Mandal, Debasish; Mallick, Dibyendu; Shaik, Sason
2018-01-16
This Account outlines interplay of theory and experiment in the quest to identify the reactive-spin-state in chemical reactions that possess a few spin-dependent routes. Metalloenzymes and synthetic models have forged in recent decades an area of increasing appeal, in which oxometal species bring about functionalization of hydrocarbons under mild conditions and via intriguing mechanisms that provide a glimpse of Nature's designs to harness these reactions. Prominent among these are oxoiron(IV) complexes, which are potent H-abstractors. One of the key properties of oxoirons is the presence of close-lying spin-states, which can mediate H-abstractions. As such, these complexes form a fascinating chapter of spin-state chemistry, in which chemical reactivity involves spin-state interchange, so-called two-state reactivity (TSR) and multistate reactivity (MSR). TSR and MSR pose mechanistic challenges. How can one determine the structure of the reactive transition state (TS) and its spin state for these mechanisms? Calculations can do it for us, but the challenge is to find experimental probes. There are, however, no clear kinetic signatures for the reactive-spin-state in such reactions. This is the paucity that our group has been trying to fill for sometime. Hence, it is timely to demonstrate how theory joins experiment in realizing this quest. This Account uses a set of the H-abstraction reactions of 24 synthetic oxoiron(IV) complexes and 11 hydrocarbons, together undergoing H-abstraction reactions with TSR/MSR options, which provide experimentally determined kinetic isotope effect (KIE exp ) data. For this set, we demonstrate that comparing KIE exp results with calculated tunneling-augmented KIE (KIE TC ) data leads to a clear identification of the reactive spin-state during H-abstraction reactions. In addition, generating KIE exp data for a reaction of interest, and comparing these to KIE TC values, provides the mechanistic chemist with a powerful capability to
Wang, Dong; Ray, Kallol; Collins, Michael J.; Farquhar, Erik R.; Frisch, Jonathan R.; Gomez, Laura; Jackson, Timothy A.; Kerscher, Marion; Waleska, Arkadius; Comba, Peter; Costas, Miquel; Que, Lawrence, Jr.
2013-01-01
Oxoiron(IV) species have been found to act as the oxidants in the catalytic cycles of several mononuclear nonheme iron enzymes that activate dioxygen. To gain insight into the factors that govern the oxidative reactivity of such complexes, a series of five synthetic S = 1 [FeIV(O)(LN5)]2+ complexes has been characterized with respect to their spectroscopic and electrochemical properties as well as their relative abilities to carry out oxo transfer and hydrogen atom abstraction. The Fe=O units...
International Nuclear Information System (INIS)
Draksharapu, Apparao; Rasheed, Waqas; Klein, Johannes E.M.N.; Que, Lawrence Jr.
2017-01-01
Ceric ammonium nitrate (CAN) or Ce IV (NH 4 ) 2 (NO 3 ) 6 is often used in artificial water oxidation and generally considered to be an outer-sphere oxidant. Herein we report the spectroscopic and crystallographic characterization of [(N4Py)Fe III -O-Ce IV (OH 2 )(NO 3 ) 4 ] + (3), a complex obtained from the reaction of [(N4Py)Fe II (NCMe)] 2+ with 2 equiv CAN or [(N4Py)Fe IV =O] 2+ (2) with Ce III (NO 3 ) 3 in MeCN. Surprisingly, the formation of 3 is reversible, the position of the equilibrium being dependent on the MeCN/water ratio of the solvent. These results suggest that the Fe IV and Ce IV centers have comparable reduction potentials. Moreover, the equilibrium entails a change in iron spin state, from S=1 Fe IV in 2 to S=5/2 in 3, which is found to be facile despite the formal spin-forbidden nature of this process. This observation suggests that Fe IV =O complexes may avail of reaction pathways involving multiple spin states having little or no barrier. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)
Energy Technology Data Exchange (ETDEWEB)
Draksharapu, Apparao; Rasheed, Waqas; Klein, Johannes E.M.N.; Que, Lawrence Jr. [Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, MN (United States)
2017-07-24
Ceric ammonium nitrate (CAN) or Ce{sup IV}(NH{sub 4}){sub 2}(NO{sub 3}){sub 6} is often used in artificial water oxidation and generally considered to be an outer-sphere oxidant. Herein we report the spectroscopic and crystallographic characterization of [(N4Py)Fe{sup III}-O-Ce{sup IV}(OH{sub 2})(NO{sub 3}){sub 4}]{sup +} (3), a complex obtained from the reaction of [(N4Py)Fe{sup II}(NCMe)]{sup 2+} with 2 equiv CAN or [(N4Py)Fe{sup IV}=O]{sup 2+} (2) with Ce{sup III}(NO{sub 3}){sub 3} in MeCN. Surprisingly, the formation of 3 is reversible, the position of the equilibrium being dependent on the MeCN/water ratio of the solvent. These results suggest that the Fe{sup IV} and Ce{sup IV} centers have comparable reduction potentials. Moreover, the equilibrium entails a change in iron spin state, from S=1 Fe{sup IV} in 2 to S=5/2 in 3, which is found to be facile despite the formal spin-forbidden nature of this process. This observation suggests that Fe{sup IV}=O complexes may avail of reaction pathways involving multiple spin states having little or no barrier. (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)
Pan, Zhengzheng; Newcomb, Martin
2011-06-01
Disproportionation of oxoiron(IV) porphyrin (Compound II) to oxoiron(IV) porphyrin radical cation (Compound I) was studied in three P450 model systems with different electronic structures. Direct conversion of Compound II to Compound I has been observed for 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin (TDCPP) in acid-catalyzed reactions in a mixed solvent of acetonitrile and water (1:1, v/v) containing excess m-CPBA oxidant, with a second-order rate constant of (1.3 ± 0.2) × 10(2) M(-1) s(-1). The acid-catalyzed disproportionation heavily depends on the electron demand of the substituted aryl groups on the porphyrin macrocycle. The disproportionation equilibrium constants show drastic change for the three porphyrin systems.
Spin-crossover behavior of polymeric iron(III) complexes
International Nuclear Information System (INIS)
Maeda, Yonezo; Miyamoto, Makoto; Takashima, Yoshimasa; Oshio, Hiroaki
1989-01-01
Polymeric spin-crossover iron(III) complexes possessing poly(4-vinylpyridine), poly(N-vinylimidazole) or poly(octylmethacrylate-co-4-vinylpyridine) as ligand are prepared. In this experience enriched 57 Fe was used to get strong Moessbauer absorption. The enriched behavior of the complexes were examined by magnetic susceptibilities measurement, and Moessbauer and esr spectroscopies. Some of them show spin-state behavior over a wide range of temperature. Some of them show rapid spin-state interexchange compared to the Moessbauer time scale and others not. Spin-crossover behavior of polymeric complexes is characterized of wide spin-state transition temperature range
The spin glasses: the paradigm of the complex systems
International Nuclear Information System (INIS)
Ruiz-Lorenzo, J.J.
1997-01-01
The solution of the spin glasses in the Mean Field approximation gives some interesting characteristics such as the existence of an infinite number of pure states organized in an ultrametric way (like in Taxonomy). These properties raise the spin glasses to a paradigm of the complex systems. (Author) 7 refs
Spin Propensities of Octahedral Complexes From Density Functional Theory
DEFF Research Database (Denmark)
Mortensen, Sara R.; Kepp, Kasper Planeta
2015-01-01
The fundamental balance between high- and low-spin states of transition metal systems depends on both the metal ion and the ligands surrounding it, as often visualized by the spectrochemical series. Most density functionals do not reproduce this balance, and real spin state propensities depend...... on orbital pairing and vibrational entropies absent in the spectrochemical series. Thus, we systematically computed the tendency toward high or low spin of "text-book" octahedral metal complexes versus ligand and metal type, using eight density functionals. Dispersion effects were generally ... assessment of spin state propensities versus ligand and metal type and reveal, e.g., that CN- is consistently weaker than CO for M(II) but stronger than CO for M(III) and SCN- and NCS- change order in M(II) versus M(III) complexes. Contrary to expectation based on the spectrochemical series, Cl- and Br...
Spin label EPR-based characterization of biosystem complexity
Strancar, J.; Koklic, T.; Arsov, Z.; Filipic, B.; Stopar, D.; Hemminga, M.A.
2005-01-01
Following the widely spread EPR spin-label applications for biosystem characterization, a novel approach is proposed for EPR-based characterization of biosystem complexity. Hereto a computational method based on a hybrid evolutionary optimization (HEO) is introduced. The enormous volume of
Optical pump - nuclear resonance probe experiments on spin crossover complexes
Sakshath, S.; Jenni, K.; Scherthan, L.; Würtz, P.; Herlitschke, M.; Sergeev, I.; Strohm, C.; Wille, H.-C.; Röhlsberger, R.; Wolny, J. A.; Schünemann, V.
2017-11-01
A novel sample environment enabling optical pump - nuclear resonance probe experiments has been installed at the beamline P01, Petra III, DESY Hamburg. This set-up has been used to investigate optically induced spin state changes of spin crossover (SCO) complexes by nuclear resonant scattering immediately after excitation by an optical laser pulse. Here, we report the technical details as well as first results of the experiments performed at 290 K and 80 K on the SCO complexes [Fe (NH2trz)3]Cl2 and [Fe(PM-BiA)2(NCS)2], respectively. The 57Fe-enriched SCO complexes were excited by a 531 nm laser with a pulse length indicate the presence of high spin (HS) states when the complexes are excited by laser pulses and a pure low spin (LS) state in the absence of any laser pulse. Furthermore, the dependence of the optically excited HS-fraction has been determined as a function of the average optical power.
Theoretical Study of Spin Crossover in 30 Iron Complexes
DEFF Research Database (Denmark)
Kepp, Kasper Planeta
2016-01-01
Spin crossover was studied in 30 iron complexes using density functional theory to quantify the direction and magnitude of dispersion, relativistic effects, zero-point energies, and vibrational entropy. Remarkably consistent entropy−enthalpy compensation was identified. Zero-point energies favor...
Graham, Michael J; Krzyaniak, Matthew D; Wasielewski, Michael R; Freedman, Danna E
2017-07-17
Quantum information processing (QIP) has the potential to transform numerous fields from cryptography, to finance, to the simulation of quantum systems. A promising implementation of QIP employs unpaired electronic spins as qubits, the fundamental units of information. Though molecular electronic spins offer many advantages, including chemical tunability and facile addressability, the development of design principles for the synthesis of complexes that exhibit long qubit superposition lifetimes (also known as coherence times, or T 2 ) remains a challenge. As nuclear spins in the local qubit environment are a primary cause of shortened superposition lifetimes, we recently conducted a study which employed a modular spin-free ligand scaffold to place a spin-laden propyl moiety at a series of fixed distances from an S = 1 / 2 vanadium(IV) ion in a series of vanadyl complexes. We found that, within a radius of 4.0(4)-6.6(6) Å from the metal center, nuclei did not contribute to decoherence. To assess the generality of this important design principle and test its efficacy in a different coordination geometry, we synthesized and investigated three vanadium tris(dithiolene) complexes with the same ligand set employed in our previous study: K 2 [V(C 5 H 6 S 4 ) 3 ] (1), K 2 [V(C 7 H 6 S 6 ) 3 ] (2), and K 2 [V(C 9 H 6 S 8 ) 3 ] (3). We specifically interrogated solutions of these complexes in DMF-d 7 /toluene-d 8 with pulsed electron paramagnetic resonance spectroscopy and electron nuclear double resonance spectroscopy and found that the distance dependence present in the previously synthesized vanadyl complexes holds true in this series. We further examined the coherence properties of the series in a different solvent, MeCN-d 3 /toluene-d 8 , and found that an additional property, the charge density of the complex, also affects decoherence across the series. These results highlight a previously unknown design principle for augmenting T 2 and open new pathways for the
Electron spin resonance of radicals and metal complexes
International Nuclear Information System (INIS)
1993-01-01
The materials are a collection of extended synopsis of papers presented at the conference sessions. The broad area of magnetic techniques applications has been described as well as their spectra interpretation methods. The ESR, NMR, ENDOR and spin echo were applied for studying the radiation and UV induced radicals in chemical and biological systems. Also in the study of complexes of metallic ions (having the paramagnetic properties) and their interaction with the matrix, the magnetic techniques has been commonly used. They are also very convenient tool for the study of reaction kinetics and mechanism as well as interaction of paramagnetic species with themselves and crystal lattice or with the surface as for thee catalytic processes
Merino, J.; Jacko, A. C.; Khosla, A. L.; Powell, B. J.
2017-11-01
We consider layered decorated honeycomb lattices at two-thirds filling, as realized in some trinuclear organometallic complexes. Localized S =1 moments with a single-spin anisotropy emerge from the interplay of Coulomb repulsion and spin molecular-orbit coupling (SMOC). Magnetic anisotropies with bond-dependent exchange couplings occur in the honeycomb layers when the direct intracluster exchange and the spin molecular-orbital coupling are both present. We find that the effective spin exchange model within the layers is an XXZ + 120∘ honeycomb quantum compass model. The intrinsic nonspherical symmetry of the multinuclear complexes leads to very different transverse and longitudinal spin molecular-orbital couplings, which greatly enhances the single-spin and exchange coupling anisotropies. The interlayer coupling is described by an XXZ model with anisotropic biquadratic terms. As the correlation strength increases the system becomes increasingly one-dimensional. Thus, if the ratio of SMOC to the interlayer hopping is small this stabilizes the Haldane phase. However, as the ratio increases there is a quantum phase transition to the topologically trivial "D phase." We also predict a quantum phase transition from a Haldane phase to a magnetically ordered phase at sufficiently strong external magnetic fields.
Spin crossover studies in cationic complexes of iron by using Moessbauer spectroscopy
International Nuclear Information System (INIS)
Vadera, S.R.; Kumar, N.
1990-01-01
The spin transition in two new cationic complexes of iron, i.e. iron bipyridine formate, [Fe(bipy) 3 ](HCOO) 2 .5(HCOOH) and iron bipyridine tetrafluoro borate, [Fe(bipy) 3 ](BF 4 ) 2 .2H 2 O were studied by Moessbauer spectroscopy. From quadrupole splitting values, it was established that at different temperatures both complexes show the coexistence of both high spin state and low spin state at 300 K, while complete transformation to low spin state occurs at 77 K. Both compounds were prepared by electrochemical technique. (author) 12 refs.; 1 fig.; 1 tab
Tracking excited-state charge and spin dynamics in iron coordination complexes
DEFF Research Database (Denmark)
Zhang, Wenkai; Alonso-Mori, Roberto; Bergmann, Uwe
2014-01-01
to spin state, can elucidate the spin crossover dynamics of [Fe(2,2'-bipyridine)(3)](2+) on photoinduced metal-to-ligand charge transfer excitation. We are able to track the charge and spin dynamics, and establish the critical role of intermediate spin states in the crossover mechanism. We anticipate......Crucial to many light-driven processes in transition metal complexes is the absorption and dissipation of energy by 3d electrons(1-4). But a detailed understanding of such non-equilibrium excited-state dynamics and their interplay with structural changes is challenging: a multitude of excited...... states and possible transitions result in phenomena too complex to unravel when faced with the indirect sensitivity of optical spectroscopy to spin dynamics(5) and the flux limitations of ultrafast X-ray sources(6,7). Such a situation exists for archetypal poly-pyridyl iron complexes, such as [Fe(2...
Electron spin resonance characterization of a multi-nitrogen complex in diamond
Iakoubovskii, K
2002-01-01
The W27 centre has been characterized by means of electron spin resonance in natural diamond. The centre exhibits spin S=1, a large spin-spin coupling constant D=99 mT, and a complex hyperfine interaction structure interpreted as originating from interaction of an S=1 electronic system with five nitrogen atoms: two of these sites are equivalent and are located near the S = 1 electrons; three others are nearly equivalent and more remote. The centre is suggested to include a divacancy, where one vacancy, bound to two nitrogen atoms and one carbon atom, has trapped an extra electron, while the second vacancy is bound to three substitutional nitrogen atoms.
Electrical manipulation of spin states in a single electrostatically gated transition-metal complex
DEFF Research Database (Denmark)
Osorio, Edgar A; Moth-Poulsen, Kasper; van der Zant, Herre S J
2010-01-01
We demonstrate an electrically controlled high-spin (S = 5/2) to low-spin (S = 1/2) transition in a three-terminal device incorporating a single Mn(2+) ion coordinated by two terpyridine ligands. By adjusting the gate-voltage we reduce the terpyridine moiety and thereby strengthen the ligand......-field on the Mn-atom. Adding a single electron thus stabilizes the low-spin configuration and the corresponding sequential tunnelling current is suppressed by spin-blockade. From low-temperature inelastic cotunneling spectroscopy, we infer the magnetic excitation spectrum of the molecule and uncover also...... a strongly gate-dependent singlet-triplet splitting on the low-spin side. The measured bias-spectroscopy is shown to be consistent with an exact diagonalization of the Mn-complex, and an interpretation of the data is given in terms of a simplified effective model....
Nuclear inelastic scattering study of a dinuclear iron(II) complex showing a direct spin transition
Energy Technology Data Exchange (ETDEWEB)
Wolny, J. A., E-mail: wolny@physik.uni-kl.de [University of Kaiserslautern, Department of Physics (Germany); Garcia, Y. [Université Catholique de Louvain, Institute of Condensed Matter and Nanosciences, Molecules, Solids and Reactivity (IMCN/MOST) (Belgium); Faus, I.; Rackwitz, S. [University of Kaiserslautern, Department of Physics (Germany); Schlage, K.; Wille, H.-C. [DESY (Germany); Schünemann, V. [University of Kaiserslautern, Department of Physics (Germany)
2016-12-15
The results of the nuclear inelastic scattering (NIS)/nuclear resonance vibrational spectroscopy (NRVS) for the powder spectra of dimeric [Fe {sub 2}L{sub 5}(NCS) {sub 4}] (L = N-salicylidene-4-amino-1,2,4-triazole) complex are presented. This system is spin crossover (SCO) material tagged with a fluorophore that can sense or “feel” the SCO signal ripping through the molecular network and thereby providing an opportunity to register the SCO transition. The spectra have been measured for the low-spin and high-spin phases of the complex. The high-spin isomer reveals one broad band above 200 cm {sup −1}, while the low-spin one displays two intense bands in the range from 390 to 430 cm {sup −1}, accompanied by a number of weaker bands below this area and one at ca. 490 cm {sup −1}. A normal coordinate analysis based on density functional calculations yields the assignment of the spin marker bands to particular molecular modes. In addition the vibrational contribution to the spin transition has been estimated.
Accurate Computed Enthalpies of Spin Crossover in Iron and Cobalt Complexes
DEFF Research Database (Denmark)
Kepp, Kasper Planeta; Cirera, J
2009-01-01
Despite their importance in many chemical processes, the relative energies of spin states of transition metal complexes have so far been haunted by large computational errors. By the use of six functionals, B3LYP, BP86, TPSS, TPSSh, M06L, and M06L, this work studies nine complexes (seven with iron...... effects of first-row transition metal systems. Furthermore, it is shown that given an experimental structure of an iron complex, TPSSh can predict the electronic state corresponding to that experimental structure. We recommend this functional as current state-of-the-art for studying spin crossover...... and two with cobalt) for which experimental enthalpies of spin crossover are available. It is shown that such enthalpies can be used as quantitative benchmarks of a functional's ability to balance electron correlation in both the involved states. TPSSh achieves an unprecedented mean absolute error...
2010-01-01
Temperature and pressure effects on the spin state of ferric ions in the [Fe(sal2-trien)][Ni(dmit)2] spin crossover complex correspondance: Corresponding author. Tel.: +33561333190; fax: +33561553003. (Bousseksou, Azzedine) (Bousseksou, Azzedine) Laboratoire de Chimie de Coordination--> , CNRS UPR8241--> , Toulouse--> - FRANCE (Szilagyi, P.A. Petra A.) Eotvos Lorand University--> ...
The classical-quantum divergence of complexity in modelling spin chains
Directory of Open Access Journals (Sweden)
Whei Yeap Suen
2017-08-01
Full Text Available The minimal memory required to model a given stochastic process - known as the statistical complexity - is a widely adopted quantifier of structure in complexity science. Here, we ask if quantum mechanics can fundamentally change the qualitative behaviour of this measure. We study this question in the context of the classical Ising spin chain. In this system, the statistical complexity is known to grow monotonically with temperature. We evaluate the spin chain's quantum mechanical statistical complexity by explicitly constructing its provably simplest quantum model, and demonstrate that this measure exhibits drastically different behaviour: it rises to a maximum at some finite temperature then tends back towards zero for higher temperatures. This demonstrates how complexity, as captured by the amount of memory required to model a process, can exhibit radically different behaviour when quantum processing is allowed.
Spin-dependent recombination involving oxygen-vacancy complexes in silicon
Franke, David P.; Hoehne, Felix; Vlasenko, Leonid S.; Itoh, Kohei M.; Brandt, Martin S.
2014-05-01
Spin-dependent relaxation and recombination processes in γ-irradiated n-type Czochralski-grown silicon are studied using continuous wave (cw) and pulsed electrically detected magnetic resonance (EDMR). Two processes involving the SL1 center, the neutral excited triplet state of the oxygen-vacancy complex, are observed which can be separated by their different dynamics. One of the processes is the relaxation of the excited SL1 state to the ground state of the oxygen-vacancy complex, the other a charge transfer between 31P donors and SL1 centers forming close pairs, as indicated by electrically detected electron double resonance. For both processes, the recombination dynamics is studied with pulsed EDMR techniques. We demonstrate the feasibility of true zero-field cw and pulsed EDMR for spin-1 systems and use this to measure the lifetimes of the different spin states of SL1 also at vanishing external magnetic field.
Spin-polarized transport through single-molecule magnet Mn6 complexes
Cremades, Eduard
2013-01-01
The coherent transport properties of a device, constructed by sandwiching a Mn6 single-molecule magnet between two gold surfaces, are studied theoretically by using the non-equilibrium Green\\'s function approach combined with density functional theory. Two spin states of such Mn6 complexes are explored, namely the ferromagnetically coupled configuration of the six MnIII cations, leading to the S = 12 ground state, and the low S = 4 spin state. For voltages up to 1 volt the S = 12 ground state shows a current one order of magnitude larger than that of the S = 4 state. Furthermore this is almost completely spin-polarized, since the Mn6 frontier molecular orbitals for S = 12 belong to the same spin manifold. As such the high-anisotropy Mn6 molecule appears as a promising candidate for implementing, at the single molecular level, both spin-switches and low-temperature spin-valves. © 2013 The Royal Society of Chemistry.
Spin crossover in Fe(II) complexes with N4S2 coordination
DEFF Research Database (Denmark)
Arroyave, Alejandra; Lennartson, Anders; Dragulescu-Andrasi, Alina
2016-01-01
A systematic study of a series of Fe(II) complexes with the tetradentate N2S2-binding ligand and NCX− coligands (X = S, Se, BH3) conclusively demonstrates the occurrence of temperature-driven spin crossover (SCO), which is rarely observed for the Fe(II) ion in the N4S2 coordination environment...
Are octahedral ruthenium (II/III) and osmium (II/III) complexes always low-spin?
Czech Academy of Sciences Publication Activity Database
Srnec, Martin; Chalupský, Jakub; Rulíšek, Lubomír
2008-01-01
Roč. 73, č. 10 (2008), s. 1231-1244 ISSN 0010-0765 R&D Projects: GA MŠk LC512 Institutional research plan: CEZ:AV0Z40550506 Keywords : ruthenium complexes * osmium * spin state * electronic spectra Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.784, year: 2008
Spin-dependent recombination involving oxygen-vacancy complexes in silicon
Franke, David P.; Hoehne, Felix; Vlasenko, Leonid S.; Itoh, Kohei M.; Brandt, Martin S.
2014-01-01
Spin-dependent relaxation and recombination processes in $\\gamma$-irradiated $n$-type Czochralski-grown silicon are studied using continuous wave (cw) and pulsed electrically detected magnetic resonance (EDMR). Two processes involving the SL1 center, the neutral excited triplet state of the oxygen-vacancy complex, are observed which can be separated by their different dynamics. One of the processes is the relaxation of the excited SL1 state to the ground state of the oxygen-vacancy complex, t...
High-spin Mn-oxo complexes and their relevance to the oxygen-evolving complex within photosystem II.
Gupta, Rupal; Taguchi, Taketo; Lassalle-Kaiser, Benedikt; Bominaar, Emile L; Yano, Junko; Hendrich, Michael P; Borovik, A S
2015-04-28
The structural and electronic properties of a series of manganese complexes with terminal oxido ligands are described. The complexes span three different oxidation states at the manganese center (III-V), have similar molecular structures, and contain intramolecular hydrogen-bonding networks surrounding the Mn-oxo unit. Structural studies using X-ray absorption methods indicated that each complex is mononuclear and that oxidation occurs at the manganese centers, which is also supported by electron paramagnetic resonance (EPR) studies. This gives a high-spin Mn(V)-oxo complex and not a Mn(IV)-oxy radical as the most oxidized species. In addition, the EPR findings demonstrated that the Fermi contact term could experimentally substantiate the oxidation states at the manganese centers and the covalency in the metal-ligand bonding. Oxygen-17-labeled samples were used to determine spin density within the Mn-oxo unit, with the greatest delocalization occurring within the Mn(V)-oxo species (0.45 spins on the oxido ligand). The experimental results coupled with density functional theory studies show a large amount of covalency within the Mn-oxo bonds. Finally, these results are examined within the context of possible mechanisms associated with photosynthetic water oxidation; specifically, the possible identity of the proposed high valent Mn-oxo species that is postulated to form during turnover is discussed.
High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II
Gupta, Rupal; Taguchi, Taketo; Lassalle-Kaiser, Benedikt; Bominaar, Emile L.; Yano, Junko; Hendrich, Michael P.; Borovik, A. S.
2015-01-01
The structural and electronic properties of a series of manganese complexes with terminal oxido ligands are described. The complexes span three different oxidation states at the manganese center (III–V), have similar molecular structures, and contain intramolecular hydrogen-bonding networks surrounding the Mn–oxo unit. Structural studies using X-ray absorption methods indicated that each complex is mononuclear and that oxidation occurs at the manganese centers, which is also supported by electron paramagnetic resonance (EPR) studies. This gives a high-spin MnV–oxo complex and not a MnIV–oxy radical as the most oxidized species. In addition, the EPR findings demonstrated that the Fermi contact term could experimentally substantiate the oxidation states at the manganese centers and the covalency in the metal–ligand bonding. Oxygen-17–labeled samples were used to determine spin density within the Mn–oxo unit, with the greatest delocalization occurring within the MnV–oxo species (0.45 spins on the oxido ligand). The experimental results coupled with density functional theory studies show a large amount of covalency within the Mn–oxo bonds. Finally, these results are examined within the context of possible mechanisms associated with photosynthetic water oxidation; specifically, the possible identity of the proposed high valent Mn–oxo species that is postulated to form during turnover is discussed. PMID:25852147
Polymorphism in the spin-crossover ferric complexes [(TPA)Fe(III)(TCC)]PF6.
Collet, Eric; Boillot, Marie Laure; Hebert, Johan; Moisan, Nicolas; Servol, Marina; Lorenc, Maciej; Toupet, Loïc; Buron-Le Cointe, Marylise; Tissot, Antoine; Sainton, Joelle
2009-08-01
We have identified two polymorphs of the molecular complex [(TPA)Fe((III))(TCC)]PF(6) [TPA = tris(2-pyridylmethyl)amine and TCC = 3,4,5,6-tetrachlorocatecholate dianion]: one is monoclinic and the other is orthorhombic. By lowering the temperature both undergo a thermal spin-crossover between a high-spin (S = 5/2) and a low-spin (S = 1/2) state, which we detected by magnetic, optical and X-ray diffraction measurements. The thermal crossover is only slightly shifted between the polymorphs. Their crystalline structures consist of similar cation layers alternating with PF(6) anion layers, packed differently in the two polymorphs. The magnetic and optical properties of the polymorphs are presented.
Lisewski, Andreas Martin; Lichtarge, Olivier
2010-08-01
Recurrent international financial crises inflict significant damage to societies and stress the need for mechanisms or strategies to control risk and tamper market uncertainties. Unfortunately, the complex network of market interactions often confounds rational approaches to optimize financial risks. Here we show that investors can overcome this complexity and globally minimize risk in portfolio models for any given expected return, provided the margin requirement remains below a critical, empirically measurable value. In practice, for markets with centrally regulated margin requirements, a rational stabilization strategy would be keeping margins small enough. This result follows from ground states of the random field spin glass Ising model that can be calculated exactly through convex optimization when relative spin coupling is limited by the norm of the network’s Laplacian matrix. In that regime, this novel approach is robust to noise in empirical data and may be also broadly relevant to complex networks with frustrated interactions that are studied throughout scientific fields.
Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes.
Dugan, Thomas R; Bill, Eckhard; MacLeod, K Cory; Brennessel, William W; Holland, Patrick L
2014-03-03
Very few hydride complexes are known in which the metals have a high-spin electronic configuration. We describe the characterization of several high-spin iron(II) hydride/deuteride isotopologues and their exchange reactions with one another and with H2/D2. Though the hydride/deuteride signal is not observable in NMR spectra, the choice of isotope has an influence on the chemical shifts of distant protons in the dimers through the paramagnetic isotope effect on chemical shift. This provides the first way to monitor the exchange of H and D in the bridging positions of these hydride complexes. The rate of exchange depends on the size of the supporting ligand, and this is consistent with the idea that H2/D2 exchange into the hydrides occurs through the dimeric complexes rather than through a transient monomer. The understanding of H/D exchange mechanisms in these high-spin iron hydride complexes may be relevant to postulated nitrogenase mechanisms.
Energy Technology Data Exchange (ETDEWEB)
Abdallah, Samer A., E-mail: samer.abdallah@eecs.qmul.ac.uk [School of Electronic Engineering and Computer Science, Queen Mary University of London, London E1 4NS (United Kingdom); Plumbley, Mark D., E-mail: mark.plumbley@eecs.qmul.ac.uk [School of Electronic Engineering and Computer Science, Queen Mary University of London, London E1 4NS (United Kingdom)
2012-01-09
We propose the binding information as an information theoretic measure of complexity between multiple random variables, such as those found in the Ising or Potts models of interacting spins, and compare it with several previously proposed measures of statistical complexity, including excess entropy, Bialek et al.'s predictive information, and the multi-information. We discuss and prove some of the properties of binding information, particularly in relation to multi-information and entropy, and show that, in the case of binary random variables, the processes which maximise binding information are the ‘parity’ processes. The computation of binding information is demonstrated on Ising models of finite spin systems, showing that various upper and lower bounds are respected and also that there is a strong relationship between the introduction of high-order interactions and an increase of binding-information. Finally we discuss some of the implications this has for the use of the binding information as a measure of complexity. -- Highlights: ► We introduce ‘binding information’ as a entropic/statistical measure of complexity. ► Binding information (BI) is related to earlier notions of predictive information. ► We derive upper and lower bounds of BI relation to entropy and multi-information. ► Parity processes found to maximise BI in finite sets of binary random variables. ► Application to spin glasses shows highest BI obtained with high-order interactions.
Insights on the Structural Details of Endonuclease EcoRI-DNA Complexes by Electron Spin Resonance
Sarver, Jessica
2009-03-01
Pulsed electron spin resonance (ESR) was used to probe the binding specificity of EcoRI, a restriction endonuclease. Using site-directed spin labeling, a nitroxide side chain was incorporated into the protein, enabling the use of ESR to study structural details of EcoRI. Distance measurements were performed on EcoRI mutants when bound to varying sequences of DNA using the Double Electron-Electron Resonance experiment. These distances demonstrated that the average structure in the arm regions of EcoRI, thought to play a major role in binding specificity, is the same when the protein binds to different sequences of DNA. Also, it was determined that the arms exhibit higher flexibility when bound to sequences other than the specific sequence due to the larger distance distributions acquired from these spin labeled complexes. Molecular dynamics (MD) simulations were performed on the spin-label-modified specific EcoRI-DNA crystal structure to model the average nitroxide orientation. The distance distributions from MD were found to be narrower than experiment, indicating the need for a more rigorous sampling of the nitroxide conformers in silico.
Tadyszak, Krzysztof; Rudowicz, Czesław; Ohta, Hitoshi; Sakurai, Takahiro
2017-10-01
The spin Hamiltonian (SH) parameters experimentally determined by EMR (EPR) may be corroborated or otherwise using various theoretical modeling approaches. To this end semiempirical modeling is carried out for high-spin (S=2) manganese (III) 3d 4 ions in complex of tetraphenylporphyrinato manganese (III) chloride (MnTPPCl). This modeling utilizes the microscopic spin Hamiltonians (MSH) approach developed for the 3d 4 and 3d 6 ions with spin S=2 at orthorhombic and tetragonal symmetry sites in crystals, which exhibit an orbital singlet ground state. Calculations of the zero-field splitting (ZFS) parameters and the Zeeman electronic (Ze) factors (g || =g z , g ⊥ =g x =g y ) are carried out for wide ranges of values of the microscopic parameters using the MSH/VBA package. This enables to examine the dependence of the theoretically determined ZFS parameters b k q (in the Stevens notation) and the Zeeman factors g i on the spin-orbit (λ), spin-spin (ρ) coupling constant, and the ligand-field energy levels (Δ i ) within the 5 D multiplet. The results are presented in suitable tables and graphs. The values of λ, ρ, and Δ i best describing Mn(III) ions in MnTPPCl are determined by matching the theoretical second-rank ZFSP b 2 0 (D) parameter and the experimental one. The fourth-rank ZFS parameters (b 4 0 , b 4 4 ) and the ρ (spin-spin)-related contributions, which have been omitted in previous studies, are considered for the first time here and are found important. Semiempirical modeling results are compared with those obtained recently by the density functional theory (DFT) and/or ab initio methods. Copyright © 2017 Elsevier Inc. All rights reserved.
Komeda, Tadahiro; Katoh, Keiichi; Yamashita, Masahiro
2014-05-01
We review recent studies of double-decker and triple-decker phthalocyanine (Pc) molecules adsorbed on surfaces in terms of the bonding configuration, electronic structure and spin state. The Pc molecule has been studied extensively in surface science. A Pc molecule can contain various metal atoms at the center, and the class of the molecule is called as metal phthalocyanine (MPc). If the center metal has a large radius, like as lanthanoid metals, it becomes difficult to incorporate the metal atom inside of the Pc ring. Pc ligands are placed so as to sandwich the metal atom, where the metal atom is placed out of the Pc plane. The molecule in this configuration is called as a multilayer-decker Pc molecule. After the finding that the double-decker Pc lanthanoid complex shows single-molecule magnet (SMM) behavior, it has attracted a large attention. This is partly due to a rising interest for the ‘molecular spintronics’, in which the freedoms of spin and charge of an electron are applied to the quantum process of information. SMMs represent a class of compounds in which a single molecule behaves as a magnet. The reported blocking temperature, below which a single SMM molecule works as an quantum magnet, has been increasing with the development in the molecular design and synthesis techniques of multiple-decker Pc complex. However, even the bulk properties of these molecules are promising for the use of electronic materials, the films of multi-decker Pc molecules is less studied than those for the MPc molecules. An intriguing structural property is expected for the multi-decker Pc molecules since the Pc planes are linked by metal atoms. This gives an additional degree of freedom to the rotational angle between the two Pc ligands, and they can make a wheel-like symmetric rotation. Due to a simple and well-defined structure of a multi-decker Pc complex, the molecule can be a model molecule for molecular machine studies. The multi-decker Pc molecules can provide
DEFF Research Database (Denmark)
Døssing, Anders Rørbæk; Wolf, Matthias M. N.; Gross, Ruth
2008-01-01
The photoinduced low-spin (S = 0) to high-spin (S = 2) transition of the iron(II) spin-crossover systems [Fe(btpa)](PF6)2 and [Fe(b(bdpa))](PF6)2 in solution have been studied for the first time by means of ultrafast transient infrared spectroscopy at room temperature. Negative and positive inf...... absorption cross sections. The simulated infrared difference spectra are dominated by an increase of the absorption cross section upon high-spin state formation in accordance with the experimental infrared spectra....... The photoinduced low-spin (S = 0) to high-spin (S = 2) transition of the iron(II) spin-crossover systems [Fe(btpa)](PF6)2 and [Fe(b(bdpa))](PF6)2 in solution have been studied for the first time by means of ultrafast transient infrared spectroscopy at room temperature. Negative and positive...... infrared difference bands between 1000 and 1065 cm-1 that appear within the instrumental system response time of 350 fs after excitation at 387 nm display the formation of the vibrationally unrelaxed and hot high-spin 5T2 state. Vibrational relaxation is observed and characterized by the time constants 9...
Baishya, Bikash; Reddy, G N Manjunatha; Prabhu, Uday Ramesh; Row, T N Guru; Suryaprakash, N
2008-10-23
The proton NMR spectra of fluorine-substituted benzamides are very complex (Figure 1) due to severe overlap of (1)H resonances from the two aromatic rings, in addition to several short and long-range scalar couplings experienced by each proton. With no detectable scalar couplings between the inter-ring spins, the (1)H NMR spectra can be construed as an overlap of spectra from two independent phenyl rings. In the present study we demonstrate that it is possible to separate the individual spectrum for each aromatic ring by spin system filtering employing the multiple-quantum-single-quantum correlation methodology. Furthermore, the two spin states of fluorine are utilized to simplify the spectrum corresponding to each phenyl ring by the spin-state selection. The demonstrated technique reduces spectral complexity by a factor of 4, in addition to permitting the determination of long-range couplings of less than 0.2 Hz and the relative signs of heteronuclear couplings. The technique also aids the judicious choice of the spin-selective double-quantum-single-quantum J-resolved experiment to determine the long-range homonuclear couplings of smaller magnitudes.
arXiv Spin models in complex magnetic fields: a hard sign problem
de Forcrand, Philippe
2018-01-01
Coupling spin models to complex external fields can give rise to interesting phenomena like zeroes of the partition function (Lee-Yang zeroes, edge singularities) or oscillating propagators. Unfortunately, it usually also leads to a severe sign problem that can be overcome only in special cases; if the partition function has zeroes, the sign problem is even representation-independent at these points. In this study, we couple the N-state Potts model in different ways to a complex external magnetic field and discuss the above mentioned phenomena and their relations based on analytic calculations (1D) and results obtained using a modified cluster algorithm (general D) that in many cases either cures or at least drastically reduces the sign-problem induced by the complex external field.
DEFF Research Database (Denmark)
Zhang, Wenkai; Kjær, Kasper Skov; Alonso-Mori, Roberto
2017-01-01
iron complexes with four cyanide (CN-;) ligands and one 2,2′-bipyridine (bpy) ligand. This enables MLCT excited state and metal-centered excited state energies to be manipulated with partial independence and provides a path to suppressing spin crossover. We have combined X-ray Free-Electron Laser (XFEL......) Kβ hard X-ray fluorescence spectroscopy with femtosecond time-resolved UV-visible absorption spectroscopy to characterize the electronic excited state dynamics initiated by MLCT excitation of [Fe(CN)4(bpy)]2-. The two experimental techniques are highly complementary; the time-resolved UV...
The complexity of translationally invariant low-dimensional spin lattices in 3D
Bausch, Johannes; Piddock, Stephen
2017-11-01
In this theoretical paper, we consider spin systems in three spatial dimensions and consider the computational complexity of estimating the ground state energy, known as the local Hamiltonian problem, for translationally invariant Hamiltonians. We prove that the local Hamiltonian problem for 3D lattices with face-centered cubic unit cells and 4-local translationally invariant interactions between spin-3/2 particles and open boundary conditions is QMAEXP-complete, where QMAEXP is the class of problems which can be verified in exponential time on a quantum computer. We go beyond a mere embedding of past hard 1D history state constructions, for which the local spin dimension is enormous: even state-of-the-art constructions have local dimension 42. We avoid such a large local dimension by combining some different techniques in a novel way. For the verifier circuit which we embed into the ground space of the local Hamiltonian, we utilize a recently developed computational model, called a quantum ring machine, which is especially well suited for translationally invariant history state constructions. This is encoded with a new and particularly simple universal gate set, which consists of a single 2-qubit gate applied only to nearest-neighbour qubits. The Hamiltonian construction involves a classical Wang tiling problem as a binary counter which translates one cube side length into a binary description for the encoded verifier input and a carefully engineered history state construction that implements the ring machine on the cubic lattice faces. These novel techniques allow us to significantly lower the local spin dimension, surpassing the best translationally invariant result to date by two orders of magnitude (in the number of degrees of freedom per coupling). This brings our models on par with the best non-translationally invariant construction.
Directory of Open Access Journals (Sweden)
Hrishit Banerjee
2017-07-01
Full Text Available Metal organic complexes consisting of transition metal centers linked by organic ligands, may show bistability which enables the system to be observed in two different electronic states depending on external condition. One of the spectacular examples of molecular bistability is the spin-crossover phenomena. Spin-Crossover (SCO describes the phenomena in which the transition metal ion in the complex under the influence of external stimuli may show a crossover between a low-spin and high-spin state. For applications in memory devices, it is desirable to make the SCO phenomena cooperative, which may happen with associated hysteresis effect. In this respect, compounds with extended solid state structures containing metal ions connected by organic spacer linkers like linear polymers, coordination network solids are preferred candidates over isolated molecules or molecular assemblies. The microscopic understanding, design and control of mechanism driving cooperativity, however, are challenging. In this review we discuss the recent theoretical progress in this direction.
Rational design of single-ion magnets and spin qubits based on mononuclear lanthanoid complexes.
Baldoví, José J; Cardona-Serra, Salvador; Clemente-Juan, Juan M; Coronado, Eugenio; Gaita-Ariño, Alejandro; Palii, Andrew
2012-11-19
Here we develop a general approach to calculating the energy spectrum and the wave functions of the low-lying magnetic levels of a lanthanoid ion submitted to the crystal field created by the surrounding ligands. This model allows us to propose general criteria for the rational design of new mononuclear lanthanoid complexes behaving as single-molecule magnets (SMMs) or acting as robust spin qubits. Three typical environments exhibited by these metal complexes are considered, namely, (a) square antiprism, (b) triangular dodecahedron, and (c) trigonal prism. The developed model is used to explain the properties of some representative examples showing these geometries. Key questions in this area, such as the chemical tailoring of the superparamagnetic energy barrier, tunneling gap, or spin relaxation time, are discussed. Finally, in order to take into account delocalization and/or covalent effects of the ligands, this point-charge model is complemented with ab initio calculations, which provide accurate information on the charge distribution around the metal, allowing for an explanation of the SMM behavior displayed by some sandwich-type organometallic compounds.
High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study.
Mantel, Claire; Chen, Hongyu; Crabtree, Robert H; Brudvig, Gary W; Pécaut, Jacques; Collomb, Marie-Noëlle; Duboc, Carole
2005-03-01
The isolation, structural characterization, and electronic properties of two six-coordinated chloromanganese (III) complexes, [Mn(terpy)(Cl)3] (1) and [Mn(Phterpy)(Cl)3] (2), are reported (terpy = 2,2':6'2"-terpyridine, Phterpy = 4'-phenyl-2,2':6',2"-terpyridine). These complexes complement a series of mononuclear azide and fluoride Mn(lll) complexes synthesized with neutral N-tridentate ligands, [Mn(L)(X)3] (X = F- or N3 and L = terpy or bpea [N,N-bis(2-pyridylmethyl)-ethylamine)], previously described. Similar to these previous complexes, 1 and 2 exhibit a Jahn-Teller distortion of the octahedron, characteristic of a high-spin Mn(III) complex (S = 2). The analysis of the crystallographic data shows that, in both cases, the manganese ion lies in the center of a distorted octahedron characterized by an elongation along the tetragonal axis. Their electronic properties were investigated by multifrequency EPR (190-475 GHz) performed in the solid state at different temperatures (5-15 K). This study confirms our previous results and further shows that: i) the sign of D is correlated with the nature of the tetragonal distortion; ii) the magnitude of D is not sensitive to the nature of the anions in our series of rhombic complexes, contrary to the porphyrinic systems; iii) the [E/D] values (0.124 for 1 and 0.085 for 2) are smaller compared to those found for the [Mn(L)(X)3] complexes (in the range of 0.146 to 0.234); and iv) the E term increases when the ligand-field strength of the equatorial ligands decreases.
Gildea, Brendan; Harris, Michelle M; Gavin, Laurence C; Murray, Caroline A; Ortin, Yannick; Müller-Bunz, Helge; Harding, Charles J; Lan, Yanhua; Powell, Annie K; Morgan, Grace G
2014-06-16
Eleven new mononuclear manganese(III) complexes prepared from two hexadentate ligands, L1 and L2, with different degrees of steric bulk in the substituents are reported. L1 and L2 are Schiff bases resulting from condensation of N,N'-bis(3-aminopropyl)ethylenediamine with 3-methoxy-2-hydroxybenzaldehyde and 3-ethoxy-2-hydroxybenzaldehyde respectively, and are members of a ligand series we have abbreviated as R-Sal2323 to indicate the 323 alkyl connectivity in the starting tetraamine and the substitution (R) on the phenolate ring. L1 hosts a methoxy substituent on both phenolate rings, while L2 bears a larger ethoxy group in the same position. Structural and magnetic properties are reported in comparison with those of a previously reported analogue with L1, namely, [MnL1]NO3, (1e). The BPh4(-) and PF6(-) complexes [MnL1]BPh4, (1a), [MnL2]BPh4, (2a), [MnL1]PF6, (1b'), and [MnL2]PF6, (2b), with both ligands L1 and L2, remain high-spin (HS) over the measured temperature range. However, the monohydrate of (1b') [MnL1]PF6·H2O, (1b), shows gradual spin-crossover (SCO), as do the ClO4(-), BF4(-), and NO3(-) complexes [MnL1]ClO4·H2O, (1c), [MnL2]ClO4, (2c), [MnL1]BF4·H2O, (1d), [MnL2]BF4·0.4H2O, (2d), [MnL1]NO3, (1e), and [MnL2]NO3·EtOH, (2e). The three complexes formed with ethoxy-substituted ligand L2 all show a higher T1/2 than the analogous complexes with methoxy-substituted ligand L1. Analysis of distortion parameters shows that complexes formed with the bulkier ligand L2 exhibit more deformation from perfect octahedral geometry, leading to a higher T1/2 in the SCO examples, where T1/2 is the temperature where the spin state is 50% high spin and 50% low spin. Spin state assignment in the solid state is shown to be solvate-dependent for complexes (1b) and (2e), and room temperature UV-visible and NMR spectra indicate a solution-state spin assignment intermediate between fully HS and fully low spin in 10 complexes, (1a)-(1e) and (2a)-(2e).
Petrenko, T. L.; Bryksa, V. P.
2017-08-01
At present the nitrogen-vacancy (NV) complex in diamond is the most promising defect for application in the area of quantum computing. This provides a stimulus for an extensive search of other defects in semiconductors with similar properties. Recently it was shown that the NCVSi defect complex in SiC is perspectively appropriate for this goal as well. In the present work we perform comparative ab initio studies of NV complexes in diamond and 3C-SiC. We focus both on radiospectroscopic characterization of these defects and on the calculation of the equilibrium concentration of complexes in irradiated crystals. In particular a full set of spin-Hamiltonian parameters including g-tensors, hyperfine tensors and the spin-spin part of zero-field splitting constant Dss were calculated for both negative and neutral charge states as well as for excited quartet states of neutral complexes. Comparison of calculated values with the available experimental data and results of other calculations show good agreement, especially in the case when hybrid and meta-hybrid functionals were used. This makes the unambiguous identification of negative NV complexes in both materials possible. Our calculations reveal that the ground states of neutral complexes are a difficult case for both DFT calculations and experimental observations. This is caused by multi-determinantal behavior of wave function for such complexes, which leads to a large amount of spin contamination and to the broken symmetry solution which appeared for single Slater determinant DFT calculations. Based on the calculated minimum of free energy of neutral and negative complexes in SiC and diamond we obtained the equilibrium concentrations of these complexes depending on the vacancy concentration produced by irradiation. We show that in some dose regions both negative and neutral complexes coexist, while in other regions only one charge state prevails. Comparison of the calculated and experimental dose dependencies for
Szczęśniak, Dominik; Ennaoui, Ahmed; Ahzi, Saïd
2016-09-01
Recently, the transition metal dichalcogenides have attracted renewed attention due to the potential use of their low-dimensional forms in both nano- and opto-electronics. In such applications, the electronic and transport properties of monolayer transition metal dichalcogenides play a pivotal role. The present paper provides a new insight into these essential properties by studying the complex band structures of popular transition metal dichalcogenide monolayers (MX 2, where M = Mo, W; X = S, Se, Te) while including spin-orbit coupling effects. The conducted symmetry-based tight-binding calculations show that the analytical continuation from the real band structures to the complex momentum space leads to nonlinear generalized eigenvalue problems. Herein an efficient method for solving such a class of nonlinear problems is presented and yields a complete set of physically relevant eigenvalues. Solutions obtained by this method are characterized and classified into propagating and evanescent states, where the latter states manifest not only monotonic but also oscillatory decay character. It is observed that some of the oscillatory evanescent states create characteristic complex loops at the direct band gap of MX 2 monolayers, where electrons can directly tunnel between the band gap edges. To describe these tunneling currents, decay behavior of electronic states in the forbidden energy region is elucidated and their importance within the ballistic transport regime is briefly discussed.
A low-spin Fe(III) complex with 100-ps ligand-to-metal charge transfer photoluminescence
DEFF Research Database (Denmark)
Chabera, Pavel; Liu, Yizhu; Prakash, Om
2017-01-01
sufficiently to realize a long charge-transfer lifetime of 100 picoseconds (ps) and room-temperature photoluminescence. This species is a low-spin Fe(III) d(5) complex, and emission occurs from a long-lived doublet ligand-to-metal charge-transfer ((LMCT)-L-2) state that is rarely seen for transition-metal...... complexes(4,16,17). The absence of intersystem crossing, which often gives rise to large excited-state energy losses in transition-metal complexes, enables the observation of spin-allowed emission directly to the ground state and could be exploited as an increased driving force in photochemical reactions......Transition-metal complexes are used as photosensitizers(1), in light-emitting diodes, for biosensing and in photocatalysis(2). A key feature in these applications is excitation from the ground state to a charge-transfer state(3,4); the long charge-transfer-state lifetimes typical for complexes...
Czech Academy of Sciences Publication Activity Database
Kumbhakar, D.; Sarkar, B.; Maji, S.; Mobin, S. M.; Fiedler, Jan; Urbanos, F. A.; Jimenez-Aparicio, R.; Kaim, W.; Lahiri, G. K.
2008-01-01
Roč. 130, č. 51 (2008), s. 17575-17583 ISSN 0002-7863 R&D Projects: GA MŠk OC 139; GA MŠk LC510 Institutional research plan: CEZ:AV0Z40400503 Keywords : intramolecular valence * spin interaction * diruthenium complex Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 8.091, year: 2008
Mos, B.; Verkerk, P.; Pouget, S.; Van Zon, A.; Bel, G.J.; De Leeuw, S.W.; Eisenbach, C.D.
2000-01-01
We determined the self part of the intermediate scattering function in liquid polyethyleneoxide (PEO) and PEO–alkali iodide complexes by means of neutron spin-echo spectroscopy and molecular dynamics (MD) computer simulations. We present the first accurate quantitative results on the segmental
Micera, G.; And Others
1984-01-01
Background, procedures, and results are provided for an experiment which examines, through electron spin resonance spectroscopy, complex species formed by cupric and 2,6-dihydroxybenzoate ions in aqueous solutions. The experiment is illustrative of several aspects of inorganic and coordination chemistry, including the identification of species…
Energy Technology Data Exchange (ETDEWEB)
Wolny, Juliusz A., E-mail: wolny@physik.uni-kl.de; Rackwitz, Sergej [University of Kaiserslautern, Department of Physics (Germany); Achterhold, Klaus [Technische Universitaet Muenchen, Department of Physics (Germany); Muffler, Kai; Schuenemann, Volker [University of Kaiserslautern, Department of Physics (Germany)
2012-03-15
The vibrational properties of Fe(II) 1D spin crossover polymers have been characterized by nuclear inelastic scattering (NIS). The complexes under study were the tosylate and perchlorate salts of ([Fe(4-amino-1,2,4-triazole){sub 3}] <{sup +2}){sub n} complexes. The complexes have LS (S = 0) marker bands in the range of 300-500 cm{sup - 1}, while the marker bands corresponding to the HS (S = 2) state are detected between 200 cm{sup - 1} and 300 cm{sup - 1}, in line with the decreasing Fe-N bond strengths during the transition from LS to HS. Accompanying DFT calculations using the functional B3LYP and the basis set CEP-31G confirm these assignments.
García-Rubio, Inés; Mitrikas, George
2010-08-01
The wide use of the heme group by nature is a consequence of its unusual "electronic flexibility." Major changes in the electronic structure of this molecule can result from small perturbations in its environment. To understand the way the electronic distribution is dictated by the structure of the heme site, it is extremely important to have methods to reliably determine both of them. In this work we propose a way to obtain this information in ferric low-spin heme centers via the determination of g, A, and Q tensors of the coordinated nitrogens using electron spin echo envelope modulation experiments at Q-band microwave frequencies. The results for two bisimidazole heme model complexes, namely, PPIX(Im)(2) and CPIII(Im)(2), where PPIX is protoporphyrin IX, CPIII is coproporphyrin III, and Im is imidazole, selectively labeled with (15)N on the heme or imidazole nitrogens are presented. The planes of the axial ligands were found to be parallel and oriented approximately along one of the N-Fe-N directions of the slightly ruffled porphyrin ring (approximately 10 degrees ). The spin density was determined to reside in an iron d orbital perpendicular to the heme plane and oriented along the other porphyrin N-Fe-N direction, perpendicular to the axial imidazoles. The benefit of the method presented here lies in the use of Q-band microwave frequencies, which improves the orientation selection, results in no/fewer combination lines in the spectra, and allows separation of the contributions of hyperfine and quadrupole interactions due to the fulfillment of the exact cancellation condition at g ( Z ) and the possibility of performing hyperfine decoupling experiments at the g ( X ) observer position. These experimental advantages make the interpretation of the spectra straightforward, which results in precise and reliable determination of the structure and spin distribution.
Directory of Open Access Journals (Sweden)
Wasinee Phonsri
2017-08-01
Full Text Available The structural and magnetic properties of a range of new iron(III bis-tridentate Schiff base complexes are described with emphasis on how intermolecular structural interactions influence spin states and spin crossover (SCO in these d5 materials. Three pairs of complexes were investigated. The first pair are the neutral, heteroleptic complexes [Fe(3-OMe-SalEen(thsa] 1 and [Fe(3-MeOSalEen(3-EtOthsa] 2, where 3-R-HSalEen = (E-2-(((2-(ethylaminoethyliminomethyl-6-R-phenol and 3-R-H2thsa = thiosemicarbazone-3-R-salicylaldimine. They display spin transitions above room temperature. However, 2 shows incomplete and gradual change, while SCO in 1 is complete and more abrupt. Lower cooperativity in 2 is ascribed to the lack of π–π interactions, compared to 1. The second pair, cationic species [Fe(3-EtOSalEen2]NO3 3 and [Fe(3-EtOSalEen2]Cl 4 differ only in the counter-anion. They show partial SCO above room temperature with 3 displaying a sharp transition at 343 K. Weak hydrogen bonds from cation to Cl− probably lead to weaker cooperativity in 4. The last pair, CsH2O[Fe(3-MeO-thsa2] 5 and Cs(H2O2[Fe(5-NO2-thsa2] 6, are anionic homoleptic chelates that have different substituents on the salicylaldiminate rings of thsa2−. The Cs cations bond to O atoms of water and the ligands, in unusual ways thus forming attractive 1D and 3D networks in 5 and 6, respectively, and 5 remains HS (high spin at all temperatures while 6 remains LS (low spin. Comparisons are made to other literature examples of Cs salts of [Fe(5-R-thsa2]− (R = H and Br.
Energy Technology Data Exchange (ETDEWEB)
Nakamoto, Akio; Kamebuchi, Hajime, E-mail: cc106909@mail.ecc.u-tokyo.ac.jp [University of Tokyo, Graduate School of Arts and Sciences (Japan); Enomoto, Masaya [Tokyo University of Science, Department of Chemistry, Faculty of Science Division I (Japan); Kojima, Norimichi [University of Tokyo, Graduate School of Arts and Sciences (Japan)
2012-03-15
[Fe(II)(H-trz){sub 3}]-Nafion (trz = triazole) is a transparent spin crossover complex film, where the spin crossover transition between the low-spin (S = 0) and the high-spin (S = 2) states takes place between 225 K and 300 K. In this film, two doublets corresponding to the low-spin and high-spin states were observed in the {sup 57}Fe Moessbauer spectra, reflecting the spin crossover transition. From the analysis of {sup 57}Fe Moessbauer spectra, the Debye temperatures of the low-spin and high-spin sites were estimated at 185 K and 176 K, respectively, in the temperature range between 10 K and 150 K. In this film, the total intensity of the Moessbauer spectra corresponding to the low-spin and high-spin sites drastically decreases above 200 K, reflecting the glass transition of Nafion, where the lattice vibration of [Fe(H-trz){sub 3}]{sub n}{sup 2n+} is softened just as in solution due to micro-Brown motion of the segment of Nafion polymer membrane.
Energy Technology Data Exchange (ETDEWEB)
Andersen, Richard; Walter, Marc D.; Berg, David J.; Andersen, Richard A.
2006-11-04
The paramagnetic 1:1 coordination complexes of (C5Me5)2Yb with a series of diazabutadiene ligands, RN=C(R')C(R')=NR, where R= CMe3, CHMe2, adamantyl, p-tolyl, p-anisyl, and mesityl when R'=H, and R= p-anisyl when R'= Me, have been prepared. The complexes are paramagnetic, but their magnetic moments are less than expected for the two uncoupled spin carriers, (C5Me5)2Yb(III, 4f13) and the diazabutadiene radical anions (S=1/2), which implies exchange coupling between the spins. The variable temperature 1H NMR spectra show that rotation about the R-N bond is hindered and these barriers are estimated. The barriers are largely determined by steric effects but electronic effects are not unimportant.
Energy Technology Data Exchange (ETDEWEB)
Souchard, J.P.; Massol, M.; Nepveu, F. [Toulouse-3 Univ., 31 (France)
1996-01-01
Superoxide anion is implicated in the pathogenesis of several human diseases including ischaemia, atherosclerosis and inflammation when molecular or enzymatic antioxidant systems cannot regulate its formation. In order to investigate superoxide dismutase (SOD) mimics, a method using Electron Spin Resonance (ESR) has been developed to quantify anti-oxidative activities of Mn(II) compounds. The acetaldehyde / xanthine oxidase system produced superoxide anion and the 5,5-dimethyl-I-pyroline-N-oxide (DMPO) was used as spin trap. The complexing properties of the usual phosphate buffer towards Mn{sup 2+} being not negligible comparatively to those of the studied ligands, activities of free ligands and Mn(II) complexes have been compared according to the buffer, phosphate or organic. (Authors). 7 refs., 1 tab., 2 figs.,.
Optimal Configuration for Relaxation Times Estimation in Complex Spin Echo Imaging
Directory of Open Access Journals (Sweden)
Fabio Baselice
2014-01-01
Full Text Available Many pathologies can be identified by evaluating differences raised in the physical parameters of involved tissues. In a Magnetic Resonance Imaging (MRI framework, spin-lattice T1 and spin-spin T2 relaxation time parameters play a major role in such an identification. In this manuscript, a theoretical study related to the evaluation of the achievable performances in the estimation of relaxation times in MRI is proposed. After a discussion about the considered acquisition model, an analysis on the ideal imaging acquisition parameters in the case of spin echo sequences, i.e., echo and repetition times, is conducted. In particular, the aim of the manuscript consists in providing an empirical rule for optimal imaging parameter identification with respect to the tissues under investigation. Theoretical results are validated on different datasets in order to show the effectiveness of the presented study and of the proposed methodology.
1D iron(II) spin crossover complexes with 1,2,4-triazol-4-yl-propanoic acid
Energy Technology Data Exchange (ETDEWEB)
Railliet, Antoine P.; Naik, Anil D. [Universite Catholique de Louvain, Institute of Condensed Matter and Nanosciences (Belgium); Rotaru, Aurelian [' Stefan cel Mare' University, Department of Electrical Engineering and Computer Science (Romania); Marchand-Brynaert, Jacqueline; Garcia, Yann, E-mail: yann.garcia@uclouvain.be [Universite Catholique de Louvain, Institute of Condensed Matter and Nanosciences (Belgium)
2012-03-15
A series of 1D coordination polymers [Fe(patrz){sub 3}]X{sub 2}{center_dot}solv, (patrz = 1,2,4-triazol-4-yl-propanoic acid; X = BF{sub 4{sup -}}, ClO{sub 4{sup -}}, Cl{sup - }, NO{sub 3}-bar and solv = MeOH or H{sub 2}O) were precipitated from methanol. Their spin crossover properties were studied by temperature dependent SQUID magnetometry and {sup 57}Fe Moessbauer spectroscopy, both for solvated and desolvated complexes. Compounds show gradual incomplete spin crossover with distinct thermochromism, in particular [Fe(patrz){sub 3}](BF{sub 4}){sub 2}{center_dot}MeOH, for which only 27% of Fe{sup II} ions are switched to the low-spin state at 77 K, as determined by a detailed {sup 57}Fe Moessbauer study. Other prominent features of this work are the interesting self assembly of 1D chain with exclusively triazole coordination from patrz ligand despite its ditopic nature and a hysteretic room temperature spin crossover in [Fe(patrz){sub 3}]Cl{sub 2}.
1D iron(II) spin crossover complexes with 1,2,4-triazol-4-yl-propanoic acid
International Nuclear Information System (INIS)
Railliet, Antoine P.; Naik, Anil D.; Rotaru, Aurelian; Marchand-Brynaert, Jacqueline; Garcia, Yann
2012-01-01
A series of 1D coordination polymers [Fe(patrz) 3 ]X 2 ·solv, (patrz = 1,2,4-triazol-4-yl-propanoic acid; X = BF 4 - , ClO 4 - , Cl − , NO 3 -bar and solv = MeOH or H 2 O) were precipitated from methanol. Their spin crossover properties were studied by temperature dependent SQUID magnetometry and 57 Fe Mössbauer spectroscopy, both for solvated and desolvated complexes. Compounds show gradual incomplete spin crossover with distinct thermochromism, in particular [Fe(patrz) 3 ](BF 4 ) 2 ·MeOH, for which only 27% of Fe II ions are switched to the low-spin state at 77 K, as determined by a detailed 57 Fe Mössbauer study. Other prominent features of this work are the interesting self assembly of 1D chain with exclusively triazole coordination from patrz ligand despite its ditopic nature and a hysteretic room temperature spin crossover in [Fe(patrz) 3 ]Cl 2 .
Energy Technology Data Exchange (ETDEWEB)
Canton, S. E. [Department; Zhang, X. [X-ray; Lawson Daku, M. L. [Département; Liu, Y. [Centre; Zhang, J. [School; Alvarez, S. [Departament
2015-01-30
Establishing a tractable yet complete reaction coordinate for the spin-state interconversion in d(4)-d(7) transition metal complexes is an integral aspect of controlling the dynamics that govern their functionality. For spin crossover phenomena, the limitations of a single-mode approximation that solely accounts for an isotropic increase in the metal-ligand bond length have long been recognized for all but the simple octahedral monodentate FeII compounds. However, identifying the coupled deformations that also impact on the unimolecular rate constants remains experimentally and theoretically challenging, especially for samples that do not display long-range order or when crystallization profoundly alters the dynamics. Owing to the rapid progress in ultrafast X-ray absorption spectroscopy (XAS), it is now possible to obtain transient structural information in any physical phase with unprecedented details. Using picosecond XAS and DFT modeling, the structure adopted by the photoinduced high-spin state of solvated [Fe(terpy)(2)](2+) (terpy: 2,2':6',2 ''-terpyridine) has been recently established. Based on these results, the methodology of the continuous shape measure is applied to classify and quantify the short-lived distortion of the first coordination shell. The reaction coordinate of the spin-state interconversion is clearly identified as a double axial bending. This finding sets a benchmark for gauging the influence of first-sphere and second-sphere interactions in the family of FeII complexes that incorporate terpy derivatives. Some implications for the optimization of related photoactive FeII complexes are also outlined.
Krzystek, J.; Telser, Joshua; Pardi, Luca A.; Goldberg, David P.; Hoffman, Brian M.; Brunel, Louis-Claude
1999-12-27
High-field and -frequency electron paramagnetic resonance (HFEPR) spectroscopy has been used to study two complexes of high-spin manganese(III), d(4), S = 2. The complexes studied were (tetraphenylporphyrinato)manganese(III) chloride and (phthalocyanato)manganese(III) chloride. Our previous HFEPR study (Goldberg, D. P.; Telser, J.; Krzystek, J.; Montalban, A. G.; Brunel, L.-C.; Barrett, A. G. M.; Hoffman, B. M. J. Am. Chem. Soc. 1997, 119, 8722-8723) included results on the porphyrin complex; however, we were unable to obtain true powder pattern HFEPR spectra, as the crystallites oriented in the intense external magnetic field. In this work we are now able to immobilize the powder, either in an n-eicosane mull or KBr pellet and obtain true powder pattern spectra. These spectra have been fully analyzed using spectral simulation software, and a complete set of spin Hamiltonian parameters has been determined for each complex. Both complexes are rigorously axial systems, with relatively low magnitude zero-field splitting: D approximately -2.3 cm(-)(1) and g values quite close to 2.00. Prior to this work, no experimental nor theoretical data exist for the metal-based electronic energy levels in Mn(III) complexes of porphyrinic ligands. This lack of information is in contrast to other transition metal complexes and is likely due to the dominance of ligand-based transitions in the absorption spectra of Mn(III) complexes of this type. We have therefore made use of theoretical values for the electronic energy levels of (phthalocyanato)copper(II), which electronically resembles these Mn(III) complexes. This analogy works surprisingly well in terms of the agreement between the calculated and experimentally determined EPR parameters. These results show a significant mixing of the triplet (S = 1) excited state with the quintet (S = 2) ground state in Mn(III) complexes with porphyrinic ligands. This is in agreement with the experimental observation of lower spin ground states in
Solvent-Induced Polymorphism of Iron(II Spin Crossover Complexes
Directory of Open Access Journals (Sweden)
Ivan Šalitroš
2016-07-01
Full Text Available Two new mononuclear iron(II compounds (1 and (2 of the general formula [Fe(L2](BF42·nCH3CN (L = 4-(2-bromoethyn-1-yl-2,6-bis(pyrazol-1-ylpyridine, n = 1 for (1 and n = 2 for compound (2, were synthesized. The room temperature crystallization afforded concomitant formation of two different solvent analogues: compound (1 exhibiting triclinic P-1 and compound (2 monoclinic C2/c symmetry. Single-crystal X-ray studies confirmed the presence of the LS (low-spin state for both compounds at 180 K and of the HS (high-spin state for compound (2 at 293 K, in full agreement with the magnetic investigations for both solvent polymorphs. Compound (1 exhibits spin transition above 293 K followed by subsequent solvent liberation, while the spin transition of (2 takes already place at 237 K. After complete solvent removal from the crystal lattice, compound (1d (the desolvated polymorph derived from (1 exhibits spin transition centered at 342 K accompanied by a thermal hysteresis loop, while the analogous compound (2d (the desolvated derivate of compound (2 remains blocked in the HS state over all the investigated temperature range.
Burton, J D; Tsymbal, E Y
2011-04-15
A giant tunneling electroresistance effect may be achieved in a ferroelectric tunnel junction by exploiting the magnetoelectric effect at the interface between the ferroelectric barrier and a magnetic La(1-x)Sr(x)MnO3 electrode. Using first-principles density-functional theory we demonstrate that a few magnetic monolayers of La(1-x)Sr(x)MnO3 near the interface act, in response to ferroelectric polarization reversal, as an atomic-scale spin valve by filtering spin-dependent current. This produces more than an order of magnitude change in conductance, and thus constitutes a giant resistive switching effect.
Energy Technology Data Exchange (ETDEWEB)
Liu, Cunming; Zhang, Jianxin [State; Lawson Daku, Latévi M. [Département; Gosztola, David; Canton, Sophie E. [ELI-ALPS, ELI-HU Non-Profit Ltd., Dugonics ter 13, Szeged 6720, Hungary; Attosecond; Zhang, Xiaoyi
2017-11-17
Investigating the photoinduced electronic and structural response of bistable molecular building blocks incorporating transition metals in solution phase constitutes a necessary stepping stone for steering their properties towards applications and perfomance optimizations. This work presents a detailed X-ray transient absorption (XTA) spectroscopy study of a prototypical spin crossover (SCO) complex [FeII(mbpy)3]2+ (where mbpy=4,4’-dimethyl-2,2’-bipyridine) with a [FeIIN6] first coordination shell in water (H2O) and acetonitrile (CH3CN). The unprecedented data quality of the XTA spectra together with the direct fitting of the difference spectra in k space using a large number of scattering paths enables resolving the subtle difference in the photoexcited structures of an FeII complex in two solvents for the first time. Compared to the low spin (LS) 1A1 state, the average Fe-N bond elongations for the photoinduced high spin (HS) 5T2 state are found to be 0.181 . 0.003 Å in H2O and 0.199 . 0.003 Å in CH3CN. This difference in structural response is attributed to ligand-solvent interactions that are stronger in H2O than in CH3CN for the HS excited state. Our studies demonstrate that, although the metal center of [FeII(mbpy)3]2+ could have been expected to be rather shielded by the three bidentate ligands with quasi-octahedral-coordination, the ligand field strength in the HS excited state is nevertheless indirectly affected by solvation that modifies the charge distribution within the Fe-N covalent bonds. More generally, this work highlights the importance of including solvation effects in order to develop a generalized understanding of the spin-state switching at the atomic level.
Spin-Circuit Representation of Spin Pumping
Roy, Kuntal
2017-07-01
Circuit theory has been tremendously successful in translating physical equations into circuit elements in an organized form for further analysis and proposing creative designs for applications. With the advent of new materials and phenomena in the field of spintronics and nanomagnetics, it is imperative to construct the spin-circuit representations for different materials and phenomena. Spin pumping is a phenomenon by which a pure spin current can be injected into the adjacent layers. If the adjacent layer is a material with a high spin-orbit coupling, a considerable amount of charge voltage can be generated via the inverse spin Hall effect allowing spin detection. Here we develop the spin-circuit representation of spin pumping. We then combine it with the spin-circuit representation for the materials having spin Hall effect to show that it reproduces the standard results as in the literature. We further show how complex multilayers can be analyzed by simply writing a netlist.
International Nuclear Information System (INIS)
Sato, Taichi; Nakamura, Takato
1981-01-01
In the extraction of vanadium (IV) from aqueous solutions containing hydrochloric acid and/or a mixture of hydrochloric acid and lithium chloride by bis(2-ethylhexyl) hydrogenphosphate (DEHPA; HX), trioctylmethylammonium chloride (Aliquat-336), trioctylamine (TOA), trioctylphosphine oxide (TOPO) and tributyl phosphate (TBP), the complexes formed in the organic phases have been examined by spectrophotometry and electron spin resonance spectroscopy. It is found that in the extraction by DEHPA, the vanadium in the organic phase exists as the monomeric species, VO(X 2 H) 2 , or the polymeric one, (VOX 2 )sub(n), and that in the extractions by Aliquat-336, TOA, TOPO, and TBP, tetravalent vanadium complexes are stable in the organic phases extracted from a mixed solution of hydrochloric acid and lithium chloride, while complexes containing pentavalent vanadium and VOV 4+ ions are formed in the organic phases extracted from hydrochloric acid solutions. (author)
Light-induced spin crossover observed for a Fe(II) complex embedded in a Nafion membrane
International Nuclear Information System (INIS)
Winkler, H.; Rusanov, V.; McGarvey, J. J.; Toftlund, H.; Trautwein, A. X.; Wolny, J. A.
2006-01-01
Light-induced spin crossover has been observed for the first time by means of Moessbauer spectroscopy for a Fe(II) complex embedded in a Nafion membrane. The results obtained confirm other independent observations we have made, which point to the possibility of generating a long-lived HS state by means of laser irradiation of the same system (C. Brady, PhD thesis Queens University, Belfast 2002; J.A. Wolny, H. Toftlund, J.J. McGarvey, C. Brady, manuscript in preparation).
Czech Academy of Sciences Publication Activity Database
Laguta, Valentyn; Nikl, Martin
2013-01-01
Roč. 250, č. 2 (2013), s. 254-260 ISSN 0370-1972 R&D Projects: GA MŠk(CZ) LM2011029; GA ČR GAP204/12/0805; GA AV ČR IAA100100810 Grant - others:SAFMAT(XE) CZ.2.16/3.1.00/22132 Institutional support: RVO:68378271 Keywords : scintillators * point defects * electron spin resonance * polarons Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.605, year: 2013
Top Quark Pair Properties - Spin Correlation, Charge Asymmetry, and Complex Final States - at ATLAS
Directory of Open Access Journals (Sweden)
Brost Elizabeth
2014-04-01
Full Text Available We present measurements of top quark pair properties performed with the ATLAS detector at the Large Hadron Collider in proton-proton collisions at a center-of-mass energy of √s = 7 TeV. The latest measurements of spin correlation and charge asymmetry in tt¯$t\\overline t $ events, as well as measurements of the cross section for tt¯$t\\overline t $ production in association with vector bosons, are presented.
High-spin Mn-oxo complexes and their relevance to the oxygen-evolving complex within photosystem II
Gupta, R; Taguchi, T; Lassalle-Kaiser, B; Bominaar, EL; Yano, J; Hendrich, MP; Borovik, AS
2015-01-01
© 2015, National Academy of Sciences. All rights reseved. The structural and electronic properties of a series of manganese complexes with terminal oxido ligands are described. The complexes span three different oxidation states at the manganese center (III-V), have similar molecular structures, and contain intramolecular hydrogen-bonding networks surrounding the Mn-oxo unit. Structural studies using X-ray absorption methods indicated that each complex is mononuclear and that oxidation occurs...
Cramer, Joel; Seifert, Tom; Kronenberg, Alexander; Fuhrmann, Felix; Jakob, Gerhard; Jourdan, Martin; Kampfrath, Tobias; Kläui, Mathias
2018-02-14
We measure the inverse spin Hall effect of Cu 1-x Ir x thin films on yttrium iron garnet over a wide range of Ir concentrations (0.05 ⩽ x ⩽ 0.7). Spin currents are triggered through the spin Seebeck effect, either by a continuous (dc) temperature gradient or by ultrafast optical heating of the metal layer. The spin Hall current is detected by electrical contacts or measurement of the emitted terahertz radiation. With both approaches, we reveal the same Ir concentration dependence that follows a novel complex, nonmonotonous behavior as compared to previous studies. For small Ir concentrations a signal minimum is observed, whereas a pronounced maximum appears near the equiatomic composition. We identify this behavior as originating from the interplay of different spin Hall mechanisms as well as a concentration-dependent variation of the integrated spin current density in Cu 1-x Ir x . The coinciding results obtained for dc and ultrafast stimuli provide further support that the spin Seebeck effect extends to terahertz frequencies, thus enabling a transfer of established spintronic measurement schemes into the terahertz regime. Our findings also show that the studied material allows for efficient spin-to-charge conversion even on ultrafast time scales.
Vugman, N V; de Araújo, M B; Pinhal, N M; Magon, C J; da Costa Filho, A J
2004-05-01
Electron spin-lattice relaxation rates for the low spin [Ni(CN)(4)](1-) and [Ni(CN)(4)](3-) complexes in NaCl host lattice were measured by the inversion recovery technique in the temperature range 7-50K. The data for both paramagnetic species fit very well to a relaxation process involving localized anharmonic vibration modes, also responsible for the g-tensor temperature dependence.
The Complex Spin State of 103P-Hartley 2: Kinematics and Orientation in Space
Belton, Michael J. S.; Thomas, Peter; Li, Jian-Yang; Williams, Jade; Carcich, Brian; A'Hearn, Michael F.; McLaughlin, Stephanie; Farnham, Tony; McFadden, Lucy; Lisse, Carey M.;
2013-01-01
We derive the spin state of the nucleus of Comet 103P/Hartley 2, its orientation in space, and its short-term temporal evolution from a mixture of observations taken from the DIXI (Deep Impact Extended Investigation) spacecraft and radar observations. The nucleus is found to spin in an excited long-axis mode (LAM) with its rotational angular momentum per unit mass, M, and rotational energy per unit mass, E, slowly decreasing while the degree of excitation in the spin increases through perihelion passage. M is directed toward (RA, Dec; J2000) = 8+/-+/- 4 deg., 54 +/- 1 deg. (obliquity = 48 +/- 1 deg.). This direction is likely changing, but the change is probably <6 deg. on the sky over the approx. 81.6 days of the DIXI encounter. The magnitudes of M and E at closest approach (JD 2455505.0831866 2011-11-04 13:59:47.310) are 30.0 +/- 0.2 sq. m/s and (1.56 +/- 0.02) X 10(exp -3) sq. m /sq. s respectively. The period of rotation about the instantaneous spin vector, which points in the direction (RA, Dec; J2000) = 300 +/- 3.2deg., 67 +/- 1.3 deg. at the time of closest approach, was 14.1 +/- 0.3 h. The instantaneous spin vector circulates around M, inclined at an average angle of 33.2 +/- 1.3 deg. with an average period of 18.40 +/- 0.13 h at the time of closest approach. The period of roll around the principal axis of minimum inertia (''long'' axis) at that time is 26.72 +/- 0.06 h. The long axis is inclined to M by approx. 81.2 +/- 0.6 deg. on average, slowly decreasing through encounter. We infer that there is a periodic nodding motion of the long axis with half the roll period, i.e., 13.36+/- 0.03 h, with amplitude of 1 again decreasing through encounter. The periodic variability in the circulation and roll rates during a cycle was at the 2% and 10-14% level respectively. During the encounter there was a secular lengthening of the circulation period of the long axis by 1.3 +/- 0.2 min/d, in agreement with ground-based estimates, while the period of roll around the
CONNECTING ANGULAR MOMENTUM AND GALACTIC DYNAMICS: THE COMPLEX INTERPLAY BETWEEN SPIN, MASS, AND MORPHOLOGY
International Nuclear Information System (INIS)
Teklu, Adelheid F.; Remus, Rhea-Silvia; Dolag, Klaus; Beck, Alexander M.; Burkert, Andreas; Schulze, Felix; Steinborn, Lisa K.; Schmidt, Andreas S.
2015-01-01
The evolution and distribution of the angular momentum of dark matter (DM) halos have been discussed in several studies over the past decades. In particular, the idea arose that angular momentum conservation should allow us to infer the total angular momentum of the entire DM halo from measuring the angular momentum of the baryonic component, which is populating the center of the halo, especially for disk galaxies. To test this idea and to understand the connection between the angular momentum of the DM halo and its galaxy, we use a state-of-the-art, hydrodynamical cosmological simulation taken from the set of Magneticum Pathfinder simulations. Thanks to the inclusion of the relevant physical processes, the improved underlying numerical methods, and high spatial resolution, we successfully produce populations of spheroidal and disk galaxies self-consistently. Thus, we are able to study the dependence of galactic properties on their morphology. We find that (1) the specific angular momentum of stars in disk and spheroidal galaxies as a function of their stellar mass compares well with observational results; (2) the specific angular momentum of the stars in disk galaxies is slightly smaller compared to the specific angular momentum of the cold gas, in good agreement with observations; (3) simulations including the baryonic component show a dichotomy in the specific stellar angular momentum distribution when splitting the galaxies according to their morphological type (this dichotomy can also be seen in the spin parameter, where disk galaxies populate halos with slightly larger spin compared to spheroidal galaxies); (4) disk galaxies preferentially populate halos in which the angular momentum vector of the DM component in the central part shows a better alignment to the angular momentum vector of the entire halo; and (5) the specific angular momentum of the cold gas in disk galaxies is approximately 40% smaller than the specific angular momentum of the total DM halo
Wilbraham, Liam; Adamo, Carlo; Ciofini, Ilaria
2018-01-01
The computationally assisted, accelerated design of inorganic functional materials often relies on the ability of a given electronic structure method to return the correct electronic ground state of the material in question. Outlining difficulties with current density functionals and wave function-based approaches, we highlight why double hybrid density functionals represent promising candidates for this purpose. In turn, we show that PBE0-DH (and PBE-QIDH) offers a significant improvement over its hybrid parent functional PBE0 [as well as B3LYP* and coupled cluster singles and doubles with perturbative triples (CCSD(T))] when computing spin-state splitting energies, using high-level diffusion Monte Carlo calculations as a reference. We refer to the opposing influence of Hartree-Fock (HF) exchange and MP2, which permits higher levels of HF exchange and a concomitant reduction in electronic density error, as the reason for the improved performance of double-hybrid functionals relative to hybrid functionals. Additionally, using 16 transition metal (Fe and Co) complexes, we show that low-spin states are stabilised by increasing contributions from MP2 within the double hybrid formulation. Furthermore, this stabilisation effect is more prominent for high field strength ligands than low field strength ligands.
Kulik, L V; Lubitz, W; Messinger, J
2005-07-05
The temperature dependence of the electron spin-lattice relaxation time T1 was measured for the S0 state of the oxygen-evolving complex (OEC) in photosystem II and for two dinuclear manganese model complexes by pulse EPR using the inversion-recovery method. For [Mn(III)Mn(IV)(mu-O)2 bipy4]ClO4, the Raman relaxation process dominates at temperatures below 50 K. In contrast, Orbach type relaxation was found for [Mn(II)Mn(III)(mu-OH)(mu-piv)2(Me3 tacn)2](ClO4)2 between 4.3 and 9 K. For the latter complex, an energy separation of 24.7-28.0 cm(-1) between the ground and the first excited electronic state was determined. In the S0 state of photosystem II, the T1 relaxation times were measured in the range of 4.3-6.5 K. A comparison with the relaxation data (rate and pre-exponential factor) of the two model complexes and of the S2 state of photosystem II indicates that the Orbach relaxation process is dominant for the S0 state and that its first excited state lies 21.7 +/- 0.4 cm(-1) above its ground state. The results are discussed with respect to the structure of the OEC in photosystem II.
Auclair-Desrotour, P.; Mathis, S.; Laskar, J.
2018-02-01
Context. Thermal atmospheric tides can torque telluric planets away from spin-orbit synchronous rotation, as observed in the case of Venus. They thus participate in determining the possible climates and general circulations of the atmospheres of these planets. Aims: The thermal tidal torque exerted on an atmosphere depends on its internal structure and rotation and on the tidal frequency. Particularly, it strongly varies with the convective stability of the entropy stratification. This dependence has to be characterized to constrain and predict the rotational properties of observed telluric exoplanets. Moreover, it is necessary to validate the approximations used in global modelings such as the traditional approximation, which is used to obtain separable solutions for tidal waves. Methods: We wrote the equations governing the dynamics of thermal tides in a local vertically stratified section of a rotating planetary atmosphere by taking into account the effects of the complete Coriolis acceleration on tidal waves. This allowed us to analytically derive the tidal torque and the tidally dissipated energy, which we used to discuss the possible regimes of tidal dissipation and to examine the key role played by stratification. Results: In agreement with early studies, we find that the frequency dependence of the thermal atmospheric tidal torque in the vicinity of synchronization can be approximated by a Maxwell model. This behavior corresponds to weakly stably stratified or convective fluid layers, as observed previously. A strong stable stratification allows gravity waves to propagate, and makes the tidal torque negligible. The transition is continuous between these two regimes. The traditional approximation appears to be valid in thin atmospheres and in regimes where the rotation frequency is dominated by the forcing or the buoyancy frequencies. Conclusions: Depending on the stability of their atmospheres with respect to convection, observed exoplanets can be tidally
Energy Technology Data Exchange (ETDEWEB)
Lehar, F.; Adiasevich, B.; Androsov, V.P.; Angelov, N.; Anischenko, N.; Antonenko, V.; Ball, J.; Baryshevsky, V.G.; Bazhanov, N.A.; Belyaev, A.A.; Benda, B.; Bodyagin, V.; Borisov, N.; Borzunov, Yu.; Bradamante, F.; Bunyatova, E.; Burinov, V.; Chernykh, E.; Combet, M.; Datskov, A.; Durand, G.; Dzyubak, A.P.; Fontaine, J.M.; Get`man, V.A.; Giorgi, M.; Golovanov, L.; Grebenyuk, V.; Grosnick, D.; Gurevich, G.; Hasegawa, T.; Hill, D.; Horikawa, N.; Igo, G.; Janout, Z.; Kalinnikov, V.A.; Karnaukhov, I.M.; Kasprzyk, T.; Khachaturov, B.A.; Kirillov, A.; Kisselev, Yu.; Kousmine, E.S.; Kovalenko, A.; Kovaljov, A.I.; Ladygin, V.P.; Lazarev, A.; Leconte, P.; Lesquen, A. de; Lukhanin, A.A.; Mango, S.; Martin, A.; Matafonov, V.N.; Matyushevsky, E.; Mironov, S.; Neganov, A.B.; Neganov, B.S.; Nomofilov, A.; Perelygin, V.; Plis, Yu.; Pilipenko, Yu.; Pisarev, I.L.; Piskunov, N.; Polunin, Yu.; Popkov, Yu.P.; Propov, A.A.; Prokofiev, A.N.; Rekalo, M.P.; Rukoyatkin, P.; Sans, J.L.; Sapozhnikov, M.G.; Sharov, V.; Shilov, S.; Shishov, Yu.; Sitnik, I.M.; Sorokin, P.V.; Spinka, H.; Sporov, E.A.; Strunov, L.N.; Svetov, A.; De Swart, J.J.; Telegin, Yu.P.; Tolmashov, I.; Trentalange, S.; Tsvinev, A.; Usov, Yu.A.; Vikhrov, V.V.; Whitten, C.A.; Zaporozhets, S.; Zarubin, A.; Zhdanov, A.A.; Zolin, L. [CEA Centre d`Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France). Dept. d`Astrophysique, de Physique des Particules, de Physique Nucleaire et de l`Instrumentation Associee]|[I.V. Kurchatov Inst. of Atomic Energy, Moscow (Russian Federation)]|[Kharkov Inst. of Physics and Technology (Russian Federation)]|[Lab. of Nuclear Problems, JINR, Dubna (Russian Federation)]|[Lab. of High Energy Physics, JINR, Dubna (Russian Federation)]|[Lab. National SATURNE, CNRS, 91 - Gif-sur-Yvette (France)]|[Inst. of Physics, Belarus Academy of Sciences, Minsk (Belarus)]|[Dept. of Physics, Petersburg Nuclear Physics Inst., Gatchina (Russian Federation)
1995-03-01
A movable polarized proton target is planned to be installed in polarized beams of the Synchrophasotron-Nuclotron complex in order to carry out a spin physics experimental program at Dubna. The project is described and the first proposed experiments are discussed. ((orig.))
International Nuclear Information System (INIS)
Lehar, F.; Adiasevich, B.; Androsov, V.P.; Angelov, N.; Anischenko, N.; Antonenko, V.; Ball, J.; Baryshevsky, V.G.; Bazhanov, N.A.; Belyaev, A.A.; Benda, B.; Bodyagin, V.; Borisov, N.; Borzunov, Yu.; Bradamante, F.; Bunyatova, E.; Burinov, V.; Chernykh, E.; Combet, M.; Datskov, A.; Durand, G.; Dzyubak, A.P.; Fontaine, J.M.; Get'man, V.A.; Giorgi, M.; Golovanov, L.; Grebenyuk, V.; Grosnick, D.; Gurevich, G.; Hasegawa, T.; Hill, D.; Horikawa, N.; Igo, G.; Janout, Z.; Kalinnikov, V.A.; Karnaukhov, I.M.; Kasprzyk, T.; Khachaturov, B.A.; Kirillov, A.; Kisselev, Yu.; Kousmine, E.S.; Kovalenko, A.; Kovaljov, A.I.; Ladygin, V.P.; Lazarev, A.; Leconte, P.; Lesquen, A. de; Lukhanin, A.A.; Mango, S.; Martin, A.; Matafonov, V.N.; Matyushevsky, E.; Mironov, S.; Neganov, A.B.; Neganov, B.S.; Nomofilov, A.; Perelygin, V.; Plis, Yu.; Pilipenko, Yu.; Pisarev, I.L.; Piskunov, N.; Polunin, Yu.; Popkov, Yu.P.; Propov, A.A.; Prokofiev, A.N.; Rekalo, M.P.; Rukoyatkin, P.; Sans, J.L.; Sapozhnikov, M.G.; Sharov, V.; Shilov, S.; Shishov, Yu.; Sitnik, I.M.; Sorokin, P.V.; Spinka, H.; Sporov, E.A.; Strunov, L.N.; Svetov, A.; De Swart, J.J.; Telegin, Yu.P.; Tolmashov, I.; Trentalange, S.; Tsvinev, A.; Usov, Yu.A.; Vikhrov, V.V.; Whitten, C.A.; Zaporozhets, S.; Zarubin, A.; Zhdanov, A.A.; Zolin, L.
1995-01-01
A movable polarized proton target is planned to be installed in polarized beams of the Synchrophasotron-Nuclotron complex in order to carry out a spin physics experimental program at Dubna. The project is described and the first proposed experiments are discussed. ((orig.))
Lehar, F.; Adiasevich, B.; Androsov, V. P.; Angelov, N.; Anischenko, N.; Antonenko, V.; Ball, J.; Baryshevsky, V. G.; Bazhanov, N. A.; Belyaev, A. A.; Benda, B.; Bodyagin, V.; Borisov, N.; Borzunov, Yu.; Bradamante, F.; Bunyatova, E.; Burinov, V.; Chernykh, E.; Combet, M.; Datskov, A.; Durand, G.; Dzyubak, A. P.; Fontaine, J. M.; Get'man, V. A.; Giorgi, M.; Golovanov, L.; Grebenyuk, V.; Grosnick, D.; Gurevich, G.; Hasegawa, T.; Hill, D.; Horikawa, N.; Igo, G.; Janout, Z.; Kalinnikov, V. A.; Karnaukhov, I. M.; Kasprzyk, T.; Khachaturov, B. A.; Kirillov, A.; Kisselev, Yu.; Kousmine, E. S.; Kovalenko, A.; Kovaljov, A. I.; Ladygin, V. P.; Lazarev, A.; Leconte, Ph.; de Lesquen, A.; Lukhanin, A. A.; Mango, S.; Martin, A.; Matafonov, V. N.; Matyushevsky, E.; Mironov, S.; Neganov, A. B.; Neganov, B. S.; Nomofilov, A.; Perelygin, V.; Plis, Yu.; Pilipenko, Yu.; Pisarev, I. L.; Piskunov, N.; Polunin, Yu.; Popkov, Yu. P.; Propov, A. A.; Prokofiev, A. N.; Rekalo, M. P.; Rukoyatkin, P.; Sans, J. L.; Sapozhnikov, M. G.; Sharov, V.; Shilov, S.; Shishov, Yu.; Sitnik, I. M.; Sorokin, P. V.; Spinka, H.; Sporov, E. A.; Strunov, L. N.; Svetov, A.; de Swart, J. J.; Telegin, Yu. P.; Tolmashov, I.; Trentalange, S.; Tsvinev, A.; Usov, Yu. A.; Vikhrov, V. V.; Whitten, C. A.; Zaporozhets, S.; Zarubin, A.; Zhdanov, A. A.; Zolin, L.
1995-02-01
A movable polarized proton target is planned to be installed in polarized beams of the Synchrophasotron-Nuclotron complex in order to carry out a spin physics experimental program at Dubna. The project is described and the first proposed experiments are discussed.
Okazawa, A.; Yoshida, J.; Kida, N.; Kashima, I.; Murata, W.; Enomoto, M.; Kojima, N.
2014-04-01
We have investigated magnetic properties in a series of photoresponsive dithiooxalato (dto)-bridged iron mixed-valence complexes, (SP-R)[FeIIFeIII(dto)3] (SP-R = R-substituted pyridospiropyran cation; R = Me, Et, and Pr; abbreviated as 1 Me, 1 Et, and 1 Pr, respectively). As for our previous reports, 1 Me and 1 Et show two-step succeeding ferromagnetic transitions at T C = 25 & 8 K and 22 & 5 K, respectively. However, 1 Et has no hysteresis in the magnetic susceptibility, while 1 Me undergoes the charge transfer phase transition with thermal hysteresis around 75 K. To elucidate the two-step transitions of them, we measured 57Fe Mössbauer spectra of 1 Et. The spectra of FeII ( S = 2) and FeIII ( S = 1/2) in the HTP were observed in the magnetically ordered state as well as the paramagnetic state, and revealed that only HTP exists in a temperature range up to 5 K. The result is consistent with that of 1 Pr, where one ferromagnetic phase transition occurs at T C = 10 K. 57Fe Mössbauer spectroscopy is useful to clarify the origin of the succeeding magnetic transition for these systems.
Spin Hall and spin swapping torques in diffusive ferromagnets
Pauyac, C. O.
2017-12-08
A complete set of the generalized drift-diffusion equations for a coupled charge and spin dynamics in ferromagnets in the presence of extrinsic spin-orbit coupling is derived from the quantum kinetic approach, covering major transport phenomena, such as the spin and anomalous Hall effects, spin swapping, spin precession and relaxation processes. We argue that the spin swapping effect in ferromagnets is enhanced due to spin polarization, while the overall spin texture induced by the interplay of spin-orbital and spin precessional effects displays a complex spatial dependence that can be exploited to generate torques and nucleate/propagate domain walls in centrosymmetric geometries without use of external polarizers, as opposed to the conventional understanding of spin-orbit mediated torques.
Fukuda, Takamitsu; Matsumura, Kazuya; Ishikawa, Naoto
2013-10-10
Nuclear spin driven quantum tunneling of magnetization (QTM) phenomena, which arise from admixture of more than two orthogonal electronic spin wave functions through the couplings with those of the nuclear spins, are one of the important magnetic relaxation processes in lanthanide single molecule magnets (SMMs) in the low temperature range. Although recent experimental studies have indicated that the presence of the intramolecular f-f interactions affects their magnetic relaxation processes, little attention has been given to their mechanisms and, to the best of our knowledge, no rational theoretical models have been proposed for the interpretations of how the nuclear spin driven QTMs are influenced by the f-f interactions. Since quadruple-decker phthalocyanine complexes with two terbium or dysprosium ions as the magnetic centers show moderate f-f interactions, these are appropriate to investigate the influence of the f-f interactions on the dynamic magnetic relaxation processes. In the present paper, a theoretical model including ligand field (LF) potentials, hyperfine, nuclear quadrupole, magnetic dipolar, and the Zeeman interactions has been constructed to understand the roles of the nuclear spins for the QTM processes, and the resultant Zeeman plots are obtained. The ac susceptibility measurements of the magnetically diluted quadruple-decker monoterbium and diterbium phthalocyanine complexes, [Tb-Y] and [Tb-Tb], have indicated that the presence of the f-f interactions suppresses the QTMs in the absence of the external magnetic field (H(dc)) being consistent with previous reports. On the contrary, the faster magnetic relaxation processes are observed for [Tb-Tb] than [Tb-Y] at H(dc) = 1000 Oe, clearly demonstrating that the QTMs are rather enhanced in the presence of the external magnetic field. Based on the calculated Zeeman diagrams, these observations can be attributed to the enhanced nuclear spin driven QTMs for [Tb-Tb]. At the H(dc) higher than 2000 Oe, the
Spin crossover properties of the [Fe(PM-BiA) sub 2 (NCS) sub 2] complex - phases I and II
Letard, J F; Nguyen, O; Marcen, S; Marchivie, M; Guionneau, P; Chasseau, D; Guetlich, P
2003-01-01
In the present review, we reexamine the photomagnetic properties of the [Fe (PM-BiA) sub 2 (NCS) sub 2], cis-bis(thiocyanato)-bis[(N-2'-pyridylmethylene)-4-(aminobiphenyl)] iron(II), compound which exhibits, depending on the synthetic method, an exceptionally abrupt spin transition (phase 1) with a very narrow hysteresis (T sub 1 sub / sub 2 arrow down = 168 K and T sub 1 sub / sub 2 arrow up = 173 K) or a gradual spin conversion (phase II) occurring at 190 K. In both cases, light irradiation in the tail of the sup 1 MLCT-LS absorption band, at 830 nm, results in the population of the high-spin state according to the light-induced excited spin-state trapping (LIESST) effect. The capacity of a compound to retain the light-induced HS information, estimated through the T(LIESST) experiment, is determined for both phases. Interestingly, the shape of the T(LIESST) curve is more gradual for the phase II than for the phase I and the T(LIESST) value is found considerably lower in the case of the phase II. The kinetic...
Microscopic studies of nonlocal spin dynamics and spin transport (invited)
Energy Technology Data Exchange (ETDEWEB)
Adur, Rohan; Du, Chunhui; Cardellino, Jeremy; Scozzaro, Nicolas; Wolfe, Christopher S.; Wang, Hailong; Herman, Michael; Bhallamudi, Vidya P.; Pelekhov, Denis V.; Yang, Fengyuan; Hammel, P. Chris, E-mail: hammel@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210 (United States)
2015-05-07
Understanding the behavior of spins coupling across interfaces in the study of spin current generation and transport is a fundamental challenge that is important for spintronics applications. The transfer of spin angular momentum from a ferromagnet into an adjacent normal material as a consequence of the precession of the magnetization of the ferromagnet is a process known as spin pumping. We find that, in certain circumstances, the insertion of an intervening normal metal can enhance spin pumping between an excited ferromagnetic magnetization and a normal metal layer as a consequence of improved spin conductance matching. We have studied this using inverse spin Hall effect and enhanced damping measurements. Scanned probe magnetic resonance techniques are a complementary tool in this context offering high resolution magnetic resonance imaging, localized spin excitation, and direct measurement of spin lifetimes or damping. Localized magnetic resonance studies of size-dependent spin dynamics in the absence of lithographic confinement in both ferromagnets and paramagnets reveal the close relationship between spin transport and spin lifetime at microscopic length scales. Finally, detection of ferromagnetic resonance of a ferromagnetic film using the photoluminescence of nitrogen vacancy spins in neighboring nanodiamonds demonstrates long-range spin transport between insulating materials, indicating the complexity and generality of spin transport in diverse, spatially separated, material systems.
White, Gaye F; Schermann, Sonya M; Bradley, Justin; Roberts, Andrew; Greene, Nicholas P; Berks, Ben C; Thomson, Andrew J
2010-01-22
The Tat system is used to transport folded proteins across the cytoplasmic membrane in bacteria and archaea and across the thylakoid membrane of plant chloroplasts. Multimers of the integral membrane TatA protein are thought to form the protein-conducting element of the Tat pathway. Nitroxide radicals were introduced at selected positions within the transmembrane helix of Escherichia coli TatA and used to probe the structure of detergent-solubilized TatA complexes by EPR spectroscopy. A comparison of spin label mobilities allowed classification of individual residues as buried within the TatA complex or exposed at the surface and suggested that residues Ile(12) and Val(14) are involved in interactions between helices. Analysis of inter-spin distances suggested that the transmembrane helices of TatA subunits are arranged as a single-walled ring containing a contact interface between Ile(12) on one subunit and Val(14) on an adjacent subunit. Experiments in which labeled and unlabeled TatA samples were mixed demonstrate that TatA subunits are exchanged between TatA complexes. This observation is consistent with the TatA dynamic polymerization model for the mechanism of Tat transport.
Directory of Open Access Journals (Sweden)
Suguru Murata
2016-05-01
Full Text Available To investigate the π-extension effect on an unusual negative-charged spin crossover (SCO FeIII complex with a weak N2O4 first coordination sphere, we designed and synthesized a series of anionic FeIII complexes from a π-extended naphthalene derivative ligand. Acetonitrile-solvate tetramethylammonium (TMA salt 1 exhibited an SCO conversion, while acetone-solvate TMA salt 2 was in a high-spin state. The crystal structural analysis for 2 revealed that two-leg ladder-like cation-anion arrays derived from π-stacking interactions between π-ligands of the FeIII complex anion and Coulomb interactions were found and the solvated acetone molecules were in one-dimensional channels between the cation-anion arrays. A desolvation-induced single-crystal-to-single-crystal transformation to desolvate compound 2’ may be driven by Coulomb energy gain. Furthermore, the structural comparison between quasi-polymorphic compounds 1 and 2 revealed that the synergy between Coulomb and π-stacking interactions induces a significant distortion of coordination structure of 2.
Large thermal hysteresis for iron(II) spin crossover complexes with N-(pyrid-4-yl)isonicotinamide.
Lochenie, Charles; Bauer, Wolfgang; Railliet, Antoine P; Schlamp, Stephan; Garcia, Yann; Weber, Birgit
2014-11-03
A new series of iron(II) 1D coordination polymers with the general formula [FeL1(pina)]·xsolvent with L1 being a tetradentate N2O2(2-) coordinating Schiff-base-like ligand [([3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentanedionato)(2-)-N,N',O(2),O(2)'], and pina being a bridging axial ligand N-(pyrid-4-yl)isonicotinamide, are discussed. The X-ray crystal structure of [FeL1(pina)]·2MeOH was solved for the low-spin state. The compound crystallizes in the monoclinic space group P21/c, and the analysis of the crystal packing reveals the formation of a hydrogen bond network where additional methanol molecules are included. Different magnetic properties are observed for the seven samples analyzed, depending on the nature of the included solvent molecules. The widest hysteresis loop is observed for a fine crystalline sample of composition [FeL1(pina)]·xH2O/MeOH. The 88 K wide thermal hysteresis loop (T1/2↑ = 328 K and T1/2↓ = 240 K) is centered around room temperature and can be repeated without of a loss of the spin transition properties. For the single crystals of [FeL1(pina)]·2MeOH, a 51 K wide hysteresis loop is observed (T1/2↑ = 296 K and T1/2↓ = 245 K) that is also stable for several cycles. For a powder sample of [FeL1(pina)]·0.5H2O·0.5MeOH a cooperative spin transition with a 46 K wide hysteresis loop around room temperature is observed (T1/2↑ = 321 K and T1/2↓ = 275 K). This compound was further investigated using Mössbauer spectroscopy and DSC. Both methods reveal that, in the cooling mode, the spin transition is accompanied by a phase transition while in the heating mode a loss of the included methanol is observed that leads to a loss of the spin transition properties. These results show that the pina ligand was used successfully in a crystal-engineering-like approach to generate 1D coordination polymers and improve their spin crossover properties.
Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi
2012-01-01
In a new branch of physics and technology called spin-electronics or spintronics, the flow of electrical charge (usual current) as well as the flow of electron spin, the so-called 'spin current', are manipulated and controlled together. This book provides an introduction and guide to the new physics and application of spin current.
Energy Technology Data Exchange (ETDEWEB)
Abdulmalic, Mohammad A. [Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Chemie, Straße der Nationen 62, D-09111 Chemnitz (Germany); Fronk, Michael [Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Physik, Reichenhainer Straße 70, D-09107 Chemnitz (Germany); Bräuer, Björn [Stanford Institute of Materials and Energy Science, Stanford University, Stanford, CA 94025 (United States); Zahn, Dietrich R.T. [Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Physik, Reichenhainer Straße 70, D-09107 Chemnitz (Germany); Salvan, Georgeta, E-mail: salvan@physik.tu-chemnitz.de [Technische Universität Chemnitz, Fakultät für Naturwissenschaften, Institut für Physik, Reichenhainer Straße 70, D-09107 Chemnitz (Germany); Eya' ane Meva, Francois [Department of Pharmaceutical Sciences, Faculty of Medicine and Pharmaceutical Sciences, University of Douala, BP 2701 (Cameroon); and others
2016-12-01
This work reports the first example of the spectroscopic measurements of the Magneto-Optical Kerr Effect (MOKE) of films being composed of trinuclear transition metal complexes on a non-transparent substrate at room temperature. The thin films of the tailor-made trinuclear bis(oxamidato) type complex 5 ([Cu{sub 3}(opbo{sup n}Pr{sub 2})(tmcd){sub 2}(NO{sub 3}){sub 2}], opbo{sup n}Pr{sub 2} = o-phenylenebis(N’-{sup n}propyloxamido, tmcd=trans-(1 R,2 R)-N,N,N′,N′-tetramethyl-cyclohexanediamine) and of the bis(oxamato) type complexes 11 ([Cu{sub 2}Ni(opbaCF{sub 3})(pmdta){sub 2}(NO{sub 3}){sub 2}], opbaCF{sub 3} = 4-trifluoromethyl-o-phenylenebis(oxamato), pmdta = N,N,N,′N″,N″-pentamethyldiethylenetriamine) and 12 ([Cu{sub 3}(opba)(bppe){sub 2}(NO{sub 3}){sub 2}] (opba = o-phenylenebis(oxamato), bppe = S-N,N-bis(2-picolyl)−1-phenylethylamine) were fabricated by spin-coating and their thicknesses in the range between 0.5 µm and 2 µm was determined by spectroscopic ellipsometry. Based on the spectroscopic ellipsometry results it was also possible to determine the optical constants of the film and compare them with the absorption of the complexes in solution in order to confirm the complex integrity after the film deposition. The fabrication of high-quality films which exhibit Kerr rotation up to 0.2 mrad (11.5 mdeg) was only possible due to tailor-made synthesis, which allows circumventing intermolecular interactions of the trinuclear complexes during the film formation. - Highlights: • Tailor-made trinuclear bis(oxamidato) and bis(oxamato) type complexes were synthesized. • Thin films (between 0.5 µm and 2 µm) were fabricated by spin-coating. • The film optical constants indicate the complex integrity after the deposition. • Film quality enabled first spectroscopic MOKE measurements of multi-nuclear complexes. • Magneto-optical Kerr rotation up to 11.5 mdeg was observed at RT (in 1.7 T).
Local Noncollinear Spin Analysis.
Abate, Bayileyegn A; Joshi, Rajendra P; Peralta, Juan E
2017-12-12
In this work, we generalize the local spin analysis of Clark and Davidson [J. Chem. Phys. 2001 115 (16), 7382] for the partitioning of the expectation value of the molecular spin square operator, ⟨Ŝ 2 ⟩, into atomic contributions, ⟨Ŝ A ·Ŝ B ⟩, to the noncollinear spin case in the framework of density functional theory (DFT). We derive the working equations, and we show applications to the analysis of the noncollinear spin solutions of typical spin-frustrated systems and to the calculation of magnetic exchange couplings. In the former case, we employ the triangular H 3 He 3 test molecule and a Mn 3 complex to show that the local spin analysis provides additional information that complements the standard one-particle spin population analysis. For the calculation of magnetic exchange couplings, J AB , we employ the local spin partitioning to extract ⟨Ŝ A ·Ŝ B ⟩ as a function of the interatomic spin orientation given by the angle θ. This, combined with the dependence of the electronic energy with θ, provides a methodology to extract J AB from DFT calculations that, in contrast to conventional energy differences based methods, does not require the use of ad hoc S A and S B values.
Aluminum-stabilized low-spin iron(II) hydrido complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane.
Oishi, Masataka; Endo, Togo; Oshima, Masato; Suzuki, Hiroharu
2014-05-19
We investigated herein the reactions of (Me3tacn)FeCln (1a: n = 3, 1b: n = 2) with common aluminum hydride reagents and a bulky dihydridoaluminate {Li(ether)2}{Al(OC6H3-2,6-(t)Bu2)}(μ-H)2, which yielded the diamagnetic hydrido complexes 2-4 containing Fe(II) and Al(III). In particular, the use of divalent 1b afforded excellent isolated yields. The structures of 2-4 were determined using spectroscopic and crystallographic analyses. The crystal structures showed distorted octahedral Fe centers and fairly short Fe-Al distances [2.19-2.24 Å]. The structures of cation moiety 2 and neutral complex 4 were further probed using DFT calculations, which indicated a stable low-spin Fe(II) state and strongly electron-donating nature of the (Me3tacn)FeH3 fragment toward the Al(III) center.
Garcia-Bosch, Isaac; Adam, Suzanne M; Schaefer, Andrew W; Sharma, Savita K; Peterson, Ryan L; Solomon, Edward I; Karlin, Kenneth D
2015-01-28
Here we describe a new approach for the generation of heme-peroxo-Cu compounds, using a "naked" complex synthon, [(F8)Fe(III)-(O2(2-))-Cu(II)(MeTHF)3](+) (MeTHF = 2-methyltetrahydrofuran; F8 = tetrakis(2,6-difluorophenyl)porphyrinate). Addition of varying ligands (L) for Cu allows the generation and spectroscopic characterization of a family of high- and low-spin Fe(III)-(O2(2-))-Cu(II)(L) complexes. These possess markedly varying Cu(II) coordination geometries, leading to tunable Fe-O, O-O, and Cu-O bond strengths. DFT calculations accompanied by vibrational data correlations give detailed structural insights.
Fries, Pascal H.; Belorizky, Elie
2007-05-01
The relaxation of the electronic spin S of a paramagnetic metal ion with fully quenched orbital angular momentum in its ground state is investigated in an external magnetic field through a systematic study of the time correlation functions governing the evolution of the statistical operator (density matrix). Let ω0 be the Larmor angular frequency of S. When the relaxation is induced by a time-fluctuating perturbing Hamiltonian ℏH1(t ) of time correlation τc, it is demonstrated that after a transient period the standard Redfield approximation is relevant to calculate the evolution of the populations of the spin states if ∥H1∥2τc2/(1+ω02τc2)≪1 and that this transient period becomes shorter than τc at sufficiently high field for a zero-field splitting perturbing Hamiltonian. This property, proven analytically and confirmed by numerical simulation, explains the surprising success of several simple expressions of the longitudinal electronic relaxation rate 1/T1e derived from the Redfield approximation well beyond its expected validity range ∥H1∥τc≪1. It has favorable practical consequences on the interpretation of the paramagnetic relaxation enhancement of nuclei used for structural and dynamic studies.
Dieny, B.; Sousa, R.; Prejbeanu, L.
2007-04-01
tunnel junctions were introduced as memory elements in new types of non-volatile magnetic memories (MRAM). A first 4Mbit product was launched by Freescale in July 2006. Future generations of memories are being developed by academic groups or companies. the combination of magnetic elements with CMOS components opens a whole new paradigm in hybrid electronic components which can change the common conception of the architecture of complex electronic components with a much tighter integration of logic and memory. the steady magnetic excitations stimulated by spin-transfer might be used in a variety of microwave components provided the output power can be increased. Intense research and development efforts are being aimed at increasing this power by the synchronization of oscillators. The articles compiled in this special issue of Journal of Physics: Condensed Matter, devoted to spin electronics, review these recent developments. All the contributors are greatly acknowledged.
Matei, Iulia; Ariciu, Ana Maria; Neacsu, Maria Victoria; Collauto, Alberto; Salifoglou, Athanasios; Ionita, Gabriela
2014-09-25
In this work, we present evidence on the suitability of spin probes to report on the thermal treatment of bovine serum albumin (BSA), in the temperature range 293-343 K, and indirectly monitor the release of sodium dodecyl sulfate (SDS) from its complex with BSA using a covalent gel with β-cyclodextrin (β-CD) in the network. The spin probes used, 5- and 7-doxyl-stearic acids (5-DSA, 7-DSA) or 4-(N,N'-dimethyl-N-hexadecyl)ammonium-2,2',6,6'-tetramethylpiperidine-1-oxyl iodide (CAT16), present similar, fatty acid-like structural features. Their continuous wave electron paramagnetic resonance (CW-EPR) spectra, however, reflect different dynamics when complexed with BSA: a restricted motion for 5-DSA, almost nonsensitive to the heating/cooling cycle, and a faster temperature-dependent dynamic motion for CAT16. Molecular docking allows us to rationalize these results by revealing the different binding modes of 5-DSA and CAT16. The EPR data on the temperature effect on BSA are supported by circular dichroism results projecting recovery, upon cooling, of the initial binding ability of BSA for samples heated to 323 K. The interactions occurring in BSA/SDS/β-CD systems are investigated by CW-EPR and FT-ESEEM spectroscopies. It is found that the covalent gel containing β-CD can efficiently remove SDS from the BSA/SDS complex. The gel is not permeable to BSA but it can encapsulate SDS, thus yielding the free protein in solution and allowing recovery of the native protein conformation. Collectively, the accrued knowledge supports potential applications in protein purification biotechnological processes.
Energy Technology Data Exchange (ETDEWEB)
Ozkanlar, Abdullah; Cape, Jonathan L.; Hurst, James K.; Clark, Aurora E.
2011-09-05
Density functional theory (DFT) has been used to investigate the plausibility of water addition to the simple mononuclear ruthenium complexes, [(NH{sub 3}){sub 3}(bpy)Ru=O]{sup 2+}/{sup 3+} and [(NH{sub 3}){sub 3}(bpy)RuOH]{sup 3+}, in which the OH fragment adds to the 2,2{prime}-bipyridine (bpy) ligand. Activation of bpy toward water addition has frequently been postulated within the literature, although there exists little definitive experimental evidence for this type of 'covalent hydration'. In this study, we examine the energetic dependence of the reaction upon metal oxidation state, overall spin state of the complex, as well as selectivity for various positions on the bipyridine ring. The thermodynamic favorability is found to be highly dependent upon all three parameters, with free energies of reaction that span favorable and unfavorable regimes. Aqueous addition to [(NH{sub 3}){sub 3}(bpy)Ru=O]{sup 3+} was found to be highly favorable for the S = 1/2 state, while reduction of the formal oxidation state on the metal center makes the reaction highly unfavorable. Examination of both facial and meridional isomers reveals that when bipyridine occupies the position trans to the ruthenyl oxo atom, reactivity toward OH addition decreases and the site preferences are altered. The electronic structure and spectroscopic signatures (EPR parameters and simulated spectra) have been determined to aid in recognition of 'covalent hydration' in experimental systems. EPR parameters are found to uniquely characterize the position of the OH addition to the bpy as well as the overall spin state of the system.
Cazacu, Maria; Shova, Sergiu; Soroceanu, Alina; Machata, Peter; Bucinsky, Lukas; Breza, Martin; Rapta, Peter; Telser, Joshua; Krzystek, J; Arion, Vladimir B
2015-06-15
Mononuclear nickel(II), copper(II), and manganese(III) complexes with a noninnocent tetradentate Schiff base ligand containing a disiloxane unit were prepared in situ by reaction of 3,5-di-tert-butyl-2-hydroxybenzaldehyde with 1,3-bis(3-aminopropyl)tetramethyldisiloxane followed by addition of the appropriate metal(II) salt. The ligand H2L resulting from these reactions is a 2:1 condensation product of 3,5-di-tert-butyl-2-hydroxybenzaldehyde with 1,3-bis(3-aminopropyl)tetramethyldisiloxane. The resulting metal complexes, NiL·0.5CH2Cl2, CuL·1.5H2O, and MnL(OAc)·0.15H2O, were characterized by elemental analysis, spectroscopic methods (IR, UV-vis, X-band EPR, HFEPR, (1)H NMR), ESI mass spectrometry, and single crystal X-ray diffraction. Taking into account the well-known strong stabilizing effects of tert-butyl groups in positions 3 and 5 of the aromatic ring on phenoxyl radicals, we studied the one-electron and two-electron oxidation of the compounds using both experimental (chiefly spectroelectrochemistry) and computational (DFT) techniques. The calculated spin-density distribution and localized orbitals analysis revealed the oxidation locus and the effect of the electrochemical electron transfer on the molecular structure of the complexes, while time-dependent DFT calculations helped to explain the absorption spectra of the electrochemically generated species. Hyperfine coupling constants, g-tensors, and zero-field splitting parameters have been calculated at the DFT level of theory. Finally, the CASSCF approach has been employed to theoretically explore the zero-field splitting of the S = 2 MnL(OAc) complex for comparison purposes with the DFT and experimental HFEPR results. It is found that the D parameter sign strongly depends on the metal coordination geometry.
Hapka, Michał; Żuchowski, Piotr S; Szczęśniak, Małgorzata M; Chałasiński, Grzegorz
2012-10-28
Two open-shell formulations of the symmetry-adapted perturbation theory are presented. They are based on the spin-unrestricted Kohn-Sham (SAPT(UKS)) and unrestricted Hartree-Fock (SAPT(UHF)) descriptions of the monomers, respectively. The key reason behind development of SAPT(UKS) is that it is more compatible with density functional theory (DFT) compared to the previous formulation of open-shell SAPT based on spin-restricted Kohn-Sham method of Żuchowski et al. [J. Chem. Phys. 129, 084101 (2008)]. The performance of SAPT(UKS) and SAPT(UHF) is tested for the following open-shell van der Waals complexes: He···NH, H(2)O···HO(2), He···OH, Ar···OH, Ar···NO. The results show an excellent agreement between SAPT(UKS) and SAPT(ROKS). Furthermore, for the first time SAPT based on DFT is shown to be suitable for the treatment of interactions involving Π-state radicals (He···OH, Ar···OH, Ar···NO). In the interactions of transition metal dimers ((3)Σ(u)(+))Au(2) and ((13)Σ(g)(+))Cr(2) we show that SAPT is incompatible with the use of effective core potentials. The interaction energies of both systems expressed instead as supermolecular UHF interaction plus dispersion from SAPT(UKS) result in reasonably accurate potential curves.
Valenzuela, Sergio O; Saitoh, Eiji; Kimura, Takashi
2017-01-01
Since the discovery of the giant magnetoresistance effect in magnetic multilayers in 1988, a new branch of physics and technology, called spin-electronics or spintronics, has emerged, where the flow of electrical charge as well as the flow of electron spin, the so-called “spin current,” are manipulated and controlled together. The physics of magnetism and the application of spin current have progressed in tandem with the nanofabrication technology of magnets and the engineering of interfaces and thin films. This book aims to provide an introduction and guide to the new physics and applications of spin current, with an emphasis on the interaction between spin and charge currents in magnetic nanostructures.
2003-08-01
applications, a ferromagnetic metal may be used as a source of spin-polarized electronics to be injected into a semiconductor, a superconductor or a...physical phenomena in II-VI and III-V semiconductors. In II-VI systems, the Mn2+ ions act to boost the electron spin precession up to terahertz ...conductors, proximity effect between ferromagnets and superconductors , and the effects of spin injection on the physical properties of the
Vozková, Markéta
2011-01-01
1 ABSTRACT The aim of this text is to provide an analysis of the phenomenon of spin doctoring in the Euro-Atlantic area. Spin doctors are educated people in the fields of semiotics, cultural studies, public relations, political communication and especially familiar with the infrastructure and the functioning of the media industry. Critical reflection of manipulative communication techniques puts spin phenomenon in historical perspective and traces its practical use in today's social communica...
Bovier, Anton
2007-01-01
Spin glass theory is going through a stunning period of progress while finding exciting new applications in areas beyond theoretical physics, in particular in combinatorics and computer science. This collection of state-of-the-art review papers written by leading experts in the field covers the topic from a wide variety of angles. The topics covered are mean field spin glasses, including a pedagogical account of Talagrand's proof of the Parisi solution, short range spin glasses, emphasizing the open problem of the relevance of the mean-field theory for lattice models, and the dynamics of spin glasses, in particular the problem of ageing in mean field models. The book will serve as a concise introduction to the state of the art of spin glass theory, usefull to both graduate students and young researchers, as well as to anyone curious to know what is going on in this exciting area of mathematical physics.
Hong, Seungwoo; Pfaff, Florian Felix; Kwon, Eunji; Wang, Yong; Seo, Mi-Sook; Bill, Eckhard; Ray, Kallol; Nam, Wonwoo
2014-09-22
High-valent cobalt-oxo intermediates are proposed as reactive intermediates in a number of cobalt-complex-mediated oxidation reactions. Herein we report the spectroscopic capture of low-spin (S=1/2) Co(IV)-oxo species in the presence of redox-inactive metal ions, such as Sc(3+), Ce(3+), Y(3+), and Zn(2+), and the investigation of their reactivity in C-H bond activation and sulfoxidation reactions. Theoretical calculations predict that the binding of Lewis acidic metal ions to the cobalt-oxo core increases the electrophilicity of the oxygen atom, resulting in the redox tautomerism of a highly unstable [(TAML)Co(III)(O˙)](2-) species to a more stable [(TAML)Co(IV)(O)(M(n+))] core. The present report supports the proposed role of the redox-inactive metal ions in facilitating the formation of high-valent metal-oxo cores as a necessary step for oxygen evolution in chemistry and biology. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Abhervé, Alexandre; Recio-Carretero, María José; López-Jordà, Maurici; Clemente-Juan, Juan Modesto; Canet-Ferrer, Josep; Cantarero, Andrés; Clemente-León, Miguel; Coronado, Eugenio
2016-09-19
The synthesis and magnetostructural characterization of [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](ClO4)13·(CH3)2CO)6·(solvate) (2) are reported. This compound is obtained as a secondary product during synthesis of the mononuclear complex [Fe(II)(bppCOOH)2](ClO4)2 (1). The single-crystal X-ray diffraction structure of 2 shows that it contains the nonanuclear cluster of the formula [Fe(III)3(μ3-O)(H2O)3[Fe(II)(bppCOOH)(bppCOO)]6](13+), which is formed by a central Fe(III)3O core coordinated to six partially deprotonated [Fe(II)(bppCOOH)(bppCOO)](+) complexes. Raman spectroscopy studies on single crystals of 1 and 2 have been performed to elucidate the spin and oxidation states of iron in 2. These studies and magnetic characterization indicate that most of the iron(II) complexes of 2 remain in the low-spin (LS) state and present a gradual and incomplete spin crossover above 300 K. On the other hand, the Fe(III) trimer shows the expected antiferromagnetic behavior. From the structural point of view, 2 represents the first example in which bppCOO(-) acts as a bridging ligand, thus forming a polynuclear magnetic complex.
TOPICAL REVIEW: Spin current, spin accumulation and spin Hall effect
Directory of Open Access Journals (Sweden)
Saburo Takahashi and Sadamichi Maekawa
2008-01-01
Full Text Available Nonlocal spin transport in nanostructured devices with ferromagnetic injector (F1 and detector (F2 electrodes connected to a normal conductor (N is studied. We reveal how the spin transport depends on interface resistance, electrode resistance, spin polarization and spin diffusion length, and obtain the conditions for efficient spin injection, spin accumulation and spin current in the device. It is demonstrated that the spin Hall effect is caused by spin–orbit scattering in nonmagnetic conductors and gives rise to the conversion between spin and charge currents in a nonlocal device. A method of evaluating spin–orbit coupling in nonmagnetic metals is proposed.
Buhrman, Robert; Daughton, James; Molnár, Stephan; Roukes, Michael
2004-01-01
This report is a comparative review of spin electronics ("spintronics") research and development activities in the United States, Japan, and Western Europe conducted by a panel of leading U.S. experts in the field. It covers materials, fabrication and characterization of magnetic nanostructures, magnetism and spin control in magnetic nanostructures, magneto-optical properties of semiconductors, and magnetoelectronics and devices. The panel's conclusions are based on a literature review and a series of site visits to leading spin electronics research centers in Japan and Western Europe. The panel found that Japan is clearly the world leader in new material synthesis and characterization; it is also a leader in magneto-optical properties of semiconductor devices. Europe is strong in theory pertaining to spin electronics, including injection device structures such as tunneling devices, and band structure predictions of materials properties, and in development of magnetic semiconductors and semiconductor heterost...
International Nuclear Information System (INIS)
Fischer, K.H.; Hertz, J.A.
1993-01-01
Spin glasses, simply defined by the authors as a collection of spins (i.e., magnetic moments) whose low-temperature state is a frozen disordered one, represent one of the fascinating new fields of study in condensed matter physics, and this book is the first to offer a comprehensive account of the subject. Included are discussions of the most important developments in theory, experimental work, and computer modeling of spin glasses, all of which have taken place essentially within the last two decades. The first part of the book gives a general introduction to the basic concepts and a discussion of mean field theory, while the second half concentrates on experimental results, scaling theory, and computer simulation of the structure of spin glasses
Hogue, Ross W; Feltham, Humphrey L C; Miller, Reece G; Brooker, Sally
2016-05-02
Access to a new family of thioether-linked PSRT ligands, 4-substituted-3,5-bis{[(2-pyridylmethyl)sulfanyl]methyl}-4H-1,2,4-triazoles (analogues of the previously studied amino-linked PMRT ligands), has been established. Four such ligands have been prepared, PSPhT, PS(i)BuT, PS(t-Bu)PhT, and PS(Me)PhT, with R = Ph, (i)Bu, (t-Bu)Ph, and (Me)Ph, respectively. Three dinuclear colorless to pale green iron(II) complexes, [Fe(II)2(PSRT)2](BF4)4·solvent, featuring N4S2 donor sets, were prepared. Single-crystal structure determinations on [Fe(II)2(PSPhT)2](BF4)4·2MeCN·H2O, [Fe(II)2(PSPhT)2](BF4)4·2(1)/2MeCN·(1)/2H2O·THF, [Fe(II)2(PS(Me)PhT)2](BF4)4·2MeCN, and [Fe(II)2(PS(i)BuT)2](BF4)4·4MeCN reveal that all four are stabilized in the [HS-HS] state to 100 K and that both possible binding modes of the bis-terdentate ligands, cis- and trans-axial, are observed. Variable-temperature magnetic susceptibility studies of air-dried crystals (solvatomorphs of the single crystal samples) reveal the first examples of spin crossover (SCO) for a dinuclear iron(II) complex with N4S2 coordination. Specifically, [Fe(II)2(PSPhT)2](BF4)4·2(1)/2H2O undergoes a multistep but complete SCO from [HS-HS] to [LS-LS], whereas [Fe(II)2(PS(Me)PhT)2](BF4)4·1(1)/2MeCN·2H2O exhibits a half-SCO from [HS-HS] to [HS-LS]. In contrast, [Fe(II)2(PS(i)BuT)2](BF4)4·MeCN·H2O remains [HS-HS] down to 50 K. The reflectance spectrum of pale green [Fe(II)2(PSPhT)2](BF4)4·(1)/2CHCl3·2(1)/2H2O (solvatomorph A) reveals a trace of LS character (572 nm band (1)A1g → (1)T1g). Evans' (1)H NMR method and UV-vis spectroscopy studies revealed that on cooling dark green acetonitrile solutions of these complexes from 313 to 233 K, all three undergo SCO centered at or near room temperature. The tendency of the complexes to go LS in solution reflects the electronic impact of R on the σ-donor strength of the PSRT ligand, whereas the opposite trend in stabilization of the LS state is seen in the solid state, where
Hasegawa, Koji; Ono, Taka-aki; Inoue, Yorinao; Kusunoki, Masami
1999-01-01
Possible spin-exchange structures of the Mn(III,IV,IV,IV) cluster in an S 2 state of plant photosystem II were computer-searched, within the range compatible with X-ray absorption data, by diagonalizing each Heisenberg spin-exchange Hamiltonian and then by checking whether it can take the S=1/2 ground state capable of explaining the effective 55Mn hyperfine constants determined from oriented multiline spectra and the first excited state with excitation energy around 20-50 cm -1, or not. The possible spin-exchange structures were found to be distributed in those that contain only one strong-antiferromagnetic coupling and at most two intermediate coupling(s). The most probable structures are discussed in detail.
Wilbraham, Liam; Verma, Pragya; Truhlar, Donald G; Gagliardi, Laura; Ciofini, Ilaria
2017-05-04
The spin-state orderings in nine Fe(II) and Fe(III) complexes with ligands of diverse ligand-field strength were investigated with multiconfiguration pair-density functional theory (MC-PDFT). The performance of this method was compared to that of complete active space second-order perturbation theory (CASPT2) and Kohn-Sham density functional theory. We also investigated the dependence of CASPT2 and MC-PDFT results on the size of the active-space. MC-PDFT reproduces the CASPT2 spin-state ordering, the dependence on the ligand field strength, and the dependence on active space at a computational cost that is significantly reduced as compared to CASPT2.
Three-Spin System with a Twist: A Bis(semiquinonato)copper Complex with Non-Planar Copper(II) Center
Czech Academy of Sciences Publication Activity Database
Ye, S.; Sarkar, B.; Lissner, F.; Schleid, T.; van Slageren, J.; Fiedler, Jan; Kaim, W.
2005-01-01
Roč. 44, č. 14 (2005), s. 2103-2106 ISSN 1433-7851 R&D Projects: GA ČR GA203/03/0821; GA MŠk OC D15.10; GA AV ČR IAA400400505; GA MŠk 1P05OC068 Institutional research plan: CEZ:AV0Z40400503 Keywords : copper * electrochemistry * EPR spectroscopy * radical ligands * spin-spin interactions Subject RIV: CF - Physical ; Theoretical Chem istry Impact factor: 9.596, year: 2005
DEFF Research Database (Denmark)
Popovski, Petar; Simeone, Osvaldo; Nielsen, Jimmy Jessen
2015-01-01
on traffic load and interference condition leads to performance gains. In this letter, a general network of multiple interfering two-way links is studied under the assumption of a balanced load in the two directions for each link. Using the notion of interference spin, we introduce an algebraic framework...
Schwarz, H.
2017-01-01
The thesis "Spinning Worlds" is about the characterisation of two types of gas-giant exoplanets: Hot Jupiters, with orbital periods of fewer than five days, and young, wide-orbit gas giants, with orbital periods as long as thousands of years. The thesis is based on near-infrared observations of 1
Harding, David J; Phonsri, Wasinee; Harding, Phimphaka; Murray, Keith S; Moubaraki, Boujemaa; Jameson, Guy N L
2015-09-14
[Fe(qsal-Br)2]NO3·2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T½(1st step) = 136 K and T½(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.
Magnetic Exchange Couplings from Local Spin Analysis
Joshi, Rajendra; Abate, Bayileyegn Akanie; Peralta, Juan
We propose a method to calculate the magnetic exchange coupling parameters in transition metal complexes from a single spin-configuration. Our method uses constraint density functional theory and a local spin population analysis in combination to a non spin formalism to effectively extract the magnetic exchange parameter from the derivative of the electronic energy and spin pair correlation values. We show proof-of-concept calculations on the H-He-H systems and small transition metal complexes. DOE DE-SC0005027.
In a spin at Brookhaven spin physics
Makdisi, Y I
2003-01-01
The mysterious quantity that is spin took centre stage at Brookhaven for the SPIN2002 meeting last September. The 15th biennial International Spin Physics Symposium (SPIN2002) was held at Brookhaven National Laboratory on 9-14 September 2002. Some 250 spin enthusiasts attended, including experimenters and theorists in both nuclear and high-energy physics, as well as accelerator physicists and polarized target and polarized source experts. The six-day symposium included 23 plenary talks and 150 parallel talks. SPIN2002 was preceded by a one-day spin physics tutorial for students, postdocs, and anyone else who felt the need for a refresher course. (2 refs).
Spin transport in epitaxial graphene
Tbd, -
2014-03-01
Spintronics is a paradigm focusing on spin as the information vector in fast and ultra-low-power non volatile devices such as the new STT-MRAM. Beyond its widely distributed application in data storage it aims at providing more complex architectures and a powerful beyond CMOS solution for information processing. The recent discovery of graphene has opened novel exciting opportunities in terms of functionalities and performances for spintronics devices. We will present experimental results allowing us to assess the potential of graphene for spintronics. We will show that unprecedented highly efficient spin information transport can occur in epitaxial graphene leading to large spin signals and macroscopic spin diffusion lengths (~ 100 microns), a key enabler for the advent of envisioned beyond-CMOS spin-based logic architectures. We will also show that how the device behavior is well explained within the framework of the Valet-Fert drift-diffusion equations. Furthermore, we will show that a thin graphene passivation layer can prevent the oxidation of a ferromagnet, enabling its use in novel humide/ambient low-cost processes for spintronics devices, while keeping its highly surface sensitive spin current polarizer/analyzer behavior and adding new enhanced spin filtering property. These different experiments unveil promising uses of graphene for spintronics.
Spin Coherence in Semiconductor Nanostructures
National Research Council Canada - National Science Library
Flatte, Michael E
2006-01-01
... dots, tuning of spin coherence times for electron spin, tuning of dipolar magnetic fields for nuclear spin, spontaneous spin polarization generation and new designs for spin-based teleportation and spin transistors...
Sharma, Savita K; Schaefer, Andrew W; Lim, Hyeongtaek; Matsumura, Hirotoshi; Moënne-Loccoz, Pierre; Hedman, Britt; Hodgson, Keith O; Solomon, Edward I; Karlin, Kenneth D
2017-12-06
Peroxynitrite ( - OON═O, PN) is a reactive nitrogen species (RNS) which can effect deleterious nitrative or oxidative (bio)chemistry. It may derive from reaction of superoxide anion (O 2 •- ) with nitric oxide (·NO) and has been suggested to form an as-yet unobserved bound heme-iron-PN intermediate in the catalytic cycle of nitric oxide dioxygenase (NOD) enzymes, which facilitate a ·NO homeostatic process, i.e., its oxidation to the nitrate anion. Here, a discrete six-coordinate low-spin porphyrinate-Fe III complex [(P Im )Fe III ( - OON═O)] (3) (P Im ; a porphyrin moiety with a covalently tethered imidazole axial "base" donor ligand) has been identified and characterized by various spectroscopies (UV-vis, NMR, EPR, XAS, resonance Raman) and DFT calculations, following its formation at -80 °C by addition of ·NO (g) to the heme-superoxo species, [(P Im )Fe III (O 2 •- )] (2). DFT calculations confirm that 3 is a six-coordinate low-spin species with the PN ligand coordinated to iron via its terminal peroxidic anionic O atom with the overall geometry being in a cis-configuration. Complex 3 thermally transforms to its isomeric low-spin nitrato form [(P Im )Fe III (NO 3 - )] (4a). While previous (bio)chemical studies show that phenolic substrates undergo nitration in the presence of PN or PN-metal complexes, in the present system, addition of 2,4-di-tert-butylphenol ( 2,4 DTBP) to complex 3 does not lead to nitrated phenol; the nitrate complex 4a still forms. DFT calculations reveal that the phenolic H atom approaches the terminal PN O atom (farthest from the metal center and ring core), effecting O-O cleavage, giving nitrogen dioxide (·NO 2 ) plus a ferryl compound [(P Im )Fe IV ═O] (7); this rebounds to give [(P Im )Fe III (NO 3 - )] (4a).The generation and characterization of the long sought after ferriheme peroxynitrite complex has been accomplished.
Czech Academy of Sciences Publication Activity Database
Srnec, Martin; Chalupský, Jakub; Fojta, Miroslav; Zendlová, Lucie; Havran, Luděk; Hocek, Michal; Kývala, Mojmír; Rulíšek, Lubomír
2008-01-01
Roč. 130, č. 33 (2008), s. 10947-10954 ISSN 0002-7863 R&D Projects: GA MŠk LC512; GA MŠk(CZ) LC06035; GA ČR GA203/05/0936; GA ČR GA203/05/0043 Institutional research plan: CEZ:AV0Z40550506; CEZ:AV0Z50040507 Keywords : reduction potentials * spin-orbit coupling * relativistis effects * multireference calculations Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 8.091, year: 2008
International Nuclear Information System (INIS)
Ohnuma, Yuichi; Matsuo, Mamoru; Maekawa, Sadamichi; Saitoh, Eeiji
2017-01-01
Spin Seebeck and spin Peltier effects, which are mutual conversion phenomena of heat and spin, are discussed on the basis of the microscopic theory. First, the spin Seebeck effect, which is the spin-current generation due to heat current, is discussed. The recent progress in research on the spin Seebeck effect are introduced. We explain the origin of the observed sign changes of the spin Seebeck effect in compensated ferromagnets. Next, the spin Peltier effect, which is the heat-current generation due to spin current, is discussed. Finally, we show that the spin Seebeck and spin Peltier effects are summarized by Onsager's reciprocal relation and derive Kelvin's relation for the spin and heat transports. (author)
Hard Probes and Spin Physics at STAR
Tokarev, M V
2004-01-01
Spin is one of the most enigmatic and least understandable properties of elementary particles. The study of the proton spin puzzle is an important part of the physics program at the Relativistic Heavy Ion Collider (RHIC) accelerating both nuclei and polarized protons. STAR is one of the two large detectors at RHIC. It has an excellent capability for spin physics. In the present work the overview of the STAR spin physics program is given. It includes the highest priority measurements of single- and double-spin asymmetries allowing one to determine gluon contribution to proton spin, to separate sea and valence quark flavor polarizations, to measure quark transversity. A brief description of the RHIC accelerator complex, some detail of the STAR detector and its perfomance are presented.
Controlling a nuclear spin in a nanodiamond
Knowles, Helena S.; Kara, Dhiren M.; Atatüre, Mete
2017-09-01
The sensing capability of a single optically bright electronic spin in diamond can be enhanced by making use of proximal dark nuclei as ancillary spins. Such systems, so far realized only in bulk diamond, can provide orders of magnitude higher sensitivity and spectral resolution in the case of magnetic sensing, as well as improved readout fidelity and state storage time in quantum information schemes. Nanodiamonds offer opportunities for scanning and embedded nanoscale probes, yet electronic-nuclear spin complexes have so far remained inaccessible. Here, we demonstrate coherent control of a 13C nuclear spin located 4 Å from a nitrogen-vacancy center in a nanodiamond and show coherent exchange between the two components of this hybrid spin system. We extract a free precession time T2* of 26 μ s for the nuclear spin, which exceeds the bare-electron free-precession time in nanodiamond by two orders of magnitude.
Spin trapping in γ-irradiated system
International Nuclear Information System (INIS)
Taniguchi, Hitoshi
1998-01-01
Spin trapping techniques, allowing one to visualize transient free radical populations by reacting short-lived radicals with a spin trap to produce persistent spin adduct radicals, require that the rate constant for parent radical addition to the spin trap be sufficiently large. The study on the rate of spin trapping reactions, dependent upon steric and electronic (polar) interactions in the complex, has been extended to nitrone spin trapping using 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. We concentrated on the trapping of carboxyalkyl radicals which feature strong hydrogen bonding between the hydroxyl group of the spin addend carboxyl function and the aminosyl oxygen, and a strongly electron withdrawing effect of the spin addend on the DMPO ring. These two features in these radicals, enhancing the polarization of the N 1 -C 2 bond to produce spin adduct fragmentation, were found to be significantly more pronounced than in the case of hydroxylalkyl radical adducts to DMPO. (J.P.N.)
High frequency spin torque oscillators with composite free layer spin valve
International Nuclear Information System (INIS)
Natarajan, Kanimozhi; Arumugam, Brinda; Rajamani, Amuda
2016-01-01
We report the oscillations of magnetic spin components in a composite free layer spin valve. The associated Landau–Lifshitz–Gilbert–Slonczewski (LLGS) equation is studied by stereographically projecting the spin on to a complex plane and the spin components were found. A fourth order Runge–Kutta numerical integration on LLGS equation also confirms the similar trajectories of the spin components. This study establishes the possibility of a Spin Torque Oscillator in a composite free layer spin valve, where the exchange coupling is ferromagnetic in nature. In-plane and out-of-plane precessional modes of magnetization oscillations were found in zero applied magnetic field and the frequencies of the oscillations were calculated from Fast Fourier Transform of the components of magnetization. Behavior of Power Spectral Density for a range of current density is studied. Finally our analysis shows the occurrence of highest frequency 150 GHz, which is in the second harmonics for the specific choice of system parameters.
High-spin nuclear spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Diamond, R.M.
1986-07-01
High-spin spectroscopy is the study of the changes in nuclear structure, properties, and behavior with increasing angular momentum. It involves the complex interplay between collective and single-particle motion, between shape and deformation changes, particle alignments, and changes in the pairing correlations. A review of progress in theory, experimentation, and instrumentation in this field is given. (DWL)
Nuclear spin pumping and electron spin susceptibilities
Danon, J.; Nazarov, Y.V.
2011-01-01
In this work we present a new formalism to evaluate the nuclear spin dynamics driven by hyperfine interaction with nonequilibrium electron spins. To describe the dynamics up to second order in the hyperfine coupling it suffices to evaluate the susceptibility and fluctuations of the electron spin.
Widespread spin polarization effects in photoemission from topological insulators
Energy Technology Data Exchange (ETDEWEB)
Jozwiak, C.; Chen, Y. L.; Fedorov, A. V.; Analytis, J. G.; Rotundu, C. R.; Schmid, A. K.; Denlinger, J. D.; Chuang, Y.-D.; Lee, D.-H.; Fisher, I. R.; Birgeneau, R. J.; Shen, Z.-X.; Hussain, Z.; Lanzara, A.
2011-06-22
High-resolution spin- and angle-resolved photoemission spectroscopy (spin-ARPES) was performed on the three-dimensional topological insulator Bi{sub 2}Se{sub 3} using a recently developed high-efficiency spectrometer. The topological surface state's helical spin structure is observed, in agreement with theoretical prediction. Spin textures of both chiralities, at energies above and below the Dirac point, are observed, and the spin structure is found to persist at room temperature. The measurements reveal additional unexpected spin polarization effects, which also originate from the spin-orbit interaction, but are well differentiated from topological physics by contrasting momentum and photon energy and polarization dependencies. These observations demonstrate significant deviations of photoelectron and quasiparticle spin polarizations. Our findings illustrate the inherent complexity of spin-resolved ARPES and demonstrate key considerations for interpreting experimental results.
Kwon, Yoon Hye; Mai, Binh Khanh; Lee, Yong-Min; Dhuri, Sunder N; Mandal, Debasish; Cho, Kyung-Bin; Kim, Yongho; Shaik, Sason; Nam, Wonwoo
2015-04-16
We show by experiments that nonheme Fe(IV)O species react with cyclohexene to yield selective hydrogen atom transfer (HAT) reactions with virtually no C═C epoxidation. Straightforward DFT calculations reveal, however, that C═C epoxidation on the S = 2 state possesses a low-energy barrier and should contribute substantially to the oxidation of cyclohexene by the nonheme Fe(IV)O species. By modeling the selectivity of this two-site reactivity, we show that an interplay of tunneling and spin inversion probability (SIP) reverses the apparent barriers and prefers exclusive S = 1 HAT over mixed HAT and C═C epoxidation on S = 2. The model enables us to derive a SIP value by combining experimental and theoretical results.
Magnetic Nanostructures Spin Dynamics and Spin Transport
Farle, Michael
2013-01-01
Nanomagnetism and spintronics is a rapidly expanding and increasingly important field of research with many applications already on the market and many more to be expected in the near future. This field started in the mid-1980s with the discovery of the GMR effect, recently awarded with the Nobel prize to Albert Fert and Peter Grünberg. The present volume covers the most important and most timely aspects of magnetic heterostructures, including spin torque effects, spin injection, spin transport, spin fluctuations, proximity effects, and electrical control of spin valves. The chapters are written by internationally recognized experts in their respective fields and provide an overview of the latest status.
Fujinami, Takeshi; Nishi, Koshiro; Hamada, Daisuke; Murakami, Keishiro; Matsumoto, Naohide; Iijima, Seiichiro; Kojima, Masaaki; Sunatsuki, Yukinari
2015-08-03
Solvent-free spin crossover Fe(II) complex fac-[Fe(II)(HL(n-Pr))3]Cl·PF6 was prepared, where HL(n-Pr) denotes 2-methylimidazol-4-yl-methylideneamino-n-propyl. The magnetic susceptibility measurements at scan rate of 0.5 K min(-1) showed two successive spin transition processes consisting of the first spin transition T1 centered at 122 K (T1↑ = 127.1 K, T1↓ = 115.8 K) and the second spin transition T2 centered at ca. 105 K (T2↑ = 115.8 K, T2↓ = 97.2 K). The magnetic susceptibility measurements at the scan rate of 2.0, 1.0, 0.5, 0.25, and 0.1 K min(-1) showed two scan speed dependent spin transitions, while the Mössbauer spectra detected only the first spin transition T1. The crystal structures were determined at 160, 143, 120, 110, 95 K in the cooling mode, and 110, 120, and 130 K in the warming mode so as to follow the spin transition process of high-spin HS → HS(T1) → HS(T2) → low-spin LS → LS(T2) → LS(T1) → HS. The crystal structures at all temperatures have a triclinic space group P1̅ with Z = 2. The complex-cation has an octahedral N6 coordination geometry with three bidentate ligands and assume a facial-isomer with Δ- and Λ-enantimorphs. Three imidazole groups of fac-[Fe(II)(HL(n-Pr))3](2+) are hydrogen-bonded to three Cl(-) ions. The 3:3 NH(imidazole)···Cl(-) hydrogen-bonds form a stepwise ladder assembly structure, which is maintained during the spin transition process. The spin transition process is related to the structural changes of the FeN6 coordination environment, the order-disorder of PF6(-) anion, and the conformation change of n-propyl groups. The Fe-N bond distance in the HS state is longer by 0.2 Å than that in the LS state. Disorder of PF6(-) anion is not observed in the LS state but in the HS state. The conformational changes of n-propyl groups are found in the spin transition processes except for HS → HS(T1) → HS(T2).
Decoherence dynamics of a single spin versus spin ensemble
Dobrovitski, V.V.; Feiguin, A.E.; Awschalom, D.D.; Hanson, R.
2008-01-01
We study decoherence of central spins by a spin bath, focusing on the difference between measurement of a single central spin and measurement of a large number of central spins (as found in typical spin-resonance experiments). For a dilute spin bath, the single spin demonstrates Gaussian
A New Spin on Photoemission Spectroscopy
Energy Technology Data Exchange (ETDEWEB)
Jozwiak, Chris [Univ. of California, Berkeley, CA (United States)
2008-12-01
The electronic spin degree of freedom is of general fundamental importance to all matter. Understanding its complex roles and behavior in the solid state, particularly in highly correlated and magnetic materials, has grown increasingly desirable as technology demands advanced devices and materials based on ever stricter comprehension and control of the electron spin. However, direct and efficient spin dependent probes of electronic structure are currently lacking. Angle Resolved Photoemission Spectroscopy (ARPES) has become one of the most successful experimental tools for elucidating solid state electronic structures, bolstered by-continual breakthroughs in efficient instrumentation. In contrast, spin-resolved photoemission spectroscopy has lagged behind due to a lack of similar instrumental advances. The power of photoemission spectroscopy and the pertinence of electronic spin in the current research climate combine to make breakthroughs in Spin and Angle Resolved Photoemission Spectroscopy (SARPES) a high priority . This thesis details the development of a unique instrument for efficient SARPES and represents a radical departure from conventional methods. A custom designed spin polarimeter based on low energy exchange scattering is developed, with projected efficiency gains of two orders of magnitude over current state-of-the-art polarimeters. For energy analysis, the popular hemispherical analyzer is eschewed for a custom Time-of-Flight (TOF) analyzer offering an additional order of magnitude gain in efficiency. The combined instrument signifies the breakthrough needed to perform the high resolution SARPES experiments necessary for untangling the complex spin-dependent electronic structures central to today's condensed matter physics.
Brouard, M.; Hughes, D. W.; Kalogerakis, K. S.; Simons, J. P.
2000-03-01
The product-state-resolved dynamics of the reaction H+CO2→OH(2Π;ν,N,Ω,f)+CO have been explored in the gas phase at 298 K and center-of-mass collision energies of 2.5 and 1.8 eV (respectively, 241 and 174 kJ mol-1), using photon initiation coupled with Doppler-resolved laser-induced fluorescence detection. A broad range of quantum-state-resolved differential cross sections (DCSs) and correlated product kinetic energy distributions have been measured to explore their sensitivity to spin-orbit, Λ-doublet, rotational and vibrational state selection in the scattered OH. The new measurements reveal a rich dynamical picture. The channels leading to OH(Ω,N˜1) are remarkably sensitive to the choice of spin-orbit state: Those accessing the lower state, Ω=3/2, display near-symmetric forward-backward DCSs consistent with the intermediacy of a short-lived, rotating HOCO (X˜ 2A') collision complex, but those accessing the excited spin-orbit state, Ω=1/2, are strongly focused backwards at the higher collision energy, indicating an alternative, near-direct microscopic pathway proceeding via an excited potential energy surface. The new results offer a new way of reconciling the conflicting results of earlier ultrafast kinetic studies. At the higher collision energy, the state-resolved DCSs for the channels leading to OH(Ω,N˜5-11) shift from forward-backward symmetric toward sideways-forward scattering, a behavior which resembles that found for the analogous reaction of fast H atoms with N2O. The correlated product kinetic energy distributions also bear a similarity to the H/N2O reaction; on average, 40% of the available energy is concentrated in rotation and/or vibration in the scattered CO, somewhat less than predicted by a phase space theory calculation. At the lower collision energy the discrepancy is much greater, and the fraction of internal excitation in the CO falls closer to 30%. All the results are consistent with a dynamical model involving short
Spin-polarized spin excitation spectroscopy
International Nuclear Information System (INIS)
Loth, Sebastian; Lutz, Christopher P; Heinrich, Andreas J
2010-01-01
We report on the spin dependence of elastic and inelastic electron tunneling through transition metal atoms. Mn, Fe and Cu atoms were deposited onto a monolayer of Cu 2 N on Cu(100) and individually addressed with the probe tip of a scanning tunneling microscope. Electrons tunneling between the tip and the substrate exchange energy and spin angular momentum with the surface-bound magnetic atoms. The conservation of energy during the tunneling process results in a distinct onset threshold voltage above which the tunneling electrons create spin excitations in the Mn and Fe atoms. Here we show that the additional conservation of spin angular momentum leads to different cross-sections for spin excitations depending on the relative alignment of the surface spin and the spin of the tunneling electron. For this purpose, we developed a technique for measuring the same local spin with a spin-polarized and a non-spin-polarized tip by exchanging the last apex atom of the probe tip between different transition metal atoms. We derive a quantitative model describing the observed excitation cross-sections on the basis of an exchange scattering process.
Magnons, Spin Current and Spin Seebeck Effect
Maekawa, Sadamichi
2012-02-01
When metals and semiconductors are placed in a temperature gradient, the electric voltage is generated. This mechanism to convert heat into electricity, the so-called Seebeck effect, has attracted much attention recently as the mechanism for utilizing wasted heat energy. [1]. Ferromagnetic insulators are good conductors of spin current, i.e., the flow of electron spins [2]. When they are placed in a temperature gradient, generated are magnons, spin current and the spin voltage [3], i.e., spin accumulation. Once the spin voltage is converted into the electric voltage by inverse spin Hall effect in attached metal films such as Pt, the electric voltage is obtained from heat energy [4-5]. This is called the spin Seebeck effect. Here, we present the linear-response theory of spin Seebeck effect based on the fluctuation-dissipation theorem [6-8] and discuss a variety of the devices. [4pt] [1] S. Maekawa et al, Physics of Transition Metal Oxides (Springer, 2004). [0pt] [2] S. Maekawa: Nature Materials 8, 777 (2009). [0pt] [3] Concept in Spin Electronics, eds. S. Maekawa (Oxford University Press, 2006). [0pt] [4] K. Uchida et al., Nature 455, 778 (2008). [0pt] [5] K. Uchida et al., Nature Materials 9, 894 (2010) [0pt] [6] H. Adachi et al., APL 97, 252506 (2010) and Phys. Rev. B 83, 094410 (2011). [0pt] [7] J. Ohe et al., Phys. Rev. B (2011) [0pt] [8] K. Uchida et al., Appl. Phys. Lett. 97, 104419 (2010).
Spin state switching in iron coordination compounds
Directory of Open Access Journals (Sweden)
Philipp Gütlich
2013-02-01
Full Text Available The article deals with coordination compounds of iron(II that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure and irradiation with light. The spin states involved have different magnetic and optical properties suitable for their detection and characterization. Spin crossover compounds, though known for more than eight decades, have become most attractive in recent years and are extensively studied by chemists and physicists. The switching properties make such materials potential candidates for practical applications in thermal and pressure sensors as well as optical devices.The article begins with a brief description of the principle of molecular spin state switching using simple concepts of ligand field theory. Conditions to be fulfilled in order to observe spin crossover will be explained and general remarks regarding the chemical nature that is important for the occurrence of spin crossover will be made. A subsequent section describes the molecular consequences of spin crossover and the variety of physical techniques usually applied for their characterization. The effects of light irradiation (LIESST and application of pressure are subjects of two separate sections. The major part of this account concentrates on selected spin crossover compounds of iron(II, with particular emphasis on the chemical and physical influences on the spin crossover behavior. The vast variety of compounds exhibiting this fascinating switching phenomenon encompasses mono-, oligo- and polynuclear iron(II complexes and cages, polymeric 1D, 2D and 3D systems, nanomaterials, and polyfunctional materials that combine spin crossover with another physical or chemical property.
Abdel-Rahman, Laila H.; El-Khatib, Rafat M.; Nassr, Lobna A. E.; Abu-Dief, Ahmed M.; Lashin, Fakhr El-Din
2013-07-01
In this study, new Fe(II) Schiff base amino acid chelates derived from the condensation of o-hydroxynaphthaldehyde with L-alanine, L-phenylalanine, L-aspartic acid, L-histidine and L-arginine were synthesized and characterized via elemental, thermogravimetric analysis, molar conductance, IR, electronic, mass spectra and magnetic moment measurements. The stoichiometry and the stability constants of the complexes were determined spectrophotometrically. Correlation of all spectroscopic data suggested that Schiff bases ligands exhibited tridentate with ONO sites coordinating to the metal ions via protonated phenolic-OH, azomethine-N and carboxylate-O with the general formulae [Fe(HL)2]·nH2O. But in case of L-histidine, the ligand acts as tetradentate via deprotonated phenolic-OH, azomethine-N, carboxylate-O and N-imidazole ring ([FeL(H2O)2]·2H2O), where HL = mono anion and L = dianion of the ligand. The structure of the prepared complexes is suggested to be octahedral. The prepared complexes were tested for their teratogenicity on chick embryos and found to be safe until a concentration of 100 μg/egg with full embryos formation. Moreover, the interaction between CT-DNA and the investigated complexes were followed by spectrophotometric and viscosity measurements. It was found that, the prepared complexes bind to DNA via classical intercalative mode and showed a different DNA activity with the sequence: nhi > nari > nali > nasi > nphali. Furthermore, the free ligands and their complexes are screened for their in vitro antibacterial and antifungal activity against three types of bacteria, Escherichia coli, Pseudomonas aeruginosa and Bacillus cereus and three types of anti fungal cultures, Penicillium purpurogenium, Aspergillus flavus and Trichotheium rosium in order to assess their antimicrobial potential. The results show that the metal complexes are more reactive with respect to their corresponding Schiff base amino acid ligands.
High-Spin Cobalt Hydrides for Catalysis
Energy Technology Data Exchange (ETDEWEB)
Holland, Patrick L. [Univ. of Rochester, NY (United States)
2013-08-29
Organometallic chemists have traditionally used catalysts with strong-field ligands that give low-spin complexes. However, complexes with a weak ligand field have weaker bonds and lower barriers to geometric changes, suggesting that they may lead to more rapid catalytic reactions. Developing our understanding of high-spin complexes requires the use of a broader range of spectroscopic techniques, but has the promise of changing the mechanism and/or selectivity of known catalytic reactions. These changes may enable the more efficient utilization of chemical resources. A special advantage of cobalt and iron catalysts is that the metals are more abundant and cheaper than those currently used for major industrial processes that convert unsaturated organic molecules and biofeedstocks into useful chemicals. This project specifically evaluated the potential of high-spin cobalt complexes for small-molecule reactions for bond rearrangement and cleavage reactions relevant to hydrocarbon transformations. We have learned that many of these reactions proceed through crossing to different spin states: for example, high-spin complexes can flip one electron spin to access a lower-energy reaction pathway for beta-hydride elimination. This reaction enables new, selective olefin isomerization catalysis. The high-spin cobalt complexes also cleave the C-O bond of CO2 and the C-F bonds of fluoroarenes. In each case, the detailed mechanism of the reaction has been determined. Importantly, we have discovered that the cobalt catalysts described here give distinctive selectivities that are better than known catalysts. These selectivities come from a synergy between supporting ligand design and electronic control of the spin-state crossing in the reactions.
Matsuo, Mamoru; Saitoh, Eiji; Maekawa, Sadamichi
2017-01-01
We investigate the interconversion phenomena between spin and mechanical angular momentum in moving objects. In particular, the recent results on spin manipulation and spin-current generation by mechanical motion are examined. In accelerating systems, spin-dependent gauge fields emerge, which enable the conversion from mechanical angular momentum into spins. Such a spin-mechanical effect is predicted by quantum theory in a non-inertial frame. Experiments which confirm the effect, i.e., the resonance frequency shift in nuclear magnetic resonance, the stray field measurement of rotating metals, and electric voltage generation in liquid metals, are discussed.
Two-dimensional spin diffusion in multiterminal lateral spin valves
Saha, D.; Basu, D.; Holub, M.; Bhattacharya, P.
2008-01-01
The effects of two-dimensional spin diffusion on spin extraction in lateral semiconductor spin valves have been investigated experimentally and theoretically. A ferromagnetic collector terminal of variable size is placed between the ferromagnetic electron spin injector and detector of a conventional lateral spin valve for spin extraction. It is observed that transverse spin diffusion beneath the collector terminal plays an important role along with the conventional longitudinal spin diffusion in describing the overall transport of spin carriers. Two-dimensional spin diffusion reduces the perturbation of the channel electrochemical potentials and improves spin extraction.
Czech Academy of Sciences Publication Activity Database
Sarkar, B.; Patra, S.; Fiedler, Jan; Sunoj, R. B.; Janardanan, D.; Mobin, S. M.; Niemeyer, M.; Lahiri, G. K.; Kaim, W.
2005-01-01
Roč. 44, č. 35 (2005), s. 5655-5658 ISSN 0044-8249 R&D Projects: GA AV ČR IAA400400505; GA ČR GA203/03/0821; GA MŠk LC510 Institutional research plan: CEZ:AV0Z40400503 Keywords : azobispyridine * bridging ligand s * mixed -valed complexes * N- ligand s Subject RIV: CF - Physical ; Theoretical Chemistry
DEFF Research Database (Denmark)
Leibold, Michael; Kisslinger, Sandra; Heinemann, Frank W.
2016-01-01
-pyridylmethyl)amine, also abbreviated as tpa in the literature] we modified the ligand by increasing systematically the chelate ring sizes from 5 to 6 thus obtaining complexes [Fe(pmea)(NCS)2], [Fe(pmap)(NCS)2], and [Fe(tepa)(NCS)2] [pmea = N,N-bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine, pmap = N,N-bis[2...
Dynamic nuclear spin polarization
Energy Technology Data Exchange (ETDEWEB)
Stuhrmann, H.B. [GKSS-Forschungszentrum Geesthacht GmbH (Germany)
1996-11-01
Polarized neutron scattering from dynamic polarized targets has been applied to various hydrogenous materials at different laboratories. In situ structures of macromolecular components have been determined by nuclear spin contrast variation with an unprecedented precision. The experiments of selective nuclear spin depolarisation not only opened a new dimension to structural studies but also revealed phenomena related to propagation of nuclear spin polarization and the interplay of nuclear polarisation with the electronic spin system. The observation of electron spin label dependent nuclear spin polarisation domains by NMR and polarized neutron scattering opens a way to generalize the method of nuclear spin contrast variation and most importantly it avoids precontrasting by specific deuteration. It also likely might tell us more about the mechanism of dynamic nuclear spin polarisation. (author) 4 figs., refs.
International Nuclear Information System (INIS)
Anon.
1980-01-01
From 25 September to 1 October, some 150 spin enthusiasts gathered in Lausanne for the 1980 International Symposium on High Energy Physics with Polarized Beams and Polarized Targets. The programme was densely packed, covering physics interests with spin as well as the accelerator and target techniques which make spin physics possible
Bauer, G.E.W.; Brataas, A.; Tserkovnyak, Y.; Van Wees, B.J.
2003-01-01
A magnetoelectronic thin-film transistor is proposed that can display negative differential resistance and gain. The working principle is the modulation of the soure–drain current in a spin valve by the magnetization of a third electrode, which is rotated by the spin-torque created by a control spin
Wang, Qiang; Venneri, Shari; Zarrabi, Niloofar; Wang, Hongfeng; Desplanches, Cédric; Létard, Jean-François; Seda, Takele; Pilkington, Melanie
2015-04-21
The Schiff-base condensation of the R,R-(+)-diamine () with 2,6-diacetyl pyridine in the presence of Fe(II) affords the macrocyclic complex [Fe(dpN3O2)(CN)2] () (dp = diphenyl) with ligand centred chirality comprising of a 1 : 1 mixture of LS 6- and HS 7-coordinate Fe(II) centres. Variable temperature magnetic susceptibility and Mössbauer studies reveal that () undergoes an incomplete thermal SCO transition with a T1/2 = 250 K as well as a LIESST effect. In contrast its racemic counterpart () comprises of mostly LS Fe(II) and exhibits no LIESST properties.
Energy Technology Data Exchange (ETDEWEB)
Kamusella, Sirko
2017-03-01
In this thesis the superconducting and magnetic phases of LiOH(Fe,Co)(Se,S), CuFeAs/CuFeSb, and LaFeP{sub 1-x}As{sub x}O - belonging to the 11, 111 and 1111 structural classes of iron-based arsenides and chalcogenides - are investigated by means of {sup 57}Fe Moessbauer spectroscopy and muon spin rotation/relaxation (μSR). Of major importance in this study is the application of high magnetic fields in Moessbauer spectroscopy to distinguish and characterize ferro- (FM) and antiferromagnetic (AFM) order. A user-friendly Moessbauer data analysis program was developed to provide suitable model functions not only for high field spectra, but relaxation spectra or parameter distributions in general. In LaFeP{sub 1-x}As{sub x}O the reconstruction of the Fermi surface is described by the vanishing of the Γ hole pocket with decreasing x. The continuous change of the orbital character and the covalency of the d-electrons is shown by Moessbauer spectroscopy. A novel antiferromagnetic phase with small magnetic moments of ∼ 0.1 μ{sub B} state is characterized. The superconducting order parameter is proven to continuously change from a nodal to a fully gapped s-wave like Fermi surface in the superconducting regime as a function of x, partially investigated on (O,F) substituted samples. LiOHFeSe is one of the novel intercalated FeSe compounds, showing strongly increased T{sub C} = 43 K mainly due to increased interlayer spacing and resulting two-dimensionality of the Fermi surface. The primary interest of the samples of this thesis is the simultaneously observed ferromagnetism and superconductivity. The local probe techniques prove that superconducting sample volume gets replaced by ferromagnetic volume. Ferromagnetism arises from magnetic order with T{sub C} = 10 K of secondary iron in the interlayer. The tendency of this system to show (Li,Fe) disorder is preserved upon (Se,S) substitution. However, superconductivity gets suppressed. The results of Moessbauer spectroscopy
Latanowicz, L; Medycki, W; Jakubas, R
2009-11-01
Molecular dynamics of a polycrystalline sample of [(CH(3))(4)P](3)Sb(2)Br(9) (PBA) has been studied on the basis of the T(1) (24.7 MHz) relaxation time measurement, the proton second moment of NMR and the earlier published T(1) (90 MHz) relaxation times. The study was performed in a wide range of temperatures (30-337 K). The tunnel splitting omega(T) of the methyl groups was estimated as of low frequency (from kHz to few MHz). The proton spin pairs of the methyl group are known to perform a complex internal motion being a resultant of four components. Three of them involve mass transportation over and through the potential barrier and are characterized by the correlation times tau(3) and tau(T)of the jumps over the barrier and tunnel jumps in the threefold potential of the methyl group and tau(iso) the correlation time of isotropic rotation of the whole TMP cation. For tau(3) and tau(iso) the Arrhenius temperature dependence was assumed, while for tau(T)--the Schrödinger one. The fourth motion causes fluctuations of the tunnel splitting frequency, omega(T), and it is related to the lifetime of the methyl spin at the energy level. The correlation function for this fourth motion (tau(omega) correlation time) has been proposed by Müller-Warmuth et al. In this paper a formula for the correlation function and spectral density of the complex motion made of the above-mentioned four components was derived and used in interpretation of the T(1) relaxation time. The second moment of proton NMR line at temperatures below 50K is four times lower than its value for the rigid structure. The three components of the internal motion characterized by tau(T), tau(H), and tau(iso) were proved to reduce the second moment of the NMR line. The tunnel jumps of the methyl group reduce M(2) at almost 0K, the classical jumps over the barrier reduce M(2) in the vicinity of 50K, while the isotropic motion near 150K. Results of the study on the dynamics of CH(3) groups of TMP cation based on
Spin physics in semiconductors
2017-01-01
This book offers an extensive introduction to the extremely rich and intriguing field of spin-related phenomena in semiconductors. In this second edition, all chapters have been updated to include the latest experimental and theoretical research. Furthermore, it covers the entire field: bulk semiconductors, two-dimensional semiconductor structures, quantum dots, optical and electric effects, spin-related effects, electron-nuclei spin interactions, Spin Hall effect, spin torques, etc. Thanks to its self-contained style, the book is ideally suited for graduate students and researchers new to the field.
Cuc, Diana; Bouguet-Bonnet, Sabine; Morel-Desrosiers, Nicole; Morel, Jean-Pierre; Mutzenhardt, Pierre; Canet, Daniel
2009-03-19
This study deals with the exact location of the monovalent metal cations Cs(+) and Tl(+) which are complexed by the p-sulfonatocalix[4]arene in water. This determination rests on the measurements of longitudinal relaxation times of carbon-13 not directly bonded to protons. The difference between the relaxation times of the free calixarene and of the complex definitely demonstrates that the monovalent metal cation is well inside the calixarene cavity. These features are in fact enhanced by the presence of paramagnetic species which act in a different way in the complexed form. Experimental results also show without any ambiguity that the calixarene cavity is essentially hydrophobic. Finally, it is observed that thallium is more mobile than cesium within the calixarene cavity.
Ziaei, Vafa; Bredow, Thomas
2017-03-17
The reliable calculation of the excited states of charge-transfer (CT) compounds poses a major challenge to the ab initio community because the frequently employed method, time-dependent density functional theory (TD-DFT), massively relies on the underlying density functional, resulting in heavily Hartree-Fock (HF) exchange-dependent excited-state energies. By applying the highly sophisticated many-body perturbation approach, we address the encountered unreliabilities and inconsistencies of not optimally tuned (standard) TD-DFT regarding photo-excited CT phenomena, and present results concerning accurate vertical transition energies and the correct energetic ordering of the CT and the first visible singlet state of a recently synthesized thermodynamically stable large hybrid perylene bisimide-macrocycle complex. This is a large-scale application of the quantum many-body perturbation approach to a chemically relevant CT system, demonstrating the system-size independence of the quality of the many-body-based excitation energies. Furthermore, an optimal tuning of the ωB97X hybrid functional can well reproduce the many-body results, making TD-DFT a suitable choice but at the expense of introducing a range-separation parameter, which needs to be optimally tuned. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Sousa, Carmen; Domingo, Alex; de Graaf, Coen
2017-11-16
The second-order spin-orbit coupling is evaluated in two transition-metal complexes to establish the effect on the deactivation mechanism of the excited low-spin state in systems that undergo spin transitions under the influence of light. We compare the standard perturbational approach to calculate the second-order interaction with a variational strategy based on the effective Hamiltonian theory and show that the former one can only be applied in some special cases and even then gives results that largely overestimate the interaction. The combined effect of geometry distortions and second-order spin-orbit coupling leads to sizeable interactions for states that are nearly uncoupled in the symmetric (average) structure of the complex. This opens the possibility of a direct deactivation from the singlet and triplet states of the metal-to-ligand charge-transfer manifold to the final high-spin state as suggested from the interpretation of experimental data but so far not supported by theoretical descriptions of the light-induced spin crossover. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Delcey, Mickaël G; Freitag, Leon; Pedersen, Thomas Bondo; Aquilante, Francesco; Lindh, Roland; González, Leticia
2014-05-07
We present a formulation of analytical energy gradients at the complete active space self-consistent field (CASSCF) level of theory employing density fitting (DF) techniques to enable efficient geometry optimizations of large systems. As an example, the ground and lowest triplet state geometries of a ruthenium nitrosyl complex are computed at the DF-CASSCF level of theory and compared with structures obtained from density functional theory (DFT) using the B3LYP, BP86, and M06L functionals. The average deviation of all bond lengths compared to the crystal structure is 0.042 Å at the DF-CASSCF level of theory, which is slightly larger but still comparable with the deviations obtained by the tested DFT functionals, e.g., 0.032 Å with M06L. Specifically, the root-mean-square deviation between the DF-CASSCF and best DFT coordinates, delivered by BP86, is only 0.08 Å for S0 and 0.11 Å for T1, indicating that the geometries are very similar. While keeping the mean energy gradient errors below 0.25%, the DF technique results in a 13-fold speedup compared to the conventional CASSCF geometry optimization algorithm. Additionally, we assess the singlet-triplet energy vertical and adiabatic differences with multiconfigurational second-order perturbation theory (CASPT2) using the DF-CASSCF and DFT optimized geometries. It is found that the vertical CASPT2 energies are relatively similar regardless of the geometry employed whereas the adiabatic singlet-triplet gaps are more sensitive to the chosen triplet geometry.
Muon spin relaxation in random spin systems
International Nuclear Information System (INIS)
Toshimitsu Yamazaki
1981-01-01
The longitudinal relaxation function Gsub(z)(t) of the positive muon can reflect dynamical characters of local field in a unique way even when the correlation time is longer than the Larmor period of local field. This method has been applied to studies of spin dynamics in spin glass systems, revealing sharp but continuous temperature dependence of the correlation time. Its principle and applications are reviewed. (author)
Zimmerman, Paul M; Bell, Franziska; Goldey, Matthew; Bell, Alexis T; Head-Gordon, Martin
2012-10-28
The restricted active space spin flip (RAS-SF) method is extended to allow ground and excited states of molecular radicals to be described at low cost (for small numbers of spin flips). RAS-SF allows for any number of spin flips and a flexible active space while maintaining pure spin eigenfunctions for all states by maintaining a spin complete set of determinants and using spin-restricted orbitals. The implementation supports both even and odd numbers of electrons, while use of resolution of the identity integrals and a shared memory parallel implementation allow for fast computation. Examples of multiple-bond dissociation, excited states in triradicals, spin conversions in organic multi-radicals, and mixed-valence metal coordination complexes demonstrate the broad usefulness of RAS-SF.
The susceptibilities in the spin-S Ising model
International Nuclear Information System (INIS)
Ainane, A.; Saber, M.
1995-08-01
The susceptibilities of the spin-S Ising model are evaluated using the effective field theory introduced by Tucker et al. for studying general spin-S Ising model. The susceptibilities are studied for all spin values from S = 1/2 to S = 5/2. (author). 12 refs, 4 figs
Henneaux, Marc; Vasiliev, Mikhail A
2017-01-01
Symmetries play a fundamental role in physics. Non-Abelian gauge symmetries are the symmetries behind theories for massless spin-1 particles, while the reparametrization symmetry is behind Einstein's gravity theory for massless spin-2 particles. In supersymmetric theories these particles can be connected also to massless fermionic particles. Does Nature stop at spin-2 or can there also be massless higher spin theories. In the past strong indications have been given that such theories do not exist. However, in recent times ways to evade those constraints have been found and higher spin gauge theories have been constructed. With the advent of the AdS/CFT duality correspondence even stronger indications have been given that higher spin gauge theories play an important role in fundamental physics. All these issues were discussed at an international workshop in Singapore in November 2015 where the leading scientists in the field participated. This volume presents an up-to-date, detailed overview of the theories i...
Spin caloritronics in graphene
Energy Technology Data Exchange (ETDEWEB)
Ghosh, Angsula; Frota, H. O. [Department of Physics, Federal University of Amazonas, Av. Rodrigo Octavio 3000-Japiim, 69077-000 Manaus, AM (Brazil)
2015-06-14
Spin caloritronics, the combination of spintronics with thermoelectrics, exploiting both the intrinsic spin of the electron and its associated magnetic moment in addition to its fundamental electronic charge and temperature, is an emerging technology mainly in the development of low-power-consumption technology. In this work, we study the thermoelectric properties of a Rashba dot attached to two single layer/bilayer graphene sheets as leads. The temperature difference on the two graphene leads induces a spin current, which depends on the temperature and chemical potential. We demonstrate that the Rashba dot behaves as a spin filter for selected values of the chemical potential and is able to filter electrons by their spin orientation. The spin thermopower has also been studied where the effects of the chemical potential, temperature, and also the Rashba term have been observed.
Spin caloritronics in graphene
Frota, H. O.; Ghosh, Angsula
2014-08-01
Spin caloritronics, the combination of spintronics with thermoelectrics, based on spin and heat transport has attracted a great attention mainly in the development of low-power-consumption technology. In this work we study the thermoelectric properties of a quantum dot attached to two single layer graphene sheets as leads. The temperature difference on the two graphene leads induces a spin current which depends on the temperature and chemical potential. We demonstrate that the quantum dot behaves as a spin filter for selected values of the chemical potential and is able to filter electrons by their spin orientation. The spin thermopower has also been studied where the effects of the chemical potential, temperature and also the Coulomb repulsion due to the double occupancy of an energy level have been observed.
Gaggioli, Carlo Alberto; Belpassi, Leonardo; Tarantelli, Francesco; Harvey, Jeremy N; Belanzoni, Paola
2017-10-31
A spin-forbidden chemical reaction involves a change in the total electronic spin state from reactants to products. The mechanistic study is challenging because such a reaction does not occur on a single diabatic potential energy surface (PES), but rather on two (or multiple) spin diabatic PESs. One possible approach is to calculate the so-called "minimum energy crossing point" (MECP) between the diabatic PESs, which however is not a stationary point. Inclusion of spin-orbit coupling between spin states (SOC approach) allows the reaction to occur on a single adiabatic PES, in which a transition state (TS SOC) as well as activation free energy can be calculated. This Concept article summarizes a previously published application in which, for the first time, the SOC effects, using spin-orbit ZORA Hamiltonian within density functional theory (DFT) framework, are included and account for the mechanism of a spin-forbidden reaction in gold chemistry. The merits of the MECP and TS SOC approaches and the accuracy of the results are compared, considering both our recent calculations on molecular oxygen addition to gold(I)-hydride complexes and new calculations for the prototype spin-forbidden N 2 O and N 2 Se dissociation reactions. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Quantum computing with acceptor spins in silicon.
Salfi, Joe; Tong, Mengyang; Rogge, Sven; Culcer, Dimitrie
2016-06-17
The states of a boron acceptor near a Si/SiO2 interface, which bind two low-energy Kramers pairs, have exceptional properties for encoding quantum information and, with the aid of strain, both heavy hole and light hole-based spin qubits can be designed. Whereas a light-hole spin qubit was introduced recently (arXiv:1508.04259), here we present analytical and numerical results proving that a heavy-hole spin qubit can be reliably initialised, rotated and entangled by electrical means alone. This is due to strong Rashba-like spin-orbit interaction terms enabled by the interface inversion asymmetry. Single qubit rotations rely on electric-dipole spin resonance (EDSR), which is strongly enhanced by interface-induced spin-orbit terms. Entanglement can be accomplished by Coulomb exchange, coupling to a resonator, or spin-orbit induced dipole-dipole interactions. By analysing the qubit sensitivity to charge noise, we demonstrate that interface-induced spin-orbit terms are responsible for sweet spots in the dephasing time [Formula: see text] as a function of the top gate electric field, which are close to maxima in the EDSR strength, where the EDSR gate has high fidelity. We show that both qubits can be described using the same starting Hamiltonian, and by comparing their properties we show that the complex interplay of bulk and interface-induced spin-orbit terms allows a high degree of electrical control and makes acceptors potential candidates for scalable quantum computation in Si.
Directory of Open Access Journals (Sweden)
Giorgio Papini
2017-12-01
Full Text Available We study the spin current tensor of a Dirac particle at accelerations close to the upper limit introduced by Caianiello. Continual interchange between particle spin and angular momentum is possible only when the acceleration is time-dependent. This represents a stringent limit on the effect that maximal acceleration may have on spin physics in astrophysical applications. We also investigate some dynamical consequences of maximal acceleration.
Czech Academy of Sciences Publication Activity Database
Jungwirth, Tomáš; Wunderlich, Joerg; Olejník, Kamil
2012-01-01
Roč. 11, č. 5 (2012), s. 382-390 ISSN 1476-1122 EU Projects: European Commission(XE) 268066 - 0MSPIN; European Commission(XE) 215368 - SemiSpinNet Grant - others:AV ČR(CZ) AP0801 Program:Akademická prémie - Praemium Academiae Institutional research plan: CEZ:AV0Z10100521 Keywords : spin Hall effect * spintronics * spin transistor Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 35.749, year: 2012
Torczynski, John R.
2000-01-01
A spin coating apparatus requires less cleanroom air flow than prior spin coating apparatus to minimize cleanroom contamination. A shaped exhaust duct from the spin coater maintains process quality while requiring reduced cleanroom air flow. The exhaust duct can decrease in cross section as it extends from the wafer, minimizing eddy formation. The exhaust duct can conform to entrainment streamlines to minimize eddy formation and reduce interprocess contamination at minimal cleanroom air flow rates.
International Nuclear Information System (INIS)
Hakioglu, T
2009-01-01
Based on Khodas et al (2004 Phys. Rev. Lett. 92 086602), we propose a device acting like a controllable prism for an incident spin. The device is a large quantum well where Rashba and Dresselhaus spin-orbit interactions are present and controlled by the plunger gate potential, the electric field and the barrier height. A totally destructive interference can be manipulated externally between the Rashba and Dresselhaus couplings. The spin-dependent transmission/reflection amplitudes are calculated as the control parameters are changed. The device operates as a spin prism/converter/filter in different regimes and may stimulate research in promising directions in spintronics in analogy with linear optics.
International Nuclear Information System (INIS)
Murakami, Shuichi
2009-01-01
We review our recent theoretical works on the quantum spin Hall effect. First we compare edge states in various 2D systems, and see whether they are robust or fragile against perturbations. Through the comparisons we see the robust nature of edge states in 2D quantum spin Hall phases. We see how it is protected by the Z 2 topological number, and reveal the nature of the Z 2 topological number by studying the phase transition between the quantum spin Hall and insulator phases. We also review our theoretical proposal of the ultrathin bismuth film as a candidate to the 2D quantum spin Hall system. (author)
International Nuclear Information System (INIS)
Fischer, K.H.
1985-01-01
Experimental results of spin glass studies are reviewed and related to existing theories. Investigations of spin glasses are concentrated on atomic structure, metallurgical treatment, and high-temperature susceptibility of alloys, on magnetic properties at low temperature and near the freezing temperature, on anisotropy behaviour measured by ESR, NMR and torque, on specific heat, Moessbauer effect, neutron scattering and muon-spin depolarization experiments, ultrasound and transport properties. Some new theories of spin glasses are discussed which have been developed since Part I appeared
Effects of spin-orbit coupling on the spin structure of deposited transition-metal clusters
Mankovsky, S.; Bornemann, S.; Minár, J.; Polesya, S.; Ebert, H.; Staunton, J. B.; Lichtenstein, A. I.
2009-07-01
The influence of the spin-orbit coupling on the magnetic structure of deposited transition-metal nanostructures has been studied by fully relativistic electronic-structure calculations. The interplay of exchange coupling and magnetic anisotropy was monitored by studying the corresponding magnetic torque calculated within ab initio and model approaches. We find that a spin-orbit-induced Dzyaloshinski-Moriya interaction has a profound effect on the spin structure of such complex magnetic systems and that in combination with magnetic anisotropies and isotropic exchange this can result in peculiar magnetic properties.
Noise in tunneling spin current across coupled quantum spin chains
Aftergood, Joshua; Takei, So
2017-01-01
We theoretically study the spin current and its dc noise generated between two spin-1/2 spin chains weakly coupled at a single site in the presence of an over-population of spin excitations and a temperature elevation in one subsystem relative to the other, and compare the corresponding transport quantities across two weakly coupled magnetic insulators hosting magnons. In the spin chain scenario, we find that applying a temperature bias exclusively leads to a vanishing spin current and a conc...
Hung, Sheng-Wei; Yang, Fuh-An; Chen, Jyh-Horung; Wang, Shin-Shin; Tung, Jo-Yu
2008-08-18
The crystal structures of diamagnetic dichloro(2-aza-2-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrinato-N,N',N'')-tin(IV) methanol solvate [Sn(2-NCH 3NCTPP)Cl 2.2(0.2MeOH); 6.2(0.2MeOH)] and paramagnetic bromo(2-aza-2-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrinato-N,N',N'')-manganese(III) [Mn(2-NCH 3NCTPP)Br; 5] were determined. The coordination sphere around Sn (4+) in 6.2(0.2MeOH) is described as six-coordinate octahedron ( OC-6) in which the apical site is occupied by two transoid Cl (-) ligands, whereas for the Mn (3+) ion in 5, it is a five-coordinate square pyramid ( SPY-5) in which the unidentate Br (-) ligand occupies the axial site. The g value of 9.19 (or 10.4) measured from the parallel polarization (or perpendicular polarization) of X-band EPR spectra at 4 K is consistent with a high spin mononuclear manganese(III) ( S = 2) in 5. The magnitude of axial ( D) and rhombic ( E) zero-field splitting (ZFS) for the mononuclear Mn(III) in 5 were determined approximately as -2.4 cm (-1) and -0.0013 cm (-1), respectively, by paramagnetic susceptibility measurements and conventional EPR spectroscopy. Owing to weak C(45)-H(45A)...Br(1) hydrogen bonds, the mononuclear Mn(III) neutral molecules of 5 are arranged in a one-dimensional network. A weak Mn(III)...Mn(III) ferromagnetic interaction ( J = 0.56 cm (-1)) operates via a [Mn(1)-C(2)-C(1)-N(4)-C(45)-H(45A)...Br(1)-Mn(1)] superexchange pathway in complex 5.
Effect of spin rotation coupling on spin transport
International Nuclear Information System (INIS)
Chowdhury, Debashree; Basu, B.
2013-01-01
We have studied the spin rotation coupling (SRC) as an ingredient to explain different spin-related issues. This special kind of coupling can play the role of a Dresselhaus like coupling in certain conditions. Consequently, one can control the spin splitting, induced by the Dresselhaus like term, which is unusual in a semiconductor heterostructure. Within this framework, we also study the renormalization of the spin-dependent electric field and spin current due to the k → ⋅p → perturbation, by taking into account the interband mixing in the rotating system. In this paper we predict the enhancement of the spin-dependent electric field resulting from the renormalized spin rotation coupling. The renormalization factor of the spin electric field is different from that of the SRC or Zeeman coupling. The effect of renormalized SRC on spin current and Berry curvature is also studied. Interestingly, in the presence of this SRC-induced SOC it is possible to describe spin splitting as well as spin galvanic effect in semiconductors. -- Highlights: •Studied effect of spin rotation coupling on the spin electric field, spin current and Berry curvature. •In the k → ⋅p → framework we study the renormalization of spin electric field and spin current. •For an inertial system we have discussed the spin splitting. •Expression for the Berry phase in the inertial system is discussed. •The inertial spin galvanic effect is studied
Spin labels. Applications in biology
International Nuclear Information System (INIS)
Frangopol, T.P.; Frangopol, M.; Ionescu, S.M.; Pop, I.V.; Benga, G.
1980-11-01
The main applications of spin labels in the study of biomembranes, enzymes, nucleic acids, in pharmacology, spin immunoassay are reviewed along with the fundamentals of the spin label method. 137 references. (author)
International Nuclear Information System (INIS)
Bushuev, M.B.; Lavrenova, L.G.; Shvedenkov, Yu.G.; Varnek, V.A.; Sheludyakova, L.A.; Volkov, V.V.; Larionov, S.V.
2008-01-01
Methods for the synthesis of iron(II) complexes with 1,2,4-triazole (HTrz) and 4-amino-1,2,4-triazole (NH 2 Trz) containing the decahydro-closo-decaborate ion [B 10 H 10 ] 2 -were developed. The empirical formulas of the complexes were Fe(HTrz) 3 B 10 H 10 · H 2 O (I) and Fe(NH 2 Trz) 3 B 10 H 10 · H 2 O (II). The complexes were examined by static magnetic susceptibility measurements in the temperature range 2-300 K and Moessbauer, IR, and electronic spectroscopy. Complex I exhibits the reversible spin transition 1 A 1 ↔ 5 T 2 and pink ↔ white thermochromism. The temperatures of the forward and reverse transitions in complex I were 246 and 233 K, respectively. Complex II remained in the high-spin state over the whole temperature range. The sharp decrease in its effective magnetic moment at T 2+ ions [ru
Azman, Adam M.; Esteb, John J.
2016-01-01
A coin-flipping analogy and free corresponding web app have been developed to facilitate student understanding of the origins of spin-spin splitting. First-order splitting patterns can easily be derived and understood. "Complex" splitting patterns (e.g., doublet of quartets), are easily incorporated into the analogy. A study of the…
Spin Switching via Quantum Dot Spin Valves
Gergs, N. M.; Bender, S. A.; Duine, R. A.; Schuricht, D.
2018-01-01
We develop a theory for spin transport and magnetization dynamics in a quantum dot spin valve, i.e., two magnetic reservoirs coupled to a quantum dot. Our theory is able to take into account effects of strong correlations. We demonstrate that, as a result of these strong correlations, the dot gate voltage enables control over the current-induced torques on the magnets and, in particular, enables voltage-controlled magnetic switching. The electrical resistance of the structure can be used to read out the magnetic state. Our model may be realized by a number of experimental systems, including magnetic scanning-tunneling microscope tips and artificial quantum dot systems.
Quantum state transfer in spin chains via shortcuts to adiabaticity
Huang, Bi-Hua; Kang, Yi-Hao; Chen, Ye-Hong; Shi, Zhi-Cheng; Song, Jie; Xia, Yan
2018-01-01
Based on shortcuts to adiabaticity and quantum Zeno dynamics, we present a protocol to implement quantum state transfer (QST) in a quantum spin-1/2 chain. In the protocol, the complex Hamiltonian of an N -site system is simplified, and a simple effective Hamiltonian is present. It is shown that only the control of the coupling strengths between the boundary spins and the bulk spins are required for QST. Numerical simulations demonstrate that the protocol possesses high efficiency and is robust against the decay and the fluctuations of the control fields. The protocol might provide an alternative choice for transferring quantum states via spin chain systems.
Controlling spin flips of molecules in an electromagnetic trap
Reens, David; Wu, Hao; Langen, Tim; Ye, Jun
2017-12-01
Doubly dipolar molecules exhibit complex internal spin dynamics when electric and magnetic fields are both applied. Near magnetic trap minima, these spin dynamics lead to enhancements in Majorana spin-flip transitions by many orders of magnitude relative to atoms and are thus an important obstacle for progress in molecule trapping and cooling. We conclusively demonstrate and address this with OH molecules in a trap geometry where spin-flip losses can be tuned from over 200 s-1 to below our 2 s-1 vacuum-limited loss rate with only a simple external bias coil and with minimal impact on trap depth and gradient.
Energy Technology Data Exchange (ETDEWEB)
Peskin, M.E. [Stanford Univ., CA (United States)
1994-12-01
When the strong interactions were a mystery, spin seemed to be just a complication on top of an already puzzling set of phenomena. But now that particle physicists have understood the strong, weak, and electromagnetic interactions, to be gauge theories, with matter built of quarks and leptons, it is recognized that the special properties of spin 1/2 and spin 1 particles have taken central role in the understanding of Nature. The lectures in this summer school will be devoted to the use of spin in unravelling detailed questions about the fundamental interactions. Thus, why not begin by posing a deeper question: Why is there spin? More precisely, why do the basic pointlike constituents of Nature carry intrinsic nonzero quanta of angular momentum? Though the authos has found no definite answer to this question, the pursuit of an answer has led through a wonderful tangle of speculations on the deep structure of Nature. Is spin constructed or is it fundamental? Is it the requirement of symmetry? In the furthest flights taken, it seems that space-time itself is too restrictive a notion, and that this must be generalized in order to gain a full appreciation of spin. In any case, there is no doubt that spin must play a central role in unlocking the mysteries of fundamental physics.
Hawkes, N
1999-01-01
RAL is fostering commerical exploitation of its research and facilities in two main ways : spin-out companies exploit work done at the lab, spin-in companies work on site taking advantage of the facilities and the expertise available (1/2 page).
International Nuclear Information System (INIS)
Masaike, Akira
1993-01-01
Despite playing a major role in today's Standard Model, spin - the intrinsic angular momentum carried by particles - is sometimes dismissed as an inessential complication. However several major spin questions with important implications for the Standard Model remain unanswered, and recent results and new technological developments made the 10th International Symposium on High Energy Spin Physics, held in Nagoya, Japan, in November, highly topical. The symposium covered a wide range of physics, reflecting the diversity of spin effects, however four main themes were - the spin content of the nucleon, tests of symmetries and physics beyond standard models, intermediate energy physics, and spin technologies. Opening the meeting, T. Kinoshita reviewed the status of measurements of the anomalous magnetic moment (g-2) of the electron and the muon. The forthcoming experiment at Brookhaven (September 1991, page 23) will probe beyond the energy ranges open to existing electronpositron colliders. For example muon substructure will be opened up to 5 TeV and Ws to 2 TeV. R.L. Jaffe classified quark-parton distributions in terms of their spin dependence, pointing out their leftright attributes, and emphasized the importance of measuring transverse spin distributions through lepton pair production
Kamra, A.; Witek, F.P.; Meyer, S.; Huebl, H.; Geprägs, S.; Gross, R.; Bauer, G.E.W.; Goennenwein, S.T.B.
2014-01-01
We measure the low-frequency thermal fluctuations of pure spin current in a platinum film deposited on yttrium iron garnet via the inverse spin Hall effect (ISHE)-mediated voltage noise as a function of the angle ? between the magnetization and the transport direction. The results are consistent
Antiferromagnetic spin Seebeck effect.
Energy Technology Data Exchange (ETDEWEB)
Wu, Stephen M.; Zhang, Wei; KC, Amit; Borisov, Pavel; Pearson, John E.; Jiang, J. Samuel; Lederman, David; Hoffmann, Axel; Bhattacharya, Anand
2016-03-03
We report on the observation of the spin Seebeck effect in antiferromagnetic MnF2. A device scale on-chip heater is deposited on a bilayer of MnF2 (110) (30nm)/Pt (4 nm) grown by molecular beam epitaxy on a MgF2(110) substrate. Using Pt as a spin detector layer, it is possible to measure the thermally generated spin current from MnF2 through the inverse spin Hall effect. The low temperature (2–80 K) and high magnetic field (up to 140 kOe) regime is explored. A clear spin-flop transition corresponding to the sudden rotation of antiferromagnetic spins out of the easy axis is observed in the spin Seebeck signal when large magnetic fields (>9T) are applied parallel to the easy axis of the MnF2 thin film. When the magnetic field is applied perpendicular to the easy axis, the spin-flop transition is absent, as expected.
International Nuclear Information System (INIS)
Peskin, M.E.
1994-01-01
When the strong interactions were a mystery, spin seemed to be just a complication on top of an already puzzling set of phenomena. But now that particle physicists have understood the strong, weak, and electromagnetic interactions, to be gauge theories, with matter built of quarks and leptons, it is recognized that the special properties of spin 1/2 and spin 1 particles have taken central role in the understanding of Nature. The lectures in this summer school will be devoted to the use of spin in unravelling detailed questions about the fundamental interactions. Thus, why not begin by posing a deeper question: Why is there spin? More precisely, why do the basic pointlike constituents of Nature carry intrinsic nonzero quanta of angular momentum? Though the authos has found no definite answer to this question, the pursuit of an answer has led through a wonderful tangle of speculations on the deep structure of Nature. Is spin constructed or is it fundamental? Is it the requirement of symmetry? In the furthest flights taken, it seems that space-time itself is too restrictive a notion, and that this must be generalized in order to gain a full appreciation of spin. In any case, there is no doubt that spin must play a central role in unlocking the mysteries of fundamental physics
DEFF Research Database (Denmark)
Jensen, J.; Houmann, Jens Christian Gylden; Bjerrum Møller, Hans
1975-01-01
with increasing temperatures implies that the two-ion coupling is effectively isotropic above ∼ 150 K. We present arguments for concluding that, among the mechanisms which may introduce anisotropic two-ion couplings in the rare-earth metals, the modification of the indirect exchange interaction by the spin......The energies of spin waves propagating in the c direction of Tb have been studied by inelastic neutron scattering, as a function of a magnetic field applied along the easy and hard directions in the basal plane, and as a function of temperature. From a general spin Hamiltonian, consistent...... with the symmetry, we deduce the dispersion relation for the spin waves in a basal-plane ferromagnet. This phenomenological spin-wave theory accounts for the observed behavior of the magnon energies in Tb. The two q⃗-dependent Bogoliubov components of the magnon energies are derived from the experimental results...
Spherical 2+p spin-glass model: An exactly solvable model for glass to spin-glass transition
International Nuclear Information System (INIS)
Crisanti, A.; Leuzzi, L.
2004-01-01
We present the full phase diagram of the spherical 2+p spin-glass model with p≥4. The main outcome is the presence of a phase with both properties of full replica symmetry breaking phases of discrete models, e.g., the Sherrington-Kirkpatrick model, and those of one replica symmetry breaking. This phase has a finite complexity which leads to different dynamic and static properties. The phase diagram is rich enough to allow the study of different kinds of glass to spin glass and spin glass to spin glass phase transitions
Decay of Rabi Oscillations by Dipolar-Coupled Dynamical Spin Environments
Dobrovitski, V.V.; Feiguin, A.E.; Hanson, R.; Awschalom, D.D.
2009-01-01
We study the Rabi oscillations decay of a spin decohered by a spin bath whose internal dynamics is caused by dipolar coupling between the bath spins. The form and rate of decay as a function of the intrabath coupling is obtained analytically, and confirmed numerically. The complex form of decay
Nam, W; Lee, H J; Oh, S Y; Kim, C; Jang, H G
2000-07-01
An electron-rich iron(III) porphyrin complex (meso-tetramesitylporphinato)iron(III) chloride [Fe(TMP)Cl], was found to catalyze the epoxidation of olefins by aqueous 30% H2O2 when the reaction was carried out in the presence of 5-chloro-1-methylimidazole (5-Cl-1-Melm) in aprotic solvent. Epoxides were the predominant products with trace amounts of allylic oxidation products, indicating that Fenton-type oxidation reactions were not involved in the olefin epoxidation reactions. cis-Stilbene was stereospecifically oxidized to cis-stilbene oxide without giving isomerized trans-stilbene oxide product, demonstrating that neither hydroperoxy radical (HOO*) nor oxoiron(IV) porphyrin [(TMP)FeIV=O] was responsible for the olefin epoxidations. We also found that the reactivities of other iron(III) porphyrin complexes such as (meso-tetrakis(2,6-dichlorophenyl)porphinato)iron(III) chloride [Fe(TDCPP)Cl], (meso-tetrakis(2,6-difluorophenyl)porphinato)iron(III) chloride [Fe(TDFPP)Cl], and (meso-tetrakis(pentafluorophenyl)porphinato)iron(III) chloride [Fe(TPFPP)CI] were significantly affected by the presence of the imidazole in the epoxidation of olefins by H2O2. These iron porphyrin complexes did not yield cyclohexene oxide in the epoxidation of cyclohexene by H2O2 in the absence of 5-Cl-1-MeIm in aprotic solvent; however, addition of 5-Cl-1-MeIm to the reaction solutions gave high yields of cyclohexene oxide with the formation of trace amounts of allylic oxidation products. We proposed, on the basis of the results of mechanistic studies, that the role of the imidazole is to decelerate the O-O bond cleavage of an iron(III) hydroperoxide porphyrin (or H2O2-iron(II) porphyrin adduct) and that the intermediate transfers its oxygen to olefins prior to the O-O bond cleavage.
Ting, David Z.
2007-01-01
The resonant tunneling spin pump is a proposed semiconductor device that would generate spin-polarized electron currents. The resonant tunneling spin pump would be a purely electrical device in the sense that it would not contain any magnetic material and would not rely on an applied magnetic field. Also, unlike prior sources of spin-polarized electron currents, the proposed device would not depend on a source of circularly polarized light. The proposed semiconductor electron-spin filters would exploit the Rashba effect, which can induce energy splitting in what would otherwise be degenerate quantum states, caused by a spin-orbit interaction in conjunction with a structural-inversion asymmetry in the presence of interfacial electric fields in a semiconductor heterostructure. The magnitude of the energy split is proportional to the electron wave number. Theoretical studies have suggested the possibility of devices in which electron energy states would be split by the Rashba effect and spin-polarized currents would be extracted by resonant quantum-mechanical tunneling.
Nuclear spins in nanostructures
International Nuclear Information System (INIS)
Coish, W.A.; Baugh, J.
2009-01-01
We review recent theoretical and experimental advances toward understanding the effects of nuclear spins in confined nanostructures. These systems, which include quantum dots, defect centers, and molecular magnets, are particularly interesting for their importance in quantum information processing devices, which aim to coherently manipulate single electron spins with high precision. On one hand, interactions between confined electron spins and a nuclear-spin environment provide a decoherence source for the electron, and on the other, a strong effective magnetic field that can be used to execute local coherent rotations. A great deal of effort has been directed toward understanding the details of the relevant decoherence processes and to find new methods to manipulate the coupled electron-nuclear system. A sequence of spectacular new results have provided understanding of spin-bath decoherence, nuclear spin diffusion, and preparation of the nuclear state through dynamic polarization and more general manipulation of the nuclear-spin density matrix through ''state narrowing.'' These results demonstrate the richness of this physical system and promise many new mysteries for the future. (Abstract Copyright [2009], Wiley Periodicals, Inc.)
Spin drift and spin diffusion currents in semiconductors
Energy Technology Data Exchange (ETDEWEB)
Idrish Miah, M [Nanoscale Science and Technology Centre and School of Biomolecular and Physical Sciences, Griffith University, Nathan, Brisbane, QLD 4111 (Australia)], E-mail: m.miah@griffith.edu.au
2008-09-15
On the basis of a spin drift-diffusion model, we show how the spin current is composed and find that spin drift and spin diffusion contribute additively to the spin current, where the spin diffusion current decreases with electric field while the spin drift current increases, demonstrating that the extension of the spin diffusion length by a strong field does not result in a significant increase in spin current in semiconductors owing to the competing effect of the electric field on diffusion. We also find that there is a spin drift-diffusion crossover field for a process in which the drift and diffusion contribute equally to the spin current, which suggests a possible method of identifying whether the process for a given electric field is in the spin drift or spin diffusion regime. Spin drift-diffusion crossover fields for GaAs are calculated and are found to be quite small. We derive the relations between intrinsic spin diffusion length and the spin drift-diffusion crossover field of a semiconductor for different electron statistical regimes. The findings resulting from this investigation might be important for semiconductor spintronics.
Spin drift and spin diffusion currents in semiconductors
Directory of Open Access Journals (Sweden)
M Idrish Miah
2008-01-01
Full Text Available On the basis of a spin drift-diffusion model, we show how the spin current is composed and find that spin drift and spin diffusion contribute additively to the spin current, where the spin diffusion current decreases with electric field while the spin drift current increases, demonstrating that the extension of the spin diffusion length by a strong field does not result in a significant increase in spin current in semiconductors owing to the competing effect of the electric field on diffusion. We also find that there is a spin drift-diffusion crossover field for a process in which the drift and diffusion contribute equally to the spin current, which suggests a possible method of identifying whether the process for a given electric field is in the spin drift or spin diffusion regime. Spin drift-diffusion crossover fields for GaAs are calculated and are found to be quite small. We derive the relations between intrinsic spin diffusion length and the spin drift-diffusion crossover field of a semiconductor for different electron statistical regimes. The findings resulting from this investigation might be important for semiconductor spintronics.
Spin drift and spin diffusion currents in semiconductors
International Nuclear Information System (INIS)
Idrish Miah, M
2008-01-01
On the basis of a spin drift-diffusion model, we show how the spin current is composed and find that spin drift and spin diffusion contribute additively to the spin current, where the spin diffusion current decreases with electric field while the spin drift current increases, demonstrating that the extension of the spin diffusion length by a strong field does not result in a significant increase in spin current in semiconductors owing to the competing effect of the electric field on diffusion. We also find that there is a spin drift-diffusion crossover field for a process in which the drift and diffusion contribute equally to the spin current, which suggests a possible method of identifying whether the process for a given electric field is in the spin drift or spin diffusion regime. Spin drift-diffusion crossover fields for GaAs are calculated and are found to be quite small. We derive the relations between intrinsic spin diffusion length and the spin drift-diffusion crossover field of a semiconductor for different electron statistical regimes. The findings resulting from this investigation might be important for semiconductor spintronics.
Kraus, Per; Ross, Simon F.
2013-05-01
The principles of quantum mechanics and relativity impose rigid constraints on theories of massless particles with nonzero spin. Indeed, Yang-Mills theory and General Relativity are the unique solution in the case of spin-1 and spin-2. In asymptotically flat spacetime, there are fundamental obstacles to formulating fully consistent interacting theories of particles of spin greater than 2. However, indications are that such theories are just barely possible in asymptotically anti-de Sitter or de Sitter spacetimes, where the non-existence of an S-matrix provides an escape from the theorems restricting theories in Minkowski spacetime. These higher spin gravity theories are therefore of great intrinsic interest, since they, along with supergravity, provide the only known field theories generalizing the local invariance principles of Yang-Mills theory and General Relativity. While work on higher spin gravity goes back several decades, the subject has gained broader appeal in recent years due to its appearance in the AdS/CFT correspondence. In three and four spacetime dimensions, there exist duality proposals linking higher spin gravity theories to specific conformal field theories living in two and three dimensions respectively. The enlarged symmetry algebra of the conformal field theories renders them exactly soluble, which makes them excellent laboratories for understanding in detail the holographic mechanism behind AdS/CFT duality. Steady progress is also being made on better understanding the space of possible higher spin gravity theories and their physical content. This work includes classifying the possible field multiplets and their interactions, constructing exact solutions of the nonlinear field equations, and relating higher spin theories to string theory. A full understanding of these theories will involve coming to grips with the novel symmetry principles that enlarge those of General Relativity and Yang-Mills theory, and one can hope that this will provide
Spin transfer torque with spin diffusion in magnetic tunnel junctions
Manchon, Aurelien
2012-08-09
Spin transport in magnetic tunnel junctions in the presence of spin diffusion is considered theoretically. Combining ballistic tunneling across the barrier and diffusive transport in the electrodes, we solve the spin dynamics equation in the metallic layers. We show that spin diffusion mixes the transverse spin current components and dramatically modifies the bias dependence of the effective spin transfer torque. This leads to a significant linear bias dependence of the out-of-plane torque, as well as a nonconventional thickness dependence of both spin torque components.
Electron spin and nuclear spin manipulation in semiconductor nanosystems
International Nuclear Information System (INIS)
Hirayama, Yoshiro; Yusa, Go; Sasaki, Satoshi
2006-01-01
Manipulations of electron spin and nuclear spin have been studied in AlGaAs/GaAs semiconductor nanosystems. Non-local manipulation of electron spins has been realized by using the correlation effect between localized and mobile electron spins in a quantum dot- quantum wire coupled system. Interaction between electron and nuclear spins was exploited to achieve a coherent control of nuclear spins in a semiconductor point contact device. Using this device, we have demonstrated a fully coherent manipulation of any two states among the four spin levels of Ga and As nuclei. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
McWeeny, Roy
2004-01-01
Originally delivered as a series of lectures, this volume systematically traces the evolution of the ""spin"" concept from its role in quantum mechanics to its assimilation into the field of chemistry. Author Roy McWeeny presents an in-depth illustration of the deductive methods of quantum theory and their application to spins in chemistry, following the path from the earliest concepts to the sophisticated physical methods employed in the investigation of molecular structure and properties. Starting with the origin and development of the spin concept, the text advances to an examination of sp
2013-01-01
This book covers all principal aspects of currently investigated frustrated systems, from exactly solved frustrated models to real experimental frustrated systems, going through renormalization group treatment, Monte Carlo investigation of frustrated classical Ising and vector spin models, low-dimensional systems, spin ice and quantum spin glass. The reader can - within a single book - obtain a global view of the current research development in the field of frustrated systems.This new edition is updated with recent theoretical, numerical and experimental developments in the field of frustrated
Czech Academy of Sciences Publication Activity Database
Wunderlich, Joerg; Park, B.G.; Irvine, A.C.; Zarbo, Liviu; Rozkotová, E.; Němec, P.; Novák, Vít; Sinova, Jairo; Jungwirth, Tomáš
2010-01-01
Roč. 330, č. 6012 (2010), s. 1801-1804 ISSN 0036-8075 R&D Projects: GA AV ČR KAN400100652; GA MŠk LC510 EU Projects: European Commission(XE) 215368 - SemiSpinNet Grant - others:AV ČR(CZ) AP0801 Program:Akademická prémie - Praemium Academiae Institutional research plan: CEZ:AV0Z10100521 Keywords : spin Hall effect * spintronics * spin transistor Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 31.364, year: 2010
Energy Technology Data Exchange (ETDEWEB)
Luccio, A.U. [Brookhaven National Lab., Upton, NY (United States); Katayama, T. [Univ. of Tokyo (Japan); Wu, H. [Riken Inst., Tokyo (Japan)
1997-07-01
In the acceleration of polarized protons in RHIC many spin depolarizing resonances are encountered. Helical Siberian snakes will be used to overcome depolarizing effects. The behavior of polarization can be studied by numerical tracking in a model accelerator. That allows one to check the strength of the resonances, to study the effect of snakes, to find safe lattice tune regions, and finally to study the operation of special devices like spin flippers. In this paper the authors describe numerical spin tracking. Results show that, for the design corrected distorted orbit and the design beam emittance, the polarization of the beam will be preserved in the whole range of proton energies in RHIC.
SPINning parallel systems software
International Nuclear Information System (INIS)
Matlin, O.S.; Lusk, E.; McCune, W.
2002-01-01
We describe our experiences in using Spin to verify parts of the Multi Purpose Daemon (MPD) parallel process management system. MPD is a distributed collection of processes connected by Unix network sockets. MPD is dynamic processes and connections among them are created and destroyed as MPD is initialized, runs user processes, recovers from faults, and terminates. This dynamic nature is easily expressible in the Spin/Promela framework but poses performance and scalability challenges. We present here the results of expressing some of the parallel algorithms of MPD and executing both simulation and verification runs with Spin
High spin spectroscopy of 70Ge
International Nuclear Information System (INIS)
Kumar Raju, M.; Sugathan, P.; Seshi Reddy, T.; Thirumala Rao, B.V.; Madhusudhana Rao, P.V.; Muralithar, S.; Singh, R.P.; Bhowmik, R.K.
2011-01-01
Structure of nuclei in mass 70 region is of interest due to presence of a variety of complex phenomenon. In these nuclei rapid change of nuclear shape with proton and neutron numbers, spin and excitation energy. Valance nucleons in f-p-g shell configuration will drive the nuclei towards high deformations. Relatively large values of quadrupole deformation are evident in the even-even nuclei in this region. Present study is aimed to explore the high spin structure of the 70 Ge nucleus. A negative parity structure was reported in an earlier study
Spin squeezing and quantum correlations
Indian Academy of Sciences (India)
2 states. A coherent spin-s state. (CSS) θ φ can then be thought of as having no quantum correlations as the constituent. 2s elementary spins point in the same direction ˆn(θ φ) which is the mean spin direction. 2. State classification and squeezing. In order to discuss squeezing, we begin with the squeezing condition itself.
Geometry of spin coherent states
Chryssomalakos, C.; Guzmán-González, E.; Serrano-Ensástiga, E.
2018-04-01
Spin states of maximal projection along some direction in space are called (spin) coherent, and are, in many respects, the ‘most classical’ available. For any spin s, the spin coherent states form a 2-sphere in the projective Hilbert space \
Spin Hall effect and spin swapping in diffusive superconductors
Espedal, Camilla; Lange, Peter; Sadjina, Severin; Mal'shukov, A. G.; Brataas, Arne
2017-02-01
We consider the spin-orbit-induced spin Hall effect and spin swapping in diffusive superconductors. By employing the nonequilibrium Keldysh Green's function technique in the quasiclassical approximation, we derive coupled transport equations for the spectral spin and particle distributions and for the energy density in the elastic scattering regime. We compute four contributions to the spin Hall conductivity, namely, skew scattering, side jump, anomalous velocity, and the Yafet contribution. The reduced density of states in the superconductor causes a renormalization of the spin Hall angle. We demonstrate that all four of these contributions to the spin Hall conductivity are renormalized in the same way in the superconducting state. In its simplest manifestation, spin swapping transforms a primary spin current into a secondary spin current with swapped current and polarization directions. We find that the spin-swapping coefficient is not explicitly but only implicitly affected by the superconducting gap through the renormalized diffusion coefficients. We discuss experimental consequences for measurements of the (inverse) spin Hall effect and spin swapping in four-terminal geometries. In our geometry, below the superconducting transition temperature, the spin-swapping signal is increased an order of magnitude while changes in the (inverse) spin Hall signal are moderate.
CERN. Geneva
2014-01-01
The conjectured relation between higher spin theories on anti de-Sitter (AdS) spaces and weakly coupled conformal field theories is reviewed. I shall then outline the evidence in favour of a concrete duality of this kind, relating a specific higher spin theory on AdS3 to a family of 2d minimal model CFTs. Finally, I shall explain how this relation fits into the framework of the familiar stringy AdS/CFT correspondence.
Khatua, Subhankar; Shankar, R.; Ganesh, R.
2018-02-01
A fundamental motif in frustrated magnetism is the fully mutually coupled cluster of N spins, with each spin coupled to every other spin. Clusters with N =2 and 3 have been extensively studied as building blocks of square and triangular lattice antiferromagnets. In both cases, large-S semiclassical descriptions have been fruitfully constructed, providing insights into the physics of macroscopic magnetic systems. Here, we develop a semiclassical theory for the N =4 cluster. This problem has rich mathematical structure with a ground-state space that has nontrivial topology. We show that ground states are appropriately parametrized by a unit vector order parameter and a rotation matrix. Remarkably, in the low-energy description, the physics of the cluster reduces to that of an emergent free spin-S spin and a rigid rotor. This successfully explains the spectrum of the quadrumer and its associated degeneracies. However, this mapping does not hold in the vicinity of collinear ground states due to a subtle effect that arises from the nonmanifold nature of the ground-state space. We demonstrate this by an analysis of soft fluctuations, showing that collinear states have a larger number of soft modes. Nevertheless, as these singularities only occur on a subset of measure zero, the mapping to a spin and a rotor provides a good description of the quadrumer. We interpret thermodynamic properties of the quadrumer that are accessible in molecular magnets, in terms of the rotor and spin degrees of freedom. Our study paves the way for field theoretic descriptions of systems such as pyrochlore magnets.
Bird, Richard S.
Spider spinning is a snappy name for the problem of listing the ideals of a totally acyclic poset in such a way that each ideal is computed from its predecessor in constant time. Such an algorithm is said to be loopless. Our aim in these lectures is to show how to calculate a loopless algorithm for spider spinning. The calculation makes use of the fundamental laws of functional programming and the real purpose of the exercise is to show these laws in action.
Fleurov, V.; Ivanov, V. A.; Peeters, F. M.; Vagner, I. D.
2001-01-01
Spatially nonhomogeneously spin polarized nuclei are proposed as a new mechanism to monitor electron states in a nanostructure, or as a means to createn and, if necessary, reshape such nanostructures in the course of the experiment. We found that a polarization of nulear spins may lift the spin polarization of the electron states in a nanostructure and, if sufficiently strong, leads to a polarization of the electron spins. Polarized nuclear spins may form an energy landscape capable of bindin...
Chudnovsky, Eugene M.
2007-01-01
An extension of Drude model is proposed that accounts for spin and spin-orbit interaction of charge carriers. Spin currents appear due to combined action of the external electric field, crystal field and scattering of charge carriers. The expression for spin Hall conductivity is derived for metals and semiconductors that is independent of the scattering mechanism. In cubic metals, spin Hall conductivity $\\sigma_s$ and charge conductivity $\\sigma_c$ are related through $\\sigma_s = [2 \\pi \\hbar...
Designing organic spin filters in the coherent tunneling regime.
Herrmann, Carmen; Solomon, Gemma C; Ratner, Mark A
2011-06-14
Spin filters, that is, systems which preferentially transport electrons of a certain spin orientation, are an important element for spintronic schemes and in chemical and biological instances of spin-selective electronic communication. We study the relation between molecular structure and spin filtering functionality employing a theoretical analysis of both model and stable organic radicals based on substituted benzene, which are bound to gold electrodes, with a combination of density functional theory and the Landauer-Imry-Büttiker approach. We compare the spatial distribution of the spin density and of the frontier central subsystem molecular orbitals, and local contributions to the transmission. Our results suggest that the delocalization of the singly occupied molecular orbital and of the spin density onto the benzene ring connected to the electrodes, is a good, although not the sole indicator of spin filtering functionality. The stable radicals under study do not effectively act as spin filters, while the model phenoxy-based radicals are effective due to their much larger spin delocalization. These conclusions may also be of interest for electron transfer experiments in electron donor-bridge-acceptor complexes.
Spin-Current and Spin-Splitting in Helicoidal Molecules Due to Spin-Orbit Coupling
Caetano, R. A.
2016-03-01
The use of organic materials in spintronic devices has been seriously considered after recent experimental works have shown unexpected spin-dependent electrical properties. The basis for the confection of any spintronic device is ability of selecting the appropriated spin polarization. In this direction, DNA has been pointed out as a potential candidate for spin selection due to the spin-orbit coupling originating from the electric field generated by accumulated electrical charges along the helix. Here, we demonstrate that spin-orbit coupling is the minimum ingredient necessary to promote a spatial spin separation and the generation of spin-current. We show that the up and down spin components have different velocities that give rise to a spin-current. By using a simple situation where spin-orbit coupling is present, we provide qualitative justifications to our results that clearly point to helicoidal molecules as serious candidates to integrate spintronic devices.
Spin Torques in Systems with Spin Filtering and Spin Orbit Interaction
Ortiz Pauyac, Christian
2016-06-19
In the present thesis we introduce the reader to the ﬁeld of spintronics and explore new phenomena, such as spin transfer torques, spin ﬁltering, and three types of spin-orbit torques, Rashba, spin Hall, and spin swapping, which have emerged very recently and are promising candidates for a new generation of memory devices in computer technology. A general overview of these phenomena is presented in Chap. 1. In Chap. 2 we study spin transfer torques in tunnel junctions in the presence of spin ﬁltering. In Chap. 3 we discuss the Rashba torque in ferromagnetic ﬁlms, and in Chap. 4 we study spin Hall eﬀect and spin swapping in ferromagnetic ﬁlms, exploring the nature of spin-orbit torques based on these mechanisms. Conclusions and perspectives are summarized in Chap. 5.
Optical spin generation/detection and spin transport lifetimes
International Nuclear Information System (INIS)
Miah, M. Idrish
2011-01-01
We generate electron spins in semiconductors by optical pumping. The detection of them is also performed by optical technique using time-resolved pump-probe photoluminescence polarization measurements in the presence of an external magnetic field perpendicular to the generated spin. The spin polarization in dependences of the pulse length, pump-probe delay and external magnetic field is studied. From the dependence of spin-polarization on the delay of the probe, the electronic spin transport lifetimes and the spin relaxation frequencies as a function of the strength of the magnetic field are estimated. The results are discussed based on hyperfine effects for interacting electrons.
Optical spin generation/detection and spin transport lifetimes
Energy Technology Data Exchange (ETDEWEB)
Miah, M. Idrish, E-mail: m.miah@griffith.edu.au [Department of Physics, University of Chittagong, Chittagong 4331 (Bangladesh)
2011-02-25
We generate electron spins in semiconductors by optical pumping. The detection of them is also performed by optical technique using time-resolved pump-probe photoluminescence polarization measurements in the presence of an external magnetic field perpendicular to the generated spin. The spin polarization in dependences of the pulse length, pump-probe delay and external magnetic field is studied. From the dependence of spin-polarization on the delay of the probe, the electronic spin transport lifetimes and the spin relaxation frequencies as a function of the strength of the magnetic field are estimated. The results are discussed based on hyperfine effects for interacting electrons.
Grimme, Stefan; Bannwarth, Christoph; Dohm, Sebastian; Hansen, Andreas; Pisarek, Jana; Pracht, Philipp; Seibert, Jakob; Neese, Frank
2017-11-13
We present a composite procedure for the quantum-chemical computation of spin-spin-coupled 1 H NMR spectra for general, flexible molecules in solution that is based on four main steps, namely conformer/rotamer ensemble (CRE) generation by the fast tight-binding method GFN-xTB and a newly developed search algorithm, computation of the relative free energies and NMR parameters, and solving the spin Hamiltonian. In this way the NMR-specific nuclear permutation problem is solved, and the correct spin symmetries are obtained. Energies, shielding constants, and spin-spin couplings are computed at state-of-the-art DFT levels with continuum solvation. A few (in)organic and transition-metal complexes are presented, and very good, unprecedented agreement between the theoretical and experimental spectra was achieved. The approach is routinely applicable to systems with up to 100-150 atoms and may open new avenues for the detailed (conformational) structure elucidation of, for example, natural products or drug molecules. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
Thermoelectric spin voltage in graphene.
Sierra, Juan F; Neumann, Ingmar; Cuppens, Jo; Raes, Bart; Costache, Marius V; Valenzuela, Sergio O
2018-02-01
In recent years, new spin-dependent thermal effects have been discovered in ferromagnets, stimulating a growing interest in spin caloritronics, a field that exploits the interaction between spin and heat currents 1,2 . Amongst the most intriguing phenomena is the spin Seebeck effect 3-5 , in which a thermal gradient gives rise to spin currents that are detected through the inverse spin Hall effect 6-8 . Non-magnetic materials such as graphene are also relevant for spin caloritronics, thanks to efficient spin transport 9-11 , energy-dependent carrier mobility and unique density of states 12,13 . Here, we propose and demonstrate that a carrier thermal gradient in a graphene lateral spin valve can lead to a large increase of the spin voltage near to the graphene charge neutrality point. Such an increase results from a thermoelectric spin voltage, which is analogous to the voltage in a thermocouple and that can be enhanced by the presence of hot carriers generated by an applied current 14-17 . These results could prove crucial to drive graphene spintronic devices and, in particular, to sustain pure spin signals with thermal gradients and to tune the remote spin accumulation by varying the spin-injection bias.
Noise in tunneling spin current across coupled quantum spin chains
Aftergood, Joshua; Takei, So
2018-01-01
We theoretically study the spin current and its dc noise generated between two spin-1 /2 spin chains weakly coupled at a single site in the presence of an over-population of spin excitations and a temperature elevation in one subsystem relative to the other, and we compare the corresponding transport quantities across two weakly coupled magnetic insulators hosting magnons. In the spin chain scenario, we find that applying a temperature bias exclusively leads to a vanishing spin current and a concomitant divergence in the spin Fano factor, defined as the spin current noise-to-signal ratio. This divergence is shown to have an exact analogy to the physics of electron scattering between fractional quantum Hall edge states and not to arise in the magnon scenario. We also reveal a suppression in the spin current noise that exclusively arises in the spin chain scenario due to the fermion nature of the spin-1/2 operators. We discuss how the spin Fano factor may be extracted experimentally via the inverse spin Hall effect used extensively in spintronics.
Energy Technology Data Exchange (ETDEWEB)
Yokosawa, A.
1992-12-23
Spin physics activities at medium and high energies became significantly active when polarized targets and polarized beams became accessible for hadron-hadron scattering experiments. My overview of spin physics will be inclined to the study of strong interaction using facilities at Argonne ZGS, Brookhaven AGS (including RHIC), CERN, Fermilab, LAMPF, an SATURNE. In 1960 accelerator physicists had already been convinced that the ZGS could be unique in accelerating a polarized beam; polarized beams were being accelerated through linear accelerators elsewhere at that time. However, there was much concern about going ahead with the construction of a polarized beam because (i) the source intensity was not high enough to accelerate in the accelerator, (ii) the use of the accelerator would be limited to only polarized-beam physics, that is, proton-proton interaction, and (iii) p-p elastic scattering was not the most popular topic in high-energy physics. In fact, within spin physics, [pi]-nucleon physics looked attractive, since the determination of spin and parity of possible [pi]p resonances attracted much attention. To proceed we needed more data beside total cross sections and elastic differential cross sections; measurements of polarization and other parameters were urgently needed. Polarization measurements had traditionally been performed by analyzing the spin of recoil protons. The drawbacks of this technique are: (i) it involves double scattering, resulting in poor accuracy of the data, and (ii) a carbon analyzer can only be used for a limited region of energy.
Spin crossover in an elastic chain of exchange clusters beyond mean field approximation.
Morozov, Vitaly; Lukzen, Nikita; Ovcharenko, Victor
2010-11-07
Exact analysis of spin crossover in infinite elastic chain of two-spin exchange clusters was performed theoretically beyond mean-field approximation. Statistical mechanics of the system was exactly calculated by means of the transfer matrix technique. A possibility of spin-Peierls-like magneto-structural transition in a one-dimensional chain was shown as a result of interrelation of spin and elastic subsystems of the chain. The importance of the boundary conditions for spin crossover to occur was shown. The smoothness of spin crossover depends on the parameters of chain elasticity and the crossover position on the temperature scale is defined by the dependence of exchange integral on the cluster deformation. The proposed model qualitatively describes the main scenario of spin crossover effect in the chain polymer heterospin complex of copper(ii) hexafluoroacetylacetonate with methyl pyrazol-substituted nitronyl nitroxide containing two-spin exchange clusters.
Quantum spin transistor with a Heisenberg spin chain
Marchukov, O. V.; Volosniev, A. G.; Valiente, M.; Petrosyan, D.; Zinner, N. T.
2016-01-01
Spin chains are paradigmatic systems for the studies of quantum phases and phase transitions, and for quantum information applications, including quantum computation and short-distance quantum communication. Here we propose and analyse a scheme for conditional state transfer in a Heisenberg XXZ spin chain which realizes a quantum spin transistor. In our scheme, the absence or presence of a control spin excitation in the central gate part of the spin chain results in either perfect transfer of an arbitrary state of a target spin between the weakly coupled input and output ports, or its complete blockade at the input port. We also discuss a possible proof-of-concept realization of the corresponding spin chain with a one-dimensional ensemble of cold atoms with strong contact interactions. Our scheme is generally applicable to various implementations of tunable spin chains, and it paves the way for the realization of integrated quantum logic elements. PMID:27721438
Miller, Jan D; Hupka, Jan; Aranowski, Robert
2012-11-20
A spinning fluids reactor, includes a reactor body (24) having a circular cross-section and a fluid contactor screen (26) within the reactor body (24). The fluid contactor screen (26) having a plurality of apertures and a circular cross-section concentric with the reactor body (24) for a length thus forming an inner volume (28) bound by the fluid contactor screen (26) and an outer volume (30) bound by the reactor body (24) and the fluid contactor screen (26). A primary inlet (20) can be operatively connected to the reactor body (24) and can be configured to produce flow-through first spinning flow of a first fluid within the inner volume (28). A secondary inlet (22) can similarly be operatively connected to the reactor body (24) and can be configured to produce a second flow of a second fluid within the outer volume (30) which is optionally spinning.
Spin gating electrical current
Ciccarelli, C.; Zârbo, L. P.; Irvine, A. C.; Campion, R. P.; Gallagher, B. L.; Wunderlich, J.; Jungwirth, T.; Ferguson, A. J.
2012-09-01
The level of the chemical potential is a fundamental parameter of the electronic structure of a physical system, which consequently plays an important role in defining the properties of active electrical devices. We directly measure the chemical potential shift in the relativistic band structure of the ferromagnetic semiconductor (Ga,Mn)As, controlled by changes in its magnetic order parameter. Our device comprises a non-magnetic aluminum single electron channel capacitively coupled to the (Ga,Mn)As gate electrode. The chemical potential shifts of the gate are directly read out from the shifts in the Coulomb blockade oscillations of the single electron transistor. The experiments introduce a concept of spin gating electrical current. In our spin transistor spin manipulation is completely removed from the electrical current carrying channel.
Rackham, Neil
1995-01-01
True or false? In selling high-value products or services: "closing" increases your chance of success; it is essential to describe the benefits of your product or service to the customer; objection handling is an important skill; and open questions are more effective than closed questions. All false, says Neil Rackham. He and his team studied more than 35,000 sales calls made by 10,000 sales people in 23 countries over 12 years. Their findings revealed that many of the methods developed for selling low-value goods just don't work for major sales. Rackham went on to introduce his SPIN-selling method, where SPIN describes the whole selling process - Situation questions, Problem questions, Implication questions, Need-payoff questions. SPIN-selling provides you with a set of simple and practical techniques which have been tried in many of today's leading companies with dramatic improvements to their sales performance.
Krishnan, Chethan; Raju, Avinash
2017-06-01
We construct a candidate for the most general chiral higher spin theory with AdS3 boundary conditions. In the Chern-Simons language, on the left it has the Drinfeld-Sokolov reduced form, but on the right all charges and chemical potentials are turned on. Altogether (for the spin-3 case) these are 19 functions. Despite this, we show that the resulting metric has the form of the "most general" AdS3 boundary conditions discussed by Grumiller and Riegler. The asymptotic symmetry algebra is a product of a W3 algebra on the left and an affine s l (3 )k current algebra on the right, as desired. The metric and higher spin fields depend on all the 19 functions. We compare our work with previous results in the literature.
DEFF Research Database (Denmark)
Jensen, J.; Houmann, Jens Christian Gylden
1975-01-01
The selection rules for the linear couplings between magnons and phonons propagating in the c direction of a simple basal-plane hcp ferromagnet are determined by general symmetry considerations. The acoustic-optical magnon-phonon interactions observed in the heavy-rare-earth metals have been...... explained by Liu as originating from the mixing of the spin states of the conduction electrons due to the spin-orbit coupling. We find that this coupling mechanism introduces interactions which violate the selection rules for a simple ferromagnet. The interactions between the magnons and phonons propagating...... in the c direction of Tb have been studied experimentally by means of inelastic neutron scattering. The magnons are coupled to both the acoustic- and optical-transverse phonons. By studying the behavior of the acoustic-optical coupling, we conclude that it is a spin-mixed-induced coupling as proposed...
Spin flexoelectricity and chiral spin structures in magnetic films
Pyatakov, A. P.; Sergeev, A. S.; Mikailzade, F. A.; Zvezdin, A. K.
2015-01-01
In this short review a broad range of chiral phenomena observed in magnetic films (spin cycloid and skyrmion structures formation as well as chirality dependent domain wall motion) is considered under the perspective of spin flexoelectricity, i.e. the relation between bending of magnetization pattern and electric polarization. The similarity and the difference between the spin flexoelectricity and the newly emerged notion of spin flexomagnetism is discussed. The phenomenological arguments bas...
Kimura, Akifumi; Ishida, Takayuki
2018-01-01
Spin-crossover (SCO) is a reversible transition between low-spin (LS) and high-spin (HS) states by external stimuli like heat. The SCO behavior of [Fe(Ar-pybox)2](ClO4)2 was investigated, where Ar-pybox stands for 4-aryl-2,6-bis(oxazolin-2-yl)pyridine with Ar = 4-pyridyl (4Py), 3-thienyl (3Th), and phenyl (Ph). They were characterized by means of single-crystal X-ray diffraction study, being consistent with the results of the magnetic measurements. The SCO temperatures (T1/2) in the polycrystalline state were determined to be 360 and 230 K for Ar = 4Py and Ph, respectively. The 3Th derivative possessed a HS state in all the temperature range. The solution susceptometry was also performed to purge intermolecular interaction and rigid crystal lattice effects, affording T1/2 = 310, 240, and 240 K for Ar = 4Py, 3Th, and Ph, respectively, in acetone. The substituent effect analysis using the Hammett substituent constant (σp) clarified that electron-withdrawing groups raise T1/2. A plausible model describing the substituent effect on T1/2 is proposed based on d-π interaction. The present result is regarded as a successful example of crystal field engineering.
Spinning geodesic Witten diagrams
International Nuclear Information System (INIS)
Dyer, Ethan; Freedman, Daniel Z.; Massachusetts Institute of Technology; Massachusetts Institute of Technology; Sully, James; McGill University, Montreal, QC
2017-01-01
We present an expression for the four-point conformal blocks of symmetric traceless operators of arbitrary spin as an integral over a pair of geodesics in Anti-de Sitter space, generalizing the geodesic Witten diagram formalism of Hijano et al. to arbitrary spin. As an intermediate step in the derivation, we identify a convenient basis of bulk threepoint interaction vertices which give rise to all possible boundary three point structures. Lastly, we highlight a direct connection between the representation of the conformal block as geodesic Witten diagram and the shadow operator formalism.
Spin gating electrical current
Czech Academy of Sciences Publication Activity Database
Ciccarelli, C.; Zarbo, Liviu; Irvine, A.C.; Campion, R. P.; Gallagher, B. L.; Wunderlich, Joerg; Jungwirth, Tomáš; Ferguson, A.J.
2012-01-01
Roč. 101, č. 12 (2012), , , "122411-1"-"122411-4" ISSN 0003-6951 R&D Projects: GA AV ČR KJB100100802; GA AV ČR KAN400100652 EU Projects: European Commission(XE) 268066 - 0MSPIN; European Commission(XE) 215368 - SemiSpinNet Grant - others:AV ČR(CZ) AP0801 Program:Akademická prémie - Praemium Academiae Institutional research plan: CEZ:AV0Z10100521 Keywords : ferromagnetic resonance * spin-orbit coupling * nanodevices Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.794, year: 2012 http://arxiv.org/abs/1203.2439
Directory of Open Access Journals (Sweden)
Alexander W. Chao
2007-01-01
Full Text Available As a polarized beam is accelerated through a depolarization resonance, its polarization is reduced by a well-defined calculable reduction factor. When the beam subsequently crosses a second resonance, the final beam polarization is considered to be reduced by the product of the two reduction factors corresponding to the two crossings, each calculated independently of the other. This is a good approximation when the spread of spin precession frequency Δν_{spin} of the beam (particularly due to its energy spread is sufficiently large that the spin precession phases of individual particles smear out completely during the time τ between the two crossings. This approximate picture, however, ignores two spin dynamics effects: an interference-overlap effect and a spin echo effect. This paper is to address these two effects. The interference-overlap effect occurs when Δν_{spin} is too small, or when τ is too short, to complete the smearing process. In this case, the two resonance crossings overlap each other, and the final polarization exhibits constructive or destructive interference patterns depending on the exact value of τ. Typically, the beam’s energy spread is large and this interference-overlap effect does not occur. To study this effect, therefore, it is necessary to reduce the beam energy spread and to consider two resonance crossings very close to each other. The other mechanism, also due to the interplay between two resonance crossings, is spin echo. It turns out that even when the precession phases appear to be completely smeared between the two crossings, there will still be a sudden and short-lived echo signal of beam polarization at a time τ after the second crossing; the magnitude of which can be as large as 57%. This echo signal exists even when the beam has a sizable energy spread and when τ is very large, and could be a sensitive (albeit challenging way to experimentally test the intricate spin dynamics in a synchrotron
Obukhov, Y N
2001-01-08
The gravitational effects in the relativistic quantum mechanics are investigated. The exact Foldy-Wouthuysen transformation is constructed for the Dirac particle coupled to the static spacetime metric. As a direct application, we analyze the nonrelativistic limit of the theory. The new term describing the specific spin (gravitational moment) interaction effect is recovered in the Hamiltonian. The comparison of the true gravitational coupling with the purely inertial case demonstrates that the spin relativistic effects do not violate the equivalence principle for the Dirac fermions.
Investigation of non-collinear spin states with scanning tunneling microscopy.
Wulfhekel, W; Gao, C L
2010-03-05
Most ferromagnetic and antiferromagnetic substances show a simple collinear arrangement of the local spins. Under certain circumstances, however, the spin configuration is non-collinear. Scanning tunneling microscopy with its potential atomic resolution is an ideal tool for investigating these complex spin structures. Non-collinearity can be due to topological frustration of the exchange interaction, due to relativistic spin-orbit coupling or can be found in excited states. Examples for all three cases are given, illustrating the capabilities of spin-polarized scanning tunneling microscopy.
International Nuclear Information System (INIS)
Faris, W.G.
1981-01-01
Dankel has shown how to incorporate spin into stochastic mechanics. The resulting non-local hidden variable theory gives an appealing picture of spin correlation experiments in which Bell's inequality is violated. (orig.)
International Nuclear Information System (INIS)
Westlund, P.O.
1994-01-01
Specific mechanisms of relaxation encountered in paramagnetic systems are described: the T1-NMRD curve and the paramagnetically enhanced nuclear spin relaxation (PER) are first discussed and a general theory of PER is proposed (nuclear paramagnetic spin relaxation theory, lattice operators, decomposition approximation, general expression of dipolar correlation functions for slow tumbling complexes, low-field approach). Numerically calculated NMRD curves are described (reorientation model, pseudo-rotation models, vibration models). Experimental studies are then analyzed: NMRD studies of paramagnetic species in an aqueous system, paramagnetic hydrated metal ions in poly-electrolytes and biochemical systems, lyotropic liquid crystalline phases, polymer solutions. 19 fig., 60 ref
Computational approach to the study of thermal spin crossover phenomena
International Nuclear Information System (INIS)
Rudavskyi, Andrii; Broer, Ria; Sousa, Carmen; Graaf, Coen de; Havenith, Remco W. A.
2014-01-01
The key parameters associated to the thermally induced spin crossover process have been calculated for a series of Fe(II) complexes with mono-, bi-, and tridentate ligands. Combination of density functional theory calculations for the geometries and for normal vibrational modes, and highly correlated wave function methods for the energies, allows us to accurately compute the entropy variation associated to the spin transition and the zero-point corrected energy difference between the low- and high-spin states. From these values, the transition temperature, T 1/2 , is estimated for different compounds
Spin wave propagation in a uniformly biased curved magnonic waveguide
Sadovnikov, A. V.; Davies, C. S.; Kruglyak, V. V.; Romanenko, D. V.; Grishin, S. V.; Beginin, E. N.; Sharaevskii, Y. P.; Nikitov, S. A.
2017-08-01
Using Brillouin light scattering microscopy and micromagnetic simulations, we study the propagation and transformation of magnetostatic spin waves across uniformly biased curved magnonic waveguides. Our results demonstrate that the spin wave transmission through the bend can be enhanced or weakened by modifying the distribution of the inhomogeneous internal magnetic field spanning the structure. Our results open up the possibility of optimally molding the flow of spin waves across networks of magnonic waveguides, thereby representing a step forward in the design and construction of the more complex magnonic circuitry.
Antiferromagnetic spin-orbitronics
Manchon, Aurelien
2015-05-01
Antiferromagnets have long remained an intriguing and exotic state of matter, whose application has been restricted to enabling interfacial exchange bias in metallic and tunneling spin-valves [1]. Their role in the expanding field of applied spintronics has been mostly passive and the in-depth investigation of their basic properties mostly considered from a fundamental perspective.
Indian Academy of Sciences (India)
Home; Journals; Resonance – Journal of Science Education; Volume 3; Issue 11. The Story of Spin - From Spectroscopy to Relativistic Quantum Mechanics. N Mukunda. Book Review Volume 3 Issue 11 November 1998 pp 89-90. Fulltext. Click here to view fulltext PDF. Permanent link:
International Nuclear Information System (INIS)
Suzuki, T.; Sagawa, H.
2000-01-01
Complete text of publication follows. Spin and isospin modes in nuclei are investigated. We discuss some of the following topics. 1. Spin-dipole excitations in 12 C and 16 O are studied (1). Effects of tensor and spin-orbit interactions on the distribution of the strengths are investigated, and neutral current neutrino scattering cross sections in 16 O are obtained for heavy-flavor neutrinos from the supernovae. 2. Gamow-Teller (GT) and spin-dipole (SD) modes in 208 Bi are investigated. Quenching and fragmentation of the GT strength are discussed (2). SD excitations and electric dipole (E1) transitions between the GT and SD states are studied (3). Calculated E1 strengths are compared with the sum rule values obtained within the 1p-1h and 1p-1h + 2p-2h configuration spaces. 3. Coulomb displacement energy (CDE) of the IAS of 14 Be is calculated, and the effects of the halo on the CDE and the configuration of the halo state are investigated. 4. Spreading width of IAS and isospin dependence of the width are investigated (4). Our formula for the width explains very well the observed isospin dependence (5). (author)
Bergshoeff, E.; Sezgin, E.; Townsend, P.K.
1988-01-01
Several alternative actions for a bosonic membrane have recently been proposed. We show that a linearly realized locally world-volume-supersymmetric (spinning membrane) extension of any of these actions implies an analogous extension of the standard Dirac membrane action. We further show that a
International Nuclear Information System (INIS)
1981-11-01
This booklet gives examples of 'nuclear spin off', from research programmes carried out for the UKAEA, under the following headings; non destructive testing; tribology; environmental protection; flow measurement; material sciences; mechanical engineering; marine services; biochemical technology; electronic instrumentation. (U.K.)
International Nuclear Information System (INIS)
Bramson, B.D.
1978-01-01
An isolated system in general relativity makes a transition between stationary states. It is shown that the spin vectors of the system, long before and long after the emission of radiation, are supertranslation invariant and, hence, independent of the choice of Minkowski observation space. (author)
Spin Injection in Indium Arsenide
Directory of Open Access Journals (Sweden)
Mark eJohnson
2015-08-01
Full Text Available In a two dimensional electron system (2DES, coherent spin precession of a ballistic spin polarized current, controlled by the Rashba spin orbit interaction, is a remarkable phenomenon that’s been observed only recently. Datta and Das predicted this precession would manifest as an oscillation in the source-drain conductance of the channel in a spin-injected field effect transistor (Spin FET. The indium arsenide single quantum well materials system has proven to be ideal for experimental confirmation. The 2DES carriers have high mobility, low sheet resistance, and high spin orbit interaction. Techniques for electrical injection and detection of spin polarized carriers were developed over the last two decades. Adapting the proposed Spin FET to the Johnson-Silsbee nonlocal geometry was a key to the first experimental demonstration of gate voltage controlled coherent spin precession. More recently, a new technique measured the oscillation as a function of channel length. This article gives an overview of the experimental phenomenology of the spin injection technique. We then review details of the application of the technique to InAs single quantum well (SQW devices. The effective magnetic field associated with Rashba spin-orbit coupling is described, and a heuristic model of coherent spin precession is presented. The two successful empirical demonstrations of the Datta Das conductance oscillation are then described and discussed.
Spin tunnelling in mesoscopic systems
Indian Academy of Sciences (India)
Spin tunnelling; spin path integrals; discrete phase integral method; diabolical points. ... technologies. Our purpose in this article is rather different. The molecular systems have total spin of the order of 10, and magnetocrystalline anisotropies of few tens of Kelvin ...... The point С' is of this new type, and here it may be said to.
Spin transport in graphene nanostructures
Guimaraes, M. H. D.; van den Berg, J. J.; Vera-Marun, I. J.; Zomer, P. J.; van Wees, B. J.
2014-01-01
Graphene is an interesting material for spintronics, showing long spin relaxation lengths even at room temperature. For future spintronic devices it is important to understand the behavior of the spins and the limitations for spin transport in structures where the dimensions are smaller than the
van Driel, H.J.
2012-01-01
In this Thesis, we show that in a rotating two-component Bose mixture, the spin drag between the two different spin species shows a Hall effect. This spin drag Hall effect can be observed experimentally by studying the out-of-phase dipole mode of the mixture. We determine the damping of this mode
Spin Transport in Semiconductor heterostructures
International Nuclear Information System (INIS)
Marinescu, Domnita Catalina
2011-01-01
The focus of the research performed under this grant has been the investigation of spin transport in magnetic semiconductor heterostructures. The interest in these systems is motivated both by their intriguing physical properties, as the physical embodiment of a spin-polarized Fermi liquid, as well as by their potential applications as spintronics devices. In our work we have analyzed several different problems that affect the spin dynamics in single and bi-layer spin-polarized two-dimensional (2D) systems. The topics of interests ranged from the fundamental aspects of the electron-electron interactions, to collective spin and charge density excitations and spin transport in the presence of the spin-orbit coupling. The common denominator of these subjects is the impact at the macroscopic scale of the spin-dependent electron-electron interaction, which plays a much more subtle role than in unpolarized electron systems. Our calculations of several measurable parameters, such as the excitation frequencies of magneto-plasma modes, the spin mass, and the spin transresistivity, propose realistic theoretical estimates of the opposite-spin many-body effects, in particular opposite-spin correlations, that can be directly connected with experimental measurements.
Spinning Them Off: Entrepreneuring Practices in Corporate Spin-Offs
Directory of Open Access Journals (Sweden)
Katja Maria Hydle
2016-01-01
Full Text Available This paper focuses on the practices between parent and child firms in corporate spinoffs. We uncover the enacted aspects of knowledge, called knowing, through theories from seven cases of incumbent-backed spin-offs and find that the management of the parent firms are highly involved in the spin-offs. The practices associated with spinning off are solving problems, involving multidisciplinary expertise and entrepreneuring management at the parent firm. We contribute to the spin-off literature by discussing the knowledge required for successfully spinning off child firms and to practice theory by empirically uncovering the practical understanding involved in the origin and perpetuation of an organization.
Spin flexoelectricity and chiral spin structures in magnetic films
Pyatakov, A. P.; Sergeev, A. S.; Mikailzade, F. A.; Zvezdin, A. K.
2015-06-01
In this short review a broad range of chiral phenomena observed in magnetic films (spin cycloid and skyrmion structures formation as well as chirality dependent domain wall motion) is considered under the perspective of spin flexoelectricity, i.e. the relation between bending of magnetization pattern and electric polarization. The similarity and the difference between the spin flexoelectricity and the newly emerged notion of spin flexomagnetism are discussed. The phenomenological arguments based on the geometrical idea of curvature-induced effects are supported by analysis of the microscopic mechanisms of spin flexoelectricity based on three-site ion indirect exchange and twisted RKKY interaction models.
Excitation of coherent propagating spin waves by pure spin currents.
Demidov, Vladislav E; Urazhdin, Sergei; Liu, Ronghua; Divinskiy, Boris; Telegin, Andrey; Demokritov, Sergej O
2016-01-28
Utilization of pure spin currents not accompanied by the flow of electrical charge provides unprecedented opportunities for the emerging technologies based on the electron's spin degree of freedom, such as spintronics and magnonics. It was recently shown that pure spin currents can be used to excite coherent magnetization dynamics in magnetic nanostructures. However, because of the intrinsic nonlinear self-localization effects, magnetic auto-oscillations in the demonstrated devices were spatially confined, preventing their applications as sources of propagating spin waves in magnonic circuits using these waves as signal carriers. Here, we experimentally demonstrate efficient excitation and directional propagation of coherent spin waves generated by pure spin current. We show that this can be achieved by using the nonlocal spin injection mechanism, which enables flexible design of magnetic nanosystems and allows one to efficiently control their dynamic characteristics.
Spin-wave-induced spin torque in Rashba ferromagnets
Umetsu, Nobuyuki; Miura, Daisuke; Sakuma, Akimasa
2015-05-01
We study the effects of Rashba spin-orbit coupling on the spin torque induced by spin waves, which are the plane-wave dynamics of magnetization. The spin torque is derived from linear-response theory, and we calculate the dynamic spin torque by considering the impurity-ladder-sum vertex corrections. This dynamic spin torque is divided into three terms: a damping term, a distortion term, and a correction term for the equation of motion. The distorting torque describes a phenomenon unique to the Rashba spin-orbit coupling system, where the distorted motion of magnetization precession is subjected to the anisotropic force from the Rashba coupling. The oscillation mode of the precession exhibits an elliptical trajectory, and the ellipticity depends on the strength of the nesting effects, which could be reduced by decreasing the electron lifetime.
Yang, Yumeng; Xu, Yanjun; Xie, Hang; Xu, Baoxi; Wu, Yihong
2017-07-01
We demonstrate an ultrathin and semitransparent anisotropic and spin Hall magnetoresistance sensor based on NiFe/Pt heterostructures. The use of a spin-orbit torque effective field for transverse biasing allows us to reduce the total thickness of the sensors down to 3-4 nm, thereby leading to the semitransparency. Despite the extremely simple design, the spin-orbit torque effective field biased NiFe/Pt sensor exhibits levels of linearity and sensitivity comparable to those of sensors using more complex linearization schemes. In a proof-of-concept design using a full Wheatstone bridge comprising four sensing elements, we obtained a sensitivity up to 202.9 mΩ Oe-1, a linearity error below 5%, and a detection limit down to 20 nT. The transmittance of the sensor is over 50% in the visible range.
Spin Structures in Magnetic Nanoparticles
DEFF Research Database (Denmark)
Mørup, Steen; Brok, Erik; Frandsen, Cathrine
2013-01-01
Spin structures in nanoparticles of ferrimagnetic materials may deviate locally in a nontrivial way from ideal collinear spin structures. For instance, magnetic frustration due to the reduced numbers of magnetic neighbors at the particle surface or around defects in the interior can lead to spin...... canting and hence a reduced magnetization. Moreover, relaxation between almost degenerate canted spin states can lead to anomalous temperature dependences of the magnetization at low temperatures. In ensembles of nanoparticles, interparticle exchange interactions can also result in spin reorientation...
Magnetic Hamiltonian and phase diagram of the quantum spin liquid Ca10Cr7O28
Balz, Christian; Lake, Bella; Nazmul Islam, A. T. M.; Singh, Yogesh; Rodriguez-Rivera, Jose A.; Guidi, Tatiana; Wheeler, Elisa M.; Simeoni, Giovanna G.; Ryll, Hanjo
2017-05-01
A spin liquid is a new state of matter with topological order where the spin moments continue to fluctuate coherently down to the lowest temperatures rather than develop static long-range magnetic order as found in conventional magnets. For spin liquid behavior to arise in a material the magnetic Hamiltonian must be "frustrated", where the combination of lattice geometry, interactions, and anisotropies gives rise to competing spin arrangements in the ground state. Theoretical Hamiltonians which produce spin liquids are spin ice, the Kitaev honeycomb model, and the kagome antiferromagnet. Spin liquid behavior, however, in real materials is rare because they can only approximate these Hamiltonians and often have weak higher-order terms that destroy the spin liquid state. Ca10Cr7O28 is a new quantum spin liquid candidate with magnetic Cr5 + ions that possess quantum spin number S =½ . The spins are entirely dynamic in the ground state and the excitation spectrum is broad and diffuse, as is typical of spinons which are the excitations of a spin liquid. In this paper we determine the Hamiltonian of Ca10Cr7O28 using inelastic neutron scattering under high magnetic field to induce a field-polarized paramagnetic ground state and spin-wave excitations that can be fitted to extract the interactions. We further explore the phase diagram by using inelastic neutron scattering and heat capacity measurements and establish the boundaries of the spin liquid phase as a function of magnetic field and temperature. Our results show that Ca10Cr7O28 consists of distorted kagome bilayers with several isotropic ferromagnetic and antiferromagnetic interactions where, unexpectedly, the ferromagnetic interactions are stronger than the antiferromagnetic ones. This complex Hamiltonian does not correspond to any known spin liquid model and points to new directions in the search for quantum spin liquid behavior.
Rinaldi, C.; Bertoli, S.; Asa, M.; Baldrati, L.; Manzoni, C.; Marangoni, M.; Cerullo, G.; Bianchi, M.; Sordan, R.; Bertacco, R.; Cantoni, M.
2016-10-01
The measurement of the spin diffusion length and/or lifetime in semiconductors is a key issue for the realisation of spintronic devices, exploiting the spin degree of freedom of carriers for storing and manipulating information. In this paper, we address such parameters in germanium (0 0 1) at room temperature (RT) by three different measurement methods. Exploiting optical spin orientation in the semiconductor and spin filtering across an insulating MgO barrier, the dependence of the resistivity on the spin of photo-excited carriers in Fe/MgO/Ge spin photodiodes (spin-PDs) was electrically detected. A spin diffusion length of 0.9 ± 0.2 µm was obtained by fitting the photon energy dependence of the spin signal by a mathematical model. Electrical techniques, comprising non-local four-terminal and Hanle measurements performed on CoFeB/MgO/Ge lateral devices, led to spin diffusion lengths of 1.3 ± 0.2 µm and 1.3 ± 0.08 µm, respectively. Despite minor differences due to experimental details, the order of magnitude of the spin diffusion length is the same for the three techniques. Although standard electrical methods are the most employed in semiconductor spintronics for spin diffusion length measurements, here we demonstrate optical spin orientation as a viable alternative for the determination of the spin diffusion length in semiconductors allowing for optical spin orientation.
Spin diffusion length of Permalloy using spin absorption in lateral spin valves
Sagasta, Edurne; Omori, Yasutomo; Isasa, Miren; Otani, YoshiChika; Hueso, Luis E.; Casanova, Fèlix
2017-08-01
We employ the spin absorption technique in lateral spin valves to extract the spin diffusion length of Permalloy (Py) as a function of temperature and resistivity. A linear dependence of the spin diffusion length with the conductivity of Py is observed, evidencing that the Elliott-Yafet mechanism is the dominant spin relaxation mechanism in Permalloy. Completing the dataset with additional data found in the literature, we obtain λPy = (0.91 ± 0.04) (fΩm2)/ρPy.
Russ, Maximilian; Burkard, Guido
2017-10-01
-only qubits which can be divided into short-ranged and long-ranged interactions. Both of these interaction types are expected to be necessary in a large-scale quantum computer. The short-ranged interactions use the exchange coupling by placing qubits next to each other and applying exchange-pulses (DiVincenzo et al 2000 Nature 408 339, Fong and Wandzura 2011 Quantum Inf. Comput. 11 1003, Setiawan et al 2014 Phys. Rev. B 89 085314, Zeuch et al 2014 Phys. Rev. B 90 045306, Doherty and Wardrop 2013 Phys. Rev. Lett. 111 050503, Shim and Tahan 2016 Phys. Rev. B 93 121410), while the long-ranged interactions use the photons of a superconducting microwave cavity as a mediator in order to couple two qubits over long distances (Russ and Burkard 2015 Phys. Rev. B 92 205412, Srinivasa et al 2016 Phys. Rev. B 94 205421). The nature of the three-electron qubit states each having the same total spin and total spin in z-direction (same Zeeman energy) provides a natural protection against several sources of noise (DiVincenzo et al 2000 Nature 408 339, Taylor et al 2013 Phys. Rev. Lett. 111 050502, Kempe et al 2001 Phys. Rev. A 63 042307, Russ and Burkard 2015 Phys. Rev. B 91 235411). The price to pay for this advantage is an increase in gate complexity. We also take into account the decoherence of the qubit through the influence of magnetic noise (Ladd 2012 Phys. Rev. B 86 125408, Mehl and DiVincenzo 2013 Phys. Rev. B 87 195309, Hung et al 2014 Phys. Rev. B 90 045308), in particular dephasing due to the presence of nuclear spins, as well as dephasing due to charge noise (Medford et al 2013 Phys. Rev. Lett. 111 050501, Taylor et al 2013 Phys. Rev. Lett. 111 050502, Shim and Tahan 2016 Phys. Rev. B 93 121410, Russ and Burkard 2015 Phys. Rev. B 91 235411, Fei et al 2015 Phys. Rev. B 91 205434), fluctuations of the energy levels on each dot due to noisy gate voltages or the environment. Several techniques are discussed which partly decouple the qubit from magnetic noise (Setiawan et al 2014 Phys
1984-01-01
The bulk of the muon spin rotation research work centered around the development of the muon spin rotation facility at the Alternating Gradient Synchrotron (AGS) of Brookhaven National Laboratory (BNL). The collimation system was both designed and fabricated at Virginia State University. This improved collimation system, plus improvements in detectors and electronics enabled the acquisition of spectra free of background out to 15 microseconds. There were two runs at Brookhaven in 1984, one run was devoted primarily to beam development and the other run allowed several successful experiments to be performed. The effect of uniaxial strain on an Fe(Si) crystal at elevated temperature (360K) was measured and the results are incorporated herein. A complete analysis of Fe pulling data taken earlier is included.
International Nuclear Information System (INIS)
Salesi, G.
1995-07-01
Starting from the Pauli current the decomposition of the non-relativistic local velocity has been obtained in two parts (in the ordinary tensorial language): one parallel and the other orthogonal to the impulse. The former is recognized to be the classical part, that is, the center-of-mass (CM) velocity, and the latter the quantum one, that is, the velocity of the motion in the CM frame (namely, the internal spin motion or Zitterbewegung). Inserting this complete, composite expression of the velocity into the kinetic energy term of the classical non-relativistic (i.e. Newtonian) Lagrangian, the author straightforwardly get the appearance of the so called quantum potential associates as it is known, to the Madelung fluid. In such a way, the quantum mechanical behaviour of particles appears to be strictly correlated to the existence of spin and Zitterbewegung
Spin Chain in Magnetic Field: Limitations of the Large-N Mean-Field Theory
Energy Technology Data Exchange (ETDEWEB)
Wohlfeld, K. [Stanford Institute for Materials and Energy Sciences, SLAC National Laboratory and Stanford University, Menlo Park, California 94025, USA; Institute of Theoretical Physics, Faculty of Physics, University of Warsaw, Pasteura 5, PL-02093 Warszawa, Poland; Chen, Cheng-Chien [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA; van Veenendaal, M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA; Department of Physics, Northern Illinois University, De Kalb, Illinois 60115, USA; Devereaux, T. P. [Stanford Institute for Materials and Energy Sciences, SLAC National Laboratory and Stanford University, Menlo Park, California 94025, USA
2015-02-01
Motivated by the recent success in describing the spin and orbital spectrum of a spin-orbital chain using a large-N mean-field approximation, we apply the same formalism to the case of a spin chain in the external magnetic field. It occurs that in this case, which corresponds to N = 2 in the approximation, the large-N mean-field theory cannot qualitatively reproduce the spin excitation spectra at high magnetic fields, which polarize more than 50% of the spins in the magnetic ground state. This, rather counterintuitively, shows that the physics of a spin chain can under some circumstances be regarded as more complex than the physics of a spin-orbital chain.
Gentili, Denis; Liscio, Fabiola; Demitri, Nicola; Schäfer, Bernhard; Borgatti, Francesco; Torelli, Piero; Gobaut, Benoit; Panaccione, Giancarlo; Rossi, Giorgio; Degli Esposti, Alessandra; Gazzano, Massimo; Milita, Silvia; Bergenti, Ilaria; Ruani, Giampiero; Šalitroš, Ivan; Ruben, Mario; Cavallini, Massimiliano
2016-01-07
We investigated the influence of surfaces in the formation of different crystal structures of a spin crossover compound, namely [Fe(L)2] (LH: (2-(pyrazol-1-yl)-6-(1H-tetrazol-5-yl)pyridine), which is a neutral compound thermally switchable around room temperature. We observed that the surface induces the formation of two different crystal structures, which exhibit opposite spin transitions, i.e. on heating them up to the transition temperature, one polymorph switches from high spin to low spin and the second polymorph switches irreversibly from low spin to high spin. We attributed this inversion to the presence of water molecules H-bonded to the complex tetrazolyl moieties in the crystals. Thin deposits were investigated by means of polarized optical microscopy, atomic force microscopy, X-ray diffraction, X-ray absorption spectroscopy and micro Raman spectroscopy; moreover the analysis of the Raman spectra and the interpretation of spin inversion were supported by DFT calculations.
McDowell, M.
2002-12-01
Looking at lopsided Pangaea, shown imaginatively on many illustrated proposals, I wondered what would happen if the configuration were put in high relief on a globe and spun on axis. Then I wondered if the present configuration of land masses would itself balance as a spinning top. So I got two Replogle globes, two boxes of colored modeling clay sticks, and two fat knitting needles, to fit through the capped holes at the poles of the globes. The clay sticks I cut up into 3 mm. (1/8") slices, using a different color for each continent, and applied to the first globe, assuming the extreme exaggeration above the geoid, no matter how crude, would tell the story. Inserting one needle through the globe and securing it, I balanced the globe on the point of the needle and twirled it like a top. Result: Wobbly! Top end of needle gyrated unevenly, and here it was supposed to make a smooth precessional cone. Oh boy. For the second globe, I used a Scotese "free stuff" interpretation of Pangaea, which I had to augment considerably using USGS, DuToit, Irving and other references, fitting it on the globe and applying identical clay color slices to what I judged generally accepted land surfaces. Result: the thing would hardly stand up, let alone spin. Conclusion: Although a refinement of application on the "today" globe might eliminate nutation, creating a smoother spin, there is no way any refinement of Pangaea on the same size globe can come close. While the concept of a supercontinent may be viable, I theorize that it had to have evolved on a far smaller globe, where land mass could balance, and the "breakup" would not have caused us to wildly gyrate on our axis. Because Pangaea, she no spin.
Czech Academy of Sciences Publication Activity Database
Sinova, Jairo; Valenzuela, O.V.; Wunderlich, Joerg; Back, C.H.; Jungwirth, Tomáš
2015-01-01
Roč. 87, č. 4 (2015), s. 1213-1259 ISSN 0034-6861 R&D Projects: GA MŠk(CZ) LM2011026; GA ČR GB14-37427G EU Projects: European Commission(XE) 268066 - 0MSPIN Institutional support: RVO:68378271 Keywords : spin Hall effect * spintronics Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 33.177, year: 2015
Ray, J. R.
1982-01-01
The fundamental variational principle for a perfect fluid in general relativity is extended so that it applies to the metric-torsion Einstein-Cartan theory. Field equations for a perfect fluid in the Einstein-Cartan theory are deduced. In addition, the equations of motion for a fluid with intrinsic spin in general relativity are deduced from a special relativistic variational principle. The theory is a direct extension of the theory of nonspinning fluids in special relativity.
2006-06-01
high temporal resolution. An instrument has been developed for exactly this type of live-cell imaging. This new instrument scans 1000 microbeams across...Imaging System. Instead of scanning a single laser beam across the cell, this new instrument scans 1000 microbeams simultaneously using a spinning...multipoint-excitation, multipoint- emission characteristics of UltraView RS, which confers three main advantages over traditional beam scanning LSCMs for
Lord, Michael D; Mandel, Stanley W; Wager, Jeffrey D
2002-06-01
Spinouts rarely take off; most, in fact, fall into one or more of four traps that doom them from the start. Some companies spin out ventures that are too close to the core of their businesses, in effect selling off their crown jewels. Sometimes, a parent company uses the spinout primarily to pawn off debt or expenses or to quickly raise external capital for itself. Other times, a company may try to spin out an area of its business that lacks one or more of the critical legs of a successful company--a coherent business model, say, or a solid financial base. And in many cases, parent companies can't bring themselves to sever their ownership ties and give up control of their spinouts. R.J. Reynolds, the tobacco giant, managed to avoid these traps when it successfully spun out a most unlikely venture, the pharmaceutical company Targacept. As the story illustrates, the problem with spinouts is similar to the problem of rich children. Their parents have the wherewithal to spoil them or shelter them or cling to them, but what they need is tough love and discipline--much the same discipline that characterizes successful start-ups. R.J. Reynolds recognized that it didn't know that much about the pharmaceutical business and couldn't merely try to spin out a small clone of itself. It had to treat the venture as if it were essentially starting from scratch, with a passionate entrepreneurial leader, a solid business plan, help from outside partners in the industry, and ultimately substantial venture backing. That these lessons are less obvious to executives contemplating spinning out ventures closer to their core businesses may be why so many spinouts fail.
Spinning geometry = Twisted geometry
International Nuclear Information System (INIS)
Freidel, Laurent; Ziprick, Jonathan
2014-01-01
It is well known that the SU(2)-gauge invariant phase space of loop gravity can be represented in terms of twisted geometries. These are piecewise-linear-flat geometries obtained by gluing together polyhedra, but the resulting geometries are not continuous across the faces. Here we show that this phase space can also be represented by continuous, piecewise-flat three-geometries called spinning geometries. These are composed of metric-flat three-cells glued together consistently. The geometry of each cell and the manner in which they are glued is compatible with the choice of fluxes and holonomies. We first remark that the fluxes provide each edge with an angular momentum. By studying the piecewise-flat geometries which minimize edge lengths, we show that these angular momenta can be literally interpreted as the spin of the edges: the geometries of all edges are necessarily helices. We also show that the compatibility of the gluing maps with the holonomy data results in the same conclusion. This shows that a spinning geometry represents a way to glue together the three-cells of a twisted geometry to form a continuous geometry which represents a point in the loop gravity phase space. (paper)
Krasnov, K V
1999-01-01
The term ‘spin foam models’ was invented only a couple years ago by Baez to refer to a new approach to quantization of general relativity that appeared as an offsping of loop quantum gravity. Although this new approach was motivated, both logically and historically, by loop quantum gravity, it became clear by now that the two approaches are rather independent. While loop quantum gravity attempts to give a canonical quantization of general relativity, spin foam model approach is set to make sense of the path integral for gravity. Eventually, the two approaches will probably be shown to be equivalent, but no rigorous result to this effect exists as for now. In this thesis I develop the spin foam quantization of gravity from scratch, referring to results from loop quantum gravity only for comparison. I start from a review of 2 + 1 gravity and discuss different roots to quantize it. While some of them, as, for example, using Chern-Simons theory, only exist in 2 + 1, others can be generalized t...
Breakdown of Spin-Waves in Anisotropic Magnets: Spin Dynamics in α-RuCl3
Winter, Stephen; Riedl, Kira; Honecker, Andreas; Valenti, Roser
α -RuCl3 has recently emerged as a promising candidate for realizing the hexagonal Kitaev model in a real material. Similar to the related iridates (e.g. Na2IrO3), complex magnetic interactions arise from a competition between various similar energy scales, including spin-orbit coupling (SOC), Hund's coupling, and crystal-field splitting. Due to this complexity, the correct spin Hamiltonians for such systems remain hotly debated. For α-RuCl3, a combination of ab-initio calculations, microscopic considerations, and analysis of the static magnetic response have suggested off-diagonal couplings (Γ ,Γ') and long-range interactions in addition to the expected Kitaev exchange. However, the effect of such additional terms on the dynamic response remains unclear. In this contribution, we discuss the recently measured inelastic neutron scattering response in the context of realistic proposals for the microscopic spin Hamiltonian. We conclude that the observed scattering continuum, which has been taken as a signature of Kitaev spin liquid physics, likely persists over a broad range of parameters.
Bifurcation analysis and phase diagram of a spin-string model with buckled states.
Ruiz-Garcia, M; Bonilla, L L; Prados, A
2017-12-01
We analyze a one-dimensional spin-string model, in which string oscillators are linearly coupled to their two nearest neighbors and to Ising spins representing internal degrees of freedom. String-spin coupling induces a long-range ferromagnetic interaction among spins that competes with a spin-spin antiferromagnetic coupling. As a consequence, the complex phase diagram of the system exhibits different flat rippled and buckled states, with first or second order transition lines between states. This complexity translates to the two-dimensional version of the model, whose numerical solution has been recently used to explain qualitatively the rippled to buckled transition observed in scanning tunneling microscopy experiments with suspended graphene sheets. Here we describe in detail the phase diagram of the simpler one-dimensional model and phase stability using bifurcation theory. This gives additional insight into the physical mechanisms underlying the different phases and the behavior observed in experiments.
Spinning particle approach to higher spin field theory
International Nuclear Information System (INIS)
Corradini, Olindo
2011-01-01
We shortly review on the connection between higher-spin gauge field theories and supersymmetric spinning particle models. In such approach the higher spin equations of motion are linked to the first-class constraint algebra associated with the quantization of particle models. Here we consider a class of spinning particle models characterized by local O(N)-extended supersymmetry since these models are known to provide an alternative approach to the geometric formulation of higher spin field theory. We describe the canonical quantization of the models in curved target space and discuss the obstructions that appear in presence of an arbitrarily curved background. We then point out the special role that conformally flat spaces appear to have in such models and present a derivation of the higher-spin curvatures for maximally symmetric spaces.
Entanglement entropy in random quantum spin-S chains
International Nuclear Information System (INIS)
Saguia, A.; Boechat, B.; Continentino, M. A.; Sarandy, M. S.
2007-01-01
We discuss the scaling of entanglement entropy in the random singlet phase (RSP) of disordered quantum magnetic chains of general spin S. Through an analysis of the general structure of the RSP, we show that the entanglement entropy scales logarithmically with the size of a block, and we provide a closed expression for this scaling. This result is applicable for arbitrary quantum spin chains in the RSP, being dependent only on the magnitude S of the spin. Remarkably, the logarithmic scaling holds for the disordered chain even if the pure chain with no disorder does not exhibit conformal invariance, as is the case for Heisenberg integer-spin chains. Our conclusions are supported by explicit evaluations of the entanglement entropy for random spin-1 and spin-3/2 chains using an asymptotically exact real-space renormalization group approach
Spin current through quantum-dot spin valves
International Nuclear Information System (INIS)
Wang, J; Xing, D Y
2006-01-01
We report a theoretical study of the influence of the Coulomb interaction on the equilibrium spin current in a quantum-dot spin valve, in which the quantum dot described by the Anderson impurity model is coupled to two ferromagnetic leads with noncollinear magnetizations. In the Kondo regime, electrons transmit through the quantum dot via higher-order virtual processes, in which the spin of either lead electrons or a localized electron on the quantum dot may reverse. It is found that the magnitude of the spin current decreases with increasing Coulomb interactions due to spin flip effects on the dot. However, the spatial direction of the spin current remains unchanged; it is determined only by the exchange coupling between two noncollinear magnetizations
Spin Transfer Torque in Graphene
Lin, Chia-Ching; Chen, Zhihong
2014-03-01
Graphene is an idea channel material for spin transport due to its long spin diffusion length. To develop graphene based spin logic, it is important to demonstrate spin transfer torque in graphene. Here, we report the experimental measurement of spin transfer torque in graphene nonlocal spin valve devices. Assisted by a small external in-plane magnetic field, the magnetization reversal of the receiving magnet is induced by pure spin diffusion currents from the injector magnet. The magnetization switching is reversible between parallel and antiparallel configurations by controlling the polarity of the applied charged currents. Current induced heating and Oersted field from the nonlocal charge flow have also been excluded in this study. Next, we further enhance the spin angular momentum absorption at the interface of the receiving magnet and graphene channel by removing the tunneling barrier in the receiving magnet. The device with a tunneling barrier only at the injector magnet shows a comparable nonlocal spin valve signal but lower electrical noise. Moreover, in the same preset condition, the critical charge current density for spin torque in the single tunneling barrier device shows a substantial reduction if compared to the double tunneling barrier device.
Spin waves and spin instabilities in quantum plasmas
Andreev, P. A.; Kuz'menkov, L. S.
2014-01-01
We describe main ideas of method of many-particle quantum hydrodynamics allows to derive equations for description of quantum plasma evolution. We also present definitions of collective quantum variables suitable for quantum plasmas. We show that evolution of magnetic moments (spins) in quantum plasmas leads to several new branches of wave dispersion: spin-electromagnetic plasma waves and self-consistent spin waves. Propagation of neutron beams through quantum plasmas is also considered. Inst...
Hardy's argument and successive spin-s measurements
International Nuclear Information System (INIS)
Ahanj, Ali
2010-01-01
We consider a hidden-variable theoretic description of successive measurements of noncommuting spin observables on an input spin-s state. In this scenario, the hidden-variable theory leads to a Hardy-type argument that quantum predictions violate it. We show that the maximum probability of success of Hardy's argument in quantum theory is ((1/2)) 4s , which is more than in the spatial case.
Unprecedented multi-stable spin crossover molecular material with two thermal memory channels.
Seredyuk, Maksym; Muñoz, M Carmen; Castro, Miguel; Romero-Morcillo, Tania; Gaspar, Ana B; Real, Jose Antonio
2013-05-17
Two in one: A new iron(II) complex with short alkyl substituents exhibits an unprecedented bimodal behavior governed by the coexistence of three phases: two structurally different low-spin phases and one high-spin phase. The compound features two distinct well-separated strong cooperative spin-crossover transitions by varying the scan rate (see graphic). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Spin transport in spin filtering magnetic tunneling junctions.
Li, Yun; Lee, Eok Kyun
2007-11-01
Taking into account spin-orbit coupling and s-d interaction, we investigate spin transport properties of the magnetic tunneling junctions with spin filtering barrier using Landauer-Büttiker formalism implemented with the recursive algorithm to calculate the real-space Green function. We predict completely different bias dependence of negative tunnel magnetoresistance (TMR) between the systems composed of nonmagnetic electrode (NM)/ferromagnetic barrier (FB)/ferromagnet (FM) and NM/FB/FM/NM spin filtering tunnel junctions (SFTJs). Analyses of the results provide us possible ways of designing the systems which modulate the TMR in the negative magnetoresistance regime.
Spin-orbit mediated control of spin qubits
DEFF Research Database (Denmark)
Flindt, Christian; Sørensen, A.S; Flensberg, Karsten
2006-01-01
We propose to use the spin-orbit interaction as a means to control electron spins in quantum dots, enabling both single-qubit and two-qubit operations. Very fast single-qubit operations may be achieved by temporarily displacing the electrons. For two-qubit operations the coupling mechanism is based...... on a combination of the spin-orbit coupling and the mutual long-ranged Coulomb interaction. Compared to existing schemes using the exchange coupling, the spin-orbit induced coupling is less sensitive to random electrical fluctuations in the electrodes defining the quantum dots....
High-field spin dynamics of antiferromagnetic quantum spin chains
DEFF Research Database (Denmark)
Enderle, M.; Regnault, L.P.; Broholm, C.
2000-01-01
present recent work on the high-field spin dynamics of the S = I antiferromagnetic Heisenberg chains NENP (Haldane ground state) and CsNiCl3 (quasi-1D HAF close to the quantum critical point), the uniform S = 1/2 chain CTS, and the spin-Peierls system CuGeO3. (C) 2000 Elsevier Science B,V. All rights......The characteristic internal order of macroscopic quantum ground states in one-dimensional spin systems is usually not directly accessible, but reflected in the spin dynamics and the field dependence of the magnetic excitations. In high magnetic fields quantum phase transitions are expected. We...
Visualizing spin states using the spin coherent state representation
Lee Loh, Yen; Kim, Monica
2015-01-01
Orbital angular momentum eigenfunctions are readily understood in terms of spherical harmonics. However, the quantum mechanical phenomenon of spin is often said to be mysterious and hard to visualize, with no classical analog. Many textbooks give a heuristic and somewhat unsatisfying picture of a precessing spin vector. Here, we show that the spin-coherent-state representation is a striking, elegant, and mathematically meaningful tool for visualizing spin states. We also demonstrate that cartographic projections such as the Hammer projection are useful for visualizing functions defined on spherical surfaces.
Spin Currents and Spin Orbit Torques in Ferromagnets and Antiferromagnets
Hung, Yu-Ming
This thesis focuses on the interactions of spin currents and materials with magnetic order, e.g., ferromagnetic and antiferromagnetic thin films. The spin current is generated in two ways. First by spin-polarized conduction-electrons associated with the spin Hall effect in heavy metals (HMs) and, second, by exciting spin-waves in ferrimagnetic insulators using a microwave frequency magnetic field. A conduction-electron spin current can be generated by spin-orbit coupling in a heavy non-magnetic metal and transfer its spin angular momentum to a ferromagnet, providing a means of reversing the magnetization of perpendicularly magnetized ultrathin films with currents that flow in the plane of the layers. The torques on the magnetization are known as spin-orbit torques (SOT). In the first part of my thesis project I investigated and contrasted the quasistatic (slowly swept current) and pulsed current-induced switching characteristics of micrometer scale Hall crosses consisting of very thin (thesis project studies and considers applications of SOT-driven domain wall (DW) motion in a perpendicularly magnetized ultrathin ferromagnet sandwiched between a heavy metal and an oxide. My experiment results demonstrate that the DW motion can be explained by a combination of the spin Hall effect, which generates a SOT, and Dzyaloshinskii-Moriya interaction, which stabilizes chiral Neel-type DW. Based on SOT-driven DW motion and magnetic coupling between electrically isolated ferromagnetic elements, I proposed a new type of spin logic devices. I then demonstrate the device operation by using micromagnetic modeling which involves studying the magnetic coupling induced by fringe fields from chiral DWs in perpendicularly magnetized nanowires. The last part of my thesis project reports spin transport and spin-Hall magnetoresistance (SMR) in yttrium iron garnet Y3Fe5O 12 (YIG)/NiO/Pt trilayers with varied NiO thickness. To characterize the spin transport through NiO we excite
QED approach to the nuclear spin-spin coupling tensor
International Nuclear Information System (INIS)
Romero, Rodolfo H.; Aucar, Gustavo A.
2002-01-01
A quantum electrodynamical approach for the calculation of the nuclear spin-spin coupling tensor of nuclear-magnetic-resonance spectroscopy is given. Quantization of radiation fields within the molecule is considered and expressions for the magnetic field in the neighborhood of a nucleus are calculated. Using a generalization of time-dependent response theory, an effective spin-spin interaction is obtained from the coupling of nuclear magnetic moments to a virtual quantized magnetic field. The energy-dependent operators obtained reduce to usual classical-field expressions at suitable limits
Magnetic coupling and spin structure in nanocrystalline iron powders
International Nuclear Information System (INIS)
Slawska-Waniewska, A; Grafoute, M; Greneche, J M
2006-01-01
Pure single-phase iron nanostructured particles with pseudo-cubic shape crystalline grains and linear dimensions of around 11 nm can be produced by the low energy ball milling of microcrystalline Fe under argon atmosphere. The long range ferromagnetic correlation of exchange coupled crystallites extending across grain boundaries leads to a reduction of the effective anisotropy, as expected from the generalized random anisotropy model. This ferromagnetic network of correlated grains is preserved at low temperatures. No spin-glass freezing process is detected. Slight oxidation of the particles with formation of an FeO phase is achieved with deliberately prolonged milling. This FeO phase leads to non-collinear spin structure at the interfaces that suppresses the intergrain correlations and enhances the role of long range dipolar interactions. The interface spin disorder and the complex state of the intergrain interactions are the sources of the spin-glass-like behaviour found in these Fe-FeO nanocomposites
International Nuclear Information System (INIS)
Entin-Wohlman, O.
2005-01-01
Full Text:The spin-Hall effect is described. The Rashba and Dresselhaus spin-orbit interactions are both shown to yield the low temperature spin-Hall effect for strongly localized electrons coupled to phonons. A frequency-dependent electric field E(ω) generates a spin-polarization current, normal to E, due to interference of hopping paths. At zero temperature the corresponding spin-Hall conductivity is real and is proportional to ω 2 . At non-zero temperatures the coupling to the phonons yields an imaginary term proportional to ω. The interference also yields persistent spin currents at thermal equilibrium, at E = 0. The contributions from the Dresselhaus and Rashba interactions to the interference oppose each other
Current-driven spin dynamics in spin-orbit coupled superconductors
Vignale, Giovanni
2012-02-01
The study of the interplay between spin-orbit coupling (SOC) and superconductivity in two-dimensional electron gases (2DEG) has recently gained impetus following the discovery of i) 2DEGs in InAs or GaAs semiconductor heterostructures that are proximized by ordinary s-wave superconducting leads -- a class of systems which plays a key role in the quest for Majorana fermions -- and ii) 2DEGs that form at interfaces between complex oxides such as LaAlO3 and SrTiO3, which display tunable SOC and, under appropriate conditions, superconductivity. Motivated by this body of experimental and theoretical literature, we investigate the collective spin dynamics of an archetypical 2DEG model Hamiltonian with Rashba SOC in the presence of repulsive electron-electron (e-e) interactions. In the absence of superconductivity a Rashba 2DEG exhibits spin oscillations, which, at long wavelength and for weak repulsive interactions, have a frequency 2 αkF, α being the strength of SOC and kF the usual 2D Fermi wavenumber in the absence of SOC. These oscillations, however, are damped and quickly decay due to the emission of (double) electron-hole pairs, which, in the normal phase, are present at arbitrary low energies. In the presence of superconductivity, collective spin oscillations continue to exist in a wide range of parameters, because the Cooper pairs are mixtures of singlet and triplet components. Further, these excitations are undamped because they lie inside the superconducting gap where no other excitation exists. These spin oscillations can be excited by the application of a magnetic field or a supercurrent and can be used to realize persistent spin oscillators operating in the frequency range of 10 GHz - 1 THz.[4pt] Work supported by EU FP7 Programme Grant No. 215368-SEMISPINNET, No. 234970- NANOCTM and No. 248629-SOLID, and by NSF DMR-0705460.
How should spin-weighted spherical functions be defined?
Boyle, Michael
2016-09-01
Spin-weighted spherical functions provide a useful tool for analyzing tensor-valued functions on the sphere. A tensor field can be decomposed into complex-valued functions by taking contractions with tangent vectors on the sphere and the normal to the sphere. These component functions are usually presented as functions on the sphere itself, but this requires an implicit choice of distinguished tangent vectors with which to contract. Thus, we may more accurately say that spin-weighted spherical functions are functions of both a point on the sphere and a choice of frame in the tangent space at that point. The distinction becomes extremely important when transforming the coordinates in which these functions are expressed, because the implicit choice of frame will also transform. Here, it is proposed that spin-weighted spherical functions should be treated as functions on the spin or rotation groups, which simultaneously tracks the point on the sphere and the choice of tangent frame by rotating elements of an orthonormal basis. In practice, the functions simply take a quaternion argument and produce a complex value. This approach more cleanly reflects the geometry involved, and allows for a more elegant description of the behavior of spin-weighted functions. In this form, the spin-weighted spherical harmonics have simple expressions as elements of the Wigner 𝔇 representations, and transformations under rotation are simple. Two variants of the angular-momentum operator are defined directly in terms of the spin group; one is the standard angular-momentum operator L, while the other is shown to be related to the spin-raising operator ð.
Observation of the spin Nernst effect
Meyer, S.; Chen, Y.-T.; Wimmer, S.; Althammer, M.; Wimmer, T.; Schlitz, R.; Geprägs, S.; Huebl, H.; Ködderitzsch, D.; Ebert, H.; Bauer, G. E. W.; Gross, R.; Goennenwein, S. T. B.
2017-10-01
The observation of the spin Hall effect triggered intense research on pure spin current transport. With the spin Hall effect, the spin Seebeck effect and the spin Peltier effect already observed, our picture of pure spin current transport is almost complete. The only missing piece is the spin Nernst (-Ettingshausen) effect, which so far has been discussed only on theoretical grounds. Here, we report the observation of the spin Nernst effect. By applying a longitudinal temperature gradient, we generate a pure transverse spin current in a Pt thin film. For readout, we exploit the magnetization-orientation-dependent spin transfer to an adjacent yttrium iron garnet layer, converting the spin Nernst current in Pt into a controlled change of the longitudinal and transverse thermopower voltage. Our experiments show that the spin Nernst and the spin Hall effect in Pt are of comparable magnitude, but differ in sign, as corroborated by first-principles calculations.
Symplectic integrators for spin systems
McLachlan, Robert I.; Modin, Klas; Verdier, Olivier
2014-06-01
We present a symplectic integrator, based on the implicit midpoint method, for classical spin systems where each spin is a unit vector in R3. Unlike splitting methods, it is defined for all Hamiltonians and is O (3)-equivariant, i.e., coordinate-independent. It is a rare example of a generating function for symplectic maps of a noncanonical phase space. It yields a new integrable discretization of the spinning top.
Asymptotics of relativistic spin networks
International Nuclear Information System (INIS)
Barrett, John W; Steele, Christopher M
2003-01-01
The stationary phase technique is used to calculate asymptotic formulae for SO(4) relativistic spin networks. For the tetrahedral spin network this gives the square of the Ponzano-Regge asymptotic formula for the SU(2) 6j-symbol. For the 4-simplex (10j-symbol) the asymptotic formula is compared with numerical calculations of the spin network evaluation. Finally, we discuss the asymptotics of the SO(3, 1) 10j-symbol
Spin currents in metallic nanostructures
Energy Technology Data Exchange (ETDEWEB)
Czeschka, Franz Dominik
2011-09-05
A pure spin current, i.e., a flow of angular momentum without accompanying net charge current, is a key ingredient in the field of spintronics. In this thesis, we experimentally investigated two different concepts for pure spin current sources suggested by theory. The first is based on a time-dependent magnetization precession which ''pumps'' a pure spin current into an adjacent non-magnetic conductor. Our experiments quantitatively corroborated important predictions expected theoretically for this approach, including the dependence of the spin current on the sample geometry and the microwave power. Even more important, we could show for the first time that the spin pumping concept is viable in a large variety of ferromagnetic materials and that it only depends on the magnetization damping. Therefore, our experiments established spin pumping as generic phenomenon and demonstrated that it is a powerful way to generate pure spin currents. The second theoretical concept is based on the conversion of charge currents into spin currents in non-magnetic nanostructures via the spin Hall effect. We experimentally investigated this approach in H-shaped, metallic nanodevices, and found that the predictions are linked to requirements not realizable with the present experimental techniques, neither in sample fabrication nor in measurement technique. Indeed, our experimental data could be consistently understood by a spin-independent transport model describing the transition from diffusive to ballistic transport. In addition, the implementation of advanced fabrication and measurement techniques allowed to discover a new non-local phenomenon, the non-local anisotropic magnetoresistance. Finally, we also studied spin-polarized supercurrents carried by spin-triplet Cooper pairs. We found that low resistance interfaces are a key requirement for further experiments in this direction. (orig.)
Towards spin injection into silicon
Energy Technology Data Exchange (ETDEWEB)
Dash, S.P.
2007-08-15
Si has been studied for the purpose of spin injection extensively in this thesis. Three different concepts for spin injection into Si have been addressed: (1) spin injection through a ferromagnet-Si Schottky contact, (2) spin injection using MgO tunnel barriers in between the ferromagnet and Si, and (3) spin injection from Mn-doped Si (DMS) as spin aligner. (1) FM-Si Schottky contact for spin injection: To be able to improve the interface qualities one needs to understand the atomic processes involved in the formation of silicide phases. In order to obtain more detailed insight into the formation of such phases the initial stages of growth of Co and Fe were studied in situ by HRBS with monolayer depth resolution.(2) MgO tunnel barrier for spin injection into Si: The fabrication and characterization of ultra-thin crystalline MgO tunnel barriers on Si (100) was presented. (3) Mn doped Si for spin injection: Si-based diluted magnetic semiconductor samples were prepared by doping Si with Mn by two different methods i) by Mn ion implantation and ii) by in-diffusion of Mn atoms (solid state growth). (orig.)
DEFF Research Database (Denmark)
Flindt, Christian; Sørensen, A. S.; Lukin, M. D.
2007-01-01
We propose a semiconductor device that can electrically generate entangled electron spin-photon states, providing a building block for entanglement of distant spins. The device consists of a p-i-n diode structure that incorporates a coupled double quantum dot. We show that electronic control...... of the diode bias and local gating allow for the generation of single photons that are entangled with a robust quantum memory based on the electron spins. Practical performance of this approach to controlled spin-photon entanglement is analyzed....
DEFF Research Database (Denmark)
Bruun, Georg
2011-01-01
We examine spin diffusion in a two-component homogeneous Fermi gas in the normal phase. Using a variational approach, analytical results are presented for the spin diffusion coefficient and the related spin relaxation time as a function of temperature and interaction strength. For low temperatures......, strong correlation effects are included through the Landau parameters which we extract from Monte Carlo results. We show that the spin diffusion coefficient has a minimum for a temperature somewhat below the Fermi temperature with a value that approaches the quantum limit ~/m in the unitarity regime...
International Nuclear Information System (INIS)
Wasson, J.R.; Salinas, J.E.
1980-01-01
Published literature concerning electron spin resonance (ESR) from July 1977 to July 1979 is reviewed. The 108 literature sources cited were chosen from literally thousands and are intended to serve as a guide to the current literature and to provide an eclectic selection of publications cited for their contributions to the advance and/or applications of ESR spectroscopy. 40 of the sources are reviews, and a table is included to indicate the topic(s) mainly covered in each review. Other divisions of the material reviewed are apparatus and spectral analysis, analytical applications, and selected paramagnetic materials
Angular dependence of spin-orbit spin-transfer torques
Lee, Ki-Seung
2015-04-06
In ferromagnet/heavy-metal bilayers, an in-plane current gives rise to spin-orbit spin-transfer torque, which is usually decomposed into fieldlike and dampinglike torques. For two-dimensional free-electron and tight-binding models with Rashba spin-orbit coupling, the fieldlike torque acquires nontrivial dependence on the magnetization direction when the Rashba spin-orbit coupling becomes comparable to the exchange interaction. This nontrivial angular dependence of the fieldlike torque is related to the Fermi surface distortion, determined by the ratio of the Rashba spin-orbit coupling to the exchange interaction. On the other hand, the dampinglike torque acquires nontrivial angular dependence when the Rashba spin-orbit coupling is comparable to or stronger than the exchange interaction. It is related to the combined effects of the Fermi surface distortion and the Fermi sea contribution. The angular dependence is consistent with experimental observations and can be important to understand magnetization dynamics induced by spin-orbit spin-transfer torques.
Diffusion equation and spin drag in spin-polarized transport
DEFF Research Database (Denmark)
Flensberg, Karsten; Jensen, Thomas Stibius; Mortensen, Asger
2001-01-01
We study the role of electron-electron interactions for spin-polarized transport using the Boltzmann equation, and derive a set of coupled transport equations. For spin-polarized transport the electron-electron interactions are important, because they tend to equilibrate the momentum of the two-s...
Fujinami, Takeshi; Nishi, Koshiro; Matsumoto, Naohide; Iijima, Seiichiro; Halcrow, Malcolm A; Sunatsuki, Yukinari; Kojima, Masaaki
2011-12-07
Two Fe(II) complexes fac-[Fe(II)(HL(n-Pr))(3)]Cl·Y (Y = AsF(6) (1) and BF(4) (2)) were synthesized, where HL(n-Pr) is 2-methylimidazole-4-yl-methylideneamino-n-propyl. Each complex-cation has the same octahedral N(6) geometry coordinated by three bidentate ligands and assumes facial-isomerism, fac-[Fe(II)(HL(n-Pr))(3)](2+) with Δ- and Λ-enantiomorphs. Three imidazole groups per Δ- or Λ-fac-[Fe(II)(HL(n-Pr))(3)](2+) are hydrogen-bonded to three Cl(-) ions or, from the viewpoint of the Cl(-) ion, one Cl(-) ion is hydrogen-bonded to three neighbouring fac-[Fe(II)(HL(n-Pr))(3)](2+) cations. The 3 : 3 NH···Cl(-) hydrogen bonds between Δ- or Λ-fac-[Fe(II)(HL(n-Pr))(3)](2+) and Cl(-) generate two kinds of assembly structures. The directions of the 3 : 3 NH···Cl(-) hydrogen bonds and hence the resulting assembly structures are determined by the size of the anion Y, though Y is not involved into the network structure and just accommodated in the cavity. Compound 1 has a 1D ladder structure giving a larger cavity, in which the Δ- and Λ-fac-[Fe(II)(HL(n-Pr))(3)](2+) enantiomorphs are bridged by two NH···Cl(-) hydrogen bonds. Compound 2 has a 2D network structure with a net unit of a cyclic trimer of {fac-[Fe(II)(HL(n-Pr))(3)](2+)···Cl(-)}(3) giving a smaller cavity, in which Δ- or Λ-fac-[Fe(II)(HL(n-Pr))(3)](2+) species with the same chirality are linked by NH···Cl(-) hydrogen bonds to give a homochiral 2D network structure. Magnetic susceptibility and Mössbauer spectral measurements demonstrated that compound 1 showed an abrupt one-step spin crossover with 4.0 K thermal hysteresis of T(c↓) = 125.5 K and T(c↑) = 129.5 K and compound 2 showed no spin transition and stayed in the high-spin state over the 5-300 K temperature range.
Integrable Spin Chains with U(1)^3 symmetry and generalized Lunin-Maldacena backgrounds
DEFF Research Database (Denmark)
Freyhult, L.; Kristjansen, C.; Mansson, T.
2005-01-01
We consider the most general three-state spin chain with U(1)^3 symmetry and nearest neighbour interaction. Our model contains as a special case the spin chain describing the holomorphic three scalar sector of the three parameter complex deformation of N=4 SYM, dual to type IIB string theory...
The determination of the in situ structure by nuclear spin contrast variation
International Nuclear Information System (INIS)
Stuhrmann, H.B.; Nierhaus, K.H.
1994-01-01
Polarized neutron scattering from polarized nuclear spins in hydrogenous substances opens a new way of contrast variation. The enhanced contrast due to proton spin polarization was used for the in situ structure determination of tRNA of the functional complex of the E.coli ribosome
Spin caloritronics, origin and outlook
Energy Technology Data Exchange (ETDEWEB)
Yu, Haiming, E-mail: haiming.yu@buaa.edu.cn [Fert Beijing Institute, School of Electronic and Information Engineering, BDBC, Beihang University (China); Brechet, Sylvain D. [Institute of Physics, station 3, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne-EPFL (Switzerland); Ansermet, Jean-Philippe, E-mail: jean-philippe.ansermet@epfl.ch [Institute of Physics, station 3, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne-EPFL (Switzerland)
2017-03-03
Spin caloritronics refers to research efforts in spintronics when a heat current plays a role. In this review, we start out by reviewing the predictions that can be drawn from the thermodynamics of irreversible processes. This serves as a conceptual framework in which to analyze the interplay of charge, spin and heat transport. This formalism predicts tensorial relations between vectorial quantities such as currents and gradients of chemical potentials or of temperature. Transverse effects such as the Nernst or Hall effects are predicted on the basis that these tensors can include an anti-symmetric contribution, which can be written with a vectorial cross-product. The local symmetry of the system may determine the direction of the vector defining such transverse effects, such as the surface of an isotropic medium. By including magnetization as state field in the thermodynamic description, spin currents appear naturally from the continuity equation for the magnetization, and dissipative spin torques are derived, which are charge-driven or heat-driven. Thermodynamics does not give the strength of these effects, but may provide relationships between them. Based on this framework, the review proceeds by showing how these effects have been observed in various systems. Spintronics has become a vast field of research, and the experiments highlighted in this review pertain only to heat effects on transport and magnetization dynamics, such as magneto-thermoelectric power, or the spin-dependence of the Seebeck effect, the spin-dependence of the Peltier effect, the spin Seebeck effect, the magnetic Seebeck effect, or the Nernst effect. The review concludes by pointing out predicted effects that are yet to be verified experimentally, and in what novel materials the standard thermal spin effects could be investigated. - Highlights: • Thermodynamic description of transport: three-current model. • Magneto-thermoelectric power and spin-dependent Peltier effects. • Thermal
Nuclear Spin-Spin Coupling in HD, HT, and DT
Puchalski, Mariusz; Komasa, Jacek; Pachucki, Krzysztof
2018-02-01
The interaction between nuclear spins in a molecule is exceptionally sensitive to the physics beyond the standard model. However, all present calculations of the nuclear spin-spin coupling constant J are burdened by computational difficulties, which hinders the comparison to experimental results. Here, we present a variational approach and calculate the constant J in the hydrogen molecule with the controlled numerical precision, using the adiabatic approximation. The apparent discrepancy with experimental result is removed by an analysis of nonadiabatic effects based on the experimental values of the J constant for HD, HT, and DT molecules. This study significantly improves the reliability of the NMR theory for searching new physics in the spin-spin coupling.
International Nuclear Information System (INIS)
Lee, S.Y.
1990-01-01
The generalized snake configuration offers advantages of either shorter total snake length and smaller orbit displacement in the compact configuration or the multi-functions in the split configuration. We found that the compact configuration can save about 10% of the total length of a snake. On other hand, the spilt snake configuration can be used both as a snake and as a spin rotator for the helicity state. Using the orbit compensation dipoles, the spilt snake configuration can be located at any distance on both sides of the interaction point of a collider provided that there is no net dipole rotation between two halves of the snake. The generalized configuration is then applied to the partial snake excitation. Simple formula have been obtained to understand the behavior of the partial snake. Similar principle can also be applied to the spin rotators. We also estimate the possible snake imperfections are due to various construction errors of the dipole magnets. Accuracy of field error of better than 10 -4 will be significant. 2 refs., 5 figs
Berezovsky, Jesse
As we begin to look at how spin qubits might be integrated into a scalable platform, a promising strategy is to engineer the magnetic environment of the spins using micron- or nanometer-scale ferromagnetic (FM) elements, for functionalities such as nanoscale addressability, spin-wave mediated coupling, or enhanced sensing. The promise of these FM/spin interactions brings with it the question of how the coherence properties of the spin will be affected by coupling to these complex mesoscopic systems. To explore the physics of individual spins coupled to a proximal, dynamic ferromagnetic structure, we have studied interactions between individual nitrogen-vacancy (NV) spins and a model FM system - a vortex magnetization state. The complex, yet controllable, spin texture of a FM vortex, formed in a thin disk or nanowire, allows one to study different regimes of interaction with a nearby confined spin. The vortex core produces a large static dipole-like fringe field. The vortex state also displays discrete dynamic modes ranging from several 100 MHz to GHz. By applying an in-plane magnetic field, the position of the vortex core relative to the NV spin can be controlled with nanometer-scale resolution, and time resolution of 10s of nanoseconds. As the vortex core is translated into proximity with an NV spin, the fringe field from the core generates a large position-dependent spin splitting, permitting nanoscale spin addressability. We also find that the dynamic interaction of the vortex, NV spin, and applied microwave field results in amplification of the Rabi transition rate by more than an order of magnitude. Finally, we explore how spin decoherence and relaxation mechanisms are enhanced as the vortex core approaches the NVs, with implications for proposed technology incorporating coherent spins and proximal FM elements. We acknowledge support from DOE, Award No. DE-SC008148.
Energy Technology Data Exchange (ETDEWEB)
Artru, X. [Institut de Physique Nucleaire de Lyon, IN2P3-CNRS, Universite Claude Bernard, 43 boulevard du 11 Novembre 1918, F-69622 Villeurbanne (France)
2002-07-01
The aim of this introduction, which is far from exhaustive, was to give an overview on the richness of transverse spin quantity and its differences in comparison with helicity. From the experimental point of view, the physics of quark transversity in deep inelastic reaction is still practically unexplored. This situation will certainly change rapidly, with planned experiments at DESY (HERMES), Brookhaven (RHIC) and CERN (COMPAS), but there is a long way before knowing the transversity distribution, {delta}q(x), as precisely as the helicity distribution, {delta}q(x), now. Unless polarized anti-proton beams become feasible, experiments probing quark transversity will rely mainly on 'quark polarimeters', like {lambda}'s or the Collins effect. These polarimeters will have to be calibrated at e{sup +}e{sup -} colliders. The Collins polarimeter will by the way allow the flavor decomposition of {delta}q(x), using mesons of various charging and strangeness. Quark polarimetry is by itself an interesting topic of non-perturbative QCD, and may teach us something about the breaking of chiral symmetry. Let us recall that, if chiral symmetry were unbroken, transversity would be undefined. The transversity physics program is not at all a 'remake' of the helicity one. Helicity and transversity probe rather different aspects of the hadron structure. Differences between {delta}q(x) and {delta}q(x) will reveal non-relativistic effects in the baryon wave function. Also {delta}q(x) does not couples to gluon distributions, thus it is free from anomaly. In that respect it is a more clean probe than {delta}q(x). In fact, the combination of helicity and transversity measurements will perhaps be the most interesting. Polarized parton densities taking only the helicity degree of freedom are almost 'classical'. Quantum aspects of spin correlations, like violation of Bell's inequality, can be found only when varying the spin quantification axis
Microscopic theory of cooperative spin crossover: Interaction of molecular modes with phonons
Energy Technology Data Exchange (ETDEWEB)
Palii, Andrew, E-mail: andrew.palii@uv.es, E-mail: klokishner@yahoo.com; Ostrovsky, Serghei; Reu, Oleg; Klokishner, Sophia, E-mail: andrew.palii@uv.es, E-mail: klokishner@yahoo.com [Institute of Applied Physics, Academy of Sciences of Moldova, Academy Str. 5, MD-2028 Kishinev (Moldova, Republic of); Tsukerblat, Boris [Department of Chemistry, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva 84105 (Israel); Decurtins, Silvio; Liu, Shi-Xia [Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern (Switzerland)
2015-08-28
In this article, we present a new microscopic theoretical approach to the description of spin crossover in molecular crystals. The spin crossover crystals under consideration are composed of molecular fragments formed by the spin-crossover metal ion and its nearest ligand surrounding and exhibiting well defined localized (molecular) vibrations. As distinguished from the previous models of this phenomenon, the developed approach takes into account the interaction of spin-crossover ions not only with the phonons but also a strong coupling of the electronic shells with molecular modes. This leads to an effective coupling of the local modes with phonons which is shown to be responsible for the cooperative spin transition accompanied by the structural reorganization. The transition is characterized by the two order parameters representing the mean values of the products of electronic diagonal matrices and the coordinates of the local modes for the high- and low-spin states of the spin crossover complex. Finally, we demonstrate that the approach provides a reasonable explanation of the observed spin transition in the [Fe(ptz){sub 6}](BF{sub 4}){sub 2} crystal. The theory well reproduces the observed abrupt low-spin → high-spin transition and the temperature dependence of the high-spin fraction in a wide temperature range as well as the pronounced hysteresis loop. At the same time within the limiting approximations adopted in the developed model, the evaluated high-spin fraction vs. T shows that the cooperative spin-lattice transition proves to be incomplete in the sense that the high-spin fraction does not reach its maximum value at high temperature.
Superconductive analogue of spin glasses
International Nuclear Information System (INIS)
Feigel'man, M.; Ioffe, L.; Vinokur, V.; Larkin, A.
1987-07-01
The properties of granular superconductors in magnetic fields, namely the existence of a new superconductive state analogue of the low-temperature superconductive state in spin glasses are discussed in the frame of the infinite-range model and the finite-range models. Experiments for elucidation of spin-glass superconductive state in real systems are suggested. 30 refs
Featonby, David
2017-11-01
The motion of a spinning top can be mystifying at times until some basic principles are understood. In this question the key to understanding what happens is the nature of the bottom tip of the top in contact with the surface on which it spins.
Decoherence in Quantum Spin Systems
De Raedt, H; Dobrovitski, VV; Landau, DP; Lewis, SP; Schuttler, HB
2003-01-01
Computer simulations of decoherence in quantum spin systems require the solution of the time-dependent Schrodinger equation for interacting quantum spin systems over extended periods of time. We use exact diagonalization, the Chebyshev polynomial technique, four Suzuki-formula algorithms, and the
Erlingsson, S.I.
2003-01-01
The main theme of this thesis is the hyperfine interaction between the many lattice nuclear spins and electron spins localized in GaAs quantum dots. This interaction is an intrinsic property of the material. Despite the fact that this interaction is rather weak, it can, as shown in this thesis,
Black Hole Spin Measurement Uncertainty
Salvesen, Greg; Begelman, Mitchell C.
2018-01-01
Angular momentum, or spin, is one of only two fundamental properties of astrophysical black holes, and measuring its value has numerous applications. For instance, obtaining reliable spin measurements could constrain the growth history of supermassive black holes and reveal whether relativistic jets are powered by tapping into the black hole spin reservoir. The two well-established techniques for measuring black hole spin can both be applied to X-ray binaries, but are in disagreement for cases of non-maximal spin. This discrepancy must be resolved if either technique is to be deemed robust. We show that the technique based on disc continuum fitting is sensitive to uncertainties regarding the disc atmosphere, which are observationally unconstrained. By incorporating reasonable uncertainties into black hole spin probability density functions, we demonstrate that the spin measured by disc continuum fitting can become highly uncertain. Future work toward understanding how the observed disc continuum is altered by atmospheric physics, particularly magnetic fields, will further strengthen black hole spin measurement techniques.
International Nuclear Information System (INIS)
Anon.
1992-01-01
Lasers are now an everyday tool in particle physics, particularly for the spin polarization of beams, targets, and even short-lived particles. Development has been boosted in recent years by the availability of reliable multiwatt tunable lasers to select spin in an experimentally useful sample
Quantum Adiabatic Algorithms and Large Spin Tunnelling
Boulatov, A.; Smelyanskiy, V. N.
2003-01-01
We provide a theoretical study of the quantum adiabatic evolution algorithm with different evolution paths proposed in this paper. The algorithm is applied to a random binary optimization problem (a version of the 3-Satisfiability problem) where the n-bit cost function is symmetric with respect to the permutation of individual bits. The evolution paths are produced, using the generic control Hamiltonians H (r) that preserve the bit symmetry of the underlying optimization problem. In the case where the ground state of H(0) coincides with the totally-symmetric state of an n-qubit system the algorithm dynamics is completely described in terms of the motion of a spin-n/2. We show that different control Hamiltonians can be parameterized by a set of independent parameters that are expansion coefficients of H (r) in a certain universal set of operators. Only one of these operators can be responsible for avoiding the tunnelling in the spin-n/2 system during the quantum adiabatic algorithm. We show that it is possible to select a coefficient for this operator that guarantees a polynomial complexity of the algorithm for all problem instances. We show that a successful evolution path of the algorithm always corresponds to the trajectory of a classical spin-n/2 and provide a complete characterization of such paths.
Exploring Localization in Nuclear Spin Chains
Wei, Ken Xuan; Ramanathan, Chandrasekhar; Cappellaro, Paola
2018-02-01
Characterizing out-of-equilibrium many-body dynamics is a complex but crucial task for quantum applications and understanding fundamental phenomena. A central question is the role of localization in quenching thermalization in many-body systems and whether such localization survives in the presence of interactions. Probing this question in real systems necessitates the development of an experimentally measurable metric that can distinguish between different types of localization. While it is known that the localized phase of interacting systems [many-body localization (MBL)] exhibits a long-time logarithmic growth in entanglement entropy that distinguishes it from the noninteracting case of Anderson localization (AL), entanglement entropy is difficult to measure experimentally. Here, we present a novel correlation metric, capable of distinguishing MBL from AL in high-temperature spin systems. We demonstrate the use of this metric to detect localization in a natural solid-state spin system using nuclear magnetic resonance (NMR). We engineer the natural Hamiltonian to controllably introduce disorder and interactions, and observe the emergence of localization. In particular, while our correlation metric saturates for AL, it slowly keeps increasing for MBL, demonstrating analogous features to entanglement entropy, as we show in simulations. Our results show that our NMR techniques, akin to measuring out-of-time correlations, are well suited for studying localization in spin systems.
Josephson spin current in triplet superconductor junctions
Asano, Yasuhiro
2006-01-01
This paper theoretically discusses the spin current in spin-triplet superconductor / insulator / spin-triplet superconductor junctions. At low temperatures, a midgap Andreev resonant state anomalously enhances not only the charge current but also the spin current. The coupling between the Cooper pairs and the electromagnetic fields leads to the Frounhofer pattern in the direct current spin flow in magnetic fields and the alternative spin current under applied bias-voltages.
Martin, N.; Bonville, P.; Lhotel, E.; Guitteny, S.; Wildes, A.; Decorse, C.; Ciomaga Hatnean, M.; Balakrishnan, G.; Mirebeau, I.; Petit, S.
2017-10-01
We report on diffuse neutron scattering experiments providing evidence for the presence of random strains in the quantum spin-ice candidate Pr2Zr2O7 . Since Pr3 + is a non-Kramers ion, the strain deeply modifies the picture of Ising magnetic moments governing the low-temperature properties of this material. It is shown that the derived strain distribution accounts for the temperature dependence of the specific heat and of the spin-excitation spectra. Taking advantage of mean-field and spin-dynamics simulations, we argue that the randomness in Pr2Zr2O7 promotes a new state of matter, which is disordered yet characterized by short-range antiferroquadrupolar correlations, and from which emerge spin-ice-like excitations. Thus, this study gives an original research route in the field of quantum spin ice.
Directory of Open Access Journals (Sweden)
N. Martin
2017-10-01
Full Text Available We report on diffuse neutron scattering experiments providing evidence for the presence of random strains in the quantum spin-ice candidate Pr_{2}Zr_{2}O_{7}. Since Pr^{3+} is a non-Kramers ion, the strain deeply modifies the picture of Ising magnetic moments governing the low-temperature properties of this material. It is shown that the derived strain distribution accounts for the temperature dependence of the specific heat and of the spin-excitation spectra. Taking advantage of mean-field and spin-dynamics simulations, we argue that the randomness in Pr_{2}Zr_{2}O_{7} promotes a new state of matter, which is disordered yet characterized by short-range antiferroquadrupolar correlations, and from which emerge spin-ice-like excitations. Thus, this study gives an original research route in the field of quantum spin ice.
Optimized three-dimensional fast-spin-echo MRI.
Mugler, John P
2014-04-01
Spin-echo-based acquisitions are the workhorse of clinical MRI because they provide a variety of useful image contrasts and are resistant to image artifacts from radio-frequency or static field inhomogeneity. Three-dimensional (3D) acquisitions provide datasets that can be retrospectively reformatted for viewing in freely selectable orientations, and are thus advantageous for evaluating the complex anatomy associated with many clinical applications of MRI. Historically, however, 3D spin-echo-based acquisitions have not played a significant role in clinical MRI due to unacceptably long acquisition times or image artifacts associated with details of the acquisition method. Recently, optimized forms of 3D fast/turbo spin-echo imaging have become available from several MR-equipment manufacturers (for example, CUBE [GE], SPACE [Siemens], and VISTA [Philips]). Through specific design strategies and optimization, including short non-spatially selective radio-frequency pulses to significantly shorten the echo spacing and variable flip angles for the refocusing radio-frequency pulses to suppress blurring or considerably lengthen the useable duration of the spin-echo train, these techniques permit single-slab 3D imaging of sizeable volumes in clinically acceptable acquisition times. These optimized fast/turbo spin-echo pulse sequences provide a robust and flexible approach for 3D spin-echo-based imaging with a broad range of clinical applications. Copyright © 2014 Wiley Periodicals, Inc.
Atomic-Scale Nuclear Spin Imaging Using Quantum-Assisted Sensors in Diamond
Directory of Open Access Journals (Sweden)
A. Ajoy
2015-01-01
Full Text Available Nuclear spin imaging at the atomic level is essential for the understanding of fundamental biological phenomena and for applications such as drug discovery. The advent of novel nanoscale sensors promises to achieve the long-standing goal of single-protein, high spatial-resolution structure determination under ambient conditions. In particular, quantum sensors based on the spin-dependent photoluminescence of nitrogen-vacancy (NV centers in diamond have recently been used to detect nanoscale ensembles of external nuclear spins. While NV sensitivity is approaching single-spin levels, extracting relevant information from a very complex structure is a further challenge since it requires not only the ability to sense the magnetic field of an isolated nuclear spin but also to achieve atomic-scale spatial resolution. Here, we propose a method that, by exploiting the coupling of the NV center to an intrinsic quantum memory associated with the nitrogen nuclear spin, can reach a tenfold improvement in spatial resolution, down to atomic scales. The spatial resolution enhancement is achieved through coherent control of the sensor spin, which creates a dynamic frequency filter selecting only a few nuclear spins at a time. We propose and analyze a protocol that would allow not only sensing individual spins in a complex biomolecule, but also unraveling couplings among them, thus elucidating local characteristics of the molecule structure.
Spin-lattice relaxation of individual solid-state spins
Norambuena, A.; Muñoz, E.; Dinani, H. T.; Jarmola, A.; Maletinsky, P.; Budker, D.; Maze, J. R.
2018-03-01
Understanding the effect of vibrations on the relaxation process of individual spins is crucial for implementing nanosystems for quantum information and quantum metrology applications. In this work, we present a theoretical microscopic model to describe the spin-lattice relaxation of individual electronic spins associated to negatively charged nitrogen-vacancy centers in diamond, although our results can be extended to other spin-boson systems. Starting from a general spin-lattice interaction Hamiltonian, we provide a detailed description and solution of the quantum master equation of an electronic spin-one system coupled to a phononic bath in thermal equilibrium. Special attention is given to the dynamics of one-phonon processes below 1 K where our results agree with recent experimental findings and analytically describe the temperature and magnetic-field scaling. At higher temperatures, linear and second-order terms in the interaction Hamiltonian are considered and the temperature scaling is discussed for acoustic and quasilocalized phonons when appropriate. Our results, in addition to confirming a T5 temperature dependence of the longitudinal relaxation rate at higher temperatures, in agreement with experimental observations, provide a theoretical background for modeling the spin-lattice relaxation at a wide range of temperatures where different temperature scalings might be expected.
A Probabilistic Model of Spin and Spin Measurements
Niehaus, Arend
2016-01-01
Several theoretical publications on the Dirac equation published during the last decades have shown that, an interpretation is possible, which ascribes the origin of electron spin and magnetic moment to an autonomous circular motion of the point-like charged particle around a fixed centre. In more recent publications an extension of the original so called "Zitterbewegung Interpretation" of quantum mechanics was suggested, in which the spin results from an average of instantaneous spin vectors over a Zitterbewegung period. We argue that, the corresponding autonomous motion of the electron should, if it is real, determine non-relativistic spin measurements. Such a direct connection with the established formal quantum mechanical description of spin measurements, into which spin is introduced as a "non-classical" quantity has, to our knowledge, not been reported. In the present work we show that, under certain "model assumptions" concerning the proposed autonomous motion, results of spin measurements, including measurements of angular correlations in singlet systems, can indeed be correctly described using classical probabilities. The success of the model is evidence for the "reality" of the assumed autonomous motion. The resulting model violates the Bell—inequalities to the same extent as quantum mechanics.
Quantum Spin Liquids in Frustrated Spin-1 Diamond Antiferromagnets
Buessen, Finn Lasse; Hering, Max; Reuther, Johannes; Trebst, Simon
2018-01-01
Motivated by the recent synthesis of the spin-1 A -site spinel NiRh2 O4 , we investigate the classical to quantum crossover of a frustrated J1-J2 Heisenberg model on the diamond lattice upon varying the spin length S . Applying a recently developed pseudospin functional renormalization group approach for arbitrary spin-S magnets, we find that systems with S ≥3 /2 reside in the classical regime, where the low-temperature physics is dominated by the formation of coplanar spirals and a thermal (order-by-disorder) transition. For smaller local moments S =1 or S =1 /2 , we find that the system evades a thermal ordering transition and forms a quantum spiral spin liquid where the fluctuations are restricted to characteristic momentum-space surfaces. For the tetragonal phase of NiRh2 O4 , a modified J1-J2--J2⊥ exchange model is found to favor a conventionally ordered Néel state (for arbitrary spin S ), even in the presence of a strong local single-ion spin anisotropy, and it requires additional sources of frustration to explain the experimentally observed absence of a thermal ordering transition.
Spin flexoelectricity and chiral spin structures in magnetic films
International Nuclear Information System (INIS)
Pyatakov, A.P.; Sergeev, A.S.; Mikailzade, F.A.; Zvezdin, A.K.
2015-01-01
In this short review a broad range of chiral phenomena observed in magnetic films (spin cycloid and skyrmion structures formation as well as chirality dependent domain wall motion) is considered under the perspective of spin flexoelectricity, i.e. the relation between bending of magnetization pattern and electric polarization. The similarity and the difference between the spin flexoelectricity and the newly emerged notion of spin flexomagnetism are discussed. The phenomenological arguments based on the geometrical idea of curvature-induced effects are supported by analysis of the microscopic mechanisms of spin flexoelectricity based on three-site ion indirect exchange and twisted RKKY interaction models. - Highlights: • Magnetic structure formation in thin films is analogous to flexoelectric phenomena in crystals. • The microscopic mechanism of spin flexoelectricity is the antisymmetric exchange. • Spin cycloid in thin film of metals can be the result of Rashba interaction in 2DEG. • The chirality-dependent Néel-type magnetic domain wall motion is observed in electric field
Spin flexoelectricity and chiral spin structures in magnetic films
Energy Technology Data Exchange (ETDEWEB)
Pyatakov, A.P., E-mail: pyatakov@physics.msu.ru [M.V. Lomonosov Moscow State University, Leninskie gori, Moscow 119991 (Russian Federation); Sergeev, A.S. [M.V. Lomonosov Moscow State University, Leninskie gori, Moscow 119991 (Russian Federation); Mikailzade, F.A. [Department of Physics, Gebze Technical University, Gebze, 41400 Kocaeli (Turkey); Zvezdin, A.K. [A.M. Prokhorov General Physics Institute, Vavilova St., 38, Moscow 119991 (Russian Federation)
2015-06-01
In this short review a broad range of chiral phenomena observed in magnetic films (spin cycloid and skyrmion structures formation as well as chirality dependent domain wall motion) is considered under the perspective of spin flexoelectricity, i.e. the relation between bending of magnetization pattern and electric polarization. The similarity and the difference between the spin flexoelectricity and the newly emerged notion of spin flexomagnetism are discussed. The phenomenological arguments based on the geometrical idea of curvature-induced effects are supported by analysis of the microscopic mechanisms of spin flexoelectricity based on three-site ion indirect exchange and twisted RKKY interaction models. - Highlights: • Magnetic structure formation in thin films is analogous to flexoelectric phenomena in crystals. • The microscopic mechanism of spin flexoelectricity is the antisymmetric exchange. • Spin cycloid in thin film of metals can be the result of Rashba interaction in 2DEG. • The chirality-dependent Néel-type magnetic domain wall motion is observed in electric field.
Busz, Piotr; Tomaszewski, Damian; Martinek, Jan
2017-08-01
We analyze a model of a double quantum dot Cooper pair splitter coupled to two ferromagnetic detectors and demonstrate the possibility of determination of spin correlation by current measurements. We use perturbation theory, taking account of the exchange interaction with the detectors, which leads to complex spin dynamics in the dots. This affects the measured spin and restricts the use of ferromagnetic detectors to the nonlinear current-voltage characteristic regime at the current plateau, where the relevant spin projection is conserved, in contrast to the linear current-voltage characteristic regime, in which the spin information is distorted. Moreover, we show that for separable states the spin correlation can only be determined in a limited parameter regime, much more restricted than in the case of entangled states. We propose an entanglement test based on the Bell inequality.
Three-stage decoherence dynamics of an electron spin qubit in an optically active quantum dot
Bechtold, Alexander; Rauch, Dominik; Li, Fuxiang; Simmet, Tobias; Ardelt, Per-Lennart; Regler, Armin; Müller, Kai; Sinitsyn, Nikolai A.; Finley, Jonathan J.
2015-12-01
The control of solid-state qubits requires a detailed understanding of the decoherence mechanisms. Despite considerable progress in uncovering the qubit dynamics in strong magnetic fields, decoherence at very low magnetic fields remains puzzling, and the role of quadrupole coupling of nuclear spins is poorly understood. For spin qubits in semiconductor quantum dots, phenomenological models of decoherence include two basic types of spin relaxation: fast dephasing due to static but randomly distributed hyperfine fields (~2 ns) and a much slower process (>1 μs) of irreversible monotonic relaxation due either to nuclear spin co-flips or other complex many-body interaction effects. Here we show that this is an oversimplification; the spin qubit relaxation is determined by three rather than two distinct stages. The additional stage corresponds to the effect of coherent precession processes that occur in the nuclear spin bath itself, leading to a relatively fast but incomplete non-monotonic relaxation at intermediate timescales (~750 ns).
k-asymmetric spin splitting at the interface between transition metal ferromagnets and heavy metals
Grytsiuk, Sergii
2016-05-23
We systematically investigate the spin-orbit coupling-induced band splitting originating from inversion symmetry breaking at the interface between a Co monolayer and 4d (Tc, Ru, Rh, Pd, and Ag) or 5d (Re, Os, Ir, Pt, and Au) transition metals. In spite of the complex band structure of these systems, the odd-in-k spin splitting of the bands displays striking similarities with the much simpler Rashba spin-orbit coupling picture. We establish a clear connection between the overall strength of the odd-in-k spin splitting of the bands and the charge transfer between the d orbitals at the interface. Furthermore, we show that the spin splitting of the Fermi surface scales with the induced orbital moment, weighted by the spin-orbit coupling.
Spin Orbit Interaction Engineering for beyond Spin Transfer Torque memory
Wang, Kang L.
Spin transfer torque memory uses electron current to transfer the spin torque of electrons to switch a magnetic free layer. This talk will address an alternative approach to energy efficient non-volatile spintronics through engineering of spin orbit interaction (SOC) and the use of spin orbit torque (SOT) by the use of electric field to improve further the energy efficiency of switching. I will first discuss the engineering of interface SOC, which results in the electric field control of magnetic moment or magneto-electric (ME) effect. Magnetic memory bits based on this ME effect, referred to as magnetoelectric RAM (MeRAM), is shown to have orders of magnitude lower energy dissipation compared with spin transfer torque memory (STTRAM). Likewise, interests in spin Hall as a result of SOC have led to many advances. Recent demonstrations of magnetization switching induced by in-plane current in heavy metal/ferromagnetic heterostructures have been shown to arise from the large SOC. The large SOC is also shown to give rise to the large SOT. Due to the presence of an intrinsic extraordinarily strong SOC and spin-momentum lock, topological insulators (TIs) are expected to be promising candidates for exploring spin-orbit torque (SOT)-related physics. In particular, we will show the magnetization switching in a chromium-doped magnetic TI bilayer heterostructure by charge current. A giant SOT of more than three orders of magnitude larger than those reported in heavy metals is also obtained. This large SOT is shown to come from the spin-momentum locked surface states of TI, which may further lead to innovative low power applications. I will also describe other related physics of SOC at the interface of anti-ferromagnetism/ferromagnetic structure and show the control exchange bias by electric field for high speed memory switching. The work was in part supported by ERFC-SHINES, NSF, ARO, TANMS, and FAME.
Bradamante, Franco
2005-01-01
COMPASS is a new fixed target experiment presently in operation at CERN. It has the goal to investigate hadron structure and hadron spectroscopy by using either muon or hadron beams. From measurements of various hadron asymmetries in polarized muon - nucleon scattering it will be possible to determine the contribution of the gluons to the nucleon spin. Main objective of the hadron program is the search of exotic states, and glueballs in particular. This physics programme is carried out with a two-stage magnetic spectrometer, with particle identification and calorimetry in both stages, which has started collecting physics data in 2002, and will run at the CERN SPS at least until 2010. Preliminary results from the 2002 run with a 160 GeV muon beam are presented for several physics channels under investigation.
Directory of Open Access Journals (Sweden)
V.M. Loktev
2008-09-01
Full Text Available We analyze the spectral properties of a phenomenological model for a weakly doped two-dimensional antiferromagnet, in which the carriers move within one of the two sublattices where they were introduced. Such a constraint results in the free carrier spectra with the maxima at k=(± π/2 , ± π/2 observed in some cuprates. We consider the spectral properties of the model by taking into account fluctuations of the spins in the antiferromagnetic background. We show that such fluctuations lead to a non-pole-like structure of the single-hole Green's function and these fluctuations can be responsible for some anomalous "strange metal" properties of underdoped cuprates in the nonsuperconducting regime.
Martin, G. J.
1986-02-01
Laser gyroscopes have advantages compared to mechanical gyroscopes. Thus, they are more rugged and reliable, and, therefore, offer lower life-cycle costs. They are not yet more accurate than high-quality mechanical systems, but they have excellent development potential. Problems which can arise in the case of the spinning-rotor systems are related to their sensitivity to gravitational fields in the increasingly high-g environment of modern military aircraft. Optically based systems, on the other hand, have, in principle, no gravitational sensitivity and are in addition highly linear over a large dynamic range. The principles of operation of ring laser gyros (RLG) are discussed, taking into account the utilization of the Sagnac effect. Attention is given to the approaches found to overcome a number of engineering difficulties which arose in connection with the construction of RLG, techniques for limiting laser beam competition, aspects of geometry, and the current state of the art.
Minimal model of spin-transfer torque and spin pumping caused by the spin Hall Effect
Czech Academy of Sciences Publication Activity Database
Chen, W.; Sigrist, M.; Sinova, Jairo; Manske, D.
2016-01-01
Roč. 115, č. 21 (2016), 1-5, č. článku 217203. ISSN 0031-9007 Institutional support: RVO:68378271 Keywords : spin tronics * spin Hall effect Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 8.462, year: 2016
Competing Spin Liquids and Hidden Spin-Nematic Order in Spin Ice with Frustrated Transverse Exchange
Directory of Open Access Journals (Sweden)
Mathieu Taillefumier
2017-12-01
Full Text Available Frustration in magnetic interactions can give rise to disordered ground states with subtle and beautiful properties. The spin ices Ho_{2}Ti_{2}O_{7} and Dy_{2}Ti_{2}O_{7} exemplify this phenomenon, displaying a classical spin-liquid state, with fractionalized magnetic-monopole excitations. Recently, there has been great interest in closely related “quantum spin-ice” materials, following the realization that anisotropic exchange interactions could convert spin ice into a massively entangled, quantum spin liquid, where magnetic monopoles become the charges of an emergent quantum electrodynamics. Here we show that even the simplest model of a quantum spin ice, the XXZ model on the pyrochlore lattice, can realize a still-richer scenario. Using a combination of classical Monte Carlo simulation, semiclassical molecular-dynamics simulation, and analytic field theory, we explore the properties of this model for frustrated transverse exchange. We find not one, but three competing forms of spin liquid, as well as a phase with hidden, spin-nematic order. We explore the experimental signatures of each of these different states, making explicit predictions for inelastic neutron scattering. These results show an intriguing similarity to experiments on a range of pyrochlore oxides.
Competing Spin Liquids and Hidden Spin-Nematic Order in Spin Ice with Frustrated Transverse Exchange
Taillefumier, Mathieu; Benton, Owen; Yan, Han; Jaubert, L. D. C.; Shannon, Nic
2017-10-01
Frustration in magnetic interactions can give rise to disordered ground states with subtle and beautiful properties. The spin ices Ho2 Ti2 O7 and Dy2 Ti2 O7 exemplify this phenomenon, displaying a classical spin-liquid state, with fractionalized magnetic-monopole excitations. Recently, there has been great interest in closely related "quantum spin-ice" materials, following the realization that anisotropic exchange interactions could convert spin ice into a massively entangled, quantum spin liquid, where magnetic monopoles become the charges of an emergent quantum electrodynamics. Here we show that even the simplest model of a quantum spin ice, the XXZ model on the pyrochlore lattice, can realize a still-richer scenario. Using a combination of classical Monte Carlo simulation, semiclassical molecular-dynamics simulation, and analytic field theory, we explore the properties of this model for frustrated transverse exchange. We find not one, but three competing forms of spin liquid, as well as a phase with hidden, spin-nematic order. We explore the experimental signatures of each of these different states, making explicit predictions for inelastic neutron scattering. These results show an intriguing similarity to experiments on a range of pyrochlore oxides.
SpinS: Extending LTSmin with Promela through SpinJa
van der Berg, Freark; van der Berg, Freark Iwert; Laarman, Alfons; Heljanko, K.; Knottenbelt, W.J.
2012-01-01
We show how PROMELA can be supported by the high-performance generic model checking tools of LTSMIN. The success of the SPIN model checker has made PROMELA an important modeling language. SPINJA was created as a Java implementation of SPIN, in an effort to make the model checker easily extendible
The continuous spin limit of higher spin field equations
Energy Technology Data Exchange (ETDEWEB)
Bekaert, Xavier [Institut des Hautes Etudes Scientifiques, Le Bois-Marie, 35 route de Chartres, 91440 Bures-sur-Yvette (France); Mourad, Jihad [APC, Universite Paris VII, 2 place Jussieu, 75251 Paris Cedex 05 (France); LPT, Bat. 210, Universite Paris XI, 91405 Orsay Cedex (France)
2006-01-15
We show that the Wigner equations describing the continuous spin representations can be obtained as a limit of massive higher-spin field equations. The limit involves a suitable scaling of the wave function, the mass going to zero and the spin to infinity with their product being fixed. The result allows to transform the Wigner equations to a gauge invariant Fronsdal-like form. We also give the generalisation of the Wigner equations to higher dimensions with fields belonging to arbitrary representations of the massless little group.
International Nuclear Information System (INIS)
Zhang, Wenxu; Peng, Bin; Han, Fangbin; Wang, Qiuru; Zhang, Wanli; Soh, Wee Tee; Ong, Chong Kim
2016-01-01
We develop a method for universally resolving the important issue of separating the inverse spin Hall effect (ISHE) from the spin rectification effect (SRE) signal. This method is based on the consideration that the two effects depend on the spin injection direction: The ISHE is an odd function of the spin injection direction while the SRE is independent on it. Thus, the inversion of the spin injection direction changes the ISHE voltage signal, while the SRE voltage remains. It applies generally to analyzing the different voltage contributions without fitting them to special line shapes. This fast and simple method can be used in a wide frequency range and has the flexibility of sample preparation.
Spin Hall effect, Hall effect and spin precession in diffusive normal metals
Shchelushkin, R. V.; Brataas, Arne
2005-01-01
We study transport in normal metals in an external magnetic field. This system exhibits an interplay between a transverse spin imbalance (spin Hall effect) caused by the spin-orbit interaction, a Hall effect via the Lorentz force, and spin precession due to the Zeeman effect. Diffusion equations for spin and charge flow are derived. The spin and charge accumulations are computed numerically in experimentally relevant thin film geometries. The out-of-plane spin Hall potential is suppressed whe...
Spin Hamiltonian effective parameters from periodic electronic structure calculations
International Nuclear Information System (INIS)
Rivero, P; Moreira, I de Pr; Illas, F
2008-01-01
This paper presents and discusses a general procedure to extract spin Hamiltonian effective parameters from periodic calculations. The methodology is illustrated through representative examples of increasing complexity covering systems with three dimensional magnetic order or with a two dimensional magnetic structure. Some more complex systems are discussed where physical intuition based on the crystal structure of the system does not provide a reliable guide but where the present approach can be applied in a straightforward way
Owen, L.A.; Bright, Jordon; Finkel, R.C.; Jaiswal, M.K.; Kaufman, D.S.; Mahan, S.; Radtke, U.; Schneider, J.S.; Sharp, W.; Singhvi, A.K.; Warren, C.N.
2007-01-01
A Late Quaternary spit-shoreline complex on the northern shore of Pleistocene Lake Mojave of southeastern California, USA was studied with the goal of comparing accelerator mass spectrometry (AMS) radiocarbon, luminescence, electron spin resonance (ESR), terrestrial cosmogenic radionuclide (TCN) surface exposure, amino acid racemization (AAR) and U-series dating methods. The pattern of ages obtained by the different methods illustrates the complexity of processes acting in the lakeshore environment and highlights the utility of a multi-method approach. TCN surface exposure ages (mostly ???20-30 ka) record the initial erosion of shoreline benches, whereas radiocarbon ages on shells (determined in this and previous studies) within the spit, supported by AAR data, record its construction at fluctuating lake levels from ???16 to 10 ka. Luminescence ages on spit sediment (???6-7 ka) and ESR ages on spit shells (???4 ka) are anomalously young relative to radiocarbon ages of shells within the same deposits. The significance of the surprisingly young luminescence ages is not clear. The younger ESR ages could be a consequence of post-mortem enrichment of U in the shells. High concentrations of detrital thorium in tufa coating spit gravels inhibited the use of single-sample U-series dating. Detailed comparisons such as this provide one of the few means of assessing the accuracy of Quaternary dating techniques. More such comparisons are needed. ?? 2007 Elsevier Ltd and INQUA.
Spin Hall effect-driven spin torque in magnetic textures
Manchon, Aurelien
2011-07-13
Current-induced spin torque and magnetization dynamics in the presence of spin Hall effect in magnetic textures is studied theoretically. The local deviation of the charge current gives rise to a current-induced spin torque of the form (1 - ΒM) × [(u 0 + αH u 0 M) ∇] M, where u0 is the direction of the injected current, H is the Hall angle and is the non-adiabaticity parameter due to spin relaxation. Since αH and ×can have a comparable order of magnitude, we show that this torque can significantly modify the current-induced dynamics of both transverse and vortex walls. © 2011 American Institute of Physics.
Spin and torsion in gravitation
De Sabbata, Venzo
1994-01-01
This book gives an exposition of both the old and new results of spin and torsion effects on gravitational interactions with implications for particle physics, cosmology etc. Physical aspects are stressed and measurable effects in relation to other areas of physics are discussed.Among the topics discussed are: alternative ways of unifying gravity with electroweak and strong interactions by an energy dependent spin torsion coupling constant; the idea that all interactions can be understood as originating from spin curvature coupling; the possibility of cosmological models with torsion providing
Spinning fluids in general relativity
Ray, J. R.; Smalley, L. L.
1982-01-01
General relativity field equations are employed to examine a continuous medium with internal spin. A variational principle formerly applied in the special relativity case is extended to the general relativity case, using a tetrad to express the spin density and the four-velocity of the fluid. An energy-momentum tensor is subsequently defined for a spinning fluid. The equations of motion of the fluid are suggested to be useful in analytical studies of galaxies, for anisotropic Bianchi universes, and for turbulent eddies.
Spin-spin correlations in the tt'-Hubbard model
International Nuclear Information System (INIS)
Husslein, T.; Newns, D.M.; Mattutis, H.G.; Pattnaik, P.C.; Morgenstern, I.; Singer, J.M.; Fettes, W.; Baur, C.
1994-01-01
We present calculations of the tt'-Hubbard model using Quantum Monte Carlo techniques. The parameters are chosen so that the van Hove Singularity in the density of states and the Fermi level coincide. We study the behaviour of the system with increasing Hubbard interaction U. Special emphasis is on the spin-spin correlation (SSC). Unusual behaviour for large U is observed there and in the momentum distribution function (n(q)). (orig.)
Quantum Entropy and Complexity
Benatti, F.; Oskouei, S. Khabbazi; Abad, A. Shafiei Deh
We study the relations between the recently proposed machine-independent quantum complexity of P. Gacs [1] and the entropy of classical and quantum systems. On one hand, by restricting Gacs complexity to ergodic classical dynamical systems, we retrieve the equality between the Kolmogorov complexity rate and the Shannon entropy rate derived by A. A. Brudno [2]. On the other hand, using the quantum Shannon-McMillan theorem [3], we show that such an equality holds densely in the case of ergodic quantum spin chains.
Model of the electron spin in stochastic physics
Spavieri, Gianfranco
1990-01-01
The electron is conceived here as a complex structure composed of a subparticle that is bound to a nearly circular motion. Although in quantum mechanics the spin is not representable, in classical stochastic physics this corresponds to the angular momentum of the subparticle. In fact, assuming Schrödinger-type hydrodynamic equations of motion for the subparticle, the spin-1/2 representation in configuration space and the corresponding Pauli matrices for the electron are obtained. The Hamiltonian of Pauli's theory as the nonrelativistic limit of Dirac's equation is also derived.
Neutron scattering studies of magnetic molecular spin clusters
International Nuclear Information System (INIS)
Chaboussant, G.; Basler, R.; Sieber, A.; Ochsenbein, S.T.; Guedel, H.-U.
2004-01-01
Molecular magnets are crystalline materials made up of interacting magnetic centres within each molecule. Each such 'spin-cluster' is magnetically well isolated from its neighbours due to the surrounding ligands. The resulting magnetic properties are governed by exchange interactions between neighbouring spins and magneto-crystalline anisotropy. We present a brief overview of the salient features observed in three very different molecular magnets (Mn 4 , Ni 12 and V 15 ) where magnetic frustration plays a crucial role. It is demonstrated that Inelastic Neutron Scattering (INS) is an excellent technique to elucidate complex behaviour associated with geometrically frustrated molecular magnets
Computer studies of multiple-quantum spin dynamics
International Nuclear Information System (INIS)
Murdoch, J.B.
1982-11-01
The excitation and detection of multiple-quantum (MQ) transitions in Fourier transform NMR spectroscopy is an interesting problem in the quantum mechanical dynamics of spin systems as well as an important new technique for investigation of molecular structure. In particular, multiple-quantum spectroscopy can be used to simplify overly complex spectra or to separate the various interactions between a nucleus and its environment. The emphasis of this work is on computer simulation of spin-system evolution to better relate theory and experiment
Computer studies of multiple-quantum spin dynamics
Energy Technology Data Exchange (ETDEWEB)
Murdoch, J.B.
1982-11-01
The excitation and detection of multiple-quantum (MQ) transitions in Fourier transform NMR spectroscopy is an interesting problem in the quantum mechanical dynamics of spin systems as well as an important new technique for investigation of molecular structure. In particular, multiple-quantum spectroscopy can be used to simplify overly complex spectra or to separate the various interactions between a nucleus and its environment. The emphasis of this work is on computer simulation of spin-system evolution to better relate theory and experiment.
Spin tunneling and manipulation in nanostructures.
Sherman, E Ya; Ban, Yue; Gulyaev, L V; Khomitsky, D V
2012-09-01
The results for joint effects of tunneling and spin-orbit coupling on spin dynamics in nanostructures are presented for systems with discrete and continuous spectra. We demonstrate that tunneling plays the crucial role in the spin dynamics and the abilities of spin manipulation by external electric field. This result can be important for design of nanostructures-based spintronics devices.
RESEARCH PLAN FOR SPIN PHYSICS AT RHIC.
Energy Technology Data Exchange (ETDEWEB)
AIDALA, C.; BUNCE, G.; ET AL.
2005-02-01
In this report we present the research plan for the RHIC spin program. The report covers (1) the science of the RHIC spin program in a world-wide context; (2) the collider performance requirements for the RHIC spin program; (3) the detector upgrades required, including timelines; (4) time evolution of the spin program.
Some recent developments in spin glasses
Indian Academy of Sciences (India)
I give some experimental and theoretical background to spin glasses, and then discuss the nature of the phase transition in spin glasses with vector spins. Results of Monte Carlo simulations of the Heisenberg spin glass model in three dimensions are presented. A finite-size scaling analysis of the correlation length of the ...
Some recent developments in spin glasses
Indian Academy of Sciences (India)
Abstract. I give some experimental and theoretical background to spin glasses, and then discuss the nature of the phase transition in spin glasses with vector spins. Results of Monte Carlo simulations of the Heisenberg spin glass model in three dimensions are presented. A finite-size scaling analysis of the correlation length ...
Phase space representations for spin23
International Nuclear Information System (INIS)
Polubarinov, I.V.
1991-01-01
General properties of spin matrices and density ones are considered for any spin s. For spin 2 3 phase space representations are constructed. Representations, similar to the Bell one, for the correlator of projections of two spins 2 3 in the singlet state are found. Quantum analogs of the Bell inequality are obtained. 14 refs
SPIN SUSCEPTIBILITY IN HIGH - TC SUPERCONDUCTIVITY
African Journals Online (AJOL)
USER
2012-07-05
Jul 5, 2012 ... Anderson (KGA)rules(Suzuki,Suzuki,2009) will upturn the. Cu spins. It turns that this process introduces the now measurable spin fluctuations in the cuprates. The AFM sublattices contain two spin magnetic moments as we know and according to basic theory of magnetism, equal and opposite spin currents ...
Analytical gradients for density functional calculations with approximate spin projection.
Saito, Toru; Thiel, Walter
2012-11-08
We have derived and implemented analytical gradients for broken-symmetry unrestricted density functional calculations (BS-UDFT) with removal of spin contamination by Yamaguchi's approximate spin projection method. Geometry optimizations with these analytical gradients (AGAP-opt) yield results consistent with those obtained with the previously available numerical gradients (NAP-opt). The AGAP-opt approach is found to be more precise, efficient, and robust than NAP-opt. It allows full geometry optimizations for large open-shell systems. We report results for three types of organic diradicals and for a binuclear vanadium(II) complex to demonstrate the merits of removing the spin contamination effects during geometry optimization (AGAP-opt vs BS-UDFT) and to illustrate the superior performance of the analytical gradients (AGAP-opt vs NAP-opt). The results for the vanadium(II) complex indicate that the AGAP-opt method is capable of handling pronounced spin contamination effects in large binuclear transition metal complexes with two magnetic centers.
Magnetoelectric control of spin currents
Energy Technology Data Exchange (ETDEWEB)
Gómez, J. E.; Vargas, J. M.; Avilés-Félix, L.; Butera, A. [Centro Atómico Bariloche, Instituto de Nanociencia y Nanotecnología (CNEA) and Conicet, 8400 Bariloche, Río Negro (Argentina)
2016-06-13
The ability to control the spin current injection has been explored on a hybrid magnetoelectric system consisting of a (011)-cut ferroelectric lead magnesium niobate-lead titanate (PMNT) single crystal, a ferromagnetic FePt alloy, and a metallic Pt. With this PMNT/FePt/Pt structure we have been able to control the magnetic field position or the microwave excitation frequency at which the spin pumping phenomenon between FePt and Pt occurs. We demonstrate that the magnetoelectric heterostructure operating in the L-T (longitudinal magnetized-transverse polarized) mode couples the PMNT crystal to the magnetostrictive FePt/Pt bilayer, displaying a strong magnetoelectric coefficient of ∼140 Oe cm kV{sup −1}. Our results show that this mechanism can be effectively exploited as a tunable spin current intensity emitter and open the possibility to create an oscillating or a bistable switch to effectively manipulate spin currents.
Magnetoelectric control of spin currents
International Nuclear Information System (INIS)
Gómez, J. E.; Vargas, J. M.; Avilés-Félix, L.; Butera, A.
2016-01-01
The ability to control the spin current injection has been explored on a hybrid magnetoelectric system consisting of a (011)-cut ferroelectric lead magnesium niobate-lead titanate (PMNT) single crystal, a ferromagnetic FePt alloy, and a metallic Pt. With this PMNT/FePt/Pt structure we have been able to control the magnetic field position or the microwave excitation frequency at which the spin pumping phenomenon between FePt and Pt occurs. We demonstrate that the magnetoelectric heterostructure operating in the L-T (longitudinal magnetized-transverse polarized) mode couples the PMNT crystal to the magnetostrictive FePt/Pt bilayer, displaying a strong magnetoelectric coefficient of ∼140 Oe cm kV −1 . Our results show that this mechanism can be effectively exploited as a tunable spin current intensity emitter and open the possibility to create an oscillating or a bistable switch to effectively manipulate spin currents.
Spin Structure Analyses of Antiferromagnets
International Nuclear Information System (INIS)
Chung, Jae Ho; Song, Young Sang; Lee, Hak Bong
2010-05-01
We have synthesized series of powder sample of incommensurate antiferromagnetic multiferroics, (Mn, Co)WO 4 and Al doped Ba 0.5 Sr 1.5 Zn 2 Fe 12 O 22 , incommensurate antiferromagnetic multiferroics. Their spin structure was studied by using the HRPD. In addition, we have synthesized series of crystalline samples of incommensurate multiferroics, (Mn, Co)WO 4 and olivines. Their spin structure was investigated using neutron diffraction under high magnetic field. As a result, we were able to draw the phase diagram of (Mn, Co)WO 4 as a function of composition and temperature. We learned the how the spin structure changes with increased ionic substitution. Finally we have drawn the phase diagram of the multicritical olivine Mn2SiS4/Mn2GeS4 as a function of filed and temperature through the spin structure studies
International Nuclear Information System (INIS)
Gamboa, J.; Rivelles, V.O.
1989-01-01
Self-dual particles in two-dimensions are presented. They were obtained from chiral boson particle by square root technique. The propagator of spinning self-dual particle is calculated using the BFV formalism. (M.C.K.)
Spin and charge transport in the presence of spin-orbit interaction
Indian Academy of Sciences (India)
Home; Journals; Pramana – Journal of Physics; Volume 58; Issue 2. Spin and ... We present the study of spin and charge transport in nanostructures in the presence of spin-orbit (SO) interaction. ... Using these tight binding Hamiltonians and spin resolved Landauer–Büttiker formula, spin and charge transport is studied.
Spin Hall effect by surface roughness
Zhou, Lingjun
2015-01-08
The spin Hall and its inverse effects, driven by the spin orbit interaction, provide an interconversion mechanism between spin and charge currents. Since the spin Hall effect generates and manipulates spin current electrically, to achieve a large effect is becoming an important topic in both academia and industries. So far, materials with heavy elements carrying a strong spin orbit interaction, provide the only option. We propose here a new mechanism, using the surface roughness in ultrathin films, to enhance the spin Hall effect without heavy elements. Our analysis based on Cu and Al thin films suggests that surface roughness is capable of driving a spin Hall angle that is comparable to that in bulk Au. We also demonstrate that the spin Hall effect induced by surface roughness subscribes only to the side-jump contribution but not the skew scattering. The paradigm proposed in this paper provides the second, not if only, alternative to generate a sizable spin Hall effect.
Spin-controlled atom-ion chemistry.
Sikorsky, Tomas; Meir, Ziv; Ben-Shlomi, Ruti; Akerman, Nitzan; Ozeri, Roee
2018-03-02
Quantum control of chemical reactions is an important goal in chemistry and physics. Ultracold chemical reactions are often controlled by preparing the reactants in specific quantum states. Here we demonstrate spin-controlled atom-ion inelastic (spin-exchange) processes and chemical (charge-exchange) reactions in an ultracold Rb-Sr + mixture. The ion's spin state is controlled by the atomic hyperfine spin state via spin-exchange collisions, which polarize the ion's spin parallel to the atomic spin. We achieve ~ 90% spin polarization due to the absence of strong spin-relaxation channel. Charge-exchange collisions involving electron transfer are only allowed for (RbSr) + colliding in the singlet manifold. Initializing the atoms in various spin states affects the overlap of the collision wave function with the singlet molecular manifold and therefore also the reaction rate. Our observations agree with theoretical predictions.
Stronach, C. E.
1983-01-01
The muon spin rotation (MuSR) technique is used to probe the microscopic electron density in materials. High temperature MuSR and magnetization measurements in nickel are in progress to allow an unambiguous determination of the muon impurity interaction and the impurity induced change in local spin density. The first results on uniaxial stress induced frequency shifts in an Fe single crystal are also reported.
International Nuclear Information System (INIS)
Lindgaard, P.-A.
1978-01-01
When neutron scattering data became available for the light rare earths (REs) and the RE compounds, a need was felt for a systematic theory for excitations in crystal-field dominated systems. The crystal field mixes the wavefunctions and provides a coupling between the ground state and the excited states for many operators, whereas for the Heisenberg system only J - has a nonzero matrix element to the first excited state. A review is given of successful applications of the theory in the interpretation of several experiments. The excitation spectrum for neutron scattering is simply given by the poles of the imaginary part of the enhanced wave-vector-dependent susceptibility tensor calculated in the random-phase approximation. A discussion of the effect of two-ion anisotropy is given. The formalism reduces to the conventional spin wave theory for the Heisenberg system when the crystal field is negligible compared to the exchange interaction. However, this theory has the drawback that it is necessary to know the crystal field in advance and each value of J must then be treated separately. A review of the results in the RE Laves-phase compounds and in the heavy rare earths is given, and the status of the current understanding of the interactions is rare earths and their compounds is discussed. (author)
International Nuclear Information System (INIS)
Tannenbaum, M.J.
1996-01-01
Operation of RHIC with two beams of highly polarized protons (70%, either longitudinal or transverse) at high luminosity L = 2 x 10 32 cm -2 sec -1 for two months/year will allow the STAR and PHENIX detectors to perform high statististics studies of polarization phenomena in the perturbative region of hard scattering where both QCD and ElectroWeak theory make detailed predictions for polarization effects. The collision c.m. energy, √s = 200 - 500 GeV, represents a new domain for the study of spin. Direct photon production will be used to measure the gluon polarization in the polarized proton. A new twist comes from W-boson production which is expected to be 100% parity violating and will thus allow measurements of flavor separated Quark and antiquark (u, bar u, d, bar d) polarization distributions. Searches for parity violation in strong interaction processes such as jet and leading particle production will be a sensitive way to look for new physics beyond the standard model, one possibility being quark substructure
Energy Technology Data Exchange (ETDEWEB)
Grames, J M; Benesch, J F; Clark, J; Hansknecht, J; Kazimi, R; Machie, D; Poelker, M; Stutzman, M L; Suleiman, R
2011-03-01
A new 4pi spin manipulator composed of two Wien filters oriented orthogonally and separated by two solenoids has been installed at the CEBAF/Jefferson Lab photoinjector. The new spin manipulator is used to precisely set the electron spin direction at an experiment in any direction (in or out of plane of the accelerator) and provides the means to reverse, or flip, the helicity of the electron beam on a daily basis. This reversal is being employed to suppress systematic false asymmetries that can jeopardize challenging parity violation experiments that strive to measure increasingly small physics asymmetries [*,**,***]. The spin manipulator is part of the ultra-high vacuum polarized electron source beam line and has been successfully operated with 100keV and 130keV electron beam at high current (>100 microAmps). A unique feature of the device is that spin-flipping requires only the polarity of one solenoid magnet be changed. Performance characteristics of the Two Wien Filter Spin Flipper will be summarized.
Positivity of spin foam amplitudes
International Nuclear Information System (INIS)
Baez, John C; Christensen, J Daniel
2002-01-01
The amplitude for a spin foam in the Barrett-Crane model of Riemannian quantum gravity is given as a product over its vertices, edges and faces, with one factor of the Riemannian 10j symbols appearing for each vertex, and simpler factors for the edges and faces. We prove that these amplitudes are always nonnegative for closed spin foams. As a corollary, all open spin foams going between a fixed pair of spin networks have real amplitudes of the same sign. This means one can use the Metropolis algorithm to compute expectation values of observables in the Riemannian Barrett-Crane model, as in statistical mechanics, even though this theory is based on a real-time (e iS ) rather than imaginary-time e -S path integral. Our proof uses the fact that when the Riemannian 10j symbols are nonzero, their sign is positive or negative depending on whether the sum of the ten spins is an integer or half-integer. For the product of 10j symbols appearing in the amplitude for a closed spin foam, these signs cancel. We conclude with some numerical evidence suggesting that the Lorentzian 10j symbols are always nonnegative, which would imply similar results for the Lorentzian Barrett-Crane model
Experimental Realization of a Quantum Spin Pump
DEFF Research Database (Denmark)
Watson, Susan; Potok, R.; M. Marcus, C.
2003-01-01
We demonstrate the operation of a quantum spin pump based on cyclic radio-frequency excitation of a GaAs quantum dot, including the ability to pump pure spin without pumping charge. The device takes advantage of bidirectional mesoscopic fluctuations of pumped current, made spin......-dependent by the application of an in-plane Zeeman field. Spin currents are measured by placing the pump in a focusing geometry with a spin-selective collector....
Spin stabilized magnetic levitation of horizontal rotors.
Energy Technology Data Exchange (ETDEWEB)
Romero, Louis Anthony
2004-10-01
In this paper we present an analysis of a new configuration for achieving spin stabilized magnetic levitation. In the classical configuration, the rotor spins about a vertical axis; and the spin stabilizes the lateral instability of the top in the magnetic field. In this new configuration the rotor spins about a horizontal axis; and the spin stabilizes the axial instability of the top in the magnetic field.
Thermal entanglement properties of small spin clusters
Bose, Indrani; Tribedi, Amit
2005-01-01
Exchange interactions in spin systems can give rise to quantum entanglement in the ground and thermal states of the systems. In this paper, we consider a spin tetramer, with spins of magnitude 1/2, in which the spins interact via nearest-neighbour, diagonal and four-spin interactions of strength J1, J2 and K respectively. The ground and thermal state entanglement properties of the tetramer are calculated analytically in the various limiting cases. Signatures of quantum phase transition (QPT) ...
Quantum spin transport in semiconductor nanostructures
Energy Technology Data Exchange (ETDEWEB)
Schindler, Christoph
2012-05-15
In this work, we study and quantitatively predict the quantum spin Hall effect, the spin-orbit interaction induced intrinsic spin-Hall effect, spin-orbit induced magnetizations, and spin-polarized electric currents in nanostructured two-dimensional electron or hole gases with and without the presence of magnetic fields. We propose concrete device geometries for the generation, detection, and manipulation of spin polarization and spin-polarized currents. To this end a novel multi-band quantum transport theory, that we termed the multi-scattering Buettiker probe model, is developed. The method treats quantum interference and coherence in open quantum devices on the same footing as incoherent scattering and incorporates inhomogeneous magnetic fields in a gauge-invariant and nonperturbative manner. The spin-orbit interaction parameters that control effects such as band energy spin splittings, g-factors, and spin relaxations are calculated microscopically in terms of an atomistic relativistic tight-binding model. We calculate the transverse electron focusing in external magnetic and electric fields. We have performed detailed studies of the intrinsic spin-Hall effect and its inverse effect in various material systems and geometries. We find a geometry dependent threshold value for the spin-orbit interaction for the inverse intrinsic spin-Hall effect that cannot be met by n-type GaAs structures. We propose geometries that spin polarize electric current in zero magnetic field and analyze the out-of-plane spin polarization by all electrical means. We predict unexpectedly large spin-orbit induced spin-polarization effects in zero magnetic fields that are caused by resonant enhancements of the spin-orbit interaction in specially band engineered and geometrically designed p-type nanostructures. We propose a concrete realization of a spin transistor in HgTe quantum wells, that employs the helical edge channel in the quantum spin Hall effect.
Amplification of spin-current polarization
Saha, D.; Holub, M.; Bhattacharya, P.
2007-08-01
A ferromagnet/semiconductor based electrically controlled spin-current amplifier using a dual-drain nonlocal lateral spin valve is demonstrated. The spin polarization injected by the source into the channel is amplified at the second drain contact. An amplified current spin polarization of 100% is measured. The controlled variation of amplifier gain with bias is also demonstrated. The observations are explained in the framework of the spin drift-diffusion model.
Quantum spin transport in semiconductor nanostructures
International Nuclear Information System (INIS)
Schindler, Christoph
2012-01-01
In this work, we study and quantitatively predict the quantum spin Hall effect, the spin-orbit interaction induced intrinsic spin-Hall effect, spin-orbit induced magnetizations, and spin-polarized electric currents in nanostructured two-dimensional electron or hole gases with and without the presence of magnetic fields. We propose concrete device geometries for the generation, detection, and manipulation of spin polarization and spin-polarized currents. To this end a novel multi-band quantum transport theory, that we termed the multi-scattering Buettiker probe model, is developed. The method treats quantum interference and coherence in open quantum devices on the same footing as incoherent scattering and incorporates inhomogeneous magnetic fields in a gauge-invariant and nonperturbative manner. The spin-orbit interaction parameters that control effects such as band energy spin splittings, g-factors, and spin relaxations are calculated microscopically in terms of an atomistic relativistic tight-binding model. We calculate the transverse electron focusing in external magnetic and electric fields. We have performed detailed studies of the intrinsic spin-Hall effect and its inverse effect in various material systems and geometries. We find a geometry dependent threshold value for the spin-orbit interaction for the inverse intrinsic spin-Hall effect that cannot be met by n-type GaAs structures. We propose geometries that spin polarize electric current in zero magnetic field and analyze the out-of-plane spin polarization by all electrical means. We predict unexpectedly large spin-orbit induced spin-polarization effects in zero magnetic fields that are caused by resonant enhancements of the spin-orbit interaction in specially band engineered and geometrically designed p-type nanostructures. We propose a concrete realization of a spin transistor in HgTe quantum wells, that employs the helical edge channel in the quantum spin Hall effect.
Optical investigation of spin injection from (Ga,Mn)As into n-GaAs
Energy Technology Data Exchange (ETDEWEB)
Endres, Bernhard; Sperl, Matthias; Utz, Martin; Schuh, Dieter; Einwanger, Andreas; Ciorga, Mariusz; Back, Christian; Bayreuther, Guenther [Universitaet Regensburg (Germany)
2011-07-01
Spin injection from a Ga(Mn,As) contact into a n-GaAs channel through an Esaki diode structure was investigated. Details of the layer structure are described in Ref 1. After lithographic patterning the spin polarization in the GaAs was measured by p-MOKE at low temperatures across a cleaved edge as described in Ref. 2. From the distribution of the spin polarization below the injecting contact the spin diffusion length and the drift dependent spin decay length can be estimated, which are important parameters for the calculation of the spin lifetime from Hanle-measurements. However, several contributions to the Hanle curves as the stray field, dynamic nuclear polarization and a tilted magnetization of the injector make the calculation of the spin lifetime more complex. In this contribution the different parameters of the sample are characterized by fitting experimental data with a one-dimensional drift-diffusion equation. A spin diffusion length of about 5 {mu}m and a spin lifetime of 10 ns was observed.
NMR Investigation of beta-Substituted High-Spin and Low-Spin Iron(III) Tetraphenylporphyrins.
Wojaczynski, Jacek; Latos-Grazynski, Lechoslaw; Hrycyk, Witold; Pacholska, Ewa; Rachlewicz, Krystyna; Szterenberg, Ludmila
1996-11-06
The NMR spectra of a series of beta-substituted iron(III) tetraphenylporphyrin (2-X-TPP) complexes have been studied to elucidate the relationship between the electron donating/withdrawing properties of the 2-substituent and the (1)H NMR spectral pattern. The electronic nature of the substituent has been significantly varied and covered the -0.6 to 0.8 Hammett constant range. Both high-spin and low-spin complexes of the general formula (2-X-TPP)Fe(III)Cl and [(2-X-TPP)Fe(III)(CN)(2)](-) have been investigated. The (1)H NMR data for the following substituents (X) have been reported: py(+), NO(2), CN, CH(3), BzO (C(6)H(5)COO), H, D, Br, Cl, CH(3), NH(2), NH(3)(+), NHCH(3), OH, and O(-). The (1)H NMR resonances for low-spin dicyano complexes have been completely assigned by a combination of two-dimensional COSY and NOESY experiments. In the case of selected high-spin complexes, the 3-H resonance has been identified by the selective deuteration of all but the 3-H position. The pattern of unambiguously assigned seven pyrrole resonances reflects the asymmetry imposed by 2-substitution and has been used as an unique (1)H NMR spectroscopic probe to map the spin density distribution. The pyrrole isotropic shifts of [(2-X-TPP)Fe(III)(CN)(2)](-) are dominated by the contact term. In order to quantify the substituent effect, the dependence of isotropic shift of all low-spin pyrrole resonances and 3-H high-spin pyrrole resonance versus Hammett constants has been studied. The electronic effect is strongly localized at the beta-substituted pyrrole. The major change of the isotropic shift has also been noted for only one of two adjacent pyrrole rings, i.e., at 7-H and 8-H positions. These neighboring protons, located on a single pyrrole ring, experienced opposite shift changes when electron withdrawing/donating properties were modified. Two other pyrrole rings for all investigated derivatives revealed considerably smaller, substituent related, isotropic shift changes. A long
Progressive freezing of interacting spins in isolated finite magnetic ensembles
Bhattacharya, Kakoli; Dupuis, Veronique; Le-Roy, Damien; Deb, Pritam
2017-02-01
Self-organization of magnetic nanoparticles into secondary nanostructures provides an innovative way for designing functional nanomaterials with novel properties, different from the constituent primary nanoparticles as well as their bulk counterparts. Collective magnetic properties of such complex closed packing of magnetic nanoparticles makes them more appealing than the individual magnetic nanoparticles in many technological applications. This work reports the collective magnetic behaviour of magnetic ensembles comprising of single domain Fe3O4 nanoparticles. The present work reveals that the ensemble formation is based on the re-orientation and attachment of the nanoparticles in an iso-oriented fashion at the mesoscale regime. Comprehensive dc magnetic measurements show the prevalence of strong interparticle interactions in the ensembles. Due to the close range organization of primary Fe3O4 nanoparticles in the ensemble, the spins of the individual nanoparticles interact through dipolar interactions as realized from remnant magnetization measurements. Signature of super spin glass like behaviour in the ensembles is observed in the memory studies carried out in field cooled conditions. Progressive freezing of spins in the ensembles is corroborated from the Vogel-Fulcher fit of the susceptibility data. Dynamic scaling of relaxation reasserted slow spin dynamics substantiating cluster spin glass like behaviour in the ensembles.
Magnon Mode Selective Spin Transport in Compensated Ferrimagnets
Cramer, Joel
2017-04-13
We investigate the generation of magnonic thermal spin currents and their mode selective spin transport across interfaces in insulating, compensated ferrimagnet/normal metal bilayer systems. The spin Seebeck effect signal exhibits a nonmonotonic temperature dependence with two sign changes of the detected voltage signals. Using different ferrimagnetic garnets, we demonstrate the universality of the observed complex temperature dependence of the spin Seebeck effect. To understand its origin, we systematically vary the interface between the ferrimagnetic garnet and the metallic layer, and by using different metal layers we establish that interface effects play a dominating role. They do not only modify the magnitude of the spin Seebeck effect signal but in particular also alter its temperature dependence. By varying the temperature, we can select the dominating magnon mode and we analyze our results to reveal the mode selective interface transmission probabilities for different magnon modes and interfaces. The comparison of selected systems reveals semiquantitative details of the interfacial coupling depending on the materials involved, supported by the obtained field dependence of the signal.
Proof of the Spin Statistics Connection 2: Relativistic Theory
Santamato, Enrico; De Martini, Francesco
2017-12-01
The traditional standard theory of quantum mechanics is unable to solve the spin-statistics problem, i.e. to justify the utterly important "Pauli Exclusion Principle" but by the adoption of the complex standard relativistic quantum field theory. In a recent paper (Santamato and De Martini in Found Phys 45(7):858-873, 2015) we presented a proof of the spin-statistics problem in the nonrelativistic approximation on the basis of the "Conformal Quantum Geometrodynamics". In the present paper, by the same theory the proof of the spin-statistics theorem is extended to the relativistic domain in the general scenario of curved spacetime. The relativistic approach allows to formulate a manifestly step-by-step Weyl gauge invariant theory and to emphasize some fundamental aspects of group theory in the demonstration. No relativistic quantum field operators are used and the particle exchange properties are drawn from the conservation of the intrinsic helicity of elementary particles. It is therefore this property, not considered in the standard quantum mechanics, which determines the correct spin-statistics connection observed in Nature (Santamato and De Martini in Found Phys 45(7):858-873, 2015). The present proof of the spin-statistics theorem is simpler than the one presented in Santamato and De Martini (Found Phys 45(7):858-873, 2015), because it is based on symmetry group considerations only, without having recourse to frames attached to the particles. Second quantization and anticommuting operators are not necessary.
Spin-inversion in nanoscale graphene sheets with a Rashba spin-orbit barrier
Directory of Open Access Journals (Sweden)
Somaieh Ahmadi
2012-03-01
Full Text Available Spin-inversion properties of an electron in nanoscale graphene sheets with a Rashba spin-orbit barrier is studied using transfer matrix method. It is found that for proper values of Rashba spin-orbit strength, perfect spin-inversion can occur in a wide range of electron incident angle near the normal incident. In this case, the graphene sheet with Rashba spin-orbit barrier can be considered as an electron spin-inverter. The efficiency of spin-inverter can increase up to a very high value by increasing the length of Rashba spin-orbit barrier. The effect of intrinsic spin-orbit interaction on electron spin inversion is then studied. It is shown that the efficiency of spin-inverter decreases slightly in the presence of intrinsic spin-orbit interaction. The present study can be used to design graphene-based spintronic devices.
Spin-transfer torque in spin filter tunnel junctions
Ortiz Pauyac, Christian
2014-12-08
Spin-transfer torque in a class of magnetic tunnel junctions with noncollinear magnetizations, referred to as spin filter tunnel junctions, is studied within the tight-binding model using the nonequilibrium Green\\'s function technique within Keldysh formalism. These junctions consist of one ferromagnet (FM) adjacent to a magnetic insulator (MI) or two FM separated by a MI. We find that the presence of the magnetic insulator dramatically enhances the magnitude of the spin-torque components compared to conventional magnetic tunnel junctions. The fieldlike torque is driven by the spin-dependent reflection at the MI/FM interface, which results in a small reduction of its amplitude when an insulating spacer (S) is inserted to decouple MI and FM layers. Meanwhile, the dampinglike torque is dominated by the tunneling electrons that experience the lowest barrier height. We propose a device of the form FM/(S)/MI/(S)/FM that takes advantage of these characteristics and allows for tuning the spin-torque magnitudes over a wide range just by rotation of the magnetization of the insulating layer.
Spin relaxation in quantum dots: Role of the phonon modulated spin-orbit interaction
Alcalde, A. M.; Romano, C. L.; Sanz, L.; Marques, G. E.
2010-01-01
We calculate the spin relaxation rates in a parabolic InSb quantum dots due to the spin interaction with acoustical phonons. We considered the deformation potential mechanism as the dominant electron-phonon coupling in the Pavlov-Firsov spin-phonon Hamiltonian. We analyze the behavior of the spin relaxation rates as a function of an external magnetic field and mean quantum dot radius. Effects of the spin admixture due to Dresselhaus contribution to spin-orbit interaction are also discussed.
Singh, Madhav K.; Jha, Pradeep K.; Bhattacherjee, Aranya B.
2017-09-01
In this article, we study the spin and tunneling dynamics as a function of magnetic field in a one-dimensional GaAs double quantum dot with both the Dresselhaus and Rashba spin-orbit coupling. In particular, we consider different spatial widths for the spin-up and spin-down electronic states. We find that the spin dynamics is a superposition of slow as well as fast Rabi oscillations. It is found that the Rashba interaction strength as well as the external magnetic field strongly modifies the slow Rabi oscillations which is particularly useful for implementing solid state selective spin transport device.
Spin dynamics with inertia in metallic ferromagnets
Kikuchi, Toru; Tatara, Gen
2015-11-01
The nonadiabatic contribution of environmental degrees of freedom yields an effective inertia of spin in the effective spin dynamics. In this paper, we study several aspects of the inertia of spin in metallic ferromagnets: (i) a concrete expression of the spin inertia ms: ms=ℏ Sc/(2 gsd) , where Sc is the spin polarization of conduction electrons and gsd is the s d coupling constant; (ii) a dynamical behavior of spin with inertia, discussed from the viewpoints of a spinning top and of a particle on a sphere; (iii) the behavior of spin waves and domain walls in the presence of inertia and the behavior of spin with inertia under a time-dependent magnetic field.
International Nuclear Information System (INIS)
Hong Fenglei; Zhang Yun; Ishikawa, Jun; Onae, Atsushi; Matsumoto, Hirokazu
2002-01-01
Hyperfine structures of the R(87)33-0, R(145)37-0, and P(132)36-0 transitions of molecular iodine near 532 nm are measured by observing the heterodyne beat-note signal of two I 2 -stabilized lasers, whose frequencies are bridged by an optical frequency comb generator. The measured hyperfine splittings are fit to a four-term Hamiltonian, which includes the electric quadrupole, spin-rotation, tensor spin-spin, and scalar spin-spin interactions, with an accuracy of ∼720 Hz. High-accurate hyperfine constants are obtained from this fit. Vibration dependences of the tensor spin-spin and scalar spin-spin hyperfine constants are determined for molecular iodine, for the first time to our knowledge. The observed hyperfine transitions are good optical frequency references in the 532-nm region
Universal spin dynamics in quantum wires
Energy Technology Data Exchange (ETDEWEB)
Fajardo, E. A.; Zülicke, U.; Winkler, R.
2017-10-01
We discuss the universal spin dynamics in quasi-one-dimensional systems including the real spin in narrow-gap semiconductors like InAs and InSb, the valley pseudospin in staggered single-layer graphene, and the combination of real spin and valley pseudospin characterizing single-layer transition metal dichalcogenides (TMDCs) such as MoS2, WS2, MoS2, and WSe2. All these systems can be described by the same Dirac-like Hamiltonian. Spin-dependent observable effects in one of these systems thus have counterparts in each of the other systems. Effects discussed in more detail include equilibrium spin currents, current-induced spin polarization (Edelstein effect), and spin currents generated via adiabatic spin pumping. Our work also suggests that a long-debated spin-dependent correction to the position operator in single-band models should be absent.
Spin transport in benzofurane bithiophene based organic spin valves
Energy Technology Data Exchange (ETDEWEB)
Palosse, Mathieu; Séguy, Isabelle; Bedel-Pereira, Élena [CNRS, LAAS, 7 avenue du Colonel Roche, F-31400 Toulouse (France); Université de Toulouse (France); UPS, INSA, INP, ISAE (France); LAAS (France); CEMES, F-31077 Toulouse (France); Villeneuve-Faure, Christina [Université de Toulouse (France); UPS, INSA, INP, ISAE (France); LAAS (France); CEMES, F-31077 Toulouse (France); LAPLACE, Université Paul Sabatier, 118, route de Narbonne 31062 Toulouse Cedex 9 (France); Mallet, Charlotte; Frère, Pierre [MOLTECH-Anjou, UMR CNRS 6200, Université d’Angers, 2 Bd Lavoisier 49045 ANGERS Cedex (France); Warot-Fonrose, Bénédicte; Biziere, Nicolas [Université de Toulouse (France); UPS, INSA, INP, ISAE (France); LAAS (France); CEMES, F-31077 Toulouse (France); CNRS, CEMES-CNRS UPR 8011, 29 rue Jeanne Marvig, BP 94347, FR-31055 Toulouse Cedex 4 (France); Bobo, Jean-François, E-mail: jfbobo@cemes.fr [Université de Toulouse (France); UPS, INSA, INP, ISAE (France); LAAS (France); CEMES, F-31077 Toulouse (France); CNRS, CEMES-ONERA, NMH, 2 avenue Edouard Belin, FR-31055 Toulouse Cedex 4 (France)
2014-01-15
In this paper we present spin transport in organic spin-valves using benzofurane bithiophene (BF3) as spacer layer between NiFe and Co ferromagnetic electrodes. The use of an AlO{sub x} buffer layer between the top electrode and the organic layer is discussed in terms of improvements of stacking topology, electrical transport and oxygen contamination of the BF3 layer. A study of magnetic hysteresis cycles evidences spin-valve behaviour. Transport properties are indicative of unshorted devices with non-linear I-V characteristics. Finally we report a magnetoresistance of 3% at 40 K and 10 mV in a sample with a 50 nm thick spacer layer, using an AlO{sub x} buffer layer.
Spin relaxation in disordered media
International Nuclear Information System (INIS)
Dzheparov, F S
2011-01-01
A review is given on theoretical grounds and typical experimental appearances of spin dynamics and relaxation in solids containing randomly distributed nuclear and/or electronic spins. Brief content is as follows. Disordered and magnetically diluted systems. General outlines of the spin transport theory. Random walks in disordered systems (RWDS). Observable values in phase spin relaxation, free induction decay (FID). Interrelation of longitudinal and transversal relaxation related to dynamics of occupancies and phases. Occupation number representation for equations of motion. Continuum media approximation and inapplicability of moment expansions. Long-range transitions vs percolation theory. Concentration expansion as a general constructive basis for analytical methods. Scaling properties of propagators. Singular point. Dynamical and kinematical memory in RWDS. Ways of regrouping of concentration expansions. CTRW and semi-phenomenology. Coherent medium approximation for nuclear relaxation via paramagnetic impurities. Combining of memory functions and cumulant expansions for calculation of FID. Path integral representations for RWDS. Numerical simulations of RWDS. Spin dynamics in magnetically diluted systems with low Zeeman and medium low dipole temperatures. Cluster expansions, regularization of dipole interactions and spectral dynamics.
Spin-Spin Cross Relaxation in Single-Molecule Magnets
Wernsdorfer, W.; Bhaduri, S.; Tiron, R.; Hendrickson, D. N.; Christou, G.
2002-10-01
The one-body tunnel picture of single-molecule magnets (SMMs) is not always sufficient to explain the measured tunnel transitions. An improvement to the picture is proposed by including also two-body tunnel transitions such as spin-spin cross relaxation (SSCR) which are mediated by dipolar and weak superexchange interactions between molecules. A Mn4 SMM is used as a model system. At certain external fields, SSCRs lead to additional quantum resonances which show up in hysteresis loop measurements as well-defined steps. A simple model is used to explain quantitatively all observed transitions.
Energy Technology Data Exchange (ETDEWEB)
Ebisawa, T.; Tasaki, S.; Kawai, T.; Akiyoshi, T. [Kyoto Univ., Kumatori, Osaka (Japan). Research Reactor Inst.; Achiwa, N.; Hino, M.; Otake, Y.; Funahashi, H.
1996-08-01
The authors have developed cold neutron optics and interferometry using multilayer mirrors. The advantages of the multilayer mirrors are their applicability to long wavelength neutrons and a great variety of the mirror performance. The idea of the present spin interferometry is based on nonmagnetic neutron spin quantum precession using multilayer spin splitters. The equation for polarized neutrons means that the polarized neutrons are equivalent to the coherent superposition of two parallel spin eigenstates. The structure and principle of a multilayer spin splitter are explained, and the nonmagnetic gap layer of the multilayer spin splitter gives rise to neutron spin quantum precession. The performance test of the multilayer spin splitter were made with a new spin interferometer, which is analogous optically to a spin echo system with vertical precession field. The spin interferometers were installed at Kyoto University research reactor and the JRR-3. The testing method and the results are reported. The performance tests on a new phase-spin echo interferometer are described, and its applications to the development of a high resolution spin echo system and a Jamin type cold neutron interferometer are proposed. (K.I.)
International Nuclear Information System (INIS)
Anon.
1995-01-01
energies of 1.2, 2.5 et 3.6 GeV, underline that spin effects decrease with energy and tend to zero in agreement with the prediction of a nonpertubative quantum chromodynamics (QCD) model, where the strong fluctuations of vacuum gluon fields (instantons) provide the main contribution. The rapid vanishing of neutron-proton difference, observed for the first time, suggests that the prediction is valid for both isospin 0 and 1 states. It will be interesting to take measurements using a transversely polarized beam and target, where different behaviour is expected. With the polarizing solenoid shipped to Mainz for another experiment, the JINR setup needs a new solenoid and superconducting coils for transverse target polarization. Construction has begun in Dubna and Kharkov, respectively. Additional INTAS financial support will be requested
Quantum correlation properties in Matrix Product States of finite-number spin rings
Zhu, Jing-Min; He, Qi-Kai
2018-02-01
The organization and structure of quantum correlation (QC) of quantum spin-chains are very rich and complex. Hence the depiction and measures about the QC of finite-number spin rings deserved to be investigated intensively by using Matrix Product States(MPSs) in addition to the case with infinite-number. Here the dependencies of the geometric quantum discord(GQD) of two spin blocks on the total spin number, the spacing spin number and the environment parameter are presented in detail. We also compare the GQD with the total correlation(TC) and the classical correlation(CC) and illustrate its characteristics. Predictably, our findings may provide the potential of designing the optimal QC experimental detection proposals and pave the way for the designation of optimal quantum information processing schemes.
QCD SPIN PHYSICS IN HADRONIC INTERACTIONS.
Energy Technology Data Exchange (ETDEWEB)
VOGELSANG,W.
2007-06-19
We discuss spin phenomena in high-energy hadronic scattering, with a particular emphasis on the spin physics program now underway at the first polarized proton-proton collider, RHIC. Experiments at RHIC unravel the spin structure of the nucleon in new ways. Prime goals are to determine the contribution of gluon spins to the proton spin, to elucidate the flavor structure of quark and antiquark polarizations in the nucleon, and to help clarify the origin of transverse-spin phenomena in QCD. These lectures describe some aspects of this program and of the associated physics.
DEFF Research Database (Denmark)
Clausen, Kurt Nørgaard; Lebech, Bente
1980-01-01
Spin wave excitations in a single crystal of Ho2Co17 have been studied at 4.8 and 78 K. The results are discussed in terms of a linear spin wave model. At 78 K both ground state and excited state spin waves are observed.......Spin wave excitations in a single crystal of Ho2Co17 have been studied at 4.8 and 78 K. The results are discussed in terms of a linear spin wave model. At 78 K both ground state and excited state spin waves are observed....
Tunable doping of a metal with molecular spins
Gang, T.; Yilmaz, M. Deniz; Ataç, D.; Bose, S. K.; Strambini, E.; Velders, A. H.; de Jong, M. P.; Huskens, J.; van der Wiel, W. G.
2012-04-01
The mutual interaction of localized magnetic moments and their interplay with itinerant conduction electrons in a solid are central to many phenomena in condensed-matter physics, including magnetic ordering and related many-body phenomena such as the Kondo effect, the Ruderman-Kittel-Kasuya-Yoshida interaction and carrier-induced ferromagnetism in diluted magnetic semiconductors. The strength and relative importance of these spin phenomena are determined by the magnitude and sign of the exchange interaction between the localized magnetic moments and also by the mean distance between them. Detailed studies of such systems require the ability to tune the mean distance between the localized magnetic moments, which is equivalent to being able to control the concentration of magnetic impurities in the host material. Here, we present a method for doping a gold film with localized magnetic moments that involves depositing a monolayer of a metal terpyridine complex onto the film. The metal ions in the complexes can be cobalt or zinc, and the concentration of magnetic impurities in the gold film can be controlled by varying the relative amounts of cobalt complexes (which carry a spin) and zinc complexes (which have zero spin). Kondo and weak localization measurements demonstrate that the magnetic impurity concentration can be systematically varied up to ~800 ppm without any sign of inter-impurity interaction. Moreover, we find no evidence for the unwanted clustering that is often produced when using alternative methods.
Spin qubits in antidot lattices
DEFF Research Database (Denmark)
Pedersen, Jesper Goor; Flindt, Christian; Mortensen, Niels Asger
2008-01-01
We suggest and study designed defects in an otherwise periodic potential modulation of a two-dimensional electron gas as an alternative approach to electron spin based quantum information processing in the solid-state using conventional gate-defined quantum dots. We calculate the band structure a...... electron transport between distant defect states in the lattice, and for a tunnel coupling of neighboring defect states with corresponding electrostatically controllable exchange coupling between different electron spins.......We suggest and study designed defects in an otherwise periodic potential modulation of a two-dimensional electron gas as an alternative approach to electron spin based quantum information processing in the solid-state using conventional gate-defined quantum dots. We calculate the band structure...
Next generation spin torque memories
Kaushik, Brajesh Kumar; Kulkarni, Anant Aravind; Prajapati, Sanjay
2017-01-01
This book offers detailed insights into spin transfer torque (STT) based devices, circuits and memories. Starting with the basic concepts and device physics, it then addresses advanced STT applications and discusses the outlook for this cutting-edge technology. It also describes the architectures, performance parameters, fabrication, and the prospects of STT based devices. Further, moving from the device to the system perspective it presents a non-volatile computing architecture composed of STT based magneto-resistive and all-spin logic devices and demonstrates that efficient STT based magneto-resistive and all-spin logic devices can turn the dream of instant on/off non-volatile computing into reality.
International Nuclear Information System (INIS)
Walker, P.; Dracoulis, G.
1994-01-01
The reaction pathways in stars, where all the heavy elements in the Universe were formed, are inextricably linked with isomers that live long enough to capture a neutron or proton before they decay. These isomers usually have excitation energies below 0.1 MeV. It is also possible to find highly excited isomers, with several MeV of excitation energy, that are trapped because of their large angular momentum (or spin). But attempts to understand the long-lived highly excited isomers, sometimes known as ''spin traps'', have been hampered by the difficulty of producing this exotic form of nuclear matter. Now, a new generation of radioactive ion beams promises a revolution in the study of high-spin nuclear traps. (author)
Spin structures in antiferromagnetic nanoparticles
DEFF Research Database (Denmark)
Brok, Erik
a detailed knowledge of it can be important for applications of antiferromagnetic nanoparticles for example combined with ferromagnetic nanoparticles in nanocomposite devices. In this thesis the magnetic structure, in particular the orientation of the spins in the antiferromagnetic sublattices......, proposed to explain the unusual magnetic properties of the mineral. In summary the thesis have demonstrated methods for investigation of spin structures in magnetic nanoparticles. In particular, the classical model of the temperature dependence of canted spin structures sucessfully explains many...... experimental observations of anomalous temperature dependence in nanoparticle and bulk systems. Morover, XY Z neutron polarisation analysis have been demonstrated to be an effective way of investigating the magnetic properties of antiferromagnetic nanoparticles, significantly improving the unpolarised neutron...
Extrinsic spin Hall effect in graphene
Rappoport, Tatiana
The intrinsic spin-orbit coupling in graphene is extremely weak, making it a promising spin conductor for spintronic devices. In addition, many applications also require the generation of spin currents in graphene. Theoretical predictions and recent experimental results suggest one can engineer the spin Hall effect in graphene by greatly enhancing the spin-orbit coupling in the vicinity of an impurity. The extrinsic spin Hall effect then results from the spin-dependent skew scattering of electrons by impurities in the presence of spin-orbit interaction. This effect can be used to efficiently convert charge currents into spin-polarized currents. I will discuss recent experimental results on spin Hall effect in graphene decorated with adatoms and metallic cluster and show that a large spin Hall effect can appear due to skew scattering. While this spin-orbit coupling is small if compared with what it is found in metals, the effect is strongly enhanced in the presence of resonant scattering, giving rise to robust spin Hall angles. I will present our single impurity scattering calculations done with exact partial-wave expansions and complement the analysis with numerical results from a novel real-space implementation of the Kubo formalism for tight-binding Hamiltonians. The author acknowledges the Brazilian agencies CNPq, CAPES, FAPERJ and INCT de Nanoestruturas de Carbono for financial support.
COMMISSIONING SPIN ROTATORS IN RHIC
International Nuclear Information System (INIS)
MACKAY, W.W.; AHRENS, L.; BAI, M.; COURANT, E.D.; FISCHER, W.; HUANG, H.; LUCCIO, A.; MONTAG, C.; PILAT, F.; PTITSYN, V.; ROSER, T.; SATOGATA, T.; TRBOJEVIC, D.; VANZIEJTS, J.
2003-01-01
During the summer of 2002, eight superconducting helical spin rotators were installed into RHIC in order to control the polarization directions independently at the STAR and PHENIX experiments. Without the rotators, the orientation of polarization at the interaction points would only be vertical. With four rotators around each of the two experiments, we can rotate either or both beams from vertical into the horizontal plane through the interaction region and then back to vertical on the other side. This allows independent control for each beam with vertical, longitudinal, or radial polarization at the experiment. In this paper, we present results from the first run using the new spin rotators at PHENIX
Stigloher, J.; Decker, M.; Körner, H. S.; Tanabe, K.; Moriyama, T.; Taniguchi, T.; Hata, H.; Madami, M.; Gubbiotti, G.; Kobayashi, K.; Ono, T.; Back, C. H.
2016-07-01
We report the experimental observation of Snell's law for magnetostatic spin waves in thin ferromagnetic Permalloy films by imaging incident, refracted, and reflected waves. We use a thickness step as the interface between two media with different dispersion relations. Since the dispersion relation for magnetostatic waves in thin ferromagnetic films is anisotropic, deviations from the isotropic Snell's law known in optics are observed for incidence angles larger than 25 ° with respect to the interface normal between the two magnetic media. Furthermore, we can show that the thickness step modifies the wavelength and the amplitude of the incident waves. Our findings open up a new way of spin wave steering for magnonic applications.
Harmony of spinning conformal blocks
Energy Technology Data Exchange (ETDEWEB)
Schomerus, Volker [DESY Hamburg, Theory Group,Notkestraße 85, 22607 Hamburg (Germany); Sobko, Evgeny [Nordita and Stockholm University,Roslagstullsbacken 23, SE-106 91 Stockholm (Sweden); Isachenkov, Mikhail [Department of Particle Physics and Astrophysics, Weizmann Institute of Science,Rehovot 7610001 (Israel)
2017-03-15
Conformal blocks for correlation functions of tensor operators play an increasingly important role for the conformal bootstrap programme. We develop a universal approach to such spinning blocks through the harmonic analysis of certain bundles over a coset of the conformal group. The resulting Casimir equations are given by a matrix version of the Calogero-Sutherland Hamiltonian that describes the scattering of interacting spinning particles in a 1-dimensional external potential. The approach is illustrated in several examples including fermionic seed blocks in 3D CFT where they take a very simple form.
Harmony of spinning conformal blocks
Energy Technology Data Exchange (ETDEWEB)
Schomerus, Volker [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). Theory Group; Sobko, Evgeny [Stockholm Univ. (Sweden); Nordita, Stockholm (Sweden); Isachenkov, Mikhail [Weizmann Institute of Science, Rehovoth (Israel). Dept. of Particle Physics and Astrophysics
2016-12-07
Conformal blocks for correlation functions of tensor operators play an increasingly important role for the conformal bootstrap programme. We develop a universal approach to such spinning blocks through the harmonic analysis of certain bundles over a coset of the conformal group. The resulting Casimir equations are given by a matrix version of the Calogero-Sutherland Hamiltonian that describes the scattering of interacting spinning particles in a 1-dimensional external potential. The approach is illustrated in several examples including fermionic seed blocks in 3D CFT where they take a very simple form.
International Nuclear Information System (INIS)
Close, F.E.
1994-01-01
When the new data on polarised lepton nucleon scattering are compared at the same value of Q 2 and with a common set of assumptions, a consistent picture of the spin content of the nucleon begins to emerge. Higher order effects in 0(α s ), higher twist effects, modern data on unpolarized structure functions and an updated value for F/D are all important in analysing the data. The detailed x dependences of the polarisation asymmetry in the valence quark region are shown to confirm 20 year old predictions of the quark model and I argue that these are an important ingredient in decoding the nucleon spin puzzle. (author)
Spin tunnelling in mesoscopic systems
Garg, Anupam
2001-02-01
We study spin tunnelling in molecular magnets as an instance of a mesoscopic phenomenon, with special emphasis on the molecule Fe8. We show that the tunnel splitting between various pairs of Zeeman levels in this molecule oscillates as a function of applied magnetic field, vanishing completely at special points in the space of magnetic fields, known as diabolical points. This phenomena is explained in terms of two approaches, one based on spin-coherent-state path integrals, and the other on a generalization of the phase integral (or WKB) method to difference equations. Explicit formulas for the diabolical points are obtained for a model Hamiltonian.
International Nuclear Information System (INIS)
Close, F.E.
1993-06-01
When the new data on polarised lepton nucleon scattering are compared at the same value of Q 2 and with a common set of assumptions, a consistent picture of the spin content of the nucleon begins to emerge. Higher order effects in O(α s ), higher twist effects, modern data on unpolarised structure functions and an updated value for F/D are all important in analysing the data. The detailed x dependences of the polarisation asymmetry in the valence quark region are shown to confirm 20 year old predictions of the quark model and I argue that these are an important ingredient in decoding the nucleon spin puzzle. (author)
Spin interferometry in anisotropic spin-orbit fields
Saarikoski, Henri; Reynoso, Andres A.; Baltanás, José Pablo; Frustaglia, Diego; Nitta, Junsaku
2018-03-01
Electron spins in a two-dimensional electron gas can be manipulated by spin-orbit (SO) fields originating from either Rashba or Dresselhaus interactions with independent isotropic characteristics. Together, though, they produce anisotropic SO fields with consequences on quantum transport through spin interference. Here we study the transport properties of modeled mesoscopic rings subject to Rashba and Dresselhaus [001] SO couplings in the presence of an additional in-plane Zeeman field acting as a probe. By means of one- and two-dimensional quantum transport simulations we show that this setting presents anisotropies in the quantum resistance as a function of the Zeeman field direction. Moreover, the anisotropic resistance can be tuned by the Rashba strength up to the point to invert its response to the Zeeman field. We also find that a topological transition in the field texture that is associated with a geometric phase switching is imprinted in the anisotropy pattern. We conclude that resistance anisotropy measurements can reveal signatures of SO textures and geometric phases in spin carriers.
Spatiotemporal dynamics of the spin transition in [Fe (HB(tz)3) 2] single crystals
Ridier, Karl; Rat, Sylvain; Shepherd, Helena J.; Salmon, Lionel; Nicolazzi, William; Molnár, Gábor; Bousseksou, Azzedine
2017-10-01
The spatiotemporal dynamics of the spin transition have been thoroughly investigated in single crystals of the mononuclear spin-crossover (SCO) complex [Fe (HB (tz )3)2] (tz = 1 ,2 ,4-triazol-1-yl) by optical microscopy. This compound exhibits an abrupt spin transition centered at 334 K with a narrow thermal hysteresis loop of ˜1 K (first-order transition). Most single crystals of this compound reveal exceptional resilience upon repeated switching (several hundred cycles), which allowed repeatable and quantitative measurements of the spatiotemporal dynamics of the nucleation and growth processes to be carried out. These experiments revealed remarkable properties of the thermally induced spin transition: high stability of the thermal hysteresis loop, unprecedented large velocities of the macroscopic low-spin/high-spin phase boundaries up to 500 µm/s, and no visible dependency on the temperature scan rate. We have also studied the dynamics of the low-spin → high-spin transition induced by a local photothermal excitation generated by a spatially localized (Ø = 2 μ m ) continuous laser beam. Interesting phenomena have been evidenced both in quasistatic and dynamic conditions (e.g., threshold effects and long incubation periods, thermal activation of the phase boundary propagation, stabilization of the crystal in a stationary biphasic state, and thermal cutoff frequency). These measurements demonstrated the importance of thermal effects in the transition dynamics, and they enabled an accurate determination of the thermal properties of the SCO compound in the framework of a simple theoretical model.
Current-induced spin-orbit torques in ferromagnetic and antiferromagnetic systems
Manchon, Aurelien
2018-01-29
Spin-orbit coupling in inversion-asymmetric magnetic crystals and structures has emerged as a powerful tool to generate complex magnetic textures, interconvert charge and spin under applied current, and control magnetization dynamics. Current-induced spin-orbit torques mediate the transfer of angular momentum from the lattice to the spin system, leading to sustained magnetic oscillations or switching of ferromagnetic as well as antiferromagnetic structures. The manipulation of magnetic order, domain walls and skyrmions by spin-orbit torques provides evidence of the microscopic interactions between charge and spin in a variety of materials and opens novel strategies to design spintronic devices with potentially high impact in data storage, nonvolatile logic, and magnonic applications. This paper reviews recent progress in the field of spin-orbitronics, focusing on theoretical models, material properties, and experimental results obtained on bulk noncentrosymmetric conductors and multilayer heterostructures, including metals, semiconductors, and topological insulator systems. Relevant aspects for improving the understanding and optimizing the efficiency of nonequilibrium spin-orbit phenomena in future nanoscale devices are also discussed.
A Low Spin Manganese(IV) Nitride Single Molecule Magnet.
Ding, Mei; Cutsail, George E; Aravena, Daniel; Amoza, Martín; Rouzières, Mathieu; Dechambenoit, Pierre; Losovyj, Yaroslav; Pink, Maren; Ruiz, Eliseo; Clérac, Rodolphe; Smith, Jeremy M
2016-09-01
Structural, spectroscopic and magnetic methods have been used to characterize the tris(carbene)borate compound PhB(MesIm) 3 Mn≡N as a four-coordinate manganese(IV) complex with a low spin ( S = 1/2) configuration. The slow relaxation of the magnetization in this complex, i.e. its single-molecule magnet (SMM) properties, is revealed under an applied dc field. Multireference quantum mechanical calculations indicate that this SMM behavior originates from an anisotropic ground doublet stabilized by spin-orbit coupling. Consistent theoretical and experiment data show that the resulting magnetization dynamics in this system is dominated by ground state quantum tunneling, while its temperature dependence is influenced by Raman relaxation.
Polarized hyperons probe dynamics of quark spin
International Nuclear Information System (INIS)
Daniel S. Carman; T. S. Harry Lee; Mac Mestayer; Reinhard Schumacher
2007-01-01
Researchers at Jefferson Laboratory demonstrate how two analyses of the same data provide two plausible models of spin transfer in exclusive hyperon production, yielding quite different pictures of quark spin dynamics and challenging existing theories
Proton polarimeters for spin transfer experiments
International Nuclear Information System (INIS)
McNaughton, M.W.
1985-01-01
The design and use of proton polarimeters for spin transfer (Wolfenstein parameter) measurements is discussed. Polarimeters are compared with polarized targets for spin dependent experiments. 32 refs., 4 figs
Spin diffusion and torques in disordered antiferromagnets
Manchon, Aurelien
2017-02-01
We have developed a drift-diffusion equation of spin transport in collinear bipartite metallic antiferromagnets. Starting from a model tight-binding Hamiltonian, we obtain the quantum kinetic equation within Keldysh formalism and expand it to the lowest order in spatial gradient using Wigner expansion method. In the diffusive limit, these equations track the spatio-temporal evolution of the spin accumulations and spin currents on each sublattice of the antiferromagnet. We use these equations to address the nature of the spin transfer torque in (i) a spin-valve composed of a ferromagnet and an antiferromagnet, (ii) a metallic bilayer consisting of an antiferromagnet adjacent to a heavy metal possessing spin Hall effect, and in (iii) a single antiferromagnet possessing spin Hall effect. We show that the latter can experience a self-torque thanks to the non-vanishing spin Hall effect in the antiferromagnet.
Suppression of quantum tunneling for all spins for easy-axis systems
International Nuclear Information System (INIS)
Khare, Avinash; Paranjape, M. B.
2011-01-01
The semiclassical limit of quantum spin systems corresponds to a dynamical Lagrangian which contains the usual kinetic energy, the couplings and interactions of the spins, and an additional, first-order kinematical term which corresponds to the Wess-Zumino-Novikov-Witten (WZNW) term for the spin degree of freedom. It was shown that in the case of the kinetic dynamics determined only by the WZNW term, half-odd integer spin systems show a lack of tunneling phenomena, whereas integer spin systems are subject to it in the case of potentials with easy-plane easy-axis symmetry. Here we prove for the theory with a normal quadratic kinetic term of arbitrary strength or the first-order theory with azimuthal symmetry (which is equivalently the so-called easy-axis situation), that the tunneling is in fact suppressed for all nonzero values of spin. This model exemplifies the concept that in the presence of complex Euclidean action, it is necessary to use the ensuing complex critical points in order to define the quantum (perturbation) theory. In the present example, if we do not do so, exactly the opposite, erroneous conclusion that the tunneling is unsuppressed for all spins, is reached.
Central Limit Theorem for Exponentially Quasi-local Statistics of Spin Models on Cayley Graphs
Reddy, Tulasi Ram; Vadlamani, Sreekar; Yogeshwaran, D.
2018-04-01
Central limit theorems for linear statistics of lattice random fields (including spin models) are usually proven under suitable mixing conditions or quasi-associativity. Many interesting examples of spin models do not satisfy mixing conditions, and on the other hand, it does not seem easy to show central limit theorem for local statistics via quasi-associativity. In this work, we prove general central limit theorems for local statistics and exponentially quasi-local statistics of spin models on discrete Cayley graphs with polynomial growth. Further, we supplement these results by proving similar central limit theorems for random fields on discrete Cayley graphs taking values in a countable space, but under the stronger assumptions of α -mixing (for local statistics) and exponential α -mixing (for exponentially quasi-local statistics). All our central limit theorems assume a suitable variance lower bound like many others in the literature. We illustrate our general central limit theorem with specific examples of lattice spin models and statistics arising in computational topology, statistical physics and random networks. Examples of clustering spin models include quasi-associated spin models with fast decaying covariances like the off-critical Ising model, level sets of Gaussian random fields with fast decaying covariances like the massive Gaussian free field and determinantal point processes with fast decaying kernels. Examples of local statistics include intrinsic volumes, face counts, component counts of random cubical complexes while exponentially quasi-local statistics include nearest neighbour distances in spin models and Betti numbers of sub-critical random cubical complexes.
Energy Technology Data Exchange (ETDEWEB)
Farberovich, Oleg V. [School of Physics and Astronomy, Beverly and Raymond Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978 (Israel); Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation); Voronezh State University, Voronezh 394000 (Russian Federation); Mazalova, Victoria L., E-mail: mazalova@sfedu.ru [Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation); Soldatov, Alexander V. [Research Center for Nanoscale Structure of Matter, Southern Federal University, Zorge 5, 344090 Rostov-on-Don (Russian Federation)
2015-11-15
pattern with the anisotropic exchange models conventionally used for the analysis of this system and, with the results of the experimental XANES spectra, shows that our complex investigations provide a good description of the pattern of the spin levels and the spin structures of the nanomagnetic Ni{sub 7} qubit. The results are discussed in the view of the general problem of the solid-state spin qubits and the spin structure of the Ni cluster. - Highlights: • We present the model of the quantum solid-state qubit. • We have studied the Rabi oscillations and the electron spin decoherence. • The quantum entanglement is important for a quantum computation. • We have analyzed a behavior of the entanglement in the finite clusters.
Spin transport and relaxation in graphene
International Nuclear Information System (INIS)
Han Wei; McCreary, K.M.; Pi, K.; Wang, W.H.; Li Yan; Wen, H.; Chen, J.R.; Kawakami, R.K.
2012-01-01
We review our recent work on spin injection, transport and relaxation in graphene. The spin injection and transport in single layer graphene (SLG) were investigated using nonlocal magnetoresistance (MR) measurements. Spin injection was performed using either transparent contacts (Co/SLG) or tunneling contacts (Co/MgO/SLG). With tunneling contacts, the nonlocal MR was increased by a factor of ∼1000 and the spin injection/detection efficiency was greatly enhanced from ∼1% (transparent contacts) to ∼30%. Spin relaxation was investigated on graphene spin valves using nonlocal Hanle measurements. For transparent contacts, the spin lifetime was in the range of 50-100 ps. The effects of surface chemical doping showed that for spin lifetimes in the order of 100 ps, charged impurity scattering (Au) was not the dominant mechanism for spin relaxation. While using tunneling contacts to suppress the contact-induced spin relaxation, we observed the spin lifetimes as long as 771 ps at room temperature, 1.2 ns at 4 K in SLG, and 6.2 ns at 20 K in bilayer graphene (BLG). Furthermore, contrasting spin relaxation behaviors were observed in SLG and BLG. We found that Elliot-Yafet spin relaxation dominated in SLG at low temperatures whereas Dyakonov-Perel spin relaxation dominated in BLG at low temperatures. Gate tunable spin transport was studied using the SLG property of gate tunable conductivity and incorporating different types of contacts (transparent and tunneling contacts). Consistent with theoretical predictions, the nonlocal MR was proportional to the SLG conductivity for transparent contacts and varied inversely with the SLG conductivity for tunneling contacts. Finally, bipolar spin transport in SLG was studied and an electron-hole asymmetry was observed for SLG spin valves with transparent contacts, in which nonlocal MR was roughly independent of DC bias current for electrons, but varied significantly with DC bias current for holes. These results are very important for
Relationship between the complex susceptibility and the plasma dispersion function
International Nuclear Information System (INIS)
Jimenez D, H.; Cabral P, A.
1991-04-01
It is shown that when magnetization processes in a spin system and resonant excitation of spin n states occur in the presence of internal and or external random line-broadening mechanisms, the complex magnetic susceptibility of the plasma dispersion function. letter could be useful spin in system is proportional to the relationship found in this spectroscopies such as EPR and NMR, for example, as its fitting to experimental absorption and dispersion profiles produces their Lorentzian and Gaussian contents. (Author)
Relationship between the complex susceptibility and the plasma dispersion function
Energy Technology Data Exchange (ETDEWEB)
Jimenez D, H.; Cabral P, A
1991-04-15
It is shown that when magnetization processes in a spin system and resonant excitation of spin n states occur in the presence of internal and or external random line-broadening mechanisms, the complex magnetic susceptibility of the plasma dispersion function. letter could be useful spin in system is proportional to the relationship found in this spectroscopies such as EPR and NMR, for example, as its fitting to experimental absorption and dispersion profiles produces their Lorentzian and Gaussian contents. (Author)
Magnus effects on spinning transonic missiles
Seginer, A.; Rosenwasser, I.
1983-01-01
Magnus forces and moments were measured on a basic-finner model spinning in transonic flow. Spin was induced by canted fins or by full-span or semi-span, outboard and inboard roll controls. Magnus force and moment reversals were caused by Mach number, reduced spin rate, and angle of attack variations. Magnus center of pressure was found to be independent of the angle of attack but varied with the Mach number and model configuration or reduced spin rate.
Electron Spin Dynamics in Semiconductor Quantum Dots
International Nuclear Information System (INIS)
Marie, X.; Belhadj, T.; Urbaszek, B.; Amand, T.; Krebs, O.; Lemaitre, A.; Voisin, P.
2011-01-01
An electron spin confined to a semiconductor quantum dot is not subject to the classical spin relaxation mechanisms known for free carriers but it strongly interacts with the nuclear spin system via the hyperfine interaction. We show in time resolved photoluminescence spectroscopy experiments on ensembles of self assembled InAs quantum dots in GaAs that this interaction leads to strong electron spin dephasing.
The chirality operators for Heisenberg spin systems
International Nuclear Information System (INIS)
Subrahmanyam, V.
1994-01-01
The ground state of closed Heisenberg spin chains with an odd number of sites has a chiral degeneracy, in addition to a two-fold Kramers degeneracy. A non-zero chirality implies that the spins are not coplanar, and is a measure of handedness. The chirality operator, which can be treated as a spin-1/2 operator, is explicitly constructed in terms of the spin operators, and is given as commutator of permutation operators. (author). 3 refs
Deformed Fredkin spin chain with extensive entanglement
Salberger, Olof; Udagawa, Takuma; Zhang, Zhao; Katsura, Hosho; Klich, Israel; Korepin, Vladimir
2017-06-01
We introduce a new spin chain which is a deformation of the Fredkin spin chain and has a phase transition between bounded and extensive entanglement entropy scaling. In this chain, spins have a local interaction of three nearest neighbors. The Hamiltonian is frustration-free and its ground state can be described analytically as a weighted superposition of Dyck paths that depends on a deformation parameter t. In the purely spin 1/2 case, whenever t\
Spin-polarized light-emitting diodes based on organic bipolar spin valves
Energy Technology Data Exchange (ETDEWEB)
Vardeny, Zeev Valentine; Nguyen, Tho Duc; Ehrenfreund, Eitan Avraham
2017-10-25
Spin-polarized organic light-emitting diodes are provided. Such spin-polarized organic light-emitting diodes incorporate ferromagnetic electrodes and show considerable spin-valve magneto-electroluminescence and magneto-conductivity responses, with voltage and temperature dependencies that originate from the bipolar spin-polarized space charge limited current.
Spin Transport in Nondegenerate Si with a Spin MOSFET Structure at Room Temperature
Sasaki, Tomoyuki; Ando, Yuichiro; Kameno, Makoto; Tahara, Takayuki; Koike, Hayato; Oikawa, Tohru; Suzuki, Toshio; Shiraishi, Masashi
2014-09-01
Spin transport in nondegenerate semiconductors is expected to pave the way to the creation of spin transistors, spin logic devices, and reconfigurable logic circuits, because room-temperature (RT) spin transport in Si has already been achieved. However, RT spin transport has been limited to degenerate Si, which makes it difficult to produce spin-based signals because a gate electric field cannot be used to manipulate such signals. Here, we report the experimental demonstration of spin transport in nondegenerate Si with a spin metal-oxide-semiconductor field-effect transistor (MOSFET) structure. We successfully observe the modulation of the Hanle-type spin-precession signals, which is a characteristic spin dynamics in nondegenerate semiconductors. We obtain long spin transport of more than 20 μm and spin rotation greater than 4π at RT. We also observe gate-induced modulation of spin-transport signals at RT. The modulation of the spin diffusion length as a function of a gate voltage is successfully observed, which we attribute to the Elliott-Yafet spin relaxation mechanism. These achievements are expected to lead to the creation of practical Si-based spin MOSFETs.
Gate-tunable black phosphorus spin valve with nanosecond spin lifetimes
Avsar, Ahmet; Tan, Jun Y.; Kurpas, Marcin; Gmitra, Martin; Watanabe, Kenji; Taniguchi, Takashi; Fabian, Jaroslav; Özyilmaz, Barbaros
2017-09-01
Two-dimensional materials offer new opportunities for both fundamental science and technological applications, by exploiting the electron's spin. Although graphene is very promising for spin communication due to its extraordinary electron mobility, the lack of a bandgap restricts its prospects for semiconducting spin devices such as spin diodes and bipolar spin transistors. The recent emergence of two-dimensional semiconductors could help overcome this basic challenge. In this letter we report an important step towards making two-dimensional semiconductor spin devices. We have fabricated a spin valve based on ultrathin (~5 nm) semiconducting black phosphorus (bP), and established fundamental spin properties of this spin channel material, which supports all electrical spin injection, transport, precession and detection up to room temperature. In the non-local spin valve geometry we measure Hanle spin precession and observe spin relaxation times as high as 4 ns, with spin relaxation lengths exceeding 6 μm. Our experimental results are in a very good agreement with first-principles calculations and demonstrate that the Elliott-Yafet spin relaxation mechanism is dominant. We also show that spin transport in ultrathin bP depends strongly on the charge carrier concentration, and can be manipulated by the electric field effect.
Detection and Control of Individual Nuclear Spins Using a Weakly Coupled Electron Spin
Taminiau, T.H.; Wagenaar, J.J.T.; Van der Sar, T.; Jelezko, F.; Dobrovitski, V.V.; Hanson, R.
2012-01-01
We experimentally isolate, characterize, and coherently control up to six individual nuclear spins that are weakly coupled to an electron spin in diamond. Our method employs multipulse sequences on the electron spin that resonantly amplify the interaction with a selected nuclear spin and at the same
Spin transfer and spin pumping in disordered normal metal-antiferromagnetic insulator systems
Gulbrandsen, Sverre A.; Brataas, Arne
2018-02-01
We consider an antiferromagnetic insulator that is in contact with a metal. Spin accumulation in the metal can induce spin-transfer torques on the staggered field and on the magnetization in the antiferromagnet. These torques relate to spin pumping: the emission of spin currents into the metal by a precessing antiferromagnet. We investigate how the various components of the spin-transfer torque are affected by spin-independent disorder and spin-flip scattering in the metal. Spin-conserving disorder reduces the coupling between the spins in the antiferromagnet and the itinerant spins in the metal in a manner similar to Ohm's law. Spin-flip scattering leads to spin-memory loss with a reduced spin-transfer torque. We discuss the concept of a staggered spin current and argue that it is not a conserved quantity. Away from the interface, the staggered spin current varies around a 0 mean in an irregular manner. A network model explains the rapid decay of the staggered spin current.
Adiabatic analysis of collisions. III. Remarks on the spin model
International Nuclear Information System (INIS)
Fano, U.
1979-01-01
Analysis of a spin-rotation model illustrates how transitions between adiabatic channel states stem from the second, rather than from the first, rate of change of these states, provided that appropriate identification of channels and scaling of the independent variable are used. These remarks, like the earlier development of a post-adiabatic approach, aim at elucidating the surprising success of approximate separation of variables in the treatment of complex mechanical systems
Spin State as a Marker for the Structural Evolution of Nature's Water-Splitting Catalyst.
Krewald, Vera; Retegan, Marius; Neese, Frank; Lubitz, Wolfgang; Pantazis, Dimitrios A; Cox, Nicholas
2016-01-19
In transition-metal complexes, the geometric structure is intimately connected with the spin state arising from magnetic coupling between the paramagnetic ions. The tetramanganese-calcium cofactor that catalyzes biological water oxidation in photosystem II cycles through five catalytic intermediates, each of which adopts a specific geometric and electronic structure and is thus characterized by a specific spin state. Here, we review spin-structure correlations in Nature's water-splitting catalyst. The catalytic cycle of the Mn4O5Ca cofactor can be described in terms of spin-dependent reactivity. The lower "inactive" S states of the catalyst, S0 and S1, are characterized by low-spin ground states, SGS = 1/2 and SGS = 0. This is connected to the "open cubane" topology of the inorganic core in these states. The S2 state exhibits structural and spin heterogeneity in the form of two interconvertible isomers and is identified as the spin-switching point of the catalytic cycle. The first S2 state form is an open cubane structure with a low-spin SGS = 1/2 ground state, whereas the other represents the first appearance of a closed cubane topology in the catalytic cycle that is associated with a higher-spin ground state of SGS = 5/2. It is only this higher-spin form of the S2 state that progresses to the "activated" S3 state of the catalyst. The structure of this final metastable catalytic state was resolved in a recent report, showing that all manganese ions are six-coordinate. The magnetic coupling is dominantly ferromagnetic, leading to a high-spin ground state of SGS = 3. The ability of the Mn4O5Ca cofactor to adopt two distinct structural and spin-state forms in the S2 state is critical for water binding in the S3 state, allowing spin-state crossing from the inactive, low-spin configuration of the catalyst to the activated, high-spin configuration. Here we describe how an understanding of the magnetic properties of the catalyst in all S states has allowed conclusions on
Energy Technology Data Exchange (ETDEWEB)
Switzner, Nathan; Henry, Dick
2009-03-20
In a second development order, spin-forming equipment was again evaluated using the test shape, a hemispherical shell. In this second development order, pure vanadium and alloy titanium (Ti-6Al-4V) were spin-formed, as well as additional copper and 21-6-9 stainless. In the first development order the following materials had been spin-formed: copper (alloy C11000 ETP), 6061 aluminum, 304L stainless steel, 21-6-9 stainless steel, and tantalum-2.5% tungsten. Significant challenges included properly adjusting the rotations-per-minute (RPM), cracking at un-beveled edges and laser marks, redressing of notches, surface cracking, non-uniform temperature evolution in the titanium, and cracking of the tailstock. Lessons learned were that 300 RPM worked better than 600 RPM for most materials (at the feed rate of 800 mm/min); beveling the edges to lower the stress reduces edge cracking; notches, laser marks, or edge defects in the preform doom the process to cracking and failure; coolant is required for vanadium spin-forming; increasing the number of passes to nine or more eliminates surface cracking for vanadium; titanium develops a hot zone in front of the rollers; and the tailstock should be redesigned to eliminate the cylindrical stress concentrator in the center.
Superselective pseudocontinuous arterial spin labeling
Helle, M.; Norris, D.G.; Rufer, S.; Alfke, K.; Jansen, O.; van Osch, M.J.
2010-01-01
A new technique for the imaging of flow territories of individual extra- and intracranial arteries is presented. The method is based on balanced pseudocontinuous arterial spin labeling but employs additional time-varying gradients in between the radiofrequency pulses of the long labeling train. The
Spin squeezing and quantum correlations
Indian Academy of Sciences (India)
Spin squeezing and quantum correlations. K S MALLESH1, SWARNAMALA SIRSI2, MAHMOUD A A SBAIH1, P N DEEPAK1 and G RAMACHANDRAN3. 1Department of Studies in Physics, University of Mysore, Mysore 570 006, India. 2 Department of Physics, Yuvaraja's College, University of Mysore, Mysore 570 005, ...
Indian Academy of Sciences (India)
The mechanism for the generation of high angular momentum states in the restricted va- lence space around ... The generation of higher spin states re- .... Channel Number. 1. Counts. 0. 200. 400. 600. Channel Number. 1. Counts multiplicity. 0cp. 1cp. 2cp. 3cp. 4cp. 5cp. 0a. 1a. 2a. Charged particle. 6cp. Alpha multiplicity. −.
Algebraic topology of spin glasses
International Nuclear Information System (INIS)
Koma, Tohru
2011-01-01
We study the topology of frustration in d-dimensional Ising spin glasses with d ≥ 2 with nearest-neighbor interactions. We prove the following. For any given spin configuration, the domain walls on the unfrustration network are all transverse to a frustrated loop on the unfrustration network, where a domain wall is defined to be a connected element of the collection of all the (d - 1)-cells which are dual to the bonds having an unfavorable energy, and the unfrustration network is the collection of all the unfrustrated plaquettes. These domain walls are topologically nontrivial because they are all related to the global frustration of a loop on the unfrustration network. Taking account of the thermal stability for the domain walls, we can explain the numerical results that three- or higher-dimensional systems exhibit a spin glass phase, whereas two-dimensional ones do not. Namely, in two dimensions, the thermal fluctuations of the topologically nontrivial domain walls destroy the order of the frozen spins on the unfrustration network, whereas they do not in three or higher dimensions. This may be interpreted as a global topological effect of the frustrations.
Spinning targets for laser fusion
International Nuclear Information System (INIS)
Baldwin, D.E.; Ryutov, D.D.
1995-09-01
Several techniques for spinning the ICF targets up prior to or in the course of their compression are suggested. Interference of the rotational shear flow with Rayleigh-Taylor instability is briefly discussed and possible consequences for the target performance are pointed out
Indian Academy of Sciences (India)
2001-07-31
Jul 31, 2001 ... c Indian Academy of Sciences. Vol. 57, No. 1. — journal of. July 2001 physics pp. 175–179. High spin spectroscopy of. 139. Pr. S CHANDA. ½. , SARMISHTHA BHATTACHARYYA. ¾. , TUMPA BHATTACHARJEE .... which is configured under LINUX platform. Around 90 x10 two and higher fold events were ...
Le Goff, J M
2000-01-01
The Spin Muon Collaboration at CERN has covered a wide range of spin physics. The main aim of the collaboration was the measurement of the $g_{1}$ spin structure functions of the proton and the neutron (using deuteron targets) in the range $0.003
Spin tunnelling in mesoscopic systems
Indian Academy of Sciences (India)
We study spin tunnelling in molecular magnets as an instance of a mesoscopic phenomenon, with special emphasis on the molecule Fe8. We show that the tunnel splitting between various pairs of Zeeman levels in this molecule oscillates as a function of applied magnetic ﬁeld, vanishing completely at special points in the ...
Spinning pipe gas lens revisited
CSIR Research Space (South Africa)
Mafusire, C
2008-01-01
Full Text Available , there is little information on optical phase aberrations and no study to date on the propagation parameters of the laser beam, but has rather remained rooted in the domain of ray optics. Researchers revisit the spinning pipe gas lens in this paper with new...
Spin determination of fission resonances
International Nuclear Information System (INIS)
Keyworth, G.A.
1976-01-01
The present status of available information on the channel quantum numbers for resonance fission and the most urgently needed additional experiments are examined. The role of spin in the 235 U + n system is emphasized. The discussion relies heavily on recent alignment measurements and polarization results
Mass and spin of double dual solutions in Poincare gauge theory
International Nuclear Information System (INIS)
Mielke, E.W.; Wallner, R.P.
1988-01-01
Mass and spin are derived for a class of exact solutions of the Poincare gauge (PG) theory of gravity, provided the curvature fulfills a modified double-duality ansatz. It is executed a (3+1)-decomposition and clarified and semplified the structure of the energy-momentum and spin complexes. In case the quadratic PG Lagrangian contains the curvature-square pieces in the Yang-Mills fashion, the (3+1)-decomposition provides rather detailed information on admissible solutions. The PG energy-momentum complex turns out to be intimately related to the von Freud complex of general relativity
High energy spin isospin modes in nuclei
International Nuclear Information System (INIS)
Chanfray, G.; Ericson, M.
1984-01-01
The high energy response of nuclei to a spin-isospin excitation is investigated. We show the existence of a strong contrast between the spin transverse and spin longitudinal responses. The second one undergoes a shadow effect in the Δ region and displays the occurrence of the pionic branch
Recent advances of spin crossover research
Gutlich, P; van Koningsbruggen, PJ; Renz, F; Schonherr, T
2004-01-01
Thermal spin transition (spin crossover), one of the most fascinating dynamic electronic structure phenomena occurring in coordination compounds of third row transition metal ions, mostly of iron(II), iron(III) and cobalt(II) with critical ligand field strengths competing with the spin pairing
Simple classical approach to spin resonance phenomena
DEFF Research Database (Denmark)
Gordon, R A
1977-01-01
A simple classical method of describing spin resonance in terms of the average power absorbed by a spin system is discussed. The method has several advantages over more conventional treatments, and a number of important spin resonance phenomena, not normally considered at the introductory level...
Overview of longitudinal spin physics at PHENIX
International Nuclear Information System (INIS)
Liu, Mingxiong
2007-01-01
We present a brief overview of the longitudinal spin physics program in the PHENIX experiment at the Relativistic Heavy Ion Collider at BNL. The main goal is to study the longitudinal spin structure of the proton with strongly interacting probes at high energy to resolve the long standing 'spin crisis'. The latest results from PHENIX are presented. (author)
Geometry of Spin: Clifford Algebraic Approach
Indian Academy of Sciences (India)
of Pauli matrices follow from the underlying algebra. Clif- ford algebraic approach provides a geometrical and hence intuitive way to understand quantum theory of spin, and is a natural formalism to study spin. Clifford algebraic formal- ism has lot of applications in every field where spin plays an important role. Introduction.
Study of squeezing in spin clusters
International Nuclear Information System (INIS)
Reboiro, M.; Civitarese, O.; Rebon, L.
2007-01-01
The conditions under which spin squeezing occurs in an asymmetric chain of spins are discussed. The time evolution of the system is calculated for different initial conditions. The effects of the use of spin coherent states to model the initial condition are analyzed
Spin-glass transition in disordered terbium
International Nuclear Information System (INIS)
Hauser, J.J.
1985-01-01
While crystalline Tb is a helix antiferromagnet with a Neel temperature of 229 K which becomes ferromagnetic at 222 K, disordered Tb exhibits a spin-glass transition. The spin-glass freezing temperature ranges from 183 to 53 K, the lowest temperatures corresponding to the greatest degree of atomic disorder. These experiments constitute the first evidence for an elemental spin-glass. (author)
Geometry of Spin: Clifford Algebraic Approach
Indian Academy of Sciences (India)
... all the propertiesof Pauli matrices follow from the underlying algebra. Cliffordalgebraic approach provides a geometrical and henceintuitive way to understand quantum theory of spin, and isa natural formalism to study spin. Clifford algebraic formalismhas lot of applications in every field where spin plays animportant role.
Muon spin rotation and other microscopic probes of spin-glass dynamics
International Nuclear Information System (INIS)
MacLaughlin, D.E.
1980-01-01
A number of different microscopic probe techniques have been employed to investigate the onset of the spin-glass state in dilute magnetic alloys. Among these are Moessbauer-effect spectroscopy, neutron scattering, ESR of the impurity spins, host NMR and, most recently, muon spin rotation and depolarization. Spin probes yield information on the microscopic static and dynamic behavior of the impurity spins, and give insight into both the spin freezing process and the nature of low-lying excitations in the ordered state. Microscopic probe experiments in spin glasses are surveyed, and the unique advantages of muon studies are emphasized
Electrical detection of spin current and spin relaxation in nonmagnetic semiconductors
International Nuclear Information System (INIS)
Miah, M Idrish
2008-01-01
We report an electrical method for the detection of spin current and spin relaxation in nonmagnetic semiconductors. Optically polarized spins are dragged by an electric field in GaAs. We use the anomalous Hall effect for the detection of spin current and spin relaxation. It is found that the effect depends on the electric field and doping density as well as on temperature, but not on the excitation power. A calculation for the effect is performed using the measured spin polarization by a pump-probe experiment. The results are also discussed in comparison with a quantitative evaluation of the spin lifetimes of the photogenerated electrons under drift in GaAs
Electrical detection of spin current and spin relaxation in nonmagnetic semiconductors
Energy Technology Data Exchange (ETDEWEB)
Miah, M Idrish [Nanoscale Science and Technology Centre and School of Biomolecular and Physical Sciences, Griffith University, Nathan, Brisbane, QLD 4111 (Australia); Department of Physics, University of Chittagong, Chittagong 4331 (Bangladesh)], E-mail: m.miah@griffith.edu.au
2008-09-21
We report an electrical method for the detection of spin current and spin relaxation in nonmagnetic semiconductors. Optically polarized spins are dragged by an electric field in GaAs. We use the anomalous Hall effect for the detection of spin current and spin relaxation. It is found that the effect depends on the electric field and doping density as well as on temperature, but not on the excitation power. A calculation for the effect is performed using the measured spin polarization by a pump-probe experiment. The results are also discussed in comparison with a quantitative evaluation of the spin lifetimes of the photogenerated electrons under drift in GaAs.
Inverse spin Hall effect induced by spin pumping into semiconducting ZnO
Energy Technology Data Exchange (ETDEWEB)
Lee, Jung-Chuan [Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Huang, Leng-Wei [Graduate Institute of Applied Physics, National Chengchi University, Taipei 11605, Taiwan (China); Hung, Dung-Shing, E-mail: dshung@mail.mcu.edu.tw [Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Department of Information and Telecommunications Engineering, Ming Chuan University, Taipei 111, Taiwan (China); Chiang, Tung-Han [Department of Physics, National Cheng Kung University, Tainan 70101, Taiwan (China); Huang, J. C. A., E-mail: jcahuang@mail.ncku.edu.tw [Department of Physics, National Cheng Kung University, Tainan 70101, Taiwan (China); Advanced Optoelectronic Technology Center, National Cheng Kung University, Tainan 70101, Taiwan (China); Liang, Jun-Zhi [Advanced Optoelectronic Technology Center, National Cheng Kung University, Tainan 70101, Taiwan (China); Department of Physics, Fu Jen Catholic University, Taipei 242, Taiwan (China); Lee, Shang-Fan, E-mail: leesf@phys.sinica.edu.tw [Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Graduate Institute of Applied Physics, National Chengchi University, Taipei 11605, Taiwan (China)
2014-02-03
The inverse spin Hall effect (ISHE) of n-type semiconductor ZnO thin films with weak spin-orbit coupling has been observed by utilizing the spin pumping method. In the ferromagnetic resonance condition, the spin pumping driven by the dynamical exchange interaction of a permalloy film injects a pure spin current into the adjacent ZnO layer. This spin current gives rise to a DC voltage through the ISHE in the ZnO layer, and the DC voltage is proportional to the microwave excitation power. The effect is sizeable even when the spin backflow is considered.
Inverse spin Hall effect induced by spin pumping into semiconducting ZnO
International Nuclear Information System (INIS)
Lee, Jung-Chuan; Huang, Leng-Wei; Hung, Dung-Shing; Chiang, Tung-Han; Huang, J. C. A.; Liang, Jun-Zhi; Lee, Shang-Fan
2014-01-01
The inverse spin Hall effect (ISHE) of n-type semiconductor ZnO thin films with weak spin-orbit coupling has been observed by utilizing the spin pumping method. In the ferromagnetic resonance condition, the spin pumping driven by the dynamical exchange interaction of a permalloy film injects a pure spin current into the adjacent ZnO layer. This spin current gives rise to a DC voltage through the ISHE in the ZnO layer, and the DC voltage is proportional to the microwave excitation power. The effect is sizeable even when the spin backflow is considered
Mariette, Céline; Trzop, Elzbieta; Zerdane, Serhane; Fertey, Pierre; Zhang, Daopeng; Valverde-Muñoz, Francisco J; Real, José Antonio; Collet, Eric
2017-08-01
The complex relaxation from the photoinduced high-spin phase (PIHS) to the low-spin phase of the bimetallic two-dimensional coordination spin-crossover polymer [Fe[(Hg(SCN) 3 ) 2 ](4,4'-bipy) 2 ] n is reported. During the thermal relaxation, commensurate and incommensurate spin-state concentration waves (SSCWs) form. However, contrary to the steps forming at thermal equilibrium, associated with long-range SSCW order, the SSCWs forming during the relaxation from the PIHS phase correspond to short-range order, revealed by diffuse X-ray scattering. This is interpreted as resulting from the competition between the two types of SSCW order and another structural symmetry breaking, due to ligand ordering, occurring at low temperature and precluding long-range SSCW order.
Spinning Reserve From Responsive Loads
Energy Technology Data Exchange (ETDEWEB)
Kirby, B.J.
2003-04-08
Responsive load is the most underutilized reliability resource available to the power system today. It is currently not used at all to provide spinning reserve. Historically there were good reasons for this, but recent technological advances in communications and controls have provided new capabilities and eliminated many of the old obstacles. North American Electric Reliability Council (NERC), Federal Energy Regulatory Commission (FERC), Northeast Power Coordinating Council (NPCC), New York State Reliability Council (NYSRC), and New York Independent System Operator (NYISO) rules are beginning to recognize these changes and are starting to encourage responsive load provision of reliability services. The Carrier ComfortChoice responsive thermostats provide an example of these technological advances. This is a technology aimed at reducing summer peak demand through central control of residential and small commercial air-conditioning loads. It is being utilized by Long Island Power Authority (LIPA), Consolidated Edison (ConEd), Southern California Edison (SCE), and San Diego Gas and Electric (SDG&E). The technology is capable of delivering even greater response in the faster spinning reserve time frame (while still providing peak reduction). Analysis of demand reduction testing results from LIPA during the summer of 2002 provides evidence to back up this claim. It also demonstrates that loads are different from generators and that the conventional wisdom, which advocates for starting with large loads as better ancillary service providers, is flawed. The tempting approach of incrementally adapting ancillary service requirements, which were established when generators were the only available resources, will not work. While it is easier for most generators to provide replacement power and non-spinning reserve (the slower response services) than it is to supply spinning reserve (the fastest service), the opposite is true for many loads. Also, there is more financial
Directory of Open Access Journals (Sweden)
A. Gover
2006-06-01
Full Text Available The problems of spin-polarized free-electron beam interaction with electromagnetic wave at electron-spin resonance conditions in a magnetic field and of superradiant spin-flip radiative emission are analyzed in the framework of a comprehensive classical model. The spontaneous emission of spin-flip radiation from electron beams is very weak. We show that the detectivity of electron spin resonant spin-flip and combined spin-flip/cyclotron-resonance-emission radiation can be substantially enhanced by operating with ultrashort spin-polarized electron beam bunches under conditions of superradiant (coherent emission. The proposed radiative spin-state modulation and the spin-flip radiative emission schemes can be used for control and noninvasive diagnostics of polarized electron/positron beams. Such schemes are of relevance in important scattering experiments off nucleons in nuclear physics and off magnetic targets in condensed matter physics.
Quantum spin liquid and spin ice states in new pyrochlores
Sibille, Romain
Magnetic systems with competing interactions can adopt exotic ground states. A particularly promising class is that of the geometrically frustrated magnets, such as the A2B2O7 pyrochlores, in which unusual spin liquids appear. Some of these phases feature short-range correlated states analogous to a Coulomb phase and give rise to emergent quasiparticle excitations. Although cases like the classical spin ice are reasonably well understood, the theoretical expectation is that quantum fluctuations lead to novel phases which are quantum spin liquids (QSLs). For instance, the quantum spin ice (QSI) is a generalization of the classical spin ice state to include quantum fluctuations, such that the effective theory becomes emergent quantum electrodynamics - the classical monopoles become coherent quantum quasiparticles, and a novel excitation playing the role of the photon appears. In this talk, I will present results on three novel materials with potential for QSL states. Each of them corresponds to a way to potentially strengthen the role of quantum fluctuations on the ground state properties of pyrochlore magnets. Firstly, I will demonstrate that, in Tb2Hf2O7, where a sizeable gap isolates the non-Kramers ground state doublet at low temperature, a large amount of anion Frenkel disorder leads to quenched random crystal fields and disordered magnetic interactions. The detailed study of this material demonstrates that disorder can play a crucial role in preventing long-range magnetic order at low temperatures, and instead induces a strongly-fluctuating Coulomb spin liquid with defect-induced frozen magnetic degrees of freedom. Secondly, I will present results on another QSL candidate based on non-Kramers ions, Pr2Hf2O7, which displays striking characteristics of the ferromagnetic correlations expected in a QSI. Finally, in the pyrochlore Ce2Sn2O7, where macroscopic measurements suggest an antiferromagnetic liquid ground state with quantum fluctuations, I will present
Electron-Spin Filters Would Offer Spin Polarization Greater than 1
Ting, David Z.
2009-01-01
A proposal has been made to develop devices that would generate spin-polarized electron currents characterized by polarization ratios having magnitudes in excess of 1. Heretofore, such devices (denoted, variously, as spin injectors, spin polarizers, and spin filters) have typically offered polarization ratios having magnitudes in the approximate range of 0.01 to 0.1. The proposed devices could be useful as efficient sources of spin-polarized electron currents for research on spintronics and development of practical spintronic devices.
International Nuclear Information System (INIS)
Levi, Michele; Steinhoff, Jan
2016-01-01
The next-to-next-to-leading order spin-squared interaction potential for generic compact binaries is derived for the first time via the effective field theory for gravitating spinning objects in the post-Newtonian scheme. The spin-squared sector is an intricate one, as it requires the consideration of the point particle action beyond minimal coupling, and mainly involves the spin-squared worldline couplings, which are quite complex, compared to the worldline couplings from the minimal coupling part of the action. This sector also involves the linear in spin couplings, as we go up in the nonlinearity of the interaction, and in the loop order. Hence, there is an excessive increase in the number of Feynman diagrams, of which more are higher loop ones. We provide all the Feynman diagrams and their values. The beneficial ''nonrelativistic gravitational'' fields are employed in the computation. This spin-squared correction, which enters at the fourth post-Newtonian order for rapidly rotating compact objects, completes the conservative sector up to the fourth post-Newtonian accuracy. The robustness of the effective field theory for gravitating spinning objects is shown here once again, as demonstrated in a recent series of papers by the authors, which obtained all spin dependent sectors, required up to the fourth post-Newtonian accuracy. The effective field theory of spinning objects allows to directly obtain the equations of motion, and the Hamiltonians, and these will be derived for the potential obtained here in a forthcoming paper
Nonlinear spin current generation in noncentrosymmetric spin-orbit coupled systems
Hamamoto, Keita; Ezawa, Motohiko; Kim, Kun Woo; Morimoto, Takahiro; Nagaosa, Naoto
2017-06-01
Spin current plays a central role in spintronics. In particular, finding more efficient ways to generate spin current has been an important issue and has been studied actively. For example, representative methods of spin-current generation include spin-polarized current injections from ferromagnetic metals, the spin Hall effect, and the spin battery. Here, we theoretically propose a mechanism of spin-current generation based on nonlinear phenomena. By using Boltzmann transport theory, we show that a simple application of the electric field E induces spin current proportional to E2 in noncentrosymmetric spin-orbit coupled systems. We demonstrate that the nonlinear spin current of the proposed mechanism is supported in the surface state of three-dimensional topological insulators and two-dimensional semiconductors with the Rashba and/or Dresselhaus interaction. In the latter case, the angular dependence of the nonlinear spin current can be manipulated by the direction of the electric field and by the ratio of the Rashba and Dresselhaus interactions. We find that the magnitude of the spin current largely exceeds those in the previous methods for a reasonable magnitude of the electric field. Furthermore, we show that application of ac electric fields (e.g., terahertz light) leads to the rectifying effect of the spin current, where dc spin current is generated. These findings will pave a route to manipulate the spin current in noncentrosymmetric crystals.
Dramatically Enhanced Spin Dynamo with Plasmonic Diabolo Cavity.
Gou, Peng; Qian, Jie; Xi, Fuchun; Zou, Yuexin; Cao, Jun; Yu, Haochi; Zhao, Ziyi; Yang, Le; Xu, Jie; Wang, Hengliang; Zhang, Lijian; An, Zhenghua
2017-07-13
The applications of spin dynamos, which could potentially power complex nanoscopic devices, have so far been limited owing to their extremely low energy conversion efficiencies. Here, we present a unique plasmonic diabolo cavity (PDC) that dramatically improves the spin rectification signal (enhancement of more than three orders of magnitude) under microwave excitation; further, it enables an energy conversion efficiency of up to ~0.69 mV/mW, compared with ~0.27 μV/mW without a PDC. This remarkable improvement arises from the simultaneous enhancement of the microwave electric field (~13-fold) and the magnetic field (~195-fold), which cooperate in the spin precession process generates photovoltage (PV) efficiently under ferromagnetic resonance (FMR) conditions. The interplay of the microwave electromagnetic resonance and the ferromagnetic resonance originates from a hybridized mode based on the plasmonic resonance of the diabolo structure and Fabry-Perot-like modes in the PDC. Our work sheds light on how more efficient spin dynamo devices for practical applications could be realized and paves the way for future studies utilizing both artificial and natural magnetism for applications in many disciplines, such as for the design of future efficient wireless energy conversion devices, high frequent resonant spintronic devices, and magnonic metamaterials.
2-vertex Lorentzian spin foam amplitudes for dipole transitions
Sarno, Giorgio; Speziale, Simone; Stagno, Gabriele V.
2018-04-01
We compute transition amplitudes between two spin networks with dipole graphs, using the Lorentzian EPRL model with up to two (non-simplicial) vertices. We find power-law decreasing amplitudes in the large spin limit, decreasing faster as the complexity of the foam increases. There are no oscillations nor asymptotic Regge actions at the order considered, nonetheless the amplitudes still induce non-trivial correlations. Spin correlations between the two dipoles appear only when one internal face is present in the foam. We compute them within a mini-superspace description, finding positive correlations, decreasing in value with the Immirzi parameter. The paper also provides an explicit guide to computing Lorentzian amplitudes using the factorisation property of SL(2,C) Clebsch-Gordan coefficients in terms of SU(2) ones. We discuss some of the difficulties of non-simplicial foams, and provide a specific criterion to partially limit the proliferation of diagrams. We systematically compare the results with the simplified EPRLs model, much faster to evaluate, to learn evidence on when it provides reliable approximations of the full amplitudes. Finally, we comment on implications of our results for the physics of non-simplicial spin foams and their resummation.
Field theory of the spinning electron: I - Internal motions
International Nuclear Information System (INIS)
Salesi, Giovanni; Recami, Erasmo; Universidade Estadual de Campinas, SP
1994-05-01
One of the most satisfactory picture of spinning particles is the Barut-Zanghi (BZ) classical theory for the relativistic electron, that relates the electron spin with the so-called Zitterbewegung (zbw). The BZ theory has been recently studied in the Lagrangian and Hamiltonian symplectic formulations, both in flat and in curved space-time. The BZ motion equations constituted the starting point for two recent works about spin and electron structure, co-authored by us, which adopted the Clifford algebra formalism. In this letter, by employing on the contrary the ordinary tensorial language, we first write down a meaningful (real) equation of motion, describing particle classical paths, quite different from the corresponding (complex) equation of the standard Dirac theory. As a consequence, we succeed in regarding the electron as an extended-type object with a classically intelligible structure (thus overcoming some long-standing, well-known problems). Second, we make explicit the kinematical properties of the 4-velocity field v μ , which also result to be quite different from the ordinary ones, valid for scalar particles. At last, we analyze the inner zbw motions, both time-like and light-like, as functions of the initial conditions (in particular, for the case of classical uniform motions, the z component of spin s is shown to be quantized). In so doing, we make explicit the strict correlation existing between electron polarization and zbw kinematics. (author). 9 refs
Field theory of the spinning electron: I - Internal motions
Energy Technology Data Exchange (ETDEWEB)
Salesi, Giovanni [Universita Statale di Catania (Italy). Dipt. di Fisica; Recami, Erasmo [Universita Statale di Bergamo, Dalmine, BG (Italy). Facolta di Ingegneria]|[Universidade Estadual de Campinas, SP (Brazil). Dept. de Matematica Aplicada
1994-05-01
One of the most satisfactory picture of spinning particles is the Barut-Zanghi (BZ) classical theory for the relativistic electron, that relates the electron spin with the so-called Zitterbewegung (zbw). The BZ theory has been recently studied in the Lagrangian and Hamiltonian symplectic formulations, both in flat and in curved space-time. The BZ motion equations constituted the starting point for two recent works about spin and electron structure, co-authored by us, which adopted the Clifford algebra formalism. In this letter, by employing on the contrary the ordinary tensorial language, we first write down a meaningful (real) equation of motion, describing particle classical paths, quite different from the corresponding (complex) equation of the standard Dirac theory. As a consequence, we succeed in regarding the electron as an extended-type object with a classically intelligible structure (thus overcoming some long-standing, well-known problems). Second, we make explicit the kinematical properties of the 4-velocity field v{sup {mu}}, which also result to be quite different from the ordinary ones, valid for scalar particles. At last, we analyze the inner zbw motions, both time-like and light-like, as functions of the initial conditions (in particular, for the case of classical uniform motions, the z component of spin s is shown to be quantized). In so doing, we make explicit the strict correlation existing between electron polarization and zbw kinematics. (author). 9 refs.
Spin Splitting in Different Semiconductor Quantum Wells
International Nuclear Information System (INIS)
Hao Yafei
2012-01-01
We theoretically investigate the spin splitting in four undoped asymmetric quantum wells in the absence of external electric field and magnetic field. The quantum well geometry dependence of spin splitting is studied with the Rashba and the Dresselhaus spin-orbit coupling included. The results show that the structure of quantum well plays an important role in spin splitting. The Rashba and the Dresselhaus spin splitting in four asymmetric quantum wells are quite different. The origin of the distinction is discussed in this work. (condensed matter: electronic structure, electrical, magnetic, and optical properties)
Theory of the spin Peltier effect
Ohnuma, Y.; Matsuo, M.; Maekawa, S.
2017-10-01
A microscopic theory of the spin Peltier effect in a bilayer structure comprising a paramagnetic metal (PM) and a ferromagnetic insulator (FI) based on the nonequilibrium Green's function method is presented. Spin current and heat current driven by temperature gradient and spin accumulation are formulated as functions of spin susceptibilities in the PM and the FI, and are summarized by Onsager's reciprocal relations. By using the current formulas, we estimate heat generation and absorption at the interface driven by the heat-current injection mediated by spins from PM into FI.
Energy Technology Data Exchange (ETDEWEB)
Leviatan, A. [Racah Institute of Physics, The Hebrew University, Jerusalem 91904, (Israel); Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Institute for Nuclear Theory, University of Washington, Box 351550, Seattle, Washington 98195 (United States); Ginocchio, J. N. [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)
2000-02-01
We use the empirical evidence that F-spin multiplets exist in nuclei for only selected states as an indication that F spin can be regarded as a partial symmetry. We show that there is a class of non-F-scalar IBM-2 Hamiltonians with partial F-spin symmetry, which reproduce the known systematics of collective bands in nuclei. These Hamiltonians predict that the scissors states have good F-spin and form F-spin multiplets, which is supported by the existing data. (c) 2000 The American Physical Society.
International Nuclear Information System (INIS)
Leviatan, A.; Ginocchio, J. N.
2000-01-01
We use the empirical evidence that F-spin multiplets exist in nuclei for only selected states as an indication that F spin can be regarded as a partial symmetry. We show that there is a class of non-F-scalar IBM-2 Hamiltonians with partial F-spin symmetry, which reproduce the known systematics of collective bands in nuclei. These Hamiltonians predict that the scissors states have good F-spin and form F-spin multiplets, which is supported by the existing data. (c) 2000 The American Physical Society
Leviatan, A
2000-01-01
We use the empirical evidence that F-spin multiplets exist in nuclei for only selected states as an indication that F spin can be regarded as a partial symmetry. We show that there is a class of non-F-scalar IBM-2 Hamiltonians with partial F-spin symmetry, which reproduce the known systematics of collective bands in nuclei. These Hamiltonians predict that the scissors states have good F-spin and form F-spin multiplets, which is supported by the existing data. (22 refs).
Enhanced magnetoresistance in lateral spin-valves
Adari, R.; Patil, T.; Murthy, M.; Maheshwari, R.; Vaidya, G.; Ganguly, S.; Saha, D.
2010-09-01
The effect of feature sizes on the characteristics of lateral spintronic devices have been investigated experimentally and theoretically. It is demonstrated that confining spin-transport in the active region of a device enhances magnitude of the spin-dependent response substantially. Numerical simulation of spin-transport corroborates the experimental observations. Device characteristics are found to be a strong function of spin-polarizer and analyzer dimensions. The response is observed to attain a peak value for an optimum device feature size, and this is seen to be a function of temperature. Spin dependent effects become weaker for very small and very large devices.
Spin-Crossing in an Organometallic Pt-Benzene Complex
Czech Academy of Sciences Publication Activity Database
Granatier, Jaroslav; Dubecký, M.; Lazar, P.; Otyepka, M.; Hobza, Pavel
2013-01-01
Roč. 9, č. 3 (2013), s. 1461-1468 ISSN 1549-9618 R&D Projects: GA ČR GBP208/12/G016 Grant - others:GA ČR(CZ) GAP208/10/1742 Program:GA Institutional support: RVO:61388963 Keywords : quantum Monte Carlo * 2nd-order perturbation-theory * density-functional theory * augmented-wave method Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 5.310, year: 2013
Spin-spin correlations of magnetic impurities in graphene
Guclu, A. D.; Bulut, Nejat
2014-01-01
We study the interaction between two magnetic adatom impurities in graphene using the Anderson model. The two-impurity Anderson Hamiltonian is solved numerically by using the quantum Monte Carlo technique. We find that the inter-impurity spin susceptibility is strongly enhanced at low temperatures, significantly diverging from the well-known Ruderman-Kittel-Kasuya-Yoshida (RKKY) result which decays as $R^{-3}$.
Majorana spin in magnetic atomic chain systems
Li, Jian; Jeon, Sangjun; Xie, Yonglong; Yazdani, Ali; Bernevig, B. Andrei
2018-03-01
In this paper, we establish that Majorana zero modes emerging from a topological band structure of a chain of magnetic atoms embedded in a superconductor can be distinguished from trivial localized zero energy states that may accidentally form in this system using spin-resolved measurements. To demonstrate this key Majorana diagnostics, we study the spin composition of magnetic impurity induced in-gap Shiba states in a superconductor using a hybrid model. By examining the spin and spectral densities in the context of the Bogoliubov-de Gennes (BdG) particle-hole symmetry, we derive a sum rule that relates the spin densities of localized Shiba states with those in the normal state without superconductivity. Extending our investigations to a ferromagnetic chain of magnetic impurities, we identify key features of the spin properties of the extended Shiba state bands, as well as those associated with a localized Majorana end mode when the effect of spin-orbit interaction is included. We then formulate a phenomenological theory for the measurement of the local spin densities with spin-polarized scanning tunneling microscopy (STM) techniques. By combining the calculated spin densities and the measurement theory, we show that spin-polarized STM measurements can reveal a sharp contrast in spin polarization between an accidental-zero-energy trivial Shiba state and a Majorana zero mode in a topological superconducting phase in atomic chains. We further confirm our results with numerical simulations that address generic parameter settings.
Quantum Spin Lenses in Atomic Arrays
Directory of Open Access Journals (Sweden)
A. W. Glaetzle
2017-09-01
Full Text Available We propose and discuss quantum spin lenses, where quantum states of delocalized spin excitations in an atomic medium are focused in space in a coherent quantum process down to (essentially single atoms. These can be employed to create controlled interactions in a quantum light-matter interface, where photonic qubits stored in an atomic ensemble are mapped to a quantum register represented by single atoms. We propose Hamiltonians for quantum spin lenses as inhomogeneous spin models on lattices, which can be realized with Rydberg atoms in 1D, 2D, and 3D, and with strings of trapped ions. We discuss both linear and nonlinear quantum spin lenses: in a nonlinear lens, repulsive spin-spin interactions lead to focusing dynamics conditional to the number of spin excitations. This allows the mapping of quantum superpositions of delocalized spin excitations to superpositions of spatial spin patterns, which can be addressed by light fields and manipulated. Finally, we propose multifocal quantum spin lenses as a way to generate and distribute entanglement between distant atoms in an atomic lattice array.
Electronic structures of ruthenium complexes encircling non ...
Indian Academy of Sciences (India)
Electronic structural forms of selected mononuclear and dinuclear ruthenium complexes encompassing redox non-innocent terminal as well as bridging ligands have been addressed. The sensitive valence and spin situations of the complexes have been established in the native and accessible redox states via detailed ...
Thermal imaging of spin Peltier effect
Daimon, Shunsuke; Iguchi, Ryo; Hioki, Tomosato; Saitoh, Eiji; Uchida, Ken-Ichi
2016-12-01
The Peltier effect modulates the temperature of a junction comprising two different conductors in response to charge currents across the junction, which is used in solid-state heat pumps and temperature controllers in electronics. Recently, in spintronics, a spin counterpart of the Peltier effect was observed. The `spin Peltier effect' modulates the temperature of a magnetic junction in response to spin currents. Here we report thermal imaging of the spin Peltier effect; using active thermography technique, we visualize the temperature modulation induced by spin currents injected into a magnetic insulator from an adjacent metal. The thermal images reveal characteristic distribution of spin-current-induced heat sources, resulting in the temperature change confined only in the vicinity of the metal/insulator interface. This finding allows us to estimate the actual magnitude of the temperature modulation induced by the spin Peltier effect, which is more than one order of magnitude greater than previously believed.
Spherical designs and anticoherent spin states
International Nuclear Information System (INIS)
Crann, Jason; Pereira, Rajesh; Kribs, David W
2010-01-01
Anticoherent spin states are quantum states that exhibit maximally nonclassical behaviour in a certain sense. Any spin state whose Majorana representation is a Platonic solid is called a perfect state. By direct calculation, it has been shown that any perfect state is an anticoherent spin state. We show that any spin state whose Majorana representation is both the orbit of a finite subgroup of O(3) and a spherical t-design must be an anticoherent spin state of order t. Since all Platonic solids are spherical designs, this result gives an explanation of the anticoherence of perfect states and explains their observed order. We also show that any spin state whose Majorana representation lies in any single open hemisphere cannot be anticoherent of any order. This result is then used to give further relations between spherical designs and anticoherent spin states. We also pose some questions relating spherical designs and geometric entanglement.
Spin and radiation in intense laser fields
International Nuclear Information System (INIS)
Walser, M.W.; Urbach, D.J.; Hatsagortsyan, K.Z.; Hu, S.X.; Keitel, C.H.
2002-01-01
The spin dynamics and its reaction on the particle motion are investigated for free and bound electrons in intense linearly polarized laser fields. Employing both classical and quantum treatments we analytically evaluate the spin oscillation of free electrons in intense laser fields and indicate the effect of spin-orbit coupling on the motion of the electron. In Mott scattering an estimation for the spin oscillation is derived. In intense laser ion dynamics spin signatures are studied in detail with emphasis on high-order harmonic generation in the tunneling regime. First- and second-order calculations in the ratio of electron velocity and the speed of light show spin signatures in the radiation spectrum and spin-orbit effects in the electron polarization
Charge and spin transport in mesoscopic superconductors
Directory of Open Access Journals (Sweden)
M. J. Wolf
2014-02-01
Full Text Available Background: Non-equilibrium charge transport in superconductors has been investigated intensely in the 1970s and 1980s, mostly in the vicinity of the critical temperature. Much less attention has been paid to low temperatures and the role of the quasiparticle spin.Results: We report here on nonlocal transport in superconductor hybrid structures at very low temperatures. By comparing the nonlocal conductance obtained by using ferromagnetic and normal-metal detectors, we discriminate charge and spin degrees of freedom. We observe spin injection and long-range transport of pure, chargeless spin currents in the regime of large Zeeman splitting. We elucidate charge and spin transport by comparison to theoretical models.Conclusion: The observed long-range chargeless spin transport opens a new path to manipulate and utilize the quasiparticle spin in superconductor nanostructures.
Electrically Driven Spin Dynamics of Paramagnetic Impurities
Saha, D.; Siddiqui, L.; Bhattacharya, P.; Datta, S.; Basu, D.; Holub, M.
2008-05-01
The spin dynamics of dilute paramagnetic impurities embedded in a semiconductor GaAs channel of a conventional lateral spin valve has been investigated. It is observed that the electron spin of paramagnetic Mn atoms can be polarized electrically when driven by a spin valve in the antiparallel configuration. The transient current through the MnAs/GaAs/MnAs spin valve bears the signature of the underlying spin dynamics driven by the exchange interaction between the conduction band electrons in GaAs and the localized Mn electron spins. The time constant for this interaction is observed to be dependent on temperature and is estimated to be 80 ns at 15 K.
Modulation bandwidth of a spin laser
Banerjee, D.; Adari, R.; Murthy, M.; Suggisetti, P.; Ganguly, S.; Saha, D.
2011-04-01
We have studied small signal frequency response of a spin laser. We have shown that the response is characterized by two distinct resonant peaks corresponding to the two polarization modes of the spin laser. It is observed that the modulation bandwidth of a spin laser can be smaller or larger than that of a conventional laser depending upon the current bias and spin relaxation time constant. A small value for spin relaxation constant may not be detrimental for modulation bandwidth. This anomalous observation is explained by considering both the amplitude and phase response of the two polarization modes. A spin laser can act as a combination of low-pass and bandpass filters. The passband frequency range is tunable by external bias. We have also studied the evolution of resonant peaks and modulation bandwidth as a function of spin relaxation time constant.
Prediction for spin Fano factor generated by biased quantum spin chains
Aftergood, Joshua; Takei, So
We theoretically study noise in the spin current injected into a normal metal from a 1D Heisenberg spin- 1 / 2 antiferromagnet. We consider the noise generated in two separate scenarios: first by inducing an over-population of one chiral mode relative to the other in the spin chain at uniform temperature, and second by elevating the temperature of the spin chain relative to the metal, i.e., by way of the spin Seebeck effect. We compute excess noise in the normal metal generated by the coupling to the spin chain and predict the spin Fano factor, defined as the noise in the spin current normalized by the average spin current, for both scenarios. The authors thank the PSC-CUNY Research Award Program for its support.
Spin physics highlights from STAR
Directory of Open Access Journals (Sweden)
Gibson A.
2015-01-01
Full Text Available As the world’s only polarized proton collider, the Relativistic Heavy Ion Collider (RHIC at Brookhaven plays an important role in understanding the spin structure of the proton. The STAR detector, with its large acceptance for calorimetry and tracking, has been used to study polarized proton collisions for more than a decade with a range of jet, meson, and boson probes. We will discuss jets, neutral pions, and W bosons as probes of the proton’s helicity structure. Here STAR measurements have significant impact on global fits of sea quark polarizations and have provided the first firm evidence of non-zero gluon polarization within the proton. We will discuss W/Z bosons, jets, pions, and pion-jet correlations as probes of the transverse spin structure of the proton, and we will use the example of a proposed dijet measurement with an upgraded STAR detector to peer into the future.
Energy Technology Data Exchange (ETDEWEB)
Close, F.E.
1993-06-01
When the new data on polarised lepton nucleon scattering are compared at the same value of Q{sup 2} and with a common set of assumptions, a consistent picture of the spin content of the nucleon begins to emerge. Higher order effects in O({alpha}{sub s}), higher twist effects, modern data on unpolarised structure functions and an updated value for F/D are all important in analysing the data. The detailed x dependences of the polarisation asymmetry in the valence quark region are shown to confirm 20 year old predictions of the quark model and I argue that these are an important ingredient in decoding the nucleon spin puzzle. (author).
Spin chains and string theory.
Kruczenski, Martin
2004-10-15
Recently, an important test of the anti de Sitter/conformal field theory correspondence has been done using rotating strings with two angular momenta. We show that such a test can be described more generally as the agreement between two actions: one a low energy description of a spin chain appearing in the field theory side, and the other a limit of the string action in AdS5xS5. This gives a map between the mean value of the spin in the boundary theory and the position of the string in the bulk, and shows how a string action can emerge from a gauge theory in the large-N limit.
Film edge nonlocal spin valves.
McCallum, Andrew T; Johnson, Mark
2009-06-01
Spintronics is a new paradigm for integrated digital electronics. Recently established as a niche for nonvolatile magnetic random access memory (MRAM), it offers new functionality while demonstrating low-power and high-speed performance. However, to reach high density spintronic technology must make a transition to the nanometer scale. Prototype devices are presently made using a planar geometry and have an area determined by the lithographic feature size, currently about 100 nm. Here we present a new nonplanar geometry in which one lateral dimension is given by a film thickness, on the order of 10 nm. With this new approach, cell sizes can shrink by an order of magnitude. The geometry is demonstrated with a nonlocal spin valve, where we study devices with an injector/detector separation much less than the spin diffusion length.
Nuclear spin polarization of targets
International Nuclear Information System (INIS)
Happer, W.
1990-01-01
Lasers can be used to produce milligrams to grams of noble gas nuclei with spin polarizations in excess of 50%. These quantities are sufficient to be very useful targets in nuclear physics experiments. Alkali-metal atoms are used to capture the angular momentum of circularly polarized laser photons, and the alkali-metal atoms transfer their angular momentum to noble gas atoms in binary or three-body collisions. Non-radiative collisions between the excited alkali atoms and molecular quenching gases are essential to avoid radiation trapping. The spin exchange can involve gas-phase van der Waals molecules, consisting of a noble gas atom and an alkali metal atom. Surface chemistry is also of great importance in determining the wall-induced relaxation rates of the noble gases
Oscillating spin-2 dark matter
Marzola, Luca; Raidal, Martti; Urban, Federico R.
2018-01-01
The negative outcomes of laboratory searches, juxtaposed with cosmological observations, may indicate that dark matter has a gravitational origin. We show that coherent oscillations of a massive spin-2 field emerging from bimetric theory can easily account for the observed dark matter abundance. The framework, based on the only known consistent extension of general relativity to interacting spin-2 fields, is testable in precision measurements of the electric charge variation by means of atomic clocks, molecular systems, dedicated resonant mass detectors, as well as gravity interferometers and axionlike-particle experiments. These searches, therefore, provide a new window into the phenomenology of gravity which complements the results of dedicated tests of gravitation. We also present a multimetric extension of the scenario that straightforwardly implements the clockwork mechanism for gravity, explaining the apparent weakness of this force.
Electromagnetic deflection of spinning particles
International Nuclear Information System (INIS)
Costella, J.P.; McKellar, B.H.J.
1992-01-01
It is shown that it is possible to obtain self-consistent and physically acceptable relativistic classical equations of motion for a point-like spin-half particle possessing an electric charge and magnetic dipole moment, directly from a manifestly covariant Lagrangian, if the classical degrees of freedom are appropriately chosen. The equations obtained encompass the well-tested Lorentz force and Thomas-Bargmann-Michel-Telegdi spin equations, as well as providing a definite specification of the classical magnetic dipole force, whose exact form has been the subject of recent debate. Radiation reaction - the force and torque on an accelerated particle due to its self-interaction - is neglected at this stage. 18 refs
Spin-independent transparency of pure spin current at normal/ferromagnetic metal interface
Hao, Runrun; Zhong, Hai; Kang, Yun; Tian, Yufei; Yan, Shishen; Liu, Guolei; Han, Guangbing; Yu, Shuyun; Mei, Liangmo; Kang, Shishou
2018-03-01
The spin transparency at the normal/ferromagnetic metal (NM/FM) interface was studied in Pt/YIG/Cu/FM multilayers. The spin current generated by the spin Hall effect (SHE) in Pt flows into Cu/FM due to magnetic insulator YIG blocking charge current and transmitting spin current via the magnon current. Therefore, the nonlocal voltage induced by an inverse spin Hall effect (ISHE) in FM can be detected. With the magnetization of FM parallel or antiparallel to the spin polarization of pure spin currents ({{\\boldsymbol{σ }}}sc}), the spin-independent nonlocal voltage is induced. This indicates that the spin transparency at the Cu/FM interface is spin-independent, which demonstrates that the influence of spin-dependent electrochemical potential due to spin accumulation on the interfacial spin transparency is negligible. Furthermore, a larger spin Hall angle of Fe20Ni80 (Py) than that of Ni is obtained from the nonlocal voltage measurements. Project supported by the National Basic Research Program of China (Grant No. 2015CB921502), the National Natural Science Foundation of China (Grant Nos. 11474184 and 11627805), the 111 Project, China (Grant No. B13029), and the Fundamental Research Funds of Shandong University, China.
Spin precession and spin Hall effect in monolayer graphene/Pt nanostructures
Savero Torres, W.; Sierra, J. F.; Benítez, L. A.; Bonell, F.; Costache, M. V.; Valenzuela, S. O.
2017-12-01
Spin Hall effects have surged as promising phenomena for spin logics operations without ferromagnets. However, the magnitude of the detected electric signals at room temperature in metallic systems has been so far underwhelming. Here, we demonstrate a two-order of magnitude enhancement of the signal in monolayer graphene/Pt devices when compared to their fully metallic counterparts. The enhancement stems in part from efficient spin injection and the large spin resistance of graphene but we also observe 100% spin absorption in Pt and find an unusually large effective spin Hall angle of up to 0.15. The large spin-to-charge conversion allows us to characterise spin precession in graphene under the presence of a magnetic field. Furthermore, by developing an analytical model based on the 1D diffusive spin-transport, we demonstrate that the effective spin-relaxation time in graphene can be accurately determined using the (inverse) spin Hall effect as a means of detection. This is a necessary step to gather full understanding of the consequences of spin absorption in spin Hall devices, which is known to suppress effective spin lifetimes in both metallic and graphene systems.
Computational mechanics of classical spin systems
Feldman, David Polant
How does nature self-organize and how can scientists discover such organization? Is there an objective notion of pattern, or is the discovery of patterns a purely subjective process? And what mathematical vocabulary is appropriate for describing and quantifying pattern, structure, and organization? This dissertation compares and contrasts the way in which statistical mechanics, information theory, and computational mechanics address these questions. After an in-depth review of the statistical mechanical, information theoretic, and computational mechanical approaches to structure and pattern, I present exact analytic results for the excess entropy and ɛ- machines for one-dimensional, finite-range discrete classical spin systems. The excess entropy, a form of mutual information, is an information theoretic measure of apparent spatial memory. The ɛ-machine-the central object of computational mechanics-is defined as the minimal model capable of statistically reproducing a given configuration, where the model is chosen to belong to the least powerful model class(es) in a stochastic generalization of the discrete computation hierarchy. These results for one-dimensional spin systems demonstrate that the measures of pattern from information theory and computational mechanics differ from known thermodynamic and statistical mechanical functions. Moreover, they capture important structural features that are otherwise missed. In particular, the excess entropy serves to detect ordered, low entropy density patterns. It is superior in many respects to other functions used to probe the structure of a distribution, such as structure factors and the specific heat. More generally, ɛ-machines are seen to be the most direct approach to revealing the group and semigroup symmetries possessed by the spatial patterns and to estimating the minimum amount of memory required to reproduce the configuration ensemble, a quantity known as the statistical complexity. It is shown that the
Indian Academy of Sciences (India)
September 2000 physics pp.L471–L478. High spin states in. 63. Cu. B MUKHERJEE. ½,¾. , S MURALITHAR. ½. , R P SINGH. ½. , R KUMAR. ½. , K RANI. ½. ,. S C PANCHOLI. ¿ and R K BHOWMIK. ½. ½. Nuclear Science Centre, P.B. No. 10502, New Delhi 110 067, India. 2. Jawaharlal Nehru University, New Delhi 110 ...
Spin dynamics of bilayer manganites
Indian Academy of Sciences (India)
gations to understand the microscopic mechanism of this phenomenon. Together .... La1.2Sr1.8Mn2O7 optic acoustic. Figure 2. Q scans along [1 0 0] at T = 1.6. K for different constant energy transfers through the reciprocal point Q = (1, 0, 1) ... The optic spin-wave energy gap directly gives the intra-bilayer exchange inter-.