Finite element methods a practical guide
Whiteley, Jonathan
2017-01-01
This book presents practical applications of the finite element method to general differential equations. The underlying strategy of deriving the finite element solution is introduced using linear ordinary differential equations, thus allowing the basic concepts of the finite element solution to be introduced without being obscured by the additional mathematical detail required when applying this technique to partial differential equations. The author generalizes the presented approach to partial differential equations which include nonlinearities. The book also includes variations of the finite element method such as different classes of meshes and basic functions. Practical application of the theory is emphasised, with development of all concepts leading ultimately to a description of their computational implementation illustrated using Matlab functions. The target audience primarily comprises applied researchers and practitioners in engineering, but the book may also be beneficial for graduate students.
On the reliability of finite element solutions
International Nuclear Information System (INIS)
Prasad, K.S.R.K.
1975-01-01
The extent of reliability of the finite element method for analysis of nuclear reactor structures, and that of reactor vessels in particular and the need for the engineer to guard against the pitfalls that may arise out of both physical and mathematical models have been high-lighted. A systematic way of checking the model to obtain reasonably accurate solutions is presented. Quite often sophisticated elements are suggested for specific design and stress concentration problems. The desirability or otherwise of these elements, their scope and utility vis-a-vis the use of large stack of conventional elements are discussed from the view point of stress analysts. The methods of obtaining a check on the reliability of the finite element solutions either through modelling changes or an extrapolation technique are discussed. (author)
Molybdenum: the element and aqueous solution chemistry
International Nuclear Information System (INIS)
Sykes, A.G.
1987-01-01
This chapter on the chemistry of the coordination compounds of molybdenum concentrates on the element itself, its recovery from ores and its use in the manufacture of steels. Most of the chapter is devoted to the aqueous solution chemistry of molybdenum in oxidation states II, III and IV. (UK)
Multi-element determination of soil solution by INAA
International Nuclear Information System (INIS)
Qian Qinfang; Wu Shuiqing; Tian Jibing
1992-01-01
One of the factors influencing crop growth is the effective elemental contents, especially trace elements, under the circumstances of the same concentrations of N, P and K in soil. In order to obtain the data of effective elemental contents in soil, a novel method was introduced. In this method, soil solution was extracted by a squeezer. The concentrations of elements in soil solution were determined by INAA. Study on the compositions and the contents of elements in soil solution will provide information on making a suitable soil environment for plant growth and on rational and economical manuring
Solution chemistry of element 104: Pt. 1
International Nuclear Information System (INIS)
Czerwinski, K.R.; Gregorich, K.E.; Hannink, N.J.; Kacher, C.D.; Kadkhodayan, B.A.; Kreek, S.A.; Lee, D.M.; Nurmia, M.J.; Tuerler, A.; Seaborg, G.T.; Hoffman, D.C.
1994-01-01
Liquid-liquid extractions of element 104 (Rf), Zr, Nb, Th, and Eu were conducted using triisooctylamine (TIOA), an organic soluble high molecular weight amine. Initial studies were conducted studying the extraction of Zr, Nb, Th and Eu from 12 M HCl in an organic phase of TIOA in benzene. Tracer loss due to thin sample formation was examined using 95 Zr. Based on the tracer extraction results, Rf extractions were conducted with an aqueous phase of 12 M HCl and an organic phase of 1.0 M and 0.1 M TIAO in benzene. The Rf extraction results showed that 0.1 M TIOA in benzene extracts Rf to a greater extent than 1.0 M TIOA in benzene. This difference is attributed to Rf loss during thin sample formation. The extraction of Rf by TIOA is further evidence that Rf behaves similar to the group 4 elements. (orig.)
An efficient finite element solution for gear dynamics
International Nuclear Information System (INIS)
Cooley, C G; Parker, R G; Vijayakar, S M
2010-01-01
A finite element formulation for the dynamic response of gear pairs is proposed. Following an established approach in lumped parameter gear dynamic models, the static solution is used as the excitation in a frequency domain solution of the finite element vibration model. The nonlinear finite element/contact mechanics formulation provides accurate calculation of the static solution and average mesh stiffness that are used in the dynamic simulation. The frequency domain finite element calculation of dynamic response compares well with numerically integrated (time domain) finite element dynamic results and previously published experimental results. Simulation time with the proposed formulation is two orders of magnitude lower than numerically integrated dynamic results. This formulation admits system level dynamic gearbox response, which may include multiple gear meshes, flexible shafts, rolling element bearings, housing structures, and other deformable components.
A finite element solution method for quadrics parallel computer
International Nuclear Information System (INIS)
Zucchini, A.
1996-08-01
A distributed preconditioned conjugate gradient method for finite element analysis has been developed and implemented on a parallel SIMD Quadrics computer. The main characteristic of the method is that it does not require any actual assembling of all element equations in a global system. The physical domain of the problem is partitioned in cells of n p finite elements and each cell element is assigned to a different node of an n p -processors machine. Element stiffness matrices are stored in the data memory of the assigned processing node and the solution process is completely executed in parallel at element level. Inter-element and therefore inter-processor communications are required once per iteration to perform local sums of vector quantities between neighbouring elements. A prototype implementation has been tested on an 8-nodes Quadrics machine in a simple 2D benchmark problem
A multigrid solution method for mixed hybrid finite elements
Energy Technology Data Exchange (ETDEWEB)
Schmid, W. [Universitaet Augsburg (Germany)
1996-12-31
We consider the multigrid solution of linear equations arising within the discretization of elliptic second order boundary value problems of the form by mixed hybrid finite elements. Using the equivalence of mixed hybrid finite elements and non-conforming nodal finite elements, we construct a multigrid scheme for the corresponding non-conforming finite elements, and, by this equivalence, for the mixed hybrid finite elements, following guidelines from Arbogast/Chen. For a rectangular triangulation of the computational domain, this non-conforming schemes are the so-called nodal finite elements. We explicitly construct prolongation and restriction operators for this type of non-conforming finite elements. We discuss the use of plain multigrid and the multilevel-preconditioned cg-method and compare their efficiency in numerical tests.
Solutions of group IV elements in liquid lithium
International Nuclear Information System (INIS)
Dadd, A.T.; Hubberstey, P.; Roberts, P.G.
1982-01-01
The solubilities of tin (0.00 = 22 Sn 5 . A simple thermochemical cycle is used to demonstrate that, whereas carbon dissolves endothermically in both liquid lithium and liquid sodium, the heavier Group IV elements dissolve exothermically. A similar cycle is used to derive solvation enthalpies (for the neutral gaseous species) for all Group IV elements in the two solvents. The trend in solvation enthalpy: C > Si > Ge > Sn > Pb is indicative of a diminishing affinity of solvent for solute and is attributed to the increasing metallic character of the solute as the Group is descended. (author)
A Summary of the Space-Time Conservation Element and Solution Element (CESE) Method
Wang, Xiao-Yen J.
2015-01-01
The space-time Conservation Element and Solution Element (CESE) method for solving conservation laws is examined for its development motivation and design requirements. The characteristics of the resulting scheme are discussed. The discretization of the Euler equations is presented to show readers how to construct a scheme based on the CESE method. The differences and similarities between the CESE method and other traditional methods are discussed. The strengths and weaknesses of the method are also addressed.
Hybrid Fundamental Solution Based Finite Element Method: Theory and Applications
Directory of Open Access Journals (Sweden)
Changyong Cao
2015-01-01
Full Text Available An overview on the development of hybrid fundamental solution based finite element method (HFS-FEM and its application in engineering problems is presented in this paper. The framework and formulations of HFS-FEM for potential problem, plane elasticity, three-dimensional elasticity, thermoelasticity, anisotropic elasticity, and plane piezoelectricity are presented. In this method, two independent assumed fields (intraelement filed and auxiliary frame field are employed. The formulations for all cases are derived from the modified variational functionals and the fundamental solutions to a given problem. Generation of elemental stiffness equations from the modified variational principle is also described. Typical numerical examples are given to demonstrate the validity and performance of the HFS-FEM. Finally, a brief summary of the approach is provided and future trends in this field are identified.
Extraction of transplutonium elements from carbonate solutions by alkylpyrocatechol
International Nuclear Information System (INIS)
Karalova, Z.K.; Myasoedov, B.F.; Rodionova, L.M.; Kuznetsova, V.S.
1983-01-01
Extraction of americium, berkelium as well as Ce, Eu, Th, U, Zr, Cs, Fe with solution of 4(α, α-dioctylethyl)pyrocatechol (DOP) in toluene from carbonate solutions to determine conditions of their separation has been studied. It is established that americium extraction is quite sensitive to the changes of potassium carbonate concentration. The maximum extraction of americium (R >90%) is observed in the case of 0.1-0.5 mol/l of K 2 CO 3 solutions and the minimum one (R=2.5%) - in the case of 8 mol/l K 2 CO 3 . Americium extraction increases sharply when sodium hydroxide is introduced in carbonate solutions. It is shown that varying sodium hydroxide concentration it is possible to achieve qualitative extraction of americium even from saturated solution of potassium carbonate. Reextraction of TPE is easily realized with 3 mol/l HCl solution. The system K 2 CO 3 (KOH)-DOP proved to be perspective for Am separation from Bk, Ce, Cs, actinoid elements as well as from Fe
Finite element solution of quasistationary nonlinear magnetic field
International Nuclear Information System (INIS)
Zlamal, Milos
1982-01-01
The computation of quasistationary nonlinear two-dimensional magnetic field leads to the following problem. There is given a bounded domain OMEGA and an open nonempty set R included in OMEGA. We are looking for the magnetic vector potential u(x 1 , x 2 , t) which satisifies: 1) a certain nonlinear parabolic equation and an initial condition in R: 2) a nonlinear elliptic equation in S = OMEGA - R which is the stationary case of the above mentioned parabolic equation; 3) a boundary condition on delta OMEGA; 4) u as well as its conormal derivative are continuous accross the common boundary of R and S. This problem is formulated in two equivalent abstract ways. There is constructed an approximate solution completely discretized in space by a generalized Galerkin method (straight finite elements are a special case) and by backward A-stable differentiation methods in time. Existence and uniqueness of a weak solution is proved as well as a weak and strong convergence of the approximate solution to this solution. There are also derived error bounds for the solution of the two-dimensional nonlinear magnetic field equations under the assumption that the exact solution is sufficiently smooth
International Nuclear Information System (INIS)
Iwata, K.; Matsumiya, T.; Sawada, H.; Kawakami, K.
2003-01-01
The method is presented to predict the activity coefficients and the interaction parameters of the solute elements in infinite dilute Si solutions by the use of first-principles calculations based on density functional theory. In this method, the regular solution model is assumed. The calculated activity coefficients in solid Si are converted to those in molten Si by the use of the solid-liquid partition coefficients. Furthermore, the interaction parameters in solid Si solutions are calculated and compared with reported experimental values of those in liquid Si solutions. The results show that the calculated activity coefficients and interaction parameters of Al, Fe, Ti and Pb in Si solutions are in good agreement with the tendency of the experiments. However, the calculations have some quantitative discrepancy from the experiments. It is expected that consideration of the excess entropy would reduce this discrepancy
Effects of solute interstitial elements on swelling of stainless steel
International Nuclear Information System (INIS)
Stiegler, J.O.; Leitnaker, J.M.; Bloom, E.E.
1975-01-01
High-purity stainless steel (HPS), equivalent to type 316 stainless steel in major alloy elements but with greatly reduced interstitial elements and manganese contents, was irradiated in the temperature range 725 to 875 K to fluences ranging from 1.0 to 3.5 x 10 26 neutrons/m 2 (>0.1 MeV). The HPS swelled 20 to 50 times more than commercial grade 316 stainless steel (316 SS), and about the same as commercial-purity nickel, which has about the same interstitial content as HPS. A fine-grained 316 SS in which interstitial elements but not manganese were precipitated by thermomechanical treatments also showed exaggerated swelling, approaching that of HPS, which suggests that swelling in commercial stainless steels is retarded by small amounts of interstitial elements normally present in them and not by the major alloying elements. Interstitials tend to precipitate from solution during irradiation, and bulk extractions of precipitate particles were made to evaluate the extent of the precipitation reactions. At both 643 and 853 K precipitation was clearly enhanced by irradiation significantly enough to alter the matrix composition, which suggests that swelling may be increased at high fluences over that predicted by extrapolation of lower fluence data. These observations are discussed in terms of potential behaviour of fuel cladding materials and of the validity and interpretation of accelerated schemes for simulating neutron damage. (author)
Redox reactions for group 5 elements, including element 105, in aqueous solutions
International Nuclear Information System (INIS)
Ionova, G.V.; Pershina, V.; Johnson, E.; Fricke, B.; Schaedel, M.
1992-08-01
Standard redox potentials Edeg(M z+x /M z+ ) in acidic solutions for group 5 elements including element 105 (Ha) and the actinide, Pa, have been estimated on the basis of the ionization potentials calculated via the multiconfiguration Dirac-Fock method. Stability of the pentavalent state was shown to increase along the group from V to Ha, while that of the tetra- and trivalent states decreases in this direction. Our estimates have shown no extra stability of the trivalent state of hahnium. Element 105 should form mixed-valence complexes by analogy with Nb due to the similar values of their potentials Edeg(M 3+ /M 2+ ). The stability of the maximum oxidation state of the elements decreases in the direction 103 > 104 > 105. (orig.)
Eigenvalue solutions in finite element thermal transient problems
International Nuclear Information System (INIS)
Stoker, J.R.
1975-01-01
The eigenvalue economiser concept can be useful in solving large finite element transient heat flow problems in which the boundary heat transfer coefficients are constant. The usual economiser theory is equivalent to applying a unit thermal 'force' to each of a small sub-set of nodes on the finite element mesh, and then calculating sets of resulting steady state temperatures. Subsequently it is assumed that the required transient temperature distributions can be approximated by a linear combination of this comparatively small set of master temperatures. The accuracy of a reduced eigenvalue calculation depends upon a good choice of master nodes, which presupposes at least a little knowledge about what sort of shape is expected in the unknown temperature distributions. There are some instances, however, where a reasonably good idea exists of the required shapes, permitting a modification to the economiser process which leads to greater economy in the number of master temperatures. The suggested new approach is to use manually prescribed temperature distributions as the master distributions, rather than using temperatures resulting from unit thermal forces. Thus, with a little pre-knowledge one may write down a set of master distributions which, as a linear combination, can represent the required solution over the range of interest to a reasonable engineering accuracy, and using the minimum number of variables. The proposed modified eigenvalue economiser technique then uses the master distributions in an automatic way to arrive at the required solution. The technique is illustrated by some simple finite element examples
Methods for removing transuranic elements from waste solutions
International Nuclear Information System (INIS)
Slater, S.A.; Chamberlain, D.B.; Connor, C.; Sedlet, J.; Srinivasan, B.; Vandegrift, G.F.
1994-11-01
This report outlines a treatment scheme for separating and concentrating the transuranic (TRU) elements present in aqueous waste solutions stored at Argonne National Laboratory (ANL). The treatment method selected is carrier precipitation. Potential carriers will be evaluated in future laboratory work, beginning with ferric hydroxide and magnetite. The process will result in a supernatant with alpha activity low enough that it can be treated in the existing evaporator/concentrator at ANL. The separated TRU waste will be packaged for shipment to the Waste Isolation Pilot Plant
Finite element based composite solution for neutron transport problems
International Nuclear Information System (INIS)
Mirza, A.N.; Mirza, N.M.
1995-01-01
A finite element treatment for solving neutron transport problems is presented. The employs region-wise discontinuous finite elements for the spatial representation of the neutron angular flux, while spherical harmonics are used for directional dependence. Composite solutions has been obtained by using different orders of angular approximations in different parts of a system. The method has been successfully implemented for one dimensional slab and two dimensional rectangular geometry problems. An overall reduction in the number of nodal coefficients (more than 60% in some cases as compared to conventional schemes) has been achieved without loss of accuracy with better utilization of computational resources. The method also provides an efficient way of handling physically difficult situations such as treatment of voids in duct problems and sharply changing angular flux. It is observed that a great wealth of information about the spatial and directional dependence of the angular flux is obtained much more quickly as compared to Monte Carlo method, where most of the information in restricted to the locality of immediate interest. (author)
Thermal stresses in rectangular plates: variational and finite element solutions
International Nuclear Information System (INIS)
Laura, P.A.A.; Gutierrez, R.H.; Sanchez Sarmiento, G.; Basombrio, F.G.
1978-01-01
This paper deals with the development of an approximate method for the analysis of thermal stresses in rectangular plates (plane stress problem) and an evaluation of the relative accuracy of the finite element method. The stress function is expanded in terms of polynomial coordinate functions which identically satisfy the boundary conditions, and a variational approach is used to determine the expansion coefficients. The results are in good agreement with a finite element approach. (Auth.)
Finite element solution of two dimensional time dependent heat equation
International Nuclear Information System (INIS)
Maaz
1999-01-01
A Microsoft Windows based computer code, named FHEAT, has been developed for solving two dimensional heat problems in Cartesian and Cylindrical geometries. The programming language is Microsoft Visual Basic 3.0. The code makes use of Finite element formulation for spatial domain and Finite difference formulation for time domain. Presently the code is capable of solving two dimensional steady state and transient problems in xy- and rz-geometries. The code is capable excepting both triangular and rectangular elements. Validation and benchmarking was done against hand calculations and published results. (author)
Finite element approach to solution of multidimensional quasi ...
African Journals Online (AJOL)
problems whose function can be expressed as derivatives and integrated functional or on solution of quasi-harmonic functions whose physical behaviors are governed by a general quasi-harmonic differential equation that can be treated as a quadratic functional that can be minimized over a region. The functional of a ...
Symplectic discretization for spectral element solution of Maxwell's equations
International Nuclear Information System (INIS)
Zhao Yanmin; Dai Guidong; Tang Yifa; Liu Qinghuo
2009-01-01
Applying the spectral element method (SEM) based on the Gauss-Lobatto-Legendre (GLL) polynomial to discretize Maxwell's equations, we obtain a Poisson system or a Poisson system with at most a perturbation. For the system, we prove that any symplectic partitioned Runge-Kutta (PRK) method preserves the Poisson structure and its implied symplectic structure. Numerical examples show the high accuracy of SEM and the benefit of conserving energy due to the use of symplectic methods.
Rehman, Asad; Ali, Ishtiaq; Qamar, Shamsul
An upwind space-time conservation element and solution element (CE/SE) scheme is extended to numerically approximate the dusty gas flow model. Unlike central CE/SE schemes, the current method uses the upwind procedure to derive the numerical fluxes through the inner boundary of conservation elements. These upwind fluxes are utilized to calculate the gradients of flow variables. For comparison and validation, the central upwind scheme is also applied to solve the same dusty gas flow model. The suggested upwind CE/SE scheme resolves the contact discontinuities more effectively and preserves the positivity of flow variables in low density flows. Several case studies are considered and the results of upwind CE/SE are compared with the solutions of central upwind scheme. The numerical results show better performance of the upwind CE/SE method as compared to the central upwind scheme.
Directory of Open Access Journals (Sweden)
Asad Rehman
Full Text Available An upwind space-time conservation element and solution element (CE/SE scheme is extended to numerically approximate the dusty gas flow model. Unlike central CE/SE schemes, the current method uses the upwind procedure to derive the numerical fluxes through the inner boundary of conservation elements. These upwind fluxes are utilized to calculate the gradients of flow variables. For comparison and validation, the central upwind scheme is also applied to solve the same dusty gas flow model. The suggested upwind CE/SE scheme resolves the contact discontinuities more effectively and preserves the positivity of flow variables in low density flows. Several case studies are considered and the results of upwind CE/SE are compared with the solutions of central upwind scheme. The numerical results show better performance of the upwind CE/SE method as compared to the central upwind scheme. Keywords: Dusty gas flow, Solid particles, Upwind schemes, Rarefaction wave, Shock wave, Contact discontinuity
LIBS detection of heavy metal elements in liquid solutions by using wood pellet as sample matrix
International Nuclear Information System (INIS)
Wen Guanhong; Sun Duixiong; Su Maogen; Dong Chenzhong
2013-01-01
Laser-induced breakdown spectroscopy (LIBS) has been applied to the analysis of heavy metals in liquid sample. A new approach was presented to improve the detection limit and minimize the sample matrix effects, in which dried wood pellets absorbed the given amounts of Cr standard solutions and then were baked because they have stronger and rapid absorption properties for liquid samples as well as simple elemental compositions. In this work, we have taken a typical heavy metal Cr element as an example, and investigated the spectral feasibility of Cr solutions and dried wood pellets before and after absorbing Cr solutions at the same experimental conditions, respectively. The results were demonstrated to successfully produce a superior analytical response for heavy metal elements by using wood pellet as sample matrix according to obtained LOD of 0.07 ppm for Cr element in solutions. (author)
LIBS Detection of Heavy Metal Elements in Liquid Solutions by Using Wood Pellet as Sample Matrix
International Nuclear Information System (INIS)
Wen Guanhong; Sun Duixiong; Su Maogen; Dong Chenzhong
2014-01-01
Laser-induced breakdown spectroscopy (LIBS) has been applied to the analysis of heavy metals in liquid samples. A new approach was presented to lower the limit of detection (LOD) and minimize the sample matrix effects, in which dried wood pellets absorbed the given amounts of Cr standard solutions and then were baked because they have stronger and rapid absorption properties for liquid samples as well as simple elemental compositions. In this work, we have taken a typical heavy metal Cr element as an example, and investigated the spectral feasibility of Cr solutions and dried wood pellets before and after absorbing Cr solutions at the same experimental conditions. The results were demonstrated to successfully produce a superior analytical response for heavy metal elements by using wood pellet as sample matrix according to the obtained LOD of 0.07 ppm for Cr element in solutions
Application of finite element method in the solution of transport equation
International Nuclear Information System (INIS)
Maiorino, J.R.; Vieira, W.J.
1985-01-01
It is presented the application of finite element method in the solution of second order transport equation (self-adjoint) for the even parity flux. The angular component is treated by expansion in Legendre polinomials uncoupled of the spatial component, which is approached by an expansion in base functions, interpolated in each spatial element. (M.C.K.) [pt
International Nuclear Information System (INIS)
Soares, Eufemia Paez; Saiki, Mitiko; Wiebeck, Helio
2005-01-01
In the present study a radiometric method was established to determine the migration of elements from food plastic packagings to a simulated acetic acid solution. This radiometric method consisted of irradiating plastic samples with neutrons at IEA-R1 nuclear reactor for a period of 16 hours under a neutron flux of 10 12 n cm -2 s -1 and, then to expose them to the element migration into a simulated solution. The radioactivity of the activated elements transferred to the solutions was measured to evaluate the migration. The experimental conditions were: time of exposure of 10 days at 40 deg C and 3% acetic acid solution was used as simulated solution, according to the procedure established by the National Agency of Sanitary Monitoring (ANVISA). The migration study was applied for plastic samples from soft drink and juice packagings. The results obtained indicated the migration of elements Co, Cr and Sb. The advantage of this methodology was no need to analyse the blank of simulantes, as well as the use of high purity simulated solutions. Besides, the method allows to evaluate the migration of the elements into the food content instead of simulated solution. The detention limits indicated high sensitivity of the radiometric method. (author)
The intervals method: a new approach to analyse finite element outputs using multivariate statistics
Directory of Open Access Journals (Sweden)
Jordi Marcé-Nogué
2017-10-01
Full Text Available Background In this paper, we propose a new method, named the intervals’ method, to analyse data from finite element models in a comparative multivariate framework. As a case study, several armadillo mandibles are analysed, showing that the proposed method is useful to distinguish and characterise biomechanical differences related to diet/ecomorphology. Methods The intervals’ method consists of generating a set of variables, each one defined by an interval of stress values. Each variable is expressed as a percentage of the area of the mandible occupied by those stress values. Afterwards these newly generated variables can be analysed using multivariate methods. Results Applying this novel method to the biological case study of whether armadillo mandibles differ according to dietary groups, we show that the intervals’ method is a powerful tool to characterize biomechanical performance and how this relates to different diets. This allows us to positively discriminate between specialist and generalist species. Discussion We show that the proposed approach is a useful methodology not affected by the characteristics of the finite element mesh. Additionally, the positive discriminating results obtained when analysing a difficult case study suggest that the proposed method could be a very useful tool for comparative studies in finite element analysis using multivariate statistical approaches.
The intervals method: a new approach to analyse finite element outputs using multivariate statistics
De Esteban-Trivigno, Soledad; Püschel, Thomas A.; Fortuny, Josep
2017-01-01
Background In this paper, we propose a new method, named the intervals’ method, to analyse data from finite element models in a comparative multivariate framework. As a case study, several armadillo mandibles are analysed, showing that the proposed method is useful to distinguish and characterise biomechanical differences related to diet/ecomorphology. Methods The intervals’ method consists of generating a set of variables, each one defined by an interval of stress values. Each variable is expressed as a percentage of the area of the mandible occupied by those stress values. Afterwards these newly generated variables can be analysed using multivariate methods. Results Applying this novel method to the biological case study of whether armadillo mandibles differ according to dietary groups, we show that the intervals’ method is a powerful tool to characterize biomechanical performance and how this relates to different diets. This allows us to positively discriminate between specialist and generalist species. Discussion We show that the proposed approach is a useful methodology not affected by the characteristics of the finite element mesh. Additionally, the positive discriminating results obtained when analysing a difficult case study suggest that the proposed method could be a very useful tool for comparative studies in finite element analysis using multivariate statistical approaches. PMID:29043107
Sousa, A. N. Laurindo; Ojeda-González, A.; Prestes, A.; Klausner, V.; Caritá, L. A.
2018-02-01
This work aims to demonstrate the analytical solution of the Grad-Shafranov (GS) equation or generalized Ampere's law, which is important in the studies of self-consistent 2.5-D solution for current sheet structures. A detailed mathematical development is presented to obtain the generating function as shown by Walker (RSPSA 91, 410, 1915). Therefore, we study the general solution of the GS equation in terms of the Walker's generating function in details without omitting any step. The Walker's generating function g( ζ) is written in a new way as the tangent of an unspecified function K( ζ). In this trend, the general solution of the GS equation is expressed as exp(- 2Ψ) = 4| K '( ζ)|2/cos2[ K( ζ) - K( ζ ∗)]. In order to investigate whether our proposal would simplify the mathematical effort to find new generating functions, we use Harris's solution as a test, in this case K( ζ) = arctan(exp( i ζ)). In summary, one of the article purposes is to present a review of the Harris's solution. In an attempt to find a simplified solution, we propose a new way to write the GS solution using g( ζ) = tan( K( ζ)). We also present a new analytical solution to the equilibrium Ampere's law using g( ζ) = cosh( b ζ), which includes a generalization of the Harris model and presents isolated magnetic islands.
Use of the iterative solution method for coupled finite element and boundary element modeling
International Nuclear Information System (INIS)
Koteras, J.R.
1993-07-01
Tunnels buried deep within the earth constitute an important class geomechanics problems. Two numerical techniques used for the analysis of geomechanics problems, the finite element method and the boundary element method, have complementary characteristics for applications to problems of this type. The usefulness of combining these two methods for use as a geomechanics analysis tool has been recognized for some time, and a number of coupling techniques have been proposed. However, not all of them lend themselves to efficient computational implementations for large-scale problems. This report examines a coupling technique that can form the basis for an efficient analysis tool for large scale geomechanics problems through the use of an iterative equation solver
Solution microcalorimeter for measuring heats of solution of radioactive elements and compounds
International Nuclear Information System (INIS)
Raschella, D.L.
1978-12-01
The microcalorimeter vessel is constructed of tantalum metal, with a nominal volume of 5 cm 3 . Its energy equivalent is 24 J K -1 when containing 5 cm 3 H 2 O. The thermal leakage modulus is 0.010 min -1 . A thermistor is employed as the temperature sensor. The operating sensitivity is about 1 x 10 -5 K (300 μJ). The performance of the calorimetry system was tested using tris(hydroxymethyl)aminomethane (TRIS) and magnesium metal. The results of the TRIS experiments, at a concentration of 1 g dm -3 in 0.1 N HCl at 298 K, yielded a heat of solution of -29.606 +- 0.063 kJ mol -1 . The magnesium experiments, in 1 N HCl at 298 K, gave a heat of solution of -465.965 +- 1.136 kJ mol -1 . The heat of solution of curium-248 metal in 1 N HCl at 298 K was measured. The experiments, which should not be considered definitive, yielded a heat of solution of -606.4 +- 1.8 kJ mol -1 . A single measurement in 6 N HCl gave a heat of solution of -602.3 kJ mol -1 . From these results the heat of formation of Cm 3+ /sub (aq)/ is calculated to be -607.2 +- 2.5 kJ mol -1
On reactions of polymerization of p-element hydroxides in aqueous solutions
International Nuclear Information System (INIS)
Tikavyj, V.F.; Lesnikovich, A.I.
1978-01-01
The tendency of p-element hydroxides towards polymerization in aqueous solutions has been considered with respect to their location in the Periodic Table. Stable hydroxides of d-elements are practically all polymerized; among s-elements only berillium and magnesium hydroxides polymerize as the least dissociated ones. Hydroxides of the elements located to the right of the 4 Group and above the 5-th Period do not polymerize in aqueous solutions. The structure and tendency towards polymerization of In, Te, and I compounds have been studied. The tendency to polymerization of all hydroxides of p-elements located below the 4-th Period is explained from the standpoint of electron structure and the simplest thermodynamic analysis (entropy, enthalpy)
Distribution of trace elements between clays and zeolites and aqueous solutions similar to sea water
International Nuclear Information System (INIS)
Berger, G.
1992-01-01
The mechanisms of solid-solution partitioning during mineral crystallization in sea water have been investigated for Rb, Cs, Co, Sr, U, Th and lanthanides as trace elements, and Fe, Mg-chlorite/smectites and Na-zeolites as solid phases. These minerals have been synthesized by alteration at 40 o C in saline solutions of silicate glasses of appropriate compositions. The variation of the distribution coefficients (D) with the concentration of the elements as well as competition mechanisms between elements of analogous crystallochemical properties have been studied. The ''trapping'' of trace elements is shown to be governed by two mechanisms, according to D values or to water-rock ratios. At low values of D the incorporation of elements is controlled only by D, whereas at high values it is controlled by the number of available crystallochemical sites. (Author)
Effect of organic substrates on available elemental contents in nutrient solution
Energy Technology Data Exchange (ETDEWEB)
Ao, Y.S.; Sun, M.; Li, Y.Q. [Shanghai Jiao Tong University, Shanghai (China). School for Agriculture & Biology
2008-07-15
In this paper, the changes of available elemental contents in the nutrient solution extracts of organic substrates (peat moss, charred rice husk, chicken manure, sawdust, turfgrass clipping and weathered coal) were studied and compared with that in the water extracts. Results showed that available elemental contents in the nutrient solution extracts are significantly different between organic substrates, whereas ionic concentrations are basically under steady condition after treatment for 36-108 h. Ionic contents in the nutrient solution extracts are not equal to the value of adding ionic concentrations in the supplied nutrient solution to that in the water extract. Thus, a mathematical model was proposed for adjusting the composition of supplied nutrient solution to match plant requirements in the organic soilless culture system.
Isolation of transplutonium elements on ion exchangers from solutions of high salt concentration
International Nuclear Information System (INIS)
Guseva, L.I.; Tikhomirova, G.S.; Stepushkina, V.V.
1985-01-01
The behaviour of transplutonium elements (TPE) on cation and anion exchangers in aqueous alcoholic solutions of chlorides and nitrates of some alkali and alkaline earth metals depending on different factors: salt concentration, content of alcohol and of acid in the solution as well as the nature of a cation was studied. The data obtained were used to determine the optimal conditions of concentration of TPE on ion exchangers from solutions containing great quantities of salts. The advantages of the use of aqueous alcoholic solutions of nitric acid in the isolation of TPE are shown. (author)
Solution of the conjugated heat transfer problem for the fuel elements assemblies
International Nuclear Information System (INIS)
Golba, V.S.; Ivanenko, I.J.; Zinina, G.A.
1997-01-01
The paper presents the assemblies conjugated heat conductivity problem calculation and experimental method. The method is based on the temperature superposition modified concept and subchannel method and allows to predict the fuel elements surface temperatures with availability of fuel elements inside structure of any complication caused by technological and working defects and with availability of depositions with low heat conductivity on the fuel elements surfaces. According to the method developed the partial solutions of the heat conductivity equation at the heat removal boundaries (solid-liquid) are found separately for the fuel elements and for the liquid. The heat conductivity equation partial solutions for the fuel elements are predicted by calculations. The coolant heat conductivity equation partial solution ('influence functions') data massif is obtained in present work experimentally in the fuel assembly model consists of 7 tube bundle of fuel elements imitators placed in right grating with relative grating step equal to 1.1 and cooled by eutectic alloy Pb-Bi. It is shown that 'subchannel prediction method' decreases the crosswise heat transfer in comparison with crosswise heat transfer, when the fuel element inside structure is taken into account. Also in the paper it is shown that it is possible to realize the assembly temperature prediction method suggested without carrying out the experiments in the assembly's model in order to get the external problem influence functions'. (author)
Directory of Open Access Journals (Sweden)
Neng Wan
2014-01-01
Full Text Available In terms of the poor geometric adaptability of spline element method, a geometric precision spline method, which uses the rational Bezier patches to indicate the solution domain, is proposed for two-dimensional viscous uncompressed Navier-Stokes equation. Besides fewer pending unknowns, higher accuracy, and computation efficiency, it possesses such advantages as accurate representation of isogeometric analysis for object boundary and the unity of geometry and analysis modeling. Meanwhile, the selection of B-spline basis functions and the grid definition is studied and a stable discretization format satisfying inf-sup conditions is proposed. The degree of spline functions approaching the velocity field is one order higher than that approaching pressure field, and these functions are defined on one-time refined grid. The Dirichlet boundary conditions are imposed through the Nitsche variational principle in weak form due to the lack of interpolation properties of the B-splines functions. Finally, the validity of the proposed method is verified with some examples.
Blank, D. G.; Morgan, J.
2017-12-01
Large earthquakes that occur on convergent plate margin interfaces have the potential to cause widespread damage and loss of life. Recent observations reveal that a wide range of different slip behaviors take place along these megathrust faults, which demonstrate both their complexity, and our limited understanding of fault processes and their controls. Numerical modeling provides us with a useful tool that we can use to simulate earthquakes and related slip events, and to make direct observations and correlations among properties and parameters that might control them. Further analysis of these phenomena can lead to a more complete understanding of the underlying mechanisms that accompany the nucleation of large earthquakes, and what might trigger them. In this study, we use the discrete element method (DEM) to create numerical analogs to subduction megathrusts with heterogeneous fault friction. Displacement boundary conditions are applied in order to simulate tectonic loading, which in turn, induces slip along the fault. A wide range of slip behaviors are observed, ranging from creep to stick slip. We are able to characterize slip events by duration, stress drop, rupture area, and slip magnitude, and to correlate the relationships among these quantities. These characterizations allow us to develop a catalog of rupture events both spatially and temporally, for comparison with slip processes on natural faults.
Survey of meshless and generalized finite element methods: A unified approach
Babuška, Ivo; Banerjee, Uday; Osborn, John E.
In the past few years meshless methods for numerically solving partial differential equations have come into the focus of interest, especially in the engineering community. This class of methods was essentially stimulated by difficulties related to mesh generation. Mesh generation is delicate in many situations, for instance, when the domain has complicated geometry; when the mesh changes with time, as in crack propagation, and remeshing is required at each time step; when a Lagrangian formulation is employed, especially with nonlinear PDEs. In addition, the need for flexibility in the selection of approximating functions (e.g., the flexibility to use non-polynomial approximating functions), has played a significant role in the development of meshless methods. There are many recent papers, and two books, on meshless methods; most of them are of an engineering character, without any mathematical analysis.In this paper we address meshless methods and the closely related generalized finite element methods for solving linear elliptic equations, using variational principles. We give a unified mathematical theory with proofs, briefly address implementational aspects, present illustrative numerical examples, and provide a list of references to the current literature.The aim of the paper is to provide a survey of a part of this new field, with emphasis on mathematics. We present proofs of essential theorems because we feel these proofs are essential for the understanding of the mathematical aspects of meshless methods, which has approximation theory as a major ingredient. As always, any new field is stimulated by and related to older ideas. This will be visible in our paper.
Energy Technology Data Exchange (ETDEWEB)
Kim, S. [Purdue Univ., West Lafayette, IN (United States)
1994-12-31
Parallel iterative procedures based on domain decomposition techniques are defined and analyzed for the numerical solution of wave propagation by finite element and finite difference methods. For finite element methods, in a Lagrangian framework, an efficient way for choosing the algorithm parameter as well as the algorithm convergence are indicated. Some heuristic arguments for finding the algorithm parameter for finite difference schemes are addressed. Numerical results are presented to indicate the effectiveness of the methods.
Solution of two energy-group neutron diffusion equation by triangular elements
International Nuclear Information System (INIS)
Correia Filho, A.
1981-01-01
The application of the triangular finite elements of first order in the solution of two energy-group neutron diffusion equation in steady-state conditions is aimed at. The EFTDN (triangular finite elements in neutrons diffusion) computer code in FORTRAN IV language is developed. The discrete formulation of the diffusion equation is obtained applying the Galerkin method. The power method is used to solve the eigenvalues' problem and the convergence is accelerated through the use of Chebshev polynomials. For the equation systems solution the Gauss method is applied. The results of the analysis of two test-problems are presented. (Author) [pt
Mutual influences in solution spectroscopy of Fe, Ni Cr, Ti elements taken two by two
International Nuclear Information System (INIS)
Baudin, Guy; Henon, Genevieve
1960-01-01
The effect of third elements in solution spectroscopy has been studied for Fe, Ni Cr, Ti elements taken two by two. The existence of a linear relation Δc x /c x = f(c y ) between this effect and the third element concentration has been evidenced and opens interesting perspectives for the analysis of stainless steels. Reprint of a paper published in Comptes rendus des seances de l'Academie des Sciences, t. 250, p. 1463-1465, sitting of 22 February 1960 [fr
Energy Technology Data Exchange (ETDEWEB)
Reddy, J N; Chao, W C [Virginia Polytechnic Inst. and State Univ., Blacksburg (USA). Dept. of Engineering Science and Mechanics
1981-04-01
In this study the effects of reduced integration, mesh size, and element type (i.e. linear or quadratic) on the accuracy of a penalty-finite element based on the theory governing thick, laminated, anisotropic composite plates are investigated. In order to assess the accuracy of the present finite element, exact closed-form solutions are developed for cross-ply and antisymmetric angle-ply rectangular plates simply supported and subjected to sinusoidally distributed mechanical and/or thermal loadings, and free vibration.
Shen, Hua
2016-10-19
A maximum-principle-satisfying space-time conservation element and solution element (CE/SE) scheme is constructed to solve a reduced five-equation model coupled with the stiffened equation of state for compressible multifluids. We first derive a sufficient condition for CE/SE schemes to satisfy maximum-principle when solving a general conservation law. And then we introduce a slope limiter to ensure the sufficient condition which is applicative for both central and upwind CE/SE schemes. Finally, we implement the upwind maximum-principle-satisfying CE/SE scheme to solve the volume-fraction-based five-equation model for compressible multifluids. Several numerical examples are carried out to carefully examine the accuracy, efficiency, conservativeness and maximum-principle-satisfying property of the proposed approach.
Shen, Hua; Wen, Chih-Yung; Parsani, Matteo; Shu, Chi-Wang
2016-01-01
A maximum-principle-satisfying space-time conservation element and solution element (CE/SE) scheme is constructed to solve a reduced five-equation model coupled with the stiffened equation of state for compressible multifluids. We first derive a sufficient condition for CE/SE schemes to satisfy maximum-principle when solving a general conservation law. And then we introduce a slope limiter to ensure the sufficient condition which is applicative for both central and upwind CE/SE schemes. Finally, we implement the upwind maximum-principle-satisfying CE/SE scheme to solve the volume-fraction-based five-equation model for compressible multifluids. Several numerical examples are carried out to carefully examine the accuracy, efficiency, conservativeness and maximum-principle-satisfying property of the proposed approach.
Directory of Open Access Journals (Sweden)
José Miguel Vargas-Félix
2012-11-01
Full Text Available The Finite Element Method (FEM is used to solve problems like solid deformation and heat diffusion in domains with complex geometries. This kind of geometries requires discretization with millions of elements; this is equivalent to solve systems of equations with sparse matrices and tens or hundreds of millions of variables. The aim is to use computer clusters to solve these systems. The solution method used is Schur substructuration. Using it is possible to divide a large system of equations into many small ones to solve them more efficiently. This method allows parallelization. MPI (Message Passing Interface is used to distribute the systems of equations to solve each one in a computer of a cluster. Each system of equations is solved using a solver implemented to use OpenMP as a local parallelization method.The Finite Element Method (FEM is used to solve problems like solid deformation and heat diffusion in domains with complex geometries. This kind of geometries requires discretization with millions of elements; this is equivalent to solve systems of equations with sparse matrices and tens or hundreds of millions of variables. The aim is to use computer clusters to solve these systems. The solution method used is Schur substructuration. Using it is possible to divide a large system of equations into many small ones to solve them more efficiently. This method allows parallelization. MPI (Message Passing Interface is used to distribute the systems of equations to solve each one in a computer of a cluster. Each system of equations is solved using a solver implemented to use OpenMP as a local parallelization method.
Finite-element solutions of the AER-2 rod ejection benchmark by CRONOS
International Nuclear Information System (INIS)
Kolev, N.P.; Lenain, R.; Fedon-Magnaud, C.
2001-01-01
The finite-element option in CRONOS was used to analyse the AER-2 rod-ejection benchmark for WWER-440. The objective is to obtain spatially converged solutions by means of node subdivision and approximation refinement. This paper presents the first phase of analysis dealing with the initial and just-ejected states used for calculation of the initial reactivity. Fine-mesh and extrapolated to zero mesh size solutions were obtained and verified by comparison to MAG code solutions. These differences provide potential for large deviations in the transient results and deserve further attention in reactor safety analysis (Authors)
Solution of Fokker–Planck equation by finite element and finite ...
Indian Academy of Sciences (India)
The response of a structural system to white noise excitation (delta-correlated) constitutes a Markov vector process whose transitional probability density function (TPDF) is governed by both the forward Fokker–Planck and backward Kolmogorov equations. Numerical solution of these equations by ﬁnite element and ﬁnite ...
Saturated salt solution method: a useful cadaver embalming for surgical skills training.
Hayashi, Shogo; Homma, Hiroshi; Naito, Munekazu; Oda, Jun; Nishiyama, Takahisa; Kawamoto, Atsuo; Kawata, Shinichi; Sato, Norio; Fukuhara, Tomomi; Taguchi, Hirokazu; Mashiko, Kazuki; Azuhata, Takeo; Ito, Masayuki; Kawai, Kentaro; Suzuki, Tomoya; Nishizawa, Yuji; Araki, Jun; Matsuno, Naoto; Shirai, Takayuki; Qu, Ning; Hatayama, Naoyuki; Hirai, Shuichi; Fukui, Hidekimi; Ohseto, Kiyoshige; Yukioka, Tetsuo; Itoh, Masahiro
2014-12-01
This article evaluates the suitability of cadavers embalmed by the saturated salt solution (SSS) method for surgical skills training (SST). SST courses using cadavers have been performed to advance a surgeon's techniques without any risk to patients. One important factor for improving SST is the suitability of specimens, which depends on the embalming method. In addition, the infectious risk and cost involved in using cadavers are problems that need to be solved. Six cadavers were embalmed by 3 methods: formalin solution, Thiel solution (TS), and SSS methods. Bacterial and fungal culture tests and measurement of ranges of motion were conducted for each cadaver. Fourteen surgeons evaluated the 3 embalming methods and 9 SST instructors (7 trauma surgeons and 2 orthopedists) operated the cadavers by 21 procedures. In addition, ultrasonography, central venous catheterization, and incision with cauterization followed by autosuture stapling were performed in some cadavers. The SSS method had a sufficient antibiotic effect and produced cadavers with flexible joints and a high tissue quality suitable for SST. The surgeons evaluated the cadavers embalmed by the SSS method to be highly equal to those embalmed by the TS method. Ultrasound images were clear in the cadavers embalmed by both the methods. Central venous catheterization could be performed in a cadaver embalmed by the SSS method and then be affirmed by x-ray. Lungs and intestines could be incised with cauterization and autosuture stapling in the cadavers embalmed by TS and SSS methods. Cadavers embalmed by the SSS method are sufficiently useful for SST. This method is simple, carries a low infectious risk, and is relatively of low cost, enabling a wider use of cadavers for SST.
Anion-exchange Studies of Radioactive Trace Elements in Sulphuric Acid Solutions
Energy Technology Data Exchange (ETDEWEB)
Samsahl, K
1963-01-15
As part of a chemical group separation procedure used as a pretreatment in gamma spectrometric analysis, a study has been made of the adsorption from sulphuric acid solutions on strongly basic anion exchange resins, prepared in the hydroxide and the sulphate forms, of trace activities of Na, P, K, Ca, Sc, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Rb, Sr, Zr, Nb, Mo, Tc, Ag, Cd, In, Cs, Ba, La, Ce, Hf, Ta, W, Ir, Pa and Np. Besides adsorbing some of the trace elements in the solution, the anion exchange resin in the hydroxide form will neutralize the bulk of the sulphuric acid. This makes possible the subsequent sequential separation of chloride complexes on short anion-exchange columns by a stepwise increasing of the HCl concentration of the solution. On the basis of the results obtained in the present and earlier experiments, a new improved chemical group-separation procedure for mixtures of radioactive trace elements is outlined.
Numerical solution of multi group-Two dimensional- Adjoint equation with finite element method
International Nuclear Information System (INIS)
Poursalehi, N.; Khalafi, H.; Shahriari, M.; Minoochehr
2008-01-01
Adjoint equation is used for perturbation theory in nuclear reactor design. For numerical solution of adjoint equation, usually two methods are applied. These are Finite Element and Finite Difference procedures. Usually Finite Element Procedure is chosen for solving of adjoint equation, because it is more use able in variety of geometries. In this article, Galerkin Finite Element method is discussed. This method is applied for numerical solving multi group, multi region and two dimensional (X, Y) adjoint equation. Typical reactor geometry is partitioned with triangular meshes and boundary condition for adjoint flux is considered zero. Finally, for a case of defined parameters, Finite Element Code was applied and results were compared with Citation Code
Fundamental solutions and dual boundary element methods for fracture in plane Cosserat elasticity.
Atroshchenko, Elena; Bordas, Stéphane P A
2015-07-08
In this paper, both singular and hypersingular fundamental solutions of plane Cosserat elasticity are derived and given in a ready-to-use form. The hypersingular fundamental solutions allow to formulate the analogue of Somigliana stress identity, which can be used to obtain the stress and couple-stress fields inside the domain from the boundary values of the displacements, microrotation and stress and couple-stress tractions. Using these newly derived fundamental solutions, the boundary integral equations of both types are formulated and solved by the boundary element method. Simultaneous use of both types of equations (approach known as the dual boundary element method (BEM)) allows problems where parts of the boundary are overlapping, such as crack problems, to be treated and to do this for general geometry and loading conditions. The high accuracy of the boundary element method for both types of equations is demonstrated for a number of benchmark problems, including a Griffith crack problem and a plate with an edge crack. The detailed comparison of the BEM results and the analytical solution for a Griffith crack and an edge crack is given, particularly in terms of stress and couple-stress intensity factors, as well as the crack opening displacements and microrotations on the crack faces and the angular distributions of stresses and couple-stresses around the crack tip.
International Nuclear Information System (INIS)
Vaganov, P.A.; Kol'tsov, A.A.; Kulikov, V.D.; Mejer, V.A.
1983-01-01
The multi-element instrumental neutron activation analysis of samples of mountain rocks (sandstones, aleurolites and shales of one of gold deposits) is performed. The spectra of irradiated samples are measured by Ge(Li) detector of the volume of 35 mm 3 . The content of 22 chemical elements is determined in each sample. The results of analysis serve as reliable basis for multi-dimensional statistic information processing, they constitute the basis for the generalized characteristics of rocks which brings about the solution of classification problem for rocks of different deposits
Energy Technology Data Exchange (ETDEWEB)
Fischer, P.F. [Brown Univ., Providence, RI (United States)
1996-12-31
Efficient solution of the Navier-Stokes equations in complex domains is dependent upon the availability of fast solvers for sparse linear systems. For unsteady incompressible flows, the pressure operator is the leading contributor to stiffness, as the characteristic propagation speed is infinite. In the context of operator splitting formulations, it is the pressure solve which is the most computationally challenging, despite its elliptic origins. We seek to improve existing spectral element iterative methods for the pressure solve in order to overcome the slow convergence frequently observed in the presence of highly refined grids or high-aspect ratio elements.
International Nuclear Information System (INIS)
Choi, C. Y.; Park, C. T.; Kim, T. H.; Han, K. N.; Choe, S. H.
1995-01-01
A geometrical inverse heat conduction problem is solved for the development of Infrared Computerized-Axial-Tomography (IR CAT) Scan by using a boundary element method in conjunction with regularization procedure. In this problem, an overspecified temperature condition by infrared scanning is provided on the surface, and is used together with other conditions to solve the position of an unknown boundary (cavity). An auxiliary problem is introduced in the solution of this problem. By defining a hypothetical inner boundary for the auxiliary problem domain, the cavity is located interior to the domain and its position is determined by solving a potential problem. Boundary element method with regularization procedure is used to solve this problem, and the effects of regularization on the inverse solution method are investigated by means of numerical analysis
Susana, Apriliani Dewi; Titus, Amol
2013-01-01
This study aims at identifying key issues in SR franchise business along the six elements of marketing mix: people, partner, place, product, promotion, and price, and then propose solution recommendations for the identified issues. Data is collected through a method of in-depth interviews with key SR stakeholders, internally and externally, namely end customers, SR personnels, and SR franchisees. Issues identified are mapped into a Problem Tree Analysis diagram to determine causal relations...
Energy Technology Data Exchange (ETDEWEB)
Gourisse, D. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1966-09-01
A review of the kinetics of U, Np, Pu, Am oxidation-reduction reactions is proposed. The relations between the different activation thermodynamic functions (compensatory effect, formal entropy of the activated complex, magnitude of reactions velocities) are considered. The effects of acidity, ionic strength deuterium and mixed solvents polarity on reactions rates are described. The effect of different anions on reactions rates are explained by variations of the reaction standard free energy and variations of the activation free energy (coulombic interactions) resulting from the complexation of dissolved species by these anions. (author) [French] Une revue systematique de la cinetique des reactions d'oxydo-reduction des elements U, Np, Pu, Am, en solution perchlorique est proposee. Des considerations relatives aux grandeurs thermodynamiques d'activation associees aux actes elementaires (effet de compensation, entropie standard des complexes actives, rapidite des reactions) sont developpees. L'influence de l'acidite, de la force ionique, de l'eau lourde et de la polarite des solvants mixtes sur la vitesse des reactions est decrite. Enfin l'influence des differents anions sur la vitesse des reactions est expliquee par les variations de l'enthalpie libre standard de la reaction et de l'enthalpie libre d'activation (travail des forces electrostatiques) resultant de la complexation des especes dissoutes dans la solution. (auteur)
Energy Technology Data Exchange (ETDEWEB)
Gourisse, D [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1966-09-01
A review of the kinetics of U, Np, Pu, Am oxidation-reduction reactions is proposed. The relations between the different activation thermodynamic functions (compensatory effect, formal entropy of the activated complex, magnitude of reactions velocities) are considered. The effects of acidity, ionic strength deuterium and mixed solvents polarity on reactions rates are described. The effect of different anions on reactions rates are explained by variations of the reaction standard free energy and variations of the activation free energy (coulombic interactions) resulting from the complexation of dissolved species by these anions. (author) [French] Une revue systematique de la cinetique des reactions d'oxydo-reduction des elements U, Np, Pu, Am, en solution perchlorique est proposee. Des considerations relatives aux grandeurs thermodynamiques d'activation associees aux actes elementaires (effet de compensation, entropie standard des complexes actives, rapidite des reactions) sont developpees. L'influence de l'acidite, de la force ionique, de l'eau lourde et de la polarite des solvants mixtes sur la vitesse des reactions est decrite. Enfin l'influence des differents anions sur la vitesse des reactions est expliquee par les variations de l'enthalpie libre standard de la reaction et de l'enthalpie libre d'activation (travail des forces electrostatiques) resultant de la complexation des especes dissoutes dans la solution. (auteur)
High-precision solution to the moving load problem using an improved spectral element method
Wen, Shu-Rui; Wu, Zhi-Jing; Lu, Nian-Li
2018-02-01
In this paper, the spectral element method (SEM) is improved to solve the moving load problem. In this method, a structure with uniform geometry and material properties is considered as a spectral element, which means that the element number and the degree of freedom can be reduced significantly. Based on the variational method and the Laplace transform theory, the spectral stiffness matrix and the equivalent nodal force of the beam-column element are established. The static Green function is employed to deduce the improved function. The proposed method is applied to two typical engineering practices—the one-span bridge and the horizontal jib of the tower crane. The results have revealed the following. First, the new method can yield extremely high-precision results of the dynamic deflection, the bending moment and the shear force in the moving load problem. In most cases, the relative errors are smaller than 1%. Second, by comparing with the finite element method, one can obtain the highly accurate results using the improved SEM with smaller element numbers. Moreover, the method can be widely used for statically determinate as well as statically indeterminate structures. Third, the dynamic deflection of the twin-lift jib decreases with the increase in the moving load speed, whereas the curvature of the deflection increases. Finally, the dynamic deflection, the bending moment and the shear force of the jib will all increase as the magnitude of the moving load increases.
SOLUTION OF TRANSIENT HEAT CONDUCTION PROBLEM BY THE FINITE ELEMENT METHOD
Directory of Open Access Journals (Sweden)
Süleyman TAŞGETİREN
1995-01-01
Full Text Available Determination of temperature distribution is generally the first step in the design of machine elements subjected to ubnormal temperatures in their service life and for selection of materials. During this heat transfer analysis, the boundary and enviromental conditions must be modeled realistically and the geometry must be well represented. A variety of materials deviating from simple constant property isotropic material to composit materials having different properties according to direction of reinforcements are to be analysed. Then, the finite element method finds a large application area due to its use of same notation in heat transfer analysis and mechanical analysis of elements. In this study, the general formulation of two dimensional transient heat conduction is developed and a sample solution is given for arectangular bar subjected to convection baundary condition.
TRIP: a finite element computer program for the solution of convection heat transfer problems
International Nuclear Information System (INIS)
Slagter, W.; Roodbergen, H.A.
1976-01-01
The theory and use of the finite element code TRIP are described. The code calculates temperature distributions in three-dimensional continua subjected to convection heat transfer. A variational principle for transport phenomena is applied to solve the convection heat transfer problem with temperature and heat flux boundary conditions. The finite element discretization technique is used to reduce the continuous spatial solution into a finite number of unknowns. The method is developed in detail to determine temperature distributions in coolant passages of fuel rod bundles which are idealized by hexahedral elements. The development of the TRIP code is discussed and the listing of the program is given in FORTRAN IV. An example is given to illustrate the validity and practicality of the method
International Nuclear Information System (INIS)
Calabrese, C.R.; Grant, C.R.
1990-01-01
This work presents comparisons between measured fluxes obtained by activation of Manganese foils in the light water, enriched uranium research pool reactor RA-2 MTR (Materials Testing Reactors) fuel element) and fluxes calculated by the finite element method FEM using DELFIN code, and describes the heterogeneus finite elements by a set of solutions of the transport equations for several different configurations obtained using the collision probability code HUEMUL. The agreement between calculated and measured fluxes is good, and the advantage of using FEM is showed because to obtain the flux distribution with same detail using an usual diffusion calculation it would be necessary 12000 mesh points against the 2000 points that FEM uses, hence the processing time is reduced in a factor ten. An interesting alternative to use in MTR fuel management is presented. (Author) [es
International Nuclear Information System (INIS)
Tachimori, Shoichi
1990-02-01
A mathematical model of chemical reactions with actinide elements: REACT code, was developed to simulate change of valency states of U, Pu and Np in the aqueous nitric acid solution. Twenty seven rate equations for the redox reactions involving some reductants, disproportionation reactions, and radiolytic growth and decay reaction of nitrous acid were programmed in the code . Eight numerical solution methods such as Porsing method to solve the rate equations were incorporated parallel as options depending on the characteristics of the reaction systems. The present report gives a description of the REACT code, e.g., chemical reactions and their rate equations, numerical solution methods, and some examples of the calculation results. A manual and a source file of the program was attached to the appendix. (author)
International Nuclear Information System (INIS)
Koteras, J.R.
1996-01-01
The prediction of stresses and displacements around tunnels buried deep within the earth is an important class of geomechanics problems. The material behavior immediately surrounding the tunnel is typically nonlinear. The surrounding mass, even if it is nonlinear, can usually be characterized by a simple linear elastic model. The finite element method is best suited for modeling nonlinear materials of limited volume, while the boundary element method is well suited for modeling large volumes of linear elastic material. A computational scheme that couples the finite element and boundary element methods would seem particularly useful for geomechanics problems. A variety of coupling schemes have been proposed, but they rely on direct solution methods. Direct solution techniques have large storage requirements that become cumbersome for large-scale three-dimensional problems. An alternative to direct solution methods is iterative solution techniques. A scheme has been developed for coupling the finite element and boundary element methods that uses an iterative solution method. This report shows that this coupling scheme is valid for problems where nonlinear material behavior occurs in the finite element region
Allen, Phillip A.; Wells, Douglas N.
2013-01-01
No closed form solutions exist for the elastic-plastic J-integral for surface cracks due to the nonlinear, three-dimensional nature of the problem. Traditionally, each surface crack must be analyzed with a unique and time-consuming nonlinear finite element analysis. To overcome this shortcoming, the authors have developed and analyzed an array of 600 3D nonlinear finite element models for surface cracks in flat plates under tension loading. The solution space covers a wide range of crack shapes and depths (shape: 0.2 less than or equal to a/c less than or equal to 1, depth: 0.2 less than or equal to a/B less than or equal to 0.8) and material flow properties (elastic modulus-to-yield ratio: 100 less than or equal to E/ys less than or equal to 1,000, and hardening: 3 less than or equal to n less than or equal to 20). The authors have developed a methodology for interpolating between the goemetric and material property variables that allows the user to reliably evaluate the full elastic-plastic J-integral and force versus crack mouth opening displacement solution; thus, a solution can be obtained very rapidly by users without elastic-plastic fracture mechanics modeling experience. Complete solutions for the 600 models and 25 additional benchmark models are provided in tabular format.
International Nuclear Information System (INIS)
Tsuruta, T.
2006-01-01
The effects of proton, thorium and uranium on the bioaccumulation of thorium and uranium from the solution (pH 3.5) containing uranium and thorium using Streptomyces levoris cells were examined. The amount of thorium accumulated using the cells decreased by the pre-contact between the cells and the solution (pH 3.5) containing no metals, whereas that of uranium was almost unaffected by the treatment. The amount of thorium was almost unaffected by the existence of uranium. On the other hand, the amount of uranium accumulated was strongly affected by the thorium, especially thorium addition after uranium accumulation. The decrease of uranium accumulated by the addition of thorium after the accumulation of uranium was higher than that from the solution containing both elements. Therefore, the contribution of uranium-thorium exchange reaction was higher than that of competition reaction. Accordingly, proton-uranium-thorium exchange reaction was occurred in the accumulation of thorium from the solution containing thorium and uranium. The gram-positive bacteria, such as Micrococcus luteus, Arthrobacter nicotianae, Bacillus subtilis and B. megaterium, has a much higher separation factor as thorium/uranium than that of actinomycetes. These gram-positive bacterial strains can be used for the accumulation of thorium from the solution containing uranium and thorium
Bakker, Mark
2010-08-01
A new analytic solution approach is presented for the modeling of steady flow to pumping wells near rivers in strip aquifers; all boundaries of the river and strip aquifer may be curved. The river penetrates the aquifer only partially and has a leaky stream bed. The water level in the river may vary spatially. Flow in the aquifer below the river is semi-confined while flow in the aquifer adjacent to the river is confined or unconfined and may be subject to areal recharge. Analytic solutions are obtained through superposition of analytic elements and Fourier series. Boundary conditions are specified at collocation points along the boundaries. The number of collocation points is larger than the number of coefficients in the Fourier series and a solution is obtained in the least squares sense. The solution is analytic while boundary conditions are met approximately. Very accurate solutions are obtained when enough terms are used in the series. Several examples are presented for domains with straight and curved boundaries, including a well pumping near a meandering river with a varying water level. The area of the river bottom where water infiltrates into the aquifer is delineated and the fraction of river water in the well water is computed for several cases.
Effect of solute elements in Ni alloys on blistering under He + and D + ion irradiation
Wakai, E.; Ezawa, T.; Takenaka, T.; Imamura, J.; Tanabe, T.; Oshima, R.
2007-08-01
Effects of solute atoms on microstructural evolution and blister formation have been investigated using Ni alloys under 25 keV He + and 20 keV D + irradiation at 500 °C to a dose of about 4 × 10 21 ions/m 2. The specimens used were pure Ni, Ni-Si, Ni-Co, Ni-Cu, Ni-Mn and Ni-Pd alloys. The volume size factors of solute elements for the Ni alloys range from -5.8% to +63.6%. The formations of blisters were observed in the helium-irradiated specimens, but not in the deuteron-irradiated specimens. The areal number densities of blisters increased with volume size difference of solute atoms. The dependence of volume size on the areal number densities of blisters was very similar to that of the number densities of bubbles on solute atoms. The size of the blisters inversely decreased with increasing size of solute atoms. The formation of blisters was intimately related to the bubble growth, and the gas pressure model for the formation of blisters was supported by this study.
Finite element simulation of moisture movement and solute transport in a large caisson
International Nuclear Information System (INIS)
Huyakorn, P.S.; Jones, B.G.; Parker, J.C.; Wadsworth, T.D.; White, H.O. Jr.
1987-01-01
The results of the solute transport experiments performed on compacted, crushed Bandelier Tuff in caisson B of the experimental cluster described by DePoorter (1981) are simulated. Both one- and three-dimensional simulations of solute transport have been performed using two selected finite element codes. Results of bromide and iodide tracer experiments conducted during near-steady flow conditions have been analyzed for pulse additions made on December 6, 1984, and followed over a period of up to 60 days. In addition, a pulse addition of nonconservative strontium tracer on September 28, 1984, during questionably steady flow conditions has been analyzed over a period of 240 days. One-dimensional finite element flow and transport simulations were carried out assuming the porous medium to be homogeneous and the injection source uniformly distributed. To evaluate effects of the nonuniform source distribution and also to investigate effects of inhomogeneous porous medium properties, three dimensional finite element analyses of transport were carried out. Implications of the three-dimensional effects for the design and analysis of future tracer studies are discussed
Finite element method solution of simplified P3 equation for flexible geometry handling
International Nuclear Information System (INIS)
Ryu, Eun Hyun; Joo, Han Gyu
2011-01-01
In order to obtain efficiently core flux solutions which would be much closer to the transport solution than the diffusion solution is, not being limited by the geometry of the core, the simplified P 3 (SP 3 ) equation is solved with the finite element method (FEM). A generic mesh generator, GMSH, is used to generate linear and quadratic mesh data. The linear system resulting from the SP 3 FEM discretization is solved by Krylov subspace methods (KSM). A symmetric form of the SP 3 equation is derived to apply the conjugate gradient method rather than the KSMs for nonsymmetric linear systems. An optional iso-parametric quadratic mapping scheme, which is to selectively model nonlinear shapes with a quadratic mapping to prevent significant mismatch in local domain volume, is also implemented for efficient application of arbitrary geometry handling. The gain in the accuracy attainable by the SP 3 solution over the diffusion solution is assessed by solving numerous benchmark problems having various core geometries including the IAEA PWR problems involving rectangular fuels and the Takeda fast reactor problems involving hexagonal fuels. The reference transport solution is produced by the McCARD Monte Carlo code and the multiplication factor and power distribution errors are assessed. In addition, the effect of quadratic mapping is examined for circular cell problems. It is shown that significant accuracy gain is possible with the SP 3 solution for the fast reactor problems whereas only marginal improvement is noted for thermal reactor problems. The quadratic mapping is also quite effective handling geometries with curvature. (author)
A study on removal of elemental mercury in flue gas using fenton solution
International Nuclear Information System (INIS)
Liu, Yangxian; Wang, Yan; Wang, Qian; Pan, Jianfeng; Zhang, Yongchun; Zhou, Jianfei; Zhang, Jun
2015-01-01
Highlights: • A novel technique on oxidation of Hg 0 using Fenton was proposed. • The effects of several process parameters on Hg 0 removal were studied. • Products and ·OH in solution were detected. • Reaction mechanism of Hg 0 removal was studied. • Simultaneous removal of Hg 0 , NO and SO 2 was also studied. - Abstract: A novel technique on oxidation-separation of elemental mercury (Hg 0 ) in flue gas using Fenton solution in a bubbling reactor was proposed. The effects of several process parameters (H 2 O 2 concentration, Hg 0 inlet concentration, Fe 2+ concentration, solution temperature, solution pH, gas flow) and several flue gas components (NO, SO 2 , O 2 , CO 2 , inorganic ions and particulate matters on Hg 0 removal were studied. The results indicate that H 2 O 2 concentration, Fe 2+ concentration, solution pH and gas flow have great effects on Hg 0 removal. Solution temperature, Hg 0 , NO, SO 2 , CO 3 2− and HCO 3 − concentrations also have significant effects on Hg 0 removal. However, Cl − , SO 4 2− , NO 3 − , O 2 and CO 2 concentrations only have slight effects on Hg 0 removal. Furthermore, reaction mechanism of Hg 0 removal and simultaneous removal process of Hg 0 , NO and SO 2 were also studied. Hg 0 is removed by oxidation of ·OH and oxidation of H 2 O 2 . The simultaneous removal efficiencies of 100% for SO 2 , 100% for Hg 0 and 88.3% for NO were obtained under optimal test conditions. The results demonstrated the feasibility of Hg 0 removal and simultaneous removal of Hg 0 , SO 2 and NO using Fenton solution in a bubbling reactor
A three-dimensional spectral element model for the solution of the hydrostatic primitive equations
Iskandarani, M; Levin, J C
2003-01-01
We present a spectral element model to solve the hydrostatic primitive equations governing large-scale geophysical flows. The highlights of this new model include unstructured grids, dual h-p paths to convergence, and good scalability characteristics on present day parallel computers including Beowulf-class systems. The behavior of the model is assessed on three process-oriented test problems involving wave propagation, gravitational adjustment, and nonlinear flow rectification, respectively. The first of these test problems is a study of the convergence properties of the model when simulating the linear propagation of baroclinic Kelvin waves. The second is an intercomparison of spectral element and finite-difference model solutions to the adjustment of a density front in a straight channel. Finally, the third problem considers the comparison of model results to measurements obtained from a laboratory simulation of flow around a submarine canyon. The aforementioned tests demonstrate the good performance of th...
Value assignment and uncertainty evaluation for single-element reference solutions
Possolo, Antonio; Bodnar, Olha; Butler, Therese A.; Molloy, John L.; Winchester, Michael R.
2018-06-01
A Bayesian statistical procedure is proposed for value assignment and uncertainty evaluation for the mass fraction of the elemental analytes in single-element solutions distributed as NIST standard reference materials. The principal novelty that we describe is the use of information about relative differences observed historically between the measured values obtained via gravimetry and via high-performance inductively coupled plasma optical emission spectrometry, to quantify the uncertainty component attributable to between-method differences. This information is encapsulated in a prior probability distribution for the between-method uncertainty component, and it is then used, together with the information provided by current measurement data, to produce a probability distribution for the value of the measurand from which an estimate and evaluation of uncertainty are extracted using established statistical procedures.
On the application of finite element method in the solution of steady state diffusion equation
International Nuclear Information System (INIS)
Ono, S.
1982-01-01
The solution of the steady state neutron diffusion equation is obtained by using the finite element method. Specifically the variational approach is used for one dimensional problems and the weighted residual method (Galerkin) for one and two dimensional problems. The spatial domain is divided into retangular elements and the neutron flux is approximated by linear (one dimensional case), and bilinear (two-dimensional case) functions. Numerical results are obtained with a FORTRAN IV computer program and compared with those obtained by the finite difference CITATION code. The results show that linear or bilinear functions, do not satisfactorily describe the differential parameters in highly heterogeneous reactor cases, but provide good results for integral parameters such as multiplication factor. (Author) [pt
Energy Technology Data Exchange (ETDEWEB)
Cwik, T. [California Institute of Technology, Pasadena, CA (United States); Katz, D.S. [Cray Research, El Segundo, CA (United States)
1996-12-31
Finite element modeling has proven useful for accurately simulating scattered or radiated electromagnetic fields from complex three-dimensional objects whose geometry varies on the scale of a fraction of an electrical wavelength. An unstructured finite element model of realistic objects leads to a large, sparse, system of equations that needs to be solved efficiently with regard to machine memory and execution time. Both factorization and iterative solvers can be used to produce solutions to these systems of equations. Factorization leads to high memory requirements that limit the electrical problem size of three-dimensional objects that can be modeled. An iterative solver can be used to efficiently solve the system without excessive memory use and in a minimal amount of time if the convergence rate is controlled.
International Nuclear Information System (INIS)
Guseva, L.I.; Tikhomirova, G.S.
1984-01-01
The behaviour of Am, Cm, Pu and certain fragment elements (Cs, Sr, Y, Zr, Nb, Ru, Eu) on cationite dauex-50 in aqueous and aqueous-alcohol solutions of HCl and HNO 3 has been studied. Dependences of distribution coefficients and separation factors of the elements on the acid concentration and alcohol content in the solutions are presented. The sorption of TPE by cationite from HCl and HNO 3 solutions in the presence of alcohol is shown to increase over the range of concentrations studied (from 0.5 mol/L to 4-5 mol/L), which is explained by the salting-out effect of alcohol. The distribution coefficients of TPE in the solutions, containing >= 50% alcohol, constitute >= 10 2 . The distribution coefficients of the fragment elements in the presence of alcohol also increase, but to a considerably lesser extent, which results in a better separation. The study of the washing-out curves has shown that, to separate TPE from fragment elements on cationites, both HCl and HNO 3 solutions can be used, at that, in the case of aqueous solutions a better separation is attained at acid concentration, equal to 1 mol/L, and in the case of eluating by aqueous-alcohol solutions a good separation is achieved at hig-her concentrations of the acids as well
Abdrassilova, Gulnara S.
2017-09-01
In the context of development of the agriculture as the driver of the economy of Kazakhstan it is imperative to study new types of agrarian constructions (agroparks, agrotourists complexes, "vertical" farms, conservatories, greenhouses) that can be combined into complexes - agrarian technoparks. Creation of agrarian technoparks as elements of the infrastructure of the agglomeration shall ensure the breakthrough in the field of agrarian goods production, storing and recycling. Modeling of architectural-planning solutions of agrarian technoparks supports development of the theory and practice of designing objects based on innovative approaches.
Solution of three-dimensional energy equation using finite element method
International Nuclear Information System (INIS)
Bhasin, V.; Singh, R.K.; Dutta, B.K.; Kushwaha, H.S.
1993-01-01
In the present work an attempt has been made to formulate an efficient 3-D finite element program for solving coupled momentum-energy equation with unsymmetric frontal solver and a suitable upwinding scheme. Based on the above solution technique of energy equation it can be concluded that upwinding scheme can lead to fairly accurate and smooth results even with coarse mesh. Otherwise the mesh size requirement will be extremely stringent for most of the practical problems. With upwinding the additional computer time required is marginally more. This effort has resulted in getting practical solution for large size real life problems in nuclear industry. The program was used for computation of temperature field in heavy water moderator of Madras Atomic Power Station (MAPS) reactor, in new mode of operation. (author). 9 refs., 7 figs
Formulation of natural convection around repository for dual reciprocity boundary element solution
International Nuclear Information System (INIS)
Vrankar, L.; Sarler, B.
1998-01-01
The disposal of high-level radioactive wastes in deep geological formations is of pronounced technological importance for nuclear safety. The understanding of related fluid flow, heat and mass transport in geological systems is of great interest. This article prepares necessary physical, mathematical and numerical fundamentals for computational modeling of related phenomena. The porous media is described by the simple Darcy law and momentum-energy coupling is due to Boussinesq approximation. The Dual Reciprocity of Boundary Element Method (DRBEM) is used for solving coupled mass, momentum and energy equations in two-dimensions for the steady buoyancy induced convection problem in an semi-infinite porous media. It is structured by weighting with the fundamental solution of the Laplace equation. The inverse multi quadrics are used in the DRBEM transformation. The solution is obtained in an iterative way.(author)
International Nuclear Information System (INIS)
Hutchinson, S.; Costillo, S.; Dalton, K.; Hensel, E.
1990-01-01
A study is conducted of the finite element solution of the partial differential equations governing two-dimensional electromagnetic field scattering problems on a SIMD computer. A nodal assembly technique is introduced which maps a single node to a single processor. The physical domain is first discretized in parallel to yield the node locations of an O-grid mesh. Next, the system of equations is assembled and then solved in parallel using a conjugate gradient algorithm for complex-valued, non-symmetric, non-positive definite systems. Using this technique and Thinking Machines Corporation's Connection Machine-2 (CM-2), problems with more than 250k nodes are solved. Results of electromagnetic scattering, governed by the 2-d scalar Hemoholtz wave equations are presented in this paper. Solutions are demonstrated for a wide range of objects. A summary of performance data is given for the set of test problems
Solution of the inverse scattering problem at fixed energy with non-physical S matrix elements
International Nuclear Information System (INIS)
Eberspaecher, M.; Amos, K.; Apagyi, B.
1999-12-01
The quantum mechanical inverse elastic scattering problem is solved with the modified Newton-Sabatier method. A set of S matrix elements calculated from a realistic analytic optical model potential serves as input data. It is demonstrated that the quality of the inversion potential can be improved by including non-physical S matrix elements to half, quarter and eighth valued partial waves if the original set does not contain enough information to determine the interaction potential. We demonstrate that results can be very sensitive to the choice of those non-physical S matrix values both with the analytic potential model and in a real application in which the experimental cross section for the symmetrical scattering system of 12 C+ 12 C at E=7.998 MeV is analyzed
Directory of Open Access Journals (Sweden)
Liquan Mei
2014-01-01
Full Text Available A Galerkin method for a modified regularized long wave equation is studied using finite elements in space, the Crank-Nicolson scheme, and the Runge-Kutta scheme in time. In addition, an extrapolation technique is used to transform a nonlinear system into a linear system in order to improve the time accuracy of this method. A Fourier stability analysis for the method is shown to be marginally stable. Three invariants of motion are investigated. Numerical experiments are presented to check the theoretical study of this method.
Lu, Benzhuo; Holst, Michael J; McCammon, J Andrew; Zhou, Y C
2010-09-20
In this paper we developed accurate finite element methods for solving 3-D Poisson-Nernst-Planck (PNP) equations with singular permanent charges for electrodiffusion in solvated biomolecular systems. The electrostatic Poisson equation was defined in the biomolecules and in the solvent, while the Nernst-Planck equation was defined only in the solvent. We applied a stable regularization scheme to remove the singular component of the electrostatic potential induced by the permanent charges inside biomolecules, and formulated regular, well-posed PNP equations. An inexact-Newton method was used to solve the coupled nonlinear elliptic equations for the steady problems; while an Adams-Bashforth-Crank-Nicolson method was devised for time integration for the unsteady electrodiffusion. We numerically investigated the conditioning of the stiffness matrices for the finite element approximations of the two formulations of the Nernst-Planck equation, and theoretically proved that the transformed formulation is always associated with an ill-conditioned stiffness matrix. We also studied the electroneutrality of the solution and its relation with the boundary conditions on the molecular surface, and concluded that a large net charge concentration is always present near the molecular surface due to the presence of multiple species of charged particles in the solution. The numerical methods are shown to be accurate and stable by various test problems, and are applicable to real large-scale biophysical electrodiffusion problems.
International Nuclear Information System (INIS)
Korgaonkar, V.
1967-10-01
The exchange of thorium and uranium between a strong base anion resin and a mixed water + ethanol solvent containing nitrate ions is studied. It is assumed that in the resin the thorium and uranium are fixed in the form of the complexes Th(NO 3 ) 6 2- and UO 2 (NO 3 ) 4 2- in solution these elements are present in the form of complexes having the general formula: Th(NO 3 ) 6-n n-2 and UO 2 (NO 3 ) 4-n n-2 It has been possible to deduce a law for the changes in the partition functions of thorium and uranium as a function of the concentrations of the various species in solution and of the complexing ion NO 3 . From this has been deduced the optimum operational conditions for separating a mixture of these two elements. Finally, in these conditions, the influence of a few interfering ions has been studied: Ba, Bi, Ce, La, Mo, Pb, Zr. The method proposed can be used either as a preparation, or for the dosage of thorium by a quantitative separation. (author) [fr
Solution of the diffusion equations for several groups by the finite elements method
International Nuclear Information System (INIS)
Arredondo S, C.
1975-01-01
The code DELFIN has been implemented for the solution of the neutrons diffusion equations in two dimensions obtained by applying the approximation of several groups of energy. The code works with any number of groups and regions, and can be applied to thermal reactors as well as fast reactor. Providing it with the diffusion coefficients, the effective sections and the fission spectrum we obtain the results for the systems multiplying constant and the flows of each groups. The code was established using the method of finite elements, which is a form of resolution of the variational formulation of the equations applying the Ritz-Galerkin method with continuous polynomial functions by parts, in one case of the Lagrange type with rectangular geometry and up to the third grade. The obtained results and the comparison with the results in the literature, permit to reach the conclusion that it is convenient, to use the rectangular elements in all the cases where the geometry permits it, and demonstrate also that the finite elements method is better than the finite differences method. (author)
Finite Volume Element (FVE) discretization and multilevel solution of the axisymmetric heat equation
Litaker, Eric T.
1994-12-01
The axisymmetric heat equation, resulting from a point-source of heat applied to a metal block, is solved numerically; both iterative and multilevel solutions are computed in order to compare the two processes. The continuum problem is discretized in two stages: finite differences are used to discretize the time derivatives, resulting is a fully implicit backward time-stepping scheme, and the Finite Volume Element (FVE) method is used to discretize the spatial derivatives. The application of the FVE method to a problem in cylindrical coordinates is new, and results in stencils which are analyzed extensively. Several iteration schemes are considered, including both Jacobi and Gauss-Seidel; a thorough analysis of these schemes is done, using both the spectral radii of the iteration matrices and local mode analysis. Using this discretization, a Gauss-Seidel relaxation scheme is used to solve the heat equation iteratively. A multilevel solution process is then constructed, including the development of intergrid transfer and coarse grid operators. Local mode analysis is performed on the components of the amplification matrix, resulting in the two-level convergence factors for various combinations of the operators. A multilevel solution process is implemented by using multigrid V-cycles; the iterative and multilevel results are compared and discussed in detail. The computational savings resulting from the multilevel process are then discussed.
A study on removal of elemental mercury in flue gas using fenton solution
Energy Technology Data Exchange (ETDEWEB)
Liu, Yangxian; Wang, Yan; Wang, Qian; Pan, Jianfeng [School of Energy and Power Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013 (China); Zhang, Yongchun [Jiangsu Province Special Equipment Safety Supervision Inspection Institute (Branch of Wuxi), Wuxi 214000 (China); Zhou, Jianfei [School of Energy and Power Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013 (China); Zhang, Jun [Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, Southeast University, Nanjing 210096 (China)
2015-07-15
Highlights: • A novel technique on oxidation of Hg{sup 0} using Fenton was proposed. • The effects of several process parameters on Hg{sup 0} removal were studied. • Products and ·OH in solution were detected. • Reaction mechanism of Hg{sup 0} removal was studied. • Simultaneous removal of Hg{sup 0}, NO and SO{sub 2} was also studied. - Abstract: A novel technique on oxidation-separation of elemental mercury (Hg{sup 0}) in flue gas using Fenton solution in a bubbling reactor was proposed. The effects of several process parameters (H{sub 2}O{sub 2} concentration, Hg{sup 0} inlet concentration, Fe{sup 2+} concentration, solution temperature, solution pH, gas flow) and several flue gas components (NO, SO{sub 2}, O{sub 2}, CO{sub 2}, inorganic ions and particulate matters on Hg{sup 0} removal were studied. The results indicate that H{sub 2}O{sub 2} concentration, Fe{sup 2+} concentration, solution pH and gas flow have great effects on Hg{sup 0} removal. Solution temperature, Hg{sup 0}, NO, SO{sub 2}, CO{sub 3}{sup 2−} and HCO{sub 3}{sup −} concentrations also have significant effects on Hg{sup 0} removal. However, Cl{sup −}, SO{sub 4}{sup 2−}, NO{sub 3}{sup −}, O{sub 2} and CO{sub 2} concentrations only have slight effects on Hg{sup 0} removal. Furthermore, reaction mechanism of Hg{sup 0} removal and simultaneous removal process of Hg{sup 0}, NO and SO{sub 2} were also studied. Hg{sup 0} is removed by oxidation of ·OH and oxidation of H{sub 2}O{sub 2}. The simultaneous removal efficiencies of 100% for SO{sub 2}, 100% for Hg{sup 0} and 88.3% for NO were obtained under optimal test conditions. The results demonstrated the feasibility of Hg{sup 0} removal and simultaneous removal of Hg{sup 0}, SO{sub 2} and NO using Fenton solution in a bubbling reactor.
Rienstra, S.W.; Eversman, W.
2001-01-01
An explicit, analytical, multiple-scales solution for modal sound transmission through slowly varying ducts with mean flow and acoustic lining is tested against a numerical finite-element solution solving the same potential flow equations. The test geometry taken is representative of a high-bypass
Energy Technology Data Exchange (ETDEWEB)
Maichin, B.; Knapp, G. [Technische Univ., Graz (Austria). Inst. fuer Analytische Chemie, Mikro- und Radiochemie; Kettisch, P. [Anton Paar GmbH, Graz (Austria)
2000-01-01
Investigations of microwave assisted drying of sample materials and microwave assisted evaporation of aqueous sample solutions and acidic digestion residues were accomplished by means of special rotors for the microwave digestion system MULTIWAVE. To check the results obtained by microwave assisted drying, the samples were also conventionally dried at 105 C in an oven. The following samples have been dried: 10 g each of meat, fish, apple, cucumber, potato, mustard, yogurt, clay and marl; 1 g each of certified reference material TORT 2 (lobster hepatopancreas), BCR 278 (mussel tissue) and BCR 422 (cod muscle); 500 g garden mould. Microwave assisted drying takes 40 min for organic samples and 30 min for inorganic material. Important is a slow increase of microwave power during the first 20 min. The results agree well with conventional drying at 105 C. Losses of As, Se and Hg have been investigated for 3 CRMs. Only Se shows losses in the range of 20%. Losses of As, Be, Cd, Co, Cr, Cu, Fe, Hg, Li, Mg, Mn, Mo, Ni, Pb, Sb, Se, Sr, Ti, Tl, V and Zn after evaporation of aqueous samples and acidic solutions after wet digestion, respectively, have been investigated. 50 mL aqueous solution was evaporated almost to dryness within 25 min. The recovery of Hg is 40-50%, of Se 90-95% and of the other elements 97-102%. 0.2 g each of TORT 2, BCR 278 and BCR 422 have been digested with 4 mL nitric acid and 1 mL hydrochloric acid by means of the microwave digestion system MULTIWAVE. The digestion residue was evaporated almost to dryness and dissolved again in 10 mL diluted nitric acid. In this case no element losses have been observed. The measured concentration of As, Cd, Cu, Fe, Mn, Hg, Pb, Mo, Ni, Se, Sr, V and Zn agree very well with the certified values. An important prerequisite for good recoveries is not to evaporate the solutions to complete dryness. (orig.)
Makedonska, N.; Sparks, D. W.; Aharonov, E.
2012-12-01
Pressure solution (also termed chemical compaction) is considered the most important ductile deformation mechanism operating in the Earth's upper crust. This mechanism is a major player in a variety of geological processes, including evolution of sedimentary basins, hydrocarbon reservoirs, aquifers, earthquake recurrence cycles, and fault healing. Pressure solution in massive rocks often localizes into solution seams or stylolites. Field observations of stylolites often show elastic/brittle interactions in regions between pressure solution features, including and shear fractures, veins and pull-apart features. To understand these interactions, we use a grain-scale model based on the Discrete Element Method that allows granular dissolution at stressed contacts between grains. The new model captures both the slow chemical compaction process and the more abrupt brittle fracturing and sliding between grains. We simulate a sample of rock as a collection of particles, each representing either a grain or a unit of rock, bonded to each other with breakable cement. We apply external stresses to this sample, and calculate elastic and frictional interactions between the grains. Dissolution is modeled by an irreversible penetration of contacting grains into each other at a rate that depends on the contact stress and an adjustable rate constant. Experiments have shown that dissolution rates at grain contacts are greatly enhanced when there is a mineralogical contrast. Therefore, we dissolution rate constant can be increased to account for an amount of impurities (e.g. clay in a quartz or calcite sandstone) that can accumulate on dissolving contacts. This approach allows large compaction and shear strains within the rock, while allowing examination of local grain-scale heterogeneity. For example, we will describe the effect of pressure solution on the distribution of contact forces magnitudes and orientations. Contact forces in elastic granular packings are inherently
Bilyeu, David
This dissertation presents an extension of the Conservation Element Solution Element (CESE) method from second- to higher-order accuracy. The new method retains the favorable characteristics of the original second-order CESE scheme, including (i) the use of the space-time integral equation for conservation laws, (ii) a compact mesh stencil, (iii) the scheme will remain stable up to a CFL number of unity, (iv) a fully explicit, time-marching integration scheme, (v) true multidimensionality without using directional splitting, and (vi) the ability to handle two- and three-dimensional geometries by using unstructured meshes. This algorithm has been thoroughly tested in one, two and three spatial dimensions and has been shown to obtain the desired order of accuracy for solving both linear and non-linear hyperbolic partial differential equations. The scheme has also shown its ability to accurately resolve discontinuities in the solutions. Higher order unstructured methods such as the Discontinuous Galerkin (DG) method and the Spectral Volume (SV) methods have been developed for one-, two- and three-dimensional application. Although these schemes have seen extensive development and use, certain drawbacks of these methods have been well documented. For example, the explicit versions of these two methods have very stringent stability criteria. This stability criteria requires that the time step be reduced as the order of the solver increases, for a given simulation on a given mesh. The research presented in this dissertation builds upon the work of Chang, who developed a fourth-order CESE scheme to solve a scalar one-dimensional hyperbolic partial differential equation. The completed research has resulted in two key deliverables. The first is a detailed derivation of a high-order CESE methods on unstructured meshes for solving the conservation laws in two- and three-dimensional spaces. The second is the code implementation of these numerical methods in a computer code. For
Towards a unified solution of localization failure with mixed finite elements
Benedetti, Lorenzo; Cervera, Miguel; Chiumenti, Michele; Zeidler, Antonia; Fischer, Jan-Thomas
2015-04-01
Notwithstanding computational scientists made significant steps in the numerical simulation of failure in last three decades, the strain localization problem is still an open question. Especially in a geotechnical setting, when dealing with stability analysis of slopes, it is necessary to provide correct distribution of displacements, to evaluate the stresses in the ground and, therefore, to be able to identify the slip lines that brings to progressive collapse of the slope. Finite elements are an attractive method of solution thanks to profound mathematical foundations and the possibility of describing generic geometries. In order to account for the onset of localization band, the smeared crack approach [1] is introduced, that is the strain localization is assumed to occur in a band of finite width where the displacements are continuous and the strains are discontinuous but bounded. It is well known that this kind of approach poses some challenges. The standard irreducible formulation of FEM is known to be heavily affected by spurious mesh dependence when softening behavior occurs and, consequently, slip lines evolution is biased by the orientation of the mesh. Moreover, in the case of isochoric behavior, unbounded pressure oscillations arise and the consequent locking of the stresses pollutes the numerical solution. Both problems can be shown not to be related to the mathematical statement of the continuous problem but instead to its discrete (FEM) counterpart. Mixed finite element formulations represent a suitable alternative to mitigate these drawbacks. As it has been shown in previous works by Cervera [2], a mixed formulation in terms of displacements and pressure not only provides a propitious solution to the problem of incompressibility, but also it was found to possess the needed robustness in case of strain concentration. This presentation introduces a (stabilized) mixed finite element formulation with continuous linear strain and displacement
Lavery, N.; Taylor, C.
1999-07-01
Multigrid and iterative methods are used to reduce the solution time of the matrix equations which arise from the finite element (FE) discretisation of the time-independent equations of motion of the incompressible fluid in turbulent motion. Incompressible flow is solved by using the method of reduce interpolation for the pressure to satisfy the Brezzi-Babuska condition. The k-l model is used to complete the turbulence closure problem. The non-symmetric iterative matrix methods examined are the methods of least squares conjugate gradient (LSCG), biconjugate gradient (BCG), conjugate gradient squared (CGS), and the biconjugate gradient squared stabilised (BCGSTAB). The multigrid algorithm applied is based on the FAS algorithm of Brandt, and uses two and three levels of grids with a V-cycling schedule. These methods are all compared to the non-symmetric frontal solver. Copyright
International Nuclear Information System (INIS)
Camp, D.C.
1984-07-01
Advantages of using Co-57 as an exciter for K XRFA include: a compact design that requires no x-ray tubes; the exciter-detector assembly locates remote from support electronics; on-line, at-line, or off-line configurations for monitor/measurements; systems that can be run by semi-skilled technicians, once programmed; and operated via remote terminals with results sent to control rooms; heavy element concentrations that are measurable thru industrial pipes; independent of minor changes in solution matrix or source half life with concentration results reported in near-real-time; a dynamic range of measurable concentrations that is greater than 10 4 ; measurement times that are reasonable even at 1 gram/liter; and for nuclear safeguards, it provides the <0.5% accuracy required by DOE for the accountability of U, Pu, or both, once the system is calibrated
International Nuclear Information System (INIS)
Nikolaev, V.M.; Lebedev, V.M.; Lebedeva, L.S.
1986-01-01
The mechanisms of transplutonium (TPE) and rare earth elements (REE) extraction by HDEHP from lactic acid solutions are analysed in the literature. On the base of the known expressions and experimental data the model for TPE and REE extraction by HDEHP from lactic acid, accounting lactic acid and metal extraction as MeA 3 x3HA, MeLA 2 x2HA and MeLA 2 complexes, is suggested. The expression, permitting to estimate quantitatively the effect of TPE and REE complexing with lactic acid and the extraction of complex forms on the distribution coefficient of the extracted metal, is obtained. Comparison of calculational data with experimental ones show their good coincidence that confirms the rightness of the model accepted for extraction
International Nuclear Information System (INIS)
Kılıç, Emre; Eibert, Thomas F.
2015-01-01
An approach combining boundary integral and finite element methods is introduced for the solution of three-dimensional inverse electromagnetic medium scattering problems. Based on the equivalence principle, unknown equivalent electric and magnetic surface current densities on a closed surface are utilized to decompose the inverse medium problem into two parts: a linear radiation problem and a nonlinear cavity problem. The first problem is formulated by a boundary integral equation, the computational burden of which is reduced by employing the multilevel fast multipole method (MLFMM). Reconstructed Cauchy data on the surface allows the utilization of the Lorentz reciprocity and the Poynting's theorems. Exploiting these theorems, the noise level and an initial guess are estimated for the cavity problem. Moreover, it is possible to determine whether the material is lossy or not. In the second problem, the estimated surface currents form inhomogeneous boundary conditions of the cavity problem. The cavity problem is formulated by the finite element technique and solved iteratively by the Gauss–Newton method to reconstruct the properties of the object. Regularization for both the first and the second problems is achieved by a Krylov subspace method. The proposed method is tested against both synthetic and experimental data and promising reconstruction results are obtained
Energy Technology Data Exchange (ETDEWEB)
Kılıç, Emre, E-mail: emre.kilic@tum.de; Eibert, Thomas F.
2015-05-01
An approach combining boundary integral and finite element methods is introduced for the solution of three-dimensional inverse electromagnetic medium scattering problems. Based on the equivalence principle, unknown equivalent electric and magnetic surface current densities on a closed surface are utilized to decompose the inverse medium problem into two parts: a linear radiation problem and a nonlinear cavity problem. The first problem is formulated by a boundary integral equation, the computational burden of which is reduced by employing the multilevel fast multipole method (MLFMM). Reconstructed Cauchy data on the surface allows the utilization of the Lorentz reciprocity and the Poynting's theorems. Exploiting these theorems, the noise level and an initial guess are estimated for the cavity problem. Moreover, it is possible to determine whether the material is lossy or not. In the second problem, the estimated surface currents form inhomogeneous boundary conditions of the cavity problem. The cavity problem is formulated by the finite element technique and solved iteratively by the Gauss–Newton method to reconstruct the properties of the object. Regularization for both the first and the second problems is achieved by a Krylov subspace method. The proposed method is tested against both synthetic and experimental data and promising reconstruction results are obtained.
Fast solution of neutron diffusion problem by reduced basis finite element method
International Nuclear Information System (INIS)
Chunyu, Zhang; Gong, Chen
2018-01-01
Highlights: •An extremely efficient method is proposed to solve the neutron diffusion equation with varying the cross sections. •Three orders of speedup is achieved for IAEA benchmark problems. •The method may open a new possibility of efficient high-fidelity modeling of large scale problems in nuclear engineering. -- Abstract: For the important applications which need carry out many times of neutron diffusion calculations such as the fuel depletion analysis and the neutronics-thermohydraulics coupling analysis, fast and accurate solutions of the neutron diffusion equation are demanding but necessary. In the present work, the certified reduced basis finite element method is proposed and implemented to solve the generalized eigenvalue problems of neutron diffusion with variable cross sections. The order reduced model is built upon high-fidelity finite element approximations during the offline stage. During the online stage, both the k eff and the spatical distribution of neutron flux can be obtained very efficiently for any given set of cross sections. Numerical tests show that a speedup of around 1100 is achieved for the IAEA two-dimensional PWR benchmark problem and a speedup of around 3400 is achieved for the three-dimensional counterpart with the fission cross-sections, the absorption cross-sections and the scattering cross-sections treated as parameters.
Bíró, Oszkár; Koczka, Gergely; Preis, Kurt
2014-05-01
An efficient finite element method to take account of the nonlinearity of the magnetic materials when analyzing three-dimensional eddy current problems is presented in this paper. The problem is formulated in terms of vector and scalar potentials approximated by edge and node based finite element basis functions. The application of Galerkin techniques leads to a large, nonlinear system of ordinary differential equations in the time domain. The excitations are assumed to be time-periodic and the steady-state periodic solution is of interest only. This is represented either in the frequency domain as a finite Fourier series or in the time domain as a set of discrete time values within one period for each finite element degree of freedom. The former approach is the (continuous) harmonic balance method and, in the latter one, discrete Fourier transformation will be shown to lead to a discrete harmonic balance method. Due to the nonlinearity, all harmonics, both continuous and discrete, are coupled to each other. The harmonics would be decoupled if the problem were linear, therefore, a special nonlinear iteration technique, the fixed-point method is used to linearize the equations by selecting a time-independent permeability distribution, the so-called fixed-point permeability in each nonlinear iteration step. This leads to uncoupled harmonics within these steps. As industrial applications, analyses of large power transformers are presented. The first example is the computation of the electromagnetic field of a single-phase transformer in the time domain with the results compared to those obtained by traditional time-stepping techniques. In the second application, an advanced model of the same transformer is analyzed in the frequency domain by the harmonic balance method with the effect of the presence of higher harmonics on the losses investigated. Finally a third example tackles the case of direct current (DC) bias in the coils of a single-phase transformer.
The boundary element method for the solution of the multidimensional inverse heat conduction problem
International Nuclear Information System (INIS)
Lagier, Guy-Laurent
1999-01-01
This work focuses on the solution of the inverse heat conduction problem (IHCP), which consists in the determination of boundary conditions from a given set of internal temperature measurements. This problem is difficult to solve due to its ill-posedness and high sensitivity to measurement error. As a consequence, numerical regularization procedures are required to solve this problem. However, most of these methods depend on the dimension and the nature, stationary or transient, of the problem. Furthermore, these methods introduce parameters, called hyper-parameters, which have to be chosen optimally, but can not be determined a priori. So, a new general method is proposed for solving the IHCP. This method is based on a Boundary Element Method formulation, and the use of the Singular Values Decomposition as a regularization procedure. Thanks to this method, it's possible to identify and eliminate the directions of the solution where the measurement error plays the major role. This algorithm is first validated on two-dimensional stationary and one-dimensional transient problems. Some criteria are presented in order to choose the hyper-parameters. Then, the methodology is applied to two-dimensional and three-dimensional, theoretical or experimental, problems. The results are compared with those obtained by a standard method and show the accuracy of the method, its generality, and the validity of the proposed criteria. (author) [fr
Effects of solute elements on hardening of thermally-aged RPV model alloys
International Nuclear Information System (INIS)
Dohi, Kenji; Nishida, Kenji; Nomoto, Akiyoshi; Soneda, Naoki; Liu, Li; Sekimura, Naoto; Li Zhengcao
2012-01-01
The investigation of effects of solute elements on the copper-enriched cluster, which is a cause of radiation embrittlement of reactor pressure vessel steels, is needed in order to understand the mechanism of the hardening and the cluster formation. The dependence of the hardness change and the formation of thermally-aged Fe-Cu model alloys doped Ni, Si and Mn on aging time are investigated using Vickers harness tester and three dimensional atom probe. Ni addition suppresses hardening, and Si addition accelerates hardening slightly at the initial stage of the aging. Mn addition accelerates hardening much more but does not almost affect the peak hardness. Ni and Si addition increase the number density and the size of the cluster, while Mn addition remarkably increases the number density and the size of the cluster at the initial stage of the aging. In addition, there is no clear correlation between the square root of the volume fraction of the clusters and the hardness change for all of the alloys. The reasons are considered to be the decrease in the solute hardening caused by the cluster formation and the difference in the shear modulus of the cluster due to the difference in the chemical composition of the cluster. (author)
Energy Technology Data Exchange (ETDEWEB)
L' Her, M [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1967-01-01
The aim of this work is the application of spectrophotometric titrations to the analysis of uranium-containing solutions. We have been led to examine the general principles involved in these titrations, and we give a brief outline of these principles. In the first part we deal therefore with spectrophotometric titrations from a general point of view, examining their fundamental principle, their practical execution as well as the various possibilities of the method. The advantage of the titration are examined, in particular that of lending itself simultaneous determination of two species. The possibility of applying these spectrophotometric titrations to the analysis of uranium-containing solutions is the subject of the second part of this report: the dosage of a few species in uranium (VI) solutions is described. To this second part is added an experimental appendix consisting of a description of the apparatus, as well as of the operational techniques used for certain titrations, in particular those involving solutions containing uranium. (author) [French] Le but de ce travail est l'application des titrages spectrophotometriques a l'analyse des solutions uraniferes. Nous avons ete amenes a examiner les principes generaux de ces titrages, principes qu'il nous est apparu necessaire de rappeler. Dans une premiere partie nous traiterons donc d'une facon generale des titrages spectrophotometriques, en examinant leur principe fondamental, leur mise en oeuvre ainsi que les possibilites diverses de dosage. Nous examinerons aussi les avantages de la methode de titrage, en insistant notamment sur la possibilite de faire des dosages successifs. La possibilite d'application de ces titrages spectrophotometriques a l'analyse des solutions uraniferes sera le sujet de la deuxieme partie: nous y decrivons le dosage de quelques especes, dans les solutions d'uranium (VI). A cette deuxieme partie nous joindrons une annexe experimentale comportant une description de l'appareillage que
Directory of Open Access Journals (Sweden)
Siqi Li
2017-11-01
Full Text Available Energy sustainability is of vital importance to regional sustainability, because energy sustainability is closely related to both regional economic growth and social stability. The existing energy sustainability evaluation methods lack a unified system to determine the relevant influencing factors, are relatively weak in quantitative analysis, and do not fully describe the ‘paradoxical’ characteristics of energy sustainability. To solve those problems and to reasonably and objectively evaluate energy sustainability, we propose an energy sustainability evaluation model based on the matter-element extension method. We first select energy sustainability evaluation indexes based on previous research and experience. Then, a variation coefficient method is used to determine the weights of these indexes. Finally, the study establishes the classical domain, joint domain, and the matter-element relationship to evaluate energy sustainability through matter-element extension. Data from Shandong Province is used as a case study to evaluate the region’s energy sustainability. The case study shows that the proposed energy sustainability evaluation model, based on the matter-element extension method, can effectively evaluate regional energy sustainability.
Massimi, Lorenzo; Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia
2018-02-26
Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents' efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements' removal efficiency which resulted to be in correlation with the specific adsorbents' chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.
Energy Technology Data Exchange (ETDEWEB)
Jo, Jong Chull; Shin, Won Ky [Korea Institute of Nuclear Safety, Taejon (Korea, Republic of)
1997-12-31
This paper presents an effective and simple procedure for the simulation of the motion of the solid-liquid interfacial boundary and the transient temperature field during phase change process. To accomplish this purpose, an iterative implicit solution algorithm has been developed by employing the dual reciprocity boundary element method. The dual reciprocity boundary element approach provided in this paper is much simpler than the usual boundary element method applying a reciprocity principle and an available technique for dealing with domain integral of boundary element formulation simultaneously. The effectiveness of the present analysis method have been illustrated through comparisons of the calculation results of an example with its semi-analytical or other numerical solutions where available. 22 refs., 3 figs. (Author)
International Nuclear Information System (INIS)
Jo, Jong Chull; Shin, Won Ky
1997-01-01
This paper presents an effective and simple procedure for the simulation of the motion of the solid-liquid interfacial boundary and the transient temperature field during phase change process. To accomplish this purpose, an iterative implicit solution algorithm has been developed by employing the dual reciprocity boundary element method. The dual reciprocity boundary element approach provided in this paper is much simpler than the usual boundary element method applying a reciprocity principle and an available technique for dealing with domain integral of boundary element formulation simultaneously. The effectiveness of the present analysis method have been illustrated through comparisons of the calculation results of an example with its semi-analytical or other numerical solutions where available
Energy Technology Data Exchange (ETDEWEB)
Jo, Jong Chull; Shin, Won Ky [Korea Institute of Nuclear Safety, Taejon (Korea, Republic of)
1998-12-31
This paper presents an effective and simple procedure for the simulation of the motion of the solid-liquid interfacial boundary and the transient temperature field during phase change process. To accomplish this purpose, an iterative implicit solution algorithm has been developed by employing the dual reciprocity boundary element method. The dual reciprocity boundary element approach provided in this paper is much simpler than the usual boundary element method applying a reciprocity principle and an available technique for dealing with domain integral of boundary element formulation simultaneously. The effectiveness of the present analysis method have been illustrated through comparisons of the calculation results of an example with its semi-analytical or other numerical solutions where available. 22 refs., 3 figs. (Author)
International Nuclear Information System (INIS)
Kaiser, H.G.
1985-01-01
The author is concerned with the flow conditions in case of narrow fuel element grids of pressurised-water reactors. Starting from the mathematical formulation of the flow processes for incompressible, isothermal flows, models of the turbulence characteristics are being developed. Besides turbulence models, and network structure the finite element method is treated as numeric solution process. Finally the results are summarized and discussed. (HAG) [de
Energy Technology Data Exchange (ETDEWEB)
Yokoi, T [Building Research Institute, Tokyo (Japan); Sanchez-Sesma, F [Universidad National Autonoma de Mexico, (Mexico). Institute de Ingenieria
1997-05-27
Formulation is introduced for discretizing a boundary integral equation into an indirect boundary element method for the solution of 3-dimensional topographic problems. Yokoi and Takenaka propose an analytical solution-capable reference solution (solution for the half space elastic body with flat free surface) to problems of topographic response to seismic motion in a 2-dimensional in-plane field. That is to say, they propose a boundary integral equation capable of effectively suppressing the non-physical waves that emerge in the result of computation in the wake of the truncation of the discretized ground surface making use of the wave field in a semi-infinite elastic body with flat free surface. They apply the proposed boundary integral equation discretized into the indirect boundary element method to solve some examples, and succeed in proving its validity. In this report, the equation is expanded to deal with 3-dimensional topographic problems. A problem of a P-wave vertically landing on a flat and free surface is solved by the conventional boundary integral equation and the proposed boundary integral equation, and the solutions are compared with each other. It is found that the new method, different from the conventional one, can delete non-physical waves from the analytical result. 4 figs.
DEFF Research Database (Denmark)
including convection-difmsion-reaction PDEs are numerically solved using the two methods on the same spatial grid. Even though the CE/SE method uses a simple stencil structure and is developed on a simple mathematical basis (i.e., Gauss' divergence theorem), accurate and computationally-efficient solutions...
International Nuclear Information System (INIS)
Masiello, E.
2006-01-01
The principal goal of this manuscript is devoted to the investigation of a new type of heterogeneous mesh adapted to the shape of the fuel pins (fuel-clad-moderator). The new heterogeneous mesh guarantees the spatial modelling of the pin-cell with a minimum of regions. Two methods are investigated for the spatial discretization of the transport equation: the discontinuous finite element method and the method of characteristics for structured cells. These methods together with the new representation of the pin-cell result in an appreciable reduction of calculation points. They allow an exact modelling of the fuel pin-cell without spatial homogenization. A new synthetic acceleration technique based on an angular multigrid is also presented for the speed up of the inner iterations. These methods are good candidates for transport calculations for a nuclear reactor core. A second objective of this work is the application of method of characteristics for non-structured geometries to the study of double heterogeneity problem. The letters is characterized by fuel material with a stochastic dispersion of heterogeneous grains, and until now was solved with a model based on collision probabilities. We propose a new statistical model based on renewal-Markovian theory, which makes possible to take into account the stochastic nature of the problem and to avoid the approximations of the collision probability model. The numerical solution of this model is guaranteed by the method of characteristics. (author)
Energy Technology Data Exchange (ETDEWEB)
Fujii, Katsuhiko, E-mail: fujiik@inss.co.jp [Institute of Nuclear Safety System Inc., 64 Sata, Mihama 919-1205 (Japan); Ohkubo, Tadakatsu, E-mail: OHKUBO.Tadakatsu@nims.go.jp [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047 (Japan); Fukuya, Koji, E-mail: fukuya@inss.co.jp [Institute of Nuclear Safety System Inc., 64 Sata, Mihama 919-1205 (Japan)
2011-10-01
The effects of the elements Mn, Ni, Si and Cu on irradiation hardening and microstructural evolution in low alloy steels were investigated in ion irradiation experiments using five kinds of alloys prepared by removing Mn, Ni and Si from, and adding 0.05 wt.%Cu to, the base alloy (Fe-1.5Mn-0.5Ni-0.25Si). The alloy without Mn showed less hardening and the alloys without Ni or Si showed more hardening. The addition of Cu had hardly any influence on hardening. These facts indicated that Mn enhanced hardening and that Ni and Si had some synergetic effects. The formation of solute clusters was not confirmed by atom probe (AP) analysis, whereas small dislocation loops were identified by TEM observation. The difference in hardening between the alloys with and without Mn was qualitatively consistent with loop formation. However, microstructural components that were not detected by the AP and TEM were assumed to explain the hardening level quantitatively.
International Nuclear Information System (INIS)
Max, Bertrand
2014-01-01
Alloy 718 is the superalloy the most widely used in industry due to its excellent mechanical properties, as well as oxidation and corrosion resistance in wide range of temperatures and solicitation modes. Nevertheless, it is a well-known fact that this alloy is sensitive to stress corrosion cracking and oxidation assisted cracking under loading in the range of temperatures met in service. Mechanisms explaining this phenomenon are not well understood: nevertheless, it is well established that a relation exists between a change in fracture mode and the apparition of plastic instabilities phenomenon. During this study, the instability phenomenon, Portevin-Le Chatelier effect, in alloy 718 was studied by tensile tests in wide ranges of temperatures and strain rates. Different domains of plastic instabilities have been evidenced. Their characteristics suggest the existence of interactions between dislocations and different types of solute elements: interstitials for lower temperatures and substitutionals for higher testing temperatures. Mechanical spectroscopy tests have been performed on alloy 718 and various alloys which composition is comparable to that of alloy 718. These tests prove the mobility of molybdenum atoms in the alloy in the studied temperature range. Specific tests have been performed to study interaction phenomenon between plasticity and oxidation. These results highlight the strong effect of plastic strain rate on both mechanical behavior and intergranular cracking in alloy 718. The subsequent discussion leads to propose hypothesis on coupling effects between deformation mechanisms and oxidation assisted embrittlement in the observed cracking processes. (author)
Khan, Sabeel M.; Sunny, D. A.; Aqeel, M.
2017-09-01
Nonlinear dynamical systems and their solutions are very sensitive to initial conditions and therefore need to be approximated carefully. In this article, we present and analyze nonlinear solution characteristics of the periodically forced Chen system with the application of a variational method based on the concept of finite time-elements. Our approach is based on the discretization of physical time space into finite elements where each time-element is mapped to a natural time space. The solution of the system is then determined in natural time space using a set of suitable basis functions. The numerical algorithm is presented and implemented to compute and analyze nonlinear behavior at different time-step sizes. The obtained results show an excellent agreement with the classical RK-4 and RK-5 methods. The accuracy and convergence of the method is shown by comparing numerically computed results with the exact solution for a test problem. The presented method has shown a great potential in dealing with the solutions of nonlinear dynamical systems and thus can be utilized in delineating different features and characteristics of their solutions.
Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia
2018-01-01
Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements. PMID:29495363
Directory of Open Access Journals (Sweden)
Lorenzo Massimi
2018-02-01
Full Text Available Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.
Rahmouni, Lyes; Adrian, Simon B.; Cools, Kristof; Andriulli, Francesco P.
2018-01-01
In this paper, we present a new discretization strategy for the boundary element formulation of the Electroencephalography (EEG) forward problem. Boundary integral formulations, classically solved with the Boundary Element Method (BEM), are widely used in high resolution EEG imaging because of their recognized advantages, in several real case scenarios, in terms of numerical stability and effectiveness when compared with other differential equation based techniques. Unfortunately, however, it is widely reported in literature that the accuracy of standard BEM schemes for the forward EEG problem is often limited, especially when the current source density is dipolar and its location approaches one of the brain boundary surfaces. This is a particularly limiting problem given that during an high-resolution EEG imaging procedure, several EEG forward problem solutions are required, for which the source currents are near or on top of a boundary surface. This work will first present an analysis of standardly and classically discretized EEG forward problem operators, reporting on a theoretical issue of some of the formulations that have been used so far in the community. We report on the fact that several standardly used discretizations of these formulations are consistent only with an L2-framework, requiring the expansion term to be a square integrable function (i.e., in a Petrov-Galerkin scheme with expansion and testing functions). Instead, those techniques are not consistent when a more appropriate mapping in terms of fractional-order Sobolev spaces is considered. Such a mapping allows the expansion function term to be a less regular function, thus sensibly reducing the need for mesh refinements and low-precisions handling strategies that are currently required. These more favorable mappings, however, require a different and conforming discretization, which must be suitably adapted to them. In order to appropriately fulfill this requirement, we adopt a mixed
International Nuclear Information System (INIS)
Gureghian, A.B.
1979-01-01
A mathematical model of ground water transport through an aquifer is presented. The solute of interest is a metal tracer or radioactive material which may undergo decay through a sorbing unconfined aquifer. The subject is developed under the following headings: flow equation, solute equation, boundary conditions, finite element formulation, element formulation, solution scheme (flow equation, solute equation), results and discussions, water movement in a ditch drained aquifer under transient state, water and solute movement in a homogeneous and unsaturated soil, transport of 226 Ra in nonhomogeneous aquifer, tailings pond lined, and tailings pond unlined. It is concluded that this mathematical model may have a wide variety of applications. The uranium milling industry may find it useful to evaluate the hydrogeological suitability of their disposal sites. It may prove suited for the design of clay disposal ponds destined to hold hazardous liquids. It may also provide a means of estimating the long-term impact of radionuclides or other pollutants on the quality of ground water. 31 references, 9 figures, 3 tables
Malakpoor, K.; Kaasschieter, E.F.; Huyghe, J.M.R.J.
2007-01-01
The swelling and shrinkage of biological tissues are modelled by a four-component mixture theory [J.M. Huyghe and J.D. Janssen, Int. J. Engng. Sci. 35 (1997) 793-802; K. Malakpoor, E.F. Kaasschieter and J.M. Huyghe, Mathematical modelling and numerical solution of swelling of cartilaginous tissues.
International Nuclear Information System (INIS)
Ragusa, J. C.
2004-01-01
In this paper, a method for performing spatially adaptive computations in the framework of multigroup diffusion on 2-D and 3-D Cartesian grids is investigated. The numerical error, intrinsic to any computer simulation of physical phenomena, is monitored through an a posteriori error estimator. In a posteriori analysis, the computed solution itself is used to assess the accuracy. By efficiently estimating the spatial error, the entire computational process is controlled through successively adapted grids. Our analysis is based on a finite element solution of the diffusion equation. Bilinear test functions are used. The derived a posteriori error estimator is therefore based on the Hessian of the numerical solution. (authors)
DEFF Research Database (Denmark)
Schmidt, I.K.; Tietema, A.; Williams, D.
2004-01-01
Soil water chemistry and element budgets were studied at three northwestern European Calluna vulgaris heathland sites in Denmark (DK), The Netherlands (NL), and Wales (UK). Responses to experimental nighttime warming and early summer drought were followed during a two-year period. Soil solution...
Growth of tourmaline single crystals containing transition metal elements in hydrothermal solutions
Setkova, Tatiana; Shapovalov, Yury; Balitsky, Vladimir
2011-03-01
Interest in the growth of tourmaline single crystals is based on the promising piezoelectric and pyroelectric properties of this material compared to quartz crystals currently in use. Moreover, synthetic tourmaline can be used as a substitute for the natural stone in the jewelry industry similar to other synthetic analogues of gemstones. Single crystals of colored Co-, Ni-, Fe-, (Ni,Cr)-, (Ni,Fe)-, and (Co,Ni,Cr)-containing tourmalines with concentration of transition metal elements up to 16 wt% on a seed have been grown from complex boron-containing hydrothermal solutions at a range of temperatures 400-750 °C and pressures 100 MPa. Experiments were conducted under conditions of a thermal gradient in titanium and chromium-nickel autoclaves. Tourmaline growth on a seed crystal occurs only if separate tourmaline-forming components (monocrystalline corundum and quartz bars) are used as charge. All tourmalines specified above grow in analogous (+) direction of the optical axis with a speed of 0.05 mm/day by faces of the trigonal pyramid, except tourmalines containing chromium. They grow in analogous (+0001) direction with a speed 0.05 mm/day, and in antilogous (-0001) direction with a speed of 0.01 mm/day by faces of the trigonal pyramid and in prism direction with a speed of 0.001 mm/day. Along with the large single crystals, a great amount of finest (30-150 μm in size) tourmaline crystals was formed during the runs by spontaneous nucleation both on the surface of the seed crystals and in the charge.
International Nuclear Information System (INIS)
Mair, R.J.; Taylor, R.N.; Higgins, K.G.; Potts, D.M.
1989-01-01
Analyses have been undertaken on an advancing tunnel heading at great depth in a clay formation corresponding to the test drift construction at Mol. Belgium. Simplifying assumptions enable plasticity solutions to be used to model the behaviour of a tunnel heading in a linear elastic-perfectly plastic soil. Finite element analysis with the same soil model has been undertaken of the test drift construction, assuming axisymmetric conditions. The results are compared with the plasticity solutions and with the measurements of lining stresses, soil movements and pore pressures by SCK/CEN. Good agreement is obtained between the plasticity solutions and finite element analysis. The measured immediate build-up of stress on the linings is well-predicted and reasonable agreement is obtained between predicted and measured soil movements. The measured pore-pressure changes are poorly predicted by the analyses
International Nuclear Information System (INIS)
Soares, Eufemia Paez; Saki, Mitiko; Silva, Leonardo G.A.
2007-01-01
Brazilian plastic production for food packagings, in recent years, has grown in the same proportion as food consumption. Considering that the plastic manufacturing involves catalytic processes and the use of additives, when the foods are in direct contact with these materials, the components present in plastics may migrate to the food. The Brazilian Health Surveillance Agency (ANVISA) has established boundary-values of migrants as well as procedures to evaluate migration of elements and substances from plastic packaging to food. In this study elemental composition of poly (ethylene terephthalate) - PET - packaging and results of elemental migration were obtained. Instrumental Neutron Activation Analysis (INAA) was used to determine elemental concentrations in PET packagings and the radiometric method was applied for elemental migration determination. This radiometric method consisted of irradiating the PET samples with neutrons, followed by migration exposition and radioactivity measurement in food-simulated solution. Experimental conditions used for migration were 10 days exposure period at 40 deg C. Migration was evaluated for soft drink, juice and water PET packaging. The analytical results indicated that PET packagings contain Co and Sb and those elements are transferred to the simulated solutions. However, these migration results were lower than the maximum tolerance values established by ANVISA. The migration detection limits also indicated high sensitivity of the radiometric method. (author)
Directory of Open Access Journals (Sweden)
Antonio Gledson Goulart
2013-12-01
Full Text Available In this paper, the equation for the gravity wave spectra in mean atmosphere is analytically solved without linearization by the Adomian decomposition method. As a consequence, the nonlinear nature of problem is preserved and the errors found in the results are only due to the parameterization. The results, with the parameterization applied in the simulations, indicate that the linear solution of the equation is a good approximation only for heights shorter than ten kilometers, because the linearization the equation leads to a solution that does not correctly describe the kinetic energy spectra.
Directory of Open Access Journals (Sweden)
Марина Анатоліівна Рябікіна
2016-07-01
Full Text Available Modern industry uses a lot of elements as additives to improve the service characteristics of metal products that are to be used for various purposes. These elements can be divided into two groups: the first group includes the elements interacting with iron and improving its characteristics (alloying elements, and the second group includes the elements, that modify the characteristics of the structure and properties in an undesirable direction. These are trace elements: S, P, O, As, and others in steel. The negative impact of these elements shows itself as banding, the formation of non-metallic inclusions, flakes, grain boundary segregations et al. The influence of the elements of the both groups on the properties of steel depends on the nature and level of interatomic interaction in the alloy. Computational and analytical study of the major impurity elements in steel impact on the interatomic bond strength and the probability of forming complexes, clusters, and chemical compounds with the basic alloying elements in the steel has been carried out in the work. The theoretical parameter which defines the strength of the ion-covalent bond of two atoms: non-metallic – metallic is the electronegativity of elements. The electronegativity difference of the metal and non-metallic elements increasing, the ionic bonding and thermodynamic stability of these compounds increase. On the other hand, concentration of valent electrons is a universal characteristic of an atomic element which determines many of its properties, and especially the energy of interatomic interaction. Energy calculations of pairwise interatomic impurity elements: H, C, N, S, P, As interaction with Fe and major alloying elements in steel: Mn, Cr, Si, V, Al, Ti, W, Cu, Mo, Nb were made. It has been stated that all the impurity elements except phosphorus, hydrogen and arsenic have sufficient high adhesion with the majority of the metal elements in the modern steels. Phosphorus does
Belaid, D; Vendeuvre, T; Bouchoucha, A; Brémand, F; Brèque, C; Rigoard, P; Germaneau, A
2018-05-08
Treatment for fractures of the tibial plateau is in most cases carried out by stable fixation in order to allow early mobilization. Minimally invasive technologies such as tibioplasty or stabilization by locking plate, bone augmentation and cement filling (CF) have recently been used to treat this type of fracture. The aim of this paper was to determine the mechanical behavior of the tibial plateau by numerically modeling and by quantifying the mechanical effects on the tibia mechanical properties from injury healing. A personalized Finite Element (FE) model of the tibial plateau from a clinical case has been developed to analyze stress distribution in the tibial plateau stabilized by balloon osteoplasty and to determine the influence of the cement injected. Stress analysis was performed for different stages after surgery. Just after surgery, the maximum von Mises stresses obtained for the fractured tibia treated with and without CF were 134.9 MPa and 289.9 MPa respectively on the plate. Stress distribution showed an increase of values in the trabecular bone in the treated model with locking plate and CF and stress reduction in the cortical bone in the model treated with locking plate only. The computed results of stresses or displacements of the fractured models show that the cement filling of the tibial depression fracture may increase implant stability, and decrease the loss of depression reduction, while the presence of the cement in the healed model renders the load distribution uniform. Copyright © 2018 Elsevier Ltd. All rights reserved.
Contreras, Michael T.; Trease, Brian P.; Bojanowski, Cezary; Kulakx, Ronald F.
2013-01-01
A wheel experiencing sinkage and slippage events poses a high risk to planetary rover missions as evidenced by the mobility challenges endured by the Mars Exploration Rover (MER) project. Current wheel design practice utilizes loads derived from a series of events in the life cycle of the rover which do not include (1) failure metrics related to wheel sinkage and slippage and (2) performance trade-offs based on grouser placement/orientation. Wheel designs are rigorously tested experimentally through a variety of drive scenarios and simulated soil environments; however, a robust simulation capability is still in development due to myriad of complex interaction phenomena that contribute to wheel sinkage and slippage conditions such as soil composition, large deformation soil behavior, wheel geometry, nonlinear contact forces, terrain irregularity, etc. For the purposes of modeling wheel sinkage and slippage at an engineering scale, meshfree nite element approaches enable simulations that capture su cient detail of wheel-soil interaction while remaining computationally feasible. This study implements the JPL wheel-soil benchmark problem in the commercial code environment utilizing the large deformation modeling capability of Smooth Particle Hydrodynamics (SPH) meshfree methods. The nominal, benchmark wheel-soil interaction model that produces numerically stable and physically realistic results is presented and simulations are shown for both wheel traverse and wheel sinkage cases. A sensitivity analysis developing the capability and framework for future ight applications is conducted to illustrate the importance of perturbations to critical material properties and parameters. Implementation of the proposed soil-wheel interaction simulation capability and associated sensitivity framework has the potential to reduce experimentation cost and improve the early stage wheel design proce
Energy Technology Data Exchange (ETDEWEB)
Williams, P. T. [Univ. of Tennessee, Knoxville, TN (United States)
1993-09-01
As the field of computational fluid dynamics (CFD) continues to mature, algorithms are required to exploit the most recent advances in approximation theory, numerical mathematics, computing architectures, and hardware. Meeting this requirement is particularly challenging in incompressible fluid mechanics, where primitive-variable CFD formulations that are robust, while also accurate and efficient in three dimensions, remain an elusive goal. This dissertation asserts that one key to accomplishing this goal is recognition of the dual role assumed by the pressure, i.e., a mechanism for instantaneously enforcing conservation of mass and a force in the mechanical balance law for conservation of momentum. Proving this assertion has motivated the development of a new, primitive-variable, incompressible, CFD algorithm called the Continuity Constraint Method (CCM). The theoretical basis for the CCM consists of a finite-element spatial semi-discretization of a Galerkin weak statement, equal-order interpolation for all state-variables, a 0-implicit time-integration scheme, and a quasi-Newton iterative procedure extended by a Taylor Weak Statement (TWS) formulation for dispersion error control. Original contributions to algorithmic theory include: (a) formulation of the unsteady evolution of the divergence error, (b) investigation of the role of non-smoothness in the discretized continuity-constraint function, (c) development of a uniformly H^{1} Galerkin weak statement for the Reynolds-averaged Navier-Stokes pressure Poisson equation, (d) derivation of physically and numerically well-posed boundary conditions, and (e) investigation of sparse data structures and iterative methods for solving the matrix algebra statements generated by the algorithm.
International Nuclear Information System (INIS)
Thien, Bruno M.J.; Kulik, Dmitrii A.; Curti, Enzo
2014-01-01
Highlights: • There are several models able to describe trace element partitioning in growing minerals. • To describe complex systems, those models must be embedded in a geochemical code. • We merged two models into a unified one suitable for implementation in a geochemical code. • This unified model was tested against coprecipitation experimental data. • We explored how our model reacts to solution depletion effects. - Abstract: Thermodynamics alone is usually not sufficient to predict growth-rate dependencies of trace element partitioning into host mineral solid solutions. In this contribution, two uptake kinetic models were analyzed that are promising in terms of mechanistic understanding and potential for implementation in geochemical modelling codes. The growth Surface Entrapment Model (Watson, 2004) and the Surface Reaction Kinetic Model (DePaolo, 2011) were shown to be complementary, and under certain assumptions merged into a single analytical expression. This Unified Uptake Kinetics Model was implemented in GEMS3K and GEM-Selektor codes ( (http://gems.web.psi.ch)), a Gibbs energy minimization package for geochemical modelling. This implementation extends the applicability of the unified uptake kinetics model to accounting for non-trivial factors influencing the trace element partitioning into solid solutions, such as the changes in aqueous solution composition and speciation, or the depletion effects in closed geochemical systems
Model Experiments on Chemical Properties of Superheavy Elements in Aqueous Solutions
Szeglowski, Z
2003-01-01
This paper presents a brief review of model experiments on investigation of chemical properties of transactinide elements, ranging from 104 to 116. The possibilities of isolation of the nuclei of these elements from nuclear reaction products, using the ion-exchange method, are also considered.
A coupled boundary element-finite difference solution of the elliptic modified mild slope equation
DEFF Research Database (Denmark)
Naserizadeh, R.; Bingham, Harry B.; Noorzad, A.
2011-01-01
The modified mild slope equation of [5] is solved using a combination of the boundary element method (BEM) and the finite difference method (FDM). The exterior domain of constant depth and infinite horizontal extent is solved by a BEM using linear or quadratic elements. The interior domain...
International Nuclear Information System (INIS)
Li Zhenhu; Jiao Rongzhou; Zhu Yongjun
1994-01-01
A study has been made of the extraction equilibrium of Am(III) and rare earth elements (III) in HNO 3 solution with P507-sulphonating kerosene. It has been found that this equilibrium depends on saponification ratio of P507, feed acidity, metal concentration as well as phase ratio. The extraction ability in order is La< Ce< Am< Pr< Nd< Sm. The model of distribution ratio has been founded. The agreement for calculated and experimental values of distribution ratio is fairly good. These values can be used to design the extraction and separation process of Am and rare earth elements
International Nuclear Information System (INIS)
Franke, H.P.
1976-05-01
The finite element method is applied to the solution of the stationary 3D group diffusion equations. For this, a programme system with the name of FEM3D is established which also includes a module for semi-automatic mesh generation. Tetrahedral finite elements are used. The neutron fluxes are described by complete first- or second-order Lagrangian polynomials. General homogeneous boundary conditions are allowed. The studies show that realistic three-dimensional problems can be solved at less expense by iterative methods, in particular so when especially adapted matrix handling and storage schemes are used efficiently. (orig./RW) [de
Segregation of solute elements at grain boundaries in an ultrafine grained Al-Zn-Mg-Cu alloy
International Nuclear Information System (INIS)
Sha, Gang; Yao, Lan; Liao, Xiaozhou; Ringer, Simon P.; Chao Duan, Zhi; Langdon, Terence G.
2011-01-01
The solute segregation at grain boundaries (GBs) of an ultrafine grained (UFG) Al-Zn-Mg-Cu alloy processed by equal-channel angular pressing (ECAP) at 200 o C was characterised using three-dimensional atom probe. Mg and Cu segregate strongly to the grain boundaries. In contrast, Zn does not always show clear segregation and may even show depletion near the grain boundaries. Trace element Si selectively segregates at some GBs. An increase in the number of ECAP passes leads to a decrease in the grain size but an increase in solute segregation at the boundaries. The significant segregation of alloying elements at the boundaries of ultrafine-grained alloys implies that less solutes will be available in the matrix for precipitation with a decrease in the average grain size. -- Research Highlights: → Atom probe tomography has been employed successfully to reveal unique segregation of solutes at ultrafine grained material. → Mg and Cu elements segregated strongly at the grain boundary of an ultrafine grained Al-Zn-Mg-Cu alloy processed by 4-pass and 8-pass ECAP at 200 o C. Zn frequently depleted at GBs with a Zn depletion region of 7-15 nm in width on one or both sides of the GBs. Only a small fraction (3/13) of GBs were observed with a low level of Zn segregation where the combined Mg and Cu excess is over 3.1 atom/nm 2 . Si appeared selectively segregated at some of the GBs. → The increase in number of ECAP passes from 4 to 8 correlated with the increase in mean level segregation of Mg and Cu for both solute excess and peak concentration. → The change of plane normal of a grain boundary within 30 o only leads to a slight change in the solute segregation level.
International Nuclear Information System (INIS)
Cho, C.M.; Axmann, H.
1965-01-01
Determination of small quantities of plant nutrients in the soil solution of flooded rice soils is a difficult problem. The concentrations of Mn, Fe and P, for example, in some soil solutions are so small that no chemical method gives any accurate result. Neutron activation analysis was reported to give a much lower limit of detectability for several elements, while for elements with low-induced activity after neutron irradiation, substoichiometric isotopic dilution analysis was applied. One of the advantages of neutron activation analysis lies in the fact that simultaneous activation of every inducible element in a sample takes place. This gives an opportunity to determine many elements by one sample preparation and irradiation. This, however, is not a simple task since identification of the activated products and their quantitative estimation becomes very difficult. Certain operations of separation must be carried out before activity measurements. Ion-exchange resin columns and chemical separation following the addition of carriers were successfully used for the determination of many elements after neutron irradiation. These procedures, however, cannot be directly applied to the determination of the elements of agronomic interest. A procedure was developed to determine several elements of agronomic interest. Times of irradiation and cooling, quick separation by ion-exchange columns, together with chemical precipitation for β-emitters of relatively long half-lives, were all combined to get the maximum benefit from neutron activation analysis. For Fe, for which no satisfactory neutron activation analysis has yet been developed, a modified substoichiometric double isotope dilution procedure is applied
International Nuclear Information System (INIS)
Gabella, W.E.; Ruth, R.D.; Warnock, R.L.
1988-05-01
Periodic solutions of the Hamilton-Jacobi equation determine invariant tori in phase space. The Fourier spectrum of a torus with respect to angular coordinates gives useful information about nonlinear resonances and their potential for causing instabilities. We describe a method to solve the Hamilton-Jacobi equation for an arbitrary accelerator lattice. The method works with Fourier modes of the generating functions, and imposes periodicity in the machine azimuth by a shooting method. We give examples leading to three-dimensional plots in a surface of section. It is expected that the technique will be useful in lattice optimization. 14 refs., 6 figs., 1 tab
The speciation of dissolved elements in aquatic solution. Radium and actinides
International Nuclear Information System (INIS)
Haesaenen, E.
1994-01-01
In the publication, the chemistry and speciation of radium, thorium, protactinium, uranium, neptunium, lutonium, americium and curium in ground-water environment is reviewed. Special attention is given to the transuranium elements, which have a central role in the repository of nuclear wastes. The most important methods used in the speciation of these elements is presented. The laser-induced methods, developed in the 1980's, are especially discussed. These have made it possible, e.g., to speciate the transuranium elements in their very low, actual repository ground-water concentrations (10-100 ng/l). (54 refs., 10 figs., 3 tabs.)
International Nuclear Information System (INIS)
Biswas, Sujoy; Rupawate, V.H.; Hareendran, K.N.; Roy, S.B.
2014-01-01
A new process based on solvent extraction has been developed for separation of uranium, thorium and rare earths from monazite leach solution using organophosphorous extractants. The Thorium cake coming from monazite source was dissolved in HNO 3 medium in presence of trace amount of HF for feed preparation. The separation of U(VI) was carried out by liquid-liquid extraction using tris-2-ethyl hexyl phosphoric acid (TEHP) in dodecane leaving thorium and rare earths elements in the raffinate. The thorium from raffinate was selectively extracted using 1M tri iso amyl phosphate (TiAP) in dodecane in organic phase leaving all rare earths elements in aqueous solution. The uranium and thorium from organic medium was quantitatively stripped using 0.05 M HNO 3 counter current mode. Results indicate the quantitative separation of uranium, thorium and rare earths from thorium cake (monazite source) using organophosphorous extractant in counter current mode
Glazyrina, O. V.; Pavlova, M. F.
2016-11-01
We consider the parabolic inequality with monotone with respect to a gradient space operator, which is depended on integral with respect to space variables solution characteristic. We construct a two-layer differential scheme for this problem with use of penalty method, semidiscretization with respect to time variable method and the finite element method (FEM) with respect to space variables. We proved a convergence of constructed mothod.
Czech Academy of Sciences Publication Activity Database
Šesnic, S.; Dorić, V.; Poljak, D.; Šušnjara, A.; Artaud, J.F.
2018-01-01
Roč. 46, č. 4 (2018), s. 1027-1034 ISSN 0093-3813 R&D Projects: GA MŠk(CZ) 8D15001 Institutional support: RVO:61389021 Keywords : Finite element analysis * Tokamaks * current diffusion equation (CDE) * finite-element method (FEM) Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics) Impact factor: 1.052, year: 2016
Numerical solution of recirculating flow by a simple finite element recursion relation
Energy Technology Data Exchange (ETDEWEB)
Pepper, D W; Cooper, R E
1980-01-01
A time-split finite element recursion relation, based on linear basis functions, is used to solve the two-dimensional equations of motion. Recirculating flow in a rectangular cavity and free convective flow in an enclosed container are analyzed. The relation has the advantage of finite element accuracy and finite difference speed and simplicity. Incorporating dissipation parameters in the functionals decreases numerical dispersion and improves phase lag.
International Nuclear Information System (INIS)
Mirza, Anwar M.; Iqbal, Shaukat; Rahman, Faizur
2007-01-01
A spatially adaptive grid-refinement approach has been investigated to solve the even-parity Boltzmann transport equation. A residual based a posteriori error estimation scheme has been utilized for checking the approximate solutions for various finite element grids. The local particle balance has been considered as an error assessment criterion. To implement the adaptive approach, a computer program ADAFENT (adaptive finite elements for neutron transport) has been developed to solve the second order even-parity Boltzmann transport equation using K + variational principle for slab geometry. The program has a core K + module which employs Lagrange polynomials as spatial basis functions for the finite element formulation and Legendre polynomials for the directional dependence of the solution. The core module is called in by the adaptive grid generator to determine local gradients and residuals to explore the possibility of grid refinements in appropriate regions of the problem. The a posteriori error estimation scheme has been implemented in the outer grid refining iteration module. Numerical experiments indicate that local errors are large in regions where the flux gradients are large. A comparison of the spatially adaptive grid-refinement approach with that of uniform meshing approach for various benchmark cases confirms its superiority in greatly enhancing the accuracy of the solution without increasing the number of unknown coefficients. A reduction in the local errors of the order of 10 2 has been achieved using the new approach in some cases
Energy Technology Data Exchange (ETDEWEB)
Mirza, Anwar M. [Department of Computer Science, National University of Computer and Emerging Sciences, NUCES-FAST, A.K. Brohi Road, H-11, Islamabad (Pakistan)], E-mail: anwar.m.mirza@gmail.com; Iqbal, Shaukat [Faculty of Computer Science and Engineering, Ghulam Ishaq Khan (GIK) Institute of Engineering Science and Technology, Topi-23460, Swabi (Pakistan)], E-mail: shaukat@giki.edu.pk; Rahman, Faizur [Department of Physics, Allama Iqbal Open University, H-8 Islamabad (Pakistan)
2007-07-15
A spatially adaptive grid-refinement approach has been investigated to solve the even-parity Boltzmann transport equation. A residual based a posteriori error estimation scheme has been utilized for checking the approximate solutions for various finite element grids. The local particle balance has been considered as an error assessment criterion. To implement the adaptive approach, a computer program ADAFENT (adaptive finite elements for neutron transport) has been developed to solve the second order even-parity Boltzmann transport equation using K{sup +} variational principle for slab geometry. The program has a core K{sup +} module which employs Lagrange polynomials as spatial basis functions for the finite element formulation and Legendre polynomials for the directional dependence of the solution. The core module is called in by the adaptive grid generator to determine local gradients and residuals to explore the possibility of grid refinements in appropriate regions of the problem. The a posteriori error estimation scheme has been implemented in the outer grid refining iteration module. Numerical experiments indicate that local errors are large in regions where the flux gradients are large. A comparison of the spatially adaptive grid-refinement approach with that of uniform meshing approach for various benchmark cases confirms its superiority in greatly enhancing the accuracy of the solution without increasing the number of unknown coefficients. A reduction in the local errors of the order of 10{sup 2} has been achieved using the new approach in some cases.
International Nuclear Information System (INIS)
Pershina, V.; Trubert, D.; Le Naour, C.; Kratz, J.V.
2002-01-01
Fully relativistic molecular density-functional calculations of the electronic structures of hydrated, hydrolyzed and fluoride/chloride complexes have been performed for group-4 elements Zr, Hf, and element 104, Rf. Using the electronic density distribution data, relative values of the free energy change for hydrolysis and complex formation reactions were defined. The results show the following trend for the first hydrolysis step of the cationic species: Zr>Hf>Rf in agreement with experiments. For the complex formation in HF solutions, the trend to a decrease from Zr to Hf is continued with Rf, provided no hydrolysis takes place. At pH>0, further fluorination of hydrolyzed species or fluoro-complexes has an inversed trend in the group Rf≥Zr>Hf, with the difference between the elements being very small. For the complex formation in HCl solutions, the trend is continued with Rf, so that Zr>Hf>Rf independently of pH. A decisive energetic factor in hydrolysis or complex formation processes proved to be a predominant electrostatic metal-ligand interaction. Trends in the K d (distribution coefficient) values for the group-4 elements are expected to follow those of the complex formation
Bosch, Jessica; Stoll, Martin; Benner, Peter
2014-01-01
We consider the efficient solution of the Cahn-Hilliard variational inequality using an implicit time discretization, which is formulated as an optimal control problem with pointwise constraints on the control. By applying a semi-smooth Newton
Liu, Yun-Feng; Fan, Ying-Ying; Dong, Hui-Yue; Zhang, Jian-Xing
2017-12-01
The method used in biomechanical modeling for finite element method (FEM) analysis needs to deliver accurate results. There are currently two solutions used in FEM modeling for biomedical model of human bone from computerized tomography (CT) images: one is based on a triangular mesh and the other is based on the parametric surface model and is more popular in practice. The outline and modeling procedures for the two solutions are compared and analyzed. Using a mandibular bone as an example, several key modeling steps are then discussed in detail, and the FEM calculation was conducted. Numerical calculation results based on the models derived from the two methods, including stress, strain, and displacement, are compared and evaluated in relation to accuracy and validity. Moreover, a comprehensive comparison of the two solutions is listed. The parametric surface based method is more helpful when using powerful design tools in computer-aided design (CAD) software, but the triangular mesh based method is more robust and efficient.
International Nuclear Information System (INIS)
Sradjono; Erni Rifandriyah, A.; Zahardi
1995-01-01
Separation of uranium and rare-earth elements from Rirang ore leach solution was carried out through a two-step precipitation. Several condition affecting the separation processes were examined including solution pH, reagent concentration, and reaction prepitation time. Optimum conditions for the first and second precipitation steps include adjustment of precipitation pH to 1.3 and 2.3, respectively by the addition of 7.3% of NH 4 OH solution and allowing 60 minutes precipitation/reaction time. Based on the conditions, about 6% of Th, 3% of U, 0.9% of PO 4 3- , and none of RE were recovered in the first precipitation step meanwhile, about 99% of RE, 55% of U, 76% of PO 4 3- , and of the Th were recovered in the second step. (author). 3 refs. 4 tabs. 4 figs
The spectral element approach for the solution of neutron transport problems
International Nuclear Information System (INIS)
Barbarino, A.; Dulla, S.; Ravetto, P.; Mund, E.H.
2011-01-01
In this paper a possible application of the Spectral Element Method to neutron transport problems is presented. The basic features of the numerical scheme on the one-dimensional diffusion equation are illustrated. Then, the AN model for neutron transport is introduced, and the basic steps for the construction of a bi-dimensional solver are described. The AN equations are chosen for their structure, involving a system of coupled elliptic-type equations. Some calculations are carried out on typical benchmark problems and results are compared with the Finite Element Method, in order to evaluate their performances. (author)
Provenance determination of pottery by trace element analysis. Problems, solutions and applications
International Nuclear Information System (INIS)
Mommsen, H.
2001-01-01
Provenance determinations of pottery by chemical analysis is reviewed and shown to work well. Since pottery is produced from a well homogenized clay paste according to a certain recipe, sharp elemental patterns are expected for a series of products having the same origin. To obtain such patterns when forming compositional groups of pottery, a consideration of experimental errors, a correction for dilution and a choice of only stable elements is necessary. The patterns thus obtained will have low probability of overlap with groups of different origin. Examples for well defined groups of German stonewares and of Mycenaean wares from the Peloponnese are recorded. (author)
A solution for the integration of finite element analysis in a ship design environment
International Nuclear Information System (INIS)
Finifter, D.; Wyniecki, P.; Castel, J. de
1982-01-01
The DEMAIN system for the pre- and post-processing of finite element analyses of ship structures is presented. It is shown that this new modelling concept, although being self-contained and specialized, has features which relate it to computer-aided design applications of a more general nature. Thus, compared to other finite element pre/post-processors, it allows a more natural occurrence of the structural analysis task in the design flow and can be considered a major step towards an integrated design and analysis system. (orig.)
Rubnicu, Alin
2013-01-01
The envelope of the building often has a complex geometry in which a multitude of different sub-assemblies can be identified. The envelope elements specific to roof areas can generally be of three types: walk and non-walk terrace roof as well as roof truss. The exterior joinery analysed is PVC type with four glass sheets.
Czech Academy of Sciences Publication Activity Database
Okrouhlík, Miloslav; Pták, Svatopluk; Valdek, U.
2009-01-01
Roč. 16, č. 2 (2009), s. 103-121 ISSN 1802-1484 R&D Projects: GA AV ČR 1ET400760509 Institutional research plan: CEZ:AV0Z20760514 Keywords : stress wave propagation * finite element method * validity of models Subject RIV: BI - Acoustics
International Nuclear Information System (INIS)
Razbash, A.A.; Sevast'yanov, Yu.G.
1985-01-01
Ce(3, 4), Eu(3), Gd(3), Sm(3), Sc(3) distribution coefficients are determined in the macroporic phosphonic acid cationite KRF-20T-60 in nitric acid solutions in 0.1-2.0 M concentration interval using statistical method. A simple method of cerium-139 radionuclide extraction from the industrial lanthanum target is developed. The product yield made up more than 99%, specific activity - 2.37x10 9 Bq/mg, radiochemical purity - no less than 99.9%
Finite element limit analysis based plastic limit pressure solutions for cracked pipes
International Nuclear Information System (INIS)
Shim, Do Jun; Huh, Nam Su; Kim, Yun Jae; Kim, Young Jin
2002-01-01
Based on detailed FE limit analyses, the present paper provides tractable approximations for plastic limit pressure solutions for axial through-wall cracked pipe; axial (inner) surface cracked pipe; circumferential through-wall cracked pipe; and circumferential (inner) surface cracked pipe. Comparisons with existing analytical and empirical solutions show a large discrepancy in circumferential short through-wall cracks and in surface cracks (both axial and circumferential). Being based on detailed 3-D FE limit analysis, the present solutions are believed to be the most accurate, and thus to be valuable information not only for plastic collapse analysis of pressurised piping but also for estimating non-linear fracture mechanics parameters based on the reference stress approach
Thermometric titration of a free acid and of uranyl in spent fuel element solutions
International Nuclear Information System (INIS)
Zamek, M.; Strafelda, F.
1975-01-01
A method was elaborated of determining nitric acid in the presence of uranyl nitrate in both aqueous and non-aqueous solutions using a pyridine aqueous solution as a titration agent, and of determining excess uranyl after a hydrogen peroxide addition by a further titration using the same agent. Even a hundred-fold excess of magnesium did not disturb the titration. The method is used in operating solution analyses in the extraction fuel reprocessing in the presence of a small amount of plutonium and of fission products. The reproducibility and accuracy of the method varied in the order of tens to units per cent depending on the concentration of components to be determined. The procedure is applicable for test volumes ranging between 0.1 and 10 ml in concentrations of 1 to 10 -3 M. (author)
Bosch, Jessica
2014-04-01
We consider the efficient solution of the Cahn-Hilliard variational inequality using an implicit time discretization, which is formulated as an optimal control problem with pointwise constraints on the control. By applying a semi-smooth Newton method combined with a Moreau-Yosida regularization technique for handling the control constraints we show superlinear convergence in function space. At the heart of this method lies the solution of large and sparse linear systems for which we propose the use of preconditioned Krylov subspace solvers using an effective Schur complement approximation. Numerical results illustrate the competitiveness of this approach. © 2014 Elsevier Inc.
A POSSIBLE SOLUTION WITH PASSIVE PROTECTION STRUCTURAL RESISTANCE ELEMENTS TO CARGO SHIPS
Directory of Open Access Journals (Sweden)
MUNTEANU Ildikó Renata
2014-09-01
Full Text Available The authors are proposing an additional fire protection solution (semi-passive for cargo ships, by inserting in the tubular strength structure (hollow section, some rectangular, thin wall pipes manufactured of copper alloy, filled with cooling fluid, that, once the fire bursts, it will be activated (i.e. will be pumped into a closed circuit; this closed system contains also a well dimensioned radiator. This innovative solution could bring improvements with regard to the classic one, of intumescent paints, by extending the safe period for evacuating people and goods.
International Nuclear Information System (INIS)
L'Her, M.
1967-01-01
The aim of this work is the application of spectrophotometric titrations to the analysis of uranium-containing solutions. We have been led to examine the general principles involved in these titrations, and we give a brief outline of these principles. In the first part we deal therefore with spectrophotometric titrations from a general point of view, examining their fundamental principle, their practical execution as well as the various possibilities of the method. The advantage of the titration are examined, in particular that of lending itself simultaneous determination of two species. The possibility of applying these spectrophotometric titrations to the analysis of uranium-containing solutions is the subject of the second part of this report: the dosage of a few species in uranium (VI) solutions is described. To this second part is added an experimental appendix consisting of a description of the apparatus, as well as of the operational techniques used for certain titrations, in particular those involving solutions containing uranium. (author) [fr
International Nuclear Information System (INIS)
Correia Filho, A.
1981-04-01
The Neutron Diffusion Equation at two groups of energy is solved with the use of the Finite - Element Method with first order triangular elements. The program EFTDN (Triangular Finite Elements on Neutron Diffusion) was developed using the language FORTRAN IV. The discrete formulation of the Diffusion Equation is obtained with the application of the Galerkin's Method. In order to solve the eigenvalue - problem, the Method of the Power is applied and, with the purpose of the convergence of the results, Chebshev's polynomial expressions are applied. On the solution of the systems of equations Gauss' Method is applied, divided in two different parts: triangularization of the matrix of coeficients and retrosubstitution taking in account the sparsity of the system. Several test - problems are solved, among then two P.W.R. type reactors, the ZION-1 with 1300 MWe and the 2D-IAEA - Benchmark. Comparision of results with standard solutions show the validity of application of the EFM and precision of the results. (Author) [pt
International Nuclear Information System (INIS)
Xuan Fuzhen; Liu Changjun; Li Peining
2005-01-01
This paper is concerned with the prediction of limit load of the piping branch junctions with circumferential crack under internal pressure. Recently, we have developed a new approach for predicting the limit load of two-cylinder intersection structures with diameter ratio larger than 0.5, which has been successfully applied to defect free cases under various loading conditions. In the present work, we consider the extension of the approach to cover cracked piping branch junctions. On the basis of stress analysis in the vicinity of intersection line, a closed form of limit load solution for piping branch junctions with circumferential crack was developed. Then, 36 finite element (FE) models of piping branch junction with various dimensions of structure and crack were analyzed by using nonlinear finite element software. The limit loads from FE analysis and the proposed solution are compared with each other. Overall good agreement between the estimated solutions and the FE results provides confidence in the use of the proposed formulae for defect assessment of piping branch junctions in practice
Arbabi, Vahid; Pouran, Behdad; Zadpoor, Amir A; Weinans, Harrie
2017-04-23
Osteoarthritis (OA) is a debilitating disease that is associated with degeneration of articular cartilage and subchondral bone. Degeneration of articular cartilage impairs its load-bearing function substantially as it experiences tremendous chemical degradation, i.e. proteoglycan loss and collagen fibril disruption. One promising way to investigate chemical damage mechanisms during OA is to expose the cartilage specimens to an external solute and monitor the diffusion of the molecules. The degree of cartilage damage (i.e. concentration and configuration of essential macromolecules) is associated with collisional energy loss of external solutes while moving across articular cartilage creates different diffusion characteristics compared to healthy cartilage. In this study, we introduce a protocol, which consists of several steps and is based on previously developed experimental micro-Computed Tomography (micro-CT) and finite element modeling. The transport of charged and uncharged iodinated molecules is first recorded using micro-CT, which is followed by applying biphasic-solute and multiphasic finite element models to obtain diffusion coefficients and fixed charge densities across cartilage zones.
International Nuclear Information System (INIS)
Ferreira, Monica Barcellos Jansen; Carmo, Eduardo Gomes Dutra do
2000-01-01
Heat transfer problems in heterogenous media with large variation of thermal conductivity are notorious for the difficulties in obtaining good numerical results. In this work it is proposed an application of a new mixed discontinuous finite element formulation to this class of problems, which produces good results without the need of high mesh refinement. Stability and consistency aspects are considered and numerical results are presented to show the efficacy of the method. (author)
Organic radionuclide compounds in soil solutions and their role in elements absorption in plants
International Nuclear Information System (INIS)
Agapkin, G.I.; Tikhomirov, F.A.
1991-01-01
The results of reference experiments with introduction of radioactive labels ( 35 S, 45 Ca, 59 Fe, 85 , 125 I) into 5 types of climatophytic soils by the method of radiogel-chromatography allow to ascertain that in soil solutions 59 Fe and 125 I incorporate completely and 35 S, 45 Ca and 85 Sr incorporate by 60-90 % into the composition of one of three fractions of organic compounds with molecular masses of 4x10 2 -6x10 4 . It is shown that significant variations between soils in the absorption of such radionuclides as 4 5 Ca, 58 Fe, 85 Sr and 125 I are celated to a different degree of their transport into soil solutions as well as to differencies in their distribution by molecular-mass fractions of water-soluble organic compounds
Formation of ammonia complexes of alkaline earth elements in aqueous solutions
International Nuclear Information System (INIS)
Padar, T.G.; Stupko, T.V.; Isaev, I.D.; Pashkov, G.L.; Mironov, V.E.
1990-01-01
Coefficients of ammonia distribution between aqueous solutions of calcium, strontium, barium and ammonium perchlorate mixtures at ionic strength - 0.50; 1.0 and 1.5 at 298.2 K and ammonia concentrations 0.2-10 mol/dm 3 are measured. Formation of ammonia complexes of M(NH 3 ) n 2+ composition is shown. Logarithms of stepped stability constants for solutions with zero ionic strength for Ca 2+ are: -0.13; -0.25; -0.52 and -0.77, where n=1-4; for Sr 2+ : -0.04; -0.42 and -0.70, where n=1-3 and for Ba 2+ : -0.11; -0.50 and 0.76, where n=1-3
Energy Technology Data Exchange (ETDEWEB)
Spitsyn, V. I.; Balukova, V. D.; Gromov, V. V.; Zakharov, S. I.; Zhagin, B. P.; Spiridonov, F. M.
1960-07-01
Research on the sorption of radioisotopes under natural conditions employing the controlled filtration process was performed. Radioisotopes were introduced into the solution as soon as filtration had become steady and the process continued for four months. Soil samples were then taken by drilling at different depths and analysed to determine their radioisotope content. Diffusion of radioisotopes was observed at depths of up to 10 m; two distinct boundaries of soil-activity decrease were ascertained: at the surface of the site and at the depth of the solution filtration front. In addition, the radiostrontium absorption by natural sorbents, principally pure minerals widely distributed in soils and subsoils, was investigated separately. The presence of calcium ions, even in small quantities, sharply reduces the degree of radiostrontium sorption. However, other conditions being equal, strontium may be absorbed to a greater extent than calcium, according to the composition of the sorbent. The field investigations of radiostrontium sorption and migration showed that when filtering radioactive solutions two possible variants have to be taken into account. In the first case the solutions are discharged into soil unaffected by any flow of ground water. In this situation the radiostrontium is retained by the soil. In the second case, the radioisotopes proceed directly into the water-bearing horizon. The radiostrontium will then migrate with the ground water flow and through the soil and this migration will be further affected by the sorption and desorption processes occurring. The experiments performed demonstrate the ease with which long-lived radioisotopes migrate under natural conditions and call attention to the need for thorough study of ground water problems in connexion with various methods of disposing of radioactive waste into ground. (author)
International Nuclear Information System (INIS)
Guppy, C.B.
1962-03-01
In the methods adopted in this report transfer functions in the form of the ratio of two polynomials of the complex variable s are derived from sets of laplace transformed simultaneous differential equations. The set of algebraic simultaneous equations are solved using Cramer's Rule and this gives rise to determinants having polynomial elements. It is shown how the determinants are formed when transfer functions are specified. The procedure for finding the polynomial coefficients from a given determinant is fully described. The first method adopted is a direct one and reduces a determinant with first degree polynomial elements to secular form and follows this by an application of the similarity transformation to reduce the determinant to a form from which the polynomial coefficients can be read out directly. The programme is able to solve a single determinant with polynomial elements and this can be used to reduce an eigenvalue problem in the form of a secular determinant to polynomial form if the need arises. A description is given of the way in which the data is to be set out for solution by the programme. A description is also given of a method used in an earlier programme for solving polynomial determinants by curve fitting techniques using Chebyshev Polynomials. In this method determinants with polynomial elements of any degree can be solved. (author)
International Nuclear Information System (INIS)
Michard, A.; Albarede, F.; Michard, G.; Minster, J.F.; Charlou, J.L.
1983-01-01
The mobility of rare-earth elements (REE) and U during hydrothermal alteration of the basalts at spreading centres has long been a matter of concern because of its bearing on the evolution and recycling of the oceanic crust. Previous approaches to this problem have been indirect, through studies on altered dredged basalts or ophiolites. Sampling of hydrothermal vent waters from the East Pacific Rise (EPR) at 13 0 N is reported. It provides the first direct evidence of REE-enriched solutions which, however, leave the budget of these elements in the crust and the ocean rather unmodified. In constrast, uranium, like magnesium, is quantitatively taken up from the seawater during the hydrothermal process. (author)
Solution of the Lambda modes problem of a nuclear power reactor using an h–p finite element method
International Nuclear Information System (INIS)
Vidal-Ferrandiz, A.; Fayez, R.; Ginestar, D.; Verdú, G.
2014-01-01
Highlights: • An hp finite element method is proposed for the Lambda modes problem of a nuclear reactor. • Different strategies can be implemented for increasing the accuracy of the solutions. • 2D and 3D benchmarks have been studied obtaining accurate results. - Abstract: Lambda modes of a nuclear power reactor have interest in reactor physics since they have been used to develop modal methods and to study BWR reactor instabilities. An h–p-Adaptation finite element method has been implemented to compute the dominant modes the fundamental mode and the next subcritical modes of a nuclear reactor. The performance of this method has been studied in three benchmark problems, a homogeneous 2D reactor, the 2D BIBLIS reactor and the 3D IAEA reactor
Directory of Open Access Journals (Sweden)
GONCHARENKO D. F.
2017-01-01
Full Text Available Problem statement. Currently sanitary drainage systems of large cities in Ukraine are significantly worn down with prolonged use and due to inefficient solutions for protection of the structures from aggressive effects of the environment, poor quality of materials and construction and installation works during building. Restoration of performance characteristics, reliability and durability of sewer tunnels is the costly and technically complex task, which is urgently needed to be fulfilled to prevent accidents including those with serious environmental impact. Modern work technique and the materials used for restoration allow us to solve these problems with different levels of efficiency, while reducing the cost of restoration due to use of recycled polymeric raw material, as well as to improvement of technological solutions is a currently important direction of research. Purpose of the article. To develop solutions for restoring serviceability, reliability and durability of sewer tunnels taking into account the accumulated experience in renovation of water disposal networks. Conclusion. Use of components made of recycled polymer composite materials during restoring sewer tunnels has significant economic and environmental effects and allows to undertake repair work in hard-to-reach areas.
International Nuclear Information System (INIS)
Cunha Furtado, F. da; Galeao, A.C.N.R.
1984-01-01
A numerical procedure for the integration of the incompressible Navier-Stokes equations, when expressed in terms of a stream function equation and a vorticity transport equation, is presented. This procedure comprises: the variational formulation of the equations, the construction of the approximation spaces by the finite element method and the discretization via the Galerkin method. For the stationary problems, the system of non-linear algebraic equations resulting from the discretization is solved by the Newton-Raphson algorithm. Finally, for the transient problems, the solution of the non-linear ordinary differential equations resulting from the spatial discretization is accomplished through a Crank-Nicolson scheme. (Author) [pt
International Nuclear Information System (INIS)
Hubert, J.
1979-01-01
The variational finite element method (of the Rayleigh-Ritz type) has been applied to solve the standard diffusion-convection equation of radial flow in a dispersive medium. It was shown that the imposing of the boundary condition ΔC/Δx = 0 (=null concentration gradient) introduced great errors in computation results. To remedy it this condition was imposed at the free end of the artifical domain. Its other end joined to the downstream boundary of the investigated domain. The results of calculations compared with the known analytical solutions of the parallel flow show their good accuracy. The method was used to discuss the applicability of the approximate analytical solutions of the radial flow. (author)
Liu, Meilin
2012-08-01
A discontinuous Galerkin finite element method (DG-FEM) with a highly accurate time integration scheme for solving Maxwell equations is presented. The new time integration scheme is in the form of traditional predictor-corrector algorithms, PE CE m, but it uses coefficients that are obtained using a numerical scheme with fully controllable accuracy. Numerical results demonstrate that the proposed DG-FEM uses larger time steps than DG-FEM with classical PE CE) m schemes when high accuracy, which could be obtained using high-order spatial discretization, is required. © 1963-2012 IEEE.
Energy Technology Data Exchange (ETDEWEB)
Lipnikov, Konstantin [Los Alamos National Laboratory; Agouzal, Abdellatif [UNIV DE LYON; Vassilevski, Yuri [Los Alamos National Laboratory
2009-01-01
We present a new technology for generating meshes minimizing the interpolation and discretization errors or their gradients. The key element of this methodology is construction of a space metric from edge-based error estimates. For a mesh with N{sub h} triangles, the error is proportional to N{sub h}{sup -1} and the gradient of error is proportional to N{sub h}{sup -1/2} which are optimal asymptotics. The methodology is verified with numerical experiments.
Liu, Meilin; Sirenko, Kostyantyn; Bagci, Hakan
2012-01-01
A discontinuous Galerkin finite element method (DG-FEM) with a highly accurate time integration scheme for solving Maxwell equations is presented. The new time integration scheme is in the form of traditional predictor-corrector algorithms, PE CE m, but it uses coefficients that are obtained using a numerical scheme with fully controllable accuracy. Numerical results demonstrate that the proposed DG-FEM uses larger time steps than DG-FEM with classical PE CE) m schemes when high accuracy, which could be obtained using high-order spatial discretization, is required. © 1963-2012 IEEE.
Shan, Xiao-Quan; Wang, Zhongwen; Wang, Weisheng; Zhang, Shuzhen; Wen, Bei
2003-02-01
A labile rhizosphere soil solution fraction has been recommended to predict the bioavailability of heavy metals and rare earth elements to plants. This method used moist rhizosphere soil in combination with a mixture of 0.01 mol L(-1) of low-molecular-weight organic acids (LMWOAs) as extractant. The extracted soil solutions were fractionated into two colloidal fractions of soil solution fraction, F(lrss). For the soil solutions extracted with a mixture of LMWOAs the concentrations of heavy metals and rare earth elements in F(2) and F(3) were quite similar. However, the mean concentrations of Cr, Ni, Zn, Cu, Pb, Cd, La, Ce, Pr, and Nd in F(lrss) accounted for 79.9%, 91.3%, 90.8%, 60.1%, 77.5%, 75.3%, 81.2%, 77.2%, 80.3%, and 79.5%, respectively, of their concentrations in F(2). In contrast, there were no differences in the extractable metal concentrations between the three fractions while the first step of the method recommended by the European Community of Reference (BCR), where 0.1 mol L(-1) acetic acid was used as an extractant. The single correlation analysis was made between metal concentrations in the different fractions of soil solutions and their concentrations in wheat. If the first step of BCR method was used there was no good correlation between heavy metals in soil pools and that in wheat shoots and roots. When LMWAOs were used a good correlation was obtained between the concentrations of heavy metals in soil pools and that in wheat roots, which followed a general order of r(1 kD, LMWOAs) >r(0.2 microm, LMWOAs) approximately r(0.45 microm, LMWOAs). In the case of rare earth elements the good correlation was obtained for both the wheat roots and shoots. Generally, the correlation coefficients obtained by LMWAOs were better than that obtained by the first step of BCR method. Therefore, LMWAOs and F(lrss) were strongly recommended to predict the bioavailability of metals in soil pools to plants.
Effect of solute elements on hardening of thermally-aged RPV model alloys
International Nuclear Information System (INIS)
Nomoto, A.; Nishida, K.; Dohi, K.; Soneda, N.; Liu, L.; Sekimura, N.; Li, Z.
2015-01-01
Embrittlement correlation methods for irradiated reactor pressure vessel (RPV) steels have been developed worldwide to predict the amount of embrittlement during plant operation. The effect of chemical composition on embrittlement is not fully understood, particularly the process of solute atom behavior during solute atom formation. In this series of slides we report the results of thermal ageing experiments of RPV model alloys in order to obtain information on the effect of chemical composition on the hardening process. We can draw the following conclusions. First, the addition of Ni or Si alone to Fe-Cu model alloys does not have clear effect but the addition of Mn to Fe-Cu-Ni alloy accelerates the cluster formation and hardening drastically, the effect of composition on the cluster strength is not clear. Secondly, the hardening process before the hardening peak has linear correlation with APT (Atom Probe Tomography) results and the RSS (Root-Sum-Square)sum model seems to explain the relationship between increase in hardness and APT data in a more consistent manner
Numerical solution of critical state in superconductivity by finite element software
Energy Technology Data Exchange (ETDEWEB)
Hong, Z; Campbell, A M; Coombs, T A [Cambridge University Engineering Department, Trumpington Street, Cambridge CB2 1PZ (United Kingdom)
2006-12-15
A numerical method is proposed to analyse the electromagnetic behaviour of systems including high-temperature superconductors (HTSCs) in time-varying external fields and superconducting cables carrying AC transport current. The E-J constitutive law together with an H-formulation is used to calculate the current distribution and electromagnetic fields in HTSCs, and the magnetization of HTSCs; then the forces in the interaction between the electromagnet and the superconductor and the AC loss of the superconducting cable can be obtained. This numerical method is based on solving the partial differential equations time dependently and is adapted to the commercial finite element software Comsol Multiphysics 3.2. The advantage of this method is to make the modelling of the superconductivity simple, flexible and extendable.
A Finite Element Solution of Lateral Periodic Poisson–Boltzmann Model for Membrane Channel Proteins
Xu, Jingjie; Lu, Benzhuo
2018-01-01
Membrane channel proteins control the diffusion of ions across biological membranes. They are closely related to the processes of various organizational mechanisms, such as: cardiac impulse, muscle contraction and hormone secretion. Introducing a membrane region into implicit solvation models extends the ability of the Poisson–Boltzmann (PB) equation to handle membrane proteins. The use of lateral periodic boundary conditions can properly simulate the discrete distribution of membrane proteins on the membrane plane and avoid boundary effects, which are caused by the finite box size in the traditional PB calculations. In this work, we: (1) develop a first finite element solver (FEPB) to solve the PB equation with a two-dimensional periodicity for membrane channel proteins, with different numerical treatments of the singular charges distributions in the channel protein; (2) add the membrane as a dielectric slab in the PB model, and use an improved mesh construction method to automatically identify the membrane channel/pore region even with a tilt angle relative to the z-axis; and (3) add a non-polar solvation energy term to complete the estimation of the total solvation energy of a membrane protein. A mesh resolution of about 0.25 Å (cubic grid space)/0.36 Å (tetrahedron edge length) is found to be most accurate in linear finite element calculation of the PB solvation energy. Computational studies are performed on a few exemplary molecules. The results indicate that all factors, the membrane thickness, the length of periodic box, membrane dielectric constant, pore region dielectric constant, and ionic strength, have individually considerable influence on the solvation energy of a channel protein. This demonstrates the necessity to treat all of those effects in the PB model for membrane protein simulations. PMID:29495644
International Nuclear Information System (INIS)
Pershina, V.; Bastug, T.
1999-01-01
Calculations of the electronic structure of MF 6 - and MBr 6 - complexes of Nb, Ta, Pa and element 105, Db, formed in HF and HBr solutions have been performed using the Dirac-Slater Discrete Variational method. On the basis of results of these calculations, relative values of the free energy change of reactions of complex formation have been determined. The order of the complex formation for both acids is shown to be Pa >> Nb > Db > Ta. Such a sequence is defined by a predominant electrostatic energy of the metal-ligand interaction. The hydrolysis of compounds, as a reverse process, proved to change as Ta > Db > Nb >> Pa. Using the theory of metal extraction by anion exchange, the following trend in the extraction of the anionic species from both the HF and HBr aqueous solutions has been predicted: Pa >> Nb ≥ Db > Ta. The strength of the ML 6 - complexes is shown to decrease from MF 6 , to MCl 6 and further to MBr 6 - which is reflected by shifting the complex formation process to the area of higher acid concentrations. (orig.)
Adib, Arash; Poorveis, Davood; Mehraban, Farid
2018-03-01
In this research, two equations are considered as examples of hyperbolic and elliptic equations. In addition, two finite element methods are applied for solving of these equations. The purpose of this research is the selection of suitable method for solving each of two equations. Burgers' equation is a hyperbolic equation. This equation is a pure advection (without diffusion) equation. This equation is one-dimensional and unsteady. A sudden shock wave is introduced to the model. This wave moves without deformation. In addition, Laplace's equation is an elliptical equation. This equation is steady and two-dimensional. The solution of Laplace's equation in an earth dam is considered. By solution of Laplace's equation, head pressure and the value of seepage in the directions X and Y are calculated in different points of earth dam. At the end, water table is shown in the earth dam. For Burgers' equation, least-square method can show movement of wave with oscillation but Galerkin method can not show it correctly (the best method for solving of the Burgers' equation is discrete space by least-square finite element method and discrete time by forward difference.). For Laplace's equation, Galerkin and least square methods can show water table correctly in earth dam.
A Boundary Element Solution to the Problem of Interacting AC Fields in Parallel Conductors
Directory of Open Access Journals (Sweden)
Einar M. Rønquist
1984-04-01
Full Text Available The ac fields in electrically insulated conductors will interact through the surrounding electromagnetic fields. The pertinent field equations reduce to the Helmholtz equation inside each conductor (interior problem, and to the Laplace equation outside the conductors (exterior problem. These equations are transformed to integral equations, with the magnetic vector potential and its normal derivative on the boundaries as unknowns. The integral equations are then approximated by sets of algebraic equations. The interior problem involves only unknowns on the boundary of each conductor, while the exterior problem couples unknowns from several conductors. The interior and the exterior problem are coupled through the field continuity conditions. The full set of equations is solved by standard Gaussian elimination. We also show how the total current and the dissipated power within each conductor can be expressed as boundary integrals. Finally, computational results for a sample problem are compared with a finite difference solution.
International Nuclear Information System (INIS)
Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.
1993-10-01
Sixty commercially available or experimental absorber materials were evaluated for partitioning high-level radioactive waste. These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. The distributions of 14 elements onto each absorber were measured from simulated solutions that represent acid-dissolved sludge and alkaline supernate solutions from Hanford high-level waste (HLW) Tank 102-SY. The selected elements, which represent fission products (Ce, Cs, Sr, Tc, and Y); actinides (U, Pu, and Am); and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr), were traced by radionuclides and assayed by gamma spectrometry. Distribution coefficients for each of the 1680 element/absorber/solution combinations were measured for dynamic contact periods of 30 min, 2 h, and 6 h to provide sorption kinetics information for the specified elements from these complex media. More than 5000 measured distribution coefficients are tabulated
International Nuclear Information System (INIS)
Ensor, D.D.
1984-01-01
This final report summarizes the significant results obtained during our investigation of the fundamental solution properties of the transuranium elements for the period July 1, 1979 to September 30, 1984. Primary interest of the project was the development of improved separation methods for the trivalent actinide elements from each other and from the chemically similar trivalent lanthanide elements using solvent extraction techniques. Two different synergistic systems were investigated. The combination of dialkynaphthalenesulfonic acids with a crown ether or an oxime was an attempt to combine the excellent ion exchange properties of the sulfonic extractant with a synergistic agent which would improve the selectivity of the extraction system. The results showed that the presence of the crown ether improved the extraction of the light lanthanides by approximately 50% while the heavy lanthanides were unaffected. The use of the oxime in combination with the sulfonic acid extractant showed significant enhancement for all metal ions studied but little, if any, selectivity. The use of novel oxygen donors as synergistic agents in combination with thenoyltrifluoroacetone provided significant enhancement for the extraction of trivalent lanthanides and actinides. The data showed the best selectivity was obtained using a linear polyether as the synergistic agent. The crown ether and the cryptand showed significant synergistic capabilities but lacked selectivity due to their rigid cavities. The results of this study indicate that the linear polyether is more promising as a synergistic agent because of its flexibility and ease of chemical modification of the end groups. 10 figures, 5 tables
Energy Technology Data Exchange (ETDEWEB)
Alleon, G. [EADS-CCR, 31 - Blagnac (France); Carpentieri, B.; Du, I.S.; Giraud, L.; Langou, J.; Martin, E. [Cerfacs, 31 - Toulouse (France)
2003-07-01
The boundary element method has become a popular tool for the solution of Maxwell's equations in electromagnetism. It discretizes only the surface of the radiating object and gives rise to linear systems that are smaller in size compared to those arising from finite element or finite difference discretizations. However, these systems are prohibitively demanding in terms of memory for direct methods and challenging to solve by iterative methods. In this paper we address the iterative solution via preconditioned Krylov methods of electromagnetic scattering problems expressed in an integral formulation, with main focus on the design of the pre-conditioner. We consider an approximate inverse method based on the Frobenius-norm minimization with a pattern prescribed in advance. The pre-conditioner is constructed from a sparse approximation of the dense coefficient matrix, and the patterns both for the pre-conditioner and for the coefficient matrix are computed a priori using geometric information from the mesh. We describe the implementation of the approximate inverse in an out-of-core parallel code that uses multipole techniques for the matrix-vector products, and show results on the numerical scalability of our method on systems of size up to one million unknowns. We propose an embedded iterative scheme based on the GMRES method and combined with multipole techniques, aimed at improving the robustness of the approximate inverse for large problems. We prove by numerical experiments that the proposed scheme enables the solution of very large and difficult problems efficiently at reduced computational and memory cost. Finally we perform a preliminary study on a spectral two-level pre-conditioner to enhance the robustness of our method. This numerical technique exploits spectral information of the preconditioned systems to build a low rank-update of the pre-conditioner. (authors)
International Nuclear Information System (INIS)
Alleon, G.; Carpentieri, B.; Du, I.S.; Giraud, L.; Langou, J.; Martin, E.
2003-01-01
The boundary element method has become a popular tool for the solution of Maxwell's equations in electromagnetism. It discretizes only the surface of the radiating object and gives rise to linear systems that are smaller in size compared to those arising from finite element or finite difference discretizations. However, these systems are prohibitively demanding in terms of memory for direct methods and challenging to solve by iterative methods. In this paper we address the iterative solution via preconditioned Krylov methods of electromagnetic scattering problems expressed in an integral formulation, with main focus on the design of the pre-conditioner. We consider an approximate inverse method based on the Frobenius-norm minimization with a pattern prescribed in advance. The pre-conditioner is constructed from a sparse approximation of the dense coefficient matrix, and the patterns both for the pre-conditioner and for the coefficient matrix are computed a priori using geometric information from the mesh. We describe the implementation of the approximate inverse in an out-of-core parallel code that uses multipole techniques for the matrix-vector products, and show results on the numerical scalability of our method on systems of size up to one million unknowns. We propose an embedded iterative scheme based on the GMRES method and combined with multipole techniques, aimed at improving the robustness of the approximate inverse for large problems. We prove by numerical experiments that the proposed scheme enables the solution of very large and difficult problems efficiently at reduced computational and memory cost. Finally we perform a preliminary study on a spectral two-level pre-conditioner to enhance the robustness of our method. This numerical technique exploits spectral information of the preconditioned systems to build a low rank-update of the pre-conditioner. (authors)
Rare earth elements in sedimentary phosphate deposits: Solution to the global REE crisis?
Emsbo, Poul; McLaughlin, Patrick I.; Breit, George N.; du Bray, Edward A.; Koenig, Alan E.
2015-01-01
The critical role of rare earth elements (REEs), particularly heavy REEs (HREEs), in high-tech industries has created a surge in demand that is quickly outstripping known global supply and has triggered a worldwide scramble to discover new sources. The chemical analysis of 23 sedimentary phosphate deposits (phosphorites) in the United States demonstrates that they are significantly enriched in REEs. Leaching experiments using dilute H2SO4 and HCl, extracted nearly 100% of their total REE content and show that the extraction of REEs from phosphorites is not subject to the many technological and environmental challenges that vex the exploitation of many identified REE deposits. Our data suggest that phosphate rock currently mined in the United States has the potential to produce a significant proportion of the world's REE demand as a byproduct. Importantly, the size and concentration of HREEs in some unmined phosphorites dwarf the world's richest REE deposits. Secular variation in phosphate REE contents identifies geologic time periods favorable for the formation of currently unrecognized high-REE phosphates. The extraordinary endowment, combined with the ease of REE extraction, indicates that such phosphorites might be considered as a primary source of REEs with the potential to resolve the global REE (particularly for HREE) supply shortage.
International Nuclear Information System (INIS)
Cho, Moon Sung; Kim, Y. M.; Lee, Y. W.
2006-01-01
The fundamental design for a gas-cooled reactor relies on an understanding of the behavior of a coated particle fuel. KAERI, which has been carrying out the Korean VHTR (Very High Temperature modular gas cooled Reactor) Project since 2004, is developing a fuel performance analysis code for a VHTR named COPA (COated Particle fuel Analysis). A validation of COPA was attempted by comparing its benchmark results with the visco-elastic solutions obtained from the ABAQUS code calculations for the IAEA-CRP-6 TRISO coated particle benchmark problems involving a creep, swelling, and pressure. However, the ABAQUS finite element model used for the above-mentioned analysis did not consider the material nonlinearity of the SiC coating layer that showed stress levels higher than the assumed yield point of the material. In this study, a consideration of the material nonlinearity is included in the ABAQUS model to obtain the visco-elastoplastic solutions and the results are compared with the visco-elastic solutions obtained from the previous ABAQUS model
Ash, Christopher; Drábek, Ondřej; Tejnecký, Václav; Jehlička, Jan; Michon, Ninon; Borůvka, Luboš
2016-01-01
Shredded card (SC) was assessed for use as a sorbent of potentially toxic elements (PTE) carried from contaminated soil in various leachates (oxalic acid, formic acid, CaCl2, water). We further assessed SC for retention of PTE, using acidified water (pH 3.4). Vertical columns and a peristaltic pump were used to leach PTE from soils (O and A/B horizons) before passing through SC. Sorption onto SC was studied by comparing leachates, and by monitoring total PTE contents on SC before and after leaching. SC buffers against acidic soil conditions that promote metals solubility; considerable increases in solution pH (+4.49) were observed. Greatest differences in solution PTE content after leaching with/without SC occurred for Pb. In oxalic acid, As, Cd, Pb showed a high level of sorption (25, 15, and 58x more of the respective PTE in leachates without SC). In formic acid, Pb sorption was highly efficient (219x more Pb in leachate without SC). In water, only Pb showed high sorption (191x more Pb in leachate without SC). In desorption experiments, release of PTE from SC varied according to the source of PTE (organic/mineral soil), and type of solvent used. Arsenic was the PTE most readily leached in desorption experiments. Low As sorption from water was followed by fast release (70% As released from SC). A high rate of Cd sorption from organic acid solutions was followed by strong retention (~12% Cd desorption). SC also retained Pb after sorption from water, with subsequent losses of ≤8.5% of total bound Pb. The proposed use of this material is for the filtration of PTE from extract solution following soil washing. Low-molecular-mass organic acids offer a less destructive, biodegradable alternative to strong inorganic acids for soil washing. PMID:26900684
Directory of Open Access Journals (Sweden)
Christopher Ash
Full Text Available Shredded card (SC was assessed for use as a sorbent of potentially toxic elements (PTE carried from contaminated soil in various leachates (oxalic acid, formic acid, CaCl2, water. We further assessed SC for retention of PTE, using acidified water (pH 3.4. Vertical columns and a peristaltic pump were used to leach PTE from soils (O and A/B horizons before passing through SC. Sorption onto SC was studied by comparing leachates, and by monitoring total PTE contents on SC before and after leaching. SC buffers against acidic soil conditions that promote metals solubility; considerable increases in solution pH (+4.49 were observed. Greatest differences in solution PTE content after leaching with/without SC occurred for Pb. In oxalic acid, As, Cd, Pb showed a high level of sorption (25, 15, and 58x more of the respective PTE in leachates without SC. In formic acid, Pb sorption was highly efficient (219x more Pb in leachate without SC. In water, only Pb showed high sorption (191x more Pb in leachate without SC. In desorption experiments, release of PTE from SC varied according to the source of PTE (organic/mineral soil, and type of solvent used. Arsenic was the PTE most readily leached in desorption experiments. Low As sorption from water was followed by fast release (70% As released from SC. A high rate of Cd sorption from organic acid solutions was followed by strong retention (~12% Cd desorption. SC also retained Pb after sorption from water, with subsequent losses of ≤8.5% of total bound Pb. The proposed use of this material is for the filtration of PTE from extract solution following soil washing. Low-molecular-mass organic acids offer a less destructive, biodegradable alternative to strong inorganic acids for soil washing.
Directory of Open Access Journals (Sweden)
A. Kazakov
2016-12-01
Full Text Available The paper discusses a nonlinear parabolic equation describing the process of heat conduction for the case of the power dependence of the heat conductivity factor on temperature. Besides heat distribution in space, it describes filtration of a polytropic gas in a porous medium, whereupon, in the English-language literature, this equation is generally referred to as the porous medium equation. A distinctive feature of this equation is the degeneration of its parabolic type when the required function becomes zero, whereupon the equation acquires some properties typical of first-order equations. Particularly, in some cases, it proves possible to substantiate theorems of the existence and uniqueness of heat-wave (filtration-wave type solutions for it. This paper proves a theorem of the existence and uniqueness of the solution to the problem of the motion of a heat wave with a specified front in the instance of two independent variables. At that, since the front has the form of a closed plane curve, a transition t o the polar coordinate system is performed. The solution is constructed in the form of a series, a constructible recurrent procedure for calculating its coefficients being proposed. The series convergence is proved by the majorant method. A boundary-element-based computation algorithm in the form of a computer program has been developed and implemented to solve the problem under study. Test examples are considered, the calculations made by a program designed by the authors being compared with the truncated series. A good agreement of the obtained results has been established.
International Nuclear Information System (INIS)
Souza, Altivo Monteiro de
2008-12-01
The world energy consumption has been increasing strongly in recent years. Nuclear energy has been regarded as a suitable option to supply this growing energy demand in industrial scale. In view of the need of improving the understanding and capacity of analysis of nuclear power plants, modern simulation techniques for flow and heat transfer problems are gaining greater importance. A large number of problems found in nuclear reactor engineering can be dealt assuming axial symmetry. Thus, in this work a stabilized finite element formulation for the solution of the Navier-Stokes and energy equations for axisymmetric problems have been developed and tested. The formulation has been implemented in the NS S OLVER M PI 2 D A program developed at the Parallel Computation Laboratory of the Instituto de Engenharia Nuclear (LCP/IEN) and is now available either for safety analysis or design of nuclear systems. (author)
International Nuclear Information System (INIS)
Vieira, Andre Luiz Pinto da Silva
2000-01-01
As the auxiliary oils used in machining evolved from integral into aqueous emulsion, and later on into aqueous-solution synthetic oils, the components cleaning process with organic solvents, originally adopted at the Fuel Element Factory (FEC), Industrias Nucleares do Brasil S.A. (INB) began to present problems in removing oil residues from machined components, due to the incompatibility between aqueous and organic media. In order to eliminate such incompatibility and adapt the process to the environmental laws restricting production and use of chlorinated or fluorinated solvents as a measure for preserving the atmosphere's ozone layer, in 1995 INB initiated the development of a components cleaning process using biodegradable aqueous detergent. The effort was completed in 2000 with the construction of a machine in keeping with the specific geometry of the fuel-assembly components and the operating conditions required for working with the new process. (author)
Dudar, O. I.; Dudar, E. S.
2017-11-01
The features of application of the 1D dimensional finite element method (FEM) in combination with the laminar solutions method (LSM) for the calculation of underground ventilating networks are considered. In this case the processes of heat and mass transfer change the properties of a fluid (binary vapour-air mix). Under the action of gravitational forces it leads to such phenomena as natural draft, local circulation, etc. The FEM relations considering the action of gravity, the mass conservation law, the dependence of vapour-air mix properties on the thermodynamic parameters are derived so that it allows one to model the mentioned phenomena. The analogy of the elastic and plastic rod deformation processes to the processes of laminar and turbulent flow in a pipe is described. Owing to this analogy, the guaranteed convergence of the elastic solutions method for the materials of plastic type means the guaranteed convergence of the LSM for any regime of a turbulent flow in a rough pipe. By means of numerical experiments the convergence rate of the FEM - LSM is investigated. This convergence rate appeared much higher than the convergence rate of the Cross - Andriyashev method. Data of other authors on the convergence rate comparison for the finite element method, the Newton method and the method of gradient are provided. These data allow one to conclude that the FEM in combination with the LSM is one of the most effective methods of calculation of hydraulic and ventilating networks. The FEM - LSM has been used for creation of the research application programme package “MineClimate” allowing to calculate the microclimate parameters in the underground ventilating networks.
International Nuclear Information System (INIS)
Cao, Menghua; Hu, Yuan; Sun, Qian; Wang, Linling; Chen, Jing; Lu, Xiaohua
2013-01-01
This study investigated the simultaneous desorption of trace metal elements and polychlorinated biphenyl (PCB) from mixed contaminated soil with a novel combination of biosurfactant saponin and biodegradable chelant S,S-ethylenediaminedisuccinic acid (EDDS). Results showed significant promotion and synergy on Pb, Cu and PCB desorption with the mixed solution of saponin and EDDS. The maximal desorption of Pb, Cu and PCB were achieved 99.8%, 85.7% and 45.7%, respectively, by addition of 10 mM EDDS and 3000 mg L −1 saponin. The marked interaction between EDDS and saponin contributed to the synergy performance. The sorption of EDDS and saponin on soil was inhibited by each other. EDDS could enhance the complexation of metals with the saponin micelles and the solubilization capabilities of saponin micelles for PCB. Our study suggests the combination of saponin and EDDS would be a promising alternative for remediation of co-contaminated soils caused by hydrophobic organic compounds (HOCs) and metals. -- Highlights: ► A novel combination of biosurfactant saponin and EDDS was used to simultaneously remove mixed contaminations from soil. ► Significant synergy on Pb, Cu and PCB desorption were achieved with EDDS/saponin. ► The marked interaction between EDDS and saponin contributed to the synergy performance. -- Significant synergistic effect on Pb, Cu and PCB desorption were achieved with the mixed solution of saponin and EDDS
Martínez-Fernández, Domingo; Bingöl, Deniz; Komárek, Michael
2014-07-15
Two experiments were carried out to study the competition for adsorption between trace elements (TEs) and nutrients following the application of nano-maghemite (NM) (iron nano-oxide; Fe2O3) to a soil solution (the 0.01molL(-1) CaCl2 extract of a TEs-contaminated soil). In the first, the nutrients K, N, and P were added to create a set of combinations: potential availability of TEs during their interaction with NM and nutrients were studied. In the second, response surface methodology was used to develop predictive models by central composite design (CCD) for competition between TEs and the nutrients K and N for adsorption onto NM. The addition of NM to the soil solution reduced specifically the concentrations of available As and Cd, but the TE-adsorption capacity of NM decreased as the P concentration increased. The CCD provided more concise and valuable information, appropriate to estimate the behavior of NM sequestering TEs: according to the suggested models, K(+) and NH4(+) were important factors for Ca, Fe, Mg, Mn, Na, and Zn adsorption (Radj(2)=95%, except for Zn with Radj(2)=87%). The obtained information and models can be used to predict the effectiveness of NM for the stabilization of TEs, crucial during the phytoremediation of contaminated soils. Copyright © 2014 Elsevier B.V. All rights reserved.
Energy Technology Data Exchange (ETDEWEB)
Birkholzer, J.; Karasaki, K. [Lawrence Berkeley National Lab., CA (United States). Earth Sciences Div.
1996-07-01
Fracture network simulators have extensively been used in the past for obtaining a better understanding of flow and transport processes in fractured rock. However, most of these models do not account for fluid or solute exchange between the fractures and the porous matrix, although diffusion into the matrix pores can have a major impact on the spreading of contaminants. In the present paper a new finite element code TRIPOLY is introduced which combines a powerful fracture network simulator with an efficient method to account for the diffusive interaction between the fractures and the adjacent matrix blocks. The fracture network simulator used in TRIPOLY features a mixed Lagrangian-Eulerian solution scheme for the transport in fractures, combined with an adaptive gridding technique to account for sharp concentration fronts. The fracture-matrix interaction is calculated with an efficient method which has been successfully used in the past for dual-porosity models. Discrete fractures and matrix blocks are treated as two different systems, and the interaction is modeled by introducing sink/source terms in both systems. It is assumed that diffusive transport in the matrix can be approximated as a one-dimensional process, perpendicular to the adjacent fracture surfaces. A direct solution scheme is employed to solve the coupled fracture and matrix equations. The newly developed combination of the fracture network simulator and the fracture-matrix interaction module allows for detailed studies of spreading processes in fractured porous rock. The authors present a sample application which demonstrate the codes ability of handling large-scale fracture-matrix systems comprising individual fractures and matrix blocks of arbitrary size and shape.
International Nuclear Information System (INIS)
Crevoisier, D.; Voltz, M.; Chanzy, A.
2009-01-01
Ross [Ross PJ. Modeling soil water and solute transport - fast, simplified numerical solutions. Agron J 2003;95:1352-61] developed a fast, simplified method for solving Richards' equation. This non-iterative 1D approach, using Brooks and Corey [Brooks RH, Corey AT. Hydraulic properties of porous media. Hydrol. papers, Colorado St. Univ., Fort Collins: 1964] hydraulic functions, allows a significant reduction in computing time while maintaining the accuracy of the results. The first aim of this work is to confirm these results in a more extensive set of problems, including those that would lead to serious numerical difficulties for the standard numerical method. The second aim is to validate a generalisation of the Ross method to other mathematical representations of hydraulic functions. The Ross method is compared with the standard finite element model, Hydrus-1D [Simunek J, Sejna M, Van Genuchten MTh. The HYDRUS-1D and HYDRUS-2D codes for estimating unsaturated soil hydraulic and solutes transport parameters. Agron Abstr 357; 1999]. Computing time, accuracy of results and robustness of numerical schemes are monitored in 1D simulations involving different types of homogeneous soils, grids and hydrological conditions. The Ross method associated with modified Van Genuchten hydraulic functions [Vogel T, Cislerova M. On the reliability of unsaturated hydraulic conductivity calculated from the moisture retention curve. Transport Porous Media 1988:3:1-15] proves in every tested scenario to be more robust numerically, and the compromise of computing time/accuracy is seen to be particularly improved on coarse grids. Ross method run from 1.25 to 14 times faster than Hydrus-1D. (authors)
International Nuclear Information System (INIS)
Aly, M.M.I.
2010-01-01
Lanthanide elements such as lanthanum and neodymium are important elements in photo-electronic and metallurgical industries as well as in nuclear technology. The main constituents of the spent nuclear fuel are actinides like uranium, thorium and various fission products including lanthanides. The co-ordination compounds of the trivalent lanthanum and neodymium continues to be an active research area, which includes the specific spectroscopic and magnetic properties of rare earth ions and their applications as super molecular device, contrast-enhancing agents in magnetic resonance imaging, optical signal amplifiers and electroluminescent (EL) devices. Hence, the separation and purification of these elements is of great concern. Solvent extraction technique is employed to separate and purify rare earth elements in an industrial scale, but the separation of lanthanum and neodymium is a difficult task, as lanthanide ions exhibit similar chemical and physical properties. They have generally common and stable +3 oxidation state that requires synthesis of certain extractants which are able to extract them from different aqueous solutions. During the last twenty years, different publications have pointed out the remarkable properties of alkyl amide in the field of separation chemistry. These extractants are able to form stable co-ordination compounds with different metallic ions. In this concern, this thesis deals with the synthesis of different amide extractants namely N, N diethylacetoamide (DEAA), N, N Teteraphenyl malonamide (TPMA), N, N diphenylbenzamide (DPBA), N, N' diphenylacetoamide (DPAA), and N, N' Teteraethyl malonamide (TEMA), which were synthesized, characterized and compared with Aliquat-336 in kerosene for extraction and separation of La (III) and Nd (III). The effect of the different parameters affecting the extraction of these metals from aqueous nitric acid medium in the different systems has been studied in terms of shaking time, nitric acid, hydrogen
Energy Technology Data Exchange (ETDEWEB)
Ryu, Eun Hyun; Song, Yong Mann; Park, Joo Hwan [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)
2013-05-15
If time-dependent equation is solved with the FEM, the limitation of the input geometry will disappear. It has often been pointed out that the numerical methods implemented in the RFSP code are not state-of-the-art. Although an acceleration method such as the Coarse Mesh Finite Difference (CMFD) for Finite Difference Method (FDM) does not exist for the FEM, one should keep in mind that the number of time steps for the transient simulation is not large. The rigorous formulation in this study will richen the theoretical basis of the FEM and lead to an extension of the dynamics code to deal with a more complicated problem. In this study, the formulation for the 1-D, 1-G Time Dependent Neutron Diffusion Equation (TDNDE) without consideration of the delay neutron will first be done. A problem including one multiplying medium will be solved. Also several conclusions from a comparison between the numerical and analytic solutions, a comparison between solutions with various element orders, and a comparison between solutions with different time differencing will be made to be certain about the formulation and FEM solution. By investigating various cases with different values of albedo, theta, and the order of elements, it can be concluded that the finite element solution is agree well with the analytic solution. The higher the element order used, the higher the accuracy improvements are obtained.
International Nuclear Information System (INIS)
Kulich, N.V.; Nemtsev, V.A.
1986-01-01
The analytical solution to the problem on the stationary temperature field in an infinite structural element of rectangular profile characteristic of the conjugation points of a vessel and a tube sheet of a heat exchanger (or of a finned surface) at the third-kind boundary conditions has been obtained by the methods of the complex variable function theory. With the help of the obtained analytical dependences the calculations of the given element of the design and the comparison with the known data have been conducted. The proposed analytical solution can be effectively used in calculations of temperature fields in finned surfaces and structural elements of the power equipment of the considered profile and the method is applied for solution of the like problems
Directory of Open Access Journals (Sweden)
Lyakhovich Leonid
2017-01-01
Full Text Available This paper is devoted to formulation and general principles of approximation of multipoint boundary problem of static analysis of deep beam with the use of combined application of finite element method (FEM discrete-continual finite element method (DCFEM. The field of application of DCFEM comprises structures with regular physical and geometrical parameters in some dimension (“basic” dimension. DCFEM presupposes finite element approximation for non-basic dimension while in the basic dimension problem remains continual. DCFEM is based on analytical solutions of resulting multipoint boundary problems for systems of ordinary differential equations with piecewise-constant coefficients.
International Nuclear Information System (INIS)
Cheng, C.Z.
1988-12-01
A nonvariational ideal MHD stability code (NOVA) has been developed. In a general flux coordinate (/psi/, θ, /zeta/) system with an arbitrary Jacobian, the NOVA code employs Fourier expansions in the generalized poloidal angle θ and generalized toroidal angle /zeta/ directions, and cubic-B spline finite elements in the radial /psi/ direction. Extensive comparisons with these variational ideal MHD codes show that the NOVA code converges faster and gives more accurate results. An extended version of NOVA is developed to integrate non-Hermitian eigenmode equations due to energetic particles. The set of non-Hermitian integro-differential eigenmode equations is numerically solved by the NOVA-K code. We have studied the problems of the stabilization of ideal MHD internal kink modes by hot particle pressure and the excitation of ''fishbone'' internal kink modes by resonating with the energetic particle magnetic drift frequency. Comparisons with analytical solutions show that the values of the critical β/sub h/ from the analytical theory can be an order of magnitude different from those computed by the NOVA-K code. 24 refs., 11 figs., 1 tab
Ting, Eric; Nguyen, Nhan; Trinh, Khanh
2014-01-01
This paper presents a static aeroelastic model and longitudinal trim model for the analysis of a flexible wing transport aircraft. The static aeroelastic model is built using a structural model based on finite-element modeling and coupled to an aerodynamic model that uses vortex-lattice solution. An automatic geometry generation tool is used to close the loop between the structural and aerodynamic models. The aeroelastic model is extended for the development of a three degree-of-freedom longitudinal trim model for an aircraft with flexible wings. The resulting flexible aircraft longitudinal trim model is used to simultaneously compute the static aeroelastic shape for the aircraft model and the longitudinal state inputs to maintain an aircraft trim state. The framework is applied to an aircraft model based on the NASA Generic Transport Model (GTM) with wing structures allowed to flexibly deformed referred to as the Elastically Shaped Aircraft Concept (ESAC). The ESAC wing mass and stiffness properties are based on a baseline "stiff" values representative of current generation transport aircraft.
Energy Technology Data Exchange (ETDEWEB)
Cheng, C.Z.
1988-12-01
A nonvariational ideal MHD stability code (NOVA) has been developed. In a general flux coordinate (/psi/, theta, /zeta/) system with an arbitrary Jacobian, the NOVA code employs Fourier expansions in the generalized poloidal angle theta and generalized toroidal angle /zeta/ directions, and cubic-B spline finite elements in the radial /psi/ direction. Extensive comparisons with these variational ideal MHD codes show that the NOVA code converges faster and gives more accurate results. An extended version of NOVA is developed to integrate non-Hermitian eigenmode equations due to energetic particles. The set of non-Hermitian integro-differential eigenmode equations is numerically solved by the NOVA-K code. We have studied the problems of the stabilization of ideal MHD internal kink modes by hot particle pressure and the excitation of ''fishbone'' internal kink modes by resonating with the energetic particle magnetic drift frequency. Comparisons with analytical solutions show that the values of the critical ..beta../sub h/ from the analytical theory can be an order of magnitude different from those computed by the NOVA-K code. 24 refs., 11 figs., 1 tab.
Wiche, Oliver; Székely, Balazs; Kummer, Nicolai-Alexeji; Moschner, Christin; Heilmeier, Hermann
2016-09-01
This study aims to investigate how intercropping of oat (Avena sativa L.) with white lupin (Lupinus albus L.) affects the mobile fractions of trace metals (Fe, Mn, Pb, Cd, Th, U, Sc, La, Nd, Ge) in soil solution. Oat and white lupin were cultivated in monocultures and mixed cultures with differing oat/white lupin ratios (11% and 33% lupin, respectively). Temporal variation of soil solution chemistry was compared with the mobilization of elements in the rhizosphere of white lupin and concentrations in plant tissues. Relative to the monocrops, intercropping of oat with 11% white lupin significantly increased the concentrations of Fe, Pb, Th, La and Nd in soil solution as well as the concentrations of Fe, Pb, Th, Sc, La and Nd in tissues of oat. Enhanced mobility of the mentioned elements corresponded to a depletion of elements in the rhizosphere soil of white lupin. In mixed cultures with 33% lupin, concentrations in soil solution only slightly increased. We conclude that intercropping with 11% white lupin might be a promising tool for phytoremediation and phytomining research enhancing mobility of essential trace metals as well as elements with relevance for phytoremediation (Pb, Th) and phytomining (La, Nd, Sc) in soil.
Tsiveriotis, K.; Brown, R. A.
1993-01-01
A new method is presented for the solution of free-boundary problems using Lagrangian finite element approximations defined on locally refined grids. The formulation allows for direct transition from coarse to fine grids without introducing non-conforming basis functions. The calculation of elemental stiffness matrices and residual vectors are unaffected by changes in the refinement level, which are accounted for in the loading of elemental data to the global stiffness matrix and residual vector. This technique for local mesh refinement is combined with recently developed mapping methods and Newton's method to form an efficient algorithm for the solution of free-boundary problems, as demonstrated here by sample calculations of cellular interfacial microstructure during directional solidification of a binary alloy.
Corrosion studies of thermally sensitised AGR fuel element brace in pH7 and pH9.2 borate solutions
International Nuclear Information System (INIS)
Tyfield, S.P.; Smith, C.A.
1987-04-01
Brace and cladding of AGR fuel elements sensitised in reactor are susceptible to intergranular and crevice corrosion, which may initiate in the pH7 borate pond storage environment of CEGB/SSEB stations. This report considers the benefit in corrosion control that is provided by raising the pond solution pH to 9.2, whilst maintaining the boron level at 1250 gm -3 . The greater corrosion protection provided by pH9.2 solution compared to the pH7 borate solution is demonstrated by a series of tests with non-active laboratory sensitised brace samples exposed to solutions dosed with chloride or sulphate in order to promote localised corrosion. The corrosion tests undertaken consisted of 5000 hour immersions at 32 0 C and shorter term electrochemically monitored experiments (rest potential, impedance, anodic current) generally conducted at 22 0 C. The pH9.2 solution effectively inhibited the initiation of crevice and intergranular corrosion in the presence of low levels of chloride and sulphate, whereas the pH7 solution did not always do so. However, the pH9.2 solution, dosed with 40 gm -3 chloride, failed to suppress fully crevice corrosion initiated in unborated 40 gm -3 chloride solution at 22 0 C. Fluoride is not deleterious at low levels ∼ 10 gm -3 in the borate solutions. The significant improvement in corrosion control demonstrated for the change from pH7 to pH9.2 borate solution on laboratory sensitised brace samples should ideally be confirmed using complete irradiated AGR fuel elements. (U.K.)
Yang, Z.; Li, Z.; Dollevoet, R.P.B.J.; Tournay, H; Grassie, S
2015-01-01
The precise mechanism which activates squeal, especially flange squeal has not been fully explained. The complex non-Hertzian contact and the broad-band high frequency feature bring great challenges to the modelling work of flange squeal. In this paper, an explicit integration finite element method
International Nuclear Information System (INIS)
Aldape U, F.
1989-01-01
This work presents: 1) The methodology and the experimental conditions of the PIXE technique so that it is used as a better option inside the analytical methods in aerosols studies, 2) The development, tests and applications of a cascade impactor of the Batelle type built to determine particle size to use it jointly with the mentioned technique in the determination of the elements concentration according to its size.By this way is fulfilled with the first goal of this extensive project. (Author)
Directory of Open Access Journals (Sweden)
Aleksandar Ž. Kostić
2014-01-01
Full Text Available Solutions of milk protein concentrate, whey protein concentrate and bovine serum albumin (BSA were treated with polyacrylic hydrogel to establish whether the hydrogel could be used for decontamination of heavy metal ions from milk protein-based products. The obtained results indicated that swelling of hydrogel in these solutions had different effects on their mineral, trace element and total protein content. Total protein and phosphorus content increased in milk protein concentrate and whey protein concentrate solutions after swelling of hydrogel without changes in their protein compositions. On the other hand, the protein content in BSA solution decreased after swelling. The content of Na did not change in milk protein concentrate solution, whereas it significantly increased in whey protein concentrate solution after hydrogel swelling. The content of Ca and Mg was reduced after the swelling in milk protein concentrate and whey protein concentrate solutions for 20.3–63.4 %, depending on the analysed sample and the mineral. The content of Zn did not change during swelling, whereas the content of Fe, Cu, Mn, Ni and Pb significantly decreased after hydrogel swelling in all analysed samples. According to the obtained results, the addition of polyacrylic hydrogel to milk and whey protein concentrate solutions can significantly decrease the content of heavy metal ions without affecting their protein composition. Therefore, this work could be useful in developing a new technological process for heavy metal purification of milk protein-based products.
International Nuclear Information System (INIS)
Williams, M.M.R.; Hall, S.K.; Eaton, M.D.
2014-01-01
Highlights: • A rectangular reactor cell with an elliptical fuel element. • Solution of transport and diffusion equations by Fourier expansion. • Numerical examples showing convergence. • Two group cell problems. - Abstract: A method for solving the diffusion and transport equations in a rectangular lattice cell with an elliptical fuel element has been developed using a Fourier expansion of the neutron flux. The method is applied to a one group model with a source in the moderator. The cell flux is obtained and also the associated disadvantage factor. In addition to the one speed case, we also consider the two group equations in the cell which now become an eigenvalue problem for the lattice multiplication factor. The method of solution relies upon an efficient procedure to solve a large set of simultaneous linear equations and for this we use the IMSL library routines. Our method is compared with the results from a finite element code. The main drawback of the problem arises from the very large number of terms required in the Fourier series which taxes the storage and speed of the computer. Nevertheless, useful solutions are obtained in geometries that would normally require the use of finite element or analogous methods, for this reason the Fourier method is useful for comparison with that type of numerical approach. Extension of the method to more intricate fuel shapes, such as stars and cruciforms as well as superpositions of these, is possible
International Nuclear Information System (INIS)
Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.
1994-08-01
As part of the Hanford Tank Waste Remediation System program at Los Alamos, we evaluated 63 commercially available or experimental absorber materials for their ability to remove hazardous components from high-level waste (HLW). These absorbers included cation and anion exchange resins, inorganic exchangers, composite absorbers, and a series of liquid extractants sorbed on porous support-beads. We tested these absorbers with three solutions prepared to simulate acid-dissolved sludge (pH 0.6), acidified supernate (pH 3.5), and alkaline supernate (pH 13.9) from underground storage tank 102-SY at the Hanford Reservation near Richland, Washington. To these simulants we added the appropriate radionuclides and used gamma spectrometry to measure fission products (Ce, Cs, Sr, Tc, and Y), actinides (U, Pu, and Am), and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr). For each of more than 2500 element/absorber/solution combinations, we measured distribution coefficients for dynamic contact periods of 30 min, 2 h, and 6 h to obtain information about sorption kinetics. Because we measured the sorption of many different elements, the tabulated results indicate those elements most likely to interfere with the sorption of elements of greater interest. On the basis of nearly 7500 measured distribution coefficients, we determined that many of these absorbers appear suitable for processing HLW. This study supersedes the previous version of LA-12654, in which results attributed to a solution identified as an alkaline supernate simulant were misleading because that solution contained insufficient hydroxide
International Nuclear Information System (INIS)
Bryson, J.W.; Johnson, W.G.; Bass, B.R.
1977-01-01
A parameter study was conducted on stresses in reinforced nozzle-to-cylinder attachments under internal pressure loading as analyzed by the finite-element method. Twenty-five models with branch-to-run diameter ratios 0.08 less than or equal to d/D less than or equal to 0.50 and run diameter-to-thickness ratios 10 less than or equal to D/T less than or equal to 100 were investigated. A three-dimensional finite-element program, CORTES-SA, which was developed at the University of California at Berkeley specifically for analyzing tee-joint configurations, was used in the study. It was concluded from the study that both of the reinforcement designs investigated significantly reduce maximum stresses relative to configurations having little or no reinforcement. For internal pressure loading, neither of the reinforcement designs offered a significant advantage over the other in that both types of reinforcement gave very nearly the same maximum stresses
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Park, H.; De Oliveira, C. R. E.
2007-01-01
This paper describes the verification of the recently developed space-angle self-adaptive algorithm for the finite element-spherical harmonics method via the Method of Manufactured Solutions. This method provides a simple, yet robust way for verifying the theoretical properties of the adaptive algorithm and interfaces very well with the underlying second-order, even-parity transport formulation. Simple analytic solutions in both spatial and angular variables are manufactured to assess the theoretical performance of the a posteriori error estimates. The numerical results confirm reliability of the developed space-angle error indicators. (authors)
Energy Technology Data Exchange (ETDEWEB)
Mohamed, M. Shadi, E-mail: m.s.mohamed@durham.ac.uk [School of Engineering and Computing Sciences, University of Durham, South Road, Durham DH1 3LE (United Kingdom); Seaid, Mohammed; Trevelyan, Jon [School of Engineering and Computing Sciences, University of Durham, South Road, Durham DH1 3LE (United Kingdom); Laghrouche, Omar [Institute for Infrastructure and Environment, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom)
2013-10-15
We investigate the effectiveness of the partition-of-unity finite element method for transient conduction–radiation problems in diffusive grey media. The governing equations consist of a semi-linear transient heat equation for the temperature field and a stationary diffusion approximation to the radiation in grey media. The coupled equations are integrated in time using a semi-implicit method in the finite element framework. We show that for the considered problems, a combination of hyperbolic and exponential enrichment functions based on an approximation of the boundary layer leads to improved accuracy compared to the conventional finite element method. It is illustrated that this approach can be more efficient than using h adaptivity to increase the accuracy of the finite element method near the boundary walls. The performance of the proposed partition-of-unity method is analyzed on several test examples for transient conduction–radiation problems in two space dimensions.
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Marin, B [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires
1969-07-01
The aim of this work is to compare the complexation in chloride solutions of trivalent lanthanides and actinides. We have first studied the solvatation of these cations without complexation. We found a difference between Am, Cm and Rare Earths (we can separate lanthanides into Light and Heavy Rare Earths). For studying the complexation we choose the technic of electrophoresis on paper after establishing a simple theory of mobilities in complex solutions. The hydrolysis of these cations was studied and compared in chloride solutions. We have then studied the complexation with the Cl{sup -} ligand in some solutions: HCl, NH{sub 4}Cl, CaCl{sub 2}, CeCl{sub 3}, LiCl. We have established that the complexation is the same in dilute HCl solutions but in concentrated solutions the trivalent actinides are more complexed. This difference is sharper in LiCl solutions. We also proposed the different models of complex in these solutions. (author) [French] Le but de ce travail est de comparer les transuraniens et lanthanides trivalents au point de vue de leur complexation en solution chlorhydrique. Nous avons ete amenes tout d'abord a etudier la solvatation de ces cations non complexes. C'est ainsi que nous pouvons constater une difference entre Am, Cm et les lanthanides. Ces derniers pouvant se separer en lanthanides legers et lanthanides lourds. Pour etudier la complexation nous avons utilise l'electrophorese sur papier apres avoir donne une theorie simple des mobilites en milieu complexant. Apres avoir etudie et compare l'hydrolyse de ces divers cations en solution chlorhydrique, nous avons etudie leur complexation avec l'ion Cl{sup -} dans dans divers milieux: HCl, NH{sub 4}Cl, CaCl{sub 2}, CeCl{sub 3}, LiCl. ous avons note qu'en solution HCl les deux series se comportent de la meme facon pour des concentrations faibles en Cl{sup -} mais que les transuraniens se complexent plus fortement dans les solutions concentrees. Cette difference s'accroit encore dans les milieux
International Nuclear Information System (INIS)
Pröbstle, M.; Neumeier, S.; Feldner, P.; Rettig, R.; Helmer, H.E.; Singer, R.F.; Göken, M.
2016-01-01
Solid solution strengthening of the γ matrix is one key factor for improving the creep strength of single crystal nickel-base superalloys at high temperatures. Therefore a strong partitioning of solid solution hardening elements to the matrix is beneficial for high temperature creep strength. Different Rhenium-free alloys which are derived from CMSX-4 are investigated. The alloys have been characterized regarding microstructure, phase compositions as well as creep strength. It is found that increasing the Titanium (Ti) as well as the Tungsten (W) content causes a stronger partitioning of the solid solution strengtheners, in particular W, to the γ phase. As a result the creep resistance is significantly improved. Based on these ideas, a Rhenium-free alloy with an optimized chemistry regarding the partitioning behavior of W is developed and validated in the present study. It shows comparable creep strength to the Rhenium containing second generation alloy CMSX-4 in the high temperature / low stress creep regime and is less prone to the formation of deleterious topologically close packed (TCP) phases. This more effective usage of solid solution strengtheners can enhance the creep properties of nickel-base superalloys while reducing the content of strategic elements like Rhenium.
International Nuclear Information System (INIS)
Li, Yuebing; Lei, Yuebao; Gao, Zengliang
2014-01-01
Global limit load solutions for thick-walled cylinders with circumferential internal/external surface and through-wall defects under combined positive/negative axial force, positive/negative global bending moment and internal pressure have been developed in Part I of this paper. In this Part II, elastic-perfectly plastic 3-D finite element (FE) analyses are performed for selected cases, covering a wide range of geometries and load combinations, to validate the developed limit load solutions. The results show that these limit load solutions can predict the FE data very well for the cases with shallow or deep and short cracks and are conservative. For the cases with very long and deep cracks, the predictions are reasonably accurate and more conservative. -- Highlights: • Elastic-perfectly plastic 3D finite element limiting analyses of cylinders. • Thin/thick-walled cylinders with circumferential surface defects. • Combined loading for pressure, end-force and global bending moment. • Totally 1458 cases analysed and tabulated normalised results provided. • Results used to validate the developed limit load solutions in Part I of this paper
International Nuclear Information System (INIS)
Collin, Michel
1969-01-01
A preliminary study of actinide migration on ion exchange paper has been carried out on trace amounts with a view to subsequent application in micro-analysis. The first tests have made it possible to define the factors having an effect on the migrational velocities of aqueous and alcohol-water solutions of HCl and HNO 3 . The behaviour, of actinides has then been studied in non-saline acid solutions. The results obtained for each element separately are interesting from the point of view of their mutual separation. This analytical technique has finally been applied successfully to the migration of 300 μg of uranium deposited from a 1 ml volume of solution. (author) [fr
Collins, Jeffery D.; Volakis, John L.; Jin, Jian-Ming
1990-01-01
A new technique is presented for computing the scattering by 2-D structures of arbitrary composition. The proposed solution approach combines the usual finite element method with the boundary-integral equation to formulate a discrete system. This is subsequently solved via the conjugate gradient (CG) algorithm. A particular characteristic of the method is the use of rectangular boundaries to enclose the scatterer. Several of the resulting boundary integrals are therefore convolutions and may be evaluated via the fast Fourier transform (FFT) in the implementation of the CG algorithm. The solution approach offers the principal advantage of having O(N) memory demand and employs a 1-D FFT versus a 2-D FFT as required with a traditional implementation of the CGFFT algorithm. The speed of the proposed solution method is compared with that of the traditional CGFFT algorithm, and results for rectangular bodies are given and shown to be in excellent agreement with the moment method.
Energy Technology Data Exchange (ETDEWEB)
Korgaonkar, V. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1967-10-01
The exchange of thorium and uranium between a strong base anion resin and a mixed water + ethanol solvent containing nitrate ions is studied. It is assumed that in the resin the thorium and uranium are fixed in the form of the complexes Th(NO{sub 3}){sub 6}{sup 2-} and UO{sub 2}(NO{sub 3}){sub 4}{sup 2-} in solution these elements are present in the form of complexes having the general formula: Th(NO{sub 3}){sub 6-n}{sup n-2} and UO{sub 2}(NO{sub 3}){sub 4-n}{sup n-2} It has been possible to deduce a law for the changes in the partition functions of thorium and uranium as a function of the concentrations of the various species in solution and of the complexing ion NO{sub 3}. From this has been deduced the optimum operational conditions for separating a mixture of these two elements. Finally, in these conditions, the influence of a few interfering ions has been studied: Ba, Bi, Ce, La, Mo, Pb, Zr. The method proposed can be used either as a preparation, or for the dosage of thorium by a quantitative separation. (author) [French] On etudie l'echange du thorium et de l'uranium entre une resine anion base forte et un solvant mixte eau + ethanol charge en ions nitrates. On a suppose que, dans la resine, le thorium et l'uranium sont fixes sous forme de complexes Th(NO{sub 3}){sub 6}{sup 2-} et UO{sub 2}(NO{sub 3}){sub 4}{sup 2-} en solution, ces elements sont engages dans des complexes de formule generale: Th(NO{sub 3}){sub 6-n}{sup n-2} and UO{sub 2}(NO{sub 3}){sub 4-n}{sup n-2} On a pu degager une loi de variation des coefficients de partage du thorium et de l'uranium en fonction des concentrations des diverses especes en solution et de l'anion complexant NO{sub 3}{sup -}. On en a deduit les conditions operatoires optimales necessaires pour separer les deux elements a partir de leurs melanges. Enfin, dans ces conditions, on a etudie l'influence de quelques elements genants: Ba, Bi, Ce, La, Mo, Pb, Zr. La methode preconisee peut etre
Directory of Open Access Journals (Sweden)
Giancarlo G. Bordonaro
2018-04-01
Full Text Available The ultimate goal in hot roll pass design is to manufacture a rolled product with the required dimensional accuracy, defect free surface, and mechanical properties. The proper selection of process parameters is crucial to meet increasing requirements for desired quality and geometrical properties of rolled products. Due to the complex behavior of the metal flow at high temperatures and the severe plastic deformations in shape rolling, most efforts that have been made so far only rely upon the practical experience gained by operators. The large number of variables involved and the difficulty in investigating the process characteristics, make the use of finite element (FE tools an effective and attractive opportunity towards a thorough understanding of the rolling process. In this work, Design of Experiment (DOE is proposed as a powerful and viable method for the prediction of rolling process parameters while reducing the computational effort. Nonlinear 3D FE models of the hot rolling process are developed for a large set of complex cross-section shapes and validated against experimental evidences provided by real plant products at each stage of the deformation sequence. Based on the accuracy of the validated FE models, DOE is applied to investigate the flat rolling process under a series of many parameters and scenarios. Effects of main roll forming variables are analyzed on material flow behavior and geometrical features of a rolled product. The selected DOE factors are the workpiece temperature, diameter size, diameter reduction (draught, and rolls angular velocity. The selected DOE responses are workpiece spread, effective stresses, contact stresses, and rolls reaction loads. Eventually, the application of Pareto optimality (a Multi-Criteria Decision Making method allows to detect an optimal combination of design factors which respect desired target requirements for the responses.
International Nuclear Information System (INIS)
Maenhaut, W.; De Reu, L.; Tomza, U.; Versieck, J.
1982-01-01
Particle induced X-ray emission (p.i.x.e.) and neutron activation analysis (n.a.a.) are proposed for determining the trace element content of human serum albumin. Application of these methods to some commercial albumin solutions provided concentration data for up to 19 elements, most of which were present at a level below a few μg ml -1 . The precision of the p.i.x.e. technique, as determined by irradiating up to 20 targets from one sample, was about 3% for those elements where counting statistics were good. A comparison between the p.i.x.e. and n.a.a. results showed close agreement, indicating that p.i.x.e. can yield data which are accurate to within 10%. Neutron activation showed very good sensitivity for the elements producing long-lived nuclides (tsub(1/2) >= 3 days), but had rather high detection limits for the other elements, unless radiochemical separations were used. (Auth.)
Directory of Open Access Journals (Sweden)
Marcin Krzeszowiec
2015-03-01
Full Text Available Computer simulations of physical phenomena are at the moment common both in science and industry. The possibility of finding approximate solutions for complicated systems of differential equations, mathematically describing issues in the fields of mechanics, physics or chemistry, allows for shorten design and research time, often significantly reducing the need for expensive experimental studies or costly production of prototypes. However, the mentioned prevalence of these methods, particularly the Finite Element Method, resulted in analysis outcomes to be often in advance regarded as accurate ones. The purpose of the article is to showcase, on a simple stress analysis problem, how parameters such as the density of the finite element mesh, finite element formulation or integration scheme significantly influence on the simulation results and how easy it is to end up with the results that do not hold any physical sense, despite the fact that all the basic assumptions of correct analysis (suitable boundary conditions, total system energy stored etc. have been met. The results of this study can serve as a warning against premature conclusion drawing from calculations carried out by means of FEM simulation.[b]Keywords[/b]: computational mechanics, finite element method, shell elements, numerical integration
International Nuclear Information System (INIS)
Krot, N.; Shilov, V.; Bessonov, A.; Budantseva, N.; Charushnikova, I.; Perminov, V.; Astafurova, L.
1996-06-01
Highly alkaline radioactive waste solutions originating from production of plutonium for military purposes are stored in underground tanks at the U.S. Department of Energy Hanford Site. The purification of alkaline solutions from neptunium and plutonium is important in the treatment and disposal of these wastes. This report describes scoping tests with sodium hydroxide solutions, where precipitation techniques were investigated to perform the separation. Hydroxides of iron (III), manganese (II), cobalt (II, III), and chromium (III); manganese (IV) oxide, and sodium uranate were investigated as carriers. The report describes the optimum conditions that were identified to precipitate these carriers homogeneously throughout the solution by reductive, hydrolytic, or catalytic decomposition of alkali-soluble precursor compounds by a technique called the Method of Appearing Reagents. The coprecipitation of pentavalent and hexavalent neptunium and plutonium was investigated for the candidate agents under optimum conditions and is described in this report along with the following results. Plutonium coprecipitated well with all tested materials except manganese (IV) oxide. Neptunium only coprecipitated well with uranate. The report presents a hypothesis to explain these behaviors. Further tests with more complex solution matrices must be performed
Energy Technology Data Exchange (ETDEWEB)
Krot, N.; Shilov, V.; Bessonov, A.; Budantseva, N.; Charushnikova, I.; Perminov, V.; Astafurova, L. [Russian Academy of Science (Russian Federation). Inst. of Physical Chemistry
1996-06-06
Highly alkaline radioactive waste solutions originating from production of plutonium for military purposes are stored in underground tanks at the U.S. Department of Energy Hanford Site. The purification of alkaline solutions from neptunium and plutonium is important in the treatment and disposal of these wastes. This report describes scoping tests with sodium hydroxide solutions, where precipitation techniques were investigated to perform the separation. Hydroxides of iron (III), manganese (II), cobalt (II, III), and chromium (III); manganese (IV) oxide, and sodium uranate were investigated as carriers. The report describes the optimum conditions that were identified to precipitate these carriers homogeneously throughout the solution by reductive, hydrolytic, or catalytic decomposition of alkali-soluble precursor compounds by a technique called the Method of Appearing Reagents. The coprecipitation of pentavalent and hexavalent neptunium and plutonium was investigated for the candidate agents under optimum conditions and is described in this report along with the following results. Plutonium coprecipitated well with all tested materials except manganese (IV) oxide. Neptunium only coprecipitated well with uranate. The report presents a hypothesis to explain these behaviors. Further tests with more complex solution matrices must be performed.
Liu, Jingshou; Ding, Wenlong; Yang, Haimeng; Jiu, Kai; Wang, Zhe; Li, Ang
2018-04-01
Natural fractures have long been considered important factors in the production of gas from shale reservoirs because they can connect pore spaces and enlarge transport channels, thereby influencing the migration, accumulation and preservation of shale gas. Industrial-level shale gas production has been initiated in the lower Silurian Longmaxi Formation in northern Guizhou, South China. However, it is important to quantitatively predict the distribution of natural fractures in the lower Silurian shale reservoirs to locate additional 'sweet spots' in northern Guizhou. In this study, data obtained from outcrops, cores, thin sections, field-emission scanning electron microscope (FE-SEM) images and X-ray diffraction (XRD) were used to determine the developmental characteristics and controlling factors of these fractures. Correlation analysis indicated that the mechanical parameters of the Longmaxi shale are mainly related to the total organic carbon (TOC), quartz, clay, calcite and dolomite contents. The spatial variations in the mechanical parameters of the Longmaxi shale were determined based on the spatial variations in the TOC and mineral contents. Then, a heterogeneous geomechanical model of the study area was established based on interpretations of the fault systems derived from seismic data and acoustic emission (AE) experiments performed on samples of the relevant rocks. The paleotectonic stress fields during the Yanshanian period were obtained using the finite element method (FEM). Finally, a fracture density calculation model was established to analyze the quantitative development of fractures, and the effects of faults and mechanical parameters on the development of fractures were determined. The results suggest that the main developmental period of tectonic fractures in the Longmaxi Formation was the Early Yanshanian period. During this time, the horizontal principal stress conditions were dominated by a SE-NW-trending (135-315°) compressional stress field
DEFF Research Database (Denmark)
Larsen, Jon Steffen; Santos, Ilmar
2015-01-01
An efficient finite element scheme for solving the non-linear Reynolds equation for compressible fluid coupled to compliant structures is presented. The method is general and fast and can be used in the analysis of airfoil bearings with simplified or complex foil structure models. To illustrate...
International Nuclear Information System (INIS)
Liu, Ying; Imashuku, Susumu; Kawai, Jun
2014-01-01
A portable total reflection X-ray fluorescence spectrometer (TXRF) was used to analyze leaching solutions of hijiki seaweeds. S, Cl, K, Ca, Ti, Fe, Ni, As and Br were detected in the solutions. Arsenic quantification results were compared to those from ICP-AES. The TXRF quantification results of arsenic were not significantly different from those of ICP-AES, as two-way analysis of variance (ANOVA) method was applied to the significance test. This kind of small and high sensitive TXRF spectrometer can be used in food quality and environmental pollution investigation. (author)
Directory of Open Access Journals (Sweden)
Pavel A. Akimov
2017-12-01
Full Text Available As is well known, the formulation of a multipoint boundary problem involves three main components: a description of the domain occupied by the structure and the corresponding subdomains; description of the conditions inside the domain and inside the corresponding subdomains, the description of the conditions on the boundary of the domain, conditions on the boundaries between subdomains. This paper is a continuation of another work published earlier, in which the formulation and general principles of the approximation of the multipoint boundary problem of a static analysis of deep beam on the basis of the joint application of the finite element method and the discrete-continual finite element method were considered. It should be noted that the approximation within the fragments of a domain that have regular physical-geometric parameters along one of the directions is expedient to be carried out on the basis of the discrete-continual finite element method (DCFEM, and for the approximation of all other fragments it is necessary to use the standard finite element method (FEM. In the present publication, the formulas for the computing of displacements partial derivatives of displacements, strains and stresses within the finite element model (both within the finite element and the corresponding nodal values (with the use of averaging are presented. Boundary conditions between subdomains (respectively, discrete models and discrete-continual models and typical conditions such as “hinged support”, “free edge”, “perfect contact” (twelve basic (basic variants are available are under consideration as well. Governing formulas for computing of elements of the corresponding matrices of coefficients and vectors of the right-hand sides are given for each variant. All formulas are fully adapted for algorithmic implementation.
International Nuclear Information System (INIS)
Gado, J.
1986-02-01
The four group, 2D and 3D hexagonal geometry HTGR benchmark problems and a 2D hexagonal geometry PWR (WWER) benchmark problem have been solved by using the finite element diffusion code DIFGEN. The hexagons (or hexagonal prisms) were subdivided into first order or second order triangles or quadrilaterals (or triangular or quadrilateral prisms). In the 2D HTGR case of the number of the inserted absorber rods was also varied (7, 6, 0 or 37 rods). The calculational results are in a good agreement with the results of other calculations. The larger systematic series of DIFGEN calculations have given a quantitative picture on the convergence properties of various finite element modellings of hexagonal grids in DIFGEN. (orig.)
International Nuclear Information System (INIS)
Szeglowski, Z.; Bruchertseifer, H.; Brudanin, V.B.
1993-01-01
A rapid method for continuous separation of short-lived tungsten isotopes from the lanthanides has been developed. It consists in transforming nuclear reaction products from the target by an aerosol jet to an absorber where the KCl particulates are dissolved in 0.2 M HF and percolating the product solution through three successively linked columns filled with ion exchange resins Dowex 50X8 (cationite), Dowex 1X8 (anionite) and again Dowex 50X8. 3 refs
He, Qiaolin
2011-06-01
In this article we discuss the numerical solution of the Navier-Stokes-Cahn-Hilliard system modeling the motion of the contact line separating two immiscible incompressible viscous fluids near a solid wall. The method we employ combines a finite element space approximation with a time discretization by operator-splitting. To solve the Cahn-Hilliard part of the problem, we use a least-squares/conjugate gradient method. We also show that the scheme has the total energy decaying in time property under certain conditions. Our numerical experiments indicate that the method discussed here is accurate, stable and efficient. © 2011 Elsevier Inc.
Chapela Lara, M.; Schuessler, J. A.; Buss, H. L.; McDowell, W. H.
2017-12-01
During the evolution of the critical zone, the predominant source of nutrients to the vegetation changes from bedrock weathering to atmospheric inputs and biological recycling. In parallel, the architecture of the critical zone changes with time, promoting a change in water flow regime from near-surface porous flow during early weathering stages to more complex flow regimes modulated by clay-rich regolith during the late stages of weathering. As a consequence of these two concurrent processes, we can expect the predominant sources and pathways of solutes to the streams to also change during critical zone evolution. If this is true, we would observe a decoupling between the solutes used by the vegetation and those that determine the composition of the streams during the late stages of weathering, represented by geomorphically stable tropical settings. To test these hypotheses, we are analyzing the elemental and Mg isotopic composition of regolith and streams at the humid tropical Luquillo Critical Zone Observatory. We aim to trace the relative contributions of the surficial, biologically mediated pathways and the deeper, weathering controlled nutrient pathways. We also investigate the role of lithology on the solute decoupling between the vegetation and the stream, by examining two similar headwater catchments draining two different bedrocks (andesitic volcaniclastic and granitic). Our preliminary elemental and Mg isotope results are consistent with atmospheric inputs in the upper 2 m of regolith in both lithologies and with bedrock weathering at depth. During a short storm event ( 6 h), a headwater stream draining volcaniclastic bedrock showed a large variation in Mg and δ26Mg, correlated with total suspended solids, while another similar headwater granitic stream showed a much narrower variation. A larger stream draining volcaniclastic bedrock showed changes in Mg concentration in response to rain during the same storm event, but did not change in δ26Mg
Energy Technology Data Exchange (ETDEWEB)
Li, D.G. [School of Materials Science and Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Tubular Goods Research Center of CNPC, Xi' an 710065 (China)], E-mail: dangguoli78@yahoo.com.cn; Feng, Y.R.; Bai, Z.Q. [Tubular Goods Research Center of CNPC, Xi' an 710065 (China); Zhu, J.W.; Zheng, M.S. [School of Materials Science and Engineering, Xi' an Jiaotong University, Xi' an 710049 (China)
2007-11-01
The influences of temperature, chloride ions and chromium element on the electronic property of passive film formed on carbon steel in NaHCO{sub 3}/Na{sub 2}CO{sub 3} buffer solution are investigated by capacitance measurement and electrochemical impedance spectroscopy (EIS). The results show that the passive film appears n-type semiconductive character; with increasing the solution temperature, the addition of chromium into carbon steel and increasing the concentration of chloride ions, the slopes of Mott-Schottky plots decrease, which indicates the increment of the defect density in the passive film. EIS results show that the transfer impedance R{sub 1} and the diffusion impedance W decrease with increasing the solution temperature, with the addition of chromium into carbon steel and with increasing the chloride ions concentration. It can be concluded that the corrosion protection effect of passive film on the substrate decreases with increasing the solution temperature, adding chromium into carbon steel and increasing chloride ions concentration.
Directory of Open Access Journals (Sweden)
Drozd Wojciech
2016-01-01
Full Text Available The article presents issues related to the solutions with light clay and straw bale in the contemporary housing. Building using straw bale and light clay is simple, eco-friendly and accessible to all. It fits in with the idea of sustainable development, supporting local businesses and giving people the opportunity to integrate in the design and construction of the house. The article presents the thermal analysis for both walls made of straw bale and of light clay. The analysis showed a very good performance. All positive aspects allow treating straw and light clay as a viable alternative to the commonly used technologies for erecting buildings.
International Nuclear Information System (INIS)
Ragusa, Jean C.
2015-01-01
In this paper, we propose a piece-wise linear discontinuous (PWLD) finite element discretization of the diffusion equation for arbitrary polygonal meshes. It is based on the standard diffusion form and uses the symmetric interior penalty technique, which yields a symmetric positive definite linear system matrix. A preconditioned conjugate gradient algorithm is employed to solve the linear system. Piece-wise linear approximations also allow a straightforward implementation of local mesh adaptation by allowing unrefined cells to be interpreted as polygons with an increased number of vertices. Several test cases, taken from the literature on the discretization of the radiation diffusion equation, are presented: random, sinusoidal, Shestakov, and Z meshes are used. The last numerical example demonstrates the application of the PWLD discretization to adaptive mesh refinement
Soloveichik, Yury G.; Persova, Marina G.; Domnikov, Petr A.; Koshkina, Yulia I.; Vagin, Denis V.
2018-03-01
We propose an approach to solving multisource induction logging problems in multidimensional media. According to the type of induction logging tools, the measurements are performed in the frequency range of 10 kHz to 14 MHz, transmitter-receiver offsets vary in the range of 0.5-8 m or more, and the trajectory length is up to 1 km. For calculating the total field, the primary-secondary field approach is used. The secondary field is calculated with the use of the finite-element method (FEM), irregular non-conforming meshes with local refinements and a direct solver. The approach to constructing basis functions with the continuous tangential components (from Hcurl(Ω)) on the non-conforming meshes from the standard shape vector functions is developed. On the basis of this method, the algorithm of generating global matrices and a vector of the finite-element equation system is proposed. We also propose the method of grouping the logging tool positions, which makes it possible to significantly increase the computational effectiveness. This is achieved due to the compromise between the possibility of using the 1-D background medium, which is very similar to the investigated multidimensional medium for a small group, and the decrease in the number of the finite-element matrix factorizations with the increasing number of tool positions in one group. For calculating the primary field, we propose the method based on the use of FEM. This method is highly effective when the 1-D field is required to be calculated at a great number of points. The use of this method significantly increases the effectiveness of the primary-secondary field approach. The proposed approach makes it possible to perform modelling both in the 2.5-D case (i.e. without taking into account a borehole and/or invasion zone effect) and the 3-D case (i.e. for models with a borehole and invasion zone). The accuracy of numerical results obtained with the use of the proposed approach is compared with the one
International Nuclear Information System (INIS)
Park, Jai Hak; Nikishkov, G. P.
2010-01-01
An SGBEM (symmetric Galerkin boundary element method)-FEM alternating method has been proposed by Nikishkov, Park and Atluri. This method can be used to obtain mixed-mode stress intensity factors for planar and nonplanar three-dimensional cracks having an arbitrary shape. For field applications, however, it is necessary to verify the accuracy and consistency of this method. Therefore, in this study, we investigate the effects of several factors on the accuracy of the stress intensity factors obtained using the above mentioned alternating method. The obtained stress intensity factors are compared with the known values provided in handbooks, especially in the case of internal and external circumferential semi-elliptical surface cracks. The results show that the SGBEM-FEM alternating method yields accurate stress intensity factors for three-dimensional cracks, including internal and external circumferential surface cracks and that the method can be used as a robust crack analysis tool for solving field problems
International Nuclear Information System (INIS)
Zenaro, R.
1989-01-01
It was studied the chemical composition of ground water from four boreholes as a contribution to the hydrogeochemical studies in the Pocos de Caldas uranium mining. Methods for water analyses were selected and optimized in order to determine the main anions, specially the ones which form stable complexes with uranium ions. Fluoride and chloride were determined by potentiometry; phosphate, nitrate and silicate by spectrophotometry. Cations were determined by atomic absorption spectrophotometry flame emission and argon plasma emission excited by continuous current arch (DCP). Uranium was determined by fluorimetry with a concentration range from 3 to 7 ppb and its distribution calculated among the different species into solution through the measures of pH, Eh, anion amounts and stability of their respective complexes. (author) [pt
International Nuclear Information System (INIS)
Sercombe, Jérôme; Masson, Renaud; Helfer, Thomas
2013-01-01
Highlights: • This paper presents closed-formed solutions concerning pellet cladding interaction. • First, the opening of a radial crack in a pellet fragment is estimated. • Second, the stresses in the cladding in front of the pellet crack are calculated. • The closed-formed solutions are found in good agreement with 2D FE simulations. • They are then used in the fuel code ALCYONE to model PCI during power ramps. -- Abstract: This paper presents two closed-form solutions that can be used to enrich the mechanical description of fuel pellets and cladding behavior in standard one-dimensional based fuel performance codes. The first one is concerned with the estimation of the opening of a radial crack in a pellet fragment induced by the radial thermal gradient in the pellet and limited by the pellet-clad contact pressure. The second one describes the stress distribution in a cladding bore in front of an opening pellet crack. A linear angular variation of the pellet-clad contact pressure and a constant prescribed radial displacement are considered. The closed-form solutions are checked by comparison to independent finite element models of the pellet fragment and of the cladding. Their ability to describe non-axisymmetric displacement and stress fields during loading histories representative of base irradiation and power ramps is then demonstrated by cross-comparison with the 2D pellet fragment-cladding model of the multi-dimensional fuel performance code ALCYONE. The calculated radial crack opening profiles at different times and the hoop stress concentration in the cladding at the top of the ramp are found in good agreement with ALCYONE
International Nuclear Information System (INIS)
Tsuji, Masashi; Chiba, Gou
2000-01-01
A hierarchical domain decomposition boundary element method (HDD-BEM) for solving the multiregion neutron diffusion equation (NDE) has been fully parallelized, both for numerical computations and for data communications, to accomplish a high parallel efficiency on distributed memory message passing parallel computers. Data exchanges between node processors that are repeated during iteration processes of HDD-BEM are implemented, without any intervention of the host processor that was used to supervise parallel processing in the conventional parallelized HDD-BEM (P-HDD-BEM). Thus, the parallel processing can be executed with only cooperative operations of node processors. The communication overhead was even the dominant time consuming part in the conventional P-HDD-BEM, and the parallelization efficiency decreased steeply with the increase of the number of processors. With the parallel data communication, the efficiency is affected only by the number of boundary elements assigned to decomposed subregions, and the communication overhead can be drastically reduced. This feature can be particularly advantageous in the analysis of three-dimensional problems where a large number of processors are required. The proposed P-HDD-BEM offers a promising solution to the deterioration problem of parallel efficiency and opens a new path to parallel computations of NDEs on distributed memory message passing parallel computers. (author)
Luo, Zhe; Zhu, Hong; Ying, Tao; Li, Dejiang; Zeng, Xiaoqin
2018-06-01
The influences of solute atoms (Li, Al, Mn, Zn, Fe, Ni, Cu, Y, Zr) and Cl adsorption on the anodic corrosion performance on Mg (0001) surface have been investigated based on first-principles calculations, which might be useful for the design of corrosion-resistant Mg alloys. Work function and local electrode potential shift are chosen as descriptors since they quantify the barrier for charge transfer and anodic stability. We found that at 25% surface doping rate, Y decreased the work function of Mg, while the impact of remaining doping elements on the work function of Mg was trivial due to the small surface dipole moment change. The adsorption of Cl destabilized the Mg atoms at surface by weakening the bonding between surface Mg atoms. We find that a stronger hybridization of d orbits of alloying elements (e.g. Zr) with the orbits of Mg can greatly increase the local electrode potential,which even overbalances the negative effect introduced by Cl adsorbates and hence improves the corrosion resistance of Mg alloys.
Reepolmaha, Somporn; Limtrakarn, Wiroj; Uthaisang-Tanechpongtamb, Wanlaya; Dechaumphai, Pramote
2010-01-01
The purpose of this study was to estimate and compare the temperatures of two different anterior chamber solutions at the corneal endothelial level during phacoemulsification. An ophthalmic viscosurgical device (OVD) and balanced salt solution (BSS) were compared using the finite element method (FEM). The thermal properties of an OVD (IAL-F) and BSS were studied in an experimental setting. A computer-aided design model of ocular anatomy was created in two dimensions. The phaco needle was considered to be the only source of heat generation. Then, the FEM was used to demonstrate the transient temperature distribution in the two ocular models at 10, 20, 30, 40, 50 and 60 s. In these models, the anterior chamber was filled with IAL-F (IAL-F model) or BSS (BSS model). The heat generation rate of the phaco needle was 0.0004 cal/s/mm(2). The maximum corneal endothelial temperatures for the two models at 60 s were 52.67 and 41.57 degrees C, respectively. The experimental IAL-F model showed fewer changes in temperature for any given time and location. At larger distances from the heat source, less temperature variation was detected. Phacoemulsification is a potential heat-generating procedure performed between the delicate anterior chamber structures. During this procedure, IAL-F protects the endothelium against heat better than BSS. Copyright 2009 S. Karger AG, Basel.
Energy Technology Data Exchange (ETDEWEB)
Voss, Ina
2015-07-16
The research platform ENTRIA (Disposal options for radioactive residues Interdisciplinary analyses and development of evaluation principles) includes the sub-project ''Final disposal in deep geological formations without any arrangements for retrieval''. This approach considers rock salt (beside clay and granite) as host rock formation for disposal of heat-producing long-live waste. Most rock salt formations contain Mg-rich brines derived from highly evolved sea water evaporation processes now included in the rock salt mass. If such brines get access to metal-canister corrosion will allow release of soluble nuclides to the brine. In this scenario, it cannot be excluded that contaminated brines leave the deep seated disposal area and move along geological or technical migration pathways towards the rock salt/cap rock contact. The temperature of the brine will drop from near 80 C to 25 or 30 C. The deceasing temperature of the brine causes precipitation of magnesian chloride and sulfate phase in equilibrium with the brine. In order to understand the salt precipitation and the retention mechanism of dissolved trace elements experiments have been set up which allow formation of sylvite, carnallite, kainite, and hydrous Mg-sulphates under controlled conditions. The retention capacity of crystallizing salt minerals based occurring in magnesian brine solutions at decreasing temperature within a salt dome is best measured as the distribution coefficient D. This concept assumes incorporation of trace elements into the lattice of salt minerals. The distribution coefficients of the trace elements, Rb, Cs, Co, Ni, Zn, Li and B between sylvite, carnallite, kainite, and MgSO{sub 4} phases have been determined at experimental temperatures of 25, 35, 55 and 83 C. The results clearly indicate the following range of distribution coefficients (D): Sylvite D > 1 Rb and Br, D < 1 Co, Ni, Zn, Li and B, Carnallite D > 1 Rb and Cs, D < 1 Co, Ni, Zn, Li and B, Kainite D
Energy Technology Data Exchange (ETDEWEB)
Masiello, E
2006-07-01
The principal goal of this manuscript is devoted to the investigation of a new type of heterogeneous mesh adapted to the shape of the fuel pins (fuel-clad-moderator). The new heterogeneous mesh guarantees the spatial modelling of the pin-cell with a minimum of regions. Two methods are investigated for the spatial discretization of the transport equation: the discontinuous finite element method and the method of characteristics for structured cells. These methods together with the new representation of the pin-cell result in an appreciable reduction of calculation points. They allow an exact modelling of the fuel pin-cell without spatial homogenization. A new synthetic acceleration technique based on an angular multigrid is also presented for the speed up of the inner iterations. These methods are good candidates for transport calculations for a nuclear reactor core. A second objective of this work is the application of method of characteristics for non-structured geometries to the study of double heterogeneity problem. The letters is characterized by fuel material with a stochastic dispersion of heterogeneous grains, and until now was solved with a model based on collision probabilities. We propose a new statistical model based on renewal-Markovian theory, which makes possible to take into account the stochastic nature of the problem and to avoid the approximations of the collision probability model. The numerical solution of this model is guaranteed by the method of characteristics. (author)
Energy Technology Data Exchange (ETDEWEB)
Masiello, E
2006-07-01
The principal goal of this manuscript is devoted to the investigation of a new type of heterogeneous mesh adapted to the shape of the fuel pins (fuel-clad-moderator). The new heterogeneous mesh guarantees the spatial modelling of the pin-cell with a minimum of regions. Two methods are investigated for the spatial discretization of the transport equation: the discontinuous finite element method and the method of characteristics for structured cells. These methods together with the new representation of the pin-cell result in an appreciable reduction of calculation points. They allow an exact modelling of the fuel pin-cell without spatial homogenization. A new synthetic acceleration technique based on an angular multigrid is also presented for the speed up of the inner iterations. These methods are good candidates for transport calculations for a nuclear reactor core. A second objective of this work is the application of method of characteristics for non-structured geometries to the study of double heterogeneity problem. The letters is characterized by fuel material with a stochastic dispersion of heterogeneous grains, and until now was solved with a model based on collision probabilities. We propose a new statistical model based on renewal-Markovian theory, which makes possible to take into account the stochastic nature of the problem and to avoid the approximations of the collision probability model. The numerical solution of this model is guaranteed by the method of characteristics. (author)
Directory of Open Access Journals (Sweden)
Yunhuang Yang
2012-06-01
Full Text Available CV_2116 is a small hypothetical protein of 82 amino acids from the Gram-negative coccobacillus Chromobacterium violaceum. A PSI-BLAST search using the CV_2116 sequence as a query identified only one hit (E = 2e^{−07} corresponding to a hypothetical protein OR16_04617 from Cupriavidus basilensis OR16, which failed to provide insight into the function of CV_2116. The CV_2116 gene was cloned into the p15TvLic expression plasmid, transformed into E. coli, and ^{13}C- and ^{15}N-labeled NMR samples of CV_2116 were overexpressed in E. coli and purified for structure determination using NMR spectroscopy. The resulting high-quality solution NMR structure of CV_2116 revealed a novel α + β fold containing two anti-parallel β -sheets in the N-terminal two-thirds of the protein and one α-helix in the C-terminal third of the protein. CV_2116 does not belong to any known protein sequence family and a Dali search indicated that no similar structures exist in the protein data bank. Although no function of CV_2116 could be derived from either sequence or structural similarity searches, the neighboring genes of CV_2116 encode various proteins annotated as similar to bacteriophage tail assembly proteins. Interestingly, C. violaceum exhibits an extensive network of bacteriophage tail-like structures that likely result from lateral gene transfer by incorporation of viral DNA into its genome (prophages due to bacteriophage infection. Indeed, C. violaceum has been shown to contain four prophage elements and CV_2116 resides in the fourth of these elements. Analysis of the putative operon in which CV_2116 resides indicates that CV_2116 might be a component of the bacteriophage tail-like assembly that occurs in C. violaceum.
Dutton, Andrew William
1993-12-01
A combined numerical and experimental system for tissue heat transfer analysis was developed. The goal was to develop an integrated set of tools for studying the problem of providing accurate temperature estimation for use in hyperthermia treatment planning in a clinical environment. The completed system combines (1) Magnetic Resonance Angiography (MRA) to non-destructively measure the velocity field in situ, (2) the Streamwise Upwind Petrov-Galerkin finite element solution to the 3D steady state convective energy equation (CEE), (3) a medical image based automatic 3D mesh generator, and (4) a Gaussian type estimator to determine unknown thermal model parameters such as thermal conductivity, blood perfusion, and blood velocities from measured temperature data. The system was capable of using any combination of three thermal models (1) the Convective Energy Equation (CEE), (2) the Bioheat Transfer Equation (BHTE), and (3) the Effective Thermal Conductivity Equation (ETCE) Incorporation of the theoretically correct CEE was a significant theoretical advance over approximate models made possible by the use of MRA to directly measure the 3D velocity field in situ. Experiments were carried out in a perfused alcohol fixed canine liver with hyperthermia induced through scanned focused ultrasound Velocity fields were measured using Phase Contrast Angiography. The complete system was then used to (1) develop a 3D finite element model based upon user traced outlines over a series of MR images of the liver and (2) simulate temperatures at steady state using the CEE, BHTE, and ETCE thermal models in conjunction with the gauss estimator. Results of using the system on an in vitro liver preparation indicate the need for improved accuracy in the MRA scans and accurate spatial registration between the thermocouple junctions, the measured velocity field, and the scanned ultrasound power No individual thermal model was able to meet the desired accuracy of 0.5 deg C, the resolution
Li, Yinong; Tian, Chen; Liu, Weizhen; Xu, Si; Xu, Yunyun; Cui, Rongxin; Lin, Zhang
2018-01-01
Nano-Mg(OH) 2 is attracting great attention as adsorbent for pre-concentration and recovery of rare earth elements (REEs) from low-concentration solution, due to its superior removal efficiency for REEs and environmental friendliness. However, the nanoparticles also cause some severe problems during application, including aggregation, blockage in fixed-bed column, as well as the difficulties in separation and reuse. Herein, in order to avoid the mentioned problems, a carbon cloth (CC) supported nano-Mg(OH) 2 (nano-Mg(OH) 2 @CC) was synthesized by electrodeposition. The X-ray diffraction and scanning electron microscopy analysis demonstrated that the interlaced nano-sheet of Mg(OH) 2 grew firmly and uniformly on the surface of carbon cloth fibers. Batch adsorption experiments of Eu(III) indicated that the nano-Mg(OH) 2 @CC composite maintained the excellent adsorption performance of nano-Mg(OH) 2 toward Eu(III). After adsorption, the Eu containing composite was calcined under nitrogen atmosphere. The content of Eu 2 O 3 in the calcined material was as high as 99.66%. Fixed-bed column experiments indicated that no blockage for Mg(OH) 2 @CC composite was observed during the treatment, while the complete blockage of occurred to nano-Mg(OH) 2 at an effluent volume of 240 mL. Moreover, the removal efficiency of Mg(OH) 2 @CC was still higher than 90% until 4,200 mL of effluent volume. This work provides a promising method for feasible application of nanoadsorbents in fixed-bed process to recycle low-concentration REEs from wastewater.
Directory of Open Access Journals (Sweden)
F. O. Isiogugu
2016-01-01
Full Text Available The strong convergence of a hybrid algorithm to a common element of the fixed point sets of multivalued strictly pseudocontractive-type mappings and the set of solutions of an equilibrium problem in Hilbert spaces is obtained using a strict fixed point set condition. The obtained results improve, complement, and extend the results on multivalued and single-valued mappings in the contemporary literature.
International Nuclear Information System (INIS)
Bauer, Mathieu; Broekaert, Jose A.C.
2007-01-01
The use of a so-called trihedral and a T-shaped cross-flow pneumatic nebulizer with dual solution loading for inductively coupled plasma optical emission spectrometry has been studied. By these devices analyte clouds from two solutions can be mixed during the aerosol generation step. For both nebulizers the correction of matrix effects using internal standardization and standard addition calibration in an on-line way was investigated and compared to elemental determinations using a conventional cross-flow nebulizer and calibration with synthetic standard solutions without matrix matching. A significant improvement of accuracy, both for calibration with internal standardization and standard addition, was obtained in the case of four synthetic solutions containing each 40 mmol L -1 Na, K, Rb and Ba as matrix elements and 300 μg L -1 Cd, Co, Cr, Cu, Fe, Mn, Ni and Pb as analytes. Calibration by standard addition in the case of dual solution loading has been shown to be very useful in the determination of elements at minor and trace levels in steel and alumina reference materials. The results of analysis for minor concentrations of Cr, Cu and Ni in steel as well as for Ca, Fe, Ga, Li, Mg, Mn, Na, Si and Zn in alumina powder certified reference materials subsequent to sample dissolution were found to be in good agreement with the certificates. Limits of detection were found to be only slightly above those for a conventional cross-flow nebulizer and a precision better than 3% was realized with both novel nebulizers
A simple modification to the Elemental Analyzer coupled to Isotope Ratio Mass-Spectrometer (EA-IRMS) setup is described. This modification allows the users to measure nitrous oxide (N2O) and carbon dioxide (CO2) by injecting the gases directly into an online injector placed befor...
Energy Technology Data Exchange (ETDEWEB)
Spitsyn, V. I.; Balukova, V. D.; Gromov, V. V.; Zakharov, S. I.; Zhagin, B. P.; Spiridonov, F. M.
1960-07-01
Research on the sorption of radioisotopes under natural conditions employing the controlled filtration process was performed. Radioisotopes were introduced into the solution as soon as filtration had become steady and the process continued for four months. Soil samples were then taken by drilling at different depths and analysed to determine their radioisotope content. Diffusion of radioisotopes was observed at depths of up to 10 m; two distinct boundaries of soil-activity decrease were ascertained: at the surface of the site and at the depth of the solution filtration front. In addition, the radiostrontium absorption by natural sorbents, principally pure minerals widely distributed in soils and subsoils, was investigated separately. The presence of calcium ions, even in small quantities, sharply reduces the degree of radiostrontium sorption. However, other conditions being equal, strontium may be absorbed to a greater extent than calcium, according to the composition of the sorbent. The field investigations of radiostrontium sorption and migration showed that when filtering radioactive solutions two possible variants have to be taken into account. In the first case the solutions are discharged into soil unaffected by any flow of ground water. In this situation the radiostrontium is retained by the soil. In the second case, the radioisotopes proceed directly into the water-bearing horizon. The radiostrontium will then migrate with the ground water flow and through the soil and this migration will be further affected by the sorption and desorption processes occurring. The experiments performed demonstrate the ease with which long-lived radioisotopes migrate under natural conditions and call attention to the need for thorough study of ground water problems in connexion with various methods of disposing of radioactive waste into ground. (author) [French] En declenchant un processus de filtration, il a ete possible d'etudier l'absorption des elements radioactifs dans
International Nuclear Information System (INIS)
Amor, H.; Bourgeois, M.
2012-01-01
Document available in extended abstract form only. The disposal of high level, long lived waste in deep underground clay formations is investigated by several countries including France. In the safety assessment of such geological repositories, a thoughtful consideration must be given to the mechanisms and possible pathways of migration of radionuclides released from waste packages. However, when modelling the transfer of radionuclides throughout the disposal facilities and geological formations, the numerical simulations must take into consideration, in addition to long durations of concern, the variety in the properties as well as in geometrical scales of the different components of the overall disposal, including the host formation. This task presents significant computational challenges. Numerical methods used in the MELODIE software The MELODIE software is developed by IRSN, and constantly upgraded, with the aim to assess the long-term containment capabilities of underground and surface radioactive waste repositories. The MELODIE software models water flow and the phenomena involved in the transport of radionuclides in saturated and unsaturated porous media in 2 and 3 dimensions; chemical processes are represented by a retardation factor and a solubility limit, for sorption and solubility respectively, integrated in the computational equations. These equations are discretized using a so-called Finite Volume Finite Element method (FVFE), which is based on a Galerkin method to discretize time and variables, together with a Finite Volume method using the Godunov scheme for the convection term. The FVFE method is used to convert partial differential equations into a finite number of algebraic equations that match the number of nodes in the mesh used to model the considered domain. It is also used to stabilise the numerical scheme. In order to manage the variety in properties and geometrical scales of underground disposal components, an a posteriori error estimator
International Nuclear Information System (INIS)
Marsh, S.F.; Svitra, Z.V.; Bowen, S.M.
1995-01-01
As part of the Tank Waste Remediation System program at Los Alamos, we evaluated a series of cation exchange and anion exchange resins for their ability to remove hazardous components from radioactive high-level waste (HLW). The anion exchangers were Reillex TM HPQ, a polyvinyl pyridine resin, and four strong-base polystyrene resins having trimethyl, tri ethyl, tri propyl, and tributyl amine as their respective functional groups. The cation exchange resins included Amberlyst TM 15 and Amberlyst tM XN-1010 with sulfonic acid functionality, Duolite TM C-467 with phosphonic acid functionality, and poly functional Diphonix TM with di phosphonic acid, sulfonic acid, and carboxylic acid functionalities. We measured the distributions of 14 elements on these resins from solutions simulating acid-dissolved sludge (pH 0.6) and acidified supernate (pH 3.5) from underground storage tank 102-SY at the Hanford Reservation near Richland, Washington, USA. To these simulants, we added the appropriate radionuclides and used gamma spectrometry to measure fission products (Ce, Cs, Sr, Tc, and Y), actinides (U, Pu, and Am), and matrix elements (Cr, Co, Fe, Mn, Zn, and Zr). For each of the 252 element/resin/solution combinations, distribution coefficients (Kds) were measured for dynamic contact periods of 30 minutes, 2 hours, and 6 hours to obtain information about sorption kinetics from these complex media. Because we measured the sorption of many different elements, the tabulated results indicate which unwanted elements are most likely to interfere with the sorption of elements of special interest. On the basis of these 756 measured Kd values, we conclude that some of the tested resins appear suitable for partitioning hazardous components from Hanford HLW. (author). 10 refs., 11 tabs
Bao, Kai
2012-10-01
In this paper, a semi-implicit finite element method is presented for the coupled Cahn-Hilliard and Navier-Stokes equations with the generalized Navier boundary condition for the moving contact line problems. In our method, the system is solved in a decoupled way. For the Cahn-Hilliard equations, a convex splitting scheme is used along with a P1-P1 finite element discretization. The scheme is unconditionally stable. A linearized semi-implicit P2-P0 mixed finite element method is employed to solve the Navier-Stokes equations. With our method, the generalized Navier boundary condition is extended to handle the moving contact line problems with complex boundary in a very natural way. The efficiency and capacity of the present method are well demonstrated with several numerical examples. © 2012 Elsevier Inc..
Bao, Kai; Shi, Yi; Sun, Shuyu; Wang, Xiaoping
2012-01-01
In this paper, a semi-implicit finite element method is presented for the coupled Cahn-Hilliard and Navier-Stokes equations with the generalized Navier boundary condition for the moving contact line problems. In our method, the system is solved in a decoupled way. For the Cahn-Hilliard equations, a convex splitting scheme is used along with a P1-P1 finite element discretization. The scheme is unconditionally stable. A linearized semi-implicit P2-P0 mixed finite element method is employed to solve the Navier-Stokes equations. With our method, the generalized Navier boundary condition is extended to handle the moving contact line problems with complex boundary in a very natural way. The efficiency and capacity of the present method are well demonstrated with several numerical examples. © 2012 Elsevier Inc..
Strack, O. D. L.
2018-02-01
We present equations for new limitless analytic line elements. These elements possess a virtually unlimited number of degrees of freedom. We apply these new limitless analytic elements to head-specified boundaries and to problems with inhomogeneities in hydraulic conductivity. Applications of these new analytic elements to practical problems involving head-specified boundaries require the solution of a very large number of equations. To make the new elements useful in practice, an efficient iterative scheme is required. We present an improved version of the scheme presented by Bandilla et al. (2007), based on the application of Cauchy integrals. The limitless analytic elements are useful when modeling strings of elements, rivers for example, where local conditions are difficult to model, e.g., when a well is close to a river. The solution of such problems is facilitated by increasing the order of the elements to obtain a good solution. This makes it unnecessary to resort to dividing the element in question into many smaller elements to obtain a satisfactory solution.
El-Deftar, Moteaa M; Robertson, James; Foster, Simon; Lennard, Chris
2015-06-01
Laser-induced breakdown spectroscopy (LIBS) is an emerging atomic emission based solid sampling technique that has many potential forensic applications. In this study, the analytical performance of LIBS, as well as that of inductively coupled plasma mass spectrometry (ICP-MS), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and X-ray microfluorescence (μXRF), was evaluated for the ability to conduct elemental analyses on Cannabis plant material, with a specific investigation of the possible links between hydroponic nutrients and elemental profiles from associated plant material. No such study has been previously published in the literature. Good correlation among the four techniques was observed when the concentrations or peak areas of the elements of interest were monitored. For Cannabis samples collected at the same growth time, the elemental profiles could be related to the use of particular commercial nutrients. In addition, the study demonstrated that ICP-MS, LA-ICP-MS and LIBS are suitable techniques for the comparison of Cannabis samples from different sources, with high discriminating powers being achieved. On the other hand, μXRF method was not suitable for the discrimination of Cannabis samples originating from different growth nutrients. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.
He, Qiaolin; Glowinski, Roland; Wang, Xiao Ping
2011-01-01
element space approximation with a time discretization by operator-splitting. To solve the Cahn-Hilliard part of the problem, we use a least-squares/conjugate gradient method. We also show that the scheme has the total energy decaying in time property
International Nuclear Information System (INIS)
Fernandes, A.; Maiorino, J.R.
1989-01-01
This work presents a method to solve the neutron transport equation in thre space dimensions. The angular flux is aproximated by spherical harmonics and the finite element method is applied to the space component. The program originated by the analytical development is being tested and some results are presented. (author) [pt
Energy Technology Data Exchange (ETDEWEB)
Winsel, A; Von Doehren, H H
1972-01-27
A method for regenerating a fuel cell with Ag-catalyzed O electrodes containing Ni and H electrodes containing Raney Ni where the voltage had dropped from 750 to 630 mV within 3200 hr at 50 mA/cm/sup 2/ is described. An aqueous NH/sub 3/-NH/sub 4/Cl solution was passed through the cell under 1 atm H at 60/sup 0/, whereby 27 g Ni was dissolved as the hydroxide. The voltage of the regenerated cell was 770 mV and remained constant during 500 hr operation. The Ni ions in the regenerating solutions were removed by electrolysis.
International Nuclear Information System (INIS)
Kraus, H.G.; Jones, J.L.
1986-01-01
The problem of non-linear superconducting magnet and electrical protection circuit system transients is formulated. To enable studying the effects of coil normalization transients, coil distortion (due to imbalanced magnetic forces), internal coil arcs and shorts, and other normal and off-normal circuit element responses, the following capabilities are included: temporal, voltage and current-dependent voltage sources, current sources, resistors, capacitors and inductors. The concept of self-mutual inductance, and the form of the associated inductance matrix, is discussed for internally shorted coils. This is a Kirchhoff's voltage loop law and Kirchhoff's current node law formulation. The non-linear integrodifferential equation set is solved via a unique hybrid finite difference/integral finite element technique. (author)
International Nuclear Information System (INIS)
Wanty, R.B.; Langmuir, D.; Chatham, J.R.
1981-08-01
This report presents the results of further research on the groundwater geochemistry of 96 well waters in two uraniferous aquifers in Texas and Wyoming, and is a continuation of the work presented by Chatham et al. (1981). In this study variations in concentrations of U, As, Mo, Se and V were compared with the saturation state of the groundwater with respect to mineral phases of these elements known or expected to occur in each area. The non-radiogenic trace elements exhibited strong redox dependence consistent with thermodynamic predictions, but their variations did not pinpoint existing uranium ore bodies, because of a shift in groundwater flow patterns since the time of ore emplacement. Saturation levels of trace element minerals such as realgar, native Se, and molybdenite showed broad anomalies around the ore-bearing areas, similar to patterns found for U minerals by Langmuir and Chatham (1980), and Chatham et al. (1981). The radiogenic elements Ra and Rn showed significant anomalies directly within the ore zones. Helium anomalies were displaced in the direction of groundwater flow, but by their magnitude and areal extent provided strong evidence for the existence of nearby uranium accumulations. Uranium isotope ratios showed no systematic variations within the two aquifers studied. Saturation maps for kaolinite, illite, montmorillonite and the zeolites analcime and clinoptilolite provided 1 to 2 km anomalies around the ore at the Texas site. Saturation values for the gangue minerals pyrite and calcite defined the redox interface and often suggested the position of probable uranium mineralization. When properly used, the groundwater geochemical concepts for exploration can accurately pinpoint uranium mineralization at a fraction of the cost of conventional methods that involve test drilling and geophysical and core logging
Energy Technology Data Exchange (ETDEWEB)
Wanty, R.B.; Langmuir, D.; Chatham, J.R.
1981-08-01
This report presents the results of further research on the groundwater geochemistry of 96 well waters in two uraniferous aquifers in Texas and Wyoming, and is a continuation of the work presented by Chatham et al. (1981). In this study variations in concentrations of U, As, Mo, Se and V were compared with the saturation state of the groundwater with respect to mineral phases of these elements known or expected to occur in each area. The non-radiogenic trace elements exhibited strong redox dependence consistent with thermodynamic predictions, but their variations did not pinpoint existing uranium ore bodies, because of a shift in groundwater flow patterns since the time of ore emplacement. Saturation levels of trace element minerals such as realgar, native Se, and molybdenite showed broad anomalies around the ore-bearing areas, similar to patterns found for U minerals by Langmuir and Chatham (1980), and Chatham et al. (1981). The radiogenic elements Ra and Rn showed significant anomalies directly within the ore zones. Helium anomalies were displaced in the direction of groundwater flow, but by their magnitude and areal extent provided strong evidence for the existence of nearby uranium accumulations. Uranium isotope ratios showed no systematic variations within the two aquifers studied. Saturation maps for kaolinite, illite, montmorillonite and the zeolites analcime and clinoptilolite provided 1 to 2 km anomalies around the ore at the Texas site. Saturation values for the gangue minerals pyrite and calcite defined the redox interface and often suggested the position of probable uranium mineralization. When properly used, the groundwater geochemical concepts for exploration can accurately pinpoint uranium mineralization at a fraction of the cost of conventional methods that involve test drilling and geophysical and core logging.
Altman, Michael D.; Bardhan, Jaydeep P.; White, Jacob K.; Tidor, Bruce
2009-01-01
We present a boundary-element method (BEM) implementation for accurately solving problems in biomolecular electrostatics using the linearized Poisson–Boltzmann equation. Motivating this implementation is the desire to create a solver capable of precisely describing the geometries and topologies prevalent in continuum models of biological molecules. This implementation is enabled by the synthesis of four technologies developed or implemented specifically for this work. First, molecular and accessible surfaces used to describe dielectric and ion-exclusion boundaries were discretized with curved boundary elements that faithfully reproduce molecular geometries. Second, we avoided explicitly forming the dense BEM matrices and instead solved the linear systems with a preconditioned iterative method (GMRES), using a matrix compression algorithm (FFTSVD) to accelerate matrix-vector multiplication. Third, robust numerical integration methods were employed to accurately evaluate singular and near-singular integrals over the curved boundary elements. Finally, we present a general boundary-integral approach capable of modeling an arbitrary number of embedded homogeneous dielectric regions with differing dielectric constants, possible salt treatment, and point charges. A comparison of the presented BEM implementation and standard finite-difference techniques demonstrates that for certain classes of electrostatic calculations, such as determining absolute electrostatic solvation and rigid-binding free energies, the improved convergence properties of the BEM approach can have a significant impact on computed energetics. We also demonstrate that the improved accuracy offered by the curved-element BEM is important when more sophisticated techniques, such as non-rigid-binding models, are used to compute the relative electrostatic effects of molecular modifications. In addition, we show that electrostatic calculations requiring multiple solves using the same molecular geometry
Energy Technology Data Exchange (ETDEWEB)
Choi, Jeong Ho [Samjung E and W, Changwon (Korea, Republic of); Lee, Jung Hwan [Korea Institute of Materials Science,Changwon (Korea, Republic of); Lee, Je Hyun [Changwon National University, Changwon (Korea, Republic of)
2014-05-15
The objective of this study is to find the density, stiffness, and strength of truss-wall unit cell models. The diamond-corrugation, triangular-corrugation, and Navtruss-corrugation models are used for the unit cell. The ideal solutions derived for these are based on solid wall unit cell models and are developed using the Gibson-Ashby theory. To verify the ideal solutions of the models, the density, strength, and stiffness are simulated using ABAQUS software and compared with the ideal solutions on a log-log scale. The material properties of stainless steel 304 are applied. The diameter is 0.5 mm; the opening width is 0.5 mm; and the corrugation angle is 45 .deg. . Consequently, the relative Young's modulus and relative yield strength of the truss-wall unit models are good matches for the ideal expectations. It may be possible to apply a truss-wall model to diverse fields such as transportation or biomedical applications as one of the open-cell cellular solids.
International Nuclear Information System (INIS)
Choi, Jeong Ho; Lee, Jung Hwan; Lee, Je Hyun
2014-01-01
The objective of this study is to find the density, stiffness, and strength of truss-wall unit cell models. The diamond-corrugation, triangular-corrugation, and Navtruss-corrugation models are used for the unit cell. The ideal solutions derived for these are based on solid wall unit cell models and are developed using the Gibson-Ashby theory. To verify the ideal solutions of the models, the density, strength, and stiffness are simulated using ABAQUS software and compared with the ideal solutions on a log-log scale. The material properties of stainless steel 304 are applied. The diameter is 0.5 mm; the opening width is 0.5 mm; and the corrugation angle is 45 .deg. . Consequently, the relative Young's modulus and relative yield strength of the truss-wall unit models are good matches for the ideal expectations. It may be possible to apply a truss-wall model to diverse fields such as transportation or biomedical applications as one of the open-cell cellular solids.
International Nuclear Information System (INIS)
Le Marois, Gilles.
1980-06-01
Slight differences between the complexation in aqueous solution of 4f and 5f series ions are revealed by the use of a soft, aromatic and chelating ligand of the o-phenanthroline type. Trivalent actinide ions are extrated selectively in the presence of a carboxylic acid. This extraction takes place at high pH and does not require large quantities of salts in aqueous solution, which increase the volume of radioactive wastes for storage. Only the first two o-phenanthroline complexes of these ions are obtained in aqueous solution. Determination of the constants of formation of such complexes shows the stronger affinity of the ligand for actinide ions. An inversion of the usual order of complexation of the different actinide valencies is also observed: pentavalent ions are most complexed than trivalent, o-phenanthroline stabilises actinide ions preferentially because they are more liable to form bonds with delocalised electrons. Finally a slight stabilisation of europium at valency II shows the participation of electrons by back bonding of the metal, due to the strong conjugation of the ligand π electrons [fr
Czech Academy of Sciences Publication Activity Database
Strnad, L.; Ettler, V.; Mihaljevič, M.; Hladil, Jindřich
2008-01-01
Roč. 9, - (2008), s. 235-236 ISSN 1885-7264. [Reunión de la Sociedad Española de Mineralogía /28./ ; Reunión de la Sociedad Española de Arcillas /21./. Zaragoza, 16.09.2008-19.09.2008] R&D Projects: GA AV ČR IAA300130702 Institutional research plan: CEZ:AV0Z30130516 Keywords : trace elements * reference material * carbonate * ICP-MS * laser ablation Subject RIV: DB - Geology ; Mineralogy http://www.ehu.es/sem/macla_pdf/macla9/macla9_235.pdf
Kavner, A.
2017-12-01
In a multicomponent multiphase geochemical system undergoing a chemical reaction such as precipitation and/or dissolution, the partitioning of species between phases is determined by a combination of thermodynamic properties and transport processes. The interpretation of the observed distribution of trace elements requires models integrating coupled chemistry and mechanical transport. Here, a framework is presented that predicts the kinetic effects on the distribution of species between two reacting phases. Based on a perturbation theory combining Navier-Stokes fluid flow and chemical reactivity, the framework predicts rate-dependent partition coefficients in a variety of different systems. We present the theoretical framework, with applications to two systems: 1. species- and isotope-dependent Soret diffusion of species in a multicomponent silicate melt subjected to a temperature gradient, and 2. Elemental partitioning and isotope fractionation during precipitation of a multicomponent solid from a multicomponent liquid phase. Predictions will be compared with results from experimental studies. The approach has applications for understanding chemical exchange in at boundary layers such as the Earth's surface magmatic systems and at the core/mantle boundary.
International Nuclear Information System (INIS)
Gwo, J.P.; Jardine, P.M.; Yeh, G.T.; Wilson, G.V.
1995-04-01
Matrix diffusion, a diffusive mass transfer process,in the structured soils and geologic units at ORNL, is believe to be an important subsurface mass transfer mechanism; it may affect off-site movement of radioactive wastes and remediation of waste disposal sites by locally exchanging wastes between soil/rock matrix and macropores/fractures. Advective mass transfer also contributes to waste movement but is largely neglected by researchers. This report presents the first documented 2-D multiregion solute transport code (MURT) that incorporates not only diffusive but also advective mass transfer and can be applied to heterogeneous porous media under transient flow conditions. In this report, theoretical background is reviewed and the derivation of multiregion solute transport equations is presented. Similar to MURF (Gwo et al. 1994), a multiregion subsurface flow code, multiplepore domains as suggested by previous investigators (eg, Wilson and Luxmoore 1988) can be implemented in MURT. Transient or steady-state flow fields of the pore domains can be either calculated by MURF or by modelers. The mass transfer process is briefly discussed through a three-pore-region multiregion solute transport mechanism. Mass transfer equations that describe mass flux across pore region interfaces are also presented and parameters needed to calculate mass transfer coefficients detailed. Three applications of MURT (tracer injection problem, sensitivity analysis of advective and diffusive mass transfer, hillslope ponding infiltration and secondary source problem) were simulated and results discussed. Program structure of MURT and functions of MURT subroutiness are discussed so that users can adapt the code; guides for input data preparation are provided in appendices
International Nuclear Information System (INIS)
Chatham, J.R.; Wanty, R.B.; Langmuir, D.
1981-02-01
Groundwaters from aquifers in two different sandstone-type uranium mining districts in Texas and Wyoming were collected and chemically analyzed. The data were used to compare the merits of using the computed saturation state of the groundwater with respect to uranium minerals, to that of single-element tracers in the groundwater for geochemical prospecting. Chemical properties of the Texas waters were influenced locally by preferred groundwater flow within buried fluvial channel deposits; upward leakage of brines along growth faults into the aquifer; and the establishment of a redox interface (Eh = 0 volts) within the aquifer. Chemical characteristics of aquifer waters in Wyoming changed gradually downdip, reflecting regional homogeneity in groundwater flow and a more gradual downdip reduction of Eh values than in Texas. The most reliable indicator of reduced uranium ore in both study sites was the saturation state of groundwater with respect to uraninite or coffinite. For both minerals, this saturation state increased from 15 to 20 log units as reduced ore deposits were approached over distances of 3 to 4.5 km in both sites. Tyuyamunite and carnotite approached or exceeded saturation in some oxidized waters of the Texas site reflecting possible occurrences of these minerals. The radiogenic elements Ta and Rn were excellent indicators of ore directly within the deposits, where anomalous values were 2 to 3 orders of magnitude above background. Helium also increased near the ore, although anomalies were generally displaced in the direction of groundwater flow. Uranium and uranium isotope values did not individually pinpoint ore, but may be used together to classify groundwater samples in terms of their position relative to uranium mineralization
Element-topology-independent preconditioners for parallel finite element computations
Park, K. C.; Alexander, Scott
1992-01-01
A family of preconditioners for the solution of finite element equations are presented, which are element-topology independent and thus can be applicable to element order-free parallel computations. A key feature of the present preconditioners is the repeated use of element connectivity matrices and their left and right inverses. The properties and performance of the present preconditioners are demonstrated via beam and two-dimensional finite element matrices for implicit time integration computations.
Standard elements; Elements standards
Energy Technology Data Exchange (ETDEWEB)
Blanc, B [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1958-07-01
Following his own experience the author recalls the various advantages, especially in the laboratory, of having pre-fabricated vacuum-line components at his disposal. (author) [French] A la suite de sa propre experience, l'auteur veut rappeler les divers avantages que presente, tout particulierement en laboratoire, le fait d'avoir a sa disposition des elements pre-fabriques de canalisations a vide. (auteur)
International Nuclear Information System (INIS)
Lautard, J.J.; Flumiani, T.
2003-01-01
The mixed dual finite element method is usually used for the resolution of the SPN transport equations (simplified PN equations) in 3D homogenized geometries (composed by homogenized rectangles or hexagons). This method produces fast results with little memory requirements. We have extended the previous method to the treatment of unstructured geometries composed by quadrilaterals (for the moment limited to 2D), allowing us to treat geometries where fuel pins are exactly represented. The iterative resolution of the resulting matrix system is a generalization of the one already developed for the cartesian and the hexagonal geometries. In order to illustrate and to show the efficiency of this method, results on the NEA-C5G7-MOX benchmark are given. The previous benchmark has been extended for the hexagonal geometry and we provide here some results. This method is a first step towards the treatment of pin by pin core calculations without homogenization. The present solver is a prototype. It shows the efficiency of the method and it has to be extended to 3D calculations as well as to exact transport calculations. We also intend to extend the method to the treatment of unstructured geometries composed by quadrilaterals with curved edges (sectors of a circle).The iterative algorithm has yet to be accelerated using multigrid techniques through a coupling with the present homogenized solver (MINOS). In the future, it will be included in the next generation neutronic toolbox DESCARTES currently under development
International Nuclear Information System (INIS)
Sanzi, H; Elvira, G; Kloster, M; Asta, E; Zalazar, M
2006-01-01
All welding processes induce deformations and thermal tensions, which must be evaluated correctly since they can influence a component's structural integrity. This work determines the distribution of temperatures that develop during a manual welding process with shielded electrodes (SMAW), on the circumference seam of a pipe for use in polyducts. A simplified model of Finite Elements (FEA) using three dimensional solids is proposed for the study. The analysis considers that while the welding process is underway, no heat is lost into the environment, that is, adiabatic conditions are considered, and the transformations produced in the material due to phase changes do not produce modifications in the properties of the supporting or base materials. The results of the simulation are compared with those obtained by recent analytical studies developed by different investigators, such as Nguyen, Ohta, Matsuoka, Suzuki and Taeda, where a continuously moving three dimensional double ellipsoidal source was used. The results are then compared with the experimental results by measuring with thermocouples. This study reveals the sensitivity and the validity of the proposed computer model, and in a second stage optimizes the engineering times for the resolution of a problem like the one presented in order to design the corresponding welding procedure (CW)
Cooper, Zara; Courtwright, Andrew; Karlage, Ami; Gawande, Atul; Block, Susan
2014-12-01
To provide a description of communication breakdowns and to identify interventions to improve surgical decision making for elderly patients with serious illness and acute, life-threatening surgical conditions. Communication between surgeons, patients, and surrogates about goals of treatment plays an important and understudied role in determining the surgical interventions elderly patients with serious illness receive. Communication breakdowns may lead to nonbeneficial procedures in acute events near the end of life. We review the available literature on factors that lead to communication challenges and nonbeneficial surgery at the end of life. We use this review to identify solutions for navigating surgical decision making for seriously ill elderly patients with acute surgical conditions. Surgeon, patient, surrogate, and systemic factors-including time constraints, inadequate provider communication skills and training, uncertainty about prognosis, patient and surrogate anxiety and fear of inaction, and limitations in advance care planning-contribute to communication challenges and nonbeneficial surgery at the end of life. Surgeons could accomplish more effective communication with seriously ill elderly patients if they had a structured, standardized approach to exploring patients' preferences and to integrating those preferences into surgical decisions in the acute setting. Improved communication among surgeons, patients, and surrogates is necessary to ensure that patients receive the care that they want and to avoid nonbeneficial treatment. Further research is needed to learn how to best structure these conversations in the emergency surgical setting.
Rodrigues, S M; Henriques, B; Ferreira da Silva, E; Pereira, M E; Duarte, A C; Groenenberg, J E; Römkens, P F A M
2010-12-01
To assess environmental risks related to contaminants in soil it is essential to predict the available pool of inorganic contaminants at regional scales, accounting for differences between soils from variable geologic and climatic origins. An approach composed of a well-accepted soil extraction procedure (0.01 M CaCl(2)) and empirical Freundlich-type models in combination with mechanistically based models which to date have been used only in temperate regions was applied to 136 soils from a South European area and evaluated for its possible general use in risk assessment. Empirical models based on reactive element pools and soil properties (pH, organic carbon, clay, total Al, Fe and Mn) provided good estimations of available concentrations for a broad range of contaminants including As, Ba, Cd, Co, Cu, Hg, Mo, Ni, Pb, Sb, Se and Zn (r(2): 0.46-0.89). The variation of the pools of total Al in soils expressed the sorptive capacity of aluminosilicates and Al oxides at the surfaces and edges of clay minerals better than the actual variability of clay contents. The approach has led to recommendations for further research with particular emphasis on the impact of clay on the solubility of As and Sb, on the mechanisms controlling Cr and U availability and on differences in binding properties of soil organic matter from different climatic regions. This study showed that such approach may be included with a good degree of certainty for first step risk assessment procedures to identify potential risk areas for leaching and uptake of inorganic contaminants in different environmental settings. Copyright © 2010 Elsevier Ltd. All rights reserved.
Kordy, M.; Wannamaker, P.; Maris, V.; Cherkaev, E.; Hill, G.
2016-01-01
Following the creation described in Part I of a deformable edge finite-element simulator for 3-D magnetotelluric (MT) responses using direct solvers, in Part II we develop an algorithm named HexMT for 3-D regularized inversion of MT data including topography. Direct solvers parallelized on large-RAM, symmetric multiprocessor (SMP) workstations are used also for the Gauss-Newton model update. By exploiting the data-space approach, the computational cost of the model update becomes much less in both time and computer memory than the cost of the forward simulation. In order to regularize using the second norm of the gradient, we factor the matrix related to the regularization term and apply its inverse to the Jacobian, which is done using the MKL PARDISO library. For dense matrix multiplication and factorization related to the model update, we use the PLASMA library which shows very good scalability across processor cores. A synthetic test inversion using a simple hill model shows that including topography can be important; in this case depression of the electric field by the hill can cause false conductors at depth or mask the presence of resistive structure. With a simple model of two buried bricks, a uniform spatial weighting for the norm of model smoothing recovered more accurate locations for the tomographic images compared to weightings which were a function of parameter Jacobians. We implement joint inversion for static distortion matrices tested using the Dublin secret model 2, for which we are able to reduce nRMS to ˜1.1 while avoiding oscillatory convergence. Finally we test the code on field data by inverting full impedance and tipper MT responses collected around Mount St Helens in the Cascade volcanic chain. Among several prominent structures, the north-south trending, eruption-controlling shear zone is clearly imaged in the inversion.
Karaton, Muhammet
2014-01-01
A beam-column element based on the Euler-Bernoulli beam theory is researched for nonlinear dynamic analysis of reinforced concrete (RC) structural element. Stiffness matrix of this element is obtained by using rigidity method. A solution technique that included nonlinear dynamic substructure procedure is developed for dynamic analyses of RC frames. A predicted-corrected form of the Bossak-α method is applied for dynamic integration scheme. A comparison of experimental data of a RC column element with numerical results, obtained from proposed solution technique, is studied for verification the numerical solutions. Furthermore, nonlinear cyclic analysis results of a portal reinforced concrete frame are achieved for comparing the proposed solution technique with Fibre element, based on flexibility method. However, seismic damage analyses of an 8-story RC frame structure with soft-story are investigated for cases of lumped/distributed mass and load. Damage region, propagation, and intensities according to both approaches are researched.
Energy Technology Data Exchange (ETDEWEB)
Souza, Altivo Monteiro de
2008-12-15
The world energy consumption has been increasing strongly in recent years. Nuclear energy has been regarded as a suitable option to supply this growing energy demand in industrial scale. In view of the need of improving the understanding and capacity of analysis of nuclear power plants, modern simulation techniques for flow and heat transfer problems are gaining greater importance. A large number of problems found in nuclear reactor engineering can be dealt assuming axial symmetry. Thus, in this work a stabilized finite element formulation for the solution of the Navier-Stokes and energy equations for axisymmetric problems have been developed and tested. The formulation has been implemented in the NS{sub S}OLVER{sub M}PI{sub 2}D{sub A} program developed at the Parallel Computation Laboratory of the Instituto de Engenharia Nuclear (LCP/IEN) and is now available either for safety analysis or design of nuclear systems. (author)
Galvanic element. Galvanisches Element
Energy Technology Data Exchange (ETDEWEB)
Sprengel, D.; Haelbig, H.
1980-01-03
The invention concerns a gas-tight sealed accumulator with positive and negative electrode plates and an auxillary electrode electroconductively bound to the latter for suppressing oxygen pressure. The auxillary electrode is an intermediate film electrode. The film catalysing oxygen reduction is hydrophilic in character and the other film is hydrophobic. A double coated foil has proved to be advantageous, the hydrophilic film being formed from polymer-bound activated carbon and the hydrophrobic film from porous polytetrafluoroethylene. A metallic network of silver or nickel is rolled into the outer side of the activated carbon film. This auxillary electrode can be used to advantage in all galvanic elements. Even primary cells fall within the scope of application for auxillary electrodes because many of these contain a highly oxidized electrodic material which tends to give off oxygen.
Celani, F; Righi, E; Trenta, G; Catena, C; D’Agostaro, G; Quercia, P; Andreassi, V; Marini, P; Di Stefano, V; Nakamura, M; Mancini, A; Sona, P G; Fontana, F; Gamberale, L; Garbelli, D; Celia, E; Falcioni, F; Marchesini, M; Novaro, E; Mastromatteo, U
2005-01-01
Abstract They were continued, at National Institute of Nuclear Physics, Frascati National Laboratories-Italy, the systematic studies about detection of new elements, some even with isotopic composition different from natural one, after prolonged electrolysis of Pd wires. The electrolytic solution adopted is the, unusual, used from our experimental group since 1999. In short, it was a mixture of both heavy ethyl alcohol (C2H5OD at 90-95%) and water (D2O, at 10-5%), with Th salts at micromolar concentration and Hg at even lower concentration (both of spectroscopic purity). The liquid solutions, before use, were carefully vacuum distilled (and on line 100nm filtered) at low temperatures (30-40°C) and analysed by ICP-MS. The pH was kept quite mild (acidic at about 3-4). The cathode is Pd (99.9% purity) in the shape of long (60cm) and thin wires (diameter only 0.05mm). Before use, it is carefully cleaned and oxidised by Joule heating in air following a (complex) procedure from us continuously improved (since 1995...
OXIDATION OF TRANSURANIC ELEMENTS
Moore, R.L.
1959-02-17
A method is reported for oxidizing neptunium or plutonium in the presence of cerous values without also oxidizing the cerous values. The method consists in treating an aqueous 1N nitric acid solution, containing such cerous values together with the trivalent transuranic elements, with a quantity of hydrogen peroxide stoichiometrically sufficient to oxidize the transuranic values to the hexavalent state, and digesting the solution at room temperature.
Energy Technology Data Exchange (ETDEWEB)
Desre, P. [Ecole Nationale Superieure d' Electrochimie et d' Electrometallurgie (France); Schaub, B. [Centre d' Etudes Nucleaires de Grenoble (France); Bonnier, I. E. [Ecole Nationale Superieure d' Electrochimie et d' Electrometallurgie, Grenoble (France)
1966-01-15
The authors calculate the distribution coefficient {Gamma}{sub i} between the liquid and solid phases of an element i in the presence of other elements j in a solvent M ({Gamma}{sub i} = x'{sub i}/x{sub i}, where x'{sub i} and x{sub i} are the atomic fractions of i in the solid and liquid phases respectively) from the thermodynamic properties of binary systems of the type (i, M), (j, M) and (i, j). They show that the interaction of all the elements present may, under certain conditions, strongly affect the value of the coefficient {Gamma}{sub i}. This effect is pronounced if the following condition is fulfilled: {gamma}{sup {infinity}}{sub i(M)}, {gamma}{sup {infinity}}{sub j(M)} > {gamma}{sup {infinity}}{sub ij} where {gamma}{sup {infinity}}{sub i(M)}, {gamma}{sup {infinity}}{sub j(M)} and {gamma}{sup {infinity}}{sub ij} are limiting activity coefficients of the constituents i and j in the (i, M) (j, M) and (i, j) liquid state systems. It is a simple matter to deduce from this condition an application to the purification of metals by the zone-melting method; the condition enables one to choose an element j which is added deliberately to a metal in order to facilitate the elimination-of an element i (subsequent elimination of the element j being also, of course, a simple matter). For example, the authors were able to confirm that the addition of aluminium to beryllium enables one to improve the elimination of iron during the purification of the beryllium by the zone-melting technique, the aluminium acting as a carrier. (author) [French] Les auteurs calculent le coefficient de distribution Greek-Capital-Letter-Gamma {sub i} entre phases liquide et solide d'un element i en presence d'autres elements j dans un solvant M ( Greek-Capital-Letter-Gamma {sub i} = x'{sub i}/x{sub i}, x'{sub i} et x{sub i} representant respectivement les fractions atomiques de i dans les phases solide et liquide), a partir des proprietes thermodynamiques des systemes binaires de type: (i, M
Analysis of trace elements in human hair by PIXE
International Nuclear Information System (INIS)
Baptista, G.B.; Montenegro, E.C.; Paschoa, A.S.; Barros Leite, C.V. de.
1980-10-01
The PIXE method was applied to the analysis of trace elements in scalp hair using two methods for target preparation. In the first method eigth hair strands each with nearly cylindrical geommetry and approximately the same diameter were selected and placed on an aluminum frame. In the second method a given mass of hair was dissolved with nitric acid and a known amount of strontium was added to the solution and dripped on a membrane filter using a micropipet. The results for the concentrations of trace elements in hair obtained by the two methods are compared and several aspects of the analysis is discussed. (Author) [pt
Finite element approximation to the even-parity transport equation
International Nuclear Information System (INIS)
Lewis, E.E.
1981-01-01
This paper studies the finite element method, a procedure for reducing partial differential equations to sets of algebraic equations suitable for solution on a digital computer. The differential equation is cast into the form of a variational principle, the resulting domain then subdivided into finite elements. The dependent variable is then approximated by a simple polynomial, and these are linked across inter-element boundaries by continuity conditions. The finite element method is tailored to a variety of transport problems. Angular approximations are formulated, and the extent of ray effect mitigation is examined. Complex trial functions are introduced to enable the inclusion of buckling approximations. The ubiquitous curved interfaces of cell calculations, and coarse mesh methods are also treated. A concluding section discusses limitations of the work to date and suggests possible future directions
Transfer Pricing Profit Split Methods : A Practical Solution?
Quttineh, Yousef
2009-01-01
The purpose of this master’s thesis is to explain and analyze whether today’s existing regulations provide sufficient guidance on how to apply the Profit Split Method (PSM) in practice. Since the enterprises’ profits arising from intra-group transactions increases, the tax base for any government also becomes larger and more important. This issue will likely become even more problematic as the globalization branches out and the majority of the global trade is undertaken between associated ent...
International Nuclear Information System (INIS)
Moeller, P.; Parekh, P.P.; Morteani, G.; Hoefs, J.
1979-01-01
Rare-earth element (REE) and stable-isotope distribution patterns in calcites from the mining areas of St. Andreasberg, Clausthal and Bad Grund, western Harz, Germany, have been determined. Three types of REE distribution patterns were found: type I is characterized by high amounts of light REE without any Ce and Eu anomalies and relativity homogeneous C- and O-isotopic composition. Type II displays conspicuous Ce and Eu anomalies at lower levels of concentration of the light REE. Type III has very low amounts of REE. Type II and III exhibit a more variable C-isotopic composition than type I. The calcite with type I patterns is assumed to be derived mainly from magnetic waters. A possible source for the magnetic waters seems to be the Brocken-Oker granite. Type-II calcites and the sulfides are probably derived from upheated country rock whereas calcite with type-III pattern mineralized from relatively cold descending solutions. The calcite with type-I pattern turns out to be not in equilibrium with sulfides, although both are in intimate contact, e.g. in banded ores. This non-equilibrium indicates two independent sources for this calcite with type-I pattern and the sulfides. (Auth.)
Energy Technology Data Exchange (ETDEWEB)
Sivaramakrishnan, C. K.; Jadhav, A. V.; Reghuraman, K.; Mathew, K. A.; Nair, P. S.; Ramaniah, M. V.
1973-07-01
Research progress is reported on studies of the transplutonium elements including recovery and purification of americium, preparation of /sup 238/Pu, extraction studies using diethylhexyl phosphate. (DHM)
DEFF Research Database (Denmark)
Hajeb, Parvaneh; Shakibazadeh, Shahram; Sloth, Jens Jørgen
2016-01-01
Food is considered the main source of toxic element (arsenic, cadmium, lead, and mercury) exposure to humans, and they can cause major public health effects. In this chapter, we discuss the most important sources for toxic element in food and the foodstuffs which are significant contributors to h...
Directory of Open Access Journals (Sweden)
G.A Ramírez R.
2013-03-01
Full Text Available In this work we present numerical solutions of the Rayleigh-Plesset equation which describes the evolution of cavitating bubbles. In order to do that, we consider FEMG (Finite Element Method Galerkin; this simulation is performed for an inviscid and incompressible fluid in an uniform temperature field with constant surface tension, and the cavitation model into the which the pressure inside bubbles is equal to the fluid vapor pressure. Thus, in this problem is considered the Dirichlet boundary problem, and we obtained criteria for the boundary conditions at the cavitation phenomenon through to the which give rise to the bubble growing.En este trabajo se plantean soluciones numéricas a la ecuación de Rayleigh-Plesset que describe la evolución de las burbujas en la cavitación. Para ello, se considera el MEFG (Método del Elemento Finito de Galerkin; tal simulación se realiza en un fluido invíscido e incompresible en un campo de temperatura uniforme, una tensión superficial esencialmente constante, y el modelo de cavitación en el flujo siendo la presión interna de las burbujas igual a la presión de vapor del fluido. De esta manera, para el problema se considera el problema de Dirichlet y se obtienen los criterios de frontera que auspician el fenómeno de cavitación a través del crecimiento de las burbujas o cavidades.
Finite elements and approximation
Zienkiewicz, O C
2006-01-01
A powerful tool for the approximate solution of differential equations, the finite element is extensively used in industry and research. This book offers students of engineering and physics a comprehensive view of the principles involved, with numerous illustrative examples and exercises.Starting with continuum boundary value problems and the need for numerical discretization, the text examines finite difference methods, weighted residual methods in the context of continuous trial functions, and piecewise defined trial functions and the finite element method. Additional topics include higher o
International Nuclear Information System (INIS)
Habersbergerova, A.; Janovsky, I.
1985-01-01
The factors were studied affecting thiosulfate radiolysis in the so-called spray solution for nuclear power plant containments. The reaction mechanism of primary radiolytic reactions leading to thiosulfate decomposition was studied using pulse radiolysis. Also measured was hydrazine loss in the irradiation of the bubbling solution intended for the capture of volatile chemical forms of radioiodine. Pulse radiolysis was used to study the kinetics of hydrazine reaction with elemental iodine. (author)
International Nuclear Information System (INIS)
Armijo, J.S.
1976-01-01
A fuel element for nuclear reactors is proposed which has a higher corrosion resisting quality in reactor operations. The zirconium alloy coating around the fuel element (uranium or plutonium compound) has on its inside a protection layer of metal which is metallurgically bound to the substance of the coating. As materials are namned: Alluminium, copper, niobium, stainless steel, and iron. This protective metallic layer has another inner layer, also metallurgically bound to its surface, which consists usually of a zirconium alloy. (UWI) [de
Utilization of Large Cohesive Interface Elements for Delamination Simulation
DEFF Research Database (Denmark)
Bak, Brian Lau Verndal; Lund, Erik
2012-01-01
This paper describes the difficulties of utilizing large interface elements in delamination simulation. Solutions to increase the size of applicable interface elements are described and cover numerical integration of the element and modifications of the cohesive law....
Adaptive finite-element ballooning analysis of bipolar ionized fields
International Nuclear Information System (INIS)
Al-Hamouz, Z.M.
1995-01-01
This paper presents an adaptive finite-element iterative method for the analysis of the ionized field around high-voltage bipolar direct-current (HVDC) transmission line conductors without resort to Deutsch's assumption. A new iterative finite-element ballooning technique is proposed to solve Poisson's equation wherein the commonly used artificial boundary around the transmission line conductors is simulated at infinity. Unlike all attempts reported in the literature for the solution of ionized field, the constancy of the conductors' surface field at the corona onset value is directly implemented in the finite-element formulation. In order to investigate the effectiveness of the proposed method, a laboratory model was built. It has been found that the calculated V-I characteristics and the ground-plane current density agreed well with those measured experimentally. The simplicity in computer programming in addition to the low number of iterations required to achieve convergence characterize this method of analysis
Zee, van der S.E.A.T.M.; Leijnse, A.
2013-01-01
Solute transport is of importance in view of the movement of nutrient elements, e.g. towards the plant root system, and because of a broad range of pollutants. Pollution is not necessarily man induced, but may be due to geological or geohydrological causes, e.g. in the cases of pollution with
An Inexpensive Solution Calorimeter
Kavanagh, Emma; Mindel, Sam; Robertson, Giles; Hughes, D. E. Peter
2008-01-01
We describe the construction of a simple solution calorimeter, using a miniature bead thermistor as a temperature-sensing element. This has a response time of a few seconds and made it possible to carry out a thermometric reaction in under a minute, which led to minimal heat losses. Small temperature changes of 1 K associated with enthalpies of…
Tani, Laurits
2015-01-01
To control Peltier elements, temperature controller was used. I used TEC-1091 that was manufactured my Meerstetter Engineering. To gain control with the temperature controller, software had to be intalled on a controlling PC. There were different modes to control the Peltier: Tempererature controller to control temperature, Static current/voltage to control voltage and current and LIVE ON/OFF to auto-tune the controller respectively to the system. Also, since near the collision pipe there is much radiation, radiation-proof Peltier elements have to be used. To gain the best results, I had to find the most efficient Peltier elements and try to get their cold side to -40 degrees Celsius.
Solute segregation during irradiation
International Nuclear Information System (INIS)
Wiedersich, H.; Okamoto, P.R.; Lam, N.Q.
1977-01-01
Irradiation at elevated temperature induces redistribution of the elements in alloys on a microstructural level. This phenomenon is caused by differences in the coupling of the various alloy constituents to the radiation-induced defect fluxes. A simple model of the segregation process based on coupled reaction-rate and diffusion equations is discussed. The model gives a good description of the experimentally observed consequences of radiation-induced segregation, including enrichment or depletion of solute elements near defect sinks such as surfaces, voids and dislocations; precipitation of second phases in solid solutions; precipitate redistribution in two-phase alloys; and effects of defect-production rates on void-swelling rates in alloys with minor solute additions
International Nuclear Information System (INIS)
Kennedy, S.T.
1982-01-01
A nuclear reactor fuel element wherein a stack of nuclear fuel is prevented from displacement within its sheath by a retainer comprising a tube member which is radially expanded into frictional contact with the sheath by means of a captive ball within a tapered bore. (author)
International Nuclear Information System (INIS)
Hemingway, J.D.
1975-01-01
The review is covered in sections, entitled: predicted nuclear properties - including closed shells, decay characteristics; predicted chemical properties - including electronic structure and calculated properties, X-radiation, extrapolated chemical properties, separation chemistry; methods of synthesis; the natural occurrence of superheavy elements. (U.K.)
Energy Technology Data Exchange (ETDEWEB)
Dierssen, H
1999-07-01
Subjects: Concentrations, vertical and regional distributions of dissolved and suspended particulate trace elements; Trace element fluxes - vertical, regional, seasonal; The role of particulate organic carbon and atmospheric dust in vertical transport; Fractionation of trace elements in particulate material during transport. [German] Themen dieser Arbeit sind: Konzentrationen, vertikale und regionale Verteilungen von geloesten und suspendierten partikulaeren Spurenelementem (SE); SE-Fluesse vertikal, regional und saisonal; die Rolle des partikulaeren organischen Kohlenstoffs und des atmosphaerischen Staubeintrags beim Vertikaltransport; Fraktionierung von SE im partikulaeren Material beim Transport. (orig./SR)
Remediation using trace element humate surfactant
Energy Technology Data Exchange (ETDEWEB)
Riddle, Catherine Lynn; Taylor, Steven Cheney; Bruhn, Debra Fox
2016-08-30
A method of remediation at a remediation site having one or more undesirable conditions in which one or more soil characteristics, preferably soil pH and/or elemental concentrations, are measured at a remediation site. A trace element humate surfactant composition is prepared comprising a humate solution, element solution and at least one surfactant. The prepared trace element humate surfactant composition is then dispensed onto the remediation site whereby the trace element humate surfactant composition will reduce the amount of undesirable compounds by promoting growth of native species activity. By promoting native species activity, remediation occurs quickly and environmental impact is minimal.
Energy Technology Data Exchange (ETDEWEB)
Sharipov, A U; Yangirov, I Z
1982-01-01
A clay-powder, cement, and water-base plugging solution is proposed having reduced solution viscosity characteristics while maintaining tensile strength in cement stone. This solution utilizes silver graphite and its ingredients, by mass weight, are as follows: cement 51.2-54.3%; claypowder 6.06-9.1%; silver graphite 0.24-0.33%; with water making up the remainder.
International Nuclear Information System (INIS)
Flerov, G.
1976-01-01
The history is briefly described of the investigation of superheavy elements at the Joint Institute for Nuclear Research at Dubna. The significance of the investigation is assessed from the point of view of the nuclear structure study and major problems encountered in experimental efforts are indicated. Current experimental methods aiming at the discovery or the production of superheavy nuclei with Z approximately 114 are listed. (I.W.)
International Nuclear Information System (INIS)
Yilmaz, C.; Akkas, N.
1979-01-01
In previous studies a fluid element is incorporated in the widely used general purpose finite element program SAPIV. This type of problem is of interest in the design of nuclear components involving geometric complexities and nonlinearities. The elasticity matrix of a general-purpose finite element program is modified in such a way that it becomes possible to idealize fluid as a structural finite element with zero shear modulus and a given bulk modules. Using the modified version of SAPIV, several solid-fluid interactions problems are solved. The numerical solutions are compared with the available analytical solutions. They are shown to be in reasonable aggrement. It is also shown that by solving an exterior-fluid interaction problem, the pressure wave propagation in the acoustic medium can be solved with the same approach. In this study, two of the problem not studied in the previous work will be presented. These problems are namely the effects of the link elements used at solid-fluid interfaces and of the concentrated loads on the response of the fluid medium. Truss elements are used as the link elements. After these investigations, it is decided that general purpose finite element programs with slight modifications can be used in the safety analysis of nuclear reactor plants. By this procedure it is possible to handle two-dimensional plane strain and tridimensional axisymmetric problems of this type. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Yokoi, T [Akita University, Akita (Japan). Mining College
1996-05-01
As a method of computation of wave fields in irregularly stratified media by use of the indirect boundary element method, an induction formula was proposed in a previous report, utilizing the reference solution representing the wave field in corresponding horizontally stratified media. This algorithm applies to other types of vibration source. In computation of a wave field with the focus in presence on the ground or in the ground, the algorithm is incorporated into the computation as a vector including the reference solution as a variable. There exists no need to modify the algorithm. Once the reference solution is obtained, the wave field in the irregularly stratified media is automatically constructed by the proposed algorithm. The wave field to be the reference solution to a point source in the horizontally stratified media, is determined when the solution is obtained of the frequency/wavenumber domain by use of the reflection/transmission matrix of Kennet (1983) and converted into the solution of the spatial domain by use of the discrete wavenumber representation of Bouchon and Aki (1977). 8 refs., 2 figs.
Energy Technology Data Exchange (ETDEWEB)
Yuandi, Cheng [Academia Sinica, Shanghai, SH (China). Shanghai Inst. of Nuclear Research
1988-12-31
Autopsy samples of hair, kidney-cortex, liver and lung were analysed by radiochemical neutron activation analysis to determine the trace elements As, Cd, Hg, Cu and Zn, by instrumental neutron activation analysis to determine the trace elements Se, Na, Mg, Cl, Br, S, Cr, Co, and Rb and by PIXE to determine Fe, Ca and Mn. 15 refs, 22 figs, 10 tabs.
International Nuclear Information System (INIS)
Cheng Yuandi
1988-01-01
Autopsy samples of hair, kidney-cortex, liver and lung were analysed by radiochemical neutron activation analysis to determine the trace elements As, Cd, Hg, Cu and Zn, by instrumental neutron activation analysis to determine the trace elements Se, Na, Mg, Cl, Br, S, Cr, Co, and Rb and by PIXE to determine Fe, Ca and Mn. 15 refs, 22 figs, 10 tabs
International Nuclear Information System (INIS)
Abbott, T.I.; Jones, C.G.
1984-01-01
Radiographic elements are disclosed comprised of first and second silver halide emulsion layers separated by an interposed support capable of transmitting radiation to which the second image portion is responsive. At least the first imaging portion contains a silver halide emulsion in which thin tubular silver halide grains of intermediate aspect ratios (from 5:1 to 8:1) are present. Spectral sensitizing dye is adsorbed to the surface of the tubular grains. Increased photographic speeds can be realized at comparable levels of crossover. (author)
Structural modeling techniques by finite element method
International Nuclear Information System (INIS)
Kang, Yeong Jin; Kim, Geung Hwan; Ju, Gwan Jeong
1991-01-01
This book includes introduction table of contents chapter 1 finite element idealization introduction summary of the finite element method equilibrium and compatibility in the finite element solution degrees of freedom symmetry and anti symmetry modeling guidelines local analysis example references chapter 2 static analysis structural geometry finite element models analysis procedure modeling guidelines references chapter 3 dynamic analysis models for dynamic analysis dynamic analysis procedures modeling guidelines and modeling guidelines.
Hofmann, S
1999-01-01
The outstanding aim of experimental investigations of heavy nuclei is the exploration of spherical 'SuperHeavy Elements' (SHEs). On the basis of the nuclear shell model, the next double magic shell-closure beyond sup 2 sup 0 sup 8 Pb is predicted at proton numbers between Z=114 and 126 and at neutron number N=184. All experimental efforts aiming at identifying SHEs (Z>=114) were negative so far. A highly sensitive search experiment was performed in November-December 1995 at SHIP. The isotope sup 2 sup 9 sup 0 116 produced by 'radiative capture' was searched for in the course of a 33 days irradiation of a sup 2 sup 0 sup 8 Pb target with sup 8 sup 2 Se projectiles, however, only cross-section limits were measured. Positive results were obtained in experiments searching for elements from 110 to 112 using cold fusion and the 1n evaporation channel. The produced isotopes were unambiguously identified by means of alpha-alpha correlations. Not fission, but alpha emission is the dominant decay mode. The measurement ...
Czech Academy of Sciences Publication Activity Database
Strnad, L.; Ettler, V.; Mihaljevič, M.; Hladil, Jindřich; Chrastný, V.
2009-01-01
Roč. 33, č. 3 (2009), s. 347-355 ISSN 1639-4488 R&D Projects: GA AV ČR IAA300130702 Institutional research plan: CEZ:AV0Z30130516 Keywords : trace elements * carbonate * reference material * MACS-1 MACS-2 * laser ablation ICP-MS Subject RIV: DD - Geochemistry Impact factor: 2.061, year: 2009
International Nuclear Information System (INIS)
Hirose, Yasuo.
1982-01-01
Purpose: To increase the plenum space in a fuel element used for a liquid metal cooled reactor. Constitution: A fuel pellet is secured at one end with an end plug and at the other with a coil spring in a tubular container. A mechanism for fixing the coil spring composed of a tubular unit is mounted by friction with the inner surface of the tubular container. Accordingly, the recoiling force of the coil spring can be retained by fixing mechanism with a small volume, and since a large amount of plenum space can be obtained, the internal pressure rise in the cladding tube can be suppressed even if large quantities of fission products are discharged. (Kamimura, M.)
International Nuclear Information System (INIS)
Seitz, M.G.
1982-01-01
Reviewed in this statement are methods of preparing solutions to be used in laboratory experiments to examine technical issues related to the safe disposal of nuclear waste from power generation. Each approach currently used to prepare solutions has advantages and any one approach may be preferred over the others in particular situations, depending upon the goals of the experimental program. These advantages are highlighted herein for three approaches to solution preparation that are currently used most in studies of nuclear waste disposal. Discussion of the disadvantages of each approach is presented to help a user select a preparation method for his particular studies. Also presented in this statement are general observations regarding solution preparation. These observations are used as examples of the types of concerns that need to be addressed regarding solution preparation. As shown by these examples, prior to experimentation or chemical analyses, laboratory techniques based on scientific knowledge of solutions can be applied to solutions, often resulting in great improvement in the usefulness of results
International Nuclear Information System (INIS)
Iwano, Yoshihiko.
1993-01-01
Microfine cracks having a depth of less than 10% of a pipe thickness are disposed radially from a central axis each at an interval of less than 100 micron over the entire inner circumferential surface of a zirconium alloy fuel cladding tube. For manufacturing such a nuclear fuel element, the inside of the cladding tube is at first filled with an electrolyte solution of potassium chloride. Then, electrolysis is conducted using the cladding tube as an anode and the electrolyte solution as a cathode, and the inner surface of the cladding tube with a zirconium dioxide layer having a predetermined thickness. Subsequently, the cladding tube is laid on a smooth steel plate and lightly compressed by other smooth steel plate to form microfine cracks in the zirconium dioxide layer on the inner surface of the cladding tube. Such a compressing operation is continuously applied to the cladding tube while rotating the cladding tube. This can inhibit progress of cracks on the inner surface of the cladding tube, thereby enabling to prevent failure of the cladding tube even if a pellet/cladding tube mechanical interaction is applied. Accordingly, reliability of the nuclear fuel elements is improved. (I.N.)
Etienne, Brauns
2013-01-01
Reverse electrodialysis electrical power generation is based on the transport of salt ions through ion conductive membranes. The ion flux, equivalent to an electric current, results from a salinity gradient, induced by two salt solutions at significantly different concentrations. Such equivalent electric current in combination with the corresponding electrochemical potential difference across the membrane, equivalent to an electric potential, results in a battery equivalency. While having a c...
Optical selection of trace elements for discriminant analysis
International Nuclear Information System (INIS)
Rasmussen, S.E.; Erasmus, C.S.; Watterson, J.I.W.; Sellschop, J.P.F.
This report describes different methods of element selection; a combination of stepwise multivariate analysis of variance for primary element selection, and principle component analysis regression for the element interrelationship analysis. These offer a satisfactory solution to the problem of element selection
Evidence of nonuniqueness and oscillatory solutions in computational fluid mechanics
International Nuclear Information System (INIS)
Nunziato, J.W.; Gartling, D.K.; Kipp, M.E.
1985-01-01
We will review some of our recent experiences in computing solutions for nonlinear fluids in relatively simple, two-dimensional geometries. The purpose of this discussion will be to display by example some of the interesting but difficult questions that arise when ill-behaved solutions are obtained numerically. We will consider two examples. As the first example, we will consider a nonlinear elastic (compressible) fluid with chemical reactions and discuss solutions for detonation and detonation failure in a two-dimensional cylinder. In this case, the numerical algorithm utilizes a finite-difference method with artificial viscosity (von Neumann-Richtmyer method) and leads to two, distinctly different, stable solutions depending on the time step criterion used. The second example to be considered involves the convection of a viscous fluid in a rectangular container as a result of an exothermic polymerization reaction. A solidification front develops near the top of the container and propagates down through the fluid, changing the aspect ratio of the region ahead of the front. Using a Galerkin-based finite element method, a numerical solution of the partial differential equations is obtained which tracks the front and correctly predicts the fluid temperatures near the walls. However, the solution also exhibits oscillatory behavior with regard to the number of cells in the fluid ahead of the front and in the strength of the cells. More definitive experiments and analysis are required to determine whether this oscillatory phenomena is a numerical artifact or a physical reality. 20 refs., 14 figs
Chemistry of the actinide elements. Second edition
International Nuclear Information System (INIS)
Katz, J.J.; Seaborg, G.T.; Morss, L.R.
1987-01-01
This is an exhaustive, updated discourse on the chemistry of Actinides, Volume 1 contains a systematic coverage of the elements Ac, Th, Pa, U, Np, and Pu, which constitutes Part 1 of the work. The characterization of each element is discussed in terms of its nuclear properties, occurrence, preparation, atomic and metallic properties, chemistry of specific compounds, and solution chemistry. The first part of Volume 2 follows the same format as Volume 1 but is confined to the elements Am, Cm, Bk, Cf, and Es, plus a more condensed coverage of the Transeinsteinium elements (Fm, Md, No, Lw, and 104-109). Part 2 of this volume is devoted to a discussion of the actinide elements in general, with a specific focus on electronic spectra, thermodynamic and magnetic properties, the metallic state, structural chemistry, solution kinetics, organometallic chemistry for σ- and π-bonded compounds, and some concluding remarks on the superheavy elements
Energy Technology Data Exchange (ETDEWEB)
Rosales, Mario F [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)
1988-12-31
This article is based in the electromagnetic modeling presented in the first part of the series for the indirect solution of partial differential equations. Magnetic systems in closed regions with moving or axial symmetry, whose total current density is partially known (induction problems) are considered. Includes the ability to deal with means in movement and a sinusoidal behavior for the source density current is assumed. Some algorithms are developed that are implanted in the software CALIIE-2D of the Instituto de Investigaciones Electricas (IIE) to obtain the numerical solutions of these problems. The basic systems of algebraic equations are obtained through the application of the Galerkin method in the discreteness of the finite element with first order triangular elements. [Espanol] Este articulo se basa en la modelacion electromagnetica presentada en la primera parte de la serie y en el planteamiento proporcionado en la segunda parte para la solucion indirecta de ecuaciones diferenciales parciales. Se consideran sistemas magneticos en regiones cerradas con simetria traslacional o axial, cuya densidad de corriente total es parcialmente conocida (problemas de induccion). Incluye la capacidad para tratar medios con movimiento y se supone un comportamiento senoidal para la densidad de corriente fuente. Se desarrollan los algoritmos que se implantan en el programa de computo CALIIE-2D del Instituto de Investigaciones Electricas (IIE) para obtener las soluciones numericas de estos problemas. Los sistemas basicos de ecuaciones algebraicas se obtienen mediante la aplicacion del metodo de Galerkin en la discretizacion de elemento finito con elementos triangulares de primer orden.
Energy Technology Data Exchange (ETDEWEB)
Aldape U, F [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)
1989-01-15
This work presents: 1) The methodology and the experimental conditions of the PIXE technique so that it is used as a better option inside the analytical methods in aerosols studies, 2) The development, tests and applications of a cascade impactor of the Batelle type built to determine particle size to use it jointly with the mentioned technique in the determination of the elements concentration according to its size.By this way is fulfilled with the first goal of this extensive project. (Author)
Sonneveld, C.; Voogt, W.
2009-01-01
The characteristics of the soil solution in the root environment in the greenhouse industry differ much from those for field grown crops. This is caused firstly by the growing conditions in the greenhouse, which strongly differ from those in the field and secondly the function attributed to the soil
International Development Research Centre (IDRC) Digital Library (Canada)
The Crucible Group operates on the basis of good faith –– producing best effort non-consensus texts. ..... science and technology-based solutions to agricultural production constraints, it is ...... In 1997 researchers at Case Western Reserve Medical School in Ohio (US) ...... Is there a need to update the system-wide IP audit?
Annevelink, E.; Bos, H.L.; Meesters, K.P.H.; Oever, van den M.J.A.; Haas, de W.; Kuikman, P.J.; Rietra, R.P.J.J.; Sikirica, N.
2016-01-01
The fifth part of this report on Circular Solutions is about the circular principle From Waste to Resource. The purpose of this study is to select promising options for the implementation of this circular principle and to elaborate these options further.
Geoghegan, Michael W
2005-01-01
Podcasting is the art of recording radio show style audio tracks, then distributing them to listeners on the Web via podcasting software such as iPodder. From downloading podcasts to producing a track for fun or profit, ""Podcast Solutions"" covers the entire world of podcasting with insight, humor, and the unmatched wisdom of experience.
FINITE ELEMENT ANALYSIS OF STRUCTURES
Directory of Open Access Journals (Sweden)
PECINGINA OLIMPIA-MIOARA
2015-05-01
Full Text Available The application of finite element method is analytical when solutions can not be applied for deeper study analyzes static, dynamic or other types of requirements in different points of the structures .In practice it is necessary to know the behavior of the structure or certain parts components of the machine under the influence of certain factors static and dynamic . The application of finite element in the optimization of components leads to economic growth , to increase reliability and durability organs studied, thus the machine itself.
International Nuclear Information System (INIS)
Tonks, M.R.; Williamson, R.; Masson, R.
2015-01-01
The Finite Element Method (FEM) is a numerical technique for finding approximate solutions to boundary value problems. While FEM is commonly used to solve solid mechanics equations, it can be applied to a large range of BVPs from many different fields. FEM has been used for reactor fuels modelling for many years. It is most often used for fuel performance modelling at the pellet and pin scale, however, it has also been used to investigate properties of the fuel material, such as thermal conductivity and fission gas release. Recently, the United Stated Department Nuclear Energy Advanced Modelling and Simulation Program has begun using FEM as the basis of the MOOSE-BISON-MARMOT Project that is developing a multi-dimensional, multi-physics fuel performance capability that is massively parallel and will use multi-scale material models to provide a truly predictive modelling capability. (authors)
International Nuclear Information System (INIS)
Anon.
1975-01-01
The status is reported of studies on the solid-state chemistry of the actinides and lanthanides, spectroscopy of actinide compounds, and dynamic chemical description of actinide elements in solution. Phase studies were done on Rb 2 UO 4 , K 2 UO 4 , Li 2 UO 4 , and Es 2 U 2 O 7 . The lithium neptunate (VI) system was investigated and the existence of Li 2 NpO 4 was established. In oxidation-reduction studies it was shown that Am(III) can be electrolytically oxidized to Am(IV) in strong H 3 PO 4 , but Cf(III) and Pr(III) do not oxidize. The low-temperature absorption spectrum of thin films of NpBr 3 was investigated. (U.S.)
Energy Technology Data Exchange (ETDEWEB)
Duran, Celal; Bulut, Volkan N.; Gundogdu, Ali; Ozdes, Duygu; Yildirim, Nuri [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon (Turkey); Soylak, Mustafa, E-mail: soylak@erciyes.edu.tr [Department of Chemistry, Faculty of Arts and Sciences, Erciyes University, 38039 Kayseri (Turkey); Senturk, H. Basri [Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon (Turkey); Elci, Latif [Pamukkale University, Faculty of Arts and Sciences, Department of Chemistry, 20020 Denizli (Turkey)
2009-08-15
A separation/preconcentration procedure, based on the coprecipitation of Cr{sup 3+}, Fe{sup 3+}, Pb{sup 2+} and Zn{sup 2+} ions using a new organic coprecipitant, 3-phenly-4-o-hydroxybenzylidenamino-4,5-dihydro-1,2,4-triazole-5-one (POHBAT) without adding any carrier element has been developed. The method, thus, has been called carrier element-free coprecipitation (CEFC). The resultant concentrated elements were determined by flame atomic absorption spectrometric determinations. The influences of some analytical parameters including pH of the solution, amount of the coprecipitant, standing time, centrifugation rate and time, sample volume and diverse ions were investigated on the quantitative recoveries of analyte ions. The validation of the present preconcentration procedure was performed by the analysis of two certified reference materials. The recoveries of understudy analytes were found in the range of 93-98%, while the detection limits were calculated in the range of 0.3-2.0 {mu}g L{sup -1}. The precision of the method evaluated as relative standard deviation (R.S.D.), was in the range of 3-7% depend on the analytes. The proposed method was successfully applied to environmental samples for the determination of the analytes.
International Nuclear Information System (INIS)
Duran, Celal; Bulut, Volkan N.; Gundogdu, Ali; Ozdes, Duygu; Yildirim, Nuri; Soylak, Mustafa; Senturk, H. Basri; Elci, Latif
2009-01-01
A separation/preconcentration procedure, based on the coprecipitation of Cr 3+ , Fe 3+ , Pb 2+ and Zn 2+ ions using a new organic coprecipitant, 3-phenly-4-o-hydroxybenzylidenamino-4,5-dihydro-1,2,4-triazole-5-one (POHBAT) without adding any carrier element has been developed. The method, thus, has been called carrier element-free coprecipitation (CEFC). The resultant concentrated elements were determined by flame atomic absorption spectrometric determinations. The influences of some analytical parameters including pH of the solution, amount of the coprecipitant, standing time, centrifugation rate and time, sample volume and diverse ions were investigated on the quantitative recoveries of analyte ions. The validation of the present preconcentration procedure was performed by the analysis of two certified reference materials. The recoveries of understudy analytes were found in the range of 93-98%, while the detection limits were calculated in the range of 0.3-2.0 μg L -1 . The precision of the method evaluated as relative standard deviation (R.S.D.), was in the range of 3-7% depend on the analytes. The proposed method was successfully applied to environmental samples for the determination of the analytes.
Development of polygon elements based on the scaled boundary finite element method
International Nuclear Information System (INIS)
Chiong, Irene; Song Chongmin
2010-01-01
We aim to extend the scaled boundary finite element method to construct conforming polygon elements. The development of the polygonal finite element is highly anticipated in computational mechanics as greater flexibility and accuracy can be achieved using these elements. The scaled boundary polygonal finite element will enable new developments in mesh generation, better accuracy from a higher order approximation and better transition elements in finite element meshes. Polygon elements of arbitrary number of edges and order have been developed successfully. The edges of an element are discretised with line elements. The displacement solution of the scaled boundary finite element method is used in the development of shape functions. They are shown to be smooth and continuous within the element, and satisfy compatibility and completeness requirements. Furthermore, eigenvalue decomposition has been used to depict element modes and outcomes indicate the ability of the scaled boundary polygonal element to express rigid body and constant strain modes. Numerical tests are presented; the patch test is passed and constant strain modes verified. Accuracy and convergence of the method are also presented and the performance of the scaled boundary polygonal finite element is verified on Cook's swept panel problem. Results show that the scaled boundary polygonal finite element method outperforms a traditional mesh and accuracy and convergence are achieved from fewer nodes. The proposed method is also shown to be truly flexible, and applies to arbitrary n-gons formed of irregular and non-convex polygons.
Domain decomposition methods for mortar finite elements
Energy Technology Data Exchange (ETDEWEB)
Widlund, O.
1996-12-31
In the last few years, domain decomposition methods, previously developed and tested for standard finite element methods and elliptic problems, have been extended and modified to work for mortar and other nonconforming finite element methods. A survey will be given of work carried out jointly with Yves Achdou, Mario Casarin, Maksymilian Dryja and Yvon Maday. Results on the p- and h-p-version finite elements will also be discussed.
Elements of partial differential equations
Sneddon, Ian Naismith
1957-01-01
Geared toward students of applied rather than pure mathematics, this volume introduces elements of partial differential equations. Its focus is primarily upon finding solutions to particular equations rather than general theory.Topics include ordinary differential equations in more than two variables, partial differential equations of the first and second orders, Laplace's equation, the wave equation, and the diffusion equation. A helpful Appendix offers information on systems of surfaces, and solutions to the odd-numbered problems appear at the end of the book. Readers pursuing independent st
DEFF Research Database (Denmark)
Efeoglu, Arkin; Møller, Charles; Serie, Michel
2013-01-01
This paper outlines an artifact building and evaluation proposal. Design Science Research (DSR) studies usually consider encapsulated artifact that have relationships with other artifacts. The solution prototype as a composed artifact demands for a more comprehensive consideration in its systematic...... environment. The solution prototype that is composed from blending product and service prototype has particular impacts on the dualism of DSR’s “Build” and “Evaluate”. Since the mix between product and service prototyping can be varied, there is a demand for a more agile and iterative framework. Van de Ven......’s research framework seems to fit this purpose. Van de Ven allows for an iterative research approach to problem solving with flexible starting point. The research activity is the result between the iteration of two dimensions. This framework focuses on the natural evaluation, particularly on ex...
Energy Technology Data Exchange (ETDEWEB)
None
1973-07-01
Research progress is reported on studies in heavy element chemistry. Topics considered are: synergistic complexes of plutonyl ion; water uptake in synergistic systems; formation constants of some uranyl BETA -diketone complexes; thermodynamic acid dissociation constants of BETA -diketones; thermodynamic formation constants of uranyl BETA -diketonates; thiocyanate complexes of some trivalent lanthanides and actinides; stability constants of actinide complexes using dinonyl naphthalenesulfonic acid extraction; TBP extraction of actinides; stability constants of complexes of Pu(III) with 5- sulfosalicycllc acid; and solvent extraction behavior of Pu( VII). (DHM)
DEFF Research Database (Denmark)
Damkilde, Lars; Pedersen, Ronnie
2012-01-01
This paper describes a new triangular plane element which can be considered as a linear strain triangular element (LST) extended with incompatible displacement modes. The extended element will have a full cubic interpolation of strains and stresses. The extended LST-element is connected with other...... elements similar to the LST-element i.e. through three corner nodes and three mid-side nodes. The incompatible modes are associated with two displacement gradients at each mid-side node and displacements in the central node. The element passes the patch test and converges to the exact solution. The element...... often show a very slow convergence, and the numerical solutions will in general overestimate the bearing capacity and underestimate the displacements. The examples show that the extended incompatible element behaves much better than the corresponding compatible elements especially for coarse meshes....
Discrete elements method of neutron transport
International Nuclear Information System (INIS)
Mathews, K.A.
1988-01-01
In this paper a new neutron transport method, called discrete elements (L N ) is derived and compared to discrete ordinates methods, theoretically and by numerical experimentation. The discrete elements method is based on discretizing the Boltzmann equation over a set of elements of angle. The discrete elements method is shown to be more cost-effective than discrete ordinates, in terms of accuracy versus execution time and storage, for the cases tested. In a two-dimensional test case, a vacuum duct in a shield, the L N method is more consistently convergent toward a Monte Carlo benchmark solution
Finite element computation of plasma equilibria
International Nuclear Information System (INIS)
Rivier, M.
1977-01-01
The applicability of the finite element method is investigated for the numerical solution of the nonlinear Grad-Shafranov equation with free boundary for the flux function of a plasma at equilibrium. This method is based on the case of variational principles and finite dimensional subspaces whose elements are piecewise polynomial functions obtained by a Lagrange type interpolation procedure over a triangulation of the domain. Two cases of plasma pressure (exponential and quadratic including a vacuum region) were examined. In both cases the nonuniqueness of the solutions was shown in exhibiting a deeper solution in the case of exponential pressure function, and a non-constant solution for a quadratic pressure function. In order to get this ''other'' solution, two linearization methods were tested with two different constraints. Different cross sections are investigated
Elemental analysis: Reduction to SI units; Rueckfuehrung in der Elementanalytik
Energy Technology Data Exchange (ETDEWEB)
Rienitz, O.; Jaehrling, R.; Schiel, D. [PTB-Arbeitsgruppe ' ' Anorganische Analytik' ' , Braunschweig (Germany); Matschat, R.; Kipphardt, H. [Bundesanstalt fuer Materialforschung und -pruefung, Berlin (Germany); Gernand, W.; Oeter, D. [MercK KGaA (Germany)
2005-12-15
In a joint project, PTB, BAM and Merck KGaA worked on a metrological reduction system for all elements relevant to analysis. The BAM certified primary pure substances with a relative error of U{sub rel} {<=} 0.01% for the mass of the main element. This was achieved by measuring the mass components of all potential impurities, i.e. practically all elements of the periodic system except the main element. These pure substances are the national reference standards of elemental analysis. From them, PTB produces primary elementa solutions and transfer solutions which are passed on as reference standards. The industrial partner constructed the DKD calibration laboratory, which certifies commercial secondary calibration solutions on the basis of the reference standard solutions produced by PTB. With this final product, measurements in elemental analysis can be reduced to the SI units system as a routine procedure. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Morris, J; Johnson, S
2007-12-03
The Distinct Element Method (also frequently referred to as the Discrete Element Method) (DEM) is a Lagrangian numerical technique where the computational domain consists of discrete solid elements which interact via compliant contacts. This can be contrasted with Finite Element Methods where the computational domain is assumed to represent a continuum (although many modern implementations of the FEM can accommodate some Distinct Element capabilities). Often the terms Discrete Element Method and Distinct Element Method are used interchangeably in the literature, although Cundall and Hart (1992) suggested that Discrete Element Methods should be a more inclusive term covering Distinct Element Methods, Displacement Discontinuity Analysis and Modal Methods. In this work, DEM specifically refers to the Distinct Element Method, where the discrete elements interact via compliant contacts, in contrast with Displacement Discontinuity Analysis where the contacts are rigid and all compliance is taken up by the adjacent intact material.
Energy Technology Data Exchange (ETDEWEB)
Rosales, Mauricio F [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)
1988-12-31
This article is based in the electromagnetic modeling presented in the first part. Here are only considered the magnetic systems or electric systems in closed regions with moving or axial symmetry, whose total current density or total electric load density is known. The algorithms that have been implanted in the software CLIIE-2D of the Instituto de Investigaciones Electricas (IIE) are developed in order to obtain numerical solutions for these problems. The basic systems of algebraic equations are obtained by means of the application of the Galerkin method in the discreteness of the finite element with first order triangular elements. [Espanol] Este articulo se basa en la modelacion electromagnetica presentada en la primera parte. Aqui solo se consideran sistemas magneticos o sistemas electricos en regiones cerradas con simetria translacional o axial, cuya densidad de corriente total o densidad de carga electrica total es conocida. Se desarrollan los algoritmos que se han implantado en el programa de computo CLIIE-2D, del Instituto de Investigaciones Electricas (IIE) con el fin de obtener soluciones numericas para estos problemas. Los sistemas basicos de ecuaciones algebraicas se obtienen mediante la aplicacion del metodo de Galerkin en la discretizacion de elemento finito con elementos triangulares de primer orden.
Energy Technology Data Exchange (ETDEWEB)
Rosales, Mauricio F. [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)
1987-12-31
This article is based in the electromagnetic modeling presented in the first part. Here are only considered the magnetic systems or electric systems in closed regions with moving or axial symmetry, whose total current density or total electric load density is known. The algorithms that have been implanted in the software CLIIE-2D of the Instituto de Investigaciones Electricas (IIE) are developed in order to obtain numerical solutions for these problems. The basic systems of algebraic equations are obtained by means of the application of the Galerkin method in the discreteness of the finite element with first order triangular elements. [Espanol] Este articulo se basa en la modelacion electromagnetica presentada en la primera parte. Aqui solo se consideran sistemas magneticos o sistemas electricos en regiones cerradas con simetria translacional o axial, cuya densidad de corriente total o densidad de carga electrica total es conocida. Se desarrollan los algoritmos que se han implantado en el programa de computo CLIIE-2D, del Instituto de Investigaciones Electricas (IIE) con el fin de obtener soluciones numericas para estos problemas. Los sistemas basicos de ecuaciones algebraicas se obtienen mediante la aplicacion del metodo de Galerkin en la discretizacion de elemento finito con elementos triangulares de primer orden.
Superheavy element chemistry. Achievements and perspectives
International Nuclear Information System (INIS)
Schaedel, M.
2007-01-01
Superheavy elements have been synthesized and chemically characterized one-atom-at-a-time up to element 108. Presently, the quest for element 112 is one of the hottest topics in this field. The transactinide elements 104 to 108 are members of group 4 to 8 of the Periodic Table and element 112 belongs into group 12. Chemical properties of some of these elements, like elements 104 and 105, show stunning deviations from simple extrapolations within their respective group while others exhibit great similarities with their lighter homologues elements. First experiments to investigate seaborgium (Sg, element 106) in aqueous solution were performed. Again, in large international collaborations at the GSI, several gas-phase chemistry experiments were performed with hassium (Hs, element 108). Recently, the highly efficient and very clean separation of Hs was applied for nuclear studies of various Hs nuclides investigating their cross section and their nuclear decay properties in the region of the doubly-magic 270 Hs (Z=108, N=162). To overcome certain limitations of the presently used on-line chemical separations the new TransActinide Separation and Chemistry Apparatus (TASCA) - with a gas-filled recoil separator as a front-end tool - was designed and built at the GSI in a collaborative effort. Presently in its commissioning phase, TASCA shall be a key instrument for a big leap into quantitatively and qualitatively new experiments in the region of superheavy elements. (author)
The finite element method in engineering, 2nd edition
International Nuclear Information System (INIS)
Rao, S.S.
1986-01-01
This work provides a systematic introduction to the various aspects of the finite element method as applied to engineering problems. Contents include: introduction to finite element method; solution of finite element equations; solid and structural mechanics; static analysis; dynamic analysis; heat transfer; fluid mechanics and additional applications
Anthology of dry storage solutions
Energy Technology Data Exchange (ETDEWEB)
Allimann, Nathalie; Otton, Camille [AREVA, Paris (France)
2012-03-15
Around 35,000 PWR, BWR or Veer used fuel elements with various enrichment value up to 5%, various cooling time down to 2 years and various burn-ups up to 60,000 Mwd/tU are currently stored in AREVA dry storage solutions. These solutions are delivered in the United States, in Japan and in many European countries like Belgium, Switzerland, Italy, Armenia and Germany. With more than 1000 dry storage solutions delivered all over the world AREVA is the leader on this market. Dealing with dry storage is not an easy task. Products have to be flexible, to be adapted to customer needs and to the national regulations which may stipulate very strict tests such as airplane crash or simulation of earthquake. To develop a dry storage solution for a foreign country means to deal with its national competent authorities. All the national competent authorities do not have the same requirements. Storage conditions may also be different.
Anthology of dry storage solutions
International Nuclear Information System (INIS)
Allimann, Nathalie; Otton, Camille
2012-01-01
Around 35,000 PWR, BWR or Veer used fuel elements with various enrichment value up to 5%, various cooling time down to 2 years and various burn-ups up to 60,000 Mwd/tU are currently stored in AREVA dry storage solutions. These solutions are delivered in the United States, in Japan and in many European countries like Belgium, Switzerland, Italy, Armenia and Germany. With more than 1000 dry storage solutions delivered all over the world AREVA is the leader on this market. Dealing with dry storage is not an easy task. Products have to be flexible, to be adapted to customer needs and to the national regulations which may stipulate very strict tests such as airplane crash or simulation of earthquake. To develop a dry storage solution for a foreign country means to deal with its national competent authorities. All the national competent authorities do not have the same requirements. Storage conditions may also be different
Bubble-Enriched Least-Squares Finite Element Method for Transient Advective Transport
Directory of Open Access Journals (Sweden)
Rajeev Kumar
2008-01-01
Full Text Available The least-squares finite element method (LSFEM has received increasing attention in recent years due to advantages over the Galerkin finite element method (GFEM. The method leads to a minimization problem in the L2-norm and thus results in a symmetric and positive definite matrix, even for first-order differential equations. In addition, the method contains an implicit streamline upwinding mechanism that prevents the appearance of oscillations that are characteristic of the Galerkin method. Thus, the least-squares approach does not require explicit stabilization and the associated stabilization parameters required by the Galerkin method. A new approach, the bubble enriched least-squares finite element method (BELSFEM, is presented and compared with the classical LSFEM. The BELSFEM requires a space-time element formulation and employs bubble functions in space and time to increase the accuracy of the finite element solution without degrading computational performance. We apply the BELSFEM and classical least-squares finite element methods to benchmark problems for 1D and 2D linear transport. The accuracy and performance are compared.
International Nuclear Information System (INIS)
Greenwood, N.N.; Earnshaw, A.
1984-01-01
This textbook presents an account of the chemistry of the elements for both undergraduate and postgraduate students. It covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic;, bio-inorganic and other areas of chemistry which apply. The following elements of special nuclear interest are included: Rb, Cs, Fr, Sr, Ba, Ra, Po, At, Rn, Sc, Y, Zr, Hf, V, Nb, Ta, Mo, Tc, Ru, the Lanthanide Elements, the Actinide Elements. (U.K.)
Lanthanide complexation in aqueous solutions
International Nuclear Information System (INIS)
Choppin, G.R.
1984-01-01
The lanthanide elements form an extended series of cations with the same charge, slightly varying radii and useful magnetic and spectroscopic properties. Their use in technology is growing rapidly as their properties are more fully explored. The lanthanides also offer scientists valuable and often unique probes for investigating a variety of chemical and physical phenomena. This review has attempted to call attention to these latter uses without trying to provide a thorough discussion of all the relevant literature. Hopefully, awareness of the more interesting facets of present studies of lanthanide complexes in aqueous solution will spur even more advances in the use of these elements. (Auth.)
Chemistry of transuranium elements
International Nuclear Information System (INIS)
Anon.
1976-01-01
The half-wave amalgamation potential of No (element 102) was determined. Studies on the preparation and properties of Cf are reported; previously reported results on Es were confirmed. The heat of solution of Bk was measured. Spectroscopic and x-ray diffraction studies of Es-253 bromides are reported. Salicylate complexes with Sm(III), Am(III), Th(IV), and U(IV)O 2 were prepared; crystal data are given. Results of studies on the effect of secondary bonds on the strength of O double bond Np double bond O bonds are reported. The M series x rays of Np were measured. Anomalous spin--orbit splitting of the 4f level in the actinide series is reported. Progress is reported in studies on the Cf oxide system for oxygen pressures up to 760 mm and temperatures between 25 and 1000 0 C, as well as structural parameters of transplutonium oxysulfates and oxysulfides and actinide and lanthanide hydroxides. The electron paramagnetic resonance spectrum of 253 Es 2+ was observed in the cubic monocrystal hosts BaF 2 and SrCl 2
MESHREF, Finite Elements Mesh Combination with Renumbering
International Nuclear Information System (INIS)
1973-01-01
1 - Nature of physical problem solved: The program can assemble different meshes stored on tape or cards. Renumbering is performed in order to keep band width low. Voids and/ or local refinement are possible. 2 - Method of solution: Topology and geometry are read according to input specifications. Abundant nodes and elements are eliminated. The new topology and geometry are stored on tape. 3 - Restrictions on the complexity of the problem: Maximum number of nodes = 2000. Maximum number of elements = 1500
Transuranium elements in organic chemical forms
International Nuclear Information System (INIS)
Sakanoue, Masanobu; Yamamoto, Masayoshi
1987-01-01
It is very important to achive an understanding what role organic matter plays in the behavior of transuranium elements in the environment. This paper reports the studies on characteristics of fallout Pu and Am in soil closely related to soil organic matter, and interaction of humic acid and Am (III) in aqueous solution. From the results obtained, it was suggested that the humic acids had strong interaction with transuranium elements, but such soluble complexes were removed soon from the solution by coagulation and sorption on soil. (author)
Using reciprocity in Boundary Element Calculations
DEFF Research Database (Denmark)
Juhl, Peter Møller; Cutanda Henriquez, Vicente
2010-01-01
The concept of reciprocity is widely used in both theoretical and experimental work. In Boundary Element calculations reciprocity is sometimes employed in the solution of computationally expensive scattering problems, which sometimes can be more efficiently dealt with when formulated...... as the reciprocal radiation problem. The present paper concerns the situation of having a point source (which is reciprocal to a point receiver) at or near a discretized boundary element surface. The accuracy of the original and the reciprocal problem is compared in a test case for which an analytical solution...
Higher-Order Finite Element Solutions of Option Prices
DEFF Research Database (Denmark)
Raahauge, Peter
2004-01-01
Kinks and jumps in the payoff function of option contracts prevent an effectiveimplementation of higher-order numerical approximation methods. Moreover, thederivatives (the greeks) are not easily determined around such singularities, even withstandard lower-order methods. This paper suggests...... for prices as well as for first and second order derivatives(delta and gamma). Unlike similar studies, numerical approximation errors aremeasured both as weighted averages and in the supnorm over a state space includingtime-to-maturities down to a split second.KEYWORDS: Numerical option pricing, Transformed...
Kinetics of transuranium element oxidation-reduction reactions in solution
International Nuclear Information System (INIS)
Gourisse, D.
1966-09-01
A review of the kinetics of U, Np, Pu, Am oxidation-reduction reactions is proposed. The relations between the different activation thermodynamic functions (compensatory effect, formal entropy of the activated complex, magnitude of reactions velocities) are considered. The effects of acidity, ionic strength deuterium and mixed solvents polarity on reactions rates are described. The effect of different anions on reactions rates are explained by variations of the reaction standard free energy and variations of the activation free energy (coulombic interactions) resulting from the complexation of dissolved species by these anions. (author) [fr
CERCA's fuel elements instrumentation manufacturing
International Nuclear Information System (INIS)
Harbonnier, G.; Jarousse, C.; Pin, T.; Febvre, M.; Colomb, P.
2005-01-01
When research and test reactors wish to further understand the Fuel Elements behavior when operating as well as mastering their irradiation conditions, operators carry out neutron and thermo hydraulic analysis. For thermal calculation, the codes used have to be preliminary validated, at least in the range of the reactor safety operational limits. When some further investigations are requested either by safety authorities or for its own reactor needs, instrumented tools are the ultimate solution for providing representative measurements. Such measurements can be conducted for validating thermal calculation codes, at nominal operating condition as well as during transients ones, or for providing numerous and useful data in the frame of a new products qualification program. CERCA, with many years of experience for implanting thermocouples in various products design, states in this poster his manufacturing background on instrumented elements, plates or targets. (author)
Finite elements methods in mechanics
Eslami, M Reza
2014-01-01
This book covers all basic areas of mechanical engineering, such as fluid mechanics, heat conduction, beams, and elasticity with detailed derivations for the mass, stiffness, and force matrices. It is especially designed to give physical feeling to the reader for finite element approximation by the introduction of finite elements to the elevation of elastic membrane. A detailed treatment of computer methods with numerical examples are provided. In the fluid mechanics chapter, the conventional and vorticity transport formulations for viscous incompressible fluid flow with discussion on the method of solution are presented. The variational and Galerkin formulations of the heat conduction, beams, and elasticity problems are also discussed in detail. Three computer codes are provided to solve the elastic membrane problem. One of them solves the Poisson’s equation. The second computer program handles the two dimensional elasticity problems, and the third one presents the three dimensional transient heat conducti...
Electrical machine analysis using finite elements
Bianchi, Nicola
2005-01-01
OUTLINE OF ELECTROMAGNETIC FIELDSVector AnalysisElectromagnetic FieldsFundamental Equations SummaryReferencesBASIC PRINCIPLES OF FINITE ELEMENT METHODSIntroductionField Problems with Boundary ConditionsClassical Method for the Field Problem SolutionThe Classical Residual Method (Galerkin's Method)The Classical Variational Method (Rayleigh-Ritz's Method)The Finite Element MethodReferencesAPPLICATIONS OF THE FINITE ELEMENT METHOD TO TWO-DIMENSIONAL FIELDSIntroductionLinear Interpolation of the Function fApplication of the Variational MethodSimple Descriptions of Electromagnetic FieldsAppendix: I
Linear and Nonlinear Finite Elements.
1983-12-01
Metzler. Con/ ugte rapdent solution of a finite element elastic problem with high Poson rato without scaling and once with the global stiffness matrix K...nonzero c, that makes u(0) = 1. According to the linear, small deflection theory of the membrane the central displacement given to the membrane is not... theory is possible based on the approximations (l-y 2 )t = +y’ 2 +y , (1-y)’ 1-y’ 2 - y" (6) that change eq. (5) to V) = , [yŖ(1 + y") - Qy
Energy Technology Data Exchange (ETDEWEB)
Yang, J. [National Energy Technology Lab. (NETL), Albany, OR (United States); Oregon State Univ., Corvallis, OR (United States). College of Earth, Ocean, and Atmospheric Science; Torres, M. [Oregon State Univ., Corvallis, OR (United States). College of Earth, Ocean, and Atmospheric Science; Verba, C. [National Energy Technology Lab. (NETL), Albany, OR (United States); Oregon State Univ., Corvallis, OR (United States); Hakala, A. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)
2017-08-01
The accurate quantification of the rare earth element (REE) dissolved concentrations in natural waters are often inhibited by their low abundances in relation to other dissolved constituents such as alkali, alkaline earth elements, and dissolved solids. The high abundance of these constituents can suppress the overall analytical signal as well as create isobaric interferences on the REEs during analysis. Waters associated with natural gas operations on black shale plays are characterized by high salinities and high total dissolved solids (TDS) contents >150,000 mg/L. Methods used to isolate and quantify dissolved REEs in seawater were adapted in order to develop the capability of analyzing REEs in waters that are high in TDS. First, a synthetic fluid based on geochemical modelling of natural brine formation fluids was created within the Marcellus black shale with a TDS loading of 153,000 mg/L. To this solution, 1,000 ng/mL of REE standards was added based on preliminary analyses of experimental fluids reacted at high pressure and temperature with Marcellus black shale. These synthetic fluids were then run at three different dilution levels of 10, 100, and 1,000–fold dilutions through cation exchange columns using AG50-X8 exchange resin from Eichrom Industries. The eluent from the cation columns were then sent through a seaFAST2 unit directly connected to an inductively coupled plasma mass spectrometer (ICP-MS) to analyze the REEs. Percent recoveries of the REEs ranged from 80–110% and fell within error for the external reference standard used and no signal suppression or isobaric interferences on the REEs were observed. These results demonstrate that a combined use of cation exchange columns and seaFAST2 instrumentation are effective in accurately quantifying the dissolved REEs in fluids that are >150,000 mg/L in TDS and have Ba:Eu ratios in excess of 380,000.
Data Element Registry Services
U.S. Environmental Protection Agency — Data Element Registry Services (DERS) is a resource for information about value lists (aka code sets / pick lists), data dictionaries, data elements, and EPA data...
Thermodynamic stability of radioactivity standard solutions
International Nuclear Information System (INIS)
Iroulard, M.G.
2007-04-01
The basic requirement when preparing radioactivity standard solutions is to guarantee the concentration of a radionuclide or a radioelement, expressed in the form of activity concentration (Ac = A/m (Bq/g), with A: activity and m: mass of solution). Knowledge of the law of radioactive decay and the half-life of a radionuclide or radioelement makes it possible to determine the activity concentration at any time, and this must be confirmed subsequently by measurement. Furthermore, when radioactivity standard solutions are prepared, it is necessary to establish optimal conditions of thermodynamic stability of the standard solutions. Radioactivity standard solutions are prepared by metrology laboratories from original solutions obtained from a range of suppliers. These radioactivity standard solutions must enable preparation of liquid and/or solid radioactivity standard sources of which measurement by different methods can determine, at a given instant, the activity concentration of the radionuclide or radioelement present in the solution. There are a number of constraints associated with the preparation of such sources. Here only those that relate to the physical and chemical properties of the standard solution are considered, and therefore need to be taken into account when preparing a radioactivity standard solution. These issues are considered in this document in accordance with the following plan: - A first part devoted to the chemical properties of the solutions: - the solubilization media: ultra-pure water and acid media, - the carriers: concentration, oxidation state of the radioactive element and the carrier element. - A second part describing the methodology of the preparation, packaging and storage of standard solutions: - glass ampoules: the structure of glasses, the mechanisms of their dissolution, the sorption phenomenon at the solid-solution interface, - quartz ampoules, - cleaning and packaging: cleaning solutions, internal surface coatings and
Thermodynamic stability of radioactivity standard solutions
Energy Technology Data Exchange (ETDEWEB)
Iroulard, M.G
2007-04-15
The basic requirement when preparing radioactivity standard solutions is to guarantee the concentration of a radionuclide or a radioelement, expressed in the form of activity concentration (Ac = A/m (Bq/g), with A: activity and m: mass of solution). Knowledge of the law of radioactive decay and the half-life of a radionuclide or radioelement makes it possible to determine the activity concentration at any time, and this must be confirmed subsequently by measurement. Furthermore, when radioactivity standard solutions are prepared, it is necessary to establish optimal conditions of thermodynamic stability of the standard solutions. Radioactivity standard solutions are prepared by metrology laboratories from original solutions obtained from a range of suppliers. These radioactivity standard solutions must enable preparation of liquid and/or solid radioactivity standard sources of which measurement by different methods can determine, at a given instant, the activity concentration of the radionuclide or radioelement present in the solution. There are a number of constraints associated with the preparation of such sources. Here only those that relate to the physical and chemical properties of the standard solution are considered, and therefore need to be taken into account when preparing a radioactivity standard solution. These issues are considered in this document in accordance with the following plan: - A first part devoted to the chemical properties of the solutions: - the solubilization media: ultra-pure water and acid media, - the carriers: concentration, oxidation state of the radioactive element and the carrier element. - A second part describing the methodology of the preparation, packaging and storage of standard solutions: - glass ampoules: the structure of glasses, the mechanisms of their dissolution, the sorption phenomenon at the solid-solution interface, - quartz ampoules, - cleaning and packaging: cleaning solutions, internal surface coatings and
Transuranic element behavior in soils and plants
International Nuclear Information System (INIS)
Wildung, R.E.
1982-01-01
The principal objective of this study is to define soil, plant, and foliar interaction processes that influence the availability of transuranic elements to agricultural plants and animals as a basis for improved modeling and dose-assessment. Major areas of emphasis are: (1) soil and soil-microbial processes that influence the concentration and form of transuranic elements in soil solutions and availability to the plant root with time; (2) deposition and plant interception of airborne submicronic particles containing transuranic elements and their susceptibility to leaching; (3) plant processes that influence transport across plant root membrane and foliar surfaces, as well as the form and sites of deposition of transuranic elements in mature plants; and (4) the integrated effect of soil and plant processes on transuranic element availability to, and form in, animals that consume plants
International Nuclear Information System (INIS)
Lee, Byeong Hae
1992-02-01
This book gives descriptions of basic finite element method, which includes basic finite element method and data, black box, writing of data, definition of VECTOR, definition of matrix, matrix and multiplication of matrix, addition of matrix, and unit matrix, conception of hardness matrix like spring power and displacement, governed equation of an elastic body, finite element method, Fortran method and programming such as composition of computer, order of programming and data card and Fortran card, finite element program and application of nonelastic problem.
Power Series Solution to the Pendulum Equation
Benacka, Jan
2009-01-01
This note gives a power series solution to the pendulum equation that enables to investigate the system in an analytical way only, i.e. to avoid numeric methods. A method of determining the number of the terms for getting a required relative error is presented that uses bigger and lesser geometric series. The solution is suitable for modelling the…
Radiolabelled cellular blood elements
International Nuclear Information System (INIS)
Sinzinger, H.
1990-01-01
This book reports on radiolabelled cellular blood elements, covering new advances made during the past several years, in particular the use of Tc-99 as a tracer for blood elements. Coverage extends to several radiolabelled monoclonal antibodies that are specific for blood components and may label blood elements in vivo
Directory of Open Access Journals (Sweden)
Camilo Méndez
2014-12-01
Full Text Available Rare (Earth Elements is a cycle of works for solo piano. The cycle was inspired by James Dillon’s Book of Elements (Vol. I-V. The complete cycle will consist of 14 pieces; one for each selected rare (earth element. The chosen elements are Neodymium, Erbium, Tellurium, Hafnium, Tantalum, Technetium, Indium, Dysprosium, Lanthanium, Cerium, Europium, Terbium, Yttrium and Darmstadtium. These elements were selected due to their special atomic properties that in many cases make them extremely valuable for the development of new technologies, and also because of their scarcity. To date, only 4 works have been completed Yttrium, Technetium, Indium and Tellurium.
International Nuclear Information System (INIS)
Wachspress, E.
2009-01-01
Triangles and rectangles are the ubiquitous elements in finite element studies. Only these elements admit polynomial basis functions. Rational functions provide a basis for elements having any number of straight and curved sides. Numerical complexities initially associated with rational bases precluded extensive use. Recent analysis has reduced these difficulties and programs have been written to illustrate effectiveness. Although incorporation in major finite element software requires considerable effort, there are advantages in some applications which warrant implementation. An outline of the basic theory and of recent innovations is presented here. (authors)
International Nuclear Information System (INIS)
Seaborg, G.T.; Loveland, W.D.
1990-01-01
This book is the 12th volume in a series on transuranium elements. Varied techniques for production of these elements, the methods used in the identification, and the exquisitely refined microchemical techniques required to deal wth samples sometimes involving only a few atoms are described in detail. The chapter on synthesis of the new elements is liberally laced with reminiscences of the proud progenitors as well as the criteria for the discovery of a new chemical element. The authors lament that the superheavy elements (elements in the region of atomic number 114) still elude detection even though their creation should be possible, and some, at least, should survive long enough to be detected. One chapter in the book is devoted to practical applictions of uranium, and the transuranic elements
Performance Modelling of Timber Facade Elements
Surmeli-Anac, A.N.
2013-01-01
Windows and doors are essential elements of buildings. These seemingly simple components have become increasingly complex over the last decades. They have to fulfil an increased number of functions which ask for contradictory solutions and need to comply with more and more severe requirements.
Simultaneous Multi-Element Electrothermal Atomic Absorption ...
African Journals Online (AJOL)
width of transmittance profile 120 pm, a linear CCD array attached to a PC and a tube atomizer furnished with a carbon fibre collector. In the experiments simultaneous determination of 18 elements was performed in the mixed solutions at the mg ...
International Nuclear Information System (INIS)
Bailey, Teresa S.; Warsa, James S.; Chang, Jae H.; Adams, Marvin L.
2011-01-01
We present a new spatial discretization of the discrete-ordinates transport equation in two dimensional Cartesian (X-Y) geometry for arbitrary polygonal meshes. The discretization is a discontinuous finite element method (DFEM) that utilizes piecewise bi-linear (PWBL) basis functions, which are formally introduced in this paper. We also present a series of numerical results on quadrilateral and polygonal grids and compare these results to a variety of other spatial discretization that have been shown to be successful on these grid types. Finally, we note that the properties of the PWBL basis functions are such that the leading-order piecewise bi-linear discontinuous finite element (PWBLD) solution will satisfy a reasonably accurate diffusion discretization in the thick diffusion limit, making the PWBLD method a viable candidate for many different classes of transport problems. (author)
International Nuclear Information System (INIS)
Bailey, T.S.; Chang, J.H.; Warsa, J.S.; Adams, M.L.
2010-01-01
We present a new spatial discretization of the discrete-ordinates transport equation in two-dimensional Cartesian (X-Y) geometry for arbitrary polygonal meshes. The discretization is a discontinuous finite element method (DFEM) that utilizes piecewise bi-linear (PWBL) basis functions, which are formally introduced in this paper. We also present a series of numerical results on quadrilateral and polygonal grids and compare these results to a variety of other spatial discretizations that have been shown to be successful on these grid types. Finally, we note that the properties of the PWBL basis functions are such that the leading-order piecewise bi-linear discontinuous finite element (PWBLD) solution will satisfy a reasonably accurate diffusion discretization in the thick diffusion limit, making the PWBLD method a viable candidate for many different classes of transport problems.
Energy Technology Data Exchange (ETDEWEB)
Bailey, T S; Chang, J H; Warsa, J S; Adams, M L
2010-12-22
We present a new spatial discretization of the discrete-ordinates transport equation in two-dimensional Cartesian (X-Y) geometry for arbitrary polygonal meshes. The discretization is a discontinuous finite element method (DFEM) that utilizes piecewise bi-linear (PWBL) basis functions, which are formally introduced in this paper. We also present a series of numerical results on quadrilateral and polygonal grids and compare these results to a variety of other spatial discretizations that have been shown to be successful on these grid types. Finally, we note that the properties of the PWBL basis functions are such that the leading-order piecewise bi-linear discontinuous finite element (PWBLD) solution will satisfy a reasonably accurate diffusion discretization in the thick diffusion limit, making the PWBLD method a viable candidate for many different classes of transport problems.
International Symposium on Boundary Element Methods : Advances in Solid and Fluid Mechanics
Tseng, Kadin
1990-01-01
The Boundary Element Method (BEM) has become established as an effective tool for the solutions of problems in engineering science. The salient features of the BEM have been well documented in the open literature and therefore will not be elaborated here. The BEM research has progressed rapidly, especially in the past decade and continues to evolve worldwide. This Symposium was organized to provide an international forum for presentation of current research in BEM for linear and nonlinear problems in solid and fluid mechanics and related areas. To this end, papers on the following topics were included: rotary wing aerodynamics, unsteady aerodynamics, design and optimization, elasticity, elasto dynamics and elastoplasticity, fracture mechanics, acoustics, diffusion and wave motion, thermal analysis, mathematical aspects and boundary/finite element coupled methods. A special session was devoted to parallel/vector supercomputing with emphasis on mas sive parallelism. This Symposium was sponsored by United ...
Transuranium element recovering method for spent nuclear fuel
International Nuclear Information System (INIS)
Todokoro, Akio; Kihara, Yoshiyuki; Okada, Hisashi
1998-01-01
Spent fuels are dissolved in nitric acid, the obtained dissolution liquid is oxidized by electrolysis, and nitric acid of transuranium elements are precipitated together with nitric acid of uranium elements from the dissolution solution and recovered. Namely, the transuranium elements are oxidized to an atomic value level at which nitric acid can be precipitated by an oxidizing catalyst, and cooled to precipitate nitric acid of transuranium elements together with nitric acid of transuranium elements, accordingly, it is not necessary to use a solvent which has been used so far upon recovering transuranium elements. Since no solvent waste is generated, a recovery method taking the circumstance into consideration can be provided. Further, nitric acid of uranium elements and nitric acid of transuranium elements precipitated and recovered together are dissolved in nitric acid again, cooled and only uranium elements are precipitated selectively, and recovered by filtration. The amount of wastes can be reduced to thereby enabling to mitigate control for processing. (N.H.)
Boundary element method for modelling creep behaviour
International Nuclear Information System (INIS)
Zarina Masood; Shah Nor Basri; Abdel Majid Hamouda; Prithvi Raj Arora
2002-01-01
A two dimensional initial strain direct boundary element method is proposed to numerically model the creep behaviour. The boundary of the body is discretized into quadratic element and the domain into quadratic quadrilaterals. The variables are also assumed to have a quadratic variation over the elements. The boundary integral equation is solved for each boundary node and assembled into a matrix. This matrix is solved by Gauss elimination with partial pivoting to obtain the variables on the boundary and in the interior. Due to the time-dependent nature of creep, the solution has to be derived over increments of time. Automatic time incrementation technique and backward Euler method for updating the variables are implemented to assure stability and accuracy of results. A flowchart of the solution strategy is also presented. (Author)
Solution of a Complex Least Squares Problem with Constrained Phase.
Bydder, Mark
2010-12-30
The least squares solution of a complex linear equation is in general a complex vector with independent real and imaginary parts. In certain applications in magnetic resonance imaging, a solution is desired such that each element has the same phase. A direct method for obtaining the least squares solution to the phase constrained problem is described.
Particle Modelling with the Discrete Element Method: A success story of PARDEM
Ooi, Jin Y.; Magnanimo, Vanessa; Sun, J.; Luding, Stefan
2016-01-01
Bulk handling, transport and processing of particulate materials such as powders and granules are integral to a wide range of industrial processes in many fields [1] and [3] or natural, geophysical phenomena and hazards like landslides [3]. Particulate systems are difficult to handle and display
Chemical analysis of rare earth elements
International Nuclear Information System (INIS)
Tsukahara, Ryoichi; Sakoh, Takefumi; Nagai, Iwao
1994-01-01
Recently attention has been paid to ICP-AES or ICP-MS, and the reports on the analysis of rare earth elements by utilizing these methods continue to increase. These reports have become to take about 30% of the reports on rare earth analysis, and this is because these methods are highly sensitive to rare earth elements, and also these methods have spread widely. In ICP-AES and ICP-MS, mostly solution samples are measured, therefore, solids must be made into solution. At the time of quantitatively determining the rare earth elements of low concentration, separation and concentration are necessary. Referring to the literatures reported partially in 1990 and from 1991 to 1993, the progress of ICP-AES and ICP-MS is reported. Rare earth oxides and the alloys containing rare earth elements are easily decomposed with acids, but the decomposition of rocks is difficult, and its method is discussed. The separation of the rare earth elements from others in geochemical samples, cation exchange process is frequently utilized. Also solvent extraction process has been studied. For the separation of rare earth elements mutually, chromatography is used. The spectral interference in spectral analysis was studied. The comparison of these methods with other methods is reported. (K.I)
Chemistry gains a new element: Z=106
International Nuclear Information System (INIS)
Gaeggeler, H.W.; Eichler, B.; Tuerler, A.
1997-01-01
Even though 112 chemical elements are presently known, for elements with atomic numbers above 105 only nuclear decay properties have been investigated so far. Such data allow to proof the existence of a given nuclide, but they do not yield any information with respect to the position of a chemical element in the Periodic Table. We have performed ever first chemical investigations of element 106. According to the Periodic Table element 106 should be a member of group 6, having similar chemical properties as W, Mo and Cr. Two different techniques were applied to separate and identify element 106: a liquid chromatography system (ARCA = Automated Rapid Chemistry Apparatus) and a continuous isothermal chromatography device (OLGA = On-Line Gaschemistry Apparatus). With ARCA about 5'000 separations on small cation exchange columns (Aminex A6) with a 0.1 M HNO 3 /5.10 -4 M Hf solution were performed and with OLGA the gas adsorption behaviour of oxychlorides on quartz columns using Cl 2 /SOCl 2 /O 2 as reactive gas were studied. On the basis of only ten detected atoms, it was possible to proof that element 106 forms complexes which are eluted at positions similar to those of Mo and W. In addition, in the gas phase element 106 forms oxychlorides of lower volatility compared to those of Mo and W. (author) 1 ref
Whiteley, J. P.
2017-10-01
Large, incompressible elastic deformations are governed by a system of nonlinear partial differential equations. The finite element discretisation of these partial differential equations yields a system of nonlinear algebraic equations that are usually solved using Newton's method. On each iteration of Newton's method, a linear system must be solved. We exploit the structure of the Jacobian matrix to propose a preconditioner, comprising two steps. The first step is the solution of a relatively small, symmetric, positive definite linear system using the preconditioned conjugate gradient method. This is followed by a small number of multigrid V-cycles for a larger linear system. Through the use of exemplar elastic deformations, the preconditioner is demonstrated to facilitate the iterative solution of the linear systems arising. The number of GMRES iterations required has only a very weak dependence on the number of degrees of freedom of the linear systems.
Inorganic elements in sugar samples
Energy Technology Data Exchange (ETDEWEB)
Salles, Paulo M.B. de; Campos, Tarcisio P.R. de, E-mail: pauladesalles@yahoo.com.br, E-mail: tprcampos@pq.cnpq.br [Universidade Federal de Minas Gerais (DEN/UFMG), Belo Horizonte, MG (Brazil). Departamento de Engenharia Nuclear; Menezes, Maria Angela de B.C., E-mail: menezes@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)
2013-07-01
Sugar is considered a safe food ingredient; however, it can be contaminated by organic elements since its planting until its production process. Thus, this study aims at checking the presence of inorganic elements in samples of crystal, refined and brown sugar available for consumption in Brazil. The applied technique was neutron activation analysis, the k{sub 0} method, using the TRIGA MARK - IPR-R1 reactor located at CDTN/CNEN, in Belo Horizonte. It was identified the presence of elements such as, Au, Br, Co, Cr, Hf, K, Na, Sb, Sc and Zn in the samples of crystal/refined sugar and the presence of As, Au, Br, Ca, Co, Cr, Cs, Fe, Hf, K, Na, Sb, Sc, Sm, Sr, Th and Zn in the brown sugar samples. The applied technique was appropriate to this study because it was not necessary to put the samples in solution, essential condition in order to apply other techniques, avoiding contaminations and sample losses, besides allowing a multi elementary detection in different sugar samples. (author)
Inorganic elements in sugar samples
International Nuclear Information System (INIS)
Salles, Paulo M.B. de; Campos, Tarcisio P.R. de
2013-01-01
Sugar is considered a safe food ingredient; however, it can be contaminated by organic elements since its planting until its production process. Thus, this study aims at checking the presence of inorganic elements in samples of crystal, refined and brown sugar available for consumption in Brazil. The applied technique was neutron activation analysis, the k 0 method, using the TRIGA MARK - IPR-R1 reactor located at CDTN/CNEN, in Belo Horizonte. It was identified the presence of elements such as, Au, Br, Co, Cr, Hf, K, Na, Sb, Sc and Zn in the samples of crystal/refined sugar and the presence of As, Au, Br, Ca, Co, Cr, Cs, Fe, Hf, K, Na, Sb, Sc, Sm, Sr, Th and Zn in the brown sugar samples. The applied technique was appropriate to this study because it was not necessary to put the samples in solution, essential condition in order to apply other techniques, avoiding contaminations and sample losses, besides allowing a multi elementary detection in different sugar samples. (author)
DEFF Research Database (Denmark)
Kragh, Helge
2009-01-01
of the nineteenth century. In the modest form of a yellow spectral line known as D3, 'helium' was sometimes supposed to exist in the Sun's atmosphere, an idea which is traditionally ascribed to J. Norman Lockyer. Did Lockyer discover helium as a solar element? How was the suggestion received by chemists, physicists...... and astronomers in the period until the spring of 1895, when William Ramsay serendipitously found the gas in uranium minerals? The hypothetical element helium was fairly well known, yet Ramsay's discovery owed little or nothing to Lockyer's solar element. Indeed, for a brief while it was thought that the two...... elements might be different. The complex story of how helium became established as both a solar and terrestrial element involves precise observations as well as airy speculations. It is a story that is unique among the discovery histories of the chemical elements....
Energy Technology Data Exchange (ETDEWEB)
Hoffman, D.C.
1990-05-01
Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered.
International Nuclear Information System (INIS)
Hoffman, D.C.
1990-05-01
Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered
Klijn, F.; Slikker, M.; Tijs, S.H.
2000-01-01
In this note we introduce an egalitarian solution, called the dual egalitarian solution, that is the natural counterpart of the egalitarian solution of Dutta and Ray (1989).We prove, among others, that for a convex game the egalitarian solution coincides with the dual egalitarian solution for its
Finite element model to study calcium distribution in oocytes ...
African Journals Online (AJOL)
Parvaiz Ahmad Naik
2015-03-20
Mar 20, 2015 ... Department of Mathematics, Maulana Azad National Institute of Technology, Bhopal 462051 ... finite element method has been employed to obtain the solution. ..... Nelson MT, Cheng H, Rubart M. Relaxation of arterial smooth.
Highly accurate symplectic element based on two variational principles
Qing, Guanghui; Tian, Jia
2018-02-01
For the stability requirement of numerical resultants, the mathematical theory of classical mixed methods are relatively complex. However, generalized mixed methods are automatically stable, and their building process is simple and straightforward. In this paper, based on the seminal idea of the generalized mixed methods, a simple, stable, and highly accurate 8-node noncompatible symplectic element (NCSE8) was developed by the combination of the modified Hellinger-Reissner mixed variational principle and the minimum energy principle. To ensure the accuracy of in-plane stress results, a simultaneous equation approach was also suggested. Numerical experimentation shows that the accuracy of stress results of NCSE8 are nearly the same as that of displacement methods, and they are in good agreement with the exact solutions when the mesh is relatively fine. NCSE8 has advantages of the clearing concept, easy calculation by a finite element computer program, higher accuracy and wide applicability for various linear elasticity compressible and nearly incompressible material problems. It is possible that NCSE8 becomes even more advantageous for the fracture problems due to its better accuracy of stresses.
International Nuclear Information System (INIS)
Arya, S.P; s.
1978-01-01
A nuclear fuel element loading system is described which conveys a plurality of fuel rods to longitudinal passages in fuel elements. Conveyor means successively position the fuel rods above the longitudinal passages in axial alignment therewith and adapter means guide the fuel rods from the conveyor means into the longitudinal passages. The fuel elements are vibrated to cause the fuel rods to fall into the longitudinal passages through the adapter means
International Nuclear Information System (INIS)
Vogel, J.S.; McAninch, J.; Freeman, S.
1996-08-01
AMS (Accelerator Mass Spectrometry) provides high detection sensitivity for isotopes whose half-lives are between 10 years and 100 million years. 14 C is the most developed of such isotopes and is used in tracing natural and anthropogenic organic compounds in the Earth's biosphere. Thirty-three elements in the main periodic table and 17 lanthanides or actinides have long lived isotopes, providing potential tracers for research in elemental biochemistry. Overlap of biologically interesting heavy elements and possible AMS tracers is discussed
Analogs for transuranic elements
International Nuclear Information System (INIS)
Weimer, W.C.; Laul, J.C.; Kutt, J.C.
1981-01-01
A combined theoretical and experimental approach is being used to estimate the long-term environmental and biogeochemical behaviors of selected transuranic elements. The objective of this research is to estimate the effect that long-term (hundreds of years) environmental weathering has on the behavior of the transuranic elements americium and curium. This is achieved by investigating the actual behavior of naturally occurring rare earth elements, especially neodymium, that serve as transuranic analogs. Determination of the analog element behavior provides data that can be used to estimate the ultimate availability to man of transuranic materials released into the environment
Chemistry of superheavy elements
International Nuclear Information System (INIS)
Schaedel, M.
2012-01-01
The chemistry of superheavy elements - or transactinides from their position in the Periodic Table - is summarized. After giving an overview over historical developments, nuclear aspects about synthesis of neutron-rich isotopes of these elements, produced in hot-fusion reactions, and their nuclear decay properties are briefly mentioned. Specific requirements to cope with the one-atom-at-a-time situation in automated chemical separations and recent developments in aqueous-phase and gas-phase chemistry are presented. Exciting, current developments, first applications, and future prospects of chemical separations behind physical recoil separators ('pre-separator') are discussed in detail. The status of our current knowledge about the chemistry of rutherfordium (Rf, element 104), dubnium (Db, element 105), seaborgium (Sg, element 106), bohrium (Bh, element 107), hassium (Hs, element 108), copernicium (Cn, element 112), and element 114 is discussed from an experimental point of view. Recent results are emphasized and compared with empirical extrapolations and with fully-relativistic theoretical calculations, especially also under the aspect of the architecture of the Periodic Table. (orig.)
International Nuclear Information System (INIS)
Ma Songhua; Fang Jianping; Zheng Chunlong
2009-01-01
By means of an extended mapping method and a variable separation method, a series of solitary wave solutions, periodic wave solutions and variable separation solutions to the (2 + 1)-dimensional breaking soliton system is derived.
Analytical solutions to matrix diffusion problems
Energy Technology Data Exchange (ETDEWEB)
Kekäläinen, Pekka, E-mail: pekka.kekalainen@helsinki.fi [Laboratory of Radiochemistry, Department of Chemistry, P.O. Box 55, FIN-00014 University of Helsinki (Finland)
2014-10-06
We report an analytical method to solve in a few cases of practical interest the equations which have traditionally been proposed for the matrix diffusion problem. In matrix diffusion, elements dissolved in ground water can penetrate the porous rock surronuding the advective flow paths. In the context of radioactive waste repositories this phenomenon provides a mechanism by which the area of rock surface in contact with advecting elements is greatly enhanced, and can thus be an important delay mechanism. The cases solved are relevant for laboratory as well for in situ experiments. Solutions are given as integral representations well suited for easy numerical solution.
INTERCULTURAL MISUNDERSTANDINGS: CAUSES AND SOLUTIONS
Directory of Open Access Journals (Sweden)
Майкл Б Хиннер
2017-12-01
Full Text Available Intercultural misunderstandings involve a number of complex causes which can easily escalate into conflicts. Since conflicts are also complex, it is not easy to find solutions because there is no one solution for all problems. Systems Theory, transdisciplinarity, and the social ecological model take a holistic approach in investigating complex phenomena. They permit the creation of a theoretical framework based on previous empirical research and theories across scientific disciplines to identify the relevant elements of complex phenomena and to understand the interrelationship of these elements. Intercultural misunderstandings and conflicts are very complex phenomena because they include culture, perception, identity, ethnocentrism, relationships, trust building and conflict management as well as intercultural commu-nication competence which entails cognition, metacognition, and social metacognition. Since most em-pirical studies focus on isolated, individual elements in specific contexts, this article describes the theoretical framework of how the various findings and theories developed in different scientific disciplines can be used to form a cohesive framework to help circumvent intercultural misunderstandings and conflicts. In so doing, it follows the general principles of Systems Theory, transdisciplinarity, and the social ecological model.
Accounting for straight parts effects on elbow's flexibilities in a beam type finite element program
International Nuclear Information System (INIS)
Millard, A.
1983-01-01
An extension of Von Karman's theory is applied to the calculations of the flexibility factor of a pipe bend terminated by a straight part or a flange. This analysis is restricted to the linear elastic deformation behaviour under in plane bending. Analytical solutions are given for the propagation of ovalization in the elbow and in the straight part. Considering the response of the piping structures, we note that the ovalization of the piping systems are reduced significantly when the straight parts or flanges effects are included. This results are presented in terms of global as well local flexibility factors. They have been compared to numerical results obtained by shell type finite elements method. A complete piping system is analyzed, for economical reasons, with a beam type approach. Also, we show how it is possible to take into account an elbow's flexibilities the straight parts effects by means of flexibilities factors introduced in a beam type elements. We have implemented this method in the computer program TEDEL. In some specific geometrical features, we compare solutions using shell type elements and our formulation. (orig.)
Accounting for straight parts effects on elbow's flexibilities in a beam type finite element program
International Nuclear Information System (INIS)
Millard, A.; Vaghi, H.; Ricard, A.
1983-08-01
An extension of Von Karman's theory is applied to the calculations of the flexibility factor of a pipe bend terminated by a straight part or a flange. This analysis is restricted to the linear elastic deformation behaviour under in plane bending. Analytical solutions are given for the propagation of ovalization in the elbow and in the straight part. Considering the response of the piping structures, we note that the ovalization of the piping systems are reduced significantly when the straight parts or flanges effects are included. The results are presented in terms of global as well local flexibility factors. They have been compared to numerical results obtained by shell type finite element method. A complete piping system is analyzed, for economical reasons, with a beam type approach. Also, we show how it is possible to take into account on elbow's flexibilities the straight parts effects by means of flexibilities factors introduced in a beam type element. We have implemented this method in the computer program TEDEL. In some specific geometrical features, we compare solutions using shell type elements and our formulation
Computation of Asteroid Proper Elements: Recent Advances
Knežević, Z.
2017-12-01
The recent advances in computation of asteroid proper elements are briefly reviewed. Although not representing real breakthroughs in computation and stability assessment of proper elements, these advances can still be considered as important improvements offering solutions to some practical problems encountered in the past. The problem of getting unrealistic values of perihelion frequency for very low eccentricity orbits is solved by computing frequencies using the frequency-modified Fourier transform. The synthetic resonant proper elements adjusted to a given secular resonance helped to prove the existence of Astraea asteroid family. The preliminary assessment of stability with time of proper elements computed by means of the analytical theory provides a good indication of their poorer performance with respect to their synthetic counterparts, and advocates in favor of ceasing their regular maintenance; the final decision should, however, be taken on the basis of more comprehensive and reliable direct estimate of their individual and sample average deviations from constancy.
Vonk, J.A.; Smulders, Fee O.H.; Christianen, Marjolijn J.A.; Govers, Laura L.
2017-01-01
Knowledge on the role of seagrass leaf elements and in particular micronutrients and their ranges is limited. We present a global database, consisting of 1126 unique leaf values for ten elements, obtained from literature and unpublished data, spanning 25 different seagrass species from 28 countries.
International Nuclear Information System (INIS)
Ghiorso, A.
1975-09-01
The work done with element 106 is reviewed, and a new experiment which bears on the properties of the isotope of mass 260 with atomic number 104 is discussed. It is noted that in the case of element 106 a link is demonstrated to the granddaughter as well as the daughter
Cady, Susan
2005-01-01
One of the first tasks students learn in chemistry is to pronounce and spell the names of elements and learn their corresponding chemical symbols. Repetitive oral recitation is commonly used to learn this information, but games and puzzles can make this task creative, variable, and fun. Elemental Food for Thought is a puzzlelike activity that…
International Nuclear Information System (INIS)
Mogard, J.H.
1977-01-01
A nuclear fuel element is disclosed for use in power producing nuclear reactors, comprising a plurality of axially aligned ceramic cylindrical fuel bodies of the sintered type, and a cladding tube of metal or metal alloys, wherein said cladding tube on its cylindrical inner surface is provided with a plurality of slightly protruding spacing elements distributed over said inner surface
Proceedings of transuranium elements
International Nuclear Information System (INIS)
Anon.
1992-01-01
The identification of the first synthetic elements was established by chemical evidence. Conclusive proof of the synthesis of the first artificial element, technetium, was published in 1937 by Perrier and Segre. An essential aspect of their achievement was the prediction of the chemical properties of element 43, which had been missing from the periodic table and which was expected to have properties similar to those of manganese and rhenium. The discovery of other artificial elements, astatine and francium, was facilitated in 1939-1940 by the prediction of their chemical properties. A little more than 50 years ago, in the spring of 1940, Edwin McMillan and Philip Abelson synthesized element 93, neptunium, and confirmed its uniqueness by chemical means. On August 30, 1940, Glenn Seaborg, Arthur Wahl, and the late Joseph Kennedy began their neutron irradiations of uranium nitrate hexahydrate. A few months later they synthesized element 94, later named plutonium, by observing the alpha particles emitted from uranium oxide targets that had been bombarded with deuterons. Shortly thereafter they proved that is was the second transuranium element by establishing its unique oxidation-reduction behavior. The symposium honored the scientists and engineers whose vision and dedication led to the discovery of the transuranium elements and to the understanding of the influence of 5f electrons on their electronic structure and bonding. This volume represents a record of papers presented at the symposium
Application of Mass Lumped Higher Order Finite Elements
International Nuclear Information System (INIS)
J. Chen, H.R. Strauss, S.C. Jardin, W. Park, L.E. Sugiyama, G. Fu, J. Breslau
2005-01-01
There are many interesting phenomena in extended-MHD such as anisotropic transport, mhd, 2-fluid effects stellarator and hot particles. Any one of them challenges numerical analysts, and researchers are seeking for higher order methods, such as higher order finite difference, higher order finite elements and hp/spectral elements. It is true that these methods give more accurate solution than their linear counterparts. However, numerically they are prohibitively expensive. Here we give a successful solution of this conflict by applying mass lumped higher order finite elements. This type of elements not only keep second/third order accuracy but also scale closely to linear elements by doing mass lumping. This is especially true for second order lump elements. Full M3D and anisotropic transport models are studied
Comparison of trace element contamination levels (Cu, Zn, Fe, Cd ...
African Journals Online (AJOL)
SERVER
2008-03-18
Mar 18, 2008 ... Chemical analysis of the trace elements in the soft tissues. The trace elements of interest (Cu, Zn, Fe, Pb, Cd) were then determined in the digested solutions, using Thermoelemental type. M6 brand of an atomic absorption Spectrometer equipped with a flame operated atomisation system and a deuterium ...
Modelling Convergence of Finite Element Analysis of Cantilever Beam
African Journals Online (AJOL)
Convergence studies are carried out by investigating the convergence of numerical results as the number of elements is increased. If convergence is not obtained, the engineer using the finite element method has absolutely no indication whether the results are indicative of a meaningful approximation to the correct solution ...
Rare earth elements materials production from apatite ores
International Nuclear Information System (INIS)
Anufrieva, A V; Buynovskiy, A S; Makaseev, Y N; Mazov, I N; Nefedov, R A; Sachkov, V I; Valkov, A V; Andrienko, O S; Stepanova, O B
2016-01-01
The paper deals with the study of processing apatite ores with nitric acid and extraction of the rare earth elements. The rare earth elements can be successfully separated and recovered by extraction from the nitrate- phosphate solution, being an tributyl phosphate as extraction agent. The developed scheme of the processing apatite concentrate provides obtaining rare earth concentrates with high qualitative characteristics. (paper)
High accuracy 3D electromagnetic finite element analysis
International Nuclear Information System (INIS)
Nelson, E.M.
1996-01-01
A high accuracy 3D electromagnetic finite element field solver employing quadratic hexahedral elements and quadratic mixed-order one-form basis functions will be described. The solver is based on an object-oriented C++ class library. Test cases demonstrate that frequency errors less than 10 ppm can be achieved using modest workstations, and that the solutions have no contamination from spurious modes. The role of differential geometry and geometrical physics in finite element analysis will also be discussed
High accuracy 3D electromagnetic finite element analysis
International Nuclear Information System (INIS)
Nelson, Eric M.
1997-01-01
A high accuracy 3D electromagnetic finite element field solver employing quadratic hexahedral elements and quadratic mixed-order one-form basis functions will be described. The solver is based on an object-oriented C++ class library. Test cases demonstrate that frequency errors less than 10 ppm can be achieved using modest workstations, and that the solutions have no contamination from spurious modes. The role of differential geometry and geometrical physics in finite element analysis will also be discussed
Elution behaviors of elements from the hair
International Nuclear Information System (INIS)
Akashi, Junko; Fukushima, Ichiro; Imahori, Akira
1981-01-01
The elution of the neutron activated elements out of hair soaked in some organic solvents and EDTA solution was studied. Soakage of the hair sample, which was washed with water and acetone in advance as IAEA's proposal, in ether and acetone for 30 minutes each resulted in no elution of Hg, Zn, Co and Se. Elution of Zn and Co from the powdered hair sample soaked in 0.1 M EDTA solution was rapid, while Zn did not elute out from the cut hair (2 -- 3 mm length) on the same condition. Hg, Se and Au were not eluted out by 0.1 M EDTA solution in the both case of cut hair and of powdered hair. Br was removed by 0.1 M EDTA solution from the cut hair and from the powdered hair with equal ease. (author)
Recovery of trans-plutonium elements; Recuperation des elements transplutoniens
Energy Technology Data Exchange (ETDEWEB)
Espie, J Y; Poncet, B; Simon, A [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires
1970-07-01
The object of this work is to study the recovery of americium and curium from the fission-product solution obtained from the processing of irradiated fuel elements made of natural metallic uranium alloyed with aluminium, iron and silicon; these elements have been subjected to an average irradiation of 4000 MW days/ton in a gas-graphite type reactor having a thermal power of 3.7 MW/ton of uranium. The process used consists of 3 extraction cycles and one americium-curium separation: - 1) extraction cycle in 40 per cent TBP: extraction of actinides and lanthanides; elimination of fission products; - 2) extraction cycle in 8 per cent D2EHPA: decontamination from the fission products, decontamination of actinides from lanthanides; - 3) extraction cycle in 40 per cent TBP: separation of the complexing agent and concentration of the actinides; - 4) americium-curium separation by precipitation. (authors) [French] Cette etude a pour objet, la recuperation de l'americium et du curium de la solution de produits de fission provenant du traitement de combustibles irradies a base d'uranium naturel metallique allie a l'aluminium, le fer, et le silicium, et ayant subi une irradiation moyenne de 4000 MWj/t dans une pile du type graphite-gaz, dont la puissance thermique est de 3.7 MW/t d'uranium. Le procede utilise comprend 3 cycles d'extraction et une separation americium-curium: - 1. cycle d'extraction dans le TBP a 40 pour cent: extraction des actinides et des lanthanides, elimination des produits de fission; - 2. cycle d'extraction dans le D2EHPA a 8 pour cent: decontamination en produits de fission, decontamination des actinides en lanthanides; - 3. cycle d'extraction dans le TBP a 40 pour cent: separation du complexant et concentration des actinides; - 4. separation americium-curium par precipitation. (auteurs)
Huang, Chih-Hsu; Lin, Chou-Ching K; Ju, Ming-Shaung
2015-02-01
Compared with the Monte Carlo method, the population density method is efficient for modeling collective dynamics of neuronal populations in human brain. In this method, a population density function describes the probabilistic distribution of states of all neurons in the population and it is governed by a hyperbolic partial differential equation. In the past, the problem was mainly solved by using the finite difference method. In a previous study, a continuous Galerkin finite element method was found better than the finite difference method for solving the hyperbolic partial differential equation; however, the population density function often has discontinuity and both methods suffer from a numerical stability problem. The goal of this study is to improve the numerical stability of the solution using discontinuous Galerkin finite element method. To test the performance of the new approach, interaction of a population of cortical pyramidal neurons and a population of thalamic neurons was simulated. The numerical results showed good agreement between results of discontinuous Galerkin finite element and Monte Carlo methods. The convergence and accuracy of the solutions are excellent. The numerical stability problem could be resolved using the discontinuous Galerkin finite element method which has total-variation-diminishing property. The efficient approach will be employed to simulate the electroencephalogram or dynamics of thalamocortical network which involves three populations, namely, thalamic reticular neurons, thalamocortical neurons and cortical pyramidal neurons. Copyright © 2014 Elsevier Ltd. All rights reserved.
Separation of transuranium elements and fission products from medium activity aqueous liquid wastes
International Nuclear Information System (INIS)
Gompper, K.; Kunze, S.; Eden, G.; Loesch, G.; Zemski, C.
1986-01-01
In the course of work performed between January 1981 and June 1985 on the separation of TRU elements and fission products three liquid alpha containing waste streams were treated: - medium level waste solutions, - waste solutions from the acid digestion of burnable alpha containing solid residues, - waste solutions from mixed oxide fuel element fabrication. The method of separation was initially developed and optimized with simulating substances. Subesequently it was tested with real waste solutions
Actinide elements in aquatic and terrestrial environments
International Nuclear Information System (INIS)
Bondietti, E.A.; Bogle, M.A.; Brantley, J.N.
1979-01-01
Progress is reported on the following research projects: water-sediment interactions of U, Pu, Am, and Cm; relative availability of actinide elements from abiotic to aquatic biota; comparative uptake of transuranic elements by biota bordering Pond 3513; metabolic reduction of 239 Np from Np(V) to Np(IV) in cotton rats; evaluation of hazards associated with transuranium releases to the biosphere; predicting Pu in bone; adsorption--solubility--complexation phenomena in actinide partitioning between sorbents and solution; comparative soil extraction data; and comparative plant uptake data
Saha's ionization equation for high Z elements
International Nuclear Information System (INIS)
Godwal, B.K.; Sikka, S.K.
1977-01-01
Saha's ionization equation has been solved for high Z elements with the aim of providing input for opacity calculations. Results are presented for two elements, tungsten and uranium. The ionization potentials have been evaluated using the simple Bhor's formula with suitable effective charges for ions. The reliability of the free electron density, ion concentrations, etc., obtained from the Saha's equation solutions has been checked by comparing the P and E computed from them with those given by the Thomas-Fermi-Dirac equation of state. The agreement between the two is good from temperatures above 0.2 keV. (author)
Lumped elements for RF and microwave circuits
Bahl, Inder
2003-01-01
Due to the unprecedented growth in wireless applications over the past decade, development of low-cost solutions for RF and microwave communication systems has become of great importance. This practical new book is the first comprehensive treatment of lumped elements, which are playing a critical role in the development of the circuits that make these cost-effective systems possible. The books offers you an in-depth understanding of the different types of RF and microwave circuit elements, including inductors, capacitors, resistors, transformers, via holes, airbridges, and crossovers. Support
Directory of Open Access Journals (Sweden)
Yichao Gao
2011-01-01
Full Text Available The dam-reservoir system is divided into the near field modeled by the finite element method, and the far field modeled by the excellent high-order doubly asymptotic open boundary (DAOB. Direct and partitioned coupled methods are developed for the analysis of dam-reservoir system. In the direct coupled method, a symmetric monolithic governing equation is formulated by incorporating the DAOB with the finite element equation and solved using the standard time-integration methods. In contrast, the near-field finite element equation and the far-field DAOB condition are separately solved in the partitioned coupled methodm, and coupling is achieved by applying the interaction force on the truncated boundary. To improve its numerical stability and accuracy, an iteration strategy is employed to obtain the solution of each step. Both coupled methods are implemented on the open-source finite element code OpenSees. Numerical examples are employed to demonstrate the performance of these two proposed methods.
Elements of algebraic coding systems
Cardoso da Rocha, Jr, Valdemar
2014-01-01
Elements of Algebraic Coding Systems is an introductory text to algebraic coding theory. In the first chapter, you'll gain inside knowledge of coding fundamentals, which is essential for a deeper understanding of state-of-the-art coding systems. This book is a quick reference for those who are unfamiliar with this topic, as well as for use with specific applications such as cryptography and communication. Linear error-correcting block codes through elementary principles span eleven chapters of the text. Cyclic codes, some finite field algebra, Goppa codes, algebraic decoding algorithms, and applications in public-key cryptography and secret-key cryptography are discussed, including problems and solutions at the end of each chapter. Three appendices cover the Gilbert bound and some related derivations, a derivation of the Mac- Williams' identities based on the probability of undetected error, and two important tools for algebraic decoding-namely, the finite field Fourier transform and the Euclidean algorithm f...
International Nuclear Information System (INIS)
Papoyan, V.V.
1989-01-01
A Kerr generalized solution for a stationary axially-symmetric gravitational field of rotating self-gravitational objects is given. For solving the problem Einstein equations and their combinations are used. The particular cases: internal and external Schwarzschild solutions are considered. The external solution of the stationary problem is a Kerr solution generalization. 3 refs
Energy Technology Data Exchange (ETDEWEB)
Hofmann, S. [GSI, Darmstadt (Germany)
1996-12-31
The new elements 110, 111, and 112 were synthesized and unambiguously identified in experiments at SHIP. Due to strong shell effects the dominant decay mode is not fission, but emission of alpha particles. Theoretical investigations predict that maximum shell effects should exist in nuclei near proton number 114 and neutron number 184. Measurements give hope that isotopes of element 114 close to the island of spherical Superheavy Elements could be produced by fusion reactions using {sup 118}Pb as target. systematic studies of the reaction cross-sections indicate that transfer of nucleons is the important process to initiate the fusion.
International Nuclear Information System (INIS)
Grossman, L.N.; Levin, H.A.
1975-01-01
A nuclear fuel element has disposed therein an alloy having the essential components of nickel, titanium and zirconium, and the alloy reacts with water, water vapor and reactive gases at reactor ambient temperatures. The alloy is disposed in the plenum of the fuel element in the form of particles in a hollow gas permeable container having a multiplicity of openings of size smallr than the size of the particles. The container is preferably held in the spring in the plenum of the fuel element. (E.C.B.)
International Nuclear Information System (INIS)
Michaud, Georges; Montmerle, Thierry
1977-01-01
This paper is dealing with the origin of the elements in the universe. The scheme of nucleosynthesis is kept to explain the stellar generation of helium, carbon, etc... from the initial hydrogen; but a nonlinear theory is then elaborated to account for the anomalous abundances which were observed. The chemical elements would diffuse throughout the outer layers of a star under the action of the opposite forces of gravitation and radiation. This theory, with completing the nucleosynthesis, would contribute to give a consistent scheme of the elemental origin and abundances [fr
International Nuclear Information System (INIS)
Noakes, J.E.; Culp, R.A.
1983-01-01
A radiochromic solution which is sensitive to small dosages of ionizing and ultraviolet radiation is described. It consists of a solution of a leucocyanide dye in a clear polar solvent with enough organic acid added to make the solution at least slightly acidic and responds to radiation by permanently changing color. Up to one half of the solution by weight can be replaced by a second solution of an aromatic solvent and an organic fluor. Another modification of the invention is a solution of a leucocyanide dye in a clear polar solvent having an aromatic group, an organic fluor, and enough organic acid to make the solution at least slightly acidic. (author)
Environmental mineralogy - Understanding element behavior in ecosystems
International Nuclear Information System (INIS)
Brown Jr, G.E.; Calas, G.
2011-01-01
Environmental Mineralogy has developed over the past decade in response to the recognition that minerals are linked in many important ways with the global ecosystem. Minerals are the main repositories of the chemical elements in Earth's crust and thus are the main sources of elements needed for the development of civilization, contaminant and pollutant elements that impact global and local ecosystems, and elements that are essential plant nutrients. These elements are released from minerals through natural processes, such as chemical weathering, and anthropogenic activities, such as mining and energy production, agriculture and industrial activities, and careless waste disposal. Minerals also play key roles in the biogeochemical cycling of the elements, sequestering elements and releasing them as the primary minerals in crustal rocks undergo various structural and compositional transformations in response to physical, chemical, and biological processes that produce secondary minerals and soils. These processes have resulted in the release of toxic elements such as arsenic in groundwater aquifers, which is having a major impact on the health of millions of people in South and Southeast Asia. The interfaces between mineral surfaces and aqueous solutions are the locations of most chemical reactions that control the composition of the natural environment, including the composition of natural waters. The nuclear fuel cycle, from uranium mining to the disposition of high-level nuclear waste, is also intimately related to minerals. A fundamental understanding of these processes requires molecular-scale information about minerals, their bulk structures and properties such as solubility, their surfaces, and their interactions with aqueous solutions, atmospheric and soil gases, natural organic matter, and biological organisms. Gaining this understanding is further complicated by the presence of natural, incidental, and manufactured nano-particles in the environment, which
Semi-analytic solution to planar Helmholtz equation
Directory of Open Access Journals (Sweden)
Tukač M.
2013-06-01
Full Text Available Acoustic solution of interior domains is of great interest. Solving acoustic pressure fields faster with lower computational requirements is demanded. A novel solution technique based on the analytic solution to the Helmholtz equation in rectangular domain is presented. This semi-analytic solution is compared with the finite element method, which is taken as the reference. Results show that presented method is as precise as the finite element method. As the semi-analytic method doesn’t require spatial discretization, it can be used for small and very large acoustic problems with the same computational costs.
Liquid scintillation solutions
International Nuclear Information System (INIS)
Long, E.C.
1976-01-01
The liquid scintillation solution described includes a mixture of: a liquid scintillation solvent, a primary scintillation solute, a secondary scintillation solute, a variety of appreciably different surfactants, and a dissolving and transparency agent. The dissolving and transparency agent is tetrahydrofuran, a cyclic ether. The scintillation solvent is toluene. The primary scintillation solute is PPO, and the secondary scintillation solute is dimethyl POPOP. The variety of appreciably different surfactants is composed of isooctylphenol-polyethoxyethanol and sodium dihexyl sulphosuccinate [fr
Representativeness elements of an hybrid reactor demonstrator
International Nuclear Information System (INIS)
Kerdraon, D.; Billebaud, A.; Brissot, R.; David, S.; Giorni, A.; Heuer, D.; Loiseaux, J.M.; Meplan, O.
2000-11-01
This document deals with the quantification of the minimum thermal power level for a demonstrator and the definition of the physical criteria which define the representative character of a demonstrator towards a power reactor. Solutions allowing to keep an acceptable flow in an industrial core, have also been studied. The document is divided in three parts: the representativeness elements, the considered solutions and the characterization of the neutrons flows at the interfaces and the dose rates at the outer surface of the vessel. (A.L.B.)
Thermohydraulic analysis in pipelines using the finite element method
International Nuclear Information System (INIS)
Costa, L.E.; Idelsohn, S.R.
1984-01-01
The Finite Element Method (FEM) is employed for the numerical solution of fluid flow problems with combined heat transfer mechanisms. Boussinesq approximations are used for the solution of the governing equations. The application of the FEM leads to a set of simultaneous nonlinear equations. The development of the method, for the solution of bidimensional and axisymmetric problems, is presented. Examples of fluid flow in pipes, including natural and forced convection, are solved with the proposed method and discussed in the paper. (Author) [pt
Bridge element deterioration rates.
2008-10-01
This report describes the development of bridge element deterioration rates using the NYSDOT : bridge inspection database using Markov chains and Weibull-based approaches. It is observed : that Weibull-based approach is more reliable for developing b...
International Nuclear Information System (INIS)
Anon.
1975-01-01
Methods of sample collection, sample storage, sample procedures and radioanalytical procedures for transuranic elements in marine environment are reviewed and recommended. Alpha spectrometry and scintillation techniques are used for measurement of isotopic content. Separation processes for samples are described
International Nuclear Information System (INIS)
Anon.
1976-01-01
Heavy element research activities in metallurgy and ceramics during 1976 at Lawrence Berkeley Laboratory are reviewed. Topics include: microstructure, properties and alloy design; ceramic alloy program; high resolution and high voltage electron microscopy; and powder metallurgy
International Nuclear Information System (INIS)
Hindle, E.D.
1981-01-01
An array of rods comprising zirconium alloy sheathed nuclear fuel pellets assembled to form a fuel element for a pressurised water reactor is claimed. The helium gas pressure within each rod differs substantially from that of its closest neighbours
International Nuclear Information System (INIS)
Hindle, E.D.
1984-01-01
The fuel elements for a pressurised water reactor comprise arrays of rods of zirconium alloy sheathed nuclear fuel pellets. The helium gas pressure within each rod differs substantially from that of its closest neighbours
Transposable elements in cancer.
Burns, Kathleen H
2017-07-01
Transposable elements give rise to interspersed repeats, sequences that comprise most of our genomes. These mobile DNAs have been historically underappreciated - both because they have been presumed to be unimportant, and because their high copy number and variability pose unique technical challenges. Neither impediment now seems steadfast. Interest in the human mobilome has never been greater, and methods enabling its study are maturing at a fast pace. This Review describes the activity of transposable elements in human cancers, particularly long interspersed element-1 (LINE-1). LINE-1 sequences are self-propagating, protein-coding retrotransposons, and their activity results in somatically acquired insertions in cancer genomes. Altered expression of transposable elements and animation of genomic LINE-1 sequences appear to be hallmarks of cancer, and can be responsible for driving mutations in tumorigenesis.
Divergent picornavirus IRES elements
DEFF Research Database (Denmark)
Belsham, Graham
2009-01-01
Internal ribosome entry site (IRES) elements were first identified about 20 years ago within the 5' untranslated region of picornavirus RNAs. They direct a cap-independent mechanism of translation initiation on the viral RNA. Within the picornavirus family it is now known that there are four...... classes of IRES element which vary in size (450-270nt), they also have different, complex, secondary structures and distinct requirements for cellular proteins to allow them to function. This review describes the features of each class of picornavirus IRES element but focuses on the characteristics...... of the most recently described group, initially identified within the porcine teschovirus-1 RNA, which has strong similarities to the IRES elements from within the genomes of hepatitis C virus and the pestiviruses which are members of the flavivirus family. The selection of the initiation codon...
ELEMENTS OF SAFETY IN PARAGLIDING
Directory of Open Access Journals (Sweden)
Janez Mekinc
2016-06-01
Full Text Available Paragliding is an opportunity for tourism development, depending on what position the sport has place in the local community, the restrictions for paragliders and the safety components of the region. The paper explores the phenomenon of paragliding and safety elements in the Upper Soča region, one of ten best paragliding sites in the world (Placestoseeinyourlifetime, 2015. The purpose of the research is to analyse the safety elements, the development and the risk of paragliding.The goals of the research are to propose solutions in order to improve the safety conditions for paragliding and to make suggestions on the further development of paragliding within the framework of tourism in the Upper Soča destination. According to the interviewees, paragliding is becoming safer from year to year. This is also supported with the ever-growing numbers of pilots, and on the other hand, the number of accidents that do not follow the same trend. The identified causes for the accidents are human errors or weather conditions. The statistical data confirmed the paragliding in the Upper Soča region, with its unique geographical location, has a positive impact on local tourism and its development. The results of the study are useful for paragliders, local tourism stakeholders, researchers of sport tourism, as well to municipalities in the Upper Soča region.
Novel porcine repetitive elements
Directory of Open Access Journals (Sweden)
Nonneman Dan J
2006-12-01
Full Text Available Abstract Background Repetitive elements comprise ~45% of mammalian genomes and are increasingly known to impact genomic function by contributing to the genomic architecture, by direct regulation of gene expression and by affecting genomic size, diversity and evolution. The ubiquity and increasingly understood importance of repetitive elements contribute to the need to identify and annotate them. We set out to identify previously uncharacterized repetitive DNA in the porcine genome. Once found, we characterized the prevalence of these repeats in other mammals. Results We discovered 27 repetitive elements in 220 BACs covering 1% of the porcine genome (Comparative Vertebrate Sequencing Initiative; CVSI. These repeats varied in length from 55 to 1059 nucleotides. To estimate copy numbers, we went to an independent source of data, the BAC-end sequences (Wellcome Trust Sanger Institute, covering approximately 15% of the porcine genome. Copy numbers in BAC-ends were less than one hundred for 6 repeat elements, between 100 and 1000 for 16 and between 1,000 and 10,000 for 5. Several of the repeat elements were found in the bovine genome and we have identified two with orthologous sites, indicating that these elements were present in their common ancestor. None of the repeat elements were found in primate, rodent or dog genomes. We were unable to identify any of the replication machinery common to active transposable elements in these newly identified repeats. Conclusion The presence of both orthologous and non-orthologous sites indicates that some sites existed prior to speciation and some were generated later. The identification of low to moderate copy number repetitive DNA that is specific to artiodactyls will be critical in the assembly of livestock genomes and studies of comparative genomics.
International Nuclear Information System (INIS)
Wieser, R.
1987-01-01
The spherical fuel elements are stored dry in cans. The cans themselves are stacked in parallel storage shafts, which are combined into a rectangular storage space. The storage space is made earthquake-proof by surrounding it with concrete. It consists of a ceiling assembled from several steel parts, which is connected to the floor by support elements. A cooling air ventilation station supplies the individual storage shaft and therefore the cans with cooling air via incoming and outgoing pipes. (DG) [de
Intrusion detection system elements
International Nuclear Information System (INIS)
Eaton, M.J.; Mangan, D.L.
1980-09-01
This report highlights elements required for an intrusion detection system and discusses problems which can be encountered in attempting to make the elements effective. Topics discussed include: sensors, both for exterior detection and interior detection; alarm assessment systems, with the discussion focused on video assessment; and alarm reporting systems, including alarm communication systems and dislay/console considerations. Guidance on careful planning and design of a new or to-be-improved system is presented
Structural elements design manual
Draycott, Trevor
2012-01-01
Gives clear explanations of the logical design sequence for structural elements. The Structural Engineer says: `The book explains, in simple terms, and with many examples, Code of Practice methods for sizing structural sections in timber, concrete,masonry and steel. It is the combination into one book of section sizing methods in each of these materials that makes this text so useful....Students will find this an essential support text to the Codes of Practice in their study of element sizing'.
Graybill, George
2007-01-01
Young scientists will be thrilled to explore the invisible world of atoms, molecules and elements. Our resource provides ready-to-use information and activities for remedial students using simplified language and vocabulary. Students will label each part of the atom, learn what compounds are, and explore the patterns in the periodic table of elements to find calcium (Ca), chlorine (Cl), and helium (He) through hands-on activities.
Solute redistribution studies in oxidised zirconium alloys
Energy Technology Data Exchange (ETDEWEB)
Khera, S K; Kale, G B; Gadiyar, H S [Bhabha Atomic Research Centre, Bombay (India). Metallurgy Div.
1977-01-01
Electron microprobe studies on solute distribution in oxide layers and in the regions near oxide metal interface have been carried out in the case of zircaloy-2 and zirconium binary alloys containing niobium, tin, iron, copper, chromium and nickel and oxidised in steam at 550 deg C. In the case of alloys having higher oxidation rates, the oxide of solute element was found to dissolve in ZrO/sub 2/ without any composition variation. However, for solute addition with limited solubility like Cr, Cu and Fe, solute enrichment at metal/oxide interface and depletion of the same matrix has been observed. The intensity profiles for nickel distribution were also found to be identical to Fe or Cr distribution. The mode of solute distribution has been discussed in relation to oxidation behaviour of these alloys.
International Nuclear Information System (INIS)
Penrose, R.T.; Thompson, J.R.
1976-01-01
A method of protecting the cladding of a nuclear fuel element from internal attack and a nuclear fuel element for use in the core of a nuclear reactor are disclosed. The nuclear fuel element has disposed therein an additive of a barium-containing material and the barium-containing material collects reactive gases through chemical reaction or adsorption at temperatures ranging from room temperature up to fuel element plenum temperatures. The additive is located in the plenum of the fuel element and preferably in the form of particles in a hollow container having a multiplicity of gas permeable openings in one portion of the container with the openings being of a size smaller than the size of the particles. The openings permit gases and liquids entering the plenum to contact the particles. The additive is comprised of elemental barium or a barium alloy containing one or more metals in addition to barium such as aluminum, zirconium, nickel, titanium and combinations thereof. 6 claims, 3 drawing figures
Analytical Solution of Multicompartment Solute Kinetics for Hemodialysis
Directory of Open Access Journals (Sweden)
Przemysław Korohoda
2013-01-01
Full Text Available Objective. To provide an exact solution for variable-volume multicompartment kinetic models with linear volume change, and to apply this solution to a 4-compartment diffusion-adjusted regional blood flow model for both urea and creatinine kinetics in hemodialysis. Methods. A matrix-based approach applicable to linear models encompassing any number of compartments is presented. The procedure requires the inversion of a square matrix and the computation of its eigenvalues λ, assuming they are all distinct. This novel approach bypasses the evaluation of the definite integral to solve the inhomogeneous ordinary differential equation. Results. For urea two out of four eigenvalues describing the changes of concentrations in time are about 105 times larger than the other eigenvalues indicating that the 4-compartment model essentially reduces to the 2-compartment regional blood flow model. In case of creatinine, however, the distribution of eigenvalues is more balanced (a factor of 102 between the largest and the smallest eigenvalue indicating that all four compartments contribute to creatinine kinetics in hemodialysis. Interpretation. Apart from providing an exact analytic solution for practical applications such as the identification of relevant model and treatment parameters, the matrix-based approach reveals characteristic details on model symmetry and complexity for different solutes.
Application of finite element numerical technique to nuclear reactor geometries
Energy Technology Data Exchange (ETDEWEB)
Rouai, N M [Nuclear engineering department faculty of engineering Al-fateh universty, Tripoli (Libyan Arab Jamahiriya)
1995-10-01
Determination of the temperature distribution in nuclear elements is of utmost importance to ensure that the temperature stays within safe limits during reactor operation. This paper discusses the use of Finite element numerical technique (FE) for the solution of the two dimensional heat conduction equation in geometries related to nuclear reactor cores. The FE solution stats with variational calculus which considers transforming the heat conduction equation into an integral equation I(O) and seeks a function that minimizes this integral and hence gives the solution to the heat conduction equation. In this paper FE theory as applied to heat conduction is briefly outlined and a 2-D program is used to apply the theory to simple shapes and to two gas cooled reactor fuel elements. Good results are obtained for both cases with reasonable number of elements. 7 figs.
Application of finite element numerical technique to nuclear reactor geometries
International Nuclear Information System (INIS)
Rouai, N. M.
1995-01-01
Determination of the temperature distribution in nuclear elements is of utmost importance to ensure that the temperature stays within safe limits during reactor operation. This paper discusses the use of Finite element numerical technique (FE) for the solution of the two dimensional heat conduction equation in geometries related to nuclear reactor cores. The FE solution stats with variational calculus which considers transforming the heat conduction equation into an integral equation I(O) and seeks a function that minimizes this integral and hence gives the solution to the heat conduction equation. In this paper FE theory as applied to heat conduction is briefly outlined and a 2-D program is used to apply the theory to simple shapes and to two gas cooled reactor fuel elements. Good results are obtained for both cases with reasonable number of elements. 7 figs
Element Verification and Comparison in Sierra/Solid Mechanics Problems
Energy Technology Data Exchange (ETDEWEB)
Ohashi, Yuki; Roth, William
2016-05-01
The goal of this project was to study the effects of element selection on the Sierra/SM solutions to five common solid mechanics problems. A total of nine element formulations were used for each problem. The models were run multiple times with varying spatial and temporal discretization in order to ensure convergence. The first four problems have been compared to analytical solutions, and all numerical results were found to be sufficiently accurate. The penetration problem was found to have a high mesh dependence in terms of element type, mesh discretization, and meshing scheme. Also, the time to solution is shown for each problem in order to facilitate element selection when computer resources are limited.
Infinite elements for soil-structure interaction analysis in multi-layered halfspaces
International Nuclear Information System (INIS)
Yun, Chung Bang; Kim, Jae Min; Yang, Shin Chu
1994-01-01
This paper presents the theoretical aspects of a computer code (KIESSI) for soil-structure interaction analysis in a multi-layered halfspace using infinite elements. The shape functions of the infinite elements are derived from approximate expressions of the analytical solutions. Three different infinite elements are developed. They are the horizontal, the vertical and the comer infinite elements (HIE, VIE and CIE). Numerical example analyses are presented for demonstrating the effectiveness of the proposed infinite elements
The chemistry of the actinide elements. Volume I
International Nuclear Information System (INIS)
Katz, J.J.; Seaborg, G.T.; Morss, L.R.
1986-01-01
The Chemistry of the Actinide Elements is a comprehensive, contemporary and authoritative exposition of the chemistry and related properties of the 5f series of elements: actinium, thorium, protactinium, uranium and the first eleven. This second edition has been completely restructured and rewritten to incorporate current research in all areas of actinide chemistry and chemical physics. The descriptions of each element include accounts of their history, separation, metallurgy, solid-state chemistry, solution chemistry, thermo-dynamics and kinetics. Additionally, separate chapters on spectroscopy, magnetochemistry, thermodynamics, solids, the metallic state, complex ions and organometallic compounds emphasize the comparative chemistry and unique properties of the actinide series of elements. Comprehensive lists of properties of all actinide compounds and ions in solution are given, and there are special sections on such topics as biochemistry, superconductivity, radioisotope safety, and waste management, as well as discussion of the transactinides and future elements
Comparison of 3-D finite elements for incompressible fluid flow
International Nuclear Information System (INIS)
Robichaud, M.; Tanguy, P.A.
1985-01-01
In recent years, the finite element method applied to the solution of incompressible fluid flow has been in constant evolution. In the present state-of-the-art, 2-D problems are solved routinely and reliable results are obtained at a reasonable cost. In 3-D the finite element method is still undergoing active research and many methods have been proposed to solve the Navier-Stokes equations at 'low cost'. These methods have in common the choice of the element which has a trilinear velocity and a discontinuous constant pressure (Q1-PO). The prohibitive cost of 3-D finite element method in fluid flow is the reason for this choice: the Q1-PO is the simplest and the cheapest 3-D element. However, as mentioned in (5) and (6), it generates 'spurious' pressure modes phenomenon called checkerboarding. On regular mesh these spurious modes can be filtered but on distorted mesh the pressure solution is meaningless. (author)
Peridynamic Multiscale Finite Element Methods
Energy Technology Data Exchange (ETDEWEB)
Costa, Timothy [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bond, Stephen D. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Littlewood, David John [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Moore, Stan Gerald [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
2015-12-01
The problem of computing quantum-accurate design-scale solutions to mechanics problems is rich with applications and serves as the background to modern multiscale science research. The prob- lem can be broken into component problems comprised of communicating across adjacent scales, which when strung together create a pipeline for information to travel from quantum scales to design scales. Traditionally, this involves connections between a) quantum electronic structure calculations and molecular dynamics and between b) molecular dynamics and local partial differ- ential equation models at the design scale. The second step, b), is particularly challenging since the appropriate scales of molecular dynamic and local partial differential equation models do not overlap. The peridynamic model for continuum mechanics provides an advantage in this endeavor, as the basic equations of peridynamics are valid at a wide range of scales limiting from the classical partial differential equation models valid at the design scale to the scale of molecular dynamics. In this work we focus on the development of multiscale finite element methods for the peridynamic model, in an effort to create a mathematically consistent channel for microscale information to travel from the upper limits of the molecular dynamics scale to the design scale. In particular, we first develop a Nonlocal Multiscale Finite Element Method which solves the peridynamic model at multiple scales to include microscale information at the coarse-scale. We then consider a method that solves a fine-scale peridynamic model to build element-support basis functions for a coarse- scale local partial differential equation model, called the Mixed Locality Multiscale Finite Element Method. Given decades of research and development into finite element codes for the local partial differential equation models of continuum mechanics there is a strong desire to couple local and nonlocal models to leverage the speed and state of the
Discrete elements method of neutral particle transport
International Nuclear Information System (INIS)
Mathews, K.A.
1983-01-01
A new discrete elements (L/sub N/) transport method is derived and compared to the discrete ordinates S/sub N/ method, theoretically and by numerical experimentation. The discrete elements method is more accurate than discrete ordinates and strongly ameliorates ray effects for the practical problems studied. The discrete elements method is shown to be more cost effective, in terms of execution time with comparable storage to attain the same accuracy, for a one-dimensional test case using linear characteristic spatial quadrature. In a two-dimensional test case, a vacuum duct in a shield, L/sub N/ is more consistently convergent toward a Monte Carlo benchmark solution than S/sub N/, using step characteristic spatial quadrature. An analysis of the interaction of angular and spatial quadrature in xy-geometry indicates the desirability of using linear characteristic spatial quadrature with the L/sub N/ method
Diffractive optical elements written by photodeposition
International Nuclear Information System (INIS)
Baal-Zedaka, I.; Hava, S.; Mirchin, N.; Margolin, R.; Zagon, M.; Lapsker, I.; Azoulay, J.; Peled, A.
2003-01-01
In this work direct laser writing of diffractive optical elements (DOE) by photodeposition (PD) of amorphous selenium (a-Se) from colloid solutions has been investigated. We used a computer controlled laser scanner for patterning thin film micro-profiles creating thus planar optical elements by direct beam writing on surfaces immersed in a liquid phase PD cell. The laser employed was an argon ion laser at 488 nm wavelength, with powers up to 55 mW, for writing typically 25-250 μm wide lines of 200 nm thickness at rates of about 150 μm/s. Various elements made of photodeposited thin films on polymethyl-methacrylate (PMMA) substrates were produced for prototyping microlenses, linear grating arrays, cylindrical and circular profiled DOE patterns
The finite element response matrix method
International Nuclear Information System (INIS)
Nakata, H.; Martin, W.R.
1983-02-01
A new technique is developed with an alternative formulation of the response matrix method implemented with the finite element scheme. Two types of response matrices are generated from the Galerkin solution to the weak form of the diffusion equation subject to an arbitrary current and source. The piecewise polynomials are defined in two levels, the first for the local (assembly) calculations and the second for the global (core) response matrix calculations. This finite element response matrix technique was tested in two 2-dimensional test problems, 2D-IAEA benchmark problem and Biblis benchmark problem, with satisfatory results. The computational time, whereas the current code is not extensively optimized, is of the same order of the well estabilished coarse mesh codes. Furthermore, the application of the finite element technique in an alternative formulation of response matrix method permits the method to easily incorporate additional capabilities such as treatment of spatially dependent cross-sections, arbitrary geometrical configurations, and high heterogeneous assemblies. (Author) [pt
Finite element analysis of inelastic structural behavior
International Nuclear Information System (INIS)
Argyris, J.H.; Szimmat, J.; Willam, K.J.
1977-01-01
The paper describes recent achievements in the finite element analysis of inelastic material behavior. The main purpose is to examine the interaction of three disciplines; (i) the finite element formulation of large deformation problems in the light of a systematic linearization, (ii) the constitutive modelling of inelastic processes in the rate-dependent and rate-independent response regime and (iii) the numerical solution of nonlinear rate problems via incremental iteration techniques. In the first part, alternative finite element models are developed for the idealization of large deformation problems. A systematic approach is presented to linearize the field equations locally by an incremental procedure. The finite element formulation is then examined for the description of inelastic material processes. In the second part, nonlinear and inelastic material phenomena are classified and illustrated with representative examples of concrete and metal components. In particular, rate-dependent and rate-independent material behavior is examined and representative constitutive models are assessed for their mathematical characterization. Hypoelastic, elastoplastic and endochronic models are compared for the description rate-independent material phenomena. In the third part, the numerial solution of inelastic structural behavior is discussed. In this context, several incremental techniques are developed and compared for tracing the evolution of the inelastic process. The numerical procedures are examined with regard to stability and accuracy to assess the overall efficiency. The 'optimal' incremental technique is then contrasted with the computer storage requirements to retain the data for the 'memory-characteristics' of the constitutive model
First aqueous chemistry with Seaborgium (element 106)
International Nuclear Information System (INIS)
Schaedel, M.; Bruechle, W.; Schausten, B.; Schimpf, E.; Jaeger, E.; Wirth, G.; Guenther, R.; Gregorich, K.E.; Hoffman, D.C.; Lee, D.M.; Sylwester, E.R.; Nagame, Y.; Oura, Y.
1996-11-01
For the first time, chemical separations of element 106 (Seaborgium, Sg) were performed in aqueous solutions. The isotopes 265 Sg and 266 Sg were produced in the 248 Cm+ 22 Ne reaction at a beam energy of 121 MeV. The reaction products were continuously transported by a He(KCl)-jet to the computer-controlled liquid chromatography system ARCA. In 0.1 M HNO 3 /5 x 10 -4 M HF, Sg was found to be eluted within 10 s from 1.6 x 8 mm cation-exchange columns (Aminex A6, 17.5±2 μm) together with the hexavalent Mo- and W-ions, while hexavalent U-ions and tetravalent Zr-, Hf-, and element 104 ions were strongly retained on the column. Element 106 was detected by measuring correlated α-decays of the daughter isotopes 78-s 261 104 and 26-s 257 102. For the isotope 266 Sg, we have evidence for a spontaneous fission branch. It yields a partial spontaneous-fission half-life which is in agreement with recent theoretical predictions. The chemical results show that the most stable oxidation state of Sg in aqueous solution is +6, and that like its homologs Mo and W, Sg forms neutral or anionic oxo- or oxohalide-compounds under the present condition. In these first experiments, Sg exhibits properties very characteristic of group 6 elements, and does not show U-like properties. (orig.)
Advances in 3D electromagnetic finite element modeling
International Nuclear Information System (INIS)
Nelson, E.M.
1997-01-01
Numerous advances in electromagnetic finite element analysis (FEA) have been made in recent years. The maturity of frequency domain and eigenmode calculations, and the growth of time domain applications is briefly reviewed. A high accuracy 3D electromagnetic finite element field solver employing quadratic hexahedral elements and quadratic mixed-order one-form basis functions will also be described. The solver is based on an object-oriented C++ class library. Test cases demonstrate that frequency errors less than 10 ppm can be achieved using modest workstations, and that the solutions have no contamination from spurious modes. The role of differential geometry and geometrical physics in finite element analysis is also discussed
A Posteriori Error Estimation for Finite Element Methods and Iterative Linear Solvers
Energy Technology Data Exchange (ETDEWEB)
Melboe, Hallgeir
2001-10-01
This thesis addresses a posteriori error estimation for finite element methods and iterative linear solvers. Adaptive finite element methods have gained a lot of popularity over the last decades due to their ability to produce accurate results with limited computer power. In these methods a posteriori error estimates play an essential role. Not only do they give information about how large the total error is, they also indicate which parts of the computational domain should be given a more sophisticated treatment in order to reduce the error. A posteriori error estimates are traditionally aimed at estimating the global error, but more recently so called goal oriented error estimators have been shown a lot of interest. The name reflects the fact that they estimate the error in user-defined local quantities. In this thesis the main focus is on global error estimators for highly stretched grids and goal oriented error estimators for flow problems on regular grids. Numerical methods for partial differential equations, such as finite element methods and other similar techniques, typically result in a linear system of equations that needs to be solved. Usually such systems are solved using some iterative procedure which due to a finite number of iterations introduces an additional error. Most such algorithms apply the residual in the stopping criterion, whereas the control of the actual error may be rather poor. A secondary focus in this thesis is on estimating the errors that are introduced during this last part of the solution procedure. The thesis contains new theoretical results regarding the behaviour of some well known, and a few new, a posteriori error estimators for finite element methods on anisotropic grids. Further, a goal oriented strategy for the computation of forces in flow problems is devised and investigated. Finally, an approach for estimating the actual errors associated with the iterative solution of linear systems of equations is suggested. (author)
International Nuclear Information System (INIS)
Callahan, G.D.; Fossum, A.F.
1982-11-01
General plasticity theory and solution techniques as are currently employed in RE/SPEC's finite element plasticity code SPECTROM-II are presented. Various yield functions are discussed and their differences are illustrated using example problems. Comparison of the results of SPECTROM-II with analytical solutions, numerical solutions, and the general purpose finite element program MARC-CDC show excellent agreement
International Nuclear Information System (INIS)
Ahmed, Mainuddin
2005-01-01
A new solution of Einstein equation in general relativity is found. This solution solves an outstanding problem of thermodynamics and black hole physics. Also this work appears to conclude the interpretation of NUT spacetime. (author)
Fuel element transport container
International Nuclear Information System (INIS)
Benna, P.; Neuenfeldt, W.
1979-01-01
The reprocessing system includes a large number of waterfilled ponds next to each other for the intermediate storage of fuel elements from LWR's. The fuel element transport device is allocated to a middle pond. The individual ponds are separated from each other by walls, and are only accessible from the middle pond via narrow passages. The transport device includes a telescopic running rail for a trolley with a grab device for the fuel element. The running rail is supported in turn by a second trolley, which can be moved by wheels on rails. Part of the drive of the first trolley is arranged on the second one. Using this transport device, adjacent ponds can be served through the passage openings. (DG) [de
International Nuclear Information System (INIS)
Hirayama, Satoshi; Kawada, Toshiyuki; Matsuzaki, Masayoshi.
1980-01-01
Purpose: To provide a fuel element for reducing the mechanical interactions between a fuel-cladding tube and the fuel element and for alleviating the limits of the operating conditions of a reactor. Constitution: A fuel element having mainly uranium dioxide consists of a cylindrical outer pellet and cylindrical inner pellet inserted into the outer pellet. The outer pellet contains two or more additives selected from aluminium oxide, beryllium oxide, magnesium oxide, silicon oxide, sodium oxide, phosphorus oxide, calcium oxide and iron oxide, and the inner pellet contains nuclear fuel substance solely or one additive selected from calcium oxide, silicon oxide, aluminium oxide, magnesium oxide, zirconium oxide and iron oxide. The outer pellet of the fuel thus constituted is reduced in mechanical strength and also in the mechanical interactions with the cladding tube, and the plastic fluidity of the entire pellet is prevented by the inner pellet increased in the mechanical strength. (Kamimura, M.)
Creativity Management Key Elements
Directory of Open Access Journals (Sweden)
Rosa María Fuchs Ángeles
2015-09-01
Full Text Available Organizations are constantly looking towards innovation. In order to reach it they must foment creativity. This paper analyzes a series of elements considered in the organizational creativity management and proposes a model with the indispensable factors that organizations should consider to reach it. These elements are: culture and organizational environment, strategy, structure, communication, relation with customers, human resources (recruiting, training, job design, compensation, promotion, and performance evaluation, long term orientation and the organizational life cycle. Having the analysis of those elements as a basis, the indispensable pillars on management creativity are identified. The proposed model is based on 5 pillars: the alignment between strategic, culture and organizational structure, called by the authors 'Holy Trinity'; intern publicity; customer’s voice; recognition and a look towards future. Finally, the case of an innovative Peruvian enterprise is presented from the model’s perspective and the study conclusions.
Energy Technology Data Exchange (ETDEWEB)
Burley, H.H. [ed.
1956-08-01
It is the purpose of the Fuel Element Technical Manual to Provide a single document describing the fabrication processes used in the manufacture of the fuel element as well as the technical bases for these processes. The manual will be instrumental in the indoctrination of personnel new to the field and will provide a single data reference for all personnel involved in the design or manufacture of the fuel element. The material contained in this manual was assembled by members of the Engineering Department and the Manufacturing Department at the Hanford Atomic Products Operation between the dates October, 1955 and June, 1956. Arrangement of the manual. The manual is divided into six parts: Part I--introduction; Part II--technical bases; Part III--process; Part IV--plant and equipment; Part V--process control and improvement; and VI--safety.
Memon, Sajid; Nataraj, Neela; Pani, Amiya Kumar
2012-01-01
In this article, a posteriori error estimates are derived for mixed finite element Galerkin approximations to second order linear parabolic initial and boundary value problems. Using mixed elliptic reconstructions, a posteriori error estimates in L∞(L2)- and L2(L2)-norms for the solution as well as its flux are proved for the semidiscrete scheme. Finally, based on a backward Euler method, a completely discrete scheme is analyzed and a posteriori error bounds are derived, which improves upon earlier results on a posteriori estimates of mixed finite element approximations to parabolic problems. Results of numerical experiments verifying the efficiency of the estimators have also been provided. © 2012 Society for Industrial and Applied Mathematics.
A finite element model for protein transport in vivo
Directory of Open Access Journals (Sweden)
Montas Hubert J
2007-06-01
Full Text Available Abstract Background Biological mass transport processes determine the behavior and function of cells, regulate interactions between synthetic agents and recipient targets, and are key elements in the design and use of biosensors. Accurately predicting the outcomes of such processes is crucial to both enhancing our understanding of how these systems function, enabling the design of effective strategies to control their function, and verifying that engineered solutions perform according to plan. Methods A Galerkin-based finite element model was developed and implemented to solve a system of two coupled partial differential equations governing biomolecule transport and reaction in live cells. The simulator was coupled, in the framework of an inverse modeling strategy, with an optimization algorithm and an experimental time series, obtained by the Fluorescence Recovery after Photobleaching (FRAP technique, to estimate biomolecule mass transport and reaction rate parameters. In the inverse algorithm, an adaptive method was implemented to calculate sensitivity matrix. A multi-criteria termination rule was developed to stop the inverse code at the solution. The applicability of the model was illustrated by simulating the mobility and binding of GFP-tagged glucocorticoid receptor in the nucleoplasm of mouse adenocarcinoma. Results The numerical simulator shows excellent agreement with the analytic solutions and experimental FRAP data. Detailed residual analysis indicates that residuals have zero mean and constant variance and are normally distributed and uncorrelated. Therefore, the necessary and sufficient criteria for least square parameter optimization, which was used in this study, were met. Conclusion The developed strategy is an efficient approach to extract as much physiochemical information from the FRAP protocol as possible. Well-posedness analysis of the inverse problem, however, indicates that the FRAP protocol provides insufficient
International Nuclear Information System (INIS)
Aftanas, B.L.
1996-01-01
This Functional Design Criteria (FDC) addresses remediation of the plutonium-bearing solutions currently in inventory at the Plutonium Finishing Plant (PFP). The recommendation from the Environmental Impact Statement (EIS) is that the solutions be treated thermally and stabilized as a solid for long term storage. For solutions which are not discardable, the baseline plan is to utilize a denitration process to stabilize the solutions prior to packaging for storage
DEFF Research Database (Denmark)
Hansen, Hans
Elements of Social Security is a comparative study of important elements of the social security systems in Denmark (DK), Sweden (S), Finland (FIN), Austria (A), Germany (D), the Netherlands (NL), Great Britain (GB) and Canada (CAN). It should be emphasized that Germany is the former West Germany...... (Alte Länder). This is the 9th and last edition of the publication,covering income levels and rules for social security and personal taxation for 1999. Basis for the projections to 1999 income levels is the 1998 data (in some cases 1999 data)for OECD's Taxing Wages as reported by national experts....
Amir-Moez, A R; Sneddon, I N
1962-01-01
Elements of Linear Space is a detailed treatment of the elements of linear spaces, including real spaces with no more than three dimensions and complex n-dimensional spaces. The geometry of conic sections and quadric surfaces is considered, along with algebraic structures, especially vector spaces and transformations. Problems drawn from various branches of geometry are given.Comprised of 12 chapters, this volume begins with an introduction to real Euclidean space, followed by a discussion on linear transformations and matrices. The addition and multiplication of transformations and matrices a
Bibliography on transuranium elements
International Nuclear Information System (INIS)
Sood, D.D.
1991-01-01
A selective bibliography of prominent publications on transuranium elements is compiled. Heading papers, symposia proceedings and the textbooks are included in the bibliography. The bibliography is arranged under the headings: (1)Books, Symposia Proceedings, Reviews etc., (2)Discovery, (3)Weighable Isolation, (4)Metal Preparation, (5)Nuclear Properties, (6)Plutonium as Reactor Fuel, (7)Fuel Reprocessing, (8)Solid State Chemistry, Thermochemistry and Spectroscopy, (9)Radiation Safety, (10)Applications, and (11)Some Typical Indian Papers. Total number of references cited are 298. The bibliography, though selective, will serve as a starting point for comprehensive literature search on transuranium elements. (author)
Classical solutions in supergravity
International Nuclear Information System (INIS)
Baaklini, N.S.; Ferrara, S.; Nieuwenhuizen Van, P.
1977-06-01
Classical solutions of supergravity are obtained by making finite global supersymmetry rotation on known solutions of the field equations of the bosonic sector. The Schwarzschild and the Reissner-Nordstoem solutions of general relativity are extended to various supergravity systems and the modification to the perihelion precession of planets is discussed
International Nuclear Information System (INIS)
Long, E.C.
1977-01-01
A liquid scintillation solution is described which includes (1) a scintillation solvent (toluene and xylene), (2) a primary scintillation solute (PPO and Butyl PBD), (3) a secondary scintillation solute (POPOP and Dimethyl POPOP), (4) a plurality of substantially different surfactants and (5) a filter dissolving and/or transparentizing agent. 8 claims
On mesh refinement and accuracy of numerical solutions
Zhou, Hong; Peters, Maria; van Oosterom, Adriaan
1993-01-01
This paper investigates mesh refinement and its relation with the accuracy of the boundary element method (BEM) and the finite element method (FEM). TO this end an isotropic homogeneous spherical volume conductor, for which the analytical solution is available, wag used. The numerical results
Minimal solution of linear formed fuzzy matrix equations
Directory of Open Access Journals (Sweden)
Maryam Mosleh
2012-10-01
Full Text Available In this paper according to the structured element method, the $mimes n$ inconsistent fuzzy matrix equation $Ailde{X}=ilde{B},$ which are linear formed by fuzzy structured element, is investigated. The necessary and sufficient condition for the existence of a fuzzy solution is also discussed. some examples are presented to illustrate the proposed method.
Finite element analysis of three dimensional crack growth by the use of a boundary element sub model
DEFF Research Database (Denmark)
Lucht, Tore
2009-01-01
A new automated method to model non-planar three dimensional crack growth is proposed which combines the advantages of both the boundary element method and the finite element method. The proposed method links the two methods by a submodelling strategy in which the solution of a global finite...... element model containing an approximation of the crack is interpolated to a much smaller boundary element model containing a fine discretization of the real crack. The method is validated through several numerical comparisons and by comparison to crack growth measured in a test specimen for an engineering...
Finite element and boundary element applications in quantum mechanics
International Nuclear Information System (INIS)
Ueta, Tsuyoshi
2003-01-01
Although this book is one of the Oxford Texts in Applied and Engineering Mathematics, we may think of it as a physics book. It explains how to solve the problem of quantum mechanics using the finite element method (FEM) and the boundary element method (BEM). Many examples analysing actual problems are also shown. As for the ratio of the number of pages of FEM and BEM, the former occupies about 80%. This is, however, reasonable reflecting the flexibility of FEM. Although many explanations of FEM and BEM exist, most are written using special mathematical expressions and numerical computation fields. However, this book is written in the 'language of physicists' throughout. I think that it is very readable and easy to understand for physicists. In the derivation of FEM and the argument on calculation accuracy, the action integral and a variation principle are used consistently. In the numerical computation of matrices, such as simultaneous equations and eigen value problems, a description of important points is also fully given. Moreover, the practical problems which become important in the electron device design field and the condensed matter physics field are dealt with as example computations, so that this book is very practical and applicable. It is characteristic and interesting that FEM is applied to solve the Schroedinger and Poisson equations consistently, and to the solution of the Ginzburg--Landau equation in superconductivity. BEM is applied to treat electric field enhancements due to surface plasmon excitations at metallic surfaces. A number of references are cited at the end of all the chapters, and this is very helpful. The description of quantum mechanics is also made appropriately and the actual application of quantum mechanics in condensed matter physics can also be surveyed. In the appendices, the mathematical foundation, such as numerical quadrature formulae and Green's functions, is conveniently described. I recommend this book to those who need to
DEFF Research Database (Denmark)
Hansen, Hans
Elements of Social Security contains an overview of important benefit schemes in Denmark, Sweden, Finland, Austria, Germany, the Netherlands, Great Britain and Canada. The schemes are categorized according to common sets of criteria and compared. Stylized cases illustrate the impact on disposable...
DEFF Research Database (Denmark)
Hansen, Hans
Elements of Social Security contains an overview of important benefit schemes in Denmark, Sweden, Finland, Germany, the Netherlands, Great Britain and Canada. The schemes are categorized according to common sets of criteria and compared. Stylized cases illustrate the impact on disposable income...
DEFF Research Database (Denmark)
Hansen, Hans
Elements of Social Security contains an overview of important benefit schemes in Denmark, Sweden, Finland, Germany, Great Britain, the Netherlands and Canada. The schemes are categorized according to common sets of criteria and compared. Stylized cases illustrate the impact on disposable income...
Schotting, R.J.
2009-01-01
Water is the key to life. No living creature can survive without water. Too much water or polluted water are serious threats to mankind. Managing this intangible element is complex, not only in wet deltaic regions but also in the (semi-)arid regions of the world. Combined efforts of the
Keller, Rodney D.
1987-01-01
Recommends using movie clips to stimulate students' interest in reading a novel as well as to teach elements of fiction such as plot, character, setting, symbol, irony, and theme. Describes each clip and provides study questions. Includes a listing of movies made from books. (NH)
DEFF Research Database (Denmark)
Elements of Architecture explores new ways of engaging architecture in archaeology. It conceives of architecture both as the physical evidence of past societies and as existing beyond the physical environment, considering how people in the past have not just dwelled in buildings but have existed...
Weiser, Martin
2016-01-01
All relevant implementation aspects of finite element methods are discussed in this book. The focus is on algorithms and data structures as well as on their concrete implementation. Theory is covered as far as it gives insight into the construction of algorithms. Throughout the exercises a complete FE-solver for scalar 2D problems will be implemented in Matlab/Octave.
Plants' essential chemical elements
Kevin T. Smith
2007-01-01
Every garden center and hardware store sells fertilizer guaranteed to "feed" plants. In a strict sense, we can't feed plants. Food contains an energy source. Green plants capture solar energy and make their own food through photosynthesis! Photosynthesis and other metabolic processes require chemical elements in appropriate doses for plants to survive...
International Nuclear Information System (INIS)
Lawden, D.F.
1985-01-01
The book on elements of relativity theory is intended for final year school students or as an early university course in mathematical physics. Special principle of relativity, lorentz transformation, velocity transformations, relativistic mechanics, and general theory of relativity, are all discussed. (U.K.)
Photovoltaic radiation detector element
International Nuclear Information System (INIS)
Agouridis, D.C.
1980-01-01
A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein in the edge of which closely approaches but is spaced from the current collector strips
International Nuclear Information System (INIS)
Neace, J.C.
1986-01-01
This patent describes a process for removing diluent degradation products from a solvent extraction solution comprising an admixture of an organic extractant for uranium and plutonium and a non-polar organic liquid diluent, which has been used to recover uranium and plutonium from spent nuclear fuel. Comprising combining a wash solution consisting of: (a) water; and (b) a positive amount up to about, an including, 50 volume percent of at least one highly-polar water-miscible organic solvent, based on the total volume of the water and the highly-polar organic solvent, with the solvent extraction solution after uranium and plutonium values have been stripped from the solvent extraction solution, the diluent degradation products dissolving in the highly-polar organic solvent and the extractant and diluent of the extraction solution not dissolving in the highly-polar organic solvent, and separating the highly-polar organic solvent and the extraction solution to obtain a purified extraction solution
Directory of Open Access Journals (Sweden)
Woo-Young Jung
2015-04-01
Full Text Available For the solution of geometrically nonlinear analysis of plates and shells, the formulation of a nonlinear nine-node refined first-order shear deformable element-based Lagrangian shell element is presented. Natural co-ordinate-based higher order transverse shear strains are used in present shell element. Using the assumed natural strain method with proper interpolation functions, the present shell element generates neither membrane nor shear locking behavior even when full integration is used in the formulation. Furthermore, a refined first-order shear deformation theory for thin and thick shells, which results in parabolic through-thickness distribution of the transverse shear strains from the formulation based on the third-order shear deformation theory, is proposed. This formulation eliminates the need for shear correction factors in the first-order theory. To avoid difficulties resulting from large increments of the rotations, a scheme of attached reference system is used for the expression of rotations of shell normal. Numerical examples demonstrate that the present element behaves reasonably satisfactorily either for the linear or for geometrically nonlinear analysis of thin and thick plates and shells with large displacement but small strain. Especially, the nonlinear results of slit annular plates with various loads provided the benchmark to test the accuracy of related numerical solutions.