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Sample records for sorbent recovery systems

  1. Neodymium Recovery by Chitosan/Iron(III Hydroxide [ChiFer(III] Sorbent Material: Batch and Column Systems

    Directory of Open Access Journals (Sweden)

    Hary Demey

    2018-02-01

    Full Text Available A low cost composite material was synthesized for neodymium recovery from dilute aqueous solutions. The in-situ production of the composite containing chitosan and iron(III hydroxide (ChiFer(III was improved and the results were compared with raw chitosan particles. The sorbent was characterized using Fourier transform infrared spectroscopy (FTIR and scanning electron microscopy-energy dispersive X-ray analyses (SEM-EDX. The equilibrium studies were performed using firstly a batch system, and secondly a continuous system. The sorption isotherms were fitted with the Langmuir, Freundlich, and Sips models; experimental data was better described with the Langmuir equation and the maximum sorption capacity was 13.8 mg g-1 at pH 4. The introduction of iron into the biopolymer matrix increases by four times the sorption uptake of the chitosan; the individual sorption capacity of iron (into the composite was calculated as 30.9 mg Nd/g Fe. The experimental results of the columns were fitted adequately using the Thomas model. As an approach to Nd-Fe-B permanent magnets effluents, a synthetic dilute effluent was simulated at pH 4, in order to evaluate the selectivity of the sorbent material; the overshooting of boron in the column system confirmed the higher selectivity toward neodymium ions. The elution step was carried out using MilliQ-water with the pH set to 3.5 (dilute HCl solution.

  2. Sorbent Structural Impacts Due to Humidity on Carbon Dioxide Removal Sorbents for Advanced Exploration Systems

    Science.gov (United States)

    Watson, David; Knox, James C.; West, Phillip; Stanley, Christine M.; Bush, Richard

    2015-01-01

    The Life Support Systems Project (LSSP) under the Advanced Exploration Systems (AES) program builds upon the work performed under the AES Atmosphere Resource Recovery and Environmental Monitoring (ARREM) project focusing on the numerous technology development areas. The CO2 removal and associated air drying development efforts are focused on improving the current state-of-the-art system on the International Space Station (ISS) utilizing fixed beds of sorbent pellets by seeking more robust pelletized sorbents, evaluating structured sorbents, and examining alternate bed configurations to improve system efficiency and reliability. A component of the CO2 removal effort encompasses structural stability testing of existing and emerging sorbents. Testing will be performed on dry sorbents and sorbents that have been conditioned to three humidity levels. This paper describes the sorbent structural stability screening efforts in support of the LSS Project within the AES Program.

  3. Itaconic acid based potential sorbent for uranium recovery

    International Nuclear Information System (INIS)

    Kalyan, Y.; Naidu, G.R.K.; Das, Sadananda; Pandey, A.K.; Reddy, A.V.R.

    2010-01-01

    Cross-linked hydrogels and adsorptive membranes containing Itaconic acid, Acrylamide, Penta erythritol tetra acrylate and α, α-dimethyl- α-phenyl aceto phenone were prepared by UV-initiated bulk polymerization. These hydrogels and adsorptive membranes were characterized for pH uptake, sorption and desorption kinetics and selectivity towards uranium. The sorption ability of the sorbents towards uranyl ion was thoroughly examined. The developed itaconic acid based sorbents were evaluated for the recovery of uranium from lean sources like sea water. (author)

  4. Sorbent-based Oxygen Production for Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Sethi, Vijay [Western Research Inst. (WRI), Laramie, WY (United States)

    2017-01-31

    Project DE-FE0024075 deals with the development of a moderate-temperature sorbent-based oxygen production technology. Sorbent-based oxygen production process utilizes oxygen-storage properties of Perovskites to (1) adsorb oxygen from air in a solid sorbent, and (2) release the adsorbed oxygen into a sweep gas such as CO2 and/or steam for gasification systems or recycled flue gas for oxy-combustion systems. Pure oxygen can be produced by the use of vacuum instead of a sweep gas to affect the pressure swing. By developing more efficient and stable, higher sorption capacity, newer class of materials operating at moderate temperatures this process represents a major advancement in air separation technology. Newly developed perovskite ceramic sorbent materials with order-disorder transition have a higher O2 adsorption capacity, potentially 200 °C lower operating temperatures, and up to two orders of magnitude faster desorption rates than those used in earlier development efforts. The performance advancements afforded by the new materials lead to substantial savings in capital investment and operational costs. Cost of producing oxygen using sorbents could be as much as 26% lower than VPSA and about 13% lower than a large cryogenic air separation unit. Cost advantage against large cryogenic separation is limited because sorbent-based separation numbers up sorbent modules for achieving the larger capacity.

  5. Recovery of Lithium from Geothermal Brine with Lithium-Aluminum Layered Double Hydroxide Chloride Sorbents.

    Science.gov (United States)

    Paranthaman, Mariappan Parans; Li, Ling; Luo, Jiaqi; Hoke, Thomas; Ucar, Huseyin; Moyer, Bruce A; Harrison, Stephen

    2017-11-21

    We report a three-stage bench-scale column extraction process to selectively extract lithium chloride from geothermal brine. The goal of this research is to develop materials and processing technologies to improve the economics of lithium extraction and production from naturally occurring geothermal and other brines for energy storage applications. A novel sorbent, lithium aluminum layered double hydroxide chloride (LDH), is synthesized and characterized with X-ray powder diffraction, scanning electron microscopy, inductively coupled plasma optical emission spectrometry (ICP-OES), and thermogravimetric analysis. Each cycle of the column extraction process consists of three steps: (1) loading the sorbent with lithium chloride from brine; (2) intermediate washing to remove unwanted ions; (3) final washing for unloading the lithium chloride ions. Our experimental analysis of eluate vs feed concentrations of Li and competing ions demonstrates that our optimized sorbents can achieve a recovery efficiency of ∼91% and possess excellent Li apparent selectivity of 47.8 compared to Na ions and 212 compared to K ions, respectively in the brine. The present work demonstrates that LDH is an effective sorbent for selective extraction of lithium from brines, thus offering the possibility of effective application of lithium salts in lithium-ion batteries leading to a fundamental shift in the lithium supply chain.

  6. Mercury sorbent delivery system for flue gas

    Science.gov (United States)

    Klunder,; Edgar, B [Bethel Park, PA

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  7. 21 CFR 876.5600 - Sorbent regenerated dialysate delivery system for hemodialysis.

    Science.gov (United States)

    2010-04-01

    ... dialyzer. The device is used with the extracorporeal blood system and the dialyzer of the hemodialysis... dialysate conditions. The sorbent cartridge may include absorbent, ion exchange and catalytic materials. (b...

  8. Ecologically pure sorbents for power system of Myanmar

    Science.gov (United States)

    Nikitina, I. S.; Moryganova, Y. A.; Maung, Ko Ko; Arefeva, E. A.

    2017-11-01

    Currently, one of the most important problems of the thermal power plant, and many industrial enterprises in different countries is a wastewater treatment for oil products. When choosing the good sorbents is necessary to consider not only the properties and efficiency of the recommended materials, but also the cost, the possibility of environmentally friendly disposal of used sorbents and the possibility of using secondary resources. The purpose of this paper is to study the possibility of using agricultural waste in Myanmar as the sorbents in wastewater treatment containing oil products. The results of experiments have confirmed that rice hulls, and coconut fiber can be effectively used as the sorbents in wastewater treatment containing oil products at concentrations up to 10 mg/l. According to comparative analysis with the conventional sorbent-activated birch carbon (BAC-A) in the Russian power industry has shown that coconut fiber has very good sorption capacity and it is available to use as the raw materials for industries, which does not require to regenerate after using it and can be directly recycled in the factory.

  9. Performance Evaluation of Engineered Structured Sorbents for Atmosphere Revitalization Systems On Board Crewed Space Vehicles and Habitats

    Science.gov (United States)

    Howard, David F.; Perry, Jay L.; Knox, James C.; Junaedi, Christian; Roychoudhury, Subir

    2011-01-01

    Engineered structured (ES) sorbents are being developed to meet the technical challenges of future crewed space exploration missions. ES sorbents offer the inherent performance and safety attributes of zeolite and other physical adsorbents but with greater structural integrity and process control to improve durability and efficiency over packed beds. ES sorbent techniques that are explored include thermally linked and pressure-swing adsorption beds for water-save dehumidification and sorbent-coated metal meshes for residual drying, trace contaminant control, and carbon dioxide control. Results from sub-scale performance evaluations of a thermally linked pressure-swing adsorbent bed and an integrated sub-scale ES sorbent system are discussed.

  10. Heat recovery from sorbent-based CO.sub.2 capture

    Science.gov (United States)

    Jamal, Aqil; Gupta, Raghubir P

    2015-03-10

    The present invention provides a method of increasing the efficiency of exothermic CO.sub.2 capture processes. The method relates to withdrawing heat generated during the exothermic capture of CO.sub.2 with various sorbents via heat exchange with a working fluid. The working fluid is provided at a temperature and pressure such that it is in the liquid state, and has a vaporization temperature in a range such that the heat arising from the reaction of the CO.sub.2 and the sorbent causes a phase change from liquid to vapor state in whole or in part and transfers heat from to the working fluid. The resulting heated working fluid may subsequently be used to generate power.

  11. Sorbent selection and design considerations for uranium trapping

    International Nuclear Information System (INIS)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01

    The efficient removal of UF 6 from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications

  12. Release of iodine radionuclides from gas media in a system of selective block sorbents

    International Nuclear Information System (INIS)

    Moskvin, L.N.; Miroshnikov, V.S.; Mel'nikov, V.A.; Chetverikov, V.V.

    1979-01-01

    A scheme of extracting iodine radionuclides from gas flows in a system of selective sorbents has been developed. The method provides separation of three forms of iodine: the aerosol component, the elementary iodine and organic-iodine compounds. Aerosols are trapped by a mechanical filter made of porous polytetrafluoroethylene with pores of no more than 1 μm. Silver-based sorbents for the elementary iodine are made by sintering the granular polytetrafluoroethylene (the size of granules is 0.1-0.5 mm) with of finely dispersed solver (5% mass). Organic iodine compounds are extracted by a silica sorbent impregnated with silver nitrate. The efficiency of sorbents was tested in gas flows with a known content of 131 I in the form of elementary iodine and methyl iodide. The results of experiments show that the efficiency of sorption of elementary iodine by a metallic-silver sorbent and of methyl iodide by a SiO 2 /AgNO 3 sorbent constitutes no less than 99% at a flow rate of up to 200 l/h. The iodine has been extracted at a flow rate of 100 l/h during 100 hours and for that time the efficiency of the iodine sorbtion has not changed. The suggested variant of extracting iodine radionuclides from gaseous media can be used both for fast control of iodine content in gas blowoffs and for researches aimed at studying the distribution of iodine forms in steam-and-gas media depending on nuclear plant operating conditions

  13. A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Waysbort, Daniel [Israel Institute for Biological Research, PO Box 19, Ness-Ziona 74100 (Israel); McGarvey, David J. [R and T Directorate, Edgewood Chemical and Biological Center (ECBC), Aberdeen Proving Ground-Edgewood Area, MD 21010 (United States)], E-mail: david.mcgarvey@us.army.mil; Creasy, William R.; Morrissey, Kevin M.; Hendrickson, David M. [SAIC, P.O. Box 68, Gunpowder Branch, Aberdeen Proving Ground, MD 21010 (United States); Durst, H. Dupont [R and T Directorate, Edgewood Chemical and Biological Center (ECBC), Aberdeen Proving Ground-Edgewood Area, MD 21010 (United States)

    2009-01-30

    A decontamination system for chemical warfare agents was developed and tested that combines a liquid decontamination reagent solution with solid sorbent particles. The components have fewer safety and environmental concerns than traditional chlorine bleach-based products or highly caustic solutions. The liquid solution, based on Decon Green{sup TM}, has hydrogen peroxide and a carbonate buffer as active ingredients. The best solid sorbents were found to be a copolymer of ethylene glycol dimethacrylate and n-lauryl methacrylate (Polytrap 6603 Adsorber); or an allyl methacrylate cross-linked polymer (Poly-Pore E200 Adsorber). These solids are human and environmentally friendly and are commonly used in cosmetics. The decontaminant system was tested for reactivity with pinacolyl methylphosphonofluoridate (Soman, GD), bis(2-chloroethyl)sulfide (Mustard, HD), and S-(2-diisopropylaminoethyl) O-ethyl methylphosphonothioate (VX) by using NMR Spectroscopy. Molybdate ion (MoO{sub 4}{sup -2}) was added to the decontaminant to catalyze the oxidation of HD. The molybdate ion provided a color change from pink to white when the oxidizing capacity of the system was exhausted. The decontaminant was effective for ratios of agent to decontaminant of up to 1:50 for VX (t{sub 1/2} {<=} 4 min), 1:10 for HD (t{sub 1/2} < 2 min with molybdate), and 1:10 for GD (t{sub 1/2} < 2 min). The vapor concentrations of GD above the dry sorbent and the sorbent with decontamination solution were measured to show that the sorbent decreased the vapor concentration of GD. The E200 sorbent had the additional advantage of absorbing aqueous decontamination solution without the addition of an organic co-solvent such as isopropanol, but the rate depended strongly on mixing for HD.

  14. A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent

    International Nuclear Information System (INIS)

    Waysbort, Daniel; McGarvey, David J.; Creasy, William R.; Morrissey, Kevin M.; Hendrickson, David M.; Durst, H. Dupont

    2009-01-01

    A decontamination system for chemical warfare agents was developed and tested that combines a liquid decontamination reagent solution with solid sorbent particles. The components have fewer safety and environmental concerns than traditional chlorine bleach-based products or highly caustic solutions. The liquid solution, based on Decon Green TM , has hydrogen peroxide and a carbonate buffer as active ingredients. The best solid sorbents were found to be a copolymer of ethylene glycol dimethacrylate and n-lauryl methacrylate (Polytrap 6603 Adsorber); or an allyl methacrylate cross-linked polymer (Poly-Pore E200 Adsorber). These solids are human and environmentally friendly and are commonly used in cosmetics. The decontaminant system was tested for reactivity with pinacolyl methylphosphonofluoridate (Soman, GD), bis(2-chloroethyl)sulfide (Mustard, HD), and S-(2-diisopropylaminoethyl) O-ethyl methylphosphonothioate (VX) by using NMR Spectroscopy. Molybdate ion (MoO 4 -2 ) was added to the decontaminant to catalyze the oxidation of HD. The molybdate ion provided a color change from pink to white when the oxidizing capacity of the system was exhausted. The decontaminant was effective for ratios of agent to decontaminant of up to 1:50 for VX (t 1/2 ≤ 4 min), 1:10 for HD (t 1/2 1/2 < 2 min). The vapor concentrations of GD above the dry sorbent and the sorbent with decontamination solution were measured to show that the sorbent decreased the vapor concentration of GD. The E200 sorbent had the additional advantage of absorbing aqueous decontamination solution without the addition of an organic co-solvent such as isopropanol, but the rate depended strongly on mixing for HD

  15. Heat Recovery System

    Science.gov (United States)

    1984-01-01

    Ball Metal's design of ducting and controls for series of roof top heat exchangers was inspired by Tech Briefs. Heat exchangers are installed on eight press and coating lines used to decorate sheet metal. The heat recovery system provides an estimated energy savings of more than $250,000 per year.

  16. A decontamination system for chemical weapons agents using a liquid solution on a solid sorbent.

    Science.gov (United States)

    Waysbort, Daniel; McGarvey, David J; Creasy, William R; Morrissey, Kevin M; Hendrickson, David M; Durst, H Dupont

    2009-01-30

    A decontamination system for chemical warfare agents was developed and tested that combines a liquid decontamination reagent solution with solid sorbent particles. The components have fewer safety and environmental concerns than traditional chlorine bleach-based products or highly caustic solutions. The liquid solution, based on Decon Greentrade mark, has hydrogen peroxide and a carbonate buffer as active ingredients. The best solid sorbents were found to be a copolymer of ethylene glycol dimethacrylate and n-lauryl methacrylate (Polytrap 6603 Adsorber); or an allyl methacrylate cross-linked polymer (Poly-Pore E200 Adsorber). These solids are human and environmentally friendly and are commonly used in cosmetics. The decontaminant system was tested for reactivity with pinacolyl methylphosphonofluoridate (Soman, GD), bis(2-chloroethyl)sulfide (Mustard, HD), and S-(2-diisopropylaminoethyl) O-ethyl methylphosphonothioate (VX) by using NMR Spectroscopy. Molybdate ion (MoO(4)(-2)) was added to the decontaminant to catalyze the oxidation of HD. The molybdate ion provided a color change from pink to white when the oxidizing capacity of the system was exhausted. The decontaminant was effective for ratios of agent to decontaminant of up to 1:50 for VX (t(1/2) decontamination solution were measured to show that the sorbent decreased the vapor concentration of GD. The E200 sorbent had the additional advantage of absorbing aqueous decontamination solution without the addition of an organic co-solvent such as isopropanol, but the rate depended strongly on mixing for HD.

  17. Design, Fabrication, and Shakeout Testing of ATALANTE Dissolver Off-Gas Sorbent-Based Capture System

    International Nuclear Information System (INIS)

    Walker Jr, Joseph Franklin; Jubin, Robert Thomas; Jordan, Jacob A.; Bruffey, Stephanie H.

    2015-01-01

    A sorbent-based capture system designed for integration into the existing dissolver off-gas (DOG) treatment system at the ATelier Alpha et Laboratoires pour ANalyses, Transuraniens et Etudes de retraitement (ATALANTE) facility has been successfully designed and fabricated and has undergone shakeout testing. Discussions with personnel from the ATALANTE facility provided guidance that was used for the design. All components for this system were specified, procured, and received on site at Oak Ridge National Laboratory (ORNL). The system was then fabricated and tested at ORNL to verify operation. Shakeout testing resulted in a simplified system. This system should be easily installed into the existing facility and should be straightforward to operate during future experimental testing. All parts were selected to be compatible with ATALANTE power supplies, space requirements, and the existing DOG treatment system. Additionally, the system was demonstrated to meet all of four design requirements. These include (1) a dissolver off-gas flow rate of ?100 L/h (1.67 L/min), (2) an external temperature of ?50°C for all system components placed in the hot cell, (3) a sorbent bed temperature of ~150°C, and (4) a gas temperature of ~150°C upon entry into the sorbent bed. The system will be ready for shipment and installation in the existing DOG treatment system at ATALANTE in FY 2016.

  18. Waste heat recovery system

    International Nuclear Information System (INIS)

    Phi Wah Tooi

    2010-01-01

    Full text: The Konzen in-house designed anaerobic digester system for the POME (Palm Oil Mill Effluent) treatment process is one of the registered Clean Development Mechanism (CDM) projects in Malaysia. It is an organic wastewater treatment process which achieves excellent co-benefits objectives through the prevention of water pollution and reduction of greenhouse gas emissions, which is estimated to be 40,000 to 50,000 t-CO 2 per year. The anaerobic digester was designed in mesophile mode with temperature ranging from 37 degree Celsius to 45 degree Celsius. A microorganisms growth is optimum under moderately warm temperature conditions. The operating temperature of the anaerobic digester needs to be maintained constantly. There are two waste heat recovery systems designed to make the treatment process self-sustaining. The heat recovered will be utilised as a clean energy source to heat up the anaerobic digester indirectly. The first design for the waste heat recovery system utilises heat generated from the flue gas of the biogas flaring system. A stainless steel water tank with an internal water layer is installed at the top level of the flare stack. The circulating water is heated by the methane enriched biogas combustion process. The second design utilizes heat generated during the compression process for the biogas compressor operation. The compressed biogas needs to be cooled before being recycled back into the digester tank for mixing purposes. Both the waste heat recovery systems use a design which applies a common water circulation loop and hot water tank to effectively become a closed loop. The hot water tank will perform both storage and temperature buffer functions. The hot water is then used to heat up recycled sludge from 30 degree Celsius to 45 degree Celsius with the maximum temperature setting at 50 degree Celsius. The recycled sludge line temperature will be measured and monitored by a temperature sensor and transmitter, which will activate the

  19. Aerogel sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Begag, Redouane; Rhine, Wendell E.; Dong, Wenting

    2018-04-03

    The current invention describes methods and compositions of various sorbents based on aerogels of various silanes and their use as sorbent for carbon dioxide. Methods further provide for optimizing the compositions to increase the stability of the sorbents for prolonged use as carbon dioxide capture matrices.

  20. Space-filling polyhedral sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Haaland, Peter

    2016-06-21

    Solid sorbents, systems, and methods for pumping, storage, and purification of gases are disclosed. They derive from the dynamics of porous and free convection for specific gas/sorbent combinations and use space filling polyhedral microliths with facial aplanarities to produce sorbent arrays with interpenetrating interstitial manifolds of voids.

  1. Waste heat recovery system

    Energy Technology Data Exchange (ETDEWEB)

    Ernst, Timothy C.; Zigan, James A.

    2017-12-19

    A waste heat recovery system includes a Rankine cycle (RC) circuit having a pump, a boiler, an energy converter, and a condenser fluidly coupled via conduits in that order, to provide additional work. The additional work is fed to an input of a gearbox assembly including a capacity for oil by mechanically coupling to the energy converter to a gear assembly. An interface is positioned between the RC circuit and the gearbox assembly to partially restrict movement of oil present in the gear assembly into the RC circuit and partially restrict movement of working fluid present in the RC circuit into the gear assembly. An oil return line is fluidly connected to at least one of the conduits fluidly coupling the RC components to one another and is operable to return to the gear assembly oil that has moved across the interface from the gear assembly to the RC circuit.

  2. Sorbent suppliers

    International Nuclear Information System (INIS)

    Vedder, M.

    1994-01-01

    Sorbents are used to absorb or contain spilled and leaking chemicals, oils, lubricants and other process fluids. They are commonly used around the base of machinery in industrial applications, and in remediating oil spills on land and water. Sorbents are made from biodegradable, inorganic or synthetic materials. Organic materials include corn cobs, wood pulp, paper fiber and cotton. Inorganic materials include clay, perlite, expanded silicates and expanded mica. Synthetic sorbents are made from petroleum- or plastic-based materials such as polyurethane, polyethylene or polypropylene. Sorbents are available in a variety of forms, including pads, rolls, booms, pillows and loose particulate

  3. Fabrication of ATALANTE Dissolver Off-Gas Sorbent-Based Capture System

    Energy Technology Data Exchange (ETDEWEB)

    Walker, Jr., Joseph Franklin [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jubin, Robert Thomas [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-04-30

    A small sorbent-based capture system was designed that could be placed in the off-gas line from the fuel dissolver in the ATALANTE hot cells with minimal modifications to the ATALANTE dissolver off-gas system. Discussions with personnel from the ATALANTE facility provided guidance that was used for the design. All components for this system have been specified, procured, and received on site at Oak Ridge National Laboratory (ORNL), meeting the April 30, 2015, milestone for completing the fabrication of the ATALANTE dissolver off-gas capture system. This system will be tested at ORNL to verify operation and to ensure that all design requirements for ATALANTE are met. Modifications to the system will be made, as indicated by the testing, before the system is shipped to ATALANTE for installation in the hot cell facility.

  4. 40 CFR Appendix K to Part 75 - Quality Assurance and Operating Procedures for Sorbent Trap Monitoring Systems

    Science.gov (United States)

    2010-07-01

    ... Pump. Use a leak-tight, vacuum pump capable of operating within the candidate system's flow range. 5.1... sorbent trap monitoring system typically operates. The gas flow meter shall be equipped with any necessary... system typically operates. You may either follow the procedures in section 10.3.1 of Method 5 in appendix...

  5. Characterization of commercial off-the shelf regenerable sorbent to scrub carbon dioxide in a portable life support system

    Science.gov (United States)

    Arai, Tatsuya; Fricker, John

    2018-06-01

    A resin bead Mitsubishi DIAION™ CR20 was identified and characterized as a first commercial off-the shelf regenerable carbon dioxide (CO2) sorbent candidate for space life support system applications at room temperature. The CO2 adsorption rates and capacities of CR20 at varying CO2 partial pressures were obtained. The data were used to numerically simulate CO2 adsorption by a swingbed, a pair of two sorbent beds that alternately adsorb and desorb CO2 in a space suit portable life support system (PLSS). The result demonstrated that a reasonable volume of CR20 would be able to continuously adsorb CO2 with bed-swing interval of 4 min at 300-W metabolic rate, and that commercial off-the shelf CR20 would have similar performance of CO2 adsorption to the proprietary swingbed sorbent SA9T for PLSS applications.

  6. Carbon-Based Regenerable Sorbents for the Combined Carbon Dioxide and Ammonia Removal for the Primary Life Support System (PLSS)

    Science.gov (United States)

    Wojtowicz, Marek A.; Cosgrove, Joseph E.; Serio, Michael A.; Manthina, Venkata; Singh, Prabhakar; Chullen, Cinda

    2014-01-01

    Results are presented on the development of reversible sorbents for the combined carbon dioxide and trace-contaminant (TC) removal for use in Extravehicular Activities (EVAs). Since ammonia is the most important TC to be captured, data on TC sorption presented in this paper are limited to ammonia, with results relevant to other TCs to be reported at a later time. The currently available life support systems use separate units for carbon dioxide, trace contaminants, and moisture control, and the long-term objective is to replace the above three modules with a single one. Furthermore, the current TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is non-regenerable, and the carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. The objective of this study was to demonstrate the feasibility of using carbon sorbents for the reversible, concurrent sorption of carbon dioxide and ammonia. Several carbon sorbents were fabricated and tested, and multiple adsorption/vacuum-regeneration cycles were demonstrated at room temperature, and also a carbon surface conditioning technique that enhances the combined carbon dioxide and ammonia sorption without impairing sorbent regeneration.

  7. Enhanced oil recovery system

    Science.gov (United States)

    Goldsberry, Fred L.

    1989-01-01

    All energy resources available from a geopressured geothermal reservoir are used for the production of pipeline quality gas using a high pressure separator/heat exchanger and a membrane separator, and recovering waste gas from both the membrane separator and a low pressure separator in tandem with the high pressure separator for use in enhanced oil recovery, or in powering a gas engine and turbine set. Liquid hydrocarbons are skimmed off the top of geothermal brine in the low pressure separator. High pressure brine from the geothermal well is used to drive a turbine/generator set before recovering waste gas in the first separator. Another turbine/generator set is provided in a supercritical binary power plant that uses propane as a working fluid in a closed cycle, and uses exhaust heat from the combustion engine and geothermal energy of the brine in the separator/heat exchanger to heat the propane.

  8. Co-Adsorption of Ammonia and Formaldehyde on Regenerable Carbon Sorbents for the Primary Life Support System (PLSS)

    Science.gov (United States)

    Wojtowicz, Marek A.; Cosgrove, Joseph E.; Serio, Michael A.; Wilburn, Monique S.

    2016-01-01

    Results are presented on the development of a reversible carbon sorbent for trace-contaminant (TC) removal for use in Extravehicular Activities (EVAs), and more specifically in the Primary Life Support System (PLSS). The current TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is deemed non-regenerable, while the carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. Data on concurrent sorption and desorption of ammonia and formaldehyde, which are major TCs of concern, are presented in this paper. A carbon sorbent was fabricated by dry impregnation of a reticulated carbon-foam support with polyvinylidene chloride, followed by carbonization and thermal oxidation in air. Sorbent performance was tested for ammonia and formaldehyde sorption and vacuum regeneration, with and without water present in the gas stream. It was found that humidity in the gas phase enhanced ammonia-sorption capacity by a factor larger than two. Co-adsorption of ammonia and formaldehyde in the presence of water resulted in strong formaldehyde sorption (to the point that it was difficult to saturate the sorbent on the time scales used in this study). In the absence of humidity, adsorption of formaldehyde on the carbon surface was found to impair ammonia sorption in subsequent runs; in the presence of water, however, both ammonia and formaldehyde could be efficiently removed from the gas phase by the sorbent. The efficiency of vacuum regeneration could be enhanced by gentle heating to temperatures below 60 deg.

  9. Granulated bog iron ores as sorbents in passive (bio)remediation systems for arsenic removal

    Science.gov (United States)

    Debiec, Klaudia; Rzepa, Grzegorz; Bajda, Tomasz; Uhrynowski, Witold; Sklodowska, Aleksandra; Krzysztoforski, Jan; Drewniak, Lukasz

    2018-03-01

    The main element of PbRS (passive (bio)remediation systems) are sorbents, which act as natural filters retaining heavy metals and carriers of microorganisms involved in water treatment. Thus, the effectiveness of PbRS is determined by the quality of the (ad)sorbents, which should be stable under various environmental conditions, have a wide range of applications and be non-toxic to (micro)organisms used in these systems. Our previous studies showed that bog iron ores (BIOs) meet these requirements. However, further investigation of the physical and chemical parameters of BIOs under environmental conditions is required before their large-scale application in PbRS. The aim of this study was (i) to investigate the ability of granulated BIOs (gBIOs) to remove arsenic from various types of contaminated waters, and (ii) to estimate the application potential of gBIOs in technologies dedicated to water treatment. These studies were conducted on synthetic solutions of arsenic and environmental samples of arsenic contaminated water using a set of adsorption columns filled with gBIOs. The experiments performed in a static system revealed that gBIOs are appropriate arsenic and zinc adsorbent. Dynamic adsorption studies confirmed these results and showed that the actual sorption efficiency of gBIOs depends on the adsorbate concentration and is directly proportional to them. Desorption analysis showed that As-loaded gBIOs are characterized by high chemical stability and they may be reused for the (ad)sorption of other elements, i.e. zinc. It was also shown that gBIOs may be used for remediation of both highly oxygenated waters and groundwater or settling ponds, where the oxygen level is low, as both forms of inorganic arsenic (arsenate and arsenite) were effectively removed. Arsenic concentration after treatment was <100 µg/L, which is below the limit for industrial water.

  10. PCB-induced changes of a benthic community and expected ecosystem recovery following in situ sorbent amendment

    Science.gov (United States)

    Janssen, Elisabeth M.-L.; Thompson, Janet K.; Luoma, Samuel N.; Luthy, Richard G.

    2011-01-01

    The benthic community was analyzed to evaluate pollution-induced changes for the polychlorinated biphenyl (PCB)-contaminated site at Hunters Point (HP) relative to 30 reference sites in San Francisco Bay, California, USA. An analysis based on functional traits of feeding, reproduction, and position in the sediment shows that HP is depauperate in deposit feeders, subsurface carnivores, and species with no protective barrier. Sediment chemistry analysis shows that PCBs are the major risk drivers at HP (1,570 ppb) and that the reference sites contain very low levels of PCB contamination (9 ppb). Different feeding traits support the existence of direct pathways of exposure, which can be mechanistically linked to PCB bioaccumulation by biodynamic modeling. The model shows that the deposit feeder Neanthes arenaceodentata accumulates approximately 20 times more PCBs in its lipids than the facultative deposit feeder Macoma balthica and up to 130 times more than the filter feeder Mytilus edulis. The comparison of different exposure scenarios suggests that PCB tissue concentrations at HP are two orders of magnitude higher than at the reference sites. At full scale, in situ sorbent amendment with activated carbon may reduce PCB bioaccumulation at HP by up to 85 to 90% under favorable field and treatment conditions. The modeling framework further demonstrates that such expected remedial success corresponds to exposure conditions suggested as the cleanup goal for HP. However, concentrations remain slightly higher than at the reference sites. The present study demonstrates how the remedial success of a sorbent amendment, which lowers the PCB availability, can be compared to reference conditions and traditional cleanup goals, which are commonly based on bulk sediment concentrations.

  11. Advanced sorbent development progam; development of sorbents for moving-bed and fluidized-bed applications

    International Nuclear Information System (INIS)

    Ayala, R.E.; Venkataramani, V.S.

    1998-01-01

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and

  12. Advanced regenerative heat recovery system

    Science.gov (United States)

    Prasad, A.; Jasti, J. K.

    1982-02-01

    A regenerative heat recovery system was designed and fabricated to deliver 1500 scfm preheated air to a maximum temperature of 1600 F. Since this system is operating at 2000 F, the internal parts were designed to be fabricated with ceramic materials. This system is also designed to be adaptable to an internal metallic structure to operate in the range of 1100 to 1500 F. A test facility was designed and fabricated to test this system. The test facility is equipped to impose a pressure differential of up to 27 inches of water column in between preheated air and flue gas lines for checking possible leakage through the seals. The preliminary tests conducted on the advanced regenerative heat recovery system indicate the thermal effectiveness in the range of 60% to 70%. Bench scale studies were conducted on various ceramic and gasket materials to identify the proper material to be used in high temperature applications. A market survey was conducted to identify the application areas for this heat recovery system. A cost/benefit analysis showed a payback period of less than one and a half years.

  13. Multimodal flow visualization and optimization of pneumatic blood pump for sorbent hemodialysis system.

    Science.gov (United States)

    Shu, Fangjun; Parks, Robert; Maholtz, John; Ash, Steven; Antaki, James F

    2009-04-01

    Renal Solutions Allient Sorbent Hemodialysis System utilizes a two-chambered pneumatic pump (Pulsar Blood Pump, Renal Solutions, Inc., Warrendale, PA, USA) to avoid limitations associated with peristaltic pumping systems. Single-needle access is enabled by counter-pulsing the two pump chambers, thereby obviating compliance chambers or blood reservoirs. Each chamber propels 20 cc per pulse of 3 s (dual access) or 6 s (single access) duration, corresponding to a peak Reynolds number of approximately 8000 (based on inlet velocity and chamber diameter). A multimodal series of flow visualization studies (tracer particle, dye washout, and dye erosion) was conducted on a sequence of pump designs with varying port locations and diaphragms to improve the geometry with respect to risk of thrombogenesis. Experiments were conducted in a simplified flow loop using occluders to simulate flow resistance induced by tubing and dialyzer. Tracer visualization revealed flow patterns and qualitatively indicated turbulence intensity. Dye washout identified dwell volume and areas of flow stagnation for each design. Dye erosion results indicated the effectiveness and homogeneity of surface washing. Compared to a centered inlet which resulted in a fluid jet that produced two counter-rotating vortices, a tangential inlet introduced a single vortex, and kept the flow laminar. It also provided better surface washing on the pump inner surface. However, a tangential outlet did not present as much benefit as expected. On the contrary, it created a sharp defection to the flow when transiting from filling to ejection.

  14. PROCEEDINGS: MULTIPOLLUTANT SORBENT REACTIVITY ...

    Science.gov (United States)

    The report is a compilation of technical papers and visual aids presented by representatives of industry, academia, and government agencies at a workshop on multipollutant sorbent reactivity that was held at EPA's Environmental Research Center in Research Triangle Park, NC, on July 19-20, 1994. There were 16 technical presentations in three sessions, and a panel discussion between six research experts. The workshop was a forum for the exchange of ideas and information on the use of sorbents to control air emissions of acid gases (sulfur dioxide, nitrogen oxides, and hydrogen chloride); mercury and dioxins; and toxic metals, primarily from fossil fuel combustion. A secondary purpose for conducting the workshop was to help guide EPA's research planning activities. A general theme of the workshop was that a strategy of controlling many pollutants with a single system rather than systems to control individual pollutants should be a research goal. Some research needs cited were: hazardous air pollutant removal by flue gas desulfurization systems, dioxin formation and control, mercury control, waste minimization, impact of ash recycling on metals partitioning, impact of urea and sorbents on other pollutants, high temperature filtration, impact of coal cleaning on metals partitioning, and modeling dispersion of sorbents in flue gas. information

  15. Design and Development of New Carbon-Based Sorbent Systems for an Effective Containment of Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Alan C. Cooper

    2012-05-03

    This is a summary for work performed under cooperative agreement DE FC36 04GO14006 (Design and Development of New Carbon-based Sorbent Systems for an Effective Containment of Hydrogen). The project was directed to discover new solid and liquid materials that use reversible catalytic hydrogenation as the mechanism for hydrogen capture and storage. After a short period of investigation of solid materials, the inherent advantages of storing and transporting hydrogen using liquid-phase materials focused our attention exclusively on organic liquid hydrogen carriers (liquid carriers). While liquid carriers such as decalin and methylcyclohexane were known in the literature, these carriers suffer from practical disadvantages such as the need for very high temperatures to release hydrogen from the carriers and difficult separation of the carriers from the hydrogen. In this project, we were successful in using the prediction of reaction thermodynamics to discover liquid carriers that operate at temperatures up to 150 C lower than the previously known carriers. The means for modifying the thermodynamics of liquid carriers involved the use of certain molecular structures and incorporation of elements other than carbon into the carrier structure. The temperature decrease due to the more favorable reaction thermodynamics results in less energy input to release hydrogen from the carriers. For the first time, the catalytic reaction required to release hydrogen from the carriers could be conducted with the carrier remaining in the liquid phase. This has the beneficial effect of providing a simple means to separate the hydrogen from the carrier.

  16. DOLOMITE THERMAL-DECOMPOSITION MACROKINETIC MODELS FOR EVALUATION OF THE GASGENERATORS SORBENT SYSTEMS

    Directory of Open Access Journals (Sweden)

    K. V. Dobrego

    2015-01-01

    Full Text Available Employing dolomite in the capacity of a sorbent for generator gas purification is of considerable interest nowadays, as it is the impurity of generator gas that causes the major problem for creating cheep and effective co-generator plants. Designing gas purification systems employs simple but physically adequate macrokinetic models of dolomite thermal decomposition.  The  paper  analyzes  peculiarities  of  several  contemporaneous  models  of  dolomite and calcite thermal decomposition and infers on reasonable practicality for creating compact engineering dolomite-decomposition macrokinetic models and universal techniques of these models parameter reconstruction for specific dolomite samples. Such technics can be founded on thermogravimetric data and standard approximation error minimizing algorithms.The author assumes that CO2  evacuation from the reaction zone within the particle may proceed by diffusion mechanism and/or by the Darcy filtration and indicates that functional dependence of the thermal-decomposition rate from the particle sizes and the temperature differs for the specified mechanisms. The paper formulates four macrokinetic models whose correspondence verification is grounded on the experimental data. The author concludes that further work in this direction should proceed with the dolomite samples investigation and selecting the best approximation model describing experimental data in wide range of temperatures, warming up rates and the particle sizes.

  17. Granulated Bog Iron Ores as Sorbents in Passive (BioRemediation Systems for Arsenic Removal

    Directory of Open Access Journals (Sweden)

    Klaudia Debiec

    2018-03-01

    Full Text Available The main element of PbRS (passive (bioremediation systems are sorbents, which act as natural filters retaining heavy metals and carriers of microorganisms involved in water treatment. Thus, the effectiveness of PbRS is determined by the quality of the (adsorbents, which should be stable under various environmental conditions, have a wide range of applications and be non-toxic to (microorganisms used in these systems. Our previous studies showed that bog iron ores (BIOs meet these requirements. However, further investigation of the physical and chemical parameters of BIOs under environmental conditions is required before their large-scale application in PbRS. The aim of this study was (i to investigate the ability of granulated BIOs (gBIOs to remove arsenic from various types of contaminated waters, and (ii to estimate the application potential of gBIOs in technologies dedicated to water treatment. These studies were conducted on synthetic solutions of arsenic and environmental samples of arsenic contaminated water using a set of adsorption columns filled with gBIOs. The experiments performed in a static system revealed that gBIOs are appropriate arsenic and zinc adsorbent. Dynamic adsorption studies confirmed these results and showed, that the actual sorption efficiency of gBIOs depends on the adsorbate concentration and is directly proportional to them. Desorption analysis showed that As-loaded gBIOs are characterized by high chemical stability and they may be reused for the (adsorption of other elements, i.e., zinc. It was also shown that gBIOs may be used for remediation of both highly oxygenated waters and groundwater or settling ponds, where the oxygen level is low, as both forms of inorganic arsenic (arsenate and arsenite were effectively removed. Arsenic concentration after treatment was <100 μg/L, which is below the limit for industrial water.

  18. Launch and Recovery System Literature Review

    Science.gov (United States)

    2010-12-01

    water. Goldie [21] suggests a sled or cart recovery system for use with UAV’s on the Littoral Combatant Ship (LCS) and other small deck navy ships...21. Goldie , J., “A Recovery System for Unmanned Aerial Vehicles (UAVs) Aboard LCS and other Small-Deck Navy Ships,” ASNE Launch and Recovery of

  19. Microbial Heat Recovery Cell (MHRC) System Concept

    Energy Technology Data Exchange (ETDEWEB)

    None

    2017-09-01

    This factsheet describes a project that aimed to develop a microbial heat recovery cell (MHRC) system that combines a microbial reverse electrodialysis technology with waste heat recovery to convert industrial effluents into electricity and hydrogen.

  20. Studies on uranium recovery from inlet stream of Effluent Treatment Plant by novel 'In-House' sorbent

    International Nuclear Information System (INIS)

    Sangita Pal; Tewari, P.K.; Suchismita Mishra; Pandit, G.G.; Puranik, V.D.; Satpati, S.K.

    2011-01-01

    'In-House' resin Polyacrylhydroxamic acid (PHOA) has been synthesized and utilized targeting ground water remediation; recovery of uranium from low concentration aqueous solution e.g., mining activities related water, flooding of excavated or deplumed areas, nuclear plant washed effluent and process generated effluents in nuclear plant during front-end as well as back-end treatment. In the present study, treatment of field effluent containing heavy metals and radio-nuclides from contaminated mining sites reflected preference for uranium with respect to manganese. The specific complexation between the extractant and metal ion especially uranium provides high distribution co-efficient (K d ) for uranium (K d,U = 1,450 mL/g from inlet of Effluent Treatment Plant (ETP) and K d,U = 74,950 mL/g for synthetic solution) compared to high level impurity (1,000 times higher concentration) of manganese (K d,Mn = 111 mL/g from inlet of ETP and K d,Mn = 10,588 mL/g for synthetic solution). The 'In-House' resin showed significant extractability (70-95% elution efficiency) and indicates a possibility of selective removal/recovery of the valuable metal ions even from secondary sources. As a specialty, resin can be regenerated and reused. (author)

  1. Heat recovery system series arrangements

    Science.gov (United States)

    Kauffman, Justin P.; Welch, Andrew M.; Dawson, Gregory R.; Minor, Eric N.

    2017-11-14

    The present disclosure is directed to heat recovery systems that employ two or more organic Rankine cycle (ORC) units disposed in series. According to certain embodiments, each ORC unit includes an evaporator that heats an organic working fluid, a turbine generator set that expands the working fluid to generate electricity, a condenser that cools the working fluid, and a pump that returns the working fluid to the evaporator. The heating fluid is directed through each evaporator to heat the working fluid circulating within each ORC unit, and the cooling fluid is directed through each condenser to cool the working fluid circulating within each ORC unit. The heating fluid and the cooling fluid flow through the ORC units in series in the same or opposite directions.

  2. Life Support Systems: Oxygen Generation and Recovery

    Data.gov (United States)

    National Aeronautics and Space Administration — The Advanced Exploration Systems (AES) Life Support Systems project Oxygen Generation and Recovery technology development area encompasses several sub-tasks in an...

  3. Novel sorbents for environmental remediation

    Science.gov (United States)

    Manariotis, Ioannis D.; Karapanagioti, Hrissi K.; Werner, David

    2014-05-01

    Nowadays, one of the major environmental problems is the pollution of aquatic systems and soil by persistent pollutants. Persistent pollutants have been found widespread in sediments, surface waters, and drinking water supplies. The removal of pollutants can be accomplished prior to their discharge to receiving bodies or by immobilizing them onto soil. Sorption is the most commonly applied process, and activated carbons have been widely used. Rapid progress in nanotechnology and a new focus on biomass-based instead of non-renewable starting materials have produced a wide range of novel engineered sorbents including biosorbents, biochars, carbon-based nanoparticles, bio-nano hybrid materials, and iron-impregnated activated carbons. Sorbent materials have been used in environmental remediation processes and especially in agricultural soil, sediments and contaminated soil, water treatment, and industrial wastewater treatment. Furthermore, sorbents may enhance the synergistic action of other processes, such as volatilization and biodegradation. Novel sorbents have been employed for the removal or immobilization of persistent pollutants such as and include heavy metals (As, Cr, Cu, Pb, Cd, and Hg), halogenated organic compounds, endocrine disrupting chemicals, metalloids and non-metallic elements, and other organic pollutants. The development and evaluation of novel sorbents requires a multidisciplinary approach encompassing environmental, nanotechnology, physical, analytical, and surface chemistry. The necessary evaluations encompass not only the efficiency of these materials to remove pollutants from surface waters and groundwater, industrial wastewater, polluted soils and sediments, etc., but also the potential side-effects of their environmental applications. The aim of this work is to present the results of the use of biochar and impregnated carbon sorbents for the removal of organic pollutants and metals. Furthermore, the new findings from the forthcoming session

  4. Split heat pipe heat recovery system

    OpenAIRE

    E. Azad

    2008-01-01

    This paper describes a theoretical analysis of a split heat pipe heat recovery system. The analysis is based on an Effectiveness-NTU approach to deduce its heat transfer characteristics. In this study the variation of overall effectiveness of heat recovery with the number of transfer units are presented. Copyright , Manchester University Press.

  5. Long Life Moving-Bed Zinc Titanate Sorbent

    International Nuclear Information System (INIS)

    Copeland, Robert J.; Cesario, Mike; Feinberg, Daniel A.; Sibold, Jack; Windecker, Brian; Yang, Jing

    1997-01-01

    The objective of this work was to develop and test long-life sorbents for hot gas cleanup. Specifically, we measured the sulfur loading at space velocities typically used for absorption of H 2 S and regenerated the sorbent with diluted air for multiple cycles. Based on the experimental results, we prepared a conceptual design of the sorbent-fabrication system, and estimated the cost of sorbent production and of sulfur removal

  6. INFLUENCE OF SOLVENT AND SORBENT CHARACTERISTICS ON DISTRIBUTION OF PENTACHLOROPHENOL IN OCTANOL-WATER AND SOIL-WATER SYSTEMS

    Science.gov (United States)

    Sorbent and solvent characteristics influencing sorption of pentachlorophenol (PCP) were investigated. Analysis of aqueous sorption data for several sorbents over a broad pH range suggested hydrophobic sorption of neutral PCP predominates at pH 7. At pH > 7, sorption of the penta...

  7. System i Disaster Recovery Planning

    CERN Document Server

    Dolewski, Richard

    2008-01-01

    Mapping out all the preparations necessary for an effective disaster recovery plan and its safeguard-a continuous maintenance program-this guide is aimed at IT managers of small and medium businesses. The opening section covers the initial steps of auditing vulnerability, ranking essential IT functions, and reviewing the storage of tape backups, with the following discussion focused on the elements of the plan itself. The plan includes a mission statement, a definition of disaster, the assignment of staff to teams, methods of compensating for human error, and standards for documenting the step

  8. Rankine cycle waste heat recovery system

    Science.gov (United States)

    Ernst, Timothy C.; Nelson, Christopher R.

    2014-08-12

    This disclosure relates to a waste heat recovery (WHR) system and to a system and method for regulation of a fluid inventory in a condenser and a receiver of a Rankine cycle WHR system. Such regulation includes the ability to regulate the pressure in a WHR system to control cavitation and energy conversion.

  9. Proportional hazards models of infrastructure system recovery

    International Nuclear Information System (INIS)

    Barker, Kash; Baroud, Hiba

    2014-01-01

    As emphasis is being placed on a system's ability to withstand and to recover from a disruptive event, collectively referred to as dynamic resilience, there exists a need to quantify a system's ability to bounce back after a disruptive event. This work applies a statistical technique from biostatistics, the proportional hazards model, to describe (i) the instantaneous rate of recovery of an infrastructure system and (ii) the likelihood that recovery occurs prior to a given point in time. A major benefit of the proportional hazards model is its ability to describe a recovery event as a function of time as well as covariates describing the infrastructure system or disruptive event, among others, which can also vary with time. The proportional hazards approach is illustrated with a publicly available electric power outage data set

  10. Flight Path Recovery System (FPRS) design study

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-01

    The study contained herein presents a design for a Flight Path Recovery System (FPPS) for use in the NURE Program which will be more accurate than systems presently used, provide position location data in digital form suitable for automatic data processing, and provide for flight path recovery in a more economic and operationally suitable manner. The design is based upon the use of presently available hardware and technoloy, and presents little, it any, development risk. In addition, a Flight Test Plan designed to test the FPRS design concept is presented.

  11. Flight Path Recovery System (FPRS) design study

    International Nuclear Information System (INIS)

    1978-09-01

    The study contained herein presents a design for a Flight Path Recovery System (FPPS) for use in the NURE Program which will be more accurate than systems presently used, provide position location data in digital form suitable for automatic data processing, and provide for flight path recovery in a more economic and operationally suitable manner. The design is based upon the use of presently available hardware and technoloy, and presents little, it any, development risk. In addition, a Flight Test Plan designed to test the FPRS design concept is presented

  12. Enhancement of gravimetric forced flow through system to determine sorption, swelling, and mass transfer characteristics of liquid sorbents

    Science.gov (United States)

    Dresp, G.; Petermann, M.; Fieback, T. M.

    2018-04-01

    An existing apparatus for forced flow through of liquid sorbents has been enhanced with an optically accessible system including a transparent crucible, high pressure viewing cell, and camera. With this optical system, the active surface area between gas and liquid can be determined in situ for the first time under industrial process conditions while maintaining the accuracy of a magnetic suspension balance. Additionally, occurring swelling and the resulting buoyancy changes can now be corrected, further improving the quality of the data. Validation measurements focusing on the sorption isotherms, swelling, and bubble geometry of 1-butyl-3-methylimidazolium tetrafluoroborate with nitrogen at 303 K and up to 17 MPa, as well as with carbon dioxide at 303 K, 323 K, and 373 K at up to 3.5 MPa were completed. Absorption of nitrogen resulted in no observable volume change, whereas absorption of carbon dioxide resulted in temperature independent swelling of up to 9.8%. The gas bubble's structure and behavior during its ascend through the liquid was optically tracked in situ. Combining these two data sets with the absorption kinetics forms the basis to determine the measuring system independent mass transfer coefficients, which are applicable in other laboratory scale and industrial processes.

  13. Hydrogen Purification and Recycling for an Integrated Oxygen Recovery System Architecture

    Science.gov (United States)

    Abney, Morgan B.; Greenwood, Zachary; Wall, Terry; Miller, Lee; Wheeler, Ray

    2016-01-01

    The United States Atmosphere Revitalization life support system on the International Space Station (ISS) performs several services for the crew including oxygen generation, trace contaminant control, carbon dioxide (CO2) removal, and oxygen recovery. Oxygen recovery is performed using a Sabatier reactor developed by Hamilton Sundstrand, wherein CO2 is reduced with hydrogen in a catalytic reactor to produce methane and water. The water product is purified in the Water Purification Assembly and recycled to the Oxygen Generation Assembly (OGA) to provide O2 to the crew. This architecture results in a theoretical maximum oxygen recovery from CO2 of approximately 54% due to the loss of reactant hydrogen in Sabatier-produced methane that is currently vented outside of ISS. Plasma Methane Pyrolysis technology (PPA), developed by Umpqua Research Company, provides the capability to further close the Atmosphere Revitalization oxygen loop by recovering hydrogen from Sabatier-produced methane. A key aspect of this technology approach is to purify the hydrogen from the PPA product stream which includes acetylene, unreacted methane and byproduct water and carbon monoxide. In 2015, four sub-scale hydrogen separation systems were delivered to NASA for evaluation. These included two electrolysis single-cell hydrogen purification cell stacks developed by Sustainable Innovations, LLC, a sorbent-based hydrogen purification unit using microwave power for sorbent regeneration developed by Umpqua Research Company, and a LaNi4.6Sn0.4 metal hydride produced by Hydrogen Consultants, Inc. Here we report the results of these evaluations, discuss potential architecture options, and propose future work.

  14. Uses and abuses of recovery: implementing recovery-oriented practices in mental health systems

    Science.gov (United States)

    Slade, Mike; Amering, Michaela; Farkas, Marianne; Hamilton, Bridget; O'Hagan, Mary; Panther, Graham; Perkins, Rachel; Shepherd, Geoff; Tse, Samson; Whitley, Rob

    2014-01-01

    An understanding of recovery as a personal and subjective experience has emerged within mental health systems. This meaning of recovery now underpins mental health policy in many countries. Developing a focus on this type of recovery will involve transformation within mental health systems. Human systems do not easily transform. In this paper, we identify seven mis-uses (“abuses”) of the concept of recovery: recovery is the latest model; recovery does not apply to “my” patients; services can make people recover through effective treatment; compulsory detention and treatment aid recovery; a recovery orientation means closing services; recovery is about making people independent and normal; and contributing to society happens only after the person is recovered. We then identify ten empirically-validated interventions which support recovery, by targeting key recovery processes of connectedness, hope, identity, meaning and empowerment (the CHIME framework). The ten interventions are peer support workers, advance directives, wellness recovery action planning, illness management and recovery, REFOCUS, strengths model, recovery colleges or recovery education programs, individual placement and support, supported housing, and mental health trialogues. Finally, three scientific challenges are identified: broadening cultural understandings of recovery, implementing organizational transformation, and promoting citizenship. PMID:24497237

  15. Desulfurization sorbent regeneration

    Science.gov (United States)

    Jalan, V.M.; Frost, D.G.

    1982-07-07

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

  16. General Atomic's radioactive gas recovery system

    International Nuclear Information System (INIS)

    Mahn, J.A.; Perry, C.A.

    1975-01-01

    General Atomic Company has developed a Radioactive Gas Recovery System for the HTGR which separates, for purposes of retention, the radioactive components from the non-radioactive reactor plant waste gases. This provides the capability for reducing to an insignificant level the amount of radioactivity released from the gas waste system to the atmosphere--a most significant improvement in reducing total activity release to the environment. (U.S.)

  17. Kinetic energy recovery systems in motor vehicles

    Science.gov (United States)

    Śliwiński, C.

    2016-09-01

    The article draws attention to the increasing environmental pollution caused by the development of vehicle transport and motorization. Different types of design solutions used in vehicles for the reduction of fuel consumption, and thereby emission of toxic gasses into the atmosphere, were specified. Historical design solutions concerning energy recovery devices in mechanical vehicles which used flywheels to accumulate kinetic energy were shown. Developmental tendencies in the area of vehicle manufacturing in the form of hybrid electric and electric devices were discussed. Furthermore, designs of energy recovery devices with electrical energy storage from the vehicle braking and shock absorbing systems were presented. A mechanical energy storing device using a flywheel operating under vacuum was presented, as were advantages and disadvantages of both systems, the limitations they impose on individual constructions and safety issues. The paper also discusses a design concept of an energy recovery device in mechanical vehicles which uses torsion springs as the main components of energy accumulation during braking. The desirability of a cooperation of both the mechanical- and electrical energy recovery devices was indicated.

  18. Recovery of the immune system after exercise.

    Science.gov (United States)

    Peake, Jonathan M; Neubauer, Oliver; Walsh, Neil P; Simpson, Richard J

    2017-05-01

    The notion that prolonged, intense exercise causes an "open window" of immunodepression during recovery after exercise is well accepted. Repeated exercise bouts or intensified training without sufficient recovery may increase the risk of illness. However, except for salivary IgA, clear and consistent markers of this immunodepression remain elusive. Exercise increases circulating neutrophil and monocyte counts and reduces circulating lymphocyte count during recovery. This lymphopenia results from preferential egress of lymphocyte subtypes with potent effector functions [e.g., natural killer (NK) cells, γδ T cells, and CD8 + T cells]. These lymphocytes most likely translocate to peripheral sites of potential antigen encounter (e.g., lungs and gut). This redeployment of effector lymphocytes is an integral part of the physiological stress response to exercise. Current knowledge about changes in immune function during recovery from exercise is derived from assessment at the cell population level of isolated cells ex vivo or in blood. This assessment can be biased by large changes in the distribution of immune cells between blood and peripheral tissues during and after exercise. Some evidence suggests that reduced immune cell function in vitro may coincide with changes in vivo and rates of illness after exercise, but more work is required to substantiate this notion. Among the various nutritional strategies and physical therapies that athletes use to recover from exercise, carbohydrate supplementation is the most effective for minimizing immune disturbances during exercise recovery. Sleep is an important aspect of recovery, but more research is needed to determine how sleep disruption influences the immune system of athletes. Copyright © 2017 the American Physiological Society.

  19. A regenerable potassium and phosphate sorbent system to enhance dialysis efficacy and device portability: an in vitro study.

    Science.gov (United States)

    Wester, Maarten; Simonis, Frank; Gerritsen, Karin G; Boer, Walther H; Wodzig, Will K; Kooman, Jeroen P; Joles, Jaap A

    2013-09-01

    Continuous dialysis could provide benefit by constant removal of potassium and phosphate. This study investigates the suitability of specific potassium and phosphate sorbents for incorporation in an extracorporeal device by capacity and regenerability testing. Capacity testing was performed in uraemic plasma. Regenerability was tested for potassium sorbents, with adsorption based on cationic exchange for sodium, with 0.1 M and 1.0 M NaCl. To regenerate phosphate sorbents, with adsorption based on anionic exchange, 0.1 M and 1.0 M NaHCO3 and NaOH were used. Subsequently, sodium polystyrene divinylbenzene sulphonate (RES-A) and iron oxide hydroxide (FeOOH) beads were incorporated in a cartridge for testing in bovine blood using a recirculating blood circuit and a dialysis circuit separated by a high-flux dialyzer (dynamic setup). Preloading was tested to assess whether this could limit calcium and magnesium adsorption. In the batch-binding assays, zirconium phosphate most potently adsorbed potassium (0.44 ± 0.05 mmol/g) and RES-A was the best regenerable potassium sorbent (92.9 ± 5.7% with 0.1 M NaCl). Zirconium oxide hydroxide (ZIR-hydr) most potently adsorbed phosphate (0.23 ± 0.05 mmol/g) and the polymeric amine sevelamer carbonate was the best regenerable sorbent (85.7 ± 5.2% with 0.1 M NaHCO3). In the dynamic setup, a potassium adsorption of 10.72 ± 2.06 mmol in 3 h was achieved using 111 g of RES-A and a phosphate adsorption of 4.73 ± 0.53 mmol in 3 h using 55 g of FeOOH. Calcium and magnesium preloading was shown to reduce the net adsorption in 3 h from 3.57 ± 0.91 to -0.29 ± 1.85 and 1.02 ± 0.05 to -0.31 ± 0.18 mmol, respectively. RES-A and FeOOH are suitable, regenerizable sorbents for potassium and phosphate removal in dialysate regeneration. Use of zirconium carbonate and ZIR-hydr may further increase phosphate adsorption, but may compromise sorbent regenerability. Use of polymeric amines for phosphate adsorption may enhance sorbent

  20. Sorbent Scoping Studies

    International Nuclear Information System (INIS)

    Chancellor, Christopher John

    2016-01-01

    The Los Alamos National Laboratory-Carlsbad Operations (LANL-CO) office was tasked by the DOE CBFO, Office of the Manager to perform a review of the acceptable knowledge (AK) to identify the oxidizers and sorbents in transuranic (TRU) waste streams, to conduct scoping studies on the oxidizers and sorbents identified in AK review to inform the Quality Level 1 (QL1) testing, and to conduct a series of QL1 tests to provide the scientific data to support a basis of knowledge document for determining the criteria for (1) accepting waste at the Waste Isolation Pilot Plant (WIPP) without treatment, (2) determining waste that will require treatment, and (3) if treatment is required, how the treatment must be performed. The purpose of this report is to present the results of the AK review of sorbents present in active waste streams, provide a technical analysis of the sorbent list, report the results of the scoping studies for the fastest-burning organic sorbent, and provide the list of organic and inorganic sorbents to be used in the development of a Test Plan for Preparation and Testing of Sorbents Mixed with Oxidizer found in Transuranic Waste (DWT-TP-001). The companion report, DWT-RPT-001, Oxidizer Scoping Studies, has similar information for oxidizers identified during the AK review of TRU waste streams. The results of the oxidizer and sorbent scoping studies will be used to inform the QL1 test plan. The QL1 test results will support the development of a basis of knowledge document that will evaluate oxidizing chemicals and sorbents in TRU waste and provide guidance for treatment.

  1. Sorbent Scoping Studies

    Energy Technology Data Exchange (ETDEWEB)

    Chancellor, Christopher John [Los Alamos National Lab. (LANL), Carlsbad, NM (United States). Difficult Waste Team

    2016-11-14

    The Los Alamos National Laboratory–Carlsbad Operations (LANL-CO) office was tasked by the DOE CBFO, Office of the Manager to perform a review of the acceptable knowledge (AK) to identify the oxidizers and sorbents in transuranic (TRU) waste streams, to conduct scoping studies on the oxidizers and sorbents identified in AK review to inform the Quality Level 1 (QL1) testing, and to conduct a series of QL1 tests to provide the scientific data to support a basis of knowledge document for determining the criteria for (1) accepting waste at the Waste Isolation Pilot Plant (WIPP) without treatment, (2) determining waste that will require treatment, and (3) if treatment is required, how the treatment must be performed. The purpose of this report is to present the results of the AK review of sorbents present in active waste streams, provide a technical analysis of the sorbent list, report the results of the scoping studies for the fastest-burning organic sorbent, and provide the list of organic and inorganic sorbents to be used in the development of a Test Plan for Preparation and Testing of Sorbents Mixed with Oxidizer found in Transuranic Waste (DWT-TP-001). The companion report, DWT-RPT-001, Oxidizer Scoping Studies, has similar information for oxidizers identified during the AK review of TRU waste streams. The results of the oxidizer and sorbent scoping studies will be used to inform the QL1 test plan. The QL1 test results will support the development of a basis of knowledge document that will evaluate oxidizing chemicals and sorbents in TRU waste and provide guidance for treatment.

  2. Use of two-phase aqueous systems based on water-soluble polymers in thin-layer and extraction chromatography for recovery and separtion of actinides

    International Nuclear Information System (INIS)

    Molochnikova, N.P.; Shkinev, V.M.; Myasoedov, B.F.

    1995-01-01

    The feasibility has been demonstrated of using two-phase aqueous systems based on water-soluble polymers, polyethylene glycol and dextran sulfate, in thin-layer and extraction chromatography for recovery and separation of actinides. A convenient method has been proposed for continuous recovery of 239 Np from 243 Am, originating from differences in sorption of tri- and pentavalent actinides from sulfate solutions containing potassium phosphotungstate by silica gel impregnated with polyethylene glycol. New plates for thin-layer chromatography using water-soluble polymers have been developed. These plates were used to study behavior of americium in various oxidation states in thin sorbent layers

  3. Recovery of the Education System in Myanmar

    Directory of Open Access Journals (Sweden)

    Martin Hayden And Richard Martin

    2013-10-01

    Full Text Available Myanmar's education system is in a very weakened state. The physical condition and human resource capacity of the system is poor by any standard, and teachers, whether in schools, colleges or universities, have few opportunities and little incentive for professional development. A process of recovery is getting underway, but it will take years before significant improvements are evident. Major cultural change is required in the style of leadership and management at all levels of government, and there is also a desperate need for more financial resources. This paper documents the current state of the education system in Myanmar and advances three priority areas for immediate attention.

  4. Aminosilicone solvent recovery methods and systems

    Science.gov (United States)

    Spiry, Irina Pavlovna; Perry, Robert James; Wood, Benjamin Rue; Singh, Surinder Prabhjot; Farnum, Rachel Lizabeth; Genovese, Sarah Elizabeth

    2018-02-13

    The present invention is directed to aminosilicone solvent recovery methods and systems. The methods and systems disclosed herein may be used to recover aminosilicone solvent from a carbon dioxide containing vapor stream, for example, a vapor stream that leaves an aminosilicone solvent desorber apparatus. The methods and systems of the invention utilize a first condensation process at a temperature from about 80.degree. C. to about 150.degree. C. and a second condensation process at a temperature from about 5.degree. C. to about 75.degree. C. The first condensation process yields recovered aminosilicone solvent. The second condensation process yields water.

  5. Mercury removal sorbents

    Science.gov (United States)

    Alptekin, Gokhan

    2016-03-29

    Sorbents and methods of using them for removing mercury from flue gases over a wide range of temperatures are disclosed. Sorbent materials of this invention comprise oxy- or hydroxyl-halogen (chlorides and bromides) of manganese, copper and calcium as the active phase for Hg.sup.0 oxidation, and are dispersed on a high surface porous supports. In addition to the powder activated carbons (PACs), this support material can be comprised of commercial ceramic supports such as silica (SiO.sub.2), alumina (Al.sub.2O.sub.3), zeolites and clays. The support material may also comprise of oxides of various metals such as iron, manganese, and calcium. The non-carbon sorbents of the invention can be easily injected into the flue gas and recovered in the Particulate Control Device (PCD) along with the fly ash without altering the properties of the by-product fly ash enabling its use as a cement additive. Sorbent materials of this invention effectively remove both elemental and oxidized forms of mercury from flue gases and can be used at elevated temperatures. The sorbent combines an oxidation catalyst and a sorbent in the same particle to both oxidize the mercury and then immobilize it.

  6. CO2 Capacity Sorbent Analysis Using Volumetric Measurement Approach

    Science.gov (United States)

    Huang, Roger; Richardson, Tra-My Justine; Belancik, Grace; Jan, Darrell; Knox, Jim

    2017-01-01

    In support of air revitalization system sorbent selection for future space missions, Ames Research Center (ARC) has performed CO2 capacity tests on various solid sorbents to complement structural strength tests conducted at Marshall Space Flight Center (MSFC). The materials of interest are: Grace Davison Grade 544 13X, Honeywell UOP APG III, LiLSX VSA-10, BASF 13X, and Grace Davison Grade 522 5A. CO2 capacity was for all sorbent materials using a Micromeritics ASAP 2020 Physisorption Volumetric Analysis machine to produce 0C, 10C, 25C, 50C, and 75C isotherms. These data are to be used for modeling data and to provide a basis for continued sorbent research. The volumetric analysis method proved to be effective in generating consistent and repeatable data for the 13X sorbents, but the method needs to be refined to tailor to different sorbents.

  7. Recovery evaluation of organophosphorus pesticides from bee pollen by matrix solid-phase dispersion extraction using sorbents based on silica and titania

    International Nuclear Information System (INIS)

    Torres-Perea, C; Muñoz-Rodríguez, D; Carrera-Figueiras, C; Medina-Peralta, S; Moguel-Ordóñez, Y B

    2013-01-01

    This work focused on the evaluation of the recovery of organophosphorus pesticides from bee pollen after matrix solid phase-dispersion extraction (MSPD). Materials based on silica, titania and titania modified with polivylnylimidazole or polyestirene were used as adsorbents for the extraction of pesticides. Small amounts of fortified pollen (0.1 g, at 1 micro-g/g of pesticides), adsorbent (0.4 g) and solvent elution (1 mL de acetonitrile – ACN) were used in the extractions. For recovery evaluation, pollen extracts were analyzed by gas chromatography coupled with mass spectrometry.

  8. Rankine cycle waste heat recovery system

    Science.gov (United States)

    Ernst, Timothy C.; Nelson, Christopher R.

    2015-09-22

    A waste heat recovery (WHR) system connects a working fluid to fluid passages formed in an engine block and/or a cylinder head of an internal combustion engine, forming an engine heat exchanger. The fluid passages are formed near high temperature areas of the engine, subjecting the working fluid to sufficient heat energy to vaporize the working fluid while the working fluid advantageously cools the engine block and/or cylinder head, improving fuel efficiency. The location of the engine heat exchanger downstream from an EGR boiler and upstream from an exhaust heat exchanger provides an optimal position of the engine heat exchanger with respect to the thermodynamic cycle of the WHR system, giving priority to cooling of EGR gas. The configuration of valves in the WHR system provides the ability to select a plurality of parallel flow paths for optimal operation.

  9. Alkaline sorbent injection for mercury control

    Science.gov (United States)

    Madden, Deborah A.; Holmes, Michael J.

    2002-01-01

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  10. Automated magnetic sorbent extraction based on octadecylsilane functionalized maghemite magnetic particles in a sequential injection system coupled with electrothermal atomic absorption spectrometry for metal determination.

    Science.gov (United States)

    Giakisikli, Georgia; Anthemidis, Aristidis N

    2013-06-15

    A new automatic sequential injection (SI) system for on-line magnetic sorbent extraction coupled with electrothermal atomic absorption spectrometry (ETAAS) has been successfully developed for metal determination. In this work, we reported effective on-line immobilization of magnetic silica particles into a microcolumn by the external force of two strong neodymium iron boron (NdFeB) magnets across it, avoiding the use of frits. Octadecylsilane functionalized maghemite magnetic particles were used as sorbent material. The potentials of the system were demonstrated for trace cadmium determination in water samples. The method was based on the on-line complex formation with diethyldithiocarbamate (DDTC), retention of Cd-DDTC on the surface of the MPs and elution with isobutyl methyl ketone (IBMK). The formation mechanism of the magnetic solid phase packed column and all critical parameters (chemical, flow, graphite furnace) influencing the performance of the system were optimized and offered good analytical characteristics. For 5 mL sample volume, a detection limit of 3 ng L(-1), a relative standard deviation of 3.9% at 50 ng L(-1) level (n=11) and a linear range of 9-350 ng L(-1) were obtained. The column remained stable for more than 600 cycles keeping the cost down in routine analysis. The proposed method was evaluated by analyzing certified reference materials and natural waters. Copyright © 2013 Elsevier B.V. All rights reserved.

  11. Performance assessment techniques for groundwater recovery and treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Kirkpatrick, G.L. [Environmental Resources Management, Inc., Exton, PA (United States)

    1993-03-01

    Groundwater recovery and treatment (pump and treat systems) continue to be the most commonly selected remedial technology for groundwater restoration and protection programs at hazardous waste sites and RCRA facilities nationwide. Implementing a typical groundwater recovery and treatment system includes the initial assessment of groundwater quality, characterizing aquifer hydrodynamics, recovery system design, system installation, testing, permitting, and operation and maintenance. This paper focuses on methods used to assess the long-term efficiency of a pump and treat system. Regulatory agencies and industry alike are sensitive to the need for accurate assessment of the performance and success of groundwater recovery systems for contaminant plume abatement and aquifer restoration. Several assessment methods are available to measure the long-term performance of a groundwater recovery system. This paper presents six assessment techniques: degree of compliance with regulatory agency agreement (Consent Order of Record of Decision), hydraulic demonstration of system performance, contaminant mass recovery calculation, system design and performance comparison, statistical evaluation of groundwater quality and preferably, integration of the assessment methods. Applying specific recovery system assessment methods depends upon the type, amount, and quality of data available. Use of an integrated approach is encouraged to evaluate the success of a groundwater recovery and treatment system. The methods presented in this paper are for engineers and corporate management to use when discussing the effectiveness of groundwater remediation systems with their environmental consultant. In addition, an independent (third party) system evaluation is recommended to be sure that a recovery system operates efficiently and with minimum expense.

  12. Design of engineered sorbent barriers

    International Nuclear Information System (INIS)

    Jones, E.O.; Freeman, H.D.

    1988-08-01

    A sorbent barrier uses sorbent material such as activated carbon or natural zeolites to prevent the migration of radionuclides from a low-level waste site to the aquifer. The sorbent barrier retards the movement of radioactive contaminants, thereby providing time for the radionuclides to decay. Sorbent barriers can be a simple, effective, and inexpensive method for reducing the migration of radionuclides to the environment. Designing a sorbent barrier consists of using soil and sorbent material properties and site conditions as input to a model which will determine the necessary sorbent barrier thickness to meet contaminant limits. The paper will cover the following areas: techniques for measuring sorption properties of barrier materials and underlying soils, use of a radionuclide transport model to determine the required barrier thickness and performance under a variety of site conditions, and cost estimates for applying the barrier. 8 refs., 6 figs., 1 tab

  13. Design of engineered sorbent barriers

    International Nuclear Information System (INIS)

    Jones, E.O.; Freeman, H.D.

    1988-01-01

    A sorbent barrier uses sorbent material such as activated carbon or natural zeolites to prevent the migration of radionuclides from a low-level waste site to the aquifer. The sorbent barrier retards the movement of radioactive contaminants, thereby providing time for the radionuclides to decay. Sorbent barriers can be a simple, effective, and inexpensive method for reducing the migration of radionuclides to the environment. Designing a sorbent barrier consists of using soil and sorbent material properties and site conditions as input to a model which will determine the necessary sorbent barrier thickness to meet contaminant limits. The paper covers the following areas: techniques for measuring sorption properties of barrier materials and underlying soils, use of a radionuclide transport model to determine the required barrier thickness and performance under a variety of site conditions, and cost estimates for applying the barrier

  14. Amoxicillin in a biological water recovery system

    International Nuclear Information System (INIS)

    Morse, A.; Jackson, A.; Rainwater, K.; Pickering, K.

    2002-01-01

    wastewater recovery system as a drinking water supply source. (author)

  15. F- and H-Area Seepage Basins Water Treatment System Process Optimization and Alternative Chemistry Ion Exchange/Sorbent Material Screening Clearwell Overflow Study

    Energy Technology Data Exchange (ETDEWEB)

    Serkiz, S.M.

    2000-08-30

    This study investigated alternative ion exchange/sorbent materials and polishing chemistries designed to remove specific radionuclides not removed during the neutralization/precipitation/clarification process.

  16. Desulfurization Sorbents for Transport-Bed Applications

    International Nuclear Information System (INIS)

    Gupta, Raghubir P.; Turk, Brian S.; Vierheilig, Albert A.

    1997-01-01

    This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. The specific objectives are: (1) To develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-(micro)m particle size range for transport reactor applications; (2) To transfer sorbent production technology to private sector; and (3) To provide technical support to Sierra Pacific Clean Coal Technology Demonstration plant and FETC's Hot-Gas Desulfurization Process Development Unit (PDU), both employing a transport reactor system

  17. Space Station Freedom regenerative water recovery system configuration selection

    Science.gov (United States)

    Reysa, R.; Edwards, J.

    1991-01-01

    The Space Station Freedom (SSF) must recover water from various waste water sources to reduce 90 day water resupply demands for a four/eight person crew. The water recovery system options considered are summarized together with system configuration merits and demerits, resource advantages and disadvantages, and water quality considerations used to select the SSF water recovery system.

  18. Preconcentration of traces of radionuclides with sorbents based on spherical polyurethane membrane systems in the analysis of environmental samples

    International Nuclear Information System (INIS)

    Palagyi, S.; Braun, T.

    1986-01-01

    In the paper the importance of preconcentration and a permanent need for efficient preconcentrating agents in environmental analysis are pointed out. The increased attention is devoted to the foamed polyurethane sorbents as a novel advance in the separation chemistry. The paper has two main aims. The first is to present a survey of recent applications of unloaded and reagent loaded open-cell type resilient polyurethane foams to the separation and preconcentration of radionuclides from environmental samples. The second is to show the newest results in the use of these foams for the preconcentration and determination of traces of some mainly inorganic species in environmental samples by radioanalytical techniques. Some future possibilities of the use of polyurethane foams in trace elemental determinations in environmental analysis are also outlined. (author)

  19. Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification

    KAUST Repository

    Lively, Ryan P.; Bessho, Naoki; Bhandari, Dhaval A.; Kawajiri, Yoshiaki; Koros, William J.

    2012-01-01

    We describe thermally moderated multi-layered pseudo-monolithic hollow fiber sorbents entities, which can be packed into compact modules to provide small-footprint, efficient H2 purification/CO2 removal systems for use in on-site steam methane reformer product gas separations. Dual-layer hollow fibers are created via dry-jet, wet-quench spinning with an inner "active" core of cellulose acetate (porous binder) and zeolite NaY (69 wt% zeolite NaY) and an external sheath layer of pure cellulose acetate. The co-spun sheath layer reduces the surface porosity of the fiber and was used as a smooth coating surface for a poly(vinyl-alcohol) post-treatment, which reduced the gas permeance through the fiber sorbent by at least 7 orders of magnitude, essentially creating an impermeable sheath layer. The interstitial volume between the individual fibers was filled with a thermally-moderating paraffin wax. CO2 breakthrough experiments on the hollow fiber sorbent modules with and without paraffin wax revealed that the "passively" cooled paraffin wax module had 12.5% longer breakthrough times than the "non-isothermal" module. The latent heat of fusion/melting of the wax offsets the released latent heat of sorption/desorption of the zeolites. One-hundred rapidly cycled pressure swing adsorption cycles were performed on the "passively" cooled hollow fiber sorbents using 25 vol% CO2/75 vol% He (H2 surrogate) at 60 °C and 113 psia, resulting in a product purity of 99.2% and a product recovery of 88.1% thus achieving process conditions and product quality comparable to conventional pellet processes. Isothermal and non-isothermal dynamic modeling of the hollow fiber sorbent module and a traditional packed bed using gPROMS® indicated that the fiber sorbents have sharper fronts (232% sharper) and longer adsorbate breakthrough times (66% longer), further confirming the applicability of the new fiber sorbent approach for H2 purification. © 2012, Hydrogen Energy Publications, LLC

  20. Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification

    KAUST Repository

    Lively, Ryan P.

    2012-10-01

    We describe thermally moderated multi-layered pseudo-monolithic hollow fiber sorbents entities, which can be packed into compact modules to provide small-footprint, efficient H2 purification/CO2 removal systems for use in on-site steam methane reformer product gas separations. Dual-layer hollow fibers are created via dry-jet, wet-quench spinning with an inner "active" core of cellulose acetate (porous binder) and zeolite NaY (69 wt% zeolite NaY) and an external sheath layer of pure cellulose acetate. The co-spun sheath layer reduces the surface porosity of the fiber and was used as a smooth coating surface for a poly(vinyl-alcohol) post-treatment, which reduced the gas permeance through the fiber sorbent by at least 7 orders of magnitude, essentially creating an impermeable sheath layer. The interstitial volume between the individual fibers was filled with a thermally-moderating paraffin wax. CO2 breakthrough experiments on the hollow fiber sorbent modules with and without paraffin wax revealed that the "passively" cooled paraffin wax module had 12.5% longer breakthrough times than the "non-isothermal" module. The latent heat of fusion/melting of the wax offsets the released latent heat of sorption/desorption of the zeolites. One-hundred rapidly cycled pressure swing adsorption cycles were performed on the "passively" cooled hollow fiber sorbents using 25 vol% CO2/75 vol% He (H2 surrogate) at 60 °C and 113 psia, resulting in a product purity of 99.2% and a product recovery of 88.1% thus achieving process conditions and product quality comparable to conventional pellet processes. Isothermal and non-isothermal dynamic modeling of the hollow fiber sorbent module and a traditional packed bed using gPROMS® indicated that the fiber sorbents have sharper fronts (232% sharper) and longer adsorbate breakthrough times (66% longer), further confirming the applicability of the new fiber sorbent approach for H2 purification. © 2012, Hydrogen Energy Publications, LLC

  1. Preparation and characterisation of a sorbent suitable for technetium separation from environmental matrices

    International Nuclear Information System (INIS)

    Bartosova, A.; Rajec, P.; Reich, M.

    2003-01-01

    A sorbent based on Aliquat 336 anchored on hydrophobised silica gel support as an ion exchanger was prepared. Prepared sorbent was suitable for separation of technetium-99 from environmental matrices. The sorbent properties, sorption characteristic and distribution coefficient of 99 mTcO 4 - in various medium was studied. The chemical yield of Tc during separation process was determined using 99m Tc tracer and gamma measurement. Typical sorption recoveries of Tc for this sorbent from 0.1 M HNO 3 were more than 98 %. Typical desorption recoveries using 8 M HNO 3 were in the range 92 - 96 %. The commercial TEVA Spec resin from Eichrom Industries for comparison purpose was used as well. It was found that the prepared sorbent is suitable for separation of technetium from environmental matrices. (authors)

  2. Design Recovery Technology for Real-Time Systems.

    Science.gov (United States)

    1995-10-01

    RL-TR-95-208 Final Technical Report October 1995 DESIGN RECOVERY TECHNOLOGY FOR REAL TIME SYSTEMS The MITRE Corporation Lester J. Holtzblatt...92 - Jan 95 4. TTTLE AND SUBTITLE DESIGN RECOVERY TECHNOLOGY FOR REAL - TIME SYSTEMS 6. AUTHOR(S) Lester J. Holtzblatt, Richard Piazza, and Susan...behavior of real - time systems in general, our initial efforts have centered on recovering this information from one system in particular, the Modular

  3. Sorbents for mercury removal from flue gas

    Energy Technology Data Exchange (ETDEWEB)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  4. Hydropower recovery in water supply systems: Models and case study

    International Nuclear Information System (INIS)

    Vilanova, Mateus Ricardo Nogueira; Balestieri, José Antônio Perrella

    2014-01-01

    Highlights: • We present hydropower recovery models for water supply systems. • Hydropower recovery potential in water supply systems is highly variable. • The case studied could make the supply systems self-sufficient in terms of energy. • Hydropower recovery can reduce GHGs emissions and generate carbon credits. - Abstract: The energy efficiency of water supply systems can be increased through the recovery of hydraulic energy implicit to the volumes of water transported in various stages of the supply process, which can be converted into electricity through hydroelectric recovery systems. Such a process allows the use of a clean energy source that is usually neglected in water supplies, reducing its dependence on energy from the local network and the system’s operation costs. This article evaluates the possibilities and benefits of the use of water supply facilities, structures and equipment for hydraulic energy recovery, addressing several applicable hydroelectric models. A real case study was developed in Brazil to illustrate the technical, economic and environmental aspects of hydropower recovery in water supply systems

  5. Development of a Microwave Regenerative Sorbent-Based Hydrogen Purifier

    Science.gov (United States)

    Wheeler, Richard R., Jr.; Dewberry, Ross H.; McCurry, Bryan D.; Abney, Morgan B.; Greenwood, Zachary W.

    2016-01-01

    This paper describes the design and fabrication of a Microwave Regenerative Sorbent-based Hydrogen Purifier (MRSHP). This unique microwave powered technology was developed for the purification of a hydrogen stream produced by the Plasma Pyrolysis Assembly (PPA). The PPA is a hydrogen recovery (from methane) post processor for NASA's Sabatier-based carbon dioxide reduction process. Embodied in the Carbon dioxide Reduction Assembly (CRA), currently aboard the International Space Station (ISS), the Sabatier reaction employs hydrogen to catalytically recover oxygen, in the form of water, from respiratory carbon dioxide produced by the crew. This same approach is base-lined for future service in the Air Revitalization system on extended missions into deep space where resupply is not practical. Accordingly, manned exploration to Mars may only become feasible with further closure of the air loop as afforded by the greater hydrogen recovery permitted by the PPA with subsequent hydrogen purification. By utilizing the well-known high sorbate loading capacity of molecular sieve 13x, coupled with microwave dielectric heating phenomenon, MRSHP technology is employed as a regenerative filter for a contaminated hydrogen gas stream. By design, freshly regenerated molecular sieve 13x contained in the MRSHP will remove contaminants from the effluent of a 1-CM scale PPA for several hours prior to breakthrough. By reversing flow and pulling a relative vacuum the MRSHP prototype then uses 2.45 GHz microwave power, applied through a novel coaxial antenna array, to rapidly heat the sorbent bed and drive off the contaminants in a short duration vacuum/thermal contaminant desorption step. Finally, following rapid cooling via room temperature cold plates, the MRSHP is again ready to serve as a hydrogen filter.

  6. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  7. Energy saving and recovery measures in integrated urban water systems

    Science.gov (United States)

    Freni, Gabriele; Sambito, Mariacrocetta

    2017-11-01

    The present paper describes different energy production, recovery and saving measures which can be applied in an integrated urban water system. Production measures are often based on the installation of photovoltaic systems; the recovery measures are commonly based on hydraulic turbines, exploiting the available pressure potential to produce energy; saving measures are based on substitution of old pumps with higher efficiency ones. The possibility of substituting some of the pipes of the water supply system can be also considered in a recovery scenario in order to reduce leakages and recovery part of the energy needed for water transport and treatment. The reduction of water losses can be obtained through the Active Leakage Control (ALC) strategies resulting in a reduction in energy consumption and in environmental impact. Measures were applied to a real case study to tested it the efficiency, i.e., the integrated urban water system of the Palermo metropolitan area in Sicily (Italy).

  8. Carbonaceous Asteroid Volatile Recovery (CAVoR) system, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The Carbonaceous Asteroid Volatile Recovery (CAVoR) system produces water and hydrogen-rich syngas for propellant production, life support consumables, and...

  9. Optimization-based design of waste heat recovery systems

    DEFF Research Database (Denmark)

    Cignitti, Stefano

    /or selected. This dissertation focuses on the chemical product and process systems used for waste heat recovery. Here, chemical products are working fluids, which are under continuous development and screening to fulfill regulatory environmental protection and safe operation requirements. Furthermore......, for the recovery of low-grade waste heat, new fluids and processes are needed to make the recovery technically and economically feasible. As the chemical product is influential in the design of the process system, the design of novel chemical products must be considered with the process system. Currently, state...... product and process system in terms of efficiency and sustainability. Today, some of the most important chemical product design problems are solvents and working fluids. Solvents are a vital part in the recovery of valuable resources in separation processes or waste water treatment. Working fluids...

  10. A new helium gas recovery and purification system

    International Nuclear Information System (INIS)

    Yamamotot, T.; Suzuki, H.; Ishii, J.; Hamana, I.; Hayashi, S.; Mizutani, S.; Sanjo, S.

    1974-01-01

    A helium gas recovery and purification system, based on the principle of gas permeation through a membrane, is described. The system can be used for the purification of helium gas containing air as a contaminant. The apparatus, operating at ambient temperature does not need constant attention, the recovery ratio of helium gas is satisfactory and running costs are low. Gases other than helium can be processed with the apparatus. (U.K.)

  11. A regenerable potassium and phosphate sorbent system to enhance dialysis efficacy and device portability: a study in awake goats.

    Science.gov (United States)

    Wester, Maarten; Gerritsen, Karin G; Simonis, Frank; Boer, Walther H; Hazenbrink, Diënty H; Vaessen, Koen R; Verhaar, Marianne C; Joles, Jaap A

    2017-06-01

    Patients on standard intermittent haemodialysis suffer from strong fluctuations in plasma potassium and phosphate. Prolonged dialysis with a wearable device, based on continuous regeneration of a small volume of dialysate using ion exchangers, could moderate these fluctuations and offer increased clearance of these electrolytes. We report in vivo results on the efficacy of potassium and phosphate adsorption from a wearable dialysis device. We explore whether equilibration of ion exchangers at physiological Ca 2+ , Mg 2+ and hypotonic NaCl can prevent calcium/magnesium adsorption and net sodium release, respectively. Effects on pH and HCO3- were studied. Healthy goats were instrumented with a central venous catheter and dialysed. Potassium and phosphate were infused to achieve plasma concentrations commonly observed in dialysis patients. An adsorption cartridge containing 80 g sodium poly(styrene-divinylbenzene) sulphonate and 40 g iron oxide hydroxide beads for potassium and phosphate removal, respectively, was incorporated in a dialysate circuit. Sorbents were equilibrated and regenerated with a solution containing NaCl, CaCl 2 and MgCl 2 . Blood was pumped over a dialyser and dialysate was recirculated over the adsorption cartridge in a countercurrent direction. Potassium and phosphate adsorption was 7.7 ± 2.7 and 4.9 ± 1.3 mmol in 3 h, respectively. Adsorption capacity remained constant during consecutive dialysis sessions and increased with increasing K + and PO43-. Equilibration at physiological Ca 2+ and Mg 2+ prevented net adsorption, eliminating the need for post-cartridge calcium and magnesium infusion. Equilibration at hypotonic NaCl prevented net sodium release Fe 2+ and arterial pH did not change. Bicarbonate was adsorbed, which could be prevented by equilibrating at HCO3- 15 mM. We demonstrate clinically relevant, concentration-dependent, pH-neutral potassium and phosphate removal in vivo with small volumes of regenerable ion exchangers in our

  12. Water purification from radionuclides with using fibroid sorbents

    International Nuclear Information System (INIS)

    Khaydarov, R. A.; Gapurova, O.U.; Khaydarov, R.R.

    2005-01-01

    Full text: Purification waste water and drinking water from radionuclides, heavy metal ions, organic contamination is one of the important problems today. For solving this problem we have created three types of fibroid sorbents on the base of Polyester: cationic and anionic exchange and carbonic. Main properties of these sorbents are described in this article. For example characteristics of the sorbents for removing radionuclides Co-60,57, Zn-65, Sr-89,90, Cs-134,137, etc., radionuclides containing organic molecules M-P-32, M-I-131, M-Mo-99+Tc-99m, M-C-14, etc., heavy metal ions Zn, Ni, Cu, Sb, Pb, Cd, Cr, U, etc., organic molecules (pesticides, phenols, dioxin, benzene, toluene, etc.) were investigated. Influence of pH on percent removal, influence of K, Na and another ions concentrations in the liquid on the percent removal, decreasing of the saturation capacity from number of regeneration and another characteristics are described. Static exchange capacity of the cationic sorbents is 1-2 mg-equ/g and anionic - 0.5-1 mg-equ/g. Capacity of the carbonic sorbents for benzene is 100 mg/g. Time of chemical balance setting is 1-2 s. The sorbents are effective in removing the low concentrations of contamination from the water (lower than 100-200 mg/l) and the air (lower than 100 mg/m 3 ). The use of sorbents in drinking water filters and mini-systems is described. The industrial water purification system consists of coagulating unit, sorbent unit and disinfectant unit. The systems are used in atomic power stations, electroplating plants, matches plants, leather and skin treating plants, car-washing stations, etc

  13. Decision support systems for recovery of endangered species

    International Nuclear Information System (INIS)

    Armstrong, C.E.

    1995-01-01

    The listing of a species as endangered under the Endangered Species Act invokes a suite of responses to help improve conditions for the recovery of that species, to include identification of stressors contributing to population loss, decision analysis of the impacts of proposed recovery options, and implementation of optimal recovery measures. The ability of a decision support system to quantify inherent stressor uncertainties and to identify the key stressors that can be controlled or eliminated becomes key to ensuring the recovery of an endangered species. The listing of the Snake River sockeye, spring/summer chinook, and fall chinook salmon species in the Snake River as endangered provides a vivid example of the importance of sophisticated decision support systems. Operational and physical changes under consideration at eight of the hydroelectric dams along the Columbia and Lower Snake River pose significant financial impacts to a variety of stakeholders involved in the salmon population recovery process and carry significant uncertainties of outcome. A decision support system is presented to assist in the identification of optimal recovery actions for this example that includes the following: creation of datamarts of information on environmental, engineering, and ecological values that influence species survival; incorporation of decision analysis tools to determine optimal decision policies; and the use of geographic information systems (GIS) to provide a context for decision analysis and to communicate the impacts of decision policies

  14. Novel Sorbent to Clean Up Biogas for CHPs

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gökhan O. [TDA Research, Incorporated, Wheat Ridge, CO (United States); Jayataman, Ambalavanan [TDA Research, Incorporated, Wheat Ridge, CO (United States); Schaefer, Matthew [TDA Research, Incorporated, Wheat Ridge, CO (United States); Ware, Michael [TDA Research, Incorporated, Wheat Ridge, CO (United States); Hunt, Jennifer [FuelCell Energy, Inc., Danbury, CT (United States); Dobek, Frank [FuelCell Energy, Inc., Danbury, CT (United States)

    2015-05-30

    In this project, TDA Research Inc. (TDA) has developed low-cost (on a per unit volume of gas processed basis), high-capacity expendable sorbents that can remove both the H2S and organic sulfur species in biogas to the ppb levels. The proposed sorbents will operate downstream of a bulk desulfurization system as a polishing bed to provide an essentially sulfur-free gas to a fuel cell (or any other application that needs a completely sulfur-free feed). Our sorbents use a highly dispersed mixed metal oxides active phase with desired modifiers prepared over on a mesoporous support. The support structure allows the large organic sulfur compounds (such as the diethyl sulfide and dipropyl sulfide phases with a large kinetic diameter) to enter the sorbent pores so that they can be adsorbed and removed from the gas stream.

  15. Dual layer hollow fiber sorbents: Concept, fabrication and characterization

    KAUST Repository

    Bhandari, Dhaval

    2013-02-01

    Hollow fiber sorbents are pseudo-monolithic separations materials created with fiber spinning technology using a polymer \\'binder\\', impregnated with high loadings of sorbent \\'fillers\\' [1]. To increase purified gas recovery during the sorption step and to ensure consistent sorption capacity over repeated cycles, a dense, thin polymer barrier layer on the fiber sorbents is needed to allow only thermal interactions between the sorbate loaded layer and the thermal regeneration fluid. This paper considers materials and methods to create delamination-free dual layer fiber sorbents, with a porous core and a barrier sheath layer formed using a simultaneous co-extrusion process. Low permeability polymers were screened for sheath layer creation, with the core layer comprising cellulose acetate polymer as binder and zeolite NaY as sorbent fillers. Appropriate core and sheath layer dope compositions were determined by the cloud-point method and rheology measurements. The morphology of the as-spun fibers was characterized in detail by SEM, EDX and gas permeation analysis. A simplified qualitative model is described to explain the observed fiber morphology. The effects of core, sheath spin dope and bore fluid compositions, spinning process parameters such as air-gap height, spin dope and coagulation bath temperatures, and elongation draw ratio are examined in detail. © 2012 Elsevier B.V. All rights reserved.

  16. Design manual. [High temperature heat pump for heat recovery system

    Energy Technology Data Exchange (ETDEWEB)

    Burch, T.E.; Chancellor, P.D.; Dyer, D.F.; Maples, G.

    1980-01-01

    The design and performance of a waste heat recovery system which utilizes a high temperature heat pump and which is intended for use in those industries incorporating indirect drying processes are described. It is estimated that use of this heat recovery system in the paper, pulp, and textile industries in the US could save 3.9 x 10/sup 14/ Btu/yr. Information is included on over all and component design for the heat pump system, comparison of prime movers for powering the compressor, control equipment, and system economics. (LCL)

  17. Characterization of calcium carbonate sorbent particle in furnace environment

    International Nuclear Information System (INIS)

    Lee, Kang Soo; Jung, Jae Hee; Keel, Sang In; Yun, Jin Han; Min, Tai Jin; Kim, Sang Soo

    2012-01-01

    The oxy-fuel combustion system is a promising technology to control CO 2 and NO X emissions. Furthermore, sulfation reaction mechanism under CO 2 -rich atmospheric condition in a furnace may lead to in-furnace desulfurization. In the present study, we evaluated characteristics of calcium carbonate (CaCO 3 ) sorbent particles under different atmospheric conditions. To examine the physical/chemical characteristics of CaCO 3 , which is used as a sorbent particle for in-furnace desulfurization in the oxy-fuel combustion system, they were injected into high temperature drop tube furnace (DTF). Experiments were conducted at varying temperatures, residence times, and atmospheric conditions in a reactor. To evaluate the aerosolizing characteristics of the CaCO 3 sorbent particle, changes in the size distribution and total particle concentration between the DTF inlet and outlet were measured. Structural changes (e.g., porosity, grain size, and morphology) of the calcined sorbent particles were estimated by BET/BJH, XRD, and SEM analyses. It was shown that sorbent particles rapidly calcined and sintered in the air atmosphere, whereas calcination was delayed in the CO 2 atmosphere due to the higher CO 2 partial pressure. Instead, the sintering effect was dominant in the CO 2 atmosphere early in the reaction. Based on the SEM images, it was shown that the reactions of sorbent particles could be explained as a grain–subgrain structure model in both the air and CO 2 atmospheres.

  18. Maxwell-Stefan based modelling of ion exchange systems containing common species (Cd"2"+, Na"+) and distinct sorbents (ETS-4, ETS-10)

    International Nuclear Information System (INIS)

    Lito, P. F.; Aniceto, J. P. S.; Silva, C. M.

    2015-01-01

    Cadmium(II) is a toxic hazardous cation, whose presence in the environment causes great concern because of its bioaccumulation in organisms and bio amplification along food chain. Hence, the removal of cadmium compounds from industrial waters and wastewaters is particularly essential, which requires intensive experimental and modelling studies to deal with the problem. In this work, the ion exchange of Cd"2"+ ions from aqueous solution using microporous titanosilicates (ETS-4 and ETS-10) has been modelled using adapted Maxwell-Stefan equations for the ions transport inside the sorbent particles. The fundamentals of the Maxwell-Stefan equations along with correlations for the convective mass transfer coefficients have been used with advantage to reduce the number of model parameters. In the whole, the model was able to represent successfully the kinetic behaviour of 11 independent and very distinct curves of both studied systems (Cd2"+"/Na"+/ETS-4 and Cd"2"+/Na"+/ ETS-10). The predictive capability of the model has been also shown, since several uptake curves were accurately predicted with parameters fitted previously to different sets of experimental data.

  19. Possibilities of heat energy recovery from greywater systems

    Science.gov (United States)

    Niewitecka, Kaja

    2018-02-01

    Waste water contains a large amount of heat energy which is irretrievably lost, so it is worth thinking about the possibilities of its recovery. It is estimated that in a residential building with full sanitary fittings, about 70% of the total tap water supplied is discharged as greywater and could be reused. The subject of the work is the opportunity to reuse waste water as an alternative source of heat for buildings. For this purpose, the design of heat exchangers used in the process of greywater heat recovery in indoor sewage systems, public buildings as well as in industrial plants has been reviewed. The possibility of recovering heat from waste water transported in outdoor sewage systems was also taken into consideration. An exemplary waste water heat recovery system was proposed, and the amount of heat that could be obtained using a greywater heat recovery system in a residential building was presented. The work shows that greywater heat recovery systems allow for significant savings in preheating hot tap water, and the rate of cost reimbursement depends on the purpose of the building and the type of installation. At the same time, the work shows that one should adjust the construction solutions of heat exchangers and indoor installations in buildings to the quality of the medium flowing, which is greywater.

  20. Experimental study on an innovative multifunction heat pipe type heat recovery two-stage sorption refrigeration system

    International Nuclear Information System (INIS)

    Li, T.X.; Wang, R.Z.; Wang, L.W.; Lu, Z.S.

    2008-01-01

    An innovative multifunction heat pipe type sorption refrigeration system is designed, in which a two-stage sorption thermodynamic cycle based on two heat recovery processes was employed to reduce the driving heat source temperature, and the composite sorbent of CaCl 2 and activated carbon was used to improve the mass and heat transfer performances. For this test unit, the heating, cooling and heat recovery processes between two reactive beds are performed by multifunction heat pipes. The aim of this paper is to investigate the cycled characteristics of two-stage sorption refrigeration system with heat recovery processes. The two sub-cycles of a two-stage cycle have different sorption platforms though the adsorption and desorption temperatures are equivalent. The experimental results showed that the pressure evolutions of two beds are nearly equivalent during the first stage, and desorption pressure during the second stage is large higher than that in the first stage while the desorption temperatures are same during the two operation stages. In comparison with conventional two-stage cycle, the two-stage cycle with heat recovery processes can reduce the heating load for desorber and cooling load for adsorber, the coefficient of performance (COP) has been improved more than 23% when both cycles have the same regeneration temperature of 103 deg. C and the cooling water temperature of 30 deg. C. The advanced two-stage cycle provides an effective method for application of sorption refrigeration technology under the condition of low-grade temperature heat source or utilization of renewable energy

  1. Adsorption of Ammonia on Regenerable Carbon Sorbents

    Science.gov (United States)

    Wójtowicz, Marek A.; Cosgrove, Jesph E.; Serio, Michael A..; Wilburn, Monique

    2015-01-01

    Results are presented on the development of reversible sorbents for the combined carbon dioxide, moisture, and trace-contaminant (TC) removal for use in Extravehicular Activities (EVAs), and more specifically in the Primary Life Support System (PLSS). The currently available life support systems use separate units for carbon dioxide, trace contaminants, and moisture control, and the long-term objective is to replace the above three modules with a single one. Data on sorption and desorption of ammonia, which is a major TC of concern, are presented in this paper. The current TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is non-regenerable, and the carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. In this study, several carbon sorbents were fabricated and tested for ammonia sorption. Ammonia-sorption capacity was related to carbon pore structure characteristics, and the temperature of oxidative carbon-surface treatment was optimized for enhanced ammonia-sorption performance.

  2. Engineered sorbent barriers for low-level waste disposal

    International Nuclear Information System (INIS)

    Mitchell, S.J.; Freeman, H.D.; Buelt, J.L.

    1987-01-01

    The Engineered Sorbent Barriers Program at Pacific Northwest Laboratory is developing sorbent materials to prevent the migration of radionuclides from low-level waste sites. These materials would allow water to pass, preventing the bathtub effect at humid sites. Screening studies identified promising sorbent materials for three key radionuclides: for cesium, greensand; for cobalt, activated charcoal; and for strontium, synthetic zeolite of clinoptilolite. Mixtures of these sorbent materials were tested in 0.6-m-diameter columns using radioactive leachates. To simulate expected worst-case conditions, the leachate solution contained the radionuclides, competing cations, and a chelating agent, adjusted to a pH of 5. A sorbent barrier comprised of greensand (1 wt%), activated charcoal (6 wt%), synthetic zeolite (20 wt%), and soil (73 wt%) achieved the decontamination factors necessary to meet the regulatory performance requirements established for this study. Sorbent barriers can be applied to shallow land burial, as backfill around the waste or engineered structures, or as backup to other liner systems. 2 references, 6 figures, 3 tables

  3. Engineered sorbent barriers for low-level waste disposal.

    Energy Technology Data Exchange (ETDEWEB)

    Freeman, H.D.; Mitchell, S.J.; Buelt, J.L.

    1986-12-01

    The Engineered Sorbent Barriers Program at Pacific Northwest Laboratory is investigating sorbent materials to prevent the migration of soluble radio nuclides from low-level waste sites. These materials would allow water to pass, preventing the bathtub effect at humid sites. Laboratory studies identifield promising sorbent materials for three key radionuclides: for cesium, greensand; for cobalt, activated charcoal; and for strontium, synthetic zeolite or clinoptilolite. Mixtures of these sorbent materials were tested in 0.6-m-diameter columns using radioactive leachates. To simulate expected worst-case conditions, the leachate solution contained the radionuclides, competing cations, and a chelating agent and was adjusted to a pH of 5. A sorbent barrier comprised of greensand (1 wt%), activated charcoal (6 wt%), synthetic zeolite (20 wt%), and local soil (73 wt%) achieved the decontamination factors necessary to meet the regulatory performance requirements established for this study. Sorbent barriers can be applied to shallow-land burial, as backfill around the waste or engineered structures, or as backup to other liner systems. 7 refs., 14 figs., 12 tabs.

  4. Engineered sorbent barriers for low-level waste disposal

    International Nuclear Information System (INIS)

    Freeman, H.D.; Mitchell, S.J.; Buelt, J.L.

    1986-12-01

    The Engineered Sorbent Barriers Program at Pacific Northwest Laboratory is investigating sorbent materials to prevent the migration of soluble radio nuclides from low-level waste sites. These materials would allow water to pass, preventing the bathtub effect at humid sites. Laboratory studies identifield promising sorbent materials for three key radionuclides: for cesium, greensand; for cobalt, activated charcoal; and for strontium, synthetic zeolite or clinoptilolite. Mixtures of these sorbent materials were tested in 0.6-m-diameter columns using radioactive leachates. To simulate expected worst-case conditions, the leachate solution contained the radionuclides, competing cations, and a chelating agent and was adjusted to a pH of 5. A sorbent barrier comprised of greensand (1 wt%), activated charcoal (6 wt%), synthetic zeolite (20 wt%), and local soil (73 wt%) achieved the decontamination factors necessary to meet the regulatory performance requirements established for this study. Sorbent barriers can be applied to shallow-land burial, as backfill around the waste or engineered structures, or as backup to other liner systems. 7 refs., 14 figs., 12 tabs

  5. Optimal control of a one product recovery system with backlogging

    NARCIS (Netherlands)

    Kiesmüller, G.P.; Minner, S.; Kleber, R.

    2000-01-01

    In this paper a product recovery system for one product is investigated. The system contains one inventory for returned and recoverable items and one for serviceable items. Demands are satisfied from serviceable inventory where backlogging of demands is allowed. In addition, there is the possibility

  6. Cross-linked poly(tetrahydrofuran) as promising sorbent for organic solvent/oil spill

    Energy Technology Data Exchange (ETDEWEB)

    Yati, Ilker; Ozan Aydin, Gulsah; Bulbul Sonmez, Hayal, E-mail: hayalsonmez@gtu.edu.tr

    2016-05-15

    Highlights: • Poly(tetrahydrofuran) based sorbents were prepared. • PTHF sorbents demonstrate reusability at least for ten times. • PTHF based sorbents show fast and quick absorption-desorption process. • 19 g of oil can be absorbed by 1 g of PTHF based sorbent. - Abstract: In this study, a series of different molecular weights of poly(tetrahydrofuran) (PTHF), which is one of the most important commercial polymers around the world, was condensed with tris[3-(trimethoxysilyl)propyl]isocyanurate (ICS) to generate a cross-linked 3-dimensional network in order to obtain organic solvent/oil sorbents having high swelling capacity. The prepared sorbents show high and fast swelling capacity in oils such as dichloromethane (DCM), tetrahydrofuran (THF), acetone, t-butyl methyl ether (MTBE), gasoline, euro diesel, and crude oil. The recovery of the absorbed oils from contaminated surfaces, especially from water, and the regeneration of the sorbents after several applications are effective. The characterization and thermal properties of the sorbents are identified by Fourier transform infrared spectroscopy (FTIR), solid-state {sup 13}C and {sup 29}Si cross-polarization magic angle spinning (CPMAS) nuclear magnetic resonance (NMR), differential scanning calorimetry (DSC) and thermal gravimetric analyses (TGA), respectively. The new usage area of PTHF is emerged by the preparation of PTHF-based network structure with high oil absorption capacity and having excellent reusability as an oil absorbent for the removal of organic liquids from the spill site.

  7. A comparative study of homemade C18 and commercial C18 sorbents for preconcentration of lead by minicolumn solid phase extraction

    International Nuclear Information System (INIS)

    Maltez, H.F.; Curtius, A.J.; Carasek, E.; Melo, L.F.C.; Sales Fontes Jardim, I.C.; Nascimento de Queiroz do, S.C.

    2004-01-01

    A comparative study of commercial C 18 chemically immobilized on silica and homemade C 18 , as sorbents for Pb complexed with 0,0-diethyl-dithiophosphate (DDTP) in a flow injection preconcentration system is reported. The homemade C 18 sorbent was obtained by sorption of poly(methyloctadecylsiloxane) (PMODS) on the silica support followed by immobilization using thermal treatment. The method follows the concept of green chemistry, since there are no toxic residues after synthesis. The complexed Pb was formed in 1.0 mol L -1 HCI medium and retained on the minicolumn filled with the sorbents. The elution was carried out using ethanol, and the richest 210 μL fraction was collected and analyzed by flame atomic absorption spectrometry. Chemical and flow variables were optimized for each sorbent. The results demonstrated that the performance of the proposed homemade C 18 sorbent for preconcentration of Pb complexed with DDTP is very similar to commercial C 18 chemically bonded on silica. By processing 25 mL, the enrichment factors were 129 and 125 for commercial C 18 and homemade C 18 , respectively. The limit of detection for commercial and homemade C 18 was 0.2 μg L -1 and 0.6 μg L -1 , respectively. The relative standard deviation (RSD) was lower than 1.2 % for both sorbents for a Pb concentration of 100 μg L -1 . The method was also applied successfully to the analysis of water samples, and the accuracy was tested by recovery measurements on spiked samples and biological reference material. (author)

  8. Helium-Hydrogen Recovery System, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Immense quantities of expensive liquefied helium are required at Stennis and Kennedy Space Centers for pre-cooling rocket engine propellant systems prior to filling...

  9. Process Control for Precipitation Prevention in Space Water Recovery Systems

    Science.gov (United States)

    Sargusingh, Miriam; Callahan, Michael R.; Muirhead, Dean

    2015-01-01

    The ability to recover and purify water through physiochemical processes is crucial for realizing long-term human space missions, including both planetary habitation and space travel. Because of their robust nature, rotary distillation systems have been actively pursued by NASA as one of the technologies for water recovery from wastewater primarily comprised of human urine. A specific area of interest is the prevention of the formation of solids that could clog fluid lines and damage rotating equipment. To mitigate the formation of solids, operational constraints are in place that limits such that the concentration of key precipitating ions in the wastewater brine are below the theoretical threshold. This control in effected by limiting the amount of water recovered such that the risk of reaching the precipitation threshold is within acceptable limits. The water recovery limit is based on an empirically derived worst case wastewater composition. During the batch process, water recovery is estimated by monitoring the throughput of the system. NASA Johnson Space Center is working on means of enhancing the process controls to increase water recovery. Options include more precise prediction of the precipitation threshold. To this end, JSC is developing a means of more accurately measuring the constituent of the brine and/or wastewater. Another means would be to more accurately monitor the throughput of the system. In spring of 2015, testing will be performed to test strategies for optimizing water recovery without increasing the risk of solids formation in the brine.

  10. Tanker self-help spill recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Smedley, J B; Wainwright, J G; Ehman, T K

    1991-12-01

    An investigation was conducted of the circumstances in which oil spills occur from tankers at sea by analyzing available historical oil spill data. A data base of marine oil spills greater than 134 tonnes occurring from 1974 and June 1990, included in an appendix, was among the information analyzed. The analysis showed that marine oil spills of 5,000 tonnes and greater account for 39.4% of the accidents yet 94.7% of the total spilled quantity; 84% of those spills occur in vessels of 20,000 deadweight tonnes and larger. Of spills over 5,000 tonnes, 78.5% occur outside of harbor or pier areas where spill response equipment may not be readily available. Over 50% of spills are caused by groundings or collisions where the vessel crew might be able to respond in mitigating and controlling the outflow of oil. The review suggested that tanker self-help systems warrant serious consideration. Potential self-help systems are described, ranging from additives such as bioremediation, dispersants, and solidifiers to equipment such as portable pumps, booms, and skimmers. Candidate systems were examined in terms of their safety, ease of operation, practicability, and effectiveness. Their possible performance was then assessed for the case of major marine oil spills that have occurred in Canadian waters. Four systems are identified as potential candidates for further evaluation and possible implementation: internal oil transfer, hydrostatic loading, external oil lightering, and contingency planning. A system design is evaluated and its benefits and possible implementation are outlined, based on integration of the preferred attributes of the above four options. Recommendations for implementation are also provided. 28 refs., 6 figs., 33 tabs.

  11. System and method for determining the net output torque from a waste heat recovery system

    Science.gov (United States)

    Tricaud, Christophe; Ernst, Timothy C.; Zigan, James A.

    2016-12-13

    The disclosure provides a waste heat recovery system with a system and method for calculation of the net output torque from the waste heat recovery system. The calculation uses inputs from existing pressure and speed sensors to create a virtual pump torque sensor and a virtual expander torque sensor, and uses these sensors to provide an accurate net torque output from the WHR system.

  12. Faulted systems recovery experience. Final report, May 1992

    International Nuclear Information System (INIS)

    1992-05-01

    This report addresses the recovery (i.e., return to service from a faulted, or otherwise unavailable, condition) of important nuclear power plant front-line and support systems and equipment. It contains information based on operating experience relative to the times to recover from a variety of plant events. It also indicates the nature of the operator actions involved. This information is intended to provide useful insights to utilities who are undertaking Individual Plant Examinations (IPEs) per Generic Letter 88-20 of the Nuclear Regulatory Commission. The report provides a database of recovery experience primarily derived from Licensee Event Reports (LERs). The database contains recovery duration information for 205 demand events and 98 nondemand events. In particular, it contains recovery durations for 42 pump related and 143 valve related events that are representative of demand conditions. Experience shows that, overall, about one-half of all pumps and valves are recovered in 30 minutes or less. Specific recovery experience is dependent on the equipment type, the plant system involved, and the failure mode encountered. (author)

  13. Cloud Standby: Disaster Recovery of Distributed Systems in the Cloud

    OpenAIRE

    Lenk , Alexander; Tai , Stefan

    2014-01-01

    International audience; Disaster recovery planning and securing business processes against outtakes have been essential parts of running a company for decades. As IT systems became more important, and especially since more and more revenue is generated over the Internet, securing the IT systems that support the business processes against outages is essential. Using fully operational standby sites with periodically updated standby systems is a well-known approach to prepare against disasters. ...

  14. Temperature control of evaporators in automotive waste heat recovery systems

    NARCIS (Netherlands)

    Oom, M.E.E.; Feru, E.; de Jager, A.G.; de Lange, H.C.; Ouwerkerk, H.

    2017-01-01

    his paper presents a control strategy for the steam generation process in automotive waste heat recovery systems that are based on the subcritical Rankine cycle. The central question is how to regulate the flow of water into the evaporator such that dry steam is generated at its outlet, subject to

  15. Optimal Control of Diesel Engines with Waste Heat Recovery System

    NARCIS (Netherlands)

    Willems, F.P.T.; Donkers, M.C.F.; Kupper, F.

    2014-01-01

    This study presents an integrated energy and emission management strategy for a Euro-VI diesel engine with Waste Heat Recovery (WHR) system. This Integrated Powertrain Control (IPC) strategy optimizes the CO2-NOx trade-off by minimizing the operational costs associated with fuel and AdBlue

  16. Optimal control of diesel engines with waste heat recovery systems

    NARCIS (Netherlands)

    Willems, F.P.T.; Donkers, M.C.F.; Kupper, F.; Waschl, H.; Kolmanovsky, I.; Steinbuch, M.; Del Re, L.

    2014-01-01

    This study presents an integrated energy and emission management strategy for a Euro-VI diesel engine with Waste Heat Recovery (WHR) system. This Integrated Powertrain Control (IPC) strategy optimizes the CO 2 - NO x trade-off by minimizing the operational costs associated with fuel and AdBlue

  17. Design and analysis of heat recovery system in bioprocess plant

    International Nuclear Information System (INIS)

    Anastasovski, Aleksandar; Rašković, Predrag; Guzović, Zvonimir

    2015-01-01

    Highlights: • Heat integration of a bioprocess plant is studied. • Bioprocess plant produces yeast and ethyl-alcohol. • The design of a heat recovery system is performed by batch pinch analysis. • Direct and indirect heat integration approaches are used in process design. • The heat recovery system without a heat storage opportunity is more profitable. - Abstract: The paper deals with the heat integration of a bioprocess plant which produces yeast and ethyl-alcohol. The referent plant is considered to be a multiproduct batch plant which operates in a semi-continuous mode. The design of a heat recovery system is performed by batch pinch analysis and by the use of the Time slice model. The results obtained by direct and indirect heat integration approaches are presented in the form of cost-optimal heat exchanger networks and evaluated by different thermodynamic and economic indicators. They signify that the heat recovery system without a heat storage opportunity can be considered to be a more profitable solution for the energy efficiency increase in a plant

  18. Control of automotive waste heat recovery systems with parallel evaporators

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; Rascanu, G.C.; Jager, de A.G.; Steinbuch, M.

    2014-01-01

    In this paper, Model Predictive Control (MPC) is applied to control a Waste Heat Recovery system for a highly dynamic automotive application. As a benchmark, a commonly applied control strategy is used that consists of a feedforward based on engine conditions and of two PI controllers that

  19. Flow-injection determination of total organic fluorine with off-line defluorination reaction on a solid sorbent bed.

    Science.gov (United States)

    Musijowski, Jacek; Trojanowicz, Marek; Szostek, Bogdan; da Costa Lima, José Luis Fontes; Lapa, Rui; Yamashita, Hiroki; Takayanagi, Toshio; Motomizu, Shoji

    2007-09-26

    Considering recent reports on widespread occurrence and concerns about perfluoroalkyl substances (PFAS) in environmental and biological systems, analysis of these compounds have gained much attention in recent years. Majority of analyte-specific methods are based on a LC/MS/MS or a GC/MS detection, however many environmental or biological studies would benefit from a total organic fluorine (TOF) determination. Presented work was aimed at developing a method for TOF determination. TOF is determined as an amount of inorganic fluoride obtained after defluorination reaction conducted off-line using sodium biphenyl reagent directly on the sorbent without elution of retained analytes. Recovered fluoride was analyzed using flow-injection system with either fluorimetric or potentiometric detection. The TOF method was tested using perfluorocarboxylic acids (PFCA), including perfluorooctanoic acid (PFOA), as model compounds. Considering low concentrations of PFAS in natural samples, solid-phase extraction as a preconcentration procedure was evaluated. Several carbon-based sorbents were tested, namely multi-wall carbon nanotubes, carbon nanofibres and activated carbon. Good sorption of all analytes was achieved and defluorination reaction was possible to carry out directly on a sorbent bed. Recoveries obtained for PFCAs, adsorbed on an activated carbon sorbent, and measured as TOF, were 99.5+/-1.7, 110+/-9.4, 95+/-26, 120+/-32, 110+/-12 for C4, C6, C8, C10 and C12-PFCA, respectively. Two flow systems that would enable the defluorination reaction and fluoride determination in a single system were designed and tested.

  20. Sol-gel derived sorbents

    Science.gov (United States)

    Sigman, Michael E.; Dindal, Amy B.

    2003-11-11

    Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

  1. Transaction Costs in Collective Waste Recovery Systems in the EU

    OpenAIRE

    Nozharov, Shteryo

    2018-01-01

    The study aims to identify the institutional flaws of the current EU waste management model by analysing the economic model of extended producer responsibility and collective waste management systems and to create a model for measuring the transaction costs borne by waste recovery organizations. The model was approbated by analysing the Bulgarian collective waste management systems that have been complying with the EU legislation for the last 10 years. The analysis focuses on waste oils becau...

  2. Uranium recovery from low-level aqueous sources

    International Nuclear Information System (INIS)

    Kelmers, A.D.; Goeller, H.E.

    1981-03-01

    The aqueous sources of soluble uranium were surveyed and evaluated in terms of the uranium geochemical cycle in an effort to identify potential unexploited resources. Freshwater sources appeared to be too low in uranium content to merit consideration, while seawater, although very dilute (approx. 3.3 ppB), contains approx. 4 x 10 9 metric tons of uranium in all the world's oceans. A literature review of recent publications and patents concerning uranium recovery from seawater was conducted. Considerable experimental work is currently under way in Japan; less is being done in the European countries. An assessment of the current state of technology is presented in this report. Repeated screening programs have identified hydrous titanium oxide as the most promising candidate absorbent. However, some of its properties such as distribution coefficient, selectivity, loading, and possibly stability appear to render its use inadequate in a practical recovery system. Also, various assessments of the energy efficiency of pumped or tidal power schemes for contacting the sorbent and seawater are in major disagreement. Needed future research and development tasks are discussed. A fundamental sorbent development program to greatly improve sorbent properties would be required to permit practical recovery of uranium from seawater. Major unresolved engineering aspects of such recovery systems are also identified and discussed

  3. Thermal energy recovery of air conditioning system--heat recovery system calculation and phase change materials development

    International Nuclear Information System (INIS)

    Gu Zhaolin; Liu Hongjuan; Li Yun

    2004-01-01

    Latent heat thermal energy storage systems can be used to recover the rejected heat from air conditioning systems, which can be used to generate low-temperature hot water. It decreases not only the consumption of primary energy for heating domestic hot water but also the calefaction to the surroundings due to the rejection of heat from air conditioning systems. A recovery system using phase change materials (PCMs) to store the rejected (sensible and condensation) heat from air conditioning system has been developed and studied, making up the shortage of other sensible heat storage system. Also, PCMs compliant for heat recovery of air conditioning system should be developed. Technical grade paraffin wax has been discussed in this paper in order to develop a paraffin wax based PCM for the recovery of rejected heat from air conditioning systems. The thermal properties of technical grade paraffin wax and the mixtures of paraffin wax with lauric acid and with liquid paraffin (paraffin oil) are investigated and discussed, including volume expansion during the phase change process, the freezing point and the heat of fusion

  4. Optimal control of Formula One car energy recovery systems

    Science.gov (United States)

    Limebeer, D. J. N.; Perantoni, G.; Rao, A. V.

    2014-10-01

    The utility of orthogonal collocation methods in the solution of optimal control problems relating to Formula One racing is demonstrated. These methods can be used to optimise driver controls such as the steering, braking and throttle usage, and to optimise vehicle parameters such as the aerodynamic down force and mass distributions. Of particular interest is the optimal usage of energy recovery systems (ERSs). Contemporary kinetic energy recovery systems are studied and compared with future hybrid kinetic and thermal/heat ERSs known as ERS-K and ERS-H, respectively. It is demonstrated that these systems, when properly controlled, can produce contemporary lap time using approximately two-thirds of the fuel required by earlier generation (2013 and prior) vehicles.

  5. Coating membranes for a sorbent-based artificial liver: adsorption characteristics

    NARCIS (Netherlands)

    de Koning, H. W.; Chamuleau, R. A.; Bantjes, A.

    1982-01-01

    Techniques are described for the coating of sorbents to be used in an artificial liver support system based on mixed sorbent bed hemoperfusion. Activated charcoal has been coated with cellulose acetate (CA) by solvent evaporation. With Amberlite XAD-4, the Wurster technique was used for coating with

  6. Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

    2007-12-31

    The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or “cut line” to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel

  7. Comparison of Configurations for High-Recovery Inland Desalination Systems

    Directory of Open Access Journals (Sweden)

    Philip A. Davies

    2012-09-01

    Full Text Available Desalination of brackish groundwater (BW is an effective approach to augment water supply, especially for inland regions that are far from seawater resources. Brackish water reverse osmosis (BWRO desalination is still subject to intensive energy consumption compared to the theoretical minimum energy demand. Here, we review some of the BWRO plants with various system arrangements. We look at how to minimize energy demands, as these contribute considerably to the cost of desalinated water. Different configurations of BWRO system have been compared from the view point of normalized specific energy consumption (SEC. Analysis is made at theoretical limits. The SEC reduction of BWRO can be achieved by (i increasing number of stages, (ii using an energy recovery device (ERD, or (iii operating the BWRO in batch mode or closed circuit mode. Application of more stages not only reduces SEC but also improves water recovery. However, this improvement is less pronounced when the number of stages exceeds four. Alternatively and more favourably, the BWRO system can be operated in Closed Circuit Desalination (CCD mode and gives a comparative SEC to that of the 3-stage system with a recovery ratio of 80%. A further reduction of about 30% in SEC can be achieved through batch-RO operation. Moreover, the costly ERDs and booster pumps are avoided with both CCD and batch-RO, thus furthering the effectiveness of lowering the costs of these innovative approaches.

  8. Engineered sorbent barriers for low-level waste disposal

    International Nuclear Information System (INIS)

    Mitchell, S.J.; Freeman, H.D.; Buelt, J.L.

    1986-01-01

    Pacific Northwest Laboratory is developing sorbent materials to prevent the migration of radionuclides from low-level waste sites. These materials would allow water to pass, preventing the bathtub effect at humid sites. Screening studies identified promising sorbent materials for three key radionuclides: for cesium, greensand; for cobalt, activated charcoal; and for strontium, synthetic zeolite or clinoptilolite. Mixtures of these sorbent materials were tested in 0.6-m-diameter columns using radioactive leachates. To simulate expected worst-case conditions, the leachate solution contained the radionuclides, competing cations, and a chelating agent, adjusted to a pH of 5. A sorbent barrier comprised of greensand (1 wt %), activated charcoal (6 wt %), synthetic zeolite (20 wt %), and soil (73 wt %) achieved the decontamination factors necessary to meet the regulatory performance requirements established for this study. Sorbent barriers can be applied to shallow land burial, as backfill around the waste or engineered structures, or as backup to other liner systems. 2 refs., 6 figs., 3 tabs

  9. Research on an IP disaster recovery storage system

    Science.gov (United States)

    Zeng, Dong; Wang, Yusheng; Zhu, Jianfeng

    2008-12-01

    According to both the Fibre Channel (FC) Storage Area Network (SAN) switch and Fabric Application Interface Standard (FAIS) mechanism, an iSCSI storage controller is put forward and based upon it, an internet Small Computer System Interface (iSCSI) SAN construction strategy for disaster recovery (DR) is proposed and some multiple sites replication models and a closed queue performance analysis method are also discussed in this paper. The iSCSI storage controller lies in the fabric level of the networked storage infrastructure, and it can be used to connect to both the hybrid storage applications and storage subsystems, besides, it can provide virtualized storage environment and support logical volume access control, and by cooperating with the remote peerparts, a disaster recovery storage system can be built on the basis of the data replication, block-level snapshot and Internet Protocol (IP) take-over functions.

  10. Progressive retry for software error recovery in distributed systems

    Science.gov (United States)

    Wang, Yi-Min; Huang, Yennun; Fuchs, W. K.

    1993-01-01

    In this paper, we describe a method of execution retry for bypassing software errors based on checkpointing, rollback, message reordering and replaying. We demonstrate how rollback techniques, previously developed for transient hardware failure recovery, can also be used to recover from software faults by exploiting message reordering to bypass software errors. Our approach intentionally increases the degree of nondeterminism and the scope of rollback when a previous retry fails. Examples from our experience with telecommunications software systems illustrate the benefits of the scheme.

  11. Energy recovery system using an organic rankine cycle

    Science.gov (United States)

    Ernst, Timothy C

    2013-10-01

    A thermodynamic system for waste heat recovery, using an organic rankine cycle is provided which employs a single organic heat transferring fluid to recover heat energy from two waste heat streams having differing waste heat temperatures. Separate high and low temperature boilers provide high and low pressure vapor streams that are routed into an integrated turbine assembly having dual turbines mounted on a common shaft. Each turbine is appropriately sized for the pressure ratio of each stream.

  12. Maintenance and Recovery of Water System for Injection (WFI)

    International Nuclear Information System (INIS)

    Wan Anuar Wan Awang; Ahmad Firdaus Jalil; Wan Mohd Firdaus Wan Ishak

    2015-01-01

    Water system for injection (WFI) is one of the main component in manufacturing pharmaceutical materials and radiopharmaceuticals. This system accredited in 2005. Water quality produced analyzed and give the unsatisfied results. The operation of WFI was stopped temporarily due to technical problems. In 2013, recovery works were implemented with budget of RM 226,500.00. Comprehensive maintenance were implemented by Rykertech (Asia) Sdn. Bhd. With duration of 24 months (October 2014 until September 2016) with cost RM 473,550.00. Now, this system operated in good condition and produced water that meet with the specifications. (author)

  13. Mechanism of protodesorption—exchange of heavy metal cations for protons in a heterophase system of H{sub 2}O–H{sub 2}SO{sub 4}–MSO{sub 4}—cellulose sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Kozlov, V.A.; Nikiforova, T.E., E-mail: tatianaenik@mail.ru; Loginova, V.A.; Koifman, O.I.

    2015-12-15

    Highlights: • Protodesorption takes place with participation of anions. • The interphase indicator MSO{sub 4} is used in ion exchange investigation. • In ion exchange process salt and acid participate in equivalent proportions. • In a protodesorption process proton acts in degree of ½. • M{sup 2+}/2Na{sup +} and M{sup 2+}/2H{sup +} exchanges take place in ion and molecular forms. - Abstract: The influence of pH on the distribution of metal cations [Cd(II), Cu(II), Fe(II), Ni(II), Zn(II)] in a four-component heterophase system (H{sub 2}O–H{sub 2}SO{sub 4}–MSO{sub 4}–cellulose sorbent) was studied. Protodesorption of metal cations was studied with indicator and constant quantities of [MSO{sub 4}] salts and constant solvent–sorbent ratio. Linear dependence lgK{sub DM2+} = f(pH) with tgα = 1/2 of the K{sub DM2+} metal ions distribution coefficients from the acidity of the aqueous phase is observed in logarithmic coordinates. Depression of the exponent corresponding to proton involvement in protodesorption from 2 (theory) to 0.5 (experiment) indicates that anions of the aqueous phase are involved in the process of exchange of metal cation for proton on the anionic centers of the sorbent, which corresponds to participation of the salt and acid components of the system in molecular non-dissociated form in an equivalent proportion H{sub 2}SO{sub 4}/MSO{sub 4} = 1/1. Different behavior of the salt and acid components in ion exchange of cations for cations and cations for protons is due to the differences in the constraint coefficients of their molecular and ionic forms which must be taken into consideration in equations describing thermodynamics of the interphase exchange.

  14. Electron energy recovery system for negative ion sources

    International Nuclear Information System (INIS)

    Dagenhart, W.K.; Stirling, W.L.

    1982-01-01

    An electron energy recovery system for negative ion sources is provided. The system, employs crossed electric and magnetic fields to separate the electrons from ions as they are extracted from a negative ion source plasma generator and before the ions are accelerated to their full kinetic energy. With the electric and magnetic fields oriented 90* to each other, the electrons are separated from the plasma and remain at approximately the electrical potential of the generator in which they were generated. The electrons migrate from the ion beam path in a precessing motion out of the ion accelerating field region into an electron recovery region provided by a specially designed electron collector electrode. The electron collector electrode is uniformly spaced from a surface of the ion generator which is transverse to the direction of migration of the electrons and the two surfaces are contoured in a matching relationship which departs from a planar configuration to provide an electric field component in the recovery region which is parallel to the magnetic field thereby forcing the electrons to be directed into and collected by the electron collector electrode. The collector electrode is maintained at a potential slightly positive with respect to the ion generator so that the electrons are collected at a small fraction of the full accelerating supply voltage energy

  15. Anionic sorbents for arsenic and technetium species

    International Nuclear Information System (INIS)

    Lucero, Daniel A.; Moore, Robert Charles; Bontchev, Ranko Panayotov; Hasan, Ahmed Ali Mohamed; Zhao, Hongting; Salas, Fred Manuel; Holt, Kathleen Caroline

    2003-01-01

    Two sorbents, zirconium coated zeolite and magnesium hydroxide, were tested for their effectiveness in removing arsenic from Albuquerque municipal water. Results for the zirconium coated zeolite indicate that phosphate present in the water interfered with the sorption of arsenic. Additionally, there was a large quantity of iron and copper present in the water, corrosion products from the piping system, which may have interfered with the uptake of arsenic by the sorbent. Magnesium hydroxide has also been proven to be a strong sorbent for arsenic as well as other metals. Carbonate, present in water, has been shown to interfere with the sorption of arsenic by reacting with the magnesium hydroxide to form magnesium carbonate. The reaction mechanism was investigated by FT-IR and shows that hydrogen bonding between an oxygen on the arsenic species and a hydrogen on the Mg(OH)2 is most likely the mechanism of sorption. This was also confirmed by RAMAN spectroscopy and XRD. Technetium exists in multiple oxidation states (IV and VII) and is easily oxidized from the relatively insoluble Tc(IV) form to the highly water soluble and mobile Tc(VII) form. The two oxidation states exhibit different sorption characteristics. Tc(VII) does not sorb to most materials whereas Tc(IV) will strongly sorb to many materials. Therefore, it was determined that it is necessary to first reduce the Tc (using SnCl2) before sorption to stabilize Tc in the environment. Additionally, the effect of carbonate and phosphate on the sorption of technetium by hydroxyapatite was studied and indicated that both have a significant effect on reducing Tc sorption

  16. Enterprise systems backup and recovery a corporate insurance policy

    CERN Document Server

    de Guise, Preston

    2008-01-01

    The success of information backup systems does not rest on IT administrators alone. Rather, a well-designed backup system comes about only when several key factors coalesce-business involvement, IT acceptance, best practice designs, enterprise software, and reliable hardware. Enterprise Systems Backup and Recovery: A Corporate Insurance Policy provides organizations with a comprehensive understanding of the principles and features involved in effective enterprise backups.Instead of focusing on any individual backup product, this book recommends corporate procedures and policies that need to be established for comprehensive data protection. It provides relevant information to any organization, regardless of which operating systems or applications are deployed, what backup system is in place, or what planning has been done for business continuity. It explains how backup must be included in every phase of system planning, development, operation, and maintenance. It also provides techniques for analyzing and impr...

  17. Characterization of calcium carbonate sorbent particle in furnace environment

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kang Soo [Aerosol and Particle Technology Laboratory, Department of Mechanical Engineering, KAIST 291 Daehak-ro, Yuseong-gu, Daejeon, 305-701 (Korea, Republic of); Jung, Jae Hee [Environment Sensor System Research Center, KIST 39-1 Hawolgok-dong, Seongbuk-gu, Seoul, 136-791 (Korea, Republic of); Keel, Sang In; Yun, Jin Han; Min, Tai Jin [Environmental Systems Research Division, KIMM 104 Sinseongno, Yuseong-gu, Daejeon, 305-343 (Korea, Republic of); Kim, Sang Soo, E-mail: sskim@kaist.ac.kr [Aerosol and Particle Technology Laboratory, Department of Mechanical Engineering, KAIST 291 Daehak-ro, Yuseong-gu, Daejeon, 305-701 (Korea, Republic of)

    2012-07-01

    The oxy-fuel combustion system is a promising technology to control CO{sub 2} and NO{sub X} emissions. Furthermore, sulfation reaction mechanism under CO{sub 2}-rich atmospheric condition in a furnace may lead to in-furnace desulfurization. In the present study, we evaluated characteristics of calcium carbonate (CaCO{sub 3}) sorbent particles under different atmospheric conditions. To examine the physical/chemical characteristics of CaCO{sub 3}, which is used as a sorbent particle for in-furnace desulfurization in the oxy-fuel combustion system, they were injected into high temperature drop tube furnace (DTF). Experiments were conducted at varying temperatures, residence times, and atmospheric conditions in a reactor. To evaluate the aerosolizing characteristics of the CaCO{sub 3} sorbent particle, changes in the size distribution and total particle concentration between the DTF inlet and outlet were measured. Structural changes (e.g., porosity, grain size, and morphology) of the calcined sorbent particles were estimated by BET/BJH, XRD, and SEM analyses. It was shown that sorbent particles rapidly calcined and sintered in the air atmosphere, whereas calcination was delayed in the CO{sub 2} atmosphere due to the higher CO{sub 2} partial pressure. Instead, the sintering effect was dominant in the CO{sub 2} atmosphere early in the reaction. Based on the SEM images, it was shown that the reactions of sorbent particles could be explained as a grain-subgrain structure model in both the air and CO{sub 2} atmospheres.

  18. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir Gupta; Alejandro Lopez-Ortiz

    2001-01-01

    Four grades of sodium bicarbonate and two grades of trona were characterized in terms of particle size distribution, surface area, pore size distribution, and attrition. Surface area and pore size distribution determinations were conducted after calcination of the materials. The sorbent materials were subjected to thermogravimetric testing to determine comparative rates and extent of calcination (in inert gas) and sorption (in a simulated coal combustion flue gas mixture). Selected materials were exposed to five calcination/sorption cycles and showed no decrease in either sorption capacity or sorption rate. Process simulations were conducted involving different heat recovery schemes. The process is thermodynamically feasible. The sodium-based materials appear to have suitable physical properties for use as regenerable sorbents and, based on thermogravimetric testing, are likely to have sorption and calcination rates that are rapid enough to be of interest in full-scale carbon sequestration processes.

  19. Effect of characteristic of sorbents on their sulfur capture capability at a fluidized bed condition

    Energy Technology Data Exchange (ETDEWEB)

    Leming Cheng; Bo Chen; Ni Liu; Zhongyang Luo; Kefa Cen [Zhejiang University, Hangzhou (China). Clean Energy and Environment Engineering Key Lab of Ministry of Education, Institute for Thermal Power Engineering

    2004-05-01

    This research was intent for finding relationships among physical and/or chemical properties of sorbents and their sulfur capture capability at a fluidized bed condition. Three limestones and two seashells were chosen as a SO{sub 2} sorbent. Characteristics of sorbents were evaluated based on atomic absorption spectrophotometer, scanning electron microscope and mercury-penetration porosimeter analyses. Their sulfur capture capabilities were measured on a fluidized bed test system at 800, 850, 900 and 950{sup o}C. Conversion of the sobents was computed and analyzed depending on the sorbents' morphology and microstructure analysis. Results showed pore size and specific surface might have large influence on sorbents' desulfurization ability in the range of 800 950{sup o}C. 14 refs., 6 figs., 4 tabs.

  20. Aquifer storage and recovery: recent hydrogeological advances and system performance.

    Science.gov (United States)

    Maliva, Robert G; Guo, Weixing; Missimer, Thomas M

    2006-12-01

    Aquifer storage and recovery (ASR) is part of the solution to the global problem of managing water resources to meet existing and future freshwater demands. However, the metaphoric "ASR bubble" has been burst with the realization that ASR systems are more physically and chemically complex than the general conceptualization. Aquifer heterogeneity and fluid-rock interactions can greatly affect ASR system performance. The results of modeling studies and field experiences indicate that more sophisticated data collection and solute-transport modeling are required to predict how stored water will migrate in heterogeneous aquifers and how fluid-rock interactions will affect the quality of stored water. It has been well-demonstrated, by historic experience, that ASR systems can provide very large volumes of storage at a lesser cost than other options. The challenges moving forward are to improve the success rate of ASR systems, optimize system performance, and set expectations appropriately.

  1. Heat recovery unit operation of HVAC system in IMEF

    International Nuclear Information System (INIS)

    Paek, S. R.; Oh, Y. W.; Song, E. S.; Park, D. K.; Joo, Y. S.; Hong, K. P.

    2003-01-01

    HVAC system including a supply and exhaust air system in IMEF(Irradiated Materials Examination Facility) is an essential facility for preventing a leakage of radioactive materials and for a preservation of a working environment. It costs a lot to operate the HVAC system in IMEF because our ventilation type is once-through system, and an air flow is maintained from low level contamination area to high level and maintained high turns of ventilation air under certain conditions. As HRU(Heat Recovery Unit) at HVAC system based on PIEF(Post Irradiation Examination Facility) operation experiences is designed and adopted, it prevents from a heating coil freezing destruction in winter and makes much energy saving etc.. Heat pipe type HRU is adopted in IMEF, and a construction and operation result of HRU is examined

  2. Water Recovery System Architecture and Operational Concepts to Accommodate Dormancy

    Science.gov (United States)

    Carter, Layne; Tabb, David; Anderson, Molly

    2017-01-01

    Future manned missions beyond low Earth orbit will include intermittent periods of extended dormancy. The mission requirement includes the capability for life support systems to support crew activity, followed by a dormant period of up to one year, and subsequently for the life support systems to come back online for additional crewed missions. NASA personnel are evaluating the architecture and operational concepts that will allow the Water Recovery System (WRS) to support such a mission. Dormancy could be a critical issue due to concerns with microbial growth or chemical degradation that might prevent water systems from operating properly when the crewed mission began. As such, it is critical that the water systems be designed to accommodate this dormant period. This paper identifies dormancy issues, concepts for updating the WRS architecture and operational concepts that will enable the WRS to support the dormancy requirement.

  3. High capacity carbon dioxide sorbent

    Science.gov (United States)

    Dietz, Steven Dean; Alptekin, Gokhan; Jayaraman, Ambalavanan

    2015-09-01

    The present invention provides a sorbent for the removal of carbon dioxide from gas streams, comprising: a CO.sub.2 capacity of at least 9 weight percent when measured at 22.degree. C. and 1 atmosphere; an H.sub.2O capacity of at most 15 weight percent when measured at 25.degree. C. and 1 atmosphere; and an isosteric heat of adsorption of from 5 to 8.5 kilocalories per mole of CO.sub.2. The invention also provides a carbon sorbent in a powder, a granular or a pellet form for the removal of carbon dioxide from gas streams, comprising: a carbon content of at least 90 weight percent; a nitrogen content of at least 1 weight percent; an oxygen content of at most 3 weight percent; a BET surface area from 50 to 2600 m.sup.2/g; and a DFT micropore volume from 0.04 to 0.8 cc/g.

  4. Decontamination formulation with sorbent additive

    Science.gov (United States)

    Tucker; Mark D. , Comstock; Robert H.

    2007-10-16

    A decontamination formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a bleaching activator, a sorbent additive, and water. The highly adsorbent, water-soluble sorbent additive (e.g., sorbitol or mannitol) is used to "dry out" one or more liquid ingredients, such as the liquid bleaching activator (e.g., propylene glycol diacetate or glycerol diacetate) and convert the activator into a dry, free-flowing powder that has an extended shelf life, and is more convenient to handle and mix in the field.

  5. Robotic Mirror Therapy System for Functional Recovery of Hemiplegic Arms.

    Science.gov (United States)

    Beom, Jaewon; Koh, Sukgyu; Nam, Hyung Seok; Kim, Wonshik; Kim, Yoonjae; Seo, Han Gil; Oh, Byung-Mo; Chung, Sun Gun; Kim, Sungwan

    2016-08-15

    Mirror therapy has been performed as effective occupational therapy in a clinical setting for functional recovery of a hemiplegic arm after stroke. It is conducted by eliciting an illusion through use of a mirror as if the hemiplegic arm is moving in real-time while moving the healthy arm. It can facilitate brain neuroplasticity through activation of the sensorimotor cortex. However, conventional mirror therapy has a critical limitation in that the hemiplegic arm is not actually moving. Thus, we developed a real-time 2-axis mirror robot system as a simple add-on module for conventional mirror therapy using a closed feedback mechanism, which enables real-time movement of the hemiplegic arm. We used 3 Attitude and Heading Reference System sensors, 2 brushless DC motors for elbow and wrist joints, and exoskeletal frames. In a feasibility study on 6 healthy subjects, robotic mirror therapy was safe and feasible. We further selected tasks useful for activities of daily living training through feedback from rehabilitation doctors. A chronic stroke patient showed improvement in the Fugl-Meyer assessment scale and elbow flexor spasticity after a 2-week application of the mirror robot system. Robotic mirror therapy may enhance proprioceptive input to the sensory cortex, which is considered to be important in neuroplasticity and functional recovery of hemiplegic arms. The mirror robot system presented herein can be easily developed and utilized effectively to advance occupational therapy.

  6. Advanced Supermarket Refrigeration/Heat Recovery Systems. Country Report, Denmark

    DEFF Research Database (Denmark)

    Knudsen, Hans-Jørgen Høgaard; Christensen, K. G.

    Annex 26 is the first international project under the IEA Heat Pump Programme that links refrigeration and heat pump technology. Recovering heat from advanced supermarket refrigeration systems for space and water heating seems obvious and is beneficial for owners and operators. Because the great...... number of supermarkets that offer frozen and chilled food and further growth of this sector may be expected, the amount of energy used for refrigeration is enormous and will likely increase in the near future. Annex 26 analysed several advanced supermarket refrigeration systems and came to remarkable...... conclusions as far energy conservation and TEWI reduction is concerned. The conclusion justify that advanced supermarket systems with heat recovery should receive great attention and support. And there is still further research needed in several areas. The Annex also included a thorough system analyses...

  7. Nondestructive assay system development for a plutonium scrap recovery facility

    International Nuclear Information System (INIS)

    Hsue, S.T.; Baker, M.P.

    1984-01-01

    A plutonium scrap recovery facility is being constructed at the Savannah River Plant (SRP). The safeguards groups of the Los Alamos National Laboratory have been working since the early design stage of the facility with SRP and other national laboratories to develop a state-of-the-art assay system for this new facility. Not only will the most current assay techniques be incorporated into the system, but also the various nondestructive assay (NDA) instruments are to be integrated with an Instrument Control Computer (ICC). This undertaking is both challenging and ambitious; an entire assay system of this type has never been done before in a working facility. This paper will describe, in particular, the effort of the Los Alamos Safeguards Assay Group in this endeavor. Our effort in this project can be roughly divided into three phases: NDA development, system integration, and integral testing. 6 references

  8. Piloted Simulation of a Model-Predictive Automated Recovery System

    Science.gov (United States)

    Liu, James (Yuan); Litt, Jonathan; Sowers, T. Shane; Owens, A. Karl; Guo, Ten-Huei

    2014-01-01

    This presentation describes a model-predictive automatic recovery system for aircraft on the verge of a loss-of-control situation. The system determines when it must intervene to prevent an imminent accident, resulting from a poor approach. It estimates the altitude loss that would result from a go-around maneuver at the current flight condition. If the loss is projected to violate a minimum altitude threshold, the maneuver is automatically triggered. The system deactivates to allow landing once several criteria are met. Piloted flight simulator evaluation showed the system to provide effective envelope protection during extremely unsafe landing attempts. The results demonstrate how flight and propulsion control can be integrated to recover control of the vehicle automatically and prevent a potential catastrophe.

  9. Oil spill recovery technology

    International Nuclear Information System (INIS)

    Nash, J.; Cooper, W.; Nee, V.; Nigim, H.

    1992-01-01

    Current deficiencies in oil spill cleanup processes have resulted in research and development of new cleanup technologies at the University of Notre Dame. Emphasis on reducing, reusing and recycling equipment and waste at a cleanup site has prompted advances in oil recovery technology as well as improvement in sorbent materials. (author)

  10. Understanding Ammonium Transport in Bioelectrochemical Systems towards its Recovery

    Science.gov (United States)

    Liu, Ying; Qin, Mohan; Luo, Shuai; He, Zhen; Qiao, Rui

    2016-03-01

    We report an integrated experimental and simulation study of ammonia recovery using microbial electrolysis cells (MECs). The transport of various species during the batch-mode operation of an MEC was examined experimentally and the results were used to validate the mathematical model for such an operation. It was found that, while the generated electrical current through the system tends to acidify (or basify) the anolyte (or catholyte), their effects are buffered by a cascade of chemical groups such as the NH3/NH4+ group, leading to relatively stable pH values in both anolyte and catholyte. The transport of NH4+ ions accounts for ~90% of the total current, thus quantitatively confirming that the NH4+ ions serve as effective proton shuttles during MEC operations. Analysis further indicated that, because of the Donnan equilibrium at cation exchange membrane-anolyte/catholyte interfaces, the Na+ ion in the anolyte actually facilitates the transport of NH4+ ions during the early stage of a batch cycle and they compete with the NH4+ ions weakly at later time. These insights, along with a new and simple method for predicting the strength of ammonia diffusion from the catholyte toward the anolyte, will help effective design and operation of bioeletrochemical system-based ammonia recovery systems.

  11. System Behaviour Charts Inform an Understanding of Biodiversity Recovery

    Directory of Open Access Journals (Sweden)

    Simon A. Black

    2015-01-01

    Full Text Available Practitioners working with species and ecosystem recovery typically deal with the complexity of, on one hand, lack of data or data uncertainties and, on the other hand, demand for critical decision-making and intervention. The control chart methods of commercial and industrial and environmental monitoring can complement an ecological understanding of wildlife systems including those situations which incorporate human activities and land use. Systems Behaviour Charts are based upon well-established control chart methods to provide conservation managers with an approach to using existing data and enable insight to aid timely planning of conservation interventions and also complement and stimulate research into wider scientific and ecological questions. When the approach is applied to existing data sets in well-known wildlife conservation cases, the subsequent Systems Behaviour Charts and associated analytical criteria demonstrate insights which would be helpful in averting problems associated with each case example.

  12. Space systems for disaster warning, response, and recovery

    CERN Document Server

    Madry, Scott

    2015-01-01

    This SpringerBrief provides a general overview of the role of satellite applications for disaster mitigation, warning, planning, recovery and response. It covers both the overall role and perspective of the emergency management community as well as the various space applications that support their work. Key insights are provided as to how satellite telecommunications, remote sensing, navigation systems, GIS, and the emerging domain of social media are utilized in the context of emergency management needs and requirements. These systems are now critical in addressing major man-made and natural disasters. International policy and treaties are covered along with various case studies from around the world. These case studies indicate vital lessons that have been learned about how to use space systems more effectively in addressing the so-called “Disaster Cycle.” This book is appropriate for practicing emergency managers, Emergency Management (EM) courses, as well as for those involved in various space applica...

  13. IEA Annex 26: Advanced Supermarket Refrigeration/Heat Recovery Systems

    Energy Technology Data Exchange (ETDEWEB)

    Baxter, VAN

    2003-05-19

    With increased concern about the impact of refrigerant leakage on global warming, a number of new supermarket refrigeration system configurations requiring significantly less refrigerant charge are being considered. In order to help promote the development of advanced systems and expand the knowledge base for energy-efficient supermarket technology, the International Energy Agency (IEA) established IEA Annex 26 (Advanced Supermarket Refrigeration/Heat Recovery Systems) under the ''IEA Implementing Agreement on Heat Pumping Technologies''. Annex 26 focuses on demonstrating and documenting the energy saving and environmental benefits of advanced systems design for food refrigeration and space heating and cooling for supermarkets. Advanced in this context means systems that use less energy, require less refrigerant and produce lower refrigerant emissions. Stated another way, the goal is to identify supermarket refrigeration and HVAC technology options that reduce the total equivalent warming impact (TEWI) of supermarkets by reducing both system energy use (increasing efficiency) and reducing total refrigerant charge. The Annex has five participating countries: Canada, Denmark, Sweden, the United Kingdom, and the United States. The working program of the Annex has involved analytical and experimental investigation of several candidate system design approaches to determine their potential to reduce refrigerant usage and energy consumption. Advanced refrigeration system types investigated include the following: distributed compressor systems--small parallel compressor racks are located in close proximity to the food display cases they serve thus significantly shortening the connecting refrigerant line lengths; secondary loop systems--one or more central chillers are used to refrigerate a secondary coolant (e.g. brine, ice slurry, or CO2) that is pumped to the food display cases on the sales floor; self-contained display cases--each food display case

  14. Recovery Audit Contractor medical necessity readiness: one health system's journey.

    Science.gov (United States)

    Scott, Judith A; Camden, Mindy

    2011-01-01

    To develop a sustainable approach to Recovery Audit Contractor medical necessity readiness that mitigates the regulatory and financial risks of the organization. Acute care hospitals. Utilizing the model for improvement and plan-do-study-act methodology, this health system designed and implemented a medical necessity case management program. We focused on 3 areas for improvement: medical necessity review accuracy, review timeliness, and physician adviser participation for secondary reviews. Over several months, we improved accuracy and timeliness of our medical necessity reviews while also generating additional inpatient revenue for the health system. We successfully enhanced regulatory compliance and reduced our financial risks associated with Recovery Audit Contractor medical necessity audits. A successful medical necessity case management program can not only enhance regulatory compliance and reduce the amount of payments recouped by Medicare, but also generate additional inpatient revenue for your organization. With health care reform and accountable care organizations on the horizon, hospitals must find ways to protect and enhance revenue in order to carry out their missions. This is one way for case managers to help in that cause, to advocate for the care of their patients, and to bring value to the organization.

  15. Advanced Waste Heat Recovery Systems within Hybrid Powertrains

    Directory of Open Access Journals (Sweden)

    Albert Boretti

    2018-01-01

    Full Text Available A waste heat recovery system (WHRS is very well known to provide no advantage during the cold start driving cycles, such as the New European Driving Cycle (NEDC, which are used for certification of emissions and assessment of fuel economy. Here, we propose a novel integrated WHRS using the internal combustion engine (ICE coolant passages and an exchanger on the exhaust working as pre-heater / boiler / super-heater of a Rankine cycle. The expander is connected to an electric generator unit (GU, and the pump is connected to an electric motor unit (MU. The vehicle is also fitted with an electric, kinetic energy recovery system (KERS. The expander and condenser are bypassed during the first part of the NEDC when the vehicle covers the four ECE-15 (Economic Commission for Europe - 15 - UDC (Urban Drive Cycle segments where the engine warms-up.  Only after the engine is fully warmed up, during the last part of the NEDC, the extra urban driving cycle (EUDC segment, the expander and condenser are activated to recover part of the coolant and exhaust energy.

  16. Removal of mercury from coal-combustion flue gas using regenerable sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, C S; Albiston, J; Broderick, T E; Stewart, R M

    1999-07-01

    The US EPA estimates that coal-fired power plants constitute the largest anthropogenic source of mercury emissions in the US. The Agency has contemplated emission regulations for power plants, but the large gas-flow rates and low mercury concentrations involved have made current treatment options prohibitively expensive. ADA Technologies, Inc. (Englewood, Colorado), in conjunction with the US DOE, is developing regenerable sorbents for the removal and recovery of mercury from flue gas. These sorbents are based on the ability of noble metals to amalgamate mercury at typical flue-gas temperatures and release mercury at higher temperatures. The process allows for recovery of mercury with minimal volumes of secondary wastes and no impact on fly ash quality. In 1997 and 1998, ADA tested a 20-cfm sorbent unit at CONSOL Inc.'s coal-combustion test facility in Library, PA. Results from the 1997 tests indicated that the sorbent can remove elemental and oxidized mercury and can be regenerated without loss of capacity. Design changes were implemented in 1998 to enhance the thermal efficiency of the process and to recover the mercury in a stable form. Testing during autumn, 1998 demonstrated 60% to 90% removal efficiency of mercury from a variety of different coals. However, contradictory removal results were obtained at the end of the test period. Subsequent laboratory analyses indicated that the sorbent had lost over half its capacity for mercury due to a decrease in available sites for mercury sorption. The presence of sulfur compounds on the sorbent suggests that thermal cycling may have condensed acid gases on the sorbent leading to deterioration of the active sorption sites. The regeneration time/temperature profile has been altered to minimize this potential in the upcoming power plant tests.

  17. Energy Recovery from a Non-Linear Electromagnetic System

    Directory of Open Access Journals (Sweden)

    Kęcik Krzysztof

    2018-03-01

    Full Text Available The paper presents study of a pseudo-magnetic levitation system (pseudo-maglev dedicated for energy harvesting. The idea rely on motion of a pseudo-levitating magnet in a coil’s terminal. The study based on real prototype harvester system, which in the pendulum dynamic vibration absorber is applied. For some parameters, the stability loss caused by the period doubling bifurcation is detected. The coexistence of two stable solutions, one of which is much better for energy harvesting is observed. The influence of the pseudo-maglev parameters on the recovered current and stability of the periodic solutions is presented in detail. The obtained results show, that the best energy recovery occurs for the high pseudo-maglev stiffness and close to the coil resistance. The amplitude’s excitation, the load resistances and the coupling coefficient strongly influence on the system’s response.

  18. Phronesis, a diagnosis and recovery tool for system administrators

    International Nuclear Information System (INIS)

    Haen, C; Barra, V; Bonaccorsi, E; Neufeld, N

    2014-01-01

    The LHCb experiment relies on the Online system, which includes a very large and heterogeneous computing cluster. Ensuring the proper behavior of the different tasks running on the more than 2000 servers represents a huge workload for the small operator team and is a 24/7 task. At CHEP 2012, we presented a prototype of a framework that we designed in order to support the experts. The main objective is to provide them with steadily improving diagnosis and recovery solutions in case of misbehavior of a service, without having to modify the original applications. Our framework is based on adapted principles of the Autonomic Computing model, on Reinforcement Learning algorithms, as well as innovative concepts such as Shared Experience. While the submission at CHEP 2012 showed the validity of our prototype on simulations, we here present an implementation with improved algorithms and manipulation tools, and report on the experience gained with running it in the LHCb Online system.

  19. Passive ventilation systems with heat recovery and night cooling

    DEFF Research Database (Denmark)

    Hviid, Christian Anker; Svendsen, Svend

    2008-01-01

    with little energy consumption and with satisfying indoor climate. The concept is based on using passive measures like stack and wind driven ventilation, effective night cooling and low pressure loss heat recovery using two fluid coupled water-to-air heat exchangers developed at the Technical University......In building design the requirements for energy consumption for ventilation, heating and cooling and the requirements for increasingly better indoor climate are two opposing factors. This paper presents the schematic layout and simulation results of an innovative multifunc-tional ventilation concept...... of Denmark. Through building integration in high performance offices the system is optimized to incorporate multiple functions like heating, cooling and ventilation, thus saving the expenses of separate cooling and heating systems. The simulation results are derived using the state-of-the-art building...

  20. Development of the Next Generation Type Water Recovery System

    Science.gov (United States)

    Oguchi, Mitsuo; Tachihara, Satoru; Maeda, Yoshiaki; Ueoka, Terumi; Soejima, Fujito; Teranishi, Hiromitsu

    According to NASA, an astronaut living on the International Space Station (ISS) requires approximately 7 kg of water per day. This includes 2 kg of drinking water as well as sanitary fresh water for hand washing, gargling, etc. This water is carried to the space station from the earth, so when more people are staying on the space station, or staying for a longer period of time, the cost of transporting water increases. Accordingly, water is a valuable commodity, and restrictions are applied to such activities as brushing teeth, washing hair, and washing clothes. The life of an astronaut in space is not necessarily a healthy one. JAXA has experience in the research of water recovery systems. Today, utilizing knowledge learned through experiences living on the space station and space shuttles, and taking advantage of the development of new materials for device construction, it is possible to construct a new water recovery system. Therefore, JAXA and New Medican Tech Corporation (NMT) have created a system for collaborative development. Based on the technologies of both companies, we are proceeding to develop the next generation of water recovery devices in order to contribute to safe, comfortable, and healthy daily life for astronauts in space. The goal of this development is to achieve a water purification system based on reverse osmosis (RO) membranes that can perform the following functions. • Preprocessing that removes ammonia and breaks down organic matter contained in urine. • Post-processing that adds minerals and sterilizes the water. • Online TOC measurement for monitoring water quality. • Functions for measuring harmful substances. The RO membrane is an ultra-low-pressure type membrane with a 0.0001 micron (0.1 nanometer) pore size and an operating pressure of 0.4 to 0.6 MPa. During processing with the RO membrane, nearly all of the minerals contained in the cleaned water are removed, resulting in water that is near the quality of deionized water

  1. Microlith-based Structured Sorbent for Carbon Dioxide, Humidity, and Trace Contaminant Control in Manned Space Habitats

    Science.gov (United States)

    Junaedi, Christian; Roychoudhury, SUbir; Howard, David F.; Perry, Jay L.; Knox, James C.

    2011-01-01

    To support continued manned space exploration, the development of atmosphere revitalization systems that are lightweight, compact, durable, and power efficient is a key challenge. The systems should be adaptable for use in a variety of habitats and should offer operational functionality to either expel removed constituents or capture them for closedloop recovery. As mission durations increase and exploration goals reach beyond low earth orbit, the need for regenerable adsorption processes for continuous removal of CO2 and trace contaminants from cabin air becomes critical. Precision Combustion, Inc. (PCI) and NASA Marshall (MSFC) have been developing an Engineered Structured Sorbents (ESS) approach based on PCI s patented Microlith technology to meet the requirements of future, extended human spaceflight explorations. This technology offers the inherent performance and safety attributes of zeolite and other sorbents with greater structural integrity, regenerability, and process control, thereby providing potential durability and efficiency improvements over current state-of-the-art systems. The major advantages of the ESS explored in this study are realized through the use of metal substrates to provide structural integrity (i.e., less partition of sorbents) and enhanced thermal control during the sorption process. The Microlith technology also offers a unique internal resistive heating capability that shows potential for short regeneration time and reduced power requirement compared to conventional systems. This paper presents the design, development, and performance results of the integrated adsorber modules for removing CO2, water vapor, and trace chemical contaminants. A related effort that utilizes the adsorber modules for sorption of toxic industrial chemicals is also discussed. Finally, the development of a 4-person two-leg ESS system for continuous CO2 removal is also presented.

  2. Vacuum system of the compact Energy Recovery Linac

    Energy Technology Data Exchange (ETDEWEB)

    Honda, T., E-mail: tohru.honda@kek.jp; Tanimoto, Y.; Nogami, T.; Takai, R.; Obina, T.; Asaoka, S.; Uchiyama, T.; Nakamura, N. [High Energy Accelerator Research Organization (KEK) (1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan) (Japan)

    2016-07-27

    The compact Energy Recovery Linac (cERL), a test accelerator to establish important technologies demanded for future ERL-based light sources, was constructed in late 2013 at KEK. The accelerator was successfully commissioned in early 2014, and demonstrated beam circulation with energy recovery. In the cERL vacuum system, low-impedance vacuum components are required to circulate high-intensity, low-emittance and short-bunch electron beams. We therefore developed ultra-high-vacuum (UHV)-compatible flanges that can connect beam tubes seamlessly, and employed retractable beam monitors, namely, a movable Faraday cup and screen monitors. In most parts of the accelerator, pressures below 1×10{sup −7} Pa are required to mitigate beam-gas interactions. Particularly, near the photocathode electron gun and the superconducting (SC) cavities, pressures below 1×10{sup −8} Pa are required. The beam tubes in the sections adjoining the SC cavities were coated with non-evaporable getter (NEG) materials, to reduce gas condensation on the cryo-surfaces. During the accelerator commissioning, stray magnetic fields from the permanent magnets of some cold cathode gauges (CCGs) were identified as a source of the disturbance to the beam orbit. Magnetic shielding was specially designed as a remedy for this issue.

  3. Sorbent Nanotechnologies for Water Cleaning

    Science.gov (United States)

    Ahmed, Snober

    Despite decades of regulatory efforts to mitigate water pollution, many chemicals, particularly heavy metals, still present risks to human health. In addition to direct exposure, certain metals such as mercury threaten public health due to its persistence, bioaccumulation and bioamplification throughout the food chain. A number of U.S. Federal and State regulations have been established to reduce the levels of mercury in water. Activated carbon (AC) has been widely explored for the removal of mercury. However, AC suffers from many limitations inherent to its chemical properties, and it becomes increasingly challenging to meet current and future regulations by simply modifying AC to enhance its performance. Recently, the performance of nanosorbents have been studied in order to removal pollutants. Nanosorbents utilize the ultra-high reactive surface of nanoparticles for rapid, effective and even permanent sequestration of heavy metals from water and air, thus showed promising results as compared to AC. The goal of this thesis research is to develop nanomaterial-based sorbents for the removal of mercury from water. It describes the development of a new solid-support assisted growth of selenium nanoparticles, their use for water remediation, and the development of a new nanoselenium-based sorbent sponge for fast and efficient mercury removal. The nanoselenium sorbent not only shows irreversible interaction with mercury but also exhibits remarkable properties by overcoming the limitations of AC. The nanoselenium sponge was shown to remove mercury to undetectable levels within one minute. This new sponge technology would have an impact on inspiring new stringent regulations and lowering costs to help industries meet regulatory requirements, which will ultimately help improve air and water quality, aquatic life and public health.

  4. Energy-Recovery Pressure-Reducer in District Heating System

    Directory of Open Access Journals (Sweden)

    Dariusz Borkowski

    2018-06-01

    Full Text Available Already existing man-made infrastructures that create water flow and unused pressure are interesting energy sources to which micro-hydropower plants can be applied. Apart from water supply systems (WSSs, which are widely described in the literature, significant hydropower potential can also be found in district heating systems (DHSs. In this paper, a prototype, a so-called energy-recovery pressure-reducer (ERPR, utilized for a DHS, is presented. It consisted of a pump as a turbine coupled to a permanent magnet synchronous generator (PMSG. The latter was connected to the power grid through the power electronic unit (PEU. The variable-speed operation allowed one to modify the turbine characteristics to match the substation’s hydraulic conditions. The proposed ERPR device could be installed in series to the existing classic pressure reducing valve (PRV as an independent device that reduces costs and simplifies system installation. The test results of the prototype system located in a substation of Cracow’s DHS are presented. The steady-state curves and regulation characteristics show the prototype’s operating range and efficiency. In this study, the pressure-reducer impact on the electrical and hydraulic systems, and on the environment, were analyzed. The operation tests during the annual heating season revealed an average system’s efficiency of 49%.

  5. Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage

    Directory of Open Access Journals (Sweden)

    Yannan Zhang

    2016-10-01

    Full Text Available To store low-temperature heat below 100 °C, novel composite sorbents were developed by impregnating LiCl into expanded vermiculite (EVM in this study. Five kinds of composite sorbents were prepared using different salt concentrations, and the optimal sorbent for application was selected by comparing both the sorption characteristics and energy storage density. Textural properties of composite sorbents were obtained by extreme-resolution field emission scanning electron microscopy (ER-SEM and an automatic mercury porosimeter. After excluding two composite sorbents which would possibly exhibit solution leakage in practical thermal energy storage (TES system, thermochemical characterizations were implemented through simulative sorption experiments at 30 °C and 60% RH. Analyses of thermogravimetric analysis/differential scanning calorimetry (TGA/DSC curves indicate that water uptake of EVM/LiCl composite sorbents is divided into three parts: physical adsorption of EVM, chemical adsorption of LiCl crystal, and liquid–gas absorption of LiCl solution. Energy storage potential was evaluated by theoretical calculation based on TGA/DSC curves. Overall, EVMLiCl20 was selected as the optimal composite sorbent with water uptake of 1.41 g/g, mass energy storage density of 1.21 kWh/kg, and volume energy storage density of 171.61 kWh/m3.

  6. Evaluation of silk-floss fiber and dog fur as sorbent materials for the petroleum sector

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Lucas P. dos [Universidade Federal do Parana (PGMec/UFPR), Curitiba, PR (Brazil). Programa de Pos-Graduacao em Engenharia Mecanica; Dubiella, Juliana [Universidade Federal do Parana (DEMEC/UFPR), Curitiba, PR (Brazil). Dept. de Engenharia Mecanica. Programa Institucional de Bolsas de Iniciacao Cientifica; Perotta, Larissa [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil). Programa Interdisciplinar em Engenharia de Petroleo e Gas Natural; Satyanarayana, Kestur G. [Universidade Federal do Parana (UFPR), Curitiba, PR (Brazil). Dept. de Quimica; Flores-Sahagun, Thais Sydenstricker [Universidade Federal do Parana (DEMEC/UFPR), Curitiba, PR (Brazil). Dept. de Engenharia Mecanica

    2009-07-01

    In this study silk-floss and dog fur were tested as sorbent materials for oils and the results were compared with peat, a commercial sorbent. Sorption tests were carried out in dry and aqueous systems, with and without stirring for different periods of time (5-1440 min). Density, hydrophobicity, buoyancy and water uptake by the fibers of the impregnated sorbents have been determined. The use of silk-floss and dog fur was also tested in columns to purify water containing toluene, benzene, motor oil or sunflower oil. Breakthrough curves during 120 min were drawn for each material with the samples (oily water or water containing benzene or toluene) and were analyzed by ultraviolet spectroscopy. It was concluded that the silk-floss is the best sorbent material (65.3 g oil/g sorbent) followed by the dog fur (34.6 g oil/g sorbent) and peat (19.5 g oil/g sorbent), for sorption time of 1 h in dynamic condition. The efficiency of the pollutant removal from water with the use of adsorption columns was high for both materials although the use of dog fur was preferable because of the slight superiority in efficiency compared to silk-floss and also, due to the easier packing of the dog fur in the column. (author)

  7. System and process for capture of H.sub.2S from gaseous process streams and process for regeneration of the capture agent

    Science.gov (United States)

    Heldenbrant, David J; Koech, Phillip K; Rainbolt, James E; Bearden, Mark D; Zheng, Feng

    2014-02-18

    A system and process are disclosed for selective removal and recovery of H.sub.2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H.sub.2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H.sub.2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.

  8. Lime-Based Sorbents for High-Temperature CO2 Capture—A Review of Sorbent Modification Methods

    Science.gov (United States)

    Manovic, Vasilije; Anthony, Edward J.

    2010-01-01

    This paper presents a review of the research on CO2 capture by lime-based looping cycles undertaken at CanmetENERGY’s (Ottawa, Canada) research laboratories. This is a new and very promising technology that may help in mitigation of global warming and climate change caused primarily by the use of fossil fuels. The intensity of the anticipated changes urgently requires solutions such as more cost-effective technologies for CO2 capture. This new technology is based on the use of lime-based sorbents in a dual fluidized bed combustion (FBC) reactor which contains a carbonator—a unit for CO2 capture, and a calciner—a unit for CaO regeneration. However, even though natural materials are cheap and abundant and very good candidates as solid CO2 carriers, their performance in a practical system still shows significant limitations. These limitations include rapid loss of activity during the capture cycles, which is a result of sintering, attrition, and consequent elutriation from FBC reactors. Therefore, research on sorbent performance is critical and this paper reviews some of the promising ways to overcome these shortcomings. It is shown that reactivation by steam/water, thermal pre-treatment, and doping simultaneously with sorbent reforming and pelletization are promising potential solutions to reduce the loss of activity of these sorbents over multiple cycles of use. PMID:20948952

  9. Lime-Based Sorbents for High-Temperature CO2 Capture—A Review of Sorbent Modification Methods

    Directory of Open Access Journals (Sweden)

    Edward J. Anthony

    2010-08-01

    Full Text Available This paper presents a review of the research on CO2 capture by lime-based looping cycles undertaken at CanmetENERGY’s (Ottawa, Canada research laboratories. This is a new and very promising technology that may help in mitigation of global warming and climate change caused primarily by the use of fossil fuels. The intensity of the anticipated changes urgently requires solutions such as more cost-effective technologies for CO2 capture. This new technology is based on the use of lime-based sorbents in a dual fluidized bed combustion (FBC reactor which contains a carbonator—a unit for CO2 capture, and a calciner—a unit for CaO regeneration. However, even though natural materials are cheap and abundant and very good candidates as solid CO2 carriers, their performance in a practical system still shows significant limitations. These limitations include rapid loss of activity during the capture cycles, which is a result of sintering, attrition, and consequent elutriation from FBC reactors. Therefore, research on sorbent performance is critical and this paper reviews some of the promising ways to overcome these shortcomings. It is shown that reactivation by steam/water, thermal pre-treatment, and doping simultaneously with sorbent reforming and pelletization are promising potential solutions to reduce the loss of activity of these sorbents over multiple cycles of use.

  10. Process options and projected mass flows for the HTGR refabrication scrap recovery system

    International Nuclear Information System (INIS)

    Tiegs, S.M.

    1979-03-01

    The two major uranium recovery processing options reviewed are (1) internal recovery of the scrap by the refabrication system and (2) transfer to and external recovery of the scrap by the head end of the reprocessing system. Each option was reviewed with respect to equipment requirements, preparatory processing, and material accountability. Because there may be a high cost factor on transfer of scrap fuel material to the reprocessing system for recovery, all of the scrap streams will be recycled internally within the refabrication system, with the exception of reject fuel elements, which will be transferred to the head end of the reprocessing system for uranium recovery. The refabrication facility will be fully remote; thus, simple recovery techniques were selected as the reference processes for scrap recovery. Crushing, burning, and leaching methods will be used to recover uranium from the HTGR refabrication scrap fuel forms, which include particles without silicon carbide coatings, particles with silicon carbide coatings, uncarbonized fuel rods, carbon furnace parts, perchloroethylene distillation bottoms, and analytical sample remnants. Mass flows through the reference scrap recovery system were calculated for the HTGR reference recycle facility operating with the highly enriched uranium fuel cycle. Output per day from the refabrication scrap recovery system is estimated to be 4.02 kg of 2355 U and 10.85 kg of 233 U. Maximum equipment capacities were determined, and future work will be directed toward the development and costing of the scrap recovery system chosen as reference

  11. Assessing nuclear power plant safety and recovery from earthquakes using a system-of-systems approach

    International Nuclear Information System (INIS)

    Ferrario, E.; Zio, E.

    2014-01-01

    We adopt a ‘system-of-systems’ framework of analysis, previously presented by the authors, to include the interdependent infrastructures which support a critical plant in the study of its safety with respect to the occurrence of an earthquake. We extend the framework to consider the recovery of the system of systems in which the plant is embedded. As a test system, we consider the impacts produced on a nuclear power plant (the critical plant) embedded in the connected power and water distribution, and transportation networks which support its operation. The Seismic Probabilistic Risk Assessment of such system of systems is carried out by Hierarchical modeling and Monte Carlo simulation. First, we perform a top-down analysis through a hierarchical model to identify the elements that at each level have most influence in restoring safety, adopting the criticality importance measure as a quantitative indicator. Then, we evaluate by Monte Carlo simulation the probability that the nuclear power plant enters in an unsafe state and the time needed to recover its safety. The results obtained allow the identification of those elements most critical for the safety and recovery of the nuclear power plant; this is relevant for determining improvements of their structural/functional responses and supporting the decision-making process on safety critical-issues. On the test system considered, under the given assumptions, the components of the external and internal water systems (i.e., pumps and pool) turn out to be the most critical for the safety and recovery of the plant. - Highlights: • We adopt a system-of-system framework to analyze the safety of a critical plant exposed to risk from external events, considering also the interdependent infrastructures that support the plant. • We develop a hierarchical modeling framework to represent the system of systems, accounting also for its recovery. • Monte Carlo simulation is used for the quantitative evaluation of the

  12. TG-FTIR measurement of CO2-H2O co-adsorption for CO2 air capture sorbent screening

    NARCIS (Netherlands)

    Smal, I.M.; Yu, Qian; Veneman, Rens; Fränzel-Luiten, B.; Brilman, Derk Willem Frederik

    2014-01-01

    Capturing atmospheric CO2 using solid sorbents is gaining interest. As ambient air normally contains much more (up to 100 times) water than CO2, a selective sorbent is desirable as co-adsorption will most likely occur. In this study, a convenient method based on an TG-FTIR analysis system is

  13. System tradeoffs in siting a solar photovoltaic material recovery infrastructure.

    Science.gov (United States)

    Goe, Michele; Gaustad, Gabrielle; Tomaszewski, Brian

    2015-09-01

    The consumption and disposal of rare and hazardous metals contained in electronics and emerging technologies such as photovoltaics increases the material complexity of the municipal waste stream. Developing effective waste policies and material recovery systems is required to inhibit landfilling of valuable and finite resources. This work developed a siting and waste infrastructure configuration model to inform the management and recovery of end-of-life photovoltaics. This model solves the siting and waste location-allocation problem for a New York State case study by combining multi-criteria decision methods with spatial tools, however this methodology is generalizable to any geographic area. For the case study, the results indicate that PV installations are spatially statistically significant (i.e., clustered). At least 9 sites, which are co-located with landfills and current MRFs, were 'highly' suitable for siting according to our criteria. After combining criteria in an average weighted sum, 86% of the study area was deemed unsuitable for siting while less than 5% is characterized as highly suitable. This method implicitly prioritized social and environmental concerns and therefore, these concerns accounted for the majority of siting decisions. As we increased the priority of economic criteria, the likelihood of siting near ecologically sensitive areas such as coastline or socially vulnerable areas such as urban centers increased. The sensitivity of infrastructure configurations to land use and waste policy are analyzed. The location allocation model results suggest current tip fees are insufficient to avoid landfilling of photovoltaics. Scenarios where tip fees were increased showed model results where facilities decide to adopt limited recycling technologies that bypass compositionally complex materials; a result with strong implications for global PV installations as well as other waste streams. We suggest a multi-pronged approach that lowers technology cost

  14. Duct burners in heat recovery system for cogeneration and captive power plants

    International Nuclear Information System (INIS)

    Majumdar, J.

    1992-01-01

    Our oil explorations both onshore and offshore have thrown open bright prospects of cogeneration by using natural gas in gas turbine power plants with heat recovery units. Both for co-gen and combined cycle systems, supplementary firing of GT exhaust gas is normally required. Hence, duct burners have significant role for effective contribution towards of efficacy of heat recovery system for gas turbine exhaust gas. This article details on various aspects of duct burners in heat recovery systems. (author)

  15. High temperature heat recovery systems; Les recuperateurs de chaleur a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Martin, L.

    2003-07-15

    A state-of-the-art of high temperature heat recovery systems has been made to highlight the advantages of recovery in different energy cycles, and to compare the different geometries, materials and fabrication processes used by the different manufacturers. This leads to define the criteria that a heat recovery system must satisfy in gas turbine cogeneration applications. The pre-dimensioning of a recovery system has been performed in order to compare different geometries and to evaluate them with respect to the criteria defined in the bibliographic study. Finally, the new configuration of the 'Claire' loop has permitted to experimentally characterize a recovery system with an innovative technology based on an helical geometry. These tests have permitted to obtain the global data of the recovery system (efficiency, pressure drop, global exchange coefficient, friction coefficient, velocity and temperature profiles) and to position it with respect to the criteria defined in the bibliographic study. (J.S.)

  16. Lithium test module on ITER: engineering design of the tritium recovery system

    International Nuclear Information System (INIS)

    Finn, P.A.

    1988-01-01

    The design presented is an overview of the tritium recovery system for a lithium module on an ITER type reactor. The design of a tritium recovery system for larger blanket units, sectors, etc. could use the information developed in this report. A goal of this design was to ensure that a reliable, integrated performance of the tritium recovery system could be demonstrated. An equally important goal was to measure and account for the tritium in the liquid lithium blanket module and its recovery system in order to validate the operation of the blanket module

  17. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30

    includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  18. Novel approach to high-throughput determination of endocrine disruptors using recycled diatomaceous earth as a green sorbent phase for thin-film solid-phase microextraction combined with 96-well plate system.

    Science.gov (United States)

    Kirschner, Nicolas; Dias, Adriana Neves; Budziak, Dilma; da Silveira, Cristian Berto; Merib, Josias; Carasek, Eduardo

    2017-12-15

    A sustainable approach to TF-SPME is presented using recycled diatomaceous earth, obtained from a beer purification process, as a green sorbent phase for the determination of bisphenol A (BPA), benzophenone (BzP), triclocarban (TCC), 4-methylbenzylidene camphor (4-MBC) and 2-ethylhexyl-p-methoxycinnamate (EHMC) in environmental water samples. TF-SPME was combined with a 96-well plate system allowing for high-throughput analysis due to the simultaneous extraction/desorption up to 96 samples. The proposed sorbent phase exhibited good stability in organic solvents, as well as satisfactory analytical performance. The optimized method consisted of 240 min of extraction at pH 6 with the addition of NaCl (15% w/v). A mixture of MeOH:ACN (50:50 v/v) was used for the desorption the analytes, using a time of 30 min. Limits of detection varied from 1 μg L -1 for BzP and TCC to 8 μg L -1 for the other analytes, and R 2 ranged from 0.9926 for 4-MBC to 0.9988 for BPA. This novel and straightforward approach offers an environmentally-friendly and very promising alternative for routine analysis. . The total sample preparation time per sample was approximately 2.8 min, which is a significant advantage when a large number of analytical run is required. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Systems analysis for the development of small resource recovery systems: system performance data. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Crnkovich, P G; Helmstetter, A J

    1980-10-01

    The technologies that should be developed to make small-scale solid waste processing facilities attractive and viable for small municipalities with solid waste between 50 and 250 tons per day are identified. The resource recovery systems investigated were divided into three categories: thermal processng, mechanical separation, and biological processing. Thermal processing systems investigated are: excess-air incineration; starved-air incineration/gasification; and pyrolysis (indirect heating). Mechanical processing systems investigated are: coarse refuse derived fuel; materials separation; dust refuse derived fuel; densified refuse derived fuel; and fine refuse derived fuel. Mechanical processing components investigated include: receiving module; primary size reduction module; combustible separation module; refuse derived fuel preparation module; fuel densification; fuel storage module; ferrous separation; and building and facilities. Pretreatment processes and principle methods of bioconversion of MSW dealing with biological processing are investigated. (MCW)

  20. 40 CFR 35.928-3 - Implementation of the industrial cost recovery system.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 1 2010-07-01 2010-07-01 false Implementation of the industrial cost...-Clean Water Act § 35.928-3 Implementation of the industrial cost recovery system. (a) When a grantee's industrial cost recovery system is approved, implementation of the approved system shall become a condition...

  1. Retrofit acid gas emission control for municipal waste incineration application of dry sorbent injection

    International Nuclear Information System (INIS)

    Zmuda, J.T.; Smith, P.V.

    1991-01-01

    Dry sorbent injection (DSI) has been successfully demonstrated on coal fired boiler applications as a means of reducing sulfur dioxide emissions. More recently, the dry sorbent injection process was applied to an existing municipal waste incinerator to provide acid gas emission controls. The results obtained from the successful demonstration of the sorbent injection system on an existing municipal incinerator are presented. Removal efficiencies of compounds such as HCl, SO 2 , SO 3 , mercury, and others by the use of sorbent injection are shown. Effects of the DSI system on downstream equipment, such as electrostatic precipitators, fabric filters, ash handling systems, and waste management is included. The impacts of the DSI system on the furnace is also discussed. In this paper a discussion of dry sorbent injection as a means of reducing acid gas and other emissions from existing municipal waste incinerators which may be affected by the regulations is presented. An application case study will outline typical exhaust conditions, expected pollution reductions, capital and operating costs, and type of available sorbents and their costs

  2. Evaluation of Solid Sorbents as a Retrofit Technology for CO2 Capture

    Energy Technology Data Exchange (ETDEWEB)

    Sjostrom, Sharon [Ada-Es, Inc., Highlands Ranch, CO (United States)

    2016-06-02

    ADA completed a DOE-sponsored program titled Evaluation of Solid Sorbents as a Retrofit Technology for CO2 Capture under program DE-FE0004343. During this program, sorbents were analyzed for use in a post-combustion CO2 capture process. A supported amine sorbent was selected based upon superior performance to adsorb a greater amount of CO2 than the activated carbon sorbents tested. When the most ideal sorbent at the time was selected, it was characterized and used to create a preliminary techno-economic analysis (TEA). A preliminary 550 MW coal-fired power plant using Illinois #6 bituminous coal was designed with a solid sorbent CO2 capture system using the selected supported amine sorbent to both facilitate the TEA and to create the necessary framework to scale down the design to a 1 MWe equivalent slipstream pilot facility. The preliminary techno-economic analysis showed promising results and potential for improved performance for CO2 capture compared to conventional MEA systems. As a result, a 1 MWe equivalent solid sorbent system was designed, constructed, and then installed at a coal-fired power plant in Alabama. The pilot was designed to capture 90% of the CO2 from the incoming flue gas at 1 MWe net electrical generating equivalent. Testing was not possible at the design conditions due to changes in sorbent handling characteristics at post-regenerator temperatures that were not properly incorporated into the pilot design. Thus, severe pluggage occurred at nominally 60% of the design sorbent circulation rate with heated sorbent, although no handling issues were noted when the system was operated prior to bringing the regenerator to operating temperature. Testing within the constraints of the pilot plant resulted in 90% capture of the incoming CO2 at a flow rate equivalent of 0.2 to 0.25 MWe net electrical generating equivalent. The reduction in equivalent flow rate at 90% capture was

  3. Hybrid heat recovery - flat plate Stirling engine system

    International Nuclear Information System (INIS)

    Bogdanizh, A.M.; Budin, R.; Sutlovizh, I.

    2000-01-01

    In this paper, the possibility of process condensate heat recovery for boiler water preheating as well as for combined heat and power production for chosen process in textile industry has been investigated. The garment industry requires low pressure process steam or hot water for which production expensive fossil fuel should be used. Fuel usage can be reduced by various energy conservation methods. During the process a great quantity of hot condensate or waste hot water is rejected in the sewage system. To reduce heat wastes and improve technological process this condensate could be returned to the boiler for feed water preheating. When 60% condensate is returned to the steam generator about 8 % natural gas is saved. The rest of the condensate should be used for driving low temperature flat plate Stirling motor the advantage of the flat plate Stirling engine is ability to work at low temperatures. This engine produces electrical energy which can put in motion an electrogenerator in the same plant. While Stirling engine can be used electrical power and economical effect could be much greater using such a hybrid system the process waste heat is not only converted into useful work but at the same time thermal pollution is greatly diminished. (Author)

  4. LHCb: Phronesis, a diagnosis and recovery tool for system administrators

    CERN Multimedia

    Haen, C; Bonaccorsi, E; Neufeld, N

    2013-01-01

    The backbone of the LHCb experiment is the Online system, which is a very large and heterogeneous computing center. Making sure of the proper behavior of the many different tasks running on the more than 2000 servers represents a huge workload for the small expert-operator team and is a 24/7 task. At the occasion of CHEP 2012, we presented a prototype of a framework that we designed in order to support the experts. The main objective is to provide them with always improving diagnosis and recovery solutions in case of misbehavior of a service, without having to modify the original applications. Our framework is based on adapted principles of the Autonomic Computing model, on reinforcement learning algorithms, as well as innovative concepts such as Shared Experience. While the presentation made at CHEP 2012 showed the validity of our prototype on simulations, we here present a version with improved algorithms, manipulation tools, and report on experience with running it in the LHCb Online system.

  5. WASTE HEAT RECOVERY IN HEAT PUMP SYSTEMS: SOLUTION TO REDUCE GLOBAL WARMING

    Directory of Open Access Journals (Sweden)

    Y. Baradey

    2015-11-01

    Full Text Available Energy conversion technologies, where waste heat recovery systems are included, have received significant attention in recent years due to reasons that include depletion of fossil fuel, increasing oil prices, changes in climatic conditions, and global warming. For low temperature applications, there are many sources of thermal waste heat, and several recovery systems and potential useful applications have been proposed by researchers [1-4]. In addition, many types of equipment are used to recover waste thermal energy from different systems at low, medium, and high temperature applications, such as heat exchangers, waste heat recovery boiler, thermo-electric generators, and recuperators. In this paper, the focus is on waste heat recovery from air conditioners, and an efficient application of these energy resources. Integration of solar energy with heat pump technologies and major factors that affect the feasibility of heat recovery systems have been studied and reviewed as well. KEYWORDS: waste heat recovery; heat pump.

  6. Sorbents for the oxidation and removal of mercur

    Science.gov (United States)

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

    2017-09-12

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  7. Sorbents for the oxidation and removal of mercury

    Science.gov (United States)

    Olson, Edwin S [Grand Forks, ND; Holmes, Michael J [Thompson, ND; Pavlish, John H [East Grand Forks, MN

    2008-10-14

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  8. Sorbents for the oxidation and removal of mercury

    Science.gov (United States)

    Olson, Edwin S [Grand Forks, ND; Holmes, Michael J [Thompson, ND; Pavlish, John H [East Grand Forks, MN

    2012-05-01

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  9. Data summary report for M.W. Kellogg Z-sorb sorbent tests. CRADA 92-008 Final report

    Energy Technology Data Exchange (ETDEWEB)

    Everett, C E; Monaco, S J

    1994-05-01

    A series of tests were undertaken from August 6, 1992 through July 6, 1993 at METC`s High Pressure Bench-Scale Hot Gas Desulfurization Unit to support a Cooperative Research and Development Agreement (CRADA) between METC`s Sorbent Development Cluster and M.W. Kellogg. The M.W. Kellogg Company is currently developing a commercial offering of a hot gas clean-up system to be used in Integrated Gasification Combined Cycle (IGCC) systems. The intent of the CRADA agreement was to identify a suitable zinc-based desulfurization sorbent for the Sierra Pacific Power Company Clean Coal Technology Project, to identify optimum operating conditions for the sorbent, and to estimate potential sorbent loss per year. This report presents results pertaining to Phillips Petroleum`s Z-Sorb III sorbent.

  10. Lawrence Livermore Laboratory concept for uranium recovery from seawater

    International Nuclear Information System (INIS)

    Gregg, D.; Wang, F.

    1980-01-01

    The Lawrence Livermore Laboratory concept for uranium recovery from seawater involves the following process steps: (1) produce activated carbon via a coal gasification plant; (2) contact activated carbon sorbent with seawater using a settling process (no pumping of seawater); (3) vacuum activated carbon from sea floor; (4) gasify or burn activated carbon (further concentrating the uranium in the ash); (5) extract the uranium from the rich ash ore by conventional techniques. The process advantages are: (1) eliminates seawater pumping, the need for an illuent, and the need for a fresh water wash; (2) should result in much lower capital investment and regional process energy. Major process issues are: (1) uranium loading on activated carbon; (2) activated carbon modifications required to improve the sorbtion performance; (3) activated carbon particle size needed to meet system requirements; (4) minimization of sorbent losses when contacted with seawater

  11. Sorption of methylxanthines by different sorbents

    Science.gov (United States)

    Dmitrienko, S. G.; Andreeva, E. Yu.; Tolmacheva, V. V.; Terent'eva, E. A.

    2013-05-01

    Sorption of caffeine, theophylline, theobromine, diprophylline, and pentoxyphylline on different sorbents (supercross-linked polystyrene, surface-modified copolymer of styrene and divinylbenzene Strata-X, and carbon nanomaterials Taunit and Diasorb-100-C16T) was studied in a static mode in an effort to find new sorbents suitable for sorption isolation and concentration of methylxanthines. The peculiarities of sorption of methylxanthines were explained in relation to the solution acidity, the nature of the sorbates and their concentration, the nature of the solvent, and the structural characteristics of the sorbents.

  12. Sorbents for waste water purification from radionuclides and other toxic substances

    International Nuclear Information System (INIS)

    Maddalone, R.F.; MakKlenason, L.Ts.

    1996-01-01

    The TRW firm (USA) developed the system for sorption and disposal of radionuclides, heavy metals and organic substances, based on utilization of carbon sorbents. The sorbent is produced through processing natural coal by alkali-salt solution and has a large specific pores surface (up to 1000 m 2 /g). The sorbent carboxyl ionogenic groups are able of absorbing heavy metals cations from waste waters. Sorption by uranium constituted 30 mg/l. The sorbent with absorbed substances may be burnt (it contains no sulfur) or delivered for vitrification. The volume of disposed materials constitutes in comparison with existing techniques for uranium isotopes 420000 : 1. The costs are reduced up to 0.26 doll/m 2 of reprocessed water. 2 refs., 2 figs., 4 tabs

  13. Experimental investigation of various vegetable fibers as sorbent materials for oil spills.

    Science.gov (United States)

    Annunciado, T R; Sydenstricker, T H D; Amico, S C

    2005-11-01

    Oil spills are a global concern due to their environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. This research investigates the use of various vegetable fibers, namely mixed leaves residues, mixed sawdust, sisal (Agave sisalana), coir fiber (Cocos nucifera), sponge-gourd (Luffa cylindrica) and silk-floss as sorbent materials of crude oil. Sorption tests with crude oil were conducted in deionized and marine water media, with and without agitation. Water uptake by the fibers was investigated by tests in dry conditions and distillation of the impregnated sorbent. The silk-floss fiber showed a very high degree of hydrophobicity and oil sorption capacity of approximately 85goil/g sorbent (in 24hours). Specific gravity measurements and buoyancy tests were also used to evaluate the suitability of these fibers for the intended application.

  14. Experimental investigation of various vegetable fibers as sorbent materials for oil spills

    Energy Technology Data Exchange (ETDEWEB)

    Annunciado, T.R.; Sydenstricker, T.H.D.; Amico, S.C. [Federal University of Parana, Curitiba, (Brazil). Department of Mechanical Engineering

    2005-11-15

    Oil spills are a global concern due to their environmental and economical impact. various commercial systems have been developed to control these spills, including the use of fibers as sorbents. This research investigates the use of various vegetable fibers, namely mixed leaves residues, mixed sawdust, sisal (Agave sisalana), coir fiber (Cocos nucifera), sponge-gourd (Luffa cylindrica) and silk-floss as sorbent materials of crude oil. Sorption tests with crude oil were conducted in deionized and marine water media, with and without agitation. Water uptake by the fibers was investigated by tests in dry conditions and distillation of the impregnated sorbent. The silk-floss fiber showed a very high degree of hydrophobicity and oil sorption capacity of approximately 85 g oil/g sorbent (in 24 hours). Specific gravity measurements and buoyancy tests were also used to evaluate the suitability of these fibers for the intended application. (author)

  15. Regenerable sorbents for mercury capture in simulated coal combustion flue gas.

    Science.gov (United States)

    Rodríguez-Pérez, Jorge; López-Antón, M Antonia; Díaz-Somoano, Mercedes; García, Roberto; Martínez-Tarazona, M Rosa

    2013-09-15

    This work demonstrates that regenerable sorbents containing nano-particles of gold dispersed on an activated carbon are efficient and long-life materials for capturing mercury species from coal combustion flue gases. These sorbents can be used in such a way that the high investment entailed in their preparation will be compensated for by the recovery of all valuable materials. The characteristics of the support and dispersion of gold in the carbon surface influence the efficiency and lifetime of the sorbents. The main factor that determines the retention of mercury and the regeneration of the sorbent is the presence of reactive gases that enhance mercury retention capacity. The capture of mercury is a consequence of two mechanisms: (i) the retention of elemental mercury by amalgamation with gold and (ii) the retention of oxidized mercury on the activated carbon support. These sorbents were specifically designed for retaining the mercury remaining in gas phase after the desulfurization units in coal power plants. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Phronesis, a diagnosis and recovery tool for system administrators

    CERN Document Server

    Haen, Christophe; Neufeld, Niko

    The administration of a large computer infrastructure is a great challenge in many aspects and requires experts in various domains to be successful. One criterion to which the users of a data center are directly exposed is the availability of the infrastructure. A high availability comes at the cost of constant and performant monitoring solutions as well as experts ready to diagnose and solve the problems. It is unfortunately not always possible to have an expert team constantly on site. This work presents a tool which is meant to support system administrators in their tasks by diagnosing problems, offering recovery solutions, and acting as a history and knowledge database. We will first detail what large data centers are composed of and what are the various competences that are required in order to successfully administrate them. This will lead us to consider the problems that are traditionally encountered by the administrators. Those problems are at the source of this project, and we will define our goals f...

  17. A Novel Low-Overhead Recovery Approach for Distributed Systems

    Directory of Open Access Journals (Sweden)

    B. Gupta

    2009-01-01

    Full Text Available We have addressed the complex problem of recovery for concurrent failures in distributed computing environment. We have proposed a new approach in which we have effectively dealt with both orphan and lost messages. The proposed checkpointing and recovery approaches enable each process to restart from its recent checkpoint and hence guarantee the least amount of recomputation after recovery. It also means that a process needs to save only its recent local checkpoint. In this regard, we have introduced two new ideas. First, the proposed value of the common checkpointing interval is such that it enables an initiator process to log the minimum number of messages sent by each application process. Second, the determination of the lost messages is always done a priori by an initiator process; besides it is done while the normal distributed application is running. This is quite meaningful because it does not delay the recovery approach in any way.

  18. Implementing forward recovery using checkpointing in distributed systems

    Science.gov (United States)

    Long, Junsheng; Fuchs, W. K.; Abraham, Jacob A.

    1991-01-01

    The paper describes the implementation of a forward recovery scheme using checkpoints and replicated tasks. The implementation is based on the concept of lookahead execution and rollback validation. In the experiment, two tasks are selected for the normal execution and one for rollback validation. It is shown that the recovery strategy has nearly error-free execution time and an average redundancy lower than TMR.

  19. Model predictive control of a waste heat recovery system for automotive diesel engines

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; de Jager, A.G.; Steinbuch, M.

    2014-01-01

    In this paper, a switching Model Predictive Control strategy is designed for an automotive Waste Heat Recovery system with two parallel evaporators. The objective is to maximize Waste Heat Recovery system output power, while satisfying safe operation under highly dynamic disturbances from the

  20. Low-Cost Sorbents: A Literature Summary

    National Research Council Canada - National Science Library

    Bailey, Susan

    1997-01-01

    The capital and regeneration costs of activated carbon and ion exchange media suggest that better process economics may be achieved with disposable sorbents for the treatment of metals-contaminated...

  1. Control optimizations for heat recovery from CO2 refrigeration systems in supermarket

    International Nuclear Information System (INIS)

    Ge, Y.T.; Tassou, S.A.

    2014-01-01

    Highlights: • Application of supermarket energy control system model. • Heat recovery from CO 2 refrigeration system in supermarket space conditioning. • Effect of pressure controls of CO 2 refrigeration system on heat recovery potentials. • Control optimization of CO 2 refrigeration system for heat recovery in supermarket. - Abstract: A modern supermarket energy control system has a concurrent need for electricity, food refrigeration and space heating or cooling. Approximately 10% of this energy is for conventional gas-powered heating. In recent years, the use of CO 2 as a refrigerant in supermarket systems has received considerable attention due to its negligible contribution to direct greenhouse gas emissions and excellent thermophysical and heat transfer properties. CO 2 refrigeration systems also offer more compact component designs over a conventional HFC system and heat recovery potential from compressor discharge. In this paper, the heat recovery potential of an all-CO 2 cascade refrigeration system in a supermarket has been investigated using the supermarket simulation model “SuperSim” developed by the authors. It has been shown that at UK weather conditions, the heat recovery potential of CO 2 refrigeration systems can be increased by increasing the condenser/gas cooler pressure to the point where all the heat requirements are satisfied. However, the optimum level of heat recovery will vary during the year and the control system should be able to continuously optimize this level based on the relative cost of energy, i.e., gas and electricity

  2. Performance investigation of a cogeneration plant with the efficient and compact heat recovery system

    KAUST Repository

    Myat, Aung; Thu, Kyaw; Kim, Young-Deuk; Choon, Ng Kim

    2011-01-01

    This paper presents the performance investigation of a cogeneration plant equipped with an efficient waste heat recovery system. The proposed cogeneration system produces four types of useful energy namely: (i) electricity, (ii) steam, (iii) cooling

  3. Evaluation of Carbon Dioxide Capture From Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Benson, Steven [Univ. of North Dakota, Grand Forks, ND (United States); Srinivasachar, Srivats [Envergex LLC, Sturbridge, MA (United States); Laudal, Daniel [Univ. of North Dakota, Grand Forks, ND (United States); Browers, Bruce [Barr Engineering, Minneapolis, MN (United States)

    2014-12-31

    A novel hybrid solid sorbent technology for CO₂ capture and separation from coal combustion-derived flue gas was evaluated. The technology – Capture of CO₂ by Hybrid Sorption (CACHYS™) – is a solid sorbent technology based on the following ideas: 1) reduction of energy for sorbent regeneration, 2) utilization of novel process chemistry, 3) contactor conditions that minimize sorbent-CO₂ heat of reaction and promote fast CO₂ capture, and 4) low-cost method of heat management. This report provides key information developed during the course of the project that includes sorbent performance, energy for sorbent regeneration, physical properties of the sorbent, the integration of process components, sizing of equipment, and overall capital and operational cost of the integrated CACHYS™ system. Seven sorbent formulations were prepared and evaluated at the lab-scale for energy requirements and CO₂ capture performance. Sorbent heat of regeneration ranged from 30-80 kJ/mol CO₂ and was found to be dependent on process conditions. Two sorbent formulations (designated HCK-4 & HCK-7) were down-selected for additional fixed-bed testing. Additional testing involved subjecting the sorbents to 100 continuous cycles in the fixed-bed reactor to determine performance as a function of time. The working capacity achieved for HCK-4 sorbent ranged from 5.5-8.0 g CO₂/100 g sorbent, while the HCK-7 typically ranged from 8.0-10.0 g CO₂/100 g sorbent. Overall, there was no deterioration in capacity with continuous cycling for either sorbent. The CACHYS™ bench-scale testing system designed and fabricated under this award consists of a dual circulating fluidized-bed adsorber and a moving-bed regenerator. The system takes a flue gas slipstream from the University of North Dakota’s coal-fired steam plant. Prior to being sent to the adsorber, the flue gas is scrubbed to remove SO₂ and particulate. During parametric testing of the adsorber, CO₂ capture achieved using

  4. Preparation of an aminopropyl imidazole-modified silica gel as a sorbent for solid-phase extraction of carboxylic acid compounds and polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Wang, Na; Guo, Yong; Wang, Licheng; Liang, Xiaojing; Liu, Shujuan; Jiang, Shengxiang

    2014-05-21

    In this paper, a kind of aminopropyl imidazole-modified silica sorbent was synthesized and used as a solid-phase extraction (SPE) sorbent for the determination of carboxylic acid compounds and polycyclic aromatic hydrocarbons (PAHs). The resultant aminopropyl imidazole-modified silica sorbent was characterized by Fourier transform infrared spectroscopy (FT-IR) and elemental analysis (EA) to ensure the successful binding of aminopropyl imidazole on the surface of silica gel. Then the aminopropyl imidazole-modified silica sorbent served as a SPE sorbent for the enrichment of carboxylic acid compounds and PAHs. The new sorbent exhibited high extraction efficiency towards the tested compounds and the results show that such a sorbent can offer multiple intermolecular interactions: electrostatic, π-π, and hydrophobic interactions. Several parameters affecting the extraction recovery, such as the pH of sample solution, the pH of eluent, the solubility of eluent, the volume of eluent, and sample loading, were also investigated. Under the optimized conditions, the proposed method was applied to the analysis of four carboxylic acid compounds and four PAHs in environmental water samples. Good linearities were obtained for all the tested compounds with R(2) larger than 0.9903. The limits of detection were found to be in the range of 0.0065-0.5 μg L(-1). The recovery values of spiked river water samples were from 63.2% to 112.3% with relative standard deviations (RSDs) less than 10.1% (n = 4).

  5. SO{sub 2} retention by reactivated CaO-based sorbent from multiple CO{sub 2} capture cycles

    Energy Technology Data Exchange (ETDEWEB)

    Vasilije Manovic; Edward J. Anthony [CANMET Energy Technology Centre-Ottawa, Ottawa, ON (Canada). Natural Resources Canada

    2007-06-15

    This paper examines the reactivation of spent sorbent, produced from multiple CO{sub 2} capture cycles, for use in SO{sub 2} capture. CaO-based sorbent samples were obtained from Kelly Rock limestone using three particle size ranges, each containing different impurities levels. Using a thermogravimetric analyzer (TGA), the sulfation behavior of partially sulfated and unsulfated samples obtained after multiple calcination-carbonation cycles in a tube furnace (TF), following steam reactivation in a pressurized reactor, is examined. In addition, samples calcined/sintered under different conditions after hydration are also examined. The results show that suitably treated spent sorbent has better sulfation characteristics than that of the original sorbent. Thus for example, after 2 h sulfation, {gt} 80% of the CaO was sulfated. In addition, the sorbent showed significant activity even after 4 h when {gt} 95% CaO was sulfated. The results were confirmed by X-ray diffraction (XRD) analysis, which showed that, by the end of the sulfation process, samples contained CaSO{sub 4} with only traces of unreacted CaO. The superior behavior of spent reactivated sorbent appears to be due to swelling of the sorbent particles during steam hydration. The surface area morphology of sorbent after reactivation was examined by scanning electron microscopy (SEM). Ca(OH){sub 2} crystals were seen, which displayed their regular shape, and their elemental composition was confirmed by energy-dispersive X-ray (EDX) analysis. These results allow the proposal of a new process for the use of CaO-based sorbent in fluidized bed combustion (FBC) systems, which incorporates CO{sub 2} capture, sorbent reactivation, and SO{sub 2} retention. 26 refs., 4 figs., 2 tabs.

  6. Sorbents for effective removal of radioactive antimony during chemical decontamination

    International Nuclear Information System (INIS)

    Nishad, Padala Abdul; Bhaskarapillai, Anupkumar; Velmurugan, Sankaralingam

    2014-01-01

    Removal of radioactive antimony is a challenging problem. Often, during decontamination, they get mobilized around the system and redeposit in different areas thus offsetting the reduction in the radiation field obtained by removing other activities such as 60 Co. Thus, there is a clear need for better antimony removing materials/strategies for effective reactor decontamination. In this regard, six commercially available sorbents namely, Tulsion A33 (strong base anion (-OH) resin), Amberlite IRC-718 (chelating resin), Radex ® Sb-1000, nano TiO 2 -special grade (Inorganic type IX), Chitosan (biosorbent) and Aeroxide p25 (nano TiO 2 , Inorganic type IX) were evaluated for their antimony sorption properties. Radex ® and TiO 2 based materials were found to be more effective in removing both Sb(V) and Sb(III). Solution pH was seen to significantly influence the antimony sorption and the effect was more prominent in anion resin, when tested under column conditions. Apart from the commercial sorbents, we have synthesised a robust high performing sorbent (TA-Chitosan beads) in the form of stable beads, using nano-TiO 2 and chitosan. The beads were found to retain the antimony sorption properties of the nano-TiO 2 , while adapting a physical format suitable for large scale operations. The sorbent exhibited almost complete sorption of antimony both in low (ppb level) as well as high concentrations of antimony. The suitability of the beads for use in column mode has been established and its radiation stability was probed in detail. The beads were found to be stable to irradiations as ascertained from the TOC values and unchanged sorption properties. The sorption properties of the CHITA beads in typical decontamination formulation containing mixture of complexing agents have been investigated in detail. (author)

  7. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    International Nuclear Information System (INIS)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; William J. McMichael; Douglas P. Harrison; Ya Liang

    2002-01-01

    The objective of this project is to develop a simple, inexpensive process to separate CO(sub 2) as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbents being investigated in this project are primarily alkali carbonates, and particularly sodium carbonate and potassium carbonate, which are converted to bicarbonates, through reaction with carbon dioxide and water vapor. Bicarbonates are regenerated to carbonates when heated, producing a nearly pure CO(sub 2) stream after condensation of water vapor. This quarter, electrobalance tests conducted at LSU indicated that exposure of sorbent to water vapor prior to contact with carbonation gas does not significantly increase the reaction rate. Calcined fine mesh trona has a greater initial carbonation rate than calcined sodium bicarbonate, but appears to be more susceptible to loss of reactivity under severe calcination conditions. The Davison attrition indices for Grade 5 sodium bicarbonate, commercial grade sodium carbonate and extra fine granular potassium carbonate were, as tested, outside of the range suitable for entrained bed reactor testing. Fluidized bed testing at RTI indicated that in the initial stages of reaction potassium carbonate removed 35% of the carbon dioxide in simulated flue gas, and is reactive at higher temperatures than sodium carbonate. Removals declined to 6% when 54% of the capacity of the sorbent was exhausted. Carbonation data from electrobalance testing was correlated using a shrinking core reaction model. The activation energy of the reaction of sodium carbonate with carbon dioxide and water vapor was determined from nonisothermal thermogravimetry

  8. The effect of short recovery period investment on least-cost generation system expansion

    International Nuclear Information System (INIS)

    Yiqun He; David, A.K.; Fernando, P.N.

    1995-01-01

    The effect of the short recovery period of private investment on least-cost generation system expansion is analysed, and a trade-off method for generation system expansion, which gives consideration to both the least-cost strategy and the short recovery period of private investment, is presented. First, the optimal mix of generation units under a standard recovery period for all units is established, and then the surcharge, due to the difference between the short recovery period and the standard recovery period, is calculated and shared between all units. The former is an optimization to make best use of natural resources, and the latter is a trade-off method to spread the surcharge throughout the system. (Author)

  9. Double-Shell Tanks System Maintenance and Recovery Needs Report

    International Nuclear Information System (INIS)

    SMITH, D.F.

    2002-01-01

    This report represents an initial effort to identify maintenance equipment needed to support critical components used for delivery of waste feed to the Waste Isolation and Treatment Plant (WTP). Rough estimates of cost benefits for selected maintenance capabilities are provided. A follow-on to this report should include a detailed cost analysis showing cost benefits and tradeoffs in selection and development of specific maintenance capabilities. Critical component failures during delivery of waste feed from the DSTs to the WTP have the potential to idle WTP facilities if the duration of the recovery operations are long enough to allow the WTP to exhaust a planned 60-day lag storage capacity for waste feed. If a critical component within the transfer route fails, current planning does not provide for an alternative HLW feed source. Critical components with relatively high failure frequencies and recovery times are identified, along with a summary of documentation regarding historical maintenance and recovery operations and planning. Components, such as mixer pumps and transfer pumps, are estimated to have relatively long recovery times due, in part, to the current practice of sending spare pumps, when needed, off-site to a remote location, for vendor refurbishment and testing prior to installation in a tank. No capability is provided on-site for pump ''run-in''. As neither the spare pumps in storage, installed pumps, or other critical components are subjected to periodic preventive maintenance, and these critical components are planned to be operated intermittently over a long period of time, component failures are to be expected. Recommendations are made for further analysis to identify specific equipment cost benefits, development costs, and tradeoffs in selection of alternatives. This new equipment will provide capabilities for component storage and maintenance in line with vendor recommendations, reduce the duration of recovery operations, and support personnel

  10. DEVELOPMENT OF BIOSURFACTANT-MEDIATED OIL RECOVERY IN MODEL POROUS SYSTEMS AND COMPUTER SIMULATIONS OF BIOSURFACTANT-MEDIATED OIL RECOVERY

    Energy Technology Data Exchange (ETDEWEB)

    M.J. McInerney; S.K. Maudgalya; R. Knapp; M. Folmsbee

    2004-05-31

    Current technology recovers only one-third to one-half of the oil that is originally present in an oil reservoir. Entrapment of petroleum hydrocarbons by capillary forces is a major factor that limits oil recovery (1, 3, 4). Hydrocarbon displacement can occur if interfacial tension (IFT) between the hydrocarbon and aqueous phases is reduced by several orders of magnitude. Microbially-produced biosurfactants may be an economical method to recover residual hydrocarbons since they are effective at low concentrations. Previously, we showed that substantial mobilization of residual hydrocarbon from a model porous system occurs at biosurfactant concentrations made naturally by B. mojavensis strain JF-1 if a polymer and 2,3-butanediol were present (2). In this report, we include data on oil recovery from Berea sandstone experiments along with our previous data from sand pack columns in order to relate biosurfactant concentration to the fraction of oil recovered. We also investigate the effect that the JF-2 biosurfactant has on interfacial tension (IFT). The presence of a co-surfactant, 2,3-butanediol, was shown to improve oil recoveries possibly by changing the optimal salinity concentration of the formulation. The JF-2 biosurfactant lowered IFT by nearly 2 orders of magnitude compared to typical values of 28-29 mN/m. Increasing the salinity increased the IFT with or without 2,3-butanediol present. The lowest interfacial tension observed was 0.1 mN/m. Tertiary oil recovery experiments showed that biosurfactant solutions with concentrations ranging from 10 to 60 mg/l in the presence of 0.1 mM 2,3-butanediol and 1 g/l of partially hydrolyzed polyacrylamide (PHPA) recovered 10-40% of the residual oil present in Berea sandstone cores. When PHPA was used alone, about 10% of the residual oil was recovered. Thus, about 10% of the residual oil recovered in these experiments was due to the increase in viscosity of the displacing fluid. Little or no oil was recovered at

  11. Optimization of SHINE Process: Design and Verification of Plant-Scale AG 1 Anion-Exchange Concentration Column and Titania Sorbent Pretreatment

    Energy Technology Data Exchange (ETDEWEB)

    Stepinski, Dominique C. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Abdul, Momen [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Youker, Amanda J. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Rotsch, David A. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Tkac, Peter [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Chemerisov, Sergey [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division

    2016-06-01

    Argonne National Laboratory has developed a Mo-recovery and -purification system for the SHINE medical technologies process, which uses a uranyl sulfate solution for the accelerator-driven production of Mo-99. The objective of this effort is to reduce the processing time for the acidification of the Mo-99 product prior to loading onto a concentration column and concentration of the Mo-99 product solution. Two methods were investigated: (1) the replacement of the titania concentration column by an anion-exchange column to decrease processing time and increase the radioiodine-decontamination efficiency and (2) pretreatment of the titania sorbent to improve its effectiveness for the Mo-recovery and -concentration columns. Promising results are reported for both methods.

  12. Passive ventilation systems with heat recovery and night cooling

    DEFF Research Database (Denmark)

    Hviid, Christian Anker; Svendsen, Svend

    2008-01-01

    with little energy consumption and with satisfying indoor climate. The concept is based on using passive measures like stack and wind driven ventilation, effective night cooling and low pressure loss heat recovery using two fluid coupled water-to-air heat exchangers developed at the Technical University...... simulation program ESP-r to model the heat and air flows and the results show the feasibility of the proposed ventilation concept in terms of low energy consumption and good indoor climate....

  13. Integrated dry NO{sub x}/SO{sub 2} emissions control system sodium-based dry sorbent injection test report. Test period: August 4, 1993--July 29, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.A.; Shimoto, G.H.; Muzio, L.J. [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Co. of Colorado, Denver, CO (United States)

    1997-04-01

    The project goal is to demonstrate up to 70% reductions in NOx and SO{sub 2} emissions through the integration of: (1) down-fired low-NOx burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NOx removal; and (3) dry sorbent injection and duct humidification for SO{sub 2} removal. This report documents the sixth phase of the test program, where the performance of dry sorbent injection with sodium compounds was evaluated as a SO{sub 2} removal technique. Dry sorbent injection was performed in-duct downstream of the air heater (ahead of the fabric filter), as well as at a higher temperature location between the economizer and air heater. Two sodium compounds were evaluated during this phase of testing: sodium sesquicarbonate and sodium bicarbonate. In-duct sodium injection with low levels of humidification was also investigated. This sixth test phase was primarily focused on a parametric investigation of sorbent type and feed rate, although boiler load and sorbent preparation parameters were also varied.

  14. Feasibility analysis of a small-scale ORC energy recovery system for vehicular application

    International Nuclear Information System (INIS)

    Capata, Roberto; Toro, Claudia

    2014-01-01

    Highlights: • We analyzed the feasibility of an “on-board” ORC recovery system to power auxiliaries. • Performance of the ORC cycle has been simulated with CAMEL-Pro™. • Several relevant ORC components have been designed. • Approximate characteristics dimensions of HRSG and evaporator have been calculated and a preliminary layout provided. • The evaluation of a possible assembling of the system has been developed. - Abstract: This paper analyses the feasibility of an “on-board” innovative and patented ORC recovery system. The vehicle thermal source can be either a typical diesel engine (1400 cc) or a small gas turbine set (15–30 kW). The sensible heat recovered from the exhaust gases feeds the energy recovery system that can produce sufficient extra power to sustain the conditioning system and other auxiliaries. The concept is suitable for all types of thermally propelled vehicles, but it is studied here for automotive applications. The characteristics of the organic cycle-based recovery system are discussed, and a preliminary design of the main components, such as the heat recovery exchanger, the evaporator and the pre-heater is presented. The main challenge are the imposed size and weight limitations that require a particular design for this compact recovery system. A possible system layout is analyzed and the requirements for a prototypal application are investigated

  15. Application of inorganic sorbents for sewage purification from copper

    International Nuclear Information System (INIS)

    Yelizarova, I.A.; Tomchuk, T.K.; Kalinin, N.F.; Vol'khin, V.V.; Levichek, M.S.; Gulyaeva, E.I.

    1986-01-01

    Article presents the results of elaboration of synthesis methods of sorbent on the base of phosphate and magnesium hydroxide. As a result of study the technology of sorbent production with optimal properties was elaborated.

  16. IN SITU STEAM ENHANCED RECOVERY PROCESS - HUGHES ENVIRONMENTAL SYSTEMS, INC. - INNOVATIVE TECHNOLOGY EVALUATION REPORT

    Science.gov (United States)

    This Innovative Technology Evaluation report summarizes the findings of an evaluation of the in situ Steam Enhanced Recovery Process (SERP) operated by Hughes Environmental Systems, Inc. at the Rainbow Disposal facility in Huntington Beach, California. he technology demonstration...

  17. Bypass valve and coolant flow controls for optimum temperatures in waste heat recovery systems

    Science.gov (United States)

    Meisner, Gregory P

    2013-10-08

    Implementing an optimized waste heat recovery system includes calculating a temperature and a rate of change in temperature of a heat exchanger of a waste heat recovery system, and predicting a temperature and a rate of change in temperature of a material flowing through a channel of the waste heat recovery system. Upon determining the rate of change in the temperature of the material is predicted to be higher than the rate of change in the temperature of the heat exchanger, the optimized waste heat recovery system calculates a valve position and timing for the channel that is configurable for achieving a rate of material flow that is determined to produce and maintain a defined threshold temperature of the heat exchanger, and actuates the valve according to the calculated valve position and calculated timing.

  18. Estimation of free-hydrocarbon recovery from dual-pump systems

    International Nuclear Information System (INIS)

    Charbeneau, R.J.

    1995-01-01

    Free-product hydrocarbon which floats on the water table may be recovered using single-pump and dual-pump systems. The factors that affect the long-term free-product recovery using dual-pump systems include the free-product thickness as measured in monitoring wells, the ground-water pumping rate, hydrocarbon density and viscosity, and the soil permeability. This paper presents a simple model for prediction of free-product recovery using dual-pump systems. The model predicts the long-term rather than short-term recovery rates, and lends itself to spreadsheet calculations on microcomputers. A particularly simple form arises for cases where the drawdown is small. An application for estimating recovery from a dual-pump system is presented, and limitations of the model are summarized

  19. Use of common time base for checkpointing and rollback recovery in a distributed system

    Science.gov (United States)

    Ramanathan, Parameswaran; Shin, Kang G.

    1993-01-01

    An approach to checkpointing and rollback recovery in a distributed computing system using a common time base is proposed. A common time base is established in the system using a hardware clock synchronization algorithm. This common time base is coupled with the idea of pseudo-recovery points to develop a checkpointing algorithm that has the following advantages: reduced wait for commitment for establishing recovery lines, fewer messages to be exchanged, and less memory requirement. These advantages are assessed quantitatively by developing a probabilistic model.

  20. Application of a power recovery system to gas turbine exhaust gases

    International Nuclear Information System (INIS)

    Baudat, N.P.; James, O.R.

    1979-01-01

    This paper discusses the application of a power recovery system to recover waste heat from the exhaust gases of gas turbines and convert this energy into shaft horsepower. Also discussed are power cycles, selection of power fluid, equipment selection, and application of the power recovery system to various gas turbines. Several charts and tables are included: process flow diagram, cycle efficiencies, curve for estimating recoverable horsepower

  1. Quaternary ammonium-functionalized silica sorbents for the solid-phase extraction of aromatic amines under normal phase conditions.

    Science.gov (United States)

    Vidal, Lorena; Robin, Orlane; Parshintsev, Jevgeni; Mikkola, Jyri-Pekka; Riekkola, Marja-Liisa

    2013-04-12

    Quaternary ammonium-functionalized silica materials were synthesized and applied for solid-phase extraction (SPE) of aromatic amines, which are classified as priority pollutants by US Environmental Protection Agency. Hexamethylenetetramine used for silica surface modification for the first time was employed as SPE sorbent under normal phase conditions. Hexaminium-functionalized silica demonstrated excellent extraction efficiencies for o-toluidine, 4-ethylaniline and quinoline (recoveries 101-107%), while for N,N-dimethylaniline and N-isopropylaniline recoveries were from low to moderate (14-46%). In addition, the suitability of 1-alkyl-3-(propyl-3-sulfonate) imidazolium-functionalized silica as SPE sorbent was tested under normal phase conditions. The recoveries achieved for the five aromatic amines ranged from 89 to 99%. The stability of the sorbent was evaluated during and after 150 extractions. Coefficients of variation between 4.5 and 10.2% proved a high stability of the synthesized sorbent. Elution was carried out using acetonitrile in the case of hexaminium-functionalized silica and water for 1-alkyl-3-(propyl-3-sulfonate) imidazolium-functionalized silica sorbent. After the extraction the analytes were separated and detected by liquid chromatography ultraviolet detection (LC-UV). The retention mechanism of the materials was primarily based on polar hydrogen bonding and π-π interactions. Comparison made with activated silica proved the quaternary ammonium-functionalized materials to offer different selectivity and better extraction efficiencies for aromatic amines. Finally, 1-alkyl-3-(propyl-3-sulfonate) imidazolium-functionalized silica sorbent was successfully tested for the extraction of wastewater and soil samples. Copyright © 2013 Elsevier B.V. All rights reserved.

  2. Heat pipe heat exchangers in heat recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Stulc, P; Vasiliev, L L; Kiseljev, V G; Matvejev, Ju N

    1985-01-01

    The results of combined research and development activities of the National Research Institute for Machine Design, Prague, C.S.S.R. and the Institute for Heat and Mass Transfer, Minsk, U.S.S.R. concerning intensification heat pipes used in heat pipe heat exchangers are presented. This sort of research has been occasioned by increased interest in heat power economy trying to utilise waste heat produced by various technological processes. The developed heat pipes are deployed in construction of air-air, gas-air or gas-gas heat recovery exchangers in the field of air-engineering and air-conditioning. (author).

  3. Topical Report 5: Sorbent Performance Report

    Energy Technology Data Exchange (ETDEWEB)

    Krutka, Holly; Sjostrom, Sharon

    2011-05-31

    ADA-ES has completed an extensive sorbent screening program funded primarily through DOE NETL cooperative agreement DE-NT0005649 with support from EPRI and industry cost-share participants. Tests were completed on simulated and actual flue gas. The overall project objective is to address the viability and accelerate development of a solid-based postcombustion CO2 capture technology that can be retrofit to the existing fleet of coal-fired power plants. An important component of the viability assessment was to evaluate the state of development of sorbents and measure key performance characteristics under realistic operating conditions.

  4. Recovery Migration after Hurricanes Katrina and Rita: Spatial Concentration and Intensification in the Migration System

    Science.gov (United States)

    Fussell, Elizabeth; DeWaard, Jack

    2015-01-01

    Changes in the human migration systems of Hurricane Katrina- and Rita-affected Gulf of Mexico coastline counties provide an example of how climate change may affect coastal populations. Crude climate change models predict a mass migration of “climate refugees,” but an emerging literature on environmental migration suggests most migration will be short-distance and short-duration within existing migration systems, with implications for the population recovery of disaster-struck places. In this research, we derive a series of hypotheses on recovery migration predicting how the migration system of hurricane-affected coastline counties in the Gulf of Mexico was likely to have changed between the pre-disaster and the recovery periods. We test these hypotheses using data from the Internal Revenue Service on annual county-level migration flows, comparing the recovery period migration system (2007–2009) to the pre-disaster period (1999–2004). By observing county-to-county ties and flows we find that recovery migration was strong, as the migration system of the disaster-affected coastline counties became more spatially concentrated while flows within it intensified and became more urbanized. Our analysis demonstrates how migration systems are likely to be affected by the more intense and frequent storms anticipated by climate change scenarios with implications for the population recovery of disaster-affected places. PMID:26084982

  5. Recovery Migration After Hurricanes Katrina and Rita: Spatial Concentration and Intensification in the Migration System.

    Science.gov (United States)

    Curtis, Katherine J; Fussell, Elizabeth; DeWaard, Jack

    2015-08-01

    Changes in the human migration systems of the Gulf of Mexico coastline counties affected by Hurricanes Katrina and Rita provide an example of how climate change may affect coastal populations. Crude climate change models predict a mass migration of "climate refugees," but an emerging literature on environmental migration suggests that most migration will be short-distance and short-duration within existing migration systems, with implications for the population recovery of disaster-stricken places. In this research, we derive a series of hypotheses on recovery migration predicting how the migration system of hurricane-affected coastline counties in the Gulf of Mexico was likely to have changed between the pre-disaster and the recovery periods. We test these hypotheses using data from the Internal Revenue Service on annual county-level migration flows, comparing the recovery period migration system (2007-2009) with the pre-disaster period (1999-2004). By observing county-to-county ties and flows, we find that recovery migration was strong: the migration system of the disaster-affected coastline counties became more spatially concentrated, while flows within it intensified and became more urbanized. Our analysis demonstrates how migration systems are likely to be affected by the more intense and frequent storms anticipated by climate change scenarios, with implications for the population recovery of disaster-affected places.

  6. Waste heat recovery system for recapturing energy after engine aftertreatment systems

    Science.gov (United States)

    Ernst, Timothy C.; Nelson, Christopher R.

    2014-06-17

    The disclosure provides a waste heat recovery (WHR) system including a Rankine cycle (RC) subsystem for converting heat of exhaust gas from an internal combustion engine, and an internal combustion engine including the same. The WHR system includes an exhaust gas heat exchanger that is fluidly coupled downstream of an exhaust aftertreatment system and is adapted to transfer heat from the exhaust gas to a working fluid of the RC subsystem. An energy conversion device is fluidly coupled to the exhaust gas heat exchanger and is adapted to receive the vaporized working fluid and convert the energy of the transferred heat. The WHR system includes a control module adapted to control at least one parameter of the RC subsystem based on a detected aftertreatment event of a predetermined thermal management strategy of the aftertreatment system.

  7. Influence of lignin on properties of wood-inorganic sorbents

    International Nuclear Information System (INIS)

    Remez, V.P.; Charina, M.V.; Klass, S.M.; Shubin, A.S.; Tkachev, K.V.; Isaeva, O.F.

    1986-01-01

    Present article is devoted to influence of lignin on properties of wood-inorganic sorbents. The influence of component composition of matrix on sorption properties of sorbents and their stability in different mediums is studied. The dependence of sorption capacity of sorbent on component matrix composition and its porous structure is defined.

  8. Calculation of critical fault recovery time for nonlinear systems based on region of attraction analysis

    DEFF Research Database (Denmark)

    Tabatabaeipour, Mojtaba; Blanke, Mogens

    2014-01-01

    of a system. It must be guaranteed that the trajectory of a system subject to fault remains in the region of attraction (ROA) of the post-fault system during this time. This paper proposes a new algorithm to compute the critical fault recovery time for nonlinear systems with polynomial vector elds using sum...

  9. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; William J. McMichael; Douglas P. Harrison; Ya Liang

    2002-01-01

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, or ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. This quarter, five cycle thermogravimetric tests were conducted at the Louisiana State University (LSU) with sodium bicarbonate Grade 3 (SBC{number_sign}3) which showed that carbonation activity declined slightly over 5 cycles following severe calcination conditions of 200 C in pure CO{sub 2}. Three different sets of calcination conditions were tested. Initial carbonation activity (as measured by extent of reaction in the first 25 minutes) was greatest subsequent to calcination at 120 C in He, slightly less subsequent to calcination in 80% CO{sub 2}/20% H{sub 2}O, and lowest subsequent to calcination in pure CO{sub 2} at 200 C. Differences in the extent of reaction after 150 minutes of carbonation, subsequent to calcination under the same conditions followed the same trend but were less significant. The differences between fractional carbonation under the three calcination conditions declined with increasing cycles. A preliminary fixed bed reactor test was also conducted at LSU. Following calcination, the sorbent removed approximately 19% of the CO{sub 2} in the simulated flue gas. CO{sub 2} evolved during subsequent calcination was consistent with an extent of carbonation of approximately 49%. Following successful testing of SBC{number_sign}3 sorbent at RTI reported in the last quarter, a two cycle fluidized bed reactor test was conducted with trona as the sorbent precursor, which was calcined to sodium carbonate. In the first

  10. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    International Nuclear Information System (INIS)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; William J. McMichael; Douglas P. Harrison; Ya Liang

    2002-01-01

    The objective of this project is to develop a simple, inexpensive process to separate CO(sub 2) as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, or ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO(sub 2) stream after condensation of water vapor. This quarter, five cycle thermogravimetric tests were conducted at the Louisiana State University (LSU) with sodium bicarbonate Grade 3 (SBC(number s ign)3) which showed that carbonation activity declined slightly over 5 cycles following severe calcination conditions of 200 C in pure CO(sub 2). Three different sets of calcination conditions were tested. Initial carbonation activity (as measured by extent of reaction in the first 25 minutes) was greatest subsequent to calcination at 120 C in He, slightly less subsequent to calcination in 80% CO(sub 2)/20% H(sub 2)O, and lowest subsequent to calcination in pure CO(sub 2) at 200 C. Differences in the extent of reaction after 150 minutes of carbonation, subsequent to calcination under the same conditions followed the same trend but were less significant. The differences between fractional carbonation under the three calcination conditions declined with increasing cycles. A preliminary fixed bed reactor test was also conducted at LSU. Following calcination, the sorbent removed approximately 19% of the CO(sub 2) in the simulated flue gas. CO(sub 2) evolved during subsequent calcination was consistent with an extent of carbonation of approximately 49%. Following successful testing of SBC(number s ign)3 sorbent at RTI reported in the last quarter, a two cycle fluidized bed reactor test was conducted with trona as the sorbent precursor, which was calcined to sodium carbonate. In the first carbonation cycle, CO

  11. Study on a heat recovery system for the thermal power plant utilizing air cooling island

    International Nuclear Information System (INIS)

    Sun, Jian; Fu, Lin; Sun, Fangtian; Zhang, Shigang

    2014-01-01

    A new heat recovery system for CHP (combined heat and power) systems named HRU (heat recovery unit) is presented, which could recover the low grade heat of exhausted steam from the turbine at the thermal power plant directly. Heat recovery of exhausted steam is often accomplished by recovering the heat of cooling water in current systems. Therefore, two processes of heat transfer is needed at least. However, exhausted steam could be condensed in the evaporator of HRU directly, which reduce one process of heat transfer. A special evaporator is designed condense the exhausted steam directly. Simulated results are compared to experiments, which could include the calculation of heat transfer coefficients of different parts of HRU. It is found that about 25Mw of exhausted steam is recovered by this system. HRU could be promising for conventional CHP systems, which could increase the total energy efficiency obviously and enlarge the heating capacity of a built CHP system. - Highlights: • A new heat recovery system for thermal power plant is presented. • A mathematical model including heat transfer coefficients calculation is given. • This heat recovery system is experimented at a thermal power plant. • Performances of this system under different working conditions are simulated

  12. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    Science.gov (United States)

    Ayala, Raul E.

    1993-01-01

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  13. Recovery of uranium from seawater-status of technology and needed future research and development

    International Nuclear Information System (INIS)

    Kelmers, A.D.

    1980-01-01

    A survey of recent publications concerning uranium recovery from seawater shows that considerable experimental work in this area is currently under way in Japan, less in European countries. Repeated screening programs have identified hydrous titanium oxide as the most promising candidate adsorbent; however, many of its properties, such as distribution coefficient, selectivity, loading, and possibly stability, appear to fall far short of those required for a practical recovery system. In addition, various evaluations of the energy efficiency of pumped or tidal power schemes for contacting the sorbent and seawater are in serious disagreement. Needed future research and development tasks have been identified. A fundamental development program to achieve significantly improved adsorbent properties would be required to permit economical recovery of uranium from seawater. Unresolved engineering aspects of such recovery systems are also identified and discussed. 63 references

  14. Investigation of recovery system for Am and Cm. Results in 1999

    International Nuclear Information System (INIS)

    Watanabe, Masayuki; Kamiya, Masayoshi; Tanaka, Hiroshi

    2000-07-01

    In JAPAN NUCLEAR CYCLE DEVELOPMENT INSTITUTE, the feasibility study has been carried out in order to evaluate various methods of FBR cycle technology and to propose candidate concepts of practical technology. As a part of this, we investigated material balance and a process flow diagram of SETFICS process for the recovery system of Am and Cm from high level radioactive liquid waste, and we preliminarily evaluated the equipment scale, the cost and waste generation rate of this system. As a result, it was obtained that these values are about 17,15 and 10%, respectively, of the recycle plant based on the simplified PUREX process. In addition, we investigated preliminary flowsheets of 4 recovery systems for Am and Cm, and compared each to each of them. It was evaluated that the equipment scale of any process was also equivalent. From these results, each system is applicable as the recovery system of Am and Cm. But these results suggest that the facility may be much larger than the PUREX plant, in spite of small contents of the recovery materials in each system. Therefore, whichever method is applied to the recovery system of Am and Cm, we need to develop the process in order to make the system more compact and economical. (author)

  15. Adsorption of Carbon Dioxide, Ammonia, Formaldehyde, and Water Vapor on Regenerable Carbon Sorbents

    Science.gov (United States)

    Wojtowicz, Marek A.; Cosgrove, Joseph E.; Serio, Michael A.; Wilburn, Monique

    2015-01-01

    Results are presented on the development of reversible sorbents for the combined carbon dioxide, moisture, and trace-contaminant (TC) removal for use in Extravehicular Activities (EVAs), and more specifically in the Primary Life Support System (PLSS). The currently available life support systems use separate units for carbon dioxide, trace contaminants, and moisture control, and the long-term objective is to replace the above three modules with a single one. Furthermore, the current TC-control technology involves the use of a packed bed of acid-impregnated granular charcoal, which is nonregenerable, and the carbon-based sorbent under development in this project can be regenerated by exposure to vacuum at room temperature. In this study, several carbon sorbents were fabricated and tested for simultaneous carbon dioxide, ammonia, formaldehyde, and water sorption. Multiple adsorption/vacuum-regeneration cycles were demonstrated at room temperature, and also the enhancement of formaldehyde sorption by the presence of ammonia in the gas mixture.

  16. Application of Taguchi method for separation of uranium from acetate bearing wastewater using hydroxamic acid based sorbent

    International Nuclear Information System (INIS)

    Satpati, S.K.; Hareendran, K.; Roy, S.B.; Vaidya, A.; Bankar, V.; Dasgupta, K.; Pal, S.

    2016-01-01

    Separation and recovery of uranium from effluent of nuclear facility has drawn immense attention in separation science research. The acetic acid based uranium solution effluent generated in uranium metal powder production facility was targeted for the study. Solid state separation technique has been employed using hydroxamic acid based chelating sorbent because of several advantages. In the study, the sorbent performances have been evaluated for its important parameters like isotherm, efficiency and kinetics. The equilibrium adsorption capacity (q e ) and distribution coefficient (K d ) of U(VI) have been evaluated as 3.24 mg/g sorbent and 805 ml/g sorbent respectively. Uranium has been recovered using HCl solution. Uranium removal from the feed was found to be more than 95% and the recovery of uranium was more than 99% from the adsorbed phase. Elution process is faster than sorption process. Taguchi optimization method has been applied for designing experimental study and also to identify the optimum operational conditions for uranium separation process.The developed process is useful for separation and recovery of uranium from acetate bearing wastewater generated in uranium processing facilities

  17. Non-carbon sorbents for mercury removal from flue gases

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, G.O.; Dubovik, M.; Cesario, M. [TDA Research Inc., Wheat Ridge, CO (United States)

    2005-07-01

    TDA Research Inc. is developing a new sorbent that can effectively remove mercury from flue gases. It is made of non-carbon based materials and will therefore not alter the properties of the fly ash. The sorbent can be produced as an injectable powder. The paper summarises the initial testing results of the new sorbent. The sorbent exhibited 7.5 to 11.0 mg/g mercury absorption capacity under representative flue gas streams depending on the operating temperature and gas hourly space velocity. The sorbent also showed resistance to sulfur poisoning by sulfur dioxide. 6 refs., 3 figs., 1 tab.

  18. Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Hepworth, M.T.; Slimane, R.B.

    1994-11-01

    The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

  19. Application of engineered sorbent barriers Summary of Laboratory Data for FY 1988

    Energy Technology Data Exchange (ETDEWEB)

    Freeman, H.D.; Jones, E.O.

    1989-09-01

    Laboratory studies were conducted in FY 1988 Pacific Northwest Laboratory to determine the effect of contact time, pH, solution to solid ratio, and particle size on the performance of a number of materials in adsorbing radioactive cobalt, strontium, and cesium. The laboratory studies were conducted to provide background information useful in designing an engineered sorbent barrier, which restricts the migration of radionuclides from low-level waste sites. Understanding how the variables affect the adsorption of ions on the sorbent materials is the key to estimating the performance of sorbent barriers under a variety of conditions. The scope of the studies was limited to three radionuclides and four sorbent materials, but the general approach can be used to evaluate other radionuclides and conditions. The sorbent materials evaluated in this study included clinoptilolite, activated carbon, bentonite clay, and Savannah River soil. The clinoptilolite and activated carbon were identified in previous studies as the most cost-effective materials for sorption of the three radionuclides under consideration. The bentonite clay was evaluated as a component of the barrier that could be used to modify the permeability of the barrier system. The Savannah River soil was used to represent soil from a humid site. 3 refs., 14 figs., 1 tab.

  20. Radon adsorption in fibrous carbon sorbents

    International Nuclear Information System (INIS)

    Anshakov, O.M.; Kish, A.O.; Chudakov, V.A.; Matvejchuk, S.V.; Sokolovskij, A.S.; Ugolev, I.I.

    2006-01-01

    Radon sorption in woven fibrous sorbents 'AUT-M' and 'Busofit' and nonwoven fiber in the temperature range 0-50 degrees centigrade was studied. Adsorption heat of radon from the ambient air in different types of carbon fiber was determined. (authors)

  1. Analysis of Ethane and Diethylbenzene Bridged Sorbents

    Science.gov (United States)

    2017-12-13

    Textiles modified in this manner have been shown to reduce or eliminate transport of chemical warfare agents and simulants across the fabric barrier...B.J. Johnson; B.J. Melde; M.H. Moore; A.P. Malanoski; J.R. Taft, "Improving sorbents for glycerol capture in biodiesel refinement," Materials 10

  2. Microwave synthesis of nanostructured oxide sorbents doped with lanthanides

    Energy Technology Data Exchange (ETDEWEB)

    Mitrofanov, Andrey A., E-mail: mitrofanov-a@icloud.com; Silyavka, Elena S.; Shilovskikh, Vladimir V.; Kolonitckii, Petr D.; Sukhodolov, Nikolai G.; Selyutin, Artem A., E-mail: selutin@inbox.ru [Saint Petersburg State University, 7/9, Universitetskaya nab., St. Petersburg, 199034 (Russian Federation)

    2016-06-17

    A number of nanostructured mesoporous oxide systems based on aluminum oxide, doped with lanthanide ions have been obtained in this study. Structure and morphology of oxides obtained have been examined by X-ray diffraction analysis, thermogravimetric analysis, scanning electron microscopy. The surface area of the samples was determined by the BET method. The dependence of the adsorption of insulin on synthesized oxides from the concentration was investigated. The containing of insulin in solutions after adsorption was determined by the Bradford method. The isotherms of adsorption of insulin on resulting oxide sorbents were plotted, the dependence capacity of the sorption of insulin from the lanthanide dopant was determined.

  3. NMR transmit-receive system with short recovery time and effective isolation

    Science.gov (United States)

    Jurga, K.; Reynhardt, E. C.; Jurga, S.

    A transmit-receive system with a short recovery time and excellent isolation has been developed. The system operates in conjunction with an ENI Model 3200L broadband amplifier and a spin-lock NMR pulse spectrometer. The system has been tested in the frequency range 5.5 to 52 MHz and seems not to generate any background noise.

  4. Integrated energy and emission management for heavy-duty diesel engines with waste heat recovery system

    NARCIS (Netherlands)

    Willems, F.P.T.; Kupper, F.; Rascanu, G.; Feru, E.

    2015-01-01

    Rankine-cycleWasteHeatRecovery (WHR)systems are promising solutions to reduce fuel consumption for trucks. Due to coupling between engine andWHR system, control of these complex systems is challenging. This study presents an integrated energy and emission management strategy for an Euro-VI Diesel

  5. Cluster as a Service for Disaster Recovery in Intercloud Systems: Design and Modeling

    OpenAIRE

    Mohammad Ali Khoshkholghi

    2014-01-01

    Nowadays, all modern IT technologies aim to create dynamic and flexible environments. For this reason, InterCloud has been designed to provide a vast and flexible virtualized environment in which many clouds can interact with one another in a dynamic way. Disaster recovery is one of the main applications of InterCloud which can be supported by Cluster as a Service. However, the previous studies addressed disaster recovery and Cluster as a Service separately. In addition, system backup and dis...

  6. The antimicrobial efficiency of silver activated sorbents

    International Nuclear Information System (INIS)

    Đolić, Maja B.; Rajaković-Ognjanović, Vladana N.; Štrbac, Svetlana B.; Rakočević, Zlatko Lj.; Veljović, Đorđe N.; Dimitrijević, Suzana I.; Rajaković, Ljubinka V.

    2015-01-01

    Highlights: • Different sorbents were activated by Ag + -ions and modified sorbents were determined by sorption capacities, in range of values: 42.06–3.28 mg/g. • Granulated activated carbon (GAC), natural zeolit (Z) and titanium dioxide (T) activated by Ag + -ions were tested against E. coli, S. aureus and C. albicans. • The most successful bacteria removal was obtained using Ag/Z against S. aureus and E. coli, while the yeast cell reduction reached unsatisfactory effect for all three activated sorbents. • XRD, XPS and FE-SEM analysis showed that the chemical state of the silver activating agent affects the antimicrobial activity, as well as the structural properties of the material. • An overall microbial cell reduction, which is performed by separated antimicrobial tests on the Ag + -activated surface and Ag + -ions in aquatic solutions, is a consequence of both mechanisms. - Abstract: This study is focused on the surface modifications of the materials that are used for antimicrobial water treatment. Sorbents of different origin were activated by Ag + -ions. The selection of the most appropriate materials and the most effective activation agents was done according to the results of the sorption and desorption kinetic studies. Sorption capacities of selected sorbents: granulated activated carbon (GAC), zeolite (Z), and titanium dioxide (T), activated by Ag + -ions were following: 42.06, 13.51 and 17.53 mg/g, respectively. The antimicrobial activity of Ag/Z, Ag/GAC and Ag/T sorbents were tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and yeast C. albicans. After 15 min of exposure period, the highest cell removal was obtained using Ag/Z against S. aureus and E. coli, 98.8 and 93.5%, respectively. Yeast cell inactivation was unsatisfactory for all three activated sorbents. The antimicrobial pathway of the activated sorbents has been examined by two separate tests – Ag + -ions desorbed from the activated surface to the

  7. CO2 recovery system using solar energy; Taiyo energy wo riyoshita CO2 bunri kaishu system

    Energy Technology Data Exchange (ETDEWEB)

    Hosho, F; Naito, H; Yugami, H; Arashi, H [Tohoku University, Sendai (Japan)

    1997-11-25

    As a part of studies on chemical absorption process with MEA (monoethanolamine) for CO2 recovery from boiler waste gas in thermal power plants, use of solar heat as MEA regenerating energy was studied. An integrated stationary evacuated concentrator (ISEC) effective as collector in a medium temperature range was used to realize a regenerating temperature range of 100-120degC. ISEC is featured by vacuum insulation, use of selective absorbing membranes for an absorber, a CPC (compound parabolic concentrator)-shaped reflection mirror, and high-efficiency. An MEA regenerator is composed of an ISEC and PG(propylene glycol)-MEA heat exchanger, and circulates PG as heat medium. Heat collection experiment was also made using water instead of MEA. Both batch and continuous systems could supply a heat quantity necessary for MEA regeneration. CO2 concentration in the top of the regenerator rapidly decreased with PG circulation regenerating MEA. As mol ratios of CO2/MEA were compared between before and after regeneration, a recovery rate was estimated to be 59.4% for the batch system. 8 figs., 4 tabs.

  8. Evaluation of Dry Sorbent Injection Technology for Pre-Combustion CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Richardson, Carl [URS Group, Inc., Austin, TX (United States); Steen, William [URS Group, Inc., Austin, TX (United States); Triana, Eugenio [URS Group, Inc., Austin, TX (United States); Machalek, Thomas [URS Group, Inc., Austin, TX (United States); Davila, Jenny [URS Group, Inc., Austin, TX (United States); Schmit, Claire [URS Group, Inc., Austin, TX (United States); Wang, Andrew [URS Group, Inc., Austin, TX (United States); Temple, Brian [URS Group, Inc., Austin, TX (United States); Lu, Yongqi [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Lu, Hong [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Zhang, Luzheng [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ruhter, David [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Rostam-Abadi, Massoud [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Sayyah, Maryam [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ito, Brandon [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Suslick, Kenneth [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States)

    2013-09-30

    This document summarizes the work performed on Cooperative Agreement DE-FE0000465, “Evaluation of Dry Sorbent Technology for Pre-Combustion CO{sub 2} Capture,” during the period of performance of January 1, 2010 through September 30, 2013. This project involves the development of a novel technology that combines a dry sorbent-based carbon capture process with the water-gas-shift reaction for separating CO{sub 2} from syngas. The project objectives were to model, develop, synthesize and screen sorbents for CO{sub 2} capture from gasified coal streams. The project was funded by the DOE National Energy Technology Laboratory with URS as the prime contractor. Illinois Clean Coal Institute and The University of Illinois Urbana-Champaign were project co-funders. The objectives of this project were to identify and evaluate sorbent materials and concepts that were suitable for capturing carbon dioxide (CO{sub 2}) from warm/hot water-gas-shift (WGS) systems under conditions that minimize energy penalties and provide continuous gas flow to advanced synthesis gas combustion and processing systems. Objectives included identifying and evaluating sorbents that efficiently capture CO{sub 2} from a gas stream containing CO{sub 2}, carbon monoxide (CO), and hydrogen (H{sub 2}) at temperatures as high as 650 °C and pressures of 400-600 psi. After capturing the CO{sub 2}, the sorbents would ideally be regenerated using steam, or other condensable purge vapors. Results from the adsorption and regeneration testing were used to determine an optimal design scheme for a sorbent enhanced water gas shift (SEWGS) process and evaluate the technical and economic viability of the dry sorbent approach for CO{sub 2} capture. Project work included computational modeling, which was performed to identify key sorbent properties for the SEWGS process. Thermodynamic modeling was used to identify optimal physical properties for sorbents and helped down-select from the universe of possible sorbent

  9. CO{sub 2} capture efficiency and energy requirement analysis of power plant using modified calcium-based sorbent looping cycle

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y.J.; Zhao, C.S.; Chen, H.C.; Ren, Q.Q.; Duan, L.B. [Southeast University, Nanjing (China). School of Energy & Environment

    2011-03-15

    This paper examines the average carbonation conversion, CO{sub 2} capture efficiency and energy requirement for post-combustion CO{sub 2} capture system during the modified calcium-based sorbent looping cycle. The limestone modified with acetic acid solution, i.e. calcium acetate is taken as an example of the modified calcium-based sorbents. The modified limestone exhibits much higher average carbonation conversion than the natural sorbent under the same condition. The CO{sub 2} capture efficiency increases with the sorbent flow ratios. Compared with the natural limestone, much less makeup mass flow of the recycled and the fresh sorbent is needed for the system when using the modified limestone at the same CO{sub 2} capture efficiency. Achieving 0.95 of CO{sub 2} capture efficiency without sulfation, 272 kJ/mol CO{sub 2} is required in the calciner for the natural limestone, whereas only 223 kJ/mol CO{sub 2} for the modified sorbent. The modified limestone possesses greater advantages in CO{sub 2} capture efficiency and energy consumption than the natural sorbent. When the sulfation and carbonation of the sorbents take place simultaneously, more energy is required. It is significantly necessary to remove SO{sub 2} from the flue gas before it enters the carbonator in order to reduce energy consumption in the calciner.

  10. Method for controlling exhaust gas heat recovery systems in vehicles

    Science.gov (United States)

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  11. In situ microbial systems for the enhancement of oil recovery

    International Nuclear Information System (INIS)

    Moses, V.

    1991-01-01

    Microbial Enhancement of Oil Recovery (MEOR) offers important new opportunities in the quest for increased oil production. It refers not to a single technique but rather to a collection of methodologies, analogous to parallel non-microbiological methods. MEOR has relevance for many type of production and reservoir problems detailed protocols: may be tailored specifically to a range of individual reservoir conditions. Microorganisms downhole can generate a wide variety of chemical products from inexpensive feed stocks: where these are more cost-effective than oil field chemicals injected from the surface, microbial methods may win widespread acceptance. MEOR methods must be defined precisely; in any particular reservoir procedure their proposed mechanism of action must be clearly understood and criteria established for evaluating their success. The most important applications for MEOR are 1) the production f insoluble or highly viscous polymer to control coning or to plug selectively high permeability thief zones and fractures, 2) the continuous generation of the active agents for polymer-and/or surfactant floods, 3) matrix acidisation and acid fracturing in carbonate rocks stimulate flows into production wells. All these approaches are currently actively been explored; several programmes for field-testing microbial EOR methods already exist, or are being readied, and rapid progress is likely within the next few years. (author)

  12. Assessment of raw luffa as a natural hollow oleophilic fibrous sorbent for oil spill cleanup

    Directory of Open Access Journals (Sweden)

    Ola Abdelwahab

    2014-03-01

    Full Text Available Oil spills have a global concern due to its environmental and economical impact. Various commercial systems have been developed to control these spills, including the use of fibers as sorbents. However, plant biomass is renewable resource that can be converted into useful materials and energy. Luffa, an agricultural waste, was used as a sorbent material. The present study examines the adsorption capacity of raw luffa fibers for different types of oil and water pickup. The investigation revealed that the efficiency of fibers to remove crude oil from sea water was related to the surface properties of the fibers, concentration of the oil, amount of the fibers, as well as the temperature of the crude oil. The results show high sorption efficiency of luffa fibers for different kinds of oil. This sorbent also exhibited a good reusability since the decrease in sorption efficiency did not exceed 50% of the initial value after three sorption cycles.

  13. Investigating the interactions of decentralized and centralized wastewater heat recovery systems.

    Science.gov (United States)

    Sitzenfrei, Robert; Hillebrand, Sebastian; Rauch, Wolfgang

    2017-03-01

    In the urban water cycle there are different sources for extracting energy. In addition to potential and chemical energy in the wastewater, thermal energy can also be recovered. Heat can be recovered from the wastewater with heat exchangers that are located decentralized and/or centralized at several locations throughout the system. It can be recovered directly at the source (e.g. in the showers and bathrooms), at building block level (e.g. warm water tanks collecting all grey water), in sewers or at the wastewater treatment plant. However, an uncoordinated installation of systems on such different levels can lead to competing technologies. To investigate these interactions, a modelling environment is set up, tested and calibrated based on continuous sewer temperature and flow measurements. With that approach different heat recovery scenarios on a household level (decentralized) and of in-sewer heat recovery (centralized) are investigated. A maximum performance drop of 40% for a centralized energy recovery system was estimated when all bathrooms are equipped with decentralized recovery systems. Therefore, the proposed modelling approach is suitable for testing different future conditions and to identify robust strategies for heat recovery systems from wastewater.

  14. Evaluation of trigeneration system using microturbine, ammonia-water absorption chiller, and a heat recovery boiler

    Energy Technology Data Exchange (ETDEWEB)

    Preter, Felipe C.; Rocha, Marcelo S.; Simoes-Moreira, Jose Roberto [SISEA - Alternative Energy Systems Lab. Dept. of Mechanical Engineering. University of Sao Paulo (EP/USP), SP (Brazil)], e-mails: felipe.preter@poli.usp.br, msrocha@poli.usp.br, jrsimoes@usp.br; Andreos, Ronaldo [COMGAS - Companhia de Gas de Sao Paulo, SP (Brazil)], e-mail: randreos@comgas.com.br

    2010-07-01

    In this work, a CCHP or tri generation system has been projected, mounted, and tested in laboratory, combining a microturbine for power generation, a heat recovery boiler for hot water production, and an ammonia water absorption chiller for chilled water production. The project was motivated by the large practical applications of this kind of energy recovery system in commerce, and industry, and, in general, more than 85% of the energy source is used as power, hot water, and cold water. In the first part, the trigeneration system theoretical model is detailed, and in the second part, experimental results are presented for different operation conditions. (author)

  15. Effects of introducing energy recovery processes to the municipal solid waste management system in Ulaanbaatar, Mongolia.

    Science.gov (United States)

    Toshiki, Kosuke; Giang, Pham Quy; Serrona, Kevin Roy B; Sekikawa, Takahiro; Yu, Jeoung-soo; Choijil, Baasandash; Kunikane, Shoichi

    2015-02-01

    Currently, most developing countries have not set up municipal solid waste management systems with a view of recovering energy from waste or reducing greenhouse gas emissions. In this article, we have studied the possible effects of introducing three energy recovery processes either as a single or combination approach, refuse derived fuel production, incineration and waste power generation, and methane gas recovery from landfill and power generation in Ulaanbaatar, Mongolia, as a case study. We concluded that incineration process is the most suitable as first introduction of energy recovery. To operate it efficiently, 3Rs strategies need to be promoted. And then, RDF production which is made of waste papers and plastics in high level of sorting may be considered as the second step of energy recovery. However, safety control and marketability of RDF will be required at that moment. Copyright © 2014. Published by Elsevier B.V.

  16. Regenerable Sorbent for Combined CO2, Water, and Trace-Contaminant Capture in the Primary Life Support System (PLSS), Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The NASA objective of expanding the human experience into the far reaches of space requires the development of regenerable life support systems. This proposal...

  17. Regenerable Sorbent for Combined CO2, Water, and Trace-Contaminant Capture in the Primary Life Support System (PLSS), Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The NASA objective of expanding the human experience into the far reaches of space requires the development of regenerable life support systems. This proposal...

  18. Optimal operation of integrated processes. Studies on heat recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Glemmestad, Bjoern

    1997-12-31

    Separators, reactors and a heat exchanger network (HEN) for heat recovery are important parts of an integrated plant. This thesis deals with the operation of HENs, in particular, optimal operation. The purpose of heat integration is to save energy, but the HEN also introduces new interactions and feedback into the overall plant. A prerequisite for optimisation is that there are extra degrees of freedom left after regulatory control is implemented. It is shown that extra degrees of freedom may not always be utilized for energy optimisation, and a quantitative expression for the degrees of freedom that can be so utilized are presented. A simplified expression that is often valid is also deduced. The thesis presents some improvements and generalisations of a structure based method that has been proposed earlier. Structural information is used to divide possible manipulations into three categories depending on how each manipulation affects the utility consumption. By means of these categories and two heuristic rules for operability, the possible manipulations are ordered in a priority table. This table is used to determine which manipulation should be preferred and which manipulation should be selected if an active manipulation is saturated. It is shown that the method may correspond to split-range control. A method that uses parametric information in addition to structural information is proposed. In this method, the optimal control structure is found through solving an integer programming problem. The thesis also proposes a method that combines the use of steady state optimisation and optimal selection of measurements. 86 refs., 46 figs., 8 tabs.

  19. Development of a tritium recovery system from CANDU tritium removal facility

    International Nuclear Information System (INIS)

    Draghia, M.; Pasca, G.; Porcariu, F.

    2015-01-01

    The main purpose of the Tritium Recovery System (TRS) is to reduce to a maximum possible extent the release of tritium from the facility following a tritium release in confinement boundaries and also to have provisions to recover both elemental and vapors tritium from the purging gases during maintenance and components replacement from various systems processing tritium. This work/paper proposes a configuration of Tritium Recovery System wherein elemental tritium and water vapors are recovered in a separated, parallel manner. The proposed TRS configuration is a combination of permeators, a platinum microreactor (MR) and a trickle bed reactor (TBR) and consists of two branches: one branch for elemental tritium recovery from tritiated deuterium gas and the second one for tritium recovery from streams containing a significant amount of water vapours but a low amount, below 5%, of tritiated gas. The two branches shall work in a complementary manner in such a way that the bleed stream from the permeators shall be further processed in the MR and TBR in view of achieving the required decontamination level. A preliminary evaluation of the proposed TRS in comparison with state of the art tritium recovery system from tritium processing facilities is also discussed. (authors)

  20. Development of a tritium recovery system from CANDU tritium removal facility

    Energy Technology Data Exchange (ETDEWEB)

    Draghia, M.; Pasca, G.; Porcariu, F. [SC.IS.TECH SRL, Timisoara (Romania)

    2015-03-15

    The main purpose of the Tritium Recovery System (TRS) is to reduce to a maximum possible extent the release of tritium from the facility following a tritium release in confinement boundaries and also to have provisions to recover both elemental and vapors tritium from the purging gases during maintenance and components replacement from various systems processing tritium. This work/paper proposes a configuration of Tritium Recovery System wherein elemental tritium and water vapors are recovered in a separated, parallel manner. The proposed TRS configuration is a combination of permeators, a platinum microreactor (MR) and a trickle bed reactor (TBR) and consists of two branches: one branch for elemental tritium recovery from tritiated deuterium gas and the second one for tritium recovery from streams containing a significant amount of water vapours but a low amount, below 5%, of tritiated gas. The two branches shall work in a complementary manner in such a way that the bleed stream from the permeators shall be further processed in the MR and TBR in view of achieving the required decontamination level. A preliminary evaluation of the proposed TRS in comparison with state of the art tritium recovery system from tritium processing facilities is also discussed. (authors)

  1. Development of the automated circulating tumor cell recovery system with microcavity array.

    Science.gov (United States)

    Negishi, Ryo; Hosokawa, Masahito; Nakamura, Seita; Kanbara, Hisashige; Kanetomo, Masafumi; Kikuhara, Yoshihito; Tanaka, Tsuyoshi; Matsunaga, Tadashi; Yoshino, Tomoko

    2015-05-15

    Circulating tumor cells (CTCs) are well recognized as useful biomarker for cancer diagnosis and potential target of drug discovery for metastatic cancer. Efficient and precise recovery of extremely low concentrations of CTCs from blood has been required to increase the detection sensitivity. Here, an automated system equipped with a microcavity array (MCA) was demonstrated for highly efficient and reproducible CTC recovery. The use of MCA allows selective recovery of cancer cells from whole blood on the basis of differences in size between tumor and blood cells. Intra- and inter-assays revealed that the automated system achieved high efficiency and reproducibility equal to the assay manually performed by well-trained operator. Under optimized assay workflow, the automated system allows efficient and precise cell recovery for non-small cell lung cancer cells spiked in whole blood. The automated CTC recovery system will contribute to high-throughput analysis in the further clinical studies on large cohort of cancer patients. Copyright © 2014 Elsevier B.V. All rights reserved.

  2. Electrochemically modified carbon fiber bundles as selective sorbent for online solid-phase microextraction of sulfonamides

    International Nuclear Information System (INIS)

    Ling, Xu; Zhang, Wenpeng; Chen, Zilin

    2016-01-01

    The authors show that carbon fiber bundles electrochemically modified with the conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) is a viable sorbent for online solid-phase microextraction (SPME) of the sulfonamides (sulfadiazine, sulfadimidine and sulfamethoxazole) prior to their determination by HPLC. The fibers were packed in a tube loop made from polyether ether ketone (PEEK) that was coupled to the HPLC system for online SPME. Preconcentration factors can reach values of up to 300, and the limit of detection (at an S/N ration of 3) can be as low as 0.05 ng⋅mL −1 . The method was applied to the analysis of the sulfonamides in spiked rat plasma with intra-day and inter-day RSDs of <3.33 and <4.57 %, and with recoveries in the range from 91.7 to 97.8 % in spiked plasma. The in-tube SPME was also applied to the determination of the 3 sulfonamides in rat plasma after oral administration (tablet powder) with high sensitivity. In addition to its efficient extraction, the PEEK tube based SPME has chemical and mechanical stability under even harsh conditions. (author)

  3. Control of a waste heat recovery system with decoupled expander for improved diesel engine efficiency

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; Jager, de A.G.; Steinbuch, M.

    2015-01-01

    In this paper, a switching Model Predictive Control strategy is proposed for a Waste Heat Recovery system in heavy-duty automotive application. The objective is to maximize the WHR system output power while satisfying the output constraints under highly dynamic engine variations. For control design,

  4. Hydrogen Gas Recycling for Energy Efficient Ammonia Recovery in Electrochemical Systems

    NARCIS (Netherlands)

    Kuntke, Philipp; Rodríguez Arredondo, Mariana; Widyakristi, Laksminarastri; Heijne, ter Annemiek; Sleutels, Tom H.J.A.; Hamelers, Hubertus V.M.; Buisman, Cees J.N.

    2017-01-01

    Recycling of hydrogen gas (H2) produced at the cathode to the anode in an electrochemical system allows for energy efficient TAN (Total Ammonia Nitrogen) recovery. Using a H2 recycling electrochemical system (HRES) we achieved high TAN transport rates at low energy input. At

  5. Load ratio determines the ammonia recovery and energy input of an electrochemical system

    NARCIS (Netherlands)

    Rodríguez Arredondo, Mariana; Kuntke, Philipp; Heijne, Ter Annemiek; Hamelers, Hubertus V.M.; Buisman, Cees J.N.

    2017-01-01

    Complete removal and recovery of total ammonia nitrogen (TAN) from wastewaters in (bio)electrochemical systems has proven to be a challenge. The system performance depends on several factors, such as current density, TAN loading rate and pH. The interdependence among these factors is not well

  6. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    Energy Technology Data Exchange (ETDEWEB)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at

  7. Confidence Estimation of Reliability Indices of the System with Elements Duplication and Recovery

    Directory of Open Access Journals (Sweden)

    I. V. Pavlov

    2017-01-01

    Full Text Available The article considers a problem to estimate a confidence interval of the main reliability indices such as availability rate, mean time between failures, and operative availability (in the stationary state for the model of the system with duplication and independent recovery of elements.Presents a solution of the problem for a situation that often arises in practice, when there are unknown exact values of the reliability parameters of the elements, and only test data of the system or its individual parts (elements, subsystems for reliability are known. It should be noted that the problems of the confidence estimate of reliability indices of the complex systems based on the testing results of their individual elements are fairly common function in engineering practice when designing and running the various engineering systems. The available papers consider this problem, mainly, for non-recovery systems.Describes a solution of this problem for the important particular case when the system elements are duplicated by the reserved elements, and the elements that have failed in the course of system operation are recovered (regardless of the state of other elements.An approximate solution of this problem is obtained for the case of high reliability or "fast recovery" of elements on the assumption that the average recovery time of elements is small as compared to the average time between failures.

  8. Distributed Diagnosis, Prognosis and Recovery for Complex Systems, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Complex space systems such as lunar habitats generate huge amounts of data. For example, the International Space Station (ISS) has over 250,000 individually...

  9. FLYWHEEL BASED KINETIC ENERGY RECOVERY SYSTEMS (KERS) INTEGRATED IN VEHICLES

    OpenAIRE

    THOMAS MATHEWS; NISHANTH D

    2013-01-01

    Today, many hybrid electric vehicles have been developed in order to reduce the consumption of fossil fuels; unfortunately these vehicles require electrochemical batteries to store energy, with high costs as well as poor conversion efficiencies. By integrating flywheel hybrid systems, these drawbacks can be overcome and can potentially replace battery powered hybrid vehicles cost effectively. The paper will explain the engineering, mechanics of the flywheel system and it’s working in detail. ...

  10. Performance and economic assessments of a solid oxide fuel cell system with a two-step ethanol-steam-reforming process using CaO sorbent

    Science.gov (United States)

    Tippawan, Phanicha; Arpornwichanop, Amornchai

    2016-02-01

    The hydrogen production process is known to be important to a fuel cell system. In this study, a carbon-free hydrogen production process is proposed by using a two-step ethanol-steam-reforming procedure, which consists of ethanol dehydrogenation and steam reforming, as a fuel processor in the solid oxide fuel cell (SOFC) system. An addition of CaO in the reformer for CO2 capture is also considered to enhance the hydrogen production. The performance of the SOFC system is analyzed under thermally self-sufficient conditions in terms of the technical and economic aspects. The simulation results show that the two-step reforming process can be run in the operating window without carbon formation. The addition of CaO in the steam reformer, which runs at a steam-to-ethanol ratio of 5, temperature of 900 K and atmospheric pressure, minimizes the presence of CO2; 93% CO2 is removed from the steam-reforming environment. This factor causes an increase in the SOFC power density of 6.62%. Although the economic analysis shows that the proposed fuel processor provides a higher capital cost, it offers a reducing active area of the SOFC stack and the most favorable process economics in term of net cost saving.

  11. Crosslinked polymeric ionic liquids as solid-phase microextraction sorbent coatings for high performance liquid chromatography.

    Science.gov (United States)

    Yu, Honglian; Merib, Josias; Anderson, Jared L

    2016-03-18

    Neat crosslinked polymeric ionic liquid (PIL) sorbent coatings for solid-phase microextraction (SPME) compatible with high-performance liquid chromatography (HPLC) are reported for the first time. Six structurally different PILs were crosslinked to nitinol supports and applied for the determination of select pharmaceutical drugs, phenolics, and insecticides. Sampling conditions including sample solution pH, extraction time, desorption solvent, desorption time, and desorption solvent volume were optimized using design of experiment (DOE). The developed PIL sorbent coatings were stable when performing extractions under acidic pH and remained intact in various organic desorption solvents (i.e., methanol, acetonitrile, acetone). The PIL-based sorbent coating polymerized from the IL monomer 1-vinyl-3-(10-hydroxydecyl) imidazolium chloride [VC10OHIM][Cl] and IL crosslinker 1,12-di(3-vinylbenzylimidazolium) dodecane dichloride [(VBIM)2C12] 2[Cl] exhibited superior extraction performance compared to the other studied PILs. The extraction efficiency of pharmaceutical drugs and phenolics increased when the film thickness of the PIL-based sorbent coating was increased while many insecticides were largely unaffected. Satisfactory analytical performance was obtained with limits of detection (LODs) ranging from 0.2 to 2 μg L(-1) for the target analytes. The accuracy of the analytical method was examined by studying the relative recovery of analytes in real water samples, including tap water and lake water, with recoveries varying from 50.2% to 115.9% and from 48.8% to 116.6%, respectively. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Simulation and Analysis of Isotope Separation System for Fusion Fuel Recovery System

    Science.gov (United States)

    Senevirathna, Bathiya; Gentile, Charles

    2011-10-01

    This paper presents results of a simulation of the Fuel Recovery System (FRS) for the Laser Inertial Fusion Engine (LIFE) reactor. The LIFE reaction will produce exhaust gases that will need to be recycled in the FRS along with xenon, the chamber's intervention gas. Solids and liquids will first be removed and then vapor traps are used to remove large gas molecules such as lead. The gas will be reacted with lithium at high temperatures to extract the hydrogen isotopes, protium, deuterium, and tritium in hydride form. The hydrogen isotopes will be recovered using a lithium blanket processing system already in place and this product will be sent to the Isotope Separation System (ISS). The ISS will be modeled in software to analyze its effectiveness. Aspen HYSYS was chosen for this purpose for its widespread use industrial gas processing systems. Reactants and corresponding chemical reactions had to be initialized in the software. The ISS primarily consists of four cryogenic distillation columns and these were modeled in HYSYS based on design requirements. Fractional compositions of the distillate and liquid products were analyzed and used to optimize the overall system.

  13. System-based strategies for p53 recovery.

    Science.gov (United States)

    Azam, Muhammad Rizwan; Fazal, Sahar; Ullah, Mukhtar; Bhatti, Aamer I

    2018-06-01

    The authors have proposed a systems theory-based novel drug design approach for the p53 pathway. The pathway is taken as a dynamic system represented by ordinary differential equations-based mathematical model. Using control engineering practices, the system analysis and subsequent controller design is performed for the re-activation of wild-type p53. p53 revival is discussed for both modes of operation, i.e. the sustained and oscillatory. To define the problem in control system paradigm, modification in the existing mathematical model is performed to incorporate the effect of Nutlin. Attractor point analysis is carried out to select the suitable domain of attraction. A two-loop negative feedback control strategy is devised to drag the system trajectories to the attractor point and to regulate cellular concentration of Nutlin, respectively. An integrated framework is constituted to incorporate the pharmacokinetic effects of Nutlin in the cancerous cells. Bifurcation analysis is also performed on the p53 model to see the conditions for p53 oscillation.

  14. New polymer bounces into sorbent market

    International Nuclear Information System (INIS)

    Roy, K.A.

    1991-01-01

    Spectacular spills like the Exxon Valdez capture headlines and dominate conversation, but most releases involve quantities too small to attract media attention. For these spills, companies often rely on sorbents to collect the oil and dispose it. These devices come in a variety of shapes, sizes and absorbent materials, including a new generation of products that offers solid results-literally. This paper reports on the Solidifier which absorbs oil, as well as chlorinated solvents, hydrocarbons and PCBs, and, as the name implies, solidifies into a rubber-like material. A polymer used extensively in the rubber industry is the key to the sorbent's success. Oil and other contaminants, act like catalysts. They dissolve into the polymer, causing its molecules to bond together and form a rubber-like mass. No. 2 diesel fuel oil can be bounced on the floor after it solidifies

  15. Adsorption of gaseous RuO4 by various sorbents. II

    International Nuclear Information System (INIS)

    Vujisic, L.; Nikolic, R.

    1983-01-01

    Sorption of gaseous RuO 4 on impregnated Alcoa Alumina H-151, impregnated charcoal, silica gel and HEPA filter was investigated. The results obtained on various sorbents are compared and discussed in connection with possibilities to use the chosen material in air cleaning systems

  16. EVALUATION OF SOLID SORBENTS AS A RETROFIT TECHNOLOGY FOR CO2 CAPTURE FROM COAL-FIRED POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    Holly Krutka; Sharon Sjostrom

    2011-07-31

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process/equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines; 31 carbon based materials; 6 zeolites; 7 supported carbonates (evaluated under separate funding); and 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different

  17. Collaborate or not? : A system dynamics study on disruption recovery

    NARCIS (Netherlands)

    Zhu, Quan; Krikke, Harold; Caniels, Marjolein C. J.

    2016-01-01

    Purpose – The purpose of this paper is to investigate different combinations of collaboration strategies to deal with different types of supply chain disruptions, find the best combination, and provide targeting suggestions for investments. Design/methodology/approach – A system dynamics simulation

  18. Color Recovery Effect of Different Bleaching Systems on a ...

    African Journals Online (AJOL)

    Composite samples were immersed in coffee and turnip juice for 1 week in each. One laser activated bleaching (LB) (Biolase Laserwhite*20) and three conventional bleaching systems (Ultradent Opalescence Boost 40% (OB), Ultradent Opalescence PF 15% home bleaching (HB), Crest 3D White [Whitening Mouthwash]) ...

  19. Recovery from severe dysphagia in systemic sclerosis - myositis ...

    African Journals Online (AJOL)

    Background: Dysphagia is common in inflammatory myopathies and usually responds to corticosteroids. Severe dysphagia requiring feeding by percutaneous endoscopic gastrostomy is associated with significant morbidity and high mortality. Clinical case: A 56-year old African Black woman initially presented with systemic ...

  20. Validation of Safety-Critical Systems for Aircraft Loss-of-Control Prevention and Recovery

    Science.gov (United States)

    Belcastro, Christine M.

    2012-01-01

    Validation of technologies developed for loss of control (LOC) prevention and recovery poses significant challenges. Aircraft LOC can result from a wide spectrum of hazards, often occurring in combination, which cannot be fully replicated during evaluation. Technologies developed for LOC prevention and recovery must therefore be effective under a wide variety of hazardous and uncertain conditions, and the validation framework must provide some measure of assurance that the new vehicle safety technologies do no harm (i.e., that they themselves do not introduce new safety risks). This paper summarizes a proposed validation framework for safety-critical systems, provides an overview of validation methods and tools developed by NASA to date within the Vehicle Systems Safety Project, and develops a preliminary set of test scenarios for the validation of technologies for LOC prevention and recovery

  1. Thermal comfort analysis of a low temperature waste energy recovery system. SIECHP

    Energy Technology Data Exchange (ETDEWEB)

    Herrero Martin, R. [Departamento de Ingenieria Termica y de Fluidos, Universidad Politecnica de Cartagena, C/Dr. Fleming, s/n (Campus Muralla), 30202 Cartagena, Murcia (Spain); Rey Martinez, F.J.; Velasco Gomez, E. [Departamento de Ingenieria Energetica y Fluidomecanica, ETSII, Universidad de Valladolid, Paseo del Cauce s/n, 47011 Valladolid (Spain)

    2008-07-01

    The use of a recovery device is justified in terms of energy savings and environmental concerns. But it is clear that the use of a recovery system also has to lead to controlling indoor environmental quality, nowadays a priority concern. In this article, experimental research has been carried out whose aim is to study the thermal comfort provided by a combined recovery equipment (SIECHP), consisting of a ceramic semi-indirect evaporative cooler (SIEC) and a heat pipe device (HP) to recover energy at low temperature in air-conditioning systems. To characterize this device empirically in terms of thermal comfort (TC), Fanger's predicted mean vote (PMV), draught rate, and vertical air temperature difference were used in this study as the TC criteria. (author)

  2. Sorbents based on carbonized rice peel

    International Nuclear Information System (INIS)

    Mansurova, R. M.; Taipova, R. A.; Zhylybaeva, N. K.; Mansurov, Z. A.; Bijsenbaev, M. A.

    2004-01-01

    The process receiving of sorbents based on carbonized rice peel (RP) was received and their sorption properties were investigated. Processing carbonization of samples leading on station, this was developed in laboratory of hybrid technology. Carbonization of samples was realized in nitric atmosphere on 400-8000 deg. C. On raising temperature of carbonization content of carbon in samples is rice, hydrogen and oxygen is reduce as a result isolation of volatility products is discover. The samples carbonized on 650 deg. C (910 m 2 /g) owners with maximum removed surface is discover. On carbonization temperature 600-800 deh. C the sorption of ions, which carbonized by sorbents based on rice peel is run to 95-100 %. Electron-microscopic investigation of samples leaded on EM-125 mechanism by accelerating pressure 100 kV. From electron-microscopic print of original samples of RP it is evident, that sample consists of carbonic fractions of different species: carbonic fiber of rounded fractions, fractions of ellipsoid form and of more thickly carbonic structure. Increasing sizes of pores and modification structure of synthesized sorbent is occur during carbonization process. The RP-samples, which carbonized by 650 deg. C has the higher specific surface. Samples consist of thin carbonic scum and reducing specific surface, by higher temperature

  3. Exact Recovery of Chaotic Systems from Highly Corrupted Data

    Science.gov (United States)

    2016-08-01

    dimension to reconstruct a state space which preserves the topological properties of the original system. In [CM87, RS92], the authors use the singular...in high dimensional nonlinear functional spaces [Spr94, SL00, LCC04]. In this work, we bring together connections between compressed sensing, splitting... compact , connected attractor Λ and the flow admits a unique so-called “physical" measure µ with supp(µ) = Λ. An invariant probability measure µ for a flow

  4. Heat pipes and heat pipe exchangers for heat recovery systems

    Energy Technology Data Exchange (ETDEWEB)

    Vasiliev, L L; Grakovich, L P; Kiselev, V G; Kurustalev, D K; Matveev, Yu

    1984-01-01

    Heat pipes and heat pipe exchangers are of great importance in power engineering as a means of recovering waste heat of industrial enterprises, solar energy, geothermal waters and deep soil. Heat pipes are highly effective heat transfer units for transferring thermal energy over large distance (tens of meters) with low temperature drops. Their heat transfer characteristics and reliable working for more than 10-15 yr permit the design of new systems with higher heat engineering parameters.

  5. Triple sorbent thermal desorption/gas chromatography/mass spectrometry determination of vapor phase organic contaminants

    International Nuclear Information System (INIS)

    Ma, C.Y.; Skeen, J.T.; Dindal, A.B.; Higgins, C.E.; Jenkins, R.A.

    1994-05-01

    A thermal desorption/ps chromatography/mass spectrometry (TD/GC/MS) has been evaluated for the determination of volatile organic compounds (VOCS) in vapor phase samples using Carbosieve S-III/Carbotrap/Carotrap C triple sorbent traps (TST) similar to those available from a commercial source. The analysis was carried out with a Hewlett-Packard 5985A or 5995 GC/MS system with a modified injector to adapt an inhouse manufactured short-path desorber for transferring desorbate directly onto a cryofocusing loop for subsequent GC/MS analysis. Vapor phase standards generated from twenty six compounds were used for method validation, including alkanes, alkyl alcohols, alkyl ketones, and alkyl nitrites, a group of representative compounds that have previously been identified in a target airborne matrix. The method was validated based on the satisfactory results in terms of reproducibility, recovery rate, stability, and linearity. A relative, standard deviation of 0.55 to 24.3 % was obtained for the entire TD process (generation of gas phase standards, spiking the standards on and desorbing from TST) over a concentration range of 20 to 500 ng/trap. Linear correlation coefficients for the calibration curves as determined ranged from 0.81 to 0.99 and limits of detection ranged from 3 to 76 ng. For a majority of standards, recoveries of greater than 90% were observed. For three selected standards spiked on TSTS, minimal loss (10 to 22%) was observed after storing the spiked in, a 4 degree C refrigerator for 29 days. The only chromatographable artifact observed was a 5% conversion of isopropanol to acetone. The validated method been successfully applied, to the determination of VOCs collected from various emission sources in a diversified concentration range

  6. Energetic and exergetic analysis of waste heat recovery systems in the cement industry

    International Nuclear Information System (INIS)

    Karellas, S.; Leontaritis, A.-D.; Panousis, G.; Bellos, E.; Kakaras, E.

    2013-01-01

    In a typical cement producing procedure, 25% of the total energy used is electricity and 75% is thermal energy. However, the process is characterized by significant heat losses mainly by the flue gases and the ambient air stream used for cooling down the clinker (about 35%–40% of the process heat loss). Approximately 26% of the heat input to the system is lost due to dust, clinker discharge, radiation and convection losses from the kiln and the preheaters. A heat recovery system could be used to increase the efficiency of the cement plant and thus contribute to emissions decrease. The aim of this paper is to examine and compare energetically and exergetically, two different WHR (waste heat recovery) methods: a water-steam Rankine cycle, and an Organic Rankine Cycle (ORC). A parametric study proved that the water steam technology is more efficient than ORC in exhaust gases temperature higher than 310 °C. Finally a brief economic assessment of the most efficient solution was implemented. WHR installations in cement industry can contribute significantly in the reduction of the electrical consumptions operating cost thus being a very attractive investment with a payback period up to 5 years. - Highlights: • This paper presents waste heat recovery as a way to gain energy from the exhaust gases in a cement plant. • Water steam cycle and ORC has been analyzed for waste heat recovery. • The energetic and exergetic evaluation of the two waste heat recovery processes is presented and compared

  7. A Thermoelectric Waste-Heat-Recovery System for Portland Cement Rotary Kilns

    Science.gov (United States)

    Luo, Qi; Li, Peng; Cai, Lanlan; Zhou, Pingwang; Tang, Di; Zhai, Pengcheng; Zhang, Qingjie

    2015-06-01

    Portland cement is produced by one of the most energy-intensive industrial processes. Energy consumption in the manufacture of Portland cement is approximately 110-120 kWh ton-1. The cement rotary kiln is the crucial equipment used for cement production. Approximately 10-15% of the energy consumed in production of the cement clinker is directly dissipated into the atmosphere through the external surface of the rotary kiln. Innovative technology for energy conservation is urgently needed by the cement industry. In this paper we propose a novel thermoelectric waste-heat-recovery system to reduce heat losses from cement rotary kilns. This system is configured as an array of thermoelectric generation units arranged longitudinally on a secondary shell coaxial with the rotary kiln. A mathematical model was developed for estimation of the performance of waste heat recovery. Discussions mainly focus on electricity generation and energy saving, taking a Φ4.8 × 72 m cement rotary kiln as an example. Results show that the Bi2Te3-PbTe hybrid thermoelectric waste-heat-recovery system can generate approximately 211 kW electrical power while saving 3283 kW energy. Compared with the kiln without the thermoelectric recovery system, the kiln with the system can recover more than 32.85% of the energy that used to be lost as waste heat through the kiln surface.

  8. CO_2 capture with solid sorbent: CFD model of an innovative reactor concept

    International Nuclear Information System (INIS)

    Barelli, L.; Bidini, G.; Gallorini, F.

    2016-01-01

    Highlights: • A new reactor solution based on rotating fixed beds was presented. • The preliminary design of the reactor was approached. • A CFD model of the reactor, including CO_2 capture kinetic, was developed. • The CFD model is validated with experimental results. • Sorbent exploitation increasing is possible thanks to the new reactor. - Abstract: In future decarbonization scenarios, CCS with particular reference to post-combustion technologies will be an important option also for energy intensive industries. Nevertheless, today CCS systems are rarely installed due to high energy and cost penalties of current technology based on chemical scrubbing with amine solvent. Therefore, innovative solutions based on new/optimized solvents, sorbents, membranes and new process designs, are R&D priorities. Regarding the CO_2 capture through solid sorbents, a new reactor solution based on rotating fixed beds is presented in this paper. In order to design the innovative system, a suitable CFD model was developed considering also the kinetic capture process. The model was validated with experimental results obtained by the authors in previous research activities, showing a potential reduction of energy penalties respect to current technologies. In the future, the model will be used to identify the control logic of the innovative reactor in order to verify improvements in terms of sorbent exploitation and reduction of system energy consumption.

  9. Design of a predictive control strategy for an automotive electrically-assisted waste heat recovery system with preview

    NARCIS (Netherlands)

    Seretis, M.

    2017-01-01

    This report regards the development of a predictive control strategy for an automotive electrically-assisted Waste Heat Recovery System (eWHR) with preview information. In this system, the energy recovery is decoupled from the energy supply to the engine. For such dynamical systems with energy

  10. Design, fabrication and testing of the gas analysis system for the tritium recovery experiment, TRIO-01

    International Nuclear Information System (INIS)

    Finn, P.A.; Reedy, G.T.; Homa, M.I.; Clemmer, R.G.; Pappas, G.; Slawecki, M.A.; Graczyk, D.G.; Bowers, D.L.; Clemmer, E.D.

    1983-01-01

    The tritium recovery experiment, TRIO-01, required a gas analysis system which detected the form of tritium, the amount of tritium (differential and integral), and the presence and amount of other radioactive species. The system had to handle all contingencies and function for months at a time unattended during weekend operation. The designed system, described herein, consisted of a train of components which could be grouped as desired to match tritium release behavior

  11. Membrane heat exchanger in HVAC energy recovery systems, systems energy analysis

    Energy Technology Data Exchange (ETDEWEB)

    Nasif, M. [School of Mechanical and Manufacturing Engineering, The University of New South Wales, Sydney, NSW 2052 (Australia); Opus International Consultants (New Zealand); AL-Waked, R. [Mechanical Engineering Department, Prince Mohammad Bin Fahd University (PMU), P.O. Box 1614, AlKhobar 31952 (Saudi Arabia); Morrison, G. [School of Mechanical and Manufacturing Engineering, The University of New South Wales, Sydney, NSW 2052 (Australia); Behnia, M. [School of Aerospace, Mechanical and Mechatronic Engineering, University of Sydney, NSW 2006 (Australia)

    2010-10-15

    The thermal performance of an enthalpy/membrane heat exchanger is experimentally investigated. The heat exchanger utilizes a 60gsm Kraft paper as the heat and moisture transfer surface for HVAC energy recovery. The heat exchanger sensible, latent and total effectiveness have been determined through temperature and moisture content measurements. The annual energy consumption of an air conditioner coupled with an enthalpy/membrane heat exchanger is also studied and compared with a conventional air conditioning cycle using in-house modified HPRate software. The heat exchanger effectiveness are used as thermal performance indicators and incorporated in the modified software. Energy analysis showed that an air conditioning system coupled with a membrane heat exchanger consumes less energy than a conventional air conditioning system in hot and humid climates where the latent load is high. It has been shown that in humid climate a saving of up to 8% in annual energy consumption can be achieved when membrane heat exchanger is used instead of a conventional HVAC system. (author)

  12. Recovery of gastrointestinal swine parasites in anaerobic biodigester systems.

    Science.gov (United States)

    Cañon-Franco, William Alberto; Henao-Agudelo, Ricardo Andrés; Pérez-Bedoya, José Leandro

    2012-01-01

    Solid and liquid wastes from livestock operations represent important challenges for animal production regarding their impact in the environment and public health. Parasitological tests performed on 80 samples of affluent and effluent waters from three anaerobic biodigestors with flexible structure from swine farms of Caldas - Colombia, showed the presence of Isospora suis (45%), Eimeria suis (42.5%), E. espinosa (35%), Strongyloides ransomi (28.8%), E. perminuta (12.5%), E. cerdonis (3.8%), and E. porci (2.5%). The additional finding of eggs of Taenia spp. in 10% of the samples was probably caused by a connection between the human sewage system and the biodigester. Although we observed a mean decrease of 65.6% of parasites, these levels were insufficient to meet the minimum requirement set by Engelberg's guidelines regarding water quality. This study demonstrates the serious environmental impact that an inadequately treated animal wastewater represents, and has important implications for water resources and human health.

  13. Process for radioisotope recovery and system for implementing same

    Science.gov (United States)

    Meikrantz, David H [Idaho Falls, ID; Todd, Terry A [Aberdeen, ID; Tranter, Troy J [Idaho Falls, ID; Horwitz, E Philip [Naperville, IL

    2009-10-06

    A method of recovering daughter isotopes from a radioisotope mixture. The method comprises providing a radioisotope mixture solution comprising at least one parent isotope. The at least one parent isotope is extracted into an organic phase, which comprises an extractant and a solvent. The organic phase is substantially continuously contacted with an aqueous phase to extract at least one daughter isotope into the aqueous phase. The aqueous phase is separated from the organic phase, such as by using an annular centrifugal contactor. The at least one daughter isotope is purified from the aqueous phase, such as by ion exchange chromatography or extraction chromatography. The at least one daughter isotope may include actinium-225, radium-225, bismuth-213, or mixtures thereof. A liquid-liquid extraction system for recovering at least one daughter isotope from a source material is also disclosed.

  14. Shoreline oil cleanup, recovery and treatment evaluation system (SOCRATES)

    International Nuclear Information System (INIS)

    Rusin, J.; Lunel, T.; Sommerville, M.; Tyler, A.; Marshall, I.

    1996-01-01

    A beach cleanup computer system was developed to mitigate the impact of shoreline oiling. The program, entitled SOCRATES, was meant to determine the most suitable cleanup methodologies for a range of different spill scenarios. The development, operation and capabilities of SOCRATES was described, with recent examples of successful use during the Sea Empress spill. The factors which influenced decision making and which were central to the numerical solution were: (1) the volumetric removal rate of oil, (2) area removal rate of oil, (3) length of oil slick removed per hour, (4) volumetric removal rate of oily waste, (5) area of the oil slick, (6) length of the oil slick, (7) volume of liquid emulsion, and (8) length of beach. 14 figs

  15. Heat recovery from wastewater systems; Waermerueckgewinnung aus Abwassersystemen

    Energy Technology Data Exchange (ETDEWEB)

    Wanner, O.

    2004-07-01

    Wastewater contains large amounts of heat energy which can be recovered by means of a heat pump and a heat exchanger installed in the sewer system. Practical problems, which may arise and have been investigated in this research project, are the reduction of the heat transfer efficiency due to heat exchanger fouling and the reduction of the nitrification capacity of downstream wastewater treatment plants due to lower wastewater temperatures. A mathematical model was developed by which the decrease of the wastewater temperature in the treatment plant influent can be determined as a function of the amount of heat energy gathered from the wastewater in the sewer system. By this model the variation in time and space of the wastewater temperature in a sewer pipe is calculated for given hydraulics, geometry and environmental conditions. By analysis of data from a large wastewater treatment plant and simulations with a calibrated model, the effect of lowered influent temperatures on nitrification safety, total nitrogen removal efficiency and ammonium effluent concentrations could be quantified. A procedure is suggested by which the reserve nitrification capacity of an existing treatment plant and the increase of the ammonium effluent concentration resulting from a permanent decrease of the wastewater influent temperature can be estimated. By experiments with a pilot scale heat exchanger in a small wastewater channel, the significance of parameters known to have an effect on fouling was investigated and measures to reduce fouling were tested. The measures tested included controlled variation of the wastewater flow velocity (flushing), coatings and finish of the heat exchanger surface and obstacles mounted on the surface. The best results were obtained by regular short term increases of the flow velocity. By this measure, the efficiency of the fouled heat exchanger, which on the average was 60% of the efficiency of the clean heat exchanger, could repeatedly be raised to an

  16. Development of an on-board H2 storage and recovery system based on lithium borohydride.

    Science.gov (United States)

    2014-02-28

    Alkali metal borohydrides based on sodium and lithium, NaBH4 and LiBH4, have been evaluated as a potential hydrogen storage and recovery system for on-board vehicle use. The borohydride salts could be dissolved in water, followed by a hydrolytic reac...

  17. Experimental validation of a dynamic waste heat recovery system model for control purposes

    NARCIS (Netherlands)

    Feru, E.; Kupper, F.; Rojer, C.; Seykens, X.L.J.; Scappin, F.; Willems, F.P.T.; Smits, Jeroen; Jager, de A.G.; Steinbuch, M.

    2013-01-01

    This paper presents the identification and validation of a dynamic Waste Heat Recovery (WHR) system model. Driven by upcoming CO2 emission targets and increasing fuel costs, engine exhaust gas heat utilization has recently attracted much attention to improve fuel efficiency, especially for

  18. Optimization of paper machine heat recovery system; Paperikoneen laemmoentalteenottosysteemin optimointi - PMSY 02

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, H [Valmet Oyj Pansio, Turku (Finland)

    1999-12-31

    Conventionally the energy content of paper and board machine dryer section exhaust air is recovered in the heat recovery tower. This has had a major contribution to the overall energy economy of a paper machine. Modern paper machines have already reached momentary record speeds above 1700 m/min, and speeds above 2000 m/min will be strived to. This is possible by developing new efficient drying technologies. These will require new solutions for the heat recovery systems. At the same time requirements for new heat recovery solutions come from the gradually closing of paper mill water circulation systems. In this project a discrete tool based on optimization is developed, a tool for analyzing, optimizing and dimensioning of paper machine heat recovery systems for different process conditions. Delivery of a paper machine process requires more and more transferring of process knowledge into calculation model parameters. The overall target of the tool is to decrease the energy consumption considering new drying technologies and the gradually closing of water circulation systems. (orig.)

  19. Optimization of paper machine heat recovery system; Paperikoneen laemmoentalteenottosysteemin optimointi - PMSY 02

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, H. [Valmet Oyj Pansio, Turku (Finland)

    1998-12-31

    Conventionally the energy content of paper and board machine dryer section exhaust air is recovered in the heat recovery tower. This has had a major contribution to the overall energy economy of a paper machine. Modern paper machines have already reached momentary record speeds above 1700 m/min, and speeds above 2000 m/min will be strived to. This is possible by developing new efficient drying technologies. These will require new solutions for the heat recovery systems. At the same time requirements for new heat recovery solutions come from the gradually closing of paper mill water circulation systems. In this project a discrete tool based on optimization is developed, a tool for analyzing, optimizing and dimensioning of paper machine heat recovery systems for different process conditions. Delivery of a paper machine process requires more and more transferring of process knowledge into calculation model parameters. The overall target of the tool is to decrease the energy consumption considering new drying technologies and the gradually closing of water circulation systems. (orig.)

  20. Performance of Counter Flow Heat Recovery Ventilation Systems in Dwellings Considering the Influence of Uncertainties

    NARCIS (Netherlands)

    Yang, Z.; Cauberg, J.J.M.; Tenpierik, M.J.

    2012-01-01

    Both critical and optimistic claims have been made regarding the performance of heat recovery ventilation systems (HRVS) in dwellings. Such arguments are raised partly because two key aspects are not fully clarified, i.e. the performance criteria and the influence of uncertainties. In the current

  1. Integrated Energy & Emission Management for Heavy-Duty Diesel Engines with Waste Heat Recovery System

    NARCIS (Netherlands)

    Willems, F.P.T.; Kupper, F.; Cloudt, R.P.M.

    2012-01-01

    This study presents an integrated energy and emission management strategy for an Euro-VI diesel engine with Waste Heat Recovery (WHR) system. This Integrated Powertrain Control (IPC) strategy optimizes the CO2-NOx trade-off by minimizing the operational costs associated with fuel and AdBlue

  2. Supervisory control of a heavy-duty diesel engine with an electrified waste heat recovery system

    NARCIS (Netherlands)

    Feru, E.; Murgovski, N.; de Jager, A.G.; Willems, F.P.T.

    This paper presents an integrated energy and emission management strategy, called Integrated Powertrain Control (IPC), for an Euro-VI diesel engine with an electrified waste heat recovery system. This strategy optimizes the CO2–NOxCO2–NOx trade-off by minimizing the operational costs associated with

  3. Heat exchanger modeling and identification for control of waste heat recovery systems in diesel engines

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; Rojer, C.; Jager, B. de; Steinbuch, M.

    2013-01-01

    To meet future CO2 emission targets, Waste Heat Recovery systems have recently attracted much attention for automotive applications, especially for long haul trucks. This paper focuses on the development of a dynamic counter-flow heat exchanger model for control purposes. The model captures the

  4. Integrated energy and emission management for heavy-duty diesel engines with waste heat recovery system

    NARCIS (Netherlands)

    Willems, F.P.T.; Kupper, F.; Cloudt, R.P.M.

    2012-01-01

    This study presents an integrated energy and emission management strategy for an Euro-VI diesel engine with Waste Heat Recovery (WHR) system. This Integrated Powertrain Control (IPC) strategy optimizes the CO2-NOx trade-off by minimizing the operational costs associated with fuel and AdBlue

  5. Gas-permeable hydrophobic tubular membranes for ammonia recovery in bio-electrochemical systems

    NARCIS (Netherlands)

    Kuntke, P.; Zamora, P.; Saakes, M.; Buisman, C.J.N.; Hamelers, H.V.M.

    2016-01-01

    The application of a gas-permeable hydrophobic tubular membrane in bio-electrochemical systems enables efficient recovery of ammonia (NH3) from their cathode compartments. Due to a hydrogen evolution reaction at the cathode, no chemical addition was required to increase the pH for

  6. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  7. Properties and reactivity of reactivated calcium-based sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Davini, P. [Pisa University, Pisa (Italy). Dept. of Chemical Engineering

    2002-04-01

    Calcium-based sorbents used in the process of high temperature desulfurisation of flue gases are partly regenerable by hydration with steam; the best results are obtained for treatment temperatures of approximately 300{degree}C. The regeneration process, and the consequent increase in the sorbent consumption can be correlated to the surface characteristics (BET surface area, porosity and pore size distribution) of the sorbents themselves. In particular, the presence of suitable pore structure, also having pores large enough to let molecules easily penetrate the inner part of the sorbent particles, is very important. 27 refs., 9 figs., 2 tabs.

  8. Simple test guidelines for screening oilspill sorbents for toxicity

    International Nuclear Information System (INIS)

    Blenkinsopp, S.A.; Sergy, G.; Doe, K.; Jackman, P.; Huybers, A.

    1998-01-01

    Environment Canada's Emergencies Science Division has established a program to develop a standard test method suitable for evaluating the toxicity of common sorbent materials. Sorbents are used to absorb or adsorb spilled oil and other hazardous materials. They vary widely in composition and packaging. They are often treated with oleophilic and hydrophobic compounds to improve performance and have been used in large quantities during oil spills. Until now, their potential toxicity has never been considered. Three tests have been evaluated to determine how appropriate they are in screening the toxicity of sorbents. Seven toxicity test recommendations for sorbents were presented. 7 refs., 3 tabs., 2 figs

  9. Development of a condenser for the dual catalyst water recovery system

    Science.gov (United States)

    Budinikas, P.; Rasouli, F.; Rabadi, N.

    1983-01-01

    Conceptual evaporation/condensation systems suitable for integration with the catalytic water recovery method were evaluated. The primary requirements for each concept were its capability to operate under zero-gravity conditions, condense recovered water from a vapor-noncondensable gas mixture, and integrate with the catalytic system. Specific energy requirements were estimated for concepts meeting the primary requirements, and the concept most suitable for integration with the catalytic system was proposed. A three-man rate condenser capable of integration with the proposed system, condensing water vapor in presence of noncondensables and transferring the heat of condensation to feed urine was designed, fabricated, and tested. It was treated with steam/air mixtures at atmospheric and elevated pressures and integrated with an actual catalytic water recovery system. The condenser has a condensation efficiency exceeding 90% and heat transfer rate of approximately 85% of theoretical value at coolant temperature ranging from 7 to 80 deg C.

  10. The effect of ash elements in petroleum coke on hearth furnace heat recovery system performance

    Energy Technology Data Exchange (ETDEWEB)

    Akhmetov, M M

    1981-01-01

    Difficulties encountered in the operation of the heat recovery system of a calcination plant at Krasnovodsk Refinery caused by ash element deposits blocking the fire box are described. Deposits and coke ash composition are given. The main cause of blocking was found to be the removal of sea water salt elements which get on the coke surface when the retarded coking plant is discharged with a water-jet borer. Switching over to fresh water and air-blasting of heat recovery pipes decreased blocking considerably.

  11. DEVELOPMENT AND DEMONSTRATION OF INTEGRATED CARBON RECOVERY SYSTEMS FROM FINE COAL PROCESSING WASTE

    Energy Technology Data Exchange (ETDEWEB)

    Y.P. Chugh; D. Patil; A. Patwardhan; R.Q. Honaker; B.K. Parekh; D. Tao; Latif Khan

    2000-07-01

    The project involves the development of an efficient, environmentally friendly system for the economical recovery of carbon from fine-coal refuse ponds. The project will be conducted in two phases. Phase I was involved in the development and evaluation of process equipment and techniques to be used in carbon recovery, product dewatering and reconstitution, and refuse management. Phase II will integrate the various units into a continuously operating circuit that will be demonstrated at a site selected based on the results presented in this study.

  12. Entropy Maximization as a Basis for Information Recovery in Dynamic Economic Behavioral Systems

    Directory of Open Access Journals (Sweden)

    George Judge

    2015-02-01

    Full Text Available As a basis for information recovery in open dynamic microeconomic systems, we emphasize the connection between adaptive intelligent behavior, causal entropy maximization and self-organized equilibrium seeking behavior. This entropy-based causal adaptive behavior framework permits the use of information-theoretic methods as a solution basis for the resulting pure and stochastic inverse economic-econometric problems. We cast the information recovery problem in the form of a binary network and suggest information-theoretic methods to recover estimates of the unknown binary behavioral parameters without explicitly sampling the configuration-arrangement of the sample space.

  13. The Design of Data Disaster Recovery of National Fundamental Geographic Information System

    Science.gov (United States)

    Zhai, Y.; Chen, J.; Liu, L.; Liu, J.

    2014-04-01

    With the development of information technology, data security of information system is facing more and more challenges. The geographic information of surveying and mapping is fundamental and strategic resource, which is applied in all areas of national economic, defence and social development. It is especially vital to national and social interests when such classified geographic information is directly concerning Chinese sovereignty. Several urgent problems that needs to be resolved for surveying and mapping are how to do well in mass data storage and backup, establishing and improving the disaster backup system especially after sudden natural calamity accident, and ensuring all sectors rapidly restored on information system will operate correctly. For overcoming various disaster risks, protect the security of data and reduce the impact of the disaster, it's no doubt the effective way is to analysis and research on the features of storage and management and security requirements, as well as to ensure that the design of data disaster recovery system suitable for the surveying and mapping. This article analyses the features of fundamental geographic information data and the requirements of storage management, three site disaster recovery system of DBMS plan based on the popular network, storage and backup, data replication and remote switch of application technologies. In LAN that synchronous replication between database management servers and the local storage of backup management systems, simultaneously, remote asynchronous data replication between local storage backup management systems and remote database management servers. The core of the system is resolving local disaster in the remote site, ensuring data security and business continuity of local site. This article focuses on the following points: background, the necessity of disaster recovery system, the analysis of the data achievements and data disaster recovery plan. Features of this program is to use a

  14. Optimization of Thermoelectric Components for Automobile Waste Heat Recovery Systems

    Science.gov (United States)

    Kumar, Sumeet; Heister, Stephen D.; Xu, Xianfan; Salvador, James R.

    2015-10-01

    For a typical spark ignition engine approximately 40% of available thermal energy is lost as hot exhaust gas. To improve fuel economy, researchers are currently evaluating technology which exploits exhaust stream thermal power by use of thermoelectric generators (TEGs) that operate on the basis of the Seebeck effect. A 5% improvement in fuel economy, achieved by use of TEG output power, is a stated objective for light-duty trucks and personal automobiles. System modeling of thermoelectric (TE) components requires solution of coupled thermal and electric fluxes through the n and p-type semiconductor legs, given appropriate thermal boundary conditions at the junctions. Such applications have large thermal gradients along the semiconductor legs, and material properties are highly dependent on spatially varying temperature profiles. In this work, one-dimensional heat flux and temperature variations across thermoelectric legs were solved by using an iterative numerical approach to optimize both TE module and TEG designs. Design traits were investigated by assuming use of skutterudite as a thermoelectric material with potential for automotive applications in which exhaust gas and heat exchanger temperatures typically vary from 100°C to over 600°C. Dependence of leg efficiency, thermal fluxes and electric power generation on leg geometry, fill fractions, electric current, thermal boundary conditions, etc., were studied in detail. Optimum leg geometries were computed for a variety of automotive exhaust conditions.

  15. Integrated steam generation process and system for enhanced oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Betzer-Zilevitch, M. [Ex-Tar Technologies Inc., Calgary, AB (Canada)

    2010-07-01

    A method of producing steam for the extraction of heavy bitumens was presented. The direct contact steam generation (DCSG) method is used for the direct heat transfer between combustion gas and contaminated liquid phase water to generate steam. This paper presented details of experimental and field studies conducted to demonstrate the DCSG. Results of the study demonstrated that pressure and temperature are positively correlated. As pressure increases, the flow rate of the discharged mass decreases and the steam ratio decreases. As pressure increases, the condensate and distillate flow rates increases while water vapor losses in the non-condensable gases decrease. The study indicated that for a 10 bar pressurized system producing 9.6 mt per hour of 10,000 kpa steam and 9.6 mt per hour of distillate BFW, 70 percent of the combustion energy should be recovered to generate 10,000 kpa pressure steam for EOR. Combustion energy requirements were found to decrease when pressure decreases. 11 refs., 5 tabs., 8 figs.

  16. Waste Heat Recovery of a PEMFC System by Using Organic Rankine Cycle

    Directory of Open Access Journals (Sweden)

    Tianqi He

    2016-04-01

    Full Text Available In this study, two systems are brought forward to recover the waste heat of a proton exchange membrane fuel cell (PEMFC, which are named the organic Rankine cycle (ORC, and heat pump (HP combined organic Rankine cycle (HPORC. The performances of both systems are simulated on the platform of MATLAB with R123, R245fa, R134a, water, and ethanol being selected as the working fluid, respectively. The results show that, for PEMFC where operating temperature is constantly kept at 60 °C, there exists an optimum working temperature for each fluid in ORC and HPORC. In ORC, the maximal net power can be achieved with R245fa being selected as the working fluid. The corresponding thermal efficiency of the recovery system is 4.03%. In HPORC, the maximal net power can be achieved with water being selected in HP and R123 in ORC. The thermal efficiency of the recovery system increases to 4.73%. Moreover, the possibility of using ORC as the cooling system of PEMFC is also studied. The heat released from PEMFC stack is assumed to be wholly recovered by the ORC or HPORC system. The results indicate that the HPORC system is much more feasible for the cooling system of a PEMFC stack, since the heat recovery ability can be promoted due to the presence of HP.

  17. Research on Overconfidence in Decision-Making for the Capacity Recovery of Damaged Power Systems

    Directory of Open Access Journals (Sweden)

    Xing Bao

    2014-01-01

    Full Text Available This paper studies the influence of two types of overconfident behavior, overestimation and overprecision, on decision of capacity recovery when power system’s critical capacity is seriously damaged. A newsvendor model is used to prove that increasing regulatory punishment for electricity shortage and providing subsidy for capacity recovery are conducive measures to calibrate insufficient service level caused by an overconfident manager. The research also finds that the manager’s overprecision behavior both negatively and positively influences the decision of capacity recovery, and a calibration method could motivate manager to recover more capacity by tuning up the ratio of punishment and subsidy. However, the effectiveness of the calibration mentioned above is inevitably weakened due to the less capacity recovery given by an overestimated manager. This research also indicates that the manager should pay close attention to the random disturbance whose distribution peak is left skewed, and correspondingly more capacity recovery should be given to improve the service level of power system during the disruption.

  18. New system for higher recovery rate of water borne Cryptosporidium oocysts and Giardia cysts

    DEFF Research Database (Denmark)

    Al-Sabi, Mohammad Nafi Solaiman; Gad, Jens; Klinting, Mette

    2012-01-01

    Background: The two most common water borne pathogenic protozoa, Cryptosporidium and Giardia, cause diarrhea worldwide. Detecting these parasites in water samples depends on effective parasite recovery from the water matrix. The reported low recovery rates of the currently used filter methods...... motivate the development of systems with higher recovery rates. Materials and methods: Five replicates of IMS purified Cryptosporidium oocysts and Giardia cysts (N=2x103) were injected into a specially coated filter unit with a carefully chosen pore size. Following filtration, sonication was performed...... were 85% were recorded when the filter was sonicated. Sonication usually affects parasite viability but could be tuned into a useful tool for enhanced backwash collection of parasites using a specially constructed filter unit and a sonication protocol. The filtration...

  19. New filtration system for efficient recovery of waterborne Cryptosporidium oocysts and Giardia cysts

    DEFF Research Database (Denmark)

    Al-Sabi, Mohammad Nafi Solaiman; Gad, J. A.; Riber, Ulla

    2015-01-01

    -)cysts (1x10(2); 10 replicates) was successfully amplified using real-time PCR.ConclusionsThe use of a metallic filter, sonication and air backwash' were key factors for creating a highly efficient system for recovery of apparently undamaged protozoa.Significance and Impact of the StudyThis reagent......AimsTo develop a filtration unit for efficient recovery of waterborne Cryptosporidium oocysts and Giardia cysts ((oo-)cysts) in drinking water.Methods and ResultsThis unit utilizes a metallic filter and an ultrasound transducer for eluting (oo-)cysts, with a fixed retentate backwash volume; approx....... 400l. Changes in the viability was evaluated by seeding wild type (oo-)cysts (1x10(4)) followed by sonication for 5, 10, 20 or 40s (five replicates for each period). Flow cytometry analysis showed negligible increase in the mortality of (oo-)cysts exposed to 5-10s of sonication. Recovery rate...

  20. Design and evaluation of fluidized bed heat recovery for diesel engine systems

    Science.gov (United States)

    Hamm, J. R.; Newby, R. A.; Vidt, E. J.; Lippert, T. E.

    1985-01-01

    The potential of utilizing fluidized bed heat exchangers in place of conventional counter-flow heat exchangers for heat recovery from adiabatic diesel engine exhaust gas streams was studied. Fluidized bed heat recovery systems were evaluated in three different heavy duty transport applications: (1) heavy duty diesel truck; (2) diesel locomotives; and (3) diesel marine pushboat. The three applications are characterized by differences in overall power output and annual utilization. For each application, the exhaust gas source is a turbocharged-adiabatic diesel core. Representative subposed exhaust gas heat utilization power cycles were selected for conceptual design efforts including design layouts and performance estimates for the fluidized bed heat recovery heat exchangers. The selected power cycles were: organic rankine with RC-1 working fluid, turbocompound power turbine with steam injection, and stirling engine. Fuel economy improvement predictions are used in conjunction with capital cost estimates and fuel price data to determine payback times for the various cases.

  1. Effects of O{sub 2} and SO{sub 2} on the Capture Capacity of a Primary-Amine Based Polymeric CO{sub 2} Sorbent

    Energy Technology Data Exchange (ETDEWEB)

    Hallenbeck, Alexander P; Kitchin, John R

    2013-08-01

    Post combustion CO{sub 2} capture is most commonly carried out using an amine solution that results in a high parasitic energy cost in the stripper unit due to the need to heat the water which comprises a majority of the amine solution. It is also well known that amine solvents suffer from stability issues due to amine leaching and poisoning by flue gas impurities. Solid sorbents provide an alternative to solvent systems that would potentially reduce the energy penalty of carbon capture. However, the cost of using a particular sorbent is greatly affected by the usable lifetime of the sorbent. This work investigated the stability of a primary amine-functionalized ion exchange resin in the presence of O{sub 2} and SO{sub 2}, both of which are constituents of flue gas that have been shown to cause degradation of various amines in solvent processes. The CO{sub 2} capture capacity was measured over multiple capture cycles under continuous exposure to two simulated flue gas streams, one containing 12 vol% CO{sub 2}, 4% O{sub 2}, 84% N{sub 2}, and the other containing 12.5 vol% CO{sub 2}, 4% O{sub 2}, 431 ppm SO{sub 2}, balance N{sub 2} using a custom-built packed bed reactor. The resin maintained its CO{sub 2} capture capacity of 1.31 mol/kg over 17 capture cycles in the presence of O{sub 2} without SO{sub 2}. However, the CO{sub 2} capture capacity of the resin decreased rapidly under exposure to SO{sub 2} by an amount of 1.3 mol/kg over 9 capture cycles. Elemental analysis revealed the resin adsorbed 1.0 mol/kg of SO{sub 2}. Thermal regeneration was determined to not be possible. The poisoned resin was, however, partially regenerated with exposure to 1.5M NaOH for 3 days resulting in a 43% removal of sulfur, determined through elemental analysis, and a 35% recovery of CO{sub 2} capture capacity. Evidence was also found for amine loss upon prolonged (7 days) continuous exposure to high temperatures (120 C) in air. It is concluded that desulfurization of the flue gas

  2. Energy recovery from air flow in underground railway systems

    Energy Technology Data Exchange (ETDEWEB)

    Morrone, B.; Mariani, A. [Seconda Univ. degli studi di Napoli, Aversa (Italy). Dept. of Aerospace and Mechanical Engineering; Costanzo, M.L. [Tecnosistem spa, Napoli (Italy)

    2010-07-01

    The 20-20-20 energy policy of the European Union commits members to reduce carbon dioxide (CO{sub 2}) emissions by 20 per cent by 2020, and stipulates that 20 per cent of final-use energy is to be supplied by renewable energy sources. This paper proposed the concept of recovering energy from underground trains by using the air flow inside tunnels to drive energy conversion systems such as turbines to generate electricity. Underground trains use much of their power to overcome the aerodynamic resistance moving the air in front of the train, creating a piston effect when travelling inside tunnels at relatively low speed. Numerical simulations were used in this study to determine how much electricity could be produced. A one-dimensional numerical analysis of a specific subway train track was used to evaluate the air flow magnitude inside the tunnel. Once the air flow features were detected, the potential electricity production was evaluated by considering the characteristics of a Wells turbine. Two types of 3-dimensional models of the tunnel and train were presented. One considered a long straight tunnel with a train running in it, and a small portion of a bypass tunnel. The other considered a large part of an opposite tunnel connected to the main one through the by-pass tunnel. Both the 3D models revealed a maximum flow rate of 2.5 x 105 m{sup 3}/h, while the 1D model showed an air flow of 1.5 x 105 m{sup 3}/h. The difference was due primarily to the presence of fans in the 1D Model and different modelling assumptions. It was concluded that one single Wells type turbine placed in a by-pass tunnel can produce 32.6 kWh per day, or about 10 MWh per year, resulting in a CO{sub 2} savings of about 5.5 tons per year. 8 refs., 1 tab., 11 figs.

  3. A new pumping strategy for petroleum product recovery from contaminated hydrogeologic systems: Laboratory and field evaluations

    International Nuclear Information System (INIS)

    Abdul, A.S.

    1992-01-01

    More than 200,000 gallons of automatic transmission fluid (ATF) leaked from an underground storage tank system and contaminated an area of about 64,000 ft 2 of a soil and ground water system. A pumping strategy for improved drainage and recovery of free oil was developed, tested in a laboratory model aquifer, and implemented (1) the oil recovery rate is carefully controlled to maximize the pumping rate while maintaining continuity between the oil layer in the soil and the recovery well, to avoid isolation of the oil in the subsurface; and (2) the rate of ground water pumping is controlled to maintain the depressed oil/water interface at its prepumped position. This approach prevents further spread of oil into the ground water, prevents reduction in the volume of recoverable oil due to residual retention, and maintains a gradient for oil flow toward the recovery well. In a model aquifer study, nearly 100% of the recoverable volume of ATF was pumped from the system, and about 56,000 gallons of the ATF has been recovered from the field site

  4. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    Energy Technology Data Exchange (ETDEWEB)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-10-01

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed

  5. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    International Nuclear Information System (INIS)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-01-01

    The objective of this project is to develop a simple, inexpensive process to separate CO(sub 2) as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO(sub 2) stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO(sub 2) capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO(sub 2) and H(sub 2)O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport

  6. Exergetic Analysis, Optimization and Comparison of LNG Cold Exergy Recovery Systems for Transportation

    Directory of Open Access Journals (Sweden)

    Paweł Dorosz

    2018-01-01

    Full Text Available LNG (Liquefied Natural Gas shares in the global energy market is steadily increasing. One possible application of LNG is as a fuel for transportation. Stricter air pollution regulations and emission controls have made the natural gas a promising alternative to liquid petroleum fuels, especially in the case of heavy transport. However, in most LNG-fueled vehicles, the physical exergy of LNG is destroyed in the regasification process. This paper investigates possible LNG exergy recovery systems for transportation. The analyses focus on “cold energy” recovery systems as the enthalpy of LNG, which may be used as cooling power in air conditioning or refrigeration. Moreover, four exergy recovery systems that use LNG as a low temperature heat sink to produce electric power are analyzed. This includes single-stage and two-stage direct expansion systems, an ORC (Organic Rankine Cycle system, and a combined system (ORC + direct expansion. The optimization of the above-mentioned LNG power cycles and exergy analyses are also discussed, with the identification of exergy loss in all components. The analyzed systems achieved exergetic efficiencies in the range of 20 % to 36 % , which corresponds to a net work in the range of 214 to 380 kJ/kg L N G .

  7. Computational modelling of an Organic Rankine Cycle (ORC waste heat recovery system for an aircraft engine

    Directory of Open Access Journals (Sweden)

    Saadon S.

    2018-01-01

    Full Text Available Escalating fuel prices and carbon dioxide emission are causing new interest in methods to increase the thrust force of an aircraft engine with limitation of fuel consumption. One viable means is the conversion of exhaust engine waste heat to a more useful form of energy or to be used in the aircraft environmental system. A one-dimensional analysis method has been proposed for the organic Rankine cycle (ORC waste heat recovery system for turbofan engine in this paper. The paper contains two main parts: validation of the numerical model and a performance prediction of turbofan engine integrated to an ORC system. The cycle is compared with industrial waste heat recovery system from Hangzhou Chinen Steam Turbine Power CO., Ltd. The results show that thrust specific fuel consumption (TSFC of the turbofan engine reach lowest value at 0.91 lbm/lbf.h for 7000 lbf of thrust force. When the system installation weight is applied, the system results in a 2.0% reduction in fuel burn. Hence implementation of ORC system for waste heat recovery to an aircraft engine can bring a great potential to the aviation industry.

  8. Simulation of a heat pump system for total heat recovery from flue gas

    International Nuclear Information System (INIS)

    Wei, Maolin; Yuan, Weixing; Song, Zhijia; Fu, Lin; Zhang, Shigang

    2015-01-01

    This paper introduces an approach of using an open-cycle absorption heat pump (OAHP) for recovering waste heat from the flue gas of a gas boiler with a system model. And equivalent energy efficiency is used to evaluate two other heat recovery systems that integrate an electric compression heat pump (EHP) or an absorption heat pump (AHP) with a boiler. The key factors influencing the systems are evaluated. The OAHP system efficiency is improved by 11% compared to the base case. And the OAHP system is more efficient than the AHP or the EHP systems, especially when the solution mass flow rate is only a little less than the cold water mass flow rate. The energy efficiency comparison is supplemented with a simplified economic analysis. The results indicate that the OAHP system is the best choice for the current prices of electricity and natural gas in Beijing. - Highlights: • An OAHP system is analyzed to improve heat recovery from natural gas flue gas. • OAHP system models are presented and analyzed. • The key factors influencing the OAHP systems are analyzed. • The OAHP system is most efficient for most cases compared with other systems. • The OAHP system is more economic than other systems

  9. Extraction of trace nitrophenols in environmental water samples using boronate affinity sorbent

    International Nuclear Information System (INIS)

    Zhang, Yong; Mei, Meng; Huang, Xiaojia; Yuan, Dongxing

    2015-01-01

    In this research, the applicability of a new sorbent based on boronate affinity material is demonstrated. For this purpose, six strong polar nitrophenols were selected as models which are difficult to be extracted in neutral form (only based on hydrophobic interactions). The extracted nitrophenols were separated and determined by high-performance liquid chromatography with diode array detection. The sorbent was synthesized by in situ copolymerization of 3-acrylamidophenylboronic acid and divinylbenzene using dimethyl sulfoxide and azobisisobutyronitrile as porogen solvent and initiator, respectively. The effect of the preparation parameters in the polymerization mixture on extraction performance was investigated in detail. The size and morphology of the sorbent have been characterized via different techniques such as infrared spectroscopy, elemental analysis, scanning electron microscopy and mercury intrusion porosimetry. The important parameters influencing the extraction efficiency were studied and optimized thoroughly. Under the optimum extraction conditions, the limits of detection (S/N = 3) and limits of quantification (S/N = 10) for the target nitrophenols were 0.097–0.28 and 0.32–0.92 μg/L, respectively. The precision of the proposed method was evaluated in terms of intra- and inter-assay variability calculated as RSD, and it was found that the RSDs were all below 9%. Finally, the developed method was successfully applied for environmental water samples such as wastewater, tap, lake and river water. The recoveries varied within the range of 71.2–115% with RSD below 11% in all cases. The results well demonstrate that the new boronate affinity sorbent can extract nitrophenols effectively through multi-interactions including boron–nitrogen coordination, hydrogen-bond and hydrophobic interactions between sorbent and analytes. - Highlights: • A new boronate affinity sorbent (BAS) was prepared. • The BAS was used as the extractive medium of stir

  10. Performance evaluation and experiment system for waste heat recovery of diesel engine

    International Nuclear Information System (INIS)

    Wenzhi, Gao; Junmeng, Zhai; Guanghua, Li; Qiang, Bian; Liming, Feng

    2013-01-01

    In this paper, a waste heat recovery system is proposed where a high speed turbocharged diesel engine acts as the topper of a combined cycle with exhaust gases used for a bottoming Rankine cycle. The paper describes a mathematical model to evaluate the performance of Rankine cycle system with a reciprocating piston expander. The paper focuses on the performance evaluation and parameter selection of the heat exchanger and reciprocating piston expander that are suitable to waste heat recovery of ICE (internal combustion engine). The paper also describes the experimental setup and the preliminary results. The simulation results show that a proper intake pressure should be 4–5 MPa at its given mass flow rate of 0.015–0.021 kg/s depending on the waste heat recovery of a turbocharged diesel engine (80 kW/2590 rpm). The net power and net power rise rate at various ICE rotation speeds are calculated. The result shows that introducing heat recovery system can increase the engine power output by 12%, when diesel engine operates at 80 kW/2590 rpm. The preliminary experimental results indirectly prove the simulation model by two negative work loops in the P–V curve, under a low intake pressure and steam flow rate condition. - Highlights: • We investigate waste heat recovery through secondary fluid power cycle. • We establish a thermodynamic model of reciprocating steam engine. • We conduct the performance evaluation and experimental system development. • Primary parameters of the heat exchangers and expander are determined

  11. Engineering metal (hydr)oxide sorbents for removal of arsenate and similar weak-acid oxyanion contaminants: A critical review with emphasis on factors governing sorption processes.

    Science.gov (United States)

    Hristovski, Kiril D; Markovski, Jasmina

    2017-11-15

    To create an integrative foundation for engineering of the next generation inexpensive sorbent systems, this critical review addresses the existing knowledge gap in factor/performance relationships between weak-acid oxyanion contaminants and metal (hydr)oxide sorbents. In-depth understanding of fundamental thermodynamics and kinetics mechanisms, material fabrication, and analytical and characterization techniques, is necessary to engineer sorbent that exhibit high capacity, selectivity, stability, durability and mass transport of contaminants under a wide range of operating and water matrix conditions requirements. From the perspective of thermodynamics and kinetics, this critical review examines the factors affecting sorbent performances and analyzes the existing research to elucidate future directions aimed at developing novel sorbents for removal of weak-acid oxyanion contaminants from water. Only sorbents that allow construction of simple and inexpensive water treatment systems adapted to overcome fiscal and technological barriers burdening small communities could pave the road for providing inexpensive potable water to millions of people. Novel sorbents, which exhibit (1) poor performances in realistic operating and water matrix conditions and/or (2) do not comply with the purely driven economics factors of production scalability or cost expectations, are predestined to never be commercialized. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Modeling and Control of a Parallel Waste Heat Recovery System for Euro-VI Heavy-Duty Diesel Engines

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; Jager, B. de; Steinbuch, M.

    2014-01-01

    This paper presents the modeling and control of a waste heat recovery system for a Euro-VI heavy-duty truck engine. The considered waste heat recovery system consists of two parallel evaporators with expander and pumps mechanically coupled to the engine crankshaft. Compared to previous work, the

  13. On resilience studies of system detection and recovery techniques against stealthy insider attacks

    Science.gov (United States)

    Wei, Sixiao; Zhang, Hanlin; Chen, Genshe; Shen, Dan; Yu, Wei; Pham, Khanh D.; Blasch, Erik P.; Cruz, Jose B.

    2016-05-01

    With the explosive growth of network technologies, insider attacks have become a major concern to business operations that largely rely on computer networks. To better detect insider attacks that marginally manipulate network traffic over time, and to recover the system from attacks, in this paper we implement a temporal-based detection scheme using the sequential hypothesis testing technique. Two hypothetical states are considered: the null hypothesis that the collected information is from benign historical traffic and the alternative hypothesis that the network is under attack. The objective of such a detection scheme is to recognize the change within the shortest time by comparing the two defined hypotheses. In addition, once the attack is detected, a server migration-based system recovery scheme can be triggered to recover the system to the state prior to the attack. To understand mitigation of insider attacks, a multi-functional web display of the detection analysis was developed for real-time analytic. Experiments using real-world traffic traces evaluate the effectiveness of Detection System and Recovery (DeSyAR) scheme. The evaluation data validates the detection scheme based on sequential hypothesis testing and the server migration-based system recovery scheme can perform well in effectively detecting insider attacks and recovering the system under attack.

  14. Development of an Organic Rankine Cycle system for exhaust energy recovery in internal combustion engines

    Science.gov (United States)

    Cipollone, Roberto; Bianchi, Giuseppe; Gualtieri, Angelo; Di Battista, Davide; Mauriello, Marco; Fatigati, Fabio

    2015-11-01

    Road transportation is currently one of the most influencing sectors for global energy consumptions and CO2 emissions. Nevertheless, more than one third of the fuel energy supplied to internal combustion engines is still rejected to the environment as thermal waste at the exhaust. Therefore, a greater fuel economy might be achieved recovering the energy from exhaust gases and converting it into useful power on board. In the current research activity, an ORC-based energy recovery system was developed and coupled with a diesel engine. The innovative feature of the recovery power unit relies upon the usage of sliding vane rotary machines as pump and expander. After a preliminary exhaust gas mapping, which allowed to assess the magnitude of the thermal power to be recovered, a thermodynamic analysis was carried out to design the ORC system and the sliding vane machines using R236fa as working fluid. An experimental campaign was eventually performed at different operating regimes according to the ESC procedure and investigated the recovery potential of the power unit at design and off-design conditions. Mechanical power recovered ranged from 0.7 kW up to 1.9 kW, with an overall cycle efficiency from 3.8% up to 4.8% respectively. These results candidate sliding vane machines as efficient and reliable devices for waste heat recovery applications.

  15. A Thermal Energy Recovery System and its Applications in Building (A Short Comunication

    Directory of Open Access Journals (Sweden)

    Afsane Chavoshani

    2016-01-01

    Full Text Available In this paper a heat recovery system from oil heater as a water heater is proposed and analyzed. The potential of heat recovery is studied technically and economically. A model was built and experiments on it are discussed. Recovery of waste heat from the oil heater stack and its application in building is proven to be economically beneficial. The most part of this apparatus was a double-walled tanks and oil heater stack act as firebox for water heater. This tank with 200 liters volume was made of galvanized iron sheets and painted with black color for adsorption of solar radiation. The tank of water heater was filled with 12-15○C water. Sampling was performed at 8 in the morning to 8 at night during one week. The analysis results show that the heat recovery system is recognized as a well option for the examined residential building from both economic and environmental points of view. With the operation considering optimal economic benefits, cost is reduced by about 50%. With maximizing the environmental advantages, CO2 emissions are decreased.

  16. Phosphorus and water recovery by a novel osmotic membrane bioreactor-reverse osmosis system.

    Science.gov (United States)

    Luo, Wenhai; Hai, Faisal I; Price, William E; Guo, Wenshan; Ngo, Hao H; Yamamoto, Kazuo; Nghiem, Long D

    2016-01-01

    An osmotic membrane bioreactor-reverse osmosis (OMBR-RO) hybrid system integrated with periodic microfiltration (MF) extraction was evaluated for simultaneous phosphorus and clean water recovery from raw sewage. In this hybrid system, the forward osmosis membrane effectively retained inorganic salts and phosphate in the bioreactor, while the MF membrane periodically bled them out for phosphorus recovery with pH adjustment. The RO process was used for draw solute recovery and clean water production. Results show that phosphorus recuperation from the MF permeate was most effective when the solution pH was adjusted to 10, whereby the recovered precipitate contained 15-20% (wt/wt) of phosphorus. Periodic MF extraction also limited salinity build-up in the bioreactor, resulting in a stable biological performance and an increase in water flux during OMBR operation. Despite the build-up of organic matter and ammonia in the draw solution, OMBR-RO allowed for the recovery of high quality reused water. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

  17. Recovery in the soil-plant system of nitrogen from green manure applied on cabbage crop

    International Nuclear Information System (INIS)

    Araujo, Ednaldo da Silva; Guerra, Jose Guilherme Marinho; Espindola, Jose Antonio Azevedo; Urquiaga, Segundo; Boddey, Robert Michael; Alves, Bruno Jose Rodrigues; Martelleto, Luiz Aurelio Peres

    2011-01-01

    The objective of this work was to determine, in the soil-plant system, the recovery efficiency of N derived from green manure applied on cabbage (Brassica oleracea) crop. The experiment was divided into two stages: the first one consisted of the straw production of jack bean (Canavalia ensiformis), velvet bean (Mucuna cinereum), and sorghum (Sorghum bicolor), in substrate enriched with 15 N. The second stage consisted of the application of 15 N-labeled green manure on the cabbage beds. Treatments consisted of: fresh residues of jack bean; fresh residues of velvet bean; fresh residues of sorghum; mixture of residues of jack bean, velvet bean, and sorghum at 1:1:1; and control without green manure addition. The N recovery in the soil plant system was influenced by the green manure species used, and the recovery efficiency of the N derived from the green manure legumes varied from 9 to 16%. The jack bean treatment shows a greater recovery efficiency of nitrogen and, therefore, the best synchrony of N supply, by straw decomposition, with the cabbage crop demand. (author)

  18. Reduction of solids and nutrient loss from agricultural land by tailwater recovery systems

    Science.gov (United States)

    Omer, A.R.; Miranda, Leandro E.; Moore, M. T.; Krutz, L. J.; Prince Czarnecki, J. M.; Kröger, R.; Baker, B. H.; Hogue, J.; Allen, P. J.

    2018-01-01

    Best management practices are being implemented throughout the Lower Mississippi River Alluvial Valley with the aim of alleviating pressures placed on downstream aquatic systems by sediment and nutrient losses from agricultural land; however, research evaluating the performance of tailwater recovery (TWR) systems, an increasingly important practice, is limited. This study evaluated the ability of TWR systems to retain sediment and nutrients draining from agricultural landscapes. Composite flow-based samples were collected during flow events (precipitation or irrigation) over a two-year period in six TWR systems. Performance was evaluated by comparing concentrations and loads in water entering TWR systems (i.e., runoff or influent) from agricultural fields to water overflow exiting TWR systems (effluent). Tailwater recovery systems did not reduce concentrations of solids and nutrients, but did reduce loads of solids, phosphorus (P), and nitrogen (N) by 43%, 32%, and 44%, respectively. Annual mean load reductions were 1,142 kg solids, 0.7 kg of P, and 3.8 kg of N. Performance of TWR systems was influenced by effluent volume, system fullness, time since the previous event, and capacity of the TWR system. Mechanistically, TWR systems retain runoff on the agricultural landscape, thereby reducing the amount of sediment and nutrients entering downstream waterbodies. System performance can be improved through manipulation of influential parameters.

  19. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates

  20. A framework for the analysis of cognitive reliability in complex systems: a recovery centred approach

    International Nuclear Information System (INIS)

    Kontogiannis, Tom

    1997-01-01

    Managing complex industrial systems requires reliable performance of cognitive tasks undertaken by operating crews. The infrequent practice of cognitive skills and the reliance on operator performance for novel situations raised cognitive reliability into an urgent and essential aspect in system design and risk analysis. The aim of this article is to contribute to the development of methods for the analysis of cognitive tasks in complex man-machine interactions. A practical framework is proposed for analysing cognitive errors and enhancing error recovery through interface design. Cognitive errors are viewed as failures in problem solving which are difficult to recover under the task constrains imposed by complex systems. In this sense, the interaction between context and cognition, on the one hand, and the process of error recovery, on the other hand, become the focal points of the proposed framework which is illustrated in an analysis of a simulated emergency

  1. TRUEX process solvent cleanup with solid sorbents

    International Nuclear Information System (INIS)

    Tse, Pui-Kwan; Reichley-Yinger, L.; Vandegrift, G.F.

    1989-01-01

    Solid sorbents, alumina, silica gel, and Amberlyst A-26 have been tested for the cleanup of degraded TRUEX-NPH solvent. A sodium carbonate scrub alone does not completely remove acidic degradation products from highly degraded solvent and cannot restore the stripping performance of the solvent. By following the carbonate scrub with either neutral alumina or Amberlyst A-26 anion exchange resin, the performance of the TRUEX-NPH is substantially restored. The degraded TRUEX-NPH was characterized before and after treatment by supercritical fluid chromatography. Its performance was evaluated by americium distribution ratios, phase-separation times, and lauric acid distribution coefficients. 17 refs., 2 figs., 5 tabs

  2. Overview of case studies on recovery of aquatic systems from disturbance

    Science.gov (United States)

    Niemi, Gerald J.; Devore, Philip; Detenbeck, Naomi; Taylor, Debra; Lima, Ann; Pastor, John; Yount, J. David; Naiman, Robert J.

    1990-09-01

    An extensive review of the published literature identified more than 150 case studies in which some aspect of resilience in freshwater systems was reported. Approximately 79% of systems studied were lotic and the remainder lentic. Most of the stressor types were chemical with DDT (N=29) and rotenone (N=15) the most common. The most common nonchemical stressors were logging activity (N=16), flooding (N=8), dredging (N=3), and drought (N=7). The variety of endpoints to which recovery could be measured ranged from sparse data for phytoplankton (N=13), periphyton (N=6), and macrophytes (N=8) to relatively more data for fish (N=412) and macroinvertebrates (N=698). Unfortunately the same characteristics were rarely measured consistently among sites. For example, with respect to fish, more than 30 different species were studied and recovery was measured in many ways, most commonly on the basis of: (1) first reappearance of the species, (2) return time of predisturbance densities, and (3) return time of predisturbance average individual size. Based on these criteria, all systems in these studies seem to be resilient to most disturbances with most recovery times being less than three years. Exceptions included when (1) the disturbance resulted in physical alteration of the existing habitat, (2) residual pollutants remained in the system, or (3) the system was isolated and recolonization was suppressed.

  3. Performance investigation of a cogeneration plant with the efficient and compact heat recovery system

    KAUST Repository

    Myat, Aung

    2011-10-03

    This paper presents the performance investigation of a cogeneration plant equipped with an efficient waste heat recovery system. The proposed cogeneration system produces four types of useful energy namely: (i) electricity, (ii) steam, (iii) cooling and (iv) dehumidification. The proposed plant comprises a Capstone C30 micro-turbine which generates 24 kW of electricity, a compact and efficient waste heat recovery system and a host of waste heat activated devices namely (i) a steam generator, (ii) an absorption chiller, (iii) an adsorption chiller and (iv) a multi-bed desiccant dehumidifier. The numerical analysis for the host of waste heat recovery system and thermally activated devices using FORTRAN power station linked to powerful IMSL library is performed to investigate the performance of the overall system. A set of experiments, both part load and full load, of micro-turbine is conducted to examine the electricity generation and the exhaust gas temperature. It is observed that energy utilization factor (EUF) could achieve as high as 70% while Fuel Energy Saving Ratio (FESR) is found to be 28%.

  4. Assessment of spent mushroom substrate as sorbent of fungicides: influence of sorbent and sorbate properties.

    Science.gov (United States)

    Marín-Benito, Jesús M; Rodríguez-Cruz, M Sonia; Andrades, M Soledad; Sánchez-Martín, María J

    2012-01-01

    The capacity of spent mushroom substrate (SMS) as a sorbent of fungicides was evaluated for its possible use in regulating pesticide mobility in the environment. The sorption studies involved four different SMS types in terms of nature and treatment and eight fungicides selected as representative compounds from different chemical groups. Nonlinear sorption isotherms were observed for all SMS-fungicide combinations. The highest sorption was obtained by composted SMS from Agaricus bisporus cultivation. A significant negative and positive correlation was obtained between the K(OC) sorption constants and the polarity index values of sorbents and the K(OW) of fungicides, respectively. The statistic revealed that more than 77% of the variability in the K(OW) could be explained considering these properties jointly. The other properties of both the sorbent (total carbon, dissolved organic carbon, or pH) and the sorbate (water solubility) were nonsignificant. The hysteresis values for cyprodinil (log K(OW)= 4) were for all the sorbents much higher (>3) than for other fungicides. This was consistent with the remaining sorption after desorption considered as an indicator of the sorption efficiency of SMS for fungicides. Changes in the absorption bands of fungicides sorbed by SMS observed by FTIR permitted establishing the interaction mechanism of fungicides with SMS. The findings of this work provide evidence for the potential capacity of SMS as a sorbent of fungicides and the low desorption observed especially for some fungicides, although they suggest that more stabilized or humified organic substrates should be produced to enhance their efficiency in environmental applications. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  5. The heat recovery with heat transfer methods from solar photovoltaic systems

    International Nuclear Information System (INIS)

    Özakın, A. N.; Karsli, S.; Kaya, F.; Güllüce, H.

    2016-01-01

    Although there are many fluctuations in energy prices, they seems like rising day by day. Thus energy recovery systems have increasingly trend. Photovoltaic systems converts solar radiation directly into electrical energy thanks to semiconductors. But due to the nature of semiconductors, whole of solar energy cannot turn into electrical energy and the remaining energy turns into waste heat. The aim of this research is evaluate this waste heat energy by air cooling system. So, the energy efficiency of the system will be increased using appropriate heat transfer technologies such as fin, turbulator etc. (paper)

  6. Psychological traits influence autonomic nervous system recovery following esophageal intubation in health and functional chest pain.

    Science.gov (United States)

    Farmer, A D; Coen, S J; Kano, M; Worthen, S F; Rossiter, H E; Navqi, H; Scott, S M; Furlong, P L; Aziz, Q

    2013-12-01

    Esophageal intubation is a widely utilized technique for a diverse array of physiological studies, activating a complex physiological response mediated, in part, by the autonomic nervous system (ANS). In order to determine the optimal time period after intubation when physiological observations should be recorded, it is important to know the duration of, and factors that influence, this ANS response, in both health and disease. Fifty healthy subjects (27 males, median age 31.9 years, range 20-53 years) and 20 patients with Rome III defined functional chest pain (nine male, median age of 38.7 years, range 28-59 years) had personality traits and anxiety measured. Subjects had heart rate (HR), blood pressure (BP), sympathetic (cardiac sympathetic index, CSI), and parasympathetic nervous system (cardiac vagal tone, CVT) parameters measured at baseline and in response to per nasum intubation with an esophageal catheter. CSI/CVT recovery was measured following esophageal intubation. In all subjects, esophageal intubation caused an elevation in HR, BP, CSI, and skin conductance response (SCR; all p < 0.0001) but concomitant CVT and cardiac sensitivity to the baroreflex (CSB) withdrawal (all p < 0.04). Multiple linear regression analysis demonstrated that longer CVT recovery times were independently associated with higher neuroticism (p < 0.001). Patients had prolonged CSI and CVT recovery times in comparison to healthy subjects (112.5 s vs 46.5 s, p = 0.0001 and 549 s vs 223.5 s, p = 0.0001, respectively). Esophageal intubation activates a flight/flight ANS response. Future studies should allow for at least 10 min of recovery time. Consideration should be given to psychological traits and disease status as these can influence recovery. © 2013 John Wiley & Sons Ltd.

  7. Heat recovery investigation from dryer–thermal oxidizer system in corn-ethanol plants

    International Nuclear Information System (INIS)

    Olszewski, Pawel

    2015-01-01

    In recent years, annual corn ethanol production in the U.S. has exceeded 13,298,000,000 gallons. However, net energy balance for this sector became a subject of controversy in many discussions. The aim of the presented research is an investigation of thermal improvement opportunities in a corn ethanol plant. For this purpose, a complex mathematical model was developed for a dryer–thermal oxidizer system. Three variants were subjected thermodynamic analyses: one state of the art system and two proposed system modifications. The properties of humid gas, a mixture of combustion products and moisture evaporated from distiller's grain, were updated based on the steam properties according to the formulation proposed by the International Association for the Properties of Water and Steam. All calculations were performed by uniquely-developed C++ code. The results indicate major potential for improvement in the following areas: (i) water recovery from humid gas; (ii) heat recovery from moisture condensation – max. 44% of total primary energy usage (TPEU); and (iii) fuel savings by reduction of humid gas flow through a thermal oxidizer – max. 1.4% of TPEU. Also the presented analysis can be a starting point for further modifications in real corn ethanol manufacturing applications, leading towards pilot system implementation. - Highlights: • Mathematical model for dryer–oxidizer system in a corn ethanol plant was proposed. • Three configurations were discussed: with intercooler, regenerator, and recuperator. • Recovery rate of water condensed at various conditions and locations was quantified. • Heat recovery possibilities at various temperatures and locations have been assessed. • Energy savings in thermal oxidizer due to preliminary condensation were calculated

  8. Post-combustion carbon capture - solid sorbents and membranes

    Energy Technology Data Exchange (ETDEWEB)

    Davidson, R.M.

    2009-01-15

    This report follows on from that on solvent scrubbing for post-combustion carbon capture from coal-fired power plants by considering the use of solid sorbents and membranes instead of solvents. First, mesoporous and microporous adsorbents are discussed: carbon-based adsorbents, zeolites, hydrotalcites and porous crystals. Attempts have been made to improve the performance of the porous adsorbent by functionalising them with nitrogen groups and specifically, amine groups to react with CO{sub 2} and thus enhance the physical adsorption properties. Dry, regenerable solid sorbents have attracted a good deal of research. Most of the work has been on the carbonation/calcination cycle of natural limestone but there have also been studies of other calcium-based sorbents and alkali metal-based sorbents. Membranes have also been studied as potential post-combustion capture devices. Finally, techno-economic studies predicting the economic performance of solid sorbents and membranes are discussed. 340 refs., 21 figs., 8 tabs.

  9. Detoxication and recycling of radioactive waters using selective mineral sorbents

    International Nuclear Information System (INIS)

    Berak, L.

    1980-01-01

    Activated BaSO 4 (designated AB 70) was proposed for use in decontaminating concentrated calcium salt solutions containing a small amount of 226 Ra. The AB 70 concentration factor amounts to 2x1a 3 . A sorption contactor for applying the powder sorbent was proposed and will be tested. The AB 70 sorbent liberates small amounts of sulphates into the decontaminated solution, and thus another suitable mineral sorbent was sought. A new sorbent could be synthetized and tested, called RAS-1 whose Ra/Ca selectivity is comparable to that of AB 70 while its Ra/Ba selectivity is considerably higher. The RAS-1 sorbent is also suitable for radiochemical separation in the analysis and concentration of Ra. (Ha)

  10. Container corporation: The financial, management, and operating implications of a universal beverage container recovery system: Executive summary

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-01

    This report contains an overview of the system. It discusses containers and container materials, elements of the system, and the container recovery cost structure. It includes a financial evaluation and addresses issues of implementation.

  11. Recovery Migration to the City of New Orleans after Hurricane Katrina: A Migration Systems Approach.

    Science.gov (United States)

    Fussell, Elizabeth; Curtis, Katherine J; Dewaard, Jack

    2014-03-01

    Hurricane Katrina's effect on the population of the City of New Orleans provides a model of how severe weather events, which are likely to increase in frequency and strength as the climate warms, might affect other large coastal cities. Our research focuses on changes in the migration system - defined as the system of ties between Orleans Parish and all other U.S. counties - between the pre-disaster (1999-2004) and recovery (2007-2009) periods. Using Internal Revenue Service county-to-county migration flow data, we find that in the recovery period Orleans Parish increased the number of migration ties with and received larger migration flows from nearby counties in the Gulf of Mexico coastal region, thereby spatially concentrating and intensifying the in-migration dimension of this predominantly urban system, while the out-migration dimension contracted and had smaller flows. We interpret these changes as the migration system relying on its strongest ties to nearby and less damaged counties to generate recovery in-migration.

  12. Data Error Detection and Recovery in Embedded Systems: a Literature Review

    Directory of Open Access Journals (Sweden)

    Venu Babu Thati

    2017-06-01

    Full Text Available This paper presents a literature review on data flow error detection and recovery techniques in embedded systems. In recent years, embedded systems are being used more and more in an enormous number of applications from small mobile device to big medical devices. At the same time, it is becoming important for embedded developers to make embedded systems fault-tolerant. To make embedded systems fault-tolerant, error detection and recovery mechanisms are effective techniques to take into consideration. Fault tolerance can be achieved by using both hardware and software techniques. This literature review focuses on software-based techniques since hardware-based techniques need extra hardware and are an extra investment in cost per product. Whereas, software-based techniques needed no or limited hardware. A review on various existing data flow error detection and error recovery techniques is given along with their strengths and weaknesses. Such an information is useful to identify the better techniques among the others.

  13. Using sorbent waste materials to enhance treatment of micro-point source effluents by constructed wetlands

    Science.gov (United States)

    Green, Verity; Surridge, Ben; Quinton, John; Matthews, Mike

    2014-05-01

    Sorbent materials are widely used in environmental settings as a means of enhancing pollution remediation. A key area of environmental concern is that of water pollution, including the need to treat micro-point sources of wastewater pollution, such as from caravan sites or visitor centres. Constructed wetlands (CWs) represent one means for effective treatment of wastewater from small wastewater producers, in part because they are believed to be economically viable and environmentally sustainable. Constructed wetlands have the potential to remove a range of pollutants found in wastewater, including nitrogen (N), phosphorus (P), biochemical oxygen demand (BOD) and carbon (C), whilst also reducing the total suspended solids (TSS) concentration in effluents. However, there remain particular challenges for P and N removal from wastewater in CWs, as well as the sometimes limited BOD removal within these treatment systems, particularly for micro-point sources of wastewater. It has been hypothesised that the amendment of CWs with sorbent materials can enhance their potential to treat wastewater, particularly through enhancing the removal of N and P. This paper focuses on data from batch and mesocosm studies that were conducted to identify and assess sorbent materials suitable for use within CWs. The aim in using sorbent material was to enhance the combined removal of phosphate (PO4-P) and ammonium (NH4-N). The key selection criteria for the sorbent materials were that they possess effective PO4-P, NH4-N or combined pollutant removal, come from low cost and sustainable sources, have potential for reuse, for example as a fertiliser or soil conditioner, and show limited potential for re-release of adsorbed nutrients. The sorbent materials selected for testing were alum sludge from water treatment works, ochre derived from minewater treatment, biochar derived from various feedstocks, plasterboard and zeolite. The performance of the individual sorbents was assessed through

  14. Log-Based Recovery in Asynchronous Distributed Systems. Ph.D. Thesis

    Science.gov (United States)

    Kane, Kenneth Paul

    1989-01-01

    A log-based mechanism is described for restoring consistent states to replicated data objects after failures. Preserving a causal form of consistency based on the notion of virtual time is focused upon in this report. Causal consistency has been shown to apply to a variety of applications, including distributed simulation, task decomposition, and mail delivery systems. Several mechanisms have been proposed for implementing causally consistent recovery, most notably those of Strom and Yemini, and Johnson and Zwaenepoel. The mechanism proposed here differs from these in two major respects. First, a roll-forward style of recovery is implemented. A functioning process is never required to roll-back its state in order to achieve consistency with a recovering process. Second, the mechanism does not require any explicit information about the causal dependencies between updates. Instead, all necessary dependency information is inferred from the orders in which updates are logged by the object servers. This basic recovery technique appears to be applicable to forms of consistency other than causal consistency. In particular, it is shown how the recovery technique can be modified to support an atomic form of consistency (grouping consistency). By combining grouping consistency with casual consistency, it may even be possible to implement serializable consistency within this mechanism.

  15. Understanding Interactions between Hydrogeologic Factors, Design Variables, and System Operations for Multi-Well Aquifer Storage and Recovery Systems

    Science.gov (United States)

    Majumdar, S.; Miller, G. R.; Smith, B.; Sheng, Z.

    2017-12-01

    Aquifer Storage and Recovery (ASR) system is a powerful tool for managing our present and future freshwater supplies. It involves injection of excess water into an aquifer, storing and later recovering it when needed, such as in a drought or during peak demand periods. Multi-well ASR systems, such as the Twin Oaks Facility in San Antonio, consist of a group of wells that are used for simultaneous injection and extraction of stored water. While significant research has gone into examining the effects of hydraulic and operational factors on recovery efficiency for single ASR well, little is known about how multi-well systems respond to these factors and how energy uses may vary. In this study, we created a synthetic ASR model in MODFLOW to test a range of multi-well scenarios. We altered design parameters (well spacing, pumping capacity, well configuration), hydrogeologic factors (regional hydraulic gradient, hydraulic conductivity, dispersivity), and operational variables (injection and withdrawal durations; pumping rates) to determine the response of the system across a realistic range of interrelated parameters. We then computed energy use for each simulation, based on the hydraulic head in each well and standard pump factors, as well as recovery efficiency, based on tracer concentration in recovered water from the wells. The tracer concentration in the groundwater was determined using MT3DMS. We observed that the recovery and energy efficiencies for the Multi-well ASR system decrease with the increase in well spacing and hydraulic gradient. When longitudinal dispersivity was doubled, the recovery and energy efficiencies were nearly halved. Another finding from our study suggests that we can recover nearly 90% of the water after two successive cycles of operation. The results will be used to develop generalized operational guidelines for meeting freshwater demands and also optimise the energy consumed during pumping.

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL; SEMIANNUAL

    International Nuclear Information System (INIS)

    Gary M. Blythe

    2002-01-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO(sub X) selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO(sub 3) formed across the SCR system installed on the unit for NO(sub X) control than at removing SO(sub 3) formed in the furnace. The SO(sub 3) removal results were presented in the

  17. Synthetic Vision System Commercial Aircraft Flight Deck Display Technologies for Unusual Attitude Recovery

    Science.gov (United States)

    Prinzel, Lawrence J., III; Ellis, Kyle E.; Arthur, Jarvis J.; Nicholas, Stephanie N.; Kiggins, Daniel

    2017-01-01

    A Commercial Aviation Safety Team (CAST) study of 18 worldwide loss-of-control accidents and incidents determined that the lack of external visual references was associated with a flight crew's loss of attitude awareness or energy state awareness in 17 of these events. Therefore, CAST recommended development and implementation of virtual day-Visual Meteorological Condition (VMC) display systems, such as synthetic vision systems, which can promote flight crew attitude awareness similar to a day-VMC environment. This paper describes the results of a high-fidelity, large transport aircraft simulation experiment that evaluated virtual day-VMC displays and a "background attitude indicator" concept as an aid to pilots in recovery from unusual attitudes. Twelve commercial airline pilots performed multiple unusual attitude recoveries and both quantitative and qualitative dependent measures were collected. Experimental results and future research directions under this CAST initiative and the NASA "Technologies for Airplane State Awareness" research project are described.

  18. Design and optimization of a large flow rate booster pump in SWRO energy recovery system

    International Nuclear Information System (INIS)

    Lai, Z N; Wu, P; Wu, D Z; Wang, L Q

    2013-01-01

    Seawater reverse osmosis (SWRO) is a high energy-consumption industry, so energy efficiency is an important issue. Energy recovery systems, which contain a pressure exchanger and a booster pump, are widely used in SWRO plants. As a key part of energy recovery system, the difficulty of designing booster pumps lies in high inlet pressure, high medium causticity and large flow rate. High inlet pressure adds difficulties to seal design, and large flow rate and high efficiency requirement bring high demand for hydraulic design. In this paper, a 625 m 3 /h booster pump is designed and optimized according to the CFD (Computational Fluid Dynamics) simulation results. The impeller and volute is well designed, a new type of high pressure mechanical seal is applied and axial force is well balanced. After optimization based on blade redesign, the efficiency of the pump was improved. The best efficiency reaches more than 85% at design point according to the CFD simulation result

  19. Design and optimization of a large flow rate booster pump in SWRO energy recovery system

    Science.gov (United States)

    Lai, Z. N.; Wu, P.; Wu, D. Z.; Wang, L. Q.

    2013-12-01

    Seawater reverse osmosis (SWRO) is a high energy-consumption industry, so energy efficiency is an important issue. Energy recovery systems, which contain a pressure exchanger and a booster pump, are widely used in SWRO plants. As a key part of energy recovery system, the difficulty of designing booster pumps lies in high inlet pressure, high medium causticity and large flow rate. High inlet pressure adds difficulties to seal design, and large flow rate and high efficiency requirement bring high demand for hydraulic design. In this paper, a 625 m3/h booster pump is designed and optimized according to the CFD (Computational Fluid Dynamics) simulation results. The impeller and volute is well designed, a new type of high pressure mechanical seal is applied and axial force is well balanced. After optimization based on blade redesign, the efficiency of the pump was improved. The best efficiency reaches more than 85% at design point according to the CFD simulation result.

  20. Removal of metals from industrial wastewater and urban runoff by mineral and bio-based sorbents.

    Science.gov (United States)

    Gogoi, Harshita; Leiviskä, Tiina; Heiderscheidt, Elisangela; Postila, Heini; Tanskanen, Juha

    2018-03-01

    The study was performed to evaluate chemically modified biosorbents, hydrochloric acid treated peat (HCl-P) and citric acid treated sawdust (Citric acid-SD) for their metal removal capacity from dilute industrial wastewater and urban runoff and compare their efficiency with that of commercially available mineral sorbents (AQM PalPower M10 and AQM PalPower T5M5 magnetite). Batch and column experiments were conducted using real water samples to assess the sorbents' metal sorption capacity. AQM PalPower M10 (consisting mainly of magnesium, iron and silicon oxides) exhibited excellent Zn removal from both industrial wastewater and spiked runoff water samples even at low dosages (0.1 g/L and 0.05 g/L, respectively). The high degree of Zn removal was associated with the release of hydroxyl ions from the sorbent and subsequent precipitation of zinc hydroxide. The biosorbents removed Ni and Cr better than AQM PalPower M10 from industrial wastewater and performed well in removing Cr and Cu from spiked runoff water, although at higher dosages (0.3-0.75 g/L). The main mechanism of sorption by biosorbents was ion exchange. The sorbents required a short contact time to reach equilibrium (15-30 min) in both tested water samples. AQM PalPower T5M5 magnetite was the worst performing sorbent, leaching Zn into both industrial and runoff water and Ni into runoff water. Column tests revealed that both HCl-P and AQM PalPower M10 were able to remove metals, although some leaching was witnessed, especially As from AQM PalPower M10. The low hydraulic conductivity observed for HCl-P may restrict the possibilities of using such small particle size peat material in a filter-type passive system. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. A Low Cost, High Capacity Regenerable Sorbent for Pre-combustion CO{sub 2} Capture

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gokhan

    2012-09-30

    The overall objective of the proposed research is to develop a low cost, high capacity CO{sub 2} sorbent and demonstrate its technical and economic viability for pre-combustion CO{sub 2} capture. The specific objectives supporting our research plan were to optimize the chemical structure and physical properties of the sorbent, scale-up its production using high throughput manufacturing equipment and bulk raw materials and then evaluate its performance, first in bench-scale experiments and then in slipstream tests using actual coal-derived synthesis gas. One of the objectives of the laboratory-scale evaluations was to demonstrate the life and durability of the sorbent for over 10,000 cycles and to assess the impact of contaminants (such as sulfur) on its performance. In the field tests, our objective was to demonstrate the operation of the sorbent using actual coal-derived synthesis gas streams generated by air-blown and oxygen-blown commercial and pilot-scale coal gasifiers (the CO{sub 2} partial pressure in these gas streams is significantly different, which directly impacts the operating conditions hence the performance of the sorbent). To support the field demonstration work, TDA collaborated with Phillips 66 and Southern Company to carry out two separate field tests using actual coal-derived synthesis gas at the Wabash River IGCC Power Plant in Terre Haute, IN and the National Carbon Capture Center (NCCC) in Wilsonville, AL. In collaboration with the University of California, Irvine (UCI), a detailed engineering and economic analysis for the new CO{sub 2} capture system was also proposed to be carried out using Aspen PlusTM simulation software, and estimate its effect on the plant efficiency.

  2. Design and modeling of an advanced marine machinery system including waste heat recovery and removal of sulphur oxides

    DEFF Research Database (Denmark)

    Frimann Nielsen, Rasmus; Haglind, Fredrik; Larsen, Ulrik

    2013-01-01

    -stroke diesel engine and a conventional waste heat recovery system. The results suggest that an organic Rankine cycle placed after the conventional waste heat recovery system is able to extract the sulphuric acid from the exhaust gas, while at the same time increase power generation from waste heat by 32...... consists of a two-stroke diesel engine, the wet sulphuric process for sulphur removal and an advanced waste heat recovery system including a conventional steam Rankine cycle and an organic Rankine cycle. The results are compared with those of a state-of-the-art machinery system featuring a two...

  3. A hydraulic test stand for demonstrating the operation of Eaton’s energy recovery system (ERS)

    OpenAIRE

    Wang, Meng (Rachel); Danzl, Per; Mahulkar, Vishal; Piyabongkarn, Damrongrit (Neng); Brenner, Paul

    2016-01-01

    Fuel cost represents a significant operating expense for owners and fleet managers of hydraulic off-highway vehicles. Further, the upcoming Tier IV compliance for off-highway applications will create further expense for after-treatment and cooling. Solutions that help address these factors motivate fleet operators to consider and pursue more fuelefficient hydraulic energy recovery systems. Electrical hybridization schemes are typically complex, expensive, and often do not satisfy customer pay...

  4. Microbial ureolysis in the seawater-catalysed urine phosphorus recovery system: Kinetic study and reactor verification.

    Science.gov (United States)

    Tang, Wen-Tao; Dai, Ji; Liu, Rulong; Chen, Guang-Hao

    2015-12-15

    Our previous study has confirmed the feasibility of using seawater as an economical precipitant for urine phosphorus (P) precipitation. However, we still understand very little about the ureolysis in the Seawater-based Urine Phosphorus Recovery (SUPR) system despite its being a crucial step for urine P recovery. In this study, batch experiments were conducted to investigate the kinetics of microbial ureolysis in the seawater-urine system. Indigenous bacteria from urine and seawater exhibited relatively low ureolytic activity, but they adapted quickly to the urine-seawater mixture during batch cultivation. During cultivation, both the abundance and specific ureolysis rate of the indigenous bacteria were greatly enhanced as confirmed by a biomass-dependent Michaelis-Menten model. The period for fully ureolysis was decreased from 180 h to 2.5 h after four cycles of cultivation. Based on the successful cultivation, a lab-scale SUPR reactor was set up to verify the fast ureolysis and efficient P recovery in the SUPR system. Nearly complete urine P removal was achieved in the reactor in 6 h without adding any chemicals. Terminal Restriction Fragment Length Polymorphism (TRFLP) analysis revealed that the predominant groups of bacteria in the SUPR reactor likely originated from seawater rather than urine. Moreover, batch tests confirmed the high ureolysis rates and high phosphorus removal efficiency induced by cultivated bacteria in the SUPR reactor under seawater-to-urine mixing ratios ranging from 1:1 to 9:1. This study has proved that the enrichment of indigenous bacteria in the SUPR system can lead to sufficient ureolytic activity for phosphate precipitation, thus providing an efficient and economical method for urine P recovery. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Minimizing temperature instability of heat recovery hot water system utilizing optimized thermal energy storage

    Science.gov (United States)

    Suamir, I. N.; Sukadana, I. B. P.; Arsana, M. E.

    2018-01-01

    One energy-saving technology that starts gaining attractive for hotel industry application in Indonesia is the utilization of waste heat of a central air conditioning system to heat water for domestic hot water supply system. Implementing the technology for such application at a hotel was found that hot water capacity generated from the heat recovery system could satisfy domestic hot water demand of the hotel. The gas boilers installed in order to back up the system have never been used. The hot water supply, however, was found to be instable with hot water supply temperature fluctuated ranging from 45 °C to 62 °C. The temperature fluctuations reaches 17 °C, which is considered instable and can reduce hot water usage comfort level. This research is aimed to optimize the thermal energy storage in order to minimize the temperature instability of heat recovery hot water supply system. The research is a case study approach based on cooling and hot water demands of a hotel in Jakarta-Indonesia that has applied water cooled chillers with heat recovery systems. The hotel operation with 329 guest rooms and 8 function rooms showed that hot water production in the heat recovery system completed with 5 m3 thermal energy storage (TES) could not hold the hot water supply temperature constantly. The variations of the cooling demand and hot water demands day by day were identified. It was found that there was significant mismatched of available time (hours) between cooling demand which is directly correlated to the hot water production from the heat recovery system and hot water usage. The available TES system could not store heat rejected from the condenser of the chiller during cooling demand peak time between 14.00 and 18.00 hours. The extra heat from the heat recovery system consequently increases the temperature of hot water up to 62 °C. It is about 12 K above 50 °C the requirement hot water temperature of the hotel. In contrast, the TES could not deliver proper

  6. Recovery coefficients as a test of system linearity of response in PET

    International Nuclear Information System (INIS)

    Geworski, L.; Munz, D.L.; Knoop, B.; Hofmann, M.; Knapp, W.H.

    2002-01-01

    Aim: New imaging protocols have created an increasing demand for quantitation in dedicated PET. Besides attenuation and scatter correction the recovery correction, accounting for the instrument's limited spatial resolution, has gained importance. For clinical practicability these corrections should work independent from the object, i.e. from the actual distribution of emitter and absorber. Aim of the study was to test this object independency, i.e. system linearity of response, by comparing recovery coefficients (RC) determined for different object geometries. In fact, this comparison may serve as a final test on system linearity of response, as measured on the quantitative accuracy by which the activity concentration in small lesions can be recovered. Method: For hot and cold spot imaging situations spatial distribution of activity is different. Therefore, scatter correction algorithm has to deal with different scatter distributions. If all factors disturbing system linearity, specifically scatter and attenuation, are corrected to a sufficient degree of accuracy, the system behaves linearly resulting in the theoretical relationship. CSRC = (1-HSRC). Thus, this equation, applied hot and cold spot measurements, will serve as a test on the effectiveness of the corrections and, hence, as a test of system linearity of response. Following IEC standard procedures (IEC 61675-1) measurements were done with and without interplane septa (2D/3D) on an ECAT EXACT 922 using a cylindrical phantom containing six spheres of different diameters (10 mm - 40 mm). All data were corrected for attenuation (transmission scan) and scatter (2D: deconvolution, 3D: scatter model), as implemented in the scanner's standard software. Recovery coefficients were determined for cold (CSRC) and hot (HSRC) lesions using both 2D and 3D acquisition mode. Results: CSRC directly measured versus CSRC calculated according to eq. (1) from HSRC resulted in an excellent agreement for both 2D and 3D data

  7. Recovery Act: Hydroelectric Facility Improvement Project - Replacement of Current Mechanical Seal System with Rope Packing System

    Energy Technology Data Exchange (ETDEWEB)

    Stephens, Jessica D.

    2013-05-29

    On January 27, 2010 the City of North Little Rock, Arkansas received notification of the awarding of a Department of Energy (DOE) grant totaling $450,000 in funding from the American Recovery and Reinvestment Act (ARRA) under the Project Title: Recovery Act: Hydroelectric Facility Improvement Project – Automated Intake Clearing Equipment and Materials Management. The purpose of the grant was for improvements to be made at the City’s hydroelectric generating facility located on the Arkansas River. Improvements were to be made through the installation of an intake maintenance device (IMD) and the purchase of a large capacity wood grinder. The wood grinder was purchased in order to receive the tree limbs, tree trunks, and other organic debris that collects at the intake of the plant during high flow. The wood grinder eliminates the periodic burning of the waste material that is cleared from the intake and reduces any additional air pollution to the area. The resulting organic mulch has been made available to the public at no charge. Design discussion and planning began immediately and the wood grinder was purchased in July of 2010 and immediately put to work mulching debris that was gathered regularly from the intake of the facility. The mulch is currently available to the public for free. A large majority of the design process was spent in discussion with the Corps of Engineers to obtain approval for drawings, documents, and permits that were required in order to make changes to the structure of the powerhouse. In April of 2011, the City’s Project Engineer, who had overseen the application, resigned and left the City’s employ. A new Systems Mechanical Engineer was hired and tasked with overseeing the project. The transfer of responsibility led to a re-examination of the original assumptions and research upon which the grant proposal was based. At that point, the project went under review and a trip was booked for July 2011 to visit facilities that currently

  8. Materials recovery system for source-separated noncombustible rubbish and bulky waste in Nishinomiya

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, Yoshihiro

    1987-01-01

    Since 1980, the city of Nishinomiya has been recovering materials from source-separated non-combustible and bulky waste to reduce the amount of final disposal. Materials amounting to 33-39% of the throughput are recovered in the Shredding and Separation Facility, which consists of a manual separation system, a mechanical separation system, a shredder, a pair of shears and incinerators. The facility system is shown in order of processing of the waste. The secondary pollution control, safety equipment, instrumentation, etc., are also described. The recovery percentage and use of revenues are explained in detail.

  9. Application of fuel cells with heat recovery for integrated utility systems

    Science.gov (United States)

    Shields, V.; King, J. M., Jr.

    1975-01-01

    This paper presents the results of a study of fuel cell powerplants with heat recovery for use in an integrated utility system. Such a design provides for a low pollution, noise-free, highly efficient integrated utility. Use of the waste heat from the fuel cell powerplant in an integrated utility system for the village center complex of a new community results in a reduction in resource consumption of 42 percent compared to conventional methods. In addition, the system has the potential of operating on fuels produced from waste materials (pyrolysis and digester gases); this would provide further reduction in energy consumption.

  10. Chemically evolving systems for oil recovery enhancement in heavy oil deposits

    Science.gov (United States)

    Altunina, L. K.; Kuvshinov, I. V.; Kuvshinov, V. A.; Stasyeva, L. A.

    2017-12-01

    This work presents the results of laboratory studies and field tests of new physicochemical technologies for enhanced oil recovery of heavy oil fields under natural development conditions and with thermal-steam stimulation using oil-displacing "smart" systems. The systems are based on surfactants and buffer systems. Their rheological and acid-base properties can be regulated by their chemical evolution directly in the formation. Field tests of the technologies carried out on high-viscosity oil deposit in the Usinskoye oilfield have shown that the EOR technologies are environmentally friendly and technologically effective.

  11. Recovery of 15N-urea in soil-plant system of tanzania grass pasture

    International Nuclear Information System (INIS)

    Martha Junior, Geraldo Bueno; Vilela, Lourival; Corsi, Moacyr; Trivelin, Paulo Cesar Ocheuze

    2009-01-01

    The economic attractiveness and negative environmental impact of nitrogen (N) fertilization in pastures depend on the N use efficiency in the soil-plant system. However, the recovery of urea- 15 N by Panicum maximum cv. Tanzania pastures, one of the most widely used forage species in intensified pastoral systems, is still unknown. This experiment was conducted in a randomized complete block design with four treatments (0, 40, 80 and 120 kg ha-1 of N-urea) and three replications, to determine the recovery of 15 N urea by Tanzania grass. Forage production, total N content and N yield were not affected by fertilization (p > 0.05), reflecting the high losses of applied N under the experimental conditions. The recovery of 15 N urea (% of applied N) in forage and roots was not affected by fertilization levels (p > 0.05), but decreased exponentially in the soil and soil-plant system (p 15 N (kg ha -1 ) in forage and roots (15 to 30 cm) increased with increasing urea doses (p < 0.05). (author)

  12. Optimizing the Costs of Solid Sorbent-Based CO2 Capture Process Through Heat Integration

    Energy Technology Data Exchange (ETDEWEB)

    Sjostrom, Sharon [Ada-Es, Inc., Highlands Ranch, CO (United States)

    2016-03-18

    The focus of this project was the ADAsorb™ CO2 Capture Process, a temperature-swing adsorption process that incorporates a three-stage fluidized bed as the adsorber and a single-stage fluidized bed as the regenerator. ADAsorb™ system was designed, fabricated, and tested under DOE award DEFE0004343. Two amine-based sorbents were evaluated in conjunction with the ADAsorb™ process: “BN”, an ion-exchange resin; and “OJ”, a metal organic framework (MOF) sorbent. Two cross heat exchanger designs were evaluated for use between the adsorber and regenerator: moving bed and fluidized bed. The fluidized bed approach was rejected fairly early in the project because the additional electrical load to power blowers or fans to overcome the pressure drop required for fluidization was estimated to be nominally three times the electrical power that could be generated from the steam saved through the use of the cross heat exchanger. The Energy Research Center at Lehigh University built and utilized a process model of the ADAsorb™ capture process and integrated this model into an existing model of a supercritical PC power plant. The Lehigh models verified that, for the ADAsorb™ system, the largest contributor to parasitic power was lost electrical generation, which was primarily electric power which the host plant could not generate due to the extraction of low pressure (LP) steam for sorbent heating, followed by power for the CO2 compressor and the blower or fan power required to fluidize the adsorber and regenerator. Sorbent characteristics such as the impacts of moisture uptake, optimized adsorption and regeneration temperature, and sensitivity to changes in pressure were also included in the modeling study. Results indicate that sorbents which adsorb more than 1-2% moisture by weight are unlikely to be cost competitive unless they have an extremely high CO2 working capacity that well exceeds 15% by weight. Modeling also revealed

  13. Color recovery effect of different bleaching systems on a discolored composite resin.

    Science.gov (United States)

    Gul, P; Harorlı, O T; Ocal, I B; Ergin, Z; Barutcigil, C

    2017-10-01

    Discoloration of resin-based composites is a commonly encountered problem, and bleaching agents may be used for the therapy of the existing discoloration. The purpose of this study was to investigate in vitro color recovery effect of different bleaching systems on the heavily discolored composite resin. Fifty disk-shaped dental composite specimens were prepared using A2 shade nanohybrid universal composite resin (3M ESPE Filtek Z550, St. Paul, MN, USA). Composite samples were immersed in coffee and turnip juice for 1 week in each. One laser activated bleaching (LB) (Biolase Laserwhite*20) and three conventional bleaching systems (Ultradent Opalescence Boost 40% (OB), Ultradent Opalescence PF 15% home bleaching (HB), Crest 3D White [Whitening Mouthwash]) were tested in this study. Distilled water was used as control group. The color of the samples were measured using a spectrophotometer (VITA Easy shade Compact, VITA Zahnfabrik, Bad Säckingen, Germany). Color changes (ΔE00) were calculated using the CIEDE2000 formula. Statistical analyses were conducted using paired samples test, one-way analysis of variance, and Tukey's multiple comparison tests (α = 0.05). The staining beverages caused perceptible discoloration (ΔE00 > 2.25). The color recovery effect of all bleaching systems was statistically determined to be more effective than the control group (P OB group was found as the most effective bleaching system, there was no statistically significant difference among HB, OB, and LB groups (P > 0.05). Within the limitation of this in vitro study, the highest recovery effect was determined in office bleaching system among all bleaching systems. However, home and laser bleaching systems were determined as effective as office bleaching system.

  14. Investigations of Heat Recovery in Different Refrigeration System Solutions in Supermarkets. Effsys2 project final report

    Energy Technology Data Exchange (ETDEWEB)

    Sawalha, Same; Chen, Yang

    2010-07-01

    Supermarkets are intensive energy consumers with constantly increasing number of installations. About 50 % of the energy consumption in the supermarket is absorbed by the refrigeration system to cover the cooling demands. Simultaneously, heating is needed in the supermarket where the rejected heat from the refrigeration system is usually higher than the needs. It is an interesting possibility to utilize the rejected heat from the refrigeration system to cover the heating needs in supermarkets. The objective of this project is to investigate the heat recovery performance of the new refrigeration system solutions in supermarket applications. The focus is on environmentally friendly systems with natural working fluids, mainly CO{sub 2} trans-critical systems. The project analyzes the temperature levels and capacities of rejected heat from different system solutions and investigates its matching with the heating needs in supermarkets. Using simulation tools this project also aims at defining the system solution/s which has good energy efficiency for simultaneous cooling and heat recovery.

  15. Modeling and control of a parallel waste heat recovery system for Euro-VI heavy-duty diesel engines

    NARCIS (Netherlands)

    Feru, E.; Willems, F.P.T.; Jager, de A.G.; Steinbuch, M.

    2014-01-01

    This paper presents the modeling and control of a waste heat recovery systemfor a Euro-VI heavy-duty truck engine. The considered waste heat recovery system consists of two parallel evaporators with expander and pumps mechanically coupled to the engine crankshaft. Compared to previous work, the

  16. Thermodynamic analysis of an in-cylinder waste heat recovery system for internal combustion engines

    International Nuclear Information System (INIS)

    Zhu, Sipeng; Deng, Kangyao; Qu, Shuan

    2014-01-01

    In this paper, an in-cylinder waste heat recovery system especially for turbocharged engines is proposed to improve the thermal efficiencies of internal combustion engines. Simplified recovery processes can be described as follows: superheated steam generated by engine waste heat is injected into the pipe before the turbine to increase the boost pressure of the fresh air; intake valve close timing is adjusted to control the amount of fresh air as the original level, and thus the higher pressure charged air expands in the intake stroke and transfers the pressure energy directly to the crankshaft. In this way, the increased turbine output by the pre-turbine steam injection is finally recovered in the cylinder, which is different from the traditional Rankine cycle. The whole energy transfer processes are studied with thermodynamic analyses and numerical simulations. The results show that the mass flow rate of the injected steam has the biggest influence on the energy transfer processes followed by the temperature of the injected steam. With this in-cylinder waste heat recovery system, the fuel economy of a selected turbocharged diesel engine can be improved by 3.2% at the rated operating point when the injected mass flow ratio is set to be 0.1. - Highlights: • An in-cylinder waste heat recovery system is proposed. • Effects of injected parameters are studied with energy and exergy balance theories. • Variations of operating points on the compressor map are studied in detail. • The fuel economy is improved by 3.2% at the rated operating point

  17. Application of zirconium dioxide nanoparticle sorbent for the clean-up step in post-harvest pesticide residue analysis.

    Science.gov (United States)

    Uclés, Ana; Herrera López, Sonia; Dolores Hernando, Maria; Rosal, Roberto; Ferrer, Carmen; Fernández-Alba, Amadeo R

    2015-11-01

    The use of yttria-stabilized zirconium dioxide nanoparticles as d-SPE clean-up sorbent for a rapid and sensitive liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) method for the determination of post-harvest fungicides (carbaryl, carbendazim, chlorpropham, diphenylamine, ethoxyquin, flutriafol, imazalil, iprodione, methomyl, myclobutanil, pirimiphos-methyl, prochloraz, pyrimethanil, thiabendazole, thiophanate-methyl and tolclofos-methyl) in orange and pear samples has been evaluated and validated. The sample preparation was a modification of the QuEChERS extraction method using yttria-stabilized zirconium dioxide and multi-walled carbon nanotubes (MWCNTs) nanoparticles as the solid phase extraction (d-SPE) clean-up sorbents prior to injecting the ten-fold diluted extracts into the LC system. By using the yttria-stabilized zirconium dioxide extraction method, more recoveries in the 70-120% range were obtained - thus this method was used for the validation. Quantification was carried out using a matrix-matched calibration curve which was linear in the 1-500 µg kg(-1) range for almost all the pesticides studied. The validated limit of quantification was 10 µg kg(-1) for most of the studied compounds, except chlorpropham, ethoxyquin and thiophanate-methyl. Pesticide recoveries at the 10 and 100 µg kg(-1) concentration levels were satisfactory, with values between 77% and 120% and relative standard deviations (RSD) lower than 10% (n=5). The developed method was applied for the determination of selected fungicides in 20 real orange and pear samples. Four different pesticide residues were detected in 10 of these commodities; 20% of the samples contained pesticide residues at a quantifiable level (equal to or above the LOQs) for at least one pesticide residue. The most frequently-detected pesticide residues were: carbendazim, thiabendazole and imazalil-all were below the MRL. The highest concentration found was imazalil at 1175 µg kg

  18. Evaluation of Sorbents for Acetylene Separation in Atmosphere Revitalization Loop Closure

    Science.gov (United States)

    Abney, Morgan B.; Miller, Lee A.; Barton, Katherine

    2012-01-01

    State-of-the-art carbon dioxide reduction technology uses a Sabatier reactor to recover water from metabolic carbon dioxide. In order to maximize oxygen loop closure, a byproduct of the system, methane, must be reduced to recover hydrogen. NASA is currently exploring a microwave plasma methane pyrolysis system for this purpose. The resulting product stream of this technology includes unreacted methane, product hydrogen, and acetylene. The hydrogen and the small amount of unreacted methane resulting from the pyrolysis process can be returned to the Sabatier reactor thereby substantially improving the overall efficiency of the system. However, the acetylene is a waste product that must be removed from the pyrolysis product. Two materials have been identified as potential sorbents for acetylene removal: zeolite 4A, a commonly available commercial sorbent, and HKUST-1, a newly developed microporous metal. This paper provides an explanation of the rationale behind acetylene removal and the results of separation testing with both materials

  19. A systems perspective of managing error recovery and tactical re-planning of operating teams in safety critical domains.

    Science.gov (United States)

    Kontogiannis, Tom

    2011-04-01

    Research in human error has provided useful tools for designing procedures, training, and intelligent interfaces that trap errors at an early stage. However, this "error prevention" policy may not be entirely successful because human errors will inevitably occur. This requires that the error management process (e.g., detection, diagnosis and correction) must also be supported. Research has focused almost exclusively on error detection; little is known about error recovery, especially in the context of safety critical systems. The aim of this paper is to develop a research framework that integrates error recovery strategies employed by experienced practitioners in handling their own errors. A control theoretic model of human performance was used to integrate error recovery strategies assembled from reviews of the literature, analyses of near misses from aviation and command & control domains, and observations of abnormal situations training at air traffic control facilities. The method of system dynamics has been used to analyze and compare error recovery strategies in terms of patterns of interaction, system affordances, and types of recovery plans. System dynamics offer a promising basis for studying the nature of error recovery management in the context of team interactions and system characteristics. The proposed taxonomy of error recovery strategies can help human factors and safety experts to develop resilient system designs and training solutions for managing human errors in unforeseen situations; it may also help incident investigators to explore why people's actions and assessments were not corrected at the time. Copyright © 2011 Elsevier Ltd. All rights reserved.

  20. Diagnostic instrumentation development program for the heat recovery/seed recovery system of the open-cycle, coal-fired magnetohydrodynamic power plant

    International Nuclear Information System (INIS)

    Murphree, D.L.; Cook, R.L.; Bauman, L.E.

    1981-01-01

    Highly efficient and environmentally acceptable, the coal-fired MHD power plant is an attractive facility for producing electricity. The design of its downstream system, however, presents technological risks which must be corrected if such a plant is to be commercially viable before the end of the century. The heat recovery/seed recovery system (HRSR) at its present stage is vulnerable to corrosion on the gas side of the radiant furnace, the secondary superheater, and the intermediate temperature air heater. Slagging and fouling of the heat transfer surface have yet to be eliminated. Gas chemistry, radiant heat transfer, and particulate removal are other problematic areas which are being researched in a DOE development program whose test activities at three facilities are contributing to an MHD/HRSR data base. In addition, a 20 MWt system to study HRSR design, is being now assembled in Tennessee

  1. Potential of resource recovery in UASB/trickling filter systems treating domestic sewage in developing countries.

    Science.gov (United States)

    Bressani-Ribeiro, T; Brandt, E M F; Gutierrez, K G; Díaz, C A; Garcia, G B; Chernicharo, C A L

    2017-04-01

    This paper aims to present perspectives for energy (thermal and electric) and nutrient (N and S) recovery in domestic sewage treatment systems comprised of upflow anaerobic sludge blanket (UASB) reactors followed by sponge-bed trickling filters (SBTF) in developing countries. The resource recovery potential was characterized, taking into account 114 countries and a corresponding population of 968.9 million inhabitants living in the tropical world, which were grouped into three desired ranges in terms of cities' size. For each of these clusters, a technological arrangement flow-sheet was proposed, depending on their technical and economic viability from our best experience. Considering the population living in cities over 100, 000 inhabitants, the potential of energy and nutrient recovery via the sewage treatment scheme would be sufficient to generate electricity for approximately 3.2 million residents, as well as thermal energy for drying purposes that could result in a 24% volume reduction of sludge to be transported and disposed of in landfills. The results show that UASB/SBTF systems can play a very important role in the sanitation and environmental sector towards more sustainable sewage treatment plants.

  2. Effects of a dual-pump crude-oil recovery system, Bemidji, Minnesota, USA

    Science.gov (United States)

    Delin, Geoffrey N.; Herkelrath, William N.

    2014-01-01

    A crude-oil spill occurred in 1979 when a pipeline burst near Bemidji, MN. In 1998, the pipeline company installed a dual-pump recovery system designed to remove crude oil remaining in the subsurface at the site. The remediation from 1999 to 2003 resulted in removal of about 115,000 L of crude oil, representing between 36% and 41% of the volume of oil (280,000 to 316,000 L) estimated to be present in 1998. Effects of the 1999 to 2003 remediation on the dissolved plume were evaluated using measurements of oil thicknesses in wells plus measurements of dissolved oxygen in groundwater. Although the recovery system decreased oil thicknesses in the immediate vicinity of the remediation wells, average oil thicknesses measured in wells were largely unaffected. Dissolved-oxygen measurements indicate that a secondary plume was caused by disposal of the pumped water in an upgradient infiltration gallery; this plume expanded rapidly immediately following the start of the remediation in 1999. The result was expansion of the anoxic zone of groundwater upgradient and beneath the existing natural attenuation plume. Oil-phase recovery at this site was shown to be challenging, and considerable volumes of mobile and entrapped oil remain in the subsurface despite remediation efforts.

  3. Chemical cocktails in aquatic systems: Pesticide effects on the response and recovery of >20 animal taxa

    International Nuclear Information System (INIS)

    Hua, Jessica; Relyea, Rick

    2014-01-01

    Natural systems are often exposed to individual insecticides or combinations of multiple insecticides. Using an additive and substitutive design, we examined how populations and communities containing >20 animal taxa are affected by four insecticides applied individually and as a mixture for 18 wks in aquatic mesocosms. The four insecticides had distinct lethal effects on the response and recovery of cladocerans, copepods, amphipods, isopods, and amphibians but not snails. The lethal effect on cladocerans and copepods induced trophic cascades that facilitated algal blooms and abiotic changes (higher pH and dissolved oxygen, but lower light transmission). Exposure to endosulfan resulted in a lag effect reducing cladocerans and spring-breeding amphibian abundance. The reduction in spring-breeding amphibian abundance led to cascading indirect effects on summer-breeding amphibians. Finally, the mixture treatment had lethal effects throughout the community that led to long-term effects on amphibian mass and unique indirect consequences on phytoplankton and abiotic variables. - Highlights: • Insecticides had unique direct and indirect effects on response and recovery. • Due to lag effects, endosulfan was more toxic than expected based on 4d tests. • Variation in oviposition phenology led to positive effects on amphibians. • Lethal direct effects of mixtures were pervasive and led to unique indirect effects. - Insecticides applied individually and in a mixture have complex direct and indirect consequences on aquatic system response and recovery

  4. Marine anoxia and delayed Earth system recovery after the end-Permian extinction.

    Science.gov (United States)

    Lau, Kimberly V; Maher, Kate; Altiner, Demir; Kelley, Brian M; Kump, Lee R; Lehrmann, Daniel J; Silva-Tamayo, Juan Carlos; Weaver, Karrie L; Yu, Meiyi; Payne, Jonathan L

    2016-03-01

    Delayed Earth system recovery following the end-Permian mass extinction is often attributed to severe ocean anoxia. However, the extent and duration of Early Triassic anoxia remains poorly constrained. Here we use paired records of uranium concentrations ([U]) and (238)U/(235)U isotopic compositions (δ(238)U) of Upper Permian-Upper Triassic marine limestones from China and Turkey to quantify variations in global seafloor redox conditions. We observe abrupt decreases in [U] and δ(238)U across the end-Permian extinction horizon, from ∼3 ppm and -0.15‰ to ∼0.3 ppm and -0.77‰, followed by a gradual return to preextinction values over the subsequent 5 million years. These trends imply a factor of 100 increase in the extent of seafloor anoxia and suggest the presence of a shallow oxygen minimum zone (OMZ) that inhibited the recovery of benthic animal diversity and marine ecosystem function. We hypothesize that in the Early Triassic oceans-characterized by prolonged shallow anoxia that may have impinged onto continental shelves-global biogeochemical cycles and marine ecosystem structure became more sensitive to variation in the position of the OMZ. Under this hypothesis, the Middle Triassic decline in bottom water anoxia, stabilization of biogeochemical cycles, and diversification of marine animals together reflect the development of a deeper and less extensive OMZ, which regulated Earth system recovery following the end-Permian catastrophe.

  5. Instrumentation and control systems for monitoring and data acquisition for thermal recovery process

    Energy Technology Data Exchange (ETDEWEB)

    Aparicio, J.; Hernandez, E.; Perozo, H. [PDVSA Intevep, S.A. (Venezuela)

    2011-07-01

    Thermal recovery methods are often applied to enhance oil recovery in heavy oil reservoirs, one of its challenges is to control the displacement of the thermal front. Methods are thus implemented to obtain data on the temperatures in the wells at any given time and to monitor other variables so that the behaviour of the thermal front can be predicted. The aim of this paper is to present a new control and instrumentation scheme to measure all of the variables. A software was created using Labview a graphs-based programming language software and PostgreSQL, a database management system. Using this software, sensors can be added or removed at any time; trends can be immediately visualized; and quality of the information is ensured since there is no human intervention in the data collection or processing. This paper presented a software which improves monitoring of all of the variables affecting the behaviour of the thermal front.

  6. The Train Driver Recovery Problem - Solution Method and Decision Support System Framework

    DEFF Research Database (Denmark)

    Rezanova, Natalia Jurjevna

    2009-01-01

    the proposed model and solution method is suitable for solving in real-time. Recovery duties are generated as resource constrained paths in duty networks, and the set partitioning problem is solved with a linear programming based branch-and-price algorithm. Dynamic column generation and problem space expansion...... driver decision support system in their operational environment. Besides solving a particular optimization problem, this thesis contributes with a description of the railway planning process, tactical crew scheduling and the real-time dispatching solutions, taking a starting point in DSB S....... Rezanova NJ, Ryan DM. The train driver recovery problem–A set partitioning based model and solution method. Computers and Operations Research, in press, 2009. doi: 10.1016/j.cor.2009.03.023. 2. Clausen J, Larsen A, Larsen J, Rezanova NJ. Disruption management in the airline industry–Concepts, models...

  7. Tc Generator Development: Up-to-Date Tc Recovery Technologies for Increasing the Effectiveness of Mo Utilisation

    Directory of Open Access Journals (Sweden)

    Van So Le

    2014-01-01

    Full Text Available A review on the Mo sources available today and on the Tc generators developed up to date for increasing the effectiveness of Mo utilisation is performed in the format of detailed description of the features and technical performance of the technological groups of the Mo production and Tc recovery. The latest results of the endeavour in this field are also surveyed in regard of the technical solution for overcoming the shortage of Mo supply. The technological topics are grouped and discussed in a way to reflect the similarity in the technological process of each group. The following groups are included in this review which are high specific activity Mo: the current issues of production, the efforts of more effective utilisation, and the high specific activity Mo-based Tc generator and Tc concentration units; low specific activity Mo: the Mo production based on neutron capture and accelerators and the direct production of Tc and the methods of increasing the specific activity of Mo using Szilard-Chalmers reaction and high electric power isotopic separator; up-to-date technologies of Tc recovery from low specific activity Mo: the solvent extraction-based Tc generator, the sublimation methods for Mo/Tc separation, the electrochemical method for Tc recovery, and the column chromatographic methods for Tc recovery. Besides the traditional Tc-generator systems, the integrated Tc generator systems (Tc generator column combined with postelution purification/concentration unit are discussed with the format of process diagram and picture of real generator systems. These systems are the technetium selective sorbent column-based generators, the high Mo-loading capacity column-based integrated Tc generator systems which include the saline-eluted generator systems, and the nonsaline aqueous and organic solvent eluent-eluted generator systems using high Mo-loading capacity molybdategel and recently developed sorbent columns. Tc concentration methods used in the

  8. Physical inventory by use of modeling for the tritium aqueous waste recovery system

    International Nuclear Information System (INIS)

    Sienkiewicz, C.J.; Lentz, J.E.; Wiggins, D.V.

    1988-01-01

    Physical inventory requirements for the Tritium Aqueous Waste Recovery System (TAWRS) presented constraints that required unique solutions. Available analytical techniques for which sound measurement control practices existed could not be readily adapted to the system without significant modifications and expense. Based on the assumption that would accurately estimate total system inventory given a few key measurements, a model was developed for TAWRS. Tritium concentrations in two streams, the tritiated feed stream to the process and the tritiated hydrogen stream generated by the electrolysis cells, provided the key values to the model. The proposed mathematical model relates the tritium concentration throughout the system to the tritium concentration in these two streams. Testing of the system using low-level tritiated feed water was conducted to characterize tritium distribution in the system and to relate key values to total inventory. 4 refs., 2 figs.,

  9. In vitro catheter and sorbent-based method for clearance of radiocontrast material during cerebral interventions

    International Nuclear Information System (INIS)

    Angheloiu, George O.; Hänscheid, Heribert; Reiners, Christoph; Anderson, William D.; Kellum, John A.

    2013-01-01

    Background: Contrast-induced acute kidney injury is a severe condition resulting from the use of radiology contrast in patients with predisposing factors. Hypothesis: We hypothesized that a novel system including a device containing polymer resin sorbent beads and a custom-made suctioning catheter could efficiently remove contrast from an in vitro novel model of circulatory system (MOCS) mimicking the cerebral circulation. Methods: A custom-made catheter was built and optimized for cerebral venous approach. The efficiency of a system made of a polymer resin sorbent beads column (CST 401, Cytosorbents) and this particular catheter was tested in the MOCS running a solution composed of 0.9% saline and radio-contrast. During two series of 18 cycles of first-pass experiments we assessed the catheter's suctioning efficiency and the system's ability to clear radio-contrast injected into the MOCS's cerebral arterial segment. We also assessed the functioning and reliability of the MOCS. Results: Mean suctioning efficiency of the catheter was 84% ± 24%. The polymer sorbent column contrast removal rate was initially 96% and gradually decreased with subsequent cycles in a linear fashion during an experiment lasting approximately 90 minutes. The MOCS had a reliability of 0.9946×min −1 where 1 × min −1 was the optimum value. Conclusion: A system including a polymer resin sorbent beads column and a custom-made suctioning catheter had an excellent initial efficiency in quickly removing contrast from an artificial MOCS mimicking the cerebral circulation. MOCS is an inexpensive and relatively reliable custom-made system that can be used for training or testing purposes

  10. In vitro catheter and sorbent-based method for clearance of radiocontrast material during cerebral interventions

    Energy Technology Data Exchange (ETDEWEB)

    Angheloiu, George O., E-mail: goangheloiu@drmc.org [Heart and Vascular Institute, University of Pittsburgh Medical Center, Pittsburgh, PA (United States); Department of Cardiology, Dubois Regional Medical Center, Dubois, PA (United States); Hänscheid, Heribert; Reiners, Christoph [Department of Nuclear Medicine, University of Würzburg, Würzburg (Germany); Anderson, William D. [Cardiology Department, Exempla Healthcare, Denver, CO (United States); Kellum, John A. [CRISMA Center, Department of Critical Care Medicine, University of Pittsburgh Medical Center, Pittsburgh, PA (United States)

    2013-07-15

    Background: Contrast-induced acute kidney injury is a severe condition resulting from the use of radiology contrast in patients with predisposing factors. Hypothesis: We hypothesized that a novel system including a device containing polymer resin sorbent beads and a custom-made suctioning catheter could efficiently remove contrast from an in vitro novel model of circulatory system (MOCS) mimicking the cerebral circulation. Methods: A custom-made catheter was built and optimized for cerebral venous approach. The efficiency of a system made of a polymer resin sorbent beads column (CST 401, Cytosorbents) and this particular catheter was tested in the MOCS running a solution composed of 0.9% saline and radio-contrast. During two series of 18 cycles of first-pass experiments we assessed the catheter's suctioning efficiency and the system's ability to clear radio-contrast injected into the MOCS's cerebral arterial segment. We also assessed the functioning and reliability of the MOCS. Results: Mean suctioning efficiency of the catheter was 84% ± 24%. The polymer sorbent column contrast removal rate was initially 96% and gradually decreased with subsequent cycles in a linear fashion during an experiment lasting approximately 90 minutes. The MOCS had a reliability of 0.9946×min{sup −1} where 1 × min{sup −1} was the optimum value. Conclusion: A system including a polymer resin sorbent beads column and a custom-made suctioning catheter had an excellent initial efficiency in quickly removing contrast from an artificial MOCS mimicking the cerebral circulation. MOCS is an inexpensive and relatively reliable custom-made system that can be used for training or testing purposes.

  11. Enhanced Recovery Utilizing Variable Frequency Drives and a Distributed Power System

    Energy Technology Data Exchange (ETDEWEB)

    Randy Peden; Sanjiv Shah

    2005-07-26

    This report describes complete results of the project entitled ''Enhanced Recovery Utilizing Variable Frequency Drives and a Distributed Power System''. This demonstration project was initiated in July 2003 and completed in March 2005. The objective of the project was to develop an integrated power production/variable frequency drive system that could easily be deployed in the oil field that would increase production and decrease operating costs. This report describes all the activities occurred and documents results of the demonstration.

  12. Operations management system advanced automation: Fault detection isolation and recovery prototyping

    Science.gov (United States)

    Hanson, Matt

    1990-01-01

    The purpose of this project is to address the global fault detection, isolation and recovery (FDIR) requirements for Operation's Management System (OMS) automation within the Space Station Freedom program. This shall be accomplished by developing a selected FDIR prototype for the Space Station Freedom distributed processing systems. The prototype shall be based on advanced automation methodologies in addition to traditional software methods to meet the requirements for automation. A secondary objective is to expand the scope of the prototyping to encompass multiple aspects of station-wide fault management (SWFM) as discussed in OMS requirements documentation.

  13. Recovery of invertebrate and vertebrate populations in a coal ash stressed drainage system

    Energy Technology Data Exchange (ETDEWEB)

    Cherry, D.S.

    1979-01-01

    The influence of coal-ash basin effluent on the densities of macrobenthic invertebrate and mosquitofish populations in a swamp drainage system was studied for 50 months. The density of the aquatic biota was periodically altered by heavy ash siltation, decreased pH due to fly ash, and by arsenic, copper, selenium and zinc associated with coal ash. Siltation was most influential in decreasing numbers of invertebrates, and lowered pH (from 7.2 to 5.5) more influential in decreasing mosquito fish and retarding recovery of invertebrates. An efficient primary-secondary retaining basin system enabled most invertebrate groups to recover their previous level of abundance.

  14. Engineering Scoping Study of Thermoelectric Generator Systems for Industrial Waste Heat Recovery

    Energy Technology Data Exchange (ETDEWEB)

    Hendricks, Terry [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Choate, William T. [BCS, Inc., Laurel, MD (United States)

    2006-11-01

    This report evaluates thermoelectric generator (TEG) systems with the intent to: 1) examine industrial processes in order to identify and quantify industrial waste heat sources that could potentially use TEGs; 2) describe the operating environment that a TEG would encounter in selected industrial processes and quantify the anticipated TEG system performance; 3) identify cost, design and/or engineering performance requirements that will be needed for TEGs to operate in the selected industrial processes; and 4) identify the research, development and deployment needed to overcome the limitations that discourage the development and use of TEGs for recovery of industrial waste heat.

  15. Pumped Fluid Loop Heat Rejection and Recovery Systems for Thermal Control of the Mars Science Laboratory

    Science.gov (United States)

    Bhandari, Pradeep; Birur, Gajanana; Prina, Mauro; Ramirez, Brenda; Paris, Anthony; Novak, Keith; Pauken, Michael

    2006-01-01

    This viewgraph presentation reviews the heat rejection and heat recovery system for thermal control of the Mars Science Laboratory (MSL). The MSL mission will use mechanically pumped fluid loop based architecture for thermal control of the spacecraft and rover. The architecture is designed to harness waste heat from an Multi Mission Radioisotope Thermo-electric Generator (MMRTG) during Mars surface operations for thermal control during cold conditions and also reject heat during the cruise aspect of the mission. There are several test that are being conducted that will insure the safety of this concept. This architecture can be used during any future interplanetary missions utilizing radioisotope power systems for power generation.

  16. Model based control for waste heat recovery rankine cycle system in heavy duty trucks

    OpenAIRE

    Grelet, Vincent; Dufour, Pascal; Nadri, Madiha; Lemort, Vincent; Reiche, Thomas

    2015-01-01

    Driven by future emissions legislations and increase in fuel prices engine, gas heat recovering has recently attracted a lot of interest. In the past few years, a high number of studies have shown the interest of energy recovery Rankine based systems for heavy duty trucks engine compounding. Recent studies have brought a significant potential for such a system in a Heavy Duty (HD) vehicle, which can lead to a decrease in fuel consumption of about 5% [Wang et al. (2011)] and reduce engine emis...

  17. Technology for industrial waste heat recovery by organic Rankine cycle systems

    Science.gov (United States)

    Cain, W. G.; Drake, R. L.; Prisco, C. J.

    1984-10-01

    The recovery of industrial waste heat and the conversion thereof to useful electric power by use of Rankine cycle systems is studied. Four different aspects of ORC technology were studied: possible destructive chemical reaction between an aluminum turbine wheel and R-113 working fluid under wheel-to-rotor rub conditions; possible chemical reaction between stainless steel or carbon steel and any of five different ORC working fluids under rotor-stator rub conditions; effects on electric generator properties of extended exposure to an environment of saturated R-113 vapor/fluid; and operational proof tests under laboratory conditions of two 1070 kW, ORC, R-113 hermetic turbogenerator power module systems.

  18. Innovative bioelectrochemical-anaerobic-digestion integrated system for ammonia recovery and bioenergy production from ammonia-rich residues

    DEFF Research Database (Denmark)

    Zhang, Yifeng; Angelidaki, Irini

    2015-01-01

    (SMRC) and a continuous stirred tank reactor (CSTR), to prevent ammonia toxicity during anaerobic digestion by in-situ ammonia recovery and electricity production (Figure 1). In batch experiment, the ammonia concentration in the CSTR decreased from 6 to 0.7 g-N/L with an average recovery rate of 0.18 g-N/L(CSTR...... performance was enhanced. In addition, the coexistence of other cations in CSTR or cathode had no negative effect on the ammonia transportation. In continuous reactor operation, 112% extra biogas production was achieved due to ammonia recovery. High-throughput molecular sequencing analysis showed an impact...... of ammonia recovery on the microbial community composition in the integrated system. Results clearly indicate the great potential of the SMRC-CSTR-coupled system for efficient and cost-effective ammonia recovery, energy production and treatment of ammonia-rich residues....

  19. NIFSIL - a composite sorbent for caesium - properties and application

    International Nuclear Information System (INIS)

    Rajec, P.; Orechovska, J.

    1998-01-01

    Samples of the potassium-nickel ferrocyanides K 2 NiFe(CN) 6 , KNi 1,5 Fe(CN) 6 and Ni 2 Fe(CN) 6 were prepared and their properties studied with respect to their use as sorbents for caesium. Caesium is fixed on mixed alkaline-nickel ferrocyanide without structural change. The capacity of Cs retention never reached the theoretic value corresponding to a total release of the monovalent ions of the solid. High distribution coefficients (K D in the order of 10 4 cm 3 /g) determined in batch experiments show that these sorbents have a very high affinity for caesium ions, even in the presence of competing K + , Na + and Ca 2+ ions. The sorbents have a good chemical stability in a wide pH-range (2-12). The irradiation of some sorbent samples with high energy gamma-rays ( 60 Co) of a total dose of 1.10 5 Gy caused no remarkable changes in the sorbent properties (K D , sorption capacity and kinetics, mechanical stability). The sorbents were also tested for 85 Sr and 239 Pu and the results carried out under dynamic and batch experiments have shown that sorbents are not suitable for removal of these radionuclides. Potassium nickel hexacyanoferrate incorporated in silica-gel matrix could compete with others sorbents based on insoluble hexacyanoferrates, has the advantage of good radiation stability and suitable granulometry. The sorbent was prepared on a pilot scale with a capacity about 1000 kg per year with the prospect that it could be easily upgraded to an industrial scale

  20. ASPEN Plus simulation of coal integrated gasification combined blast furnace slag waste heat recovery system

    International Nuclear Information System (INIS)

    Duan, Wenjun; Yu, Qingbo; Wang, Kun; Qin, Qin; Hou, Limin; Yao, Xin; Wu, Tianwei

    2015-01-01

    Highlights: • An integrated system of coal gasification with slag waste heat recovery was proposed. • The goal of BF slag heat saving and emission reduction was achieved by this system. • The optimal parameters were obtained and the waste heat recovery rate reached 83.08%. • About 6.64 kmol/min syngas was produced when using one ton BF slag to provide energy. - Abstract: This article presented a model for the system of coal gasification with steam and blast furnace slag waste heat recovery by using the ASPEN Plus as the simulating and modeling tool. Constrained by mass and energy balance for the entire system, the model included the gasifier used to product syngas at the chemical equilibrium based on the Gibbs free energy minimization approach and the boiler used to recover the heat of the blast furnace slag (BF slag) and syngas. Two parameters of temperature and steam to coal ratio (S/C) were considered to account for their impacts on the Datong coal (DT coal) gasification process. The carbon gasification efficiency (CE), cold gasification efficiency (CGE), syngas product efficiency (PE) and the heating value of syngas produced by 1 kg pulverized coal (HV) were adopted as the indicators to examine the gasification performance. The optimal operating temperature and S/C were 800 °C and 1.5, respectively. At this condition, CE reached above 90% and the maximum values of the CGE, PE and HV were all obtained. Under the optimal operating conditions, 1000 kg/min BF slag, about 40.41 kg/min DT pulverized coal and 77.94 kg/min steam were fed into the gasifier and approximate 6.64 kmol/min syngas could be generated. Overall, the coal was converted to clean syngas by gasification reaction and the BF slag waste heat was also recovered effectively (reached up to 83.08%) in this system, achieving the objective of energy saving and emission reduction

  1. Octahedral molecular sieve sorbents and catalysts

    Science.gov (United States)

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2010-04-20

    Octahedral molecular sieve sorbents and catalysts are disclosed, including silver hollandite and cryptomelane. These materials can be used, for example, to catalyze the oxidation of CO.sub.x (e.g., CO), NO.sub.x (e.g., NO), hydrocarbons (e.g., C.sub.3H.sub.6) and/or sulfur-containing compounds. The disclosed materials also may be used to catalyze other reactions, such as the reduction of NO.sub.2. In some cases, the disclosed materials are capable of sorbing certain products from the reactions they catalyze. Silver hollandite, in particular, can be used to remove a substantial portion of certain sulfur-containing compounds from a gas or liquid by catalysis and/or sorption. The gas or liquid can be, for example, natural gas or a liquid hydrocarbon.

  2. Potential of Cogon Grass as an Oil Sorbent

    OpenAIRE

    Wiloso, Edi Iswanto; Barlianti, Vera; Anggraini, Irni Fitria; Hendarsyah, Hendris

    2012-01-01

    Experiments on the potential of Cogon grass (lmperata cylindrica), a weed harmful to other plants, for use as a low-cost and biodegradable oil sorbent were carried out under various spill conditions. Flowers of Cogon grass adsorbed much larger amount of high-viscosity lubricating oil (57.9 g-oil/g-sorbent) than that adsorbed by Peat Sorb (7.7 g-oil/g-sorbent), a commercial oilsorbent based on peat. However, the flowers adsorbed only 27.9 g of low-viscosity crude oillgsorbent. In an oil-water ...

  3. Lithium recovery from brine using a λ-MnO2/activated carbon hybrid supercapacitor system.

    Science.gov (United States)

    Kim, Seoni; Lee, Jaehan; Kang, Jin Soo; Jo, Kyusik; Kim, Seonghwan; Sung, Yung-Eun; Yoon, Jeyong

    2015-04-01

    Lithium is one of the most important elements in various fields including energy storage, medicine manufacturing and the glass industry, and demands for lithium are constantly increasing these days. The lime soda evaporation process using brine lake water is the major extraction method for lithium, but this process is not only inefficient and time-consuming but also causes a few environmental problems. Electrochemical recovery processes of lithium ions have been proposed recently, but the better idea for the silver negative electrodes used in these systems is required to reduce its cost or increase long term stability. Here, we report an electrochemical lithium recovery method based on a λ-MnO2/activated carbon hybrid supercapacitor system. In this system, lithium ions and counter anions are effectively captured at each electrode with low energy consumption in a salt solution containing various cationic species or simulated Salar de Atacama brine lake water in Chile. Furthermore, we designed this system as a flow process for practical applications. By experimental analyses, we confirmed that this system has high selectivity and long-term stability, with its performance being retained even after repetitive captures and releases of lithium ions. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. A graphical criterion for working fluid selection and thermodynamic system comparison in waste heat recovery

    International Nuclear Information System (INIS)

    Xi, Huan; Li, Ming-Jia; He, Ya-Ling; Tao, Wen-Quan

    2015-01-01

    In the present study, we proposed a graphical criterion called CE diagram by achieving the Pareto optimal solutions of the annual cash flow and exergy efficiency. This new graphical criterion enables both working fluid selection and thermodynamic system comparison for waste heat recovery. It's better than the existing criterion based on single objective optimization because it is graphical and intuitionistic in the form of diagram. The features of CE diagram were illustrated by studying 5 examples with different heat-source temperatures (ranging between 100 °C to 260 °C), 26 chlorine-free working fluids and two typical ORC systems including basic organic Rankine cycle(BORC) and recuperative organic Rankine cycle (RORC). It is found that the proposed graphical criterion is feasible and can be applied to any closed loop waste heat recovery thermodynamic systems and working fluids. - Highlights: • A graphical method for ORC system comparison/working fluid selection was proposed. • Multi-objectives genetic algorithm (MOGA) was applied for optimizing ORC systems. • Application cases were performed to demonstrate the usage of the proposed method.

  5. Resolution-recovery-embedded image reconstruction for a high-resolution animal SPECT system.

    Science.gov (United States)

    Zeraatkar, Navid; Sajedi, Salar; Farahani, Mohammad Hossein; Arabi, Hossein; Sarkar, Saeed; Ghafarian, Pardis; Rahmim, Arman; Ay, Mohammad Reza

    2014-11-01

    The small-animal High-Resolution SPECT (HiReSPECT) is a dedicated dual-head gamma camera recently designed and developed in our laboratory for imaging of murine models. Each detector is composed of an array of 1.2 × 1.2 mm(2) (pitch) pixelated CsI(Na) crystals. Two position-sensitive photomultiplier tubes (H8500) are coupled to each head's crystal. In this paper, we report on a resolution-recovery-embedded image reconstruction code applicable to the system and present the experimental results achieved using different phantoms and mouse scans. Collimator-detector response functions (CDRFs) were measured via a pixel-driven method using capillary sources at finite distances from the head within the field of view (FOV). CDRFs were then fitted by independent Gaussian functions. Thereafter, linear interpolations were applied to the standard deviation (σ) values of the fitted Gaussians, yielding a continuous map of CDRF at varying distances from the head. A rotation-based maximum-likelihood expectation maximization (MLEM) method was used for reconstruction. A fast rotation algorithm was developed to rotate the image matrix according to the desired angle by means of pre-generated rotation maps. The experiments demonstrated improved resolution utilizing our resolution-recovery-embedded image reconstruction. While the full-width at half-maximum (FWHM) radial and tangential resolution measurements of the system were over 2 mm in nearly all positions within the FOV without resolution recovery, reaching around 2.5 mm in some locations, they fell below 1.8 mm everywhere within the FOV using the resolution-recovery algorithm. The noise performance of the system was also acceptable; the standard deviation of the average counts per voxel in the reconstructed images was 6.6% and 8.3% without and with resolution recovery, respectively. Copyright © 2014 Associazione Italiana di Fisica Medica. Published by Elsevier Ltd. All rights reserved.

  6. Electrospun PVDF fibers and a novel PVDF/CoFe2O4 fibrous composite as nanostructured sorbent materials for oil spill cleanup

    Science.gov (United States)

    Dorneanu, Petronela Pascariu; Cojocaru, Corneliu; Olaru, Niculae; Samoila, Petrisor; Airinei, Anton; Sacarescu, Liviu

    2017-12-01

    In this work, pure polyvinylidene fluoride (PVDF) and PVDF/cobalt ferrite (CoFe2O4) magnetic fibrous composite were successfully prepared by electrospinning method for oil spill sorption applications. The pure spinel phase of CoFe2O4 and PVDF/CoFe2O4 composites were confirmed by X-ray diffraction analysis (XRD). Electrospun sorbent materials were characterized by scanning and transmission electron microscopy (SEM and TEM) as well as by contact angle measurements. In addition, the composite sorbent (PVDF/CoFe2O4) was characterized by magnetic measurements. It revealed good magnetic properties that are of real interest to facilitate the separation of the oil-loaded sorbent under the external magnetic field. Finally, the produced electrospun sorbents were tested for sorption of oily liquids, such as: decane, dodecane and commercial motor oils. We obtained good oil sorption capacity (between 9.751-23.615 g/g of pure PVDF) and (8.133-18.074 g/g for the magnetic composite) depending on the nature of oil tested. The present electrospun magnetic PVDF/CoFe2O4 fibrous composite could be potentially useful for the efficient removal of oil in water and recovery of sorbent material.

  7. LCA and Cost Analysis of Membrane Bioreactor Systems: Influence of Scale, Population Density, Climate, and Methane Recovery

    Science.gov (United States)

    Future changes in drinking and waste water infrastructure need to incorporate a holistic view of the water service sustainability tradeoffs and potential benefits when considering shifts towards new treatment technology, decentralized systems, energy recovery and reuse of treated...

  8. An integrated decision support system for wastewater nutrient recovery and recycling to agriculture

    Science.gov (United States)

    Roy, E. D.; Bomeisl, L.; Cornbrooks, P.; Mo, W.

    2017-12-01

    Nutrient recovery and recycling has become a key research topic within the wastewater engineering and nutrient management communities. Several technologies now exist that can effectively capture nutrients from wastewater, and innovation in this area continues to be an important research pursuit. However, practical nutrient recycling solutions require more than capable nutrient capture technologies. We also need to understand the role that wastewater nutrient recovery and recycling can play within broader nutrient management schemes at the landscape level, including important interactions at the nexus of food, energy, and water. We are developing an integrated decision support system that combines wastewater treatment data, agricultural data, spatial nutrient balance modeling, life cycle assessment, stakeholder knowledge, and multi-criteria decision making. Our goals are to: (1) help guide design decisions related to the implementation of sustainable nutrient recovery technology, (2) support innovations in watershed nutrient management that operate at the interface of the built environment and agriculture, and (3) aid efforts to protect aquatic ecosystems while supporting human welfare in a circular nutrient economy. These goals will be realized partly through the assessment of plausible alternative scenarios for the future. In this presentation, we will describe the tool and focus on nutrient balance results for the New England region. These results illustrate that both centralized and decentralized wastewater nutrient recovery schemes have potential to transform nutrient flows in many New England watersheds, diverting wastewater N and P away from aquatic ecosystems and toward local or regional agricultural soils where they can offset a substantial percentage of imported fertilizer. We will also highlight feasibility criteria and next steps to integrate stakeholder knowledge, economics, and life cycle assessment into the tool.

  9. Prototype demonstration of dual sorbent injection for acid gas control on municipal solid waste combustion units

    Energy Technology Data Exchange (ETDEWEB)

    None

    1994-05-01

    This report gathered and evaluated emissions and operations data associated with furnace injection of dry hydrated lime and duct injection of dry sodium bicarbonate at a commercial, 1500 ton per day, waste-to-energy facility. The information compiled during the project sheds light on these sorbents to affect acid gas emissions from municipal solid waste combustors. The information assesses the capability of these systems to meet the 1990 Clean Air Act and 1991 EPA Emission Guidelines.

  10. From carbon nanostructures to high-performance sorbents for chromatographic separation and preconcentration

    International Nuclear Information System (INIS)

    Postnov, V N; Rodinkov, O V; Moskvin, L N; Novikov, A G; Bugaichenko, A S; Krokhina, O A

    2016-01-01

    Information on carbon nanostructures (fullerenes, nanotubes, graphene, nanodiamond and nanodispersed active carbon) used to develop high-performance sorbents of organics and heavy metal ions from aqueous solutions is collected and analyzed. The advantages in the synthesis of hybrid carbon nanostructures and the possibilities of surface modification of these systems in order to carry out fast sorption pre-concentration are considered. Prospects for application of these materials in sorption technologies and analytical chemistry are discussed. The bibliography includes 364 references

  11. Construction and commissioning of a hydrogen cryogenic distillation system for tritium recovery at ICIT Rm. Valcea

    Energy Technology Data Exchange (ETDEWEB)

    Ana, George, E-mail: george.ana@icsi.ro [Institute for Cryogenic and Isotopic Technologies, Rm. Valcea (Romania); Cristescu, Ion [Karlsruhe Istitute for Technologies, Tritium Laboratory, Eggenstein-Leopoldshaffen (Germany); Draghia, Mirela [ISTECH, Timisoara (Romania); Bucur, Ciprian; Balteanu, Ovidiu; Vijulie, Mihai; Popescu, Gheorghe; Costeanu, Claudiu; Sofilca, Nicolae; Stefan, Iulia; Daramus, Robert; Niculescu, Alina; Oubraham, Anisoara; Spiridon, Ionut; Vasut, Felicia; Moraru, Carmen; Brad, Sebastian [Institute for Cryogenic and Isotopic Technologies, Rm. Valcea (Romania); Pasca, Gheorghe [ISTECH, Timisoara (Romania)

    2016-05-15

    Highlights: • Cryogenic distillation (CD) process is being employed for tritium separation from tritiated hydrogen mixtures. • Process control and safety phylosophy with the detritiation plant from Rm. Vâlcea. • Tests undertaken prior to commissioning of the CD system from Rm. Vâlcea. • Preliminary experiments with the CD system (non-radiological). - Abstract: Cryogenic distillation (CD) of hydrogen in combination with Liquid Phase Catalytic Exchange (LPCE) or Combined Electrolytic Catalytic Exchange (CECE) process is used for tritium removal/recovery from tritiated water. Tritiated water is being obtained after long time operation of CANDU reactors, or in case of ITER mainly by the Detritiation System (DS). The cryogenic distillation system (CDS) used to remove/recover tritium from a hydrogen stream consists of a cascade of cryogenic distillation columns and a refrigeration unit which provides the cooling capacity for the condensers of CD columns. The columns, together with the condensers and the process heat-exchangers are accommodated in a vacuumed cold box. In the particularly case of the ICIT Plant, the cryogenic distillation cascade consists of four columns with diameters between 100–7 mm and it has been designed to process up to 10 mc/h of tritiated deuterium. This paper will present the steps undertaken for construction and commissioning of a pilot plant for tritium removal/recovery by cryogenic distillation of hydrogen. The paper will show besides preliminary data obtained during commissioning, also general characteristics of the plant and its equipments.

  12. Design criteria document, Fire Protection Task, K Basin Essential Systems Recovery, Project W-405

    International Nuclear Information System (INIS)

    Johnson, B.H.

    1994-01-01

    The K Basin were constructed in the early 1950's with a 20 year design life. The K Basins are currently in their third design life and are serving as a near term storage facility for irradiated N Reactor fuel until an interim fuel storage solution can be implemented. In April 1994, Project W-405, K Basin Essential Systems Recovery, was established to address (among other things) the immediate fire protection needs of the 100K Area. A Fire Barrier Evaluation was performed for the wall between the active and inactive areas of the 105KE and 105KW buildings. This evaluation concludes that the wall is capable of being upgraded to provide an equivalent level of fire resistance as a qualified barrier having a fire resistance rating of 2 hours. The Fire Protection Task is one of four separate Tasks included within the scope of Project W405, K Basin Essential systems Recovery. The other three Tasks are the Water Distribution System Task, the Electrical System Task, and the Maintenance Shop/Support Facility Task. The purpose of Project W-405's Fire Protection Task is to correct Life Safety Code (NFPA 101) non-compliances and to provide fire protection features in Buildings 105KE, 105KW and 190KE that are essential for assuring the safe operation and storage of spent nuclear fuel at the 100K Area Facilities' Irradiated Fuel Storage Basins (K Basins)

  13. Modelling of Evaporator in Waste Heat Recovery System using Finite Volume Method and Fuzzy Technique

    Directory of Open Access Journals (Sweden)

    Jahedul Islam Chowdhury

    2015-12-01

    Full Text Available The evaporator is an important component in the Organic Rankine Cycle (ORC-based Waste Heat Recovery (WHR system since the effective heat transfer of this device reflects on the efficiency of the system. When the WHR system operates under supercritical conditions, the heat transfer mechanism in the evaporator is unpredictable due to the change of thermo-physical properties of the fluid with temperature. Although the conventional finite volume model can successfully capture those changes in the evaporator of the WHR process, the computation time for this method is high. To reduce the computation time, this paper develops a new fuzzy based evaporator model and compares its performance with the finite volume method. The results show that the fuzzy technique can be applied to predict the output of the supercritical evaporator in the waste heat recovery system and can significantly reduce the required computation time. The proposed model, therefore, has the potential to be used in real time control applications.

  14. An investigation of heat recovery of submarine diesel engines for combined cooling, heating and power systems

    International Nuclear Information System (INIS)

    Daghigh, Roonak; Shafieian, Abdellah

    2016-01-01

    Highlights: • The power output of the cycle is about 53 kW in the mass flow rate of 0.6 kg/s. • The output cooling water temperature of evaporator is 3.64 °C. • The absorption chiller has a coefficient of performance equal to 0.94. - Abstract: High temperature and mass flow rate of the exhaust gases of submarine diesel engines provide an appropriate potential for their thermal recovery. The current study introduces a combined cooling, heating and power system for thermal recovery of submarine diesel engines. The cooling system is composed of a mixed effect absorption chiller with two high and low pressure generators. The exhaust of the diesel engine is used in the high pressure generator, and the low pressure generator was divided into two parts. The required heat for the first and second compartments is supplied by the cooling water of the engine and condensation of the vapor generated in the high pressure generator, respectively. The power generation system is a Rankine cycle with an organic working fluid, which is considered a normal thermal system to supply hot water. The whole system is encoded based on mass stability, condensation and energy equations. The obtained findings showed that the maximum heat recovery for the power cycle occurs in exhaust gas mass ratio of 0.23–0.29 and working fluid mass flow rate of 0.45–0.57 kg/s. Further, for each specific mass ratio of exhaust gas, only a certain range of working fluid mass flow rate is used. In the refrigerant mass flow rate of 0.6 kg/s and exhaust gas mass ratio of 0.27, the power output of the cycle is 53 kW, which can also be achieved by simultaneous increase of refrigerant mass flow rate and exhaust gas mass ratio in a certain range of higher powers. In the next section, the overall distribution diagram of output water temperature of the thermal system is obtained according to the exhaust gas mass ratio in various mass flow rates, which can increase the potential of designing and controlling the

  15. Heat Recovery from Multiple-Fracture Enhanced Geothermal Systems: The Effect of Thermoelastic Fracture Interactions

    DEFF Research Database (Denmark)

    Vik, Hedda Slatlem; Salimzadeh, Saeed; Nick, Hamid

    2018-01-01

    This study investigates the effect of thermoelastic interactions between multiple parallel fractures on energy production from a multiple-fracture enhanced geothermal system. A coupled thermo-hydro-mechanical finite element model has been developed that accounts for non-isothermal fluid flow within...... increased to maximise the net energy production from the system. Otherwise, the multiple-fracture system fails to improve the energy recovery from the geothermal reservoir, as initially intended....... aperture in the adjacent fracture, and facilitates the creation of favourable flow pathways between the injection and production wells. These flow paths reduce the energy production from the system. The effects of fracture spacing, reservoir temperature gradient and mechanical properties of the rock matrix...

  16. Implementation of Exhaust Gas Recirculation for Double Stage Waste Heat Recovery System on Large Container Vessel

    DEFF Research Database (Denmark)

    Andreasen, Morten; Marissal, Matthieu; Sørensen, Kim

    2014-01-01

    Concerned to push ships to have a lower impact on the environment, the International Maritime Organization are implementing stricter regulation of NOx and SOx emissions, called Tier III, within emission control areas (ECAs). Waste Heat Recovery Systems (WHRS) on container ships consist...... of recovering some of the waste heat from the exhaust gas. This heat is converted into electrical energy used on-board instead of using auxiliary engines. Exhaust Gas Recirculation (EGR) systems, are recirculating a part of the exhaust gas through the engine combustion chamber to reduce emissions. WHRS combined...... with EGR is a potential way to improve system efficiency while reducing emissions. This paper investigates the feasibility of combining the two systems. EGR dilutes the fuel, lowering the combustion temperature and thereby the formation of NOx, to reach Tier III limitation. A double stage WHRS is set up...

  17. Cesium removal demonstration utilizing crystalline silicotitanate sorbent for processing Melton Valley Storage Tank supernate: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Walker, J.F. Jr.; Taylor, P.A.; Cummins, R.L. [and others

    1998-03-01

    This report provides details of the Cesium Removal Demonstration (CsRD), which was conducted at Oak Ridge National Laboratory (ORNL) on radioactive waste from the Melton Valley Storage Tanks. The CsRD was the first large-scale use of state-of-the-art sorbents being developed by private industry for the selective removal of cesium and other radionuclides from liquid wastes stored across the DOE complex. The crystalline silicotitanate sorbent used in the demonstration was chosen because of its effectiveness in laboratory tests using bench-scale columns. The demonstration showed that the cesium could be removed from the supernate and concentrated on a small-volume, solid waste form that would meet the waste acceptance criteria for the Nevada Test Site. During this project, the CsRD system processed > 115,000 L (30,000 gal) of radioactive supernate with minimal operational problems. Sluicing, drying, and remote transportation of the sorbent, which could not be done on a bench scale, were successfully demonstrated. The system was then decontaminated to the extent that it could be contact maintained with the use of localized shielding only. By utilizing a modular, transportable design and placement within existing facilities, the system can be transferred to different sites for reuse. The initial unit has now been removed from the process building and is presently being reinstalled for use in baseline operations at ORNL.

  18. Cesium removal demonstration utilizing crystalline silicotitanate sorbent for processing Melton Valley Storage Tank supernate: Final report

    International Nuclear Information System (INIS)

    Walker, J.F. Jr.; Taylor, P.A.; Cummins, R.L.

    1998-03-01

    This report provides details of the Cesium Removal Demonstration (CsRD), which was conducted at Oak Ridge National Laboratory (ORNL) on radioactive waste from the Melton Valley Storage Tanks. The CsRD was the first large-scale use of state-of-the-art sorbents being developed by private industry for the selective removal of cesium and other radionuclides from liquid wastes stored across the DOE complex. The crystalline silicotitanate sorbent used in the demonstration was chosen because of its effectiveness in laboratory tests using bench-scale columns. The demonstration showed that the cesium could be removed from the supernate and concentrated on a small-volume, solid waste form that would meet the waste acceptance criteria for the Nevada Test Site. During this project, the CsRD system processed > 115,000 L (30,000 gal) of radioactive supernate with minimal operational problems. Sluicing, drying, and remote transportation of the sorbent, which could not be done on a bench scale, were successfully demonstrated. The system was then decontaminated to the extent that it could be contact maintained with the use of localized shielding only. By utilizing a modular, transportable design and placement within existing facilities, the system can be transferred to different sites for reuse. The initial unit has now been removed from the process building and is presently being reinstalled for use in baseline operations at ORNL

  19. Research on the Power Recovery of Diesel Engines with Regulated Two-Stage Turbocharging System at Different Altitudes

    Directory of Open Access Journals (Sweden)

    Hualei Li

    2014-01-01

    Full Text Available Recovering the boost pressure is very important in improving the dynamic performance of diesel engines at high altitudes. A regulated two-stage turbocharging system is an adequate solution for power recovery of diesel engines. In the present study, the change of boost pressure and engine power at different altitudes was investigated, and a regulated two-stage turbocharging system was constructed with an original turbocharger and a matched low pressure turbocharger. The valve control strategies for boost pressure recovery, which formed the basis of the power recovery method, are presented here. The simulation results showed that this system was effective in recovering the boost pressure at different speeds and various altitudes. The turbine bypass valve and compressor bypass valve had different modes to adapt to changes in operating conditions. The boost pressure recovery could not ensure power recovery over the entire operating range of the diesel engine, because of variation in overall turbocharger efficiency. The fuel-injection compensation method along with the valve control strategies for boost pressure recovery was able to reach the power recovery target.

  20. Evaluation of 137Cs sorbents for fixation in concrete

    International Nuclear Information System (INIS)

    Plodinec, M.J.

    1976-01-01

    As part of the long-term waste management program at the Savannah River Laboratory, several 137 Cs sorbents were evaluated for incorporation into concrete. The sorbents studied were: Linde AW-300, AW-500, 13-X, and SK-40; Norton Zeolon 200, 500, and 900; clinoptilolite; and vermiculite. The parameters studied were sorption kinetics, leachability, and compressive strength of the concrete. The best sorbents identified were Linde AW-500 and Norton Zeolon 900. In all tests, these two sorbents performed almost identically; sorption kinetics were acceptable; both strengthened the concrete, and both gave relatively leach-resistant concrete. Vermiculite that had been heated to collapse its lattice around 137 Cs gave the most leach-resistant concrete. However, it sorbed cesium slowly, and the resulting concrete was very weak. When silica gel was added to concrete to react with free calcium, the addition had no effect on cesium leachability

  1. Dual layer hollow fiber sorbents: Concept, fabrication and characterization

    KAUST Repository

    Bhandari, Dhaval; Olanrewaju, Kayode O.; Bessho, Naoki; Breedveld, Victor; Koros, William J.

    2013-01-01

    and to ensure consistent sorption capacity over repeated cycles, a dense, thin polymer barrier layer on the fiber sorbents is needed to allow only thermal interactions between the sorbate loaded layer and the thermal regeneration fluid. This paper considers

  2. Partitioning,Automation and Error Recovery in the Control and Monitoring System of an LHC Experiment

    Institute of Scientific and Technical Information of China (English)

    C.Gaspar

    2001-01-01

    The Joint Controls Project(JCOP)is a collaboration between CERN and the four LHC experiments to find and implement common solutions for their control and monitoring systems.As part of this project and Architecture Working Group was set up in order to study the requirements and devise an architectural model that would suit the four experiments.Many issues were studied by this working group:Alarm handling,Access Control,Hierarchical Control,etc.This paper will report on the specific issue of hierarchical control and in particular partitioning,automation and error recovery.

  3. Recovery of invertebrate and vertebrate populations in a coal ash stressed drainage system

    Energy Technology Data Exchange (ETDEWEB)

    Cherry, D.S.; Larrick, S.R.; Guthrie, R.K.; Davis, E.M.; Sherberger, F.F.

    1979-09-01

    The influence of coal ash effluent on the densities of macrobenthic invertebrate and mosquitofish populations in a swamp drainage system was studied. Samples were collected during a period of 50 mo. Three perturbations in the swamp systemash siltation, low pH, and toxic elementscaused changes in population densities. Siltation from inefficient effluent management caused the greatest drop in invertebrate populations, and pH declines from flyash addition caused the greatest mosquitofish population reductions. Dipterans and odonates were most tolerant to coal ash stress. Invertebrate population recovery was observed on completion of an efficient ash retaining basin. (13 graphs, 28 references, 3 tables)

  4. Site initialization, recovery, and back-up in a distributed database system

    International Nuclear Information System (INIS)

    Attar, R.; Bernstein, P.A.; Goodman, N.

    1982-01-01

    Site initialization is the problem of integrating a new site into a running distributed database system (DDBS). Site recovery is the problem of integrating an old site into a DDBS when the site recovers from failure. Site backup is the problem of creating a static backup copy of a database for archival or query purposes. We present an algorithm that solves the site initialization problem. By modifying the algorithm slightly, we get solutions to the other two problems as well. Our algorithm exploits the fact that a correct DDBS must run a serializable concurrency control algorithm. Our algorithm relies on the concurrency control algorithm to handle all inter-site synchronization

  5. Recovery of flue gas energy in heat integrated IGCC power plants using the contact economizer system

    CSIR Research Space (South Africa)

    Madzivhandila, V

    2010-10-01

    Full Text Available Asia Pacific Confederation of APCChE 2010 Chemical Engineering Congress October 5-8, 2010, Taipei � �� Recovery of flue gas energy in heat integrated IGCC power plants using the contact economizer system Vhutshilo Madzivhandilaa, Thokozani... temperature and the thermal efficiency of the plant. The 13th Asia Pacific Confederation of APCChE 2010 Chemical Engineering Congress October 5-8, 2010, Taipei � �� 1. Introduction The IGCC (Integrated Gasification Combined Cycle) is one...

  6. Applying waste heat recovery system in a sewage sludge dryer – A technical and economic optimization

    International Nuclear Information System (INIS)

    Tańczuk, Mariusz; Kostowski, Wojciech; Karaś, Marcin

    2016-01-01

    Highlights: • A modernization of waste heat recovery system in a sludge drying plant is proposed. • Energy performance analysis rejected the downsize case of modernization. • Optimal system sizes regarding Net Present Value and Net Present Value Ratio do not coincide. • Up to 683 MW h/y of chemical energy savings for optimal heat exchanger size. • Higher profitability for the larger heat exchanger cases: paybacks below 3.65 years. - Abstract: Drying of digested sewage sludge, as an important alternative to sludge disposal at dumping sites, should comply with the requirements of high energy efficiency as well as economic feasibility. The technical and economic optimization analysis of installing a waste process heat recovery unit in a medium-temperature belt dryer operated in a municipal waste water treatment plant was carried out. Inlet capacity of the plant is 1.83 Mg of wet sludge per hour. The post-process air was indicated as a source of waste heat and the configuration of a heat recovery system was proposed. The main objective of the research was to find the optimal size of a chosen type of waste heat recovery heat exchanger for preheating ambient air to the process. The maximization of Net Present Value, and, alternatively, also Net Present Value Ratio were selected for the objective function of the optimization procedure. Simulation of yearly operation of waste heat exchanger was made for a range of different heat exchanging areas (101–270 m"2) regarding given parameters of a post-process air and different temperatures of ambient air. Energy performance of the modernization was evaluated and economic indices were calculated for each of the analyzed cases. The location of the maximum of optimization function was found and the calculations show higher profitability of the cases with larger waste heat exchanger. It can be concluded that the location of optimum of the objective function is very sensitive to the price of natural gas supplied to the

  7. Advanced Horizontal Well Recirculation Systems for Geothermal Energy Recovery in Sedimentary and Crystalline Formations

    Energy Technology Data Exchange (ETDEWEB)

    Bruno, Mike S. [Terralog Technologies USA, Inc., Calgary (Canada); Detwiler, Russell L. [Terralog Technologies USA, Inc., Calgary (Canada); Lao, Kang [Terralog Technologies USA, Inc., Calgary (Canada); Serajian, Vahid [Terralog Technologies USA, Inc., Calgary (Canada); Elkhoury, Jean [Terralog Technologies USA, Inc., Calgary (Canada); Diessl, Julia [Terralog Technologies USA, Inc., Calgary (Canada); White, Nicky [Terralog Technologies USA, Inc., Calgary (Canada)

    2012-12-13

    There is increased recognition that geothermal energy resources are more widespread than previously thought, with potential for providing a significant amount of sustainable clean energy worldwide. Recent advances in drilling, completion, and production technology from the oil and gas industry can now be applied to unlock vast new geothermal resources, with some estimates for potential electricity generation from geothermal energy now on the order of 2 million megawatts. The primary objectives of this DOE research effort are to develop and document optimum design configurations and operating practices to produce geothermal power from hot permeable sedimentary and crystalline formations using advanced horizontal well recirculation systems. During Phase I of this research project Terralog Technologies USA and The University of California, Irvine (UCI), have completed preliminary investigations and documentation of advanced design concepts for paired horizontal well recirculation systems, optimally configured for geothermal energy recovery in permeable sedimentary and crystalline formations of varying structure and material properties. We have also identified significant geologic resources appropriate for application of such technology. The main challenge for such recirculation systems is to optimize both the design configuration and the operating practices for cost-effective geothermal energy recovery. These will be strongly influenced by sedimentary formation properties, including thickness and dip, temperature, thermal conductivity, heat capacity, permeability, and porosity; and by working fluid properties.

  8. Numerical study of entrainment of the human circadian system and recovery by light treatment.

    Science.gov (United States)

    Kim, Soon Ho; Goh, Segun; Han, Kyungreem; Kim, Jong Won; Choi, MooYoung

    2018-05-09

    While the effects of light as a zeitgeber are well known, the way the effects are modulated by features of the sleep-wake system still remains to be studied in detail. A mathematical model for disturbance and recovery of the human circadian system is presented. The model combines a circadian oscillator and a sleep-wake switch that includes the effects of orexin. By means of simulations, we characterize the period-locking zone of the model, where a stable 24-hour circadian rhythm exists, and the occurrence of circadian disruption due to both insufficient light and imbalance in orexin. We also investigate how daily bright light treatments of short duration can recover the normal circadian rhythm. It is found that the system exhibits continuous phase advance/delay at lower/higher orexin levels. Bright light treatment simulations disclose two optimal time windows, corresponding to morning and evening light treatments. Among the two, the morning light treatment is found effective in a wider range of parameter values, with shorter recovery time. This approach offers a systematic way to determine the conditions under which circadian disruption occurs, and to evaluate the effects of light treatment. In particular, it could potentially offer a way to optimize light treatments for patients with circadian disruption, e.g., sleep and mood disorders, in clinical settings.

  9. Design, Prototyping, and Assessment of a Wastewater Closed-Loop Recovery and Purification System

    Directory of Open Access Journals (Sweden)

    Marco Bortolini

    2017-10-01

    Full Text Available Efforts to decrease the water use within industry are mandatory to pursue product and process sustainability. Particularly, the European Union (EU is at the top level for water consumption in industry, while some sectors, such as the food and beverage (F&B, are highly water-intensive with hundreds of liters per hour of consumed and, then, drained water. This article provides a systematic overview of the most innovative insights coming from an EU Eco-Innovation project dealing with greening the F&B industry through the design, prototyping, technical, economic, and environmental assessment of a wastewater closed-loop recovery and purification system. The system, tailored for a standard mid-size F&B company using 2–3 billion L/year of raw water, collects, purifies and recirculates the key produced wastewater streams with an overall recovery efficiency of about 56%. The proposed purification technology comes from the most efficient combination of membrane-based filtration methods, reverse osmosis (RO, and ultraviolet modules. Evidence from the technical design, full-scale on-site technology prototyping, net-present-value (NPV analysis and system life-cycle-assessment (LCA are presented concluding about the convenience of adopting the proposed solution to reduce costs and impacts on the environment.

  10. Oil sorbents from plastic wastes and polymers: A review.

    Science.gov (United States)

    Saleem, Junaid; Adil Riaz, Muhammad; Gordon, McKay

    2018-01-05

    A large volume of the waste produced across the world is composed of polymers from plastic wastes such as polyethylene (HDPE or LDPE), polypropylene (PP), and polyethylene terephthalate (PET) amongst others. For years, environmentalists have been looking for various ways to overcome the problems of such large quantities of plastic wastes being disposed of into landfill sites. On the other hand, the usage of synthetic polymers as oil sorbents in particular, polyolefins, including polypropylene (PP) and polyethylene (PE) have been reported. In recent years, the idea of using plastic wastes as the feed for the production of oil sorbents has gained momentum. However, the studies undertaking such feasibility are rather scattered. This review paper is the first of its kind reporting, compiling and reviewing these various processes. The production of an oil sorbent from plastic wastes is being seen to be satisfactorily achievable through a variety of methods Nevertheless, much work needs to be done regarding further investigation of the numerous parameters influencing production yields and sorbent qualities. For example, differences in results are seen due to varying operating conditions, experimental setups, and virgin or waste plastics being used as feeds. The field of producing oil sorbents from plastic wastes is still very open for further research, and seems to be a promising route for both waste reduction, and the synthesis of value-added products such as oil sorbents. In this review, the research related to the production of various oil sorbents based on plastics (plastic waste and virgin polymer) has been discussed. Further oil sorbent efficiency in terms of oil sorption capacity has been described. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. REMOVAL OF ANIONIC SURFACTANTS FROM WASTEWATER BY MAGNETIC MINERAL SORBENTS

    Directory of Open Access Journals (Sweden)

    Oksana Vladimirova Makarchuk

    2016-07-01

    Full Text Available The simplest and most effective method of removing low concentrations of anionic surfactants such as sodium dodecyl benzenesulfonate (SDBS and sodium lauryl sulfate (SLS is adsorption. Among adsorbents the natural clays are cheap and promising for these purposes. However, there are significant difficulties in removal of spent sorbent after the adsorption process. So, the creation of magnetic sorbents that can be effectively removed from water after sorption by magnetic separation will be a successful decision. The aim of this investigation is the creation of cheap and efficient magnetic sorbents based on natural clays and magnetite for anionic surfactant removal from wastewater. We have synthesized a series of magnetic sorbents from different natural clays with a content of magnetite from 2 to 10 wt%. The ability of magnetic sorbents to remove SDBS and SLS from aqueous solutions has been studied for different adsorbate concentrations by varying the amount of adsorbent, temperature and shaking time. Thermodynamic parameters were calculated from the slope and intercept of the linear plots of ln K against 1/T. Analysis of adsorption results obtained at different temperatures showed that the adsorption pattern on magnetic sorbents correspond to the Langmuir isotherm. It is shown that with increasing the content of magnetite in the magnetic sorbents improves not only their separation from water by magnetic separation, but adsorption capacity to SDBS and SLS. Thus, we obtained of cheap magnetic sorbents based on natural clays and magnetite by the easy way, which not only quickly separated from the solution by magnetic separation, but effectively remove anionic surfactants.

  12. Effectiveness of liquid radioactive waste purification by inorganic granulated sorbents

    International Nuclear Information System (INIS)

    Komarevskij, V.M.; Stepanets, O.V.; Sharygin, L.M.; Matveev, S.A.

    1995-01-01

    Study results on purification of simulative and real liquid radioactive wastes from fission products radionuclides and by inorganic corrosion-nature sorbents 'Thermoxide' are presented. Properties by sorption of cesium, strontium and cobalt are studied; results of experiments on purification of weakly-salted water solutions (waste waters, ships drainage tanks, showers and laundries) of the Beloyarsk NPP are presented. Sorbents source characteristics are determined. 4 refs., 2 figs., 3 tabs

  13. Comparison of a wellpoint vacuum pump system to dual pump recovery system effectiveness for the extraction of light non-aqueous phase liquids

    International Nuclear Information System (INIS)

    Koll, C.S.; Palmerton, D.L. Jr.; Kunzel, R.G.

    1994-01-01

    The effectiveness of two light non-aqueous phase liquid (LNAPL) extraction systems is compared at a site in the Mid-New Jersey Atlantic Coastal Plains Region: an existing dual pump recovery system and a wellpoint vacuum pump system. Home heating oil was released to a shallow sand and gravel aquifer by a leaky underground distribution system in the early 1970s. Eight-inch-diameter dual pump recovery wells were used for the last nine years, to lower the water table and extract LNAPL at several spill sites located throughout a residential community of 1,500 homes. Several small LNAPL plumes still exist today with surface areas ranging from 400 ft 2 to over 28,000 ft 2 . LNAPL recovery peaked in 1985 using dual pump recovery systems, averaging 33 gallons per day (gpd). In 1987, four 24-inch wells were replaced by 11 8-inch-diameter recovery wells at six sites, and LNAPL recovery rates averaged 5 gpd. In recent years, the recovery of LNAPL has declined and when graphed, is asymptotic. In 1993, dual pump recovery of LNAPL averaged 0.3 gpd for all six sites

  14. Sensing system for detection and control of deposition on pendant tubes in recovery and power boilers

    Science.gov (United States)

    Kychakoff, George [Maple Valley, WA; Afromowitz, Martin A [Mercer Island, WA; Hogle, Richard E [Olympia, WA

    2008-10-14

    A system for detection and control of deposition on pendant tubes in recovery and power boilers includes one or more deposit monitoring sensors operating in infrared regions of about 4 or 8.7 microns and directly producing images of the interior of the boiler, or producing feeding signals to a data processing system for information to enable a distributed control system by which the boilers are operated to operate said boilers more efficiently. The data processing system includes an image pre-processing circuit in which a 2-D image formed by the video data input is captured, and includes a low pass filter for performing noise filtering of said video input. It also includes an image compensation system for array compensation to correct for pixel variation and dead cells, etc., and for correcting geometric distortion. An image segmentation module receives a cleaned image from the image pre-processing circuit for separating the image of the recovery boiler interior into background, pendant tubes, and deposition. It also accomplishes thresholding/clustering on gray scale/texture and makes morphological transforms to smooth regions, and identifies regions by connected components. An image-understanding unit receives a segmented image sent from the image segmentation module and matches derived regions to a 3-D model of said boiler. It derives a 3-D structure the deposition on pendant tubes in the boiler and provides the information about deposits to the plant distributed control system for more efficient operation of the plant pendant tube cleaning and operating systems.

  15. IEA low NOx combustion project Stage III. Low NOx combustion and sorbent injection demonstration projects. V.2

    International Nuclear Information System (INIS)

    Payne, R.

    1991-03-01

    This report summarizes the main results from an IES project concerning the demonstration of low-NO x combustion and sorbent injection as techniques for the control of NO x and SO x emissions from pulverized coal fired utility boilers. The project has built upon information generated in two previous stages of activity, where NO x and SO x control processes were evaluated at both fundamental and pilot-scales. The concept for this stage of the project was for a unique collaboration, where the participating countries (Canada, Denmark and Sweden, together with the United States) have pooled information from full scale boiler demonstrations of low-NO x burner and sorbent injection technologies, and have jointly contributed to establishing a common basis for data evaluation. Demonstration testing was successfully carried out on five wall-fired commercial boiler systems which ranged in size from a 20 MW thermal input boiler used for district heating, up to a 300 MW electric utility boiler. All of these units were fired on high-volatile bituminous coals with sulfur contents ranging from 0.6-3.2 percent. At each site the existing burners were either modified or replaced to provide for low-NO x combustion, and provisions were made to inject calcium based sorbent materials into the furnace space for SO 2 emission control. The results of sorbent injection testing showed moderate levels of SO 2 removal which ranged from approximately 15 to 55 percent at an injected calcium to sulfur molar ratio to 2.0 and with boiler operation at nominal full load. Sulfur capture was found to depend upon the combined effects of parameters such as: sorbent type and reactivity; peak sorbent temperature; coal sulfur content; and the thermal characteristics of the boilers. (8 refs., 58 figs., 6 tabs.)

  16. Evaluation of Solid Sorbents As A Retrofit Technology for CO{sub 2} Capture from Coal-Fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Krutka, Holly; Sjostrom, Sharon

    2011-07-31

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process / equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines, 31 carbon based materials, 6 zeolites, 7 supported carbonates (evaluated under separate funding), 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different

  17. Material and energy recovery in integrated waste management systems. An evaluation based on life cycle assessment

    International Nuclear Information System (INIS)

    Giugliano, Michele; Cernuschi, Stefano; Grosso, Mario; Rigamonti, Lucia

    2011-01-01

    This paper reports the environmental results, integrated with those arising from mass and energy balances, of a research project on the comparative analysis of strategies for material and energy recovery from waste, funded by the Italian Ministry of Education, University and Research. The project, involving the cooperation of five University research groups, was devoted to the optimisation of material and energy recovery activities within integrated municipal solid waste (MSW) management systems. Four scenarios of separate collection (overall value of 35%, 50% without the collection of food waste, 50% including the collection of food waste, 65%) were defined for the implementation of energetic, environmental and economic balances. Two sizes of integrated MSW management system (IWMS) were considered: a metropolitan area, with a gross MSW production of 750,000 t/year and an average province, with a gross MSW production of 150,000 t/year. The environmental analysis was conducted using Life Cycle Assessment methodology (LCA), for both material and energy recovery activities. In order to avoid allocation we have used the technique of the expansion of the system boundaries. This means taking into consideration the impact on the environment related to the waste management activities in comparison with the avoided impacts related to the saving of raw materials and primary energy. Under the hypotheses of the study, both for the large and for the small IWMS, the energetic and environmental benefits are higher than the energetic and environmental impacts for all the scenarios analysed in terms of all the indicators considered: the scenario with 50% separate collection in a drop-off scheme excluding food waste shows the most promising perspectives, mainly arising from the highest collection (and recycling) of all the packaging materials, which is the activity giving the biggest energetic and environmental benefits. Main conclusions of the study in the general field of the

  18. Applicability of Zeolite Based Systems for Ammonia Removal and Recovery From Wastewater.

    Science.gov (United States)

    Das, Pallabi; Prasad, Bably; Singh, Krishna Kant Kumar

    2017-09-01

      Ammonia discharged in industrial effluents bears deleterious effects and necessitates remediation. Integrated systems devoted to recovery of ammonia in a useful form and remediation of the same addresses the challenges of waste management and its utilization. A comparative performance evaluation study was undertaken to access the suitability of different zeolite based systems (commercial zeolites and zeolites synthesized from fly ash) for removal of ammonia followed by its subsequent release. Four main parameters which were studied to evaluate the applicability of such systems for large scale usage are cost-effectiveness, ammonia removal efficiency, performance on regeneration, and ammonia release percentage. The results indicated that synthetic zeolites outperformed zeolites synthesized from fly ash, although the later proved to be more efficient in terms of total cost incurred. Process technology development in this direction will be a trade-of between cost and ammonia removal and release efficiencies.

  19. Advanced Recovery and Integrated Extraction System (ARIES) program plan. Rev. 1

    International Nuclear Information System (INIS)

    Nelson, T.O.; Massey, P.W.; Cremers, T.L.

    1996-01-01

    The Advanced Recovery and Integrated Extraction System (ARIES) demonstration combines various technologies, some of which were/are being developed under previous/other Department of Energy (DOE) funded programs. ARIES is an overall processing system for the dismantlement of nuclear weapon primaries. The program will demonstrate dismantlement of nuclear weapons and retrieval of the plutonium into a form that is compatible with long term storage and that is inspectable in an unclassified form appropriate for the application of traditional international safeguards. The success of the ARIES demonstration would lead to the development of a transportable modular or other facility type systems for weapons dismantlement to be used at other DOE sites as well as in other countries

  20. Recovery of reactor electrical assemblies using differential de-encapsulation to remove dielectric insulation systems

    International Nuclear Information System (INIS)

    Hubrig, J.G.; Hammerstone, E.B.

    1986-01-01

    State-of-the-art de-encapsulation technologies associated with the conventional dielectric insulation systems employed in the construction of electrical coils and power distribution systems do not allow for accurate fatigue/failure analysis or reliable recovery of costly assembly components. Differential de-encapsulation allows for the selective removal of contemporary thermoset resin based insulation systems to allow non-destructive penetration of insulation wall thicknesses to both examine critical areas and recover high performance metallic and non-metallic inserts for remanufacture; significantly reducing replacement costs and reactor downtime. The authors' analysis describes how the availability of engineering data from the selective and non-destructive removal of insulation materials will aid in the evaluation of original manufacture, materials and procedures; enabling redesign to enhance subsequent on line performance. They also discuss why the ability to recover coil and core assemblies for remanufacture will have a major economic impact on reactor management costs

  1. Nonlinear unknown input sliding mode observer based chaotic system synchronization and message recovery scheme with uncertainty

    International Nuclear Information System (INIS)

    Sharma, Vivek; Sharma, B.B.; Nath, R.

    2017-01-01

    In the present manuscript, observer based synchronization and message recovery scheme is discussed for a system with uncertainties. LMI conditions are analytically derived solution of which gives the observer design matrices. Earlier approaches have used adaptive laws to address the uncertainties, however in present work, decoupling approach is used to make observer robust against uncertainties. The methodology requires upper bounds on nonlinearity and the message signal and estimates for these bounds are generated adaptively. Thus no information about the nature of nonlinearity and associated Lipschitz constant is needed in proposed approach. Message signal is recovered using equivalent output injection which is a low pass filtered equivalent of the discontinuous effort required to maintain the sliding motion. Finally, the efficacy of proposed Nonlinear Unknown Input Sliding Mode Observer (NUISMO) for chaotic communication is verified by conducting simulation studies on two chaotic systems i.e. third order Chua circuit and Rossler system.

  2. Split radiator design for heat rejection optimization for a waste heat recovery system

    Science.gov (United States)

    Ernst, Timothy C.; Nelson, Christopher R.

    2016-10-18

    A cooling system provides improved heat recovery by providing a split core radiator for both engine cooling and condenser cooling for a Rankine cycle (RC). The cooling system includes a radiator having a first cooling core portion and a second cooling core portion. An engine cooling loop is fluidly connected the second cooling core portion. A condenser of an RC has a cooling loop fluidly connected to the first cooling core portion. A valve is provided between the engine cooling loop and the condenser cooling loop adjustably control the flow of coolant in the condenser cooling loop into the engine cooling loop. The cooling system includes a controller communicatively coupled to the valve and adapted to determine a load requirement for the internal combustion engine and adjust the valve in accordance with the engine load requirement.

  3. New Sorbents for Removing Arsenic From Water

    Science.gov (United States)

    McConchie, D. M.; Genc-Fuhrman, H.; Clark, M. W.; Caldicott, W.; Davies-McConchie, F. G.

    2004-12-01

    Elevated concentrations of arsenic in the drinking water used in many countries, including some of the poorest developing countries, and recognition that consuming this water can have serious consequences for human health, have led to increased investigations of ways to obtain safe water supplies. Finding new groundwater resources is a possible solution but this is a costly strategy that has no guarantee of success, particularly in areas where water is already a scarce commodity. The alternative is to treat water that is already available, but existing technologies are usually too expensive, too difficult to operate and maintain, or not completely effective when used in less developed countries or remote areas. There is therefore, an urgent need to find a simple and effective but inexpensive sorbent for arsenic that can be used to treat large volumes of water under less than ideal conditions. In this paper we present the results of field and laboratory trials that used a new, highly cost-effective, sorbent to remove arsenic from contaminated water. BauxsolT is the name given to the cocktail of minerals prepared by treating caustic bauxite refinery residues with Mg and Ca to produce a substance with a reaction pH of about 8.5, a high acid neutralizing capacity and an excellent ability to trap trace metals, metalloids and some other ionic species. The trapped ions are tightly bound by processes that include; precipitation of low solubility neoformational minerals, isomorphous substitution, solid-state diffusion, and adsorption; it is also an excellent flocculant. Although ordinary BauxsolT has an excellent ability to bind arsenate, and to a lesser extent arsenite, this ability can be further increased for particular water types by using activated BauxsolT or BauxsolT combined with small amounts of other reagents. Field trials conducted at the Gilt Edge Mine, South Dakota, showed that the addition of BauxsolT to highly sulfidic waste rock reduced the arsenic

  4. Control Structure Design of an Innovative Enhanced Biological Nutrient Recovery Activated Sludge System Coupled with a Photobioreactor

    DEFF Research Database (Denmark)

    Valverde Perez, Borja; Fuentes-Martínez, José Manuel; Flores Alsina, Xavier

    2015-01-01

    The TRENS system is a train of biological units designed for resource recovery from wastewater. It is a sequence of a modified enhanced biological phosphorus removal and recovery system (EBP2R) coupled with a photobioreactor (PBR). The bacteria-based system constructs an optimal culture media...... for the downstream algae cultivation. In this work, we present a control strategy to ensure an optimal nutrient balance to feed to the PBR, so the grown algal suspension is suitable for fertigation (irrigation and fertilization of agricultural crops). The system is able to recover up to 75% of the influent load......, while keeping an optimal N-to-P ratio of 16 in the influent to the PBR. The system is tested under different scenarios, where the influent quality is disturbed following a step change. The control system is able to reject most of the disturbances. However, when the P-recovery is limited by the bacteria...

  5. A novel cascade organic Rankine cycle (ORC) system for waste heat recovery of truck diesel engines

    International Nuclear Information System (INIS)

    Chen, Tao; Zhuge, Weilin; Zhang, Yangjun; Zhang, Lei

    2017-01-01

    Highlights: • A confluent cascade expansion ORC (CCE-ORC) system is proposed. • Cyclopentane is considered as the most suitable fluid for this system. • The CCE-ORC system performance under full operating conditions is analyzed. • The BSFC of diesel engine can be reduced by 9.2% with the CCE-ORC system. • Performance comparison of CCE-ORC and dual-loop ORC is conducted. - Abstract: Waste heat recovery (WHR) of engines has attracted increasingly more concerns recently, as it can improve engine thermal efficiency and help truck manufacturers meet the restrictions of CO_2 emission. The organic Rankine cycle (ORC) has been considered as the most potential technology of WHR. To take full advantage of waste heat energy, the waste heat in both exhaust gases and the coolant need to be recovered; however, conventional multi-source ORC systems are too complex for vehicle applications. This paper proposed a confluent cascade expansion ORC (CCE-ORC) system for engine waste heat recovery, which has simpler architecture, a smaller volume and higher efficiency compared with conventional dual-loop ORC systems. Cyclopentane is analyzed to be regarded as the most suitable working fluid for this novel system. A thermodynamic simulation method is established for this system, and off-design performance of main components and the working fluid side pressure drop in the condenser have been taken into consideration. System performance simulations under full engine operating conditions are conducted for the application of this system on a heavy-duty truck diesel engine. Results show that the engine peak thermal efficiency can be improved from 45.3% to 49.5% where the brake specific fuel consumption (BSFC) decreases from 185.6 g/(kW h) to 169.9 g/(kW h). The average BSFC in the frequently operating region can decrease by 9.2% from 187.9 g/(kW h) to 172.2 g/(kW h). Compared with the conventional dual-loop ORC system, the CCE-ORC system can generate 8% more net power, while the

  6. Systemic interpretation and the judicial recovery of the possibility for companies in common

    Directory of Open Access Journals (Sweden)

    Juliana Hinterlang dos Santos Costa

    2015-06-01

    Full Text Available The Company in common was introduced by Brazilian law from the Civil Code of 2002 in its articles 986 to 990. In the previous period it was analyzed from the irregular company name or company and fact. The first was characterized by having written contract, but this was not brought to registration with the competent body and the second when there was no social contract. This study aims to analyze the figure of the Company in common, in the current legal system, from the majority interpretation that does not recognize the right to judicial recovery. It points out that this interpretation ignores: i principles governing the legal system and the economic subsystem; and ii that the current legislation allows their accountability before legal duties in labor spheres, tax, competitive and consumer. Under these main arguments is that they have highlighted the systematic interpretation to defend the right to judicial or extrajudicial recovery. So effective is legal certainty material.    Arraste e solte o arquivo ou link aqui para traduzir o documento ou a página da Web.Arraste e solte o link aqui para traduzir a página da Web.O tipo de arquivo que você soltou não é suportado. Tente outros tipos de arquivo.O tipo de link que você soltou não é suportado. Tente outros tipos de link. 

  7. Diagnosis of vegetation recovery within herbaceous sub-systems in the West African Sahel Region

    Science.gov (United States)

    Anchang, J.; Hanan, N. P.; Prihodko, L.; Sathyachandran, S. K.; Ji, W.; Ross, C. W.

    2017-12-01

    The West African Sahel (WAS) region is an extensive water limited environment that features a delicate balance of herbaceous and woody vegetation sub systems. These play an important role in the cycling of carbon while also supporting the dominant agro-pastoral human activities in the region. Quantifying the temporal trends in vegetation with regard to these two systems is therefore very important in assessing resource sustainability and food security. In water limited areas, rainfall is a primary driver of vegetation productivity and past watershed scale studies in the WAS region have shown that increase in the slope of the productivity-to-rainfall relationship is indicative of increasing cover and density of herbaceous plants. Given the importance of grazing resources to the region, we perform a wall-to-wall pixel based analysis of changing short-term vegetation sensitivity to changing annual rainfall (hereafter referred to as dS) to examine temporal trends in herbaceous vegetation health. Results indicate that 43% of the Sahelian region has experienced changes (P Western and Central Mali and South Western Niger. Positive dS is indicative of herbaceous vegetation recovery, in response to changing management and rainfall conditions that promote long-term herbaceous community recovery following degradation during the 1970-1980s droughts.

  8. Analysis and Design of Timing Recovery Schemes for DMT Systems over Indoor Power-Line Channels

    Directory of Open Access Journals (Sweden)

    Cortés José Antonio

    2007-01-01

    Full Text Available Discrete multitone (DMT modulation is a suitable technique to cope with main impairments of broadband indoor power-line channels: spectral selectivity and cyclic time variations. Due to the high-density constellations employed to achieve the required bit-rates, synchronization issues became an important concern in these scenarios. This paper analyzes the performance of a conventional DMT timing recovery scheme designed for linear time-invariant (LTI channels when employed over indoor power lines. The influence of the channel cyclic short-term variations and the sampling jitter on the system performance is assessed. Bit-rate degradation due to timing errors is evaluated in a set of measured channels. It is shown that this synchronization mechanism limits the system performance in many residential channels. Two improvements are proposed to avoid this end: a new phase error estimator that takes into account the short-term changes in the channel response, and the introduction of notch filters in the timing recovery loop. Simulations confirm that the new scheme eliminates the bit-rate loss in most situations.

  9. Anatomical recovery of the GABAergic system after a complete spinal cord injury in lampreys.

    Science.gov (United States)

    Romaus-Sanjurjo, D; Valle-Maroto, S M; Barreiro-Iglesias, A; Fernández-López, B; Rodicio, M C

    2018-03-15

    Lampreys recover locomotion spontaneously several weeks after a complete spinal cord injury. Dysfunction of the GABAergic system following SCI has been reported in mammalian models. So, it is of great interest to understand how the GABAergic system of lampreys adapts to the post-injury situation and how this relates to spontaneous recovery. The spinal cord of lampreys contains 3 populations of GABAergic neurons and most of the GABAergic innervation of the spinal cord comes from these local cells. GABAB receptors are expressed in the spinal cord of lampreys and they play important roles in the control of locomotion. The aims of the present study were to quantify: 1) the changes in the number of GABAergic neurons and innervation of the spinal cord and 2) the changes in the expression of the gabab receptor subunits b1 and b2 in the spinal cord of the sea lamprey after SCI. We performed complete spinal cord transections at the level of the fifth gill of mature larval lampreys and GABA immunohistochemistry or gabab in situ hybridization experiments. Animals were analysed up to 10 weeks post-lesion (wpl), when behavioural analyses showed that they recovered normal appearing locomotion (stage 6 in the Ayer's scale of locomotor recovery). We observed a significant decrease in the number of GABA-ir cells and fibres 1 h after lesion both rostral and caudal to the lesion site. GABA-ir cell numbers and innervation were recovered to control levels 1 to 2 wpl. At 1, 4 and 10 wpl the expression of gabab1 and gabab2 transcripts was significantly decreased in the spinal cord compared to control un-lesioned animals. This is the first study reporting the quantitative long-term changes in the number of GABAergic cells and fibres and in the expression of gabab receptors in the spinal cord of any vertebrate following a traumatic SCI. Our results show that in lampreys there is a full recovery of the GABAergic neurons and a decrease in the expression of gabab receptors when functional

  10. European Banking Recovery and Resolution Directive: Potential Impacts on European Systemic Important Financial Institutions

    Directory of Open Access Journals (Sweden)

    Clements Akinsoyinu

    2015-09-01

    Full Text Available The great recession heralded in by the subprime mortgage crisis, took a dramatic turn for worse as a result of collapse of the Lehman Brothers bank in September 2008. The crisis deemed to be the most devastating after the Great Depression of 1929, had a debilitating effect on world economies, developing and advanced alike.  The extent of its devastation which  is still being felt in Europe and many parts of the globe reminds us the interconnectedness of financial institutions, particularly those tagged TBTF or SIFIs. Policy makers scrambled to curtail the ugly effect of the crisis by rescuing the SIFIs within their jurisdiction largely through bailout mechanism and provision of implicit guarantee for the debts of failing/failed institutions. As soon as the tide is stemmed, they cast their gaze on new crisis resolution and recovery measures that could rein in systemic risks associated with SIFIs, prevent future crises and reduce the concomitant moral hazards in the current resolution measures. This paper assesses ex ante the potential impact of implementing the new Banking recovery and resolution directives on Europe’s TBTF banksThe great recession heralded in by the subprime mortgage crisis, took a dramatic turn for worse as a result of collapse of the Lehman Brothers bank in September 2008. The crisis deemed to be the most devastating after the Great Depression of 1929, had a debilitating effect on world economies, developing and advanced alike.  The extent of its devastation which  is still being felt in Europe and many parts of the globe reminds us the interconnectedness of financial institutions, particularly those tagged TBTF or SIFIs. Policy makers scrambled to curtail the ugly effect of the crisis by rescuing the SIFIs within their jurisdiction largely through bailout mechanism and provision of implicit guarantee for the debts of failing/failed institutions. As soon as the tide is stemmed, they cast their gaze on new crisis

  11. Performance analysis of a waste heat recovery thermoelectric generation system for automotive application

    International Nuclear Information System (INIS)

    Liu, X.; Deng, Y.D.; Li, Z.; Su, C.Q.

    2015-01-01

    Graphical abstract: A new automotive exhaust-based thermoelectric generator and its “four-TEGs” system are constructed, and the performance characteristics of system are discussed through road test and revolving drum test. - Highlights: • The automotive thermoelectric generator system was constructed and studied. • Road test and revolving drum test were used to measure the output power. • A performance of 201.7 V (open circuit voltage)/944 W obtained. - Abstract: Thermoelectric power generators are one of the promising green energy sources. In this case study, an energy-harvesting system which extracts heat from an automotive exhaust pipe and turns the heat into electricity by using thermoelectric power generators (TEGs) has been constructed. The test bench is developed to analysis the performance of TEG system characteristics, which are undertaken to assess the feasibility of automotive applications. Based on the test bench, a new system called “four-TEGs” system is designed and assembled into prototype vehicle called “Warrior”, through the road test and revolving drum test table, characteristics of the system such as hot-side temperature, cold-side temperature, open circuit voltage and power output are studied, and a maximum power of 944 W was obtained, which completely meets the automotive application. The present study shows the promising potential of using this kind of thermoelectric generator for low-temperature waste heat recovery vehicle

  12. Optimized Design of Thermoelectric Energy Harvesting Systems for Waste Heat Recovery from Exhaust Pipes

    Directory of Open Access Journals (Sweden)

    Marco Nesarajah

    2017-06-01

    Full Text Available With the increasing interest in energy efficiency and resource protection, waste heat recovery processes have gained importance. Thereby, one possibility is the conversion of the heat energy into electrical energy by thermoelectric generators. Here, a thermoelectric energy harvesting system is developed to convert the waste heat from exhaust pipes, which are very often used to transport the heat, e.g., in automobiles, in industrial facilities or in heating systems. That is why a mockup of a heating is built-up, and the developed energy harvesting system is attached. To build-up this system, a model-based development process is used. The setup of the developed energy harvesting system is very flexible to test different variants and an optimized system can be found in order to increase the energy yield for concrete application examples. A corresponding simulation model is also presented, based on previously developed libraries in Modelica®/Dymola®. In the end, it can be shown—with measurement and simulation results—that a thermoelectric energy harvesting system on the exhaust pipe of a heating system delivers extra energy and thus delivers a contribution for a more efficient usage of the inserted primary energy carrier.

  13. Performance measurement, modeling, and evaluation of integrated concurrency control and recovery algorithms in distributed data base systems

    Energy Technology Data Exchange (ETDEWEB)

    Jenq, B.C.

    1986-01-01

    The performance evaluation of integrated concurrency-control and recovery mechanisms for distributed data base systems is studied using a distributed testbed system. In addition, a queueing network model was developed to analyze the two phase locking scheme in the distributed testbed system. The combination of testbed measurement and analytical modeling provides an effective tool for understanding the performance of integrated concurrency control and recovery algorithms in distributed database systems. The design and implementation of the distributed testbed system, CARAT, are presented. The concurrency control and recovery algorithms implemented in CARAT include: a two phase locking scheme with distributed deadlock detection, a distributed version of optimistic approach, before-image and after-image journaling mechanisms for transaction recovery, and a two-phase commit protocol. Many performance measurements were conducted using a variety of workloads. A queueing network model is developed to analyze the performance of the CARAT system using the two-phase locking scheme with before-image journaling. The combination of testbed measurements and analytical modeling provides significant improvements in understanding the performance impacts of the concurrency control and recovery algorithms in distributed database systems.

  14. The Advanced Exploration Systems Water Recovery Project: Innovation on 2 Fronts

    Science.gov (United States)

    Sarguisingh, Miriam M.; Neumeyer, Derek; Shull, Sarah

    2012-01-01

    As NASA looks forward to sending humans farther away from Earth, we will have to develop a transportation architecture that is highly reliable and that can sustain life for long durations without the benefit of Earth s proximity for continuous resupply or even operational guidance. NASA has consistently been challenged with performing great feats of innovation, but particularly in this time of economic stress, we are challenged to go farther with less. The Advanced Exploration Systems (AES) projects were implemented to address both of these needs by not only developing innovative technologies, but by incorporating innovative management styles and processes that foster the needed technical innovation given a small amount of resources. This presentation explains how the AES Water Recovery Project is exhibiting innovation on both fronts; technical and process. The AES Water Recovery Project (WRP) is actively engineering innovative technologies in order to maximize the efficiency of water recovery. The development of reliable, energy-efficient, and low-mass spacecraft systems to provide environmental control and life support (ECLS) is critical to enable long-duration human missions outside of low-Earth orbit. Recycling of life support consumables is necessary to reduce resupply mass and provide for vehicle autonomy. To address this, the WRP is working on a rotary distiller that has shown enhanced performance over the state-of-the-art (SOA). Additionally, the WRP is looking at innovative ways to address issues present in the state-of-the-art (SOA) systems pertaining to toxicity and calcium scale buildup. As an AES project, the WRP has a more streamlined Skunk Works like approach to technology development intended to reduce overhead but achieve a more refined end product. The project has incorporated key partnerships between NASA centers as well as between NASA and industry. A minimal project management style has been implemented such that risks are managed and

  15. Understanding Total Hip Replacement Recovery towards the Design of a Context-Aware Systems

    NARCIS (Netherlands)

    Jimenez Garcia, Juan

    2011-01-01

    Total Hip Replacement (THR) is a common procedure to improve the mobility of elderly with osteoarthritis. Presently information about the recovery process after discharge is unclear. As consequence patients and physiotherapists face uncertainties to follow an adequate trajectory for recovery.

  16. A Compact, Efficient Pyrolysis/Oxidation System for Solid Waste Resource Recovery in Space, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — Pyrolysis processing can be used in near term missions for volume reduction, water recovery (drying), stabilization, and enhanced water and oxygen recovery through...

  17. Evaluation of a flue gas driven open absorption system for heat and water recovery from fossil fuel boilers

    International Nuclear Information System (INIS)

    Wang, Zhenying; Zhang, Xiaoyue; Li, Zhen

    2016-01-01

    Highlights: • Flue gas driven open absorption system that efficiently recovers total heat. • Efficient heat and water recovery for various kinds of fossil fuel boilers. • Heat and water recovery efficiencies increase with moisture content of flue gas. • Temperature requirements for district heat supply and domestic hot water were met. • Experimental system surpasses conventional condensing system in total heat recovery. - Abstract: This paper presents an open absorption system for total heat recovery from fossil fuel boilers using the high temperature flue gas as the regeneration heat source. In this system, liquid desiccant serves as the recycling medium, which absorbs waste heat and moisture contained in the low temperature flue gas in the packed tower and then regenerates in the regenerator by the high temperature flue gas. Water vapor generated in the regenerator gets condensed after releasing heat to the heating water system and the condensing water also gets recycled. The return water collects heat from the solution water heat exchanger, the flue gas water heat exchanger and the condenser respectively and is then used for district heating. Driven by the vapor pressure difference between high humidity flue gas and the liquid desiccant, the heat recovery efficiency of the system is not limited by the dew point of the flue gas, enabling a warmer water to be heated up than the conventional condensing boiler. The performance of this system was analyzed theoretically and experimentally and the results showed that the system operated well for both district heat supply and domestic hot water supply. The system efficiency increased with the moisture content of flue gas and the total heat recovery was about 8.5%, 17.2%, 21.2%, and 9.2% higher than the conventional condensing system in the case of coal fired boiler, fuel oil boiler, natural gas boiler, and coke oven gas boiler, respectively.

  18. Cold storage condensation heat recovery system with a novel composite phase change material

    International Nuclear Information System (INIS)

    Xia, Mingzhu; Yuan, Yanping; Zhao, Xudong; Cao, Xiaoling; Tang, Zhonghua

    2016-01-01

    Highlights: • Cold storage condensation heat recovery system using PCM was proposed. • CW with a phase change temperature of nearly 80 °C was selected as the potential PCM. • The optimal mass ratio between the CW and EG was 10:1. • The thermal and physical performances of the CW/EG were investigated. • The thermal reliability was demonstrated by 1000 cycles. - Abstract: Using condensation heat from cold storage refrigeration systems to provide heat for domestic hot water preparation and industrial hot water supply promotes energy conservation. However, few studies have investigated cold storage condensation heat recovery using phase change materials (PCMs). In this study, a cold storage condensation heat recovery system that uses PCMs has been designed and analysed. According to the principle of energy cascade recycling, different operation modes could be effectively switched to recycle condensation heat. Furthermore, a novel and suitable phase change composite material is developed for cold storage condensation heat recovery, which has a relatively large latent heat, high thermal conductivity, and an appropriate phase change temperature (i.e. 80 °C). With carnauba wax (CW) as the PCM and expanded graphite (EG) as the additive, a composite was developed with an optimal mass ratio of CW:EG = 10:1. The thermal and physical properties and the interior structure of the composite were then investigated using a scanning electron microscope (SEM), thermal constants analyser (Hot Disk), differential scanning calorimeter (DSC), and Fourier transform infrared spectrometer (FT-IR). Furthermore, experiments on the melting and solidification processes and accelerated thermal cycling were also conducted. It was found that at the optimal mass ratio of 10:1, the temperatures of the CW/EG composite in the melting and solidification processes were 81.98 °C and 80.43 °C, respectively, while the corresponding latent heats were 150.9 J/g and 142.6 J/g, respectively

  19. Heat recovery properties from fuel cell system for telecommunications use; Tsushin`yo nenryo denchi system ni okeru hainetsu kaishu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Ishizawa, M.; Iida, S.; Abe, I.; Yamamoto, M. [NTT Integrated Information and Energy Systems Laboratories, Tokyo (Japan)

    1997-08-20

    NTT is developing a phosphoric-acid fuel-cell energy system for telecommunication co-generation systems to reduce energy costs and help preserve the environment. Fuel cells are used to provide electrical power to telecommunication equipment and the heat energy that is generated is used by the absorption refrigerators to cool the telecommunication rooms throughout the year. We field-tested this fuel-cell energy system in a telephone office. Two heat recovery methods were applied in the test: one uses direct steam heat recovery from fuel-cell stack coolant to keep the heat recovery temperature high and to avoid requiring a heat exchanger for the recovery; the other uses heat recovery from the reformer exhaust gas that is directly in contact with the heat recovery water to recover heat more economically. Our field tests confirmed that the average efficiency of heat recovery from fuel-cell stack coolant is 16%, and from the reformer exhaust gas is 9% under 80-kW continuous operation. Maximum total efficiency including electrical power efficiency was confirmed to be about 73% under the condition of 100-kW and an S/C ratio of 2.5 in the winter period: heat recovery from the fuel-cell stack coolant was 23%, from the reformer exhaust gas was 10%, and from electrical conversion was about 40%. 9 refs., 12 figs., 1 tab.

  20. Investigation of austenitic alloys for advanced heat recovery and hot-gas cleanup systems

    Energy Technology Data Exchange (ETDEWEB)

    Swindeman, R.W. [Oak Ridge National Lab., TN (United States)

    1997-12-01

    Materials properties were collected for the design and construction of structural components for use in advanced heat recovery and hot gas cleanup systems. Alloys systems included 9Cr-1Mo-V steel, modified 316 stainless steel, modified type 310 stainless steel, modified 20Cr-25Ni-Nb stainless steel, and modified alloy 800. Experimental work was undertaken to expand the databases for potentially useful alloys. Types of testing included creep, stress-rupture, creep-crack growth, fatigue, and post-exposure short-time tensile tests. Because of the interest in relatively inexpensive alloys for service at 700 C and higher, research emphasis was placed on a modified type 310 stainless steel and a modified 20Cr-25Ni-Nb stainless steel. Both steels were found to have useful strength to 925 C with good weldability and ductility.

  1. Improvement of CaO-based sorbent performance for CO{sub 2} looping cycles

    Energy Technology Data Exchange (ETDEWEB)

    Vasilije Manovic; Edward J. Anthony [CANMET Energy Technology Centre-Ottawa, Ottawa, ON (Canada)

    2009-07-01

    This paper presents research on CO{sub 2} capture by lime-based looping cycles. This is a new and promising technology that may help in mitigation of global warming and climate change caused primarily by the use of fossil fuels. The intensity of the anticipated changes urgently requires solutions such as the developing technologies for CO{sub 2} capture, especially those based on CaO looping cycles. This technology is at the pilot plant demonstration stage and there are still significant challenges that require solutions. The technology is based on a dual fluidized bed reactor which contains a carbonator - a unit for CO{sub 2} capture, and a calciner - a unit for CaO regeneration. The major technology components are well known from other technologies and easily applicable. However, even though CaO is a very good candidate as a solid CO{sub 2} carrier, its performance in a practical system still has significant limitations. Thus, research on CaO performance is critical and this paper discusses some of the more important problems and potential solutions that are being examined at CETC-O. To date, the most promising methods were reactivation of spent sorbent by steam, thermal pretreatment of sorbent, and doping, most likely with Al{sub 2}O{sub 3}. The combination of these methods, including pelletization, should provide us with enhanced sorbent performance. 75 refs., 19 figs.

  2. The role of graphene-based sorbents in modern sample preparation techniques.

    Science.gov (United States)

    de Toffoli, Ana Lúcia; Maciel, Edvaldo Vasconcelos Soares; Fumes, Bruno Henrique; Lanças, Fernando Mauro

    2018-01-01

    The application of graphene-based sorbents in sample preparation techniques has increased significantly since 2011. These materials have good physicochemical properties to be used as sorbent and have shown excellent results in different sample preparation techniques. Graphene and its precursor graphene oxide have been considered to be good candidates to improve the extraction and concentration of different classes of target compounds (e.g., parabens, polycyclic aromatic hydrocarbon, pyrethroids, triazines, and so on) present in complex matrices. Its applications have been employed during the analysis of different matrices (e.g., environmental, biological and food). In this review, we highlight the most important characteristics of graphene-based material, their properties, synthesis routes, and the most important applications in both off-line and on-line sample preparation techniques. The discussion of the off-line approaches includes methods derived from conventional solid-phase extraction focusing on the miniaturized magnetic and dispersive modes. The modes of microextraction techniques called stir bar sorptive extraction, solid phase microextraction, and microextraction by packed sorbent are discussed. The on-line approaches focus on the use of graphene-based material mainly in on-line solid phase extraction, its variation called in-tube solid-phase microextraction, and on-line microdialysis systems. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Development of an end-of-life vehicle recovery model using system dynamics and future research needs

    Science.gov (United States)

    Mohamad-Ali, N.; Ghazilla, R. A. R.; Abdul-Rashid, S. H.; Sakundarini, N.; Ahmad-Yazid, A.; Stephenie, L.

    2017-06-01

    The implementation of end-of-life vehicle (ELV) recovery policy in Malaysia has led vehicle manufacturers to look at different ways to improve design and development of vehicles. Nowadays, it is crucial to incorporate end-of-life (EOL) design strategies into the vehicle design in order to enhance the effectiveness of the ELV recovery network. Although recent studies have shown that product design has a significant effect on the product recovery rate, there is a lack of studies on how EOL design strategies affects the effectiveness of ELV recovery, particularly when there are dynamic changes in the behaviour of the product recovery network. Thus, in this study, we developed a preliminary model based on the system dynamics approach in order to predict the effectiveness of ELV recovery in response to dynamic changes of various factors (including EOL design strategies) in the business environment. We developed this model based on preliminary data that we had gathered from unstructured interviews with the key stakeholders of ELV management in Malaysia. We believe that our model will greatly benefit product designers in incorporating the appropriate EOL design strategies in order to boost ELV recovery effectiveness in Malaysia.

  4. Performance of an electrothermal swing adsorption system with postdesorption liquefaction for organic gas capture and recovery.

    Science.gov (United States)

    Mallouk, Kaitlin E; Rood, Mark J

    2013-07-02

    The use of adsorption on activated carbon fiber cloth (ACFC) followed by electrothermal swing adsorption (ESA) and postdesorption pressure and temperature control allows organic gases with boiling points below 0 °C to be captured from air streams and recovered as liquids. This technology has the potential to be a more sustainable abatement technique when compared to thermal oxidation. In this paper, we determine the process performance and energy requirements of a gas recovery system (GRS) using ACFC-ESA for three adsorbates with relative pressures between 8.3 × 10(-5) and 3.4 × 10(-3) and boiling points as low as -26.3 °C. The GRS is able to capture > 99% of the organic gas from the feed air stream, which is comparable to destruction efficiencies for thermal oxidizers. The energy used per liquid mole recovered ranges from 920 to 52,000 kJ/mol and is a function of relative pressure of the adsorbate in the feed gas. Quantifying the performance of the bench-scale gas recovery system in terms of its ability to remove organic gases from the adsorption stream and the energy required to liquefy the recovered organic gases is a critical step in developing new technologies to allow manufacturing to occur in a more sustainable manner. To our knowledge, this is the first time an ACFC-ESA system has been used to capture, recover, and liquefy organic compounds with vapor pressures as low as 8.3 × 10(-5) and the first time such a system has been analyzed for process performance and energy consumption.

  5. Parametric analysis of a dual loop Organic Rankine Cycle (ORC) system for engine waste heat recovery

    International Nuclear Information System (INIS)

    Song, Jian; Gu, Chun-wei

    2015-01-01

    Highlights: • A dual loop ORC system is designed for engine waste heat recovery. • The two loops are coupled via a shared heat exchanger. • The influence of the HT loop condensation parameters on the LT loop is evaluated. • Pinch point locations determine the thermal parameters of the LT loop. - Abstract: This paper presents a dual loop Organic Rankine Cycle (ORC) system consisting of a high temperature (HT) loop and a low temperature (LT) loop for engine waste heat recovery. The HT loop recovers the waste heat of the engine exhaust gas, and the LT loop recovers that of the jacket cooling water in addition to the residual heat of the HT loop. The two loops are coupled via a shared heat exchanger, which means that the condenser of the HT loop is the evaporator of the LT loop as well. Cyclohexane, benzene and toluene are selected as the working fluids of the HT loop. Different condensation temperatures of the HT loop are set to maintain the condensation pressure slightly higher than the atmosphere pressure. R123, R236fa and R245fa are chosen for the LT loop. Parametric analysis is conducted to evaluate the influence of the HT loop condensation temperature and the residual heat load on the LT loop. The simulation results reveal that under different condensation conditions of the HT loop, the pinch point of the LT loop appears at different locations, resulting in different evaporation temperatures and other thermal parameters. With cyclohexane for the HT loop and R245fa for the LT loop, the maximum net power output of the dual loop ORC system reaches 111.2 kW. Since the original power output of the engine is 996 kW, the additional power generated by the dual loop ORC system can increase the engine power by 11.2%.

  6. A Simple Vortex-Assisted Magnetic Dispersive Solid Phase Microextraction System for Preconcentration and Separation of Triazine Herbicides from Environmental Water and Vegetable Samples Using Fe₃O₄@MIL-100(Fe) Sorbent.

    Science.gov (United States)

    Nasrollahpour, Atefe; Moradi, Seyyed Ershad

    2018-04-04

    A vortex-assisted magnetic dispersive solid phase microextraction coupled with high-performance liquid chromatography has been developed for the extraction and determination of triazine herbicides by using magnetic metal organic frameworks [Fe₃O₄@MIL-100(Fe)] in environmental water and vegetable samples. The Fe₃O₄@MIL-100(Fe) composite has been characterized by using X-ray diffraction spectroscopy, tunneling electron microscopy, thermogravimetric measurement, and Brunauer-Emmett-Teller analysis. The method is based on the sorption of triazine herbicides on Fe₃O₄@MIL-100(Fe) because of the complex formation between iron oxide nanoparticles and triazine herbicides beside π-π interactions between organic parts of Fe₃O₄@MIL-100(Fe) and triazine herbicides. The experimental parameters for the preconcentration of triazine herbicides, such as the type and volume of the eluent, pH, time of the sorption and desorption, and the amount of the sorbent, were optimized. Under the optimized conditions, the method was linear over the concentration range of 0.0061 to 70 ng/mL for each triazine herbicide, and the correlation coefficients ranged from 0.9988 to 0.9997. The limit of detection of the method at a signal-to-noise ratio of 3 was 2.0 to 5.3 ng/mL. The relative standard deviations for inter- and intraday assays were in the range of 5.8 to 10.2% and 3.8 to 6.3%, respectively.

  7. Development and application of charcoal sorbents for cryopumping fusion devices

    Energy Technology Data Exchange (ETDEWEB)

    Sedgley, D.W. (Grumman Corp., Bethpage, NY (USA). Space Systems Div.)

    1989-06-01

    Progress has been made in defining the capabilities of charcoal as the most promising absorbent to be used in cryopumps for fusion power application. The capabilities of alternative methods of cryopumping helium have been examined in a literature survey and by test, and the results are described here. Considerations include pumping speed, capacity to accumulate pumped gas, ease of reconditioning, use of alternative materials and tolerance to the fusion environment. Vacuum pumps for future fusion devices must handle large quantities of helium/hydrogen isotopes and other impurities. Cryopumps or turbomolecular pumps have demonstrated the capability on a small scale, and each has an important advantage: TMPs do not accumulate gases; cryopumps can separate helium from other effluents. This paper includes a review of a method for selecting charcoals for helium cryopumping, testing of a continuously operating cryopump system, and definition of a design that is based on the requirements of the Next European Torus. Tritium limits are satisfied. The pump design incorporates the charcoal sorbent system that has been recently developed and is based on a reasonable extrapolation of current state-of-the-art. Evaluation of alternative methods of separating helium and other gases led to selection of a movable barrier as the preferred solution. (orig.).

  8. Tunable polymeric sorbent materials for fractionation of model naphthenates.

    Science.gov (United States)

    Mohamed, Mohamed H; Wilson, Lee D; Headley, John V

    2013-04-04

    The sorption properties are reported for several examples of single-component carboxylic acids representing naphthenic acids (NAs) with β-cyclodextrin (β-CD) based polyurethane sorbents. Seven single-component examples of NAs were chosen with variable z values, carbon number, and chemical structure as follows: 2-hexyldecanoic acid (z = 0 and C = 16; S1), n-caprylic acid (z = 0 and C = 8; S2), trans-4-pentylcyclohexanecarboxylic acid (z = -2 and C = 12; S3), 4-methylcyclohexanecarboxylic acid (z = -2 and C = 8; S4), dicyclohexylacetic acid (z = -4; C = 14; S5), 4-pentylbicyclo[2.2.2]octane-1-carboxylic acid (z = -4; C = 14; S6), and lithocholic acid (z = -6; C = 24; S7). The copolymer sorbents were synthesized at three relative β-CD:diisocyanate mole ratios (i.e., 1:1, 1:2, and 1:3) using 4,4'-dicyclohexylmethane diisocyanate (CDI) and 4,4'-diphenylmethane diisocyanate (MDI). The sorption properties of the copolymer sorbents were characterized using equilibrium sorption isotherms in aqueous solution at pH 9.00 with electrospray ionization mass spectrometry. The equilibrium fraction of the unbound carboxylate anions was monitored in the aqueous phase. The sorption properties of the copolymer sorbents (i.e., Qm) were obtained from the Sips isotherm model. The Qm values generally decrease as the number of accessible β-CD inclusion sites in the copolymer framework decreases. The chemical structure of the adsorbates played an important role in their relative uptake, as evidenced by the adsorbate lipophilic surface area (LSA) and the involvement of hydrophobic effects. The copolymers exhibit molecular selective sorption of the single-component carboxylates in mixtures which suggests their application as sorbents for fractionation of mixtures of NAs. By comparison, granular activated carbon (GAC) and chitosan sorbents did not exhibit any significant molecular selective sorption relative to the copolymer materials; however, evidence of variable sorption capacity was

  9. Copper Recovery from Polluted Soils Using Acidic Washing and Bioelectrochemical Systems

    Directory of Open Access Journals (Sweden)

    Karin Karlfeldt Fedje

    2015-07-01

    Full Text Available Excavation followed by landfilling is the most common method for treating soils contaminated by metals. However, as this solution is not sustainable, alternative techniques are required. Chemical soil washing is one such alternative. The aim of this experimental lab-scale study is to develop a remediation and metal recovery method for Cu contaminated sites. The method is based on the washing of soil or ash (combusted soil/bark with acidic waste liquids followed by electrolytic Cu recovery by means of bioelectrochemical systems (BES. The results demonstrate that a one- or two-step acidic leaching process followed by water washing removes >80 wt. % of the Cu. Copper with 99.7–99.9 wt. % purity was recovered from the acidic leachates using BES. In all experiments, electrical power was generated during the reduction of Cu. This clearly indicates that Cu can also be recovered from dilute solutions. Additionally, the method has the potential to wash co-pollutants such as polycyclic aromatic hydrocarbons (PAHs and oxy-PAHs.

  10. Potential for nutrient recovery and biogas production from blackwater, food waste and greywater in urban source control systems.

    Science.gov (United States)

    Kjerstadius, H; Haghighatafshar, S; Davidsson, Å

    2015-01-01

    In the last decades, the focus on waste and wastewater treatment systems has shifted towards increased recovery of energy and nutrients. Separation of urban food waste (FW) and domestic wastewaters using source control systems could aid this increase; however, their effect on overall sustainability is unknown. To obtain indicators for sustainability assessments, five urban systems for collection, transport, treatment and nutrient recovery from blackwater, greywater and FW were investigated using data from implementations in Sweden or northern Europe. The systems were evaluated against their potential for biogas production and nutrient recovery by the use of mass balances for organic material, nutrients and metals over the system components. The resulting indicators are presented in units suitable for use in future sustainability studies or life-cycle assessment of urban waste and wastewater systems. The indicators show that source control systems have the potential to increase biogas production by more than 70% compared with a conventional system and give a high recovery of phosphorus and nitrogen as biofertilizer. The total potential increase in gross energy equivalence for source control systems was 20-100%; the greatest increase shown is for vacuum-based systems.

  11. Performance Analysis of Thermoelectric Based Automotive Waste Heat Recovery System with Nanofluid Coolant

    Directory of Open Access Journals (Sweden)

    Zhi Li

    2017-09-01

    Full Text Available Output performance of a thermoelectric-based automotive waste heat recovery system with a nanofluid coolant is analyzed in this study. Comparison between Cu-Ethylene glycol (Cu-EG nanofluid coolant and ethylene glycol with water (EG-W coolant under equal mass flow rate indicates that Cu-EG nanofluid as a coolant can effectively improve power output and thermoelectric conversion efficiency for the system. Power output enhancement for a 3% concentration of nanofluid is 2.5–8 W (12.65–13.95% compared to EG-Water when inlet temperature of exhaust varies within 500–710 K. The increase of nanofluid concentration within a realizable range (6% has positive effect on output performance of the system. Study on the relationship between total area of thermoelectric modules (TEMs and output performance of the system indicates that optimal total area of TEMs exists for maximizing output performance of the system. Cu-EG nanofluid as coolant can decrease optimal total area of TEMs compared with EG-W, which will bring significant advantages for the optimization and arrangement of TEMs whether the system space is sufficient or not. Moreover, power output enhancement under Cu-EG nanofluid coolant is larger than that of EG-W coolant due to the increase of hot side heat transfer coefficient of TEMs.

  12. A review of concentrated photovoltaic-thermal (CPVT) hybrid solar systems with waste heat recovery (WHR)

    Institute of Scientific and Technical Information of China (English)

    Xing Ju; Chao Xu; Zhirong Liao; Xiaoze Du; Gaosheng Wei; Zhifeng Wang; Yongping Yang

    2017-01-01

    In conventional photovoltaic (PV) systems,a large portion of solar energy is dissipated as waste heat since the generating efficiency is usually less than 30%.As the dissipated heat can be recovered for various applications,the wasted heat recovery concentrator PV/thermal (WHR CPVT) hybrid systems have been developed.They can provide both electricity and usable heat by combining thermal systems with concentrator PV (CPV) module,which dramatically improves the overall conversion efficiency of solar energy.This paper systematically and comprehensively reviews the research and development ofWHR CPVT systems.WHR CPVT systems with innovative design configurations,different theoretical evaluation models and experimental test processes for several implementations are presented in an integrated manner.We aim to provide a global point of view on the research trends,market potential,technical obstacles,and the future work which is required in the development of WHR CPVT technology.Possibly,it will offer a generic guide to the investigators who are interested in the study of WHR CPVT systems.

  13. Dynamic Modeling of Process Technologies for Closed-Loop Water Recovery Systems

    Science.gov (United States)

    Allada, Rama Kumar; Lange, Kevin E.; Anderson, Molly S.

    2012-01-01

    Detailed chemical process simulations are a useful tool in designing and optimizing complex systems and architectures for human life support. Dynamic and steady-state models of these systems help contrast the interactions of various operating parameters and hardware designs, which become extremely useful in trade-study analyses. NASA s Exploration Life Support technology development project recently made use of such models to compliment a series of tests on different waste water distillation systems. This paper presents dynamic simulations of chemical process for primary processor technologies including: the Cascade Distillation System (CDS), the Vapor Compression Distillation (VCD) system, the Wiped-Film Rotating Disk (WFRD), and post-distillation water polishing processes such as the Volatiles Removal Assembly (VRA). These dynamic models were developed using the Aspen Custom Modeler (Registered TradeMark) and Aspen Plus(Registered TradeMark) process simulation tools. The results expand upon previous work for water recovery technology models and emphasize dynamic process modeling and results. The paper discusses system design, modeling details, and model results for each technology and presents some comparisons between the model results and available test data. Following these initial comparisons, some general conclusions and forward work are discussed.

  14. Dynamic Modeling of Process Technologies for Closed-Loop Water Recovery Systems

    Science.gov (United States)

    Allada, Rama Kumar; Lange, Kevin; Anderson, Molly

    2011-01-01

    Detailed chemical process simulations are a useful tool in designing and optimizing complex systems and architectures for human life support. Dynamic and steady-state models of these systems help contrast the interactions of various operating parameters and hardware designs, which become extremely useful in trade-study analyses. NASA s Exploration Life Support technology development project recently made use of such models to compliment a series of tests on different waste water distillation systems. This paper presents dynamic simulations of chemical process for primary processor technologies including: the Cascade Distillation System (CDS), the Vapor Compression Distillation (VCD) system, the Wiped-Film Rotating Disk (WFRD), and post-distillation water polishing processes such as the Volatiles Removal Assembly (VRA) that were developed using the Aspen Custom Modeler and Aspen Plus process simulation tools. The results expand upon previous work for water recovery technology models and emphasize dynamic process modeling and results. The paper discusses system design, modeling details, and model results for each technology and presents some comparisons between the model results and available test data. Following these initial comparisons, some general conclusions and forward work are discussed.

  15. A feasibility analysis of waste heat recovery systems for marine applications

    International Nuclear Information System (INIS)

    Baldi, Francesco; Gabrielii, Cecilia

    2015-01-01

    The shipping sector is today facing challenges which require a larger focus on energy efficiency and fuel consumption. In this article, a methodology for performing a feasibility analysis of the installation of a WHR (waste heat recovery) system on a vessel is described and applied to a case study vessel. The method proposes to calculate the amount of energy and exergy available for the WHR systems and to compare it with the propulsion and auxiliary power needs based on available data for ship operational profile. The expected exergy efficiency of the WHR system is used as an independent variable, thus allowing estimating the expected fuel savings when a detailed design of the WHR system is not yet available. The use of the proposed method can guide in the choice of the installation depending on the requirements of the owner in terms of payback time and capital investment. The results of the application of this method to the case study ship suggest that fuel savings of 5%–15% can realistically be expected, depending on the sources of waste heat used and on the expected efficiency of the WHR system. - Highlights: • Method for simple estimation of benefits from WHR on ships. • High detail account of ship operational profile is included in the analysis. • Detailed knowledge of the WHR system is not required; its exergy efficiency is used as independent variable

  16. Total Energy Recovery System for Agribusiness: Lake County study. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Fogleman, S.F.; Fisher, L.A.; Black, A.R.

    1978-04-01

    A brief summary is given of the results of a previously reported study designed to evaluate the costs and viability of combined thermodynamic and biologic cycles in a system known as the Total Energy Recovery System for Agribusiness (TERSA). This conceptual system involved the combined geothermally assisted activities of greenhouse crop and mushroom growing, fish farming, and biogas generation in an integrated biologic system such that the waste or by-products of each subsystem cycle were recovered to service input needs of companion cycles. An updated direct use geothermal system based on TERSA that is viable for implementation in Lake County is presented. Particular consideration is given to: location of geothermal resources, availability of land and irrigation quality water, compatibility of the specific direct use geothermal activities with adjacent and local uses. Private interest and opposition, and institutional factors as identified. Factors relevant to local TERSA implementation are discussed, followed by sites considered, selection criteria, site slection, and the modified system resulting. Particular attention is paid to attempt to make clear the process followed in applying this conceptual design to the specific task of realistic local implementation. Previous publications on geothermal energy and Lake County are referenced where specific details outside the scope of this study may be found. (JGB)

  17. Re-engineering the urban drainage system for resource recovery and protection of drinking water supplies.

    Science.gov (United States)

    Gumbo, B

    2000-01-01

    The Harare metropolis in Zimbabwe, extending upstream from Manyame Dam in the Upper Manyame River Basin, consists of the City of Harare and its satellite towns: Chitungwiza, Norton, Epworth and Ruwa. The existing urban drainage system is typically a single-use-mixing system: water is used and discharged to "waste", excreta are flushed to sewers and eventually, after "treatment", the effluent is discharged to a drinking water supply source. Polluted urban storm water is evacuated as fast as possible. This system not only ignores the substantial value in "waste" materials, but it also exports problems to downstream communities and to vulnerable fresh-water sources. The question is how can the harare metropolis urban drainage system, which is complex and has evolved over time, be rearranged to achieve sustainability (i.e. water conservation, pollution prevention at source, protection of the vulnerable drinking water sources and recovery of valuable materials)? This paper reviews current concepts regarding the future development of the urban drainage system in line with the new vision of "Sustainable Cities of the Future". The Harare Metropolis in Zimbabwe is taken as a case, and philosophical options for re-engineering the drainage system are discussed.

  18. Water Recovery System Design to Accommodate Dormant Periods for Manned Missions

    Science.gov (United States)

    Tabb, David; Carter, Layne

    2015-01-01

    Future manned missions beyond lower Earth orbit may include intermittent periods of extended dormancy. Under the NASA Advanced Exploration System (AES) project, NASA personnel evaluated the viability of the ISS Water Recovery System (WRS) to support such a mission. The mission requirement includes the capability for life support systems to support crew activity, followed by a dormant period of up to one year, and subsequently for the life support systems to come back online for additional crewed missions. Dormancy could be a critical issue due to concerns with microbial growth or chemical degradation that might prevent water systems from operating properly when the crewed mission began. As such, it is critical that the water systems be designed to accommodate this dormant period. This paper details the results of this evaluation, which include identification of dormancy issues, results of testing performed to assess microbial stability of pretreated urine during dormancy periods, and concepts for updating to the WRS architecture and operational concepts that will enable the ISS WRS to support the dormancy requirement.

  19. Development of Novel Sorbents for Uranium Extraction from Seawater

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Wenbin [Univ. of Chicago, IL (United States); Taylor-Pashow, Kathryn [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-01-08

    As the uranium resource in terrestrial ores is limited, it is difficult to ensure a long-term sustainable nuclear energy technology. The oceans contain approximately 4.5 billion tons of uranium, which is one thousand times the amount of uranium in terrestrial ores. Development of technologies to recover the uranium from seawater would greatly improve the uranium resource availability, sustaining the fuel supply for nuclear energy. Several methods have been previously evaluated including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons such as cost effectiveness, long term stability, and selectivity. Recent research has focused on the amidoxime functional group as a promising candidate for uranium sorption. Polymer beads and fibers have been functionalized with amidoxime functional groups, and uranium adsorption capacities as high as 1.5 g U/kg adsorbent have recently been reported with these types of materials. As uranium concentration in seawater is only ~3 ppb, great improvements to uranium collection systems must be made in order to make uranium extraction from seawater economically feasible. This proposed research intends to develop transformative technologies for economic uranium extraction from seawater. The Lin group will design advanced porous supports by taking advantage of recent breakthroughs in nanoscience and nanotechnology and incorporate high densities of well-designed chelators into such nanoporous supports to allow selective and efficient binding of uranyl ions from seawater. Several classes of nanoporous materials, including mesoporous silica nanoparticles (MSNs), mesoporous carbon nanoparticles (MCNs), meta-organic frameworks (MOFs), and covalent-organic frameworks (COFs), will be synthesized. Selective uranium-binding liagnds such as amidoxime will be incorporated into the nanoporous materials to afford a new generation of sorbent materials that will be

  20. Development of Novel Sorbents for Uranium Extraction from Seawater

    International Nuclear Information System (INIS)

    Lin, Wenbin; Taylor-Pashow, Kathryn

    2014-01-01

    As the uranium resource in terrestrial ores is limited, it is difficult to ensure a long-term sustainable nuclear energy technology. The oceans contain approximately 4.5 billion tons of uranium, which is one thousand times the amount of uranium in terrestrial ores. Development of technologies to recover the uranium from seawater would greatly improve the uranium resource availability, sustaining the fuel supply for nuclear energy. Several methods have been previously evaluated including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons such as cost effectiveness, long term stability, and selectivity. Recent research has focused on the amidoxime functional group as a promising candidate for uranium sorption. Polymer beads and fibers have been functionalized with amidoxime functional groups, and uranium adsorption capacities as high as 1.5 g U/kg adsorbent have recently been reported with these types of materials. As uranium concentration in seawater is only ~3 ppb, great improvements to uranium collection systems must be made in order to make uranium extraction from seawater economically feasible. This proposed research intends to develop transformative technologies for economic uranium extraction from seawater. The Lin group will design advanced porous supports by taking advantage of recent breakthroughs in nanoscience and nanotechnology and incorporate high densities of well-designed chelators into such nanoporous supports to allow selective and efficient binding of uranyl ions from seawater. Several classes of nanoporous materials, including mesoporous silica nanoparticles (MSNs), mesoporous carbon nanoparticles (MCNs), meta-organic frameworks (MOFs), and covalent-organic frameworks (COFs), will be synthesized. Selective uranium-binding liagnds such as amidoxime will be incorporated into the nanoporous materials to afford a new generation of sorbent materials that will be

  1. Optimal Recovery Trajectories for Automatic Ground Collision Avoidance Systems (Auto GCAS)

    Science.gov (United States)

    Suplisson, Angela W.

    The US Air Force recently fielded the F-16 Automatic Ground Collision Avoidance System (Auto GCAS). This system meets the operational requirements of being both aggressive and timely, meaning that extremely agile avoidance maneuvers will be executed at the last second to avoid the ground. This small window of automatic operation maneuvering in close proximity to the ground makes the problem challenging. There currently exists no similar Auto GCAS for manned military 'heavy' aircraft with lower climb performance such as transport, tanker, or bomber aircraft. The F-16 Auto GCAS recovery is a single pre-planned roll to wings-level and 5-g pull-up which is very effective for fighters due to their high g and climb performance, but it is not suitable for military heavy aircraft. This research proposes a new optimal control approach to the ground collision avoidance problem for heavy aircraft by mapping the aggressive and timely requirements of the automatic recovery to the optimal control formulation which includes lateral maneuvers around terrain. This novel mapping creates two ways to pose the optimal control problem for Auto GCAS; one as a Max Distance with a Timely Trigger formulation and the other as a Min Control with an Aggressive Trigger formulation. Further, the optimal path and optimal control admitted by these two formulations are demonstrated to be equivalent at the point the automatic recovery is initiated for the simplified 2-D case. The Min Control formulation was demonstrated to have faster computational speed and was chosen for the 3-D case. Results are presented for representative heavy aircraft scenarios against 3-D digital terrain. The Min Control formulation was then compared to a Multi-Trajectory Auto GCAS with five pre-planned maneuvers. Metrics were developed to quantify the improvement from using an optimal approach versus the pre-planned maneuvers. The proposed optimal Min Control method was demonstrated to require less control or trigger later

  2. Effect for Recovery of the Containment Spray System to the Release of Cesium

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Mi Ro [KHNP CRI, Daejeon (Korea, Republic of)

    2016-10-15

    In the perspective of the amount of Cs-137, the mass of Cs-137 correspondent with the 100TBq is calculated as 32g. However, during the severe accident, if the containment has been failed, it is generally expected that the mass of Cs-137 released to the environment is more than 1kg for most accident sequences So, the review and improvement of the PSA model in order to reduce containment failure frequency should be needed. Actually, the current PSA model is known to be constructed by the conservative assumptions, especially in the view point of Level 2 PSA model. Therefore, it is necessary to find this conservatism and to improve the Model using the reasonable assumptions. All of the domestic operating nuclear power plants are required to prepare the Accident Management Plan within 3 years and this Accident Management Plan should have to meet the New Safety Goal including the requirement that the sum of the accident frequency that the release of the radioactive nuclide Cs-137 to the environment exceeds the 100TBq should be less than 1.0E-6/RY. The containment spray system is the only facility that mitigates the containment over-pressurization in the operating nuclear power plants, such as Westinghouse type or OPR1000 type. In this study, the effects of the containment spray system recovery on the amount of Cesium released to the environment were analyzed. If the recovery of the containment spray system can be applied to the PSA model, it is expected that the containment failure frequency and also the amount of cesium released to the environment can be greatly reduced.

  3. Computational fluid dynamic (CFD) analysis on ALUDRA SR-10 UAV with parachute recovery system

    Science.gov (United States)

    Saim, R.; Mohd, S.; Shamsudin, S. S.; Zulkifli, M. F.; Omar, Z.; Subari@Rahmat, Z.; Masrom, M. F. Mohd; Zaki, Y.

    2017-09-01

    In an operation, belly landing is mostly applied as recovery method especially on research Unmanned Aerial Vehicle (UAV) such as Aludra SR-10. This type of landing method may encounter tough landing on hard soil and gravel which create high impact load on the aircraft. The impact may cause structural or system damage which costly to be repaired. Nowadays, Parachute Recovery System (PRS) recently used in numerous different tasks such as landing purpose to replace belly landing technique. Parachute use in this system to slow down flying or falling UAV to a safe landing by opening the canopy to increase aerodynamic drag. This paper was described the Computational Fluid Dynamic (CFD) analysis on ALUDRA SR-10 model with two different conditions i.e. the UAV equipped with and without parachute in order to identify the changes of aerodynamic characteristics. This simulation studies using solid models of aircraft and hemisphere parachute and was carried out by using ANSYS 16.0 Fluent under steady and turbulent flow and was modelled using the k-epsilon (k-ε) turbulence model. This simulation was limited to determine the drag force and drag coefficient. The obtained result showed that implementation of parachute increase 0.25 drag coefficient of the aircraft that is from 0.93 to 1.18. Subsequent to the reduction of descent rate caused by the parachute, the drag force of the aircraft increase by 0.76N. These increasing of drag force of the aircraft will produce lower terminal velocity which is expected to reduce the impact force on the aircraft during landing.

  4. Synthesis and characterization of imprinted sorbent for separation of gramine from bovine serum albumin

    International Nuclear Information System (INIS)

    Luliński, Piotr; Klejn, Dorota; Maciejewska, Dorota

    2016-01-01

    The aim of this study was to develop an efficient sorbent for separation of N,N-dimethyl-3-aminomethylindole (gramine) from bovine serum albumin. An imprinting technology was involved in the synthesis of polymers from nine different functional monomers in the presence of ethylene glycol dimethacrylate as a cross-linker. The analysis of binding capacities showed that the highest specificity towards gramine was achieved when 4-vinylbenzoic acid was used as the functional monomer in methanol to form the bulk imprinted polymer, MIP1 (imprinting factor equal to 21.3). The Scatchard analysis of MIP1 showed two classes of binding sites with the dissociation constants K_d equal to 0.105 and 6.52 μmol L"−"1. The composition and morphology of polymers were defined by "1"3C CP/MAS NMR, BET and SEM-EDS analyses. The recognition mechanism of MIP1 was tested using the structurally related bioanalytes, and the dominant role of indole moiety and ethylamine side chain was revealed. A new MISPE protocol was optimized for separation of gramine. The total recoveries on MIP1 were equal to 94 ± 12 % from standard solutions and 85 ± 11 % from bovine serum albumin. - Highlights: • Indole alkaloid (gramine) imprinted polymer was synthesized. • Very high specifity of sorbent towards gramine was achieved. • Physico-chemical characteristics of novel material was presented. • Efficient MISPE protocol was proposed for separation of gramine from model sample.

  5. Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Saeed, Asma, E-mail: asmadr@wol.net.pk [Environmental Biotechnology Group, Biotechnology and Food Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600 (Pakistan); Sharif, Mehwish [School of Biological Sciences, University of the Punjab, Lahore 54590 (Pakistan); Iqbal, Muhammad [Environmental Biotechnology Group, Biotechnology and Food Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600 (Pakistan)

    2010-07-15

    This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation {>=}0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g{sup -1}. The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions.

  6. New sorbent materials for selective extraction of cocaine and benzoylecgonine from human urine samples.

    Science.gov (United States)

    Bujak, Renata; Gadzała-Kopciuch, Renata; Nowaczyk, Alicja; Raczak-Gutknecht, Joanna; Kordalewska, Marta; Struck-Lewicka, Wiktoria; Waszczuk-Jankowska, Małgorzata; Tomczak, Ewa; Kaliszan, Michał; Buszewski, Bogusław; Markuszewski, Michał J

    2016-02-20

    An increase in cocaine consumption has been observed in Europe during the last decade. Benzoylecgonine, as a main urinary metabolite of cocaine in human, is so far the most reliable marker of cocaine consumption. Determination of cocaine and its metabolite in complex biological samples as urine or blood, requires efficient and selective sample pretreatment. In this preliminary study, the newly synthesized sorbent materials were proposed for selective extraction of cocaine and benzoylecgonine from urine samples. Application of these sorbent media allowed to determine cocaine and benzoylecgonine in urine samples at the concentration level of 100ng/ml with good recovery values as 81.7%±6.6 and 73.8%±4.2, respectively. The newly synthesized materials provided efficient, inexpensive and selective extraction of both cocaine and benzoylecgonine from urine samples, which can consequently lead to an increase of the sensitivity of the current available screening diagnostic tests. Copyright © 2015 Elsevier B.V. All rights reserved.

  7. Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption

    International Nuclear Information System (INIS)

    Saeed, Asma; Sharif, Mehwish; Iqbal, Muhammad

    2010-01-01

    This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation ≥0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g -1 . The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions.

  8. Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption.

    Science.gov (United States)

    Saeed, Asma; Sharif, Mehwish; Iqbal, Muhammad

    2010-07-15

    This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation > or = 0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g(-1). The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions. 2010 Elsevier B.V. All rights reserved.

  9. A Longitudinal Study of Decomposition Odour in Soil Using Sorbent Tubes and Solid Phase Microextraction

    Directory of Open Access Journals (Sweden)

    Katelynn A. Perrault

    2014-07-01

    Full Text Available Odour profiling of decomposed remains is important for understanding the mechanisms that cadaver dogs and forensically-relevant insects use to locate decomposed remains. The decomposition odour profile is complex and has been documented in outdoor terrestrial environments. The purpose of this study was to perform longitudinal analysis of the volatile organic compound (VOC profile in soils associated with decomposed remains across all stages of decomposition. Two VOC collection techniques (sorbent tubes and solid phase microextraction were used to collect a wider analyte range and to investigate differences in collection techniques. Pig carcasses were placed in an outdoor research facility in Australia to model the decomposition process and VOCs were collected intermittently over two months. VOCs of interest were identified over the duration of the trial, showing distinct trends in compound evolution and disappearance. The collection techniques were complementary, representing different subsets of VOCs from the overall profile. Sorbent tubes collected more decomposition-specific VOCs and these compounds were more effective at characterising the matrix over an extended period. Using both collection techniques improves the likelihood of identifying the complete VOC profile of decomposition odour. Such information is important for the search and recovery of victim remains in various stages of decomposition.

  10. Synthesis and characterization of imprinted sorbent for separation of gramine from bovine serum albumin

    Energy Technology Data Exchange (ETDEWEB)

    Luliński, Piotr; Klejn, Dorota; Maciejewska, Dorota, E-mail: dmaciejewska@wum.edu.pl

    2016-08-01

    The aim of this study was to develop an efficient sorbent for separation of N,N-dimethyl-3-aminomethylindole (gramine) from bovine serum albumin. An imprinting technology was involved in the synthesis of polymers from nine different functional monomers in the presence of ethylene glycol dimethacrylate as a cross-linker. The analysis of binding capacities showed that the highest specificity towards gramine was achieved when 4-vinylbenzoic acid was used as the functional monomer in methanol to form the bulk imprinted polymer, MIP1 (imprinting factor equal to 21.3). The Scatchard analysis of MIP1 showed two classes of binding sites with the dissociation constants K{sub d} equal to 0.105 and 6.52 μmol L{sup −1}. The composition and morphology of polymers were defined by {sup 13}C CP/MAS NMR, BET and SEM-EDS analyses. The recognition mechanism of MIP1 was tested using the structurally related bioanalytes, and the dominant role of indole moiety and ethylamine side chain was revealed. A new MISPE protocol was optimized for separation of gramine. The total recoveries on MIP1 were equal to 94 ± 12 % from standard solutions and 85 ± 11 % from bovine serum albumin. - Highlights: • Indole alkaloid (gramine) imprinted polymer was synthesized. • Very high specifity of sorbent towards gramine was achieved. • Physico-chemical characteristics of novel material was presented. • Efficient MISPE protocol was proposed for separation of gramine from model sample.

  11. Heat recovery subsystem and overall system integration of fuel cell on-site integrated energy systems

    Science.gov (United States)

    Mougin, L. J.

    1983-01-01

    The best HVAC (heating, ventilating and air conditioning) subsystem to interface with the Engelhard fuel cell system for application in commercial buildings was determined. To accomplish this objective, the effects of several system and site specific parameters on the economic feasibility of fuel cell/HVAC systems were investigated. An energy flow diagram of a fuel cell/HVAC system is shown. The fuel cell system provides electricity for an electric water chiller and for domestic electric needs. Supplemental electricity is purchased from the utility if needed. An excess of electricity generated by the fuel cell system can be sold to the utility. The fuel cell system also provides thermal energy which can be used for absorption cooling, space heating and domestic hot water. Thermal storage can be incorporated into the system. Thermal energy is also provided by an auxiliary boiler if needed to supplement the fuel cell system output. Fuel cell/HVAC systems were analyzed with the TRACE computer program.

  12. Energy recovery storage systems in electrical vehicles with batteries; Tecnicas de armazenamiento de energia em veiculos electricos a baterias

    Energy Technology Data Exchange (ETDEWEB)

    Chaves, M.; Maia, J.; Foito, D.

    2004-07-01

    In this paper are presented three energy recovery storage systems that can be used in electrical vehicles with batteries. The first storage system uses ultra capacitors that is electrical energy storage, the second system is based on superconductivity magnetic storage, and the third system uses on kinetic energy stored in flywheels. It is also presented the power electronics needed to perform the energy systems. (Author)

  13. Cryogenic system for the Energy Recovery Linac and vertical test facility at BNL

    International Nuclear Information System (INIS)

    Than, R.; Soria, V.; Lederle, D.; Orfin, P.; Porqueddu, R.; Talty, P.; Zhang, Y.; Tallerico, T.; Masi, L.

    2011-01-01

    A small cryogenic system and warm helium vacuum pumping system provides cooling to either the Energy Recovery Linac's (ERL) cryomodules that consist of a 5-cell cavity and an SRF gun or a large Vertical Test Dewar (VTD) at any given time. The cryogenic system consists of a model 1660S PSI piston plant, a 3800 liter storage dewar, subcooler, a wet expander, a 50 g/s main helium compressor, and a 170 m 3 storage tank. A system description and operating plan of the cryogenic plant and cryomodules is given. The cryogenic system for ERL and the Vertical Test Dewar has a plant that can produce the equivalent of 300W at 4.5K with the addition of a wet expander 350 W at 4.5K. Along with this system, a sub-atmospheric, warm compression system provides pumping to produce 2K at the ERL cryomodules or the Vertical Test Dewar. The cryogenic system for ERL and the Vertical Test Dewar makes use of existing equipment for putting a system together. It can supply either the ERL side or the Vertical Test Dewar side, but not both at the same time. Double valve isolation on the liquid helium supply line allows one side to be warmed to room temperature and worked on while the other side is being held at operating temperature. The cryogenic system maintain the end loads from 4.4K to 2K or colder depending on capacity. Liquid helium storage dewar capacity allows ERL or the VTD to operate above the plant's capacity when required and ERL cryomodules ballast reservoirs and VTD reservoir allows the end loads to operate on full vacuum pump capacity when required.

  14. Tributyl phosphate removal from reprocessing off-gas streams using a selected sorbent

    International Nuclear Information System (INIS)

    Parker, G.B.

    1980-01-01

    Laboratory experiments used small laboratory-scale columns packed with selected sorbent materials to remove tributyl phosphate (TBP) and iodine at conditions approaching those in actual reprocessing off-gas streams. The sorbent materials for TBP removal were placed upstream of iodine sorbent materials to protect the iodine sorbent from the deleterious effects of TBP. Methyl iodide in an airstream containing 30% TBP in normal paraffin hydrocarbons (NPH) and water vapor was metered to two packed columns of sorbents simultaneously (in parallel). One column contained a segment of 8-in. x 14-in. mesh alumina sorbent for TBP removal, the other did not. The measure of the effectiveness of TBP sorbent materials for TBP removal was determined by comparing the iodine retention of the iodine sorbent materials in the two parallel columns. Results from an 18 wt % Ag substituted mordenite iodine sorbent indicated that the iodine retention capacity of the sorbent was reduced 60% by the TBP and that the column containing iodine sorbent material protected by the alumina TBP sorbent retained 30 times more iodine than the column without TBP sorbent. TBP concentration was up to 500 mg/m 3 . Similar experiments using a 7 wt % Ag impregnated silica gel indicated that the TBP vapor had little effect on the iodine retention of the silica gel material. The stoichiometric maximum amount of iodine was retained by the silica gel material. Further experiments were conducted assessing the effects of NO 2 on iodine retention of this 7 wt % Ag sorbent. After the two columns were loaded with iodine in the presence of TBP (in NPH), one column was subjected to 2 vol % NO 2 in air. From visual comparison of the two columns, it appeared that the NO 2 regenerated the silica gel iodine sorbent and that iodine was washed off the silica gel iodine sorbent leaving the sorbent in the original state

  15. Simultaneous power generation and heat recovery using a heat pipe assisted thermoelectric generator system

    International Nuclear Information System (INIS)

    Remeli, Muhammad Fairuz; Tan, Lippong; Date, Abhijit; Singh, Baljit; Akbarzadeh, Aliakbar

    2015-01-01

    Highlights: • A new passive power cogeneration system using industrial waste heat was introduced. • Heat pipes and thermoelectrics were used for recovering waste heat and electricity. • Theoretical model predicted the 2 kW test rig could recover 1.345 kW thermal power. • 10.39 W electrical power was produced equivalent to 0.77% conversion efficiency. - Abstract: This research explores a new method of recovering waste heat and electricity using a combination of heat pipes and thermoelectric generators (HP-TEG). The HP-TEG system consists of Bismuth Telluride (Bi 2 Te 3 ) based thermoelectric generators (TEGs), which are sandwiched between two finned heat pipes to achieve a temperature gradient across the TEG for thermoelectricity generation. A theoretical model was developed to predict the waste heat recovery and electricity conversion performances of the HP-TEG system under different parametric conditions. The modelling results show that the HP-TEG system has the capability of recovering 1.345 kW of waste heat and generating 10.39 W of electrical power using 8 installed TEGs. An experimental test bench for the HP-TEG system is under development and will be discussed in this paper

  16. Grafting the sol-gel based sorbents by diazonium salts: a novel approach toward unbreakable capillary microextraction.

    Science.gov (United States)

    Bagheri, Habib; Bayat, Parisa; Piri-Moghadam, Hamed

    2013-11-29

    The present work deals with a novel approach for grafting a sol-gel based sorbent, using diazonium salts for preparation of an unbreakable capillary microextraction (CME) device in on-line combination with high performance liquid chromatography (HPLC). The use of diazonium salts modifier allowed all types of metallic and non-metallic substrates to be used without any limitation. Substrates including copper, brass, stainless steel and polytetrafluoroethylene (PTFE) were chosen to be functionalized by chemical or electrochemical reduction of 4-amino phenyl acetic acid. Then, 3-(trimethoxysilyl)propylamine (3TMSPA) was selected as the precursor and the only reagent for preparation of the desired surface chemical bonded sorbent. The presence of chemical bond between substrate, diazonium salts and 3TMSPA is more probably responsible for thermal and solvent stability and long lifetime of the prepared sorbent. Characterization of the aryl group formation on the various substrates along with the prepared sorbents was thoroughly investigated by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and thermogravimetry analysis (TGA). Typically, one of the prepared sorbents, deposited on the inner surface of the copper tube, was selected for assessing the developed method. The CME device was used for on-line extraction of atrazine, ametryn and terbutryn, as model compounds, from the aquatic media. After extraction, the HPLC mobile phase was used for on-line desorption and elution of the extracted analytes from the CME loop, containing the grafted sol-gel based sorbent, through the HPLC column. Figures of merit of the developed method were also obtained in which the linearity for the analytes was in the range of 30-1000μgL(-1). The value of LOD (S/N=3) for all analytes was 10μgL(-1) and the RSD% values (n=5) were all below 9.4% at the 500μgL(-1) level. Applicability of the developed method was examined by analyzing some real water samples in

  17. Solid-phase extraction of galloyl- and caffeoylquinic acids from natural sources (Galphimia glauca and Arnicae flos) using pure zirconium silicate and bismuth citrate powders as sorbents inside micro spin columns.

    Science.gov (United States)

    Hussain, Shah; Schönbichler, Stefan A; Güzel, Yüksel; Sonderegger, Harald; Abel, Gudrun; Rainer, Matthias; Huck, Christian W; Bonn, Günther K

    2013-10-01

    Galloyl- and caffeoylquinic acids are among the most important pharmacological active groups of natural compounds. This study describes a pre-step in isolation of some selected representatives of these groups from biological samples. A selective solid-phase extraction (SPE) method for these compounds may help assign classes and isomer designations within complex mixtures. Pure zirconium silicate and bismuth citrate powders (325 mesh) were employed as two new sorbents for optimized SPE of phenolic acids. These sorbents possess electrostatic interaction sites which accounts for additional interactions for carbon acid moieties as compared to hydrophilic and hydrophobic sorbents alone. Based on this principle, a selective SPE method for 1,3,4,5-tetragalloylquinic acid (an anti-HIV and anti-asthamatic agent) as a starting compound was developed and then deployed upon other phenolic acids with success. The recoveries and selectivities of both sorbents were compared to most commonly applied and commercially available sorbents by using high performance liquid chromatography. The nature of interaction between the carrier sorbent and the acidic target molecules was investigated by studying hydrophilic (silica), hydrophobic (C18), mixed-mode (ionic and hydrophobic: Oasis(®) MAX) and predominantly electrostatic (zirconium silicate) materials. The newly developed zirconium silicate and bismuth citrate stationary phases revealed promising results for the selective extraction of galloyl- and caffeoylquinic acids from natural sources. It was observed that zirconium silicate exhibited maximum recovery and selectivity for tetragalloylquinic acid (84%), chlorogenic acid (82%) and dicaffeoylquinic acid (94%) among all the tested sorbents. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Implementation of Enhanced Recovery After Surgery: a strategy to transform surgical care across a health system.

    Science.gov (United States)

    Gramlich, Leah M; Sheppard, Caroline E; Wasylak, Tracy; Gilmour, Loreen E; Ljungqvist, Olle; Basualdo-Hammond, Carlota; Nelson, Gregg

    2017-05-19

    Enhanced Recovery After Surgery (ERAS) programs have been shown to have a positive impact on outcome. The ERAS care system includes an evidence-based guideline, an implementation program, and an interactive audit system to support practice change. The purpose of this study is to describe the use of the Theoretic Domains Framework (TDF) in changing surgical care and application of the Quality Enhancement Research Initiative (QUERI) model to analyze end-to-end implementation of ERAS in colorectal surgery across multiple sites within a single health system. The ultimate intent of this work is to allow for the development of a model for spread, scale, and sustainability of ERAS in Alberta Health Services (AHS). ERAS for colorectal surgery was implemented at two sites and then spread to four additional sites. The ERAS Interactive Audit System (EIAS) was used to assess compliance with the guidelines, length of stay, readmissions, and complications. Data sources informing knowledge translation included surveys, focus groups, interviews, and other qualitative data sources such as minutes and status updates. The QUERI model and TDF were used to thematically analyze 189 documents with 2188 quotes meeting the inclusion criteria. Data sources were analyzed for barriers or enablers, organized into a framework that included individual to organization impact, and areas of focus for guideline implementation. Compliance with the evidence-based guidelines for ERAS in colorectal surgery at baseline was 40%. Post implementation compliance, consistent with adoption of best practice, improved to 65%. Barriers and enablers were categorized as clinical practice (22%), individual provider (26%), organization (19%), external environment (7%), and patients (25%). In the Alberta context, 26% of barriers and enablers to ERAS implementation occurred at the site and unit levels, with a provider focus 26% of the time, a patient focus 26% of the time, and a system focus 22% of the time. Using the

  19. Miniaturized solid-phase extraction of macrolide antibiotics in honey and bovine milk using mesoporous MCM-41 silica as sorbent.

    Science.gov (United States)

    Du, Li-Jing; Yi, Ling; Ye, Li-Hong; Chen, Yu-Bo; Cao, Jun; Peng, Li-Qing; Shi, Yu-Ting; Wang, Qiu-Yan; Hu, Yu-Han

    2018-02-16

    A simple and effective method of miniaturized solid-phase extraction (mini-SPE) was developed for the simultaneous purification and enrichment of macrolide antibiotics (MACs) (i.e. azithromycin, clarithromycin, erythromycin, lincomycin and roxithromycin) from honey and skim milk. Mesoporous MCM-41 silica was synthesized and used as sorbent in mini-SPE. Several key parameters affecting the performance of mini-SPE procedure were thoroughly investigated, including sorbent materials, amount of sorbent and elution solvents. Under the optimized condition, satisfactory linearity (r 2  > 0.99), acceptable precision (RSDs, 0.3-7.1%), high sensitivity (limit of detection in the range of 0.01-0.76 μg/kg), and good recoveries (83.21-105.34%) were obtained. With distinct advantages of simplicity, reliability and minimal sample requirement, the proposed mini-SPE procedure coupled with ultrahigh performance liquid chromatography and quadrupole time-of-flight tandem mass spectrometry could become an alternative tool to analyze the residues of MACs in complex food matrixes. Copyright © 2018 Elsevier B.V. All rights reserved.

  20. Performance improvement of a slip energy recovery drive system by a voltage-controlled technique

    Energy Technology Data Exchange (ETDEWEB)

    Tunyasrirut, Satean [Department of Instrumentation Engineering, Faculty of Engineering, Pathumwan Institute of Technology, 833 Rama1 Road, Pathumwan, Bangkok 10330 (Thailand); Kinnares, Vijit [Department of Electrical Engineering, Faculty of Engineering, King Mongkut' s Institute of Technology Ladkrabang, Bangkok 10520 (Thailand); Ngamwiwit, Jongkol [Department of Control Engineering, Faculty of Engineering, King Mongkut' s Institute of Technology Ladkrabang, Bangkok 10520 (Thailand)

    2010-10-15

    This paper introduces the performance improvement of a slip energy recovery drive system for the speed control of a wound rotor induction motor by a voltage-controlled technique. The slip energy occurred in the rotor circuit is transferred back to ac mains supply through a reactor instead of a step up transformer. The objective of the voltage-controlled technique is to increase power factor of the system and to reduce low order harmonics of the input line current. The drive system is designed and implemented using a voltage source inverter in conjunction with a boost chopper for DC link voltage, instead of a conventional drive using a 6 pulse converter or a Scherbius system. The slip power is recovered by the help of a voltage source inverter (VSI) based on a space vector pulse width modulation (SVPWM) technique. In order to keep the speed of the wound rotor induction motor constant over a certain range of operating conditions, the servo state feedback controller designed by a linear quadratic regulator (LQR) is also introduced in this paper. The overall control system is implemented on DSP, DS1104'TMS320F240 controller board. The performance improvement of the proposed system is tested in comparison with the conventional Scherbius system and the modified conventional Scherbius system by a 12 pulse converter in conjunction with a chopper at steady state and at dynamic conditions. A 220 W wound motor is employed for testing. It is found that the motor speed can be controlled to be constant in the operating range of 450-1200 rpm at no load and full load. It is also found that the efficiency of the proposed system is remarkably increased since the harmonics of the input ac line current is reduced while the ac line input power factor is increased. (author)