum) essential oil in microcapsules made of whey protein isolate, guar gum, and carrageenan.

Science.gov (United States)

Mehyar, Ghadeer F; Al-Ismail, Khalid M; Al-Isamil, Khalid M; Al-Ghizzawi, Hana'a M; Holley, Richard A

2014-10-01

The effects of microencapsulating cardamom essential oil (CEO) in whey protein isolate (WPI) alone and combined with guar gum (GG) and carrageen (CG) on microencapsulation efficiency, oil chemical stability, and microcapsule structure were investigated. Freeze-dried microcapsules were prepared from emulsions containing (w/w): 15% and 30% WPI; 0.1% GG, and 0.2% CG as wall materials with CEO (at 10% of polymer concentration) as core material, and physical properties and chemical stability were compared. Bulk density of microcapsules was highest in WPI without GG or CG and in 30% WPI + GG microcapsules, and was more affected by moisture content (r = -0.6) than by mean particle diameter (d43 ; r = -0.2) and span (r = 0.1). Microcapsules containing only WPI had the highest entrapped oil (7.5%) and microencapsulation efficiency (98.5%). The concentrations of 1,8-cineole and d-limonene were used as indicators for microcapsule chemical stability since they were the main components of CEO. Microcapsules retained higher (P ≤ 0.05) concentrations of both components than non-microencapsulated CEO during 16 wk storage at 20 ºC, but higher loss of both components was noted at 35 ºC. Microencapsulated d-limonene was reduced faster than 1,8-cineole regardless of temperature. The 30% WPI and 30% WPI + GG microcapsules retained CEO best throughout storage at both storage temperatures. Scanning electron micrographs revealed that WPI microcapsules had smooth surfaces, were relatively homogenous and regular in shape, whereas GG and CG addition increased visual surface porosity and reduced shape regularity. It was concluded that the best formulation for encapsulating CEO was 30% WPI. Encapsulating cardamom essential oil in whey protein isolate alone or combined with guar gum produced dried powders that effectively retained and chemically stabilized CEO, and therefore enhanced its handling and storability. © 2014 Institute of Food Technologists®

Changing patterns in world oil supplies

Energy Technology Data Exchange (ETDEWEB)

Khane, A R; Bischoff, G

1979-03-01

The aim of the oil countries to industrialize in as short a period as possible is discussed in a dialogue with Dr. Khane. The topics of the oil price rises, the price rises for industrial plant, worldwide unemployment, the standard of living and the excess capacities in industrial countries are also discussed.

Factors affecting emulsion stability and quality of oil recovered from enzyme-assisted aqueous extraction of soybeans.

Science.gov (United States)

Jung, S; Maurer, D; Johnson, L A

2009-11-01

The objectives of the present study were to assess how the stability of the emulsion recovered from aqueous extraction processing of soybeans was affected by characteristics of the starting material and extraction and demulsification conditions. Adding endopeptidase Protex 6L during enzyme-assisted aqueous extraction processing (EAEP) of extruded soybean flakes was vital to obtaining emulsions that were easily demulsified with enzymes. Adding salt (up to 1.5 mM NaCl or MgCl(2)) during extraction and storing extruded flakes before extraction at 4 and 30 degrees C for up to 3 months did not affect the stabilities of emulsions recovered from EAEP of soy flour, flakes and extruded flakes. After demulsification, highest free oil yield was obtained with EAEP of extruded flakes, followed by flour and then flakes. The same protease used for the extraction step was used to demulsify the EAEP cream emulsion from extruded full-fat soy flakes at concentrations ranging from 0.03% to 2.50% w/w, incubation times ranging from 2 to 90 min, and temperatures of 25, 50 or 65 degrees C. Highest free oil recoveries were achieved at high enzyme concentrations, mild temperatures, and short incubation times. Both the nature of enzyme (i.e., protease and phospholipase), added alone or as a cocktail, concentration of enzymes (0.5% vs. 2.5%) and incubation time (1 vs. 3 h), use during the extraction step, and nature of enzyme added for demulsifying affected free oil yield. The free oil recovered from EAEP of extruded flakes contained less phosphorus compared with conventional hexane-extracted oil. The present study identified conditions rendering the emulsion less stable, which is critical to increasing free oil yield recovered during EAEP of soybeans, an environmentally friendly alternative processing method to hexane extraction.

Evaluation of the oxidative stability of Chipotle chili (Capsicum annuum L. oleoresins in avocado oil

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L. Cerecedo-Cruz

2018-03-01

Full Text Available Capsicum annuum L. (Chipotle chili is a natural source of bioactive metabolites with antioxidant properties. The objective of this research was to obtain and characterize the oxidative stability under storage of Chipotle chili oleoresins extracted with cold-pressed avocado oil. The most efficient conditions obtained to extract carotenoids and phenolic compounds were at 1:3 ratio (chipotle chili: avocado oil; w:v at room temperature in darkness during 48 h. At the end of the harshest conditions (45 °C, 30 days, the extracts were stable to lipid oxidation with a final Totox value of 27.34, a carotenoid preservation of 85.6%, antioxidant activity retention of 80.66% and a color change (ΔE of 1.783. The kinetic constants obtained were higher for peroxide formation than for carotenoid degradation. The oleoresins obtained could be considered an economic and sustainable alternative to extract carotenoids with good oxidation stability that could be used in foodstuffs.

Preparation of Essential Oil-Based Microemulsions for Improving the Solubility, pH Stability, Photostability, and Skin Permeation of Quercetin.

Science.gov (United States)

Lv, Xia; Liu, Tiantian; Ma, Huipeng; Tian, Yan; Li, Lei; Li, Zhen; Gao, Meng; Zhang, Jianbin; Tang, Zeyao

2017-11-01

Quercetin can bring many benefits to skin based on its various bioactivities. However, the therapeutic effect of quercetin is limited due to the poor water solubility, pH instability, light instability, and skin permeation. The aim of the present work was applying essential oil-based microemulsions to improve the solubility, pH stability, photostability, and skin permeation of quercetin for topical application. Peppermint oil (PO-ME), clove oil (CO-ME), and rosemary oil (RMO-ME) were selected as model essential oils. Microemulsions composed of Cremophor EL/1,2-propanediol/essential oils (47:23:30, w/w) were selected as model formulations, based on the pseudo-ternary phase diagram and the characterizations. In the solubility study, the solubility of quercetin was improved dozens of times by microemulsions. Quercetin was found instable under alkaline condition, with 50% degraded in the solution of pH 13. However, PO-ME, CO-ME, and RMO-ME could protect quercetin from the hydroxide ions, with 47, 9, and 12% of quercetin degraded. In the photostability study, the essential oil-based microemulsions showed the capability of protecting quercetin from degradation under UV radiation. Where more than 67% of quercetin was degraded in aqueous solution, while less than 7% of quercetin degraded in microemulsions. At last, the in vitro skin permeation study showed that the essential oil-based microemulsions could enhance the permeation capacity of quercetin by 2.5-3 times compared to the aqueous solution. Hence, the prepared essential oil microemulsions could improve the solubility, pH stability, photostability, and skin permeation of quercetin, which will be beneficial for its topical application.

Microencapsulation of borage oil with blends of milk protein, β-glucan and maltodextrin through spray drying: physicochemical characteristics and stability of the microcapsules.

Science.gov (United States)

Li, Ru-Yi; Shi, Yan

2018-02-01

Borage oil is a rich commercial source of γ-linolenic acid (18:3n-6). However, borage oil is rich in omega-6 polyunsaturated fatty acids and vulnerable to oxidation. Thus, selecting appropriate wall materials is critical to the encapsulation of borage oil. The present study investigated the influence of wall materials on the physicochemical characteristics and stability of microencapsulated borage oil by spray drying. Blends of milk protein [sodium caseinate (CAS) or whey protein concentrate], β-glucan (GLU) and maltodextrin (MD) were used as the wall materials for encapsulating borage oil. The microencapsulation of borage oil with different wall materials attained high encapsulation efficiencies. The microencapsulated borage oil prepared with CAS-MD achieved the optimal encapsulation efficiency of 96.62%. The oxidative stabilities of borage oil and microencapsulated borage oil were measured by accelerated storage test at 45 °C and 33% relative humidity for 30 days. The microencapsulated borage oil presented lower peroxide values than those of borage oil, and the microcapsules prepared with CAS-10GLU-MD (consisting of CAS 50 g kg -1 , GLU 100 g kg -1 and MD 475 g kg -1 of microencapsulation) conferred borage oil with high protection against lipid oxidation. The results of the present study demonstrate that the CAS-GLU-MD blend is appropriate for microencapsulating borage oil. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Improvement of stability and carotenoids fraction of virgin olive oils by addition of microalgae Scenedesmus almeriensis extracts.

Science.gov (United States)

Limón, Piedad; Malheiro, Ricardo; Casal, Susana; Acién-Fernández, F Gabriel; Fernández-Sevilla, José M; Rodrigues, Nuno; Cruz, Rebeca; Bermejo, Ruperto; Pereira, José Alberto

2015-05-15

Humans are not capable of synthesizing carotenoids de novo and thus, their presence in human tissues is entirely of dietary origin. Consumption of essential carotenoids is reduced due to the lower intake of fruits and vegetables. Microalgae are a good source of carotenoids that can be exploited. In the present work, carotenoids rich extracts from Scenedesmus almeriensis were added to extra-virgin olive oils at different concentrations (0.1 and 0.21 mg/mL) in order to enhance the consumption of these bioactives. Extracts brought changes in olive oils color, turning them orange-reddish. Quality of olive oils was improved, since peroxidation was inhibited. Olive oils fatty acids and tocopherols were not affected. β-carotene and lutein contents increase considerably, as well as oxidative stability, improving olive oils shelf-life and nutritional value. Inclusion of S. almeriensis extracts is a good strategy to improve and enhance the consumption of carotenoids, since olive oil consumption is increasing. Copyright © 2014 Elsevier Ltd. All rights reserved.

Adaptability and stability of canola hybrids in different sowing dates

Directory of Open Access Journals (Sweden)

Luiz Henrique da Silva Lima

Full Text Available ABSTRACT Canola is an important crop in the world market, mainly for its oil being used for human consumption and biodiesel production, being a great economical option for the farmer, which are the reasons to the increase in its cultivation in Brazil. This study aimed to evaluate the adaptability and stability of canola hybrids, depending on the sowing dates. The canola hybrids (Hyola 61, Hyola 76, Hyola 411 and Hyola 433 were evaluated in three sowing dates (04/10, 04/25 and 05/10 in the agricultural years of 2013 and 2014, under a randomized complete block design with five replications. The response variables analyzed were seed yield and oil content. Adaptability and stability of the hybrids were evaluated by three methods: Wricke's ecovalence (1962; confidence index (ANNICCHIARICO, 1992 and method of maximum ideal deviation (LIN; BINNS, 1988. The methodology proposed by Wricke (1962 highlighted as stable the hybrids Hyola 61 for seed yield and Hyola 411 for oil content. In the methodology proposed by Lin and Binns (1988 and Annicchiarico (1992, the hybrids with higher general adaptability and stability were Hyola 411 and 433. These hybrids presented the highest means for seed yield and oil content with predictable and responsive behavior to changes in sowing dates tested in the region of Maringá-PR.

Degradation and stabilization of coal derived liquid. (IV). ; Effect of alcohol on coloration of coal derived light oil. Sekitan ekikayu no anteika. (IV). ; Sekitan ekikayu no chakushoku yokusei ni oyobosu alcohol no tenka koka

Energy Technology Data Exchange (ETDEWEB)

Ukegawa, K.; Matsumura, A.; Kondo, T. (National Research Institute for Pollution and Resources, Tsukuba (Japan)); TAhara, N. (Nitto Denko Corp., Osaka (Japan)); Nakamura, E. (New Energy and Industrial Technology Development Organization, Tokyo (Japan)); Niki, E. (The University of Tokyo, Tokyo (Japan). Research Center for ADvanced Science and Technology)

1990-01-20

In order to improve the color stability of a coal derived light oil, the effect of hydrotreating and various additives has been studied. The color stability has been evaluated through measuring changes in absorbance by flow-cell spectrophotometer. Following results have been obtained: The color stabilities of hydrotreated coal derived light oils were improved remarkably with increasing hydrotreating temperature and pressure. Mild hydrotreating made the color stability of the coal derived light oil much better than the fuel oil, even though the nitrogen removal was very small. Phenolic compounds additives could not improve the color stability of the coal derived light oil. Alcohol, especially methanol, made the coloration rate of the coal derived light oil small to a great extent, on account of hydrogen bonding between methanol and nitrogen compounds in the fuel oil. 4 refs., 4 figs., 3 tabs.

Effect of cross-linking of interfacial sodium caseinate by natural processing on the oxidative stability of oil-in-water (o/w) emulsions.

Science.gov (United States)

Phoon, Pui Yeu; Paul, Lake N; Burgner, John W; San Martin-Gonzalez, M Fernanda; Narsimhan, Ganesan

2014-04-02

This study investigated how enzymatic cross-linking of interfacial sodium caseinate and emulsification, via high-pressure homogenization, influenced the intrinsic oxidative stability of 4% (w/v) menhaden oil-in-water emulsions stabilized by 1% (w/v) caseinate at pH 7. Oil oxidation was monitored by the ferric thiocyanate perioxide value assay. Higher homogenization pressure resulted in improved intrinsic emulsion oxidative stability, which is attributed to increased interfacial cross-linking as indicated by higher weighted average sedimentation coefficients of interfacial protein species (from 11.2 S for 0 kpsi/0.1 MPa to 18 S for 20 kpsi/137.9 MPa). Moderate dosage of transglutaminase at 0.5-1.0 U/mL emulsion enhanced intrinsic emulsion oxidative stability further, despite a contradictory reduction in the antioxidant property of cross-linked caseinate as tested by the 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) assay. This implied the prominent role of cross-linked interfacial caseinate as a physical barrier for oxygen transfer, hence its efficacy in retarding oil oxidation.

Evaluation of Chemical Characterization, Antioxidant Activity and Oxidative Stability of Some Waste Seed Oil

Directory of Open Access Journals (Sweden)

Sibel Uluata

2017-01-01

Full Text Available In this study, fatty acid composition, antioxidant activity, total phenolic compounds (TPC and oxidative stability of cherry seed (SCO, sweet cherry seed (SCSO, mulberry seed (MSO and plum seed oil (PSO were determined. Oleic acid was determined as primary fatty acid (42.9-67.3%, and followed by linoleic acid (23.4-41.8% for SCO, SCSO and PSO. Linoleic acid was determined as primary fatty acid in MSO. γ-tocopherol was determined the main and highest tocopherol isomers varied from 579.9 to 605 mg/kg oil in SCO, SCSO and PSO, whereas δ-tocopherol was determined main tocopherol isomer with 1354mg/kg oil value in MSO. Plum seed oil (PSO was the highest antioxidant activity values in both 2,2-diphenyl-1-picrylhydrazyl (DPPH and 2,2'-azino-bis-(3-ethylbenzthiazoline-6-sulfonic acid (ABTS assays. There was no significant differences in lipid hydroperoxide and TBARS (2-thiobarbituric acid-reactive substance formation among SCO, SCSO and MSO. PSO had the highest induction period (15.1 h, followed by MSO (1.4 h, SCSO (1.5 h, SCO(1.3 h. PSO was oxidatively more stable than the other oil samples. This research shows that these waste seed oils have high antioxidant capacity and tocopherol content, so they could be used in food industry.

Development of a method for the characterization of the oxidation stability of domestic heating oil and domestic heating oil with alternative components using chemiluminescence; Entwicklung einer Analysemethode zur Charakterisierung der Oxidationsstabilitaet von Heizoel EL und Heizoel EL A mittels Chemilumineszenz

Energy Technology Data Exchange (ETDEWEB)

Koch, Winfried; Lukito, Jayadi; Schloss, Heide vom [Oel-Waerme-Institut gGmbH (OWI), Aachen-Herzogenrath (Germany)

2013-04-15

The project's aim was to develop a process that serves to determine the oxidation stability of heating oil - FAME-/ heating oil - vegetable oil-blends clearly. Due to a directed energy input by means of the process of chemiluminescence, statements about the storage stability and the thermal stability of blends can be made. During the process the ageing of blend components and of the heating oil are taken into consideration. As a result, ageing processes and products of pure heating oil as well as biogenic components can be determined. It was shown that the process is applicable to blends up to an admixture of at least 20 % (V/V) of biogenic components, whereby blends with higher admixture shares can be analyzed as well. According to DIN SPEC 51603 - 6 'Heating Oil Alternative' the admixture of FAME is limited to 20 %(V/V) and the admixture of vegetable oil to 5 % (V/V) because of the distillation range. On the basis of these investigations it could be shown how oxidation products influence the signal process of the chemiluminescence radiation and how they can be correlated by a measurable physical value. Moreover, a new evaluation criterion has been developed. By means of this criterion a good reproducibility - regarding the determination of the oxidation stability according to the chemiluminescence methodology for non-aged fuels - can be achieved. The fuel characteristic decrease in the stability of the tested fuels can be represented only partially by the chemiluminescence process, as the measured values are subject to fluctuations. (orig.)

Oil and Gas in the Arab world

International Nuclear Information System (INIS)

Anon.

1996-01-01

The state of oil and gas production in each of twelve Arab states in 1996 is reviewed. A table of proved oil reserves and production in these countries as at the end of 1995 is provided. For Arab oil producers, 1996 was a good year in price terms. Crude oil was selling at an average of $3 a barrel more than in 1995. Factors contributing to prices rises were the increase in demand accompanying global economic growth, especially in the developing economies of Asia, which was not matched by supply growth, and the news that Iraq is unlikely to return to international markets in the near future. (UK)

Effect of castor oil emulsion eyedrops on tear film composition and stability.

Science.gov (United States)

Maïssa, Cécile; Guillon, Michel; Simmons, Peter; Vehige, Joseph

2010-04-01

An emulsion eyedrop containing castor oil has been shown to modify the tear film lipid layer and increase tear film stability. The primary objectives of this investigation were to measure the prevalence of castor oil in the tear fluid over time and quantify the effects on the lipid layer. A secondary objective was to quantify the initial effects on ocular symptomatology. The investigation was an open label pilot study on 5 normal and 10 dry eye subjects. A single eyedrop (Castor oil emulsion, Allergan) was instilled in each eye; the tear film appearance and composition were monitored for 4h via in vivo visualisation using the Tearscope and post in vivo tear samples analysis by HPLC. Combined results for both normal and dry eye subjects showed that castor oil was detected up to 4h after a single eyedrop instillation and associated with an increase in the level of tear film lipid. The relative amount of various lipid families was also changed. An increase in tear lipid layer thickness was significant up to one hour post-instillation for the symptomatic sub-population. The changes in tear film characteristics were associated with significantly lower symptoms up to four hours post-instillation for the symptomatic sub-population. This pilot investigation showed that castor oil eyedrops achieved a residence time of at least four hours post-instillation, producing a more stable tear film and an associated significant decrease in ocular symptoms over the entire follow-up period for the symptomatic subjects. 2009 British Contact Lens Association. Published by Elsevier Ltd. All rights reserved.

Antioxidant activity and emulsion-stabilizing effect of pectic enzyme treated pectin in soy protein isolate-stabilized oil/water emulsion.

Science.gov (United States)

Huang, Ping-Hsiu; Lu, Hao-Te; Wang, Yuh-Tai; Wu, Ming-Chang

2011-09-14

The antioxidant activity of pectic enzyme treated pectin (PET-pectin) prepared from citrus pectin by enzymatic hydrolysis and its potential use as a stabilizer and an antioxidant for soy protein isolate (SPI)-stabilized oil in water (O/W) emulsion were investigated. Trolox equivalent antioxidant capacity (TEAC) was found to be positively associated with molecular weight (M(w)) of PET-pectin and negatively associated with degree of esterification (DE) of PET-pectin. PET-pectin (1 kDa and 11.6% DE) prepared from citrus pectin after 24 h of hydrolysis by commercial pectic enzyme produced by Aspergillus niger expressed higher α,α-diphenyl-β-picrylhydrazyl (DPPH) radical scavenging activity, TEAC, and reducing power than untreated citrus pectin (353 kDa and 60% DE). The addition of PET-pectin could increase both emulsifying activity (EA) and emulsion stability (ES) of SPI-stabilized O/W emulsion. When the SPI-stabilized lipid droplet was coated with the mixture of PET-pectin and pectin, the EA and ES of the emulsion were improved more than they were when the lipid droplet was coated with either pectin or PET-pectin alone. The amount of secondary oxidation products (thiobarbituric acid reactive substances) produced in the emulsion prepared with the mixture of SPI and PET-pectin was less than the amount produced in the emulsion prepared with either SPI or SPI/pectin. These results suggest that PET-pectin has an emulsion-stabilizing effect and lipid oxidation inhibition ability on SPI-stabilized emulsion. Therefore, PET-pectin can be used as a stabilizer as well as an antioxidant in plant origin in SPI-stabilized O/W emulsion and thus prolong the shelf life of food emulsion.

United States foreign oil policy since World War 1 : for profits and security. 2 ed.

Energy Technology Data Exchange (ETDEWEB)

Randall, S.J.

2005-07-01

This book provided a historical context for United States global oil politics, with a focus on the goals, accomplishments and challenges of United States foreign oil policy, as well as on the relationship between the state and private sectors. This second edition has integrated developments in global politics since the end of the Cold War. It was suggested that many factors have provided the context for oil policy formation: a succession of crises in Iran since the 1950s; 2 wars in Iraq; U.S. intervention in Afghanistan; the threat of international terrorism since September 11, 2001; ongoing conflicts between Israel and the Arab nations in the Middle East; political instability in Saudi Arabia and in Venezuela and the trend towards trade and investment liberalization in Latin America in the 1990s. In addition, the emergence of oil sands reserves in Canada and other sources of non-conventional oil were discussed. Nationalism and oil policies in the Depression and World War 2 were examined. The structure of decision-making in oil policies was examined. Domestic and offshore resources were reviewed, and an outline of international agreements and relationships was presented. Issues concerning OPEC countries and the Iranian Revolution were examined. It was concluded that the United States has become more and not less vulnerable, despite its military strength. The author suggested that the main policy challenge to the United States may well be the tension between its commitment to Israel and its determination to avoid alienating the Arab oil-producing states. refs., tabs., figs.

Film self-assembly properties of vacuum residua from crude oil and correlation to the stability of water/crude oil emulsions[Supercritical fluid extraction and fractional technology (SFEF)

Energy Technology Data Exchange (ETDEWEB)

Peng, Bo

2005-07-01

In this thesis, SFEF technology has been used to obtain a fine separation of vacuum residua. Three kinds of vacuum residua from Iranian Heavy Crude Oil, Iranian Light Crude Oil and Daqing Crude Oil have been separated respectively into three series narrow cut fractions as a function of the average molecular weight. And their molecular parameters have been characterized by Vapour Pressure Osmometry(VPO) system, Ultraviolet(UV) spectroscopy, Infrared(IR) spectroscopy as well as by elemental analysis. The various fractions of vacuum residua have been added to an oil/water model system. The oil phase used was pure heptane, pure toluene, a mixture of heptane and toluene etc. Various properties of the interfacial film have been studied such as the self-assembly properties, interfacial tension and interfacial viscosity, etc. The self-assembly procedure of interfacial film of vacuum residua fractions were focused by means of the Wilhelmy plate method (Paper 1). The self-assembly states of interfacial film of vacuum residua fraction from Iranian Heavy and Daqing crude oil have been revealed by using Langmuir-Blodgett technology respectively (Paper II and Paper III). From measurement of the interfacial shear viscosity, the mechanical strength of the interfacial film formed by the vacuum residua fraction has been described (Paper IV) and the roles of the surfactants added in the interfacial film have been confirmed (Paper V). At the same time, the oil/water interfacial tensions of vacuum residua fractions from the three kinds of crude oil have been studied and compared (Paper VI and Paper VII). Characteristic properties of emulsions stabilized by the vacuum residua, such as Zeta potential (Paper VIII) and particle size distribution (Paper IX), have also been studied. An attempt has been made to explain the variations of emulsion properties in terms of the interfacial self-assembly of vacuum residua fractions. Finally, based up the above research and using chemometric methods

Trinidad and Tobago: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that Trinidad and Tobago has decided to increase its oil export revenue by pumping as much crude as possible. This island nation consequently has embarked on a $403-million expansion project that covers everything from initiating secondary recovery at a number of fields to upgrading the Point a Pierre refinery. Trinidad and Tobago Oil Co. (Trintoc) is operating the project and has received a $260-million loan from the Inter-American Development Bank. Another $75 million is coming from the Export-Import Bank of Japan and the European Investment Bank. Trintoc based the work on $22 oil, a level still not achieved for any duration, but the firm shows every sign of finishing the project as planned. Completion of work should impact the nation significantly. Crude oil and products account for 60% of all exports and 24% of governmental revenue. However, oil production has tumbled about 65,000 bpd from a 1978 peak of 215,000 bpd

Venezuela: World Oil Report 1991

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports on Venezuela's expansion by state oil company PDVSA has gone from a mere concept a year ago to a well-defined plan. The five-year project that began this year and runs through 1995 received a $4-billion upgrading last fall to $25 billion. Money will be spent in increments of $5 billion/year, and all sectors are involved. Largest share, about $10.5 billion, will go to upstream projects, with $6 billion to be invested in refining, $6 billion in petrochemicals, $1.5 billion in coal and $800 million in domestic marketing. PDVSA intends to finance most of the spending directly from its cash flow. The upstream spending will go toward boosting oil production to more than 3.6 MMbpd by the beginning of 1996, with capacity topping at 4.2 MMbopd. Such heavy spending should prove a boon to the Venezuelan economy. The oil industry constitutes 23% of Venezuela's GNP, accounts for 75% of governmental revenues and produces 70% of the nation's annual foreign exchange earnings. The Ministry of Planning already is forecasting a 7% leap in real growth of the GNP this year

Homogenization conditions affect the oxidative stability of fish oil enriched milk emulsions: Oxidation linked to changes in protein composition at the oil-water interface

DEFF Research Database (Denmark)

Sørensen, Ann-Dorit Moltke; Baron, Caroline; Bruni Let, Mette

2007-01-01

Fish oil was incorporated into milk under different homogenization temperatures (50 and 72 °C) and pressures (5, 15, and 22.5 MPa). Subsequently, the oxidative stability of the milk and changes in the protein composition of the milk fat globule membrane (MFGM) were examined. Results showed...

Process Optimization for Biodiesel Production from Corn Oil and Its Oxidative Stability

Directory of Open Access Journals (Sweden)

N. El Boulifi

2010-01-01

Full Text Available Response surface methodology (RSM based on central composite design (CCD was used to optimize biodiesel production process from corn oil. The process variables, temperature and catalyst concentration were found to have significant influence on biodiesel yield. The optimum combination derived via RSM for high corn oil methyl ester yield (99.48% was found to be 1.18% wt catalyst concentration at a reaction temperature of 55.6∘C. To determine how long biodiesel can safely be stored, it is desirable to have a measurement for the stability of the biodiesel against such oxidation. Storage time and oxygen availability have been considered as possible factors influencing oxidative instability. Biodiesel from corn oil was stored for a period of 30 months, and the physico-chemical parameters of samples were measured at regular interval of time. Results show that the acid value (AV, peroxide value (PV, and viscosity (ν increased while the iodine value (IV decreased. These parameters changed very significantly when the sample was stored under normal oxygen atmosphere. However, the ν, AV, and IV of the biodiesel sample which was stored under argon atmosphere were within the limit by the European specifications (EN 14214.

Oxidative stability and alpha-tocopherol retention in soybean oil with lemon seed extract (Citrus limon) under thermoxidation.

Science.gov (United States)

Luzia, Débora Maria Moreno; Jorge, Neuza

2009-11-01

The synergistic effect of lemon seed extract with tert-butylhydroquinone (TBHQ) in soybean oil subjected to thermoxidation by Rancimat was investigated, and the influence of these antioxidants on a-tocopherol degradation in thermoxidized soybean oil. Control, LSE (2400 mg/kg Lemon Seed Extract), TBHQ (50 mg/kg), Mixture 1 (LSE + 50 mg/kg TBHQ) and Mixture 2 (LSE + 25 mg/kg TBHQ) were subjected to 180 degrees C for 20 h. Samples were taken at time 0, 5, 10, 15 and 20 h intervals and analysed for oxidative stability and alpha-tocopherol content. LSE and Mixtures 1 and 2 showed the capacity of retarding lipid oxidation when added to soya oil and also contributed to alpha-tocopherol retention in oil heated at high temperatures. However, Mixtures 1 and 2 added to the oil presented a greater antioxidant power, consequently proving the antioxidants synergistic effect.

Oil outlook to 2020

International Nuclear Information System (INIS)

Shihab-Eldin, A.; Hamel, M.; Brennand, G.

2003-01-01

OPEC's World Energy Model, OWEM, is used to develop the outlook for oil demand and supply to 2020. The reference case assumes world economic growth averaging 3.3 per cent per annum, while OPEC's Reference Basket of seven crudes remains mainly in the target range of US $22-28 a barrel, in nominal terms. With no additional assumed policy measures, for example, to reduce CO 2 emissions, the reference case sees world oil demand rising from 76 million barrels a day in 2000 to 89 mb/d in 2010 and 107 mb/d in 2020. More than three-quarters of this increase comes from developing countries. The most important sector for a demand increase is transportation, accounting for 60 per cent of the rise globally. On the supply side, the oil resource base is not considered a constraint to satisfying this increase in demand. Non-OPEC production is expected to continue to grow during the current decade, and to stabilise at a level of 53-55 mb/d beyond 2010. OPEC production is projected to reach 36 mb/d by 2010 and 52 mb/d in 2020. It is important, however, to recognise the uncertainties pervading such an assessment. For example, it is not clear how future economic growth, energy policies and technology will develop over this time horizon, and this inevitably clouds any assessment of future oil demand and supply. In an attempt to quantify one aspect of such uncertainty, other feasible economic growth rates have been assumed, the results of which suggest that OPEC output by 2010 could be 4-5 mb/d higher or lower than in the reference case, while the range is clearly even greater in the years to 2020. Moreover, policy reactions to such developments could compound the uncertainty. On the other hand, such alternative economic growth could place pressure upon oil prices to move outside OPEC's price band of $22-28/b. These uncertainties illustrate the scope of the challenges confronting the oil industry, especially given the long lead-time nature of oil industry investment, in making

Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils. Final Report

Energy Technology Data Exchange (ETDEWEB)

Huber, George W.; Upadhye, Aniruddha A.; Ford, David M.; Bhatia, Surita R.; Badger, Phillip C.

2012-10-19

This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8m were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments

Oxidative stability of fish and algae oils containing long-chain polyunsaturated fatty acids in bulk and in oil-in-water emulsions

DEFF Research Database (Denmark)

Frankel, E.N.; Satue-Gracia, T.; Meyer, Anne Boye Strunge

2002-01-01

from algae are unusually stable to oxidation, Addition of ethylenediaminetetraacetic acid (EDTA) prevented oxidation of both fish and algal oil emulsions without added iron and at low iron:EDTA molar concentrations. EDTA, however, promoted the oxidation of the corresponding emulsions that contained...... high iron:EDTA ratios. Therefore, to be effective as a metal chelator, EDTA must be added at molar concentrations higher than that of iron to inhibit oxidation of foods containing long-chain PUFA from either fish or algae and fortified with iron.......The oxidative stability of long-chain polyunsaturated fatty acid (PUFA) and docosahexaenoic acid (DHA)-containing fish and algae oils varies widely according to their fatty acid composition, the physical and colloidal states of the lipids, the contents of tocopherols and other antioxidants...

on the oxidation stability of lubricating oil

African Journals Online (AJOL)

DJFLEX

I. P. Okoye, Dpartment of Pure and Industrial Chemistry,University of Port Harcourt, Nigeria ... of the kinematic viscosity for the formulated oil were much higher than the base oil, while ... including sulphurized oil – soluble organic compounds,.

Global market trade policy analysis for petroleum oils and oils obtained from bituminous minerals, crude

Directory of Open Access Journals (Sweden)

Bagheri, F.

2012-01-01

Full Text Available This article is based on surveying the custom tariffs imposed on the world export market of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. We obtained the data according to the most updated available data provided online by UNCTAD and World Bank. The results indicate that none of the 142 countries in the world market of this product have imposed non-tariff trade barriers on the import of Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude. The developed countries and the countries with transition economies are the main world import partners. European Union, United States, China, Japan, South Korea, Canada, Singapore, Taiwan, Thailand, South Africa, Australia, Turkey, Brazil, Sweden and Belarus are the examples and have imposed low custom tariffs on Petroleum Oils and Oils Obtained from Bituminous Minerals, Crude.

New opportunities of the application of natural herb and spice extracts in plant oils: application of electron paramagnetic resonance in examining the oxidative stability.

Science.gov (United States)

Kozłowska, Mariola; Szterk, Arkadiusz; Zawada, Katarzyna; Ząbkowski, Tomasz

2012-09-01

The aim of this study was to establish the applicability of natural water-ethanol extracts of herbs and spices in increasing the oxidative stability of plant oils and in the production of novel food. Different concentrations (0, 100, 300, 500, and 700 ppm) of spice extracts and butylated hydroxyanisole (BHA) (100 ppm) were added to the studied oils. The antioxidant activity of spice extracts was determined with electron paramagnetic resonance (EPR) spectroscopy using 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical assay. The study showed that the extracts significantly increased the oxidative stability of the examined oils when compared to one of the strongest synthetic antioxidants--BHA. The applied simple production technology and addition of herb and spice extracts to plant oils enabled enhancement of their oxidative stability. The extracts are an alternative to the oils aromatized with an addition of fresh herbs, spices, and vegetables because it did not generate additional flavors thus enabling the maintenance of the characteristic ones. Moreover, it will increase the intake of natural substances in human diet, which are known to possess anticarcinogenic properties. © 2012 Institute of Food Technologists®

Physical and Oxidative Stability of Flaxseed Oil-in-Water Emulsions Fabricated from Sunflower Lecithins: Impact of Blending Lecithins with Different Phospholipid Profiles.

Science.gov (United States)

Liang, Li; Chen, Fang; Wang, Xingguo; Jin, Qingzhe; Decker, Eric Andrew; McClements, David Julian

2017-06-14

There is great interest in the formulation of plant-based foods enriched with nutrients that promote health, such as polyunsaturated fatty acids. This study evaluated the impact of sunflower phospholipid type on the formation and stability of flaxseed oil-in-water emulsions. Two sunflower lecithins (Sunlipon 50 and 90) with different phosphatidylcholine (PC) levels (59 and 90%, respectively) were used in varying ratios to form emulsions. Emulsion droplet size, charge, appearance, microstructure, and oxidation were measured during storage at 55 °C in the dark. The physical and chemical stability increased as the PC content of the lecithin blends decreased. The oxidative stability of emulsions formulated using Sunlipon 50 was better than emulsions formulated using synthetic surfactants (SDS or Tween 20). The results are interpreted in terms of the impact of emulsifier type on the colloidal interactions between oil droplets and on the molecular interactions between pro-oxidants and oil droplet surfaces.

Production of jet fuel using heavy crude oil; Producao de combustiveis de aviacao a partir de petroleos pesados

Energy Technology Data Exchange (ETDEWEB)

Om, Neyda [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Escola de Quimica; Cavado, Alberto; Reyes, Yordanka [Centro de Pesquisas do Petroleo, Cidade de Havana (Cuba); Dominguez, Zulema [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE)

2004-07-01

The production of heavy crude oils increased in the last years in the world. Crude oils with high density, viscosity, acidity and sulfur, nitrogen, metals and asphaltenes contents, by the others hand, low stability and low product quality. The challenger of many refiners is find solutions to refine the heavy crude oils, and produce fuels with certify quality, such as Jet Fuel. The principal aviation technique on the world work with gas turbines engines feted for jet fuel (JET A1). The quality specifications of this fuel are establish by International Norms: ASTM-1655, DEF STAN 91-91-3 (DERD 2494) and joint Fuelling System Check List. The world technologies to obtain jet fuel from mixtures of heavy crude oil with middle crude oils are: Atmospheric distillation, with a posterior hydrogenation and finally the additivation. Studies carried out have demonstrates that the Cubans heavy crude oils is characterized for having API less than 10, raised viscosity, high sulfur content (>6%) and asphaltenes content (more than 15%). These properties provide to its derivatives of low quality. This paper define the characteristic of Cuban heavy crude oil, the technology and operational conditions to produce jet fuel (Jet A1) and the quality of fuel produced. (author)

CEO's guide to world business costs : oil and gas equipment

International Nuclear Information System (INIS)

2004-01-01

This paper presents the results of a detailed study of wellhead equipment manufacturing costs in 11 countries in North America, Europe and Asia-Pacific. According to the Economist Intelligence Unit (EIU), Canada has a 5 per cent cost advantage and will be the best country in the world to do business between 2004 to 2008 because of its foreign trade policies, high quality infrastructure and market opportunities within the North American marketplace. KPMG Consulting developed a web-based cost model that allows investors to examine the costs involved in setting up and operating a business in more than 120 cities in Canada, the United States, the United Kingdom, France, Germany, Italy, Iceland, Luxembourg, the Netherlands, Japan and Australia. According to the model, a comparison of annual costs for oil and gas wellhead equipment manufacturing was presented for the 11 countries with reference to revenues, costs, and profits before and after income tax. In addition, Canada's research and development (R and D) cost advantage compared to the United States was presented, with reference to tax credits, expenditures, salaries, contracts, capital equipment, volume-based tax credits, and research studies. This report also includes a brief summary of 3 oil and gas companies that came to Canada and prospered. tabs., figs

Multivariate approaches for stability control of the olive oil reference materials for sensory analysis - part II: applications.

Science.gov (United States)

Valverde-Som, Lucia; Ruiz-Samblás, Cristina; Rodríguez-García, Francisco P; Cuadros-Rodríguez, Luis

2018-02-09

The organoleptic quality of virgin olive oil depends on positive and negative sensory attributes. These attributes are related to volatile organic compounds and phenolic compounds that represent the aroma and taste (flavour) of the virgin olive oil. The flavour is the characteristic that can be measured by a taster panel. However, as for any analytical measuring device, the tasters, individually, and the panel, as a whole, should be harmonized and validated and proper olive oil standards are needed. In the present study, multivariate approaches are put into practice in addition to the rules to build a multivariate control chart from chromatographic volatile fingerprinting and chemometrics. Fingerprinting techniques provide analytical information without identify and quantify the analytes. This methodology is used to monitor the stability of sensory reference materials. The similarity indices have been calculated to build multivariate control chart with two olive oils certified reference materials that have been used as examples to monitor their stabilities. This methodology with chromatographic data could be applied in parallel with the 'panel test' sensory method to reduce the work of sensory analysis. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

Physicochemical characteristics, thermal stability and antioxidant characteristics of Trichosanthes kirilowii maxim seed oil as affected by different extraction methods

International Nuclear Information System (INIS)

Hou, Z.K.; Ji, Q.Z.; Yang, L.; Gao, Z.Q.; Wang, B.C.

2017-01-01

In conducting this study, the extraction of Trichosanthes kirilowii maxim seed oils (TSO) was carried out with the help of cold pressing (CP), hot pressing (HP) and soxhlet extraction (SE). Investigation, together with comparison, was carried out with respect to the physicochemical properties, thermal stability and antioxidant action of TSO. The key ingredients in the seeds consisted of fat, fiber and protein. The physicochemical characteristics of the oils brought to light the fact that CPTSO possessed top oil quality. The findings also suggested that linoleic acid, punicic acid and oleic acid were the leading unsaturated fatty acids in TSO. It was also discovered that TSO had an almost identical chemical composition regardless of the extraction method was used. It was demonstrated by TG/DTG curves that both HPTSO and CPTSO had more thermal stability in comparison with SETSO. Furthermore, the antioxidant activity assessments emphasized that CPTSO had better radical scavenging potential. CP had the ability to deliver an extract with higher quality as well as antioxidant activity in comparison with HP and SE methods and can be taken into consideration as a more suitable method in order to attain high quality oil. [es

Climate change, future Arctic Sea ice, and the competitiveness of European Arctic offshore oil and gas production on world markets.

Science.gov (United States)

Petrick, Sebastian; Riemann-Campe, Kathrin; Hoog, Sven; Growitsch, Christian; Schwind, Hannah; Gerdes, Rüdiger; Rehdanz, Katrin

2017-12-01

A significant share of the world's undiscovered oil and natural gas resources are assumed to lie under the seabed of the Arctic Ocean. Up until now, the exploitation of the resources especially under the European Arctic has largely been prevented by the challenges posed by sea ice coverage, harsh weather conditions, darkness, remoteness of the fields, and lack of infrastructure. Gradual warming has, however, improved the accessibility of the Arctic Ocean. We show for the most resource-abundant European Arctic Seas whether and how a climate induced reduction in sea ice might impact future accessibility of offshore natural gas and crude oil resources. Based on this analysis we show for a number of illustrative but representative locations which technology options exist based on a cost-minimization assessment. We find that under current hydrocarbon prices, oil and gas from the European offshore Arctic is not competitive on world markets.

Physical stability and clinical efficacy of Crocodylus niloticus oil lotion

Directory of Open Access Journals (Sweden)

Telanie Venter

Full Text Available ABSTRACT The stability and the anti-ageing, skin hydrating and anti-erythema effects of a commercialized Crocodylus niloticus Laurenti, 1768, Crocodylidae, oil lotion was determined. The lotion was stored at controlled conditions over six months during which several stability tests were performed. For the clinical efficacy studies lotion was applied on volar forearm skin (female volunteers and compared to a liquid paraffin-containing reference product. Skin hydrating and anti-ageing effects were determined with a Corneometer®, Cutometer® and Visioscan®, following single (3 h and multiple applications (12 weeks. The Vapometer® and Mexameter® were utilized to determine this lotion's anti-erythema effects on sodium lauryl sulfate irritated skin. The lotion demonstrated good stability over 6 months. The reference product increased skin hydration and decreased skin wrinkles to a larger extent than the C. niloticus lotion after a single application, whereas the C. niloticus lotion decreased skin scaliness better than the reference product. During the long-term study, the reference product overall increased skin hydration more than the C. niloticus lotion, whereas C. niloticus lotion increased skin elasticity to a larger extent than the reference product. C. niloticus lotion increased skin wrinkles and decreased skin scaliness over 12 weeks. Compared to non-treated, irritated skin, C. niloticus lotion demonstrated some potential anti-inflammatory characteristics.

Effect of different dextrose equivalents of maltodextrin on oxidation stability in encapsulated fish oil by spray drying.

Science.gov (United States)

Abd Ghani, Asmaliza; Adachi, Sae; Shiga, Hirokazu; Neoh, Tze Loon; Adachi, Shuji; Yoshii, Hidefumi

2017-04-01

Encapsulating fish oil by spray drying with an adequate wall material was investigated to determine if stable powders containing emulsified fish-oil-droplets can be formed. In particular, the dextrose equivalent (DE) of maltodextrin (MD) affects the powder structure, surface-oil ratio, and oxidative stability of fish oil. The carrier solution was prepared using MD with different DEs (DE = 11, 19, and 25) and sodium caseinate as the wall material and the emulsifier, respectively. The percentage of microcapsules having a vacuole was 73, 39, and 38% for MD with DE = 11, 19, and 25, respectively. Peroxide values (PVs) were measured for the microcapsules incubated at 60 °C. The microcapsules prepared with MD of DE = 25 and 19 had lower PVs than those prepared with MD of DE = 11. The difference in PV can be ascribed to the difference in the surface-oil ratio of the spray-dried microcapsules.

Climate-wise choices in a world of oil abundance

Science.gov (United States)

Brandt, Adam R.; Masnadi, Mohammad S.; Englander, Jacob G.; Koomey, Jonathan; Gordon, Deborah

2018-04-01

Constrained oil supply has given way to abundance at a time when strong action on climate change is wavering. Recent innovation has pushed US oil production to all-time heights and driven oil prices lower. At the same time, attention to climate policy is wavering due to geopolitical upheaval. Nevertheless, climate-wise choices in the oil sector remain a priority, given oil’s large role in modern economies. Here we use a set of open-source models along with a detailed dataset comprising 75 global crude oils (~25% of global production) to estimate the effects of carbon intensity and oil demand on decadal scale oil-sector emissions. We find that oil resources are abundant relative to all projections of 21st century demand, due to large light-tight oil (LTO) and heavy oil/bitumen (HOB) resources. We then investigate the ‘barrel forward’ emissions from producing, refining, and consuming all products from a barrel of crude. These oil resources have diverse life-cycle-greenhouse gas (LC-GHG) emissions impacts, and median per-barrel emissions for unconventional resources vary significantly. Median HOB life cycle emissions are 1.5 times those of median LTO emissions, exceeding them by 200 kgCO2eq./bbl. We show that reducing oil LC-GHGs is a mitigation opportunity worth 10–50 gigatonnes CO2 eq. cumulatively by 2050. We discuss means to reduce oil sector LC-GHGs. Results point to the need for policymakers to address both oil supply and oil demand when considering options to reduce LC-GHGs.

Physical stability, microstructure and micro-rheological properties of water-in-oil-in-water (W/O/W) emulsions stabilized by porcine gelatin.

Science.gov (United States)

Zhu, Qiaomei; Qiu, Shuang; Zhang, Hongwei; Cheng, Yongqiang; Yin, Lijun

2018-07-01

Water-in-oil-in-water (W/O/W) emulsions could be utilized for fat-reduced food formulation and delivery of bioactive nutrients. However, due to thermodynamic instability, it is difficult to prepare stable double emulsions. The purpose of this study was to improve the stability of W/O/W double emulsions containing 2.0 M MgCl 2 by adding porcine gelatin in the inner water phase. The impact of gelatin on the physical stability, microstructure and micro-rheological properties of W/O/W emulsions was investigated. It was found that, when the concentration of porcine gelatin exceeded 4.0 wt%, the stability of emulsions was improved, due to increased viscoelasticity of emulsion droplets. When MgCl 2 concentration increased to 2.0 M, the particle size of emulsions increased, due to the osmotic pressure gradient, and the presence of gelatin further increased the droplet size. Confocal microscopy results showed that the presence of gelatin could improve the stability of W/O/W emulsions against coalescence。. Copyright © 2018. Published by Elsevier Ltd.

Biscuits fortified with micro-encapsulated shrimp oil: characteristics and storage stability.

Science.gov (United States)

Takeungwongtrakul, Sirima; Benjakul, Soottawat

2017-04-01

Characteristics and storage stability of biscuits fortified with micro-encapsulated shrimp oil (MSO) were determined. The addition of MSO increased spread ratio, whilst decreased the thickness of biscuit. The highest hardness of biscuit was obtained with addition of 9 or 12% MSO. Biscuit surface showed higher redness and yellowness when MSO was incorporated ( p  < 0.05). The addition of MSO up to 6% had no adverse effect on biscuit quality and acceptability. When biscuits added with 6% MSO were stored under different illumination conditions (light and dark), lipid oxidation in all samples increased throughout the storage of 12 days. Light accelerated lipid oxidation of biscuits as evidenced by the increases in both peroxide values and abundance of volatile compounds. No marked change in EPA, DHA and astaxanthin contents were noticeable in biscuit fortified with MSO after 12 days of storage. Therefore, the biscuit could be fortified with MSO up to 6% and must be stored in dark to assure its oxidative stability.

Frying stability of high oleic sunflower oils as affected by composition of tocopherol isomers and linoleic acid content.

Science.gov (United States)

Aladedunye, Felix; Przybylski, Roman

2013-12-01

The influence of linoleic acid content and tocopherol isomeric composition on the frying performance of high oleic sunflower oil was evaluated during a 14-day restaurant style frying operation. At equal linoleic acid content, no significant difference was observed between high oleic sunflower oil containing only α-tocopherol and the sample containing a mixture of α-, γ-, and δ-isomers as measured by the amount of total polar components, oligomers, anisidine value, and free fatty acids. On the contrary, at similar tocopherol isomeric composition, high oleic sunflower oil containing lower amount of linoleic acid showed superior frying stability compared to the sample with a higher content of linoleic acid, suggesting that the frying performance of high oleic sunflower oil is dictated primarily by the level of linoleic acid, with the tocopherol isomeric composition of the oil having no significant influence. In all oil samples, the loss of γ-tocopherol was higher than the corresponding loss of α-tocopherol. Copyright © 2013 Elsevier Ltd. All rights reserved.

Stability of transition to a world without nuclear weapons: Technical problems of verification

International Nuclear Information System (INIS)

Zhigalov, V.

1998-01-01

A serious psychological barrier to acceptance of the concept for achieving the nuclear-weapon-free world is fear of facing the prospect that one or more nations or extremist political groups might develop their own nuclear weapons. Actually this is a question of stability of the nuclear-weapon-free world. From this point of view the most effective system of verification is an absolute necessity. This system must ensure detection of so called undeclared nuclear activity at early stage. Scientists of Russian nuclear centers are working today on solving this problem. This paper is considered to be a comprehensive attempt to analyze the technical and organizational aspects of the problems of transition to a nuclear-weapons-free world, setting aside the difficulties of resolving purely political problems

Effect of cumin essential oil usage on fermentation quality, aerobic stability and in vitro digetibility of alfalfa silage.