WorldWideScience

Sample records for spatially resolved study

  1. A Spatially Resolved Study of the GRB 020903 Host Galaxy

    Science.gov (United States)

    Thorp, Mallory D.; Levesque, Emily M.

    2018-03-01

    GRB 020903 is a long-duration gamma-ray burst with a host galaxy close enough and extended enough for spatially resolved observations, making it one of less than a dozen GRBs where such host studies are possible. GRB 020903 lies in a galaxy host complex that appears to consist of four interacting components. Here we present the results of spatially resolved spectroscopic observations of the GRB 020903 host. By taking observations at two different position angles, we were able to obtain optical spectra (3600–9000 Å) of multiple regions in the galaxy. We confirm redshifts for three regions of the host galaxy that match that of GRB 020903. We measure the metallicity of these regions, and find that the explosion site and the nearby star-forming regions both have comparable subsolar metallicities. We conclude that, in agreement with past spatially resolved studies of GRBs, the GRB explosion site is representative of the host galaxy as a whole rather than localized in a metal-poor region of the galaxy.

  2. Spatially Resolved Artificial Chemistry

    DEFF Research Database (Denmark)

    Fellermann, Harold

    2009-01-01

    Although spatial structures can play a crucial role in chemical systems and can drastically alter the outcome of reactions, the traditional framework of artificial chemistry is a well-stirred tank reactor with no spatial representation in mind. Advanced method development in physical chemistry has...... made a class of models accessible to the realms of artificial chemistry that represent reacting molecules in a coarse-grained fashion in continuous space. This chapter introduces the mathematical models of Brownian dynamics (BD) and dissipative particle dynamics (DPD) for molecular motion and reaction...

  3. Spatially Resolved Artificial Chemistry

    DEFF Research Database (Denmark)

    Fellermann, Harold

    2009-01-01

    made a class of models accessible to the realms of artificial chemistry that represent reacting molecules in a coarse-grained fashion in continuous space. This chapter introduces the mathematical models of Brownian dynamics (BD) and dissipative particle dynamics (DPD) for molecular motion and reaction......Although spatial structures can play a crucial role in chemical systems and can drastically alter the outcome of reactions, the traditional framework of artificial chemistry is a well-stirred tank reactor with no spatial representation in mind. Advanced method development in physical chemistry has...

  4. A spatially resolved radio spectral index study of the dwarf irregular galaxy NGC 1569

    Science.gov (United States)

    Westcott, Jonathan; Brinks, Elias; Hindson, Luke; Beswick, Robert; Heesen, Volker

    2018-04-01

    We study the resolved radio continuum spectral energy distribution of the dwarf irregular galaxy, NGC 1569, on a beam-by-beam basis to isolate and study its spatially resolved radio emission characteristics. Utilizing high-quality NRAO Karl G. Jansky Very Large Array observations that densely sample the 1-34 GHz frequency range, we adopt a Bayesian fitting procedure, where we use H α emission that has not been corrected for extinction as a prior, to produce maps of how the separated thermal emission, non-thermal emission, and non-thermal spectral index vary across NGC 1569's main disc. We find a higher thermal fraction at 1 GHz than is found in spiral galaxies (26^{+2}_{-3} {per cent}) and find an average non-thermal spectral index α = -0.53 ± 0.02, suggesting that a young population of cosmic ray electrons is responsible for the observed non-thermal emission. By comparing our recovered map of the thermal radio emission with literature H α maps, we estimate the total reddening along the line of sight to NGC 1569 to be E(B - V) = 0.49 ± 0.05, which is in good agreement with other literature measurements. Spatial variations in the reddening indicate that a significant portion of the total reddening is due to internal extinction within NGC 1569.

  5. Spatially resolved Raman spectroscopy study of transformed zones in magnesia-partially-stabilized zirconia

    International Nuclear Information System (INIS)

    Davskardt, R.H.; Veirs, D.K.; Ritchie, R.O.

    1989-01-01

    Raman vibrational spectroscopy provides an effective phase characterization technique in materials systems containing particle dispersions of the tetragonal and monoclinic polymorphs of zirconia, each of which yields a unique Raman spectrum. An investigation is reported to assess a novel, spatially resolved Raman spectroscopy system in the study of transformed zones surrounding cracks in partially stabilized MgO-ZrO 2 (PSZ). The experimental arrangement uses an imaging (two-dimensional) photomultiplier tube to produce a one-dimensional Raman profile of phase compositions along a slitlike laser beam without translation of either the sample or the laser beam and without scanning the spectrometer. Results from phase characterization studies of the size, frontal morphology, and extent of transformation of transformation zones surrounding cracks produced under monotonic and cyclic loading conditions are presented

  6. Spatially-resolved EEL studies of plasmons in silver filled carbon nanotubes using a dedicated STEM

    International Nuclear Information System (INIS)

    Bangert, U; Harvey, A J; Seepujak, A

    2008-01-01

    Using a dedicated FEG STEM, we present highly spatially-resolved electron energy-loss (EEL) studies of individual multi-walled carbon nanotubes (MWCNTs), each with the inner cavity possessing regions completely filled with silver. The transmission and attenuation of graphite π-collective mode E-fields through the MWCNT walls are established. Noticeable changes in the graphite π-surface mode are witnessed, concomitant with coupling of the silver Mie mode and the graphite π-surface mode. The resulting collective mode is significantly red-shifted to below 5 eV, with considerable intensity in the visible frequency regime. It appears that silver retains its ability to enhance E-fields when surrounded by a MWCNT. Present observations lead to the possibility of collective modes propagating on graphene monolayers being tuned in frequency by the presence of a metal.

  7. Photosensitized production of singlet oxygen: spatially-resolved optical studies in single cells

    DEFF Research Database (Denmark)

    Breitenbach, Thomas; Kuimova, Marina; Gbur, Peter

    2009-01-01

    be monitored using viability assays. Time- and spatially-resolved optical measurements of both singlet oxygen and its precursor, the excited state sensitizer, reflect the complex and dynamic morphology of the cell. These experiments help elucidate photoinduced, oxygen-dependent events that compromise cell...

  8. Spatially-resolved studies of charge-density-wave phase slip and dynamics in NbSe3

    International Nuclear Information System (INIS)

    Lemay, S.G.; Adelman, T.L.; Zaitsev-Zotov, S.V.; Thorne, R.E.

    1999-01-01

    We review our spatially and temporally resolved studies of charge-density-wave (CDW) phase slip and dynamics in NbSe 3 . Measurements of the steady-state CDW current, phase slip and strain profiles and their transient evolutions in response to a change in current direction provide a detailed picture of the interplay between elastic deformations and plasticity in this material. (orig.)

  9. Scanning mass spectrometer setup for spatially resolved reactivity studies on model catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Roos, Matthias; Schirling, Christian; Kielbassa, Stefan; Bansmann, Joachim; Behm, Juergen [Institut fuer Oberflaechenchemie und Katalyse, Universitaet Ulm, D-89069 Ulm (Germany)

    2007-07-01

    A scanning mass spectrometer with micrometer-scale resolution was developed for investigations on the catalytic activity of microstructured planar model catalysts. Products of local surface reactions can be detected via a fine capillary orifice in a differentially pumped quadrupole mass spectrometer. The position of the sample with respect to the capillary is controlled by three piezo-driven translators. The surface reactivity of a resistive heated sample can be depicted in a spatially resolved topogram, taking into account the influence of the distance between sample and capillary on the magnitude of the QMS signal and the lateral resolution. Photolithographic structured reactive patterns on top of an inactive substrate enable investigations of mesoscopic transport effects such as coupling between catalytically active areas and of (reverse) spillover phenomena on one sample by varying the size and the distances of the active areas.

  10. Spatially resolved spectroscopy on semiconductor nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Roessler, Johanna

    2009-02-20

    Cleared edge overgrowth (CEO) nanostructures are identified and studied by 1D und 2D {mu}PL mapping scans and by time-resolved and power-dependent measurements. Distinct excitonic ground states of 2fold CEO QDs with large localization energies are achieved. The deeper localization reached as compared to the only other report on 2fold CEO QDs in literature is attributed to a new strain-free fabrication process and changed QW thickness in [001] growth. In order to achieve controlled manipulation of 2fold CEO QDs the concept of a CEO structure with three top gates and one back gate is presented. Due to the complexity of this device, a simpler test structure is realized. Measurements on this test structure confirm the necessity to either grow significantly thicker overgrowth layers or to provide separate top gates in all three spatial direction to controllably manipulate 2fold CEO QDs with an external electric field. (orig.)

  11. Study of flow behavior in all-vanadium redox flow battery using spatially resolved voltage distribution

    Science.gov (United States)

    Bhattarai, Arjun; Wai, Nyunt; Schweiss, Rüdiger; Whitehead, Adam; Scherer, Günther G.; Ghimire, Purna C.; Nguyen, Tam D.; Hng, Huey Hoon

    2017-08-01

    Uniform flow distribution through the porous electrodes in a flow battery cell is very important for reducing Ohmic and mass transport polarization. A segmented cell approach can be used to obtain in-situ information on flow behaviour, through the local voltage or current mapping. Lateral flow of current within the thick felts in the flow battery can hamper the interpretation of the data. In this study, a new method of segmenting a conventional flow cell is introduced, which for the first time, splits up both the porous felt as well as the current collector. This dual segmentation results in higher resolution and distinct separation of voltages between flow inlet to outlet. To study the flow behavior for an undivided felt, monitoring the OCV is found to be a reliable method, instead of voltage or current mapping during charging and discharging. Our approach to segmentation is simple and applicable to any size of the cell.

  12. Spatially Resolved Measurements Of Plasma Density Irregularities In The Ionosphere F Region For Scintillation Studies.

    Science.gov (United States)

    Spencer, E. A.; Russ, S.; Clark, D. C.; Latif, S.; Montalvo, C.

    2016-12-01

    This qualitative study focuses on students evidence-based explanatory models on how ocean acidification impacts oysters. Explanatory models are the crucial components of scientific endeavors as it helps scientists explain how the natural world functions and the reasons for the ways it functions. Moreover, these models assemble individual practices to understand how they work together to reach clear conclusions through scientific investigations. Due to their critical roles in making sense of authentic science, recent studies in science education suggest that these models should be part of the curriculum aligned with new science standards, i.e. Next Generation Science Standards, which stress the importance of engaging students in scientific practices. By collecting data from 400 secondary school students in Maryland, we aim to respond to the question: How can we use secondary school students' explanatory models to provide students with constructive feedback for more comprehensive learning of ocean acidification (the related evidence, causes and impact)? The data were analyzed through discourse analysis method. We highlighted and coded students' inscriptions (e.g., drawings, writings, and representations) that are signs of students' understanding (or lack thereof) of ocean acidification. These signs included explanations of pH levels, drawings of oyster growth, and inclusions of relevant data. The findings showed that the explanatory models can be critical forms of feedback as they reveal a) students' alternative conceptions on how ocean acidification impacts oysters or how acidification works in general; b) students' interpretations of oceans' (non)connectedness to Earth system; c) the choice of scientific representations and their sources; and d) the way students' integrate evidence or data from the investigations. Our work tackles an understanding of one of the most vital signs of modern climatic changes. Recent scientific evidence shows that if the change in ocean

  13. Probing Minor-merger-driven Star Formation In Early-type Galaxies Using Spatially-resolved Spectro-photometric Studies

    Science.gov (United States)

    Kaviraj, Sugata; Crockett, M.; Silk, J.; O'Connell, R. W.; Whitmore, B.; Windhorst, R.; Cappellari, M.; Bureau, M.; Davies, R.

    2012-01-01

    Recent studies that leverage the rest-frame ultraviolet (UV) spectrum have revealed widespread recent star formation in early-type galaxies (ETGs), traditionally considered to be old, passively-evolving systems. This recent star formation builds 20% of the ETG stellar mass after z 1, driven by repeated minor mergers between ETGs and small, gas-rich satellites. We demonstrate how spatially-resolved studies, using a combination of high-resolution UV-optical imaging and integral-field spectroscopy (IFS), is a powerful tool to quantify the assembly history of individual ETGs and elucidate the poorly-understood minor-merger process. Using a combination of WFC3 UV-optical (2500-8200 angstroms) imaging and IFS from the SAURON project of the ETG NGC 4150, we show that this galaxy experienced a merger with mass ratio 1:15 around 0.9 Gyr ago, which formed 3% of its stellar mass and a young kinematically-decoupled core. A UV-optical analysis of its globular cluster system shows that the bulk of the stars locked up in these clusters likely formed 6-7 Gyrs in the past. We introduce a new HST-WFC3 programme, approved in Cycle 19, which will leverage similar UV-optical imaging of a representative sample of nearby ETGs from SAURON to study the recent star formation and its drivers in unprecedented detail and put definitive constraints on minor-merger-driven star formation in massive galaxies at late epochs.

  14. Spatially Resolved Analysis of Bragg Selectivity

    Directory of Open Access Journals (Sweden)

    Tina Sabel

    2015-11-01

    Full Text Available This paper targets an inherent control of optical shrinkage in photosensitive polymers, contributing by means of spatially resolved analysis of volume holographic phase gratings. Point by point scanning of the local material response to the Gaussian intensity distribution of the recording beams is accomplished. Derived information on the local grating period and grating slant is evaluated by mapping of optical shrinkage in the lateral plane as well as through the depth of the layer. The influence of recording intensity, exposure duration and the material viscosity on the Bragg selectivity is investigated.

  15. Spatially-resolved isotopic study of carbon trapped in ∼3.43 Ga Strelley Pool Formation stromatolites

    Science.gov (United States)

    Flannery, David T.; Allwood, Abigail C.; Summons, Roger E.; Williford, Kenneth H.; Abbey, William; Matys, Emily D.; Ferralis, Nicola

    2018-02-01

    The large isotopic fractionation of carbon associated with enzymatic carbon assimilation allows evidence for life's antiquity, and potentially the early operation of several extant metabolic pathways, to be derived from the stable carbon isotope record of sedimentary rocks. Earth's organic carbon isotope record extends to the Late Eoarchean-Early Paleoarchean: the age of the oldest known sedimentary rocks. However, complementary inorganic carbon reservoirs are poorly represented in the oldest units, and commonly reported bulk organic carbon isotope measurements do not capture the micro-scale isotopic heterogeneities that are increasingly reported from younger rocks. Here, we investigated the isotopic composition of the oldest paired occurrences of sedimentary carbonate and organic matter, which are preserved as dolomite and kerogen within textural biosignatures of the ∼3.43 Ga Strelley Pool Formation. We targeted least-altered carbonate phases in situ using microsampling techniques guided by non-destructive elemental mapping. Organic carbon isotope values were measured by spatially-resolved bulk analyses, and in situ using secondary ion mass spectrometry to target microscale domains of organic material trapped within inorganic carbon matrixes. Total observed fractionation of 13C ranges from -29 to -45‰. Our data are consistent with studies of younger Archean rocks that host biogenic stromatolites and organic-inorganic carbon pairs showing greater fractionation than expected for Rubisco fixation alone. We conclude that organic matter was fixed and/or remobilized by at least one metabolism in addition to the CBB cycle, possibly by the Wood-Ljungdahl pathway or methanogenesis-methanotrophy, in a shallow-water marine environment during the Paleoarchean.

  16. Spatially resolved remote measurement of temperature by neutron resonance absorption

    Energy Technology Data Exchange (ETDEWEB)

    Tremsin, A.S., E-mail: ast@ssl.berkeley.edu [Space Sciences Laboratory, University of California at Berkeley, 7 Gauss Way, Berkeley, CA 94720 (United States); Kockelmann, W.; Pooley, D.E. [STFC, Rutherford Appleton Laboratory, ISIS Facility, Didcot OX11 0QX (United Kingdom); Feller, W.B. [NOVA Scientific, Inc., 10 Picker Road, Sturbridge, MA 01566 (United States)

    2015-12-11

    Deep penetration of neutrons into most engineering materials enables non-destructive studies of their bulk properties. The existence of sharp resonances in neutron absorption spectra enables isotopically-resolved imaging of elements present in a sample, as demonstrated by previous studies. At the same time the Doppler broadening of resonance peaks provides a method of remote measurement of temperature distributions within the same sample. This technique can be implemented at a pulsed neutron source with a short initial pulse allowing for the measurement of the energy of each registered neutron by the time of flight technique. A neutron counting detector with relatively high timing and spatial resolution is used to demonstrate the possibility to obtain temperature distributions across a 100 µm Ta foil with ~millimeter spatial resolution. Moreover, a neutron transmission measurement over a wide energy range can provide spatially resolved sample information such as temperature, elemental composition and microstructure properties simultaneously.

  17. Panchromatic SED modelling of spatially resolved galaxies

    Science.gov (United States)

    Smith, Daniel J. B.; Hayward, Christopher C.

    2018-05-01

    We test the efficacy of the energy-balance spectral energy distribution (SED) fitting code MAGPHYS for recovering the spatially resolved properties of a simulated isolated disc galaxy, for which it was not designed. We perform 226 950 MAGPHYS SED fits to regions between 0.2 and 25 kpc in size across the galaxy's disc, viewed from three different sight-lines, to probe how well MAGPHYS can recover key galaxy properties based on 21 bands of UV-far-infrared model photometry. MAGPHYS yields statistically acceptable fits to >99 per cent of the pixels within the r-band effective radius and between 59 and 77 percent of pixels within 20 kpc of the nucleus. MAGPHYS is able to recover the distribution of stellar mass, star formation rate (SFR), specific SFR, dust luminosity, dust mass, and V-band attenuation reasonably well, especially when the pixel size is ≳ 1 kpc, whereas non-standard outputs (stellar metallicity and mass-weighted age) are recovered less well. Accurate recovery is more challenging in the smallest sub-regions of the disc (pixel scale ≲ 1 kpc), where the energy balance criterion becomes increasingly incorrect. Estimating integrated galaxy properties by summing the recovered pixel values, the true integrated values of all parameters considered except metallicity and age are well recovered at all spatial resolutions, ranging from 0.2 kpc to integrating across the disc, albeit with some evidence for resolution-dependent biases. These results must be considered when attempting to analyse the structure of real galaxies with actual observational data, for which the `ground truth' is unknown.

  18. Spatially Resolved Circumnuclear Dust in Centaurus A

    OpenAIRE

    Karovska, Margarita; Marengo, Massimo; Elvis, Martin; Fazio, Giovanni; Hora, Joseph; Hinz, Philip; Hoffmann, William; Meyer, Michael; Mamajek, Eric

    2003-01-01

    In this paper we present results from our exploratory mid-IR study of Centaurus A circumnuclear environment using high-angular resolution imaging at the Magellan 6.5m telescope with the MIRAC/BLINC camera. We detected emission from a compact region surrounding the nuclear source, and obtained photometry at 8.8 microns and in the N band. Our analysis suggests that the nuclear region is resolved with a size of approximately 3 pc. The mid-IR emission from this region is likely associated with co...

  19. Spatially Resolved Isotopic Source Signatures of Wetland Methane Emissions

    Science.gov (United States)

    Ganesan, A. L.; Stell, A. C.; Gedney, N.; Comyn-Platt, E.; Hayman, G.; Rigby, M.; Poulter, B.; Hornibrook, E. R. C.

    2018-04-01

    We present the first spatially resolved wetland δ13C(CH4) source signature map based on data characterizing wetland ecosystems and demonstrate good agreement with wetland signatures derived from atmospheric observations. The source signature map resolves a latitudinal difference of 10‰ between northern high-latitude (mean -67.8‰) and tropical (mean -56.7‰) wetlands and shows significant regional variations on top of the latitudinal gradient. We assess the errors in inverse modeling studies aiming to separate CH4 sources and sinks by comparing atmospheric δ13C(CH4) derived using our spatially resolved map against the common assumption of globally uniform wetland δ13C(CH4) signature. We find a larger interhemispheric gradient, a larger high-latitude seasonal cycle, and smaller trend over the period 2000-2012. The implication is that erroneous CH4 fluxes would be derived to compensate for the biases imposed by not utilizing spatially resolved signatures for the largest source of CH4 emissions. These biases are significant when compared to the size of observed signals.

  20. Time-resolved studies

    International Nuclear Information System (INIS)

    Mills, D.M.

    1992-01-01

    When new or more powerful probes become available that offer both shorter data-collection times and the opportunity to apply innovative approaches to established techniques, it is natural that investigators consider the feasibility of exploring the kinetics of time-evolving systems. This stimulating area of research not only can lead to insights into the metastable or excited states that a system may populate on its way to a ground state, but can also lead to a better understanding of that final state. Synchrotron radiation, with its unique properties, offers just such a tool to extend X-ray measurements from the static to the time-resolved regime. The most straight-forward application of synchrotron radiation to the study of transient phenomena is directly through the possibility of decreased data-collection times via the enormous increase in flux over that of a laboratory X-ray system. Even further increases in intensity can be obtained through the use of novel X-ray optical devices. Widebandpass monochromators, e.g., that utilize the continuous spectral distribution of synchrotron radiation, can increase flux on the sample several orders of magnitude over conventional X-ray optical systems thereby allowing a further shortening of the data-collection time. Another approach that uses the continuous spectral nature of synchrotron radiation to decrease data-collection times is the open-quote parallel data collectionclose quotes method. Using this technique, intensities as a function of X-ray energy are recorded simultaneously for all energies rather than sequentially recording data at each energy, allowing for a dramatic decrease in the data-collection time

  1. Exploring the limits to spatially resolved NMR

    Energy Technology Data Exchange (ETDEWEB)

    Gaedke, Achim; Nestle, Nikolaus [TU Darmstadt, Institute of Condensed Matter Physics (Germany)

    2010-07-01

    Recent advances in MRI have demonstrated resolutions down to 1 {mu}m. Magnetic resonance force microscopy has the potential to reach sensitivity for single nuclear spins. Given these numbers, in vivo imaging of single cells or even biomacromolecules may seem possible. However, for in vivo applications, there are fundamental differences in the contrast mechanisms compared to MRI at macroscopic scales as the length scale of of molecular self-diffusion exceeds that of the spatial resolution on the NMR time scale. Those effects - which are fundamentally different from the echo attenuation in field gradient NMR - even may lead to general limitations on the spatial resolution achievable in aqueous systems with high water content. In our contribution, we explore those effects on a model system in a high-resolution stray-field imaging setup. In addition to experimental results, simulations based on the Bloch-Torrey equation are presented.

  2. Studies of Shear Band Velocity Using Spatially and Temporally Resolved Measurements of Strain During Quasistatic Compression of Bulk Metallic Glass

    Energy Technology Data Exchange (ETDEWEB)

    Wright, W J; Samale, M; Hufnagel, T; LeBlanc, M; Florando, J

    2009-06-15

    We have made measurements of the temporal and spatial features of the evolution of strain during the serrated flow of Pd{sub 40}Ni{sub 40}P{sub 20} bulk metallic glass tested under quasistatic, room temperature, uniaxial compression. Strain and load data were acquired at rates of up to 400 kHz using strain gages affixed to all four sides of the specimen and a piezoelectric load cell located near the specimen. Calculation of the displacement rate requires an assumption about the nature of the shear displacement. If one assumes that the entire shear plane displaces simultaneously, the displacement rate is approximately 0.002 m/s. If instead one assumes that the displacement occurs as a localized propagating front, the velocity of the front is approximately 2.8 m/s. In either case, the velocity is orders of magnitude less than the shear wave speed ({approx}2000 m/s). The significance of these measurements for estimates of heating in shear bands is discussed.

  3. STUDY OF USING CANON 1000D DIGITAL CAMERA FOR MULTIZONE PHOTOGRAPHY WITH SPATIALLY-RESOLVED SPECTRAL DEVICES

    Directory of Open Access Journals (Sweden)

    K. N. Kaplevskiy

    2013-01-01

    Full Text Available The possibility of use a CANON 1000D digital camera for multizone photography is demonstrated. It is found that a dynamic range of the recorded light intensities is varied from 260 to 3650 quantization levels of the ADC. Linearity of the light-sensitive element of the camera has been studied in dependence on its illumination and exposure time.

  4. Resolving the influential parameters of thermal comfort perception amidst indoor-outdoor spatial transitions: Case study in a lecture room

    NARCIS (Netherlands)

    Derks, M.T.H.; Loomans, M.G.L.C.; Mishra, A.K.; Kort, H.S.M.

    2017-01-01

    Indoor to outdoor transitions have an undeniable impact on thermal perception of occupants and can impact their evaluation of a building. These aspects are often overlooked in thermal comfort standards. We address this gap using a mixed methods study, with students in undergraduate level classrooms

  5. Magnetic Resonance Microscopy Spatially Resolved NMR Techniques and Applications

    CERN Document Server

    Codd, Sarah

    2008-01-01

    This handbook and ready reference covers materials science applications as well as microfluidic, biomedical and dental applications and the monitoring of physicochemical processes. It includes the latest in hardware, methodology and applications of spatially resolved magnetic resonance, such as portable imaging and single-sided spectroscopy. For materials scientists, spectroscopists, chemists, physicists, and medicinal chemists.

  6. Microstructural investigation into calcium phosphate biomaterials by spatially resolved cathodoluminescence

    Energy Technology Data Exchange (ETDEWEB)

    Goetze, J.; Heimann, R.B.; Hildebrandt, H. [Freiberg Univ. of Mining and Technology (Germany). Dept. of Mineralogy; Gburek, U. [Wuerzburg Univ. (Germany). Dept. of Experimental Dentistry

    2001-02-01

    From cathodoluminescence (CL) investigations of synthetic and natural calcium phosphates it can be concluded that the CL of pure synthetic apatite is mainly characterized by intrinsic luminescence, whereas the luminescence of naturally occurring apatites is frequently activated by trace elements. CL revealed internal structures within plasma-sprayed hydroxyapatite coatings which were not discernible by SEM-BSE imaging. However, cathodoluminescence microscopy alone can presently not be used in every case to characterize synthetic calcium phosphate biomaterials because of the dominant intrinsic blue CL emission. In the future, optimum results will likely be achieved by using a combination of CL microscopy and spectroscopy with other spatially resolved analytical methods such as SEM-BSE, SEM-CL or micro-Raman spectroscopy. In the present study, different types of tetracalcium phosphate dental cements could be distinguished due to varying CL colours and CL spectra that are caused by a different content of impurity Mn. These results emphasize the advantages of spectral CL measurements for spatially resolved detection of trace elements in solids. (orig.) [German] Ergebnisse von Kathodolumineszenz- (KL-) Untersuchungen synthetischer und natuerlicher Apatite zeigen, dass die KL synthetischer Apatite vorrangig durch intrinsische Lumineszenz gekennzeichnet ist, waehrend die KL natuerlicher Apatite meist durch Spurenlemente aktiviert wird. Mittels KL koennen Internstrukturen in plasmagespritzten Hydroxylapatit-Schichten sichtbar gemacht werden, die im REM-BSE nicht nachweisbar sind. Allerdings kann die KL-Mikroskopie aufgrund der dominierenden blauen intrinsischen Lumineszenz gegenwaertig nicht als alleinige Untersuchungsmethode zur Charakterisierung von Calciumphosphat Biomaterialien eingesetzt werden. Optimale Resultate werden zukuenftig durch Kombination von KL-Mikrroskopie und -spektroskopie mit anderen ortsaufgeloesten analytischen Methoden wie REM-BSE, REM-KL oder Mikro

  7. Spatially resolved NEXAFS spectroscopy of siderophores in biological matrices

    International Nuclear Information System (INIS)

    Thieme, J; Kilcoyne, D; Tyliszczak, T; Haselwandter, K

    2013-01-01

    Iron is an essential nutrient for almost all forms of life. In the presence of oxygen iron is present in its ferric form which precipitates under formation of rather insoluble oxide-hydroxide polymers. Hence the bioavailability of iron is extremely low ( −17 M at pH 7 for Fe 3+ ). Under such conditions almost all microorganisms synthesize siderophores as iron chelating agents, thus solubilizing ferric iron from rather insoluble iron sources. Siderophores form soluble complexes with Fe 3+ . The present study aims at developing a methodology that would allow for the specific detection and localization of such iron chelators in their natural environment. The applicability of spatially resolved NEXAFS spectroscopy in the soft X-ray energy (E < 1 keV) range was evaluated for localization of typical fungal hydroxamate siderophores like ferrichrome or coprogen, which can be present in various biological materials. Results obtained with the scanning transmission X-ray microscopes at beamlines 11.0.2 and 5.3.2 of the ALS have shown characteristic signatures for siderophores. Thus NEXAFS spectroscopy at the carbon K-edge, nitrogen K-edge and iron L-edge with high spatial resolution has proven to be extremely useful for their identification in their natural environment. Spectra of different siderophores as well as spectra and images of biological material containing siderophores are presented

  8. A comparative transmission electron microscopy, energy dispersive x-ray spectroscopy and spatially resolved micropillar compression study of the yttria partially stabilised zirconia - porcelain interface in dental prosthesis

    Energy Technology Data Exchange (ETDEWEB)

    Lunt, Alexander J.G., E-mail: alexander.lunt@chch.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Mohanty, Gaurav, E-mail: gaurav.mohanty@empa.ch [EMPA Materials Science & Technology, Feuerwerkerstrasse 39, CH-3602 Thun (Switzerland); Ying, Siqi, E-mail: siqi.ying@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Dluhoš, Jiří, E-mail: jiri.dluhos@tescan.cz [TESCAN Brno, s.r.o., Libušina tř. 1, 623 00 Brno-Kohoutovice (Czech Republic); Sui, Tan, E-mail: tan.sui@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom); Neo, Tee K., E-mail: neophyte@singnet.com.sg [Specialist Dental Group, Mount Elizabeth Orchard, 3 Mount Elizabeth, #08-03/08-08/08-10, 228510 (Singapore); Michler, Johann, E-mail: johann.michler@empa.ch [EMPA Materials Science & Technology, Feuerwerkerstrasse 39, CH-3602 Thun (Switzerland); Korsunsky, Alexander M., E-mail: alexander.korsunsky@eng.ox.ac.uk [Department of Engineering Science, University of Oxford, Parks Road, Oxford, Oxfordshire OX1 3PJ (United Kingdom)

    2015-12-01

    Recent studies into the origins of failure of yttria partially stabilised zirconia–porcelain veneered prosthesis have revealed the importance of micro-to-nano scale characterisation of this interface zone. Current understanding suggests that the heat treatment, residual stresses and varying microstructure at this location may contribute to near-interface porcelain chipping. In this study the chemical, microstructural and mechanical property variation across the interfacial zone has been characterised at two differing length scales and using three independent techniques; energy dispersive X-ray spectroscopy, transmission electron microscopy and micropillar compression. Energy dispersive X-ray spectroscopy mapping of the near-interface region revealed, for the first time, that the diffusional lengths of twelve principal elements are limited to within 2–6 μm of the interface. This study also revealed that 0.2–2 μm diameter zirconia grains had become detached from the bulk and were embedded in the near-interface porcelain. Transmission electron microscopy analysis demonstrated the presence of nanoscale spherical features, indicative of tensile creep induced voiding, within the first 0.4–1.5 μm from the interface. Within zirconia, variations in grain size and atomistic structure were also observed within the 3 μm closest to the interface. Micropillar compression was performed over a 100 μm range on either side of the interface at the spatial resolution of 5 μm. This revealed an increase in zirconia and porcelain loading modulus at close proximities (< 5 μm) to the interface and a decrease in zirconia modulus at distances between 6 and 41 μm from this location. The combination of the three experimental techniques has revealed intricate details of the microstructural, chemical and consequently mechanical heterogeneities in the YPSZ–porcelain interface, and demonstrated that the length scales typically associated with this behaviour are approximately ± 5

  9. High spatial resolution and temporally resolved T2* mapping of normal human myocardium at 7.0 Tesla: an ultrahigh field magnetic resonance feasibility study.

    Directory of Open Access Journals (Sweden)

    Fabian Hezel

    Full Text Available Myocardial tissue characterization using T(2(* relaxation mapping techniques is an emerging application of (preclinical cardiovascular magnetic resonance imaging. The increase in microscopic susceptibility at higher magnetic field strengths renders myocardial T(2(* mapping at ultrahigh magnetic fields conceptually appealing. This work demonstrates the feasibility of myocardial T(2(* imaging at 7.0 T and examines the applicability of temporally-resolved and high spatial resolution myocardial T(2(* mapping. In phantom experiments single cardiac phase and dynamic (CINE gradient echo imaging techniques provided similar T(2(* maps. In vivo studies showed that the peak-to-peak B(0 difference following volume selective shimming was reduced to approximately 80 Hz for the four chamber view and mid-ventricular short axis view of the heart and to 65 Hz for the left ventricle. No severe susceptibility artifacts were detected in the septum and in the lateral wall for T(2(* weighting ranging from TE = 2.04 ms to TE = 10.2 ms. For TE >7 ms, a susceptibility weighting induced signal void was observed within the anterior and inferior myocardial segments. The longest T(2(* values were found for anterior (T(2(* = 14.0 ms, anteroseptal (T(2(* = 17.2 ms and inferoseptal (T(2(* = 16.5 ms myocardial segments. Shorter T(2(* values were observed for inferior (T(2(* = 10.6 ms and inferolateral (T(2(* = 11.4 ms segments. A significant difference (p = 0.002 in T(2(* values was observed between end-diastole and end-systole with T(2(* changes of up to approximately 27% over the cardiac cycle which were pronounced in the septum. To conclude, these results underscore the challenges of myocardial T(2(* mapping at 7.0 T but demonstrate that these issues can be offset by using tailored shimming techniques and dedicated acquisition schemes.

  10. Retinal ganglion cell topography and spatial resolving power in penguins.

    Science.gov (United States)

    Coimbra, João Paulo; Nolan, Paul M; Collin, Shaun P; Hart, Nathan S

    2012-01-01

    Penguins are a group of flightless seabirds that exhibit numerous morphological, behavioral and ecological adaptations to their amphibious lifestyle, but little is known about the topographic organization of neurons in their retinas. In this study, we used retinal wholemounts and stereological methods to estimate the total number and topographic distribution of retinal ganglion cells in addition to an anatomical estimate of spatial resolving power in two species of penguins: the little penguin, Eudyptula minor, and the king penguin, Aptenodytes patagonicus. The total number of ganglion cells per retina was approximately 1,200,000 in the little penguin and 1,110,000 in the king penguin. The topographic distribution of retinal ganglion cells in both species revealed the presence of a prominent horizontal visual streak with steeper gradients in the little penguin. The little penguin retinas showed ganglion cell density peaks of 21,867 cells/mm², affording spatial resolution in water of 17.07-17.46 cycles/degree (12.81-13.09 cycles/degree in air). In contrast, the king penguin showed a relatively lower peak density of ganglion cells of 14,222 cells/mm², but--due to its larger eye--slightly higher spatial resolution in water of 20.40 cycles/degree (15.30 cycles/degree in air). In addition, we mapped the distribution of giant ganglion cells in both penguin species using Nissl-stained wholemounts. In both species, topographic mapping of this cell type revealed the presence of an area gigantocellularis with a concentric organization of isodensity contours showing a peak in the far temporal retina of approximately 70 cells/mm² in the little penguin and 39 cells/mm² in the king penguin. Giant ganglion cell densities gradually fall towards the outermost isodensity contours revealing the presence of a vertically organized streak. In the little penguin, we confirmed our cytological characterization of giant ganglion cells using immunohistochemistry for microtubule

  11. The impact of spatial resolution on resolving spatial precipitation patterns in the Himalayas

    OpenAIRE

    Bonekamp, P.N.J.; Collier, S.E.; Immerzeel, W.W.

    2017-01-01

    Frequently used gridded meteorological datasets poorly represent precipitation in the Himalaya due to their relatively low spatial resolution and the associated coarse representation of the complex topography. Dynamical downscaling using high-resolution atmospheric models may improve the accuracy and quality of the precipitation fields, as simulations at higher spatial resolution are more capable of resolving the interaction between the topography and the atmosphere. However, most physics par...

  12. Spatially-resolved measurement of optically stimulated luminescence and time-resolved luminescence

    International Nuclear Information System (INIS)

    Bailiff, I.K.; Mikhailik, V.B.

    2003-01-01

    Spatially-resolved measurements of optically stimulated luminescence (OSL) were performed using a two-dimensional scanning system designed for use with planar samples. The scanning system employs a focused laser beam to stimulate a selected area of the sample, which is moved under the beam by a motorised stage. Exposure of the sample is controlled by an electronic shutter. Mapping of the distribution of OSL using a continuous wave laser source was obtained with sub-millimeter resolution for samples of sliced brick, synthetic single crystal quartz, concrete and dental ceramic. These revealed sporadic emission in the case of brick or concrete and significant spatial variation of emission for quartz and dental ceramic slices. Determinations of absorbed dose were performed for quartz grains within a slice of modern brick. Reconfiguration of the scanner with a pulsed laser source enabled quartz and feldspathic minerals within a ceramic sample to be thinner region. about 6 nm from the extrapolation of themeasuring the time-resolved luminescence spectrum

  13. Study of optoelectronic properties of thin film solar cell materials Cu2ZnSn(S,Se)4 using multiple correlative spatially-resolved spectroscopy techniques

    Science.gov (United States)

    Chen, Qiong

    Containing only earth abundant and environmental friendly elements, quaternary compounds Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe 4 (CZTSe) are considered as promising absorber materials for thin film solar cells. The best record efficiency for this type of thin film solar cell is now 12.6%. As a promising photovoltaic (PV) material, the electrical and optical properties of CZTS(Se) have not been well studied. In this work, an effort has been made to understand the optoelectronic and structural properties, in particular the spatial variations, of CZTS(Se) materials and devices by correlating multiple spatially resolved characterization techniques with sub-micron resolution. Micro-Raman (micro-Raman) spectroscopy was used to analyze the chemistry compositions in CZTS(Se) film; Micro-Photoluminescence (micro-PL) was used to determine the band gap and possible defects. Micro-Laser-Beam-Induced-Current (micro-LBIC) was used to examine the photo-response of CZTS(Se) solar cell in different illumination conditions. Micro-reflectance was used to estimate the reflectance loss. And Micro-I-V measurement was used to compare important electrical parameters from CZTS(Se) solar cells with different device structure or absorber compositions. Scanning electron microscopy and atomic force microscopy were used to characterize the surface morphology. Successfully integrating and correlating these techniques was first demonstrated during the course of this work in our laboratory, and this level of integration and correlation has been rare in the field of PV research. This effort is significant not only for this particular project and also for a wide range of research topics. Applying this approach, in conjunction with high-temperature and high-excitation-power optical spectroscopy, we have been able to reveal the microscopic scale variations among samples and devices that appeared to be very similar from macroscopic material and device characterizations, and thus serve as a very powerful tool

  14. Spatially resolved regression analysis of pre-treatment FDG, FLT and Cu-ATSM PET from post-treatment FDG PET: an exploratory study

    Science.gov (United States)

    Bowen, Stephen R; Chappell, Richard J; Bentzen, Søren M; Deveau, Michael A; Forrest, Lisa J; Jeraj, Robert

    2012-01-01

    Purpose To quantify associations between pre-radiotherapy and post-radiotherapy PET parameters via spatially resolved regression. Materials and methods Ten canine sinonasal cancer patients underwent PET/CT scans of [18F]FDG (FDGpre), [18F]FLT (FLTpre), and [61Cu]Cu-ATSM (Cu-ATSMpre). Following radiotherapy regimens of 50 Gy in 10 fractions, veterinary patients underwent FDG PET/CT scans at three months (FDGpost). Regression of standardized uptake values in baseline FDGpre, FLTpre and Cu-ATSMpre tumour voxels to those in FDGpost images was performed for linear, log-linear, generalized-linear and mixed-fit linear models. Goodness-of-fit in regression coefficients was assessed by R2. Hypothesis testing of coefficients over the patient population was performed. Results Multivariate linear model fits of FDGpre to FDGpost were significantly positive over the population (FDGpost~0.17 FDGpre, p=0.03), and classified slopes of RECIST non-responders and responders to be different (0.37 vs. 0.07, p=0.01). Generalized-linear model fits related FDGpre to FDGpost by a linear power law (FDGpost~FDGpre0.93, pregression analysis indicates that pre-treatment FDG PET uptake is most strongly associated with three-month post-treatment FDG PET uptake in this patient population, though associations are histopathology-dependent. PMID:22682748

  15. Spatially resolved sulfur K-edge XANES spectroscopy of wheat leaves infected by Puccinia triticina

    International Nuclear Information System (INIS)

    Lichtenberg, H; Prange, A; Hormes, J; Steiner, U; Oerke, E-C

    2009-01-01

    In this study, wheat leaves infected with brown rust, a plant disease of serious economic concern caused by the fungus Puccinia triticina, were investigated using spatially resolved XANES (X-ray Absorption Near Edge Structure) spectroscopy at the sulfur K-absorption edge.

  16. Spatially resolved sulfur K-edge XANES spectroscopy of wheat leaves infected by Puccinia triticina

    Energy Technology Data Exchange (ETDEWEB)

    Lichtenberg, H; Prange, A; Hormes, J [CAMD, Louisiana State University, 6980 Jefferson Hwy, Baton Rouge, LA 70806 (United States); Steiner, U; Oerke, E-C, E-mail: lichtenberg@lsu.ed [INRES-Phytomedicine, University of Bonn, Nussallee 9, 53115 Bonn (Germany)

    2009-11-15

    In this study, wheat leaves infected with brown rust, a plant disease of serious economic concern caused by the fungus Puccinia triticina, were investigated using spatially resolved XANES (X-ray Absorption Near Edge Structure) spectroscopy at the sulfur K-absorption edge.

  17. Near-Infrared Spatially Resolved Spectroscopy for Tablet Quality Determination.

    Science.gov (United States)

    Igne, Benoît; Talwar, Sameer; Feng, Hanzhou; Drennen, James K; Anderson, Carl A

    2015-12-01

    Near-infrared (NIR) spectroscopy has become a well-established tool for the characterization of solid oral dosage forms manufacturing processes and finished products. In this work, the utility of a traditional single-point NIR measurement was compared with that of a spatially resolved spectroscopic (SRS) measurement for the determination of tablet assay. Experimental designs were used to create samples that allowed for calibration models to be developed and tested on both instruments. Samples possessing a poor distribution of ingredients (highly heterogeneous) were prepared by under-blending constituents prior to compaction to compare the analytical capabilities of the two NIR methods. The results indicate that SRS can provide spatial information that is usually obtainable only through imaging experiments for the determination of local heterogeneity and detection of abnormal tablets that would not be detected with single-point spectroscopy, thus complementing traditional NIR measurement systems for in-line, and in real-time tablet analysis. © 2015 Wiley Periodicals, Inc. and the American Pharmacists Association.

  18. Orientation Characterisation of Aerospace Materials by Spatially Resolved Acoustic Spectroscopy

    International Nuclear Information System (INIS)

    Li, Wenqi; Coulson, Jethro; Smith, Richard J; Clark, Matt; Somekh, Michael G; Sharples, Steve D; Aveson, John W

    2014-01-01

    Material characteristics in metals such as strength, stiffness and fracture resistance are strongly related to the underlying microstructure. The crystallographic structure and orientation are related to the ultrasonic properties through the stiffness matrix. In individual grains it is possible to analytically determine the ultrasonic velocity from the orientation and stiffness, or determine the stiffness from the known orientation and measured velocity. In this paper we present a technique for imaging the crystallographic orientation of grains in metals using spatially resolved acoustic spectroscopy (SRAS) and a novel inverse solver that can determine the crystallographic orientation from the known stiffness matrix for the material and the SRAS velocity measurement. Previously we have shown the ability of this technique to determine the orientation on single crystal nickel samples; we extended the technique to multigrain industrial metals, such as aluminium, nickel and Inconel. The comparison between SRAS and electron backscatter diffraction (EBSD) on the nickel sample is presented. SRAS is a fast, accurate, quantitative and robust technique for imaging material microstructure and orientation over a wide range of scales and industrial materials

  19. A study of the interference of cesium and phosphate in the low power inductively coupled radiofrequency argon plasma using spatially resolved emission and absorption measurements, ch. 4

    International Nuclear Information System (INIS)

    Kornblum, G.R.

    1977-01-01

    The literature on interferences in the radio frequency inductively coupled atmospheric argon plasma (ICP) is reviewed. Even for the most extensively investigated interferences of aluminum, phosphate and alkali elements on calcium, the studies are mostly descriptive. Inter-pretation of these data is impeded by conflicting results, the absence of thermal equilibrium and the lack of radially resolved observations. The present study of a low-power ICP $ KW) utilizes the Abel inversion technique for emission and absorption measurements of atom and ion lines to clarify the mechanism of interferences on calcium and magnesium due to phosphate and cesium. Under conditions of large carrier gas flow (4.5 l/min) the pronounced interferences are the result of three combined effects: volatilization interference, a change in excitation temperature and a shift in the ionization equilibrium. At lower carrier gas flow (1.4 l/min) the interferences are markedly reduced but still due to the same three effects. The relative preponderance of a particular type of interference depends upon the height of observation and upon the particular combination of analyte and interferent considered

  20. Spatially resolved speckle-correlometry of sol-gel transition

    Science.gov (United States)

    Isaeva, A. A.; Isaeva, E. A.; Pantyukov, A. V.; Zimnyakov, D. A.

    2018-04-01

    Sol-gel transition was studied using the speckle correlometry method with a localized light source and spatial filtering of backscattered radiation. Water solutions of technical or food gelatin with added TiO2 nanoparticles were used as studied objects. Structural transformation of "sol-gel" system was studied at various temperatures from 25°C to 50°C using analysis of the correlation and structure functions of speckle intensity fluctuations. The characteristic temperatures of "sol - gel" transition were evaluated for studied systems. Obtained results can be used for various applications in biomedicine and food industry.

  1. A framework for widespread replication of a highly spatially resolved childhood lead exposure risk model.

    Science.gov (United States)

    Kim, Dohyeong; Galeano, M Alicia Overstreet; Hull, Andrew; Miranda, Marie Lynn

    2008-12-01

    Preventive approaches to childhood lead poisoning are critical for addressing this longstanding environmental health concern. Moreover, increasing evidence of cognitive effects of blood lead levels system-based childhood lead exposure risk models, especially if executed at highly resolved spatial scales, can help identify children most at risk of lead exposure, as well as prioritize and direct housing and health-protective intervention programs. However, developing highly resolved spatial data requires labor-and time-intensive geocoding and analytical processes. In this study we evaluated the benefit of increased effort spent geocoding in terms of improved performance of lead exposure risk models. We constructed three childhood lead exposure risk models based on established methods but using different levels of geocoded data from blood lead surveillance, county tax assessors, and the 2000 U.S. Census for 18 counties in North Carolina. We used the results to predict lead exposure risk levels mapped at the individual tax parcel unit. The models performed well enough to identify high-risk areas for targeted intervention, even with a relatively low level of effort on geocoding. This study demonstrates the feasibility of widespread replication of highly spatially resolved childhood lead exposure risk models. The models guide resource-constrained local health and housing departments and community-based organizations on how best to expend their efforts in preventing and mitigating lead exposure risk in their communities.

  2. Tissue oxygenation and haemodynamics measurement with spatially resolved NIRS

    Science.gov (United States)

    Zhang, Y.; Scopesi, F.; Serra, G.; Sun, J. W.; Rolfe, P.

    2010-08-01

    We describe the use of Near Infrared Spectroscopy (NIRS) for the non-invasive investigation of changes in haemodynamics and oxygenation of human peripheral tissues. The goal was to measure spatial variations of tissue NIRS oxygenation variables, namely deoxy-haemoglobin (HHb), oxy-haemoglobin (HbO2), total haemoglobin (HbT), and thereby to evaluate the responses of the peripheral circulation to imposed physiological challenges. We present a skinfat- muscle heterogeneous tissue model with varying fat thickness up to 15mm and a Monte Carlo simulation of photon transport within this model. The mean partial path length and the mean photon visit depth in the muscle layer were derived for different source-detector spacing. We constructed NIRS instrumentation comprising of light-emitting diodes (LED) as light sources at four wavelengths, 735nm, 760nm, 810nm and 850nm and sensitive photodiodes (PD) as the detectors. Source-detector spacing was varied to perform measurements at different depths within forearm tissue. Changes in chromophore concentration in response to venous and arterial occlusion were calculated using the modified Lambert-Beer Law. Studies in fat and thin volunteers indicated greater sensitivity in the thinner subjects for the tissue oxygenation measurement in the muscle layer. These results were consistent with those found using Monte Carlo simulation. Overall, the results of this investigation demonstrate the usefulness of the NIRS instrument for deriving spatial information from biological tissues.

  3. Spatially resolved D-T(2) correlation NMR of porous media.

    Science.gov (United States)

    Zhang, Yan; Blümich, Bernhard

    2014-05-01

    Within the past decade, 2D Laplace nuclear magnetic resonance (NMR) has been developed to analyze pore geometry and diffusion of fluids in porous media on the micrometer scale. Many objects like rocks and concrete are heterogeneous on the macroscopic scale, and an integral analysis of microscopic properties provides volume-averaged information. Magnetic resonance imaging (MRI) resolves this spatial average on the contrast scale set by the particular MRI technique. Desirable contrast parameters for studies of fluid transport in porous media derive from the pore-size distribution and the pore connectivity. These microscopic parameters are accessed by 1D and 2D Laplace NMR techniques. It is therefore desirable to combine MRI and 2D Laplace NMR to image functional information on fluid transport in porous media. Because 2D Laplace resolved MRI demands excessive measuring time, this study investigates the possibility to restrict the 2D Laplace analysis to the sum signals from low-resolution pixels, which correspond to pixels of similar amplitude in high-resolution images. In this exploratory study spatially resolved D-T2 correlation maps from glass beads and mortar are analyzed. Regions of similar contrast are first identified in high-resolution images to locate corresponding pixels in low-resolution images generated with D-T2 resolved MRI for subsequent pixel summation to improve the signal-to-noise ratio of contrast-specific D-T2 maps. This method is expected to contribute valuable information on correlated sample heterogeneity from the macroscopic and the microscopic scales in various types of porous materials including building materials and rock. Copyright © 2014 Elsevier Inc. All rights reserved.

  4. Structure in nascent carbon nanotubes revealed by spatially resolved Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Landois, Périne [CEA, IRAMIS, SPAM, Laboratoire Francis Perrin (CNRS URA 2453), 91191 Gif-sur-Yvette (France); Laboratoire de Physique des Solides, UMR CNRS 8502, Université Paris Sud 11, 91405 Orsay (France); Pinault, Mathieu [CEA, IRAMIS, SPAM, Laboratoire Francis Perrin (CNRS URA 2453), 91191 Gif-sur-Yvette (France); Huard, Mickaël [Laboratoire de Physique des Solides, UMR CNRS 8502, Université Paris Sud 11, 91405 Orsay (France); Reita, Valérie [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Rouzière, Stéphan; Launois, Pascale [Laboratoire de Physique des Solides, UMR CNRS 8502, Université Paris Sud 11, 91405 Orsay (France); Mayne-L' Hermite, Martine [CEA, IRAMIS, SPAM, Laboratoire Francis Perrin (CNRS URA 2453), 91191 Gif-sur-Yvette (France); Bendiab, Nedjma, E-mail: nedjma.bendiab@grenoble.cnrs.fr [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France)

    2014-10-01

    The understanding of carbon nanotube (CNT) growth is crucial for the control of their production. In particular, the identification of structural changes of carbon possibly occurring near the catalyst particle in the very early stages of their formation is of high interest. In this study, samples of nascent CNT obtained during nucleation step and samples of vertically aligned CNT obtained during growth step are analysed by combined spatially resolved Raman spectroscopy and X-ray diffraction measurements. Spatially resolved Raman spectroscopy reveals that iron-based phases and carbon phases are co-localized at the same position, and indicates that sp{sup 2} carbon nucleates preferentially on iron-based particles during this nucleation step. Depth scan Raman spectroscopy analysis, performed on nascent CNT, highlights that carbon structural organisation is significantly changing from defective graphene layers surrounding the iron-based particles at their base up to multi-walled nanotube structures in the upper part of iron-based particles. - Highlights: • Spatial co-localization of iron and carbon structures in nascent carbon nanotubes • Imaging local carbon structure changes along catalyst particles by Raman spectroscopy. • In nascent nanotubes, significant structural changes occur along catalyst particle.

  5. Spatially resolved characterization in thin-film photovoltaics

    CERN Document Server

    Bokalic, Matevz

    2015-01-01

    The book is devoted to the spatial characterization of solar cells and PV modules. It is written both as a monograph as well as a succinct guide for the state-of-the-art spatial characterization techniques and approaches. Amongst the approaches discussed are visual imaging, electro- and photo-luminescence imaging, thermography, and light beam induced mapping techniques. Emphasis is given on the luminescence image acquisition and interpretation due to its great potential. Characterization techniques are accompanied by simulation tools. The contents are aimed at a readership of students and s

  6. A spatially resolved study of photoelectric heating and [C II] cooling in the LMC Comparison with dust emission as seen by SAGE

    NARCIS (Netherlands)

    Rubin, D.; Hony, S.; Madden, S. C.; Tielens, A. G. G. M.; Meixner, M.; Indebetouw, R.; Reach, W.; Ginsburg, A.; Kim, S.; Mochizuki, K.; Babler, B.; Block, M.; Bracker, S. B.; Engelbracht, C. W.; For, B. -Q.; Gordon, K.; Hora, J. L.; Leitherer, C.; Meade, M.; Misselt, K.; Sewilo, M.; Vijh, U.; Whitney, B.

    Context. Photoelectric heating is a dominant heating mechanism for many phases of the interstellar medium. We study this mechanism throughout the Large Magellanic Cloud (LMC). Aims. We aim to quantify the importance of the [C II] cooling line and the photoelectric heating process of various

  7. Spatially Resolved Quantification of the Surface Reactivity of Solid Catalysts.

    Science.gov (United States)

    Huang, Bing; Xiao, Li; Lu, Juntao; Zhuang, Lin

    2016-05-17

    A new property is reported that accurately quantifies and spatially describes the chemical reactivity of solid surfaces. The core idea is to create a reactivity weight function peaking at the Fermi level, thereby determining a weighted summation of the density of states of a solid surface. When such a weight function is defined as the derivative of the Fermi-Dirac distribution function at a certain non-zero temperature, the resulting property is the finite-temperature chemical softness, termed Fermi softness (SF ), which turns out to be an accurate descriptor of the surface reactivity. The spatial image of SF maps the reactive domain of a heterogeneous surface and even portrays morphological details of the reactive sites. SF analyses reveal that the reactive zones on a Pt3 Y(111) surface are the platinum sites rather than the seemingly active yttrium sites, and the reactivity of the S-dimer edge of MoS2 is spatially anisotropic. Our finding is of fundamental and technological significance to heterogeneous catalysis and industrial processes demanding rational design of solid catalysts. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. An Interferometric Study of the Post-AGB Binary 89 Herculis. 1: Spatially Resolving the Continuum Circumstellar Environment at Optical and Near-IR Wavelengths with the VLTI, NPOI, IOTA, PTI, and the CHARA Array

    Science.gov (United States)

    2013-01-01

    Herculis I. Spatially resolving the continuum circumstellar environment at optical and near-IR wavelengths with the VLTI, NPOI, IOTA , PTI, and the CHARA...public release; distribution unlimited 13. SUPPLEMENTARY NOTES A&A 559, A111 (2013) 14. ABSTRACT 15. SUBJECT TERMS 16. SECURITY CLASSIFICATION...Array ( IOTA ) and the Center for High Angular Resolution Astronomy (CHARA) Array, covering 0.5 to 2.2 μm and with baselines from 15 to 278 m. Here we

  9. SPATIALLY RESOLVED SPECTROSCOPY OF SUBMILLIMETER GALAXIES AT z ≃ 2

    Energy Technology Data Exchange (ETDEWEB)

    Olivares, V.; Treister, E.; Privon, G. C.; Nagar, N. [Universidad de Concepción, Departamento de Astronomía, Casilla 160-C, Concepción (Chile); Alaghband-Zadeh, S.; Chapman, S. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA UK (United Kingdom); Casey, Caitlin M. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Schawinski, K. [Institute for Astronomy, Department of Physics, ETH Zurich, Wolfgang-Pauli-Strasse 27, CH-8093 Zurich (Switzerland); Kurczynski, P.; Gawiser, E. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Bauer, F. E. [Instituto de Astrofísica, Facultad de Física, Pontificia Universidad Católica de Chile, Casilla 306, Santiago 22 (Chile); Sanders, D. [Institute for Astronomy, 2680 Woodlawn Drive, University of Hawaii, Honolulu, HI 96822 (United States)

    2016-08-10

    We present near-infrared integral-field spectroscopic observations targeting H α in eight submillimeter galaxies (SMGs) at z = 1.3–2.5 using the Very Large Telescope/Spectrograph for Integral Field Observations in the Near Infrared, obtaining significant detections for six of them. The star formation rates derived from the H α emission are ∼100 M {sub ⊙} yr{sup −1}, which account for only ∼20%–30% of the infrared-derived values, thus suggesting that these systems are very dusty. Two of these systems present [N ii]/H α ratios indicative of the presence of an active galactic nucleus. We mapped the spatial distribution and kinematics of the star-forming regions in these galaxies on kiloparsec scales. In general, the H α morphologies tend to be highly irregular and/or clumpy, showing spatial extents of ∼3–11 kpc. We find evidence for significant spatial offsets, of ∼0.″1–0.″4 or 1.2–3.4 kpc, between the H α and the continuum emission in three of the sources. Performing a kinemetry analysis, we conclude that the majority of the sample is not consistent with disk-like rotation-dominated kinematics. Instead, they tend to show irregular and/or clumpy and turbulent velocity and velocity dispersion fields. This can be interpreted as evidence for a scenario in which these extreme star formation episodes are triggered by galaxy–galaxy interactions and major mergers. In contrast to recent results for SMGs, these sources appear to follow the same relations between gas and star-forming rate densities as less luminous and/or normal star-forming galaxies.

  10. Simulations of the temporal and spatial resolution for a compact time-resolved electron diffractometer

    Science.gov (United States)

    Robinson, Matthew S.; Lane, Paul D.; Wann, Derek A.

    2016-02-01

    A novel compact electron gun for use in time-resolved gas electron diffraction experiments has recently been designed and commissioned. In this paper we present and discuss the extensive simulations that were performed to underpin the design in terms of the spatial and temporal qualities of the pulsed electron beam created by the ionisation of a gold photocathode using a femtosecond laser. The response of the electron pulses to a solenoid lens used to focus the electron beam has also been studied. The simulated results show that focussing the electron beam affects the overall spatial and temporal resolution of the experiment in a variety of ways, and that factors that improve the resolution of one parameter can often have a negative effect on the other. A balance must, therefore, be achieved between spatial and temporal resolution. The optimal experimental time resolution for the apparatus is predicted to be 416 fs for studies of gas-phase species, while the predicted spatial resolution of better than 2 nm-1 compares well with traditional time-averaged electron diffraction set-ups.

  11. Spatially resolved δ13C analysis using laser ablation isotope ratio mass spectrometry

    Science.gov (United States)

    Moran, J.; Riha, K. M.; Nims, M. K.; Linley, T. J.; Hess, N. J.; Nico, P. S.

    2014-12-01

    Inherent geochemical, organic matter, and microbial heterogeneity over small spatial scales can complicate studies of carbon dynamics through soils. Stable isotope analysis has a strong history of helping track substrate turnover, delineate rhizosphere activity zones, and identifying transitions in vegetation cover, but most traditional isotope approaches are limited in spatial resolution by a combination of physical separation techniques (manual dissection) and IRMS instrument sensitivity. We coupled laser ablation sampling with isotope measurement via IRMS to enable spatially resolved analysis over solid surfaces. Once a targeted sample region is ablated the resulting particulates are entrained in a helium carrier gas and passed through a combustion reactor where carbon is converted to CO2. Cyrotrapping of the resulting CO2 enables a reduction in carrier gas flow which improves overall measurement sensitivity versus traditional, high flow sample introduction. Currently we are performing sample analysis at 50 μm resolution, require 65 ng C per analysis, and achieve measurement precision consistent with other continuous flow techniques. We will discuss applications of the laser ablation IRMS (LA-IRMS) system to microbial communities and fish ecology studies to demonstrate the merits of this technique and how similar analytical approaches can be transitioned to soil systems. Preliminary efforts at analyzing soil samples will be used to highlight strengths and limitations of the LA-IRMS approach, paying particular attention to sample preparation requirements, spatial resolution, sample analysis time, and the types of questions most conducive to analysis via LA-IRMS.

  12. Spatially resolved SO2 flux emissions from Mt Etna

    Science.gov (United States)

    Bitetto, M.; Delle Donne, D.; Tamburello, G.; Battaglia, A.; Coltelli, M.; Patanè, D.; Prestifilippo, M.; Sciotto, M.; Aiuppa, A.

    2016-01-01

    Abstract We report on a systematic record of SO2 flux emissions from individual vents of Etna volcano (Sicily), which we obtained using a permanent UV camera network. Observations were carried out in summer 2014, a period encompassing two eruptive episodes of the New South East Crater (NSEC) and a fissure‐fed eruption in the upper Valle del Bove. We demonstrate that our vent‐resolved SO2 flux time series allow capturing shifts in activity from one vent to another and contribute to our understanding of Etna's shallow plumbing system structure. We find that the fissure eruption contributed ~50,000 t of SO2 or ~30% of the SO2 emitted by the volcano during the 5 July to 10 August eruptive interval. Activity from this eruptive vent gradually vanished on 10 August, marking a switch of degassing toward the NSEC. Onset of degassing at the NSEC was a precursory to explosive paroxysmal activity on 11–15 August. PMID:27773952

  13. Spatially and temporally resolved diagnostics for microsecond, intense electron beams

    International Nuclear Information System (INIS)

    Gilgenbach, R.M.; Brake, M.; Horton, L.D.; Bidwell, S.; Lucey, R.F.; Smutek, L.; Tucker, J.E.

    1985-01-01

    Experiments are underway to investigate new diagnostics for electron beams in vacuum and in a plasma background. Measured parameters include temporally resolved beam current profile and beam emittance. These characterizations are being performed during electron beam diode closure experiments (1) and beam-plasma interaction experiments with either of two long-pulse accelerators: MELBA (Michigan Electron Long Beam Accelerator): Voltage = -1 MV, Current = 10 kA, at Pulselength = 0.1 to 1μs (1.4μs) for voltage flat to within +.7% (+.10%). The second accelerator is a long-pulse Febetron with parameters: Voltage = -0.5 MV, Current = 1 kA, and Pulselength = 0.3 s. Two different configurations have been developed which use Cerenkov radiation to detect electron beam current profiles as a function of time. The first uses Cerenkov emission by electrons which impinge axially on a single fiberoptic lightguide enclosed in a lucite tube. Plasma light is blocked by graphite spray or thin foil covering the end of the optical fiber. This diagnostic has the following advantages: 1) The threshold energy for Cerenkov emission effectively discriminates between high energy beam electrons and low energy (3-5 eV) plasma electrons, 2) The small, nonconducting probe introduces a minimal perturbation into the beam-plasma system, 3) Excellent signal to noise ratio is obtained because the fiberoptic signal is directly transmitted to a photomultiplier tube in the Faraday cage, 4) Quantitative data is obtained directly

  14. Spatially resolved spectrophotometry of Comet P/Stephan-Oterma

    Science.gov (United States)

    Cochran, A. L.; Barker, E. S.

    1985-01-01

    Observations of Comet P/Stephan-Oterma were made with an Intensified Dissector Scanner spectrograph on the McDonald Observatory 2.7-m telescope during the period from July 1980 to February 1981. These spectra cover a range of heliocentric distances from 2.3 AU preperihelion to 1.8 AU postperihelion. A small aperture was used to map the spatial distributions of the gases in the coma. Column densities of the observed cometary emissions (CN, C3, CH, and C2) were calculated, and it is shown that Stephan-Oterma appeared nearly spherically symmetric. These date are used by Cochran (1985) to constrain chemical models of Stephan-Oterma.

  15. Preliminary results of spatially resolved ECR ion beam profile investigations

    International Nuclear Information System (INIS)

    Panitzsch, L.; Stalder, M.; Wimmer-Schweingruber, R.F.

    2012-01-01

    The profile of an ion beam produced in an Electron Cyclotron Resonance Ion Source (ECRIS) can vary greatly depending on the source settings and the ion-optical tuning. Strongly focussed ion beams form circular structures (hollow beams) as predicted by simulations and observed in experiments. Each of the rings is predicted to be dominated by ions with same or at least similar m/q-ratios due to ion-optical effects. To check this we performed a series of preliminary investigations to test the required tuning capabilities of our ion source. This includes beam focussing (A) and beam steering (B) using a 3D-movable extraction. Having tuned the source to deliver a beam of strongly focussed ions of different ion species and having steered this beam to match the transmittance area of the sector magnet we also recorded the ion charge state distribution of the strongly focussed beam profile at different, spatially limited positions (C). The preliminary results will be introduced within this paper: it appears that our 3D-movable extraction is very efficient to steer and to focus the beam strongly. The paper is followed by the slides of the presentation. (authors)

  16. Determining disease intervention strategies using spatially resolved simulations.

    Directory of Open Access Journals (Sweden)

    Mark Read

    Full Text Available Predicting efficacy and optimal drug delivery strategies for small molecule and biological therapeutics is challenging due to the complex interactions between diverse cell types in different tissues that determine disease outcome. Here we present a new methodology to simulate inflammatory disease manifestation and test potential intervention strategies in silico using agent-based computational models. Simulations created using this methodology have explicit spatial and temporal representations, and capture the heterogeneous and stochastic cellular behaviours that lead to emergence of pathology or disease resolution. To demonstrate this methodology we have simulated the prototypic murine T cell-mediated autoimmune disease experimental autoimmune encephalomyelitis, a mouse model of multiple sclerosis. In the simulation immune cell dynamics, neuronal damage and tissue specific pathology emerge, closely resembling behaviour found in the murine model. Using the calibrated simulation we have analysed how changes in the timing and efficacy of T cell receptor signalling inhibition leads to either disease exacerbation or resolution. The technology described is a powerful new method to understand cellular behaviours in complex inflammatory disease, permits rational design of drug interventional strategies and has provided new insights into the role of TCR signalling in autoimmune disease progression.

  17. Spatially-resolved, three-dimensional spray characterization of impinging jets by digital in-line holography

    Science.gov (United States)

    Gao, Jian; Rodrigues, Neil; Sojka, Paul; Chen, Jun

    2014-11-01

    The impinging jet injector is a preferred method for the atomization of liquid rocket propellants. The majority of experimental studies in literature are not spatially-resolved due to the limitations of widely available point-wise and two-dimensional (2D) diagnostic techniques such as phase Doppler anemometry (PDA), which requires significant experimental repetitions to give spatially-resolved measurements. In the present study, digital in-line holography (DIH) is used to provide spatially-resolved, three-dimensional (3D) characteristics of impinging jet sprays. A double-exposure DIH setup is configured to measure droplet 3D, three-component velocity as well as the size distribution. The particle information is extracted by the hybrid method, which is recently proposed as a particle detection method. To enlarge the detection volume, two parallel, collimated laser beams are used to simultaneously probe the spray at two locations, and two identical cameras are used to record the corresponding holograms. Such a setup has a detection volume of approximately 20 cm by 3.6 cm by 4.8 cm. Sprays of both Newtonian and non-Newtonian liquids corresponding to regimes at relatively lower jet Reynolds and Weber numbers are investigated. Measurements from DIH are further verified by comparison with experimental data obtained from shadowgraph and PDA. It is revealed that DIH is particularly suitable to provide spatially-resolved, 3D measurements of impinging jet sprays that are not particularly dense.

  18. Hemoglobin concentration determination based on near infrared spatially resolved transmission spectra

    Science.gov (United States)

    Zhang, Linna; Li, Gang; Lin, Ling

    2016-10-01

    Spatially resolved diffuse reflectance spectroscopy method has been proved to be more effective than single point spectroscopy method in the experiment to predict the concentration of the Intralipid diluted solutions. However, Intralipid diluted solution is simple, cannot be the representative of turbid liquids. Blood is a natural and meaningful turbid liquid, more complicate. Hemoglobin is the major constituent of the whole blood. And hemoglobin concentration is commonly used in clinical medicine to diagnose many diseases. In this paper, near infrared spatially resolved transmission spectra (NIRSRTS) and Partial Least Square Regression (PLSR) were used to predict the hemoglobin concentration of human blood. The results showed the prediction ability for hemoglobin concentration of the proposed method is better than single point transmission spectroscopy method. This paper demonstrated the feasibility of the spatially resolved diffuse reflectance spectroscopy method for practical liquid composition analysis. This research provided a new thinking of practical turbid liquid composition analysis.

  19. Spatially resolvable optical emission spectrometer for analyzing density uniformity of semiconductor process plasma

    International Nuclear Information System (INIS)

    Oh, Changhoon; Ryoo, Hoonchul; Lee, Hyungwoo; Hahn, Jae W.; Kim, Se-Yeon; Yi, Hun-Jung

    2010-01-01

    We proposed a spatially resolved optical emission spectrometer (SROES) for analyzing the uniformity of plasma density for semiconductor processes. To enhance the spatial resolution of the SROES, we constructed a SROES system using a series of lenses, apertures, and pinholes. We calculated the spatial resolution of the SROES for the variation of pinhole size, and our calculated results were in good agreement with the measured spatial variation of the constructed SROES. The performance of the SROES was also verified by detecting the correlation between the distribution of a fluorine radical in inductively coupled plasma etch process and the etch rate of a SiO 2 film on a silicon wafer.

  20. Spatially-resolved luminescence spectroscopy of CdSe quantum dots synthesized in ionic liquid crystal matrices

    International Nuclear Information System (INIS)

    Magaryan, K.A.; Mikhailov, M.A.; Karimullin, K.R.; Knyazev, M.V.; Eremchev, I.Y.; Naumov, A.V.; Vasilieva, I.A.; Klimusheva, G.V.

    2016-01-01

    The paper is devoted to investigation of luminescence properties of new quantum dot (QD)-doped materials. We studied CdSe QDs (1.8 nm and 2.3 nm) grown inside of a liquid crystalline cadmium alcanoate matrix. Temperature dependence of parameters of fluorescence spectra obtained in a wide temperature range using epi-luminescence microscopy technique was analyzed. Spatially-resolved luminescence images were measured for the areas of the samples of 150×150 µm 2 . Strong correlation between fluorescence spectra and sample structure was observed. - Highlights: • Glassy matrix with CdSe quantum dots inside fabricated in liquid crystalline mesophase. • Study of luminescence properties in a wide range of low temperatures. • Strong dependence of the luminescence spectra on spatial inhomogeneities. • Spatially-resolved luminescence imaging of quantum dots in liquid crystalline matrix.

  1. Spatially-resolved luminescence spectroscopy of CdSe quantum dots synthesized in ionic liquid crystal matrices

    Energy Technology Data Exchange (ETDEWEB)

    Magaryan, K.A., E-mail: xmagaros@gmail.com [Moscow State Pedagogical University, 29 Malaya Pirogovskaya Str., Moscow 119992 (Russian Federation); Mikhailov, M.A. [Moscow State Pedagogical University, 29 Malaya Pirogovskaya Str., Moscow 119992 (Russian Federation); Karimullin, K.R. [Moscow State Pedagogical University, 29 Malaya Pirogovskaya Str., Moscow 119992 (Russian Federation); Institute for Spectroscopy of RAS, 5 Fizicheskaya Str., Troitsk, Moscow 142190 (Russian Federation); E.K. Zavoyski Kazan Physical-Technical Institute of RAS, 10/7 Sibirski trakt Str., Kazan 420029 (Russian Federation); Knyazev, M.V.; Eremchev, I.Y. [Institute for Spectroscopy of RAS, 5 Fizicheskaya Str., Troitsk, Moscow 142190 (Russian Federation); Naumov, A.V. [Moscow State Pedagogical University, 29 Malaya Pirogovskaya Str., Moscow 119992 (Russian Federation); Institute for Spectroscopy of RAS, 5 Fizicheskaya Str., Troitsk, Moscow 142190 (Russian Federation); Vasilieva, I.A. [Moscow State Pedagogical University, 29 Malaya Pirogovskaya Str., Moscow 119992 (Russian Federation); Klimusheva, G.V. [Institute of Physics, NAS of Ukraine, 46 Prospect Nauki, Kiev 03028 (Ukraine)

    2016-01-15

    The paper is devoted to investigation of luminescence properties of new quantum dot (QD)-doped materials. We studied CdSe QDs (1.8 nm and 2.3 nm) grown inside of a liquid crystalline cadmium alcanoate matrix. Temperature dependence of parameters of fluorescence spectra obtained in a wide temperature range using epi-luminescence microscopy technique was analyzed. Spatially-resolved luminescence images were measured for the areas of the samples of 150×150 µm{sup 2}. Strong correlation between fluorescence spectra and sample structure was observed. - Highlights: • Glassy matrix with CdSe quantum dots inside fabricated in liquid crystalline mesophase. • Study of luminescence properties in a wide range of low temperatures. • Strong dependence of the luminescence spectra on spatial inhomogeneities. • Spatially-resolved luminescence imaging of quantum dots in liquid crystalline matrix.

  2. Spatially Resolved Imaging and Spectroscopy of Candidate Dual Active Galactic Nuclei

    Science.gov (United States)

    McGurk, R. C.; Max, C. E.; Medling, A. M.; Shields, G. A.; Comerford, J. M.

    2015-09-01

    When galaxies merge, both central supermassive black holes are immersed in a dense and chaotic environment. If there is sufficient gas in the nuclear regions, one expects to see close pairs of active galactic nuclei (AGNs), or dual AGNs, in a fraction of galaxy mergers. However, finding them remains a challenge. The presence of double-peaked [O iii] emission lines has been proposed as a technique to select dual AGNs efficiently. We studied a sample of double-peaked narrow [O iii] emitting AGNs from Sloan Digital Sky Survey (SDSS) DR7. By obtaining new and archival high spatial resolution images taken with the Keck II Laser Guide Star Adaptive Optics system and the near-infrared camera NIRC2, we show that 30% of 140 double-peaked [O iii] emission line SDSS AGNs have two spatial components within a 3″ radius. However, spatially resolved spectroscopy or X-ray observations are needed to confirm these galaxy pairs as systems containing two AGNs. We followed up three spatially double candidate dual AGNs with integral field spectroscopy from Keck OSIRIS and 10 candidates with long-slit spectroscopy from the Shane Kast Double Spectrograph at Lick Observatory. We find that the double-peaked emission lines in our sample of 12 candidates are caused by: one dual AGN (SDSS J114642.47+511029.6), one confirmed outflow and four likely outflows, two pairs of star-forming galaxies, one candidate indeterminate due to sky line interference, and three AGNs with spatially coincident double [O iii] peaks, likely due to unresolved complex narrow line kinematics, outflows, binary AGN, or small-scale jets.

  3. SPATIALLY RESOLVED IMAGING AND SPECTROSCOPY OF CANDIDATE DUAL ACTIVE GALACTIC NUCLEI

    Energy Technology Data Exchange (ETDEWEB)

    McGurk, R. C.; Max, C. E. [Astronomy Department and UCO-Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Medling, A. M. [Research School of Astronomy and Astrophysics, Australian National University, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia); Shields, G. A. [Laguna Falls Institute for Astrophysics, Austin, TX 78746 (United States); Comerford, J. M., E-mail: rosalie.mcgurk@gmail.com, E-mail: max@ucolick.org, E-mail: anne.medling@anu.edu.au, E-mail: shields@lfastro.org, E-mail: julie.comerford@colorado.edu [Department of Astrophysical and Planetary Sciences, University of Colorado, Boulder, CO 80309 (United States)

    2015-09-20

    When galaxies merge, both central supermassive black holes are immersed in a dense and chaotic environment. If there is sufficient gas in the nuclear regions, one expects to see close pairs of active galactic nuclei (AGNs), or dual AGNs, in a fraction of galaxy mergers. However, finding them remains a challenge. The presence of double-peaked [O iii] emission lines has been proposed as a technique to select dual AGNs efficiently. We studied a sample of double-peaked narrow [O iii] emitting AGNs from Sloan Digital Sky Survey (SDSS) DR7. By obtaining new and archival high spatial resolution images taken with the Keck II Laser Guide Star Adaptive Optics system and the near-infrared camera NIRC2, we show that 30% of 140 double-peaked [O iii] emission line SDSS AGNs have two spatial components within a 3″ radius. However, spatially resolved spectroscopy or X-ray observations are needed to confirm these galaxy pairs as systems containing two AGNs. We followed up three spatially double candidate dual AGNs with integral field spectroscopy from Keck OSIRIS and 10 candidates with long-slit spectroscopy from the Shane Kast Double Spectrograph at Lick Observatory. We find that the double-peaked emission lines in our sample of 12 candidates are caused by: one dual AGN (SDSS J114642.47+511029.6), one confirmed outflow and four likely outflows, two pairs of star-forming galaxies, one candidate indeterminate due to sky line interference, and three AGNs with spatially coincident double [O iii] peaks, likely due to unresolved complex narrow line kinematics, outflows, binary AGN, or small-scale jets.

  4. SPATIALLY RESOLVED IMAGING AND SPECTROSCOPY OF CANDIDATE DUAL ACTIVE GALACTIC NUCLEI

    International Nuclear Information System (INIS)

    McGurk, R. C.; Max, C. E.; Medling, A. M.; Shields, G. A.; Comerford, J. M.

    2015-01-01

    When galaxies merge, both central supermassive black holes are immersed in a dense and chaotic environment. If there is sufficient gas in the nuclear regions, one expects to see close pairs of active galactic nuclei (AGNs), or dual AGNs, in a fraction of galaxy mergers. However, finding them remains a challenge. The presence of double-peaked [O iii] emission lines has been proposed as a technique to select dual AGNs efficiently. We studied a sample of double-peaked narrow [O iii] emitting AGNs from Sloan Digital Sky Survey (SDSS) DR7. By obtaining new and archival high spatial resolution images taken with the Keck II Laser Guide Star Adaptive Optics system and the near-infrared camera NIRC2, we show that 30% of 140 double-peaked [O iii] emission line SDSS AGNs have two spatial components within a 3″ radius. However, spatially resolved spectroscopy or X-ray observations are needed to confirm these galaxy pairs as systems containing two AGNs. We followed up three spatially double candidate dual AGNs with integral field spectroscopy from Keck OSIRIS and 10 candidates with long-slit spectroscopy from the Shane Kast Double Spectrograph at Lick Observatory. We find that the double-peaked emission lines in our sample of 12 candidates are caused by: one dual AGN (SDSS J114642.47+511029.6), one confirmed outflow and four likely outflows, two pairs of star-forming galaxies, one candidate indeterminate due to sky line interference, and three AGNs with spatially coincident double [O iii] peaks, likely due to unresolved complex narrow line kinematics, outflows, binary AGN, or small-scale jets

  5. Spatially resolved XRF, XAFS, XRD, STXM and IR investigation of a natural U-rich clay

    Science.gov (United States)

    Denecke, M. A.; Michel, P.; Schäfer, T.; Huber, F.; Rickers, K.; Rothe, J.; Dardenne, K.; Brendebach, B.; Vitova, T.; Elie, M.

    2009-11-01

    Combined spatially resolved hard X-ray μ-XRF and μ-XAFS studies using an X-ray beam with micrometer dimensions at the INE-Beamline for actinide research at ANKA and Beamline L at HASYLAB with those from scanning transmission soft X-ray microscopy (STXM) and synchrotron-based Fourier transform infrared microspectroscopy (μ-FTIR) recorded with beam spots in the nanometer range are used to study a U-rich clay originating from Autunian shales in the Permian Lodève Basin (France). This argillaceous formation is a natural U deposit associated with organic matter (bitumen). Results allow us to differentiate between possible mechanisms leading to U enrichment: likely U immobilization via reaction with organic material associated with clay mineral. Such investigations support development of reliable assessment of the long term radiological safety for proposed nuclear waste disposal sites.

  6. Monthly and spatially resolved black carbon emission inventory of India: uncertainty analysis

    Directory of Open Access Journals (Sweden)

    U. Paliwal

    2016-10-01

    Full Text Available Black carbon (BC emissions from India for the year 2011 are estimated to be 901.11 ± 151.56 Gg yr−1 based on a new ground-up, GIS-based inventory. The grid-based, spatially resolved emission inventory includes, in addition to conventional sources, emissions from kerosene lamps, forest fires, diesel-powered irrigation pumps and electricity generators at mobile towers. The emissions have been estimated at district level and were spatially distributed onto grids at a resolution of 40 × 40 km2. The uncertainty in emissions has been estimated using a Monte Carlo simulation by considering the variability in activity data and emission factors. Monthly variation of BC emissions has also been estimated to account for the seasonal variability. To the total BC emissions, domestic fuels contributed most significantly (47 %, followed by industry (22 %, transport (17 %, open burning (12 % and others (2 %. The spatial and seasonal resolution of the inventory will be useful for modeling BC transport in the atmosphere for air quality, global warming and other process-level studies that require greater temporal resolution than traditional inventories.

  7. Spatially Resolved Gas Temperature Measurements in an Atmospheric Pressure DC Glow Microdischarge with Raman Scattering

    Science.gov (United States)

    Belostotskiy, S.; Wang, Q.; Donnelly, V.; Economou, D.; Sadeghi, N.

    2006-10-01

    Spatially resolved rotational Raman spectroscopy of ground state nitrogen N2(X^1σg^+) was used to measure the gas temperature (Tg) in a nitrogen dc glow microdischarge (gap between electrodes d˜500 μm). An original backscattering, confocal optical system was developed for collecting Raman spectra. Stray laser light and Raleigh scattering were blocked by using a triple grating monochromator and spatial filters, designed specifically for these experiments. The optical system provided a spatial resolution of electrodes, Tg increased linearly with jd, reaching 500 K at 1000 mA/cm^2 jd for a pressure of 720 Torr. Spatially resolved gas temperature measurements will also be presented and discussed in combination with a mathematical model for gas heating in the microplasma. This work is supported by DoE/NSF.

  8. Imaging buried organic islands by spatially resolved ballistic electron emission spectroscopy

    International Nuclear Information System (INIS)

    Goh, Kuan Eng J; Bannani, A; Troadec, C

    2008-01-01

    The well-known Au/n-Si(111) Schottky interface is modified by a discontinuous pentacene film (∼1.5 nm thick) and studied using spatially resolved ballistic electron emission spectroscopy (BEES). The pentacene film introduced subtle changes to the interface which cannot be definitively detected by current-voltage measurements or a standard BEES analysis of the barrier height. In contrast, analyzing the BEES results in a dual-parameter (transmission attenuation and barrier height) space allows the effect of the pentacene film on the Au/n-Si(111) interface to be clearly demonstrated. We found that the pentacene film behaves like a tunneling barrier and increases the distribution of local barrier heights with a tendency toward lower values. Our results highlight the potential of the dual-parameter BEES analysis for understanding local interface modification by molecules.

  9. Redox-dependent spatially resolved electrochemistry at graphene and graphite step edges.

    Science.gov (United States)

    Güell, Aleix G; Cuharuc, Anatolii S; Kim, Yang-Rae; Zhang, Guohui; Tan, Sze-yin; Ebejer, Neil; Unwin, Patrick R

    2015-04-28

    The electrochemical (EC) behavior of mechanically exfoliated graphene and highly oriented pyrolytic graphite (HOPG) is studied at high spatial resolution in aqueous solutions using Ru(NH3)6(3+/2+) as a redox probe whose standard potential sits close to the intrinsic Fermi level of graphene and graphite. When scanning electrochemical cell microscopy (SECCM) data are coupled with that from complementary techniques (AFM, micro-Raman) applied to the same sample area, different time-dependent EC activity between the basal planes and step edges is revealed. In contrast, other redox couples (ferrocene derivatives) whose potential is further removed from the intrinsic Fermi level of graphene and graphite show uniform and high activity (close to diffusion-control). Macroscopic voltammetric measurements in different environments reveal that the time-dependent behavior after HOPG cleavage, peculiar to Ru(NH3)6(3+/2+), is not associated particularly with any surface contaminants but is reasonably attributed to the spontaneous delamination of the HOPG with time to create partially coupled graphene layers, further supported by conductive AFM measurements. This process has a major impact on the density of states of graphene and graphite edges, particularly at the intrinsic Fermi level to which Ru(NH3)6(3+/2+) is most sensitive. Through the use of an improved voltammetric mode of SECCM, we produce movies of potential-resolved and spatially resolved HOPG activity, revealing how enhanced activity at step edges is a subtle effect for Ru(NH3)6(3+/2+). These latter studies allow us to propose a microscopic model to interpret the EC response of graphene (basal plane and edges) and aged HOPG considering the nontrivial electronic band structure.

  10. Test Sample for the Spatially Resolved Quantification of Illicit Drugs on Fingerprints Using Imaging Mass Spectrometry

    NARCIS (Netherlands)

    Muramoto, S.; Forbes, T.P.; van Asten, A.C.; Gillen, G.

    2015-01-01

    A novel test sample for the spatially resolved quantification of illicit drugs on the surface of a fingerprint using time-of-flight secondary ion mass spectrometry (ToF-SIMS) and desorption electrospray ionization mass spectrometry (DESI-MS) was demonstrated. Calibration curves relating the signal

  11. Sensitivity Analysis and Requirements for Temporally and Spatially Resolved Thermometry Using Neutron Resonance Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fernandez, Juan Carlos [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Barnes, Cris William [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Mocko, Michael Jeffrey [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Zavorka, Lukas [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2018-01-31

    This report is intended to examine the use of neutron resonance spectroscopy (NRS) to make time- dependent and spatially-resolved temperature measurements of materials in extreme conditions. Specifically, the sensitivities of the temperature estimate on neutron-beam and diagnostic parameters is examined. Based on that examination, requirements are set on a pulsed neutron-source and diagnostics to make a meaningful measurement.

  12. Retinal Ganglion Cell Distribution and Spatial Resolving Power in Deep-Sea Lanternfishes (Myctophidae)

    KAUST Repository

    De Busserolles, Fanny

    2014-01-01

    Topographic analyses of retinal ganglion cell density are very useful in providing information about the visual ecology of a species by identifying areas of acute vision within the visual field (i.e. areas of high cell density). In this study, we investigated the neural cell distribution in the ganglion cell layer of a range of lanternfish species belonging to 10 genera. Analyses were performed on wholemounted retinas using stereology. Topographic maps were constructed of the distribution of all neurons and both ganglion and amacrine cell populations in 5 different species from Nissl-stained retinas using cytological criteria. Amacrine cell distribution was also examined immunohistochemically in 2 of the 5 species using anti-parvalbumin antibody. The distributions of both the total neuron and the amacrine cell populations were aligned in all of the species examined, showing a general increase in cell density toward the retinal periphery. However, when the ganglion cell population was topographically isolated from the amacrine cell population, which comprised up to 80% of the total neurons within the ganglion cell layer, a different distribution was revealed. Topographic maps of the true ganglion cell distribution in 18 species of lanternfishes revealed well-defined specializations in different regions of the retina. Different species possessed distinct areas of high ganglion cell density with respect to both peak density and the location and/or shape of the specialized acute zone (i.e. elongated areae ventro-temporales, areae temporales and large areae centrales). The spatial resolving power was calculated to be relatively low (varying from 1.6 to 4.4 cycles per degree), indicating that myctophids may constitute one of the less visually acute groups of deep-sea teleosts. The diversity in retinal specializations and spatial resolving power within the family is assessed in terms of possible ecological functions and evolutionary history.

  13. Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

    Science.gov (United States)

    Tremsin, Anton S.; Gao, Yan; Dial, Laura C.; Grazzi, Francesco; Shinohara, Takenao

    2016-01-01

    Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with 100 μm resolution) distribution of some microstructure properties, such as residual strain, texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. In addition, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.

  14. In situ distributed diagnostics of flowable electrode systems: resolving spatial and temporal limitations.

    Science.gov (United States)

    Dennison, C R; Gogotsi, Y; Kumbur, E C

    2014-09-14

    In this study, we have developed an in situ distributed diagnostics tool to investigate spatial and temporal effects in electrochemical systems based on flowable electrodes. Specifically, an experimental approach was developed that enables spatially-resolved voltage measurements to be obtained in situ, in real-time. To extract additional data from these distributed measurements, an experimentally-parameterized equivalent circuit model with a new 'flow capacitor' circuit element was developed to predict the distributions of various system parameters during operation. As a case study, this approach was applied to investigate the behavior of the suspension electrodes used in an electrochemical flow capacitor under flowing and static conditions. The volumetric capacitance is reduced from 15.6 F ml(-1) to 1.1 F ml(-1) under flowing conditions. Results indicate that the majority of the charging in suspension electrodes occurs within ∼750 μm of the current collectors during flow, which gives rise to significant state-of-charge gradients across the cell, as well as underutilization of the available active material. The underlying cause of this observation is attributed to the relatively high electrical resistance of the slurry coupled with a stratified charging regime and insufficient residence time. The observations highlight the need to develop more conductive slurries and to design cells with reduced charge transport lengths.

  15. 3D Spatially Resolved Models of the Intracellular Dynamics of the Hepatitis C Genome Replication Cycle

    KAUST Repository

    Knodel, Markus

    2017-10-02

    Mathematical models of virus dynamics have not previously acknowledged spatial resolution at the intracellular level despite substantial arguments that favor the consideration of intracellular spatial dependence. The replication of the hepatitis C virus (HCV) viral RNA (vRNA) occurs within special replication complexes formed from membranes derived from endoplasmatic reticulum (ER). These regions, termed membranous webs, are generated primarily through specific interactions between nonstructural virus-encoded proteins (NSPs) and host cellular factors. The NSPs are responsible for the replication of the vRNA and their movement is restricted to the ER surface. Therefore, in this study we developed fully spatio-temporal resolved models of the vRNA replication cycle of HCV. Our simulations are performed upon realistic reconstructed cell structures-namely the ER surface and the membranous webs-based on data derived from immunostained cells replicating HCV vRNA. We visualized 3D simulations that reproduced dynamics resulting from interplay of the different components of our models (vRNA, NSPs, and a host factor), and we present an evaluation of the concentrations for the components within different regions of the cell. Thus far, our model is restricted to an internal portion of a hepatocyte and is qualitative more than quantitative. For a quantitative adaption to complete cells, various additional parameters will have to be determined through further in vitro cell biology experiments, which can be stimulated by the results deccribed in the present study.

  16. Time-resolved studies. Ch. 9

    International Nuclear Information System (INIS)

    Mills, Dennis M.; Argonne National Lab., IL

    1991-01-01

    Synchrotron radiation, with its unique properties, offers a tool to extend X-ray measurements from the static to the time-resolved regime. The most straight-forward application of synchrotron radiation to the study of transient phenomena is directly through the possibility of decreased data-collection times via the enormous increase in flux over that of a laboratory X-ray system. Even further increases in intensity can be obtained through the use of novel X-ray optical devices. Wide-bandpass monochromators, e.g., that utilize the continuous spectral distribution of synchrotron radiation, can increase flux on the sample several orders of magnitude over conventional X-ray optical systems thereby allowing a further shortening of the data-collection time. Another approach that uses the continuous spectral nature of synchrotron radiation to decrease data-collection times is the 'parallel data collection' method. Using this technique, intensities as a function of X-ray energy are recorded simultaneously for all energies rather than sequentially recording data at each energy, allowing for a dramatic decrease in data-collection time. Perhaps the most exciting advances in time-resolved X-ray studies will be made by those methods that exploit the pulsed nature of the radiation emitted from storage rings. Pulsed techniques have had an enormous impact in the study of the temporal evolution of transient phenomena. The extension from continuous to modulated sources for use in time-resolved work has been carried over in a host of fields that use both pulsed particle and pulsed electro-magnetic beams. In this chapter the new experimental techniques are reviewed and illustrated with some experiments. (author). 98 refs.; 20 figs.; 5 tabs

  17. Zooming into Molecular Biomarker Distribution through Spatially Resolved Mass Spectrometry on Intact Sediment Sections

    Science.gov (United States)

    Wörmer, L.; Fuchser, J.; Alfken, S.; Elvert, M.; Schimmelmann, A.; Hinrichs, K. U.

    2016-02-01

    Marine microorganisms adapt to their habitat by structural modification of their membrane lipids. After sedimentation, and due to their persistence in the sedimentary record, the information archived in them remains available on geological time-scales. Thereby sedimentary lipid biomarkers become important informants of past environments. Conventional biomarker analysis is labor-intensive and requires cm-sized samples, temporal resolution is consequently low. We here present an approach, based on laser desorption ionization (LDI) coupled to ultra high resolution mass spectrometry, that avoids wet-chemical sample preparation and enables analysis directly on sediment sections at sub-mm spatial resolution. Our initial study targeted archaeal glycerol dialkyl glycerol tetraethers (GDGTs). GDGTS are ubiquitous and persistent components in marine sediments, and used in several, widely recognized paleoenvironmental proxies. Applied to an Eastern Mediterranean Sapropel layer, GDGT-profiles with previously unachieved temporal resolution were obtained, and pointed to a strong influence of high frequency cycles on sea-surface temperature and planktonic archaeal ecology. Spatial information furthermore revealed a new view on the fine-scale patchiness of lipid distribution. Following these pioneering studies, major developments are under way. A dedicated facility has been set up at MARUM/University of Bremen, which combines lipid biomarker and elemental analysis at sub-mm resolution (down to 50 µm). We present methods for other comprehensive lipid biomarkers (e.g. alkenones or sterols) that are currently being targeted; and the application of spatially resolved biomarker analysis to recent laminated sediments (Santa Barbara Basin), yielding informative profiles with subannual resolution. We also discuss criteria for analyte and sample selection, as well as the main potentialities and constraints of this new approach.

  18. An interferometric study of the post-AGB binary 89 Herculis. I. Spatially resolving the continuum circumstellar environment at optical and near-IR wavelengths with the VLTI, NPOI, IOTA, PTI, and the CHARA Array

    Science.gov (United States)

    Hillen, M.; Verhoelst, T.; Van Winckel, H.; Chesneau, O.; Hummel, C. A.; Monnier, J. D.; Farrington, C.; Tycner, C.; Mourard, D.; ten Brummelaar, T.; Banerjee, D. P. K.; Zavala, R. T.

    2013-11-01

    Context. Binary post-asymptotic giant branch (post-AGB) stars are interesting laboratories to study both the evolution of binaries as well as the structure of circumstellar disks. Aims: A multiwavelength high angular resolution study of the prototypical object 89 Herculis is performed with the aim of identifying and locating the different emission components seen in the spectral energy distribution. Methods: A large interferometric data set, collected over the past decade and covering optical and near-infrared wavelengths, is analyzed in combination with the spectral energy distribution and flux-calibrated optical spectra. In this first paper only simple geometric models are applied to fit the interferometric data. Combining the interferometric constraints with the photometry and the optical spectra, we re-assess the energy budget of the post-AGB star and its circumstellar environment. Results: We report the first (direct) detection of a large (35-40%) optical circumstellar flux contribution and spatially resolve its emission region. Given this large amount of reprocessed and/or redistributed optical light, the fitted size of the emission region is rather compact and fits with(in) the inner rim of the circumbinary dust disk. This rim dominates our K band data through thermal emission and is rather compact, emitting significantly already at a radius of twice the orbital separation. We interpret the circumstellar optical flux as due to a scattering process, with the scatterers located in the extremely puffed-up inner rim of the disk and possibly also in a bipolar outflow seen pole-on. A non-local thermodynamic equilibrium gaseous origin in an inner disk cannot be excluded but is considered highly unlikely. Conclusions: This direct detection of a significant amount of circumbinary light at optical wavelengths poses several significant questions regarding our understanding of both post-AGB binaries and the physics in their circumbinary disks. Although the

  19. The impact of spatial resolution on resolving spatial precipitation patterns in the Himalayas

    NARCIS (Netherlands)

    Bonekamp, P.N.J.; Collier, S.E.; Immerzeel, W.W.

    2017-01-01

    Frequently used gridded meteorological datasets poorly represent precipitation in the Himalaya due to their relatively low spatial resolution and the associated coarse representation of the complex topography. Dynamical downscaling using high-resolution atmospheric models may improve the accuracy

  20. Role of density modulation in the spatially resolved dynamics of strongly confined liquids.

    Science.gov (United States)

    Saw, Shibu; Dasgupta, Chandan

    2016-08-07

    Confinement by walls usually produces a strong modulation in the density of dense liquids near the walls. Using molecular dynamics simulations, we examine the effects of the density modulation on the spatially resolved dynamics of a liquid confined between two parallel walls, using a resolution of a fraction of the interparticle distance in the liquid. The local dynamics is quantified by the relaxation time associated with the temporal autocorrelation function of the local density. We find that this local relaxation time varies in phase with the density modulation. The amplitude of the spatial modulation of the relaxation time can be quite large, depending on the characteristics of the wall and thermodynamic parameters of the liquid. To disentangle the effects of confinement and density modulation on the spatially resolved dynamics, we compare the dynamics of a confined liquid with that of an unconfined one in which a similar density modulation is induced by an external potential. We find several differences indicating that density modulation alone cannot account for all the features seen in the spatially resolved dynamics of confined liquids. We also examine how the dynamics near a wall depends on the separation between the two walls and show that the features seen in our simulations persist in the limit of large wall separation.

  1. A radially accessible tubular in situ X-ray cell for spatially resolved operando scattering and spectroscopic studies of electrochemical energy storage devices

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hao; Allan, Phoebe K.; Borkiewicz, Olaf J.; Kurtz, Charles; Grey, Clare P.; Chapman, Karena W.; Chupas, Peter J.

    2016-09-16

    A tubularoperandoelectrochemical cell has been developed to allow spatially resolved X-ray scattering and spectroscopic measurements of individual cell components, or regions thereof, during device operation. These measurements are enabled by the tubular cell geometry, wherein the X-ray-transparent tube walls allow radial access for the incident and scattered/transmitted X-ray beam; by probing different depths within the electrode stack, the transformation of different components or regions can be resolved. The cell is compatible with a variety of synchrotron-based scattering, absorption and imaging methodologies. The reliability of the electrochemical cell and the quality of the resulting X-ray scattering and spectroscopic data are demonstrated for two types of energy storage: the evolution of the distribution of the state of charge of an Li-ion battery electrode during cycling is documented using X-ray powder diffraction, and the redistribution of ions between two porous carbon electrodes in an electrochemical double-layer capacitor is documented using X-ray absorption near-edge spectroscopy.

  2. Chromatic-free spatially resolved optical emission spectroscopy diagnostics for microplasma

    International Nuclear Information System (INIS)

    Zhu Liguo; Chen Wencong; Zhu Ximing; Pu Yikang; Li Zeren

    2009-01-01

    A chromatic-free spatially resolved diagnostic system for microplasma measurement is proposed and demonstrated, which consists of an optical chromatic-free microscope mirror system, an electron multiplying charge coupled device (EMCCD), and bandpass filters. The diagnostic system free of chromatic aberrations with a spatial resolution of about 6 μm is achieved. The factors that limit the resolution of this diagnostic system have been analyzed, which are optical diffraction, the pixel size of the EMCCD, and the thickness of the microplasma. In this paper, the optimal condition for achieving a maximum resolution power has been analyzed. With this diagnostic system, we revealed the spatial nonuniformity of a microwave atmospheric-pressure argon microplasma. Furthermore, the spatial distribution of the time-averaged effective electron temperature has been estimated from the intensity distributions of 750.4 and 415.8 nm emissions.

  3. Spatially resolved acoustic spectroscopy for rapid imaging of material microstructure and grain orientation

    International Nuclear Information System (INIS)

    Smith, Richard J; Li, Wenqi; Coulson, Jethro; Clark, Matt; Somekh, Michael G; Sharples, Steve D

    2014-01-01

    Measuring the grain structure of aerospace materials is very important to understand their mechanical properties and in-service performance. Spatially resolved acoustic spectroscopy is an acoustic technique utilizing surface acoustic waves to map the grain structure of a material. When combined with measurements in multiple acoustic propagation directions, the grain orientation can be obtained by fitting the velocity surface to a model. The new instrument presented here can take thousands of acoustic velocity measurements per second. The spatial and velocity resolution can be adjusted by simple modification to the system; this is discussed in detail by comparison of theoretical expectations with experimental data. (paper)

  4. Spatially Resolving Ocean Color and Sediment Dispersion in River Plumes, Coastal Systems, and Continental Shelf Waters

    Science.gov (United States)

    Aurin, Dirk Alexander; Mannino, Antonio; Franz, Bryan

    2013-01-01

    Satellite remote sensing of ocean color in dynamic coastal, inland, and nearshorewaters is impeded by high variability in optical constituents, demands specialized atmospheric correction, and is limited by instrument sensitivity. To accurately detect dispersion of bio-optical properties, remote sensors require ample signal-to-noise ratio (SNR) to sense small variations in ocean color without saturating over bright pixels, an atmospheric correction that can accommodate significantwater-leaving radiance in the near infrared (NIR), and spatial and temporal resolution that coincides with the scales of variability in the environment. Several current and historic space-borne sensors have met these requirements with success in the open ocean, but are not optimized for highly red-reflective and heterogeneous waters such as those found near river outflows or in the presence of sediment resuspension. Here we apply analytical approaches for determining optimal spatial resolution, dominant spatial scales of variability ("patches"), and proportions of patch variability that can be resolved from four river plumes around the world between 2008 and 2011. An offshore region in the Sargasso Sea is analyzed for comparison. A method is presented for processing Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua and Terra imagery including cloud detection, stray lightmasking, faulty detector avoidance, and dynamic aerosol correction using short-wave- and near-infrared wavebands in extremely turbid regions which pose distinct optical and technical challenges. Results showthat a pixel size of approx. 520 mor smaller is generally required to resolve spatial heterogeneity in ocean color and total suspended materials in river plumes. Optimal pixel size increases with distance from shore to approx. 630 m in nearshore regions, approx 750 m on the continental shelf, and approx. 1350 m in the open ocean. Greater than 90% of the optical variability within plume regions is resolvable with

  5. The PyCASSO database: spatially resolved stellar population properties for CALIFA galaxies

    Science.gov (United States)

    de Amorim, A. L.; García-Benito, R.; Cid Fernandes, R.; Cortijo-Ferrero, C.; González Delgado, R. M.; Lacerda, E. A. D.; López Fernández, R.; Pérez, E.; Vale Asari, N.

    2017-11-01

    The Calar Alto Legacy Integral Field Area (CALIFA) survey, a pioneer in integral field spectroscopy legacy projects, has fostered many studies exploring the information encoded on the spatially resolved data on gaseous and stellar features in the optical range of galaxies. We describe a value-added catalogue of stellar population properties for CALIFA galaxies analysed with the spectral synthesis code starlight and processed with the pycasso platform. Our public database (http://pycasso.ufsc.br/, mirror at http://pycasso.iaa.es/) comprises 445 galaxies from the CALIFA Data Release 3 with COMBO data. The catalogue provides maps for the stellar mass surface density, mean stellar ages and metallicities, stellar dust attenuation, star formation rates, and kinematics. Example applications both for individual galaxies and for statistical studies are presented to illustrate the power of this data set. We revisit and update a few of our own results on mass density radial profiles and on the local mass-metallicity relation. We also show how to employ the catalogue for new investigations, and show a pseudo Schmidt-Kennicutt relation entirely made with information extracted from the stellar continuum. Combinations to other databases are also illustrated. Among other results, we find a very good agreement between star formation rate surface densities derived from the stellar continuum and the H α emission. This public catalogue joins the scientific community's effort towards transparency and reproducibility, and will be useful for researchers focusing on (or complementing their studies with) stellar properties of CALIFA galaxies.

  6. Spatially resolved characterization of biogenic manganese oxideproduction within a bacterial biofilm

    Energy Technology Data Exchange (ETDEWEB)

    Toner, Brandy; Fakra, Sirine; Villalobos, Mario; Warwick, Tony; Sposito, Garrison

    2004-10-01

    Pseudomonas putida strain MnB1, a biofilm forming bacteria, was used as a model for the study of bacterial Mn oxidation in freshwater and soil environments. The oxidation of Mn{sub (aq)}{sup +2} by P. putida was characterized by spatially and temporally resolving the oxidation state of Mn in the presence of a bacterial biofilm using scanning transmission x-ray microscopy (STXM) combined with near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the Mn-L{sub 2,3} absorption edges. Subsamples were collected from growth flasks containing 0.1 mM and 1 mM total Mn at 16, 24, 36 and 48 hours after inoculation. Immediately after collection, the unprocessed hydrated subsamples were imaged at 40 nm resolution. Manganese NEXAFS spectra were extracted from x-ray energy sequences of STXM images (stacks) and fit with linear combinations of well characterized reference spectra to obtain quantitative relative abundances of Mn(II), Mn(III) and Mn(IV). Careful consideration was given to uncertainty in the normalization of the reference spectra, choice of reference compounds, and chemical changes due to radiation damage. The STXM results confirm that Mn{sub (aq)}{sup +2} was removed from solution by P. putida and was concentrated as Mn(III) and Mn(IV) immediately adjacent to the bacterial cells. The Mn precipitates were completely enveloped by bacterial biofilm material. The distribution of Mn oxidation states was spatially heterogeneous within and between the clusters of bacterial cells. Scanning transmission x-ray microscopy is a promising tool to advance the study of hydrated interfaces between minerals and bacteria, particularly in cases where the structure of bacterial biofilms needs to be maintained.

  7. Spatially resolved synchrotron radiation induced X-ray fluorescence analyses of rare Rembrandt silverpoint drawings

    International Nuclear Information System (INIS)

    Reiche, I.; Radtke, M.; Berger, A.; Goerner, W.; Merchel, S.; Riesemeier, H.; Bevers, H.

    2006-01-01

    New analyses of a series of very rare silverpoint drawings that were executed by Rembrandt Harmensz. van Rijn (1606-1669) which are kept today in the Kupferstichkabinett (Museum of Prints and Drawings) of the State Museums of Berlin are reported here. Analysis of these drawings requires particular attention because the study has to be fully non-destructive and extremely sensitive. The metal alloy on the paper does not exceed some hundreds of μg/cm 2 . Therefore, synchrotron radiation induced X-ray fluorescence (SR-XRF) is - together with external micro-proton-induced X-ray emission - the only well-suited method for the analyses of metalpoint drawings. In some primary work, about 25 German and Flemish metalpoint drawings were investigated using spatially resolved SR-XRF analysis at the BAMline at BESSY. This study enlarges the existing French-German database of metalpoint drawings dating from the 15th and 16th centuries, as these Rembrandt drawings originate from the 17th century where this graphical technique was even rarer and already obsolete. It also illustrates how SR-XRF analysis can reinforce art historical assumptions on the dating of drawings and their connection. (orig.)

  8. Spatially resolving the dust properties and submillimetre excess in M 33

    Science.gov (United States)

    Relaño, M.; De Looze, I.; Kennicutt, R. C.; Lisenfeld, U.; Dariush, A.; Verley, S.; Braine, J.; Tabatabaei, F.; Kramer, C.; Boquien, M.; Xilouris, M.; Gratier, P.

    2018-05-01

    Context. The relative abundance of the dust grain types in the interstellar medium is directly linked to physical quantities that trace the evolution of galaxies. Because of the poor spatial resolution of the infrared and submillimetre data, we are able to study the dependence of the resolved infrared spectral energy distribution (SED) across regions of the interstellar medium (ISM) with different physical properties in just a few objects. Aims: We aim to study the dust properties of the whole disc of M 33 at spatial scales of 170 pc. This analysis allows us to infer how the relative dust grain abundance changes with the conditions of the ISM, study the existence of a submillimetre excess and look for trends of the gas-to-dust mass ratio (GDR) with other physical properties of the galaxy. Methods: For each pixel in the disc of M 33 we have fitted the infrared SED using a physically motivated dust model that assumes an emissivity index β close to two. We applied a Bayesian statistical method to fit the individual SEDs and derived the best output values from the study of the probability density function of each parameter. We derived the relative amount of the different dust grains in the model, the total dust mass, and the strength of the interstellar radiation field (ISRF) heating the dust at each spatial location. Results: The relative abundance of very small grains tends to increase, and for big grains to decrease, at high values of Hα luminosity. This shows that the dust grains are modified inside the star-forming regions, in agreement with a theoretical framework of dust evolution under different physical conditions. The radial dependence of the GDR is consistent with the shallow metallicity gradient observed in this galaxy. The strength of the ISRF derived in our model correlates with the star formation rate in the galaxy in a pixel by pixel basis. Although this is expected, it is the first time that a correlation between the two quantities has been reported

  9. SDSS IV MaNGA - spatially resolved diagnostic diagrams: a proof that many galaxies are LIERs

    Science.gov (United States)

    Belfiore, Francesco; Maiolino, Roberto; Maraston, Claudia; Emsellem, Eric; Bershady, Matthew A.; Masters, Karen L.; Yan, Renbin; Bizyaev, Dmitry; Boquien, Médéric; Brownstein, Joel R.; Bundy, Kevin; Drory, Niv; Heckman, Timothy M.; Law, David R.; Roman-Lopes, Alexandre; Pan, Kaike; Stanghellini, Letizia; Thomas, Daniel; Weijmans, Anne-Marie; Westfall, Kyle B.

    2016-09-01

    We study the spatially resolved excitation properties of the ionized gas in a sample of 646 galaxies using integral field spectroscopy data from the Sloan Digital Sky Survey IV Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) programme. Making use of Baldwin-Philips-Terlevich diagnostic diagrams we demonstrate the ubiquitous presence of extended (kpc scale) low-ionization emission-line regions (LIERs) in both star-forming and quiescent galaxies. In star-forming galaxies LIER emission can be associated with diffuse ionized gas, most evident as extraplanar emission in edge-on systems. In addition, we identify two main classes of galaxies displaying LIER emission: `central LIER' (cLIER) galaxies, where central LIER emission is spatially extended, but accompanied by star formation at larger galactocentric distances, and `extended LIER' (eLIER) galaxies, where LIER emission is extended throughout the whole galaxy. In eLIER and cLIER galaxies, LIER emission is associated with radially flat, low H α equivalent width of line emission (<3 Å) and stellar population indices demonstrating the lack of young stellar populations, implying that line emission follows tightly the continuum due to the underlying old stellar population. The H α surface brightness radial profiles are always shallower than 1/r2 and the line ratio [O III] λ5007/[O II] λλ3727,29 (a tracer of the ionization parameter of the gas) shows a flat gradient. This combined evidence strongly supports the scenario in which LIER emission is not due to a central point source but to diffuse stellar sources, the most likely candidates being hot, evolved (post-asymptotic giant branch) stars. Shocks are observed to play a significant role in the ionization of the gas only in rare merging and interacting systems.

  10. Spatially resolved spectroscopy analysis of the XMM-Newton large program on SN1006

    Science.gov (United States)

    Li, Jiang-Tao; Decourchelle, Anne; Miceli, Marco; Vink, Jacco; Bocchino, Fabrizio

    2016-04-01

    We perform analysis of the XMM-Newton large program on SN1006 based on our newly developed methods of spatially resolved spectroscopy analysis. We extract spectra from low and high resolution meshes. The former (3596 meshes) is used to roughly decompose the thermal and non-thermal components and characterize the spatial distributions of different parameters, such as temperature, abundances of different elements, ionization age, and electron density of the thermal component, as well as photon index and cutoff frequency of the non-thermal component. On the other hand, the low resolution meshes (583 meshes) focus on the interior region dominated by the thermal emission and have enough counts to well characterize the Si lines. We fit the spectra from the low resolution meshes with different models, in order to decompose the multiple plasma components at different thermal and ionization states and compare their spatial distributions. In this poster, we will present the initial results of this project.

  11. DARK MATTER SUBSTRUCTURE DETECTION USING SPATIALLY RESOLVED SPECTROSCOPY OF LENSED DUSTY GALAXIES

    International Nuclear Information System (INIS)

    Hezaveh, Yashar; Holder, Gilbert; Dalal, Neal; Kuhlen, Michael; Marrone, Daniel; Murray, Norman; Vieira, Joaquin

    2013-01-01

    We investigate how strong lensing of dusty, star-forming galaxies (DSFGs) by foreground galaxies can be used as a probe of dark matter halo substructure. We find that spatially resolved spectroscopy of lensed sources allows dramatic improvements to measurements of lens parameters. In particular, we find that modeling of the full, three-dimensional (angular position and radial velocity) data can significantly facilitate substructure detection, increasing the sensitivity of observables to lower mass subhalos. We carry out simulations of lensed dusty sources observed by early ALMA (Cycle 1) and use a Fisher matrix analysis to study the parameter degeneracies and mass detection limits of this method. We find that even with conservative assumptions, it is possible to detect galactic dark matter subhalos of ∼10 8 M ☉ with high significance in most lensed DSFGs. Specifically, we find that in typical DSFG lenses, there is a ∼55% probability of detecting a substructure with M > 10 8 M ☉ with more than 5σ detection significance in each lens, if the abundance of substructure is consistent with previous lensing results. The full ALMA array, with its significantly enhanced sensitivity and resolution, should improve these estimates considerably. Given the sample of ∼100 lenses provided by surveys such as the South Pole Telescope, our understanding of dark matter substructure in typical galaxy halos is poised to improve dramatically over the next few years.

  12. DARK MATTER SUBSTRUCTURE DETECTION USING SPATIALLY RESOLVED SPECTROSCOPY OF LENSED DUSTY GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Hezaveh, Yashar; Holder, Gilbert [Department of Physics, McGill University, 3600 Rue University, Montreal, Quebec H3A 2T8 (Canada); Dalal, Neal [Astronomy Department, University of Illinois at Urbana-Champaign, 1002 West Green Street, Urbana, IL 61801 (United States); Kuhlen, Michael [Theoretical Astrophysics Center, University of California, Berkeley, CA 94720 (United States); Marrone, Daniel [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Murray, Norman [CITA, University of Toronto, 60 St. George Street, Toronto, ON M5S 3H8 (Canada); Vieira, Joaquin [California Institute of Technology, 1200 East California Blvd, MC 249-17, Pasadena, CA 91125 (United States)

    2013-04-10

    We investigate how strong lensing of dusty, star-forming galaxies (DSFGs) by foreground galaxies can be used as a probe of dark matter halo substructure. We find that spatially resolved spectroscopy of lensed sources allows dramatic improvements to measurements of lens parameters. In particular, we find that modeling of the full, three-dimensional (angular position and radial velocity) data can significantly facilitate substructure detection, increasing the sensitivity of observables to lower mass subhalos. We carry out simulations of lensed dusty sources observed by early ALMA (Cycle 1) and use a Fisher matrix analysis to study the parameter degeneracies and mass detection limits of this method. We find that even with conservative assumptions, it is possible to detect galactic dark matter subhalos of {approx}10{sup 8} M{sub Sun} with high significance in most lensed DSFGs. Specifically, we find that in typical DSFG lenses, there is a {approx}55% probability of detecting a substructure with M > 10{sup 8} M{sub Sun} with more than 5{sigma} detection significance in each lens, if the abundance of substructure is consistent with previous lensing results. The full ALMA array, with its significantly enhanced sensitivity and resolution, should improve these estimates considerably. Given the sample of {approx}100 lenses provided by surveys such as the South Pole Telescope, our understanding of dark matter substructure in typical galaxy halos is poised to improve dramatically over the next few years.

  13. Voxel-based measurement sensitivity of spatially resolved near-infrared spectroscopy in layered tissues.

    Science.gov (United States)

    Niwayama, Masatsugu

    2018-03-01

    We quantitatively investigated the measurement sensitivity of spatially resolved spectroscopy (SRS) across six tissue models: cerebral tissue, a small animal brain, the forehead of a fetus, an adult brain, forearm muscle, and thigh muscle. The optical path length in the voxel of the model was analyzed using Monte Carlo simulations. It was found that the measurement sensitivity can be represented as the product of the change in the absorption coefficient and the difference in optical path length in two states with different source-detector distances. The results clarified the sensitivity ratio between the surface layer and the deep layer at each source-detector distance for each model and identified changes in the deep measurement area when one of the detectors was close to the light source. A comparison was made with the results from continuous-wave spectroscopy. The study also identified measurement challenges that arise when the surface layer is inhomogeneous. Findings on the measurement sensitivity of SRS at each voxel and in each layer can support the correct interpretation of measured values when near-infrared oximetry or functional near-infrared spectroscopy is used to investigate different tissue structures. (2018) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE).

  14. Meso-scale defect evaluation of selective laser melting using spatially resolved acoustic spectroscopy.

    Science.gov (United States)

    Hirsch, M; Catchpole-Smith, S; Patel, R; Marrow, P; Li, Wenqi; Tuck, C; Sharples, S D; Clare, A T

    2017-09-01

    Developments in additive manufacturing technology are serving to expand the potential applications. Critical developments are required in the supporting areas of measurement and in process inspection to achieve this. CM247LC is a nickel superalloy that is of interest for use in aerospace and civil power plants. However, it is difficult to process via selective laser melting (SLM) as it suffers from cracking during rapid cooling and solidification. This limits the viability of CM247LC parts created using SLM. To quantify part integrity, spatially resolved acoustic spectroscopy (SRAS) has been identified as a viable non-destructive evaluation technique. In this study, a combination of optical microscopy and SRAS was used to identify and classify the surface defects present in SLM-produced parts. By analysing the datasets and scan trajectories, it is possible to correlate morphological information with process parameters. Image processing was used to quantify porosity and cracking for bulk density measurement. Analysis of surface acoustic wave data showed that an error in manufacture in the form of an overscan occurred. Comparing areas affected by overscan with a bulk material, a change in defect density from 1.17% in the bulk material to 5.32% in the overscan regions was observed, highlighting the need to reduce overscan areas in manufacture.

  15. Meso-scale defect evaluation of selective laser melting using spatially resolved acoustic spectroscopy

    Science.gov (United States)

    Hirsch, M.; Catchpole-Smith, S.; Patel, R.; Marrow, P.; Li, Wenqi; Tuck, C.; Sharples, S. D.; Clare, A. T.

    2017-09-01

    Developments in additive manufacturing technology are serving to expand the potential applications. Critical developments are required in the supporting areas of measurement and in process inspection to achieve this. CM247LC is a nickel superalloy that is of interest for use in aerospace and civil power plants. However, it is difficult to process via selective laser melting (SLM) as it suffers from cracking during rapid cooling and solidification. This limits the viability of CM247LC parts created using SLM. To quantify part integrity, spatially resolved acoustic spectroscopy (SRAS) has been identified as a viable non-destructive evaluation technique. In this study, a combination of optical microscopy and SRAS was used to identify and classify the surface defects present in SLM-produced parts. By analysing the datasets and scan trajectories, it is possible to correlate morphological information with process parameters. Image processing was used to quantify porosity and cracking for bulk density measurement. Analysis of surface acoustic wave data showed that an error in manufacture in the form of an overscan occurred. Comparing areas affected by overscan with a bulk material, a change in defect density from 1.17% in the bulk material to 5.32% in the overscan regions was observed, highlighting the need to reduce overscan areas in manufacture.

  16. Multiple spatially resolved reflection spectroscopy for in vivo determination of carotenoids in human skin and blood

    Science.gov (United States)

    Darvin, Maxim E.; Magnussen, Björn; Lademann, Juergen; Köcher, Wolfgang

    2016-09-01

    Non-invasive measurement of carotenoid antioxidants in human skin is one of the important tasks to investigate the skin physiology in vivo. Resonance Raman spectroscopy and reflection spectroscopy are the most frequently used non-invasive techniques in dermatology and skin physiology. In the present study, an improved method based on multiple spatially resolved reflection spectroscopy (MSRRS) was introduced. The results obtained were compared with those obtained using the ‘gold standard’ resonance Raman spectroscopy method and showed strong correlations for the total carotenoid concentration (R  =  0.83) as well as for lycopene (R  =  0.80). The measurement stability was confirmed to be better than 10% within the total temperature range from 5 °C to  +  30 °C and pressure contact between the skin and the MSRRS sensor from 800 Pa to 18 000 Pa. In addition, blood samples taken from the subjects were analyzed for carotenoid concentrations. The MSRRS sensor was calibrated on the blood carotenoid concentrations resulting in being able to predict with a correlation of R  =  0.79. On the basis of blood carotenoids it could be demonstrated that the MSRRS cutaneous measurements are not influenced by Fitzpatrick skin types I-VI. The MSRRS sensor is commercially available under the brand name biozoom.

  17. Spatially resolved soft x-ray diagnostics in fusion energy research

    International Nuclear Information System (INIS)

    Mlynar, J.; Weinzettl, V.; Imrisek, M.; Loeffelmann, V.

    2013-01-01

    With construction of ITER, the fusion community has progressed into a new stage of research with increased focus on reactor technologies. Corresponding development of diagnostic systems for fusion is required, including research of novel diagnostic methods, validation of radiation hard detectors, and tests of sensors for real-time operation and control, which comprise development of tools for fast data analyses. In parallel, diagnostic systems on running fusion experiments substantially contribute to better understanding of reactor-relevant plasma physics, in particular of energy confinement, plasma stability and transport of impurities. In this respect, spatially resolved Soft X-ray (SXR) diagnostic systems present an interesting case study of development towards reactor-relevant systems. In magnetic confinement fusion research, spatial distribution of SXR radiation with spectral range typically 1 keV - 15 keV is mostly measured by a photosensitive single-row semiconductor elements in a pinhole camera shielded by a beryllium foil. The SXR intensity strongly depends on plasma density, temperature and effective charge, which carry a valuable information on the plasma core physics. Data from SXR diagnostic can be also used for the operation control, among others due to their sensitivity to heavy impurity concentration or to the position of the peak temperature. In order to reconstruct the spatial distribution of SXR plasma emission from the measured line integrated signals, several tomographic methods have been developed and validated. However, the semiconductor elements cannot survive in harsh conditions of future fusion reactors due to radiation damage, which calls for development of radiation hard SXR cameras. In this contribution, role of the SXR diagnostics will be presented in experience and future plans of the Czech tokamak COMPASS (IPP Prague) and the French tokamak TORE SUPRA (CEA Cadarache). In IPP Prague, data from SXR cameras recently contributed to

  18. Spatially resolved chemical analysis of cicada wings using laser-ablation electrospray ionization (LAESI) imaging mass spectrometry (IMS).

    Science.gov (United States)

    Román, Jessica K; Walsh, Callee M; Oh, Junho; Dana, Catherine E; Hong, Sungmin; Jo, Kyoo D; Alleyne, Marianne; Miljkovic, Nenad; Cropek, Donald M

    2018-03-01

    Laser-ablation electrospray ionization (LAESI) imaging mass spectrometry (IMS) is an emerging bioanalytical tool for direct imaging and analysis of biological tissues. Performing ionization in an ambient environment, this technique requires little sample preparation and no additional matrix, and can be performed on natural, uneven surfaces. When combined with optical microscopy, the investigation of biological samples by LAESI allows for spatially resolved compositional analysis. We demonstrate here the applicability of LAESI-IMS for the chemical analysis of thin, desiccated biological samples, specifically Neotibicen pruinosus cicada wings. Positive-ion LAESI-IMS accurate ion-map data was acquired from several wing cells and superimposed onto optical images allowing for compositional comparisons across areas of the wing. Various putative chemical identifications were made indicating the presence of hydrocarbons, lipids/esters, amines/amides, and sulfonated/phosphorylated compounds. With the spatial resolution capability, surprising chemical distribution patterns were observed across the cicada wing, which may assist in correlating trends in surface properties with chemical distribution. Observed ions were either (1) equally dispersed across the wing, (2) more concentrated closer to the body of the insect (proximal end), or (3) more concentrated toward the tip of the wing (distal end). These findings demonstrate LAESI-IMS as a tool for the acquisition of spatially resolved chemical information from fragile, dried insect wings. This LAESI-IMS technique has important implications for the study of functional biomaterials, where understanding the correlation between chemical composition, physical structure, and biological function is critical. Graphical abstract Positive-ion laser-ablation electrospray ionization mass spectrometry coupled with optical imaging provides a powerful tool for the spatially resolved chemical analysis of cicada wings.

  19. Dose calculation for permanent prostate implants incorporating spatially anisotropic linearly time-resolving edema

    International Nuclear Information System (INIS)

    Monajemi, T. T.; Clements, Charles M.; Sloboda, Ron S.

    2011-01-01

    Purpose: The objectives of this study were (i) to develop a dose calculation method for permanent prostate implants that incorporates a clinically motivated model for edema and (ii) to illustrate the use of the method by calculating the preimplant dosimetry error for a reference configuration of 125 I, 103 Pd, and 137 Cs seeds subject to edema-induced motions corresponding to a variety of model parameters. Methods: A model for spatially anisotropic edema that resolves linearly with time was developed based on serial magnetic resonance imaging measurements made previously at our center to characterize the edema for a group of n=40 prostate implant patients [R. S. Sloboda et al., ''Time course of prostatic edema post permanent seed implant determined by magnetic resonance imaging,'' Brachytherapy 9, 354-361 (2010)]. Model parameters consisted of edema magnitude, Δ, and period, T. The TG-43 dose calculation formalism for a point source was extended to incorporate the edema model, thus enabling calculation via numerical integration of the cumulative dose around an individual seed in the presence of edema. Using an even power piecewise-continuous polynomial representation for the radial dose function, the cumulative dose was also expressed in closed analytical form. Application of the method was illustrated by calculating the preimplant dosimetry error, RE preplan , in a 5x5x5 cm 3 volume for 125 I (Oncura 6711), 103 Pd (Theragenics 200), and 131 Cs (IsoRay CS-1) seeds arranged in the Radiological Physics Center test case 2 configuration for a range of edema relative magnitudes (Δ=[0.1,0.2,0.4,0.6,1.0]) and periods (T=[28,56,84] d). Results were compared to preimplant dosimetry errors calculated using a variation of the isotropic edema model developed by Chen et al. [''Dosimetric effects of edema in permanent prostate seed implants: A rigorous solution,'' Int. J. Radiat. Oncol., Biol., Phys. 47, 1405-1419 (2000)]. Results: As expected, RE preplan for our edema model

  20. Spatially resolved density and ionization measurements of shocked foams using x-ray fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    MacDonald, M. J.; Keiter, P. A.; Montgomery, D. S.; Scott, H. A.; Biener, M. M.; Fein, J. R.; Fournier, K. B.; Gamboa, E. J.; Kemp, G. E.; Klein, S. R.; Kuranz, C. C.; LeFevre, H. J.; Manuel, M. J. -E.; Wan, W. C.; Drake, R. P.

    2016-09-28

    We present experiments at the Trident laser facility demonstrating the use of x-ray fluorescence (XRF) to simultaneously measure density, ionization state populations, and electron temperature in shocked foams. An imaging x-ray spectrometer obtained spatially resolved measurements of Ti K-α emission. Density profiles were measured from K-α intensity. Ti ionization state distributions and electron temperatures were inferred by fitting K-α spectra to spectra from CRETIN simulations. This work shows that XRF provides a powerful tool to complement other diagnostics to make equation of state measurements of shocked materials containing a suitable tracer element.

  1. CO2 laser interferometer for temporally and spatially resolved electron density measurements

    Science.gov (United States)

    Brannon, P. J.; Gerber, R. A.; Gerardo, J. B.

    1982-09-01

    A 10.6-μm Mach-Zehnder interferometer has been constructed to make temporally and spatially resolved measurements of electron densities in plasmas. The device uses a pyroelectric vidicon camera and video memory to record and display the two-dimensional fringe pattern and a Pockels cell to limit the pulse width of the 10.6-μm radiation. A temporal resolution of 14 ns has been demonstrated. The relative sensitivity of the device for electron density measurements is 2×1015 cm-2 (the line integral of the line-of-sight length and electron density), which corresponds to 0.1 fringe shift.

  2. CO2 laser interferometer for temporally and spatially resolved electron density measurements

    International Nuclear Information System (INIS)

    Brannon, P.J.; Gerber, R.A.; Gerardo, J.B.

    1982-01-01

    A 10.6-μm Mach--Zehnder interferometer has been constructed to make temporally and spatially resolved measurements of electron densities in plasmas. The device uses a pyroelectric vidicon camera and video memory to record and display the two-dimensional fringe pattern and a Pockels cell to limit the pulse width of the 10.6-μm radiation. A temporal resolution of 14 ns has been demonstrated. The relative sensitivity of the device for electron density measurements is 2 x 10 15 cm -2 (the line integral of the line-of-sight length and electron density), which corresponds to 0.1 fringe shift

  3. Spatially resolved charge exchange flux calculations on the Toroidal Pumped Limiter of Tore Supra

    International Nuclear Information System (INIS)

    Marandet, Y.; Tsitrone, E.; Boerner, P.; Reiter, D.; Beaute, A.; Delchambre, E.; Escarguel, A.; Brezinsek, S.; Genesio, P.; Gunn, J.; Monier-Garbet, P.; Mitteau, R.; Pegourie, B.

    2009-01-01

    A spatially resolved calculation of the charge exchange particle and energy fluxes on the Toroidal Pumped Limiter (TPL) of Tore Supra is presented, as a first step towards a better understanding and modelling of carbon erosion, migration, as well as deuterium codeposition and bulk diffusion of deuterium in Tore Supra. The results are obtained with the EIRENE code run in a 3D geometry. Physical and chemical erosion maps on the TPL are calculated, and the contribution of neutrals to erosion, especially in the self-shadowed area, is calculated.

  4. Spatially resolved measurements of the magnetocaloric effect and the local magnetic field using thermography

    DEFF Research Database (Denmark)

    Christensen, Dennis; Bjørk, Rasmus; Nielsen, Kaspar Kirstein

    2010-01-01

    The magnetocaloric effect causes a magnetic material to change temperature upon application of a magnetic field. Here, spatially resolved measurements of the adiabatic temperature change are performed on a plate of gadolinium using thermography. The adiabatic temperature change is used to extract...... the corresponding change in the local magnetic field strength. The measured temperature change and local magnetic field strength are compared to results obtained with a numerical model, which takes demagnetization into account and employs experimental data....

  5. AgesGalore-A software program for evaluating spatially resolved luminescence data

    International Nuclear Information System (INIS)

    Greilich, S.; Harney, H.-L.; Woda, C.; Wagner, G.A.

    2006-01-01

    Low-light luminescence is usually recorded by photomultiplier tubes (PMTs) yielding integrated photon-number data. Highly sensitive CCD (charged coupled device) detectors allow for the spatially resolved recording of luminescence. The resulting two-dimensional images require suitable software for data processing. We present a recently developed software program specially designed for equivalent-dose evaluation in the framework of optically stimulated luminescence (OSL) dating. The software is capable of appropriate CCD data handling, parameter estimation using a Bayesian approach, and the pixel-wise fitting of functions for time and dose dependencies to the luminescence signal. The results of the fitting procedure and the equivalent-dose evaluation can be presented and analyzed both as spatial and as frequency distributions

  6. Collimated dual species oven source and its characterisation via spatially resolved fluorescence spectroscopy

    Science.gov (United States)

    Cooper, N.; Da Ros, E.; Nute, J.; Baldolini, D.; Jouve, P.; Hackermüller, L.; Langer, M.

    2018-03-01

    We describe the design, construction and characterisation of a collimated, dual-species oven source for generating intense beams of lithium and caesium in UHV environments. Our design produces full beam overlap for the two species. Using an aligned microtube array the FWHM of the output beam is restricted to  ˜75 milliradians, with an estimated axial brightness of 3.6× 1014 atoms s-1 sr-1 for Li and 7.4× 1015 atoms s-1 sr-1 for Cs. We measure the properties of the output beam using a spatially-resolved fluorescence technique, which allows for the extraction of additional information not accessible without spatial resolution.

  7. Diffusion and spatially resolved NMR in Berea and Venezuelan oil reservoir rocks.

    Science.gov (United States)

    Murgich, J; Corti, M; Pavesi, L; Voltini, F

    1992-01-01

    Conventional and spatially resolved proton NMR and relaxation measurements are used in order to study the molecular motions and the equilibrium and nonequilibrium diffusion of oils in Berea sandstone and Venezuelan reservoir rocks. In the water-saturated Berea a single line with T*2 congruent to 150 microseconds is observed, while the relaxation recovery is multiexponential. In an oil reservoir rock (Ful 13) a single narrow line is present while a distribution of relaxation rates is evidenced from the recovery plots. On the contrary, in the Ful 7 sample (extracted at a deeper depth in a different zone) two NMR components are present, with 3.5 and 30 KHz linewidths, and the recovery plot exhibits biexponential law. No echo signal could be reconstructed in the oil reservoir rocks. These findings can be related to the effects in the micropores, where motions at very low frequency can occur in a thin layer. From a comparison of the diffusion constant in water-saturated Berea, D congruent to 5*10(-6) cm2/sec, with the ones in model systems, the average size of the pores is estimated around 40 A. The density profiles at the equilibrium show uniform distribution of oils or of water, and the relaxation rates appear independent from the selected slice. The nonequilibrium diffusion was studied as a function of time in a Berea cylinder with z axis along H0, starting from a thin layer of oil at the base, and detecting the spin density profiles d(z,t) with slice-selection techniques. Simultaneously, the values of T1's were measured locally, and the distribution of the relaxation rates was observed to be present in any slice.(ABSTRACT TRUNCATED AT 250 WORDS)

  8. A High-mass Protobinary System with Spatially Resolved Circumstellar Accretion Disks and Circumbinary Disk

    Energy Technology Data Exchange (ETDEWEB)

    Kraus, S.; Kluska, J.; Kreplin, A.; Bate, M.; Harries, T. J.; Hone, E.; Anugu, A. [School of Physics, Astrophysics Group, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom); Hofmann, K.-H.; Weigelt, G. [Max-Planck-Institut für Radioastronomie, Auf dem Hügel 69, D-53121 Bonn (Germany); Monnier, J. D. [Department of Astronomy, University of Michigan, 311 West Hall, 1085 South University Avenue, Ann Arbor, MI 48109 (United States); De Wit, W. J. [ESO, Alonso de Cordova 3107, Vitacura, Santiago 19 (Chile); Wittkowski, M., E-mail: skraus@astro.ex.ac.uk [ESO, Karl-Schwarzschild-Str. 2, D-85748 Garching bei München (Germany)

    2017-01-20

    High-mass multiples might form via fragmentation of self-gravitational disks or alternative scenarios such as disk-assisted capture. However, only a few observational constraints exist on the architecture and disk structure of high-mass protobinaries and their accretion properties. Here, we report the discovery of a close (57.9 ± 0.2 mas = 170 au) high-mass protobinary, IRAS17216-3801, where our VLTI/GRAVITY+AMBER near-infrared interferometry allows us to image the circumstellar disks around the individual components with ∼3 mas resolution. We estimate the component masses to ∼20 and ∼18 M {sub ⊙} and find that the radial intensity profiles can be reproduced with an irradiated disk model, where the inner regions are excavated of dust, likely tracing the dust sublimation region in these disks. The circumstellar disks are strongly misaligned with respect to the binary separation vector, which indicates that the tidal forces did not have time to realign the disks, pointing toward a young dynamical age of the system. We constrain the distribution of the Br γ and CO-emitting gas using VLTI/GRAVITY spectro-interferometry and VLT/CRIRES spectro-astrometry and find that the secondary is accreting at a higher rate than the primary. VLT/NACO imaging shows L ′-band emission on (3–4)× larger scales than the binary separation, matching the expected dynamical truncation radius for the circumbinary disk. The IRAS17216-3801 system is ∼3× more massive and ∼5× more compact than other high-mass multiplies imaged at infrared wavelength and the first high-mass protobinary system where circumstellar and circumbinary dust disks could be spatially resolved. This opens exciting new opportunities for studying star–disk interactions and the role of multiplicity in high-mass star formation.

  9. Novel technique for spatially resolved imaging of molecular bond orientations using x-ray birefringence

    Energy Technology Data Exchange (ETDEWEB)

    Sutter, John P., E-mail: john.sutter@diamond.ac.uk; Dolbnya, Igor P.; Collins, Stephen P. [Diamond Light Source Ltd, Harwell Science and Innovation Campus, Chilton, Didcot, Oxfordshire OX11 0DE (United Kingdom); Harris, Kenneth D. M., E-mail: HarrisKDM@cardiff.ac.uk; Edwards-Gau, Gregory R.; Kariuki, Benson M. [School of Chemistry, Cardiff University, Park Place, Cardiff CF10 3AT (United Kingdom); Palmer, Benjamin A. [Department of Structural Biology, Weizmann Institute of Science, 234 Herzl St., Rehovot 7610001 (Israel)

    2016-07-27

    Birefringence has been observed in anisotropic materials transmitting linearly polarized X-ray beams tuned close to an absorption edge of a specific element in the material. Synchrotron bending magnets provide X-ray beams of sufficiently high brightness and cross section for spatially resolved measurements of birefringence. The recently developed X-ray Birefringence Imaging (XBI) technique has been successfully applied for the first time using the versatile test beamline B16 at Diamond Light Source. Orientational distributions of the C–Br bonds of brominated “guest” molecules within crystalline “host” tunnel structures (in thiourea or urea inclusion compounds) have been studied using linearly polarized incident X-rays near the Br K-edge. Imaging of domain structures, changes in C–Br bond orientations associated with order-disorder phase transitions, and the effects of dynamic averaging of C–Br bond orientations have been demonstrated. The XBI setup uses a vertically deflecting high-resolution double-crystal monochromator upstream from the sample and a horizontally deflecting single-crystal polarization analyzer downstream, with a Bragg angle as close as possible to 45°. In this way, the ellipticity and rotation angle of the polarization of the beam transmitted through the sample is measured as in polarizing optical microscopy. The theoretical instrumental background calculated from the elliptical polarization of the bending-magnet X-rays, the imperfect polarization discrimination of the analyzer, and the correlation between vertical position and photon energy introduced by the monochromator agrees well with experimental observations. The background is calculated analytically because the region of X-ray phase space selected by this setup is sampled inefficiently by standard methods.

  10. Noncontact blood species identification method based on spatially resolved near-infrared transmission spectroscopy

    Science.gov (United States)

    Zhang, Linna; Sun, Meixiu; Wang, Zhennan; Li, Hongxiao; Li, Yingxin; Li, Gang; Lin, Ling

    2017-09-01

    The inspection and identification of whole blood are crucially significant for import-export ports and inspection and quarantine departments. In our previous research, we proved Near-Infrared diffuse transmitted spectroscopy method was potential for noninvasively identifying three blood species, including macaque, human and mouse, with samples measured in the cuvettes. However, in open sampling cases, inspectors may be endangered by virulence factors in blood samples. In this paper, we explored the noncontact measurement for classification, with blood samples measured in the vacuum blood vessels. Spatially resolved near-infrared spectroscopy was used to improve the prediction accuracy. Results showed that the prediction accuracy of the model built with nine detection points was more than 90% in identification between all five species, including chicken, goat, macaque, pig and rat, far better than the performance of the model built with single-point spectra. The results fully supported the idea that spatially resolved near-infrared spectroscopy method can improve the prediction ability, and demonstrated the feasibility of this method for noncontact blood species identification in practical applications.

  11. A spatially and temporally resolved model of the electricity grid – Economic vs environmental dispatch

    International Nuclear Information System (INIS)

    Razeghi, Ghazal; Brouwer, Jack; Samuelsen, Scott

    2016-01-01

    Highlights: • A spatially and temporally resolved dispatch model is developed. • MCP and average price of electricity are determined for 2050 base case. • Economic and environmental dispatch strategies are assessed. • Environmental dispatch results in significant NO_x reduction and higher prices. • A combination of economic and environmental strategies is the preferred method. - Abstract: Substantial changes need to occur in the electricity generation sector in order to address greenhouse gas and urban air quality goals. These goals, combined with increasing energy prices, have led to elevated interest in alternative, low to zero carbon and pollutant emission technologies in this sector. The challenge is to assess the impacts of various technologies, policies, and market practices in order to develop a roadmap to meet energy and environmental goals. To this end, a spatially and temporally resolved resource dispatch model is developed that simulates an electricity market while taking into account physical constraints associated with various components of an electricity grid. Multiple technology simulation modules are developed to provide inputs to the model. The model is used to design a market-based grid, and to develop and evaluate different dispatch strategies. To maintain the system cost at acceptable levels and reduce emissions, the results reveal that the best approach is a combination of economic and environmental dispatch strategies. The methodology and the tools developed provide a means to examine various aspects of future scenarios and their impacts on different sectors, and can be used for both decision making and planning.

  12. Scanning photoelectron microscope for nanoscale three-dimensional spatial-resolved electron spectroscopy for chemical analysis.

    Science.gov (United States)

    Horiba, K; Nakamura, Y; Nagamura, N; Toyoda, S; Kumigashira, H; Oshima, M; Amemiya, K; Senba, Y; Ohashi, H

    2011-11-01

    In order to achieve nondestructive observation of the three-dimensional spatially resolved electronic structure of solids, we have developed a scanning photoelectron microscope system with the capability of depth profiling in electron spectroscopy for chemical analysis (ESCA). We call this system 3D nano-ESCA. For focusing the x-ray, a Fresnel zone plate with a diameter of 200 μm and an outermost zone width of 35 nm is used. In order to obtain the angular dependence of the photoelectron spectra for the depth-profile analysis without rotating the sample, we adopted a modified VG Scienta R3000 analyzer with an acceptance angle of 60° as a high-resolution angle-resolved electron spectrometer. The system has been installed at the University-of-Tokyo Materials Science Outstation beamline, BL07LSU, at SPring-8. From the results of the line-scan profiles of the poly-Si/high-k gate patterns, we achieved a total spatial resolution better than 70 nm. The capability of our system for pinpoint depth-profile analysis and high-resolution chemical state analysis is demonstrated. © 2011 American Institute of Physics

  13. Spatially resolved x-ray fluorescence spectroscopy of beryllium capsule implosions at the NIF

    Science.gov (United States)

    MacDonald, M. J.; Bishel, D. T.; Saunders, A. M.; Scott, H. A.; Kyrala, G.; Kline, J.; MacLaren, S.; Thorn, D. B.; Yi, S. A.; Zylstra, A. B.; Falcone, R. W.; Doeppner, T.

    2017-10-01

    Beryllium ablators used in indirectly driven inertial confinement fusion implosions are doped with copper to prevent preheat of the cryogenic hydrogen fuel. Here, we present analysis of spatially resolved copper K- α fluorescence spectra from the beryllium ablator layer. It has been shown that K- α fluorescence spectroscopy can be used to measure plasma conditions of partially ionized dopants in high energy density systems. In these experiments, K-shell vacancies in the copper dopant are created by the hotspot emission at stagnation, resulting in K-shell fluorescence at bang time. Spatially resolved copper K- α emission spectra are compared to atomic kinetics and radiation code simulations to infer density and temperature profiles. This work was supported by the US DOE under Grant No. DE-NA0001859, under the auspices of the US DOE by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344, and by Los Alamos National Laboratory under contract DE-AC52-06NA52396.

  14. Spatially resolved x-ray laser spectra and demonstration of gain in nickel-like systems

    Energy Technology Data Exchange (ETDEWEB)

    Whelan, D.A.; Keane, C.J.; MacGowan, B.J.; Matthews, D.L.; Trebes, J.E.; Eckart, M.J.

    1987-09-25

    A recent series of experiments have provided spatially resolved near field images of several candidate x-ray lasing transition in neon-like, nickel-like, and hydrogen-like ions from laser-produced plasmas. From these time-gated, spatially, and spectrally resolved measurements the source size for the J = 0 - 1 and the J = 2 - 1 transitions in Ne-like selenium have been determined. Source regions as small as 50 ..mu..m have been observed on transitions with gain-length products >9. In addition, we have obtained the first experimental evidence for the amplification of spontaneous emission in the nickel-like ions of europium and ytterbium. Gains of order 1 cm/sup -1/ and gain-length products of up to 3.8 are observed on the J = 0 - 1, 4d-4p transitions in Eu + 35 at 65.26 and 71.00 A. Analogous transitions in Yb = +42 have been identified and some evidence for ASE has been observed. 7 refs., 11 figs.

  15. Spatially resolved X-ray laser spectra and demonstration of gain in nickel-like systems

    International Nuclear Information System (INIS)

    Whelan, D.A.; Keane, C.J.; MacGowan, B.J.; Matthews, D.L.; Trebes, J.E.; Eckart, M.J.

    1987-01-01

    A recent series of experiments have provided spatially resolved near field images of several candidate x-ray lasing transition in neon-like, nickel-like, and hydrogen-like ions from laser-produced plasmas. From these time-gated, spatially, and spectrally resolved measurements the source size for the J=0-1 and the J=2-1 transitions in Ne-like selenium have been determined. Source regions as small as 50 μm have been observed on transitions with gain-length products >9. In addition, the authors have obtained the first experimental evidence for the amplification of spontaneous emission in the nickel-like ions of europium and ytterbium. Gains of order 1 cm/sup -1/ and gain-length products of up to 3.8 are observed on the J=0-1,4d-4p transitions in Eu/sup +35/ at 65.83 and 71.00A. Analogous transitions in Yb/sup +42/ have been identified and some evidence for ASE has been observed

  16. Last millennium Northern Hemisphere summer temperatures from tree rings: Part II, spatially resolved reconstructions

    Science.gov (United States)

    Anchukaitis, Kevin J.; Wilson, Rob; Briffa, Keith R.; Büntgen, Ulf; Cook, Edward R.; D'Arrigo, Rosanne; Davi, Nicole; Esper, Jan; Frank, David; Gunnarson, Björn E.; Hegerl, Gabi; Helama, Samuli; Klesse, Stefan; Krusic, Paul J.; Linderholm, Hans W.; Myglan, Vladimir; Osborn, Timothy J.; Zhang, Peng; Rydval, Milos; Schneider, Lea; Schurer, Andrew; Wiles, Greg; Zorita, Eduardo

    2017-05-01

    Climate field reconstructions from networks of tree-ring proxy data can be used to characterize regional-scale climate changes, reveal spatial anomaly patterns associated with atmospheric circulation changes, radiative forcing, and large-scale modes of ocean-atmosphere variability, and provide spatiotemporal targets for climate model comparison and evaluation. Here we use a multiproxy network of tree-ring chronologies to reconstruct spatially resolved warm season (May-August) mean temperatures across the extratropical Northern Hemisphere (40-90°N) using Point-by-Point Regression (PPR). The resulting annual maps of temperature anomalies (750-1988 CE) reveal a consistent imprint of volcanism, with 96% of reconstructed grid points experiencing colder conditions following eruptions. Solar influences are detected at the bicentennial (de Vries) frequency, although at other time scales the influence of insolation variability is weak. Approximately 90% of reconstructed grid points show warmer temperatures during the Medieval Climate Anomaly when compared to the Little Ice Age, although the magnitude varies spatially across the hemisphere. Estimates of field reconstruction skill through time and over space can guide future temporal extension and spatial expansion of the proxy network.

  17. Spatially Resolved Temperature and Water Vapor Concentration Distributions in Supersonic Combustion Facilities by TDLAT

    Science.gov (United States)

    Busa, K. M.; McDaniel J. C.; Diskin, G. S.; DePiro, M. J.; Capriotti, D. P.; Gaffney, R. L.

    2012-01-01

    Detailed knowledge of the internal structure of high-enthalpy flows can provide valuable insight to the performance of scramjet combustors. Tunable Diode Laser Absorption Spectroscopy (TDLAS) is often employed to measure temperature and species concentration. However, TDLAS is a path-integrated line-of-sight (LOS) measurement, and thus does not produce spatially resolved distributions. Tunable Diode Laser Absorption Tomography (TDLAT) is a non-intrusive measurement technique for determining two-dimensional spatially resolved distributions of temperature and species concentration in high enthalpy flows. TDLAT combines TDLAS with tomographic image reconstruction. More than 2500 separate line-of-sight TDLAS measurements are analyzed in order to produce highly resolved temperature and species concentration distributions. Measurements have been collected at the University of Virginia's Supersonic Combustion Facility (UVaSCF) as well as at the NASA Langley Direct-Connect Supersonic Combustion Test Facility (DCSCTF). Due to the UVaSCF s unique electrical heating and ability for vitiate addition, measurements collected at the UVaSCF are presented as a calibration of the technique. Measurements collected at the DCSCTF required significant modifications to system hardware and software designs due to its larger measurement area and shorter test duration. Tomographic temperature and water vapor concentration distributions are presented from experimentation on the UVaSCF operating at a high temperature non-reacting case for water vitiation level of 12%. Initial LOS measurements from the NASA Langley DCSCTF operating at an equivalence ratio of 0.5 are also presented. Results show the capability of TDLAT to adapt to several experimental setups and test parameters.

  18. Improved algorithm for estimating optical properties of food and biological materials using spatially-resolved diffuse reflectance

    Science.gov (United States)

    In this research, the inverse algorithm for estimating optical properties of food and biological materials from spatially-resolved diffuse reflectance was optimized in terms of data smoothing, normalization and spatial region of reflectance profile for curve fitting. Monte Carlo simulation was used ...

  19. Spatially resolved element analysis of historical violin varnishes by use of muPIXE.

    Science.gov (United States)

    von Bohlen, Alex; Röhrs, Stefan; Salomon, Joseph

    2007-02-01

    External muPIXE has been used for characterisation of small samples of varnish from historical violins, and pieces of varnished wood from historical and modern stringed instruments. To obtain spatially resolved information about the distribution of elements across the varnish layers single-spot analysis, line-scans, and area-mapping were performed. Local resolution of approximately 20 mum was obtained from the 3 MeV, 1 nA proton micro-probe. Results from simultaneous multi-element determination of Na, Mg, Al, Si, P, S, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Br, Rb, Sr, Ag, Cd, Sn, Ba, and Pb in historical varnishes are presented. Semi-quantitative evaluation of line-scans recorded on diverse historical varnishes is reported. The applied method is discussed in detail and the results obtained are critically reviewed and compared with those in the literature.

  20. Heat treatment of bovine bone preceding spatially resolved texture investigation by neutron diffraction

    International Nuclear Information System (INIS)

    Benmarouane, Abdelilah; Hansen, Thomas; Lodini, Alain

    2004-01-01

    Bone is a composite material of collagen and porous hydroxyapatite crystallites, aligned parallel to each other, with the c-axis parallel to the long axis of the fibre. Its texture and crystallinity has been investigated by means of neutron diffraction, using the high intensity 2-axis diffractometer D20 at ILL in particular. We show spatially resolved pole figures on a composite sample of two bone pieces of different preferred orientation. We have selected the (1 1 1) reflection, which is nearly not affected by texture to characterise the crystallinity index, and (0 0 2) to show the texture because the c-axes of hydroxyapatite crystallites is directed along the axis of the bone

  1. Spatially resolved positron annihilation spectroscopy on friction stir weld induced defects.

    Science.gov (United States)

    Hain, Karin; Hugenschmidt, Christoph; Pikart, Philip; Böni, Peter

    2010-04-01

    A friction stir welded (FSW) Al alloy sample was investigated by Doppler broadening spectroscopy (DBS) of the positron annihilation line. The spatially resolved defect distribution showed that the material in the joint zone becomes completely annealed during the welding process at the shoulder of the FSW tool, whereas at the tip, annealing is prevailed by the deterioration of the material due to the tool movement. This might be responsible for the increased probability of cracking in the heat affected zone of friction stir welds. Examination of a material pairing of steel S235 and the Al alloy Silafont36 by coincident Doppler broadening spectroscopy (CDBS) indicates the formation of annealed steel clusters in the Al alloy component of the sample. The clear visibility of Fe in the CDB spectra is explained by the very efficient trapping at the interface between steel cluster and bulk.

  2. Spatially resolved single crystal x-ray spectropolarimetry of wire array z-pinch plasmas.

    Science.gov (United States)

    Wallace, M S; Haque, S; Neill, P; Pereira, N R; Presura, R

    2018-01-01

    A recently developed single-crystal x-ray spectropolarimeter has been used to record paired sets of polarization-dependent and axially resolved x-ray spectra emitted by wire array z-pinches. In this measurement, two internal planes inside a suitable crystal diffract the x-rays into two perpendicular directions that are normal to each other, thereby separating incident x-rays into their linearly polarized components. This paper gives considerations for fielding the instrument on extended sources. Results from extended sources are difficult to interpret because generally the incident x-rays are not separated properly by the crystal. This difficulty is mitigated by using a series of collimating slits to select incident x-rays that propagate in a plane of symmetry between the polarization-splitting planes. The resulting instrument and some of the spatially resolved polarized x-ray spectra recorded for a 1-MA aluminum wire array z-pinch at the Nevada Terawatt Facility at the University of Nevada, Reno will be presented.

  3. Dwarf galaxies with ionizing radiation feedback. II. Spatially resolved star formation relation

    International Nuclear Information System (INIS)

    Kim, Ji-hoon; Krumholz, Mark R.; Goldbaum, Nathan J.; Wise, John H.; Turk, Matthew J.; Abel, Tom

    2013-01-01

    We investigate the spatially resolved star formation relation using a galactic disk formed in a comprehensive high-resolution (3.8 pc) simulation. Our new implementation of stellar feedback includes ionizing radiation as well as supernova explosions, and we handle ionizing radiation by solving the radiative transfer equation rather than by a subgrid model. Photoheating by stellar radiation stabilizes gas against Jeans fragmentation, reducing the star formation rate (SFR). Because we have self-consistently calculated the location of ionized gas, we are able to make simulated, spatially resolved observations of star formation tracers, such as Hα emission. We can also observe how stellar feedback manifests itself in the correlation between ionized and molecular gas. Applying our techniques to the disk in a galactic halo of 2.3 × 10 11 M ☉ , we find that the correlation between SFR density (estimated from mock Hα emission) and H 2 density shows large scatter, especially at high resolutions of ≲75 pc that are comparable to the size of giant molecular clouds (GMCs). This is because an aperture of GMC size captures only particular stages of GMC evolution and because Hα traces hot gas around star-forming regions and is displaced from the H 2 peaks themselves. By examining the evolving environment around star clusters, we speculate that the breakdown of the traditional star formation laws of the Kennicutt-Schmidt type at small scales is further aided by a combination of stars drifting from their birthplaces and molecular clouds being dispersed via stellar feedback.

  4. Dwarf galaxies with ionizing radiation feedback. II. Spatially resolved star formation relation

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ji-hoon; Krumholz, Mark R.; Wise, John H.; Turk, Matthew J.; Goldbaum, Nathan J.; Abel, Tom

    2013-11-15

    AWe investigate the spatially resolved star formation relation using a galactic disk formed in a comprehensive high-resolution (3.8 pc) simulation. Our new implementation of stellar feedback includes ionizing radiation as well as supernova explosions, and we handle ionizing radiation by solving the radiative transfer equation rather than by a subgrid model. Photoheating by stellar radiation stabilizes gas against Jeans fragmentation, reducing the star formation rate (SFR). Because we have self-consistently calculated the location of ionized gas, we are able to make simulated, spatially resolved observations of star formation tracers, such as Hα emission. We can also observe how stellar feedback manifests itself in the correlation between ionized and molecular gas. Applying our techniques to the disk in a galactic halo of 2.3 × 1011 M , we find that the correlation between SFR density (estimated from mock Hα emission) and H2 density shows large scatter, especially at high resolutions of ≲ 75 pc that are comparable to the size of giant molecular clouds (GMCs). This is because an aperture of GMC size captures only particular stages of GMC evolution and because Hα traces hot gas around star-forming regions and is displaced from the H2 peaks themselves. By examining the evolving environment around star clusters, we speculate that the breakdown of the traditional star formation laws of the Kennicutt-Schmidt type at small scales is further aided by a combination of stars drifting from their birthplaces and molecular clouds being dispersed via stellar feedback.

  5. Reactor for in situ measurements of spatially resolved kinetic data in heterogeneous catalysis

    Science.gov (United States)

    Horn, R.; Korup, O.; Geske, M.; Zavyalova, U.; Oprea, I.; Schlögl, R.

    2010-06-01

    The present work describes a reactor that allows in situ measurements of spatially resolved kinetic data in heterogeneous catalysis. The reactor design allows measurements up to temperatures of 1300 °C and 45 bar pressure, i.e., conditions of industrial relevance. The reactor involves reactants flowing through a solid catalyst bed containing a sampling capillary with a side sampling orifice through which a small fraction of the reacting fluid (gas or liquid) is transferred into an analytical device (e.g., mass spectrometer, gas chromatograph, high pressure liquid chromatograph) for quantitative analysis. The sampling capillary can be moved with μm resolution in or against flow direction to measure species profiles through the catalyst bed. Rotation of the sampling capillary allows averaging over several scan lines. The position of the sampling orifice is such that the capillary channel through the catalyst bed remains always occupied by the capillary preventing flow disturbance and fluid bypassing. The second function of the sampling capillary is to provide a well which can accommodate temperature probes such as a thermocouple or a pyrometer fiber. If a thermocouple is inserted in the sampling capillary and aligned with the sampling orifice fluid temperature profiles can be measured. A pyrometer fiber can be used to measure the temperature profile of the solid catalyst bed. Spatial profile measurements are demonstrated for methane oxidation on Pt and methane oxidative coupling on Li/MgO, both catalysts supported on reticulated α -Al2O3 foam supports.

  6. Obtaining absolute spatial flux measurements with a time-resolved pinhole camera

    International Nuclear Information System (INIS)

    Baker, K.L.; Porter, J.L.; Ruggles, L.E.; Fehl, D.L.; Chandler, G.A.; Vargas, M.; Mix, L.P.; Simpson, W.W.; Deeney, C.; Chrien, R.E.; Idzorek, G.C.

    1999-01-01

    A technique is described to determine the spatial x-ray flux emitted from a hohlraum wall and subsequently transmitted through a diagnostic hole. This technique uses x-ray diodes, bolometers, and a time-resolved pinhole camera to determine the spatial flux of x rays emitted through a hohlraum close-quote s diagnostic hole. The primary motivation for this analysis was the relatively long duration, nearly 100 ns, of the x-ray drive present in z-pinch driven hohlraums. This radiation causes plasma to ablate from the hohlraum walls surrounding the diagnostic hole and results in a partial obscuration that reduces the effective area over which diagnostics view the radiation. The effective change in area leads to an underestimation of the wall temperature when nonimaging diagnostics such as x-ray diodes and bolometers are used to determine power and later to infer a wall temperature. An analysis similar to the one described below is then necessary to understand the radiation environment present in x-ray driven hohlraums when these diagnostics are used and hole closure is important. copyright 1999 American Institute of Physics

  7. A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Hager, J. D., E-mail: hager@lanl.gov; Lanier, N. E.; Kline, J. L.; Flippo, K. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2014-11-15

    We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO{sub 2} foam with a Ti foam tracer. In this configuration, a broad band CsI backlighter will be used for a source and the Ti absorption spectrum measured.

  8. Study on sociological approach to resolve maintenance related social problems

    International Nuclear Information System (INIS)

    Aoki, Takayuki

    2007-01-01

    This study proposes a sociological approach to resolve maintenance related social problems. As a result of consideration, the followings were found. (1) In general, solutions to some kinds of questions can be deduced from basic laws using some theories or methodologies in the field of the natural science or engineering. The approach to resolve maintenance related social problems is similar to the approach in the natural science or engineering. (2) The points of view based on fundamental human rights, market principles and community principles, and so on, are very important in resolving maintenance related social problems and can be placed as theories or tools for resolution. (3) If such theories or tools for resolving maintenance related social problems as described above are systematically prepared, it is estimated that it becomes very much easier to resolve maintenance related social problems. (author)

  9. Comparison of grain to grain orientation and stiffness mapping by spatially resolved acoustic spectroscopy and EBSD.

    Science.gov (United States)

    Mark, A F; Li, W; Sharples, S; Withers, P J

    2017-07-01

    Our aim was to establish the capability of spatially resolved acoustic spectroscopy (SRAS) to map grain orientations and the anisotropy in stiffness at the sub-mm to micron scale by comparing the method with electron backscatter diffraction (EBSD) undertaken within a scanning electron microscope. In the former the grain orientations are deduced by measuring the spatial variation in elastic modulus; conversely, in EBSD the elastic anisotropy is deduced from direct measurements of the crystal orientations. The two test-cases comprise mapping the fusion zones for large TIG and MMA welds in thick power plant austenitic and ferritic steels, respectively; these are technologically important because, among other things, elastic anisotropy can cause ultrasonic weld inspection methods to become inaccurate because it causes bending in the paths of sound waves. The spatial resolution of SRAS is not as good as that for EBSD (∼100 μm vs. ∼a few nm), nor is the angular resolution (∼1.5° vs. ∼0.5°). However the method can be applied to much larger areas (currently on the order of 300 mm square), is much faster (∼5 times), is cheaper and easier to perform, and it could be undertaken on the manufacturing floor. Given these advantages, particularly to industrial users, and the on-going improvements to the method, SRAS has the potential to become a standard method for orientation mapping, particularly in cases where the elastic anisotropy is important over macroscopic/component length scales. © 2017 The Authors Journal of Microscopy © 2017 Royal Microscopical Society.

  10. SDSS IV MaNGA: Dependence of Global and Spatially Resolved SFR–M ∗ Relations on Galaxy Properties

    Science.gov (United States)

    Pan, Hsi-An; Lin, Lihwai; Hsieh, Bau-Ching; Sánchez, Sebastián F.; Ibarra-Medel, Héctor; Boquien, Médéric; Lacerna, Ivan; Argudo-Fernández, Maria; Bizyaev, Dmitry; Cano-Díaz, Mariana; Drory, Niv; Gao, Yang; Masters, Karen; Pan, Kaike; Tabor, Martha; Tissera, Patricia; Xiao, Ting

    2018-02-01

    The galaxy integrated Hα star formation rate–stellar mass relation, or SFR(global)–M *(global) relation, is crucial for understanding star formation history and evolution of galaxies. However, many studies have dealt with SFR using unresolved measurements, which makes it difficult to separate out the contamination from other ionizing sources, such as active galactic nuclei and evolved stars. Using the integral field spectroscopic observations from SDSS-IV MaNGA, we spatially disentangle the contribution from different Hα powering sources for ∼1000 galaxies. We find that, when including regions dominated by all ionizing sources in galaxies, the spatially resolved relation between Hα surface density (ΣHα (all)) and stellar mass surface density (Σ*(all)) progressively turns over at the high Σ*(all) end for increasing M *(global) and/or bulge dominance (bulge-to-total light ratio, B/T). This in turn leads to the flattening of the integrated Hα(global)–M *(global) relation in the literature. By contrast, there is no noticeable flattening in both integrated Hα(H II)–M *(H II) and spatially resolved ΣHα (H II)–Σ*(H II) relations when only regions where star formation dominates the ionization are considered. In other words, the flattening can be attributed to the increasing regions powered by non-star-formation sources, which generally have lower ionizing ability than star formation. An analysis of the fractional contribution of non-star-formation sources to total Hα luminosity of a galaxy suggests a decreasing role of star formation as an ionizing source toward high-mass, high-B/T galaxies and bulge regions. This result indicates that the appearance of the galaxy integrated SFR–M * relation critically depends on their global properties (M *(global) and B/T) and relative abundances of various ionizing sources within the galaxies.

  11. Spatially-resolved velocities of thermally-produced spray droplets using a velocity-divided Abel inversion of photographed streaks

    Science.gov (United States)

    Kawaguchi, Y.; Kobayashi, N.; Yamagata, Y.; Miyazaki, F.; Yamasaki, M.; Muraoka, K.

    2017-10-01

    Droplet velocities of thermal spray are known to have profound effects on important coating qualities, such as adhesive strength, porosity, and hardness, for various applications. For obtaining the droplet velocities, therefore, the TOF (time-of-flight) technique has been widely used, which relies on observations of emitted radiation from the droplets, where all droplets along the line-of-sight contribute to signals. Because droplets at and near the flow axis mostly contribute coating layers, it has been hoped to get spatially resolved velocities. For this purpose, a velocity-divided Abel inversion was devised from CMOS photographic data. From this result, it has turned out that the central velocity is about 25% higher than that obtained from the TOF technique for the case studied (at the position 150 mm downstream of the plasma spray gun, where substrates for spray coatings are usually placed). Further implications of the obtained results are discussed.

  12. A SPATIALLY RESOLVED INNER HOLE IN THE DISK AROUND GM AURIGAE

    International Nuclear Information System (INIS)

    Hughes, A. Meredith; Andrews, Sean M.; Wilner, David J.; Qi Chunhua; Espaillat, Catherine; Calvet, Nuria; D'Alessio, Paola; Williams, Jonathan P.; Hogerheijde, Michiel R.

    2009-01-01

    We present 0.''3 resolution observations of the disk around GM Aurigae with the Submillimeter Array (SMA) at a wavelength of 860 μm and with the Plateau de Bure Interferometer at a wavelength of 1.3 mm. These observations probe the distribution of disk material on spatial scales commensurate with the size of the inner hole predicted by models of the spectral energy distribution (SED). The data clearly indicate a sharp decrease in millimeter optical depth at the disk center, consistent with a deficit of material at distances less than ∼20 AU from the star. We refine the accretion disk model of Calvet et al. based on the unresolved SED and demonstrate that it reproduces well the spatially resolved millimeter continuum data at both available wavelengths. We also present complementary SMA observations of CO J = 3-2 and J = 2-1 emission from the disk at 2'' resolution. The observed CO morphology is consistent with the continuum model prediction, with two significant deviations: (1) the emission displays a larger CO J = 3-2/J = 2-1 line ratio than predicted, which may indicate additional heating of gas in the upper disk layers; and (2) the position angle of the kinematic rotation pattern differs by 11 deg. ± 2 deg. from that measured at smaller scales from the dust continuum, which may indicate the presence of a warp. We note that photoevaporation, grain growth, and binarity are unlikely mechanisms for inducing the observed sharp decrease in opacity or surface density at the disk center. The inner hole plausibly results from the dynamical influence of a planet on the disk material. Warping induced by a planet could also potentially explain the difference in position angle between the continuum and CO data sets.

  13. Final Technical Report - Consolidating Biomass Pretreatment with Saccharification by Resolving the Spatial Control Mechanisms of Fungi

    Energy Technology Data Exchange (ETDEWEB)

    Schilling, Jonathan [Univ. of Minnesota, Minneapolis, MN (United States)

    2017-07-06

    Consolidated bioprocessing (CBP) of lignocellulose combines enzymatic sugar release (saccharification) with fermentation, but pretreatments remain separate and costly. In nature, lignocellulose-degrading brown rot fungi consolidate pretreatment and saccharification, likely using spatial gradients to partition these incompatible reactions. With the field of biocatalysis maturing, reaction partitioning is increasingly reproducible for commercial use. Therefore, my goal was to resolve the reaction partitioning mechanisms of brown rot fungi so that they can be applied to bioconversion of lignocellulosic feedstocks. Brown rot fungi consolidate oxidative pretreatments with saccharification and are a focus for biomass refining because 1) they attain >99% sugar yield without destroying lignin, 2) they use a simplified cellulase suite that lacks exoglucanase, and 3) their non-enzymatic pretreatment is facilitative and may be accelerated. Specifically, I hypothesized that during brown rot, oxidative pretreatments occur ahead of enzymatic saccharification, spatially, and the fungus partitions these reactions using gradients in pH, lignin reactivity, and plant cell wall porosity. In fact, we found three key results during these experiments for this work: 1) Brown rot fungi have an inducible cellulase system, unlike previous descriptions of a constitutive mechanism. 2) The induction of cellulases is delayed until there is repression of oxidatively-linked genes, allowing the brown rot fungi to coordinate two incompatible reactions (oxidative pretreatment with enzymatic saccharification, to release wood sugars) in the same pieces of wood. 3) This transition is mediated by the same wood sugar, cellobiose, released by the oxidative pretreatment step. Collectively, these findings have been published in excellent journal outlets and have been presented at conferences around the United States, and they offer clear targets for gene discovery en route to making biofuels and biochemicals

  14. An approach to estimate spatial distribution of analyte within cells using spectrally-resolved fluorescence microscopy

    Science.gov (United States)

    Sharma, Dharmendar Kumar; Irfanullah, Mir; Basu, Santanu Kumar; Madhu, Sheri; De, Suman; Jadhav, Sameer; Ravikanth, Mangalampalli; Chowdhury, Arindam

    2017-03-01

    While fluorescence microscopy has become an essential tool amongst chemists and biologists for the detection of various analyte within cellular environments, non-uniform spatial distribution of sensors within cells often restricts extraction of reliable information on relative abundance of analytes in different subcellular regions. As an alternative to existing sensing methodologies such as ratiometric or FRET imaging, where relative proportion of analyte with respect to the sensor can be obtained within cells, we propose a methodology using spectrally-resolved fluorescence microscopy, via which both the relative abundance of sensor as well as their relative proportion with respect to the analyte can be simultaneously extracted for local subcellular regions. This method is exemplified using a BODIPY sensor, capable of detecting mercury ions within cellular environments, characterized by spectral blue-shift and concurrent enhancement of emission intensity. Spectral emission envelopes collected from sub-microscopic regions allowed us to compare the shift in transition energies as well as integrated emission intensities within various intracellular regions. Construction of a 2D scatter plot using spectral shifts and emission intensities, which depend on the relative amount of analyte with respect to sensor and the approximate local amounts of the probe, respectively, enabled qualitative extraction of relative abundance of analyte in various local regions within a single cell as well as amongst different cells. Although the comparisons remain semi-quantitative, this approach involving analysis of multiple spectral parameters opens up an alternative way to extract spatial distribution of analyte in heterogeneous systems. The proposed method would be especially relevant for fluorescent probes that undergo relatively nominal shift in transition energies compared to their emission bandwidths, which often restricts their usage for quantitative ratiometric imaging in

  15. Investigation of Co nanoparticle formation using time-dependent and spatially-resolved X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zinoveva, S.

    2008-04-15

    A crucial step towards controlled synthesis of nanoparticles is the detailed understanding of the various chemical processes that take place during the synthesis. X-ray Absorption Spectroscopy (XAS) is especially suitable for elucidating the type and structure of the intermediate metal species. It is applicable to materials that have no long range order and provides information on both electronic and geometric structures. Here a comparative study is reported of the formation of cobalt nanoparticles via thermolysis of two organometallic precursors dicobalt octacarbonyl (DCO) and alkyne-bridged dicobalt hexacarbonyl (ADH) in the presence of aluminum organics. Using time-dependent XAS a reaction pathway different from both the atom based La Mer model and the Watzky and Finsky autocatalytic surface growth model is observed. Where prior to the nucleation several intermediates are formed and the initial nucleus is composed of Co atoms coordinated with ligands Co{sub n}(CO){sub m} with n=2-3, m=3-5. The formation of Co nanoparticles was also investigated using a reaction different from thermolysis of cobalt carbonyls, namely reduction of Co (II) acetate by sodium borohydrate. Here the combination of microreactor system and spatially resolved XAS allowed ''in situ'' monitoring of the wet chemical synthesis. Several steps of the reaction were spatially resolved in the microreactor. The vertical size of the X-ray beam (50 {mu}m) focused with Kirkpatrick-Baez mirror system, determines the time resolution (better than 2 ms). The results provide direct insight into rapid process of nanoparticles formation and demonstrate the potential of this new technique for the fundamental studies of such type of processes where miniaturization and timeresolution are important. Like in the carbonyls thermolysis no evidence for the reduction of the starting complex to isolated Co{sup 0} atoms followed by nucleation of Co{sup 0} atoms was observed. (orig.)

  16. Investigation of Co nanoparticle formation using time-dependent and spatially-resolved X-ray absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Zinoveva, S

    2008-04-15

    A crucial step towards controlled synthesis of nanoparticles is the detailed understanding of the various chemical processes that take place during the synthesis. X-ray Absorption Spectroscopy (XAS) is especially suitable for elucidating the type and structure of the intermediate metal species. It is applicable to materials that have no long range order and provides information on both electronic and geometric structures. Here a comparative study is reported of the formation of cobalt nanoparticles via thermolysis of two organometallic precursors dicobalt octacarbonyl (DCO) and alkyne-bridged dicobalt hexacarbonyl (ADH) in the presence of aluminum organics. Using time-dependent XAS a reaction pathway different from both the atom based La Mer model and the Watzky and Finsky autocatalytic surface growth model is observed. Where prior to the nucleation several intermediates are formed and the initial nucleus is composed of Co atoms coordinated with ligands Co{sub n}(CO){sub m} with n=2-3, m=3-5. The formation of Co nanoparticles was also investigated using a reaction different from thermolysis of cobalt carbonyls, namely reduction of Co (II) acetate by sodium borohydrate. Here the combination of microreactor system and spatially resolved XAS allowed ''in situ'' monitoring of the wet chemical synthesis. Several steps of the reaction were spatially resolved in the microreactor. The vertical size of the X-ray beam (50 {mu}m) focused with Kirkpatrick-Baez mirror system, determines the time resolution (better than 2 ms). The results provide direct insight into rapid process of nanoparticles formation and demonstrate the potential of this new technique for the fundamental studies of such type of processes where miniaturization and timeresolution are important. Like in the carbonyls thermolysis no evidence for the reduction of the starting complex to isolated Co{sup 0} atoms followed by nucleation of Co{sup 0} atoms was observed. (orig.)

  17. SPATIALLY RESOLVED HCN ABSORPTION FEATURES IN THE CIRCUMNUCLEAR REGION OF NGC 1052

    Energy Technology Data Exchange (ETDEWEB)

    Sawada-Satoh, Satoko [Mizusawa VLBI Observatory, National Astronomical Observatory of Japan, 2-12 Hoshigaoka-cho, Mizusawa-ku, Oshu, Iwate 023-0861 (Japan); Roh, Duk-Gyoo; Oh, Se-Jin; Lee, Sang-Sung; Byun, Do-Young; Yeom, Jae-Hwan; Jung, Dong-Kyu; Kim, Hyo-Ryoung; Hwang, Ju-Yeon [Korea Astronomy and Space Science Institute, 776 Daedeok-daero, Yuseong, Daejeon 34055 (Korea, Republic of); Kameno, Seiji, E-mail: satoko.ss@nao.ac.jp, E-mail: sss@mx.ibaraki.ac.jp [Joint ALMA Observatory, Alonso de Cordova 3107 Vitacura, Santiago 763 0355 (Chile)

    2016-10-10

    We present the first VLBI detection of HCN molecular absorption in the nearby active galactic nucleus NGC 1052. Utilizing the 1 mas resolution achieved by the Korean VLBI Network, we have spatially resolved the HCN absorption against a double-sided nuclear jet structure. Two velocity features of HCN absorption are detected significantly at the radial velocity of 1656 and 1719 km s{sup −1}, redshifted by 149 and 212 km s{sup −1} with respect to the systemic velocity of the galaxy. The column density of the HCN molecule is estimated to be 10{sup 15}–10{sup 16} cm{sup −2}, assuming an excitation temperature of 100–230 K. The absorption features show high optical depth localized on the receding jet side, where the free–free absorption occurred due to the circumnuclear torus. The size of the foreground absorbing molecular gas is estimated to be on approximately one-parsec scales, which agrees well with the approximate size of the circumnuclear torus. HCN absorbing gas is likely to be several clumps smaller than 0.1 pc inside the circumnuclear torus. The redshifted velocities of the HCN absorption features imply that HCN absorbing gas traces ongoing infall motion inside the circumnuclear torus onto the central engine.

  18. SPATIALLY RESOLVED SPECTROSCOPY OF EUROPA: THE DISTINCT SPECTRUM OF LARGE-SCALE CHAOS

    International Nuclear Information System (INIS)

    Fischer, P. D.; Brown, M. E.; Hand, K. P.

    2015-01-01

    We present a comprehensive analysis of spatially resolved moderate spectral resolution near-infrared spectra obtained with the adaptive optics system at the Keck Observatory. We identify three compositionally distinct end member regions: the trailing hemisphere bullseye, the leading hemisphere upper latitudes, and a third component associated with leading hemisphere chaos units. We interpret the composition of the three end member regions to be dominated by irradiation products, water ice, and evaporite deposits or salt brines, respectively. The third component is associated with geological features and distinct from the geography of irradiation, suggesting an endogenous identity. Identifying the endogenous composition is of particular interest for revealing the subsurface composition. However, its spectrum is not consistent with linear mixtures of the salt minerals previously considered relevant to Europa. The spectrum of this component is distinguished by distorted hydration features rather than distinct spectral features, indicating hydrated minerals but making unique identification difficult. In particular, it lacks features common to hydrated sulfate minerals, challenging the traditional view of an endogenous salty component dominated by Mg-sulfates. Chloride evaporite deposits are one possible alternative

  19. Spatially resolved micro-Raman observation on the phase separation of effloresced sea salt droplets.

    Science.gov (United States)

    Xiao, Han-Shuang; Dong, Jin-Ling; Wang, Liang-Yu; Zhao, Li-Jun; Wang, Feng; Zhang, Yun-Hong

    2008-12-01

    We report on the investigation of the phase separation of individual seawater droplets in the efflorescence processes with the spatially resolved Raman system. Upon decreasing the relative humidity (RH), CaSO4.0.5H2O separated out foremost fromthe droplet atan unexpectedly high RH of approcimately 90%. Occasionally, CaSO4.2H2O substituted for CaSO4.O.5H2O crystallizing first at approximately 78% RH. Relatively large NaCI solids followed to crystallize at approximately 55% RH and led to the great loss of the solution. Then, the KMgCl3.6H2O crystallites separated out from the residual solutions, adjacentto NaCl at approximately 44% RH. Moreover, a shell structure of dried sea salt particle was found to form at low RHs, with the NaCl crystals in the core and minor supersaturated solutions covered with MgSO4 gel coating on the surface. Ultimately, the shielded solution partly effloresced into MgSO4 hydrates at very dry state (<5% RH).

  20. Algorithm of extraction optics properties from the measurement of spatially resolved diffuse reflectance

    International Nuclear Information System (INIS)

    Cunill Rodriguez, Margarita; Delgado Atencio, Jose Alberto; Castro Ramos, Jorge; Vazquez y Montiel, Sergio

    2009-01-01

    There are several methods to obtain the optical parameters of biological tissues from the measurement of spatially resolved diffuse reflectance. One of them is well-known as Video Reflectometry in which a camera CCD is used as detection and recording system of the lateral distribution of diffuse reflectance Rd(r) when an infinitely narrow light beam impinges on the tissue. In this paper, we present an algorithm that we have developed for the calibration and application of an experimental set-up of Video Reflectometry destined to extract the optical properties of models of biological tissues with optical properties similar to the human skin. The results of evaluation of the accuracy of the algorithm for optical parameters extraction is shown for a set of proofs reflectance curves with known values of these parameters. In the generation of these curves the simulation of measurement errors was also considered. The results show that it is possible to extract the optical properties with an accuracy error of less than 1% for all the proofs curves. (Author)

  1. Spatially resolved electronic structure inside and outside the vortex cores of a high-temperature superconductor

    Science.gov (United States)

    Mitrović, V. F.; Sigmund, E. E.; Eschrig, M.; Bachman, H. N.; Halperin, W. P.; Reyes, A. P.; Kuhns, P.; Moulton, W. G.

    2001-10-01

    Puzzling aspects of high-transition-temperature (high-Tc) superconductors include the prevalence of magnetism in the normal state and the persistence of superconductivity in high magnetic fields. Superconductivity and magnetism generally are thought to be incompatible, based on what is known about conventional superconductors. Recent results, however, indicate that antiferromagnetism can appear in the superconducting state of a high-Tc superconductor in the presence of an applied magnetic field. Magnetic fields penetrate a superconductor in the form of quantized flux lines, each of which represents a vortex of supercurrents. Superconductivity is suppressed in the core of the vortex and it has been suggested that antiferromagnetism might develop there. Here we report the results of a high-field nuclear-magnetic-resonance (NMR) imaging experiment in which we spatially resolve the electronic structure of near-optimally doped YBa2Cu3O7-δ inside and outside vortex cores. Outside the cores, we find strong antiferromagnetic fluctuations, whereas inside we detect electronic states that are rather different from those found in conventional superconductors.

  2. Spatially Resolved MaNGA Observations of the Host Galaxy of Superluminous Supernova 2017egm

    Science.gov (United States)

    Chen, Ting-Wan; Schady, Patricia; Xiao, Lin; Eldridge, J. J.; Schweyer, Tassilo; Lee, Chien-Hsiu; Yu, Po-Chieh; Smartt, Stephen J.; Inserra, Cosimo

    2017-11-01

    Superluminous supernovae (SLSNe) are found predominantly in dwarf galaxies, indicating that their progenitors have a low metallicity. However, the most nearby SLSN to date, SN 2017egm, occurred in the spiral galaxy NGC 3191, which has a relatively high stellar mass and correspondingly high metallicity. In this Letter, we present detailed analysis of the nearby environment of SN 2017egm using MaNGA IFU data, which provides spectral data on kiloparsec scales. From the velocity map we find no evidence that SN 2017egm occurred within some intervening satellite galaxy, and at the SN position most metallicity diagnostics yield a solar and above solar metallicity (12+{log}({{O}}/{{H}})∼ 8.8{--}9.1). Additionally, we measure a small Hα equivalent width (EW) at the SN position of just 34 Å, which is one of the lowest EWs measured at any SLSN or gamma-ray burst position, and indicative of the progenitor star being comparatively old. We also compare the observed properties of NGC 3191 with other SLSN host galaxies. The solar-metallicity environment at the position of SN 2017egm presents a challenge to our theoretical understanding, and our spatially resolved spectral analysis provides further constraints on the progenitors of SLSNe.

  3. SPATIALLY RESOLVED SPECTROSCOPY OF EUROPA: THE DISTINCT SPECTRUM OF LARGE-SCALE CHAOS

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, P. D.; Brown, M. E. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Hand, K. P., E-mail: pfischer@caltech.edu [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2015-11-15

    We present a comprehensive analysis of spatially resolved moderate spectral resolution near-infrared spectra obtained with the adaptive optics system at the Keck Observatory. We identify three compositionally distinct end member regions: the trailing hemisphere bullseye, the leading hemisphere upper latitudes, and a third component associated with leading hemisphere chaos units. We interpret the composition of the three end member regions to be dominated by irradiation products, water ice, and evaporite deposits or salt brines, respectively. The third component is associated with geological features and distinct from the geography of irradiation, suggesting an endogenous identity. Identifying the endogenous composition is of particular interest for revealing the subsurface composition. However, its spectrum is not consistent with linear mixtures of the salt minerals previously considered relevant to Europa. The spectrum of this component is distinguished by distorted hydration features rather than distinct spectral features, indicating hydrated minerals but making unique identification difficult. In particular, it lacks features common to hydrated sulfate minerals, challenging the traditional view of an endogenous salty component dominated by Mg-sulfates. Chloride evaporite deposits are one possible alternative.

  4. Spatially and time-resolved magnetization dynamics driven by spin-orbit torques

    Science.gov (United States)

    Baumgartner, Manuel; Garello, Kevin; Mendil, Johannes; Avci, Can Onur; Grimaldi, Eva; Murer, Christoph; Feng, Junxiao; Gabureac, Mihai; Stamm, Christian; Acremann, Yves; Finizio, Simone; Wintz, Sebastian; Raabe, Jörg; Gambardella, Pietro

    2017-10-01

    Current-induced spin-orbit torques are one of the most effective ways to manipulate the magnetization in spintronic devices, and hold promise for fast switching applications in non-volatile memory and logic units. Here, we report the direct observation of spin-orbit-torque-driven magnetization dynamics in Pt/Co/AlOx dots during current pulse injection. Time-resolved X-ray images with 25 nm spatial and 100 ps temporal resolution reveal that switching is achieved within the duration of a subnanosecond current pulse by the fast nucleation of an inverted domain at the edge of the dot and propagation of a tilted domain wall across the dot. The nucleation point is deterministic and alternates between the four dot quadrants depending on the sign of the magnetization, current and external field. Our measurements reveal how the magnetic symmetry is broken by the concerted action of the damping-like and field-like spin-orbit torques and the Dzyaloshinskii-Moriya interaction, and show that reproducible switching events can be obtained for over 1012 reversal cycles.

  5. SDSS-IV MaNGA: Spatially Resolved Star Formation Main Sequence and LI(N)ER Sequence

    Science.gov (United States)

    Hsieh, B. C.; Lin, Lihwai; Lin, J. H.; Pan, H. A.; Hsu, C. H.; Sánchez, S. F.; Cano-Díaz, M.; Zhang, K.; Yan, R.; Barrera-Ballesteros, J. K.; Boquien, M.; Riffel, R.; Brownstein, J.; Cruz-González, I.; Hagen, A.; Ibarra, H.; Pan, K.; Bizyaev, D.; Oravetz, D.; Simmons, A.

    2017-12-01

    We present our study on the spatially resolved Hα and M * relation for 536 star-forming and 424 quiescent galaxies taken from the MaNGA survey. We show that the star formation rate surface density ({{{Σ }}}{SFR}), derived based on the Hα emissions, is strongly correlated with the M * surface density ({{{Σ }}}* ) on kiloparsec scales for star-forming galaxies and can be directly connected to the global star-forming sequence. This suggests that the global main sequence may be a consequence of a more fundamental relation on small scales. On the other hand, our result suggests that ∼20% of quiescent galaxies in our sample still have star formation activities in the outer region with lower specific star formation rate (SSFR) than typical star-forming galaxies. Meanwhile, we also find a tight correlation between {{{Σ }}}{{H}α } and {{{Σ }}}* for LI(N)ER regions, named the resolved “LI(N)ER” sequence, in quiescent galaxies, which is consistent with the scenario that LI(N)ER emissions are primarily powered by the hot, evolved stars as suggested in the literature.

  6. Fast spatially resolved exhaust gas recirculation (EGR) distribution measurements in an internal combustion engine using absorption spectroscopy.

    Science.gov (United States)

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2015-09-01

    Exhaust gas recirculation (EGR) in internal combustion engines is an effective method of reducing NOx emissions while improving efficiency. However, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder non-uniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. A sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in the intake manifold. The study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz.

  7. Spatially resolved vertical vorticity in solar supergranulation using helioseismology and local correlation tracking

    Science.gov (United States)

    Langfellner, J.; Gizon, L.; Birch, A. C.

    2015-09-01

    Flow vorticity is a fundamental property of turbulent convection in rotating systems. Solar supergranules exhibit a preferred sense of rotation, which depends on the hemisphere. This is due to the Coriolis force acting on the diverging horizontal flows. We aim to spatially resolve the vertical flow vorticity of the average supergranule at different latitudes, both for outflow and inflow regions. To measure the vertical vorticity, we use two independent techniques: time-distance helioseismology (TD) and local correlation tracking of granules in intensity images (LCT) using data from the Helioseismic and Magnetic Imager (HMI) on board the Solar Dynamics Observatory (SDO). Both maps are corrected for center-to-limb systematic errors. We find that 8 h TD and LCT maps of vertical vorticity are highly correlated at large spatial scales. Associated with the average supergranule outflow, we find tangential (vortical) flows that reach about 10 m s-1 in the clockwise direction at 40° latitude. In average inflow regions, the tangential flow reaches the same magnitude, but in the anticlockwise direction. These tangential velocities are much smaller than the radial (diverging) flow component (300 m s-1 for the average outflow and 200 m s-1 for the average inflow). The results for TD and LCT as measured from HMI are in excellent agreement for latitudes between -60° and 60°. From HMI LCT, we measure the vorticity peak of the average supergranule to have a full width at half maximum of about 13 Mm for outflows and 8 Mm for inflows. This is larger than the spatial resolution of the LCT measurements (about 3 Mm). On the other hand, the vorticity peak in outflows is about half the value measured at inflows (e.g., 4 × 10-6 s-1 clockwise compared to 8 × 10-6 s-1 anticlockwise at 40° latitude). Results from the Michelson Doppler Imager (MDI) on board the Solar and Heliospheric Observatory (SOHO) obtained in 2010 are biased compared to the HMI/SDO results for the same period

  8. Spatially-resolved star formation histories of CALIFA galaxies. Implications for galaxy formation

    Science.gov (United States)

    González Delgado, R. M.; Pérez, E.; Cid Fernandes, R.; García-Benito, R.; López Fernández, R.; Vale Asari, N.; Cortijo-Ferrero, C.; de Amorim, A. L.; Lacerda, E. A. D.; Sánchez, S. F.; Lehnert, M. D.; Walcher, C. J.

    2017-11-01

    This paper presents the spatially resolved star formation history (SFH) of nearby galaxies with the aim of furthering our understanding of the different processes involved in the formation and evolution of galaxies. To this end, we apply the fossil record method of stellar population synthesis to a rich and diverse data set of 436 galaxies observed with integral field spectroscopy in the CALIFA survey. The sample covers a wide range of Hubble types, with stellar masses ranging from M⋆ 109 to 7 × 1011 M⊙. Spectral synthesis techniques are applied to the datacubes to retrieve the spatially resolved time evolution of the star formation rate (SFR), its intensity (ΣSFR), and other descriptors of the 2D SFH in seven bins of galaxy morphology (E, S0, Sa, Sb, Sbc, Sc, and Sd) and five bins of stellar mass. Our main results are that (a) galaxies form very fast independently of their current stellar mass, with the peak of star formation at high redshift (z > 2). Subsequent star formation is driven by M⋆ and morphology, with less massive and later type spirals showing more prolonged periods of star formation. (b) At any epoch in the past, the SFR is proportional to M⋆, with most massive galaxies having the highest absolute (but lowest specific) SFRs. (c) While today, the ΣSFR is similar for all spirals and significantly lower in early-type galaxies (ETG), in the past, the ΣSFR scales well with morphology. The central regions of today's ETGs are where the ΣSFR reached the highest values (> 103 M⊙ Gyr-1 pc-2), similar to those measured in high-redshift star-forming galaxies. (d) The evolution of ΣSFR in Sbc systems matches that of models for Milky Way-like galaxies, suggesting that the formation of a thick disk may be a common phase in spirals at early epochs. (e) The SFR and ΣSFR in outer regions of E and S0 galaxies show that they have undergone an extended phase of growth in mass between z = 2 and 0.4. The mass assembled in this phase is in agreement with

  9. Integrated circuit-based electrochemical sensor for spatially resolved detection of redox-active metabolites in biofilms.

    Science.gov (United States)

    Bellin, Daniel L; Sakhtah, Hassan; Rosenstein, Jacob K; Levine, Peter M; Thimot, Jordan; Emmett, Kevin; Dietrich, Lars E P; Shepard, Kenneth L

    2014-01-01

    Despite advances in monitoring spatiotemporal expression patterns of genes and proteins with fluorescent probes, direct detection of metabolites and small molecules remains challenging. A technique for spatially resolved detection of small molecules would benefit the study of redox-active metabolites that are produced by microbial biofilms and can affect their development. Here we present an integrated circuit-based electrochemical sensing platform featuring an array of working electrodes and parallel potentiostat channels. 'Images' over a 3.25 × 0.9 mm(2) area can be captured with a diffusion-limited spatial resolution of 750 μm. We demonstrate that square wave voltammetry can be used to detect, identify and quantify (for concentrations as low as 2.6 μM) four distinct redox-active metabolites called phenazines. We characterize phenazine production in both wild-type and mutant Pseudomonas aeruginosa PA14 colony biofilms, and find correlations with fluorescent reporter imaging of phenazine biosynthetic gene expression.

  10. Timing the formation and assembly of early-type galaxies via spatially resolved stellar populations analysis

    Science.gov (United States)

    Martín-Navarro, Ignacio; Vazdekis, Alexandre; Falcón-Barroso, Jesús; La Barbera, Francesco; Yıldırım, Akın; van de Ven, Glenn

    2018-04-01

    To investigate star formation and assembly processes of massive galaxies, we present here a spatially resolved stellar population analysis of a sample of 45 elliptical galaxies (Es) selected from the Calar Alto Legacy Integral Field Area survey. We find rather flat age and [Mg/Fe] radial gradients, weakly dependent on the effective velocity dispersion of the galaxy within half-light radius. However, our analysis shows that metallicity gradients become steeper with increasing galaxy velocity dispersion. In addition, we have homogeneously compared the stellar population gradients of our sample of Es to a sample of nearby relic galaxies, i.e. local remnants of the high-z population of red nuggets. This comparison indicates that, first, the cores of present-day massive galaxies were likely formed in gas-rich, rapid star formation events at high redshift (z ≳ 2). This led to radial metallicity variations steeper than observed in the local Universe, and positive [Mg/Fe] gradients. Secondly, our analysis also suggests that a later sequence of minor dry mergers, populating the outskirts of early-type galaxies (ETGs), flattened the pristine [Mg/Fe] and metallicity gradients. Finally, we find a tight age-[Mg/Fe] relation, supporting that the duration of the star formation is the main driver of the [Mg/Fe] enhancement in massive ETGs. However, the star formation time-scale alone is not able to fully explain our [Mg/Fe] measurements. Interestingly, our results match the expected effect that a variable stellar initial mass function would have on the [Mg/Fe] ratio.

  11. Compact Starburst Galaxies with Fast Outflows: Spatially Resolved Stellar Mass Profiles

    Science.gov (United States)

    Gottlieb, Sophia; Diamond-Stanic, Aleksandar; Lipscomb, Charles; Ohene, Senyo; Rines, Josh; Moustakas, John; Sell, Paul; Tremonti, Christy; Coil, Alison; Rudnick, Gregory; Hickox, Ryan C.; Geach, James; Kepley, Amanda

    2018-01-01

    Powerful galactic winds driven by stellar feedback and black hole accretion are thought to play an important role in regulating star formation in galaxies. In particular, strong stellar feedback from supernovae, stellar winds, radiation pressure, and cosmic rays is required by simulations of star-forming galaxies to prevent the vast majority of baryons from cooling and collapsing to form stars. However, it remains unclear whether these stellar processes play a significant role in expelling gas and shutting down star formation in massive progenitors of quiescent galaxies. What are the limits of stellar feedback? We present multi-band photometry with HST/WFC3 (F475W, F814W, F160W) for a dozen compact starburst galaxies at z~0.6 with half-light radii that suggest incredibly large central escape velocities. These massive galaxies are driving fast (>1000 km/s) outflows that have been previously attributed to stellar feedback associated with the compact (r~100 pc) starburst. But how compact is the stellar mass? In the context of the stellar feedback hypothesis, it is unclear whether these fast outflows are being driven at velocities comparable to the escape velocity of an incredibly dense stellar system (as predicted by some models of radiation-pressure winds) or at velocities that exceed the central escape velocity by large factor. Our spatially resolved measurements with HST show that the stellar mass is more extended than the light, and this requires that the physical mechanism responsible for driving the winds must be able to launch gas at velocities that are factors of 5-10 beyond the central escape velocity.

  12. Fingerprinting ancient gold by measuring Pt with spatially resolved high energy Sy-XRF

    International Nuclear Information System (INIS)

    Guerra, M.F.; Calligaro, T.; Radtke, M.; Reiche, I.; Riesemeier, H.

    2005-01-01

    Trace elements of ancient gold such as Pt, give fundamental information on the circulation of the metal in the past. In the case of objects from the cultural heritage, the determination of trace elements requires non-destructive point analysis in general. These conditions and the need of good detection limits restrain the number of applicable analytical techniques. After the development of a PIXE set-up with a selective Cu or Zn filter of 75 μm and of a PIXE-XRF set-up using a primary target of As, we tested the possibilities of spatially resolved Sy-XRF to determine Pt in gold alloys. With a Zn filter, PIXE showed a detection limit of 1000 ppm in gold while PIXE-XRF lowers this detection limit down to 80 ppm. This last value being constrained by the resonant Raman effect produced on gold. In order to improve the detection limit of Pt keeping the non-destructiveness and access to point analysis, we developed an analytical protocol for XRF with synchrotron radiation at BESSY II, using the BAMline set-up. The L-lines of Pt were excited by a beam of energy above and below 11.564 keV and measured using a Si(Li) detector with a 50 μm Cu filter. A μ-beam of 100-250 μm 2 was used according to the size of the sample. The determination of the Pt content in the samples was carried out by Monte-Carlo simulation and subtraction of Au and Pt spectra obtained on pure standards. The limit of detection for Pt of 20 ppm was determined by using certified standards. The detection limits of a small set of other characteristic elements of gold were also measured using an incident energy of 33 keV

  13. SDSS-IV MaNGA - the spatially resolved transition from star formation to quiescence

    Science.gov (United States)

    Belfiore, Francesco; Maiolino, Roberto; Maraston, Claudia; Emsellem, Eric; Bershady, Matthew A.; Masters, Karen L.; Bizyaev, Dmitry; Boquien, Médéric; Brownstein, Joel R.; Bundy, Kevin; Diamond-Stanic, Aleksandar M.; Drory, Niv; Heckman, Timothy M.; Law, David R.; Malanushenko, Olena; Oravetz, Audrey; Pan, Kaike; Roman-Lopes, Alexandre; Thomas, Daniel; Weijmans, Anne-Marie; Westfall, Kyle B.; Yan, Renbin

    2017-04-01

    Using spatially resolved spectroscopy from SDSS-IV MaNGA we have demonstrated that low ionization emission-line regions (LIERs) in local galaxies result from photoionization by hot evolved stars, not active galactic nuclei, hence tracing galactic region hosting old stellar population where, despite the presence of ionized gas, star formation is no longer occurring. LIERs are ubiquitous in both quiescent galaxies and in the central regions of galaxies where star formation takes place at larger radii. We refer to these two classes of galaxies as extended LIER (eLIER) and central LIER (cLIER) galaxies, respectively. cLIERs are late-type galaxies primarily spread across the green valley, in the transition region between the star formation main sequence and quiescent galaxies. These galaxies display regular disc rotation in both stars and gas, although featuring a higher central stellar velocity dispersion than star-forming galaxies of the same mass. cLIERs are consistent with being slowly quenched inside-out; the transformation is associated with massive bulges, pointing towards the importance of bulge growth via secular evolution. eLIERs are morphologically early types and are indistinguishable from passive galaxies devoid of line emission in terms of their stellar populations, morphology and central stellar velocity dispersion. Ionized gas in eLIERs shows both disturbed and disc-like kinematics. When a large-scale flow/rotation is observed in the gas, it is often misaligned relative to the stellar component. These features indicate that eLIERs are passive galaxies harbouring a residual cold gas component, acquired mostly via external accretion. Importantly, quiescent galaxies devoid of line emission reside in denser environments and have significantly higher satellite fraction than eLIERs. Environmental effects thus represent the likely cause for the existence of line-less galaxies on the red sequence.

  14. Antiferromagnetism Induced in the Vortex Core of Tl2Ba2CuO6++δ Probed by Spatially-Resolved 205Tl-NMR

    International Nuclear Information System (INIS)

    Kumagai, K.; Kakuyanagi, K.; Matsuda, Y.; Hasegawa, T.

    2003-01-01

    Magnetism in the vortex core state has been studied by spatially-resolved NMR. The nuclear spin lattice relaxation rate T 1 -1 of 205 Tl in nearly optimal-doped Tl 2 Ba 2 CuO 6+ δ (T c =85 K) is significantly enhanced in the vortex core region. The NMR results suggest that the suppression of the d-wave superconducting order parameter in the vortex core leads to the nucleation of islands with local antiferromagnetic (AF) order. (author)

  15. Spatially resolved determination of the short-circuit current density of silicon solar cells via lock-in thermography

    International Nuclear Information System (INIS)

    Fertig, Fabian; Greulich, Johannes; Rein, Stefan

    2014-01-01

    We present a spatially resolved method to determine the short-circuit current density of crystalline silicon solar cells by means of lock-in thermography. The method utilizes the property of crystalline silicon solar cells that the short-circuit current does not differ significantly from the illuminated current under moderate reverse bias. Since lock-in thermography images locally dissipated power density, this information is exploited to extract values of spatially resolved current density under short-circuit conditions. In order to obtain an accurate result, one or two illuminated lock-in thermography images and one dark lock-in thermography image need to be recorded. The method can be simplified in a way that only one image is required to generate a meaningful short-circuit current density map. The proposed method is theoretically motivated, and experimentally validated for monochromatic illumination in comparison to the reference method of light-beam induced current.

  16. Development of a software system for spatial resolved trace analysis of high performance materials with SIMS

    International Nuclear Information System (INIS)

    Brunner, Ch. H.

    1997-09-01

    The following work is separated into two distinctly different parts. The first one is dealing with the SIMSScan software project, an application system for secondary ion mass spectrometry. This application system primarily lays down the foundation, for the research activity introduced in the second part of this work. SIMSScan is an application system designed to provide data acquisition routines for different requirements in the field of secondary ion mass spectroscopy. The whole application package is divided into three major sections, each one dealing with specific measurement tasks. Various supporting clients and wizards, providing extended functionality to the main application, build the core of the software. The MassScan as well as the DepthScan module incorporate the SIMS in the direct imaging or stigmatic mode and are featuring the capabilities for mass spectra recording or depth profile analysis. In combination with an image recording facility the DepthScan module features the capability of spatial resolved material analysis - 3D SIMS. The RasterScan module incorporates the SIMS in scanning mode and supports an fiber optical link for optimized data transfer. The primary goal of this work is to introduce the basic ideas behind the implementation of the main application modules and the supporting clients. Furthermore, it is the intention to lay down the foundation for further developments. At the beginning a short introduction into the paradigm of object oriented programming as well as Windows TM programming is given. Besides explaining the basic ideas behind the Doc/View application architecture the focus is mainly shifted to the routines controlling the SIMS hardware and the basic concepts of multithreaded programming. The elementary structures of the view and document objects is discussed in detail only for the MassScan module, because the ideas behind data abstraction and encapsulation are quite similar. The second part introduces the research activities

  17. An x-ray detector for time-resolved studies

    International Nuclear Information System (INIS)

    Rodricks, B.; Brizard, C.; Clarke, R.; Lowe, W.

    1992-01-01

    The development of ultrahigh-brightness x-ray sources makes time-resolved x-ray studies more and more feasible. Improvements in x-ray optics components are also critical for obtaining the appropriate beam for a particular type of experiment. Moreover, fast parallel detectors will be essential in order to exploit the combination of high intensity x-ray sources and novel optics for time-resolved experiments. A CCD detector with a time resolution of microseconds has been developed at the Advanced Photon Source (APS). This detector is fully programmable using CAMAC electronics and a Micro Vax computer. The techniques of time-resolved x-ray studies, which include scattering, microradiography, microtomography, stroboscopy, etc., can be applied to a range of phenomena (including rapid thermal annealing, surface ordering, crystallization, and the kinetics of phase transition) in order to understand these time-dependent microscopic processes. Some of these applications will be illustrated by recent results performed at synchrotrons. New powerful x-ray sources now under construction offer the opportunity to apply innovative approaches in time-resolved work

  18. New understanding of rhizosphere processes enabled by advances in molecular and spatially resolved techniques

    Energy Technology Data Exchange (ETDEWEB)

    Hess, Nancy J.; Paša-Tolić, Ljiljana; Bailey, Vanessa L.; Dohnalkova, Alice C.

    2017-06-01

    Understanding the role played by microorganisms within soil systems is challenged by the unique intersection of physics, chemistry, mineralogy and biology in fostering habitat for soil microbial communities. To address these challenges will require observations across multiple spatial and temporal scales to capture the dynamics and emergent behavior from complex and interdependent processes. The heterogeneity and complexity of the rhizosphere require advanced techniques that press the simultaneous frontiers of spatial resolution, analyte sensitivity and specificity, reproducibility, large dynamic range, and high throughput. Fortunately many exciting technical advancements are now available to inform and guide the development of new hypotheses. The aim of this Special issue is to provide a holistic view of the rhizosphere in the perspective of modern molecular biology methodologies that enabled a highly-focused, detailed view on the processes in the rhizosphere, including numerous, strong and complex interactions between plant roots, soil constituents and microorganisms. We discuss the current rhizosphere research challenges and knowledge gaps, as well as perspectives and approaches using newly available state-of-the-art toolboxes. These new approaches and methodologies allow the study of rhizosphere processes and properties, and rhizosphere as a central component of ecosystems and biogeochemical cycles.

  19. Energy dissipation mechanism revealed by spatially resolved Raman thermometry of graphene/hexagonal boron nitride heterostructure devices

    Science.gov (United States)

    Kim, Daehee; Kim, Hanul; Yun, Wan Soo; Watanabe, Kenji; Taniguchi, Takashi; Rho, Heesuk; Bae, Myung-Ho

    2018-04-01

    Understanding the energy transport by charge carriers and phonons in two-dimensional (2D) van der Waals heterostructures is essential for the development of future energy-efficient 2D nanoelectronics. Here, we performed in situ spatially resolved Raman thermometry on an electrically biased graphene channel and its hBN substrate to study the energy dissipation mechanism in graphene/hBN heterostructures. By comparing the temperature profile along the biased graphene channel with that along the hBN substrate, we found that the thermal boundary resistance between the graphene and hBN was in the range of (1-2) ~ × 10-7 m2 K W-1 from ~100 °C to the onset of graphene break-down at ~600 °C in air. Consideration of an electro-thermal transport model together with the Raman thermometry conducted in air showed that a doping effect occurred under a strong electric field played a crucial role in the energy dissipation of the graphene/hBN device up to T ~ 600 °C.

  20. Time and spatially resolved LIF of OH in a plasma filament in atmospheric pressure He-H2O

    International Nuclear Information System (INIS)

    Verreycken, T; Van der Horst, R M; Baede, A H F M; Van Veldhuizen, E M; Bruggeman, P J

    2012-01-01

    The production of OH in a nanosecond pulsed filamentary discharge generated in pin-pin geometry in a He-H 2 O mixture is studied by time and spatially resolved laser-induced fluorescence. Apart from the OH density the gas temperature and the electron density are also measured. Depending on the applied voltage the discharge is in a different mode. The maximum electron densities in the low- (1.3 kV) and high-density (5 kV) modes are 2 × 10 21 m -3 and 7 × 10 22 m -3 , respectively. The gas temperature in both modes does not exceed 600 K. In the low-density mode the maximum OH density is at the centre of the discharge filament, while in the high-density mode the largest OH density is observed on the edge of the discharge. A chemical model is used to obtain an estimate of the absolute OH density. The chemical model also shows that charge exchange and dissociative recombination can explain the production of OH in the case of the high-density mode. (paper)

  1. Tunable All Reflective Spatial Heterodyne Spectroscopy, A Technique For High Resolving Power Observation OI Defused Emission Line Sources

    Science.gov (United States)

    Hosseini, Seyedeh Sona

    The solar system presents a challenge to spectroscopic observers, because it is an astrophysically low energy environment populated with often angularly extended targets (e.g, interplanetary medium, comets, planetary upper atmospheres, and planet and satellite near space environments). Spectroscopy is a proven tool for determining compositional and other properties of remote objects. Narrow band imaging and low resolving spectroscopic measurements provide information about composition, photochemical evolution, energy distribution and density. The extension to high resolving power provides further access to temperature, velocity, isotopic ratios, separation of blended sources, and opacity effects. The drawback of high-resolution spectroscopy comes from the instrumental limitations of lower throughput, the necessity of small entrance apertures, sensitivity, field of view, and large physical instrumental size. These limitations quickly become definitive for faint and/or extended targets and for spacecraft encounters. An emerging technique with promise for the study of faint, extended sources at high resolving power is the all-reflective form of the Spatial Heterodyne Spectrometer (SHS). SHS instruments are compact and naturally possess both high etendue and high resolving power. To achieve similar spectral grasp, grating spectrometers require big telescopes. SHS is a common-path beam Fourier transform interferometer that produces Fizeau fringe pattern for all other wavelengths except the tuned wavelength. Compared to similar Fourier transform Spectrometers (FTS), SHS has considerably relaxed optical tolerances that make it easier to use in the visible and UV spectral ranges. The large etendue of SHS instruments makes them ideal for observations of extended, low surface brightness, isolated emission line sources, while their intrinsically high spectral resolution enables the study of the dynamical and spectral characteristics described above. SHS also combines very

  2. Spatially resolved spectra of the 'teacup' active galactic nucleus: tracing the history of a dying quasar

    International Nuclear Information System (INIS)

    Gagne, J. P.; Crenshaw, D. M.; Fischer, T. C.; Kraemer, S. B.; Schmitt, H. R.; Keel, W. C.; Rafter, S.; Bennert, V. N.; Schawinski, K.

    2014-01-01

    The Sloan Digital Sky Survey (SDSS) Galaxy Zoo project has revealed a number of spectacular galaxies possessing extended emission-line regions (EELRs), the most famous being Hanny's Voorwerp galaxy. We present another EELR object discovered in the SDSS endeavor: the Teacup active galactic nucleus (AGN). Nicknamed for its EELR, which has a 'handle'-like structure protruding 15 kpc into the northeast quadrant of the galaxy. We analyze the physical conditions of this galaxy with long-slit, ground-based spectroscopy from the Lowell, Lick, and KPNO observatories. With the Lowell 1.8 m Perkin's telescope we took multiple observations at different offset positions, allowing us to recover spatially resolved spectra across the galaxy. Line diagnostics indicate the ionized gas is photoionized primarily by the AGN. Additionally we are able to derive the hydrogen density from the [S II] λ6716/λ6731 ratio. We generated two-component photoionization models for each spatially resolved Lowell spectrum. These models allow us to calculate the AGN bolometric luminosity seen by the gas at different radii from the nuclear center of the Teacup. Our results show a drop in bolometric luminosity by more than two orders of magnitude from the EELR to the nucleus, suggesting that the AGN has decreased in luminosity by this amount in a continuous fashion over 46,000 yr, supporting the case for a dying AGN in this galaxy independent of any IR based evidence. We demonstrate that spatially resolved photoionization modeling could be applied to EELRs to investigate long timescale variability.

  3. Spatially resolved spectra of the 'teacup' active galactic nucleus: tracing the history of a dying quasar

    Energy Technology Data Exchange (ETDEWEB)

    Gagne, J. P.; Crenshaw, D. M.; Fischer, T. C. [Department of Physics and Astronomy, Georgia State University, Astronomy Offices, 25 Park Place South SE, Suite 600, Atlanta, GA 30303 (United States); Kraemer, S. B. [Department of Physics, Catholic University of America, 620 Michigan Avenue, N.E., Washington, DC 20064 (United States); Schmitt, H. R. [Naval Research Laboratory, Washington, DC 20375 (United States); Keel, W. C. [Department of Physics and Astronomy, University of Alabama, Box 870324, Tuscaloosa, AL 35487 (United States); Rafter, S. [Physics Department, Technion, Haifa 32000 (Israel); Bennert, V. N. [Physics Department, California Polytechnic State University San Luis Obispo, CA 93407 (United States); Schawinski, K., E-mail: gagne@chara.gsu.edu [Institute for Astronomy, Department of Physics, ETH Zurich, Wolfgang-Pauli-Strasse 27, CH-8093 Zurich (Switzerland)

    2014-09-01

    The Sloan Digital Sky Survey (SDSS) Galaxy Zoo project has revealed a number of spectacular galaxies possessing extended emission-line regions (EELRs), the most famous being Hanny's Voorwerp galaxy. We present another EELR object discovered in the SDSS endeavor: the Teacup active galactic nucleus (AGN). Nicknamed for its EELR, which has a 'handle'-like structure protruding 15 kpc into the northeast quadrant of the galaxy. We analyze the physical conditions of this galaxy with long-slit, ground-based spectroscopy from the Lowell, Lick, and KPNO observatories. With the Lowell 1.8 m Perkin's telescope we took multiple observations at different offset positions, allowing us to recover spatially resolved spectra across the galaxy. Line diagnostics indicate the ionized gas is photoionized primarily by the AGN. Additionally we are able to derive the hydrogen density from the [S II] λ6716/λ6731 ratio. We generated two-component photoionization models for each spatially resolved Lowell spectrum. These models allow us to calculate the AGN bolometric luminosity seen by the gas at different radii from the nuclear center of the Teacup. Our results show a drop in bolometric luminosity by more than two orders of magnitude from the EELR to the nucleus, suggesting that the AGN has decreased in luminosity by this amount in a continuous fashion over 46,000 yr, supporting the case for a dying AGN in this galaxy independent of any IR based evidence. We demonstrate that spatially resolved photoionization modeling could be applied to EELRs to investigate long timescale variability.

  4. A diagnostic for time-resolved spatial profiles measurements on the ion temperature on JET

    International Nuclear Information System (INIS)

    Brocken, H.J.B.M.; Ven, H.W van der.

    1980-05-01

    A neutral particle scattering experiment for a continuous measurement of the ion temperature and ion density of the JET plasma in the hydrogen and deuterium phase is proposed. Space- and time-resolved measurements are possible by injection of a mono-energetic particle beam into the plasma and from the analysis of the velocity distribution of the scattered particles. The requirements on the injection system are specified and a suitable analyzer system is described

  5. Highly Resolved Studies of Vacuum Ultraviolet Photoionization Dynamics

    Science.gov (United States)

    Kakar, Sandeep

    We use measurements of dispersed fluorescence from electronically excited photoions to study fundamental aspects of intramolecular dynamics. Our experimental innovations make it possible to obtain highly resolved photoionization data that offer qualitative insights into molecular scattering. In particular, we obtain vibrationally resolved data to probe coupling between the electronic and nuclear degrees of freedom by studying the distribution of vibrational energy among photoions. Vibrationally resolved branching ratios are measured over a broad spectral range of excitation energy and their non-Franck-Condon behavior is used as a tool to investigate two diverse aspects of shape resonant photoionization. First, vibrational branching ratios are obtained for the SiF_4 5a _1^{-1} and CS_2 5sigma_{rm u} ^{-1} photoionization channels to help elucidate the microscopic aspects of shape resonant wavefunction for polyatomic molecules. It is shown that in such molecules the shape resonant wavefunction is not necessarily attributable to a specific bond in the molecule. Second, the multichannel aspect of shape resonant photoionization dynamics, reflected in continuum channel coupling, is investigated by obtaining vibrational branching ratios for the 2 sigma_{rm u}^{ -1} and 4sigma^{ -1} photoionization of the isoelectronic molecules N_2 and CO, respectively. These data indicate that effects of continuum coupling may be widespread. We also present the first set of rotationally resolved data over a wide energy range for the 2 sigma_{rm u}^{ -1} photoionization of N_2. These data probe the partitioning of the angular momentum between the photoelectron and photoion, and highlight the multicenter nature of the molecular potential. These case studies illustrate the utility of dispersed fluorescence measurements as a complement to photoelectron spectroscopy for obtaining highly resolved data for molecular photoionization. These measurements makes it possible to probe intrinsically

  6. Star Formation Histories of the LEGUS Dwarf Galaxies. II. Spatially Resolved Star Formation History of the Magellanic Irregular NGC 4449

    Science.gov (United States)

    Sacchi, E.; Cignoni, M.; Aloisi, A.; Tosi, M.; Calzetti, D.; Lee, J. C.; Adamo, A.; Annibali, F.; Dale, D. A.; Elmegreen, B. G.; Gouliermis, D. A.; Grasha, K.; Grebel, E. K.; Hunter, D. A.; Sabbi, E.; Smith, L. J.; Thilker, D. A.; Ubeda, L.; Whitmore, B. C.

    2018-04-01

    We present a detailed study of the Magellanic irregular galaxy NGC 4449 based on both archival and new photometric data from the Legacy Extragalactic UV Survey, obtained with the Hubble Space Telescope Advanced Camera for Surveys and Wide Field Camera 3. Thanks to its proximity (D = 3.82 ± 0.27 Mpc), we reach stars 3 mag fainter than the tip of the red giant branch in the F814W filter. The recovered star formation history (SFH) spans the whole Hubble time, but due to the age–metallicity degeneracy of the red giant branch stars, it is robust only over the lookback time reached by our photometry, i.e., ∼3 Gyr. The most recent peak of star formation (SF) is around 10 Myr ago. The average surface density SF rate over the whole galaxy lifetime is 0.01 M ⊙ yr‑1 kpc‑2. From our study, it emerges that NGC 4449 has experienced a fairly continuous SF regime in the last 1 Gyr, with peaks and dips whose SF rates differ only by a factor of a few. The very complex and disturbed morphology of NGC 4449 makes it an interesting galaxy for studies of the relationship between interactions and starbursts, and our detailed and spatially resolved analysis of its SFH does indeed provide some hints on the connection between these two phenomena in this peculiar dwarf galaxy. Based on observations obtained with the NASA/ESA Hubble Space Telescope at the Space Telescope Science Institute, which is operated by the Association of Universities for Research in Astronomy under NASA contract NAS 5-26555.

  7. Associations between arrhythmia episodes and temporally and spatially resolved black carbon and particulate matter in elderly patients

    Science.gov (United States)

    Zanobetti, Antonella; Coull, Brent A.; Gryparis, Alexandros; Kloog, Itai; Sparrow, David; Vokonas, Pantel S; Wright, Robert O.; Gold, Diane R; Schwartz, Joel

    2015-01-01

    Objectives Ambient air pollution has been associated with sudden deaths, some of which are likely due to ventricular arrhythmias. Defibrillator discharge studies have examined the association of air pollution with arrhythmias in sensitive populations. No studies have assessed this association using residence-specific estimates of air pollution exposure. Methods In the Normative Aging Study, we investigated the association between temporally-and spatially-resolved black carbon (BC) and PM2.5 and arrhythmia episodes (bigeminy, trigeminy or couplets episodes) measured as ventricular ectopy (VE) by 4-min electrocardiogram (ECG) monitoring in repeated measures of 701 subjects, during the years 2000 to 2010. We used a binomial distribution (having or not a VE episode) in a mixed effect model with a random intercept for subject, controlling for seasonality, temperature, day of the week, medication use, smoking, having diabetes, BMI and age. We also examined whether these associations were modified by genotype or phenotype. Results We found significant increases in VE with both pollutants and lags; for the estimated concentration averaged over the three days prior to the health assessment we found increases in the odds of having VE with an OR of 1.52 (95% CI: 1.19–1.94) for an IQR (0.30 μg/m3) increase in BC and an OR of 1.39 (95% CI: 1.12–1.71) for an IQR (5.63 μg/m3) increase in PM2.5. We also found higher effects in subjects with the GSTT1 and GSTM1 variants and in obese (P-valuespollutants may increase the risk of ventricular arrhythmia in elderly subjects. PMID:24142987

  8. A method for in-situ spatially-resolved analysis of actinides in geomedia

    International Nuclear Information System (INIS)

    Clark, S.B.; Payne, R.F.

    2005-01-01

    It is well documented that U and Pu contamination in soils and sediments is not homogeneously distributed among all environmental surfaces, yet the composition of soil/sediment grains is quite variable and the chemistry controlling the partitioning to specific grains is not well understood. Fission track analysis (FTA) is a technique that directly detects nuclides with high fission cross sections, such as 235 U and 239 Pu, in many matrices including environmental materials. The fission track detector can be used to record the spatial distribution of contamination within the geomedia matrix. One limitation to FTA is that it cannot differentiate between 235 U and 239 Pu, nor does it provide any information about the composition of the grains to which the U or Pu is sorbed. In this work, we have developed an epoxy sample preparation technique that allows location of soil/sediment grains via FTA, and the irradiated sample can subsequently be coupled to laser ablation mass spectrometry (LAMS) with no additional sample preparation. This technique successfully allows grains containing 235 U and/or 239 Pu to be located and further analyzed. LAMS data provides Pu and U isotopic information and stable element analysis of the grains, thus providing the ability to study the nature of the interactions between the Pu and U with the environmental matrix.

  9. Spatially resolving the secretome within the mycelium of the cell factory Aspergillus niger.

    Science.gov (United States)

    Krijgsheld, Pauline; Altelaar, A F Maarten; Post, Harm; Ringrose, Jeffrey H; Müller, Wally H; Heck, Albert J R; Wösten, Han A B

    2012-05-04

    Aspergillus niger is an important cell factory for the industrial production of enzymes. These enzymes are released into the culture medium, from which they can be easily isolated. Here, we determined with stable isotope dimethyl labeling the secretome of five concentric zones of 7-day-old xylose-grown colonies of A. niger that had either or not been treated with cycloheximide. As expected, cycloheximide blocked secretion of proteins at the periphery of the colony. Unexpectedly, protein release was increased by cycloheximide in the intermediate and central zones of the mycelium when compared to nontreated colonies. Electron microscopy indicated that this is due to partial degradation of the cell wall. In total, 124 proteins were identified in cycloheximide-treated colonies, of which 19 secreted proteins had not been identified before. Within the pool of 124 proteins, 53 secreted proteins were absent in nontreated colonies, and additionally, 35 proteins were released ≥4-fold in the central and subperipheral zones of cycloheximide-treated colonies when compared to nontreated colonies. The composition of the secretome in each of the five concentric zones differed. This study thus describes spatial release of proteins in A. niger, which is instrumental in understanding how fungi degrade complex substrates in nature.

  10. Spatially resolved quantification of agrochemicals on plant surfaces using energy dispersive X-ray microanalysis.

    Science.gov (United States)

    Hunsche, Mauricio; Noga, Georg

    2009-12-01

    In the present study the principle of energy dispersive X-ray microanalysis (EDX), i.e. the detection of elements based on their characteristic X-rays, was used to localise and quantify organic and inorganic pesticides on enzymatically isolated fruit cuticles. Pesticides could be discriminated from the plant surface because of their distinctive elemental composition. Findings confirm the close relation between net intensity (NI) and area covered by the active ingredient (AI area). Using wide and narrow concentration ranges of glyphosate and glufosinate, respectively, results showed that quantification of AI requires the selection of appropriate regression equations while considering NI, peak-to-background (P/B) ratio, and AI area. The use of selected internal standards (ISs) such as Ca(NO(3))(2) improved the accuracy of the quantification slightly but led to the formation of particular, non-typical microstructured deposits. The suitability of SEM-EDX as a general technique to quantify pesticides was evaluated additionally on 14 agrochemicals applied at diluted or regular concentration. Among the pesticides tested, spatial localisation and quantification of AI amount could be done for inorganic copper and sulfur as well for the organic agrochemicals glyphosate, glufosinate, bromoxynil and mancozeb. (c) 2009 Society of Chemical Industry.

  11. Time-resolved diffraction studies of muscle using synchrotron radiation

    International Nuclear Information System (INIS)

    Harford, Jeffrey; Squire, John

    1997-01-01

    Muscle contraction is one of those biological phenomena that we can all appreciate in our everyday lives. Sometimes it is when we are resting quietly and are aware of our heartbeat. At other times it may be when we are exerting ourselves and become short of breath, or when we exercise for a long period and our muscles start to ache. The way in which muscles produce force has exercised the minds of philosophers and scientists at least since the days of Erasistratus in the third century BC. Nowadays, of course, we know a very great deal about muscle structure, physiology and biochemistry, but we still do not know exactly what the molecular process is that produces movement. An ideal way of probing this process would be to be able to obtain signals from the relevant molecules as they actually go through their normal force-generating routine in an active muscle. The spatial dimensions involved are in the region of 1-50 nm, thus precluding the use of light microscopy, and the time regime is microseconds to milliseconds. Techniques with the appropriate spatial resolution might be electron microscopy and x-ray diffraction, but electron microscopy cannot yet be carried out on living tissue. X-ray diffraction methods can clearly have the right sort of spatial resolution, but what about recording diffraction patterns in the very short times involved (say 1 ms)? It is here that the high flux from synchrotron storage rings comes into its own. Using synchrotron radiation from, say, the SRS at the CCLRC Daresbury Laboratory it is possible to record x-ray diffraction patterns from living muscles in the millisecond time regime and to follow how these diffraction patterns change as the muscles go through typical contraction cycles. Unfortunately, x-ray diffraction is not a direct imaging method; the observed distribution of diffracted intensity needs to be interpreted in some way to give useful information on the spatial relationships of the force-generating molecules. This review

  12. Sub-nA spatially resolved conductivity profiling of surface and interface defects in ceria films

    Directory of Open Access Journals (Sweden)

    Tim Farrow

    2015-03-01

    Full Text Available Spatial variability of conductivity in ceria is explored using scanning probe microscopy with galvanostatic control. Ionically blocking electrodes are used to probe the conductivity under opposite polarities to reveal possible differences in the defect structure across a thin film of CeO2. Data suggest the existence of a large spatial inhomogeneity that could give rise to constant phase elements during standard electrochemical characterization, potentially affecting the overall conductivity of films on the macroscale. The approach discussed here can also be utilized for other mixed ionic electronic conductor systems including memristors and electroresistors, as well as physical systems such as ferroelectric tunneling barriers.

  13. Resolving mass flux at high spatial and temporal resolution using GRACE intersatellite measurements

    DEFF Research Database (Denmark)

    Rowlands, D. D.; Luthcke, S. B.; Klosko, S. M.

    2005-01-01

    resolution. Using 4° × 4° blocks at 10-day intervals, we estimate the mass of surplus or deficit water over a 52° × 60° grid centered on the Amazon basin for July 2003. We demonstrate that the recovered signals are coherent and correlate well with the expected hydrological signal....... the estimation of static monthly parameters. Through an analysis of the GRACE data residuals, we show that the fundamental temporal and spatial resolution of the GRACE data is 10 days and 400 km. We present an approach similar in concept to altimetric methods that recovers submonthly mass flux at a high spatial...

  14. Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting

    Science.gov (United States)

    Roeffaers, Maarten B. J.; Sels, Bert F.; Uji-I, Hiroshi; de Schryver, Frans C.; Jacobs, Pierre A.; de Vos, Dirk E.; Hofkens, Johan

    2006-02-01

    Catalytic processes on surfaces have long been studied by probing model reactions on single-crystal metal surfaces under high vacuum conditions. Yet the vast majority of industrial heterogeneous catalysis occurs at ambient or elevated pressures using complex materials with crystal faces, edges and defects differing in their catalytic activity. Clearly, if new or improved catalysts are to be rationally designed, we require quantitative correlations between surface features and catalytic activity-ideally obtained under realistic reaction conditions. Transmission electron microscopy and scanning tunnelling microscopy have allowed in situ characterization of catalyst surfaces with atomic resolution, but are limited by the need for low-pressure conditions and conductive surfaces, respectively. Sum frequency generation spectroscopy can identify vibrations of adsorbed reactants and products in both gaseous and condensed phases, but so far lacks sensitivity down to the single molecule level. Here we adapt real-time monitoring of the chemical transformation of individual organic molecules by fluorescence microscopy to monitor reactions catalysed by crystals of a layered double hydroxide immersed in reagent solution. By using a wide field microscope, we are able to map the spatial distribution of catalytic activity over the entire crystal by counting single turnover events. We find that ester hydrolysis proceeds on the lateral {1010} crystal faces, while transesterification occurs on the entire outer crystal surface. Because the method operates at ambient temperature and pressure and in a condensed phase, it can be applied to the growing number of liquid-phase industrial organic transformations to localize catalytic activity on and in inorganic solids. An exciting opportunity is the use of probe molecules with different size and functionality, which should provide insight into shape-selective or structure-sensitive catalysis and thus help with the rational design of new or

  15. Visualizing chemical states and defects induced magnetism of graphene oxide by spatially-resolved-X-ray microscopy and spectroscopy.

    Science.gov (United States)

    Wang, Y F; Singh, Shashi B; Limaye, Mukta V; Shao, Y C; Hsieh, S H; Chen, L Y; Hsueh, H C; Wang, H T; Chiou, J W; Yeh, Y C; Chen, C W; Chen, C H; Ray, Sekhar C; Wang, J; Pong, W F; Takagi, Y; Ohigashi, T; Yokoyama, T; Kosugi, N

    2015-10-20

    This investigation studies the various magnetic behaviors of graphene oxide (GO) and reduced graphene oxides (rGOs) and elucidates the relationship between the chemical states that involve defects therein and their magnetic behaviors in GO sheets. Magnetic hysteresis loop reveals that the GO is ferromagnetic whereas photo-thermal moderately reduced graphene oxide (M-rGO) and heavily reduced graphene oxide (H-rGO) gradually become paramagnetic behavior at room temperature. Scanning transmission X-ray microscopy and corresponding X-ray absorption near-edge structure spectroscopy were utilized to investigate thoroughly the variation of the C 2p(π*) states that are bound with oxygen-containing and hydroxyl groups, as well as the C 2p(σ*)-derived states in flat and wrinkle regions to clarify the relationship between the spatially-resolved chemical states and the magnetism of GO, M-rGO and H-rGO. The results of X-ray magnetic circular dichroism further support the finding that C 2p(σ*)-derived states are the main origin of the magnetism of GO. Based on experimental results and first-principles calculations, the variation in magnetic behavior from GO to M-rGO and to H-rGO is interpreted, and the origin of ferromagnetism is identified as the C 2p(σ*)-derived states that involve defects/vacancies rather than the C 2p(π*) states that are bound with oxygen-containing and hydroxyl groups on GO sheets.

  16. SPATIALLY RESOLVED OBSERVATIONS OF THE BIPOLAR OPTICAL OUTFLOW FROM THE BROWN DWARF 2MASS J12073347–3932540

    International Nuclear Information System (INIS)

    Whelan, E. T.; Ray, T. P.; Comeron, F.; Bacciotti, F.; Kavanagh, P. J.

    2012-01-01

    Studies of brown dwarf (BD) outflows provide information pertinent to questions on BD formation, as well as allowing outflow mechanisms to be investigated at the lowest masses. Here new observations of the bipolar outflow from the 24 M JUP BD 2MASS J12073347–3932540 are presented. The outflow was originally identified through the spectro-astrometric analysis of the [O I]λ6300 emission line. Follow-up observations consisting of spectra and [S II], R-band and I-band images were obtained. The new spectra confirm the original results and are used to constrain the outflow position angle (P.A.) at ∼65°. The [O I]λ6300 emission line region is spatially resolved and the outflow is detected in the [S II] images. The detection is firstly in the form of an elongation of the point-spread function (PSF) along the direction of the outflow P.A. Four faint knot-like features (labeled A-D) are also observed to the southwest of 2MASS J12073347–3932540 along the same P.A. suggested by the spectra and the elongation in the PSF. Interestingly, D, the feature furthest from the source, is bow shaped with the apex pointing away from 2MASS J12073347–3932540. A color-color analysis allows us to conclude that at least feature D is part of the outflow under investigation while A is likely a star or galaxy. Follow-up observations are needed to confirm the origin of B and C. This is a first for a BD, as BD optical outflows have to date only been detected using spectro-astrometry. This result also demonstrates for the first time that BD outflows can be collimated and episodic.

  17. SPATIALLY RESOLVED SPECTROSCOPY AND CHEMICAL HISTORY OF STAR-FORMING GALAXIES IN THE HERCULES CLUSTER: THE EFFECTS OF THE ENVIRONMENT

    International Nuclear Information System (INIS)

    Petropoulou, V.; Vilchez, J.; Iglesias-Paramo, J.; Cedres, B.; Papaderos, P.; Magrini, L.; Reverte, D.

    2011-01-01

    Spatially resolved spectroscopy has been obtained for a sample of 27 star-forming (SF) galaxies selected from our deep Hα survey of the Hercules cluster. We have applied spectral synthesis models to all emission-line spectra of this sample using the population synthesis code STARLIGHT and have obtained fundamental parameters of stellar components such as mean metallicity and age. The emission-line spectra were corrected for underlying stellar absorption using these spectral synthesis models. Line fluxes were measured and O/H and N/O gas chemical abundances were obtained using the latest empirical calibrations. We have derived the masses and total luminosities of the galaxies using available Sloan Digital Sky Survey broadband photometry. The effects of cluster environment on the chemical evolution of galaxies and on their mass-metallicity (MZ) and luminosity-metallicity (LZ) relations were studied by combining the derived gas metallicities, the mean stellar metallicities and ages, the masses and luminosities of the galaxies, and their existing H I data. Our Hercules SF galaxies are divided into three main subgroups: (1) chemically evolved spirals with truncated ionized-gas disks and nearly flat oxygen gradients, demonstrating the effect of ram-pressure stripping; (2) chemically evolved dwarfs/irregulars populating the highest local densities, possible products of tidal interactions in preprocessing events; and (3) less metallic dwarf galaxies that appear to be 'newcomers' to the cluster and are experiencing pressure-triggered star formation. Most Hercules SF galaxies follow well-defined MZ and LZ sequences (for both O/H and N/O), though the dwarf/irregular galaxies located at the densest regions appear to be outliers to these global relations, suggesting a physical reason for the dispersion in these fundamental relations. The Hercules cluster appears to be currently assembling via the merger of smaller substructures, providing an ideal laboratory where the local

  18. Influence of cutaneous and muscular circulation on spatially resolved versus standard Beer-Lambert near-infrared spectroscopy.

    Science.gov (United States)

    Messere, Alessandro; Roatta, Silvestro

    2013-12-01

    The potential interference of cutaneous circulation on muscle blood volume and oxygenation monitoring by near-infrared spectroscopy (NIRS) remains an important limitation of this technique. Spatially resolved spectroscopy (SRS) was reported to minimize the contribution of superficial tissue layers in cerebral monitoring but this characteristic has never been documented in muscle tissue monitoring. This study aims to compare SRS with the standard Beer-Lambert (BL) technique in detecting blood volume changes selectively induced in muscle and skin. In 16 healthy subjects, the biceps brachii was investigated during isometric elbow flexion at 70% of the maximum voluntary contractions lasting 10 sec, performed before and after exposure of the upper arm to warm air flow. From probes applied over the muscle belly the following variables were recorded: total hemoglobin index (THI, SRS-based), total hemoglobin concentration (tHb, BL-based), tissue oxygenation index (TOI, SRS-based), and skin blood flow (SBF), using laser Doppler flowmetry. Blood volume indices exhibited similar changes during muscle contraction but only tHb significantly increased during warming (+5.2 ± 0.7 μmol/L·cm, an effect comparable to the increase occurring in postcontraction hyperemia), accompanying a 10-fold increase in SBF. Contraction-induced changes in tHb and THI were not substantially affected by warming, although the tHb tracing was shifted upward by (5.2 ± 3.5 μmol/L·cm, P < 0.01). TOI was not affected by cutaneous warming. In conclusion, SRS appears to effectively reject interference by SBF in both muscle blood volume and oxygenation monitoring. Instead, BL-based parameters should be interpreted with caution, whenever changes in cutaneous perfusion cannot be excluded.

  19. Influence of cutaneous and muscular circulation on spatially resolved versus standard Beer–Lambert near‐infrared spectroscopy

    Science.gov (United States)

    Messere, Alessandro; Roatta, Silvestro

    2013-01-01

    Abstract The potential interference of cutaneous circulation on muscle blood volume and oxygenation monitoring by near‐infrared spectroscopy (NIRS) remains an important limitation of this technique. Spatially resolved spectroscopy (SRS) was reported to minimize the contribution of superficial tissue layers in cerebral monitoring but this characteristic has never been documented in muscle tissue monitoring. This study aims to compare SRS with the standard Beer–Lambert (BL) technique in detecting blood volume changes selectively induced in muscle and skin. In 16 healthy subjects, the biceps brachii was investigated during isometric elbow flexion at 70% of the maximum voluntary contractions lasting 10 sec, performed before and after exposure of the upper arm to warm air flow. From probes applied over the muscle belly the following variables were recorded: total hemoglobin index (THI, SRS‐based), total hemoglobin concentration (tHb, BL‐based), tissue oxygenation index (TOI, SRS‐based), and skin blood flow (SBF), using laser Doppler flowmetry. Blood volume indices exhibited similar changes during muscle contraction but only tHb significantly increased during warming (+5.2 ± 0.7 μmol/L·cm, an effect comparable to the increase occurring in postcontraction hyperemia), accompanying a 10‐fold increase in SBF. Contraction‐induced changes in tHb and THI were not substantially affected by warming, although the tHb tracing was shifted upward by (5.2 ± 3.5 μmol/L·cm, P < 0.01). TOI was not affected by cutaneous warming. In conclusion, SRS appears to effectively reject interference by SBF in both muscle blood volume and oxygenation monitoring. Instead, BL‐based parameters should be interpreted with caution, whenever changes in cutaneous perfusion cannot be excluded. PMID:24744858

  20. Fiber Bragg grating based spatially resolved characterization of flux-pinning induced strain of rectangular-shaped bulk YBCO samples

    International Nuclear Information System (INIS)

    Latka, Ines; Habisreuther, Tobias; Litzkendorf, Doris

    2011-01-01

    Highlights: → Fiber Bragg gratings (FBG) act as strain sensors, also at cryogenic temperatures. → FBGs are not sensitive to magnetic fields. → Local, shape dependent magnetostriction was detected on rectangular samples. → Magnetostrictive effects of the top surface and in a gap between two samples are different. - Abstract: We report on measurements of the spatially resolved characterization of flux-pinning induced strain of rectangular-shaped bulk YBCO samples. The spatially resolved strain measurements are accomplished by the use 2 fiber Bragg grating arrays, which are with an included angle of 45 o fixed to the surface. In this paper first attempts to confirm the shape distortions caused by the flux-pinning induced strain as predicted in will be presented. Two sample setups, a single bulk and a 'mirror' arrangement, will be compared. This mirror setup represents a model configuration for a measurement inside the superconductor, where demagnetization effects can be neglected and the magnetic field merely has a z-component.

  1. Computation of the optical properties of turbid media from slope and curvature of spatially resolved reflectance curves

    International Nuclear Information System (INIS)

    Jäger, Marion; Foschum, Florian; Kienle, Alwin

    2013-01-01

    The optical properties of turbid media were calculated from the curvature at the radial distance ρ O and the slope at the radial distance ρ* of simulated spatially resolved reflectance curves (ρ O (ρ*) denotes a decrease of the spatially resolved reflectance curve of 0.75 (2.4) orders of magnitude relative to the reflectance value at 1.2 mm). We found correlations between the curvature at ρ O and the reduced scattering coefficient as well as the slope at ρ* and the absorption coefficient. For the determination of the optical properties we used these two correlations. The calculation of the reduced scattering coefficient from the curvature at ρ O is practically independent from the absorption coefficient. Knowing the reduced scattering coefficient within a certain accuracy allows the determination of the absorption coefficient from the slope at ρ*. Additionally, we investigated the performance of an artificial neural network for the determination of the optical properties using the above explained correlations. This means we used the derivatives as input data. Our artificial neural network was capable to learn the mapping between the optical properties and the derivatives. In effect, the results for the determined optical properties improved in comparison to the above explained method. Finally, the procedure was compared to an artificial neural network that was trained without using the derivatives. (note)

  2. Spatially Resolved Characterization of Cellulose Nanocrystal-Polypropylene Composite by Confocal Raman Microscopy

    Science.gov (United States)

    Umesh P. Agarwal; Ronald Sabo; Richard S. Reiner; Craig M. Clemons; Alan W. Rudie

    2012-01-01

    Raman spectroscopy was used to analyze cellulose nanocrystal (CNC)–polypropylene (PP) composites and to investigate the spatial distribution of CNCs in extruded composite filaments. Three composites were made from two forms of nanocellulose (CNCs from wood pulp and the nanoscale fraction of microcrystalline cellulose) and two of the three composites investigated used...

  3. Spatially and spectrally resolved 10 mu m emission in Herbig Ae/Be stars

    NARCIS (Netherlands)

    van Boekel, R; Waters, LBFM; Dominik, C; Dullemond, CP; Tielens, AGGM; de Koter, A

    We present new mid-infrared spectroscopy of the emission from warm circumstellar dust grains in the Herbig Ae stars HD 100546. HD 97048 and HD 104237, with a spatial resolution Of of approximate to0."9. We find that the emission in the UIR bands at 8.6, 11.3 and (HD 97048 only) 12.7 mum is extended

  4. Spatially resolved modelling of inhomogeneous materials with a first order magnetic phase transition

    DEFF Research Database (Denmark)

    Nielsen, Kaspar Kirstein; Bahl, Christian; Smith, Anders

    2017-01-01

    of regions each having a uniform and defined through a Voronoi-map. We show that demagnetising effects, caused by a finite sample size, and spatial variation in can account for the previously experimentally observed 'virgin' effects in the adiabatic temperature change and isothermal entropy change...

  5. Chapter 1.4: Spatially Resolved Characterization of CNC-Polypropylene composite by Confocal Raman Microscopy

    Science.gov (United States)

    Umesh Agarwal; Ronald Sabo; Richard Reiner; Craig Clemons; Alan Rudie

    2013-01-01

    Raman spectroscopy was used to analyze cellulose nanocrystal (CNC)-polypropylene (PP) composites and to investigate the spatial distribution of CNCs in extruded composite filaments. Three composites were made from two forms of nanocellulose (CNCs from wood pulp and the nanoscale fraction of microcrystalline cellulose), and two of the three composites...

  6. Spatially resolved data on sediment transport: 1) field application examining fluorescent soil particle movement from tillage

    Science.gov (United States)

    Quinton, John; Hardy, Robert; Pates, Jacqueline; James, Michael

    2017-04-01

    Understanding where sediment originates from and where it travels to, in what quantities and at which rate is at the heart of many questions surrounding sediment transport. Progress towards unravelling these questions and deepening our understanding has come from a wide range of approaches, including laboratory and field experiments conducted at a variety of scales. In seeking to understand the connectivity of sources and sinks of sediment scientists have spent considerable energy in developing tracing technologies. These have included numerous studies that have relied on the chemical properties of the soil and sediment to establish source-sink connectivity, and the use of 137Ceasium, from radioactive fall-out, to map sediment redistribution. More recently there has been an upsurge in interest in the use of artificially applied soil tracers, including rare earth element oxides and magnetic minerals. However all these tracing methods have a significant drawback: they rely on the collection of samples to assess their concentration. This means that their spatial distribution cannot easily be established in situ and that the environment that is being studied is damaged by the sampling process; nor can data be collected in real time which allows a dynamic understanding of erosion and transport processes to be developed. Here we report on the field application of a fluorescent sand sized tracer at the hillslope scale during a tillage erosion experiment. Here we trialled both intensity based and particle counting methodologies for tracer enumeration. After simulating seven years of tillage on a hillslope we were able to precisely determine the distribution of the fluorescent tracer and also its incorporation and distribution within the soil profile. Single grains of tracer could be found over 35 m from the insertion point. In a second abstract we report on an application that combines novel fluorescent videography techniques with custom image processing to trace the

  7. Radiative and magnetic properties of solar active regions. II. Spatially resolved analysis of O V 62.97 nm transition region emission

    Science.gov (United States)

    Fludra, A.; Warren, H.

    2010-11-01

    Context. Global relationships between the photospheric magnetic flux and the extreme ultraviolet emission integrated over active region area have been studied in a previous paper by Fludra & Ireland (2008, A&A, 483, 609). Spatially integrated EUV line intensities are tightly correlated with the total unsigned magnetic flux, and yet these global power laws have been shown to be insufficient for accurately determining the coronal heating mechanism owing to the mathematical ill-conditioning of the inverse problem. Aims: Our aim is to establish a relationship between the EUV line intensities and the photospheric magnetic flux density on small spatial scales in active regions and investigate whether it provides a way of identifying the process that heats the coronal loops. Methods: We compare spatially resolved EUV transition region emission and the photospheric magnetic flux density. This analysis is based on the O V 62.97 nm line recorded by the SOHO Coronal Diagnostic Spectrometer (CDS) and SOHO MDI magnetograms for six solar active regions. The magnetic flux density ϕ is converted to a simulated O V intensity using a model relationship I(ϕ, L) = Cϕδ Lλ, where the loop length L is obtained from potential magnetic field extrapolations. This simulated spatial distribution of O V intensities is convolved with the CDS instrument's point spread function and compared pixel by pixel with the observed O V line intensity. Parameters δ and λ are derived to give the best fit for the observed and simulated intensities. Results: Spatially-resolved analysis of the transition region emission reveals the complex nature of the heating processes in active regions. In some active regions, particularly large, local intensity enhancements up to a factor of five are present. When areas with O V intensities above 3000 erg cm-2 s-1 sr-1 are ignored, a power law has been fitted to the relationship between the local O V line intensity and the photospheric magnetic flux density in each

  8. Spatially and temporally resolved x-ray emission from imploding laser fusion targets

    International Nuclear Information System (INIS)

    Attwood, D.T.; Coleman, L.W.; Boyle, M.J.; Phillion, D.W.; Swain, J.E.; Manes, K.R.; Larsen, J.T.

    1976-09-01

    The Livermore 15 psec x-ray streak camera has been used in conjunction with 6 μm diameter pinholes to record well resolved implosion histories of DT filled laser fusion targets. The space-time compression data provide clearly identified implosion velocities, typically 3 x 10 7 cm/sec for two-sided clamshell irradiation of a 70 μm/sup D/, .5 μm wall DT filled glass microshell. Single-sided irradiation results show hydrodynamic convergence at the target center, followed by an asymmetric but two-sided target disassembly. These experiments were performed at the two arm Janus Laser facility, which typically delivered a total of 0.4 TW in a 70 psec pulse for these experiments

  9. Spatially resolved ultrasonic attenuation in resistance spot welds: implications for nondestructive testing.

    Science.gov (United States)

    Mozurkewich, George; Ghaffari, Bita; Potter, Timothy J

    2008-09-01

    Spatial variation of ultrasonic attenuation and velocity has been measured in plane parallel specimens extracted from resistance spot welds. In a strong weld, attenuation is larger in the nugget than in the parent material, and the region of increased attenuation is surrounded by a ring of decreased attenuation. In the center of a stick weld, attenuation is even larger than in a strong weld, and the low-attenuation ring is absent. These spatial variations are interpreted in terms of differences in grain size and martensite formation. Measured frequency dependences indicate the presence of an additional attenuation mechanism besides grain scattering. The observed attenuations do not vary as commonly presumed with weld quality, suggesting that the common practice of using ultrasonic attenuation to indicate weld quality is not a reliable methodology.

  10. Research Update: Spatially resolved mapping of electronic structure on atomic level by multivariate statistical analysis

    International Nuclear Information System (INIS)

    Belianinov, Alex; Ganesh, Panchapakesan; Lin, Wenzhi; Jesse, Stephen; Pan, Minghu; Kalinin, Sergei V.; Sales, Brian C.; Sefat, Athena S.

    2014-01-01

    Atomic level spatial variability of electronic structure in Fe-based superconductor FeTe 0.55 Se 0.45 (T c = 15 K) is explored using current-imaging tunneling-spectroscopy. Multivariate statistical analysis of the data differentiates regions of dissimilar electronic behavior that can be identified with the segregation of chalcogen atoms, as well as boundaries between terminations and near neighbor interactions. Subsequent clustering analysis allows identification of the spatial localization of these dissimilar regions. Similar statistical analysis of modeled calculated density of states of chemically inhomogeneous FeTe 1−x Se x structures further confirms that the two types of chalcogens, i.e., Te and Se, can be identified by their electronic signature and differentiated by their local chemical environment. This approach allows detailed chemical discrimination of the scanning tunneling microscopy data including separation of atomic identities, proximity, and local configuration effects and can be universally applicable to chemically and electronically inhomogeneous surfaces

  11. Spatially resolved transport data for electrons in gases: Definition, interpretation and calculation

    International Nuclear Information System (INIS)

    Dujko, S.; White, R.D.; Raspopović, Z.M.; Petrović, Z.Lj.

    2012-01-01

    The spatiotemporal evolution of electron swarms in the presence of electric and magnetic fields is investigated to facilitate understanding temporal and spatial non-locality in low-temperature plasmas. Using two independent techniques, a multi-term solution of Boltzmann’s equation and a Monte Carlo simulation technique, the synergism of an applied magnetic field and non-conservative collisions (ionization and/or electron attachment) is demonstrated as a means to control the non-locality of relaxation processes. In particular, oscillatory features in the spatial and temporal profiles are demonstrated, and shown to be enhanced or suppressed through the magnetic field strength, the angle between the electric and magnetic fields, and the degree of ionization. Finally we discuss the impact of field configurations and strengths on the transport properties, highlighting the distinctions in the measured transport properties between various experimental configurations when non-conservative processes are present.

  12. Spatially and temporally resolved EUV emissions from SATURN z-pinches

    International Nuclear Information System (INIS)

    Nash, T.J.; Breeze, S.; Mock, R.; Jobe, D.

    1995-01-01

    EUV emissions can be used to measure several z-pinch parameters. The authors have measured implosion velocity from Doppler splitting of lines and estimated electron temperature during run-in from the mean ionization state of line emissions. In an argon pinch they measure an electron temperature of 100 eV before stagnation. To date Doppler split lines have measured implosion velocities less than 40 cm/microsecond. They are presently attempting to measure magnetic field or load current from Zeeman splitting and it may be possible to measure electron density from a Stark-broadened line. Opacity and ion thermal broadening may also contribute to line width information. The spectrometer utilizes a variable line space grating to give a flat focal field. Spectral resolution with a 60 micron detector resolution is up to 3,000 and generally increases with wavelength. This is sufficient to detect several plasma line broadening mechanisms. The spectrometer may detect lines above 100 angstrom and below 1,400 angstrom. Spectral range across a microchannel plate stripline detector decreases with increasing wavelength setting. The authors may gate two striplines with 1 to 12 nsec gates at any time during the pinch discharge. Each stripline spatially images the pinch diameter perpendicular to the direction of dispersion. Spatial resolution in the pinch diameter is 1 mm. Spatial acquisition along the z axis is also 1 mm. Data are presented from argon, krypton, and aluminum z-pinch discharges on the SATURN accelerator

  13. Towards real-time non contact spatial resolved oxygenation monitoring using a multi spectral filter array camera in various light conditions

    Science.gov (United States)

    Bauer, Jacob R.; van Beekum, Karlijn; Klaessens, John; Noordmans, Herke Jan; Boer, Christa; Hardeberg, Jon Y.; Verdaasdonk, Rudolf M.

    2018-02-01

    Non contact spatial resolved oxygenation measurements remain an open challenge in the biomedical field and non contact patient monitoring. Although point measurements are the clinical standard till this day, regional differences in the oxygenation will improve the quality and safety of care. Recent developments in spectral imaging resulted in spectral filter array cameras (SFA). These provide the means to acquire spatial spectral videos in real-time and allow a spatial approach to spectroscopy. In this study, the performance of a 25 channel near infrared SFA camera was studied to obtain spatial oxygenation maps of hands during an occlusion of the left upper arm in 7 healthy volunteers. For comparison a clinical oxygenation monitoring system, INVOS, was used as a reference. In case of the NIRS SFA camera, oxygenation curves were derived from 2-3 wavelength bands with a custom made fast analysis software using a basic algorithm. Dynamic oxygenation changes were determined with the NIR SFA camera and INVOS system at different regional locations of the occluded versus non-occluded hands and showed to be in good agreement. To increase the signal to noise ratio, algorithm and image acquisition were optimised. The measurement were robust to different illumination conditions with NIR light sources. This study shows that imaging of relative oxygenation changes over larger body areas is potentially possible in real time.

  14. Spatially resolved quantum plasmon modes in metallic nano-films from first-principles

    DEFF Research Database (Denmark)

    Andersen, Kirsten; Jacobsen, Karsten W.; Thygesen, Kristian S.

    2012-01-01

    Electron energy loss spectroscopy (EELS) can be used to probe plasmon excitations in nanostructured materials with atomic-scale spatial resolution. For structures smaller than a few nanometers, quantum effects are expected to be important, limiting the validity of widely used semiclassical response...... as (conventional) surface modes, subsurface modes, and a discrete set of bulk modes resembling standing waves across the film. We find clear effects of both quantum confinement and nonlocal response. The quantum plasmon modes provide an intuitive picture of collective excitations of confined electron systems...

  15. The SAMI Galaxy Survey: spatially resolving the main sequence of star formation

    Science.gov (United States)

    Medling, Anne M.; Cortese, Luca; Croom, Scott M.; Green, Andrew W.; Groves, Brent; Hampton, Elise; Ho, I.-Ting; Davies, Luke J. M.; Kewley, Lisa J.; Moffett, Amanda J.; Schaefer, Adam L.; Taylor, Edward; Zafar, Tayyaba; Bekki, Kenji; Bland-Hawthorn, Joss; Bloom, Jessica V.; Brough, Sarah; Bryant, Julia J.; Catinella, Barbara; Cecil, Gerald; Colless, Matthew; Couch, Warrick J.; Drinkwater, Michael J.; Driver, Simon P.; Federrath, Christoph; Foster, Caroline; Goldstein, Gregory; Goodwin, Michael; Hopkins, Andrew; Lawrence, J. S.; Leslie, Sarah K.; Lewis, Geraint F.; Lorente, Nuria P. F.; Owers, Matt S.; McDermid, Richard; Richards, Samuel N.; Sharp, Robert; Scott, Nicholas; Sweet, Sarah M.; Taranu, Dan S.; Tescari, Edoardo; Tonini, Chiara; van de Sande, Jesse; Walcher, C. Jakob; Wright, Angus

    2018-04-01

    We present the ˜800 star formation rate maps for the Sydney-AAO Multi-object Integral field spectrograph (SAMI) Galaxy Survey based on H α emission maps, corrected for dust attenuation via the Balmer decrement, that are included in the SAMI Public Data Release 1. We mask out spaxels contaminated by non-stellar emission using the [O III]/H β, [N II]/H α, [S II]/H α, and [O I]/H α line ratios. Using these maps, we examine the global and resolved star-forming main sequences of SAMI galaxies as a function of morphology, environmental density, and stellar mass. Galaxies further below the star-forming main sequence are more likely to have flatter star formation profiles. Early-type galaxies split into two populations with similar stellar masses and central stellar mass surface densities. The main-sequence population has centrally concentrated star formation similar to late-type galaxies, while galaxies >3σ below the main sequence show significantly reduced star formation most strikingly in the nuclear regions. The split populations support a two-step quenching mechanism, wherein halo mass first cuts off the gas supply and remaining gas continues to form stars until the local stellar mass surface density can stabilize the reduced remaining fuel against further star formation. Across all morphologies, galaxies in denser environments show a decreased specific star formation rate from the outside in, supporting an environmental cause for quenching, such as ram-pressure stripping or galaxy interactions.

  16. Spatially resolving the very high energy emission from MGRO J2019+37 with VERITAS

    International Nuclear Information System (INIS)

    Aliu, E.; Errando, M.; Aune, T.; Behera, B.; Chen, X.; Federici, S.; Beilicke, M.; Buckley, J. H.; Bugaev, V.; Benbow, W.; Cerruti, M.; Berger, K.; Bird, R.; Bouvier, A.; Ciupik, L.; Connolly, M. P.; Cui, W.; Dumm, J.; Dwarkadas, V. V.; Falcone, A.

    2014-01-01

    We present very high energy (VHE) imaging of MGRO J2019+37 obtained with the VERITAS observatory. The bright extended (∼2°) unidentified Milagro source is located toward the rich star formation region Cygnus-X. MGRO J2019+37 is resolved into two VERITAS sources. The faint, point-like source VER J2016+371 overlaps CTB 87, a filled-center remnant (SNR) with no evidence of a supernova remnant shell at the present time. Its spectrum is well fit in the 0.65-10 TeV energy range by a power-law model with photon index 2.3 ± 0.4. VER J2019+378 is a bright extended (∼1°) source that likely accounts for the bulk of the Milagro emission and is notably coincident with PSR J2021+3651 and the star formation region Sh 2–104. Its spectrum in the range 1-30 TeV is well fit with a power-law model of photon index 1.75 ± 0.3, among the hardest values measured in the VHE band, comparable to that observed near Vela-X. We explore the unusual spectrum and morphology in the radio and X-ray bands to constrain possible emission mechanisms for this source.

  17. Spatially resolved localized vibrational mode spectroscopy of carbon in liquid encapsulated Czochralski grown gallium arsenide wafers

    International Nuclear Information System (INIS)

    Yau, Waifan.

    1988-04-01

    Substitutional carbon on an arsenic lattice site is the shallowest and one of the most dominant acceptors in semi-insulating Liquid Encapsulated Czochralski (LEC) GaAs. However, the role of this acceptor in determining the well known ''W'' shape spatial variation of neutral EL2 concentration along the diameter of a LEC wafer is not known. In this thesis, we attempt to clarify the issue of the carbon acceptor's effect on this ''W'' shaped variation by measuring spatial profiles of this acceptor along the radius of three different as-grown LEC GaAs wafers. With localized vibrational mode absorption spectroscopy, we find that the profile of the carbon acceptor is relatively constant along the radius of each wafer. Average values of concentration are 8 x 10E15 cm -3 , 1.1 x 10E15 cm -3 , and 2.2 x 10E15 cm -3 , respectively. In addition, these carbon acceptor LVM measurements indicate that a residual donor with concentration comparable to carbon exists in these wafers and it is a good candidate for the observed neutral EL2 concentration variation. 22 refs., 39 figs

  18. Application of spatially resolved high resolution crystal spectrometry to inertial confinement fusion plasmas.

    Science.gov (United States)

    Hill, K W; Bitter, M; Delgado-Aparacio, L; Pablant, N A; Beiersdorfer, P; Schneider, M; Widmann, K; Sanchez del Rio, M; Zhang, L

    2012-10-01

    High resolution (λ∕Δλ ∼ 10 000) 1D imaging x-ray spectroscopy using a spherically bent crystal and a 2D hybrid pixel array detector is used world wide for Doppler measurements of ion-temperature and plasma flow-velocity profiles in magnetic confinement fusion plasmas. Meter sized plasmas are diagnosed with cm spatial resolution and 10 ms time resolution. This concept can also be used as a diagnostic of small sources, such as inertial confinement fusion plasmas and targets on x-ray light source beam lines, with spatial resolution of micrometers, as demonstrated by laboratory experiments using a 250-μm (55)Fe source, and by ray-tracing calculations. Throughput calculations agree with measurements, and predict detector counts in the range 10(-8)-10(-6) times source x-rays, depending on crystal reflectivity and spectrometer geometry. Results of the lab demonstrations, application of the technique to the National Ignition Facility (NIF), and predictions of performance on NIF will be presented.

  19. Tunable Reflective Spatial Heterodyne Spectrometer: A Technique for High Resolving Power, Wide Field Of View Observation Of Diffuse Emission Line Sources

    Science.gov (United States)

    Hosseini, Seyedeh Sona

    The purpose of this dissertation is to discuss the need for new technology in broadband high-resolution spectroscopy based on the emerging technique of Spatial Heterodyne Spectroscopy (SHS) and to propose new solutions that should enhance and generalize this technology to other fields. Spectroscopy is a proven tool for determining compositional and other properties of remote objects. Narrow band imaging and low resolving spectroscopic measurements provide information about composition, photochemical evolution, energy distribution and density. The extension to high resolving power provides further access to temperature, velocity, isotopic ratios, separation of blended sources, and opacity effects. In current high resolving power devices, the drawback of high-resolution spectroscopy is bound to the instrumental limitations of lower throughput, the necessity of small entrance apertures, sensitivity, field of view, and large physical instrumental size. These limitations quickly become handicapping for observation of faint and/or extended targets and for spacecraft encounters. A technique with promise for the study of faint and extended sources at high resolving power is the reflective format of the Spatial Heterodyne Spectrometer (SHS). SHS instruments are compact and naturally tailored for both high etendue (defined in section 2.2.5) and high resolving power. In contrast, to achieve similar spectral grasp, grating spectrometers require large telescopes. For reference, SHS is a cyclical interferometer that produces Fizeau fringe pattern for all other wavelengths except the tuned wavelength. The large etendue obtained by SHS instruments makes them ideal for observations of extended, low surface brightness, isolated emission line sources, while their intrinsically high spectral resolution enables one to study the dynamical and physical properties described above. This document contains four chapters. Chapter 1, introduces a class of scientific targets that formerly have

  20. Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy

    DEFF Research Database (Denmark)

    Grunwaldt, Jan-Dierk; Kimmerle, B.; Baiker, A.

    2009-01-01

    available techniques, X-ray absorption spectroscopy (XAS) is a well-suited tool for this purpose as the different selected examples highlight. Two different techniques, scanning and full-field X-ray microscopy/tomography, are described and compared. At first, the tomographic structure of impregnated alumina...... pellets is presented using full-field transmission microtomography and compared to the results obtained with a scanning X-ray microbeam technique to analyse the catalyst bed inside a catalytic quartz glass reactor. On the other hand, by using XAS in scanning microtomography, the structure...... metal-based catalysts. In order to obtain spectroscopic information on the spatial variation of the oxidation state of the catalyst inside the reactor XAS spectra were recorded by scanning with a micro-focussed beam along the catalyst bed. Alternatively, full-field transmission imaging was used...

  1. SPATIALLY RESOLVED GAS KINEMATICS WITHIN A Lyα NEBULA: EVIDENCE FOR LARGE-SCALE ROTATION

    Energy Technology Data Exchange (ETDEWEB)

    Prescott, Moire K. M. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Martin, Crystal L. [Department of Physics, Broida Hall, Mail Code 9530, University of California, Santa Barbara, CA 93106 (United States); Dey, Arjun, E-mail: mkmprescott@dark-cosmology.dk [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States)

    2015-01-20

    We use spatially extended measurements of Lyα as well as less optically thick emission lines from an ≈80 kpc Lyα nebula at z ≈ 1.67 to assess the role of resonant scattering and to disentangle kinematic signatures from Lyα radiative transfer effects. We find that the Lyα, C IV, He II, and C III] emission lines all tell a similar story in this system, and that the kinematics are broadly consistent with large-scale rotation. First, the observed surface brightness profiles are similar in extent in all four lines, strongly favoring a picture in which the Lyα photons are produced in situ instead of being resonantly scattered from a central source. Second, we see low kinematic offsets between Lyα and the less optically thick He II line (∼100-200 km s{sup –1}), providing further support for the argument that the Lyα and other emission lines are all being produced within the spatially extended gas. Finally, the full velocity field of the system shows coherent velocity shear in all emission lines: ≈500 km s{sup –1} over the central ≈50 kpc of the nebula. The kinematic profiles are broadly consistent with large-scale rotation in a gas disk that is at least partially stable against collapse. These observations suggest that the Lyα nebula represents accreting material that is illuminated by an offset, hidden active galactic nucleus or distributed star formation, and that is undergoing rotation in a clumpy and turbulent gas disk. With an implied mass of M(

  2. Spatial-Resolved Measurement and Analysis of Extreme-Ultraviolet Emission Spectra from Laser-Produced Al Plasmas

    International Nuclear Information System (INIS)

    Cao Shi-Quan; Su Mao-Gen; Sun Dui-Xiong; Min Qi; Dong Chen-Zhong

    2016-01-01

    Extreme ultraviolet emission from laser-produced Al plasma is experimentally and theoretically investigated. Spatial-evolution emission spectra are measured by using the spatio-temporally resolved laser produced plasma technique. Based on the assumptions of a normalized Boltzmann distribution among the excited states and a steady-state collisional-radiative model, we succeed in reproducing the spectra at different detection positions, which are in good agreement with experiments. The decay curves about the electron temperature and electron density, as well as the fractions of individual Al ions and average ionization stage with increasing the detection distance are obtained by comparison with the experimental measurements. These parameters are critical points for deeply understanding the expanding and cooling of laser produced plasmas in vacuum. (paper)

  3. Spatially and spectrally resolved photoluminescence of InGaN MQWs grown on highly Si doped a-plane GaN buffer

    Energy Technology Data Exchange (ETDEWEB)

    Thunert, Martin; Wieneke, Matthias; Dempewolf, Anja; Bertram, Frank; Dadgar, Armin; Krost, Alois; Christen, Juergen [Institute of Experimental Physics, Otto-von-Guericke-University Magdeburg (Germany)

    2011-07-01

    A set of InGaN multi quantum well (MQW) samples grown by MOVPE on highly Si doped a-plane GaN on r-plane sapphire templates has been investigated using spatially resolved photoluminescence spectroscopy ({mu}-PL). The Si doping level of nominal about 10{sup 20} cm{sup -3} leads to three dimensionally grown crystallites mostly terminated by m-facets. The MQW thickness has been systematically varied from nominally 2.1 to 4.2 nm, as well as the InGaN growth temperature, which was varied from 760 C to 700 C. The growth of a-plane GaN based devices leads to a non-polar growth direction avoiding the polarization field affected Quantum-Confined-Stark-Effect. Spatially resolved PL studies show for all samples low near band edge (NBE) GaN emission intensity over the whole area under investigation accompanied by highly intense InGaN MQW emission for single crystallites. The MQW luminescence shows a systematic blueshift with increasing InGaN growth temperature due to lower In incorporation as well as a systematic redshift with increasing MQW thickness. Excitation power dependent spectra at 4 K as well as temperature dependent PL spectra will be presented.

  4. Computed tomography with energy-resolved detection: a feasibility study

    Science.gov (United States)

    Shikhaliev, Polad M.

    2008-03-01

    The feasibility of computed tomography (CT) with energy-resolved x-ray detection has been investigated. A breast CT design with multi slit multi slice (MSMS) data acquisition was used for this study. The MSMS CT includes linear arrays of photon counting detectors separated by gaps. This CT configuration allows for efficient scatter rejection and 3D data acquisition. The energy-resolved CT images were simulated using a digital breast phantom and the design parameters of the proposed MSMS CT. The phantom had 14 cm diameter and 50/50 adipose/glandular composition, and included carcinoma, adipose, blood, iodine and CaCO3 as contrast elements. The x-ray technique was 90 kVp tube voltage with 660 mR skin exposure. Photon counting, charge (energy) integrating and photon energy weighting CT images were generated. The contrast-to-noise (CNR) improvement with photon energy weighting was quantified. The dual energy subtracted images of CaCO3 and iodine were generated using a single CT scan at a fixed x-ray tube voltage. The x-ray spectrum was electronically split into low- and high-energy parts by a photon counting detector. The CNR of the energy weighting CT images of carcinoma, blood, adipose, iodine, and CaCO3 was higher by a factor of 1.16, 1.20, 1.21, 1.36 and 1.35, respectively, as compared to CT with a conventional charge (energy) integrating detector. Photon energy weighting was applied to CT projections prior to dual energy subtraction and reconstruction. Photon energy weighting improved the CNR in dual energy subtracted CT images of CaCO3 and iodine by a factor of 1.35 and 1.33, respectively. The combination of CNR improvements due to scatter rejection and energy weighting was in the range of 1.71-2 depending on the type of the contrast element. The tilted angle CZT detector was considered as the detector of choice. Experiments were performed to test the effect of the tilting angle on the energy spectrum. Using the CZT detector with 20° tilting angle decreased the

  5. Spatially resolved near infrared observations of Enceladus' tiger stripe eruptions from Cassini VIMS

    Science.gov (United States)

    Dhingra, Deepak; Hedman, Matthew M.; Clark, Roger N.; Nicholson, Philip D.

    2017-08-01

    Particle properties of individual fissure eruptions within Enceladus' plume have been analyzed using high spatial resolution Visible and Infrared Mapping Spectrometer (VIMS) observations from the Cassini mission. To first order, the spectra of the materials emerging from Cairo, Baghdad and Damascus sulci are very similar, with a strong absorption band around 3 μm due to water-ice. The band minimum position indicates that the ice grains emerging from all the fissures are predominantly crystalline, which implies that the water-ice particles' formation temperatures are likely above 130 K. However, there is also evidence for subtle variations in the material emerging from the different source fissures. Variations in the spectral slope between 1-2.5 μm are observed and probably reflect differences in the size distributions of particles between 0.5 and 5 μm in radius. We also note variations in the shape of the 3 μm water-ice absorption band, which are consistent with differences in the relative abundance of > 5 μm particles. These differences in the particle size distribution likely reflect variations in the particle formation conditions and/or their transport within the fissures. These observations therefore provide strong motivation for detailed modeling to help place important constraints on the diversity of the sub-surface environmental conditions at the geologically active south-pole of Enceladus.

  6. Spatially resolved mapping of electrical conductivity across individual domain (grain) boundaries in graphene.

    Science.gov (United States)

    Clark, Kendal W; Zhang, X-G; Vlassiouk, Ivan V; He, Guowei; Feenstra, Randall M; Li, An-Ping

    2013-09-24

    All large-scale graphene films contain extended topological defects dividing graphene into domains or grains. Here, we spatially map electronic transport near specific domain and grain boundaries in both epitaxial graphene grown on SiC and CVD graphene on Cu subsequently transferred to a SiO2 substrate, with one-to-one correspondence to boundary structures. Boundaries coinciding with the substrate step on SiC exhibit a significant potential barrier for electron transport of epitaxial graphene due to the reduced charge transfer from the substrate near the step edge. Moreover, monolayer-bilayer boundaries exhibit a high resistance that can change depending on the height of substrate step coinciding at the boundary. In CVD graphene, the resistance of a grain boundary changes with the width of the disordered transition region between adjacent grains. A quantitative modeling of boundary resistance reveals the increased electron Fermi wave vector within the boundary region, possibly due to boundary induced charge density variation. Understanding how resistance change with domain (grain) boundary structure in graphene is a crucial first step for controlled engineering of defects in large-scale graphene films.

  7. Resolving the Spatial Structures of Bound Hole States in Black Phosphorus.

    Science.gov (United States)

    Qiu, Zhizhan; Fang, Hanyan; Carvalho, Alexandra; Rodin, A S; Liu, Yanpeng; Tan, Sherman J R; Telychko, Mykola; Lv, Pin; Su, Jie; Wang, Yewu; Castro Neto, A H; Lu, Jiong

    2017-11-08

    Understanding the local electronic properties of individual defects and dopants in black phosphorus (BP) is of great importance for both fundamental research and technological applications. Here, we employ low-temperature scanning tunnelling microscope (LT-STM) to probe the local electronic structures of single acceptors in BP. We demonstrate that the charge state of individual acceptors can be reversibly switched by controlling the tip-induced band bending. In addition, acceptor-related resonance features in the tunnelling spectra can be attributed to the formation of Rydberg-like bound hole states. The spatial mapping of the quantum bound states shows two distinct shapes evolving from an extended ellipse shape for the 1s ground state to a dumbbell shape for the 2p x excited state. The wave functions of bound hole states can be well-described using the hydrogen-like model with anisotropic effective mass, corroborated by our theoretical calculations. Our findings not only provide new insight into the many-body interactions around single dopants in this anisotropic two-dimensional material but also pave the way to the design of novel quantum devices.

  8. Spatially resolved observation of the fundamental and second harmonic standing kink modes using SDO/AIA

    Science.gov (United States)

    Pascoe, D. J.; Goddard, C. R.; Nakariakov, V. M.

    2016-09-01

    Aims: We consider a coronal loop kink oscillation observed by the Atmospheric Imaging Assembly (AIA) of the Solar Dynamics Observatory (SDO) which demonstrates two strong spectral components. The period of the lower frequency component being approximately twice that of the shorter frequency component suggests the presence of harmonics. Methods: We examine the presence of two longitudinal harmonics by investigating the spatial dependence of the loop oscillation. The time-dependent displacement of the loop is measured at 15 locations along the loop axis. For each position the displacement is fitted as the sum of two damped sinusoids, having periods P1 and P2, and a damping time τ. The shorter period component exhibits anti-phase oscillations in the loop legs. Results: We interpret the observation in terms of the first (global or fundamental) and second longitudinal harmonics of the standing kink mode. The strong excitation of the second harmonic appears connected to the preceding coronal mass ejection (CME) which displaced one of the loop legs. The oscillation parameters found are P1 = 5.00±0.62 min, P2 = 2.20±0.23 min, P1/ 2P2 = 1.15±0.22, and τ/P = 3.35 ± 1.45. A movie associated to Fig. 5 is available in electronic form at http://www.aanda.org

  9. Spatially resolved metabolic analysis reveals a central role for transcriptional control in carbon allocation to wood.

    Science.gov (United States)

    Roach, Melissa; Arrivault, Stéphanie; Mahboubi, Amir; Krohn, Nicole; Sulpice, Ronan; Stitt, Mark; Niittylä, Totte

    2017-06-15

    The contribution of transcriptional and post-transcriptional regulation to modifying carbon allocation to developing wood of trees is not well defined. To clarify the role of transcriptional regulation, the enzyme activity patterns of eight central primary metabolism enzymes across phloem, cambium, and developing wood of aspen (Populus tremula L.) were compared with transcript levels obtained by RNA sequencing of sequential stem sections from the same trees. Enzymes were selected on the basis of their importance in sugar metabolism and in linking primary metabolism to lignin biosynthesis. Existing enzyme assays were adapted to allow measurements from ~1 mm3 sections of dissected stem tissue. These experiments provided high spatial resolution of enzyme activity changes across different stages of wood development, and identified the gene transcripts probably responsible for these changes. In most cases, there was a clear positive relationship between transcripts and enzyme activity. During secondary cell wall formation, the increases in transcript levels and enzyme activities also matched with increased levels of glucose, fructose, hexose phosphates, and UDP-glucose, emphasizing an important role for transcriptional regulation in carbon allocation to developing aspen wood. These observations corroborate the efforts to increase carbon allocation to wood by engineering gene regulatory networks. © The Author 2017. Published by Oxford University Press on behalf of the Society for Experimental Biology.

  10. Spatially and Temporally Resolved Analysis of Environmental Trade-Offs in Electricity Generation.

    Science.gov (United States)

    Peer, Rebecca A M; Garrison, Jared B; Timms, Craig P; Sanders, Kelly T

    2016-04-19

    The US power sector is a leading contributor of emissions that affect air quality and climate. It also requires a lot of water for cooling thermoelectric power plants. Although these impacts affect ecosystems and human health unevenly in space and time, there has been very little quantification of these environmental trade-offs on decision-relevant scales. This work quantifies hourly water consumption, emissions (i.e., carbon dioxide, nitrogen oxides, and sulfur oxides), and marginal heat rates for 252 electricity generating units (EGUs) in the Electric Reliability Council of Texas (ERCOT) region in 2011 using a unit commitment and dispatch model (UC&D). Annual, seasonal, and daily variations, as well as spatial variability are assessed. When normalized over the grid, hourly average emissions and water consumption intensities (i.e., output per MWh) are found to be highest when electricity demand is the lowest, as baseload EGUs tend to be the most water and emissions intensive. Results suggest that a large fraction of emissions and water consumption are caused by a small number of power plants, mainly baseload coal-fired generators. Replacing 8-10 existing power plants with modern natural gas combined cycle units would result in reductions of 19-29%, 51-55%, 60-62%, and 13-27% in CO2 emissions, NOx emissions, SOx emissions, and water consumption, respectively, across the ERCOT region for two different conversion scenarios.

  11. Comparison of two spatially-resolved fossil fuel CO2 emissions inventories at the urban scale in four US cities

    Science.gov (United States)

    Liang, J.; Gurney, K. R.; O'Keeffe, D.; Patarasuk, R.; Hutchins, M.; Rao, P.

    2017-12-01

    Spatially-resolved fossil fuel CO2 (FFCO2) emissions are used not only in complex atmospheric modeling systems as prior scenarios to simulate concentrations of CO2 in the atmosphere, but to improve understanding of relationships with socioeconomic factors in support of sustainability policymaking. We present a comparison of ODIAC, a top-down global gridded FFCO2 emissions dataset, and Hesita, a bottom-up FFCO2 emissions dataset, in four US cities, including Los Angles, Indianapolis, Salt Lake City and Baltimore City. ODIAC was developed by downscaling national total emissions to 1km-by-1km grid cells using satellite nightlight imagery as proxy. Hesita was built from the ground up by allocating sector-specific county-level emissions to urban-level spatial surrogates including facility locations, road maps, building footprints/parcels, railroad maps and shipping lanes. The differences in methodology and data sources could lead to large discrepancies in FFCO2 estimates at the urban scale, and these discrepancies need to be taken into account in conducting atmospheric modeling or socioeconomic analysis. This comparison work is aimed at quantifying the statistical and spatial difference between the two FFCO2 inventories. An analysis of the difference in total emissions, spatial distribution and statistical distribution resulted in the following findings: (1) ODIAC agrees well with Hestia in total FFCO2 emissions estimates across the four cities with a difference from 3%-20%; (2) Small-scale areal and linear spatial features such as roads and buildings are either entirely missing or not very well represented in ODIAC, since nightlight imagery might not be able to capture these information. This might further lead to underestimated on-road FFCO2 emissions in ODIAC; (3) The statistical distribution of ODIAC is more concentrated around the mean with much less samples in the lower range. These phenomena could result from the nightlight halo and saturation effects; (4) The

  12. Spatially resolved flux measurements of NOx from London suggest significantly higher emissions than predicted by inventories.

    Science.gov (United States)

    Vaughan, Adam R; Lee, James D; Misztal, Pawel K; Metzger, Stefan; Shaw, Marvin D; Lewis, Alastair C; Purvis, Ruth M; Carslaw, David C; Goldstein, Allen H; Hewitt, C Nicholas; Davison, Brian; Beevers, Sean D; Karl, Thomas G

    2016-07-18

    To date, direct validation of city-wide emissions inventories for air pollutants has been difficult or impossible. However, recent technological innovations now allow direct measurement of pollutant fluxes from cities, for comparison with emissions inventories, which are themselves commonly used for prediction of current and future air quality and to help guide abatement strategies. Fluxes of NOx were measured using the eddy-covariance technique from an aircraft flying at low altitude over London. The highest fluxes were observed over central London, with lower fluxes measured in suburban areas. A footprint model was used to estimate the spatial area from which the measured emissions occurred. This allowed comparison of the flux measurements to the UK's National Atmospheric Emissions Inventory (NAEI) for NOx, with scaling factors used to account for the actual time of day, day of week and month of year of the measurement. The comparison suggests significant underestimation of NOx emissions in London by the NAEI, mainly due to its under-representation of real world road traffic emissions. A comparison was also carried out with an enhanced version of the inventory using real world driving emission factors and road measurement data taken from the London Atmospheric Emissions Inventory (LAEI). The measurement to inventory agreement was substantially improved using the enhanced version, showing the importance of fully accounting for road traffic, which is the dominant NOx emission source in London. In central London there was still an underestimation by the inventory of 30-40% compared with flux measurements, suggesting significant improvements are still required in the NOx emissions inventory.

  13. Complex EUV imaging reflectometry: spatially resolved 3D composition determination and dopant profiling with a tabletop 13nm source

    Science.gov (United States)

    Porter, Christina L.; Tanksalvala, Michael; Gerrity, Michael; Miley, Galen P.; Esashi, Yuka; Horiguchi, Naoto; Zhang, Xiaoshi; Bevis, Charles S.; Karl, Robert; Johnsen, Peter; Adams, Daniel E.; Kapteyn, Henry C.; Murnane, Margaret M.

    2018-03-01

    With increasingly 3D devices becoming the norm, there is a growing need in the semiconductor industry and in materials science for high spatial resolution, non-destructive metrology techniques capable of determining depth-dependent composition information on devices. We present a solution to this problem using ptychographic coherent diffractive imaging (CDI) implemented using a commercially available, tabletop 13 nm source. We present the design, simulations, and preliminary results from our new complex EUV imaging reflectometer, which uses coherent 13 nm light produced by tabletop high harmonic generation. This tool is capable of determining spatially-resolved composition vs. depth profiles for samples by recording ptychographic images at multiple incidence angles. By harnessing phase measurements, we can locally and nondestructively determine quantities such as device and thin film layer thicknesses, surface roughness, interface quality, and dopant concentration profiles. Using this advanced imaging reflectometer, we can quantitatively characterize materials-sciencerelevant and industry-relevant nanostructures for a wide variety of applications, spanning from defect and overlay metrology to the development and optimization of nano-enhanced thermoelectric or spintronic devices.

  14. Quantitative, depth-resolved determination of particle motion using multi-exposure, spatial frequency domain laser speckle imaging.

    Science.gov (United States)

    Rice, Tyler B; Kwan, Elliott; Hayakawa, Carole K; Durkin, Anthony J; Choi, Bernard; Tromberg, Bruce J

    2013-01-01

    Laser Speckle Imaging (LSI) is a simple, noninvasive technique for rapid imaging of particle motion in scattering media such as biological tissue. LSI is generally used to derive a qualitative index of relative blood flow due to unknown impact from several variables that affect speckle contrast. These variables may include optical absorption and scattering coefficients, multi-layer dynamics including static, non-ergodic regions, and systematic effects such as laser coherence length. In order to account for these effects and move toward quantitative, depth-resolved LSI, we have developed a method that combines Monte Carlo modeling, multi-exposure speckle imaging (MESI), spatial frequency domain imaging (SFDI), and careful instrument calibration. Monte Carlo models were used to generate total and layer-specific fractional momentum transfer distributions. This information was used to predict speckle contrast as a function of exposure time, spatial frequency, layer thickness, and layer dynamics. To verify with experimental data, controlled phantom experiments with characteristic tissue optical properties were performed using a structured light speckle imaging system. Three main geometries were explored: 1) diffusive dynamic layer beneath a static layer, 2) static layer beneath a diffuse dynamic layer, and 3) directed flow (tube) submerged in a dynamic scattering layer. Data fits were performed using the Monte Carlo model, which accurately reconstructed the type of particle flow (diffusive or directed) in each layer, the layer thickness, and absolute flow speeds to within 15% or better.

  15. Spatially Resolved Hard X-ray Emission in the Central 5 kpc of the Galaxy Merger NGC 6240

    Science.gov (United States)

    Wang, Junfeng; Nardini, E.; Fabbiano, G.; Karovska, M.; Elvis, M.; Pellegrini, S.; Max, C. E.; Risaliti, G.; U, V.; Zezas, A.

    2013-04-01

    We have obtained a deep, sub-arcsecond resolution X-ray image of the nuclear region of the luminous galaxy merger NGC 6240 with Chandra, which resolves the X-ray emission from the pair of active nuclei and the diffuse hot gas in great detail. We detect extended hard X-ray emission from 70 million K hot gas over a spatial scale of 5 kpc, indicating the presence of fast shocks with velocity of 2200 km/s. For the first time we obtain spatial distribution of this highly ionized gas emitting FeXXV and find that it shows a remarkable correspondence to the large scale morphology of H_2(1-0) S(1) line emission and Hα filaments. Propagation of fast shocks originated in the starburst driven wind into the ambient dense gas can account for this morphological correspondence. Both the energetics and the iron mass in the hot gas are consistent with the expected injection from the supernovae explosion during the starburst that is commensurate with its high star formation rate.

  16. SPATIALLY RESOLVED SPECTROSCOPY OF EUROPA’S LARGE-SCALE COMPOSITIONAL UNITS AT 3–4 μ m WITH KECK NIRSPEC

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, P. D.; Brown, M. E.; Trumbo, S. K. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Hand, K. P., E-mail: pfischer@caltech.edu [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2017-01-01

    We present spatially resolved spectroscopic observations of Europa’s surface at 3–4 μ m obtained with the near-infrared spectrograph and adaptive optics system on the Keck II telescope. These are the highest quality spatially resolved reflectance spectra of Europa’s surface at 3–4 μ m. The observations spatially resolve Europa’s large-scale compositional units at a resolution of several hundred kilometers. The spectra show distinct features and geographic variations associated with known compositional units; in particular, large-scale leading hemisphere chaos shows a characteristic longward shift in peak reflectance near 3.7 μ m compared to icy regions. These observations complement previous spectra of large-scale chaos, and can aid efforts to identify the endogenous non-ice species.

  17. Spatially Resolved Dust, Gas, and Star Formation in the Dwarf Magellanic Irregular NGC 4449

    Science.gov (United States)

    Calzetti, D.; Wilson, G. W.; Draine, B. T.; Roussel, H.; Johnson, K. E.; Heyer, M. H.; Wall, W. F.; Grasha, K.; Battisti, A.; Andrews, J. E.; Kirkpatrick, A.; Rosa González, D.; Vega, O.; Puschnig, J.; Yun, M.; Östlin, G.; Evans, A. S.; Tang, Y.; Lowenthal, J.; Sánchez-Arguelles, D.

    2018-01-01

    We investigate the relation between gas and star formation in subgalactic regions, ∼360 pc to ∼1.5 kpc in size, within the nearby starburst dwarf NGC 4449, in order to separate the underlying relation from the effects of sampling at varying spatial scales. Dust and gas mass surface densities are derived by combining new observations at 1.1 mm, obtained with the AzTEC instrument on the Large Millimeter Telescope, with archival infrared images in the range 8–500 μm from the Spitzer Space Telescope and the Herschel Space Observatory. We extend the dynamic range of our millimeter (and dust) maps at the faint end, using a correlation between the far-infrared/millimeter colors F(70)/F(1100) (and F(160)/F(1100)) and the mid-infrared color F(8)/F(24) that we establish for the first time for this and other galaxies. Supplementing our data with maps of the extinction-corrected star formation rate (SFR) surface density, we measure both the SFR–molecular gas and the SFR–total gas relations in NGC 4449. We find that the SFR–molecular gas relation is described by a power law with an exponent that decreases from ∼1.5 to ∼1.2 for increasing region size, while the exponent of the SFR–total gas relation remains constant with a value of ∼1.5 independent of region size. We attribute the molecular law behavior to the increasingly better sampling of the molecular cloud mass function at larger region sizes; conversely, the total gas law behavior likely results from the balance between the atomic and molecular gas phases achieved in regions of active star formation. Our results indicate a nonlinear relation between SFR and gas surface density in NGC 4449, similar to what is observed for galaxy samples. Based on observations obtained with the Large Millimeter Telescope Alfonso Serrano—a binational collaboration between INAOE (Mexico) and the University of Massachusetts–Amherst (USA).

  18. Development and application of methods and models for the calculation of spatially and temporally highly resolved emissions in Europe

    International Nuclear Information System (INIS)

    Thiruchittampalam, Balendra

    2014-01-01

    High spatial and temporal resolution models are essential for answering many questions of air quality management and climate modeling. High-resolution emission models are required to determine the concentration of pollutants using chemical transport models, and to quantify the impacts on health and environment and in particular to develop adequate countermeasures. The aim of this work is to develop methods for the calculation of spatially and temporally high-resolved emissions and to apply these exemplarily on a 1 km x 1 km and hourly resolution for the year 2008 in the EU-27 and EFTA countries. The derivation of methods for the spatial and temporal resolution of emissions with corresponding detailed equations is one of the major improvements that have been carried out in the course of this work. The improvement of the spatial distribution of emissions from the point source relevant sectors like energy supply, industry and waste management is achieved by considering sector specific diffuse emission shares. The progress of the spatial distribution of emissions from households is in particular the development of a fuel type weighted distribution over Europe. Another main focus is the development of the spatial distribution of road transport emissions. Due to the restricted access to traffic count data at the European level, methods have been established to provide reliable emissions on grid level for Europe. The progress in the spatial distribution of agricultural emissions is achieved by the consideration of diffuse shares similar to the other point source relevant sectors like energy supply or industry. In addition to the spatial distribution of the emissions the temporal resolution is a main focus of this work, since the state of knowledge of the temporal resolution of emissions in Europe is still rudimentary. Therefore, it was necessary to develop in particular time curves for the hourly resolution of emissions for the main sectors, namely electricity and heat

  19. Ultrafast Time-Resolved Photoluminescence Studies of Gallium-Arsenide

    Science.gov (United States)

    Johnson, Matthew Bruce

    This thesis concerns the study of ultrafast phenomena in GaAs using time-resolved photoluminescence (PL). The thesis consists of five chapters. Chapter one is an introduction, which discusses the study of ultrafast phenomena in semiconductors. Chapter two is a description of the colliding-pulse mode-locked (CPM) ring dye laser, which is at the heart of the experimental apparatus used in this thesis. Chapter three presents a detailed experimental and theoretical investigation of photoluminescence excitation correlation spectroscopy (PECS), the novel technique which is used to time-resolve ultrafast PL phenomena. Chapters 4 and 5 discuss two applications of the PECS technique. In Chapter 4 the variation of PL intensity in In-alloyed GaAs substrate material is studied, while Chapter 5 discusses the variation of carrier lifetimes in ion-damaged GaAs used in photo-conductive circuit elements (PCEs). PECS is a pulse-probe technique that measures the cross correlation of photo-excited carrier populations. The theoretical model employed in this thesis is based upon the rate equation for a simple three-level system consisting of valence and conduction bands and a single trap level. In the limit of radiative band-to-band dominated recombination, no PECS signal should be observed; while in the capture -dominated recombination limit, the PECS signal from the band-to-band PL measures the cross correlation of the excited electron and hole populations and thus, the electron and hole lifetimes. PECS is experimentally investigated using a case study of PL in semi-insulating (SI) GaAs and In -alloyed GaAs. At 77 K, the PECS signal is characteristic of a capture-dominated system, yielding an electron-hole lifetime of about 200 ps. However, at 5 K the behavior is more complicated and shows saturation effects due to the C acceptor level, which is un-ionized at 5 K. As a first application, PECS is used to investigate the large band-to-band PL contrast observed near dislocations in In

  20. An in situ spatially resolved analytical technique to simultaneously probe gas phase reactions and temperature within the packed bed of a plug flow reactor.

    Science.gov (United States)

    Touitou, Jamal; Burch, Robbie; Hardacre, Christopher; McManus, Colin; Morgan, Kevin; Sá, Jacinto; Goguet, Alexandre

    2013-05-21

    This paper reports the detailed description and validation of a fully automated, computer controlled analytical method to spatially probe the gas composition and thermal characteristics in packed bed systems. As an exemplar, we have examined a heterogeneously catalysed gas phase reaction within the bed of a powdered oxide supported metal catalyst. The design of the gas sampling and the temperature recording systems are disclosed. A stationary capillary with holes drilled in its wall and a moveable reactor coupled with a mass spectrometer are used to enable sampling and analysis. This method has been designed to limit the invasiveness of the probe on the reactor by using the smallest combination of thermocouple and capillary which can be employed practically. An 80 μm (O.D.) thermocouple has been inserted in a 250 μm (O.D.) capillary. The thermocouple is aligned with the sampling holes to enable both the gas composition and temperature profiles to be simultaneously measured at equivalent spatially resolved positions. This analysis technique has been validated by studying CO oxidation over a 1% Pt/Al2O3 catalyst and the spatial resolution profiles of chemical species concentrations and temperature as a function of the axial position within the catalyst bed are reported.

  1. Retinal Ganglion Cell Distribution and Spatial Resolving Power in Deep-Sea Lanternfishes (Myctophidae)

    KAUST Repository

    De Busserolles, Fanny; Marshall, N. Justin; Collin, Shaun P.

    2014-01-01

    Topographic analyses of retinal ganglion cell density are very useful in providing information about the visual ecology of a species by identifying areas of acute vision within the visual field (i.e. areas of high cell density). In this study, we

  2. Spectral and time-resolved studies on ocular structures

    Science.gov (United States)

    Schweitzer, D.; Jentsch, S.; Schenke, S.; Hammer, M.; Biskup, C.; Gaillard, E.

    2007-07-01

    Measurements of endogeous fluorophores open the possibility for evaluation of metabolic state at the eye. For interpretation of 2-dimensional measurements of time-resolved auto fluorescence in 2 separate spectral ranges at the human eye, comparing measurements were performed on porcine eyes. Determining excitation and emission spectra, attention was drawn of proof of coenzymes NADH and FAD in isolated anatomical structures cornea, aqueous humor, lens, vitreous, neuronal retina, retinal pigment epithelium (RPE), choroid, and sclera. All these structures exhibit auto fluorescence, highest in lens. Excitation at 350 nm results in local fluorescence maxima at 460 nm, corresponding to NADH, in all structures. This short-wave excitation allows metabolic studies only at the anterior eye, because of the limited transmission of the ocular media. During excitation at 446 nm the existence of FAD is expressed by local fluorescence maxima at 530 nm. The composition fluorescence spectra allow no discrimination between single ocular structures. Approximating the dynamic fluorescence by a double exponential function, the shortest lifetimes were detected in RPE and neuronal retina. The histograms of mean lifetime t M cover each other on lens with cornea and also on sclera with choroid. Despite the lifetimes are close between RPE and neuronal retina, the relative contributions Q I are wide different. The gradient of trend lines in cluster diagrams of amplitudes α II vs. α I allows a discrimination of ocular structures.

  3. Spatially resolved analysis of short-range structure perturbations in a plastically bent molecular crystal

    Science.gov (United States)

    Panda, Manas K.; Ghosh, Soumyajit; Yasuda, Nobuhiro; Moriwaki, Taro; Mukherjee, Goutam Dev; Reddy, C. Malla; Naumov, Panče

    2015-01-01

    The exceptional mechanical flexibility observed with certain organic crystals defies the common perception of single crystals as brittle objects. Here, we describe the morphostructural consequences of plastic deformation in crystals of hexachlorobenzene that can be bent mechanically at multiple locations to 360° with retention of macroscopic integrity. This extraordinary plasticity proceeds by segregation of the bent section into flexible layers that slide on top of each other, thereby generating domains with slightly different lattice orientations. Microscopic, spectroscopic and diffraction analyses of the bent crystal showed that the preservation of crystal integrity when stress is applied on the (001) face requires sliding of layers by breaking and re-formation of halogen-halogen interactions. Application of stress on the (100) face, in the direction where π···π interactions dominate the packing, leads to immediate crystal disintegration. Within a broader perspective, this study highlights the yet unrecognized extraordinary malleability of molecular crystals with strongly anisotropic supramolecular interactions.

  4. Proximity Effect between Two Superconductors Spatially Resolved by Scanning Tunneling Spectroscopy

    Directory of Open Access Journals (Sweden)

    V. Cherkez

    2014-03-01

    Full Text Available We present a combined experimental and theoretical study of the proximity effect in an atomic-scale controlled junction between two different superconductors. Elaborated on a Si(111 surface, the junction comprises a Pb nanocrystal with an energy gap Δ_{1}=1.2  meV, connected to a crystalline atomic monolayer of lead with Δ_{2}=0.23  meV. Using in situ scanning tunneling spectroscopy, we probe the local density of states of this hybrid system both in space and in energy, at temperatures below and above the critical temperature of the superconducting monolayer. Direct and inverse proximity effects are revealed with high resolution. Our observations are precisely explained with the help of a self-consistent solution of the Usadel equations. In particular, our results demonstrate that in the vicinity of the Pb islands, the Pb monolayer locally develops a finite proximity-induced superconducting order parameter, well above its own bulk critical temperature. This leads to a giant proximity effect where the superconducting correlations penetrate inside the monolayer a distance much larger than in a nonsuperconducting metal.

  5. Spatially resolved determination of lattice distortions in silicon nanostructures by means of electron-backscattering diffraction

    International Nuclear Information System (INIS)

    Krause, Michael

    2013-01-01

    In the submitted thesis, a novel combined approach of both focused ion beam (FIB) based target preparation and strain determination using electron backscatter diffraction (EBSD) in semiconductor nanostructures is presented. In the first part, a powerful cross-correlation algorithm for detecting small feature shifts within EBSD patterns and, consequently, determining the strain, is presented. The corresponding strain sensitivity is demonstrated using dynamically simulated diffraction patterns. Furthermore, novel procedures for automated pattern analysis are introduced. Results of systematic studies concerning the influence of ion species, ion energy and dose density on the surface quality of silicon surfaces are presented in the second part. For that matter, the assessment of surface amorphization and rippling is based on high resolution microstructural diagnostics (TEM, AFM, Raman) and molecular dynamics simulation. The high application potential of combined FIB preparation and strain analysis using EBSD is exemplarily demonstrated for a 60 nm thick sSOI-sample. The good agreement with established techniques like Raman spectroscopy and X-ray diffraction is also shown.

  6. Coupling of oceanic carbon and nitrogen: A window to spatially resolved quantitative reconstruction of nitrate inventories

    Science.gov (United States)

    Glock, N.; Liebetrau, V.; Gorb, S.; Wallmann, K. J. G.; Erdem, Z.; Schönfeld, J.; Eisenhauer, A.

    2017-12-01

    Anthropogenic impact has led to a severe acceleration of the global nitrogen cycle. Every second nitrogen atom in the biosphere may now originate from anthropogenic sources such as chemical fertilizers and the burning of fossil fuels. A quantitative reconstruction of past reactive nitrogen inventories is invaluable to facilitate projections for future scenarios and calibrations for such paleoproxies should be done as long the natural signature is still visible. Here we present a first quantitative reconstruction of nitrate concentrations in intermediate water depths of the Peruvian oxygen minimum zone over the last deglaciation using the pore density in the benthic foraminiferal species Bolivina spissa. A comparison of the nitrate reconstruction to the stable carbon isotope (δ13C) record reveals a strong coupling between the carbon and nitrogen cycles. The linear correlation between δ13C and nitrate availability remained stable over the last 22,000 years, facilitating the use of δ13C records as a quantitative nitrate proxy. The combination of the pore density record with δ13C records shows an elevated oceanic nitrate inventory during the Last Glacial Maximum as compared to the Holocene. Our novel proxy approach is consistent with the results of previous δ15N-based biogeochemical modeling studies, and thus provides sound estimates of the nitrate inventory in the glacial and deglacial ocean.

  7. SDSS-IV MaNGA: The Spatially Resolved Stellar Initial Mass Function in ˜400 Early-Type Galaxies

    Science.gov (United States)

    Parikh, Taniya; Thomas, Daniel; Maraston, Claudia; Westfall, Kyle B.; Goddard, Daniel; Lian, Jianhui; Meneses-Goytia, Sofia; Jones, Amy; Vaughan, Sam; Andrews, Brett H.; Bershady, Matthew; Bizyaev, Dmitry; Brinkmann, Jonathan; Brownstein, Joel R.; Bundy, Kevin; Drory, Niv; Emsellem, Eric; Law, David R.; Newman, Jeffrey A.; Roman-Lopes, Alexandre; Wake, David; Yan, Renbin; Zheng, Zheng

    2018-03-01

    MaNGA provides the opportunity to make precise spatially resolved measurements of the IMF slope in galaxies owing to its unique combination of spatial resolution, wavelength coverage and sample size. We derive radial gradients in age, element abundances and IMF slope analysing optical and near-infrared absorption features from stacked spectra out to the half-light radius of 366 early-type galaxies with masses 9.9 - 10.8 log M/M⊙. We find flat gradients in age and [α/Fe] ratio, as well as negative gradients in metallicity, consistent with the literature. We further derive significant negative gradients in the [Na/Fe] ratio with galaxy centres being well enhanced in Na abundance by up to 0.5 dex. Finally, we find a gradient in IMF slope with a bottom-heavy IMF in the centre (typical mass excess factor of 1.5) and a Milky Way-type IMF at the half-light radius. This pattern is mass-dependent with the lowest mass galaxies in our sample featuring only a shallow gradient around a Milky Way IMF. Our results imply the local IMF-σ relation within galaxies to be even steeper than the global relation and hint towards the local metallicity being the dominating factor behind the IMF variations. We also employ different stellar population models in our analysis and show that a radial IMF gradient is found independently of the stellar population model used. A similar analysis of the Wing-Ford band provides inconsistent results and further evidence of the difficulty in measuring and modelling this particular feature.

  8. Multidecadal persistence of organic matter in soils: insights from spatially resolved investigations at the submicrometer scale

    Science.gov (United States)

    Lutfalla, Suzanne; Barré, Pierre; Bernard, Sylvain; Le Guillou, Corentin; Alléon, Julien; Chenu, Claire

    2016-04-01

    . Altogether, the present study suggests that smectite have more efficient protection capabilities than those of illite and kaolinite.

  9. Angle-resolved photoemission spectroscopy (ARPES) studies of cuprate superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Palczewski, Ari Deibert [Iowa State Univ., Ames, IA (United States)

    2010-01-01

    This dissertation is comprised of three different angle-resolved photoemission spectroscopy (ARPES) studies on cuprate superconductors. The first study compares the band structure from two different single layer cuprates Tl2Ba2CuO6+δ (Tl2201) Tc, max ≈ 95 K and (Bi 1.35Pb0.85)(Sr1.47La0.38)CuO6+δ (Bi2201) Tc, max ≈ 35 K. The aim of the study was to provide some insight into the reasons why single layer cuprate's maximum transition temperatures are so different. The study found two major differences in the band structure. First, the Fermi surface segments close to (π,0) are more parallel in Tl2201 than in Bi2201. Second, the shadow band usually related to crystal structure is only present in Bi2201, but absent in higher Tc Tl2201. The second study looks at the different ways of doping Bi2Sr2CaCu2O8+δ (Bi2212) in-situ by only changing the post bake-out vacuum conditions and temperature. The aim of the study is to systematically look into the generally overlooked experimental conditions that change the doping of a cleaved sample in ultra high vacuum (UHV) experiments. The study found two major experimental facts. First, in inadequate UHV conditions the carrier concentration of Bi2212 increases with time, due to the absorption of oxygen from CO2/CO molecules, prime contaminants present in UHV systems. Second, in a very clean UHV system at elevated temperatures (above about 200 K), the carrier concentration decreases due to the loss of oxygen atoms from the Bi-O layer. The final study probed the particle-hole symmetry of the pseudogap phase in high temperature superconducting cuprates by looking at the thermally excited bands above the Fermi level. The data showed a particle-hole symmetric pseudogap which symmetrically closes away from the nested FS before the node. The data is

  10. Angle-resolved photoemission spectroscopy (ARPES) studies of cuprate superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Palczewski, Ari Deibert [Iowa State Univ., Ames, IA (United States)

    2010-01-01

    This dissertation is comprised of three different angle-resolved photoemission spectroscopy (ARPES) studies on cuprate superconductors. The first study compares the band structure from two different single layer cuprates Tl2Ba2CuO6+δ (Tl2201) Tc,max ~95 K and (Bi1.35Pb0.85)(Sr1.47La0.38)CuO6+δ (Bi2201) Tc,max 35 K. The aim of the study was to provide some insight into the reasons why single layer cuprate's maximum transition temperatures are so different. The study found two major di erences in the band structure. First, the Fermi surface segments close to ( π,0) are more parallel in Tl2201 than in Bi2201. Second, the shadow band usually related to crystal structure is only present in Bi2201, but absent in higher Tc Tl2201. The second study looks at the different ways of doping Bi2Sr2CaCu2O8+δ (Bi2212) in-situ by only changing the post bake-out vacuum conditions and temperature. The aim of the study is to systematically look into the generally overlooked experimental conditions that change the doping of a cleaved sample in ultra high vacuum (UHV) experiments. The study found two major experimental facts. First, in inadequate UHV conditions the carrier concentration of Bi2212 increases with time, due to the absorption of oxygen from CO2/CO molecules, prime contaminants present in UHV systems. Second, in a very clean UHV system at elevated temperatures (above about 200 K), the carrier concentration decreases due to the loss of oxygen atoms from the Bi-O layer. The final study probed the particle-hole symmetry of the pseudogap phase in high temperature superconducting cuprates by looking at the thermally excited bands above the Fermi level. The data showed a particle-hole symmetric pseudogap which symmetrically closes away from the nested FS before the node. The data is consistent with

  11. Two-Photon Irradiation of an Intracellular Singlet Oxygen Photosensitizer: Achieving Localized Sub-Cellular Excitation in Spatially-Resolved Experiments

    DEFF Research Database (Denmark)

    Pedersen, Brian Wett; Breitenbach, Thomas; Redmond, Robert W.

    2010-01-01

    The response of a given cell to spatially-resolved sub-cellular irradiation of a singlet oxygen photosensitizer (protoporphyrin IX, PpIX) using a focused laser was assessed. In these experiments, incident light was scattered over a volume greater than that defi ned by the dimensions of the laser...

  12. Development of a Schottky CdTe Medipix3RX hybrid photon counting detector with spatial and energy resolving capabilities

    Energy Technology Data Exchange (ETDEWEB)

    Gimenez, E.N., E-mail: Eva.Gimenez@diamond.ac.uk [Diamond Light Source, Harwell Campus, Oxforshire OX11 0DE (United Kingdom); Astromskas, V. [University of Surrey (United Kingdom); Horswell, I.; Omar, D.; Spiers, J.; Tartoni, N. [Diamond Light Source, Harwell Campus, Oxforshire OX11 0DE (United Kingdom)

    2016-07-11

    A multichip CdTe-Medipix3RX detector system was developed in order to bring the advantages of photon-counting detectors to applications in the hard X-ray range of energies. The detector head consisted of 2×2 Medipix3RX ASICs bump-bonded to a 28 mm×28 mm e{sup −} collection Schottky contact CdTe sensor. Schottky CdTe sensors undergo performance degrading polarization which increases with temperature, flux and the longer the HV is applied. Keeping the temperature stable and periodically refreshing the high voltage bias supply was used to minimize the polarization and achieve a stable and reproducible detector response. This leads to good quality images and successful results on the energy resolving capabilities of the system. - Highlights: • A high atomic number (CdTe sensor based) photon-counting detector was developed. • Polarization effects affected the image were minimized by regularly refreshing the bias voltage and stabilizing the temperature. • Good spatial resolution and image quality was achieved following this procedure.

  13. The spatially resolved characterisation of Egyptian blue, Han blue and Han purple by photo-induced luminescence digital imaging.

    Science.gov (United States)

    Verri, G

    2009-06-01

    The photo-induced luminescence properties of Egyptian blue, Han blue and Han purple were investigated by means of near-infrared digital imaging. These pigments emit infrared radiation when excited in the visible range. The emission can be recorded by means of a modified commercial digital camera equipped with suitable glass filters. A variety of visible light sources were investigated to test their ability to excite luminescence in the pigments. Light-emitting diodes, which do not emit stray infrared radiation, proved an excellent source for the excitation of luminescence in all three compounds. In general, the use of visible radiation emitters with low emission in the infrared range allowed the presence of the pigments to be determined and their distribution to be spatially resolved. This qualitative imaging technique can be easily applied in situ for a rapid characterisation of materials. The results were compared to those for Egyptian green and for historical and modern blue pigments. Examples of the application of the technique on polychrome works of art are presented.

  14. Discovery of Low-ionization Envelopes in the Planetary Nebula NGC 5189: Spatially-resolved Diagnostics from HST Observations

    Science.gov (United States)

    Danehkar, Ashkbiz; Karovska, Margarita; Maksym, Walter Peter; Montez, Rodolfo

    2018-01-01

    The planetary nebula NGC 5189 shows one of the most spectacular morphological structures among planetary nebulae with [WR]-type central stars. Using high-angular resolution HST/WFC3 imaging, we discovered inner, low-ionization structures within a region of 0.3 parsec × 0.2 parsec around the central binary system. We used Hα, [O III], and [S II] emission line images to construct line-ratio diagnostic maps, which allowed us to spatially resolve two distinct low-ionization envelopes within the inner, ionized gaseous environment, extending over a distance of 0.15 pc from the central binary. Both the low-ionization envelopes appear to be expanding along a NE to SW symmetric axis. The SW envelope appears smaller than its NE counterpart. Our diagnostic maps show that highly-ionized gas surrounds these low-ionization envelopes, which also include filamentary and clumpy structures. These envelopes could be a result of a powerful outburst from the central interacting binary, when one of the companions (now a [WR] star) was in its AGB evolutionary stage, with a strong mass-loss generating dense circumstellar shells. Dense material ejected from the progenitor AGB star is likely heated up as it propagates along a symmetric axis into the previously expelled low-density material. Our new diagnostic methodology is a powerful tool for high-angular resolution mapping of low-ionization structures in other planetary nebulae with complex structures possibly caused by past outbursts from their progenitors.

  15. Development of Micron-Resolved Electron Spectroscopy to Study Organic Thin Films in Real Devices

    International Nuclear Information System (INIS)

    Wang, C.-H.; Fan, L.-J.; Yang, Y.-W.; Su, J.-W.; Chan, S.-W.; Chen, M.-C.

    2010-01-01

    A straightforward application of an electron energy analyzer equipped with an image detector to micron-resolved electron spectroscopic studies of organic thin film devices is reported. The electron spectroscopies implemented include synchrotron-based UPS, XPS, and Auger yield NEXAFS. Along the non-energy-dispersion direction of the analyzer, a spatial resolution of ∼40 μm is obtained through the employment of entrance slits, electrostatic lenses and segmented CCD detector. One significant benefit offered by the technique is that the electronic transport and electronic structure of the same micron-sized sample can be directly examined. The example illustrated is a top-contact organic field effect transistor (OFET) fabricated from semiconducting triethylsilylethynyl anthradithiophene and gold electrodes. It is found that an extensive out-diffusion of gold atoms to adjacent conduction channels takes place, presumably due to the inability of soft organic materials in dissipating the excess energy with which gaseous Au atoms possess.

  16. Policy applications of a highly resolved spatial and temporal onroad carbon dioxide emissions data product for the U.S.: Analyses and their implications for mitigation

    Science.gov (United States)

    Mendoza Lebrun, Daniel

    Onroad CO2 emissions were analyzed as part of overall GHG emissions, but those studies have suffered from one or more of these five shortcomings: 1) the spatial resolution was coarse, usually encompassing a region, or the entire U.S.; 2) the temporal resolution was coarse (annual or monthly); 3) the study region was limited, usually a metropolitan planning organization (MPO) or state; 4) fuel sales were used as a proxy to quantify fuel consumption instead of focusing on travel; 5) the spatial heterogeneity of fleet and road network composition was not considered and instead national averages are used. Normalized vehicle-type state-level spatial biases range from 2.6% to 8.1%, while the road type classification biases range from -6.3% to 16.8%. These biases are found to cause errors in reduction estimates as large as ±60%, corresponding to ±0.2 MtC, for a national-average emissions mitigation strategy focused on a 10% emissions reduction from a single vehicle class. Temporal analysis shows distinct emissions seasonality that is particularly visible in the northernmost latitudes, demonstrating peak-to-peak deviations from the annual mean of up to 50%. The hourly structure shows peak-to-peak deviation from a weekly average of up to 200% for heavy-duty (HD) vehicles and 140% for light-duty (LD) vehicles. The present study focuses on reduction of travel and fuel economy improvements by putting forth several mitigation scenarios aimed at reducing VMT and increasing vehicle fuel efficiency. It was found that the most effective independent reduction strategies are those that increase fuel efficiency by extending standards proposed by the corporate average fuel economy (CAFE) or reduction of fuel consumption due to price increases. These two strategies show cumulative emissions reductions of approximately 11% and 12%, respectively, from a business as usual (BAU) approach over the 2000-2050 period. The U.S. onroad transportation sector is long overdue a comprehensive study

  17. Spatially Resolved Carbon Isotope and Elemental Analyses of the Root-Rhizosphere-Soil System to Understand Below-ground Nutrient Interactions

    Science.gov (United States)

    Denis, E. H.; Ilhardt, P.; Tucker, A. E.; Huggett, N. L.; Rosnow, J. J.; Krogstad, E. J.; Moran, J.

    2017-12-01

    The intimate relationships between plant roots, rhizosphere, and soil are fostered by the release of organic compounds from the plant (through various forms of rhizodeposition) into soil and the simultaneous harvesting and delivery of inorganic nutrients from the soil to the plant. This project's main goal is to better understand the spatial controls on bi-directional nutrient exchange through the rhizosphere and how they impact overall plant health and productivity. Here, we present methods being developed to 1) spatially track the release and migration of plant-derived organics into the rhizosphere and soil and 2) map the local inorganic geochemical microenvironments within and surrounding the rhizosphere. Our studies focused on switchgrass microcosms containing soil from field plots at the Kellogg Biological Station (Hickory Corners, Michigan), which have been cropped with switchgrass for nearly a decade. We used a 13CO2 tracer to label our samples for both one and two diel cycles and tracked subsequent movement of labeled organic carbon using spatially specific δ13C analysis (with 50 µm resolution). The laser ablation-isotope ratio mass spectrometry (LA-IRMS) approach allowed us to map the extent of 13C-label migration into roots, rhizosphere, and surrounding soil. Preliminary results show the expected decrease of organic exudates with distance from a root and that finer roots (<0.1 mm) incorporated more 13C-label than thicker roots, which likely correlates to specific root growth rates. We are adapting both laser induced breakdown spectroscopy (LIBS) and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to spatially map inorganic nutrient content in the exact same samples used for LA-IRMS analysis. Both of these methods provide rapid surface mapping of a wide range of elements (with high dynamic range) at 150 μm spatial resolution. Preliminary results show that, based on elemental content, we can distinguish between roots, rhizosphere

  18. Spatially-resolved in-situ quantification of biofouling using optical coherence tomography (OCT) and 3D image analysis in a spacer filled channel

    KAUST Repository

    Fortunato, Luca

    2016-11-21

    The use of optical coherence tomography (OCT) to investigate biomass in membrane systems has increased with time. OCT is able to characterize the biomass in-situ and non-destructively. In this study, a novel approach to process three-dimensional (3D) OCT scans is proposed. The approach allows obtaining spatially-resolved detailed structural biomass information. The 3D biomass reconstruction enables analysis of the biomass only, obtained by subtracting the time zero scan to all images. A 3D time series analysis of biomass development in a spacer filled channel under representative conditions (cross flow velocity) for a spiral wound membrane element was performed. The flow cell was operated for five days with monitoring of ultrafiltration membrane performance: feed channel pressure drop and permeate flux. The biomass development in the flow cell was detected by OCT before a performance decline was observed. Feed channel pressure drop continuously increased with increasing biomass volume, while flux decline was mainly affected in the initial phase of biomass accumulation. The novel OCT imaging approach enabled the assessment of spatial biomass distribution in the flow cell, discriminating the total biomass volume between the membrane, feed spacer and glass window. Biomass accumulation was stronger on the feed spacer during the early stage of biofouling, impacting the feed channel pressure drop stronger than permeate flux.

  19. Investigations of vertical chemical gradients in Cu(In,Ga)S{sub 2}-thin films prepared by sulfurization of sputtered precursor layers using highly spatially resolved cathodoluminescence microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ribbe, Stefan; Mueller, Mathias; Bertram, Frank; Hempel, Thomas; Christen, Juergen [Institute for Experimental Physics, Otto-von-Guericke-University Magdeburg (Germany); Rodriguez-Alvarez, Humberto; Lauche, Jakob; Schock, Hans-Werner [Helmholtz Center Berlin for Materials and Energy (Germany)

    2012-07-01

    The luminescence properties of Cu(In,Ga)S{sub 2}(CIGS)-absorber layers for thin film solar cells have been studied by highly spatially resolved cathodoluminescence (CL) at low temperature (T=5 K). In/Cu-Ga-precursors were annealed with elementary sulfur pellets in a rapid thermal process at different annealing times to represent different growth steps of the CIGS absorber layer. Spatially integral CL spectra show a dominant peak at 825 nm accompanied by a low-energy shoulder at 890 nm. Only a slight blue shift of the main peak is observed by variation of the excitation density. Investigations of cross-sections show for all samples a similar luminescence distribution. Near the molybdenum back contact distinct areas show luminescence emitting at 680-750 nm. In contrast, in upper regions of the layer a homogeneous low-energy luminescence at around 820 nm is observed which exhibits the most intensive spots on the cross-section. In local spectra we observe a change of the dominant recombination channel at the interface of these two regions.

  20. Microscopic View of Defect Evolution in Thermal Treated AlGaInAs Quantum Well Revealed by Spatially Resolved Cathodoluminescence

    Directory of Open Access Journals (Sweden)

    Yue Song

    2018-06-01

    Full Text Available An aluminum gallium indium arsenic (AlGaInAs material system is indispensable as the active layer of diode lasers emitting at 1310 or 1550 nm, which are used in optical fiber communications. However, the course of the high-temperature instability of a quantum well structure, which is closely related to the diffusion of indium atoms, is still not clear due to the system’s complexity. The diffusion process of indium atoms was simulated by thermal treatment, and the changes in the optical and structural properties of an AlGaInAs quantum well are investigated in this paper. Compressive strained Al0.07Ga0.22In0.71As quantum wells were treated at 170 °C with different heat durations. A significant decrement of photoluminescence decay time was observed on the quantum well of a sample that was annealed after 4 h. The microscopic cathodoluminescent (CL spectra of these quantum wells were measured by scanning electron microscope-cathodoluminescence (SEM-CL. The thermal treatment effect on quantum wells was characterized via CL emission peak wavelength and energy density distribution, which were obtained by spatially resolved cathodoluminescence. The defect area was clearly observed in the Al0.07Ga0.22In0.71As quantum wells layer after thermal treatment. CL emissions from the defect core have higher emission energy than those from the defect-free regions. The defect core distribution, which was associated with indium segregation gradient distribution, showed asymmetric character.

  1. Highly spatially resolved structural and optical investigation of Bi nanoparticles in Y-Er disilicate thin films

    Energy Technology Data Exchange (ETDEWEB)

    Scarangella, A. [CNR IMM-MATIS, Via S. Sofia 64, 95123 Catania (Italy); Dipartimento di Fisica e Astronomia, Università di Catania, Via S. Sofia 64, 95123 Catania (Italy); Amiard, G.; Boninelli, S., E-mail: simona.boninelli@ct.infn.it; Miritello, M. [CNR IMM-MATIS, Via S. Sofia 64, 95123 Catania (Italy); Reitano, R. [Dipartimento di Fisica e Astronomia, Università di Catania, Via S. Sofia 64, 95123 Catania (Italy); Priolo, F. [CNR IMM-MATIS, Via S. Sofia 64, 95123 Catania (Italy); Dipartimento di Fisica e Astronomia, Università di Catania, Via S. Sofia 64, 95123 Catania (Italy); Scuola Superiore di Catania, Università di Catania, Via Valdisavoia 9, 95123 Catania (Italy)

    2016-08-08

    Er-containing silicon compatible materials have been widely used as infrared emitters for microphotonics application. In this field, the additional introduction of a proper sensitizer permits to increase the Er excitation cross sections, thus increasing its optical efficiency. This work aims to investigate the influence of a post-transition metal, bismuth, on the optical properties of erbium-yttrium disilicate thin films synthesized by magnetron co-sputtering. After thermal treatments at 1000 °C in O{sub 2} or N{sub 2} environment, the presence of small precipitates, about 6 nm in diameter, was evidenced by transmission electron microscopy analyses. The spatially resolved chemical nature of the nanoparticles was discerned in the Si and O rich environments by means of scanning transmission electron microscopy–energy dispersive X-ray and scanning transmission electron microscopy–electron energy loss spectroscopy analyses performed with nanometric resolution. In particular, metallic Bi nanoparticles were stabilized in the N{sub 2} environment, being strongly detrimental for the Er emission. A different scenario was instead observed in O{sub 2}, where the formation of Bi silicate nanoparticles was demonstrated with the support of photoluminescence excitation spectroscopy. In particular, a broad band peaked at 255 nm, correlated to the excitation band of Bi silicate nanoparticles, was identified in Er excitation spectrum. Thus Bi silicate clusters act as sensitizer for Er ions, permitting to improve Er emission up to 250 times with respect to the resonant condition. Moreover, the Er decay time increases in the presence of the Bi silicate nanoparticles that act as cages for Er ions. These last results permit to further increase Er optical efficiency in the infrared range, suggesting (Bi + Er)-Y disilicate as a good candidate for applications in microphotonics.

  2. Studying the potential of point detectors in time-resolved dose verification of dynamic radiotherapy

    International Nuclear Information System (INIS)

    Beierholm, A.R.; Behrens, C.F.; Andersen, C.E.

    2015-01-01

    Modern megavoltage x-ray radiotherapy with high spatial and temporal dose gradients puts high demands on the entire delivery system, including not just the linear accelerator and the multi-leaf collimator, but also algorithms used for optimization and dose calculations, and detectors used for quality assurance and dose verification. In this context, traceable in-phantom dosimetry using a well-characterized point detector is often an important supplement to 2D-based quality assurance methods based on radiochromic film or detector arrays. In this study, an in-house developed dosimetry system based on fiber-coupled plastic scintillator detectors was evaluated and compared with a Farmer-type ionization chamber and a small-volume ionization chamber. An important feature of scintillator detectors is that the sensitive volume of the detector can easily be scaled, and five scintillator detectors of different scintillator length were thus employed to quantify volume averaging effects by direct measurement. The dosimetric evaluation comprised several complex-shape static fields as well as simplified dynamic deliveries using RapidArc, a volumetric-modulated arc therapy modality often used at the participating clinic. The static field experiments showed that the smallest scintillator detectors were in the best agreement with dose calculations, while needing the smallest volume averaging corrections. Concerning total dose measured during RapidArc, all detectors agreed with dose calculations within 1.1 ± 0.7% when positioned in regions of high homogenous dose. Larger differences were observed for high dose gradient and organ at risk locations, were differences between measured and calculated dose were as large as 8.0 ± 5.5%. The smallest differences were generally seen for the small-volume ionization chamber and the smallest scintillators. The time-resolved RapidArc dose profiles revealed volume-dependent discrepancies between scintillator and ionization chamber response

  3. A novel multiplex absorption spectrometer for time-resolved studies

    Science.gov (United States)

    Lewis, Thomas; Heard, Dwayne E.; Blitz, Mark A.

    2018-02-01

    A Time-Resolved Ultraviolet/Visible (UV/Vis) Absorption Spectrometer (TRUVAS) has been developed that can simultaneously monitor absorption at all wavelengths between 200 and 800 nm with millisecond time resolution. A pulsed photolysis laser (KrF 248 nm) is used to initiate chemical reactions that create the target species. The absorption signals from these species evolve as the composition of the gas in the photolysis region changes over time. The instrument can operate at pressures over the range ˜10-800 Torr and can measure time-resolved absorbances systems (in particular the Herriott cell), there are fundamental differences, most notably the ability to adjust each mirror to maximise the overlap between the probe beam and the photolysis laser. Another feature which aids the sensitivity and versatility of the system is the use of 2 high-throughput spectrographs coupled with sensitive line-array CCDs, which can measure absorbance from ˜200 to 800 nm simultaneously. The capability of the instrument is demonstrated via measurements of the absorption spectrum of the peroxy radical, HOCH2CH2O2, and its self-reaction kinetics.

  4. Spatially Resolved Patchy Ly α Emission within the Central Kiloparsec of a Strongly Lensed Quasar Host Galaxy at z = 2.8

    Energy Technology Data Exchange (ETDEWEB)

    Bayliss, Matthew B.; Bordoloi, Rongmon [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States); Sharon, Keren; Runnoe, Jessie; Johnson, Traci; Paterno-Mahler, Rachel [Department of Astronomy, University of Michigan, 1085 S. University Avenue, Ann Arbor, MI 48109 (United States); Acharyya, Ayan; Bian, Fuyan; Kewley, Lisa [RSAA, Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia); Gladders, Michael D. [Kavli Institute for Cosmological Physics, University of Chicago, Chicago, IL 60637 (United States); Rigby, Jane R. [Astrophysics Science Division, NASA Goddard Space Flight Center, 8800 Greenbelt Road, Greenbelt, MD 20771 (United States); Dahle, Hakon [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029, Blindern, NO-0315 Oslo (Norway); Florian, Michael, E-mail: mbayliss@mit.edu [Department of Astronomy and Astrophysics, University of Chicago, Chicago, IL 60637 (United States)

    2017-08-20

    We report the detection of extended Ly α emission from the host galaxy of SDSS J2222+2745, a strongly lensed quasar at z = 2.8. Spectroscopic follow-up clearly reveals extended Ly α in emission between two images of the central active galactic nucleus (AGN). We reconstruct the lensed quasar host galaxy in the source plane by applying a strong lens model to HST imaging and resolve spatial scales as small as ∼200 pc. In the source plane, we recover the host galaxy morphology to within a few hundred parsecs of the central AGN and map the extended Ly α emission to its physical origin on one side of the host galaxy at radii ∼0.5–2 kpc from the central AGN. There are clear morphological differences between the Ly α and rest-frame ultraviolet stellar continuum emission from the quasar host galaxy. Furthermore, the relative velocity profiles of quasar Ly α , host galaxy Ly α , and metal lines in outflowing gas reveal differences in the absorbing material affecting the AGN and host galaxy. These data indicate the presence of patchy local intervening gas in front of the central quasar and its host galaxy. This interpretation is consistent with the central luminous quasar being obscured across a substantial fraction of its surrounding solid angle, resulting in strong anisotropy in the exposure of the host galaxy to ionizing radiation from the AGN. This work demonstrates the power of strong-lensing-assisted studies to probe spatial scales that are currently inaccessible by other means.

  5. Spatially Resolved Patchy Ly α Emission within the Central Kiloparsec of a Strongly Lensed Quasar Host Galaxy at z = 2.8

    International Nuclear Information System (INIS)

    Bayliss, Matthew B.; Bordoloi, Rongmon; Sharon, Keren; Runnoe, Jessie; Johnson, Traci; Paterno-Mahler, Rachel; Acharyya, Ayan; Bian, Fuyan; Kewley, Lisa; Gladders, Michael D.; Rigby, Jane R.; Dahle, Hakon; Florian, Michael

    2017-01-01

    We report the detection of extended Ly α emission from the host galaxy of SDSS J2222+2745, a strongly lensed quasar at z = 2.8. Spectroscopic follow-up clearly reveals extended Ly α in emission between two images of the central active galactic nucleus (AGN). We reconstruct the lensed quasar host galaxy in the source plane by applying a strong lens model to HST imaging and resolve spatial scales as small as ∼200 pc. In the source plane, we recover the host galaxy morphology to within a few hundred parsecs of the central AGN and map the extended Ly α emission to its physical origin on one side of the host galaxy at radii ∼0.5–2 kpc from the central AGN. There are clear morphological differences between the Ly α and rest-frame ultraviolet stellar continuum emission from the quasar host galaxy. Furthermore, the relative velocity profiles of quasar Ly α , host galaxy Ly α , and metal lines in outflowing gas reveal differences in the absorbing material affecting the AGN and host galaxy. These data indicate the presence of patchy local intervening gas in front of the central quasar and its host galaxy. This interpretation is consistent with the central luminous quasar being obscured across a substantial fraction of its surrounding solid angle, resulting in strong anisotropy in the exposure of the host galaxy to ionizing radiation from the AGN. This work demonstrates the power of strong-lensing-assisted studies to probe spatial scales that are currently inaccessible by other means.

  6. The synthesis of carbon nanocomposites as fuel cell catalyst support and the characterization of fuel cell catalysts by spatially resolved scanning mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Li, Nan

    2007-07-01

    Ammonia decomposition over Ni/SiO{sub 2} and Ni/MgO was investigated by temperature-programmed desorption (TPD) and temperature-programmed surface reaction (TPSR) in order to produce CO{sub x} free hydrogen fuel for fuel cell application. A highly efficient route for the synthesis of carbon nanocomposites based on electrochemical deposition and iron catalyzed chemical vapor deposition (CVD) was developed in order to obtain a promising substrate for fuel cell catalysts. The duration of electrochemical deposition, temperature and time for the carbon nanotubes (CNTs) growth had been optimized to achieve higher surface area after the growth. Hierarchically structured CNTs composites had been synthesized and electrochemical studies provided evidence for the strong interaction among the substrate and grown CNTs, which are essential for the application in fuel cells. A straightforward strategy was developed to synthesize well dispersed gold nanoparticles with a diameter of 4 to 6 nm on the sidewall of multi-walled carbon nanotubes (MWNTs). A gas flow set-up was developed for the evaluation of fuel cell catalysts by performing scanning mass spectrometry with integrated constant-distance positioning. Methanol oxidation was identified as a suitable test reaction. The diameter of scanning probe was reduced in order to achieve higher spatial resolution. Spatially resolved scanning mass spectrometry was successfully applied to visualize the catalytic activity over Pt-based catalysts and monitor the local activity of a catalysts coated membrane (CCM). The gas-solid phase reaction results were proved to be accurate, reliable and independent of the sample topography. This analytical method opens the way for fast quality control of the catalyst coating with respect to even coating and absence of damages, and for a better understanding of the CCM degradation in polymer membrane electrolyte fuel cells (PEMFCs). (orig.)

  7. Time-resolved studies at PETRA III with a highly repetitive synchronized laser system

    Energy Technology Data Exchange (ETDEWEB)

    Schlie, Mortiz

    2013-09-15

    Atomic and molecular processes can nowadays be directly followed in the time domain. This is a core technique for a better understanding of the involved fundamental physics, thus auguring new applications in the future as well. Usually the so-called pump-probe technique making use of two synchronized ultrashort light pulses is utilized to obtain this time-resolved data. In this work, the development and characterization of a synchronization system enabling such pump-probe studies at the storage ring PETRA III in combination with an external, then synchronized fs-laser system is described. The synchronization is based on an extended PLL approach with three interconnected feedback loops allowing to monitor short-time losses of the lock and thus prevent them. This way, the jitter between the laser PHAROS and the PETRA III reference signal is reduced to {sigma} <5 ps. Thus the system allows to conduct experiments at a repetition rate of 130 kHz with a temporal resolution limited only by the X-ray pulse length. A major emphasis in the fundamental introductory chapters is an intuitive explanation of the basic principles of phase locked loops and the different aspects of phase noise to allow a deeper understanding of the synchronization. Furthermore, first pump-probe experiments conducted at different beamlines at PETRA III are presented, demonstrating the usability of the laser system in a scientific environment as well. In first characterizing experiments the pulse duration of PETRA III X-ray pulses has been measured to be 90 ps FWHM. In particular, there have been time resolved X-ray absorption spectroscopy experiments on Gaq3 and Znq2 conducted at beamline P11. First results show dynamics of the electronic excitation on the timescale of a few hundred pico seconds up to a few nano seconds and provide a basic understanding for further research on those molecules. For Gaq3 this data is analyzed in detail and compared with visible fluorescence measurements suggesting at

  8. Time-resolved studies at PETRA III with a highly repetitive synchronized laser system

    International Nuclear Information System (INIS)

    Schlie, Mortiz

    2013-09-01

    Atomic and molecular processes can nowadays be directly followed in the time domain. This is a core technique for a better understanding of the involved fundamental physics, thus auguring new applications in the future as well. Usually the so-called pump-probe technique making use of two synchronized ultrashort light pulses is utilized to obtain this time-resolved data. In this work, the development and characterization of a synchronization system enabling such pump-probe studies at the storage ring PETRA III in combination with an external, then synchronized fs-laser system is described. The synchronization is based on an extended PLL approach with three interconnected feedback loops allowing to monitor short-time losses of the lock and thus prevent them. This way, the jitter between the laser PHAROS and the PETRA III reference signal is reduced to σ <5 ps. Thus the system allows to conduct experiments at a repetition rate of 130 kHz with a temporal resolution limited only by the X-ray pulse length. A major emphasis in the fundamental introductory chapters is an intuitive explanation of the basic principles of phase locked loops and the different aspects of phase noise to allow a deeper understanding of the synchronization. Furthermore, first pump-probe experiments conducted at different beamlines at PETRA III are presented, demonstrating the usability of the laser system in a scientific environment as well. In first characterizing experiments the pulse duration of PETRA III X-ray pulses has been measured to be 90 ps FWHM. In particular, there have been time resolved X-ray absorption spectroscopy experiments on Gaq3 and Znq2 conducted at beamline P11. First results show dynamics of the electronic excitation on the timescale of a few hundred pico seconds up to a few nano seconds and provide a basic understanding for further research on those molecules. For Gaq3 this data is analyzed in detail and compared with visible fluorescence measurements suggesting at least

  9. SPATIALLY RESOLVED STAR FORMATION HISTORY ALONG THE DISK OF M82 USING MULTI-BAND PHOTOMETRIC DATA

    International Nuclear Information System (INIS)

    Rodriguez-Merino, L. H.; Rosa-Gonzalez, D.; Mayya, Y. D.

    2011-01-01

    We present results on the star formation history and extinction in the disk of M82 over spatial scales of 10'' (∼180 pc). Multi-band photometric data covering the far-ultraviolet to the near-infrared bands were fitted to a grid of synthetic spectral energy distributions. We obtained distribution functions of age and extinction for each of the 117 apertures analyzed, taking into account observational errors through Monte Carlo simulations. These distribution functions were fitted with Gaussian functions to obtain the mean ages and extinctions together with their errors. The zones analyzed include the high surface brightness complexes defined by O'Connell and Mangano. We found that these complexes share the same star formation history and extinction as the field stellar populations in the disk. There is an indication that the stellar populations are marginally older at the outer disk (450 Myr at ∼3 kpc) as compared to the inner disk (100 Myr at 0.5 kpc). For the nuclear region (radius less than 500 pc), we obtained an age of less than 10 Myr. The results obtained in this work are consistent with the idea that the 0.5-3 kpc part of the disk of M82 formed around 90% of the stellar mass in a star-forming episode that started around 450 Myr ago and lasted for about 350 Myr. We found that field stars are the major contributors to the flux over the spatial scales analyzed in this study, with the stellar cluster contribution being 7% in the nucleus and 0.7% in the disk.

  10. Spatially resolved analyses of uranium species using a coupled system made up of confocal laser-scanning microscopy (CLSM) and laser induced fluorescence spectroscopy (LIFS)

    International Nuclear Information System (INIS)

    Brockmann, S.; Grossmann, K.; Arnold, T.

    2014-01-01

    The fluorescent properties of uranium when excited by UV light are used increasingly for spectroscope analyses of uranium species within watery samples. Here, alongside the fluorescent properties of the hexavalent oxidation phases, the tetra and pentavalent oxidation phases also play an increasingly important role. The detection of fluorescent emission spectrums on solid and biological samples using (time-resolved) laser induced fluorescence spectroscopy (TRLFS or LIFS respectively) has, however, the disadvantage that no statements regarding the spatial localisation of the uranium can be made. However, particularly in complex, biological samples, such statements on the localisation of the uranium enrichment in the sample are desired, in order to e.g. be able to distinguish between intra and extra-cellular uranium bonds. The fluorescent properties of uranium (VI) compounds and minerals can also be used to detect their localisation within complex samples. So the application of fluorescent microscopic methods represents one possibility to localise and visualise uranium precipitates and enrichments in biological samples, such as biofilms or cells. The confocal laser-scanning microscopy (CLSM) is especially well suited to this purpose. Coupling confocal laser-scanning microscopy (CLSM) with laser induced fluorescence spectroscopy (LIFS) makes it possible to localise and visualise fluorescent signals spatially and three-dimensionally, while at the same time being able to detect spatially resolved, fluorescent-spectroscopic data. This technology is characterised by relatively low detection limits from up to 1.10 -6 M for uranium (VI) compounds within the confocal volume. (orig.)

  11. Femtosecond time-resolved studies of coherent vibrational Raman scattering in large gas-phase molecules

    International Nuclear Information System (INIS)

    Hayden, C.C.; Chandler, D.W.

    1995-01-01

    Results are presented from femtosecond time-resolved coherent Raman experiments in which we excite and monitor vibrational coherence in gas-phase samples of benzene and 1,3,5-hexatriene. Different physical mechanisms for coherence decay are seen in these two molecules. In benzene, where the Raman polarizability is largely isotropic, the Q branch of the vibrational Raman spectrum is the primary feature excited. Molecules in different rotational states have different Q-branch transition frequencies due to vibration--rotation interaction. Thus, the macroscopic polarization that is observed in these experiments decays because it has many frequency components from molecules in different rotational states, and these frequency components go out of phase with each other. In 1,3,5-hexatriene, the Raman excitation produces molecules in a coherent superposition of rotational states, through (O, P, R, and S branch) transitions that are strong due to the large anisotropy of the Raman polarizability. The coherent superposition of rotational states corresponds to initially spatially oriented, vibrationally excited, molecules that are freely rotating. The rotation of molecules away from the initial orientation is primarily responsible for the coherence decay in this case. These experiments produce large (∼10% efficiency) Raman shifted signals with modest excitation pulse energies (10 μJ) demonstrating the feasibility of this approach for a variety of gas phase studies. copyright 1995 American Institute of Physics

  12. Time resolved LIF measurements for the study of NO removal: influence of H2O

    International Nuclear Information System (INIS)

    Fresnet, F.; Baravian, G.; Magne, L.; Pasquiers, S.; Postel, C.; Puech, V.; Rousseau, A.

    2001-01-01

    We have developed a time-resolved laser-induced fluorescence (LIF) diagnostic of the NO-removal in a pre-ionized homogeneous discharge, i.e. without density nor temperature gradients, using the photo-triggering technique. This technique allows to measure specie densities in the temporal post-discharge after one homogeneous pulsed excitation, so that experimental results can be more confidently compared to predictions of a 0D-model, i.e. a model which have a spatially homogeneous kinetic description of the cleaning process. This model is fully self-consistent and describe both kinetics during the discharge and the post-discharge. We first reported the influence of electrical parameters (energy and reduced electric field) on the NO removal efficiency in the N 2 /NO mixture. Then, the influence of hydrocarbon (C 2 H 4 ) addition was determined. We showed that dissociation of NO through collision with the metastable state N 2 (a '1 Σ u - ) play the main part in the NO-removal process in homogeneously excited N 2 /NO mixture, and, that a de-excitation process of N 2 (a '1 Σ u - ) by C 2 H 4 explains that the NO-removal efficiency decreases when ethene is added to the mixture. Estimation for the rate coefficient value of this reaction, closed to the known value for methane, was also deduced from our results. In this study, the influence of water is investigated on the NO removal efficiency

  13. Spatially resolved investigation of competing nanocluster emission in quantum-disks-in-nanowires structure characterized by nanoscale cathodoluminescence

    KAUST Repository

    Prabaswara, Aditya; Stowe, David J.; Janjua, Bilal; Ng, Tien Khee; Anjum, Dalaver H.; Longo, Paolo; Zhao, Chao; Elafandy, Rami T.; Li, Xiaohang; Alyamani, Ahmed Y.; El-Desouki, Munir M.; Ooi, Boon S.

    2017-01-01

    We report on the study and characterization of nanoclusters-related recombination centers within quantum-disks-in-nanowires heterostructure by utilizing microphotoluminescence (mu-PL) and cathodoluminescence scanning transmission electron microscopy (CL-STEM). mu-PL measurement shows that the nanoclusters-related recombination center exhibits different temperature-dependent characteristics compared with the surrounding InGaN quantum-disksrelated recombination center. CL-STEM measurements reveal that these recombination centers mainly arise from irregularities within the quantum disks, with a strong, spatially localized emission when measured at low temperature. The spectra obtained from both CL-STEM and mu-PL correlate well with each other. Our work sheds light on the optical and structural properties of simultaneously coexisting recombination centers within nanowires heterostructures. (C) The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.

  14. Spatially resolved investigation of competing nanocluster emission in quantum-disks-in-nanowires structure characterized by nanoscale cathodoluminescence

    KAUST Repository

    Prabaswara, Aditya

    2017-06-30

    We report on the study and characterization of nanoclusters-related recombination centers within quantum-disks-in-nanowires heterostructure by utilizing microphotoluminescence (mu-PL) and cathodoluminescence scanning transmission electron microscopy (CL-STEM). mu-PL measurement shows that the nanoclusters-related recombination center exhibits different temperature-dependent characteristics compared with the surrounding InGaN quantum-disksrelated recombination center. CL-STEM measurements reveal that these recombination centers mainly arise from irregularities within the quantum disks, with a strong, spatially localized emission when measured at low temperature. The spectra obtained from both CL-STEM and mu-PL correlate well with each other. Our work sheds light on the optical and structural properties of simultaneously coexisting recombination centers within nanowires heterostructures. (C) The Authors. Published by SPIE under a Creative Commons Attribution 3.0 Unported License. Distribution or reproduction of this work in whole or in part requires full attribution of the original publication, including its DOI.

  15. Grid studies for the simulation of resolved structures in an Eulerian two-fluid framework

    Energy Technology Data Exchange (ETDEWEB)

    Gauss, Friederike, E-mail: f.gauss@hzdr.de; Lucas, Dirk; Krepper, Eckhard

    2016-08-15

    Highlights: • Elaborated Eulerian two-fluid methods may predict multiphase flow with large differences in interfacial length scales. • A study on the grid requirements of resolved structures in such two-fluid methods is presented. • The two-fluid results are only little dependent on the grid size. • The results justify the resolved treatment of flow structures covering only few grid cells. • A grid-dependent limit between resolved an modeled structures may be established. - Abstract: The influence of the grid size on the rise velocity of a single bubble simulated with an Eulerian two-fluid method is investigated. This study is part of the development of an elaborated Eulerian two-fluid framework, which is able to predict complex flow phenomena as arising in nuclear reactor safety research issues. Such flow phenomena cover a wide range of interfacial length scales. An important aspect of the simulation method is the distinction into small flow structures, which are modeled, and large structures, which are resolved. To investigate the requirements on the numerical grid for the simulation of such resolved structures the velocity of rising gas bubbles is a good example since theoretical values are available. It is well known that the rise velocity of resolved bubbles is clearly underestimated in a one-fluid approach if they span over only few numerical cells. In the present paper it is shown that in the case of the two-fluid model the bubble rise velocity depends only slightly on the grid size. This is explained with the use of models for the gas–liquid interfacial forces. Good approximations of the rise velocity and the bubble shape are obtained with only few grid points per bubble diameter. This result justifies the resolved treatment of flow structures, which cover only few grid cells. Thus, a limit for the distinction into resolved and modeled structures in the two-fluid context may be established.

  16. Study of the photon remnant in resolved photoproduction at HERA

    International Nuclear Information System (INIS)

    Derrick, M.; Krakauer, D.; Magill, S.

    1995-01-01

    Photoproduction at HERA is studied in ep collisions, with the ZEUS detector, for γp centre-of-mass energies ranging from 130-270 GeV. A sample of events with two high-p T jets (p T >6 GeV, η T with respect to the beam axis is measured to be 2.1±0.2 GeV, which demonstrates substantial mean transverse momenta for the photon remnant. (orig.)

  17. A spatially resolved network spike in model neuronal cultures reveals nucleation centers, circular traveling waves and drifting spiral waves.

    Science.gov (United States)

    Paraskevov, A V; Zendrikov, D K

    2017-03-23

    We show that in model neuronal cultures, where the probability of interneuronal connection formation decreases exponentially with increasing distance between the neurons, there exists a small number of spatial nucleation centers of a network spike, from where the synchronous spiking activity starts propagating in the network typically in the form of circular traveling waves. The number of nucleation centers and their spatial locations are unique and unchanged for a given realization of neuronal network but are different for different networks. In contrast, if the probability of interneuronal connection formation is independent of the distance between neurons, then the nucleation centers do not arise and the synchronization of spiking activity during a network spike occurs spatially uniform throughout the network. Therefore one can conclude that spatial proximity of connections between neurons is important for the formation of nucleation centers. It is also shown that fluctuations of the spatial density of neurons at their random homogeneous distribution typical for the experiments in vitro do not determine the locations of the nucleation centers. The simulation results are qualitatively consistent with the experimental observations.

  18. Time-resolved infrared studies of protein conformational dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Woodruff, W.H.; Causgrove, T.P.; Dyer, R.B. [Los Alamos National Laboratory, NM (United States); Callender, R.H. [Univ. of New York, NY (United States)

    1994-12-01

    We have demonstrated that TRIR in the amide I region gives structural information regarding protein conformational changes in realtime, both on processes involved in the development of the functional structure (protein folding) and on protein structural changes that accompany the functional dynamics of the native structure. Assignment of many of the amide I peaks to specific amide or sidechain structures will require much additional effort. Specifically, the congestion and complexity of the protein vibrational spectra dictate that isotope studies are an absolute requirement for more than a qualitative notion of the structural interpretation of these measurements. It is clear, however, that enormous potential exists for elucidating structural relaxation dynamics and energetics with a high degree of structural specificity using this approach.

  19. SPATIALLY RESOLVED KINEMATICS OF THE CENTRAL REGIONS OF M83: HIDDEN MASS SIGNATURES AND THE ROLE OF SUPERNOVAE

    Energy Technology Data Exchange (ETDEWEB)

    Piqueras Lopez, J.; Colina, L. [Centro de Astrobiologia, INTA-CSIC (Spain); Davies, R.; Orban de Xivry, G., E-mail: piqueraslj@cab.inta-csic.es [Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1312, 85741 Garching (Germany)

    2012-06-10

    The barred grand-design spiral M83 (NGC 5236) is one of the most studied galaxies given its proximity, orientation, and particular complexity. Nonetheless, many aspects of the central regions remain controversial, conveying our limited understanding of the inner gas and stellar kinematics, and ultimately of the nucleus evolution. In this work, we present AO VLT-SINFONI data of its central {approx}235 Multiplication-Sign 140 pc with an unprecedented spatial resolution of {approx}0.2 arcsec, corresponding to {approx}4 pc. We have focused our study on the distribution and kinematics of the stars and the ionized and molecular gas by studying the Pa{alpha} and Br{gamma} emission in detail, the H{sub 2} 1-0S(1) line at 2.122 {mu}m, and the [Fe II] line at 1.644 {mu}m, together with the CO absorption bands at 2.293 {mu}m and 2.323 {mu}m. Our results reveal a complex situation where the gas and stellar kinematics are totally unrelated. Supernova explosions play an important role in shaping the gas kinematics, dominated by shocks and inflows at scales of tens of parsecs that make them unsuitable to derive general dynamical properties. We propose that the location of the nucleus of M83 is unlikely to be related to the off-center 'optical nucleus'. The study of the stellar kinematics reveals that the optical nucleus is a gravitationally bound massive star cluster with M{sub dyn} = (1.1 {+-} 0.4) Multiplication-Sign 10{sup 7} M{sub Sun }, formed by a past starburst. The kinematic and photometric analysis of the cluster yield that the stellar content of the cluster is well described by an intermediate age population of log T(yr) = 8.0 {+-} 0.4, with a mass of M* {approx_equal} (7.8 {+-} 2.4) Multiplication-Sign 10{sup 6} M{sub Sun }.

  20. Studying the potential of point detectors in time-resolved dose verification of dynamic radiotherapy

    DEFF Research Database (Denmark)

    Beierholm, Anders Ravnsborg; Behrens, C. F.; Andersen, Claus E.

    2015-01-01

    based on fiber-coupled plastic scintillator detectors was evaluated and compared with a Farmer-type ionization chamber and a small-volume ionization chamber. An important feature of scintillator detectors is that the sensitive volume of the detector can easily be scaled, and five scintillator detectors......-volume ionization chamber and the smallest scintillators. The time-resolved RapidArc dose profiles revealed volume-dependent discrepancies between scintillator and ionization chamber response, which confirmed that correction factors for ionization chambers in high temporal and spatial dose gradients are dominated...

  1. Towards real time spatially resolved data on sediment transport: 1) tracing the motion of the fluorescent soil particles under rainfall

    Science.gov (United States)

    Quinton, John; Hardy, Rob; Pates, Jackie; James, Mike

    2017-04-01

    Understanding where sediment originates from and where it travels to, in what quantities and at which rate is at the heart of many questions surrounding sediment transport, including the connectivity problem. Progress towards unravelling these questions and deepening our understanding has come from a wide range of approaches, including laboratory and field experiments conducted at a variety of scales. In seeking to understand the connectivity of sources and sinks of sediment scientists have spent considerable energy in developing tracing technologies. These have included numerous studies that have relied on the chemical properties of the soil and sediment to establish source-sink connectivity, and the use of 137Ceasium, from radioactive fall-out, to map sediment redistribution. More recently there has been an upsurge in interest in the use of artificially applied soil tracers, including rare earth element oxides and magnetic minerals. However all these tracing methods have a significant drawback: they rely on the collection of samples to assess their concentration. This means that their spatial distribution cannot easily be established in situ and that the environment that is being studied is damaged by the sampling process; nor can data be collected in real time which allows a dynamic understanding of erosion and transport processes to be developed. In this paper we present a methodology for use with a commercially available fluorescent tracer. The tracer is produced in a range of sizes and fluorescent signatures and can be applied to the soil surface. Here we report on an application that combines novel fluorescent videography techniques with custom image processing to trace the motion of the fluorescent soil particles under rainfall. Here we demonstrate the tracking of multiple sub-millimetre particles simultaneously, establishing their position 50 times a second with submillimetre precision. From this we are able to visualise and quantify parameters such as

  2. Comparison of spatially and temporally resolved diffuse transillumination measurement systems for extraction of optical properties of scattering media.

    Science.gov (United States)

    Ortiz-Rascón, E; Bruce, N C; Garduño-Mejía, J; Carrillo-Torres, R; Hernández-Paredes, J; Álvarez-Ramos, M E

    2017-11-20

    This paper discusses the main differences between two different methods for determining the optical properties of tissue optical phantoms by fitting the spatial and temporal intensity distribution functions to the diffusion approximation theory. The consistency in the values of the optical properties is verified by changing the width of the recipient containing the turbid medium; as the optical properties are an intrinsic value of the scattering medium, independently of the recipient width, the stability in these values for different widths implies a better measurement system for the acquisition of the optical properties. It is shown that the temporal fitting method presents higher stability than the spatial fitting method; this is probably due to the addition of the time of flight parameter into the diffusion theory.

  3. A highly spatially resolved GIS-based model to assess the isoprenoid emissions from key Italian ecosystems

    Science.gov (United States)

    Pacheco, Claudia Kemper; Fares, Silvano; Ciccioli, Paolo

    2014-10-01

    The amount of Biogenic Volatile Organic Compounds (BVOC) emitted from terrestrial vegetation is of great importance in atmospheric reactivity, particularly for ozone-forming reactions and as condensation nuclei in aerosol formation and growth. This work presents a detailed inventory of isoprenoid emissions from vegetation in Italy using an original approach which combines state of the art models to estimate the species-specific isoprenoid emissions and a Geographic Information System (GIS) where emissions are spatially represented. Isoprenoid species and basal emission factors were obtained by combining results from laboratory experiments with those published in literature. For the first time, our investigation was not only restricted to isoprene and total monoterpenes, but our goal was to provide maps of isoprene and individual monoterpenes at a high-spatial (∼1 km2) and temporal resolution (daily runs, monthly trends in emissions are discussed in the text). Another novelty in our research was the inclusion of the effects of phenology on plant emissions. Our results show that: a) isoprene, a-pinene, sabinene and b-pinene are the most important compounds emitted from vegetation in Italy; b) annual biogenic isoprene and monoterpene fluxes for the year 2006 were ∼31.30 Gg and ∼37.70 Gg, respectively; and c) Quercus pubescens + Quercus petrea + Quercus robur, Quercus ilex, Quercus suber and Fagus sylvatica are the principal isoprenoid emitting species in the country. The high spatial and temporal resolution, combined with the species-specific emission output, makes the model particularly suitable for assessing local budgets, and for modeling photochemical pollution in Italy.

  4. Spatially-Resolved Ion Trajectory Measurements During Cl2 Reactive Ion Beam Etching and Ar Ion Beam Etching

    International Nuclear Information System (INIS)

    Vawter, G. Allen; Woodworth, Joseph R.; Zubrzycki, Walter J.

    1999-01-01

    The angle of ion incidence at the etched wafer location during RIBE and IBE using Cl 2 , Ar and O 2 ion beams has been characterized using an ion energy and angle analyzer. Effects of beam current and accelerator grid bias on beam divergence and the spatial uniformity of the spread of incident angles are measured. It is observed that increased total beam current can lead to reduced current density at the sample stage due to enhanced beam divergence at high currents. Results are related to preferred etch system design for uniform high-aspect-ratio etching across semiconductor wafers

  5. Spatially resolved investigation of the oil composition in single intact hyphae of Mortierella spp. with micro-Raman spectroscopy.

    Science.gov (United States)

    Münchberg, Ute; Wagner, Lysett; Spielberg, Eike T; Voigt, Kerstin; Rösch, Petra; Popp, Jürgen

    2013-02-01

    Zygomycetes are well known for their ability to produce various secondary metabolites. Fungi of the genus Mortierella can accumulate highly unsaturated lipids in large amounts as lipid droplets. However, no information about the spatial distribution or homogeneity of the oil inside the fungi is obtainable to date due to the invasive and destructive analytical techniques applied so far. Raman spectroscopy has been demonstrated to be well suited to investigate biological samples on a micrometre scale. It also has been shown that the degree of unsaturation of lipids can be determined from Raman spectra. We applied micro-Raman spectroscopy to investigate the spatial distribution and composition of lipid vesicles inside intact hyphae. For Mortierella alpina and Mortierella elongata distinct differences in the degree of unsaturation and even the impact of growth conditions are determined from the Raman spectra. In both species we found that the fatty acid saturation in the vesicles is highly variable in the first 600 μm of the growing hyphal tip and fluctuates towards a constant composition and saturation ratio in all of the remaining mycelium. Our approach facilitates in vivo monitoring of the lipid production and allows us to investigate the impact of cultivation parameters on the oil composition directly in the growing hyphae without the need for extensive extraction procedures. Copyright © 2012 Elsevier B.V. All rights reserved.

  6. Study fidelity spatial contours of industrial robots

    Directory of Open Access Journals (Sweden)

    A. V. Ivanova

    2014-01-01

    Full Text Available The purpose of this paper to identify deviations fidelity spatial contours of industrial robots, determine the error pattern detected, and define the ways to solve the problem.The paper presents the research results of fidelity spatial contours done by Fanuc M- 710iC/50 industrial robot when moving along a predetermined path. The proposed method uses a QC20-W ballbar wireless system of Renishaw company, designed to diagnose the state of the measurement and playback linear and angular displacements of the CNC.The solutions to adapt the QC20-W ballbar system to the constructive peculiarities of industrial robots with five or more independently controlled axes are given. The stages of the preparation of diagnostic systems and software robot movements are described.According to study results of errors that arise while playing back the programmed motions of a fixed point of robot capture in three mutually perpendicular planes its practical accuracy has been defined when performing movements in a given region of the working area, thereby allowing us, eventually, to draw a conclusion on the possibility to use a robot in one technological process or another.The study has resulted in emerging the guidelines for the operation of industrial robots with five or more independently controlled axes. Using these guidelines enables us to increase the playback accuracy of the industrial robot to 0.01 mm.

  7. A temporally and spatially resolved electron density diagnostic method for the edge plasma based on Stark broadening

    Energy Technology Data Exchange (ETDEWEB)

    Zafar, A., E-mail: zafara@ornl.gov [Department of Nuclear Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830 (United States); Martin, E. H.; Isler, R. C.; Caughman, J. B. O. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830 (United States); Shannon, S. C. [Department of Nuclear Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2016-11-15

    An electron density diagnostic (≥10{sup 10} cm{sup −3}) capable of high temporal (ms) and spatial (mm) resolution is currently under development at Oak Ridge National Laboratory. The diagnostic is based on measuring the Stark broadened, Doppler-free spectral line profile of the n = 6–2 hydrogen Balmer series transition. The profile is then fit to a fully quantum mechanical model including the appropriate electric and magnetic field operators. The quasi-static approach used to calculate the Doppler-free spectral line profile is outlined here and the results from the model are presented for H-δ spectra for electron densities of 10{sup 10}–10{sup 13} cm{sup −3}. The profile shows complex behavior due to the interaction between the magnetic substates of the atom.

  8. Implications for gravitational lensing and the dark matter content in clusters of galaxies from spatially resolved x-ray spectra

    Science.gov (United States)

    Loewenstein, M.

    1994-01-01

    A simple method for deriving well-behaved temperature solutions to the equation of hydrostatic equilibrium for intracluster media with X-ray imaging observations is presented and applied to a series of generalized models as well as to observations of the Perseus cluster and Abell 2256. In these applications the allowed range in the ratio of nonbaryons to baryons as a function of radius is derived, taking into account the uncertainties and crude spatial resolution of the X-ray spectra and considering a range of physically reasonable mass models with various scale heights. Particular attention is paid to the central regions of the cluster, and it is found that the dark matter can be sufficiently concentrated to be consistent with the high central mass surface densities for moderate-redshift clusters from their gravitational lensing properties.

  9. Late-Emerging and Resolving Dyslexia : A Follow-Up Study from Age 3 to 14

    NARCIS (Netherlands)

    Torppa, Minna; Eklund, Kenneth; van Bergen, Elsje; Lyytinen, Heikki

    2015-01-01

    This study focuses on the stability of dyslexia status from Grade 2 to Grade 8 in four groups: (a) no dyslexia in either grade (no-dyslexia, n = 127); (b) no dyslexia in Grade 2 but dyslexia in Grade 8 (late-emerging, n = 18); (c) dyslexia in Grade 2 but not in Grade 8 (resolving, n = 15); and (d)

  10. Study of resolved high-psub(T) neutral pions at the CERN ISR

    International Nuclear Information System (INIS)

    Kourkoumelis, C.; Resvanis, L.K.; Voulgaris, G.; Filippas, T.A.; Fokitis, E.; Fabjan, C.W.; Fields, T.; Lissauer, D.; Mannelli, I.; Mouzourakis, P.; Nakamura, K.; Nappi, A.; Willis, W.J.; Goldberg, M.; Lankford, A.J.

    1979-01-01

    The inclusive production of π 0 at large values of psub(T) in pp collisions at the ISR has been studied. In this experiment the two photons are resolved and separately measured for psub(T) values of up to 6 GeV/c, giving confidence that the desired signal has been separated from various backgrounds. (Auth.)

  11. Reduction of Guanosyl Radical by Cysteine and Cysteine-Glycine Studied by Time-Resolved CIDNP

    NARCIS (Netherlands)

    Morozova, O.B.; Kaptein, R.; Yurkovskaya, A.V.

    2012-01-01

    As a model for chemical DNA repair, reduction of guanosyl radicals in the reaction with cysteine or the dipeptide cysteine-glycine has been studied by time-resolved chemically induced dynamic nuclear polarization (CIDNP). Radicals were generated photochemically by pulsed laser irradiation of a

  12. Influence of hydrostatic pressure on dynamics and spatial distribution of protein partial molar volume: time-resolved surficial Kirkwood-Buff approach.

    Science.gov (United States)

    Yu, Isseki; Tasaki, Tomohiro; Nakada, Kyoko; Nagaoka, Masataka

    2010-09-30

    The influence of hydrostatic pressure on the partial molar volume (PMV) of the protein apomyoglobin (AMb) was investigated by all-atom molecular dynamics (MD) simulations. Using the time-resolved Kirkwood-Buff (KB) approach, the dynamic behavior of the PMV was identified. The simulated time average value of the PMV and its reduction by 3000 bar pressurization correlated with experimental data. In addition, with the aid of the surficial KB integral method, we obtained the spatial distributions of the components of PMV to elucidate the detailed mechanism of the PMV reduction. New R-dependent PMV profiles identified the regions that increase or decrease the PMV under the high pressure condition. The results indicate that besides the hydration in the vicinity of the protein surface, the outer space of the first hydration layer also significantly influences the total PMV change. These results provide a direct and detailed picture of pressure induced PMV reduction.

  13. Spectral and spatial resolving of photoelectric property of femtosecond laser drilled holes of GaSb(1-x)Bi(x).

    Science.gov (United States)

    Pan, C B; Zha, F X; Song, Y X; Shao, J; Dai, Y; Chen, X R; Ye, J Y; Wang, S M

    2015-07-15

    Femtosecond laser drilled holes of GaSbBi were characterized by the joint measurements of photoconductivity (PC) spectroscopy and laser-beam-induced current (LBIC) mapping. The excitation light in PC was focused down to 60 μm presenting the spectral information of local electronic property of individual holes. A redshift of energy band edge of about 6-8 meV was observed by the PC measurement when the excitation light irradiated on the laser drilled holes. The spatial resolving of photoelectric property was achieved by the LBIC mapping which shows "pseudo-holes" with much larger dimensions than the geometric sizes of the holes. The reduced LBIC current with the pseudo-holes is associated with the redshift effect indicating that the electronic property of the rim areas of the holes is modified by the femtosecond laser drilling.

  14. Molecular Chemical Structure of Barley Proteins Revealed by Ultra-Spatially Resolved Synchrotron Light Sourced FTIR Microspectroscopy: Comparison of Barley Varieties

    International Nuclear Information System (INIS)

    Yu, P.

    2007-01-01

    Barley protein structure affects the barley quality, fermentation, and degradation behavior in both humans and animals among other factors such as protein matrix. Publications show various biological differences among barley varieties such as Valier and Harrington, which have significantly different degradation behaviors. The objectives of this study were to reveal the molecular structure of barley protein, comparing various varieties (Dolly, Valier, Harrington, LP955, AC Metcalfe, and Sisler), and quantify protein structure profiles using Gaussian and Lorentzian methods of multi-component peak modeling by using the ultra-spatially resolved synchrotron light sourced Fourier transform infrared microspectroscopy (SFTIRM). The items of the protein molecular structure revealed included protein structure α-helices, β-sheets, and others such as β-turns and random coils. The experiment was performed at the National Synchrotron Light Source in Brookhaven National Laboratory (BNL, US Department of Energy, NY). The results showed that with the SFTIRM, the molecular structure of barley protein could be revealed. Barley protein structures exhibited significant differences among the varieties in terms of proportion and ratio of model-fitted α-helices, β-sheets, and others. By using multi-component peaks modeling at protein amide I region of 1710-1576 cm -1 , the results show that barley protein consisted of approximately 18-34% of α-helices, 14-25% of β-sheets, and 44-69% others. AC Metcalfe, Sisler, and LP955 consisted of higher (P 0.05). The ratio of α-helices to others (0.3 to 1.0, P < 0.05) and that of β-sheets to others (0.2 to 0.8, P < 0.05) were different among the barley varieties. It needs to be pointed out that using a multi-peak modeling for protein structure analysis is only for making relative estimates and not exact determinations and only for the comparison purpose between varieties. The principal component analysis showed that protein amide I Fourier

  15. Recombination dynamics in coalesced a-plane GaN ELO structures investigated by high spatially and ps-time-resolved cathodoluminescence microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bastek, B.; Bertram, F.; Christen, J. [Institute of Experimental Physics, Otto-von-Guericke-University Magdeburg (Germany); Wernicke, T.; Weyers, M. [Ferdinand-Braun-Institut fuer Hoechstfrequenztechnik, Berlin (Germany); Kneissl, M. [Institute of Solid State Physics, Technical University, Berlin (Germany)

    2008-07-01

    The characteristic epitaxial lateral overgrowth (ELO) domains of fully coalesced a-plane GaN layers were directly imaged by highly spatially and spectrally resolved cathodoluminescence microscopy (CL) at 5 K. The patterned layers were grown by MOVPE on r-plane sapphire substrate and stripe masks oriented in the [01 anti 10] direction. In the area of coherent growth (I) the broad basal plane stacking fault (BSF) emission centered at 3.41 eV dominates the spectra. Also in the region (II) of coalescence the BSF luminescence dominates, however, the intensity increases by one order of magnitude compared to area (I). In complete contrast, in the stripes associated with the laterally grown domains (III) in [0001] direction, exclusively an intense and sharp (D{sup 0},X) emission at 3.475 eV is observed. ps-time-resolved CL of the free excitons (FX) recorded from this domains (III) decays bi-exponentially. The initial lifetime of 180 ps is primarily given by the capture of FX by impurities to form bound excitons (BE). With rising temperature this capture time constant decreases as T{sup -1/4} and reaches a minimum of 104 ps at T=60 K. Above 60 K, i.e. when FX starts to dominate the BEs, the lifetime increases rapidly to a value of 240 ps for 300 K.

  16. Investigations of lateral and vertical compositional gradients in Cu(In,Ga)Se{sub 2} by highly spatially, spectrally and time resolved cathodoluminescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, Mathias; Ribbe, Stefan; Hempel, Thomas; Bertram, Frank; Christen, Juergen [Institute for Experimental Physics, Otto-von-Guericke-University, Magdeburg (Germany); Witte, Wolfram; Hariskos, Dimitrios [Zentrum fuer Sonnenenergie- und Wasserstoff-Forschung Baden-Wuerttemberg (ZSW), Stuttgart (Germany)

    2011-07-01

    Luminescence properties of Cu(In,Ga)Se{sub 2} (CIGS) layers with different thicknesses were investigated by means of highly spatially, spectrally and time resolved cathodoluminescence (CL) spectroscopy at low temperature (T=5 K). A polycrystalline CIGS thin film with a thickness of 2.4 {mu}m was grown using an in-line co-evaporation process with a final Cu-poor composition on top of a sputtered Mo layer on a soda lime glass substrate. The layer thickness was then reduced by highly controlled bromine methanol etching. The typical grainy (d{sub average}=3 {mu}m) structure of the untouched sample develops thin longish structures under the influence of the etchant. Integral CL spectra of the samples are dominated by donor-acceptor pair (DAP) luminescence. The peak energies of these spectra are ranging from 1.13 eV to 1.22 eV with decreasing layer thickness. The lateral distribution of the luminescence is inhomogeneous regarding the intensity as well as the peak energy. Time resolved CL shows a strong dependence of the initial lifetime from the emission energy.

  17. Development of an integrated fission product release and transport code for spatially resolved full-core calculations of V/HTRs

    International Nuclear Information System (INIS)

    Xhonneux, Andre; Allelein, Hans-Josef

    2014-01-01

    The computer codes FRESCO-I, FRESCO-II, PANAMA and SPATRA developed at Forschungszentrum Jülich in Germany in the early 1980s are essential tools to predict the fission product release from spherical fuel elements and the TRISO fuel performance, respectively, under given normal or accidental conditions. These codes are able to calculate a conservative estimation of the source term, i.e. quantity and duration of radionuclide release. Recently, these codes have been reversed engineered, modernized (FORTRAN 95/2003) and combined to form a consistent code named STACY (Source Term Analysis Code System). STACY will later become a module of the V/HTR Code Package (HCP). In addition, further improvements have been implemented to enable more detailed calculations. For example the distinct temperature profile along the pebble radius is now taken into account and coated particle failure rates can be calculated under normal operating conditions. In addition, the absolute fission product release of an V/HTR pebble bed core can be calculated by using the newly developed burnup code Topological Nuclide Transformation (TNT) replacing the former rudimentary approach. As a new functionality, spatially resolved fission product release calculations for normal operating conditions as well as accident conditions can be performed. In case of a full-core calculation, a large number of individual pebbles which follow a random path through the reactor core can be simulated. The history of the individual pebble is recorded, too. Main input data such as spatially resolved neutron fluxes and fluid dynamics data are provided by the VSOP code. Capabilities of the FRESCO-I and SPATRA code which allow for the simulation of the redistribution of fission products within the primary circuit and the deposition of fission products on graphitic and metallic surfaces are also available in STACY. In this paper, details of the STACY model and first results for its application to the 200 MW(th) HTR

  18. Spatially Resolved MR-Compatible Doppler Ultrasound: Proof of Concept for Triggering of Diagnostic Quality Cardiovascular MRI for Function and Flow Quantification at 3T.

    Science.gov (United States)

    Crowe, Lindsey Alexandra; Manasseh, Gibran; Chmielewski, Aneta; Hachulla, Anne-Lise; Speicher, Daniel; Greiser, Andreas; Muller, Hajo; de Perrot, Thomas; Vallee, Jean-Paul; Salomir, Rares

    2018-02-01

    We demonstrate the use of a magnetic-resonance (MR)-compatible ultrasound (US) imaging probe using spatially resolved Doppler for diagnostic quality cardiovascular MR imaging (MRI) as an initial step toward hybrid US/MR fetal imaging. A newly developed technology for a dedicated MR-compatible phased array ultrasound-imaging probe acquired pulsed color Doppler carotid images, which were converted in near-real time to a trigger signal for cardiac cine and flow quantification MRI. Ultrasound and MR data acquired simultaneously were interference free. Conventional electrocardiogram (ECG) and the proposed spatially resolved Doppler triggering were compared in 10 healthy volunteers. A synthetic "false-triggered" image was retrospectively processed using metric optimized gating (MOG). Images were scored by expert readers, and sharpness, cardiac function and aortic flow were quantified. Four-dimensional (4-D) flow (two volunteers) showed feasibility of Doppler triggering over a long acquisition time. Imaging modalities were compatible. US probe positioning was stable and comfortable. Image quality scores and quantified sharpness were statistically equal for Doppler- and ECG-triggering (p ). ECG-, Doppler-triggered, and MOG ejection fractions were equivalent (p ), with false-triggered values significantly lower (p 0.05). 4-D flow quantification gave consistent results between ECG and Doppler triggering. We report interference-free pulsed color Doppler ultrasound during MR data acquisition. Cardiovascular MRI of diagnostic quality was successfully obtained with pulsed color Doppler triggering. The hardware platform could further enable advanced free-breathing cardiac imaging. Doppler ultrasound triggering is applicable where ECG is compromised due to pathology or interference at higher magnetic fields, and where direct ECG is impossible, i.e., fetal imaging.

  19. Spectrally resolved hyperfine interactions between polaron and nuclear spins in organic light emitting diodes: Magneto-electroluminescence studies

    Energy Technology Data Exchange (ETDEWEB)

    Crooker, S. A.; Kelley, M. R.; Martinez, N. J. D.; Nie, W.; Mohite, A.; Nayyar, I. H.; Tretiak, S.; Smith, D. L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Liu, F.; Ruden, P. P. [University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2014-10-13

    We use spectrally resolved magneto-electroluminescence (EL) measurements to study the energy dependence of hyperfine interactions between polaron and nuclear spins in organic light-emitting diodes. Using layered devices that generate bright exciplex emission, we show that the increase in EL emission intensity I due to small applied magnetic fields of order 100 mT is markedly larger at the high-energy blue end of the EL spectrum (ΔI/I ∼ 11%) than at the low-energy red end (∼4%). Concurrently, the widths of the magneto-EL curves increase monotonically from blue to red, revealing an increasing hyperfine coupling between polarons and nuclei and directly providing insight into the energy-dependent spatial extent and localization of polarons.

  20. Exploratory study on a statistical method to analyse time resolved data obtained during nanomaterial exposure measurements

    International Nuclear Information System (INIS)

    Clerc, F; Njiki-Menga, G-H; Witschger, O

    2013-01-01

    Most of the measurement strategies that are suggested at the international level to assess workplace exposure to nanomaterials rely on devices measuring, in real time, airborne particles concentrations (according different metrics). Since none of the instruments to measure aerosols can distinguish a particle of interest to the background aerosol, the statistical analysis of time resolved data requires special attention. So far, very few approaches have been used for statistical analysis in the literature. This ranges from simple qualitative analysis of graphs to the implementation of more complex statistical models. To date, there is still no consensus on a particular approach and the current period is always looking for an appropriate and robust method. In this context, this exploratory study investigates a statistical method to analyse time resolved data based on a Bayesian probabilistic approach. To investigate and illustrate the use of the this statistical method, particle number concentration data from a workplace study that investigated the potential for exposure via inhalation from cleanout operations by sandpapering of a reactor producing nanocomposite thin films have been used. In this workplace study, the background issue has been addressed through the near-field and far-field approaches and several size integrated and time resolved devices have been used. The analysis of the results presented here focuses only on data obtained with two handheld condensation particle counters. While one was measuring at the source of the released particles, the other one was measuring in parallel far-field. The Bayesian probabilistic approach allows a probabilistic modelling of data series, and the observed task is modelled in the form of probability distributions. The probability distributions issuing from time resolved data obtained at the source can be compared with the probability distributions issuing from the time resolved data obtained far-field, leading in a

  1. A monolithic microsphere-fiber probe for spatially resolved Raman spectroscopy: Application to head and neck squamous cell carcinomas

    Science.gov (United States)

    Holler, S.; Haig, B.; Donovan, M. J.; Sobrero, M.; Miles, B. A.

    2018-03-01

    The ability to identify precise cancer margins in vivo during a surgical excision is critical to the well-being of the patient. Decreased operative time has been linked to shorter patient recovery time, and there are risks associated with removing either too much or too little tissue from the surgical site. The more rapidly and accurately a surgeon can identify and excise diseased tissue, the better the prognosis for the patient. To this end, we investigate both malignant and healthy oral cavity tissue using the Raman spectroscopy, with a monolithic microsphere-fiber probe. Our results indicate that this probe has decreased the size of the analyzed area by more than an order of magnitude, as compared to a conventional fiber reflection probe. Scanning the probe across the tissues reveals variations in the Raman spectra that enable us to differentiate between malignant and healthy tissues. Consequently, we anticipate that the high spatial resolution afforded by the probe will permit us to identify tumor margins in detail, thereby optimizing tissue removal and improving patient outcomes.

  2. Undergraduate ALFALFA Team: Analysis of Spatially-Resolved Star-Formation in Nearby Galaxy Groups and Clusters

    Science.gov (United States)

    Finn, Rose; Collova, Natasha; Spicer, Sandy; Whalen, Kelly; Koopmann, Rebecca A.; Durbala, Adriana; Haynes, Martha P.; Undergraduate ALFALFA Team

    2017-01-01

    As part of the Undergraduate ALFALFA Team, we are conducting a survey of the gas and star-formation properties of galaxies in 36 groups and clusters in the local universe. The galaxies in our sample span a large range of galactic environments, from the centers of galaxy groups and clusters to the surrounding infall regions. One goal of the project is to map the spatial distribution of star-formation; the relative extent of the star-forming and stellar disks provides important information about the internal and external processes that deplete gas and thus drive galaxy evolution. We obtained wide-field H-alpha observations with the WIYN 0.9m telescope at Kitt Peak National Observatory for galaxies in the vicinity of the MKW11 and NRGb004 galaxy groups and the Abell 1367 cluster. We present a preliminary analysis of the relative size of the star-forming and stellar disks as a function of galaxy morphology and local galaxy density, and we calculate gas depletion times using star-formation rates and HI gas mass. We will combine these results with those from other UAT members to determine if and how environmentally-driven gas depletion varies with the mass and X-ray properties of the host group or cluster. This work has supported by NSF grants AST-0847430, AST-1211005 and AST-1637339.

  3. Evaluating scintillator performance in time-resolved hard X-ray studies at synchrotron light sources

    International Nuclear Information System (INIS)

    Rutherford, Michael E.; Chapman, David J.; White, Thomas G.; Drakopoulos, Michael; Rack, Alexander; Eakins, Daniel E.

    2016-01-01

    Scintillator performance in time-resolved, hard, indirect detection X-ray studies on the sub-microsecond timescale at synchrotron light sources is reviewed, modelled and examined experimentally. LYSO:Ce is found to be the only commercially available crystal suitable for these experiments. The short pulse duration, small effective source size and high flux of synchrotron radiation is ideally suited for probing a wide range of transient deformation processes in materials under extreme conditions. In this paper, the challenges of high-resolution time-resolved indirect X-ray detection are reviewed in the context of dynamic synchrotron experiments. In particular, the discussion is targeted at two-dimensional integrating detector methods, such as those focused on dynamic radiography and diffraction experiments. The response of a scintillator to periodic synchrotron X-ray excitation is modelled and validated against experimental data collected at the Diamond Light Source (DLS) and European Synchrotron Radiation Facility (ESRF). An upper bound on the dynamic range accessible in a time-resolved experiment for a given bunch separation is calculated for a range of scintillators. New bunch structures are suggested for DLS and ESRF using the highest-performing commercially available crystal LYSO:Ce, allowing time-resolved experiments with an interframe time of 189 ns and a maximum dynamic range of 98 (6.6 bits)

  4. Evaluating scintillator performance in time-resolved hard X-ray studies at synchrotron light sources

    Energy Technology Data Exchange (ETDEWEB)

    Rutherford, Michael E.; Chapman, David J.; White, Thomas G. [Imperial College London, London (United Kingdom); Drakopoulos, Michael [Diamond Light Source, I12 Joint Engineering, Environmental, Processing (JEEP) Beamline, Didcot, Oxfordshire (United Kingdom); Rack, Alexander [European Synchrotron Radiation Facility, Grenoble (France); Eakins, Daniel E., E-mail: d.eakins@imperial.ac.uk [Imperial College London, London (United Kingdom)

    2016-03-24

    Scintillator performance in time-resolved, hard, indirect detection X-ray studies on the sub-microsecond timescale at synchrotron light sources is reviewed, modelled and examined experimentally. LYSO:Ce is found to be the only commercially available crystal suitable for these experiments. The short pulse duration, small effective source size and high flux of synchrotron radiation is ideally suited for probing a wide range of transient deformation processes in materials under extreme conditions. In this paper, the challenges of high-resolution time-resolved indirect X-ray detection are reviewed in the context of dynamic synchrotron experiments. In particular, the discussion is targeted at two-dimensional integrating detector methods, such as those focused on dynamic radiography and diffraction experiments. The response of a scintillator to periodic synchrotron X-ray excitation is modelled and validated against experimental data collected at the Diamond Light Source (DLS) and European Synchrotron Radiation Facility (ESRF). An upper bound on the dynamic range accessible in a time-resolved experiment for a given bunch separation is calculated for a range of scintillators. New bunch structures are suggested for DLS and ESRF using the highest-performing commercially available crystal LYSO:Ce, allowing time-resolved experiments with an interframe time of 189 ns and a maximum dynamic range of 98 (6.6 bits)

  5. Time-resolved resonance fluorescence spectroscopy for study of chemical reactions in laser-induced plasmas.

    Science.gov (United States)

    Liu, Lei; Deng, Leimin; Fan, Lisha; Huang, Xi; Lu, Yao; Shen, Xiaokang; Jiang, Lan; Silvain, Jean-François; Lu, Yongfeng

    2017-10-30

    Identification of chemical intermediates and study of chemical reaction pathways and mechanisms in laser-induced plasmas are important for laser-ablated applications. Laser-induced breakdown spectroscopy (LIBS), as a promising spectroscopic technique, is efficient for elemental analyses but can only provide limited information about chemical products in laser-induced plasmas. In this work, time-resolved resonance fluorescence spectroscopy was studied as a promising tool for the study of chemical reactions in laser-induced plasmas. Resonance fluorescence excitation of diatomic aluminum monoxide (AlO) and triatomic dialuminum monoxide (Al 2 O) was used to identify these chemical intermediates. Time-resolved fluorescence spectra of AlO and Al 2 O were used to observe the temporal evolution in laser-induced Al plasmas and to study their formation in the Al-O 2 chemistry in air.

  6. Development of Spatial Thinking in Process of Studying Stereometry

    Directory of Open Access Journals (Sweden)

    E I Sanina

    2013-12-01

    Full Text Available The article examines the development of spatial thinking while studying solid geometry. The key note of the study is to examine the selected levels of spatial thinking: the creation and manipulation of spatial images in the course of solving stereometric problems.

  7. Time-resolved X-ray studies using third generation synchrotron radiation sources

    International Nuclear Information System (INIS)

    Mills, D.M.

    1991-10-01

    The third generation, high-brilliance, hard x-ray, synchrotron radiation (SR) sources currently under construction (ESRF at Grenoble, France; APS at Argonne, Illinois; and SPring-8 at Harima, Japan) will usher in a new era of x-ray experimentation for both physical and biological sciences. One of the most exciting areas of experimentation will be the extension of x-ray scattering and diffraction techniques to the study of transient or time-evolving systems. The high repetition rate, short-pulse duration, high brilliance, and variable spectral bandwidth of these sources make them ideal for x-ray time-resolved studies. The temporal properties (bunch length, interpulse period, etc.) of these new sources will be summarized. Finally, the scientific potential and the technological challenges of time-resolved x-ray scattering from these new sources will be described. 13 refs., 4 figs

  8. SPATIALLY RESOLVING THE HK Tau B EDGE-ON DISK FROM 1.2 TO 4.7 μm: A UNIQUE SCATTERED LIGHT DISK

    International Nuclear Information System (INIS)

    McCabe, C.; Duchene, G.; Pinte, C.; Menard, F.; Stapelfeldt, K. R.; Ghez, A. M.

    2011-01-01

    We present spatially resolved scattered light images of the circumstellar disk around HK Tau B at 3.8 and 4.7 μm taken with the Keck Telescope Laser Guide Star Adaptive Optics (AO) system, and 1.6-2.12 μm images taken with the Very Large Telescope/NACO AO system. Combined with previously published optical Hubble Space Telescope data, we investigate the spatially resolved scattered light properties of this edge-on circumstellar disk and probe for the presence of large grains. The 0.6-3.8 μm scattered light observations reveal strong, and in some cases, unusual, wavelength dependencies in the observed disk morphology. The separation between the two scattered light nebulae, which is directly proportional to the disk-mass-opacity product, decreases by 30% between 0.6 and 3.8 μm. Over the same wavelength range, the FWHM of the disk nebulosity declines by a factor of two, while the flux ratio between the two nebulae increases by a factor of ∼8. No other disk known to date shows a flux ratio that increases with wavelength. Both the FWHM and nebula flux ratio are affected by the scattering phase function and the observed behavior can most readily be explained by a phase function that becomes more forward throwing with wavelength. The multi-wavelength scattered light observations also confirm the asymmetric nature of the disk and show that the level of asymmetry is a function of wavelength. We use the MCFOST radiative transfer code to model the disk at four wavelengths, corresponding to the I, H, Ks, and L' bandpasses. A single power-law grain size distribution can recreate the observed disk properties simultaneously at all four wavelengths. Bayesian analysis of the dust parameters finds a 99% probability that the maximum grain size is 5.5 μm or larger. We also find that the grain size distribution is steep, with a 99% probability of a power-law index of 4.2 or larger, suggesting that these large grains are a small fraction of the overall dust population. The best

  9. Resolving Visual Interference During Covert Spatial Orienting: Online Attentional Control Through Static Records of Prior Visual Experience

    Science.gov (United States)

    Awh, Edward; Sgarlata, Antoinette Marie; Kliestik, John

    2005-01-01

    Models of attentional control usually describe online shifts in control settings that accommodate changing task demands. The current studies suggest that online control over distractor exclusion--a core component of visual selection--can be accomplished without online shifts in top-down settings. Measurements of target discrimination accuracy…

  10. Measurement of fluorophore concentrations and fluorescence quantum yield in tissue-simulating phantoms using three diffusion models of steady-state spatially resolved fluorescence

    Energy Technology Data Exchange (ETDEWEB)

    Diamond, Kevin R; Farrell, Thomas J; Patterson, Michael S [Department of Medical Physics, Juravinski Cancer Centre and McMaster University, 699 Concession Street, Hamilton, Ontario L8V 5C2 (Canada)

    2003-12-21

    Steady-state diffusion theory models of fluorescence in tissue have been investigated for recovering fluorophore concentrations and fluorescence quantum yield. Spatially resolved fluorescence, excitation and emission reflectance were calculated by diffusion theory and Monte Carlo simulations, and measured using a multi-fibre probe on tissue-simulating phantoms containing either aluminium phthalocyanine tetrasulfonate (AlPcS{sub 4}), Photofrin or meso-tetra-(4-sulfonatophenyl)-porphine dihydrochloride (TPPS{sub 4}). The accuracy of the fluorophore concentration and fluorescence quantum yield recovered by three different models of spatially resolved fluorescence were compared. The models were based on: (a) weighted difference of the excitation and emission reflectance, (b) fluorescence due to a point excitation source or (c) fluorescence due to a pencil beam excitation source. When literature values for the fluorescence quantum yield were used for each of the fluorophores, the fluorophore absorption coefficient (and hence concentration) at the excitation wavelengthwas recovered with a root-mean-square accuracy of 11.4% using the point source model of fluorescence and 8.0% using the more complicated pencil beam excitation model. The accuracy was calculated over a broad range of optical properties and fluorophore concentrations. The weighted difference of reflectance model performed poorly, with a root-mean-square error in concentration of about 50%. Monte Carlo simulations suggest that there are some situations where the weighted difference of reflectance is as accurate as the other two models, although this was not confirmed experimentally. Estimates of the fluorescence quantum yield in multiple scattering media were also made by determining independently from the fitted absorption spectrum and applying the various diffusion theory models. The fluorescence quantum yields for AlPcS{sub 4} and TPPS{sub 4} were calculated to be 0.59 {+-} 0.03 and 0.121 {+-} 0

  11. Measurement of fluorophore concentrations and fluorescence quantum yield in tissue-simulating phantoms using three diffusion models of steady-state spatially resolved fluorescence

    International Nuclear Information System (INIS)

    Diamond, Kevin R; Farrell, Thomas J; Patterson, Michael S

    2003-01-01

    Steady-state diffusion theory models of fluorescence in tissue have been investigated for recovering fluorophore concentrations and fluorescence quantum yield. Spatially resolved fluorescence, excitation and emission reflectance were calculated by diffusion theory and Monte Carlo simulations, and measured using a multi-fibre probe on tissue-simulating phantoms containing either aluminium phthalocyanine tetrasulfonate (AlPcS 4 ), Photofrin or meso-tetra-(4-sulfonatophenyl)-porphine dihydrochloride (TPPS 4 ). The accuracy of the fluorophore concentration and fluorescence quantum yield recovered by three different models of spatially resolved fluorescence were compared. The models were based on: (a) weighted difference of the excitation and emission reflectance, (b) fluorescence due to a point excitation source or (c) fluorescence due to a pencil beam excitation source. When literature values for the fluorescence quantum yield were used for each of the fluorophores, the fluorophore absorption coefficient (and hence concentration) at the excitation wavelengthwas recovered with a root-mean-square accuracy of 11.4% using the point source model of fluorescence and 8.0% using the more complicated pencil beam excitation model. The accuracy was calculated over a broad range of optical properties and fluorophore concentrations. The weighted difference of reflectance model performed poorly, with a root-mean-square error in concentration of about 50%. Monte Carlo simulations suggest that there are some situations where the weighted difference of reflectance is as accurate as the other two models, although this was not confirmed experimentally. Estimates of the fluorescence quantum yield in multiple scattering media were also made by determining independently from the fitted absorption spectrum and applying the various diffusion theory models. The fluorescence quantum yields for AlPcS 4 and TPPS 4 were calculated to be 0.59 ± 0.03 and 0.121 ± 0.001 respectively using the point

  12. Spatially resolved synchrotron-induced X-ray fluorescence analyses of metal point drawings and their mysterious inscriptions

    International Nuclear Information System (INIS)

    Reiche, Ina; Radtke, Martin; Berger, Achim; Goerner, Wolf; Ketelsen, Thomas; Merchel, Silke; Riederer, Josef; Riesemeier, Heinrich; Roth, Michael

    2004-01-01

    Synchrotron-induced X-ray fluorescence (Sy-XRF) analysis was used to study the chemical composition of precious Renaissance silverpoint drawings. Drawings by famous artists such as Albrecht Duerer (1471-1528) and Jan van Eyck (approximately 1395-1441) must be investigated non-destructively. Moreover, extremely sensitive synchrotron- or accelerator-based techniques are needed since only small quantities of silver are deposited on the paper. New criteria for attributing these works to a particular artist could be established based on the analysis of the chemical composition of the metal points used. We illustrate how analysis can give new art historical information by means of two case studies. Two particular drawings, one of Albrecht Duerer, showing a profile portrait of his closest friend, 'Willibald Pirckheimer' (1503), and a second one attributed to Jan van Eyck, showing a 'Portrait of an elderly man', often named 'Niccolo Albergati', are the object of intense art historical controversy. Both drawings show inscriptions next to the figures. Analyses by Sy-XRF could reveal the same kind of silverpoint for the Pirckheimer portrait and its mysterious Greek inscription, contrary to the drawing by Van Eyck where at least three different metal points were applied. Two different types of silver marks were found in this portrait. Silver containing gold marks were detected in the inscriptions and over-subscriptions. This is the first evidence of the use of gold points for metal point drawings in the Middle Ages

  13. Spin-resolved magnetic studies of focused ion beam etched nano-sized magnetic structures

    International Nuclear Information System (INIS)

    Li Jian; Rau, Carl

    2005-01-01

    Scanning ion microscopy with polarization analysis (SIMPA) is used to study the spin-resolved surface magnetic structure of nano-sized magnetic systems. SIMPA is utilized for in situ topographic and spin-resolved magnetic domain imaging as well as for focused ion beam (FIB) etching of desired structures in magnetic or non-magnetic systems. Ultra-thin Co films are deposited on surfaces of Si(1 0 0) substrates, and ultra-thin, tri-layered, bct Fe(1 0 0)/Mn/bct Fe(1 0 0) wedged magnetic structures are deposited on fcc Pd(1 0 0) substrates. SIMPA experiments clearly show that ion-induced electrons emitted from magnetic surfaces exhibit non-zero electron spin polarization (ESP), whereas electrons emitted from non-magnetic surfaces such as Si and Pd exhibit zero ESP, which can be used to calibrate sputtering rates in situ. We report on new, spin-resolved magnetic microstructures, such as magnetic 'C' states and magnetic vortices, found at surfaces of FIB patterned magnetic elements. It is found that FIB milling has a negligible effect on surface magnetic domain and domain wall structures. It is demonstrated that SIMPA can evolve into an important and efficient tool to study magnetic domain, domain wall and other structures as well as to perform magnetic depth profiling of magnetic nano-systems to be used in ultra-high density magnetic recording and in magnetic sensors

  14. Spectrally and spatially resolved photoluminescence. Lateral fluctuations and depth profiles of Cu(In,Ga)Se2-absorbers

    International Nuclear Information System (INIS)

    Neumann, Oliver

    2013-01-01

    The aim of this thesis is the development and refinement of photoluminescence (PL) methods for inhomogeneous absorbers to identify lateral fluctuations and depth-dependent variations of spectroscopic, optical and opto-electronic properties in the submicron/micron range. The first approach deals with the spectral investigation of PL emission from the front and the rear side of an absorber, whereas the second idea is about the analysis of PL spectra from the front side of the absorber for different absorber thicknesses. Another technique for determination of depth-dependent variations are confocal PL measurements at cross sections of absorbers. The last concept pursues the study of lateral fluctuations with an optical near-field microscope on specially prepared absorbers. These four strategies are demonstrated with samples based on Cu(In,Ga)Se 2 .

  15. Constructing a Spatially Resolved Methane Emission Inventory of Natural Gas Production and Distribution over Contiguous United States

    Science.gov (United States)

    Li, X.; Omara, M.; Adams, P. J.; Presto, A. A.

    2017-12-01

    Methane is the second most powerful greenhouse gas after Carbon Dioxide. The natural gas production and distribution accounts for 23% of the total anthropogenic methane emissions in the United States. The boost of natural gas production in U.S. in recent years poses a potential concern of increased methane emissions from natural gas production and distribution. The Emission Database for Global Atmospheric Research (Edgar) v4.2 and the EPA Greenhouse Gas Inventory (GHGI) are currently the most commonly used methane emission inventories. However, recent studies suggested that both Edgar v4.2 and the EPA GHGI largely underestimated the methane emission from natural gas production and distribution in U.S. constrained by both ground and satellite measurements. In this work, we built a gridded (0.1° Latitude ×0.1° Longitude) methane emission inventory of natural gas production and distribution over the contiguous U.S. using emission factors measured by our mobile lab in the Marcellus Shale, the Denver-Julesburg Basin, and the Uintah Basin, and emission factors reported from other recent field studies for other natural gas production regions. The activity data (well location and count) are mostly obtained from the Drillinginfo, the EPA Greenhouse Gas Reporting Program (GHGRP) and the U.S. Energy Information Administration (EIA). Results show that the methane emission from natural gas production and distribution estimated by our inventory is about 20% higher than the EPA GHGI, and in some major natural gas production regions, methane emissions estimated by the EPA GHGI are significantly lower than our inventory. For example, in the Marcellus Shale, our estimated annual methane emission in 2015 is 600 Gg higher than the EPA GHGI. We also ran the GEOS-Chem methane simulation to estimate the methane concentration in the atmosphere with our built inventory, the EPA GHGI and the Edgar v4.2 over the nested North American Domain. These simulation results showed differences in

  16. Spatially and spectrally resolved filamentary structures in the (3/2)omega 0 emission from laser produced plasmas

    International Nuclear Information System (INIS)

    Lin, Z.; Willi, O.; Rumsby, P.T.

    This study was conducted to explore the problem of filamentation of laser light in the underdense plasma corona surrounding ablatively imploded spherical targets, a phenomenon which may prevent the realization of laser-driven fusion schemes. Preliminary observations were made of filamentary structures in the (3/2)(omega sub o) emission from microballoon targets irradiated in the ablative mode. Time integrated spectroscopy showed double and single peaked (3/2)(omega sub o) emission spectra. A simple model for the growth and collapse of filaments was based on the movement of the density contours at the bottom of the filament with large velocity. Here the laser intensity was high and various decay instabilities and scattering processes took place. In particular the two plasmon decay instability occurred where the electron density was nc/4, a region of (3/2)(omega sub o) emission. The model was consistent with the experimentally observed spectra and predicted the type of omega sub o and 2 omega sub o that should be observed in future experiments

  17. Spatially resolved band alignments at Au-hexadecanethiol monolayer-GaAs(001) interfaces by ballistic electron emission microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Junay, A.; Guézo, S., E-mail: sophie.guezo@univ-rennes1.fr; Turban, P.; Delhaye, G.; Lépine, B.; Tricot, S.; Ababou-Girard, S.; Solal, F. [Département Matériaux-Nanosciences, Institut de Physique de Rennes, UMR 6251, CNRS-Université de Rennes 1, Campus de Beaulieu, Bât 11E, 35042 Rennes Cedex (France)

    2015-08-28

    We study structural and electronic inhomogeneities in Metal—Organic Molecular monoLayer (OML)—semiconductor interfaces at the sub-nanometer scale by means of in situ Ballistic Electron Emission Microscopy (BEEM). BEEM imaging of Au/1-hexadecanethiols/GaAs(001) heterostructures reveals the evolution of pinholes density as a function of the thickness of the metallic top-contact. Using BEEM in spectroscopic mode in non-short-circuited areas, local electronic fingerprints (barrier height values and corresponding spectral weights) reveal a low-energy tunneling regime through the insulating organic monolayer. At higher energies, BEEM evidences new conduction channels, associated with hot-electron injection in the empty molecular orbitals of the OML. Corresponding band diagrams at buried interfaces can be thus locally described. The energy position of GaAs conduction band minimum in the heterostructure is observed to evolve as a function of the thickness of the deposited metal, and coherently with size-dependent electrostatic effects under the molecular patches. Such BEEM analysis provides a quantitative diagnosis on metallic top-contact formation on organic molecular monolayer and appears as a relevant characterization for its optimization.

  18. Can a one-layer optical skin model including melanin and inhomogeneously distributed blood explain spatially resolved diffuse reflectance spectra?

    Science.gov (United States)

    Karlsson, Hanna; Pettersson, Anders; Larsson, Marcus; Strömberg, Tomas

    2011-02-01

    Model based analysis of calibrated diffuse reflectance spectroscopy can be used for determining oxygenation and concentration of skin chromophores. This study aimed at assessing the effect of including melanin in addition to hemoglobin (Hb) as chromophores and compensating for inhomogeneously distributed blood (vessel packaging), in a single-layer skin model. Spectra from four humans were collected during different provocations using a twochannel fiber optic probe with source-detector separations 0.4 and 1.2 mm. Absolute calibrated spectra using data from either a single distance or both distances were analyzed using inverse Monte Carlo for light transport and Levenberg-Marquardt for non-linear fitting. The model fitting was excellent using a single distance. However, the estimated model failed to explain spectra from the other distance. The two-distance model did not fit the data well at either distance. Model fitting was significantly improved including melanin and vessel packaging. The most prominent effect when fitting data from the larger separation compared to the smaller separation was a different light scattering decay with wavelength, while the tissue fraction of Hb and saturation were similar. For modeling spectra at both distances, we propose using either a multi-layer skin model or a more advanced model for the scattering phase function.

  19. Resolving uncertainty in the spatial relationships between passive benzene exposure and risk of non-Hodgkin lymphoma.

    Science.gov (United States)

    Switchenko, Jeffrey M; Bulka, Catherine; Ward, Kevin; Koff, Jean L; Bayakly, A Rana; Ryan, P Barry; Waller, Lance A; Flowers, Christopher R

    2016-04-01

    Benzene is a known occupational carcinogen associated with increased risk of hematologic cancers, but the relationships between quantity of passive benzene exposure through residential proximity to toxic release sites, duration of exposure, lag time from exposure to cancer development, and lymphoma risk remain unclear. We collected release data through the Environmental Protection Agency's Toxics Release Inventory (TRI) from 1989 to 2003, which included location of benzene release sites, years when release occurred, and amount of release. We also collected data on incident cases of non-Hodgkin lymphoma (NHL) from the Georgia Comprehensive Cancer Registry (GCCR) for the years 1999-2008. We constructed distance-decay surrogate exposure metrics and Poisson and negative binomial regression models of NHL incidence to quantify associations between passive exposure to benzene and NHL risk and examined the impact of amount, duration of exposure, and lag time on cancer development. Akaike's information criteria (AIC) were used to determine the scaling factors for benzene dispersion and exposure periods that best predicted NHL risk. Using a range of scaling factors and exposure periods, we found that increased levels of passive benzene exposure were associated with higher risk of NHL. The best fitting model, with a scaling factor of 4 kilometers (km) and exposure period of 1989-1993, showed that higher exposure levels were associated with increased NHL risk (Level 4 (1.1-160kilograms (kg)) vs. Level 1: risk ratio 1.56 [1.44-1.68], Level 5 (>160kg) vs. Level 1: 1.60 [1.48-1.74]). Higher levels of passive benzene exposure are associated with increased NHL risk across various lag periods. Additional epidemiological studies are needed to refine these models and better quantify the expected total passive benzene exposure in areas surrounding release sites. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  20. On the Spatially Resolved Star Formation History in M51. II. X-Ray Binary Population Evolution

    Science.gov (United States)

    Lehmer, B. D.; Eufrasio, R. T.; Markwardt, L.; Zezas, A.; Basu-Zych, A.; Fragos, T.; Hornschemeier, A. E.; Ptak, A.; Tzanavaris, P.; Yukita, M.

    2017-12-01

    We present a new technique for empirically calibrating how the X-ray luminosity function (XLF) of X-ray binary (XRB) populations evolves following a star formation event. We first utilize detailed stellar population synthesis modeling of far-UV-to-far-IR photometry of the nearby face-on spiral galaxy M51 to construct maps of the star formation histories (SFHs) on subgalactic (≈400 pc) scales. Next, we use the ≈850 ks cumulative Chandra exposure of M51 to identify and isolate 2-7 keV detected point sources within the galaxy, and we use our SFH maps to recover the local properties of the stellar populations in which each X-ray source is located. We then divide the galaxy into various subregions based on their SFH properties (e.g., star formation rate (SFR) per stellar mass ({M}\\star ) and mass-weighted stellar age) and group the X-ray point sources according to the characteristics of the regions in which they are found. Finally, we construct and fit a parameterized XLF model that quantifies how the XLF shape and normalization evolves as a function of the XRB population age Our best-fit model indicates that the XRB XLF per unit stellar mass declines in normalization, by ˜3-3.5 dex, and steepens in slope from ≈10 Myr to ≈10 Gyr. We find that our technique recovers results from past studies of how XRB XLFs and XRB luminosity scaling relations vary with age and provides a self-consistent picture for how XRB XLFs evolve with age.

  1. Highlights of analytical chemistry in Switzerland. Spatially resolved plant physiological analysis using LA-HR-ICP-MS

    Energy Technology Data Exchange (ETDEWEB)

    Ulrich, A. [Swiss Federal Laboratories for Material Testing and Research (EMPA), Duebendorf (Switzerland); Barrelet, T. [Federal Office of Public Health (FOPH), Berne (Switzerland); Kraehenbuehl, U. [University of Berne, Department for Chemistry and Biochemistry, Berne (Switzerland)

    2007-06-15

    Investigations of elemental distribution in trees are interesting in plant physiological and environmental research. Seasonal element variations within single tree rings would provide important information on metabolism studies but they have not been accessible so far. Thus, a direct micro-analytical method involving laser ablation (LA) coupled to high-resolution double-focusing magnetic sector field inductively coupled plasma mass spectrometry (HR-ICP-MS) was developed. Particularly challenging aspects in method development were the high background levels of certain elements and the lack of appropriate calibration standards. Seasonal element profiles of macronutrients in Norway spruce trees from different sampling sites, altitudes and environmental conditions could be established for the first time. The method allows the measurement of low concentrations even in narrow year rings. Depending on the tree ring width, the number of laser spots per ring varied between four and eight. For discussion purposes, each ring was divided in four distinct zones commonly used in dendrology: early earlywood (EEW), late earlywood (LEW), early latewood (ELW) and late latewood (LLW). The sulphur profile displayed seasonal variations with decreasing contents in LEW and ELW, which leads to the assumption that stem sulphur is used for seasonal growth. When accrescence stops in autumn, sulphur reserves are stored in preparation for next year's growth, since methionine in tree sap was found to increase in March until July and decrease in August. A seasonal pattern was also found for phosphorus. This contradicts the hypothesis of a constant supply by mycorrhizal fungi and implies that reserves are stored towards the end of growing season for use the following spring. The linear relationship between phosphorus and sulphur underlines a strong biochemical coupling of both elements. Other macronutrients like potassium show different profiles. Potassium is of particular importance in

  2. Highlights of analytical chemistry in Switzerland. Spatially resolved plant physiological analysis using LA-HR-ICP-MS

    International Nuclear Information System (INIS)

    Ulrich, A.; Barrelet, T.; Kraehenbuehl, U.

    2007-01-01

    Investigations of elemental distribution in trees are interesting in plant physiological and environmental research. Seasonal element variations within single tree rings would provide important information on metabolism studies but they have not been accessible so far. Thus, a direct micro-analytical method involving laser ablation (LA) coupled to high-resolution double-focusing magnetic sector field inductively coupled plasma mass spectrometry (HR-ICP-MS) was developed. Particularly challenging aspects in method development were the high background levels of certain elements and the lack of appropriate calibration standards. Seasonal element profiles of macronutrients in Norway spruce trees from different sampling sites, altitudes and environmental conditions could be established for the first time. The method allows the measurement of low concentrations even in narrow year rings. Depending on the tree ring width, the number of laser spots per ring varied between four and eight. For discussion purposes, each ring was divided in four distinct zones commonly used in dendrology: early earlywood (EEW), late earlywood (LEW), early latewood (ELW) and late latewood (LLW). The sulphur profile displayed seasonal variations with decreasing contents in LEW and ELW, which leads to the assumption that stem sulphur is used for seasonal growth. When accrescence stops in autumn, sulphur reserves are stored in preparation for next year's growth, since methionine in tree sap was found to increase in March until July and decrease in August. A seasonal pattern was also found for phosphorus. This contradicts the hypothesis of a constant supply by mycorrhizal fungi and implies that reserves are stored towards the end of growing season for use the following spring. The linear relationship between phosphorus and sulphur underlines a strong biochemical coupling of both elements. Other macronutrients like potassium show different profiles. Potassium is of particular importance in needles

  3. Spatially-Resolved Influence of Temperature and Salinity on Stock and Recruitment Variability of Commercially Important Fishes in the North Sea.

    Directory of Open Access Journals (Sweden)

    Anna Akimova

    Full Text Available Understanding of the processes affecting recruitment of commercially important fish species is one of the major challenges in fisheries science. Towards this aim, we investigated the relation between North Sea hydrography (temperature and salinity and fish stock variables (recruitment, spawning stock biomass and pre-recruitment survival index for 9 commercially important fishes using spatially-resolved cross-correlation analysis. We used high-resolution (0.2° × 0.2° hydrographic data fields matching the maximal temporal extent of the fish population assessments (1948-2013. Our approach allowed for the identification of regions in the North Sea where environmental variables seem to be more influential on the fish stocks, as well as the regions of a lesser or nil influence. Our results confirmed previously demonstrated negative correlations between temperature and recruitment of cod and plaice and identified regions of the strongest correlations (German Bight for plaice and north-western North Sea for cod. We also revealed a positive correlation between herring spawning stock biomass and temperature in the Orkney-Shetland area, as well as a negative correlation between sole pre-recruitment survival index and temperature in the German Bight. A strong positive correlation between sprat stock variables and salinity in the central North Sea was also found. To our knowledge the results concerning correlations between North Sea hydrography and stocks' dynamics of herring, sole and sprat are novel. The new information about spatial distribution of the correlation provides an additional help to identify mechanisms underlying these correlations. As an illustration of the utility of these results for fishery management, an example is provided that incorporates the identified environmental covariates in stock-recruitment models.

  4. Fast and Furious: Shock heated gas as the origin of spatially resolved hard X-ray emission in the central 5 kpc of the galaxy merger NGC 6240

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Junfeng; Nardini, Emanuele; Fabbiano, Giuseppina; Karovska, Margarita; Elvis, Martin; Risaliti, Guido; Zezas, Andreas [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Pellegrini, Silvia [Dipartimento di Astronomia, Universitá di Bologna, Via Ranzani 1, I-40127 Bologna (Italy); Max, Claire [Center for Adaptive Optics, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); U, Vivian, E-mail: jfwang@northwestern.edu [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States)

    2014-01-20

    We have obtained a deep, subarcsecond resolution X-ray image of the nuclear region of the luminous galaxy merger NGC 6240 with Chandra, which resolves the X-ray emission from the pair of active nuclei and the diffuse hot gas in great detail. We detect extended hard X-ray emission from kT ∼ 6 keV (∼70 MK) hot gas over a spatial scale of 5 kpc, indicating the presence of fast shocks with a velocity of ∼2200 km s{sup –1}. For the first time, we obtain the spatial distribution of this highly ionized gas emitting Fe XXV, which shows a remarkable correspondence to the large-scale morphology of H{sub 2}(1-0) S(1) line emission and Hα filaments. Propagation of fast shocks originating in the starburst-driven wind into the ambient dense gas can account for this morphological correspondence. With an observed L {sub 0.5-8} {sub keV} = 5.3 × 10{sup 41} erg s{sup –1}, the diffuse hard X-ray emission is ∼100 times more luminous than that observed in the classic starburst galaxy M82. Assuming a filling factor of 1% for the 70 MK temperature gas, we estimate its total mass (M {sub hot} = 1.8 × 10{sup 8} M {sub ☉}) and thermal energy (E {sub th} = 6.5 × 10{sup 57} erg). The total iron mass in the highly ionized plasma is M {sub Fe} = 4.6 × 10{sup 5} M {sub ☉}. Both the energetics and the iron mass in the hot gas are consistent with the expected injection from the supernovae explosion during the starburst that is commensurate with its high star formation rate. No evidence for fluorescent Fe I emission is found in the CO filament connecting the two nuclei.

  5. Fast and Furious: Shock Heated Gas as the Origin of Spatially Resolved Hard X-Ray Emission in the Central 5 kpc of the Galaxy Merger NGC 6240

    Science.gov (United States)

    Wang, Junfeng; Nardini, Emanuele; Fabbiano, Giuseppina; Karovska, Margarita; Elvis, Martin; Pellegrini, Silvia; Max, Claire; Risaliti, Guido; U, Vivian; Zezas, Andreas

    2014-01-01

    We have obtained a deep, subarcsecond resolution X-ray image of the nuclear region of the luminous galaxy merger NGC 6240 with Chandra, which resolves the X-ray emission from the pair of active nuclei and the diffuse hot gas in great detail. We detect extended hard X-ray emission from kT ~ 6 keV (~70 MK) hot gas over a spatial scale of 5 kpc, indicating the presence of fast shocks with a velocity of ~2200 km s-1. For the first time, we obtain the spatial distribution of this highly ionized gas emitting Fe XXV, which shows a remarkable correspondence to the large-scale morphology of H2(1-0) S(1) line emission and Hα filaments. Propagation of fast shocks originating in the starburst-driven wind into the ambient dense gas can account for this morphological correspondence. With an observed L 0.5-8 keV = 5.3 × 1041 erg s-1, the diffuse hard X-ray emission is ~100 times more luminous than that observed in the classic starburst galaxy M82. Assuming a filling factor of 1% for the 70 MK temperature gas, we estimate its total mass (M hot = 1.8 × 108 M ⊙) and thermal energy (E th = 6.5 × 1057 erg). The total iron mass in the highly ionized plasma is M Fe = 4.6 × 105 M ⊙. Both the energetics and the iron mass in the hot gas are consistent with the expected injection from the supernovae explosion during the starburst that is commensurate with its high star formation rate. No evidence for fluorescent Fe I emission is found in the CO filament connecting the two nuclei.

  6. Fast and Furious: Shock heated gas as the origin of spatially resolved hard X-ray emission in the central 5 kpc of the galaxy merger NGC 6240

    International Nuclear Information System (INIS)

    Wang, Junfeng; Nardini, Emanuele; Fabbiano, Giuseppina; Karovska, Margarita; Elvis, Martin; Risaliti, Guido; Zezas, Andreas; Pellegrini, Silvia; Max, Claire; U, Vivian

    2014-01-01

    We have obtained a deep, subarcsecond resolution X-ray image of the nuclear region of the luminous galaxy merger NGC 6240 with Chandra, which resolves the X-ray emission from the pair of active nuclei and the diffuse hot gas in great detail. We detect extended hard X-ray emission from kT ∼ 6 keV (∼70 MK) hot gas over a spatial scale of 5 kpc, indicating the presence of fast shocks with a velocity of ∼2200 km s –1 . For the first time, we obtain the spatial distribution of this highly ionized gas emitting Fe XXV, which shows a remarkable correspondence to the large-scale morphology of H 2 (1-0) S(1) line emission and Hα filaments. Propagation of fast shocks originating in the starburst-driven wind into the ambient dense gas can account for this morphological correspondence. With an observed L 0.5-8 keV = 5.3 × 10 41 erg s –1 , the diffuse hard X-ray emission is ∼100 times more luminous than that observed in the classic starburst galaxy M82. Assuming a filling factor of 1% for the 70 MK temperature gas, we estimate its total mass (M hot = 1.8 × 10 8 M ☉ ) and thermal energy (E th = 6.5 × 10 57 erg). The total iron mass in the highly ionized plasma is M Fe = 4.6 × 10 5 M ☉ . Both the energetics and the iron mass in the hot gas are consistent with the expected injection from the supernovae explosion during the starburst that is commensurate with its high star formation rate. No evidence for fluorescent Fe I emission is found in the CO filament connecting the two nuclei.

  7. Climate change impact assessment in Veneto and Friuli Plain groundwater. Part II: a spatially resolved regional risk assessment.

    Science.gov (United States)

    Pasini, S; Torresan, S; Rizzi, J; Zabeo, A; Critto, A; Marcomini, A

    2012-12-01

    outcomes from the described RRA application highlighted that potential climate change impacts will occur with different extension and magnitude in the case study area. Particularly, qualitative and quantitative impacts on groundwater will occur with more severe consequences in the wettest and in the driest scenario (respectively). Moreover, such impacts will likely have little direct effects on related ecosystems - croplands, forests and natural environments - lying along the spring area (about 12% of croplands and 2% of natural environments at risk) while more severe consequences will indirectly occur on natural and anthropic systems through the reduction in quality and quantity of water availability for agricultural and other uses (about 80% of agricultural areas and 27% of groundwater bodies at risk). Copyright © 2012 Elsevier B.V. All rights reserved.

  8. Spatially and time-resolved element-specific in situ corrosion investigations with an online hyphenated microcapillary flow injection inductively coupled plasma mass spectrometry set-up

    International Nuclear Information System (INIS)

    Homazava, N.; Ulrich, A.; Kraehenbuehl, U.

    2008-01-01

    A novel technique for in situ spatial, time-resolved element-specific investigations of corrosion processes is developed. The technique is based on an online hyphenation of a specially designed microflow-capillary set-up to inductively coupled plasma mass spectrometry (ICP-MS) using flow injection sample introduction. Detailed aspects of the method development, optimization of the sample microflow introduction and flow injection characteristics for the localized corrosion analysis are described. Moreover, specific challenges of the ICP-MS analysis as applied to the analysis of corrosion sample probes, e.g. high matrix load and limited sample volume, are discussed. The efficiency of the developed technique is proved by corrosion susceptibility analysis of a commercial Al alloy. Results of the corrosion experiments of the aluminum alloy AA 6111 are presented to demonstrate the influence of various factors such as exposure time and pH value of the corrosive medium on the element-specific dissolution rates of the alloy. This novel technique provides new aspects in corrosion science and sheds new light on corrosion mechanisms

  9. The Energy-Water Nexus: Spatially-Resolved Analysis of the Potential for Desalinating Brackish Groundwater by Use of Solar Energy

    Directory of Open Access Journals (Sweden)

    Jill B. Kjellsson

    2015-06-01

    Full Text Available This research looks at coupling desalination with renewable energy sources to create a high-value product (treated water from two low value resources (brackish groundwater and intermittent solar energy. Desalination of brackish groundwater is already being considered as a potential new water supply in Texas. This research uses Texas as a testbed for spatially-resolved analysis techniques while considering depth to brackish groundwater, water quality, and solar radiation across Texas to determine the locations with the best potential for integrating solar energy with brackish groundwater desalination. The framework presented herein can be useful for policymakers, regional planners, and project developers as they consider where to site desalination facilities coupled with solar photovoltaics. Results suggest that the northwestern region of Texas—with abundant sunshine and groundwater at relatively shallow depths and low salinity in areas with freshwater scarcity—has the highest potential for solar powered desalination. The range in capacity for solar photovoltaic powered reverse osmosis desalination was found to be 1.56 × 10—6 to 2.93 × 10—5 cubic meters of water per second per square meter of solar panel (m3/s/m2.

  10. Spatially resolved ozone densities and gas temperatures in a time modulated RF driven atmospheric pressure plasma jet: an analysis of the production and destruction mechanisms

    International Nuclear Information System (INIS)

    Zhang Shiqiang; Van Gessel, Bram; Hofmann, Sven; Van Veldhuizen, Eddie; Bruggeman, Peter; Van Gaens, Wouter; Bogaerts, Annemie

    2013-01-01

    In this work, a time modulated RF driven DBD-like atmospheric pressure plasma jet in Ar + 2%O 2 , operating at a time averaged power of 6.5 W is investigated. Spatially resolved ozone densities and gas temperatures are obtained by UV absorption and Rayleigh scattering, respectively. Significant gas heating in the core of the plasma up to 700 K is found and at the position of this increased gas temperature a depletion of the ozone density is found. The production and destruction reactions of O 3 in the jet effluent as a function of the distance from the nozzle are obtained from a zero-dimensional chemical kinetics model in plug flow mode which considers relevant air chemistry due to air entrainment in the jet fluent. A comparison of the measurements and the models show that the depletion of O 3 in the core of the plasma is mainly caused by an enhanced destruction of O 3 due to a large atomic oxygen density. (paper)

  11. Monitor of spatial plans. Feasibility study

    International Nuclear Information System (INIS)

    Bollen, M.J.S.; Ritsema van Eck, J.; Farjon, J.M.J.

    2008-01-01

    The national government needs assessments of consequences of building projects in relation to spatial policy objectives such as the prevention of urban sprawl or the development of landscape qualities. Normally the effects of spatial policies appear after several years. Spatial plans can possibly indicate these effects earlier. To allow policies to be adapted to unwanted developments, the assessments should be available in the early planning stages of these building projects. The Dutch Minister of VROM has asked the Netherlands Environmental Assessment Agency to investigate the feasibility of a monitoring system based on building plans. As building projects take a long period from conception until realization, a monitoring system for these projects should include all plans for the next ten to fifteen years with an indication of the chance that these plans are realized. The existing databases in the Netherlands provide sufficient information to assess consequences of plans for those objectives that are directly related to the urbanization pattern. However, an improvement of these databases is necessary, amongst other things by coordination of these databases [nl

  12. Studies of combustion reactions at the state-resolved differential cross section level

    Energy Technology Data Exchange (ETDEWEB)

    Houston, P.L.; Suits, A.G.; Bontuyan, L.S.; Whitaker, B.J. [Cornell Univ., Ithaca, NY (United States)

    1993-12-01

    State-resolved differential reaction cross sections provide perhaps the most detailed information about the mechanism of a chemical reaction, but heretofore they have been extremely difficult to measure. This program explores a new technique for obtaining differential cross sections with product state resolution. The three-dimensional velocity distribution of state-selected reaction products is determined by ionizing the appropriate product, waiting for a delay while it recoils along the trajectory imparted by the reaction, and finally projecting the spatial distribution of ions onto a two dimensional screen using a pulsed electric field. Knowledge of the arrival time allows the ion position to be converted to a velocity, and the density of velocity projections can be inverted mathematically to provide the three-dimensional velocity distribution for the selected product. The main apparatus has been constructed and tested using photodissociations. The authors report here the first test results using crossed beams to investigate collisions between Ar and NO. Future research will both develop further the new technique and employ it to investigate methyl radical, formyl radical, and hydrogen atom reactions which are important in combustion processes. The authors intend specifically to characterize the reactions of CH{sub 3} with H{sub 2} and H{sub 2}CO; of HCO with O{sub 2}; and of H with CH{sub 4}, CO{sub 2}, and O{sub 2}.

  13. Hole emission from Ge/Si quantum dots studied by time-resolved capacitance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Kapteyn, C.M.A.; Lion, M.; Heitz, R.; Bimberg, D. [Technische Univ. Berlin (Germany). Inst. fuer Festkoerperphysik; Miesner, C.; Asperger, T.; Brunner, K.; Abstreiter, G. [Technische Univ. Muenchen, Garching (Germany). Walter-Schottky-Inst. fuer Physikalische Grundlagen der Halbleiterelektronik

    2001-03-01

    Emission of holes from self-organized Ge quantum dots (QDs) embedded in Si Schottky diodes is studied by time-resolved capacitance spectroscopy (DLTS). The DLTS signal is rather broad and depends strongly on the filling and detection bias conditions. The observed dependence is interpreted in terms of carrier emission from many-hole states of the QDs. The activation energies obtained from the DLTS measurements are a function of the amount of stored charge and the position of the Fermi level in the QDs. (orig.)

  14. Flame propagation in two-dimensional solids: Particle-resolved studies with complex plasmas

    Science.gov (United States)

    Yurchenko, S. O.; Yakovlev, E. V.; Couëdel, L.; Kryuchkov, N. P.; Lipaev, A. M.; Naumkin, V. N.; Kislov, A. Yu.; Ovcharov, P. V.; Zaytsev, K. I.; Vorob'ev, E. V.; Morfill, G. E.; Ivlev, A. V.

    2017-10-01

    Using two-dimensional (2D) complex plasmas as an experimental model system, particle-resolved studies of flame propagation in classical 2D solids are carried out. Combining experiments, theory, and molecular dynamics simulations, we demonstrate that the mode-coupling instability operating in 2D complex plasmas reveals all essential features of combustion, such as an activated heat release, two-zone structure of the self-similar temperature profile ("flame front"), as well as thermal expansion of the medium and temperature saturation behind the front. The presented results are of relevance for various fields ranging from combustion and thermochemistry, to chemical physics and synthesis of materials.

  15. Unfolding of Ubiquitin Studied by Picosecond Time-Resolved Fluorescence of the Tyrosine Residue

    OpenAIRE

    Noronha, Melinda; Lima, João C.; Bastos, Margarida; Santos, Helena; Maçanita, António L.

    2004-01-01

    The photophysics of the single tyrosine in bovine ubiquitin (UBQ) was studied by picosecond time-resolved fluorescence spectroscopy, as a function of pH and along thermal and chemical unfolding, with the following results: First, at room temperature (25°C) and below pH 1.5, native UBQ shows single-exponential decays. From pH 2 to 7, triple-exponential decays were observed and the three decay times were attributed to the presence of tyrosine, a tyrosine-carboxylate hydrogen-bonded complex, and...

  16. Time-resolved circular dichroism: Application to the study of conformal changes in biomolecules

    Science.gov (United States)

    Hache, F.

    2010-06-01

    Circular dichroism (CD) is known to be a very sensitive probe of the conformation of molecules and biomolecules. It is therefore tempting to implement CD in a pump-probe experiment in order to measure ultrarapid conformational changes which occur in photochemical processes. We present two technical developments of such time-resolved CD experiments. The first one relies on the modulation of the probe polarization from left to right circular whereas the second one measures the pump-induced ellipticity of the probe with a Babinet-Soleil compensator. Some applications are described and extension of these techniques towards the study of elementary protein folding processes is discussed.

  17. Time-resolved circular dichroism: Application to the study of conformal changes in biomolecules

    Directory of Open Access Journals (Sweden)

    Hache F.

    2010-06-01

    Full Text Available Circular dichroism (CD is known to be a very sensitive probe of the conformation of molecules and biomolecules. It is therefore tempting to implement CD in a pump-probe experiment in order to measure ultrarapid conformational changes which occur in photochemical processes. We present two technical developments of such time-resolved CD experiments. The first one relies on the modulation of the probe polarization from left to right circular whereas the second one measures the pump-induced ellipticity of the probe with a Babinet-Soleil compensator. Some applications are described and extension of these techniques towards the study of elementary protein folding processes is discussed.

  18. Time-resolved hard x-ray studies using third-generation synchrotron radiation sources (abstract)

    International Nuclear Information System (INIS)

    Mills, D.M.

    1992-01-01

    The third-generation, high-brilliance, synchrotron radiation sources currently under construction will usher in a new era of x-ray research in the physical, chemical, and biological sciences. One of the most exciting areas of experimentation will be the extension of static x-ray scattering and diffraction techniques to the study of transient or time-evolving systems. The high repetition rate, short-pulse duration, high-brilliance, variable spectral bandwidth, and large particle beam energies of these sources make them ideal for hard x-ray, time-resolved studies. The primary focus of this presentation will be on the novel instrumentation required for time-resolved studies such as optics which can increase the flux on the sample or disperse the x-ray beam, detectors and electronics for parallel data collection, and methods for altering the natural time structure of the radiation. This work is supported by the U.S. Department of Energy, BES-Materials Science, under Contract No. W-31-109-ENG-38

  19. The MASSIVE Survey - V. Spatially resolved stellar angular momentum, velocity dispersion, and higher moments of the 41 most massive local early-type galaxies

    Science.gov (United States)

    Veale, Melanie; Ma, Chung-Pei; Thomas, Jens; Greene, Jenny E.; McConnell, Nicholas J.; Walsh, Jonelle; Ito, Jennifer; Blakeslee, John P.; Janish, Ryan

    2017-01-01

    We present spatially resolved two-dimensional stellar kinematics for the 41 most massive early-type galaxies (ETGs; MK ≲ -25.7 mag, stellar mass M* ≳ 1011.8 M⊙) of the volume-limited (D McDonald Observatory, covering a 107 arcsec × 107 arcsec field of view (often reaching 2 to 3 effective radii). We measure the 2D spatial distribution of each galaxy's angular momentum (λ and fast or slow rotator status), velocity dispersion (σ), and higher order non-Gaussian velocity features (Gauss-Hermite moments h3 to h6). Our sample contains a high fraction (˜80 per cent) of slow and non-rotators with λ ≲ 0.2. When combined with the lower mass ETGs in the ATLAS3D survey, we find the fraction of slow rotators to increase dramatically with galaxy mass, reaching ˜50 per cent at MK ˜ -25.5 mag and ˜90 per cent at MK ≲ -26 mag. All of our fast rotators show a clear anticorrelation between h3 and V/σ, and the slope of the anticorrelation is steeper in more round galaxies. The radial profiles of σ show a clear luminosity and environmental dependence: the 12 most luminous galaxies in our sample (MK ≲ -26 mag) are all brightest cluster/group galaxies (except NGC 4874) and all have rising or nearly flat σ profiles, whereas five of the seven `isolated' galaxies are all fainter than MK = -25.8 mag and have falling σ. All of our galaxies have positive average h4; the most luminous galaxies have average h4 ˜ 0.05, while less luminous galaxies have a range of values between 0 and 0.05. Most of our galaxies show positive radial gradients in h4, and those galaxies also tend to have rising σ profiles. We discuss the implications for the relationship among dynamical mass, σ, h4, and velocity anisotropy for these massive galaxies.

  20. Simultaneous characterization of elemental segregation and cementite networks in high carbon steel products by spatially-resolved laser-induced breakdown spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Boué-Bigne, Fabienne, E-mail: fabienne.boue-bigne@tatasteel.com

    2014-06-01

    The reliable characterization of the level of elemental segregation and of the extent of grain-boundary cementite networks in high carbon steel products is a prerequisite for checking product quality, for the purpose of product release to customers, and to investigate the presence of defects that may have led to mechanical property failure of the product. Current methods for the characterization of segregation and cementite networks rely on two different methods of sample etching followed by visual observation, where quality scores are given based on human perception and judgment. With the continuous demand on increasing quality, some of the conventional characterization methods and their associated scoring boards have lost relevance for the precision of characterization that is required today to distinguish between a product that will perform well and one that will not. In order to move away from a qualitative, human perception based situation for the scoring of the severity of segregation and cementite networks, a new method of data evaluation based on spatially-resolved LIBS measurements was developed to provide quantitative and simultaneous characterization of both types of defects. The quantitative assessment of segregation and cementite networks is based on the acquisition of carbon concentration maps. The ability to produce rapid scanning measurements of micro and macro-scale features with adequate spatial resolution makes LIBS the measurement method of preference for this purpose. The characterization of both different defects is extracted simultaneously and from the same carbon concentration map following a series of statistical treatment and data extraction rules. LIBS results were validated against recognized methods and were applied to a significant number of routine samples. The new LIBS method offers a step change improvement in reliability for the characterization of segregation and cementite networks in steel products over the conventional methods

  1. Dynamical observation of lithium insertion/extraction reaction during charge-discharge processes in Li-ion batteries by in situ spatially resolved electron energy-loss spectroscopy.

    Science.gov (United States)

    Shimoyamada, Atsushi; Yamamoto, Kazuo; Yoshida, Ryuji; Kato, Takehisa; Iriyama, Yasutoshi; Hirayama, Tsukasa

    2015-12-01

    All-solid-state Li-ion batteries (LIBs) with solid electrolytes are expected to be the next generation devices to overcome serious issues facing conventional LIBs with liquid electrolytes. However, the large Li-ion transfer resistance at the electrode/solid-electrolyte interfaces causes low power density and prevents practical use. In-situ-formed negative electrodes prepared by decomposing the solid electrolyte Li(1+x+3z)Alx(Ti,Ge)(2-x)Si(3z)P(3-z)O12 (LASGTP) with an excess Li-ion insertion reaction are effective electrodes providing low Li-ion transfer resistance at the interfaces. Prior to our work, however, it had still been unclear how the negative electrodes were formed in the parent solid electrolytes. Here, we succeeded in dynamically visualizing the formation by in situ spatially resolved electron energy-loss spectroscopy in a transmission electron microscope mode (SR-TEM-EELS). The Li-ions were gradually inserted into the solid electrolyte region around 400 nm from the negative current-collector/solid-electrolyte interface in the charge process. Some of the ions were then extracted in the discharge process, and the rest were diffused such that the distribution was almost flat, resulting in the negative electrodes. The redox reaction of Ti(4+)/Ti(3+) in the solid electrolyte was also observed in situ during the Li insertion/extraction processes. The in situ SR-TEM-EELS revealed the mechanism of the electrochemical reaction in solid-state batteries. © The Author 2015. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  2. Time-resolved FTIR [Fourier transform infrared] emission studies of laser photofragmentation and chain reactions

    International Nuclear Information System (INIS)

    Leone, S.R.

    1990-01-01

    Recent progress is described resulting from the past three years of DOE support for studies of combustion-related photofragmentation dynamics, energy transfer, and reaction processes using a time-resolved Fourier transform infrared (FTIR) emission technique. The FTIR is coupled to a high repetition rate excimer laser which produces radicals by photolysis to obtain novel, high resolution measurements on vibrational and rotational state dynamics. The results are important for the study of numerous radical species relevant to combustion processes. The method has been applied to the detailed study of photofragmentation dynamics in systems such as acetylene, which produces C 2 H; chlorofluoroethylene to study the HF product channel; vinyl chloride and dichloroethylene, which produce HCl; acetone, which produces CO and CH 3 ; and ammonia, which produces NH 2 . In addition, we have recently demonstrated use of the FTIR technique for preliminary studies of energy transfer events under near single collision conditions, radical-radical reactions, and laser-initiated chain reaction processes

  3. Automated simulation and study of spatial-structural design processes

    NARCIS (Netherlands)

    Davila Delgado, J.M.; Hofmeyer, H.; Stouffs, R.; Sariyildiz, S.

    2013-01-01

    A so-called "Design Process Investigation toolbox" (DPI toolbox), has been developed. It is a set of computational tools that simulate spatial-structural design processes. Its objectives are to study spatial-structural design processes and to support the involved actors. Two case-studies are

  4. A Virtual Study of Grid Resolution on Experiments of a Highly-Resolved Turbulent Plume

    Science.gov (United States)

    Maisto, Pietro M. F.; Marshall, Andre W.; Gollner, Michael J.; Fire Protection Engineering Department Collaboration

    2017-11-01

    An accurate representation of sub-grid scale turbulent mixing is critical for modeling fire plumes and smoke transport. In this study, PLIF and PIV diagnostics are used with the saltwater modeling technique to provide highly-resolved instantaneous field measurements in unconfined turbulent plumes useful for statistical analysis, physical insight, and model validation. The effect of resolution was investigated employing a virtual interrogation window (of varying size) applied to the high-resolution field measurements. Motivated by LES low-pass filtering concepts, the high-resolution experimental data in this study can be analyzed within the interrogation windows (i.e. statistics at the sub-grid scale) and on interrogation windows (i.e. statistics at the resolved scale). A dimensionless resolution threshold (L/D*) criterion was determined to achieve converged statistics on the filtered measurements. Such a criterion was then used to establish the relative importance between large and small-scale turbulence phenomena while investigating specific scales for the turbulent flow. First order data sets start to collapse at a resolution of 0.3D*, while for second and higher order statistical moments the interrogation window size drops down to 0.2D*.

  5. Study Of Soot Growth And Nucleation By A Time-Resolved Synchrotron Radiation Based X-Ray Absorption Method

    National Research Council Canada - National Science Library

    Mitchell, Judith I

    2001-01-01

    This report results from a contract tasking University of Rennes I as follows: The contractor will perform a study of soot growth and nucleation by a time-resolved synchrotron radiation based x-ray absorption method...

  6. SPATIALLY RESOLVED M-BAND EMISSION FROM IO’S LOKI PATERA–FIZEAU IMAGING AT THE 22.8 m LBT

    Energy Technology Data Exchange (ETDEWEB)

    Conrad, Albert; Veillet, Christian [LBT Observatory, University of Arizona, 933 N. Cherry Ave., Tucson, AZ 85721 (United States); Kleer, Katherine de; Pater, Imke de [University of California at Berkeley, Berkeley, CA 94720 (United States); Leisenring, Jarron; Defrère, Denis; Hinz, Philip; Skemer, Andy [University of Arizona, 1428 E. University Blvd., Tucson, AZ 85721 (United States); Camera, Andrea La; Bertero, Mario; Boccacci, Patrizia [DIBRIS, University of Genoa, Via Dodecaneso 35, I-16146 Genova (Italy); Arcidiacono, Carmelo [INAF-Osservatorio Astronomico di Bologna, via Ranzani 1, I-40127 Bologna (Italy); Hofmann, Karl-Heinz; Schertl, Dieter; Weigelt, Gerd [Max Planck Institute for Radio Astronomy, Auf dem Hügel 69, D-53121 Bonn (Germany); Kürster, Martin [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany); Rathbun, Julie [Planetary Science Institute, 1700 E. Fort Lowell, Tucson, AZ 85719 (United States); Skrutskie, Michael [University of Virginia, 530 McCormick Road, Charlottesville, VA 22904 (United States); Spencer, John [Southwest Research Institute, 1050 Walnut Ste. Suite 300, Boulder, CO 80302 (United States); Woodward, Charles E., E-mail: aconrad@lbto.org [Minnesota Institute for Astrophysics, 116 Church St., Minneapolis, MN 55455 (United States)

    2015-05-15

    The Large Binocular Telescope Interferometer mid-infrared camera, LMIRcam, imaged Io on the night of 2013 December 24 UT and detected strong M-band (4.8 μm) thermal emission arising from Loki Patera. The 22.8 m baseline of the Large Binocular Telescope provides an angular resolution of ∼32 mas (∼100 km at Io) resolving the Loki Patera emission into two distinct maxima originating from different regions within Loki’s horseshoe lava lake. This observation is consistent with the presence of a high-temperature source observed in previous studies combined with an independent peak arising from cooling crust from recent resurfacing. The deconvolved images also reveal 15 other emission sites on the visible hemisphere of Io including two previously unidentified hot spots.

  7. Resolving the Strategy Paradox Applying the Strategic Flexibility: A Case Study of PT BNI Life Insurance

    Directory of Open Access Journals (Sweden)

    Endah Widati

    2012-04-01

    Full Text Available Over decades, the business environment has changed dramatically as it has been affected by the changing of environmental needs and demand. The difference level of environmental turbulence characteristics will create new business competitive landscape for all companies in any industries. Environmental turbulence is also marked by dynamics, complexity and unpredictability business environment. In such a situation, a company will be difficult to adapt the environmental changes. In a turbulent environment, a company is demanded to be able to adapt. Many researchers argue that in a turbulent environment, a company is not only demanded for having adaptive ability but also flexible ability either structural, operational or strategic. The fast pace of environmental changes provide managers unpredictable outcomes of their strategic alternative or strategic commitment. This collision of strategic commitment and strategic uncertainty is causing what Raynor (2007 named as the strategy paradox. Every company can be a victim of the strategy paradox if they cannot align their strategy with the environmental changes. Raynor (2007 pointed out that one of the ways to resolve strategy paradox is implementing strategic flexibility in term of ex ante action (proactive actions. One of the industries in Indonesia that also experiences the turbulent environment is insurance industry. This study examines and investigates the strategic flexibility as a way to resolve strategy paradox at PT BNI Life Insurance.

  8. Decomposition of time-resolved tomographic PIV

    NARCIS (Netherlands)

    Schmid, P.J.; Violato, D.; Scarano, F.

    2012-01-01

    An experimental study has been conducted on a transitional water jet at a Reynolds number of Re = 5,000. Flow fields have been obtained by means of time-resolved tomographic particle image velocimetry capturing all relevant spatial and temporal scales. The measured threedimensional flow fields have

  9. a Study on SODIUM(110) and Other Nearly Free Electron Metals Using Angle Resolved Photoemission Spectroscopy.

    Science.gov (United States)

    Lyo, In-Whan

    Electronic properties of the epitaxially grown Na(110) film have been studied using angle resolved ultraviolet photoemission spectroscopy with synchrotron radiation as the light source. Na provides an ideal ground to study the fundamental aspects of the electron-electron interactions in metals, because of its simple Fermi surface and small pseudopotential. The absolute band structure of Na(110) using angle resolved photoemission spectroscopy has been mapped out using the extrema searching method. The advantage of this approach is that the usual assumption of the unoccupied state dispersion is not required. We have found that the dispersion of Na(1l0) is very close to the parabolic band with the effective mass 1.21 M_{rm e} at 90 K. Self-consistent calculations of the self-energy for the homogeneous electron gas have been performed using the Green's function technique within the framework of the GW approximation, in the hope of understanding the narrowing mechanism of the bandwidth observed for all the nearly-free-electron (NFE) metals. Good agreements between the experimental data and our calculated self-energy were obtained not only for our data on k-dependency from Na(l10), but also for the total bandwidth corrections for other NFE metals, only if dielectric functions beyond the random phase approximation were used. Our findings emphasize the importance of the screening by long wavelength plasmons. Off-normal spectra of angle resolved photoemission from Na(110) show strong asymmetry of the bulk peak intensity for the wide range of photon energies. Using a simple analysis, we show this asymmetry has an origin in the interference of the surface Umklapp electrons with the normal electrons. We have also performed the detailed experimental studies of the anomalous Fermi level structure observed in the forbidden gap region of Na. This was claimed by A. W. Overhauser as the evidence of the charge density wave in the alkali metal. The possibility of this hypothesis is

  10. Time-resolved optical studies of wide-gap II-VI semiconductor heterostructures

    Science.gov (United States)

    Wang, Hong

    ZnSe and ZnSe-based quantum well and superlattice structures are potential candidates for light emitting devices and other optical devices such as switches and modulators working in the blue-green wavelength range. Carrier dynamics studies of these structures are important in evaluating device performance as well as understanding the underlying physical processes. In this thesis, a carrier dynamics investigation is conducted for temperature from 77K to 295K on CdZnSSe/ZnSSe single quantum well structure (SQW) and ZnSe/ZnSTe superlattice fabricated by molecular beam epitaxy (MBE). Two experimental techniques with femtosecond time resolution are used in this work: up-conversion technique for time- resolved photoluminescence (PL) and pump-probe technique for time-resolved differential absorption studies. For both heterostructures, the radiative recombination is dominated by exciton transition due to the large exciton binding energy as a result of quantum confinement effect. The measured decay time of free exciton PL in CdZnSSe/ZnSSe SQW increases linearly with increasing temperature which agrees with the theoretical prediction by considering the conservation of momentum requirement for radiative recombination. However, the recombination of free carriers is also observed in CdZnSSe/ZnSSe SQW for the whole temperature range studied. On the other hand, in ZnSe/ZnSTe superlattice structures, the non- radiative recombination processes are non-negligible even at 77K and become more important in higher temperature range. The relaxation processes such as spectral hole burning, carrier thermalization and hot-carrier cooling are observed in ZnSe/ZnSTe superlattices at room temperature (295K) by the femtosecond pump-probe measurements. A rapid cooling of the thermalized hot- carrier from 763K to 450K within 4ps is deduced. A large optical nonlinearity (i.e., the induced absorption change) around the heavy-hole exciton energy is also obtained.

  11. Angle-resolved spin wave band diagrams of square antidot lattices studied by Brillouin light scattering

    Energy Technology Data Exchange (ETDEWEB)

    Gubbiotti, G.; Tacchi, S. [Istituto Officina dei Materiali del Consiglio Nazionale delle Ricerche (IOM-CNR), Sede di Perugia, c/o Dipartimento di Fisica e Geologia, Via A. Pascoli, I-06123 Perugia (Italy); Montoncello, F.; Giovannini, L. [Dipartimento di Fisica e Scienze della Terra, Università di Ferrara, Via G. Saragat 1, I-44122 Ferrara (Italy); Madami, M.; Carlotti, G. [Dipartimento di Fisica e Geologia, Università di Perugia, Via A. Pascoli, I-06123 Perugia (Italy); Ding, J.; Adeyeye, A. O. [Information Storage Materials Laboratory, Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2015-06-29

    The Brillouin light scattering technique has been exploited to study the angle-resolved spin wave band diagrams of squared Permalloy antidot lattice. Frequency dispersion of spin waves has been measured for a set of fixed wave vector magnitudes, while varying the wave vector in-plane orientation with respect to the applied magnetic field. The magnonic band gap between the two most dispersive modes exhibits a minimum value at an angular position, which exclusively depends on the product between the selected wave vector magnitude and the lattice constant of the array. The experimental data are in very good agreement with predictions obtained by dynamical matrix method calculations. The presented results are relevant for magnonic devices where the antidot lattice, acting as a diffraction grating, is exploited to achieve multidirectional spin wave emission.

  12. Resolving Properties of Polymers and Nanoparticle Assembly through Coarse-Grained Computational Studies.

    Energy Technology Data Exchange (ETDEWEB)

    Grest, Gary S. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-09-01

    Coupled length and time scales determine the dynamic behavior of polymers and polymer nanocomposites and underlie their unique properties. To resolve the properties over large time and length scales it is imperative to develop coarse grained models which retain the atomistic specificity. Here we probe the degree of coarse graining required to simultaneously retain significant atomistic details a nd access large length and time scales. The degree of coarse graining in turn sets the minimum length scale instrumental in defining polymer properties and dynamics. Using polyethylene as a model system, we probe how the coarse - graining scale affects the measured dynamics with different number methylene group s per coarse - grained beads. Using these models we simulate polyethylene melts for times over 500 ms to study the viscoelastic properties of well - entangled polymer melts and large nanoparticle assembly as the nanoparticles are driven close enough to form nanostructures.

  13. Spin-resolved tunneling studies of the exchange field in EuS/Al bilayers.

    Science.gov (United States)

    Xiong, Y M; Stadler, S; Adams, P W; Catelani, G

    2011-06-17

    We use spin-resolved electron tunneling to study the exchange field in the Al component of EuS/Al bilayers, in both the superconducting and normal-state phases of the Al. Contrary to expectation, we show that the exchange field H(ex) is a nonlinear function of applied field, even in applied fields that are well beyond the EuS coercive field. Furthermore, the magnitude H(ex) is unaffected by the superconducting phase. In addition, H(ex) decreases significantly with increasing temperature in the temperature range of 0.1-1 K. We discuss these results in the context of recent theories of generalized spin-dependent boundary conditions at a superconductor-ferromagnet interface.

  14. Time-resolved fluorescence study of exciplex formation in diastereomeric naproxen-pyrrolidine dyads.

    Science.gov (United States)

    Khramtsova, Ekaterina A; Plyusnin, Viktor F; Magin, Ilya M; Kruppa, Alexander I; Polyakov, Nikolay E; Leshina, Tatyana V; Nuin, Edurne; Marin, M Luisa; Miranda, Miguel A

    2013-12-19

    The influence of chirality on the elementary processes triggered by excitation of the (S,S)- and (R,S)- diastereoisomers of naproxen-pyrrolidine (NPX-Pyr) dyads has been studied by time-resolved fluorescence in acetonitrile-benzene mixtures. In these systems, the quenching of the (1)NPX*-Pyr singlet excited state occurs through electron transfer and exciplex formation. Fluorescence lifetimes and quantum yields revealed a significant difference (around 20%) between the (S,S)- and (R,S)- diastereomers. In addition, the quantum yields of exciplexes differed by a factor of 2 regardless of solvent polarity. This allows us to suggest a similar influence of the chiral centers on the local charge transfer resulting in exciplex and full charge separation that leads to ion-biradicals. A simplified scheme is proposed to estimate a set of rate constant values (k1-k5) for the elementary stages in each solvent system.

  15. Time-resolved spectroscopy of the probe fluorescence in the study of human blood protein dynamic structure on SR beam

    International Nuclear Information System (INIS)

    Dobretsov, G.E.; Kurek, N.K.; Syrejshchikova, T.I.; Yakimenko, M.N.; Clarke, D.T.; Jones, G.R.; Munro, I.H.

    2000-01-01

    Time-resolved spectroscopy on the SRS of the Daresbury Laboratory was used for the study of the human serum lipoproteins and human blood albumins with fluorescent probes K-37 and K-35, developed in Russia. The probe K-37 was found sensitive to the difference in dynamic properties of the lipid objects. Two sets of the parameters were used for the description of lipid dynamic structure: (1) time-resolved fluorescence spectra and (2) time-resolved fluorescence depolarization as a function of rotational mobility of lipid molecules. Each measured dynamic parameter reflected the monotonous changes of dynamic properties in the range: lipid spheres-very low density lipoproteins-low density lipoproteins-high density lipoproteins-phospholipid liposomes. The range is characterized by the increase of the ratio polar/ nonpolar lipids. Thus, time-resolved fluorescence could be used to detect some structural modifications in lipoproteins related to atherosclerosis and subsequent cardiovascular diseases development

  16. Studies of Minerals, Organic and Biogenic Materials through Time-Resolved Raman Spectroscopy

    Science.gov (United States)

    Garcia, Christopher S.; Abedin, M. Nurul; Ismail, Syed; Sharma, Shiv K.; Misra, Anupam K.; Nyugen, Trac; Elsayed-Ali, hani

    2009-01-01

    A compact remote Raman spectroscopy system was developed at NASA Langley Research center and was previously demonstrated for its ability to identify chemical composition of various rocks and minerals. In this study, the Raman sensor was utilized to perform time-resolved Raman studies of various samples such as minerals and rocks, Azalea leaves and a few fossil samples. The Raman sensor utilizes a pulsed 532 nm Nd:YAG laser as excitation source, a 4-inch telescope to collect the Raman-scattered signal from a sample several meters away, a spectrograph equipped with a holographic grating, and a gated intensified CCD (ICCD) camera system. Time resolved Raman measurements were carried out by varying the gate delay with fixed short gate width of the ICCD camera, allowing measurement of both Raman signals and fluorescence signals. Rocks and mineral samples were characterized including marble, which contain CaCO3. Analysis of the results reveals the short (approx.10-13 s) lifetime of the Raman process, and shows that Raman spectra of some mineral samples contain fluorescence emission due to organic impurities. Also analyzed were a green (pristine) and a yellow (decayed) sample of Gardenia leaves. It was observed that the fluorescence signals from the green and yellow leaf samples showed stronger signals compared to the Raman lines. Moreover, it was also observed that the fluorescence of the green leaf was more intense and had a shorter lifetime than that of the yellow leaf. For the fossil samples, Raman shifted lines could not be observed due the presence of very strong short-lived fluorescence.

  17. An integrated approach using high time-resolved tools to study the origin of aerosols

    International Nuclear Information System (INIS)

    Di Gilio, A.; Gennaro, G. de; Dambruoso, P.; Ventrella, G.

    2015-01-01

    Long-range transport of natural and/or anthropogenic particles can contribute significantly to PM10 and PM2.5 concentrations and some European cities often fail to comply with PM daily limit values due to the additional impact of particles from remote sources. For this reason, reliable methodologies to identify long-range transport (LRT) events would be useful to better understand air pollution phenomena and support proper decision-making. This study explores the potential of an integrated and high time-resolved monitoring approach for the identification and characterization of local, regional and long-range transport events of high PM. In particular, the goal of this work was also the identification of time-limited event. For this purpose, a high time-resolved monitoring campaign was carried out at an urban background site in Bari (southern Italy) for about 20 days (1st–20th October 2011). The integration of collected data as the hourly measurements of inorganic ions in PM 2.5 and their gas precursors and of the natural radioactivity, in addition to the analyses of aerosol maps and hourly back trajectories (BT), provided useful information for the identification and chemical characterization of local sources and trans-boundary intrusions. Non-sea salt (nss) sulfate levels were found to increase when air masses came from northeastern Europe and higher dispersive conditions of the atmosphere were detected. Instead, higher nitrate and lower nss-sulfate concentrations were registered in correspondence with air mass stagnation and attributed to local traffic source. In some cases, combinations of local and trans-boundary sources were observed. Finally, statistical investigations such as the principal component analysis (PCA) applied on hourly ion concentrations and the cluster analyses, the Potential Source Contribution Function (PSCF) and the Concentration Weighted Trajectory (CWT) models computed on hourly back-trajectories enabled to complete a cognitive framework

  18. Femtosecond time-resolved two-photon photoemission study of organic semiconductor copper phthalocyanine film

    International Nuclear Information System (INIS)

    Tanaka, A.; Tohoku University; University of Rochester, NY; Yan, L.; Watkins, N.J.; Gao, Y.

    2004-01-01

    Full text: Organic semiconductors are recently attracting much interest from the viewpoints of both device and fundamental physics. These organic semiconductors are considered to be important constituents of the future devices, such as organic light-emitting diode, organic field effect transistor, and organic solid-state injection laser. In order to elucidate their detailed physical properties and to develop the future devices, it is indispensable to understand their excited-state dynamics as well as their electronic structures. The femtosecond time-resolved two-photon photoemission (TR-2PPE) spectroscopy is attracting much interest because of its capability to observe the energy-resolved excited electron dynamics. In this work, we have carried out a TR-2PPE study of the organic semiconductor copper phthalocyanine (CuPc) film. Furthermore, we have investigated the detailed electronic structure of CuPc film using the photoemission (PES) and inverse photoemission (IPES) spectroscopies. From the simultaneous PES and IPES measurements for CuPc film with a thickness of 100 nm, the lowest unoccupied molecular orbital (LUMO), highest occupied molecular orbital, and ionization potential of CuPc film have been directly determined. The observed two-photon photoemission (2PPE) spectrum of the present CuPc film, measured with photon energy of about hv=3.3 eV, exhibits a broad feature. From the energy diagram of CuPc film determined by the PES and IPES measurements, the intermediate state observed in the present 2PPE spectrum of CuPc film corresponds to the energy region between about 0.4 and 1.7 eV above the LUMO energy. From the time-resolved pump-probe measurements, it is found that the relaxation lifetimes of excited states in the present CuPc films are very short (all below 50 fs) and monotonously become faster with increasing excitation energy. We attribute this extremely fast relaxation process of photoexcitation to a rapid internal conversion process. From these results

  19. An integrated approach using high time-resolved tools to study the origin of aerosols

    Energy Technology Data Exchange (ETDEWEB)

    Di Gilio, A. [Chemistry Department, University of Bari, via Orabona, 4, 70126 Bari (Italy); ARPA PUGLIA, Corso Trieste, 27, 70126 Bari (Italy); Gennaro, G. de, E-mail: gianluigi.degennaro@uniba.it [Chemistry Department, University of Bari, via Orabona, 4, 70126 Bari (Italy); ARPA PUGLIA, Corso Trieste, 27, 70126 Bari (Italy); Dambruoso, P. [Chemistry Department, University of Bari, via Orabona, 4, 70126 Bari (Italy); ARPA PUGLIA, Corso Trieste, 27, 70126 Bari (Italy); Ventrella, G. [Chemistry Department, University of Bari, via Orabona, 4, 70126 Bari (Italy)

    2015-10-15

    Long-range transport of natural and/or anthropogenic particles can contribute significantly to PM10 and PM2.5 concentrations and some European cities often fail to comply with PM daily limit values due to the additional impact of particles from remote sources. For this reason, reliable methodologies to identify long-range transport (LRT) events would be useful to better understand air pollution phenomena and support proper decision-making. This study explores the potential of an integrated and high time-resolved monitoring approach for the identification and characterization of local, regional and long-range transport events of high PM. In particular, the goal of this work was also the identification of time-limited event. For this purpose, a high time-resolved monitoring campaign was carried out at an urban background site in Bari (southern Italy) for about 20 days (1st–20th October 2011). The integration of collected data as the hourly measurements of inorganic ions in PM{sub 2.5} and their gas precursors and of the natural radioactivity, in addition to the analyses of aerosol maps and hourly back trajectories (BT), provided useful information for the identification and chemical characterization of local sources and trans-boundary intrusions. Non-sea salt (nss) sulfate levels were found to increase when air masses came from northeastern Europe and higher dispersive conditions of the atmosphere were detected. Instead, higher nitrate and lower nss-sulfate concentrations were registered in correspondence with air mass stagnation and attributed to local traffic source. In some cases, combinations of local and trans-boundary sources were observed. Finally, statistical investigations such as the principal component analysis (PCA) applied on hourly ion concentrations and the cluster analyses, the Potential Source Contribution Function (PSCF) and the Concentration Weighted Trajectory (CWT) models computed on hourly back-trajectories enabled to complete a cognitive

  20. Dual time-resolved temperature-jump fluorescence and infrared spectroscopy for the study of fast protein dynamics.

    Science.gov (United States)

    Davis, Caitlin M; Reddish, Michael J; Dyer, R Brian

    2017-05-05

    Time-resolved temperature-jump (T-jump) coupled with fluorescence and infrared (IR) spectroscopy is a powerful technique for monitoring protein dynamics. Although IR spectroscopy of the polypeptide amide I mode is more technically challenging, it offers complementary information because it directly probes changes in the protein backbone, whereas, fluorescence spectroscopy is sensitive to the environment of specific side chains. With the advent of widely tunable quantum cascade lasers (QCL) it is possible to efficiently probe multiple IR frequencies with high sensitivity and reproducibility. Here we describe a dual time-resolved T-jump fluorescence and IR spectrometer and its application to study protein folding dynamics. A Q-switched Ho:YAG laser provides the T-jump source for both time-resolved IR and fluorescence spectroscopy, which are probed by a QCL and Ti:Sapphire laser, respectively. The Ho:YAG laser simultaneously pumps the time-resolved IR and fluorescence spectrometers. The instrument has high sensitivity, with an IR absorbance detection limit of jump induced difference spectrum from 50ns to 0.5ms. This study demonstrates the power of the dual time-resolved T-jump fluorescence and IR spectroscopy to resolve complex folding mechanisms by complementary IR absorbance and fluorescence measurements of protein dynamics. Copyright © 2017 Elsevier B.V. All rights reserved.

  1. The spatial comfort study of shophouse at Kampung Madras

    Science.gov (United States)

    Ginting, Y. U. U.; Ginting, N.; Zahrah, W.

    2018-03-01

    This Research comes from the increasing quantity of shophouse in downtown Medan and the suburban area. The condition of shophouse tend to have narrowly spaced rooms, the middle area of the house are poorly lighted, and lots of space left unused. This research is supported by many spatial issues from previous studies. This study is conducted to determine the level of comfort of shophouse as a function of living space and focused on the spatial aspect namely anthropometry, indoor space circulation, space requirement and function, spatial design and indoor visual. This study uses the descriptive method with the qualitative and quantitative approach. Data collection technique is done by field observation, questionnaire method is also used to get the respondent perception of the spatial comfort of a shophouse. The result indicates that the level of spatial comfort of the shophouse is an uncomfort. So the improvements in the circulation of access to the building, spatial design, lighting, and aeration are needed to improve the spatial comfort of a shophouse.

  2. How does spatial study design influence density estimates from spatial capture-recapture models?

    Directory of Open Access Journals (Sweden)

    Rahel Sollmann

    Full Text Available When estimating population density from data collected on non-invasive detector arrays, recently developed spatial capture-recapture (SCR models present an advance over non-spatial models by accounting for individual movement. While these models should be more robust to changes in trapping designs, they have not been well tested. Here we investigate how the spatial arrangement and size of the trapping array influence parameter estimates for SCR models. We analysed black bear data collected with 123 hair snares with an SCR model accounting for differences in detection and movement between sexes and across the trapping occasions. To see how the size of the trap array and trap dispersion influence parameter estimates, we repeated analysis for data from subsets of traps: 50% chosen at random, 50% in the centre of the array and 20% in the South of the array. Additionally, we simulated and analysed data under a suite of trap designs and home range sizes. In the black bear study, we found that results were similar across trap arrays, except when only 20% of the array was used. Black bear density was approximately 10 individuals per 100 km(2. Our simulation study showed that SCR models performed well as long as the extent of the trap array was similar to or larger than the extent of individual movement during the study period, and movement was at least half the distance between traps. SCR models performed well across a range of spatial trap setups and animal movements. Contrary to non-spatial capture-recapture models, they do not require the trapping grid to cover an area several times the average home range of the studied species. This renders SCR models more appropriate for the study of wide-ranging mammals and more flexible to design studies targeting multiple species.

  3. Investigation on the role of air in the dynamical evolution and thermodynamic state of a laser-induced aluminium plasma by spatial- and time-resolved spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Cristoforetti, G., E-mail: gabriele.cristoforetti@cnr.i [National Institute of Optics, Research Area of National Research Council, Via G.Moruzzi, 1 - 56124 Pisa (Italy); Lorenzetti, G.; Legnaioli, S.; Palleschi, V. [Institute of Chemistry of Organometallic Compounds, Research Area of National Research Council, Via G.Moruzzi, 1 - 56124 Pisa (Italy)

    2010-09-15

    The amount and the spatial distribution of air atoms and ions in a laser-induced plasma in ambient air provide important information about the formation of the plasma and its successive evolution history. For this reason, in the present work, the air mixing in a laser-induced plasma in air at atmospheric pressure and its influence on its thermodynamic evolution were studied. Information about spatial distributions of atoms and ions from Al, N and O were achieved by Abel-inverted spectra in the plume. The occurrence of LTE in the plume was also assessed by the utilization of theoretical criteria, and by the analysis of experimental spectra. Aluminium atoms and ions were found to be in LTE, while nitrogen and oxygen were not because of their longer times of relaxation toward equilibrium. Nitrogen was found to be over-ionized with respect to Saha-Eggert equilibrium, indicating that the plasma is recombining. Experimental observations suggest that the concentration of air species in the plasma is larger than that of aluminium, even in the region closer to the target, where the aluminium lines are stronger. In the front part of the plume only emission lines from air species were observed. The results suggest that a Laser-Supported Detonation (LSD) regime occurs during the trailing part of the laser pulse, resulting in the strong inclusion into the plasma of air elements. In this scenario, also the thermodynamic history of the plume is affected by the predominance of air species.

  4. Time-resolved photoelectron spectroscopy and ab initio multiple spawning studies of hexamethylcyclopentadiene

    DEFF Research Database (Denmark)

    Wolf, T. J. A.; Kuhlman, Thomas Scheby; Schalk, O.

    2014-01-01

    Time-resolved photoelectron spectroscopy and ab initio multiple spawning were applied to the ultrafast non-adiabatic dynamics of hexamethylcyclopentadiene. The high level of agreement between experiment and theory associates wavepacket motion with a distinct degree of freedom.......Time-resolved photoelectron spectroscopy and ab initio multiple spawning were applied to the ultrafast non-adiabatic dynamics of hexamethylcyclopentadiene. The high level of agreement between experiment and theory associates wavepacket motion with a distinct degree of freedom....

  5. Formation of complexes between functionalized chitosan membranes and copper: A study by angle resolved XPS

    Energy Technology Data Exchange (ETDEWEB)

    Jurado-López, Belén [Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga (Spain); Vieira, Rodrigo Silveira [Chemical Engineering Department, Universidade Federal do Ceará, UFC, 60455-760 Fortaleza, CE (Brazil); Rabelo, Rodrigo Balloni; Beppu, Marisa Masumi [School of Chemical Engineering, University of Campinas, UNICAMP, P.O. Box 6066, 13081-970 Campinas, SP (Brazil); Casado, Juan [Departamento de Química-Física, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga (Spain); Rodríguez-Castellón, Enrique, E-mail: castellon@uma.es [Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga (Spain)

    2017-01-01

    Chitosan is a biopolymer with potential applications in various fields. Recently, it has been used for heavy metals removal like copper, due to the presence of amino and hydroxyl groups in its structure. Chitosan membranes were crosslinked with epichlorohydrin and bisoxirano and functionalized with chelating agents, such as iminodiacetic acid, aspartic acid and tris-(2-amino-ethyl) polyamine. These membranes were used for copper adsorption and the formed complexes were characterized. Thermal and crystalline properties of chitosan membranes were studied by TG-DCS and X-ray diffraction. Raman, XPS and FT-IR data confirmed that copper is linked to the modified chitosan membranes by the amino groups. The oxidation state of copper-chitosan membranes were also studied by angle resolved XPS, and by UV–Vis diffuse reflectance spectroscopy. - Highlights: • Chitosan membranes were crosslinked with epichlorohydrin and bisoxirano and functionalized with chelating agents. • The chelating agent were iminodiacetic acid, aspartic acid and tris-(2-amino-ethyl) polyamine. • The functionalized membranes were used for copper adsorption and studied by ARXPS, Raman, TG-DCS, FT-IR and XRD. • Spectroscopic data confirmed that copper is linked to the modified chitosan membranes by the amino groups.

  6. Study of the spatial resolution for binary readout detectors

    Energy Technology Data Exchange (ETDEWEB)

    Yonamine, R., E-mail: ryo.yonamine@ulb.ac.be; Maerschalk, T.; Lentdecker, G. De

    2016-07-11

    Often the binary readout is proposed for high granularity detectors to reduce the generated data volume to be readout at the price of a somewhat reduced spatial resolution compared to an analogue readout. We have been studying single hit resolutions obtained with a binary readout using simulations as well as analytical approaches. In this note we show that the detector geometry could be optimized to offer an equivalent spatial resolution than with an analogue readout.

  7. Time-resolved echo-shared parallel MRA of the lung: observer preference study of image quality in comparison with non-echo-shared sequences

    International Nuclear Information System (INIS)

    Fink, C.; Puderbach, M.; Zaporozhan, J.; Plathow, C.; Kauczor, H.-U.; Ley, S.

    2005-01-01

    The aim of this study was to evaluate the image quality of time-resolved echo-shared parallel MRA of the lung. The pulmonary vasculature of nine patients (seven females, two males; median age: 44 years) with pulmonary disease was examined using a time-resolved MRA sequence combining echo sharing with parallel imaging (time-resolved echo-shared angiography technique, or TREAT). The sharpness of the vessel borders, conspicuousness of peripheral lung vessels, artifact level, and overall image quality of TREAT was assessed independently by four readers in a side-by-side comparison with non-echo-shared time-resolved parallel MRA data (pMRA) previously acquired in the same patients. Furthermore, the SNR of pulmonary arteries (PA) and veins (PV) achieved with both pulse sequences was compared. The mean voxel size of TREAT MRA was decreased by 24% compared with the non-echo-shared MRA. Regarding the sharpness of the vessel borders, conspicuousness of peripheral lung vessels, and overall image quality the TREAT sequence was rated superior in 75-76% of all cases. If the TREAT images were preferred over the pMRA images, the advantage was rated as major in 61-71% of all cases. The level of artifacts was not increased with the TREAT sequence. The mean interobserver agreement for all categories ranged between fair (artifact level) and good (overall image quality). The maximum SNR of TREAT did not differ from non-echo-shared parallel MRA (PA: TREAT: 273±45; pMRA: 280±71; PV: TREAT: 273±33; pMRA: 258±62). TREAT achieves a higher spatial resolution than non-echo-shared parallel MRA which is also perceived as an improved image quality. (orig.)

  8. Rovibronically selected and resolved two-color laser photoionization and photoelectron study of cobalt carbide cation.

    Science.gov (United States)

    Huang, Huang; Chang, Yih Chung; Luo, Zhihong; Shi, Xiaoyu; Lam, Chow-Shing; Lau, Kai-Chung; Ng, C Y

    2013-03-07

    We have conducted a two-color visible-ultraviolet (VIS-UV) resonance-enhanced laser photoionization efficiency and pulsed field ionization-photoelectron (PFI-PE) study of gaseous cobalt carbide (CoC) near its ionization onset in the total energy range of 61,200-64,510 cm(-1). The cold gaseous CoC sample was prepared by a laser ablation supersonically cooled beam source. By exciting CoC molecules thus generated to single N' rotational levels of the intermediate CoC∗((2)Σ(+); v') state using a VIS dye laser prior to UV laser photoionization, we have obtained N(+) rotationally resolved PFI-PE spectra for the CoC(+)(X(1)Σ(+); v(+) = 0 and 1) ion vibrational bands free from interference by impurity species except Co atoms produced in the ablation source. The rotationally selected and resolved PFI-PE spectra have made possible unambiguous rotational assignments, yielding accurate values for the adiabatic ionization energy of CoC(X(2)Σ(+)), IE(CoC) = 62,384.3 ± 0.6 cm(-1) (7.73467 ± 0.00007 eV), the vibrational frequency ωe (+) = 985.6 ± 0.6 cm(-1), the anharmonicity constant ωe (+)χe (+) = 6.3 ± 0.6 cm(-1), the rotational constants (Be (+) = 0.7196 ± 0.0005 cm(-1), αe (+) = 0.0056 ± 0.0008 cm(-1)), and the equilibrium bond length re (+) = 1.534 Å for CoC(+)(X(1)Σ(+)). The observation of the N(+) = 0 level in the PFI-PE measurement indicates that the CoC(+) ground state is of (1)Σ(+) symmetry. Large ΔN(+) = N(+) - N' changes up to 6 are observed for the photoionization transitions CoC(+)(X(1)Σ(+); v(+) = 0-2; N(+)) ← CoC∗((2)Σ(+); v'; N' = 6, 7, 8, and 9). The highly precise energetic and spectroscopic data obtained in the present study have served as a benchmark for testing theoretical predictions based on state-of-the-art ab initio quantum calculations at the CCSDTQ∕CBS level of theory as presented in the companion article.

  9. Spatial structure determination of (√3 x √3)R30 degrees and (1.5 x 1.5)R18 degrees CO on Cu(111) using angle-resolved photoemission extended fine structure

    International Nuclear Information System (INIS)

    Moler, E.J.; Kellar, S.A.; Huff, W.R.A.

    1997-01-01

    The authors report a study of the spatial structure of (√3 x √3)R30 degrees (low coverage) and (1.5 x 1.5)R18 degrees (intermediate coverage) CO adsorbed on Cu(111), using the Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) technique at beamline 9.3.2 at the Advanced Light Source. The CO molecule adsorbs on an atop site for both adsorption phases. Full multiple-scattering spherical-wave (MSSW) calculations were used to extract the C-Cu. bond length and the first Cu-Cu layer spacing for each adsorption phase. The authors find that the C-Cu bond length remains unchanged with increasing coverage, but the 1st Cu-Cu layer spacing contracts at the intermediate coverage. They calculate the bending mode force constant in the (1.5 x 1.5)R18 degrees phase to be K δ = 2.2 (1) x 10 -12 dyne-cm/rad from their experimentally determined bond lengths combined with previously published infra-red absorption frequencies

  10. Spatial structure determination of ({radical}3 x {radical}3)R30{degrees} and (1.5 x 1.5)R18{degrees}CO on Cu(111) using angle-resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Moler, E.J.; Kellar, S.A.; Huff, W.R.A. [Lawrence Berkeley National Lab., CA (United States)] [and others

    1997-04-01

    The authors report a study of the spatial structure of ({radical}3 x {radical}3)R30{degrees} (low coverage) and (1.5 x 1.5)R18{degrees} (intermediate coverage) CO adsorbed on Cu(111), using the Angle-Resolved Photoemission Extended Fine Structure (ARPEFS) technique at beamline 9.3.2 at the Advanced Light Source. The CO molecule adsorbs on an atop site for both adsorption phases. Full multiple-scattering spherical-wave (MSSW) calculations were used to extract the C-Cu. bond length and the first Cu-Cu layer spacing for each adsorption phase. The authors find that the C-Cu bond length remains unchanged with increasing coverage, but the 1st Cu-Cu layer spacing contracts at the intermediate coverage. They calculate the bending mode force constant in the (1.5 x 1.5)R18{degrees} phase to be K{sub {delta}} = 2.2 (1) x 10{sup {minus}12} dyne-cm/rad from their experimentally determined bond lengths combined with previously published infra-red absorption frequencies.

  11. Electronic properties of novel topological quantum materials studied by angle-resolved photoemission spectroscopy (ARPES)

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Yun [Iowa State Univ., Ames, IA (United States)

    2016-12-17

    The discovery of quantum Hall e ect has motivated the use of topology instead of broken symmetry to classify the states of matter. Quantum spin Hall e ect has been proposed to have a separation of spin currents as an analogue of the charge currents separation in quantum Hall e ect, leading us to the era of topological insulators. Three-dimensional analogue of the Dirac state in graphene has brought us the three-dimensional Dirac states. Materials with three-dimensional Dirac states could potentially be the parent compounds for Weyl semimetals and topological insulators when time-reversal or space inversion symmetry is broken. In addition to the single Dirac point linking the two dispersion cones in the Dirac/Weyl semimetals, Dirac points can form a line in the momentum space, resulting in a topological node line semimetal. These fascinating novel topological quantum materials could provide us platforms for studying the relativistic physics in condensed matter systems and potentially lead to design of new electronic devices that run faster and consume less power than traditional, silicon based transistors. In this thesis, we present the electronic properties of novel topological quantum materials studied by angle-resolved photoemission spectroscopy (ARPES).

  12. Spatially resolving a starburst galaxy at hard X-ray energies: NuSTAR, CHANDRA, AND VLBA observations of NGC 253

    DEFF Research Database (Denmark)

    Wik, D. R.; Lehmer, B. D.; Hornschemeier, A. E.

    2014-01-01

    for the first time. As a follow up to our initial study of its nuclear region, we present the first results concerning the full galaxy from simultaneous NuSTAR, Chandra, and Very Long Baseline Array monitoring of the local starburst galaxy NGC 253. Above ~10 keV, nearly all the emission is concentrated within...... is detected at E > 40 keV. We report upper limits on diffuse inverse Compton emission for a range of spatial models. For the most extended morphologies considered, these hard X-ray constraints disfavor a dominant inverse Compton component to explain the γ-ray emission detected with Fermi and H.E.S.S. If NGC...

  13. Balancing geo-privacy and spatial patterns in epidemiological studies

    Directory of Open Access Journals (Sweden)

    Chien-Chou Chen

    2017-11-01

    Full Text Available To balance the protection of geo-privacy and the accuracy of spatial patterns, we developed a geo-spatial tool (GeoMasker intended to mask the residential locations of patients or cases in a geographic information system (GIS. To elucidate the effects of geo-masking parameters, we applied 2010 dengue epidemic data from Taiwan testing the tool’s performance in an empirical situation. The similarity of pre- and post-spatial patterns was measured by D statistics under a 95% confidence interval. In the empirical study, different magnitudes of anonymisation (estimated Kanonymity ≥10 and 100 were achieved and different degrees of agreement on the pre- and post-patterns were evaluated. The application is beneficial for public health workers and researchers when processing data with individuals’ spatial information.

  14. Auditory and visual spatial impression: Recent studies of three auditoria

    Science.gov (United States)

    Nguyen, Andy; Cabrera, Densil

    2004-10-01

    Auditory spatial impression is widely studied for its contribution to auditorium acoustical quality. By contrast, visual spatial impression in auditoria has received relatively little attention in formal studies. This paper reports results from a series of experiments investigating the auditory and visual spatial impression of concert auditoria. For auditory stimuli, a fragment of an anechoic recording of orchestral music was convolved with calibrated binaural impulse responses, which had been made with the dummy head microphone at a wide range of positions in three auditoria and the sound source on the stage. For visual stimuli, greyscale photographs were used, taken at the same positions in the three auditoria, with a visual target on the stage. Subjective experiments were conducted with auditory stimuli alone, visual stimuli alone, and visual and auditory stimuli combined. In these experiments, subjects rated apparent source width, listener envelopment, intimacy and source distance (auditory stimuli), and spaciousness, envelopment, stage dominance, intimacy and target distance (visual stimuli). Results show target distance to be of primary importance in auditory and visual spatial impression-thereby providing a basis for covariance between some attributes of auditory and visual spatial impression. Nevertheless, some attributes of spatial impression diverge between the senses.

  15. An integrated approach using high time-resolved tools to study the origin of aerosols.

    Science.gov (United States)

    Di Gilio, A; de Gennaro, G; Dambruoso, P; Ventrella, G

    2015-10-15

    Long-range transport of natural and/or anthropogenic particles can contribute significantly to PM10 and PM2.5 concentrations and some European cities often fail to comply with PM daily limit values due to the additional impact of particles from remote sources. For this reason, reliable methodologies to identify long-range transport (LRT) events would be useful to better understand air pollution phenomena and support proper decision-making. This study explores the potential of an integrated and high time-resolved monitoring approach for the identification and characterization of local, regional and long-range transport events of high PM. In particular, the goal of this work was also the identification of time-limited event. For this purpose, a high time-resolved monitoring campaign was carried out at an urban background site in Bari (southern Italy) for about 20 days (1st-20th October 2011). The integration of collected data as the hourly measurements of inorganic ions in PM2.5 and their gas precursors and of the natural radioactivity, in addition to the analyses of aerosol maps and hourly back trajectories (BT), provided useful information for the identification and chemical characterization of local sources and trans-boundary intrusions. Non-sea salt (nss) sulfate levels were found to increase when air masses came from northeastern Europe and higher dispersive conditions of the atmosphere were detected. Instead, higher nitrate and lower nss-sulfate concentrations were registered in correspondence with air mass stagnation and attributed to local traffic source. In some cases, combinations of local and trans-boundary sources were observed. Finally, statistical investigations such as the principal component analysis (PCA) applied on hourly ion concentrations and the cluster analyses, the Potential Source Contribution Function (PSCF) and the Concentration Weighted Trajectory (CWT) models computed on hourly back-trajectories enabled to complete a cognitive framework

  16. A Coupled GCM-Cloud Resolving Modeling System, and a Regional Scale Model to Study Precipitation Processes

    Science.gov (United States)

    Tao, Wei-Kuo

    2007-01-01

    Recent GEWEX Cloud System Study (GCSS) model comparison projects have indicated that cloud-resolving models (CRMs) agree with observations better than traditional single-column models in simulating various types of clouds and cloud systems from different geographic locations. Current and future NASA satellite programs can provide cloud, precipitation, aerosol and other data at very fine spatial and temporal scales. It requires a coupled global circulation model (GCM) and cloud-scale model (termed a superparameterization or multi-scale modeling framework, MMF) to use these satellite data to improve the understanding of the physical processes that are responsible for the variation in global and regional climate and hydrological systems. The use of a GCM will enable global coverage, and the use of a CRM will allow for better and more sophisticated physical parameterization. NASA satellite and field campaign cloud related datasets can provide initial conditions as well as validation for both the MMF and CRMs. The Goddard MMF is based on the 2D Goddard Cumulus Ensemble (GCE) model and the Goddard finite volume general circulation model (fvGCM), and it has started production runs with two years results (1998 and 1999). Also, at Goddard, we have implemented several Goddard microphysical schemes (2ICE, several 31CE), Goddard radiation (including explicitly calculated cloud optical properties), and Goddard Land Information (LIS, that includes the CLM and NOAH land surface models) into a next generatio11 regional scale model, WRF. In this talk, I will present: (1) A brief review on GCE model and its applications on precipitation processes (microphysical and land processes), (2) The Goddard MMF and the major difference between two existing MMFs (CSU MMF and Goddard MMF), and preliminary results (the comparison with traditional GCMs), and (3) A discussion on the Goddard WRF version (its developments and applications).

  17. A study of spatial resolution in pollution exposure modelling

    Directory of Open Access Journals (Sweden)

    Gustafsson Susanna

    2007-06-01

    Full Text Available Abstract Background This study is part of several ongoing projects concerning epidemiological research into the effects on health of exposure to air pollutants in the region of Scania, southern Sweden. The aim is to investigate the optimal spatial resolution, with respect to temporal resolution, for a pollutant database of NOx-values which will be used mainly for epidemiological studies with durations of days, weeks or longer periods. The fact that a pollutant database has a fixed spatial resolution makes the choice critical for the future use of the database. Results The results from the study showed that the accuracy between the modelled concentrations of the reference grid with high spatial resolution (100 m, denoted the fine grid, and the coarser grids (200, 400, 800 and 1600 meters improved with increasing spatial resolution. When the pollutant values were aggregated in time (from hours to days and weeks the disagreement between the fine grid and the coarser grids were significantly reduced. The results also illustrate a considerable difference in optimal spatial resolution depending on the characteristic of the study area (rural or urban areas. To estimate the accuracy of the modelled values comparison were made with measured NOx values. The mean difference between the modelled and the measured value were 0.6 μg/m3 and the standard deviation 5.9 μg/m3 for the daily difference. Conclusion The choice of spatial resolution should not considerably deteriorate the accuracy of the modelled NOx values. Considering the comparison between modelled and measured values we estimate that an error due to coarse resolution greater than 1 μg/m3 is inadvisable if a time resolution of one day is used. Based on the study of different spatial resolutions we conclude that for urban areas a spatial resolution of 200–400 m is suitable; and for rural areas the spatial resolution could be coarser (about 1600 m. This implies that we should develop a pollutant

  18. Studies of nanostructures using time-resolved x-ray excited optical luminescence*

    International Nuclear Information System (INIS)

    Rosenberg, R.A.; Shenoy, G.K.; Smita, S.; Burda, C.; Sham, T.K.

    2004-01-01

    Full text:The scientific community is currently investing a great deal of effort into understanding the physics and chemistry of nanoscale structures. Synchrotron radiation techniques are being used to study the physical, electronic, and magnetic structure of nanosystems, albeit at a relatively large size (greater than 30 nm). A major challenge facing researchers is finding methods that can probe structures of the smallest scale (less than 10 nm). Optical luminescence has been shown to be directly sensitive to structures in this size range due to quantum confinement phenomena. X-ray-excited optical luminescence (XEOL) provides the capability to chemically map the sites responsible for producing low-energy (1-6 eV) fluorescence. By taking advantage of the time structure of the x-ray pulses at the Advanced Photon Source (70 ps wide, 153 ns separation), it also possible to determine the dynamic behavior of the states involved in the luminescence. In this paper we will present results of time-resolved XEOL experiments on various nanostructures including porous silicon, silicon nanowires, and CdSe nanodots

  19. Photolysis of Br2 in CCl4 studied by time-resolved X-ray scattering.

    Science.gov (United States)

    Kong, Qingyu; Lee, Jae Hyuk; Lo Russo, Manuela; Kim, Tae Kyu; Lorenc, Maciej; Cammarata, Marco; Bratos, Savo; Buslaps, Thomas; Honkimaki, Veijo; Ihee, Hyotcherl; Wulff, Michael

    2010-03-01

    A time-resolved X-ray solution scattering study of bromine molecules in CCl(4) is presented as an example of how to track atomic motions in a simple chemical reaction. The structures of the photoproducts are tracked during the recombination process, geminate and non-geminate, from 100 ps to 10 micros after dissociation. The relaxation of hot Br(2)(*) molecules heats the solvent. At early times, from 0.1 to 10 ns, an adiabatic temperature rise is observed, which leads to a pressure gradient that forces the sample to expand. The expansion starts after about 10 ns with the laser beam sizes used here. When thermal artefacts are removed by suitable scaling of the transient solvent response, the excited-state solute structures can be obtained with high fidelity. The analysis shows that 30% of Br(2)(*) molecules recombine directly along the X potential, 60% are trapped in the A/A' state with a lifetime of 5.5 ns, and 10% recombine non-geminately via diffusive motion in about 25 ns. The Br-Br distance distribution in the A/A' state peaks at 3.0 A.

  20. Time-resolved studies of direct effects of radiation on DNA

    International Nuclear Information System (INIS)

    Fielden, E.M.; O'Neill, P.; Al-Kazwini, A.

    1987-01-01

    The biological changes induced by ionising radiation are a consequence of radiation-induced chemical events taking place at times <1s. These events are strongly influenced by the presence of chemical modifiers. Since DNA is a principle target for radiation-induced cell killing, DNA-free radicals are generated by direct ionisation of DNA moieties (direct effect) and by reaction with hydroxyl radicals formed by radiolysis of the water which is in the vicinity of the DNA (indirect effect). In order to study the 'direct' effects of radiation on DNA the following model approaches are discussed:- 1) Use of the technique of pulse radiolysis to investigate in aqueous solution the interactions of deoxynucleosides with SO/sub 4//sup .-/ whereby one-electron oxidised species of the bases are generated; and 2) time resolved, radiation-induced changes to solid DNA and related macromolecules (e.g. radiation-induced luminescence) in order to obtain an understanding of charge/energy migration as a result of ionisation of DNA. The influence of chemical modifiers and of environment is discussed in terms of the properties of the radiation-induced species produced. Since the properties of base radicals produced by SO/sub 4//sup .-/ are similar to those of the base OH-adducts oxidising properties, potential similarities between the 'direct' and 'indirect' effects of radiation are presented

  1. Time-resolved luminescence studies in hydrogen uranyl phosphate intercalated with amines

    Energy Technology Data Exchange (ETDEWEB)

    Novo, Joao Batista Marques [Departamento de Quimica, Universidade Federal do Parana, CP 19081, 81531-990 Curitiba-PR (Brazil)]. E-mail: jbmnovo@quimica.ufpr.br; Batista, Fabio Roberto [Departamento de Quimica, Universidade Federal do Parana, CP 19081, 81531-990 Curitiba-PR (Brazil); Cunha, Carlos Jorge da [Departamento de Quimica, Universidade Federal do Parana, CP 19081, 81531-990 Curitiba-PR (Brazil); Dias, Lauro Camargo Jr. [Departamento de Quimica, Universidade Federal do Parana, CP 19081, 81531-990 Curitiba-PR (Brazil); Teixeira Pessine, Francisco Benedito [Instituto de Quimica, Universidade Estadual de Campinas, CP 6154, 13084-971 Campinas-SP (Brazil)

    2007-05-15

    Time-resolved luminescence decays of intercalated compounds of hydrogen uranyl phosphate (HUP) with p-toluidinium (HUPPT), benzylaminium (HUPBZ), {alpha}-methylbenzylaminium (HUPMBZ) and hydroxylaminium (HUPHAM) were studied. The prepared compounds belong to the tetragonal P4/ncc space group and showed 00 l reflections shifted to lower angles relative to HUP, indicating that the intercalation increases the c parameter of the unit cell. The luminescence decays of the compounds with 100% of intercalation ratio (HUPHAM and HUPBZ) were analyzed by Global Analysis, assuming Lianos' stretched exponential as the model function, which can be applied to compounds with restricted geometry and mobile donor and quencher molecules. It was remarkable that the luminescence decays showed that the quenching of the emission of the uranyl ions by the intercalated protonated amines is not restricted by low dimensionality of the host uranyl phosphate, and that a diffusion mechanism occurs. Benzylaminium cation efficiently quenches the excited energy of the uranyl ions at close distance, but the long-range and long-lifetime quenching is hindered. A different situation is found in the case of the small hydroxylaminium cation, where the long distance diffusion of the species is fast, playing an important role in the quenching of the excited uranyl ions at longer times.

  2. Time-resolved luminescence studies in hydrogen uranyl phosphate intercalated with amines

    International Nuclear Information System (INIS)

    Novo, Joao Batista Marques; Batista, Fabio Roberto; Cunha, Carlos Jorge da; Dias, Lauro Camargo Jr.; Teixeira Pessine, Francisco Benedito

    2007-01-01

    Time-resolved luminescence decays of intercalated compounds of hydrogen uranyl phosphate (HUP) with p-toluidinium (HUPPT), benzylaminium (HUPBZ), α-methylbenzylaminium (HUPMBZ) and hydroxylaminium (HUPHAM) were studied. The prepared compounds belong to the tetragonal P4/ncc space group and showed 00 l reflections shifted to lower angles relative to HUP, indicating that the intercalation increases the c parameter of the unit cell. The luminescence decays of the compounds with 100% of intercalation ratio (HUPHAM and HUPBZ) were analyzed by Global Analysis, assuming Lianos' stretched exponential as the model function, which can be applied to compounds with restricted geometry and mobile donor and quencher molecules. It was remarkable that the luminescence decays showed that the quenching of the emission of the uranyl ions by the intercalated protonated amines is not restricted by low dimensionality of the host uranyl phosphate, and that a diffusion mechanism occurs. Benzylaminium cation efficiently quenches the excited energy of the uranyl ions at close distance, but the long-range and long-lifetime quenching is hindered. A different situation is found in the case of the small hydroxylaminium cation, where the long distance diffusion of the species is fast, playing an important role in the quenching of the excited uranyl ions at longer times

  3. Time resolved FTIR study of the catalytic CO oxidation under periodic variation of the reactant concentration

    Energy Technology Data Exchange (ETDEWEB)

    Kritzenberger, J; Wokaun, A [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Oxidation of CO over palladium/zirconia catalyst obtained from an amorphous Pd{sub 25}Zr{sub 75} precursor was investigated by time resolved FTIR spectroscopy. Sine wave shaped modulation of the reactant concentration, i.e. variation of CO or O{sub 2} partial pressure, was used to induce variations of the IR signals of product (CO{sub 2}) and unconverted reactant (CO), which were detected in a multi-pass absorption cell. The phase shift {phi} between external perturbation and variation of the CO{sub 2} signal was examined in dependence on temperature (100{sup o}C{<=}T{<=}350{sup o}C) and modulation frequency (1.39x10{sup -4}Hz{<=}{omega}{<=}6.67x10{sup -2}Hz). From the phase shift values, a simple Eley-Rideal mechanism is excluded, and the rate limiting step of the Langmuir-Hinshelwood mechanism for the CO oxidation may be identified. Adsorption and possible surface movement of CO to the actual reaction site determine the rate of the CO oxidation on the palladium/zirconia catalyst used in our study. The introduction of an external perturbation is a first step towards the application of two-dimensional infrared spectroscopy to heterogeneous catalyzed reactions. (author) 3 figs., 4 refs.

  4. Spin-resolved x-ray photoemission studies of ferromagnetic metals

    International Nuclear Information System (INIS)

    Klebanoff, L.E.

    1996-01-01

    Recent spin-resolved x-ray photoelectron spectroscopy (SRXPS) studies of ferromagnetic metals are reviewed. SRXPS studies of metallic Fe, Co, Co 66 Fe 4 Ni 1 B 14 Si 15 , and Ni demonstrate that core-level photoemission, and the itinerant electron response to core-hole creation, are highly spin-dependent. The exchange splitting of the Fe 2p 3/2 level is found to be 0.48±0.05 eV. Lifetime broadening results for the Fe 2p 3/2 N↑ (majority spin) and N↓ (minority spin) components indicate conservation of spin in core-hole filling processes involving the valence band. SRXPS study of the Fe 2p 3/2 peak asymmetry α reveals a dependence of electron endash hole excitation on the spin of the core hole. Spin analysis of the Fe 3s XPS line shape shows it to be a three-component spectrum, rather than the two-component line shape assumed previously. A photon energy dependence of one of the Fe 3s components explains disagreement among previous Fe 3s XPS results. Comparisons of SRXPS from Co metal and Co 66 Fe 4 Ni 1 B 14 Si 15 directly demonstrate the effect of a reduced atomic magnetic moment on the spin dependence of core-level XPS. The behavior of lifetime broadenings for the N↑ and N↓ Co 2p 3/2 components show that the reduced Co magnetic moment found in the Co 66 Fe 4 Ni 1 B 14 Si 15 amorphous glass is due to the transfer of ↑-spin valence electron density to the ↓-spin valence band upon glass formation. SRXPS also allows investigation of spin-dependent core-hole screening processes and satellite production, as demonstrated in SRXPS studies of ferromagnetic Ni. Future directions of SRXPS are also explored. copyright 1996 American Vacuum Society

  5. Time Resolved Studies of Carrier Dynamics in III -v Heterojunction Semiconductors.

    Science.gov (United States)

    Westland, Duncan James

    Available from UMI in association with The British Library. Requires signed TDF. Picosecond time-resolution photoluminescence spectroscopy has been used to study transient processes in Ga _{.47}In_{.53 }As/InP multiple quantum wells (MQWs), and in bulk Ga_{.47}In _{.53}As and GaSb. To facilitate the experimental studies, apparatus was constructed to allow the detection of transient luminescence with 3ps time resolution. A frequency upconversion technique was employed. Relaxation of energetic carriers in bulk Ga _{.47}In_{.53 }As by optic phonons has been investigated, and, at carrier densities ~3 times 10^{18}cm ^{-3} is found to be a considerably slower process than simple theory predicts. The discrepancy is resolved by the inclusion of a non-equilibrium population of longitudinal optic phonons in the theoretical description. Slow energy loss is also observed in a 154A MQW under similar conditions, but carriers are found to relax more quickly in a 14A MQW with a comparable repeat period. The theory of non-equilibrium mode occupation is modified to describe the case of a MQW and is found to agree with experiment. Carrier relaxation in GaSb is studied and the importance of occupation of the L _6 conduction band valley in this material is demonstrated. The ambipolar diffusion of a photoexcited carrier plasma through an InP capping layer was investigated using an optical time-of-flight technique. This experiment also enables the efficiency of carrier capture by a Ga _{.47}In_{.53 }As quantum well to be determined. A capture time of 4ps was found.

  6. 5th Regional Study on Cadastre and Spatial Data Infrastructure

    Directory of Open Access Journals (Sweden)

    Ivica Skender

    2012-12-01

    Full Text Available In the aftermath of the 5th Regional Conference on Cadastre and Spatial Data Infrastructure (Banja Luka and Laktaši, Bosnia and Herzegovina, June 6–8, 2012, the Republic Authority for Geodetic and Property Affairs of the Republic of Srpska and the Federal Administration for Geodetic and Real Property Affairs published the 5th Regional Study on Cadastre and Spatial Data Infrastructure. The study was produced in the frame of the Project INSPIRATION – Spatial Data Infrastructure in the Western Balkans, which is being realized for the benefit and with cooperation of representatives of eight geodetic administrations in the region (Albania, Bosnia and Herzegovina, Montenegro, Croatia, Kosovo, Macedonia, Serbia by consortium led by German company GFA of Hamburg, in cooperation with GDi GISDATA of Zagreb, experts from the Austrian Environmental Agency and German company con terra GmbH and financed from the European Union IPA funding programme for 2010.

  7. Thermo-oxidative degradation study of melt-processed polyethylene and its blend with polyamide using time-resolved rheometry

    CSIR Research Space (South Africa)

    Salehiyan, Reza

    2017-05-01

    Full Text Available Time-resolved mechanical spectroscopy (TRMS) was conducted to study the thermo-oxidative degradation of linear low density polyethylene (LLDPE) samples with different thermal histories and their blends with a polyamide (PA6) in the melt state. Neat...

  8. NO kinetics in pulsed low-pressure nitrogen plasmas studied by time resolved quantum cascade laser absorption spectroscopy

    NARCIS (Netherlands)

    Welzel, S.; Guaitella, O.; Lazzaroni, C.; Pintassilgo, C.; Rousseau, A.; Röpcke, J.

    2011-01-01

    Time-resolved quantum cascade laser absorption spectroscopy at 1897 cm-1 (5.27 µm) has been applied to study the NO(X) kinetics on the micro- and millisecond time scale in pulsed low-pressure N2/NO dc discharges. Experiments have been performed under flowing and static gas conditions to infer the

  9. Developing Baltic cod recruitment models I : Resolving spatial and temporal dynamics of spawning stock and recruitment for cod, herring, and sprat

    DEFF Research Database (Denmark)

    Köster, Fritz; Möllmann, C.; Neuenfeldt, Stefan

    2001-01-01

    The Baltic Sea comprises a heterogeneous oceanographic environment influencing the spatial and temporal potential for reproductive success of cod (Gadus morhua) and sprat (Sprattus sprattus) in the different spawning basins. Hence, to quantify stock and recruitment dynamics, it is necessary......-disaggregated multispecies virtual population analyses (MSVPA) were performed for interacting species cod, herring (Clupea harengus), and sprat in the different subdivisions of the Central Baltic. The MSVPA runs revealed distinct spatial trends in population abundance, spawning biomass, recruitment, and predation...

  10. RESOLVING NEIGHBORHOOD-SCALE AIR TOXICS MODELING: A CASE STUDY IN WILMINGTON, CALIFORNIA

    Science.gov (United States)

    Air quality modeling is useful for characterizing exposures to air pollutants. While models typically provide results on regional scales, there is a need for refined modeling approaches capable of resolving concentrations on the scale of tens of meters, across modeling domains 1...

  11. Compact cryogenic Kerr microscope for time-resolved studies of electron spin transport in microstructures

    NARCIS (Netherlands)

    Rizo, P. J.; Pugzlys, A.; Liu, J.; Reuter, D.; Wieck, A. D.; van der Wal, C. H.; van Loosdrecht, P. H. M.; Pugžlys, A.

    2008-01-01

    A compact cryogenic Kerr microscope for operation in the small volume of high-field magnets is described. It is suited for measurements both in Voigt and Faraday configurations. Coupled with a pulsed laser source, the microscope is used to measure the time-resolved Kerr rotation response of

  12. Angle-resolved photoemission study of NiO and CoO

    International Nuclear Information System (INIS)

    Shen, Z.X.; Lindberg, P.A.P.; Shih, C.K.; Spicer, W.E.; Lindau, I.

    1989-01-01

    The authors report an angle-resolved photoemission investigation of the electronic structures of NiO and CoO. The lattice effects on the photoemission spectra of these highly correlated materials are important. The magnitudes of dispersions of the oxygen bands agree with band calculations, but the experimental data of the localized 3d bands do not agree with the band calculations

  13. Spatial heterogeneity study of vegetation coverage at Heihe River Basin

    Science.gov (United States)

    Wu, Lijuan; Zhong, Bo; Guo, Liyu; Zhao, Xiangwei

    2014-11-01

    Spatial heterogeneity of the animal-landscape system has three major components: heterogeneity of resource distributions in the physical environment, heterogeneity of plant tissue chemistry, heterogeneity of movement modes by the animal. Furthermore, all three different types of heterogeneity interact each other and can either reinforce or offset one another, thereby affecting system stability and dynamics. In previous studies, the study areas are investigated by field sampling, which costs a large amount of manpower. In addition, uncertain in sampling affects the quality of field data, which leads to unsatisfactory results during the entire study. In this study, remote sensing data is used to guide the sampling for research on heterogeneity of vegetation coverage to avoid errors caused by randomness of field sampling. Semi-variance and fractal dimension analysis are used to analyze the spatial heterogeneity of vegetation coverage at Heihe River Basin. The spherical model with nugget is used to fit the semivariogram of vegetation coverage. Based on the experiment above, it is found, (1)there is a strong correlation between vegetation coverage and distance of vegetation populations within the range of 0-28051.3188m at Heihe River Basin, but the correlation loses suddenly when the distance greater than 28051.3188m. (2)The degree of spatial heterogeneity of vegetation coverage at Heihe River Basin is medium. (3)Spatial distribution variability of vegetation occurs mainly on small scales. (4)The degree of spatial autocorrelation is 72.29% between 25% and 75%, which means that spatial correlation of vegetation coverage at Heihe River Basin is medium high.

  14. Time-resolved homo-FRET studies of biotin-streptavidin complexes.

    Science.gov (United States)

    Andreoni, Alessandra; Nardo, Luca; Rigler, Rudolf

    2016-09-01

    Förster resonance energy transfer is a mechanism of fluorescence quenching that is notably useful for characterizing properties of biomolecules and/or their interactions. Here we study water-solutions of Biotin-Streptavidin complexes, in which Biotin is labeled with a rigidly-bound fluorophore that can interact by Förster resonance energy transfer with the fluorophores labeling the other, up to three, Biotins of the same complex. The fluorophore, Atto550, is a Rhodamine analogue. We detect the time-resolved fluorescence decay of the fluorophores with an apparatus endowed with single-photon sensitivity and temporal resolution of ~30ps. The decay profiles we observe for samples containing constant Biotin-Atto550 conjugates and varying Streptavidin concentrations are multi-exponential. Each decay component can be associated with the rate of quenching exerted on each donor by each of the acceptors that label the other Biotin molecules, depending on the binding site they occupy. The main features that lead to this result are that (i) the transition dipole moments of the up-to-four Atto550 fluorophores that label the complexes are fixed as to both relative positions and mutual orientations; (ii) the fluorophores are identical and the role of donor in each Biotin-Streptavidin complex is randomly attributed to the one that has absorbed the excitation light (homo-FRET). Obviously the high-temporal resolution of the excitation-detection apparatus is necessary to discriminate among the fluorescence decay components. Copyright © 2016 Elsevier B.V. All rights reserved.

  15. The Hα line forming region of AB Aurigae spatially resolved at sub-AU with the VEGA/CHARA spectro-interferometer

    Science.gov (United States)

    Rousselet-Perraut, K.; Benisty, M.; Mourard, D.; Rajabi, S.; Bacciotti, F.; Bério, Ph.; Bonneau, D.; Chesneau, O.; Clausse, J. M.; Delaa, O.; Marcotto, A.; Roussel, A.; Spang, A.; Stee, Ph.; Tallon-Bosc, I.; McAlister, H.; ten Brummelaar, T.; Sturmann, J.; Sturmann, L.; Turner, N.; Farrington, C.; Goldfinger, P. J.

    2010-06-01

    Context. A crucial issue in star formation is to understand the physical mechanism by which mass is accreted onto and ejected by a young star. To derive key constraints on the launching point of the jets and on the geometry of the winds, the visible spectro-polarimeter VEGA installed on the CHARA optical array can be an efficient means of probing the structure and the kinematics of the hot circumstellar gas at sub-AU. Aims: For the first time, we observed the Herbig Ae star AB Aur in the Hα emission line, using the VEGA low spectral resolution (R = 1700) on two baselines of the array. Methods: We computed and calibrated the spectral visibilities of AB Aur between 610 nm and 700 nm in spectral bands of 20.4 nm. To simultaneously reproduce the line profile and the inferred visibility around Hα, we used a 1D radiative transfer code (RAMIDUS/PROFILER) that calculates level populations for hydrogen atoms in a spherical geometry and that produces synthetic spectro-interferometric observables. Results: We clearly resolved AB Aur in the Hα line and in a part of the continuum, even at the smallest baseline of 34 m. The small P-Cygni absorption feature is indicative of an outflow but could not be explained by a spherical stellar wind model. Instead, it favors a magneto-centrifugal X-disk or disk-wind geometry. The fit of the spectral visibilities from 610 to 700 nm could not be accounted for by a wind alone, so another component inducing a visibility modulation around Hα needed to be considered. We thus considered a brightness asymmetry possibly caused by large-scale nebulosity or by the known spiral structures. Conclusions: Thanks to the unique capabilities of VEGA, we managed to simultaneously record for the first time a spectrum at a resolution of 1700 and spectral visibilities in the visible range on a target as faint as mV = 7.1. It was possible to rule out a spherical geometry for the wind of AB Aur and provide realistic solutions to account for the Hα emission

  16. Variability of O2, H2S, and pH in intertidal sediments measured on a highly resolved spatial and temporal scale

    Science.gov (United States)

    Walpersdorf, E.; Werner, U.; Bird, P.; de Beer, D.

    2003-04-01

    We investigated the variability of O_2, pH, and H_2S in intertidal sediments to assess the time- and spatial scales of changes in environmental conditions and their effects on bacterial activities. Measurements were performed over the tidal cycle and at different seasons by the use of microsensors attached to an autonomous in-situ measuring device. This study was carried out at a sand- and a mixed flat in the backbarrier area of Spiekeroog (Germany) within the frame of the DFG research group "Biogeochemistry of the Wadden Sea". Results showed that O_2 variability was not pronounced in the coastal mixed flat, where only extreme weather conditions could increase O_2 penetration. In contrast, strong dynamics in O_2 availability, pH and maximum penetration depths of several cm were found at the sandflat. In these highly permeable sediments, we directly observed tidal pumping: at high tide O_2-rich water was forced into the plate and at low tide anoxic porewater drained off the sediment. From the lower part of the plate where organic rich clayey layers were embedded in the sediment anoxic water containing H_2S leaked out during low tide. Thus advective processes, driven by the tidal pump, waves and currents, control O_2 penetration and depth distribution of H_2S and pH. The effects of the resulting porewater exchange on mineralization rates and microbial activities will be discussed.

  17. Chemically-resolved aerosol volatility measurements from two megacity field studies

    Directory of Open Access Journals (Sweden)

    J. A. Huffman

    2009-09-01

    Full Text Available The volatilities of different chemical species in ambient aerosols are important but remain poorly characterized. The coupling of a recently developed rapid temperature-stepping thermodenuder (TD, operated in the range 54–230°C with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS during field studies in two polluted megacities has enabled the first direct characterization of chemically-resolved urban particle volatility. Measurements in Riverside, CA and Mexico City are generally consistent and show ambient nitrate as having the highest volatility of any AMS standard aerosol species while sulfate showed the lowest volatility. Total organic aerosol (OA showed volatility intermediate between nitrate and sulfate, with an evaporation rate of 0.6%·K−1 near ambient temperature, although OA dominates the residual species at the highest temperatures. Different types of OA were characterized with marker ions, diurnal cycles, and positive matrix factorization (PMF and show significant differences in volatility. Reduced hydrocarbon-like OA (HOA, a surrogate for primary OA, POA, oxygenated OA (OOA, a surrogate for secondary OA, SOA, and biomass-burning OA (BBOA separated with PMF were all determined to be semi-volatile. The most aged OOA-1 and its dominant ion, CO2+, consistently exhibited the lowest volatility, with HOA, BBOA, and associated ions for each among the highest. The similar or higher volatility of HOA/POA compared to OOA/SOA contradicts the current representations of OA volatility in most atmospheric models and has important implications for aerosol growth and lifetime. A new technique using the AMS background signal was demonstrated to quantify the fraction of species up to four orders-of-magnitude less volatile than those detectable in the MS mode, which for OA represent ~5% of the non-refractory (NR OA signal. Our results strongly imply that all OA types should be considered

  18. Experimental study of spatial distribution of Ar glow discharge plasma

    International Nuclear Information System (INIS)

    Guo, X.M.; Zhou, T.D.; Pai, S.T.

    1996-01-01

    The characteristics of the spatial distribution of Ar glow discharge plasma were experimentally investigated. By means of direct comparisons between theory and experiment, the effects of the variation of gap separation, gas pressure, and electrode radius on the spatial distributions of electron density and electric field were studied. Results indicate that the maximum electron density moves toward the cathode as the gap separation or gas pressure increases while variation of electrode radius produces little effect. Predictions from a theoretical model have been experimentally verified. General agreements between theory and experiment were found to be reasonably good except in the cathode region, where discrepancy exists. copyright 1996 American Institute of Physics

  19. Band structures of 4f and 5f materials studied by angle-resolved photoelectron spectroscopy.

    Science.gov (United States)

    Fujimori, Shin-ichi

    2016-04-20

    Recent remarkable progress in angle-resolved photoelectron spectroscopy (ARPES) has enabled the direct observation of the band structures of 4f and 5f materials. In particular, ARPES with various light sources such as lasers (hν ~ 7 eV) or high-energy synchrotron radiations (hν >/~ 400 eV) has shed light on the bulk band structures of strongly correlated materials with energy scales of a few millielectronvolts to several electronvolts. The purpose of this paper is to summarize the behaviors of 4f and 5f band structures of various rare-earth and actinide materials observed by modern ARPES techniques, and understand how they can be described using various theoretical frameworks. For 4f-electron materials, ARPES studies of CeMIn5(M = Rh, Ir, and Co) and YbRh2Si2 with various incident photon energies are summarized. We demonstrate that their 4f electronic structures are essentially described within the framework of the periodic Anderson model, and that the band-structure calculation based on the local density approximation cannot explain their low-energy electronic structures. Meanwhile, electronic structures of 5f materials exhibit wide varieties ranging from itinerant to localized states. For itinerant U5f compounds such as UFeGa5, their electronic structures can be well-described by the band-structure calculation assuming that all U5f electrons are itinerant. In contrast, the band structures of localized U5f compounds such as UPd3 and UO2 are essentially explained by the localized model that treats U5f electrons as localized core states. In regards to heavy fermion U-based compounds such as the hidden-order compound URu2Si2, their electronic structures exhibit complex behaviors. Their overall band structures are generally well-explained by the band-structure calculation, whereas the states in the vicinity of EF show some deviations due to electron correlation effects. Furthermore, the electronic structures of URu2Si2 in the paramagnetic and hidden-order phases are

  20. Time resolved spectroscopic investigation of SiD2 + D2: kinetic study

    Science.gov (United States)

    Al-Rubaiey, Najem A.; Walsh, Robin

    2017-03-01

    Silylenes (silanediyls) have made an important impact on organosilicon chemistry even if it is of more recent foundation than carbenes in organic chemistry and much less complete. These species are highly reactive intermediates. They play a central role in the chemical vapour deposition (CVD) of various silicon-containing thin films which have a technological importance in microelectronics as well as in the dry etching processes of silicon wafers. Spectroscopic methods have been developed to observe these species, a necessary pre-requisite to their direct monitoring. In this work, deuterated phenylsilane precursor, PhSiD3 was chosen for SiD2 because its analogue phenylsilane, PhSiH3 proved to be a good precursor for SiH2 and the high quality decay signals observed revealed that SiD2 be readily detected from PhSiD3 and that if other decomposition pathways (e.g. PhSiD + D2) are occurring, they do not effect measurements of the rate constants for SiD2. The absorption spectrum of SiD2 formed from the flash photolysis of a mixture of PhSiD3 and SF6 at 193nm were found in the region 17384-17391 cm-1 with strong band at 17387.07 cm-1. This single rotational line of pQ1 was chosen to monitor SiD2 removal. Time-resolved studies of SiD2 have been carried out to obtain rate constants for its bimolecular reactions with D2. The reactions were studied over the pressure range 5-100 Torr (in SF6 bath gas) at four temperatures in the range 298-498K. Single decay from 10 photolysis laser shots were averaged and found to give reasonable first-order kinetics fits. Second order kinetics were obtained by pressure dependence of the pseudo first order decay constants and substance D2 pressures within experimental error. The reaction was found to be weakly pressure dependent at all temperatures, consistent with a third-body mediated association process. In addition, SiH2+ H2 reaction is approximately ca. 60% faster than SiD2+D2 reaction. Theoretical extrapolations (using Lindemann

  1. Time resolved spectroscopic investigation of SiD2 + D2: kinetic study

    Directory of Open Access Journals (Sweden)

    Al-Rubaiey Najem A.

    2017-01-01

    Full Text Available Silylenes (silanediyls have made an important impact on organosilicon chemistry even if it is of more recent foundation than carbenes in organic chemistry and much less complete. These species are highly reactive intermediates. They play a central role in the chemical vapour deposition (CVD of various silicon-containing thin films which have a technological importance in microelectronics as well as in the dry etching processes of silicon wafers. Spectroscopic methods have been developed to observe these species, a necessary pre-requisite to their direct monitoring. In this work, deuterated phenylsilane precursor, PhSiD3 was chosen for SiD2 because its analogue phenylsilane, PhSiH3 proved to be a good precursor for SiH2 and the high quality decay signals observed revealed that SiD2 be readily detected from PhSiD3 and that if other decomposition pathways (e.g. PhSiD + D2 are occurring, they do not effect measurements of the rate constants for SiD2. The absorption spectrum of SiD2 formed from the flash photolysis of a mixture of PhSiD3 and SF6 at 193nm were found in the region 17384-17391 cm-1 with strong band at 17387.07 cm-1. This single rotational line of pQ1 was chosen to monitor SiD2 removal. Time-resolved studies of SiD2 have been carried out to obtain rate constants for its bimolecular reactions with D2. The reactions were studied over the pressure range 5-100 Torr (in SF6 bath gas at four temperatures in the range 298-498K. Single decay from 10 photolysis laser shots were averaged and found to give reasonable first-order kinetics fits. Second order kinetics were obtained by pressure dependence of the pseudo first order decay constants and substance D2 pressures within experimental error. The reaction was found to be weakly pressure dependent at all temperatures, consistent with a third-body mediated association process. In addition, SiH2+ H2 reaction is approximately ca. 60% faster than SiD2+D2 reaction. Theoretical extrapolations (using

  2. Spatial memory extinction: a c-Fos protein mapping study.

    Science.gov (United States)

    Méndez-Couz, M; Conejo, N M; Vallejo, G; Arias, J L

    2014-03-01

    While the neuronal basis of spatial memory consolidation has been thoroughly studied, the substrates mediating the process of extinction remain largely unknown. This study aimed to evaluate the functional contribution of selected brain regions during the extinction of a previously acquired spatial memory task in the Morris water maze. For that purpose, we used adult male Wistar rats trained in a spatial reference memory task. Learning-related changes in c-Fos inmunoreactive cells after training were evaluated in cortical and subcortical regions. Results show that removal of the hidden platform in the water maze induced extinction of the previously reinforced escape behavior after 16 trials, without spontaneous recovery 24h later. Extinction was related with significantly higher numbers of c-Fos positive nuclei in amygdala nuclei and prefrontal cortex. On the other hand, the lateral mammillary bodies showed higher number of c-Fos positive cells than the control group. Therefore, in contrast with the results obtained in studies of classical conditioning, we show the involvement of diencephalic structures mediating this kind of learning. In summary, our findings suggest that medial prefrontal cortex, the amygdala complex and diencephalic structures like the lateral mammillary nuclei are relevant for the extinction of spatial memory. Copyright © 2013 Elsevier B.V. All rights reserved.

  3. Spatial Temporal Modelling of Particulate Matter for Health Effects Studies

    Science.gov (United States)

    Hamm, N. A. S.

    2016-10-01

    Epidemiological studies of the health effects of air pollution require estimation of individual exposure. It is not possible to obtain measurements at all relevant locations so it is necessary to predict at these space-time locations, either on the basis of dispersion from emission sources or by interpolating observations. This study used data obtained from a low-cost sensor network of 32 air quality monitoring stations in the Dutch city of Eindhoven, which make up the ILM (innovative air (quality) measurement system). These stations currently provide PM10 and PM2.5 (particulate matter less than 10 and 2.5 m in diameter), aggregated to hourly means. The data provide an unprecedented level of spatial and temporal detail for a city of this size. Despite these benefits the time series of measurements is characterized by missing values and noisy values. In this paper a space-time analysis is presented that is based on a dynamic model for the temporal component and a Gaussian process geostatistical for the spatial component. Spatial-temporal variability was dominated by the temporal component, although the spatial variability was also substantial. The model delivered accurate predictions for both isolated missing values and 24-hour periods of missing values (RMSE = 1.4 μg m-3 and 1.8 μg m-3 respectively). Outliers could be detected by comparison to the 95% prediction interval. The model shows promise for predicting missing values, outlier detection and for mapping to support health impact studies.

  4. Investigation of local thermodynamic equilibrium of laser induced Al2O3–TiC plasma in argon by spatially resolved optical emission spectroscopy

    Directory of Open Access Journals (Sweden)

    K. Alnama

    2016-06-01

    Full Text Available Plasma plume of Al2O3–TiC is generated by third harmonic Q-switched Nd:YAG nanosecond laser. It is characterized using Optical Emission Spectroscopy (OES at different argon background gas pressures 10, 102, 103, 104 and 105 Pa. Spatial evolution of excitation and ionic temperatures is deduced from spectral data analysis. Temporal evolution of Ti I emission originated from different energy states is probed. The correlation between the temporal behavior and the spatial temperature evolution are investigated under LTE condition for the possibility to use the temporal profile of Ti I emission as an indicator for LTE validity in the plasma.

  5. A synchrotron radiation camera and data acquisition system for time resolved x-ray scattering studies

    International Nuclear Information System (INIS)

    Bordas, J.; Koch, M.H.J.; Clout, P.N.; Dorrington, E.; Boulin, C.; Gabriel, A.

    1980-01-01

    Until recently, time resolved measurements of x-ray scattering patterns have not been feasible because laboratory x-ray sources were too weak and detectors unavailable. Recent developments in both these fields have changed the situation, and it is now possible to follow changes in x-ray scattering patterns with a time resolution of a few ms. The apparatus used to achieve this is described and some examples from recent biological experiments are given. (author)

  6. Charge transport in nanostructured materials for solar energy conversion studied by time-resolved terahertz spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Němec, Hynek; Kužel, Petr; Sundström, V.

    2010-01-01

    Roč. 215, 2-3 (2010), s. 123-139 ISSN 1010-6030 R&D Projects: GA ČR(CZ) GP202/09/P099; GA AV ČR(CZ) IAA100100902; GA MŠk LC512 Institutional research plan: CEZ:AV0Z10100520 Keywords : time-resolved terahertz spectroscopy * ultrafast dynamics * bulk heterojunction * semiconductor nanostructures * transport * mobility Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.243, year: 2010

  7. Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Motokawa, Ryuhei [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan); Koizumi, Satoshi [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan)]. E-mail: koizumi@neutrons.tokai.jaeri.go.jp; Hashimoto, Takeji [Research Group of Soft Matter and Neutron Scattering, Advanced Science Research Center, Japan Atomic Energy Research Institute, Tokai, Ibaraki 319-1195 (Japan); Nakahira, Takayuki [Department of Applied Chemistry and Biotechnology, Chiba University, Chiba-shi, Chiba 263-8522 (Japan); Annaka, Masahiko [Department of Chemistry, Kyushu University, Fukuoka 812-8581 (Japan)

    2006-11-15

    We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.

  8. Electronic structure of Sr2RuO4 studied by angle-resolved photoemission spectroscopy

    International Nuclear Information System (INIS)

    Iwasawa, H.; Aiura, Y.; Saitoh, T.; Yoshida, Y.; Hase, I.; Ikeda, S.I.; Bando, H.; Kubota, M.; Ono, K.

    2007-01-01

    Electronic structure of the monolayer strontium ruthenate Sr 2 RuO 4 was investigated by high-resolution angle-resolved photoemission spectroscopy. We present photon-energy (hν) dependence of the electronic structure near the Fermi level along the ΓM line. The hν dependence has shown a strong spectral weight modulation of the Ru 4d xy and 4d zx bands

  9. Two-dimensional J-resolved nuclear magnetic resonance spectral study of two bromobenzene glutathione conjugates

    Energy Technology Data Exchange (ETDEWEB)

    Ferretti, J.A.; Highet, R.J.; Pohl, L.R.; Monks, T.J.; Hinson, J.A.

    1985-09-01

    The application of two-dimensional J-resolved nuclear magnetic resonance spectroscopy to determine the structure of two bile metabolites isolated from rats injected interperitoneally with bromobenzene is described. The structures of the two molecules are obtained unambiguously from the proton-proton spin coupling constants. The paper discusses the fundamentals of the technique and demonstrates the resolution of small long-range coupling constants.

  10. Evaluating scintillator performance in time-resolved hard X-ray studies at synchrotron light sources.

    Science.gov (United States)

    Rutherford, Michael E; Chapman, David J; White, Thomas G; Drakopoulos, Michael; Rack, Alexander; Eakins, Daniel E

    2016-05-01

    The short pulse duration, small effective source size and high flux of synchrotron radiation is ideally suited for probing a wide range of transient deformation processes in materials under extreme conditions. In this paper, the challenges of high-resolution time-resolved indirect X-ray detection are reviewed in the context of dynamic synchrotron experiments. In particular, the discussion is targeted at two-dimensional integrating detector methods, such as those focused on dynamic radiography and diffraction experiments. The response of a scintillator to periodic synchrotron X-ray excitation is modelled and validated against experimental data collected at the Diamond Light Source (DLS) and European Synchrotron Radiation Facility (ESRF). An upper bound on the dynamic range accessible in a time-resolved experiment for a given bunch separation is calculated for a range of scintillators. New bunch structures are suggested for DLS and ESRF using the highest-performing commercially available crystal LYSO:Ce, allowing time-resolved experiments with an interframe time of 189 ns and a maximum dynamic range of 98 (6.6 bits).

  11. Time-resolved EPR study of singlet oxygen in the gas phase.

    Science.gov (United States)

    Ruzzi, Marco; Sartori, Elena; Moscatelli, Alberto; Khudyakov, Igor V; Turro, Nicholas J

    2013-06-27

    X-band EPR spectra of singlet O2((1)Δg) and triplet O2((3)Σg(-)) were observed in the gas phase under low molecular-oxygen pressures PO2 = 0.175-0.625 Torr, T = 293-323 K. O2((1)Δg) was produced by quenching of photogenerated triplet sensitizers naphthalene C8H10, perdeuterated naphthalene, and perfluoronaphthalene in the gas phase. The EPR spectrum of O2((1)Δg) was also observed under microwave discharge. Integrated intensities and line widths of individual components of the EPR spectrum of O2((3)Σg(-)) were used as internal standards for estimating the concentration of O2 species and PO2 in the EPR cavity. Time-resolved (TR) EPR experiments of C8H10 were the main focus of this Article. Pulsed irradiation of C8H10 in the presence of O2((3)Σg(-)) allowed us to determine the kinetics of formation and decay for each of the four components of the O2((1)Δg) EPR signal, which lasted for only a few seconds. We found that the kinetics of EPR-component decay fit nicely to a biexponential kinetics law. The TR EPR 2D spectrum of the third component of the O2((1)Δg) EPR spectrum was examined in experiments using C8H10. This spectrum vividly presents the time evolution of an EPR component. The largest EPR signal and the longest lifetime of O2((1)Δg), τ = 0.4 s, were observed at medium pressure PO2 = 0.4 Torr, T = 293 K. The mechanism of O2((1)Δg) decay in the presence of photosensitizers is discussed. EPR spectra of O2((1)Δg) evidence that the spin-rotational states of O2((1)Δg) are populated according to Boltzmann distribution in the studied time range of 10-100 ms. We believe that this is the first report dealing with the dependence of O2((1)Δg) EPR line width on PO2 and T.

  12. Study of spatial resolution in three-dimensional rotational angiography

    International Nuclear Information System (INIS)

    Enoki, Takuya; Nasada, Toshiya; Matsumoto, Kazuma; Umehara, Takayoshi

    2006-01-01

    In interventional radiology (IVR) of cerebral aneurysms, it is important to understand the form and physical relationships between the cerebral aneurysm and the surrounding vessels. However, because the vessels in the head area are highly complex, it can be difficult to comprehend the structure using conventional angiography. Therefore, three-dimensional rotational angiography (3D-RA) has been used in recent years. This article discusses studies of the spatial resolution of 3D-RA. We reconstructed 3D-RA of an acrylic slit phantom (slit widths: 0.5, 0.75, 1.0, 1.5 mm) and examined spatial resolution by visual evaluation and profile curves. When the slit phantom was arranged to avoid the effect of beam hardening, the spatial resolution of 3D-RA was found to be as high as 0.75 mm. When the slit phantom was placed orthogonal to the rotational axis of the C-arm, the spatial resolution of 3D-RA was decreased because of the cone angle effect of X-rays. However, it was considered within the allowable range for clinical study. Consequently, 3D-RA is valuable in IVR. (author)

  13. Spatially resolved RNA-sequencing of the embryonic heart identifies a role for Wnt/β-catenin signaling in autonomic control of heart rate

    Science.gov (United States)

    Burkhard, Silja Barbara

    2018-01-01

    Development of specialized cells and structures in the heart is regulated by spatially -restricted molecular pathways. Disruptions in these pathways can cause severe congenital cardiac malformations or functional defects. To better understand these pathways and how they regulate cardiac development we used tomo-seq, combining high-throughput RNA-sequencing with tissue-sectioning, to establish a genome-wide expression dataset with high spatial resolution for the developing zebrafish heart. Analysis of the dataset revealed over 1100 genes differentially expressed in sub-compartments. Pacemaker cells in the sinoatrial region induce heart contractions, but little is known about the mechanisms underlying their development. Using our transcriptome map, we identified spatially restricted Wnt/β-catenin signaling activity in pacemaker cells, which was controlled by Islet-1 activity. Moreover, Wnt/β-catenin signaling controls heart rate by regulating pacemaker cellular response to parasympathetic stimuli. Thus, this high-resolution transcriptome map incorporating all cell types in the embryonic heart can expose spatially restricted molecular pathways critical for specific cardiac functions. PMID:29400650

  14. Spatial resolution limit study of a CCD camera and scintillator based neutron imaging system according to MTF determination and analysis

    International Nuclear Information System (INIS)

    Kharfi, F.; Denden, O.; Bourenane, A.; Bitam, T.; Ali, A.

    2012-01-01

    Spatial resolution limit is a very important parameter of an imaging system that should be taken into consideration before examination of any object. The objectives of this work are the determination of a neutron imaging system's response in terms of spatial resolution. The proposed procedure is based on establishment of the Modulation Transfer Function (MTF). The imaging system being studied is based on a high sensitivity CCD neutron camera (2×10 −5 lx at f1.4). The neutron beam used is from the horizontal beam port (H.6) of the Algerian Es-Salam research reactor. Our contribution is on the MTF determination by proposing an accurate edge identification method and a line spread function undersampling problem-resolving procedure. These methods and procedure are integrated into a MatLab code. The methods, procedures and approaches proposed in this work are available for any other neutron imaging system and allow for judging the ability of a neutron imaging system to produce spatial (internal details) properties of any object under examination. - Highlights: ► Determination of spatial response of a neutron imaging system. ► Ability of a neutron imaging system to reproduce spatial properties of any object. ► Spatial resolution limits measurement using MTF with the slanted edge method. ► Accurate edge identification and line spread function sampling improvement. ► Development of a MatLab code to compute automatically the MTF.

  15. Theoretical study of the femtosecond-resolved photoelectron spectrum of the NO molecule

    International Nuclear Information System (INIS)

    Meng Qingtian; Yang Guanghui; Sun Hailin; Han Keli; Lou Nanquan

    2003-01-01

    The effect of laser fields on the NO interaction potentials is obtained by the calculation of time-resolved photoelectron spectrum (TRPES) using the time-dependent wave-packet method. The calculation not only shows that the overlap of the pump-probe pulses makes some NO molecular 'invisible' states visible, but also that the coupling strength and the positions of relevant curves change on increasing the laser intensity. These changed potentials affect their dynamical behavior and influence the shape and position of each peak in TRPES. That the coupling strength of relevant potentials can be changed by the field-matter interaction is consistent with our ab initio calculations

  16. Time-resolved fluorescence quenching studies of sodium lauryl ether sulfate micelles

    OpenAIRE

    Friedrich, Leidi C.; Silva, Volnir O.; Moreira Jr, Paulo F.; Tcacenco, Celize M.; Quina, Frank H.

    2013-01-01

    Aggregation numbers (N Ag) of micelles of the commercial anionic detergent sodium lauryl ether sulfate (SLES), with an average of two ethylene oxide subunits, were determined at 30 and 40º C by the time-resolved fluorescence quenching method with pyrene as the fluorescent probe and the N-hexadecylpyridinium ion as the quencher. The added-salt dependent growth of SLES micelles (γ = 0.11-0.15, where γ is the slope of a plot of log aggregation number vs. log [Yaq] and [Yaq] is the sodium counter...

  17. Time-resolved study of formate on Ni( 1 1 1 ) by picosecond SFG spectroscopy

    Science.gov (United States)

    Kusafuka, K.; Noguchi, H.; Onda, K.; Kubota, J.; Domen, K.; Hirose, C.; Wada, A.

    2002-04-01

    Time-resolved vibrational measurements were carried out on formate (HCOO) adsorbed on Ni(1 1 1) surface by combining the sum-frequency generation method and picosecond laser system (time resolution of 6 ps). Rapid intensity decrease (within the time resolution) followed by intensity recovery (time constant of several tens of ps) of CH stretching signal was observed when picosecond 800 nm pulse was irradiated on the sample surface. From the results of temperature and pump fluence dependences of temporal behaviour of signal intensity, we concluded that the observed intensity change was induced by non-thermal process. Mechanism of the temporal intensity change was discussed.

  18. Gas Chromatograph Method Optimization Trade Study for RESOLVE: 20-meter Column v. 8-meter Column

    Science.gov (United States)

    Huz, Kateryna

    2014-01-01

    RESOLVE is the payload on a Class D mission, Resource Prospector, which will prospect for water and other volatile resources at a lunar pole. The RESOLVE payload's primary scientific purpose includes determining the presence of water on the moon in the lunar regolith. In order to detect the water, a gas chromatograph (GC) will be used in conjunction with a mass spectrometer (MS). The goal of the experiment was to compare two GC column lengths and recommend which would be best for RESOLVE's purposes. Throughout the experiment, an Inficon Fusion GC and an Inficon Micro GC 3000 were used. The Fusion had a 20m long column with 0.25mm internal diameter (Id). The Micro GC 3000 had an 8m long column with a 0.32mm Id. By varying the column temperature and column pressure while holding all other parameters constant, the ideal conditions for testing with each column length in their individual instrument configurations were determined. The criteria used for determining the optimal method parameters included (in no particular order) (1) quickest run time, (2) peak sharpness, and (3) peak separation. After testing numerous combinations of temperature and pressure, the parameters for each column length that resulted in the most optimal data given my three criteria were selected. The ideal temperature and pressure for the 20m column were 95 C and 50psig. At this temperature and pressure, the peaks were separated and the retention times were shorter compared to other combinations. The Inficon Micro GC 3000 operated better at lower temperature mainly due to the shorter 8m column. The optimal column temperature and pressure were 70 C and 30psig. The Inficon Micro GC 3000 8m column had worse separation than the Inficon Fusion 20m column, but was able to separate water within a shorter run time. Therefore, the most significant tradeoff between the two column lengths was peak separation of the sample versus run time. After performing several tests, it was concluded that better

  19. The Spatial Variability of Beryllium-7 Depth Distribution Study

    International Nuclear Information System (INIS)

    Jalal Sharib; Zainudin Othman; Dainee Nor Fardzila Ahmad Tugi; Noor Fadzilah Yusof; Mohd Tarmizi Ishak

    2015-01-01

    The objective of this paper is to study the spatial variability of 7 Be depth evolution in soil profile at two different sampling sites. The soil samples have been collected by using metal core in bare area in Bangi, Selangor and Timah Tasoh, Perlis , Malaysia. Two composite core samples for each sampling sites has been sectioned into 2 mm increments to a depth of 4 cm and oven dried at 45- 60 degree Celsius and gently desegregated. These two composite spatial samples are passed through a < 2 mm sieve and packed into proper geometry plastic container for 7 Be analysis by using gamma spectrometry with a 24-hour count time. From the findings, the 7 Be content in the soil samples from Bangi, Selangor study area is distributed lower depth penetration into the soil profile than Timah Tasoh, Perlis catchment due to many factors such as precipitation (fallout) and others. However, the spatial variability from both samples study area is also decreases exponentially with depth and is confined within the top few centimeters and similar with other works been reported (Blake et al., (2000) and Walling et al.,(2008). Furthermore, a detailed discussion from this study findings will be in full papers. (author)

  20. Longitudinal study of spatial working memory development in young children.

    Science.gov (United States)

    Tsujii, Takeo; Yamamoto, Eriko; Masuda, Sayako; Watanabe, Shigeru

    2009-05-27

    This study longitudinally compared activity in the frontal cortex during a spatial working memory task between 5-year-old and 7-year-old children using near-infrared spectroscopy. Eight children participated in this study twice, once at 5 years and once at 7 years of age. Behavioral analysis showed that older children performed the working memory task more precisely and more rapidly than younger children. Near-infrared spectroscopy analysis showed that right hemisphere dominance was observed in older children, whereas no hemispheric difference was apparent in younger children. Children with strengthened lateralization showed improved performance from 5 to 7 years. We therefore offer the first demonstration of the developmental changes in frontal cortical activation during spatial working memory tasks during the preschool period.

  1. Time-resolved studies of ultrarapid solidification of highly undercooled molten silicon formed by pulsed laser irradiation

    International Nuclear Information System (INIS)

    Lowndes, D.H.; Jellison, G.E. Jr.; Wood, R.F.; Carpenter, R.

    1984-01-01

    This paper reports new results of nanosecond-resolution time-resolved optical reflectivity measurements, during pulsed excimer (KrF, 248 nm) laser irradiation of Si-implanted amorphous (a) silicon layers, which, together with model calculations and post-irradiation TEM measurements, have allowed us to study both the transformation of a-Si to a highly undercooled liquid (l) phase and the subsequent ultrarapid solidification process

  2. Spatial Visualization ability improves with and without studying Technical Drawing.

    Science.gov (United States)

    Contreras, María José; Escrig, Rebeca; Prieto, Gerardo; Elosúa, M Rosa

    2018-03-27

    The results of several studies suggest that spatial ability can be improved through direct training with tasks similar to those integrated in the tests used to measure the ability. However, there is a greater interest in analyzing the effectiveness of indirect training such as games or of learning subjects that involve spatial processes to a certain extent. Thus, the objective of the present study was to analyze whether the indirect training in Technical Drawing improved the Spatial Visualization ability of Architecture students. For this purpose, a group of students enrolled in Fundamentals of Architecture were administered two tests, a Spatial Visualization task and an Abstract Reasoning task, at the beginning and the end of a semester, after having received training through the subjects "Technical Drawing I: Geometry and Perception" and "Projects I." The results of this group were compared with those of a control group of students enrolled in a Mathematics degree, who were also pre-post evaluated but had not received the training in Technical Drawing. The study showed a significant pre-post improvement in both, Visualization and reasoning. However, this improvement occurred in both groups, thereby concluding that this improvement was not due to indirect training. Furthermore, no significant differences were found between men and women in any of the groups or conditions. These results clarify those of an earlier study where improvement in Visualization after training in Technical Drawing was found but did not include a comparison with a control condition. The control condition has proved to be important in order to consider the limitations of the effect of Technical Drawing on said improvement.

  3. Spin resolved electronic transport through N@C20 fullerene molecule between Au electrodes: A first principles study

    Science.gov (United States)

    Caliskan, Serkan

    2018-05-01

    Using first principles study, through Density Functional Theory combined with Non Equilibrium Green's Function Formalism, electronic properties of endohedral N@C20 fullerene molecule joining Au electrodes (Au-N@C20) was addressed in the presence of spin property. The electronic transport behavior across the Au-N@C20 molecular junction was investigated by spin resolved transmission, density of states, molecular orbitals, differential conductance and current-voltage (I-V) characteristics. Spin asymmetric variation was clearly observed in the results due to single N atom encapsulated in the C20 fullerene cage, where the N atom played an essential role in the electronic behavior of Au-N@C20. This N@C20 based molecular bridge, exhibiting a spin dependent I-V variation, revealed a metallic behavior within the bias range from -1 V to 1 V. The induced magnetic moment, spin polarization and other relevant quantities associated with the spin resolved transport were elucidated.

  4. Multimodal MSI in Conjunction with Broad Coverage Spatially Resolved MS2 Increases Confidence in Both Molecular Identification and Localization

    Energy Technology Data Exchange (ETDEWEB)

    Veličković, Dušan; Chu, Rosalie K.; Carrell, Alyssa A. [Biosciences; Thomas, Mathew; Paša-Tolić, Ljiljana; Weston, David J. [Biosciences; Anderton, Christopher R.

    2017-12-18

    One critical aspect of mass spectrometry imaging (MSI) is the need to confidently identify detected analytes. While orthogonal tandem MS (e.g., LC-MS2) experiments from sample extracts can assist in annotating ions, the spatial information about these molecules is lost. Accordingly, this could cause mislead conclusions, especially in cases where isobaric species exhibit different distributions within a sample. In this Technical Note, we employed a multimodal imaging approach, using matrix assisted laser desorption/ionization (MALDI)-MSI and liquid extraction surface analysis (LESA)-MS2I, to confidently annotate and One critical aspect of mass spectrometry imaging (MSI) is the need to confidently identify detected analytes. While orthogonal tandem MS (e.g., LC-MS2) experiments from sample extracts can assist in annotating ions, the spatial information about these molecules is lost. Accordingly, this could cause mislead conclusions, especially in cases where isobaric species exhibit different distributions within a sample. In this Technical Note, we employed a multimodal imaging approach, using matrix assisted laser desorption/ionization (MALDI)-MSI and liquid extraction surface analysis (LESA)-MS2I, to confidently annotate and localize a broad range of metabolites involved in a tripartite symbiosis system of moss, cyanobacteria, and fungus. We found that the combination of these two imaging modalities generated very congruent ion images, providing the link between highly accurate structural information onfered by LESA and high spatial resolution attainable by MALDI. These results demonstrate how this combined methodology could be very useful in differentiating metabolite routes in complex systems.

  5. ScatterJn: An ImageJ Plugin for Scatterplot-Matrix Analysis and Classification of Spatially Resolved Analytical Microscopy Data

    Directory of Open Access Journals (Sweden)

    Fabian Zeitvogel

    2016-02-01

    Full Text Available We present ScatterJn, an ImageJ (and Fiji plugin for scatterplot-based exploration and analysis of analytical microscopy data. In contrast to commonly used scatterplot tools, it handles more than two input images (or image stacks, respectively by creating a matrix of pairwise scatterplots. The tool offers the possibility to manually classify pixels by selecting regions of datapoints in the scatterplots as well as in the spatial domain. We demonstrate its functioning using a set of elemental maps acquired by SEM-EDX mapping of a soil sample. The plugin is available at https://savannah.nongnu.org/projects/scatterjn.

  6. Angle-resolved photoemission studies of the superconducting gap symmetry in Fe-based superconductors

    Directory of Open Access Journals (Sweden)

    Y.-B. Huang

    2012-12-01

    Full Text Available The superconducting gap is the fundamental parameter that characterizes the superconducting state, and its symmetry is a direct consequence of the mechanism responsible for Cooper pairing. Here we discuss about angle-resolved photoemission spectroscopy measurements of the superconducting gap in the Fe-based high-temperature superconductors. We show that the superconducting gap is Fermi surface dependent and nodeless with small anisotropy, or more precisely, a function of the momentum location in the Brillouin zone. We show that while this observation seems inconsistent with weak coupling approaches for superconductivity in these materials, it is well supported by strong coupling models and global superconducting gaps. We also suggest that a smaller lifetime of the superconducting Cooper pairs induced by the momentum dependent interband scattering inherent to these materials could affect the residual density of states at low energies, which is critical for a proper evaluation of the superconducting gap.

  7. High Resolution Angle Resolved Photoemission Studies on Quasi-Particle Dynamics in Graphite

    Energy Technology Data Exchange (ETDEWEB)

    Leem, C.S.

    2010-06-02

    We obtained the spectral function of the graphite H point using high resolution angle resolved photoelectron spectroscopy (ARPES). The extracted width of the spectral function (inverse of the photo-hole lifetime) near the H point is approximately proportional to the energy as expected from the linearly increasing density of states (DOS) near the Fermi energy. This is well accounted by our electron-phonon coupling theory considering the peculiar electronic DOS near the Fermi level. And we also investigated the temperature dependence of the peak widths both experimentally and theoretically. The upper bound for the electron-phonon coupling parameter is 0.23, nearly the same value as previously reported at the K point. Our analysis of temperature dependent ARPES data at K shows that the energy of phonon mode of graphite has much higher energy scale than 125K which is dominant in electron-phonon coupling.

  8. Thin film growth studies using time-resolved x-ray scattering

    Science.gov (United States)

    Kowarik, Stefan

    2017-02-01

    Thin-film growth is important for novel functional materials and new generations of devices. The non-equilibrium growth physics involved is very challenging, because the energy landscape for atomic scale processes is determined by many parameters, such as the diffusion and Ehrlich-Schwoebel barriers. We review the in situ real-time techniques of x-ray diffraction (XRD), x-ray growth oscillations and diffuse x-ray scattering (GISAXS) for the determination of structure and morphology on length scales from Å to µm. We give examples of time resolved growth experiments mainly from molecular thin film growth, but also highlight growth of inorganic materials using molecular beam epitaxy (MBE) and electrochemical deposition from liquids. We discuss how scaling parameters of rate equation models and fundamental energy barriers in kinetic Monte Carlo methods can be determined from fits of the real-time x-ray data.

  9. Isotope effect on hydrated electron relaxation dynamics studied with time-resolved liquid jet photoelectron spectroscopy

    Science.gov (United States)

    Elkins, Madeline H.; Williams, Holly L.; Neumark, Daniel M.

    2016-05-01

    The excited state relaxation dynamics of the solvated electron in H2O and D2O are investigated using time-resolved photoelectron spectroscopy in a liquid microjet. The data show that the initial excited state decays on a time scale of 75 ± 12 fs in H2O and 102 ± 8 fs in D2O, followed by slower relaxation on time scales of 400 ± 70 fs and 390 ± 70 fs that are isotopically invariant within the precision of our measurements. Based on the time evolution of the transient signals, the faster and slower time constants are assigned to p → s internal conversion (IC) of the hydrated electron and relaxation on the ground electronic state, respectively. This assignment is consistent with the non-adiabatic mechanism for relaxation of the hydrated electron and yields an isotope effect of 1.4 ± 0.2 for IC of the hydrated electron.

  10. Time resolved photoluminescence studies of long lived emissive specie in F8BT:PFB blends

    Science.gov (United States)

    Gélinas, Simon; Howard, Ian; Friend, Richard; Silva, Carlos

    2009-03-01

    Type-II heterojunctions play a crucial role in organic optoelectronic devices. We use donor-acceptor polyfluorene blends as a model system to understand excited-state dynamics at heterojunctions. These interfacial excitations are intrachain singlet and triplet excitons, geminate polaron pairs, and exciplexes (interfacial charge-transfer excitons). Time-resolved photoluminescence (PL) spectra were taken at 10,and room temperature to investigate the interconversion dynamics of these species. We observe delayed PL with sub-linear excitation fluence dependence. This implies that delayed singlet exciton generation involves a bimolecular annihilation mechanism. By means of kinetic modeling, we propose triplet-triplet exciton annihilation as a regeneration route to singlet excitons, and subsequently to exciplexes. This points to a significant (<15,%) yield of triplet excitons after interfacial charge separation, and to the central role of these species on the interfacial dynamics.

  11. Studying electron distributions using the time-resolved free-bound spectra from coronal plasmas

    International Nuclear Information System (INIS)

    Matthews, D.L.; Kauffman, R.L.; Kilkenny, J.D.; Lee, R.W.

    1982-11-01

    Absorption of laser light in a plasma by inverse bremsstrahlung, I.B., can lead to a non-Maxwellian velocity distribution provided the electron-elecron collision frequency is too low to equilibrate the velocity distribution in the coronal plasma region of a laser heated aluminum disk by measuring the radiation recombination continuum. The experiments are performed using lambda/sub L/ = 0.532 μm laser light at intensities of approx. 10 16 W/cm 2 . Such parameters are predicted to produce conditions suitable for a non-thermal electron distribution. The shape of the K-shell recombination radiation has been measured using a time-resolved x-ray spectrograph. The electron distribution can be determined from deconvolution of the recombination continuum shape

  12. Metalation of positively charged water soluble mesoporphyrins studied via time-resolved SERRS spectroscopy

    Science.gov (United States)

    Procházka, Marek; Hanzliková, Jana; Štěpánek, Josef; Baumruk, Vladimir

    1997-06-01

    Time-resolved SERRS spectra of 5,10,15,20-tetrakis[4-(trimethylammonio)phenyl]21 H,23 H-porphine (TMAP) were recorded (using a multichannel Raman spectrometer) in various SERS-active Ag colloid/porphyrin systems. Data treatment based on a factor analysis was used to decompose all the SERRS spectra into two main components: SERRS spectrum of the free base TMAP and that of its Ag metalated form. The metalation kinetics obtained in this way was found to be highly dependent on the presence of phosphate anions, citrate and/or Triton X-100 in the colloidal system. The results are analogous to those previously obtained for 5,10,15,20-tetrakis(1-methyl-4-pyridyl)21 H,23 H-porphine, a porphyrin with a substantially stronger tendency towards metalation.

  13. Evolution of a Rippled Membrane during Phospholipase A2 Hydrolysis Studied by Time-Resolved AFM

    DEFF Research Database (Denmark)

    Leidy, Chad; Mouritsen, Ole G.; Jørgensen, Kent

    2004-01-01

    The sensitivity of phospholipase A2 (PLA2) for lipid membrane curvature is explored by monitoring, through time-resolved atomic force microscopy, the hydrolysis of supported double bilayers in the ripple phase. The ripple phase presents a corrugated morphology. PLA2 is shown to have higher activity...... toward the ripple phase compared to the gel phase in 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) membranes, indicating its preference for this highly curved membrane morphology. Hydrolysis of the stable and metastable ripple structures is monitored for equimolar DMPC/1,2-distearoyl- sn-glycero-3....... This is reflected in an increase in ripple spacing, followed by a sudden flattening of the lipid membrane during hydrolysis. Hydrolysis of the ripple phase results in anisotropic holes running parallel to the ripples, suggesting that the ripple phase has strip regions of higher sensitivity to enzymatic attack. Bulk...

  14. Time-resolved X-ray photoelectron spectroscopy techniques for the study of interfacial charge dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Neppl, Stefan, E-mail: sneppl@lbl.gov; Gessner, Oliver

    2015-04-15

    Highlights: • Ultrafast interfacial charge transfer is probed with atomic site specificity. • Femtosecond X-ray photoelectron spectroscopy using a free electron laser. • Efficient and flexible picosecond X-ray photoelectron pump–probe scheme using synchrotron radiation. - Abstract: X-ray photoelectron spectroscopy (XPS) is one of the most powerful techniques to quantitatively analyze the chemical composition and electronic structure of surfaces and interfaces in a non-destructive fashion. Extending this technique into the time domain has the exciting potential to shed new light on electronic and chemical dynamics at surfaces by revealing transient charge configurations with element- and site-specificity. Here, we describe prospects and challenges that are associated with the implementation of picosecond and femtosecond time-resolved X-ray photoelectron spectroscopy at third-generation synchrotrons and X-ray free-electron lasers, respectively. In particular, we discuss a series of laser-pump/X-ray-probe photoemission experiments performed on semiconductor surfaces, molecule-semiconductor interfaces, and films of semiconductor nanoparticles that demonstrate the high sensitivity of time-resolved XPS to light-induced charge carrier generation, diffusion and recombination within the space charge layers of these materials. Employing the showcase example of photo-induced electronic dynamics in a dye-sensitized semiconductor system, we highlight the unique possibility to probe heterogeneous charge transfer dynamics from both sides of an interface, i.e., from the perspective of the molecular electron donor and the semiconductor acceptor, simultaneously. Such capabilities will be crucial to improve our microscopic understanding of interfacial charge redistribution and associated chemical dynamics, which are at the heart of emerging energy conversion, solar fuel generation, and energy storage technologies.

  15. Continuous-flow liquid microjunction surface sampling probe connected on-line with high-performance liquid chromatography/mass spectrometry for spatially resolved analysis of small molecules and proteins.

    Science.gov (United States)

    Van Berkel, Gary J; Kertesz, Vilmos

    2013-06-30

    A continuous-flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by mass spectrometry. Demonstrated here is the on-line coupling of such a probe with high-performance liquid chromatography/mass spectrometry (HPLC/MS) enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. A continuous-flow liquid microjunction surface sampling probe was connected to a six-port, two-position valve for extract collection and injection to an HPLC column. A QTRAP® 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V™ ion source operated in positive electrospray ionization (ESI) mode was used for all experiments. The system operation was tested with the extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues, caffeine from a coffee bean, cocaine from paper currency, and proteins from dried sheep blood spots on paper. Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin α and β chains. Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous-flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection. Published in 2013. This article is a U.S. Government work and is in the public domain in the USA.

  16. The Oxford-Diamond In Situ Cell for studying chemical reactions using time-resolved X-ray diffraction

    Science.gov (United States)

    Moorhouse, Saul J.; Vranješ, Nenad; Jupe, Andrew; Drakopoulos, Michael; O'Hare, Dermot

    2012-08-01

    A versatile, infrared-heated, chemical reaction cell has been assembled and commissioned for the in situ study of a range of chemical syntheses using time-resolved energy-dispersive X-ray diffraction (EDXRD) on Beamline I12 at the Diamond Light Source. Specialized reactor configurations have been constructed to enable in situ EDXRD investigation of samples under non-ambient conditions. Chemical reactions can be studied using a range of sample vessels such as alumina crucibles, steel hydrothermal autoclaves, and glassy carbon tubes, at temperatures up to 1200 °C.

  17. Energy-resolved photoemission studies of Be-containing surfaces for fusion; Energievariierte Photoemissionsstudien an berylliumhaltigen Oberflaechen fuer die Fusion

    Energy Technology Data Exchange (ETDEWEB)

    Koeppen, Martin

    2013-02-04

    . Oxygen diffusion is observed and attributed to diffusion of BeO. Further, the influence of a BeO-interlayer on the carbidisation in the system C-W is investigated. Already at RT small amounts of carbidised W are visible. At 1280 K further carbidisation of W is observed. No reaction between BeO and W is visible. Carbidisation of W shows, that BeO does not serve as a diffusion barrier for C, even at RT. Using energy-resolved XPS and the newly developed quantitative model allows detailed studies of multi-component surface reactions considering the evolution of the depth distribution.

  18. Time-resolved fluorescence quenching studies of sodium lauryl ether sulfate micelles

    International Nuclear Information System (INIS)

    Friedrich, Leidi C.; Silva, Volnir O.; Quina, Frank H.; Moreira Junior, Paulo F.; Tcacenco, Celize M.

    2013-01-01

    Aggregation numbers (N Ag ) of micelles of the commercial anionic detergent sodium lauryl ether sulfate (SLES), with an average of two ethylene oxide subunits, were determined at 30 and 40 deg C by the time-resolved fluorescence quenching method with pyrene as the fluorescent probe and the N-hexadecylpyridinium ion as the quencher. The added-salt dependent growth of SLES micelles (γ = 0.11-0.15, where γ is the slope of a plot of log aggregation number vs. log [Y aq ] and [Y aq ] is the sodium counterion concentration free in the intermicellar aqueous phase) is found to be significantly lower than that of sodium alkyl sulfate micelles (γ ca. 0.25), a difference attributed to the larger headgroup size of SLES. The I 1 /I 3 vibronic intensity ratio and the rate constant for intramicellar quenching of pyrene show that the pyrene solubilization microenvironment and the intramicellar microviscosity are insensitive to micelle size or the presence of added salt. (author)

  19. Studies of the reactions of hydrogen atoms by time-resolved E. S. R. spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fessenden, R W; Verma, N C [Carnegie-Mellon Univ., Pittsburgh, Pa. (USA). Dept. of Chemistry

    1977-01-01

    Time-resolved e.s.r. spectroscopy has been used to follow directly the reactions of H atoms produced by pulse radiolysis of acid solutions. Detailed analysis of the time profile of the e.s.r. signal was carried out by means of modified Bloch equations. The increased signal found when a scavenger for OH such as t-butyl alcohol is present is shown to be mainly the result of slower H atom decay by radical-radical reaction. The reaction H + OH does not appear to produce any signal polarization. The decay curves observed in the presence of solute are readily accounted for by the treatment, and good plots of pseudo first-order rate constant against solute concentration are obtained. The absolute rate constants for reaction with H atoms are for methanol 2.5 x10/sup 6/, for ethanol 2.1 X 10/sup 7/, for isopropanol 6.8 x 10/sup 7/, and for succinic acid 3.0 x 10/sup 6/ dm/sup 3/ mol/sup -1/s/sup -1/. These values are in good agreement with the earlier chemical measurements.

  20. Isotope effect on hydrated electron relaxation dynamics studied with time-resolved liquid jet photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Elkins, Madeline H.; Williams, Holly L. [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Neumark, Daniel M., E-mail: dneumark@berkeley.edu [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    2016-05-14

    The excited state relaxation dynamics of the solvated electron in H{sub 2}O and D{sub 2}O are investigated using time-resolved photoelectron spectroscopy in a liquid microjet. The data show that the initial excited state decays on a time scale of 75 ± 12 fs in H{sub 2}O and 102 ± 8 fs in D{sub 2}O, followed by slower relaxation on time scales of 400 ± 70 fs and 390 ± 70 fs that are isotopically invariant within the precision of our measurements. Based on the time evolution of the transient signals, the faster and slower time constants are assigned to p → s internal conversion (IC) of the hydrated electron and relaxation on the ground electronic state, respectively. This assignment is consistent with the non-adiabatic mechanism for relaxation of the hydrated electron and yields an isotope effect of 1.4 ± 0.2 for IC of the hydrated electron.

  1. Time-resolved study of absorbing film assisted laser induced forward transfer of Trichoderma longibrachiatum conidia

    Energy Technology Data Exchange (ETDEWEB)

    Hopp, B [Hungarian Academy of Sciences and University of Szeged, Research Group on Laser Physics, H-6720 Szeged, Dom ter 9 (Hungary); Smausz, T [Hungarian Academy of Sciences and University of Szeged, Research Group on Laser Physics, H-6720 Szeged, Dom ter 9 (Hungary); Barna, N [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dom ter 9 (Hungary); Vass, Cs [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dom ter 9 (Hungary); Antal, Zs [Hungarian Academy of Sciences and University of Szeged, Microbiological Research Group, PO Box 533, H-6701 Szeged (Hungary); Kredics, L [Hungarian Academy of Sciences and University of Szeged, Microbiological Research Group, PO Box 533, H-6701 Szeged (Hungary); Chrisey, D [Naval Research Laboratory, Washington, DC 20375 (United States)

    2005-03-21

    We have characterized the absorbing film assisted transfer of Trichoderma longibrachiatum conidia using a synchronized laser for illumination. The transfer laser used was a KrF excimer laser ({lambda} = 248 nm, FWHM = 30 ns) and the ejected material was illuminated parallel to the quartz plate by a nitrogen laser pumped Coumarine 153 dye laser beam ({lambda} = 453 nm, FWHM 1 ns) electronically delayed relative to the transfer UV pulse. Our time-resolved investigations determined that the ejection velocity front of the conidia plume from the donor surface during the transfer procedure was 1150 m s{sup -1} at 355 mJ cm{sup -2} applied laser fluence. On the basis of the measured data, the acceleration of the emitted conidia at the plume front was approximately 10{sup 9} x g. The conidia survived the absorbing film assisted forward transfer and associated mechanical shear without significant damages suggesting that the technique might be applicable to other more fragile types of biological objects and applications.

  2. Study of combustion properties of a solid propellant by highly time-resolved passive FTIR

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Liming; Zhang, Lin; Li, Yan; Liu, Bingping; Wang, Junde [Laboratory of Advanced Spectroscopy, Nanjing University of Science and Technology, Nanjing 210014 (China)

    2006-10-15

    With a time resolution of 0.125 s and a spectral resolution of 4 cm{sup -1}, emission spectra of the combustion process of a solid propellant were recorded by highly time-resolved passive FTIR. Some gaseous combustion products, such as H{sub 2}O, CO, CO{sub 2}, NO and HCl, were distinguished by the characteristic emission band of each molecule. The equation for flame temperature calculation based on the diatomic molecule emission fine structure theory was improved through judicious utilization of the spectral running number 'm' which makes the temperature measurement simpler and faster. Some combustion information of the solid propellant had been given including the characteristic spectral profile, the distribution of the absolute spectral energy, the distribution of the combustion flame temperature, and the concentration distributions of HCl and NO versus burning time. The results will provide theoretical and experimental bases for improving the formula and raising combustion efficiency of solid propellant, and developing the design of rocket motor, infrared guidance and antiguidance systems. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  3. Time-resolved fluorescence quenching studies of sodium lauryl ether sulfate micelles

    Energy Technology Data Exchange (ETDEWEB)

    Friedrich, Leidi C.; Silva, Volnir O.; Quina, Frank H., E-mail: quina@usp.br [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Instituto de Quimica; Moreira Junior, Paulo F. [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Escola Politecnica. Departamento de Engenharia Quimica; Tcacenco, Celize M. [Fundacao Instituto de Ensino para Osasco (FIEO/UNIFIEO), SP (Brazil). Centro Universitario FIEO. Centro de Estudos Quimicos

    2013-02-15

    Aggregation numbers (N{sub Ag}) of micelles of the commercial anionic detergent sodium lauryl ether sulfate (SLES), with an average of two ethylene oxide subunits, were determined at 30 and 40 deg C by the time-resolved fluorescence quenching method with pyrene as the fluorescent probe and the N-hexadecylpyridinium ion as the quencher. The added-salt dependent growth of SLES micelles ({gamma} = 0.11-0.15, where {gamma} is the slope of a plot of log aggregation number vs. log [Y{sub aq}] and [Y{sub aq}] is the sodium counterion concentration free in the intermicellar aqueous phase) is found to be significantly lower than that of sodium alkyl sulfate micelles ({gamma} ca. 0.25), a difference attributed to the larger headgroup size of SLES. The I{sub 1}/I{sub 3} vibronic intensity ratio and the rate constant for intramicellar quenching of pyrene show that the pyrene solubilization microenvironment and the intramicellar microviscosity are insensitive to micelle size or the presence of added salt. (author)

  4. Time-Resolved Emission Spectroscopic Study of Laser-Induced Steel Plasmas

    International Nuclear Information System (INIS)

    Shah, M. L.; Pulhani, A. K.; Suri, B. M.; Gupta, G. P.

    2013-01-01

    Laser-induced steel plasma is generated by focusing a Q-switched Nd:YAG visible laser (532 nm wavelength) with an irradiance of ∼ 1 × 10 9 W/cm 2 on a steel sample in air at atmospheric pressure. An Echelle spectrograph coupled with a gateable intensified charge-coupled detector is used to record the plasma emissions. Using time-resolved spectroscopic measurements of the plasma emissions, the temperature and electron number density of the steel plasma are determined for many times of the detector delay. The validity of the assumption by the spectroscopic methods that the laser-induced plasma (LIP) is optically thin and is also in local thermodynamic equilibrium (LTE) has been evaluated for many delay times. From the temporal evolution of the intensity ratio of two Fe I lines and matching it with its theoretical value, the delay times where the plasma is optically thin and is also in LTE are found to be 800 ns, 900 ns and 1000 ns.

  5. Time-resolved study of absorbing film assisted laser induced forward transfer of Trichoderma longibrachiatum conidia

    International Nuclear Information System (INIS)

    Hopp, B; Smausz, T; Barna, N; Vass, Cs; Antal, Zs; Kredics, L; Chrisey, D

    2005-01-01

    We have characterized the absorbing film assisted transfer of Trichoderma longibrachiatum conidia using a synchronized laser for illumination. The transfer laser used was a KrF excimer laser (λ = 248 nm, FWHM = 30 ns) and the ejected material was illuminated parallel to the quartz plate by a nitrogen laser pumped Coumarine 153 dye laser beam (λ = 453 nm, FWHM 1 ns) electronically delayed relative to the transfer UV pulse. Our time-resolved investigations determined that the ejection velocity front of the conidia plume from the donor surface during the transfer procedure was 1150 m s -1 at 355 mJ cm -2 applied laser fluence. On the basis of the measured data, the acceleration of the emitted conidia at the plume front was approximately 10 9 x g. The conidia survived the absorbing film assisted forward transfer and associated mechanical shear without significant damages suggesting that the technique might be applicable to other more fragile types of biological objects and applications

  6. Spatially resolved In and As distributions in InGaAs/GaP and InGaAs/GaAs quantum dot systems

    International Nuclear Information System (INIS)

    Shen, J; Cha, J J; Song, Y; Lee, M L

    2014-01-01

    InGaAs quantum dots (QDs) on GaP are promising for monolithic integration of optoelectronics with Si technology. To understand and improve the optical properties of InGaAs/GaP QD systems, detailed measurements of the QD atomic structure as well as the spatial distributions of each element at high resolution are crucial. This is because the QD band structure, band alignment, and optical properties are determined by the atomic structure and elemental composition. Here, we directly measure the inhomogeneous distributions of In and As in InGaAs QDs grown on GaAs and GaP substrates at the nanoscale using energy dispersive x-ray spectral mapping in a scanning transmission electron microscope. We find that the In distribution is broader on GaP than on GaAs, and as a result, the QDs appear to be In-poor using a GaP matrix. Our findings challenge some of the assumptions made for the concentrations and distributions of In within InGaAs/GaAs or InGaAs/GaP QD systems and provide detailed structural and elemental information to modify the current band structure understanding. In particular, the findings of In deficiency and inhomogeneous distribution in InGaAs/GaP QD systems help to explain photoluminescence spectral differences between InGaAs/GaAs and InGaAs/GaP QD systems. (paper)

  7. Spatially resolved electron density and electron energy distribution function in Ar magnetron plasmas used for sputter-deposition of ZnO-based thin films

    Energy Technology Data Exchange (ETDEWEB)

    Maaloul, L.; Gangwar, R. K.; Morel, S.; Stafford, L., E-mail: luc.stafford@umontreal.ca [Département de Physique, Université de Montréal, Montréal, Québec H3C 3J7 (Canada)

    2015-11-15

    Langmuir probe and trace rare gases optical emission spectroscopy were used to analyze the spatial structure of the electron density and electron energy distribution function (EEDF) in a cylindrical Ar magnetron plasma reactor used for sputter-deposition of ZnO-based thin films. While a typical Bessel (zero order) diffusion profile was observed along the radial direction for the number density of charged particles at 21 cm from the ZnO target, a significant rise of these populations with respect to the Bessel function was seen in the center of the reactor at 4 cm from the magnetron surface. As for the EEDF, it was found to transform from a more or less Maxwellian far from the target to a two-temperature Maxwellian with a depletion of high-energy electrons where magnetic field confinement effects become important. No significant change in the behavior of the electron density and EEDF across a wide range of pressures (5–100 mTorr) and self-bias voltages (115–300 V) was observed during magnetron sputtering of Zn, ZnO, and In{sub 2}O{sub 3} targets. This indicates that sputtering of Zn, In, and O atoms do not play a very significant role on the electron particle balance and electron heating dynamics, at least over the range of experimental conditions investigated.

  8. Spatially resolved investigation of systemic and contact pesticides in plant material by desorption electrospray ionization mass spectrometry imaging (DESI-MSI).

    Science.gov (United States)

    Gerbig, Stefanie; Brunn, Hubertus E; Spengler, Bernhard; Schulz, Sabine

    2015-09-01

    Distribution of pesticides both on the surface of leaves and in cross sections of plant stem and leaves was investigated using desorption electrospray ionization mass spectrometry imaging (DESI-MSI) with a spatial resolution of 50-100 μm. Two commercially available insecticide sprays containing different contact pesticides were applied onto leaves of Cotoneaster horizontalis, and the distributions of all active ingredients were directly analyzed. The first spray contained pyrethrins and rapeseed oil, both known as natural insecticides. Each component showed an inhomogeneous spreading throughout the leaf, based on substance polarity and solubility. The second spray contained the synthetic insecticides imidacloprid and methiocarb. Imidacloprid accumulated on the border of the leaf, while methiocarb was distributed more homogenously. In order to investigate the incorporation of a systemically acting pesticide into Kalanchoe blossfeldiana, a commercially available insecticide tablet containing dimethoate was spiked to the soil of the plant. Cross sections of the stem and leaf were obtained 25 and 60 days after application. Dimethoate was mainly detected in the transport system of the plant after 25 days, while it was found to be homogenously distributed in a leaf section after 60 days.

  9. Angle-resolved photoemission study and first-principles calculation of the electronic structure of LaSb2

    International Nuclear Information System (INIS)

    Acatrinei, Alice I; Browne, D; Losovyj, Y B; Young, D P; Moldovan, M; Chan, Julia Y; Sprunger, P T; Kurtz, Richard L

    2003-01-01

    In this work we present valence band studies of LaSb 2 using angle-resolved photoelectron spectroscopy with synchrotron radiation and compare these data with band structure calculations. Valence band spectra reveal that Sb 5p states are dominant near the Fermi level and are hybridized with the La 5d states just below. The calculations show a fair agreement with the experimentally determined valence band spectra, allowing an identification of the observed features. We measured some dispersion for kbar, especially for Sb 5p states; no significant dispersion was found for k || . (letter to the editor)

  10. Charge recombination processes in minerals studied using optically stimulated luminescence and time-resolved exo-electrons

    DEFF Research Database (Denmark)

    Tsukamoto, Sumiko; Murray, Andrew; Ankjærgaard, Christina

    2010-01-01

    electron concentration in the conduction band. In this study, TR-OSE and time-resolved optically stimulated luminescence (TR-OSL) were measured for the first time using quartz, K-feldspar and NaCl by stimulating the samples using pulsed blue LEDs at different temperatures between 50 and 250 °C after beta...... irradiation and preheating to 280 °C. The majority of TR-OSE signals from all the samples decayed much faster than TR-OSL signals irrespective of the stimulation temperatures. This suggests that the lifetime of OSL in these dosimeters arises mainly from the relaxation of an excited state of the recombination...

  11. Time-dependent first-principles study of angle-resolved secondary electron emission from atomic sheets

    Science.gov (United States)

    Ueda, Yoshihiro; Suzuki, Yasumitsu; Watanabe, Kazuyuki

    2018-02-01

    Angle-resolved secondary electron emission (ARSEE) spectra were analyzed for two-dimensional atomic sheets using a time-dependent first-principles simulation of electron scattering. We demonstrate that the calculated ARSEE spectra capture the unoccupied band structure of the atomic sheets. The excitation dynamics that lead to SEE have also been revealed by the time-dependent Kohn-Sham decomposition scheme. In the present study, the mechanism for the experimentally observed ARSEE from atomic sheets is elucidated with respect to both energetics and the dynamical aspects of SEE.

  12. Reference-free spectroscopic determination of fat and protein in milk in the visible and near infrared region below 1000nm using spatially resolved diffuse reflectance fiber probe.

    Science.gov (United States)

    Bogomolov, Andrey; Belikova, Valeria; Galyanin, Vladislav; Melenteva, Anastasiia; Meyer, Hans

    2017-05-15

    New technique of diffuse reflectance spectroscopic analysis of milk fat and total protein content in the visible (Vis) and adjacent near infrared (NIR) region (400-995nm) has been developed and tested. Sample analysis was performed through a probe having eight 200-µm fiber channels forming a linear array. One of the end fibers was used for the illumination and other seven - for the spectroscopic detection of diffusely reflected light. One of the detection channels was used as a reference to normalize the spectra and to convert them into absorbance-equivalent units. The method has been tested experimentally using a designed sample set prepared from industrial raw milk standards with widely varying fat and protein content. To increase the modelling robustness all milk samples were measured in three different homogenization degrees. Comprehensive data analysis has shown the advantage of combining both spectral and spatial resolution in the same measurement and revealed the most relevant channels and wavelength regions. The modelling accuracy was further improved using joint variable selection and preprocessing optimization method based on the genetic algorithm. The root mean-square errors of different validation methods were below 0.10% for fat and below 0.08% for total protein content. Based on the present experimental data, it was computationally shown that the full-spectrum analysis in this method can be replaced by a sensor measurement at several specific wavelengths, for instance, using light-emitting diodes (LEDs) for illumination. Two optimal sensor configurations have been suggested: with nine LEDs for the analysis of fat and seven - for protein content. Both simulated sensors exhibit nearly the same component determination accuracy as corresponding full-spectrum analysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. On the Spatially Resolved Star Formation History in M51. I. Hybrid UV+IR Star Formation Laws and IR Emission from Dust Heated by Old Stars

    Science.gov (United States)

    Eufrasio, R. T.; Lehmer, B. D.; Zezas, A.; Dwek, E.; Arendt, R. G.; Basu-Zych, A.; Wiklind, T.; Yukita, M.; Fragos, T.; Hornschemeier, A. E.; Markwardt, L.; Ptak, A.; Tzanavaris, P.

    2017-12-01

    We present LIGHTNING, a new spectral energy distribution fitting procedure, capable of quickly and reliably recovering star formation history (SFH) and extinction parameters. The SFH is modeled as discrete steps in time. In this work, we assumed lookback times of 0-10 Myr, 10-100 Myr, 0.1-1 Gyr, 1-5 Gyr, and 5-13.6 Gyr. LIGHTNING consists of a fully vectorized inversion algorithm to determine SFH step intensities and combines this with a grid-based approach to determine three extinction parameters. We apply our procedure to the extensive far-UV-to-far-IR photometric data of M51, convolved to a common spatial resolution and pixel scale, and make the resulting maps publicly available. We recover, for M51a, a peak star formation rate (SFR) between 0.1 and 5 Gyr ago, with much lower star formation activity over the past 100 Myr. For M51b, we find a declining SFR toward the present day. In the outskirt regions of M51a, which includes regions between M51a and M51b, we recover an SFR peak between 0.1 and 1 Gyr ago, which corresponds to the effects of the interaction between M51a and M51b. We utilize our results to (1) illustrate how UV+IR hybrid SFR laws vary across M51 and (2) provide first-order estimates for how the IR luminosity per unit stellar mass varies as a function of the stellar age. From the latter result, we find that IR emission from dust heated by stars is not always associated with young stars and that the IR emission from M51b is primarily powered by stars older than 5 Gyr.

  14. Two-dimensional time-resolved X-ray diffraction study of directional solidification in steels

    International Nuclear Information System (INIS)

    Yonemura, Mitsuharu

    2009-01-01

    Full text: The high intensity heat source used for fusion welding creates steep thermal gradients of 100 degree C/s from 1800 degree Celsius. Further, the influence of a preferred orientation is serious for observation of a directional solidification that follows the dendrite growth along the direction toward the moving heat source. Therefore, we observed the rapid solidification of weld metal at a time resolution of 0.01∼0.1seconds by the Two-Dimensional Time-Resolved X-ray Diffraction (2DTRXRD) system for real welding. The diffraction ring was dynamically observed by 2DTRXRD during arc-passing over the irradiation area of X-ray with synchrotron energy of 18 KeV. The arc power output was 10 V - 150 A, and a scan speed of the arc was 1.0 mm/s. The temperature rise of instruments was suppressed by the water-cooled copper plate under the sample. Further, the temperature distribution of the weld metal was measured by the thermocouple and related to the diffraction patterns. Consequently, solidification and solid phase transformation of low carbon steels and stainless steels were observed during rapid cooling by 2DTRXRD. In the low-carbon steel, the microstructure is formed in the 2 step process; (i) formation of crystallites and (ii) increase of crystallinity. In the stainless steel, the irregular interface layer of σ/y in the quenched metal after solidification is expected that it is easy for dendrites to move at the lower temperature. In the carbide precipitation stainless steel, it is easy for NbC to grow on σ phase with a little under cooling. Further, a mist-like pattern, which differs from the halo-pattern, in the fusion zone gave some indication of the possibilities to observe the nucleation and the early solidification by 2DTRXRD. (author)

  15. Pulse radiolysis of alkanes: a time-resolved EPR study - Part I. Alkyl radicals

    International Nuclear Information System (INIS)

    Shkrob, I.A.; Trifunac, A.D.

    1995-01-01

    Time-resolved EPR was applied to detect short-lived alkyl radicals in pulse radiolysis of liquid alkanes. Two problems were addressed: (i) the mechanism of radical formation and (ii) the mechanism of chemically-induced spin polarization in these radicals. (i) The ratio of yields of penultimate and interior radicals in n-alkanes at the instant of their generation was found to be ≅ 1.25 times greater than the statistical quantity. This higher-than-statistical production of penultimate radicals indicates that the proton transfer reaction involving excited radical cations must be a prevailing route of radical generation. The relative yields of hydrogen abstraction and fragmentation for various branched alkanes are estimated. It is concluded that the fragmentation occurs prior to the formation of radicals in an excited precursor species. (ii) The analysis of spin-echo kinetics in n-alkanes suggests that the alkyl radicals gain the emissive polarization in spur reactions. This initial polarization increases with shortening of the aliphatic chain. We suggest that the origin of this polarization is the ST mechanism operating in the pairs of alkyl radicals and hydrogen atoms generated in dissociation of excited alkane molecules. It is also found that a long-chain structure of alkyl radicals results in much higher rate of Heisenberg spin exchange relative to the recombination rate (up to 30 times). That suggests prominent steric effects in recombination or the occurrence of through-chain electron exchange. The significance of these results in the context of cross-linking in polyethylene and higher paraffins is discussed. (Author)

  16. Preliminary Study on J-Resolved NMR Method Usability for Toxic Kidney's Injury Assessment.

    Science.gov (United States)

    Doskocz, Marek; Marchewka, Zofia; Jeż, Magdalena; Passowicz-Muszyńska, Ewa; Długosz, Anna

    2015-01-01

    Nowadays, the Nuclear Magnetic Resonance (NMR) techniques are tested for metabolomic urine profile in order to detect early damage of kidney. The purpose of this investigation was the initial assessment of two-dimensional J-resolved NMR urine spectra analysis usability for early kidney injuries detection. The amino acids (AA) and acids profile change after the exposure to nephrotoxic agent (the cisplatin infusion) was examined. The material was the urine of patients with non-small-cell lung cancer, treated with cisplatin in Pulmonology and Lung Cancers Clinic in Wrocław. The urine of healthy volunteers was also examined. The identification of metabolites in urine was based on two-dimensional JRES signals in spectra, described in Human Metabolites Database (HMD). The molar concentration of metabolites was calculated from the volume under the signals. The analysis was focused on amino acids and organic acids (lactid acid and pyruvic acid) profiles. Any specific amino acids were identified after cisplatin infusion in comparison to the state before infusion. However, the differences in concentration were observed over 2-fold increase in valine, isoleucine and leucine, over 3-fold in alanine. Also, the concentration of pyruvic and lactic acids increased significantly (p≤0.05, p≤0.01). There were no specific amino acids identified in response to the infusion of cisplatin; however, some changes in the concentrations of amino acids and other small molecules were found. The analysis of two-dimensional JRES spectra showed an increase of alanine, leucine, isoleucine and valine concentration after the application of cisplatin. It seems that it is worth developing the JRES method based on special computer program.

  17. Quantitative spatially resolved measurement of tissue chromophore concentrations using photoacoustic spectroscopy: application to the measurement of blood oxygenation and haemoglobin concentration

    Science.gov (United States)

    Laufer, Jan; Delpy, Dave; Elwell, Clare; Beard, Paul

    2007-01-01

    A new approach based on pulsed photoacoustic spectroscopy for non-invasively quantifying tissue chromophore concentrations with high spatial resolution has been developed. The technique is applicable to the quantification of tissue chromophores such as oxyhaemoglobin (HbO2) and deoxyhaemoglobin (HHb) for the measurement of physiological parameters such as blood oxygen saturation (SO2) and total haemoglobin concentration. It can also be used to quantify the local accumulation of targeted contrast agents used in photoacoustic molecular imaging. The technique employs a model-based inversion scheme to recover the chromophore concentrations from photoacoustic measurements. This comprises a numerical forward model of the detected time-dependent photoacoustic signal that incorporates a multiwavelength diffusion-based finite element light propagation model to describe the light transport and a time-domain acoustic model to describe the generation, propagation and detection of the photoacoustic wave. The forward model is then inverted by iteratively fitting it to measurements of photoacoustic signals acquired at different wavelengths to recover the chromophore concentrations. To validate this approach, photoacoustic signals were generated in a tissue phantom using nanosecond laser pulses between 740 nm and 1040 nm. The tissue phantom comprised a suspension of intralipid, blood and a near-infrared dye in which three tubes were immersed. Blood at physiological haemoglobin concentrations and oxygen saturation levels ranging from 2% to 100% was circulated through the tubes. The signal amplitude from different temporal sections of the detected photoacoustic waveforms was plotted as a function of wavelength and the forward model fitted to these data to recover the concentrations of HbO2 and HHb, total haemoglobin concentration and SO2. The performance was found to compare favourably to that of a laboratory CO-oximeter with measurement resolutions of ±3.8 g l-1 (±58 µM) and ±4

  18. Quantitative spatially resolved measurement of tissue chromophore concentrations using photoacoustic spectroscopy: application to the measurement of blood oxygenation and haemoglobin concentration

    Energy Technology Data Exchange (ETDEWEB)

    Laufer, Jan; Delpy, Dave; Elwell, Clare; Beard, Paul [Department of Medical Physics and Bioengineering, University College London, Malet Place Engineering Building, London WC1E 6BT (United Kingdom)

    2007-01-07

    A new approach based on pulsed photoacoustic spectroscopy for non-invasively quantifying tissue chromophore concentrations with high spatial resolution has been developed. The technique is applicable to the quantification of tissue chromophores such as oxyhaemoglobin (HbO{sub 2}) and deoxyhaemoglobin (HHb) for the measurement of physiological parameters such as blood oxygen saturation (SO{sub 2}) and total haemoglobin concentration. It can also be used to quantify the local accumulation of targeted contrast agents used in photoacoustic molecular imaging. The technique employs a model-based inversion scheme to recover the chromophore concentrations from photoacoustic measurements. This comprises a numerical forward model of the detected time-dependent photoacoustic signal that incorporates a multiwavelength diffusion-based finite element light propagation model to describe the light transport and a time-domain acoustic model to describe the generation, propagation and detection of the photoacoustic wave. The forward model is then inverted by iteratively fitting it to measurements of photoacoustic signals acquired at different wavelengths to recover the chromophore concentrations. To validate this approach, photoacoustic signals were generated in a tissue phantom using nanosecond laser pulses between 740 nm and 1040 nm. The tissue phantom comprised a suspension of intralipid, blood and a near-infrared dye in which three tubes were immersed. Blood at physiological haemoglobin concentrations and oxygen saturation levels ranging from 2% to 100% was circulated through the tubes. The signal amplitude from different temporal sections of the detected photoacoustic waveforms was plotted as a function of wavelength and the forward model fitted to these data to recover the concentrations of HbO{sub 2} and HHb, total haemoglobin concentration and SO{sub 2}. The performance was found to compare favourably to that of a laboratory CO-oximeter with measurement resolutions of {+-}3

  19. Quantitative spatially resolved measurement of tissue chromophore concentrations using photoacoustic spectroscopy: application to the measurement of blood oxygenation and haemoglobin concentration

    International Nuclear Information System (INIS)

    Laufer, Jan; Delpy, Dave; Elwell, Clare; Beard, Paul

    2007-01-01

    A new approach based on pulsed photoacoustic spectroscopy for non-invasively quantifying tissue chromophore concentrations with high spatial resolution has been developed. The technique is applicable to the quantification of tissue chromophores such as oxyhaemoglobin (HbO 2 ) and deoxyhaemoglobin (HHb) for the measurement of physiological parameters such as blood oxygen saturation (SO 2 ) and total haemoglobin concentration. It can also be used to quantify the local accumulation of targeted contrast agents used in photoacoustic molecular imaging. The technique employs a model-based inversion scheme to recover the chromophore concentrations from photoacoustic measurements. This comprises a numerical forward model of the detected time-dependent photoacoustic signal that incorporates a multiwavelength diffusion-based finite element light propagation model to describe the light transport and a time-domain acoustic model to describe the generation, propagation and detection of the photoacoustic wave. The forward model is then inverted by iteratively fitting it to measurements of photoacoustic signals acquired at different wavelengths to recover the chromophore concentrations. To validate this approach, photoacoustic signals were generated in a tissue phantom using nanosecond laser pulses between 740 nm and 1040 nm. The tissue phantom comprised a suspension of intralipid, blood and a near-infrared dye in which three tubes were immersed. Blood at physiological haemoglobin concentrations and oxygen saturation levels ranging from 2% to 100% was circulated through the tubes. The signal amplitude from different temporal sections of the detected photoacoustic waveforms was plotted as a function of wavelength and the forward model fitted to these data to recover the concentrations of HbO 2 and HHb, total haemoglobin concentration and SO 2 . The performance was found to compare favourably to that of a laboratory CO-oximeter with measurement resolutions of ±3.8 g l -1 (±58

  20. Development and application of methods and models for the calculation of spatially and temporally highly resolved emissions in Europe; Entwicklung und Anwendung von Methoden und Modellen zur Berechnung von raeumlich und zeitlich hochaufgeloesten Emissionen in Europa

    Energy Technology Data Exchange (ETDEWEB)

    Thiruchittampalam, Balendra

    2014-04-08

    High spatial and temporal resolution models are essential for answering many questions of air quality management and climate modeling. High-resolution emission models are required to determine the concentration of pollutants using chemical transport models, and to quantify the impacts on health and environment and in particular to develop adequate countermeasures. The aim of this work is to develop methods for the calculation of spatially and temporally high-resolved emissions and to apply these exemplarily on a 1 km x 1 km and hourly resolution for the year 2008 in the EU-27 and EFTA countries. The derivation of methods for the spatial and temporal resolution of emissions with corresponding detailed equations is one of the major improvements that have been carried out in the course of this work. The improvement of the spatial distribution of emissions from the point source relevant sectors like energy supply, industry and waste management is achieved by considering sector specific diffuse emission shares. The progress of the spatial distribution of emissions from households is in particular the development of a fuel type weighted distribution over Europe. Another main focus is the development of the spatial distribution of road transport emissions. Due to the restricted access to traffic count data at the European level, methods have been established to provide reliable emissions on grid level for Europe. The progress in the spatial distribution of agricultural emissions is achieved by the consideration of diffuse shares similar to the other point source relevant sectors like energy supply or industry. In addition to the spatial distribution of the emissions the temporal resolution is a main focus of this work, since the state of knowledge of the temporal resolution of emissions in Europe is still rudimentary. Therefore, it was necessary to develop in particular time curves for the hourly resolution of emissions for the main sectors, namely electricity and heat

  1. EXPERIMENTAL STUDY OF THE BEARING CAPACITY OF SPATIAL METAL FRAMES

    Directory of Open Access Journals (Sweden)

    Serpik Igor' Naftol'evich

    2012-10-01

    Full Text Available In the article, the authors describe the principal findings of the experimental study of destruction of spatial frames made of closed-profile steel rods. Six samples of frames were tested through the application of a kinematic loading scheme. Values of forces, displacements and deformations were measured over the time. Each sample was brought to the state when the load reached its maximal value. Thereafter, the load intensity was reduced to 0.6...0.7 of its maximal value. It was identified that the destruction of rods in the event of combined stress was similar to the formation of plastic hinges in the course of regular bending. In some cases, cracks were formed in the zones of plastic hinges. This process did not cause complete destruction of frames. Destruction-related conditions were also assessed by the quasi-rigidity method implemented in STARK ES 2009 software package. The input data were used to perform failure, bending and torsion tests of steel pipes. The experiments and calculations have proven that in this case the process of destruction can be considered in accordance with the limit equilibrium method by taking account of formation of spatial plastic hinges. The quasi-rigidity method can be employed to identify the maximal load that the frames can bear.

  2. Time-Resolved Studies of Laser-Induced Phase Transitions in Gallium Arsenide

    Science.gov (United States)

    Siegal, Yakir

    This thesis describes a series of time-resolved experiments of the linear and nonlinear optical properties of GaAs during laser-induced phase transitions. The first set of experiments consists of a direct determination of the behavior of the linear dielectric constant at photon energies of 2.2 eV and 4.4 eV following excitation of the sample with 1.9-eV, 70-fs laser pulses spanning a fluence range from 0 to 2.5 kJ/m^2. The results from this set of experiments were used to extract the behavior of the second-order optical susceptibility from second-harmonic generation measurements made under identical excitation conditions. These experiments are unique because they provide explicit information on the behavior of intrinsic material properties--the linear and nonlinear optical susceptibilities--during laser-induced phase transitions in semiconductors without the ambiguities in interpretation that are generally inherent in reflectivity and second-harmonic generation measurements. The dielectric constant data indicate a drop in the average bonding-antibonding splitting of GaAs following the laser pulse excitation. This behavior leads to a collapse of the band-gap on a picosecond time scale for excitation at fluences near the damage threshold of 1.0 kJ/m ^2 and even faster at higher excitation fluences. The changes in the electronic band structure result from a combination of electronic screening by the excited free carriers and structural deformation of the lattice caused by the destabilization of the covalent bonds. The behavior of the second-order susceptibility shows that the material loses long-range order before the average bonding-antibonding splitting, which is more sensitive to short-range structure, changes significantly. Loss of long-range order and a drop of more than 2 eV in the average bonding-antibonding splitting are seen even at fluences below the damage threshold, a regime in which the laser-induced changes are reversible.

  3. Study on Spatial Cultural Heritage Integrated into the Core Curriculum

    Science.gov (United States)

    Hsu, W. H.; Lai, Y. P.

    2015-08-01

    These Many countries have put a lot of efforts, promoting education of cultural heritage, to raise the conservation awareness and increase people's participation. However, the development of Taiwan's higher education about cultural heritage has not shown a significant growth, so it didn't train talents with enough cultural heritage awareness. In the workplace, these professionals will inevitably lack of comprehensions and the appropriate professional assessments for cultural heritage. Hence, the main objective of this paper is to study and combine these concepts into the core curriculum of Department of Construction and Spatial Design at Tungnan University. It takes the local "Shenkeng historic cultural district" as a case study, and will gradually develop an proper interdisciplinary course in order to help local residents implement projects of conserving cultural heritage. This plan not only can increase schools' engagements toward communities, with an ability of social civilization, but also it can encourage the conservation and maintenance of cultural heritages.

  4. Using a spatially-distributed hydrologic biogeochemistry model to study the spatial variation of carbon processes in a Critical Zone Observatory

    Science.gov (United States)

    Shi, Y.; Eissenstat, D. M.; Davis, K. J.; He, Y.

    2016-12-01

    Forest carbon processes are affected by, among other factors, soil moisture, soil temperature, soil nutrients and solar radiation. Most of the current biogeochemical models are 1-D and represent one point in space. Therefore, they cannot resolve the topographically driven hill-slope land surface heterogeneity or the spatial pattern of nutrient availability. A spatially distributed forest ecosystem model, Flux-PIHM-BGC, has been developed by coupling a 1-D mechanistic biogeochemical model Biome-BGC (BBGC) with a spatially distributed land surface hydrologic model, Flux-PIHM. Flux-PIHM is a coupled physically based model, which incorporates a land-surface scheme into the Penn State Integrated Hydrologic Model (PIHM). The land surface scheme is adapted from the Noah land surface model. Flux-PIHM is able to represent the link between groundwater and the surface energy balance, as well as the land surface heterogeneities caused by topography. In the coupled Flux-PIHM-BGC model, each Flux-PIHM model grid couples a 1-D BBGC model, while soil nitrogen is transported among model grids via subsurface water flow. In each grid, Flux-PIHM provides BBGC with soil moisture, soil temperature, and solar radiation information, while BBGC provides Flux-PIHM with leaf area index. The coupled Flux-PIHM-BGC model has been implemented at the Susquehanna/Shale Hills critical zone observatory (SSHCZO). Model results suggest that the vegetation and soil carbon distribution is primarily constrained by nitorgen availability (affected by nitorgen transport via topographically driven subsurface flow), and also constrained by solar radiation and root zone soil moisture. The predicted vegetation and soil carbon distribution generally agrees with the macro pattern observed within the watershed. The coupled ecosystem-hydrologic model provides an important tool to study the impact of topography on watershed carbon processes, as well as the impact of climate change on water resources.

  5. Study of academic achievements using spatial analysis tools

    Science.gov (United States)

    González, C.; Velilla, C.; Sánchez-Girón, V.

    2012-04-01

    In the 2010/12 academic year the College of Agricultural Engineering of the Technical University of Madrid implemented three new degrees all of them adapted to the European Space for Higher Education. These degrees are namely: Graduate in Agricultural Engineering and Science, Graduate in Food Engineering and Graduate in Agro-Environmental Engineering. A total of 382 new incoming students were finally registered and a survey study was carried out with these students about their academic achievement with the aim of finding the level of dependence among the following variables: the final mark in their secondary studies, the option followed in the secondary studies (Art, Science and Technology, and Humanities and Social Sciences), the mark obtained in the entering examination to the university and in which of the two opportunities per year this examination takes place the latter mark was obtained. Similarly, another group of 77 students were evaluated independently to the former group. These students were those entering the College in the previous academic year (2009/10) and decided to change their curricula to the new ones. Subsequently, using the tools of spatial analysis of geographic information systems, we analyzed the possible relationship between the success or failure at school and the socioeconomic profile of new students in a grade. For this purpose every student was referenced assigning UTM coordinates to their postal addresses. Furthermore, all students' secondary schools were geographically coded considering their typology (public, private, and private subsidized) and fares. Each student was represented by its average geometric point in order to be correlated to their respective record. Following this procedure a map of the performance of each student could be drawn. This map can be used as a reference system, as it includes variables as the distance from the student home to the College, that can be used as a tool to calculate the probability of success or

  6. Study of the Bulk Charge Carrier Dynamics in Anatase and Rutile TiO2 Single Crystals by Femtosecond Time Resolved Spectroscopy

    KAUST Repository

    Maity, Partha; Mohammed, Omar F.; Katsiev, Khabiboulakh; Idriss, Hicham

    2018-01-01

    as the best model for fundamental studies. Their ultrafast charge carrier dynamics especially on TiO2 anatase single crystal (the most active phase) are unresolved. Here femtosecond time resolved spectroscopy (TRS) was carried out to explore the dynamics

  7. DEFINING SPATIAL VIOLENCE. BUCHAREST AS A STUDY CASE

    Directory of Open Access Journals (Sweden)

    Celia GHYKA

    2015-05-01

    Full Text Available The paper looks at the spatial manifestations of violence, aiming to define the category of spatial violence by focusing on the recent urban history of Bucharest; it establishes links with the longer history of natural and inflicted disasters that defined the city, and it explores the spatial, urban, social and symbolical conflicts that occured during the last 25 years, pointing at their consequences on the social and urban substance of the city.

  8. Spatial Modeling of Geometallurgical Properties: Techniques and a Case Study

    Energy Technology Data Exchange (ETDEWEB)

    Deutsch, Jared L., E-mail: jdeutsch@ualberta.ca [University of Alberta, School of Mining and Petroleum Engineering, Department of Civil and Environmental Engineering (Canada); Palmer, Kevin [Teck Resources Limited (Canada); Deutsch, Clayton V.; Szymanski, Jozef [University of Alberta, School of Mining and Petroleum Engineering, Department of Civil and Environmental Engineering (Canada); Etsell, Thomas H. [University of Alberta, Department of Chemical and Materials Engineering (Canada)

    2016-06-15

    High-resolution spatial numerical models of metallurgical properties constrained by geological controls and more extensively by measured grade and geomechanical properties constitute an important part of geometallurgy. Geostatistical and other numerical techniques are adapted and developed to construct these high-resolution models accounting for all available data. Important issues that must be addressed include unequal sampling of the metallurgical properties versus grade assays, measurements at different scale, and complex nonlinear averaging of many metallurgical parameters. This paper establishes techniques to address each of these issues with the required implementation details and also demonstrates geometallurgical mineral deposit characterization for a copper–molybdenum deposit in South America. High-resolution models of grades and comminution indices are constructed, checked, and are rigorously validated. The workflow demonstrated in this case study is applicable to many other deposit types.

  9. Studying visual and spatial reasoning for design creativity

    CERN Document Server

    2015-01-01

    Creativity and design creativity in particular are being recognized as playing an increasing role in the social and economic wellbeing of a society. As a consequence creativity is becoming a focus of research. However, much of this burgeoning research is distributed across multiple disciplines that normally do not intersect with each other and researchers in one discipline are often unaware of related research in another discipline.  This volume brings together contributions from design science, computer science, cognitive science and neuroscience on studying visual and spatial reasoning applicable to design creativity. The book is the result of a unique NSF-funded workshop held in Aix-en-Provence, France. The aim of the workshop and the resulting volume was to allow researchers in disparate disciplines to be exposed to the other’s research, research methods and research results within the context of design creativity. Fifteen of the papers presented and discussed at the workshop are contained in this volu...

  10. Studies of spatial decoupling in heterogeneous LMFBR critical assemblies

    International Nuclear Information System (INIS)

    Brumbach, S.B.; Goin, R.W.; Carpenter, S.G.

    1984-01-01

    Recent measurements at the Zero Power Plutonium Reactor have studied the spatial decoupling in large, heterogeneous assemblies. These assemblies exhibited a significantly greater degree of decoupling than previous homogeneous assemblies of similar size. The flux distributions in these heterogeneous assemblies were very sensitive reactivity perturbations, and perturbed flux distributions were achieved relatively slowly. Decoupling was investigated using rod-drop, boron-oscillator and noise-coherence techniques which emphasized different times following the perturbations. Reactivity changes could be measured by analyzing the power history from a single detector using inverse kinetics methods with the assumption of an instantaneous efficiency change for the detector. For assemblies more decoupled than ZPPR-13, the instantaneous efficiency change assumption begins to be invalid

  11. Dispersion of sulphur in the northern hemisphere. A study with a 3-dimensional time-resolved model

    Energy Technology Data Exchange (ETDEWEB)

    Tarrason, L

    1996-12-31

    This thesis on atmospheric dispersion of sulphur presents a calculation of intercontinental transport of oxidized sulphur and allocates different contributions to sulphur background levels over Europe. It is found that a significant fraction of anthropogenic sulphur (AS) is transported out of continental boundaries thus affecting the background levels over major parts of the northern hemisphere. Over Europe, the contribution of AS from North America is similar in amount to that of Asian AS and natural sources from the North Atlantic Ocean. Although the yearly contribution of intercontinental transport to deposition of sulphur over Europe is quite small, it can be much more important over certain areas and seasons and is comparable to the contributions from individual European countries. The calculations are based on a three-dimensional Eulerian time-resolved model that describes sulphur dispersion in the atmosphere in connection with large-scale synoptic flows and agree well with observations. The thesis emphasizes the role of synoptic scale atmospheric motions in determining intercontinental transport of sulphur. It indicates the need to resolve individual cyclones and anticyclones in order to describe the dispersion and distribution of atmospheric sulphur in the northern hemisphere and stresses the value of comparing model calculations with observations, both in atmospheric chemistry studies and in climate applications. 260 refs., 50 figs., 17 tabs.

  12. Charge recombination processes in minerals studied using optically stimulated luminescence and time-resolved exo-electrons

    International Nuclear Information System (INIS)

    Tsukamoto, Sumiko; Murray, Andrew; Ankjaergaard, Christina; Jain, Mayank; Lapp, Torben

    2010-01-01

    A time-resolved optically stimulated exo-electron (TR-OSE) measurement system has been developed using a Photon Timer attached to a gas-flow semi-proportional pancake electron detector within a Risoe TL/OSL reader. The decay rate of the exo-electron emission after the stimulation pulse depends on the probability of (1) escape of electrons into the detector gas from the conduction band by overcoming the work function of the material and (2) thermalization of electrons in the conduction band, and subsequent re-trapping/recombination. Thus, we expect the exo-electron signal to reflect the instantaneous electron concentration in the conduction band. In this study, TR-OSE and time-resolved optically stimulated luminescence (TR-OSL) were measured for the first time using quartz, K-feldspar and NaCl by stimulating the samples using pulsed blue LEDs at different temperatures between 50 and 250 0 C after beta irradiation and preheating to 280 0 C. The majority of TR-OSE signals from all the samples decayed much faster than TR-OSL signals irrespective of the stimulation temperatures. This suggests that the lifetime of OSL in these dosimeters arises mainly from the relaxation of an excited state of the recombination centre, rather than from residence time of an electron in the conduction band.

  13. Time-resolved photoluminescence study of CdSe/CdMnS/CdS core/multi-shell nanoplatelets

    International Nuclear Information System (INIS)

    Murphy, J. R.; Delikanli, S.; Demir, H. V.; Scrace, T.; Zhang, P.; Norden, T.; Petrou, A.; Thomay, T.; Cartwright, A. N.

    2016-01-01

    We used photoluminescence spectroscopy to resolve two emission features in CdSe/CdMnS/CdS and CdSe/CdS core/multi-shell nanoplatelet heterostructures. The photoluminescence from the magnetic sample has a positive circular polarization with a maximum centered at the position of the lower energy feature. The higher energy feature has a corresponding signature in the absorption spectrum; this is not the case for the low-energy feature. We have also studied the temporal evolution of these features using a pulsed-excitation/time-resolved photoluminescence technique to investigate their corresponding recombination channels. A model was used to analyze the temporal dynamics of the photoluminescence which yielded two distinct timescales associated with these recombination channels. The above results indicate that the low-energy feature is associated with recombination of electrons with holes localized at the core/shell interfaces; the high-energy feature, on the other hand, is excitonic in nature with the holes confined within the CdSe cores.

  14. Dispersion of sulphur in the northern hemisphere. A study with a 3-dimensional time-resolved model

    Energy Technology Data Exchange (ETDEWEB)

    Tarrason, L.

    1995-12-31

    This thesis on atmospheric dispersion of sulphur presents a calculation of intercontinental transport of oxidized sulphur and allocates different contributions to sulphur background levels over Europe. It is found that a significant fraction of anthropogenic sulphur (AS) is transported out of continental boundaries thus affecting the background levels over major parts of the northern hemisphere. Over Europe, the contribution of AS from North America is similar in amount to that of Asian AS and natural sources from the North Atlantic Ocean. Although the yearly contribution of intercontinental transport to deposition of sulphur over Europe is quite small, it can be much more important over certain areas and seasons and is comparable to the contributions from individual European countries. The calculations are based on a three-dimensional Eulerian time-resolved model that describes sulphur dispersion in the atmosphere in connection with large-scale synoptic flows and agree well with observations. The thesis emphasizes the role of synoptic scale atmospheric motions in determining intercontinental transport of sulphur. It indicates the need to resolve individual cyclones and anticyclones in order to describe the dispersion and distribution of atmospheric sulphur in the northern hemisphere and stresses the value of comparing model calculations with observations, both in atmospheric chemistry studies and in climate applications. 260 refs., 50 figs., 17 tabs.

  15. Time-resolved photoluminescence study of CdSe/CdMnS/CdS core/multi-shell nanoplatelets

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, J. R. [Department of Electrical Engineering, State University of New York, University at Buffalo, Buffalo, New York 14260 (United States); Department of Physics, State University of New York, University at Buffalo, Buffalo, New York 14260 (United States); Delikanli, S.; Demir, H. V., E-mail: volkan@bilkent.edu.tr [LUMINOUS Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Materials Sciences, Nanyang Technological University, Singapore 639798 (Singapore); Department of Electrical and Electronics Engineering, Department of Physics, UNAM−Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800 (Turkey); Scrace, T.; Zhang, P.; Norden, T.; Petrou, A., E-mail: petrou@buffalo.edu [Department of Physics, State University of New York, University at Buffalo, Buffalo, New York 14260 (United States); Thomay, T.; Cartwright, A. N. [Department of Electrical Engineering, State University of New York, University at Buffalo, Buffalo, New York 14260 (United States)

    2016-06-13

    We used photoluminescence spectroscopy to resolve two emission features in CdSe/CdMnS/CdS and CdSe/CdS core/multi-shell nanoplatelet heterostructures. The photoluminescence from the magnetic sample has a positive circular polarization with a maximum centered at the position of the lower energy feature. The higher energy feature has a corresponding signature in the absorption spectrum; this is not the case for the low-energy feature. We have also studied the temporal evolution of these features using a pulsed-excitation/time-resolved photoluminescence technique to investigate their corresponding recombination channels. A model was used to analyze the temporal dynamics of the photoluminescence which yielded two distinct timescales associated with these recombination channels. The above results indicate that the low-energy feature is associated with recombination of electrons with holes localized at the core/shell interfaces; the high-energy feature, on the other hand, is excitonic in nature with the holes confined within the CdSe cores.

  16. Digital autoradiography technique for studying of spatial Impurity distributions Delara

    International Nuclear Information System (INIS)

    Khamrayeva, S.

    2001-01-01

    In this report, the possibilities of the digital image processing for autoradiographic investigations of impurity distributions in the different objects (crystals, biology, geology et al) are shown. Activation autoradiography based on the secondary beta-irradiation is the method spread widely for investigations of the spatial distribution of chemical elements in the different objects. The analysis of autoradiography features is connected with the elucidation of optical density distribution of photoemulsion by means of photometry. The photoemulsion is used as detector of secondary beta irradiation. For different technological and nature materials to have elemental shifts the fine structure of chemical element distribution is often interested. But photometry makes it difficult to study the inhomogeneous chemical elements with the little gradient of concentration (near 20%). Therefore, the suppression of the background and betterment of linear solvability are the main problems of autoradiographic analysis. Application of the fast-acting digital computers and the technical means of signals treatment are allowed to spread the possibilities and the resolution of activation autoradiography. Mechanism of creation of autoradiographic features is described. The treatment of autoradiograms was conducted with the help of the dialogue system having matrix in 512 x 512 elements. For the interpretation of the experimental data clustering analysis methodology was used. Classification of the zones on the minimum of the square mistake was conducted according to the data of histograms of the optical densities of the studying autoradiograms. It was proposed algorithm for digital treatment for reconstruction of autoradiographic features. At a minimal contrast the resolution of the method has been enhanced on the degree by adaptation of methods of digital image processing (DIP) to suppress background activity. Results of the digital autoradiographic investigations of spatial impurity

  17. Spatially-resolved in-situ quantification of biofouling using optical coherence tomography (OCT) and 3D image analysis in a spacer filled channel

    KAUST Repository

    Fortunato, Luca; Bucs, Szilard; Valladares Linares, Rodrigo; Cali, Corrado; Vrouwenvelder, Johannes S.; Leiknes, TorOve

    2016-01-01

    The use of optical coherence tomography (OCT) to investigate biomass in membrane systems has increased with time. OCT is able to characterize the biomass in-situ and non-destructively. In this study, a novel approach to process three-dimensional (3D

  18. Time-resolved imaging and immobilization study of biomaterials on hydrophobic and superhydrophobic surfaces by means of laser-induced forward transfer

    International Nuclear Information System (INIS)

    Boutopoulos, Christos; Chatzipetrou, Marianneza; Zergioti, Ioanna; Papathanasiou, Athanasios G

    2014-01-01

    In this work, we present the generation of high velocity liquid jets of a photosynthetic biomaterial in buffer solution (i.e. thylakoid membranes) and a test solution, using the laser-induced forward transfer (LIFT) technique. The high impact pressure of the collision of the jets on solid substrates, ranging from 0.045 MPa–35 MPa, resulted in strong physical immobilization of the photosynthetic biomaterial on superhydrophobic (SH) poly(methyl methacrylate) (PMMA) surfaces and hydrophobic gold surfaces. The immobilization efficiency was evaluated by fluorescence microscopy, while time-resolved imaging of the LIFT process was carried out to study the corresponding LIFT dynamics. The results show that this simple, direct and chemical-linkers-free immobilization technique is valuable for several biosensors and microfluidic applications since it can be applied to a variety of hydrophobic and SH substrates, leading to the selective immobilization of the biomaterials, due to the high spatial printing resolution of the LIFT technique. (letter)

  19. Study of Rayleigh-Love coupling from Spatial Gradient Observation

    Science.gov (United States)

    Lin, C. J.; Hosseini, K.; Donner, S.; Vernon, F.; Wassermann, J. M.; Igel, H.

    2017-12-01

    We present a new method to study Rayleigh-Love coupling. Instead of using seismograms solely, where ground motion is recorded as function of time, we incorporate with rotation and strain, also called spatial gradient where ground is represented as function of distance. Seismic rotation and strain are intrinsic different observable wavefield so are helpful to indentify wave type and wave propagation. A Mw 7.5 earthquake on 29 March 2015 occurred in Kokopo, Papua New Guinea recorded by a dense seismic array at PFO, California are used to obtaint seismic spatial gradient. We firstly estimate time series of azimuthal direction and phase velocity of SH wave and Rayleigh wave by analyzing collocated seismograms and rotations. This result also compares with frequency wavenumber methods using a nearby ANZA seismic array. We find the direction of Rayleigh wave fits well with great-circle back azimuth during wave propagation, while the direction of Love wave deviates from that, especially when main energy of Rayleigh wave arrives. From the analysis of cross-correlation between areal strain and vertical rotation, it reveals that high coherence, either positive or negative, happens at the same time when Love wave deparate from great-circle path. We also find the observed azimuth of Love wave and polarized particle motion of Rayleigh wave fits well with the fast direction of Rayleigh wave, for the period of 50 secs. We conclude the cause of deviated azimuth of Love wave is due to Rayleigh-Love coupling, as surface wave propagates through the area with anisotropic structure.

  20. Spatially resolved photoluminescence and AFM measurements on Cu(In,Ga)Se{sub 2}-based thin film absorbers prepared with different throughput speeds

    Energy Technology Data Exchange (ETDEWEB)

    Meessen, Max; Neumann, Oliver; Heise, Stephan J.; Brueggemann, Rudolf; Bauer, Gottfried H. [Institut fuer Physik, Carl von Ossietzky Universitaet Oldenburg (Germany); Witte, Wolfram; Hariskos, Dimitrios [Zentrum fuer Sonnenenergie- und Wasserstoff-Forschung Baden-Wuerttemberg (ZSW), Stuttgart (Germany)

    2011-07-01

    We study the behavior and interdependence of quantities such as photoluminescence (PL) yield, quasi-Fermi level splitting and AFM-determined surface roughness on CIGS thin-film absorbers with different thicknesses between 0.25 and 3 {mu}m achieved by varying the throughput speed in an in-line physical vapor deposition (PVD) process. These quantities are studied on the macroscopic as well as on the microscopic scale with a resolution of approximately 1 {mu}m. It is shown that the structural sizes of the inhomogeneities of the absorber layer itself and its lateral photoluminescence properties decrease with decreasing absorber thickness. These results are compared to those on samples thinned by bromine-methanol etching. Furthermore, we show that varying the thickness of the CdS buffer layer on top of the absorber influences surface recombination and thereby PL yield and quasi-Fermi level splitting. A decrease in surface recombination at higher buffer thicknesses has to be weighed against the increase in absorption in the buffer layer, which in turn decreases carrier generation in the absorber layer.

  1. Material-specific imaging system using energy-dispersive X-ray diffraction and spatially resolved CdZnTe detectors with potential application in breast imaging

    Energy Technology Data Exchange (ETDEWEB)

    Barbes, Damien, E-mail: damien.barbes@cea.fr [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, F-38054 Grenoble (France); Tabary, Joachim, E-mail: joachim.tabary@cea.fr [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, F-38054 Grenoble (France); Paulus, Caroline, E-mail: caroline.paulus@cea.fr [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, F-38054 Grenoble (France); Hazemann, Jean-Louis, E-mail: jean-louis.hazemann@neel.cnrs.fr [Univ.Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Verger, Loïck, E-mail: loick.verger@cea.fr [Univ. Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, F-38054 Grenoble (France)

    2017-03-11

    This paper presents a coherent X-ray-scattering imaging technique using a multipixel energy-dispersive system. Without any translation, the technique produces specific 1D image from data recorded by a single CdZnTe detector pixel using subpixelation techniques. The method is described in detail, illustrated by a simulation and then experimentally validated. As the main considered application of our study is breast imaging, this validation involves 2D imaging of a phantom made of plastics mimicking breast tissues. The results obtained show that our system can specifically image the phantom using a single detector pixel. For the moment, in vivo breast imaging applications remain difficult, as the dose delivered by the system is too high, but some adjustments are considered for further work.

  2. Spatially resolved vacuum tunneling spectroscopy on Bi 2Sr 2CaCu 2O 8 by STM at 4.8K

    Science.gov (United States)

    Renner, Ch.; Fischer, Ø.; Kent, A. D.; Mitzi, D. B.; Kapitulnik, A.

    1994-02-01

    We report scanning tunneling spectroscopy investigations on in-situ cleaved superconducting Bi 2Sr 2CaCu 2O 8 single crystals. Although many investigators report reproducible tunneling studies on high temperature superconductors, there nevertheless remains uncertainties about the correct intrinsic shape of the tunneling spectra. We have been able to obtain higly reproducible spectra while scanning single crystal surfaces in many different areas and taking a spectra every 5Å along lines of several hundred Ångstroms. Furthermore, we show that the spectra are independent of modifacations of the barrier obtained by changing the tip/sample distance. The experimental density of states clearly shows some filling of the gap which does not fit with a BCS-like s-wave prediction, even if some scattering in the tunneling process is accounted for.

  3. Spatially resolved vacuum tunneling spectroscopy on Bi2Sr2CaCu2O8 by STM at 4.8K

    International Nuclear Information System (INIS)

    Renner, C.; Fischer, Oe.; Kent, A.D.; Mitzi, D.B.; Kapitulnik, A.

    1994-01-01

    We report scanning tunneling spectroscopy investigations on in-situ cleaved superconducting Bi 2 Sr 2 CaCu 2 O 8 single crystals. Although many investigators report reproducible tunneling studies on high temperature superconductors, there nevertheless remains uncertainties about the correct intrinsic shape of the tunneling spectra. We have been able to obtain highly reproducible spectra while scanning single crystal surfaces in many different areas and taking a spectra every 5A along lines of several hundred AAngstroms. Furthermore, we show that the spectra are independent of modifications of the barrier obtained by changing the tip/sample distance. The experimental density of states clearly shows some filling of the gap which does not fit with a BCS-like s-wave prediction, even if some scattering in the tunneling process is accounted for. (orig.)

  4. A method for evaluating spatially-resolved NOx emissions using Kalman filter inversion, direct sensitivities, and space-based NO2 observations

    Directory of Open Access Journals (Sweden)

    R. V. Martin

    2008-09-01

    Full Text Available An inverse modeling method was developed and tested for identifying possible biases in emission inventories using satellite observations. The relationships between emission inputs and modeled ambient concentrations were estimated using sensitivities calculated with the decoupled direct method in three dimensions (DDM-3D implemented within the framework of the Community Multiscale Air Quality (CMAQ regional model. As a case study to test the approach, the method was applied to regional ground-level NOx emissions in the southeastern United States as constrained by observations of NO2 column densities derived from the Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY satellite instrument. A controlled "pseudodata" scenario with a known solution was used to establish that the methodology can achieve the correct solution, and the approach was then applied to a summer 2004 period where the satellite data are available. The results indicate that emissions biases differ in urban and rural areas of the southeast. The method suggested slight downward (less than 10% adjustment to urban emissions, while rural region results were found to be highly sensitive to NOx processes in the upper troposphere. As such, the bias in the rural areas is likely not solely due to biases in the ground-level emissions. It was found that CMAQ was unable to predict the significant level of NO2 in the upper troposphere that was observed during the NASA Intercontinental Chemical Transport Experiment (INTEX measurement campaign. The best correlation between satellite observations and modeled NO2 column densities, as well as comparison to ground-level observations of NO2, was obtained by performing the inverse while accounting for the significant presence of NO2 in the upper troposphere not captured by the regional model.

  5. Spatially resolved star formation and dust attenuation in Mrk 848: Comparison of the integral field spectra and the UV-to-IR SED

    Science.gov (United States)

    Yuan, Fang-Ting; Argudo-Fernández, María; Shen, Shiyin; Hao, Lei; Jiang, Chunyan; Yin, Jun; Boquien, Médéric; Lin, Lihwai

    2018-05-01

    We investigate the star formation history and the dust attenuation in the galaxy merger Mrk 848. Thanks to the multiwavelength photometry from the ultraviolet (UV) to the infrared (IR), and MaNGA's integral field spectroscopy, we are able to study this merger in a detailed way. We divide the whole merger into the core and tail regions, and fit both the optical spectrum and the multi-band spectral energy distribution (SED) to models to obtain the star formation properties for each region respectively. We find that the color excess of stars in the galaxy E(B-V)sSED measured with the multi-band SED fitting is consistent with that estimated both from the infrared excess (the ratio of IR to UV flux) and from the slope of the UV continuum. Furthermore, the reliability of the E(B-V)sSED is examined with a set of mock SEDs, showing that the dust attenuation of the stars can be well constrained by the UV-to-IR broadband SED fitting. The dust attenuation obtained from optical continuum E(B-V)sspec is only about half of E(B-V)sSED. The ratio of the E(B-V)sspec to the E(B-V)g obtained from the Balmer decrement is consistent with the local value (around 0.5). The difference between the results from the UV-to-IR data and the optical data is consistent with the picture that younger stellar populations are attenuated by an extra dust component from the birth clouds compared to older stellar populations which are only attenuated by the diffuse dust. Both with the UV-to-IR SED fitting and the spectral fitting, we find that there is a starburst younger than 100 Myr in one of the two core regions, consistent with the scenario that the interaction-induced gas inflow can enhance the star formation in the center of galaxies.

  6. SDSS-IV MaNGA: Spatially resolved star formation histories in galaxies as a function of galaxy mass and type

    Science.gov (United States)

    Goddard, D.; Thomas, D.; Maraston, C.; Westfall, K.; Etherington, J.; Riffel, R.; Mallmann, N. D.; Zheng, Z.; Argudo-Fernández, M.; Lian, J.; Bershady, M.; Bundy, K.; Drory, N.; Law, D.; Yan, R.; Wake, D.; Weijmans, A.; Bizyaev, D.; Brownstein, J.; Lane, R. R.; Maiolino, R.; Masters, K.; Merrifield, M.; Nitschelm, C.; Pan, K.; Roman-Lopes, A.; Storchi-Bergmann, T.; Schneider, D. P.

    2017-04-01

    We study the internal gradients of stellar population properties within 1.5 Re for a representative sample of 721 galaxies, with stellar masses ranging between 109 M⊙ and 1011.5 M⊙ from the SDSS-IV MaNGA Integral-Field-Unit survey. Through the use of our full spectral fitting code firefly, we derive light- and mass-weighted stellar population properties and their radial gradients, as well as full star formation and metal enrichment histories. We also quantify the impact that different stellar population models and full spectral fitting routines have on the derived stellar population properties and the radial gradient measurements. In our analysis, we find that age gradients tend to be shallow for both early-type and late-type galaxies. Mass-weighted age gradients of early-types arepositive (˜0.09 dex/Re) pointing to 'outside-in' progression of star formation, while late-type galaxies have negative light-weighted age gradients (˜-0.11 dex/Re), suggesting an 'inside-out' formation of discs. We detect negative metallicity gradients in both early- and late-type galaxies, but these are significantly steeper in late-types, suggesting that the radial dependence of chemical enrichment processes and the effect of gas inflow and metal transport are far more pronounced in discs. Metallicity gradients of both morphological classes correlate with galaxy mass, with negative metallicity gradients becoming steeper with increasing galaxy mass. The correlation with mass is stronger for late-type galaxies, with a slope of d(∇[Z/H])/d(log M) ˜ -0.2 ± 0.05 , compared to d(∇[Z/H])/d(log M) ˜ -0.05 ± 0.05 for early-types. This result suggests that the merger history plays a relatively small role in shaping metallicity gradients of galaxies.

  7. SPATIALLY RESOLVED [Fe II] 1.64 μm EMISSION IN NGC 5135: CLUES FOR UNDERSTANDING THE ORIGIN OF THE HARD X-RAYS IN LUMINOUS INFRARED GALAXIES

    International Nuclear Information System (INIS)

    Colina, L.; Pereira-Santaella, M.; Alonso-Herrero, A.; Arribas, S.; Bedregal, A. G.

    2012-01-01

    Spatially resolved near-IR and X-ray imaging of the central region of the luminous infrared galaxy (LIRG) NGC 5135 is presented. The kinematical signatures of strong outflows are detected in the [Fe II] 1.64 μm emission line in a compact region at 0.9 kpc from the nucleus. The derived mechanical energy release is consistent with a supernova rate of 0.05-0.1 yr –1 . The apex of the outflowing gas spatially coincides with the strongest [Fe II] emission peak and with the dominant component of the extranuclear hard X-ray emission. All these features provide evidence for a plausible direct physical link between supernova-driven outflows and the hard X-ray emitting gas in an LIRG. This result is consistent with model predictions of starbursts concentrated in small volumes and with high thermalization efficiencies. A single high-mass X-ray binary (HMXB) as the major source of the hard X-ray emission, although not favored, cannot be ruled out. Outside the active galactic nucleus, the hard X-ray emission in NGC 5135 appears to be dominated by the hot interstellar medium produced by supernova explosions in a compact star-forming region, and not by the emission due to HMXBs. If this scenario is common to (ultra)luminous infrared galaxies, the hard X-rays would only trace the most compact (≤100 pc) regions with high supernova and star formation densities, therefore a lower limit to their integrated star formation. The star formation rate derived in NGC 5135 based on its hard X-ray luminosity is a factor of two and four lower than the values obtained from the 24 μm and soft X-ray luminosities, respectively.

  8. Can RNA-Seq resolve the rapid radiation of advanced moths and butterflies (Hexapoda: Lepidoptera: Apoditrysia)? An exploratory study.

    Science.gov (United States)

    Bazinet, Adam L; Cummings, Michael P; Mitter, Kim T; Mitter, Charles W

    2013-01-01

    Recent molecular phylogenetic studies of the insect order Lepidoptera have robustly resolved family-level divergences within most superfamilies, and most divergences among the relatively species-poor early-arising superfamilies. In sharp contrast, relationships among the superfamilies of more advanced moths and butterflies that comprise the mega-diverse clade Apoditrysia (ca. 145,000 spp.) remain mostly poorly supported. This uncertainty, in turn, limits our ability to discern the origins, ages and evolutionary consequences of traits hypothesized to promote the spectacular diversification of Apoditrysia. Low support along the apoditrysian "backbone" probably reflects rapid diversification. If so, it may be feasible to strengthen resolution by radically increasing the gene sample, but case studies have been few. We explored the potential of next-generation sequencing to conclusively resolve apoditrysian relationships. We used transcriptome RNA-Seq to generate 1579 putatively orthologous gene sequences across a broad sample of 40 apoditrysians plus four outgroups, to which we added two taxa from previously published data. Phylogenetic analysis of a 46-taxon, 741-gene matrix, resulting from a strict filter that eliminated ortholog groups containing any apparent paralogs, yielded dramatic overall increase in bootstrap support for deeper nodes within Apoditrysia as compared to results from previous and concurrent 19-gene analyses. High support was restricted mainly to the huge subclade Obtectomera broadly defined, in which 11 of 12 nodes subtending multiple superfamilies had bootstrap support of 100%. The strongly supported nodes showed little conflict with groupings from previous studies, and were little affected by changes in taxon sampling, suggesting that they reflect true signal rather than artifacts of massive gene sampling. In contrast, strong support was seen at only 2 of 11 deeper nodes among the "lower", non-obtectomeran apoditrysians. These represent a much

  9. Can RNA-Seq resolve the rapid radiation of advanced moths and butterflies (Hexapoda: Lepidoptera: Apoditrysia? An exploratory study.

    Directory of Open Access Journals (Sweden)

    Adam L Bazinet

    Full Text Available Recent molecular phylogenetic studies of the insect order Lepidoptera have robustly resolved family-level divergences within most superfamilies, and most divergences among the relatively species-poor early-arising superfamilies. In sharp contrast, relationships among the superfamilies of more advanced moths and butterflies that comprise the mega-diverse clade Apoditrysia (ca. 145,000 spp. remain mostly poorly supported. This uncertainty, in turn, limits our ability to discern the origins, ages and evolutionary consequences of traits hypothesized to promote the spectacular diversification of Apoditrysia. Low support along the apoditrysian "backbone" probably reflects rapid diversification. If so, it may be feasible to strengthen resolution by radically increasing the gene sample, but case studies have been few. We explored the potential of next-generation sequencing to conclusively resolve apoditrysian relationships. We used transcriptome RNA-Seq to generate 1579 putatively orthologous gene sequences across a broad sample of 40 apoditrysians plus four outgroups, to which we added two taxa from previously published data. Phylogenetic analysis of a 46-taxon, 741-gene matrix, resulting from a strict filter that eliminated ortholog groups containing any apparent paralogs, yielded dramatic overall increase in bootstrap support for deeper nodes within Apoditrysia as compared to results from previous and concurrent 19-gene analyses. High support was restricted mainly to the huge subclade Obtectomera broadly defined, in which 11 of 12 nodes subtending multiple superfamilies had bootstrap support of 100%. The strongly supported nodes showed little conflict with groupings from previous studies, and were little affected by changes in taxon sampling, suggesting that they reflect true signal rather than artifacts of massive gene sampling. In contrast, strong support was seen at only 2 of 11 deeper nodes among the "lower", non-obtectomeran apoditrysians. These

  10. The electronic structure of clean and adsorbate-covered Bi2Se3: an angle-resolved photoemission study

    DEFF Research Database (Denmark)

    Bianchi, Marco; Hatch, Richard; Guan, Dandan

    2012-01-01

    Angle-resolved photoelectron spectroscopy is used for a detailed study of the electronic structure of the topological insulator Bi2Se3. Nominally stoichiometric and calcium-doped samples were investigated. The pristine surface shows the topological surface state in the bulk band gap. As time passes....... For a sufficiently strong band bending, additional states appear at the Fermi level. These are interpreted as quantized conduction band states. For large band bendings, these states are found to undergo a strong Rashba splitting. The formation of quantum well states is also observed for the valence band states......, the Dirac point moves to higher binding energies, indicating an increasingly strong downward bending of the bands near the surface. This time-dependent band bending is related to a contamination of the surface and can be accelerated by intentionally exposing the surface to carbon monoxide and other species...

  11. An energy resolved electron-ion coincidence study near the S 2p thresholds of the SF6 molecule

    International Nuclear Information System (INIS)

    Kivimaeki, A; Ruiz, J Alvarez; Erman, P; Hatherly, P; Garcia, E Melero; Rachlew, E; Rius i Riu, J; Stankiewicz, M

    2003-01-01

    The fragmentation dynamics of the SF 6 molecule following the excitations of S 2p electrons into unoccupied molecular orbitals has been studied using the energy-resolved electron-ion coincidence technique. Fragmentation patterns were found to depend on the particular excitation and on the electronic state of the molecular ion. The spectator resonant Auger decay at the 2p → 6a 1g resonance induces changes in the ion distributions as compared to direct photoionization. Furthermore, coincidence spectra related to the same Auger structure display different ion abundances at the 2t 2g and 4e g shape resonances. Differences were also found in the Auger decay spectra. These findings give further support for the previously suggested many-electron character of the 4e g shape resonance

  12. ESR spectrometer with a loop-gap resonator for cw and time resolved studies in a superconducting magnet.

    Science.gov (United States)

    Simon, Ferenc; Murányi, Ferenc

    2005-04-01

    The design and performance of an electron spin resonance spectrometer operating at 3 and 9 GHz microwave frequencies combined with a 9-T superconducting magnet are described. The probehead contains a compact two-loop, one gap resonator, and is inside the variable temperature insert of the magnet enabling measurements in the 0-9T magnetic field and 1.5-400 K temperature range. The spectrometer allows studies on systems where resonance occurs at fields far above the