WorldWideScience

Sample records for sorption takes place

  1. Taking place, screening place

    DEFF Research Database (Denmark)

    Hansen, Kim Toft; Waade, Anne Marit

    2019-01-01

    We introduce location studies as a new empirical approach to screen studies. Location studies represent an interdisciplinary perspective, including media, aesthetics and geography, and reflect a growing interest in places in a global media and consumption culture. The chapter analyses two recent......) with one being traditional and the other being commercial; both dramas include discussions of localities and social heritage, and both use local sports as a common metaphor for social cohesion; and both series have been partly funded by a local film Danish commissioner. However, The Legacy is shot...... to a large extent in studios, while Norskov is shot entirely on location. The study is based on interviews with producers, broadcasters, location scouts, production designers and writers, as well as quantitative and qualitative textual analyses of television drama series, the geographical places, and related...

  2. Then Daddy Takes His Place in an Australian Landscape

    OpenAIRE

    ERIN GAYLE CROUCH

    2018-01-01

    This writing accompanies a 62 minute, single channel, digital film work also titled Then Daddy Takes His Place in an Australian Landscape. The research considers themes of loss and disorientation in the above film and the film practice of Belgian filmmaker Chantal Akerman. Formally, the following writing interweaves critical engagements with Akerman’s films including No Home Movie (2015), Jeanne Dielman, 23 Commerce Quay, 1080 Brussels(1975), Là Bas (2006), with personal stories and reflecti...

  3. Mathematical modeling of phase interaction taking place in materials processing

    International Nuclear Information System (INIS)

    Zinigrad, M.

    2002-01-01

    The quality of metallic products depends on their composition and structure. The composition and the structure are determined by various physico-chemical and technological factors. One of the most important and complicated problems in the modern industry is to obtain materials with required composition, structure and properties. For example, deep refining is a difficult task by itself, but the problem of obtaining the material with the required specific level of refining is much more complicated. It will take a lot of time and will require a lot of expanses to solve this problem empirically and the result will be far from the optimal solution. The most effective way to solve such problems is to carry out research in two parallel direction. Comprehensive analysis of thermodynamics, kinetics and mechanisms of the processes taking place at solid-liquid-gaseous phase interface and building of the clear well-based physico-chemical model of the above processes taking into account their interaction. Development of mathematical models of the specific technologies which would allow to optimize technological processes and to ensure obtaining of the required properties of the products by choosing the optimal composition of the raw materials. We apply the above unique methods. We developed unique methods of mathematical modeling of phase interaction at high temperatures. These methods allows us to build models taking into account: thermodynamic characteristics of the processes, influence of the initial composition and temperature on the equilibrium state of the reactions, kinetics of homogeneous and heterogeneous processes, influence of the temperature, composition, speed of the gas flows, hydrodynamic and thermal factors on the velocity of the chemical and diffusion processes. The models can be implemented in optimization of various metallurgical processes in manufacturing of steels and non-ferrous alloys as well as in materials refining, alloying with special additives

  4. Does olfactory specific satiety take place in a natural setting?

    Science.gov (United States)

    Fernandez, P; Bensafi, M; Rouby, C; Giboreau, A

    2013-01-01

    Olfactory-specific satiety (OSS) is characterized by a specific decrease in the odor pleasantness of a food eaten to satiety or smelled without ingestion. The usual protocol for studying OSS takes place in laboratory, a setting rather removed from the real world. Here, we set out to examine OSS in a natural setting: during a meal in a restaurant. We hypothesized that an aroma contained in a food that is eaten at the beginning of a meal decreases the pleasantness of the flavor of a food with the same aroma eaten at the end of the meal. In the first experiment (Experiment 1), a test group received an appetizer flavored with a test aroma (anise) at the beginning of the meal. After the main dish, they received a dessert flavored with the same aroma. A control group received the same aromatized dessert, but after a non-aromatized appetizer. This experiment was replicated (Experiment 2) using verbena as the test aroma. For both experiments, results revealed that aroma pleasantness, but not intensity or familiarity, significantly decreased in the test groups vs. the control groups. These findings extend the concept of OSS to a realistic eating context. Copyright © 2012 Elsevier Ltd. All rights reserved.

  5. Key European Grid event to take place in Geneva

    CERN Multimedia

    2006-01-01

    EGEE'06 is the main conference of the EGEE project, which is co-funded by the European Union and hosted by CERN. More than 90 partners all over Europe and beyond are working together in EGEE to provide researchers in both academia and industry with access to major computing resources, independent of their geographic location. The largest user community of the EGEE Grid is the High-Energy Physics community and in particular the LHC experiments, which are already making heavy use of the infrastructure to prepare for data taking. However, with the many new challenges faced by EGEE in its second phase that started in April this year, an even broader audience than at previous EGEE conferences is expected. In particular, a large number of related Grid projects will feature prominently in both plenary and parallel sessions during the 5 days of this event. Industry will also be well represented, highlighting the EGEE project's commitment to technology transfer to industry. CERN is the host of the conference, which i...

  6. 4th openlab Board of Sponsors Meeting takes place at CERN on July 6, 2005

    CERN Multimedia

    Patrice Loïez

    2005-01-01

    The 4th openlab Board of Sponsors Meeting is taking place at CERN, room 513, 1-024, the 6th July 2005. The meeting will open with an Executive Session in the presence of Dr. Robert Aymar, Director General of CERN

  7. Waste Disposal: Processes Taking Place (on the way) from the Repository to the Biosphere

    International Nuclear Information System (INIS)

    Put, M.

    2000-01-01

    The main objective of SCK-CEN's R and D programme on the processes taking place on the way from the repository to the biosphere is to provide reliable and defensible models and parameters on the migration of dissolved radionuclides and gases through the host formation (Boom Clay) and the backfill materials of a deep geological repository for high level radioactive waste. The programme and main achievements in this topical area in 1999 are summarised

  8. The one-dimensional transport code CHET2, taking into account nonlinear, element-specific equilibrium sorption

    International Nuclear Information System (INIS)

    Luehrmann, L.; Noseck, U.

    1996-03-01

    While the verification report on CHET1 primarily focused on aspects such as the correctness of algorithms with respect to the modeling of advection, dispersion and diffusion, the report in hand is intended to primarily deal with nonlinear sorption and numerical sorption modeling. Another aspect discussed is the correct treatment of decay within established radioactive decay chains. First, the physical fundamentals are explained of the processes determining the radionuclide transport in the cap rock, and hence are the basis of the program discussed. The numeric algorithms the CHET2 code is based are explained, showing the details of realisation and the function of the various defaults and corrections. The iterative coupling of transport and sorption computation is illustrated by means of a program flowchart. Furthermore, the actvities for verification of the program are explained, as well as qualitative effects of computations assuming concentration-dependent sorption. The computation of the decay within decay chains is verified, and application programming using nonlinear sorption isotherms as well as the entire process of transport calculations with CHET2 are shown. (orig./DG) [de

  9. Diffusion mechanisms taking place at the early stages of cobalt deposition on Au(111)

    International Nuclear Information System (INIS)

    Oviedo, O A; Leiva, E P M; Mariscal, M M

    2008-01-01

    In the present work a detailed atomic-level analysis of some of the main diffusion mechanisms which take place during cobalt adatom deposition are studied within atom dynamics (AD) and the nudged elastic band (NEB) method. Our computer simulations reveal a very fast exchange between Co and Au atoms when the deposit is a single cobalt adatom. However, when the nucleus size increases, a decrease in the exchange probability is observed. Activation energies for different transitions are obtained using AD in combination with the NEB method

  10. DETERMINING THE FEATURES OF SPORTSWEAR TAKING PLACE IN FAST FASHION COLLECTIONS

    Directory of Open Access Journals (Sweden)

    Birsen ÇİLEROĞLU

    2014-07-01

    Full Text Available Spor ts occupies the first place among most siginificant factors increasing quality of life . It has b ecome difficult to allocate proper time for sports in the course of heavy work pace and flow of life . Such circumstances have led people to increase minor sport activities which could be done during short times allocated from daily living, thus, orienting people‟s clothing preference towards sportswear . The feeling of easiness and comfort sportswear offer to individuals enhances further such preference . The feeling of comfort individuals feel in their clothing depends on the presence of physiologic and psy chologic coherence between their bodies and environment . Demand for sportswear allowing easy - movement increased upon rise in life dynamism and standards, it began to be preferred regarding comfort of use and to take its place in daily clothing, too, define d as “casual” clothing . Spor tswear being preferred very much ; has caused the firms making and producing fashion and clothing design to give place in their collections to sportswear category . Particularly, in firms where model and clothing varieties are pl enty and new model design is made in short intervals, named as, “fast fashion” , tendency towards sportswear is growing increasingly . The sale rates of sportswear, utilization rates of which are growing increasingly, has maximum value among total clothing s ales in E - business field, too. In this research, it has been aimed to determine the features of sportswear taking place in “fast fashion” clothing collections . In order to accomplish this aim, 2014 collections of four different brands taking place in natio nal and international markets have been examined through visual analysis method . In the examinations; sportswear styles of the brand, model and style differences between brands and states of using 2014 fashion trends have been taken into account. The data obtained at the end of the analyses made have been

  11. [Marketing approval and market surveillance of medical devices in Germany: Where does policy integration take place?].

    Science.gov (United States)

    Lang, Achim

    2014-01-01

    Since 2011 new regulatory measures regarding medical devices have been set up with the aim to eliminate obstacles to innovations and to find more coordinated ways to marketing authorisation and market surveillance. This essay investigates whether these new and existing coordination mechanisms build up to a Joined-up Government approach. The analysis shows that the regulatory process should be adjusted along several dimensions. First, many organisations lack awareness regarding their stakeholders and focus solely on their immediate organisational activities. Second, the regulatory process (marketing authorisation and market surveillance) is too fragmented for an effective communication to take place. Finally, the underlying strategy process is an ad-hoc approach lacking continuity and continued involvement of, in particular, the responsible federal ministries. Copyright © 2013. Published by Elsevier GmbH.

  12. What it Takes to Successfully Implement Technology for Aging in Place: Focus Groups With Stakeholders.

    Science.gov (United States)

    Peek, Sebastiaan Theodorus Michaël; Wouters, Eveline J M; Luijkx, Katrien G; Vrijhoef, Hubertus J M

    2016-05-03

    There is a growing interest in empowering older adults to age in place by deploying various types of technology (ie, eHealth, ambient assisted living technology, smart home technology, and gerontechnology). However, initiatives aimed at implementing these technologies are complicated by the fact that multiple stakeholder groups are involved. Goals and motives of stakeholders may not always be transparent or aligned, yet research on convergent and divergent positions of stakeholders is scarce. To provide insight into the positions of stakeholder groups involved in the implementation of technology for aging in place by answering the following questions: What kind of technology do stakeholders see as relevant? What do stakeholders aim to achieve by implementing technology? What is needed to achieve successful implementations? Mono-disciplinary focus groups were conducted with participants (n=29) representing five groups of stakeholders: older adults (6/29, 21%), care professionals (7/29, 24%), managers within home care or social work organizations (5/29, 17%), technology designers and suppliers (6/29, 21%), and policy makers (5/29, 17%). Transcripts were analyzed using thematic analysis. Stakeholders considered 26 different types of technologies to be relevant for enabling independent living. Only 6 out of 26 (23%) types of technology were mentioned by all stakeholder groups. Care professionals mentioned fewer different types of technology than other groups. All stakeholder groups felt that the implementation of technology for aging in place can be considered a success when (1) older adults' needs and wishes are prioritized during development and deployment of the technology, (2) the technology is accepted by older adults, (3) the technology provides benefits to older adults, and (4) favorable prerequisites for the use of technology by older adults exist. While stakeholders seemed to have identical aims, several underlying differences emerged, for example, with regard

  13. Model of Wagons’ Placing-In and Taking-Out Problem in a Railway Station and Its Heuristic Algorithm

    Directory of Open Access Journals (Sweden)

    Chuijiang Guo

    2014-01-01

    Full Text Available Placing-in and taking-out wagons timely can decrease wagons’ dwell time in railway stations, improve the efficiency of railway transportation, and reduce the cost of goods transportation. We took the locomotive running times between goods operation sites as weights, so the wagons’ placing-in and taking-out problem could be regarded as a single machine scheduling problem, 1pijCmax, which could be transformed into the shortest circle problem in a Hamilton graph whose relaxation problem was an assignment problem. We used a Hungarian algorithm to calculate the optimal solution of the assignment problem. Then we applied a broken circle and connection method, whose computational complexity was O(n2, to find the available satisfactory order of wagons’ placing-in and taking-out. Complex problems, such as placing-in and transferring combined, taking-out and transferring combined, placing-in and taking-out combined, or placing-in, transferring, and taking-out combined, could also be resolved with the extended algorithm. A representative instance was given to illustrate the reliability and efficiency of our results.

  14. Taking back place-names – from dusty library to digital life

    DEFF Research Database (Denmark)

    Knudsen, Bo Nissen

    Danish place-names have been under publication since 1922 in the scientific series Danmarks Stednavne (Place-Names of Denmark) but only recently the huge project of a digitization of the series has been undertaken. Around 120,000 name articles are now on their way to the web as part of the Digital...... atlas of the Danish historical-administrative geography. Digitization and presentation of a scientific place-names edition poses many interesting problems in itself, especially regarding the variation over time in both the selection of names and the build-up of scholarly knowledge. How are we to convey...... mobility of the book format into a digital context – by making the content available as an application for mobile devices such as smart phones and iPads? Adding geocodes to the name articles could open up the possibility of a digital place-name lexicon allowing the end user to move around in a place...

  15. DSC studies of retrogradation and amylose-lipid transition taking place in gamma-irradiated wheat starch

    International Nuclear Information System (INIS)

    Ciesla, K.; Gluszewski, W.; Eliasson, A.C.

    2006-01-01

    It has been already shown that degradation resulting from gamma irradiation induces a decrease in order of starch granules and influences gelatinisation taking place during heating of starch and flour suspensions. In presented paper, DSC (differential scanning calorimetry) studies were carried out for wheat starch, non-irradiated and irradiated using doses in the range from 5 to 30 kGy. The influence of the conditions applied during DSC measurements on the possibility to observe differences between the amylose-lipid complex transition and retrogradation taking place in the non-irradiated and particularly irradiated starch samples was checked. The better differentiation between the amylose-lipid complex transition taking place in particular samples accompanied by the better reproducity were obtained in the case of dense suspensions as compared to the watery suspensions as well as during the first analysis performed for the recrystallised gels

  16. Sorption on inactive repository components

    International Nuclear Information System (INIS)

    Gardiner, M.P.; Smith, A.J.; Williams, S.J.

    1990-11-01

    The near-field of an intermediate level/low level radioactive waste repository will contain significant quantities of iron and steel, Magnox and Zircaloy. Their corrosion products may possess significant sorption capacity for radioelements. The sorption of americium and plutonium onto magnesium hydroxide, zirconium hydroxide, colloidal magnetite and colloidal haematite has been studied under conditions typical of the porewater of a cementitious near-field. R D values ≥ 10 5 m g -1 were measured for both actinides on the oxides and hydroxides. These values are at least as great as those measured on crushed 3:1 Blast Furnace Slag/Ordinary Portland cement. Competitive sorption experiments have shown that sorption onto the corrosion products does not take place in preference to that on the cement or the converse. Magnetite and haematite colloids are positively charged in cement-equilibrated water whilst zirconium hydroxide is negatively charged. Crushed cement was found to be positively charged. Simple experiments show that only a small proportion of haematite colloids is potentially mobile through a column of crushed cement. (author)

  17. Sorption on inactive repository components

    International Nuclear Information System (INIS)

    Gardiner, M.P.; Smith, A.J.; Williams, S.J.

    1990-07-01

    The near-field of an intermediate level/low level radioactive waste repository will contain significant quantities of iron and steel, Magnox and Zircaloy. Their corrosion products may possess significant sorption capacity for radioelements. The sorption of americium and plutonium onto magnesium hydroxide, zirconium hydroxide, colloidal magnetite and colloidal haematite has been studied under conditions typical of the porewater of a cementitious near-field. R D values ≥ 10 5 ml g -1 were measured for both actinides on the oxides and hydroxides. These values are at least as great at those measured on crushed 3:1 Blast Furnace Slag/Ordinary Portland Cement. Competitive sorption experiments have shown that sorption onto the corrosion products does not take place in preference to that on the cement or the converse. Magnetite and haematite colloids are positively charged in cement-equilibrated water whilst zirconium hydroxide is negatively charged. Crushed cement was found to be positively charged. Simple experiments show that only a small proportion of haematite colloids is potentially mobile through a column of crushed cement. (author)

  18. What it takes to successfully implement technology for aging in place: focus groups with stakeholders

    NARCIS (Netherlands)

    Eveline J.M. Wouters; Katrien G. Luijkx; Hubertus J.M. Vrijhoef; Sebastiaan Theodorus Michaël Peek MSc

    2016-01-01

    BACKGROUND: There is a growing interest in empowering older adults to age in place by deploying various types of technology (ie, eHealth, ambient assisted living technology, smart home technology, and gerontechnology). However, initiatives aimed at implementing these technologies are complicated by

  19. Advice from Rural Elders: What It Takes to Age in Place

    Science.gov (United States)

    Dye, Cheryl J.; Willoughby, Deborah F.; Battisto, Dina G.

    2011-01-01

    Older adults prefer to age in place (AIP), and there are psychological, physiological, and economic benefits in doing so. However, it is especially challenging to AIP in rural communities. AIP models have been tested in urban settings and age-segregated communities, but they are not appropriate for rural communities. This paper presents rural AIP…

  20. DETERMINING THE FEATURES OF SPORTSWEAR TAKING PLACE IN FAST FASHION COLLECTIONS

    OpenAIRE

    ÇİLEROĞLU, Birsen; KIVILCIMLAR, İnci

    2015-01-01

    Sports occupies the first place among most siginificant factors increasing quality of life. It has become difficult to allocate proper time for sports in the course of heavy work pace and flow of life. Such circumstances have led people to increase minor sport activities which could be done during short times allocated from daily living, thus, orienting people’s clothing preference towards sportswear. The feeling of easiness and comfort sportswear offer to individuals enhances further such pr...

  1. Beyond stereotypes of adolescent risk taking: Placing the adolescent brain in developmental context

    Directory of Open Access Journals (Sweden)

    Daniel Romer

    2017-10-01

    Full Text Available Recent neuroscience models of adolescent brain development attribute the morbidity and mortality of this period to structural and functional imbalances between more fully developed limbic regions that subserve reward and emotion as opposed to those that enable cognitive control. We challenge this interpretation of adolescent development by distinguishing risk-taking that peaks during adolescence (sensation seeking and impulsive action from risk taking that declines monotonically from childhood to adulthood (impulsive choice and other decisions under known risk. Sensation seeking is primarily motivated by exploration of the environment under ambiguous risk contexts, while impulsive action, which is likely to be maladaptive, is more characteristic of a subset of youth with weak control over limbic motivation. Risk taking that declines monotonically from childhood to adulthood occurs primarily under conditions of known risks and reflects increases in executive function as well as aversion to risk based on increases in gist-based reasoning. We propose an alternative Life-span Wisdom Model that highlights the importance of experience gained through exploration during adolescence. We propose, therefore, that brain models that recognize the adaptive roles that cognition and experience play during adolescence provide a more complete and helpful picture of this period of development.

  2. Sorption of Europium in zirconium silicate

    International Nuclear Information System (INIS)

    Garcia R, G.

    2004-01-01

    Some minerals have the property of sipping radioactive metals in solution, that it takes advantage to manufacture contention barriers that are placed in the repositories of nuclear wastes. The more recent investigations are focused in the development of new technologies guided to the sorption of alpha emissors on minerals which avoid their dispersion in the environment. In an effort to contribute to the understanding of this type of properties, some studies of sorption of Europium III are presented like homologous of the americium, on the surface of zirconium silicate (ZrSiO 4 ). In this work the results of sorption experiences are presented as well as the interpretation of the phenomena of the formation of species in the surface of the zirconium silicate. (Author)

  3. Understanding Where Americas Public Discussion Takes Place In Todays Society: Case Studies of Concealed Weapons Carry Reform

    Science.gov (United States)

    2016-06-01

    arguing that concealed carry permit holders are a danger to public safety and that mass shootings are taking place by citizens who are legally armed.2...who worked at an abortion clinic that had recently been bombed and whose life had been threatened was denied a license to carry because he was not...populace. The new law laid out new prohibitions and penalties enforceable statewide. Additionally, the Preemption Act was necessary to set the legal

  4. Coronavirus and influenza virus proteolytic priming takes place in tetraspanin-enriched membrane microdomains.

    Science.gov (United States)

    Earnest, James T; Hantak, Michael P; Park, Jung-Eun; Gallagher, Tom

    2015-06-01

    Coronaviruses (CoVs) and low-pathogenicity influenza A viruses (LP IAVs) depend on target cell proteases to cleave their viral glycoproteins and prime them for virus-cell membrane fusion. Several proteases cluster into tetraspanin-enriched microdomains (TEMs), suggesting that TEMs are preferred virus entry portals. Here we found that several CoV receptors and virus-priming proteases were indeed present in TEMs. Isolated TEMs, when mixed with CoV and LP IAV pseudoparticles, cleaved viral fusion proteins to fusion-primed fragments and potentiated viral transductions. That entering viruses utilize TEMs as a protease source was further confirmed using tetraspanin antibodies and tetraspanin short hairpin RNAs (shRNAs). Tetraspanin antibodies inhibited CoV and LP IAV infections, but their virus-blocking activities were overcome by expressing excess TEM-associated proteases. Similarly, cells with reduced levels of the tetraspanin CD9 resisted CoV pseudoparticle transductions but were made susceptible by overproducing TEM-associated proteases. These findings indicated that antibodies and CD9 depletions interfere with viral proteolytic priming in ways that are overcome by surplus proteases. TEMs appear to be exploited by some CoVs and LP IAVs for appropriate coengagement with cell receptors and proteases. Enveloped viruses use their surface glycoproteins to catalyze membrane fusion, an essential cell entry step. Host cell components prime these viral surface glycoproteins to catalyze membrane fusion at specific times and places during virus cell entry. Among these priming components are proteases, which cleave viral surface glycoproteins, unleashing them to refold in ways that catalyze virus-cell membrane fusions. For some enveloped viruses, these proteases are known to reside on target cell surfaces. This research focuses on coronavirus and influenza A virus cell entry and identifies TEMs as sites of viral proteolysis, thereby defining subcellular locations of virus

  5. Let us play: (unshackling liaisons, (unmasking games and (unhindered dialogue in the arena where theology takes place

    Directory of Open Access Journals (Sweden)

    Tanya van Wyk

    2017-10-01

    Full Text Available This contribution is a political-theological and hermeneutical reflection on the origin, nature, intention and contribution of a research theme identified within the dynamics of an institutional space, by taking a critical look at the �rules� and the �game� of university academia. Specific reference is made to institutional and faculty research themes, namely �reconciling diversity� and �Ecodomy � life in its fullness�. The institutional academic space is compared to a Hunger Games-style panopticon, with its �rules� and �play�. It is argued that these research themes can only make an authentic contribution if the �play� and �game�of the space in which these themes originate, are deconstructed. If this deconstruction can take place, there might be an authentic chance for unhindered dialogue towards the transformation of the academic space and the greater community it serves.

  6. The albedo problem in the case of multiple synthetic scattering taking place in a plane-symmetric slab

    International Nuclear Information System (INIS)

    Shafiq, A.; Meyer, H.E. de; Grosjean, C.C.

    1985-01-01

    An approximate model based on an improved diffusion-type theory is established for treating multiple synthetic scattering in a homogeneous slab of finite thickness. As in the case of the exact treatment given in the preceding paper (Part I), it appears possible to transform the considered transport problem into an equivalent fictitious one involving multiple isotropic scattering, therefore permitting the application of an established corrected diffusion theory for treating isotropic scattering taking place in a convex homogeneous medium bounded by a vacuum in the presence of various types of sources. The approximate values of the reflection and transmission coefficients are compared with the rigorous values listed in Part I. In this way, the high accuracy of the approximation is clearly demonstrated. (author)

  7. DSC Studies of Retrogradation and Amylose-Lipid Complex Transition Taking Place in Gamma Irradiated Wheat Starch

    International Nuclear Information System (INIS)

    Ciesla, K.

    2006-01-01

    Degradation resulting from gamma irradiation induces decrease in order of starch granules and influences the processes occurring in starch-water system. Differential scanning calorimetry (DSC) was applied at present for studying the effect of radiation with doses of 5 - 30 kGy on amylose-lipid complex transition and retrogradation occurring in wheat starch gels. Influence of the conditions applied during DSC measurements and intermediate storage was tested on the possibility to observe radiation effect. Wheat starch was irradiated with 60 C o gamma rays in a gamma cell Issledovatiel placed in the Department of Radiation Chemistry, INCT. DSC measurements were performed for ca. 50% and ca. 20% gels during heating - cooling - heating cycles (up to 3 cycles) in the temperature range 10 - 150 degree at heating and cooling rates of 10, 5 and 2.5 degree min - 1. The Seiko DSC 6200 calorimeter was used. Decrease in amylose-lipid complex transition temperature was found already after irradiation of wheat starch with a dose of 5 kGy showing modificatin of the complex structure. The differences between the irradiated and the non-irradiated samples became the easier seen in the every foregoing heating or cooling cycle as compared to the preceeding one. It is because that thermal treatment causes decrease of transition temperature in all the irradiated samples, with no effect or increase of that temperature observed in the non-irradiated ones. Irradiation hinders retrogradation taking place in ca. 50% gels but facilitates retrogradation occurring in ca. 20 % gels. Moreover, the expanded differences between the amylose-lipid complex formed in the irradiated and non-irradiated gels result due to their recrystallisation. Storage of the gels induces decrease in the temperature of the complex transition as compared to the last cycle of the first analysis. That decrease was, however, more significant in the case of all the irradiated samples than in the case of the initial sample. In

  8. Sorption mechanisms and sorption models

    International Nuclear Information System (INIS)

    Fedoroff, M.; Lefevre, G.; Duc, M.; Neskovic, C.; Milonjic, S.

    2004-01-01

    Sorption at the solid-liquid interfaces play a major role in many phenomena and technologies: chemical separations, catalysis, biological processes, transport of toxic and radioactive species in surface and underground waters. The long term safety of radioactive waste repositories is based on artificial and natural barriers, intended to sorb radionuclides after the moment when the storage matrixes and containers will be corroded. Predictions on the efficiency of sorption for more than 10 6 years have to be done in order to demonstrate the safety of such depositories, what is a goal never encountered in the history of sciences and technology. For all these purposes, and, especially for the long term prediction, acquiring of sorption data constitutes only a first step of studies. Modeling based on a very good knowledge of sorption mechanisms is needed. In this review, we shall examine the main approaches and models used to quantify sorption processes, including results taken from the literature and from our own studies. We shall compare sorption models and examine their adequacy with sorption mechanisms. The cited references are only a few examples of the numerous articles published in that field. (orig.)

  9. Where and How Do Aging Processes Take Place in Everyday Life? Answers From a New Materialist Perspective

    Directory of Open Access Journals (Sweden)

    Grit Höppner

    2018-04-01

    Full Text Available In the last decade, the focus of studies on age and aging has fundamentally changed from biological to symbolic, discursive, and cultural phenomena. Currently, the most studied topic in material gerontology is the materiality of age and aging in the context of everyday life. Scholars in this area have thus been making an important contribution to a material understanding of aging processes. As we understand them, however, both social constructivist and material gerontological concepts reach their limit when it comes to the questions of where and how aging processes actually take place in everyday life. In order to answer these two questions, we review social constructivist ideas with a particular focus on the “doing age” concept and material gerontological assumptions regarding human subjects, their material environments, and their relations. We then suggest rethinking bodily limitations and agencies addressed by scholars in the field of new materialism. The aim is to develop a new materialist-inspired understanding of aging processes that helps to reconstruct the material-discursive co-production of aging processes. These processes are deployed as mutual entanglements of materiality and meaning as well as of humans and non-human agency. This approach emphasizes the decentralization of the human actor and thus helps to map the material-discursive complexity of aging processes as relational co-products of humans and non-humans in everyday life.

  10. Sorption behaviour of caesium on a bentonite sample

    International Nuclear Information System (INIS)

    Hurel, C.; Marmier, N.; Fromage, F.; Seby, F.; Bourg, A.C.M.; Giffaut, E.

    2002-01-01

    Sorption of elements like Cs on clay is one of the principal processes delaying their release from deep repositories of nuclear wastes into the environment. The sorption processes taking place between non-purified natural clay material (bentonite) and synthetic groundwater (containing Ca, Mg, Na, K and carbonates) were therefore studied experimentally and modelled for Cs to determine whether thermodynamic computer codes capable of predicting the behaviour of this element in natural systems might be developed. The model used, based on the properties of a pure montmorillonite phase, incorporates the surface reactions for natural major ions and sorbing cations but does not have any adjustable parameters. The weight of each parameters used in the model is assessed. Surface reactions are classified as either major or minor, and a simplified model of Cs sorption that considers only the major processes is proposed. This simplified model might correspond to the less sophisticated thermodynamic model included in coupled geochemistry-transport models. (orig.)

  11. Laboratory tests on the impact of superabsorbent polymers on transformation and sorption of xenobiotics in soil taking 14C-imazalil as an example

    International Nuclear Information System (INIS)

    Achtenhagen, J.; Kreuzig, R.

    2011-01-01

    Due to water scarcity, the agricultural production in arid areas is dependent on a sustainable irrigation management. In order to optimize irrigation systems, the application of superabsorbent polymers (SAP) as soil amendments, frequently studied within the last years, may be an appropriate measure to enhance the water holding capacity and the plant-available water in poor arable soils. These persistent polymers are also able to reduce heavy metal and salt stress to crops by accumulating those inorganic compounds. However, the impact of SAP on fate and behavior of organic xenobiotics in soil is unknown. Therefore, transformation and sorption of the model substance 14 C-imazalil were monitored without and with SAP amendment in silty sand and sand soil under laboratory conditions. Within the 100-d incubation period, the transformation of 14 C-imazalil was not substantially affected by the SAP amendment even though the microbial activity increased considerably. In the silty sand soil, extractable residues dropped from 90% to 45% without and from 96% to 46% with SAP amendment. Non-extractable residues continuously increased up to 49% and 35% while mineralization reached 6% and 5%, respectively. In the sand soil, characterized by its lower microbial activity and lower organic carbon content, extractable residues merely dropped from 99% to 81% and from 100% to 85% while non-extractable residues increased from 2% to 14% and 1% to 10%, respectively. Mineralization was lower than 2%. The increased microbial activity, usually promoting transformation processes of xenobiotics, was compensated by the enhanced sorption in the amended soils revealed by the increase of soil/water distribution coefficients (K d ) of 26 to 42 L kg -1 for the silty sand and 6 to 25 L kg -1 for the sand, respectively. - Highlights: → Superabsorbent polymers (SAP) are applied as soil amendments to support irrigation measures. → The SAP effects on the fate of imazalil in soil were monitored under

  12. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data.

  13. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    International Nuclear Information System (INIS)

    Liu, Chang; Fiol, Núria; Villaescusa, Isabel; Poch, Jordi

    2016-01-01

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data

  14. Sorption-capacity limited retardation of radionuclides transport in water-saturated packing materials

    International Nuclear Information System (INIS)

    Pescatore, C.; Sullivan, T.

    1984-01-01

    Radionuclides breakthrough times as calculated through constant retardation factors obtained in dilute solutions are non-conservative. The constant retardation approach regards the solid as having infinite sorption capacity throughout the solid. However, as the solid become locally saturated, such as in the proximity of the waste form-packing materials interface, it will exhibit no retardation properties, and transport will take place as if the radionuclides were locally non-reactive. The magnitude of the effect of finite sorption capacity of the packing materials on radionuclide transport is discussed with reference to high-level waste package performance. An example based on literature sorption data indicated that the breakthrough time may be overpredicted by orders of magnitude using a constant retardation factor as compared to using the entire sorption isotherm to obtain a concentration-dependent retardation factor. 8 refs., 3 figs., 3 tabs

  15. Sorption-capacity limited retardation of radionuclides transport in water-saturated packing materials

    International Nuclear Information System (INIS)

    Pescatore, C.; Sullivan, T.

    1984-01-01

    Radionuclides breakthrough times as calculated through constant retardation factors obtained in dilute solutions are non-conservative. The constant retardation approach regards the solid as having infinite sorption capacity throughout the solid. However, as the solid becomes locally saturated, such as in the proximity of the waste form-packing materials interface, it will exhibit no retardation properties, and transport will take place as if the radionuclides were locally non-reactive. The magnitude of the effect of finite sorption capacity of the packing materials on radionuclide transport is discussed with reference to high-level waste package performance. An example based on literature sorption data indicates that the breakthrough time may be overpredicted by orders of magnitude using a constant retardation factor as compared to using the entire sorption isotherm to obtain a concentration-dependent retardation factor. 8 references, 3 figures, 3 tables

  16. Nature of transition element ions sorption by AN-61 and ANKB-10 ionites

    International Nuclear Information System (INIS)

    Mekvabishvili, T.V.; Kotov, Yu.I.; Kopylova, V.D.; Kachevskij, O.V.; Saldadze, K.M.

    1983-01-01

    The results of investigations into nature of sorption of iron (3), copper (2), zinc (2) cobalt (2), uranyl ions at contact of their salt solutions with AN-61 and ANKB-10 ionites using the; methods of IR-spectroscopy and potentiometry as well as experimental data on sorption properties of ionites are presented. Investigation into the nature of sorption of transition metals by AN-61 and ANKB-10 ionites has revealed that sorption of transition metals takes place at the expense of coordination and ion bonds formation between ions of the metals and functional groups of ionites. The effect of ion force of the solution on electro-donating properties of AN-61 and ANKB-10 ionites hous disclosed. Increase of ion force of the solution results in improvement of electron-donating properties in anionite and it does not practically affect ampholyte

  17. What does it take to make them stay? : how place satisfaction relates to willingness to stay of the creative class

    OpenAIRE

    Annell, Jonas; Terman, Felix

    2017-01-01

    Swedish students in smaller university host cities leave in favor of more attractive places after having completed their studies. Failing to retain newly graduated students is a problem for university host cities as educated people are associated with the group referred to as the creative class. Members of the creative class are drivers of regional economic growth, and have historically proven to be important for creating and developing the well-being of cities. Different place attributes hav...

  18. Properties of diclofenac sodium sorption onto natural zeolite modified with cetylpyridinium chloride.

    Science.gov (United States)

    Krajišnik, Danina; Daković, Aleksandra; Milojević, Maja; Malenović, Anđelija; Kragović, Milan; Bogdanović, Danica Bajuk; Dondur, Vera; Milić, Jela

    2011-03-01

    In this study an investigation of a model drug sorption onto cationic surfactant-modified natural zeolites as a drug formulation excipient was performed. Natural zeolite was modified with cetylpyridinium chloride in amounts equivalent to 100, 200 and 300% of its external cation-exchange capacity. The starting material and obtained organozeolites were characterized by Fourier transform infrared spectroscopy, zeta potential measurements and thermal analysis. In vitro sorption of diclofenac sodium as a model drug was studied for all surfactant/zeolite composites by means of sorption isotherm measurements in aqueous solutions (pH 7.4). The modified zeolites with three levels of surfactant coverage within the short activation time were prepared. Zeta potential measurements and thermal analysis showed that when the surfactant loading level was equal to external cation-exchange value, almost monolayer of organic phase were present at the zeolitic surface while higher amounts of surfactant produced less extended bilayers, ordered bilayers or admicelles at the zeolitic surface. Modified zeolites, obtained in this manner, were effective in diclofenac sodium sorption and the organic phase derived from adsorbed cetylpyridinium chloride was the primary sorption phase for the model drug. The Langmuir isotherm was found to describe the equilibrium sorption data well over the entire concentration range. The separate contributions of the adsorption and partition to the total sorption of DS were analyzed mathematically. Results revealed that that adsorption and partitioning of the model drug take place simultaneously. 2010 Elsevier B.V. All rights reserved.

  19. Young People Take Their Rightful Places as Full and Contributing Members of a World Class Workforce: Philadelphia Youth Network Annual Report 2006

    Science.gov (United States)

    Philadelphia Youth Network, 2006

    2006-01-01

    The title of this year's annual report has particular meaning for all of the staff at the Philadelphia Youth Network. The phrase derives from Philadelphia Youth Network's (PYN's) new vision statement, developed as part of its recent strategic planning process, which reads: All of our city's young people take their rightful places as full and…

  20. Stuck between a ROC and a hard place? Barriers to the take up of green energy in the UK

    International Nuclear Information System (INIS)

    Diaz-Rainey, Ivan; Ashton, John K.

    2008-01-01

    This paper examines the UK mechanisms for ensuring future investment in renewable energy through consumer adoption of green energy tariffs and the Renewable Obligation Certificate (ROC) system. Using a national survey and focus groups the stated willingness by UK customers to pay a premium for renewable or green energy and actual take up of such tariffs is assessed. Substantial differences between willingness to pay for and the adoption of green energy tariffs are reported. This disparity is linked to a range of factors including consumer confusion, lack of supply, complexities of constructing 'green source' tariffs under the ROC system and a lack of customer trust. It is concluded that the re-definition of the green energy market in favour of 'green source' tariffs, greater direct compliance with the Renewable Obligation by addressing supply constraints, and efforts in providing clearer information and choices for consumers via a compulsory green energy accreditation scheme are required if willing consumers' are to contribute to investment in renewable energy

  1. The Investigation of Mobbing Events Taking Place at Higher Education Institutions in Turkey Considering the Reflections on Media

    Directory of Open Access Journals (Sweden)

    Çubukçu Zühal

    2015-08-01

    considering that they are published nationally, reference newspapers and belong to different publication groups. The data used in this study was taken from the archive of the three newspapers. When the archives of the newspapers was scanned, the word “mobbing” was taken as key word for the search. In qualitative researches, newspapers are considered to be public archive and used as reference documents. The data obtained was grouped depending on the newspapers which it was taken from, on the year of publication, on where they took place, on the gender of the victims and on who the sufferers are.

  2. Sorption of 241Am onto montmorillonite, illite and hematite colloids

    International Nuclear Information System (INIS)

    Degueldre, C.; Ulrich, H.J.; Silby, H.

    1994-01-01

    Actinide sorption on colloids may be described as a competition between the formation of complexes in solution and the build up of surface complexes. The role of particle and of carbonate concentrations on the sorption/desorption of 241 Am on montmorillonite, illite and hematite colloids is investigated. Since the partition coefficient (K p ) values are virtually independent of the colloid concentrations, within the range 1 to 300 ppm, no significant aggregation takes place in the sorption/desorption experiment. At pH 8, a slight decrease of K p is observed if the concentration of total carbonate exceeds 10 -2 M. The formation of the carbonato- (and hydroxo-carbonato-) complexes in the solution competes with the formation of surface complexes on the colloids. A relationship between the sorption coefficient and the complexation of 241 Am in the solution has been found. This leads to the conclusion that, besides free americium cation, the hydroxo-, and carbonato- as well as the mixed hydroxo-carbonato-complexes are sorbed. Only when the tricarbonatocomplex [Am(CO 3 ) 3 ] 3- prevails (total carbonate concentration > 10 -2 M), a significant decrease of the distribution coefficient is observed. At pH 10 this decrease disappears because under these conditions the strong hydroxo-complexes dominate. A pragmatic and relatively simple application of surface complexation model describes the observed features. (orig.)

  3. Effect of pH on the sorption properties of bentonite Kopernica

    International Nuclear Information System (INIS)

    Galambos, M.; Paucova, V.

    2009-01-01

    In this work sorption of strontium-85 on Slovak bentonites was studied. Sorption experiments that were conducted at four different values of pH = 2, 4, 6 and 8 showed that by increasing of pH in the solution an increasing of values of percentage of sorption and of distribution relationships occur. Value approaching 99% was achieved during the sorption of strontium cations from the bentonite deposits Kopernica only at pH = 8. It can be concluded that in addition to the basic mechanism of sorption, which is ion exchange, complex-forming reactions with surface groups of bentonite take place there at higher values. The increase in value attributable to R 'hydrolytic' adsorption, because there is a reaction between Sr(OH) + and OH-groups and H + ion competition is stifled. At pH = 2 in the whole studied range of concentrations low values of sorption percent, distribution ratio and adsorbed amount of strontium were observed. It can be attributed to a significant competitive impact of hydrogen ions and disruption of the structure of bentonite.

  4. Sorption of sodium hydroxide by type I collagen and bovine corneas.

    Science.gov (United States)

    Whikehart, D R; Edwards, W C; Pfister, R R

    1991-01-01

    There are no quantitative studies on the uptake of alkali into corneal tissues. To study this phenomenon, both type I collagen and bovine corneas were incubated in sodium hydroxide (NaOH) under varying conditions for periods up to 27.5 h. The sorption (absorption or adsorption) of the alkali to protein and tissue was measured as the quantity of NaOH no longer available for titration to neutrality with hydrochloric acid. Sorption was found to be dependent on the concentration of NaOH (0.01-1 N) but independent of the incubation temperature (4-35 degrees C). In whole cornea, sorption of 1 N NaOH began immediately and increased with time up to 6 h. After 6 h, sorption decreased, together with the observed degradation and solubilization of the tissue. Stripping of the corneal endothelium alone or of the endothelium and epithelium increased sorption in a similar manner when compared to whole corneas for periods up to 4 h. These observations are compatible with ionic and nonionic bonding of hydroxide ions to collagen (including that of the cornea) and the subsequent release of hydroxide ions during hydrolysis of the protein itself. Indirect evidence also suggests the inclusion of quantities of unbound hydroxide ions in hydrated gels of glycosaminoglycans. It is proposed that in a chemical burn of the cornea, alkali is both stored in the tissue (by sorption) and reacted with it (by hydrolysis), without any net consumption of alkali taking place.

  5. Modeling of kinetics of Cr(VI) sorption onto grape stalk waste in a stirred batch reactor

    International Nuclear Information System (INIS)

    Escudero, Carlos; Fiol, Nuria; Poch, Jordi; Villaescusa, Isabel

    2009-01-01

    Recently, Cr(VI) removal by grape stalks has been postulated to follow two mechanisms, adsorption and reduction to trivalent chromium. Nevertheless, the rate at which both processes take place and the possible simultaneity of both processes has not been investigated. In this work, kinetics of Cr(VI) sorption onto grape stalk waste has been studied. Experiments were carried out at different temperatures but at a constant pH (3 ± 0.1) in a stirred batch reactor. Results showed that three steps take place in the process of Cr(VI) sorption onto grape stalk waste: Cr(VI) sorption, Cr(VI) reduction to Cr(III) and the adsorption of the formed Cr(III). Taking into account the evidences above mentioned, a model has been developed to predict Cr(VI) sorption on grape stalks on the basis of (i) irreversible reduction of Cr(VI) to Cr(III) reaction, whose reaction rate is assumed to be proportional to the Cr(VI) concentration in solution and (ii) adsorption and desorption of Cr(VI) and formed Cr(III) assuming that all the processes follow Langmuir type kinetics. The proposed model fits successfully the kinetic data obtained at different temperatures and describes the kinetics profile of total, hexavalent and trivalent chromium. The proposed model would be helpful for researchers in the field of Cr(VI) biosorption to design and predict the performance of sorption processes.

  6. Sorption of Europium in zirconium silicate; Sorcion de Europio en silicato de circonio

    Energy Technology Data Exchange (ETDEWEB)

    Garcia R, G. [ININ, Carretera Mexico-Toluca Km. 36.5, 52045 Estado de Mexico (Mexico)

    2004-07-01

    Some minerals have the property of sipping radioactive metals in solution, that it takes advantage to manufacture contention barriers that are placed in the repositories of nuclear wastes. The more recent investigations are focused in the development of new technologies guided to the sorption of alpha emissors on minerals which avoid their dispersion in the environment. In an effort to contribute to the understanding of this type of properties, some studies of sorption of Europium III are presented like homologous of the americium, on the surface of zirconium silicate (ZrSiO{sub 4}). In this work the results of sorption experiences are presented as well as the interpretation of the phenomena of the formation of species in the surface of the zirconium silicate. (Author)

  7. Test of zircon materials for sorption of europium

    International Nuclear Information System (INIS)

    Ordonez R, E.; Fernandez V, S.M.; Garcia R, G.

    2003-01-01

    In previous works it has already been made notice that some phosphates have the property of sipping radioactive metals in solution, what takes advantage to fabricate reactive barriers that are placed in the repositories of nuclear wastes. In our laboratory it has been obtained to the zirconium silicate (ZrSiO 4 ) and the alpha zirconium hydrogen phosphate (Zr(HPO 4 ) 2H 2 0) starting from sea sand in an easy and economic way. With the interest of knowing if these compounds can be used in contention barriers the evaluation of their surface properties it is made and of europium sorption. (Author)

  8. Kinetics of strontium sorption in calcium phosphate

    International Nuclear Information System (INIS)

    Bacic, S.; Komarov, V.F.; Vukovic, Z.

    1989-01-01

    Kinetics of strontium sorption by highly dispersed solids: tricalcium phosphate (Ca 3 (PO 4 ) 2 , TCP) and hydroxyapatite (Ca 5 (PO 4 ) 3 )H, HAP) were investigated. Analysis of sorption data was made taking into consideration composition and morphology of ultra micro particles. Conclusion is that the isomorphous strontium impurity is structurally sensitive element for calcium phosphate. It was determined that the beginning of strontium desorption corresponds to the beginning of transformation of the TCP - HAP (author)

  9. Studies of Dye Sensitisation Kinetics and Sorption Isotherms of Direct Red 23 on Titania

    Directory of Open Access Journals (Sweden)

    Peter J. Holliman

    2008-01-01

    Full Text Available Sorption kinetics and isotherms have been measured for a commercial dye (Direct Red 23 on different samples of powdered Titania, and the data were analysed to better understand the dye sensitization process for dye sensitised solar cells (DSSCs. For the sorption kinetics, the data show rapid initial sorption (<1 hour followed by slower rate of increasing uptake between 1 and 24 hours. While higher initial concentrations of dye correspond to higher sorption overall, less dye is absorbed from higher initial dye concentrations when considered as percentage uptake. The correlation between the sorption data and model isotherms has been considered with time. The Langmuir model shows better correlations compared to the Freundlich isotherm. The dye uptake data has also been correlated with Titania characterization data (X-ray diffraction, scanning electron microscopy, BET and zero point charge analysis. Kinetic data show significantly better fits to second-order models compared to first order. This suggests that chemisorption is taking place and that the interaction between the dye sorbate and the Titania sorbent involves electron sharing to form an ester bond.

  10. Sorption of cesium and uranium to Feldspar

    International Nuclear Information System (INIS)

    Wijland, G.C.; Pennders, R.M.J.

    1990-07-01

    Within safety assessment studies, for nuclear waste disposal in deep geologic formations, calculation for the migration of radionuclides through the geosphere are often carried out with models taking sorption into account. In the past 8 years the insight grew that other physico-chemical processes, besides sorption, could affect migration behaviour. While the currently used transport models were being improved taking either linear or non-linear sorption into account, the coupling of geochemical and transport models came into scope. In spite of these developments models which are still based on the sorption theory are frequently applied in studying migration behaviour of radionuclides. This is caused by the necessity of making preliminary pronouncements, while coupled models are still in stage of development and thermodynamic data are very limited available. Therefore one has to obtain insight in the reliability of the models based on the sorption theory. within the sorption database there is a lack of knowledge about mineralogy, composition of the fluid and the experimental conditions underlying the data. Therefore the Expert Group on geochemical Modelling supported by the Finnish proposal in order to obtain insight in the possible deviation of the sorption coefficients that can be estimated from experiments performed with standard samples, fluid composition and experimental conditions. Nine laboratories from OECD membership countries took part in this intercalibration study. In the framework of the Dutch safety assessment studies the Dutch National Institute of Public health and Environmental protection (RIVM) has decided to participate in this exercise. In this report the results are presented of sorption experiments for cesium and natural Uranium to Feldspar. (H.W.). 4 refs.; 1 fig.; 7 tabs

  11. When and Where Learning is Taking Place: Multisynaptic Changes in Strength During Different Behaviors Related to the Acquisition of an Operant Conditioning Task by Behaving Rats.

    Science.gov (United States)

    Fernández-Lamo, Iván; Delgado-García, José M; Gruart, Agnès

    2018-03-01

    Although it is generally assumed that brain circuits are modified by new experiences, the question of which changes in synaptic efficacy take place in cortical and subcortical circuits across the learning process remains unanswered. Rats were trained in the acquisition of an operant conditioning in a Skinner box provided with light beams to detect animals' approaches to lever and feeder. Behaviors such as pressing the lever, eating, exploring, and grooming were also recorded. Animals were chronically implanted with stimulating and recording electrodes in hippocampal, prefrontal, and subcortical sites relevant to the task. Field synaptic potentials were evoked during the performance of the above-mentioned behaviors and before, during, and after the acquisition process. Afferent pathways to the hippocampus and the intrinsic hippocampal circuit were slightly modified in synaptic strength during the performance of those behaviors. In contrast, afferent and efferent circuits of the medial prefrontal cortex were significantly modified in synaptic strength across training sessions, mostly at the moment of the largest change in the learning curve. Performance of behaviors nondirectly related to the acquisition process (exploring, grooming) also evoked changes in synaptic strength across training. This study helps to understand when and where learning is being engraved in the brain. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  12. Thin Places

    OpenAIRE

    Lockwood, Sandra Elizabeth

    2013-01-01

    This inquiry into the three great quests of the twentieth century–the South Pole, Mount Everest, and the Moon–examines our motivations to venture into these sublime, yet life-taking places. The Thin Place was once the destination of the religious pilgrim seeking transcendence in an extreme environment. In our age, the Thin Place quest has morphed into a challenge to evolve beyond the confines of our own physiology; through human ingenuity and invention, we reach places not meant to accommod...

  13. Geochemical modelling of the sorption of tetravalent radioelements

    International Nuclear Information System (INIS)

    Bond, K.A.; Tweed, C.J.

    1991-05-01

    The results of an experimental study of the sorption of a range of tetravalent radioelements, plutonium (IV), tin (IV), thorium(IV) and uranium(IV), onto clay at pH8 and pH11 have been successfully simulated using a triple layer sorption model. The model has been incorporated into HARPHRQ, a geochemical program based on PHREEQE. The model has been parameterised using data for sorption onto ferric oxyhydroxide and goethite. The effects of hydroxycarboxylic acids on the sorption process have also been investigated experimentally. It was generally observed that in the presence of 2x10 -3 M gluconate, sorption was reduced by up two orders of magnitude. The model has satisfactorily simulated these lower sorptivities, through assuming competing sorption and complexation reactions. This work, therefore, further confirms the need to take account of such organic materials in safety assessment modelling. (author)

  14. Sorption by cation exchange

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    1994-04-01

    A procedure for introducing exchange into geochemical/surface complexation codes is described. Beginning with selectivity coefficients, K c , defined in terms of equivalent fractional ion occupancies, a general expression for the molar based exchange code input parameters, K ex , is derived. In natural systems the uptake of nuclides onto complex sorbents often occurs by more than one mechanism. The incorporation of cation exchange and surface complexation into a geochemical code therefore enables sorption by both mechanisms to be calculated simultaneously. The code and model concepts are tested against sets of experimental data from widely different sorption studies. A proposal is made to set up a data base of selectivity coefficients. Such a data base would form part of a more general one consisting of sorption mechanism specific parameters to be used in conjunction with geochemical/sorption codes to model and predict sorption. (author) 6 figs., 6 tabs., 26 refs

  15. Sorption data bases and mechanistic sorption studies

    International Nuclear Information System (INIS)

    Bradbury, M.H.

    2000-01-01

    In common with many other countries with a nuclear programme, the Swiss concept for the disposal of radioactive waste is focused on deep burial in specially constructed repositories in geologically stable host rocks. Under such conditions, the most likely means whereby radionuclides might return to the biosphere involves their transport in slowly moving groundwater. The sorption of radionuclides by solid phases in the engineered barriers within the repository, and in the surrounding geological media, limits their release and retards their movement. Performance assessment studies for disposal concepts are carried out by Nagra, the National Cooperative for the Disposal of Radioactive Waste, in which various release scenarios are examined, and 'doses to man' calculated. The uptake of radionuclides by immobile phases is one of the pillars upon which the safety case rests. Hence, sorption databases are very important data sets for performance assessments. The methodology lying behind the construction of sorption databases, and some aspects of the supporting experimental work, are briefly described in this report. Flexible, long-term, focused research programmes are required to properly understand the radionuclide/rock/groundwater system, and this is an essential pre-requisite for producing robust state-of-the-art sorption databases. (author)

  16. Sorption data bases and mechanistic sorption studies

    Energy Technology Data Exchange (ETDEWEB)

    Bradbury, M.H

    2000-07-01

    In common with many other countries with a nuclear programme, the Swiss concept for the disposal of radioactive waste is focused on deep burial in specially constructed repositories in geologically stable host rocks. Under such conditions, the most likely means whereby radionuclides might return to the biosphere involves their transport in slowly moving groundwater. The sorption of radionuclides by solid phases in the engineered barriers within the repository, and in the surrounding geological media, limits their release and retards their movement. Performance assessment studies for disposal concepts are carried out by Nagra, the National Cooperative for the Disposal of Radioactive Waste, in which various release scenarios are examined, and 'doses to man' calculated. The uptake of radionuclides by immobile phases is one of the pillars upon which the safety case rests. Hence, sorption databases are very important data sets for performance assessments. The methodology lying behind the construction of sorption databases, and some aspects of the supporting experimental work, are briefly described in this report. Flexible, long-term, focused research programmes are required to properly understand the radionuclide/rock/groundwater system, and this is an essential pre-requisite for producing robust state-of-the-art sorption databases. (author)

  17. Sorption properties of wool

    Directory of Open Access Journals (Sweden)

    Radetić Maja M.

    2004-01-01

    Full Text Available Strict ecological legislation, especially in highly developed countries, imposed requirements for the purification of industrial effluents and the need for efficient oil clean up after sea and inland water spills. Although numerous processes have been developed, the application of sorbents is still one of the most efficient methods to remove heavy metal ions, dyes and crude oil from water. Recently, special attention was paid to sorbents based on natural fibres. A review of studies concerning the sorption properties of wool is presented in this paper. The presence of various functional groups on the wool fibre surface contributes to the efficient sorption of heavy metal ions and dyes. A hydrophobic, scaly surface and fibre crimp strongly influence the high sorption capacity of wool for oil. Wool has great sorption potential even as a recycled material. Accordingly, it can be used as a viable substitute to commercially available synthetic sorbents that show poor biodegradab ility.

  18. Effects of sorption behaviour on contaminant migration

    International Nuclear Information System (INIS)

    Melnyk, T.W.

    1985-11-01

    The effects of sorption behaviour on contaminant migration in groundwater systems are varied. Retardation of migration and dispersive effects can vary widely and contaminant concentration profiles can take a number of different shapes. This report examines the nature of some of these effects, especially those due to sorption behaviours that are dependent on the concentration of the contaminant in the groundwater. The effects are calculated using, in most cases, analytical solutions to the chemical equations imbedded in a simple reaction-cell or box-model transport algorithm. The hydrogeological parameters are held constant, and radioactive decay and hydrodynamic dispersion are excluded. A general discussion of the role of sorption equations in transport modelling is followed by presentation of migration results for a number of models of sorption behaviour varying from linear isotherms, Langmuir, Freundlich and ion-exchange isotherms, to precipitation reactions and multiple-site sorption reactions. The results are compared and general conclusions are drawn about the various migration behaviours calculated. The conclusions are that equilibrium sorption of trace contaminants can be modelled with linear isotherms (constant distribution coefficients or constant retardation factors) but the evaluation and extrapolation of the distribution coefficient are not easy. Nonlinear isotherms lead to unsymmetrical migration fronts. A comparison of Freundlich and linear isotherms is made. Sorption/desorption kinetic factors can be significant on the time scale of laboratory experiments and can cause large dispersive effects. Slow but important reactions can be missed altogether. Precipitation or mineralization behaviour cannot be modelled with constant distribution coefficients. Also, mineralization reactions can be kinetically slow even on the geological time scale. 89 refs

  19. Metal sorption on kaolinite

    International Nuclear Information System (INIS)

    Westrich, H.R.; Brady, P.V.; Cygan, R.T.; Nagy, K.L.; Anderson, H.L.

    1997-01-01

    A key issue in performance assessment of low-level radioactive waste sites is predicting the transport and retardation of radionuclides through local soils under a variety of hydrologic and geochemical conditions. Improved transport codes should include a mechanistic model of radionuclide retardation. The authors have been investigating metal sorption (Cs + , Sr 2+ , and Ba 2+ ) on a simple clay mineral (kaolinite) to better understand the geochemical interactions of common soil minerals with contaminated groundwaters. These studies include detailed characterizations of kaolinite surfaces, experimental adsorption measurements, surface complexation modeling, and theoretical simulations of cation sorption. The aluminol edge (010) site has been identified as the most likely site for metal sorption on kaolinite in natural solutions. Relative metal binding strengths decrease from Ba 2+ to Sr 2+ to Cs + , with some portion sorbed on both kaolinite edges and basal surfaces. Some Cs + also appears to be irreversibly sorbed on both sites. Molecular dynamics simulations suggest that Cs + is sorbed at aluminol (010) edge sites as an inner-sphere complex and weakly sorbed as an outer-sphere complex on (001) basal surfaces. These results provide the basis to understand and predict metal sorption onto kaolinite, and a framework to characterize sorption processes on more complex clay minerals

  20. Effect of health-promoting posters placed on the platforms of two train stations in Copenhagen, Denmark, on the choice between taking the stairs or the escalators

    DEFF Research Database (Denmark)

    Iversen, Mette Kathrine; Händel, M N; Nydal Jensen, Eva

    2007-01-01

    OBJECTIVE: The purpose of this study was to determine whether posters placed on the platforms of two train stations in Copenhagen, promoting use of the stairs, would encourage people to use the stairs rather than the adjacent escalator. An additional purpose was to see if the effect of the interv......OBJECTIVE: The purpose of this study was to determine whether posters placed on the platforms of two train stations in Copenhagen, promoting use of the stairs, would encourage people to use the stairs rather than the adjacent escalator. An additional purpose was to see if the effect...... of the intervention was maintained for a week after the poster was removed. MEASUREMENTS: The number of people using stairs and escalators at Copenhagen Central Station and Østerport Train Station in Copenhagen was recorded before and during posters promoting stair use were placed on the platforms, and a week after...... the posters were removed. Two years after the posters were removed, data were collected for 1 week at Østerport Train Station (long-term post-intervention). RESULTS: At Copenhagen Central Station, the overall stair use increased from 12% before the intervention to 16% (P

  1. Modeling of Cd(II) sorption on mixed oxide

    International Nuclear Information System (INIS)

    Waseem, M.; Mustafa, S.; Naeem, A.; Shah, K.H.; Hussain, S.Y.; Safdar, M.

    2011-01-01

    Mixed oxide of iron and silicon (0.75 M Fe(OH)3:0.25 M SiO/sub 2/) was synthesized and characterized by various techniques like surface area analysis, point of zero charge (PZC), energy dispersive X-rays (EDX) spectroscopy, Thermogravimetric and differential thermal analysis (TG-DTA), Fourier transform infrared spectroscopy (FTIR) and X-rays diffraction (XRD) analysis. The uptake of Cd/sup 2+/ ions on mixed oxide increased with pH, temperature and metal ion concentration. Sorption data have been interpreted in terms of both Langmuir and Freundlich models. The Xm values at pH 7 are found to be almost twice as compared to pH 5. The values of both DH and DS were found to be positive indicating that the sorption process was endothermic and accompanied by the dehydration of Cd/sup 2+/. Further, the negative value of DG confirms the spontaneity of the reaction. The ion exchange mechanism was suggested to take place for each Cd/sup 2+/ ions at pH 5, whereas ion exchange was found coupled with non specific adsorption of metal cations at pH 7. (author)

  2. Kinetics and reversibility of micropollutant sorption in sludge.

    Science.gov (United States)

    Barret, Maialen; Carrère, Hélène; Patau, Mathieu; Patureau, Dominique

    2011-10-01

    The fate of micropollutants throughout wastewater treatment systems is highly dependent on their sorption interactions with sludge matter. In this study, both the sorption and desorption kinetics of polycyclic aromatic hydrocarbons (PAHs) in activated sludge were shown to be very rapid in comparison to biodegradation kinetics. It was concluded that PAH transfer does not limit their biodegradation and that their fate is governed by the sorption/desorption equilibrium state. The effect of contact time between sludge and PAHs was also investigated. It was shown that aging did not influence the sorption/desorption equilibrium although PAH losses during aging suggest that sequestration phenomena had occurred. This implies that for PAH sorption assessment within treatment processes there is no need to include a contact time dimension. As a consequence, thanks to an innovative approach taking into account sorption equilibria and sequestration, this work has demonstrated that studies in the literature which, in main, deal with micropollutant sorption in sewage sludge with only a short contact time can be extrapolated to real systems in which sorption, desorption and aging occur.

  3. Test of zircon materials for sorption of europium; Pruebas de materiales circoniferos para sorcion de europio

    Energy Technology Data Exchange (ETDEWEB)

    Ordonez R, E.; Fernandez V, S.M.; Garcia R, G. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2003-07-01

    In previous works it has already been made notice that some phosphates have the property of sipping radioactive metals in solution, what takes advantage to fabricate reactive barriers that are placed in the repositories of nuclear wastes. In our laboratory it has been obtained to the zirconium silicate (ZrSiO{sub 4}) and the alpha zirconium hydrogen phosphate (Zr(HPO{sub 4}) 2H{sub 2}0) starting from sea sand in an easy and economic way. With the interest of knowing if these compounds can be used in contention barriers the evaluation of their surface properties it is made and of europium sorption. (Author)

  4. Sorption of europium (3) by polymer sorbents with grafted heterocyclic nitrogen-containing groupings

    International Nuclear Information System (INIS)

    Bel'tyukova, S.V.; Kravchenko, T.B.; Balamtsarashvili, G.M.; Roska, A.S.

    1990-01-01

    On polymer sorbents (copolymer of styrene-divinylbenzene) with grafted heterocyclic nitrogen-containing functional groupings of tetrazole, triazole and imidazole (sorbents 1,2,3, respectively). It is stated that europium sorption takes place from neutral solutions in presence of organic solvents. Luminescent properties of europium on sorbent are used to develope methods of its determination in high purity lanthanide and yttrium oxides. Europium determination limits consist 7.5·10 -5 μg/ml on 1 and 3 sorbents and 1.5·10 -4 μg/ml on sorbent 2, S p value is 0.089 and 0.075, respectivaly

  5. NS [Nuclear Safety] update. Current safety and security activities and developments taking place in the Department of Nuclear Safety and Security, Issue no. 6, March 2008

    International Nuclear Information System (INIS)

    2008-03-01

    The current issue presents information about the following activities: 1) International Conference on Illicit Nuclear Trafficking which took place in November 2007 in Edinburgh. The principal aim of the conference was to examine the threat and context of illicit nuclear trafficking of radioactive material, specifically, what is being done to combat such trafficking and where more needs to be done. The conference was also to consider how the obligations and commitments of the legally binding and non-binding international instruments could be and are being implemented by various States. 2) INSAG Message on Nuclear Safety Infrastructure in which the INSAG Chairman Richard Meserve addressed nuclear safety in the current context and various issues that warrant special attention. 3) approved for publication the Safety Requirements publication on Safety of Nuclear Fuel Cycle Facilities. 4) The Asian Nuclear Safety Network (ANSN)

  6. NS [Nuclear Safety] update. Current safety and security activities and developments taking place in the Department of Nuclear Safety and Security, Issue no. 8, September 2008

    International Nuclear Information System (INIS)

    2008-09-01

    The current issue presents information about the following activities: 1) International Workshops on Denial of Shipments raise awareness of suppliers, recipients, regulators, carriers/consignors and international organizations of the problems relating to denials of radioactive shipments to determine effective measures to prevent or reduce the instances of shipment denials and delays. 2) Communication and knowledge Management in the Department of Nuclear Safety and Security (NS). 3) Nuclear Security at the Beijing Olympics - an excellent example of the IAEA's work in protecting large scale public events. 4) The Incident and Emergency Centre's Participation in the ConvEx 3 Exercise, 9-10 July 2008, which took place at the Laguna Verde nuclear power plant in Mexico. During the 43 hour long exercise, the Incident and Emergency Centre (IEC) was fully activated. Staff members participating in the exercise represented different departments within the IAEA and the diversity of their knowledge and experience ensured an effective response

  7. NS [Nuclear Safety] update. Current safety and security activities and developments taking place in the Department of Nuclear Safety and Security. Issue no. 2, January 2007

    International Nuclear Information System (INIS)

    2006-08-01

    This newsletter reports on the training of cardiologists in radiation protection, IAEA's safety review services and the operational safety assessment review team (OSART), the international conference on management of spent fuel and the recent INSAG (International Nuclear Safety Group) publications. The IAEA has begun a major international initiative to train interventional cardiologists in radiation protection. Starting with the first course in May 2004, so far 6 regional and 3 national training courses have been conducted with the participation of over 400 health professionals putting the IAEA in a leading role in this area. A programme of two days' training has been developed, covering possible and observed radiation effects among patients and staff, international standards, dose management techniques, examples of good and bad practice and examples indicating prevention of possible injuries as a result of good practice in radiation protection. The training material is freely available on CD and will be placed on the Radiological Protection of Patients website at http://rpop.iaea.org/

  8. Place-focused physical activity research, human agency, and social justice in public health: taking agency seriously in studies of the built environment.

    Science.gov (United States)

    Blacksher, Erika; Lovasi, Gina S

    2012-03-01

    Built environment characteristics have been linked to health outcomes and health disparities. However, the effects of an environment on behavior may depend on human perception, interpretation, motivation, and other forms of human agency. We draw on epidemiological and ethical concepts to articulate a critique of research on the built environment and physical activity. We identify problematic assumptions and enumerate both scientific and ethical reasons to incorporate subjective perspectives and public engagement strategies into built environment research and interventions. We maintain that taking agency seriously is essential to the pursuit of health equity and the broader demands of social justice in public health, an important consideration as studies of the built environment and physical activity increasingly focus on socially disadvantaged communities. Attention to how people understand their environment and navigate competing demands can improve the scientific value of ongoing efforts to promote active living and health, while also better fulfilling our ethical obligations to the individuals and communities whose health we strive to protect. Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Leaf processing behaviour in Atta leafcutter ants: 90% of leaf cutting takes place inside the nest, and ants select pieces that require less cutting.

    Science.gov (United States)

    Garrett, Ryan W; Carlson, Katherine A; Goggans, Matthew Scott; Nesson, Michael H; Shepard, Christopher A; Schofield, Robert M S

    2016-01-01

    Leafcutter ants cut trimmings from plants, carry them to their underground nests and cut them into smaller pieces before inoculating them with a fungus that serves as a primary food source for the colony. Cutting is energetically costly, so the amount of cutting is important in understanding foraging energetics. Estimates of the cutting density, metres of cutting per square metre of leaf, were made from samples of transported leaf cuttings and of fungal substrate from field colonies of Atta cephalotes and Atta colombica. To investigate cutting inside the nest, we made leaf-processing observations of our laboratory colony, A. cephalotes. We did not observe the commonly reported reduction of the leaf fragments into a pulp, which would greatly increase the energy cost of processing. Video clips of processing behaviours, including behaviours that have not previously been described, are linked. An estimated 2.9 (±0.3) km of cutting with mandibles was required to reduce a square metre of leaf to fungal substrate. Only about 12% (±1%) of this cutting took place outside of the nest. The cutting density and energy cost is lower for leaf material with higher ratios of perimeter to area, so we tested for, and found that the laboratory ants had a preference for leaves that were pre-cut into smaller pieces. Estimates suggest that the energy required to transport and cut up the leaf material is comparable to the metabolic energy available from the fungus grown on the leaves, and so conservation of energy is likely to be a particularly strong selective pressure for leafcutter ants.

  10. Hypoxia and inactivity related physiological changes precede or take place in absence of significant rearrangements in bacterial community structure: The PlanHab randomized trial pilot study.

    Directory of Open Access Journals (Sweden)

    Robert Šket

    Full Text Available We explored the assembly of intestinal microbiota in healthy male participants during the randomized crossover design of run-in (5 day and experimental phases (21-day normoxic bed rest (NBR, hypoxic bed rest (HBR and hypoxic ambulation (HAmb in a strictly controlled laboratory environment, with balanced fluid and dietary intakes, controlled circadian rhythm, microbial ambiental burden and 24/7 medical surveillance. The fraction of inspired O2 (FiO2 and partial pressure of inspired O2 (PiO2 were 0.209 and 133.1 ± 0.3 mmHg for NBR and 0.141 ± 0.004 and 90.0 ± 0.4 mmHg for both hypoxic variants (HBR and HAmb; ~4000 m simulated altitude, respectively. A number of parameters linked to intestinal environment such as defecation frequency, intestinal electrical conductivity (IEC, sterol and polyphenol content and diversity, indole, aromaticity and spectral characteristics of dissolved organic matter (DOM were measured (64 variables. The structure and diversity of bacterial microbial community was assessed using 16S rRNA amplicon sequencing. Inactivity negatively affected frequency of defecation and in combination with hypoxia increased IEC (p < 0.05. In contrast, sterol and polyphenol diversity and content, various characteristics of DOM and aromatic compounds, the structure and diversity of bacterial microbial community were not significantly affected over time. A new in-house PlanHab database was established to integrate all measured variables on host physiology, diet, experiment, immune and metabolic markers (n = 231. The observed progressive decrease in defecation frequency and concomitant increase in IEC suggested that the transition from healthy physiological state towards the developed symptoms of low magnitude obesity-related syndromes was dose dependent on the extent of time spent in inactivity and preceded or took place in absence of significant rearrangements in bacterial microbial community. Species B. thetaiotamicron, B. fragilis, B

  11. Designated Places

    Data.gov (United States)

    California Natural Resource Agency — Census 2000 Place Names provides a seamless statewide GIS layer of places, including census designated places (CDP), consolidated cities, and incorporated places,...

  12. Technetium Sorption Media Review

    International Nuclear Information System (INIS)

    Duncan, J.B.; Kelly, S.E.; Robbins, R.A.; Adams, R.D.; Thorson, M.A.; Haass, C.C.

    2011-01-01

    This report presents information and references to aid in the selection of 99Tc sorption media for feasibility studies regarding the removal of 99Tc from Hanford's low activity waste. The report contains literature search material for sorption media (including ion exchange media) for the most tested media to date, including SuperLig 639, Reillex HPQ, TAM (Kruion), Purolite A520E and A530E, and Dowex 1X8. The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities in a safe, environmentally compliant, cost-effective and energy-effective manner.

  13. TECHNETIUM SORPTION MEDIA REVIEW

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN JB; KELLY SE; ROBBINS RA; ADAMS RD; THORSON MA; HAASS CC

    2011-08-25

    This report presents information and references to aid in the selection of 99Tc sorption media for feasibility studies regarding the removal of 99Tc from Hanford's low activity waste. The report contains literature search material for sorption media (including ion exchange media) for the most tested media to date, including SuperLig 639, Reillex HPQ, TAM (Kruion), Purolite A520E and A530E, and Dowex 1X8. The U.S. Department of Energy (DOE), Office of River Protection (ORP) is responsible for management and completion of the River Protection Project (RPP) mission, which comprises both the Hanford Site tank farms and the Waste Treatment and Immobilization Plant (WTP). The RPP mission is to store, retrieve and treat Hanford's tank waste; store and dispose of treated wastes; and close the tank farm waste management areas and treatment facilities in a safe, environmentally compliant, cost-effective and energy-effective manner.

  14. Spectroscopic investigations on sorption of uranium onto suspended bentonite. Effects of pH, ionic strength and complexing anions

    Energy Technology Data Exchange (ETDEWEB)

    Verma, Parveen Kumar; Pathak, Priyanath; Mohapatra, Manoj; Mohapatra, Prasanta Kumar [Bhabha Atomic Research Centre, Mumbai (India). Radiochemistry Div.; Yadav, Ashok Kumar; Jha, Sambhunath; Bhattacharyya, Dibyendu [Bhabha Atomic Research Centre, Mumbai (India). Atomic and Molecular Physics Div.

    2015-06-01

    } edge. There was shift in the absorbance edge which was attributed to decrease in electron density at U(VI) due to surface or ligand complexation. The R space spectra are mainly dominated by the back-scattering from the axial oxygens in the first shell. The inner-sphere multinuclear complex formation takes place during the U(VI) sorption onto bentonite.

  15. Parametric study of the sorption of Cs(I) and Sr(II) on mixture of bentonite and magnetite using SCM + IEXM

    International Nuclear Information System (INIS)

    Filipska, H.; Stamberg, K.

    2005-01-01

    of sorption, K(Cs/Sr), on total KD, % of sorption for Cs and Sr and for their individual species, etc. The individual quantities were related to the mass of bentonite and/or magnetite or to the type of functional group mentioned (edge and/or layer sites). From the results it is evident that the sorption selectivity depends not only on pH and type of sorbent, but also on the type of functional group; e.g., in the pH interval studied (4-9), the sorption of Cs is more selective than sorption of Sr on layer sites, on edge sites it is vice versa. On the whole, the sorption reactions of Cs(I) and Sr(II) taking place on layer sites play the most important role in the sorption process. (authors)

  16. Sorption of actinides onto nanodiamonds

    Energy Technology Data Exchange (ETDEWEB)

    Buchatskaya, Yulia; Romanchuk, Anna; Yakovlev, Ruslan; Kulakova, Inna [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry; Shiryaev, Andrei [Russian Academy of Sciences, Moscow (Russian Federation). Frumkin Institute of Physical Chemistry and Electrochemistry; Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry; Kalmykov, Stepan [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry; Russian Academy of Sciences, Moscow (Russian Federation). Frumkin Institute of Physical Chemistry and Electrochemistry; Russian Academy of Sciences, Moscow (Russian Federation). Vernadsky Institute of Geochemistry and Analytical Chemistry

    2015-06-01

    Detonation nanodiamonds (ND) present a significant part of nanocarbons group, which could be produced on commercial scale by detonation of explosives in a closed chamber. Their unique properties of high surface area, low weight and radiation resistance make ND a prospective candidate for applications in sorption processes in radiochemistry. To study the influence of surface chemistry on sorption properties, apristine sample of ND was treated with acids and hydrogen. The surface chemistry of the samples was characterised by infrared spectroscopy, X-ray photoelectron spectroscopy and Boehm titration. The sorption properties of ND were tested fordifferent radionuclides. The sorption capacity of ND was shown to be higher than those of commonly used radionuclide sorbents like activated carbon and compariable to other members of nanocarbon group like graphene oxide and carbon nanotubes. The sorption properties were shown to be influenced by the presence of oxygen-containing groups on the surface of ND. This represents an opportunity to increase the sorption capacity of ND.

  17. Sorption of actinides onto nanodiamonds

    International Nuclear Information System (INIS)

    Buchatskaya, Yulia; Romanchuk, Anna; Yakovlev, Ruslan; Kulakova, Inna; Shiryaev, Andrei; Russian Academy of Sciences, Moscow; Kalmykov, Stepan; Russian Academy of Sciences, Moscow; Russian Academy of Sciences, Moscow

    2015-01-01

    Detonation nanodiamonds (ND) present a significant part of nanocarbons group, which could be produced on commercial scale by detonation of explosives in a closed chamber. Their unique properties of high surface area, low weight and radiation resistance make ND a prospective candidate for applications in sorption processes in radiochemistry. To study the influence of surface chemistry on sorption properties, apristine sample of ND was treated with acids and hydrogen. The surface chemistry of the samples was characterised by infrared spectroscopy, X-ray photoelectron spectroscopy and Boehm titration. The sorption properties of ND were tested fordifferent radionuclides. The sorption capacity of ND was shown to be higher than those of commonly used radionuclide sorbents like activated carbon and compariable to other members of nanocarbon group like graphene oxide and carbon nanotubes. The sorption properties were shown to be influenced by the presence of oxygen-containing groups on the surface of ND. This represents an opportunity to increase the sorption capacity of ND.

  18. Sorption analyses in materials science: selected oxides

    International Nuclear Information System (INIS)

    Fuller, E.L. Jr.; Condon, J.B.; Eager, M.H.; Jones, L.L.

    1981-01-01

    Physical adsorption studies have been shown to be extremely valuable in studying the chemistry and structure of dispersed materials. Many processes rely on the access to the large amount of surface made available by the high degree of dispersion. Conversely, there are many applications where consolidation of the dispersed solids is required. Several systems (silica gel, alumina catalysts, mineralogic alumino-silicates, and yttrium oxide plasters) have been studied to show the type and amount of chemical and structural information that can be obtained. Some review of current theories is given and additional concepts are developed based on statistical and thermodynamic arguments. The results are applied to sorption data to show that detailed sorption analyses are extremely useful and can provide valuable information that is difficult to obtain by any other means. Considerable emphasis has been placed on data analyses and interpretation of a nonclassical nature to show the potential of such studies that is often not recognized nor utilized

  19. Positron Spectroscopy of Nanodiamonds after Hydrogen Sorption

    Directory of Open Access Journals (Sweden)

    Lyudmila Nikitina

    2018-01-01

    Full Text Available The structure and defects of nanodiamonds influence the hydrogen sorption capacity. Positronium can be used as a sensor for detecting places with the most efficient capture of hydrogen atoms. Hydrogenation of carbon materials was performed from gas atmosphere. The concentration of hydrogen absorbed by the sample depends on the temperature and pressure. The concentration 1.2 wt % is achieved at the temperature of 243 K and the pressure of 0.6 MPa. The hydrogen saturation of nanodiamonds changes the positron lifetime. Increase of sorption cycle numbers effects the positron lifetime, as well as the parameters of the Doppler broadening of annihilation line. The electron-positron annihilation being a sensitive method, it allows detecting the electron density fluctuation of the carbon material after hydrogen saturation.

  20. Major growth in coke production takes place

    International Nuclear Information System (INIS)

    Swain, E.J.

    1991-01-01

    U.S. petroleum coke production has increased 64% during the 10-year period from 1980 to 1990. This dramatic rise makes it timely to discuss the history and future of U.S. coking capacity, production, and processing. The article covers the properties and uses of the various grades of petroleum coke, as well as pricing and market trends

  1. Geochemistry of REE in Acid Mine Drainage: Sorption onto Basaluminite and Schwertmannite.

    Science.gov (United States)

    Lozano Letellier, A.; Ayora, C.; Fernandez-Martinez, A.

    2017-12-01

    The geochemistry of Rare Earth Elements (REE) has been investigated in natural streams and in mine areas during the last decades. Most of these studies agree that REE are mobile in acidic waters and they transferred to a solid phase when pH increases. However, there is no agreement on the pH range, on which precipitates can retain REE and the mechanisms responsible for the retention. Thus, whereas some authors determined that hydrous ferric oxides (HFOs) scavenge REE from pH 3, other authors observed REE retention by hydrous aluminum oxides (HAOs) from pH 4 to 6.1. A field survey conducted in the Odiel River in the SW Spain showed that pH values higher than 5, REE, Cu, Al and Fe concentrations in the river were lower than expected from a theoretical mixture because they were trapped in the precipitates. For pH below 4, however, only schwertmannite (Fe8O8OH6SO4) and no basaluminite (Al4SO4OH10·5H2O) precipitated. Then, REE, Cu and Al behaved conservatively and Fe does not, indicating that REE are trapped in the Al but not in the Fe solid phase. These observations are perfectly consistent with the REE accumulation in the Al-rich precipitates in the AMD treatment systems. Taking into account these observations, sorption experiments with synthetic basaluminite and schwertmannite at different pH were performed in the laboratory. For Lanthanides and Yttrium, sorption edge took place at pH higher than 5, whereas Sc sorption started at pH 4. A surface complexation model is proposed to explain the retention mechanism onto these two precipitates. Both minerals, schwertmannite and basaluminite showed similar sorption behavior. However, as schwertmannite formation occurs at pH lower than 4, no REE elements are sorbed on it.

  2. Lead sorption-desorption from organic residues.

    Science.gov (United States)

    Duarte Zaragoza, Victor M; Carrillo, Rogelio; Gutierrez Castorena, Carmen M

    2011-01-01

    Sorption and desorption are mechanisms involved in the reduction of metal mobility and bioavailability in organic materials. Metal release from substrates is controlled by desorption. The capacity of coffee husk and pulp residues, vermicompost and cow manure to adsorb Pb2+ was evaluated. The mechanisms involved in the sorption process were also studied. Organic materials retained high concentrations of lead (up to 36,000 mg L(-1)); however, the mechanisms of sorption varied according to the characteristics of each material: degree of decomposition, pH, cation exchange capacity and percentage of organic matter. Vermicompost and manure removed 98% of the Pb from solution. Lead precipitated in manure and vermicompost, forming lead oxide (PbO) and lead ferrite (PbFe4O7). Adsorption isotherms did not fit to the typical Freundlich and Langmuir equations. Not only specific and non-specific adsorption was observed, but also precipitation and coprecipitation. Lead desorption from vermicompost and cow manure was less than 2%. For remediation of Pb-polluted sites, the application of vermicompost and manure is recommended in places with alkaline soils because Pb precipitation can be induced, whereas coffee pulp residue is recommended for acidic soils where Pb is adsorbed.

  3. Sorption properties of carbon nanostructures

    International Nuclear Information System (INIS)

    Eletskii, Aleksandr V

    2004-01-01

    The current status of research in sorption properties of carbon nanotubes (CNTs) is reviewed. The structural peculiarities of CNTs, determining their sorption characteristics, are considered. The mechanisms of sorption of gaseous and condensed substances by such structures are analyzed. Special attention is paid to the problem of using CNTs for storing hydrogen and other gaseous substances. Methods for filling CNTs with liquid materials, based on capillary phenomena and wetting the graphite surface of the CNT with liquids of various nature, are considered. Properties of 'peapods' formed as a result of filling single-walled CNTs with fullerene molecules are reviewed. Also considered are perspectives on the applied usage of the sorption properties of CNTs in electrochemical and fuel cells, and material storage devices, as well as for producing superminiature metallic conductors. (reviews of topical problems)

  4. Autoradiographic studies of actinide sorption in groundwater systems

    International Nuclear Information System (INIS)

    O'Kelley, G.D.; Beall, G.W.; Allard, B.

    1980-01-01

    Autoradiography is a convenient and sensitive technique for the study of spacial distributions of alpha radioactive nuclides on slabs of rock or on other planar surfaces. The autoradiographic camera contains an arrangement for placing in firm contact Polaroid sheet film, a plastic scintillator screen, and the radioactive face of the specimen. As an example of the use of the autoradiographic method, a series of sorption experiments were carried out in which synthetic groundwater solutions of americium, neptunium, uranium, and plutonium were contacted with Climax Stock granite under aerated and anoxic conditions at pH 8 to 9. The sorption observed at specific mineral sites was correlated with data on sorption of these actinides on pure minerals

  5. Gamma-induced radiation polymerization of kaolin composite for sorption of lanthanum, europium and uranium ions from low-grade monazite leachate

    International Nuclear Information System (INIS)

    Metwally, S.S.; Hassan, R.S.; El-Masry, E.H.; Borai, E.H.

    2018-01-01

    Gamma radiation polymerization method was used for the modification of kaolin to produce (poly acrylamide-acrylic acid)-Kaolin (PAM-AA-K). Monazite ore is one of the main resources of uranium and lanthanide elements, therefore, this work focused on sorption of uranium, lanthanum and europium ions from low grade monazite leachate. The removal percent for Eu 3+ , La 3+ and UO 2 2+ are 94.6, 91.6 and 73.4%, respectively. Monolayer capacity of Eu 3+ , La 3+ and UO 2 2+ were found to be 54.64, 45.87 and 37.59 mg/g, respectively. The sorption mechanism of lanthanum and europium ions on PAM-AA-K composite mainly takes place as Ln(OH) 2+ , and for uranium as uranyl ion, UO 2 2+ . (author)

  6. Connecting people to place

    NARCIS (Netherlands)

    Horlings, L.G.

    2016-01-01

    The article describes a process of preparing a research design on place-shaping, as outcome of a process of co-design between academic actors and non-academic actors in Brazil, South Africa and The Netherlands, taking place in the context of the project TRANSPLACE. The joint research design

  7. Children's Places

    DEFF Research Database (Denmark)

    Using a cross-cultural approach the book investigates children's places in different societies. "Children's Places" examines the ways in which children and adults, from their different vantage-points in society, negotiate proper places of children in both social and spatial terms. It looks at some...

  8. Women take the island: nation, profession, place Women take the island: nation, profession, place

    Directory of Open Access Journals (Sweden)

    Ruth Morse

    2008-04-01

    Full Text Available The Tempest has been one of Shakespeare’s most adapted plays. Its stage history is concomitantly a history of the British theatre, from regularized comedy to semi-opera to pantomime to opera. It has had other lives, too, from its position in romantic ideas of Shakespeare’s biography and his so-called farewell to the stage, to a supporting role as witness for the nineteenth-century Darwinians’ idea of the missing link, to a veritable efflorescence of walk-on parts, cameos, and star vehicles in twentieth-century psychoanalytic and social arguments about European expansion.2 The play has given us individual poems and paintings, not to speak of screen-plays for several film adaptations. The Tempest has been one of Shakespeare’s most adapted plays. Its stage history is concomitantly a history of the British theatre, from regularized comedy to semi-opera to pantomime to opera. It has had other lives, too, from its position in romantic ideas of Shakespeare’s biography and his so-called farewell to the stage, to a supporting role as witness for the nineteenth-century Darwinians’ idea of the missing link, to a veritable efflorescence of walk-on parts, cameos, and star vehicles in twentieth-century psychoanalytic and social arguments about European expansion.2 The play has given us individual poems and paintings, not to speak of screen-plays for several film adaptations.

  9. Dispersion, sorption and photodegradation of petroleum hydrocarbons in dispersant-seawater-sediment systems.

    Science.gov (United States)

    Zhao, Xiao; Liu, Wen; Fu, Jie; Cai, Zhengqing; O'Reilly, S E; Zhao, Dongye

    2016-08-15

    This work examined effects of model oil dispersants on dispersion, sorption and photodegradation of petroleum hydrocarbons in simulated marine systems. Three dispersants (Corexit 9500A, Corexit 9527A and SPC 1000) were used to prepare dispersed water accommodated oil (DWAO). While higher doses of dispersants dispersed more n-alkanes and PAHs, Corexit 9500A preferentially dispersed C11-C20 n-alkanes, whereas Corexit 9527A was more favorable for smaller alkanes (C10-C16), and SPC 1000 for C12-C28 n-alkanes. Sorption of petroleum hydrocarbons on sediment was proportional to TPH types/fractions in the DWAOs. Addition of 18mg/L of Corexit 9500A increased sediment uptake of 2-3 ring PAHs, while higher dispersant doses reduced the uptake, due to micelle-enhanced solubilization effects. Both dispersed n-alkanes and PAHs were susceptible to photodegradation under simulated sunlight. For PAHs, both photodegradation and photo-facilitated alkylation were concurrently taking place. The information can facilitate sounder assessment of fate and distribution of dispersed oil hydrocarbons in marine systems. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Evaluation of sorption distribution coefficient of Cs onto granite using sorption data collected in sorption database and sorption model

    International Nuclear Information System (INIS)

    Nagasaki, S.

    2013-01-01

    Based on the sorption distribution coefficients (K d ) of Cs onto granite collected from the JAERI Sorption Database (SDB), the parameters for a two-site model without the triple-layer structure were optimized. Comparing the experimentally measured K d values of Cs onto Mizunami granite carried out by JAEA with the K d values predicted by the model, the effect of the ionic strength on the K d values of Cs onto granite was evaluated. It was found that K d values could be determined using the content of biotite in granite at a sodium concentration ([Na]) of 1 x 10 -2 to 5 x 10 -1 mol/dm 3 . It was suggested that in high ionic strength solutions, the sorption of Cs onto other minerals such as microcline should also be taken into account. (author)

  11. Evaluation of sorption distribution coefficient of Cs onto granite using sorption data collected in sorption database and sorption model

    Energy Technology Data Exchange (ETDEWEB)

    Nagasaki, S., E-mail: nagasas@mcmaster.ca [McMaster Univ., Hamilton, Ontario (Canada)

    2013-07-01

    Based on the sorption distribution coefficients (K{sub d}) of Cs onto granite collected from the JAERI Sorption Database (SDB), the parameters for a two-site model without the triple-layer structure were optimized. Comparing the experimentally measured K{sub d} values of Cs onto Mizunami granite carried out by JAEA with the K{sub d} values predicted by the model, the effect of the ionic strength on the K{sub d} values of Cs onto granite was evaluated. It was found that K{sub d} values could be determined using the content of biotite in granite at a sodium concentration ([Na]) of 1 x 10{sup -2} to 5 x 10{sup -1} mol/dm{sup 3} . It was suggested that in high ionic strength solutions, the sorption of Cs onto other minerals such as microcline should also be taken into account. (author)

  12. Place Branding

    DEFF Research Database (Denmark)

    Medway, Dominic; Swanson, Kathryn; Neirotti, Lisa Delpy

    2015-01-01

    Purpose: – The purpose of this paper is to report on a special session entitled “Place branding: Are we wasting our time?”, held at the American Marketing Association’s Summer Marketing Educators’ conference in 2014. Design/methodology/approach: – The report details the outcome of an Oxford......: – The outcome of the debate points towards a need for place brands to develop as more inclusive and organic entities, in which case it may be best for place practitioners to avoid creating and imposing a place brand and instead help shape it from the views of stakeholder constituencies. This shifts the notion...... of place branding towards an activity centred on “curation”. Originality/value: – The use of a competitive debating format as a means for exploring academic ideas and concepts in the place management field....

  13. Experimental and Theoretical Studies on Alkaline Degradation of Cellulose and its Impact on the Sorption of Radionuclides

    Energy Technology Data Exchange (ETDEWEB)

    Loon, L.R. van; Glaus, M A

    1998-08-01

    For more than ten years, cellulose degradation has been regarded as an important process which can adversely effect the sorption of radionuclides on cement in a radioactive waste repository. However, so far, it was not possible to quantify this effect. This study reports new experimental data on alkaline degradation of cellulose, together with a re-evaluation of old literature data. For the first time now, it becomes possible to quantitatively estimate the potential role of cellulose degradation in performance assessment studies. In the first part of this study, a literature overview of other studies on alkaline degradation of cellulose is given, together with a general discussion on the effect of organic ligands on the sorption of radionuclides. Further, an overview of the important mechanisms of alkaline degradation of cellulose and some kinetic aspects of the main reactions taking place is presented. The relevance of the processes for performance assessment is explained in detail. The discussion forms the starting-point for a detailed experimental program for evaluating the role of alkaline degradation of cellulose in performance assessment. In the second part, experimental studies on alkaline degradation are presented. Different cellulosic materials were degraded in an artificial cement pore water, representing the first stage of cement degradation. The most important degradation products ({alpha}- and {beta}-isosaccharinic acid) were characterised and the results compared with other studies. Kinetic parameters for the main reactions were measured and discussed. A good agreement was found between the measured values and values extrapolated from the literature. The solubility of the sparingly soluble Ca-salt of {alpha}-isosaccharinic acid (ISA) was studied as well as the interaction of ISA with cement. Sorption of ISA on cement can keep the ISA concentration in the pore water of a repository at a low level. The effect of pure ISA and degradation products on the

  14. Experimental and Theoretical Studies on Alkaline Degradation of Cellulose and its Impact on the Sorption of Radionuclides

    International Nuclear Information System (INIS)

    Loon, L.R. van; Glaus, M.A.

    1998-08-01

    For more than ten years, cellulose degradation has been regarded as an important process which can adversely effect the sorption of radionuclides on cement in a radioactive waste repository. However, so far, it was not possible to quantify this effect. This study reports new experimental data on alkaline degradation of cellulose, together with a re-evaluation of old literature data. For the first time now, it becomes possible to quantitatively estimate the potential role of cellulose degradation in performance assessment studies. In the first part of this study, a literature overview of other studies on alkaline degradation of cellulose is given, together with a general discussion on the effect of organic ligands on the sorption of radionuclides. Further, an overview of the important mechanisms of alkaline degradation of cellulose and some kinetic aspects of the main reactions taking place is presented. The relevance of the processes for performance assessment is explained in detail. The discussion forms the starting-point for a detailed experimental program for evaluating the role of alkaline degradation of cellulose in performance assessment. In the second part, experimental studies on alkaline degradation are presented. Different cellulosic materials were degraded in an artificial cement pore water, representing the first stage of cement degradation. The most important degradation products (α- and β-isosaccharinic acid) were characterised and the results compared with other studies. Kinetic parameters for the main reactions were measured and discussed. A good agreement was found between the measured values and values extrapolated from the literature. The solubility of the sparingly soluble Ca-salt of α-isosaccharinic acid (ISA) was studied as well as the interaction of ISA with cement. Sorption of ISA on cement can keep the ISA concentration in the pore water of a repository at a low level. The effect of pure ISA and degradation products on the sorption of

  15. Sorption isotherms, GAB parameters and isosteric heat of sorption

    NARCIS (Netherlands)

    Quirijns, E.J.; Boxtel, van A.J.B.; Loon, van W.K.P.; Straten, van G.

    2005-01-01

    The diffusion-sorption drying model has been developed as a physics-based way to model the decreasing drying rate at low moisture contents. This new model is founded on the existence of different classes of water: free and bound water. The transition between these classes and the corresponding

  16. Better Place

    DEFF Research Database (Denmark)

    Rask, Morten; Bakke, Nikolas; Lindhøj, Jan

    Better Place is trying to reshape the automotive industry by shifting transportation from a dependency on oil to a reliance on environmentally friendly renewable energy. Better Place is developing an extensive infrastructure system that will utilise overcapacity in the production of wind power...... among others and that will drive the global transportation industry to becoming driven by electric vehicles (EVs). Better Place does this by selling its customers 'mileage' and a car without a battery. The case highlights the internationalisation process of Better Place from an international business...... perspective in order to encourage a discussion and debate about how Better Place can make their grand vision a reality in the future by overcoming the obstacles that historically have been challenging the rise of the EV industry. The case includes a historical background of the EV industry by using Denmark...

  17. Sorption compressor/mechanical expander hybrid refrigeration

    Science.gov (United States)

    Jones, J. A.; Britcliffe, M.

    1987-01-01

    Experience with Deep Space Network (DSN) ground-based cryogenic refrigerators has proved the reliability of the basic two-stage Gifford-McMahon helium refrigerator. A very long life cryogenic refrigeration system appears possible by combining this expansion system or a turbo expansion system with a hydride sorption compressor in place of the usual motor driven piston compressor. To test the feasibility of this system, a commercial Gifford-McMahon refrigerator was tested using hydrogen gas as the working fluid. Although no attempt was made to optimize the system for hydrogen operation, the refrigerator developed 1.3 W at 30 K and 6.6 W at 60 K. The results of the test and of theoretical performances of the hybrid compressor coupled to these expansion systems are presented.

  18. SORPTION AND SOLUBILITY OF LOW-SHRINKAGE RESIN-BASED DENTAL COMPOSITES

    Directory of Open Access Journals (Sweden)

    Sevda Yantcheva

    2016-04-01

    Full Text Available Background: Resin-based composites are well-established restorative materials. However, these materials may absorb significant amounts of water when exposed to aqueous environments. Sorption and solubility are affecting composite restorations by two different mechanisms; the first is the up taking of water producing an increased weight and the second is the dissolution of materials in water, leading to a weight reduction of the final conditioned samples. Objective: To measure the water sorption and solubility of different low-shrinkage resin-based composites. Six materials were selected: Filtek P60, Filtek Ultimate, SonicFill, Filtek Silorane, Kalore and Venus Diamond. Materials and methods: Five disc specimens were prepared of each material and polymerized with diode light-curing unit. Water sorption and solubility of the different materials were were calculated by means of weighting the samples before and after water immersion and desiccation. Data were statistically analyzed using Shapiro-Wilk One Way Analysis of Variance followed by the Holm-Sidak comparison test . Results: There were significant differences (p<=0.001 between materials regarding sorption and solubility. Regarding sorption F. Silorane showed lowest values, followed by SonicFill, without significant difference between them. Statistical significant differences exist between F. Silorane and F.P60, F. Ultimate, Kalore. Significant differences exist between SonicFill and F. Ultimate. F.Silorane (-0.018 and Kalore (-0.010 showed lowest values of solubility but there were marginal difference among all composites investigated. Conclusions: 1.The material with lowest values of sorption and solubility was F.Silorane. 2. The attained sorption and solubility values for composites are influenced by the differences in resin matrix composition and filler contend. 3. Modifications of dimethacrylate matrix did not minimize significantly sorption and solubility of composites. 4. Besides water

  19. Healthy Places

    Centers for Disease Control (CDC) Podcasts

    Every person has a stake in environmental public health. As the environment deteriorates, so does the physical and mental health of the people within it. Healthy places are those designed and built to improve the quality of life for all people who live, work, worship, learn, and play within their borders -- where every person is free to make choices amid a variety of healthy, available, accessible, and affordable options. The CDC recognizes significant health issues and places that are vital in developing the Healthy Places program and provides examples in this report.

  20. Place (National)

    Data.gov (United States)

    Department of Transportation — This map layer includes cities and towns in the United States, Puerto Rico, and the U.S. Virgin Islands (NTAD). A city or town is a place with a recorded population,...

  1. Taking antacids

    Science.gov (United States)

    Heartburn - antacids; Reflux - antacids; GERD - antacids ... Antacids are a good treatment for heartburn that occurs once in a while. Take antacids about 1 hour after eating or when you have heartburn. If you are taking ...

  2. Determination of Chlorinated Solvent Sorption by Porous Material-Application to Trichloroethene Vapor on Cement Mortar.

    Science.gov (United States)

    Musielak, Marion; Brusseau, Mark L; Marcoux, Manuel; Morrison, Candice; Quintard, Michel

    2014-08-01

    Experiments have been performed to investigate the sorption of trichloroethene (TCE) vapor by concrete material or, more specifically, the cement mortar component. Gas-flow experiments were conducted using columns packed with small pieces of cement mortar obtained from the grinding of typical concrete material. Transport and retardation of TCE at high vapor concentrations (500 mg L -1 ) was compared to that of a non-reactive gas tracer (Sulfur Hexafluoride, SF6). The results show a large magnitude of retardation (retardation factor = 23) and sorption (sorption coefficient = 10.6 cm 3 g -1 ) for TCE, compared to negligible sorption for SF6. This magnitude of sorption obtained with pollutant vapor is much bigger than the one obtained for aqueous-flow experiments conducted for water-saturated systems. The considerable sorption exhibited for TCE under vapor-flow conditions is attributed to some combination of accumulation at the air-water interface and vapor-phase adsorption, both of which are anticipated to be significant for this system given the large surface area associated with the cement mortar. Transport of both SF6 and TCE was simulated successfully with a two-region physical non-equilibrium model, consistent with the dual-medium structure of the crushed cement mortar. This work emphasizes the importance of taking into account sorption phenomena when modeling transport of volatile organic compounds through concrete material, especially in regard to assessing vapor intrusion.

  3. Healthy Places

    Centers for Disease Control (CDC) Podcasts

    2007-04-10

    Every person has a stake in environmental public health. As the environment deteriorates, so does the physical and mental health of the people within it. Healthy places are those designed and built to improve the quality of life for all people who live, work, worship, learn, and play within their borders -- where every person is free to make choices amid a variety of healthy, available, accessible, and affordable options. The CDC recognizes significant health issues and places that are vital in developing the Healthy Places program and provides examples in this report.  Created: 4/10/2007 by CDC National Center for Environmental Health.   Date Released: 4/13/2007.

  4. Designed Places

    DEFF Research Database (Denmark)

    Stender, Marie

    The 2008 financial crisis has left traces in the built environment of Copenhagen like many other places: Building projects are left unfinished or their function or finish is changed due to new economic circumstances. An ethnographic exploration of these traces exposes central aspects of what is a......, and when the ceilings leak water, the residents suspect it to be a consequence of the crisis. The paper discusses how market forces interact with the material surroundings we inhabit and explores the relationship between controlled and uncontrollable in the design of places....

  5. Secret Places.

    Science.gov (United States)

    Ridolfi, Kerry

    1997-01-01

    Argues that children are as deep as the ocean, with secret places inside of them waiting to be opened. Notes that it is powerful for students to learn they can make sense of the world through words, and describes inviting them into poetry as they read poetry, create poetry packets, and write and revise poems. (SR)

  6. Envisioning place

    DEFF Research Database (Denmark)

    Schmidt, Garbi; Glick Schiller, Nina

    2016-01-01

    together, the articles contribute to an emerging relational social science by approaching urban sociabilities through four interrelated parameters: (1) a concept of place-making situated within trajectories of differential and multiscalar power; (2) a discursive analysis of narratives and silences...

  7. Comparison of sorption measurements on argillaceous rocks and bentonite with predictions using the SGT-E2 approach to derive sorption data bases

    Energy Technology Data Exchange (ETDEWEB)

    Bradbury, M. H.; Baeyens, B; Marques Fernandes, M.

    2014-11-15

    In Stage 1 of the Sectoral Plan for Deep Geological Repositories, four rock types have been identified as being suitable host rocks for a radioactive waste repository, namely, Opalinus Clay for a high-level (HLW) and a low- and intermediate-level (L/ILW) repository, and 'Brauner Dogger', Effingen Member and Helvetic Marls for a L/ILW repository. Sorption data bases (SDBs) for all of these host rocks are required for the provisional safety analyses, including all of the bounding porewater and mineralogical composition combinations. In addition, SDBs are needed for the rock formations lying below Opalinus Clay (lower confining units) and for the bentonite backfill in the HLW repository. A detailed procedure was developed for deriving SDBs for argillaceous rocks (and bentonite) based on sorption edge measurements on illite (and montmorillonite), the hypothesis that 2:1 clay minerals are the dominant sorbents and a series of so called conversion factors which take into account the different radionuclide speciations in the different porewaters. Since this methodology for generating SDBs is relatively new, a validation and demonstration of the robustness and reliability of the sorption values derived was required. This report describes an extensive piece of work in which blind predictions of sorption values were compared with measured ones. Sorption isotherms were measured for the following metal ions Cs(I), Co(II), Ni(II), Eu(III), Th(IV) and U(VI) in a range of realistic porewater chemistries for a range of host rock mineralogies. In the end 53 isotherm data sets were measured. For each of these isotherms a prediction was made of the sorption at trace concentrations using the SDB derivation methodology. A comparison between measured and predicted values for each case was then made. This validation study shows that the methodology used for the derivation of the sorption data bases for argillaceous rocks and bentonite produces reliable sorption values. (authors)

  8. Superplasticizer function and sorption in high performance cement based grouts

    International Nuclear Information System (INIS)

    Onofrei, M.; Gray, M.N.; Roe, L.H.

    1991-08-01

    This report describes laboratory studies undertaken to determine interactions between the main components of high-performance cement-based grout. These interactions were studied with the grouts in both their unset and hardened states with the specific intention of determining the following: the mechanistic function of superplasticizer; the phase of residence of the superplasticizer in hardened materials; and the permanence of the superplasticizer in hardened grouts. In unset pastes attempts were made to extract superplasticizer by mechanical processes. In hardened grout the superplasticizer was leached from the grouts. A microautoradiographic method was developed to investigate the phases of residence of superplasticizer in hardened grouts and confirm the inferences from the leaching studies. In hardened grout the superplasticizer was located on the hydrated phases formed during the early stages of cement hydration. These include tricalcium aluminate hydrates and tricalcium silicate phases. There is some tendency for the superplasticizer to sorb on ettringite. The presence of superplasticizer did not coincide with the locations of unreacted silica fume and high silica content phases such as C 2 S-H. The observations explain the findings of the studies of unset pastes which also showed that the sorption of superplasticizer is likely to be enhanced with increased mixing water content and, hence, distribution in and exposure to the hydration reaction surfaces in the grout. Superplasticizer can be leached in very small quantities from the hardened grouts. Rapid release takes place from the unsorbed superplasticizer contained in the accessible pore space. Subsequent release likely occurs with dissolution of the cement phases and the exposure of isolated pores to groundwater. (au) (37 refs.)

  9. Places Connected:

    DEFF Research Database (Denmark)

    Hansen, Annette Skovsted

    This paper argues that development assistance contributed to the globalization of the 20th century by financing truly global networks of people. By focusing on the networks financed by development assistance bound by the national histories of Denmark and Japan, I illustrate how the people who...... experiences of place, however, when it is often the same people who experience many different places? Along with many other so-called donors in the 1950s, Denmark and Japan chose to invest in the education of own and other nationals involved in development and thereby financed personal connections between...... individuals throughout the world. Development assistance , where there are two or three links only between a Bangladeshi farmer, a street child in Sao Paolo and the President of the United States, the Queen of Denmark, or a suburban house wife in Japan, who has never left the Osaka area, but mothered a United...

  10. Places available**

    CERN Multimedia

    2003-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: ACCESS 2000 - niveau 1 : 13 & 14.11.03 (2 jours) C++ for Particle Physicists : 17 – 21.11.03 (6 X 3-hour lectures) Programmation automate Schneider TSX Premium – niveau 2 : 18 – 21.11.03 (4 jours) JAVA 2 Enterprise Edition – Part 1 : WEB Applications : 20 & ...

  11. Sorption Energy Maps of Clay Mineral Surfaces

    International Nuclear Information System (INIS)

    Cygan, Randall T.; Kirkpatrick, R. James

    1999-01-01

    A molecular-level understanding of mineral-water interactions is critical for the evaluation and prediction of the sorption properties of clay minerals that may be used in various chemical and radioactive waste disposal methods. Molecular models of metal sorption incorporate empirical energy force fields, based on molecular orbital calculations and spectroscopic data, that account for Coulombic, van der Waals attractive, and short-range repulsive energies. The summation of the non-bonded energy terms at equally-spaced grid points surrounding a mineral substrate provides a three dimensional potential energy grid. The energy map can be used to determine the optimal sorption sites of metal ions on the exposed surfaces of the mineral. By using this approach, we have evaluated the crystallographic and compositional control of metal sorption on the surfaces of kaolinite and illite. Estimates of the relative sorption energy and most stable sorption sites are derived based on a rigid ion approximation

  12. Places available

    CERN Multimedia

    2004-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. Places available The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses : Introduction à Outlook : 19.8.2004 (1 journée) Outlook (short course I) : E-mail : 31.8.2004 (2 hours, morning) Outlook (short course II) : Calendar, Tasks and Notes : 31.8.2004 (2 hours, afternoon) Instructor-led WBTechT Study or Follow-up for Microsoft Applications : 7.9.2004 (morning) Outlook (short course III) : Meetings and Delegation : 7.9.2004 (2 hours, afternoon) Introduction ...

  13. Places disponibles*/Places available **

    CERN Multimedia

    2003-01-01

    Des places sont disponibles dans les cours suivants : Places are available in the following course : Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 20 - 22.1.03 (3 days) Introduction to PVSS : 27.1.03 (Afternoon) free course but registration necessary Basic PVSS : 28 - 30.1.03 (3 days) MAGNE-03 - Magnétisme pour l'électrotechnique : 28 - 30.1.03 (3 jours) MAGNE-03 - Magnetism for Technical Electronics : 11 - 13.2.03 (3 days) AutoCAD 2002 - niveau 1 : 24, 25.2 et 3, 4.3.03 (4 jours) AutoCAD 2002 - niveau 2 : 10 & 11.3.03 (2 jours) C++ for Particle Physicists : 10 - 14.3.03 (6 X 3 hour lectures) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 17, 18, 24 & 25.3.03 (6 jours) * Etant donné le délai d'impression du Bulletin, ces places peuvent ne plus être disponibles au moment de sa parution. Veuillez consulter notre site Web pour avoir la dernière mise à jour. ** The number of places available may vary. Please check our Web site to find out the current availability. Si vous désirez ...

  14. Applicability of microautoradiography to sorption studies

    International Nuclear Information System (INIS)

    Thompson, J.L.; Wolfsberg, K.

    1979-01-01

    The technique of microautoradiography was applied to the study of the sorption of uranium and americium on five rock types which exist at the Nevada Test Site. It was found that autoradiograms could be prepared in a few days which would allow the specific minerals responsible for sorption to be identified. Furthermore, the state of aggregation of the sorbed species was clearly indicated. It was concluded that microautoradiography was a useful adjunct to currently used methods for studying sorption of certain radionuclides

  15. Strontium sorption on Savannah River Plant soils

    International Nuclear Information System (INIS)

    Hoeffner, S.L.

    1984-12-01

    A laboratory study of strontium-85 sorption was conducted using Savannah River Plant soil and groundwater from the low-level waste burial ground. Systematic variation of soil and water composition indicates that strontium sorption is most strongly a function of pH. Changes in clay content and in K + , Ca 2+ , or Mg 2+ concentrations influence strontium sorption indirectly through the slight pH changes which result. The ions Na + , Cl - , and NO 3 - have no effect. Ferrous ion, added to groundwater to simulate the conditions of water at the bottom of waste trenches, did not account for low strontium sorption observed with some trench waters

  16. Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid

    International Nuclear Information System (INIS)

    Milosavljevic, Nedeljko B.; Ristic, Mirjana D.; Peric-Grujic, Aleksandra A.; Filipovic, Jovanka M.; Strbac, Svetlana B.; Rakocevic, Zlatko Lj.; Kalagasidis Krusic, Melina T.

    2011-01-01

    Highlights: → A removal of Zn 2+ ions by pH-sensitive Ch/IA/MAA hydrogel from aqueous solutions was studied. → SEM/EDX analysis and AFM surface topography indicate that sorption takes place on the surface of the hydrogel and in the bulk. → FTIR spectra of the Ch/IA/MAA hydrogel, free and Zn-loaded, indicate that -NH 2 , -OH and -COOH groups are involved in the sorption process. → The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. → The adsorption capacities did not show any significant decrease after the third reuse cycle. - Abstract: Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn 2+ ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudo-second order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.

  17. Taking Stock.

    Science.gov (United States)

    Merriam, Sharan B.

    1993-01-01

    A complete theory of adult learning must take into consideration the learner, learning process, and context. Andragogy, self-directed learning, consciousness, critical theory, feminism, transformational learning, and situated cognition contribute to understanding of this complex phenomenon. (SK)

  18. Planned place of birth

    DEFF Research Database (Denmark)

    Overgaard, Charlotte; Coxon, Kirstie; Stewart, Mary

    Title Planned place of birth: issues of choice, access and equity. Outline In Northern European countries, giving birth is generally safe for healthy women with uncomplicated pregnancies, and their babies. However, place of birth can affect women’s outcomes and experiences of birth. Whilst tertiary...... countries, maternity care is provided free to women, through public financing of health care; universal access to care is therefore secured. Nevertheless, different models of care exist, and debates about the appropriateness of providing maternity care in different settings take place in both countries...... in Denmark Coxon K et al: Planned place of birth in England: perceptions of accessing obstetric units, midwife led units and home birth amongst women and their partners. How these papers interrelate These papers draw upon recent research in maternity care, undertaken in Denmark and in England. In both...

  19. Places available**

    CERN Multimedia

    Places are available in the following courses: Hands-on Introduction to Python Programming: 11-13.08.2003 (3 days) Introduction to the CERN Engineering Data Management System (EDMS): 26.08.2003 (1 day) The CERN Engineering Data Management System (EDMS) for Engineers: 27.08.2003 (1 day) CLEAN-2002 : Travailler en salle blanche : 4.09.2003 (une demi-journée) AutoCAD 2002 - Level 1: 4, 5, 15, 16.09.2003 (2 x 2 days) AutoCAD Mechanical 6 PowerPack : 17, 18, 25, 26.09.2003 et 2, 3.10.2003 (3 x 2 journées, français) AutoCAD 2002 - niveau 1 : 23, 24, 30.09.2003 et 1.10.2003 (2 x 2 journées) Introduction to the CERN Engineering Data Management System (EDMS): 23.09.2003 (1 day) The CERN Engineering Data Management System (EDMS) for Local Administrators: 24-25.09.2003 (2 days) AutoCAD 2002 - niveau 2 : 8 et 10.10.2003 (2 journées) CLEAN-2002: Working in a Cleanroom: 23.10.2003 (half day, p.m.) ** The number of places available may vary. Please check our Web site to find out the current availabili...

  20. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: Hands-on Introduction to Python Programming: 11-13.08.2003(3 days) Introduction to the CERN Engineering Data Management System (EDMS): 26.08.2003 (1 day) The CERN Engineering Data Management System (EDMS) for Engineers: 27.08.2003 (1 day) CLEAN-2002 : Travailler en salle blanche : 4.09.2003 (une demi-journée) AutoCAD 2002 - Level 1: 4, 5, 15, 16.09.2003 (2 x 2 days) AutoCAD Mechanical 6 PowerPack : 17, 18, 25, 26.09.2003 et 2, 3.10.2003 (3 x 2 journées, français) AutoCAD 2002 - niveau 1 : 23, 24, 30.09.2003 et 1.10.2003 (2 x 2 journées) Introduction to the CERN Engineering Data Management System (EDMS): 23.09.2003 (1 day) The CERN Engineering Data Management System (EDMS) for Local Administrators: 24-25.09.2003 (2 days) AutoCAD 2002 - niveau 2 : 8 et 10.10.2003 (2 journées) CLEAN-2002: Working in a Cleanroom: 23.10.2003 (half day, p.m.) ** The number of places available may vary. Please ch...

  1. Media places

    DEFF Research Database (Denmark)

    Linde, Per; Messeter, Jörn

    The impact that ubiquitous wireless network technologies and mobile phones have on our experience of the modern cityscape, has been a driving force in many research projects in recent years. The agendas differ in relation to perspectives, but it seems safe to claim that such technologies are no l......The impact that ubiquitous wireless network technologies and mobile phones have on our experience of the modern cityscape, has been a driving force in many research projects in recent years. The agendas differ in relation to perspectives, but it seems safe to claim that such technologies...... construction of place in the urban setting. The concept of Hertzian space, put forth by Anthony Dunne and others (Dunne, 1999) also carries a dimension of how spaces of wireless communication may be problematized, and how we can criticize cultural phenomena taken for granted through innovative technology. From...... this perspective wireless technology can also be a way of temporarily appropriating places within the city space for a variety of different groups, at times questioning hierarchical structures of ownership of public spaces. These spaces can be said to be hybrid spaces, bringing forth the fundamental question...

  2. Places available**

    CERN Multimedia

    2003-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval Tel. 74924technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: MATLAB Fundamentals and Programming Techniques (ML01) : 2 & 3.12.03 (2 days) Oracle 8i : SQL : 3 - 5.12.03 (3 days) The EDMS MTF in practice : 5.12.03 (afternoon, free of charge) Modeling Dynamic Systems with Simulink (SL01) : 8 & 9.12.03 (2 days) Signal Processing with MATLAB (SG01) : 11 & 12.12.03 (2 days) The JAVA Programming Language - l...

  3. Places available**

    CERN Multimedia

    2003-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: MATLAB Fundamentals and Programming Techniques (ML01) :2 & 3.12.03 (2 days) Oracle 8i : SQL : 3 - 5.12.03 (3 days) The EDMS MTF in practice : 5.12.03 (afternoon, free of charge) Modeling Dynamic Systems with Simulink (SL01) : 8 & 9.12.03 (2 days) Signal Processing with MATLAB (SG01) : 11 & ...

  4. Places available**

    CERN Multimedia

    2004-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt.TECHNICAL TRAINING Monique Duval tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: The JAVA Programming Language Level 1 : 9 & 10.1.2004 (2 days) The JAVA Programming Language Level 2 : 11 to 13.1.2004 (3 days) LabVIEW base 1 : 25 - 27.2.2004 (3 jours) CLEAN-2002 : Working in a Cleanroom : 10.3.2004 (afternoon - free of charge) C++ for Particle Physicists : 8 - 12.3.2004 ( 6 X 4-hour sessions) LabVIEW Basics 1 : 22 - 24.3.20...

  5. Places available**

    CERN Document Server

    2004-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: The JAVA Programming Language Level 1 :9 & 10.1.2004 (2 days) The JAVA Programming Language Level 2 : 11 to 13.1.2004 (3 days) Hands-on Introduction to Python Programming : 16 - 18.2.2004 (3 days - free of charge) CLEAN-2002 : Working in a Cleanroom : 10.3.2004 (afternoon - free of charge) C++ for Particle Physicists : 8 - 12.3.2004...

  6. Places available**

    CERN Document Server

    2003-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval Tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: JAVA 2 Enterprise Edition - Part 1 : WEB Applications : 20 & 21.11.03(2 days) FrontPage 2000 - niveau 1 : 20 & 21.11.03 (2 jours) Oracle 8i : SQL : 3 - 5.12.03 (3 days) Oracle 8i : Programming with PL/SQL : 8 - 10.12.03 (3 days) The JAVA Programming Language - leve...

  7. Places available**

    CERN Multimedia

    2003-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. TECHNICAL TRAINING Monique Duval tel. 74924 technical.training@cern.ch ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: Project Planning with MS-Project : 15 & 22.1.2004 (2 days) Joint PVSS JCOP Framework Course : 2 sessions : 2 - 6.2.2004 and 16 - 20-2-2004 (5 days) Hands-on Introduction to Python Programming : 16 - 18.2.2004 (3 days - free of charge) C++ for Particle Physicists : 8 - 12.3.2004 ( 6 X 4-hour sessions)

  8. Places available **

    CERN Multimedia

    2003-01-01

    Des places sont disponibles dans les cours suivants : Places are available in the following courses : WorldFIP 2003 pour utilisateurs : 11-14.2.03 (4 jours) DISP-2003 ? Spring I Term : Introduction to Digital Signal Processing : 20, 27.2, 6, 13, 20, 27.3, 3.4.03 (7 X 2-hour lectures) AXEL-2003 - Introduction to Accelerators : 24-28.2.03 (10 X 1-hour lectures) AutoCAD 2002 - niveau 1 : 24, 25.2 & 3, 4.3.03 (4 jours) Introduction à Windows 2000 au CERN : 25.2.03 (1/2 journée) LabView base 2/LabView Basics 2 : 10 & 11.3.03 (2 jours/2 days) langue à définir/Language to be decided C++ for Particle Physicists : 10 ? 14.3.03 (6 X 3-hour lectures) Introduction to PVSS : 10.3.03 (half day, afternoon) Basic PVSS : 11 - 13.3.03 (3 days) LabView avancé /LabView Advanced : 12 - 14.3.03 (3 jours/3days) Langue à définir/language to be decided AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 17, 18, 24 & 25.3.03 (6 jours) PVSS - JCOP Framework Tutorial : 14.3.03 (1 day) MAGNE-03 - Magnetism for Technical Ele...

  9. Places available **

    CERN Multimedia

    2003-01-01

    Des places sont disponibles dans les cours suivants : Places are available in the following courses : Introduction à Windows 2000 au CERN : 25.2.03 (1/2 journée) LabView base 2/LabView Basics 2 : 10 & 11.3.03 (2 jours/2 days) langue à définir/Language to be decided C++ for Particle Physicists : 10 - 14.3.03 (6 X 3-hour lectures) Introduction to PVSS : 10.3.03 (half day, afternoon) Basic PVSS : 11 - 13.3.03 (3 days) LabView avancé /LabView Advanced : 12 - 14.3.03 (3 jours/3days) Langue à définir/Language to be decided AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 17, 18, 24 & 25.3.03 (6 jours) PVSS - JCOP Framework Tutorial : 14.3.03 (1 day) CLEAN-2002 : Working in a cleanroom : 2.4.03 (half-day, afternoon, free course, registration required) LabView base 1/LabView Basics 1 : 9 - 11.4.03 (3 jours/3 days) Langue à définir/Language to be decided DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (...

  10. Places available **

    CERN Multimedia

    2003-01-01

    Des places sont disponibles dans les cours suivants : Places are available in the following courses : DISP-2003 - Spring I Term : Introduction to Digital Signal Processing : 20, 27.2, 6, 13, 20, 27.3, 3.4.03 (7 X 2-hour lectures) AXEL-2003 - Introduction to Accelerators : 24 - 28.2.03 (10 X 1-hour lectures) AutoCAD 2002 - niveau 1 : 24, 25.2 & 3, 4.3.03 (4 jours) Introduction à Windows 2000 au CERN : 25.2.03 (1/2 journée) LabView base 2/LabView Basics 2 : 10 & 11.3.03 (2 jours/2 days) langue à définir/Language to be decided C++ for Particle Physicists : 10 - 14.3.03 (6 X 3-hour lectures) Introduction to PVSS : 10.3.03 (half day, afternoon) Basic PVSS : 11 - 13.3.03 (3 days) LabView avancé /LabView Advanced : 12 - 14.3.03 (3 jours/3days) Langue à définir/language to be decided AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 17, 18, 24 & 25.3.03 (6 jours) PVSS - JCOP Framework Tutorial : 14.3.03 (1 day) CLEAN-2002 : Working in a cleanroom : 2.4.03 (half-day, afternoon, free course, regis...

  11. Places available **

    CERN Multimedia

    2003-01-01

    Des places sont disponibles dans les cours suivants : Places are available in the following courses : C++ for Particle Physicists : 10 - 14.3.03 (6 X 3-hour lectures) Introduction to PVSS : 10.3.03 (half day, afternoon) Basic PVSS : 11 - 13.3.03 (3 days) PVSS - JCOP Framework Tutorial : 14.3.03 (1 day) CLEAN-2002 : Working in a cleanroom : 2.4.03 (half-day, afternoon, free course, registration required) LabView base 1/LabView Basics 1 : 9 - 11.4.03 (3 jours/3 days) Langue à définir/language to be decided DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03 (6 jours) Formation Siemens SIMATIC /Siemens SIMATIC Training : Introduction à STEP7 /Introduction to STEP7 : 11 & 12.3.03 / 3 & 4.6.03 (2 jours/2 days) Programmation STEP7/STEP7 Programming : 31.3 - 4.4.03 / 16...

  12. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: Conception de PCB rapides dans le flot Cadence : 11.6.03 (matin) EXCEL 2000 - level 1 : 12 & 13.6.03 (2 days) Introduction to PVSS : 16.6.03 (p.m.) Basic PVSS : 17 - 19.6.03 (3 days) Réalisation de PCB rapides dans le flot Cadence : 17.6.03 (matin) PVSS - JCOP Framework Tutorial : 20.6.03 (1 day) Programmation automate Schneider : Programmation automate Schneider TSX Premium - 2ème niveau : 24 - 27.6.03 (4 jours) - audience : toute personne qui veux maitriser la mise en uvre et la programmation des fonctions spécialisées d'un automate TSX Premium - objectifs : maitriser la mise en uvre et la programmation des fonctions spécialisées d'un automate TSX Premium Cours de sécurité : Etre TSO au CERN : Prochaines sessions : 24, 25 & 27.6.03 - 4, 5 & 7.11.03 (session de 3 jours) ** The number of places available may vary. Please check our Web site to find out the current availability. If you wish to participate in one of these courses, pl...

  13. Places available**

    CERN Multimedia

    2003-01-01

    If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. ** The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses : EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) CLEAN-2002 : Working in a Cleanroom (free of charge) : 23.10.03 (half day) The EDMS-MTF in practice (free of charge) :  28 -  30.10.03 (6 half-day sessions) AutoCAD 2002 - Level 1 : 3, 4, 12, 13.11.03 (4 days) LabVIEW TestStand ver. 3 : 4 & 5.11.03 (2 days) Introduction to Pspice : 4.11.03 p.m. (half-day) Hands-on Introduction to Python Programm...

  14. PLACES AVAILABLE

    CERN Multimedia

    Enseignement Technique; Tél. 74924; Technical Training; Monique Duval; Tel. 74924

    2000-01-01

    Places available Places are available in the following courses:   LabView hands-on 13.11.00 4 hours LabView Basics 1 14 - 16.11.00 3 days Nouveautés de WORD 19 et 20.10.00 2 jours ACCESS 1er niveau 30 - 31.10.00 2 jours Advanced aspects of the C language 2 - 3.11.00 2 days Introduction to Oracle SQL and PL/SQL 13 - 17.11.00 5 days C++ for Particle Physicists 20 - 24.11.00 6 lectures Develop PL/SQL Program Units 20 - 22.11.00 3 days Oracle Application Server Develop Web-Based Applications with PL/SQL 27 - 28.11.00 2 days Programmation TSX Premium 1 28.11 - 1.12.00 4 jours Programmation TSX Premium 2 12 - 15.12.00 4 jours If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : http://www.cern.ch/Training/ or fill in an “application for training” form available from your Divisional Secretariat or from your DTO (Divisional Training Offi...

  15. Production of sorption-active polypropylene fibers by radiation-induce grafting of glycidyl methacrylate as a precursor monomer

    International Nuclear Information System (INIS)

    Bondar, Yu.V.; Kim, H.J.; Lim, Y.J.; Kravets, L.I.

    2004-01-01

    Full text: Two types of sorption-active polypropylene fiber carrying strong-acid sulfonate groups and amino groups have been synthesized by radiation-induced graft polymerization of glycidyl methacrylate (GMA) with subsequent chemical modification of the epoxy groups of poly-GMA graft chains. The effect of various polymerization parameters on the GMA grafting degree was investigated in detail. The epoxy ring-opening of poly-GMA graft chains with introduction of strong-acid sulfonate groups was carried out with sodium hydrogen sulfite in water-dimethylformamide solution at 70 o C. The main peculiarities of the sulfonation reaction in depending on the reaction time and GMA grafting degree have been investigated. It was shown that for the samples with GMA grafting degree more than 50% two simultaneous processes take place during the sulfonation reaction, namely the incorporation of the sulfonate groups via opening of the GMA epoxy-rings as well as hydrolysis of the GMA epoxy-rings with the formation of α-glycol groups. Amine groups were incorporated by treatment of GMA-grafted polypropylene fibers with excess of diethylene triamine reagent. The conversion of the epoxy groups into the functional groups was investigated as a function of the degree of GMA grafting and reaction time. The ion-exchange characteristics of obtained sorption-active polypropylene fibers were determined

  16. Production of sorption-active polypropylene fiber by radiation-induce grafting of glycidyl methacrylate as a precursor monomer

    International Nuclear Information System (INIS)

    Bondar, Yu.V.; Kim, H.J.; Lim, Y.J.; Kravets, L.I.

    2004-01-01

    Two types of sorption-active polypropylene fiber carrying strong-acid sulfonate groups and amino groups have been synthesized by radiation-induced graft polymerization of glycidyl methacrylate (GMA) with subsequent chemical modification of the epoxy groups of poly-GMA graft chains. The effect of various polymerization parameters on the GMA grafting degree was investigated in detail. The epoxy ring-opening of poly-GMA graft chains with introduction of strong-acid sulfonate groups was carried out with sodium hydrogen sulfite in water-dimethylformamide solution at 70 o C. The main peculiarities of the sulfonation reaction in depending on the reaction time and GMA grafting degree have been investigated. It was shown that for the samples with GMA grafting degree more than 50% two simultaneous processes take place during the sulfonation reaction, namely the incorporation of the sulfonate groups via opening of the GMA epoxy-rings as well as hydrolysis of the GMA epoxy-rings with the formation of α-glycol groups. Amine groups were incorporated by treatment of GMA-grafted polypropylene fibers with excess of diethylene triamine reagent. The conversion of the epoxy groups into the functional groups was investigated as a function of the degree of GMA grafting and reaction time. The ion-exchange characteristics of obtained sorption-active polypropylene fibers were determined. (author)

  17. Experimental methodology to study radionuclide sorption and migration in geological formations and engineered barriers of waste repositories

    International Nuclear Information System (INIS)

    Rojo Sanz, H.

    2010-01-01

    In Spain, the waste management options include either the possibility of a final storage in a deep geological repository (DGR) or the centralized temporal surface disposal (CTS). DGRs are based in a multi-barrier concept with the geological barrier and including the vitrified waste, the metal containers and engineered barriers such as compacted bentonite and cement-based materials. On the other hand, CTS mainly considers concrete and cement to confine the metal canisters containing the waste. Radionuclide migration will mainly take place by the existence of chemical concentration gradients being thus diffusion the main transport mechanism or by the existence of hydraulic gradients due to the existence of water-conductive fractures. Radionuclide sorption/retention on the materials composing the natural and engineered barriers is the fundamental process controlling contaminant migration. The evaluation of sorption parameters and the understanding of the different mechanisms leading to radionuclide retention are very important issues. The study of diffusion processes is very relevant as well. This paper describes the main experimental methodologies applied to analyse radionuclide transport in the different barriers of radioactive repositories. Particularly we focused on obtaining of retention parameters as distribution coefficients, kd, or retardation factors, Rf, and diffusion coefficients of radionuclides. (Author) 6 refs.

  18. Place identity and place scale: the impact of place salience.

    OpenAIRE

    Bernardo, Fátima; Palma-Oliveira, José-Manuel

    2013-01-01

    Research about place, place identity and attachment supports the idea that bonds with places may differ depending on the place scale. Based on the view that identity is context-dependent, this paper brings to the table the impact of manipulating the salience of place on the intensity of place identity and place attachment reported. A study was designed to examine place identity and place attachment in two groups of residents (permanent and temporary) at three different scales (nei...

  19. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Introduction to Databases :  3 - 4.7.01 (2 days) The JAVA programming language Level 2 : 4 - 6.7.01 (3 days) Enterprise JavaBeans :  9 - 11.7.01 (3 days) Design Patterns :  10 - 12.7.01 (3 days) C++ for Particle Physicists :  23 - 27.7.01 (6 3-hour lectures) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : http://www.cern.ch/Training/ or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt.

  20. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Introduction to Perl 5 : 2 - 3.7.01 (2 days) Introduction to Databases :  3 - 4.7.01 (2 days) JAVA programming language Level 2 : 4 - 6.7.01 (3 days) Enterprise JavaBeans :  9 - 11.7.01 (3 days) Design Patterns :  10 - 12.7.01 (3 days) C++ for Particle Physicists :  23 - 27.7.01 (6 3-hour lectures) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : http://www.cern.ch/Training/ or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt.

  1. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: CLEAN-2002 : Travailler en salle blanche (cours gratuit) : 13.08.2002 (matin) Introduction to the CERN Enginnering Data Management System :  27.8.02  (1 day) The CERN Engineering Data Management System for Advanced Users :  28.8.02  (1 day) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. Technical Training Monique Duval Tel.74924 monique.duval@cern.ch    

  2. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: C++ Programming Level 2 - Traps & Pitfalls:  16 - 19.7.02 (4 days) Frontpage 2000 - level 1 :  22 - 23.7.02  (2 days) Introduction à Windows 2000 au CERN : 24.7.02 (après-midi) CLEAN-2002 : Travailler en salle blanche (cours gratuit) : 13.08.2002 (matin) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. Technical Training Monique Duval Tel.74924 monique.duval@cern.ch

  3. Placing knowledge

    DEFF Research Database (Denmark)

    Adriansen, Hanne Kirstine; Valentin, Karen; Nielsen, Gritt B.

    ; on the other hand, the rationale for strengthening mobility through internationalisation is based on an imagination of the potentials of particular locations (academic institutions). Intrigued by this tension between universality and particularity in academic knowledge production, this paper presents...... preliminary findings from a project that study internationalisation of higher education as an agent in the interrelated processes of place-making and knowledge-making. The project is based on three case-studies. In this paper, focus is on PhD students’ change of research environment. This is used as a case......Internationalisation of higher education is premised by a seeming paradox: On the one hand, academic knowledge strives to be universal in the sense that it claims to produce generalizable, valid and reliable knowledge that can be used, critiqued, and redeveloped by academics from all over the world...

  4. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: December 2002   PCAD Schémas - Débutants :  5 & 6.12.02  (2 jours) PCAD PCB - Débutants :  9 - 11.12.02  (3 jours) FrontPage 2000 - level 1:  9 & 10.12.02  (2 days) Introduction à la CAO Cadence (cours gratuit) :  10 & 11.12.02  (2 jours) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. Technical Training Monique Duval Tel.74924 monique.duval@cern.ch

  5. Sorption of cadmium and lead by clays from municipal incinerator ash- water suspensions

    Science.gov (United States)

    Roy, W.R.; Krapac, I.G.; Steele, J.D.

    1993-01-01

    The effect of Cl complexation in extracts of a flue gas-scrubber incinerator fly ash sample on the sorption of Cd and Pb by kaolinite and illite was investigated using batch-sorption methods. In the pH range of 5 to 9, Cl complexation may reduce sorption and thus increase the mobility of these metals. When an ash-water suspension was acidified to pH 6.85, the dissolution of Cl and Ca essentially eliminated Cd sorption because of complexation and cationic competition. Cadmium would be considered as either mobile or very mobile under these conditions. Lead was not soluble in the pH- 6.85 suspension. At pH 12, the approximate pH of water in contact with flue gas-scrubber fly ash, Cd was essentially insoluble and Pb occurred as anionic Pb hydroxide. Anionic Pb was sorbed by the two clays, and the extent of sorption was not influenced by Cl or carbonate complexation. Sorption constants, derived from isotherms, suggested that Pb would be relatively immobile in saturated soil-water systems. The recent concern that highly alkaline, flue gas-scrubber fly ash may release environmentally significant concentrations of mobile Pb when placed in an ash-disposal site with a soil liner should be reevaluated in light of this study.

  6. Sorption-desorption of samarium in Febex bentonite

    International Nuclear Information System (INIS)

    Ramirez-Guinart, O.; Rigol, A.; Vidal, M.; Fernandez-Poyatos, P.; Alba, M. D.

    2012-01-01

    with a Be window. Determination of Sm in the solutions derived from sorption-desorption experiments. Samarium concentrations were determined with ICP-OES and ICP-MS. The wavelength used in the ICP-OES was 359.3 nm, whereas the isotope 147 Sm was used in the ICP-MS. The quantification limits for the ICP-OES and ICP-MS were 30 μg L -1 and 10 ng L -1 , respectively. The initial sample shows an asymmetric 001 reflexion whose maximum corresponds to a basal spacing of 14.6 A and a shoulder to a higher 2θ. This is compatible with a heterogeneity composition of the interlayer space where divalent cations predominate. After sorption in water and at increasing Sm concentrations, the peaks became symmetric and the 001 reflexion shifted progressively to lower 2θ up to a basal spacing of 15.3 A compatible with a more homogeneous composition of the interlayer space and the exchange of the original interlayer divalent cations with Sm. These results indicated that whereas at lower concentration sorption was controlled by inner-sphere mechanisms, at higher initial Sm concentrations the predominant sorption mechanism was cationic exchange. The scenario differed when the sorption took place in the interstitial water medium, as the 001 reflexion did not shift to lower 2θ, but it widened and slightly shifted to higher 2θ. Both facts indicate competitiveness between Sm and the cations in the solution. Although the affinity for the interlayer space, in general, increases with the cation charge and then favors Sm, this was only observed for the highest initial Sm concentrations. Samarium sorption-desorption Samarium sorption was higher in water than in the interstitial, basically due to the cationic competition effect both for specific and for ionic-exchange, regular sites. This was consistent with results from the XRD analyses, and it was corroborated by the increase in the divalent cation concentrations in the final solutions after sorption when increasing samarium initial

  7. Sorption of radionuclides on inorganic sorbents

    International Nuclear Information System (INIS)

    Rajec, P.; Matel, L.

    1995-01-01

    The sorption of cesium, strontium, plutonium and americium from water solution on natural zeolite, clay minerals, synthetic zeolites and ferrocyanides in silica gel matrix was studied. The same experiments but with synthetic zeolites irradiated by the dose 100 kGy proved no change in sorption properties. 1 tab., 4 refs

  8. Nitrate Sorption in an Agricultural Soil Profile

    Directory of Open Access Journals (Sweden)

    Wissem Hamdi

    2013-01-01

    Full Text Available Increasing concentrations of in surface water and groundwater can cause ecological and public health effects and has come under increased scrutiny by both environmental scientists and regulatory agencies. For many regions though, including the Sahel of Tunisia, little is known about the sorption capacity of soils. In this project we measured sorption by a profile of an iso-humic soil from Chott Meriem, Tunisia. Soil samples were collected from four soil depths (0–25, 25–60, 60–90, and 90–120 cm on 1 June 2011, and their sorption capacity was determined using batch experiments under laboratory conditions. The effects of contact time, the initial concentration, and the soil-solution ratio on sorption were investigated. In general, the results suggested that was weakly retained by the Chott Meriem soil profile. The quantity of sorption increased with depth, contact time, initial concentration, and soil-solution ratios. To evaluate the sorption capacities of the soil samples at concentrations ranging between 25 and 150 mg L−1 experimental data were fitted to both Freundlich and Langmuir isotherm sorption models. The results indicated that Freundlich model was better for describing sorption in this soil profile.

  9. Autoradiographic study of actinide sorption on climax stock granite

    International Nuclear Information System (INIS)

    Beall, G.W.; O'Kelley, G.D.; Allard, B.

    1980-06-01

    An autoradiographic technique that employed an arrangement for placing in firm contact Polaroid sheet film, a scintillator screen, and the radioactive face of a specimen was applied to a study of the sorption of americium, neptunium, plutonium, and uranium on Climax Stock granite under varying conditions of pH and Eh. Qualitative agreement was found between the sorption of americium on crushed, pure minerals and on the minerals comprising the specimen of Climax Stock granite. The observations also supported a mechanism for reduction of Np(V) to Np(IV) and Pu(VI) to Pu(IV) by Fe(II)-containing minerals. There was no evidence for reduction of U(VI) by the Fe(II)-containing minerals, although the uranium, assumed to be present as UO 2 2+ , appeared to be the only actinide species to exhibit sorption by a simple, cation-exchange mechanism at particular mineral sites. Some implications of these results for nuclear waste isolation are discussed briefly

  10. Sorption of mercury on chemically synthesized polyaniline

    International Nuclear Information System (INIS)

    Remya Devi, P.S.; Verma, R.; Sudersanan, M.

    2006-01-01

    Sorption of inorganic mercury (Hg 2+ ) and methyl mercury, on chemically synthesized polyaniline, in 0.1-10N HCl solutions has been studied. Hg 2+ is strongly sorbed at low acidities and the extent of sorption decreases with increase in acidity. The sorption of methyl mercury is very low in the HCl concentration range studied. Sorption of Hg 2+ on polyaniline in 0.1-10N LiCl and H 2 SO 4 solutions has also been studied. The analysis of the data indicates that the sorption of Hg 2+ depends on the degree of protonation of polyaniline and the nature of mercury(II) chloride complexes in solution. X-ray photoelectron spectroscopy analysis (XPS) of polyaniline sorbed with mercury show that mercury is bound as Hg 2+ . Sorbed mercury is quantitatively eluted from polyaniline with 0.5N HNO 3 . Polyaniline can be used for separation and pre-concentration of inorganic mercury from aqueous samples. (author)

  11. Phenanthrene sorption on biochar-amended soils

    DEFF Research Database (Denmark)

    Kahawaththa Gamage, Inoka Damayanthi Kumari; Moldrup, Per; Paradelo Pérez, Marcos

    2014-01-01

    on their influences on the sorption of environmental contaminants. In a field-based study at two experimental sites in Denmark, we investigated the effect of birch wood-derived biochar (Skogans kol) on the sorption of phenanthrene in soils with different properties. The soil sorption coefficient, Kd (L kg-1......), of phenanthrene was measured on sandy loam and loamy sand soils which have received from zero up to 100 t ha-1 of biochar. Results show that birch wood biochar had a higher Kd compared to soils. Furthermore, the application of birch wood biochar enhanced the sorption of phenanthrene in agricultural soils...... carbon, while it negatively correlated with clay content. The results also revealed that biochar-mineral interactions play an important role in the sorption of phenanthrene in biochar-amended soil....

  12. Cobalt sorption onto Savannah River Plant soils

    International Nuclear Information System (INIS)

    Hoeffner, S.L.

    1985-06-01

    A laboratory study of cobalt-60 sorption was conducted using Savannah River Plant soil and groundwater from the low-level waste burial ground. Systematic variation of soil and water composition indicates that cobalt sorption is most strongly a function of pH. Over a pH range of 2 to 9, the distribution coefficient ranged from 2 to more than 10,000 mL/g. Changes in clay content and in K + , Ca 2+ , or Mg 2+ concentrations influence cobalt sorption indirectly through the slight pH changes which result. The ions Na + , Cl - , and NO 3 - have no effect on cobalt sorption. Ferrous ion, added to groundwater to simulate the condition of water at the bottom of the waste trenches, accounts for part of the decrease in cobalt sorption observed with trench waters. 17 refs., 3 figs., 4 tabs

  13. Places available **

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: PIPES-2003 - Pratique du Sertissage de tubes métalliques et multicouches : 26.8.03 (stage pratique) The CERN Engineering Data Management System (EDMS) for Engineers : 27.8.03 (1 day, free of charge) CLEAN-2002 : Travailler en salle blanche : 4.9.03 (une demi-journée, séminaire gratuit) The CERN Engineering Data Management System (EDMS) for Local Administrators : 24 & 25.9.03 (2 days, free of charge) Siemens SIMATIC Training : Programmation STEP7 - niveau 1 : 29 - 2.10.03 (4 jours) - ouverture des inscriptions fin août Programmation STEP7 - niveau 2 : 13 - 17.10.03 (5 jours) - ouverture des inscriptions fin août Réseau Simatic Net : 22 & 23.10.03 (2 jours) - ouverture des inscriptions fin août CLEAN-2002 : Working in a Cleanroom : 23.20.03 (half day, free of charge) These courses will be given in French or Englis...

  14. Places available**

    CERN Document Server

    2003-01-01

    Places are available in the following courses : FrontPage 2000 - niveau 1: 20 & 21.5.03 (2 jours) PIPES-2003 : Pratique du sertissage de tubes métalliques et multicouches: 21.5.03 (1 jour) Introduction à la CAO Cadence: de la saisie de schéma Concept-HDL au PCB : 20 & 22.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (E): 5, 6, 12, 13, 26, 27.6.03 (6 days) EXCEL 2000 - niveau 1: 10 & 11.6.03 (2 jours) Conception de PCB rapides dans le flot Cadence: 11.6.03 (matin) EXCEL 2000 - level 1: 12 & 13.6.03 (2 days) Introduction to PVSS: 16.6.03 (half-day, pm) Basic PVSS: 17 - 19.6.03 (3 days) Réalisation de PCB rapides dans le flot Cadence: 17.6.03 (matin) LabView DSC (language to be defined): 19 & 20.6.03 PVSS - JCOP Framework Tutorial: 20.6.03 (1 day) EXCEL 2000 - niveau 2: 24 & 25.6.03 (2 jours) Siemens SIMATIC Training: Introduction to STEP7: 3 & 4.6.03 (2 days) STEP7 Programming: 16 - 20.6.03 (5 days) Simatic Net Network: 26 & 27.6.03 (2 days) These courses will be given...

  15. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: LabView Hands-on (bilingue/bilingual - gratuit/free of charge) : 13.9.02 (a.m.) LabView DAQ Hands-on (bilingue/bilingual - gratuit/free of charge) : 13.9.02 (p.m.) AutoCAD 2002 - niveau 1 : 19, 20, 26, 27.9.02 (4 jours) LabView Base 1 : 23 - 25.9.02 (3 jours) LabView DAQ (E) : 26 - 27.9.02 (2 days) AutoCAD Mechanical 6 PowerPack (F) : 30.9, 1, 2, 9, 10, 11.10.02 (6 jours) CLEAN-2002 : Working in a Cleanroom (free of charge) : 10.10.02 (half-day, p.m.) AutoCAD 2002 - niveau 2 : 14 - 15.10.02 (2 jours) AutoCAD 2002 - Level 1 : 17, 18, 24, 25.10.02 (4 days) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Of...

  16. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Introduction to Oracle 8i : SQL and PL/SQL:  7 - 11.10.02  (5 days) CLEAN-2002 : Working in a Cleanroom (free of charge):  10.10.02  (half-day, p.m.) AutoCAD 2002 - niveau 2 :  14 - 15.10.02  (2 jours) Introduction à DesignSpace :  16.10.02  (1 journée) Introduction to DesignSpace:  17.10.02  (1 day) AutoCAD 2002 - Level 1:  17, 18, 24, 25.10.02  (4 days) AutoCAD Mechanical 6 PowerPack (F) :  21, 22, 23.10 et 4, 5, 6.11.02  (6 jours) Introduction à ANSYS/Introduction to ANSYS (langue à définir suivant demande/ Language to be chosen according to demand):  21 - 25.10.02  (5 jours/days) HREF-2002: Helium Refrigeration Techniques (English-French, bilingual) :  21 - 25.10.2002  (7 half days) HREF-2002: Techniques de la Réfri...

  17. Places available**

    CERN Document Server

    2003-01-01

    Places are available in the following courses : The CERN EDMS for Local Administrators : 24 & 25.9.03 (2 days, free of charge) HeREF-2003 : Techniques de la réfrigération Hélium (cours en français avec support en anglais) : 6 - 10.10.2003 (7 demi-journées) The Java Programming Language Level 1 : 6 - 7.10.2003 (2 days) Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 8 - 10.10.2003 (3 days) FileMaker - niveau 1 : 9 & 10.10.03 (2 jours) EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) AutoCAD 2002 - niveau 1 : 20, 21, 27, 28.10.03 (4 jours) CLEAN-2002 : Working in a Cleanroom : 23.10.03 (half day, free of charge) AutoCAD 2002 - Level 1 : 3, 4, 12, 13.11.03 (4 days) AutoCAD 2002 - niveau 2 : 10 & 11.11.03 (2 jours) ACCESS 2000 - niveau 1 : 13 & 14.11.03 (2 jours) AutoCAD Mechanical 6 PowerPack (E) : 17, 18, 24, 25.11 & 1, 2.12.03 (6...

  18. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Introduction à DesignSpace :  16.10.02  (1 journée) AutoCAD Mechanical 6 PowerPack (F) :  21, 22, 23.10 et 4, 5, 6.11.02  (6 jours) Introduction à ANSYS 21 - 25.10.02  (5 jours/days) HREF-2002: Helium Refrigeration Techniques (English-French, bilingual) :  21 - 25.10.2002  (7 half days) LabVIEW Basics 1 (English):  21 - 23.10.02  (3 days) LabVIEW Basics 2 (English):  24 & 25.10.02  (2 days) Oracle 8i : Access the Database with Java:  7 & 8.11.02  (2 days) AutoCAD 2002 - niveau 2 :  7 & 8.11.02  (2 jours) AutoCAD 2002 - Level 1:  14, 15, 21, 22.11.02  (4 days) LabVIEW - Advanced (English) :  18 - 20.11.2002  (3 days) AutoCAD 2002 - niveau 1 :  19, 20, 25, 26.11.02 (4 jours) Oracle iDS Designer: First Class:&...

  19. Places available**

    CERN Document Server

    2003-01-01

    Places are available in the following courses: CLEAN-2002 : Travailler en salle blanche (séminaire gratuit) : 4.9.03 (une demi-journée) The CERN EDMS for Local Administrators (free of charge) : 24 & 25.9.03 (2 days) HeREF-2003 : Techniques de la réfrigération Hélium (cours en français avec support en anglais) : 6 - 10.10.2003 (7 demi-journées) The Java Programming Language Level 1 : 6 - 7.10.2003 (2 days) Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 8 - 10.10.2003 (3 days) FileMaker - niveau 1 : 9 & 10.10.03 (2 jours) EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) AutoCAD 2002 - niveau 1 : 20, 21, 27, 28.10.03 (4 jours) CLEAN-2002 : Working in a Cleanroom (free of charge) : 23.10.03 (half day) AutoCAD Mechanical 6 PowerPack (E) : 23, 24, 30, 31.10 & 12, 13.11.03 (6 days) AutoCAD 2002 - niveau 2 : 10 & 11.11.03 (2 jours)...

  20. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: The CERN EDMS for Local Administrators : 24 & 25.9.03 (2 days, free of charge) HeREF-2003 : Techniques de la réfrigération Hélium cours en français avec support en anglais) : 6 - 10.10.2003 (7 demi-journées) The Java Programming Language Level 1 : 6 - 7.10.2003 (2 days) Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 8 - 10.10.2003 (3 days) FileMaker - niveau 1 : 9 & 10.10.03 (2 jours) EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) AutoCAD 2002 - niveau 1 : 20, 21, 27, 28.10.03 (4 jours) CLEAN-2002 : Working in a Cleanroom : 23.10.03 (half day, free of charge) AutoCAD 2002 - Level 1 : 3, 4, 12, 13.11.03 (4 days) AutoCAD 2002 - niveau 2 : 10 & 11.11.03 (2 jours) ACCESS 2000 - niveau 1 : 13 & 14.11.03 (2 jours) AutoCAD Mechanical 6 PowerPack (E) : 17, 18, 24, 25.11 & 1, 2.12.03 (6 days) FrontPage 2000 - niveau 1 : 20 & 21.11.03 (2 jours) MAGNE-03 : Magnétisme pour l'électrotechnique : 25 - 27.11.03 (3 jours) ...

  1. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: LabView hands-on (bilingue/bilingual): 5.11.02 (matin/morning) LabView DAQ hands-on (bilingue/bilingual):  5.11.02  (après-midi afternoon) Introduction au PC et Windows 2000 au CERN:  6 & 7.11.02  (2 jours) Oracle 8i : Access the Database with Java:  7 & 8.11.02  (2 days) AutoCAD 2002 - niveau 2:  7 & 8.11.02  (2 jours) Introduction to PVSS (free of charge):  11.11.2002 pm  (1/2 day) Basic PVSS:  12 - 14.11.02  (3 days) EXCEL 2000 - niveau 1:  12 & 13.11.02  (2 jours) CLEAN-2002: Working in a Cleanroom (English, free of charge):  13.11.2002  (afternoon) LabView Base 1 :  13 - 15.11.02  (3 jours) AutoCAD 2002 - Level 1:  14, 15, 21, 22.11.2002  (4 days) LabVIEW - Advanced:  18 - 20.11.02  (3 days) Auto...

  2. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: PIPES-2003 - Pratique du sertissage de tubes métalliques et multicouches :26.8.03(stage pratique) The CERN EDMS for Engineers (free of charge) : 27.8.03 (1 day) CLEAN-2002 : Travailler en salle blanche (séminaire gratuit) : 4.9.03(une demi-journée) The CERN EDMS for Local Administrators (free of charge) : 24 & 25.9.03 (2 days) HeREF-2003 : Techniques de la réfrigération Hélium (cours en français avec support en anglais) : 6 - 10.10.2003 (7 demi-journées) The Java Programming Language Level 1 : 6 - 7.10.2003 (2 days) Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 8 - 10.10.2003 (3 days) FileMaker - niveau 1 : 9 & 10.10.03 (2 jours) EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) AutoCAD 2002 - niveau 1 : 20, 21, 27, 28.10.03 (4 jours) CLEAN-2002 : Working in a Cleanroom (free of charge) : 23.10.03 (half day) AutoCAD Mechanical 6 PowerPack (E) : 23, 24, 30, 31.10 & 12, 13.11.03 (6 days) AutoCAD 2002 - niveau 2...

  3. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses: The CERN EDMS for Local Administrators (free of charge) : 24 & 25.9.03 (2 days) HeREF-2003 : Techniques de la réfrigération Hélium (cours en français avec support en anglais) : 6 - 10.10.2003 (7 demi-journées) The Java Programming Language Level 1 : 6 - 7.10.2003 (2 days) Java 2 Enterprise Edition - Part 2 : Enterprise JavaBeans : 8 - 10.10.2003 (3 days) FileMaker - niveau 1 : 9 & 10.10.03 (2 jours) EXCEL 2000 - niveau 1 : 20 & 22.10.03 (2 jours) AutoCAD 2002 - niveau 1 : 20, 21, 27, 28.10.03 (4 jours) CLEAN-2002 : Working in a Cleanroom (free of charge) : 23.10.03 (half day) AutoCAD Mechanical 6 PowerPack (E) : 23, 24, 30, 31.10 & 12, 13.11.03 (6 days) AutoCAD 2002 - niveau 2 : 10 & 11.11.03 (2 jours) ACCESS 2000 - niveau 1 : 13 & 14.11.03 (2 jours) FrontPage 2000 - niveau 1 : 20...

  4. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: October 2002   Introduction to the CERN Engineering Data Management System (free of charge):  29.10.2002  (1 day) The CERN EDMS for Advanced users (free of charge):  30.10.2002  (1 day) November 2002   LabView hands-on (bilingue/bilingual): 5.11.02 (matin/morning) LabView DAQ hands-on (bilingue/bilingual):  5.11.02  (après-midi afternoon) Introduction au PC et Windows 2000 au CERN :  6 & 7.11.02  (2 jours) Oracle 8i : Access the Database with Java:  7 & 8.11.02  (2 days) AutoCAD 2002 - niveau 2 :  7 & 8.11.02  (2 jours) Introduction to PVSS (free of charge):  11.11.2002 pm  (1/2 day) Basic PVSS:  12 - 14.11.02  (3 days) EXCEL 2000 - niveau 1 :  12 & 13.11.02  (2 jours) CLEAN-2002: Working in a Cleanroom (English, free ...

  5. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Introduction to Oracle 8i : SQL and PL/SQL:  7 - 11.10.02  (5 days) CLEAN-2002 : Working in a Cleanroom (free of charge):  10.10.02  (half-day, p.m.) LabView Hands-on (bilingue/bilingual) : 10.10.02 (matin/morning) LabView DAQ Hands-on (bilingue/bilingual)  10.10.02 (après-midi /afternoon) Introduction à DesignSpace :  16.10.02  (1 journée) Introduction to DesignSpace:  17.10.02  (1 day) AutoCAD Mechanical 6 PowerPack (F) :  21, 22, 23.10 et 4, 5, 6.11.02  (6 jours) Introduction à ANSYS/Introduction to ANSYS (langue à définir suivant demande/ Language to be chosen according to demand):  21 - 25.10.02  (5 jours/days) HREF-2002: Helium Refrigeration Techniques (English-French, bilingual) :  21 - 25.10.2002  (7 half days) HREF-2002: Techniques de la...

  6. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel 74924

    2002-01-01

    Places are available in the following courses: LabView hands-on : 21.01.02 (1/2 journée) LabView DAQ hands-on : 21.01.02 (1/2 journée) FileMaker Pro : 22 - 25.1.02 (4 jours) MS-Project 2000 : 24 & 25.01.02 (2 jours) Introduction au PC et à Windows 2000 au CERN : 29 - 30.1.02 (2 jours) LabView Base 1 : 4 - 6.2.02 (3 jours) LabView DAQ (E) : 7 & 8.02.02 (2 days) Hands-on Object-Oriented Design & Programming with Java : 11 - 13.02.02 (3 days) C++ for Particle Physicists : 11 - 15.3.2002 (6 * 3 hour lectures) Cours sur la migration AutoCAD : AutoCAD : Mise à jour AutoCAD r-14 vers 2002 (2 jours) AutoCAD Mechanical PowerPack 6 basé sur AutoCAD 2002 (5 jours) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO ...

  7. PLACES AVAILABLE

    CERN Multimedia

    Enseignement Technique; Tél. 74924; Technical Training; Monique Duval; Tel. 74924

    2000-01-01

    Places are available in the following courses : Premiers pas avec votre PC 12 - 15.9.00 (4 demi-journées) WORD 20, 21 et 26, 27.9.2000 (4 jours) JAVA programming level 1 25 - 26.9.2000 (2 days) Gaz inflammables 1 26.9.2000 (1 journée) Advanced aspects of PERL 5 6.10.2000 (1 day) Initiation au WWW 10 - 12.10.00 (3 demi-journées) WORD : importer et manipuler des images 16.10.2000 (1 journée) FileMaker 17, 18 et 24, 25.10.00 (4 jours) Nouveautés de WORD 19 et 20.10.2000 (2 jours) ACCESS 1er niveau 30 - 31.10.00 (2 jours)Introduction à PowerPoint 6.11.00 (1 journée)Nouveautés d’EXCEL 7.11.2000(4 demi-journées)Excel 13, 14 et 20, 21.11.00 (4 jours) LabView hands-on 13.11.2000(4 hours)LabView Basics 1 14 - 16.11.2000 (3 days) MS-Project 1er niveau 14-17.11.00 (4 demi-journées) If you wish to participate in one of these courses, please discuss with your supervisor and apply elec...

  8. PLACES AVAILABLE

    CERN Multimedia

    TECHNICAL TRAINING; Tel. 74460

    2001-01-01

    Places are available in the following courses: MS-Project 1er niveau : 20 - 23.2.01 (4 matins) Architecture d'automatisme : 20 - 21.2.01 (2 jours) Introduction à PowerPoint : 26.2.01 (1 journée) Programmation TSX Premium 1 (Schneider) : 26.2 - 2.3.01 (5 jours) Premiers pas avec votre PC : 27.2 - 2.3.01 (4 matins) C++ for Particle Physicists : 5 - 9.3.01 (6*3 hour lectures) EXCEL : 6, 7 et 13, 14.3.01 (4 jours) The JAVA programming language level 2 :  12 - 14.3.01 (3 days) Nouveautés de FileMaker :  20 - 23.03.01 (4 matins) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : http://www.cern.ch/Training/ or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt.

  9. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2002-01-01

    Places are available in the following courses: LabView hands-on : 21.01.02 (1/2 journée) LabView DAQ hands-on : 21.01.02 (1/2 journée) FileMaker Pro : 22 - 25.1.02 (4 jours) MS-Project 2000 : 22, 24 & 25.01.02 (3 jours) Introduction au PC et à Windows 2000 au CERN : 29 - 30.1.02 (2 jours) LabView Base 1 : 4 - 6.2.02 (3 jours) LabView DAQ  (E) :  7 & 8.02.02 (2 days) Hands-on Object-Oriented Design & Programming with Java :  11 - 13.02.02 (3 days) PVSS basics :  11 - 15.2.02 (5 days) Introduction à Windows 2000 : 18.2.02 (1 demi-journée) Introduction to the CERN Engineering Data Management System :  20.2.02 (1 day) The CERN Engineering Data Management System for Advanced users :  21.2.02  (1 day) C++ for Particle Physicists :  11 - 15.3.2002  (6 * 3 hour lectures) Cours sur la migration AutoCAD : AutoCAD : Mise à...

  10. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: LabVIEW - Basics 1 :  10 - 12.12.01 (3 days) Introduction to XML :  12 & 13.12.01 (2 days) Introduction au PC et Windows 2000 : 12 & 14.12.01 (2 jours) LabVIEW - Basics 2 :  13 - 14.12.01 (2 days) Habilitation électrique : superviseurs : 17.12.2001 (1/2 journée) MS-Project 2000 : 10 & 11.01.02 (2 jours) EXCEL 2000 - niveau 2 : 15 - 16.1.02 (2 jours) Sécurité dans les installations cryogéniques: 15-17.1.2002 (2 demi-journées) C++ Programming Level 2 - Traps and Pitfalls :  15 - 18.1.2002  (4 days) ELEC-2002 Winter Term: Readout and system electronics for Physics  15.1.2002 - 7.2.2002 (8 half- days) Nouveautés de WORD 2000 : 18.1.02 (1/2 journée) LabView hands-on : 21.01.02 (1/2 journée) LabView DAQ hands-on : 21.01.02 (1/2 journée) FileMaker Pro : 22 -...

  11. PLACES AVAILABLE

    CERN Multimedia

    Enseignement Technique; Tel. 74924

    2001-01-01

    Places are available in the following courses: MS-Project 2000 : 10 & 11.01.02 (2 jours) EXCEL 2000 - niveau 2 : 15 - 16.1.02 (2 jours) Sécurité dans les installations cryogéniques: 15-17.1.2002 (2 demi-journées) C++ Programming Level 2 - Traps and Pitfalls :  15 - 18.1.2002  (4 days) ELEC-2002 Winter Term: Readout and system electronics for Physics  15.1.2002 - 7.2.2002 (8 half- days) Nouveautés de WORD 2000 : 18.1.02 (1/2 journée) LabView hands-on : 21.01.02 (1/2 journée) LabView DAQ hands-on : 21.01.02 (1/2 journée) FileMaker Pro : 22 - 25.1.02 (4 jours) MS-Project 2000 : 24 & 25.01.02 (2 jours) Introduction au PC et à Windows 2000 au CERN : 29 - 30.1.02 (2 jours) LabView Base 1 : 4 - 6.2.02 (3 jours) LabView DAQ  (E) :  7 & 8.02.02 (2 days) Hands-on Object-Oriented Design & Programming with Java :&nbs...

  12. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : CLEAN-2002 : Working in a cleanroom (free course, registration required) : 2.4.03 (half-day, afternoon) LabView base 1/LabView Basics 1 (Langue à définir/ language to be decided) : 9 - 11.4.03 (3 jours/3 days) DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03(6 jours) Formation Siemens SIMATIC /Siemens SIMATIC Training : Introduction à STEP7 /Introduction to STEP7 : 3 & 4.6.03 (2 jours/2 days) Programmation STEP7/STEP7 Programming : 31.3 - 4.4.03 / 16 - 20.6.03 (5 jours/5 days) Réseau Simatic Net /Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 These courses will be given in French or English following the requests. Cours de sécurité : Etre TSO au CERN : 3 sessions sont programmées pour 2003 : 25...

  13. Places available **

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : CLEAN-2002 : Working in a cleanroom (free course, registration required): 11.4.03 (half-day, afternoon, ) LabView Basics 2 : 10 - 11.4.03 (3 days) DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) Oracle iDS Reports : Build Internet Reports : 5 - 9.5.03 (5 days) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03 (6 jours) Formation Siemens SIMATIC /Siemens SIMATIC Training : Introduction à STEP7 /Introduction to STEP7 : 3 & 4.6.03 (2 jours/2 days) Programmation STEP7/STEP7 Programming : 31.3 - 4.4.03 / 16 - 20.6.03 (5 jours/5 days) Réseau Simatic Net /Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 These courses will be given in French or English following the requests. Cours de sécurité : Etre TSO au CERN : Prochaines sessions : 24, 25 & 27.6....

  14. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) Oracle iDS Reports : Build Internet Reports : 5 - 9.5.03 (5 days) LabView DAQ (language to be defined) : 8 & 9.5.03 AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03 (6 jours) AutoCAD 2002 - niveau 2 : 3 & 4.6.03 (2 jours) LabView DSC (language to be defined) : 19 & 20.6.03 Siemens SIMATIC Training : Introduction to STEP7 : 3 & 4.6.03 (2 days) STEP7 Programming : 16 - 20.6.03 (5 days) Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 (sessions of 2 days) These courses will be given in French or English following the requests. Cours de sécurité : Etre TSO au CERN : Prochaines sessions : 24, 25 & 27.6.03 - 4, 5 & 7.11.03 (session de 3 jours) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description ...

  15. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Habilitation électrique : recyclage HT/BT : 11 - 15.3.2002  (2 * 2 heures) PVSS Basics :  8 - 12.4.02  (5 days) ELEC-2002 : Spring Term :  9, 11, 16, 18, 23, 25, 30.4.02 (7 * 2.5 hours) LabVIEW base 1 : 22 - 24.4.02 (3 jours) LabVIEW DSC (F) 25 & 26.4.02 (2 jours) LabVIEW Basics 2 : 13 & 14.5.02 (2 days) LabVIEW DAQ (F) : 15 & 16.5.02 (2 jours) Cours sur la migration AutoCAD :   AutoCAD : Mise à jour AutoCAD r-14 vers 2002 (2 jours) AutoCAD Mechanical PowerPack 6 basé sur AutoCAD 2002 (5 jours) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applica...

  16. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : CLEAN-2002 : Working in a cleanroom (free course, registration required): 11.4.03 (half-day, afternoon, ) LabView Basics 2 : 10 - 11.4.03 (3 days) DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) Oracle iDS Reports : Build Internet Reports : 5 - 9.5.03 (5 days) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03(6 jours) Formation Siemens SIMATIC /Siemens SIMATIC Training : Introduction à STEP7 /Introduction to STEP7 : 3 & 4.6.03 (2 jours/2 days) Programmation STEP7/STEP7 Programming : 31.3 - 4.4.03 / 16 - 20.6.03 (5 jours/5 days) Réseau Simatic Net /Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 These courses will be given in French or English following the requests. Cours de sécurité : Etre TSO au CERN : Prochaines sessions : 24, 25 & 27.6...

  17. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) Programmation de pilotes périphériques : 5 - 8.5.03 (4 jours) Oracle iDS Reports : Build Internet Reports : 5 - 9.5.03 (5 days) LabView DAQ (language to be defined) : 8 & 9.5.03 AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.0 (6 jours) FrontPage 2000 - niveau 1 : 20 & 21.5.03 (2 jours) AutoCAD 2002 - niveau 2 : 3 & 4.6.03 (2 jours) EXCEL 2000 - niveau 1 : 10 & 11.6.03 (2 jours) EXCEL 2000 - level 1 : 12 & 13.6.03 (2 days) PowerPoint 2000 (F) : 17 & 18.6.03 (2 jours) FrontPage 2000 - niveau 2 : 19 & 20.6.03 (2 jours) LabView DSC (langue à décider/language to be defined) : 19 & 20.6.03 EXCEL 2000 - niveau 2 : 24 & 25.6.03 (2 jours) Siemens SIMATIC Training : Introduction to STEP7 : 3 & 4.6.03 (2 days) STEP7 Programming : 16 - 20.6.03 (5 days) Simatic Net Network : 26 & 27.6.03 ...

  18. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : CLEAN-2002 : Working in a cleanroom (free course, registration required): 11.4.03 (half-day, afternoon) LabView Basics 2 : 10 - 11.4.03 (3 days) DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures) AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) Oracle iDS Reports : Build Internet Reports : 5 - 9.5.03 (5 days) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03(6 jours) Formation Siemens SIMATIC /Siemens SIMATIC Training : Introduction à STEP7 /Introduction to STEP7 : 3 & 4.6.03 (2 jours/2 days) Programmation STEP7/STEP7 Programming : 16 - 20.6.03 (5 jours/5 days) Réseau Simatic Net /Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 These courses will be given in French or English following the requests. Cours de sécurité : Etre TSO au CERN : Prochaines sessions : 24, 25 & 27.6.03 - 4, 5 & 7....

  19. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : Introduction to PVSS : 10.3.03 (half-day, afternoon) CLEAN-2002 : Working in a cleanroom : 2.4.03 (half-day, afternoon, free course, registration required) LabView Basics 1 : 9 - 11.4.03 (3 days) Language to be decided. DISP-2003 - Spring II Term : Advanced Digital Signal Processing : 30.4, 7, 14, 21.5.03 (4 X 2-hour lectures). AutoCAD 2002 - niveau 1 : 29, 30.4 et 7, 8.5.03 (4 jours) AutoCAD 2002 - niveau 2 : 5 & 6.5.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 12, 13, 20, 21, 27 & 28.5.03 (6 jours) Siemens SIMATIC Training: Introduction to STEP7 : 3 & 4.6.03 (2 days) STEP7 Programming : 31.3 - 4.4.03 / 16 - 20.6.03 (5 days) Simatic Net Network : 15 & 16.4.03 / 26 & 27.6.03 These courses will be given in French or English following the requests. Cours de sécurité: Etre TSO au CERN : 3 sessions sont programmées pour 2003 : 25, 26 & 28.3.03 - 24, 25 & 27.6.03 - 4, 5 & 7.11.03 (sessions de 3 jours) ** The number o...

  20. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: November 2002   Hands-on Object-Oriented Design and Programming with C++:  19 - 21.11.02  (3 days)  December 2002   LabVIEW - DSC (English) :  2 - 3.12.02  (2 days) AutoCAD 2002 - niveau 2 :  2 & 3.12.02  (2 jours) FileMaker (Français) :  2 - 5.12.02  (4 jours) PCAD Schémas - Débutants :  5 & 6.12.02  (2 jours) PCAD PCB - Débutants :  9 - 11.12.02  (3 jours) FrontPage 2000 - level 1:  9 & 10.12.02  (2 days) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisiona...

  1. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: November 2002   Java Programming Language level 1 :  28 & 29.11.02  (2 days) December 2002   LabVIEW - DSC (English) :  2 - 3.12.02  (2 days) FileMaker (Français) :  2 - 5.12.02  (4 jours) PCAD Schémas - Débutants :  5 & 6.12.02  (2 jours) PCAD PCB - Débutants :  9 - 11.12.02  (3 jours) FrontPage 2000 - level 1:  9 & 10.12.02  (2 days) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at : Technical Training or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. Technical Training M...

  2. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: November 2002   Introduction to PVSS (free of charge): 11.11.02  (afternoon) EXCEL 2000 - niveau 1 :  12 & 13.11.02  (2 jours) CLEAN-2002: Working in a Cleanroom (English, free of charge):  13.11.2002  (afternoon) AutoCAD 2002 - niveau 1 :  14, 15, 21, 22.11.02  (4 jours) Hands-on Object-Oriented Design and Programming with C++:  19 - 21.11.02  (3 days)  EXCEL 2000 - niveau 2 :  25 & 26.11.02  (2 jours) FrontPage 2000 - niveau 1 :  27 & 28.11.02  (2 jours) December 2002   LabVIEW - DSC (English) :  2 - 3.12.02  (2 days) AutoCAD 2002 - niveau 2 :  2 & 3.12.02  (2 jours) FileMaker (Français) :  2 - 5.12.02  (4 jours) PCAD Schémas - Débutants :  5 & 6.12.02 ...

  3. PLACES AVAILABLE

    CERN Multimedia

    Technical training; Tel. 74924

    2001-01-01

    Places are available in the following courses: PROFIBUS : 25 - 26.9.01 (2 jours) PROFIBUS : 27 - 28.9.01 (2 days) Automates et réseaux de terrain : 3 - 4.10.2001 (2 jours) PCAD Schémas - débutants : 4 - 5.10.01 (2 jours) PCAD PCB - débutants : 8 - 10.10.01 (3 jours) Programmation TSX Premium 1 : 15 - 19.10.01 (5 jours) Programmation TSX Premium 1 : 22 - 26.10.01 (5 jours) Programming TSX Premium 2: 19 - 23.11.01 (5 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) Autocad Migration support courses: a detailed calendar will be published shortly for this series of sessions which will start on 15.10.2001. Registration is already open AutoCAD : Mise à jour AutoCAD r-14 vers 2002 (2 jours) AutoCAD Mechanical PowerPack 6 basé sur AutoCAD 2002 (5 jours) The following LabView courses will be given in either English or French according to demand LabVIEW - Base 1 / LabVIEW - Basics 1 : 10 - 12.9.01 (3 jours / 3 days)...

  4. PLACES AVAILABLES

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: PVSS Basics : 20 - 24.8.01 (5 days) PROFIBUS : 25 - 26.9.01 (2 jours) PROFIBUS : 27 - 28.9.01 (2 days) PCAD Schémas - débutants : 4 - 5.10.01 (2 jours) PCAD PCB - débutants : 8 - 10.10.01 (3 jours) Programming TSX Premium 1: 15 - 19.10.01 (5 days) Programmation TSX Premium 1 : 22 - 26.10.01 (5 jours) Programming TSX Premium 2: 19 - 23.11.01 (5 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) The following LabView courses will be given in either English or French according to demand LabVIEW - Base 1 / LabVIEW - Basics 1 : 10 - 12.9.01 (3 jours / 3 days) LabVIEW - DAQ / LabVIEW - DAQ : 13 - 14.9.01 (2 jours / 2 days) LabVIEW - Base 1 / LabVIEW - Basics 1 : 15 - 17.10.01 (3 jours / 3 days) LabVIEW - Base 2 / LabVIEW - Basics 2 : 18 - 19.10.01 (2 jours / 2 days) LabVIEW - Base 1 / LabVIEW - Basics 1 : 12 - 14.11.01 (3 jours / 3 days) LabVIEW - DAQ / LabVIEW - DAQ : 15 - 16.11.01 (2 jours / 2...

  5. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: November 2002   LabView hands-on (bilingue/bilingual): 5.11.02 (matin/morning) LabView DAQ hands-on (bilingue/bilingual):  5.11.02  (après-midi afternoon) PCAD Schémas - Débutants :  5 & 6.11.02  (2 jours) PCAD PCB - Débutants :  9 - 11.11.02  (3 jours) Introduction au PC et Windows 2000 au CERN :  6 & 7.11.02  (2 jours) Oracle 8i : Access the Database with Java :  7 & 8.11.02  (2 days) Introduction to PVSS (free of charge):  11.11.2002 pm  (1/2 day) Basic PVSS:  12 - 14.11.02  (3 days) EXCEL 2000 - niveau 1 :  12 & 13.11.02  (2 jours) CLEAN-2002: Working in a Cleanroom (English, free of charge):  13.11.2002  (afternoon) LabView Base 1 :  13 - 15.11.02  (3 jours) AutoCAD 2002 - niveau 1 :  14, 15, 21, 22.11.02  (4 jours) LabVIEW - Advanced:  18 - 20.11.02  (3 days) Hands-on Object-Oriented Design and Programming with C++ :  19 - 21.11.02  (3 days)  LabVIEW - Basics 2:  21 - 22.11.02 ...

  6. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : EXCEL 2000 - niveau 1 : 10 & 11.6.03 (2 jours) Conception de PCB rapides dans le flot Cadence : 11.6.03 (matin) EXCEL 2000 - level 1 : 12 & 13.6.03 (2 days) Introduction to PVSS : 16.6.03 (p.m.) Basic PVSS : 17 - 19.6.03 (3 days) Réalisation de PCB rapides dans le flot Cadence : 17.6.03 (matin) PVSS - JCOP Framework Tutorial : 20.6.03 (1 day) EXCEL 2000 - niveau 2 : 24 & 25.6.03 (2 jours) Siemens SIMATIC Training : Introduction to STEP7 : 3 & 4.6.03 (2 jours/2 days) STEP7 Programming : 16 - 20.6.03 (5 jours/5 days) Simatic Net Network : 26 & 27.6.03 (2 jours/2 days) These courses will be given in French or English following the requests. Programmation automate Schneider : Programmation automate Schneider TSX Premium - 1er niveau : 10 - 13.6.03 (4 jours) - audience : toute personne qui veux maitriser la msie en uvre et la programmation d'un automate TSX Premium - objectifs : maitriser la mise en uvre et la programmation d'un autom...

  7. Places available**

    CERN Multimedia

    2003-01-01

    Places are available in the following courses : FrontPage 2000 - niveau 1 : 20 & 21.5.03 (2 jours) PIPES-2003 : Pratique du sertissage de tubes métalliques et multicouches : 21.5.03 (1 jour) Introduction à la CAO Cadence : de la saisie de schéma Concept-HDL au PCB : 20 & 22.5.03 (2 jours) AutoCAD 2002 - niveau 2 : 3 & 4.6.03 (2 jours) AutoCAD Mechanical 6 PowerPack (F) : 5, 6, 12, 13, 26, 27.6.03 (6 jours) EXCEL 2000 - niveau 1 : 10 & 11.6.03 (2 jours) Conception de PCB rapides dans le flot Cadence : 11.6.03 (matin) EXCEL 2000 - level 1 : 12 & 13.6.03 (2 days) PowerPoint 2000 (F) : 17 & 18.6.03 (2 jours) Réalisation de PCB rapides dans le flot Cadence : 17.6.03 (matin) FrontPage 2000 - niveau 2 : 19 & 20.6.03 (2 jours) LabView DSC (langue à décider/language to be defined) : 19 & 20.6.03 EXCEL 2000 - niveau 2 : 24 & 25.6.03 (2 jours) Siemens SIMATIC Training: Introduction to STEP7 : 3 & 4.6.03 (2 days) STEP7 Programming : 16 - 20.6.03 (5 days) Simatic...

  8. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: PVSS Basics : 20 - 24.8.01 (5 days) PROFIBUS : 25 - 26.9.01 (2 jours) PROFIBUS : 27 - 28.9.01 (2 days) PCAD Schémas - débutants : 4 - 5.10.01 (2 jours) PCAD PCB - débutants : 8 - 10.10.01 (3 jours) Programming TSX Premium 1: 15 - 19.10.01 (5 days) Programmation TSX Premium 1 : 22 - 26.10.01 (5 jours) Programming TSX Premium 2: 19 - 23.11.01 (5 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) The following LabView courses will be given in either English or French according to demand LabVIEW - Base 1 / LabVIEW - Basics 1 : 10 - 12.9.01 (3 jours / 3 days) LabVIEW - DAQ / LabVIEW - DAQ : 13 - 14.9.01 (2 jours / 2 days) LabVIEW - Base 1 / LabVIEW - Basics 1 : 15 - 17.10.01 (3 jours / 3 days) LabVIEW - Base 2 / LabVIEW - Basics 2 : 18 - 19.10.01 (2 jours / 2 days) LabVIEW - Base 1 / LabVIEW - Basics 1 : 12 - 14.11.01 (3 jours / 3 days) LabVIEW - DAQ / LabVIEW - DAQ : 15 - 16.11.01 (2 jours / 2...

  9. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Introduction à Windows 2000 au CERN : 2 sessions de _ journée les 24 et 25.9.01 PROFIBUS : 25 - 26.9.01 (2 jours) PROFIBUS : 27 - 28.9.01 (2 days) PowerPoint 2000 : 1 et 2.10.01 (2 jours) EXCEL 2000 - niveau 1 : 3 et 4.10.01 (2 jours) Automates et réseaux de terrain : 3 - 4.10.2001 (2 jours) PCAD Schémas - débutants : 4 - 5.10.01 (2 jours) Introduction à Outlook : 5.10.01 (1 journée) Frontpage 2000 - niveau 1 : 8 et 9.10.01 (2 jours) PCAD PCB - débutants : 8 - 10.10.01 (3 jours) C++ for Particle Physicists : 8 - 12.10.01 (6 3-hour lectures) MS-Project 2000 - niveau 1 : 15 - 18.10.01 (4 demi-journées) LabView Basics 1 :  15 - 17.10.01  (3 days) Programmation TSX Premium 1 : 15 - 19.10.01 (5 jours) WORD 2000 : importer et manipuler des images : 19.10.01 (1 journée) Programmation TSX Premium 1 : 22 - 26.10.01...

  10. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Cadence Board Design tools : Upgrading to release 14 :  3 1-day sessions on 9, 10 & 11.10.01 MS-Project 2000 - niveau 1 : 15 - 18.10.01 (4 demi-journées) LabView Base 2 : 18 & 19.10.01 (2 jours) WORD 2000 : importer et manipuler des images : 19.10.01 (1 journée) Contract Follow-up (F) :  30.10.01 (1/2 journée) The CERN Engineering Data Management System for Electronics Design :  30.10.01 (1 day) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) The Java programming language Level 1: 8 - 9.11.01 (2 days) LabView Base 1 : 12 - 14.11.01 (3 jours) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to XML :  19 - 20.11.01 (2 days) Programming TSX Premium 1 :  19 - 23.11.01  (5 days) Introduction to C Programming :  21- 23.11.01 (3 days) The Java programming language Level 2:  26 - 28.11.01 (...

  11. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Introduction à Windows 2000 au CERN : 2 sessions de _ journée les 24 et 25.9.01 PROFIBUS : 25 - 26.9.01 (2 jours) PROFIBUS : 27 - 28.9.01 (2 days) EXCEL 2000 - niveau 1 : 3 et 4.10.01 (2 jours) Automates et réseaux de terrain : 3 - 4.10.2001 (2 jours) Introduction à Outlook : 5.10.01 (1 journée) Frontpage 2000 - niveau 1 : 8 et 9.10.01 (2 jours) C++ for Particle Physicists : 8 - 12.10.01 (6 lectures) MS-Project 2000 - niveau 1 : 15 - 18.10.01 (4 demi-journées) Programmation TSX Premium 1 : 15 - 19.10.01 (5 jours) WORD 2000 : importer et manipuler des images : 19.10.01 (1 journée) Programmation TSX Premium 1 : 22 - 26.10.01 (5 jours) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) The Java programming language Level 1: 8 - 9.11.01 (2 days) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to XML :  19 - 20.11.01 (2...

  12. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: EXCEL 2000 - niveau 1 : 3 et 4.10.01 (2 jours) Automates et réseaux de terrain : 3 - 4.10.2001 (2 jours) Introduction à Outlook : 5.10.01 (1 journée) C++ for Particle Physicists : 8 - 12.10.01 (6 lectures) Cadence Board Design tools : Upgrading to release 14 : 3 1-day sessions on 9, 10 & 11.10.01 MS-Project 2000 - niveau 1 : 15 - 18.10.01 (4 demi-journées) LabView Base 2 : 18 & 19.10.01 (2 jours) WORD 2000 : importer et manipuler des images : 19.10.01 (1 journée) The CERN Engineering Data Management System for Electronics Design :  30.10.01 (1 day) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) The Java programming language Level 1: 8 - 9.11.01 (2 days) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to XML :  19 - 20.11.01 (2 days) Programming TSX Premium 1 :  19 - 23.11.01  (5 days) Introd...

  13. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: MS-Project 2000 - niveau 1 : 15 - 18.10.01 (4 demi-journées) LabView Base 2 : 18 & 19.10.01 (2 jours) WORD 2000 : importer et manipuler des images : 19.10.01 (1 journée) Contract Follow-up (F) : 30.10.01 (1/2 journée) The CERN Engineering Data Management System for Electronics Design :  30.10.01 (1 day) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) The Java programming language Level 1: 8 - 9.11.01 (2 days) LabView Base 1 : 12 - 14.11.01 (3 jours) Automates et réseaux de terrain : 13 & 14.11.01 (2 jours) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to XML :  19 - 20.11.01 (2 days) Programming TSX Premium 1 :  19 - 23.11.01  (5 days) Introduction to C Programming :  21- 23.11.01 (3 days) The Java programming language Level 2:  26 - 28.11.01 (3 days) Programmation TSX Premium 2 : 26 ...

  14. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: LabView Base 1 :  23 - 25.9.02  (3 jours) Object-Oriented Analysis & Design using UML:  25 - 27.9.02  (3 days) LabView DAQ (E):  26 - 27.9.02  (2 days) Introduction to Oracle 8i : SQL and PL/SQL:  7 - 11.10.02  (5 days) CLEAN-2002 : Working in a Cleanroom (free of charge):  10.10.02  (half-day, p.m.) AutoCAD 2002 - niveau 2 :  14 - 15.10.02  (2 jours) Introduction à DesignSpace :  16.10.02  (1 journée) Introduction to DesignSpace:  17.10.02  (1 day) AutoCAD 2002 - Level 1:  17, 18, 24, 25.10.02  (4 days) AutoCAD Mechanical 6 PowerPack (F) :  21, 22, 23.10 et 4, 5, 6.11.02  (6 jours) Introduction à ANSYS/Introduction to ANSYS (langue à définir suivant demande/ Language to be chosen according to demand):...

  15. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Java 2 Enterprise Edition - Part 2: Enterprise JavaBeans:  18 - 20.9.02  (3 days) AutoCAD 2002 - niveau 1 :  19, 20, 26, 27.9.02  (4 jours) LabView Base 1 :  23 - 25.9.02  (3 jours) Object-Oriented Analysis & Design using UML:  25 - 27.9.02  (3 days) LabView DAQ (E):  26 - 27.9.02  (2 days) Introduction to Oracle 8i : SQL and PL/SQL:  7 - 11.10.02  (5 days) CLEAN-2002 : Working in a Cleanroom (free of charge):  10.10.02  (half-day, p.m.) AutoCAD 2002 - niveau 2 :  14 - 15.10.02  (2 jours) Introduction à DesignSpace :  16.10.02  (1 journée) Introduction to DesignSpace:  17.10.02  (1 day) AutoCAD 2002 - Level 1:  17, 18, 24, 25.10.02  (4 days) AutoCAD Mechanical 6 PowerPack (F) :  21, 22, 23.10 et 4, 5, 6.11....

  16. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Automates et réseaux de terrain : 13 & 14.11.01 (3 jours) Introduction à Windows 2000 au CERN : 12 - 14.11.01 (1/2 journée) Introduction to Windows 2000 at CERN :  14.11.01  (half-day) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Sécurité dans les installations cryogéniques : 21 - 22.11.2001 (2 demi-journées) Introduction to C Programming :  21- 23.11.01 (3 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) Contract Follow-up (F) : 26.11.01 (1/2 journée) Object-Oriented Analysis and Design :  27 - 30.11.2001  (4 days) Introduction to the CERN Engineering Data Management System :  30.11.2001 (1 day) Electromagnetic Compatibility (EMC): Introduction (bilingual) :  3.12.01 (half-day) Introduction to the CERN Engineering Data Management System : 07.12.2001...

  17. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Contract Follow-up (F) : 30.10.01 (1/2 journée) The CERN Engineering Data Management System for Electronics Design :  30.10.01 (1 day) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) Nouveautés d'EXCEL : 5.11.01 (1/2 journée) Introduction a Windows 2000 au CERN : 6.11.01 (1/2 journée) The Java programming language Level 1: 8 - 9.11.01 (2 days) LabView Base 1 : 12 - 14.11.01 (3 jours) Automates et réseaux de terrain : 13 & 14.11.01 (2 jours) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to XML :  19 - 20.11.01 (2 days) Programming TSX Premium 1 :  19 - 23.11.01  (5 days) Introduction to C Programming :  21- 23.11.01 (3 days) The Java programming language Level 2:  26 - 28.11.01 (3 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) Autocad Migration support courses: a detail...

  18. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Contract Follow-up (F) : 30.10.01 (1/2 journée) The CERN Engineering Data Management System for Electronics Design :  30.10.01 (1 day) Nouveautés d'Excel 2000 : 5.11.01 (1/2 journée) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) Introduction à Windows 2000 au CERN : 6.11.01 (1/2 journée) The Java programming language Level 1: 8 - 9.11.01 (2 days) LabView Base 1 : 12 - 14.11.01 (3 jours) LabVIEW DAQ (F) : 15 & 16.11.01 (2 jours) Automates et réseaux de terrain : 13 & 14.11.01 (2 jours) Introduction to PERL 5 :  15 - 16.11.01  (2 days) LabVIEW - DAQ : 15 - 16.11.01 (2 jours) Introduction to XML :  19 - 20.11.01 (2 days) Introduction to C Programming :  21- 23.11.01 (3 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) Object-Oriented Analysis and Design :  27 - 30.11.2001 (4 days) Hands...

  19. PLACES AVAILABLE

    CERN Multimedia

    Technical Training; Tel. 74924

    2001-01-01

    Places are available in the following courses: Nouveautés d'EXCEL : 5.11.01 (1/2 journée) Introduction a Windows 2000 au CERN : 6.11.01 (1/2 journée) UNIX pour non-programmeurs : 5 - 7.11.01 (3 jours) Design Patterns :  7 - 8.11.01 (2 days) The Java programming language Level 1: 8 - 9.11.01 (2 days) Automates et réseaux de terrain : 13 & 14.11.01 (3 jours) Introduction à Windows 2000 au CERN : 12 - 14.11.01 (1/2 journée) Introduction to Windows 2000 at CERN :  14.11.01  (half-day) Introduction to PERL 5 :  15 - 16.11.01  (2 days) Introduction to C Programming :  21- 23.11.01 (3 days) Programmation TSX Premium 2 : 26 - 30.11.01 (5 jours) Contract Follow-up (F) : 26.11.01 (1/2 journée) Object-Oriented Analysis and Design :  27 - 30.11.2001  (4 days) Hands-on Object-Oriented Design and Programming with C++ :  11 - 13.12.2...

  20. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: ELEC-2002 : Spring Term :  9, 11, 16, 18, 23, 25, 30.4.02 (7 * 2.5 hours) Object-Oriented Analysis & Design: 16 - 19.4.02  (4 days) The CERN Engineering Data Management System for Advanced users:  16.4.02  (1 day) Migration from AutoCAD 14 towards AutoCAD Mechanical6 PowerPack:  17 - 19.4 and 2 &3.5.02  (5 days) AutoCAD - niveau 1 : 22, 23, 29, 30.4 et 6, 7.5.02 (6 jours) LabVIEW base 1 : 22 - 24.4.02 (3 jours) CLEAN 2002 : working in a cleanroom:  24.4.02  (half-day, pm) LabVIEW DSC (F) 25 & 26.4.02 (2 jours) AutoCAD : Mise à jour AutoCAD r-14 vers 2002 : 25 & 26.4.02 (2 jours) Cotations selon les normes GPS de l'ISO : 29 - 30.4.02 (2 jours) Introduction to the CERN Engineering Data Management System:  7.5.02  (1 day) LabVIEW Basics 2 : 13 & 14.5.02 (2 days) AutoCAD Mechanical 6 PowerPack (F) : 13-...

  1. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: Introduction to the CERN Engineering Data Management System:  7.5.02  (1 day) LabVIEW Basics 2: 13 & 14.5.02 (2 days) AutoCAD Mechanical 6 PowerPack (F) : 13-14, 17, 21, 27-28.5.02 (6 jours) WorldFIP - Généralités : 14.5.2002 (1/2 journée) WorldFIP - Développer avec MicroFIP HANDLER : 14.5 - après-midi, 15.5.02 - matin (1 jour) WorldFIP - FullFIP FDM : FIP Device Manager (F) : 15.5 - après-midi, 16.5.02 - matin (1 jour) LabVIEW DAQ (F) : 15 & 16.5.02 (2 jours) EXCEL 2000 - niveau 2 : 22 & 23.5.02 (2 jours) The CERN Engineering Data Management System for Advanced users:  30.5.02  (1 day) LabVIEW Basics 1:  3 - 5.6.02  (3 days) AutoCAD 2002 - condensé : 4 - 6.6.02 (3 jours) LabVIEW DAQ (E):  6 & 7.6.02  (2 days) AutoCAD 2002 - Level 1:  10 - ...

  2. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: The CERN Engineering Data Management System for Advanced users : 16.4.02  (1 day) Migration from AutoCAD 14 towards AutoCAD Mechanical6 PowerPack:  17 - 19.4 and 2 &3.5.02  (5 days) AutoCAD - niveau 1 : 22, 23, 29, 30.4 et 6, 7.5.02 (6 jours) LabVIEW base 1 : 22 - 24.4.02 (3 jours) CLEAN 2002 : working in a cleanroom:  24.4.02  (half-day, pm) LabVIEW DSC (F) 25 & 26.4.02 (2 jours) AutoCAD : Mise à jour AutoCAD r-14 vers 2002 : 25 & 26.4.02 (2 jours) Cotations selon les normes GPS de l'ISO : 29 - 30.4.02 (2 jours) Introduction to the CERN Engineering Data Management System:  7.5.02  (1 day) LabVIEW Basics 2: 13 & 14.5.02 (2 days) AutoCAD Mechanical 6 PowerPack (F) : 13-14, 17, 21, 27-28.5.02 (6 jours) WorldFIP - Généralités : 14.5.2002 (1/2 journée) WorldFIP - Développer avec Micr...

  3. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: LabVIEW Basics 2: 13 & 14.5.02 (2 days) WorldFIP - Généralités : 14.5.2002 (1/2 journée) WorldFIP - Développer avec MicroFIP HANDLER : 14.5 - après-midi, 15.5.02 - matin (1 jour) WorldFIP - FullFIP FDM : FIP Device Manager (F) : 15.5 - après-midi, 16.5.02 - matin (1 jour) LabVIEW DAQ (F) : 15 & 16.5.02 (2 jours) EXCEL 2000 - niveau 2 : 22 & 23.5.02 (2 jours) The CERN Engineering Data Management System for Advanced users:  30.5.02  (1 day) LabVIEW Basics 1:  3 - 5.6.02  (3 days) AutoCAD 2002 - condensé : 4 - 6.6.02 (3 jours) LabVIEW DAQ (E):  6 & 7.6.02  (2 days) AutoCAD 2002 - Level 1:  10 - 12 and 24 - 26.6.02  (6 days) If you wish to participate in one of these courses, please discuss with your supervisor and apply electronically directly from the c...

  4. PLACES AVAILABLE

    CERN Multimedia

    Monique Duval

    2002-01-01

    Places are available in the following courses: LabVIEW base 1 : 22 - 24.4.02 (3 jours) CLEAN 2002 : working in a cleanroom:  24.4.02  (half-day, pm) LabVIEW DSC (F) 25 & 26.4.02 (2 jours) AutoCAD : Mise à jour AutoCAD r-14 vers 2002 : 25 & 26.4.02 (2 jours) Cotations selon les normes GPS de l'ISO : 29 - 30.4.02 (2 jours) Introduction to the CERN Engineering Data Management System:  7.5.02  (1 day) LabVIEW Basics 2: 13 & 14.5.02 (2 days) AutoCAD Mechanical 6 PowerPack (F) : 13-14, 17, 21, 27-28.5.02 (6 jours) WorldFIP - Généralités : 14.5.2002 (1/2 journée) WorldFIP - Développer avec MicroFIP HANDLER : 14.5 - après-midi, 15.5.02 - matin (1 jour) WorldFIP - FullFIP FDM : FIP Device Manager (F) : 15.5 - après-midi, 16.5.02 - matin (1 jour) LabVIEW DAQ (F) : 15 & 16.5.02 (2 jours) EXCEL 2000 - niveau 2 : 22 & 23.5.02 (2 jours)...

  5. ‘We are a community [but] that takes a certain amount of energy’: Exploring shared visions, social action, and resilience in place-based community-led energy initiatives

    International Nuclear Information System (INIS)

    Parkhill, K.A.; Shirani, F.; Butler, C.; Henwood, K.L.; Groves, C.; Pidgeon, N.F.

    2015-01-01

    Highlights: • We engage with conceptual characteristics of 3 community-led energy case studies. • We examine data from interviews to explore the issues community energy groups face. • Shared visions, social action and social resilience are important to community energy. • Creating and maintaining shared visions, social action and social resilience is extremely challenging. - Abstract: In UK energy policy, community-led energy initiatives are increasingly being imbued with transformative power to facilitate low carbon transitions. The ways that such expectations for communities are manifesting in practice remains, however, relatively poorly understood. In particular, key conceptual developments in unpacking what constitutes ‘community’ that highlight the significance of ‘place’ along with important characteristics, such as shared visions, collective social action, and resilience, have yet to be comprehensively explored in the context of community-led energy initiatives. This paper uses an interpretive stance to engage with these conceptual ideas about community and provides insights into the nature of community and its meaning for developing energy-related initiatives and realising the wider goals of energy policy. The paper draws on data from in-depth qualitative, longitudinal interviews undertaken in two residential communities and one purely workplace-based community, which are engaged in community energy initiatives. We argue that there are difficulties and ambiguities in creating shared visions, achieving social action, and developing resilience that are related to the specificities of community in place, but that all three characteristics are likely to be important for the making of sustainable places

  6. Alligator Rivers Analogue project. Uranium sorption. Final Report - Volume 13

    International Nuclear Information System (INIS)

    Waite, T.D.; Payne, T.E.; Davis, J.A.; Sekine, K.

    1992-01-01

    In this volume, the results of studies of uranium sorption (adsorption and desorption) to both single, well-defined mineral phases, and to selected natural (Koongarra) substrates are reported. The single phases included the amorphous iron oxide ferrihydrite, crystalline silica and two naturally occurring kaolinites, KGa-1 and Nichika. The surface properties of these materials were rigorously defined, and adsorption studies were conducted over a range of solution pH, ionic strength, carbonate content, adsorbent and adsorbate concentrations, and in the presence of uranium complexants and (potentially) competing adsorbates (such as phosphate and fluoride). The results of these studies were modelled using the 'surface complexation' approach, with a diffuse layer description of the electrical double layer. The impacts of mineral phase transformations (specifically the aging of amorphous ferrihydrite to more crystalline forms) on the uptake and desorption of uranium are also reported. The amount of data obtained in this study, with a number of experimental parameters being varied over a wide range, has enabled more confidence to be placed in the modelling results. The derived model for ferrihydrite adequately accounts for the effect on U sorption of a number of parameters, most notably pH, pCO 2 and total U present. Few (if any) of the models previously proposed are adequate in this respect. While the modelling of the data for the natural substrates is not as advanced, the U sorption data on the natural substrates show similar features to the U sorption on the model substrates. This suggests that the insights obtained in the modelling of the data for ferrihydrite will be valuable in deriving a model for the more complex natural substrates

  7. Alligator Rivers Analogue project. Uranium sorption. Final Report - Volume 13

    Energy Technology Data Exchange (ETDEWEB)

    Waite, T D; Payne, T E [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW (Australia); Davis, J A [United States Geological Survey, Water Resources Division, Menlo Park, CA (United States); Sekine, K [Japan Atomic Energy Research Institute, Tokai-mura, Ibaraki (Japan)

    1993-12-31

    In this volume, the results of studies of uranium sorption (adsorption and desorption) to both single, well-defined mineral phases, and to selected natural (Koongarra) substrates are reported. The single phases included the amorphous iron oxide ferrihydrite, crystalline silica and two naturally occurring kaolinites, KGa-1 and Nichika. The surface properties of these materials were rigorously defined, and adsorption studies were conducted over a range of solution pH, ionic strength, carbonate content, adsorbent and adsorbate concentrations, and in the presence of uranium complexants and (potentially) competing adsorbates (such as phosphate and fluoride). The results of these studies were modelled using the `surface complexation` approach, with a diffuse layer description of the electrical double layer. The impacts of mineral phase transformations (specifically the aging of amorphous ferrihydrite to more crystalline forms) on the uptake and desorption of uranium are also reported. The amount of data obtained in this study, with a number of experimental parameters being varied over a wide range, has enabled more confidence to be placed in the modelling results. The derived model for ferrihydrite adequately accounts for the effect on U sorption of a number of parameters, most notably pH, pCO{sub 2} and total U present. Few (if any) of the models previously proposed are adequate in this respect. While the modelling of the data for the natural substrates is not as advanced, the U sorption data on the natural substrates show similar features to the U sorption on the model substrates. This suggests that the insights obtained in the modelling of the data for ferrihydrite will be valuable in deriving a model for the more complex natural substrates 87 refs., 27 tabs., 56 figs.

  8. Brand new authentic places

    DEFF Research Database (Denmark)

    Stender, Marie

    the relation and interplay between the two. This study strives to fill this gap by ethnographically tracing the process from design to occupancy including the role of branding as a means to create authenticity. The concept of authenticity is often associated with old houses and neighbourhoods, but also in new......How are places and material surroundings ascribed with meaning when new residential neighbourhoods are designed, branded and taken into use? Existing research on housing, neighbourhoods and urban design tends to take the perspective of either the architect or the user rather than to explore...... neighbourhoods stories of authenticity seems to be of great importance giving value and identity to place and people. By way of design and branding new places are implied with notions of the real, the original and the unique referring to e.g. its historical past, architectural uniqueness, sustainability or sense...

  9. Prediction of metal sorption in soils

    International Nuclear Information System (INIS)

    Westrich, Henry R.; Anderson, Harold L. Jr.; Arthur, Sara E.; Brady, Patrick V.; Cygan, Randall T.; Liang, Jianjie; Zhang, Pengchu; Yee, N.

    2000-01-01

    Radionuclide transport in soils and groundwaters is routinely calculated in performance assessment (PA) codes using simplified conceptual models for radionuclide sorption, such as the K D approach for linear and reversible sorption. Model inaccuracies are typically addressed by adding layers of conservativeness (e.g., very low K D 's), and often result in failed transport predictions or substantial increases in site cleanup costs. Realistic assessments of radionuclide transport over a wide range of environmental conditions can proceed only from accurate, mechanistic models of the sorption process. They have focused on the sorption mechanisms and partition coefficients for Cs + , Sr 2+ and Ba 2+ (analogue for Ra 2+ ) onto iron oxides and clay minerals using an integrated approach that includes computer simulations, sorption/desorption measurements, and synchrotron analyses of metal sorbed substrates under geochemically realistic conditions. Sorption of Ba 2+ and Sr 2+ onto smectite is strong, pH-independent, and fully reversible, suggesting that cation exchange at the interlayer basal sites controls the sorption process. Sr 2+ sorbs weakly onto geothite and quartz, and is pH-dependent. Sr 2+ sorption onto a mixture of smectite and goethite, however, is pH- and concentration dependent. The adsorption capacity of montmorillonite is higher than that of goethite, which may be attributed to the high specific surface area and reaction site density of clays. The presence of goethite also appears to control the extent of metal desorption. In-situ, extended X-ray absorption fine structure (EXAFS) spectroscopic measurements for montmorillonite and goethite show that the first shell of adsorbed Ba 2+ is coordinated by 6 oxygens. The second adsorption shell, however, varies with the mineral surface coverage of adsorbed Ba 2+ and the mineral substrate. This suggests that Ba 2+ adsorption on mineral surfaces involves more than one mechanism and that the stability of sorbed

  10. Sorption of fluorescent polystyrene microplastic particles to edible seaweed Fucus vesiculosus

    DEFF Research Database (Denmark)

    Sundbæk, Kasper Bjerrum; Due Würtzner Koch, Ida; Greve Villaro, Clara

    2018-01-01

    .65 mg L−1 (corresponding to 597 particles per mL) in filtrated seawater (50 mL) to treat F. vesiculosus distal tips in blue cap flasks (100 mL) placed in a rotary box for 2 h. Results showed sorption of PS microplastic particles to F. vesiculosus analysed by microscopy and a significant reduction...

  11. Places disponibles/Places available

    CERN Multimedia

    2004-01-01

    Si vous désirez participer à l'un des cours suivants, veuillez en discuter avec votre superviseur et vous inscrire électroniquement en direct depuis les pages de description des cours dans le Web que vous trouvez à l'adresse : http://www.cern.ch/Training/ ou remplissez une « demande de formation » disponible auprès du Secrétariat de votre Division ou de votre DTO (Délégué divisionnaire à la formation). Les places seront attribuées dans l'ordre de réception des inscriptions. If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an "application for training" form available from your Divisional Secretariat or from your DTO (Divisional Training Off...

  12. Sorption behavior of cesium onto bentonite colloid

    International Nuclear Information System (INIS)

    Iijima, Kazuki; Masuda, Tsuguya; Tomura, Tsutomu

    2004-01-01

    It is considered that bentonite colloid might be generated from bentonite which will be used as buffer material in geological disposal system, and can facilitate the migration of radionuclides by means of sorption. In order to examine this characteristic, sorption and desorption experiments of Cs onto bentonite colloid were carried out to obtain its distribution coefficient (Kd) and information on the reversibility of its sorption. In addition, particle size distribution and shape of colloid were investigated and their effect on the sorption behavior was discussed. Kds for Cs were around 20 m 3 /kg for sorption and 30 m 3 /kg for desorption, in which sorbed Cs was desorbed by 8.4x10 -4 mol/l of NaCl solution. These values did not show any dependencies on Cs concentration and duration of sorption and desorption. The first 20% of sorbed Cs was desorbed reversibly at least. Most of colloidal particles were larger than 200 nm and TEM micrographs showed they had only several sheets of the clay crystal. Obtained Kds for colloidal bentonite were larger than those for powdered bentonite. This can be caused by difference of competing ions in the solution, characteristics of contained smectite, or sorption site density. (author)

  13. Sorption of uranyl ions on hydrous oxides

    International Nuclear Information System (INIS)

    Gupta, A.R.; Venkataramani, B.

    1988-01-01

    Sorption of uranyl ions on hydrous titanium oxide (HTiO), magnetite (MAG), and hydrous thorium oxide (HThO) has been studied as a function of pH. Hydrous oxides have been characterized by their pH-titration curves, intrinsic dissociation constants (pK ai * ) and point of zero charge (pH pzc ). The fraction of protonated surface hydroxyl groups as well as the surface pH (pH surf ) as a function of solution pH have been computed. The distribution of various hydrolyzed species of uranyl ions with solution pH have been compared with uranyl sorption isotherm on these oxides. Sorption edge in all the cases occurs when free hydroxyl groups are available on the surface and pH surf is sufficiently high to favor the formation of dimer-like species on the surface. A new model for the sorption process, called surface hydrolysis model, which explains these and other features of uranyl sorption on hydrous oxides has been proposed. The model visualizes the sorption process as linking of uranyl ions with two adjacent free surface hydroxyl groups without deprotonation (provided the surface pH is high for the hydrolysis of uranyl ions) and formation of dimer-like structures on the surface. The new model has been successfully applied to the present and other available data on uranyl ion sorption on hydrous oxides. (author)

  14. Sorption equilibria of ethanol on cork.

    Science.gov (United States)

    Lequin, Sonia; Chassagne, David; Karbowiak, Thomas; Bellat, Jean-Pierre

    2013-06-05

    We report here for the first time a thermodynamic study of gaseous ethanol sorption on raw cork powder and plate. Our study aims at a better understanding of the reactivity of this material when used as a stopper under enological conditions, thus in close contact with a hydroethanolic solution, wine. Sorption−desorption isotherms were accurately measured by thermogravimetry at 298 K in a large range of relative pressures. Sorption enthalpies were determined by calorimetry as a function of loading. Sorption−desorption isotherms exhibit a hysteresis loop probably due to the swelling of the material and the absorption of ethanol. Surprisingly, the sorption enthalpy of ethanol becomes lower than the liquefaction enthalpy as the filling increases. This result could be attributed to the swelling of the material, which would generate endothermic effects. Sorption of SO₂ on cork containing ethanol was also studied. When the ethanol content in cork is 2 wt %, the amount of SO₂ sorbed is divided by 2. Thus, ethanol does not enhance the sorption rate for SO₂ but, on the contrary, decreases the SO₂ sorption activity onto cork, probably because of competitive sorption mechanisms.

  15. Sorption of streptococcus faecium to glass

    International Nuclear Information System (INIS)

    Oerstavik, D.

    1977-01-01

    A method has been developed by which to study the sorption of Streptococcus faecium to soda-lime cover glasses. Conditions were chosen to minimize the influence on sorption of bacterial polymer production, passive sorption being studied rather than attachment mediated by metabolic activities. Sorption of S. faecium increased with increasing temperature (to 50degC), time, and cell concentration, but equilibrium apparently was not reached even after incubation for 8 hours or at a cell concentration of 3 x 10 10 per ml. Sorption increased with solute molarity up to 0.1 M concentration of NaCl and KCl, indicating an effect of the electrical double layers on the apposition of cells to the glass surface. Desorption of bacteria could be obtained after multiple washings of the glasses in buffer or by the action of Tween 80, but not if sorbed bacteria were left in distilled water, various salt solutions, urea, or in suspensions of unlabelled bacteria. It was concluded that sorption occurred as a result of chemical interactions between the glass and the cell surface. Tween 80 at a concentration of 1 per cent inhibited sorption to 26 per cent of buffer controls, 2 M urea was less effective, and 1 M NaCl was without effect. It is suggested that hydrophobic interactions may be of importance in the binding of S. faecium to glass. (author)

  16. Heavy metal sorption by microalgae

    International Nuclear Information System (INIS)

    Sandau, E.; Sandau, P.; Pulz, O.

    1996-01-01

    Viable microalgae are known to be able to accumulate heavy metals (bioaccumulation). Against a background of the increasing environmental risks caused by heavy metals, the microalgae Chlorella vulgaris and Spirulina platensis and their potential for the biological removal of heavy metals from aqueous solutions were taken as an example for investigation. Small-scale cultivation tests (50 l) with Cd-resistant cells of Chlorella vulgaris have shown that approx. 40% of the added 10 mg Cd/l was removed from the solution within seven days. At this heavy metal concentration sensitive cells died. Non-viable microalgae are able to eliminate heavy metal ions in a short time by biosorption in uncomplicated systems, without any toxicity problems. Compared with original biomasses, the sorption capacity of microalgal by-products changes only insignificantly. Their low price makes them economical. (orig.)

  17. Metal Sorption to Dolomite Surfaces

    International Nuclear Information System (INIS)

    Brady, P.V.; Papenguth, H.W.; Kelly, J.W.

    1999-01-01

    Potential human intrusion into the Waste Isolation Pilot Plant (WIPP) might release actinides into the Culebra Dolomite where sorption reactions will affect of radiotoxicity from the repository. Using a limited residence time reactor the authors have measured Ca, Mg, Nd adsorption/exchange as a function of ionic strength, P CO2 , and pH at 25 C. By the same approach, but using as input radioactive tracers, adsorption/exchange of Am, Pu, U, and Np on dolomite were measured as a function of ionic strength, P CO2 , and pH at 25 C. Metal adsorption is typically favored at high pH. Calcium and Mg adsorb in near-stoichiometric proportions except at high pH. Adsorption of Ca and Mg is diminished at high ionic strengths (e.g., 0.5M NaCl) pointing to association of Na + with the dolomite surface, and the possibility that Ca and Mg sorb as hydrated, outer-sphere complexes. Sulfate amplifies sorption of Ca and Mg, and possibly Nd as well. Exchange of Nd for surface Ca is favored at high pH, and when Ca levels are low. Exchange for Ca appears to control attachment of actinides to dolomite as well, and high levels of Ca 2+ in solution will decrease Kds. At the same time, to the extent that high P CO2 increase Ca 2+ levels, JK d s will decrease with CO 2 levels as well, but only if sorbing actinide-carbonate complexes are not observed to form (Am-carbonate complexes appear to sorb; Pu-complexes might sorb as well; U-carbonate complexation leads to desorption). This indirect CO 2 effect is observed primarily at, and above, neutral pH. High NaCl levels do not appear to affect to actinide K d s

  18. Sorption of methylxanthines by different sorbents

    Science.gov (United States)

    Dmitrienko, S. G.; Andreeva, E. Yu.; Tolmacheva, V. V.; Terent'eva, E. A.

    2013-05-01

    Sorption of caffeine, theophylline, theobromine, diprophylline, and pentoxyphylline on different sorbents (supercross-linked polystyrene, surface-modified copolymer of styrene and divinylbenzene Strata-X, and carbon nanomaterials Taunit and Diasorb-100-C16T) was studied in a static mode in an effort to find new sorbents suitable for sorption isolation and concentration of methylxanthines. The peculiarities of sorption of methylxanthines were explained in relation to the solution acidity, the nature of the sorbates and their concentration, the nature of the solvent, and the structural characteristics of the sorbents.

  19. Sorption isolation of strontium from seawater

    International Nuclear Information System (INIS)

    Avramenko, V.A.; Zheleznov, V.V.; Kaplun, E.V.; Sokol'nitskaya, T.A.; Yukhkam, A.A.

    2001-01-01

    Sorption isolation of strontium from seawater is considered and prospects of use of selective adsorbents for purification of seawater or liquid radioactive wastes mixed with seawater from 90 Sr are discussed. Comparative analysis of sorptive properties of adsorbents of different nature is done. It is shown that sorption-reagent materials developed by authors can to afford effective separation of 90 Sr from seawater. Possible mechanism of strontium sorption by these adsorbents is considered. The prospect of their use for purification of liquid radioactive wastes from strontium is shown [ru

  20. What is taking place in science classrooms?: A case study analysis of teaching and learning in seventh-grade science of one Alabama school and its impact on African American student learning

    Science.gov (United States)

    Norman, Lashaunda Renea

    This qualitative case study investigated the teaching strategies that improve science learning of African American students. This research study further sought the extent the identified teaching strategies that are used to improve African American science learning reflect culturally responsive teaching. Best teaching strategies and culturally responsive teaching have been researched, but there has been minimal research on the impact that both have on science learning, with an emphasis on the African American population. Consequently, the Black-White achievement gap in science persists. The findings revealed the following teaching strategies have a positive impact on African American science learning: (a) lecture-discussion, (b) notetaking, (c) reading strategies, (d) graphic organizers, (e) hands-on activities, (f) laboratory experiences, and (g) cooperative learning. Culturally responsive teaching strategies were evident in the seventh-grade science classrooms observed. Seven themes emerged from this research data: (1) The participating teachers based their research-based teaching strategies used in the classroom on all of the students' learning styles, abilities, attitudes towards science, and motivational levels about learning science, with no emphasis on the African American student population; (2) The participating teachers taught the state content standards simultaneously using the same instructional model daily, incorporating other content areas when possible; (3) The participating African American students believed their seventh-grade science teachers used a variety of teaching strategies to ensure science learning took place, that science learning was fun, and that science learning was engaging; (4) The participating African American students genuinely liked their teacher; (5) The participating African American students revealed high self-efficacy; (6) The African American student participants' parents value education and moved to Success Middle School

  1. PCB congener sorption to carbonaceous sediment components: Macroscopic comparison and characterization of sorption kinetics and mechanism

    International Nuclear Information System (INIS)

    Choi, Hyeok; Al-Abed, Souhail R.

    2009-01-01

    Sorption of polychlorinated biphenyls (PCBs) to sediment is a key process in determining their mobility, bioavailability, and chemical decomposition in aquatic environments. In order to examine the validity of currently used interpretation approaches for PCBs sorption, comparative results on 2-chlorobiphenyl sorption to carbonaceous components in sediments (activated carbon, carbon black, coal, soot, graphite, flyash, wood) were macroscopically correlated with the structural, morphological, crystallographic, and compositional properties of the carbonaceous components. Since the Freundlich sorption constant, K F (L kg -1 ) spanned several orders of magnitude, ranging from log K F of 6.13-5.27 for activated carbon, 5.04 for carbon black, 3.83 for coal to 3.08 for wood, organic carbon partitioning approach should be more specifically categorized, considering the various forms, nature and origins of organic carbon in sediment. Sorption rate constants and fraction parameters, which were numerically defined from empirical kinetic model with fast and slow sorption fractions, were closely related to the physicochemical properties of the carbonaceous components. Sorption interpretation approaches with a specific property and viewpoint, such as organic carbon partitioning, soot carbon distribution, or surface area correlation, did not properly explain the overall results on sorption capacity, fast and slow sorption kinetics, and partitioning coefficient. It is also important to emphasize the heterogeneous nature of sediment and the difficulties of encompassing the partitioning among its carbonaceous components.

  2. PCB congener sorption to carbonaceous sediment components: Macroscopic comparison and characterization of sorption kinetics and mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Hyeok [National Risk Management Research Laboratory, U.S. Environmental Protection Agency, 26 West Martin Luther King Drive, Cincinnati, OH 45268 (United States); Al-Abed, Souhail R., E-mail: al-abed.souhail@epa.gov [National Risk Management Research Laboratory, U.S. Environmental Protection Agency, 26 West Martin Luther King Drive, Cincinnati, OH 45268 (United States)

    2009-06-15

    Sorption of polychlorinated biphenyls (PCBs) to sediment is a key process in determining their mobility, bioavailability, and chemical decomposition in aquatic environments. In order to examine the validity of currently used interpretation approaches for PCBs sorption, comparative results on 2-chlorobiphenyl sorption to carbonaceous components in sediments (activated carbon, carbon black, coal, soot, graphite, flyash, wood) were macroscopically correlated with the structural, morphological, crystallographic, and compositional properties of the carbonaceous components. Since the Freundlich sorption constant, K{sub F} (L kg{sup -1}) spanned several orders of magnitude, ranging from log K{sub F} of 6.13-5.27 for activated carbon, 5.04 for carbon black, 3.83 for coal to 3.08 for wood, organic carbon partitioning approach should be more specifically categorized, considering the various forms, nature and origins of organic carbon in sediment. Sorption rate constants and fraction parameters, which were numerically defined from empirical kinetic model with fast and slow sorption fractions, were closely related to the physicochemical properties of the carbonaceous components. Sorption interpretation approaches with a specific property and viewpoint, such as organic carbon partitioning, soot carbon distribution, or surface area correlation, did not properly explain the overall results on sorption capacity, fast and slow sorption kinetics, and partitioning coefficient. It is also important to emphasize the heterogeneous nature of sediment and the difficulties of encompassing the partitioning among its carbonaceous components.

  3. Carbon dioxide sorption on EDTA modified halloysite

    Directory of Open Access Journals (Sweden)

    Waszczuk Patrycja

    2016-01-01

    Full Text Available In this paper the sorption study of CO2 on EDTA surface modified halloysite was conducted. In the paper chemical modification of halloysite from the Dunino deposit (Poland and its influence on sorption of CO2 are presented. A halloysite samples were washed with water-EDTA 1% solution, centrifuged to separate liquid and impurities and dried. The samples were tested for the sorption capacity using a manometric method with pressure up to 3 MPa. A Langmuir adsorption model was fitted to the data. The results showed that EDTA had a limited effect on the increase of sorption potential at low pressure and the samples exhibited similar results to that ones treated solely with the water solution.

  4. Sorption of metaldehyde using granular activated carbon

    Directory of Open Access Journals (Sweden)

    S. Salvestrini

    2017-09-01

    Full Text Available In this work, the ability of granular activated carbon (GAC to sorb metaldehyde was evaluated. The kinetic data could be described by an intra-particle diffusion model, which indicated that the porosity of the sorbent strongly influenced the rate of sorption. The analysis of the equilibrium sorption data revealed that ionic strength and temperature did not play any significant role in the metaldehyde uptake. The sorption isotherms were successfully predicted by the Freundlich model. The GAC used in this paper exhibited a higher affinity and sorption capacity for metaldehyde with respect to other GACs studied in previous works, probably as a result of its higher specific surface area and high point of zero charge.

  5. Study of sorption of technetium on pyrrhotine

    International Nuclear Information System (INIS)

    Shen Dong; Fan Xianhua; Su Xiguang; Zeng Jishu

    2001-01-01

    The sorption behaviors of technetium on pyrrhotine are studied with batch experiment and dilute sulfuric acid is used to dissolve the technetium adsorbed on pyrrhotine. Sorption and desorption experiment are performed under aerobic and anaerobic conditions (inert gas box). The results show that a significant sorption of technetium on pyrrhotine is found under aerobic and anaerobic conditions, and the sorption on the mineral is supposed to be due to the reduction of TcO 4 - to insoluble TcO 2 ·nH 2 O. Desorption process of the sorbed technetium into dilute sulfuric acid is found to be different under aerobic and anaerobic conditions. On addition of H 2 O 2 to the leach solution a sudden increase of the technetium concentration is observed

  6. Radionuclide sorption on granitic drill core material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Locklund, B.

    1987-11-01

    Distribution ratios were determined for Sr-85, Cs-134 and Eu-152 on crushed granite and fissure coating/filling material from Stripa mines. Measurements were also carried out on intact fissure surfaces. The experimental data for Sr-85, Cs-134 on crushed material can be accomodated by a sorption model based on the assumption that the crushed material consists of porous spheres with outer and inner surfaces available for sorption. In the case of Eu-152 only sorption on the outer surfaces of the crushed material was observed. The absence of sorption on inner surfaces is most probably due to high depletion of the more strongly sorbed Eu-152 in the water phase and very low diffusivity of Eu-152 in the sorbed state. (orig./HP)

  7. Sorption of heteropoly acids by polyurethane foam

    International Nuclear Information System (INIS)

    Dmitreinko, S.G.; Goncharova, L.V.; Runov, V.K.; Zakharov, V.N.; Aslanova, L.A.

    1997-01-01

    Sorption of oxidized and reduced forms of molybdosilicic, molybdophosphoric and molybdovanadophosphoric acids by polyurethane foam based on ethers and esters is studied. On the basis of sorption dependence on solution pH, polyurethane foam type and spectral characteristics of sorbates the suggestion has been made that in the polyurethane foam phase there are two main types of sorbent-sorbate interaction: electrostatic (ion-ion) and with hydrogen bond formation: and it is impossible to determine the contribution of every interaction

  8. Sorption of organophosphate esters by carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Wei; Yan, Li [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Duan, Jinming [School of Environmental and Municipal Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Jing, Chuanyong, E-mail: cyjing@rcees.ac.cn [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China)

    2014-05-01

    Graphical abstract: The interfacial interactions between the OPE molecules and CNTs. - Highlights: • Oxygen-containing groups on CNTs change the sorption property for OPEs. • Molecular configuration of OPEs has insignificant impact on their sorption. • Hydrophobic, π–π EDA and Brønsted acid–base interaction occurred between the CNTs and OPEs. - Abstract: Insights from the molecular-level mechanism of sorption of organophosphate esters (OPEs) on carbon nanotubes (CNTs) can further our understanding of the fate and transport of OPEs in the environment. The motivation for our study was to explore the sorption process of OPEs on multi-walled CNTs (MWCNTs), single-walled CNTs (SWCNTs) and their oxidized counterparts (O-MWCNTs and O-SWCNTs), and its molecular mechanism over a wide concentration range. The sorption isotherm results revealed that the hydrophobicity of OPEs dominated their affinities on a given CNT and the π–π electron donor–acceptor (EDA) interaction also played an important role in the sorption of aromatic OPEs. This π–π EDA interaction, verified with Raman and FT-IR spectroscopy, could restrict the radial vibration of SWCNTs and affect the deformation vibration γ(CH) bands of OPE molecules. The OPE surface coverage on CNTs, estimated using the nonlinear Dubinin–Ashtakhov model, indicated that the oxygen-containing functional groups on CNTs could interact with water molecules by H-bonding, resulting in a decrease in effective sorption sites. In addition, FTIR analysis also confirmed the occurrence of Brønsted acid–base interactions between OPEs and surface OH groups of SWCNTs. Our results should provide mechanistic insights into the sorption mechanism of OPE contaminants on CNTs.

  9. Sorption of fomesafen in Brazilian soils

    OpenAIRE

    Silva,G.R.; D'Antonino,L.; Faustino,L.A.; Silva,A.A.; Ferreira,F.A.; Texeira,C.C.

    2013-01-01

    The study of the dynamics of a herbicide in the soil focus on the interactions with environmental components to obtain agronomic efficiency, ensuring selectivity to the culture and risk reduction of environmental impact. This study evaluated the sorption process of fomesafen in the Brazilian soils Ultisol, Cambisol, and Organosol. Besides soil, washed sand was used as an inert material for determination of the sorption ratio of fomesafen in the soil. The bioassay method was applied, using Sor...

  10. Take heart!

    CERN Multimedia

    Alizée Dauvergne

    2010-01-01

    Recently, ten new semi-automatic defibrillators were installed at various locations around CERN. This is a preventive measure intended to provide cardiac arrest victims with the best possible response. The first responder could be you!   The Director-General has welcomed the initiative of the Medical Service and Fire Brigade for the installation of ten new semi-automatic defibrillators. You have probably seen them on your way to the restaurant, for example:  brand new semi-automatic defibrillators, ready for an emergency. Housed in a white wall-mounted case, the bright red defibrillators are marked with a white heart symbol crossed by a lightning bolt (see photo). The defibrillator is designed so that anyone can use it. “Anyone can use it, you don’t need to be a health professional,” says Dr Reymond from CERN's Medical Service. Together with the CERN Fire Brigade, he is behind the initiative to have these units put in place. And with good reason, as the unit...

  11. Taking Leave?

    CERN Multimedia

    2000-01-01

    Planning a holiday? Then if you're a member of the personnel, you'll need to use the Laboratory's new leave system that will be put in place on 1 October. Leave allocations don't change - you are entitled to just as much holiday as before - but instead of being credited annually, your leave will be credited on a monthly basis, and this information will be communicated on your salary slip. The reason for the change is that with the various new leave schemes such as Recruitment by Saved Leave (RSL) and the Progressive Retirement Programme (PRP), a streamlined procedure was required for dealing with all kinds of leave. In the new system, each member of the personnel will have leave accounts to which leave will be credited monthly from the payroll and debited each time an absence is registered in the CERN Electronic Document Handling system (EDH). Leave balances will appear on monthly pay slips, and full details of leave transactions and balances will be available through EDH at all times. As the leave will be c...

  12. Iodine sorption by microwave irradiated hydrotalcites

    Energy Technology Data Exchange (ETDEWEB)

    Paredes, S.P. [Universidad Autonoma de Puebla, Facultad de Ciencias Quimicas, C.P. 72570, Puebla, Pue (Mexico); Instituto Politecnico Nacional, ESIQIE, C.P. 07738, Mexico, D.F. (Mexico); Fetter, G. [Universidad Autonoma de Puebla, Facultad de Ciencias Quimicas, C.P. 72570, Puebla, Pue (Mexico)]. E-mail: geolarfetter@yahoo.com.mx; Bosch, P. [Universidad Nacional Autonoma de Mexico, Instituto de Investigaciones en Materiales, C.P. 04510, Mexico, D.F. (Mexico); Bulbulian, S. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, C.P. 11801, Mexico, D.F. (Mexico)

    2006-12-15

    Mg-Al hydrotalcite-like compounds (HT) were prepared by the microwave method on the one hand with ethoxide-acetylacetonate and on the other with acetylacetonate as precursors. They presented a maximum sorption capacity of 2.179 and 1.517 meq of {sup 131}I{sup -}/g of hydrotalcite respectively. When the hydrotalcites were calcined and rehydrated in a {sup 131}I{sup -} solution, iodine sorption decreased in both samples to 1.515 and 1.446, respectively. The corresponding value for nitrated hydrotalcite which was prepared by the conventional method for comparison purposes, was 0.570. The radionuclide content in hydrotalcites was determined by {gamma}-spectrometry. {sup 131}I{sup -} sorption is dependent on two main parameters: one is the type of the interlayer organic material and the second the surface area. It was found that hydrotalcites prepared with ethoxide-acetylacetonate were better sorbents for {sup 131}I{sup -} than those with acetylacetonate. Still, if the specific surface area increased, {sup 131}I{sup -}sorption increased as well; nitrated HT resulted in low specific surface area and a low sorption capacity. It is, therefore, concluded that organic residues present in the samples prepared by the microwave method favor the sorption of radioactive anions, in particular {sup 131}I{sup -} if compared with nitrated and/or carbonate interlayered hydrotalcites.

  13. Migration and sorption phenomena in packaged foods.

    Science.gov (United States)

    Gnanasekharan, V; Floros, J D

    1997-10-01

    Rapidly developing analytical capabilities and continuously evolving stringent regulations have made food/package interactions a subject of intense research. This article focuses on: (1) the migration of package components such as oligomers and monomers, processing aids, additives, and residual reactants in to packaged foods, and (2) sorption of food components such as flavors, lipids, and moisture into packages. Principles of diffusion and thermodynamics are utilized to describe the mathematics of migration and sorption. Mathematical models are developed from first principles, and their applicability is illustrated using numerical simulations and published data. Simulations indicate that available models are system (polymer-penetrant) specific. Furthermore, some models best describe the early stages of migration/sorption, whereas others should be used for the late stages of these phenomena. Migration- and/or sorption-related problems with respect to glass, metal, paper-based and polymeric packaging materials are discussed, and their importance is illustrated using published examples. The effects of migrating and absorbed components on food safety, quality, and the environment are presented for various foods and packaging materials. The impact of currently popular packaging techniques such as microwavable, ovenable, and retortable packaging on migration and sorption are discussed with examples. Analytical techniques for investigating migration and sorption phenomena in food packaging are critically reviewed, with special emphasis on the use and characteristics of food-simulating liquids (FSLs). Finally, domestic and international regulations concerning migration in packaged foods, and their impact on food packaging is briefly presented.

  14. Sorption of ferrous iron by EPS from the acidophilic bacterium Acidiphilium Sp.: A mechanism proposal

    Energy Technology Data Exchange (ETDEWEB)

    Tapia, J.M.; MuNoz, J.; Gonzlez, F.; Blazquez, M.L.; Ballester, A.

    2016-07-01

    The aim of this work was to assess the uptake of Fe(II) by extracellular polymeric substances (EPS) from the acidophilic bacterium Acidiphillium 3.2Sup(5). These EPS were extracted using EDTA. EPS of A. 3.2Sup(5) loaded in sorption tests with Fe(II), were characterized using the following experimental techniques: scanning electron microscopy (SEM) with energy dispersive X-ray microanalysis (EDX), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The experimental results indicate that EPS adsorb ferrous iron according to Freundlich model with a metal sorption uptake of K = 1.14 mg1−1/n L1/n g−1 and a sorption intensity of 1/n = 1.26. In addition, ferrous iron sorption by EPS took place by preferential interaction with the carboxyl group which promotes the formation of ferrous iron oxalates (FeC2O4). Since the interaction reaction was reversible (Log K = 0.77 ± 0.33), that means that the cation sorption can be reversed at convenience. (Author)

  15. Sorption of Eu(III) on Pseudomonas fluorescens in the presence of citric acid

    International Nuclear Information System (INIS)

    Suzuki, Yoshinori; Tsushima, Satoru; Yamamoto, Ichiro; Nankawa, Takuya; Yoshida, Takahiro; Ozaki, Takuo; Ohnuki, Toshihiko; Francis, Arokiasamy J.; Enokida, Youichi

    2005-01-01

    We studied the sorption of Eu(III) on Pseudomonas fluorescens in the absence and presence of citric acid by a batch method. The cells were placed in a solution containing 2 μM of Eu(III) and 0, 100, or 1000 μM of citric acid at pH 3 9 for 5 hours. In the absence of citric acid, almost 100% of Eu(III) was sorbed on P. fluorescens at pHs below 7; above 7, sorption decreased with an increase in pH. The time course of Eu(III) sorption on P. fluorescens showed that a fraction of it was desorbed into the solution at alkaline pHs, suggesting that the bacterium may release some exudates. With citric acid present, we found that at higher concentrations there was lower sorption of Eu(III), reflecting the formation of Eu(III)-citrate complexes with the Eu(III)-cell-surface complexes. This decrease in Eu(III) sorption was significant in alkaline pHs. These findings suggest that citric acid which is ubiquitously found in the environment enhances migration of trivalent actinides in the alkaline environment. (author)

  16. Studies of the effects of organic materials on the sorption of uranium and plutonium

    International Nuclear Information System (INIS)

    Berry, J.A.; Bond, K.A.; Ferguson, D.R.; Pilkington, N.J.

    1989-10-01

    The effects of the presence of cellulosic degradation products on the sorption of uranium and plutonium on London clay and Caithness flagstones have been studied using the batch sorption method. Experimental conditions were chosen to simulate both those expected close to a cementitious repository (pH ∼ 11) and at the edge of the zone of migration of the calcium plume (pH ∼ 8). Work was carried out (i) under baseline conditions, in the absence of organic materials (ii) with gluconate, acting as a well-characterised simulant (iii) with authentic degradation products. These experimental studies are complemented by thermodynamic modelling work, the results of which are presented in a companion paper. The results have shown that organic degradation products can have a marked effect on sorption and the present work provides further evidence of the need to take account of the presence of such materials in safety assessment modelling. (author)

  17. Influence of sorption competition on sorption data for MX-80 bentonite used in performance assessment

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.; Marques Fernandes, M.

    2012-01-01

    Document available in extended abstract form only. In order to obtain a (quasi) mechanistic understanding of radionuclide uptake on clay minerals and argillaceous rocks, the majority of sorption experiments have been carried out on purified clay minerals such as montmorillonite and illite at trace concentrations (sorption edges), or as a function of concentration (sorption isotherms), with a single radionuclide under well-defined conditions in simple background electrolytes. As a result of such studies the 2 site proto-lysis non electrostatic surface complexation cation exchange (2SPNE SC/CE) sorption model, was developed and has been successfully applied to quantitatively describe the uptake of numerous radionuclides of differing valences as a function of pH and concentration on montmorillonite. In a deep geological repository for high level waste, stable impurities arise from many sources: they are present in the pore waters, in the tunnel back fill materials and host rock formations, they arise from the corrosion of the carbon steel canister and finally they are dissolved from the spent fuel and vitrified high level waste simultaneously with the radionuclides. These impurities, which are an integral part of a realistic repository system, can potentially compete with radionuclides for the sorption sites on the backfill materials and host rock and thus reduce their uptake on them. The influence of competitive sorption is not intrinsically included (or only partly so) in the sorption model. It is clearly an inherently important issue to quantify the influence of sorption competition on the transport of released radionuclides through the multi-barrier system in a deep repository. In this study an extreme case of a competitive sorption scenario in the near field of a HLW repository is presented. Two factors are considered: one associated with the high concentrations and the other with competitive sorption effects. The tendency in both cases is to cause a reduction in

  18. Influence of soil properties on vapor-phase sorption of trichloroethylene

    International Nuclear Information System (INIS)

    Bekele, Dawit N.; Naidu, Ravi; Chadalavada, Sreenivasulu

    2016-01-01

    Highlights: • Vapor intrusion is a major exposure pathway for volatile hydrocarbons. • Certainty in transport processes enhances vapor intrusion model precision. • Detailed understanding of vadose zone vapor transport processes save resources. • Vapor sorption near-steady-state conditions at sites may take months or years. • Type of clay fractions equitably affects sorption of trichloroethylene vapor. - Abstract: Current practices in health risk assessment from vapor intrusion (VI) using mathematical models are based on assumptions that the subsurface sorption equilibrium is attained. The time required for sorption to reach near-steady-state conditions at sites may take months or years to achieve. This study investigated the vapor phase attenuation of trichloroethylene (TCE) in five soils varying widely in clay and organic matter content using repacked columns. The primary indicators of TCE sorption were vapor retardation rate (R_t), the time required for the TCE vapor to pass through the soil column, and specific volume of retention (V_R), and total volume of TCE retained in soil. Results show TCE vapor retardation is mainly due to the rapid partitioning of the compound to SOM. However, the specific volume of retention of clayey soils with secondary mineral particles was higher. Linear regression analyses of the SOM and clay fraction with V_R show that a unit increase in clay fraction results in higher sorption of TCE (V_R) than the SOM. However, partitioning of TCE vapor was not consistent with the samples' surface areas but was mainly a function of the type of secondary minerals present in soils.

  19. Influence of soil properties on vapor-phase sorption of trichloroethylene

    Energy Technology Data Exchange (ETDEWEB)

    Bekele, Dawit N. [Global Center for Environmental Remediation, University of Newcastle, Callaghan, NSW 2308 (Australia); CRC for Contamination Assessment & Remediation of the Environment, Building X (Environmental Sciences Building), University of South Australia, Mawson Lakes, SA 5095 (Australia); Naidu, Ravi, E-mail: Ravi.Naidu@newcastle.edu.au [Global Center for Environmental Remediation, University of Newcastle, Callaghan, NSW 2308 (Australia); CRC for Contamination Assessment & Remediation of the Environment, Building X (Environmental Sciences Building), University of South Australia, Mawson Lakes, SA 5095 (Australia); Chadalavada, Sreenivasulu [Global Center for Environmental Remediation, University of Newcastle, Callaghan, NSW 2308 (Australia); CRC for Contamination Assessment & Remediation of the Environment, Building X (Environmental Sciences Building), University of South Australia, Mawson Lakes, SA 5095 (Australia)

    2016-04-05

    Highlights: • Vapor intrusion is a major exposure pathway for volatile hydrocarbons. • Certainty in transport processes enhances vapor intrusion model precision. • Detailed understanding of vadose zone vapor transport processes save resources. • Vapor sorption near-steady-state conditions at sites may take months or years. • Type of clay fractions equitably affects sorption of trichloroethylene vapor. - Abstract: Current practices in health risk assessment from vapor intrusion (VI) using mathematical models are based on assumptions that the subsurface sorption equilibrium is attained. The time required for sorption to reach near-steady-state conditions at sites may take months or years to achieve. This study investigated the vapor phase attenuation of trichloroethylene (TCE) in five soils varying widely in clay and organic matter content using repacked columns. The primary indicators of TCE sorption were vapor retardation rate (R{sub t}), the time required for the TCE vapor to pass through the soil column, and specific volume of retention (V{sub R}), and total volume of TCE retained in soil. Results show TCE vapor retardation is mainly due to the rapid partitioning of the compound to SOM. However, the specific volume of retention of clayey soils with secondary mineral particles was higher. Linear regression analyses of the SOM and clay fraction with V{sub R} show that a unit increase in clay fraction results in higher sorption of TCE (V{sub R}) than the SOM. However, partitioning of TCE vapor was not consistent with the samples' surface areas but was mainly a function of the type of secondary minerals present in soils.

  20. Radionuclides sorption in clay soils

    International Nuclear Information System (INIS)

    Siraky, G.; Lewis, C.; Hamlat, S.; Nollmann, C.E.

    1987-01-01

    The sorption behaviour of clay soils is examined through a parametric study of the distribution coefficient (Kd) for the radionuclides of interest, Cs and Sr. This work is a preliminary stage of the migration studies of these nuclides in a porous medium (ground of Ezeiza, Argentina) and the evaluation of radiologic impact of the removal of low and intermediate activity wastes in shallow trenches. The determination of Kd is performed by a static technique or batch. The phases are separated by centrifugation at 20000 g during 1 hour. The activity of supernatant solution of Cs-137 and Sr-85 is measured in a detecting system of I Na(Tl) well-type. Two types of parameters were changed: a) those related to the determination method: phase separation (centrifugation vs. centrifugation plus filtration); equilibrium period, ratio solid/liquid; b) those related to the geochemical system: pH of contact solution, carrier concentration, competitive ions, ionic strength, desorption. It was observed that the modification of parameters in the Kd-measurement does not change the order of magnitude of results. (Author)

  1. Neptunium(V) sorption on kaolinite

    Energy Technology Data Exchange (ETDEWEB)

    Amayri, S.; Jermolajev, A.; Reich, T. [Mainz Univ. (Germany). Inst. of Nuclear Chemistry

    2011-07-01

    The sorption behavior of neptunium(V) onto the clay mineral kaolinite was studied in batch experiments under different experimental conditions: [Np(V)] = 7 x 10{sup -12}-8 x 10{sup -6} M, solid-to-liquid ratio 2-20 g L{sup -1}, I = 0.1 and 0.01 M NaClO{sub 4}, pH = 6-10, ambient air and Ar atmosphere. The short-lived isotope {sup 239}Np (T{sub 1/2} = 2.36 d) was used instead of {sup 237}Np (T{sub 1/2} = 2.14 x 10{sup 6} a) to study the sorption behavior of Np(V) at environmentally-relevant concentrations, i.e., 7 x 10{sup -12} M Np. In addition, {sup 239}Np(V) served as tracer to measure sorption isotherms over six orders of magnitude in Np concentration (4.8 x 10{sup -12}-1.0 x 10{sup -4} M). The results show that Np(V) sorption on kaolinite is strongly influenced by pH, CO{sub 2}, and ionic strength. The sorption of 8 x 10{sup -6} M Np(V) at pH 9.0, and ionic strength of 0.1 M NaClO{sub 4} was proportional to the solid-to-liquid ratio of kaolinite in the range of 2-10 g L{sup -1}. In the absence of CO{sub 2}, the Np(V) uptake increased continuously with increasing pH value up to 97% at pH 10. Under ambient CO{sub 2}, the sorption of Np decreased above pH 8 up to zero at pH 10. An increase of Np(V) concentration from 7 x 10{sup -12} to 8 x 10{sup -6} M resulted in a shift of the sorption pH edge by up to one pH unit to higher pH values. The ionic strength influenced the Np(V) sorption onto kaolinite only in the presence of ambient CO{sub 2}. Under Ar atmosphere the sorption of Np(V) was independent from ionic strength, indicating the formation of inner-sphere complexes of Np(V) with kaolinite. Time-dependent batch experiments at pH 9.0 under ambient CO{sub 2} showed that the sorption of Np(V) on kaolinite is fast and fully reversible over six orders in Np(V) concentration. (orig.)

  2. Sorption behavior of neptunium on bentonite -- Effect of calcium ion on the sorption

    International Nuclear Information System (INIS)

    Kozai, Naofumi; Ohnuki, Toshihiko; Muraoka, Susumu

    1995-01-01

    The sorption behavior of neptunium on bentonite was studied with batch type sorption and desorption experiments over a pH range of 2 to 8. A series of parallel studies using Na-smectite, Ca-smectite and admixtures of Na-smectite and calcite quantified the capacity of Ca 2+ (which occurs in bentonite as an exchangeable cation of smectite and as a component of calcite) to inhibit the sorption of neptunium. The distribution coefficient (K d ) of neptunium for bentonite was constant from pH 2 to 7, while for pure Na-smectite K d increased below pH 5 due to specific sorption of neptunium on Na-smectite. Specific sorption was defined as occurring when neptunium could be desorbed by a strong acid (1 M HCl) but was stable in the presence of 1 M KCl. It was found that the quantity of neptunium sorbed on Na-smectite was inversely proportional to the concentration of Ca 2+ in solution, an effect most pronounced at pH 2+ limits the specific sorption capacity of Na-smectite for neptunium. Similarly, in the mixture of Na-smectite and calcite, sufficient Ca 2+ was solubilized to depress neptunium sorption. This investigation demonstrates that Ca 2+ contained in bentonite as exchangeable cation and released from calcite reduces the specific sorption of neptunium

  3. Dynamics of arsenic-containing compounds' sorption on sediments

    Energy Technology Data Exchange (ETDEWEB)

    Reczynski, W.; Posmyk, G.; Nowak, K. [AGH Univ. of Science and Technology, Faculty of Material Science and Ceramics, Dept. of Analytical Chemistry, Krakow (Poland)

    2004-07-01

    River and lake sediments constitute complex and difficult analytical samples. On the other hand, sediments play a fundamental role in the distribution of toxic compounds in aquatic systems and in the evaluation of the current state and the course of changes taking place in the environment. Among elements present in the environment in trace concentrations, but having well-elaborated toxic properties, one of most dangerous is arsenic. The element occurs in the environment in several chemical forms, predominant are inorganic forms of As(V) and As(III), and methylated forms such as monomethylarsonic acid (MMAA) and dimethylarsinic acid (DMAA). Objectives. Reported herein are experiments, which were undertaken with the aim of examining the dynamics of arsenic sorption in sediments and its dependence on speciation of the element and the pH in the environment. Simultaneously, influence of organic matter content and chemical composition of the sediments on As sorption, were investigated. Methods. Sediment samples (upper 10 cm layer) were collected from three sites located in the vicinity of Cracow: Rudawa river - 37 km long river, flowing mainly through the suburban area; Vistula river - heavily contaminated, main Polish river; Dobczyce reservoir - artificial reservoir on Raba river, total capacity of 125,000,000 m{sup 3}, supplying about 60% of drinking water to the of Cracow. Using XRD and IR methods, mineral composition of sediments was analysed. Concentrations of iron, manganese, aluminium and arsenic as well as organic matter content in solid samples were analysed. Examined sediments of Vistula river and Dobczyce lake were characterised by relatively high concentrations of arsenic, iron, manganese and aluminium. Rudawa river. At pH 3, the concentration of inorganic As in solution decreased from an initial value of 0.049 {mu}g/ml to 0.012 {mu}g/ml in 7.5 hours time. The same decreasing tendency was found at pH 5 (initial value 0.046 {mu}g/ml, after 7.5 hours - 0

  4. Technetium sorption by stibnite from natural water

    International Nuclear Information System (INIS)

    Peretroukhine, V.; Sergeant, C.; Deves, G.; Poulain, S.; Vesvres, M.H.; Thomas, B.; Simonoff, M.

    2006-01-01

    The sorption of technetium by powdered and polished mineral stibnite Sb 2 S 3 has been investigated in simulated and natural underground waters from the Meuse/Haute-Marne region (France). The sorption by powdered stibnite has been found to be complete under both aerobic and anaerobic conditions in batch experiments. The sorption rate is higher in the absence of oxygen than under aerobic condition. Increasing the temperature from 30 C to 60 C results in a rise of the sorption rate by 9.1 and 27 times under anaerobic and aerobic conditions, respectively. The observed differences in sorption kinetics in the presence and in absence of oxygen are explained by the interaction of oxygen with sulfide ion in aerobic conditions and by the reduction of technetium(VII) by iron(II) and by other impurities present in natural water and in the mineral, and by the subsequent sorption of Tc(IV) on stibnite under anaerobic conditions. The sorption on a polished mineral surface resulted in the formation of a technetium film, probably Tc 2 S 7 , with a thickness of 1-3 μg Tc/cm 2 pH 3-6 and 4-12 μg Tc/cm 2 at 9-12. The simultaneous formation of stibnite colloids with adsorbed technetium occurs at pH 9-12. The study of the technetium film on the mineral by proton induced X-ray emission analysis showed it to be at least one order of magnitude thinner on the SiO 2 impurities than on the main Sb 2 S 3 component and the iron impurities. (orig.)

  5. Computer simulation of molecular sorption in zeolites

    International Nuclear Information System (INIS)

    Calmiano, Mark Daniel

    2001-01-01

    The work presented in this thesis encompasses the computer simulation of molecular sorption. In Chapter 1 we outline the aims and objectives of this work. Chapter 2 follows in which an introduction to sorption in zeolites is presented, with discussion of structure and properties of the main zeolites studied. Chapter 2 concludes with a description of the principles and theories of adsorption. In Chapter 3 we describe the methodology behind the work carried out in this thesis. In Chapter 4 we present our first computational study, that of the sorption of krypton in silicalite. We describe work carried out to investigate low energy sorption sites of krypton in silicalite where we observe krypton to preferentially sorb into straight and sinusoidal channels over channel intersections. We simulate single step type I adsorption isotherms and use molecular dynamics to study the diffusion of krypton and obtain division coefficients and the activation energy. We compare our results to previous experimental and computational studies where we show our work to be in good agreement. In Chapter 5 we present a systematic study of the sorption of oxygen and nitrogen in five lithium substituted zeolites using a transferable interatomic potential that we have developed from ab initio calculations. We show increased loading of nitrogen compared to oxygen in all five zeolites studied as expected and simulate adsorption isotherms, which we compare to experimental and simulated data in the literature. In Chapter 6 we present work on the sorption of ferrocene in the zeolite NaY. We show that a simulated, low energy sorption site for ferrocene is correctly located by comparing to X-ray powder diffraction results for this same system. The thesis concludes with some overall conclusions and discussion of opportunities for future work. (author)

  6. I could never take the place of your man

    DEFF Research Database (Denmark)

    Andersen, Poul Houman; Munksgaard, Kristin B.

    We explore the dynamic tensions between the strategic change intentions by business actors and the rigidities of routines in business networks. We capture strategic change acts using the recent advances in the literature on network pictures as way to understand the value creation logics of managers...... and we coin the term network picturing to describe this process. We develop a theoretical framework that links network pictures and the patterned processes of interaction in business network routines. Here, we argue that the resistance managers' meet in their change efforts is likely, even if the change...... efforts do not directly rival or contradict that of other actors in the exchange party in a resource-dependency sense, but may be caused simply by disrupting the existing business network. We use three case studies to illustrate and further explore the tensions between network picturing and network...

  7. How Does Photosynthesis Take Place in Our Oceans?

    OpenAIRE

    Ghosh, Tonmoy; Mishra, Sandhya

    2017-01-01

    The food we eat ultimately comes from plants, either directly or indirectly. The importance of plants as the global kitchen can never be underestimated. Plants “eat” sunlight and carbon dioxide to produce their own food and food for the millions of other organisms dependent on them. A molecule, chlorophyll (Chl), is crucial for this process, since it absorbs sunlight. However, the way land plants produce their food is very different from the way plants in the oceans produce their food. Since ...

  8. When radionuclides take the place of vital elements

    International Nuclear Information System (INIS)

    Rouffignac, Ch. de; Poncy, J.L.; Martin, M.

    2003-01-01

    The radiosensitivity of the kidneys is a major factor restricting the applications of chemoradiotherapy. However, improved knowledge of the mechanisms involved has allowed new treatments to be developed that attenuate the effects of the irradiation or delay its consequences. Certain radioactive elements can behave in the body like calcium, and so exhibit a special affinity for bone structures. The skin is the first tissue that is damaged by external exposure to ionising radiation. The early and late responses to irradiation in this complex organ are still poorly understood. Thanks to DNA micro-arrays, the response of skin cells to irradiation, and in particular that of epidermal stem cells, can now be studied globally. (authors)

  9. Does the measurement take place when nobody observes it

    Energy Technology Data Exchange (ETDEWEB)

    Gurvitz, Shmuel [Department of Particle Physics and Astrophysics, Weizmann Institute of Science, Rehovot (Israel); Beijing Computational Science Research Center, Beijing (China)

    2017-06-15

    We consider non-selective continuous measurements of a particle tunneling to a reservoir of finite band-width (Λ). The particle is continuously monitored by frequent projective measurements (''quantum trajectory''), separated by a time-interval τ. A simple analytical expression for the decay rate has been obtained. For Markovian reservoirs (Λ → ∞), no effect of the measurements is found. Otherwise for a finite Λ, the decay rate always depends on the measurement time τ. This result is compared with alternative calculations, with no intermediate measurements, but when the measurement device is included in the Schroedinger evolution. We found that the detector affects the system by the decoherence rate (Γ{sub d}), related to the detector's signal. Although both treatments are different, the final results become very close for τ = 2/Γ{sub d}. This τ corresponds to the minimal time for which the detector's signal can be distinguished by an ''observer''. This indicates a fundamental role of information in quantum motion and can be used for the extension of the quantum trajectory method for non-Markovian environments. (copyright 2016 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. BP-Mobil partnership. The common network takes place

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    After the partnership between BP and Mobil was signed, the program of transformation of the petrol stations network started in November 1996 in the UK and concern 3300 stations in Europe and 800 stations in France. About 9100 stations will be transformed by the end of 1998. BP France is the operator for petroleum products (petrol, fuel, bitumens, LPG..) with a 70% share holding (30% for Mobil) while Mobil is the major shareholder (51%) for the lubricants and special products activities. The chemical, aviation nd maritime activities are not concerned. Thanks to the fusion of their down-file activities in Europe, the benefits of the partnership should reach 600 to 700 million of US Dollars each year. However the restructuring cost should reach 740 millions of US Dollars in two years, which doubles the initial estimation. Short paper. (J.S.)

  11. Sorption of cesium in intact rock

    International Nuclear Information System (INIS)

    Puukko, E.

    2014-04-01

    The mass distribution coefficient K d is used in performance assessment (PA) to describe sorption of a radionuclide on rock. The R d is determined using crushed rock which causes uncertainty in converting the R d values to K d values for intact rock. This work describes a method to determine the equilibrium of sorption on intact rock. The rock types of the planned Olkiluoto waste disposal site were T-series mica gneiss (T-MGN), T-series tonalite granodiorite granite gneiss (T-TGG), P-series tonalite granodiorite granite gneiss (P-TGG) and pegmatitic granite (PGR). These rocks contain different amount of biotite which is the main sorbing mineral. The sorption of cesium on intact rock slices was studied by applying an electrical field to speed up migration of cesium into the rock. Cesium is in the solution as a noncomplex cation Cs + and it is sorbed by ion exchange. The tracer used in the experiments was 134 Cs. The experimental sorption on the intact rock is compared with values calculated using the in house cation exchange sorption model (HYRL model) in PHREEQC program. The observed sorption on T-MGN and T-TGG rocks was close to the calculated values. Two PGR samples were from a depth of 70 m and three samples were from a depth of 150 m. Cesium sorbed more than predicted on the two 70 m PGR samples. The sorption of Cs on the three 150 m PGR samples was small which was consistent with the calculations. The pegmatitic granite PGR has the smallest content of biotite of the four rock types. In the case of P-TGG rock the observed values of sorption were only half of the calculated values. Two kind of slices were cut from P-TGG drill core. The slices were against and to the direction of the foliation of the biotite rims. The sorption of cesium on P-TGG rock was same in both cases. The results indicated that there was no effect of the directions of the electric field and the foliation of biotite in the P-TGG rock. (orig.)

  12. Recent progress in sorption mechanisms and models

    International Nuclear Information System (INIS)

    Fedoroff, M.; Lefevre, G.

    2005-01-01

    Full text of publication follows: Sorption-desorption phenomena play an important role in the migration of radioactive species in surface and underground waters. In order to predict the transport of these species, we need a good knowledge of sorption processes and data, together with reliable models able to be included in transport calculation. Traditional approaches based on experimentally determined distribution coefficients (Kd) and sorption isotherms have a limited predictive capability, since they are very sensitive to the numerous parameters characterizing the solution and the solid. Models based on thermodynamic equilibria were developed to account for the influence these parameters: the ion exchange model and the surface complexation models (2-pK mono-site, 1-pK multi-site, with several different electrostatic models: CCM, DLM, BSM, TLM,...). Although these models are very useful, studies performed in recent years showed that they have important theoretical and experimental limitations, which result in the fact that we must be very careful when we use them for extrapolating sorption data to long term and to large natural systems. Among all problems which can be found are: the possibility to fit a set of experimental data with different models, sometimes bad adequacy with the real sorption processes, some theoretical limitations such as a rigorous definition of reference and standard states in surface equilibria, slow kinetics which prevent from equilibrium achievement, irreversibility, solubility and evolution of solid phases... Through the increase of the number of sensitive spectroscopic methods, we are now able to know more about sorption processes at the atomic scale. Models such as the 1-pK CD-MUSIC model can account for the influence of orientation of the faces of the solid. More and more examples of the influence of this orientation on the sorption properties are known. Calculations performed by 'ab initio' modeling is also useful to predict the

  13. The NEA sorption data base (SDB)

    International Nuclear Information System (INIS)

    Ruegger, B.; Ticknor, K.

    1992-01-01

    The current NEA Sorption Data Base is developed to replace the former International Sorption Information Retrieval System (ISIRS) initiated at Pacific Northwest Laboratory and contains about 11,000 distribution coefficients with corresponding experimental condition parameters describing sorption of key nuclides for a large variety of solid and liquid phases. The SDB is designed to run on a micro-computer using the commercially available database software dBASE III Plus. For each recorded sorption experiment, the SDB provides a bibliographical reference, the most complete characterization of the solid and liquid phases available, a description of the experimental conditions and the distribution coefficient or retardation factor for each element studied. When available, parameters such as temperature, initial radionuclide concentration, pH, Eh, contact time, solid to solution ratio, sample origin, oxidation state and type of solution are included. The SDB provides information for a wide variety of rocks or geological materials, buffer backfill candidates, concretes/cements, elements (Am, Cs, Co, I, Np, Pu, Ra, Sr, Se, Tc, U and, to a lesser extent, Ag, Ba, C, Ce, Eu, Fe, Mn, Mo, Na, Nb, Ni, Pd, Pm, Ru, Sb, Sn, Y, Zn, and Zr), or radioisotopes. A compilation of sorption data like SDB provide a readily available source of data for radioactive waste repository performance assessments when site specific data are not available or essential, for example, during a site selection phase. 2 appendices

  14. Radionuclide sorption from the safety evaluation perspective

    International Nuclear Information System (INIS)

    1992-01-01

    Research and development directed towards the assessment of the long-term performance of radioactive waste disposal systems has been recognised as a priority area with a strong need for international co-operation and co-ordination. The ultimate aims is to promote the quality and credibility of safety assessment techniques for radioactive waste disposal. Sorption in the geosphere is one of the key processes for retarding the transport of radionuclide from the underground disposal facility to the biosphere. In many cases, sorption in the near field and in the biosphere is also important. A workshop, organised to favor discussion around a small number of invited papers, was held in October 1991: - to evaluate critically the way sorption processes are incorporated in performance assessment models; - to identify open issues of high priority, and; - to propose future activities to resolve these issues. These proceedings reproduce the invited papers and the conclusions and recommendations adopted by the workshop. Eight papers are in the INIS SCOPE. The main subjects studied are: sorption database comparison, sorption database development and three case studies, experimental techniques, adsorption models

  15. Sorption of radionuclides by tertiary clays

    International Nuclear Information System (INIS)

    Wagner, J.F.; Czurda, K.A.

    1990-01-01

    The sorption capacity of different clay types for some metals (Co, Cs, Sr and Zn), occurring as common radionuclides in radioactive waste deposits, had been analysed by a static (batch technique) and a dynamic method (percolation tests, in which the driving force is a hydraulic gradient). Sorption capacity generally increased with an increasing pH of solution. A decrease of sorption capacity had been observed in the order Zn > Cs ≥ Co > Sr for the batch and Cs > Zn > Sr > Co for the percolation tests. Clay marls showed a distinctly higher sorption respectively retention capacity as pure clays. Sorption capacity depends on solution parameters like type and concentration of radionuclide, pH, salt concentration, etc., and on rock parameters like mineral content (e.g. swelling clay minerals and carbonates), organic material, rock pH, micro fabric, etc. A third parameter of great influence is the contact time between clay and solution. The adsorption isotherms reflect two different adsorption mechanisms: a very rapid adsorption (a few minutes) on the external surfaces of clay minerals and a slow adsorption process (weeks and longer), due to the diffusion of metal ions into the interlayer space of clay minerals. 12 refs., 9 figs., 1 tab

  16. Moisture sorption of Thai red curry powder

    Directory of Open Access Journals (Sweden)

    Sudathip Inchuen

    2009-12-01

    Full Text Available Moisture sorption study was conducted on Thai red curry powder prepared by two different drying methods, viz. microwave and hot-air drying. Moisture sorption isotherms of the red curry powder at 30 C and water activity in the range of 0.113-0.970 were determined by a static gravimetric method. The isotherms exhibited Type III behaviour. The moisture sorption data were fitted to several sorption models and a non-linear regression analysis method was used to evaluate the constants of the sorption equations. The fit was evaluated using the coefficient of determination (R2, the reduced chi-square (2 and the root mean square error (RMSE. The GAB model followed by the Lewiski-3 model gave the best fit to the experimental data. The monolayer moisture content, taken as the safe minimum moisture level in the red curry powder, was determined using the BET equation and was found to range between 0.080 - 0.085 gram water per gram dry matter.

  17. Perspective Taking in Workplaces

    Directory of Open Access Journals (Sweden)

    Zappalà Salvatore

    2014-07-01

    Full Text Available Workplaces are often described as places in which individuals are motivated by their self-interests and in which negative events like time pressure, anxiety, conflict with co-workers, miscomprehensions, difficulties in solving problems, not-transmitted or not-exchanged information that lead to mistakes, and in some cases to injuries, stress or control, are part of everyday life (Dormann & Zapf, 2002; Schabracq, Winnubst and Cooper, 2003. Such situations are often the result of the limited comprehension of needs, skills, or information available to colleagues, supervisors, subordinates, clients or providers. However, workplaces are also places in which employees take care of clients, support colleagues and subordinates (Rhoades & Eisenberger, 2002, are enthusiastic about their job (Bakker et al., 2008, are motivated by leaders that encourage employees to transcend their own self-interests for the good of the group or the organization and provide them with the confidence to perform beyond expectations (Bass, 1997. Thus positive relationships at work are becoming a new interdisciplinary domain of inquiry (Dutton & Ragins, 2006. Within this positive relationships framework, in this paper we focus on a positive component of workplaces, and particularly on an individual cognitive and emotional process that has an important role in the workplace because it facilitates interpersonal relations and communications: it is the perspective taking process. In order to describe perspective taking, we will refer to some empirical studies and particularly to the review published by Parker, Atkins and Axtell in 2008 on the International Review of Industrial and Organizational Psychology.

  18. Sorption behaviour of radioactive technetium in soils

    International Nuclear Information System (INIS)

    Xia Deying

    1996-01-01

    The sorption behaviour of technetium in different soils has been studied by batch experiments under aerobic conditions. The soil samples have been taken to study the characteristics and to derive the pH-Eh values. In addition, the activated carbon and reduced iron powder have been selected as additives to the JAERI sand according to the former research work, so that the technetium sorption behaviour in the artificial soils can be studied under similar conditions. The experimental results show that all these soil samples except for the gluey soil have a very small distribution coefficient for Tc, while the artificial soils have a very large distribution coefficient for Tc. Besides, for artificial soils, the distribution coefficient (R d ) values will become larger and larger when more additive is added and more contact time is allowed. The physico-chemical fixation processes and possible sorption modes have been discussed as well

  19. Sorption of radioactive technetium on pyrrhotine

    International Nuclear Information System (INIS)

    Shen, D.; Fan, X.H.; Su, X.G.; Zeng, J.S.; Dong, Y.

    2002-01-01

    The sorption behavior of technetium on pyrrhotine was studied with batch experiments and diluted sulfuric acid (less than 2.88 mol/l) was used to dissolve the technetium adsorbed on pyrrhotine. A significant sorption of technetium on pyrrhotine was observed under aerobic and anaerobic conditions, and the sorption on the mineral was supposed to be due to the reduction of TcO 4 - to insoluble TcO 2 x nH 2 O. Sorbed technetium on the mineral could be desorbed by diluted sulfuric acid. The maximum desorption ratio under aerobic conditions was much higher than that of under anaerobic conditions, meanwhile, the desorption rates under anaerobic conditions were higher than that of under aerobic conditions in the initial stage of the experiments. (author)

  20. Water sorption and transport in dry crispy bread crust

    NARCIS (Netherlands)

    Meinders, M.B.J.; Nieuwenhuijzen, van N.H.; Tromp, R.H.; Hamer, R.J.; Vliet, van T.

    2010-01-01

    Water sorption and dynamical properties of bread crust have been studied using gravimetric sorption experiments. Water uptake and loss were followed while relative humidity (RH) was stepwise in- or decreased (isotherm experiment) or varied between two adjusted values (oscillatory experiment).

  1. The sorption of acids in cellular side of apple pressing

    International Nuclear Information System (INIS)

    Asoev, M.G.; Mukhiddinov, Z.K.

    1994-01-01

    Equilibrium swell of sample refuse after separation of water is use for study of sorption of hydrochloric acid. Quantity adsorb acids set a price to difference her concentration before and after equilibrium sorption

  2. Molecular simulation of polycyclic aromatic hydrocarbon sorption to black carbon

    NARCIS (Netherlands)

    Haftka, J.J.H.; Parsons, J.R.; Govers, H.A.J.

    2009-01-01

    Strong sorption of hydrophobic organic contaminants to soot or black carbon (BC) is an important environmental process limiting the bioremediation potential of contaminated soils and sediments. Reliable methods to predict BC sorption coefficients for organic contaminants are therefore required. A

  3. Tritium sorption on protective coatings for concrete

    International Nuclear Information System (INIS)

    Miller, J.M.; Senohrabek, J.A.; Allsop, P.A.

    1992-11-01

    Because of the high sorption level of tritium on unprotected concrete, a program to examine the effectiveness of various concrete coatings and sealants in reducing tritium sorption was undertaken, and various exposure conditions were examined. Coatings of epoxy, polyurethane, bituminous sealant, bituminous sealant covered with polyvinylidene chloride wrap, alkyd paint, and sodium silicate were investigated with tritium (HTO) vapor concentration, humidity and contact time being varied. An exposure to HT was also carried out, and the effect of humidity on the tritium desorption rate was investigated. The relative effectiveness of the coatings was in the order of bituminous sealant + wrap > bituminous sealant > solvent-based epoxy > 100%-solids epoxy > alkyd paint > sodium silicate. The commercially available coatings for concrete resulted in tritium sorption being reduced to less than 7% of unprotected concrete. This was improved to ∼0.1% with the use of the Saran wrap (polyvinylidene chloride). The amount of tritium sorbed was proportional to tritium concentration. The total tritium sorbed decreased with an increase in humidity. A saturation effect was observed with increasing exposure time for both the coated and unprotected samples. Under the test conditions, complete saturation was not achieved within the maximum 8-hour contact time, except for the solvent-based epoxy. The desorption rate increased with a higher-humidity air purge stream. HT desorbed more rapidly than HTO, but the amount sorbed was smaller. The experimental program showed that HTO sorption by concrete can be significantly reduced with the proper choice of coating. However, tritium sorption on concrete and proposed coatings will continue to be a concern until the effects of the various conditions that affect the adsorption and desorption of tritium are firmly established for both chronic and acute tritium release conditions. Material sorption characteristics must also be considered in

  4. On the derivation of a sorption database

    International Nuclear Information System (INIS)

    Ewart, F.T.; Haworth, A.; Wisbey, S.J.

    1992-01-01

    The safety arguments in support of many radioactive waste repository concepts are heavily dependent on the existence of a sorption reaction. Such a reaction will, in the near field, reduce the magnitude of the release of a number of hazardous radionuclides so that their release to the geosphere is dispersed in time. In the geosphere, the sorption reactions provide a mechanism whereby the migration of the elements released from the repository is retarded and the radioisotopes then subsequently decay. The processes involved in sorption cannot in many cases be satisfactorily represented in thermodynamic terms such as are employed in the description of dissolution and precipitation. Experiments that investigate these reactions are not easy to perform. The sorption parameters that are obtained experimentally for the near field relate, in the UK case, to sorption on to a cementitious surface. These surfaces, since they consist substantially of calcium hydroxide or calcium silicate hydrates, control the aqueous chemistry, do not permit pH changes to be made and limit the range of concentrations of sorbate that may be used. In the far field, on the other hand, the surfaces are not in general so active with respect to the solution chemistry and data can be obtained across a wide spectrum of aqueous chemistries. These data, although they may be useful in testing and parameterizing models, may not have validity under field conditions since the minerals will, inevitably, react to the changes in water chemistry, over geological timescales. The uncertainties in the experimental data are, for many elements and solids, balanced by a reasonable agreement between workers in the values of the parameters used to describe sorption. 22 refs., 1 fig., 1 tab

  5. Europium sorption on zirconia at elevated temperatures: experimental study and modeling

    International Nuclear Information System (INIS)

    Eglizaud, N.; Catalette, H.

    2005-01-01

    Full text of publication follows: Direct disposal of spent nuclear fuel in deep underground repository is being considered by several countries. The waste package maintains an elevated temperature for thousands of years. As sorption is one of the main phenomenon limiting the dispersion of radionuclides in the environment, it has to be studied at elevated temperatures. Zirconia is an oxide produced by cladding oxidation which is suspected in the near field of a nuclear repository. It then could possibly be in contact with waste elements as Europium (III), the sorption of which is therefore studied on zirconia. Experiments were performed by the batch method at a solid/liquid ratio of 10 g.L-1. The sorption edges were recorded in the pH-range from 2 to 10 at 2.10 -5 mol.L -1 Eu(NO 3 ) 3 (I = 0.1 mol.L -1 KNO 3 ). An over-pressure device in an autoclave with an incorporated filtering system allowed the experiments, carbonate free, at 25 deg. C, 50 deg. C, 80 deg. C, 120 deg. C and 150 deg. C and in situ pH measurements. Filtrates were analyzed by the ICP-AES method. Sorption isotherms show an increase in the sorption phenomenon when the temperature raises. The half sorption pH decreases from 7 at 25 deg. C to 3,6 at 150 deg. C. The distribution coefficients that were obtained at elevated temperatures enriched the databases of integrated performance assessment codes. Raw data were modeled with the surface complexation theory using the double layer model (DLM). Several possible surface complexes were examined and discussed, taking into account aqueous hydrolyzed and precipitated species of Europium. A good agreement between experimental values and modeled isotherms was found at all studied temperatures. Results were consistent with a bidentate complex formed by Europium (III) on the zirconia surface. Associated formation constants were then determined with the geochemical computer code CHESS. (authors)

  6. Sorption Properties of Some Romanian Gingerbread

    Directory of Open Access Journals (Sweden)

    Tulbure Anca

    2014-06-01

    Full Text Available Water activity of gingerbread is very important for keeping the product freshness and shelf life. Water activity is influenced by composition, water content and temperature. The water content of gingerbread could vary according with storage condition. i.e. rH. 11 gingerbread samples were analysed. The water content and water activity lies between 7.0 and 12.6% and respectively 0.590 and 0.715. The sorption isotherms were determined at 30°C by gravimetric method. The moisture sorption is influenced by composition, especially sweeteners and humectants. Honey and invert sugar have the same impact on gingerbread higroscopicity.

  7. Sorption of radionuclides on hard rocks

    International Nuclear Information System (INIS)

    Berry, J.A.; Bourke, P.J.; Green, A.; Littleboy, A.K.

    1987-09-01

    Methods for measuring sorption on hard rocks, particularly of strontium, caesium, neptunium and americium on Darley Dale sandstone and Welsh slate have been investigated. The methods tried included batch tests with crushed rock and tests of simultaneous diffusion and convection with sorption on intact rock. High pressures (800m H 2 O) were used in the convective tests to pump water quickly through the rock samples and to measure high sorptivities in times shorter than those needed in the diffusive methods with intact samples. (author)

  8. A Sorption Hysteresis Model For Cellulosic Materials

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Damkilde, Lars

    2006-01-01

    The equilibrium concentration of adsorbed water in cellulosic materials is dependent on the history of the variations of vapor pressure in the ambient air, i.e. sorption hysteresis. Existing models to describe this phenomenon such as the independent domain theory have numerical drawbacks and....../or imply accounting for the entire history variations of every material point. This paper presents a sorption hysteresis model based on a state formulation and expressed in closed-form solutions, which makes it suitable for implementation into a numerical method....

  9. Sorption of natural uranium by algerian bentonite

    International Nuclear Information System (INIS)

    Megouda, N.; Kadi, H.; Hamla, M.S.; Brahimi, H.

    2004-01-01

    Full text.Batch sorption experiments have been used to assess the sorption behaviour of uranium onto natural and drilling bentonites. The operating parameters (pH, aolis-liquid ratio, particle size, time and initial uranium concentration) influenced the rate of adsorption. The distribution coefficient (Kd) range values at equilibrium time are 45.95-1079.26 ml/g and 32.81-463053 ml/g for the drilling and natural bentonites respectively. The equilibrium isotherms show that the data correlate with both Freundlich and Langmuir models

  10. Sorption characteristic of coal as regards of gas mixtures emitted in the process of the self-heating of coal

    Directory of Open Access Journals (Sweden)

    Wojtacha-Rychter Karolina

    2017-01-01

    Full Text Available One of the most challenging tasks in the coal mining sector is the detection of endogenous fire risks. Under field conditions, the distance between the points where samples for the analyses are collected and the actual place where coal self-heating takes place may be quite remote. Coal is a natural sorbent with a diverse character of pore structures which are surrounded by fractures and cleavage planes constituting ideal spaces for the flow and adsorption of gases. The gases (methane, ethane, ethylene, propane, propylene, acetylene, carbon dioxide, carbon monoxide, hydrogen released from the source of fire migrate through the seam and may be subject to adsorption, or they may cause the desorption of gases accumulated in coal. Therefore, the values of reference sample concentrations may be overstated or understated, respectively. The objective of this experimental study was to investigate the adsorption phenomena accompanying the flow of a multi-component gas mixture through a coal bed which may occur in situ. The research was conducted by means of a method based on a series of calorimetric/chromatographic measurements taken to determine the amount of gases released during coal heating at various temperatures under laboratory conditions. Based on the results obtained in the course of the experiments, it was concluded that the amount of gas adsorbed in the seam depends on the type of coal and the gas. Within the multi-component gas mixture, hydrocarbons demonstrated the largest sorption capacity, especially as concerns propylene.

  11. Speciation of plutonium during sorption and diffusion in Opalinus clay

    International Nuclear Information System (INIS)

    Kaplan, Ugras

    2013-01-01

    The presented work was carried out in the framework of the BMWi-project ''Interaction and migration of actinides in natural clay rocks taking into account humic substances and clay organic matter - Interactions of neptunium and plutonium with natural clay rocks''. For the long-term safety assessments of nuclear repositories, the possible migration of the radiotoxic wastes into the environment must be considered. Due to its long half-life (T 1/2 = 24000 y) 239 Pu has a significant contribution to the radiotoxicity of spent nuclear fuel in a repository after long periods of storage. The redox-sensitive plutonium has a very complicated chemical behavior. In aqueous solution under environmental relevant conditions Pu can exist in oxidation states +III to +VI and it can exist in up to four oxidation states simultaneously in a solution. Clays are considered as a possible host rock formation for of high-level radioactive waste disposal. Therefore, detailed information on the mobilization and immobilization of plutonium through / into the groundwater from a repository are of special interest. In this work new insights into the interaction between Pu and natural Opalinus clay (OPA, Mont Terri, Switzerland) are obtained with regard to the disposal of heat-generating radioactive waste in a deep geological repository.rnThe focus of this work was on the determination of the speciation of Pu on the mineral surface after sorption and diffusion process by different synchrotron based techniques (μ-XRF, μ-XANES/-EXAFS, μ-XRD, and EXAFS/XANES). The interaction between Pu and OPA was studied in batch sorption and diffusion experiments in dependence of various experimental parameters (e.g. pH, Pu oxidation state). Sorption experiments showed that some experimental parameters (e.g. temperature, humic acid) have a significant impact on the sorption of Pu on OPA. Speciation studies were performed as a function of various chemical parameters on powder samples form batch experiments as

  12. Modelling Ni diffusion in bentonite using different sorption models

    International Nuclear Information System (INIS)

    Pfingsten, W.; Baeyens, B.; Bradbury, M.

    2010-01-01

    different modelling approaches a) an analytical solution with constant Kd using a constant Ni(II) concentration level at x = 0 (e.g. at the canister surface) and zero Ni(II) initial background concentration in the bentonite, b) a numerical 'constant K d approach' taking into account the initial Ni(II) background concentration in the bentonite pore water, and c) a reactive transport approach using the code MCOTAC in one-dimensional spatial geometry with an incorporated mechanistic sorption model which includes surface proto-lysis, surface complexation and cation exchange reactions. Charge balance is explicitly formulated for the surface complexation reactions. Selectivity coefficients and surface complexation data for Ni(II) were taken from Bradbury and Baeyens (2005); the related Fe(II) data were obtained from the Linear Free Energy Relationship (LFER) contained in the same publication. The Ni(II) breakthrough in the bentonite was calculated for different Ni(II) concentration levels with and without considering competition with Fe(II) on exchange and surface complexation sites for different Fe(II) concentrations in the bentonite pore water. The comparison allows the following observations to be made: for trace Ni(II) concentrations, the numerical 'constant K d approach' yield similar results to the reactive transport approach. For higher Ni(II) concentrations, the calculated Ni(II) breakthroughs differ from each other: the reactive transport approach yields an earlier breakthrough than the numerical 'constant K d approach' for a Ni concentration level of 10 -5 M. However, for a Ni(II) concentration level of 10 -4 M, the reactive transport approach yield a later but steeper breakthrough, reaching the maximum Ni(II) concentration level earlier than the numerical 'constant K d approach'. Fe(II) competition reactions could only be taken into account using the reactive transport approach. The results yield a general dependency of the Ni

  13. The sorption behaviour of 99Tc on activated carbon

    International Nuclear Information System (INIS)

    Xia Deying; Zeng Jishu

    2004-01-01

    The sorption behaviour of 99 Tc on apricot-pit activated carbon with batch experiment is studied. The influence of such factors as sorbent particle size, temperature, pH value on sorption ratio, and the Freundlich sorption isotherms are reported in this paper. (author)

  14. Suitability of Moshi Pumice for Phosphorus Sorption in Constructed ...

    African Journals Online (AJOL)

    The study of Moshi Pumice's phosphorus sorption behaviours and properties was carried out in laboratory scale where by 1-2 mm, 2-4 mm and 4-8 mm grains were tested using batch experiments. The results show that Moshi Pumice has high phosphorus sorption capacity. The sorption capacity for the Moshi Pumice was ...

  15. Phosphorus sorption in relation to soil grain size and geochemical ...

    African Journals Online (AJOL)

    By using stepwise regression, the combination of Al, Fe, clay and Ca predicted more than 94% of the variation in the P sorption capacity of soils samples from Simiyu and Kagera basins. These four soil properties, which are strongly related to P sorption, could therefore be used as quick tests for predicting the P sorption ...

  16. Sorption of Heterocyclic Organic Compounds to Multiwalled Carbon Nanotubes.

    Science.gov (United States)

    Metzelder, Florian; Funck, Matin; Schmidt, Torsten C

    2018-01-16

    Sorption is an important natural and technical process. Sorption coefficients are typically determined in batch experiments, but this may be challenging for weakly sorbing compounds. An alternative method enabling analysis of those compounds is column chromatography. A column packed with the sorbent is used and sorption data are determined by relating sorbate retention to that of a nonretarded tracer. In this study, column chromatography was applied for the first time to study sorption of previously hardly investigated heterocyclic organic compounds to multiwalled carbon nanotubes (MWCNTs). Sorption data for these compounds are very limited in literature, and weak sorption is expected from predictions. Deuterium oxide was used as nonretarded tracer. Sorption isotherms were well described by the Freundlich model and data showed reasonable agreement with predicted values. Sorption was exothermic and physisorption was observed. H-bonding may contribute to overall sorption, which is supported by reduced sorption with increasing ionic strength due to blocking of functional groups. Lowering pH reduced sorption of ionizable compounds, due to electrostatic repulsion at pH 3 where sorbent as well as sorbates were positively charged. Overall, column chromatography was successfully used to study sorption of heterocyclic compounds to MWCNTs and could be applied for other carbon-based sorbents.

  17. Attenuation of polychlorinated biphenyl sorption to charcoal by humic acids

    NARCIS (Netherlands)

    Koelmans, A.A.; Meulman, B.; Meijer, T.; Jonker, M.T.O.

    2009-01-01

    Strong sorption to black carbon may limit the environmental risks of organic pollutants, but interactions with cosorbing humic acid (HA) may interfere. We studied the attenuative effect of HA additions on the sorption of polychlorinated biphenyls (PCBs) to a charcoal. "Intrinsic" sorption to

  18. Sorption mechanisms of perfluorinated compounds on carbon nanotubes

    International Nuclear Information System (INIS)

    Deng Shubo; Zhang Qiaoying; Nie Yao; Wei Haoran; Wang Bin; Huang Jun; Yu Gang; Xing Baoshan

    2012-01-01

    Sorption of perfluorinated compounds (PFCs) on carbon nanotubes (CNTs) is critical for understanding their subsequent transport and fate in aqueous environments, but the sorption mechanisms remain largely unknown. In this study, the sorption of six PFCs on CNTs increased with increasing C-F chain length when they had a same functional group, and the CNTs with hydroxyl and carboxyl groups had much lower adsorbed amount than the pristine CNTs, indicating that hydrophobic interaction dominated the sorption of PFCs on the CNTs. Electrostatic repulsion suppressed the sorption of PFCs on the CNTs, resulting in the lower sorption with increasing pH. Hydrogen bonding interaction was negligible. The hydrophobic C-F chains can be closely adsorbed on the CNTs surface in parallel to the axis or along the curvature, making it impossible to form micelles on the CNT surface, leading to the lower sorption than other adsorbents. Highlights: ► Sorption capacities of PFOA on different CNTs are less than that on activated carbon and resins. ► Hydrophobic interaction is principally involved in the sorption of PFCs on CNTs. ► Electrostatic repulsion suppresses the sorption of PFCs on CNTs. - Hydrophobic interaction dominated the sorption of perfluorinated compounds on carbon nanotubes, while electrostatic repulsion suppressed their sorption.

  19. Hydration and sorption characteristics of a polyfunctional weak-base anion exchanger after the sorption of vanillin and ethylvanillin

    Science.gov (United States)

    Rodionova, D. O.; Voronyuk, I. V.; Eliseeva, T. V.

    2016-07-01

    Features of the sorption of substituted aromatic aldehydes by a weak-base anion exchanger under equilibrium conditions are investigated using vanillin and ethylvanillin as examples. Analysis of the sorption isotherms of carbonyl compounds at different temperatures allows us to calculate the equilibrium characteristics of their sorption and assess the entropy and enthalpy contributions to the energy of the process. Hydration characteristics of the macroporous weak-base anion exchanger before and after the sorption of aromatic aldehydes are compared.

  20. Predicting the uptake of Cs, Co, Ni, Eu, Th and U on argillaceous rocks using sorption models for illite

    International Nuclear Information System (INIS)

    Marques Fernandes, Maria; Vér, Nóra; Baeyens, Bart

    2015-01-01

    Highlights: • Contaminant retention in argillaceous rocks controlled by sorption on clay minerals. • Cs, Ni, Co, Eu, Th and UO 2 sorption isotherm measurements on Boda and Opalinus Clay. • Boda and Opalinus Clay exhibit different mineralogies and porewater compositions. • Blind predictions using quasi-mechanistic sorption models developed for illite. • Good agreement between measurements and blind predictions. - Abstract: Reliable predictions of radiocontaminant migration are a requirement for the establishment of radioactive waste repositories. Parametrization of the necessary sorption models seems to be, however, extremely challenging given the multi-mineralic composition of the lithosphere. In this study it is shown for two argillaceous rocks – Boda and Opalinus Clay relevant for the Hungarian and Swiss repository concepts, respectively – that this task can be substantially simplified by taking into account only the most sorptive mineral fraction, namely the 2:1 clay minerals illite and illite/smectite mixed layers. Two different models were required to blind predict the sorption isotherms of Cs, Co, Ni, Eu, Th and UO 2 measured on the two clay rock samples in a synthetic porewater. Cs sorption was modelled with the generalised Cs (GCs) sorption model and the sorption of the other cations with the 2site protolysis non electrostatic surface complexation and cation exchange (2SPNE SC/CE) model. The 2SPNE SC/CE model for illite was extended with surface complexation reactions on weak sites for Co, Ni, Eu, UO 2 and on strong sites for Eu-carbonato complexes. Complementary to the sorption measurements and modelling, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to probe the retention mechanism of Ni on illite, Boda and Opalinus Clay at higher loadings. The reliable blind predictions of the selected metal cations, which are representative for monovalent alkaline metals, divalent transition metals, lanthanides, and trivalent

  1. A suggested approach toward measuring sorption and applying sorption data to repository performance assessment

    International Nuclear Information System (INIS)

    Rundberg, R.S.

    1991-01-01

    The sorption of radioisotopes in relation to geologic disposal of radioactive wastes is discussed. Properties of the radioactive materials, rocks, and minerals, and the chemistry involved are described. 51 refs., 12 figs. CBS

  2. Sorption of fission nuclides on model milk components. II. Sorption of radiostrontium on hydroxyapatite in milk and whey

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Kopunec, R.; Matel, L.; Macasek, F.

    1999-01-01

    In this work the whey was chosen as a model solution of liquid phase for sorption study of strontium on hydroxyapatite. The whey was obtained using two methods - ultracentrifugation and precipitation of casein. The sorption was studied at a different pH and at a different concentration of calcium. The sorption of strontium on hydroxyapatite from milk was studied, too. (authors)

  3. Kinetics and thermodynamic for sorption of arsenate by Lanthanum-exchanged zeolite

    International Nuclear Information System (INIS)

    Mohd Jelas Haron; Saiful Adli Masdan; Mohd Zobir Hussein; Zulkarnain Zainal; Anuar Kassim

    2007-01-01

    Zeolites are crystalline, hydrated aluminosilicate containing exchangeable alkaline and alkaline earth cations in their structural frameworks. Since zeolites have permanent negative charges on their surfaces, they have no affinity for anions. However recent studies have shown that modification of zeolites with certain surfactants or metal cations yield sorbents with a strong affinity for many anions. In this paper, modification of zeolites (zeolite A, X and ZSM5) were performed by exchange of naturally occurring cations with lanthanum ion that forms low solubility arsenate salt. The exchanged zeolites were used to sorb arsenate from aqueous solution. Among parameters investigated were effect of pH, arsenate initial concentrations, contact time and temperature. The maximum exchanged capacity of La (III) ion was obtained when using solution with initial pH of 4. Zeolite X gives the highest La (III) exchanged capacity compared to other zeolites. The results showed that As (V) sorption by La-zeolites occurred at about pH 6.5 and increased as pH increased and reaching maximum at equilibrium pH about 7.8. On the other hand, almost no arsenate sorption occurred on un exchanged zeolites. This indicates that La (III) ion on the exchanged zeolites is taking part on the As(V) sorption via surface precipitation. The results also showed that the sorption capacities increased with increasing initial As (V) concentrations. The sorption followed Langmuir model with maximum sorption capacities of 0.41, 0.21 and 0.19 mmol/g at 25 degree Celsius for La exchanged zeolite X (La-ZX), La exchanged zeolite ZSM5 (La-ZSM) and La exchanged zeolite A (La-ZA), respectively. The amounts of sorption of As (V) by La exchanged zeolite increased as temperature increased from 25 to 70 degree Celsius indicating that the process is endothermic. The free energy changes ( ΔG degree) for the sorption at 25 degree Celsius were -10.25, -9.65 and -8.49 kJ/ mol for La-ZX, La-ZSM and La-ZA, respectively. The

  4. Development of mechanistic sorption model and treatment of uncertainties for Ni sorption on montmorillonite/bentonite

    International Nuclear Information System (INIS)

    Ochs, Michael; Ganter, Charlotte; Tachi, Yukio; Suyama, Tadahiro; Yui, Mikazu

    2011-02-01

    Sorption and diffusion of radionuclides in buffer materials (bentonite) are the key processes in the safe geological disposal of radioactive waste, because migration of radionuclides in this barrier is expected to be diffusion-controlled and retarded by sorption processes. It is therefore necessary to understand the detailed/coupled processes of sorption and diffusion in compacted bentonite and develop mechanistic /predictive models, so that reliable parameters can be set under a variety of geochemical conditions relevant to performance assessment (PA). For this purpose, JAEA has developed the integrated sorption and diffusion (ISD) model/database in montmorillonite/bentonite systems. The main goal of the mechanistic model/database development is to provide a tool for a consistent explanation, prediction, and uncertainty assessment of K d as well as diffusion parameters needed for the quantification of radionuclide transport. The present report focuses on developing the thermodynamic sorption model (TSM) and on the quantification and handling of model uncertainties in applications, based on illustrating by example of Ni sorption on montmorillonite/bentonite. This includes 1) a summary of the present state of the art of thermodynamic sorption modeling, 2) a discussion of the selection of surface species and model design appropriate for the present purpose, 3) possible sources and representations of TSM uncertainties, and 4) details of modeling, testing and uncertainty evaluation for Ni sorption. Two fundamentally different approaches are presented and compared for representing TSM uncertainties: 1) TSM parameter uncertainties calculated by FITEQL optimization routines and some statistical procedure, 2) overall error estimated by direct comparison of modeled and experimental K d values. The overall error in K d is viewed as the best representation of model uncertainty in ISD model/database development. (author)

  5. Gas Sorption, Diffusion, and Permeation in Nafion

    KAUST Repository

    Mukaddam, Mohsin Ahmed; Litwiller, Eric; Pinnau, Ingo

    2015-01-01

    The gas permeability of dry Nafion films was determined at 2 atm and 35 °C for He, H2, N2, O2, CO2, CH4, C2H6, and C3H8. In addition, gas sorption isotherms were determined by gravimetric and barometric techniques as a function of pressure up to 20

  6. Development of a microminiature sorption cooler

    NARCIS (Netherlands)

    Burger, Johannes; Holland, Harry; ter Brake, Marcel; Rogalla, Horst; Wade, Larry

    1997-01-01

    The development of a microcooler for operations below 80 K, for low temperature electronic devices requiring small cooling powers of the order of 10 mW is described. A sorption compressor combined with Joule-Thomson (JT) expansion was selected for miniaturization. The advantage of the system is

  7. Sorption of radiocalcium on human hair

    International Nuclear Information System (INIS)

    Rakovic, M.; Pilecka, N.

    1987-01-01

    The sorption of 45 Ca on hair from a 45 CaCl 2 solution (2.5x10 -3 mol l -1 ) was studied. The calcium amounts sorbed in 1 min to 5 h range between 0.8 and 7.2% with respect to the originally present calcium in hair. (author) 3 refs

  8. Sorption of methanol in alkali exchange zeolites

    NARCIS (Netherlands)

    Rep, M.; Rep, M.; Corma, Avelino; Palomares, A.E.; Palomares gimeno, A.E.; van Ommen, J.G.; Lefferts, Leonardus; Lercher, J.A.

    2000-01-01

    Metal cation methanol sorption complexes in MFI (ZSM5), MOR and X have been studied by in situ i.r. spectroscopy in order to understand the nature of interactions of methanol in the molecular sieve pores. The results show that (a) a freely vibrating hydroxy and methyl group of methanol exist on

  9. Radionuclide sorption database for Swiss safety assessment

    International Nuclear Information System (INIS)

    McKinley, I.G.; Hadermann, J.

    1984-10-01

    Recommended sorption data for use in transport models for a Swiss High-Level Waste repository are presented. The models used in 'Project Gewaehr 1985' assume linear sorption isotherms and require elemental partition coefficient (Kd) data. On the basis of a literature search 'realistic' Kd data for 22 elements have been selected for weathered crystalline rock and sediments in contact with a reducing groundwater and also sediments with a less reducing groundwater. In an appendix sorption data for 28 elements on bentonite backfill are given. These data are supplemented with 'conservative' estimates taken to represent minimum reasonable values. Available data are discussed for each element clearly exhibiting (i) the large gaps in knowledge, (ii) their unbalanced distribution between different elements and, hence, (iii) the need for further experiments in the laboratory, the field and analogue studies. An overview of the theoretical concepts of sorption, experimental methodology and data interpretation is given in order to put the values into context. General problem areas are identified. (Auth.)

  10. Radionuclide sorption kinetics and column sorption studies with Columbia River basalts

    International Nuclear Information System (INIS)

    Barney, G.S.

    1983-09-01

    The kinetics of radionuclide sorption and desorption reactions in basalt-groundwater systems were evaluated at 60 degrees C using a batch equilibration method. It was found that many sorption reactions on surfaces of fresh (unaltered) basalt from the Umtanum and Cohassett flows are slow. Some reactions require more than 50 days to reach a steady state. Sorption of neptunium and uranium in oxidizing (air saturated) groundwater appears to be controlled by slow reduction of these elements by the basalt surfaces. The resulting lower oxidation states are more strongly sorbed. Technetium and selenium, which are anionic under oxidizing conditions, are not measurably sorbed on fresh basalt surfaces, but are slightly sorbed on the altered surfaces of flow top basalt. Under reducing conditions, where the groundwater contains dilute hydrazine, sorption is faster for neptunium, uranium, technetium, selenium, and lead. Plutonium sorption rates were not affected by the groundwater Eh. It was shown that radium was precipitated rather than sorbed under the conditions of these experiments. Umtanum flow top material sorbed radionuclides much faster than fresh basalt surfaces due to its greater surface area and cation exchange capacity. Desorption rates for plutonium, uranium, neptunium, technetium, and selenium were generally much less than sorption rates (especially for reducing conditions). These radionuclides are irreversibly sorbed on the basalts. 25 refs., 20 figs., 19 tabs

  11. Radionuclide sorption on crushed and intact granitic rock

    International Nuclear Information System (INIS)

    Eriksen, Tryggve E.; Locklund, Birgitta

    1989-05-01

    The specific surface areas and distribution ratios for sorption of 85 Sr, 137 Cs and 152 Eu were measured for crushed and intact granite rock. The experimental data can be accommodated by a sorption model encompassing sorption on outer and inner surface. It is clearly demonstrated that the time required to obtain reliable Kd-values for the sorption of strongly sorbing radionuclides like 152 Eu is very long due to solution depletion and slow diffusion into the rock. A combination of surface area measurements and batch sorption with small particles may therefore be preferable when studying strongly sorbing nuclides. (authors) (17 figs., 6 tabs.)

  12. Sorption and migration of neptunium in porous sedimentary materials

    International Nuclear Information System (INIS)

    Tanaka, Tadao; Mukai, Masayuki; Nakayama, Shinichi

    2005-01-01

    Column migration experiments of neptunium were conducted for porous sedimentary materials: coastal sand, tuffaceous sand, ando soil, reddish soil, yellowish soil and loess, and migration behavior, sorption mechanisms and chemical formation of Np were investigated. The migration behavior of Np in each material was much different each other, due to chemical formation in solution and/or sorption mechanism of Np. Mathematical models of different concepts were applied to the experimental results to interpret the sorption mechanism and the migration behavior. It can be concluded that both of instantaneous equilibrium sorption and sorption-desorption kinetics have to be considered to model the Np migration in sedimentary materials. (author)

  13. Sorption of 4-ethylphenol and 4-ethylguaiacol by suberin from cork.

    Science.gov (United States)

    Gallardo-Chacón, Joan-Josep; Karbowiak, Thomas

    2015-08-15

    Cork shows an active role in the sorption of volatile phenols from wine. The sorption properties of 4-ethylphenol and 4-ethylguaiacol phenols in hydro-alcoholic medium placed in contact with suberin extracted from cork were especially investigated. To that purpose, suberin was immersed in model wine solutions containing several concentrations of each phenol and the amount of the compound remaining in the liquid phase was determined by SPME-GC-MS. Sorption isotherms of 4-ethylguaiacol and 4-ethylphenol by suberin followed the Henry's model. The solid/liquid partition coefficients (KSL) between the suberin and the model wine were also determined for several other volatile phenols. Suberin displayed rather high sorption capacity, which was positively correlated to the hydrophobicity of the volatile. Finally, the capacity of suberin to decrease the concentration of 4-ethylphenol and 4-ethylguaiacol was also tested in real wines affected by a Brettanomyces character. It also lead to a significant reduction of their concentration in wine. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Sorption of niobium on boreal forest soil

    Energy Technology Data Exchange (ETDEWEB)

    Soederlund, Mervi; Hakanen, Martti; Lehto, Jukka [Helsinki Univ. (Finland). Lab. of Radiochemistry

    2015-07-01

    The sorption of niobium (Nb) was investigated on humus and mineral soil samples taken from various depths of a four-metre deep forest soil pit on Olkiluoto Island, southwestern Finland. Mass distribution coefficients, K{sub d}, were determined in batch sorption tests. The steady state of Nb sorption was observed in the mineral soil samples already after one week of equilibration, and sorption decreased with depth from a very high value of 185000 mL/g at 0.7 m to 54000 mL/g at 3.4 m. The reason behind this decrease is probably the tenfold reduction in the specific surface area of the soil at the same depth range. Distribution coefficients were clearly lower in the humus layer (1000 mL/g). The K{sub d} values determined in pure water at a pH range of 4.7-6.5 were at a high level (above 55000 mL/g), but decreased dramatically above pH 6.5, corresponding to the change in the major Nb species from the neutral Nb(OH){sub 5} to the low-sorbing anionic Nb(OH){sub 6}{sup -} and Nb(OH){sub 7}{sup 2-}. However, the K{sub d} values in the model soil solution were in the slightly alkaline range an order of magnitude higher than in pure water, which is probably caused by the formation of calcium niobate surface precipitate or electrostatic interaction between surface-sorbed calcium and solute Nb. Among nine soil constituent minerals kaolinite performed best in retaining Nb in both pure water and model soil solution at pH 8, whereas potassium feldspar showed the poorest sorption. The K{sub d} value for kaolinite was above 500000 mL/g in both solutions, while the respective potassium feldspar values were in the range of 120-220 mL/g.

  15. Sorption behaviour of perfluoroalkyl substances in soils.

    Science.gov (United States)

    Milinovic, Jelena; Lacorte, Silvia; Vidal, Miquel; Rigol, Anna

    2015-04-01

    The sorption behaviour of three perfluoroalkyl substances (PFASs), perfluorooctane sulfonic acid (PFOS), perfluorooctanoic acid (PFOA) and perfluorobutane sulfonic acid (PFBS), was studied in six soils with contrasting characteristics, especially in the organic carbon content. Sorption isotherms were obtained by equilibrating the soil samples with 0.01 mol L(-1) CaCl2 solutions spiked with increasing concentrations of the target PFAS. The sorption reversibility of PFASs was also tested for some of the samples. Liquid chromatography coupled to tandem mass spectrometry was used to quantify the target PFASs in the solutions. Both the Freundlich and linear models were appropriate to describe the sorption behaviour of PFASs in soils, and enabled us to derive solid-liquid distribution coefficients (Kd) for each compound in each soil. Kd values increased from 19 to 295 mL g(-1) for PFOS, from 2.2 to 38 mL g(-1) for PFOA and from 0.4 to 6.8 mL g(-1) for PFBS, and were positively correlated with the organic carbon content of the soil. KOC values obtained from the correlations were 710, 96 and 17 mL g(-1) for PFOS, PFOA and PFBS, respectively. Whereas Kd values decreased in the sequence PFOS>PFOA>PFBS, desorption yields were lower than 13% for PFOS, from 24 to 58% for PFOA, and from 32 to 60% for PFBS. This shows that the physicochemical characteristics of PFASs, basically their hydrophobicity, controlled their sorption behaviour in soils, with PFOS being the most irreversibly sorbed PFAS. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Modeling Fission Product Sorption in Graphite Structures

    International Nuclear Information System (INIS)

    Szlufarska, Izabela; Morgan, Dane; Allen, Todd

    2013-01-01

    The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high-temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission products

  17. SORPTION OF Au(III BY Saccharomyces cerevisiae BIOMASS

    Directory of Open Access Journals (Sweden)

    Amaria Amaria

    2010-07-01

    Full Text Available Au(III sorption by S. cerevisiae biomass extracted from beer waste industry was investigated. Experimentally, the sorption was conducted in batch method. This research involved five steps: 1 identification the functional groups present in the S. cerevisiae biomass by infrared spectroscopic technique, 2 determination of optimum pH, 3 determination of the sorption capacity and energy, 4 determination of the sorption type by conducting desorption of sorbed Au(III using specific eluents having different desorption capacity such as H2O (van der Waals, KNO3 (ion exchange, HNO3 (hydrogen bond, and tiourea (coordination bond, 5 determination of effective eluents in Au(III desorption by partial desorption of sorbed Au(III using thiourea, NaCN and KI. The remaining Au(III concentrations in filtrate were analyzed using Atomic Absorption Spectrophotometer. The results showed that: 1 Functional groups of S. cerevisiae biomass that involved in the sorption processes were hydroxyl (-OH, carboxylate (-COO- and amine (-NH2, 2 maximum sorption was occurred at pH 4, equal to 98.19% of total sorption, 3 The sorption capacity of biomass was 133.33 mg/g (6.7682E-04 mol/g and was involved sorption energy 23.03 kJ mol-1, 4 Sorption type was dominated by coordination bond, 5 NaCN was effective eluent to strip Au(III close to 100%.   Keywords: sorption, desorption, S. cerevisiae biomass, Au(III

  18. Thermodynamic sorption modelling in support of radioactive waste disposal safety cases - NEA sorption project phase III

    International Nuclear Information System (INIS)

    2012-01-01

    A central safety function of radioactive waste disposal repositories is the prevention or sufficient retardation of radionuclide migration to the biosphere. Performance assessment exercises in various countries, and for a range of disposal scenarios, have demonstrated that one of the most important processes providing this safety function is the sorption of radionuclides along potential migration paths beyond the engineered barriers. Thermodynamic sorption models (TSMs) are key for improving confidence in assumptions made about such radionuclide sorption when preparing a repository's safety case. This report presents guidelines for TSM development as well as their application in repository performance assessments. They will be of particular interest to the sorption modelling community and radionuclide migration modellers in developing safety cases for radioactive waste disposal Contents: 1 - Thermodynamic sorption models and radionuclide migration: Sorption and radionuclide migration; Applications of TSMs in radioactive waste disposal studies; Requirements for a scientifically defensible, calibrated TSM applicable to radioactive waste disposal; Current status of TSMs in radioactive waste management; 2 - Theoretical basis of TSMs and options in model development: Conceptual building blocks of TSMs and integration with aqueous chemistry; The TSM representation of sorption and relationship with Kd values; Theoretical basis of TSMs; Example of TSM for uranyl sorption; Options in TSM development; Illustration of TSM development and effects of modelling choices; Summary: TSMs for constraining Kd values - impact of modelling choices; 3 - Determination of parameters for TSMs: Overview of experimental determination of TSM parameters; Theoretical estimation methods of selected model parameters; Case study: sorption modelling of trivalent lanthanides/actinides on illite; Indicative values for certain TSM parameters; Parameter uncertainty; Illustration of parameter sensitivity

  19. Place Branding in Systems of Place

    DEFF Research Database (Denmark)

    Zenker, Sebastian; Andéhn, Mikael

    2015-01-01

    , this presents a challenge, since the role of a place in this system of geographical abstractions constitutes a piece of information more vital than any other in defining the place. Our understanding of places cannot be separated from their scale, and any effort at managing the reputation and meaning.......g. the European Union or Africa). Using the example of nation branding for Sudan and Slovenia, one can identify supranational places such as “sub-Saharan Africa” or “Eastern Europe”, carrying their own highly salient and often negative meaning in much of the Western world. We explore how association to a system...

  20. Defluoridation by Bacteriogenic Iron Oxides: Sorption Studies

    Science.gov (United States)

    Evans, K.; Ferris, F.

    2009-05-01

    At concentrations above 1 mg/L, fluoride in drinking water can lead to dental and skeletal fluorosis, a disease that causes mottling of the teeth, calcification of ligaments, crippling bone deformities and many other physiological disorders that can, ultimately, lead to death. Conservative estimates are that fluorosis afflicts tens of millions of people worldwide. As there is no treatment for fluorosis, prevention is the only means of controlling the disease. While numerous defluoridation techniques have been explored, no single method has been found to be both effective and inexpensive enough to implement widely. Our research began in India, with a large-scale geochemical study of the groundwater in a fluoride-contaminated region of Orissa. Having developed a better understanding of the geochemical relationships that exist between fluoride and other parameters present in an affected area, as well as the complex relationships that arise among those parameters that can impact the presence of fluoride, we began investigating certain remediation scenarios involving iron oxides. A common approach to remediation involves the partitioning of fluoride from groundwater by sorption onto a variety of materials, one of the most effective of which is iron oxide whose surface area acts as a scavenger for fluoride. In the presence of iron oxidizing bacteria, the oxidation rate of iron has been shown to be ˜6 times greater than in their absence; fluoride should, therefore, be removed from an aqueous environment by bacteriogenic iron oxides (BIOS) much more quickly than by abiotic iron oxides. Most recently, sorption studies have been conducted using both BIOS and synthetic hydrous ferric oxides in order to compare the behavior between biotic and abiotic sorbents. These studies have provided sorption isotherms that allow comparison of fluoride removed by sorption to BIOS versus synthetic iron oxides. Sorption affinity constants have also been determined, which allow for the

  1. Isotherm, kinetic, and thermodynamic study of ciprofloxacin sorption on sediments.

    Science.gov (United States)

    Mutavdžić Pavlović, Dragana; Ćurković, Lidija; Grčić, Ivana; Šimić, Iva; Župan, Josip

    2017-04-01

    In this study, equilibrium isotherms, kinetics and thermodynamics of ciprofloxacin on seven sediments in a batch sorption process were examined. The effects of contact time, initial ciprofloxacin concentration, temperature and ionic strength on the sorption process were studied. The K d parameter from linear sorption model was determined by linear regression analysis, while the Freundlich and Dubinin-Radushkevich (D-R) sorption models were applied to describe the equilibrium isotherms by linear and nonlinear methods. The estimated K d values varied from 171 to 37,347 mL/g. The obtained values of E (free energy estimated from D-R isotherm model) were between 3.51 and 8.64 kJ/mol, which indicated a physical nature of ciprofloxacin sorption on studied sediments. According to obtained n values as measure of intensity of sorption estimate from Freundlich isotherm model (from 0.69 to 1.442), ciprofloxacin sorption on sediments can be categorized from poor to moderately difficult sorption characteristics. Kinetics data were best fitted by the pseudo-second-order model (R 2  > 0.999). Thermodynamic parameters including the Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) were calculated to estimate the nature of ciprofloxacin sorption. Results suggested that sorption on sediments was a spontaneous exothermic process.

  2. Testosterone sorption and desorption: Effects of soil particle size

    Energy Technology Data Exchange (ETDEWEB)

    Qi, Yong, E-mail: yqi01@unomaha.edu [Civil Engineering Dept., University of Nebraska-Lincoln at Omaha Campus, Omaha, NE 68182 (United States); Zhang, Tian C. [Civil Engineering Dept., University of Nebraska-Lincoln at Omaha Campus, Omaha, NE 68182 (United States); Ren, Yongzheng [School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2014-08-30

    Graphical abstract: - Highlights: • Smaller soil particles have higher sorption and lower desorption rates. • The sorption capacity ranks as clay > silt > sand. • Small particles like clays have less potential for desorption. • Colloids (clays) have high potential to facilitate the transport of hormones in soil–water environments. - Abstract: Soils contain a wide range of particles of different diameters with different mobility during rainfall events. Effects of soil particles on sorption and desorption behaviors of steroid hormones have not been investigated. In this study, wet sieve washing and repeated sedimentation methods were used to fractionate the soils into five ranges. The sorption and desorption properties and related mechanisms of testosterone in batch reactors filled with fractionated soil particles were evaluated. Results of sorption and desorption kinetics indicate that small soil particles have higher sorption and lower desorption rates than that of big ones. Thermodynamic results show the sorption processes are spontaneous and exothermal. The sorption capacity ranks as clay > silt > sand, depending mainly on specific surface area and surface functional groups. The urea control test shows that hydrogen bonding contributes to testosterone sorption onto clay and silt but not on sand. Desorption tests indicate sorption is 36–65% irreversible from clay to sand. Clays have highest desorption hysteresis among these five soil fractions, indicating small particles like clays have less potential for desorption. The results provide indirect evidence on the colloid (clay)-facilitated transport of hormones (micro-pollutants) in soil environments.

  3. Effect of natural organic materials on cadmium and neptunium sorption

    International Nuclear Information System (INIS)

    Kung, K.S.; Triay, I.R.

    1994-01-01

    In a batch sorption study of the effect of naturally occurring organic materials on the sorption of cadmium and neptunium on oxides and tuff surfaces, the model sorbents were synthetic goethite, boehmite, amorphous silicon oxides, and a crushed tuff material from Yucca Mountain, Nevada. An amino acid, 3-(3,4-dihydroxypheny)-DL-alanine (DOPA), and an aquatic-originated fulvic material, Nordic aquatic fulvic acid (NAFA), were used as model organic chemicals. Sorption isotherm results showed that DOPA sorption followed the order aluminum oxide > iron oxide > silicon oxide and that the amount of DOAP sorption for a given sorbent increased as the solution pH was raised. The sorption of cadmium and neptunium on the iron oxide was about ten times higher than that on the aluminum oxide. The sorption of cadmium and neptunium on natural tuff material was much lower than that on aluminum and iron oxides. The sorption of cadmium on iron and aluminum oxides was found to be influenced by the presence of DOPA, and increasing the amount of DOPA coating resulted in higher cadmium sorption on aluminum oxide. However, for iron oxide, cadmium sorption decreased with increasing DOPA concentration. The presence of the model organic materials DOPA and NAFA did not affect the sorption of neptunium on tuff material or on the iron and aluminum oxides. Spectroscopic results indicate that cadmium complexes strongly with DOPA. Therefore, the effect of the organic material, DOPA, on the cadmium sorption is readily observed. However, neptunium is possibly complexed weakly with organic material. Thus, DOPA and NAFA have little effect on neptunium sorption on all sorbents selected for study

  4. Sorption of actinides in granitic rock

    International Nuclear Information System (INIS)

    Allard, B

    1982-11-01

    The sorption of americium (III), neptunium(V) and plutonium on geologic media under oxic conditions has been measured by a batch technique. The aqueous phase was a synthetic groundwater or 4M NaCl solution. The solid phase was a pure mineral, representative of igneous rocks, or granite. Altogether 40 different minerals and rocks were used. The effects of pH and the ionic strength of the aqueous phase as well as of the cation exchange capacity and the surface/mass ratio of the solid sorbent are discussed. Empirical equations giving the distribution coefficient as a function of pH in the environmental pH-range 7-9 are suggested. Some observations and conclusions concerning sorption mechanisms are given. (author)

  5. Sorption of zinc on human teeth

    International Nuclear Information System (INIS)

    Helal, A.; Amin, H.; Alian, G.

    1997-01-01

    Zinc containing dental amalgams are sometimes used as fillings by dentists. The freshly mixed mass of the amalgam alloy and liquid mercury packed or condensed into a prepared tooth cavity. Zinc has been included in amalgams alloys up to 2% as an aid in manufacturing by helping to produce clean sound castings of the ingots. Although such restorations have a relatively long service life, they are subject to corrosion and galvanic action, thus releasing metallic products into the oral environment. The aim of this paper is to investigate the uptake (sorption) of Zinc ionic species on human teeth using the radioactive tracer technique. For this purpose the isotope Zn-65 produced from pile-irradiation of zinc metal was used. The various liquids studied were drinking water (tap water), tea, coffee, red tea and chicken soup. Sorption was studied through immersion of a single human tooth (extracted) in each of these liquids

  6. Sorption of 60 Co on inorganic solids

    International Nuclear Information System (INIS)

    Granados C, F.; Bulbulian G, S.; Mardel V, B.

    2003-01-01

    The behavior of sorption of the 60 Co in aqueous solution under static conditions to different values of pH of the aqueous solution (1, 3, 5, 7, and 10) on MgO, MnO 2 , SnO, TiO 2 , activated carbon and calcinate hydrotalcite was investigated. It was found that the best sorbents of the 60 Co was the MnO 2 , activated carbon and TiO 2 whose sorption was incremented when increasing the pH value of the aqueous solutions, in the one case of the hydrated oxides, the 60 Co interacted with the electrically charged surface of the sorbents that depends on the pH of the solution and of the point of zero charge (zpc) of the sorbent. (Author)

  7. Noble metal extraction and sorption concentrating

    International Nuclear Information System (INIS)

    Petrukhin, O.M.; Malofeeva, G.I.

    1985-01-01

    Works performed in the USSR Academy of Sciences GEOCHI laboratory of extraction methods and devoted to selectivity problems of extraction and sorption methods of platinum metal, cadmium and indium concentrating in analytical chemistry are discussed. On choosing complexino. reagent main attention is paid to the selectivity variation based on different stability of metal complexes. Platinum metals are extracted in the form of ion associates when usinq hard, mainly oxyqen-containing, extractants. Coordination-solvated metal complexes are extracted white usinq extractants containing sulfur, trivalent phosphorus and aromatic nitroqen as donor anions. Selectivity is maximum for sulfur- and nitroren-containinq extractants and sorbents. In case of the group extraction of platinum metals sorption is preferable and in case of selective extraction of individual metals, especially, in case of need of relative concentratinq extraction is preferable

  8. Uranium sorption on tezontle volcanic rock

    International Nuclear Information System (INIS)

    Lopez M, B. E.; Duran B, J. M.; Iturbe G, J. L.; Olguin G, M. T.

    2009-01-01

    It is described a study that demonstrates that hexavalent uranium ions were sorbed by the naturally occurring mineral using a batch technique. This mineral is found in abundant quantities in Mexico. Our study focused on the separation of U Vi from synthetic aqueous systems of both H 2 O-UO 2 (NO 3 ) 2 .6H 2 O (acid) and H 2 O-Na 4 [UO 2 (CO 3 ) 3 ] (basic). The chemical speciation was performed by using high voltage electrophoresis, and the uranium content was determined by UV-Vis spectroscopy. The quantified U(Vi) sorption by tezontle from acidic and basic systems was 2.72 and 1.68 μmol/g, respectively, and the sorption behavior is discussed considering the surface charge of the tezontle at different ph values based on the point of zero charge characteristic of this material. (Author)

  9. Sorption of phenanthrene on agricultural soils

    DEFF Research Database (Denmark)

    Soares, Antonio; Møldrup, Per; Minh, Luong Nhat

    2013-01-01

    Polyaromatic hydrocarbon (PAH) sorption to soil is a key process deciding the transport and fate of PAH, and potential toxic impacts in the soil and groundwater ecosystems, for example in connection with atmospheric PAH deposition on soils. There are numerous studies on PAH sorption in relatively......, 0.25–1-m depth) by the single-point adsorption method. The organic carbon partition coefficient, KOC (liter per kilogram) for topsoils was found generally to fall between the KOC values estimated by the two most frequently used models for PAH partitioning, the Abdul et al. (Hazardous Waste...... & Hazardous Materials 4(3):211–222, 1987) model and Karickhoff et al. (Water Research 13:241–248, 1979) model. A less-recognized model by Karickhoff (Chemosphere 10:833–846, 1981), yielding a KOC of 14,918 L kg−1, closely corresponded to the average measured KOC value for the topsoils, and this model...

  10. Sorption of radionuclides on London clay

    International Nuclear Information System (INIS)

    Berry, J.A.; Bourke, P.J.; Green, A.; Littleboy, A.K.

    1989-02-01

    Techniques for studying the sorption of radionuclides on London clay have been investigated. This work involved the use of through-diffusion, in-diffusion, high-pressure convection and batch methods to study the sorption of iodide, strontium, caesium and americium. Through-diffusion and high-pressure convection methods were found to be most useful for investigating weakly and moderately sorbing nuclides and give realistic values for sorptivity. The batch technique remains the most practical method of obtaining large quantities of data within a relatively short timescale but gives very high sorptivity values. It is however very useful for intercomparisons of nuclides or geological media. The in-diffusion method requires further refinement for use with strongly sorbing nuclides. Good agreement between through-diffusion and high-pressure convection methods was obtained for the sorptivity of strontium, whilst trends observed for caesium by through-diffusion were confirmed by batch measurements. (author)

  11. Sorption studies of radioelements on geological materials

    International Nuclear Information System (INIS)

    Berry, John A.; Yui, Mikazu; Kitamura, Akira

    2007-11-01

    Batch sorption experiments have been carried out to study the sorption of uranium, technetium, curium, neptunium, actinium, protactinium, polonium, americium and plutonium onto bentonite, granodiorite and tuff. Mathematical modelling using the HARPHRQ program and the HATCHES database was carried out to predict the speciation of uranium and technetium in the equilibrated seawater, and neptunium, americium and plutonium in the rock equilibrated water. Review of the literature for thermodynamic data for curium, actinium, protactinium and polonium was carried out. Where sufficient data were available, predictions of the speciation and solubility were made. This report is a summary report of the experimental work conducted by AEA Technology during April 1991-March 1998, and the main results have been presented at Material Research Society Symposium Proceedings and published as proceedings of them. (author)

  12. Sorption behaviour of herbicides in soils

    International Nuclear Information System (INIS)

    Luchini, L.C.; Wiendl, F.M.; Ruegg, E.F.; Instituto Biologico, Sao Paulo

    1988-01-01

    Environmental contamination by herbicides is related with the sorption phenomenon of these compounds in the soils. The behaviour of paraquat, 2,4-D and diuron was studied in soils with different physico-chemical properties, through the Freundlich adsorption and desorption isotherms, using 14 C-radiolabeled herbicides. Results of the range of the adsorption-desorption of each herbicide was related mainly with the chemical characteristics of these compounds. (author) [pt

  13. Phosphate sorption characteristics of European alpine soils

    Czech Academy of Sciences Publication Activity Database

    Kaňa, Jiří; Kopáček, Jiří; Camarero, L.; Garcia-Pausas, J.

    2011-01-01

    Roč. 75, č. 3 (2011), s. 862-870 ISSN 0361-5995 R&D Projects: GA ČR(CZ) GA526/09/0567; GA AV ČR(CZ) KJB600960907 Grant - others:EU EMERGE(CZ) EVK1-CT-1999-00032 Institutional research plan: CEZ:AV0Z60170517 Keywords : phosphate sorption * alpine soil s * acidification Subject RIV: DJ - Water Pollution ; Quality Impact factor: 1.979, year: 2011

  14. Moisture sorption isotherms of dehydrated whey proteins

    Directory of Open Access Journals (Sweden)

    Suzana Rimac Brnčić

    2010-03-01

    Full Text Available Moisture sorption isotherms describe the relation between the moisture content of the dry material (food and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as monolayer value of two commercial powdered whey protein isolates before and after tribomechanical micronisation and enzymatic hydrolysis, respectively. At the same time it was necessary to evaluate the best moisture sorption isotherm equation to fit the experimental data. The equilibrium moisture contents in investigated samples were determined using standard gravimetric method at 20 °C. The range of water activities was 0.11 to 0.75. The monolayer moisture content was estimated from sorption data using Brunauer-Emmett-Teller (BET and Guggenheim-Anderson-de Boer (GAB models. The results have shown that tribomechanically treated whey protein isolates as well as protein hydrolizates had lower monolayer moisture content values as well as higher corresponding water activity. Therefore, in spite of the fact that they have lower moisture content, they can be storage at higher relative humidity compared to untreated samples. BET model gave better fit to experimental sorption data for a water activity range from 0.11-0.54, while GAB model gave the closest fit for a water activity to 0.75.

  15. Moisture sorption isotherms of dehydrated whey proteins

    OpenAIRE

    Suzana Rimac Brnčić; Vesna Lelas; Zoran Herceg; Marija Badanjak

    2010-01-01

    Moisture sorption isotherms describe the relation between the moisture content of the dry material (food) and relative humidity of the surrounding environment. The data obtained are important in modelling of drying process conditions, packaging and shelf-life stability of food that will provide maximum retaining of aroma, colour and texture as well as nutritive and biological value. The objective of this research was to establish the equilibrium moisture content and water activity, as well as...

  16. Sorption studies of caesium by complex hexacyanoferrates

    International Nuclear Information System (INIS)

    Jacobi, D.

    1992-01-01

    A comprehensive literature review was carried out on the preparation of complex hexacyanoferrates in a granular form suitable for use in a packed column. The preparation of sodium nickel hexacyanoferrate using a freeze-thaw method was studied in detail and a method developed to produce a consistent and reproducible granular product. The equilibrium and sorption kinetics were studied using batch and column tests, and the process modelled to predict performance under various conditions. (author)

  17. Sorption of antimony on human teeth

    International Nuclear Information System (INIS)

    Nofal, M.; Amin, H.; Alian, G.

    1997-01-01

    The study of the uptake of toxic elements on human teeth represents an interesting research area, as the fate of these elements when present in the human food is of health significance. Since antimony is one of the common toxic elements and since, the chemical behaviour of antimony is similar to that of arsenic, one of the most important toxic elements commonly encountered in cases of food poisoning, it has been decided to investigate its uptake on human teeth and on other restoration materials. The radioactive tracer technique was used to evaluate the concentration of antimony sorbed on teeth. This tracer was obtained by irradiation of antimony metal in the reactor, subsequent dissolution in concentrated sulphuric acid, evaporation to dryness and making the solution 6 M in Hydrochloric acid (1). Antimony prepared in this way is in the trivalent state (Sb III). Sorption was studied in water, tea, coffee, red tea and chicken soup. The highest sorption was achieved from water and chicken soup and least sorption was noticed in case of coffee. The results are presented in the form of the depletion of the radioactivity (A) of antimony with time in presence of a tooth in water and other drinks

  18. Sorption of radon-222 to natural sediments

    International Nuclear Information System (INIS)

    Wong, C.S.; Chin, Y.P.; Gschwend, P.M.

    1992-01-01

    The sorption of radon to sediments was investigated, since this may affect the use of porewater radon profiles for estimating bed irrigation rates. Batch experiments showed that radon has an organic-carbon-normalized sediment-water partition coefficient (K oc , L kg oc -1 ) of 21.1 ± 2.9 for a Boston Harbor sediment, 25.3 ± 2.1 for a Charles River sediment, and 22.4 ± 2.6 for a Buzzards Bay sediment. These values are in close agreement with predictions using radon's octanol-water partition coefficient (K ow ), which was measured to be 32.4 ± 1.5. Temperature and ionic strength effects on K oc were estimated to be small. Given rapid sorption kinetics, the authors suggest that slurry stripping techniques used by many investigators to measure 222 Rn in sediment samples collect both sorbed and dissolved radon. Sorption effects were included in a transport model to obtain revised estimates of irrigation rates from existing literature profiles. Irrigation rates had to be increased over previously reported values in proportion to the sediment organic matter content

  19. Radionuclide sorption studies on abyssal red clays

    International Nuclear Information System (INIS)

    Erickson, K.L.

    1979-01-01

    The radionuclide sorption properties of a widely distributed abyssal red clay are being experimentally investigated using batch equilibration techniques. This paper summarizes sorption equilibrium data obtained when 0.68 N NaCl solutions containing either Tc, U, Pu, Am or Cm were contacted with samples of the red clay and also summarizes some initial results from experiments designed to determine the relative selectivity of the clay for various nuclides. Under mildly oxidizing conditions, the sorption equilibrium distribution coefficients for technetium were essentially zero. At solution-phase nuclide concentrations on the order of 10 -6 M and less and at solution pH values of about 6.9, the distribution coefficients for plutonium were about 3 x 10 3 m1/gm and for uranium, americium, and curium were about 10 5 ml/gm or greater. However, at solution pH values of about 2.7, the distribution coefficients for each of the nuclides were greatly diminished. Initial experiments conducted in order to determine the relative selectivity of the clay for cesium, barium, and cerium, indicated that the silicate phases in the clay were selective for cesium over barium and cerium. These experiments also indicated that the hydrous oxide phases were selective for cerium over barium and for barium over cesium

  20. Physical-chemical hydrodynamics of the processes of sorption-membrane technology of LRW treatment

    International Nuclear Information System (INIS)

    Alexander D Efanov; Pyotr N Martynov; Yuri D Boltoev; Ivan V Yagodkin; Nataliya G Bogdanovich; Sergey S Skvortsov; Alexander R Sokolovsky; Elena V Ignatova; Gennady V Grigoriev; Vitaly V Grigorov

    2005-01-01

    Full text of publication follows: Liquid radioactive NPP waste is generated, when radioactive water is collected and mixed from various routine and non-routine process measures being performed in accordance with the operating regulations of reactor units with water coolant. The main sources of LRW are the primary loop water coolant, deactivation, regeneration and rinse waters, waste laundry and showers water producing the initial averaged LRW as well as spent fuel element cooling pond water and water of biological protection tanks. LRW handling can be substantially advanced, in particular, through development and introduction of the non-conventional sorption-membrane technology of NPP LRW treatment, being developed at SSC RF IPPE. This technology makes use of natural inorganic sorbents (tripolite, zeolite, ion-exchange materials) and filtering nano-structured metallic and ceramic membranes (titanium, zirconium, chromium and other or their oxides, carbides and nitrides). The efficiency of the sorption membrane technology is associated just with the investigation of the physical-chemical processes of sorption, coagulation and sedimentation under the conditions of forced and free convection occurring in LRW. Besides, it is necessary to take into consideration that the hydrodynamics of the flows of LRW being decontaminated by membrane filtration depends on the structure and composition of the porous composition pare 'nano-structured membrane-substrate'. Neglecting these peculiarities can result in drastic reduction of the time of stable LRW filtration, reduction of the operability resource of filtration systems or in quick mechanical destruction of porous materials. The paper presents the investigation results on: -the effect of the convection flows being generated by air bubbling or LRW stirring by agitator on the static sorption conditions (sorption time, medium pH, sorbent dispersity, sorbent concentration in liquid medium) and on the efficiency of extraction by

  1. Continuing bonds and place.

    Science.gov (United States)

    Jonsson, Annika; Walter, Tony

    2017-08-01

    Where do people feel closest to those they have lost? This article explores how continuing bonds with a deceased person can be rooted in a particular place or places. Some conceptual resources are sketched, namely continuing bonds, place attachment, ancestral places, home, reminder theory, and loss of place. The authors use these concepts to analyze interview material with seven Swedes and five Britons who often thought warmly of the deceased as residing in a particular place and often performing characteristic actions. The destruction of such a place, by contrast, could create a troubling, haunting absence, complicating the deceased's absent-presence.

  2. Mathematical Modeling of Moisture Sorption Isotherms and Determination of Isosteric Heats of Sorption of Ziziphus Leaves

    Directory of Open Access Journals (Sweden)

    Amel Saad

    2014-01-01

    Full Text Available Desorption and adsorption equilibrium moisture isotherms of Ziziphus spina-christi leaves were determined using the gravimetric-static method at 30, 40, and 50°C for water activity (aw ranging from 0.057 to 0.898. At a given aw, the results show that the moisture content decreases with increasing temperature. A hysteresis effect was observed. The experimental data of sorption were fitted by eight models (GAB, BET, Henderson-Thompson, modified-Chung Pfost, Halsey, Oswin, Peleg, and Adam and Shove. After evaluating the models according to several criteria, the Peleg and Oswin models were found to be the most suitable for describing the sorption curves. The net isosteric heats of desorption and adsorption of Ziziphus spina-christi leaves were calculated by applying the Clausius-Clapeyron equation to the sorption isotherms and an expression for predicting these thermodynamic properties was given.

  3. Investigation of metal ions sorption of brown peat moss powder

    Science.gov (United States)

    Kelus, Nadezhda; Blokhina, Elena; Novikov, Dmitry; Novikova, Yaroslavna; Chuchalin, Vladimir

    2017-11-01

    For regularities research of sorptive extraction of heavy metal ions by cellulose and its derivates from aquatic solution of electrolytes it is necessary to find possible mechanism of sorption process and to choice a model describing this process. The present article investigates the regularities of aliovalent metals sorption on brown peat moss powder. The results show that sorption isotherm of Al3+ ions is described by Freundlich isotherm and sorption isotherms of Na+ i Ni2+ are described by Langmuir isotherm. To identify the mechanisms of brown peat moss powder sorption the IR-spectra of the initial brown peat moss powder samples and brown peat moss powder samples after Ni (II) sorption were studied. Metal ion binding mechanisms by brown peat moss powder points to ion exchange, physical adsorption, and complex formation with hydroxyl and carboxyl groups.

  4. Sorption of citalopram, irbesartan and fexofenadine in soils: Estimation of sorption coefficients from soil properties.

    Science.gov (United States)

    Klement, Aleš; Kodešová, Radka; Bauerová, Martina; Golovko, Oksana; Kočárek, Martin; Fér, Miroslav; Koba, Olga; Nikodem, Antonín; Grabic, Roman

    2018-03-01

    The sorption of 3 pharmaceuticals, which may exist in 4 different forms depending on the solution pH (irbesartan in cationic, neutral and anionic, fexofenadine in cationic, zwitter-ionic and anionic, and citalopram cationic and neutral), in seven different soils was studied. The measured sorption isotherms were described by Freundlich equations, and the sorption coefficients, K F (for the fixed n exponent for each compound), were related to the soil properties to derive relationships for estimating the sorption coefficients from the soil properties (i.e., pedotransfer rules). The largest sorption was obtained for citalopram (average K F value for n = 1 was 1838 cm 3  g -1 ) followed by fexofenadine (K F  = 35.1 cm 3/n μg 1-1/n g -1 , n = 1.19) and irbesartan (K F  = 3.96 cm 3/n μg 1-1/n g -1 , n = 1.10). The behavior of citalopram (CIT) in soils was different than the behaviors of irbesartan (IRB) and fexofenadine (FEX). Different trends were documented according to the correlation coefficients between the K F values for different compounds (R IRB,FEX  = 0.895, p-valuesoil properties in the pedotransfer functions. While the K F value for citalopram was positively related to base cation saturation (BCS) or sorption complex saturation (SCS) and negatively correlated to the organic carbon content (Cox), the K F values of irbesartan and fexofenadine were negatively related to BCS, SCS or the clay content and positively related to Cox. The best estimates were obtained by combining BCS and Cox for citalopram (R 2  = 93.4), SCS and Cox for irbesartan (R 2  = 96.3), and clay content and Cox for fexofenadine (R 2  = 82.9). Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Influence of selected factors on strontium sorption on bentonites

    International Nuclear Information System (INIS)

    Galambos, M.; Kufcakova, J.; Rajec, P.

    2007-01-01

    Sorption on bentonite will play an important role in retarding the migration of radionuclides from a waste repository. Bentonite is a natural clay and one of the most promising candidates for use as a buffer material in the geological disposal systems for high-level nuclear waste. It is intended to isolate metal canisters with highly radioactive waste products from the surrounding rocks because of its ability to retard the movement of radionuclides by sorption. Bentonite is characterized by low permeability, water swelling capability and excellent sorption potential for cationic radionuclides. To correctly assess the sorption potential of radionuclides on bentonite is essential for the development of predictive migration models. The sorption of strontium on bentonite from different Slovak deposits - Jelsovy potok, Kopernica and Lieskovec has been investigated under various experimental conditions, such as contact time, sorbate concentrations, presence of complementary cation. Sorption was studied using the batch technique. The uptake of Sr was rapid and equilibrium was reached almost instantaneously. The instantaneous uptake may be due to adsorption and/or exchange of the metal with some ions on the surface of the adsorbent. The best sorption characteristics distinguish bentonite Kopernica, sorption capacity for Sr of the fraction under 45 mm is 0,48 mmol·g -1 for Sr. The highest values of distribution coefficient were reached for the bentonite Jelsovy potok. Radiation stability has been investigated, the higher sorption parameters were observed for the irradiated bentonites, which can be explained by the increase of specific surface of the bentonite samples. The presence of complementary cations depresses the sorption of Sr on bentonite. Cations Ca 2+ exhibit higher effect on cesium sorption than the Na 2+ ions. Results indicate that the sorption of Sr 2+ on bentonite will be affected by the presence of high concentrations of various salts in the waste water

  6. suitability of murram for phosphorus sorption in constructed wetlands

    African Journals Online (AJOL)

    Mimi

    sorption isotherms, determination of Phosphorus sorption capacity of the substrates, determination of. Phosphorus sorption as the function of time and determination of effect of temperature on the ... (Na2O + K2O) % SiO2. %. P2O5. %. TiO2. %. LOI. %. 19.2. 1.3. 0.69. 5.13. 0.05. 6.7. 61.9. 0.04. 0.51. 4.4. As presented in ...

  7. Mechanism of cesium sorption on potassium titanium hexacyanoferrate

    International Nuclear Information System (INIS)

    Sun Yongxia; Xu Shiping; Song Chongli

    1998-01-01

    The mechanism of cesium sorption on potassium titanium hexacyanoferrate is described. The dependence of the sorption speed on temperature, particle granule size, and the stirring speed is studied. The results show that the sorption process is controlled by liquid film diffusion and particle diffusion. An exchange reaction occurs mainly between K + in the exchanger and Cs + in the solution, i.e. potassium titanium hexacyanoferrate, and Cs + of simulated high-level liquid waste

  8. Sorption of curium by silica colloids: Effect of humic acid

    International Nuclear Information System (INIS)

    Kar, Aishwarya Soumitra; Kumar, Sumit; Tomar, B.S.; Manchanda, V.K.

    2011-01-01

    Sorption of curium by silica colloids has been studied as a function of pH and ionic strength using 244 Cm as a tracer. The sorption was found to increase with increasing pH and reach a saturation value of ∼95% at pH beyond 5.3. The effect of humic acid on the sorption of 244 Cm onto silica was studied by changing the order of addition of the metal ion and humic acid. In general, in the presence of humic acid (2 mg/L), the sorption increased at lower pH (<5) while it decreased in the pH range 6.5-8 and above pH 8, the sorption was found to increase again. As curium forms strong complex with humic acid, its presence results in the enhancement of curium sorption at lower pH. At higher pH the humic acid present in the solution competes with the surface sites for curium thus decreasing the sorption. The decrease in the Cm sorption in presence of humic acid was found to be less when humic acid was added after the addition of curium. Linear additive model qualitatively reproduced the profile of the Cm(III) sorption by silica in presence of humic acid at least in the lower pH region, however it failed to yield quantitative agreement with the experimental results. The results of the present study evidenced the incorporation of Cm into the silica matrix.

  9. Development of Web-based Software for Sorption Database

    International Nuclear Information System (INIS)

    Han, Byoung Sub; Lee, Jae Min; Seo, Min Seok; Kim, Dong Keon

    2009-08-01

    Sorption studies of radionuclides are important parts of research on radioactive waste disposal which is commonly faced in most countries where nuclear programs (power production, a variety of peaceful applications, and research) are implemented. The Sorption Database (DB) plays a very important role in the safety assessment of the radioactive waste disposal. The Sorption DB which is opened externally can be used as reference material of establishing a national policy by improving and changing the pre-developed Sorption program to be web-based. From the industrial point of view, if the Sorption DB is opened to the outside, the safety-related confidence can be achieved for nuclear industry. As the information of Sorption DB is opened, not only credibility can be provided to the administration, local governments and nearby residents, but also input of the collected information can be achieved by online. In addition, the reference material and external awareness/reliability about the domestic level of the Sorption DB management system and the current state can be achieved internationally. In order to provide the information of Sorption DB to users in more efficient way, the analysis and complement of management and search capability for the existing Sorption DB program have been performed and web-based management system has been built to provide services to users. In addition, by applying statistical techniques, it has been designed and implemented to display the accuracy and error of the information

  10. Determining Sorption Rate by a Continuous Gravimetric Method

    National Research Council Canada - National Science Library

    Hall, Monicia R; Procell, Lawrence R; Bartram, Philip W; Shuely, Wendel J

    2003-01-01

    ... were automatically recorded in an Excel file while CARC coupons were submerged in solvent. Initial sorption rates were determined for butyl acetate, butyl ether, cyclohexane and propylene carbonate...

  11. The sorption of polonium, actinium and protactinium onto geological materials

    International Nuclear Information System (INIS)

    Baston, G.M.N.; Berry, J.A.; Brownsword, M.; Heath, T.G.; Ilett, D.J.; McCrohon, R.; Tweed, C.J.; Yui, M.

    1999-01-01

    This paper describes a combined experimental and modeling program of generic sorption studies to increase confidence in the performance assessment for a potential high-level radioactive waste repository in Japan. The sorption of polonium, actinium and protactinium onto geological materials has been investigated. Sorption of these radioelements onto bentonite, tuff and granodiorite from equilibrated de-ionized water was studied under reducing conditions at room temperature. In addition, the sorption of actinium and protactinium was investigated at 60 C. Thermodynamic chemical modeling was carried out to aid interpretation of the results

  12. The sorption of polonium, actinium and protactinium onto geological materials

    Energy Technology Data Exchange (ETDEWEB)

    Baston, G.M.N.; Berry, J.A.; Brownsword, M.; Heath, T.G.; Ilett, D.J.; McCrohon, R.; Tweed, C.J.; Yui, M.

    1999-07-01

    This paper describes a combined experimental and modeling program of generic sorption studies to increase confidence in the performance assessment for a potential high-level radioactive waste repository in Japan. The sorption of polonium, actinium and protactinium onto geological materials has been investigated. Sorption of these radioelements onto bentonite, tuff and granodiorite from equilibrated de-ionized water was studied under reducing conditions at room temperature. In addition, the sorption of actinium and protactinium was investigated at 60 C. Thermodynamic chemical modeling was carried out to aid interpretation of the results.

  13. Comparison of neptunium sorption results using batch and column techniques

    International Nuclear Information System (INIS)

    Triay, I.R.; Furlano, A.C.; Weaver, S.C.; Chipera, S.J.; Bish, D.L.

    1996-08-01

    We used crushed-rock columns to study the sorption retardation of neptunium by zeolitic, devitrified, and vitric tuffs typical of those at the site of the potential high-level nuclear waste repository at Yucca Mountain, Nevada. We used two sodium bicarbonate waters (groundwater from Well J-13 at the site and water prepared to simulate groundwater from Well UE-25p No. 1) under oxidizing conditions. It was found that values of the sorption distribution coefficient, Kd, obtained from these column experiments under flowing conditions, regardless of the water or the water velocity used, agreed well with those obtained earlier from batch sorption experiments under static conditions. The batch sorption distribution coefficient can be used to predict the arrival time for neptunium eluted through the columns. On the other hand, the elution curves showed dispersivity, which implies that neptunium sorption in these tuffs may be nonlinear, irreversible, or noninstantaneous. As a result, use of a batch sorption distribution coefficient to calculate neptunium transport through Yucca Mountain tuffs would yield conservative values for neptunium release from the site. We also noted that neptunium (present as the anionic neptunyl carbonate complex) never eluted prior to tritiated water, which implies that charge exclusion does not appear to exclude neptunium from the tuff pores. The column experiments corroborated the trends observed in batch sorption experiments: neptunium sorption onto devitrified and vitric tuffs is minimal and sorption onto zeolitic tuffs decreases as the amount of sodium and bicarbonate/carbonate in the water increases

  14. Experimental study of strontium sorption on fissure filling material

    Energy Technology Data Exchange (ETDEWEB)

    Eriksen, T E; Cui, Daqing [Royal Institute of Technology, Stockholm (Sweden). Dept. of Chemistry

    1994-12-01

    We have carried out a comparative study of sorption and desorption of strontium in groundwater on separated magnetic and size fractions of fissure filling material taken from natural fissures in granitic rock. Complete reversibility of the sorption process was demonstrated by identical Freundlich isotherms, isotopic exchangeability and pH dependence of the distribution coefficients Rd. The sorption was found to be strongly pH dependent in the range 3-11. The pH effect can be accommodated in the sorption model by considering the surface areas and surface charges of the minerals in the fissure filling material. 20 refs, 9 figs, 3 tabs.

  15. Experimental study of strontium sorption on fissure filling material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Cui, Daqing

    1994-12-01

    We have carried out a comparative study of sorption and desorption of strontium in groundwater on separated magnetic and size fractions of fissure filling material taken from natural fissures in granitic rock. Complete reversibility of the sorption process was demonstrated by identical Freundlich isotherms, isotopic exchangeability and pH dependence of the distribution coefficients Rd. The sorption was found to be strongly pH dependent in the range 3-11. The pH effect can be accommodated in the sorption model by considering the surface areas and surface charges of the minerals in the fissure filling material. 20 refs, 9 figs, 3 tabs

  16. Acquisition of sorption isotherms for modified woods by the use of dynamic vapour sorption instrumentation. Principles and Practice

    DEFF Research Database (Denmark)

    Engelund, Emil Tang; Klamer, Morten; Venås, Thomas Mark

    2010-01-01

    The complex wood-water relationship has been the topic of numerous studies. Sorption isotherms – in particular – have been derived for hundreds of wood species, their sap- and heartwood sections as well as for decayed, engineered and modified wood materials. However, the traditional methods...... for obtaining sorption isotherms are very time consuming. With new dynamic vapour sorption (DVS) instrumentation, the acquisition of data for constructing sorption isotherms is suddenly dramatically lowered. Where the traditional methods often required months, data can now be obtained in a matter of days...... depending on the number of data points required. The fast data acquisition makes DVS a useful tool in studying the sorption properties of wood, and especially in studying the effect of different modification treatments on these properties. This study includes an investigation of the sorption properties...

  17. My Place Is Not Your Place

    DEFF Research Database (Denmark)

    Zenker, Sebastian; Beckmann, Suzanne C.

    2013-01-01

    Purpose – Cities increasingly compete with each other for attracting tourists, investors, companies, or residents. Marketers therefore focus on establishing the city as a brand, disregarding that the perception and knowledge of a city differ dramatically between the target audiences. Hence, place...... branding should emphasize much more the perceptions of the different target groups and develop strategies for advanced place brand management. The aim of this paper is to assess the important discrepancies between the city brand perceptions of different target groups with the help of network analysis......-ended-question survey with 334 participants. Findings – Structural differences for the city brand perceptions of two different target groups and the differences between perceptions of an external and internal target group are highlighted. The results and the managerial implications for place marketers are discussed...

  18. Place branding, embeddedness and endogenous rural development

    NARCIS (Netherlands)

    Donner, Mechthild; Horlings, Lummina; Fort, Fatiha; Vellema, Sietze

    2017-01-01

    This article deals with place branding on the regional scale, in the rural context of food and tourism networks in Europe. Place branding is linked to the concepts of endogenous rural development, territory and embeddedness, by analysing how the valorisation of specific rural assets takes shape.

  19. Populated Places of Iowa

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — This coverage contains points that represent populated places, ie. cities, towns, villages or any other named place where people live. The coverage was developed...

  20. Experimental methodology to study radionuclide sorption and migration in geological formations and engineered barriers of waste repositories; Metodologia experimental para estudios de sorcion y migracion de radionucleidos en formaciones geologicas y barreras de almacenamientos de residuos

    Energy Technology Data Exchange (ETDEWEB)

    Rojo Sanz, H.

    2010-07-01

    In Spain, the waste management options include either the possibility of a final storage in a deep geological repository (DGR) or the centralized temporal surface disposal (CTS). DGRs are based in a multi-barrier concept with the geological barrier and including the vitrified waste, the metal containers and engineered barriers such as compacted bentonite and cement-based materials. On the other hand, CTS mainly considers concrete and cement to confine the metal canisters containing the waste. Radionuclide migration will mainly take place by the existence of chemical concentration gradients being thus diffusion the main transport mechanism or by the existence of hydraulic gradients due to the existence of water-conductive fractures. Radionuclide sorption/retention on the materials composing the natural and engineered barriers is the fundamental process controlling contaminant migration. The evaluation of sorption parameters and the understanding of the different mechanisms leading to radionuclide retention are very important issues. The study of diffusion processes is very relevant as well. This paper describes the main experimental methodologies applied to analyse radionuclide transport in the different barriers of radioactive repositories. Particularly we focused on obtaining of retention parameters as distribution coefficients, kd, or retardation factors, Rf, and diffusion coefficients of radionuclides. (Author) 6 refs.

  1. 3.3. Sorption activity of cross-linked polymers of ethynyl-piperidol

    International Nuclear Information System (INIS)

    Khalikov, D.Kh.

    2012-01-01

    The sorption activity of cross-linked polymers of ethynyl-piperidol was studied. The bilirubin sorption was studied as well. The kinetic of bilirubin sorption and human serum albumin at their joint presence in hydrogel solutions was defined. Bilirubin sorption and change of albumin composition was considered. The sorption of middle molecular peptides was considered as well. The sorption of endogenous toxin by means of ethynyl-piperidol polymers was done.

  2. Sorption of nitrate onto amine-crosslinked wheat straw: characteristics, column sorption and desorption properties.

    Science.gov (United States)

    Xing, Xu; Gao, Bao-Yu; Zhong, Qian-Qian; Yue, Qin-Yan; Li, Qian

    2011-02-15

    The nitrate removal process was evaluated using a fixed-bed column packed with amine-crosslinked wheat straw (AC-WS). Column sorption and desorption characteristics of nitrate were studied extensively. Solid-state (13)C NMR and zeta potential analysis validated the existence of crosslinked amine groups in AC-WS. Raman shift of the nitrate peaks suggested the electrostatic attraction between the adsorbed ions and positively charged amine sites. The column sorption capacity (q(ed)) of the AC-WS for nitrate was 87.27 mg g(-1) in comparison with the raw WS of 0.57 mg g(-1). Nitrate sorption in column was affected by bed height, influent nitrate concentration, flow rate and pH, and of all these, influent pH demonstrated an essential effect on the performance of the column. In addition, desorption and dynamic elution tests were repeated for several cycles, with high desorption rate and slight losses in its initial column sorption capacity. Copyright © 2010 Elsevier B.V. All rights reserved.

  3. The importance of places and place branding

    NARCIS (Netherlands)

    Kovács, Z.; Musterd, S.; Musterd, S.; Kovács, Z.

    2013-01-01

    In the analytical part of this study, we highlight that, despite globalisation and growing uniformity, there is still an important role for place itself in the location decisions of economic players. Part III of this volume deals with this. Even though city-regions across the world have become

  4. A woman's rightful place?

    Science.gov (United States)

    1993-04-01

    Rural development projects in sub-Saharan Africa tend not to succeed because they do not consider women's role and their significance, even though women constitute 70% of agricultural workers, 80% of food producers, 100% of people who prepare meals, and 60-90% do food marketing. Development specialists ignore women because they are not involved in political activities and in decision making. As long as women and women's contributions are not considered, rural development projects will remain inefficient and development will not take place. Thus, projects must include women as agents and beneficiaries of development in key sectors of the economy. Rural development specialists must also consider the effect male labor emigration has on rural women. For example, drought has forced many men to leave their villages, leaving a work force consisting of 95% women to fight desertification. All too often, women have no or limited land ownership rights, thereby keeping them from improving the land, e.g., planting perennial fruit crops. They also tend to be hired hands rather than food producers. They cannot obtain bank loans because they do not own land, and because they are often illiterate (over 90% female illiteracy in 28 African countries), they can neither understand nor complete bank loan forms. Rural development projects further alienate women by aiming training programs to men or by using male agricultural extension agents. Women react to this alienation by rejecting projects that do not benefit them and follow more profitable activities which sometimes interfere with projects. Thus, rural development programs need to invest in women to ensure viable and efficient sustainable development.

  5. Humidity sorption on natural building stone

    Science.gov (United States)

    Franzen, C.; Mirwald, P.

    2003-04-01

    processes, physical, chemical or biological, depend on the presence of water. Like most porous materials building stone respond on humidity by water uptake. The sorption isotherm represents the equilibrium moisture, specific for each material. The determination of the isotherm for stone of low and small porosity like marble is difficult. With the help of a newly developed water sorption analysis chamber [2], which allows the simultaneous measurement of 11 samples, good results on stone/rock samples have been obtained. Even at marble species with pore volumes lower than 0.4 % isotherms are measured. This analytical method offers new insights in the pore behaviour of low porosity materials. The advantages of this technique which supplements other techniques (e.g. BET, Hg-porosimetry) are: i) the testing agent is identical to the weathering agent, water; ii) the atmospheric parameters at the measurement reflect the natural conditions - thus no changes to the material properties have to be considered; iii) due to the small diameter of the water molecule (~0.28 nm), smaller pores are reached than e.g. with N2 (~0.31 nm). Sorption isotherms of sandstone (Baumberg, Obernkirchen, Groeden), granite (Brixen), and marble (Sterzing, Laas) are presented. Particular as to marbles the resolution is considerably higher. A previously observed negative hysteresis [3] seems an effect due to limited data resolution. [1] Snethlage, R. (1984) Steinkonservierung, Bayer. LA Denkmalpflege, Ah. 22, 203 S. [2] Griesser, U.J., Dillenz, J. (2002) Neuartiges, vollautomatisches Feuchtesorptionsprüfgerät mit hohem Probendurchsatz, Feuchtetag 2002, Weimar, 85-93. [3] Fimmel, R. (1996) Verwitterungsverhalten der alpinen Marmore von Laas und Sterzing, Diss. Univ. Ibk, 116 S.

  6. EXAFS study of plutonium sorption onto kaolinite

    International Nuclear Information System (INIS)

    Reich, T.Y.; Banik, L.; Buda, R.A.; Amayri, S.; Drebert, J.; Kratz, J.V.; Trautmann, N.; Reich, T.; Ageev, A.L.; Korshunov, M.E.

    2007-01-01

    The uptake mechanism of plutonium by kaolinite was investigated by applying X-ray absorption spectroscopy to batch sorption samples (total Pu concentrations 1 and 10 μM; 4 g kaolinite/L in 0.1 M NaClO 4 ; 1 ≤ pH ≤ 9; presence and absence of ambient CO 2 ). For XAFS measurements, one sample was prepared from a Pu(III) solution at pH 6 under argon atmosphere. Three samples were obtained by sorption of Pu(IV) at pH I, 4, and 9 in an air-equilibrated system. The Pu L III -edge XANES spectra indicated that in all samples, including the Pu(III) sample, plutonium is sorbed at the kaolinite surface as Pu(IV). The Pu L III -edge k 3 -weighted EXAFS spectra showed eight oxygen atoms at an average Pu-O distance of 2.3 angstrom. Two Pu atoms were detected at ∼ 3.7 angstrom in all spectra, indicating the formation of polynuclear Pu(IV) species at the kaolinite surface. For the sample prepared from Pu(III) solution, an additional Pu-O shell at 3.2 angstrom was observed. The spectra of samples prepared from Pu(IV) included a Pu-Al/Si co-ordination shell at approximately 3.6 angstrom, indicating formation of inner-sphere sorption complexes. The structural models used in the least-squares fits were confirmed by an alternative EXAFS data analysis approach based on a modified Tikhonov regularization method. (authors)

  7. Taking warfarin (Coumadin)

    Science.gov (United States)

    ... page: //medlineplus.gov/ency/patientinstructions/000292.htm Taking warfarin (Coumadin) To use the sharing features on this ... form a clot or have bleeding problems. Taking Warfarin It is important that you take warfarin exactly ...

  8. Sorption of pesticides to aquifer minerals

    DEFF Research Database (Denmark)

    Clausen, Liselotte; Fabricius, Ida Lykke

    2000-01-01

    This paper summarizes results from a work were the sorption of five pesticides on seven minerals were studied in order to quantify the adsorption to different mineral surfaces. Investigated mineral phases are: quartz, calcite, kaolinite, a-alumina, and three iron oxides (2-line ferrihydrite......, goethite, lepidocrocite). Selected pesticides are: atrazine, isoproturon, mecoprop, 2,4-D, and bentazone. The results demonstrate that pesticides adsorb to pure mineral surfaces. However, the size of the adsorption depends on the type of pesticide and the type of mineral....

  9. Tritium sorption by cement and subsequent release

    International Nuclear Information System (INIS)

    Ono, F.; Tanaka, S.; Yamawaki, M.

    1994-01-01

    In a fusion reactor or tritium handling facilities, contamination of concrete by tritium and subsequent release from it to the reactor or experimental rooms is a matter of problem for safety control of tritium and management of operational environment. In order to evaluate these tritium behavior, interaction of tritiated water with concrete or cement should be clarified. In the present study, HTO sorption and subsequent release from cement were studied by combining various experimental methods. From the basic studies on tritium-cement interactions, it has become possible to evaluate tritium uptake by cement or concrete and subsequent tritium release behavior as well as tritium removing methods from them

  10. Thermodynamics of imidacloprid sorption in Croatian soils

    Science.gov (United States)

    Milin, Čedomila; Broznic, Dalibor

    2015-04-01

    Neonicotinoids are increasingly replacing the organophosphate and methylcarbamate acetylcholinesterase inhibitors which are losing their effectiveness because of selection for resistant pest populations. Imidacloprid is the most important neonicotinoid with low soil persistence, high insecticidal potency and relatively low mammalian toxicity. In Croatia, imidacloprid is most commonly used in olive growing areas, including Istria and Kvarner islands, as an effective means of olive fruit fly infestation control. Sorption-desorption behavior of imidacloprid in six soils collected from five coastal regions in Croatia at 20, 30 and 40°C was investigated using batch equilibrium technique. Isothermal data were applied to Freundlich, Langmuir and Temkin equation, and the thermodynamic parameters ΔH°, ΔG°, ΔS° were calculated. The sorption isotherm curves were of non-linear and may be classified as L-type suggesting a relatively high sorption capacity for imidacloprid. Our results showed that the KFsor values decreased for all the tested soils as the temperature increases, indicating that the temperature strongly influence the sorption. Values of ΔG° were negative (-4.65 to -2.00 kJ/mol) indicating that at all experimental temperatures the interactions of imidacloprid with soils were spontaneous process. The negative and small ΔH° values (-19.79 to -8.89 kJ/mol) were in the range of weak forces, such as H-bonds, consistent with interactions and par¬titioning of the imidacloprid molecules into soil organic matter. The ΔS° values followed the range of -57.12 to -14.51 J/molK, suggesting that imidacloprid molecules lose entropy during transition from the solution phase to soil surface. It was found that imidacloprid desorption from soil was concentration and temperature dependent, i.e. at lower imidacloprid concentrations and temperature, lower desorption percentage occurred. Desorption studies revealed that hysteretic behavior under different temperature

  11. Sorption of radiostrontium from liquid metallic rubidium

    International Nuclear Information System (INIS)

    Zhujkov, B.L.; Kokhnyuk, V.M.; Vincent, J.S.

    2008-01-01

    One studied the radiostrontium (in particular, 82 Sr) sorption from the liquid metallic Rb in various inorganic sorbents (both metals and oxides). One studied the temperature dependence and the dynamics of the adsorption and put forward an interpretation of the observed mechanisms. The elaborated approach enables to extract 82 Sr efficiently from the Rb targets upon their irradiation by the accelerated protons. One studies various procedures and the applicability of the process to ensure elaboration of a new highly efficient process to produce 82 Sr, in particular, with the targets of the circulating Rb [ru

  12. Pu sorption to activated conglomerate anaerobic bacteria

    International Nuclear Information System (INIS)

    Sasaki, Takayuki; Kudo, Akira

    2001-01-01

    The sorption of Pu to the anaerobic bacteria activated under specific conditions of temperature, pH and depleted nutrients after long dormant period was investigated. After 4 h at neutral pH, the distribution coefficient (K d ) between bacteria and aqueous phase at 308 and 278 K had around 10 3 to 10 4 . After over 5 days, however, the K d at only 308 K had increased to over 10 5 . Sterilized (dead) and dormant anaerobic bacteria adsorbed Pu to the same extent. (author)

  13. Take Charge. Take the Test. PSA (:30)

    Centers for Disease Control (CDC) Podcasts

    As part of the Take Charge. Take the Test. campaign, this 30 second PSA encourages African American women to get tested for HIV. Locations for a free HIV test can be found by visiting hivtest.org/takecharge or calling 1-800-CDC-INFO (1-800-232-4636).

  14. Place in Transition

    DEFF Research Database (Denmark)

    Mikkelsen, Jacob Bjerre; Lange, Ida Sofie Gøtzsche

    from the 'Everyday World'. Within mobilities studies, research has focused on different aspects and consequences of the post-oil society (see Dennis & Urry 2009, Urry 2013). This paper discusses the conception of place within the enclosed 'Oil World' with point of departure in relocation...... and redefinition of oil rigs from an urban design perspective. The paper constitutes a theoretical basis for future design scenarios - exemplified through visionary urban design proposals for a specific site in the city of Esbjerg, Denmark. Relocating rigs to an urban context initiates discussions of conception...... of 'Place' questioning the fixity of 'Place' (Jensen 2010). Scoped through a relational sense of place (Massey 1993) and the potential of exploring new relations between places (Burns & Kahn 2005), the paper challenges the notion of 'Place as God' (Hvattum 2010). These places in transition contest...

  15. Taking climate to the market

    International Nuclear Information System (INIS)

    Boyle, S.

    1998-01-01

    Since the 1997 Kyoto Protocol set binding targets for greenhouse gas reductions, there has been a rapid increase in interest in emissions trading. This is based on the premise that reduction options may be cheaper in countries such as those of eastern Europe and the developing world, than in others such as the USA and Norway. As long as real emission reductions take place, and given that climate change is a global problem, setting up an emissions trading market should provide a much cheaper option than reductions applied solely at a national level. The real prospects for a viable market, what it will look like, and the deals already taking place are examined. (UK)

  16. Functionalization of Magnetic Chitosan Particles for the Sorption of U(VI, Cu(II and Zn(II—Hydrazide Derivative of Glycine-Grafted Chitosan

    Directory of Open Access Journals (Sweden)

    Mohammed F. Hamza

    2017-05-01

    Full Text Available A new magnetic functionalized derivative of chitosan is synthesized and characterized for the sorption of metal ions (environmental applications and metal valorization. The chemical modification of the glycine derivative of chitosan consists of: activation of the magnetic support with epichlorohydrin, followed by reaction with either glycine to produce the reference material (i.e., Gly sorbent or glycine ester hydrochloride, followed by hydrazinolysis to synthesize the hydrazide functionalized sorbent (i.e., HGly sorbent. The materials are characterized by titration, elemental analysis, FTIR analysis (Fourrier-transform infrared spectrometry, TGA analysis (thermogravimetric analysis and with SEM-EDX (scanning electron microscopy coupled to energy dispersive X-ray analysis. The sorption performances for U(VI, Cu(II, and Zn(II are tested in batch systems. The sorption performances are compared for Gly and HGly taking into account the effect of pH, the uptake kinetics (fitted by the pseudo-second order rate equation, and the sorption isotherms (described by the Langmuir and the Sips equations. The sorption capacities of the modified sorbent reach up to 1.14 mmol U g−1, 1.69 mmol Cu g−1, and 0.85 mmol Zn g−1. In multi-metal solutions of equimolar concentration, the chemical modification changes the preferences for given metal ions. Metal ions are desorbed using 0.2 M HCl solutions and the sorbents are re-used for five cycles of sorption/desorption without significant loss in performances.

  17. Column Chromatography To Obtain Organic Cation Sorption Isotherms.

    Science.gov (United States)

    Jolin, William C; Sullivan, James; Vasudevan, Dharni; MacKay, Allison A

    2016-08-02

    Column chromatography was evaluated as a method to obtain organic cation sorption isotherms for environmental solids while using the peak skewness to identify the linear range of the sorption isotherm. Custom packed HPLC columns and standard batch sorption techniques were used to intercompare sorption isotherms and solid-water sorption coefficients (Kd) for four organic cations (benzylamine, 2,4-dichlorobenzylamine, phenyltrimethylammonium, oxytetracycline) with two aluminosilicate clay minerals and one soil. A comparison of Freundlich isotherm parameters revealed isotherm linearity or nonlinearity was not significantly different between column chromatography and traditional batch experiments. Importantly, skewness (a metric of eluting peak symmetry) analysis of eluting peaks can establish isotherm linearity, thereby enabling a less labor intensive means to generate the extensive data sets of linear Kd values required for the development of predictive sorption models. Our findings clearly show that column chromatography can reproduce sorption measures from conventional batch experiments with the benefit of lower labor-intensity, faster analysis times, and allow for consistent sorption measures across laboratories with distinct chromatography instrumentation.

  18. Sorption of Triangular Silver Nanoplates on Polyurethane Foam

    Science.gov (United States)

    Furletov, A. A.; Apyari, V. V.; Garshev, A. V.; Volkov, P. A.; Tolmacheva, V. V.; Dmitrienko, S. G.

    2018-02-01

    The sorption of triangular silver nanoplates on polyurethane foam is investigated as a procedure for creating a nanocomposite sensing material for subsequent use in optical means of chemical analysis. Triangular silver nanoplates are synthesized and characterized, and a simple sorption technique for the formation of a composite material based on these nanoplates is proposed.

  19. Sorption and desorption of diuron in Oxisol under biochar application

    Directory of Open Access Journals (Sweden)

    Fabiano André Petter

    Full Text Available ABSTRACT The objective of this study was to verify the kinetics of sorption and desorption of diuron in an Oxisol under application of biochar. The samples were collected in a field experiment conducted in randomized design blocks consisted of 2 base fertilization levels (0 and 400 kg∙ha−1 NPK 00-20-20 fertilizer formula and 3 doses of biochar (0, 8 and 16 Mg∙ha−1. In the evaluation of sorption and desorption, Batch Equilibrium method was used. The kinetics of sorption and desorption of diuron, total organic carbon, fulvic acid, humic acid and humin, pH and partition coefficient to organic carbon were evaluated. The Freundlich isotherm was adjusted appropriately to describe diuron sorption kinetics in all the studied treatments. The application of biochar provided increment in the sorption (Kf and reduction in the desorption of diuron in 64 and 44%, respectively. This effect is attributed to the biochar contribution to the total organic carbon and C-humin and of these to diuron through hydrophobic interactions and hydrogen bonds. The positive correlation between the partition coefficient to organic carbon and Kf confirms the importance of soil organic compartment in the sorption of diuron. There was no competition of NPK fertilizer for the same sorption site of diuron. The increase and reduction in sorption and desorption, respectively, show that the application of biochar is an important alternative for the remediation of soil leaching of diuron, especially in sandy soils.

  20. CO2 sorption of a ceramic separation membrane

    NARCIS (Netherlands)

    Wormeester, Herbert; Benes, Nieck Edwin; Spijksma, G.I.; Verweij, H.; Poelsema, Bene

    2004-01-01

    The ellipsometric characterization of the CO2 sorption of a silica membrane provides a fast and accurate technique for the characterization of maximum sorption and the heat of adsorption. Both parameters are evaluated for the 73 nm thick silica layer as well as the 1650 nm thick supporting γ-layer.

  1. Status report on SIRS: sorption information retrieval system

    International Nuclear Information System (INIS)

    Hostetler, D.D.; Serne, R.J.; Baldwin, A.J.; Petrie, G.M.

    1980-11-01

    Two major uses were identified for the Sorption Information Retrieval System: (1) to aid geochemists in the elucidation of sorption mechanisms; and (2) to aid safety assessment modelers in selection of Kds for any given scenerio. Other benefits such as providing an auditable vehicle for the Kd selection were also discussed

  2. Effect of humic acid (HA) on sulfonamide sorption by biochars

    International Nuclear Information System (INIS)

    Lian, Fei; Sun, Binbin; Chen, Xi; Zhu, Lingyan; Liu, Zhongqi; Xing, Baoshan

    2015-01-01

    Effect of quantity and fractionation of loaded humic acid (HA) on biochar sorption for sulfonamides was investigated. The HA was applied in two different modes, i.e. pre-coating and co-introduction with sorbate. In pre-coating mode, the polar fractions of HA tended to interact with low-temperature biochars via H-bonding, while the hydrophobic fractions were likely to be adsorbed by high-temperature biochars through hydrophobic and π-π interactions, leading to different composition and structure of the HA adlayers. The influences of HA fractionation on biochar sorption for sulfonamides varied significantly, depending on the nature of interaction between HA fraction and sorbate. Meanwhile, co-introduction of HA with sulfonamides revealed that the effect of HA on sulfonamide sorption was also dependent on HA concentration. These findings suggest that the amount and fractionation of adsorbed HA are tailored by the surface properties of underlying biochars, which differently affect the sorption for organic contaminants. - Highlights: • Effect of quantity and fractionation of coated HA on sorption of sulfonamides by BC was studied. • Fractionation of coated HA is tailored by surface properties of BC. • Roles of HA in BC sorption depend on interaction between HA adlayer and sorbate. • Roles of HA in sulfonamide sorption by BC also depend on HA aqueous concentration. - The quantity and fractionation of adsorbed HA play a major role in sulfonamide sorption by biochars

  3. Sorption of malachite green (MG) by cassava stem biochar (CSB ...

    African Journals Online (AJOL)

    Cassava stem biochar (CSB) was produced by pyrolyzing CS at 500°C for 2 hours at nitrogen environment. Proximate and ultimate analyses were conducted on CS and CSB. Batch sorption experiment on synthetic MG wastewater was optimized for the sorbent dosage, MG solution pH and contact time. Sorption data was ...

  4. Competitive sorption of heavy metals by water hyacinth roots.

    Science.gov (United States)

    Zheng, Jia-Chuan; Liu, Hou-Qi; Feng, Hui-Min; Li, Wen-Wei; Lam, Michael Hon-Wah; Lam, Paul Kwan-Sing; Yu, Han-Qing

    2016-12-01

    Heavy metal pollution is a global issue severely constraining aquaculture practices, not only deteriorating the aquatic environment but also threatening the aquaculture production. One promising solution is adopting aquaponics systems where a synergy can be established between aquaculture and aquatic plants for metal sorption, but the interactions of multiple metals in such aquatic plants are poorly understood. In this study, we investigated the absorption behaviors of Cu(II) and Cd(II) in water by water hyacinth roots in both single- and binary-metal systems. Cu(II) and Cd(II) were individually removed by water hyacinth roots at high efficiency, accompanied with release of protons and cations such as Ca 2+ and Mg 2+ . However, in a binary-metal arrangement, the Cd(II) sorption was significantly inhibited by Cu(II), and the higher sorption affinity of Cu(II) accounted for its competitive sorption advantage. Ionic exchange was identified as a predominant mechanism of the metal sorption by water hyacinth roots, and the amine and oxygen-containing groups are the main binding sites accounting for metal sorption via chelation or coordination. This study highlights the interactive impacts of different metals during their sorption by water hyacinth roots and elucidates the underlying mechanism of metal competitive sorption, which may provide useful implications for optimization of phytoremediation system and development of more sustainable aquaculture industry. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Analysis of ideal sorption compressor cycles operating with gas mixtures

    NARCIS (Netherlands)

    Tzabar, N.; ter Brake, H.J.M.

    2018-01-01

    Sorption-based compressors are thermally driven and because of the absence of moving parts they are vibration free, and have the potential for long life. Sorption-based compressors have been reported to operate Joule–Thomson (JT) cryogenic coolers with pure working fluids. However, using mixed

  6. Picloram and Aminopyralid Sorption to Soil and Clay Minerals

    Science.gov (United States)

    Aminopyralid sorption data are lacking, and these data are needed to predict off-target transport and plant available herbicide in soil solution. The objective of this research was to determine the sorption of picloram and aminopyralid to five soils and three clay minerals and determine if the pote...

  7. Hysteresis and Temperature Dependency of Moisture Sorption – New Measurements

    DEFF Research Database (Denmark)

    Rode, Carsten; Hansen, Kurt Kielsgaard

    2011-01-01

    measurements of hysteresis and temperature dependency of the moisture sorption characteristics of three different porous building materials: aerated concrete, cement paste and spruce. Scanning curves are measured for all three materials where periods with adsorption and desorption interrupt each other...... intermittently. For one of the materials, aerated concrete, the sorption curves are determined at three different temperatures....

  8. Sorption of fluoroquinolones and sulfonamides in 13 Brazilian soils.

    Science.gov (United States)

    Leal, Rafael Marques Pereira; Alleoni, Luis Reynaldo Ferracciú; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges

    2013-08-01

    Animal production is a leading economic activity in Brazil and antibiotics are widely used. However, the occurrence, behavior, and impacts of antibiotics in Brazilian soils are still poorly known. We evaluated the sorption behavior of four fluoroquinolones (norfloxacin, ciprofloxacin, danofloxacin, and enrofloxacin) and five sulfonamides (sulfadiazine, sulfachloropyridazine, sulfamethoxazole, sulfadimidine, and sulfathiazole) in 13 Brazilian soils with contrasting physical, chemical, and mineralogical properties. Fluoroquinolone sorption was very high (Kd≥544 L kg(-1)) whereas sulfonamide sorption ranged from low to high (Kd=0.7-70.1 L kg(-1)), consistent with previous reports in the literature. Soil texture and cation exchange capacity were the soil attributes that most affected sorption. Cation exchange was the most important sorption mechanism for the fluoroquinolones in highly weathered tropical soils, although cation bridging and ion pairing could not be ruled out. Hydrophobic partition played an important role in the sorption of the sulfonamides, but sorption was also affected by non-hydrophobic interactions with organic and/or mineral surfaces. Sorption for both compound classes tended to be higher in soils with high Al and Fe oxihydroxide contents, but they were not correlated with Kd values. No direct effect of soil pH was seen. The fluoroquinolones are not expected to leach even in worst-case scenarios (soils rich in sand and poor in organic carbon), whereas soil attributes dictate leaching potential for the sulfonamides. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. A quantitative mechanistic description of Ni, Zn and Ca sorption on Na-montmorillonite. Part III: modelling

    International Nuclear Information System (INIS)

    Baeyens, B.; Bradbury, M.H.

    1995-07-01

    Titration and sorption measurements, carried out under a wide variety of conditions on Na-montmorillonite, were examined in terms of cation exchange and surface complexation mechanisms. A computer code called MINSORB was developed and used throughout this work. This code allowed the uptake of radionuclides by both mechanisms to be calculated simultaneously; also taking into account competitive reactions from other cations present. A stepwise iterative fitting/modelling procedure is described. For the case of Na-montmorillonite it is demonstrated that an electrostatic term in the surface complexation model is not required. A basic data set comprising of site capacities and protonation/deprotonation constants was defined, which was valid for all surface complexation sorption reactions. The main study was carried out with Ni, but impurity cations present in the system, particularly Zn, had to be examined in addition due to their competitive effects on Ni sorption. The surface complexation behaviour of Ni and Zn was investigated in detail to give intrinsic surface complexation constants on two of the =SOH type sites included in the model. The sorption of Mg, Ca and Mn is also considered, though in less detail, and estimated surface complexation constants for these nuclides are presented. Cation exchange was included in all of the calculations. Measured selectivity coefficients for Ni-Na, Zn-Na and Ca-Na exchange reactions are given. The model, with the derived parameters, allowed all the data from titration measurements through sorption edges to sorption isotherms to be calculated. (author) 31 figs., 9 tabs., refs

  10. A quantitative mechanistic description of Ni, Zn and Ca sorption on Na-Montmorillonite. Part III: Modelling

    International Nuclear Information System (INIS)

    Baeyens, B.; Bradbury, M.H.

    1995-07-01

    Titration and sorption measurements, carried out under a wide variety of conditions on Na-montmorillonite, were examined in terms of cation exchange and surface complexation mechanisms. A computer code called MINSORB was developed and used throughout this work. This code allowed the uptake of radionuclides by both mechanisms to be calculated simultaneously; also taking into account competitive reactions from other cations present. A stepwise iterative fitting/modelling procedure is described. For the case of Na-montmorillonite it is demonstrated that an electrostatic term in the surface complexation model is not required. A basic data set comprising of site capacities and protonation/deprotonation constants was defined, which was valid for all surface complexation sorption reactions. The main study was carried out with Ni, but impurity cations present in the system, particularly Zn, had to be examined in addition due to their competitive effects on Ni sorption. The surface complexation behaviour of Ni and Zn was investigated in detail to give intrinsic surface complexation constants on two of the ≡SOH type sites included in the model. The sorption of Mg, Ca and Mn is also considered, though in less detail, and estimated surface complexation constants for these nuclides are presented. Cation exchange was included in all of the calculations. Measured selectivity coefficients for Ni-Na, Zn-Na and Ca-Na exchange reactions are given. The model, with the derived parameters, allowed all the data from titration measurements through sorption edges to sorption isotherms to be calculated. (author) 31 figs., 9 tabs., refs

  11. Sorption ability of the soil and its impact on environmental contamination

    Science.gov (United States)

    Gargošová, Helena Zlámalová; Vávrová, Milada

    2014-01-01

    From the physical point of view, soil is a heterogenic polydisperse system. It often becomes a place of a secondary contamination during extinguishing uncontrolled areal fires in nature. Foam extinguishing agents (FEAs), used at these events, basically contain surface active substances and perfluorinated compounds. These tend to be captured in the soil matrix due to their specific properties. Contaminants could be partly flushed out with rainwater, which causes several times dilution of contamination and lower ecotoxic activity. However in the dry season, foam solution infiltrates into the bed soil without any dilution. This study deals with the direct influence of soil the sorption complex on ecotoxicity of five selected FEAs, i.e. Expyrol F 15, Finiflam F 15, Moussol APS F 15, Pyrocool B and Sthamex F 15. The substances tested were prepared in concentration of work solution and then applied on standard soil matrix LUFA 2.3. For experimental purposes, a column infiltration apparatus was designed and compiled. Filtrates were collected and then tested using the plant organisms Sinapis alba and Allium cepa L. The study compared ecotoxicologic effects of filtrates with an original work solution. Moussol APS F 15 seems to be the least ecotoxic of the FEAs tested. A direct influence of soil sorption complex onto ecotoxicity reduction was also established. This finding demonstrates the sorption ability of soil particles and ion exchange activity of the soil matrix. It is a positive finding for biota of aquatic environment, yet at the expense of those in soil. PMID:26109897

  12. Soil sorption complex influence on dynamics of 239,240Pu and 241Am mobile and fixed forms in different landscapes

    International Nuclear Information System (INIS)

    Leinova, S.L.; Sokolik, G.A.; Kilchitskaya, S.L.; Ivanova, T.G.; Zhukovich, N.V.; Kimlenko, I.M.

    1998-01-01

    The physico-chemical forms of 239,240 Pu and 241 Am in soil and radionuclide distribution between the main components of soil sorption complex were analyzed. The content of 'hot' particles in soils in Belarus is about 10-1.10 4 particles/m 2 . During the post accident period the 'hot' particles quantity decreased 40-200 times and 50-20000 times in mineral and organogenic soils, respectively. Their activity decreased 1.2-1.4 times per year in mineral soils and 1.3-1.5 times in organic soils. Their destruction velocity is determined by the soil media properties and the particle composition: the particles of 'condensed' nature are destroyed more quickly than those of fuel nature. The velocity of release of transuranium elements from the 'hot' particles increases with increasing soil acidity and humus content in soils. The radionuclides exhibiting different bond strength with soil sorption complex were determined by sequential selective extraction. The share of the most mobile exchange forms of 239,240 Pu is less than 10%. The quantity of potential mobile acid soluble forms of 239,240 Pu increases with time and changes in the sequence: peat soils 241 Am (85%) in comparison with 2 39,240 Pu (40%) was found. The content of 241 Am mobile forms increases with soil depth. It can be expected that in soils with high content of organic substances the accumulation of 239,240 Pu and 241 Am in surface soil layers will take place in future, but in mineral soils significant amounts of radionuclides will enter illuvial horizons as a result of vertical migration

  13. Place-Specific Computing

    DEFF Research Database (Denmark)

    Messeter, Jörn

    2009-01-01

    An increased interest in the notion of place has evolved in interaction design based on the proliferation of wireless infrastructures, developments in digital media, and a ‘spatial turn’ in computing. In this article, place-specific computing is suggested as a genre of interaction design that add......An increased interest in the notion of place has evolved in interaction design based on the proliferation of wireless infrastructures, developments in digital media, and a ‘spatial turn’ in computing. In this article, place-specific computing is suggested as a genre of interaction design...... that addresses the shaping of interactions among people, place-specific resources and global socio-technical networks, mediated by digital technology, and influenced by the structuring conditions of place. The theoretical grounding for place-specific computing is located in the meeting between conceptions...... of place in human geography and recent research in interaction design focusing on embodied interaction. Central themes in this grounding revolve around place and its relation to embodiment and practice, as well as the social, cultural and material aspects conditioning the enactment of place. Selected...

  14. From sense of place to visualization of place: examining people-place relationships for insight on developing geovisualizations.

    Science.gov (United States)

    Newell, Robert; Canessa, Rosaline

    2018-02-01

    Effective resource planning incorporates people-place relationships, allowing these efforts to be inclusive of the different local beliefs, interests, activities and needs. 'Geovisualizations' can serve as potentially powerful tools for facilitating 'place-conscious' resource planning, as they can be developed with high degrees of realism and accuracy, allowing people to recognize and relate to them as 'real places'. However, little research has been done on this potential, and the place-based applications of these visual tools are poorly understood. This study takes steps toward addressing this gap by exploring the relationship between sense of place and 'visualization of place'. Residents of the Capital Regional District of BC, Canada, were surveyed about their relationship with local coastal places, concerns for the coast, and how they mentally visualize these places. Factor analysis identified four sense of place dimensions - nature protection values, community and economic well-being values, place identity and place dependence, and four coastal concerns dimensions - ecological, private opportunities, public space and boating impacts. Visualization data were coded and treated as dependent variables in a series of logistic regressions that used sense of place and coastal concerns dimensions as predictors. Results indicated that different aspects of sense of place and (to a lesser degree) concerns for places influence the types of elements people include in their mental visualization of place. In addition, sense of place influenced the position and perspective people assume in these visualizations. These findings suggest that key visual elements and perspectives speak to different place relationships, which has implications for developing and using geovisualizations in terms of what elements should be included in tools and (if appropriate) depicted as affected by potential management or development scenarios.

  15. Sorption of Np (Ⅴ) on Beishan granite fracture filling materials

    International Nuclear Information System (INIS)

    Jiang Tao; Wang Bo; Bao Liangjin; Zhou Duo; Long Haoqi; Song Zhixin; Chen Xi

    2012-01-01

    The sorption behaviors of Np (Ⅴ) on the granite fracture filling materials were studied by batch experiments under anaerobic in Beishan groundwater. The impact of pH of groundwater, CO 3 2- , humic acid and different components of granite fracture filling materials on sorption of Np (Ⅴ) was investigated. The results show that the granite fracture filling materials have strong capacity of Np (Ⅴ) adsorption. The value of K d , for Np (Ⅴ) sorption on the granite fracture filling materials is 843 mL/g. With the increase of pH, the value of K d increases at first and then decreases. K d of Np sorption on granite fracture filling materials in the presence of CO 3 2- and humic acid decreases. The chlorite and feldspar are major contributors to the sorption of Np (Ⅴ) on Beishan granite fracture filling materials. (authors)

  16. Sorption of polycyclic aromatic hydrocarbons on particulate organic matters

    International Nuclear Information System (INIS)

    Guo Xueyan; Luo Lei; Ma Yibing; Zhang Shuzhen

    2010-01-01

    Particulate organic matter (POM) is a key organic matter fraction which can influence soil fertility. Its interactions with hydrophobic organic pollutants (HOCs) have not been characterized and the mechanisms of retention of HOCs by POM remain unclear. In the present study, sorption behaviors of polycyclic aromatic hydrocarbons (PAHs) naphthalene (NAP), phenanthrene (PHE), and pyrene (PYR) by POMs separated from different soils were examined and the POMs were characterized by elemental analysis, solid state 13 C NMR, and Fourier transform infrared spectroscopy (FT-IR). The results indicated that POMs were mainly composed of aliphatic components with high polarity. The different original POMs showed similar chemical composition and configuration. Sorption behaviors of PAHs indicated that there was no significant difference in sorption capacity among the POMs. Sorption of NAP and PHE by POMs displayed a nonlinear isotherm, while sorption of PYR yielded a linear isotherm. No significant hysteresis and ionic strength effect were observed for PAH desorption from the POMs.

  17. Sorption of perfluoroalkyl substances to two types of minerals.

    Science.gov (United States)

    Hellsing, Maja S; Josefsson, Sarah; Hughes, Arwel V; Ahrens, Lutz

    2016-09-01

    The sorption of perfluoroalkyl substances (PFASs) was investigated for two model soil mineral surfaces, alumina (Al2O3) and silica (SiO2), on molecular level using neutron scattering. The PFASs were selected (i.e. perfluorohexanoic acid (PFHxA), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), and perfluorooctane sulfonic acid (PFOS)) to examine the role of hydrophobic chain length and hydrophilic functional group on their sorption behaviour. All four PFASs were found to sorb to alumina surface (positively charged) forming a hydrated layer consisting of 50% PFASs. The PFAS solubility limit, which decrease with chain length, was found to strongly influence the sorption behaviour. The sorbed PFAS layer could easily be removed by gentle rinsing with water, indicating release upon rainfall in the environment. No sorption was observed for PFOA and PFOS at silica surface (negatively charged), showing electrostatic interaction being the driving force in the sorption process. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Sorption behaviour of cobalt-60 on Suez Canal bottom sediments

    International Nuclear Information System (INIS)

    Abdel Gawad, S.A.; El-Shinawy, R.M.K.; Abdel Malik, W.E.Y.

    1981-01-01

    Mineralogical, elemental analysis and sorption behaviour of the Suez Canal bottom sediments in the Port Said area were investigated. It was found that the bottom sediment consist mainly of quartz, feldspars and traces of calcite mineral. The cation-exchange capacity was found to increase as the particle size of the sediment decreased. Sorption of 60 Co by the bottom sediment increased with contact time up to 6 h. Variation of the solution pH from 4 to 9 showed limited increase in the sorption of 60 Co. As carrier concentrations increase from 10 -7 N to 10 -3 N, sorption of Co was found to increase linearly following Freundlich isotherm. The presence of Mg 2+ and Fe 3+ in solution depressed the sorption of 60 Co by the sediments. The desorption of 60 Co from bottom sediment with distilled and Suez Canal water was found to increase with contact time. (author)

  19. Sorption mechanisms of metals to graphene oxide

    International Nuclear Information System (INIS)

    Showalter, Allison R; Bunker, Bruce A; Duster, Thomas A; Szymanowski, Jennifer E S; Na, Chongzheng; Fein, Jeremy B

    2016-01-01

    Environmental toxic metal contamination remediation and prevention is an ongoing issue. Graphene oxide is highly sorptive for many heavy metals over a wide pH range under different ionic strength conditions. We present x-ray absorption fine structure (XAFS) spectroscopy results investigating the binding environment of Pb(II), Cd(II) and U(VI) ions onto multi-layered graphene oxide (MLGO). Analysis indicates that the dominant sorption mechanism of Pb to MLGO changes as a function of pH, with increasing inner sphere contribution as pH increases. In contrast, the sorption mechanism of Cd to MLGO remains constant under the studied pH range. This adsorption mechanism is an electrostatic attraction between the hydrated Cd +2 ion and the MLGO surface. The U(VI), present as the uranyl ion, changes only subtly as a function of pH and is bound to the surface via an inner sphere bond. Knowledge of the binding mechanism for each metal is necessary to help in optimizing environmental remediation or prevention in filtration systems. (paper)

  20. Mercury Sorption onto Malt Spent Rootlets

    Science.gov (United States)

    Manariotis, I. D.; Anagnostopoulos, V.; Karapanagioti, H. K.; Chrysikopoulos, C.

    2011-12-01

    Mercury is a metal of particular concern due to its toxicity even at relatively low concentrations. The maximum permissible level for mercury in drinking water set by the European Union is 0.001 mg/L. Mercury is released into the environment via four principal pathways: (1) natural processes; i.e. a volcanic eruption, (2) incidental to some other activity; i.e. coal burning power plants, (3) accidentally during the manufacture, breakage or disposal of products that have mercury put into them deliberately, and (4) direct use in industrial settings. The present study focuses on the removal of mercury (II) from aqueous solutions via sorption onto Malt Spent Rootlets (MSR). Batch experiments were conducted employing MSR with size ranging from 0.18 to 1 mm. The effects of pH, mercury concentration, contact time, and solid to liquid ratio on mercury sorption onto MSR were investigated. The highest mercury removal from the aqueous phase, of 41%, was observed at pH of 5.

  1. Tritium sorption by cement and subsequent release

    International Nuclear Information System (INIS)

    Ono, F.; Yamawaki, M.

    1995-01-01

    In a fusion reactor or tritium-handling facilities, contamination of concrete by tritium and subsequent release from it to the reator or experimental room is a matter of problem for safe control of tritium and management of operational environment. In order to evaluate this tritium behavior, interaction of tritiated water with concrete or cement should be clarified. In the present study, HTO sorption and subsequent release from cement were experimentally studied.(1)Sorption experiments were conducted using columns packed with cement particles of different sizes. From the analysis of the breakthrough curve, tritium diffusivity in macropores and microparticles were evaluated.(2)From the short-term tritium release experiments, effective desorption rate constants were evaluated and the effects of temperature and moisture were studied.(3)In the long-term tritium release experiments to 6000h, the tritium release mechanism was found to be composed of three kinds of water: initially from capillary water, and in the second stage from gel water and from the water in the cement crystal.(4)Tritium release behavior by heat treatment to 800 C was studied. A high temperature above 600 C was required for the tritium trapped in the crystal water to be released. (orig.)

  2. Sorption of uranium by cellulose derivatives

    International Nuclear Information System (INIS)

    Muroi, M.; Imai, S.; Hamaguchi, A.

    1985-01-01

    The sorption behaviour of uranium was investigated by batch and column methods using four cellulose derivatives, two having an amino group and two having an amino group plus a dithiocarboxylate group. All four derivatives showed maximum uranium sorption from pure water in the neutral region or from artificial sea water in the acidic region. In the batch method, quantitative removal of 100 μg of uranium from 50 ml of water at pH 5.0 was achieved by equilibration with 50 mg of any of the four sorbents. The percentage removal under these conditions decreased gradually with increasing concentration of uranium above 100 μg per 50 ml. A similar high percentage removal of uranium was achieved using artificial sea water. In the column method, quantitative removal of 5 μg of uranium from 1l of water at pH 6.7 was achieved with 200 mg of either of the two sorbents. Similar quantitative removal of uranium was achieved from 1l of artificial sea water at pH 5.4 with 500 mg of either of the two sorbents. (author)

  3. Uranium sorption on tezontle volcanic rock

    Energy Technology Data Exchange (ETDEWEB)

    Lopez M, B. E.; Duran B, J. M.; Iturbe G, J. L.; Olguin G, M. T., E-mail: beatriz.lopez@inin.gob.m [ININ, Departamento de Quimica, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2009-07-01

    It is described a study that demonstrates that hexavalent uranium ions were sorbed by the naturally occurring mineral using a batch technique. This mineral is found in abundant quantities in Mexico. Our study focused on the separation of U Vi from synthetic aqueous systems of both H{sub 2}O-UO{sub 2}(NO{sub 3}){sub 2}.6H{sub 2}O (acid) and H{sub 2}O-Na{sub 4}[UO{sub 2}(CO{sub 3}){sub 3}] (basic). The chemical speciation was performed by using high voltage electrophoresis, and the uranium content was determined by UV-Vis spectroscopy. The quantified U(Vi) sorption by tezontle from acidic and basic systems was 2.72 and 1.68 mumol/g, respectively, and the sorption behavior is discussed considering the surface charge of the tezontle at different ph values based on the point of zero charge characteristic of this material. (Author)

  4. Gas Sorption, Diffusion, and Permeation in Nafion

    KAUST Repository

    Mukaddam, Mohsin Ahmed

    2015-12-22

    The gas permeability of dry Nafion films was determined at 2 atm and 35 °C for He, H2, N2, O2, CO2, CH4, C2H6, and C3H8. In addition, gas sorption isotherms were determined by gravimetric and barometric techniques as a function of pressure up to 20 atm. Nafion exhibited linear sorption uptake for low-solubility gases, following Henry’s law, and convex behavior for highly sorbing condensable gases, indicating rubber-like behavior at 35 °C. XRD results demonstrated that Nafion contains bimodal amorphous chain domains with average d-spacing values of 2.3 and 5.3 Å. Only helium and hydrogen showed relatively high gas permeability of 37 and 7 barrers, respectively; all other gases exhibited low permeability that decreased significantly as penetrant size increased. Dry Nafion was characterized by extraordinarily high selectivities: He/H2 = 5.2, He/CH4 = 445, He/C2H6 = 1275, He/C3H8 = 7400, CO2/CH4 = 28, CO2/C2H6 = 79, CO2/C3H8 = 460, H2/CH4 = 84, H2/C2H6 = 241, and H2/C3H8 = 1400. These high selectivities could make Nafion a potential candidate membrane material for dry feeds for helium recovery and carbon dioxide separation from natural gas and removal of higher hydrocarbons from hydrogen-containing refinery gases.

  5. Status of sorption information retrieval system

    International Nuclear Information System (INIS)

    Hostetler, D.D.; Serne, R.J.; Brandstetter, A.

    1979-09-01

    A Sorption Information Retrieval System (SIRS) is being designed to provide an efficient, computerized, data base for information on radionuclide sorption in geologic media. The data bank will include Kd values for a large number of radionuclides occurring in radioactive wastes originating from the commercial nuclear power industry. Kd values determined to date span several groundwater compositions and a wide variety of rock types and minerals. The data system will not only include Kd values, but also background information on the experiments themselves. This will allow the potential user to retrieve not only the Kd values of interest but also sufficient information to evaluate the accuracy and usefulness of the data. During FY-1979, the logic structure of the system was designed, the software programmed, the data categories selected, and the data format specified. About 40% of the approximately 5000 Kd experiments performed by the Waste Isolation Safety Assessment Program (WISAP) and its subcontractors during FY-1977 and FY-1978 have been evaluated, coded and keypunched. Additional software improvements and system testing are needed before the system will be fully operational. A workshop requested by the NEA was held to discuss potential internatioal participation in the data system

  6. Immobilization of metal hexa-cyanoferrates in chitin beads for cesium sorption: synthesis and characterization

    International Nuclear Information System (INIS)

    Vincent, T.; Guibal, E.; Vincent, C.; Barre, Y.; Guari, Y.; Le Saout, G.

    2014-01-01

    Five metal-potassium hexacyanoferrate/chitin composites (based on Cu, Ni, Zn, Co or Fe co-metal) have been prepared and characterized, using SEM-EDX, TEM, X-ray diffraction and FT-IR, before being compared for Cs(I) and 137 Cs(I) sorption. The Zn-ion exchanger was characterized by a much larger crystal size of about 250 nm compared with a few tens of nm for other ion-exchangers. The ion exchangers are well distributed in the whole mass of the composite and they are fully accessible to Cs(I), as evidenced by Cs(I) distribution after metal sorption. Uptake kinetics can be modeled using both the pseudo-second order rate equation and the Crank equation (resistance to intra-particle diffusion coefficient). Sorption isotherms showed substantial differences in the sorbents that can be ranked as Cu ≥ Ni ≥ Zn ≥ Co ≥ Fe. However, based on 137 Cs K d values, the sorbents can be ranked as Co≥≥Fe≥≥Cu≥≥Ni≥Zn. Taking into account the cost and toxicity of metals (both in terms of manufacturing and potential metal release) a Prussian Blue based sorbent (i.e., iron-potassium hexacyanoferrate/chitin composite) sounds to be a good composite for Cs(I) recovery from radionuclide-containing effluents. (authors)

  7. Management and communication courses – Places available

    CERN Multimedia

    2012-01-01

    There are places available in some management and communication courses taking place in the period January to March 2013.   For more information on the course, click on the course title, which will bring you to the training catalogue. You can then sign-up on-line. For advice, you can contact: Erwin Mosselmans, tel. 74125, erwin.mosselmans@cern.ch Nathalie Dumeaux, tel. 78144, nathalie.dumeaux@cern.ch Courses in English (or bilingual) Session Duration Language Availability How to get, as a supervisor, the most out of the annual interview 21 January 1 day English 2 places Project Engineering 24 and 25 January 2 days English 6 places How to get, as a supervisor, the most out of the annual interview 31 January 1 day English 6 places Conflict Resolution for Managers 19 and 20 February 2 days English One more place Project Scheduling & Costing 6 and 7 March 2 days English 2 places Communicati...

  8. Sorption and diffusion of Cs and I in concrete

    International Nuclear Information System (INIS)

    Andersson, K.; Torstenfelt, B.; Allard, B.

    1983-01-01

    Concrete has been suggested as a possible encapsulation material for long-term storage of low and medium level radioactive waste. At an underground storage of concrete encapsulated waste, a slow release of radioactive elements into the groundwater by diffusion through the concrete must be considered in the safety analysis. The diffusion may be delayed by sorption reactions on the solid. A wide range of long-lived radionuclides may be present in the low and medium level radioactive waste. Here, the sorption and diffusion of iodide and cesium on slag cement paste and concrete has been studied. The influence of four different water phases (pore water, groundwater, Baltic Sea water and sea water) as well as the influence of some added species (carbonate, sulphate and magnesium) has been investigated. A significant sorption of iodide on cement paste in contact with pore water was observed, indicating that the diffusion may be expected to be retarded in this medium. For cesium the highest sorption was found for concrete and groundwater. This means that the sorption increases as the concrete is weathered. Low or insignificant sorption was found for the cement paste, indicating that the ballast is responsible for the Cs-sorption. Carbonatization enhances the Cs-sorption by about a factor of 3. The diffusivity of Cs in concrete and cement paste was determined to between 2x10 - 14 and 8x10 - 14 m 2 /s in pore water (where an insignificant sorption was observed). The choice of ballast as well as addition of suitable getters with high sorption of the long-lived radionuclides might decrease the mass transfer rate through the cement. (Authors)

  9. Effect of humic acid on sorption of technetium by alumina

    International Nuclear Information System (INIS)

    Kumar, S.; Rawat, N.; Kar, A.S.; Tomar, B.S.; Manchanda, V.K.

    2011-01-01

    Highlights: → Tc sorption on alumina has been studied under aerobic as well anaerobic condition over pH 3-10. → Effect of humic acid on sorption of Tc by alumina has been investigated. → Linear additive modeling and surface complexation modeling were carried out to delineate the role of humic acid in Tc(IV) sorption in ternary system of Tc(IV)-humic acid-alumina. → Sorption of humic acid onto alumina and strong complexation of Tc(IV) with humic acid were found to govern the sorption of Tc(IV) in the ternary system. - Abstract: Sorption of technetium by alumina has been studied in absence as well as in presence of humic acid using 95 Tc m as a tracer. Measurements were carried out at fixed ionic strength (0.1 M NaClO 4 ) under varying pH (3-10) as well as redox (aerobic and reducing anaerobic) conditions. Under aerobic conditions, negligible sorption of technetium was observed onto alumina both in absence and in presence of humic acid. However, under reducing conditions (simulated with [Sn(II)] = 10 -6 M), presence of humic acid enhanced the sorption of technetium in the low pH region significantly and decreased at higher pH with respect to that in absence of humic acid. Linear additive as well as surface complexation modeling of Tc(IV) sorption in presence of humic acid indicated the predominant role of sorbed humic acid in deciding technetium sorption onto alumina.

  10. Take Charge. Take the Test. PSA (:30)

    Centers for Disease Control (CDC) Podcasts

    2012-03-07

    As part of the Take Charge. Take the Test. campaign, this 30 second PSA encourages African American women to get tested for HIV. Locations for a free HIV test can be found by visiting hivtest.org/takecharge or calling 1-800-CDC-INFO (1-800-232-4636).  Created: 3/7/2012 by National Center for HIV/AIDS, Viral Hepatitis, STD, and TB Prevention (NCHHSTP).   Date Released: 3/7/2012.

  11. Alkali release and sorption during combustion and gasification of coal under pressure; Freisetzung und Einbindung von Alkalien bei der Verbrennung und Vergasung von Kohle unter Druck

    Energy Technology Data Exchange (ETDEWEB)

    Steffin, C.R.; Wanzl, W.; Heek, K.H. van [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Geschaeftsbereich FuelTec - Kokerei- und Brennstofftechnik

    1999-09-01

    Investigations and model calculations have shown that water-soluble alkaline substances (in German coal, mostly NaCl) are released by a desorption process rather than a purely physical evaporation process. Sorption takes place in the presence of reactive oxygen species (H{sub 2}O or O{sub 2}), but only the reaction with water vapour is applicable to technical processes. Soorption is preferred to desorption at low temperatures both kinetically and thermodynamically. Metakaolin has a high alkali sorption capacity and potential depending significantly on the chemical properties of the clay mineral. With increasing basicity, the sorption potential decreases drastically, which has a significant effect in terms of fuel selection and mode of operation of the process of coal dust combustion under pressure. A fuel with low alkali emissions would be a coal grade with a small fraction of water-soluble alkalis and a high fraction of acid clay minerals. Intensive scrubbing in a wet chemical treatment stage may serve to reduce the water-soluble alkalis. [Deutsch] Die Untersuchungen und Modellrechnungen haben gezeigt, dass die Freisetzung der wasserloeslichen Alkalien, was in deutschen Steinkohlen hauptsaechlich NaCl ist, ein Desorptionsmechanismus zugrunde liegt und die Vorstellung eines rein physikalischen Verdampfungsprozesses verworfen werden muss. Die Einbindung der Alkalien findet unter Teilnahme reaktiver Sauerstoffspezies (H{sub 2}O oder O{sub 2}) statt, wobei aber nur die Reaktion mit Wasserdampf auch auf technische Prozesse uebertragbar ist. Die Einbindung ist gegenueber der Desorption bei niedrigen Temperaturen kinetisch und thermodynamisch bevorzugt. Metakaolin besitzt eine hohe Kapazitaet und ein hohes Potential zur Einbindung von Alkalien, wobei die Faehigkeit zur Einbindung ganz entscheidend von den chemischen Eigenschaften des Tonminerals abhaengig ist. Mit steigender Basizitaet nimmt das Einbindungspotential der Mineralsubstanz drastisch ab. Das hat auch

  12. Water sorption kinetics of damaged beans: GAB model

    Directory of Open Access Journals (Sweden)

    Fernanda M. Baptestini

    Full Text Available ABSTRACT The objective of this study was to model the water sorption kinetics of damaged beans. Grains with initial moisture content of 53.85%, dry basis (d.b., were used. One portion of the grains was used to obtain desorption isotherms, while the other was subjected to drying until the moisture content of 5.26% (d.b., so that it was subjected to the adsorption. For the induction of damage, a Stein Breakage Tester was used. To obtain the equilibrium moisture content, grains were placed in a climatic chamber at 20, 30, 40 and 50 ± 1 °C combined with relative humidity of 30, 40, 50, 70 and 90 ± 3%. The GAB model fitted well to the equilibrium moisture experimental data of damaged grains and control. With increasing temperature, the monolayer moisture contents decreased in adsorption and desorption processes, ranging from 9.84 to 5.10% d.b. The lower moisture content in the monolayer in damaged grains indicates that lower moisture content is necessary to ensure their conservation.

  13. Mechanistic Processes Controlling Gas Sorption in Shale Reservoirs

    Science.gov (United States)

    Schaef, T.; Loring, J.; Ilton, E. S.; Davidson, C. L.; Owen, T.; Hoyt, D.; Glezakou, V. A.; McGrail, B. P.; Thompson, C.

    2014-12-01

    Utilization of CO2 to stimulate natural gas production in previously fractured shale-dominated reservoirs where CO2 remains in place for long-term storage may be an attractive new strategy for reducing the cost of managing anthropogenic CO2. A preliminary analysis of capacities and potential revenues in US shale plays suggests nearly 390 tcf in additional gas recovery may be possible via CO2 driven enhanced gas recovery. However, reservoir transmissivity properties, optimum gas recovery rates, and ultimate fate of CO2 vary among reservoirs, potentially increasing operational costs and environmental risks. In this paper, we identify key mechanisms controlling the sorption of CH4 and CO2 onto phyllosilicates and processes occurring in mixed gas systems that have the potential of impacting fluid transfer and CO2 storage in shale dominated formations. Through a unique set of in situ experimental techniques coupled with molecular-level simulations, we identify structural transformations occurring to clay minerals, optimal CO2/CH4 gas exchange conditions, and distinguish between adsorbed and intercalated gases in a mixed gas system. For example, based on in situ measurements with magic angle spinning NMR, intercalation of CO2 within the montmorillonite structure occurs in CH4/CO2 gas mixtures containing low concentrations (hydrocarbon recovery processes.

  14. Extended sorption partitioning models for pesticide leaching risk assessments: Can we improve upon the k{sub oc} concept?

    Energy Technology Data Exchange (ETDEWEB)

    Jarvis, Nicholas, E-mail: nicholas.jarvis@slu.se

    2016-01-01

    Models used to assess leaching of pesticides to groundwater still rely on the sorption k{sub oc} value, even though its limitations have been known for several decades, especially for soils of low organic carbon content (i.e. subsoils). This is mainly because the general applicability of any improved model approach that is also simple enough to use for regulatory purposes has not been demonstrated. The objective of this study was to test and compare alternative models of sorption that could be useful in pesticide risk assessment and management. To this end, a database containing the results of batch sorption experiments for pesticides was compiled from published studies in the literature, which placed at least as much emphasis on measurements in subsoil horizons as in topsoil. The database includes 785 data entries from 34 different published studies and for 21 different active substances. Overall, the apparent k{sub oc} value, k{sub oc(app)}, roughly doubled as the soil organic carbon content decreased by a factor of ten. Nevertheless, in nearly half of the individual datasets, a constant k{sub oc} value proved to be an adequate model. Further analysis showed that significant increases in k{sub oc(app)} in subsoil were found primarily for the more weakly adsorbing compounds (k{sub oc} values < ca. 100–200 L kg{sup −1}) and that sorption to clay in loamy and clayey-textured subsoil horizons was the main cause. Tests with the MACRO model demonstrated that sorption to clay minerals may significantly affect the outcome of regulatory exposure and risk assessments for leaching to groundwater. The k{sub oc} concept currently used in leaching models should therefore be replaced by an alternative approach that gives a more realistic representation of pesticide sorption in subsoil. The two alternative models tested in this study appear to have widespread applicability and are also simple enough to parameterize for this purpose. - Highlights: • A database was collated

  15. The value of place

    Science.gov (United States)

    Dentzau, Michael W.

    2014-03-01

    This commentary seeks to expand the dialogue on place-based science education presented in Katie Lynn Brkich's article, where the connections fifth grade students make between their formal earth science curriculum and their lived experiences are highlighted. The disconnect between the curriculum the students are offered and their immediate environment is clear, and we are presented with examples of how they strive to make connections between the content and what they are familiar with—namely their surroundings. "Place" is identified as a term with complex meanings and interpretations, even in the scope of place-based science education, and understanding how the term is used in any given scenario is essential to understanding the implications of place-based education. Is place used as a location, locale or a sense of place? To understand "place" is to acknowledge that for the individual, it is highly situational, cultural and personal. It is just such attributes that make place-based education appealing, and potentially powerful, pedagogically on one hand, yet complex for implementation on the other. The argument is posed that place is particularly important in the context of education about the environment, which in its simplest manifestation, connects formal science curriculum to resources that are local and tangible to students. The incorporation of place in such a framework seeks to bridge the gap between formal school science subjects and students' lived experiences, yet acknowledges the tensions that can arise between accommodating place meanings and the desire to acculturate students into the language of the scientific community. The disconnect between guiding policy frameworks and the reality of the Next Generation Science Standards is addressed opening an avenue for further discussion of the importance of socio-cultural frameworks of science learning in an ever increasing era of accountability.

  16. Technical training: places available

    CERN Multimedia

    HR Department

    2007-01-01

    CERN Technical Training: Open Courses (April - June 2007) The following course sessions are currently scheduled in the framework of the CERN Technical Training Programme 2007:   AutoCAD 2006 - niveau 1 (course in French): 25.4.- 26.4.2007 & 2.5. - 3.5.2007 (4 days in 2 modules, 5 places available) AutoCAD 2006 - niveau 1 (course in French): 27.6.- 28.6.2007 & 3.7. - 4.7.2007 (4 days in 2 modules, 5 places available) AutoCAD Mechanical 2006 (course in French) 21.6.-22.6.2007 (2 days, 8 places available) * NEW COURSE* Automate de securite S7 (course in French) 14.5.-16.5.2007 (3 days, 4 places available) * NEW COURSE* Automate de securite S7 (course in French): 9.5.-11.5.2007 (3 days, 4 places available) JCOP - Joint PVSS-JCOP Frameswork (course in English): 21.5.-25.5.2007 (5 days, 12 places available) JCOP - Finite State Machines in the JCOP Frameswork (course in English): 12.6.-14.6.2007 (3 days, 12 places available) LabVIEW Basics 1 (in English): 2.-4.5.2007 (3 days, 7 places ...

  17. A Sense of Place

    Directory of Open Access Journals (Sweden)

    Rachel Black

    2012-09-01

    Full Text Available People increasingly want to know where their food and wine comes from and who produces it. This is part of developing a taste of place, or what the French call terroir. The academic and industry debates surrounding the concept of terroir are explored, and the efforts of Massachusetts wine producers to define their sense of place are discussed.

  18. Place in transition

    DEFF Research Database (Denmark)

    Mikkelsen, Jacob Bjerre; Lange, Ida Sofie Gøtzsche

    2017-01-01

    World. This paper discusses the conception of place in the Oil World, with the relocation and transformation of oil rigs from an urban design perspective as its point of departure, using Esbjerg, Denmark, as a case study. Combining a theoretical understanding of places as relational with a design...

  19. The Case for Place

    Science.gov (United States)

    Thomas, Lisa Carlucci

    2012-01-01

    Bookstores, record stores, libraries, Facebook: these places--both physical and virtual--demonstrate an established and essential purpose as centers of community, expertise, convenience, immediacy, and respect. Yet as digital, mobile, and social shifts continue to transform culture and interactions, these spaces and places transform, too.…

  20. Sorption of cesium in young till soils

    Energy Technology Data Exchange (ETDEWEB)

    Lusa, Merja; Lempinen, Janne; Ahola, Hanna; Soederlund, Mervi; Lehto, Jukka [Helsinki Univ. (Finland). Laboratory of Radiochemistry; Lahdenperae, Anne-Maj [Saanio and Riekkola Oy, Consulting Engineers, Helsinki (Finland); Ikonen, Ari T.K. [Posiva Oy, Eurajoki (Finland)

    2014-10-01

    Soil samples from three forest soil pits were examined down to a depth of approximately three metres using 1 M ammonium acetate extraction and microwave-assisted extraction with concentrated nitric acid (HNO{sub 3}), to study the binding of cesium (Cs) at Olkiluoto Island, southern Finland. Ammonium acetate was used to extract the readily exchangeable Cs fractions roughly representing the Cs fraction in soil which is available for plants. Microwave-assisted HNO{sub 3} extraction dissolves various minerals, e.g. carbonates, most sulphides, arsenides, selenides, phosphates, molybdates, sulphates, iron (Fe) and manganese (Mn) oxides and some silicates (olivine, biotite, zeolite), and reflects the total Cs concentrations. Cs was mostly found in the strongly bound fraction obtained through HNO{sub 3} extraction. The average Cs concentrations found in this fraction were 3.53 ± 0.30 mg/kg (d.w.), 3.06 ± 1.86 mg/kg (d.w.) and 1.83 ± 0.42 mg/kg (d.w.) in the three soil pits, respectively. The average exchangeable Cs found in the ammonium acetate extraction in all three sampling pits was 0.015 ± 0.008 mg/kg (d.w.). In addition, Cs concentrations in the soil solution were determined and in situ distribution coefficients (K{sub d}) for Cs were calculated. Furthermore, the in situ K{sub d} data was compared with the Cs K{sub d} data obtained using the model batch experiments. The in situ K{sub d} values were observed to fairly well follow the trend of batch sorption data with respect to soil depth, but on average the batch distribution coefficients were almost an order of magnitude higher than the in situ K{sub d} data. In situ Cs sorption data could be satisfactory fitted with the Langmuir sorption isotherm, but the Freundlich isotherm failed to fit the data. Finally, distribution coefficients were calculated by an ion exchange approach using soil solution data, the cation exchange capacity (CEC) as well as Cs to sodium (Na) and Cs to potassium (K) ion exchange selectivity

  1. A suggested approach toward measuring sorption and applying sorption data to repository performance assessment

    International Nuclear Information System (INIS)

    Rundberg, R.S.

    1992-01-01

    The prediction of radionuclide migration for the purpose of assessing the safety of a nuclear waste repository will be based on a collective knowledge of hydrologic and geochemical properties of the surrounding rock and groundwater. This knowledge along with assumption about the interactions of radionuclides with groundwater and minerals form the scientific basis for a model capable of accurately predicting the repository's performance. Because the interaction of radionuclides in geochemical systems is known to be complicated, several fundamental and empirical approaches to measuring the interaction between radionuclides and the geologic barrier have been developed. The approaches applied to the measurement of sorption involve the use of pure minerals, intact, or crushed rock in dynamic and static experiments. Each approach has its advantages and disadvantages. There is no single best method for providing sorption data for performance assessment models which can be applied without invoking information derived from multiple experiments. 53 refs., 12 figs

  2. Non-Place

    DEFF Research Database (Denmark)

    formulation. The anthology contains 17 articles engaged directly in the application, retrofitting and broadening of the concept of the non-place to a range of literary and media texts, as well as the merging of this concept to other theoretical concepts by e.g. Michel Foucault, Gilles Deleuze, Alain Badiou......We spend more and more of our everyday lives in what Marc Augé calls non-places – homogenous, but bland places of transit. This anthology addresses the representations of non-places in literature, culture and media, and critiques and re-actualizes Augé’s work twenty years after its initial...... Jutland, and many others. This anthology is the seventh publication in the IRGiC series and it springs from a research seminar held at Aalborg University in May 2013: “Non-Place in Literature, Media and Culture”....

  3. Place-Specific Computing

    DEFF Research Database (Denmark)

    Messeter, Jörn; Johansson, Michael

    project place- specific computing is explored through design oriented research. This article reports six pilot studies where design students have designed concepts for place-specific computing in Berlin (Germany), Cape Town (South Africa), Rome (Italy) and Malmö (Sweden). Background and arguments...... for place-specific computing as a genre of interaction design are described. A total number of 36 design concepts designed for 16 designated zones in the four cities are presented. An analysis of the design concepts is presented indicating potentials, possibilities and problems as directions for future......An increased interest in the notion of place has evolved in interaction design. Proliferation of wireless infrastructure, developments in digital media, and a ‘spatial turn’ in computing provides the base for place-specific computing as a suggested new genre of interaction design. In the REcult...

  4. Technical training - places available

    CERN Multimedia

    2012-01-01

    If you would like more information on a course, or for any other inquiry/suggestions, please contact Technical.Training@cern.ch Valeria Perez Reale, Learning Specialist, Technical Programme Coordinator (Tel.: 62424) Eva Stern and Elise Romero, Technical Training Administration (Tel.: 74924) HR Department »Electronics design Next Session Duration Language Availability Comprehensive VHDL for FPGA Design 08-Oct-12 to 12-Oct-12 5 days English 3 places available Foundations of Electromagnetism and Magnet Design (EMAG) 14-Nov-12 to 27-Nov-12 6 days English 20 places available Impacts de la suppression du plomb (RoHS) en électronique 26-Oct-12 to 26-Oct-12 8 hours French 15 places available Introduction to VHDL 10-Oct-12 to 11-Oct-12 2 days English 7 places available LabVIEW Real Time and FPGA 13-Nov-12 to 16-Nov-12 5 days French 5 places available »Mechanical design Next Se...

  5. Study of sorption processes of copper on synthetic hydroxyapatite

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Galambos, M.; Ometakova, J.; Rajec, P.; Caplovicova, M.

    2012-01-01

    The sorption of copper on synthetic hydroxyapatite was investigated using a batch method and radiotracer technique. The hydroxyapatite sample prepared by a wet precipitation process was of high crystallinity with Ca/P ratio of 1.688. The sorption of copper on hydroxyapatite was pH independent ranging from 4 to 6 as a result of buffering properties of hydroxyapatite. The adsorption of copper was rapid and the percentage of Cu sorption was >98% during the first 15-30 min of the contact time. The experimental data for sorption of copper have been interpreted in the term of Langmuir isotherm. The sorption of Cu 2+ ions was performed by ion-exchange with Ca 2+ cations on the crystal surface of hydroxyapatite under experimental conditions. The competition effect of Zn 2+ , Fe 2+ and Pb 2+ towards Cu 2+ sorption was stronger than that of Co 2+ , Ni 2+ and Ca 2+ ions. The ability of the bivalent cations to depress the sorption of copper on hydroxyapatite was in the following order Pb 2+ > Fe 2+ > Zn 2+ > Co 2+ ∼ Ni 2+ . (author)

  6. Sorption of U(VI) species on hydroxyapatite

    International Nuclear Information System (INIS)

    Thakur, P.; Moore, R.C.; Choppin, G.R.

    2005-01-01

    The sorption of uranyl (UO 2 2+ ) cations to hydroxyapatite was studied as a function of the amount of sorbent, ionic strength, U(VI) concentration, pH and temperature. The rate of uranyl sorption on hydroxyapatite decreased with increased uranyl concentrations. The amount sorbed decreased with increased ionic strength and increased with pH to a maximum at 7-8. The sorption data for UO 2 2+ were fitted well by the Freundlich and Dubinin-Radushkevich (D-R) isotherms. The anions Cl - , NO 3 - , SO 4 2- and CH 3 COO - decreased the sorption of uranium on hydroxyapatite while S 2 O 3 2- slightly increased it. The sorbed uranium was desorbed by 0.10 M and 1.00 M solutions of HCl and HNO 3 . The thermodynamic parameters for the sorption of UO 2 2+ were measured at temperatures of 298, 313, 323 and 333 K. The temperature dependence confirmed an endothermic heat of sorption. The activation energy for the sorption process was calculated to be +2.75±0.02 kJ/mol. (orig.)

  7. Artificial Weathering of Biotite and Uranium Sorption Characteristics

    International Nuclear Information System (INIS)

    Lee, Seung Yeop; Baik, Min Hoon; Lee, Jae Kwang

    2009-01-01

    An experiment for uranium sorption onto fresh and weathered biotites was performed. After centrifugation, concentrations of uranium in the supernatants were analyzed using ICP-MS, and biotite samples were investigated using XRD and SEM. With powdered biotites (<3 mm in size), we have conducted uranium sorption experiments about fresh and weathered biotites to obtain uranium sorption amounts in various pH conditions. The uranium sorption was not high at a low pH (e.g., pH 3), but increased with increasing pH. There were lower uranium sorption by the weathered biotites than by the fresh ones, and the difference was much larger at higher pH (e.g., pH 11). The lower sorption values of uranium by the weathered biotites may be caused by a change of mineral surfaces and a chemical behavior of surrounding dissolved elements. It seems that the uranium-mineral interaction has been diminished, especially, in the weathered biotite by a destruction and dissolution of preferential sorption sites on the mineral surfaces and by the colloidal formation from dissolved elements.

  8. Mechanisms of metal sorption by biochars: Biochar characteristics and modifications.

    Science.gov (United States)

    Li, Hongbo; Dong, Xiaoling; da Silva, Evandro B; de Oliveira, Letuzia M; Chen, Yanshan; Ma, Lena Q

    2017-07-01

    Biochar produced by thermal decomposition of biomass under oxygen-limited conditions has received increasing attention as a cost-effective sorbent to treat metal-contaminated waters. However, there is a lack of information on the roles of different sorption mechanisms for different metals and recent development of biochar modification to enhance metal sorption capacity, which is critical for biochar field application. This review summarizes the characteristics of biochar (e.g., surface area, porosity, pH, surface charge, functional groups, and mineral components) and main mechanisms governing sorption of As, Cr, Cd, Pb, and Hg by biochar. Biochar properties vary considerably with feedstock material and pyrolysis temperature, with high temperature producing biochars with higher surface area, porosity, pH, and mineral contents, but less functional groups. Different mechanisms dominate sorption of As (complexation and electrostatic interactions), Cr (electrostatic interactions, reduction, and complexation), Cd and Pb (complexation, cation exchange, and precipitation), and Hg (complexation and reduction). Besides sorption mechanisms, recent advance in modifying biochar by loading with minerals, reductants, organic functional groups, and nanoparticles, and activation with alkali solution to enhance metal sorption capacity is discussed. Future research needs for field application of biochar include competitive sorption mechanisms of co-existing metals, biochar reuse, and cost reduction of biochar production. Published by Elsevier Ltd.

  9. Role of interlayer hydration in lincomycin sorption by smectite clays.

    Science.gov (United States)

    Wang, Cuiping; Ding, Yunjie; Teppen, Brian J; Boyd, Stephen A; Song, Cunyi; Li, Hui

    2009-08-15

    Lincomycin, an antibiotic widely administered as a veterinary medicine, is frequently detected in water. Little is known about the soil-water distribution of lincomycin despite the fact that this is a major determinant of its environmental fate and potential for exposure. Cation exchange was found to be the primary mechanism responsible for lincomycin sorption by soil clay minerals. This was evidenced by pH-dependent sorption, and competition with inorganic cations for sorptive sites. As solution pH increased, lincomycin sorption decreased. The extent of reduction was consistent with the decrease in cationic lincomycin species in solution. The presence of Ca2+ in solution diminished lincomycin sorption. Clay interlayer hydration status strongly influenced lincomycin adsorption. Smectites with the charge deficit from isomorphic substitution in tetrahedral layers (i.e., saponite) manifest a less hydrated interlayer environment resulting in greater sorption than that by octahedrally substituted clays (i.e., montmorillonite). Strongly hydrated exchangeable cations resulted in a more hydrated clay interlayer environment reducing sorption in the order of Ca- smectite. X-ray diffraction revealed that lincomycin was intercalated in smectite clay interlayers. Sorption capacity was limited by clay surface area rather than by cation exchange capacity. Smectite interlayer hydration was shown to be a major, yet previously unrecognized, factor influencing the cation exchange process of lincomycin on aluminosilicate mineral surfaces.

  10. Web-based sorption database (KAERI-SDB)

    International Nuclear Information System (INIS)

    Lee, Jae Kwang; Baik, Min Hoon

    2010-10-01

    Radionuclide sorption data is necessary for the safety assessment of radioactive waste disposal. However the accessibility to the nuclide sorption database is limited. The web-based sorption database (KAERI-SDB) was developed to provide sorption data in a convenient way. The development of the KAERI-SDB was achieved by improving the performance of pre-existing sorption DB programme (SDB-21C) and incorporating the user requirement. The KAERI-SDB was designed that users can access it by using a web browser. Main functions of the KAERI-SDB include (1) log-in/join, (2) search and store of sorption data and (3) scatter plot chart and index chart. It is expected that the KAERI-SDB is widely applied to the safety assessment of radioactive waste disposal by enhancing the accessibility to experts and practitioner related the nuclear industry and governmental administration. It is also expected that reliabilities for the radioactive waste disposal increased by opening the web-based sorption DB to public

  11. A mechanistic approach to the generation of sorption databases

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    1992-01-01

    Sorption of radionuclides in the near and far fields of an underground nuclear waste repository is one of the most important processes retarding their release to the environment. In the vast majority of cases sorption data have been presented in terms of empirical parameters such as distribution coefficients and isotherm equations. A consequence of this empirical methodology is that the sorption data are only strictly valid under the experimental conditions at which they were measured. Implicit in this approach is the need to generate large amounts of data and fitting parameters necessary for an empirical description of sorption under all realistically conceivable conditions which may arise in space and time along the migration pathway to Man. An alternative approach to the problem is to try to understand, and develop model descriptions of, underlying retention mechanisms and to identify those systems parameters which essentially determine the extent of sorption. The aim of this work is to see to what extent currently existing mechanistic models, together with their associated data, can be applied to predict sorption data from laboratory experiments on natural systems. This paper describes the current status of this work which is very much in an early stage of development. An example is given whereby model predictions are compared with laboratory results for the sorption of Np at trace concentrations under oxidizing conditions on a series of minerals relevant to granite formations. 31 refs., 11 figs., 5 tabs

  12. Water vapor sorption thermodynamics of the Nafion ionomer membrane.

    Science.gov (United States)

    Wadsö, Lars; Jannasch, Patric

    2013-07-18

    The water interactions of polymer electrolyte membranes are of significant interest when these materials are used in, for example, fuel cells. We have therefore studied the sorption thermodynamics of Nafion with a sorption calorimeter that simultaneously measures the sorption isotherm and the mixing (sorption) enthalpy. This unique method is suitable for investigating the sorption thermodynamics of ionic polymers. The measurements were made at 25 °C on a series of samples dried at different temperatures from 25 to 120 °C. The sorption isotherms indicate that the samples dried at 120 °C lost about 0.8 more water molecules per sulfonic group during the drying than did the samples dried at 25 °C, and this result was verified gravimetrically. The mixing enthalpies showed several peaks or plateaus for the samples dried at 60-120 °C. This behavior was seen up to about 2 water molecules per sulfonic group. As these peaks were not directly related to any feature in the sorption isotherm, they probably have their origin in a secondary process, such as a reorganization of the polymer.

  13. Sorption of strontium by magnetically modified yeast cells

    International Nuclear Information System (INIS)

    Hu Yantao; Ji Yanqin; Tian Qing; Shao Xianzhang; Shi Jianhe; Ivo Safarik; Zhang Shengdong; Li Jinying

    2008-01-01

    Magnetically modified fodder's yeast (Kluyveromyces fragilis) cells using water based magnetic fluid, were characterized by scanning electron microscopy (SEM) and Vibrating Sample Magnetometer (VSM). The sorption-desorption properties of Sr 2+ by these yeast cells from nitrate salt of Sr 2+ were studied. The results demonstrated that the Sr 2+ sorption volume by these cells enhanced with increasing pH and reached a plateau between pH 4.0 and 7.0. A minor effect by temperature was observed. The sorption volumes are 19.5 mg/g and 53.5 mg/g from 10 ppm and 40 ppm Sr 2+ solution respectively within 20 min. The sorption of Sr 2+ in these cells can be desorbed under 0.1 mol/L HNO 3 solution. The maximum Sr 2+ sorption volume is 96.7 mg/g at 20℃. The sorption characteristic fits Langmuir model well with 140.8 mg/g calculated maximum sorption volume by these yeast cells. (authors)

  14. On some investigation features of sorption of flotation reagents labelled by soft β-emitters on mineral surface

    International Nuclear Information System (INIS)

    Korobochkin, V.P.; Gladyshev, V.P.; Latypova, O.A.

    1983-01-01

    A correction for self-absorption, taking into account concrete dimensions of mineral grain during sorption of flotation reagents on mineral surface is deduced. On the basis of the regularity obtained problems of the sensitivity of the determination method of reagent activity sorbed by minerals which are labelled by radioactive isotopes are considered. Improved technique is described and statistical analysis of the experimental data obtained is carried out

  15. Where is 'place' in Aging in place?

    DEFF Research Database (Denmark)

    Blaakilde, Anne Leonora

    2015-01-01

    is influenced by universalism, aiming at equality in terms of access to health services and care. However, these welfare provisions seem to be deeply embedded in methodological nationalism, since only citizens with residence within the borders of Denmark have the right to live in public nursing homes or receive......The aim of this article is to contribute a transnational perspective to the field of environmental gerontology and the concept of aging in place. Seniors from the northern hemisphere, among them Danish citizens, are increasingly adapting to transnational lives as they move to warmer climates...... in-home help. It is argued that we should consider public solutions to the problems faced by frail Danish citizens in transnational settings, enhancing their opportunities to live abroad....

  16. Plutonium sorption to nanocast mesoporous carbon

    Energy Technology Data Exchange (ETDEWEB)

    Parsons-Moss, Tashi; Wang, Deborah; Jones, Stephen; Olive, Daniel; Nitsche, Heino [California Univ., Berkeley, CA (United States). Dept. of Chemistry; Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Nuclear Science Div.; Tueysuez, Harun [Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Nuclear Science Div.; Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2014-09-01

    Nanocast ordered mesoporous carbons are attractive as sorbents because of their extremely high surface areas and large pore volumes. This paper compares Pu uptake, added as Pu(VI), to both untreated and chemically oxidized CMK-(carbon molecular sieves from KAIST) type mesoporous carbon with that to a commercial amorphous activated carbon. The CMK was synthesized via nanocasting by using cubic ordered mesoporous silica KIT-6 as a hard template, and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption. A portion of the CMK was oxidized by treatment with nitric acid, and will be called OX CMK. The three carbon powders have similar particle morphology, and high BET surface areas. The activated carbon is disordered, while the CMK materials show large domains of ordered cubic mesostructure. The CMK material seems to have more oxygen-containing functional groups than the activated carbon, and the oxidation of the CMK increased the density of these groups, especially - COOH, thus lowering the point of zero charge (PZC) of the material. Batch studies of all 3 materials with plutonium solutions, in a 0.1 M NaClO{sub 4} matrix were performed to investigate pH dependence, sorption kinetics, Pu uptake capacities, competition with ethylenediaminetetraacetic acid (EDTA) in solution, and Pu desorption. Both CMK materials demonstrated high Pu sorption from solutions of pH 3 or greater, and the oxidized CMK also showed high sorption from pH 2 solutions. The activated carbon bound less Pu, and at a much slower rate than CMK. All other batch experiments were carried out in pH 4 solutions. The Pu uptake from low-concentration solutions was faster for the oxidized CMK than for untreated CMK, but in more concentrated samples (∝ 250 μM Pu), the Pu uptake kinetics and apparent capacity were the same for oxidized and untreated CMK. The 23-h Pu uptake capacity of the CMK

  17. Retention/sorption and geochemical modelling

    Energy Technology Data Exchange (ETDEWEB)

    Arcos, D.; Grandia, F.; Domenech, C. [Enviros Spain, S.L., Barcelona (Spain); SCK-CEN, Mol (Belgium); Sellin, P. [SKB - Swedish Nuclear Fuel and Waste Management, SE, Stockholm (Sweden); Hunter, F.M.I.; Bate, F.; Heath, T.G.; Hoch, A. [Serco Assurance, Oxfordshire (United Kingdom); Werme, L.O. [SKB - Svensk Karnbranslehantering AB, Stockholm (Sweden); Bruggeman, C.; Maes, I.A.; Breynaert, E.; Vancluysen, J. [Leuven Katholieke Univ., Lab. for Colloid Chemistry (Belgium); Montavon, G.; Guo, Z. [Ecole des Mines, 44 - Nantes (France); Riebe, B.; Bunnenberg, C.; Meleshyn, A. [Leibniz Univ. Hannover, Zentrum fur Strahlenschutz und Radiookologie, Hannover (Germany); Dultz, S. [Leibniz Univ. Hannover, Institut fur Bodenkunde, Hannover (Germany)

    2007-07-01

    This session gathers 4 articles dealing with: the long-term geochemical evolution of the near field of a KBS-3 HLNW repository: insights from reactive transport modelling (D. Arcos, F. Grandia, C. Domenech, P. Sellin); the investigation of iron transport into bentonite from anaerobically corroding steel: a geochemical modelling study (F.M.I. Hunter, F. Bate, T.G. Heath, A. Hoch, L.O. Werme); SeO{sub 3}{sup 2-} adsorption on conditioned Na-illite: XAS spectroscopy, kinetics, surface complexation model and influence of compaction (C. Bruggeman, A. Maes, G. Montavon, E. Breynaert, Z. Guo, J. Vancluysen); the influence of temperature and gamma-irradiation on the anion sorption capacity of modified bentonites (B. Riebe, C. Bunnenberg, A. Meleshyn, S. Dultz)

  18. Sorption of radionuclides on a soil

    International Nuclear Information System (INIS)

    Fukui, Masami

    1979-01-01

    Disposal of radioactive wastes into the ground has been discussed, and this paper emphasized significance of the investigation for underground water flow and for the prediction of radionuclides through a stratified aquifer using column experiments to evaluate the internal radiation dose. Distributions and redistributions of radionuclides in a sandy layer were observed to identify the sorption model which predicts the behavior, and the underground water flow in the Plio-Pleistocene Osaka Group was investigated as an example, by mean of the measurement of 222 Rn concentration, the pumping technique and the tracer technique using the activation analysis. Then, the estimation of radioactive concentration in the underground water was worked out for the boundary condition of steady state inflow of liquid wastes and of which the 90 Sr are leached from the solidified body, moreover, the equation which easily evaluates the suitability of the disposal site was proposed. These approach may be useful for the actual site selection of radioactive wastes disposal. (author)

  19. Study of the radium sorption/desorption on goethite

    International Nuclear Information System (INIS)

    Bassot, S.; Stammose, D.; Mallet, C.; Lefebvre, C.; Ferreux, J.-M.

    2000-01-01

    The oxi-hydroxides, present at trace level in uranium mill tailings, are responsible of about 70% of the 226 radium sorption, half being fixed on crystallized forms. This radionuclide (half time=1622y), present at high level (50 to 100kBq.kg -1 ), can be released in groundwater, involving a possible contamination of the food chain (actual concentration limit=0.37Bq.1 -1 ). So, it is very important to point out the mechanisms of the radium sorption/desorption on crystallized oxi-hydroxides as a function of chemical conditions of the system. The radium sorption on synthetic goethite α-FeOOH has been studied as a function of contact time, initial radium activity, pH, sodium and calcium concentrations. The results show that, after one hour of contact time (necessary to reach equilibrium), the radium sorption increases widely in a pH range 6-7. The increase of Na + concentration is without influence on the radium sorption, indicating the low interactions between sodium and surface sites. At the opposite, the presence of calcium in solution decreases widely the radium sorption, that indicates a competition between calcium and radium for the same kind of sorption sites of the oxi-hydroxide surface. The percentage of radium desorbed increases widely with time, from 1 to 120h and becomes constant at a time higher than 120h. This long equilibrium time for desorption in comparison with sorption one can be explain by a local evolution of the sorption sites of the solid, which become less accessible for the solution in contact. (author)

  20. Assessing the Portion of the Crack Length Contributing to Water Sorption in Concrete Using X-ray Absorption

    DEFF Research Database (Denmark)

    Pease, Bradley Justin; Couch, Jon; Geiker, Mette Rica

    2009-01-01

    While it is generally known that cracks accelerate fluid movements, there is a need to quantify how cracks influence the controlling transport mechanism(s) for more accurate service life modeling. This paper describes an experimental approach using x-ray absorption measurements to quantify the in......-ray absorption measurements over time. The effect cracks have on sorption is discussed and compared to the behavior of pristine concrete. In addition, the maximum water sorption depth after one hour of exposure is compared to crack lengths determined by the cracked hinge model.......While it is generally known that cracks accelerate fluid movements, there is a need to quantify how cracks influence the controlling transport mechanism(s) for more accurate service life modeling. This paper describes an experimental approach using x-ray absorption measurements to quantify...... the influence of cracks with varying width and length on water sorption in concrete. Concrete wedge splitting specimens, conditioned to 50% relative humidity, were loaded to varying crack openings. Water sorption was monitored for ponded specimens with varying crack widths and lengths by taking multiple x...

  1. Sorption of Metal Ions on Clay Minerals.

    Science.gov (United States)

    Schlegel; Manceau; Chateigner; Charlet

    1999-07-01

    The local structural environment of Co sorbed on hectorite (a magnesian smectite) has been investigated by polarized EXAFS (P-EXAFS) spectroscopy on a self-supporting film of Co-sorbed hectorite. This sorption sample was prepared by contacting Co and hectorite at pH 6.5 and at high ionic strength (0.3 M NaNO3) to favor pH-dependent sorption reaction over cation exchange. A self-supporting film was elaborated after 120 h of reacting time, when apparent quasi-equilibrium conditions were attained. The half-width at half maximum of the orientation distribution of c* axis of individual clay platelets off the film normal was determined by quantitative texture analysis, and found to be equal to 18.9 degrees. Co K-edge P-EXAFS spectra were recorded at angles between the incident beam and the film normal equal to 0 degrees, 35 degrees, 50 degrees, and 60 degrees; the 90 degrees spectrum was obtained by extrapolation. Spectral analysis led to the identification of the two nearest cationic subshells containing 1.6 +/- 0.4 Mg at 3.03 Å and 2.2 +/- 0.5 Si at 3.27 Å. These distances are respectively characteristic of edge-sharing linkages between Mg and Co octahedra and of corner-sharing linkages between Co octahedra and Si tetrahedra, as in clay structures. The angular dependence of the Co-Mg and Co-Si contributions indicates that Co-Mg pairs are oriented parallel to the film plane, whereas Co-Si pairs are not. These results are interpreted by the formation of Co inner-sphere mononuclear surface complexes located at the edges of hectorite platelets, in the continuity of the (Mg, Li) octahedral sheet. Copyright 1999 Academic Press.

  2. Taking iron supplements

    Science.gov (United States)

    ... medlineplus.gov/ency/article/007478.htm Taking iron supplements To use the sharing features on this page, ... levels. You may also need to take iron supplements as well to rebuild iron stores in your ...

  3. Context in place

    DEFF Research Database (Denmark)

    Nordentoft, Helle Merete; Thomsen, Rie

    specifically argue for a more grounded approach to the conception of context - a topographic approach - in which the physical setting - i.e. 'the place' becomes an inevitable part of analyses of guidance practices in order to understand participants' sense-making processes. In the paper we draw on two case...... studies on interdisciplinary clinical supervision and work place guidance in which there appears to be a mismatch between intended outcomes and actual events. The analyses demonstrate and support that 'the place' seems - to influence partipants' responses in the guidance sessions and, therefore, must...

  4. SORPTION OF Cu2+ IONS ONTO DIATOMITE CONSTITUENTS

    Directory of Open Access Journals (Sweden)

    Vasile Rusu

    2009-06-01

    Full Text Available Studies of the sorption capacity towards Cu2+ ions of diatomite from the Ghidirim location of RM, as well as of the extracted clay phase are presented. Separated clay fraction from diatomic material is clean enough, and especially is rich in montmorillonite. Maximum sorption capacity for studied clay fraction is achieved by rising the temperature of calcination treatment up to 200oC. At higher temperatures the lattice of montmorillonite is contracted and its sorption capacity towards Cu2+ ions decreases strongly.

  5. Modeling and Prediction of Soil Water Vapor Sorption Isotherms

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per

    2015-01-01

    Soil water vapor sorption isotherms describe the relationship between water activity (aw) and moisture content along adsorption and desorption paths. The isotherms are important for modeling numerous soil processes and are also used to estimate several soil (specific surface area, clay content.......93) for a wide range of soils; and (ii) develop and test regression models for estimating the isotherms from clay content. Preliminary results show reasonable fits of the majority of the investigated empirical and theoretical models to the measured data although some models were not capable to fit both sorption...... directions accurately. Evaluation of the developed prediction equations showed good estimation of the sorption/desorption isotherms for tested soils....

  6. Sorption and desorption of diuron in Oxisol under biochar application

    OpenAIRE

    Petter, Fabiano André; Ferreira, Tamara Santos; Sinhorin, Adilson Paulo; Lima, Larissa Borges de; Morais, Leidimar Alves de; Pacheco, Leandro Pereira

    2016-01-01

    ABSTRACT The objective of this study was to verify the kinetics of sorption and desorption of diuron in an Oxisol under application of biochar. The samples were collected in a field experiment conducted in randomized design blocks consisted of 2 base fertilization levels (0 and 400 kg∙ha−1 NPK 00-20-20 fertilizer formula) and 3 doses of biochar (0, 8 and 16 Mg∙ha−1). In the evaluation of sorption and desorption, Batch Equilibrium method was used. The kinetics of sorption and desorption of diu...

  7. Interim report on modeling sorption with EQ3/6

    International Nuclear Information System (INIS)

    Viani, B.

    1988-01-01

    Reversible, equilibrium models of sorption to be incorporated into the EQ3/6 geochemical modeling package are summarized. Empirical sorption models as formulated in linear, Langmuir, and Freundlich isotherms will be developed as options to EQ3/6. This work will be done at LLNL. Options for modeling sorption using surface- complexation constructs (diffuse, constant capacitance, and triple-layer models) will also be developed. Development of the surface-complexation options will require part of the work be done under contract. 27 refs., 1 fig

  8. Implementation of sorption hysteresis in multi-Fickian moisture transport

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Svensson, Staffan

    2007-01-01

    In the cellular structure of wood, bound-water diffusion and water-vapor diffusion interact via sorption in a complex moisture-transportation system. At low relative humidities, moisture transport may be modeled by a Fickian diffusion equation with a good approximation. At higher relative......-35% in moisture content. Hence, for a precise moisture content computation, sorption hysteresis must be taken into account. The present paper explains the relation between sorption hysteresis and multi-Fickian moisture transport, and clarifies how models for the two phenomena are coupled. To illustrate...

  9. Sorption of molybdenum by cellulose polyphosphate from acid solutions

    International Nuclear Information System (INIS)

    Luneva, N.K.; Oputina, A.G.; Ermolenko, I.N.

    1985-01-01

    The sorption of molybdenum on cellulose polyphosphate from acid solutions of ammonium molybdate depending on the phosphorus content in samples, concentration and pH of the solution, sorption time is studied. It is shown that a maximum molybdenum content on the cellulose samples with different phosphorus content is pointed out at an ammonium molybdate concentration 0.02 M. Saturation of the sorption curve is attained at molar ratio of adsrbed molybdenum to phosphorus 1:4. In case of small fillings the compound with molybdenum to phosphorus ratio 1:10 is formed

  10. Sorption of Co2+ on modified inorganic materials

    International Nuclear Information System (INIS)

    Hanzel, R.; Rajec, P.

    1999-01-01

    The aim of this study was preparation and characterization of sorbents on the base a silica-gel matrix with immobilized functional group (imidazole or crown-ether). Sorption of cobalt from aqueous solutions on prepared sorbents in static conditions (by 'batch' method) in the dependence of concentration, pH value,, as well as kinetics of sorption were studied. The influence of heavy or toxic metals [Hg(II), Cd(II), Mn(II), Zn(II), Cu(II), Fe(III), Cr(III), Al(III), Na and K] on sorption of cobalt was studied, too

  11. Arsenic Sorption on Mechanically Activated Magnetite and Olivine

    Directory of Open Access Journals (Sweden)

    Zdenka Bujňáková

    2012-12-01

    Full Text Available Arsenic sorption on mechanically activated minerals such as magnetite Fe3O4 (Kiruna, Sweden and olivine (Mg,Fe2SiO4 (Ǻheim,Norway has been studied and compared in this work. Experiments were carried out with non-activated and mechanically activatedsamples. The activation of both minerals was performed in a planetary mill at different milling conditions. The specific surface areaand consequent sorption activity were enhanced by mechanical activation. The using of olivine seems to be better than magnetite fromthe point of view of milling time, which is necessary for achievement of the same sorption effect.

  12. Sorption of trace cesium on 21 Hanford Site sediment types

    International Nuclear Information System (INIS)

    Routson, R.C.; Barney, G.S.; Smith, R.M.; Delegard, C.A.

    1980-03-01

    Sorption of trace cesium (Cs) was measured on 21 Hanford Site sediment types. A Box-Behnken statistical design was used to develop empirical-statistical equations predicting 137 Cs sorption as a function of the equilibrium concentrations of macroions Na + , K + , and Ca +2 in solution over the concentration ranges of 3.0 to 0.001M, 0.2 to 0.002M, and 0.2 to 0.002M, respectively. These equations are required to estimate trace Cs transport from Hanford ground disposal sites. Average Cs sorption equations for the 21 sediments will be presented and discussed

  13. Management and communication courses – Places available

    CERN Multimedia

    2013-01-01

    There are places available in some management and communication courses taking place in the period April to June 2013.   For more information on the course, click on the course title, this will bring you to the training catalogue. You can then sign-up online. For advice, you can contact: - Erwin Mosselmans, tel. 74125, erwin.mosselmans@cern.ch - Nathalie Dumeaux, tel. 78144, nathalie.dumeaux@cern.ch Courses in English (or bilingual) Sessions Duration Language Availability Managing stress 29 and 30 May 2 days English 3 places Making Presentations 30, 31 May & 25 June 3 days English 2 places Communicating Effectively - Residential course 4 to 6 June 3 days Bilingual 9 places Handling difficult conversations (Adapted from Dealing with Conflict) 7 and 14 June and 13 September 3 days English 6 places Voice and Nonverbal Behaviour in Speech Communication 17 and 18 June 1 day 4 hours English 7 plac...

  14. Integrated sorption and diffusion model for bentonite. Part 1. Clay-water interaction and sorption modeling in dispersed systems

    International Nuclear Information System (INIS)

    Tachi, Yukio; Suyama, Tadahiro; Ochs, Michael

    2014-01-01

    To predict the long-term migration of radionuclides (RNs) under variable conditions within the framework of safety analyses for geological disposal, thermodynamic sorption models are very powerful tools. The integrated sorption and diffusion (ISD) model for compacted bentonite was developed to achieve a consistent combination of clay–water interaction, sorption, and diffusion models. The basic premise considered in the ISD model was to consistently use the same simple surface model design and parameters for describing RNs sorption/diffusion as well as clay surface and porewater chemistry. A simple 1-site non-electrostatic surface complexation model in combination with a 1-site ion exchange model was selected to keep sorption model characteristics relatively robust for compacted systems. Fundamental parameters for the proposed model were evaluated from surface titration data for purified montmorillonite. The resulting basic model was then parameterized on the basis of selected published sorption data-sets for Np(V), Am(III), and U(VI) in dispersed systems, which cover a range of key geochemical conditions such as pH, ionic strength, and carbonate concentration. The sorption trends for these RNs can be quantitatively described by the model considering a full suite of surface species including hydrolytic and carbonate species. The application of these models to the description of diffusive-sorptive transport in compacted bentonites is presented in Part 2. (author)

  15. Development of a Self-Consistent Model of Plutonium Sorption: Quantification of Sorption Enthalpy and Ligand-Promoted Dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Brian [Clemson Univ., SC (United States); Kaplan, Daniel I [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Arai, Yuji [Univ. of Illinois, Urbana-Champaign, IL (United States); Becker, Udo [Univ. of Michigan, Ann Arbor, MI (United States); Ewing, Rod [Stanford Univ., CA (United States)

    2016-12-29

    This university lead SBR project is a collaboration lead by Dr. Brian Powell (Clemson University) with co-principal investigators Dan Kaplan (Savannah River National Laboratory), Yuji Arai (presently at the University of Illinois), Udo Becker (U of Michigan) and Rod Ewing (presently at Stanford University). Hypothesis: The underlying hypothesis of this work is that strong interactions of plutonium with mineral surfaces are due to formation of inner sphere complexes with a limited number of high-energy surface sites, which results in sorption hysteresis where Pu(IV) is the predominant sorbed oxidation state. The energetic favorability of the Pu(IV) surface complex is strongly influenced by positive sorption entropies, which are mechanistically driven by displacement of solvating water molecules from the actinide and mineral surface during sorption. Objectives: The overarching objective of this work is to examine Pu(IV) and Pu(V) sorption to pure metal (oxyhydr)oxide minerals and sediments using variable temperature batch sorption, X-ray absorption spectroscopy, electron microscopy, and quantum-mechanical and empirical-potential calculations. The data will be compiled into a self-consistent surface complexation model. The novelty of this effort lies largely in the manner the information from these measurements and calculations will be combined into a model that will be used to evaluate the thermodynamics of plutonium sorption reactions as well as predict sorption of plutonium to sediments from DOE sites using a component additivity approach.

  16. Environmental Conditions Influencing Sorption of Inorganic Anions to Multiwalled Carbon Nanotubes Studied by Column Chromatography.

    Science.gov (United States)

    Metzelder, Florian; Schmidt, Torsten C

    2017-05-02

    Sorption to carbon-based nanomaterials is typically studied in batch experiments. An alternative method offering advantages to study sorption is column chromatography. Sorbent packed columns are used and sorption data are determined by relating sorbate retention to that of a nonretarded tracer. We have now for the first time applied this technique to study the influence of environmental conditions on sorption of inorganic anions (bromide, nitrite, nitrate, and iodide) to multiwalled carbon nanotubes. Deuterium oxide was used as nonretarded tracer. Sorption isotherms were best described by the Freundlich model. Sorption increased in the order bromide 4.5 the surface charge was negative, but sorption was still detectable at pH 6 and 9. Consequently, other forces than electrostatic attraction contributed to sorption. These forces may include H-bonding as indicated by sorption enthalpy determined by variation of column temperature. Overall, column chromatography represents a promising alternative in sorption studies to reveal sorbent properties.

  17. Technical training - Places available

    CERN Document Server

    2012-01-01

    If you would like more information on a course, or for any other inquiry/suggestions, please contact Technical.Training@cern.ch Valeria Perez Reale, Learning Specialist, Technical Programme Coordinator (Tel.: 62424) Eva Stern and Elise Romero, Technical Training Administration (Tel.: 74924)   Electronics design Next Session Duration Language Availability Certified LabVIEW Associate Developer (CLAD) 06-Dec-12 to 06-Dec-12 1 hour English One more place available Compatibilité électromagnetique (CEM): Applications 23-Nov-12 to 23-Nov-12 3.5 hours English 3 places available Compatibilité électromagnétique (CEM): Introduction 23-Nov-12 to 23-Nov-12 3 hours English 43 places available Effets des Radiations sur les composants et systèmes électroniques 11-Dec-12 to 12-Dec-12 1 day 4 hours French 9 places available LabVIEW for beginners ...

  18. History, Criticism and Place

    DEFF Research Database (Denmark)

    Hinds, Mat; Carter, Adrian; Malpas, Jeff

    2012-01-01

    Rory Spence and Richard Leplastrier shared a conversation and friendship that lasted 20years until Spence's death in 2004. The discussions focused largely upon issues of place, distilled through the practice of Leplastrier....

  19. Marine Place Names

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This data set contains the geographic place names for features in the U.S territorial waters and outer continental shelf. These names can be used to find or define a...

  20. Self-Placing Concrete

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    Certain concrete pours have areas where the congestion of reinforcing bars make placement of concrete almost impossible. Using conventional placing and vibration techniques, the resulting concrete can have considerable honeycombing due to the development of voids. Self-placing concrete is a possible solution to the problem. Also known as self-compactable concrete, self-consolidating concrete, flowable concrete, and non-vibration concrete. These concretes eliminate the need for vibration in a ...

  1. 'A Place to Sit'

    DEFF Research Database (Denmark)

    Hvejsel, Marie Frier; Klok, Julie Skovgaard; Bøhnke, Mia Marker

    Published in 2014 on the occasion of the third 'A Place to Sit' exhibition as a reflection upon three years of teaching tectonic method in architecture using the furniture scale as a learning basis.......Published in 2014 on the occasion of the third 'A Place to Sit' exhibition as a reflection upon three years of teaching tectonic method in architecture using the furniture scale as a learning basis....

  2. Technical training - Places available

    CERN Multimedia

    2012-01-01

    If you would like more information on a course, or for any other inquiry/suggestions, please contact Technical.Training@cern.ch Valeria Perez Reale, Learning Specialist, Technical Programme Coordinator (Tel.: 62424) Eva Stern and Elise Romero, Technical Training Administration (Tel.: 74924) HR Department Electronic Design Next Session Duration Language Availability Comprehensive VHDL for FPGA Design 08-Oct-12 to 12-Oct-12 5 days English 4 places Electrostatique / Protection ESD 28-Sep-12 to 28-Sep-12 3 hours French 25 places Impacts de la suppression du plomb (RoHS) en électronique 26-Oct-12 to 26-Oct-12 8 hours French 14 places Introduction to VHDL 10-Oct-12 to 11-Oct-12 2 days English 9 places LabVIEW Real Time and FPGA 13-Nov-12 to 16-Nov-12 5 days French 5 places LabVIEW for Experts 24-Sep-12 to 28-Sep-12 5 days English 6 places LabVIEW for beginners 15-Oct-12 to 17-...

  3. Sorption of Sr, Co and Zn on illite: Batch experiments and modelling including Co in-diffusion measurements on compacted samples

    Science.gov (United States)

    Montoya, V.; Baeyens, B.; Glaus, M. A.; Kupcik, T.; Marques Fernandes, M.; Van Laer, L.; Bruggeman, C.; Maes, N.; Schäfer, T.

    2018-02-01

    Experimental investigations on the uptake of divalent cations (Sr, Co and Zn) onto illite (Illite du Puy, Le-Puy-en-Velay, France) were carried out by three different international research groups (Institute for Nuclear Waste Disposal, KIT (Germany), Group Waste & Disposal, SCK-CEN, (Belgium) and Laboratory for Waste Management, PSI (Switzerland)) in the framework of the European FP7 CatClay project. The dependence of solid-liquid distribution ratios (Rd values) on pH at trace metal conditions (sorption edges) and on the metal ion concentration (sorption isotherms) was determined in dilute suspensions of homo-ionic Na-illite (Na-IdP) under controlled N2 atmosphere. The experimental results were modelled using the 2 Site Protolysis Non Electrostatic Surface Complexation and Cation Exchange (2SPNE SC/CE) sorption model. The sorption of Sr depends strongly on ionic strength, while a rather weak pH dependence is observed in a pH range between 3 and 11. The data were modelled with cation exchange reactions, taking into account competition with H, K, Ca, Mg and Al, and surface complexation on weak amphotheric edge sites at higher pH values. The sorption of Co on Na-IdP, however, is strongly pH dependent. Cation exchange on the planar sites and surface complexation on strong and weak amphoteric edge sites were used to describe the Co sorption data. Rd values for Co derived from in-diffusion measurements on compacted Na-IdP samples (bulk-dry density of 1700 kg m-3) between pH 5.0 and 9.0 are in good agreement with the batch sorption data. The equivalence of both approaches to measure sorption was thus confirmed for the present test system. In addition, the results highlight the importance of both major and minor surface species for the diffusive transport behaviour of strongly sorbing metal cations. While surface complexes at the edge sites determine largely the Rd value, the diffusive flux may be governed by those species bound to the planar sites, even at low fractional

  4. Sorption of radioiodine in organo-clays and -soils

    International Nuclear Information System (INIS)

    Bors, J.

    1990-01-01

    In the framework of investigations on the sorption of radioiodine to natural and artificially altered soil components, a number of clay minerals and natural soils were treated with quaternary alkylammonium ions to replace the exchangeable metal cations. With help of batch experiments the resulting organo-clays were tested with respect to their sorption capability of radioiodine quantified by the distribution ratio (R D -value). Treatment of bentonite, vermiculite and cretaceous clay as well as of samples from natural horizons of chernozem soil with hexadecylpyridinium (HDPY + ) and benzethonium (BE + ) exhibited sorptions rates and amounts, which are several orders of magnitude higher than those of the respective untreated samples. Moderate increases of the R D -values were found after cation exchange with hexadecyltrimethylammonium (HDTMA + ), while the applications of trimethylphenylammonium (TMPA + ) and tetramethylammonium (TMA + ) were ineffective. Considerable sorption of radioiodine was observed with the commercially available Bentone. (orig.)

  5. Sorption of radioiodine in organo-clays and -soils

    Energy Technology Data Exchange (ETDEWEB)

    Bors, J. (Niedersaechsisches Inst. fuer Radiooekologie, Hannover (Germany, F.R.))

    1990-01-01

    In the framework of investigations on the sorption of radioiodine to natural and artificially altered soil components, a number of clay minerals and natural soils were treated with quaternary alkylammonium ions to replace the exchangeable metal cations. With help of batch experiments the resulting organo-clays were tested with respect to their sorption capability of radioiodine quantified by the distribution ratio (R{sub D}-value). Treatment of bentonite, vermiculite and cretaceous clay as well as of samples from natural horizons of chernozem soil with hexadecylpyridinium (HDPY{sup +}) and benzethonium (BE{sup +}) exhibited sorptions rates and amounts, which are several orders of magnitude higher than those of the respective untreated samples. Moderate increases of the R{sub D}-values were found after cation exchange with hexadecyltrimethylammonium (HDTMA{sup +}), while the applications of trimethylphenylammonium (TMPA{sup +}) and tetramethylammonium (TMA{sup +}) were ineffective. Considerable sorption of radioiodine was observed with the commercially available Bentone. (orig.).

  6. Transformation and sorption of illicit drug biomarkers in sewer biofilms

    DEFF Research Database (Denmark)

    Ramin, Pedram; Brock, Andreas Libonati; Causanilles Llanes, Ana

    2017-01-01

    , 16 drug biomarkers were selected, including the major human metabolites of mephedrone, methadone, cocaine, heroin, codeine and tetrahydrocannabinol (THC). Transformation and sorption of these substances were assessed in targeted batch experiments using laboratory-scale biofilm reactors operated under...

  7. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    Isothermal, kinetic and thermodynamic studies on basic dye sorption onto tartaric acid esterified wheat straw. ... African Journal of Biotechnology ... esterified wheat straw (EWS), was originally prepared by solid phase thermochemistry method.

  8. Isothermal, kinetic and thermodynamic studies on basic dye sorption ...

    African Journals Online (AJOL)

    PRECIOUS

    2009-12-15

    Dec 15, 2009 ... The isothermal data correlated with the Langmuir model better than the. Freundlich model. ... there were two intra-particle diffusion steps in the dye sorption processes. .... rated monolayer of sorbate molecule on the sorbent.

  9. Sorption and desorption of insecticides in Brazilian soils

    International Nuclear Information System (INIS)

    Luchini, L.C.; Lord, K.A.; Ruegg, E.F.

    1980-01-01

    The sorption from aqueous solution of ten Brazilian soil types of four organochlorine, two organophosphorus and one carbamate insecticide was determined in the laboratory using gas chromatographic and radiometric techniques. Measurements showed that soils richest in organic matter, sorbed all substances except aldrin more strongly than the other soils. DDT was the most and aldrin the least sorbed organochlorine pesticide, being dieldrin sorbed two to four times more strongly than aldrin. Sorption of lindane varied in different soils. The organophosphate insecticides malathion and parathion were strongly sorbed in the soils richest in organic matter and weakly sorbed in the poorest soils heing moderately sorbed by the other soils. Sorption of carbaryl by all soils is small. Lindane was desorbed from the soil richest in organic matter and the extent of desorption was dependent on the sorption time. (Author) [pt

  10. Sorption of 237Pu by the diatom Asterionella formosa

    International Nuclear Information System (INIS)

    Conway, H.L.; Wahlgren, M.A.; Peterson, N.; Nelson, D.M.

    1976-01-01

    Knowledge of the behavior of the man-made radionuclide plutonium within aquatic environments is of fundamental importance in assessing its potential hazards and ecological impact. The sorption of plutonium by phytoplankton and other algae is the dominant factor in the biological transport of plutonium in the aquatic environment, and it has been suggested that sorption by phytoplankton may be responsible for the seasonal loss of plutonium from the epilimnion of Lake Michigan. A unialgal diatom culture was spiked with 237 Pu tracer solution in an attempt to simulate the behavior of fallout plutonium observed in field studies. The results were encouraging in that the 237 Pu in the filtered lake water medium exhibited strongly anionic properties similar to fallout plutonium in Lake Michigan, with limited sorption on container walls. The purpose of the present study was to extend the investigations of the sorption of plutonium by phytoplankton in a controlled environment using continuous culture techniques

  11. Copper foliar sorption: study of cuticular uptake and penetration

    International Nuclear Information System (INIS)

    Chamel, Andre; Bougie, Bernadette

    1977-01-01

    Results show that copper is easily retained by enzymatically isolated cuticles from pear leaves discs. The sorption is very rapid during the first hour, then progressively slower with increasing time. Upper and lower cuticles exhibit the same sorption when immersed, but the sorption by the upper internal surface is greater than that by the external surface. Sorption depends on the dates of sampling of the leaves and vegetal species. The variation of the process with concentrations is hyperbolic. The retained copper may be partially exchanged: from 16 to 95% after 24 hours of exchange in a cupric solution, as the Cu concentration increases from 10 -6 to 10 -2 M. The penetration of copper through astomatous cuticular discs is extremely reduced if there is pure water in the receiver unit [fr

  12. Effects of sorption hysteresis on radionuclide releases from waste packages

    International Nuclear Information System (INIS)

    Barney, G.S.; Reed, D.T.

    1985-01-01

    A one-dimensional, numerical transport model was used to calculate radionuclide releases from waste packages emplaced in a nuclear waste repository in basalt. The model incorporates both sorption and desorption isotherm parameters measured previously for sorption of key radionuclides on the packing material component of the waste package. Sorption hysteresis as described by these isotherms lowered releases of some radionuclides by as much as two orders of magnitude. Radionuclides that have low molar inventories (relative to uranium), high solubility, and strongly sorbed, are most affected by sorption hysteresis. In these cases, almost the entire radionuclide inventory is sorbed on the packing material. The model can be used to help optimize the thickness of the packing material layer by comparing release rate versus packing material thickness curves with Nuclear Regulatory Commission (NRC) and Environmental Protection Agency (EPA) release limits

  13. Experimental Results and Model Calculations of a Hybrid Adsorption-Compression Heat Pump Based on a Roots Compressor and Silica Gel-Water Sorption

    Energy Technology Data Exchange (ETDEWEB)

    Van der Pal, M.; De Boer, R.; Wemmers, A.K.; Smeding, S.F.; Veldhuis, J.B.J.; Lycklama a Nijeholt, J.A.

    2013-10-15

    Thermally driven sorption systems can provide significant energy savings, especially in industrial applications. The driving temperature for operation of such systems limits the operating window and can be a barrier for market-introduction. By adding a compressor, the sorption cycle can be run using lower waste heat temperatures. ECN has recently started the development of such a hybrid heat pump. The final goal is to develop a hybrid heat pump for upgrading lower (<100C) temperature industrial waste heat to above pinch temperatures. The paper presents the first measurements and model calculations of a hybrid heat pump system using a water-silica gel system combined with a Roots type compressor. From the measurements can be seen that the effect of the compressor is dependent on where in the cycle it is placed. When placed between the evaporator and the sorption reactor, it has a considerable larger effect compared to the compressor placed between the sorption reactor and the condenser. The latter hardly improves the performance compared to purely heat-driven operation. This shows the importance of studying the interaction between all components of the system. The model, which shows reasonable correlation with the measurements, could proof to be a valuable tool to determine the optimal hybrid heat pump configuration.

  14. Understanding mechanisms to predict and optimize biochar for agrochemical sorption

    Science.gov (United States)

    Hall, Kathleen; Gámiz, Beatriz; Cox, Lucia; Spokas, Kurt; Koskinen, William

    2017-04-01

    The ability of biochars to bind various organic compounds has been widely studied due to the potential effects on pesticide fate in soil and interest in the adoption of biochar as a "low-cost" filter material. However, the sorptive behaviors of biochars are extremely variable and much of the reported data is limited to specific biochar-chemical interactions. The lack of knowledge regarding biochar sorption mechanisms limits our current ability to predict and optimize biochar's use. This work unveils mechanistic drivers of organic pesticide sorption on biochars through targeted alteration of biochar surface chemistry. Changes in the quantity and type of functional groups on biochars and other black carbon materials were achieved through treatments with H2O2, and CO2, and characterized using Fourier transform infrared spectroscopy and scanning electron microscope (SEM/EDX). The sorption capacities of these treated biochars were subsequently measured to evaluate the effects of different surface moieties on the binding of target herbicides cyhalofop acid ((R)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propionic acid) and clomazone (2-[(2-chlorophenyl)methyl]-4,4-dimethyl-1,2-oxazolidin-3-one). Sorption of both herbicides on the studied biochars increased following H2O2 activation; however, the influence of the H2O2 activation on sorption was more pronounced for cyhalofop acid (pKa = 3.9) than clomazone, which is non-ionizable. Increased cyhalofop acid sorption on H2O2 treated biochars can be attributed to the increase in oxygen containing functional groups as well as the decrease in biochar pH. In contrast, CO2 activation reduced the sorption of cyhalofop acid compared to untreated biochar. FTIR data suggest the reduced sorption on CO2 -treated biochar was due to the removal of surface carboxyl groups, further supporting the role of specific functionality in the sorption of ionizable herbicides. Results from this work offer insight into the mechanisms of sorption and

  15. Kinetics of the sorption of triterpene saponin by hypercrosslinked polystyrene

    Science.gov (United States)

    Mironenko, N. V.; Brezhneva, T. A.; Selemenev, V. F.

    2013-03-01

    The kinetics of sorption of triterpene saponin by the polymer sorbent NM-200 is considered. The influence of the surface activity of glycoside on the rate of formation and structure of the adsorption layer on the sorbent's surface is established. The rate-determining step of sorption is found to be diffusion into the sorbent grain. The value of the activation energy demonstrates the determining role of dispersion forces in the interaction between triterpene saponin and the polymer sorbent MN-200.

  16. Further developments of the RES3T sorption database

    International Nuclear Information System (INIS)

    Brendler, V.

    2002-01-01

    RES 3 T - the Rossendorf expert system for surface and sorption thermodynamics currently under development has been expanded towards the provision of comprehensive sorption data sets suitable for complex natural systems of rocks and soils. Also a statistical evaluation of the available SCM (surface complexation model) data is now implemented. Finally, a normalization of SCM parameters to a standard site density has been incorporated. (orig.)

  17. Sorption heat engines: simple inanimate negative entropy generators

    OpenAIRE

    Muller, Anthonie W. J.; Schulze-Makuch, Dirk

    2005-01-01

    The name 'sorption heat engines' is proposed for simple negative entropy generators that are driven by thermal cycling and work on alternating adsorption and desorption. These generators are in general not explicitly recognized as heat engines. Their mechanism is applicable to the fields of engineering, physics, chemistry, geology, and biology, in particular the origin of life. Four kinds of sorption heat engines are distinguished depending on the occurrence of changes in the adsorbent or ads...

  18. Sorption Properties of Steam Treated Wood and Plant Fibres

    DEFF Research Database (Denmark)

    Hoffmeyer, Preben; Jensen, Signe Kamp; Jones, Dennis

    2003-01-01

    temperatures the behaviour was different for low/medium RH and high RH. For low/medium range RH (.... This behaviour corresponds to the reduction of the number of primary sorption sites on e.g. hemicellulose. For high range RH (> ca. 85 %) two additional mechanisms may have been active. One is the capillary sorption in micropores created as a result of the thermal degradation of cell wall matter. A second...

  19. Sorption and pertechnetate by salts of molybdophosphoric acid

    International Nuclear Information System (INIS)

    Suess, M.; Pfrepper, G.

    1983-01-01

    The sorption of pertechnetate on salts of molybdophosphoric acid from nitric acid and in the presence of electrolytes was investigated. Distribution coefficients from 10 to 100 ml/g were found. The sorption of pertechnetate can be increased by the addition of K + , NH 4 + , Rb + and Cs + salts. A saturation capacity of proportional 0,19 mmol/g ammonium phosphomolybdate was found from the adsorption isotherms. The formation of alkali metal pertechnetate associates in the sorbent phase is supposed. (orig.)

  20. Methods for in-place testing of HEPA and iodine filters used in nuclear power plants

    International Nuclear Information System (INIS)

    Holmberg, R.; Laine, J.

    1978-04-01

    The purpose of this work was a general investigation of existing in-place test methods and to build an equipment for in-place testing of HEPA and iodine sorption filters. In this work the discussion is limited to methods used in in-place testing of HEPA and iodine sorption filters used in light-water-cooled reactor plants. Dealy systems, built for the separation of noble gases, and testing of them is not discussed in the work. Contaminants present in the air of a reactor containment can roughly be diveded into three groups: aerosols, reactive gases, and noble gases. The aerosols are filtered with HEPA (High Efficiency Particulate Air) filters. The most important reactive gases are molecular iodine and its two compounds: hydrogen iodide and methyl iodide. Of gases to be removed by the filters methyl iodide is the gas most difficult to remove especially at high relative humidities. Impregnated activated charcoal is generally used as sorption material in the iodine filters. Experience gained from the use of nuclear power plants proves that the function of high efficiency air filter systems can not be considered safe until this is proved by in-place tests. In-place tests in use are basically equal. A known test agent is injected upstream of the filter to be tested. The efficiency is calculated from air samples taken from both sides of the filter. (author)

  1. Sorption of strontium on bentonites from Slovak deposits

    International Nuclear Information System (INIS)

    Kufcakova, J.; Galambos, M.; Rajc, P.

    2005-01-01

    Sorption on bentonite from different Slovak deposits / Jelsovy potok, Kopernica and Lieskove has been investigated under various experimental conditions, such as contact time, pH, sorbate concentrations, presence of complementary cation. The sorption of strontium from aqueous solutions was investigated using a radiometric determination of distribution coefficient, Kd. The individual solutions were labelled with radiotracer. Radiation stability has been investigated, the higher sorption parameters were observed for the irradiated bentonites /tab.l/ , which can be explained by the increase of specific surface and change of solubility of the irradiated samples of bentonite. The presence of complementary cations, Na + , K + , NH 4 + , Ca 2+ , Mg 2+ and Ba 2+ depresses the sorption of Sr on bentonite. In the case of bentonite Kopernica the effectiveness in reducing the sorption of strontium by cations followed the order K + 4 + + 2+ 2+ 2+ . Results indicate that the sorption of Sr + on bentonite will be affected by the presence of high concentrations of various salts in the waste water effluents. (author)

  2. Moisture sorption isotherms and thermodynamic properties of bovine leather

    Science.gov (United States)

    Fakhfakh, Rihab; Mihoubi, Daoued; Kechaou, Nabil

    2018-04-01

    This study was aimed at the determination of bovine leather moisture sorption characteristics using a static gravimetric method at 30, 40, 50, 60 and 70 °C. The curves exhibit type II behaviour according to the BET classification. The sorption isotherms fitting by seven equations shows that GAB model is able to reproduce the equilibrium moisture content evolution with water activity for moisture range varying from 0.02 to 0.83 kg/kg d.b (0.9898 thermodynamic properties such as isosteric heat of sorption, sorption entropy, spreading pressure, net integral enthalpy and entropy. Net isosteric heat of sorption and differential entropy were evaluated through direct use of moisture isotherms by applying the Clausius-Clapeyron equation and used to investigate the enthalpy-entropy compensation theory. Both sorption enthalpy and entropy for desorption increase to a maximum with increasing moisture content, and then decrease sharply with rising moisture content. Adsorption enthalpy decreases with increasing moisture content. Whereas, adsorption entropy increases smoothly with increasing moisture content to a maximum of 6.29 J/K.mol. Spreading pressure increases with rising water activity. The net integral enthalpy seemed to decrease and then increase to become asymptotic. The net integral entropy decreased with moisture content increase.

  3. Investigation of rare earths sorption from sulfuric- and hydrochloric media

    International Nuclear Information System (INIS)

    Nikonov, V.N.; Mikhlin, E.B.; Norina, T.M.; Afonina, T.A.

    1978-01-01

    A rate of equilibrium attainment has been studied during REE sorption from sulfuric and hydrochloric acid solutions and pulps. It has been shown that equilibrium upon sorption from hydrochloric acid solutions is attained faster than from sulfuric acid solutions. Equilibrium upon sorption from pulps is attained considerably slower than upon sorption from solutions. In all cases REM of cerium subgroup are sorbed better. An effect has been studied of the medium acidity on sorbability of REM and elements of iron and calcium impurities. It has been established that sorbability of these elements decreases with increasing acid concentration. Selectivity of REM sorption from sulfuric acid solutions decreases with a rise in H 2 SO 4 concentration in the solution. For hydrochloric acid solutions it remains constant in a wide range of HCl concentrations. Sorption leaching of REM from concentrates and cakes of sulfuric and hydrochloric acids in the presence of KU-2 leads to high technical and economic indexes: extraction with respect to the total amount of REM and yttrium into a commercial product is 76-86% for sulfuric acid solutions and 81-90% for hydrochloric solutions

  4. Modelling of a diffusion-sorption experiment on sandstone

    International Nuclear Information System (INIS)

    Smith, P.A.

    1989-11-01

    The results of a diffusion-sorption experiment on a sample of Darley Dale sandstone, using simulated groundwater spiked with a mixture of 125 I, 85 Sr and 137 Cs, are modelled by a one-dimensional porous medium approach in which sorption is described by Freundlich isotherms. The governing equations are solved analytically for the special case of a linear isotherm, and numerically using the computer code RANCHDIFF for non-linear isotherms. A set of time-dependent, ordinary differential equations is obtained using the Lagrange interpolation technique and integrated by Gear's variable order predictor-corrector method. It is shown that the sorption behaviour of 85 Sr can be modelled successfully by a linear isotherm, using a sorption parameter consistent with batch-sorption tests. The behaviour of 137 Cs may be modelled by a non-linear isotherm, but the amount of 137 Cs sorbed is less than that anticipated from batch-sorption tests. 125 I is assumed to be non-sorbing and is used to determine the porosity of the sandstone. (author) 10 figs., 4 tabs., 6 refs

  5. The sorption of silver by poorly crystallized manganese oxides

    Science.gov (United States)

    Anderson, B.J.; Jenne, E.A.; Chao, T.T.

    1973-01-01

    The sorption of silver by poorly crystallized manganese oxides was studied using synthesized samples of three members of the manganous manganite (birnessite) group, of different chemical composition and crystallinity, and a poorly organized ??-MnO2. All four oxides sorbed significant quantities of silver. The manganous manganites showed the greatest sorption (up to 0.5 moles silver/mole MnOx at pH 7) while the ??-MnO2 showed the least (0.3 moles silver/ mole MnOx at pH 7). Sorption of silver was adequately described by the Langmuir equation over a considerable concentration range. The relationship failed at low pH values and high equilibrium silver concentrations. The sorption capacity showed a direct relationship with pH. However, the rate of increase of sorption capacity decreased at the higher pH values. Silver sorption maxima. were not directly related to surface area but appeared to vary with the amount of occluded sodium and potassium present in the manganese oxide. The important processes involved in the uptake of silver by the four poorly crystallized manganese oxides ara considered to be surface exchange for manganese, potassium and sodium as well as exchange for structural manganese, potassium and sodium. ?? 1973.

  6. Thermodynamic parameters and sorption of U(VI) on ACSD

    International Nuclear Information System (INIS)

    Donat, R.; Cilgi, G.K.; Cetisli, H.; Aytas, S.

    2009-01-01

    This paper discusses the sorption properties for U(VI) by alginate coated CaSO 4 x 2H 2 O sepiolite and calcined diatomite earth (Kieselguhr) (ACSD). The removal of U(VI) from aqueous solution by sorption onto ACSF in a single component system with various contact times, pH, temperatures, and initial concentrations of U(VI) was investigated. The sorption patterns of uranium on the composite adsorbent followed the Langmuir, Freundlich and Dubinin-Radushkhevic (D-R) isotherms. The Freundlich, Langmuir, and D-R models have been applied and the data correlated well with Freundlich model and that the sorption was physical in nature (sorption energy, E a = 17.05 kJ/mol). The thermodynamic parameters such as variation of enthalpy ΔH, variation of entropy ΔS and variation of Gibbs free energy ΔG were calculated from the slope and intercept of lnK 0 vs. 1/T plots. Thermodynamic parameters (ΔH ads = 31.83 kJ/mol, ΔS ads = 167 J/mol x K, ΔGdeg ads (293.15 K) = -17.94 kJ/mol) showed the endothermic heat of sorption and the feasibility of the process. The thermodynamics of U(VI) ion/ACSD system indicates the spontaneous and endothermic nature of the process. It was noted that an increase in temperature resulted in a higher uranium loading per unit weight of the adsorbent. (author)

  7. Compilation of radionuclide sorption coefficients for performance assessment

    Energy Technology Data Exchange (ETDEWEB)

    Carbol, P.; Engkvist, I. [PI Chemical Consulting HB, Landvetter (Sweden)

    1997-09-01

    The report presents four possible site-specific conditions in Sweden. The different sorption mechanisms applicable to the studied elements together with the K{sub d} concept are shortly summarised. The influence of organic substances present in the groundwater on the element`s sorption and mobility is also discussed. Criteria for selection of K{sub d} values are presented together with sensitivity of the values to pH, E{sub h} and salinity. Sorption coefficients are recommended for elements in the repository with half-life above 5.3 years. The elements reviewed are: Cs, Sr, Ra, Ln, Ac, Th, Pa, U, Np, Pu, Am, Cm, Co, Ni, Cd, Zr, Nb, Tc, Pd, Ag, Sn, C, I, Cl, Se and Kr. For every element there is a recommendation of a realistic K{sub d} value with an uncertainty limit. The selection is based on experimental investigations or chemical analogues. In some cases few or no K{sub d} data were found, and it is recommended that sorption studies be performed on elements such as Cd, Pa, Cm, Zr, Nb, Pd, Ag and Sn. The recommended K{sub d} values for the different element`s sorption on granitic rock, serve as a guidance of the sorption performance 87 refs, 18 tabs

  8. Compilation of radionuclide sorption coefficients for performance assessment

    International Nuclear Information System (INIS)

    Carbol, P.; Engkvist, I.

    1997-09-01

    The report presents four possible site-specific conditions in Sweden. The different sorption mechanisms applicable to the studied elements together with the K d concept are shortly summarised. The influence of organic substances present in the groundwater on the element's sorption and mobility is also discussed. Criteria for selection of K d values are presented together with sensitivity of the values to pH, E h and salinity. Sorption coefficients are recommended for elements in the repository with half-life above 5.3 years. The elements reviewed are: Cs, Sr, Ra, Ln, Ac, Th, Pa, U, Np, Pu, Am, Cm, Co, Ni, Cd, Zr, Nb, Tc, Pd, Ag, Sn, C, I, Cl, Se and Kr. For every element there is a recommendation of a realistic K d value with an uncertainty limit. The selection is based on experimental investigations or chemical analogues. In some cases few or no K d data were found, and it is recommended that sorption studies be performed on elements such as Cd, Pa, Cm, Zr, Nb, Pd, Ag and Sn. The recommended K d values for the different element's sorption on granitic rock, serve as a guidance of the sorption performance

  9. Experimental determination of sorption in fractured flow systems

    Science.gov (United States)

    Zimmerman, Mitchell D.; Bennett, Philip C.; Sharp, John M.; Choi, Wan-Joo

    2002-09-01

    Fracture "skins" are alteration zones on fracture surfaces created by a variety of biological, chemical, and physical processes. Skins increase surface area, where sorption occurs, compared to the unaltered rock matrix. This study examines the sorption of organic solutes on altered fracture surfaces in an experimental fracture-flow apparatus. Fracture skins containing abundant metal oxides, clays, and organic material from the Breathitt Formation (Kentucky, USA) were collected in a manner such that skin surface integrity was maintained. The samples were reassembled in the lab in a flow-through apparatus that simulated ˜2.7 m of a linear fracture "conduit." A dual-tracer injection scheme was utilized with the sorbing or reactive tracer compared to a non-reactive tracer (chloride) injected simultaneously. Sorption was assessed from the ratio of the first temporal moments of the breakthrough curves and from the loss of reactive tracer mass and evaluated as a function of flow velocity and solute type. The breakthrough curves suggest dual-flow regimes in the fracture with both sorbing and non-sorbing flow fields. Significant sorption occurs for the reactive components, and sorption increased with decreasing flow rate and decreasing compound solubility. Based on moment analysis, however, there was little retardation of the center of solute mass. These data suggest that non-equilibrium sorption processes dominate and that slow desorption and boundary layer diffusion cause extensive tailing in the breakthrough curves.

  10. Sorption Coefficients for Iodine, Silver, and Cesium on Dust Particles

    International Nuclear Information System (INIS)

    Stempniewicz, M.M.; Goede, P.

    2014-01-01

    This paper describes the work performed to find relevant experimental data and find the sorption coefficients that represent well the available data for cesium, iodine, and silver on dust particles. The purpose of this work is to generate a set of coefficients that may be recommended for the computer code users. The work was performed using the computer code SPECTRA. Calculations were performed for the following data: • I-131 on AVR dust; • Ag-110m on AVR dust; • Cs-13 and Cs-137 on AVR dust. Available data was matched using the SPECTRA Sorption Model. S = A(T) · C_V-B(T) · C_d. The results are summarized as follows: • The available data can be correlated. The data scatter is about 4 orders of magnitude. Therefore the coefficients of the Langmuir isotherms vary by 4 orders of magnitude. • Sorption rates are higher at low temperatures and lower at high temperatures. This tendency has been observed in the data compiled at Oak Ridge. It is therefore surmised that the highest value of the sorption coefficients are appropriate for the low temperatures and the lowest value of the sorption coefficients are appropriate for the high temperatures. The recommended sorption coefficients are presented in this paper. • The present set of coefficients is very rough and should be a subject for future verification against experimental data. (author)

  11. Correlational study between sorption and goo apparent organoclays

    International Nuclear Information System (INIS)

    Silva, D.L.; Silva, M.R.O.; Ferreira, H.S.; Brasileiro, C.T.

    2016-01-01

    The sorption of surfactants in bentonite clay can occur through the mechanism of adsorption and absorption, this being a very supple phenomenon according clay and surfactant utilized. Thus the more surfactant sorbed at the organoclay it becomes, and can be used in various applications, including in oil drilling fluid. This study aimed to correlate the sorption of surfactants with the rheological properties of non-aqueous fluids (oil base). In organophilization process was used Bentongel clay which had its concentration varied from 3.16 to 7.16% by weight of clay. It was used to organophilization an ionic surfactant Praepagem WB with 75% of active matter, where its concentration ranged from 127-181 mEq. After organophilizated the clays were filtered, dried in an oven for 48 hours and passed in ABNT sieve No. 200, to be so characterized. Sorption was calculated from mathematical equations. Non-aqueous fluids were prepared according to standard Petrobras (EP-1EP-00023A) for rheological testing. Correlating the sorption of surfactant, and the rheological properties of non-aqueous fluid, obtained satisfactory results where observed through the scatter plots there is a strong correlation between the variables sorption and apparent viscosity, it should also be noted that the viscosity is a variable which increases with an increase in sorption, confirming that the surfactant concentration influences the viscosity. (author)

  12. (Re)tasting places

    DEFF Research Database (Denmark)

    Hedegaard, Liselotte

    2015-01-01

    What does geographical origin mean? It is an expression that associates food and wine with a specific place, an association embedded in the concept ‘terroir’ that refers to the complex interaction between a physical environment and local craftsmanship. It is a claim protected through labelling......-schemes and a claim that adds value to the place-related foods. However, viewing the connection between food and place as a question of proving a relationship or as a matter of protecting commercial claims does not seem to provide a satisfactory account for the status of geographically designated foods as being...... particularly attractive Central to the interest of this paper is to approach an understanding of geographical origin as a point of reference for taste. In terms of being sensory experience, taste is subjective. It is difficult to describe verbally and yet at the same time it is a trigger of the memory of past...

  13. Stress at Work Place

    OpenAIRE

    Mohammad A. Shahrour

    2010-01-01

    One of hardest forms of stresses to avoid is that work place or job stress Job stress refers to stress experienced by an individual at or because of issues at their work place The term work related stress has many meanings and it causes different levels of anxiety. Not all challenges at work can be called stress as some of these challenges drive employees upward, and empower them to learn new skills or push them to work harder to achieve a certain goal. So, this type of challenges cannot be c...

  14. Ageing in communal place

    DEFF Research Database (Denmark)

    Aarhus, Rikke; Ballegaard, Stinne Aaløkke; Grönvall, Erik

    2009-01-01

    In this paper we adopt the position that design of social media for the elderly and virtual senior communities may be informed by studying `real´senior communities. Since current research efforts target the role of social media and virtual communities for supporting seniors ageing in place, i.......e. in their homes, housing communities seems a natural place to begin this enquiry. We conducted observations and informal interviews in six different senior dwellings. In this paper we present the key findings from these visits related to social interaction and the formation of communities and explicate how...

  15. Sorption and diffusion of FE(II) in bentonite

    International Nuclear Information System (INIS)

    Muurinen, A.; Tournassat, C.; Hadi, J.; Greneche, J.-M.

    2014-02-01

    The iron in the engineering barrier system of a nuclear waste repository interacts via the corrosion process with the swelling clay intended as the buffer material. This interaction may affect the sealing properties of the clay. In the case of iron-bentonite interaction, redox reactions, dissolution/precipitation, the diffusion and sorption are coupled together. In a combined study different processes are difficult to distinguish from each other, and more specific studies are needed for the separate processes. In particular, there is a need for well-controlled diffusion and sorption experiments where iron is kept as Fe(II). In this project, sorption and diffusion of Fe(II) in bentonite have been studied. The experiments were carried out under low-oxygen conditions in an anaerobic glove-box. The radioactive isotope ( 55 Fe) was used as a tracer in the experiments. The sorption experiments were carried out with two batches of purified MX-80 bentonite. One was purified at Bureau de Recherches Geologiques et Minieres, French Geological Survey (BRGM) and the other one at VTT Technical Research Centre of Finland (VTT). Experiments were also carried out with synthetic smectite, which did not include iron, which was prepared at LMPC (ENSC, F 68093 Mulhouse, France). The sorption experiments were carried out in 0.3 M and 0.05 M NaCl solutions as a function of pH, and in 0.3 M NaCl solution buffered at pH 5 as a function of added Fe(II) concentration. The separation of bentonite and solution at the end of the sorption experiment was carried out in the early phase by centrifuging only. In the later phase, ultrafiltering was added in order to improve the separation. The diffusion experiments were carried out in compacted samples prepared from MX-80 purified at VTT and saturated with 0.3 M NaCl at pH 8 and 5. A non-steady-state diffusion experiment method, where the tracer was introduced as an impulse source between two bentonite plugs was used in the measurements

  16. Sorption and diffusion of FE(II) in bentonite

    Energy Technology Data Exchange (ETDEWEB)

    Muurinen, A. [VTT Technical Research Centre of Finland, Espoo (Finland); Tournassat, C.; Hadi, J. [BRGM, Orleans (France); Greneche, J.-M. [LPCE, Le Mans (France)

    2014-02-15

    The iron in the engineering barrier system of a nuclear waste repository interacts via the corrosion process with the swelling clay intended as the buffer material. This interaction may affect the sealing properties of the clay. In the case of iron-bentonite interaction, redox reactions, dissolution/precipitation, the diffusion and sorption are coupled together. In a combined study different processes are difficult to distinguish from each other, and more specific studies are needed for the separate processes. In particular, there is a need for well-controlled diffusion and sorption experiments where iron is kept as Fe(II). In this project, sorption and diffusion of Fe(II) in bentonite have been studied. The experiments were carried out under low-oxygen conditions in an anaerobic glove-box. The radioactive isotope ({sup 55}Fe) was used as a tracer in the experiments. The sorption experiments were carried out with two batches of purified MX-80 bentonite. One was purified at Bureau de Recherches Geologiques et Minieres, French Geological Survey (BRGM) and the other one at VTT Technical Research Centre of Finland (VTT). Experiments were also carried out with synthetic smectite, which did not include iron, which was prepared at LMPC (ENSC, F 68093 Mulhouse, France). The sorption experiments were carried out in 0.3 M and 0.05 M NaCl solutions as a function of pH, and in 0.3 M NaCl solution buffered at pH 5 as a function of added Fe(II) concentration. The separation of bentonite and solution at the end of the sorption experiment was carried out in the early phase by centrifuging only. In the later phase, ultrafiltering was added in order to improve the separation. The diffusion experiments were carried out in compacted samples prepared from MX-80 purified at VTT and saturated with 0.3 M NaCl at pH 8 and 5. A non-steady-state diffusion experiment method, where the tracer was introduced as an impulse source between two bentonite plugs was used in the measurements

  17. Sorption of organic water pollutants on dead vegetable biomass; Sorption organischer Wasserschadstoffe an abgestorbene pflanzliche Biomasse

    Energy Technology Data Exchange (ETDEWEB)

    Kraeuter, A.

    2001-03-01

    Hemp-derived biological sorption agents were produced, and their physical, chemical and sorptive characteristics were tested in batch and filter tests. The experiments were accompanied by model calculations. In the natural state, the sorption agents had a kation exchange capacity of 0.1-0.3 mmol/g, modified sorption agents had about 2 mmol/g. Kationized hemp had values of 0.34 mmol/g and thermally modified hemp absorption agents absorbed more than 1.2 mmol/g of dichlorophenol. In the case of a liquid effluent from a textile dyeing plant, only a discoloration effect was achieved. The absorption agents can be regenerated, combusted or composted after use. [German] Im Rahmen dieser Arbeit wurden naturbelassene und modifizierte Billig-Biosorbentien aus Hanfschaeben zur Entfernung organischer Schadstoffe aus Waessern hergestellt und ihre physikalischen, chemischen und sorptiven Eigenschaften in Batch- und Filterversuchen untersucht. Wegen der Komplexheit des Systems ''Biosorption organischer Wasserschadstoffe'' wurden die ermittelten Sorptionsisothermen mit den Ansaetzen nach Langmuir und Freundlich beschrieben. Die Sorptionskinetik und das Durchbruchsverhalten wurde ebenfalls mit einfachen Ansaetzen modelliert. Naturbelassene Hanfschaeben erreichten Kationenaustauschkapazitaeten von 0,1-0,3 mmol/g, entsprechend modifizierte Hanfschaeben ca. 2 mmol/g. Kationisierte Hanfschaeben dagegen erreichten Anionenaustauschkapazitaeten von 0,34 mmol/g und thermisch modifizierte Hanfschaeben sorbierten bis ueber 1,2 mmol/g Dichlorphenol. Bei der Behandlung eines Abwassers aus einer Textilfaerberei beschraenkte sich die Reinigungsleistung der hergestellten Biosorbentien auf eine Entfaerbung. Nach Schadstoffbeladung koennen die Hanfschaeben regeneriert, thermisch verwertet oder kompostiert werden. (orig.)

  18. Understanding hydrogen sorption in a metal-organic framework with open-metal sites and amide functional groups

    KAUST Repository

    Pham, Tony T.

    2013-05-09

    Grand canonical Monte Carlo (GCMC) studies of the mechanism of hydrogen sorption in an rht-MOF known as Cu-TPBTM are presented. The MOF is a decorated/substituted isostructural analogue to the unembellished rht-MOF, PCN-61, that was studied previously [ Forrest, K. A.J. Phys. Chem. C 2012, 116, 15538-15549. ]. The simulations were performed using three different hydrogen potentials of increasing complexity. Simulated hydrogen sorption isotherms and calculated isosteric heat of adsorption, Qst, values were in excellent agreement with the reported experimental data for only a polarizable model in one of four experimentally observed crystal structure configurations. The study demonstrates the ability of modeling to distinguish the differential sorption of distinct strucures; one configuration is found to be dominant due to favorable interactions with substrates. In addition, it was discovered that the presence of polar amide groups had a significant effect on the electrostatics of the Cu2+ ions and directs the low-pressure physisorption of hydrogen in the MOF. This is in contrast to what was observed in PCN-61, where an exterior copper ion had a higher relative charge and was the favored loading site. This tunability of the electrostatics of the copper ions via chemical substitution on the MOF framework can be explained by the presence of the negatively charged oxygen atom of the amide group that causes the interior Cu2+ ion to exhibit a higher positive charge through an inductive effect. Further, control simulations, taking advantage of the flexibility afforded by theoretical modeling, include artificially modified charges for both Cu2+ ions chosen equal to or with a higher charge on the exterior Cu2+ ion. This choice resulted in distinctly different hydrogen sorption characteristics in Cu-TPBTM with no direct sorption on the open-metal sites. Thus, this study demonstrates both the tunable nature of MOF platforms and the possibility for rational design of sorption

  19. Technical training - Places available

    CERN Multimedia

    Davide Vitè

    2006-01-01

    Places available as of 16.5.2006 (May-November course sessions) Technical Training: Places available The number of places available may vary. Please check our Web site to find out the current availability. Places are available on the following courses: Title Hours Date Language ACROBAT 7.0 : Utilisation de fichiers PDF 8 8.05.06 F WORD 2003 - niveau 2 : ECDL 16 22-23.05.06 23-24.05.06 F Comprehensive VHDL for FPGA Design 40 29.05-2.06.06 E C++ Programming Part 2 - Advanced C++ and its Traps and Pitfalls 32 30.05-2.06.06 E ACROBAT 7.0 : Utilisation de fichiers PDF 24 7-9.06.06 E AutoCAD Mechanical 2006 16 13-14.06.06 F CERN EDMS for Local Administrators 16 13-14.06.06 E LabVIEW Base 2 32 27.06-5.07.06 F C++ Programming Part 3 - Templates and the STL (Standard Template Library) 16 27-28.06.06 E C++ Programming Part 4 - Exceptions 8 29.06.06 E FrontPage 2003 - niveau 1 16 29-...

  20. The Value of Place

    Science.gov (United States)

    Dentzau, Michael W.

    2014-01-01

    This commentary seeks to expand the dialogue on place-based science education presented in Katie Lynn Brkich's article, where the connections fifth grade students make between their formal earth science curriculum and their lived experiences are highlighted. The disconnect between the curriculum the students are offered and their immediate…

  1. The power of place.

    Science.gov (United States)

    Lock, Lin R; Gibb, Heather J

    2003-06-01

    to describe the power that 'place' holds over the postnatal-care experiences of women. a study informed by phenomenology within a feminist framework was undertaken to examine the experiences of women electing early postnatal discharge. Three extended conversations with each woman participating in the study were audiotaped and transcribed. Journal notes made by the researcher added to the audiotaped data. Thematic analysis revealed major structures of experience. data were obtained from conversations with women in their respective homes. five women, parity 1-3, living in the Sydney metropolitan area and birthing in their local hospitals participated in the study. four major constructs of experience were revealed through analysis and include spatiality, corporeality, temporality and relationality. In this paper, components of spatiality expressed through the power place exerts in matters of physical environment,control, confidence, safety, time, talk and the heart of the matter are presented. the experiences of women entering the foreign place of hospital to birth their children were those of alienation and disempowerment while the familiar territory of home offered stronger feelings of security and support. failing to recognise the impact of place on the experiences of postnatal women reduces the likelihood that midwives will be able to offer sensitive and appropriate care.

  2. Ageing in Communal Place

    DEFF Research Database (Denmark)

    Aarhus, Rikke; Ballegaard, Stinne Aaløkke; Grönvall, Erik

    2009-01-01

    In this paper we adopt the position that design of social media for the elderly and virtual senior communities may be informed by studying ‘real’ senior communities. Since current research efforts target the role of social media and virtual communities for supporting seniors ageing in place, i...

  3. Technical training - Places available

    CERN Multimedia

    2003-01-01

    * Etant donné le délai d'impression du Bulletin, ces places peuvent ne plus être disponibles au moment de sa parution. Veuillez consulter notre site Web pour avoir la dernière mise à jour. ** The number of places available may vary. Please check our Web site to find out the current availability. Des places sont disponibles dans les cours suivants : Places are available in the following courses: Hands-on Introduction to Python Programming 12 – 14.11.03 (3 days) ACCESS 2000 – niveau 1 13 & 14.11.03 (2 jours) C++ for Particle Physicists 17 – 21.11.03 (6 x 3-hour lectures) Programmation automate Schneider TSX Premium – niveau 2  18 – 21.11.03 (4 jours) Planification de projet avec MS-Project/Project Planning with MS-Project (gratuit/free of charge – langue à définir/language to be defined) : 18 & 25.11.03 (2 jours/2 days) JAVA 2 Enterprise Edition – Part 1 : WEB...

  4. Application of simplified desorption method to sorption study. (2) Sorption of neptunium (V) on montmorillonite-based mixtures

    International Nuclear Information System (INIS)

    Kozai, Naofumi; Ohnuki, Toshihiko

    2013-01-01

    To elucidate the sorption behaviors of radionuclides in multi-mineral systems and the mutual effects of minerals on the sorption, this paper carried out the sorption and desorption experiments of neptunium(V) on montmorillonite-based two-mineral mixtures. The Np sorbed on montmorillonite at pH from 4 to 8 was desorbed with 1M KCl solutions, indicating that the sorption was cation exchange. The Np sorbed on apatite and calcite was nondesorbable with 1M KCl solutions, which is in harmony with the knowledge that Np forms strong complexes with the phosphate groups of apatite and the carbonate groups of calcite. This study utilized these clear distinguishes of the desorption behaviors for examining the two-mineral systems. In montmorillonite-apatite mixtures, the sorption on the montmorillonite was decreased and Np was accumulated on the apatite. In montmorillonite-calcite mixtures, the sorption on the montmorillonite was decreased due to the interference by the calcium and carbonate ions dissolved from calcite while no accumulation of Np to calcite was observed. (author)

  5. Vertical barriers with increased sorption capacities

    International Nuclear Information System (INIS)

    Bradl, H.B.

    1997-01-01

    Vertical barriers are commonly used for the containment of contaminated areas. Due to the very small permeability of the barrier material which is usually in the order of magnitude of 10-10 m/s or less the advective contaminant transport can be more or less neglected. Nevertheless, there will always be a diffusive contaminant transport through the barrier which is caused by the concentration gradient. Investigations have been made to increase the sorption capacity of the barrier material by adding substances such as organoclays, zeolites, inorganic oxides and fly ashes. The contaminants taken into account where heavy metals (Pb) and for organic contaminants Toluole and Phenantrene. The paper presents results of model calculations and experiments. As a result, barrier materials can be designed 'tailor-made' depending on the individual contaminant range of each site (e.g. landfills, gasworks etc.). The parameters relevant for construction such as rheological properties, compressive strength and permeability are not affected by the addition of the sorbents

  6. Characterization of nanoporous shales with gas sorption

    Science.gov (United States)

    Joewondo, N.; Prasad, M.

    2017-12-01

    The understanding of the fluid flow in porous media requires the knowledge of the pore system involved. Fluid flow in fine grained shales falls under different regime than transport regime in conventional reservoir due to the different average pore sizes in the two materials; the average pore diameter of conventional sandstones is on the micrometer scale, while of shales can be as small as several nanometers. Mercury intrusion porosimetry is normally used to characterize the pores of conventional reservoir, however with increasingly small pores, the injection pressure required to imbibe the pores becomes infinitely large due to surface tension. Characterization of pores can be expressed by a pore size distribution (PSD) plot, which reflects distribution of pore volume or surface area with respect to pore size. For the case of nanoporous materials, the surface area, which serves as the interface between the rock matrix and fluid, becomes increasingly large and important. Physisorption of gas has been extensively studied as a method of nanoporous solid characterization (particularly for the application of catalysis, metal organic frameworks, etc). The PSD is obtained by matching the experimental result to the calculated theoretical result (using Density Functional Theory (DFT), a quantum mechanics based modelling method for molecular scale interactions). We present the challenges and experimental result of Nitrogen and CO2 gas sorption on shales with various mineralogy and the interpreted PSD obtained by DFT method. Our result shows significant surface area contributed by the nanopores of shales, hence the importance of surface area measurements for the characterization of shales.

  7. How to take statins

    Science.gov (United States)

    ... allergies. You are taking other medicines. You have diabetes. You have liver disease. You should not take statins if you ... with your provider about the possible risks for: Liver damage Severe ... High blood sugar, or type 2 diabetes Memory loss Confusion

  8. Note Taking and Recall

    Science.gov (United States)

    Fisher, Judith L.; Harris, Mary B.

    1974-01-01

    To study the effect of note taking and opportunity for review on subsequent recall, 88 college students were randomly assigned to five treatment groups utilizing different note taking and review combinations. No treatment effects were found, although quality of notes was positively correlated with free recall an multiple-choice measures.…

  9. Settings: In a Variety of Place. . .

    Science.gov (United States)

    Cairo, Peter; And Others

    This document consists of the fourth section of a book of readings on issues related to adult career development. The four chapters in this fourth section focus on settings in which adult career development counseling may take place. "Career Planning and Development in Organizations" (Peter Cairo) discusses several concepts and definitions…

  10. Sorption data bases for generic Swiss argillaceous rock systems

    International Nuclear Information System (INIS)

    Bradbury, M. H.; Baeyens, B.; Thoenen, T.

    2010-09-01

    In Switzerland the site selection procedure for both high level waste (HLW) and low and intermediate level waste (L/ILW) repositories is specified by the Swiss Federal Office of Energy in the Sectoral Plan for Deep Geological Repositories. In the forthcoming stage 2 of this plan, potential sites will be identified within regions previously selected based on the presence of suitable host rocks, namely Opalinus Clay, 'Brauner Dogger', Effingen Member and Helvetic Marl. Preliminary safety analyses are an integral part of this procedure, and require, amongst other information, the radionuclide sorption properties of the host rock. This report describes a methodology to develop a Generic Rock Sorption Data Base (GR-SDB) for argillaceous rocks. The method will be used to compile specific SDBs for the above mentioned host rocks. Arguments are presented that the main factor influencing sorption on argillaceous rocks is the phyllosilicate mineral content. These minerals are particularly effective at binding metals to their surfaces by cation exchange and surface complexation. Generally, the magnitude of sorption is directly correlated with the phyllosilicate content (2:1 type clays: illite/smectite/illitesmectite mixed layers), and this parameter best reflects the sorption potential of a given mineral assembly. Consequently, sorption measurements on illite were preferably used as source data for the GR-SDB. The second component influencing radionuclide sorption is the porewater chemistry. In the present report, generic water compositions were extracted from the analytical ranges of deep ground waters in various sedimentary formations in Switzerland. In order to cover the range of ionic strength (I) and pH values of Swiss ground waters in argillaceous rocks, five types of generic water compositions were defined, combining low, intermediate and high values of ionic strength and pH. The GR-SDB for in situ conditions was derived using conversion factors (CF). As the name

  11. Sorption mechanisms of chromate with coprecipitated ferrihydrite in aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Mamun, Abdullah Al, E-mail: mamun@toki.waseda.jp [Graduate School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Morita, Masao, E-mail: masao.swimer@akane.waseda.jp [Graduate School of Creative Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Matsuoka, Mitsuaki, E-mail: m-matsuoka@aoni.waseda.jp [Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan); Tokoro, Chiharu, E-mail: tokoro@waseda.jp [Faculty of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555 (Japan)

    2017-07-15

    Highlights: • Coprecipitation showed twice the sorption density of simple adsorption at pH 5. • Mechanism shift from outer- to inner-sphere surface complexation at high Cr/Fe. • In coprecipitation the mechanism shift occurs at lower Cr/Fe ratios than adsorption. • Higher-molar-ratio bidentate binuclear Cr−Fe bonds; yielded ferrihydrite expansion. - Abstract: Hexavalent chromium (Cr(VI)) attracted researchers’ interest for its toxicity, natural availability and removal difficulty. Nevertheless, its sorption mechanism is not clearly understood yet. In this work, we elucidated the sorption mechanism of the co-precipitation of chromates with ferrihydrite through quantitative analysis. The influence of Cr/Fe molar ratio on sorption was investigated by zeta potential measurements, X-ray diffraction (XRD) and X-ray adsorption fine-structure analysis (XAFS). Coprecipitation at pH 5 showed almost twice the sorption density of adsorption at pH 5. In co-precipitation, a shift of the XRD peak due to inner-sphere sorption of chromate was observed at Cr/Fe molar ratio 0.5. For adsorption, the same peak shift was confirmed at Cr/Fe molar ratio of 1. Zeta potential at pH 5 suggested that the sorption mechanism changed at Cr/Fe molar ratio 0.25 for coprecipitation and at Cr/Fe molar ratio of 1 for adsorption. Fitting of Cr and Fe K-edge extended X-ray adsorption fine-structure suggested that ferrihydrite immobilized Cr(VI) via outer sphere surface complexation for lower Cr/Fe ratios and via inner-sphere surface complexation for higher molar ratios. At higher molar ratios, bidentate binuclear Cr−Fe bonds were well established, thus resulting in the expansion of the ferrihydrite structure.

  12. Sorption of radionuclides from spent fuel in crystalline rocks

    International Nuclear Information System (INIS)

    Nikula, A.

    1982-10-01

    The safe disposal of spent nuclear fuel or reprocessed waste is an essential element in the expansion of the nuclear power industry. Stable rock formations e.g. granite are considered to be potential sites for disposal. A major factor in evaluating the degree of safety of the disposal is the sorption of radionuclides in rock, which affects their retardation. The report considers the chemical forms of the hazardous radionuclides of spent nuclear fuel in groundwater and the effects of the water's properties on them. In the groundwater near the Olkiluoto power plant site cesium, strontium and radium are in cationic form, iodine as I - . Technetium would occur as TcO +2 , but the pertechnetate form is also possible. Uranium most probably would be as U(VI) plutonium and neptunium as Np(IV) or Np(V). The valences for thorium, americium and curium are not changed in this groundwater and would be +4, +3 and +3, respectively. The actinides in groundwater are all in hydrated or complex form. An increase on the ionic stregth of the groundwater in most instances causes a decrease in the sorption of nuclides since the ion exchange capacity of the rock is limited. Anionic ligands also decrease sorption of cations by complex formation. In some case, on the other hand, high salt concentrations may cause formation of radiocolloids of lanthanides and neptunium and thus increase sorption. In all cases the degree of sorption described by the distribution ratio Ksub(d) was influenced by the pH of the groundwater. Sorption of cesium and strontium increased with growing pH. The sorption behaviour of actinides was in positive correlation with formation of hydroxide complexes at different pH values. The Ksub(d) values of Cs, Sr, Co, Ni and Am for Olkiluoto granites were found to agree with Swedish values, also determined at ambient atmospheric conditions

  13. Comparing uranyl sorption complexes on soil and reference clays

    International Nuclear Information System (INIS)

    Chisholm-Brause, C.J.; Berg, J.M.; Conradson, S.D.; Morris, D.E.; McKinley, J.P.; Zachara, J.M.

    1993-01-01

    Clay minerals and other components in natural soils may play a key role in limiting the mobility of uranium in the environment through the formation of sorption complexes. Reference clays are frequently used as models to study sorption processes because they have well-known chemical and physical properties, but they may differ chemically and morphologically from clays derived from natural soils. Therefore, inferences based on reference clay data have been questioned. The authors have used luminescence and x-ray absorption spectroscopies to characterize the sorption complexes of aqueous uranyl (UO 2 2+ ) species on two soil smectites from the Kenoma and Ringold formations, and compared these results to those obtained on reference smectite clays. The pH dependence of uptake suggests that the ratio of sorption on amphoteric edge sites is greater for the soil smectites than for reference clays such as Wyoming montmorillonite (SWy-1). The luminescence spectra for uranyl sorbed to the soil clays are very similar to those for uranyl sorbed principally to the edge sites of SWy-1. This observation supports the solution data suggesting that adsorption to amphoteric sites is a more important mechanism for soil clays. However, the spectral data indicate that the sorption complexes on natural and reference clays are quite similar. Furthermore, as with the reference clays, the authors have found that the chemistry of the solution plays a greater role in defining the sorption complex than does the clay matrix. Thus, if differences in surface properties are adequately taken into account, the reference clays may serve as useful analogs for soil clays in investigations of metal-ion sorption

  14. Natural minerals and synthetic materials for sorption of radioactive anions

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Mun Ja; Chun, Kwan Sik; Kim, Seung Soo

    1998-07-01

    Technetium-99 and iodine-129 are fission products with long half-lives, and exist as highly soluble anionic species. Studies on natural and synthetic materials sorbing TcO{sub 4} and/or I have been performed by several researchers. The application of these materials as an additive in the high-level waste disposal has been considered. The iron- or sulfide-containing minerals such as metal iron, iron powder, stibnite and pyrrhotite show a high capacity for TcO{sub 4} sorption. And the small amounts of activated carbon are reported to have high distribution coefficients recently. In the iodine sorption studies, sulfide-, copper-, lead- or mercury-containing minerals can be a candidate. Pyrite, chalcopyrite, galena, Cu{sub 2}S and CuS reveal a high capacity for I sorption. The synthetic materials were found to have high sorption capacity and compensate the defects of natural minerals, which contain hydrous oxides such as zirconium oxide, aluminium oxide and mercarbide. The mercarbide has the high distribution coefficients for the sorption of TcO{sub 4} and I. Recently it was proposed that the synthetic clay, hydrotalcite, could be useful for the fixation of anion. However, to determine the applicability of those natural and synthetic materials as an additive to a buffer or backfill material for sorption of TcO{sub 4} and/or I, the sorption behavior of the anions on those materials under the repository conditions should be identified. (author). 32 refs., 21 tabs., 10 figs

  15. Sericitization of illite decreases sorption capabilities for cesium

    Science.gov (United States)

    Choung, S.; Hwang, J.; Han, W.; Shin, W.

    2017-12-01

    Release of radioactive cesium (137Cs) to environment occurs through nuclear accidents such as Chernobyl and Fukushima. The concern is that 137Cs has long half-life (t1/2 = 30.2 years) with chemical toxicity and γ-radiation. Sorption techniques are mainly applied to remove 137Cs from aquatic environment. In particular, it has been known well that clay minerals (e.g, illite) are effective and economical sorbents for 137Cs. Illite that was formed by hydrothermal alteration exist with sericite through "sericitization" processes. Although sericite has analogous composition and lattice structure with illite, the sorptive characteristics of illite and sericite for radiocesium could be different. This study evaluated the effects of hydrothermal alteration and weathering process on illite cesium sorption properties. Natural illite samples were collected at Yeongdong area in Korea as the world-largest hydrothermal deposits for illite. The samples were analyzed by XRF, XRD and SEM-EDX to determine mineralogy, chemical compositions and morphological characteristics, and used for batch sorption experiments. The Yeongdong illites predominantly consist of illite, sericite, quartz, and albite. The measured cesium sorption distribution coefficients (Kd,Cs) of reference illite and sericite were approximately 6000 and 400 L kg-1 at low aqueous concentration (Cw 10-7 M), respectively. In contrast, Kd,Cs values for the Yeongdong illite samples ranged from 500 to 4000 L kg-1 at identical concentration. The observed narrow and sharp XRD peak of sericite indicated that the sericite has better crystallinity compared to illite. These experimental results suggested that sericitization processes of illite can decline the sorption capabilities of illite for cesium under various hydrothermal conditions. In particular, weathering experiments raised the cesium sorption to illite, which seems to be related to the increase of preferential sorption sites for cesium through crystallinity destruction

  16. Experiencing the enchantment of place and mobility

    DEFF Research Database (Denmark)

    Bærenholdt, Jørgen Ole

    2016-01-01

    in several layers of reality. To better understand experiences taking place in intersections between realities, J.R.R. Tolkien’s concept of how real enchantment produces a Secondary World suggests that we see fantasy as real, and this proposition is compared to Georg Simmel’s more modernist suggestion......Experiences of place and mobility play central roles not only in what was traditionally understood as tourism, but also in the broader practices of travelling and visiting sites and sights. On the one hand, such experiences are performed to an extent where it is difficult to isolate the sites...... and movements experienced per se, since visitors and travellers take part in ‘doing’ places and mobility. On the other, experience sites and routes stand out with specific traces and characteristics affording some – and not other – experiences. This paper discusses conceptual understandings that may help...

  17. Parks, People and Places

    DEFF Research Database (Denmark)

    Molin, Julie Frøik

    This thesis suggests, by applying a ‘place’ perspective, that involving users in operational management of green spaces holds potentials for enhancing ‘place attachment’ of urban inhabitants. As this can also build their commitment to decision making on their local living environment, green space...... maintenance becomes a potentially important setting for governance processes. Through a number of qualitative case studies, based on semi-structured interviews with municipal and community actors in Denmark and England, this dissertation explores the status and potentials of applying a place-based governance...... approach to green space maintenance. To guide the exploration a theoretical framework was developed inductively, structured around concepts of environmental governance in combination with strategic approaches to green space management. The framework is operationalised by analyses of the governance...

  18. Technical Training: Places available

    CERN Multimedia

    Monique Duval

    2004-01-01

    If you wish to participate in one of the following courses, please discuss with your supervisor and apply electronically directly from the course description pages that can be found on the Web at: http://www.cern.ch/Training/ or fill in an 'application for training' form available from your Divisional Secretariat or from your DTO (Divisional Training Officer). Applications will be accepted in the order of their receipt. The number of places available may vary. Please check our Web site to find out the current availability. Places are available in the following courses: The Joint PVSS JCOP Framework: 14 - 18.6.2004 (5 days) EXCEL 2003 - niveau 2 : 17 & 18.6.2004 (2 jours) MAGNE-04 : Magnétisme pour l'électrotechnique : 6 au 8.7.2004 (3 jours) Technical Training Monique Duval - Tel.74924 technical.training@cern.ch

  19. Sorption of microamount of colloidal silver iodide on hydrated iron(III) oxide

    International Nuclear Information System (INIS)

    Kepak, F.; Nova, J.

    1975-01-01

    Sorption of a microamount of colloidal silver iodide labelled with 131 I on hydrated iron/III/ oxide suspension was studied. The sorption dependence upon pH, sorbent amount, and inert electrolyte concentration has revealed that sorption of silver iodide reaches no more than 63%. The sorption lasted one hour during which the maximum value was reached. Desorption time was one hour, as well. Except for measuring the sorption dependence on pH, the sorption pH was 7.0, temperature 24+-2 0 C. (F.G.)

  20. Sorption data bases for argillaceous rocks and bentonite for the provisional safety analyses for SGT-E2

    International Nuclear Information System (INIS)

    Baeyens, B.; Thoenen, T.; Bradbury, M. H.; Marques Fernandes, M.

    2014-11-01

    In Stage 1 of the Sectoral Plan for Deep Geological Repositories, four rock types have been identified as being suitable host rocks for a radioactive waste repository, namely, Opalinus Clay for a high-level (HLW) and a low- and intermediate-level (L/ILW) repository, and 'Brauner Dogger', Effingen Member and Helvetic Marls for a L/ILW repository. Sorption data bases (SDBs) for all of these host rocks are required for the provisional safety analyses, including all of the bounding porewater and mineralogical composition combinations. In addition, SDBs are needed for the rock formations lying below Opalinus Clay (lower confining units) and for the bentonite backfill in the HLW repository. In some previous work Bradbury et al. (2010) have described a methodology for developing sorption data bases for argillaceous rocks and compacted bentonite. The main factors influencing the sorption in such systems are the phyllosilicate mineral content, particular the 2:1 clay mineral content (illite/smectite/illite-smectite mixed layers) and the water chemistry which determines the radionuclide species in the aqueous phase. The source sorption data were taken predominantly from measurements on illite (or montmorillonite in the case of bentonite) and converted to the defined conditions in each system considered using a series of so called conversion factors to take into account differences in mineralogy, in pH and in radionuclide speciation. Finally, a Lab → Field conversion factor was applied to adapt sorption data measured in dispersed systems (batch experiments) to intact rock under in-situ conditions. This methodology to develop sorption data bases has been applied to the selected host rocks, lower confining units and compacted bentonite taking into account the mineralogical and porewater composition ranges defined. Confidence in the validity and correctness of this methodology has been built up through additional studies: (i) sorption values obtained in the manner