WorldWideScience

Sample records for sorption conceptual models

  1. GEOQUIMICO : an interactive tool for comparing sorption conceptual models (surface complexation modeling versus K[D])

    International Nuclear Information System (INIS)

    Hammond, Glenn E.; Cygan, Randall Timothy

    2007-01-01

    Within reactive geochemical transport, several conceptual models exist for simulating sorption processes in the subsurface. Historically, the K D approach has been the method of choice due to ease of implementation within a reactive transport model and straightforward comparison with experimental data. However, for modeling complex sorption phenomenon (e.g. sorption of radionuclides onto mineral surfaces), this approach does not systematically account for variations in location, time, or chemical conditions, and more sophisticated methods such as a surface complexation model (SCM) must be utilized. It is critical to determine which conceptual model to use; that is, when the material variation becomes important to regulatory decisions. The geochemical transport tool GEOQUIMICO has been developed to assist in this decision-making process. GEOQUIMICO provides a user-friendly framework for comparing the accuracy and performance of sorption conceptual models. The model currently supports the K D and SCM conceptual models. The code is written in the object-oriented Java programming language to facilitate model development and improve code portability. The basic theory underlying geochemical transport and the sorption conceptual models noted above is presented in this report. Explanations are provided of how these physicochemical processes are instrumented in GEOQUIMICO and a brief verification study comparing GEOQUIMICO results to data found in the literature is given

  2. Recent progress in sorption mechanisms and models

    International Nuclear Information System (INIS)

    Fedoroff, M.; Lefevre, G.

    2005-01-01

    Full text of publication follows: Sorption-desorption phenomena play an important role in the migration of radioactive species in surface and underground waters. In order to predict the transport of these species, we need a good knowledge of sorption processes and data, together with reliable models able to be included in transport calculation. Traditional approaches based on experimentally determined distribution coefficients (Kd) and sorption isotherms have a limited predictive capability, since they are very sensitive to the numerous parameters characterizing the solution and the solid. Models based on thermodynamic equilibria were developed to account for the influence these parameters: the ion exchange model and the surface complexation models (2-pK mono-site, 1-pK multi-site, with several different electrostatic models: CCM, DLM, BSM, TLM,...). Although these models are very useful, studies performed in recent years showed that they have important theoretical and experimental limitations, which result in the fact that we must be very careful when we use them for extrapolating sorption data to long term and to large natural systems. Among all problems which can be found are: the possibility to fit a set of experimental data with different models, sometimes bad adequacy with the real sorption processes, some theoretical limitations such as a rigorous definition of reference and standard states in surface equilibria, slow kinetics which prevent from equilibrium achievement, irreversibility, solubility and evolution of solid phases... Through the increase of the number of sensitive spectroscopic methods, we are now able to know more about sorption processes at the atomic scale. Models such as the 1-pK CD-MUSIC model can account for the influence of orientation of the faces of the solid. More and more examples of the influence of this orientation on the sorption properties are known. Calculations performed by 'ab initio' modeling is also useful to predict the

  3. Modeling Fission Product Sorption in Graphite Structures

    International Nuclear Information System (INIS)

    Szlufarska, Izabela; Morgan, Dane; Allen, Todd

    2013-01-01

    The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high-temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission products

  4. Modeling Fission Product Sorption in Graphite Structures

    Energy Technology Data Exchange (ETDEWEB)

    Szlufarska, Izabela [University of Wisconsin, Madison, WI (United States); Morgan, Dane [University of Wisconsin, Madison, WI (United States); Allen, Todd [University of Wisconsin, Madison, WI (United States)

    2013-04-08

    The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high- temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission

  5. A Sorption Hysteresis Model For Cellulosic Materials

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Damkilde, Lars

    2006-01-01

    The equilibrium concentration of adsorbed water in cellulosic materials is dependent on the history of the variations of vapor pressure in the ambient air, i.e. sorption hysteresis. Existing models to describe this phenomenon such as the independent domain theory have numerical drawbacks and/or i...

  6. Model Building for Conceptual Change

    Science.gov (United States)

    Jonassen, David; Strobel, Johannes; Gottdenker, Joshua

    2005-01-01

    Conceptual change is a popular, contemporary conception of meaningful learning. Conceptual change describes changes in conceptual frameworks (mental models or personal theories) that learners construct to comprehend phenomena. Different theories of conceptual change describe the reorganization of conceptual frameworks that results from different…

  7. Conceptual IT model

    Science.gov (United States)

    Arnaoudova, Kristina; Stanchev, Peter

    2015-11-01

    The business processes are the key asset for every organization. The design of the business process models is the foremost concern and target among an organization's functions. Business processes and their proper management are intensely dependent on the performance of software applications and technology solutions. The paper is attempt for definition of new Conceptual model of IT service provider, it could be examined as IT focused Enterprise model, part of Enterprise Architecture (EA) school.

  8. Development of mechanistic sorption model and treatment of uncertainties for Ni sorption on montmorillonite/bentonite

    International Nuclear Information System (INIS)

    Ochs, Michael; Ganter, Charlotte; Tachi, Yukio; Suyama, Tadahiro; Yui, Mikazu

    2011-02-01

    Sorption and diffusion of radionuclides in buffer materials (bentonite) are the key processes in the safe geological disposal of radioactive waste, because migration of radionuclides in this barrier is expected to be diffusion-controlled and retarded by sorption processes. It is therefore necessary to understand the detailed/coupled processes of sorption and diffusion in compacted bentonite and develop mechanistic /predictive models, so that reliable parameters can be set under a variety of geochemical conditions relevant to performance assessment (PA). For this purpose, JAEA has developed the integrated sorption and diffusion (ISD) model/database in montmorillonite/bentonite systems. The main goal of the mechanistic model/database development is to provide a tool for a consistent explanation, prediction, and uncertainty assessment of K d as well as diffusion parameters needed for the quantification of radionuclide transport. The present report focuses on developing the thermodynamic sorption model (TSM) and on the quantification and handling of model uncertainties in applications, based on illustrating by example of Ni sorption on montmorillonite/bentonite. This includes 1) a summary of the present state of the art of thermodynamic sorption modeling, 2) a discussion of the selection of surface species and model design appropriate for the present purpose, 3) possible sources and representations of TSM uncertainties, and 4) details of modeling, testing and uncertainty evaluation for Ni sorption. Two fundamentally different approaches are presented and compared for representing TSM uncertainties: 1) TSM parameter uncertainties calculated by FITEQL optimization routines and some statistical procedure, 2) overall error estimated by direct comparison of modeled and experimental K d values. The overall error in K d is viewed as the best representation of model uncertainty in ISD model/database development. (author)

  9. Sorption of fission nuclides on model milk components. II. Sorption of radiostrontium on hydroxyapatite in milk and whey

    International Nuclear Information System (INIS)

    Rosskopfova, O.; Kopunec, R.; Matel, L.; Macasek, F.

    1999-01-01

    In this work the whey was chosen as a model solution of liquid phase for sorption study of strontium on hydroxyapatite. The whey was obtained using two methods - ultracentrifugation and precipitation of casein. The sorption was studied at a different pH and at a different concentration of calcium. The sorption of strontium on hydroxyapatite from milk was studied, too. (authors)

  10. Interim report on modeling sorption with EQ3/6

    International Nuclear Information System (INIS)

    Viani, B.

    1988-01-01

    Reversible, equilibrium models of sorption to be incorporated into the EQ3/6 geochemical modeling package are summarized. Empirical sorption models as formulated in linear, Langmuir, and Freundlich isotherms will be developed as options to EQ3/6. This work will be done at LLNL. Options for modeling sorption using surface- complexation constructs (diffuse, constant capacitance, and triple-layer models) will also be developed. Development of the surface-complexation options will require part of the work be done under contract. 27 refs., 1 fig

  11. Mathematical Modeling of Moisture Sorption Isotherms and Determination of Isosteric Heats of Sorption of Ziziphus Leaves

    Directory of Open Access Journals (Sweden)

    Amel Saad

    2014-01-01

    Full Text Available Desorption and adsorption equilibrium moisture isotherms of Ziziphus spina-christi leaves were determined using the gravimetric-static method at 30, 40, and 50°C for water activity (aw ranging from 0.057 to 0.898. At a given aw, the results show that the moisture content decreases with increasing temperature. A hysteresis effect was observed. The experimental data of sorption were fitted by eight models (GAB, BET, Henderson-Thompson, modified-Chung Pfost, Halsey, Oswin, Peleg, and Adam and Shove. After evaluating the models according to several criteria, the Peleg and Oswin models were found to be the most suitable for describing the sorption curves. The net isosteric heats of desorption and adsorption of Ziziphus spina-christi leaves were calculated by applying the Clausius-Clapeyron equation to the sorption isotherms and an expression for predicting these thermodynamic properties was given.

  12. Modeling and Prediction of Soil Water Vapor Sorption Isotherms

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per

    2015-01-01

    Soil water vapor sorption isotherms describe the relationship between water activity (aw) and moisture content along adsorption and desorption paths. The isotherms are important for modeling numerous soil processes and are also used to estimate several soil (specific surface area, clay content.......93) for a wide range of soils; and (ii) develop and test regression models for estimating the isotherms from clay content. Preliminary results show reasonable fits of the majority of the investigated empirical and theoretical models to the measured data although some models were not capable to fit both sorption...... directions accurately. Evaluation of the developed prediction equations showed good estimation of the sorption/desorption isotherms for tested soils....

  13. Surface complexation modeling of americium sorption onto volcanic tuff.

    Science.gov (United States)

    Ding, M; Kelkar, S; Meijer, A

    2014-10-01

    Results of a surface complexation model (SCM) for americium sorption on volcanic rocks (devitrified and zeolitic tuff) are presented. The model was developed using PHREEQC and based on laboratory data for americium sorption on quartz. Available data for sorption of americium on quartz as a function of pH in dilute groundwater can be modeled with two surface reactions involving an americium sulfate and an americium carbonate complex. It was assumed in applying the model to volcanic rocks from Yucca Mountain, that the surface properties of volcanic rocks can be represented by a quartz surface. Using groundwaters compositionally representative of Yucca Mountain, americium sorption distribution coefficient (Kd, L/Kg) values were calculated as function of pH. These Kd values are close to the experimentally determined Kd values for americium sorption on volcanic rocks, decreasing with increasing pH in the pH range from 7 to 9. The surface complexation constants, derived in this study, allow prediction of sorption of americium in a natural complex system, taking into account the inherent uncertainty associated with geochemical conditions that occur along transport pathways. Published by Elsevier Ltd.

  14. Modelling of a diffusion-sorption experiment on sandstone

    International Nuclear Information System (INIS)

    Smith, P.A.

    1989-11-01

    The results of a diffusion-sorption experiment on a sample of Darley Dale sandstone, using simulated groundwater spiked with a mixture of 125 I, 85 Sr and 137 Cs, are modelled by a one-dimensional porous medium approach in which sorption is described by Freundlich isotherms. The governing equations are solved analytically for the special case of a linear isotherm, and numerically using the computer code RANCHDIFF for non-linear isotherms. A set of time-dependent, ordinary differential equations is obtained using the Lagrange interpolation technique and integrated by Gear's variable order predictor-corrector method. It is shown that the sorption behaviour of 85 Sr can be modelled successfully by a linear isotherm, using a sorption parameter consistent with batch-sorption tests. The behaviour of 137 Cs may be modelled by a non-linear isotherm, but the amount of 137 Cs sorbed is less than that anticipated from batch-sorption tests. 125 I is assumed to be non-sorbing and is used to determine the porosity of the sandstone. (author) 10 figs., 4 tabs., 6 refs

  15. Event-Based Conceptual Modeling

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    2009-01-01

    The purpose of the paper is to obtain insight into and provide practical advice for event-based conceptual modeling. We analyze a set of event concepts and use the results to formulate a conceptual event model that is used to identify guidelines for creation of dynamic process models and static...... information models. We characterize events as short-duration processes that have participants, consequences, and properties, and that may be modeled in terms of information structures. The conceptual event model is used to characterize a variety of event concepts and it is used to illustrate how events can...... be used to integrate dynamic modeling of processes and static modeling of information structures. The results are unique in the sense that no other general event concept has been used to unify a similar broad variety of seemingly incompatible event concepts. The general event concept can be used...

  16. Model Breaking Points Conceptualized

    Science.gov (United States)

    Vig, Rozy; Murray, Eileen; Star, Jon R.

    2014-01-01

    Current curriculum initiatives (e.g., National Governors Association Center for Best Practices and Council of Chief State School Officers 2010) advocate that models be used in the mathematics classroom. However, despite their apparent promise, there comes a point when models break, a point in the mathematical problem space where the model cannot,…

  17. Development of a Self-Consistent Model of Plutonium Sorption: Quantification of Sorption Enthalpy and Ligand-Promoted Dissolution

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Brian [Clemson Univ., SC (United States); Kaplan, Daniel I [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Arai, Yuji [Univ. of Illinois, Urbana-Champaign, IL (United States); Becker, Udo [Univ. of Michigan, Ann Arbor, MI (United States); Ewing, Rod [Stanford Univ., CA (United States)

    2016-12-29

    This university lead SBR project is a collaboration lead by Dr. Brian Powell (Clemson University) with co-principal investigators Dan Kaplan (Savannah River National Laboratory), Yuji Arai (presently at the University of Illinois), Udo Becker (U of Michigan) and Rod Ewing (presently at Stanford University). Hypothesis: The underlying hypothesis of this work is that strong interactions of plutonium with mineral surfaces are due to formation of inner sphere complexes with a limited number of high-energy surface sites, which results in sorption hysteresis where Pu(IV) is the predominant sorbed oxidation state. The energetic favorability of the Pu(IV) surface complex is strongly influenced by positive sorption entropies, which are mechanistically driven by displacement of solvating water molecules from the actinide and mineral surface during sorption. Objectives: The overarching objective of this work is to examine Pu(IV) and Pu(V) sorption to pure metal (oxyhydr)oxide minerals and sediments using variable temperature batch sorption, X-ray absorption spectroscopy, electron microscopy, and quantum-mechanical and empirical-potential calculations. The data will be compiled into a self-consistent surface complexation model. The novelty of this effort lies largely in the manner the information from these measurements and calculations will be combined into a model that will be used to evaluate the thermodynamics of plutonium sorption reactions as well as predict sorption of plutonium to sediments from DOE sites using a component additivity approach.

  18. Sorption isotherms: A review on physical bases, modeling and measurement

    Energy Technology Data Exchange (ETDEWEB)

    Limousin, G. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France) and Laboratoire d' etude des Transferts en Hydrologie et Environnement (CNRS-INPG-IRD-UJF), BP 53, 38041 Grenoble Cedex (France)]. E-mail: guillaumelimousin@yahoo.fr; Gaudet, J.-P. [Laboratoire d' etude des Transferts en Hydrologie et Environnement (CNRS-INPG-IRD-UJF), BP 53, 38041 Grenoble Cedex (France); Charlet, L. [Laboratoire de Geophysique Interne et Techtonophysique - CNRS-IRD-LCPC-UJF-Universite de Savoie, BP 53, 38041 Grenoble Cedex (France); Szenknect, S. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France); Barthes, V. [Atomic Energy Commission, Tracers Technology Laboratory, 38054 Grenoble Cedex (France); Krimissa, M. [Electricite de France, Division Recherche et Developpement, Laboratoire National d' Hydraulique et d' Environnement - P78, 6 quai Watier, 78401 Chatou (France)

    2007-02-15

    The retention (or release) of a liquid compound on a solid controls the mobility of many substances in the environment and has been quantified in terms of the 'sorption isotherm'. This paper does not review the different sorption mechanisms. It presents the physical bases underlying the definition of a sorption isotherm, different empirical or mechanistic models, and details several experimental methods to acquire a sorption isotherm. For appropriate measurements and interpretations of isotherm data, this review emphasizes 4 main points: (i) the adsorption (or desorption) isotherm does not provide automatically any information about the reactions involved in the sorption phenomenon. So, mechanistic interpretations must be carefully verified. (ii) Among studies, the range of reaction times is extremely wide and this can lead to misinterpretations regarding the irreversibility of the reaction: a pseudo-hysteresis of the release compared with the retention is often observed. The comparison between the mean characteristic time of the reaction and the mean residence time of the mobile phase in the natural system allows knowing if the studied retention/release phenomenon should be considered as an instantaneous reversible, almost irreversible phenomenon, or if reaction kinetics must be taken into account. (iii) When the concentration of the retained substance is low enough, the composition of the bulk solution remains constant and a single-species isotherm is often sufficient, although it remains strongly dependent on the background medium. At higher concentrations, sorption may be driven by the competition between several species that affect the composition of the bulk solution. (iv) The measurement method has a great influence. Particularly, the background ionic medium, the solid/solution ratio and the use of flow-through or closed reactor are of major importance. The chosen method should balance easy-to-use features and representativity of the studied

  19. Re-evaluation of the sorption behaviour of Bromide and Sulfamethazine under field conditions using leaching data and modelling methods

    Science.gov (United States)

    Gassmann, Matthias; Olsson, Oliver; Höper, Heinrich; Hamscher, Gerd; Kümmerer, Klaus

    2016-04-01

    The simulation of reactive transport in the aquatic environment is hampered by the ambiguity of environmental fate process conceptualizations for a specific substance in the literature. Concepts are usually identified by experimental studies and inverse modelling under controlled lab conditions in order to reduce environmental uncertainties such as uncertain boundary conditions and input data. However, since environmental conditions affect substance behaviour, a re-evaluation might be necessary under environmental conditions which might, in turn, be affected by uncertainties. Using a combination of experimental data and simulations of the leaching behaviour of the veterinary antibiotic Sulfamethazine (SMZ; synonym: sulfadimidine) and the hydrological tracer Bromide (Br) in a field lysimeter, we re-evaluated the sorption concepts of both substances under uncertain field conditions. Sampling data of a field lysimeter experiment in which both substances were applied twice a year with manure and sampled at the bottom of two lysimeters during three subsequent years was used for model set-up and evaluation. The total amount of leached SMZ and Br were 22 μg and 129 mg, respectively. A reactive transport model was parameterized to the conditions of the two lysimeters filled with monoliths (depth 2 m, area 1 m²) of a sandy soil showing a low pH value under which Bromide is sorptive. We used different sorption concepts such as constant and organic-carbon dependent sorption coefficients and instantaneous and kinetic sorption equilibrium. Combining the sorption concepts resulted in four scenarios per substance with different equations for sorption equilibrium and sorption kinetics. The GLUE (Generalized Likelihood Uncertainty Estimation) method was applied to each scenario using parameter ranges found in experimental and modelling studies. The parameter spaces for each scenario were sampled using a Latin Hypercube method which was refined around local model efficiency maxima

  20. Conceptual Models for Search Engines

    Science.gov (United States)

    Hendry, D. G.; Efthimiadis, E. N.

    Search engines have entered popular culture. They touch people in diverse private and public settings and thus heighten the importance of such important social matters as information privacy and control, censorship, and equitable access. To fully benefit from search engines and to participate in debate about their merits, people necessarily appeal to their understandings for how they function. In this chapter we examine the conceptual understandings that people have of search engines by performing a content analysis on the sketches that 200 undergraduate and graduate students drew when asked to draw a sketch of how a search engine works. Analysis of the sketches reveals a diverse range of conceptual approaches, metaphors, representations, and misconceptions. On the whole, the conceptual models articulated by these students are simplistic. However, students with higher levels of academic achievement sketched more complete models. This research calls attention to the importance of improving students' technical knowledge of how search engines work so they can be better equipped to develop and advocate policies for how search engines should be embedded in, and restricted from, various private and public information settings.

  1. Conceptual Modeling via Logic Programming

    Science.gov (United States)

    1990-01-01

    CONCEPTUAL MODELING VIA LOGIC PROGRAMaNG 12. PERSONAL AUTHOR(S) John Burge, Bill Noah, Las Smith 13a. TYPE OF REPORT 13b. TIME COVERED 14. DATE OF...interpreter and named it Prolog for middle. He found that his program got into an "Programmation en logique ." It provided the infinite loop unless he used... lA N C I WA v Cruse Mle Submartine 44 0 0 0 0 0835 I 9 33 ICC 33 High F.e cruise Misaile 640 0 8S S44 0 0 High Post cruise missile 840 2 7S 440 too

  2. Surface complexation model of uranyl sorption on Georgia kaolinite

    Science.gov (United States)

    Payne, T.E.; Davis, J.A.; Lumpkin, G.R.; Chisari, R.; Waite, T.D.

    2004-01-01

    The adsorption of uranyl on standard Georgia kaolinites (KGa-1 and KGa-1B) was studied as a function of pH (3-10), total U (1 and 10 ??mol/l), and mass loading of clay (4 and 40 g/l). The uptake of uranyl in air-equilibrated systems increased with pH and reached a maximum in the near-neutral pH range. At higher pH values, the sorption decreased due to the presence of aqueous uranyl carbonate complexes. One kaolinite sample was examined after the uranyl uptake experiments by transmission electron microscopy (TEM), using energy dispersive X-ray spectroscopy (EDS) to determine the U content. It was found that uranium was preferentially adsorbed by Ti-rich impurity phases (predominantly anatase), which are present in the kaolinite samples. Uranyl sorption on the Georgia kaolinites was simulated with U sorption reactions on both titanol and aluminol sites, using a simple non-electrostatic surface complexation model (SCM). The relative amounts of U-binding >TiOH and >AlOH sites were estimated from the TEM/EDS results. A ternary uranyl carbonate complex on the titanol site improved the fit to the experimental data in the higher pH range. The final model contained only three optimised log K values, and was able to simulate adsorption data across a wide range of experimental conditions. The >TiOH (anatase) sites appear to play an important role in retaining U at low uranyl concentrations. As kaolinite often contains trace TiO2, its presence may need to be taken into account when modelling the results of sorption experiments with radionuclides or trace metals on kaolinite. ?? 2004 Elsevier B.V. All rights reserved.

  3. Kinetic modeling of water sorption by roasted and ground coffee

    Directory of Open Access Journals (Sweden)

    Fernanda Machado Baptestini

    2017-05-01

    Full Text Available The objective of this study was to model the kinetics of water sorption in roasted and ground coffee. Crude Arabica coffee beans with an initial moisture content of 0.1234 kgwkgdm-1 were used. These beans were roasted to a medium roast level (SCCA # 55 and ground at three particle sizes: coarse (1.19 mm, medium (0.84 mm and fine (0.59 mm. To obtain the water sorption isotherms and the isosteric heat, different conditions of temperature and relative humidity were analyzed using the dynamic method at 25ºC (0.50, 0.60, 0.70, and 0.80 of RH and 30°C (0.30, 0.40, 0.50, 0.60, 0.70, and 0.80 of RH and using the static method at 25ºC (0.332 and 0.438 of RH. The GAB model best represented the hygroscopic equilibrium of roasted coffee at every particle size. Isosteric heat of sorption for the fine particle size increased with increments of equilibrium moisture content, indicating a strong bond energy between water molecules and the product components. The Gibbs free energy decreased with the increase in equilibrium moisture content and with temperature.

  4. On the evolution of conceptual modeling

    OpenAIRE

    Kaschek, Roland H.

    2008-01-01

    Since the 1980s the need increased for overcoming idiosyncrasies of approaches to modeling in the various sub-disciplines of computing. The theoretical model of evolution is used in this paper for analyzing how computing and conceptual modeling have changed. It is concluded that computing has changed into a social phenomenon with a technical core and that therefore relying on (formal) model semantics as the sole tool for the discussion of conceptual modeling is no more adequate. A number of l...

  5. Modeling of Cd(II) sorption on mixed oxide

    International Nuclear Information System (INIS)

    Waseem, M.; Mustafa, S.; Naeem, A.; Shah, K.H.; Hussain, S.Y.; Safdar, M.

    2011-01-01

    Mixed oxide of iron and silicon (0.75 M Fe(OH)3:0.25 M SiO/sub 2/) was synthesized and characterized by various techniques like surface area analysis, point of zero charge (PZC), energy dispersive X-rays (EDX) spectroscopy, Thermogravimetric and differential thermal analysis (TG-DTA), Fourier transform infrared spectroscopy (FTIR) and X-rays diffraction (XRD) analysis. The uptake of Cd/sup 2+/ ions on mixed oxide increased with pH, temperature and metal ion concentration. Sorption data have been interpreted in terms of both Langmuir and Freundlich models. The Xm values at pH 7 are found to be almost twice as compared to pH 5. The values of both DH and DS were found to be positive indicating that the sorption process was endothermic and accompanied by the dehydration of Cd/sup 2+/. Further, the negative value of DG confirms the spontaneity of the reaction. The ion exchange mechanism was suggested to take place for each Cd/sup 2+/ ions at pH 5, whereas ion exchange was found coupled with non specific adsorption of metal cations at pH 7. (author)

  6. Sorption of organic compounds to activated carbons. Evaluation of isotherm models

    NARCIS (Netherlands)

    Pikaar, I.; Koelmans, A.A.; Noort, van P.C.M.

    2006-01-01

    Sorption to 'hard carbon' (black carbon, coal, kerogen) in soils and sediments is of major importance for risk assessment of organic pollutants. We argue that activated carbon (AC) may be considered a model sorbent for hard carbon. Here, we evaluate six sorption models on a literature dataset for

  7. Kinetic modeling of heavy metal sorption by vinyl pyridine based copolymer

    Directory of Open Access Journals (Sweden)

    Maksin Danijela D.

    2012-01-01

    Full Text Available Commercial macroporous poly(4-vinylpyridine-co-divinylbenzene [P4VPD], known as REILLEX-425 was characterized by mercury porosimetry, nitrogen physisorption, Fourier transformed infrared (FTIR spectroscopy and elemental analysis. Sorption rates of P4VPD for Cu(II, Co(II and Cr(VI ions were determined in static non-competitive experiments, at room temperature (298 K. Rapid sorption was observed, especially for Co(II, with half time, t1/2, of 1.5 min and high experimental maximal capacity, Qmax, of 3.08 mmol g-1. Four kinetic models (pseudo-first and pseudo-second order model, intraparticle diffusion and Boyd model were used for analyzing metal sorption by P4VPD. Metal ions sorption is well represented by the pseudo-second-order model, with definite influence of pore and film diffusion on sorption rates. [Projekat Ministarstva nauke Republike Srbije, br. III43009

  8. Conceptual Models Core to Good Design

    CERN Document Server

    Johnson, Jeff

    2011-01-01

    People make use of software applications in their activities, applying them as tools in carrying out tasks. That this use should be good for people--easy, effective, efficient, and enjoyable--is a principal goal of design. In this book, we present the notion of Conceptual Models, and argue that Conceptual Models are core to achieving good design. From years of helping companies create software applications, we have come to believe that building applications without Conceptual Models is just asking for designs that will be confusing and difficult to learn, remember, and use. We show how Concept

  9. Model Based Control of Moisture Sorption in a Historical Interior

    Directory of Open Access Journals (Sweden)

    P. Zítek

    2005-01-01

    Full Text Available This paper deals with a novel scheme for microclimate control in historical exhibition rooms, inhibiting moisture sorption phenomena that are inadmissible from the preventive conservation point of view. The impact of air humidity is the most significant harmful exposure for a great deal of the cultural heritage deposited in remote historical buildings. Leaving the interior temperature to run almost its spontaneous yearly cycle, the proposed non-linear model-based control protects exhibits from harmful variations in moisture content by compensating the temperature drifts with an adequate adjustment of the air humidity. Already implemented in a medieval interior since 1999, the proposed microclimate control has proved capable of permanently maintaining constant a desirable moisture content in organic or porous materials in the interior of a building. 

  10. The ternary sorption system U(VI)-phosphate-silica explained by spectroscopy and thermodynamic modelling

    Energy Technology Data Exchange (ETDEWEB)

    Foerstendorf, Harald; Stockmann, Madlen; Heim, Karsten; Mueller, Katharina; Brendler, Vinzenz [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Surface Processes; Comarmond, M.J.; Payne, T.E. [Australian Nuclear Science and Technology Organisation, Lucas Heights (Australia); Steudtner, Robin [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Inst. of Resource Ecology

    2017-06-01

    Spectroscopic data of sorption processes potentially provide direct impact on Surface Complexation Modelling (SCM) approaches. Based on spectroscopic data of the ternary sorption system U(VI)/phosphate/silica strongly suggesting the formation of a precipitate as the predominant surface process, SCM calculations accurately reproduced results from classical batch experiments.

  11. The ternary sorption system U(VI)-phosphate-silica explained by spectroscopy and thermodynamic modelling

    International Nuclear Information System (INIS)

    Foerstendorf, Harald; Stockmann, Madlen; Heim, Karsten; Mueller, Katharina; Brendler, Vinzenz; Steudtner, Robin

    2017-01-01

    Spectroscopic data of sorption processes potentially provide direct impact on Surface Complexation Modelling (SCM) approaches. Based on spectroscopic data of the ternary sorption system U(VI)/phosphate/silica strongly suggesting the formation of a precipitate as the predominant surface process, SCM calculations accurately reproduced results from classical batch experiments.

  12. Use of thermodynamic sorption models to derive radionuclide Kd values for performance assessment: Selected results and recommendations of the NEA sorption project

    Science.gov (United States)

    Ochs, M.; Davis, J.A.; Olin, M.; Payne, T.E.; Tweed, C.J.; Askarieh, M.M.; Altmann, S.

    2006-01-01

    For the safe final disposal and/or long-term storage of radioactive wastes, deep or near-surface underground repositories are being considered world-wide. A central safety feature is the prevention, or sufficient retardation, of radionuclide (RN) migration to the biosphere. To this end, radionuclide sorption is one of the most important processes. Decreasing the uncertainty in radionuclide sorption may contribute significantly to reducing the overall uncertainty of a performance assessment (PA). For PA, sorption is typically characterised by distribution coefficients (Kd values). The conditional nature of Kd requires different estimates of this parameter for each set of geochemical conditions of potential relevance in a RN's migration pathway. As it is not feasible to measure sorption for every set of conditions, the derivation of Kd for PA must rely on data derived from representative model systems. As a result, uncertainty in Kd is largely caused by the need to derive values for conditions not explicitly addressed in experiments. The recently concluded NEA Sorption Project [1] showed that thermodynamic sorption models (TSMs) are uniquely suited to derive K d as a function of conditions, because they allow a direct coupling of sorption with variable solution chemistry and mineralogy in a thermodynamic framework. The results of the project enable assessment of the suitability of various TSM approaches for PA-relevant applications as well as of the potential and limitations of TSMs to model RN sorption in complex systems. ?? by Oldenbourg Wissenschaftsverlag.

  13. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the modelModel validation by checking it against independent sets of data.

  14. Factors influencing sorption of ciprofloxacin onto activated sludge: Experimental assessment and modelling implications

    DEFF Research Database (Denmark)

    Polesel, Fabio; Lehnberg, Kai; Dott, Wolfgang

    2015-01-01

    and described, particularly for zwitterionic chemicals. Here we present an assessment of the effects of pH and iron salt dosing on the sorption of ciprofloxacin onto activated sludge using laboratory experiments and full-scale fate modelling. Experimental results were described with Freundlich isotherms...... and showed that non-linear sorption occurred under all the conditions tested. The greatest sorption potential was measured at pH = 7.4, at which ciprofloxacin is speciated mostly as zwitterion. Iron salt dosing increased sorption under aerobic and, to a lesser extent, anoxic conditions, whereas no effect...... was registered under anaerobic conditions. The activated sludge model for xenobiotics (ASM-X) was extended with Freundlich-based sorption kinetics and used to predict the fate of ciprofloxacin in a wastewater treatment plant (WWTP). Scenario simulations, using experimental Freundlich parameters, were used...

  15. Kinetics of neptunium(V) sorption and desorption on goethite: An experimental and modeling study

    Science.gov (United States)

    Tinnacher, Ruth M.; Zavarin, Mavrik; Powell, Brian A.; Kersting, Annie B.

    2011-11-01

    Various sorption phenomena, such as aging, hysteresis and irreversible sorption, can cause differences between contaminant (ad)sorption and desorption behavior and lead to apparent sorption 'asymmetry'. We evaluate the relevance of these characteristics for neptunium(V) (Np(V)) sorption/desorption on goethite using a 34-day flow-cell experiment and kinetic modeling. Based on experimental results, the Np(V) desorption rate is much slower than the (ad)sorption rate, and appears to decrease over the course of the experiment. The best model fit with a minimum number of fitting parameters was achieved with a multi-reaction model including (1) an equilibrium Freundlich site (site 1), (2) a kinetically-controlled, consecutive, first-order site (site 2), and (3) a parameter ψ, which characterizes the desorption rate on site 2 based on a concept related to transition state theory (TST). This approach allows us to link differences in adsorption and desorption kinetics to changes in overall reaction pathways, without assuming different adsorption and desorption affinities (hysteresis) or irreversible sorption behavior a priori. Using modeling as a heuristic tool, we determined that aging processes are relevant. However, hysteresis and irreversible sorption behavior can be neglected within the time-frame (desorption over 32 days) and chemical solution conditions evaluated in the flow-cell experiment. In this system, desorption reactions are very slow, but they are not irreversible. Hence, our data do not justify an assumption of irreversible Np(V) sorption to goethite in transport models, which effectively limits the relevance of colloid-facilitated Np(V) transport to near-field environments. However, slow Np(V) desorption behavior may also lead to a continuous contaminant source term when metals are sorbed to bulk mineral phases. Additional long-term experiments are recommended to definitely rule out irreversible Np(V) sorption behavior at very low surface loadings and

  16. A new safety assessment model for shallow land burial of LLW based on multicomponent sorption theory

    International Nuclear Information System (INIS)

    Katoh, N.; Asano, T.; Tasaka, H.

    1984-01-01

    A new model on the radionuclide migration in underground environment is developed based on ''multicomponent sorption theory''. The model is capable of predicting the behaviors of the coexisting materials in soil-ground water system as ''multicomponent sorption phenomena'' and also predicting the radinuclide migration affected by the changes of concentrations of coexisting materials. The model is not a ''statistical model'' but a ''chemical model'' based on the ''ion exchange theory'' and ''adsorption theory''. Additionally, the model is a ''kinetic model'' capable of estimating the effect of ''rate of sorption'' on the radionuclide migration. The validity of the model was checked by the results of column experiments for sorption. Finally, sample calculations on the radionuclide migration in reference shallow land burial site were carried out for demonstration

  17. Sorption Modeling and Verification for Off-Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Tavlarides, Lawrence [Syracuse Univ., NY (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Gabitto, Jorge [Prairie View Texas A& M; DePaoli, David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-12-20

    processes. These models were built on a numerical framework for solving conservation law problems in one-dimensional geometries such as spheres, cylinders, and lines. Coupled with the framework are specific models for adsorption in commercial adsorbents, such as zeolites and mordenites. Utilizing this modeling approach, the authors were able to accurately describe and predict adsorption kinetic data obtained from experiments at a variety of different temperatures and gas phase concentrations. A demonstration of how these models, and framework, can be used to simulate adsorption in fixed- bed columns is provided. The CO2 absorption work involved modeling with supportive experimental information. A dynamic model was developed to simulate CO2 absorption using high alkaline content water solutions. The model is based upon transient mass and energy balances for chemical species commonly present in CO2 absorption. A computer code was developed to implement CO2 absorption with a chemical reaction model. Experiments were conducted in a laboratory scale column to determine the model parameters. The influence of geometric parameters and operating variables on CO2 absorption was studied over a wide range of conditions. Continuing work could employ the model to control column operation and predict the absorption behavior under various input conditions and other prescribed experimental perturbations. The value of the validated models and numerical frameworks developed in this project is that they can be used to predict the sorption behavior of off-gas evolved during the reprocessing of nuclear waste and thus reduce the cost of the experiments. They can also be used to design sorption processes based on concentration limits and flow-rates determined at the plant level.

  18. Limitations of sorption isotherms on modeling groundwater contaminant transport

    International Nuclear Information System (INIS)

    Silva, Eduardo Figueira da

    2007-01-01

    Design and safety assessment of radioactive waste repositories, as well as remediation of radionuclide contaminated groundwater require the development of models capable of accurately predicting trace element fate and transport. Adsorption of trace radionuclides onto soils and groundwater is an important mechanism controlling near- and far- field transport. Although surface complexation models (SCMs) can better describe the adsorption mechanisms of most radionuclides onto mineral surfaces by directly accounting for variability of system properties and mineral surface properties, isotherms are still used to model contaminant transport in groundwater, despite the much higher system dependence. The present work investigates differences between transport model results based on these two approaches for adsorption modeling. A finite element transport model is used for the isotherm model, whereas the computer program PHREEQC is used for the SCM approach. Both models are calibrated for a batch experiment, and one-dimensional transport is simulated using the calibrated parameters. At the lower injected concentrations there are large discrepancies between SCM and isotherm transport predictions, with the SCM presenting much longer tails on the breakthrough curves. Isotherms may also provide non-conservative results for time to breakthrough and for maximum concentration in a contamination plume. Isotherm models are shown not to be robust enough to predict transport behavior of some trace elements, thus discouraging their use. The results also illustrate the promise of the SCM modeling approach in safety assessment and environmental remediation applications, also suggesting that independent batch sorption measurements can be used, within the framework of the SCM, to produce a more versatile and realistic groundwater transport model for radionuclides which is capable of accounting more accurately for temporal and spatial variations in geochemical conditions. (author)

  19. The selection and use of a sorption database for the geosphere model in the Canadian nuclear fuel waste management program

    International Nuclear Information System (INIS)

    Vandergraaf, T.T.; Ticknor, K.V.; Melnyk, T.W.

    1992-01-01

    An extensively characterized intrusive granitic formation, the Lac du Bonnet batholith, is being used as a test case for environmental and safety assessment calculations of the impact of a hypothetical disposal vault. The conceptual vault has dimensions of 2 x 2 km and is located at a depth of 500 m, near the Whiteshell Nuclear Research Establishment (WNRE) (CANADA). Hydraulic investigations of the batholith have shown that the bulk of the groundwater flow will be limited to the existing network of water-bearing fractures. Groundwater flow and contaminant transport modelling is based on a porous-medium concept for both the fracture systems and the rock matrix. Geochemical investigations have identified a number of alteration minerals in these fracture systems. The geochemistry encountered along the flow field is too complex to allow the interaction of radionuclides with the geological material to be represented by a single sorption coefficient for each radionuclide on a single rock type. However, the level of understanding of radionuclide interaction with geological materials is not sufficiently well developed to calculate radionuclide transport using models based on chemical thermodynamics or on advanced sorption models based on surface complexation or mass action. Instead, a parametric model has been developed using the total dissolved solids and radionuclide concentrations as independent variables. The mineralogical complexity of the flow field is addressed by selecting sorption data on the nine most commonly occurring fracture infilling minerals in this batholith, four common rock-forming minerals, and on altered and unaltered granite. This approach produces two polynomial equations for each radionuclide/mineral combination, one under oxic and one under anoxic conditions. Where insufficient information is available, these polynomial expressions are reduced to an equation with one variable or to a single sorption coefficient. 48 refs., 6 figs., 4 tabs

  20. Formalizing Linguistic Conventions for Conceptual Models

    Science.gov (United States)

    Becker, Jörg; Delfmann, Patrick; Herwig, Sebastian; Lis, Łukasz; Stein, Armin

    A precondition for the appropriate analysis of conceptual models is not only their syntactic correctness but also their semantic comparability. Assuring comparability is challenging especially when models are developed by different persons. Empirical studies show that such models can vary heavily, especially in model element naming, even if they express the same issue. In contrast to most ontology-driven approaches proposing the resolution of these differences ex-post, we introduce an approach that avoids naming differences in conceptual models already during modeling. Therefore we formalize naming conventions combining domain thesauri and phrase structures based on a lin-guistic grammar. This allows for guiding modelers automatically during the modeling process using standardized labels for model elements. Our approach is generic, making it applicable for any modeling language.

  1. SITE-94. Adaptation of mechanistic sorption models for performance assessment calculations

    International Nuclear Information System (INIS)

    Arthur, R.C.

    1996-10-01

    Sorption is considered in most predictive models of radionuclide transport in geologic systems. Most models simulate the effects of sorption in terms of empirical parameters, which however can be criticized because the data are only strictly valid under the experimental conditions at which they were measured. An alternative is to adopt a more mechanistic modeling framework based on recent advances in understanding the electrical properties of oxide mineral-water interfaces. It has recently been proposed that these 'surface-complexation' models may be directly applicable to natural systems. A possible approach for adapting mechanistic sorption models for use in performance assessments, using this 'surface-film' concept, is described in this report. Surface-acidity parameters in the Generalized Two-Layer surface complexation model are combined with surface-complexation constants for Np(V) sorption ob hydrous ferric oxide to derive an analytical model enabling direct calculation of corresponding intrinsic distribution coefficients as a function of pH, and Ca 2+ , Cl - , and HCO 3 - concentrations. The surface film concept is then used to calculate whole-rock distribution coefficients for Np(V) sorption by altered granitic rocks coexisting with a hypothetical, oxidized Aespoe groundwater. The calculated results suggest that the distribution coefficients for Np adsorption on these rocks could range from 10 to 100 ml/g. Independent estimates of K d for Np sorption in similar systems, based on an extensive review of experimental data, are consistent, though slightly conservative, with respect to the calculated values. 31 refs

  2. Event-Based Conceptual Modeling

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    The paper demonstrates that a wide variety of event-based modeling approaches are based on special cases of the same general event concept, and that the general event concept can be used to unify the otherwise unrelated fields of information modeling and process modeling. A set of event-based mod......The paper demonstrates that a wide variety of event-based modeling approaches are based on special cases of the same general event concept, and that the general event concept can be used to unify the otherwise unrelated fields of information modeling and process modeling. A set of event......-based modeling approaches are analyzed and the results are used to formulate a general event concept that can be used for unifying the seemingly unrelated event concepts. Events are characterized as short-duration processes that have participants, consequences, and properties, and that may be modeled in terms...

  3. Driver Performance Model: 1. Conceptual Framework

    National Research Council Canada - National Science Library

    Heimerl, Joseph

    2001-01-01

    ...'. At the present time, no such comprehensive model exists. This report discusses a conceptual framework designed to encompass the relationships, conditions, and constraints related to direct, indirect, and remote modes of driving and thus provides a guide or 'road map' for the construction and creation of a comprehensive driver performance model.

  4. Analysis of Subjective Conceptualizations Towards Collective Conceptual Modelling

    DEFF Research Database (Denmark)

    Glückstad, Fumiko Kano; Herlau, Tue; Schmidt, Mikkel Nørgaard

    2013-01-01

    This work is conducted as a preliminary study for a project where individuals' conceptualizations of domain knowledge will thoroughly be analyzed across 150 subjects from 6 countries. The project aims at investigating how humans' conceptualizations differ according to different types of mother...

  5. Analysis of Subjective Conceptualizations Towards Collective Conceptual Modelling

    DEFF Research Database (Denmark)

    Glückstad, Fumiko Kano; Herlau, Tue; Schmidt, Mikkel Nørgaard

    2013-01-01

    This work is conducted as a preliminary study for a project where individuals' conceptualizations of domain knowledge will thoroughly be analyzed across 150 subjects from 6 countries. The project aims at investigating how humans' conceptualizations differ according to different types of mother la...

  6. Experimental Study and modelling of the Sorption of Selenite and Europium Onto Smectite and Illite Clays

    Energy Technology Data Exchange (ETDEWEB)

    Missana, T.; Alonso, U.; Garcia-Gutierrez, M.

    2009-10-12

    This study provides a large set of experimental selenite sorption data for pure smectite and illite. Similar sorption behavior existed in both clays: linear within a large range of the Se concentrations investigated and independent of ionic strength. Selenite sorption was also analysed in the illite/smectite system with the clays mixed in two different proportions. The objective of the study was to provide the simplest model possible to fit the experimental data, a model also capable of describing selenite sorption in binary illite/smectite clay systems. Selenite sorption data were modeled using both a one-and a two-site non-electrostatic model that took into account the formation of two complexes at the edge sites of the clay. The complexation constants obtained by fitting sorption data of the individual minerals were incorporated into a model to predict the adsorption of selenium in the illite/ smectite mixtures; the models predictions were consistent with the experimental adsorption data. (Author) 42 refs.

  7. Experimental Study and modelling of the Sorption of Selenite and Europium Onto Smectite and Illite Clays

    International Nuclear Information System (INIS)

    Missana, T.; Alonso, U.; Garcia-Gutierrez, M.

    2009-01-01

    This study provides a large set of experimental selenite sorption data for pure smectite and illite. Similar sorption behavior existed in both clays: linear within a large range of the Se concentrations investigated and independent of ionic strength. Selenite sorption was also analysed in the illite/smectite system with the clays mixed in two different proportions. The objective of the study was to provide the simplest model possible to fit the experimental data, a model also capable of describing selenite sorption in binary illite/smectite clay systems. Selenite sorption data were modeled using both a one-and a two-site non-electrostatic model that took into account the formation of two complexes at the edge sites of the clay. The complexation constants obtained by fitting sorption data of the individual minerals were incorporated into a model to predict the adsorption of selenium in the illite/ smectite mixtures; the models predictions were consistent with the experimental adsorption data. (Author) 42 refs

  8. FRSAD conceptual modeling of aboutness

    CERN Document Server

    Zeng, Marcia; Žumer, Maja

    2012-01-01

    The first comprehensive exploration of the development and use of the International Federation of Library Associations and Institutions' (IFLA) newly released model for subject authority data, covering everything from the rationale for creating the model to practical steps for implementing it.

  9. Mathematical Model of Sorption Kinetics of Crude Oil by Rubber Particles from Scrap Tyres

    Directory of Open Access Journals (Sweden)

    Felix A. AISIEN

    2011-06-01

    Full Text Available This paper present an insight into how rubber particles from scrap tyres can be utilized to clean up oil spillages as well as how the process of sorption of crude oil by rubber particles can be stimulated based on sorption kinetics. Crude oil sorption tests using recycled rubber particles (a model absorbent were designed for investigating crude oil concentration profiles. The model based on a linear driving force (LDF was developed using a set of experimental data and multiple regression analysis. The crude oil sorption performance tests were conducted under various operating conditions by varying parameters such as rubber particle size and absorption temperature. The predictive capacity of the kinetic model was evaluated under conditions significantly different from those that have already been measured. The experimental results obtained previously were correlated with the first order sorption kinetics model developed. The results showed that the first order kinetics model accurately correlate the experimental data generated. Also, satisfactory results were obtained from simulation of other operating conditions; hence the crude oil sorption kinetics is first order.

  10. Assessing alternative conceptual models of fracture flow

    International Nuclear Information System (INIS)

    Ho, C.K.

    1995-01-01

    The numerical code TOUGH2 was used to assess alternative conceptual models of fracture flow. The models that were considered included the equivalent continuum model (ECM) and the dual permeability (DK) model. A one-dimensional, layered, unsaturated domain was studied with a saturated bottom boundary and a constant infiltration at the top boundary. Two different infiltration rates were used in the studies. In addition, the connection areas between the fracture and matrix elements in the dual permeability model were varied. Results showed that the two conceptual models of fracture flow produced different saturation and velocity profiles-even under steady-state conditions. The magnitudes of the discrepancies were sensitive to two parameters that affected the flux between the fractures and matrix in the dual permeability model: (1) the fracture-matrix connection areas and (2) the capillary pressure gradients between the fracture and matrix elements

  11. Surface Complexation Model for Strontium Sorption to Amorphous Silica and Goethite

    Energy Technology Data Exchange (ETDEWEB)

    Carroll, S; Robers, S; Criscenti, L; O' Day, P

    2007-11-30

    Strontium sorption to amorphous silica and goethite was measured as a function of pH and dissolved strontium and carbonate concentrations at 25 C. Strontium sorption gradually increases from 0 to 100% from pH 6 to 10 for both phases and requires multiple outer-sphere surface complexes to fit the data. All data are modeled using the triple layer model and the site-occupancy standard state; unless stated otherwise all strontium complexes are mononuclear. Strontium sorption to amorphous silica in the presence and absence of dissolved carbonate can be fit with tetradentate Sr{sup 2+} and SrOH{sup +} complexes on the {beta}-plane and a monodentate Sr{sup 2+} complex on the diffuse plane to account for strontium sorption at low ionic strength. Strontium sorption to goethite in the absence of dissolved carbonate can be fit with monodentate and tetradentate SrOH{sup +} complexes and a tetradentate binuclear Sr{sup 2+} species on the {beta}-plane. The binuclear complex is needed to account for enhanced sorption at high strontium surface loadings. In the presence of dissolved carbonate additional monodentate Sr{sup 2+} and SrOH{sup +} carbonate surface complexes on the {beta}-plane are needed to fit strontium sorption to goethite. Modeling strontium sorption as outer-sphere complexes is consistent with quantitative analysis of extended X-ray absorption fine structure (EXAFS) on selected sorption samples that show a single first shell of oxygen atoms around strontium indicating hydrated surface complexes at the amorphous silica and goethite surfaces. Strontium surface complexation equilibrium constants determined in this study combined with other alkaline earth surface complexation constants are used to recalibrate a predictive model based on Born solvation and crystal-chemistry theory. The model is accurate to about 0.7 log K units. More studies are needed to determine the dependence of alkaline earth sorption on ionic strength and dissolved carbonate and sulfate

  12. Surface complexation model for strontium sorption to amorphous silica and goethite

    Directory of Open Access Journals (Sweden)

    Criscenti Louise J

    2008-01-01

    Full Text Available Abstract Strontium sorption to amorphous silica and goethite was measured as a function of pH and dissolved strontium and carbonate concentrations at 25°C. Strontium sorption gradually increases from 0 to 100% from pH 6 to 10 for both phases and requires multiple outer-sphere surface complexes to fit the data. All data are modeled using the triple layer model and the site-occupancy standard state; unless stated otherwise all strontium complexes are mononuclear. Strontium sorption to amorphous silica in the presence and absence of dissolved carbonate can be fit with tetradentate Sr2+ and SrOH+ complexes on the β-plane and a monodentate Sr2+complex on the diffuse plane to account for strontium sorption at low ionic strength. Strontium sorption to goethite in the absence of dissolved carbonate can be fit with monodentate and tetradentate SrOH+ complexes and a tetradentate binuclear Sr2+ species on the β-plane. The binuclear complex is needed to account for enhanced sorption at hgh strontium surface loadings. In the presence of dissolved carbonate additional monodentate Sr2+ and SrOH+ carbonate surface complexes on the β-plane are needed to fit strontium sorption to goethite. Modeling strontium sorption as outer-sphere complexes is consistent with quantitative analysis of extended X-ray absorption fine structure (EXAFS on selected sorption samples that show a single first shell of oxygen atoms around strontium indicating hydrated surface complexes at the amorphous silica and goethite surfaces. Strontium surface complexation equilibrium constants determined in this study combined with other alkaline earth surface complexation constants are used to recalibrate a predictive model based on Born solvation and crystal-chemistry theory. The model is accurate to about 0.7 log K units. More studies are needed to determine the dependence of alkaline earth sorption on ionic strength and dissolved carbonate and sulfate concentrations for the development of

  13. Modeling volatile organic compounds sorption on dry building materials using double-exponential model

    International Nuclear Information System (INIS)

    Deng, Baoqing; Ge, Di; Li, Jiajia; Guo, Yuan; Kim, Chang Nyung

    2013-01-01

    A double-exponential surface sink model for VOCs sorption on building materials is presented. Here, the diffusion of VOCs in the material is neglected and the material is viewed as a surface sink. The VOCs concentration in the air adjacent to the material surface is introduced and assumed to always maintain equilibrium with the material-phase concentration. It is assumed that the sorption can be described by mass transfer between the room air and the air adjacent to the material surface. The mass transfer coefficient is evaluated from the empirical correlation, and the equilibrium constant can be obtained by linear fitting to the experimental data. The present model is validated through experiments in small and large test chambers. The predicted results accord well with the experimental data in both the adsorption stage and desorption stage. The model avoids the ambiguity of model constants found in other surface sink models and is easy to scale up

  14. Sorption Modeling and Verification for Off-Gas Treatment

    International Nuclear Information System (INIS)

    Tavlarides, Lawrence L.; Lin, Ronghong; Nan, Yue; Yiacoumi, Sotira; Tsouris, Costas; Ladshaw, Austin; Sharma, Ketki; Gabitto, Jorge; DePaoli, David

    2015-01-01

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  15. Sorption Modeling and Verification for Off-Gas Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Tavlarides, Lawrence L. [Syracuse Univ., NY (United States); Lin, Ronghong [Syracuse Univ., NY (United States); Nan, Yue [Syracuse Univ., NY (United States); Yiacoumi, Sotira [Georgia Inst. of Technology, Atlanta, GA (United States); Tsouris, Costas [Georgia Inst. of Technology, Atlanta, GA (United States); Ladshaw, Austin [Georgia Inst. of Technology, Atlanta, GA (United States); Sharma, Ketki [Georgia Inst. of Technology, Atlanta, GA (United States); Gabitto, Jorge [Prairie View A & M Univ., Prairie View, TX (United States); DePaoli, David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-29

    The project has made progress toward developing a comprehensive modeling capability for the capture of target species in off gas evolved during the reprocessing of nuclear fuel. The effort has integrated experimentation, model development, and computer code development for adsorption and absorption processes. For adsorption, a modeling library has been initiated to include (a) equilibrium models for uptake of off-gas components by adsorbents, (b) mass transfer models to describe mass transfer to a particle, diffusion through the pores of the particle and adsorption on the active sites of the particle, and (c) interconnection of these models to fixed bed adsorption modeling which includes advection through the bed. For single-component equilibria, a Generalized Statistical Thermodynamic Adsorption (GSTA) code was developed to represent experimental data from a broad range of isotherm types; this is equivalent to a Langmuir isotherm in the two-parameter case, and was demonstrated for Kr on INL-engineered sorbent HZ PAN, water sorption on molecular sieve A sorbent material (MS3A), and Kr and Xe capture on metal-organic framework (MOF) materials. The GSTA isotherm was extended to multicomponent systems through application of a modified spreading pressure surface activity model and generalized predictive adsorbed solution theory; the result is the capability to estimate multicomponent adsorption equilibria from single-component isotherms. This advance, which enhances the capability to simulate systems related to off-gas treatment, has been demonstrated for a range of real-gas systems in the literature and is ready for testing with data currently being collected for multicomponent systems of interest, including iodine and water on MS3A. A diffusion kinetic model for sorbent pellets involving pore and surface diffusion as well as external mass transfer has been established, and a methodology was developed for determining unknown diffusivity parameters from transient

  16. Modeling polychlorinated biphenyl sorption isotherms for soot and coal

    NARCIS (Netherlands)

    Jantunen, A.P.K.; Koelmans, A.A.; Jonker, M.T.O.

    2010-01-01

    Sorption isotherms (pg-ng/L) were measured for 11 polychlorinated biphenyls (PCBs) of varying molecular planarity from aqueous solution to two carbonaceous geosorbents, anthracite coal and traffic soot. All isotherms were reasonably log-log-linear, but smooth for traffic soot and staircase-shaped

  17. Conceptual modeling in social and physical contexts

    NARCIS (Netherlands)

    Wieringa, Roelf J.

    The history of the computing sciences shows a shift in attention from the syntactic properties of computation to the semantics of computing in the real world. A large part of this shift has been brought about by the introduction of conceptual modeling languages. In this paper I review this history

  18. Logistics and Transport - a conceptual model

    DEFF Research Database (Denmark)

    Jespersen, Per Homann; Drewes, Lise

    2004-01-01

    This paper describes how the freight transport sector is influenced by logistical principles of production and distribution. It introduces new ways of understanding freight transport as an integrated part of the changing trends of mobility. By introducing a conceptual model for understanding...... the interaction between logistics and transport, it points at ways to over-come inherent methodological difficulties when studying this relation...

  19. Modeling coupled sorption and transformation of 17β-estradiol–17-sulfate in soil–water systems

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Xuelian; Shrestha, Suman L.; Casey, Francis X. M.; Hakk, Heldur; Fan, Zhaosheng

    2014-11-01

    Animal manure is the primary source of exogenous free estrogens in the environment, which are known endocrine-disrupting chemicals to disorder the reproduction system of organisms. Conjugated estrogens can act as precursors to free estrogens, which may increase the total estrogenicity in the environment. In this study, a comprehensive model was used to simultaneously simulate the coupled sorption and transformation of a sulfate estrogen conjugate, 17 beta-estradiol-17-sulfate (E2-17S), in various soil-water systems (non-sterile/sterile; topsoil/subsoil). The simulated processes included multiple transformation pathways (i.e. hydroxylation, hydrolysis, and oxidation) and mass transfer between the aqueous, reversibly sorbed, and irreversibly sorbed phases of all soils for E2-17S and its metabolites. The conceptual model was conceived based on a series of linear sorption and first-order transformation expressions. The model was inversely solved Using finite difference to estimate process parameters. A global optimization method was applied for the inverse analysis along with variable model restrictions to estimate 36 parameters. The model provided a satisfactory simultaneous fit (R-adj(2) = 0.93 and d = 0.87) of all the experimental data and reliable parameter estimates. This modeling study improved the understanding on fate and transport of estrogen conjugates under various soil-water conditions.

  20. The conceptualization model problem—surprise

    Science.gov (United States)

    Bredehoeft, John

    2005-03-01

    The foundation of model analysis is the conceptual model. Surprise is defined as new data that renders the prevailing conceptual model invalid; as defined here it represents a paradigm shift. Limited empirical data indicate that surprises occur in 20-30% of model analyses. These data suggest that groundwater analysts have difficulty selecting the appropriate conceptual model. There is no ready remedy to the conceptual model problem other than (1) to collect as much data as is feasible, using all applicable methods—a complementary data collection methodology can lead to new information that changes the prevailing conceptual model, and (2) for the analyst to remain open to the fact that the conceptual model can change dramatically as more information is collected. In the final analysis, the hydrogeologist makes a subjective decision on the appropriate conceptual model. The conceptualization problem does not render models unusable. The problem introduces an uncertainty that often is not widely recognized. Conceptual model uncertainty is exacerbated in making long-term predictions of system performance. C'est le modèle conceptuel qui se trouve à base d'une analyse sur un modèle. On considère comme une surprise lorsque le modèle est invalidé par des données nouvelles; dans les termes définis ici la surprise est équivalente à un change de paradigme. Des données empiriques limitées indiquent que les surprises apparaissent dans 20 à 30% des analyses effectuées sur les modèles. Ces données suggèrent que l'analyse des eaux souterraines présente des difficultés lorsqu'il s'agit de choisir le modèle conceptuel approprié. Il n'existe pas un autre remède au problème du modèle conceptuel que: (1) rassembler autant des données que possible en utilisant toutes les méthodes applicables—la méthode des données complémentaires peut conduire aux nouvelles informations qui vont changer le modèle conceptuel, et (2) l'analyste doit rester ouvert au fait

  1. Conceptual geohydrological model of the separations area

    International Nuclear Information System (INIS)

    Root, R.W.; Marine, I.W.

    1977-01-01

    Subsurface drilling in and around the Separations Areas (F-Area and H-Area of the Savannah River Plant) is providing detailed information for a conceptual model of the geology and hydrology underlying these areas. This conceptual model will provide the framework needed for a mathematical model of groundwater movement beneath these areas. Existing information substantiates the presence of two areally extensive clay layers and several discontinuous clay and sandy-clay layers. These layers occur in and between beds of clayey and silty sand that make up most of the subsurface material. Within these sand beds are geologic units of differing hydraulic conductivity. For the present scale of the model, the subsurface information is considered adequate in H-Area, but additional drilling is planned in F-Area

  2. Characterization of U(VI) Sorption-Desorption Processes and Model Upscaling

    International Nuclear Information System (INIS)

    Bai, Jing; Dong, Wenming; Ball, William P.

    2006-01-01

    The objectives of the overall collaborative EMSP effort (with which this project is associated) were to characterize sorption and desorption processes of U(VI) on pristine and contaminated Hanford sediments over a range of sediment facies and materials properties and to relate such characterization both to fundamental molecular-scale understanding and field-scale models of geochemistry and mass transfer. The research was intended to provide new insights on the mechanisms of U(VI) retardation at Hanford, and to allow the development of approaches by which laboratory-developed geochemical models could be upscaled for defensible field-scale predictions of uranium transport in the environment. Within this broader context, objectives of the JHU-based project were to test hypotheses regarding the coupled roles of adsorption and impermeable-zone diffusion in controlling the fate and transport of U(VI) species under conditions of comparatively short-term exposure. In particular, this work tested the following hypotheses: (1) the primary adsorption processes in the Hanford sediment over the pH range of 7 to 10 are surface complexation reactions of aqueous U(VI) hydroxycarbonate and carbonate complexes with amphoteric edge sites on detrital phyllosilicates in the silt/clay size fraction; (2) macroscopic adsorption intensity (at given aqueous conditions) is a function of mineral composition and aquatic chemistry; and (3) equilibrium sorption and desorption to apply in short-term, laboratory-spiked pristine sediments; and (4) interparticle diffusion can be fully understood in terms of a model that couples molecular diffusion of uranium species in the porewater with equilibrium sorption under the relevant aqueous conditions. The primary focus of the work was on developing and applying both models and experiments to test the applicability of ''local equilibrium'' assumptions in the modeling interpretation of sorption retarded interparticle diffusion, as relevant to processes of

  3. Characterization of U(VI) Sorption-Desorption Processes and Model Upscaling

    Energy Technology Data Exchange (ETDEWEB)

    Bai, Jing; Dong, Wenming; Ball, William P.

    2006-10-12

    The objectives of the overall collaborative EMSP effort (with which this project is associated) were to characterize sorption and desorption processes of U(VI) on pristine and contaminated Hanford sediments over a range of sediment facies and materials properties and to relate such characterization both to fundamental molecular-scale understanding and field-scale models of geochemistry and mass transfer. The research was intended to provide new insights on the mechanisms of U(VI) retardation at Hanford, and to allow the development of approaches by which laboratory-developed geochemical models could be upscaled for defensible field-scale predictions of uranium transport in the environment. Within this broader context, objectives of the JHU-based project were to test hypotheses regarding the coupled roles of adsorption and impermeable-zone diffusion in controlling the fate and transport of U(VI) species under conditions of comparatively short-term exposure. In particular, this work tested the following hypotheses: (1) the primary adsorption processes in the Hanford sediment over the pH range of 7 to 10 are surface complexation reactions of aqueous U(VI) hydroxycarbonate and carbonate complexes with amphoteric edge sites on detrital phyllosilicates in the silt/clay size fraction; (2) macroscopic adsorption intensity (at given aqueous conditions) is a function of mineral composition and aquatic chemistry; and (3) equilibrium sorption and desorption to apply in short-term, laboratory-spiked pristine sediments; and (4) interparticle diffusion can be fully understood in terms of a model that couples molecular diffusion of uranium species in the porewater with equilibrium sorption under the relevant aqueous conditions. The primary focus of the work was on developing and applying both models and experiments to test the applicability of "local equilibrium" assumptions in the modeling interpretation of sorption retarded interparticle diffusion, as relevant to processes of U

  4. User verification of the FRBR conceptual model

    OpenAIRE

    Pisanski, Jan; Žumer, Maja

    2015-01-01

    Purpose - The paper aims to build on of a previous study of mental model s of the bibliographic universe, which found that the Functional Requirements for Bibliographic Records (FRBR) conceptual model is intuitive. Design/ methodology/approach - A total 120 participants were presented with a list of bibliographic entities and six graphs each. They were asked to choose the graph they thought best represented the relationships between entities described. Findings - The graph bas ed on the FRBR ...

  5. ORGANIZATIONAL LEARNING AND PERFORMANCE. A CONCEPTUAL MODEL

    OpenAIRE

    Alexandra Luciana GUÞÃ

    2013-01-01

    Throught this paper, our main objective is to propose a conceptual model that links the notions of organizational learning (as capability and as a process) and organizational performance. Our contribution consists in analyzing the literature on organizational learning and organizational performance and in proposing an integrated model, that comprises: organizational learning capability, the process of organizational learning, organizational performance, human capital (the value and uniqueness...

  6. A sorption model for alkalis in cement-based materials - Correlations with solubility and electrokinetic properties

    Science.gov (United States)

    Henocq, Pierre

    2017-06-01

    In cement-based materials, radionuclide uptake is mainly controlled by calcium silicate hydrates (C-S-H). This work presents an approach for defining a unique set of parameters of a surface complexation model describing the sorption behavior of alkali ions on the C-S-H surface. Alkali sorption processes are modeled using the CD-MUSIC function integrated in the Phreeqc V.3.0.6 geochemical code. Parameterization of the model was performed based on (1) retention, (2) zeta potential, and (3) solubility experimental data from the literature. This paper shows an application of this model to sodium ions. It was shown that retention, i.e. surface interactions, and solubility are closely related, and a consistent sorption model for radionuclides in cement-based materials requires a coupled surface interaction/chemical equilibrium model. In case of C-S-H with low calcium-to-silicon ratios, sorption of sodium ions on the C-S-H surface strongly influences the chemical equilibrium of the C-S-H + NaCl system by significantly increasing the aqueous calcium concentration. The close relationship between sorption and chemical equilibrium was successfully illustrated by modeling the effect of the solid-to-liquid ratio on the calcium content in solution in the case of C-S-H + NaCl systems.

  7. Conceptual and Numerical Modeling of Radionuclide Transport and Retention in Near-Surface Systems

    International Nuclear Information System (INIS)

    Pique, Angels; Arcos, David; Grandia, Fidel; Molinero, Jorge; Duro, Lara; Berglund, Sten

    2013-01-01

    Scenarios of barrier failure and radionuclide release to the near-surface environment are important to consider within performance and safety assessments of repositories for nuclear waste. A geological repository for spent nuclear fuel is planned at Forsmark, Sweden. Conceptual and numerical reactive transport models were developed in order to assess the retention capacity of the Quaternary till and clay deposits for selected radionuclides, in the event of an activity release from the repository. The elements considered were carbon (C), chlorine (Cl), cesium (Cs), iodine (I), molybdenum (Mo), niobium (Nb), nickel (Ni), radium (Ra), selenium (Se), strontium (Sr), technetium (Tc), thorium (Th), and uranium (U). According to the numerical predictions, the repository-derived nuclides that would be most significantly retained are Th, Ni, and Cs, mainly through sorption onto clays, followed by U, C, Sr, and Ra, trapped by sorption and/or incorporation into mineral phases

  8. Evaluation of theoretical and empirical water vapor sorption isotherm models for soils

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Møldrup, Per

    2016-01-01

    sorption isotherms of building materials, food, and other industrial products, knowledge about the 24 applicability of these functions for soils is noticeably lacking. We present validation of nine models for characterizing adsorption/desorption isotherms for a water activity range from 0.03 to 0.......93 for 207 soils, widely varying in texture and organic carbon content. In addition the potential applicability of the models for prediction of sorption isotherms from known clay content was investigated. While in general all investigated models described measured adsorption and desorption isotherms......The mathematical characterization of water vapor sorption isotherms of soils is crucial for modeling processes such as volatilization of pesticides and diffusive and convective water vapor transport. Although numerous physically-based and empirical models were previously proposed to describe...

  9. Generalized groundwater plume with degradation and rate-limited sorption model with Mittag-Leffler law

    Directory of Open Access Journals (Sweden)

    Badr Saad T. Alkahtani

    Full Text Available The concept of differentiation with the generalized Mittag-Leffler law is used in this paper to construct the model of movement of groundwater pollution with degradation and limited sorption. The fractional differentiation used in the model is in Riemann-Liouville sense. The new model is solved analytically using the Green Laplace transform approach. A numerical scheme is used to obtain the numerical solution of the modified model. Keywords: Movement of groundwater pollution, Plume with degradation, Rate-limited sorption, Atangana-Baleanu derivative in Riemann-Liouville sense

  10. Development of a Composite Non-Electrostatic Surface Complexation Model Describing Plutonium Sorption to Aluminosilicates

    Energy Technology Data Exchange (ETDEWEB)

    Powell, B A; Kersting, A; Zavarin, M; Zhao, P

    2008-10-28

    Due to their ubiquity in nature and chemical reactivity, aluminosilicate minerals play an important role in retarding actinide subsurface migration. However, very few studies have examined Pu interaction with clay minerals in sufficient detail to produce a credible mechanistic model of its behavior. In this work, Pu(IV) and Pu(V) interactions with silica, gibbsite (Aloxide), and Na-montmorillonite (smectite clay) were examined as a function of time and pH. Sorption of Pu(IV) and Pu(V) to gibbsite and silica increased with pH (4 to 10). The Pu(V) sorption edge shifted to lower pH values over time and approached that of Pu(IV). This behavior is apparently due to surface mediated reduction of Pu(V) to Pu(IV). Surface complexation constants describing Pu(IV)/Pu(V) sorption to aluminol and silanol groups were developed from the silica and gibbsite sorption experiments and applied to the montmorillonite dataset. The model provided an acceptable fit to the montmorillonite sorption data for Pu(V). In order to accurately predict Pu(IV) sorption to montmorillonite, the model required inclusion of ion exchange. The objective of this work is to measure the sorption of Pu(IV) and Pu(V) to silica, gibbsite, and smectite (montmorillonite). Aluminosilicate minerals are ubiquitous at the Nevada National Security Site and improving our understanding of Pu sorption to aluminosilicates (smectite clays in particular) is essential to the accurate prediction of Pu transport rates. These data will improve the mechanistic approach for modeling the hydrologic source term (HST) and provide sorption Kd parameters for use in CAU models. In both alluvium and tuff, aluminosilicates have been found to play a dominant role in the radionuclide retardation because their abundance is typically more than an order of magnitude greater than other potential sorbing minerals such as iron and manganese oxides (e.g. Vaniman et al., 1996). The sorption database used in recent HST models (Carle et al., 2006

  11. Validation of water sorption-based clay prediction models for calcareous soils

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Razzaghi, Fatemeh; Moosavi, Ali

    2017-01-01

    . The low organic carbon content of the soils and the low fraction of low-activity clay minerals like kaolinite suggested that the clay content under-predictions were due to large CaCO3 contents. Thus, for such water-sorption based models to work accurately for calcareous soils, a correction factor......Soil particle size distribution (PSD), particularly the active clay fraction, mediates soil engineering, agronomic and environmental functions. The tedious and costly nature of traditional methods of determining PSD prompted the development of water sorption-based models for determining the clay...... fraction. The applicability of such models to semi-arid soils with significant amounts of calcium carbonate and/or gypsum is unknown. The objective of this study was to validate three water sorption-based clay prediction models for 30 calcareous soils from Iran and identify the effect of CaCO3...

  12. Surface complexation modelling: Experiments on the sorption of nickel on quartz

    International Nuclear Information System (INIS)

    Puukko, E.; Hakanen, M.

    1995-10-01

    Assessing the safety of a final repository for nuclear wastes requires knowledge concerning the way in which the radionuclides released are retarded in the geosphere. The aim of the work is to aquire knowledge of empirical methods repeating the experiments on the sorption of nickel on quartz described in the reports published by the British Geological Survey (BGS). The experimental results were modelled with computer models at the Technical Research Centre of Finland (VTT Chemical Technology). The results showed that the experimental knowledge of the sorption of Ni on quartz have been acheved by repeating the experiments of BGS. Experiments made with the two quartz types, Min-U-Sil 5 (MUS) and Nilsiae, showed the difference in sorption of Ni in the low ionic strength solution (0.001 M NaNO 3 ). The sorption of Ni on MUS was higher than predicted by the Surface Complexation Model (SCM). The phenomenon was also observed by the BGS, and may be due to the different amounts of inpurities in the MUS and in the NLS. In other respects, the results of the sorption experiments fitted quite well with those predicted by the SCM model. (8 refs., 8 figs., 11 tabs.)

  13. Effect of glutamic acid on copper sorption onto kaolinite - Batch experiments and surface complexation modeling.

    Science.gov (United States)

    Karimzadeh, Lotfollah; Barthen, Robert; Stockmann, Madlen; Gruendig, Marion; Franke, Karsten; Lippmann-Pipke, Johanna

    2017-07-01

    High carbonate content of the European Kupferschiefer ore deposits is a challenge for acid copper leaching (pH ≤ 2). Therefore investigating the mobility behavior of Cu(II) under conditions related to an alternative, neutrophil biohydrometallurgical Cu(II) leaching approach is of interest. As glutamic acid (Glu) might be present as a component in the growth media, we studied its effects on the adsorption of Cu(II) onto kaolinite. The binary and ternary batch sorption measurements of Cu(II) and Glu onto kaolinite were performed in the presence of 10 mM NaClO 4 as background electrolyte and at a pH range from 4 to 9. Sorption experiments were modeled by the charge-distribution multi-site ion complexation (CD-MUSIC) model by using single sorption site (≡SOH) and monodentate surface complexation reactions. Glu sorption on kaolinite is weak (kaolinite mimics the Freundlich model. The proposed CD-MUSIC model provides a close fit to the experimental data and predicts the sorption of Cu(II), Cu(II)-Glu and Glu onto kaolinite as well as the effect of Glu on Cu(II) mobility. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. The conceptual model of organization social responsibility

    OpenAIRE

    LUO, Lan; WEI, Jingfu

    2014-01-01

    With the developing of the research of CSR, people more and more deeply noticethat the corporate should take responsibility. Whether other organizations besides corporatesshould not take responsibilities beyond their field? This paper puts forward theconcept of organization social responsibility on the basis of the concept of corporate socialresponsibility and other theories. And the conceptual models are built based on theconception, introducing the OSR from three angles: the types of organi...

  15. Optimization of isotherm models for pesticide sorption on biopolymer-nanoclay composite by error analysis.

    Science.gov (United States)

    Narayanan, Neethu; Gupta, Suman; Gajbhiye, V T; Manjaiah, K M

    2017-04-01

    A carboxy methyl cellulose-nano organoclay (nano montmorillonite modified with 35-45 wt % dimethyl dialkyl (C 14 -C 18 ) amine (DMDA)) composite was prepared by solution intercalation method. The prepared composite was characterized by infrared spectroscopy (FTIR), X-Ray diffraction spectroscopy (XRD) and scanning electron microscopy (SEM). The composite was utilized for its pesticide sorption efficiency for atrazine, imidacloprid and thiamethoxam. The sorption data was fitted into Langmuir and Freundlich isotherms using linear and non linear methods. The linear regression method suggested best fitting of sorption data into Type II Langmuir and Freundlich isotherms. In order to avoid the bias resulting from linearization, seven different error parameters were also analyzed by non linear regression method. The non linear error analysis suggested that the sorption data fitted well into Langmuir model rather than in Freundlich model. The maximum sorption capacity, Q 0 (μg/g) was given by imidacloprid (2000) followed by thiamethoxam (1667) and atrazine (1429). The study suggests that the degree of determination of linear regression alone cannot be used for comparing the best fitting of Langmuir and Freundlich models and non-linear error analysis needs to be done to avoid inaccurate results. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. A two-phase moisture transport model accounting for sorption hysteresis in layered porous building constructions

    DEFF Research Database (Denmark)

    Johannesson, Björn; Janz, Mårten

    2009-01-01

    and exhibits different transport properties. A successful model of such a case may shred light on the performance of different constructions with regards to, for example, mould growth and freeze thaw damages. For this purpose a model has been developed which is based on a two phase flow, vapor and liquid water......, with account also to sorption hysteresis. The different materials in the considered layered construction are assigned different properties, i.e. vapor and liquid water diffusivities and boundary (wetting and drying) sorption curves. Further, the scanning behavior between wetting and drying boundary curves...

  17. Sorption of phosphate onto calcite; results from batch experiments and surface complexation modeling

    DEFF Research Database (Denmark)

    Sø, Helle Ugilt; Postma, Dieke; Jakobsen, Rasmus

    2011-01-01

    of a high degree of super-saturation with respect to hydroxyapatite (SIHAP⩽7.83). The amount of phosphate adsorbed varied with the solution composition, in particular, adsorption increases as the CO32- activity decreases (at constant pH) and as pH increases (at constant CO32- activity). The primary effect....... Generally the model captures the variation in phosphate adsorption onto calcite as a function of solution composition, though it was necessary to include two types of sorption sites (strong and weak) in the model to reproduce the convex shape of the sorption isotherms....

  18. A conceptual model of political market orientation

    DEFF Research Database (Denmark)

    Ormrod, Robert P.

    2005-01-01

    . The remaining four constructs are attitudinal, designed to capture the awareness of members to the activities and importance of stakeholder groups in society, both internal and external to the organisation. The model not only allows the level of a party's political market orientation to be assessed, but also......This article proposes eight constructs of a conceptual model of political market orientation, taking inspiration from the business and political marketing literature. Four of the constructs are 'behavioural' in that they aim to describe the process of how information flows through the organisation...

  19. Modalities for an Allegorical Conceptual Data Model

    Directory of Open Access Journals (Sweden)

    Bartosz Zieliński

    2014-05-01

    Full Text Available Allegories are enriched categories generalizing a category of sets and binary relations. In this paper, we extend a new, recently-introduced conceptual data model based on allegories by adding support for modal operators and developing a modal interpretation of the model in any allegory satisfying certain additional (but natural axioms. The possibility of using different allegories allows us to transparently use alternative logical frameworks, such as fuzzy relations. Mathematically, our work demonstrates how to enrich with modal operators and to give a many world semantics to an abstract algebraic logic framework. We also give some examples of applications of the modal extension.

  20. Summarization of clinical information: a conceptual model.

    Science.gov (United States)

    Feblowitz, Joshua C; Wright, Adam; Singh, Hardeep; Samal, Lipika; Sittig, Dean F

    2011-08-01

    To provide high-quality and safe care, clinicians must be able to optimally collect, distill, and interpret patient information. Despite advances in text summarization, only limited research exists on clinical summarization, the complex and heterogeneous process of gathering, organizing and presenting patient data in various forms. To develop a conceptual model for describing and understanding clinical summarization in both computer-independent and computer-supported clinical tasks. Based on extensive literature review and clinical input, we developed a conceptual model of clinical summarization to lay the foundation for future research on clinician workflow and automated summarization using electronic health records (EHRs). Our model identifies five distinct stages of clinical summarization: (1) Aggregation, (2) Organization, (3) Reduction and/or Transformation, (4) Interpretation and (5) Synthesis (AORTIS). The AORTIS model describes the creation of complex, task-specific clinical summaries and provides a framework for clinical workflow analysis and directed research on test results review, clinical documentation and medical decision-making. We describe a hypothetical case study to illustrate the application of this model in the primary care setting. Both practicing physicians and clinical informaticians need a structured method of developing, studying and evaluating clinical summaries in support of a wide range of clinical tasks. Our proposed model of clinical summarization provides a potential pathway to advance knowledge in this area and highlights directions for further research. Copyright © 2011 Elsevier Inc. All rights reserved.

  1. Evaluation of a Generic Multisurface Sorption Model for Inorganic Soil Contaminants

    NARCIS (Netherlands)

    Dijkstra, J.J.; Meeussen, J.C.L.; Comans, R.N.J.

    2009-01-01

    The performance of a multisurface sorption model approach, composed of well-accepted surface complexation models in combination with published “generic” parameter sets, is evaluated for its possible use in risk assessment. For that purpose, the leaching of a broad range of potential soil

  2. Markov models and the ensemble Kalman filter for estimation of sorption rates.

    Energy Technology Data Exchange (ETDEWEB)

    Vugrin, Eric D.; McKenna, Sean Andrew (Sandia National Laboratories, Albuquerque, NM); Vugrin, Kay White

    2007-09-01

    Non-equilibrium sorption of contaminants in ground water systems is examined from the perspective of sorption rate estimation. A previously developed Markov transition probability model for solute transport is used in conjunction with a new conditional probability-based model of the sorption and desorption rates based on breakthrough curve data. Two models for prediction of spatially varying sorption and desorption rates along a one-dimensional streamline are developed. These models are a Markov model that utilizes conditional probabilities to determine the rates and an ensemble Kalman filter (EnKF) applied to the conditional probability method. Both approaches rely on a previously developed Markov-model of mass transfer, and both models assimilate the observed concentration data into the rate estimation at each observation time. Initial values of the rates are perturbed from the true values to form ensembles of rates and the ability of both estimation approaches to recover the true rates is examined over three different sets of perturbations. The models accurately estimate the rates when the mean of the perturbations are zero, the unbiased case. For the cases containing some bias, addition of the ensemble Kalman filter is shown to improve accuracy of the rate estimation by as much as an order of magnitude.

  3. Conceptual Model of Dynamic Geographic Environment

    Directory of Open Access Journals (Sweden)

    Martínez-Rosales Miguel Alejandro

    2014-04-01

    Full Text Available In geographic environments, there are many and different types of geographic entities such as automobiles, trees, persons, buildings, storms, hurricanes, etc. These entities can be classified into two groups: geographic objects and geographic phenomena. By its nature, a geographic environment is dynamic, thus, it’s static modeling is not sufficient. Considering the dynamics of geographic environment, a new type of geographic entity called event is introduced. The primary target is a modeling of geographic environment as an event sequence, because in this case the semantic relations are much richer than in the case of static modeling. In this work, the conceptualization of this model is proposed. It is based on the idea to process each entity apart instead of processing the environment as a whole. After that, the so called history of each entity and its spatial relations to other entities are defined to describe the whole environment. The main goal is to model systems at a conceptual level that make use of spatial and temporal information, so that later it can serve as the semantic engine for such systems.

  4. Achievements and Problems of Conceptual Modelling

    Science.gov (United States)

    Thalheim, Bernhard

    Database and information systems technology has substantially changed. Nowadays, content management systems, (information-intensive) web services, collaborating systems, internet databases, OLAP databases etc. have become buzzwords. At the same time, object-relational technology has gained the maturity for being widely applied. Conceptual modelling has not (yet) covered all these novel topics. It has been concentrated for more than two decades around specification of structures. Meanwhile, functionality, interactivity and distribution must be included into conceptual modelling of information systems. Also, some of the open problems that have been already discussed in 1987 [15, 16] still remain to be open. At the same time, novel models such as object-relational models or XML-based models have been developed. They did not overcome all the problems but have been sharpening and extending the variety of open problems. The open problem presented are given for classical areas of database research, i.e., structuring and functionality. The entire are of distribution and interaction is currently an area of very intensive research.

  5. Modelling the fate of ciprofloxacin in activated sludge systems - The relevance of the sorption process

    DEFF Research Database (Denmark)

    Polesel, Fabio; Lehnberg, Kai; Dott, Wolfgang

    of ciprofloxacin in a full-scale activated sludge system. Sorption was described by linear kinetics and, in an extended version of ASM-X, using a Freundlich-based submodel. In the latter case, Freundlich parameter values estimated from the batch experiments were used for model calibration. The prediction accuracy......H conditions, rather than reduced salt dosing, can be responsible for the decrease of ciprofloxacin sorption in the full-scale WWTP. The most accurate predictions were obtained for Freundlich parameter values of K=0.01 (μg(1-1/n) L1/n mg-1) and 1/n=1.33. A pH increase was therefore estimated to cause reduced...... sorption in the anoxic and the aerobic reactors, possibly being a consequence of the lower sorption extent exhibited by the anionic ciprofloxacin species. Comparable prediction accuracy was obtained using linear sorption. A 20-fold decrease of the anoxic and aerobic KD values (1.1 and 0.42 L gXSS-1 under...

  6. Europium sorption on zirconia at elevated temperatures: experimental study and modeling

    International Nuclear Information System (INIS)

    Eglizaud, N.; Catalette, H.

    2005-01-01

    Full text of publication follows: Direct disposal of spent nuclear fuel in deep underground repository is being considered by several countries. The waste package maintains an elevated temperature for thousands of years. As sorption is one of the main phenomenon limiting the dispersion of radionuclides in the environment, it has to be studied at elevated temperatures. Zirconia is an oxide produced by cladding oxidation which is suspected in the near field of a nuclear repository. It then could possibly be in contact with waste elements as Europium (III), the sorption of which is therefore studied on zirconia. Experiments were performed by the batch method at a solid/liquid ratio of 10 g.L-1. The sorption edges were recorded in the pH-range from 2 to 10 at 2.10 -5 mol.L -1 Eu(NO 3 ) 3 (I = 0.1 mol.L -1 KNO 3 ). An over-pressure device in an autoclave with an incorporated filtering system allowed the experiments, carbonate free, at 25 deg. C, 50 deg. C, 80 deg. C, 120 deg. C and 150 deg. C and in situ pH measurements. Filtrates were analyzed by the ICP-AES method. Sorption isotherms show an increase in the sorption phenomenon when the temperature raises. The half sorption pH decreases from 7 at 25 deg. C to 3,6 at 150 deg. C. The distribution coefficients that were obtained at elevated temperatures enriched the databases of integrated performance assessment codes. Raw data were modeled with the surface complexation theory using the double layer model (DLM). Several possible surface complexes were examined and discussed, taking into account aqueous hydrolyzed and precipitated species of Europium. A good agreement between experimental values and modeled isotherms was found at all studied temperatures. Results were consistent with a bidentate complex formed by Europium (III) on the zirconia surface. Associated formation constants were then determined with the geochemical computer code CHESS. (authors)

  7. Conceptual Modelling of Complex Production Systems

    Directory of Open Access Journals (Sweden)

    Nenad Perši

    2008-12-01

    Full Text Available Complex system dynamics, structure and behaviour performances call for a wide range of methods, algorithms and tools to reach a model capable of finding optimal performing parameters. In the modelling process, it is up to the analyst to select the appropriate combination of methods, algorithms and tools to express significant system performances. Such a methodology for designing complex systems should be based upon conceptual modelling to perform a sensitive analysis of different system levels and views, allowing system representations for developing computer models.Complex systems, such as business systems with a continuous-discrete production process, require a well organised supply chain highly reactive to production assortment changes. Aligning two different production components distinctive in their behaviour is especially delicate at the production parameters transition point. Such system performances require distinctive designing methods that can follow the double nature of the production process behaviour in accordance with their entities dynamics caused by assortment changes. Consequently, such systems need different conceptual presentations for their purpose to be realized from different views and aspects.

  8. Uranium(VI) sorption on iron oxides in Hanford Site sediment: Application of a surface complexation model

    International Nuclear Information System (INIS)

    Um, Wooyong; Serne, R. Jeffrey; Brown, Christopher F.; Rod, Kenton A.

    2008-01-01

    Sorption of U(VI) on Hanford fine sand (HFS) with varying Fe-oxide (especially ferrihydrite) contents showed that U(VI) sorption increased with the incremental addition of synthetic ferrihydrite into HFS, consistent with ferrihydrite being one of the most reactive U(VI) sorbents present in natural sediments. Surface complexation model (SCM) calculations for U(VI) sorption, using only U(VI) surface-reaction constants obtained from U(VI) sorption data on freshly synthesized ferrihydrite at different pHs, were similar to the measured U(VI) sorption results on pure synthetic ferrihydrite and on HFS with high contents of ferrihydrite (5 wt%) added. However, the SCM prediction using only U(VI) sorption reactions and constants for synthetic ferrihydrite overestimated U(VI) sorption on the natural HFS or HFS with addition of low amounts of added ferrihydrite (1 wt% added). Over-predicted U(VI) sorption was attributed to reduced reactivity of natural ferrihydrite present in Hanford Site sediments, compared to freshly prepared synthetic ferrihydrite. Even though the SCM general composite (GC) approach is considered to be a semi-quantitative estimation technique for contaminant sorption, which requires systematic experimental data on the sorbent-sorbate system being studied to obtain credible SCM parameters, the general composite SCM model was still found to be a useful technique for describing U(VI) sorption on natural sediments. Based on U(VI) batch sorption results, two simple U(VI) monodentate surface species, SO U O 2 HCO 3 and SO U O 2 OH on ferrihydrite and phyllosillicate in HFS, respectively, can be successfully used to describe U(VI) sorption onto Hanford Site sediment contacting varying geochemical solutions

  9. Conceptual Frameworks in the Doctoral Research Process: A Pedagogical Model

    Science.gov (United States)

    Berman, Jeanette; Smyth, Robyn

    2015-01-01

    This paper contributes to consideration of the role of conceptual frameworks in the doctoral research process. Through reflection on the two authors' own conceptual frameworks for their doctoral studies, a pedagogical model has been developed. The model posits the development of a conceptual framework as a core element of the doctoral…

  10. A Structural Equation Model of Conceptual Change in Physics

    Science.gov (United States)

    Taasoobshirazi, Gita; Sinatra, Gale M.

    2011-01-01

    A model of conceptual change in physics was tested on introductory-level, college physics students. Structural equation modeling was used to test hypothesized relationships among variables linked to conceptual change in physics including an approach goal orientation, need for cognition, motivation, and course grade. Conceptual change in physics…

  11. Actinides sorption onto hematite. Experimental data, surface complexation modeling and linear free energy relationship

    Energy Technology Data Exchange (ETDEWEB)

    Romanchuk, Anna Y.; Kalmykov, Stephan N. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Chemistry

    2014-07-01

    The sorption of actinides in different valence states - Am(III), Th(IV), Np(V) and U(VI) onto hematite have been revisited with the special emphasis on the equilibrium constants of formation of surface species. The experimental sorption data have been treated using surface complexation modeling from which the set of new values of equilibrium constants were obtained. Formation of inner sphere monodentate surface species adequately describes the pH-sorption edges for actinide ions indicative the ionic electrostatic nature of bonding with small or no covalency contribution. The linear free energy relationship representing the correlation between the hydrolysis constants and surface complexation constants has been developed for various cations including K(I), Li(I), Na(I), Ag(I), Tl(I), Sr(II), Cu(II), Co(II), La(III), Eu(III), Ga(III), Am(III), Th(IV), Np(V), U(VI). (orig.)

  12. Reactive transport modeling at uranium in situ recovery sites: uncertainties in uranium sorption on iron hydroxides

    Science.gov (United States)

    Johnson, Raymond H.; Tutu, Hlanganani; Brown, Adrian; Figueroa, Linda; Wolkersdorfer, Christian

    2013-01-01

    Geochemical changes that can occur down gradient from uranium in situ recovery (ISR) sites are important for various stakeholders to understand when evaluating potential effects on surrounding groundwater quality. If down gradient solid-phase material consists of sandstone with iron hydroxide coatings (no pyrite or organic carbon), sorption of uranium on iron hydroxides can control uranium mobility. Using one-dimensional reactive transport models with PHREEQC, two different geochemical databases, and various geochemical parameters, the uncertainties in uranium sorption on iron hydroxides are evaluated, because these oxidized zones create a greater risk for future uranium transport than fully reduced zones where uranium generally precipitates.

  13. A conceptual model of referee efficacy

    Directory of Open Access Journals (Sweden)

    Félix eGuillén

    2011-02-01

    Full Text Available This paper presents a conceptual model of referee efficacy, defines the concept, proposes sources of referee specific efficacy information, and suggests consequences of having high or low referee efficacy. Referee efficacy is defined as the extent to which referees believe they have the capacity to perform successfully in their job. Referee efficacy beliefs are hypothesized to be influenced by mastery experiences, referee knowledge/education, support from significant others, physical/mental preparedness, environmental comfort, and perceived anxiety. In turn, referee efficacy beliefs are hypothesized to influence referee performance, referee stress, athlete rule violations, athlete satisfaction, and co-referee satisfaction.

  14. Sierra toolkit computational mesh conceptual model

    International Nuclear Information System (INIS)

    Baur, David G.; Edwards, Harold Carter; Cochran, William K.; Williams, Alan B.; Sjaardema, Gregory D.

    2010-01-01

    The Sierra Toolkit computational mesh is a software library intended to support massively parallel multi-physics computations on dynamically changing unstructured meshes. This domain of intended use is inherently complex due to distributed memory parallelism, parallel scalability, heterogeneity of physics, heterogeneous discretization of an unstructured mesh, and runtime adaptation of the mesh. Management of this inherent complexity begins with a conceptual analysis and modeling of this domain of intended use; i.e., development of a domain model. The Sierra Toolkit computational mesh software library is designed and implemented based upon this domain model. Software developers using, maintaining, or extending the Sierra Toolkit computational mesh library must be familiar with the concepts/domain model presented in this report.

  15. Significance of kinetics for sorption on inorganic colloids: modeling and experiment interpretation issues.

    Science.gov (United States)

    Painter, S; Cvetkovic, V; Pickett, D; Turner, D R

    2002-12-15

    A two-site kinetic model for solute sorption on inorganic colloids is developed. The model quantifies linear first-order sorption on two types of sites ("fast" and "slow") characterized by two pairs of rates (forward and reverse). We use the model to explore data requirements for long-term predictive calculations of colloid-facilitated transport and to evaluate laboratory kinetic sorption data of Lu et al.. Five batch sorption data sets are considered with plutonium as the tracer and montmorillonite, hematite, silica, and smectite as colloids. Using asymptotic results applicable on the time scale of limited duration experiments, a robust estimation procedure is developed for the fast-site partitioning coefficient K(C) and the slow forward rate alpha. The estimated range of K(C) is 1.1-76 L/g, and the range for alpha is 0.0017-0.02 1/h. The fast reverse rate k(r) is estimated in the range 0.012-0.1 1/h. Comparison of one-site and two-site sorption interpretations reveals the difficulty in discriminating between the two models for montmorillonite and to a lesser extent for hematite. For silica and smectite, the two-site model clearly provides a better representation of the data as compared with a single site model. Kinetic data for silica are available for different colloid concentrations (0.2 g/L and 1 g/L). For the range of experimental conditions considered, alpha appears to be independent of colloid concentration.

  16. Models for the sorption of volatile organic compounds by diesel soot and atmospheric aerosols.

    Science.gov (United States)

    Atapattu, Sanka N; Poole, Colin F

    2009-04-01

    The solvation parameter model is used to characterize interactions responsible for the sorption of varied organic compounds by diesel soot and atmospheric aerosols at 15 degrees C and 50% relative humidity. Individual models are obtained for eight aerosol samples characterized as urban, suburban, rural and coastal. Combining the individual aerosol models resulted in a general aerosol model with only a minor loss of modeling power for alkanecarboxylic acids and low-molecular weight alcohols compared with the individual models. A second group of compounds identified as weak nitrogen-containing bases were consistent outliers to all models most likely due to participation in ion-exchange interactions not considered by the models. The diesel soot and atmospheric aerosols exhibit similar characteristics with respect to their sorption interactions although differences in relative magnitude allow the two particle types to be easily distinguished. Sorption interactions are favored by strong dispersion interactions for both particle types. Of note is the strong hydrogen-bond basicity and relatively weak hydrogen-bond acidity of these materials. The particles are quite dipolar/polarizable and slightly electron lone pair repulsive. The sorption properties of the atmospheric aerosols are influenced by the relative humidity, in particular, the aerosols become significantly more hydrogen-bond acidic at high relative humidity most likely due to incorporation of increasing amounts of condensed or film water in the aerosol phase. Dividing the data into training and test sets suggests that the proposed models are capable of estimating distribution constants (log K) to about 0.20 log units for diesel soot (n = 84) and 0.14 log units for the general atmospheric aerosol model (n = 385) where n indicates the number of compounds included in the model.

  17. [The concepts and conceptual models of psychopharmacology].

    Science.gov (United States)

    Gor'kov, V A

    1996-01-01

    The present approaches to the testing and use of drugs, psychotropic ones in particular, are characterized by inadequate efficiency: the ratio of agents successfully undergone preclinical, clinical, and postclinical tests is 100:5:1 and in clinical psychopharmacotherapy, the proportion of drug-resistant patients and the incidence of side effects are rather high. The groundless supposition that interspecies- and intraspecies-specific sensitivity to drugs is equal may explain this notion, which contradicts the concept of the biochemical stability of species and to the principle of molecular economy in species-specific ratios. To enhance the efficiency of tests and pharmacotherapy, it is suggested that the existing conceptual model "concentration-effect" should be replaced by the extended one "sensitivity-concentration-effect" as it is more scientifically substantiated. Increases in the efficiency of psychopharmacotherapy may be, among other things, reached by individually predicting the most effective psychotropic agents with clinical, paraclinical, pharmacokinetic, and other predictors.

  18. Front-end conceptual platform modeling

    DEFF Research Database (Denmark)

    Guðlaugsson, Tómas Vignir; Ravn, Poul Martin; Mortensen, Niels Henrik

    2014-01-01

    Platform thinking has been the subject of investigation and deployment in many projects in both academia and industry. Most contributions involve the restructuring of product programs, and only a few support front-end development of a new platform in parallel with technology development. This con......Platform thinking has been the subject of investigation and deployment in many projects in both academia and industry. Most contributions involve the restructuring of product programs, and only a few support front-end development of a new platform in parallel with technology development....... The conclusion is that the Conceptual Product Platform model supports stakeholders in achieving an overview of the development tasks and communicating these across multidisciplinary development teams, as well as making decisions on the contents of the platform and providing a link between technical solutions...

  19. A unifying conceptual model of entrepreneurial management

    DEFF Research Database (Denmark)

    Senderovitz, Martin

    of entrepreneurial management? The paper builts on the seminal work by Stevenson (1983, 1990) and proposes a discussion and elaboration of the understanding and definition of entrepreneurial management in terms of the relationship between entrepreneurial opportunities and firm resources.......This article offers a systematic analysis and synthesis of the area of entrepreneurial management. Through a presentation of two main perspectives on entrepreneurial management and a newly developed unifying conceptual entrepreneurial management model, the paper discusses a number of theoretical...... disagreements, managerial dilemmas and paradoxes. On the basis of the findings and conclusions of the study, the article contributes with and overview of the entrepreneurial management field, and offers an answer to the overall research question: What constitutes the most essential areas and challenges...

  20. Development of conceptual groundwater flow model for Pali Area ...

    African Journals Online (AJOL)

    The study also extensively uses GIS for preprocessing of hydrological, hydrogeological and geological data. In our view, the methodology presented here provides better tools for building a conceptual model for tackling groundwater modeling problems. Keywords: Groundwater flow model, conceptual model, groundwater ...

  1. Revealing chemophoric sites in organophosphorus insecticides through the MIA-QSPR modeling of soil sorption data.

    Science.gov (United States)

    Daré, Joyce K; Silva, Cristina F; Freitas, Matheus P

    2017-10-01

    Soil sorption of insecticides employed in agriculture is an important parameter to probe the environmental fate of organic chemicals. Therefore, methods for the prediction of soil sorption of new agrochemical candidates, as well as for the rationalization of the molecular characteristics responsible for a given sorption profile, are extremely beneficial for the environment. A quantitative structure-property relationship method based on chemical structure images as molecular descriptors provided a reliable model for the soil sorption prediction of 24 widely used organophosphorus insecticides. By means of contour maps obtained from the partial least squares regression coefficients and the variable importance in projection scores, key molecular moieties were targeted for possible structural modification, in order to obtain novel and more environmentally friendly insecticide candidates. The image-based descriptors applied encode molecular arrangement, atoms connectivity, groups size, and polarity; consequently, the findings in this work cannot be achieved by a simple relationship with hydrophobicity, usually described by the octanol-water partition coefficient. Copyright © 2017 Elsevier Inc. All rights reserved.

  2. Modeling the mechanism involved during the sorption of methylene blue onto fly ash.

    Science.gov (United States)

    Kumar, K Vasanth; Ramamurthi, V; Sivanesan, S

    2005-04-01

    Batch sorption experiments were carried out to remove methylene blue from its aqueous solutions using fly ash as an adsorbent. Operating variables studied were initial dye concentration, fly ash mass, pH, and contact time. Maximum color removal was observed at a basic pH of 8. Equilibrium data were represented well by a Langmuir isotherm equation with a monolayer sorption capacity of 5.718 mg/g. Sorption data were fitted to both Lagergren first-order and pseudo-second-order kinetic models and the data were found to follow pseudo-second-order kinetics. Rate constants at different initial concentrations were estimated. The process mechanism was found to be complex, consisting of both surface adsorption and pore diffusion. The effective diffusion parameter D(i) values were estimated at different initial concentrations and the average value was determined to be 2.063 x 10(-9)cm2/s. Analysis of sorption data using a Boyd plot confirms the particle diffusion as the rate-limiting step for the dye concentration ranges studied in the present investigation (20 to 60 mg/L).

  3. A conceptual holding model for veterinary applications

    Directory of Open Access Journals (Sweden)

    Nicola Ferrè

    2014-05-01

    Full Text Available Spatial references are required when geographical information systems (GIS are used for the collection, storage and management of data. In the veterinary domain, the spatial component of a holding (of animals is usually defined by coordinates, and no other relevant information needs to be interpreted or used for manipulation of the data in the GIS environment provided. Users trying to integrate or reuse spatial data organised in such a way, frequently face the problem of data incompatibility and inconsistency. The root of the problem lies in differences with respect to syntax as well as variations in the semantic, spatial and temporal representations of the geographic features. To overcome these problems and to facilitate the inter-operability of different GIS, spatial data must be defined according to a “schema” that includes the definition, acquisition, analysis, access, presentation and transfer of such data between different users and systems. We propose an application “schema” of holdings for GIS applications in the veterinary domain according to the European directive framework (directive 2007/2/EC - INSPIRE. The conceptual model put forward has been developed at two specific levels to produce the essential and the abstract model, respectively. The former establishes the conceptual linkage of the system design to the real world, while the latter describes how the system or software works. The result is an application “schema” that formalises and unifies the information-theoretic foundations of how to spatially represent a holding in order to ensure straightforward information-sharing within the veterinary community.

  4. Sorption isotherms modeling approach of rice-based instant soup mix stored under controlled temperature and humidity

    Directory of Open Access Journals (Sweden)

    Yogender Singh

    2015-12-01

    Full Text Available Moisture sorption isotherms of rice-based instant soup mix at temperature range 15–45°C and relative humidity from 0.11 to 0.86 were determined using the standard gravimetric static method. The experimental sorption curves were fitted by five equations: Chung-Pfost, GAB, Henderson, Kuhn, and Oswin. The sorption isotherms of soup mix decreased with increasing temperature, exhibited type II behavior according to BET classification. The GAB, Henderson, Kuhn, and Oswin models were found to be the most suitable for describing the sorption curves. The isosteric heat of sorption of water was determined from the equilibrium data at different temperatures. It decreased as moisture content increased and was found to be a polynomial function of moisture content. The study has provided information and data useful in large-scale commercial production of soup and have great importance to combat the problem of protein-energy malnutrition in underdeveloped and developing countries.

  5. Creating a Universe, a Conceptual Model

    Directory of Open Access Journals (Sweden)

    James R. Johnson

    2016-10-01

    Full Text Available Space is something. Space inherently contains laws of nature: universal rules (mathematics, space dimensions, types of forces, types of fields, and particle species, laws (relativity, quantum mechanics, thermodynamics, and electromagnetism and symmetries (Lorentz, Gauge, and symmetry breaking. We have significant knowledge about these laws of nature because all our scientific theories assume their presence. Their existence is critical for developing either a unique theory of our universe or more speculative multiverse theories. Scientists generally ignore the laws of nature because they “are what they are” and because visualizing different laws of nature challenges the imagination. This article defines a conceptual model separating space (laws of nature from the universe’s energy source (initial conditions and expansion (big bang. By considering the ramifications of changing the laws of nature, initial condition parameters, and two variables in the big bang theory, the model demonstrates that traditional fine tuning is not the whole story when creating a universe. Supporting the model, space and “nothing” are related to the laws of nature, mathematics and multiverse possibilities. Speculation on the beginning of time completes the model.

  6. A Conceptual Modeling Approach for OLAP Personalization

    Science.gov (United States)

    Garrigós, Irene; Pardillo, Jesús; Mazón, Jose-Norberto; Trujillo, Juan

    Data warehouses rely on multidimensional models in order to provide decision makers with appropriate structures to intuitively analyze data with OLAP technologies. However, data warehouses may be potentially large and multidimensional structures become increasingly complex to be understood at a glance. Even if a departmental data warehouse (also known as data mart) is used, these structures would be also too complex. As a consequence, acquiring the required information is more costly than expected and decision makers using OLAP tools may get frustrated. In this context, current approaches for data warehouse design are focused on deriving a unique OLAP schema for all analysts from their previously stated information requirements, which is not enough to lighten the complexity of the decision making process. To overcome this drawback, we argue for personalizing multidimensional models for OLAP technologies according to the continuously changing user characteristics, context, requirements and behaviour. In this paper, we present a novel approach to personalizing OLAP systems at the conceptual level based on the underlying multidimensional model of the data warehouse, a user model and a set of personalization rules. The great advantage of our approach is that a personalized OLAP schema is provided for each decision maker contributing to better satisfy their specific analysis needs. Finally, we show the applicability of our approach through a sample scenario based on our CASE tool for data warehouse development.

  7. Guiding principles for conceptual model creation in manufacturing simulation

    NARCIS (Netherlands)

    Van der Zee, Durk-Jouke; Van der Vorst, Jack G. A. J.; Henderson, S.G.; Biller, B.; Hsieh, M.-H.; Shortle, J.; Tew, J.D.; Barton, R.R.

    2007-01-01

    Conceptual models serve as abstractions of user's perceptions of a system. The choice and detailing of these abstractions are key to model use and understanding for analyst and project stakeholders. In this article we consider guidance for the analyst in his creative job of conceptual modeling. More

  8. Effect of glutamic acid on copper sorption onto kaolinite. Batch experiments and surface complexation modeling

    International Nuclear Information System (INIS)

    Karimzadeh, Lotfallah; Barthen, Robert; Gruendig, Marion; Franke, Karsten; Lippmann-Pipke, Johanna; Stockmann, Madlen

    2017-01-01

    In this work, we study the mobility behavior of Cu(II) under conditions related to an alternative, neutrophile biohydrometallurgical Cu(II) leaching approach. Sorption of copper onto kaolinite influenced by glutamic acid (Glu) was investigated in the presence of 0.01 M NaClO 4 by means of binary and ternary batch adsorption measurements over a pH range of 4 to 9 and surface complexation modeling.

  9. Effect of glutamic acid on copper sorption onto kaolinite. Batch experiments and surface complexation modeling

    Energy Technology Data Exchange (ETDEWEB)

    Karimzadeh, Lotfallah; Barthen, Robert; Gruendig, Marion; Franke, Karsten; Lippmann-Pipke, Johanna [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Reactive Transport; Stockmann, Madlen [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Surface Processes

    2017-06-01

    In this work, we study the mobility behavior of Cu(II) under conditions related to an alternative, neutrophile biohydrometallurgical Cu(II) leaching approach. Sorption of copper onto kaolinite influenced by glutamic acid (Glu) was investigated in the presence of 0.01 M NaClO{sub 4} by means of binary and ternary batch adsorption measurements over a pH range of 4 to 9 and surface complexation modeling.

  10. Conceptual models of the wind-driven and thermohaline circulation

    NARCIS (Netherlands)

    Drijfhout, S.S.; Marshall, D.P.; Dijkstra, H.A.

    2013-01-01

    Conceptual models are a vital tool for understanding the processes that maintain the global ocean circulation, both in nature and in complex numerical ocean models. In this chapter we provide a broad overview of our conceptual understanding of the wind-driven circulation, the thermohaline

  11. On the general ontological foundations of conceptual modeling

    NARCIS (Netherlands)

    Guizzardi, G.; Herre, Heinrich; Wagner, Gerd; Spaccapietra, Stefano; March, Salvatore T.; Kambayashi, Yahiko

    2002-01-01

    As pointed out in the pioneering work of [WSW99,EW01], an upper level ontology allows to evaluate the ontological correctness of a conceptual model and to develop guidelines how the constructs of a conceptual modeling language should be used. In this paper we adopt the General Ontological Language

  12. Lumped conceptual hydrological model for Purna river basin, India

    Indian Academy of Sciences (India)

    Home; Journals; Sadhana; Volume 40; Issue 8 ... Conceptual hydrological NAM model; calibration; sensitivity analysis; validation; Tapi basin; Purna catchment. ... In present study, a lumped conceptual hydrological model, NAM (MIKE11), is calibrated while optimizing the runoff simulations on the basis of minimization of ...

  13. Modeling PCN-61 and PCN-66: Isostructural rht -Metal–Organic Frameworks with Distinct CO 2 Sorption Mechanisms

    KAUST Repository

    Pham, Tony

    2014-11-05

    © 2014 American Chemical Society. Simulations of CO2 sorption were performed in two members of the highly tunable rht-metal-organic framework (MOF) platform: PCN-61 and PCN-66. These MOFs differ only in the triisophthalate ligand used to synthesize the respective MOFs. In PCN-61, the center of the ligand contains a benzene ring; this ring is substituted with a triphenylamine group in PCN-66. There are two chemically distinct Cu2+ ions that comprise the copper paddlewheels, [Cu2(O2CR)4], in all rht-MOFs. One type of Cu2+ ion, denoted Cu1, projects into the truncated tetrahedral (T-Td) and truncated octahedral (T-Oh) cages, while the other Cu2+ ion, denoted Cu2, projects into the cuboctahedral (cub-Oh) cages. Electronic structure calculations revealed that, in PCN-61, the Cu2 ions have a significantly higher partial positive charge than the Cu1 ions, whereas the opposite was observed in PCN-66. The simulations revealed that the CO2 molecules sorb initially onto the Cu2+ ions that have the higher partial positive charge, i.e., the Cu2 ions in PCN-61 and the Cu1 ions in PCN-66. This was demonstrated by examining the radial distribution function, g(r), about both Cu2+ ions and the modeled structure at low loading for both MOFs. This study provided insights into how differences in the charge distributions about the copper paddlewheels between two isostructural MOFs, arising from the choice of functionality on the ligand, can lead to different CO2 binding sites at low loading and suggests a more general conceptual framework for controlling sorption through the tuning of MOF electronics.

  14. Surface-complexation models for sorption onto heterogeneous surfaces

    International Nuclear Information System (INIS)

    Harvey, K.B.

    1997-10-01

    This report provides a description of the discrete-logK spectrum model, together with a description of its derivation, and of its place in the larger context of surface-complexation modelling. The tools necessary to apply the discrete-logK spectrum model are discussed, and background information appropriate to this discussion is supplied as appendices. (author)

  15. Predicting the uptake of Cs, Co, Ni, Eu, Th and U on argillaceous rocks using sorption models for illite

    International Nuclear Information System (INIS)

    Marques Fernandes, Maria; Vér, Nóra; Baeyens, Bart

    2015-01-01

    Highlights: • Contaminant retention in argillaceous rocks controlled by sorption on clay minerals. • Cs, Ni, Co, Eu, Th and UO 2 sorption isotherm measurements on Boda and Opalinus Clay. • Boda and Opalinus Clay exhibit different mineralogies and porewater compositions. • Blind predictions using quasi-mechanistic sorption models developed for illite. • Good agreement between measurements and blind predictions. - Abstract: Reliable predictions of radiocontaminant migration are a requirement for the establishment of radioactive waste repositories. Parametrization of the necessary sorption models seems to be, however, extremely challenging given the multi-mineralic composition of the lithosphere. In this study it is shown for two argillaceous rocks – Boda and Opalinus Clay relevant for the Hungarian and Swiss repository concepts, respectively – that this task can be substantially simplified by taking into account only the most sorptive mineral fraction, namely the 2:1 clay minerals illite and illite/smectite mixed layers. Two different models were required to blind predict the sorption isotherms of Cs, Co, Ni, Eu, Th and UO 2 measured on the two clay rock samples in a synthetic porewater. Cs sorption was modelled with the generalised Cs (GCs) sorption model and the sorption of the other cations with the 2site protolysis non electrostatic surface complexation and cation exchange (2SPNE SC/CE) model. The 2SPNE SC/CE model for illite was extended with surface complexation reactions on weak sites for Co, Ni, Eu, UO 2 and on strong sites for Eu-carbonato complexes. Complementary to the sorption measurements and modelling, extended X-ray absorption fine structure (EXAFS) spectroscopy was used to probe the retention mechanism of Ni on illite, Boda and Opalinus Clay at higher loadings. The reliable blind predictions of the selected metal cations, which are representative for monovalent alkaline metals, divalent transition metals, lanthanides, and trivalent

  16. Conceptualizing Telehealth in Nursing Practice: Advancing a Conceptual Model to Fill a Virtual Gap.

    Science.gov (United States)

    Nagel, Daniel A; Penner, Jamie L

    2016-03-01

    Increasingly nurses use various telehealth technologies to deliver health care services; however, there has been a lag in research and generation of empirical knowledge to support nursing practice in this expanding field. One challenge to generating knowledge is a gap in development of a comprehensive conceptual model or theoretical framework to illustrate relationships of concepts and phenomena inherent to adoption of a broad range of telehealth technologies to holistic nursing practice. A review of the literature revealed eight published conceptual models, theoretical frameworks, or similar entities applicable to nursing practice. Many of these models focus exclusively on use of telephones and four were generated from qualitative studies, but none comprehensively reflect complexities of bridging nursing process and elements of nursing practice into use of telehealth. The purpose of this article is to present a review of existing conceptual models and frameworks, discuss predominant themes and features of these models, and present a comprehensive conceptual model for telehealth nursing practice synthesized from this literature for consideration and further development. This conceptual model illustrates characteristics of, and relationships between, dimensions of telehealth practice to guide research and knowledge development in provision of holistic person-centered care delivery to individuals by nurses through telehealth technologies. © The Author(s) 2015.

  17. Sorption Behavior of CO2 and CH4 of Glassy Polymeric Membranes and Analytical Discussion of Partial Immobilization Model

    Directory of Open Access Journals (Sweden)

    M. Mahdavian

    2007-06-01

    Full Text Available Among various reported membrane-based gas separation processes, the best explanation is generally achieved by the solution-diffusion model. The main factors in this model are the solubility and diffusivity of permeationcomponents through the membrane. The prediction of permeability and diffusivity in multicomponent gas permeation as well as the separation evaluation equilibrium and kinetic interactions requires a proper explanation of sorption and diffusion phenomena in the polymer matrix. Investigation made by various researchers in this area shows that the equilibrium interaction (sorption step plays the key role in determining diffusion and permeation in multicomponent system. Therefore, the proper description of sorption behaviour of gas mixture in the polymer is an essential task. The dual-mode sorption (Langmuir-Henry is usually used for the description of equilibrium isotherm of gases in glassy polymers based on this model; the diffusive behaviour of the system is subsequently analyzed by the partial immobilization model. In this study, the equilibrium sorption of CO2/CH4 mixture in various polymers was modelled using the experimental data available in the literature. The differences in the mechanism of adsorption for CO2 and CH4 were analyzed by considering variations in mode of sorption for each adsorbed component at different pressures. By introducing a new adsorption parameter, P50/50, (the pressure at which the portion of two modes in sorption are equal the contribution of each adsorbed component in occupying Langmuir sites was evaluated. The results indicate that the relative significance of sorption mode for each component is a function of pressure and it is different for various polymers.

  18. Conceptual and Numerical Models for UZ Flow and Transport

    International Nuclear Information System (INIS)

    Liu, H.

    2000-01-01

    The purpose of this Analysis/Model Report (AMR) is to document the conceptual and numerical models used for modeling of unsaturated zone (UZ) fluid (water and air) flow and solute transport processes. This is in accordance with ''AMR Development Plan for U0030 Conceptual and Numerical Models for Unsaturated Zone (UZ) Flow and Transport Processes, Rev 00''. The conceptual and numerical modeling approaches described in this AMR are used for models of UZ flow and transport in fractured, unsaturated rock under ambient and thermal conditions, which are documented in separate AMRs. This AMR supports the UZ Flow and Transport Process Model Report (PMR), the Near Field Environment PMR, and the following models: Calibrated Properties Model; UZ Flow Models and Submodels; Mountain-Scale Coupled Processes Model; Thermal-Hydrologic-Chemical (THC) Seepage Model; Drift Scale Test (DST) THC Model; Seepage Model for Performance Assessment (PA); and UZ Radionuclide Transport Models

  19. Measurements and modelling of Pm sorption onto TiO2 and goethite

    International Nuclear Information System (INIS)

    Jakobsson, A.M.; Albinsson, Y.; Rundberg, R.S.

    2004-01-01

    The sorption of Pm (1 x 10 -9 M) onto TiO 2 and goethite has been studied as a function of pH and ionic strength (0.01, 0.1 M NaClO 4 ) at ambient temperature under N 2 atmosphere. For both minerals studied there is no effect of the different ionic strengths and the sorption (log K a vs. pH) increases with a slope of ∝2. At the same pH sorption is lower on the more positively (or less negatively) charged goethite (pH pzc = 8.4) than on the TiO 2 (pH pzc = 6.2). A comparison to other trivalent cations sorbed on different substrates (made by extracting values from %-sorbed curves and calculating these to K a ) indicate a similar pH-dependence. The results have been fitted using a 1-pK basic stern model with FITEQL [1]. An a priori restriction was that only one sorption reaction stoichiometry at a time was to be used to keep the number of parameters as small as possible. Outersphere and mono-, bi- and tri-dentate inner-sphere complexes were fitted. For each fit the value of the capacitance was varied to find the value that provided the best fit. Two different site densities were used: 1 site/nm 2 and 2.31 sites/nm 2 . For the low site density the reaction which provides the best fit was: ≡ SOH 0.5- + Pm +3 ≡ SOHPm 2.5+ for both minerals. At the high site density the same reaction fits for TiO 2 while there are several reactions that are equivalent in the fit for goethite. (orig.)

  20. Conceptualization

    NARCIS (Netherlands)

    Scheerens, Jaap; Scheerens, Jaap

    2017-01-01

    In the second chapter a conceptual analysis of Opportunity to Learn (OTL) is given, covering also related terms, such as instructional alignment and test preparation. The OTL issue is highlighted from three educational research traditions: educational effectiveness research, curriculum research and

  1. Using Conceptual Change Theories to Model Position Concepts in Astronomy

    Science.gov (United States)

    Yang, Chih-Chiang; Hung, Jeng-Fung

    2012-01-01

    The roles of conceptual change and model building in science education are very important and have a profound and wide effect on teaching science. This study examines the change in children's position concepts after instruction, based on different conceptual change theories. Three classes were chosen and divided into three groups, including a…

  2. An ontologically well-founded profile for UML conceptual models

    NARCIS (Netherlands)

    Guizzardi, G.; Wagner, Gerd; van Sinderen, Marten J.; Guarino, Nicola; Persson, Anne; Stirna, Janis

    2004-01-01

    UML class diagrams can be used as a language for expressing a conceptual model of a domain. In a series of papers [1,2,3] we have been using the General Ontological Language (GOL) and its underlying upper level ontology, proposed in [4,5], to evaluate the ontological correctness of a conceptual UML

  3. Toolkit for Conceptual Modeling (TCM): User's Guide and Reference

    NARCIS (Netherlands)

    Dehne, F.; Wieringa, Roelf J.

    1997-01-01

    The Toolkit for Conceptual Modeling (TCM) is a suite of graphical editors for a number of graphical notation systems that are used in software specification methods. The notations can be used to represent the conceptual structure of the software - hence the name of the suite. This manual describes

  4. Modeling Manganese Sorption and Surface Oxidation During Filtration

    OpenAIRE

    Bierlein, Kevin Andrew

    2012-01-01

    Soluble manganese (Mn) is a common contaminant in drinking water sources. High levels of Mn can lead to aesthetic water quality problems, necessitating removal of Mn during treatment to minimize consumer complaints. Mn may be removed during granular media filtration by the â natural greensand effect,â in which soluble Mn adsorbs to manganese oxide-coated (MnOx(s)) media and is then oxidized by chlorine, forming more manganese oxide. This research builds on a previous model developed by Mer...

  5. Diffusion and sorption on hardened cement pastes - experiments and modelling results

    Energy Technology Data Exchange (ETDEWEB)

    Jakob, A.; Sarott, F.-A.; Spieler, P.

    1999-08-01

    Large parts of repositories for low and intermediate level radioactive waste consist of cementitious materials. Radionuclides are transported by diffusion in the cement matrix or, in case of fractured or highly permeable cement, by advection and dispersion. In this work we aim at a mechanistic understanding of diffusion processes of some reactive tracers. On the laboratory scale, ten through-diffusion experiments were performed to study these processes for Cl{sup -}, I{sup -}, Cs{sup +} and Ni{sup 2+} ions in a Sulphate Resisting Portland Cement (SRPC) equilibrated with an artificial pore water. Some of the experiments continued up to nearly three years with daily measurements. In all the experiments, a cement disk initially saturated with an artificial pore water was exposed on one side to a highly diluted solution containing the species of interest. On the second side, a near-zero concentration boundary was maintained to drive through-diffusion of the tracer. The changes of concentrations on both sides of the samples were monitored, allowing careful mass balances. From these data, values of the diffusive flux and the mass of tracer taken up by the cementitious material were determined as a function of time. In the subsequent modelling, the time histories of these tracer breakthroughs were fitted using five different models. The simplest model neglects all retarding mechanisms except pure diffusion. More complex models either account for instantaneous equilibrium sorption in form of linear or non-linear (Freundlich) sorption or for first-order sorption kinetics where the forward reaction may be linear or non-linear according to the Freundlich isotherm, while the back-reaction is linear. Hence, the analysis allows the extraction of the diffusion coefficient and parameter values for the sorption isotherm or rate-constants for sorption and desorption. The fits to the experimental data were carried out by an automated Marquardt-Levenberg procedure yielding error

  6. Modeling of cesium sorption on biotite using cation exchange selectivity coefficients

    Energy Technology Data Exchange (ETDEWEB)

    Kylloenen, Jarkko; Hakanen, Martti; Harjula, Risto; Lehto, Jukka [Helsinki Univ. (Finland). Lab. of Radiochemistry; Lindberg, Antero [Geological Survey of Finland, Espoo (Finland); Vehkamaeki, Marko [Helsinki Univ. (Finland). Lab. of Inorganic Chemistry

    2014-07-01

    For the modeling of cesium sorption on biotite, samples of natural biotite separated from gneissic rocks were converted into monoionic potassium, sodium, and calcium forms, and sorption isotherms for Cs/K, Cs/Na and Cs/Ca exchange were determined at pH 6 and 8 in 10{sup -4}-10{sup -8} M Cs solutions. Selectivity coefficients for Cs/K, Cs/Na, and Cs/Ca ion exchange reactions were calculated from the isotherm data, using the Gaines-Thomas convention. At Cs loadings below 1% of the total ion exchange capacity, the overall selectivity coefficient for Cs/Ca exchange was approximately five and seven orders of magnitude higher than those for Cs/Na and Cs/K exchange, respectively. Based on the selectivity coefficients, the ion exchange isotherms were modeled with the U.S. Geological Survey PhreeqC program, assuming three different types of ion exchange site: sites on the basal planes on biotite crystal surfaces with 95% site abundance, probable interlayer sites on crystal edges [frayed edge sites (FESs)] (0.02%) and third-type sites (5%), the physical background of which is unclear. Of these three types, the FES sites were superior in Cs selectivity, while the planar sites exhibited the lowest selectivity, and the third-type sites had selectivity between these two. The functionality of the model was successfully verified by modeling the Cs sorption isotherms on crushed mica gneiss rock in saline groundwater. Determination of the exchangeable ions K, Na, Ca, and Cs on the basal plane and edge surfaces by scanning electron microscopy-energy-dispersive x-ray spectroscopy (SEM-EDX) supports the results of modeling: edge sites highly prefer Cs ions and also Ca and Na ions but not K ions.

  7. MOLECULAR DYNAMICS MODELING OF SORPTION OF PESTICIDES ONTO THE SURFACES OF KAOLINITE

    Science.gov (United States)

    To accurately predict the fate of contaminants in the environment and to make sound decisions about environmental remediation, we must accurately understand sorption mechanisms and surface reactivity of environmental particles. Sorption of selected pesticides on kaolinite surface...

  8. Conceptual model for transport processes in the Culebra Dolomite Member, Rustler Formation

    Energy Technology Data Exchange (ETDEWEB)

    Holt, R.M. [Holt Hydrogeology, Placitas, NM (United States)

    1997-08-01

    The Culebra Dolomite Member of the Rustler Formation represents a possible pathway for contaminants from the Waste Isolation Pilot Plant underground repository to the accessible environment. The geologic character of the Culebra is consistent with a double-porosity, multiple-rate model for transport in which the medium is conceptualized as consisting of advective porosity, where solutes are carried by the groundwater flow, and fracture-bounded zones of diffusive porosity, where solutes move through slow advection or diffusion. As the advective travel length or travel time increases, the nature of transport within a double-porosity medium changes. This behavior is important for chemical sorption, because the specific surface area per unit mass of the diffusive porosity is much greater than in the advective porosity. Culebra transport experiments conducted at two different length scales show behavior consistent with a multiple-rate, double-porosity conceptual model for Culebra transport. Tracer tests conducted on intact core samples from the Culebra show no evidence of significant diffusion, suggesting that at the core scale the Culebra can be modeled as a single-porosity medium where only the advective porosity participates in transport. Field tracer tests conducted in the Culebra show strong double-porosity behavior that is best explained using a multiple-rate model.

  9. Sorption by cation exchange

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    1994-04-01

    A procedure for introducing exchange into geochemical/surface complexation codes is described. Beginning with selectivity coefficients, K c , defined in terms of equivalent fractional ion occupancies, a general expression for the molar based exchange code input parameters, K ex , is derived. In natural systems the uptake of nuclides onto complex sorbents often occurs by more than one mechanism. The incorporation of cation exchange and surface complexation into a geochemical code therefore enables sorption by both mechanisms to be calculated simultaneously. The code and model concepts are tested against sets of experimental data from widely different sorption studies. A proposal is made to set up a data base of selectivity coefficients. Such a data base would form part of a more general one consisting of sorption mechanism specific parameters to be used in conjunction with geochemical/sorption codes to model and predict sorption. (author) 6 figs., 6 tabs., 26 refs

  10. The Model Vision Project: A Conceptual Framework for Service Delivery

    Science.gov (United States)

    Bourgeault, Stanley E.; And Others

    1977-01-01

    Described are the conceptualization, implementation, and results to date of the George Peabody College for Teachers Model Center for Severely Handicapped Multi-impaired Children with Visual Impairment as a Primary Handicapping Condition. (Author/IM)

  11. Sorption and desorption kinetics of some radionuclides on suspended matter: comparison of different models

    International Nuclear Information System (INIS)

    Ciffroy, P.; Siclet, F.; Garnier, J.M.; Pham Mai, K.

    1996-01-01

    To obtain suitable data for modelling radionuclides migration in freshwater streams, the sorption and desorption kinetics of some radionuclides (54Mn, 58Co, 134Cs) on suspended matter were studied under controlled laboratory conditions. The experimental results show that: -for some radionuclides (58Co, 54Mn), the adsorption process is progressive and slow; after 5 days, an important fraction of the radioactivity is associated to the particles. For 134Cs, very fast sorption is followed by much slower and extended uptake. -the retention of 134Cs, and above all of 54Mn and 58Co, on suspended matter is stronger when the particles have been previously in contact with the radionuclides during a long period. This retention could be due to the slow transfer of 54Mn and 58Co to non-exchangeable sites of the particles. This effect of contact time during preliminary adsorption is less important for 134Cs. The results of uptake and release experiments were used to test models describing the radionuclides interactions with suspended solids. Two kinetic models are compared in this paper. The model taking into account two distinct types of sites on the solid phase and irreversible processes better describes the interactions of radionuclides with suspended matter

  12. Water Sorption Isotherm of Pea Starch Edible Films and Prediction Models.

    Science.gov (United States)

    Saberi, Bahareh; Vuong, Quan V; Chockchaisawasdee, Suwimol; Golding, John B; Scarlett, Christopher J; Stathopoulos, Costas E

    2015-12-24

    The moisture sorption isotherm of pea starch films prepared with various glycerol contents as plasticizer was investigated at different storage relative humidities (11%-96% RH) and at 5 ± 1, 15 ± 1, 25 ± 1 and 40 ± 1 °C by using gravimetric method. The results showed that the equilibrium moisture content of all films increased substantially above a w = 0.6. Films plasticized with glycerol, under all temperatures and RH conditions (11%-96%), adsorbed more moisture resulting in higher equilibrium moisture contents. Reduction of the temperature enhanced the equilibrium moisture content and monolayer water of the films. The obtained experimental data were fitted to different models including two-parameter equations (Oswin, Henderson, Brunauer-Emmitt-Teller (BET), Flory-Huggins, and Iglesias-Chirife), three-parameter equations Guggenhiem-Anderson-deBoer (GAB), Ferro-Fontan, and Lewicki) and a four-parameter equation (Peleg). The three-parameter Lewicki model was found to be the best-fitted model for representing the experimental data within the studied temperatures and whole range of relative humidities (11%-98%). Addition of glycerol increased the net isosteric heat of moisture sorption of pea starch film. The results provide important information with estimating of stability and functional characteristics of the films in various environments.

  13. Water Sorption Isotherm of Pea Starch Edible Films and Prediction Models

    Directory of Open Access Journals (Sweden)

    Bahareh Saberi

    2015-12-01

    Full Text Available The moisture sorption isotherm of pea starch films prepared with various glycerol contents as plasticizer was investigated at different storage relative humidities (11%–96% RH and at 5 ± 1, 15 ± 1, 25 ± 1 and 40 ± 1 °C by using gravimetric method. The results showed that the equilibrium moisture content of all films increased substantially above aw = 0.6. Films plasticized with glycerol, under all temperatures and RH conditions (11%–96%, adsorbed more moisture resulting in higher equilibrium moisture contents. Reduction of the temperature enhanced the equilibrium moisture content and monolayer water of the films. The obtained experimental data were fitted to different models including two-parameter equations (Oswin, Henderson, Brunauer–Emmitt–Teller (BET, Flory–Huggins, and Iglesias–Chirife, three-parameter equations Guggenhiem–Anderson–deBoer (GAB, Ferro–Fontan, and Lewicki and a four-parameter equation (Peleg. The three-parameter Lewicki model was found to be the best-fitted model for representing the experimental data within the studied temperatures and whole range of relative humidities (11%–98%. Addition of glycerol increased the net isosteric heat of moisture sorption of pea starch film. The results provide important information with estimating of stability and functional characteristics of the films in various environments.

  14. Analysis and modeling of moisture sorption behavior for antimicrobial composite protein films.

    Science.gov (United States)

    Lei, Qiao; Pan, Jiazhen; Bao, Jianqiang; Huang, Zhiying; Zhang, Yuting

    2014-01-01

    The WPI-NaCas-GLY antimicrobial film takes full advantage of the controlled release of active or antimicrobial agents as well as demonstrates a great potential for functioning as an alternative biodegradable polymer in practical applications. The moisture sorption kinetics of the film as an important carrier of active agents was investigated at various relative humidities (RH). The results indicated that the moisture sorption characterization and procedure of this film can be described well by the empirical Peleg model with higher confidence and concordance. The model could predict the film's moisture content at any time (Mt), the time to reach any given level of R (tR), the equilibrium moisture at any RH condition (Me), and isotherm trend based upon experimental data and modeled constants k(1), k(2), a, b, c, and d without giving consideration to their physical meaning. The water vapor transmission rate of the WPI-NaCas-GLY antimicrobial film increased exponentially with increasing RH due to its hydrophilicity, which was primarily caused by the presence of glycerol in a higher content. The results also suggested that aw predominately affects the film's Me values compared with the temperature factor by fixed nonlinear multiple regression analyses.

  15. Applicability of surface complexation modelling in TVO's studies on sorption of radionuclides

    International Nuclear Information System (INIS)

    Carlsson, T.

    1994-03-01

    The report focuses on the possibility of applying surface complexation theories to the conditions at a potential repository site in Finland and of doing proper experimental work in order to determine necessary constants for the models. The report provides background information on: (1) what type experiments should be carried out in order to produce data for surface complexation modelling of sorption phenomena under potential Finnish repository conditions, and (2) how to design and perform properly such experiments, in order to gather data, develop models or both. The report does not describe in detail how proper surface complexation experiments or modelling should be carried out. The work contains several examples of information that may be valuable in both modelling and experimental work. (51 refs., 6 figs., 4 tabs.)

  16. Modeling of kinetics of Cr(VI) sorption onto grape stalk waste in a stirred batch reactor

    International Nuclear Information System (INIS)

    Escudero, Carlos; Fiol, Nuria; Poch, Jordi; Villaescusa, Isabel

    2009-01-01

    Recently, Cr(VI) removal by grape stalks has been postulated to follow two mechanisms, adsorption and reduction to trivalent chromium. Nevertheless, the rate at which both processes take place and the possible simultaneity of both processes has not been investigated. In this work, kinetics of Cr(VI) sorption onto grape stalk waste has been studied. Experiments were carried out at different temperatures but at a constant pH (3 ± 0.1) in a stirred batch reactor. Results showed that three steps take place in the process of Cr(VI) sorption onto grape stalk waste: Cr(VI) sorption, Cr(VI) reduction to Cr(III) and the adsorption of the formed Cr(III). Taking into account the evidences above mentioned, a model has been developed to predict Cr(VI) sorption on grape stalks on the basis of (i) irreversible reduction of Cr(VI) to Cr(III) reaction, whose reaction rate is assumed to be proportional to the Cr(VI) concentration in solution and (ii) adsorption and desorption of Cr(VI) and formed Cr(III) assuming that all the processes follow Langmuir type kinetics. The proposed model fits successfully the kinetic data obtained at different temperatures and describes the kinetics profile of total, hexavalent and trivalent chromium. The proposed model would be helpful for researchers in the field of Cr(VI) biosorption to design and predict the performance of sorption processes.

  17. Modeling of kinetics of Cr(VI) sorption onto grape stalk waste in a stirred batch reactor

    Energy Technology Data Exchange (ETDEWEB)

    Escudero, Carlos, E-mail: u1058115@correu.udg.edu [Department of Chemical Engineering, Escola Politecnica Superior, Universitat de Girona, Avda. Lluis Santalo s/n, 17002 Girona (Spain); Fiol, Nuria, E-mail: nuria.fiol@udg.edu [Department of Chemical Engineering, Escola Politecnica Superior, Universitat de Girona, Avda. Lluis Santalo s/n, 17002 Girona (Spain); Poch, Jordi, E-mail: Jordi.poch@udg.edu [Department of Applied Mathematics, Escola Politecnica Superior, Universitat de Girona, Avda. Lluis Santalo s/n, 17002 Girona (Spain); Villaescusa, Isabel [Department of Chemical Engineering, Escola Politecnica Superior, Universitat de Girona, Avda. Lluis Santalo s/n, 17002 Girona (Spain)

    2009-10-15

    Recently, Cr(VI) removal by grape stalks has been postulated to follow two mechanisms, adsorption and reduction to trivalent chromium. Nevertheless, the rate at which both processes take place and the possible simultaneity of both processes has not been investigated. In this work, kinetics of Cr(VI) sorption onto grape stalk waste has been studied. Experiments were carried out at different temperatures but at a constant pH (3 {+-} 0.1) in a stirred batch reactor. Results showed that three steps take place in the process of Cr(VI) sorption onto grape stalk waste: Cr(VI) sorption, Cr(VI) reduction to Cr(III) and the adsorption of the formed Cr(III). Taking into account the evidences above mentioned, a model has been developed to predict Cr(VI) sorption on grape stalks on the basis of (i) irreversible reduction of Cr(VI) to Cr(III) reaction, whose reaction rate is assumed to be proportional to the Cr(VI) concentration in solution and (ii) adsorption and desorption of Cr(VI) and formed Cr(III) assuming that all the processes follow Langmuir type kinetics. The proposed model fits successfully the kinetic data obtained at different temperatures and describes the kinetics profile of total, hexavalent and trivalent chromium. The proposed model would be helpful for researchers in the field of Cr(VI) biosorption to design and predict the performance of sorption processes.

  18. Modeling of kinetics of Cr(VI) sorption onto grape stalk waste in a stirred batch reactor.

    Science.gov (United States)

    Escudero, Carlos; Fiol, Nuria; Poch, Jordi; Villaescusa, Isabel

    2009-10-15

    Recently, Cr(VI) removal by grape stalks has been postulated to follow two mechanisms, adsorption and reduction to trivalent chromium. Nevertheless, the rate at which both processes take place and the possible simultaneity of both processes has not been investigated. In this work, kinetics of Cr(VI) sorption onto grape stalk waste has been studied. Experiments were carried out at different temperatures but at a constant pH (3+/-0.1) in a stirred batch reactor. Results showed that three steps take place in the process of Cr(VI) sorption onto grape stalk waste: Cr(VI) sorption, Cr(VI) reduction to Cr(III) and the adsorption of the formed Cr(III). Taking into account the evidences above mentioned, a model has been developed to predict Cr(VI) sorption on grape stalks on the basis of (i) irreversible reduction of Cr(VI) to Cr(III) reaction, whose reaction rate is assumed to be proportional to the Cr(VI) concentration in solution and (ii) adsorption and desorption of Cr(VI) and formed Cr(III) assuming that all the processes follow Langmuir type kinetics. The proposed model fits successfully the kinetic data obtained at different temperatures and describes the kinetics profile of total, hexavalent and trivalent chromium. The proposed model would be helpful for researchers in the field of Cr(VI) biosorption to design and predict the performance of sorption processes.

  19. Kinetic Modelling of the Removal of Multiple Heavy Metallic Ions from Mine Waste by Natural Zeolite Sorption

    Directory of Open Access Journals (Sweden)

    Amanda L. Ciosek

    2017-07-01

    Full Text Available This study investigates the sorption of heavy metallic ions (HMIs, specifically lead (Pb2+, copper (Cu2+, iron (Fe3+, nickel (Ni2+ and zinc (Zn2+, by natural zeolite (clinoptilolite. These HMIs are combined in single-, dual-, triple-, and multi-component systems. The batch mode experiments consist of a total initial concentration of 10 meq/L normality for all systems, acidified to a pH of 2 by concentrated nitric (HNO3 acid. A zeolite dosage of 4 g per 100 mL of synthetic nitrate salt aqueous solution is applied, for a contact period of 5 to 180 min. Existing kinetic models on HMIs sorption are limited for multi-component system combinations. Therefore, this study conducts kinetic analysis by both reaction and diffusion models, to quantify the sorption process. The study concludes that the process correlates best with the pseudo-second-order (PSO kinetic model. In the multi-component system combining all five HMIs, the initial sorption rate and theoretical equilibrium capacity are determined as 0.0033 meq/g·min and 0.1159 meq/g, respectively. This provides significant insight into the mechanisms associated with the sorption process, as well as contributing to the assessment of natural zeolite as a sorbent material in its application in industrial wastewater treatment.

  20. Modified permeability modeling of coal incorporating sorption-induced matrix shrinkage

    Science.gov (United States)

    Soni, Aman

    The variation in the cleat permeability of coalbed methane (CBM) reservoirs is attributed primarily to two cardinal processes, with opposing effects. Increase in effective stresses with reduction in pore pressure tends to decrease the cleat permeability, whereas the sorption-induced coal matrix shrinkage actuates reduction in the effective stresses which increases the reservoir permeability. The net effect of the two processes determines the pressure-dependent-permeability and, hence, the overall trend of CBM production with depletion. Several analytical models have been developed and used to predict the dynamic behavior of CBM reservoir permeability during production through pressure depletion, all based on combining the two effects. The purpose of this study was to introduce modifications to two most commonly used permeability models, namely the Palmer and Mansoori, and Shi and Durucan, for permeability variation and evaluate their performance when projecting gas production. The basis for the modification is the linear relationship between the volume of sorbed gas and the associated matrix shrinkage. Hence, the impact of matrix shrinkage is incorporated as a function of the amount of gas produced, or that remaining in coal, at any time during production. Since the exact production from a reservoir is known throughout its life, this significantly simplifies the process of permeability modeling. Furthermore, the modification is also expected to streamline the process of modeling by classifying the shrinkage parameters for coals of different regions, but with similar characteristics. A good analogy is the San Juan basin, where sorption characteristics of coal are so well understood and defined that operators no longer carry out laboratory sorption work. The goal is to achieve the same for incorporation of the matrix shrinkage behavior. Another modification is to incorporate the matrix, or grain, compressibility effect of coal as a correction factor in the Shi and

  1. Application of multiple sorption model to estimation of CO2 sequestration capacity or CH4 recovery in polish hard coals

    Directory of Open Access Journals (Sweden)

    Jodłowski Grzegorz

    2017-01-01

    Full Text Available The aim of the study is to estimate the theoretical capacity of coal deposits in terms of carbon dioxide storage and methane recovery estimate during the injection of carbon dioxide. The Multiple Sorption Model was used for this purpose. The range of sorption measurement data on which the simulations were based does not exceed the critical point for both methane and carbon dioxide. The model allows to calculate absorption, adsorption, expansion and total theoretical sorption. For further consideration absorption was used as the process of the percolation of the gas in the bulk of the coal matter as well as the total theoretical sorption, the occurrence of which is possible due to the presence of fractures in the coal seam. Calculated levels of absorption and the total theoretical adsorption were applied to estimate the possible storage capacity of carbon dioxide based on the data associated with the content of coal in the mining fields of individual Polish coal mines. Moreover, MSM development for the gas mixture sorption can be used to roughly assess the recovery of methane naturally occurring in coal deposits during such a process.

  2. Kinetic modeling of pH-dependent antimony (V) sorption and transport in iron oxide-coated sand.

    Science.gov (United States)

    Cai, Yongbing; Li, Lulu; Zhang, Hua

    2015-11-01

    Understanding the mechanisms and kinetics controlling the retention and transport of antimony (Sb) is prerequisite for evaluating the risk of groundwater contamination by the toxic element. In this study, kinetic batch and saturated miscible displacement experiments were performed to investigate effects of protonation-deprotonation reactions on sorption-desorption and transport of Sb(V) in iron oxide-coated sand (IOCS). Results clearly demonstrated that Sb(V) sorption was highly nonlinear and time dependent, where both sorption capacity and kinetic rates decreased with increasing solution pH. Breakthrough curves (BTCs) obtained at different solution pH exhibited that mobility of Sb(V) were higher under neutral to alkaline condition than under acidic condition. Because of the nonlinear and non-equilibrium nature of Sb(V) retention and transport, multi-reaction models (MRM) with equilibrium and kinetic sorption expressions were utilized successfully to simulate the experiment data. Equilibrium distribution coefficient (Ke) and reversible kinetic retention parameters (k1 and k2) of both kinetic sorption and transport experiment showed marked decrease as pH increased from 4.0 to 7.5. Surface complexation is suggested as the dominant mechanism for the observed pH-dependent phenomena, which need to be incorporated into the kinetic models to accurately simulate the reactive transport of Sb(V) in vadose zone and aquifers. Copyright © 2015. Published by Elsevier Ltd.

  3. Lumped conceptual hydrological model for Purna river basin, India

    Indian Academy of Sciences (India)

    graphical information system (GIS) based hydrological models are becoming increasingly useful in prediction of ... models are preferred over lumped conceptual models in prediction of runoff provided exten- sive data ..... high values of CQOF may be ascribed due to presence of certain low permeable soil like clay and bare ...

  4. Conceptual model for assessment of inhalation exposure: Defining modifying factors

    NARCIS (Netherlands)

    Tielemans, E.; Schneider, T.; Goede, H.; Tischer, M.; Warren, N.; Kromhout, H.; Tongeren, M. van; Hemmen, J. van; Cherrie, J.W.

    2008-01-01

    The present paper proposes a source-receptor model to schematically describe inhalation exposure to help understand the complex processes leading to inhalation of hazardous substances. The model considers a stepwise transfer of a contaminant from the source to the receptor. The conceptual model is

  5. Behaviour of selenate in soils: experimental approach and modeling of hysteresis of sorption/desorption

    International Nuclear Information System (INIS)

    Loffredo, N.

    2010-01-01

    In the context of future storage of nuclear material in deep geological layers, the transfer of selenium-79 from groundwater to biosphere through irrigation is one of the scenarios considered by the ANDRA (National Agency for Radioactive Waste Management). So, the soil would act as an interface between the geosphere and biosphere. Actually the model adopted to evaluate the element mobility in soil is based on a simple representation of its distribution between the quantity adsorbed on the soil and the amount remaining in the solution (KD model). Such distribution is considered as instantaneous, reversible and linear with the concentration of contamination. This model has some inadequacies with respect to selenium because this latter can be present in different redox states that control its mobility and whose transformation kinetics among states are poorly known (Se(-II), Se(0), Se(IV) and Se(VI)). In order to improve predictions on the mobility of selenium in soil, selenate (Se(VI)) - which is the most mobile form - has been used to study its interactions with respect to two different soils (soil B and soil R). A kinetic model, alternative to the K d model, has been developed to describe the evolution of stocks of Se(VI) in solution. This model considers that a fraction of selenium is associated with soil in a reversibly way (potentially mobile) and a portion of it is stabilized in soil (pseudo-irreversibly fixed). This model integrates on one hand, in the soil, kinetics of biotic and abiotic stabilization and on the other hand, in solution, a reduction kinetic. With the goal of acquiring the parameters of the models, various experiments using dialysis bags have been effectuated, both in batch and with open-flow reactors. The parameter acquisition has allowed kinetic and K d models to be compared in different realistic scenarios of contamination (chronic or sequential) of a surface soil with 79 Se(VI). In addition, the sorption mechanisms of Se(VI) have been

  6. Mathematical model of the sorption phenomenon of methanol in activated coal

    International Nuclear Information System (INIS)

    Cortes, Farid B.; Chejne, Farid; Mejia, Juan M.; Londono, Carlos A.

    2009-01-01

    A transient model of a sorption refrigerator using activated carbon/methanol pair is presented. It is a non-uniform pressure model conformed by the mass, energy and momentum balance equations in cylindrical coordinates, for the activated coal bed contained in the adsorber. The results obtained from the simulation were suitably validated by the experimental information obtained from field test data and from data reported in the literature, presenting errors below 1.6% for each cycle step. The model allows to get data of temperature, pressure, density and gas velocity profiles in radial direction, as well as the solid temperature and the quantity of adsorbed methanol in the activated carbon bed in adsorption/evaporation and desorption/condensation steps.

  7. Mathematical model of the sorption phenomenon of methanol in activated coal

    Energy Technology Data Exchange (ETDEWEB)

    Cortes, Farid B.; Chejne, Farid; Mejia, Juan M.; Londono, Carlos A. [Grupo de Termodinamica Aplicada y Energias Alternativas - Instituto de Energia, Facultad de Minas, Universidad Nacional de Colombia, sede Medellin (Colombia)

    2009-05-15

    A transient model of a sorption refrigerator using activated carbon/methanol pair is presented. It is a non-uniform pressure model conformed by the mass, energy and momentum balance equations in cylindrical coordinates, for the activated coal bed contained in the adsorber. The results obtained from the simulation were suitably validated by the experimental information obtained from field test data and from data reported in the literature, presenting errors below 1.6% for each cycle step. The model allows to get data of temperature, pressure, density and gas velocity profiles in radial direction, as well as the solid temperature and the quantity of adsorbed methanol in the activated carbon bed in adsorption/evaporation and desorption/condensation steps. (author)

  8. A quantitative mechanistic description of Ni, Zn and Ca sorption on Na-Montmorillonite. Part III: Modelling

    International Nuclear Information System (INIS)

    Baeyens, B.; Bradbury, M.H.

    1995-07-01

    Titration and sorption measurements, carried out under a wide variety of conditions on Na-montmorillonite, were examined in terms of cation exchange and surface complexation mechanisms. A computer code called MINSORB was developed and used throughout this work. This code allowed the uptake of radionuclides by both mechanisms to be calculated simultaneously; also taking into account competitive reactions from other cations present. A stepwise iterative fitting/modelling procedure is described. For the case of Na-montmorillonite it is demonstrated that an electrostatic term in the surface complexation model is not required. A basic data set comprising of site capacities and protonation/deprotonation constants was defined, which was valid for all surface complexation sorption reactions. The main study was carried out with Ni, but impurity cations present in the system, particularly Zn, had to be examined in addition due to their competitive effects on Ni sorption. The surface complexation behaviour of Ni and Zn was investigated in detail to give intrinsic surface complexation constants on two of the ≡SOH type sites included in the model. The sorption of Mg, Ca and Mn is also considered, though in less detail, and estimated surface complexation constants for these nuclides are presented. Cation exchange was included in all of the calculations. Measured selectivity coefficients for Ni-Na, Zn-Na and Ca-Na exchange reactions are given. The model, with the derived parameters, allowed all the data from titration measurements through sorption edges to sorption isotherms to be calculated. (author) 31 figs., 9 tabs., refs

  9. Conceptual adsorption models and open issues pertaining to performance assessment

    International Nuclear Information System (INIS)

    Serne, R.J.

    1992-01-01

    Recently several articles have been published that question the appropriateness of the distribution coefficient, Rd, concept to quantify radionuclide migration. Several distinct issues surrounding the modeling of nuclide retardation. The first section defines adsorption terminology and discusses various adsorption processes. The next section describes five commonly used adsorption conceptual models, specifically emphasizing what attributes that affect adsorption are explicitly accommodated in each model. I also review efforts to incorporate each adsorption model into performance assessment transport computer codes. The five adsorption conceptual models are (1) the constant Rd model, (2) the parametric Rd model, (3) isotherm adsorption models, (4) mass action adsorption models, and (5) surface-complexation with electrostatics models. The final section discusses the adequacy of the distribution ratio concept, the adequacy of transport calculations that rely on constant retardation factors and the status of incorporating sophisticated adsorption models into transport codes. 86 refs., 1 fig., 1 tab

  10. Guide for developing conceptual models for ecological risk assessments

    Energy Technology Data Exchange (ETDEWEB)

    Suter, G.W., II

    1996-05-01

    Ecological conceptual models are the result of the problem formulation phase of an ecological risk assessment, which is an important component of the Remedial Investigation process. They present hypotheses of how the site contaminants might affect the site ecology. The contaminant sources, routes, media, routes, and endpoint receptors are presented in the form of a flow chart. This guide is for preparing the conceptual models; use of this guide will standardize the models so that they will be of high quality, useful to the assessment process, and sufficiently consistent so that connections between sources of exposure and receptors can be extended across operable units (OU). Generic conceptual models are presented for source, aquatic integrator, groundwater integrator, and terrestrial OUs.

  11. Guide for developing conceptual models for ecological risk assessments

    International Nuclear Information System (INIS)

    Suter, G.W., II.

    1996-05-01

    Ecological conceptual models are the result of the problem formulation phase of an ecological risk assessment, which is an important component of the Remedial Investigation process. They present hypotheses of how the site contaminants might affect the site ecology. The contaminant sources, routes, media, routes, and endpoint receptors are presented in the form of a flow chart. This guide is for preparing the conceptual models; use of this guide will standardize the models so that they will be of high quality, useful to the assessment process, and sufficiently consistent so that connections between sources of exposure and receptors can be extended across operable units (OU). Generic conceptual models are presented for source, aquatic integrator, groundwater integrator, and terrestrial OUs

  12. Conceptual Modeling of Time-Varying Information

    DEFF Research Database (Denmark)

    Gregersen, Heidi; Jensen, Christian Søndergaard

    2004-01-01

    A wide range of database applications manage information that varies over time. Many of the underlying database schemas of these were designed using the Entity-Relationship (ER) model. In the research community as well as in industry, it is common knowledge that the temporal aspects of the mini-world...... are important, but difficult to capture using the ER model. Several enhancements to the ER model have been proposed in an attempt to support the modeling of temporal aspects of information. Common to the existing temporally extended ER models, few or no specific requirements to the models were given...

  13. Equilibrium sorption of cobalt, cesium, and strontium on Bandelier Tuff: analysis of alternative mathematical modeling

    International Nuclear Information System (INIS)

    Polzer, W.L.; Fuentes, H.R.; Essington, E.H.; Roensch, F.R.

    1985-01-01

    Sorption isotherms are derived from batch equilibrium data for cobalt, cesium and strontium on Bandelier Tuff. Experiments were conducted at an average temperature of 23 0 C and equilibrium was defined at 48 hours. The solute concentrations ranged from 0 to 500 mg/L. The radioactive isotopes 60 Co, 137 Cs, and 85 Sr were used to trace the sorption of the stable solutes. The Linear, Langmuir, Freundlich and a Modified Freundlich isotherm equations are evaluated. The Modified Freundlich isotherm equation is validated as a preferred general mathematical tool for representing the sorption of the three solutes. The empirical constants derived from the Modified Freundlich isotherm equation indicate that under dynamic flow conditions strontium will move most rapidly and cobalt least rapidly. On the other hand, chemical dispersion will be greatest for cesium and least for strontium. Hill Plots of the sorption data suggest that in the region of low saturation sorption of all three solutes is impeded by interactions among sorption sites; cobalt exhibits the greatest effect of interactions and strontium shows only a minimal effect. In the saturation region of 50% or more, sorption of cobalt is enhanced slightly by interactions among sorption sites whereas sorption of cesium and strontium appears to be independent of site interactions. 9 references, 4 figures, 2 tables

  14. A Conceptual Framework of Business Model Emerging Resilience

    OpenAIRE

    Goumagias, Nikolaos; Fernandes, Kiran; Cabras, Ignazio; Li, Feng; Shao, Jianhua; Devlin, Sam; Hodge, Victoria; Cowling, Peter; Kudenko, Daniel

    2016-01-01

    In this paper we introduce an environmentally driven conceptual framework of Business Model change. Business models acquired substantial momentum in academic literature during the past decade. Several studies focused on what exactly constitutes a Business Model (role model, recipe, architecture etc.) triggering a theoretical debate about the Business Model’s components and their corresponding dynamics and relationships. In this paper, we argue that for Business Models as cognitive structures,...

  15. Incorporating classic adsorption isotherms into modern surface complexation models: implications for sorption of radionuclides

    International Nuclear Information System (INIS)

    Kulik, D.A.

    2005-01-01

    Full text of publication follows: Computer-aided surface complexation models (SCM) tend to replace the classic adsorption isotherm (AI) analysis in describing mineral-water interface reactions such as radionuclide sorption onto (hydr) oxides and clays. Any site-binding SCM based on the mole balance of surface sites, in fact, reproduces the (competitive) Langmuir isotherm, optionally amended with electrostatic Coulomb's non-ideal term. In most SCM implementations, it is difficult to incorporate real-surface phenomena (site heterogeneity, lateral interactions, surface condensation) described in classic AI approaches other than Langmuir's. Thermodynamic relations between SCMs and AIs that remained obscure in the past have been recently clarified using new definitions of standard and reference states of surface species [1,2]. On this basis, a method for separating the Langmuir AI into ideal (linear) and non-ideal parts [2] was applied to multi-dentate Langmuir, Frumkin, and BET isotherms. The aim of this work was to obtain the surface activity coefficient terms that make the SCM site mole balance constraints obsolete and, in this way, extend thermodynamic SCMs to cover sorption phenomena described by the respective AIs. The multi-dentate Langmuir term accounts for the site saturation with n-dentate surface species, as illustrated on modeling bi-dentate U VI complexes on goethite or SiO 2 surfaces. The Frumkin term corrects for the lateral interactions of the mono-dentate surface species; in particular, it has the same form as the Coulombic term of the constant-capacitance EDL combined with the Langmuir term. The BET term (three parameters) accounts for more than a monolayer adsorption up to the surface condensation; it can potentially describe the surface precipitation of nickel and other cations on hydroxides and clay minerals. All three non-ideal terms (in GEM SCMs implementation [1,2]) by now are used for non-competing surface species only. Upon 'surface dilution

  16. Educational game models: conceptualization and evaluation ...

    African Journals Online (AJOL)

    The relationship between educational theories, game design and game development are used to develop models for the creation of complex learning environments. The Game Object Model (GOM), that marries educational theory and game design, forms the basis for the development of the Persona Outlining Model (POM) ...

  17. Menthor Editor: An Ontology-Driven Conceptual Modeling Platform

    NARCIS (Netherlands)

    Moreira, João Luiz; Sales, Tiago Prince; Guerson, John; Braga, Bernardo F.B; Brasileiro, Freddy; Sobral, Vinicius

    2016-01-01

    The lack of well-founded constructs in ontology tools can lead to the construction of non-intended models. In this demonstration we present the Menthor Editor, an ontology-driven conceptual modelling platform which incorporates the theories of the Unified Foundational Ontology (UFO). We illustrate

  18. Conceptual Model of Artifacts for Design Science Research

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    2015-01-01

    We present a conceptual model of design science research artifacts. The model views an artifact at three levels. At the artifact level a selected artifact is viewed as a combination of material and immaterial aspects and a set of representations hereof. At the design level the selected artifact...

  19. Conceptual astronomy: A novel model for teaching postsecondary science courses

    Science.gov (United States)

    Zeilik, Michael; Schau, Candace; Mattern, Nancy; Hall, Shannon; Teague, Kathleen W.; Bisard, Walter

    1997-10-01

    An innovative, conceptually based instructional model for teaching large undergraduate astronomy courses was designed, implemented, and evaluated in the Fall 1995 semester. This model was based on cognitive and educational theories of knowledge and, we believe, is applicable to other large postsecondary science courses. Major components were: (a) identification of the basic important concepts and their interrelationships that are necessary for connected understanding of astronomy in novice students; (b) use of these concepts and their interrelationships throughout the design, implementation, and evaluation stages of the model; (c) identification of students' prior knowledge and misconceptions; and (d) implementation of varied instructional strategies targeted toward encouraging conceptual understanding in students (i.e., instructional concept maps, cooperative small group work, homework assignments stressing concept application, and a conceptually based student assessment system). Evaluation included the development and use of three measures of conceptual understanding and one of attitudes toward studying astronomy. Over the semester, students showed very large increases in their understanding as assessed by a conceptually based multiple-choice measure of misconceptions, a select-and-fill-in concept map measure, and a relatedness-ratings measure. Attitudes, which were slightly positive before the course, changed slightly in a less favorable direction.

  20. Motivation to Improve Work through Learning: A Conceptual Model

    Directory of Open Access Journals (Sweden)

    Kueh Hua Ng

    2014-12-01

    Full Text Available This study aims to enhance our current understanding of the transfer of training by proposing a conceptual model that supports the mediating role of motivation to improve work through learning about the relationship between social support and the transfer of training. The examination of motivation to improve work through motivation to improve work through a learning construct offers a holistic view pertaining to a learner's profile in a workplace setting, which emphasizes learning for the improvement of work performance. The proposed conceptual model is expected to benefit human resource development theory building, as well as field practitioners by emphasizing the motivational aspects crucial for successful transfer of training.

  1. Problem Solving, Modeling, and Local Conceptual Development.

    Science.gov (United States)

    Lesh, Richard; Harel, Guershon

    2003-01-01

    Describes similarities and differences between modeling cycles and stages of development. Includes examples of relevant constructs underlying children's developing ways of thinking about fractions, ratios, rates, proportions, or other mathematical ideas. Concludes that modeling cycles appear to be local or situated versions of the general stages…

  2. Geologic Conceptual Model of Mosul Dam

    Science.gov (United States)

    2007-09-01

    geomechanical characteristics or geotechnical properties. As an example, if the locations and depths of zones of high grout-take are known, these zones can...Dam safety Foundation grout Geologic model GIS Gypsum Hydrogeology Iraq geology Karst 3-D modeling 16. SECURITY CLASSIFICATION

  3. Including sorption to black carbon in modelling bioaccumulation of polycyclic aromatic hydrocarbons: Uncertainty analysis and comparison with field data

    NARCIS (Netherlands)

    Hauck, M.; Hendriks, A.J.; Huijbregts, M.J.A.; Koelmans, A.A.; Heuvel-Greve, van den M.J.; Moermond, C.T.A.; Veltman, K.; Vethaak, A.D.

    2007-01-01

    Model estimations of bioaccumulation of polycyclic aromatic hydrocarbons (PAHs) have been higher than field or laboratory data. This has been explained by strong sorption to black carbon (BC). In this paper, eight previously published bioaccumulation datasets were reinterpreted in terms of

  4. The ACTIVE conceptual framework as a structural equation model.

    Science.gov (United States)

    Gross, Alden L; Payne, Brennan R; Casanova, Ramon; Davoudzadeh, Pega; Dzierzewski, Joseph M; Farias, Sarah; Giovannetti, Tania; Ip, Edward H; Marsiske, Michael; Rebok, George W; Schaie, K Warner; Thomas, Kelsey; Willis, Sherry; Jones, Richard N

    2018-01-01

    Background/Study Context: Conceptual frameworks are analytic models at a high level of abstraction. Their operationalization can inform randomized trial design and sample size considerations. The Advanced Cognitive Training for Independent and Vital Elderly (ACTIVE) conceptual framework was empirically tested using structural equation modeling (N=2,802). ACTIVE was guided by a conceptual framework for cognitive training in which proximal cognitive abilities (memory, inductive reasoning, speed of processing) mediate treatment-related improvement in primary outcomes (everyday problem-solving, difficulty with activities of daily living, everyday speed, driving difficulty), which in turn lead to improved secondary outcomes (health-related quality of life, health service utilization, mobility). Measurement models for each proximal, primary, and secondary outcome were developed and tested using baseline data. Each construct was then combined in one model to evaluate fit (RMSEA, CFI, normalized residuals of each indicator). To expand the conceptual model and potentially inform future trials, evidence of modification of structural model parameters was evaluated by age, years of education, sex, race, and self-rated health status. Preconceived measurement models for memory, reasoning, speed of processing, everyday problem-solving, instrumental activities of daily living (IADL) difficulty, everyday speed, driving difficulty, and health-related quality of life each fit well to the data (all RMSEA .95). Fit of the full model was excellent (RMSEA = .038; CFI = .924). In contrast with previous findings from ACTIVE regarding who benefits from training, interaction testing revealed associations between proximal abilities and primary outcomes are stronger on average by nonwhite race, worse health, older age, and less education (p conceptual model. Findings suggest that the types of people who show intervention effects on cognitive performance potentially may be different from

  5. Kinetics and Equilibrium Sorption Models: Fitting Plutonium, Strontium, Uranium and Neptunium Loading on Monosodium Titanate (MST)

    Energy Technology Data Exchange (ETDEWEB)

    Fondeur, F

    2006-03-08

    The Dubinin-Astashov (DA) isotherm parameters for U, Pu, Sr and Np have been updated to include additional data obtained since the original derivation. The DA isotherms were modified to include a kinetic function derived by Rahn to describe sorbate loading from the beginning of sorption up to steady state. The final functions describe both kinetic and thermodynamic sorption.

  6. Equilibrium modeling of mono and binary sorption of Cu(II and Zn(II onto chitosan gel beads

    Directory of Open Access Journals (Sweden)

    Nastaj Józef

    2016-12-01

    Full Text Available The objective of the work are in-depth experimental studies of Cu(II and Zn(II ion removal on chitosan gel beads from both one- and two-component water solutions at the temperature of 303 K. The optimal process conditions such as: pH value, dose of sorbent and contact time were determined. Based on the optimal process conditions, equilibrium and kinetic studies were carried out. The maximum sorption capacities equaled: 191.25 mg/g and 142.88 mg/g for Cu(II and Zn(II ions respectively, when the sorbent dose was 10 g/L and the pH of a solution was 5.0 for both heavy metal ions. One-component sorption equilibrium data were successfully presented for six of the most useful three-parameter equilibrium models: Langmuir-Freundlich, Redlich-Peterson, Sips, Koble-Corrigan, Hill and Toth. Extended forms of Langmuir-Freundlich, Koble-Corrigan and Sips models were also well fitted to the two-component equilibrium data obtained for different ratios of concentrations of Cu(II and Zn(II ions (1:1, 1:2, 2:1. Experimental sorption data were described by two kinetic models of the pseudo-first and pseudo-second order. Furthermore, an attempt to explain the mechanisms of the divalent metal ion sorption process on chitosan gel beads was undertaken.

  7. A nursing conceptual model for contamination.

    Science.gov (United States)

    Green, Pauline M; Polk, Laura V

    2012-02-01

    To propose a nursing model of contamination that describes the key features of contamination at a level of abstraction needed for clinical decision making. Relevant literature on contamination, biopreparedness, and classic epidemiologic literature were reviewed and analyzed. A model of contamination was created along with a description of benefits of use in practice, education, and research. The nursing profession is called to respond to contamination incidents on a local, national, and global level. Achieving optimum health outcomes while managing contamination incidents is enhanced by nurses' use of a model that incorporates six elements to identify and name instances of contamination and select suitable outcomes and interventions. © 2011, The Authors. International Journal of Nursing Knowledge © 2011, NANDA International.

  8. Modelling students' knowledge organisation: Genealogical conceptual networks

    Science.gov (United States)

    Koponen, Ismo T.; Nousiainen, Maija

    2018-04-01

    Learning scientific knowledge is largely based on understanding what are its key concepts and how they are related. The relational structure of concepts also affects how concepts are introduced in teaching scientific knowledge. We model here how students organise their knowledge when they represent their understanding of how physics concepts are related. The model is based on assumptions that students use simple basic linking-motifs in introducing new concepts and mostly relate them to concepts that were introduced a few steps earlier, i.e. following a genealogical ordering. The resulting genealogical networks have relatively high local clustering coefficients of nodes but otherwise resemble networks obtained with an identical degree distribution of nodes but with random linking between them (i.e. the configuration-model). However, a few key nodes having a special structural role emerge and these nodes have a higher than average communicability betweenness centralities. These features agree with the empirically found properties of students' concept networks.

  9. Sensitivity of Deep Soil Organic Carbon Age to Sorption, Transport and Microbial Interactions - Insights from a Calibrated Process Model

    Science.gov (United States)

    Ahrens, B.; Schrumpf, M.; Reichstein, M.

    2013-12-01

    Subsoil soil organic carbon (SOC) is characterized by conventional radiocarbon ages on the order of centuries to millennia. Most vertically explicit SOC turnover models represent this persistence of deep SOC by one pool that has millennial turnover times. This approach lumps different stabilizing mechanisms such as chemical recalcitrance, sorptive stabilization and energy limitation into a single rate constant. As an alternative, we present a continuous, vertically explicit SOC decomposition model that allows for stabilization via sorption and microbial interactions (COMISSION model). We compare the COMISSION model with the SOC profile of a Haplic Podzol under a Norway spruce forest. In the COMISSION model two pools receive aboveground litter input and vertically distributed root litter input. The readily leachable and soluble fraction of litter input enters a dissolved organic carbon pool (DOC), while the rest enters the residue pool which represents polymeric, non-soluble SOC. The residue pool is depolymerized with extracellular enzymes produced by a microbial pool to enter the DOC pool which represents SOC potentially available for assimilation by microbes. The adsorption/desorption of DOC from/to mineral surfaces controls the availability of carbon in the DOC pool for assimilatory uptake by microbes. The sorption of DOC is modeled with dynamic Langmuir equations. The desorbed part of the DOC pool not only constitutes the substrate for the microbial pool, but is also transported via advection. Interactions of microbes with the residue and DOC pool are modeled with Michaelis-Menten kinetics - this not only allows representing ';priming', but also the retardation of decomposition via energy limitation in the deep soil where substrate is scarce. Further, soil organic matter is recycled within the soil profile through microbial processing - dead microbes either enter the DOC or the residue pool, and thereby also contribute to longer residence times with soil depth

  10. A Conceptual Model of Investor Behavior

    NARCIS (Netherlands)

    M. Lovric (Milan); U. Kaymak (Uzay); J. Spronk (Jaap)

    2008-01-01

    textabstractBased on a survey of behavioral finance literature, this paper presents a descriptive model of individual investor behavior in which investment decisions are seen as an iterative process of interactions between the investor and the investment environment. This investment process is

  11. Learning strategies: a synthesis and conceptual model

    Science.gov (United States)

    Hattie, John A. C.; Donoghue, Gregory M.

    2016-08-01

    The purpose of this article is to explore a model of learning that proposes that various learning strategies are powerful at certain stages in the learning cycle. The model describes three inputs and outcomes (skill, will and thrill), success criteria, three phases of learning (surface, deep and transfer) and an acquiring and consolidation phase within each of the surface and deep phases. A synthesis of 228 meta-analyses led to the identification of the most effective strategies. The results indicate that there is a subset of strategies that are effective, but this effectiveness depends on the phase of the model in which they are implemented. Further, it is best not to run separate sessions on learning strategies but to embed the various strategies within the content of the subject, to be clearer about developing both surface and deep learning, and promoting their associated optimal strategies and to teach the skills of transfer of learning. The article concludes with a discussion of questions raised by the model that need further research.

  12. Designing Public Library Websites for Teens: A Conceptual Model

    Science.gov (United States)

    Naughton, Robin Amanda

    2012-01-01

    The main goal of this research study was to develop a conceptual model for the design of public library websites for teens (TLWs) that would enable designers and librarians to create library websites that better suit teens' information needs and practices. It bridges a gap in the research literature between user interface design in human-computer…

  13. Exploring conceptual models for community engagement at higher ...

    African Journals Online (AJOL)

    A critical conceptual analysis of the South African Higher Education context reflects the lack of a structural and functional framework for the conceptualisation of community engagement (CE) in higher education. The purpose of this article is to explore a framework and model for the conceptualisation of CE for a better ...

  14. LCM 3.0: A Language for describing Conceptual Models

    NARCIS (Netherlands)

    Feenstra, Remco; Wieringa, Roelf J.

    1993-01-01

    The syntax of the conceptual model specification language LCM is defined. LCM uses equational logic to specify data types and order-sorted dynamic logic to specify objects with identity and mutable state. LCM specifies database transactions as finite sets of atomic object transitions.

  15. A conceptual model specification language (CMSL Version 2)

    NARCIS (Netherlands)

    Wieringa, Roelf J.

    1992-01-01

    Version 2 of a language (CMSL) to specify conceptual models is defined. CMSL consists of two parts, the value specification language VSL and the object spercification language OSL. There is a formal semantics and an inference system for CMSL but research on this still continues. A method for

  16. A conceptual framework for a mentoring model for nurse educators ...

    African Journals Online (AJOL)

    Transformation in South Africa resulted in changes in the mandate of Higher Education Institutions (HEIs). Therefore, the need to design a mentoring model for recruiting and retaining nurse educators to meet the demands of teaching and learning became evident. The aim of the study was to develop a conceptual ...

  17. A New Conceptual Model for Understanding International Students' College Needs

    Science.gov (United States)

    Alfattal, Eyad

    2016-01-01

    This study concerns the theory and practice of international marketing in higher education with the purpose of exploring a conceptual model for understanding international students' needs in the context of a four-year college in the United States. A transcendental phenomenological design was employed to investigate the essence of international…

  18. Developing a Conceptual Model of STEAM Teaching Practices

    Science.gov (United States)

    Quigley, Cassie F.; Herro, Dani; Jamil, Faiza M.

    2017-01-01

    STEAM, where the "A" represents arts and humanities, is considered a transdisciplinary learning process that has the potential to increase diverse participation in science, technology, engineering, and math (STEM) fields. However, a well-defined conceptual model that clearly articulates essential components of the STEAM approach is…

  19. Conceptualizations of Creativity: Comparing Theories and Models of Giftedness

    Science.gov (United States)

    Miller, Angie L.

    2012-01-01

    This article reviews seven different theories of giftedness that include creativity as a component, comparing and contrasting how each one conceptualizes creativity as a part of giftedness. The functions of creativity vary across the models, suggesting that while the field of gifted education often cites the importance of creativity, the…

  20. Conceptual basis for developing of trainig models in complex ...

    African Journals Online (AJOL)

    This paper presents conceptual basis for developing of training models of interactive assembling system for automatic building of application software systems, obtained during practical works over "Design and architecture of software systems" and "Object-oriented analysis and design" courses. The system is intended for ...

  1. A Conceptual Model of Investor Behavior

    OpenAIRE

    Lovric, M.; Kaymak, U.; Spronk, J.

    2008-01-01

    textabstractBased on a survey of behavioral finance literature, this paper presents a descriptive model of individual investor behavior in which investment decisions are seen as an iterative process of interactions between the investor and the investment environment. This investment process is influenced by a number of interdependent variables and driven by dual mental systems, the interplay of which contributes to boundedly rational behavior where investors use various heuristics and may exh...

  2. Statistical equivalence of prediction models of the soil sorption coefficient obtained using different log P algorithms.

    Science.gov (United States)

    Olguin, Carlos José Maria; Sampaio, Silvio César; Dos Reis, Ralpho Rinaldo

    2017-10-01

    The soil sorption coefficient normalized to the organic carbon content (K oc ) is a physicochemical parameter used in environmental risk assessments and in determining the final fate of chemicals released into the environment. Several models for predicting this parameter have been proposed based on the relationship between log K oc and log P. The difficulty and cost of obtaining experimental log P values led to the development of algorithms to calculate these values, some of which are free to use. However, quantitative structure-property relationship (QSPR) studies did not detail how or why a particular algorithm was chosen. In this study, we evaluated several free algorithms for calculating log P in the modeling of log K oc , using a broad and diverse set of compounds (n = 639) that included several chemical classes. In addition, we propose the adoption of a simple test to verify if there is statistical equivalence between models obtained using different data sets. Our results showed that the ALOGPs, KOWWIN and XLOGP3 algorithms generated the best models for modeling K oc , and these models are statistically equivalent. This finding shows that it is possible to use the different algorithms without compromising statistical quality and predictive capacity. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Modeling in transport phenomena a conceptual approach

    CERN Document Server

    Tosun, Ismail

    2007-01-01

    Modeling in Transport Phenomena, Second Edition presents and clearly explains with example problems the basic concepts and their applications to fluid flow, heat transfer, mass transfer, chemical reaction engineering and thermodynamics. A balanced approach is presented between analysis and synthesis, students will understand how to use the solution in engineering analysis. Systematic derivations of the equations and the physical significance of each term are given in detail, for students to easily understand and follow up the material. There is a strong incentive in science and engineering to

  4. Conceptual design interpretations, mindset and models

    CERN Document Server

    Andreasen, Mogens Myrup; Cash, Philip

    2015-01-01

    Maximising reader insights into the theory, models, methods and fundamental reasoning of design, this book addresses design activities in industrial settings, as well as the actors involved. This approach offers readers a new understanding of design activities and related functions, properties and dispositions. Presenting a ‘design mindset’ that seeks to empower students, researchers, and practitioners alike, it features a strong focus on how designers create new concepts to be developed into products, and how they generate new business and satisfy human needs.   Employing a multi-faceted perspective, the book supplies the reader with a comprehensive worldview of design in the form of a proposed model that will empower their activities as student, researcher or practitioner. We draw the reader into the core role of design conceptualisation for society, for the development of industry, for users and buyers of products, and for citizens in relation to public systems. The book also features original con...

  5. Conceptual Models as Tools for Communication Across Disciplines

    Directory of Open Access Journals (Sweden)

    Marieke Heemskerk

    2003-12-01

    Full Text Available To better understand and manage complex social-ecological systems, social scientists and ecologists must collaborate. However, issues related to language and research approaches can make it hard for researchers in different fields to work together. This paper suggests that researchers can improve interdisciplinary science through the use of conceptual models as a communication tool. The authors share lessons from a workshop in which interdisciplinary teams of young scientists developed conceptual models of social-ecological systems using data sets and metadata from Long-Term Ecological Research sites across the United States. Both the process of model building and the models that were created are discussed. The exercise revealed that the presence of social scientists in a group influenced the place and role of people in the models. This finding suggests that the participation of both ecologists and social scientists in the early stages of project development may produce better questions and more accurate models of interactions between humans and ecosystems. Although the participants agreed that a better understanding of human intentions and behavior would advance ecosystem science, they felt that interdisciplinary research might gain more by training strong disciplinarians than by merging ecology and social sciences into a new field. It is concluded that conceptual models can provide an inspiring point of departure and a guiding principle for interdisciplinary group discussions. Jointly developing a model not only helped the participants to formulate questions, clarify system boundaries, and identify gaps in existing data, but also revealed the thoughts and assumptions of fellow scientists. Although the use of conceptual models will not serve all purposes, the process of model building can help scientists, policy makers, and resource managers discuss applied problems and theory among themselves and with those in other areas.

  6. Examination of a conceptual model of child neglect.

    Science.gov (United States)

    Dubowitz, Howard; Newton, Rae R; Litrownik, Alan J; Lewis, Terri; Briggs, Ernestine C; Thompson, Richard; English, Diana; Lee, Li-Ching; Feerick, Margaret M

    2005-05-01

    This study attempted to provide empirical support for conceptual definitions of child neglect. We identified 12 types of needs, conceptualizing neglect as occurring when children's basic needs are not adequately met. We examined measures administered to 377 children and caregivers at ages 4 and 6 years participating in longitudinal studies on child mal-treatment to identify potential indicators of these needs. Indicators were found for latent constructs, operationalizing three of the basic needs (emotional support and/or affection, protection from family conflict and/or violence, and from community violence). These latent constructs were used in a measurement model; this supported the conceptual definitions of neglect. A structural equation model then assessed whether the latent constructs were associated with child adjustment at age 8 years. Low level of perceived support from mother was associated with internalizing and externalizing behavior problems. Exposure to family conflict was also linked to these problems, and to social difficulties. Finally, children's sense of experiencing little early affection was associated with subsequent externalizing behavior and social problems. The approach of conceptualizing neglect in terms of unmet child needs, developing a measurement model to define latent neglect constructs, and relating these constructs to subsequent adjustment can build our understanding of neglect.

  7. Conceptual model innovation management: market orientation

    Directory of Open Access Journals (Sweden)

    L.Ya. Maljuta

    2015-06-01

    Full Text Available The article highlights issues that determine the beginning of the innovation process. Determined that until recently in Ukraine at all levels of innovation management (regional, sectoral, institutional dominated grocery orientation innovation that focus on production innovation and found that the transition to a market economy, the restructuring of production and complexity of social needs led to the strengthening of the consumer. It is proved that innovation itself – not the ultimate goal, but only a means of satisfying consumer needs. It proved that changing production conditions, complications of social needs and the need to improve the competitiveness of innovations require finding new forms of innovation. In this regard, proposed to allocate such basic scheme (model of innovation in small businesses, individual entrepreneurs, venture capital firms, eksplerents, patients, violents and commutants, spin-offs and spin-out company, network (or shell company and a network of small businesses.

  8. Collaborative Rural Healthcare Network: A Conceptual Model

    Directory of Open Access Journals (Sweden)

    U. Raja

    2011-07-01

    Full Text Available Healthcare is a critical issue in rural communities throughout the world. Provision of timely and cost effective health care in these communities is a challenge since it is coupled with a lack of adequate infrastructure and manpower support. Twenty percent of the United States of America‘s population resides in rural communities, i.e., 59 million people; however, only nine percent of the nation’s physicians practice in rural communities. Shortage of health care personnel and the lack of equipment and facilities often force rural residents to travel long distances to receive needed medical treatment. Researchers and practitioners are in search of solutions to address these unique challenges. In this research, we present a proposed collaborative model of a health information system for rural communities and the challenges and opportunities of this global issue.

  9. Conceptual model of male military sexual trauma.

    Science.gov (United States)

    Elder, William B; Domino, Jessica L; Rentz, Timothy O; Mata-Galán, Emma L

    2017-08-01

    Male sexual trauma is understudied, leaving much to be known about the unique mental health needs of male survivors. This study examined veteran men's perceptions of the effects of military sexual trauma. Military sexual trauma was defined as physically forced, verbally coerced, or substance-incapacitated acts experienced during military service. Interviews were conducted with 21 male veterans who reported experiencing military sexual trauma. Data were drawn together using a grounded theory methodology. Three categories emerged from data analysis, including (a) types of military sexual trauma (being touched in a sexual way against their will [N = 18]; sexual remarks directed at them [N = 15]; being physically forced to have sex [N = 13]); (b) negative life effects (difficulty trusting others [N = 18]; fear of abandonment [N = 17]; substance use [N = 13]; fear of interpersonal violence [N = 12]; conduct and vocational problems [N = 11]; irritability/aggression [N = 8]; insecurity about sexual performance [N = 8]; difficulty managing anger [N = 8]); and (c) posttraumatic growth (N = 15). Results from this study suggest sexual trauma in the military context may affect systems of self-organization, specifically problems in affective, self-concept, and relational domains, similar to symptoms of those who have experienced prolonged traumatic stressors. This model can be used by clinicians to select treatments that specifically target these symptoms and promote posttraumatic growth. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

  10. Trade-offs underlying maternal breastfeeding decisions: A conceptual model

    OpenAIRE

    Tully, Kristin P.; Ball, Helen L.

    2011-01-01

    This paper presents a new conceptual model that generates predictions about breastfeeding decisions and identifies interactions that affect outcomes. We offer a contextual approach to infant feeding that models multi-directional influences by expanding on the evolutionary parent–offspring conflict and situation-specific breastfeeding theories. The main hypothesis generated from our framework suggests that simultaneously addressing breastfeeding costs and benefits, in relation to how they are ...

  11. A Traceability-based Method to Support Conceptual Model Evolution

    OpenAIRE

    Ruiz Carmona, Luz Marcela

    2014-01-01

    Renewing software systems is one of the most cost-effective ways to protect software investment, which saves time, money and ensures uninter- rupted access to technical support and product upgrades. There are several mo- tivations to promote investment and scientific effort for specifying systems by means of conceptual models and supporting its evolution. As an example, the software engineering community is addressing solutions for supporting model traceability, continuous improvement of busi...

  12. Elements of a flexible approach for conceptual hydrological modeling : 1. Motivation and theoretical development

    NARCIS (Netherlands)

    Fenicia, F.; Kavetski, D.; Savenije, H.H.G.

    2011-01-01

    This paper introduces a flexible framework for conceptual hydrological modeling, with two related objectives: (1) generalize and systematize the currently fragmented field of conceptual models and (2) provide a robust platform for understanding and modeling hydrological systems. In contrast to

  13. Modeling Np and Pu transport with a surface complexation model and spatially variant sorption capacities: Implications for reactive transport modeling and performance assessments of nuclear waste disposal sites

    Science.gov (United States)

    Glynn, P.D.

    2003-01-01

    One-dimensional (1D) geochemical transport modeling is used to demonstrate the effects of speciation and sorption reactions on the ground-water transport of Np and Pu, two redox-sensitive elements. Earlier 1D simulations (Reardon, 1981) considered the kinetically limited dissolution of calcite and its effect on ion-exchange reactions (involving 90Sr, Ca, Na, Mg and K), and documented the spatial variation of a 90Sr partition coefficient under both transient and steady-state chemical conditions. In contrast, the simulations presented here assume local equilibrium for all reactions, and consider sorption on constant potential, rather than constant charge, surfaces. Reardon's (1981) seminal findings on the spatial and temporal variability of partitioning (of 90Sr) are reexamined and found partially caused by his assumption of a kinetically limited reaction. In the present work, sorption is assumed the predominant retardation process controlling Pu and Np transport, and is simulated using a diffuse-double-layer-surface-complexation (DDLSC) model. Transport simulations consider the infiltration of Np- and Pu-contaminated waters into an initially uncontaminated environment, followed by the cleanup of the resultant contamination with uncontaminated water. Simulations are conducted using different spatial distributions of sorption capacities (with the same total potential sorption capacity, but with different variances and spatial correlation structures). Results obtained differ markedly from those that would be obtained in transport simulations using constant Kd, Langmuir or Freundlich sorption models. When possible, simulation results (breakthrough curves) are fitted to a constant K d advection-dispersion transport model and compared. Functional differences often are great enough that they prevent a meaningful fit of the simulation results with a constant K d (or even a Langmuir or Freundlich) model, even in the case of Np, a weakly sorbed radionuclide under the

  14. Conceptual Commitments of the LIDA Model of Cognition

    Science.gov (United States)

    Franklin, Stan; Strain, Steve; McCall, Ryan; Baars, Bernard

    2013-06-01

    Significant debate on fundamental issues remains in the subfields of cognitive science, including perception, memory, attention, action selection, learning, and others. Psychology, neuroscience, and artificial intelligence each contribute alternative and sometimes conflicting perspectives on the supervening problem of artificial general intelligence (AGI). Current efforts toward a broad-based, systems-level model of minds cannot await theoretical convergence in each of the relevant subfields. Such work therefore requires the formulation of tentative hypotheses, based on current knowledge, that serve to connect cognitive functions into a theoretical framework for the study of the mind. We term such hypotheses "conceptual commitments" and describe the hypotheses underlying one such model, the Learning Intelligent Distribution Agent (LIDA) Model. Our intention is to initiate a discussion among AGI researchers about which conceptual commitments are essential, or particularly useful, toward creating AGI agents.

  15. Sorption of diclofenac and naproxen onto MWCNT in model wastewater treated by H2O2 and/or UV.

    Science.gov (United States)

    Czech, Bożena; Oleszczuk, Patryk

    2016-04-01

    The application of oxidation processes such as UV and/or H2O2 will change the physicochemical properties of carbon nanotubes (CNT). It may affect the sorption affinity of CNT to different contaminants and then affect their fate in the environment. In the present study the adsorption of two very common used pharmaceuticals (diclofenac and naproxen) onto CNT treated by UV, H2O2 or UV/H2O2 was investigated. Four different adsorption models (Freundlich, Langmuir, Temkin, Dubinin-Radushkevich) were tested. The best fitting of experimental data was observed for Freundlich or Langmuir model. The significant relationships between Q calculated from Langmuir model with O% and dispersity were observed. Kinetics of diclofenac and naproxen followed mainly pseudo-second order indicating for chemisorption limiting step of adsorption. The data showed that the mechanism of sorption was physical or chemical depending on the type of CNT modification. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. Surface complexation modeling of U(VI) sorption on GMZ bentonite in the presence of fulvic acid

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Jie [Lanzhou Univ. (China). Radiochemistry Laboratory; Ministry of Industry and Information Technology, Guangzhou (China). The 5th Electronics Research Inst.; Luo, Daojun [Ministry of Industry and Information Technology, Guangzhou (China). The 5th Electronics Research Inst.; Qiao, Yahua; Wang, Liang; Zhang, Chunming [Ministry of Environmental Protection, Beijing (China). Nuclear and Radiation Safety Center; Wu, Wangsuo [Lanzhou Univ. (China). Radiochemistry Laboratory; Ye, Yuanlv [Ministry of Environmental Protection, Beijing (China). Nuclear and Radiation Safety Center; Lanzhou Univ. (China). Radiochemistry Laboratory

    2017-03-01

    In this work, experiments and modeling for the interactions between uranyl ion and GMZ bentonite in the presence of fulvic acid are presented. The results demonstrated that FA is strongly bound to GMZ bentonite, and these molecules have a very large effect on the U(VI) sorption. The results also demonstrated that U(VI) sorption to GMZ bentonite in the presence and absence of sorbed FA can be well predicted by combining SHM and DLM. According to the model calculations, the nature of the interactions between FA with U(VI) at GMZ bentonite surface is mainly surface complex. The first attempt to simulate clay interaction with humus by the SHM model.

  17. Application of surface complexation modelling: Nickel sorption on quartz, manganese oxide, kaolinite and goethite, and thorium on silica

    International Nuclear Information System (INIS)

    Olin, M.; Lehikoinen, J.

    1997-12-01

    The study is a follow-up to a previous modelling task on mechanistic sorption. The experimental work has been carried out at the Laboratory of Radiochemistry, University of Helsinki (HYRL), and the sorption modelling was performed using the HYDRAQL code. Parameters taken from the open literature were employed in the modelling phase. The thermodynamic data for aqueous solutions were extracted from the EQ3/6 database and subsequently modified for HYDRAQL where necessary. The experimental data were obtained from five different experiments, four of which concerned the adsorption of nickel. The first experimental system was a mixture of Nilsiae quartz and manganese dioxide. In the second experiment, quartz was equilibrated with a fresh and saline groundwater simulant instead of an electrolyte solution. The third and fourth experiments dealt with nickel adsorption from an electrolyte solution onto goethite and kaolinite surfaces respectively. In the fifth experiment, adsorption of thorium onto a quartz surface was investigated

  18. Conceptual Model of Iodine Behavior in the Subsurface at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lee, Brady D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Johnson, Christian D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qafoku, Nikolla [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Szecsody, James E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kyle, Jennifer E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tfaily, Malak M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snyder, Michelle MV [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Saunders, Danielle L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawter, Amanda R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Oostrom, Martijn L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tartakovsky, Guzel D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Leavy, Ian I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); McElroy, Erin M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Appriou, Delphine [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sahajpal, Rahul [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Carroll, Matthew M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Chu, Rosalie K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Cordova, Elsa [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Last, George V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lee, Hope [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kaplan, Daniel I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Garcia, Whitney L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kerisit, Sebastien N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qafoku, Odeta [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bowden, Mark E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Smith, Frances N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Toyoda, Jason G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Plymale, Andrew E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2017-09-01

    Isotopes of iodine were generated during plutonium production within the nine production reactors at the U.S. Department of Energy Hanford Site. The short half-life 131I that was released from the fuel into the atmosphere during the dissolution process (when the fuel was dissolved) in the Hanford Site 200 Area is no longer present at concentrations of concern in the environment. The long half-life 129I generated at the Hanford Site during reactor operations was (1) stored in single-shell and double-shell tanks, (2) discharged to liquid disposal sites (e.g., cribs and trenches), (3) released to the atmosphere during fuel reprocessing operations, or (4) captured by off-gas absorbent devices (silver reactors) at chemical separations plants (PUREX, B-Plant, T-Plant, and REDOX). Releases of 129I to the subsurface have resulted in several large, though dilute, plumes in the groundwater. There is also 129I remaining in the vadose zone beneath disposal or leak locations. The fate and transport of 129I in the environment and potential remediation technologies are currently being studied as part of environmental remediation activities at the Hanford Site. A conceptual model describing the nature and extent of subsurface contamination, factors that control plume behavior, and factors relevant to potential remediation processes is needed to support environmental remedy decisions. Because 129I is an uncommon contaminant, relevant remediation experience and scientific literature are limited. In addition, its behavior in subsurface is different from that of other more common and important contaminants (e.g., U, Cr and Tc) in terms of sorption (adsorption and precipitation), and aqueous phase species transformation via redox reactions. Thus, the conceptual model also needs to both describe known contaminant and biogeochemical process information and identify aspects about which additional information is needed to effectively support remedy decisions.

  19. Promoting Conceptual Coherence in Quantum Learning through Computational Models

    Science.gov (United States)

    Lee, Hee-Sun

    2012-02-01

    In order to explain phenomena at the quantum level, scientists use multiple representations in verbal, pictorial, mathematical, and computational forms. Conceptual coherence among these multiple representations is used as an analytical framework to describe student learning trajectories in quantum physics. A series of internet-based curriculum modules are designed to address topics in quantum mechanics, semiconductor physics, and nano-scale engineering applications. In these modules, students are engaged in inquiry-based activities situated in a highly interactive computational modeling environment. This study was conducted in an introductory level solid state physics course. Based on in-depth interviews with 13 students, methods for identifying conceptual coherence as a function of students' level of understanding are presented. Pre-post test comparisons of 20 students in the course indicate a statistically significant improvement in students' conceptual coherence of understanding quantum phenomena before and after the course, Effect Size = 1.29 SD. Additional analyses indicate that students who responded to the modules more coherently improved their conceptual coherence to a greater extent than those who did less to the modules after controlling for their course grades.

  20. Conceptual Model of the Globalization for Domain-Specific Languages

    OpenAIRE

    Clark, Tony; Van Den Brand, Mark; Combemale, Benoit; Rumpe, Bernhard

    2015-01-01

    International audience; Domain Specific Languages (DSL) have received some prominence recently. Designing a DSL and all their tools is still cumbersome and lots of work. Engineering of DSLs is still at infancy, not even the terms have been coined and agreed on. In particular globalization and all its consequences need to be precisely defined and discussed. This chapter provides a definition of the relevant terms and relates them, such that a conceptual model emerges. The authors think that th...

  1. Advanced practice nursing and conceptual models of nursing.

    Science.gov (United States)

    Fawcett, Jacqueline; Newman, Diana M L; McAllister, Margaret

    2004-04-01

    This column focuses on advanced practice nursing. A definition and central competency of advanced practice are given and four roles assumed by advanced practice nurses are identified. Questions related primarily to the advanced practice role of nurse practitioner are raised. Two nurse scholars who teach and practice discuss their experiences as advanced practice nurses, with an emphasis on the importance of using a conceptual model of nursing as a guide for their practice.

  2. Fatigue in fibromyalgia: a conceptual model informed by patient interviews

    DEFF Research Database (Denmark)

    Humphrey, Louise; Arbuckle, Rob; Mease, Philip

    2010-01-01

    Fatigue is increasingly recognized as an important symptom in fibromyalgia (FM). Unknown however is how fatigue is experienced by individuals in the context of FM. We conducted qualitative research in order to better understand aspects of fatigue that might be unique to FM as well as the impact...... it has on patients' lives. The data obtained informed the development of a conceptual model of fatigue in FM....

  3. Identification of Chemistry Learning Problems Viewed From Conceptual Change Model

    OpenAIRE

    Redhana, I. W; Sudria, I. B. N; Hidayat, I; Merta, L. M

    2017-01-01

    This study aimed at describing and explaining chemistry learning problems viewed from conceptual change model and misconceptions of students. The study was qualitative research of case study type conducted in one class of SMAN 1 Singaraja. Subjects of the study were a chemistry teacher and students. Data were obtained through classroom observation, interviews, and conception tests. The chemistry learning problems were grouped based on aspects of necessity, intelligibility, plausibility, and f...

  4. Conceptual Model of Climate Change Impacts at LANL

    Energy Technology Data Exchange (ETDEWEB)

    Dewart, Jean Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-05-17

    Goal 9 of the LANL FY15 Site Sustainability Plan (LANL 2014a) addresses Climate Change Adaptation. As part of Goal 9, the plan reviews many of the individual programs the Laboratory has initiated over the past 20 years to address climate change impacts to LANL (e.g. Wildland Fire Management Plan, Forest Management Plan, etc.). However, at that time, LANL did not yet have a comprehensive approach to climate change adaptation. To fill this gap, the FY15 Work Plan for the LANL Long Term Strategy for Environmental Stewardship and Sustainability (LANL 2015) included a goal of (1) establishing a comprehensive conceptual model of climate change impacts at LANL and (2) establishing specific climate change indices to measure climate change and impacts at Los Alamos. Establishing a conceptual model of climate change impacts will demonstrate that the Laboratory is addressing climate change impacts in a comprehensive manner. This paper fulfills the requirement of goal 1. The establishment of specific indices of climate change at Los Alamos (goal 2), will improve our ability to determine climate change vulnerabilities and assess risk. Future work will include prioritizing risks, evaluating options/technologies/costs, and where appropriate, taking actions. To develop a comprehensive conceptual model of climate change impacts, we selected the framework provided in the National Oceanic and Atmospheric Administration (NOAA) Climate Resilience Toolkit (http://toolkit.climate.gov/).

  5. Incorporating agricultural land cover in conceptual rainfall runoff models

    Science.gov (United States)

    Euser, Tanja; Hrachowitz, Markus; Winsemius, Hessel; Savenije, Hubert

    2015-04-01

    Incorporating spatially variable information is a frequently discussed option to increase the performance of (semi) distributed conceptual rainfall runoff models. One of the methods to do this is by using these spatially variable information to delineate Hydrological Response Units (HRUs) within a catchment. This study tests whether the incorporation of an additional agricultural HRU in a conceptual hydrological model can better reflect the spatial differences in runoff generation and therefore improve the simulation of the wetting phase in autumn. The study area is the meso-scale Ourthe catchment in Belgium. A previous study in this area showed that spatial patterns in runoff generation were already better represented by incorporation of a wetland and a hillslope HRU, compared to a lumped model structure. The influences which are considered by including an agriculture HRU are increased drainage speed due to roads, plough pans and increased infiltration excess overland flow (drainage pipes area only limited present), and variable vegetation patterns due to sowing and harvesting. In addition, the vegetation is not modelled as a static resistance towards evaporation, but the Jarvis stress functions are used to increase the realism of the modelled transpiration; in land-surface models the Jarvis stress functions are already often used for modelling transpiration. The results show that an agricultural conceptualisation in addition to wetland and hillslope conceptualisations leads to small improvements in the modelled discharge. However, the influence is larger on the representation of spatial patterns and the modelled contributions of different HRUs to the total discharge.

  6. Risk assessment of pesticide transport with water erosion: A conceptual model

    Science.gov (United States)

    Yang, Xiaomei; Van Der Zee, Sjoerd E. A. T. M.; Gai, Lingtong; Wesseling, Jan G.; Ritsema, Coen J.; Geissen, Violette

    2017-04-01

    Pesticides are widely used in agriculture, horticulture, and forestry, and pesticide pollution has become an important issue worldwide. Entraining in runoff and being attached to eroded soil particles, posing a risk to water and soil quality and human health. In order to assess the risk of pesticide during water erosion processes, a simple integrative model of pesticide transport by runoff and erosion was developed. Taking soil hydrological and pesticide behaviour into account, such as water infiltration, erosion, runoff, and pesticide transport and degradation in soil, the conceptual framework was based on the known assumptions such as the convection-dispersion equation and lognormal distributions of soil properties associated with transport, sorption, degradation, and erosion. A sensitivity analysis was conducted and the results indicated that the total amount of pesticide related to soil eroded by water washing increased with slope gradient, rainfall intensity, and water field capacity of the soil. The mass of transported pesticide decreased as the micro-topography of the soil surface became obviously and the time from pesticide sprayed to erosion occurring associated with pesticide degradation negatively influenced the total amount of transported pesticide. The mechanisms involved in pesticide transport, such as runoff, infiltration, soil erosion, and pesticide transport and decay in the topsoil, thus can be well accounted for pesticide risk assessment especially in the region with intensive pesticide use and soil water erosion events.

  7. Conceptual Model of Quantities, Units, Dimensions, and Values

    Science.gov (United States)

    Rouquette, Nicolas F.; DeKoenig, Hans-Peter; Burkhart, Roger; Espinoza, Huascar

    2011-01-01

    JPL collaborated with experts from industry and other organizations to develop a conceptual model of quantities, units, dimensions, and values based on the current work of the ISO 80000 committee revising the International System of Units & Quantities based on the International Vocabulary of Metrology (VIM). By providing support for ISO 80000 in SysML via the International Vocabulary of Metrology (VIM), this conceptual model provides, for the first time, a standard-based approach for addressing issues of unit coherence and dimensional analysis into the practice of systems engineering with SysML-based tools. This conceptual model provides support for two kinds of analyses specified in the International Vocabulary of Metrology (VIM): coherence of units as well as of systems of units, and dimension analysis of systems of quantities. To provide a solid and stable foundation, the model for defining quantities, units, dimensions, and values in SysML is explicitly based on the concepts defined in VIM. At the same time, the model library is designed in such a way that extensions to the ISQ (International System of Quantities) and SI Units (Systeme International d Unites) can be represented, as well as any alternative systems of quantities and units. The model library can be used to support SysML user models in various ways. A simple approach is to define and document libraries of reusable systems of units and quantities for reuse across multiple projects, and to link units and quantity kinds from these libraries to Unit and QuantityKind stereotypes defined in SysML user models.

  8. Kinetics, equilibrium data and modeling studies for the sorption of chromium by Prosopis juliflora bark carbon

    Directory of Open Access Journals (Sweden)

    M. Kumar

    2017-05-01

    Full Text Available In this study, the activated carbon was prepared from Prosopis juliflora bark as a novel adsorbent. Removal of chromium (Cr was assessed by varying the parameters like metal concentration, temperature, pH, adsorbent dose and contact time. The feasibility of the sorption was studied using Freundlich and Langmuir isotherms including linear and non-linear regression methods. In Langmuir, various forms of linearized equations were evaluated. The isotherm parameter of dimensionless separation factor (RL was also studied. The kinetics of adsorption was studied by using Lagergren’s pseudo-first order and pseudo-second order equations and the results have shown that the adsorption process follows pseudo-second order kinetics and the adsorption process depends on both time and concentration. The mechanistic pathway of the adsorption process was evaluated with intraparticle diffusion model. The effect of heat of adsorption of the adsorbate onto the adsorbent material was determined using the thermodynamic parameters and the reusability of the adsorbent materials was ascertained with desorption studies. The adsorbent material characterization was done by using Fourier Transform Infrared Spectroscopy (FTIR, X-ray Diffraction (XRD method and morphology of the surface of adsorbent was identified with Scanning Electron Microscope (SEM.

  9. On conceptual differentiation and integration of strategy and business model

    Directory of Open Access Journals (Sweden)

    Ivan Stefanovic

    2012-06-01

    Full Text Available The objective of this paper is to develop the conceptual integration of strategy and business model. Theoretical method is used in order to achieve this objective. The theory building leads to the construction of conceptual model of strategy and business model, and provides its underlying logic. The main finding is that strategy is a pattern within which a business model changes. Only one strategy may exist for a firm in a concrete time frame, while there may be countless business models in the same period. Therefore, strategy represents the sum of all business models and their changes within a specified period. Each business model matches the set of functional strategies and their interdependencies, making strategic content in some particular moment, i.e. each business model is actually a bisection of the business strategy or a bisection of a set of functional strategies in one concrete moment. This specific contribution can be understood only if one takes an appropriate viewpoint of the process of strategy formation, namely the reactive perspective.

  10. Structure and Thermodynamics of Carbon Dioxide Sorption in Silica Pores from Experiments and Computer Models

    Science.gov (United States)

    Vlcek, L.; Rother, G.; Chialvo, A.; Cole, D. R.

    2011-12-01

    Injection of CO2 into geologic formations has been proposed as a key element to reduce the impact of greenhouse gases emissions. Quantitative understanding of CO2 adsorption in porous mineral environments at thermodynamic conditions relevant to proposed sequestration sites is thus a prerequisite for the assessment of their viability. In this study we use a combination of neutron scattering, adsorption experiments, and computer modeling to investigate the thermodynamics of near-critical carbon dioxide in the pores of SiO2 aerogel, which serves as a model of a high-porosity reservoir rock. Small angle neutron scattering (SANS) experiments provide input for the optimization of the computer model of the aerogel matrix, and also serve as a sensitive probe of local density changes of confined CO2 as a function of external pressure. Additional details of the aerogel basic building blocks and SiO2 surface are derived from TEM images. An independent source of global adsorption data is obtained from gravimetric experiments. The structural and thermodynamic aspects of CO2 sorption are linked using computer simulations, which include the application of the optimized diffusion limited cluster-cluster aggregation algorithm (DLCA), classical density functional theory (DFT) modeling of large-scale CO2 density profiles, and molecular dynamics simulations of the details of interactions between CO2 molecules and the amorphous silica surfaces. This integrated approach allows us to span scales ranging from 1Å to 1μm, as well as to infer the detailed structure of silica threads forming the framework of the silica matrix.

  11. Conceptual Models in Health Informatics Research: A Literature Review and Suggestions for Development.

    Science.gov (United States)

    Gray, Kathleen; Sockolow, Paulina

    2016-02-24

    Contributing to health informatics research means using conceptual models that are integrative and explain the research in terms of the two broad domains of health science and information science. However, it can be hard for novice health informatics researchers to find exemplars and guidelines in working with integrative conceptual models. The aim of this paper is to support the use of integrative conceptual models in research on information and communication technologies in the health sector, and to encourage discussion of these conceptual models in scholarly forums. A two-part method was used to summarize and structure ideas about how to work effectively with conceptual models in health informatics research that included (1) a selective review and summary of the literature of conceptual models; and (2) the construction of a step-by-step approach to developing a conceptual model. The seven-step methodology for developing conceptual models in health informatics research explained in this paper involves (1) acknowledging the limitations of health science and information science conceptual models; (2) giving a rationale for one's choice of integrative conceptual model; (3) explicating a conceptual model verbally and graphically; (4) seeking feedback about the conceptual model from stakeholders in both the health science and information science domains; (5) aligning a conceptual model with an appropriate research plan; (6) adapting a conceptual model in response to new knowledge over time; and (7) disseminating conceptual models in scholarly and scientific forums. Making explicit the conceptual model that underpins a health informatics research project can contribute to increasing the number of well-formed and strongly grounded health informatics research projects. This explication has distinct benefits for researchers in training, research teams, and researchers and practitioners in information, health, and other disciplines.

  12. Conceptual Models in Health Informatics Research: A Literature Review and Suggestions for Development

    Science.gov (United States)

    2016-01-01

    Background Contributing to health informatics research means using conceptual models that are integrative and explain the research in terms of the two broad domains of health science and information science. However, it can be hard for novice health informatics researchers to find exemplars and guidelines in working with integrative conceptual models. Objectives The aim of this paper is to support the use of integrative conceptual models in research on information and communication technologies in the health sector, and to encourage discussion of these conceptual models in scholarly forums. Methods A two-part method was used to summarize and structure ideas about how to work effectively with conceptual models in health informatics research that included (1) a selective review and summary of the literature of conceptual models; and (2) the construction of a step-by-step approach to developing a conceptual model. Results The seven-step methodology for developing conceptual models in health informatics research explained in this paper involves (1) acknowledging the limitations of health science and information science conceptual models; (2) giving a rationale for one’s choice of integrative conceptual model; (3) explicating a conceptual model verbally and graphically; (4) seeking feedback about the conceptual model from stakeholders in both the health science and information science domains; (5) aligning a conceptual model with an appropriate research plan; (6) adapting a conceptual model in response to new knowledge over time; and (7) disseminating conceptual models in scholarly and scientific forums. Conclusions Making explicit the conceptual model that underpins a health informatics research project can contribute to increasing the number of well-formed and strongly grounded health informatics research projects. This explication has distinct benefits for researchers in training, research teams, and researchers and practitioners in information, health, and other

  13. National Identity: Conceptual models, discourses and political change

    DEFF Research Database (Denmark)

    Harder, Peter

    2014-01-01

    Cognitive Linguistics has demonstrated the applicability of a conceptual approach to the understanding of political issues, cf. Lakoff (2008) and many others. From a different perspective, critical discourse analysis has approached political concepts with a focus on issues involving potentially...... in Harder (2010), however, both the analytic stance of critical discourse analysis (based on the hermeneutics of suspicion), and the cognitivist stance of Lakoff (2008) are too narrow: The understanding of political language requires a wider framework of social cognitive linguistics. Essential features...... of conceptual models or discourses. This is especially important in cases that involve conflictive political issues such as national and ethnic identity. The article reports on a historical project with a linguistic dimension in my department (PI Stuart Ward, cf. Ward 2004), which aims to throw light...

  14. Conceptual Modeling in the Time of the Revolution: Part II

    Science.gov (United States)

    Mylopoulos, John

    Conceptual Modeling was a marginal research topic at the very fringes of Computer Science in the 60s and 70s, when the discipline was dominated by topics focusing on programs, systems and hardware architectures. Over the years, however, the field has moved to centre stage and has come to claim a central role both in Computer Science research and practice in diverse areas, such as Software Engineering, Databases, Information Systems, the Semantic Web, Business Process Management, Service-Oriented Computing, Multi-Agent Systems, Knowledge Management, and more. The transformation was greatly aided by the adoption of standards in modeling languages (e.g., UML), and model-based methodologies (e.g., Model-Driven Architectures) by the Object Management Group (OMG) and other standards organizations. We briefly review the history of the field over the past 40 years, focusing on the evolution of key ideas. We then note some open challenges and report on-going research, covering topics such as the representation of variability in conceptual models, capturing model intentions, and models of laws.

  15. A Conceptual Model of eLearning Adoption

    Directory of Open Access Journals (Sweden)

    Muneer Abbad

    2011-05-01

    Full Text Available Internet-based learning systems are being used in many universities and firms but their adoption requires a solid understanding of the user acceptance processes. The technology acceptance model (TAM has been used to test the acceptance of various technologies and software within an e-learning context. This research aims to discuss the main factors of a successful e-learning adoption by students. A conceptual research framework of e-learning adoption is proposed based on the TAM model.

  16. A Conceptual Model for Multidimensional Analysis of Documents

    Science.gov (United States)

    Ravat, Franck; Teste, Olivier; Tournier, Ronan; Zurlfluh, Gilles

    Data warehousing and OLAP are mainly used for the analysis of transactional data. Nowadays, with the evolution of Internet, and the development of semi-structured data exchange format (such as XML), it is possible to consider entire fragments of data such as documents as analysis sources. As a consequence, an adapted multidimensional analysis framework needs to be provided. In this paper, we introduce an OLAP multidimensional conceptual model without facts. This model is based on the unique concept of dimensions and is adapted for multidimensional document analysis. We also provide a set of manipulation operations.

  17. Conceptual modelling of evapotranspiration for simulations of climate change effects

    Energy Technology Data Exchange (ETDEWEB)

    Lindstroem, G.; Gardelin, M.; Persson, Magnus

    1994-09-01

    The evapotranspiration routines in existing conceptual hydrological models have been identified as one of the weaknesses which appear when these models are used for the simulation of hydrological effects of a changing climate. The hydrological models in operational use today usually have a very superficial description of evapotranspiration. They have, nevertheless, been able to yield reasonable results. The objective of this paper is to analyse and suggest modifications of existing evapotranspiration routines in conceptual hydrological models to make them more appropriate for use in simulation of the effects of a changing climate on water resources. The following modifications of the evapotranspiration routine were formulated and tested in the HBV model: Temperature anomaly correction of evapotranspiration, potential evapotranspiration by a simplified Thornthwaite type formula, interception submodel, spatially distributed evapotranspiration routine and alternative formulations of lake evapotranspiration. Sensitivity analyses were thereafter made to illustrate the effects of uncertainty in the hydrological model structure versus those of the uncertainty in the climate change predictions. 34 refs, 15 figs, 6 tabs

  18. A Conceptual Culture Model for Design Science Research

    Directory of Open Access Journals (Sweden)

    Thomas Richter

    2016-03-01

    Full Text Available The aim of design science research (DSR in information systems is the user-centred creation of IT-artifacts with regard to specific social environments. For culture research in the field, which is necessary for a proper localization of IT-artifacts, models and research approaches from social sciences usually are adopted. Descriptive dimension-based culture models most commonly are applied for this purpose, which assume culture being a national phenomenon and tend to reduce it to basic values. Such models are useful for investigations in behavioural culture research because it aims to isolate, describe and explain culture-specific attitudes and characteristics within a selected society. In contrast, with the necessity to deduce concrete decisions for artifact-design, research results from DSR need to go beyond this aim. As hypothesis, this contribution generally questions the applicability of such generic culture dimensions’ models for DSR and focuses on their theoretical foundation, which goes back to Hofstede’s conceptual Onion Model of Culture. The herein applied literature-based analysis confirms the hypothesis. Consequently, an alternative conceptual culture model is being introduced and discussed as theoretical foundation for culture research in DSR.

  19. Conceptual models of microseismicity induced by fluid injection

    Science.gov (United States)

    Baro Urbea, J.; Lord-May, C.; Eaton, D. W. S.; Joern, D.

    2017-12-01

    Variations in the pore pressure due to fluid invasion are accountable for microseismic activity recorded in geothermal systems and during hydraulic fracturing operations. To capture this phenomenon on a conceptual level, invasion percolation models have been suggested to represent the flow network of fluids within a porous media and seismic activity is typically considered to be directly related to the expansion of the percolated area. Although such models reproduce scale-free frequency-magnitude distributions, the associated b-values of the Gutenberg-Richter relation do not align with observed data. Here, we propose an alternative conceptual invasion percolation model that decouples the fluid propagation from the microseismic events. Instead of a uniform pressure, the pressure is modeled to decay along the distance from the injection site. Wet fracture events are simulated with a stochastic spring block model exhibiting stick-slip dynamics as a result of the variations of the pore pressure. We show that the statistics of the stick-slip events are scale-free, but now the b-values depend on the level of heterogeneity in the local static friction coefficients. Thus, this model is able to reproduce the wide spectrum of b-values observed in field catalogs associated with fluid induced microseismicity. Moreover, the spatial distribution of microseismic events is also consistent with observations.

  20. A Conceptual Model for Engagement of the Online Learner

    Directory of Open Access Journals (Sweden)

    Lorraine M. Angelino

    2009-01-01

    Full Text Available Engagement of the online learner is one approach to reduce attrition rates. Attrition rates for classes taught through distance education are 10 – 20% higher than classes taught in a face-to-face setting. This paper introduces a Model for Engagement and provides strategies to engage the online learner. The Model depicts various opportunities where student-instructor, student-student, student-content, and student-community engagement can occur. The Model is divided into four strategic areas: (a recruitment, (b coursework, (c post coursework, and (d alumni. The theoretical framework for the model is Tinto‟s student integration model. The conceptual design of the model is based on engagement practices from an online Health Care Management (HCMT certificate program at a university in South Carolina.

  1. Regional knowledge economy development indicative planning system conceptual model

    Directory of Open Access Journals (Sweden)

    Elena Davidovna Vaisman

    2012-12-01

    Full Text Available The subject of the research is the processes of Russian knowledge economy development, its progress on the regional level is taken as a theme, which determined the purpose of research: development of the regional knowledge economy development indicative planning method conceptual model. The methodological base of the research is the knowledge economy concept and supply and demand theory, the methods of comparative and system analysis and theoretical modeling; common generalization and classification methods and regression models are used in the work. As a result, we managed to create the regional knowledge economy development indicative planning method conceptual model, which includes the choice of the types of indicative plans and the justification for the complex of indicators according to the stated requirements to this complex. The model of supply and demand for knowledge dependency from the knowledge cost, allowing to determine the acceptable range for the indicators proceeding from the demand and supply levels and their interrelation, is developed. The obtained results may be used by the regional government authorities while planning the regional innovative development and consulting companies while making the proposals for this development

  2. Our evolving conceptual model of the coastal eutrophication problem

    Science.gov (United States)

    Cloern, James E.

    2001-01-01

    A primary focus of coastal science during the past 3 decades has been the question: How does anthropogenic nutrient enrichment cause change in the structure or function of nearshore coastal ecosystems? This theme of environmental science is recent, so our conceptual model of the coastal eutrophication problem continues to change rapidly. In this review, I suggest that the early (Phase I) conceptual model was strongly influenced by limnologists, who began intense study of lake eutrophication by the 1960s. The Phase I model emphasized changing nutrient input as a signal, and responses to that signal as increased phytoplankton biomass and primary production, decomposition of phytoplankton-derived organic matter, and enhanced depletion of oxygen from bottom waters. Coastal research in recent decades has identified key differences in the responses of lakes and coastal-estuarine ecosystems to nutrient enrichment. The contemporary (Phase II) conceptual model reflects those differences and includes explicit recognition of (1) system-specific attributes that act as a filter to modulate the responses to enrichment (leading to large differences among estuarine-coastal systems in their sensitivity to nutrient enrichment); and (2) a complex suite of direct and indirect responses including linked changes in: water transparency, distribution of vascular plants and biomass of macroalgae, sediment biogeochemistry and nutrient cycling, nutrient ratios and their regulation of phytoplankton community composition, frequency of toxic/harmful algal blooms, habitat quality for metazoans, reproduction/growth/survival of pelagic and benthic invertebrates, and subtle changes such as shifts in the seasonality of ecosystem functions. Each aspect of the Phase II model is illustrated here with examples from coastal ecosystems around the world. In the last section of this review I present one vision of the next (Phase III) stage in the evolution of our conceptual model, organized around 5

  3. Combined Estimation of Hydrogeologic Conceptual Model and Parameter Uncertainty

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, Philip D.; Ye, Ming; Neuman, Shlomo P.; Cantrell, Kirk J.

    2004-03-01

    The objective of the research described in this report is the development and application of a methodology for comprehensively assessing the hydrogeologic uncertainties involved in dose assessment, including uncertainties associated with conceptual models, parameters, and scenarios. This report describes and applies a statistical method to quantitatively estimate the combined uncertainty in model predictions arising from conceptual model and parameter uncertainties. The method relies on model averaging to combine the predictions of a set of alternative models. Implementation is driven by the available data. When there is minimal site-specific data the method can be carried out with prior parameter estimates based on generic data and subjective prior model probabilities. For sites with observations of system behavior (and optionally data characterizing model parameters), the method uses model calibration to update the prior parameter estimates and model probabilities based on the correspondence between model predictions and site observations. The set of model alternatives can contain both simplified and complex models, with the requirement that all models be based on the same set of data. The method was applied to the geostatistical modeling of air permeability at a fractured rock site. Seven alternative variogram models of log air permeability were considered to represent data from single-hole pneumatic injection tests in six boreholes at the site. Unbiased maximum likelihood estimates of variogram and drift parameters were obtained for each model. Standard information criteria provided an ambiguous ranking of the models, which would not justify selecting one of them and discarding all others as is commonly done in practice. Instead, some of the models were eliminated based on their negligibly small updated probabilities and the rest were used to project the measured log permeabilities by kriging onto a rock volume containing the six boreholes. These four

  4. MEASUREMENT AND MODELLING OF SORPTION EQUILIBRIUM CURVE OF WATER ON PA6, PP, HDPE AND PVC BY USING FLORY-HUGGINS MODEL

    Directory of Open Access Journals (Sweden)

    Suherman Suherman

    2012-02-01

    Full Text Available The sorption of water on granular polyamide-6 (PA6, granular polypropylene (PP, and powdery high density polyethylene (HDPE and powdery polyvinyl chloride (PVC were measured using a gravimetric method in a magnetic suspension balance (MSB. The Flory-Huggins model was successfully applied on the sorption equilibrium curve of all investigated polymers. The influence of temperature is low. The value of Flory-Huggins parameters(c of PA6, PVC, PP and HDPE were 1.8, 5.8, 6.3, and 8.1, respectively. The water in PA6 is mainly bound moisture, while in PP, HDPE and PVC it is mainly surface moisture.

  5. A CONCEPTUAL MODEL FOR EFFECTIVE DISTANCE LEARNING IN HIGHER A CONCEPTUAL MODEL FOR EFFECTIVE DISTANCE LEARNING IN HIGHER A CONCEPTUAL MODEL FOR EFFECTIVE DISTANCE LEARNING IN HIGHER EDUCATION

    Directory of Open Access Journals (Sweden)

    Mehran FARAJOLLAHI

    2010-07-01

    Full Text Available The present research aims at presenting a conceptual model for effective distance learning in higher education. Findings of this research shows that an understanding of the technological capabilities and learning theories especially constructive theory and independent learning theory and communicative and interaction theory in Distance learning is an efficient factor in the planning of effective Distance learning in higher education. Considering the theoretical foundations of the present research, in the effective distance learning model, the learner is situated at the center of learning environment. For this purpose, the learner needs to be ready for successful learning and the teacher has to be ready to design the teaching- learning activities when they initially enter the environment. In the present model, group and individual active teaching-learning approach, timely feedback, using IT and eight types of interactions have been designed with respect to theoretical foundations and current university missions. From among the issues emphasized in this model, one can refer to the Initial, Formative and Summative evaluations. In an effective distance learning environment, evaluation should be part of the learning process and the feedback resulting from it should be used to improve learning. For validating the specified features, the opinions of Distance learning experts in Payame Noor, Shiraz, Science and Technology and Amirkabir Universities have been used which verified a high percentage of the statistical sample of the above mentioned features.

  6. Conceptual Change Texts in Chemistry Teaching: A Study on the Particle Model of Matter

    Science.gov (United States)

    Beerenwinkel, Anne; Parchmann, Ilka; Grasel, Cornelia

    2011-01-01

    This study explores the effect of a conceptual change text on students' awareness of common misconceptions on the particle model of matter. The conceptual change text was designed based on principles of text comprehensibility, of conceptual change instruction and of instructional approaches how to introduce the particle model. It was evaluated in…

  7. Modeling the effect of operating variables on sorption of PAHs from ...

    African Journals Online (AJOL)

    The application of artificial neural network (ANN) technology to the simulation of factors affecting sorption of polycyclic aromatic hydrocarbon (PAHs) onto ripe and unripe orange peels is presented in this work. A 3-layer backward propagation network structure was applied using pattern recognition tool in MATHLAB 7.9.0 ...

  8. Penetration Testing Professional Ethics: a conceptual model and taxonomy

    Directory of Open Access Journals (Sweden)

    Justin Pierce

    2006-05-01

    Full Text Available In an environment where commercial software is continually patched to correct security flaws, penetration testing can provide organisations with a realistic assessment of their security posture. Penetration testing uses the same principles as criminal hackers to penetrate corporate networks and thereby verify the presence of software vulnerabilities. Network administrators can use the results of a penetration test to correct flaws and improve overall security. The use of hacking techniques, however, raises several ethical questions that centre on the integrity of the tester to maintain professional distance and uphold the profession. This paper discusses the ethics of penetration testing and presents our conceptual model and revised taxonomy.

  9. A conceptual model for local content development in petroleum industry

    Directory of Open Access Journals (Sweden)

    Abolfazl Kazzazi

    2012-10-01

    Full Text Available A novel concept, local content, in oil industry is gradually emerging. Local content should be defined in terms of value addition in local country (by local staff, local materials, local services and facilities rather than in terms of ownership of the company performing the value added activities. Many oil exporting countries have taken a positive approach toward local content development to maximize the benefits from oil and gas extraction. The purpose of this study is to develop a conceptual model for local content development in petroleum industry. Local content can generally be defined in terms of the ownership and/ or location of the enterprises involved in production and/ or the value-added in the production process. Local content promotion will have to vary significantly between countries, depending on the current status of their economic, political and social development. This model is useful for state governments to consider all aspects and factors affecting local content development generally. Local content development outcomes are economic growth, industrial growth and spillover effects. The paper begins with examining the factors accommodated in literature believed to influence the local content promotion. Based on our review, the conceptual model derived includes key factors of local content that evaluate local content development, and examine interrelations between local policies, local infrastructure, local environment, and local capability.

  10. A CONCEPTUAL FRAMEWORK FOR SUSTAINABLE POULTRY SUPPLY CHAIN MODEL

    Directory of Open Access Journals (Sweden)

    Mohammad SHAMSUDDOHA

    2013-12-01

    Full Text Available Now a day, sustainable supply chain is the crucially considerable matter for future focused industries. As a result, attention in supply chain management has increasingly amplified since the 1980s when firms discovered its benefits of mutual relationships within and beyond their own organization. This is why, concern researchers are trying hard to develop new theory or model which might help the corporate sector for achieving sustainability in their supply chains. This kind of reflection can be seen by the number of papers published and in particular by journal since 1980. The objectives of this paper are twofold. First, it offers a literature review on sustainable supply chain management taking papers published in last three decades. Second, it offers a conceptual sustainable supply chain process model in light of triple bottom line theory. The model has been developed by taking in-depth interview of an entrepreneur from a Poultry case industry in Bangladesh.

  11. Conceptual Model of Uranium in the Vadose Zone for Acidic and Alkaline Wastes Discharged at the Hanford Site Central Plateau

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Szecsody, James E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qafoku, Nikolla [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Serne, R. Jeffrey [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-09-01

    Historically, uranium was disposed in waste solutions of varying waste chemistry at the Hanford Site Central Plateau. The character of how uranium was distributed in the vadose zone during disposal, how it has continued to migrate through the vadose zone, and the magnitude of potential impacts on groundwater are strongly influenced by geochemical reactions in the vadose zone. These geochemical reactions can be significantly influenced by the disposed-waste chemistry near the disposal location. This report provides conceptual models and supporting information to describe uranium fate and transport in the vadose zone for both acidic and alkaline wastes discharged at a substantial number of waste sites in the Hanford Site Central Plateau. The conceptual models include consideration of how co-disposed acidic or alkaline fluids influence uranium mobility in terms of induced dissolution/precipitation reactions and changes in uranium sorption with a focus on the conditions near the disposal site. This information, when combined with the extensive information describing uranium fate and transport at near background pH conditions, enables focused characterization to support effective fate and transport estimates for uranium in the subsurface.

  12. Updated Conceptual Model for the 300 Area Uranium Groundwater Plume

    Energy Technology Data Exchange (ETDEWEB)

    Zachara, John M.; Freshley, Mark D.; Last, George V.; Peterson, Robert E.; Bjornstad, Bruce N.

    2012-11-01

    The 300 Area uranium groundwater plume in the 300-FF-5 Operable Unit is residual from past discharge of nuclear fuel fabrication wastes to a number of liquid (and solid) disposal sites. The source zones in the disposal sites were remediated by excavation and backfilled to grade, but sorbed uranium remains in deeper, unexcavated vadose zone sediments. In spite of source term removal, the groundwater plume has shown remarkable persistence, with concentrations exceeding the drinking water standard over an area of approximately 1 km2. The plume resides within a coupled vadose zone, groundwater, river zone system of immense complexity and scale. Interactions between geologic structure, the hydrologic system driven by the Columbia River, groundwater-river exchange points, and the geochemistry of uranium contribute to persistence of the plume. The U.S. Department of Energy (DOE) recently completed a Remedial Investigation/Feasibility Study (RI/FS) to document characterization of the 300 Area uranium plume and plan for beginning to implement proposed remedial actions. As part of the RI/FS document, a conceptual model was developed that integrates knowledge of the hydrogeologic and geochemical properties of the 300 Area and controlling processes to yield an understanding of how the system behaves and the variables that control it. Recent results from the Hanford Integrated Field Research Challenge site and the Subsurface Biogeochemistry Scientific Focus Area Project funded by the DOE Office of Science were used to update the conceptual model and provide an assessment of key factors controlling plume persistence.

  13. A conceptual model of people's vulnerability to floods

    Science.gov (United States)

    Milanesi, Luca; Pilotti, Marco; Ranzi, Roberto

    2015-01-01

    Hydraulic risk maps provide the baseline for land use and emergency planning. Accordingly, they should convey clear information on the potential physical implications of the different hazards to the stakeholders. This paper presents a vulnerability criterion focused on human stability in a flow specifically devised for rapidly evolving floods where life, before than economic values, might be threatened. The human body is conceptualized as a set of cylinders and its stability to slipping and toppling is assessed by forces and moments equilibrium. Moreover, a depth threshold to consider drowning is assumed. In order to widen its scope of application, the model takes the destabilizing effect of local slope (so far disregarded in the literature) and fluid density into account. The resulting vulnerability classification could be naturally subdivided in three levels (low, medium, and high) that are limited by two stability curves for children and adults, respectively. In comparison with the most advanced literature conceptual approaches, the proposed model is weakly parameterized and the computed thresholds fit better the available experimental data sets. A code that implements the proposed algorithm is provided.

  14. Importance of incorporating agriculture in conceptual rainfall-runoff models

    Science.gov (United States)

    de Boer-Euser, Tanja; Hrachowitz, Markus; Winsemius, Hessel; Savenije, Hubert

    2016-04-01

    Incorporating spatially variable information is a frequently discussed option to increase the performance of (semi-)distributed conceptual rainfall-runoff models. One of the methods to do this is by using this spatially variable information to delineate Hydrological Response Units (HRUs) within a catchment. In large parts of Europe the original forested land cover is replaced by an agricultural land cover. This change in land cover probably affects the dominant runoff processes in the area, for example by increasing the Hortonian overland flow component, especially on the flatter and higher elevated parts of the catchment. A change in runoff processes implies a change in HRUs as well. A previous version of our model distinguished wetlands (areas close to the stream) from the remainder of the catchment. However, this configuration was not able to reproduce all fast runoff processes, both in summer as in winter. Therefore, this study tests whether the reproduction of fast runoff processes can be improved by incorporating a HRU which explicitly accounts for the effect of agriculture. A case study is carried out in the Ourthe catchment in Belgium. For this case study the relevance of different process conceptualisations is tested stepwise. Among the conceptualisations are Hortonian overland flow in summer and winter, reduced infiltration capacity due to a partly frozen soil and the relative effect of rainfall and snow smelt in case of this frozen soil. The results show that the named processes can make a large difference on event basis, especially the Hortonian overland flow in summer and the combination of rainfall and snow melt on (partly) frozen soil in winter. However, differences diminish when the modelled period of several years is evaluated based on standard metrics like Nash-Sutcliffe Efficiency. These results emphasise on one hand the importance of incorporating the effects of agricultural in conceptual models and on the other hand the importance of more event

  15. A conceptual model for translating omic data into clinical action

    Directory of Open Access Journals (Sweden)

    Timothy M Herr

    2015-01-01

    Full Text Available Genomic, proteomic, epigenomic, and other "omic" data have the potential to enable precision medicine, also commonly referred to as personalized medicine. The volume and complexity of omic data are rapidly overwhelming human cognitive capacity, requiring innovative approaches to translate such data into patient care. Here, we outline a conceptual model for the application of omic data in the clinical context, called "the omic funnel." This model parallels the classic "Data, Information, Knowledge, Wisdom pyramid" and adds context for how to move between each successive layer. Its goal is to allow informaticians, researchers, and clinicians to approach the problem of translating omic data from bench to bedside, by using discrete steps with clearly defined needs. Such an approach can facilitate the development of modular and interoperable software that can bring precision medicine into widespread practice.

  16. Modeling the sorption kinetic of metsulfuron-methyl on Andisols and Ultisols volcanic ash-derived soils: kinetics parameters and solute transport mechanisms.

    Science.gov (United States)

    Cáceres, Lizethly; Escudey, Mauricio; Fuentes, Edwar; Báez, María E

    2010-07-15

    Metsulfuron-methyl sorption kinetic was studied in Andisol and Ultisol soils in view of their distinctive physical and chemical properties: acidic pH and variable surface charge. Different kinetic models were applied to the experimental results. The pseudo-second-order model fitted sorption kinetics data better than the pseudo-first-order model. The rate constant and the initial rate constant values obtained through this model demonstrated the different behavior of metsulfuron-methyl in both kinds of soils, both parameters being the highest for Andisol. The application of Elovich equation, intraparticle diffusion model and a two-site nonequilibrium model (TSNE) allowed to conclude that: (i) the high organic matter content is the governing factor for Andisols where mass transfer across the boundary layer, and in a lesser degree, intraparticle diffusion were the two processes controlling sorption kinetic and (ii) the mineral composition was more relevant in Ultisols where rate was controlled almost exclusively by intraparticle diffusion into macropores and micropores. The slower sorption rate on Ultisols, the mechanism involved and the lower sorption capacity of this kind of soils must be taken into account to assess leaching behavior of this herbicide. 2010 Elsevier B.V. All rights reserved.

  17. A conceptual ENSO model under realistic noise forcing

    Directory of Open Access Journals (Sweden)

    J. Saynisch

    2006-01-01

    Full Text Available We investigated the influence of atmospheric noise on the generation of interannual El Niño variability. Therefore, we perturbed a conceptual ENSO delay model with surrogate windstress data generated from tropical windspeed measurements. The effect of the additional stochastic forcing was studied for various parameter sets including periodic and chaotic regimes. The evaluation was based on a spectrum and amplitude-period relation comparison between model and measured sea surface temperature data. The additional forcing turned out to increase the variability of the model output in general. The noise-free model was unable to reproduce the observed spectral bandwidth for any choice of parameters. On the contrary, the stochastically forced model is capable of producing a realistic spectrum. The weakly nonlinear regimes of the model exhibit a proportional relation between amplitude and period matching the relation derived from measurement data. The chaotic regime, however, shows an inversely proportional relation. A stability analysis of the different regimes revealed that the spectra of the weakly nonlinear regimes are robust against slight parameter changes representing disregarded physical mechanisms, whereas the chaotic regime exhibits a very unstable realistic spectrum. We conclude that the model including stochastic forcing in a parameter range of moderate nonlinearity best matches the real conditions. This suggests that atmospheric noise plays an important role in the coupled tropical pacific ocean-atmosphere system.

  18. Sorption of Sr, Co and Zn on illite: Batch experiments and modelling including Co in-diffusion measurements on compacted samples

    Science.gov (United States)

    Montoya, V.; Baeyens, B.; Glaus, M. A.; Kupcik, T.; Marques Fernandes, M.; Van Laer, L.; Bruggeman, C.; Maes, N.; Schäfer, T.

    2018-02-01

    Experimental investigations on the uptake of divalent cations (Sr, Co and Zn) onto illite (Illite du Puy, Le-Puy-en-Velay, France) were carried out by three different international research groups (Institute for Nuclear Waste Disposal, KIT (Germany), Group Waste & Disposal, SCK-CEN, (Belgium) and Laboratory for Waste Management, PSI (Switzerland)) in the framework of the European FP7 CatClay project. The dependence of solid-liquid distribution ratios (Rd values) on pH at trace metal conditions (sorption edges) and on the metal ion concentration (sorption isotherms) was determined in dilute suspensions of homo-ionic Na-illite (Na-IdP) under controlled N2 atmosphere. The experimental results were modelled using the 2 Site Protolysis Non Electrostatic Surface Complexation and Cation Exchange (2SPNE SC/CE) sorption model. The sorption of Sr depends strongly on ionic strength, while a rather weak pH dependence is observed in a pH range between 3 and 11. The data were modelled with cation exchange reactions, taking into account competition with H, K, Ca, Mg and Al, and surface complexation on weak amphotheric edge sites at higher pH values. The sorption of Co on Na-IdP, however, is strongly pH dependent. Cation exchange on the planar sites and surface complexation on strong and weak amphoteric edge sites were used to describe the Co sorption data. Rd values for Co derived from in-diffusion measurements on compacted Na-IdP samples (bulk-dry density of 1700 kg m-3) between pH 5.0 and 9.0 are in good agreement with the batch sorption data. The equivalence of both approaches to measure sorption was thus confirmed for the present test system. In addition, the results highlight the importance of both major and minor surface species for the diffusive transport behaviour of strongly sorbing metal cations. While surface complexes at the edge sites determine largely the Rd value, the diffusive flux may be governed by those species bound to the planar sites, even at low fractional

  19. A conceptual model to improve performance in virtual teams

    Directory of Open Access Journals (Sweden)

    Shopee Dube

    2016-09-01

    Full Text Available Background: The vast improvement in communication technologies and sophisticated project management tools, methods and techniques has allowed geographically and culturally diverse groups to operate and function in a virtual environment. To succeed in this virtual environment where time and space are becoming increasingly irrelevant, organisations must define new ways of implementing initiatives. This virtual environment phenomenon has brought about the formation of virtual project teams that allow organisations to harness the skills and knowhow of the best resources, irrespective of their location. Objectives: The aim of this article was to investigate performance criteria and develop a conceptual model which can be applied to enhance the success of virtual project teams. There are no clear guidelines of the performance criteria in managing virtual project teams. Method: A qualitative research methodology was used in this article. The purpose of content analysis was to explore the literature to understand the concept of performance in virtual project teams and to summarise the findings of the literature reviewed. Results: The research identified a set of performance criteria for the virtual project teams as follows: leadership, trust, communication, team cooperation, reliability, motivation, comfort and social interaction. These were used to conceptualise the model. Conclusion: The conceptual model can be used in a holistic way to determine the overall performance of the virtual project team, but each factor can be analysed individually to determine the impact on the overall performance. The knowledge of performance criteria for virtual project teams could aid project managers in enhancing the success of these teams and taking a different approach to better manage and coordinate them.

  20. Can Bayesian Belief Networks help tackling conceptual model uncertainties in contaminated site risk assessment?

    DEFF Research Database (Denmark)

    Troldborg, Mads; Thomsen, Nanna Isbak; McKnight, Ursula S.

    A key component in risk assessment of contaminated sites is the formulation of a conceptual site model. The conceptual model is a simplified representation of reality and forms the basis for the mathematical modelling of contaminant fate and transport at the site. A conceptual model should...... therefore identify the most important site-specific features and processes that may affect the contaminant transport behaviour at the site. The development of a conceptual model will always be associated with uncertainties due to lack of data and understanding of the site conditions, and often many...... different conceptual models may describe the same contaminated site equally well. In many cases, conceptual model uncertainty has been shown to be one of the dominant sources for uncertainty and is therefore essential to account for when quantifying uncertainties in risk assessments. We present here...

  1. Formulations of transport in catchment-scale conceptual models

    Science.gov (United States)

    De Vos, Lotte; Hrachowitz, Markus

    2017-04-01

    Standard conceptual hydrological models can rarely accommodate stream tracer dynamics at the catchment scale. They rely on the generation of runoff through the propagation of a pressure wave and do not account for the actual advective movement of particles. Over the last years different model frameworks have been developed to account for this shortcoming. The difference between the frameworks lies in whether they are based on mixing coefficients or storage age selection functions. Both methods have shown their ability to capture the stream chemistry response. It is however not clear how these distinct approaches compare to each other and to reality. The object of this research is to provide clarification in this matter. To achieve this, the hydrological and stream water chemistry response for a set of contrasting research catchments is modelled, using both the mixing coefficient and the storage age selection approach. The results are analysed using the concept of transit times, where information on the fluxes and states in all model components is used to generate distributions that describe the age structure of water. By comparing the distributions generated by both methods and by evaluating the overall model performances, more insight is gained on how mixing occurs at the catchment scale. This contributes to the understanding of the integrated system dynamics of catchments, which is relevant for the development of good water quality models that accurately describe the integrated response of a hydrological system.

  2. The structure of conceptual models with application to the Aespoe HRL project

    International Nuclear Information System (INIS)

    Olsson, Olle; Baeckblom, G.; Wikberg, P.; Gustafson, G.; Stanfors, R.

    1994-05-01

    In performance assessment a sequence of models is used to describe the function of the geological barrier. This report proposes a general structure and terminology for description of these models. A model description consists of the following components: A conceptual model which defines the geometric framework in which the problem is solved, the dimensions of the modelled volume, descriptions of the processes included in the model, and the boundary conditions; Data which are introduced into the conceptual model, and a mathematical or numerical tool used to produce output data. Contradictory to common practice in geohydrologic modelling it is proposed that the term conceptual model is restricted to define in what way the model is constructed, and that this is separated from any specific application of the conceptual model. Hence, the conceptual model should not include any specific data. 5 refs, 2 figs, 4 tabs

  3. Geophysical Conceptual Model for Benthic Flux and Submarine Groundwater Discharge

    Science.gov (United States)

    King, J. N.

    2010-12-01

    Numerous investigators characterize benthic flux and submarine groundwater discharge (SGD) using a geochemical conceptual model that relies on the estimation of tracer fluxes into and out of a control volume. (Benthic flux is the rate of flow across the bed of any water body, per unit area of bed. Benthic flux is a vector that includes both discharge and recharge components. SGD is a benthic water discharge flux to a marine water body.) For the geochemical approach, benthic discharge flux or SGD is estimated by summing the flux of tracer into or out of the control volume---a water body or portion of a water body---and deducing that tracer deficiency within the control volume must be explained by SGD. Typically, estimated or measured fluxes include advection and mixing in surface-water, diffusion, evasion across the air-water interface, production, and decay. The geochemical model, however, does not account for fluxes that do not transport tracer. For example, investigators found equivalent (the upper 30 cm of sediment in the Indian River Lagoon, Florida, in June and July 2003. At this location, a surface-gravity wave with a five-centimeter amplitude and one-second period in 0.5 m of water forced a 12-cm-per-day SGD. The radon tracer technique may not characterize SGD forced by the one-second wave due to the time scale of the wave, the absence of a radon activity gradient between bed medium and surface water, and the the wave affects the flow field within the porous medium. A new geophysical conceptual model for benthic flux is proposed. The model parses benthic flux into components driven by individual forcing mechanisms. The model recognizes that benthic flux components may interact in a constructive or destructive manner, such that benthic flux generated by multiple forcing mechanisms at the same location may not be equivalent to the linear sum of benthic flux generated by single forcing mechanisms. Restated: the whole may be different than the sum of the parts

  4. Climate stability and sensitivity in some simple conceptual models

    Energy Technology Data Exchange (ETDEWEB)

    Bates, J. Ray [University College Dublin, Meteorology and Climate Centre, School of Mathematical Sciences, Dublin (Ireland)

    2012-02-15

    A theoretical investigation of climate stability and sensitivity is carried out using three simple linearized models based on the top-of-the-atmosphere energy budget. The simplest is the zero-dimensional model (ZDM) commonly used as a conceptual basis for climate sensitivity and feedback studies. The others are two-zone models with tropics and extratropics of equal area; in the first of these (Model A), the dynamical heat transport (DHT) between the zones is implicit, in the second (Model B) it is explicitly parameterized. It is found that the stability and sensitivity properties of the ZDM and Model A are very similar, both depending only on the global-mean radiative response coefficient and the global-mean forcing. The corresponding properties of Model B are more complex, depending asymmetrically on the separate tropical and extratropical values of these quantities, as well as on the DHT coefficient. Adopting Model B as a benchmark, conditions are found under which the validity of the ZDM and Model A as climate sensitivity models holds. It is shown that parameter ranges of physical interest exist for which such validity may not hold. The 2 x CO{sub 2} sensitivities of the simple models are studied and compared. Possible implications of the results for sensitivities derived from GCMs and palaeoclimate data are suggested. Sensitivities for more general scenarios that include negative forcing in the tropics (due to aerosols, inadvertent or geoengineered) are also studied. Some unexpected outcomes are found in this case. These include the possibility of a negative global-mean temperature response to a positive global-mean forcing, and vice versa. (orig.)

  5. Application of two-parameter and three-parameter isotherm models at uranium bio sorption by baker's yeast

    International Nuclear Information System (INIS)

    Keshtkar, A.; Montazer Rahmati, M. M.; Khodapanah, N.

    2010-01-01

    In this work, the ability of free and immobilized deactivated baker's yeast saccharomyces cerevisiae to remove uranium ions was investigated using a batch bio sorption procedure with respect to the initial p H (3.0-6.0), contact time (24 h), initial ion concentration (50-400 mg/g) and presence of secondary ions (Cr(V I)). The removal of uranium was approximately 90% and 50% at low concentrations, whereas it was about 80% and 15% at high concentrations at an optimum p H of 5 and 5.5, using 1 g/1 of adsorbent in 24 h of equilibration time for immobilized and free baker's yeast, respectively. Experimental results at 30 d eg C indicated that the uptake capacity of uranium ions by immobilized baker's yeast biomass on calcium alginate was reduced by the presence of secondary ions. The experimental data obtained at the optimum have been analyzed using two two-parameter models, Langmuir and Freundlich, and one three-parameter model, Redlich-Peterson. Taking into three statistical error functions, the data were best fitted to the Redlich-Peterson model. Using the Langmuir equation, the saturated monolayer sorption capacities of uranium ions onto immobilized and free baker's yeast were 592.8 and 73 mg/g, respectively at 30 d eg C .

  6. Recruiting Transcultural Qualitative Research Participants: A Conceptual Model

    Directory of Open Access Journals (Sweden)

    Phyllis Eide

    2005-06-01

    Full Text Available Working with diverse populations poses many challenges to the qualitative researcher who is a member of the dominant culture. Traditional methods of recruitment and selection (such as flyers and advertisements are often unproductive, leading to missed contributions from potential participants who were not recruited and researcher frustration. In this article, the authors explore recruitment issues related to the concept of personal knowing based on experiences with Aboriginal Hawai'ian and Micronesian populations, wherein knowing and being known are crucial to successful recruitment of participants. They present a conceptual model that incorporates key concepts of knowing the other, cultural context, and trust to guide other qualitative transcultural researchers. They also describe challenges, implications, and concrete suggestions for recruitment of participants.

  7. CONCEPTUAL MODEL OF CONSUMERS TRUST TO ONLINE SHOPS

    Directory of Open Access Journals (Sweden)

    T. Dubovyk

    2014-06-01

    Full Text Available In the article the conceptual model of the major factors that influence consumers trust in online shop: reliability of online store, reliable information system for making purchases online, factors of ethic interactiveness (security, third-party certification, internet-marketing communications of online-shop and other factors – that is divided enterprises of trade and consumers (demographic variables, psychological perception of internet-marketing communications, experience of purchase of commodities are in the Internet. The degree of individual customer trust propensity which reflects the personality traits, culture and previous experience. An implement signs of consumer confidence due to site elements online shop – graphic design, structured design, design of content, design harmonized with perception of target audience.

  8. Assessment of private hospital portals: A conceptual model

    Directory of Open Access Journals (Sweden)

    Mehdi Alipour-Hafezi

    2016-01-01

    Full Text Available Introduction: Hospital portals, as the first virtual entry, play an important role in connecting people with hospital and also presenting hospital virtual services. The main purpose of this article was to suggest a conceptual model to improve Tehran private hospital portals. The suggested model can be used by all the health portals that are in the same circumstances and all the health portals which are in progress. Method: This is a practical research, using evaluative survey research method. Research population includes all the private hospital portals in Tehran, 34 portals, and ten top international hospital portals. Data gathering tool used in this research was a researcher-made checklist including 14 criteria and 77 sub-criteria with their weight score. In fact, objective observation with the mentioned checklist was used to gather information. Descriptive statistics were used to analyze the data and tables and graphs were used to present the organized data. Also, data were analyzed using independent t-test. Conceptual modeling technique was used to design the model and demonstration method was used to evaluate the proposed model. In this regard, SPSS statistical software was used to perform the tests. Results:The comparative study between the two groups of portals, TPH and WTH, in the 14 main criteria showed that the value of t-test in contact information criteria was 0.862, portal page specification was -1.378, page design criteria -1.527, updating pages -0.322, general information and access roads -3.161, public services -7.302, patient services -4.154, patient data -8.703, research and education -9.155, public relationship -3.009, page technical specifications -4.726, telemedicine -7.488, pharmaceutical services -6.183, and financial services -2.782. Finally, the findings demonstrated that Tehran private hospital portals in criterion of contact information were favorable; page design criteria were relatively favorable; page technical

  9. Modelling in Primary School: Constructing Conceptual Models and Making Sense of Fractions

    Science.gov (United States)

    Shahbari, Juhaina Awawdeh; Peled, Irit

    2017-01-01

    This article describes sixth-grade students' engagement in two model-eliciting activities offering students the opportunity to construct mathematical models. The findings show that students utilized their knowledge of fractions including conceptual and procedural knowledge in constructing mathematical models for the given situations. Some students…

  10. An empirical conceptual gully evolution model for channelled sea cliffs

    Science.gov (United States)

    Leyland, Julian; Darby, Stephen E.

    2008-12-01

    Incised coastal channels are a specific form of incised channel that are found in locations where stream channels flowing to cliffed coasts have the excess energy required to cut down through the cliff to reach the outlet water body. The southern coast of the Isle of Wight, southern England, comprises soft cliffs that vary in height between 15 and 100 m and which are retreating at rates ≤ 1.5 m a - 1 , due to a combination of wave erosion and landslides. In several locations, river channels have cut through the cliffs to create deeply (≤ 45 m) incised gullies, known locally as 'Chines'. The Chines are unusual in that their formation is associated with dynamic shoreline encroachment during a period of rising sea-level, whereas existing models of incised channel evolution emphasise the significance of base level lowering. This paper develops a conceptual model of Chine evolution by applying space for time substitution methods using empirical data gathered from Chine channel surveys and remotely sensed data. The model identifies a sequence of evolutionary stages, which are classified based on a suite of morphometric indices and associated processes. The extent to which individual Chines are in a state of growth or decay is estimated by determining the relative rates of shoreline retreat and knickpoint recession, the former via analysis of historical aerial images and the latter through the use of a stream power erosion model.

  11. Vulnerability Assessment Models to Drought: Toward a Conceptual Framework

    Directory of Open Access Journals (Sweden)

    Kiumars Zarafshani

    2016-06-01

    Full Text Available Drought is regarded as a slow-onset natural disaster that causes inevitable damage to water resources and to farm life. Currently, crisis management is the basis of drought mitigation plans, however, thus far studies indicate that effective drought management strategies are based on risk management. As a primary tool in mitigating the impact of drought, vulnerability assessment can be used as a benchmark in drought mitigation plans and to enhance farmers’ ability to cope with drought. Moreover, literature pertaining to drought has focused extensively on its impact, only awarding limited attention to vulnerability assessment as a tool. Therefore, the main purpose of this paper is to develop a conceptual framework for designing a vulnerability model in order to assess farmers’ level of vulnerability before, during and after the onset of drought. Use of this developed drought vulnerability model would aid disaster relief workers by enhancing the adaptive capacity of farmers when facing the impacts of drought. The paper starts with the definition of vulnerability and outlines different frameworks on vulnerability developed thus far. It then identifies various approaches of vulnerability assessment and finally offers the most appropriate model. The paper concludes that the introduced model can guide drought mitigation programs in countries that are impacted the most by drought.

  12. A CONCEPTUAL MODEL FOR IMPROVED PROJECT SELECTION AND PRIORITISATION

    Directory of Open Access Journals (Sweden)

    P. J. Viljoen

    2012-01-01

    Full Text Available

    ENGLISH ABSTRACT: Project portfolio management processes are often designed and operated as a series of stages (or project phases and gates. However, the flow of such a process is often slow, characterised by queues waiting for a gate decision and by repeated work from previous stages waiting for additional information or for re-processing. In this paper the authors propose a conceptual model that applies supply chain and constraint management principles to the project portfolio management process. An advantage of the proposed model is that it provides the ability to select and prioritise projects without undue changes to project schedules. This should result in faster flow through the system.

    AFRIKAANSE OPSOMMING: Prosesse om portefeuljes van projekte te bestuur word normaalweg ontwerp en bedryf as ’n reeks fases en hekke. Die vloei deur so ’n proses is dikwels stadig en word gekenmerk deur toue wat wag vir besluite by die hekke en ook deur herwerk van vorige fases wat wag vir verdere inligting of vir herprosessering. In hierdie artikel word ‘n konseptuele model voorgestel. Die model berus op die beginsels van voorsieningskettings sowel as van beperkingsbestuur, en bied die voordeel dat projekte geselekteer en geprioritiseer kan word sonder onnodige veranderinge aan projekskedules. Dit behoort te lei tot versnelde vloei deur die stelsel.

  13. BIM-Enabled Conceptual Modelling and Representation of Building Circulation

    Directory of Open Access Journals (Sweden)

    Jin Kook Lee

    2014-08-01

    Full Text Available This paper describes how a building information modelling (BIM-based approach for building circulation enables us to change the process of building design in terms of its computational representation and processes, focusing on the conceptual modelling and representation of circulation within buildings. BIM has been designed for use by several BIM authoring tools, in particular with the widely known interoperable industry foundation classes (IFCs, which follow an object-oriented data modelling methodology. Advances in BIM authoring tools, using space objects and their relations defined in an IFC's schema, have made it possible to model, visualize and analyse circulation within buildings prior to their construction. Agent-based circulation has long been an interdisciplinary topic of research across several areas, including design computing, computer science, architectural morphology, human behaviour and environmental psychology. Such conventional approaches to building circulation are centred on navigational knowledge about built environments, and represent specific circulation paths and regulations. This paper, however, places emphasis on the use of ‘space objects’ in BIM-enabled design processes rather than on circulation agents, the latter of which are not defined in the IFCs' schemas. By introducing and reviewing some associated research and projects, this paper also surveys how such a circulation representation is applicable to the analysis of building circulation-related rules.

  14. Volatile Organic Molecules Sorption onto Carbon Nanotubes: Experiment and Molecular Modeling

    Czech Academy of Sciences Publication Activity Database

    Simha Martynková, G.; Plachá, D.; Plevová, Eva

    2016-01-01

    Roč. 12, č. 1 (2016), s. 142-146 ISSN 2211-8128 R&D Projects: GA MŠk ED1.1.00/02.0070 Institutional support: RVO:68145535 Keywords : carbon nanotubes * sorption * naphthalene * formaldehyde Subject RIV: CB - Analytical Chemistry, Separation http://ac.els-cdn.com/S2211812816000341/1-s2.0-S2211812816000341-main.pdf?_tid=a9631cda-969b-11e6-9761-00000aab0f01&acdnat=1476950778_b6de7ebc7654df3afb52d7e7fb4c0986

  15. Testing a Conceptual Change Model Framework for Visual Data

    Science.gov (United States)

    Finson, Kevin D.; Pedersen, Jon E.

    2015-01-01

    An emergent data analysis technique was employed to test the veracity of a conceptual framework constructed around visual data use and instruction in science classrooms. The framework incorporated all five key components Vosniadou (2007a, 2007b) described as existing in a learner's schema: framework theory, presuppositions, conceptual domains,…

  16. Conceptual Modeling Framework for E-Area PA HELP Infiltration Model Simulations

    Energy Technology Data Exchange (ETDEWEB)

    Dyer, J. A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2017-11-30

    A conceptual modeling framework based on the proposed E-Area Low-Level Waste Facility (LLWF) closure cap design is presented for conducting Hydrologic Evaluation of Landfill Performance (HELP) model simulations of intact and subsided cap infiltration scenarios for the next E-Area Performance Assessment (PA).

  17. Developing a conceptual model for selecting and evaluating online markets

    Directory of Open Access Journals (Sweden)

    Sadegh Feizollahi

    2013-04-01

    Full Text Available There are many evidences, which emphasis on the benefits of using new technologies of information and communication in international business and many believe that E-Commerce can help satisfy customer explicit and implicit requirements. Internet shopping is a concept developed after the introduction of electronic commerce. Information technology (IT and its applications, specifically in the realm of the internet and e-mail promoted the development of e-commerce in terms of advertising, motivating and information. However, with the development of new technologies, credit and financial exchange on the internet websites were constructed so to facilitate e-commerce. The proposed study sends a total of 200 questionnaires to the target group (teachers - students - professionals - managers of commercial web sites and it manages to collect 130 questionnaires for final evaluation. Cronbach's alpha test is used for measuring reliability and to evaluate the validity of measurement instruments (questionnaires, and to assure construct validity, confirmatory factor analysis is employed. In addition, in order to analyze the research questions based on the path analysis method and to determine markets selection models, a regular technique is implemented. In the present study, after examining different aspects of e-commerce, we provide a conceptual model for selecting and evaluating online marketing in Iran. These findings provide a consistent, targeted and holistic framework for the development of the Internet market in the country.

  18. Hemispheric Asymmetry of Global Warming Explained by a Conceptual Model

    Science.gov (United States)

    Funke, C. S.; Alexeev, V. A.

    2017-12-01

    Polar Amplification, the process of amplified warming at high latitudes, manifests itself differently in the Arctic and Antarctic. Not only is the temperature increase in the Arctic more pronounced than in the Antarctic but the dramatic sea ice decline in the Arctic over the last few decades also contrasts sharply with trendless to weak positive trend of Antarctic sea ice throughout the same period. This asymmetric behavior is often partly attributed to the differences in configuration of continents in the Arctic and Antarctic: the Arctic Ocean is surrounded by land while the Southern Ocean has a continent in the middle. A simple conceptual energy balance model of Budyko-Sellers type, accounting for differences between the Northern and Southern hemispheres, is applied to study the mechanisms of climate sensitivity to a variety of forcings. Asymmetry in major modes of variability is explained using an eigenmode analysis of the linearized model. Negative forcings over Antarctica such as from ozone depletion were found to have an amplified effect on southern hemisphere climate and may be an important cause of the muted warming and slightly positive Antarctic sea ice trend.

  19. Addressing Conceptual Model Uncertainty in the Evaluation of Model Prediction Errors

    Science.gov (United States)

    Carrera, J.; Pool, M.

    2014-12-01

    Model predictions are uncertain because of errors in model parameters, future forcing terms, and model concepts. The latter remain the largest and most difficult to assess source of uncertainty in long term model predictions. We first review existing methods to evaluate conceptual model uncertainty. We argue that they are highly sensitive to the ingenuity of the modeler, in the sense that they rely on the modeler's ability to propose alternative model concepts. Worse, we find that the standard practice of stochastic methods leads to poor, potentially biased and often too optimistic, estimation of actual model errors. This is bad news because stochastic methods are purported to properly represent uncertainty. We contend that the problem does not lie on the stochastic approach itself, but on the way it is applied. Specifically, stochastic inversion methodologies, which demand quantitative information, tend to ignore geological understanding, which is conceptually rich. We illustrate some of these problems with the application to Mar del Plata aquifer, where extensive data are available for nearly a century. Geologically based models, where spatial variability is handled through zonation, yield calibration fits similar to geostatiscally based models, but much better predictions. In fact, the appearance of the stochastic T fields is similar to the geologically based models only in areas with high density of data. We take this finding to illustrate the ability of stochastic models to accommodate many data, but also, ironically, their inability to address conceptual model uncertainty. In fact, stochastic model realizations tend to be too close to the "most likely" one (i.e., they do not really realize the full conceptualuncertainty). The second part of the presentation is devoted to argue that acknowledging model uncertainty may lead to qualitatively different decisions than just working with "most likely" model predictions. Therefore, efforts should concentrate on

  20. Development of Conceptual Benchmark Models to Evaluate Complex Hydrologic Model Calibration in Managed Basins Using Python

    Science.gov (United States)

    Hughes, J. D.; White, J.

    2013-12-01

    For many numerical hydrologic models it is a challenge to quantitatively demonstrate that complex models are preferable to simpler models. Typically, a decision is made to develop and calibrate a complex model at the beginning of a study. The value of selecting a complex model over simpler models is commonly inferred from use of a model with fewer simplifications of the governing equations because it can be time consuming to develop another numerical code with data processing and parameter estimation functionality. High-level programming languages like Python can greatly reduce the effort required to develop and calibrate simple models that can be used to quantitatively demonstrate the increased value of a complex model. We have developed and calibrated a spatially-distributed surface-water/groundwater flow model for managed basins in southeast Florida, USA, to (1) evaluate the effect of municipal groundwater pumpage on surface-water/groundwater exchange, (2) investigate how the study area will respond to sea-level rise, and (3) explore combinations of these forcing functions. To demonstrate the increased value of this complex model, we developed a two-parameter conceptual-benchmark-discharge model for each basin in the study area. The conceptual-benchmark-discharge model includes seasonal scaling and lag parameters and is driven by basin rainfall. The conceptual-benchmark-discharge models were developed in the Python programming language and used weekly rainfall data. Calibration was implemented with the Broyden-Fletcher-Goldfarb-Shanno method available in the Scientific Python (SciPy) library. Normalized benchmark efficiencies calculated using output from the complex model and the corresponding conceptual-benchmark-discharge model indicate that the complex model has more explanatory power than the simple model driven only by rainfall.

  1. Kinetics of volatile organic compound sorption/desorption on clay minerals

    Science.gov (United States)

    Morrissey, Fergus A.; Grismer, Mark E.

    1999-03-01

    's adsorb onto surfaces other than the external mineral surfaces. The fraction of mass sorbed on the mineral surface ranged from 30% to 75% of the equilibrium sorbed mass. Equilibrium sorption mass correlates approximately to mineral specific surface area and, similarly, the fraction of `irreversible' sorption appears to be proportional to the specific surface area of the clay mineral. Finally, the experimental results suggest that sorption processes (once the sorbate has diffused to the sorbent) are not instantaneous. Due to the experimental inter-particle length scales and intra-particle diffusion processes, diffusional time constants associated with each process during sorption experiments were generally found to be within two orders of magnitude. Such close agreement would not be expected if particles larger than a few micrometers (i.e., aggregates) comprised part of the sorbing soil system. Although the experiments were conducted using oven-dry clays, it is hoped that these results offer an improved conceptual model of clay mineral sorption processes to better explain field observations of VOC persistence in the subsurface.

  2. Three Roles of Conceptual Models in Information System Design and Use

    NARCIS (Netherlands)

    Wieringa, Roelf J.; Falkenberg, Eckhard D.; Lindgreen, Paul

    1989-01-01

    This paper attempts to draw together results from information systems research, linguistic theory, and methodology in order to present a unified framework in which to understand conceptual models. Three different roles of conceptual models (CM's) in the design and use of information systems (IS's)

  3. Non-monotonic reasoning in conceptual modeling and ontology design: A proposal

    CSIR Research Space (South Africa)

    Casini, G

    2013-06-01

    Full Text Available -1 2nd International Workshop on Ontologies and Conceptual Modeling (Onto.Com 2013), Valencia, Spain, 17-21 June 2013 Non-monotonic reasoning in conceptual modeling and ontology design: A proposal Giovanni Casini1 and Alessandro Mosca2 1...

  4. Applying a Conceptual Model in Sport Sector Work- Integrated Learning Contexts

    Science.gov (United States)

    Agnew, Deborah; Pill, Shane; Orrell, Janice

    2017-01-01

    This paper applies a conceptual model for work-integrated learning (WIL) in a multidisciplinary sports degree program. Two examples of WIL in sport will be used to illustrate how the conceptual WIL model is being operationalized. The implications for practice are that curriculum design must recognize a highly flexible approach to the nature of…

  5. Teacher Emotion Research: Introducing a Conceptual Model to Guide Future Research

    Science.gov (United States)

    Fried, Leanne; Mansfield, Caroline; Dobozy, Eva

    2015-01-01

    This article reports on the development of a conceptual model of teacher emotion through a review of teacher emotion research published between 2003 and 2013. By examining 82 publications regarding teacher emotion, the main aim of the review was to identify how teacher emotion was conceptualised in the literature and develop a conceptual model to…

  6. Theory analysis of the Dental Hygiene Human Needs Conceptual Model.

    Science.gov (United States)

    MacDonald, L; Bowen, D M

    2017-11-01

    Theories provide a structural knowing about concept relationships, practice intricacies, and intuitions and thus shape the distinct body of the profession. Capturing ways of knowing and being is essential to any professions' practice, education and research. This process defines the phenomenon of the profession - its existence or experience. Theory evaluation is a systematic criterion-based assessment of a specific theory. This study presents a theory analysis of the Dental Hygiene Human Needs Conceptual Model (DH HNCM). Using the Walker and Avant Theory Analysis, a seven-step process, the DH HNCM, was analysed and evaluated for its meaningfulness and contribution to dental hygiene. The steps include the following: (i) investigate the origins; (ii) examine relationships of the theory's concepts; (iii) assess the logic of the theory's structure; (iv) consider the usefulness to practice; (v) judge the generalizability; (vi) evaluate the parsimony; and (vii) appraise the testability of the theory. Human needs theory in nursing and Maslow's Hierarchy of Need Theory prompted this theory's development. The DH HNCM depicts four concepts based on the paradigm concepts of the profession: client, health/oral health, environment and dental hygiene actions, and includes validated eleven human needs that evolved overtime to eight. It is logical, simplistic, allows scientific predictions and testing, and provides a unique lens for the dental hygiene practitioner. With this model, dental hygienists have entered practice, knowing they enable clients to meet their human needs. For the DH HNCM, theory analysis affirmed that the model is reasonable and insightful and adds to the dental hygiene professions' epistemology and ontology. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  7. Facets of private practice nursing: a conceptual model.

    Science.gov (United States)

    Wilson, Anne; Averis, Andrea

    2002-04-01

    This paper critically examines the literature relating to private practice nursing. Particular attention is given to the reasons nurses choose private practice and the major issues involved. A conceptual model has been developed based on this information. Nurses' roles are expanding into different work domains. Private practice nursing is one of the advanced practice options available. It also requires the nurse to develop business knowledge and skills. A literature search was conducted of Pub-Med, Cinahl, Medline and InfoTrac databases using the terms 'private practice', 'nurse entrepreneur', 'nurses in business', Inurse practitioners', 'self-employed nurse', 'advanced practice' and 'clinical nurse specialist'. Further relevant articles were identified from the reference lists of papers detected by this literature search. In addition, conference proceedings were examined for any other material on this topic. A thorough search of the existing literature revealed one unpublished theoretically based study which examined limited aspects of private practice nursing in Victoria. A reasonable number of articles and publications that provided anecdotal and personal accounts of being a nurse in business were identified. This review highlights the need for further theoretically based research in this area of nursing, so as to expand nursing knowledge. Suggestions are given for further research in this topical area. Existing research into private practice nursing is limited and not sufficient to inform changes to policy and nurse education. More research is needed.

  8. Virtual Learning Environment for Entrepreneurship: A Conceptual Model

    Directory of Open Access Journals (Sweden)

    Douglas Sparkes

    2016-06-01

    Full Text Available The University of Waterloo has a history as an innovative and entrepreneurial university. With increasing demand for entrepreneurship education and venture development support there has been increasing interest in how to provide this support virtually. To address this need, an entrepreneurship platform consisting of four primary components; entrepreneurial team engagement, mentor engagement, provision of 'just-in-time' learning resources, and social network creation is under development. Engagement and social network creation are built around a series of gamified events that provide structure and feedback for the participants, as well as focal points for mentoring and network development. The 'embedding' of these early-stage ventures into a supportive social network aligns with a belief that one does not simply launch new ventures, but rather launch networks. These event gates are supported by a system of 'just-in-time' learning modules allow the participants to develop their own learning program, and may be drawn upon as needed. In this paper we discuss the conceptual model as well as progress on development of its key features. We also discuss some of the early results and lessons learned integrating it into several initiatives underway in Canada and Kenya.

  9. Conceptual and numerical modeling approach of the Guarani Aquifer System

    Directory of Open Access Journals (Sweden)

    L. Rodríguez

    2013-01-01

    Full Text Available In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormous volume of water; however, it is not well known, being difficult to assess the impact of exploitation currently used to supply over 25 million inhabitants. This is a sensitive issue because the aquifer is shared by four countries. Moreover, an integrated groundwater model, and therefore a global water balance, were not available. In this work, a transient regional scale model for the entire aquifer based upon five simplified, equally plausible conceptual models represented by different hydraulic conductivity parametrizations is used to analyze the flow system and water balance components. Combining an increasing number of hydraulic conductivity zones and an appropriate set of boundary conditions, the hypothesis of a continuous sedimentary unit yielded errors within the calibration target in a regional sense. The magnitude of the water budget terms resulted very similar for all parametrizations. Recharge and stream/aquifer fluxes were the dominant components representing, on average, 84.2% of total inflows and 61.4% of total outflows, respectively. However, leakage was small compared to stream discharges of main rivers. For instance, the simulated average leakage for the Uruguay River was 8 m3 s−1 while the observed absolute minimum discharge was 382 m3 s−1. Streams located in heavily pumped regions switched from a gaining condition in early years to a losing condition over time. Water is discharged through

  10. Conceptual and numerical modeling approach of the Guarani Aquifer System

    Science.gov (United States)

    Rodríguez, L.; Vives, L.; Gomez, A.

    2013-01-01

    In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormous volume of water; however, it is not well known, being difficult to assess the impact of exploitation currently used to supply over 25 million inhabitants. This is a sensitive issue because the aquifer is shared by four countries. Moreover, an integrated groundwater model, and therefore a global water balance, were not available. In this work, a transient regional scale model for the entire aquifer based upon five simplified, equally plausible conceptual models represented by different hydraulic conductivity parametrizations is used to analyze the flow system and water balance components. Combining an increasing number of hydraulic conductivity zones and an appropriate set of boundary conditions, the hypothesis of a continuous sedimentary unit yielded errors within the calibration target in a regional sense. The magnitude of the water budget terms resulted very similar for all parametrizations. Recharge and stream/aquifer fluxes were the dominant components representing, on average, 84.2% of total inflows and 61.4% of total outflows, respectively. However, leakage was small compared to stream discharges of main rivers. For instance, the simulated average leakage for the Uruguay River was 8 m3 s-1 while the observed absolute minimum discharge was 382 m3 s-1. Streams located in heavily pumped regions switched from a gaining condition in early years to a losing condition over time. Water is discharged through the aquifer boundaries, except at the eastern boundary. On average

  11. Modelling public risk evaluation of natural hazards: a conceptual approach

    Science.gov (United States)

    Plattner, Th.

    2005-04-01

    In recent years, the dealing with natural hazards in Switzerland has shifted away from being hazard-oriented towards a risk-based approach. Decreasing societal acceptance of risk, accompanied by increasing marginal costs of protective measures and decreasing financial resources cause an optimization problem. Therefore, the new focus lies on the mitigation of the hazard's risk in accordance with economical, ecological and social considerations. This modern proceeding requires an approach in which not only technological, engineering or scientific aspects of the definition of the hazard or the computation of the risk are considered, but also the public concerns about the acceptance of these risks. These aspects of a modern risk approach enable a comprehensive assessment of the (risk) situation and, thus, sound risk management decisions. In Switzerland, however, the competent authorities suffer from a lack of decision criteria, as they don't know what risk level the public is willing to accept. Consequently, there exists a need for the authorities to know what the society thinks about risks. A formalized model that allows at least a crude simulation of the public risk evaluation could therefore be a useful tool to support effective and efficient risk mitigation measures. This paper presents a conceptual approach of such an evaluation model using perception affecting factors PAF, evaluation criteria EC and several factors without any immediate relation to the risk itself, but to the evaluating person. Finally, the decision about the acceptance Acc of a certain risk i is made by a comparison of the perceived risk Ri,perc with the acceptable risk Ri,acc.

  12. Triple domain in situ sorption modeling of organochlorine pesticides, polychlorobiphenyls, polyaromatic hydrocarbons, polychlorinated dibenzo-p-dioxins, and polychlorinated dibenzofurans in aquatic sediments

    NARCIS (Netherlands)

    Koelmans, A.A.; Kaag, N.H.B.M.; Sneekes, A.C.; Peeters, E.T.H.M.

    2009-01-01

    Here we analyze the potential of black carbon (BC) and oil-inclusive models to explain in situ sorption of 1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene (DDE), 1,1-dichloro-2,2-bis(p-chlorophenyl)ethane (DDD), organochlorine pesticides (OCP), polychlorobiphenyls (PCB), polyaromatic hydrocarbons

  13. Conceptual model of water resources in the Kabul Basin, Afghanistan

    Science.gov (United States)

    Mack, Thomas J.; Akbari, M. Amin; Ashoor, M. Hanif; Chornack, Michael P.; Coplen, Tyler B.; Emerson, Douglas G.; Hubbard, Bernard E.; Litke, David W.; Michel, Robert L.; Plummer, Niel; Rezai, M. Taher; Senay, Gabriel B.; Verdin, James P.; Verstraeten, Ingrid M.

    2010-01-01

    The United States (U.S.) Geological Survey has been working with the Afghanistan Geological Survey and the Afghanistan Ministry of Energy and Water on water-resources investigations in the Kabul Basin under an agreement supported by the United States Agency for International Development. This collaborative investigation compiled, to the extent possible in a war-stricken country, a varied hydrogeologic data set and developed limited data-collection networks to assist with the management of water resources in the Kabul Basin. This report presents the results of a multidisciplinary water-resources assessment conducted between 2005 and 2007 to address questions of future water availability for a growing population and of the potential effects of climate change. Most hydrologic and climatic data-collection activities in Afghanistan were interrupted in the early 1980s as a consequence of war and civil strife and did not resume until 2003 or later. Because of the gap of more than 20 years in the record of hydrologic and climatic observations, this investigation has made considerable use of remotely sensed data and, where available, historical records to investigate the water resources of the Kabul Basin. Specifically, this investigation integrated recently acquired remotely sensed data and satellite imagery, including glacier and climatic data; recent climate-change analyses; recent geologic investigations; analysis of streamflow data; groundwater-level analysis; surface-water- and groundwater-quality data, including data on chemical and isotopic environmental tracers; and estimates of public-supply and agricultural water uses. The data and analyses were integrated by using a simplified groundwater-flow model to test the conceptual model of the hydrologic system and to assess current (2007) and future (2057) water availability. Recharge in the basin is spatially and temporally variable and generally occurs near streams and irrigated areas in the late winter and early

  14. Building Conceptual Models of Field-Scale Uranium Reactive Transport in a Dynamic Vadose Zone-Aquifer-River System

    International Nuclear Information System (INIS)

    Yabusaki, Steven B.; Fang, Yilin; Waichler, Scott R.

    2008-01-01

    Subsurface simulation is being used to build, test, and couple conceptual process models to better understand controls on a 0.4 km by 1.0 km uranium plume that has persisted above the drinking water standard in the groundwater of the Hanford 300 Area over the last 15 years. At this site, uranium-contaminated sediments in the vadose zone and aquifer are subject to significant variations in water levels and velocities driven by the diurnal, weekly, seasonal, and episodic Columbia River stage dynamics. Groundwater flow reversals typically occur twice a day with significant exchange of river water and groundwater in the near-river aquifer. Mixing of the dilute solution chemistry of the river with the groundwater complicates the uranium sorption behavior as the mobility of U(VI) has been shown experimentally to be a function of pH, carbonate, calcium, and uranium. Furthermore, uranium mass transfer between solid and aqueous phases has been observed to be rate-limited in the context of the high groundwater velocities resulting from the river stage fluctuations and the highly transmissive sediments (hydraulic conductivities ∼1500 m/d). One- and two-dimensional vertical cross-sectional simulations of variably-saturated flow and reactive transport, based on laboratory-derived models of distributed rate mass transfer and equilibrium multicomponent surface complexation, are used to assess uranium transport at the dynamic vadose zone aquifer interface as well as changes to uranium mobility due to incursions of river water into the aquifer

  15. Sorption Energy Maps of Clay Mineral Surfaces

    International Nuclear Information System (INIS)

    Cygan, Randall T.; Kirkpatrick, R. James

    1999-01-01

    A molecular-level understanding of mineral-water interactions is critical for the evaluation and prediction of the sorption properties of clay minerals that may be used in various chemical and radioactive waste disposal methods. Molecular models of metal sorption incorporate empirical energy force fields, based on molecular orbital calculations and spectroscopic data, that account for Coulombic, van der Waals attractive, and short-range repulsive energies. The summation of the non-bonded energy terms at equally-spaced grid points surrounding a mineral substrate provides a three dimensional potential energy grid. The energy map can be used to determine the optimal sorption sites of metal ions on the exposed surfaces of the mineral. By using this approach, we have evaluated the crystallographic and compositional control of metal sorption on the surfaces of kaolinite and illite. Estimates of the relative sorption energy and most stable sorption sites are derived based on a rigid ion approximation

  16. A Scoping Review: Conceptualizations and Pedagogical Models of Learning in Nursing Simulation

    Science.gov (United States)

    Poikela, Paula; Teräs, Marianne

    2015-01-01

    Simulations have been implemented globally in nursing education for years with diverse conceptual foundations. The aim of this scoping review is to examine the literature regarding the conceptualizations of learning and pedagogical models in nursing simulations. A scoping review of peer-reviewed articles published between 2000 and 2013 was…

  17. A conceptual modeling framework for discrete event simulation using hierarchical control structures.

    Science.gov (United States)

    Furian, N; O'Sullivan, M; Walker, C; Vössner, S; Neubacher, D

    2015-08-01

    Conceptual Modeling (CM) is a fundamental step in a simulation project. Nevertheless, it is only recently that structured approaches towards the definition and formulation of conceptual models have gained importance in the Discrete Event Simulation (DES) community. As a consequence, frameworks and guidelines for applying CM to DES have emerged and discussion of CM for DES is increasing. However, both the organization of model-components and the identification of behavior and system control from standard CM approaches have shortcomings that limit CM's applicability to DES. Therefore, we discuss the different aspects of previous CM frameworks and identify their limitations. Further, we present the Hierarchical Control Conceptual Modeling framework that pays more attention to the identification of a models' system behavior, control policies and dispatching routines and their structured representation within a conceptual model. The framework guides the user step-by-step through the modeling process and is illustrated by a worked example.

  18. Hydrogeological conceptual model development and numerical modelling using CONNECTFLOW, Forsmark modelling stage 2.3

    Energy Technology Data Exchange (ETDEWEB)

    Follin, Sven (SF GeoLogic AB, Taeby (Sweden)); Hartley, Lee; Jackson, Peter; Roberts, David (Serco TAP (United Kingdom)); Marsic, Niko (Kemakta Konsult AB, Stockholm (Sweden))

    2008-05-15

    Three versions of a site descriptive model (SDM) have been completed for the Forsmark area. Version 0 established the state of knowledge prior to the start of the site investigation programme. Version 1.1 was essentially a training exercise and was completed during 2004. Version 1.2 was a preliminary site description and concluded the initial site investigation work (ISI) in June 2005. Three modelling stages are planned for the complete site investigation work (CSI). These are labelled stage 2.1, 2.2 and 2.3, respectively. An important component of each of these stages is to address and continuously try to resolve discipline-specific uncertainties of importance for repository engineering and safety assessment. Stage 2.1 included an updated geological model for Forsmark and aimed to provide a feedback from the modelling working group to the site investigation team to enable completion of the site investigation work. Stage 2.2 described the conceptual understanding and the numerical modelling of the bedrock hydrogeology in the Forsmark area based on data freeze 2.2. The present report describes the modelling based on data freeze 2.3, which is the final data freeze in Forsmark. In comparison, data freeze 2.3 is considerably smaller than data freeze 2.2. Therefore, stage 2.3 deals primarily with model confirmation and uncertainty analysis, e.g. verification of important hypotheses made in stage 2.2 and the role of parameter uncertainty in the numerical modelling. On the whole, the work reported here constitutes an addendum to the work reported in stage 2.2. Two changes were made to the CONNECTFLOW code in stage 2.3. These serve to: 1) improve the representation of the hydraulic properties of the regolith, and 2) improve the conditioning of transmissivity of the deformation zones against single-hole hydraulic tests. The changes to the modelling of the regolith were made to improve the consistency with models made with the MIKE SHE code, which involved the introduction

  19. Experimental Results and Model Calculations of a Hybrid Adsorption-Compression Heat Pump Based on a Roots Compressor and Silica Gel-Water Sorption

    Energy Technology Data Exchange (ETDEWEB)

    Van der Pal, M.; De Boer, R.; Wemmers, A.K.; Smeding, S.F.; Veldhuis, J.B.J.; Lycklama a Nijeholt, J.A.

    2013-10-15

    Thermally driven sorption systems can provide significant energy savings, especially in industrial applications. The driving temperature for operation of such systems limits the operating window and can be a barrier for market-introduction. By adding a compressor, the sorption cycle can be run using lower waste heat temperatures. ECN has recently started the development of such a hybrid heat pump. The final goal is to develop a hybrid heat pump for upgrading lower (<100C) temperature industrial waste heat to above pinch temperatures. The paper presents the first measurements and model calculations of a hybrid heat pump system using a water-silica gel system combined with a Roots type compressor. From the measurements can be seen that the effect of the compressor is dependent on where in the cycle it is placed. When placed between the evaporator and the sorption reactor, it has a considerable larger effect compared to the compressor placed between the sorption reactor and the condenser. The latter hardly improves the performance compared to purely heat-driven operation. This shows the importance of studying the interaction between all components of the system. The model, which shows reasonable correlation with the measurements, could proof to be a valuable tool to determine the optimal hybrid heat pump configuration.

  20. Complexities and contingencies conceptualized: towards a model of reproductive navigation

    NARCIS (Netherlands)

    van der Sijpt, E.; Cohn, S.

    2014-01-01

    This chapter provides sociocultural evidence for a different conceptualization of reproductive health behaviour. On the basis of long-term anthropological fieldwork in the East Province of Cameroon the author analyses of the social complexities and contingencies of local fertility-related decisions

  1. Mapping the Territory: A Conceptual Model of Scholastic Journalism.

    Science.gov (United States)

    Arnold, Mary

    Intended to provide a comprehensive conceptual framework to serve as a scaffold for past, present, and future research on "scholastic journalism" (journalism in the secondary school), a topical content analysis of the Association for Education in Journalism and Mass Communication (AEJMC) Secondary Education Division research, teaching,…

  2. Using Multilevel Modeling in Language Assessment Research: A Conceptual Introduction

    Science.gov (United States)

    Barkaoui, Khaled

    2013-01-01

    This article critiques traditional single-level statistical approaches (e.g., multiple regression analysis) to examining relationships between language test scores and variables in the assessment setting. It highlights the conceptual, methodological, and statistical problems associated with these techniques in dealing with multilevel or nested…

  3. Nonequilibrium sorption and transport of volatile petroleum hydrocarbons in surfactant-modified zeolite

    Science.gov (United States)

    Simpson, Joshua A.; Bowman, Robert S.

    2009-08-01

    We characterized the nonequilibrium sorption and transport of benzene, toluene, ethylbenzene, and xylenes (BTEX) by surfactant-modified zeolite (SMZ) in batch and column tests. The SMZ was shown in previous studies to be an effective sorbent for removal of BTEX from oilfield wastewaters prior to disposal or reuse. A two-site, first-order chemical nonequilibrium model was used to determine sorption parameters from the batch results. Individual BTEX linear sorption coefficients, Kd, ranged from 7.5 to 37 L kg - 1 and were independent of BTEX concentration or competing solutes, suggesting that partitioning was the mechanism of sorption. The Kd values were the same whether the zeolite was covered by a monolayer or bilayer of the surfactant hexadecyltrimethylammonium (HDTMA). Batch rate coefficients and the fraction of "instantaneous" sorption sites decreased with BTEX hydrophobicity and with total BTEX concentration. The fraction of "instantaneous" sites was 3-11 times greater for the monolayer as compared to the bilayer SMZ. These observations are consistent with a conceptual model in which BTEX are rapidly partitioned into hydrophobic monolayer surfaces and more slowly partitioned to hydrophilic bilayer surfaces. Results from the batch experiments were used to predict BTEX transport through columns of SMZ. Batch-derived rate and site-distribution parameters accurately described the transport dynamics, but the batch-derived Kds significantly underestimated BTEX retardation. Excess dissolved HDTMA in the batch experiments likely led to anomalously low Kd values for those determinations.

  4. Conceptual and numerical modelling of radionuclide transport in near-surface systems at Forsmark. SR-Site Biosphere

    Energy Technology Data Exchange (ETDEWEB)

    Pique, Angels; Grandia, Fidel; Sena, Clara; Arcos, David; Molinero, Jorge; Duro, Lara; Bruno, Jordi (Amphos21 Consulting S.L., Barcelona (Spain))

    2010-11-15

    In the framework of the SR-Site safety assessment, a conceptual and numerical modelling of radionuclide reactive transport in near-surface systems (including till and clay systems) at Forsmark has been carried out. The objective was to evaluate the retention capacity of the near-surface systems, composed of Quaternary deposits, which would be the last natural barrier for an eventual radionuclide release from the deep repository prior to reaching the biosphere. The studied radionuclides are 14C, 129I, 36Cl, 94Nb, 59Ni, 93Mo, 79Se, 99Tc, 230Th, 90Sr, 226Ra, 135Cs and U. Conceptual description and numerical simulations of radionuclide reactive transport show that cation exchange and surface complexation on illite are active processes for the retention of several radionuclides (U, Th, Ni, Cs, Sr, Ra). Surface complexation on iron hydroxide is an active process in the till system, able to effectively retain U and Ni. Another retention process of importance is the incorporation of the radionuclides into mineral phases, either by the precipitation of pure phases or solid solutions. Quantitative modelling has been useful to illustrate the incorporation of C and Sr in the carbonate solid solution in the considered model domains (till and clay), as well as the precipitation of uraninite in the clay sediments and the precipitation of native selenium and radiobarite in the till. Other mineral phases that could, a priori, retain U, Se, Nb and Tc do not precipitate in the simulations, either due to the pH-Eh conditions and/or because the dissolved concentration of the element is not high enough under the considered simulation conditions. It is important to keep in mind that changes in these parameters and in the boundary conditions could modify the predicted behaviour of these elements. The radionuclides that are most significantly retarded are Th, Ni and Cs, mainly through sorption onto illite. Therefore, if the amount of illite (or available sorption sites) decreases, the

  5. Conceptual and numerical modelling of radionuclide transport in near-surface systems at Forsmark. SR-Site Biosphere

    International Nuclear Information System (INIS)

    Pique, Angels; Grandia, Fidel; Sena, Clara; Arcos, David; Molinero, Jorge; Duro, Lara; Bruno, Jordi

    2010-11-01

    In the framework of the SR-Site safety assessment, a conceptual and numerical modelling of radionuclide reactive transport in near-surface systems (including till and clay systems) at Forsmark has been carried out. The objective was to evaluate the retention capacity of the near-surface systems, composed of Quaternary deposits, which would be the last natural barrier for an eventual radionuclide release from the deep repository prior to reaching the biosphere. The studied radionuclides are 14 C, 129 I, 36 Cl, 94 Nb, 59 Ni, 93 Mo, 79 Se, 99 Tc, 230 Th, 90 Sr, 226 Ra, 135 Cs and U. Conceptual description and numerical simulations of radionuclide reactive transport show that cation exchange and surface complexation on illite are active processes for the retention of several radionuclides (U, Th, Ni, Cs, Sr, Ra). Surface complexation on iron hydroxide is an active process in the till system, able to effectively retain U and Ni. Another retention process of importance is the incorporation of the radionuclides into mineral phases, either by the precipitation of pure phases or solid solutions. Quantitative modelling has been useful to illustrate the incorporation of C and Sr in the carbonate solid solution in the considered model domains (till and clay), as well as the precipitation of uraninite in the clay sediments and the precipitation of native selenium and radiobarite in the till. Other mineral phases that could, a priori, retain U, Se, Nb and Tc do not precipitate in the simulations, either due to the pH-Eh conditions and/or because the dissolved concentration of the element is not high enough under the considered simulation conditions. It is important to keep in mind that changes in these parameters and in the boundary conditions could modify the predicted behaviour of these elements. The radionuclides that are most significantly retarded are Th, Ni and Cs, mainly through sorption onto illite. Therefore, if the amount of illite (or available sorption sites

  6. MARKET ENTRY STRATEGIES TO EMERGING MARKETS: A CONCEPTUAL MODEL OF TURNKEY PROJECT DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Bistra Vassileva

    2016-11-01

    Full Text Available The main purpose of the paper is to analyse the international market entry strategies in the light of globalisation processes and to propose a conceptual model of turnkey projects as market entry mode. The specific research objectives are as follows: 1. to develop an integrated framework of the turnkey marketing process as a conceptual model; 2. to analyse BRICS countries as potential host countries for turnkey projects implementation; 3. to assess potential implications of proposed conceptual model for global market entry decisions.

  7. A participative and facilitative conceptual modelling framework for discrete event simulation studies in healthcare

    OpenAIRE

    Kotiadis, Kathy; Tako, Antuela; Vasilakis, Christos

    2014-01-01

    Existing approaches to conceptual modelling (CM) in discrete-event simulation do not formally support the participation of a group of stakeholders. Simulation in healthcare can benefit from stakeholder participation as it makes possible to share multiple views and tacit knowledge from different parts of the system. We put forward a framework tailored to healthcare that supports the interaction of simulation modellers with a group of stakeholders to arrive at a common conceptual model. The fra...

  8. Selection and Configuration of Sorption Isotherm Models in Soils Using Artificial Bees Guided by the Particle Swarm

    Directory of Open Access Journals (Sweden)

    Tadikonda Venkata Bharat

    2017-01-01

    Full Text Available A precise estimation of isotherm model parameters and selection of isotherms from the measured data are essential for the fate and transport of toxic contaminants in the environment. Nonlinear least-square techniques are widely used for fitting the isotherm model on the experimental data. However, such conventional techniques pose several limitations in the parameter estimation and the choice of appropriate isotherm model as shown in this paper. It is demonstrated in the present work that the classical deterministic techniques are sensitive to the initial guess and thus the performance is impeded by the presence of local optima. A novel solver based on modified artificial bee-colony (MABC algorithm is proposed in this work for the selection and configuration of appropriate sorption isotherms. The performance of the proposed solver is compared with the other three solvers based on swarm intelligence for model parameter estimation using measured data from 21 soils. Performance comparison of developed solvers on the measured data reveals that the proposed solver demonstrates excellent convergence capabilities due to the superior exploration-exploitation abilities. The estimated solutions by the proposed solver are almost identical to the mean fitness values obtained over 20 independent runs. The advantages of the proposed solver are presented.

  9. Study of uranium(VI) and radium(II) sorption at trace level on kaolinite using a multisite ion exchange model.

    Science.gov (United States)

    Reinoso-Maset, Estela; Ly, Jacques

    2016-06-01

    Uranium and the long-lived decay product radium-226 are abundantly present in mine wastes produced during uranium extraction activities. In the case of release to the surrounding environment, these radionuclides are at trace level compared to groundwater solutes, and the presence, content and properties of clay minerals in the host environment influence the extent of radionuclide sorption and, in turn, migration. Since clays are known to have the distinctive property of retaining ions, the aim of this work was to study the sorption of trace U(VI) and Ra(II) on a common phyllosilicate mineral, kaolinite, in the presence of excess K, a common groundwater cation, in order to obtain a thermodynamic database that describes the ion exchange equilibria occurring at the mineral-solution interface. Following a detailed experimental protocol using chemical and radiochemical analytical techniques, batch experiments over a wide pH range (from 2 to 11) and fixed concentration (ca. 10(-9) M), and additional adsorption isotherms at two different solution pH (6.2 and 10.4) over a concentration range (10(-10) to 10(-4) M) were carried out to measure the distribution coefficient (Kd) of U(VI) and Ra(II) sorption on kaolinite. The experimental sorption data was processed according to a general multisite sorbent/multispecies sorbate ion exchange model, which allowed deducing the charge of adsorbed species and the stoichiometry of the associated adsorption equilibria on kaolinite's surface sites. Aqueous speciation calculations predicted Ra(II) as Ra(2+) over the working pH range, and its adsorption curves and isotherms were explained using three sorption sites. Adsorption of U(VI) occurred on four sorption sites and was governed by its solution speciation, with positively charged hydroxylated (UO2(2+) and UO2(OH)(+)) and silicate (UO2(H3SiO4)(+)) species being adsorbed between pH 2 and 6, whereas its negatively charged forms (UO2(OH)3(-) and UO2(OH)4(2-)) dominated U(VI) sorption at

  10. TECHNETIUM SORPTION BY CEMENTITIOUS MATERIALS UNDER REDUCING CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, D.; Estes, S.; Arai, Y.; Powell, B.

    2012-01-31

    The objective of this study was to measure Tc sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. Earlier studies were conducted and the experimental conditions were found not to simulate those of the facility. Through a five month subcontract with Clemson University, sorption of {sup 99}Tc to four cementitious materials was examined within an anaerobic glovebag targeting a 0.1% H2(g)/ 99.9% N{sub 2}(g) atmosphere. Early experiments based on Tc sorption and Eh indicated that 0.1% H{sub 2}(g) (a reductant) was necessary to preclude experimental impacts from O{sub 2}(g) diffusion into the glovebag. Preliminary data to date (up to 56 days) indicates that sorption of {sup 99}Tc to cementitious materials increased with increasing slag content for simulated saltstone samples. This is consistent with the conceptual model that redox active sulfide groups within the reducing slag facilitate reduction of Tc(VII) to Tc(IV). These experiments differ from previous experiments where a 2% H{sub 2}(g) atmosphere was maintained (Kaplan et al., 2011 (SRNL-STI-2010-00668)). The impact of the 2% H{sub 2}(g) reducing atmosphere on this data was examined and determined to cause the reduction of Tc in experimental samples without slag. In the present ongoing study, after 56 days, Tc sorption by the 50-year old cement samples (no slag) was undetectable, whereas Tc sorption in the cementitious materials containing slag continues to increase with contact time (measured after 1, 4, 8, 19 and 56 days). Sorption was not consistent with spike concentrations and steady state has not been demonstrated after 56 days. The average conditional K{sub d} value for the Vault 2 cementitious material was 6,362 mL/g (17% slag), for the TR547 Saltstone (45% slag) the conditional K{sub d} was 1258 mL/g, and for TR545 (90% slag) the conditional K{sub d} was 12,112 mL/g. It is anticipated that additional samples will be collected until steady state

  11. A CONCEPTUAL TRAJECTORY MULTIDIMENSIONAL MODEL: AN APPLICATION TO PUBLIC TRANSPORTATION

    Directory of Open Access Journals (Sweden)

    FRANCISCO MORENO

    2011-01-01

    Full Text Available Actualmente, gracias a tecnologías como los sistemas de posicionamiento global y dispositivos móviles provistos de sensores, se puede recopilar una gran cantidad de datos sobre objetos móviles, e.g., datos relacionados con la trayectoria seguida por estos objetos. Por otra parte, las Bodegas de Datos (BDs, usualmente modeladas mediante una vista multidimensional de los datos, son bases de datos especializadas para ayudar en la toma de decisiones. Desafortunadamente, las BDs convencionales ofrecen poco soporte para la gestión de trayectorias. Aunque existen algunas propuestas que tratan con BDs de trayectorias, ninguna de ellas se enfoca en su modelamiento conceptual multidimensional. En este artículo se extiende un modelo conceptual multidimensional espacial donde se incorporan las trayectorias como conceptos de primera clase. Con el fi n de mostrar la conveniencia de la propuesta, se presenta un ejemplo relacionado con transporte público.

  12. The effect of different log P algorithms on the modeling of the soil sorption coefficient of nonionic pesticides.

    Science.gov (United States)

    dos Reis, Ralpho Rinaldo; Sampaio, Silvio César; de Melo, Eduardo Borges

    2013-10-01

    Collecting data on the effects of pesticides on the environment is a slow and costly process. Therefore, significant efforts have been focused on the development of models that predict physical, chemical or biological properties of environmental interest. The soil sorption coefficient normalized to the organic carbon content (Koc) is a key parameter that is used in environmental risk assessments. Thus, several log Koc prediction models that use the hydrophobic parameter log P as a descriptor have been reported in the literature. Often, algorithms are used to calculate the value of log P due to the lack of experimental values for this property. Despite the availability of various algorithms, previous studies fail to describe the procedure used to select the appropriate algorithm. In this study, models that correlate log Koc with log P were developed for a heterogeneous group of nonionic pesticides using different freeware algorithms. The statistical qualities and predictive power of all of the models were evaluated. Thus, this study was conducted to assess the effect of the log P algorithm choice on log Koc modeling. The results clearly demonstrate that the lack of a selection criterion may result in inappropriate prediction models. Seven algorithms were tested, of which only two (ALOGPS and KOWWIN) produced good results. A sensible choice may result in simple models with statistical qualities and predictive power values that are comparable to those of more complex models. Therefore, the selection of the appropriate log P algorithm for modeling log Koc cannot be arbitrary but must be based on the chemical structure of compounds and the characteristics of the available algorithms. Copyright © 2013 Elsevier Ltd. All rights reserved.

  13. Effect of hydrolyzed whey protein on surface morphology, water sorption, and glass transition temperature of a model infant formula.

    Science.gov (United States)

    Kelly, Grace M; O'Mahony, James A; Kelly, Alan L; O'Callaghan, Donal J

    2016-09-01

    Physical properties of spray-dried dairy powders depend on their composition and physical characteristics. This study investigated the effect of hydrolyzed whey protein on the microstructure and physical stability of dried model infant formula. Model infant formulas were produced containing either intact (DH 0) or hydrolyzed (DH 12) whey protein, where DH=degree of hydrolysis (%). Before spray drying, apparent viscosities of liquid feeds (at 55°C) at a shear rate of 500 s(-1) were 3.02 and 3.85 mPa·s for intact and hydrolyzed infant formulas, respectively. On reconstitution, powders with hydrolyzed whey protein had a significantly higher fat globule size and lower emulsion stability than intact whey protein powder. Lactose crystallization in powders occurred at higher relative humidity for hydrolyzed formula. The Guggenheim-Anderson-de Boer equation, fitted to sorption isotherms, showed increased monolayer moisture when intact protein was present. As expected, glass transition decreased significantly with increasing water content. Partial hydrolysis of whey protein in model infant formula resulted in altered powder particle surface morphology, lactose crystallization properties, and storage stability. Copyright © 2016 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

  14. The 8 Learning Events Model: a Pedagogic Conceptual Tool Supporting Diversification of Learning Methods

    NARCIS (Netherlands)

    Verpoorten, Dominique; Poumay, M; Leclercq, D

    2006-01-01

    Please, cite this publication as: Verpoorten, D., Poumay, M., & Leclercq, D. (2006). The 8 Learning Events Model: a Pedagogic Conceptual Tool Supporting Diversification of Learning Methods. Proceedings of International Workshop in Learning Networks for Lifelong Competence Development, TENCompetence

  15. Supporting conceptual modelling of dynamic systems: A knowledge engineering perspective on qualitative reasoning

    NARCIS (Netherlands)

    Liem, J.

    2013-01-01

    Research has shown that even students educated in science at prestigious universities have misconceptions about the systems underlying climate change, sustainability and government spending. Interactive conceptual modelling and simulation tools, which are based on Artificial Intelligence techniques,

  16. A conceptual model of channel choice : measuring online and offline shopping value perceptions

    NARCIS (Netherlands)

    Broekhuizen, Thijs L.J.; Jager, Wander

    2004-01-01

    This study tries to understand how consumers evaluate channels for their purchasing. Specifically, it develops a conceptual model that addresses consumer value perceptions of using the Internet versus the traditional (physical) channel. Previous research showed that perceptions of price, product

  17. Experimental And Modelling Investigations on Na-Illite: Acid-Base Behaviour And the Sorption Of Strontium, Nickel, Europium And Uranyl

    International Nuclear Information System (INIS)

    Bradbury, M.H.; Baeyens, B.

    2005-06-01

    In an extensive study the physico-chemical, protolysis and sorption characteristics of Sr(II), Ni(II), Eu(III) and U(VI) have been measured on illite and modeled over a wide range of pH, sorbate and NaCI0 4 concentrations. SampIes of Illite du Puy, collected in the region of Le Puy-en- Velay, France, were carefully conditioned to the Na-form and physico-chemically characterised. Potentiometric titrations on suspensions of the Na-illite were carried out using a batch back titration technique in 0.01, 0.1 and 0.5 M NaCI0 4 background electrolytes from pH 2 to 12 in an inert atmosphere glove box. The supernatant solutions from each titration experiment in each series were analysed for K, Mg, Ca, Sr, Si, Al, Fe and Mn. The titration data were modeled in terms of the protolysis of two amphoteric edge sites (=S W1 0H and =S W2 0H) without an electrostatic term. The protonation/deprotonation constants and site capacities obtained from the titration measurements were then fixed. The sorption edge and isotherm data were modeled with strong (=S S OH) and weak (=S W1 0H) surface complexation sites, assumed to have the same protolysis constants, again without electrostatic terms. Uptake by cation exchange was included in all of the calculations. This sorption model, the 2 site protolysis non electrostatic surface complexation and cation exchange model, had been developed previously for montmorillonite and was successful in describing the sorption characteristics of Sr, Ni, Eu and U on Na-illite over a wide range of conditions. Cation exchange capacity, strong and weak site capacities and protolysis constants for Na-illite are given, together with surface complexation constants and selectivity coefficients for Sr, Ni, Eu and U. At 0.01 M NaCI0 4 and pH below 8 the sorption of Sr, Ni, Eu and U was dominated by a cation exchange mechanism. The strong dependency of sorption on pH observed under these conditions arose from the competitive effects of Ca and Al on the uptake of the

  18. Large regional groundwater modeling - a sensitivity study of some selected conceptual descriptions and simplifications

    International Nuclear Information System (INIS)

    Ericsson, Lars O.; Holmen, Johan

    2010-12-01

    The primary aim of this report is: - To present a supplementary, in-depth evaluation of certain conceptual simplifications, descriptions and model uncertainties in conjunction with regional groundwater simulation, which in the first instance refer to model depth, topography, groundwater table level and boundary conditions. Implementation was based on geo-scientifically available data compilations from the Smaaland region but different conceptual assumptions have been analysed

  19. ASSETS MANAGEMENT - A CONCEPTUAL MODEL DECOMPOSING VALUE FOR THE CUSTOMER AND A QUANTITATIVE MODEL

    Directory of Open Access Journals (Sweden)

    Susana Nicola

    2015-03-01

    Full Text Available In this paper we describe de application of a modeling framework, the so-called Conceptual Model Decomposing Value for the Customer (CMDVC, in a Footwear Industry case study, to ascertain the usefulness of this approach. The value networks were used to identify the participants, both tangible and intangible deliverables/endogenous and exogenous assets, and the analysis of their interactions as the indication for an adequate value proposition. The quantitative model of benefits and sacrifices, using the Fuzzy AHP method, enables the discussion of how the CMDVC can be applied and used in the enterprise environment and provided new relevant relations between perceived benefits (PBs.

  20. Two-Dimensional Model for Reactive-Sorption Columns of Cylindrical Geometry: Analytical Solutions and Moment Analysis.

    Science.gov (United States)

    Khan, Farman U; Qamar, Shamsul

    2017-05-01

    A set of analytical solutions are presented for a model describing the transport of a solute in a fixed-bed reactor of cylindrical geometry subjected to the first (Dirichlet) and third (Danckwerts) type inlet boundary conditions. Linear sorption kinetic process and first-order decay are considered. Cylindrical geometry allows the use of large columns to investigate dispersion, adsorption/desorption and reaction kinetic mechanisms. The finite Hankel and Laplace transform techniques are adopted to solve the model equations. For further analysis, statistical temporal moments are derived from the Laplace-transformed solutions. The developed analytical solutions are compared with the numerical solutions of high-resolution finite volume scheme. Different case studies are presented and discussed for a series of numerical values corresponding to a wide range of mass transfer and reaction kinetics. A good agreement was observed in the analytical and numerical concentration profiles and moments. The developed solutions are efficient tools for analyzing numerical algorithms, sensitivity analysis and simultaneous determination of the longitudinal and transverse dispersion coefficients from a laboratory-scale radial column experiment. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  1. Research program to develop and validate conceptual models for flow and transport through unsaturated, fractured rock

    International Nuclear Information System (INIS)

    Glass, R.J.; Tidwell, V.C.

    1991-09-01

    As part of the Yucca Mountain Project, our research program to develop and validate conceptual models for flow and transport through unsaturated fractured rock integrates fundamental physical experimentation with conceptual model formulation and mathematical modeling. Our research is directed toward developing and validating macroscopic, continuum-based models and supporting effective property models because of their widespread utility within the context of this project. Success relative to the development and validation of effective property models is predicted on a firm understanding of the basic physics governing flow through fractured media, specifically in the areas of unsaturated flow and transport in a single fracture and fracture-matrix interaction

  2. Research program to develop and validate conceptual models for flow and transport through unsaturated, fractured rock

    International Nuclear Information System (INIS)

    Glass, R.J.; Tidwell, V.C.

    1991-01-01

    As part of the Yucca Mountain Project, our research program to develop and validate conceptual models for flow and transport through unsaturated fractured rock integrates fundamental physical experimentation with conceptual model formulation and mathematical modeling. Our research is directed toward developing and validating macroscopic, continuum-based models and supporting effective property models because of their widespread utility within the context of this project. Success relative to the development and validation of effective property models is predicated on a firm understanding of the basic physics governing flow through fractured media, specifically in the areas of unsaturated flow and transport in a single fracture and fracture-matrix interaction. 43 refs

  3. Regional hydrogeological conceptual model of candidate Beishan area for high level radioactive waste disposal repository

    International Nuclear Information System (INIS)

    Wang Hailong; Guo Yonghai

    2014-01-01

    The numerical modeling of groundwater flow is an important aspect of hydrogeological assessment in siting of a high level radioactive waste disposal repository. Hydrogeological conceptual model is the basic and premise of numerical modeling of groundwater flow. Based on the hydrogeological analysis of candidate Beishan area, surface water system was created by using DEM data and the modeling area is determined. Three-dimensional hydrogeological structure model was created through GMS software. On the basis of analysis and description of boundary condition, flow field, groundwater budget and hydrogeological parameters, hydrogeological conceptual model was set up for the Beishan area. (authors)

  4. Phenanthrene sorption to Chinese coal: Importance of coal's geochemical properties

    International Nuclear Information System (INIS)

    Yan Caixia; Yang Yi; Liu Min; Nie Minghua; Zhou, John L.

    2011-01-01

    Highlights: → Phen was chosen as the probe compound for determining the sorption of PAHs to a series of different Chinese coal samples. → The combined partition and adsorption model yielded a better fit than the Freundlich isotherm. → Compared to total carbon, BC might play more important role in the sorption of Phen to coal samples. → Relationships between aromatic and aliphatic carbon contents and sorption parameters indicated the significance of aromatic and aliphatic carbon in the coal sorption behavior. - Abstract: Phenanthrene (Phen) was chosen as the probe compound for determining the sorption of PAHs to a series of different coal samples from China. Based on elemental analysis and nuclear magnetic resonance (NMR) spectra analysis, coal samples were characterized with different metamorphic evolutional degrees. The experimental sorption data were fitted well by the Freundlich model, suggesting enhanced sorption capacity and strong nonlinearity of coal samples. The combined partition and adsorption model yielded a better fit than the Freundlich isotherm, indicating that adsorption dominated the sorption at low aqueous concentrations. Correlations between coal properties and sorption capacity values indicated that C%, H/C and O/C atomic ratios were the key factors controlling the sorption behavior. Compared to total carbon, BC might play more important role in the sorption of Phen to coal samples. Moreover, there existed nonlinear relationships between combined carbon, aromatic and aliphatic carbon contents and log K Fr and n values, respectively, indicating the significance of aromatic and aliphatic carbon in the coal sorption behavior.

  5. Organizational intellectual capital and the role of the nurse manager: A proposed conceptual model.

    Science.gov (United States)

    Gilbert, Jason H; Von Ah, Diane; Broome, Marion E

    Nurse managers must leverage both the human capital and social capital of the teams they lead in order to produce quality outcomes. Little is known about the relationship between human capital and social capital and how these concepts may work together to produce organizational outcomes through leadership of nurses. The purpose of this article was to explore the concepts of human capital and social capital as they relate to nursing leadership in health care organizations. Specific aims included (a) to synthesize the literature related to human capital and social capital in leadership, (b) to refine the conceptual definitions of human capital and social capital with associated conceptual antecedents and consequences, and (c) to propose a synthesized conceptual model guiding further empirical research of social capital and human capital in nursing leadership. A systematic integrative review of leadership literature using criteria informed by Whittemore and Knafl (2005) was completed. CINAHL Plus with Full Text, Academic Search Premier, Business Source Premier, Health Business FullTEXT, MEDLINE, and PsychINFO databases were searched for the years 1995 to 2016 using terms "human capital," "social capital," and "management." Analysis of conceptual definitions, theoretical and conceptual models, antecedents and consequences, propositions or hypotheses, and empirical support for 37 articles fitting review criteria resulted in the synthesis of the proposed Gilbert Conceptual Model of Organizational Intellectual Capital. The Gilbert Conceptual Model of Organizational Intellectual Capital advances the propositions of human capital theory and social capital theory and is the first model to conceptualize the direct and moderating effects that nurse leaders have on the human capital and social capital of the teams they lead. This model provides a framework for further empirical study and may have implications for practice, organizational policy, and education related to nursing

  6. Modeling of radionuclide and heavy metal sorption around low and high pH waste disposal sites at Oak Ridge, Tennessee: Classification review package

    International Nuclear Information System (INIS)

    Saunders, J.A.

    1994-10-01

    Modeling of mineral precipitation and metal sorption reactions using MINTEQA2 and the iron oxyhydroxide diffuse-layer model has provided insights into geochemical processes governing contaminant migration from low-level radioactive waste disposal sites at the US Department of Energy's Oak Ridge National Laboratory and Y-12 Plant at Oak Ridge, Tennessee. Both acidic and basic nuclear-fuel reprocessing wastes, locally mixed with decontamination solvents, were disposed of in unlined trenches and lagoons. Model results show that as wastes move toward neutral pH due to reactions with surrounding soils and saprolite, mineral precipitation and sorption can limit the solubility of heavy metals and radionuclides. However, observed contaminant levels in monitoring wells indicate that at least locally, wastes are moving in faults and fractures and are not retarded by sorption reactions along such flow paths. Model results also support previous studies that have indicated organic complexing agents used in decontamination procedures can enhance radionuclide and heavy metal solubility when mixed with nuclear fuel reprocessing wastes. However, complex interactions between metal-organic complexes and mineral surfaces and natural organic matter, biodegradation, and fracture flow complicate the interpretation of contaminant mobility

  7. What do we know about the defect types detected in conceptual models?

    NARCIS (Netherlands)

    Granda, Maria Fernanda; Condori-Fernandez, Nelly; Vos, Tanja E.J.; Pastor, Oscar

    2015-01-01

    In Model-Driven Development (MDD), defects are managed at the level of conceptual models because the other artefacts are generated from them, such as more refined models, test cases and code. Although some studies have reported on defect types at model level, there still does not exist a clear and

  8. A Conceptual Model for Analysing Management Development in the UK Hospitality Industry

    Science.gov (United States)

    Watson, Sandra

    2007-01-01

    This paper presents a conceptual, contingent model of management development. It explains the nature of the UK hospitality industry and its potential influence on MD practices, prior to exploring dimensions and relationships in the model. The embryonic model is presented as a model that can enhance our understanding of the complexities of the…

  9. Literature Review of Enterprise Systems Research Using Institutional Theory: Towards a Conceptual Model

    DEFF Research Database (Denmark)

    Svejvig, Per

    This paper sets out to examine the use of institutional theory as a conceptually rich lens to study social issues of enterprise systems (ES) research. More precisely, the purpose is to categorize current ES research using institutional theory to develop a conceptual model that advances ES research....... Key institutional features are presented such as isomorphism, rationalized myths, bridging macro and micro structures, and institutional logics and their implications for ES research are discussed. Through a literature review of 180 articles, of which 18 papers are selected, we build a conceptual...

  10. ON AN APPROACH TO MODELLING THE CONCEPTUAL SPACE OF LANGUAGE SIGNS AND TEXTS

    Directory of Open Access Journals (Sweden)

    Ivanova, E.V.

    2017-12-01

    Full Text Available The paper examines one of the possible approaches to exploring the conceptual space represented by language signs and texts. The notion of the cognitheme as a unit of knowledge in the form of a proposition, functional for modelling the conceptual space, is defined and some principles of the cognitheme analysis are discussed. The cognitheme is considered as a unit of modelling mental entities reflected in the language, for example, such as the concept or the conceptual space connected with a text, and at the same time as a unit of conceptualization significant in its own right, revealing elements of knowledge important for a language community and thus fixed in language signs and texts. A feasible classification of cognithemes is described, examples illustrating this classification are given.

  11. Sorption and migration of neptunium in porous sedimentary materials

    International Nuclear Information System (INIS)

    Tanaka, Tadao; Mukai, Masayuki; Nakayama, Shinichi

    2005-01-01

    Column migration experiments of neptunium were conducted for porous sedimentary materials: coastal sand, tuffaceous sand, ando soil, reddish soil, yellowish soil and loess, and migration behavior, sorption mechanisms and chemical formation of Np were investigated. The migration behavior of Np in each material was much different each other, due to chemical formation in solution and/or sorption mechanism of Np. Mathematical models of different concepts were applied to the experimental results to interpret the sorption mechanism and the migration behavior. It can be concluded that both of instantaneous equilibrium sorption and sorption-desorption kinetics have to be considered to model the Np migration in sedimentary materials. (author)

  12. Three-dimensional conceptual model for the Hanford Site unconfined aquifer system: FY 1994 status report

    Energy Technology Data Exchange (ETDEWEB)

    Thorne, P.D.; Chamness, M.A.; Vermeul, V.R.; Macdonald, Q.C.; Schubert, S.E.

    1994-11-01

    This report documents work conducted during the fiscal year 1994 to development an improved three-dimensional conceptual model of ground-water flow in the unconfined aquifer system across the Hanford Site Ground-Water Surveillance Project, which is managed by Pacific Northwest Laboratory. The main objective of the ongoing effort to develop an improved conceptual model of ground-water flow is to provide the basis for improved numerical report models that will be capable of accurately predicting the movement of radioactive and chemical contaminant plumes in the aquifer beneath Hanford. More accurate ground-water flow models will also be useful in assessing the impacts of changes in facilities and operations. For example, decreasing volumes of operational waste-water discharge are resulting in a declining water table in parts of the unconfined aquifer. In addition to supporting numerical modeling, the conceptual model also provides a qualitative understanding of the movement of ground water and contaminants in the aquifer.

  13. Conceptual Models of the Individual Public Service Provider

    DEFF Research Database (Denmark)

    Andersen, Lotte Bøgh; Bhatti, Yosef; Petersen, Ole Helby

    Individual public service providers’ motivation can be conceptualized as either extrinsic, autonomous or prosocial, and the question is how we can best theoretically understand this complexity without losing too much coherence and parsimony. Drawing on Allison’s approach (1969), three perspectives...... are used to gain insight on the motivation of public service providers; namely principal-agent theory, self-determination theory and public service motivation theory. We situate the theoretical discussions in the context of public service providers being transferred to private organizations...... as a consequence of outsourcing by the public sector. Although this empirical setting is interesting in itself, here it serves primarily as grist for a wider discussion on strategies for applying multiple theoretical approaches and crafting a theoretical synthesis. The key contribution of the paper is thus...

  14. Investigating conceptual models for physical property couplings in solid solution models of cement

    International Nuclear Information System (INIS)

    Benbow, Steven; Watson, Claire; Savage, David

    2005-11-01

    The long-term behaviour of cementitious engineered barriers is an important process to consider when modelling the migration of radionuclides from a geological repository for nuclear waste. The modelling of cement is complicated by the fact that the cement is dominated by the behaviour of calcium silicate hydrate (CSH) gel which is a complex solid exhibiting incongruent dissolution behaviour. In this report, we have demonstrated the implementation of a solid-solution CSH gel model within a geochemical transport modelling framework using the Raiden computer code to investigate cement/concrete-groundwater interactions. The modelling conducted here shows that it is possible to couple various conceptual models for the evolution of physical properties of concrete with a solid solution model for cement degradation in a fully coupled geochemical transport model to describe the interaction of cement/concrete engineered barriers with groundwater. The results show that changes to the conceptual models and flow rates can give rise to very different evolutions. Most simulations were carried out at a reduced 'experimental' scale rather than full repository scale. The work has shown the possibility to investigate also the changing physical properties of degrading cement. To further develop the model more emphasis is needed on kinetics and the detailed development of a nearly clogged pore space. Modelling of the full repository scale could be another way forward to understand the behaviour of degrading concrete. A general conclusion is that the combined effects of chemical evolution and physical degradation should be analysed in performance assessments of cementitious repositories. Moreover, the project results will be used as one basis in coming reviews of SKB's safety assessments of repositories for spent fuel and low-and intermediate level waste

  15. Investigating conceptual models for physical property couplings in solid solution models of cement

    Energy Technology Data Exchange (ETDEWEB)

    Benbow, Steven; Watson, Claire; Savage, David [Quintesssa Ltd., Henley-on-Thames (United Kingdom)

    2005-11-15

    The long-term behaviour of cementitious engineered barriers is an important process to consider when modelling the migration of radionuclides from a geological repository for nuclear waste. The modelling of cement is complicated by the fact that the cement is dominated by the behaviour of calcium silicate hydrate (CSH) gel which is a complex solid exhibiting incongruent dissolution behaviour. In this report, we have demonstrated the implementation of a solid-solution CSH gel model within a geochemical transport modelling framework using the Raiden computer code to investigate cement/concrete-groundwater interactions. The modelling conducted here shows that it is possible to couple various conceptual models for the evolution of physical properties of concrete with a solid solution model for cement degradation in a fully coupled geochemical transport model to describe the interaction of cement/concrete engineered barriers with groundwater. The results show that changes to the conceptual models and flow rates can give rise to very different evolutions. Most simulations were carried out at a reduced 'experimental' scale rather than full repository scale. The work has shown the possibility to investigate also the changing physical properties of degrading cement. To further develop the model more emphasis is needed on kinetics and the detailed development of a nearly clogged pore space. Modelling of the full repository scale could be another way forward to understand the behaviour of degrading concrete. A general conclusion is that the combined effects of chemical evolution and physical degradation should be analysed in performance assessments of cementitious repositories. Moreover, the project results will be used as one basis in coming reviews of SKB's safety assessments of repositories for spent fuel and low-and intermediate level waste.

  16. A Conceptual View of the Officer Procurement Model (TOPOPS). Technical Report No. 73-73.

    Science.gov (United States)

    Akman, Allan; Nordhauser, Fred

    This report presents the conceptual design of a computer-based linear programing model of the Air Force officer procurement system called TOPOPS. The TOPOPS model is an aggregate model which simulates officer accession and training and is directed at optimizing officer procurement in terms of either minimizing cost or maximizing accession quality…

  17. Elements of a flexible approach for conceptual hydrological modeling : 2. Application and experimental insights

    NARCIS (Netherlands)

    Kavetski, D.; Fenicia, F.

    2011-01-01

    In this article's companion paper, flexible approaches for conceptual hydrological modeling at the catchment scale were motivated, and the SUPERFLEX framework, based on generic model components, was introduced. In this article, the SUPERFLEX framework and the “fixed structure” GR4H model (an hourly

  18. A Hierarchical Structural Model for the Interpretation of Mercury Porosimetry and Nitrogen Sorption.

    Science.gov (United States)

    Rigby

    2000-04-15

    A new model of interpretation for the mercury porosimetry experiment has been presented. The void space of a porous solid is modeled by separate representations of both the macroscopic (>10 µm) and the mesoscopic (catalyst manufacture and the deactivation of catalysts by coke deposition. Copyright 2000 Academic Press.

  19. Quantification of Cation Sorption to Engineered Barrier Materials Under Extreme Conditions

    International Nuclear Information System (INIS)

    Powell, Brian; Schlautman, Mark; Rao, Linfeng; Nitsche, Heino; Gregorich, Kenneth

    2016-01-01

    The objective of this research is to examine mechanisms and thermodynamics of actinide sorption to engineered barrier materials (iron (oxyhydr)oxides and bentonite clay) for nuclear waste repositories under high temperature and high ionic strength conditions using a suite of macroscopic and microscopic techniques which will be coupled with interfacial reaction models. Gaining a mechanistic understanding of interfacial processes governing the sorption/sequestration of actinides at mineral-water interfaces is fundamental for the accurate prediction of actinide behavior in waste repositories. Although macroscale sorption data and various spectroscopic techniques have provided valuable information regarding speciation of actinides at solid-water interfaces, significant knowledge gaps still exist with respect to sorption mechanisms and the ability to quantify sorption, particularly at high temperatures and ionic strengths. This objective is addressed through three major tasks: (1) influence of oxidation state on actinide sorption to iron oxides and clay minerals at elevated temperatures and ionic strengths; (2) calorimetric titrations of actinide-mineral suspensions; (3) evaluation of bentonite performance under repository conditions. The results of the work will include a qualitative conceptual model and a quantitative thermodynamic speciation model describing actinide partitioning to minerals and sediments, which is based upon a mechanistic understanding of specific sorption processes as determined from both micro-scale and macroscale experimental techniques. The speciation model will be a thermodynamic aqueous and surface complexation model of actinide interactions with mineral surfaces that is self-consistent with macroscopic batch sorption data, calorimetric and potentiometric titrations, X-ray absorption Spectroscopy (XAS, mainly Extended X-ray Absorption Fine Structure (EXAFS)), and electron microscopy analyses. The novelty of the proposed work lies largely in

  20. Quantification of Cation Sorption to Engineered Barrier Materials Under Extreme Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Powell, Brian [Clemson Univ., SC (United States); Schlautman, Mark [Clemson Univ., SC (United States); Rao, Linfeng [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Nitsche, Heino [Univ. of California, Berkeley, CA (United States); Gregorich, Kenneth [Univ. of California, Berkeley, CA (United States)

    2016-02-02

    The objective of this research is to examine mechanisms and thermodynamics of actinide sorption to engineered barrier materials (iron (oxyhydr)oxides and bentonite clay) for nuclear waste repositories under high temperature and high ionic strength conditions using a suite of macroscopic and microscopic techniques which will be coupled with interfacial reaction models. Gaining a mechanistic understanding of interfacial processes governing the sorption/sequestration of actinides at mineral-water interfaces is fundamental for the accurate prediction of actinide behavior in waste repositories. Although macroscale sorption data and various spectroscopic techniques have provided valuable information regarding speciation of actinides at solid-water interfaces, significant knowledge gaps still exist with respect to sorption mechanisms and the ability to quantify sorption, particularly at high temperatures and ionic strengths. This objective is addressed through three major tasks: (1) influence of oxidation state on actinide sorption to iron oxides and clay minerals at elevated temperatures and ionic strengths; (2) calorimetric titrations of actinide-mineral suspensions; (3) evaluation of bentonite performance under repository conditions. The results of the work will include a qualitative conceptual model and a quantitative thermodynamic speciation model describing actinide partitioning to minerals and sediments, which is based upon a mechanistic understanding of specific sorption processes as determined from both micro-scale and macroscale experimental techniques. The speciation model will be a thermodynamic aqueous and surface complexation model of actinide interactions with mineral surfaces that is self-consistent with macroscopic batch sorption data, calorimetric and potentiometric titrations, X-ray absorption Spectroscopy (XAS, mainly Extended X-ray Absorption Fine Structure (EXAFS)), and electron microscopy analyses. The novelty of the proposed work lies largely in

  1. Navigating Tensions Between Conceptual and Metaconceptual Goals in the Use of Models

    Science.gov (United States)

    Delgado, Cesar

    2015-04-01

    Science education involves learning about phenomena at three levels: concrete (facts and generalizations), conceptual (concepts and theories), and metaconceptual (epistemology) (Snir et al. in J Sci Educ Technol 2(2):373-388, 1993). Models are key components in science, can help build conceptual understanding, and may also build metaconceptual understanding. Technology can transform teaching and learning by turning models into interactive simulations that learners can investigate. This paper identifies four characteristics of models and simulations that support conceptual learning but misconstrue models and science at a metaconceptual level. Ahistorical models combine the characteristics of several historical models; they conveniently compile ideas but misrepresent the history of science (Gilbert in Int J Sci Math Educ 2(2):115-130, 2004). Teleological models explain behavior in terms of a final cause; they can lead to useful heuristics but imply purpose in processes driven by chance and probability (Talanquer in Int J Sci Educ 29(7):853-870, 2007). Epistemological overreach occurs when models or simulations imply greater certainty and knowledge about phenomena than warranted; conceptualizing nature as being well known (e.g., having a mathematical structure) poses the danger of conflating model and reality or data and theory. Finally, models are inevitably ontologically impoverished. Real-world deviations and many variables are left out of models, as models' role is to simplify. Models and simulations also lose much of the sensory data present in phenomena. Teachers, designers, and professional development designers and facilitators must thus navigate the tension between conceptual and metaconceptual learning when using models and simulations. For each characteristic, examples are provided, along with recommendations for instruction and design. Prompts for explicit reflective activities around models are provided for each characteristic

  2. Conceptual model of sediment processes in the upper Yuba River watershed, Sierra Nevada, CA

    Science.gov (United States)

    Curtis, J.A.; Flint, L.E.; Alpers, Charles N.; Yarnell, S.M.

    2005-01-01

    This study examines the development of a conceptual model of sediment processes in the upper Yuba River watershed; and we hypothesize how components of the conceptual model may be spatially distributed using a geographical information system (GIS). The conceptual model illustrates key processes controlling sediment dynamics in the upper Yuba River watershed and was tested and revised using field measurements, aerial photography, and low elevation videography. Field reconnaissance included mass wasting and channel storage inventories, assessment of annual channel change in upland tributaries, and evaluation of the relative importance of sediment sources and transport processes. Hillslope erosion rates throughout the study area are relatively low when compared to more rapidly eroding landscapes such as the Pacific Northwest and notable hillslope sediment sources include highly erodible andesitic mudflows, serpentinized ultramafics, and unvegetated hydraulic mine pits. Mass wasting dominates surface erosion on the hillslopes; however, erosion of stored channel sediment is the primary contributor to annual sediment yield. We used GIS to spatially distribute the components of the conceptual model and created hillslope erosion potential and channel storage models. The GIS models exemplify the conceptual model in that landscapes with low potential evapotranspiration, sparse vegetation, steep slopes, erodible geology and soils, and high road densities display the greatest hillslope erosion potential and channel storage increases with increasing stream order. In-channel storage in upland tributaries impacted by hydraulic mining is an exception. Reworking of stored hydraulic mining sediment in low-order tributaries continues to elevate upper Yuba River sediment yields. Finally, we propose that spatially distributing the components of a conceptual model in a GIS framework provides a guide for developing more detailed sediment budgets or numerical models making it an

  3. Mass discharge estimation from contaminated sites: Multi-model solutions for assessment of conceptual uncertainty

    Science.gov (United States)

    Thomsen, N. I.; Troldborg, M.; McKnight, U. S.; Binning, P. J.; Bjerg, P. L.

    2012-04-01

    Mass discharge estimates are increasingly being used in the management of contaminated sites. Such estimates have proven useful for supporting decisions related to the prioritization of contaminated sites in a groundwater catchment. Potential management options can be categorised as follows: (1) leave as is, (2) clean up, or (3) further investigation needed. However, mass discharge estimates are often very uncertain, which may hamper the management decisions. If option 1 is incorrectly chosen soil and water quality will decrease, threatening or destroying drinking water resources. The risk of choosing option 2 is to spend money on remediating a site that does not pose a problem. Choosing option 3 will often be safest, but may not be the optimal economic solution. Quantification of the uncertainty in mass discharge estimates can therefore greatly improve the foundation for selecting the appropriate management option. The uncertainty of mass discharge estimates depends greatly on the extent of the site characterization. A good approach for uncertainty estimation will be flexible with respect to the investigation level, and account for both parameter and conceptual model uncertainty. We propose a method for quantifying the uncertainty of dynamic mass discharge estimates from contaminant point sources on the local scale. The method considers both parameter and conceptual uncertainty through a multi-model approach. The multi-model approach evaluates multiple conceptual models for the same site. The different conceptual models consider different source characterizations and hydrogeological descriptions. The idea is to include a set of essentially different conceptual models where each model is believed to be realistic representation of the given site, based on the current level of information. Parameter uncertainty is quantified using Monte Carlo simulations. For each conceptual model we calculate a transient mass discharge estimate with uncertainty bounds resulting from

  4. Unified model for sorption, sequestration and degradation in soils and sediments

    DEFF Research Database (Denmark)

    Trapp, Stefan; Mayer, P. M.; Rein, Arno

    2011-01-01

    The objective of this study is to combine ad/desorption models for organic compounds with the growth and degradation kinetics of microbes in a mathematical simulation model. The goal is to interpret and predict observed effects, such as increasing persistence with time, decreasing degradation rates...... kinetics minus decay (maintenance) rate, degradation is due to bacterial maintenance or growth. The evolving non-linear differential equations are solved numerically. The model is formulated in activity notation and implemented in Matlab. Comparison to the analytical Best equation gave (for suitable...... the project PUB - Prediction of persistence of soil pollutants under various conditions of bioavailability....

  5. Measuring and modeling surface sorption dynamics of organophosphate flame retardants on impervious surfaces

    Data.gov (United States)

    U.S. Environmental Protection Agency — The data presented in this data file is a product of a journal publication. The dataset contains measured and model predicted OPFRs gas-phase and surface-phase...

  6. Conceptual Model of Offshore Wind Environmental Risk Evaluation System

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Richard M.; Copping, Andrea E.; Van Cleve, Frances B.; Unwin, Stephen D.; Hamilton, Erin L.

    2010-06-01

    In this report we describe the development of the Environmental Risk Evaluation System (ERES), a risk-informed analytical process for estimating the environmental risks associated with the construction and operation of offshore wind energy generation projects. The development of ERES for offshore wind is closely allied to a concurrent process undertaken to examine environmental effects of marine and hydrokinetic (MHK) energy generation, although specific risk-relevant attributes will differ between the MHK and offshore wind domains. During FY10, a conceptual design of ERES for offshore wind will be developed. The offshore wind ERES mockup described in this report will provide a preview of the functionality of a fully developed risk evaluation system that will use risk assessment techniques to determine priority stressors on aquatic organisms and environments from specific technology aspects, identify key uncertainties underlying high-risk issues, compile a wide-range of data types in an innovative and flexible data organizing scheme, and inform planning and decision processes with a transparent and technically robust decision-support tool. A fully functional version of ERES for offshore wind will be developed in a subsequent phase of the project.

  7. Conceptual Modeling of Events as Information Objects and Change Agents

    DEFF Research Database (Denmark)

    Bækgaard, Lars

    Traditionally, semantic data models have not supported the modeling of behavior. We present an event modeling approach that can be used to extend semantic data models like the entity-relationship model and the functional data model. We model an event as a two-sided phenomenon that is seen as a to...... it is comparable to an executable transaction schema. Finally, we briefly compare our approach to object-oriented approaches based on encapsulated objects.......Traditionally, semantic data models have not supported the modeling of behavior. We present an event modeling approach that can be used to extend semantic data models like the entity-relationship model and the functional data model. We model an event as a two-sided phenomenon that is seen...... as a totality of an information object and a change agent. When an event is modeled as an information object it is comparable to an entity that exists only at a specific point in time. It has attributes and can be used for querying and specification of constraints. When an event is modeled as a change agent...

  8. Conceptual framework for model-based analysis of residence time distribution in twin-screw granulation

    DEFF Research Database (Denmark)

    Kumar, Ashish; Vercruysse, Jurgen; Vanhoorne, Valerie

    2015-01-01

    within each module where different granulation rate processes dominate over others. Currently, experimental data is used to determine the residence time distributions. In this study, a conceptual model based on classical chemical engineering methods is proposed to better understand and simulate...... the residence time distribution in a TSG. The experimental data were compared with the proposed most suitable conceptual model to estimate the parameters of the model and to analyse and predict the effects of changes in number of kneading discs and their stagger angle, screw speed and powder feed rate...

  9. Modelling of ion sorption on complex solid materials. Synthesis of research activities

    International Nuclear Information System (INIS)

    Marmier, Nicolas

    2000-01-01

    In this HDR (Accreditation to Supervise Researches) report, the author proposes an overview of his research activities which are part of efforts of qualification and quantification of retention capacities of synthetic and artificial materials used to confine nuclear wastes in an underground geological site by absorption of radio-elements possibly passed into solution. More specifically, these research works focused on models aimed at predicting the behaviour of a mixing with respect to adsorption, and thus at avoiding too cumbersome experimental characterizations. The author presents the designed modelling approach and models, describes the implemented scientific approach and the associated data acquisition methodology, and discusses the obtained results. He finally proposed an assessment of these research works, and discusses research perspectives on a short and medium term [fr

  10. A modeling study of vacuum sorption characteristics of carbon dioxide on 4A zeolite molecular sieves

    Energy Technology Data Exchange (ETDEWEB)

    Prazniak, J.K.; Byers, C.H.

    1987-08-01

    A model is presented to describe the isothermal adsorption of carbon dioxide (CO/sub 2/) and of nitrogen (N/sub 2/) on 4A zeolite molecular sieves under cryogenic conditions. The model is comprised of a fluid-phase mass balance representing the dynamics of gas in the bed and a one-dimensional diffusion equation representing adsorption in the solid. Cubic crystals of 4A zeolite are assumed to be spherical, and the concentration dependence of the diffusivity of the sorbate in both the gas and solid phases is considered. Numerical solution of the parabolic partial differential model equations is accomplished using orthogonal collocation in conjunction with an ordinary differential equation integrator suitable for stiff equations. 34 refs., 18 figs., 5 tabs.

  11. Grammatical Conversion of Descriptive Narrative - an application of discourse analysis in conceptual modelling

    Directory of Open Access Journals (Sweden)

    Bruce Calway

    1996-05-01

    Full Text Available Fact-oriented conceptual modelling begins with the search for facts about a universe of discourse (UoD. These facts may be obtained from many sources, including information systems reports, tables, manuals and descriptive narrative both verbal and written. This paper presents some initial findings that support the use of discourse analysis techniques as an approach to developing elementary fact based sentences for information systems conceptual schema development from written text. Although this discussion paper only considers the NIAM (fact-oriented conceptual schema modelling method, the IS087 report from which the research case study is taken describes other conceptual methods for which the research contained in this paper could be applicable (e.g. Entity Relationship analysis. The case study could be modelled exactly in the form in which the text is initially found, but grammatical analysis focuses consideration on alternative, potentially better, expressions of a sentence, a theme which is described and demonstrated. As a result of having applied grammatical sentence simplification with co-ordinate clause splitting, each sentence could be expressed as a complete, finite, independent collection of declarative simple statements. The outcome from the application of the techniques described provides at a minimum a discourse analysis of descriptive narrative which will have retained its meaning and contextual integrity while at the same time providing a simplified and independent clause representation for input to the fact-oriented conceptual schema modelling procedure.

  12. Conceptual design of an integrated technology model for carbon policy assessment.

    Energy Technology Data Exchange (ETDEWEB)

    Backus, George A.; Dimotakes, Paul E. (NASA Jet Propulsion Laboratory, Pasadena, CA)

    2011-01-01

    This report describes the conceptual design of a technology choice model for understanding strategies to reduce carbon intensity in the electricity sector. The report considers the major modeling issues affecting technology policy assessment and defines an implementable model construct. Further, the report delineates the basis causal structure of such a model and attempts to establish the technical/algorithmic viability of pursuing model development along with the associated analyses.

  13. Effect of morphology on water sorption in cellular solid foods. Part I: Pore scale network model

    NARCIS (Netherlands)

    Esveld, D.C.; Sman, van der R.G.M.; Dalen, van G.; Duynhoven, van J.P.M.; Meinders, M.B.J.

    2012-01-01

    A pore scale network model is developed to predict the dynamics of moisture diffusion into complex cellular solid foods like bread, crackers, and cereals. The morphological characteristics of the sample, including the characteristics of each cellular void and the open pore connections between them

  14. Surface complexation modeling of Cd(II) sorption to montmorillonite, bacteria, and their composite

    Science.gov (United States)

    Wang, Ning; Du, Huihui; Huang, Qiaoyun; Cai, Peng; Rong, Xingmin; Feng, Xionghan; Chen, Wenli

    2016-10-01

    Surface complexation modeling (SCM) has emerged as a powerful tool for simulating heavy metal adsorption processes on the surface of soil solid components under different geochemical conditions. The component additivity (CA) approach is one of the strategies that have been widely used in multicomponent systems. In this study, potentiometric titration, isothermal adsorption, zeta potential measurement, and extended X-ray absorption fine-structure (EXAFS) spectra analysis were conducted to investigate Cd adsorption on 2 : 1 clay mineral montmorillonite, on Gram-positive bacteria Bacillus subtilis, and their mineral-organic composite. We developed constant capacitance models of Cd adsorption on montmorillonite, bacterial cells, and mineral-organic composite. The adsorption behavior of Cd on the surface of the composite was well explained by CA-SCM. Some deviations were observed from the model simulations at pH SCM closely coincided with the estimated value of EXAFS at pH 6. The model could be useful for the prediction of heavy metal distribution at the interface of multicomponents and their risk evaluation in soils and associated environments.

  15. Effect of model dissolved organic matter coating on sorption of phenanthrene by TiO2 nanoparticles.

    Science.gov (United States)

    Wang, Xilong; Ma, Enxing; Shen, Xiaofang; Guo, Xiaoying; Zhang, Meng; Zhang, Haiyun; Liu, Ye; Cai, Fei; Tao, Shu; Xing, Baoshan

    2014-11-01

    Dissolved organic matter (DOM) may alter the sorption of hydrophobic organic contaminants (HOC) to metal oxide nanoparticles (NPs), but the role of DOM and NP types is poorly understood. Here, phenanthrene sorption was quantified on four types of nano-TiO2 (three rutile, one anatase), and a bulk, raw TiO2 powder. Prior to the sorption experiments, these nanoparticles were coated using four different organic materials: Lignin (LIG), tannic acid (TAN), Congo red (CON), and capsorubin (CAP). Lignin, tannic acid, congo red and capsorubin coating substantially enhanced phenanthrene sorption to various TiO2 particles. After coating with a specific DOM, Kd values by the DOM-coated TiO2 particles on percent organic carbon content and surface area (SA) basis (Koc/SA) generally followed the order: TiO2 NPs with hydrophobic surfaces > bulk TiO2 particles > other TiO2 NPs. Different Koc/SA values of various DOM-TiO2 complexes resulted from distinct conformation of the coated DOM and aggregation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  16. A model for information retrieval driven by conceptual spaces

    OpenAIRE

    Tanase, D.

    2015-01-01

    A retrieval model describes the transformation of a query into a set of documents. The question is: what drives this transformation? For semantic information retrieval type of models this transformation is driven by the content and structure of the semantic models. In this case, Knowledge Organization Systems (KOSs) are the semantic models that encode the meaning employed for monolingual and cross-language retrieval. The focus of this research is the relationship between these meanings’ repre...

  17. Public–private partnership conceptual framework and models for the ...

    African Journals Online (AJOL)

    The framework for PPPs identified three models, viz. state, hybrid and private sector models. In the 'state model' the water services value chain is 100% government funded and owned infrastructure. Government is a key player in infrastructure investment and inefficiencies within the public expenditure management systems ...

  18. Conceptual Model of Iodine Behavior in the Subsurface at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Truex, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lee, Brady D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Johnson, Christian D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qafoku, Nikolla P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Last, George V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lee, Michelle H. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kaplan, Daniel I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-09-01

    The fate and transport of 129I in the environment and potential remediation technologies are currently being studied as part of environmental remediation activities at the Hanford Site. A conceptual model describing the nature and extent of subsurface contamination, factors that control plume behavior, and factors relevant to potential remediation processes is needed to support environmental remedy decisions. Because 129I is an uncommon contaminant, relevant remediation experience and scientific literature are limited. Thus, the conceptual model also needs to both describe known contaminant and biogeochemical process information and to identify aspects about which additional information needed to effectively support remedy decisions. this document summarizes the conceptual model of iodine behavior relevant to iodine in the subsurface environment at the Hanford site.

  19. University Library Strategy Development: A Conceptual Model of Researcher Performance to Inform Service Delivery

    Science.gov (United States)

    Maddox, Alexia; Zhao, Linlin

    2017-01-01

    This case study presents a conceptual model of researcher performance developed by Deakin University Library, Australia. The model aims to organize research performance data into meaningful researcher profiles, referred to as researcher typologies, which support the demonstration of research impact and value. Three dimensions shaping researcher…

  20. The Role of Model Building in Problem Solving and Conceptual Change

    Science.gov (United States)

    Lee, Chwee Beng; Jonassen, David; Teo, Timothy

    2011-01-01

    This study examines the effects of the activity of building systems models for school-based problems on problem solving and on conceptual change in elementary science classes. During a unit on the water cycle in an Asian elementary school, students constructed systems models of the water cycle. We found that representing ill-structured problems as…

  1. Examining the Etiology of Reading Disability as Conceptualized by the Hybrid Model

    Science.gov (United States)

    Erbeli, Florina; Hart, Sara A.; Wagner, Richard K.; Taylor, Jeanette

    2018-01-01

    A fairly recent definition of reading disability (RD) is that in the form of a hybrid model. The model views RD as a latent construct that is manifested through various observable unexpected impairments in reading-related skills and through inadequate response to intervention. The current report evaluated this new conceptualization of RD from an…

  2. Experimental and modeling analysis of coupled non-Fickian transport and sorption in natural soils.

    Science.gov (United States)

    Rubin, Shira; Dror, Ishai; Berkowitz, Brian

    2012-05-01

    We present experimental breakthrough curve (BTC) data and a modeling investigation of conservative and sorbing tracer transport in natural soils. By analyzing the data using the continuous time random walk (CTRW) model, we probe the traditional approach of using conservative tracer model parameters as a basis for quantifying the transport of sorbing solutes in the same domain when non-Fickian transport is present. Many known contaminants in groundwater are sorbed to the host solid porous medium, to varying extents, while being transported; this enhances the long tailing of BTCs which often already occurs because of the inherent non-Fickian nature of the transport. The CTRW framework has been shown to account very well for non-Fickian conservative (nonsorbing) transport. Here, we examine two BTC data sets in laboratory columns packed with natural soils; the first (previously analyzed by Mao and Ren (2004)) comprises transport of (conservative) bromide and (sorbing) atrazine tracers, while the second presents new data with bromide and tribromoneopentyl alcohol (TBNPA), a key flame retardant, as a sorbing solute. TBNPA has received little attention in the past, and is shown to be sorbed onto Bet Dagan soil in a nonlinear manner. We find that the transport behavior of bromide is non-Fickian in all cases, which is caused by the heterogeneity of the soil. Comparative model analysis of the non-Fickian BTCs of the conservative, and sorbing tracers and examination of the fitting parameters, exemplify the coupling between transport and adsorption/desorption processes. The difference in transport parameters used to match the conservative and sorbing data sets shows that conservative tracer parameters (average velocity and dispersion coefficient) are not valid for the transport of reactive tracers. Copyright © 2012 Elsevier B.V. All rights reserved.

  3. Study of cesium sorption in Brazilian clays for their utilization as engineering barrier in repository

    International Nuclear Information System (INIS)

    Freire, Carolina B.; Tello, Cledola Cassia O. de

    2013-01-01

    The radioactive wastes require suitable and safe management from beginning of their generation until the storage in repository. The backfill layer is considered one of the most important components of the engineering barrier of the repository. As CNEN is presently implementing a repository for low and intermediate level wastes, named RBMN project, the results obtained with this research may be applied in the future, during the phases of elaboration of the repository conceptual design. Therefore, is important to know the properties of different materials that can be used as backfill layer. The objective of this research was to characterize some Brazilian clays in order to evaluate the viability of their use in the backfill layer, one of the radioactive waste repository barriers. The main function of this barrier is to contribute in the delay of the radionuclides movement, and to prevent their release into the environment. Four clays provided by national suppliers were selected for the research: Ca-Bentonite, Na-Bentonite, Kaolinite and Vermiculite. Their physical, chemical and mineralogical characteristics were determined, and also their sorption potential of Cesium cation. In accordance to Freundlich and Langmuir models the Vermiculite was the best sorbers of cesium. The clays presented the n value of the Freundlich model different of 1, that mean heterogenic sorption or that the clays present sorption regions of different energy. From the results was possible to conclude that the Vermiculite clay contain regions of sorption higher energy. (author)

  4. Unified model for sorption, sequestration and degradation in soils and sediments

    DEFF Research Database (Denmark)

    Trapp, Stefan; Mayer, Philipp; Rein, Arno

    kinetics minus decay (maintenance) rate, degradation is due to bacterial maintenance or growth. The evolving non-linear differential equations are solved numerically. The model is formulated in activity notation and implemented in Matlab. Comparison to the analytical Best equation gave (for suitable...... and degradation processes simultaneously and coupled together. By this, we hope to get a better understanding of aging and persistence in soil and of the formation of bound residues (better: non-extractable residues), but the goal is also the optimization of amendments, such as DOC, compost or charcoal...

  5. Conceptual Processes for Linking Eutrophication and Network Models

    Science.gov (United States)

    2006-08-01

    1 PURPOSE: This three-year study investigates the coupling of eutrophication and network models, applies the results to a specific problem , and...affect water quality problems such as low dissolved oxygen? No straightforward means of coupling the two modeling approaches is available or...Dorothy H. Tillman, Dr. Carl F. Cerco, and Mr. Mark R. Noel of the Water Quality and Contaminant Modeling Branch, Enviromental Laboratory (EL

  6. Water-Chemistry Evolution and Modeling of Radionuclide Sorption and Cation Exchange during Inundation of Frenchman Flat Playa

    Energy Technology Data Exchange (ETDEWEB)

    Hershey, Ronald; Cablk, Mary; LeFebre, Karen; Fenstermaker, Lynn; Decker, David

    2013-08-01

    dioxide and calcite; dissolution of sodium chloride, gypsum, and composite volcanic glass; and precipitation of composite clay and quartz represented changes in water as it disappeared from the playa. This modeling provided an understanding of the water-soil geochemical environment, which was then used to evaluate the potential mobility of residual radionuclides into the playa soils by water. Because there is no information on the chemical forms of anthropogenic radionuclides in Frenchman Flat playa soil, it was assumed that soil radionuclides go into solution when the playa is inundated. In mobility modeling, a select group of radionuclides were allowed to sorb onto, or exchange with, playa soil minerals to evaluate the likelihood that the radionuclides would be removed from water during playa inundation. Radionuclide mobility modeling suggested that there would be minimal sorption or exchange of several important radionuclides (uranium, cesium, and technetium) with playa minerals such that they may be mobile in water when the playa is inundated and could infiltrate into the subsurface. Mobility modeling also showed that plutonium may be much less mobile because of sorption onto calcite, but the amount of reactive surface area of playa soil calcite is highly uncertain. Plutonium is also known to sorb onto colloidal particles suspended in water, suspended colloidal particles will move with the water, providing a mechanism to redistribute plutonium when Frenchman Flat playa is inundated. Water chemistry, stable isotopes, and geochemical modeling showed that residual radionuclides in Frenchman Flat playa soils could be mobilized in water when the playa is inundated with precipitation. Also, there is potential for these radionuclides to infiltrate into the subsurface with water. As a result of the information obtained both during this study and the conclusions drawn from it, additional data collection, investigation, and modeling are recommended. Specifically: sampling the

  7. Modeling sorption phenomena and moisture migration rates in paprika (Capsicum annuumL.) using physicochemical characteristics.

    Science.gov (United States)

    Shirkole, S S; Sutar, P P

    2018-02-01

    In the present study, the GAB and moisture migration rate models were used to predict the shelf life of paprika under domestic (40 °C and 90% RH) and industrial (5, 10, 15 and 20 °C with 70% RH) storage conditions. The correlations between physicochemical characteristics and moisture content of paprika were developed to estimate the stability of the paprika. The estimated shelf life of low moisture paprika (4.40% dry basis) was found to be 101 and 31 days in HDPE and LDPE packages, respectively when stored in domestic condition. In industrial storage condition, the shelf life prediction was 5.47 years in HDPE and 1.68 years in LDPE packages. The first order kinetic models of extractable color (ASTA) and degree of caking described the quality degradation of paprika during storage. The relative humidity and temperature of the storage environment were significant parameters affecting the stability of paprika. The shelf life of paprika can be extended by storage at or below monolayer moisture content and low temperature.

  8. PHOSPHORUS SORPTION ISOTHERMS AND EXTERNAL ...

    African Journals Online (AJOL)

    ACSS

    both models fitted well with the P sorption data of the soils. The adsorption maxima (Xm) and bonding energy (b) values of the soils derived from Langmuir model were in the ranges of 560-833 mg P kg-1 and 0.16-20 L kg-1, respectively. The Freundlich capacity factor (Kf) ranged from 237 to 1200 mg kg-1.The EPRs of the ...

  9. Isotherm, kinetic, and thermodynamic study of ciprofloxacin sorption on sediments.

    Science.gov (United States)

    Mutavdžić Pavlović, Dragana; Ćurković, Lidija; Grčić, Ivana; Šimić, Iva; Župan, Josip

    2017-04-01

    In this study, equilibrium isotherms, kinetics and thermodynamics of ciprofloxacin on seven sediments in a batch sorption process were examined. The effects of contact time, initial ciprofloxacin concentration, temperature and ionic strength on the sorption process were studied. The K d parameter from linear sorption model was determined by linear regression analysis, while the Freundlich and Dubinin-Radushkevich (D-R) sorption models were applied to describe the equilibrium isotherms by linear and nonlinear methods. The estimated K d values varied from 171 to 37,347 mL/g. The obtained values of E (free energy estimated from D-R isotherm model) were between 3.51 and 8.64 kJ/mol, which indicated a physical nature of ciprofloxacin sorption on studied sediments. According to obtained n values as measure of intensity of sorption estimate from Freundlich isotherm model (from 0.69 to 1.442), ciprofloxacin sorption on sediments can be categorized from poor to moderately difficult sorption characteristics. Kinetics data were best fitted by the pseudo-second-order model (R 2  > 0.999). Thermodynamic parameters including the Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) were calculated to estimate the nature of ciprofloxacin sorption. Results suggested that sorption on sediments was a spontaneous exothermic process.

  10. An independent verification and validation of the Future Theater Level Model conceptual model

    Energy Technology Data Exchange (ETDEWEB)

    Hartley, D.S. III; Kruse, K.L.; Martellaro, A.J.; Packard, S.L.; Thomas, B. Jr.; Turley, V.K.

    1994-08-01

    This report describes the methodology and results of independent verification and validation performed on a combat model in its design stage. The combat model is the Future Theater Level Model (FTLM), under development by The Joint Staff/J-8. J-8 has undertaken its development to provide an analysis tool that addresses the uncertainties of combat more directly than previous models and yields more rapid study results. The methodology adopted for this verification and validation consisted of document analyses. Included were detailed examination of the FTLM design documents (at all stages of development), the FTLM Mission Needs Statement, and selected documentation for other theater level combat models. These documents were compared to assess the FTLM as to its design stage, its purpose as an analytical combat model, and its capabilities as specified in the Mission Needs Statement. The conceptual design passed those tests. The recommendations included specific modifications as well as a recommendation for continued development. The methodology is significant because independent verification and validation have not been previously reported as being performed on a combat model in its design stage. The results are significant because The Joint Staff/J-8 will be using the recommendations from this study in determining whether to proceed with develop of the model.

  11. Public–private partnership conceptual framework and models for the ...

    African Journals Online (AJOL)

    (2012c) Project to Revise the Pricing Strategy for Water Use. Charges and Develop a Funding Model for Water Infrastructure. Development and Use and a Model for the Establishment of an. Economic Regulator (Contract No. WP10465). Review of Principles and Experience for Infrastructure Finance. Department of Water.

  12. A conceptual model for the development and management of the ...

    African Journals Online (AJOL)

    2009-07-13

    Jul 13, 2009 ... A hydrogeological model was developed to elucidate ground- water flow mechanisms and possibilities of recharge in the. Cape Flats. The model is based on local climate, hydrology, geomorphology, geology and chemical and isotope geochem- istry (Fig. 16). The groundwater from the Cape Flats aquifer.

  13. A Framework for Conceptual Modeling of Geographic Data Quality

    DEFF Research Database (Denmark)

    Friis-Christensen, Anders; Christensen, J.V.; Jensen, Christian Søndergaard

    2004-01-01

    Sustained advances in wireless communications, geo-positioning, and consumer electronics pave the way to a kind of location-based service that relies on the tracking of the continuously changing positions of an entire population of service users. This type of service is characterized by large...... of geographic data and quality. The approach integrates quality information with the basic model constructs. This results in a model that enables object-oriented specification of quality requirements and of acceptable quality levels. More specifically, it extends the Unified Modeling Language with new modeling...... constructs based on standard classes, attributes, and associations that include quality information. A case study illustrates the utility of the quality-enabled model. reported....

  14. Modeling of sorption processes on solid-phase ion-exchangers

    Science.gov (United States)

    Dorofeeva, Ludmila; Kuan, Nguyen Anh

    2018-03-01

    Research of alkaline elements separation on solid-phase ion-exchangers is carried out to define the selectivity coefficients and height of an equivalent theoretical stage for both continuous and stepwise filling of column by ionite. On inorganic selective sorbents the increase in isotope enrichment factor up to 0.0127 is received. Also, parametrical models that are adequately describing dependence of the pressure difference and the magnitude expansion in the ion-exchange layer from the flow rate and temperature have been obtained. The concentration rate value under the optimum realization conditions of process and depending on type of a selective material changes in a range 1.021÷1.092. Calculated results show agreement with experimental data.

  15. Sensitivity of hydrological performance assessment analysis to variations in material properties, conceptual models, and ventilation models

    Energy Technology Data Exchange (ETDEWEB)

    Sobolik, S.R.; Ho, C.K.; Dunn, E. [Sandia National Labs., Albuquerque, NM (United States); Robey, T.H. [Spectra Research Inst., Albuquerque, NM (United States); Cruz, W.T. [Univ. del Turabo, Gurabo (Puerto Rico)

    1996-07-01

    The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level nuclear waste repository. Site characterization includes surface- based and underground testing. Analyses have been performed to support the design of an Exploratory Studies Facility (ESF) and the design of the tests performed as part of the characterization process, in order to ascertain that they have minimal impact on the natural ability of the site to isolate waste. The information in this report pertains to sensitivity studies evaluating previous hydrological performance assessment analyses to variation in the material properties, conceptual models, and ventilation models, and the implications of this sensitivity on previous recommendations supporting ESF design. This document contains information that has been used in preparing recommendations for Appendix I of the Exploratory Studies Facility Design Requirements document.

  16. Sensitivity of hydrological performance assessment analysis to variations in material properties, conceptual models, and ventilation models

    International Nuclear Information System (INIS)

    Sobolik, S.R.; Ho, C.K.; Dunn, E.; Robey, T.H.; Cruz, W.T.

    1996-07-01

    The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level nuclear waste repository. Site characterization includes surface- based and underground testing. Analyses have been performed to support the design of an Exploratory Studies Facility (ESF) and the design of the tests performed as part of the characterization process, in order to ascertain that they have minimal impact on the natural ability of the site to isolate waste. The information in this report pertains to sensitivity studies evaluating previous hydrological performance assessment analyses to variation in the material properties, conceptual models, and ventilation models, and the implications of this sensitivity on previous recommendations supporting ESF design. This document contains information that has been used in preparing recommendations for Appendix I of the Exploratory Studies Facility Design Requirements document

  17. Conceptual Development af a 3D Product Configuration Model

    DEFF Research Database (Denmark)

    Skauge, Jørn

    2006-01-01

    Paper. This project deals with 3D product configuration of a digital building element which has been developed as a prototype in cooperation between a product manufacturer and a research institution in Denmark. The project falls within the concept of product modelling which is more and more used ......’s production of steel fire sliding doors. The development of the 3D digital model is based on practical rather than theoretical research. The result of the research is a prototype digital 3D model to be presented live....

  18. A Proposed Conceptual Model of Military Medical Readiness

    National Research Council Canada - National Science Library

    Van Hall, Brian M

    2007-01-01

    .... The purpose of this research is to consolidate existing literature on the latent variable of medical readiness, and to propose a composite theoretical model of medical readiness that may provide...

  19. Sorption of metaldehyde using granular activated carbon

    Directory of Open Access Journals (Sweden)

    S. Salvestrini

    2017-09-01

    Full Text Available In this work, the ability of granular activated carbon (GAC to sorb metaldehyde was evaluated. The kinetic data could be described by an intra-particle diffusion model, which indicated that the porosity of the sorbent strongly influenced the rate of sorption. The analysis of the equilibrium sorption data revealed that ionic strength and temperature did not play any significant role in the metaldehyde uptake. The sorption isotherms were successfully predicted by the Freundlich model. The GAC used in this paper exhibited a higher affinity and sorption capacity for metaldehyde with respect to other GACs studied in previous works, probably as a result of its higher specific surface area and high point of zero charge.

  20. Environmental Conditions Influencing Sorption of Inorganic Anions to Multiwalled Carbon Nanotubes Studied by Column Chromatography.

    Science.gov (United States)

    Metzelder, Florian; Schmidt, Torsten C

    2017-05-02

    Sorption to carbon-based nanomaterials is typically studied in batch experiments. An alternative method offering advantages to study sorption is column chromatography. Sorbent packed columns are used and sorption data are determined by relating sorbate retention to that of a nonretarded tracer. We have now for the first time applied this technique to study the influence of environmental conditions on sorption of inorganic anions (bromide, nitrite, nitrate, and iodide) to multiwalled carbon nanotubes. Deuterium oxide was used as nonretarded tracer. Sorption isotherms were best described by the Freundlich model. Sorption increased in the order bromide 4.5 the surface charge was negative, but sorption was still detectable at pH 6 and 9. Consequently, other forces than electrostatic attraction contributed to sorption. These forces may include H-bonding as indicated by sorption enthalpy determined by variation of column temperature. Overall, column chromatography represents a promising alternative in sorption studies to reveal sorbent properties.

  1. A study on modeling customer preferences for conceptual design

    International Nuclear Information System (INIS)

    Han, Soon Young; Seo, Seok Hoon; Choi, Hae Jin

    2015-01-01

    In this paper, we propose a concept selection method to evaluate future market performances of concept candidates, and to choose the best concept among those. The main and interaction effects of product performance factors, economic factors, and time on a market performance are modeled using a Bayesian framework-based Artificial neural network (ANN). The Bayesian framework is employed to measure the potential risk of wrong selection in using a trained ANN model. Based on the measured uncertainty bounds in the predicted future market performance, the most promising and robust concept may be selected. To validate our concept-selection method, we employed an automobile concept selection problem in the U.S. market. Seventeen concepts were assumed to compete in 2013, and the future market share with error bounds was predicted using the trained model based on sale data

  2. A CONCEPTUAL MULTIDIMENSIONAL MODEL FOR ASSESSING SMART SUSTAINABLE CITIES

    Directory of Open Access Journals (Sweden)

    Sukaina Al-Nasrawi

    2015-12-01

    Full Text Available The concept of Smart Sustainable Cities (SSC is gaining increasing attention by the countries around the globe, particularly in response to potential future environmental challenges and increased proportion of populations living in cities. Several countries claim to have implemented or in the process of implementing SSCs, and there are many models that can be used to measure how 'smart' the initiatives and cities are. This paper critically evaluates the main models to measure city smartness and identifies deficiencies, namely that they are not sensitive to the needs, resources, priorities and wider context for individual cities. The paper suggests a multidimensional methodological model that assists in evaluating the smartness level of a city while being sensitive to its context. It provides further contribution by combining sustainable and smart attributes of a city

  3. A New Model to Facilitate Individualized Case Conceptualization and Treatment of Social Phobia: An Examination and Reaction to Moscovitch's Model

    Science.gov (United States)

    Heimberg, Richard G.

    2009-01-01

    Moscovitch's (2009) model of social phobia is put forth as an integration and extension of previous cognitive-behavioral models. The author asserts that his approach overcomes a number of shortcomings of previous models and will serve to better guide case conceptualization, treatment planning, and intervention implementation for clients with…

  4. Hydrogeologic setting and conceptual hydrologic model of the Spring Creek basin, Centre County, Pennsylvania

    Science.gov (United States)

    Fulton, John W.; Koerkle, Edward H.; McAuley, Steven D.; Hoffman, Scott A.; Zarr, Linda F.

    2005-01-01

    The Spring Creek Basin, Centre County, Pa., is experiencing some of the most rapid growth and development within the Commonwealth. This trend has resulted in land-use changes and increased water use, which will affect the quantity and quality of stormwater runoff, surface water, ground water, and aquatic resources within the basin. The U.S. Geological Survey (USGS), in cooperation with the ClearWater Conservancy (CWC), Spring Creek Watershed Community (SCWC), and Spring Creek Watershed Commission (SCWCm), has developed a Watershed Plan (Plan) to assist decision makers in water-resources planning. One element of the Plan is to provide a summary of the basin characteristics and a conceptual model that incorporates the hydrogeologic characteristics of the basin. The report presents hydrogeologic data for the basin and presents a conceptual model that can be used as the basis for simulating surface-water and ground-water flow within the basin. Basin characteristics; sources of data referenced in this text; physical characteristics such as climate, physiography, topography, and land use; hydrogeologic characteristics; and water-quality characteristics are discussed. A conceptual model is a simplified description of the physical components and interaction of the surface- and ground-water systems. The purpose for constructing a conceptual model is to simplify the problem and to organize the available data so that the system can be analyzed accurately. Simplification is necessary, because a complete accounting of a system, such as Spring Creek, is not possible. The data and the conceptual model could be used in development of a fully coupled numerical model that dynamically links surface water, ground water, and land-use changes. The model could be used by decision makers to manage water resources within the basin and as a prototype that is transferable to other watersheds.

  5. Structure of conceptual models in the senior operating staff of nuclear power plants

    Directory of Open Access Journals (Sweden)

    Oboznov A. A.

    2017-09-01

    Full Text Available Background. The relationships between conceptual model structures and an operator’s professional efficiency are of direct practical importance, particularly in the case of large-scale industrial complexes combining several human-machine systems. A typical example is the power unit of a nuclear power plant (NPP. Objective and methods. The purpose of this study was to explore the conceptual models of senior reactor operators (SROs of NPPs. The study involved 64 men working as SRO at five NPPs in Russia. The methods included: structured interviews, expert estimations, multidimensional scaling (ALSCAL, the K-means clustering algorithm, and frequency analysis. The procedure was as follows: 32 key characteristics of the power unit were defined, including shift operators’ jobs and duties, technical subsystems, types of equipment, and the crucial power unit parameters. The participants were offered a 32×32 matrix for pair-wise estimation of the strength of the links between these key characteristics on a seven-point scale (496 links in total. Results. A general scheme of key characteristics in the conceptual models was defined. is scheme was displayed in the operators regardless of their employment history. Within the scheme, however, two types of conceptual models were identified, which could be distinguished by the relative number of strong links between the key characteristics. With respect to intersystem links including key characteristics of the reactor and turbine NPP departments, this number was significantly higher in models of Type 1 than in those of Type 2. A positive correlation between the number of these links and the professional efficiency indicators was also established. Operators with Type 1 models were able to more predictably represent the power unit operation. Conclusion. The main role in creating predictable and efficient conceptual models was played by strong intersystem links in mental representations of workflow.

  6. A Conceptual Trust Model for Managing E-Commerce Environment ...

    African Journals Online (AJOL)

    E-commerce helps businesses to increase production flexibility by ensuring timely availability of components from suppliers. However, of paramount concern is the issue of trust. Some trust models such as Pretty Good Privacy (PGP) and Public Key Infrastructure based on X.509 (PKIX) are based on the notion of delegation ...

  7. Animation Model to Conceptualize ATP Generation: A Mitochondrial Oxidative Phosphorylation

    Science.gov (United States)

    Jena, Ananta Kumar

    2015-01-01

    Adenosine triphosphate (ATP) is the molecular unit of intracellular energy and it is the product of oxidative phosphorylation of cellular respiration uses in cellular processes. The study explores the growth of the misconception levels amongst the learners and evaluates the effectiveness of animation model over traditional methods. The data…

  8. Resilience in adults with cancer: development of a conceptual model.

    Science.gov (United States)

    Deshields, Teresa L; Heiland, Mark F; Kracen, Amanda C; Dua, Priya

    2016-01-01

    Resilience is a construct addressed in the psycho-oncology literature and is especially relevant to cancer survivorship. The purpose of this paper is to propose a model for resilience that is specific to adults diagnosed with cancer. To establish the proposed model, a brief review of the various definitions of resilience and of the resilience literature in oncology is provided. The proposed model includes baseline attributes (personal and environmental) which impact how an individual responds to an adverse event, which in this paper is cancer-related. The survivor has an initial response that fits somewhere on the distress-resilience continuum; however, post-cancer experiences (and interventions) can modify the initial response through a process of recalibration. The literature reviewed indicates that resilience is a common response to cancer diagnosis or treatment. The proposed model supports the view of resilience as both an outcome and a dynamic process. Given the process of recalibration, a discussion is provided of interventions that might facilitate resilience in adults with cancer. Copyright © 2015 John Wiley & Sons, Ltd.

  9. A New Conceptual Model for the Continuum of Land Rights

    African Journals Online (AJOL)

    Akrofi

    In order to inform the development of a new model, a systems understanding is used to identify five primary elements of land ... normative responses to communal and customary land administration systems are consistent with modernization theory in that they are ...... year, fractional shares. Occupation, use. Individuals have.

  10. Integrating O/S models during conceptual design, part 3

    Science.gov (United States)

    Ebeling, Charles E.

    1994-12-01

    Space vehicles, such as the Space Shuttle, require intensive ground support prior to, during, and after each mission. Maintenance is a significant part of that ground support. All space vehicles require scheduled maintenance to ensure operability and performance. In addition, components of any vehicle are not one-hundred percent reliable so they exhibit random failures. Once detected, a failure initiates unscheduled maintenance on the vehicle. Maintenance decreases the number of missions which can be completed by keeping vehicles out of service so that the time between the completion of one mission and the start of the next is increased. Maintenance also requires resources such as people, facilities, tooling, and spare parts. Assessing the mission capability and resource requirements of any new space vehicle, in addition to performance specification, is necessary to predict the life cycle cost and success of the vehicle. Maintenance and logistics support has been modeled by computer simulation to estimate mission capability and resource requirements for evaluation of proposed space vehicles. The simulation was written with Simulation Language for Alternative Modeling II (SLAM II) for execution on a personal computer. For either one or a fleet of space vehicles, the model simulates the preflight maintenance checks, the mission and return to earth, and the post flight maintenance in preparation to be sent back into space. THe model enables prediction of the number of missions possible and vehicle turn-time (the time between completion of one mission and the start of the next) given estimated values for component reliability and maintainability. The model also facilitates study of the manpower and vehicle requirements for the proposed vehicle to meet its desired mission rate. This is the 3rd part of a 3 part technical report.

  11. Acid-base surface chemistry and sorption of some lanthanides on K +-saturated Marblehead illite: II. a multisite-surface complexation modeling

    Science.gov (United States)

    Kulik, Dmitrii A.; Aja, Stephen U.; Sinitsyn, Vasilii A.; Wood, Scott A.

    2000-01-01

    The surface reactivity and sorption of Nd and Eu onto K +-saturated Marblehead illite at 25°C, measured in aqueous 0.01, 0.1, and 1.0 M KCl solutions, were interpreted with a multi-site-surface complexation model. Model potentiometric titration and sorption curves (computed using the Gibbs free energy minimization code, Selektor-A) resolve into reactions on variable-charge amphoteric sites on edge surfaces and on permanent-charge siloxane surfaces (φ x). Standard partial molal Gibbs free energy of formation from elements (g 2980) for surface complexes were derived from oxide (SiO 2,am and γ-Al 2O 3) surface deprotonation KA10, KA20 and electrolyte adsorption constants KCl0, KNa0. Because surface complexation reactions on siloxane basal surfaces are negligible in 1 M KCl, models of surface charge and adsorption edges of Nd and Eu presumed that C 1 is equal to 1.6 Fm -2 for amphoteric site types, and a maximum site density of 1.2 ± 0.2 sites nm -2 for the outer-sphere species, (Al>OH 2+Cl -). To obtain values of g 2980 for exchangeable cations and charged X ˜REE complexes, ion exchange sites were assumed to be fully deprotonated in 1.0 M KCl solutions (pH > 2.7). Proton release and REE 3+ uptake on ion exchange sites were then simulated (pH 4.0) from initial values of 20 to 48%. The application of Gibbs free energy minimization to sorption processes is innovative in that simultaneous treatment of surface complexation reactions and minerals stability is feasible in any system without introducing mass-balance constraints particular to surface species.

  12. The ISO Edi Conceptual Model Activity and Its Relationship to OSI.

    Science.gov (United States)

    Fincher, Judith A.

    1990-01-01

    The edi conceptual model is being developed to define common structures, services, and processes that syntax-specific standards like X12 and EDIFACT could adopt. Open Systems Interconnection (OSI) is of interest to edi because of its potential to help enable global interoperability across Electronic Data Interchange (EDI) functional groups. A…

  13. College Men's Meanings of Masculinities and Contextual Influences: Toward a Conceptual Model

    Science.gov (United States)

    Harris, Frank, III

    2010-01-01

    Based on a grounded theory study involving 68 male undergraduates, a conceptual model of the meanings college men ascribe to masculinities is proposed in this article. The participants equated masculinities with "being respected," "being confident and self-assured," "assuming responsibility," and "embodying physical prowess." Contextual factors…

  14. Towards an Integrated Conceptual Model of International Student Adjustment and Adaptation

    Science.gov (United States)

    Schartner, Alina; Young, Tony Johnstone

    2016-01-01

    Despite a burgeoning body of empirical research on "the international student experience", the area remains under-theorized. The literature to date lacks a guiding conceptual model that captures the adjustment and adaptation trajectories of this unique, growing, and important sojourner group. In this paper, we therefore put forward a…

  15. An Update on the Conceptual-Production Systems Model of Apraxia: Evidence from Stroke

    Science.gov (United States)

    Stamenova, Vessela; Black, Sandra E.; Roy, Eric A.

    2012-01-01

    Limb apraxia is a neurological disorder characterized by an inability to pantomime and/or imitate gestures. It is more commonly observed after left hemisphere damage (LHD), but has also been reported after right hemisphere damage (RHD). The Conceptual-Production Systems model (Roy, 1996) suggests that three systems are involved in the control of…

  16. On the foundation for roles in RM-ODP: contributions from conceptual modelling

    NARCIS (Netherlands)

    Guizzardi, G.; Andrade Almeida, João; Linington, P.F.; Vallecillo, A.; Wood, B.

    2007-01-01

    In this paper, we attempt to provide a semantic foundation for the role-related concepts in the RM-ODP. We believe that some theories of conceptual modelling may help us to provide a well-founded underpinning for these concepts, and to harmonize competing proposals for them. As a starting point of

  17. Landscape evolution and agricultural land salinization in coastal area: A conceptual model.

    Science.gov (United States)

    Bless, Aplena Elen; Colin, François; Crabit, Armand; Devaux, Nicolas; Philippon, Olivier; Follain, Stéphane

    2018-06-01

    Soil salinization is a major threat to agricultural lands. Among salt-affected lands, coastal areas could be considered as highly complex systems, where salinization degradation due to anthropogenic pressure and climate-induced changes could significantly alter system functioning. For such complex systems, conceptual models can be used as evaluation tools in a preliminary step to identify the main evolutionary processes responsible for soil and water salinization. This study aimed to propose a conceptual model for water fluxes in a coastal area affected by salinity, which can help to identify the relationships between agricultural landscape evolution and actual salinity. First, we conducted field investigations from 2012 to 2016, mainly based on both soil (EC 1/5 ) and water (EC w ) electrical conductivity survey. This allowed us to characterize spatial structures for EC 1/5 and EC w and to identify the river as a preponderant factor in land salinization. Subsequently, we proposed and used a conceptual model for water fluxes and conducted a time analysis (1962-2012) for three of its main constitutive elements, namely climate, river, and land systems. When integrated within the conceptual model framework, it appeared that the evolution of all constitutive elements since 1962 was responsible for the disruption of system equilibrium, favoring overall salt accumulation in the soil root zone. Copyright © 2017 Elsevier B.V. All rights reserved.

  18. A Conceptual Model and Process for Client-driven Agile Requirements Prioritization

    NARCIS (Netherlands)

    Racheva, Z.; Daneva, Maia; Herrmann, Andrea; Wieringa, Roelf J.

    Continuous customer-centric requirements reprioritization is essential in successfully performing agile software development. Yet, in the agile RE literature, very little is known about how agile reprioritization happens in practice. Generic conceptual models about this process are missing, which in

  19. The Interactions between Problem Solving and Conceptual Change: System Dynamic Modelling as a Platform for Learning

    Science.gov (United States)

    Lee, Chwee Beng

    2010-01-01

    This study examines the interactions between problem solving and conceptual change in an elementary science class where students build system dynamic models as a form of problem representations. Through mostly qualitative findings, we illustrate the interplay of three emerging intervening conditions (epistemological belief, structural knowledge…

  20. Exploring Conceptual Models for Community Engagement at Higher Education Institutions in South Africa

    Science.gov (United States)

    Bender, Gerda

    2008-01-01

    A critical conceptual analysis of the South African Higher Education context reflects the lack of a structural and functional framework for the conceptualisation of community engagement (CE) in higher education. The purpose of this article is to explore a framework and model for the conceptualisation of CE for a better understanding of community…

  1. A conceptual model of plant responses to climate with implications for monitoring ecosystem change

    Science.gov (United States)

    C. David. Bertelsen

    2013-01-01

    Climate change is affecting natural systems on a global scale and is particularly rapid in the Southwest. It is important to identify impacts of a changing climate before ecosystems become unstable. Recognizing plant responses to climate change requires knowledge of both species present and plant responses to variable climatic conditions. A conceptual model derived...

  2. The Effect of 7E Model on Conceptual Success of Students in the Unit of Electromagnetism

    Science.gov (United States)

    Turgut, Umit; Colak, Alp; Salar, Riza

    2016-01-01

    The aim of this study was to investigate the impact of the course materials developed in accordance with 7E model in the unit of electromagnetism in high school physics class on students' conceptual success. The present study was conducted with a total of 52 11th grade students in two separate classrooms at a high school. The action research…

  3. A Conceptual Model for Teaching Critical Thinking in a Knowledge Economy

    Science.gov (United States)

    Chadwick, Clifton

    2011-01-01

    Critical thinking, viewed as rational and analytic thinking, is crucial for participation in a knowledge economy and society. This article provides a brief presentation of the importance of teaching critical thinking in a knowledge economy; suggests a conceptual model for teaching thinking; examines research on the historical role of teachers in…

  4. Pathways to Life Success: A Conceptual Model of Financial Well-Being for Young Adults

    Science.gov (United States)

    Shim, Soyeon; Xiao, Jing J.; Barber, Bonnie L.; Lyons, Angela C.

    2009-01-01

    The purpose of this study is to describe and test a conceptual model of the potential antecedents and consequences of financial well-being in young adulthood. Data (N = 781) were collected via an online survey conducted at a large state university in the southwestern United States. Our results suggest that self-actualizing personal values,…

  5. Dealing with unexpected events on the flight deck : A conceptual model of startle and surprise

    NARCIS (Netherlands)

    Landman, H.M.; Groen, E.L.; Paassen, M.M. van; Bronkhorst, A.W.; Mulder, M.

    2017-01-01

    Objective: A conceptual model is proposed in order to explain pilot performance in surprising and startling situations. Background: Today’s debate around loss of control following in-flight events and the implementation of upset prevention and recovery training has highlighted the importance of

  6. Dealing With Unexpected Events on the Flight Deck : A Conceptual Model of Startle and Surprise

    NARCIS (Netherlands)

    Landman, H.M.; Groen, Eric L.; van Paassen, M.M.; Bronkhorst, Adelbert W.; Mulder, M.

    2017-01-01

    Objective: A conceptual model is proposed in order to explain pilot performance in surprising and startling situations. Background: Today’s debate around loss of control following in-flight events and the implementation of upset prevention and recovery training has highlighted the importance of

  7. A Study to Determine the Mental Models in Preschool Children's Conceptualization of a Desert Environment

    Science.gov (United States)

    Ahi, Berat

    2016-01-01

    This study aimed to determine mental models and identify codes (schemes) used in conceptualizing a desert environment. The sample for this study consisted of 184--out of a total population of 3,630--children in preschool education in the central district of Kastamonu, Turkey. Within the scope of this study, the children were initially asked to…

  8. A Conceptual/Cross-cultural Model for Teaching Anthropology in the Elementary School.

    Science.gov (United States)

    Dynneson, Thomas L.

    A conceptual/cross-cultural model, developed to help elementary teachers cope with the problems of initiating cultural, ethnic, or anthropology studies, is presented in five sections. (1) A brief description of the structure and methodology of anthropology defines in outline form the fields of cultural and social anthropology, physical…

  9. Managing Higher Education in a Climate of Contraction: A Conceptual Model.

    Science.gov (United States)

    Doyle, K. J.

    1980-01-01

    A conceptual framework for managing higher education during a period of no growth, based on a model developed for business organizations by Joseph Schumpeter, is examined. Five categories of innovations included: new products (courses), new methods (improving productivity), new markets (students), new productive factors (sources of income), and…

  10. Conceptual design of a regional water quality screening model

    International Nuclear Information System (INIS)

    Davis, M.J.

    1981-01-01

    This water quality assessment methodology is intended to predict concentrations at future times and to estimate the impacts on water quality of energy-related activities (including industrial boilers). Estimates of impacts on water quality at future times are based on incremental changes in pollutant inputs to the body water. Important features of the model are: use of measured concentrations to account for existing conditions; consideration of incremental changes in pollutant loads; emphasis on the energy sector and industrial boilers; analysis restricted to streams only; no attempt to fully account for pollutant behavior; and flexible design, so that future improvements can be incorporated. The basic approach is very similar to the one used by Argonne's ARQUAL model but will allow more complex pollutant behavior and more flexibility in use

  11. Combat aircraft mission tradeoff models for conceptual design evaluation

    OpenAIRE

    Malakhoff, Lev A

    1988-01-01

    A methodology is developed to address the analyses of combat aircraft attrition. The operations of an aircraft carrier task force are modeled using the systems dynamics simulation language DYNAMO. The three mission-roles include: surface attack, lighter escort, and carrier defense. The level of analysis is performed over the entire campaign, going beyond the traditional single·sortie analysis level. These analyses are performed by determining several measures of effectiveness (...

  12. Conceptual Modeling of Performance Indicators of Higher Education Institutions

    OpenAIRE

    Kahveci, Tuba Canvar; Taşkın, Harun; Toklu, Merve Cengiz

    2013-01-01

    Measuring and analyzing any type of organization are carried out by different actors in the organization. The performance indicators of performance management system increase according to products or services of the organization. Also these indicators should be defined for all levels of the organization. Finally, all of these characteristics make the performance evaluation process more complex for organizations. In order to manage this complexity, the process should be modeled at the beginnin...

  13. Data Relationships: Towards a Conceptual Model of Scientific Data Catalogs

    Science.gov (United States)

    Hourcle, J. A.

    2008-12-01

    As the amount of data, types of processing and storage formats increase, the total number of record permutations increase dramatically. The result is an overwhelming number of records that make identifying the best data object to answer a user's needs more difficult. The issue is further complicated as each archive's data catalog may be designed around different concepts - - anything from individual files to be served, series of similarly generated and processed data, or something entirely different. Catalogs may not only be flat tables, but may be structured as multiple tables with each table being a different data series, or a normalized structure of the individual data files. Merging federated search results from archives with different catalog designs can create situations where the data object of interest is difficult to find due to an overwhelming number of seemingly similar or entirely unwanted records. We present a reference model for discussing data catalogs and the complex relationships between similar data objects. We show how the model can be used to improve scientist's ability to quickly identify the best data object for their purposes and discuss technical issues required to use this model in a federated system.

  14. Assessment of entrepreneurship pedagogy on entrepreneurship knowledge and entrepreneurial human capital asset: A conceptual model

    Directory of Open Access Journals (Sweden)

    Chidimma Odira Okeke

    2016-06-01

    Full Text Available This study is an effort to propose a conceptual model to measure the impact assessment of entrepreneurship pedagogic. It delineates entrepreneurship education pedagogic into four dimensions and opined specific level for each dimension. Reviewing the entrepreneurship education programme, assessment of entrepreneurship pedagogic evaluates the structure that influence growth mindset development through embedded heuristic strategies, thus, the impact on entrepreneurship knowledge and entrepreneurial capital asset context is proposed. Affirming Fayolle, Gailly, and Lassa-Clerc conceptual affinity that entrepreneurship education share with learning theories and entrepreneurship pedagogical content knowledge were conceptualized to suggest some practical realism guidelines of what insightful philosophy of teaching entrepreneurship need to achieve. With direct synthesis of relevant literature, propositions relating to entrepreneurship pedagogic structure along with the institutional connectedness and associated dimensions of entrepreneurship pedagogic assessment outcome were postulated. Also, the paper proposes the need for further assessment of specific forms of pedagogic impact on entrepreneurial human capital asset.

  15. Technologies for conceptual modelling and intelligent query formulation

    CSIR Research Space (South Africa)

    Alberts, R

    2008-11-01

    Full Text Available modelling and intelligent query formulation R ALBERTS1, K BRITZ1, A GERBER1, K HALLAND1,2, T MEYER1, L PRETORIUS1,2 (1) Knowledge Systems Group, Meraka Institute, CSIR, Pretoria, Gauteng, South Africa (2) School of Computing, University of South... this problem still more pressing: in this case an excess of information can be equivalent to an absence of information It is therefore necessary to use tools that organise data into intelligible and easily-accessible structures and return answers...

  16. [Cognitive therapy: foundations, conceptual models, applications and research].

    Science.gov (United States)

    Knapp, Paulo; Beck, Aaron T

    2008-10-01

    There is growing interest in the cognitive model of psychotherapy stimulated by an extensive body of research findings demonstrating its effectiveness for a varied set of psychiatric disorders and medical conditions. This review article aims to give an overview of the historical and philosophical background to contemporary cognitive and cognitive-behavioral approaches to psychotherapy, pointing out similarities across and differences between them. A presentation of the cognitive model as designed by Aaron Beck, and some of the cognitive and behavioral techniques used in emotional disorders will be discussed. Outcome studies and meta-analyses contemplating the efficacy of cognitive and cognitive-behavioral therapies in various psychological and medical conditions will be briefly depicted. Through review of articles and textbooks, especially the works of Aaron Beck from which this review article has heavily borrowed, the origins and foundations of the cognitive-behavioral approaches to the treatment of psychiatric and medical conditions are described. Through Medline, the search of randomized controlled trials and meta-analyses has pointed out the evidence-based efficacy of this psychotherapeutic approach. Cognitive-behavioral therapies in general and Beckian cognitive therapy in particular hold a theoretical foundation and a varied set of techniques, whose evidence-based efficacy was demonstrated for the treatment of diverse mental and physical conditions.

  17. Implementation of sorption hysteresis in multi-Fickian moisture transport

    DEFF Research Database (Denmark)

    Frandsen, Henrik Lund; Svensson, Staffan

    2007-01-01

    In the cellular structure of wood, bound-water diffusion and water-vapor diffusion interact via sorption in a complex moisture-transportation system. At low relative humidity, moisture transport may be modeled by a Fickian diffusion equation to a good approximation. At higher relative humidity...... this behavior. The multi-Fickian model describes the combined transport of bound water and vapor and their interaction through sorption. The bound-water concentration is also influenced by sorption hysteresis. In the worst case, sorption hysteresis may result in deviations of up to 30-35% in moisture content....... Hence, for a precise moisture content computation, sorption hysteresis must be taken into account. The present paper explains the relation between sorption hysteresis and multi-Fickian moisture transport, and clarifies how models for the two phenomena are coupled. To illustrate the effects, a finite...

  18. Effect of natural organic materials on cadmium and neptunium sorption

    International Nuclear Information System (INIS)

    Kung, K.S.; Triay, I.R.

    1994-01-01

    In a batch sorption study of the effect of naturally occurring organic materials on the sorption of cadmium and neptunium on oxides and tuff surfaces, the model sorbents were synthetic goethite, boehmite, amorphous silicon oxides, and a crushed tuff material from Yucca Mountain, Nevada. An amino acid, 3-(3,4-dihydroxypheny)-DL-alanine (DOPA), and an aquatic-originated fulvic material, Nordic aquatic fulvic acid (NAFA), were used as model organic chemicals. Sorption isotherm results showed that DOPA sorption followed the order aluminum oxide > iron oxide > silicon oxide and that the amount of DOAP sorption for a given sorbent increased as the solution pH was raised. The sorption of cadmium and neptunium on the iron oxide was about ten times higher than that on the aluminum oxide. The sorption of cadmium and neptunium on natural tuff material was much lower than that on aluminum and iron oxides. The sorption of cadmium on iron and aluminum oxides was found to be influenced by the presence of DOPA, and increasing the amount of DOPA coating resulted in higher cadmium sorption on aluminum oxide. However, for iron oxide, cadmium sorption decreased with increasing DOPA concentration. The presence of the model organic materials DOPA and NAFA did not affect the sorption of neptunium on tuff material or on the iron and aluminum oxides. Spectroscopic results indicate that cadmium complexes strongly with DOPA. Therefore, the effect of the organic material, DOPA, on the cadmium sorption is readily observed. However, neptunium is possibly complexed weakly with organic material. Thus, DOPA and NAFA have little effect on neptunium sorption on all sorbents selected for study

  19. Effect of natural organic materials on cadmium and neptunium sorption

    International Nuclear Information System (INIS)

    Kung, K.S.; Triay, I.R.

    1995-01-01

    In a batch sorption study of the effect of naturally occurring organic materials on the sorption of cadmium and neptunium on oxides and tuff surfaces, the model sorbents were synthetic goethite, boehmite, amorphous silicon oxides, and a crushed tuff material from Yucca Mountain, Nevada. An amino acid, 3-(3,4-dihydroxypheny)-DL-alanine (DOPA), and an aquatic-originated fulvic material, Nordic aquatic fulvic acid (NAFA), were used as model organic chemicals. Sorption isotherm results showed that DOPA sorption followed the order aluminum oxide > iron oxide > silicon oxide and that the amount of DOPA sorption for a given sorbent increased as the solution pH was raised. The sorption of cadmium and neptunium on the iron oxide was about ten times higher than that on the aluminum oxide. The sorption of cadmium and neptunium on natural tuff material was much lower than that on aluminum and iron oxides. The sorption of cadmium on iron and aluminum oxides was found to be influenced by the presence of DOPA, and increasing the amount of DOPA coating resulted in higher cadmium sorption on aluminum oxide. However, for iron oxide, cadmium sorption decreased with increasing DOPA concentration. The presence of the model organic materials DOPA and NAFA did not affect the sorption of neptunium on tuff material or on the iron and aluminum oxides. Spectroscopic results indicate that cadmium complexes strongly with DOPA. Therefore, the effect of the organic material, DOPA, on the cadmium sorption is readily observed. However, neptunium is possibly complexed weakly with organic material. Thus, DOPA and NAFA have little effect on neptunium sorption on all sorbents selected for study. (authors). 8 refs., 10 figs

  20. Radionuclide sorption on granitic drill core material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Locklund, B.

    1987-11-01

    Distribution ratios were determined for Sr-85, Cs-134 and Eu-152 on crushed granite and fissure coating/filling material from Stripa mines. Measurements were also carried out on intact fissure surfaces. The experimental data for Sr-85, Cs-134 on crushed material can be accomodated by a sorption model based on the assumption that the crushed material consists of porous spheres with outer and inner surfaces available for sorption. In the case of Eu-152 only sorption on the outer surfaces of the crushed material was observed. The absence of sorption on inner surfaces is most probably due to high depletion of the more strongly sorbed Eu-152 in the water phase and very low diffusivity of Eu-152 in the sorbed state. (orig./HP)

  1. A revised conceptual hydrogeologic model of a crystalline rock environment, Whiteshell research area, southeastern Manitoba, Canada

    International Nuclear Information System (INIS)

    Stevenson, D.R.; Brown, A.; Davison, C.C.; Gascoyne, M.; McGregor, R.G.; Ophori, D.U.; Scheier, N.W.; Stanchell, F.; Thorne, G.A.; Tomsons, D.K.

    1996-04-01

    A revised conceptual hydrogeologic model of regional groundwater flow in the crystalline rocks of the Whiteshell Research Area (WRA) has been developed by a team of AECL geoscientists. The revised model updates an earlier model developed in 1985, and has a much broader database. This database was compiled from Landsat and airborne radar images, geophysical surveys and surface mapping, and from analyses of fracture logs, hydraulic tests and water samples collected from a network of deep boreholes drilled across the WRA. The boundaries of the revised conceptual model were selected to coincide with the natural hydraulic boundaries assumed for the regional groundwater flow systems in the WRA. The upper and lower boundaries are the water table and a horizontal plane 4 km below ground surface. For modelling purposes the rocks below 4 km are considered to be impermeable. The rocks of the modelled region were divided on the basis of fracture characteristics into three categories: fractured zones (FZs); moderately fractured rock (MFR); and sparsely fractured rock (SFR). The FZs are regions of intensely fractured rock. Seventy-six FZs were selected to form the fault framework within the revised conceptual model. The physical rock/water properties of the FZs, MFR and SFR were selected by analysis of field data from hydraulic and tracer tests, laboratory test data and water quality data. These properties were used to define a mathematical groundwater flow model of the WRA using AECL's MOTIF finite element code (Ophori et al. 1995, 1996). (author). 29 refs., 4 tabs., 12 figs

  2. Managing the Marine Environment, Conceptual Models and Assessment Considerations for the European Marine Strategy Framework Directive

    Directory of Open Access Journals (Sweden)

    Christopher John Smith

    2016-08-01

    Full Text Available Conceptual models summarize, visualize and explain actual or predicted situations and how they might be tackled. In recent years, Pressure-State-Response (P-S-R frameworks have been central to conceptualizing marine ecosystem issues and then translating those to stakeholders, environmental managers and researchers. Society is concerned about the risks to the natural and human system posed by those Pressures (thus needing risk assessment and then needs to act to minimize or compensate those risks (as risk management. This research relates this to the DPSIR (Drivers-Pressure-State(change-Impact-Response hierarchical framework using standardized terminology/definitions and lists of impacting Activities and Pressures affecting ecosystem components, incorporating the European Marine Strategy Framework Directive (MSFD legal decision components. This uses the example of fishing activity and the pressure of trawling from abrasion on the seabed and its effects on particular components. The mechanisms of Pressure acting on State changes are highlighted here as an additional refinement to DPSIR. The approach moves from conceptual models to actual assessments including: assessment methodologies (interactive matrices, ecosystem modeling, Bayesian Belief Networks, Bow-tie approach, some assessment tools data availability, confidence, scaling, cumulative effects and multiple simultaneous Pressures, which more often occur in multi-use and multi-user areas. In defining and describing the DPSIR Conceptual Framework we consider its use in re-world ecosystems affected by multiple pressures or multiple mechanisms of single pressures, and show how it facilitates management and assessment issues with particular relevance to the MSFD.

  3. CONCEPTUAL MODELLING AND ORGANIZATION OF SECURITY MECHANISMS IN DISTRIBUTED SYSTEMS

    Directory of Open Access Journals (Sweden)

    T. Galibus

    2016-01-01

    Full Text Available We analyze the existing DS from the point of security and construct a two-level hierarchy of models. Such approach allows us to separate the abstraction (architecture level and the concrete (component level of ISS. The core set of methods, i. e. authentication and key exchange protocols, corresponds to the abstraction level and is defined as security infrastructure (SI. The final security parameters optimization and additional mechanisms such as authorization, routing and data auditing of the protection mechanisms are configured on the component level of the DS. In addition, we outline the systematic step-by-step ISS configuration method.

  4. The Adoption of New Technology: Conceptual Model and Application

    Directory of Open Access Journals (Sweden)

    Miriam Christi Nemoto

    2010-12-01

    Full Text Available The decision to adopt a new technology or not depends on the benefits to be gained by incorporating new technical, functional or esthetic solutions, in order to attain the company’s competitive positioning; this decision also depends on the costs and risks involved. In general terms, businesses lack the resources, whether financial, human, or structural, to innovate or even to adapt new technologies. The objectives of this study are to test an innovation adoption model on a real case and show the importance of international cooperation for new technology implementation processes, based on a decision-making case about whether or not to adopt a new technology that occurred in eletronic company in Brazil (called “A”. The new technology might help to solve certain challenges the company faced in its printer plant, by increasing efficiency and cutting costs.

  5. A conceptual model for barrier free facilities planning.

    Science.gov (United States)

    Bittencourt, R S; de M Guimarães, L B

    2012-01-01

    This paper presents the proposal of a model for planning a barrier free industrial facilities, considering the demands that inclusion requires, ranging from outside the factory (social environment), to the needs of the production system and the workstation. Along with literature review, the demands were identified in a shoe manufacturer that employs people with disabilities, and organized taxonomically in agreement with the structure for planning facilities. The results show that the problems are not primarily related to eliminating architectural barriers and factors aimed at preventing risks to people's health and safety but, rather, are related to the company's cultural environment, because the main hazards are managerial. In special cases, it is suggested there is a need to adjust those parts of tasks that the worker cannot do, or even to re-schedule work so as to make it possible for employees with disabilities to perform their tasks.

  6. Three-dimensional conceptual model for the Hanford Site unconfined aquifer system, FY 1993 status report

    International Nuclear Information System (INIS)

    Thorne, P.D.; Chamness, M.A.; Spane, F.A. Jr.; Vermeul, V.R.; Webber, W.D.

    1993-12-01

    The ground water underlying parts of the Hanford Site (Figure 1.1) contains radioactive and chemical contaminants at concentrations exceeding regulatory standards (Dresel et al. 1993). The Hanford Site Ground-Water Surveillance Project, operated by Pacific Northwest Laboratory (PNL), is responsible for monitoring the movement of these contaminants to ensure that public health and the environment are protected. To support the monitoring effort, a sitewide three-dimensional ground-water flow model is being developed. This report provides an update on the status of the conceptual model that will form the basis for constructing a numerical three-dimensional flow model for, the site. Thorne and Chamness (1992) provide additional information on the initial development of the three-dimensional conceptual model

  7. Apparel shopping behaviour – Part 2: Conceptual theoretical model, market segments, profiles and implications

    Directory of Open Access Journals (Sweden)

    R. Du Preez

    2003-10-01

    Full Text Available This article is based on the conceptual theoretical model developed in Part 1 of this series of articles. The objective of this research is to identify female apparel consumer market segments on the basis of differentiating lifestyles, shopping orientation, cultural consciousness, store patronage and demographics. These profiles are discussed in full and the implications thereof for retailers, marketers and researchers are highlighted. A new conceptual model is proposed and recommendations are made for further research. Opsomming Hierdie artikel word gebaseer op die konseptuele teoretiese model wat reeds in Deel 1 van hierdie artikelreeks ontwikkel is. Die doel van hierdie navorsing is om marksegmente van vroue klere-kopers te identifiseer na aanleiding van hulle lewenstyle, kooporiëntasie, kulturele bewustheid, winkelvoorkeurgedrag en demografie. Hierdie profiele word volledig beskryf en die implikasies van die verskillende profiele vir kleinhandelaars, bemarkers en navorsers word uitgelig. ’n Nuwe konseptuele model word voorgestel en aanbevelings vir verdere navorsing word gemaak.

  8. A Conceptual Model of Technology Transfer for Public Universities in Mexico

    Directory of Open Access Journals (Sweden)

    Hugo Necoechea

    2013-12-01

    Full Text Available Technology transfer from academic and scientific institutions has been transformed into a strategic variable for companies and nations who wish to cope with the challenges of a global economy. Since the early 1970s, many technology transfer models have tried to introduce key factors in the process. Previous studies have shown that technology transfer is influenced by various elements. This study is based on a review of two recent technology transfer models that we have used as basic concepts for developing our own conceptual model. Researcher–firm networks have been considered as key elements in the technology transfer process between public universities and firms. The conceptual model proposed could be useful to improve the efficiency of existing technology transfer mechanisms.

  9. A year 2003 conceptual model for the U.S. telecommunications infrastructure.

    Energy Technology Data Exchange (ETDEWEB)

    Cox, Roger Gary; Reinert, Rhonda K.

    2003-12-01

    To model the telecommunications infrastructure and its role and robustness to shocks, we must characterize the business and engineering of telecommunications systems in the year 2003 and beyond. By analogy to environmental systems modeling, we seek to develop a 'conceptual model' for telecommunications. Here, the conceptual model is a list of high-level assumptions consistent with the economic and engineering architectures of telecommunications suppliers and customers, both today and in the near future. We describe the present engineering architectures of the most popular service offerings, and describe the supplier markets in some detail. We also develop a characterization of the customer base for telecommunications services and project its likely response to disruptions in service, base-lining such conjectures against observed behaviors during 9/11.

  10. CONCEPTUAL MODEL OF FINANCIAL INDEXES FOR INFORMATIVE SYSTEM IN NAPS OF UKRAINE

    Directory of Open Access Journals (Sweden)

    Alla V. Kilchenko

    2011-10-01

    Full Text Available The actual task of modern information society forming is a construction and introduction of the information systems in educational management. The article contains the analysis of subject domain of the informative system in the National Academy of Pedagogical Sciences of Ukraine, description of financial documents and facilities for automations of their treatment in the integrated environment of Windows SharePoint Services – Microsoft Word. The conceptual model of information is presented, it is shown, as on its basis facilities of automation of work are built with financial documents. The CRT forms of document life cycle are resulted in the information system: conceptual model of information, logical model of data, physical model of data, template, a document, eventual document with the automatic filling of indexes of financial documents.

  11. Some problems with social cognition models: a pragmatic and conceptual analysis.

    Science.gov (United States)

    Ogden, Jane

    2003-07-01

    Empirical articles published between 1997 and 2001 from 4 health psychology journals that tested or applied 1 or more social cognition models (theory of reasoned action, theory of planned behavior, health belief model, and protection motivation theory; N = 47) were scrutinized for their pragmatic and conceptual basis. In terms of their pragmatic basis, these 4 models were useful for guiding research. The analysis of their conceptual basis was less positive. First, these models do not enable the generation of hypotheses because their constructs are unspecific; they therefore cannot be tested. Second, they focus on analytic truths rather than synthetic ones, and the conclusions resulting from their application are often true by definition rather than by observation. Finally, they may create and change both cognitions and behavior rather than describe them.

  12. Conceptualization of Approaches and Thought Processes Emerging in Validating of Model in Mathematical Modeling in Technology Aided Environment

    Science.gov (United States)

    Hidiroglu, Çaglar Naci; Bukova Güzel, Esra

    2013-01-01

    The aim of the present study is to conceptualize the approaches displayed for validation of model and thought processes provided in mathematical modeling process performed in technology-aided learning environment. The participants of this grounded theory study were nineteen secondary school mathematics student teachers. The data gathered from the…

  13. A surface complexation model of YREE sorption on Ulva lactuca in 0.05-5.0 M NaCl solutions

    Science.gov (United States)

    Zoll, Alison M.; Schijf, Johan

    2012-11-01

    We present distribution coefficients, log iKS, for the sorption of yttrium and the rare earth elements (YREEs) on BCR-279, a dehydrated tissue homogenate of a marine macroalga, Ulva lactuca, resembling materials featured in chemical engineering studies aimed at designing renewable biosorbents. Sorption experiments were conducted in NaCl solutions of different ionic strength (0.05, 0.5, and 5.0 M) at T = 25 °C over the pH range 2.7-8.5. Distribution coefficients based on separation of the dissolved and particulate phase by conventional filtration (3 kDa) using an existing pH-dependent model. Colloid-corrected values were renormalized to free-cation concentrations by accounting for YREE hydrolysis and chloride complexation. At each ionic strength, the pH dependence of the renormalized values is accurately described with a non-electrostatic surface complexation model (SCM) that incorporates YREE binding to three monoprotic functional groups, previously characterized by alkalimetric titration, as well as binding of YREE-hydroxide complexes (MOH2+) to the least acidic one (pKa ∼ 9.5). In non-linear regressions of the distribution coefficients as a function of pH, each pKa was fixed at its reported value, while stability constants of the four YREE surface complexes were used as adjustable parameters. Data for a single fresh U. lactuca specimen in 0.5 M NaCl show generally the same pH-dependent behavior but a lower degree of sorption and were excluded from the regressions. Good linear free-energy relations (LFERs) between stability constants of the YREE-acetate and YREE-hydroxide solution complex and surface complexes with the first and third functional group, respectively, support their prior tentative identifications as carboxyl and phenol. A similar confirmation for the second group is precluded by insufficient knowledge of the stability of YREE-phosphate complexes and a perceived lack of YREE binding in 0.05 M NaCl; this issue awaits further study. The results

  14. Understanding decreases in land relative humidity with global warming: conceptual model and GCM simulations

    OpenAIRE

    Byrne, Michael P.; O'Gorman, Paul A.

    2016-01-01

    Climate models simulate a strong land-ocean contrast in the response of near-surface relative humidity to global warming: relative humidity tends to increase slightly over oceans but decrease substantially over land. Surface energy balance arguments have been used to understand the response over ocean but are difficult to apply over more complex land surfaces. Here, a conceptual box model is introduced, involving moisture transport between the land and ocean boundary layers and evapotranspira...

  15. Soundscape descriptors and a conceptual framework for developing predictive soundscape models

    OpenAIRE

    Aletta, F.; Kang, J.; Axelsson, O.

    2016-01-01

    Soundscape exists through human perception of the acoustic environment. This paper investigates how soundscape currently is assessed and measured. It reviews and analyzes the main soundscape descriptors in the soundscape literature, and provides a conceptual framework for developing predictive models in soundscape studies. A predictive soundscape model provides a means of predicting the value of a soundscape descriptor, and the blueprint for how to design soundscape. It is the key for impleme...

  16. Pesticide fate on catchment scale: conceptual modelling of stream CSIA data

    Science.gov (United States)

    Lutz, Stefanie R.; van der Velde, Ype; Elsayed, Omniea F.; Imfeld, Gwenaël; Lefrancq, Marie; Payraudeau, Sylvain; van Breukelen, Boris M.

    2017-10-01

    Compound-specific stable isotope analysis (CSIA) has proven beneficial in the characterization of contaminant degradation in groundwater, but it has never been used to assess pesticide transformation on catchment scale. This study presents concentration and carbon CSIA data of the herbicides S-metolachlor and acetochlor from three locations (plot, drain, and catchment outlets) in a 47 ha agricultural catchment (Bas-Rhin, France). Herbicide concentrations at the catchment outlet were highest (62 µg L-1) in response to an intense rainfall event following herbicide application. Increasing δ13C values of S-metolachlor and acetochlor by more than 2 ‰ during the study period indicated herbicide degradation. To assist the interpretation of these data, discharge, concentrations, and δ13C values of S-metolachlor were modelled with a conceptual mathematical model using the transport formulation by travel-time distributions. Testing of different model setups supported the assumption that degradation half-lives (DT50) increase with increasing soil depth, which can be straightforwardly implemented in conceptual models using travel-time distributions. Moreover, model calibration yielded an estimate of a field-integrated isotopic enrichment factor as opposed to laboratory-based assessments of enrichment factors in closed systems. Thirdly, the Rayleigh equation commonly applied in groundwater studies was tested by our model for its potential to quantify degradation on catchment scale. It provided conservative estimates on the extent of degradation as occurred in stream samples. However, largely exceeding the simulated degradation within the entire catchment, these estimates were not representative of overall degradation on catchment scale. The conceptual modelling approach thus enabled us to upscale sample-based CSIA information on degradation to the catchment scale. Overall, this study demonstrates the benefit of combining monitoring and conceptual modelling of concentration

  17. Facilitating Corporate Entrepreneurship in Public Sector Higher Education Institutions: A Conceptual Model

    Directory of Open Access Journals (Sweden)

    Javed Nayyar Malik

    2012-06-01

    Full Text Available This paper develops a conceptual model of public sector corporate entrepreneurship for the state government higher education institutions. The proposed model is intended to depict the main antecedents that relate to corporate entrepreneurship within the public sector higher education institution  and the impact of corporate entrepreneurship on public sector HEI’s performance, as well as factors influencing its continuous performance.

  18. Development of a conceptual flow-path model of nuclide migration in crystalline rock -- A case study at the Kamaishi In-Situ Test Site, Japan

    International Nuclear Information System (INIS)

    Osawa, H.; Ota, K.; Yoshida, H.; Sasamoto, H.; Nohara, T.

    1995-01-01

    The objective of this study is to develop a conceptual flow-path model for nuclide migration in fractured crystalline rock at the Kamaishi In-Situ Test Site (KITS) because improvement of existing models of matrix diffusion, based on realistic geological data, is necessary for a better understanding of nuclide migration into rock matrix. Data from field observations indicate that fractures at the KITS can be classified into three types; type A with a zone of fracture fillings, type B with a zone of fracture fillings and an altered zone, type C consisting of several fractures with a zone of fracture fillings and an altered zone. Fracture type B was studied in detail by laboratory experiments because type B is predominant in the studied area with more than 60% of a total of 400 fractures observed in the fracture mapping. Data from laboratory experiments on core, crosscutting a water-bearing fracture and the surrounding rock, indicate that the zone of fracture fillings and the altered zone in the vicinity of the fracture contain flow-paths in which nuclides can migrate and be trapped. The fracture fillings contain more interconnected and permeable flow-paths than the altered and unaltered zones. This implies that migrating nuclides can access flow-paths in the altered zone. The altered zone adjacent to the zone of the fracture fillings contains flow-paths such as microfractures, cracks within quartz, and grain boundaries between altered minerals, through which nuclides will migrate from the fracture fillings into the altered zone and be trapped. The fracture fillings and the specimen of the altered zone have higher sorption capacity than the specimen of the unaltered zone. These data suggest that retention of nuclides can be expected in the vicinity of the fracture. A conceptual flow-path model consisting of zone of fracture fillings, an altered zone, and an unaltered zone has been developed for a better understanding of nuclide migration in fracture type B

  19. What Can Be Learned From a Laboratory Model of Conceptual Change? Descriptive Findings and Methodological Issues

    Science.gov (United States)

    Ohlsson, Stellan; Cosejo, David G.

    2014-07-01

    The problem of how people process novel and unexpected information— deep learning (Ohlsson in Deep learning: how the mind overrides experience. Cambridge University Press, New York, 2011)—is central to several fields of research, including creativity, belief revision, and conceptual change. Researchers have not converged on a single theory for conceptual change, nor has any one theory been decisively falsified. One contributing reason is the difficulty of collecting informative data in this field. We propose that the commonly used methodologies of historical analysis, classroom interventions, and developmental studies, although indispensible, can be supplemented with studies of laboratory models of conceptual change. We introduce re- categorization, an experimental paradigm in which learners transition from one definition of a categorical concept to another, incompatible definition of the same concept, a simple form of conceptual change. We describe a re-categorization experiment, report some descriptive findings pertaining to the effects of category complexity, the temporal unfolding of learning, and the nature of the learner's final knowledge state. We end with a brief discussion of ways in which the re-categorization model can be improved.

  20. Sorption properties of wool

    Directory of Open Access Journals (Sweden)

    Radetić Maja M.

    2004-01-01

    Full Text Available Strict ecological legislation, especially in highly developed countries, imposed requirements for the purification of industrial effluents and the need for efficient oil clean up after sea and inland water spills. Although numerous processes have been developed, the application of sorbents is still one of the most efficient methods to remove heavy metal ions, dyes and crude oil from water. Recently, special attention was paid to sorbents based on natural fibres. A review of studies concerning the sorption properties of wool is presented in this paper. The presence of various functional groups on the wool fibre surface contributes to the efficient sorption of heavy metal ions and dyes. A hydrophobic, scaly surface and fibre crimp strongly influence the high sorption capacity of wool for oil. Wool has great sorption potential even as a recycled material. Accordingly, it can be used as a viable substitute to commercially available synthetic sorbents that show poor biodegradab ility.

  1. The EBM-DPSER Conceptual Model: Integrating Ecosystem Services into the DPSIR Framework

    Science.gov (United States)

    Kelble, Christopher R.; Loomis, Dave K.; Lovelace, Susan; Nuttle, William K.; Ortner, Peter B.; Fletcher, Pamela; Cook, Geoffrey S.; Lorenz, Jerry J.; Boyer, Joseph N.

    2013-01-01

    There is a pressing need to integrate biophysical and human dimensions science to better inform holistic ecosystem management supporting the transition from single species or single-sector management to multi-sector ecosystem-based management. Ecosystem-based management should focus upon ecosystem services, since they reflect societal goals, values, desires, and benefits. The inclusion of ecosystem services into holistic management strategies improves management by better capturing the diversity of positive and negative human-natural interactions and making explicit the benefits to society. To facilitate this inclusion, we propose a conceptual model that merges the broadly applied Driver, Pressure, State, Impact, and Response (DPSIR) conceptual model with ecosystem services yielding a Driver, Pressure, State, Ecosystem service, and Response (EBM-DPSER) conceptual model. The impact module in traditional DPSIR models focuses attention upon negative anthropomorphic impacts on the ecosystem; by replacing impacts with ecosystem services the EBM-DPSER model incorporates not only negative, but also positive changes in the ecosystem. Responses occur as a result of changes in ecosystem services and include inter alia management actions directed at proactively altering human population or individual behavior and infrastructure to meet societal goals. The EBM-DPSER conceptual model was applied to the Florida Keys and Dry Tortugas marine ecosystem as a case study to illustrate how it can inform management decisions. This case study captures our system-level understanding and results in a more holistic representation of ecosystem and human society interactions, thus improving our ability to identify trade-offs. The EBM-DPSER model should be a useful operational tool for implementing EBM, in that it fully integrates our knowledge of all ecosystem components while focusing management attention upon those aspects of the ecosystem most important to human society and does so within

  2. TOWARDS A CONCEPTUAL FRAMEWORK OF ISLAMIC LEADERSHIP SUCCESSOR'S ATTRIBUTES MODEL AND GOOD GOVERNANCE

    Directory of Open Access Journals (Sweden)

    Naji Zuhair Alsarhi

    2015-12-01

    Full Text Available The purpose of this paper is to propose a conceptual model that explains the relationship between Islamic leadership successionpersonalityattributes and good governance. The paper sources information from an extensive search of literature to design a conceptual model of Islamic leadership succession (personal attributes & governmental characteristics of Succession and good governance. The model will provide an integration of relationships that will add valuable insights into improved leadership succession theory in the related literature. The paper may assist particularly policy makers and strategists to focus on new possibilities of leadership successors attributes that will lead to improved governance as well as government performance in the world in general, and the Palestine community, in particular.

  3. Sorption of organophosphate esters by carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Wei; Yan, Li [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China); Duan, Jinming [School of Environmental and Municipal Engineering, Xi’an University of Architecture and Technology, Xi’an 710055 (China); Jing, Chuanyong, E-mail: cyjing@rcees.ac.cn [State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 (China)

    2014-05-01

    Graphical abstract: The interfacial interactions between the OPE molecules and CNTs. - Highlights: • Oxygen-containing groups on CNTs change the sorption property for OPEs. • Molecular configuration of OPEs has insignificant impact on their sorption. • Hydrophobic, π–π EDA and Brønsted acid–base interaction occurred between the CNTs and OPEs. - Abstract: Insights from the molecular-level mechanism of sorption of organophosphate esters (OPEs) on carbon nanotubes (CNTs) can further our understanding of the fate and transport of OPEs in the environment. The motivation for our study was to explore the sorption process of OPEs on multi-walled CNTs (MWCNTs), single-walled CNTs (SWCNTs) and their oxidized counterparts (O-MWCNTs and O-SWCNTs), and its molecular mechanism over a wide concentration range. The sorption isotherm results revealed that the hydrophobicity of OPEs dominated their affinities on a given CNT and the π–π electron donor–acceptor (EDA) interaction also played an important role in the sorption of aromatic OPEs. This π–π EDA interaction, verified with Raman and FT-IR spectroscopy, could restrict the radial vibration of SWCNTs and affect the deformation vibration γ(CH) bands of OPE molecules. The OPE surface coverage on CNTs, estimated using the nonlinear Dubinin–Ashtakhov model, indicated that the oxygen-containing functional groups on CNTs could interact with water molecules by H-bonding, resulting in a decrease in effective sorption sites. In addition, FTIR analysis also confirmed the occurrence of Brønsted acid–base interactions between OPEs and surface OH groups of SWCNTs. Our results should provide mechanistic insights into the sorption mechanism of OPE contaminants on CNTs.

  4. Ecohydrologic Response of a Wetland Indicator Species to Climate Change and Streamflow Regulation: A Conceptual Model

    Science.gov (United States)

    Ward, E. M.; Gorelick, S.

    2015-12-01

    The Peace-Athabasca Delta ("Delta") in northeastern Alberta, Canada, is a UNESCO World Heritage Site and a Ramsar Wetland of International Importance. Delta ecohydrology is expected to respond rapidly to upstream water demand and climate change, with earlier spring meltwater, decreased springtime peak flow, and a decline in springtime ice-jam flooding. We focus on changes in the population and distribution of muskrat (Ondatra zibethicus), an ecohydrologic indicator species. We present a conceptual model linking hydrology and muskrat ecology. Our conceptual model links seven modules representing (1) upstream water demand, (2) streamflow and snowmelt, (3) floods, (4) the water balance of floodplain lakes, (5) muskrat habitat suitability, (6) wetland vegetation, and (7) muskrat population dynamics predicted using an agent-based model. Our goal is to evaluate the effects of different climate change and upstream water demand scenarios on the abundance and distribution of Delta muskrat, from present-2100. Moving from the current conceptual model to a predictive quantitative model, we will rely on abundant existing data and Traditional Ecological Knowledge of muskrat and hydrology in the Delta.

  5. Linking Land Change with Driving Forces and Actors: Four Conceptual Models

    Directory of Open Access Journals (Sweden)

    Anna M. Hersperger

    2010-12-01

    Full Text Available Models in land change research are often chosen arbitrarily based on practical rather than theoretical considerations. More specifically, research on land change is often based on a research framework with three crucial elements - driving forces, actors, and land change - in an ad hoc and case-specific configuration. The lack of solid and widely applicable concepts about the conceptual link between these three elements can negatively affect individual research projects and hamper communication and generalizations beyond the individual project. We present four basic models for linking land change with driving forces and actors. These models are illustrated with examples from the research literature. Based on the main characteristics of the models and practical considerations, we propose guidelines for choosing among the four models for specific studies. More generally, we want to raise awareness that land change research is especially demanding with respect to conceptual backgrounds and that conceptual considerations will help improve the scientific quality of individual studies as well as their potential contribution towards generic theories of land change.

  6. Conceptual model elaboration for the safety assessment of phosphogypsum use in sanitary landfills

    Energy Technology Data Exchange (ETDEWEB)

    Cota, Stela D.; Braga, Leticia T.P.; Jacomino, Vanusa F., E-mail: sdsc@cdtn.b, E-mail: letsteixeira@gmail.co, E-mail: vmfj@cdtn.b [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2009-07-01

    Phosphogypsum is a by-product of the phosphatic fertilizer production from the beneficiation of phosphate minerals (apatites). Produced in large quantities throughout the world and stored temporally in stacks, the final destination of this product is nowadays a subject of investigation. Due to the presence of radionuclides ({sup 226}Ra, {sup 232}Th and {sup 40}K, mainly), possible applications for the phosphogypsum must be verified for radiological safety. The goal of this paper was to elaborate a representative water flow conceptual model of a sanitary landfill for the safety assessment of the impact of using phosphogypsum as a cover material. For this, the ground water flow in variably saturated conditions and solute transport model HYDRUS-2D has been used for simulating the impact in the saturated zone of potential radionuclides leaching. The conceptual model was developed by collecting and analyzing the data from environmental license documentation of municipal sanitary landfills located on the State of Minas Gerais, Brazil. In order to fulfill the requirements of HDRUS-2D model in terms of the necessary parameters, the physical characteristics and typical configuration of the landfills, as well as the hydrogeological parameters of soils and aquifers related to the local of placement of the landfills, were taken in account for the formulation of the conceptual model. (author)

  7. Proposal for a parametric conceptual CAD model of a mono-modular inertial fusion reactor

    International Nuclear Information System (INIS)

    Vezzani, M.; Cerullo, N.; Lanza, S.

    2001-01-01

    The present work tries to solve the problem of realizing a parametric conceptual CAD model of a modular reactor for future inertial fusion power plants. The choice of a modular structure seems to be a good solution for efficiency and economic requirements. On the other hand, the realization of a parametric-variational CAD model is very useful to optimize nuclear and mechanical parameters and to permit the shift from the conceptual to the final model. First, geometric solutions for a modular reactor are analysed; the most interesting is that of a 20-face regular polyhedron (icosahedron). The subdivision of each face into six equal triangles consents to obtain a mono-modular reactor with 120 modules (called 'ICO120'). This solution should be easy, efficient and cheap. Secondly, the work proposes a conceptual CAD model of the ICO120 reactor in which special attention is put on the parametrization. Starting from such parametric model it will be possible to develop and optimize icosahedral reactors with different features, sizes and performances

  8. Europium retention onto clay minerals from 25 to 150 °C: Experimental measurements, spectroscopic features and sorption modelling

    Science.gov (United States)

    Tertre, E.; Berger, G.; Simoni, E.; Castet, S.; Giffaut, E.; Loubet, M.; Catalette, H.

    2006-09-01

    The sorption of Eu(III) onto kaolinite and montmorillonite was investigated up to 150 °C. The clays were purified samples, saturated with Na in the case of montmorillonite. Batch experiments were conducted at 25, 40, 80 and 150 °C in 0.5 M NaClO 4 solutions to measure the distribution coefficients (Kd) of Eu as a trace element (les argiles: influence des silicates. Ph.D. Thesis, Université Paris Sud, France, 330p].

  9. Patient-Clinician Communication About Pain: A Conceptual Model and Narrative Review.

    Science.gov (United States)

    Henry, Stephen G; Matthias, Marianne S

    2018-02-01

    Productive patient-clinician communication is an important component of effective pain management, but we know little about how patients and clinicians actually talk about pain in clinical settings and how it might be improved to produce better patient outcomes. The objective of this review was to create a conceptual model of patient-clinician communication about noncancer pain, review and synthesize empirical research in this area, and identify priorities for future research. A conceptual model was developed that drew on existing pain and health communication research. CINAHL, EMBASE, and PubMed were searched to find studies reporting empirical data on patient-clinician communication about noncancer pain; results were supplemented with manual searches. Studies were categorized and analyzed to identify crosscutting themes and inform model development. The conceptual model comprised the following components: contextual factors, clinical interaction, attitudes and beliefs, and outcomes. Thirty-nine studies met inclusion criteria and were analyzed based on model components. Studies varied widely in quality, methodology, and sample size. Two provisional conclusions were identified: contrary to what is often reported in the literature, discussions about analgesics are most frequently characterized by patient-clinician agreement, and self-presentation during patient-clinician interactions plays an important role in communication about pain and opioids. Published studies on patient-clinician communication about noncancer pain are few and diverse. The conceptual model presented here can help to identify knowledge gaps and guide future research on communication about pain. Investigating the links between communication and pain-related outcomes is an important priority for future research. © 2018 American Academy of Pain Medicine. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com

  10. Statistical and Conceptual Model Testing Geomorphic Principles through Quantification in the Middle Rio Grande River, NM.

    Science.gov (United States)

    Posner, A. J.

    2017-12-01

    The Middle Rio Grande River (MRG) traverses New Mexico from Cochiti to Elephant Butte reservoirs. Since the 1100s, cultivating and inhabiting the valley of this alluvial river has required various river training works. The mid-20th century saw a concerted effort to tame the river through channelization, Jetty Jacks, and dam construction. A challenge for river managers is to better understand the interactions between a river training works, dam construction, and the geomorphic adjustments of a desert river driven by spring snowmelt and summer thunderstorms carrying water and large sediment inputs from upstream and ephemeral tributaries. Due to its importance to the region, a vast wealth of data exists for conditions along the MRG. The investigation presented herein builds upon previous efforts by combining hydraulic model results, digitized planforms, and stream gage records in various statistical and conceptual models in order to test our understanding of this complex system. Spatially continuous variables were clipped by a set of river cross section data that is collected at decadal intervals since the early 1960s, creating a spatially homogenous database upon which various statistical testing was implemented. Conceptual models relate forcing variables and response variables to estimate river planform changes. The developed database, represents a unique opportunity to quantify and test geomorphic conceptual models in the unique characteristics of the MRG. The results of this investigation provides a spatially distributed characterization of planform variable changes, permitting managers to predict planform at a much higher resolution than previously available, and a better understanding of the relationship between flow regime and planform changes such as changes to longitudinal slope, sinuosity, and width. Lastly, data analysis and model interpretation led to the development of a new conceptual model for the impact of ephemeral tributaries in alluvial rivers.

  11. Strategies to Move From Conceptual Models to Quantifying Resilience in FEW Systems

    Science.gov (United States)

    Padowski, J.; Adam, J. C.; Boll, J.; Barber, M. E.; Cosens, B.; Goldsby, M.; Fortenbery, R.; Fowler, A.; Givens, J.; Guzman, C. D.; Hampton, S. E.; Harrison, J.; Huang, M.; Katz, S. L.; Kraucunas, I.; Kruger, C. E.; Liu, M.; Luri, M.; Malek, K.; Mills, A.; McLarty, D.; Pickering, N. B.; Rajagopalan, K.; Stockle, C.; Richey, A.; Voisin, N.; Witinok-Huber, B.; Yoder, J.; Yorgey, G.; Zhao, M.

    2017-12-01

    Understanding interdependencies within Food-Energy-Water (FEW) systems is critical to maintain FEW security. This project examines how coordinated management of physical (e.g., reservoirs, aquifers, and batteries) and non-physical (e.g., water markets, social capital, and insurance markets) storage systems across the three sectors promotes resilience. Coordination increases effective storage within the overall system and enhances buffering against shocks at multiple scales. System-wide resilience can be increased with innovations in technology (e.g., smart systems and energy storage) and institutions (e.g., economic systems and water law). Using the Columbia River Basin as our geographical study region, we use an integrated approach that includes a continuum of science disciplines, moving from theory to practice. In order to understand FEW linkages, we started with detailed, connected conceptual models of the food, energy, water, and social systems to identify where key interdependencies (i.e., overlaps, stocks, and flows) exist within and between systems. These are used to identify stress and opportunity points, develop innovation solutions across FEW sectors, remove barriers to the adoption of solutions, and quantify increases in system-wide resilience to regional and global change. The conceptual models act as a foundation from which we can identify key drivers, parameters, time steps, and variables of importance to build and improve existing systems dynamic and biophysical models. Our process of developing conceptual models and moving to integrated modeling is critical and serves as a foundation for coupling quantitative components with economic and social domain components and analyses of how these interact through time and space. This poster provides a description of this process that pulls together conceptual maps and integrated modeling output to quantify resilience across all three of the FEW sectors (a.k.a. "The Resilience Calculator"). Companion posters

  12. Applying model analysis to a resource-based analysis of the Force and Motion Conceptual Evaluation

    Directory of Open Access Journals (Sweden)

    Trevor I. Smith

    2014-07-01

    Full Text Available Previously, we analyzed the Force and Motion Conceptual Evaluation in terms of a resources-based model that allows for clustering of questions so as to provide useful information on how students correctly or incorrectly reason about physics. In this paper, we apply model analysis to show that the associated model plots provide more information regarding the results of investigations using these question clusters than normalized gain graphs. We provide examples from two different institutions to show how the use of model analysis with our redefined clusters can provide previously hidden insight into the effectiveness of instruction.

  13. Simulation of shallow groundwater levels: Comparison of a data-driven and a conceptual model

    Science.gov (United States)

    Fahle, Marcus; Dietrich, Ottfried; Lischeid, Gunnar

    2015-04-01

    Despite an abundance of models aimed at simulating shallow groundwater levels, application of such models is often hampered by a lack of appropriate input data. Difficulties especially arise with regard to soil data, which are typically hard to obtain and prone to spatial variability, eventually leading to uncertainties in the model results. Modelling approaches relying entirely on easily measured quantities are therefore an alternative to encourage the applicability of models. We present and compare two models for calculating 1-day-ahead predictions of the groundwater level that are only based on measurements of potential evapotranspiration, precipitation and groundwater levels. The first model is a newly developed conceptual model that is parametrized using the White method (which estimates the actual evapotranspiration on basis of diurnal groundwater fluctuations) and a rainfall-response ratio. Inverted versions of the two latter approaches are then used to calculate the predictions of the groundwater level. Furthermore, as a completely data-driven alternative, a simple feed-forward multilayer perceptron neural network was trained based on the same inputs and outputs. Data of 4 growing periods (April to October) from a study site situated in the Spreewald wetland in North-east Germany were taken to set-up the models and compare their performance. In addition, response surfaces that relate model outputs to combinations of different input variables are used to reveal those aspects in which the two approaches coincide and those in which they differ. Finally, it will be evaluated whether the conceptual approach can be enhanced by extracting knowledge of the neural network. This is done by replacing in the conceptual model the default function that relates groundwater recharge and groundwater level, which is assumed to be linear, by the non-linear function extracted from the neural network.

  14. A conceptual model of psychosocial risk and protective factors for excessive gestational weight gain.

    Science.gov (United States)

    Hill, Briony; Skouteris, Helen; McCabe, Marita; Milgrom, Jeannette; Kent, Bridie; Herring, Sharon J; Hartley-Clark, Linda; Gale, Janette

    2013-02-01

    nearly half of all women exceed the guideline recommended pregnancy weight gain for their Body Mass Index (BMI) category. Excessive gestational weight gain (GWG) is correlated positively with postpartum weight retention and is a predictor of long-term, higher BMI in mothers and their children. Psychosocial factors are generally not targeted in GWG behaviour change interventions, however, multifactorial, conceptual models that include these factors, may be useful in determining the pathways that contribute to excessive GWG. We propose a conceptual model, underpinned by health behaviour change theory, which outlines the psychosocial determinants of GWG, including the role of motivation and self-efficacy towards healthy behaviours. This model is based on a review of the existing literature in this area. there is increasing evidence to show that psychosocial factors, such as increased depressive symptoms, anxiety, lower self-esteem and body image dissatisfaction, are associated with excessive GWG. What is less known is how these factors might lead to excessive GWG. Our conceptual model proposes a pathway of factors that affect GWG, and may be useful for understanding the mechanisms by which interventions impact on weight management during pregnancy. This involves tracking the relationships among maternal psychosocial factors, including body image concerns, motivation to adopt healthy lifestyle behaviours, confidence in adopting healthy lifestyle behaviours for the purposes of weight management, and actual behaviour changes. health-care providers may improve weight gain outcomes in pregnancy if they assess and address psychosocial factors in pregnancy. Copyright © 2011 Elsevier Ltd. All rights reserved.

  15. Seepage weathering impacts on erosivity of arid stream banks: A new conceptual model

    Science.gov (United States)

    Nachshon, Uri

    2016-05-01

    Field observations have indicated the formation of horizontal, pipe shape cavities, along gully and dry stream channel banks in the semi-arid region of the northern Negev Desert, Israel. Piping is a well-known phenomenon in humid regions due to subsurface water flow and seepage weathering. However, in dry environments where rain events are scarce and subsurface water flow is rare, it is proposed here that capillary flow of saline water in the vadose zone leads to similar processes. It is suggested that where saline and shallow ground water persists, capillary flow may result in salt accumulation and precipitation at the top of the capillary fringe, consequently rendering this zone to be more susceptible to erosion. A conceptual model is presented and field observations, laboratory experiments, and a physically-based model are used to prove the feasibility of the proposed conceptual model and to explain why salts accumulate at the top of the capillary fringe, even though evaporation acts all along the vertical stream channel or gully banks. It is suggested that the low evaporative flux, in comparison to the liquid water flux, disables salt accumulation along the profile to the top of the capillary fringe where the liquid water flux is minimal. The presented findings strengthen the conceptual model, but thorough field studies are needed to estimate the impact of the proposed mechanism on erosion processes on a field scale.

  16. A conceptual model of HIV/AIDS stigma from five African countries.

    Science.gov (United States)

    Holzemer, William L; Uys, Leana; Makoae, Lucy; Stewart, Anita; Phetlhu, René; Dlamini, Priscilla S; Greeff, Minrie; Kohi, Thecla W; Chirwa, Maureen; Cuca, Yvette; Naidoo, Joanne

    2007-06-01

    This paper is a report on the development of a conceptual model delineating contexts and processes of HIV/AIDS stigma as reported by persons living with HIV/AIDS and nurses from African countries. It is part of a larger study to increase understanding of HIV/AIDS stigma. Researchers have defined stigma, explored determinants and outcomes of stigma and attempted to measure its multiple dimensions. This literature is difficult to synthesize, and often does not distinguish adequately between experiences of stigma and its causes and outcomes. Forty-three focus groups were held with persons living with HIV/AIDS and nurses in five African countries in 2004. Focus group recordings were transcribed and coded. The data were organized into a conceptual model of HIV/AIDS stigma. Two components were identified in the data: contextual factors--environment, healthcare system, agents--that influence and affect stigma and the stigma process itself. The stigma process included four dimensions: triggers of stigma, stigmatizing behaviours, types of stigma and the outcomes of stigma. A conceptual model is presented that delineates the dynamic nature of stigma as reported by study participants. The model may be used to identify areas appropriate for the design and testing of stigma reduction interventions that have a goal of reducing the burden of HIV/AIDS stigma.

  17. A Conceptual Modeling for a GoldSim Program for Safety Assessment of an LILW Repository

    International Nuclear Information System (INIS)

    Lee, Youn Myoung; Hwang, Yong Soo; Kang, Chul Hyung; Lee, Sung Ho

    2009-12-01

    Modeling study and development of a total system performance assessment (TSPA) program, by which an assessment of safety and performance for a low- and intermediate-level radioactive waste disposal repository with normal or abnormal nuclide release cases associated with the various FEPs involved in the performance of the proposed repository could be made has been carrying out by utilizing GoldSim under contract with KRMC. The report deals with a detailed conceptual modeling scheme by which a GoldSim program modules, all of which are integrated into a TSPA program as well as the input data set currently available. In-depth system models that are conceptually and rather practically described and then ready for implementing into a GoldSim program are introduced with plenty of illustrative conceptual models and sketches. The GoldSim program that will be finally developed through this project is expected to be successfully applied to the post closure safety assessment required both for the LILW repository and pyro processed repository by the regulatory body with both increased practicality and much reduced uncertainty

  18. Enabling new graduate midwives to work in midwifery continuity of care models: A conceptual model for implementation.

    Science.gov (United States)

    Cummins, Allison M; Catling, Christine; Homer, Caroline S E

    2017-12-04

    High-level evidence demonstrates midwifery continuity of care is beneficial for women and babies. Women have limited access to midwifery continuity of care models in Australia. One of the factors limiting women's access is recruiting enough midwives to work in continuity. Our research found that newly graduated midwives felt well prepared to work in midwifery led continuity of care models, were well supported to work in the models and the main driver to employing them was a need to staff the models. However limited opportunities exist for new graduate midwives to work in midwifery continuity of care. The aim of this paper therefore is to describe a conceptual model developed to enable new graduate midwives to work in midwifery continuity of care models. The findings from a qualitative study were synthesised with the existing literature to develop a conceptual model that enables new graduate midwives to work in midwifery continuity of care. The model contains the essential elements to enable new graduate midwives to work in midwifery continuity of care models. Each of the essential elements discussed are to assist midwifery managers, educators and new graduates to facilitate the organisational changes required to accommodate new graduates. The conceptual model is useful to show maternity services how to enable new graduate midwives to work in midwifery continuity of care models. Copyright © 2017 Australian College of Midwives. Published by Elsevier Ltd. All rights reserved.

  19. Investigation of metal ions sorption of brown peat moss powder

    Science.gov (United States)

    Kelus, Nadezhda; Blokhina, Elena; Novikov, Dmitry; Novikova, Yaroslavna; Chuchalin, Vladimir

    2017-11-01

    For regularities research of sorptive extraction of heavy metal ions by cellulose and its derivates from aquatic solution of electrolytes it is necessary to find possible mechanism of sorption process and to choice a model describing this process. The present article investigates the regularities of aliovalent metals sorption on brown peat moss powder. The results show that sorption isotherm of Al3+ ions is described by Freundlich isotherm and sorption isotherms of Na+ i Ni2+ are described by Langmuir isotherm. To identify the mechanisms of brown peat moss powder sorption the IR-spectra of the initial brown peat moss powder samples and brown peat moss powder samples after Ni (II) sorption were studied. Metal ion binding mechanisms by brown peat moss powder points to ion exchange, physical adsorption, and complex formation with hydroxyl and carboxyl groups.

  20. Investigation On Ethics In Public Sector Necessity Or Obligation Planning A Conceptual Model

    Directory of Open Access Journals (Sweden)

    N. Ghozat

    2015-06-01

    Full Text Available Abstract These All the objectives are attainable in line with ethics and if a system is not ethical in spite of scientific and modern facilities it cannot achieve its goals so the main duty of managers is to provide ground for morality since trustworthy morality are the fundamental axes in any system this article has tried to consider ethical issues according Islamic and Iranian values how should be the view point toward ethics in any system is it a necessity or obligation In this article we are to provide a conceptual model base on Iranian situation so our article which is a descriptive one uses multi sources of gathering data questionnaire interview to criticize the theoretical views based on western values and to offer a conceptual model.

  1. Interpersonal pattern dynamics and adaptive behavior in multiagent neurobiological systems: conceptual model and data.

    Science.gov (United States)

    Passos, Pedro; Araújo, Duarte; Davids, Keith; Gouveia, Luis; Serpa, Sidónio; Milho, João; Fonseca, Sofia

    2009-10-01

    Ecological dynamics characterizes adaptive behavior as an emergent, self-organizing property of interpersonal interactions in complex social systems. The authors conceptualize and investigate constraints on dynamics of decisions and actions in the multiagent system of team sports. They studied coadaptive interpersonal dynamics in rugby union to model potential control parameter and collective variable relations in attacker-defender dyads. A videogrammetry analysis revealed how some agents generated fluctuations by adapting displacement velocity to create phase transitions and destabilize dyadic subsystems near the try line. Agent interpersonal dynamics exhibited characteristics of chaotic attractors and informational constraints of rugby union boxed dyadic systems into a low dimensional attractor. Data suggests that decisions and actions of agents in sports teams may be characterized as emergent, self-organizing properties, governed by laws of dynamical systems at the ecological scale. Further research needs to generalize this conceptual model of adaptive behavior in performance to other multiagent populations.

  2. Conceptual Model for Mitigating Human – Wildlife Conflict based on System Thinking

    Science.gov (United States)

    Patana, Pindi; Mawengkang, Herman; Silvi Lydia, Maya

    2018-01-01

    In conservation process it is unavoidably that conflict incidents may occur among the people and wild-life in the surrounding of the conservation area. Mitigating conflict between wildlife and people is considered a top conservation priority, particularly in landscapes where high densities of people and wildlife co-occur. This conflict is also happened in Leuser conservation area located in the border of North Sumatra and Aceh province, Indonesia. Easing the conflict problem is very difficult. This paper proposes a conceptual model based on system thinking to explore factors that may have great influence on the conflict and to figure out mitigating the conflict. We show how this conceptual framework can be utilized to analyze the conflict occur and further how it could used to develop a multi- criteria decision model.

  3. Radicalization into Violent Extremism II: A Review of Conceptual Models and Empirical Research

    Directory of Open Access Journals (Sweden)

    Randy Borum

    2011-01-01

    Full Text Available Over the past decade, analysts have proposed several frameworks to explain the process of radicalization into violent extremism (RVE. These frameworks are based primarily on rational, conceptual models which are neither guided by theory nor derived from systematic research. This article reviews recent (post-9/11 conceptual models of the radicalization process and recent (post-9/11 empirical studies of RVE. It emphasizes the importance of distinguishing between ideological radicalization and terrorism involvement, though both issues deserve further empirical inquiry. Finally, it summarizes some recent RVE-related research efforts, identifies seven things that social science researchers and operational personnel still need to know about violent radicalization, and offers a set of starting assumptions to move forward with a research agenda that might help to thwart tomorrow's terrorists.

  4. Conceptual Model of Weight Management in Overweight and Obese African-American Females.

    Science.gov (United States)

    Sutton, Suzanne M; Magwood, Gayenell S; Nemeth, Lynne S; Jenkins, Carolyn M

    2017-04-01

    Weight management of overweight and obese (OWO) African-American females (AAFs) is a poorly defined concept, leading to ineffective treatment of overweight and obesity, prevention of health sequelae, and risk reduction. A conceptual model of the phenomenon of weight management in OWO AAFs was developed through dimensional analysis of the literature. Constructs were identified and sorted into the dimensions of perspective, context, conditions, process, and consequences and integrated into an explanatory matrix. Through dimensional analysis, weight management in OWO AAFs was characterized as a multidimensional concept, defined from the perspective of weight loss in community-dwelling AAFs. Behaviors associated with weight management are strongly influenced by intrinsic factors and extrinsic conditions, which influence engagement in the processes and consequences of weight management. The resulting conceptual model of weight management in OWO AAFs provides a framework for research interventions applicable in a variety of settings. © 2016 Wiley Periodicals, Inc.

  5. Tijeras Arroyo Groundwater Current Conceptual Model and Corrective Measures Evaluation Report - December 2016.

    Energy Technology Data Exchange (ETDEWEB)

    Copland, John R. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-03-01

    This Tijeras Arroyo Groundwater Current Conceptual Model and Corrective Measures Evaluation Report (CCM/CME Report) has been prepared by the U.S. Department of Energy (DOE) and Sandia Corporation (Sandia) to meet requirements under the Sandia National Laboratories-New Mexico (SNL/NM) Compliance Order on Consent (the Consent Order). The Consent Order, entered into by the New Mexico Environment Department (NMED), DOE, and Sandia, became effective on April 29, 2004. The Consent Order identified the Tijeras Arroyo Groundwater (TAG) Area of Concern (AOC) as an area of groundwater contamination requiring further characterization and corrective action. This report presents an updated Conceptual Site Model (CSM) of the TAG AOC that describes the contaminant release sites, the geological and hydrogeological setting, and the distribution and migration of contaminants in the subsurface. The dataset used for this report includes the analytical results from groundwater samples collected through December 2015.

  6. Development of a conceptual model of the role of hospital nurses in health promotion in Jordan.

    Science.gov (United States)

    Shoqirat, N

    2015-05-19

    International evidence reveals that hospital nurses have not been able to incorporate health promotion effectively into the framework of their care. This can be attributed to unclear conceptualizing of the barriers and facilitators to the role of nurses in health promotion. An integrative review was carried out to develop a conceptual model to assist hospital nurses in Jordan to understand how health promotion activities can be developed. Factors affecting the involvement of nurses in health promotion - ranging from limited knowledge about health promotion to the social image of nursing - can be structured into three levels: the micro (individual), meso (organizational) and macro (population). By understanding the interplay of factors between and within the levels, nurses and other health professionals can draw on the individual, social and organizational factors that influence nurses' role in health promotion. The proposed model can be considered as a springboard for developing health promotion activities related to hospitals in other Muslim-majority contexts.

  7. Conceptual data modeling on the KRR-1 and 2 decommissioning database

    International Nuclear Information System (INIS)

    Park, Hee Seoung; Park, Seung Kook; Lee, Kune Woo; Park, Jin Ho

    2002-01-01

    A study of the conceptual data modeling to realize the decommissioning database on the KRR-1 and 2 was carried out. In this study, the current state of the abroad decommissioning databased was investigated to make a reference of the database. A scope of the construction of decommissioning database has been set up based on user requirements. Then, a theory of the database construction was established and a scheme on the decommissioning information was classified. The facility information, work information, radioactive waste information, and radiological information dealing with the decommissioning database were extracted through interviews with an expert group and also decided upon the system configuration of the decommissioning database. A code which is composed of 17 bit was produced considering the construction, scheme and information. The results of the conceptual data modeling and the classification scheme will be used as basic data to create a prototype design of the decommissioning database

  8. Getting innovation out of suppliers? A conceptual model for characterizing supplier inputs to new product development

    OpenAIRE

    Lakemond, Nicolette; Rosell, David T.

    2011-01-01

    There are many studies on supplier collaborations in NPD. However, there is not much written about what suppliers actually contribute to innovation. Based on a literature review focusing on 80 articles we develop a conceptual framework categorizing different supplier inputs to innovation. This model is formulated by characterizing supplier inputs related to the component level and architectural level, and inputs that are incremental or radical in nature. On a component level, supplier inputs ...

  9. A conceptual model for the use of social media in companies

    OpenAIRE

    Nistor, Cristian

    2013-01-01

    Social media is currently an evolving “wave” in online business marketing. Marketers are beginning to drive the use of social media as a component in their marketing strategy and campaigns to reach out to customers and fans. Within the subdisciplines of marketing that may use social media include promotions, marketing intelligence, sentiments research, public relations, marketing communications and product and customer management. This paper will try to find a conceptual model ...

  10. A Conceptual Model of Knowledge Sharing and Market Orientation in the Tourism Sector

    OpenAIRE

    Chien M. Yeh; Han N. Hu; Shu H. Tsai

    2011-01-01

    Problem statement: Marketing scholars have emphasized the importance of market orientation. While a number of studies discover the positive influence of market orientation on a variety of organizations phenomena, the understanding of factors that facilitate market orientation is limited. This study develops a conceptual model in which knowledge sharing is proposed to be the antecedent to three perspectives of market orientation-customer orientation, competitor orientation ...

  11. Experimental study of strontium sorption on fissure filling material

    International Nuclear Information System (INIS)

    Eriksen, T.E.; Cui, Daqing

    1994-12-01

    We have carried out a comparative study of sorption and desorption of strontium in groundwater on separated magnetic and size fractions of fissure filling material taken from natural fissures in granitic rock. Complete reversibility of the sorption process was demonstrated by identical Freundlich isotherms, isotopic exchangeability and pH dependence of the distribution coefficients Rd. The sorption was found to be strongly pH dependent in the range 3-11. The pH effect can be accommodated in the sorption model by considering the surface areas and surface charges of the minerals in the fissure filling material. 20 refs, 9 figs, 3 tabs

  12. Conceptual framework of Tenaga Nasional Berhad (TNB) cost of service (COS) model

    Science.gov (United States)

    Zainudin, WNRA; Ishak, WWM; Sulaiman, NA

    2017-09-01

    One of Malaysia Electricity Supply Industry (MESI) objectives is to ensure Tenaga Nasional Berhad (TNB) economic viability based on a fair economic electricity pricing. In meeting such objective, a framework that investigates the effect of cost of service (COS) on revenue is in great need. This paper attempts to present a conceptual framework that illustrate the distribution of the COS among TNB’s various cost centres which are subsequently redistributed in varying quantities among all of its customer categories. A deep understanding on the concepts will ensure optimal allocation of COS elements between different sub activities of energy production processes can be achieved. However, this optimal allocation needs to be achieved with respect to the imposed TNB revenue constraint. Therefore, the methodology used for this conceptual approach is being modelled into four steps. Firstly, TNB revenue requirement is being examined to ensure the conceptual framework addressed the requirement properly. Secondly, the revenue requirement is unbundled between three major cost centres or business units consist of generation, transmission and distribution and the cost is classified based on demand, energy and customers related charges. Finally, the classified costs are being allocated to different customer categories i.e. Household, Commercial, and Industrial. In summary, this paper proposed a conceptual framework on the cost of specific services that TNB currently charging its customers and served as potential input into the process of developing revised electricity tariff rates. On that purpose, the finding of this COS study finds cost to serve customer varies with the voltage level that customer connected to, the timing and the magnitude of customer demand on the system. This COS conceptual framework could potentially be integrated into a particular tariff structure and serve as a useful tool for TNB.

  13. Conceptual ecological models to support detection of ecological change on Alaska National Wildlife Refuges

    Science.gov (United States)

    Woodward, Andrea; Beever, Erik A.

    2011-01-01

    More than 31 million hectares of land are protected and managed in 16 refuges by the U.S. Fish and Wildlife Service (USFWS) in Alaska. The vastness and isolation of Alaskan refuges give rise to relatively intact and complete ecosystems. The potential for these lands to provide habitat for trust species is likely to be altered, however, due to global climate change, which is having dramatic effects at high latitudes. The ability of USFWS to effectively manage these lands in the future will be enhanced by a regional inventory and monitoring program that integrates and supplements monitoring currently being implemented by individual refuges. Conceptual models inform monitoring programs in a number of ways, including summarizing important ecosystem components and processes as well as facilitating communication, discussion and debate about the nature of the system and important management issues. This process can lead to hypotheses regarding future changes, likely results of alternative management actions, identification of monitoring indicators, and ultimately, interpretation of monitoring results. As a first step towards developing a monitoring program, the 16 refuges in Alaska each created a conceptual model of their refuge and the landscape context. Models include prominent ecosystem components, drivers, and processes by which components are linked or altered. The Alaska refuge system also recognizes that designing and implementing monitoring at regional and ecoregional extents has numerous scientific, fiscal, logistical, and political advantages over monitoring conducted exclusively at refuge-specific scales. Broad-scale monitoring is particularly advantageous for examining phenomena such as climate change because effects are best interpreted at broader spatial extents. To enable an ecoregional perspective, a rationale was developed for deriving ecoregional boundaries for four ecoregions (Polar, Interior Alaska, Bering Coast, and North Pacific Coast) from the

  14. The Persuasion Model of conceptual change and its application to misconceptions in evolution

    Science.gov (United States)

    Garner, Joanna Kate

    Previous work has attempted to account for the factors involved in conceptual change (e.g. Posner, Strike, Hewson & Gertzog, 1982; Pintrich, Marx & Boyle, 1993). While progress has been made, cognitive restructuring remains to be positioned within a unifying theory of change. Here, a new model of conceptual change is put forward. The Persuasion Model of conceptual change builds on previous frameworks (Posner, Strike, Hewson & Gertzog, 1982; Pintrich, Marx & Boyle, 1993; Vosniadou, 1994) including the psychology of persuasion (Heuristic-Systematic Model, Chaiken, 1980; Elaboration Likelihood Model, Petty & Cacioppo, 1986; Social Judgement Theory, Sherif & Hovland, 1953) and cognitive and motivational theories of learning (Johnson-Laird, 1983; Mayer & Moreno, 1988; Wittrock, 1974b). High quality, elaborative processing of a persuasive message leads to change. Mental models are positioned as the mechanism by which meaning is created, manipulated, inspected and evaluated. These processes result in a continuum of cognitive restructuring. A study of conceptual change in Evolutionary Biology examined the viability of the Persuasion Model. It was predicted that knowledge, beliefs, interest and cognitive style would predict elaborative processing. Processing was hypothesized to influence information comprehensibility, plausibility, fruitfulness and compatibility with prior knowledge. Judgments were hypothesized to influence learning outcomes. Evolutionary knowledge and beliefs were assessed at pre- and posttest in 375 college students using multiple choice, likert-scale and extended response items. Need for Cognition, Need for Cognitive Closure, Epistemological Beliefs, Religiosity, Dogmatism, Moral Values and Argument Evaluation Ability were measured using paper-and-pencil questionnaires. Participants read a text and indicated elaborative processing and information evaluation. Ninety percent of participants held at least one misconception at pre-test. Significant gains on

  15. Evaluating and Refining the Conceptual Model Used in the Study of Health and Activity in Preschool Environments (SHAPES) Intervention.

    Science.gov (United States)

    Saunders, Ruth P; Pfeiffer, Karin; Brown, William H; Howie, Erin K; Dowda, Marsha; O'Neill, Jennifer R; McIver, Kerry; Pate, Russell R

    2017-12-01

    This study investigated the utility of the Study of Health and Activity in Preschool Environments (SHAPES) conceptual model, which targeted physical activity (PA) behavior in preschool children, by examining the relationship between implementation monitoring data and child PA during the school day. We monitored implementation completeness and fidelity based on multiple elements identified in the conceptual model. Comparing high-implementing, low-implementing, and control groups revealed no association between implementation and outcomes. We performed post hoc analyses, using process data, to refine our conceptual model's depiction of an effective preschool PA-promoting environment. Results suggest that a single component of the original four-component conceptual model, providing opportunities for moderate-to-vigorous physical activity through recess for 4-year-old children in preschool settings, may be a good starting place for increasing moderate-to-vigorous physical activity. Interventions that are implemented with optimal levels of completeness and fidelity are more likely to achieve behavior change if they are based on accurate conceptual models. Examining the mechanisms through which an intervention produces its effects, as articulated in the conceptual model that guides it, is particularly important for environmentally focused interventions because they are guided by emerging frameworks. The results of this study underscore the utility of using implementation monitoring data to examine the conceptual model on which the intervention is based.

  16. An updated conceptual model of Delta Smelt biology: Our evolving understanding of an estuarine fish

    Science.gov (United States)

    Baxter, Randy; Brown, Larry R.; Castillo, Gonzalo; Conrad, Louise; Culberson, Steven D.; Dekar, Matthew P.; Dekar, Melissa; Feyrer, Frederick; Hunt, Thaddeus; Jones, Kristopher; Kirsch, Joseph; Mueller-Solger, Anke; Nobriga, Matthew; Slater, Steven B.; Sommer, Ted; Souza, Kelly; Erickson, Gregg; Fong, Stephanie; Gehrts, Karen; Grimaldo, Lenny; Herbold, Bruce

    2015-01-01

    The main purpose of this report is to provide an up-to-date assessment and conceptual model of factors affecting Delta Smelt (Hypomesus transpacificus) throughout its primarily annual life cycle and to demonstrate how this conceptual model can be used for scientific and management purposes. The Delta Smelt is a small estuarine fish that only occurs in the San Francisco Estuary. Once abundant, it is now rare and has been protected under the federal and California Endangered Species Acts since 1993. The Delta Smelt listing was related to a step decline in the early 1980s; however, population abundance decreased even further with the onset of the “pelagic organism decline” (POD) around 2002. A substantial, albeit short-lived, increase in abundance of all life stages in 2011 showed that the Delta Smelt population can still rebound when conditions are favorable for spawning, growth, and survival. In this report, we update previous conceptual models for Delta Smelt to reflect new data and information since the release of the last synthesis report about the POD by the Interagency Ecological Program for the San Francisco Estuary (IEP) in 2010. Specific objectives include:

  17. Comparison of a Conceptual Groundwater Model and Physically Based Groundwater Mode

    Science.gov (United States)

    Yang, J.; Zammit, C.; Griffiths, J.; Moore, C.; Woods, R. A.

    2017-12-01

    Groundwater is a vital resource for human activities including agricultural practice and urban water demand. Hydrologic modelling is an important way to study groundwater recharge, movement and discharge, and its response to both human activity and climate change. To understand the groundwater hydrologic processes nationally in New Zealand, we have developed a conceptually based groundwater flow model, which is fully integrated into a national surface-water model (TopNet), and able to simulate groundwater recharge, movement, and interaction with surface water. To demonstrate the capability of this groundwater model (TopNet-GW), we applied the model to an irrigated area with water shortage and pollution problems in the upper Ruamahanga catchment in Great Wellington Region, New Zealand, and compared its performance with a physically-based groundwater model (MODFLOW). The comparison includes river flow at flow gauging sites, and interaction between groundwater and river. Results showed that the TopNet-GW produced similar flow and groundwater interaction patterns as the MODFLOW model, but took less computation time. This shows the conceptually-based groundwater model has the potential to simulate national groundwater process, and could be used as a surrogate for the more physically based model.

  18. Development and testing of a fast conceptual river water quality model.

    Science.gov (United States)

    Keupers, Ingrid; Willems, Patrick

    2017-04-15

    Modern, model based river quality management strongly relies on river water quality models to simulate the temporal and spatial evolution of pollutant concentrations in the water body. Such models are typically constructed by extending detailed hydrodynamic models with a component describing the advection-diffusion and water quality transformation processes in a detailed, physically based way. This approach is too computational time demanding, especially when simulating long time periods that are needed for statistical analysis of the results or when model sensitivity analysis, calibration and validation require a large number of model runs. To overcome this problem, a structure identification method to set up a conceptual river water quality model has been developed. Instead of calculating the water quality concentrations at each water level and discharge node, the river branch is divided into conceptual reservoirs based on user information such as location of interest and boundary inputs. These reservoirs are modelled as Plug Flow Reactor (PFR) and Continuously Stirred Tank Reactor (CSTR) to describe advection and diffusion processes. The same water quality transformation processes as in the detailed models are considered but with adjusted residence times based on the hydrodynamic simulation results and calibrated to the detailed water quality simulation results. The developed approach allows for a much faster calculation time (factor 10 5 ) without significant loss of accuracy, making it feasible to perform time demanding scenario runs. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. A hybrid conceptual-fuzzy inference streamflow modelling for the Letaba River system in South Africa

    Science.gov (United States)

    Katambara, Zacharia; Ndiritu, John G.

    There has been considerable water resources developments in South Africa and other regions in the world in order to meet the ever-increasing water demands. These developments have not been matched with a similar development of hydrological monitoring systems and hence there is inadequate data for managing the developed water resources systems. The Letaba River system ( Fig. 1) is a typical case of such a system in South Africa. The available water on this river is over-allocated and reliable daily streamflow modelling of the Letaba River that adequately incorporates the main components and processes would be an invaluable aid to optimal operation of the system. This study describes the development of a calibrated hybrid conceptual-fuzzy-logic model and explores its capability in reproducing the natural processes and human effects on the daily stream flow in the Letaba River. The model performance is considered satisfactory in view of the complexity of the system and inadequacy of relevant data. Performance in modelling streamflow improves towards the downstream and matches that of a stand-alone fuzzy-logic model. The hybrid model obtains realistic estimates of the major system components and processes including the capacities of the farm dams and storage weirs and their trajectories. This suggests that for complex data-scarce River systems, hybrid conceptual-fuzzy-logic modelling may be used for more detailed and dependable operational and planning analysis than stand-alone fuzzy modelling. Further work will include developing and testing other hybrid model configurations.

  20. A conceptual model of psychosomatic illness in children. Family organization and family therapy.

    Science.gov (United States)

    Minuchin, S; Baker, L; Rosman, B L; Liebman, R; Milman, L; Todd, T C

    1975-08-01

    Linear and open systems (multiple feedback) models of psychosomatic illness in children are contrasted in terms of their implications for cause and treatment. An open systems family model is presented that describes three necessary (but not independently sufficient) conditions for the development and maintenance of severe psychosomatic problems in children: (1) a certain type of family organization that encourages somatization; (2) involvement of the child in parental conflict; and (3) physiological vulnerability. Predisposition for psychosomatic illness, symptom choice, and maintenance are discussed within this conceptual framework. We report on family therapy strategies based on this model and the results of family treatment with 48 cases of "brittle" diabetes, psychosomatic asthma, and anorexia nervosa.

  1. Apparel shopping behaviour – Part 1: Towards the development of a conceptual theoretical model

    Directory of Open Access Journals (Sweden)

    R Du Preez

    2003-10-01

    Full Text Available Apparel shopping behaviour in a multicultural society is a complex phenomenon. The objective of this paper is to analyse various theoretical models from two disciplines, namely Consumer Behaviour and Clothing, and to develop a new conceptual theoretical model focussing on variables influencing apparel shopping behaviour in a multicultural consumer society. Variables were presented as market dominated, consumer dominated, and/or market and consumer interaction variables. Retailers, marketers, educators, researchers and students could benefit from the proposed model and recommendations are made in this regard. Part 2 reports on an empirical study based on the proposed conceptual theoretical model and discusses market segments and profiles. Opsomming Klere-aankoopgedrag in ’n multi-kulturele verbruikersamelewing is ’n komplekse fenomeen. Die doelwit van die artikel is om verskeie teoretiese modelle vanuit twee dissiplines, naamlik Verbruikersielkunde en Kleding, te analiseer. ’n Nuwe konseptuele teoretiese model is ontwikkel. Die model fokus op veranderlikes wat klereaankoopgedrag in ’n multi-kulturele verbruikersamelewing beïnvloed. Veranderlikes word gegroepeer op grond van die mate waartoe dit oorheers word deur die mark, verbruiker en/of die interaksie tussen die mark en die verbruiker. Kleinhandelaars, bemarkers, opvoeders, navorsers en studente sou kon voordeel trek uit die voorgestelde model. Aanbevelings word in dié verband gemaak. In Deel 2 word ’n empiriese studie gerapporteer. Dié studie is op hierdie voorgestelde konseptuele teoretiese model gegrond en marksegmente sowel as profiele word bespreek.

  2. A Conceptual Space Logic

    DEFF Research Database (Denmark)

    Nilsson, Jørgen Fischer

    1999-01-01

    Conceptual spaces have been proposed as topological or geometric means for establishing conceptual structures and models. This paper, after briey reviewing conceptual spaces, focusses on the relationship between conceptual spaces and logical concept languages with operations for combining concepts...... to form concepts. Speci cally is introduced an algebraic concept logic, for which conceptual spaces are installed as semantic domain as replacement for, or enrichment of, the traditional....

  3. Technetium Sorption By Cementitious Materials Under Reducing Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Kaplan, Daniel I. [Savannah River National Lab., Aiken, SC (United States); Estes, Shanna L. [Clemson Univ., SC (United States). Environmental Engineering and Earth Sciences; Arai, Yuji [Clemson Univ., SC (United States). College of Agriculture, Forestry and Life Sciences; Powell, Brian A. [Clemson Univ., SC (United States). Environmental Engineering and Earth Sciences

    2013-07-18

    The objective of this study was to measure Tc sorption to cementitious materials under reducing conditions to simulate Saltstone Disposal Facility conditions. Earlier studies were conducted and the experimental conditions were found not to simulate those of the facility. Through a five month subcontract with Clemson University, sorption of {sup 99}Tc to four cementitious materials was examined within an anaerobic glovebag targeting a 0.1% H{sub 2}(g)/ 99.9% N{sub 2}(g) atmosphere. Early experiments based on Tc sorption and Eh indicated that 0.1% H{sub 2}(g) (a reductant) was necessary to preclude experimental impacts from O{sub 2}(g) diffusion into the glovebag. Preliminary data to date (up to 56 days) indicates that sorption of {sup 99}Tc to cementitious materials increased with increasing slag content for simulated saltstone samples. This is consistent with the conceptual model that redox active sulfide groups within the reducing slag facilitate reduction of Tc(VII) to Tc(IV). These experiments differ from previous experiments where a 2% H{sub 2}(g) atmosphere was maintained (Kaplan et al., 2011 (SRNL-STI-2010-00668)). The impact of the 2% H{sub 2}(g) reducing atmosphere on this data was examined and determined to cause the reduction of Tc in experimental samples without slag. In the present ongoing study, after 56 days, Tc sorption by the 50-year old cement samples (no slag) was undetectable, whereas Tc sorption in the cementitious materials containing slag continues to increase with contact time (measured after 1, 4, 8, 19 and 56 days). Sorption was not consistent with spike concentrations and steady state has not been demonstrated after 56 days. The average conditional K{sub d} value for the Vault 2 cementitious material was 873 mL/g (17% slag), for the TR547 Saltstone (45% slag) the conditional K{sub d} was 168 mL/g, and for TR545 (90% slag) the conditional K{sub d} was 1,619 mL/g. It is anticipated that additional samples will be collected until steady state

  4. A conceptual definition of vocational rehabilitation based on the ICF: building a shared global model.

    Science.gov (United States)

    Escorpizo, Reuben; Reneman, Michiel F; Ekholm, Jan; Fritz, Julie; Krupa, Terry; Marnetoft, Sven-Uno; Maroun, Claude E; Guzman, Julietta Rodriguez; Suzuki, Yoshiko; Stucki, Gerold; Chan, Chetwyn C H

    2011-06-01

    The International Classification of Functioning, Disability and Health (ICF) is a conceptual framework and classification system by the World Health Organization (WHO) to understand functioning. The objective of this discussion paper is to offer a conceptual definition for vocational rehabilitation (VR) based on the ICF. We presented the ICF as a model for application in VR and the rationale for the integration of the ICF. We also briefly reviewed other work disability models. Five essential elements of foci were found towards a conceptual definition of VR: an engagement or re-engagement to work, along a work continuum, involved health conditions or events leading to work disability, patient-centered and evidence-based, and is multi-professional or multidisciplinary. VR refers to a multi-professional approach that is provided to individuals of working age with health-related impairments, limitations, or restrictions with work functioning and whose primary aim is to optimize work participation. We propose that the ICF and VR interface be explored further using empirical and qualitative works and encouraging stakeholders' participation.

  5. A conceptual model of how US families with athletic adolescent daughters manage food and eating.

    Science.gov (United States)

    Travis, Susan; Bisogni, Carole; Ranzenhofer, Lisa

    2010-02-01

    Health professionals concerned about the risks of adolescent obesity and disordered eating practices need greater understanding of how families with adolescents manage food in today's fast paced environment. This paper sought to gain conceptual understanding of the food and eating routines of families with a female adolescent athlete from the perspectives of mothers and daughters. Ten white, non-Hispanic mothers and their daughters were purposively sampled from high school track and cross country teams in Upstate New York. Informants completed in-depth, qualitative interviews. Researchers used the constant comparative method to analyze transcripts for emergent themes and to build a conceptual framework that represented the many factors and processes involved in the construction of family food routines. Families varied in forms and patterns of family eating activities with mothers playing a pivotal role in these routines. Family members' individual needs and values were negotiated in constructing these routines. In this sample the daughters' involvement in sports influenced family eating routines, but mothers' employment, ethnicity, social support, income, and areas of residence also played a role. The model describes how individual participants' food choice processes interact to produce family food routines. The conceptual model can inform research and practice related to the family environments in which adolescents experience food and eating. 2009 Elsevier Ltd. All rights reserved.

  6. Intention to Purchase Products under Volume Discount Scheme: A Conceptual Model and Research Propositions

    Directory of Open Access Journals (Sweden)

    Mohammad Iranmanesh

    2014-12-01

    Full Text Available Many standard brands sell products under the volume discount scheme (VDS as more and more consumers are fond of purchasing products under this scheme. Despite volume discount being commonly practiced, there is a dearth of research, both conceptual and empirical, focusing on purchase characteristics factors and consumer internal evaluation concerning the purchase of products under VDS. To attempt to fill this void, this article develops a conceptual model on VDS with the intention of delineating the influence of the purchase characteristics factors on the consumer intention to purchase products under VDS and provides an explanation of their effects through consumer internal evaluation. Finally, the authors discuss the managerial implications of their research and offer guidelines for future empirical research.

  7. COPEWELL: A Conceptual Framework and System Dynamics Model for Predicting Community Functioning and Resilience After Disasters.

    Science.gov (United States)

    Links, Jonathan M; Schwartz, Brian S; Lin, Sen; Kanarek, Norma; Mitrani-Reiser, Judith; Sell, Tara Kirk; Watson, Crystal R; Ward, Doug; Slemp, Cathy; Burhans, Robert; Gill, Kimberly; Igusa, Tak; Zhao, Xilei; Aguirre, Benigno; Trainor, Joseph; Nigg, Joanne; Inglesby, Thomas; Carbone, Eric; Kendra, James M

    2018-02-01

    Policy-makers and practitioners have a need to assess community resilience in disasters. Prior efforts conflated resilience with community functioning, combined resistance and recovery (the components of resilience), and relied on a static model for what is inherently a dynamic process. We sought to develop linked conceptual and computational models of community functioning and resilience after a disaster. We developed a system dynamics computational model that predicts community functioning after a disaster. The computational model outputted the time course of community functioning before, during, and after a disaster, which was used to calculate resistance, recovery, and resilience for all US counties. The conceptual model explicitly separated resilience from community functioning and identified all key components for each, which were translated into a system dynamics computational model with connections and feedbacks. The components were represented by publicly available measures at the county level. Baseline community functioning, resistance, recovery, and resilience evidenced a range of values and geographic clustering, consistent with hypotheses based on the disaster literature. The work is transparent, motivates ongoing refinements, and identifies areas for improved measurements. After validation, such a model can be used to identify effective investments to enhance community resilience. (Disaster Med Public Health Preparedness. 2018;12:127-137).

  8. Analysis of Economic Burden of Seasonal Influenza: An Actuarial Based Conceptual Model

    Directory of Open Access Journals (Sweden)

    S. S. N. Perera

    2017-01-01

    Full Text Available Analysing the economic burden of the seasonal influenza is highly essential due to the large number of outbreaks in recent years. Mathematical and actuarial models can be considered as management tools to understand the dynamical behavior, predict the risk, and compute it. This study is an attempt to develop conceptual model to investigate the economic burden due to seasonal influenza. The compartment SIS (susceptible-infected-susceptible model is used to capture the dynamical behavior of influenza. Considering the current investment and future medical care expenditure as premium payment and benefit (claim, respectively, the insurance and actuarial based conceptual model is proposed to model the present economic burden due to the spread of influenza. Simulation is carried out to demonstrate the variation of the present economic burden with respect to model parameters. The sensitivity of the present economic burden is studied with respect to the risk of disease spread. The basic reproduction is used to identify the risk of disease spread. Impact of the seasonality is studied by introducing the seasonally varying infection rate. The proposed model provides theoretical background to investigate the economic burden of seasonal influenza.

  9. Conceptual Models for the Fracture Network in Contaminated Shale Based on Different Lines of Evidence

    Science.gov (United States)

    Parker, B. L.; Chapman, S.; Cherry, J. A.

    2009-05-01

    In investigations of groundwater flow in fractured sedimentary rock, there is typically a large discrepancy between the number of fractures identified by different methods in boreholes. The methods directed at fracture geometry such as inspection of continuous core and borehole imaging (acoustic, optical, electrical televiewing, borehole camera, etc.) commonly identify numerous fractures. In contrast, the methods that infer fractures from measurements in the open borehole water column (borehole flow meters, temperature, electrical conductance, full borehole dilution) show far fewer fractures. These two different categories of data support two very different conceptual models for the fracture networks in which groundwater flow occurs. A study was conducted at a contaminated industrial site in an area of approximately 150m by 100m located on a fractured Ordovician shale in New York State where a fracture network conceptual model was initially developed based primarily on borehole flow metering and related cross-borehole hydraulic tests. In this conceptual model based on eight boreholes having a maximum depth of 50 m, the total number of flow zones identified was 14 over 140 m of open hole and ranged from none to five per hole. PCE DNAPL released decades ago has caused substantial VOC contamination (PCE, TCE, cis-DCE, and VC) and this contamination was delineated by means of a large number of contaminant analyses on samples from continuous rock core at an average spacing of 0.3 m. Although groundwater flow occurs almost entirely in the fractures, almost all the contaminant mass resides in the rock matrix (porosity 2-5%) because of long term diffusion-driven mass transfer from fractures to the matrix. The rock core contaminant profiles indicate that advective transport has occurred over decades through numerous fractures in each borehole. Therefore, many of the fractures identified from corelogs and televiewing must have active groundwater flow. This supports a

  10. Radionuclide sorption from the safety evaluation perspective

    International Nuclear Information System (INIS)

    1992-01-01

    Research and development directed towards the assessment of the long-term performance of radioactive waste disposal systems has been recognised as a priority area with a strong need for international co-operation and co-ordination. The ultimate aims is to promote the quality and credibility of safety assessment techniques for radioactive waste disposal. Sorption in the geosphere is one of the key processes for retarding the transport of radionuclide from the underground disposal facility to the biosphere. In many cases, sorption in the near field and in the biosphere is also important. A workshop, organised to favor discussion around a small number of invited papers, was held in October 1991: - to evaluate critically the way sorption processes are incorporated in performance assessment models; - to identify open issues of high priority, and; - to propose future activities to resolve these issues. These proceedings reproduce the invited papers and the conclusions and recommendations adopted by the workshop. Eight papers are in the INIS SCOPE. The main subjects studied are: sorption database comparison, sorption database development and three case studies, experimental techniques, adsorption models

  11. Sorption of tylosin on clay minerals.

    Science.gov (United States)

    Zhang, Qian; Yang, Chen; Huang, Weilin; Dang, Zhi; Shu, Xiaohua

    2013-11-01

    The equilibrium sorption of tylosin (TYL) on kaolinite and montmorillonite was measured at different solution pH using batch reactor systems. The results showed that all the sorption isotherms were nonlinear and that the nonlinearity decreased as the solution pH increased for a given clay. At a specific aqueous concentration, the single-point sorption distribution coefficient (KD) of TYL decreased rapidly as the solution pH increased. A speciation-dependent sorption model that accounted for the contributions of the cationic and neutral forms of TYL fit the data well, suggesting that the sorption may be dominated by both ion exchange and hydrophobic interactions. The isotherm data also fit well to a dual mode model that quantifies the contributions of a site-limiting Langmuir component (ion exchange) and a non-specific linear partitioning component (hydrophobic interactions). X-ray diffraction analyses revealed that the interlayers of montmorillonite were expanded due to the uptake of TYL. TYL molecules likely form a monolayer surface coverage. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Structure and use of conceptual models in the Aespoe site investigations

    International Nuclear Information System (INIS)

    Gustafsson, Gunnar

    1998-01-01

    Early in the Aespoe project a need for structuring and clarification of the models used for different purposes was identified. The problem lied not in the numerical codes or the data base used for the modelling but rather in the process of how the real world was conceptualized into descriptive and predictive models. A proposal on how to structure these conceptual assumptions was made on which a standardised representation of used models was worked out. An essential objective has been to condensate the model descriptions to one page and still present the essential aspects of each model. It is hoped that in this way it is easier to obtain an overview of the assumptions underlying each model and facilitate comparison between different models. The base for the description is the 'intended use of the model'. Based on the intended use the next step is to identify what 'physical' processes should be included in the model. In some cases these processes can be represented by constitutive equations. The next step is to define the 'concepts' needed to solve the problem. The concepts may be separated into four groups. Firstly, the type of 'geometrical framework' and the framework-related parameters have to be defined. Secondly, the type of 'material properties' to be assigned to the domains defined by the geometrical framework must be decided. Thirdly, the 'spatial assignment method' of the material properties within a domain has to be described. Finally, the model normally has a limited extent and the 'boundary conditions' have to be defined to compute or judge the effects within the model. For a real case the data can now be defined for the four groups of concepts by analysing measurements representing the actual case. If needed a 'numerical or mathematical tool' that handles the processes and concepts should the be chosen. 'Output parameters' of interest for model purposes must then be defined

  13. SITE-94. The SKN conceptual model of Aespoe. Based on pre-investigations 1986-1990

    International Nuclear Information System (INIS)

    Sundquist, U.; Torssander, P.

    1996-12-01

    The present report describes the SKN (National Board for Spent Nuclear Fuel) conceptual model, which is a combined structural, hydrogeological and geochemical model. The development of the model has been carried out by stages with commencement in 1990. This report summarizes the main parts of the work performed. Initially, the development of the model was part of the program of SKN regarding review of SKB R and D work at Aespoe Hard Rock Laboratory. At a later stage, the SKN model was further developed and integrated into SITE-94. This development comprised evaluation of additional hydrogeological and geochemical data in order to strengthen the model. This report summarizes two earlier reports by SKN written in Swedish. Furthermore, a comprehensive description of the hydrogeological and geochemical evaluation is presented. 58 refs

  14. Status report on SIRS: sorption information retrieval system

    Energy Technology Data Exchange (ETDEWEB)

    Hostetler, D.D.; Serne, R.J.; Baldwin, A.J.; Petrie, G.M.

    1980-11-01

    Two major uses were identified for the Sorption Information Retrieval System: (1) to aid geochemists in the elucidation of sorption mechanisms; and (2) to aid safety assessment modelers in selection of Kds for any given scenerio. Other benefits such as providing an auditable vehicle for the Kd selection were also discussed.

  15. Status report on SIRS: sorption information retrieval system

    International Nuclear Information System (INIS)

    Hostetler, D.D.; Serne, R.J.; Baldwin, A.J.; Petrie, G.M.

    1980-11-01

    Two major uses were identified for the Sorption Information Retrieval System: (1) to aid geochemists in the elucidation of sorption mechanisms; and (2) to aid safety assessment modelers in selection of Kds for any given scenerio. Other benefits such as providing an auditable vehicle for the Kd selection were also discussed

  16. Empirical evaluation of the conceptual model underpinning a regional aquatic long-term monitoring program using causal modelling

    Science.gov (United States)

    Irvine, Kathryn M.; Miller, Scott; Al-Chokhachy, Robert K.; Archer, Erik; Roper, Brett B.; Kershner, Jeffrey L.

    2015-01-01

    Conceptual models are an integral facet of long-term monitoring programs. Proposed linkages between drivers, stressors, and ecological indicators are identified within the conceptual model of most mandated programs. We empirically evaluate a conceptual model developed for a regional aquatic and riparian monitoring program using causal models (i.e., Bayesian path analysis). We assess whether data gathered for regional status and trend estimation can also provide insights on why a stream may deviate from reference conditions. We target the hypothesized causal pathways for how anthropogenic drivers of road density, percent grazing, and percent forest within a catchment affect instream biological condition. We found instream temperature and fine sediments in arid sites and only fine sediments in mesic sites accounted for a significant portion of the maximum possible variation explainable in biological condition among managed sites. However, the biological significance of the direct effects of anthropogenic drivers on instream temperature and fine sediments were minimal or not detected. Consequently, there was weak to no biological support for causal pathways related to anthropogenic drivers’ impact on biological condition. With weak biological and statistical effect sizes, ignoring environmental contextual variables and covariates that explain natural heterogeneity would have resulted in no evidence of human impacts on biological integrity in some instances. For programs targeting the effects of anthropogenic activities, it is imperative to identify both land use practices and mechanisms that have led to degraded conditions (i.e., moving beyond simple status and trend estimation). Our empirical evaluation of the conceptual model underpinning the long-term monitoring program provided an opportunity for learning and, consequently, we discuss survey design elements that require modification to achieve question driven monitoring, a necessary step in the practice of

  17. Sorption behaviour of W, Hf, Lu, U, and Th on ion exchangers from HCl/H2O2 solutions. Model experiments for chemical studies of seaborgium (Sg)

    International Nuclear Information System (INIS)

    Schumann, D.; Andrassy, M.; Nitsche, H.; Misiak, R.; Schaedel, M.; Bruechle, W.; Schausten, B.; Kratz, J.V.

    1997-08-01

    In model experiments with W, Hf, Th, and U radionuclides, a chemical system was developed for the separation of seaborgium from element 104 and heavy actinides, i.e., cation exchange on DOWEX 50 x 8 from solutions containing 0.1-1.0 M HCl and 0.5-2.0 vol.% H 2 O 2 . The system should be suitable for fast on-line experiments if seaborgium exibits a non-uranium-like behaviour. Adding hydrogen peroxide to mixed HCl/HF solutions suppresses the partial sorption of W and, presumably seaborgium, on the cation exchanger. This way, the elution volume can be minimized. Prospects for anion exchange separations of group 6 from 4 elements are also briefly discussed. (orig.)

  18. Sorption of nickel on chitosan

    International Nuclear Information System (INIS)

    Pivarciova, O.; Rosskopfova, O.; Galambos, M.

    2012-01-01

    This work was focused on the study of sorption properties of nickel on chitosan. Sorption of nickel on the selected sorbents was studied by batch method. Radionuclide 63 Ni was used as a tracer. Langmuir isotherm was used for interpretation of the sorption of nickel on chitosan by varying the concentration of Ni 2 + cations in aqueous phase.

  19. Evolution of the conceptual model of unsaturated zone hydrology at yucca mountain, nevada

    International Nuclear Information System (INIS)

    Flint, A. L.; Flint, L. E.; Bodvarsson, G. S.; Kwicklis, E. M.; Fabryka-Martin, J.

    2001-01-01

    Yucca Mountain is an arid site proposed for consideration as the United States' first underground high-level radioactive waste repository. Low rainfall (approximately 170 mm/yr) and a thick unsaturated zone (500-1000 m) are important physical attributes of the site because the quantity of water likely to reach the waste and the paths and rates of movement of the water to the saturated zone under future climates would be major factors in controlling the concentrations and times of arrival of radionuclides at the surrounding accessible environment. The framework for understanding the hydrologic processes that occur at this site and that control how quickly water will penetrate through the unsaturated zone to the water table has evolved during the past 15 yr. Early conceptual models assumed that very small volumes of water infiltrated into the bedrock (0.5-4.5 mm/yr, or 2-3 percent of rainfall), that much of the infiltrated water flowed laterally within the upper nonwelded units because o f capillary barrier effects, and that the remaining water flowed down faults with a small amount flowing through the matrix of the lower welded, fractured rocks. It was believed that the matrix had to be saturated for fractures to show. However, accumulating evidence indicated that infiltration rates were higher than initially estimated, such as infiltration modeling based on neutron borehole data, bomb-pulse isotopes deep in the mountain, perched water analyses and thermal analyses. Mechanisms supporting lateral diversion did not apply at these higher fluxes, and the flux calculated in the lower welded unit exceeded the conductivity of the matrix, implying vertical flow of water into the high permeability fractures of the potential repository host rock, and disequilibrium between matrix and fracture water potentials. The development of numerical modeling methods and parameter values evolved concurrently with the conceptual model in order to account for the observed field data

  20. Sorption and desorption of 17α-ethinylestradiol onto sediments affected by rhamnolipidic biosurfactants.

    Science.gov (United States)

    Guo, Yan-Ping; Hu, Yong-You; Lin, Hui; Ou, Xue-Lian

    2018-02-15

    Many studies have addressed the desorption and mobilization performances of sorbed contaminants affected by different rhamnolipidic biosurfactants. Study results have been mixed and complicated. Rhamnolipids are always microbial produced with variable homologues. In this study, two representative rhamnolipidic fractions (i.e., RL-F1 and RL-F2, which are mono- and di-rhamnolipids, respectively) were investigated and compared to determine their influence on 17α-ethynylestradiol (EE2) distribution within sediment-water sorption and desorption systems. In general, the coexistence of RL-F1 and EE2 enhanced EE2 sorption in a wider monorhamnolipidic dosage range when freshly treated sorbate was used. The sorbed EE2 concentration decreased as the RL-F1 dosage increased in the aged sorbate desorption systems. However, RL-F2 facilitated EE2 mobilization in both sorption and desorption processes. Experimental data were estimated using a conceptual model that considered the sorbed rhamnolipids and aqueous micelles for organic partitioning. The model results indicated that the rhamnolipid type is an important factor influencing organic distribution, in addition to sorbate aging process and sediment characteristics. The use of a rhamnolipidic mixture containing both mono- and di-rhamnosyl components may not achieve the desired effect when the biosurfactant-enhanced mobilization or immobilization approach is selected. These results are significant for selecting and applying rhamnolipids to remediate contaminants. Copyright © 2017. Published by Elsevier B.V.

  1. Rubber airplane: Constraint-based component-modeling for knowledge representation in computer-aided conceptual design

    Science.gov (United States)

    Kolb, Mark A.

    1990-01-01

    Viewgraphs on Rubber Airplane: Constraint-based Component-Modeling for Knowledge Representation in Computer Aided Conceptual Design are presented. Topics covered include: computer aided design; object oriented programming; airfoil design; surveillance aircraft; commercial aircraft; aircraft design; and launch vehicles.

  2. Sorption of 3,3',4,4'-tetrachlorobiphenyl by microplastics: A case study of polypropylene.

    Science.gov (United States)

    Zhan, Zhiwei; Wang, Jundong; Peng, Jinping; Xie, Qilai; Huang, Ying; Gao, Yifan

    2016-09-15

    Though plastics show good chemical inertness, they could sorb polychlorinated biphenyls (PCBs) and other toxic pollutants from the surrounding environment. Thus, ingestion of microplastics by marine organisms potentially enhances the transport and bioavailability of toxic chemicals. However, there is lack of studies on the sorption capacity, mechanism and factors affecting the sorption behavior. Here, sorption of PCBs by microplastics in the simulated seawater was studied using the batch oscillation equilibration technique, in which polypropylene (PP) and 3,3',4,4'-tetrachlorobiphenyl (PCB77) acted as model plastic and PCB, respectively. Factors including particle size, temperature and solution environment were investigated. Results showed that, equilibrium sorption time is about 8h and sorption capacity increase with decreasing particle size and temperature. Different sorption capacity in three solution environments was observed. Equilibrium data in three solution environments fitted very well to the Langmuir sorption model, indicating chemical sorption is the predominant mechanism. Copyright © 2016 Elsevier Ltd. All rights reserved.

  3. Enhancing climate literacy through the use of an interdisciplinary global change framework and conceptual models

    Science.gov (United States)

    Bean, J. R.; Zoehfeld, K.; Mitchell, K.; Levine, J.; White, L. D.

    2016-12-01

    Understanding climate change and how to mitigate the causes and consequences of anthropogenic activities are essential components of the Next Generations Science Standards. To comprehend climate change today and why current rates and magnitudes of change are of concern, students must understand the various factors that drive Earth system processes and also how they interrelate. The Understanding Global Change web resource in development from the UC Museum of Paleontology will provide science educators with a conceptual framework, graphical models, lessons, and assessment templates for teaching NGSS aligned, interdisciplinary, climate change curricula. To facilitate students learning about the Earth as a dynamic, interacting system of ongoing processes, the Understanding Global Change site will provide explicit conceptual links for the causes of climate change (e.g., burning of fossil fuels, deforestation), Earth system processes (e.g., Earth's energy budget, water cycle), and the changes scientists measure in the Earth system (e.g., temperature, precipitation). The conceptual links among topics will be presented in a series of storyboards that visually represent relationships and feedbacks among components of the Earth system and will provide teachers with guides for implementing NGSS-aligned climate change instruction that addresses physical science, life sciences, Earth and space science, and engineering performance expectations. These visualization and instructional methods are used by teachers during professional development programs at UC Berkeley and the Smithsonian National Museum of Natural History and are being tested in San Francisco Bay Area classrooms.

  4. Sorption reactions in groundwater: various aspects to modelling the transport behaviour of zinc; Sorptionsreaktionen im Grundwasser: Unterschiedliche Aspekte bei der Modellierung des Transportverhaltens von Zink

    Energy Technology Data Exchange (ETDEWEB)

    Hadeler, A.

    1999-08-01

    The dispersal of trace substance in groundwater may be limited by dissolution and precipitation and, of particular interest in this paper, by sorption and desorption processes. These surface-active processes, which have a decisive influence on groundwater quality, depend on the concomitant geochemical conditions prevailing in the water, the constituents of the aquifer and on the surface properties of the solids. Taking the geochemical conditions prevailing naturally in brown coal mining areas as a point of departure this study was aimed at examining the influence of acidification processes on the transport behaviour inorganic pollutants for the example of zinc. For this purpose oxic column trials were carried out on sandy aquifer material. The data were supplemented by a detailed characterisation of the solid surfaces and modelled on the basis of a transport-reaction model as well as mechanistically with due regard to surface complexing. [German] Die Ausbreitung von Spurenstoffen im Grundwasser wird ausser durch Loesungs- und Faellungsprozesse vor allem durch Sorptions- bzw. Desorptionsvorgaenge limitiert. Diese fuer die Grundwasserqualitaet entscheidenden oberflaechenaktiven Prozesse sind von den variablen geochemischen Randbedingungen im Wasser, vom Stoffbestand des Aquifers und von den Oberflaecheneigenschaften der Feststoffe abhaengig. In Anlehnung an die natuerlichen im Bereich von Braunkohle-Abbaugebieten herrschenden geochemischen Bedingungen wurde der Einfluss von Versauerungsprozessen auf das Transportverhalten von anorganischen Schadstoffen, am Beispiel von Zink, auf der Basis von oxischen Saeulenversuchen an sandigem Aquifermaterial untersucht. Die Daten wurden durch eine detaillierte Charakterisierung der Feststoff-Oberflaechen ergaenzt und sowohl mit Hilfe eines Transport-Reaktionsmodells als auch mechanistisch unter Einbeziehung der Oberflaechenkomplexierung modelliert. (orig.)

  5. Photocatalytic TMO-NMs adsorbent: Temperature-Time dependent Safranine degradation, sorption study validated under optimized effective equilibrium models parameter with standardized statistical analysis

    Science.gov (United States)

    Wahab, Rizwan; Khan, Farheen; Kaushik, Nagendra Kumar; Musarrat, Javed; Al-Khedhairy, Abdulaziz A.

    2017-01-01

    In this paper, chemically synthesized copper oxide nanoparticles (CuO-NPs), were employed for two processes: one is photocatalytic degradation and second one adsorption for the sorption of safranine (SA) dye in an aqueous medium at pH = 12.01. The optimized analytes amount (nano-adsorbent = 0.10 g, conc. range of SA dye 56.13 ppm to 154.37 ppm, pH = 12.01, temperature 303 K) reached to equilibrium point in 80 min, which acquired for chemical adsorption-degradation reactions. The degredated SA dye data’s recorded by UV-visible spectroscopy for the occurrence of TMO-NMs of CuO-NPs at anticipated period of interval. The feasible performance of CuO-NPs was admirable, shows good adsorption capacity qm = 53.676 mg g−1 and most convenient to best fitted results establish by linear regression equation, corresponded for selected kinetic model (pseudo second order (R2 = 0.9981), equilibrium isotherm models (Freundlich, Langmuir, Dubnin-Radushkevich (D-R), Temkin, H-J and Halsey), and thermodynamic parameters (∆H° = 75461.909 J mol−1, ∆S° = 253.761 J mol−1, ∆G° = −1427.93 J mol−1, Ea = 185.142 J mol−1) with error analysis. The statistical study revealed that CuO-NPs was an effective adsorbent certified photocatalytic efficiency (η = 84.88%) for degradation of SA dye, exhibited more feasibility and good affinity toward adsorbate, the sorption capacity increases with increased temperature at equilibrium point. PMID:28195174

  6. Bayesian Assessment of the Uncertainties of Estimates of a Conceptual Rainfall-Runoff Model Parameters

    Science.gov (United States)

    Silva, F. E. O. E.; Naghettini, M. D. C.; Fernandes, W.

    2014-12-01

    This paper evaluated the uncertainties associated with the estimation of the parameters of a conceptual rainfall-runoff model, through the use of Bayesian inference techniques by Monte Carlo simulation. The Pará River sub-basin, located in the upper São Francisco river basin, in southeastern Brazil, was selected for developing the studies. In this paper, we used the Rio Grande conceptual hydrologic model (EHR/UFMG, 2001) and the Markov Chain Monte Carlo simulation method named DREAM (VRUGT, 2008a). Two probabilistic models for the residues were analyzed: (i) the classic [Normal likelihood - r ≈ N (0, σ²)]; and (ii) a generalized likelihood (SCHOUPS & VRUGT, 2010), in which it is assumed that the differences between observed and simulated flows are correlated, non-stationary, and distributed as a Skew Exponential Power density. The assumptions made for both models were checked to ensure that the estimation of uncertainties in the parameters was not biased. The results showed that the Bayesian approach proved to be adequate to the proposed objectives, enabling and reinforcing the importance of assessing the uncertainties associated with hydrological modeling.

  7. A hydrogeophysical conceptual model of Mount Toondina impact crater, South Australia

    Science.gov (United States)

    Dressler, Andrew Kelly

    Mount Toondina, South Australia is an impact crater that currently has groundwater discharging through evapotranspiration, but formerly had eight springs or more flowing around the crater ring. Using field geophysical and geochemical data, a hydrogeophysical conceptual model was developed that suggests that advection of groundwater to the surface through a sandstone layer is the dominant flow mechanism for the system, creating a ring of vegetation at the surface, although faults provide controls over some spring locations. The data also suggest that sufficient fluid density contrast combined with a vertical permeability structure may allow free convection to occur in the impact crater. The conceptual model was tested by developing numerical models to evaluate the permeability structure and the potential for mixed convection in the Mount Toondina system. The FEFLOW models suggest that the Mount Toondina impact crater spring system is controlled by mixed convective flow from the subsurface to the ring of vegetation around the springs which maintains brackish conditions relative to adjacent saline conditions. The models indicated that convective processes result throughout the crater although the character of convection is controlled by the relative permeability of the formations. The results can be applied to better manage flora and fauna in the Mount Toondina area and help to interpret potential for groundwater flow in and around other impact craters.

  8. A Conceptual Model of Professional Socialization within Student Affairs Graduate Preparation Programs

    Directory of Open Access Journals (Sweden)

    Rosemary J Perez

    2016-01-01

    Full Text Available Prior research exploring professional socialization in student affairs has been grounded in models that do not fully capture the distinct features of the field. Moreover, these studies have primarily focused on the transition into full-time work positions, and they have captured what happens to new professionals rather than how individuals understand their socialization experiences. With these gaps in mind, this conceptual paper presents a new model of professional socialization in student affairs graduate preparation programs that draws upon literature in the helping professions (i.e., nursing, social work, research on doctoral students and pre-tenure faculty, and the theoretical frameworks of sensemaking and self-authorship to highlight the dynamic relationship between individuals and organizations during the socialization process. Specifically, this model attempts to illuminate the cognitive mechanisms that undergird how individuals interpret their professional socialization. In doing so, the model proposes different ways individuals may make sense of their student affairs graduate training experiences based on (a whether or not they encounter discrepancies and (b their developmental capacity for self-authorship. The conceptual model presented here has implications for shaping graduate level coursework and fieldwork within student affairs preparation programs.

  9. Reducing structural uncertainty in conceptual hydrological modeling in the semi-arid Andes

    Science.gov (United States)

    Hublart, P.; Ruelland, D.; Dezetter, A.; Jourde, H.

    2014-10-01

    The use of lumped, conceptual models in hydrological impact studies requires placing more emphasis on the uncertainty arising from deficiencies and/or ambiguities in the model structure. This study provides an opportunity to combine a multiple-hypothesis framework with a multi-criteria assessment scheme to reduce structural uncertainty in the conceptual modeling of a meso-scale Andean catchment (1515 km2) over a 30 year period (1982-2011). The modeling process was decomposed into six model-building decisions related to the following aspects of the system behavior: snow accumulation and melt, runoff generation, redistribution and delay of water fluxes, and natural storage effects. Each of these decisions was provided with a set of alternative modeling options, resulting in a total of 72 competing model structures. These structures were calibrated using the concept of Pareto optimality with three criteria pertaining to streamflow simulations and one to the seasonal dynamics of snow processes. The results were analyzed in the four-dimensional space of performance measures using a fuzzy c-means clustering technique and a differential split sample test, leading to identify 14 equally acceptable model hypotheses. A filtering approach was then applied to these best-performing structures in order to minimize the overall uncertainty envelope while maximizing the number of enclosed observations. This led to retain 8 model hypotheses as a representation of the minimum structural uncertainty that could be obtained with this modeling framework. Future work to better consider model predictive uncertainty should include a proper assessment of parameter equifinality and data errors, as well as the testing of new or refined hypotheses to allow for the use of additional auxiliary observations.

  10. Reducing structural uncertainty in conceptual hydrological modelling in the semi-arid Andes

    Science.gov (United States)

    Hublart, P.; Ruelland, D.; Dezetter, A.; Jourde, H.

    2015-05-01

    The use of lumped, conceptual models in hydrological impact studies requires placing more emphasis on the uncertainty arising from deficiencies and/or ambiguities in the model structure. This study provides an opportunity to combine a multiple-hypothesis framework with a multi-criteria assessment scheme to reduce structural uncertainty in the conceptual modelling of a mesoscale Andean catchment (1515 km2) over a 30-year period (1982-2011). The modelling process was decomposed into six model-building decisions related to the following aspects of the system behaviour: snow accumulation and melt, runoff generation, redistribution and delay of water fluxes, and natural storage effects. Each of these decisions was provided with a set of alternative modelling options, resulting in a total of 72 competing model structures. These structures were calibrated using the concept of Pareto optimality with three criteria pertaining to streamflow simulations and one to the seasonal dynamics of snow processes. The results were analyzed in the four-dimensional (4-D) space of performance measures using a fuzzy c-means clustering technique and a differential split sample test, leading to identify 14 equally acceptable model hypotheses. A filtering approach was then applied to these best-performing structures in order to minimize the overall uncertainty envelope while maximizing the number of enclosed observations. This led to retain eight model hypotheses as a representation of the minimum structural uncertainty that could be obtained with this modelling framework. Future work to better consider model predictive uncertainty should include a proper assessment of parameter equifinality and data errors, as well as the testing of new or refined hypotheses to allow for the use of additional auxiliary observations.

  11. Constraining performance assessment models with tracer test results: a comparison between two conceptual models

    Science.gov (United States)

    McKenna, Sean A.; Selroos, Jan-Olof

    Tracer tests are conducted to ascertain solute transport parameters of a single rock feature over a 5-m transport pathway. Two different conceptualizations of double-porosity solute transport provide estimates of the tracer breakthrough curves. One of the conceptualizations (single-rate) employs a single effective diffusion coefficient in a matrix with infinite penetration depth. However, the tracer retention between different flow paths can vary as the ratio of flow-wetted surface to flow rate differs between the path lines. The other conceptualization (multirate) employs a continuous distribution of multiple diffusion rate coefficients in a matrix with variable, yet finite, capacity. Application of these two models with the parameters estimated on the tracer test breakthrough curves produces transport results that differ by orders of magnitude in peak concentration and time to peak concentration at the performance assessment (PA) time and length scales (100,000 years and 1,000 m). These differences are examined by calculating the time limits for the diffusive capacity to act as an infinite medium. These limits are compared across both conceptual models and also against characteristic times for diffusion at both the tracer test and PA scales. Additionally, the differences between the models are examined by re-estimating parameters for the multirate model from the traditional double-porosity model results at the PA scale. Results indicate that for each model the amount of the diffusive capacity that acts as an infinite medium over the specified time scale explains the differences between the model results and that tracer tests alone cannot provide reliable estimates of transport parameters for the PA scale. Results of Monte Carlo runs of the transport models with varying travel times and path lengths show consistent results between models and suggest that the variation in flow-wetted surface to flow rate along path lines is insignificant relative to variability in

  12. Parenting around child snacking: development of a theoretically-guided, empirically informed conceptual model.

    Science.gov (United States)

    Davison, Kirsten K; Blake, Christine E; Blaine, Rachel E; Younginer, Nicholas A; Orloski, Alexandria; Hamtil, Heather A; Ganter, Claudia; Bruton, Yasmeen P; Vaughn, Amber E; Fisher, Jennifer O

    2015-09-17

    Snacking contributes to excessive energy intakes in children. Yet factors shaping child snacking are virtually unstudied. This study examines food parenting practices specific to child snacking among low-income caregivers. Semi-structured interviews were conducted in English or Spanish with 60 low-income caregivers of preschool-aged children (18 non-Hispanic white, 22 African American/Black, 20 Hispanic; 92% mothers). A structured interview guide was used to solicit caregivers' definitions of snacking and strategies they use to decide what, when and how much snack their child eats. Interviews were audio-recorded, transcribed verbatim and analyzed using an iterative theory-based and grounded approach. A conceptual model of food parenting specific to child snacking was developed to summarize the findings and inform future research. Caregivers' descriptions of food parenting practices specific to child snacking were consistent with previous models of food parenting developed based on expert opinion [1, 2]. A few noteworthy differences however emerged. More than half of participants mentioned permissive feeding approaches (e.g., my child is the boss when it comes to snacks). As a result, permissive feeding was included as a higher order feeding dimension in the resulting model. In addition, a number of novel feeding approaches specific to child snacking emerged including child-centered provision of snacks (i.e., responding to a child's hunger cues when making decisions about snacks), parent unilateral decision making (i.e., making decisions about a child's snacks without any input from the child), and excessive monitoring of snacks (i.e., monitoring all snacks provided to and consumed by the child). The resulting conceptual model includes four higher order feeding dimensions including autonomy support, coercive control, structure and permissiveness and 20 sub-dimensions. This study formulates a language around food parenting practices specific to child snacking

  13. Why are you telling me that? A conceptual model of the social function of autobiographical memory.

    Science.gov (United States)

    Alea, Nicole; Bluck, Susan

    2003-03-01

    In an effort to stimulate and guide empirical work within a functional framework, this paper provides a conceptual model of the social functions of autobiographical memory (AM) across the lifespan. The model delineates the processes and variables involved when AMs are shared to serve social functions. Components of the model include: lifespan contextual influences, the qualitative characteristics of memory (emotionality and level of detail recalled), the speaker's characteristics (age, gender, and personality), the familiarity and similarity of the listener to the speaker, the level of responsiveness during the memory-sharing process, and the nature of the social relationship in which the memory sharing occurs (valence and length of the relationship). These components are shown to influence the type of social function served and/or, the extent to which social functions are served. Directions for future empirical work to substantiate the model and hypotheses derived from the model are provided.

  14. Parameter dimensionality reduction of a conceptual model for streamflow prediction in Canadian, snowmelt dominated ungauged basins

    Science.gov (United States)

    Arsenault, Richard; Poissant, Dominique; Brissette, François

    2015-11-01

    This paper evaluated the effects of parametric reduction of a hydrological model on five regionalization methods and 267 catchments in the province of Quebec, Canada. The Sobol' variance-based sensitivity analysis was used to rank the model parameters by their influence on the model results and sequential parameter fixing was performed. The reduction in parameter correlations improved parameter identifiability, however this improvement was found to be minimal and was not transposed in the regionalization mode. It was shown that 11 of the HSAMI models' 23 parameters could be fixed with little or no loss in regionalization skill. The main conclusions were that (1) the conceptual lumped models used in this study did not represent physical processes sufficiently well to warrant parameter reduction for physics-based regionalization methods for the Canadian basins examined and (2) catchment descriptors did not adequately represent the relevant hydrological processes, namely snow accumulation and melt.

  15. Integrated approach to model decomposed flow hydrograph using artificial neural network and conceptual techniques

    Science.gov (United States)

    Jain, Ashu; Srinivasulu, Sanaga

    2006-02-01

    This paper presents the findings of a study aimed at decomposing a flow hydrograph into different segments based on physical concepts in a catchment, and modelling different segments using different technique viz. conceptual and artificial neural networks (ANNs). An integrated modelling framework is proposed capable of modelling infiltration, base flow, evapotranspiration, soil moisture accounting, and certain segments of the decomposed flow hydrograph using conceptual techniques and the complex, non-linear, and dynamic rainfall-runoff process using ANN technique. Specifically, five different multi-layer perceptron (MLP) and two self-organizing map (SOM) models have been developed. The rainfall and streamflow data derived from the Kentucky River catchment were employed to test the proposed methodology and develop all the models. The performance of all the models was evaluated using seven different standard statistical measures. The results obtained in this study indicate that (a) the rainfall-runoff relationship in a large catchment consists of at least three or four different mappings corresponding to different dynamics of the underlying physical processes, (b) an integrated approach that models the different segments of the decomposed flow hydrograph using different techniques is better than a single ANN in modelling the complex, dynamic, non-linear, and fragmented rainfall runoff process, (c) a simple model based on the concept of flow recession is better than an ANN to model the falling limb of a flow hydrograph, and (d) decomposing a flow hydrograph into the different segments corresponding to the different dynamics based on the physical concepts is better than using the soft decomposition employed using SOM.

  16. Description and evaluation of a mechanistically based conceptual model for spall

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, F.D.; Knowles, M.K.; Thompson, T.W. [and others

    1997-08-01

    A mechanistically based model for a possible spall event at the WIPP site is developed and evaluated in this report. Release of waste material to the surface during an inadvertent borehole intrusion is possible if future states of the repository include high gas pressure and waste material consisting of fine particulates having low mechanical strength. The conceptual model incorporates the physics of wellbore hydraulics coupled to transient gas flow to the intrusion borehole, and mechanical response of the waste. Degraded waste properties using of the model. The evaluations include both numerical and analytical implementations of the conceptual model. A tensile failure criterion is assumed appropriate for calculation of volumes of waste experiencing fragmentation. Calculations show that for repository gas pressures less than 12 MPa, no tensile failure occurs. Minimal volumes of material experience failure below gas pressure of 14 MPa. Repository conditions dictate that the probability of gas pressures exceeding 14 MPa is approximately 1%. For these conditions, a maximum failed volume of 0.25 m{sup 3} is calculated.

  17. Conceptual framework for model-based analysis of residence time distribution in twin-screw granulation.

    Science.gov (United States)

    Kumar, Ashish; Vercruysse, Jurgen; Vanhoorne, Valérie; Toiviainen, Maunu; Panouillot, Pierre-Emmanuel; Juuti, Mikko; Vervaet, Chris; Remon, Jean Paul; Gernaey, Krist V; De Beer, Thomas; Nopens, Ingmar

    2015-04-25

    Twin-screw granulation is a promising continuous alternative for traditional batchwise wet granulation processes. The twin-screw granulator (TSG) screws consist of transport and kneading element modules. Therefore, the granulation to a large extent is governed by the residence time distribution within each module where different granulation rate processes dominate over others. Currently, experimental data is used to determine the residence time distributions. In this study, a conceptual model based on classical chemical engineering methods is proposed to better understand and simulate the residence time distribution in a TSG. The experimental data were compared with the proposed most suitable conceptual model to estimate the parameters of the model and to analyse and predict the effects of changes in number of kneading discs and their stagger angle, screw speed and powder feed rate on residence time. The study established that the kneading block in the screw configuration acts as a plug-flow zone inside the granulator. Furthermore, it was found that a balance between the throughput force and conveying rate is required to obtain a good axial mixing inside the twin-screw granulator. Although the granulation behaviour is different for other excipients, the experimental data collection and modelling methods applied in this study are generic and can be adapted to other excipients. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Understanding How Domestic Violence Support Services Promote Survivor Well-being: A Conceptual Model.

    Science.gov (United States)

    Sullivan, Cris M

    2018-01-01

    Domestic violence (DV) victim service programs have been increasingly expected by legislators and funders to demonstrate that they are making a significant difference in the lives of those using their services. Alongside this expectation, they are being asked to describe the Theory of Change guiding how they believe their practices lead to positive results for survivors and their children. Having a widely accepted conceptual model is not just potentially useful to funders and policy makers as they help shape policy and practice -- it can also help programs continually reflect upon and improve their work. This paper describes the iterative and collaborative process undertaken to generate a conceptual model describing how DV victim services are expected to improve survivors' lives. The Social and Emotional Well-Being Framework guiding the model is an ideal structure to use to describe the goals and practices of DV programs because this framework: (1) accurately represents DV programs' goal of helping survivors and their children thrive; and (2) recognizes the importance of community, social, and societal context in influencing individuals' social and emotional well-being. The model was designed to guide practice and to generate new questions for research and evaluation that address individual, community, and systems factors that promote or hinder survivor safety and well-being.

  19. Conceptual model of sedimentation in the Sacramento-San Joaquin River Delta

    Science.gov (United States)

    Schoellhamer, David H.; Wright, Scott A.; Drexler, Judith Z.

    2012-01-01

    Sedimentation in the Sacramento–San Joaquin River Delta builds the Delta landscape, creates benthic and pelagic habitat, and transports sediment-associated contaminants. Here we present a conceptual model of sedimentation that includes submodels for river supply from the watershed to the Delta, regional transport within the Delta and seaward exchange, and local sedimentation in open water and marsh habitats. The model demonstrates feedback loops that affect the Delta ecosystem. Submerged and emergent marsh vegetation act as ecosystem engineers that can create a positive feedback loop by decreasing suspended sediment, increasing water column light, which in turn enables more vegetation. Sea-level rise in open water is partially countered by a negative feedback loop that increases deposition if there is a net decrease in hydrodynamic energy. Manipulation of regional sediment transport is probably the most feasible method to control suspended sediment and thus turbidity. The conceptual model is used to identify information gaps that need to be filled to develop an accurate sediment transport model.

  20. Conceptualising forensic science and forensic reconstruction. Part I: A conceptual model.

    Science.gov (United States)

    Morgan, R M

    2017-11-01

    There has been a call for forensic science to actively return to the approach of scientific endeavour. The importance of incorporating an awareness of the requirements of the law in its broadest sense, and embedding research into both practice and policy within forensic science, is arguably critical to achieving such an endeavour. This paper presents a conceptual model (FoRTE) that outlines the holistic nature of trace evidence in the 'endeavour' of forensic reconstruction. This model offers insights into the different components intrinsic to transparent, reproducible and robust reconstructions in forensic science. The importance of situating evidence within the whole forensic science process (from crime scene to court), of developing evidence bases to underpin each stage, of frameworks that offer insights to the interaction of different lines of evidence, and the role of expertise in decision making are presented and their interactions identified. It is argued that such a conceptual model has value in identifying the future steps for harnessing the value of trace evidence in forensic reconstruction. It also highlights that there is a need to develop a nuanced approach to reconstructions that incorporates both empirical evidence bases and expertise. A conceptual understanding has the potential to ensure that the endeavour of forensic reconstruction has its roots in 'problem-solving' science, and can offer transparency and clarity in the conclusions and inferences drawn from trace evidence, thereby enabling the value of trace evidence to be realised in investigations and the courts. Copyright © 2017 The Author. Published by Elsevier B.V. All rights reserved.