Sample records for sole source aquifer

  1. EPA Sole Source Aquifers

    U.S. Environmental Protection Agency — Information on sole source aquifers (SSAs) is widely used in assessments under the National Environmental Policy Act and at the state and local level. A national...

  2. Region 9 Sole Source Aquifers

    U.S. Environmental Protection Agency — There are 7 polygons representing 6 individual sole source aquifer boundaries and one streamflow source area in California, Arizona, and Nevada. Various efforts were...

  3. EPA Region 1 Sole Source Aquifers

    U.S. Environmental Protection Agency — This coverage contains boundaries of EPA-approved sole source aquifers. Sole source aquifers are defined as an aquifer designated as the sole or principal source of...

  4. Sole Source Aquifers for NY and NJ

    U.S. Environmental Protection Agency — This layer is the designated sole source aquifers of New York and New Jersey. A Sole Source Aquifer, is an aquifer that supplies 50% or more of the drinking water...

  5. National Sole Source Aquifer GIS Layer

    U.S. Environmental Protection Agency — This data set contains indexes and Esri shape files of boundaries of the designated sole source aquifers and related aquifer boundaries. Data provide a vector...

  6. EPA Region 6 Sole Source Aquifers in Louisiana, Geographic NAD83, EPA (1996) [sole_source_aquifers_LA_EPA_1996

    Louisiana Geographic Information Center — Polygon layer of EPA Region 6 sole source aquifers in Louisiana. The sole source aquifers represented are Chicot and Southern Hills in Louisiana/Mississippi.

  7. Sole Source Aquifer Program | Drinking Water in New ...


    The Safe Drinking Water Act gives EPA the authority to designate aquifers which are the sole or principal drinking water source for an area, and which, if contaminated, would create a significant hazard to public health.

  8. 78 FR 19261 - Safe Drinking Water Act Sole Source Aquifer Program; Designation of Bainbridge Island, Washington...


    ... AGENCY Safe Drinking Water Act Sole Source Aquifer Program; Designation of Bainbridge Island, Washington.... SUMMARY: Notice is hereby given that pursuant to Section 1424(e) of the Safe Drinking Water Act, the... Aquifer System located in Kitsap County, Washington is the sole or principle source of drinking water...

  9. Second Sourcing vs. Sole Sourcing with Capacity Investment and Asymmetric Information

    Cuihong Li; Laurens G. Debo


    We study the decision of a manufacturer (the buyer), expecting new sourcing opportunities in the future, in selecting between sole- and second-sourcing strategies for a noncommodity component. In a sole-sourcing strategy, the buyer commits to sourcing from a single supplier (the incumbent) over the entire horizon. In a second-sourcing strategy, the buyer keeps the option open to source from a new supplier (the entrant) in the future. Supplier costs are private information, and the incumbent's...

  10. The source of naturally occurring arsenic in a coastal sand aquifer of eastern Australia.

    O'Shea, Bethany; Jankowski, Jerzy; Sammut, Jesmond


    The discovery of dissolved arsenic in a coastal aquifer used extensively for human consumption has led to widespread concern for its potential occurrence in other sandy coastal environments in eastern Australia. The development of an aquifer specific geomorphic model (herein) suggests that arsenic is regionally derived from erosion of arsenic-rich stibnite (Sb(2)S(3)) mineralisation present in the hinterland. Fluvial processes have transported the eroded material over time to deposit an aquifer lithology elevated in arsenic. Minor arsenic contribution to groundwater is derived from mineralised bedrock below the unconsolidated aquifer. An association with arsenic and pyrite has been observed in the aquifer in small discrete arsenian pyrite clusters rather than actual acid sulfate soil horizons. This association is likely to influence arsenic distribution in the aquifer, but is not the dominant control on arsenic occurrence. Arsenic association with marine clays is considered a function of their increased adsorptive capacity for arsenic and not solely on the influence of sea level inundation of the aquifer sediments during the Quaternary Period. These findings have implications for, but are not limited to, coastal aquifers. Rather, any aquifer containing sediments derived from mineralised provenances may be at risk of natural arsenic contamination. Groundwater resource surveys should thus incorporate a review of the aquifer source provenance when assessing the likely risk of natural arsenic occurrence in an aquifer.

  11. Sole-Source Lighting for Controlled-Environment Agriculture

    Mitchell.Cary; Stutte, Gary W.


    Since plants on Earth evolved under broad-spectrum solar radiation, anytime they are grown exclusively under electric lighting that does not contain all wavelengths in similar proportion to those in sunlight, plant appearance and size could be uniquely different. Nevertheless, plants have been grown for decades under fluorescent (FL) (1) + incandescent (IN) (2) lamps as a sole source of lighting (SSL), and researchers have become comfortable that, in certain proportions of FL + IN for a given species, plants can appear "normal" relative to their growth outdoors. The problem with using such traditional SSLs for commercial production typically is short lamp lifespans and not obtaining enough photosynthetically active radiation (PAR, 400-700 nm) when desired. These limitations led to supplementation of FL + IN lamp outputs with longer-lived, high-intensity discharge (HID) lamps in growth chambers (3). As researchers became comfortable that mixes of orange-biased high-pressure sodium (HPS) and blue-biased metal halide (MH) HIDs together also could give normal plant growth at higher intensities, growth chambers and phytotrons subsequently were equipped mainly with HID lamps, with their intense thermal output filtered out by ventilated light caps or thermal-controlled water barriers. For the most part, IN and HID lamps have found a home in commercial protected horticulture, usually for night-break photoperiod lighting (IN) or for seasonal supplemental lighting (mostly HPS) in greenhouses. However, lack of economically viable options for SSL have held back aspects of year-round indoor agriculture from taking off commercially.

  12. Source speciation resolving hydrochemical complexity of coastal aquifers.

    Sonkamble, Sahebrao; Chandra, Subash; Ahmed, Shakeel; Rangarajan, R


    There is a growing concern of seawater intrusion to freshwater aquifers due to groundwater overexploitation in the eastern coastal belt of Southern India. The problem becomes complex in the regions where industrial effluents are also contaminating the freshwater aquifers. In order to understand the hydrochemical complexity of the system, topographic elevation, static water level measurements, major ion chemistry, ionic cross plots, water type contours and factor analysis were applied for 144 groundwater samples of shallow and deep sources from Quaternary and Tertiary coastal aquifers, located within the industrial zone of 25 km(2) area near Cuddalore, Southern India. The ionic cross plots indicates dissolution of halite minerals from marine sources and seawater mixing into inland aquifers up to the level of 9.3%. The factor analysis explains three significant factors totaling 86.3% of cumulative sample variance which includes varying contribution from marine, industrial effluent and freshwater sources.

  13. 75 FR 53269 - Federal Acquisition Regulation; Tribal Consultation; Justification and Approval of Sole-Source 8...


    ... Authorization Act (NDAA) for FY 2010, Public Law 111-84. Section 811 addresses requirements for the justification and approval of sole-source contracts over $20 million under the 8(a) small business development... business under the Small Business Administration's 8(a) business development program, including...

  14. Nitrate Removal from Drinking Water with Sodium Citrate as Sole Carbon Source

    YAN Bo; ZHAO Lin; TAN Xin


    This paper investigates the effect of using sodium citrate(NaC6H5O6*2H2O)as sole carbon source for nitrate removal from drinking water.With sodium citrate as sole carbon source, batch experiments have been conducted to study the law of denitrification influenced by pH, C/N and temperature. Results show that a denitrification rate reaching 1.32 g NO-3-N /(g Biomass*d) was obtained when pH was at 7.5,C/N at 1.7(atom ratio), and temperature from 20 ℃ to 30 ℃. The results also show that denitrification rate with sodium citrate as carbon source approaches to that with methanol as carbon source.

  15. Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas.

    Musgrove, M; Opsahl, S P; Mahler, B J; Herrington, C; Sample, T L; Banta, J R


    Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO3(-)) loading to surface and groundwater. We investigate variability and sources of NO3(-) in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008-12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO3(-) stable isotopes (δ(15)N and δ(18)O). These data were augmented by historical data collected from 1937 to 2007. NO3(-) concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO3(-) concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO3(-) concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO3(-). These results highlight the vulnerability of karst aquifers to NO3(-) contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008-10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO3(-) than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a previously unrecognized

  16. Sources of sulfate supporting anaerobic metabolism in a contaminated aquifer

    Ulrich, G.A.; Breit, G.N.; Cozzarelli, I.M.; Suflita, J.M.


    Field and laboratory techniques were used to identify the biogeochemical factors affecting sulfate reduction in a shallow, unconsolidated alluvial aquifer contaminated with landfill leachate. Depth profiles of 35S-sulfate reduction rates in aquifer sediments were positively correlated with the concentration of dissolved sulfate. Manipulation of the sulfate concentration in samples revealed a Michaelis-Menten-like relationship with an apparent Km and Vmax of approximately 80 and 0.83 ??M SO4-2??day-1, respectively. The concentration of sulfate in the core of the leachate plume was well below 20 ??M and coincided with very low reduction rates. Thus, the concentration and availability of this anion could limit in situ sulfate-reducing activity. Three sulfate sources were identified, including iron sulfide oxidation, barite dissolution, and advective flux of sulfate. The relative importance of these sources varied with depth in the alluvium. The relatively high concentration of dissolved sulfate at the water table is attributed to the microbial oxidation of iron sulfides in response to fluctuations of the water table. At intermediate depths, barite dissolves in undersaturated pore water containing relatively high concentrations of dissolved barium (???100 ??M) and low concentrations of sulfate. Dissolution is consistent with the surface texture of detrital barite grains in contact with leachate. Laboratory incubations of unamended and barite-amended aquifer slurries supported the field observation of increasing concentrations of barium in solution when sulfate reached low levels. At a deeper highly permeable interval just above the confining bottom layer of the aquifer, sulfate reduction rates were markedly higher than rates at intermediate depths. Sulfate is supplied to this deeper zone by advection of uncontaminated groundwater beneath the landfill. The measured rates of sulfate reduction in the aquifer also correlated with the abundance of accumulated iron sulfide

  17. Growth kinetics and toxicity of Enterobacter cloacae grown on linear alkylbenzene sulfonate as sole carbon source.

    Khleifat, Khaled M; Tarawneh, Khaled A; Ali Wedyan, Mohammad; Al-Tarawneh, Amjad A; Al Sharafa, Khalid


    A successful attempt was made to isolate linear alkylbenzene sulfonate (LAS)-degrading bacteria from soil irrigated with wastewater. The isolated bacteria were able to use LAS as sole carbon and energy source. Maximum growth rates on LAS reached only 0.27 h(-1). 16S-rRNA sequencing and fatty-acid analysis placed the bacteria in the genus Enterobacter cloacae. The growth curves of E. cloacae both in the presence of and the absence of LAS were monitored using measurements of optical density at 600 nm in two different media, nutrient broth and M9 minimal medium, and were modeled mathematically. Growth in NB fit the Riccati and Voltera models, indicating that LAS is not toxic to E. cloacae cells. However, growth of E. cloacae in LAS-containing MM fit the Riccati and Voltera models, whereas growth in LAS-free MM fit the Riccati model only. Furthermore, the kinetic data shown were modeled by Monod's, Andrew's, and Tessier's specific growth rate equations, coupled with the rate of consumption of different concentrations of LAS as sole carbon and energy source, and we determined that Andrew's model best fit these data adequately as a result of the cell-inhibitory effect.

  18. Biological phosphorus removal in anoxic-aerobic sequencing batch reactor with starch as sole carbon source.

    Luo, Dacheng; Yuan, Linjiang; Liu, Lun; Chai, Lu; Wang, Xin


    In traditional biological phosphorus removal (BPR), phosphorus release in anaerobic stage is the prerequisite of phosphorus excessive uptake in aerobic conditions. Moreover, when low molecular weight of the organic substance such as volatile fatty acids (VFAs) is scarce in bulk liquid or anaerobic condition does not exist, phosphate accumulating organisms (PAOs) have difficulty removing phosphorus. However, in this work, phosphorus removal in two anoxic-aerobic sequencing batch reactors (SBRs) was observed when starch was supplied as a sole carbon source. The relations of the BPR with idle period were investigated in the two identical SBRs; the idle times were set to 0.5 hr (R1) and 4 hr (R2), respectively. Results of the study showed that, in the two SBRs, phosphorus concentrations of 0.26-3.11 mg/L in effluent were obtained after aeration when phosphorus concentration in influent was about 8 mg/L. Moreover, lower accumulations/transformations of polyhydroxyalkanoates (PHAs) and higher transformation of glycogen occurred in the SBRs, indicating that glycogen was the main energy source that was different from the traditional mechanism of BPR. Under the different idle time, the phosphorus removal was a little different. In R2, which had a longer idle period, phosphorus release was very obvious just as occurs in a anaerobic-aerobic regime, but there was a special phenomenon of chemical oxygen demand increase, while VFAs had no notable change. It is speculated that PAOs can assimilate organic compounds in the mixed liquor, which were generated from glycolysis by fermentative organisms, coupled with phosphorus release. In R1, which had a very short idle period, anaerobic condition did not exist; phosphorus removal rate reached 63%. It is implied that a new metabolic pathway can occur even without anaerobic phosphorus release when starch is supplied as the sole carbon source.

  19. Carbon utilization profiles of river bacterial strains facing sole carbon sources suggest metabolic interactions.

    Goetghebuer, Lise; Servais, Pierre; George, Isabelle F


    Microbial communities play a key role in water self-purification. They are primary drivers of biogenic element cycles and ecosystem processes. However, these communities remain largely uncharacterized. In order to understand the diversity-heterotrophic activity relationship facing sole carbon sources, we assembled a synthetic community composed of 20 'typical' freshwater bacterial species mainly isolated from the Zenne River (Belgium). The carbon source utilization profiles of each individual strain and of the mixed community were measured in Biolog Phenotype MicroArrays PM1 and PM2A microplates that allowed testing 190 different carbon sources. Our results strongly suggest interactions occurring between our planktonic strains as our synthetic community showed metabolic properties that were not displayed by its single components. Finally, the catabolic performances of the synthetic community and a natural community from the same sampling site were compared. The synthetic community behaved like the natural one and was therefore representative of the latter in regard to carbon source consumption. © FEMS 2017. All rights reserved. For permissions, please e-mail:

  20. Culture strategies for lipid production using acetic acid as sole carbon source by Rhodosporidium toruloides.

    Huang, Xiang-Feng; Liu, Jia-Nan; Lu, Li-Jun; Peng, Kai-Ming; Yang, Gao-Xiang; Liu, Jia


    Rhodosporidium toruloides AS 2.1389 was tested using different concentrations of acetic acid as a low-cost carbon source for the production of microbial lipids, which are good raw materials for biodiesel production. It grew and had higher lipid contents in media containing 4-20 g/L acetic acid as the sole carbon source, compared with that in glucose-containing media under the same culture conditions. At acetic acid concentrations as high as 20 g/L and the optimal carbon-to-nitrogen ratio (C/N) of 200 in a batch culture, the highest biomass production was 4.35 g/L, with a lipid content of 48.2%. At acetic acid concentrations as low as 4 g/L, a sequencing batch culture (SBC) with a C/N of 100 increased biomass production to 4.21 g/L, with a lipid content of 38.6%. These results provide usable culture strategies for lipid production by R. toruloides AS 2.1389 when using diverse waste-derived volatile fatty acids.

  1. Saliva as the Sole Nutritional Source in the Development of Multispecies Communities in Dental Plaque.

    Jakubovics, Nicholas S


    Dental plaque is a polymicrobial biofilm that forms on the surfaces of teeth and, if inadequately controlled, can lead to dental caries or periodontitis. Nutrient availability is the fundamental limiting factor for the formation of dental plaque, and for its ability to generate acid and erode dental enamel. Nutrient availability is also critical for bacteria to grow in subgingival biofilms and to initiate periodontitis. Over the early stages of dental plaque formation, micro-organisms acquire nutrients by breaking down complex salivary substrates such as mucins and other glycoproteins. Once dental plaque matures, dietary carbohydrates become more important for supragingival dental plaque, and gingival crevicular fluid forms the major nutrient source for subgingival microorganisms. Many species of oral bacteria do not grow in laboratory monocultures when saliva is the sole nutrient source, and it is now clear that intermicrobial interactions are critical for the development of dental plaque. This chapter aims to provide an overview of the key metabolic requirements of some well-characterized oral bacteria, and the nutrient webs that promote the growth of multispecies communities and underpin the pathogenicity of dental plaque for both dental caries and periodontitis.

  2. Saline Groundwater from Coastal Aquifers As a Source for Desalination.

    Stein, Shaked; Russak, Amos; Sivan, Orit; Yechieli, Yoseph; Rahav, Eyal; Oren, Yoram; Kasher, Roni


    Reverse osmosis (RO) seawater desalination is currently a widespread means of closing the gap between supply and demand for potable water in arid regions. Currently, one of the main setbacks of RO operation is fouling, which hinders membrane performance and induces pressure loss, thereby reducing system efficiency. An alternative water source is saline groundwater with salinity close to seawater, pumped from beach wells in coastal aquifers which penetrate beneath the freshwater-seawater interface. In this research, we studied the potential use of saline groundwater of the coastal aquifer as feedwater for desalination in comparison to seawater using fieldwork and laboratory approaches. The chemistry, microbiology and physical properties of saline groundwater were characterized and compared with seawater. Additionally, reverse osmosis desalination experiments in a cross-flow system were performed, evaluating the permeate flux, salt rejection and fouling propensities of the different water types. Our results indicated that saline groundwater was significantly favored over seawater as a feed source in terms of chemical composition, microorganism content, silt density, and fouling potential, and exhibited better desalination performance with less flux decline. Saline groundwater may be a better water source for desalination by RO due to lower fouling potential, and reduced pretreatment costs.

  3. Isolation and characterization of a bacterium which utilizes polyester polyurethane as a sole carbon and nitrogen source.

    Nakajima-Kambe, T; Onuma, F; Kimpara, N; Nakahara, T


    Various soil samples were screened for the presence of microorganisms which have the ability to degrade polyurethane compounds. Two strains with good polyurethane degrading activity were isolated. The more active strain was tentatively identified as Comamonas acidovorans. This strain could utilize polyester-type polyurethanes but not the polyether-type polyurethanes as sole carbon and nitrogen sources. Adipic acid and diethylene glycol were probably the main degradation products when polyurethane was supplied as a sole carbon and nitrogen source. When ammonium nitrate was used as nitrogen source, only diethylene glycol was detected after growth on polyurethane.

  4. Continuous operation of an ultra-low-power microcontroller using glucose as the sole energy source.

    Lee, Inyoung; Sode, Takashi; Loew, Noya; Tsugawa, Wakako; Lowe, Christopher Robin; Sode, Koji


    An ultimate goal for those engaged in research to develop implantable medical devices is to develop mechatronic implantable artificial organs such as artificial pancreas. Such devices would comprise at least a sensor module, an actuator module, and a controller module. For the development of optimal mechatronic implantable artificial organs, these modules should be self-powered and autonomously operated. In this study, we aimed to develop a microcontroller using the BioCapacitor principle. A direct electron transfer type glucose dehydrogenase was immobilized onto mesoporous carbon, and then deposited on the surface of a miniaturized Au electrode (7mm(2)) to prepare a miniaturized enzyme anode. The enzyme fuel cell was connected with a 100 μF capacitor and a power boost converter as a charge pump. The voltage of the enzyme fuel cell was increased in a stepwise manner by the charge pump from 330mV to 3.1V, and the generated electricity was charged into a 100μF capacitor. The charge pump circuit was connected to an ultra-low-power microcontroller. Thus prepared BioCapacitor based circuit was able to operate an ultra-low-power microcontroller continuously, by running a program for 17h that turned on an LED every 60s. Our success in operating a microcontroller using glucose as the sole energy source indicated the probability of realizing implantable self-powered autonomously operated artificial organs, such as artificial pancreas. Copyright © 2016 Elsevier B.V. All rights reserved.

  5. Characterization of Biosurfactant Produced during Degradation of Hydrocarbons Using Crude Oil As Sole Source of Carbon

    Patowary, Kaustuvmani; Patowary, Rupshikha; Kalita, Mohan C.; Deka, Suresh


    Production and spillage of petroleum hydrocarbons which is the most versatile energy resource causes disastrous environmental pollution. Elevated oil degrading performance from microorganisms is demanded for successful microbial remediation of those toxic pollutants. The employment of biosurfactant-producing and hydrocarbon-utilizing microbes enhances the effectiveness of bioremediation as biosurfactant plays a key role by making hydrocarbons bio-available for degradation. The present study aimed the isolation of a potent biosurfactant producing indigenous bacteria which can be employed for crude oil remediation, along with the characterization of the biosurfactant produced during crude oil biodegradation. A potent bacterial strain Pseudomonas aeruginosa PG1 (identified by 16s rDNA sequencing) was isolated from hydrocarbon contaminated soil that could efficiently produce biosurfactant by utilizing crude oil components as the carbon source, thereby leading to the enhanced degradation of the petroleum hydrocarbons. Strain PG1 could degrade 81.8% of total petroleum hydrocarbons (TPH) after 5 weeks of culture when grown in mineral salt media (MSM) supplemented with 2% (v/v) crude oil as the sole carbon source. GCMS analysis of the treated crude oil samples revealed that P. aeruginosa PG1 could potentially degrade various hydrocarbon contents including various PAHs present in the crude oil. Biosurfactant produced by strain PG1 in the course of crude oil degradation, promotes the reduction of surface tension (ST) of the culture medium from 51.8 to 29.6 mN m−1, with the critical micelle concentration (CMC) of 56 mg L−1. FTIR, LC-MS, and SEM-EDS studies revealed that the biosurfactant is a rhamnolipid comprising of both mono and di rhamnolipid congeners. The biosurfactant did not exhibit any cytotoxic effect to mouse L292 fibroblastic cell line, however, strong antibiotic activity against some pathogenic bacteria and fungus was observed. PMID:28275373

  6. Aquifers

    Earth Data Analysis Center, University of New Mexico — This map layer contains the shallowest principal aquifers of the conterminous United States, Hawaii, Puerto Rico, and the U.S. Virgin Islands, portrayed as polygons....

  7. Aquifers

    Department of Homeland Security — This map layer contains the shallowest principal aquifers of the conterminous United States, Hawaii, Puerto Rico, and the U.S. Virgin Islands, portrayed as polygons....

  8. 40 CFR 144.7 - Identification of underground sources of drinking water and exempted aquifers.


    ... of drinking water and exempted aquifers. 144.7 Section 144.7 Protection of Environment ENVIRONMENTAL... Provisions § 144.7 Identification of underground sources of drinking water and exempted aquifers. (a) The..., except where exempted under paragraph (b) of this section, as an underground source of drinking...

  9. Groundwater sources and geochemical processes in a crystalline fault aquifer

    Roques, Clément; Aquilina, Luc; Bour, Olivier; Maréchal, Jean-Christophe; Dewandel, Benoît; Pauwels, Hélène; Labasque, Thierry; Vergnaud-Ayraud, Virginie; Hochreutener, Rebecca


    The origin of water flowing in faults and fractures at great depth is poorly known in crystalline media. This paper describes a field study designed to characterize the geochemical compartmentalization of a deep aquifer system constituted by a graben structure where a permeable fault zone was identified. Analyses of the major chemical elements, trace elements, dissolved gases and stable water isotopes reveal the origin of dissolved components for each permeable domain and provide information on various water sources involved during different seasonal regimes. The geochemical response induced by performing a pumping test in the fault-zone is examined, in order to quantify mixing processes and contribution of different permeable domains to the flow. Reactive processes enhanced by the pumped fluxes are also identified and discussed. The fault zone presents different geochemical responses related to changes in hydraulic regime. They are interpreted as different water sources related to various permeable structures within the aquifer. During the low water regime, results suggest mixing of recent water with a clear contribution of older water of inter-glacial origin (recharge temperature around 7 °C), suggesting the involvement of water trapped in a local low-permeability matrix domain or the contribution of large scale circulation loops. During the high water level period, due to inversion of the hydraulic gradient between the major permeable fault zone and its surrounding domains, modern water predominantly flows down to the deep bedrock and ensures recharge at a local scale within the graben. Pumping in a permeable fault zone induces hydraulic connections with storage-reservoirs. The overlaid regolith domain ensures part of the flow rate for long term pumping (around 20% in the present case). During late-time pumping, orthogonal fluxes coming from the fractured domains surrounding the major fault zone are dominant. Storage in the connected fracture network within the

  10. Yeast species utilizing uric acid, adenine, n-alkylamines or diamines as sole source of carbon and energy.

    Middelhoven, W J; De Kievit, H; Biesbroek, A L


    Yeast strains utilizing uric acid, adenine, monoamines or diamines as sole source of carbon and energy were isolated from several soil samples by the enrichment culture method. The most common species was Trichosporon cutaneum. Strains of Candida catenulata, C. famata, C. parapsilosis, C. rugosa, Cryptococcus laurentii, Stephanoascus ciferrii and Tr. adeninovorans were also isolated. All strains utilizing uric acid as sole carbon source utilized some primary n-alkyl-l-amines, hydroxyamines or diamines as well. The ascomycetous yeast strains showing these characteristics all belonged to species known to assimilate hydrocarbons. Type strains of hydrocarbon-positive yeast species which were not found in the enrichment cultures generally assimilated putrescine, some type strains also butylamine or pentylamine, but none assimilated uric acid. Methanol-positive species were not isolated. Type strains of methanol-positive and of hydrocarbon-negative species did not assimilate uric acid, butylamine or putrescine. Assimilation of putrescine as sole source of carbon and energy may be a valuable diagnostic criterion in yeast taxonomy.

  11. Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer and intermediate aquifer system in southwest Florida

    Sacks, Laura A.; Tihansky, Ann B.


    In southwest Florida, sulfate concentrations in water from the Upper Floridan aquifer and overlying intermediate aquifer system are commonly above 250 milligrams per liter (the drinking water standard), particularly in coastal areas. Possible sources of sulfate include dissolution of gypsum from the deeper part of the Upper Floridan aquifer or the middle confining unit, saltwater in the aquifer, and saline waters from the middle confining unit and Lower Floridan aquifer. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated for the Peace and Myakka River Basins and adjacent coastal areas of southwest Florida. Samples were collected from 63 wells and a saline spring, including wells finished at different depth intervals of the Upper Floridan aquifer and intermediate aquifer system at about 25 locations. Sampling focused along three ground-water flow paths (selected based on a predevelopment potentiometric-surface map). Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (delta deuterium, oxygen-18, carbon-13 of inorganic carbon, and sulfur-34 of sulfate and sulfide); the ratio of strontium-87 to strontium-86 was analyzed for waters along one of the flow paths. Chemical and isotopic data indicate that dedolomitization reactions (gypsum and dolomite dissolution and calcite precipitation) control the chemical composition of water in the Upper Floridan aquifer in inland areas. This is confirmed by mass-balance modeling between wells in the shallowest interval in the aquifer along the flow paths. However, gypsum occurs deeper in the aquifer than these wells. Upwelling of sulfate-rich water that previously dissolved gypsum in deeper parts of the aquifer is a more likely source of sulfate than gypsum dissolution in shallow parts of the aquifer. This deep ground water moves to shallower zones in the aquifer discharge area. Saltwater from the Upper Floridan aquifer

  12. Longitudinal dispersion with time-dependent source concentration in semi-infinite aquifer

    Mritunjay Kumar Singh; Nav Kumar Mahato; Premlata Singh


    An analytical solution is obtained to predict the contaminant concentration along unsteady ground-water flow in semi-in finite aquifer. Initially,the aquifer is not supposed to be solute free ,i.e.,aquifer is not clean.A time-dependent source concentration is considered at the origin of the aquifer and at the other end of the aquifer, it is supposed to be zero. The time-dependent forms of unsteady velocities are considered in which one such form ,i.e., sinusoidal form represents the seasonal pattern in a year in tropical regions. The Laplace Transformation Technique (LTT)is used to get an analytical solution and a graphical representation is made through MATLAB.

  13. Defense Contracting: DOD’s Use of Class Justifications for Sole-Source Contracts


    under these class justifications included: • The Army’s Counter Narco -Terrorism Program covered technology development and application, training... Narco -Terrorism Program $0 – no cost modification one responsible source Counter Narco - Terrorism Army Counter Narcotics Transnational Threats...Project Not identifiable one responsible source Counter Narco - Terrorism Air Force Local Exchange Services (dial tone) $3 Unusual and

  14. Functional diversity of the microbial community in healthy subjects and periodontitis patients based on sole carbon source utilization.

    Yifei Zhang

    Full Text Available Chronic periodontitis is one of the most common forms of biofilm-induced diseases. Most of the recent studies were focus on the dental plaque microbial diversity and microbiomes. However, analyzing bacterial diversity at the taxonomic level alone limits deeper comprehension of the ecological relevance of the community. In this study, we compared the metabolic functional diversity of the microbial community in healthy subjects and periodontitis patients in a creative way--to assess the sole carbon source utilization using Biolog assay, which was first applied on oral micro-ecology assessment. Pattern analyses of 95-sole carbon sources catabolism provide a community-level phenotypic profile of the microbial community from different habitats. We found that the microbial community in the periodontitis group had greater metabolic activity compared to the microbial community in the healthy group. Differences in the metabolism of specific carbohydrates (e.g. β-methyl-D-glucoside, stachyose, maltose, D-mannose, β-methyl-D-glucoside and pyruvic acid were observed between the healthy and periodontitis groups. Subjects from the healthy and periodontitis groups could be well distinguished by cluster and principle component analyses according to the utilization of discriminate carbon sources. Our results indicate significant difference in microbial functional diversity between healthy subjects and periodontitis patients. We also found Biolog technology is effective to further our understanding of community structure as a composite of functional abilities, and it enables the identification of ecologically relevant functional differences among oral microbial communities.

  15. Astaxanthin hyperproduction by Phaffia rhodozyma (now Xanthophyllomyces dendrorhous) with raw coconut milk as sole source of energy.

    Domíguez-Bocanegra, A R; Torres-Muñoz, J A


    Natural carbon sources, such as those present in cane sugar molasses and grape juice, promote the synthesis of astaxanthin in different Phaffia rhodozyma yeasts. One of these, coconut milk, has a very rich nutrient composition. The aim of this work was to investigate the utility of coconut milk as sole source of energy for astaxanthin pigment production by P. rhodozyma strains. Currently, coconut pulp is widely used in industrial processes in Mexico for the production of shampoos, candies, food, etc. However, coconut milk is a waste product. We show that coconut milk enhances astaxanthin production. The fermentation yielded 850 microg/g yeast with the NRRL-10921 wild-type strain and 1850 microg/g yeast with the mutated R1 strain. Production was better than reported results employing other natural carbon sources.


    Teresa Krzyśko-Łupicka


    The results of growth kinetics of the studied Fusarium fungi in the presence of N-(2-pirydyloamino methyle-nobisphosphonic acid, were expressed by dry weight [g·dm-3]. Only Fusarium oxysporum XVI has been capa-ble to grow in acidic medium (pH 4.0 using N-(2-pirydylamino methylene-bisphosphonic acid as an alterna-tive source of phosphorus. In these conditions the N-(2-pirydylamino methylenebisphosphonic acid degrada-tion was carried out to utilize phosphorus compounds as a source of nutrient components for this strain. The presence of N-(2-pirydylamino methylenebisphosphonic acid receded a growth rate of mycelium but did not have an effect on spores of tested fungi.

  17. The activated sludge metabolic characteristics changing sole carbon source from readily biodegradable acetate to toxic phenol.

    Wu, Changyong; Zhou, Yuexi; Song, Jiamei


    A sequencing batch reactor was used to investigate the effect of carbon sources on the metabolism of activated sludge. Acetate and phenol, with the chemical oxygen demand (COD) of 330-350 mg L(-1), was used as the carbon source in Periods I and II, respectively. Acetate decreased in the initial 120 min with the intracellular storage materials (XSTO), extracellular polymeric substances (EPS), and the soluble microbial products (SMP) accumulating to 131.0 mg L(-1), 347.5 mg L(-1), and 35.5 mg L(-1), respectively. Then, XSTO and EPS decreased to 124.5 mg L(-1) and 340.0 mg L(-1), respectively, in the following 120 min. When acetate was replaced by phenol, it could not be used at the beginning due to its toxicity. The XSTO decreased from 142 mg L(-1) to 54.6 mg L(-1) during the aeration period. The EPS had a significant increase, with the highest value of 618.1 mg L(-1), which then decreased to 245.6 mg L(-1) at 240 min. The phenol was gradually degraded with the acclimation and it can be fully degraded 18 d later. Meanwhile, the usage ratio of the internal carbon source decreased. The effluent SMP in Period II was 1.7 times that in Period I.

  18. Macroscopic Thermal Energy Balance on Montane Valley Aquifers and Groundwater Recharge Source Identification

    Trask, J. C.; Fogg, G. E.


    Several recent publications have highlighted the need to improve definition of groundwater flow patterns in montane regions, presenting case studies with several field investigative approaches. Determination of the depth of upland bedrock groundwater circulation and identification of valley aquifer recharge sources in montane areas is needed for improved characterization of montane groundwater flow patterns and for aquifer source protection planning. In most upland bedrock regions, wells and boreholes are scarce, adding to the challenges inherent to investigating groundwater flow in fractured rock systems. Approaches using natural environmental tracers have previously been shown to be effective in quantifying subsurface recharge into valley aquifers from groundwater flow within adjoining mountain-front and mountain-block areas. Thermal tracing of montane groundwater flow is easy and inexpensive relative to other environmental tracer and geophysical techniques, and can complement other approaches (e.g. Manning and Solomon, 2005). We present a heat flow tracer approach to identification of montane valley aquifer recharge sources. A novel application of a macroscopic thermal energy balance is introduced and used in recharge source analysis for two mountain-front bounding basin-fill aquifers located in the Sierra Nevada, USA. We show that robust upper and lower bounds on total heat flow and sources of recharge into montane valley aquifers may be determined without numerical modeling by using a macroscopic thermal energy balance. Several factors tend to enhance focusing of geothermal conductive heat flow from depth toward montane valley margins. Analytic bracketing techniques, applicable to domains with irregular boundary geometry and non-uniform thermal boundary conditions, are used together with thermal data to obtain quantitative bounds on conductive heat flow across aquifer domain boundaries. Thermal data required include: (i) a rough estimate of regional geothermal

  19. Biodegradation and utilization of 4-n-nonylphenol by Aspergillus versicolor as a sole carbon and energy source

    Krupiński, Mariusz; Janicki, Tomasz [Department of Industrial Microbiology and Biotechnology, University of Lodz, Banacha 12/16, 90-237 Łódź (Poland); Pałecz, Bartłomiej [Department of Physical Chemistry, University of Lodz, Pomorska 165, 90-236 Łódź (Poland); Długoński, Jerzy, E-mail: [Department of Industrial Microbiology and Biotechnology, University of Lodz, Banacha 12/16, 90-237 Łódź (Poland)


    Highlights: • A. versicolor is able to degrade 4-n-NP as the sole source of carbon and energy. • 4-n-NP removal by A. versicolor was accompanied by the formation of metabolites. • Radioactive experiments show complete 4-n-NP mineralization by A. versicolor. • 4-n-NP initiates heat production in the A. versicolor spores. - Abstract: 4-n-Nonylphenol (4-n-NP) is an environmental pollutant with endocrine-disrupting activities that is formed during the degradation of nonylphenol polyethoxylates, which are widely used as surfactants. Utilization of 4-n-NP by the filamentous fungus Aspergillus versicolor as the sole carbon and energy source was investigated. By means of gas chromatography–mass spectrometry, we showed that in the absence of any carbon source other than 4-n-NP in the medium, A. versicolor completely removed the xenobiotic (100 mg L{sup −1}) after 3 d of cultivation. Moreover, mass spectrometric analysis of intracellular extracts led to the identification of eight intermediates. The mineralization of the xenobiotic in cultures supplemented with 4-n-NP [ring-{sup 14}C(U)] as a growth substrate was also assessed. After 3 d of incubation, approximately 50% of the initially applied radioactivity was recovered in the form of {sup 14}CO{sub 2}, proving that this xenobiotic was completely metabolized and utilized by A. versicolor as a carbon source. Based on microscopic analysis, A. versicolor is capable of germinating spores under such conditions. To confirm these observations, a microcalorimetric method was used. The results show that even the highest amount of 4-n-NP initiates heat production in the fungal samples, proving that metabolic processes were affected by the use of 4-n-NP as an energetic substrate.

  20. Sources of salinity and urban pollution in the Quaternary sand aquifers of Dar es Salaam, Tanzania

    Walraevens, Kristine; Mjemah, Ibrahimu Chikira; Mtoni, Yohana; Van Camp, Marc


    Groundwater is globally important for human consumption, and changes in quality can have serious consequences. The study area is within a coastal aquifer where groundwater quality is influenced by various potential sources of salinity that determine the composition of water extracted from wells. Groundwater chemistry data from the aquifer have been acquired to determine the geochemical conditions and processes that occur in this area and assess their implications for aquifer susceptibility. Analysis of groundwater samples shows that the dominant watertype is mostly NaCl with pH coral reef limestone deposits are located and the watertype evolves towards CaHCO3. In the lower aquifer, Cl- is higher than in the upper aquifer. The origin of salinity in the area is strongly influenced by groundwater ascending from deep marine Miocene Spatangid Shales through faults, seawater incursion on the border of the Indian Ocean, and throughout, there is some salinity within the Quaternary aquifer, especially in intercalated deltaic clays in the fluviatile deposits, showing some marine influences. The seawater intrusion is linked to the strongly increasing groundwater exploitation since 1997. Another process that plays a major role to the concentration of major ions in the groundwater is calcite dissolution. Next to geogenic salinity and seawater intrusion, anthropogenic pollution as well is affecting groundwater quality in the aquifer. An important result of this study is the observation of high nitrate concentrations, that call for improved sanitation in the area, where domestic sewage with on-site sanitation (mainly pit latrines) also threatens the groundwater resource.

  1. A bacterium capable of using phytol as its sole carbon source, isolated from algal sediment of Mud Lake, Florida.

    Hoag, K B; Bradley, W H; Tousimis, A J; Price, D L


    A species of Flavobacterium that consistently attacks pure phytol and can use it as a sole source of carbon has been isolated from the blue-green algal sediment of Mud Lake, Florida. Biochemical tests demonstrate that this bacterium also readily uses various other organic compounds. This bacterium may account for the degradation products of chlorophyll and its side chain phytol, which have been found in the Mud Lake algal sediment. Phytol and its degradation products play a role in Refsum's disease, but phytol is also the most promising precursor of the isoprenoid hydrocarbons found in oil shale of the Green River Formation (Eocene) of Colorado, Utah, and Wyoming. The discovery of this species of Flavobacterium is a significant product of a protracted study of the bacteriology, phycology, zoology, and geochemistry of the algal sediment forming in Mud Lake, which is believed to be a modern analogue of the kind of algal sediment that, through geologic time, became oil shale.

  2. Degradation of o-chloronitrobenzene as the sole carbon and nitrogen sources by Pseudomonas putida OCNB-1

    WU Haizhen; WEI Chaohai; WAMG Yaqin; HE Qincong; LIANG Shizhong


    A bacterial strain that utilized o-chloronitrobenzene (o-CNB) as the sole carbon, nitrogen and energy sources was isolated from an activated sludge collected from an industrial waste treatment plant. It was identified as Pseudomonas putida based on its morphology, physiological, and biochemical characteristics with an automatic biometrical system and the 16S rRNA sequence analysis. Microcosm study showed that the biodegradation of o-CNB was optimized at culture medium pH 8.0 and temperature of 32℃. At these conditions, the strain degraded 85% of o-CNB at a starting concentration of 1.1 mmol/L in 42 h. o-Chloroaniline was identified as the major metabolite with both high performance liquid chromatography (HPLC) and gas chromatography-mass spectrometry (GC-MS). The study showed that o-chloronitrobenzene degradation by Pseudomonas putida OCNB-1 was initiated by aniline dioxyenase, nitrobenzene reductase and catechol-1,2-dioxygenase.

  3. Growth of the yeast Kluyveromyces marxianus CBS 6556 on different sugar combinations as sole carbon and energy source.

    Fonseca, Gustavo Graciano; de Carvalho, Nuno Miguel Barbosa; Gombert, Andreas Karoly


    The yeast Kluyveromyces marxianus has been pointed out as a promising microorganism for a variety of industrial bioprocesses. Although genetic tools have been developed for this yeast and different potential applications have been investigated, quantitative physiological studies have rarely been reported. Here, we report and discuss the growth, substrate consumption, metabolite formation, and respiratory parameters of K. marxianus CBS 6556 during aerobic batch bioreactor cultivations, using a defined medium with different sugars as sole carbon and energy source, at 30 and 37 °C. Cultivations were carried out both on single sugars and on binary sugar mixtures. Carbon balances closed within 95 to 101 % in all experiments. Biomass and CO2 were the main products of cell metabolism, whereas by-products were always present in very low proportion (<3 % of the carbon consumed), as long as full aerobiosis was guaranteed. On all sugars tested as sole carbon and energy source (glucose, fructose, sucrose, lactose, and galactose), the maximum specific growth rate remained between 0.39 and 0.49 h(-1), except for galactose at 37 °C, which only supported growth at 0.31 h(-1). Different growth behaviors were observed on the binary sugar mixtures investigated (glucose and lactose, glucose and galactose, lactose and galactose, glucose and fructose, galactose and fructose, fructose and lactose), and the observations were in agreement with previously published data on the sugar transport systems in K. marxianus. We conclude that K. marxianus CBS 6556 does not present any special nutritional requirements; grows well in the range of 30 to 37 °C on different sugars; is capable of growing on sugar mixtures in a shorter period of time than Saccharomyces cerevisiae, which is interesting from an industrial point of view; and deviates tiny amounts of carbon towards metabolite formation, as long as full aerobiosis is maintained.

  4. Investigating sources and pathways of perfluoroalkyl acids (PFAAs) in aquifers in Tokyo using multiple tracers.

    Kuroda, Keisuke; Murakami, Michio; Oguma, Kumiko; Takada, Hideshige; Takizawa, Satoshi


    We employed a multi-tracer approach to investigate sources and pathways of perfluoroalkyl acids (PFAAs) in urban groundwater, based on 53 groundwater samples taken from confined aquifers and unconfined aquifers in Tokyo. While the median concentrations of groundwater PFAAs were several ng/L, the maximum concentrations of perfluorooctane sulfonate (PFOS, 990 ng/L), perfluorooctanoate (PFOA, 1800 ng/L) and perfluorononanoate (PFNA, 620 ng/L) in groundwater were several times higher than those of wastewater and street runoff reported in the literature. PFAAs were more frequently detected than sewage tracers (carbamazepine and crotamiton), presumably owing to the higher persistence of PFAAs, the multiple sources of PFAAs beyond sewage (e.g., surface runoff, point sources) and the formation of PFAAs from their precursors. Use of multiple methods of source apportionment including principal component analysis-multiple linear regression (PCA-MLR) and perfluoroalkyl carboxylic acid ratio analysis highlighted sewage and point sources as the primary sources of PFAAs in the most severely polluted groundwater samples, with street runoff being a minor source (44.6% sewage, 45.7% point sources and 9.7% street runoff, by PCA-MLR). Tritium analysis indicated that, while young groundwater (recharged during or after the 1970s, when PFAAs were already in commercial use) in shallow aquifers (groundwater (recharged before the 1950s, when PFAAs were not in use) in deep aquifers (50-500 m depth). This study demonstrated the utility of multiple uses of tracers (pharmaceuticals and personal care products; PPCPs, tritium) and source apportionment methods in investigating sources and pathways of PFAAs in multiple aquifer systems.

  5. Investigating sources and pathways of perfluoroalkyl acids (PFAAs) in aquifers in Tokyo using multiple tracers

    Kuroda, Keisuke, E-mail: [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Murakami, Michio [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Oguma, Kumiko [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Takada, Hideshige [Laboratory of Organic Geochemistry (LOG), Institute of Symbiotic Science and Technology, Tokyo University of Agriculture and Technology, Fuchu, Tokyo 183-8509 (Japan); Takizawa, Satoshi [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan)


    We employed a multi-tracer approach to investigate sources and pathways of perfluoroalkyl acids (PFAAs) in urban groundwater, based on 53 groundwater samples taken from confined aquifers and unconfined aquifers in Tokyo. While the median concentrations of groundwater PFAAs were several ng/L, the maximum concentrations of perfluorooctane sulfonate (PFOS, 990 ng/L), perfluorooctanoate (PFOA, 1800 ng/L) and perfluorononanoate (PFNA, 620 ng/L) in groundwater were several times higher than those of wastewater and street runoff reported in the literature. PFAAs were more frequently detected than sewage tracers (carbamazepine and crotamiton), presumably owing to the higher persistence of PFAAs, the multiple sources of PFAAs beyond sewage (e.g., surface runoff, point sources) and the formation of PFAAs from their precursors. Use of multiple methods of source apportionment including principal component analysis–multiple linear regression (PCA–MLR) and perfluoroalkyl carboxylic acid ratio analysis highlighted sewage and point sources as the primary sources of PFAAs in the most severely polluted groundwater samples, with street runoff being a minor source (44.6% sewage, 45.7% point sources and 9.7% street runoff, by PCA–MLR). Tritium analysis indicated that, while young groundwater (recharged during or after the 1970s, when PFAAs were already in commercial use) in shallow aquifers (< 50 m depth) was naturally highly vulnerable to PFAA pollution, PFAAs were also found in old groundwater (recharged before the 1950s, when PFAAs were not in use) in deep aquifers (50–500 m depth). This study demonstrated the utility of multiple uses of tracers (pharmaceuticals and personal care products; PPCPs, tritium) and source apportionment methods in investigating sources and pathways of PFAAs in multiple aquifer systems. - Highlights: • Aquifers in Tokyo had high levels of perfluoroalkyl acids (up to 1800 ng/L). • PFAAs were more frequently detected than sewage

  6. Isolation of bacteria capable of growth with 2-methylisoborneol and geosmin as the sole carbon and energy sources.

    Guttman, Lior; van Rijn, Jaap


    Using a relatively simple enrichment technique, geosmin and 2-methylisoborneol (MIB)-biodegrading bacteria were isolated from a digestion basin in an aquaculture unit. Comparison of 16S rRNA gene sequences affiliated one of the three isolates with the Gram-positive genus Rhodococcus, while the other two isolates were found to be closely related to the Gram-negative family Comamonadaceae (Variovorax and Comamonas). Growth rates and geosmin and MIB removal rates by the isolates were determined under aerated and nonaerated conditions in mineral medium containing either of the two compounds as the sole carbon and energy source. All isolates exhibited their fastest growth under aerobic conditions, with generation times ranging from 3.1 to 5.7 h, compared to generation times of up to 19.1 h in the nonaerated flasks. Incubation of the isolates with additional carbon sources caused a significant increase in their growth rates, while removal rates of geosmin and MIB were significantly lower than those for incubation with only geosmin or MIB. By fluorescence in situ hybridization, members of the genera Rhodococcus and Comamonas were detected in geosmin- and MIB-enriched sludge from the digestion basin.

  7. Investigation of Firn Aquifer Structure in Southeastern Greenland Using Active Source Seismology

    Montgomery, Lynn N.; Schmerr, Nicholas; Burdick, Scott; Forster, Richard R.; Koenig, Lora; Legchenko, Anatoly; Ligtenberg, Stefan; Miège, Clément; Miller, Olivia L.; Solomon, D. Kip


    In spring of 2011, a perennial storage of water was observed in the firn of the southeastern Greenland ice sheet, a region of both high snow accumulation and high melt. This aquifer is created through percolation of surface meltwater downward through the firn, saturating the pore space above the ice-firn transition. The aquifer may play a significant role in sea level rise through storage or draining freshwater into the ocean. We carried out a series of active source seismic experiments using continuously refracted P-waves and inverted the first P-arrivals using a transdimensional Bayesian approach where the depth, velocity, and number of layers are allowed to vary to identify the seismic velocities associated with the base of the aquifer. When our seismic approach is combined with a radar sounding of the water table situated at the top of the firn aquifer, we are able to quantify the volume of water present. In our study region, the base of the aquifer lies on average 27.7±2.9 m beneath the surface, with an average thickness of 11.5±5.5 m. Using a Wyllie average for porosity, we found the aquifer has an average water content of 16±8%, with considerable variation in water storage capacity along the studied east-west flow line, 40 km upstream of the Helheim glacier terminus. Between 2015 and 2016, we observed a 1-2 km uphill expansion of the aquifer system, with a site dry in summer 2015 exhibiting a water content of 530 kg m-2 in summer 2016. We estimate the volume of water stored in the aquifer across the entire region upstream of Helheim glacier to be 4.7±3.1 Gt, approximately 3% of the total water stored in firn aquifers across the Greenland ice sheet. Elucidating the volume of water stored within these recently discovered aquifers is vital for determining the hydrological structure and stability of the southeastern Greenland ice sheet.

  8. Light intensity and quality from sole-source light-emitting diodes impact growth, morphology, and nutrient content of Brassica microgreens

    Multi-layer vertical production systems using sole-source (SS) lighting can be used for microgreen production; however, traditional SS lighting can consume large amounts of electrical energy. Light-emitting diodes (LEDs) offer many advantages over conventional light sources including: high photoelec...

  9. Techniques for Source Zone and Plume Characterization of Tetrachloroethene in Fractured Limestone Aquifers

    Fjordbøge, Annika Sidelmann; Mosthaf, Klaus; Janniche, Gry S.;

    Characterization of chlorinated solvents in fractured limestone aquifers is essential for proper development of site specific conceptual models and subsequent risk assessment and remediation. High resolution characterization is challenged by the difficulties involved in collection of intact core...... samples as water flushing during drilling often results in extensive core losses, especially from zones with soft limestone in contact with flint beds. Field investigations with alternative characterization techniques have been carried out at two Danish sites with tetrachloroethene (PCE) contaminated...... fractured limestone aquifers. The two sites represent different scales (source and plume) and contaminant levels (DNAPL and dissolved). The scope of the investigations was to evaluate different techniques for characterization of the contaminant distribution in the limestone aquifers and to obtain...

  10. Isolation and characterization of a Sinorhizobium fredii mutant that cannot utilize proline as the sole carbon and nitrogen source

    HUANG Sheng; BAI Xueliang; MA Qingsheng; TANG Xianlai; WU Bo


    Sinorhizobium fredii strain HN01 can use proline as the sole carbon and nitrogen source. A mutant strain GXHN100 unable to catabolize proline was screened from 6000 Tn5gusA5 random insertional mutants of S.fredii strain HN01. Sequencing analysis showed that an open reading frame, named pmrA (proline metabolic relative), was inserted by the Tn5gusA5. A positive clone, named pGXHN100 which containing 3.3kb foreign DNA fragment of S.fredii strain HN01, was isolated from a partial gene library of S.fredii HN01 by colony in situ hybridization. Sequence analysis showed that pGXHN100 contained the entire pmrA gene. The 3.3kb DNA fragment of pGXHN100 was cloned into a broad-host-range cosmid vector pLAFR3 to form plasmid pGXHN200 which was subsequently introduced into GXHN100 to form a complemented strain GXHN200. Plant test showed that GXHN100 was effective and no obvious changes in nitrogenase activity comparing with parental strain. But GXHN100 nodulated 2 days later on soybean and its nodulation efficiency and competitiveness were decreased. The complemented strain GXHN200 restored the nodulation efficiency and competitiveness of GXHN100 to the wild type.

  11. Water Supply Source Evaluation in Unmanaged Aquifer Recharge Zones: The Mezquital Valley (Mexico Case Study

    Antonio Hernández-Espriú


    Full Text Available The Mezquital Valley (MV hosts the largest unmanaged aquifer recharge scheme in the world. The metropolitan area of Mexico City discharges ~60 m3/s of raw wastewater into the valley, a substantial share of which infiltrates into the regional aquifer. In this work, we aim to develop a comprehensive approach, adapted from oil and gas reservoir modeling frameworks, to assess water supply sources located downgradient from unmanaged aquifer recharge zones. The methodology is demonstrated through its application to the Mezquital Valley region. Geological, geoelectrical, petrophysical and hydraulic information is combined into a 3D subsurface model and used to evaluate downgradient supply sources. Although hydrogeochemical variables are yet to be assessed, outcomes suggest that the newly-found groundwater sources may provide a long-term solution for water supply. Piezometric analyses based on 25-year records suggest that the MV is close to steady-state conditions. Thus, unmanaged recharge seems to have been regulating the groundwater balance for the last decades. The transition from unmanaged to managed recharge is expected to provide benefits to the MV inhabitants. It will also be likely to generate new uncertainties in relation to aquifer dynamics and downgradient systems.

  12. Aquifers survey in the context of source rocks exploitation: from baseline acquisition to long term monitoring

    Garcia, Bruno; Rouchon, Virgile; Deflandre, Jean-Pierre


    Producing hydrocarbons from source rocks (like shales: a mix of clays, silts, carbonate and sandstone minerals containing matured organic matter, i.e. kerogen oil and gas, but also non-hydrocarbon various species of chemical elements including sometimes radioactive elements) requires to create permeability within the rock matrix by at least hydraulically fracturing the source rock. It corresponds to the production of hydrocarbon fuels that have not been naturally expelled from the pressurized matured source rock and that remain trapped in the porosity or/and kerogen porosity of the impermeable matrix. Azimuth and extent of developed fractures can be respectively determined and mapped by monitoring the associated induced microseismicity. This allows to have an idea of where and how far injected fluids penetrated the rock formation. In a geological context, aquifers are always present in the vicinity -or on fluid migration paths- of such shale formations: deep aquifers (near the shale formation) up to sub-surface and potable (surface) aquifers. Our purpose will be to track any unsuitable invasion or migration of chemicals specifies coming from matured shales of production fluids including both drilling and fracturing ones into aquifers. Our objective is to early detect and alarm of any anomaly to avoid any important environmental issue. The approach consists in deploying a specific sampling tool within a well to recover formation fluids and to run a panoply of appropriate laboratory tests to state on fluid characteristics. Of course for deep aquifers, such a characterization process may consider aquifer properties prior producing shale oil and gas, as they may contain naturally some chemical species present in the source rocks. One can also consider that a baseline acquisition could be justified in case of possible previous invasion of non-natural fluids in the formation under survey (due to any anthropogenic action at surface or in the underground). The paper aims

  13. Old Soles

    Yu Yan


    Amid the rhythmic tap-dance of production inside Neiliansheng's factory in Xicheng District of Beijing,He Kaiying,a master of Neiliansheng cloth shoes,was teaching an apprentice to draw the outline of a sole.The 56-year-old senior shoemaker guides three young apprentices,passing on traditional shoemaking skills that have been in place since the company's establishment. Neiliansheng,which means "unstopped promotions in official ranks" in Chinese,is a classic cloth shoe brand created in Beijing in 1853.It once provided shoes for emperors and royal court officials.At that time,wearing the court shoes of Neiliansheng was a fashion statement in Beijing and a mark of high status.

  14. Source, extent, and degradation of herbicides in a shallow aquifer near Hesston, Kansas

    Perry, C.A.


    Atrazine, alachlor, cyanazine, metolachlor, and metribuzin were detected in water from a domestic well completed in a shallow aquifer underlying the Harvey County Experiment Field near Hesston, Kansas. The study described in this report investigated the source, extent, and degradation of these five herbicides. Hydrogeologic analysis of the site enabled estimation of the degradation half-lives of the herbicides in the saturated zone. The most probable source of the contamination was back- siphonage or spillage of herbicides from a sprayer tank into a trench backfilled with sand. The herbicides moved downgradient to the domestic well and then moved into the aquifer via the annular space in the well. Once in the aquifer, the contaminants remained nearly stationary with very little lateral movement away from the point of injection. Decreases in herbicide concentrations were caused mainly by degradation of the parent compounds and to a lesser degree, by extensive pumping of the well. Estimated herbicide degradation half-lives in the saturated environment were 1,000 days for atrazine, 400 days for alachlor, 250 days for cyanazine, 350 days for metolachlor, and 350 days for metribuzin. The herbicides will likely be eliminated from the soil and groundwater at the experiment field by continued natural degradation at the land surface and by degradation in and continued pumping of water from the aquifer. Pumping will remove any degradation products as well as the remaining parent compounds. (USGS)

  15. Denitrification and inference of nitrogen sources in the karstic Floridan Aquifer

    Heffernan, J.B.; Albertin, A.R.; Fork, M.L.; Katz, B.G.; Cohen, M.J.


    Aquifer denitrification is among the most poorly constrained fluxes in global and regional nitrogen budgets. The few direct measurements of denitrification in groundwaters provide limited information about its spatial and temporal variability, particularly at the scale of whole aquifers. Uncertainty in estimates of denitrification may also lead to underestimates of its effect on isotopic signatures of inorganic N, and thereby confound the inference of N source from these data. In this study, our objectives are to quantify the magnitude and variability of denitrification in the Upper Floridan Aquifer (UFA) and evaluate its effect on N isotopic signatures at the regional scale. Using dual noble gas tracers (Ne, Ar) to generate physical predictions of N2 gas concentrations for 112 observations from 61 UFA springs, we show that excess (i.e. denitrification-derived) N2 is highly variable in space and inversely correlated with dissolved oxygen (O2). Negative relationship between O2 and ??15NNO 3 across a larger dataset of 113 springs, well-constrained isotopic fractionation coefficients, and strong 15N: 18O covariation further support inferences of denitrification in this uniquely organic-matter-poor system. Despite relatively low average rates, denitrification accounted for 32% of estimated aquifer N inputs across all sampled UFA springs. Back-calculations of source ??15NNO 3 based on denitrification progression suggest that isotopically-enriched nitrate (NO3-) in many springs of the UFA reflects groundwater denitrification rather than urban- or animal-derived inputs. ?? Author(s) 2011.

  16. Improved biological phosphorus removal performance driven by the aerobic/extended-idle regime with propionate as the sole carbon source.

    Wang, Dongbo; Li, Xiaoming; Yang, Qi; Zheng, Wei; Wu, Yan; Zeng, Tianjing; Zeng, Guangming


    Our previous studies proved that biological phosphorus removal (BPR) could be achieved in an aerobic/extended-idle (AEI) process employing two typical substrates of glucose and acetate as the carbon sources. This paper further evaluated the feasibility of another important substrate, propionate, serving as the carbon source for BPR in the AEI process, and compared the BPR performance between the AEI and anaerobic/oxic (A/O) processes. Two sequencing batch reactors (SBRs) were operated, respectively, as the AEI and A/O regimes for BPR using propionate as the sole substrate. The results showed that the AEI-reactor removed 2.98 ± 0.04-4.06 ± 0.06 mg of phosphorus per g of total suspended solids during the course of the steady operational trial, and the phosphorus content of the dried sludge was reached 8.0 ± 0.4% after 56-day operation, demonstrating the good performance of phosphorus removal. Then, the efficiencies of BPR and the transformations of the intracellular storages were compared between two SBRs. It was observed that the phosphorus removal efficiency was maintained around 95% in the AEI-reactor, and about 83% in the A/O-reactor, although the latter showed much greater transformations of both polyhydroxyalkanoates and glycogen. The facts clearly showed that BPR could be enhanced by the AEI regime using propionate as the carbon source. Finally, the mechanisms for the propionate fed AEI-reactor improving BPR were investigated. It was found that the sludge cultured by the AEI regime had more polyphosphate containing cells than that by the A/O regime. Further investigation revealed that the residual nitrate generated in the last aerobic period was readily deteriorated BPR in the A/O-SBR, but a slight deterioration was observed in the AEI-SBR. Moreover, the lower glycogen transformation measured in the AEI-SBR indicated that the biomass cultured by the AEI regime contained less glycogen accumulating organisms activities than that by the A/O regime

  17. Microrespirometric determination of the effectiveness factor and biodegradation kinetics of aerobic granules degrading 4-chlorophenol as the sole carbon source

    Vital-Jacome, Miguel [Department of Biotechnology and Bioengineering, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (Cinvestav-IPN), Av. IPN 2508, 07360 México DF, México (Mexico); Buitrón, Germán; Moreno-Andrade, Ivan; Garcia-Rea, Victor [Laboratory for Research on Advanced Process for Water Treatment, Unidad Académica Juriquilla, Instituto de Ingeniería, Universidad Nacional Autónoma de México, Blvd. Juriquilla 3001, Querétaro 76320, México (Mexico); Thalasso, Frederic, E-mail: [Department of Biotechnology and Bioengineering, Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional (Cinvestav-IPN), Av. IPN 2508, 07360 México DF, México (Mexico)


    Highlights: • Microrespirometry was used to characterize aerobic granules. • Kinetic parameters for 4-chorophenol degradation were determined. • Intrinsic and apparent kinetic parameters were quantified and contrasted. • Aerobic granules presented lower μ{sub max} and higher K{sub S} than disaggregated granules. • Microrespirometry can be useful in model development and calibration. - Abstract: In this study, a microrespirometric method was used, i.e., pulse respirometry in microreactors, to characterize mass transfer and biodegradation kinetics in aerobic granules. The experimental model was an aerobic granular sludge in a sequencing batch reactor (SBR) degrading synthetic wastewater containing 4-chlorophenol as the sole carbon source. After 15 days of acclimation, the SBR process degraded 4-chlorophenol at a removal rate of up to 0.9 kg COD m{sup −3} d{sup −1}, and the degradation kinetics were well described by the Haldane model. The microrespirometric method consisted of injecting pulses of 4-chlorophenol into the 24 wells of a microreactor system containing the SBR samples. From the respirograms obtained, the following five kinetic parameters were successfully determined during reactor operation: (i) Maximum specific oxygen uptake rate, (ii) substrate affinity constant, (iii) substrate inhibition constant, (iv) maximum specific growth rate, and (v) cell growth yield. Microrespirometry tests using granules and disaggregated granules allowed for the determination of apparent and intrinsic parameters, which in turn enabled the determination of the effectiveness factor of the granular sludge. It was concluded that this new high-throughput method has the potential to elucidate the complex biological and physicochemical processes of aerobic granular biosystems.

  18. Proliferation and function of microbodies in the nematophagous fungus Arthrobotrys oligospora during growth on oleic acid or D-alanine as the sole carbon source

    Dijksterhuis, Jan; Harder, Willem; Veenhuis, Marten


    The nematophagous fungus Arthrobotrys oligospora is able to grow on oleic acid or D-alanine as the sole carbon source. During growth on oleic acid, activities of enzymes of the beta-oxidation pathway, but not catalase, were induced. In the presence of D-alanine, both D-amino acid oxidase and catalas

  19. Characterization of DNAPL Source Zone Architecture and Associated Plume Response in 2-D Aquifer Cell Experiments

    Granbery, E. K.; Cápiro, N.; Christ, J.; Pennell, K.


    A series of two-dimensional (2-D) aquifer cell experiments was conducted to evaluate the effects of DNAPL source zone architecture on down-gradient plume and flux-averaged effluent concentrations. The aquifer cells (1.0 m length x 48 cm height x 1.4 cm internal thickness) were packed with different size fractions of quartz sands and low permeability lens configurations to achieve a range of source zone saturation distributions. A mixed DNAPL, consisting of 1:1 trichloroethene (TCE) and tetrachloroethene (PCE), was released into the source zone region of the aquifer cell at a flow rate of 2.0 ml/min and allowed to redistribute for a period of 48 hours. The DNAPL saturation distribution was quantified using a light transmission system and characterized by the ganglia-to-pool ratio (GTP, 0 to infinity) and ganglia fraction (GF, 0-100%), where saturations less than 0.13 represent discrete ganglia and saturations equal to or greater than 0.13 are considered to represent "pools". Effluent dissolved-phase TCE and PCE concentrations were monitored continuously, while down-gradient plume concentrations were collected periodically from 25 side-port samples. To accelerate mass removal, the aquifer cells were flushed with 1.5 pore volumes of 4% Tween 80, a nonionic, food-grade surfactant that has been shown to facilitate microbial reductive dechlorination. Experimental data are used to evaluate interrelationships between the initial source zone architecture, mass removal, reductions in mass flux, and plume evolution.

  20. Modeling nonpoint source nitrate contamination and associated uncertainty in groundwater of U.S. regional aquifers

    Gurdak, J. J.; Lujan, C.


    Nonpoint source nitrate contamination in groundwater is spatially variable and can result in elevated nitrate concentrations that threaten drinking-water quality in many aquifers of the United States. Improved modeling approaches are needed to quantify the spatial controls on nonpoint source nitrate contamination and the associated uncertainty of predictive models. As part of the U.S. Geological Survey National Water Quality Assessment Program, logistic regression models were developed to predict nitrate concentrations greater than background in recently recharged (less than 50 years) groundwater in selected regional aquifer systems of the United States; including the Central Valley, California Coastal Basins, Basin and Range, Floridan, Glacial, Coastal Lowlands, Denver Basin, High Plains, North Atlantic Coastal Plain, and Piedmont aquifer systems. The models were used to evaluate the spatial controls of climate, soils, land use, hydrogeology, geochemistry, and water-quality conditions on nitrate contamination. The novel model Raster Error Propagation Tool (REPTool) was used to estimate error propagation and prediction uncertainty in the predictive nitrate models and to determine an approach to reduce uncertainty in future model development. REPTool consists of public-domain, Python-based packages that implement Latin Hypercube sampling within a probabilistic framework to track error propagation in geospatial models and quantitatively estimate the prediction uncertainty of the model output. The presented nitrate models, maps, and uncertainty analysis provide important tools for water-resource managers of regional groundwater systems to identify likely areas and the spatial controls on nonpoint source nitrate contamination in groundwater.

  1. Sources and Movement of Saline Groundwater in a Coastal Aquifer, Southern California, USA

    Anders, R.; Stolp, B. J.; Danskin, W. R.


    Development of local groundwater resources in coastal areas is limited by the presence of saline groundwater. For a study in the San Diego area, a geochemical approach was used to investigate the sources and movement of saline groundwater in the coastal aquifer. Chemical and isotopic data were collected from multiple-depth monitoring-well sites near the San Diego coastline at discrete intervals to depths of more than 650 meters. The groundwater samples were analyzed for major and minor ions, the stable isotopes of hydrogen, oxygen, and strontium, and radioactive isotopes of tritium and carbon-14. Each chemical and isotopic tracer preserves some aspect of the hydrologic history of the groundwater ranging from the chemical characteristics (major and minor ions), to the source of water (stable isotopes of oxygen and hydrogen), to the types of rock encountered in the groundwater flow system (strontium isotopes), to time-since-recharge (tritium and carbon-14). By using sodium-to-calcium mass ratios, in combination with the isotopic data, the occurrence of saline groundwater as a result of seawater intrusion was distinguishable from groundwater in a previously-saline aquifer that has been "flushed" by fresher continental recharge. The systematic analysis of these tracers indicate that the sources and movement of saline groundwater in the coastal San Diego area are dominated by: 1) regional flow of higher-elevation precipitation that recharged many thousands of years ago along deep flowpaths; 2) recharge of local precipitation in relatively shallower portions of the flow system; and 3) intrusion of seawater that primarily entered the aquifer during pre-modern times. Use of multiple chemical and isotopic tracers provides unique insight regarding the processes affecting groundwater quality, enabling local water agencies to assess the groundwater resources in the coastal aquifer and begin to reduce the area's reliance on imported water.

  2. Nitrogen-isotope analysis of groundwater nitrate in carbonate aquifers: Natural sources versus human pollution

    Kreitler, Charles W.; Browning, Lawrence A.


    Results of nitrogen-isotope analyses of nitrate in the waters of the Cretaceous Edwards aquifer in Texas, U.S.A., indicate that the source of the nitrate is naturally-occurring nitrogen compounds in the recharge streams. In contrast, nitrogen isotopes of nitrate in the fresh waters of the Pleistocene Ironshore Formation on Grand Cayman Island, West Indies, indicate that human wastes are the source of the nitrate. The Cretaceous Edwards Limestone is a prolific aquifer that produces principally from fracture porosity along the Balcones Fault Zone. Recharge is primarily by streams crossing the fault zone. Rainfall is ˜ 70 cm yr. -1, and the water table is generally deeper than 30 m below land surface. The δ15 N of 73 samples of nitrate from Edwards waters ranged from + 1.9 to + 10‰ with an average of + 6.2‰. This δ15 N range is within the range of nitrate in surface water in the recharge streams ( δ 15N range = + 1 to + 8.3‰ ) and within the range of nitrate in surface water from the Colorado River, Texas, ( δ 15N range = + 1 to + 11‰ ). No sample was found to be enriched in 15N, which would suggest the presence of nitrate from animal waste ( δ 15N range = + 10 to + 22‰ ). The Ironshore Formation contains a small freshwater lens that is recharged entirely by percolation through the soil. Average rainfall is 165 cm yr. -1, and the water table is within 3 m of land surface. The δ15 N of four nitrate samples from water samples of the Ironshore Formation ranged from + 18 to + 23.9‰, which indicates a cesspool/septictank source of the nitrate. Limestone aquifers in humid environments that are recharged by percolation through the soil appear to be more susceptible to contamination by septic tanks than are aquifers in subhumid environments that feature thick unsaturated sections and are recharged by streams.

  3. Denitrification and inference of nitrogen sources in the karstic Floridan Aquifer

    J. B. Heffernan


    Full Text Available Aquifer denitrification is among the most poorly constrained fluxes in global and regional nitrogen budgets. The few direct measurements of denitrification in groundwaters provide limited information about its spatial and temporal variability, particularly at the scale of whole aquifers. Uncertainty in estimates of denitrification may also lead to underestimates of its effect on isotopic signatures of inorganic N, and thereby confound the inference of N source from these data. In this study, our objectives are to quantify the magnitude and variability of denitrification in the Upper Floridan Aquifer (UFA and evaluate its effect on N isotopic signatures at the regional scale. Using dual noble gas tracers (Ne, Ar to generate physical predictions of N2 gas concentrations for 112 observations from 61 UFA springs, we show that excess (i.e. denitrification-derived N2 is highly variable in space and inversely correlated with dissolved oxygen (O2. Negative relationships between O2 and δ15NNO3 across a larger dataset of 113 springs, well-constrained isotopic fractionation coefficients, and strong 15N:18O covariation further support inferences of denitrification in this uniquely organic-matter-poor system. Despite relatively low average rates, denitrification accounted for 32 % of estimated aquifer N inputs across all sampled UFA springs. Back-calculations of source δ15NNO3 based on denitrification progression suggest that isotopically-enriched nitrate (NO3 in many springs of the UFA reflects groundwater denitrification rather than urban- or animal-derived inputs.

  4. Source and mobility of Rare Earth Elements in a sedimentary aquifer system: Aquitaine basin (Southern France)

    Negrel, P. J.; Petelet-Giraud, E.; Millot, R.; Malcuit, E.


    , middle Eocene, and late Eocene. One important feature, in these confined systems isolated from anthropogenic influence, is the range in salinities by a factor of 10, from 250 mg/L up to 2.5 g/L. The ΣREE, in the range 2-54 ng/L, with a dependence on salinity when expressed in % HCO3 or SO4, reflect the carbonate or evaporite source of REEs. The UCC normalized-REE patterns show a large variability as exemplified by the REE flat patterns-low SREE associated with salinity controlled by HCO3. In the present work, the REEs are investigated in terms of saturation indices, speciation modelling, REE patterns in order to recognize the aquifer type hosting groundwater and decipher the origin of the salinity of the groundwater as some part of the aquifer display in the groundwater concentration of chemical element exceeding the drinking water standard (SO4, F...). Such high concentrations of naturally-occurring substances (e.g. unaffected by human activities) can have negative impacts on groundwater thresholds and deciphering their origin by means of geochemical tools like REE is a remaining challenge.

  5. Mineralization of melamine and cyanuric acid as sole nitrogen source by newly isolated Arthrobacter spp. using a soil-charcoal perfusion method.

    Hatakeyama, Takashi; Takagi, Kazuhiro; Yamazaki, Kenichi; Sakakibara, Futa; Ito, Koji; Takasu, Eiichi; Naokawa, Takuji; Fujii, Kunihiko


    Melamine belongs to the s-triazine family, and industrially used as raw product in many ways all over the world. Melamine has been reported for human harmful effects and detected from some crops, soil and water. To remove melamine from the polluted environment, the efficient melamine-mineralizing microorganisms have been needed. We newly isolated three melamine-degrading bacteria from the same upland soil sample using soil-charcoal perfusion method. These bacteria were classified as Arthrobacter sp. MCO, Arthrobacter sp. CSP and Microbacterium sp. ZEL by 16S rRNA genes sequencing analysis. Both Arthrobacter species completely degraded melamine within 2 days, and consumed melamine as a sole nitrogen source. Both strains also grew in cyanuric acid as sole nitrogen source, and released small quantities of ammonium ions. These strains are the first identified bacteria that can mineralize both melamine and cyanuric acid as sole initial nitrogen source in Arthrobacter sp. Although ammeline and ammelide intermediates were detected, these strains possess none of the known genes encoding melamine degrading enzymes. Since the Arthrobacter strains also degraded melamine in a high pH liquid medium, they present as potential bioremediation agents in melamine-polluted environments.

  6. The use of nitrate isotopes to identify contamination sources in the Bou-Areg aquifer (Morocco)

    Re, Viviana [Ca' Foscari University of Venice, Department of Molecular Sciences and Nanosystems, Dorsoduro 2137, Venice, 30123 (Italy); Sacchi, Elisa [University of Pavia, Department of Earth and Environmental Sciences, Via Ferrata 1, Pavia, 27100 (Italy); Allais, Enrico [ISO4 s.n.c., Via Ferrata 1, Pavia, 27100 (Italy)


    The Bou-Areg coastal aquifer (Morocco) is affected by high nitrate levels in groundwater, with possible consequences for the natural environment and human health. The use of environmental tracers, including δ{sup 15}NNO{sub 3} and δ{sup 18}ONO{sub 3}, allowed identifying the main sources of nitrate contamination in groundwater samples collected in 2010. These are manure and septic effluents, especially in urban areas, and synthetic fertilizers in agricultural areas. This work represents a preliminary step for a more detailed nitrate vulnerability assessment to support groundwater management and protection in the studied region. (authors)

  7. Characterization of a newly isolated freshwater Eustigmatophyte alga capable of utilizing far-red light as its sole light source.

    Wolf, Benjamin M; Niedzwiedzki, Dariusz M; Magdaong, Nikki Cecil M; Roth, Robyn; Goodenough, Ursula; Blankenship, Robert E


    Oxygenic phototrophs typically utilize visible light (400-700 nm) to drive photosynthesis. However, a large fraction of the energy in sunlight is contained in the far-red region, which encompasses light beyond 700 nm. In nature, certain niche environments contain high levels of this far-red light due to filtering by other phototrophs, and in these environments, organisms with photosynthetic antenna systems adapted to absorbing far-red light are able to thrive. We used selective far-red light conditions to isolate such organisms in environmental samples. One cultured organism, the Eustigmatophyte alga Forest Park Isolate 5 (FP5), is able to absorb far-red light using a chlorophyll (Chl) a-containing antenna complex, and is able to grow under solely far-red light. Here we characterize the antenna system from this organism, which is able to shift the absorption of Chl a to >705 nm.


    Chapelle, Francis H.; Knobel, LeRoy L.


    Identifying sources and sinks of dissolved inorganic carbon species is an important step in understanding the geochemistry of ground-water systems. This is particularly important for Atlantic Coastal Plain aquifers because bicarbonate (HCO//3** minus ) is frequently the major dissolved anion. The purpose of this paper is to document the stable carbon isotope composition of dissolved inorganic carbon in the Aquia aquifer, Maryland, and to use this data to help identify sources and sinks of dissolved HCO//3** minus . Subjects covered include hydrogeology, ground-water chemistry, sources and sinks, and others. Refs.

  9. Production of FucoPol by Enterobacter A47 using waste tomato paste by-product as sole carbon source.

    Antunes, Sílvia; Freitas, Filomena; Sevrin, Chantal; Grandfils, Christian; Reis, Maria A M


    Out-of-specification tomato paste, a by-product from the tomato processing industry, was used as the sole substrate for cultivation of the bacterium Enterobacter A47 and production of FucoPol, a value-added fucose-rich extracellular polysaccharide. Among the different tested fed-batch strategies, pH-stat, DO-stat and continuous substrate feeding, the highest production (8.77gL(-1)) and overall volumetric productivity (2.92gL(-1)d(-1)) were obtained with continuous substrate feeding at a constant flow rate of 11gh(-1). The polymer produced had the typical FucoPol composition (37mol% fucose, 27mol% galactose, 23mol% glucose and 12mol% glucuronic acid, with an acyl groups content of 13wt%). The average molecular weight was 4.4×10(6)Da and the polydispersity index was 1.2. This study demonstrated that out-of-specification tomato paste is a suitable low-cost substrate for the production of FucoPol, thus providing a route for the valorization of this by-product into a high-value microbial product.

  10. Utilization of DNA as a Sole Source of Phosphorus, Carbon, and Energy by Shewanella spp.: Ecological and Physiological Implications for Dissimilatory Metal Reduction▿

    Pinchuk, Grigoriy E.; Ammons, Christine; Culley, David E.; Li, Shu-Mei W.; McLean, Jeff S.; Romine, Margaret F.; Nealson, Kenneth H.; Fredrickson, Jim K.; Beliaev, Alexander S.


    The solubility of orthophosphate (PO43−) in iron-rich sediments can be exceedingly low, limiting the bioavailability of this essential nutrient to microbial populations that catalyze critical biogeochemical reactions. Here we demonstrate that dissolved extracellular DNA can serve as a sole source of phosphorus, as well as carbon and energy, for metal-reducing bacteria of the genus Shewanella. Shewanella oneidensis MR-1, Shewanella putrefaciens CN32, and Shewanella sp. strain W3-18-1 all grew with DNA but displayed different growth rates. W3-18-1 exhibited the highest growth rate with DNA. While strain W3-18-1 displayed Ca2+-independent DNA utilization, both CN32 and MR-1 required millimolar concentrations of Ca2+ for growth with DNA. For S. oneidensis MR-1, the utilization of DNA as a sole source of phosphorus is linked to the activities of extracellular phosphatase(s) and a Ca2+-dependent nuclease(s), which are regulated by phosphorus availability. Mass spectrometry analysis of the extracellular proteome of MR-1 identified one putative endonuclease (SO1844), a predicted UshA (bifunctional UDP-sugar hydrolase/5′ nucleotidase), a predicted PhoX (calcium-activated alkaline phosphatase), and a predicted CpdB (bifunctional 2′,3′ cyclic nucleotide 2′ phosphodiesterase/3′ nucleotidase), all of which could play important roles in the extracellular degradation of DNA under phosphorus-limiting conditions. Overall, the results of this study suggest that the ability to use exogenous DNA as the sole source of phosphorus is widespread among the shewanellae, and perhaps among all prokaryotes, and may be especially important for nutrient cycling in metal-reducing environments. PMID:18156329

  11. Identifying sources and controlling factors of arsenic release in saline groundwater aquifers

    Liu, C. -W.; Lu, K.-L.; Kao, Y.-H.; Wang, C.-J.; Maji, S.-K.; Lee, J.-F.


    An integrated hydrogeochemical study was carried out to realize the occurrence of arsenic (As) in a saline aquifer. Saline groundwater was mostly concentrated in the uppermost aquifer, and non-saline water was in the lower aquifer in the study area. High As concentrations were found in both the uppermost and lower aquifers. No correlation among salinity, well depth and As concentration was observed. Various forms of Fe oxyhydroxides were identified in the magnetic fractions,...

  12. The Power of Biocatalysis: A One‐Pot Total Synthesis of Rhamnolipids from Butane as the Sole Carbon and Energy Source

    Gehring, Christian; Wessel, Mirja; Schaffer, Steffen


    Abstract Microbially derived surfactants, so‐called biosurfactants, have drawn much attention in recent years and are expected to replace current petrochemical surfactants, owing to their environmental and toxicological benefits. One strategy to support that goal is to reduce production costs by replacing relatively expensive sugars with cheaper raw materials, such as short‐chain alkanes. Herein, we report the successful one‐pot total synthesis of rhamnolipids, a class of biosurfactants with 12 stereocenters, from butane as sole carbon and energy source through the design of a tailored whole‐cell biocatalyst. PMID:28032017

  13. Ground-water hydraulics, regional flow, and ground-water development of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama

    Bush, Peter W.; Johnston, Richard H.


    The Floridan aquifer system is one of the major sources of groundwater supplies in the United States. This productive aquifer system underlies all of Florida, southeast Georgia, and small parts of adjoining Alabama and South Carolina, for a total area of about 100,000 square miles. About 3 billion gallons of water per day were withdrawn from the aquifer system in 1980, and in many areas the Floridan is the sole source of freshwater.

  14. Water quality and possible sources of nitrate in the Cimarron Terrace Aquifer, Oklahoma, 2003

    Masoner, Jason R.; Mashburn, Shana L.


    Water from the Cimarron terrace aquifer in northwest Oklahoma commonly has nitrate concentrations that exceed the maximum contaminant level of 10 milligrams per liter of nitrite plus nitrate as nitrogen (referred to as nitrate) set by the U.S. Environmental Protection Agency for public drinking water supplies. Starting in July 2003, the U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, conducted a study in the Cimarron terrace aquifer to assess the water quality and possible sources of nitrate. A qualitative and quantitative approach based on multiple lines of evidence from chemical analysis of nitrate, nitrogen isotopes in nitrate, pesticides (indicative of cropland fertilizer application), and wastewater compounds (indicative of animal or human wastewater) were used to indicate possible sources of nitrate in the Cimarron terrace aquifer. Nitrate was detected in 44 of 45 ground-water samples and had the greatest median concentration (8.03 milligrams per liter) of any nutrient analyzed. Nitrate concentrations ranged from nitrate concentrations exceeding the maximum contaminant level of 10 milligrams per liter. Nitrate concentrations in agricultural areas were significantly greater than nitrate concentrations in grassland areas. Pesticides were detected in 15 of 45 ground-water samples. Atrazine and deethylatrazine, a metabolite of atrazine, were detected most frequently. Deethylatrazine was detected in water samples from 9 wells and atrazine was detected in samples from 8 wells. Tebuthiuron was detected in water samples from 5 wells; metolachlor was detected in samples from 4 wells; prometon was detected in samples from 4 wells; and alachlor was detected in 1 well. None of the detected pesticide concentrations exceeded the maximum contaminant level or health advisory level set by the U.S. Environmental Protection Agency. Wastewater compounds were detected in 28 of 45 groundwater samples. Of the 20 wastewater compounds

  15. On the autarchic use of solely PIXE data in particulate matter source apportionment studies by receptor modeling

    Lucarelli, F. [Department of Physics and Astronomy, University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); National Institute of Nuclear Physics (INFN)-Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Nava, S., E-mail: [National Institute of Nuclear Physics (INFN)-Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Calzolai, G. [Department of Physics and Astronomy, University of Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Chiari, M. [National Institute of Nuclear Physics (INFN)-Florence, Via G. Sansone 1, 50019 Sesto Fiorentino (Italy); Giannoni, M.; Traversi, R.; Udisti, R. [Department of Chemistry, University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino (Italy)


    Particle Induced X-ray Emission (PIXE) analysis of aerosol samples allows simultaneous detection of several elements, including important tracers of many particulate matter sources. This capability, together with the possibility of analyzing a high number of samples in very short times, makes PIXE a very effective tool for source apportionment studies by receptor modeling. However, important aerosol components, like nitrates, OC and EC, cannot be assessed by PIXE: this limitation may strongly compromise the results of a source apportionment study if based on PIXE data alone. In this work, an experimental dataset characterised by an extended chemical speciation (elements, EC–OC, ions) is used to test the effect of reducing input species in the application of one of the most widely used receptor model, namely Positive Matrix Factorization (PMF). The main effect of using only PIXE data is that the secondary nitrate source is not identified and the contribution of biomass burning is overestimated, probably due to the similar seasonal pattern of these two sources.

  16. Occurrence, Distribution, Sources, and Trends of Elevated Chloride Concentrations in the Mississippi River Valley Alluvial Aquifer in Southeastern Arkansas

    Kresse, Timothy M.; Clark, Brian R.


    Water-quality data from approximately 2,500 sites were used to investigate the distribution of chloride concentrations in the Mississippi River Valley alluvial aquifer in southeastern Arkansas. The large volume and areal distribution of the data used for the investigation proved useful in delineating areas of elevated (greater than 100 milligrams per liter) chloride concentrations, assessing potential sources of saline water, and evaluating trends in chloride distribution and concentration over time. Irrigation water containing elevated chloride concentrations is associated with negative effects to rice and soybeans, two of the major crops in Arkansas, and a groundwater chloride concentration of 100 milligrams per liter is recommended as the upper limit for use on rice. As such, accurately delineating areas with high salinity ground water, defining potential sources of chloride, and documenting trends over time is important in assisting the agricultural community in water management. The distribution and range of chloride concentrations in the study area revealed distinct areas of elevated chloride concentrations. Area I includes an elongated, generally northwest-southeast trending band of moderately elevated chloride concentrations in the northern part of the study area. This band of elevated chloride concentrations is approximately 40 miles in length and varies from approximately 2 to 9 miles in width, with a maximum chloride concentration of 360 milligrams per liter. Area II is a narrow, north-south trending band of elevated chloride concentrations in the southern part of the study area, with a maximum chloride concentration of 1,639 milligrams per liter. A zone of chloride concentrations exceeding 200 milligrams per liter is approximately 25 miles in length and 5 to 6 miles in width. In Area I, low chloride concentrations in samples from wells completed in the alluvial aquifer next to the Arkansas River and in samples from the upper Claiborne aquifer, which

  17. Carbon isotopes of dissolved inorganic carbon reflect utilization of different carbon sources by microbial communities in two limestone aquifer assemblages

    M. E. Nowak


    Full Text Available Isotopes of dissolved inorganic carbon (DIC are used to indicate both transit times and biogeochemical evolution of groundwaters. These signals can be complicated in carbonate aquifers, as both abiotic (i.e., carbonate equilibria and biotic factors influence the δ13C and 14C of DIC. We applied a novel graphical method for tracking changes in the δ13C and 14C of DIC in two distinct aquifer complexes identified in the Hainich Critical Zone Exploratory (CZE, a platform to study how water transport links surface and shallow groundwaters in limestone and marlstone rocks in central Germany. For more quantitative estimates of contributions of different biotic and abiotic carbon sources to the DIC pool, we used the NETPATH geochemical modeling program, which accounts for changes in dissolved ions in addition to C isotopes. Although water residence times in the Hainich CZE aquifers based on hydrogeology are relatively short (years or less, DIC isotopes in the shallow, mostly anoxic, aquifer assemblage (HTU were depleted in 14C compared to a deeper, oxic, aquifer complex (HTL. Carbon isotopes and chemical changes in the deeper HTL wells could be explained by interaction of recharge waters equilibrated with post-bomb 14C sources with carbonates. However, oxygen depletion and δ13C and 14C values of DIC below those expected from the processes of carbonate equilibrium alone indicate considerably different biogeochemical evolution of waters in the upper aquifer assemblage (HTU wells. Changes in 14C and 13C in the upper aquifer complexes result from a number of biotic and abiotic processes, including oxidation of 14C-depleted OM derived from recycled microbial carbon and sedimentary organic matter as well as water–rock interactions. The microbial pathways inferred from DIC isotope shifts and changes in water chemistry in the HTU wells were supported by comparison with in situ microbial community structure based on 16S rRNA analyses. Our findings

  18. Growth of Arthrobacter sp. strain JBH1 on nitroglycerin as the sole source of carbon and nitrogen.

    Husserl, Johana; Spain, Jim C; Hughes, Joseph B


    Arthrobacter sp. strain JBH1 was isolated from nitroglycerin-contaminated soil by selective enrichment. Detection of transient intermediates and simultaneous adaptation studies with potential intermediates indicated that the degradation pathway involves the conversion of nitroglycerin to glycerol via 1,2-dinitroglycerin and 1-mononitroglycerin, with concomitant release of nitrite. Glycerol then serves as the source of carbon and energy.

  19. Growth of Arthrobacter sp. Strain JBH1 on Nitroglycerin as the Sole Source of Carbon and Nitrogen ▿

    Husserl, Johana; Spain, Jim C.; Hughes, Joseph B.


    Arthrobacter sp. strain JBH1 was isolated from nitroglycerin-contaminated soil by selective enrichment. Detection of transient intermediates and simultaneous adaptation studies with potential intermediates indicated that the degradation pathway involves the conversion of nitroglycerin to glycerol via 1,2-dinitroglycerin and 1-mononitroglycerin, with concomitant release of nitrite. Glycerol then serves as the source of carbon and energy. PMID:20061454

  20. Optimal Medium Composition to Enhance Poly-β-hydroxybutyrate Production by Ralstonia eutropha Using Cane Molasses as Sole Carbon Source

    Ali Bozorg


    Full Text Available In order to reduce the costs associated with Poly-β-hydroxybutyrate production, growth and Poly-β-hydroxybutyrate production of Ralstonia eutropha were studied in batch culture on different carbon sources. Experiments were designed and conducted to not only lower the cost of Poly-β-hydroxybutyrate production by using inexpensive substrates, but also to increase Poly-β-hydroxybutyrate production by optimizing the culture medium composition. Low cost, abundant carbon sources, including cane molasses, beet molasses, soya bean, and corn steep liquor were used to investigate the possibility of Poly-β-hydroxybutyrate production in such renewable carbon sources. Based on the experimental results, cane molasses with production of 0.49 g/L Poly-β-hydroxybutyrate was selected as the most efficient carbon source. To improve bacterial growth and Poly-β-hydroxybutyrate production, different chemicals were then used to pretreat the cane molasses. Sulfuric acid, with 33% enhancement in Poly-β-hydroxybutyrate production, revealed the highest efficiency in removing heavy metals and suspended impurities and was used to pretreat cane molasses in the subsequent experiments. Additionally, to make the process even more efficient and ultimately more effective, urea and corn steep liquor were used as nitrogen/minerals and vitamin sources, respectively. Using the Response Surface Methodology and through a 2n factorial Central Composite Design, the medium composition was then optimized, and maximum biomass concentration of 5.03 g/L and Poly-β-hydroxybutyrate concentration of 1.63 g/L were obtained.

  1. Scale-up of an alkaline protease from Bacillus pumilus MTCC 7514 utilizing fish meal as a sole source of nutrients.

    Gupta, Rishikesh Kumar; Prasad, Dinesh; Sathesh, Jaykumar; Naidu, Ramachandra Boopathy; Kamini, Numbi Ramudu; Palanivel, Saravanan; Gowthaman, Marichetti Kuppuswami


    Fish meal grades SL1 and SL2 from Sardine (Sardinella longiceps) and NJ from Pink Perch (Nemipterus japonicas) were evaluated as a sole source of carbon and nitrogen in the medium for alkaline protease production by Bacillus pumilus MTCC 7514. The analysis of the fish meal suggests that the carbon and nitrogen contents in fish meal are sufficient to justify its choice as replacement for other nutrients. Protease production increased significantly (4,914 U/ml) in medium containing only fish meal, compared with the basal medium (2,646 U/ml). However, the elimination of inorganic salts from media reduced the protease productivity. In addition, all the three grades of fish meal yielded almost the same amounts of protease when employed as the sole source of carbon and nitrogen. Nevertheless, the best results were observed in fish meal SL1 medium. Furthermore, protease production was enhanced to 6,966 U/ml and 7,047 U/ml on scaling up from flask (4,914 U/ml) to 3.7 and 20 L fermenters, respectively, using fish meal (10 g/l). Similarly, the corresponding improvement in productivities over flask (102.38 U/ml/h) was 193.5 and 195.75 U/ml/h in 3.7 and 20 L fermenters, respectively. The crude protease was found to have dehairing ability in leather processing, which is bound to have great environmental benefits.

  2. The marine isolate Novosphingobium sp. PP1Y shows specific adaptation to use the aromatic fraction of fuels as the sole carbon and energy source.

    Notomista, Eugenio; Pennacchio, Francesca; Cafaro, Valeria; Smaldone, Giovanni; Izzo, Viviana; Troncone, Luca; Varcamonti, Mario; Di Donato, Alberto


    Novosphingobium sp. PP1Y, isolated from a surface seawater sample collected from a closed bay in the harbour of Pozzuoli (Naples, Italy), uses fuels as its sole carbon and energy source. Like some other Sphingomonads, this strain can grow as either planktonic free cells or sessile-aggregated flocks. In addition, this strain was found to grow as biofilm on several types of solid and liquid hydrophobic surfaces including polystyrene, polypropylene and diesel oil. Strain PP1Y is not able to grow on pure alkanes or alkane mixtures but is able to grow on a surprisingly wide range of aromatic compounds including mono, bi, tri and tetracyclic aromatic hydrocarbons and heterocyclic compounds. During growth on diesel oil, the organic layer is emulsified resulting in the formation of small biofilm-coated drops, whereas during growth on aromatic hydrocarbons dissolved in paraffin the oil layer is emulsified but the drops are coated only if the mixtures contain selected aromatic compounds, like pyrene, propylbenzene, tetrahydronaphthalene and heterocyclic compounds. These peculiar characteristics suggest strain PP1Y has adapted to efficiently grow at the water/fuel interface using the aromatic fraction of fuels as the sole carbon and energy source.

  3. Source and migration of dissolved manganese in the Central Nile Delta Aquifer, Egypt

    Bennett, P. C.; El Shishtawy, A. M.; Sharp, J. M.; Atwia, M. G.


    Dissolved metals in waters in shallow deltaic sediments are one of the world's major health problems, and a prime example is arsenic contamination in Bangladesh. The Central Nile Delta Aquifer, a drinking water source for more than 6 million people, can have high concentrations of dissolved manganese (Mn). Standard hydrochemical analyses coupled with sequential chemical extraction is used to identify the source of the Mn and to identify the probable cause of the contamination. Fifty-nine municipal supply wells were sampled and the results compared with published data for groundwaters and surface waters. Drill cuttings from 4 wells were collected and analyzed by sequential chemical extraction to test the hypothesized Mn-generating processes. The data from this research show that the Mn source is not deep saline water, microbial reduction of Mn oxides at the production depth, or leakage from irrigation drainage ditches. Instead, Mn associated with carbonate minerals in the surficial confining layer and transported down along the disturbed well annulus of the municipal supply wells is the likely source. This analysis provides a basis for future hydrogeological and contaminant transport modeling as well as remediation-modification of well completion practices and pumping schedules to mitigate the problem.

  4. Investigating the Sources of Nitrogen Contamination in the Shallow Aquifer of Jakarta using a Newly Developed Distributed River-Aquifer Flow and Transport Model

    Costa, D.; Burlando, P.; Liong, S. Y.


    Recent observations in the shallow aquifer of Jakarta show a rise in nitrate (NO3-) levels. Groundwater is extensively used in the city to compensate for the limited public water supply network and therefore the risk to public health from a rise in NO3- concentration is high. NO3- has been identified as a cofactor for methemoglobinemia in infants, a disease which can lead to death in extreme cases. The NO3- levels detected are still below regulatory limits for drinking purposes but strategies are necessary to contain the growing problem. To this end, the main sources and pathways of inorganic compounds containing nitrogen (N) - i.e. nitrate, nitrite (NO2-) and ammonium (NH4+) - were investigated. We combined 3 years of field measurements in the Ciliwung River, the major river flowing through Jakarta, with a distributed river-aquifer interaction model to characterize the N-cycle in both systems and quantify the contribution of river infiltration in the overall groundwater N budget. The computed infiltration fluxes were compared to estimates of leaks from poorly maintained septic tanks, which are extensively used in the city, to identify the main source of groundwater contamination. Observations show a strong and interdependent spatial and seasonal variability in the levels of NO3-, NO2- and NH4+ in the river, which is caused by changes in nitrification/denitrification rates due to variations in dissolved oxygen concentrations. Simulation results suggest that such dynamics in the river cause river to aquifer contamination patterns to likewise change over space and time, which leads to heterogeneous vulnerability distributions. The estimated contribution of river-N infiltration to the observed NO3- groundwater levels is small if compared to that originating from all leaking septic tanks inside Jakarta. However, in the vicinity of the Ciliwung, river to groundwater N-loading can play an important role in the local NO3- groundwater levels because it is highly

  5. Fingerprinting groundwater salinity sources in the Gulf Coast Aquifer System, USA

    Chowdhury, Ali H.; Scanlon, Bridget R.; Reedy, Robert C.; Young, Steve


    Understanding groundwater salinity sources in the Gulf Coast Aquifer System (GCAS) is a critical issue due to depletion of fresh groundwater and concerns for potential seawater intrusion. The study objective was to assess sources of groundwater salinity in the GCAS using ˜1,400 chemical analyses and ˜90 isotopic analyses along nine well transects in the Texas Gulf Coast, USA. Salinity increases from northeast (median total dissolved solids (TDS) 340 mg/L) to southwest (median TDS 1,160 mg/L), which inversely correlates with the precipitation distribution pattern (1,370- 600 mm/yr, respectively). Molar Cl/Br ratios (median 540-600), depleted δ2H and δ18O (-24.7‰, -4.5‰) relative to seawater (Cl/Br ˜655 and δ2H, δ18O 0‰, 0‰, respectively), and elevated 36Cl/Cl ratios (˜100), suggest precipitation enriched with marine aerosols as the dominant salinity source. Mass balance estimates suggest that marine aerosols could adequately explain salt loading over the large expanse of the GCAS. Evapotranspiration enrichment to the southwest is supported by elevated chloride concentrations in soil profiles and higher δ18O. Secondary salinity sources include dissolution of salt domes or upwelling brines from geopressured zones along growth faults, mainly near the coast in the northeast. The regional extent and large quantities of brackish water have the potential to support moderate-sized desalination plants in this location. These results have important implications for groundwater management, suggesting a current lack of regional seawater intrusion and a suitable source of relatively low TDS water for desalination.

  6. Using artificial sweeteners to identify contamination sources and infiltration zones in a coupled river-aquifer system

    Bichler, Andrea; Muellegger, Christian; Hofmann, Thilo


    In shallow or unconfined aquifers the infiltration of contaminated river water might be a major threat to groundwater quality. Thus, the identification of possible contamination sources in coupled surface- and groundwater systems is of paramount importance to ensure water quality. Micropollutants like artificial sweeteners are promising markers for domestic waste water in natural water bodies. Compounds, such as artificial sweeteners, might enter the aquatic environment via discharge of waste water treatment plants, leaky sewer systems or septic tanks and are ubiquitously found in waste water receiving waters. The hereby presented field study aims at the (1) identification of contamination sources and (2) delineation of infiltration zones in a connected river-aquifer system. River bank filtrate in the groundwater body was assessed qualitatively and quantitatively using a combined approach of hydrochemical analysis and artificial sweeteners (acesulfame ACE) as waste water markers. The investigated aquifer lies within a mesoscale alpine head water catchment and is used for drinking water production. It is hypothesized that a large proportion of the groundwater flux originates from bank filtrate of a nearby losing stream. Water sampling campaigns in March and July 2012 confirmed the occurrence of artificial sweeteners at the investigated site. The municipal waste water treatment plant was identified as point-source for ACE in the river network. In the aquifer ACE was present in more than 80% of the monitoring wells. In addition, water samples were classified according to their hydrochemical composition, identifying two predominant types of water in the aquifer: (1) groundwater influenced by bank filtrate and (2) groundwater originating from local recharge. In combination with ACE concentrations a third type of water could be discriminated: (3) groundwater influence by bank filtrate but infiltrated prior to the waste water treatment plant. Moreover, the presence of ACE

  7. Genome-enabled analysis of the utilization of taurine as sole source of carbon or of nitrogen by Rhodobacter sphaeroides 2.4.1.

    Denger, Karin; Smits, Theo H M; Cook, Alasdair M


    A degradative pathway for taurine (2-aminoethanesulfonate) in Rhodobacter sphaeroides 2.4.1 was proposed by Brüggemann et al. (2004) (Microbiology 150, 805-816) on the basis of a partial genome sequence. In the present study, R. sphaeroides 2.4.1 was found to grow exponentially with taurine as the sole source of carbon and energy for growth. When taurine was the sole source of nitrogen in succinate-salts medium, the taurine was rapidly degraded, and most of the organic nitrogen was excreted as the ammonium ion, which was then utilized for growth. Most of the enzymes involved in dissimilation, taurine dehydrogenase (TDH), sulfoacetaldehyde acetyltransferase (Xsc) and phosphate acetyltransferase (Pta), were found to be inducible, and evidence for transcription of the corresponding genes (tauXY, xsc and pta), as well as of tauKLM, encoding the postulated TRAP transporter for taurine, and of tauZ, encoding the sulfate exporter, was obtained by reverse-transcription PCR. An additional branch of the pathway, observed by Novak et al. (2004) (Microbiology 150, 1881-1891) in R. sphaeroides TAU3, involves taurine : pyruvate aminotransferase (Tpa) and a presumptive ABC transporter (NsbABC). No evidence for a significant role of this pathway, or of the corresponding alanine dehydrogenase (Ald), was obtained for R. sphaeroides 2.4.1. The anaplerotic pathway needed under these conditions in R. sphaeroides 2.4.1 seems to involve malyl-CoA lyase, which was synthesized inducibly, and not malate synthase (GlcB), whose presumed gene was not transcribed under these conditions.

  8. Hydrochemical characterization and pollution sources identification of groundwater in Salawusu aquifer system of Ordos Basin, China.

    Yang, Qingchun; Wang, Luchen; Ma, Hongyun; Yu, Kun; Martín, Jordi Delgado


    Ordos Basin is located in an arid and semi-arid region of northwestern China, which is the most important energy source bases in China. Salawusu Formation (Q3 s) is one of the most important aquifer systems of Ordos Basin, which is adjacent to Jurassic coalfield areas. A large-scale exploitation of Jurassic coal resources over ten years results in series of influences to the coal minerals, such as exposed to the oxidation process and dissolution into the groundwater due to the precipitation infiltration. Therefore, how these processes impact groundwater quality is of great concerns. In this paper, the descriptive statistical method, Piper trilinear diagram, ratios of major ions and canonical correspondence analysis are employed to investigate the hydrochemical evolution, determine the possible sources of pollution processes, and assess the controls on groundwater compositions using the monitored data in 2004 and 2014 (before and after large-scale coal mining). Results showed that long-term exploration of coal resources do not result in serious groundwater pollution. The hydrochemical types changed from HCO3(-)-CO3(2-) facies to SO4(2-)-Cl facies during 10 years. Groundwater hardness, nitrate and sulfate pollution were identified in 2014, which was most likely caused by agricultural activities. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Chemical Source Tracking of Bacterial Contamination Using Micropollutants - A Karst Aquifer Case Study

    Zirlewagen, Johannes; Hillebrand, Olav; Nödler, Karsten; Licha, Tobias; Schiperski, Ferry; Stange, Claudia; Tiehm, Andreas; Scheytt, Traugott


    Karst aquifers are important drinking water resources in many parts of the world, though they are well known for their high vulnerability to contamination. Rainfall and snowmelt often trigger temporary contamination of karst water resources. Free-range animal breeding and application of manure on the one hand and sewage leakage or spillage on the other hand are usually regarded as main sources for fecal contamination. But distinction of their respective contributions is difficult. This study investigates the feasibility to track the origin of fecal contamination from the occurrences of indicator bacteria and chemical source indicators in karst spring water. The study site is the 45 km² rural catchment of the perennial karst spring Gallusquelle in SW-Germany (mean discharge: 0.5 m³/s). Overflow events of a stormwater detention basin (combined sewer system) are known to impact water quality at the spring. There is no free-range animal breeding in the catchment but intense application of manure. Following two heavy rainfall events with overflow of the stormwater detention basin, spring water was sampled over several days. Samples were analysed for indicator bacteria (total Coliform, E. coli, Enterococci) and 57 micropollutants, among them cyclamate and metazachlor. For the Gallusquelle catchment the artificial sweetener cyclamate and the herbicide metazachlor have been established as source specific indicators, the former for the sewer system and the latter for cropland. Though recharge in the Gallusquelle catchment is predominantly diffuse, there is a significant portion of direct recharge reflected by distinct breakthrough curves for cyclamate and metazachlor. The breakthrough of indicator bacteria coincides very well with the occurrence of both, cyclamate and metazachlor. However, indicator bacteria cannot be unambiguously tracked back to a specific source.


    LIU Guo-qing; ZHOU Zhi-fang


    By combining sand tank tests with numerical simulations,this paper studies the temperature fields around constant heat sources to reveal the mechanism of the natural convection and its influence on the temperature fields in the process of energy storage.Using the “24-channel temperature auto acquisition system” developed by our research group in the tests,the temperatures are recorded at measuring points within the research area in the tests,the revised Brinkman equation and a transfer-convection balance model are used for solving the aquifer water-thermal coupling problems,and through comparison of the test results with the calculation results,it is discovered that the influence ranges and the variations of the two temperature fields are consistent,which validates the mathematical model.On the basis of this,we also study the influences of the heat source positions and the boundary conditions on the temperature fields,and the results show that,under the natural convection,the heat source positions may influence the distribution of the temperature fields,thus affect the energy storage.For the same energy storage layer,the temperature field for the top energy storage is characterized by a smaller heat influence range and a relatively concentrated temperature distribution.However,when the heat source is at the bottom,the range of a temperature field,and the temperature is relatively dispersed,which is not favorable to heat recycle,with the same heat sourcc position,the boundary conditions determine the size of the critical Rayleigh number,and thus have an influence on the occurrence and the strength of the natural convection,and accordingly,on the temperature fields.

  11. Analysis of the separation of aquifers and potential shale gas source rocks: a national-scale screening study from the UK.

    Bloomfield, John; Ward, Rob; Garcia-Bajo, Marieta; Hart, Alwyn


    A number of potential pathways can be identified for the migration of methane and contaminants associated with the shale gas extraction process to aquifers. These include the possible movement of contaminants from shale gas reservoirs that have been hydraulically fractured to overlying aquifers. The risk of contamination of an overlying aquifer is a function of i.) the separation of the potential shale gas source rock and the aquifer, ii.) the hydraulic characteristics (e.g. hydraulic conductivity, storage and hydrogeochemistry) of the rocks in the intervening interval, and iii.) regional and local physio-chemical gradients. Here we report on a national-scale study from the UK to assess the former, i.e. the vertical separation between potential shale gas source rocks and major aquifers, as a contribution to more informed management of the risks associated with shale gas development if and when it takes place in the UK. Eleven aquifers are considered in the study. These are aquifers that have been designated by the environment agencies of England (Environment Agency) and Wales (Natural Resources Wales) under the EU Water Framework Directive as being nationally important (Principal Aquifers). The shale gas source rocks have been defined on best publically available evidence for potential gas productivity and include both shales and clay formations. Based on a national geological fence diagram consisting of ~80 geological sections, totalling ~12,000km in length, down to >5km in depth, and with a typical spacing of 30km, the lower surfaces of each aquifer unit and upper surfaces of each shale/clay unit have been estimated at a spatial resolution of 3x3km. These surfaces have then been used to estimate vertical separations between pairs of shale/clay and aquifer units. The modelling process will be described and the aquifer, shale and separation maps presented and discussed. The aquifers are defined by geological units and since these geological units may be found at

  12. Effect of exposure history on microbial herbicide degradation in an aerobic aquifer affected by a point source

    Tuxen, Nina; de Lipthay, J.R.; Albrechtsen, Hans-Jørgen;


    The effects of in situ exposure to low concentrations (micrograms per liter) of herbicides on aerobic degradation of herbicides in aquifers were studied by laboratory batch experiments. Aquifer material and groundwater were collected from a point source with known exposure histories to the herbic......The effects of in situ exposure to low concentrations (micrograms per liter) of herbicides on aerobic degradation of herbicides in aquifers were studied by laboratory batch experiments. Aquifer material and groundwater were collected from a point source with known exposure histories...... to the herbicides mecoprop (MCPP), dichlorprop, BAM, bentazone, isoproturon, and DNOC. Degradation of the phenoxy acids, mecoprop and dichlorprop, was observed in five of six sampling points from within the plume. Mecoprop was mineralized, and up to 70% was recovered as 14CO2. DNOC was degraded in only two of six...... sampling points from within the plume, and neither BAM, bentazone, nor isoproturon was degraded in any sampling point. A linear correlation (R2 g 0.83) between pre-exposure and amount of herbicide degraded within 50 days was observed for the phenoxy acids, mecoprop and dichlorprop. An improved model fit...

  13. Fluoride in the Serra Geral Aquifer System: Source Evaluation Using Stable Isotopes and Principal Component Analysis

    Arthur Schmidt Nanni


    Full Text Available Groundwater with anomalous fluoride content and water mixture patterns were studied in the fractured Serra Geral Aquifer System, a basaltic to rhyolitic geological unit, using a principal component analysis interpretation of groundwater chemical data from 309 deep wells distributed in the Rio Grande do Sul State, Southern Brazil. A four-component model that explains 81% of the total variance in the Principal Component Analysis is suggested. Six hydrochemical groups were identified. δ18O and δ2H were analyzed in 28 Serra Geral Aquifer System samples in order to identify stable isotopes patterns and make comparisons with data from the Guarani Aquifer System and meteoric waters. The results demonstrated a complex water mixture between the Serra Geral Aquifer System and the Guarani Aquifer System, with meteoric recharge and ascending water infiltration through an intensive tectonic fracturing.

  14. Speciation and Source Identification for Arsenic in the Southern High Plains Aquifer

    Venkataraman, K.; Rainwater, K.; Jackson, W. A.; Ridley, M. K.


    Significant levels of arsenic have been detected in the groundwater of the Southern High Plains. The potential sources include atmospheric deposition, the use of agricultural defoliants and natural subsurface geochemical interactions. To identify the source of arsenic, groundwater and soil samples were collected by the Texas Tech University Water Resources Center from sites spread over 18 counties in the West Texas region. Arsenic and its inorganic species were quantified along with commonly occurring and related cations and anions such as iron, manganese, copper and sulfate. Correlation studies were conducted to understand the variation of arsenical species with related parameters. A geochemical modeling tool, MINTEQ was used to predict the speciation of arsenic and compare these results with lab analyses. Sensitivity analysis was also conducted with MINTEQ to study the behavior of arsenical species with variations in total iron and field parameters such as pH, ORP, and DO. The distribution of arsenic and its species in the soil profiles tested indicated a positive correlation with depth. The highest concentrations were found close to the water table while the upper soil layers had low to non-detect concentrations. In the groundwater samples, arsenic concentration and speciation varied significantly between sites. As (III) was found to be the dominant species in the majority (>80%) of the samples. MINTEQ speciation forecasts compared favorably with a majority of the groundwater analyses. Sensitivity analyses indicated a negative correlation between As(III) and ORP, while increasing iron concentration increased the levels of As(III). Decreasing iron caused no significant change in the concentration of As(III). Low concentrations of arsenic in the shallow layers of the soil have led to the elimination of atmospheric deposition and the use of defoliants as potential sources of contamination. The combination of analytical results and the geochemical simulations

  15. Deep karstified dolomite aquifer as a source of drinking water - isotopic measurements

    Bracic Zeleznik, Branka; Cencur Curk, Barbara; Zvab Rozic, Petra; Torkar, Anja; Vreca, Polona; Brencic, Mihael


    The Ljubljana Moor extends from the southern part of Ljubljana, the capital of Slovenia, to Krim-Mokrc karstic mountains. The sedimentation basin of Ljubljana Moor is filled up in the central part with lacustrine and marshy sediments and on the borders of the basin are the gravel fans. In the base of sedimentation basin is prequaternary karstified upper triasic dolomite. Ljubljana Moor aquifer is one of the biggest and very important drinking water sources in the central part of Slovenia. The water field Brest with 13 wells is situated in southern part of Moor, on I\\vska fan. The wells of different depth, from 28 m to 200 m, pump groundwater from various geological units, quaternary sediments and karstified dolomite. The land use on recharge area is agriculture and urbanization and in the last decade we monitor the deterioration of groundwater quality in quaternary sediments. In 2011 the 200 m deep well (VD Brest-3a) was drilled to catch the groundwater better quality in triasic dolomite that is in hydraulic connection with the karstic area in hinterland. To determine the recharge dynamic, origin and age of groundwater in dolomite, we provide several isotopic samplings on different depths. We measured oxygen (δ18O), deuterium (δ2H) and inorganic carbon (δ13CDIC). .

  16. Key enzymes enabling the growth of Arthrobacter sp. strain JBH1 with nitroglycerin as the sole source of carbon and nitrogen.

    Husserl, Johana; Hughes, Joseph B; Spain, Jim C


    Flavoprotein reductases that catalyze the transformation of nitroglycerin (NG) to dinitro- or mononitroglycerols enable bacteria containing such enzymes to use NG as the nitrogen source. The inability to use the resulting mononitroglycerols limits most strains to incomplete denitration of NG. Recently, Arthrobacter strain JBH1 was isolated for the ability to grow on NG as the sole source of carbon and nitrogen, but the enzymes and mechanisms involved were not established. Here, the enzymes that enable the Arthrobacter strain to incorporate NG into a productive pathway were identified. Enzyme assays indicated that the transformation of nitroglycerin to mononitroglycerol is NADPH dependent and that the subsequent transformation of mononitroglycerol is ATP dependent. Cloning and heterologous expression revealed that a flavoprotein catalyzes selective denitration of NG to 1-mononitroglycerol (1-MNG) and that 1-MNG is transformed to 1-nitro-3-phosphoglycerol by a glycerol kinase homolog. Phosphorylation of the nitroester intermediate enables the subsequent denitration of 1-MNG in a productive pathway that supports the growth of the isolate and mineralization of NG.

  17. Salinity sources of Kefar Uriya wells in the Judea Group aquifer of Israel. Part 1—conceptual hydrogeological model

    Avisar, D.; Rosenthal, E.; Flexer, A.; Shulman, H.; Ben-Avraham, Z.; Guttman, J.


    In the Yarkon-Taninim groundwater basin, the karstic Judea Group aquifer contains groundwater of high quality. However, in the western wells of the Kefar Uriya area located in the foothills of the Judea Mountains, brackish groundwater was locally encountered. The salinity of this water is caused presumably by two end members designated as the 'Hazerim' and 'Lakhish' water types. The Hazerim type represents surface water percolating through a highly fractured thin chalky limestone formation overlying the Judea Group aquifer. The salinity of the water derives conjointly from several sources such as leachates from rendzina and grumosols, dissolution of caliche crusts which contain evaporites and of rock debris from the surrounding formations. This surface water percolates downwards into the aquifer through a funnel- or chimney-like mechanism. This local salinization mechanism supercedes another regional process caused by the Lakhish waters. These are essentially diluted brines originating from deep formations in the western parts of the Coastal Plain. The study results show that salinization is not caused by the thick chalky beds of the Senonian Mt Scopus Group overlying the Judea Group aquifer, as traditionally considered but prevalently by aqueous leachates from soils and rock debris. The conceptual qualitative hydrogeological model of the salinization as demonstrated in this study, is supported by a quantitative hydrological model presented in another paper in this volume.

  18. Numerical simulations of the impact of seasonal heat storage on source zone emission in a TCE contaminated aquifer

    Popp, Steffi; Beyer, Christof; Dahmke, Andreas; Bauer, Sebastian


    In urban regions, with high population densities and heat demand, seasonal high temperature heat storage in the shallow subsurface represents an attractive and efficient option for a sustainable heat supply. In fact, the major fraction of energy consumed in German households is used for room heating and hot water production. Especially in urbanized areas, however, the installation of high temperature heat storage systems is currently restricted due to concerns on negative influences on groundwater quality caused e.g. by possible interactions between heat storages and subsurface contaminants, which are a common problem in the urban subsurface. Detailed studies on the overall impact of the operation of high temperature heat storages on groundwater quality are scarce. Therefore, this work investigates possible interactions between groundwater temperature changes induced by heat storage via borehole heat exchangers and subsurface contaminations by numerical scenario analysis. For the simulation of non-isothermal groundwater flow, and reactive transport processes the OpenGeoSys code is used. A 2D horizontal cross section of a shallow groundwater aquifer is assumed in the simulated scenario, consisting of a sandy sediment typical for Northern Germany. Within the aquifer a residual trichloroethene (TCE) contaminant source zone is present. Temperature changes are induced by a seasonal heat storage placed within the aquifer with scenarios of maximum temperatures of 20°C, 40°C and 60°C, respectively, during heat injection and minimum temperatures of 2°C during heat extraction. In the scenario analysis also the location of the heat storage relative to the TCE source zone and plume was modified. Simulations were performed in a homogeneous aquifer as well as in a set of heterogeneous aquifers with hydraulic conductivity as spatially correlated random fields. In both cases, results show that the temperature increase in the heat plume and the consequential reduction of water

  19. LNAPL source zone delineation using soil gases in a heterogeneous silty-sand aquifer

    Cohen, Grégory J. V.; Jousse, Florie; Luze, Nicolas; Höhener, Patrick; Atteia, Olivier


    Source delineation of hydrocarbon contaminated sites is of high importance for remediation work. However, traditional methods like soil core extraction and analysis or recent Membrane Interface Probe methods are time consuming and costly. Therefore, the development of an in situ method based on soil gas analysis can be interesting. This includes the direct measurement of volatile organic compounds (VOCs) in soil gas taken from gas probes using a PID (Photo Ionization Detector) and the analysis of other soil gases related to VOC degradation distribution (CH4, O2, CO2) or related to presence of Light Non-Aqueous Phase Liquid (LNAPL) as 222Rn. However, in widespread heterogeneous formations, delineation by gas measurements becomes more challenging. The objective of this study is twofold: (i) to analyse the potential of several in situ gas measurement techniques in comparison to soil coring for LNAPL source delineation at a heterogeneous contaminated site where the techniques might be limited by a low diffusion potential linked to the presence of fine sands and silts, and (ii) to analyse the effect of vertical sediment heterogeneities on the performance of these gas measurement methods. Thus, five types of gases were analysed: VOCs, their three related degradation products O2, CO2 and CH4 and 222Rn. Gas measurements were compared to independent LNAPL analysis by coring. This work was conducted at an old industrial site frequently contaminated by a Diesel-Fuel mixture located in a heterogeneous fine-grained aquifer. Results show that in such heterogeneous media migration of reactive gases like VOCs occurs only across small distances and the VOC concentrations sampled with gas probes are mainly related to local conditions rather than the presence of LNAPL below the gas probe. 222Rn is not well correlated with LNAPL because of sediment heterogeneity. Oxygen, CO2, and especially CH4, have larger lengths of diffusion and give the clearest picture for LNAPL presence at this

  20. New locus (ttr) in Escherichia coli K-12 affecting sensitivity to bacteriophage T2 and growth on oleate as the sole carbon source.

    Morona, R; Henning, U


    The nature of resistance to phage T2 in Escherichia coli K-12 was investigated by analyzing a known phage T2-resistant mutant and by isolating new T2-resistant mutants. It was found that mutational alterations at two loci, ompF (encoding the outer membrane protein OmpF) and ttr (T-two resistance), are needed to give full resistance to phage T2. A ttr::Tn10 mutation was isolated and was mapped between aroC and dsdA, where the fadL gene (required for long-chain fatty acid transport) is located. The receptor affected by ttr was the major receptor used by phage T2 and was located in the outer membrane. Phage T2 was thus able to use two outer membrane proteins as receptors. All strains having a ttr::Tn10 allele and most of the independently isolated phage T2-resistant mutants were unable to grow on oleate as the sole carbon and energy source, i.e., they had the phenotype of fadL mutants. The gene fadL is known to encode an inner membrane protein. The most likely explanation is that fadL and ttr are in an operon and that ttr encodes an outer membrane protein which functions in translocating long-chain fatty acids across the outer membrane and also as a receptor for phage T2.

  1. Impacts of high β-galactosidase expression on central metabolism of recombinant Pichia pastoris GS115 using glucose as sole carbon source via (13)C metabolic flux analysis.

    Nie, Yongsheng; Huang, Mingzhi; Lu, Junjie; Qian, Jiangchao; Lin, Weilu; Chu, Ju; Zhuang, Yingping; Zhang, Siliang


    The yeast Pichia pastoris GS115 is a widely used microbial cell factory for the production of heterologous protein. In order to reveal the impacts of high heterologous protein expression on the central metabolism of Pichia pastoris GS115 using glucose as sole carbon source, we engineered a high β-galactosidase expression strain P. pastoris G1HL and a low expression control strain P. pastoris GHL through controlling the initiation strength of constitutive promoter pGAP. The carbon flux distributions in these two strains were quantified via (13)C metabolic flux analysis. Compared to the control strain, G1HL showed a lower growth rate, a higher flux through glycolysis pathway, a higher flux through pentose phosphate pathway, and a lower flux through by-products secretion pathway. The metabolic flux redistribution in G1HL was thought to compensate the increased redox cofactors and energy demands caused by the high protein expression. Although the fluxes through Krebs cycle in two engineered strains were almost the same, they were significantly lower than those in wild strain. The enhanced expression of β-galactosidase by glutamate supplementation demonstrated the potential of P. pastoris GS115 to catabolize more carbon through the Krebs cycle for even higher protein expression. In conclusion, our work indicates that P. pastoris GS115 can readjusts the central metabolism for higher heterologous protein expression and provides strategies for strain development or process optimization for enhancing production of heterologous protein.

  2. A comparison of sole carbon source utilization patterns and phospholipid fatty acid profiles to detect changes in the root microflora of hydroponically grown crops.

    Khalil, S; Bååth, E; Alsanius, B; Englund, J E; Sundin, P; Gertsson, U E; Jensén, P


    Sole carbon source utilization (SCSU) patterns and phospholipid fatty acid (PLFA) profiles were compared with respect to their potential to characterize root-inhabiting microbial communities of hydroponically grown crops. Sweet pepper (Capsicum annum cv. Evident), lettuce (Lactuca sativa cv. Grand Rapids), and four different cultivars of tomato (Lycopersicon esculentum cvs. Gitana, Armada, Aromata, and Elin) were grown in 1-L black plastic beakers placed in a cultivation chamber with artificial light. In addition to the harvest of the plants after 6 weeks, plants of one tomato cultivar, cv. Gitana, were also harvested after 4 and 8 weeks. The cultivation in this study was performed twice. Principal component analysis was used to analyze the data. Both characterization methods had the ability to discriminate between the root microflora of different plant species, cultivars, and one tomato cultivar at different ages. Differences in both SCSU patterns and PLFA profiles were larger between plant species than between cultivars, but for both methods the largest differences were between the two cultivations. Still, the differences between treatments were always due to differences in the same PLFAs in both cultivations. This was not the case for the SCSU patterns when different plant ages were studied. Furthermore, PLFA profiles showed less variation between replicates than did SCSU patterns. This larger variation observed among the SCSU data indicates that PLFA may be more useful to detect changes in the root microflora of hydroponically grown crops than the SCSU technique.

  3. Final policy toward owners of property containing contaminated aquifers

    Kandell, E.


    The policy states the agency`s position that, subject to certain conditions, where hazardous substances have come to be located on or in a property solely as the result of subsurface migration in an aquifer from a source or sources outside the property. EPA will not take enforcement actions under CERCLA, 42 U.S.C. 106 and 107 against the owner of such property to require the performance of response actions or the payment of response costs.

  4. [Effects of two typical substrates as the sole carbon source on biological phosphorus removal with a single-stage oxic process].

    Liu, Yi-Lin; Wang, Dong-Bo; Li, Xiao-Ming; Yang, Qi; Zou, Gao-Long; Jia, Bin; Zeng, Tian-Jing; Ding, Yan; Zeng, Guang-Ming


    To investigate the performances of phosphorus removal in a sequencing batch reactor (SBR) with single-stage oxic process using synthetical wastewater, glucose (R1) and acetate (R2) were fed to two SBRs as the sole carbon source, respectively. The operation run mode was determined to be: influent --> aeration (4 h) --> settling (8 h) --> effluent. The results showed that the performance of phosphorus removal in R1 was higher than that in R2 after steady-operation. Total phosphorus (TP) removed per MLVSS in R1 and R2 were 7.2-7.7 and 3.8-4.6 mg x g(-1) during aeration, respectively, but the rate of phosphorus release at the two reactors were 3.6-3.8 and 2.7-3.1 mg x g(-1) during the idle zone, respectively. The energy storage of poly-beta-hydroxyalkanoates (PHA) was constant nearly in R1 during the whole period, but glycogen was accumulated to the maximum value at 30 minutes of aeration, and then was decreased to the initial level. However in R2, PHA and glycogen were both accumulated at about 45 minutes of aeration. This phenomenon suggested that glycogen is the main energy source for metabolism during aerobic period in R1, and the main energy resource come from the decomposition of PHA and the hydrolysis of glycogen in R2. The facts showed that glycogen could replace PHAs to supply energy for phosphate uptake and polyphosphate accumulation in such a single-stage oxic process. Since glycogen accumulated in R1 was more than that in R2, the efficiency of phosphorus removal in R1 was higher than that in R2.

  5. Innovative environmental tracer techniques for evaluating sources of spring discharge from a carbonate aquifer bisected by a river.

    Heilweil, Victor M; Sweetkind, Donald S; Gerner, Steven J


    Littlefield Springs discharge about 1.6 m³ /s along a 10-km reach of the Virgin River in northwestern Arizona. Understanding their source is important for salinity control in the Colorado River Basin. Environmental tracers suggest that Littlefield Springs are a mixture of older groundwater from the regional Great Basin carbonate aquifer and modern (post-1950s) seepage from the Virgin River. While corrected ¹⁴C apparent ages range from 1 to 9 ka, large amounts of nucleogenic ⁴He and low ³He/⁴He ratios suggest that the carbonate aquifer component is likely even older Pleistocene recharge. Modeled infiltration of precipitation, hydrogeologic cross sections, and hydraulic gradients all indicate recharge to the carbonate aquifer likely occurs in the Clover and Bull Valley Mountains along the northern part of the watershed, rather than in the nearby Virgin Mountains. This high-altitude recharge is supported by relatively cool noble-gas recharge temperatures and isotopically depleted δ²H and δ¹⁸O. Excess (crustal) SF₆ and ⁴He precluded dating of the modern component of water from Littlefield Springs using SF₆ and ³H/³He methods. Assuming a lumped-parameter model with a binary mixture of two piston-flow components, Cl⁻ /Br⁻, Cl⁻ /F⁻, δ²H, and CFCs indicate the mixture is about 60% Virgin River water and 40% groundwater from the carbonate aquifer, with an approximately 30-year groundwater travel time for Virgin River seepage to re-emerge at Littlefield Springs. This suggests that removal of high-salinity sources upstream of the Virgin River Gorge would reduce the salinity of water discharging from Littlefield Springs into the Virgin River within a few decades.

  6. A novel pink-pigmented facultative methylotroph, Methylobacterium thiocyanatum sp. nov., capable of growth on thiocyanate or cyanate as sole nitrogen sources.

    Wood, A P; Kelly, D P; McDonald, I R; Jordan, S L; Morgan, T D; Khan, S; Murrell, J C; Borodina, E


    The isolation and properties of a novel species of pink-pigmented methylotroph, Methylobacterium thiocyanatum, are described. This organism satisfied all the morphological, biochemical, and growth-substrate criteria to be placed in the genus Methylobacterium. Sequencing of the gene encoding its 16S rRNA confirmed its position in this genus, with its closest phylogenetic relatives being M. rhodesianum, M. zatmanii and M. extorquens, from which it differed in its ability to grow on several diagnostic substrates. Methanol-grown organisms contained high activities of hydroxypyruvate reductase -3 micromol NADH oxidized min-1 (mg crude extract protein)-1], showing that the serine pathway was used for methylotrophic growth. M. thiocyanatum was able to use thiocyanate or cyanate as the sole source of nitrogen for growth, and thiocyanate as the sole source of sulfur in the absence of other sulfur compounds. It tolerated high concentrations (at least 50 mM) of thiocyanate or cyanate when these were supplied as nitrogen sources. Growing cultures degraded thiocyanate to produce thiosulfate as a major sulfur end product, apparently with the intermediate formation of volatile sulfur compounds (probably hydrogen sulfide and carbonyl sulfide). Enzymatic hydrolysis of thiocyanate by cell-free extracts was not demonstrated. Cyanate was metabolized by means of a cyanase enzyme that was expressed at approximately sevenfold greater activity during growth on thiocyanate [Vmax 634 +/- 24 nmol NH3 formed min-1 (mg protein)-1] than on cyanate [89 +/- 9 nmol NH3 min-1 (mg protein)-1]. Kinetic study of the cyanase in cell-free extracts showed the enzyme (1) to exhibit high affinity for cyanate (Km 0.07 mM), (2) to require bicarbonate for activity, (3) to be subject to substrate inhibition by cyanate and competitive inhibition by thiocyanate (Ki 0.65 mM), (4) to be unaffected by 1 mM ammonium chloride, (5) to be strongly inhibited by selenocyanate, and (6) to be slightly inhibited by 5 m

  7. Identifying sources and controlling factors of arsenic release in saline groundwater aquifers

    C.-W. Liu


    Full Text Available An integrated hydrogeochemical study is carried out to realize the occurrence of arsenic (As in a saline aquifer. Saline groundwater was mostly concentrated in the uppermost aquifer and non-saline water was in the lower aquifer in the study area. High As concentrations were found in both uppermost and lower aquifers. No correlation among salination, well depth and As concentration was observed. Both reducing and oxidizing forms of Fe oxyhydroxides were identified in the magnetic fractions, which were concentrated by high gradient magnetic separation (HGMS technique, revealing that the redox cycling of Fe occurred in the subsurface. High levels of Fe, HCO3-, DOC and NH4+ concentrations accompanying alkaline pH in the As-rich groundwater were consistent with the mechanism triggered by the microbial-mediated reductive dissolution of Fe oxyhydroxides. A threshold value of 50 μg L−1. As concentration was used as an indicator for identification of active proceeding reductive dissolution of As-bearing Fe oxyhydroxides in the saline aquifer. Desorption behaviors of As were relevant to its valence in the sediments and the co-existence of anions. Experimental and numerical results showed that additions of Cl- and SO42-, which represented the main anions of saline water, had minor effect on leaching sedimentary As. Although bicarbonate addition resulted in less As desorption than that of phosphate on a molar basis, the contribution of bicarbonate to the total release of As was greater than phosphate due to the much higher concentration of bicarbonate in groundwater and the associated microbial mediation. Collectively, the chemical effect of saline water on the As-release to groundwater is mild in the coastal aquifer.

  8. Principal aquifers can contribute radium to sources of drinking water under certain geochemical conditions

    Szabo, Zoltan; Fischer, Jeffrey M.; Hancock, Tracy Connell


    What are the most important factors affecting dissolved radium concentrations in principal aquifers used for drinking water in the United States? Study results reveal where radium was detected and how rock type and chemical processes control radium occurrence. Knowledge of the geochemical conditions may help water-resource managers anticipate where radium may be elevated in groundwater and minimize exposure to radium, which contributes to cancer risk. Summary of Major Findings: * Concentrations of radium in principal aquifers used for drinking water throughout the United States generally were below 5 picocuries per liter (pCi/L), the U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL) for combined radium - radium-226 (Ra-226) plus radium-228 (Ra-228) - in public water supplies. About 3 percent of sampled wells had combined radium concentrations greater than the MCL. * Elevated concentrations of combined radium were more common in groundwater in the eastern and central United States than in other regions of the Nation. About 98 percent of the wells that contained combined radium at concentrations greater than the MCL were east of the High Plains. * The highest concentrations of combined radium were in the Mid-Continent and Ozark Plateau Cambro-Ordovician aquifer system and the Northern Atlantic Coastal Plain aquifer system. More than 20 percent of sampled wells in these aquifers had combined radium concentrations that were greater than or equal to the MCL. * Concentrations of Ra-226 correlated with those of Ra-228. Radium-226 and Ra-228 occur most frequently together in unconsolidated sand aquifers, and their presence is strongly linked to groundwater chemistry. * Three common geochemical factors are associated with the highest radium concentrations in groundwater: (1) oxygen-poor water, (2) acidic conditions (low pH), and (3) high concentrations of dissolved solids.

  9. Aerobic biodegradation of trichloroethylene and phenol co-contaminants in groundwater by a bacterial community using hydrogen peroxide as the sole oxygen source.

    Li, Hui; Zhang, Shi-yang; Wang, Xiao-li; Yang, Jie; Gu, Ji-dong; Zhu, Rui-li; Wang, Ping; Lin, Kuang-fei; Liu, Yong-di


    Trichloroethylene (TCE) and phenol were often found together as co-contaminants in the groundwater of industrial contaminated sites. An effective method to remove TCE was aerobic biodegradation by co-metabolism using phenol as growth substrates. However, the aerobic biodegradation process was easily limited by low concentration of dissolved oxygen (DO) in groundwater, and DO was improved by air blast technique with difficulty. This study enriched a bacterial community using hydrogen peroxide (H2O2) as the sole oxygen source to aerobically degrade TCE by co-metabolism with phenol in groundwater. The enriched cultures were acclimatized to 2-8 mM H2O2 which induced catalase, superoxide dismutase and peroxidase to decompose H2O2 to release O2 and reduce the toxicity. The bacterial community could degrade 120 mg/L TCE within 12 days by using 8 mM H2O2 as the optimum concentration, and the TCE degradation efficiency reached up to 80.6%. 16S rRNA gene cloning and sequencing showed that Bordetella, Stenotrophomonas sp., Sinorhizobium sp., Variovorax sp. and Sphingobium sp. were the dominant species in the enrichments, which were clustered in three phyla: Alphaproteobacteria, Betaproteobacteria and Gammaproteobacteria. Polymerase chain reaction detection proved that phenol hydroxylase (Lph) gene was involved in the co-metabolic degradation of phenol and TCE, which indicated that hydroxylase might catalyse the epoxidation of TCE to form the unstable molecule TCE-epoxide. The findings are significant for understanding the mechanism of biodegradation of TCE and phenol co-contamination and helpful for the potential applications of an aerobic bioremediation in situ the contaminated sites.

  10. Determining the source of nitrate pollution in the Niger discontinuous aquifers using the natural {15N }/{14N } ratios

    Girard, Pierre; Hillaire-Marcel, Claude


    In the semi-arid Niamey area (Niger), more than 10% of the deep wells exploiting the fracture network of the Precambrian aquifer are contaminated by nitrates, with concentrations as high as 10 meq l -1. In order to identify the source(s) of this pollution, nitrate and 15N contents in the polluted wells were monitored over a 20-month period. Potential sources of nitrate contamination were also analyzed for their 15N content. The isotopic compositions of nitrate in polluted waters were > + 12‰ and in rare cases exceeded +17‰. Latrines (˜ + 15‰) may be the major nitrate source for wells showing δ15N values above +15‰. Below this value, waters may be polluted by a combination of nitrates from both latrine and soil sources (˜ + 10‰). In some cases, the soil may account for up to 85% of the groundwater nitrate load. This mode of groundwater pollution is thought to be a consequence of deforestation. Despite their reputation as polluting agents, fertilizers ( +0.5 < δ 15N < + 3.6‰ ) which are used in rice paddies close to the contaminated areas, do not appear to be a significant source of nitrate contamination. Denitrification is probably not a significant process in the study area. Results suggest that nitrate contamination of the aquifer is a consequence of unregulated urbanization (home-made latrines) and deforestation. While latrines are limited to the urban zones, intensive cutting of the forest to meet the city dwellers' wood demand occurs in an ever increasing area around the capital, threatening the local water supply.

  11. Aquifer thermal energy storage. International symposium: Proceedings



    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  12. Factors associated with sources, transport, and fate of volatile organic compounds and their mixtures in aquifers of the United States

    Squillace, P.J.; Moran, M.J.


    Factors associated with sources, transport, and fate of volatile organic compounds (VOCs) in groundwater from aquifers throughout the United States were evaluated using statistical methods. Samples were collected from 1631 wells throughout the conterminous United States between 1996 and 2002 as part of the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. Water samples from wells completed in aquifers used to supply drinking water were analyzed for more than 50 VOCs. Wells were primarily rural domestic water supplies (1184), followed by public water supplies (216); the remaining wells (231) supplied a variety of uses. The median well depth was 50 meters. Age-date information shows that about 60% of the samples had a fraction of water recharged after 1953. Chloroform, toluene, 1,2,4-trimethylbenzene, and perchloroethene were some of the frequently detected VOCs. Concentrations generally were less than 1 ??g/L. Source factors include, in order of importance, general land-use activity, septic/sewer density, and sites where large concentrations of VOCs are potentially released, such as leaking underground storage tanks. About 10% of all samples had VOC mixtures that were associated with concentrated sources; 20% were associated with dispersed sources. Important transport factors included well/screen depth, precipitation/groundwater recharge, air temperature, and various soil characteristics. Dissolved oxygen was strongly associated with VOCs and represents the fate of many VOCs in groundwater. Well type (domestic or public water supply) was also an important explanatory factor. Results of multiple analyses show the importance of (1) accounting for both dispersed and concentrated sources of VOCs, (2) measuring dissolved oxygen when sampling wells to help explain the fate of VOCs, and (3) limiting the type of wells sampled in monitoring networks to avoid unnecessary variance in the data, or controlling for this variance during data analysis.

  13. Changes in sources and storage in a karst aquifer during a transition from drought to wet conditions

    Wong, C.I.; Mahler, B.J.; Musgrove, M.; Banner, J.L.


    Understanding the sources and processes that control groundwater compositions and the timing and magnitude of groundwater vulnerability to potential surface-water contamination under varying meteorologic conditions is critical to informing groundwater protection policies and practices. This is especially true in karst terrains, where infiltrating surface water can rapidly affect groundwater quality. We analyzed the evolution of groundwater compositions (major ions and Sr isotopes) during the transition from extreme drought to wetconditions, and used inverse geochemical modeling (PHREEQC) to constrain controls on groundwater compositions during this evolution. Spring water and groundwater from two wells dominantly receiving diffuse and conduit flow (termed diffuse site and conduit site, respectively) in the Barton Springs segment of the Edwards aquifer (central Texas, USA) and surface water from losing streams that recharge the aquifer were sampled every 3–4 weeks during November 2008–March 2010. During this period, water compositions at the spring and conduit sites changed rapidly but there was no change at the diffuse site, illustrating the dual nature (i.e., diffuse vs. conduit) of flow in this karst system. Geochemical modeling demonstrated that, within a month of the onset of wetconditions, the majority of spring water and groundwater at the conduit site was composed of surface water, providing quantitative information on the timing and magnitude of the vulnerability of groundwater to potential surface-water contamination. The temporal pattern of increasing spring discharge and changing pattern of covariation between spring discharge and surface-water (steam) recharge indicates that that there were two modes of aquifer response—one with a small amount of storage and a second that accommodates more storage.

  14. CHROMagar Candida as the Sole Primary Medium for Isolation of Yeasts and as a Source Medium for the Rapid-Assimilation-of-Trehalose Test

    Murray, Melissa P.; Zinchuk, Riva; Larone, Davise H.


    The chromogenic medium BBL CHROMagar Candida (CAC) was evaluated as a sole primary medium for the isolation of yeasts from clinical specimens in which yeasts are the primary concern. Additionally, the reliability of the rapid-assimilation-of-trehalose (RAT) test in yielding correct results with isolates taken from CAC was assessed. A total of 270 throat, urine, and genital (TUG) specimens were streaked onto CAC, Sabouraud dextrose agar (SDA), inhibitory mold agar (IMA), and Mycosel (MYC). A t...

  15. SoleSound

    Zanotto, Damiano; Turchet, Luca; Boggs, Emily Marie;


    This paper introduces the design of SoleSound, a wearable system designed to deliver ecological, audio-tactile, underfoot feedback. The device, which primarily targets clinical applications, uses an audio-tactile footstep synthesis engine informed by the readings of pressure and inertial sensors...

  16. Assessment of nonpoint-source contamination of the High Plains Aquifer in south-central Kansas, 1987

    Helgesen, John O.; Stullken, Lloyd E.; Rutledge, A.T.


    Ground-water quality was assessed in a 5,000-square-mile area of the High Plains aquifer in south-central Kansas that is susceptible to nonpoint-source contamination from agricultural and petroleum-production activities. Of particular interest was the presence of agricultural chemicals and petroleum-derived hydrocarbons that might have been associated with brines that formerly were disposed into unlined ponds. Random sampling of ground water was done within a framework of discrete land-use areas (irrigated cropland, petroleum-production land containing former brine-disposal ponds, and undeveloped rangeland) of 3-10 square miles. Although true baseline water-quality conditions probably are rare, in this region they are represented most closely by ground water in areas of undeveloped rangeland. The sampling design enabled statistical hypothesis testing, using nonparametric procedures, of the effects of land use, unsaturated-zone lithology, and type of well sampled. Results indicate that regional ground-water quality has been affected by prevailing land-use activities, as shown by increased concentrations of several inorganic constituents. Ground water beneath irrigated cropland was characterized by significantly larger concentrations of hardness, alkalinity, calcium, magnesium, potassium, fluofide, and nitrite plus nitrate than was water beneath undeveloped rangeland. Few nondegraded pesticides were detected in the aquifer, probably because of degradation and sorption. Atrazine was the most common, but only in small concentrations. round water beneath petroleum-production land was characterized by significantly larger concentrations of hardness, alkalinity, dissolved solids, sodium, and chloride than was water beneath undeveloped rangeland. Nonpoint-source contamination by oil-derived hydrocarbons was not discernible. The occurrences of trace organic compounds were similar between petroleum-production land and undeveloped rangeland, which indicates a natural origin

  17. Identifying microbial carbon sources during ethanol and toluene biodegradation in a pilot-scale experimental aquifer system using isotopic analysis

    Clay, S.; McLeod, H.; Smith, J. E.; Roy, J. W.; Slater, G. F.


    Combining ethanol with gasoline has become increasingly common in order to create more environmentally conscience transportation fuels. These blended fuels are favourable alternatives since ethanol is a non-toxic and highly labile renewable biomass-based resource which is an effective fuel oxygenate that reduces air pollution. Recent research however, has indicated that upon accidental release into groundwater systems, the preferential microbial metabolism of ethanol can cause progressively reducing conditions leading to slower biodegradation of petroleum hydrocarbons. Therefore, the presence of ethanol can result in greater persistence of BTEX compounds and longer hydrocarbon plumes in groundwater systems. Microbial biodegradation and community carbon sources coupled to aqueous geochemistry were monitored in a pilot-scale laboratory tank (80cm x 525cm x 175cm) simulating an unconfined sand aquifer. Dissolved ethanol and toluene were continuously injected into the aquifer at a controlled rate over 330 days. Carbon isotope analyses were performed on phospholipid fatty acid (PLFA) samples collected from 4 different locations along the aquifer. Initial stable carbon isotope values measured over days 160-185 in the bacterial PLFA ranged from δ13C = -10 to -21‰, which is indicative of dominant ethanol incorporation by the micro-organisms based on the isotopic signature of ethanol derived from corn, a C4 plant. A negative shift to δ13C = -10 to -30‰ observed over days 185-200, suggests a change in microbial metabolisms associated with less ethanol incorporation. This generally corresponds to a decrease in ethanol concentrations from day 40 to full attenuation at approximately day 160, and the onset of toluene depletion observed on day 120 and continuing thereafter. In addition, aqueous methane concentrations first detected on day 115 continued to rise to 0.38-0.70 mmol/L at all monitoring locations, demonstrating a significant redox shift to low energy methanogenic

  18. CHROMagar Candida as the sole primary medium for isolation of yeasts and as a source medium for the rapid-assimilation-of-trehalose test.

    Murray, Melissa P; Zinchuk, Riva; Larone, Davise H


    The chromogenic medium BBL CHROMagar Candida (CAC) was evaluated as a sole primary medium for the isolation of yeasts from clinical specimens in which yeasts are the primary concern. Additionally, the reliability of the rapid-assimilation-of-trehalose (RAT) test in yielding correct results with isolates taken from CAC was assessed. A total of 270 throat, urine, and genital (TUG) specimens were streaked onto CAC, Sabouraud dextrose agar (SDA), inhibitory mold agar (IMA), and Mycosel (MYC). A total of 69 blood culture broths that were smear positive for yeast were streaked onto CAC and SDA. A 1-h RAT test (NCCLS M35-A) was performed simultaneously on isolates from CAC and SDA. A total of 112 TUG specimens yielded yeast colonies (CAC, 111 colonies; IMA, 105; SDA, 103; MYC, 91). The 69 blood culture yeasts grew on both CAC and SDA. Mixed cultures of yeasts were detected on 11 CAC plates but were unrecognized on other media. Colonies suspected of being C. glabrata on 32 CAC plates were all RAT test positive and confirmed to be C. glabrata; of 59 colonies with various characteristics of color and morphology on CAC, none were RAT positive, and all were conventionally identified as yeasts other than C. glabrata (sensitivity and specificity, 100%). The same isolates from SDA tested for RAT produced six false negatives and no false positives (sensitivity, 81%; specificity, 100%). The results show that CAC can be used as the sole primary medium for recovery of yeasts from clinical specimens. Additionally, isolates grown on CAC yield excellent results with the RAT test utilized in this study.

  19. Age and quality of ground water and sources of nitrogen in the aquifers in Pumpkin Creek Valley, western Nebraska, 2000

    Steele, G.V.; Cannia, J.C.; Sibray, S.S.; McGuire, V.L.


    Ground water is the source of drinking water for the residents of Pumpkin Creek Valley, western Nebraska. In this largely agricultural area, shallow aquifers potentially are susceptible to nitrate contamination. During the last 10 years, ground-water levels in the North Platte Natural Resources District have declined and contamination has become a major problem for the district. In 2000, the U.S. Geological Survey and the North Platte Natural Resources District began a cooperative study to determine the age and quality of the ground water and the sources of nitrogen in the aquifers in Pumpkin Creek Valley. Water samples were collected from 8 surface-water sites, 2 springs, and 88 ground-water sites during May, July, and August 2000. These samples were analyzed for physical properties, nutrients or nitrate, and hydrogen and oxygen isotopes. In addition, a subset of samples was analyzed for any combination of chlorofluorocarbons, tritium, tritium/helium, sulfur-hexafluoride, carbon-14, and nitrogen-15. The apparent age of ground water in the alluvial aquifer typically varied from about 1980 to modern, whereas ground water in the fractured Brule Formation had a median value in the 1970s. The Brule Formation typically contained ground water that ranged from the 1940s to the 1990s, but low-yield wells had apparent ages of 5,000 to 10,000 years before present. Data for oxygen-18 and deuterium indicated that lake-water samples showed the greatest effects from evaporation. Ground-water data showed no substantial evaporative effects and some ground water became isotopically heavier as the water moved downgradient. In addition, the physical and chemical ground-water data indicate that Pumpkin Creek is a gaining stream because little, if any, of its water is lost to the ground-water system. The water-quality type changed from a sodium calcium bicarbonate type near Pumpkin Creek's headwaters to a calcium sodium bicarbonate type near its mouth. Nitrate concentrations were

  20. Characterisation of Seasonal Temperature Variation in a Shallow, Urban Aquifer: Implications for the Sustainable Development of Ground Source Heating Systems

    Patton, Ashley M.; Farr, Gareth J.; Boon, David P.; James, David R.


    Groundwater thermally enhanced by the Urban Heat Island effect can be utilised by ground source heating systems (GSHSs). However, the near subsurface is subject to seasonal temperature variation reflected in shallow groundwater that can differ by several degrees throughout the year. To sustainably manage the near surface thermal resource an understanding of factors which control variation in groundwater temperature and how these are transmitted through the aquifer is needed. We show that even in relatively small urban areas (Cardiff, U.K., situated on a shallow gravel aquifer) the Zone of Seasonal Fluctuation (ZSF) can vary in depth by 8m. GSHSs are more efficient if they are sited below the ZSF, where temperatures are more stable. In Spring 2014, 48 groundwater monitoring boreholes were profiled at a 1m resolution to measure groundwater temperature across Cardiff. These were reprofiled that Autumn and compared to the Spring temperatures, defining the ZSF. The average depth to the base of the ZSF was 9.5mbgl but ranged from 7.1-15.5mbgl. The amplitude of the differences between Spring and Autumn temperatures also varied. To better understand the high spatial variability 60 boreholes were instrumented with in situ temperature loggers, recording at half-hourly intervals. The first year's data revealed the amplitudes of temperature variation within boreholes with loggers at similar depths were not always consistent. It was also noted that lag times between air temperature and groundwater temperature were not uniform across the sites. The data also showed that where gravels occurred at shallower depths the ZSF tended to be shallower and lag times shorter. The wide spatial variability of the ZSF may be partially explained by differing landuse. Those boreholes in open, grassed areas showed a deeper ZSF than those in built-up areas but built-up areas generally showed the greatest variation between Spring and Autumn temperature profiles, suggesting heat loss from buildings

  1. Major-ion and selected trace-metal chemistry of the Biscayne Aquifer, Southeast Florida

    Radell, M.J.; Katz, B.G.


    The major-ion and selected trace-metal chemistry of the Biscayne aquifer was characterized as part of the Florida Ground-Water Quality Monitoring Network Program, a multiagency cooperative effort concerned with delineating baseline water quality for major aquifer systems in the State. The Biscayne aquifer is unconfined and serves as the sole source of drinking water for more than 3 million people in southeast Florida. The Biscayne aquifer consists of highly permeable interbedded limestone and sandstone of Pleistocene and Pliocene age underlying most of Dade and Broward Counties and parts of Palm Beach and Monroe Counties. The high permeability is largely caused by extensive carbonate dissolution. Water sampled from 189 wells tapping the Biscayne aquifer was predominantly a calcium bicarbonate type with some mixed types occurring in coastal areas and near major canals. Major - ion is areally uniform throughout the aquifer. According to nonparametric statistical tests of major ions and dissolved solids, the concentrations of calcium, sodium, bicarbonate, and dissolved solids increased significantly with well depth ( 0.05 significance level ), probably a result of less circulation at depth. Potassium and nitrate concentrations decreased significantly with depth. Although the source of recharge to the aquifer varies seasonally, there was no statistical difference in the concentration of major ions in pared water samples from 27 shallow wells collected during wet and dry seasons. Median concentrations for barium, chromium, copper, lead, and manganese were below maximum or secondary maximum contaminant levels set by the US Environmental Protection Agency. The median iron concentration only slightly exceeded the secondary maximum contaminant level. The concentration of barium was significantly related (0.05 significance level) to calcium and bicarbonate concentration. No distinct areal pattern or vertical distribution of the selected trace metals was evident in water from

  2. Identification of immiscible NAPL contaminant sources in aquifers by a modified two-level saturation based imperialist competitive algorithm

    Ghafouri, H. R.; Mosharaf-Dehkordi, M.; Afzalan, B.


    A simulation-optimization model is proposed for identifying the characteristics of local immiscible NAPL contaminant sources inside aquifers. This model employs the UTCHEM 9.0 software as its simulator for solving the governing equations associated with the multi-phase flow in porous media. As the optimization model, a novel two-level saturation based Imperialist Competitive Algorithm (ICA) is proposed to estimate the parameters of contaminant sources. The first level consists of three parallel independent ICAs and plays as a pre-conditioner for the second level which is a single modified ICA. The ICA in the second level is modified by dividing each country into a number of provinces (smaller parts). Similar to countries in the classical ICA, these provinces are optimized by the assimilation, competition, and revolution steps in the ICA. To increase the diversity of populations, a new approach named knock the base method is proposed. The performance and accuracy of the simulation-optimization model is assessed by solving a set of two and three-dimensional problems considering the effects of different parameters such as the grid size, rock heterogeneity and designated monitoring networks. The obtained numerical results indicate that using this simulation-optimization model provides accurate results at a less number of iterations when compared with the model employing the classical one-level ICA.

  3. Potential of using arsenic-safe aquifers as sustainable drinking water sources in arsenic-affected areas of Bengal basin, India and Bangladesh

    Bhattacharya, Prosun; Mukherjee, Abhijit; Biswas, Ashis; Hossain, Mohammed; von Brömssen, Mattias


    horizontal flow system, and ii) a number of shallow local flow systems. It was confirmed that groundwater irrigation, locally, affects the hydraulic heads at deeper depths. The aquifer system is however fully recharged during the monsoon. Groundwater abstraction for drinking water purposes in rural areas poses little threat for cross-contamination. Installing irrigation- or high capacity drinking water supply wells at deeper depths is however strongly discouraged and assessing sustainability of targeted low-As aquifers remain a main concern. Delineation of safe aquifer(s) that can be targeted by cheap drilling technology for tubewell (TW) installation becomes highly imperative to ensure access to safe and sustainable drinking water sources for the As-affected population in Bengal Basin. In order to replicate the salient outcomes of the Matlab study results, an investigation was carried out in West Bengal, India covering an area of ˜100 km2 to investigate the potentiality of brown sand aquifers (BSA) as a safe drinking water source which is currently being practiced in the area for safe tubewell installation. The results revealed salient hydrogeochemical contrasts within the sedimentary sequence designated as shallow grey sand aquifers (GSA) and the brown sand aquifers (BSA) within shallow depth (perceived by the local driller in Matlab. Although the major ion compositions indicated close similarity, the redox conditions were markedly different in groundwater abstracted from the two group of aquifers. The redox condition in the BSA is delineated to be Mn oxy-hydroxide reducing, not sufficiently lowered for As mobilization into groundwater. In contrast, lower Eh in groundwater of GSA, along with the enrichments of NH4+, PO43-, Fe and As reflect reductive dissolution of Fe-oxyhydroxide coupled to microbially mediated oxidation of organic matter as the prevailing redox process causing As mobilization into groundwater of this aquifer type. The outcomes of the study has thus

  4. Septic systems as sources of organic wastewater compounds in domestic drinking water wells in a shallow sand and gravel aquifer

    Schaider, Laurel A., E-mail:; Ackerman, Janet M.; Rudel, Ruthann A.


    Domestic drinking water wells serve 44 million people in the US and are common globally. They are often located in areas served by onsite wastewater treatment systems, including septic systems, which can be sources of biological and chemical pollutants to groundwater. In this study we tested 20 domestic drinking water wells in a sand and gravel aquifer on Cape Cod, Massachusetts, USA, for 117 organic wastewater compounds (OWCs) and for inorganic markers of septic system impact. We detected 27 OWCs, including 12 pharmaceuticals, five per- and polyfluoroalkyl substances (PFASs), four organophosphate flame retardants, and an artificial sweetener (acesulfame). Maximum concentrations of several PFASs and pharmaceuticals were relatively high compared to public drinking water supplies in the US. The number of detected OWCs and total concentrations of pharmaceuticals and of PFASs were positively correlated with nitrate, boron, and acesulfame and negatively correlated with well depth. These wells were all located in areas served exclusively by onsite wastewater treatment systems, which are likely the main source of the OWCs in these wells, although landfill leachate may also be a source. Our results suggest that current regulations to protect domestic wells from pathogens in septic system discharges do not prevent OWCs from reaching domestic wells, and that nitrate, a commonly measured drinking water contaminant, is a useful screening tool for OWCs in domestic wells. Nitrate concentrations of 1 mg/L NO{sub 3}-N, which are tenfold higher than local background and tenfold lower than the US federal drinking water standard, were associated with wastewater impacts from OWCs in this study. - Highlights: • We tested 20 domestic drinking water wells for 117 organic wastewater compounds. • PFASs, pharmaceuticals, and an artificial sweetener were most frequently detected. • Nitrate, boron, and well depth were all correlated with PFASs and pharmaceuticals. • Acesulfame

  5. Defense Logistics Agency Aviation Generally Purchased SoleSource Spare Parts From the General Electric Company at Fair and Reasonable Prices, but Improvements Could Be Made (Redacted)


    including: • FAR Subpart 2.1, “ Definitions ;” • FAR Part 10, “ Market Research;” • DFARS Subpart 215.4, “Contract Pricing ;” • DFARS PGI 212.1...Defense Logistics Agency Aviation Generally Purchased Sole‑Source Spare Parts From the General Electric Company at Fair and Reasonable Prices , but...Purchased Sole‑Source Spare Parts From the General Electric Company at Fair and Reasonable Prices , but Improvements Could Be Made Visit us at

  6. Septic systems as sources of organic wastewater compounds in domestic drinking water wells in a shallow sand and gravel aquifer.

    Schaider, Laurel A; Ackerman, Janet M; Rudel, Ruthann A


    Domestic drinking water wells serve 44 million people in the US and are common globally. They are often located in areas served by onsite wastewater treatment systems, including septic systems, which can be sources of biological and chemical pollutants to groundwater. In this study we tested 20 domestic drinking water wells in a sand and gravel aquifer on Cape Cod, Massachusetts, USA, for 117 organic wastewater compounds (OWCs) and for inorganic markers of septic system impact. We detected 27 OWCs, including 12 pharmaceuticals, five per- and polyfluoroalkyl substances (PFASs), four organophosphate flame retardants, and an artificial sweetener (acesulfame). Maximum concentrations of several PFASs and pharmaceuticals were relatively high compared to public drinking water supplies in the US. The number of detected OWCs and total concentrations of pharmaceuticals and of PFASs were positively correlated with nitrate, boron, and acesulfame and negatively correlated with well depth. These wells were all located in areas served exclusively by onsite wastewater treatment systems, which are likely the main source of the OWCs in these wells, although landfill leachate may also be a source. Our results suggest that current regulations to protect domestic wells from pathogens in septic system discharges do not prevent OWCs from reaching domestic wells, and that nitrate, a commonly measured drinking water contaminant, is a useful screening tool for OWCs in domestic wells. Nitrate concentrations of 1mg/L NO3-N, which are tenfold higher than local background and tenfold lower than the US federal drinking water standard, were associated with wastewater impacts from OWCs in this study.

  7. L-Arogenate is a chemoattractant which can be utilized as the sole source of carbon and nitrogen by Pseudomonas aeruginosa

    Fischer, R.S.; Song, Jian; Gu, Wei; Jensen, R.A. [Univ. of Florida, Gainesville, FL (United States)


    L-Arogenate is a commonplace amino acid in nature in consideration of its role as a ubiquitous precursor of L-phenylalanine and/or L-tyrosine. However, the questions of whether it serves as a chemoattractant molecule and whether it can serve as a substrate for catabolism have never been studied. We found that Pseudomonas aeruginosa recognizes L-arogenate as a chemoattractant molecule which can be utilized as a source of both carbon and nitrogen. Mutants lacking expression of either cyclohexadienyl dehydratase or phenylalanine hydroxylase exhibited highly reduced growth rates when utilizing L-arogenate as a nitrogen source. Utilization of L-arogenate as a source of either carbon or nitrogen was dependent upon {sub S}{sup 54}, as revealed by the use of an rpoN null mutant. The evidence suggests that catabolism of L-arogenate proceeds via alternative pathways which converge at 4-hydroxyphenylpyruvate. In one pathway, prephenate formed in the periplasm by deamination of L-arogenate is converted to 4-hydroxyphenylpyruvate by cyclohexadienyl dehydrogenase. The second route depends upon the sequential action of periplasmic cyclohexadienyl dehydratase, phenylalanine hydroxylase, and aromatic aminotransferase. 32 refs., 5 figs., 4 tabs.

  8. Alluvial Aquifer

    Kansas Data Access and Support Center — This coverage shows the extents of the alluvial aquifers in Kansas. The alluvial aquifers consist of unconsolidated Quaternary alluvium and contiguous terrace...

  9. Assessing sources of nitrate contamination in the Shiraz urban aquifer (Iran) using the δ(15)N and δ(18)O dual-isotope approach.

    Amiri, Haleh; Zare, Mohammad; Widory, David


    Nitrate ([Formula: see text]) is one of the major threats to the quality of the drinking water taken from the Shiraz aquifer. This aquifer undergoes high anthropogenic pressures from multiple local urban (including uncontrolled sewage systems), agricultural and industrial activities, resulting in [Formula: see text] concentrations as high as 149 mg L(-1), well above the 50 mg L(-1) guideline defined by the World Health Organisation. We coupled here classical chemical and dual isotope (δ(15)N and δ(18)O of [Formula: see text]) approaches trying to characterize sources and potential processes controlling the budget of this pollutant. Chemical data indicate that nitrate in this aquifer is explained by distinct end-members: while mineral fertilizers isotopically show to have no impact, our isotope approach identifies natural soil nitrification and organic [Formula: see text] (manure and/or septic waste) as the two main contributors. Isotope data suggest that natural denitrification may occur within the aquifer, but this conclusion is not supported by the study of other chemical parameters.

  10. Conceptual model of leachate migration in a granular aquifer derived from the integration of multi-source characterization data (St-Lambert, Canada)

    Tremblay, Laurie; Lefebvre, René; Paradis, Daniel; Gloaguen, Erwan


    Numerical models encompassing source zones and receptors, based on representative conceptual models and accounting for aquifer heterogeneity, are needed to understand contaminant migration and fate; however, aquifer characterization seldom provides the necessary data. This study aimed to develop a workflow for field characterization and data integration, which could: (1) be adapted to the definition of subwatershed-scale aquifer heterogeneity (over 10 km2) and (2) adequately support mass transport model development. The study involved the field investigation of a shallow granular aquifer in a 12-km2 subwatershed in Saint-Lambert-de-Lauzon, Canada, in which a decommissioned landfill is emitting a leachate plume managed by natural attenuation. Using proven field methods, the characterization sequence was designed to optimize each method in terms of location, scale of acquisition, density and quality. The emphasis was on the acquisition of detailed indirect geophysical data that were integrated with direct hydraulic and geochemical data. This report focuses on the first qualitative and geostatistical data integration steps of the workflow leading to the development of a hydrogeological conceptual model. This is a prerequisite for further integration steps: prediction of hydrofacies and hydraulic conductivity ( K), geostatistical simulations of K, studies of geochemical processes and numerical modeling.

  11. Modeling mass transport in aquifers: The distributed-source problem. Research report, July 1988-June 1990

    Serrano, S.E.


    A new methodology to model the time and space evolution of groundwater variables in a system of acquifers when certain components of the model, such as the geohydrologic information, the boundary conditions, the magnitude and variability of the sources or physical parameters are uncertain and defined in stochastic terms. This facilitates a more realistic statistical representation of groundwater flow and groundwater pollution forecasting for either the saturated or the unsaturated zone. The method is based on applications of modern mathematics to the solution of the resulting stochastic transport equations. The procedure exhibits considerable advantages over the existing stochastic modeling techniques.

  12. Geogenic sources of benzene in aquifers used for public supply, California

    Belitz, Kenneth; Landon, Matthew K.


    Statistical evaluation of two large statewide data sets from the California State Water Board's Groundwater Ambient Monitoring and Assessment Program (1973 wells) and the California Department of Public Health (12417 wells) reveals that benzene occurs infrequently (1.7%) and at generally low concentrations (median detected concentration of 0.024 μg/L) in groundwater used for public supply in California. When detected, benzene is more often related to geogenic (45% of detections) than anthropogenic sources (27% of detections). Similar relations are evident for the sum of 17 hydrocarbons analyzed. Benzene occurs most frequently and at the highest concentrations in old, brackish, and reducing groundwater; the detection frequency was 13.0% in groundwater with tritium 1600 μS/cm, and anoxic conditions. This groundwater is typically deep (>180 m). Benzene occurs somewhat less frequently in recent, shallow, and reducing groundwater; the detection frequency was 2.6% in groundwater with tritium ≥1 pCi/L, depth <30 m, and anoxic conditions. Evidence for geogenic sources of benzene include: higher concentrations and detection frequencies with increasing well depth, groundwater age, and proximity to oil and gas fields; and higher salinity and lower chloride/iodide ratios in old groundwater with detections of benzene, consistent with interactions with oil-field brines.

  13. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer is an important source of water...

  14. Geochemical and isotopic composition of ground water with emphasis on sources of sulfate in the upper Floridan Aquifer in parts of Marion, Sumter, and Citrus counties, Florida

    Sacks, Laura A.


    In inland areas of northwest central Florida, sulfate concentrations in the Upper Floridan aquifer are extremely variable and sometimes exceed drinking water standards (250 milligrams per liter). This is unusual because the aquifer is unconfined and near the surface, allowing for active recharge. The sources of sulfate and geochemical processes controlling ground-water composition were evaluated in this area. Water was sampled from thirty-three wells in parts of Marion, Sumter, and Citrus Counties, within the Southwest Florida Water Management District; these included at least a shallow and a deep well at fifteen separate locations. Ground water was analyzed for major ions, selected trace constituents, dissolved organic carbon, and stable isotopes (sulfur-34 of sulfate and sulfide, carbon-13 of inorganic carbon, deuterium, and oxygen-18). Sulfate concentrations ranged from less than 0.2 to 1,400 milligrams per liter, with higher sulfate concentrations usually in water from deeper wells. The samples can be categorized into a low sulfate group (less than 30 milligrams per liter) and a high sulfate group (greater than 30 milligrams per liter). For the high sulfate water, concentrations of calcium and magnesium increased concurrently with sulfate. Chemical and isotopic data and mass-balance modeling indicate that the composition of high sulfate waters is controlled by dedolomitization reactions (dolomite dissolution and calcite precipitation, driven by dissolution of gypsum). Gypsum occurs deeper in the aquifer than open intervals of sampled wells. Upward flow has been documented in deeper parts of the aquifer in the study area, which may be driven by localized discharge areas or rapid flow in shallow parts of the aquifer. Mixing between shallow ground water and sulfate-rich water that dissolved gypsum at the base of the aquifer is probably responsible for the range of concentrations observed in the study area. Other solutes that increased with sulfate apparently

  15. Methane Sources and Migration Mechanisms in the Shallow Trinity Aquifer in Parker and Hood Counties, Texas - a Noble Gas Analysis

    Wen, T.; Castro, C.; Nicot, J. P.; Hall, C. M.; Mickler, P. J.; Darvari, R.


    The presence of elevated methane in groundwaters within the Barnett Shale footprint in Parker and Hood counties, Texas has caused public concern that hydrocarbon production may facilitate migration of natural gas into a critical groundwater resource. This study places constraints on the source of methane in these groundwaters by analyzing water and stray gas data from groundwater wells and gas production wells from both the Barnett Shale and Strawn Group for methane content and noble gases, both of crustal and atmospheric origin. Particular emphasis is given to the atmospheric heavier noble gases 84Kr and 132Xe, which are significantly less affected by the presence of excess air, commonly present in modern Texas groundwaters (e.g., [1]). Dissolved methane concentrations are positively correlated with crustal 4He, 21Ne and 40Ar and suggest that noble gases and methane in these groundwaters originate from a common source, likely the Strawn Group, which the sampled aquifer overlies unconformably. This finding is further supported by the noble gas isotopic signature of stray gas when compared to the gas isotopic signatures of both Barnett Shale and the Strawn Group. In contrast to most samples, four groundwater wells with the highest methane concentrations unequivocally show heavy depletion of the atmospheric noble gases 20Ne, 36Ar, 84Kr and 132Xe with respect to freshwater recharge equilibrated with the atmosphere (ASW). This is consistent with predicted noble gas concentrations in a residual water phase in contact with a gas phase with initial ASW composition at 18°C-25°C, assuming a closed-system and suggest a highly localized gas source. All these four wells, without exception, tap into the Strawn Group and it is likely that shallow gas accumulations, as they are known to exist, were reached. Additionally, lack of correlation between 84Kr/36Ar and 132Xe/36Ar fractionation levels and distance to the nearest production wells does not support the notion that methane

  16. Arsenic and other oxyanion-forming trace elements in an alluvial basin aquifer: Evaluating sources and mobilization by isotopic tracers (Sr, B, S, O, H, Ra)

    Vinson, David S., E-mail: [Duke University, Division of Earth and Ocean Sciences, Box 90227, Durham, NC 27708 (United States); McIntosh, Jennifer C. [University of Arizona, Department of Hydrology and Water Resources, 1133 E. James E. Rogers Way, Tucson, AZ 85721 (United States); Dwyer, Gary S.; Vengosh, Avner [Duke University, Division of Earth and Ocean Sciences, Box 90227, Durham, NC 27708 (United States)


    Highlights: > Elevated natural As and F occur in the Willcox Basin aquifer of Arizona. > Oxyanion-forming elements are derived from volcanic-source aquifer sediments. > Sr isotopes trace sediment sources linked to oxyanion-forming trace elements. > {sup 87}Sr/{sup 86}Sr > 0.720 indicates Proterozoic crystalline-source sediment contributing low As. > Both sediment source and hydrogeochemical evolution (Ca/Na) affect As levels. - Abstract: The Willcox Basin is a hydrologically closed basin in semi-arid southeastern Arizona (USA) and, like many other alluvial basins in the southwestern USA, is characterized by oxic, near-neutral to slightly basic groundwater containing naturally elevated levels of oxyanion-forming trace elements such as As. This study evaluates the sources and mobilization of these oxyanionic trace elements of health significance by using several isotopic tracers of water-rock interaction and groundwater sources ({sup 87}Sr/{sup 86}Sr, {delta}{sup 34}S{sub SO4}, {delta}{sup 11}B, {delta}{sup 2}H, {delta}{sup 18}O, {sup 3}H). Values of {delta}{sup 2}H (-85 per mille to -64 per mille) and {delta}{sup 18}O (-11.8 per mille to -8.6 per mille) are consistent with precipitation and groundwater in adjacent alluvial basins, and low to non-detectable {sup 3}H activities further imply that modern recharge is slow in this semi-arid environment. Large variations in {sup 87}Sr/{sup 86}Sr ratios imply that groundwater has interacted with multiple sediment sources that constitute the basin-fill aquifer, including Tertiary felsic volcanic rocks, Paleozoic sedimentary rocks, and Proterozoic crystalline rocks. In general, low concentrations of oxyanion-forming trace elements and F{sup -} are associated with a group of waters exhibiting highly radiogenic values of {sup 87}Sr/{sup 86}Sr (0.72064-0.73336) consistent with waters in Proterozoic crystalline rocks in the mountain blocks (0.73247-0.75010). Generally higher As concentrations (2-29 {mu}g L{sup -1}), other

  17. Monitoring priority substances, other organic contaminants and heavy metals in a volcanic aquifer from different sources and hydrological processes

    Estevez, Esmeralda, E-mail: [Dpt. Física (GEOVOL), Universidad de Las Palmas de Gran Canaria, 35017 Las Palmas de Gran Canaria, Canary Islands (Spain); Agrifood and Phytopathological Laboratory (Cabildo de Gran Canaria), 35413 Arucas, Canary Islands (Spain); Cabrera, María del Carmen, E-mail: [Dpt. Física (GEOVOL), Universidad de Las Palmas de Gran Canaria, 35017 Las Palmas de Gran Canaria, Canary Islands (Spain); IMDEA Water Institute, Alcalá de Henares, Madrid (Spain); Fernández-Vera, Juan Ramón, E-mail: [Agrifood and Phytopathological Laboratory (Cabildo de Gran Canaria), 35413 Arucas, Canary Islands (Spain); Molina-Díaz, Antonio, E-mail: [Analytical Chemistry Research Group, Department of Physical and Analytical Chemistry, University of Jaen, 23071 Jaen (Spain); Robles-Molina, José, E-mail: [Analytical Chemistry Research Group, Department of Physical and Analytical Chemistry, University of Jaen, 23071 Jaen (Spain); Palacios-Díaz, María del Pino, E-mail: [Dpt. de Patología Animal, Producción Animal, Bromatología y Tecnología de los Alimentos (GEOVOL), Universidad de Las Palmas de Gran Canaria, 35413 Arucas, Canary Islands (Spain)


    Irrigation with reclaimed water (R) is necessary to guarantee the sustainability of semi-arid areas. Results obtained during a two years monitoring network (2009–2011) in Gran Canaria are presented, including the analysis of chemical parameters, N and S isotopes, priority substances (2008/105/EC, 2013/39/EU), other organic contaminants and heavy metals in groundwater and R used to irrigate a golf course. The aims of this work are to evaluate the contamination in a volcanic aquifer, relate the presence of organic contaminants and heavy metals with the hydrogeochemistry and identify pollution sources in the area. No priority substance exceeded the EU thresholds for surface water, although seventeen were detected in R. The most frequent compounds were hexachlorobenzene, chlorpyrifos ethyl, fluorene, phenanthrene and pyrene. These compounds were detected at low concentration, except chlorpyrifos. Chlorpyrifos ethyl, terbuthylazine, diuron, terbutryn, procymidone, atrazine and propazine exceeded the European threshold concentration for pesticides in groundwater (100 ng L{sup −1}). Therefore, the priority substances chlorpyrifos ethyl and diuron must be included in monitoring studies. The priority pesticides chlorfenvinphos and diazinon were always detected in R but rarely in groundwater. Besides, the existence of contaminants not related to the current R irrigation has been identified. Absence of environmental problems related to heavy metals can be expected. The relationship among contaminant presence, hydrogeochemistry, including the stable isotopic prints of δ{sup 18}O, δ{sup 15}N and δ{sup 34}S and preferential recharge paths has been described. The coastal well shows high values of EC, nitrate, a variable chemistry, and 50% of organic contaminants detected above 100 ng L{sup −1}. The well located in the recharge area presents a stable hydrochemistry, the lowest value of δ{sup 15}N and the lowest contaminants occurrence. The area is an example of a complex

  18. The Southern Hills regional aquifer system of southeastern Louisiana and southwestern Mississippi

    Buono, A.


    The Southern Hills regional aquifer system, named in a petition to the Environmental Protection Agency for designation as a sole or principal source of drinking water, is the primary source of public and domestic supplies in the northern 10 parishes of southeastern Louisiana. The gulfward dipping and thickening, complexly interbedded aquifer system extends from the northern limit of the recharge area near Vicksburg, Mississippi, as far as the Baton Rouge area in southeastern Louisiana. As many as 13 interdependent aquifer units compose the system in the southern part of the area and are known to coalesce or pinch out northward (updip) into fewer units. Aquifer water is almost exclusively a soft, sodium bicarbonate type with an average dissolved-solids concentration of about 220 milligrams per liter in southeastern Louisiana. Although several streams are available as alternatives for supply, they have not been accepted by local officials because of the additional water treatment that would be necessary and the extensive distribution system needed to deliver water to areas not near a source stream. Groundwater use in 1980 for public and domestic supply averaged 121 Mgal/d (million gallons per day), serving 744,000 people in southeastern Louisiana. In southwestern Mississippi, where the aquifer system is also the primary source for public and domestic supply, water use for these categories in 1980 totaled 25 Mgal/d, serving about 273,000 people. (USGS)

  19. Carbonate aquifers

    Cunningham, Kevin J.; Sukop, Michael; Curran, H. Allen


    Only limited hydrogeological research has been conducted using ichnology in carbonate aquifer characterization. Regardless, important applications of ichnology to carbonate aquifer characterization include its use to distinguish and delineate depositional cycles, correlate mappable biogenically altered surfaces, identify zones of preferential groundwater flow and paleogroundwater flow, and better understand the origin of ichnofabric-related karst features. Three case studies, which include Pleistocene carbonate rocks of the Biscayne aquifer in southern Florida and Cretaceous carbonate strata of the Edwards–Trinity aquifer system in central Texas, demonstrate that (1) there can be a strong relation between ichnofabrics and groundwater flow in carbonate aquifers and (2) ichnology can offer a useful methodology for carbonate aquifer characterization. In these examples, zones of extremely permeable, ichnofabric-related macroporosity are mappable stratiform geobodies and as such can be represented in groundwater flow and transport simulations.

  20. A computationally simplistic poly-phasic approach to explore microbial communities from the Yucatan aquifer as a potential sources of novel natural products.

    Marfil-Santana, Miguel David; O'Connor-Sánchez, Aileen; Ramírez-Prado, Jorge Humberto; De Los Santos-Briones, Cesar; López-Aguiar; Lluvia, Korynthia; Rojas-Herrera, Rafael; Lago-Lestón, Asunción; Prieto-Davó, Alejandra


    The need for new antibiotics has sparked a search for the microbes that might potentially produce them. Current sequencing technologies allow us to explore the biotechnological potential of microbial communities in diverse environments without the need for cultivation, benefitting natural product discovery in diverse ways. A relatively recent method to search for the possible production of novel compounds includes studying the diverse genes belonging to polyketide synthase pathways (PKS), as these complex enzymes are an important source of novel therapeutics. In order to explore the biotechnological potential of the microbial community from the largest underground aquifer in the world located in the Yucatan, we used a polyphasic approach in which a simple, non-computationally intensive method was coupled with direct amplification of environmental DNA to assess the diversity and novelty of PKS type I ketosynthase (KS) domains. Our results suggest that the bioinformatic method proposed can indeed be used to assess the novelty of KS enzymes; nevertheless, this in silico study did not identify some of the KS diversity due to primer bias and stringency criteria outlined by the metagenomics pipeline. Therefore, additionally implementing a method involving the direct cloning of KS domains enhanced our results. Compared to other freshwater environments, the aquifer was characterized by considerably less diversity in relation to known ketosynthase domains; however, the metagenome included a family of KS type I domains phylogenetically related, but not identical, to those found in the curamycin pathway, as well as an outstanding number of thiolases. Over all, this first look into the microbial community found in this large Yucatan aquifer and other fresh water free living microbial communities highlights the potential of these previously overlooked environments as a source of novel natural products.

  1. Inquiry and Aquifers.

    Leuenberger, Ted; Shepardson, Daniel; Harbor, Jon; Bell, Cheryl; Meyer, Jason; Klagges, Hope; Burgess, Willie


    Presents inquiry-oriented activities that acquaint students with groundwater sources, movement of water through aquifers, and contamination of groundwater by pollution. In one activity, students use well log data from web-based resources to explore groundwater systems. Provides sample well log data for those not having access to local information.…

  2. Inquiry and Aquifers.

    Leuenberger, Ted; Shepardson, Daniel; Harbor, Jon; Bell, Cheryl; Meyer, Jason; Klagges, Hope; Burgess, Willie


    Presents inquiry-oriented activities that acquaint students with groundwater sources, movement of water through aquifers, and contamination of groundwater by pollution. In one activity, students use well log data from web-based resources to explore groundwater systems. Provides sample well log data for those not having access to local information.…

  3. Ozark Aquifer

    Kansas Data Access and Support Center — These digital maps contain information on the altitude of the base and top, the extent, and the potentiometric surface of the Ozark aquifer in Kansas. The Ozark...

  4. Hydrogeology - AQUIFER_SYSTEMS_BEDROCK_IDNR_IN: Bedrock Aquifer Systems of Indiana (Indiana Department of Natural Resources, 1:500,000, Polygon Shapefile)

    NSGIC State | GIS Inventory — AQUIFER_SYSTEMS_BEDROCK_IDNR_IN is a polygon shapefile that shows bedrock aquifer systems of the State of Indiana. The source scale of the map depicting the aquifers...

  5. Hydrogeology - AQUIFER_SYSTEMS_BEDROCK_IDNR_IN: Bedrock Aquifer Systems of Indiana (Indiana Department of Natural Resources, 1:500,000, Polygon Shapefile)

    NSGIC GIS Inventory (aka Ramona) — AQUIFER_SYSTEMS_BEDROCK_IDNR_IN is a polygon shapefile that shows bedrock aquifer systems of the State of Indiana. The source scale of the map depicting the aquifers...

  6. Polyhydroxyalkanoate as a slow-release carbon source for in situ bioremediation of contaminated aquifers: From laboratory investigation to pilot-scale testing in the field.

    Pierro, Lucia; Matturro, Bruna; Rossetti, Simona; Sagliaschi, Marco; Sucato, Salvatore; Alesi, Eduard; Bartsch, Ernst; Arjmand, Firoozeh; Papini, Marco Petrangeli


    A pilot-scale study aiming to evaluate the potential use of poly-3-hydroxy-butyrate (PHB) as an electron donor source for in situ bioremediation of chlorinated hydrocarbons in groundwater was conducted. Compared with commercially available electron donors, PHB offers a restricted fermentation pathway (i.e., through acetic acid and molecular hydrogen) by avoiding the formation of any residual carbon that could potentially spoil groundwater quality. The pilot study was carried out at an industrial site in Italy, heavily contaminated by different chlorinated aliphatic hydrocarbons (CAHs). Prior to field testing, PHB was experimentally verified as a suitable electron donor for biological reductive dechlorination processes at the investigated site by microcosm studies carried out on site aquifer material and measuring the quantitative transformation of detected CAHs to ethene. Owing to the complex geological characteristics of the aquifer, the use of a groundwater circulation well (GCW) was identified as a potential strategy to enable effective delivery and distribution of electron donors in less permeable layers and to mobilise contaminants. A 3-screened, 30-m-deep GCW coupled with an external treatment unit was installed at the site. The effect of PHB fermentation products on the in situ reductive dechlorination processes were evaluated by quantitative real-time polymerase chain reaction (qPCR). The results from the first 4 months of operation clearly demonstrated that the PHB fermentation products were effectively delivered to the aquifer and positively influenced the biological dechlorination activity. Indeed, an increased abundance of Dehalococcoides mccartyi (up to 6.6 fold) and reduced CAH concentrations at the installed monitoring wells were observed.

  7. Monitoring Groundwater Temperatures in a Shallow Urban Aquifer Before, During and After Installation of a Ground Source Heat System in Cardiff, U.K.

    Patton, Ashley M.; Farr, Gareth J.; Boon, David P.; James, David R.; Williams, Bernard; Tucker, David; Harcombe, Gareth


    Exploitation of shallow urban aquifers, warmed by the Urban Heat Island Effect, is a relatively new concept in the U.K. An extensive groundwater temperature baseline monitoring network has been established for a shallow superficial aquifer in the city of Cardiff, U.K., to characterise groundwater temperatures and monitor the impacts of the first open-loop ground source heat pump (GSHP) installed in the city. In Spring 2014, temperature profiling was carried out at 1m depth intervals at 168 groundwater monitoring boreholes across Cardiff, establishing baseline groundwater temperatures within the shallow (form the first U.K. 2D city heat map. During the warmest time of year, Autumn 2014, a subset of boreholes were re-profiled to ascertain seasonal temperature variation, defining the Zone of Seasonal Fluctuation. Re-profiling was again carried out at these boreholes in Autumn 2015 to confirm these temperatures as normal for that time of year. By comparing Spring and Autumn profiles, the average depth to the base of the Zone of Seasonal Fluctuation was found to be 9.5mbgl. Two >100m boreholes showed the urban warming effect may extend to 80mbgl, before temperatures follow the predicted geothermal gradient. We term this the Zone of Anthropogenic Influence. After initial baseline temperatures were established, a site was selected for the installation of a shallow GSHP. Before installation work began, a monitoring network was set up to establish a temperature baseline for future GSHPs and identify any impacts on the thermal resource caused by removing ~2°C from the abstracted groundwater prior to reinjection into the aquifer. This comprised of 97 temperature loggers in 60 boreholes, including the abstraction and recharge boreholes and boreholes up and down gradient of the site. Some of these boreholes have multiple loggers at different depths, including the near-surface, but the majority of loggers were placed within the boreholes' slotted sections, below the base of the

  8. Transient heterogeneity in an aquifer undergoing bioremediation of hydrocarbons.

    Schillig, P C; Devlin, J F; Roberts, J A; Tsoflias, G P; McGlashan, M A


    Localized, transient heterogeneity was studied in a sand aquifer undergoing benzene, toluene, ethylbenzene, and xylene bioremediation using a novel array of multilevel, in situ point velocity probes (PVPs). The experiment was conducted within a sheet-pile alleyway to maintain a constant average flow direction through time. The PVPs measured changes in groundwater velocity direction and magnitude at the centimeter scale, making them ideal to monitor small-scale changes in hydraulic conductivity (K). Velocities were shown to vary nonuniformly by up to a factor of 3 when a source of oxygen was established down-gradient of the petroleum spill. In spite of these local variations, the average groundwater velocity within the 7 m × 20 m sheet-piled test area only varied within ± 25%. The nonuniform nature of the velocity variations across the gate indicated that the changes were not due solely to seasonal hydraulic gradient fluctuations. At the conclusion of the experiment, microbial biomass levels in the aquifer sediments was approximately 1 order of magnitude higher in the oxygen-amended portion of the aquifer than at the edge of the plume or in locations up-gradient of the source. These data suggest that the transient velocities resulted, at least in part, from enhanced biological activity that caused transient heterogeneities in the porous medium.

  9. A new approach to the modification of cell membrane glycosphingolipids: Ganglioside composition of JTC-12 P3 cells altered by feeding with galactose as a sole carbohydrate source in protein- and lipid-free synthetic medium

    Kawaguchi, Tatsuya (Univ. of Tokyo (Japan) Kumamoto Univ. Medical School (Japan)); Takaoka, Toshiko; Yoshida, Eiko (Univ. of Tokyo (Japan)); Iwamori, Masao; Nagai, Yoshitaka (Univ. of Tokyo (Japan) Niigata Univ. (Japan)); Takatsuki, Kiyoshi (Kumamoto Univ. Medical School (Japan))


    A significant difference in the glycosphingolipid composition of JTC-12 P3 cells established from monkey kidney tissue was observed when cells cultured in a protein- and lipid-free synthetic medium containing glucose (DM-160) as a sole carbohydrate source were transferred and cultured in the same medium containing galactose and pyruvic acid (DM-170) in place of glucose. In particular, the amounts of gangliosides GM3, GM2, and GD3 in the cells cultured in DM-170 were 5.3-, 17.8-, and more than 8-fold those in the cells cultured in DM-160, respectively, indicating that anabolism of gangliosides is greatly enhanced in cells cultured in the presence of galactose and pyruvic acid, as compared with cells cultured in the presence of glucose. In fact, after cultivation of cells in the medium with N-acetyl-D-({sup 14}C)mannosamine for 96 h, the radioactivity incorporated into the gangliosides of the cells in DM-170 was 10-fold that of the cells in DM-160. Among the gangliosides of the cells in DM-170, highly sialylated molecules such as GD3, GD1a, GD1b, and GT1b were preferentially labeled, indicating that the sialytransferases responsible for the synthesis of gangliosides are significantly more activated in cells cultured in DM-170 than in DM-160. These observations reveal that the glycosphingolipid composition of the plasma membrane can be modified epigenetically under well-defined conditions and provide important clues for clarifying the roles of glycosphingolipids associated with particular cell functions.

  10. Combining stable isotopes with contamination indicators: A method for improved investigation of nitrate sources and dynamics in aquifers with mixed nitrogen inputs.

    Minet, E P; Goodhue, R; Meier-Augenstein, W; Kalin, R M; Fenton, O; Richards, K G; Coxon, C E


    Excessive nitrate (NO3(-)) concentration in groundwater raises health and environmental issues that must be addressed by all European Union (EU) member states under the Nitrates Directive and the Water Framework Directive. The identification of NO3(-) sources is critical to efficiently control or reverse NO3(-) contamination that affects many aquifers. In that respect, the use of stable isotope ratios (15)N/(14)N and (18)O/(16)O in NO3(-) (expressed as δ(15)N-NO3(-) and δ(18)O-NO3(-), respectively) has long shown its value. However, limitations exist in complex environments where multiple nitrogen (N) sources coexist. This two-year study explores a method for improved NO3(-) source investigation in a shallow unconfined aquifer with mixed N inputs and a long established NO3(-) problem. In this tillage-dominated area of free-draining soil and subsoil, suspected NO3(-) sources were diffuse applications of artificial fertiliser and organic point sources (septic tanks and farmyards). Bearing in mind that artificial diffuse sources were ubiquitous, groundwater samples were first classified according to a combination of two indicators relevant of point source contamination: presence/absence of organic point sources (i.e. septic tank and/or farmyard) near sampling wells and exceedance/non-exceedance of a contamination threshold value for sodium (Na(+)) in groundwater. This classification identified three contamination groups: agricultural diffuse source but no point source (D+P-), agricultural diffuse and point source (D+P+) and agricultural diffuse but point source occurrence ambiguous (D+P±). Thereafter δ(15)N-NO3(-) and δ(18)O-NO3(-) data were superimposed on the classification. As δ(15)N-NO3(-) was plotted against δ(18)O-NO3(-), comparisons were made between the different contamination groups. Overall, both δ variables were significantly and positively correlated (p contamination groups revealed that denitrification did not occur in the absence of point source

  11. Methane baseline concentrations and sources in shallow aquifers from the shale gas-prone region of the St. Lawrence lowlands (Quebec, Canada).

    Moritz, Anja; Hélie, Jean-Francois; Pinti, Daniele L; Larocque, Marie; Barnetche, Diogo; Retailleau, Sophie; Lefebvre, René; Gélinas, Yves


    Hydraulic fracturing is becoming an important technique worldwide to recover hydrocarbons from unconventional sources such as shale gas. In Quebec (Canada), the Utica Shale has been identified as having unconventional gas production potential. However, there has been a moratorium on shale gas exploration since 2010. The work reported here was aimed at defining baseline concentrations of methane in shallow aquifers of the St. Lawrence Lowlands and its sources using δ(13)C methane signatures. Since this study was performed prior to large-scale fracturing activities, it provides background data prior to the eventual exploitation of shale gas through hydraulic fracturing. Groundwater was sampled from private (n = 81), municipal (n = 34), and observation (n = 15) wells between August 2012 and May 2013. Methane was detected in 80% of the wells with an average concentration of 3.8 ± 8.8 mg/L, and a range of -50‰, indicating a potential thermogenic source. Localized areas of high methane concentrations from predominantly biogenic sources were found throughout the study area. In several samples, mixing, migration, and oxidation processes likely affected the chemical and isotopic composition of the gases, making it difficult to pinpoint their origin. Energy companies should respect a safe distance from major natural faults in the bedrock when planning the localization of hydraulic fracturation activities to minimize the risk of contaminating the surrounding groundwater since natural faults are likely to be a preferential migration pathway for methane.

  12. Lithology, hydrologic characteristics, and water quality of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas

    Kresse, Timothy M.; Westerman, Drew A.; Hart, Rheannon M.


    A study to assess the potential of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas, as a viable source of public-supply water was conducted by the U.S. Geological Survey in cooperation with the Little Rock, District, U.S. Army Corps of Engineers. An important study component was to identify possible changes in hydrologic conditions following installation of James W. Trimble Lock and Dam 13 (December 1969) on the Arkansas River near the study area. Data were gathered for the study in regard to the lithology, hydrologic characteristics, and water quality of the aquifer. Lithologic information was obtained from drillers’ logs of wells drilled from 1957 through 1959. Water-quality samples were collected from 10 irrigation wells and analyzed for inorganic constituents and pesticides. To evaluate the potential viability of the alluvial aquifer in the Van Buren area, these data were compared to similar stratigraphic, lithologic, and groundwater-quality data from the Arkansas River Valley alluvial aquifer at Dardanelle, Ark., where the aquifer provides a proven, productive, sole-source of public-supply water.

  13. Wuxia's Children Shoes sole: Touching Children's Heart


    @@ Wuxia Children shoes sole company, founded in 1998, is the first professional children shoes sole business in Wenzhou city. It is located in Huanglong Commercial Center,Wenzhou city, Zhejiang province.

  14. Percentage of probability of nonpoint-source nitrate contamination of recently recharged ground water in the High Plains aquifer

    U.S. Geological Survey, Department of the Interior — This raster data set represents the percentage of probability of nonpoint-source nitrate contamination (greater than the proposed background concentration of 4...

  15. Source of salts in the Waianae part of the Pearl Harbor aquifer near Barbers Point water tunnel, Oahu, Hawaii

    Eyre, P.R.


    The salinity of the water supply of Barbers Point Naval Air Station has increased markedly since 1983. The Naval Air Station obtains its water, about 3 million gal/day, from Barbers Point shaft, a water shaft that taps the Waianae part of the Pearl Harbor aquifer underlying the dry, southeastern flank of the Waianae mountains on the island on Oahu, Hawaii. From 1983 to 1985 the chloride concentration of the water, increased from 220 to 250 mg/L and has remained near that level through 1986. The EPA has established 250 mg/L as the maximum recommended chloride concentration in drinking water because above that level many people can taste the salt. The high chloride concentration in shallow groundwater at all wells in the area indicates that most of the salts in the freshwater lens are contributed by rainfall, sea spray, and irrigation return water. At Barbers Point shaft, pumping may draw a small amount of saltwater from the transition zone and increase the chloride concentration in the pumped water by about 20 mg/L. Salinity of the lens decreases progressively inland in response to recharge from relatively fresher water and in response to an increasing lens thickness with increasing distance from the shoreline. The increase, in 1983, in the chloride concentration of water at the shaft was most probably the result of saltier recharge water reaching the water table, and not the result of increased mixing of underlying saltwater with the freshwater. The chloride concentration of the recharge water has probably increased because, in 1980, the drip method of irrigation began to replace the furrow method on sugarcane fields near the shaft. A mixing-cell model was used to estimate the effect of drip irrigation on the chloride concentration of the groundwater in the vicinity of Barbers Point shaft. The model predicted an increase in chloride concentration of about 50 mg/L. The observed increase was about 30 mg/L and the chloride concentration is presently stable at 245 to

  16. Regional assessment of concentrations and sources of pharmaceutically active compounds, pesticides, nitrate, and E. coli in post-glacial aquifer environments (Canada).

    Saby, Marion; Larocque, Marie; Pinti, Daniele L; Barbecot, Florent; Gagné, Sylvain; Barnetche, Diogo; Cabana, Hubert


    There is growing concern worldwide about the exposure of groundwater resources to pharmaceutically active compounds (PhACs) and agricultural contaminants, such as pesticides, nitrate, and Escherichia coli. For regions with a low population density and an abundance of water, regional contamination assessments are not carried out systematically due to the typically low concentrations and high costs of analyses. The objectives of this study were to evaluate regional-scale contaminant distributions in untreated groundwater in a rural region of Quebec (Canada). The geological and hydrogeological settings of this region are typical of post-glacial regions around the world, where groundwater flow can be complex due to heterogeneous geological conditions. A new spatially distributed Anthropogenic Footprint Index (AFI), based on land use data, was developed to assess surface pollution risks. The Hydrogeochemical Vulnerability Index (HVI) was computed to estimate aquifer vulnerability. Nine wells had detectable concentrations of one to four of the 13 tested PhACs, with a maximum concentration of 116ng·L(-1) for benzafibrate. A total of 34 of the 47 tested pesticides were detected in concentrations equal to or greater than the detection limit, with a maximum total pesticide concentration of 692ng·L(-1). Nitrate concentrations exceeded 1mg·L(-1) N-NO3 in 15.3% of the wells, and the Canadian drinking water standard was exceeded in one well. Overall, 13.5% of the samples had detectable E. coli. Including regional-scale sources of pollutants to the assessment of aquifer vulnerability with the AFI did not lead to the identification of contaminated wells, due to the short groundwater flow paths between recharge and the sampled wells. Given the occurrence of contaminants, the public health concerns stemming from these new data on regional-scale PhAC and pesticide concentrations, and the local flow conditions observed in post-glacial terrains, there is a clear need to investigate

  17. DESIGN OF AQUIFER REMEDIATION SYSTEMS: (2) Estimating site-specific performance and benefits of partial source removal

    A Lagrangian stochastic model is proposed as a tool that can be utilized in forecasting remedial performance and estimating the benefits (in terms of flux and mass reduction) derived from a source zone remedial effort. The stochastic functional relationships that describe the hyd...

  18. Engineering E. coli for the biosynthesis of 3-hydroxy-γ-butyrolactone (3HBL) and 3,4-dihydroxybutyric acid (3,4-DHBA) as value-added chemicals from glucose as a sole carbon source.

    Dhamankar, Himanshu; Tarasova, Yekaterina; Martin, Collin H; Prather, Kristala L J


    3-hydroxy-γ-butyrolactone (3HBL) is a versatile chiral synthon, deemed a top value-added chemical from biomass by the DOE. We recently reported the first biosynthetic pathway towards 3HBL and its hydrolyzed form, 3,4-dihydroxybutyric acid (3,4-DHBA) in recombinant Escherichia coli using glucose and glycolic acid as feedstocks and briefly described their synthesis solely from glucose. Synthesis from glucose requires integration of the endogenous glyoxylate shunt with the 3,4-DHBA/3HBL pathway and co-overexpression of seven genes, posing challenges with respect to expression, repression of the glyoxylate shunt and optimal carbon distribution between the two pathways. Here we discuss engineering this integration. While appropriate media and over-expression of glyoxylate shunt enzymes helped overcome repression, two orthogonal expression systems were employed to address the expression and carbon distribution challenge. Synthesis of up to 0.3g/L of 3HBL and 0.7g/L of 3,4-DHBA solely from glucose was demonstrated, amounting to 24% of the theoretical maximum.

  19. 40 CFR 146.4 - Criteria for exempted aquifers.


    ... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Criteria for exempted aquifers. 146.4... for exempted aquifers. An aquifer or a portion thereof which meets the criteria for an “underground source of drinking water” in § 146.3 may be determined under 40 CFR 144.8 to be an “exempted aquifer”...

  20. Evaluating the Sources and Fate of Nitrate in the Alluvial Aquifers in the Shijiazhuang Rural and Suburban Area, China: Hydrochemical and Multi-Isotopic Approaches

    Yanpeng Zhang


    Full Text Available The identification of the sources and fate of NO\\(_{3}^{-}\\ contaminants is important to protect the water quality of aquifer systems. In this study, NO\\(_{3}^{-}\\ contaminated groundwater from the drinking water wells in the Shijiazhuang area, China, was chemically (NO\\(_{3}^{-}\\/Cl\\(^{\\rm{{-}}}\\ ratio and isotopically (\\(δ\\\\(^{\\rm{15}}\\N\\(_{\\rm{NO3}}\\, \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{NO3}}\\ and \\(\\delta\\\\(^{\\rm{13}}\\C\\(_{\\rm{DOC}}\\; \\(\\delta\\\\(^{\\rm{2}}\\H\\(_{\\rm{H2O}}\\, \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{H2O}}\\ characterized to identify the sources of NO\\(_{3}^{-}\\ and address subsequent biogeochemical processes. The positive correlations between dominant anions and cations suggested that the dissolution of calcium carbonate and gypsum minerals was the most effective process in the groundwater. Elevated concentrations of NO\\(_{3}^{-}\\, Cl\\(^{\\rm{{-}}}\\ and Mg\\(^{\\rm{2+}}\\ could be related to the wastewater irrigation and usage of fertilizers. The natural water in the study area originated primarily from precipitation and experienced a limited extent of evaporation, as demonstrated by measurements of \\(\\delta\\\\(^{\\rm{2}}\\H\\(_{\\rm{H2O}}\\ and \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{H2O}}\\. A cross-plot of \\(\\delta\\\\(^{\\rm{15}}\\N\\(_{\\rm{NO3}}\\ vs. \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{NO3}}\\ gave an enrichment of the 15N isotope relative to the 18O isotope by a factor of 2. A further insight into the denitrification process was obtained by the synergistic changes in \\(\\delta\\\\(^{\\rm{13}}\\C\\(_{\\rm{DOC}}\\ and \\(\\delta\\\\(^{\\rm{15}}\\N\\(_{\\rm{NO3}}\\ values, confirming that a low extent of denitrification occurred. Nitrification processes were evaluated by means of \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{NO3}}\\ and \\(\\delta\\\\(^{\\rm{18}}\\O\\(_{\\rm{H2O}}\\. The initial \\(\\delta\\\\(^{\\rm{15}}\\N\\(_{\\rm{NO3}}\\ value(s of the NO\\(_{3}^{-}\\ source(s

  1. Stable isotope and noble gas constraints on the source and residence time of spring water from the Table Mountain Group Aquifer, Paarl, South Africa and implications for large scale abstraction

    Miller, J. A.; Dunford, A. J.; Swana, K. A.; Palcsu, L.; Butler, M.; Clarke, C. E.


    Large scale groundwater abstraction is increasingly being used to support large urban centres especially in areas of low rainfall but presents particular challenges in the management and sustainability of the groundwater system. The Table Mountain Group (TMG) Aquifer is one of the largest and most important aquifer systems in South Africa and is currently being considered as an alternative source of potable water for the City of Cape Town, a metropolis of over four million people. The TMG aquifer is a fractured rock aquifer hosted primarily in super mature sandstones, quartzites and quartz arenites. The groundwater naturally emanates from numerous springs throughout the cape region. One set of springs were examined to assess the source and residence time of the spring water. Oxygen and hydrogen isotopes indicate that the spring water has not been subject to evaporation and in combination with Na/Cl ratios implies that recharge to the spring systems is via coastal precipitation. Although rainfall in the Cape is usually modelled on orographic rainfall, δ18O and δ2H values of some rainfall samples are strongly positive indicating a stratiform component as well. Comparing the spring water δ18O and δ2H values with that of local rainfall, indicates that the springs are likely derived from continuous bulk recharge over the immediate hinterland to the springs and not through large and/or heavy downpours. Noble gas concentrations, combined with tritium and radiocarbon activities indicate that the residence time of the TMG groundwater in this area is decadal in age with a probable maximum upper limit of ∼40 years. This residence time is probably a reflection of the slow flow rate through the fractured rock aquifer and hence indicates that the interconnectedness of the fractures is the most important factor controlling groundwater flow. The short residence time of the groundwater suggest that recharge to the springs and the Table Mountain Group Aquifer as a whole is

  2. Separation and capture of CO2 from large stationary sources and sequestration in geological formations--coalbeds and deep saline aquifers.

    White, Curt M; Strazisar, Brian R; Granite, Evan J; Hoffman, James S; Pennline, Henry W


    The topic of global warming as a result of increased atmospheric CO2 concentration is arguably the most important environmental issue that the world faces today. It is a global problem that will need to be solved on a global level. The link between anthropogenic emissions of CO2 with increased atmospheric CO2 levels and, in turn, with increased global temperatures has been well established and accepted by the world. International organizations such as the United Nations Framework Convention on Climate Change (UNFCCC) and the Intergovernmental Panel on Climate Change (IPCC) have been formed to address this issue. Three options are being explored to stabilize atmospheric levels of greenhouse gases (GHGs) and global temperatures without severely and negatively impacting standard of living: (1) increasing energy efficiency, (2) switching to less carbon-intensive sources of energy, and (3) carbon sequestration. To be successful, all three options must be used in concert. The third option is the subject of this review. Specifically, this review will cover the capture and geologic sequestration of CO2 generated from large point sources, namely fossil-fuel-fired power gasification plants. Sequestration of CO2 in geological formations is necessary to meet the President's Global Climate Change Initiative target of an 18% reduction in GHG intensity by 2012. Further, the best strategy to stabilize the atmospheric concentration of CO2 results from a multifaceted approach where sequestration of CO2 into geological formations is combined with increased efficiency in electric power generation and utilization, increased conservation, increased use of lower carbon-intensity fuels, and increased use of nuclear energy and renewables. This review covers the separation and capture of CO2 from both flue gas and fuel gas using wet scrubbing technologies, dry regenerable sorbents, membranes, cryogenics, pressure and temperature swing adsorption, and other advanced concepts. Existing

  3. Hydrology of the Claiborne aquifer and interconnection with the Upper Floridan aquifer in southwest Georgia

    Gordon, Debbie W.; Gonthier, Gerard


    The U.S. Geological Survey conducted a study, in cooperation with the Georgia Environmental Protection Division, to define the hydrologic properties of the Claiborne aquifer and evaluate its connection with the Upper Floridan aquifer in southwest Georgia. The effort involved collecting and compiling hydrologic data from the aquifer in subarea 4 of southwestern Georgia. Data collected for this study include borehole geophysical logs in 7 wells, and two 72-hour aquifer tests to determine aquifer properties.The top of the Claiborne aquifer extends from an altitude of about 200 feet above the North American Vertical Datum of 1988 (NAVD 88) in Terrell County to 402 feet below NAVD 88 in Decatur County, Georgia. The base of the aquifer extends from an altitude of about 60 feet above NAVD 88 in eastern Sumter County to about 750 feet below NAVD 88 in Decatur County. Aquifer thickness ranges from about 70 feet in eastern Early County to 400 feet in Decatur County.The transmissivity of the Claiborne aquifer, determined from two 72-hour aquifer tests, was estimated to be 1,500 and 700 feet squared per day in Mitchell and Early Counties, respectively. The storage coefficient was estimated to be 0.0006 and 0.0004 for the same sites, respectively. Aquifer test data from Mitchell County indicate a small amount of leakage occurred during the test. Groundwater-flow models suggest that the source of the leakage was the underlying Clayton aquifer, which produced about 2.5 feet of drawdown in response to pumping in the Claiborne aquifer. The vertical hydraulic conductivity of the confining unit between the Claiborne and Clayton aquifers was simulated to be about 0.02 foot per day.Results from the 72-hour aquifer tests run for this study indicated no interconnection between the Claiborne and overlying Upper Floridan aquifers at the two test sites. Additional data are needed to monitor the effects that increased withdrawals from the Claiborne aquifer may have on future water resources.

  4. Future groundwater extraction scenarios for an aquifer in a semiarid environment: case study of Guadalupe Valley Aquifer, Baja California, Northwest Mexico.

    Campos-Gaytan, Jose Ruben; Kretzschmar, Thomas; Herrera-Oliva, Claudia Soledad


    Semiarid northwestern Mexico presents a growing water demand produced by agricultural and domestic requirements during the last two decades. The community of Guadalupe Valley and the city of Ensenada rely on groundwater pumping from the local aquifer as its sole source of water supply. This dependency has resulted in an imbalance between groundwater pumpage and natural recharge. A two-dimensional groundwater flow model was applied to the Guadalupe Valley Aquifer, which was calibrated and validated for the period 1984-2005. The model analysis verified that groundwater levels in the region are subject to steep declines due to decades of intensive groundwater exploitation for agricultural and domestic purposes. The calibrated model was used to assess the effects of different water management scenarios for the period 2007-2025. If the base case (status quo) scenario continues, groundwater levels are in a continuous drawdown trend. Some wells would run dry by August 2017, and water demand may not be met without incurring in an overdraft. The optimistic scenario implies the achievement of the mean groundwater recharge and discharge. Groundwater level depletion could be stopped and restored. The sustainable scenario implies the reduction of current extraction (up to about 50 %), when groundwater level depletion could be stopped. A reduction in current extraction mitigates water stress in the aquifer but cannot solely reverse declining water tables across the region. The combination of reduced current extraction and an implemented alternative solution (such as groundwater artificial recharge), provides the most effective measure to stabilize and reverse declining groundwater levels while meeting water demands in the region.

  5. Biogeographic patterns of desert springs in the Great Basin with an emphasis on regional aquifer thermal springs as refugia for vulnerable crenobiotic species

    Forrest, M.; Sada, D. W.; Norris, R. D.


    The desert springs of the Great Basin Region in western North America provide ideal systems to study biogeographic and evolutionary patterns. In arid regions, springs are biodiversity hotspots because they often provide the sole source of water for the biota within and around them. In the Great Basin, springs provide critical habitat for diverse and extensive crenobiotic flora and fauna comprising over 125 endemic species. These aquatic environments represent island ecosystems surrounded by seas of desert, and researchers have compiled large databases of their biota and chemistry. Consequently, desert springs are excellent systems for biogeographic studies and multivariate statistical analyses of relationships between the chemical and physical characteristics of the springs and the biological communities that they support. The purpose of this study is to elucidate the relationships between the physicochemical characteristics of springs and their biota using multivariate statistical analyses to characterize 1325 springs, including regional aquifer springs, local aquifer cold springs and geothermal springs. The analyses reveal that regional aquifer thermal springs harbor disproportionate numbers of crenobiotic species including endemic gastropods, fishes, and aquatic insects. However, these regional aquifer springs also contain significantly more introduced species than cold and geothermal local aquifer springs. Springs are threatened by anthropogenic impacts including groundwater depletion and pollution, alteration of flow regimes, and the introduction of exotic species. In this study, one of the major factors that distinguished regional aquifer thermal springs from cold and geothermal local aquifer springs was the higher number of introduced species found in regional aquifer springs. This may be due to the influences of the same physicochemical characteristics that allow regional aquifer springs to serve as refugia for endemic species--species that are able to gain

  6. Lichen nitidus of palms and soles

    Gandhi Vijay


    Full Text Available Lichen nitidus occurs uncommonly on the palms and soles and has an unusual morphology at these sites. Two patients who presented with lesions on the palms and soles are reported. The first patient had rough papules with prominent keratotic plugs. In the second patient, the lesion was an irregular plaque with peripheral papules showing keratotic plugs. Both patients had typical lesions elsewhere on the body. Histopathology confirmed the diagnosis. Awareness of this variant will help in prompt recognition of the condition.


    IONESCU Cozmin


    Full Text Available One solution for attaching soles on footwear is to inject them directly into the upper part using moulds with unique cavities. Injection moulds are manufactured for each sole design, for each foot, right and left, and for each size number. As a result of the market demand for a large number of soles designs, the execution costs of moulds for each of them are substantial. In the case of small manufacturers, injection moulds wear out morally long before they wear out physically. This paper will present some design solutions for moulds that have reusable parts that can be used from one sole design to another, without changing the entire mould. Using these moulds, soles design can be modified by interchanging some modules which are fitted into the main mould cavities. These solutions represent a cheaper and faster alternative for classic moulds, with unique single cavities.

  8. Mineralogical sources of groundwater fluoride in Archaen bedrock/regolith aquifers: Mass balances from southern India and north-central Sri Lanka

    B.M. Hallett


    New hydrological insights for the region: An estimate of weathering duration for the in situ regolith in Andhra Pradesh, 250–380 Ka, is close to a previous estimate for southern India. Partial or total destruction of the primary F-bearing bedrock minerals and consistent depletion of F in the remnant minerals result in a much reduced total F content in the regolith. Leaching experiments and field relationships, however, indicate a greater potential for F mobilisation to groundwater from the regolith than the bedrock. Schemes for managed aquifer recharge should beware the risk of mobilising additional F to groundwater.

  9. Hydrogeology of Two Areas of the Tug Hill Glacial-Drift Aquifer, Oswego County, New York

    Miller, Todd S.; Bugliosi, Edward F.; Hetcher-Aguila, Kari K.; Eckhardt, David A.


    Two water-production systems, one for the Village of Pulaski and the other for the Villages of Sandy Creek and Lacona in Oswego County, New York, withdraw water from the Tug Hill glacial-drift aquifer, a regional sand and gravel aquifer along the western flank of the Tug Hill Plateau, and provide the sole source of water for these villages. As a result of concerns about contamination of the aquifer, two studies were conducted during 2001 to 2004, one for each water-production system, to refine the understanding of ground-water flow surrounding these water-production systems. Also, these studies were conducted to determine the cause of the discrepancy between ground-water ages estimated from previously constructed numerical ground-water-flow models for the Pulaski and Sandy Creek/Lacona well fields and the apparent ground-water ages determined using concentrations of tritium and chlorofluorocarbons. The Village of Pulaski withdrew 650,000 gallons per day in 2000 from four shallow, large-diameter, dug wells finished in glaciolacustrine deposits consisting of sand with some gravelly lenses 3 miles east of the village. Four 2-inch diameter test wells were installed upgradient from each production well, hydraulic heads were measured, and water samples collected and analyzed for physical properties, inorganic constituents, nutrients, bacteria, tritium, dissolved gases, and chlorofluorocarbons. Recharge to the Tug Hill glacial-drift aquifer is from precipitation directly over the aquifer and from upland sources in the eastern part of the recharge area, including (1) unchannelized runoff from till and bedrock hills east of the aquifer, (2) seepage to the aquifer from streams that drain the Tug Hill Plateau, (3) ground-water inflow from the till and bedrock on the adjoining Tug Hill Plateau. Water-quality data collected from four piezometers near the production wells in November 2003 indicated that the water is a calcium-bicarbonate type with iron concentrations that

  10. Debunking Technical Competency as the Sole Source of Innovation


    electric light permitted work past sunset and hence increased productivity and output. The automobile and aircraft opened opportunities for Americans...opened their own bicycle business, but Wilbur’s interest in aeronautics started after reading about a famous German glider pilot. Wilbur’s Thomas...inventors attempted to develop such a machine; however, on December 17, 1903, an unlikely high school dropout with a printing press and bicycle repair

  11. A Black Hills-Madison Aquifer origin for Dakota Aquifer groundwater in northeastern Nebraska.

    Stotler, Randy; Harvey, F Edwin; Gosselin, David C


    Previous studies of the Dakota Aquifer in South Dakota attributed elevated groundwater sulfate concentrations to Madison Aquifer recharge in the Black Hills with subsequent chemical evolution prior to upward migration into the Dakota Aquifer. This study examines the plausibility of a Madison Aquifer origin for groundwater in northeastern Nebraska. Dakota Aquifer water samples were collected for major ion chemistry and isotopic analysis ((18)O, (2)H, (3)H, (14)C, (13)C, (34)S, (18)O-SO(4), (87)Sr, (37)Cl). Results show that groundwater beneath the eastern, unconfined portion of the study area is distinctly different from groundwater sampled beneath the western, confined portion. In the east, groundwater is calcium-bicarbonate type, with delta(18)O values (-9.6 per thousand to -12.4 per thousand) similar to local, modern precipitation (-7.4 per thousand to -10 per thousand), and tritium values reflecting modern recharge. In the west, groundwater is calcium-sulfate type, having depleted delta(18)O values (-16 per thousand to -18 per thousand) relative to local, modern precipitation, and (14)C ages 32,000 to more than 47,000 years before present. Sulfate, delta(18)O, delta(2)H, delta(34)S, and delta(18)O-SO(4) concentrations are similar to those found in Madison Aquifer groundwater in South Dakota. Thus, it is proposed that Madison Aquifer source water is also present within the Dakota Aquifer beneath northeastern Nebraska. A simple Darcy equation estimate of groundwater velocities and travel times using reported physical parameters from the Madison and Dakota Aquifers suggests such a migration is plausible. However, discrepancies between (14)C and Darcy age estimates indicate that (14)C ages may not accurately reflect aquifer residence time, due to mixtures of varying aged water.

  12. Groundwater Mounding in Non-uniform Aquifers with Implications for Managed Aquifer Recharge

    Zlotnik, V. A.; Noel, P.; Kacimov, A. R.; Al Maktoumi, A. K.


    Many areas of the world (e.g. the Middle East and North Africa countries) are deficient in observation networks and hydrogeological data needed for Managed Aquifer Recharge (MAR) design. Therefore, diagnostic analytical approaches are appropriate for feasibility studies of MAR. It was found that the common assumption of aquifer thickness uniformity often does not hold, especially in mountainous watersheds. However, the only practical result available for non-uniform aquifers was developed for well hydraulics applications (point sinks or sources) by Hantush (1962), while the recharge zones may cover large areas on the scale of kilometers, such as temporarily filled impoundments (natural and engineered reservoirs in wadis, depressions, trenches, etc.) or perennial streams accepting massive treated wastewater discharge. To address these important, but overlooked MAR problems in sloping aquifers, a set of new closed-form analytical solutions for water table elevations were obtained. Interestingly, the 2D groundwater flow equation acquires the advection-dispersion equation form in these cases. The quadratures in closed-form solutions obtained by the Green's function method converge rapidly. These models account for both shapes and orientations of sources with respect to the direction of the aquifer base gradient. Qualitatively, solutions in sloping aquifers have an important trait: the mounding is limited in time and space, unlike in aquifers with a horizontal base. Aquifers with the greater slopes have the lesser potential of waterlogging from the rising water table and different storage characteristics (height and volume of locally stored water). Computational aspects of these solutions for MAR analyses are illustrated by example utilizing regional aquifer properties near Az Zarqa River, Jordan. (This study was supported by a grant from USAID-FABRI, project contract: AID-OAA-TO-11-00049, Subcontract: 1001624 -12S-19745).

  13. Hydrogeology of the Cambrian-Ordovician aquifer system in the northern Midwest: B in Regional aquifer-system analysis

    Young, H.L.; Siegel, D.I.


    The Cambrian-Ordovician aquifer system contains the most extensive and continuous aquifers in the northern Midwest of the United States. It is the source of water for many municipalities, industries, and rural water users. Since the beginning of ground-water development from the aquifer system in the late 1800's, hydraulic heads have declined hundreds of feet in the heavily pumped Chicago-Milwaukee area and somewhat less in other metropolitan areas. The U.S. Geological Survey has completed a regional assessment of this aquifer system within a 161,000-square-mile area encompassing northern Illinois, northwestern Indiana, Iowa, southeastern Minnesota, northern Missouri, and Wisconsin.

  14. Influence of a compost layer on the attenuation of 28 selected organic micropollutants under realistic soil aquifer treatment conditions: insights from a large scale column experiment.

    Schaffer, Mario; Kröger, Kerrin Franziska; Nödler, Karsten; Ayora, Carlos; Carrera, Jesús; Hernández, Marta; Licha, Tobias


    Soil aquifer treatment is widely applied to improve the quality of treated wastewater in its reuse as alternative source of water. To gain a deeper understanding of the fate of thereby introduced organic micropollutants, the attenuation of 28 compounds was investigated in column experiments using two large scale column systems in duplicate. The influence of increasing proportions of solid organic matter (0.04% vs. 0.17%) and decreasing redox potentials (denitrification vs. iron reduction) was studied by introducing a layer of compost. Secondary effluent from a wastewater treatment plant was used as water matrix for simulating soil aquifer treatment. For neutral and anionic compounds, sorption generally increases with the compound hydrophobicity and the solid organic matter in the column system. Organic cations showed the highest attenuation. Among them, breakthroughs were only registered for the cationic beta-blockers atenolol and metoprolol. An enhanced degradation in the columns with organic infiltration layer was observed for the majority of the compounds, suggesting an improved degradation for higher levels of biodegradable dissolved organic carbon. Solely the degradation of sulfamethoxazole could clearly be attributed to redox effects (when reaching iron reducing conditions). The study provides valuable insights into the attenuation potential for a wide spectrum of organic micropollutants under realistic soil aquifer treatment conditions. Furthermore, the introduction of the compost layer generally showed positive effects on the removal of compounds preferentially degraded under reducing conditions and also increases the residence times in the soil aquifer treatment system via sorption. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Compilation of geologic, hydrologic, and ground-water flow modeling information for the Spokane Valley-Rathdrum Prairie aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

    Kahle, Sue C.; Caldwell, Rodney R.; Bartolino, James R.


    The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington Department of Ecology compiled and described geologic, hydrologic, and ground-water flow modeling information about the Spokane Valley-Rathdrum Prairie (SVRP) aquifer in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, ground- and surface-water interactions, computer flow models, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho and the Spokane valley and Hillyard Trough, Washington, was designated a Sole Source Aquifer by the U.S. Environmental Protection Agency in 1978. Continued growth, water management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer is composed of sand, gravel, cobbles, and boulders primarily deposited by a series of catastrophic glacial outburst floods from ancient Glacial Lake Missoula. The material deposited in this high-energy environment is coarser-grained than is typical for most basin-fill deposits, resulting in an unusually productive aquifer with well yields as high as 40,000 gallons per minute. In most places, the aquifer is bounded laterally by bedrock composed of granite, metasedimentary rocks, or basalt. The lower boundary of the aquifer is largely unknown except along the margins or in shallower parts of the aquifer where wells have penetrated its entire thickness and reached bedrock or silt and clay deposits. Based on surface geophysics, the thickness of the aquifer is about 500 ft near the Washington-Idaho state line, but more than 600 feet within the Rathdrum Prairie and more than 700 feet in the Hillyard trough based on drilling records. Depth to water in the aquifer is greatest in the northern

  16. Groundwater vulnerability mapping of Qatar aquifers

    Baalousha, Husam Musa


    Qatar is one of the most arid countries in the world with limited water resources. With little rainfall and no surface water, groundwater is the only natural source of fresh water in the country. Whilst the country relies mainly on desalination of seawater to secure water supply, groundwater has extensively been used for irrigation over the last three decades, which caused adverse environmental impact. Vulnerability assessment is a widely used tool for groundwater protection and land-use management. Aquifers in Qatar are carbonate with lots of fractures, depressions and cavities. Karst aquifers are generally more vulnerable to contamination than other aquifers as any anthropogenic-sourced contaminant, especially above a highly fractured zone, can infiltrate quickly into the aquifer and spread over a wide area. The vulnerability assessment method presented in this study is based on two approaches: DRASTIC and EPIK, within the framework of Geographical Information System (GIS). Results of this study show that DRASTIC vulnerability method suits Qatar hydrogeological settings more than EPIK. The produced vulnerability map using DRASTIC shows coastal and karst areas have the highest vulnerability class. The southern part of the country is located in the low vulnerability class due to occurrence of shale formation within aquifer media, which averts downward movement of contaminants.

  17. Potentiometric surfaces and water-level trends in the Cockfield (upper Claiborne) aquifer in southern Arkansas and the Wilcox (lower Wilcox) aquifer of northeastern and southern Arkansas, 2012

    Rodgers, Kirk D.


    The Cockfield aquifer, located in southern Arkansas, is composed of Eocene-age sand beds found near the base of the Cockfield Formation of Claiborne Group. The Wilcox aquifer, located in northeastern and southern Arkansas, is composed of Paleocene-age sand beds found in the middle to lower part of the Wilcox Group. The Cockfield and Wilcox aquifers are primary sources of groundwater. In 2010, withdrawals from the Cockfield aquifer in Arkansas totaled 19.2 million gallons per day (Mgal/d), and withdrawals from the Wilcox aquifer totaled 36.5 Mgal/d.

  18. Isotopes in the Hueco Bolson aquifer, Texas (USA) and Chihuahua (Mexico): local and general implications for recharge sources in alluvial basins

    Eastoe, Christopher J.; Hibbs, Barry J.; Olivas, Alfredo Granados; Hogan, James F.; Hawley, John; Hutchison, William R.


    Stable isotope data for the Hueco Bolson aquifer (Texas, USA and Chihuahua, Mexico) distinguish four water types. Two types relate to recharge from the Rio Grande: pre-dam (pre-1916) river water with oxygen-18 and deuterium (δ18O, δD, ‰) from (-11.9, -90) to (-10.1, -82), contrasts with present-day river water (-8.5, -74) to (-5.3, -56). Pre-dam water is found beneath the Rio Grande floodplain and Ciudad Juárez, and is mixed with post-dam river water beneath the floodplain. Two other types relate to recharge of local precipitation; evidence of temporal change of precipitation isotopes is present in both types. Recharge from the Franklin and Organ Mountains plots between (-10.9, -76) and (-8.5, -60) on the global meteoric water line (GMWL), and is found along the western side of the Hueco Bolson, north of the Rio Grande. Recharge from the Diablo Plateau plots on an evaporation trend originating on the GMWL near (-8.5, -58). This water is found in the southeastern Hueco Bolson, north of the river; evaporation may be related to slow recharge through fine-grained sediment. Pre-dam water, recognizable by isotope composition, provides information on groundwater residence times in this and other dammed river basins.

  19. Hydrogeologic Framework and Ground-Water Budget of the Spokane Valley-Rathdrum Prairie Aquifer, Spokane County, Washington, and Bonner and Kootenai Counties, Idaho

    Kahle, Sue C.; Bartolino, James R.


    The U.S. Geological Survey, in cooperation with the Idaho Department of Water Resources and Washington State Department of Ecology, investigated the hydrogeologic framework and ground-water budget of the Spokane Valley-Rathdrum Prairie (SVRP) aquifer located in northern Idaho and northeastern Washington. Descriptions of the hydrogeologic framework, water-budget components, and further data needs are provided. The SVRP aquifer, which covers about 370 square miles including the Rathdrum Prairie, Idaho, and the Spokane Valley and Hillyard Trough, Washington, is the sole source of drinking water for more than 500,000 residents. Continued growth, water-management issues, and potential effects on water availability and water quality in the aquifer and in the Spokane and Little Spokane Rivers have illustrated the need to better understand and manage the region's water resources. The SVRP aquifer consists mostly of gravels, cobbles, and boulders - deposited during a series of outburst floods resulting from repeated collapse of the ice dam that impounded ancient Glacial Lake Missoula. In most places, the SVRP aquifer is bounded by bedrock of pre-Tertiary granite or metasedimentary rocks, or Miocene basalt and associated sedimentary deposits. Discontinuous fine-grained layers are scattered throughout the SVRP aquifer at considerably different altitudes and with considerably different thicknesses. In the Hillyard Trough and the Little Spokane River Arm of the aquifer, a massive fine-grained layer with a top altitude ranging from about 1,500 to 1,700 feet and thickness ranging from about 100 to 200 feet separates the aquifer into upper and lower units. Most of the Spokane Valley part of the aquifer is devoid of fine-grained layers except near the margins of the valley and near the mouths of lakes. In the Rathdrum Prairie, multiple fine-grained layers are scattered throughout the aquifer with top altitudes ranging from about 1,700 to 2,400 feet with thicknesses ranging from 1

  20. Lower Cretaceous aquifers

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Lower Cretaceous aquifers in the states of Montana, Wyoming, South Dakota, Kansas, Nebraska, Iowa, and Minnesota..

  1. Hydrogeology and water quality of the Floridan aquifer system and effect of Lower Floridan aquifer withdrawals on the Upper Floridan aquifer at Barbour Pointe Community, Chatham County, Georgia, 2013

    Gonthier, Gerard J.; Clarke, John S.


    Two test wells were completed at the Barbour Pointe community in western Chatham County, near Savannah, Georgia, in 2013 to investigate the potential of using the Lower Floridan aquifer as a source of municipal water supply. One well was completed in the Lower Floridan aquifer at a depth of 1,080 feet (ft) below land surface; the other well was completed in the Upper Floridan aquifer at a depth of 440 ft below land surface. At the Barbour Pointe test site, the U.S. Geological Survey completed electromagnetic (EM) flowmeter surveys, collected and analyzed water samples from discrete depths, and completed a 72-hour aquifer test of the Floridan aquifer system withdrawing from the Lower Floridan aquifer.Based on drill cuttings, geophysical logs, and borehole EM flowmeter surveys collected at the Barbour Pointe test site, the Upper Floridan aquifer extends 369 to 567 ft below land surface, the middle semiconfining unit, separating the two aquifers, extends 567 to 714 ft below land surface, and the Lower Floridan aquifer extends 714 to 1,056 ft below land surface.A borehole EM flowmeter survey indicates that the Upper Floridan and Lower Floridan aquifers each contain four water-bearing zones. The EM flowmeter logs of the test hole open to the entire Floridan aquifer system indicated that the Upper Floridan aquifer contributed 91 percent of the total flow rate of 1,000 gallons per minute; the Lower Floridan aquifer contributed about 8 percent. Based on the transmissivity of the middle semiconfining unit and the Floridan aquifer system, the middle semiconfining unit probably contributed on the order of 1 percent of the total flow.Hydraulic properties of the Upper Floridan and Lower Floridan aquifers were estimated based on results of the EM flowmeter survey and a 72-hour aquifer test completed in Lower Floridan aquifer well 36Q398. The EM flowmeter data were analyzed using an AnalyzeHOLE-generated model to simulate upward borehole flow and determine the transmissivity of

  2. Hydrogeochemical Analysis of an Overexploited Aquifer In Bangladesh Toward Managed Aquifer Recharge Project Implementation

    Rahman, M. A.; Wiegand, B. A.; Pervin, M.; Sauter, M.


    In most parts of the upper Dupitila aquifer (Dhaka City, Bangladesh) the average groundwater depletion reaches 2-3 m/year due to increasing water demands of the growing population. To counteract overexploitation of the aquifer, a more sustainable water management is required. The analysis of the local water resources system suggests that Managed Aquifer Recharge (MAR) would help to restore groundwater resources to strengthen water supply of Dhaka City, e.g., by using collected urban monsoon runoff and excess surface water from rivers. To assess possible effects of surface water or rainwater injection on groundwater quality, a comprehensive hydrogeochemical survey of the Dupitila aquifer is required. This paper presents hydrogeochemical data to document the current status of groundwater quality and to evaluate potential groundwater pollution by mobilization of hazardous chemicals as a result of changes in the hydrochemical equilibria. We performed a comprehensive review of available secondary data sources and will present new results from hydrochemical and Sr isotope investigations of water samples that were conducted within this study. Currently, groundwater quality in the upper Dupitila aquifer is characterized by variations in the electrical conductivity in the range of 200 to 1100 μS/cm, which may indicate some anthropogenic contamination by leakage from waste disposal including the sewage network and from surface water infiltration into the groundwater aquifer. Dissolved oxygen concentrations range from 1.0 to 4.9 mg/L (average 2.5 mg/L) in the upper Dupitila aquifer, while the lower Dupilita aquifer shows dissolved oxygen concentrations in the range 0 to 0.7 mg/L. Concentrations of major ions show some variation primarily due to a sedimentologically/mineralogically heterogeneous aquifer composition (sand, gravel, clay horizons), but may also be affected by anthropogenic processes. The groundwater composition is predominated by Ca-Mg-HCO3 and saturation values

  3. Why Observable Space Is Solely Three Dimensional

    Rabinowitz, Mario


    Quantum (and classical) binding energy considerations in n-dimensional space indicate that atoms (and planets) can only exist in three-dimensional space. This is why observable space is solely 3-dimensional. Both a novel Virial theorem analysis, and detailed classical and quantum energy calculations for 3-space circular and elliptical orbits indicate that they have no orbital binding energy in greater than 3-space. The same energy equation also excludes the possibility of atom-like bodies in strictly 1 and 2-dimensions. A prediction is made that in the search for deviations from r^-2 of the gravitational force at sub-millimeter distances such a deviation must occur at < ~ 10^-10 m (or < ~10^-12 m considering muoniom), since atoms would disintegrate if the curled up dimensions of string theory were larger than this. Callender asserts that the often-repeated claim in previous work that stable orbits are possible in only three dimensions is not even remotely established. The binding energy analysis herein ...

  4. Integrated geophysical application to investigate groundwater potentiality of the shallow Nubian aquifer at northern Kharga, West

    Younis, Abdellatif; Soliman, Mamdouh; Moussa, Salah; Massoud, Usama; ElNabi, Sami Abd; Attia, Magdy


    Continuous evaluation of groundwater aquifers in the basin of Kharga Oasis is very important. Groundwater in Kharga Oasis represents the major factor for the development plans of this area as it is the sole source for water supplies required for drinking and irrigation purposes. This study is concerned by analyzing the groundwater potentiality of the shallow aquifer at the northern part of Kharga basin by integrated application of Vertical Electrical Sounding (VES) and Time domain Electromagnetic (TEM) techniques. The VES data were measured at 28 points arranged along a north-south trending line by applying Schlumberger array with a maximum current-electrode spacing (AB) of 1000 m. The TEM data were measured at 167 points arranged along 11 east-west trending lines by using a single square loop with 50 m loop-side length. The VES and TEM data have been individually inverted, where the VES models were used as initial models for TEM data inversion. The final models were used for construction of 17 geoelectrical sections and 5 contour maps describing subsurface water-bearing layers at the investigated area. Correlation of the obtained models with geologic, hydrogeologic and borehole information indicates that the shallow aquifer comprises two zones (A-up) and (B-down) separated by a highly conductive shale layer. The upper zone (A) is composed of fine to medium sand with thin clay intercalations. It exhibits low to moderate resistivities. This zone was detected at depth values ranging from 10 to 70 m below ground surface (bgs) and shows a thickness of 25-90 m. The lower zone (B) exhibits moderate to high resistivity values with expected good water quality. The upper surface of zone B was detected at 60-165 m depth.

  5. 饲料中添加不同脂肪源对半滑舌鳎亲鱼繁殖性能和仔鱼质量的影响%Effect of different lipid source in diet on the reproductive performance and larval quality of tongue sole Cynoglossus semilaevis

    吕庆凯; 梁萌青; 郑珂珂; 王新星


    Three experimental diets with fish oil, soybean oil and olive oil as different lipid source and a commercial diet as control were used to feed broodstock of tongue sole Cynoglossus semilaevis for 8 weeks to investigate the effects of different fat source on spawning performance, fatty acids composition in eggs and quality of larvae. Results showed that in terms of the relative fecundity, the control was the highest, followed by olive oil treatment, fish oil treatment, and soybean oil treatment as the lowest. The abnormal egg ratio of control was the lowest follwed by, fish oil treatment, olive oil treatment, and soybean oil treatment as the highest (9. 77%, 14. 53%, 19. 4% and 17. 35% respectively)(P<0. 05). Abnormal larva ratio among treatments was significantly different (P<0. 05) (3. 34% , 3. 12% , 8. 85% and 17. 35% respectively). Hatching rate of control was the highest, followed by fish oil treatment, olive oil treatment, and soybean oil treatment as the lowest (P<0. 05) (95.49%, 84.88%, 79.57% and 74. 27% respectively). It indicated that during spawning period, a certain amount of n-3 HUFA in diet, especially docosahexenoic acid (DHA) needs to maintain egg development and larval growth. Oleic acid and linoleic acid (LA) were selectively retained and played an important roles in tongue sole egg development process. We conclude that soybean oil or olive oil or fish oil as a single lipid source of diets can not provide sufficient fatty acids for tongue sole C. sem-ilaevis.%以精制鱼油、大豆油、橄榄油为脂肪源配制3组实验饲料,以一种商业饲料为对照组,进行连续56 d饲喂半滑舌鳎亲鱼试验,研究不同脂肪源对半滑舌鳎亲鱼繁殖性能、卵子脂肪酸组成和仔鱼质量的影响.结果显示,对照组亲鱼的相对产卵量最高,橄榄油组次之,鱼油组比橄榄油组低,豆油组最低.对照组的卵子畸形率最低为9.77%,鱼油组为14.53%,橄榄油组为19.4%,豆油组最高为35.17%(P<0

  6. Origin and structures of groundwater humic substances from three Danish aquifers

    Grøn, C.; Wassenaar, L.; Krog, M.


    Structural, chemical, and isotopic parameters were used to identify the origins of groundwater humic substances from three Danish aquifers. A variety of analytical techniques (visible light absorption, molecular weight distribution, C-13-NMR spectroscopy, elemental composition with major elements...... and halogens, hydrolyzable amino acids and carbohydrates, carbon isotopes) applied to aquatic humic and fulvic acids led to consistent structural interpretations for each of the three aquifers studied. For humic substances in two-aquifers, the analyses suggested source rocks in agreement with geological...... and hydrogeochemical information. In a third aquifer, source rock identification was inconclusive, and multiple fossil and recent organic carbon sources are suggested....

  7. Characterisation of a DNAPL source zone in a porous aquifer using the Partitioning Interwell Tracer Test and an inverse modelling approach.

    Dridi, Lotfi; Pollet, Ingrid; Razakarisoa, Olivier; Schäfer, Gerhard


    In this paper, we discuss the results of a Partitioning Interwell Tracer Test (PITT) performed in a large scale experiment with a well-defined TCE spill, and present a novel combined analytical-numerical inverse modelling approach using measured concentration profiles within a TCE plume to predict the distribution of the DNAPL in a virtual vertical plane of the source. The proposed inverse modelling approach assumes local thermodynamic equilibrium of the distribution of TCE between the NAPL phase and the aqueous phase and no decay or sorption of the dissolved TCE concentrations downstream of the spill area. The analytical part of the inverse modelling approach contains two steps. As a first step, the location of the contaminant in a virtual vertical plane of a porous medium is fixed by using measured concentration profiles and considering the dissolution of the organic phase under equilibrium conditions. In the second step, the volume of contaminant entrapped in the source cells is estimated. A multiphase advective-dispersive transport model is used in the final step to adjust the volumes quantified in the second step. The predictions are highly dependent on the quantity and quality of the data in space and time. From the PITT-breakthrough curves measured at the pumping well, a mean TCE saturation in the sweep zone of 0.0004 was derived, which is very low compared to that determined at the local scale. In a second analysis, tracer breakthrough curves available at measuring points placed closely downstream and upstream of the presumed source zone, were used to explain why the globally obtained DNAPL saturation was very low compared to the "real", locally evaluated TCE saturations in the source zone. This was principally caused by the overall travel time compared to the short travel time of the tracers in the source zone. Another reason is that due to bypassing, only part of the volume of tracer injected had been in contact and had eventually interacted with the

  8. Reconnaissance of the hydrology, water quality, and sources of bacterial and nutrient contamination in the Ozark Plateaus aquifer system and Cave Springs Branch of Honey Creek, Delaware County, Oklahoma, March 1999-March 2000

    Schlottmann, Jamie L.; Tanner, Ralph S.; Samadpour, Mansour


    A reconnaissance investigation of hydrology and water quality was conducted to evaluate possible sources of bacteria and nutrient contamination in the Cave Springs Branch basin and the underlying karstic Ozark Plateau aquifer system. Objectives were to: (1) determine the directions of ground-water flow in the basin and determine whether Cave Springs Branch interacts with ground water, (2) compare water quality in Cave Springs Branch with water quality in nearby wells to determine whether the stream is contaminating nearby wells, and (3) determine sources of fecal coliform bacteria and nitrate contamination in Cave Springs Branch and ground water. Potential sources of bacteria and nitrate in the area include cultivated agriculture, cow and horse on pasture, poultry production, households, and wildlife. Presence of fecal coliform and fecal streptococcal bacteria directly indicate fecal contamination and the potential for the presence of other pathogenic organisms in a water supply. Nitrate in drinking water poses health risks and may indicate the presence of additional contaminants. Fecal coliform bacteria colony counts were least in wells, intermediate in the poultry-processing plant wastewater outfall and Honey Creek above the confluence with Cave Springs Branch, and greatest in Cave Springs Branch. Bacteria strains and resistance to antibiotics by some bacteria indicate that livestock may have been sources of some bacteria in the water samples. Multiple antibiotic resistances were not present in the isolates from the water samples, indicating that the bacteria may not be from human or poultry sources. Ribotyping indicates that Escherichia coli bacteria in water samples from the basin were from bird, cow, horse, dog, deer, and human sources. The presence of multiple ribotypes from each type of animal source except bird indicates that most of the bacteria are from multiple populations of source animals. Identifiable sources of bacteria in Cave Springs Branch at the

  9. FEWA: a Finite Element model of Water flow through Aquifers

    Yeh, G.T.; Huff, D.D.


    This report documents the implementation and demonstration of a Finite Element model of Water flow through Aquifers (FEWA). The particular features of FEWA are its versatility and flexibility to deal with as many real-world problems as possible. Point as well as distributed sources/sinks are included to represent recharges/pumpings and rainfall infiltrations. All sources/sinks can be transient or steady state. Prescribed hydraulic head on the Dirichlet boundaries and fluxes on Neumann or Cauchy boundaries can be time-dependent or constant. Source/sink strength over each element and node, hydraulic head at each Dirichlet boundary node, and flux at each boundary segment can vary independently of each other. Either completely confined or completely unconfined aquifers, or partially confined and partially unconfined aquifers can be dealt with effectively. Discretization of a compound region with very irregular curved boundaries is made easy by including both quadrilateral and triangular elements in the formulation. Large-field problems can be solved efficiently by including a pointwise iterative solution strategy as an optional alternative to the direct elimination solution method for the matrix equation approximating the partial differential equation of groundwater flow. FEWA also includes transient flow through confining leaky aquifers lying above and/or below the aquifer of interest. The model is verified against three simple cases to which analytical solutions are available. It is then demonstrated by two examples of how the model can be applied to heterogeneous and anisotropic aquifers with transient boundary conditions, time-dependent sources/sinks, and confining aquitards for a confined aquifer of variable thickness and for a free surface problem in an unconfined aquifer, respectively. 20 references, 25 figures, 8 tables.

  10. The effect of iron oxidation in the groundwater of the alluvial aquifer of the Velika Morava River, Serbia, on the clogging of water supply wells

    Majkić-Dursun Brankica


    Full Text Available The oxidation of dissolved iron(II in groundwater and precipitation on the screens and discharge pipes of water wells that tap shallow alluvial aquifers leads to the formation of well encrustations. Well clogging has a number of adverse impacts reflected in declining production capacity, increasing parasitic drawdown and growing maintenance costs of the water supply source. Chemical clogging rarely occurs as a stand-alone process in the groundwater of shallow alluvial aquifers; it is generally catalyzed by micro-organisms, the role of which is important to explain rapid blocking. This paper presents a calculation of the rate of homogeneous chemical oxidation of iron in wells that tap the alluvial aquifer of the Velika Morava River in Serbia, where there are pronounced iron hydroxide clogging issues. When the dynamic groundwater level drops to such an extent that the pumps need to be shut down, or when the well capacity is very low, the results show that there is enough time for iron encrustation to form. Iron oxidation does not occur solely inside the well; the process tends to extend into a much wider zone, beyond the well. [Projekat Ministartsva nauke Republike Srbije, br. TR37014

  11. Ground-water flow simulation and chemical and isotopic mixing equation analysis to determine source contributions to the Missouri River alluvial aquifer in the vicinity of the Independence, Missouri, well field

    Kelly, Brian P.


    The city of Independence, Missouri, operates a well field in the Missouri River alluvial aquifer. Steady-state ground-water flow simulation, particle tracking, and the use of chemical and isotopic composition of river water, ground water, and well-field pumpage in a two-component mixing equation were used to determine the source contributions of induced inflow from the Missouri River and recharge to ground water from precipitation in well-field pumpage. Steady-state flow-budget analysis for the simulation-defined zone of contribution to the Independence well field indicates that 86.7 percent of well-field pumpage is from induced inflow from the river, and 6.7 percent is from ground-water recharge from precipitation. The 6.6 percent of flow from outside the simulation-defined zone of contribution is a measure of the uncertainty of the estimation, and occurs because model cells are too large to uniquely define the actual zone of contribution. Flow-budget calculations indicate that the largest source of water to most wells is the Missouri River. Particle-tracking techniques indicate that the Missouri River supplies 82.3 percent of the water to the Independence well field, ground-water recharge from precipitation supplies 9.7 percent, and flow from outside defined zones of contribution supplies 8.0 percent. Particle tracking was used to determine the relative amounts of source water to total well-field pumpage as a function of traveltime from the source. Well-field pumpage that traveled 1 year or less from the source was 8.8 percent, with 0.6 percent from the Missouri River, none from precipitation, and 8.2 percent between starting cells. Well-field pumpage that traveled 2 years or less from the source was 10.3 percent, with 1.8 percent from the Missouri River, 0.2 percent from precipitation, and 8.3 percent between starting cells. Well-field pumpage that traveled 5 years or less from the source was 36.5 percent, with 27.1 percent from the Missouri River, 1.1 percent

  12. On the aquitard-aquifer interface flow and the drawdown sensitivity with a partially penetrating pumping well in an anisotropic leaky confined aquifer

    Feng, Qinggao; Zhan, Hongbin


    A mathematical model for describing groundwater flow to a partially penetrating pumping well of a finite diameter in an anisotropic leaky confined aquifer is developed. The model accounts for the jointed effects of aquitard storage, aquifer anisotropy, and wellbore storage by treating the aquitard leakage as a boundary condition at the aquitard-aquifer interface rather than a volumetric source/sink term in the governing equation, which has never developed before. A new semi-analytical solution for the model is obtained by the Laplace transform in conjunction with separation of variables. Specific attention was paid on the flow across the aquitard-aquifer interface, which is of concern if aquitard and aquifer have different pore water chemistry. Moreover, Laplace-domain and steady-state solutions are obtained to calculate the rate and volume of (total) leakage through the aquitard-aquifer interface due to pump in a partially penetrating well, which is also useful for engineers to manager water resources. The sensitivity analyses for the drawdown illustrate that the drawdown is most sensitive to the well partial penetration. It is apparently sensitive to the aquifer anisotropic ratio over the entire time of pumping. It is moderately sensitive to the aquitard/aquifer specific storage ratio at the intermediate times only. It is moderately sensitive to the aquitard/aquifer vertical hydraulic conductivity ratio and the aquitard/aquifer thickness ratio with the identical influence at late times.

  13. Relations of nonpoint-source nitrate and atrazine concentrations in the High Plains aquifer to selected explanatory variables in six Nebraska study areas

    Druliner, A.D.; Chen, H.H.; McGrath, T.S.


    Statistical techniques were used to relate nonpoint-source ground-water contamination by nitrate and atrazine to a variety of explanatory variables for six study areas in Nebraska. Water samples were collected from 268 wells in 12 counties from 1984 through 1987 and were analyzed for nitrate concentrations; water samples from 210 of the wells were analyzed for atrazine. A number of hydrochemical, climatic, hydrologic, soil, and land-use explanatory variables, which were believed to affect the contamination of ground water by agricultural chemicals, were identified and quantified for each of the 268 wells. Multiple regression methods were used to determine which explanatory variables were statistically related to ground-water concentrations of nitrate and atrazine. Regression models predicting nitrate and atrazine concentrations were produced that explained from about 50 to 68 percent of the variation in the dependent variables. Geographic- information-system methods were used to produce maps predicting nitrate and atrazine concentrations in ground water for one study area using selected regression and logistic models. The results of this study indicate that multiple regression techniques coupled with geographic information systems can be an effective means of identifying areas of potential ground-water contamination by nitrate and atrazine.

  14. 40 CFR 1042.620 - Engines used solely for competition.


    ... CFR 1068.101(b)(4). (f) You must permanently label engines exempted under this section to clearly... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Engines used solely for competition... Special Compliance Provisions § 1042.620 Engines used solely for competition. The provisions of...

  15. Nine decades of North Sea sole and plaice distribution

    Engelhard, G.H.; Pinnegar, J.K.; Kell, L.T.; Rijnsdorp, A.D.


    Recent studies based mainly on research survey data suggest that within the North Sea, sole Solea solea and plaice Pleuronectes platessa have exhibited distribution shifts in recent decades—on average southward for sole and northward to deeper waters for plaice. Various hypotheses may account for su

  16. Arsenic release during managed aquifer recharge (MAR)

    Pichler, T.; Lazareva, O.; Druschel, G.


    The mobilization and addition of geogenic trace metals to groundwater is typically caused by anthropogenic perturbations of the physicochemical conditions in the aquifer. This can add dangerously high levels of toxins to groundwater, thus compromising its use as a source of drinking water. In several regions world-wide, aquifer storage and recovery (ASR), a form of managed aquifer recharge (MAR), faces the problem of arsenic release due to the injection of oxygenated storage water. To better understand this process we coupled geochemical reactive transport modeling to bench-scale leaching experiments to investigate and verify the mobilization of geogenic arsenic (As) under a range of redox conditions from an arsenic-rich pyrite bearing limestone aquifer in Central Florida. Modeling and experimental observations showed similar results and confirmed the following: (1) native groundwater and aquifer matrix, including pyrite, were in chemical equilibrium, thus preventing the release of As due to pyrite dissolution under ambient conditions; (2) mixing of oxygen-rich surface water with oxygen-depleted native groundwater changed the redox conditions and promoted the dissolution of pyrite, and (3) the behavior of As along a flow path was controlled by a complex series of interconnected reactions. This included the oxidative dissolution of pyrite and simultaneous sorption of As onto neo-formed hydrous ferric oxides (HFO), followed by the reductive dissolution of HFO and secondary release of adsorbed As under reducing conditions. Arsenic contamination of drinking water in these systems is thus controlled by the re-equilibration of the system to more reducing conditions rather than a purely oxidative process.

  17. Groundwater level responses to precipitation variability in Mediterranean insular aquifers

    Lorenzo-Lacruz, Jorge; Garcia, Celso; Morán-Tejeda, Enrique


    Groundwater is one of the largest and most important sources of fresh water on many regions under Mediterranean climate conditions, which are exposed to large precipitation variability that includes frequent meteorological drought episodes, and present high evapotranspiration rates and water demand during the dry season. The dependence on groundwater increases in those areas with predominant permeable lithologies, contributing to aquifer recharge and the abundance of ephemeral streams. The increasing pressure of tourism on water resources in many Mediterranean coastal areas, and uncertainty related to future precipitation and water availability, make it urgent to understand the spatio-temporal response of groundwater bodies to precipitation variability, if sustainable use of the resource is to be achieved. We present an assessment of the response of aquifers to precipitation variability based on correlations between the Standardized Precipitation Index (SPI) at various time scales and the Standardized Groundwater Index (SGI) across a Mediterranean island. We detected three main responses of aquifers to accumulated precipitation anomalies: (i) at short time scales of the SPI (24 months). The differing responses were mainly explained by differences in lithology and the percentage of highly permeable rock strata in the aquifer recharge areas. We also identified differences in the months and seasons when aquifer storages are more dependent on precipitation; these were related to climate seasonality and the degree of aquifer exploitation or underground water extraction. The recharge of some aquifers, especially in mountainous areas, is related to precipitation variability within a limited spatial extent, whereas for aquifers located in the plains, precipitation variability influence much larger areas; the topography and geological structure of the island explain these differences. Results indicate large spatial variability in the response of aquifers to precipitation in

  18. Polluted aquifers: identification and characterisation by statistical analysis.

    Boemo, Analía; Musso, Haydée; Lomniczi, Irene


    Hierarchical clustering and principal component analysis applied to chemical components and physicochemical properties of well water proved to be a useful tool for identification and characterisation of aquifers. Underground water of Lerma Valley (Salta, Argentina) was examined for its physical and chemical properties by sampling 46 wells located in two adjacent areas separated by hills, one of them polluted with boron since 1991. Hierarchical clustering splits sampled sites into two main clusters, corresponding to the two areas, establishing the fact that the aquifers should be considered as two different entities in spite of their common recharge area. Values of boron concentration in the eastern area decreased in most of the wells since the pollution sources were eradicated, while four of them experienced a substantial increase, proof of the slow self-recovery of the aquifer. The use of principal component analysis provided evidence of the incipient boron pollution of the aquifer of the western area.

  19. Vertical electrical sounding to delineate the potential aquifer zones for drinking water in Niamey city, Niger, Africa

    Joy Choudhury; K Lohith Kumar; E Nagaiah; S Sonkamble; Shakeel Ahmed; Venay Kumar


    Niger is a landlocked African country and the only source of surface water is the Niger River which flows in the western part of Niger and only few villages near to the river gets benefited from it, leaving most of the areas dependent on groundwater solely. The groundwater resources in Niger are mainly used for drinking, livestock and domestic needs. It can be observed that the water exploitation is minimal there due to several factors like undeveloped areas, less population, limited wells, rain-fed irrigation, etc. The delineation of potential aquifer zones is an important aspect for groundwater prospecting. Hence, the direct current (DC) resistivity soundings method also known as vertical electrical sounding (VES) is one of the most applied geophysical techniques for groundwater prospecting that was used in the capital city, Niamey of Niger. Twelve VES surveys, each of AB spacing 400 m were carried out in lateritic and granitic rock formations with a view to study the layer response and to delineate the potential zones. Potential aquifer zones were at shallow depth ranging from 10 to 25 m for the drilled borehole depth of 80–85 m in every village. Analysis of the result showed a good correlation between the acquired data and the lithologs.

  20. Evaluation of permeability and non-Darcy flow in vuggy macroporous limestone aquifer samples with lattice Boltzmann methods

    Sukop, Michael C.; Huang, Haibo; Alvarez, Pedro F.; Variano, Evan A.; Cunningham, Kevin J.


    Lattice Boltzmann flow simulations provide a physics-based means of estimating intrinsic permeability from pore structure and accounting for inertial flow that leads to departures from Darcy's law. Simulations were used to compute intrinsic permeability where standard measurement methods may fail and to provide better understanding of departures from Darcy's law under field conditions. Simulations also investigated resolution issues. Computed tomography (CT) images were acquired at 0.8 mm interscan spacing for seven samples characterized by centimeter-scale biogenic vuggy macroporosity from the extremely transmissive sole-source carbonate karst Biscayne aquifer in southeastern Florida. Samples were as large as 0.3 m in length; 7–9 cm-scale-length subsamples were used for lattice Boltzmann computations. Macroporosity of the subsamples was as high as 81%. Matrix porosity was ignored in the simulations. Non-Darcy behavior led to a twofold reduction in apparent hydraulic conductivity as an applied hydraulic gradient increased to levels observed at regional scale within the Biscayne aquifer; larger reductions are expected under higher gradients near wells and canals. Thus, inertial flows and departures from Darcy's law may occur under field conditions. Changes in apparent hydraulic conductivity with changes in head gradient computed with the lattice Boltzmann model closely fit the Darcy-Forchheimer equation allowing estimation of the Forchheimer parameter. CT-scan resolution appeared adequate to capture intrinsic permeability; however, departures from Darcy behavior were less detectable as resolution coarsened.

  1. Vertical electrical sounding to delineate the potential aquifer zones for drinking water in Niamey city, Niger, Africa

    Choudhury, Joy; Kumar, K. Lohith; Nagaiah, E.; Sonkamble, S.; Ahmed, Shakeel; Kumar, Venay


    Niger is a landlocked African country and the only source of surface water is the Niger River which flows in the western part of Niger and only few villages near to the river gets benefited from it, leaving most of the areas dependent on groundwater solely. The groundwater resources in Niger are mainly used for drinking, livestock and domestic needs. It can be observed that the water exploitation is minimal there due to several factors like undeveloped areas, less population, limited wells, rain-fed irrigation, etc. The delineation of potential aquifer zones is an important aspect for groundwater prospecting. Hence, the direct current (DC) resistivity soundings method also known as vertical electrical sounding (VES) is one of the most applied geophysical techniques for groundwater prospecting that was used in the capital city, Niamey of Niger. Twelve VES surveys, each of AB spacing 400 m were carried out in lateritic and granitic rock formations with a view to study the layer response and to delineate the potential zones. Potential aquifer zones were at shallow depth ranging from 10 to 25 m for the drilled borehole depth of 80-85 m in every village. Analysis of the result showed a good correlation between the acquired data and the lithologs.

  2. Characterization of shallow unconsolidated aquifers in West Africa using different hydrogeological data sources as a contribution to the promotion of manual drilling and low cost techniques for groundwater exploration

    Fussi, Fabio; Fumagalli, Letizia; Bonomi, Tullia; Kane, Cheikh H.; Fava, Francesco; Di Mauro, Biagio; Hamidou, Barry; Niang, Magatte; Wade, Souleye; Colombo, Roberto


    Manual drilling refers to several drilling methods that rely on human energy to construct a borehole and complete a water supply (Danert, 2015). It can be an effective strategy to increase access to groundwater in low income countries , but manual drilling can be applied only where shallow geological layers are relatively soft and water table is not too deep. It is important therefore to identify those zones where shallow hydrogeological conditions are suitable, investigating the characteristics of shallow porous aquifers. Existing hydrogeological studies are generally focused in the characterization of deep fractures aquifers, more productive and able to ensure water supply for large settlements. Information concerning shallow porous aquifers are limited. This research has been carried out in two different study areas in West Africa (North-Western Senegal and Eastern Guinea). Aim of the research is the characterization of shallow aquifer using different methods and the identification of hydrogeological condition suitable for manual drilling implementation. Three different methods to estimate geometry and hydraulic properties of shallow unconsolidated aquifers have been used: The first method is based on the analysis of stratigraphic data obtained from borehole logs of the national water point database in both countries. The following steps have been implemented on the original information using the software TANGAFRIC, specifically designed for this study: a) identification of most frequent terms used for hydrogeological description in Senegal and Guinea database; b) definition of standard categories and manual codification of data; c) automatic extraction of average distribution of textural classes at different depth intervals in the unconsolidated aquifer; d) estimation of hydraulic parameters using conversion tables between texture and hydraulic conductivity available in the literature. . The second method is based on the interpretation of pump and recovery test

  3. The effects of urbanization on groundwater quantity and quality in the Zahedan aquifer, southeast Iran

    Khazaei, E.; Mackay, R.; Warner, J.W.


    This paper investigates the impacts of urban growth on groundwater quality and quantity in the Zahedan aquifer, which is the sole source of water supply for the city of Zahedan, Iran. The investigation is based on the collection of available historical data, supplemented by field and laboratory investigations. Groundwater levels in 40 wells were measured in December 2000. In addition, 102 water samples were taken in two periods during November and December 2000. Of these, 43 samples were analyzed for major ions, 32 samples were analyzed for nitrogen and phosphorus and the remainder for bacteriological contamination. The water level data show that there has been a general decline since 1977 due to over-abstraction. The magnitude of this decline has reached about 20 m in some places. However, in one area over the same period, a rise of about 3 m has been observed. This occurs as a result of the local hydrogeological conditions of shallow bedrock and relatively low permeability materials down stream of this area that limits the flow of groundwater towards the northeastern part of the aquifer. The general fall in groundwater levels has been accompanied by a change in the direction of the groundwater flow and an overall reduction of the areal extent of the saturated region of the aquifer. The city now has a serious problem such that even if the abstracted groundwater is rationed, water is not available for long periods because the demand far exceeds the supply. The heavy impact of urbanization on the groundwater quality is shown through the observed high nitrate (up to 295 mg/l as nitrate) and high phosphorus values (about 0.1 mg/l as P). Significant changes in the chloride concentration are also observed in two areas: increasing from 100 mg/l to 1,600 mg/l and from 2,000 mg/l to 4,000 mg/l, respectively. Furthermore, the bacteriological investigations show that 33 percent of the 27 collected groundwater samples are positive for total coliform and 11 percent of the


    Rosemary J. Dyson


    Full Text Available This study assessed human kinetics in relation to golf shoe outer sole design features during the golf swing using a driver club by measuring both within the shoe, and beneath the shoe at the natural grass interface. Three different shoes were assessed: metal 7- spike shoe, alternative 7-spike shoe, and a flat soled shoe. In-shoe plantar pressure data were recorded using Footscan RS International pressure insoles and sampling at 500 Hz. Simultaneously ground reaction force at the shoe outer sole was measured using 2 natural grass covered Kistler force platforms and 1000 Hz data acquisition. Video recording of the 18 right-handed golfers at 200 Hz was undertaken while the golfer performed 5 golf shots with his own driver in each type of shoe. Front foot (nearest to shot direction maximum vertical force and torque were greater than at the back foot, and there was no significant difference related to the shoe type. Wearing the metal spike shoe when using a driver was associated with more torque generation at the back foot (p < 0. 05 than when the flat soled shoe was worn. Within shoe regional pressures differed significantly with golf shoe outer sole design features (p < 0.05. Comparison of the metal spike and alternative spike shoe results provided indications of the quality of regional traction on the outer sole. Potential golf shoe outer sole design features and traction were presented in relation to phases of the golf swing movement. Application of two kinetic measurement methods identified that moderated (adapted muscular control of foot and body movement may be induced by golf shoe outer sole design features. Ground reaction force measures inform comparisons of overall shoe functional performance, and insole pressure measurements inform comparisons of the underfoot conditions induced by specific regions of the golf shoe outer sole


    IONESCU Cozmin


    Full Text Available Carried research regarding footwear soles reveald that by moulding footwear details can be obtained in a wide variety of models. Shoe soles are complex three dimensional objects and for attaching them with the uppers, the interor countour of the soles has to correspond to the featherline contour of the last. That’s why, is necessary that soles design to be done with high accuracy and in strict accordance to the last. Nowadays, there are specialized software applications which can perform various computer aided design processes for footwear. Among the high performance systems used for the design of footwear soles and injection moulds for shoe soles, we may mention: Delcam Shoe Solution, Delcam PowerSHAPE-e, Padsy II and Padsy III, Shoe Master System, Lectra System, Parmel System and ATOS II System. This paper presents a 3D design method, developed by the authors, for footwear flat soles using PowerSHAPE-e software programm from of Delcam Crispin. The computer-aided design technique used in this paper highlights several important advantages that include: increased design quality; three dimensional viewing of soles, which can lead to immediate decisions, regarding the acceptance of newly developed models; it can be appreciated the complexity of mould cavities execution, without the need of making prototypes; the outlines of construction templates are accurately obtained for the mould cavities and for all size numbers; calculations can easily be done for determining the soles volume for the entire size number, with implications on estimating polymer blend consumption and so on.

  6. Opportunities to enhance management of karstic aquifers

    Parizek, Richard R.


    Methods exist to obtain “new sources of water.” Examples include: (1) capturing and enhancing stormwater recharge and retention within diffuse-flow portions of karst and other aquifers; (2) recycling and reuse of waste water; (3) reducing evapotranspiration and rejected recharge; and (4) ameliorating atmospheric acid deposition through use of alkaline groundwater. These little used management methods have immense potential to sustain future water demands. Full utilization of “new” and traditional water resources requires an understanding of the hydrogeologic framework of karstic aquifers. Reliable conceptual, numerical flow and transport models are needed to help evaluate, select, and design viable water management options. Three such simulation examples are provided together with a discussion of Penn State’s Wastewater reuse project where recharge approaches 3.785 × 109l/year

  7. Nitrate in aquifers beneath agricultural systems.

    Burkart, M R; Stoner, J D


    Research from several regions of the world provides spatially anecdotal evidence to hypothesize which hydrologic and agricultural factors contribute to groundwater vulnerability to nitrate contamination. Analysis of nationally consistent measurements from the U.S. Geological Survey's NAWQA program confirms these hypotheses for a substantial range of agricultural systems. Shallow unconfined aquifers are most susceptible to nitrate contamination associated with agricultural systems. Alluvial and other unconsolidated aquifers are the most vulnerable and also shallow carbonate aquifers that provide a substantial but smaller contamination risk. Where any of these aquifers are overlain by permeable soils the risk of contamination is larger. Irrigated systems can compound this vulnerability by increasing leaching facilitated by additional recharge and additional nutrient applications. The system of corn, soybean, and hogs produced significantly larger concentrations of groundwater nitrate than all other agricultural systems because this system imports the largest amount of N-fertilizer per unit production area. Mean nitrate under dairy, poultry, horticulture, and cattle and grains systems were similar. If trends in the relation between increased fertilizer use and groundwater nitrate in the United States are repeated in other regions of the world, Asia may experience increasing problems because of recent increases in fertilizer use. Groundwater monitoring in Western and Eastern Europe as well as Russia over the next decade may provide data to determine if the trend in increased nitrate contamination can be reversed. If the concentrated livestock trend in the United States is global, it may be accompanied by increasing nitrogen contamination in groundwater. Concentrated livestock provide both point sources in the confinement area and intense non-point sources as fields close to facilities are used for manure disposal. Regions where irrigated cropland is expanding, such as

  8. Hydrochemical and geoelectrical investigation of the coastal shallow aquifers in El-Omayed area, Egypt.

    Atwia, M G; Masoud, A A


    Monitoring and assessment of the coastal aquifers are becoming a worldwide concern for the need of additional and sustainable water resources to satisfy demographic growth and economic development. A hydrochemical and geoelectrical investigation was conducted in the El-Omayed area in the northwestern coast of Egypt. The aim of the study was to delineate different water-bearing formations, provide a general evaluation of groundwater quality, and identify the recharge sources in aquifers. Thirty-seven water samples were collected and chemically analyzed from the sand dune accumulations and oolitic limestone aquifers. Fifteen profiles of vertical electrical soundings (VESs) were obtained in the oolitic limestone aquifer to examine the variations of subsurface geology and associated groundwater chemistry. The groundwater reserves in the El-Omayed area are mainly contained in sand dune accumulations and oolitic limestone aquifers. The aquifer of sand dune accumulations contains freshwater of low salinity (average total dissolved solids (TDS) = 974 mg/l). Groundwater of oolitic limestone aquifer is slightly brackish (average TDS = 1,486 mg/l). Groundwater of these aquifers can be used for irrigation under special management for salinity control, and regular leaching as indicated by electrical conductivity and sodium adsorption ratio. Results of VES interpretation classified the subsurface sequence of oolitic limestone aquifer into four geoelectric zones, with increasing depth, calcareous loam, gypsum, oolitic limestone, and sandy limestone. Oolitic limestone constitutes the main aquifer and has a thickness of 12-32 m.


    Ramesh Kumar


    Full Text Available Lipomas are benign soft tissue tumors that can occur at any age and frequently on the upper back, neck, shoulder and abdomen. We present a case of lipoma over sole of foot which is an uncommon location.

  10. High Temperature Aquifer Storage

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas


    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  11. FEMA: a Finite Element Model of Material Transport through Aquifers

    Yeh, G.T.; Huff, D.D.


    This report documents the construction, verification, and demonstration of a Finite Element Model of Material Transport through Aquifers (FEMA). The particular features of FEMA are its versatility and flexibility to deal with as many real-world problems as possible. Mechanisms included in FEMA are: carrier fluid advection, hydrodynamic dispersion and molecular diffusion, radioactive decay, sorption, source/sinks, and degradation due to biological, chemical as well as physical processes. Three optional sorption models are embodied in FEMA. These are linear isotherm and Freundlich and Langmuir nonlinear isotherms. Point as well as distributed source/sinks are included to represent artificial injection/withdrawals and natural infiltration of precipitation. All source/sinks can be transient or steady state. Prescribed concentration on the Dirichlet boundary, given gradient on the Neumann boundary segment, and flux at each Cauchy boundary segment can vary independently of each other. The aquifer may consist of as many formations as desired. Either completely confined or completely unconfined or partially confined and partially unconfined aquifers can be dealt with effectively. FEMA also includes transient leakage to or from the aquifer of interest through confining beds from or to aquifers lying below and/or above.

  12. Specific yield, High Plains aquifer

    U.S. Geological Survey, Department of the Interior — This raster data set represents specific-yield ranges in the High Plains aquifer of the United States. The High Plains aquifer underlies 112.6 million acres (176,000...

  13. Saline aquifer mapping project in the southeastern United States

    Williams, Lester J.; Spechler, Rick M.


    In 2009, the U.S. Geological Survey initiated a study of saline aquifers in the southeastern United States to evaluate the potential use of brackish or saline water from the deeper portions of the Floridan aquifer system and the underlying Coastal Plain aquifer system (Fig. 1). The objective of this study is to improve the overall understanding of the available saline water resources for potential future development. Specific tasks are to (1) develop a digital georeferenced database of borehole geophysical data to enable analysis and characterization of saline aquifers (see locations in Fig. 1), (2) identify and map the regional extent of saline aquifer systems and describe the thickness and character of hydrologic units that compose these systems, and (3) delineate salinity variations at key well sites and along section lines to provide a regional depiction of the freshwater-saltwater interfaces. Electrical resistivity and induction logs, coupled with a variety of different porosity logs (sonic, density, and neutron), are the primary types of borehole geophysical logs being used to estimate the water quality in brackish and saline formations. The results from the geophysical log calculations are being compared to available water-quality data obtained from water wells and from drill-stem water samples collected in test wells. Overall, the saline aquifer mapping project is helping to improve the understanding of saline water resources in the area. These aquifers may be sources of large quantities of water that could be treated by using reverse osmosis or similar technologies, or they could be used for aquifer storage and recovery systems.

  14. Hydrogeology, ground-water movement, and subsurface storage in the Floridan aquifer system in southern Florida

    Meyer, Frederick W.


    The Floridan aquifer system of southern Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the aquifer system in southern Florida generally is at depths ranging from 500 to 1,000 feet, and the average thickness is about 3,000 feet. It is divided into three general hydrogeologic units: (1) the Upper Floridan aquifer, (2) the middle confining unit, and (3) the Lower Floridan aquifer. The Upper Floridan aquifer contains brackish ground water, and the Lower Floridan aquifer contains salty ground water that compares chemically to modern seawater. Zones of high permeability are present in the Upper and Lower Floridan aquifers. A thick, cavernous dolostone in the Lower Floridan aquifer, called the Boulder Zone, is one of the most permeable carbonate units in the world (transmissivity of about 2.5 x 107 feet squared per day). Ground-water movement in the Upper Floridan aquifer is generally southward from the area of highest head in central Florida, eastward to the Straits of Florida, and westward to the Gulf of Mexico. Distributions of natural isotopes of carbon and uranium generally confirm hydraulic gradients in the Lower Floridan aquifer. Groundwater movement in the Lower Floridan aquifer is inland from the Straits of Florida. The concentration gradients of the carbon and uranium isotopes indicate that the source of cold saltwater in the Lower Floridan aquifer is seawater that has entered through the karat features on the submarine Miami Terrace near Fort Lauderdale. The relative ages of the saltwater suggest that the rate of inland movement is related in part to rising sea level during the Holocene transgression. Isotope, temperature, and salinity anomalies in waters from the Upper Floridan aquifer of southern Florida suggest upwelling of saltwater from the Lower Floridan aquifer. The results of the study support the hypothesis of circulating relatively modern seawater and cast doubt on the theory that the

  15. The quality of our Nation's waters: water quality in the Upper Floridan aquifer and overlying surficial aquifers, southeastern United States, 1993-2010

    Berndt, Marian P.; Katz, Brian G.; Kingsbury, James A.; Crandall, Christy A.


    About 10 million people rely on groundwater from the Upper Floridan and surficial aquifers for drinking water. The Upper Floridan aquifer also is of primary importance to the region as a source of water for irrigation and as a source of crystal clear water that discharges to springs and streams providing recreational and tourist destinations and unique aquatic habitats. The reliance of the region on the Upper Floridan aquifer for drinking water and for the tourism and agricultural economies highlights the importance of long-term management to sustain the availability and quality of these resources.

  16. Oman metamorphic sole formation reveals early subduction dynamics

    Soret, Mathieu; Agard, Philippe; Dubacq, Benoît; Plunder, Alexis; Ildefonse, Benoît; Yamato, Philippe; Prigent, Cécile


    Metamorphic soles correspond to m to ~500m thick tectonic slices welded beneath most of the large-scale ophiolites. They typically show a steep inverted metamorphic structure where the pressure and temperature conditions of crystallization increase upward (from 500±100°C at 0.5±0.2 GPa to 800±100°C at 1.0±0.2 GPa), with isograds subparallel to the contact with the overlying ophiolitic peridotite. The proportion of mafic rocks in metamorphic soles also increases from the bottom (meta-sediments rich) to the top (approaching the ophiolite peridotites). These soles are interpreted as the result of heat transfer from the incipient mantle wedge toward the nascent slab (associated with large-scale fluid transfer and possible shear heating) during the first My of intra-oceanic subduction (as indicated by radiometric ages). Metamorphic soles provide therefore major constraints on early subduction dynamics (i.e., thermal structure, fluid migration and rheology along the nascent slab interface). We present a detailed structural and petrological study of the metamorphic sole from 4 major cross-sections along the Oman ophiolite. We show precise pressure-temperature estimates obtained by pseudosection modelling and EBSD measurements performed on both the garnet-bearing and garnet-free high-grade sole. Results allow quantification of the micro-scale deformation and highlight differences in pressure-temperature-deformation conditions between the 4 different locations, showing that the inverted metamorphic gradient through the sole is not continuous in all locations. Based on these new constraints, we suggest a new tectonic-petrological model for the formation of metamorphic soles below ophiolites. This model involves the stacking of several homogeneous slivers of oceanic crust leading to the present-day structure of the sole. In this view, these thrusts are the result of rheological contrasts between the sole and the peridotite as the plate interface progressively cools down

  17. sources

    Shu-Yin Chiang


    Full Text Available In this paper, we study the simplified models of the ATM (Asynchronous Transfer Mode multiplexer network with Bernoulli random traffic sources. Based on the model, the performance measures are analyzed by the different output service schemes.

  18. Transfert d'un composé organo-chloré depuis une zone source localisée en zone non saturée d'un aquifère poreux vers l'interface sol-air : expérimentations et modélisations associées

    Marzougui, Salsabil


    Two experiments were conducted on the experimental platform "SCERES" to assess the TCE vapour concentrations and fluxes in SCERES with two concrete slabs installed, one after the other, on the ground surface. This artificial aquifer is a large scale (25 x 12 x 3 m3) heterogeneous porous medium. The results showed that the TCE vapour plume covers most of the basin 3 weeks after the creation of the TCE source area in unsaturated zone. The heterogeneity of SCERES has generated a non uniform vert...

  19. Stiffness Effects in Rocker-Soled Shoes: Biomechanical Implications

    Su, Pei-Fang; Chung, Chia-Hua; Hsia, Chi-Chun; Chang, Chih-Han


    Rocker-soled shoes provide a way to reduce the possible concentration of stress, as well as change movement patterns, during gait. This study attempts to examine how plantar force and spatio-temporal variables are affected by two rocker designs, one with softer and one with denser sole materials, by comparing them with the barefoot condition and with flat-soled shoes. Eleven subjects’ gait parameters during walking and jogging were recorded. Our results showed that compared with barefoot walking, plantar forces were higher for flat shoes while lower for both types of rocker shoes, the softer-material rocker being the lowest. The plantar force of flat shoes is greater than the vertical ground reaction force, while that of both rocker shoes is much less, 13.87–30.55% body weight. However, as locomotion speed increased to jogging, for all shoe types, except at the second peak plantar force of the denser sole material rocker shoes, plantar forces were greater than for bare feet. More interestingly, because the transmission of force was faster while jogging, greater plantar force was seen in the rocker-soled shoes with softer material than with denser material; results for higher-speed shock absorption in rocker-soled shoes with softer material were thus not as good. In general, the rolling phenomena along the bottom surface of the rocker shoes, as well as an increase in the duration of simultaneous curve rolling and ankle rotation, could contribute to the reduction of plantar force for both rocker designs. The possible mechanism is the conversion of vertical kinetic energy into rotational kinetic energy. To conclude, since plantar force is related to foot-ground interface and deceleration methods, rocker-design shoes could achieve desired plantar force reduction through certain rolling phenomena, shoe-sole stiffness levels, and locomotion speeds. PMID:28046009

  20. Geochemistry of the Cambrian-Ordovician aquifer system in the northern Midwest, United States: D in Regional aquifer-system analysis

    Siegel, D.I.


    Distributions of solutes in aquifers of Cambrian and Ordovician age were studied in Minnesota, Wisconsin, Iowa, Illinois, northwestern Indiana, and northern Missouri to determine the sources of solutes and the probable chemical mechanisms that control regional variations in water quality. This work is part of the Northern Midwest Regional Aquifer-System Analysis project, whose objective is to describe and model the regional hydrogeology of the Cambrian- Ordovician aquifer system in the study region. The data base used included more than 3,000 ground-water-quality analyses from all major aquifers, but especially from the St. Peter, Jordan, and Mount Simon Sandstones and their equivalents. Regional variations in the water chemistry of glacial drift and other sedimentary units that overlie the Cambrian-Ordovician aquifer system in recharge areas in Minnesota, Iowa, Wisconsin, and Illinois were also studied, but to a lesser degree.

  1. Potential of groundwater contamination by polybrominated diphenyl ethers (PBDEs) in a sensitive bedrock aquifer (Canada)

    Levison, Jana; Novakowski, Kent; Reiner, Eric J.; Kolic, Terry


    It is necessary to understand the presence, movement, and persistence of contaminants in aquifers to develop adequate groundwater protection plans. Fractured bedrock aquifers with thin overburden cover are very sensitive to contamination, and little is known about transport processes from the ground surface to depth in this setting. This study was undertaken to investigate the potential of groundwater contamination by polybrominated diphenyl ethers (PBDEs), which are flame retardants, in a natural fractured bedrock aquifer in Canada proven to be sensitive to contamination. PBDEs, which had not been previously measured in groundwater in detail, were detected in the study aquifer at concentrations greater than those observed in surface-water bodies. Potential sources include manure, septic tanks, and the atmosphere. From this scoping study, it is evident that additional surveys of PBDE concentrations in groundwater are warranted, especially in settings with high potential source concentrations coupled with sensitive aquifers.

  2. Potentiometric surface, 2012, and water-level differences, 2005-12, of the Sparta Aquifer in north-central Louisiana

    McGee, Benton D.; Brantly, Jeffrey A.


    The Sparta aquifer is used in 15 parishes in north-central Louisiana, primarily for public supply and industrial purposes. Of those parishes, eight (Bienville, Claiborne, Jackson, Lincoln, Ouachita, Union, Webster, and Winn) rely on the Sparta aquifer as their principal source of groundwater. In 2010, withdrawals from the Sparta aquifer in Louisiana totaled 63.11 million gallons per day (Mgal/d), a reduction of more than 11 percent from 1995, when the highest rate of withdrawals (71.32 Mgal/d) from the Sparta aquifer were documented. The Sparta aquifer provides water for a variety of purposes which include public supply (34.61 Mgal/d), industrial (25.60 Mgal/d), rural domestic (1.50 Mgal/d), and various agricultural (1.40 Mgal/d). Of the 13 major aquifers or aquifer systems in Louisiana, the Sparta aquifer is currently (2012) the sixth most heavily pumped. The Sparta aquifer is the second most heavily pumped aquifer in Arkansas, which borders Louisiana to the north. In 2005, 170 Mgal/d were withdrawn from the Sparta aquifer in eastern and southern Arkansas; of that total, about 15.55 Mgal/d were withdrawn from the aquifer in Union County, which borders Claiborne and Union Parishes to the north. By 1997, a large cone of depression (a cone-shaped depression in the potentiometric surface caused by and centered on a pumping well or wells) in the Sparta aquifer centered over Union County had merged with the cone of depression at West Monroe. In 2004, the rate of withdrawal from the Sparta aquifer in Union County began to decline and water levels in the aquifer began to rise in nearby areas of Arkansas and Louisiana.

  3. Hydrogeochemical contrast between brown and grey sand aquifers in shallow depth of Bengal Basin: consequences for sustainable drinking water supply.

    Biswas, Ashis; Nath, Bibhash; Bhattacharya, Prosun; Halder, Dipti; Kundu, Amit K; Mandal, Ujjal; Mukherjee, Abhijit; Chatterjee, Debashis; Mörth, Carl-Magnus; Jacks, Gunnar


    Delineation of safe aquifer(s) that can be targeted by cheap drilling technology for tubewell (TW) installation becomes highly imperative to ensure access to safe and sustainable drinking water sources for the arsenic (As) affected population in Bengal Basin. This study investigates the potentiality of brown sand aquifers (BSA) as a safe drinking water source by characterizing its hydrogeochemical contrast to grey sand aquifers (GSA) within shallow depth (water guidelines, which warrants rigorous assessment of attendant health risk for Mn prior to considering mass scale exploitation of the BSA for possible sustainable drinking water supply.

  4. Base of aquifer contours for the Northern High Plains aquifer

    U.S. Geological Survey, Department of the Interior — Several pre-existing datasets that characterize portions of the Northern High Plains aquifer base were merged together in order to define the entire base of the...

  5. Contrasting definitions for the term `karst aquifer'

    Worthington, Stephen R. H.; Jeannin, Pierre-Yves; Alexander, E. Calvin; Davies, Gareth J.; Schindel, Geary M.


    It is generally considered that karst aquifers have distinctly different properties from other bedrock aquifers. A search of the literature found five definitions that have been proposed to differentiate karst aquifers from non-karstic aquifers. The five definitions are based upon the presence of solution channel networks, hydraulic conductivities >10-6 m/s, karst landscapes, channels with turbulent flow, and caves. The percentage of unconfined carbonate aquifers that would classify as `karst' ranges from 50%.

  6. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace aquifer covers...

  7. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately 193,000 acres and...

  8. Groundwater Exploration in Freshwater/Saline Layered Aquifers - Southern Bangladesh.

    McKelvey, P. A.; Rahman, M.


    A major urban water supply and sanitation project is being implemented in the southern coastal districts of Bangladesh, by the Governments of Bangladesh and Denmark (DPHE/DANIDA). Due to the poor quality and reliability of surface water in the coastal districts, the source for these schemes will be groundwater. However, the abstraction of large quantities of water is complicated by the fact that the shallow aquifers are thin and of poor hydraulic quality. In addition, there is saline water underlying the shallow aquifer and, in recent years, arsenic has been discovered in many shallow wells throughout Bangladesh. Over the majority of the coastal districts, a thick freshwater sand underlies the saline aquifers, at depths below 200 m. This freshwater unit is bounded by thick clays which protect it from overlying and underlying saline water. The deep aquifer has been exploited in some of the project towns but in a few areas no freshwater aquifers had been located. An exploration programme was undertaken in each of these towns to prove the location of the freshwater sands and to help plan the location and depth of production well drilling. The first exploration stage was to locate any existing deep hand pumped wells and to carry out a water quality survey. Generally, this was sufficient to prove the existence of a thick freshwater aquifer. However, exact well depths and geological data were usually lacking and an exploration well was usually required. In three of the project towns, no deep aquifers had been exploited by existing hand pumped wells and geophysical surveys were undertaken to identify the locations of freshwater aquifers. These surveys comprised resistivity sounding both within the towns and in outlying areas within a feasible pumping distance. In two cases, freshwater aquifers were inferred from the geophysical surveys and exploration drilling was undertaken to prove the resource. Exploration drilling was undertaken by local contractors using hand

  9. Mississippi River Valley alluvial aquifer

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Mississippi River Valley alluvial aquifer in the states of Missouri, Kentucky, Tennessee, Arkansas, Mississippi, and...

  10. Southeastern Coastal Plain aquifer system

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Southeastern Coastal Plain aquifer system in Kentucky, Tennessee, Mississippi, Alabama, Georgia, and South Carolina.

  11. Metatranscriptomic Analysis Reveals Unexpectedly Diverse Microbial Metabolism in a Biogeochemical Hot Spot in an Alluvial Aquifer

    Jewell, Talia N. M.; Karaoz, Ulas; Bill, Markus; Chakraborty, Romy; Brodie, Eoin L.; Williams, Kenneth H.; Beller, Harry R.


    Organic matter deposits in alluvial aquifers have been shown to result in the formation of naturally reduced zones (NRZs), which can modulate aquifer redox status and influence the speciation and mobility of metals, affecting groundwater geochemistry. In this study, we sought to better understand how natural organic matter fuels microbial communities within anoxic biogeochemical hot spots (NRZs) in a shallow alluvial aquifer at the Rifle (CO) site. We conducted a 20-day microcosm experiment in which NRZ sediments, which were enriched in buried woody plant material, served as the sole source of electron donors and microorganisms. The microcosms were constructed and incubated under anaerobic conditions in serum bottles with an initial N2 headspace and were sampled every 5 days for metagenome and metatranscriptome profiles in combination with biogeochemical measurements. Biogeochemical data indicated that the decomposition of native organic matter occurred in different phases, beginning with mineralization of dissolved organic matter (DOM) to CO2 during the first week of incubation, followed by a pulse of acetogenesis that dominated carbon flux after 2 weeks. A pulse of methanogenesis co-occurred with acetogenesis, but only accounted for a small fraction of carbon flux. The depletion of DOM over time was strongly correlated with increases in expression of many genes associated with heterotrophy (e.g., amino acid, fatty acid, and carbohydrate metabolism) belonging to a Hydrogenophaga strain that accounted for a relatively large percentage (~8%) of the metatranscriptome. This Hydrogenophaga strain also expressed genes indicative of chemolithoautotrophy, including CO2 fixation, H2 oxidation, S-compound oxidation, and denitrification. The pulse of acetogenesis appears to have been collectively catalyzed by a number of different organisms and metabolisms, most prominently pyruvate:ferredoxin oxidoreductase. Unexpected genes were identified among the most highly expressed

  12. Delineation of Fractured Aquifer Using Numerical Analysis (Factor of Resistivity Data in a Granite Terrain

    Rolland Andrade


    Full Text Available In hard rock terrain, fractured aquifers comprise the major source of groundwater availability where the phreatic aquifer is desaturated. Identification of fracture zones in hard rock terrain and potential groundwater source delineation had been a perennial problem in hydrology. The purpose of this paper is to highlight the study over a small watershed area, in a granite terrain, wherein an attempt was made to delineate and map the fractured aquifer using numerical (factor analysis of the conventional vertical electrical sounding data, which was obscure in curve matching technique. This numerical approach in concatenation with resistivity imaging or other techniques would prove to be an effective tool in groundwater exploration.

  13. Microbial dynamics in natural aquifers

    Bajracharya, Bijendra Man


    Microorganisms in groundwater form ecosystems that can transform chemical compounds. Quantitatively understanding microbial dynamics in soils and groundwater is thus essential for pollutant dynamics and biogeochemistry in the subsurface. This dissertation addresses three factors influencing microbial dynamics in aquifers and soils, namely: (1) the influence of grazing on bacteria in eutrophic aquifers, posing the question whether the carrying capacity of bacteria, which has been observed i...

  14. Degloved foot sole successfully reconstructed with split thickness skin grafts

    Janssens, Loes; Holtslag, Herman R.; Schellekens, Pascal P A; Leenen, Luke P H


    Introduction The current opinion is that split thickness skin grafts are not suitable to reconstruct a degloved foot sole. The tissue is too fragile to carry full bodyweight; and therefore, stress lesions frequently occur. The treatment of choice is the reuse of the avulsed skin whenever possible,

  15. Children's Adjustment in Joint and Sole Physical Custody Families.

    Kline, Marsha; And Others


    Examined patterns of custody and their relationship to the behavioral-emotional and social adjustment of 93 children of 3-14 years of age. Found no evidence that joint physical custody arrangements differ from sole physical custody arrangements with regard to postdivorce child adjustment. (RH)

  16. Recognition and Accountability: Sole Parent Postgraduates in University Conditions

    Hook, Genine A.


    This paper aims to examine some of ways sole parents sought recognition as postgraduate students in Australian universities. Judith Butler's theory of recognition notes that recognition is always partial and any account we give of ourselves must be given to another. Participants articulated that supervisors were critical in the process of…

  17. Acute meningoencephalitis as the sole manifestation of Q fever.

    Guerrero, M; Gutierrez, J; Carnero, C; Gonzalez-Maldonado, R; Maroto, C


    The case of a 25-year old man who presented with meningoencephalitis as the sole clinical manifestation of Q fever is described. Serological studies revealed the presence of IgM and IgG antibodies to Coxiella burnetii. The patient responded favourably to a ten-day course of i.v. ceftriaxone and was discharged without any neurological sequelae.

  18. Stocking density-dependent growth of Dover sole (Solea solea)

    Schram, E.; Heul, van der J.W.; Kamstra, A.; Verdegem, M.C.J.


    Dover sole were reared at 6 different stocking densities between 0.56 and 12.6 kg/m2 with duplicate tanks for each treatment. The experiment lasted for 55 days. Water quality effects on growth were minimised by making the flow rate per tank proportional to the feeding load. Individual initial and


    Cornelia LUCA


    Full Text Available The paper presents contributions in the designing of some electrochemical technologiesfor the manufacturing of the moulds used in the footwear soles obtaining. There are presented a fewmethods for the moulds obtaining, using electro-deposit processes. There are presented thetechnological phases of the obtaining process of the electrolytes and electrodes preparing and thetechnological stages of the moulds manufacturing.

  20. Selecting Sole: breeding programs for natural - mating populations

    Blonk, R.J.W.


    The aim of this thesis was to design a breeding program for increased productivity of farmed common sole, Solea solea, 1) using natural mating in groups to obtain offspring and 2) using present farm infrastructures as much as possible. Parental allocation with DNA marker data on offspring from

  1. Characterising Bedrock Aquifer Systems in Korea Using Paired Water-Level Monitoring Data

    Jae Min Lee


    patterns were identified from the water-level pairs: Type I of identical aquifer systems (77.8%, Type II of the different aquifer systems with different recharge flow paths (9.5%, and Type III of unmatched aquifer system pairs and correlations (12.7%. Type I and II could be used as verification of aquifer condition in the paired monitoring system. However, Type III shows the complexity of water-level fluctuation in different aquifer conditions. This study showed that confined or not-confined conditions are not directly related to the depth of wells in the aquifer. Therefore, the utilisation of groundwater as a water-supply source should be carefully designed, tested for its hydrogeologic conditions, and managed to ensure sustainable quantity and quality.

  2. Characteristics of Rural Communities with a Sole, Independently Owned Pharmacy.

    Nattinger, Matthew; Ullrich, Fred; Mueller, Keith J


    Prior RUPRI Center policy briefs have described the role of rural pharmacies in providing many essential clinical services (in addition to prescription and nonprescription medications), such as blood pressure monitoring, immunizations, and diabetes counseling, and the adverse effects of Medicare Part D negotiated networks on the financial viability of rural pharmacies.1 Because rural pharmacies play such a broad role in health care delivery, pharmacy closures can sharply reduce access to essential health care services in rural and underserved communities. These closures are of particular concern in rural areas served by a sole, independently owned pharmacy (i.e., a pharmacy unaffiliated with a chain or franchise). This policy brief characterizes the population of rural areas served by a sole, independently owned pharmacy. Dependent on a sole pharmacy, these areas are at highest risk to lose access to many essential clinical services. Key Findings. (1) In 2014 over 2.7 million people lived in 663 rural communities served by a sole, independently owned pharmacy. (2) More than one-quarter of these residents (27.9 percent) were living below 150 percent of the federal poverty level. (3) Based on estimates from 2012, a substantial portion of the residents of these areas were dependent on public insurance (i.e., Medicare and/or Medicaid, 20.5 percent) or were uninsured (15.0 percent). (4) If the sole, independent retail pharmacy in these communities were to close, the next closest retail pharmacy would be over 10 miles away for a majority of rural communities (69.7 percent).

  3. Wave-Induced Groundwater Flows in a Freshwater Beach Aquifer

    Malott, S. S.; Robinson, C. E.; O'Carroll, D. M.


    Wave-induced recirculation across the sediment-water interface can impact the transport of pollutants through a beach aquifer and their ultimate flux into coastal waters. The fate of nutrients (e.g. from septic and agricultural sources) and fecal indicator bacteria (e.g. E. coil) near the sediment-water interface are of particular concern as these pollutants often lead to degradation of recreational water quality and nearshore ecosystems. This paper presents detailed field measurements of groundwater flows in a freshwater beach aquifer on Lake Huron over periods of intensified wave conditions. Quantifying wave-driven processes in a freshwater beach aquifer enables wave effects to be studied in isolation from density and tidal effects that complicate groundwater flows in marine beaches. Water exchange across the sediment-water interface and groundwater flow patterns were measured using groundwater wells, arrays of vertically nested pressure transducers and manometers. Results show that wave action induces rapid infiltration/exfiltration across the sediment-water interface and a larger recirculation cell through the beach aquifer. Field data is used to validate a numerical groundwater model of wave-induced groundwater flows. While prior studies have simulated the effects of waves on beach groundwater flows, this study is the first attempt to validate these sophisticated modeling approaches. Finally, field data illustrating the impact of wave-induced groundwater flows on nutrient and bacteria fate and transport in beach aquifers will also be presented.

  4. Characterising aquifer treatment for pathogens in managed aquifer recharge.

    Page, D; Dillon, P; Toze, S; Sidhu, J P S


    In this study the value of subsurface treatment of urban stormwater during Aquifer Storage Transfer Recovery (ASTR) is characterised using quantitative microbial risk assessment (QMRA) methodology. The ASTR project utilizes a multi-barrier treatment train to treat urban stormwater but to date the role of the aquifer has not been quantified. In this study it was estimated that the aquifer barrier provided 1.4, 2.6, >6.0 log(10) removals for rotavirus, Cryptosporidium and Campylobacter respectively based on pathogen diffusion chamber results. The aquifer treatment barrier was found to vary in importance vis-à-vis the pre-treatment via a constructed wetland and potential post-treatment options of UV-disinfection and chlorination for the reference pathogens. The risk assessment demonstrated that the human health risk associated with potable reuse of stormwater can be mitigated (disability adjusted life years, DALYs aquifer is integrated with suitable post treatment options into a treatment train to attenuate pathogens and protect human health.

  5. Sources


    SOURCES MANUSCRITES Archives nationales Rôles de taille 1768/71 Z1G-344/18 Aulnay Z1G-343a/02 Gennevilliers Z1G-340/01 Ivry Z1G-340/05 Orly Z1G-334c/09 Saint-Remy-lès-Chevreuse Z1G-344/18 Sevran Z1G-340/05 Thiais 1779/80 Z1G-391a/18 Aulnay Z1G-380/02 Gennevilliers Z1G-385/01 Ivry Z1G-387b/05 Orly Z1G-388a/09 Saint-Remy-lès-Chevreuse Z1G-391a/18 Sevran Z1G-387b/05 Thiais 1788/89 Z1G-451/18 Aulnay Z1G-452/21 Chennevières Z1G-443b/02 Gennevilliers Z1G-440a/01 Ivry Z1G-452/17 Noiseau Z1G-445b/05 ...

  6. The quality of our Nation's waters: water quality in the Mississippi embayment-Texas coastal uplands aquifer system and Mississippi River Valley alluvial aquifer, south-central United States, 1994-2008

    Kingsbury, James A.; Barlow, Jeannie R.; Katz, Brian G.; Welch, Heather L.; Tollett, Roland W.; Fahlquist, Lynne S.


    About 8 million people rely on groundwater from the Mississippi embayment—Texas coastal uplands aquifer system for drinking water. The Mississippi River Valley alluvial aquifer also provides drinking water for domestic use in rural areas but is of primary importance to the region as a source of water for irrigation. Irrigation withdrawals from this aquifer are among the largest in the Nation and play a key role in the economy of the area, where annual crop sales total more than $7 billion. The reliance of the region on both aquifers for drinking water and irrigation highlights the importance of long-term management to sustain the availability and quality of these resources.

  7. Arsenic release from Floridan Aquifer rock during incubations simulating aquifer storage and recovery operations.

    Jin, Jin; Zimmerman, Andrew R; Norton, Stuart B; Annable, Michael D; Harris, Willie G


    While aquifer storage and recovery (ASR) is becoming widely accepted as a way to address water supply shortages, there are concerns that it may lead to release of harmful trace elements such as arsenic (As). Thus, mechanisms of As release from limestone during ASR operations were investigated using 110-day laboratory incubations of core material collected from the Floridan Aquifer, with treatment additions of labile or refractory dissolved organic matter (DOM) or microbes. During the first experimental phase, core materials were equilibrated with native groundwater lacking in DO to simulate initial non-perturbed anaerobic aquifer conditions. Then, ASR was simulated by replacing the native groundwater in the incubations vessels with DO-rich ASR source water, with DOM or microbes added to some treatments. Finally, the vessels were opened to the atmosphere to mimic oxidizing conditions during later stages of ASR. Arsenic was released from aquifer materials, mainly during transitional periods at the beginning of each incubation stage. Most As released was during the initial anaerobic experimental phase via reductive dissolution of Fe oxides in the core materials, some or all of which may have formed during the core storage or sample preparation period. Oxidation of As-bearing Fe sulfides released smaller amounts of As during the start of later aerobic experimental phases. Additions of labile DOM fueled microbially-mediated reactions that mobilized As, while the addition of refractory DOM did not, probably due to mineral sorption of DOM that made it unavailable for microbial utilization or metal chelation. The results suggest that oscillations of groundwater redox conditions, such as might be expected to occur during an ASR operation, are the underlying cause of enhanced As release in these systems. Further, ASR operations using DOM-rich surface waters may not necessarily lead to additional As releases.

  8. Aquifer test at well SMW-1 near Moenkopi, Arizona

    Carruth, Rob; Bills, Donald J.


    The Hopi villages of Lower Moencopi and Upper Moenkopi are on the Hopi Indian Reservation south of Tuba City in northern Arizona. These adjacent Hopi villages, located west and north of the confluence of Pasture Canyon Wash and Moenkopi Wash, are dependent on groundwater withdrawals from three wells that penetrate the N aquifer and from two springs that discharge from the N aquifer. The N aquifer is the principal aquifer in this region of northern Arizona and is composed of thick beds of sandstone between less permeable layers of siltstone and mudstone. The fine-grained character of the N aquifer inhibits rapid movement of water and large yields to wells; however, the aquifer is moderately productive at yields generally less than 25 gallons per minute in the study area. In recent years, the water level has declined in the three public-supply wells and the flow from the springs has decreased, causing concern that the current water supply will not be able to accommodate peak demand and allow for residential and economic growth. In addition to the challenge imposed by declining groundwater levels, the water-supply wells and springs are located about 2 miles downgradient from the Tuba City Landfill site where studies are ongoing to determine if uranium and other metals in groundwater beneath the landfill are higher than regional concentrations in the N aquifer. In August 2008, the U.S. Geological Survey, in cooperation with the Hopi Tribe, conducted an aquifer test on well SMW-1, designed to help the Hopi Tribe determine the potential yield and water quality of the N aquifer south of Moenkopi Wash as a possible source of additional water supply. Well SMW-1 was drilled south of Moenkopi Wash to a depth of 760 feet below land surface before being backfilled and cased to about 300 feet. The well penetrates, in descending order, the Navajo Sandstone and the Kayenta Formation, both units of the N aquifer. The pre-test water level in the well was 99.15 feet below land

  9. Groundwater vulnerability mapping in Guadalajara aquifers system (Western Mexico)

    Rizo-Decelis, L. David; Marín, Ana I.; Andreo, Bartolomé


    Groundwater vulnerability mapping is a practical tool to implement strategies for land-use planning and sustainable socioeconomic development coherent with groundwater protection. The objective of vulnerability mapping is to identify the most vulnerable zones of catchment areas and to provide criteria for protecting the groundwater used for drinking water supply. The delineation of protection zones in fractured aquifers is a challenging task due to the heterogeneity and anisotropy of hydraulic conductivities, which makes difficult prediction of groundwater flow organization and flow velocities. Different methods of intrinsic groundwater vulnerability mapping were applied in the Atemajac-Toluquilla groundwater body, an aquifers system that covers around 1300 km2. The aquifer supplies the 30% of urban water resources of the metropolitan area of Guadalajara (Mexico), where over 4.6 million people reside. Study area is located in a complex neotectonic active volcanic region in the Santiago River Basin (Western Mexico), which influences the aquifer system underneath the city. Previous works have defined the flow dynamics and identified the origin of recharge. In addition, the mixture of fresh groundwater with hydrothermal and polluted waters have been estimated. Two main aquifers compose the multilayer system. The upper aquifer is unconfined and consists of sediments and pyroclastic materials. Recharge of this aquifer comes from rainwater and ascending vertical fluids from the lower aquifer. The lower aquifer consists of fractured basalts of Pliocene age. Formerly, the main water source has been the upper unit, which is a porous and unconsolidated unit, which acts as a semi-isotropic aquifer. Intense groundwater usage has resulted in lowering the water table in the upper aquifer. Therefore, the current groundwater extraction is carried out from the deeper aquifer and underlying bedrock units, where fracture flow predominates. Pollution indicators have been reported in

  10. Why sole-supplier vaccine markets may be here to stay.

    Danzon, Patricia; Pereira, Nuno Sousa


    Given the structure of costs, demand, and competition, vaccine markets reach long-run equilibrium with one or very few suppliers at any point in time. Sole suppliers are less likely to exit and may have lower total social costs. Vaccine markets are dynamically competitive, with new, superior products displacing older, inferior products. Measures to address short-run supply disruptions include inventories, foreign sourcing, and improved technologies. Increasing the relative prices paid for new vaccines to levels that more closely reflect their social value compared to other new drugs and biologics is essential to achieving appropriate incentives for allocation of pharmaceutical R and D.


    Four topics were studied concerning the modeling of groundwater flow in coastal aquifers with analytic elements: (1) practical experience was obtained by constructing a groundwater model of the shallow aquifers below the Delmarva Peninsula USA using the commercial program MVAEM; ...

  12. Saturated thickness, High Plains aquifer, 2009

    U.S. Geological Survey, Department of the Interior — This raster data set represents the saturated thickness of the High Plains aquifer of the United States, 2009, in feet. The High Plains aquifer underlies...


    Four topics were studied concerning the modeling of groundwater flow in coastal aquifers with analytic elements: (1) practical experience was obtained by constructing a groundwater model of the shallow aquifers below the Delmarva Peninsula USA using the commercial program MVAEM; ...

  14. Saturated and Unsaturated Flow due to Tidal Fluctuation and Rainfall in a Coastal Aquifer

    Yeh, Hund-Der; Chuang, Mo-Hsiung; Chang, Chia-Hao


    The prediction of groundwater level fluctuations due to tidal waves propagation and localized recharge in coastal aquifers is important for the development and management of water resources in coastal areas. Most of the past models for the recharge problem consider either saturated flow or unsaturated flow in the aquifers. However, it is expected that the recharge sources infiltrating from the ground surface have significant impact on the hydraulic heads in saturated and unsaturated zones of an unconfined aquifer in reality. The objective of this study is to derive a closed-form analytical expression for predicting tidal responses in a coastal aquifer system with considering rainfall recharge as well as coupled saturated and unsaturated flow. The model is composed of a linearized Richards equation for unsaturated flow coupled with the saturated groundwater flow equation. The top boundary at the ground surface is represented by the flux condition with a source term denoting the recharge in the coastal aquifer system. The solution of the model is developed in Cartesian coordinates based on the methods of Laplace transform and double-integral transform. On the basis of the analytical solution, the groundwater head fluctuations induced by the joint effect of rainfall and oceanic tides is examined in saturated and unsaturated zones of the aquifer. In addition, the influences of the unsaturated flow on the water table movement are also investigated and discussed. Key words: analytical solution, unsaturated flow, coastal aquifer.

  15. Reducing uncertainty in calibrating aquifer flow model with multiple scales of heterogeneity.

    Zhang, Ye


    Modeling and calibration of natural aquifers with multiple scales of heterogeneity is a challenging task due to limited subsurface access. While computer modeling plays an essential role in aquifer studies, large uncertainty exists in developing a conceptual model of an aquifer and in calibrating the model for decision making. Due to uncertainties such as a lack of understanding of subsurface processes and a lack of techniques to parameterize the subsurface environment (including hydraulic conductivity, source/sink rate, and aquifer boundary conditions), existing aquifer models often suffer nonuniqueness in calibration, leading to poor predictive capability. A robust calibration methodology is needed that can address the simultaneous estimations of aquifer parameters, source/sink, and boundary conditions. In this paper, we propose a multistage and multiscale approach that addresses subsurface heterogeneity at multiple scales, while reducing uncertainty in estimating the model parameters and model boundary conditions. The key to this approach lies in the appropriate development, verification, and synthesis of existing and new techniques of static and dynamic data integration. In particular, based on a given set of observation data, new inversion techniques can be first used to estimate aquifer large-scale effective parameters and smoothed boundary conditions, based on which parameter and boundary condition estimation can be refined at increasing detail using standard or highly parameterized estimation techniques.

  16. The surficial aquifer in Pinellas County, Florida

    Causseaux, K.W.


    The surficial aquifer in Pinellas County, Florida, contains potable water throughout most of the county and is a potential source of water to augment the public supply that is presently imported from adjacent counties. The county accounts for 38 percent of the public supply consumption of ground water in the 11-county area of west-central Florida and 68 percent of this water is imported from two adjacent counties. The surficial aquifer has a saturated thickness of more than 30 feet throughout most of the county. Specific capacity per foot of screen for wells is less than 0.1 gallon per minute per foot of drawdown in some parts of the county, but yield is sufficient in most of the county for many small uses with shallow-well pumps. Minimum potential yield varies from 5 gallons per minute in the northern part of the county to more than 30 gallons per minute in the south. Concentrations of iron are high enough in parts of the county to cause staining. Chloride concentrations are less than 100 milligrams per liter in most of the county and do not pose a problem for many uses. (USGS)

  17. Saltwater intrusion in the Floridan aquifer, coastal Citrus and Hernando Counties, Florida, 1975

    Mills, L.R.; Ryder, Paul D.


    The coastal parts of Citrus and Hernando Counties, Fla., are undergoing extensive urban development along U.S. Highway 19. The Floridan aquifer, a thick sequence of limestone and dolomite , is the principal source of water supply for the coastal parts of these two counties. The construction of canals that penetrate the Floridan aquifer, deficient rainfall during 1964-75, and pumping of ground water, have caused saltwater to intrude the aquifer. A map shows the inland extend of that intrusion as of 1975. The report is based on field data collected in 1964, 1973, and 1975. (Woodard-USGS)

  18. Ground-water flow and quality in Wisconsin's shallow aquifer system

    Kammerer, P.A.


    The areal concentration distribution of commonmineral constituents and properties of ground water in Wisconsin's shallow aquifer system are described in this report. Maps depicting the water quality and the altitude of the water table are included. The shallow aquifer system in Wisconsin, composed of unconsolidated sand and gravel and shallow bedrock, is the source of most potable ground-water supplies in the State. Most ground water in the shallow aquifer system moves in local flow systems, but it interacts with regional flow systems in some areas.

  19. Coastal aquifers: Scientific advances in the face of global environmental challenges

    Post, Vincent E. A.; Werner, Adrian D.


    Coastal aquifers embody the subsurface transition between terrestrial and marine systems, and form the almost invisible pathway for tremendous volumes of freshwater that flow to the ocean. Changing conditions of the earth's landscapes and oceans can disrupt the fragile natural equilibrium between fresh and saltwater that exists in coastal zones. Among these, over-abstraction of groundwater is considered the leading man-made cause of seawater intrusion. Moreover, many of the world's largest urban settings, where sources of contamination are profuse, have been built over the freshwater in coastal aquifers. Thus, coastal aquifers are important receptors of human impacts to water on Earth (Michael et al., 2017). This Special Issue on 'Investigation and Management of Coastal Aquifers' contains current scientific advances on the topic, dealing with the storage and quality of water, affected by stressors ranging in scale from point source contamination to global climate change.

  20. Precision Dual-Aquifer Dewatering at a Low Level Radiological Cleanup in New Jersey

    Gosnell, A. S.; Langman, J. W. Jr.; Zahl, H. A.; Miller, D. M.


    Cleanup of low-level radioactive wastes at the Wayne Interim Storage Site (WISS), Wayne, New Jersey during the period October, 2000 through November, 2001 required the design, installation and operation of a dual-aquifer dewatering system to support excavation of contaminated soils. Waste disposal pits from a former rare-earth processing facility at the WISS had been in contact with the water table aquifer, resulting in moderate levels of radionuclides being present in the upper aquifer groundwater. An uncontaminated artesian aquifer underlies the water table aquifer, and is a localized drinking water supply source. The lower aquifer, confined by a silty clay unit, is flowing artesian and exhibits potentiometric heads of up to 4.5 meters above grade. This high potentiometric head presented a strong possibility that unloading due to excavation would result in a ''blowout'', particularly in areas where the confining unit was < 1 meter thick. Excavation of contaminated materials w as required down to the surface of the confining unit, potentially resulting in an artesian aquifer head of greater than 8 meters above the excavation surface. Consequently, it was determined that a dual-aquifer dewatering system would be required to permit excavation of contaminated material, with the water table aquifer dewatered to facilitate excavation, and the deep aquifer depressurized to prevent a ''blowout''. An additional concern was the potential for vertical migration of contamination present in the water table aquifer that could result from a vertical gradient reversal caused by excessive pumping in the confined system. With these considerations in mind, a conceptual dewatering plan was developed with three major goals: (1) dewater the water table aquifer to control radionuclide migration and allow excavation to proceed; (2) depressurize the lower, artesian aquifer to reduce the potential for a ''blowout''; and (3

  1. The utility of gravity and water-level monitoring at alluvial aquifer wells in southern Arizona

    Pool, D.R.


    Coincident monitoring of gravity and water levels at 39 wells in southern Arizona indicate that water-level change might not be a reliable indicator of aquifer-storage change for alluvial aquifer systems. One reason is that water levels in wells that are screened across single or multiple aquifers might not represent the hydraulic head and storage change in a local unconfined aquifer. Gravity estimates of aquifer-storage change can be approximated as a one-dimensional feature except near some withdrawal wells and recharge sources. The aquifer storage coefficient is estimated by the linear regression slope of storage change (estimated using gravity methods) and water-level change. Nonaquifer storage change that does not percolate to the aquifer can be significant, greater than 3 ??Gal, when water is held in the root zone during brief periods following extreme rates of precipitation. Monitor-ing of storage change using gravity methods at wells also can improve understanding of local hydrogeologic conditions. In the study area, confined aquifer conditions are likely at three wells where large water-level variations were accompanied by little gravity change. Unconfined conditions were indicated at 15 wells where significant water-level and gravity change were positively linearly correlated. Good positive linear correlations resulted in extremely large specific-yield values, greater than 0.35, at seven wells where it is likely that significant ephemeral streamflow infiltration resulted in unsaturated storage change. Poor or negative linear correlations indicate the occurrence of confined, multiple, or perched aquifers. Monitoring of a multiple compressible aquifer system at one well resulted in negative correlation of rising water levels and subsidence-corrected gravity change, which suggests that water-level trends at the well are not a good indicatior of overall storage change. ?? 2008 Society of Exploration Geophysicists. All rights reserved.

  2. The quality of our Nation's waters: Water quality in basin-fill aquifers of the southwestern United States: Arizona, California, Colorado, Nevada, New Mexico, and Utah, 1993-2009

    Thiros, Susan A.; Paul, Angela P.; Bexfield, Laura M.; Anning, David W.


    The Southwest Principal Aquifers consist of many basin-fill aquifers in California, Nevada, Utah, Arizona, New Mexico, and Colorado. Demands for irrigation and drinking water have substantially increased groundwater withdrawals and irrigation return flow to some of these aquifers. These changes have increased the movement of contaminants from geologic and human sources to depths used to supply drinking water in several basin-fill aquifers in the Southwest.

  3. Manifestation of pernicious anaemia as hyperpigmentation of palms and soles

    Srinivas Vaddadi


    Full Text Available Vitamin B12 deficiency produces various manifestations involving CNS, heart, skin, blood and female reproductive systems. It is seen most commonly in the older individuals, malabsorptive states and #8201;(>60% of all cases and vegetarians. Pernicious anaemia may be confused to Addison's disease as both may present with similar clinical features. Hereby we report a case of pernicious anaemia presenting with dermatological manifestation in the form of deep pigmentation of both palms of and both soles respectively, cortisol levels normal so Addition's disease ruled out. [Int J Res Med Sci 2016; 4(5.000: 1746-1748

  4. Eclissi! Quando Sole e Luna danno spettacolo in cielo

    Bastoni, Marco


    Le eclissi di Sole e di Luna sono fra gli spettacoli più avvincenti della Natura; questo libro è una guida completa alla loro osservazione e spiega come cercare, vivere e fotografare questi eventi senza necessariamente essere astrofili esperti. Cosa posso osservare durante un’eclisse? Da dove? E quando? Un’accurata selezione delle 10 eclissi imperdibili da qui al 2050 chiude l’opera, aiutando il lettore nella pianificazione delle osservazioni. Preparate i bagagli, guardate l’eclisse e lasciatevi emozionare!

  5. [Fibromatosis plantaris Ledderhose (Dupuytren's contracture of the foot sole].

    Villiger, K J


    Fibromatosis plantaris, also called Ledderhose disease, is presented on the basis of the limited literature available. The possible causes are mentioned. Two cases are reported of patients suffering from fibromatosis palmaris (Dupuytren) on both hands and fibromatosis plantaris (Ledderhose) on both feet simultaneously. It is suggested that more attention be paid to examination of the soles of the feet, especially after a period of immobilization and plaster fixation of the shank. On diagnosis of Ledderhose disease, surgery should be performed before the often irreversible deformation of the toes develops.

  6. Polyhydroxyalkanoates of Different Structure Synthesized by Activated Sludge with Acetate and Propionate as Sole Carbon Source%以乙酸钠、丙酸钠为碳源的活性污泥合成聚羟基脂肪酸酯的结构分析

    林东恩; 张逸伟; 孙东成; 沈家瑞


    聚羟基脂肪酸酯(Polyhydroxyalkanoates, PHAs)是临时储藏于活性污泥的微生物体内的能量和碳源聚合物,是完全可生物降解的热塑性塑料.为了研究碳源对PHAs结构的影响,本文采用乙酸钠、丙酸钠为碳源在厌氧条件下培养活性污泥得到2种不同的PHAs样品,通过1H NMR、13C NMR和GC-MS谱图确定其组成和比例:以乙酸钠培养活性污泥得到PHAs样品的单体组成以3-羟基丁酸酯(3-hydroxybutyrate,3HB)为主,x(3HB)/x(3HV)(3-hydroxyvalerate,3-羟基戊酸酯)为93.91∶6.09;以丙酸钠培养活性污泥得到PHAs样品的单体组成主要以3HV为主,除3HB、3HV外,另外还有2-甲基-3-羟基丁酸酯(2-methyl-3-hydroxybutyrate,2M3HB)和2-甲基-3-羟基戊酸酯(2-methyl-3-hydroxyvalerate,2M3HV), 3HB/3HV/2M3HB/2M3HV的摩尔比为28.66∶63.13∶2.55∶5.66.由此可见采用不同碳源培养活性污泥所得到的PHAs的单体组成是不同的.%Polyhydroxyalkanoates(PHAs) are Polyesters synthesized by numerous bacteria in sludge as intracellular carbon and energy storage compounds under the condition of unbalance growth. Another important aspect of PHAs is thermoplastic polyester with the remarkable characteristics of biodegradability. In this paper, in order to research the relations of carbon sources to structure of PHAs, using acetate(Ⅰ) and propionate(Ⅱ) as the unique carbon source, two kinds of PHAs samples were obtained by assimilated sludge as PHAs synthesis strains in the anaerobic process. Their structures were determined by 1H NMR 13C NMR and GC-MS. When the carbon source was acetate, the unit composition of PHAs was 93.91%(mole fraction,x) 3-hydroxybutyrate (3HB) and x=6.09% 3-hydroxyvalerate(3HV); When the carbon source was propionate, the unit composition of PHAs was x=28.66% 3HB, x=63.13% 3HV, x=2.55% 2-methy-3-hydroxybutyrate(2M3HB) and x=5.66% 2-methyl-3-hydroxyvalerate(2M3HV). It showed that PHAs obtained by activated sludge with different carbon sources

  7. Sustainable yields from large diameter wells in shallow weathered aquifers

    Rushton, K. R.; de Silva, C. S.


    Large diameter wells in shallow weathered aquifers provide a valuable source of water for domestic and agricultural purposes in many locations including the Indian subcontinent. However, when used for irrigation, these wells often fail towards the end of the dry season. By considering two case studies in the dry and intermediate rainfall zones of Sri Lanka, reasons for the limited yield of these wells are identified. The first case study is concerned with a sloping catchment; a significant proportion of the precipitation during the rainy season either becomes runoff or passes down-gradient through the aquifer and is discharged at the ground surface. Furthermore, during the dry season, groundwater discharge continues. In the second case study the topography is generally flat but, even though the aquifer fills most years during the rainy season, there is often only sufficient water to irrigate about half of each farmer's holding. These investigations are based on field information and the development of conceptual and computational models. Of critical importance in assessing the long term yield of a well is the formation of a seepage face on the side of the well, with the water table a significant distance above the pumping water level. Consequently the water table may only be lowered to about half the depth of the well. The paper concludes with recommendations for the exploitation of groundwater from shallow weathered aquifers to minimise the risk of failure during the dry season.

  8. Hot Spots and Persistence of Nitrate in Aquifers Across Scales

    Dipankar Dwivedi


    Full Text Available Nitrate-N (NO3 -- N is one of the most pervasive contaminants in groundwater. Nitrate in groundwater exhibits long-term behavior due to complex interactions at multiple scales among various geophysical factors, such as sources of nitrate-N, characteristics of the vadose zone and aquifer attributes. To minimize contamination of nitrate-N in groundwater, it is important to estimate hot spots (>10 mg/L of NO3 -- N, trends and persistence of nitrate-N in groundwater. To analyze the trends and persistence of nitrate-N in groundwater at multiple spatio-temporal scales, we developed and used an entropy-based method along with the Hurst exponent in two different hydrogeologic settings: the Trinity and Ogallala Aquifers in Texas at fine (2 km × 2 km, intermediate (10 km × 10 km and coarse (100 km × 100 km scales. Results show that nitrate-N exhibits long-term persistence at the intermediate and coarse scales. In the Trinity Aquifer, overall mean nitrate-N has declined with a slight increase in normalized marginal entropy (NME over each decade from 1940 to 2008; however, the number of hot spots has increased over time. In the Ogallala Aquifer, overall mean nitrate-N has increased with slight moderation in NME since 1940; however, the number of hot spots has significantly decreased for the same period at all scales.

  9. Classification of aquifer vulnerability using K-means cluster analysis

    Javadi, S.; Hashemy, S. M.; Mohammadi, K.; Howard, K. W. F.; Neshat, A.


    Groundwater is one of the main sources of drinking and agricultural water in arid and semi-arid regions but is becoming increasingly threatened by contamination. Vulnerability mapping has been used for many years as an effective tool for assessing the potential for aquifer pollution and the most common method of intrinsic vulnerability assessment is DRASTIC (Depth to water table, net Recharge, Aquifer media, Soil media, Topography, Impact of vadose zone and hydraulic Conductivity). An underlying problem with the DRASTIC approach relates to the subjectivity involved in selecting relative weightings for each of the DRASTIC factors and assigning rating values to ranges or media types within each factor. In this study, a clustering technique is introduced that removes some of the subjectivity associated with the indexing method. It creates a vulnerability map that does not rely on fixed weights and ratings and, thereby provides a more objective representation of the system's physical characteristics. This methodology was applied to an aquifer in Iran and compared with the standard DRASTIC approach using the water quality parameters nitrate, chloride and total dissolved solids (TDS) as surrogate indicators of aquifer vulnerability. The proposed method required only four of DRASTIC's seven factors - depth to groundwater, hydraulic conductivity, recharge value and the nature of the vadose zone, to produce a superior result. For nitrate, chloride, and TDS, respectively, the clustering approach delivered Pearson correlation coefficients that were 15, 22 and 5 percentage points higher than those obtained for the DRASTIC method.

  10. Characterization of flow dynamics and vulnerability in a coastal aquifer system.

    Murgulet, Dorina; Tick, Geoffrey R


    Traditional aquifer vulnerability techniques primarily rely on spatial property data for a region and are limited by their ability to directly or indirectly assess flow and transport processes occurring from the surface to depth within an aquifer system. The main objective of this study was to investigate groundwater vulnerability in terms of aquifer interconnectivity and flow dynamics. A combination of stable isotopes, groundwater age-dating (radiocarbon), and geomorphic/geogenic spatial analyses was applied to a regional, highly developed coastal aquifer to explain the presence of nitrate at depth. The average δ(13) C value (-17.3 ± 2‰ VPDB, n = 27) is characteristic of groundwater originating from locally infiltrated precipitation through extensively cultivated soils. The average δ(18) O and δD values (-4.0 ± 0.1‰ VSMOW, n = 27; δD: -19.3 ± 1‰ VSMOW, n = 27, respectively) are similar to precipitation water derived from maritime sources feeding the region's surface water and groundwater. Stable and radioactive isotopes reveal significant mixing between shallow and deep aquifers due to high velocities, hydraulic connection, and input of local recharge water to depths. Groundwater overdevelopment enhances deeper and faster modern water downward flux, amplifying aquifer vulnerability. Therefore, aquifer vulnerability is a variable, dependent on the type and degree of stress conditions experienced by a groundwater system as well as the geospatial properties at the near surface.

  11. Provision of Desalinated Irrigation Water by the Desalination of Groundwater within a Saline Aquifer

    David D. J. Antia


    Full Text Available Irrigated land accounts for 70% of global water usage and 30% of global agricultural production. Forty percent of this water is derived from groundwater. Approximately 20%–30% of the groundwater sources are saline and 20%–50% of global irrigation water is salinized. Salinization reduces crop yields and the number of crop varieties which can be grown on an arable holding. Structured ZVI (zero valent iron, Fe0 pellets desalinate water by storing the removed ions as halite (NaCl within their porosity. This allows an “Aquifer Treatment Zone” to be created within an aquifer, (penetrated by a number of wells (containing ZVI pellets. This zone is used to supply partially desalinated water directly from a saline aquifer. A modeled reconfigured aquifer producing a continuous flow (e.g., 20 m3/day, 7300 m3/a of partially desalinated irrigation water is used to illustrate the impact of porosity, permeability, aquifer heterogeneity, abstraction rate, Aquifer Treatment Zone size, aquifer thickness, optional reinjection, leakage and flow by-pass on the product water salinity. This desalination approach has no operating costs (other than abstraction costs (and ZVI regeneration and may potentially be able to deliver a continuous flow of partially desalinated water (30%–80% NaCl reduction for $0.05–0.5/m3.

  12. Geohydrology of the shallow aquifers in the Denver metropolitan area, Colorado

    Robson, Stanley G.


    The Denver metropolitan area is underlain by shallow layers of water-bearing sediments (aquifers) consisting of unconsolidated gravel, sand, silt, and clay. The depth to water in these aquifers is less than 20 feet in much of the area, and the aquifers provide a ready source of water to numerous shallow, small-capacity wells. The shallow depth to water also makes the aquifers susceptible to contamination from the land surface. Water percolating downward from residential, commercial, and industrial property, spills of hazardous materials, and leaks from underground storage tanks and pipelines can cause contaminants to enter the shallow aquifers. Wet basements, unstable foundation materials, and waterlogged soils also are common in areas of very shallow ground water.Knowledge of the extent, thickness, and water-table altitude of the shallow aquifers is incomplete. This, coupled with the complexity of development in this large metropolitan area, makes effective use, management, and protection of these aquifers extremely difficult. Mapping of the geologic and hydrologic characteristics of these aquifers would provide the general public and technical users with information needed to better use, manage, and protect this water resource. A study to map the geohydrology of shallow aquifers in the Denver metropolitan area was begun in 1994. The work was undertaken by the U.S. Geological Survey in cooperation with the U.S. Army-Rocky Mountain Arsenal, U.S. Department of Energy-Rocky Flats Field Office, Colorado Department of Public Health and Environment, Colorado Department of Natural Resources-State Engineers Office, Denver Water Department, Littleton-Englewood Wastewater Treatment Plant, East Cherry Creek Valley Water and Sanitation District, Metro Wastewater Reclamation District, Willows Water District, and the cities of Aurora, Lakewood, and Thornton.This report presents the results of a systematic mapping of the extent, thickness, and water-table altitude of the shallow

  13. Urban heat islands in the subsurface as sustainable source for geothermal energy

    Menberg, Kathrin; Bayer, Peter; Blum, Philipp


    The urban heat island (UHI) is not a phenomenon that solely occurs in the atmosphere with increased air temperatures. We also observe it in the subsurface, and groundwater temperatures in shallow aquifers are strongly influenced by anthropogenic land surface alterations. Widespread thermal anomalies, which are triggered by various processes, such as increased ground surface temperatures (GST) and heat loss from buildings, can be found under many urban areas. With groundwater temperatures elevated by several degrees these aquifers represent large amounts of stored thermal energy. However, to exploit these attractive geothermal reservoirs efficiently and sustainably, the processes, which lead to the profound subsurface urban warming, need to be identified and quantified. In the current study, the spatial extension of the heat anomalies beneath several German cities, such as Berlin, Munich, Karlsruhe and Cologne, is scrutinized by mapping groundwater temperatures in a dense network of observation wells. With the high-resolved spatial distribution of groundwater temperatures, the dominant heat sources and important driving factors can be identified and incorporated into an analytical heat flux model. The annual anthropogenic heat input into the aquifer originating from several heat sources, such as increased GST, basements, sewage networks, district heating networks and reinjections of thermal waste water, is estimated by a Monte Carlo simulation for the cities of Cologne and Karlsruhe. All studied cities exhibit aquifers with significantly elevated temperatures, with the highest temperatures of up to 18°C prevailing in the densely built-up city centers. But also in suburban and industrial areas groundwater temperatures are several degrees above the rural background. The accumulated heat content in the urban aquifers can be estimated based on the thermal ground properties. This content is compared to the annual space heating demand in order to analyze the space

  14. Lyme disease: sudden hearing loss as the sole presentation.

    Espiney Amaro, C; Montalvão, P; Huins, C; Saraiva, J


    Lyme disease is an uncommon tick-borne multisystemic infection caused by Borrelia burgdorferi. The most common clinical manifestation is erythema migrans. In this report, a very unusual presentation of this condition is described, in which sudden onset sensorineural hearing loss was the sole presenting symptom. Case report and review of English-language literature. A patient presented with sensorineural hearing loss, with no other symptoms or signs. Acute Lyme infection was detected by laboratory tests. Magnetic resonance imaging showed signs of labyrinthitis of the same inner ear. After hyperbaric oxygen and systemic antibiotic treatment, the patient showed total hearing recovery, and magnetic resonance imaging showed complete resolution of the labyrinthitis. To our knowledge, this is the first reported case of Lyme disease presenting only with sensorineural hearing loss. Borreliosis should be considered as an aetiological factor in sensorineural hearing loss. Adequate treatment may provide total recovery and prevent more severe forms of Lyme disease.

  15. Thiobacter subterraneus gen. nov., sp. nov., an obligately chemolithoautotrophic, thermophilic, sulfur-oxidizing bacterium from a subsurface hot aquifer.

    Hirayama, Hisako; Takai, Ken; Inagaki, Fumio; Nealson, Kenneth H; Horikoshi, Koki


    A novel, thermophilic, obligately chemolithoautotrophic, sulfur/thiosulfate-oxidizing bacterium was isolated from subsurface geothermal aquifer water (temperature approximately 70 degrees C) in the Hishikari gold mine, Japan. Cells of the isolate, designated strain C55T, were motile, straight rods with a single polar flagellum. Growth was observed at temperatures between 35 and 62 degrees C (optimum 50-55 degrees C; 60 min doubling time) and pH between 5.2 and 7.7 (optimum pH 6.5-7.0). High growth rate of strain C55T was observed on either thiosulfate or elemental sulfur as a sole energy source, with molecular oxygen as the only electron acceptor. None of the organic compounds tested supported or stimulated growth of strain C55T. The G+C content of the genomic DNA was 66.9 mol%. Phylogenetic analysis based on 16S rRNA gene sequences indicated that strain C55T was affiliated to the beta-Proteobacteria, but was distantly related to recognized genera. On the basis of its physiological and molecular properties, strain C55T (=JCM12421T=DSM 16629T=ATCC BAA-941T) is proposed as the type strain of Thiobacter subterraneus gen. nov., sp. nov.

  16. A new aquifer assessment tool using reactive tracers

    McKnight, D.; Smalley, A. L.; Banwart, S. A.; Lerner, D. N.; Thomson, N. R.; Thornton, S. F.; Wilson, R. D.


    A major obstacle to making informed decisions about trigger levels for restoration and choosing remediation options is that current Site Investigation (SI) practice fails to make optimal use of available SI techniques resulting in poor value for money in conceptual site models. Often it is simply too expensive to obtain the type of site data required to build the case for natural attenuation, even though this restoration option may be relatively cheaper than a pump-and-treat system. In particular, aquifer property measurement techniques for groundwater transport and reactions are too costly and this results in over-reliance on literature values or model assumptions. This results in overly uncertain predictions of in situ performance and therefore unnecessarily cautious risk assessment and costly remediation strategies. Therefore, cost-effective SI tools that have the capability of producing high quality characterisation data are required. The dipole flow test which circulates groundwater between isolated injection (source) and extraction (sink) chambers within a single borehole has been used successfully by others to delineate heterogeneous hydraulic properties in both highly permeable and fractured rock aquifers. We propose to extend this approach by adding a suite of reactive tracers into a dipole flow field to assess the geochemical properties and biodegradation potential of aquifers. If successful this will provide a method to ascertain site-specific parameters for use in appropriate reactive transport models. The initial phase of this project involves the construction of a laboratory-scale physical model of a dipole probe to investigate the utility of the dipole flow and reactive tracer test (DFRTT) as an aquifer assessment tool. This phase will also serve as the developmental stage between mathematical theory and a host of planned field trials. The development of the laboratory-scale DFRTT including initial scoping calculations, numerical simulation results

  17. Poroelastic responses of confined aquifers to subsurface strain changes and their use for volcano monitoring

    K. Strehlow


    Two different aquifers are invoked – an unconsolidated pyroclastic deposit and a vesicular lava flow – and embedded in an impermeable crust, overlying a magma chamber. The time-dependent, fully coupled models simulate crustal deformation accompanying chamber pressurisation and the resulting hydraulic head changes as well as porous flow in the aquifer. The simulated deformational strain leads to centimetres (pyroclastic aquifer to meters (lava flow aquifer of hydraulic head changes; both strain and hydraulic head change with time due to substantial porous flow in the hydrological system. Well level changes are particularly sensitive to chamber volume and shape, followed by chamber depth and the phase of the pore fluid. The Young's Modulus and permeability of the aquifer, as well as the strength of pressurisation also have significant influence on the hydraulic head signal. While source characteristics, the distance between chamber and aquifer and the elastic stratigraphy determine the strain field and its partitioning, flow and coupling parameters define how the aquifer responds to this strain and how signals change with time. We investigated a period of pre-eruptive head changes recorded at Usu volcano, Japan, where well data were interpreted using an analytical deformation model. We find that generic analytical models can fail to capture the complex pre-eruptive subsurface mechanics leading to well level changes, due to aquifer pressure changes being sensitive to chamber shape and lithological heterogeneities. In addition, the presence of a pore fluid and its flow have a significant influence on the strain signal in the aquifer and are commonly neglected in analytical models. These findings highlight the need for numerical models for the interpretation of observed well level signals. However, simulated water table changes do mirror volumetric strain and wells can therefore serve as comparatively cheap strain meters that could provide important insights into

  18. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries created for a previously published report about the Central Oklahoma aquifer in central Oklahoma. This area...

  19. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of Blaine, Caddo,...

  20. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Elk City aquifer in western Oklahoma. The aquifer covers an area of...

  1. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately...

  2. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace aquifer...

  3. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries of the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone is an important...

  4. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately 193,000...

  5. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digital aquifer boundaries for the High Plains aquifer in western Oklahoma. This area encompasses the panhandle counties of Cimarron,...

  6. Alpine Groundwater - Pristine Aquifers Under Threat?

    Schneider, P.; Lange, A.


    Glacier and permafrost retreat are prominent climate change indicators. However, the characteristics of climate and hydrology in mountain areas remain poorly understood relative to lowland areas. Specifically, not much is known about alpine groundwater, its recharge and water quality variations, as these remote reservoirs are rarely monitored. As global temperatures rise, glaciers and permafrost will continue to retreat forming new sediment deposits and changing infiltration conditions in high alpine terrain. Climate change impacts the hydro-chemical composition of alpine waters, accelerates weathering processes, and potentially triggers mobilization of pollutants. Accordingly, we monitored groundwater quantity and quality parameters of an alpine porous aquifer near the Tiefenbach glacier in the Gotthard Massif in Switzerland. The goal of this research was to assess quality and seasonal storage dynamics of groundwater above the timberline (2000 m). To translate hydrological science into an ecosystem service context, we focused on four attributes: Water quantity: observations of groundwater level fluctuations combined with analysis of contributing water sources based on stable isotope analysis to give a quantitative understanding of origin and amount of water, Water quality: groundwater level, groundwater temperature and electrical conductivity were used as proxies for sampling of hydro-chemical parameters with automated water samplers during primary groundwater recharge periods (snowmelt and rainfall events), Location: Alpine terrain above the timberline, especially recharge into/out of an alpine porous aquifer at a pro-glacial floodplain and Date of annual melt (albedo effect) and timing of flow (snow- and icemelt from May to September) and groundwater recharge during the growing season. The study found that the summer groundwater temperatures depend on the date of annual melt and are more sensitive to climate forcing than lowland groundwater temperatures

  7. Hydrogeochemical analysis for Tasuj plain aquifer, Iran

    Ata Allah Nadiri; Asghar Asghari Moghaddam; Frank T-C Tsai; Elham Fijani


    This study investigated the hydrogeochemical processes of groundwater in the Tasuj plain, Iran. The Tasuj plain is one of the 12 marginal plains around Urmia Lake which is currently under a critical ecological condition. In the last decades, the Tasuj plain aquifer suffered from severe groundwater level declination and caused degradation of groundwater quality. To better understand hydrogeochemical processes in the Tasuj plain, this study adopted graphical methods and multivariate statistical techniques to analyze groundwater samples. A total of 504 groundwater samples was obtained from 34 different locations (qanats, wells, and springs) over 12 years (1997–2009) and analyzed for 15 water quality parameters. From the results, the Piper diagram indicated four groundwater types and the Stiff diagram showed eight different sources of groundwater samples. The Durov diagram identified five major hydrogeochemical processes in the aquifer. However, hierarchical cluster analysis (HCA) identified five water types in the groundwater samples because HCA was able to analyze more chemical and physical data than graphical methods. The HCA result was checked by discriminant analysis and found consistency in all samples that were classified into correct groups. Using factor analysis, we identified three factors that accounted for 81.6% of the total variance of the dataset. Based on the high factor loadings of the variables, factors 1 and 2 reflected the natural hydrogeochemical processes and factor 3 explained the effect of agricultural fertilizers and human activities in the Tasuj plain. Dendrograms from 2000 to 2009 were studied to understand the temporal variation of groundwater quality. Comparing the distributions of groundwater types in 2000 and 2009, we found that the mixing zone was expanded. This may be due to artificial groundwater recharge in the recharge area and the effect of inverse ion exchange in the discharge area.

  8. The quality of our Nation's waters: water quality in the Northern Atlantic Coastal Plain surficial aquifer system, Delaware, Maryland, New Jersey, New York, North Carolina, and Virginia, 1988-2009

    Denver, Judith M.; Ator, Scott W.; Fischer, Jeffrey M.; Harned, Douglas C.; Schubert, Christopher E.; Szabo, Zoltan


    The surficial aquifer system of the Northern Atlantic Coastal Plain is made up of unconfined aquifers that underlie most of the area. This aquifer system is a critical renewable source of drinking water and is the source of most flow to streams and of recharge to underlying confined aquifers. Millions of people rely on the surficial aquifer system for public and domestic water supply, in particular in the densely populated areas of Long Island, New York, and in southern New Jersey, but also in more rural areas. Because the aquifer sediments are permeable and the water table is shallow, the surficial aquifer system is vulnerable to contamination from chemicals that are applied to the land surface and carried into groundwater with infiltrating rainfall and snowfall.

  9. Occurrence of volatile organic compounds in shallow alluvial aquifers of a Mediterranean region: Baseline scenario and ecological implications.

    Di Lorenzo, T; Borgoni, R; Ambrosini, R; Cifoni, M; Galassi, D M P; Petitta, M


    A regional survey of eight volatile organic compounds (VOCs), namely BTEX (benzene, toluene, ethylbenzene and p-xylene) and four chlorinated aliphatic hydrocarbons (CAHs: chloroform, 1,2-dichloroethane, trichloroethene and tetrachloroethene), was carried out at 174 sites, in 17 alluvial aquifers of Abruzzo, a Mediterranean region of southern Italy, from 2004 to 2009. Frequency of detection, concentration range, spatial distribution pattern, and temporal trend of contaminant concentration in each aquifer were analyzed as well as the relationships between VOC concentrations and the total amount of precipitation during the 90days preceding each sampling date. A review of published ecotoxicological data, providing an indication of the biological risk associated with the observed levels of VOC contamination, was presented and discussed. BTEX concentrations were under detection limits in all the investigated aquifers, indicating absence of contamination. In contrast, CAH contamination occurred in 14 out of 17 aquifers. The two most frequently detected compounds were chloroform and tetrachloroethene. No significant temporal trend was observed for chloroform and tetrachloroethene concentrations during the six years of observation, indicating the persistence of stable contaminations, except for some slightly decreasing trends observed in three out of 17 aquifers. In four aquifers chloroform and tetrachloroethene concentrations increased with precipitations in the preceding months. Spatial patterns of contamination differed among aquifers, indicating highly complex contaminant distributions at aquifer scale not related to single-plume geometries. Patterns of contamination by chloroform and tetrachloroethene in the most urbanized aquifers were likely associated with multiple sources of VOCs not clearly detectable at the scale used in this study. In five out of 17 aquifers, chloroform and tetrachloroethene co-occurred at concentrations that are lethal to groundwater

  10. Modeling of groundwater flow for Mujib aquifer, Jordan

    Fayez Abdulla; Tamer Al-Assa’d


    Jordan is an arid country with very limited water resources.Groundwater is the main source for its water supply.Mujib aquifer is located in the central part of Jordan and is a major source of drinking water for Amman,Madaba and Karak cities.High abstraction rates from Mujib aquifer during the previous years lead to a major decline in water levels and deterioration in groundwater quality. Therefore,proper groundwater management of Mujib aquifer is necessary;and groundwater flow modeling is essential for proper management.For this purpose,Mod flow was used to build a groundwater flow model to simulate the behavior of the flow system under different stresses.The model was calibrated for steady state condition by matching observed and simulated initial head counter lines.Drawdown data for the period 1985-1995 were used to calibrate the transient model by matching simulated drawdown with the observed one.Then,the transient model was validated by using drawdown data for the period 1996-2002.The results of the calibrated model showed that the horizontal hydraulic conductivity of the B2/A7 aquifer ranges between 0.001 and 40 m/d. Calibrated speci fic yield ranges from 0.0001 to 0.15.The water balance for the steady state condition of Mujib aquifer indicated that the total annual direct recharge is 20.4 × 106 m3, the total annual in flow is 13.0 × 106 m3, springs discharge is 15.3 × 106 m3, and total annual out flow is 18.7 × 106 m3. Different scenarios were considered to predict aquifer system response under different conditions. The results of the sensitivity analysis show that the model is highly sensitive to horizontal hydraulic conductivity and anisotropy and with lower level to the recharge rates.Also the model is sensitive to specific yield.

  11. Electrokinetically Enhanced Delivery for ERD Remediation of Chlorinated Ethenes in a Fractured Limestone Aquifer

    Broholm, Mette Martina; Hansen, Bente H.; With Nedergaard, Lærke;

    Leakage of the chlorinated solvents PCE and TCE into limestone aquifers from contaminated overburden and the long-lasting back diffusion from the secondary source in the limestone matrix pose a severe risk for contamination of drinking water resources. Dechlorination of PCE and TCE in limestone...... often accumulates cis-DCE due to incomplete dechlorination in the limestone aquifers, as observed downgradient of a PCE and TCE DNAPL source area at Naverland in Denmark. A microcosm study with limestone core material and groundwater from the Naverland site source area spiked with PCE showed...... that enhanced reductive dechlorination (ERD) by the addition of donor and specific degraders (KB1® culture) can lead to complete dechlorination of PCE and TCE in the limestone aquifer, provided sufficient contact between specific degraders, donor and specific degraders, is obtained. Advection-based delivery...

  12. Electrohydrodynamic flow caused by field-enhanced dissociation solely

    Vasilkov, S. A.; Chirkov, V. A.; Stishkov, Yu. K.


    Electrohydrodynamic (EHD) flows emerge in dielectric liquids under the action of the Coulomb force and underlie energy-efficient techniques for heat and mass transfer. The key issue in the phenomena is the way how the net charge is created. One of the most promising, yet poorly studied charge formation mechanisms is the field-enhanced dissociation (or the Wien effect). So the paper studies an EHD flow caused solely by the effect by virtue of both experiment and computer simulation. To preclude the competing mechanism of charge formation—the injection—a new EHD system of a special design was examined. Its main feature is the use of solid insulation to create the region of the strong electric field far from the electrode metal surfaces. The experimental study used the particle image velocimetry technique to observe velocity distributions, whereas the computations were based on the complete set of electrohydrodynamic equations employing the commercial software package COMSOL Multiphysics. Spatial distributions of key quantities (including the ion concentrations, the total space charge density, and the velocity) and the acting forces were obtained in the computer simulation and were analyzed. The experimental flow structure was observed for a number of voltages up to 30 kV. The comparison of the numerical and experimental results yielded a good quantitative agreement for strong electric fields though some overshoot was observed for weak ones. The results allow concluding on the applicability of the Onsager theory of the field-enhanced dissociation in the context of EHD flows.

  13. Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan

    Al Lawati, Wafa M. [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom); Higher College of Technology, Ministry of Manpower, Muscat (Oman); Jean, Jiin-Shuh [Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Kulp, Thomas R. [Department of Earth Sciences and Environmental Studies, State University of New York, Binghamton, NY (United States); Lee, Ming-Kuo [Department of Geology and Geography, Auburn University, Auburn, AL (United States); Polya, David A. [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom); Liu, Chia-Chuan [Department of Earth Sciences, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Dongen, Bart E. van, E-mail: [School of Earth, Atmospheric and Environmental Sciences, Williamson Research Centre for Molecular Environmental Science, University of Manchester, Manchester (United Kingdom)


    Highlights: ► First lipid analysis of Taiwanese aquifer sediments from groundwater As-prone region. ► Both plant-derived terrestrial and mature hydrocarbon lipid sources identified. ► Organic matter sources similar to those of other high As groundwater aquifers. ► Groundwater arsenic at depth controlled by biotic As mobilisation processes. ► Biotic As mobilisation not controlled by a specific source of analysed organic matter. -- Abstract: Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release.

  14. Digital data sets that describe aquifer characteristics of the Tillman terrace and alluvial aquifer in southwestern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digital aquifer boundaries for the Tillman terrace and alluvial aquifer in southwestern Oklahoma. The Tillman terrace aquifer encompasses...

  15. Water withdrawals and trends from the Floridan aquifer system in the southeastern United States, 1950-2000

    Marella, Richard L.; Berndt, Marian P.


    The Floridan aquifer system in the southeastern United States is one of the most productive aquifers in the world (Miller, 1990). This aquifer system underlies an area of about 100,000 square miles in southern Alabama, eastern and southern Georgia, southeastern Mississippi, southern South Carolina, and all of Florida. The Floridan aquifer system is the primary source of water for nearly 10 million people and supports agriculture, industry, and tourism throughout most of the region. In most areas, water from this aquifer is potable and needs very little treatment before use. However, in southern Florida (south of Lake Okeechobee), northwestern Florida and southern Alabama and Mississippi (Pensacola and westward), and eastern South Carolina, water in the aquifer system generally is not potable. The purpose of this report is to: Provide a general description of the Floridan aquifer system; Discuss water withdrawals by category for 2000; Highlight trends in water withdrawals between 1950 and 2000; and Provide a brief summary on the effects that human impacts have on the Floridan aquifer system.

  16. 78 FR 60875 - Assistant Secretary for Preparedness and Response; Notification of a Sole Source Cooperative...


    .... Measuring Individual Disaster Recovery: A Socioecological Framework. Disaster Medicine and Public Health..., Community Engagement, and Recovery in 21st Century Crises. Disaster Medicine and Public Health Preparedness... Serious Emotional Disturbance in Children After Hurricane Katrina. Disaster Medicine and Public...

  17. Study of a plugging microbial consortium using crude oil as sole carbon source

    Wang Jing; Yan Guiwen; An Mingquan; Liu Jieli; Zhang Houming; Chen Yun


    A microbial consortium named Y4 capable of producing biopolymers was isolated from petroleum-contaminated soil in the Dagang Oilfield, China. It includes four bacterial strains: Y4-1 (Paenibacillus sp.), Y4-2 (Actinomadura sp.), Y4-3 (Uncultured bacterium clone) and Y4-4 (Brevibacillus sp.). The optimal conditions for the growth of the consortium Y4 were as follows: temperature about 46 ℃,pH about 7.0 and salinity about 20.0 g/L. The major metabolites were analyzed with gas chromatographymass spectrometry (GC-MS). A comparison was made between individual strains and the microbial consortium for biopolymer production in different treatment processes. The experimental results showed that the microbial consortium Y4 could produce more biopolymers than individual strains, and the reason might be attributed to the synergetic action of strains. The biopolymers were observed with optical and electron microscopes and analyzed by paper chromatography. It was found that the biopolymers produced by the microbial consortium Y4 were insoluble in water and were of reticular structure, and it was concluded that the biopolymers were cellulose. Through a series of simulation experiments with sand cores, it was found that the microbial consortium Y4 could reduce the permeability of reservoir beds, and improve the efficiency of water flooding by growing biomass and producing biopolymers.The oil recovery was enhanced by 3.5% on average. The results indicated that the consortium Y4 could be used in microbial enhanced oil recovery and play an important role in bioremediation of oil polluted environments.

  18. Encystment of Azotobacter nigricans grown diazotrophically on kerosene as sole carbon source.

    García-Esquivel, Gabriela; Calva-Calva, Graciano; Ferrera-Cerrato, Ronald; Fernández-Linares, Luis Carlos; Vázquez, Refugio Rodríguez; Esparza-García, Fernando José


    Encystment of Azotobacter nigricans was induced by its diazotrophic cultivation on kerosene. Its growth and nitrogenase activity were affected by kerosene in comparison to cultures grown on sucrose. Electron microscopy of vegetative cells showed that when nitrogenase activity was higher and the poly-beta-hydroxybutyrate granules were not present to a significant extent, peripheral bodies were abundant. After 8 days of culture on kerosene, the presence of cysts with intracellular bunches of poly-beta-hydroxybutyrate granules was observed. Germination of cysts bears germinating multicelled yet unbroken capsule cysts with up to three cells inside. This is the first report of encystment induction of Azotobacter species grown on kerosene.

  19. 77 FR 23369 - Federal Acquisition Regulation; Justification and Approval of Sole-Source 8(a) Contracts


    ... contract action valuation practice is outlined in FAR 1.108(c), which provides that the final anticipated... (including potential economic, environmental, public health and safety effects, distributive impacts,...

  20. Soluble microbial products in pilot-scale drinking water biofilters with acetate as sole carbon source.

    Zhang, Ying; Ye, Chengsong; Gong, Song; Wei, Gu; Yu, Xin; Feng, Lin


    A comprehensive study on formation and characteristics of soluble microbial products (SMP) during drinking water biofiltration was made in four parallel pilot-scale ceramic biofilters with acetate as the substrate. Excellent treatment performance was achieved while microbial biomass and acetate carbon both declined with the depth of filter. The SMP concentration was determined by calculating the difference between the concentration of dissolved organic carbon (DOC), biodegradable dissolved organic carbon (BDOC) and acetate carbon. The results revealed that SMP showed an obvious increase from 0 to 100 cm depth of the filter. A rising specific ultraviolet absorbance (SUVA) was also found, indicating that benzene or carbonyl might exist in these compounds. SMP produced during this drinking water biological process were proved to have weak mutagenicity and were not precursors of by-products of chlorination disinfection. The volatile parts of SMP were half-quantity analyzed and most of them were dicarboxyl acids, others were hydrocarbons or benzene with 16-17 carbon atoms.

  1. 78 FR 54652 - Sole Source Cooperative Agreement Award to the Association for State and Territorial Health...


    ... health care, public health, and emergency management systems. This project aims to improve collaboration... health resilience, and strengthen health care, public health, and emergency management systems. One of the overarching goals of both the National Health Security Strategy (2009) and the ASPR Strategic...

  2. Hydrogeology of the Susquehanna River valley-fill aquifer system in the Endicott-Vestal area of southwestern Broome County, New York

    Randall, Allan D.; Kappel, William M.


    The village of Endicott, New York, and the adjacent town of Vestal have historically used groundwater from the Susquehanna River valley-fill aquifer system for municipal water supply, but parts of some aquifers in this urban area suffer from legacy contamination from varied sources. Endicott would like to identify sites distant from known contamination where productive aquifers could supply municipal wells with water that would not require intensive treatment. The distribution or geometry of aquifers within the Susquehanna River valley fill in western Endicott and northwestern Vestal are delineated in this report largely on the basis of abundant borehole data that have been compiled in a table of well records.

  3. The importance of some carbonate aquifers in the Guadalquivir river basin; Importancia de algunos acuiferos carbonatados representativos de la cuenca del Guadalquivir

    Pulido Boch, A.; Lopez Chicano, M.


    Carbonate aquifers play an important role in the Guadalquivir river basin, although, until present days, there are very few wells exploiting them. We can distinguish two kinds of carbonate aquifers: fissurated and karstic. In the first group, we consider the Alpujarride carbonates from the western Sierra Nevada- Alfaguara border; in the second, the most important are: Cazorla and Segura Sierras-source of the Guadalquivir river- and Sierra Gorda. The main hydrogeological characteristics of these aquifers are described and we make some reflexions about the role that the aquifers can play in the total resources of the basin. (Author)


    IONESCU Cozmin


    Full Text Available Design methods of soles and soles injection moulds must be accurate, timely and at the same time, accessible to a wide category of soles and injection moulds designers and manufacturers. For designing soles and injection moulds for soles, various dedicated CAD/CAM systems have been developed, such as: Delcam Shoe Solution (3D, Delcam PowerSHAPE-e (2D and 3D, Padsy II (2D and Padsy III (3D, Shoemaster System (2D and 3D, Lectra System (2D and 3D, Parmel System (2D and ATOS II System (3D. These systems are equipped with colour displays, plotters, digitizers, terminals and other equipment dedicated for computer aided design activities. Designing 3D soles models using computer systems enables the prevention of ambiguities inherited from 2D drawings, thus reducing errors and remanufacturing. Depending on the design complexity of soles, the technical means available for copying shoe soles and the technologies at the disposal of the soles manufacturers, soles and injection moulds designers adopt various design methods. Not all CAD/CAM systems are accessible for all users, because often their purchasing costs are high. Design method developed and presented in this paper, uses Delcam PowerSHAPE software program, which has the advantage that it can be accessed free of charge from the manufacturer's website. At the same time, this software program provides the user with all the necessary tools and instruments needed to design the most complex injection moulds and footwear sole.

  5. Use of molecular approaches in hydrogeological studies: the case of carbonate aquifers in southern Italy

    Bucci, Antonio; Petrella, Emma; Celico, Fulvio; Naclerio, Gino


    Waterborne pathogens represent a significant health risk in both developed and developing countries with sensitive sub-populations including children, the elderly, neonates, and immune-compromised people, who are particularly susceptible to enteric infections. Annually, approximately 1.8 billion people utilize a faecally contaminated water source, and waterborne diseases are resulting in up to 2.1 million human mortalities globally. Although groundwater has traditionally been considered less susceptible to contamination by enteric pathogens than surface water due to natural attenuation by overlying strata, the degree of microbial removal attributable to soils and aquifers can vary significantly depending on several factors. Thus, accurate assessment of the variable presence and concentration of microbial contaminants, and the relative importance of potentially causative factors affecting contaminant ingress, is critical in order to develop effective source (well) and resource (aquifer) protection strategies. "Traditional" and molecular microbiological study designs, when coupled with hydrogeological, hydrochemical, isotopic, and geophysical methods, have proven useful for analysis of numerous aspects of subsurface microbial dynamics. Accordingly, this overview paper presents the principal microbial techniques currently being employed (1) to predict and identify sources of faecal contamination in groundwater, (2) to elucidate the dynamics of contaminant migration, and (3) to refine knowledge about the hydrogeological characteristics and behaviours of aquifer systems affected by microbial contamination with an emphasis on carbonate aquifers, which represent an important global water supply. Previous investigations carried out in carbonate aquifers in southern Italy are discussed.

  6. Continuous biogas production from fodder beet silage as sole substrate

    Scherer, P.A.; Dobler, S.; Rohardt, S. [University of Applied Sciences, Hamburg (Germany). Research Centre of Environmental Bioengineering and Applied Biotechnology; Loock, R.; Buettner, B.; Noeldeke, P.; Brettschuh, A. [Loock Environmental Technologies, Hamburg (Germany)


    Since April 2000 a two-step anaerobic plant with two subsequent 500 m{sup 3} reactors has been producing biogas from fodder beet silage (pH 4.1) as the sole substrate. The plant is located at Kirchlengern near Bielefeld, Germany. Initially the reactors were inoculated with swine manure at 37{sup o}C. After a start-up phase the process was sustained at pH 7.5-8.0 by feeding with the silage as sole substrate twice a day. Parallel to the biogas plant at Kirchlengern four one-step laboratory reactors were continuously driven at temperatures of 37{sup o}C, 45{sup o}C, 60{sup o}C and 65{sup o}C. They were fed with the same silage, but only once per day (one impulse). The organic loading rate (OLR) was adjusted to 3.9 g volatile solids (VS)/(l*d) with a concomitant hydraulic retention time (HRT) of 27 d. There was no problem with starting the reactors, but after 86 days the volumetric gas production of the 65{sup o}C reactor ceased and a high amount of approximately 130 mM propionate could be determined. By decreasing the temperature down to 60{sup o}C a stable reactor performance was recovered for a period of at least 250 further days. During impulse feeding it was observed that the quickest recovery of gas production could be observed at 37{sup o}C or at 45{sup o}C. Recovery of 75% gas volume (related to the value before or after impulse feeding) was obtained after 5.5 and 7.5 h of feeding time point whereas the 60{sup o}C reactor needed 16 h. Slight significant differences were seen in the spectrum of volatile fatty acids (VFA) reaching at 37{sup o} or 45{sup o}C its maximum with 10-30 mM total VFA at 2-3 h after feeding. After this the VFA level declined to nearly zero (except for the 60{sup o}C reactor). Therefore the 37{sup o}C reactor was favoured. A double experiment with a second 37{sup o}C reactor was started by a somewhat different inoculation procedure from the remaining 3 reactors, but revealed similar results. By increasing the temperature no significantly

  7. Dynamics of natural contamination by aluminium and iron rich colloids in the volcanic aquifers of Central Italy.

    Viaroli, Stefano; Cuoco, Emilio; Mazza, Roberto; Tedesco, Dario


    The dynamics of natural contamination by Al and Fe colloids in volcanic aquifers of central-southern Italy were investigated. Localized perched aquifers, and their relative discharges, are strongly affected by the presence of massive suspended solids, which confer a white-lacteous coloration to the water. This phenomenon occasionally caused the interruption of water distribution due to the exceeding of Al and Fe concentrations in aquifers exploited for human supply. The cause was ascribed to water seepage from perched aquifers. Water discharges affected by such contamination was investigated for the Rocca Ripesena area (north-eastern sector of Vulsini Volcanic District) and for the Rianale Stream Valley (Roccamonfina Volcanic Complex). Hydrogeological survey of both areas confirmed the presence of perched aquifers not previously considered due to their low productivity. Pluviometric data and chemical parameters were periodically monitored. Water mineralization decreased with increasing rainfall, conversely Al and Fe concentrations increased. Statistical analysis confirmed the dependence of all the chemical variables on rock leaching, with the sole exception of Al and Fe which were imputed to colloids mobilization from local, strongly pedogenized pyroclastic material. The similarities in hydrogeological settings and mobilization dynamics in both areas suggest that the Al and Fe colloidal contamination should be more abundant than currently known in quaternary volcanic areas.

  8. The recharge process in alluvial strip aquifers in arid Namibia and implication for artificial recharge

    Sarma, Diganta; Xu, Yongxin


    Alluvial strip aquifers associated with ephemeral rivers are important groundwater supply sources that sustain numerous settlements and ecological systems in arid Namibia. More than 70 % of the population in the nation's western and southern regions depend on alluvial aquifers associated with ephemeral rivers. Under natural conditions, recharge occurs through infiltration during flood events. Due to the characteristic spatial and temporal variability of rainfall in arid regions, recharge is irregular making the aquifers challenging to manage sustainably and they are often overexploited. This condition is likely to become more acute with increasing water demand and climate change, and artificial recharge has been projected as the apparent means of increasing reliability of supply. The article explores, through a case study and numerical simulation, the processes controlling infiltration, significance of surface water and groundwater losses, and possible artificial recharge options. It is concluded that recharge processes in arid alluvial aquifers differ significantly from those processes in subhumid systems and viability of artificial recharge requires assessment through an understanding of the natural recharge process and losses from the aquifer. It is also established that in arid-region catchments, infiltration through the streambed occurs at rates dependent on factors such as antecedent conditions, flow rate, flow duration, channel morphology, and sediment texture and composition. The study provides an important reference for sustainable management of alluvial aquifer systems in similar regions.

  9. Identifying and characterizing transboundary aquifers along the Mexico-US border: An initial assessment

    Sanchez, Rosario; Lopez, Victoria; Eckstein, Gabriel


    The transboundary nature of water dividing Mexico and the United States (U.S.) transforms the entire border region into an instrument of cooperation, a source of conflict, a national security issue, and an environmental concern. Reasonable data collection and research analysis have been conducted for surface waters by joint governmental institutions and non-governmental bodies. However, with the exception of the U.S. Transboundary Assessment Act Program (TAAP) (focusing on the Hueco Bolson, Mesilla Bolson, San Pedro and Santa Cruz aquifers), there is no comparable research, institutional development, or assessment of transboundary groundwater issues on the frontier. Moreover, data collection and methodologies vary between the two countries, there is no broadly accepted definition of the transboundary nature of an aquifer, and available legal and policy frameworks are constrained by non-hydrological considerations. Hence, there is a conceptual and institutional void regarding transboundary groundwater resources between Mexico and the U.S. The purpose of this paper is to bridge this void and characterize transboundary aquifers on the Mexico-US border. It reviews existing international frameworks for identifying hydrological and social criteria that characterize an aquifer as transboundary. It then assesses data from both countries to propose where and which aquifers could be considered transboundary. Finally, the paper proposes an agenda for assessing Mexico-US transboundary aquifers as a means for improving groundwater management in the border region.

  10. Oil-in-oil emulsions stabilised solely by solid particles.

    Binks, Bernard P; Tyowua, Andrew T


    A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles. Close to inversion, emulsions are stable to coalescence and gravity-induced separation for at least one year. Increasing the viscosity of the silicone oil enables stable S/V emulsions to be prepared even with relatively hydrophilic particles. Predictions of emulsion type from calculated contact angles of a silica particle at the oil-oil interface are in agreement with experiment provided a small polar contribution to the surface energy of the oils is included. We also show that stable multiple emulsions of V/S/V can be prepared in a two-step procedure using two particle types of different hydrophobicity. At fixed particle concentration, catastrophic phase inversion of emulsions from V/S to S/V can be effected by increasing the volume fraction of vegetable oil. Finally, in the case of sunflower oil + 20 cS PDMS, the study is extended to particles other than silica which differ in chemical type, particle size and particle shape. Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers.

  11. Overview of the Ogallala Aquifer Program

    Irrigation increased markedly on the Southern High Plains during the second half of the 20th century, drawing water primarily from the Ogallala Aquifer. During this time, irrigation sustained regional farm incomes and rural economies. Withdrawals from the aquifer, however, have exceeded recharge, re...

  12. Geohydrology of the Cerro Prieto geothermal aquifer

    Sanchez R, J.; de la Pena L, A.


    The most recent information on the Cerro Prieto geothermal aquifer is summarized, with special emphasis on the initial production zone where the wells completed in the Alpha aquifer are located. These wells produce steam for power plant units 1 and 2. Brief comments also are made on the Beta aquifer, which underlies the Alpha aquifer in the Cerro Prieto I area and which extends to the east to what is known as the Cerro Prieto II and Cerro Prieto III areas. The location of the area studied is shown. The Alpha and Beta aquifers differ in their mineralogy and cementing mineral composition, temperatures, and piezometric levels. The difference in piezometric levels indicates that there is no local communication between the two aquifers. This situation has been verified by a well interference test, using well E-1 as a producer in the Beta aquifer and well M-46 as the observation well in the Alpha aquifer. No interference between them was observed. Information on the geology, geohydrology, and geochemistry of Cerro Prieto is presented.

  13. The University of Minnesota aquifer thermal energy storage (ATES) field test facility -- system description, aquifer characterization, and results of short-term test cycles

    Walton, M.; Hoyer, M.C.; Eisenreich, S.J.; Holm, N.L.; Holm, T.R.; Kanivetsky, R.; Jirsa, M.A.; Lee, H.C.; Lauer, J.L.; Miller, R.T.; Norton, J.L.; Runke, H. (Minnesota Geological Survey, St. Paul, MN (United States))


    Phase 1 of the Aquifer Thermal Energy Storage (ATES) Project at the University of Minnesota was to test the feasibility, and model, the ATES concept at temperatures above 100{degrees}C using a confined aquifer for the storage and recovery of hot water. Phase 1 included design, construction, and operation of a 5-MW thermal input/output field test facility (FTF) for four short-term ATES cycles (8 days each of heat injection, storage, and heat recover). Phase 1 was conducted from May 1980 to December 1983. This report describes the FTF, the Franconia-Ironton-Galesville (FIG) aquifer used for the test, and the four short-term ATES cycles. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are all included. The FTF consists of monitoring wells and the source and storage well doublet completed in the FIG aquifer with heat exchangers and a fixed-bed precipitator between the wells of the doublet. The FIG aquifer is highly layered and a really anisotropic. The upper Franconia and Ironton-Galesville parts of the aquifer, those parts screened, have hydraulic conductivities of {approximately}0.6 and {approximately}1.0 m/d, respectively. Primary ions in the ambient ground water are calcium and magnesium bicarbonate. Ambient temperature FIG ground water is saturated with respect to calcium/magnesium bicarbonate. Heating the ground water caused most of the dissolved calcium to precipitate out as calcium carbonate in the heat exchanger and precipitator. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water, suggesting dissolution of some constituents of the aquifer during the cycles. Further work on the ground water chemistry is required to understand water-rock interactions.

  14. Possible Processes For Acidity And Metal Contaminant Attenuation In A Polluted Estuarine Aquifer

    Patrick, E.; Xiaomin, M.; Andrew, B.; Ling, L.; Andrew, B.


    Geochemical data obtained from an estuarine sandy aquifer situated below an old industrial landfill (Ayrshire, Scotland) indicated that acidic groundwater (pH acidic plume, elevated concentrations of dissolved heavy metals (Al, Zn, Cu, Cr, Cd) were observed. Water table monitoring and chemical data showed that the groundwater is intruded by estuarine water and is tidally influenced. While geochemical processes associated with acidic plumes and related metal contamination have been widely studied in inland aquifer systems, they have received much less attention in near shore aquifers. Rarely have processes taking place in tidally influenced acidic aquifers been investigated in detail in the field. The aim of the study was to identify the key processes controlling the migration of the acidic plume and reactive transport of contaminants on the path from the aquifer to the estuary. More specifically, the research work has focused on the role played by estuarine water intrusion on the geochemical processes occurring in the aquifer. Through integration of intense geophysical, hydrogeological and hydrogeochemical Investigations, a comprehensive field-monitoring program and laboratory experiments have been carried out. Data obtained were analysed using a geochemical modelling code, PHREEQC-2. In parallel, a model for multi-components reactive transport with density dependent flow was developed and applied to the site. Results from the field, laboratory, and modelling work indicated that oxidation of sulphurous waste located in the landfill at the pollution source is the origin of the groundwater acidity. The low pH plume and associated contaminants are slowly migrating towards the estuary. Retardation of the plume and pH buffering processes are clearly occurring in the aquifer. Ion exchange, precipitation, buffering mineral dissolution, and tidal forcing on the advective-dispersive transport were identified as the main factors influencing contaminant migration and

  15. Arsenic attenuation by oxidized aquifer sediments in Bangladesh

    Stollenwerk, K.G.; Breit, G.N.; Welch, A.H.; Yount, J.C.; Whitney, J.W.; Foster, A.L.; Uddin, M.N.; Majumder, R.K.; Ahmed, N.


    Recognition of arsenic (As) contamination of shallow fluvio-deltaic aquifers in the Bengal Basin has resulted in increasing exploitation of groundwater from deeper aquifers that generally contain low concentrations of dissolved As. Pumping-induced infiltration of high-As groundwater could eventually cause As concentrations in these aquifers to increase. This study investigates the adsorption capacity for As of sediment from a low-As aquifer near Dhaka, Bangladesh. A shallow, chemically-reducing aquifer at this site extends to a depth of 50??m and has maximum As concentrations in groundwater of 900????g/L. At depths greater than 50??m, geochemical conditions are more oxidizing and groundwater has < 5????g/L As. There is no thick layer of clay at this site to inhibit vertical transport of groundwater. Arsenite [As(III)] is the dominant oxidation state in contaminated groundwater; however, data from laboratory batch experiments show that As(III) is oxidized to arsenate [As(V)] by manganese (Mn) minerals that are present in the oxidized sediment. Thus, the long-term viability of the deeper aquifers as a source of water supply is likely to depend on As(V) adsorption. The adsorption capacity of these sediments is a function of the oxidation state of As and the concentration of other solutes that compete for adsorption sites. Arsenite that was not oxidized did adsorb, but to a much lesser extent than As(V). Phosphate (P) caused a substantial decrease in As(V) adsorption. Increasing pH and concentrations of silica (Si) had lesser effects on As(V) adsorption. The effect of bicarbonate (HCO3) on As(V) adsorption was negligible. Equilibrium constants for adsorption of As(V), As(III), P, Si, HCO3, and H were determined from the experimental data and a quantitative model developed. Oxidation of As(III) was modeled with a first-order rate constant. This model was used to successfully simulate As(V) adsorption in the presence of multiple competing solutes. Results from these

  16. Geochemistry of the Arbuckle-Simpson Aquifer

    Christenson, Scott; Hunt, Andrew G.; Parkhurst, David L.; Osborn, Noel I.


    The Arbuckle-Simpson aquifer in south-central Oklahoma provides water for public supply, farms, mining, wildlife conservation, recreation, and the scenic beauty of springs, streams, and waterfalls. A new understanding of the aquifer flow system was developed as part of the Arbuckle-Simpson Hydrology Study, done in 2003 through 2008 as a collaborative research project between the State of Oklahoma and the Federal government. The U.S. Geological Survey collected 36 water samples from 32 wells and springs in the Arbuckle-Simpson aquifer in 2004 through 2006 for geochemical analyses of major ions, trace elements, isotopes of oxygen and hydrogen, dissolved gases, and dating tracers. The geochemical analyses were used to characterize the water quality in the aquifer, to describe the origin and movement of ground water from recharge areas to discharge at wells and springs, and to determine the age of water in the aquifer.

  17. Quality of groundwater at and near an aquifer storage and recovery site, Bexar, Atascosa, and Wilson Counties, Texas, June 2004-August 2008

    Otero, Cassi L.; Petri, Brian L.


    The U.S. Geological Survey, in cooperation with the San Antonio Water System, did a study during 2004-08 to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near an aquifer storage and recovery (ASR) site in Bexar, Atascosa, and Wilson Counties, Texas. Groundwater samples were collected and analyzed for selected physical properties and constituents to characterize the quality of native groundwater from the Edwards aquifer and pre- and post-injection water from the Carrizo aquifer at and near the ASR site. Geochemical and isotope data indicated no substantial changes in major-ion, trace-element, and isotope chemistry occurred as the water from the Edwards aquifer was transferred through a 38-mile pipeline to the aquifer storage and recovery site. The samples collected from the four ASR recovery wells were similar in major-ion and stable isotope chemistry compared to the samples collected from the Edwards aquifer source wells and the ASR injection well. The similarity could indicate that as Edwards aquifer water was injected, it displaced native Carrizo aquifer water, or, alternatively, if mixing of Edwards and Carrizo aquifer waters was occurring, the major-ion and stable isotope signatures for the Carrizo aquifer water might have been obscured by the signatures of the injected Edwards aquifer water. Differences in the dissolved iron and dissolved manganese concentrations indicate that either minor amounts of mixing occurred between the waters from the two aquifers, or as Edwards aquifer water displaced Carrizo aquifer water it dissolved the iron and manganese directly from the Carrizo Sand. Concentrations of radium-226 in the samples collected at the ASR recovery wells were smaller than the concentrations in samples collected from the Edwards aquifer source wells and from the ASR injection well. The smaller radium-226 concentrations in the samples collected from the ASR

  18. Availability and quality of water from drift aquifers in Marshall, Pennington, Polk, and Red Lake counties, northwestern Minnesota

    Lindgren, R.J.


    Sand and gravel aquifers present within glacial deposits are important sources of water in Marshall, Pennington, Polk, and Red Lake Counties in northwestern Minnesota. Saturated thicknesses of the unconfined aquifers range from 0 to 30 feet. Estimated horizontal hydraulic conductivities range from 2.5 to 600 feet per day. Transmissivity of the unconfined aquifers ranges from 33 to greater than 3,910 feet squared per day. Theoretical maximum well yields for 6 wells with specific-capacity data range from 12 to 123 gallons per minute.

  19. Aquifer Vulnerability maps and climate change

    Ducci, Daniela; Sellerino, Mariangela


    The aquifer vulnerability maps to contamination are used worldwide by environmental agencies and water-resource managers with the aim of preserving the water resources and of evaluating the most suitable areas where to locate new settlements. In the parametric methods, more used to assess the groundwater contamination vulnerability, e.g. the DRASTIC and the AVI methods, an important role is played by the protective capacity of cover layers to the introduction and transport of contaminants into the aquifer. Therefore, these methods point out the importance of the "Depth to water" parameter, which represents, where the aquifer is unconfined, the depth of the piezometric level and, where the aquifer is confined, the top of the aquifer. This parameter is rarely variable in confined aquifers and in deep unconfined aquifers, as karst aquifers, where the piezometric oscillations are low, compared with the depth of the water table. On the contrary, in shallow aquifers of flat areas, where in addition a large number of human activities are practiced and the contamination risk is high, the piezometric level varies suddenly with the rainfall, and it is very sensitive to drought periods and climatic changes. This affects noticeably the "Depth to water" parameter and consequently the vulnerability maps (e.g. 3 m of piezometric lowering can produce a change in the DRASTIC index from 10 to 7…). To validate this hypothesis, the DRASTC and AVI methods have been applied on a shallow aquifer located in a flat area in Campania (Italy,) considering data corresponding to an average rainfall period and to a drought period.

  20. Cenomanian-Turonian aquifer of central Israel, its development and possible use as a storage reservoir

    Schneider, Robert


    The Cenomanian-Turonian formations constitute a highly permeable dolomite and limestone aquifer in central Israel. The aquifer is on the west limb of an anticlinorium that trends north-northeast. In places it may be as much as 800 meters thick, but in the report area, largely the foothills of the Judean-Ephraim Mountains where the water development is most intensive, its thickness is generally considerably less. In some places the aquifer occurs at or near the land surface, or it is covered by sandy and gravelly coastal-plain deposits. However, in a large part of the area, it is overlain by as much as 400 meters of relatively impermeable strata, and it is probably underlain by less permeable Lower Cretaceous strata. In general the aquifer water is under artesian pressure. The porosity of the aquifer is characterized mainly by solution channels and cavities produced by jointing and faulting. In addition to the generally high permeability of the aquifer, some regions, which probably coincide with ancient drainage patterns and (or) fault zones, have exceptionally high permeabilities. The source of most of the water in the aquifer is believed to be rain that falls on the foothills area. The westward movement of ground water from the mountainous outcrop areas appears to be impeded by a zone of low permeability which is related to structural and stratigraphic conditions along the western side of the mountains. Gradients of the piezometric surface are small, and the net direction of water movement is westward and northwestward under natural conditions. Locally, however, the flow pattern may be in other directions owing to spatial variations in permeability in the aquifer, the location of natural discharge outlets, and the relation of the aquifer to adjacent geologic formations. There probably is also a large vertical component of flow. Pumping has modified the flow pattern by producing several irregularly shaped shallow depressions in the piezometric surface although, to

  1. Economics of Managed Aquifer Recharge

    Robert G. Maliva


    Full Text Available Managed aquifer recharge (MAR technologies can provide a variety of water resources management benefits by increasing the volume of stored water and improving water quality through natural aquifer treatment processes. Implementation of MAR is often hampered by the absence of a clear economic case for the investment to construct and operate the systems. Economic feasibility can be evaluated using cost benefit analysis (CBA, with the challenge of monetizing benefits. The value of water stored or treated by MAR systems can be evaluated by direct and indirect measures of willingness to pay including market price, alternative cost, value marginal product, damage cost avoided, and contingent value methods. CBAs need to incorporate potential risks and uncertainties, such as failure to meet performance objectives. MAR projects involving high value uses, such as potable supply, tend to be economically feasible provided that local hydrogeologic conditions are favorable. They need to have low construction and operational costs for lesser value uses, such as some irrigation. Such systems should therefore be financed by project beneficiaries, but dichotomies may exist between beneficiaries and payers. Hence, MAR projects in developing countries may be economically viable, but external support is often required because of limited local financial resources.

  2. Relationship of regional water quality to aquifer thermal energy storage

    Allen, R.D.


    Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to counter these potential geochemical and lithologic problems were also identified through the literature search. Regional hydrology summaries and other sources were used in reviewing aquifers of 19 drainage regions in the US to determine generic geochemical characteristics for analysis. Numerical modeling techniques were used to perform geochemical analyses of water quality from 67 selected aquifers. Candidate water resources regions were then identified for exploration and development of ATES. This study identified six principal mechanisms by which ATES reservoir permeability may be impaired: (1) particulate plugging, (2) chemical precipitation, (3) liquid-solid reactions, (4) formation disaggregation, (5) oxidation reactions, and (6) biological activity. Specific proven countermeasures to reduce or eliminate these effects were found. Of the hydrologic regions reviewed, 10 were identified as having the characteristics necessary for ATES development: (1) Mid-Atlantic, (2) South-Atlantic Gulf, (3) Ohio, (4) Upper Mississippi, (5) Lower Mississippi, (6) Souris-Red-Rainy, (7) Missouri Basin, (8) Arkansas-White-Red, (9) Texas-Gulf, and (10) California.

  3. Injection and trapping of carbon dioxide in deep saline aquifers

    Saylor, B.Z.; Zerai, B. [Case Western Reserve University, Cleveland, OH (United States). Dept. of Geological Sciences


    Carbon dioxide collected from the waste streams of point sources can be injected into deep geologic formations in order to limit the emission of greenhouse gases to the atmosphere. Deep saline aquifers provide the largest potential subsurface storage capacity for injected CO{sub 2}. Once injected, free CO{sub 2} can be retained in deep aquifers for long time periods by slow-moving, downward-directed formation waters. Over time, the injected CO{sub 2} will dissolve in the formation waters and through reactions with formation minerals, may be converted to carbonate minerals, resulting in permanent sequestration. Factors that influence the mass of CO{sub 2} that can be injected and stored in free or aqueous form, and as mineral phases, are reviewed and applied to estimate storage capacity of the Rose Run Sandstone, a saline aquifer beneath eastern Ohio, USA. It is estimated that 30 years of CO{sub 2} emissions from five of Ohio's largest coal-fired power plants can be injected into the Rose Run Sandstone and, over time, converted to aqueous and ultimately, mineral phases. 48 refs., 7 figs., 2 tabs.

  4. Potential Aquifer Vulnerability in Regions Down-Gradient from ...

    Sandstone-hosted roll-front uranium ore deposits originate when U(VI) dissolved in groundwater is reduced and precipitated as insoluble U(IV) minerals. Groundwater redox geochemistry, aqueous complexation, and solute migration are instrumental in leaching uranium from source rocks and transporting it in low concentrations to a chemical redox interface where it is deposited in an ore zone typically containing the uranium minerals uraninite, pitchblende, and/or coffinite; various iron sulfides; native selenium; clays; and calcite. In situ recovery (ISR) of these uranium ores is a process of contacting the uranium mineral deposit with leaching (lixiviant) fluids via injection of the lixiviant into wells drilled into the subsurface aquifer that hosts uranium ore, while other extraction wells pump the dissolved uranium after dissolution of the uranium minerals. Environmental concerns during and after ISR include water quality impacts from: 1) potential excursions of leaching solutions away from the injection zone into down-dip, underlying, or overlying aquifers; 2) potential migration of uranium and its decay products (e.g., Ra, Rn, Pb); and, 3) potential migration of redox-sensitive trace metals (e.g., Fe, Mn, Mo, Se, V), metalloids (e.g., As), and anions (e.g., sulfate). This review describes the geochemical processes that control roll-front uranium transport and fate in groundwater systems, identifies potential aquifer vulnerabilities to ISR operations, identifies

  5. Review: Thermal water resources in carbonate rock aquifers

    Goldscheider, Nico; Mádl-Szőnyi, Judit; Erőss, Anita; Schill, Eva


    The current knowledge on thermal water resources in carbonate rock aquifers is presented in this review, which also discusses geochemical processes that create reservoir porosity and different types of utilisations of these resources such as thermal baths, geothermal energy and carbon dioxide (CO2) sequestration. Carbonate aquifers probably constitute the most important thermal water resources outside of volcanic areas. Several processes contribute to the creation of porosity, summarised under the term hypogenic (or hypogene) speleogenesis, including retrograde calcite solubility, mixing corrosion induced by cross-formational flow, and dissolution by geogenic acids from deep sources. Thermal and mineral waters from karst aquifers supply spas all over the world such as the famous bath in Budapest, Hungary. Geothermal installations use these resources for electricity production, district heating or other purposes, with low CO2 emissions and land consumption, e.g. Germany’s largest geothermal power plant at Unterhaching near Munich. Regional fault and fracture zones are often the most productive zones, but are sometimes difficult to locate, resulting in a relatively high exploration uncertainty. Geothermal installations in deep carbonate rocks could also be used for CO2 sequestration (carbonate dissolution would partly neutralise this gas and increase reservoir porosity). The use of geothermal installations to this end should be further investigated.

  6. Hydrogeology of the Helena Valley-fill aquifer system, west-central Montana. Water resources investigation

    Briar, D.W.; Madison, J.P.


    The report, which presents the study results, describes the hydrogeology of the valley-fill aquifer system. Specific objectives were to: describe the geometry and the hydraulic characteristics of the aquifer system; define the potentiometric surface and the direction of ground-water flow; locate and quantify sources of ground-water recharge and discharge including surface- and ground-water interactions; and characterize the water quality in terms of susceptibility of the aquifer system to contamination and in terms of concentrations, distribution, and sources of major ions, trace elements, and organic compounds. The results of the study will be useful to the development of a comprehensive management program for the use and protection of the ground-water resources of the Helena Valley.

  7. Vulnerability of recently recharged groundwater in principal [corrected] aquifers of the United States to nitrate contamination.

    Gurdak, Jason J; Qi, Sharon L


    Recently recharged water (defined here as aquifer to subaquifer scale. New logistic regression models were developed using data from the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) program and National Water Information System for 17 principal aquifers of the U.S. to identify important source, transport, and attenuation factors that control nonpoint source nitrate concentrations greater than relative background levels in recently recharged groundwater and were used to predict the probability of detecting elevated nitrate in areas beyond the sampling network. Results indicate that dissolved oxygen, crops and irrigated cropland, fertilizer application, seasonally high water table, and soil properties that affect infiltration and denitrification are among the most important factors in predicting elevated nitrate concentrations. Important differences in controlling factors and spatial predictions were identified in the principal aquifer and national-scale models and support the conclusion that similar spatial scales are needed between informed groundwater management and model development.

  8. Unravelling aquifer-wetland interaction using CSAMT and gravity methods: the Mollina-Camorra aquifer and the Fuente de Piedra playa-lake, southern Spain

    Pedrera, A.; Martos-Rosillo, S.; Galindo-Zaldívar, J.; Rodríguez-Rodríguez, M.; Benavente, J.; Martín-Rodríguez, J. F.; Zúñiga-López, M. I.


    The hydrological regime of Fuente de Piedra playa-lake (Málaga, southern Spain) has been significantly affected by the intensive exploitation of groundwater in the area. The playa-lake is situated above clays, marls, and gypsum, and under unaltered conditions received surface-subsurface runoff within the watershed as well as groundwater discharge from two carbonate aquifers. We have analyzed the structure of the main one, the Mollina-Camorra carbonate aquifer, by combining controlled source audio magnetotellurics (CSAMT), gravity prospecting, and time-domain electromagnetic (TDEM) soundings. This geophysical information, together with new structural and hydrogeological data, was gathered to develop a new conceptual hydrogeological model. This model allows the hydrological linkage of the carbonate aquifer with the playa-lake system to be established. Moreover, the intensive exploitation in the carbonate aquifer, even outside the watershed of the playa-lake, has affected the hydrological regime of the system. This multidisciplinary work demonstrates the potential of geophysical methods for understanding wetland-aquifer interaction, having important groundwater management implications.

  9. A multiobjective discrete stochastic optimization approach to shared aquifer management: Methodology and application

    Siegfried, Tobias; Kinzelbach, Wolfgang


    Negative effects from groundwater mining are observed globally. They threaten future supply locally. Especially in semiarid to arid regions, where aquifers are the sole freshwater resource, this is problematic and can lead to an excessive rise of provision costs. Proper resource management in such environments is crucial. In many instances, however, aquifers are common property resources. In such cases and depending on resource characteristics and the nature of competing uses, their management is inherently multiobjective, and benefits from cooperative management are likely to be substantial. This paper presents a methodology for the determination of optimal, cooperative allocation policies in multiobjective aquifer management problems. Our model couples a finite difference aquifer model with an economic model that accounts for water provision costs. Discounted temporal installation and pumping and conveyance costs determine the vector-valued objective function. Each of the objectives characterizes the individual present costs over a given time horizon that the corresponding decision makers wish to minimize. Constraint handling is implemented by the option of moving wells. A multiobjective evolutionary algorithm is coupled to the management model so as to approximate cooperative tradeoff policies on the Pareto surface. These solutions can be ranked against existing, noncooperative status quo strategies. Consequently, the simulation-optimization model is applied to the northwest Sahara aquifer system which is used noncooperatively as a resource by Algeria, Tunisia, and Libya. We find that significant capital gains can be achieved by the establishment of intelligent pump scheduling. Since each country could benefit, a strong incentive toward the implementation of such cooperative strategies exists.

  10. Analyzing microbial and sediment geochemistry to identify safe aquifer zones in an Arsenic prone aquifer

    Kibria, G.; Hossain, M.; Kirk, M. F.; Bhattacharya, P.; Ahmed, K.; Datta, S.


    The assessment of the incidence of arsenic (As) and other oxyanions was examined in Bengal delta floodplain groundwaters from Matlab Upazila, Bangladesh. Our field campaign in 2013 covered an area of ~400km2 between North and South Matlab. Shallow tubewells except those installed within off-white sediments are mostly contaminated with high As. In our field studies we found the wells installed within light grey medium sand, the As concentration was found below 50μg/L. Groundwater abstracted from oxidized reddish sediments in contrast to reduced greyish sediments, contain significantly lower amount of dissolved As and can be a source of safe water. Sediment geochemistry and adsorption extent of oxidized red brown and reduced grey sediments to attenuate As are studied here. Sediment cores were collected at regular intervals from within depth of ~125m in Matlab. This study describes the color, lithofacies and mineralogy of the sediments The stable isotopes of groundwaters from various depths within a piezometer nest are studied also to determine the extent of hydraulic conductivity between depths of aquifers along with mechanism of recharge of the groundwater at those depths. DNA recovered from Matlab core samples averaged 450ng/g from course-grained samples and 800ng/g from fine-grained samples. After sequencing the DNA, it was found that microbial community in red or light gray sediments are different than gray-dark gray sediments (e.g. Burkholderiaceae and Pseudomonadacee are common in grey/ dark gray sediment but Streptomycetaceae is common in red/ light grey color). Rhodocyclaceae, Aeromonadaceae, Shewanellaceae are the common genera present in these sediments that are capable of reducing Fe in this aquifer environment. Synchrotron aided μXANES and μXRD studies conducted for solid state As and S speciation in the core samples at different depths indicate the occurrences of hotspots of As differently distributed in red-brown and grey sediments. Samples collected

  11. Hydrogeologic framework and salinity distribution of the Floridan aquifer system of Broward County, Florida

    Reese, Ronald S.; Cunningham, Kevin J.


    Concerns about water-level decline and seawater intrusion in the surficial Biscayne aquifer, currently the principal source of water supply to Broward County, prompted a study to refine the hydrogeologic framework of the underlying Floridan aquifer system to evaluate its potential as an alternative source of supply. This report presents cross sections that illustrate the stratigraphy and hydrogeology in eastern Broward County; maps of the upper surfaces and thicknesses of several geologic formations or units within the Floridan aquifer system; and maps of two of the potentially productive water-bearing zones within the system, the Upper Floridan aquifer and the Avon Park permeable zone. An analysis of data on rock depositional textures, associated pore networks, and flow zones in the Floridan aquifer system shows that groundwater moves through the system in two ways. These data support a conceptual, dual-porosity model of the system wherein groundwater moves either as concentrated flow in discrete, thin bedding-plane vugs or zones of vuggy megaporosity, or as diffuse flow through rocks with primarily interparticle and moldic-particle porosity. Because considerable exchange of groundwater may occur between the zones of vuggy and matrix-dominated porosity, understanding the distribution of that porosity and flow zone types is important to evaluating the suitability of the several units within the Floridan aquifer system for managing the water through practices such as aquifer storage and recovery (ASR). The salinity of the water in the Floridan aquifer system is highest in the central part of the study area, and lower toward the north and south. Although salinity generally increases with depth, in the western part of the study area a zone of relatively high saline water is perched above water of lower salinity in the underlying Avon Park permeable zone. Overall, the areas of highest salinity in the aquifer system coincide with those with the lowest estimated

  12. Detection of Euryarchaeota and Crenarchaeota in an oxic basalt aquifer.

    O'Connell, Seán P; Lehman, R Michael; Snoeyenbos-West, Oona; Winston, Vern D; Cummings, David E; Watwood, Mary E; Colwell, Frederick S


    Groundwater from an oxic, fractured basalt aquifer was examined for the presence of Archaea. DNA was extracted from cells concentrated from groundwater collected from five wells penetrating the eastern Snake River Plain Aquifer (Idaho, USA). Polymerase chain reaction (PCR) amplification of 16S rDNA was performed with Archaea-specific primers using both nested (ca. 200-bp product) and direct (ca. 600-bp product) PCR approaches. Estimates of the archaeal diversity were made by separating PCR products from all five wells by denaturing gradient gel electrophoresis (DGGE) and phylogenetic analysis of partial 16S rDNA sequences from two wells was performed following cloning procedures. Archaea were detected in all wells and the number of DGGE bands per well ranged from two to nine and varied according to PCR approach. There were 30 unique clonal 16S rDNA partial sequences (ca. 600 bp) within a total of 100 clones that were screened from two wells. Twenty-two of the 16S rDNA fragments recovered from the aquifer were related to the Crenarchaeota and Euryarchaeota kingdoms (one large clade of clones in the former and six smaller clades in the latter), with sequences ranging from 23.7 to 95.4% similar to those found in other investigations. The presence of potentially thermophilic or methanogenic Archaea in this fully oxic aquifer may be related to deep thermal sources or elevated dissolved methane concentrations. Many sequences were similar to those that represent non-thermophilic Crenarchaeota of which there are no known cultured members and therefore no putative function.

  13. Nitrate in the Columbia Aquifer, central Delmarva Peninsula, Maryland

    Bachman, L.J.


    A study of nitrate in water from 604 wells tapping the Columbia aquifer on the Delmarva Peninsula in eastern Maryland describes the factors that affect nitrate variability. Samples were collected from 196 randomly selected wells and analyzed for nitrogen species. Many were also analyzed for major ions. In addition, results of 313 nitrate analyses were randomly selected from county health department files. About 95 analyses of water samples collected from 1945 to 1978 were also evaluated. The frequency distribution of the nitrate analyses is bimodal, with 25 percent of the sample ranging from 0 to about 0.42 milligrams per liter (mg/L) nitrate as nitrogen (N), and the median is about 0.1 mg/L; the rest ranges from 0.42 to 58 mg/L, and the median is about 5.9 mg/L. The overall median nitrate concentration is about 3.5 mg/L as N. Over half of the samples had nitrate concentrations of 3 mg/L as N or higher, indicating that the water in the aquifer has been affected by human activity. Nitrate-nitrogen concentrations exceeded the water-quality standard of 10 mg/L in 15 percent of the samples established by the U.S. Environmental Protection Agency. The major factors affecting nitrate concentration are the presence of a nitrogen source, hydrogeological conditions, and the soil drainage. Sites with poorly drained soils may have a lower nitrate concentration either because the soils block the entrance of nitrate into the aquifer or because the aquifer under a poorly drained soil is associated with a chemical environment that promotes denitrification. (USGS)

  14. Aquifer-scale controls on the distribution of nitrate and ammonium in ground water near La Pine, Oregon, USA

    Hinkle, Stephen R.; Böhlke, J. K.; Duff, John H.; Morgan, David S.; Weick, Rodney J.


    SummaryGeochemical and isotopic tools were applied at aquifer, transect, and subtransect scales to provide a framework for understanding sources, transport, and fate of dissolved inorganic N in a sandy aquifer near La Pine, Oregon. NO 3 is a common contaminant in shallow ground water in this area, whereas high concentrations of NH 4-N (up to 39 mg/L) are present in deep ground water. N concentrations, N/Cl ratios, tracer-based apparent ground-water ages, N isotope data, and hydraulic gradients indicate that septic tank effluent is the primary source of NO 3. N isotope data, N/Cl and N/C relations, 3H data, and hydraulic considerations point to a natural, sedimentary organic matter source for the high concentrations of NH 4, and are inconsistent with an origin as septic tank N. Low recharge rates and flow velocities have largely restricted anthropogenic NO 3 to isolated plumes within several meters of the water table. A variety of geochemical and isotopic data indicate that denitrification also affects NO 3 gradients in the aquifer. Ground water in the La Pine aquifer evolves from oxic to increasingly reduced conditions. Suboxic conditions are achieved after about 15-30 y of transport below the water table. NO 3 is denitrified near the oxic/suboxic boundary. Denitrification in the La Pine aquifer is characterized well at the aquifer scale with a redox boundary approach that inherently captures spatial variability in the distribution of electron donors.

  15. Geochemical detection of carbon dioxide in dilute aquifers

    Aines Roger


    Full Text Available Abstract Background Carbon storage in deep saline reservoirs has the potential to lower the amount of CO2 emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO2 gas leak into dilute groundwater are important measures for the potential release of CO2 to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO2 storage reservoir. Specifically, we address the relationships between CO2 flux, groundwater flow, detection time and distance. The CO2 flux ranges from 103 to 2 × 106 t/yr (0.63 to 1250 t/m2/yr to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure. Results For the scenarios we studied, our simulations show pH and carbonate chemistry are good indicators for leakage of stored CO2 into an overlying aquifer because elevated CO2 yields a more acid pH than the ambient groundwater. CO2 leakage into a dilute groundwater creates a slightly acid plume that can be detected at some distance from the leak source due to groundwater flow and CO2 buoyancy. pH breakthrough curves demonstrate that CO2 leaks can be easily detected for CO2 flux ≥ 104 t/yr within a 15-month time period at a monitoring well screened within a permeable layer 500 m downstream from the vertical gas trace. At lower flux rates, the CO2 dissolves in the aqueous phase

  16. Development Report on the Idaho National Laboratory Sitewide Three-Dimensional Aquifer Model

    Thomas R. Wood; Catherine M. Helm-Clark; Hai Huang; Swen Magnuson; Travis McLing; Brennon Orr; Michael J. Rohe; Mitchell A. Plummer; Robert Podgorney; Erik Whitmore; Michael S. Roddy


    -velocity region near the toe of the Arco Hills. This discrepancy persisted in each of the aquifer bottom thickness scenarios that were simulated precluding decisions on which aquifer bottom thickness to use in transport simulations. When joint-calibration was performed using both water levels and velocities assigned as calibration targets, the discrepancy was prevented. This result highlighted the need to consider multiple calibration objectives and not rely solely on calibration to water levels. The next and last step in the process of constructing a fully three-dimensional groundwater flow and contaminant transport model will be calibration directly to transport from facilities. This last step will likely require further modification of the velocity fields resulting from the three-dimensional groundwater flow model presented in this report.

  17. Radial Dupuit interface flow to assess the aquifer storage and recovery potential of saltwater aquifers

    Bakker, M


    A new accurate numerical solution is presented for aquifer storage and recovery (ASR) systems in coastal aquifers; flow is approximated as radial Dupuit interface flow. The radial velocities of points on the interface are a function of time, the vertical coordinate, and the dimensionless parameter D (the discharge of the well divided by the product of the hydraulic conductivity, the square of the aquifer thickness, and the dimensionless density difference). The recovery efficiency of an ASR s...

  18. Potentiometric surface, 2013, and water-level differences, 1991-2013, of the Carrizo-Wilcox aquifer in northwest Louisiana

    Fendick, Robert B.; Carter, Kayla


    The Carrizo-Wilcox aquifer is the primary source of fresh groundwater for public supply as well as industrial, agricultural, and domestic uses in several parishes in northwestern Louisiana, including Bienville, Bossier, Caddo, De Soto, Natchitoches, Red River, Sabine, and Webster. In 2010, about 19 million gallons per day (Mgal/d) were withdrawn from the Carrizo-Wilcox aquifer in Louisiana. This is an increase of over 6 Mgal/d from 1990 withdrawal amounts. The largest increase in withdrawals occurred in Caddo (3.79 Mgal/d) and De Soto Parishes (2.32 Mgal/d), whereas the largest decrease in withdrawals occurred in Natchitoches Parish (1.17 Mgal/d). Groundwater withdrawals from the Carrizo-Wilcox aquifer have caused water-level declines throughout much of the aquifer in the study area. Additional knowledge about the effects of withdrawals on water levels and flow directions in the Carrizo-Wilcox aquifer are needed to assess current conditions in the aquifer. In 2012, the U.S. Geological Survey (USGS) in cooperation with the Louisiana Department of Natural Resources began a study to document current water levels and water-level changes in selected aquifers.

  19. MODFLOW2005 model used to simulate the effects of groundwater withdrawals from aquifers in Ocean County and vicinity, New Jersey

    Cauller, Stephen; Voronin, Lois M.; Chepiga, Mary


    A three-dimensional groundwater flow model was developed to simulate the effects of withdrawals on the groundwater-flow systems of five aquifers in and around Ocean County, New Jersey—the unconfined Kirkwood-Cohansey aquifer system and Vincentown aquifer, and three confined aquifers--the Rio Grande water-bearing zone, the Atlantic City 800-foot sand, and the Piney Point aquifer. A transient model was used to simulate conditions that represent no groundwater withdrawals, 2000–2003 groundwater withdrawals, and maximum-allocation groundwater withdrawals. Particle-tracking analysis, using results from two steady-state simulations, determine flow paths and travel times to near-shore wells screened in the unconfined Kirkwood-Cohansey aquifer system, the Rio Grande water-bearing zone, and the Atlantic City 800-foot sand. Sources of water to wells in both unconfined and confined aquifers and travel times based on particle-tracking analysis are used to assess the susceptibility of selected wells to saltwater intrusion from bay or ocean water. This USGS data release contains all of the input and output files for the simulations described in the associated model documentation report (

  20. An Aquifer Storage and Recovery system with reclaimed wastewater to preserve native groundwater resources in El Paso, Texas.

    Sheng, Zhuping


    The traditional concept of Aquifer Storage and Recovery (ASR) has been emphasized and extensively applied for water resources conservation in arid and semi-arid regions using groundwater systems as introduced in Pyne's book titled Groundwater Recharge and Wells. This paper extends the ASR concept to an integrated level in which either treated or untreated surface water or reclaimed wastewater is stored in a suitable aquifer through a system of spreading basins, infiltration galleries and recharge wells; and part or all of the stored water is recovered through production wells, dual function recharge wells, or by streams receiving increased discharge from the surrounding recharged aquifer as needed. In this paper, the author uses the El Paso Water Utilities (EPWU) ASR system for injection of reclaimed wastewater into the Hueco Bolson aquifer as an example to address challenges and resolutions faced during the design and operation of an ASR system under a new ASR system definition. This new ASR system concept consists of four subsystems: source water, storage space-aquifer, recharge facilities and recovery facilities. Even though facing challenges, this system has successfully recharged approximately 74.7 million cubic meters (19.7 billion gallons) of reclaimed wastewater into the Hueco Bolson aquifer through 10 recharge wells in the last 18 years. This ASR system has served dual purposes: reuse of reclaimed wastewater to preserve native groundwater, and restoration of groundwater by artificial recharge of reclaimed wastewater into the Hueco Bolson aquifer.

  1. The quality of our Nation's waters: water quality in the glacial aquifer system, northern United States, 1993-2009

    Warner, Kelly L.; Ayotte, Joseph D.


    The glacial aquifer system underlies much of the northern United States. About one-sixth (41 million people) of the United States population relies on the glacial aquifer system for drinking water. The primary importance of the glacial aquifer system is as a source of water for public supply to the population centers in the region, but the aquifer system also provides drinking water for domestic use to individual homes and small communities in rural areas. Withdrawals from this aquifer system for public supply are the largest in the Nation and play a key role in the economic development of parts of 26 States. Corn production has increased in the central part of the aquifer system over the last 10 years, and the increased production increases the need for water for agricultural use and the need for increased use of agrochemicals. Additionally, the steady increase in population (15 million people over the last 40 years) in urban and rural areas is resulting in an increased reliance on the glacial aquifer system for high-quality drinking water. The need to monitor, understand, and maintain the water quality of this valuable economic resource continues to grow.

  2. An extension to the DRASTIC model to assess groundwater vulnerability to pollution: application to the Haouz aquifer of Marrakech (Morocco)

    Sinan, Mohamed; Razack, Moumtaz


    An extension to the DRASTIC model is proposed in order to assess aquifer vulnerability to pollution. In contrast to the DRASTIC model, which considers the unsaturated and saturated zones together and computes a global intrinsic vulnerability index, the suggested approach discriminates between the aquifer vertical vulnerability (a concept related to the pollutant percolation) and the groundwater susceptibility (a concept that depends on the behaviour and uses of the groundwater). This approach is applied to the Haouz aquifer (Morocco) that supplies water to the Marrakech area. This aquifer is widely overexploited and there is evidence that the groundwater quality is threatened by various sources of pollution. Evaluation of the vertical vulnerability indicates that the aquifer mainly presents a moderate-to-weak vertical vulnerability. The zones potentially most favourable to pollutant percolation are mainly located in Central Haouz, along or near the surface wadis. The aquifer susceptibility is high in places located near the N’Fis, Baaja and Issil wadis. Everywhere else, low-to-moderate susceptibility is observed. This new approach therefore enables areas of vertical vulnerability and areas of susceptibility to be delineated separately. As a result, it constitutes a valuable decision-making tool for optimising the management of aquifer water resources and land-use planning.

  3. Modeling cross-hole slug tests in an unconfined aquifer

    Malama, Bwalya; Kuhlman, Kristopher L.; Brauchler, Ralf; Bayer, Peter


    A modified version of a published slug test model for unconfined aquifers is applied to cross-hole slug test data collected in field tests conducted at the Widen site in Switzerland. The model accounts for water-table effects using the linearized kinematic condition. The model also accounts for inertial effects in source and observation wells. The primary objective of this work is to demonstrate applicability of this semi-analytical model to multi-well and multi-level pneumatic slug tests. The pneumatic perturbation was applied at discrete intervals in a source well and monitored at discrete vertical intervals in observation wells. The source and observation well pairs were separated by distances of up to 4 m. The analysis yielded vertical profiles of hydraulic conductivity, specific storage, and specific yield at observation well locations. The hydraulic parameter estimates are compared to results from prior pumping and single-well slug tests conducted at the site, as well as to estimates from particle size analyses of sediment collected from boreholes during well installation. The results are in general agreement with results from prior tests and are indicative of a sand and gravel aquifer. Sensitivity analysis show that model identification of specific yield is strongest at late-time. However, the usefulness of late-time data is limited due to the low signal-to-noise ratios.

  4. Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA

    Scanlon, B.R.; Nicot, J.-P.; Reedy, R.C.; Kurtzman, D.; Mukherjee, A.; Nordstrom, D.K.


    High groundwater As concentrations in oxidizing systems are generally associated with As adsorption onto hydrous metal (Al, Fe or Mn) oxides and mobilization with increased pH. The objective of this study was to evaluate the distribution, sources and mobilization mechanisms of As in the Southern High Plains (SHP) aquifer, Texas, relative to those in other semiarid, oxidizing systems. Elevated groundwater As levels are widespread in the southern part of the SHP (SHP-S) aquifer, with 47% of wells exceeding the current EPA maximum contaminant level (MCL) of 10 μg/L (range 0.3–164 μg/L), whereas As levels are much lower in the north (SHP-N: 9% ⩾ As MCL of 10 μg/L; range 0.2–43 μg/L). The sharp contrast in As levels between the north and south coincides with a change in total dissolved solids (TDS) from 395 mg/L (median north) to 885 mg/L (median south). Arsenic is present as arsenate (As V) in this oxidizing system and is correlated with groundwater TDS (Spearman’s ρ = 0.57). The most likely current source of As is sorbed As onto hydrous metal oxides based on correlations between As and other oxyanion-forming elements (V, ρ = 0.88; Se, ρ = 0.54; B, ρ = 0.51 and Mo, ρ = 0.46). This source is similar to that in other oxidizing systems and constitutes a secondary source; the most likely primary source being volcanic ashes in the SHP aquifer or original source rocks in the Rockies, based on co-occurrence of As and F (ρ = 0.56), oxyanion-forming elements and SiO2 (ρ = 0.41), which are found in volcanic ashes. High groundwater As concentrations in some semiarid oxidizing systems are related to high evaporation. Although correlation of As with TDS in the SHP aquifer may suggest evaporative concentration, unenriched stable isotopes (δ2H: −65 to −27; δ18O: −9.1 to −4.2) in the SHP aquifer do not support evaporation. High TDS in the SHP aquifer is most likely related to upward movement of saline water from the underlying

  5. Viruses and Bacteria in Karst and Fractured Rock Aquifers in East Tennessee, USA

    A survey of enteric viruses and indicator bacteria was carried out in eight community water supply sources (four wells and four springs) in east Tennessee. Seven of the sites were in carbonate aquifers and the other was in fractured sandstone. Four sites (three wells and one sp...

  6. Viruses and Bacteria in Karst and Fractured Rock Aquifers in East Tennessee, USA

    A survey of enteric viruses and indicator bacteria was carried out in eight community water supply sources (four wells and four springs) in east Tennessee. Seven of the sites were in carbonate aquifers and the other was in fractured sandstone. Four sites (three wells and one sp...


    Linked tectonic, geochemical, and biologic processes lead to natural arsenic contamination of groundwater in Holocene alluvial aquifers, which are the main threat to human health around the world. These groundwaters are commonly found a long distance from their ultimate source of...

  8. Solute changes during aquifer storage recovery testing in a limestone/clastic aquifer

    Mirecki, J.E.; Campbell, B.G.; Conlon, K.J.; Petkewich, M.D.


    Aquifer storage recovery (ASR) was tested in the Santee Limestone/Black Mingo Aquifer near Charleston, South Carolina, to assess the feasibility for subsurface storage of treated drinking water. Water quality data obtained during two representative ASR tests were interpreted to show three things: (1) recovery efficiency of ASR in this geological setting; (2) possible changes in physical characteristics of the aquifer during ASR testing; and (3) water quality changes and potability of recovered water during short (one- and six-day) storage durations in the predominantly carbonate aquifer. Recovery efficiency for both ASR tests reported here was 54%. Successive ASR tests increased aquifer permeability of the Santee Limestone/Black Mingo Aquifer. It is likely that aquifer permeability increased during short storage periods due to dissolution of carbonate minerals and amorphous silica in aquifer material by treated drinking water. Dissolution resulted in an estimated 0.3% increase in pore volume of the permeable zones. Ground water composition generally evolved from a sodium-calcium bicarbonate water to a sodium chloride water during storage and recovery. After short duration, stored water can exceed the U.S. Environmental Protection Agency maximum contaminant level (MCL) for chloride (250 mg/L). However, sulfate, fluoride, and trihalomethane concentrations remained below MCLs during storage and recovery.Aquifer storage recovery (ASR) was tested in the Santee Limestone/Black Mingo Aquifer near Charleston, South Carolina, to assess the feasibility for subsurface storage of treated drinking water. Water quality data obtained during two representative ASR tests were interpreted to show three things: (1) recovery efficiency of ASR in this geological setting; (2) possible changes in physical characteristics of the aquifer during ASR testing; and (3) water quality changes and potability of recovered water during short (one- and six-day) storage durations in the predominantly

  9. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    Becker, C.J.; Runkle, D.L.; Rea, Alan


    ARC/INFO export and nonproprietary format files The data sets in this report include digitized aquifer boundaries and maps of hydraulic conductivity, recharge, and ground-water level elevation contours for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace aquifer covers approximately 82 square miles and supplies water for irrigation, domestic, municipal, and industrial use for the City of Enid and western Garfield County. The Quaternary-age Enid isolated terrace aquifer is composed of terrace deposits that consist of discontinuous layers of clay, sandy clay, sand, and gravel. The aquifer is unconfined and is bounded by the underlying Permian-age Hennessey Group on the east and the Cedar Hills Sandstone Formation of the Permian-age El Reno Group on the west. The Cedar Hills Sandstone Formation fills a channel beneath the thickest section of the Enid isolated terrace aquifer in the midwestern part of the aquifer. All of the data sets were digitized and created from information and maps in a ground-water modeling thesis and report of the Enid isolated terrace aquifer. The maps digitized were published at a scale of 1:62,500. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data.

  10. Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell, Kentucky/Tennessee, USA

    Vesper, Dorothy J.; White, William B.

    Continuous records of discharge, specific conductance, and temperature were collected through a series of storm pulses on two limestone springs at Fort Campbell, western Kentucky/Tennessee, USA. Water samples, collected at short time intervals across the same storm pulses, were analyzed for calcium, magnesium, bicarbonate, total organic carbon, and pH. Chemographs of calcium, calcite saturation index, and carbon dioxide partial pressure were superimposed on the storm hydrographs. Calcium concentration and specific conductance track together and dip to a minimum either coincident with the peak of the hydrograph or lag slightly behind it. The CO2 pressure continues to rise on the recession limb of the hydrograph and, as a result, the saturation index decreases on the recession limb of the hydrograph. These results are interpreted as being due to dispersed infiltration through CO2-rich soils lagging the arrival of quickflow from sinkhole recharge in the transport of storm flow to the springs. Karst spring hydrographs reflect not only the changing mix of base flow and storm flow but also a shift in source of recharge water over the course of the storm. L'enregistrement en continu du débit, de la conductivité et de la température de l'eau a été réalisé au cours d'une série de crues à deux sources émergeant de calcaires, à Fort Campbell (Kentucky occidental, Tennessee, États-Unis). Des échantillons d'eau, prélevés à de courts pas de temps lors de ces crues, ont été analysés pour le calcium, le magnésium, les bicarbonates, le carbone organique total et le pH. Les chimiogrammes de calcium, d'indice de saturation de la calcite et de la pression partielle en CO2 ont été superposés aux hydrogrammes de crue. La concentration en calcium et la conductivité de l'eau se suivent bien et passent par un minimum correspondant au pic de l'hydrogramme ou légèrement retardé. La pression partielle en CO2 continue de croître au cours de la récession de l

  11. The quality of our nation's waters: water quality in the Principal Aquifers of the Piedmont, Blue Ridge, and Valley and Ridge regions, eastern United States, 1993-2009

    Lindsey, Bruce D.; Zimmerman, Tammy M.; Chapman, Melinda J.; Cravotta, Charles A.; Szabo, Zoltan


    The aquifers of the Piedmont, Blue Ridge, and Valley and Ridge regions underlie an area with a population of more than 40 million people in 10 states. The suburban and rural population is large, growing rapidly, and increasingly dependent on groundwater as a source of supply, with more than 550 million gallons per day withdrawn from domestic wells for household use. Water from some of these aquifers does not meet human-health benchmarks for drinking water for contaminants with geologic or human sources. Water from samples in crystalline- and siliciclastic-rock aquifers frequently exceeded standards for contaminants with geologic sources, and samples in carbonate-rock aquifers frequently exceeded standards for contaminants with human sources, most often nitrate and bacteria.

  12. Hydrogeology - MO 2014 Thermoclines Ozark Aquifer (SHP)

    NSGIC GIS Inventory (aka Ramona) — Ozark Aquifer thermo cline correlates the temperature data throughout the state in the Ordovician System and the Upper Cambrian Series, consisting of the Eminence...

  13. Aquifer vulnerability for Colorado and New Mexico

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey Data Series provides raster data representing an estimate of aquifer vulnerability calculated for each 30-meter raster cell. Depth to...

  14. Evolution of carbon isotope signatures during reactive transport of hydrocarbons in heterogeneous aquifers

    Höyng, Dominik; Prommer, Henning; Blum, Philipp; Grathwohl, Peter; Mazo D'Affonseca, Fernando


    Compound-specific isotope analysis (CSIA) of organic pollutants has become a well-established tool for assessing the occurrence and extent of biodegradation processes in contaminated aquifers. However, the precision of CSIA is influenced by the degree to which assumptions underlying CSIA data interpretation hold under realistic field-scale conditions. For the first time this study demonstrates how aquifer analogs combined with reactive transport models offer an underexplored way to develop generic process understanding, evaluate monitoring and quantification strategies in highly heterogeneous subsurface settings. Data from high-resolution aquifer analogs were used in numerical experiments to track the propagation of a representative oxidizable organic compound (toluene) within a variety of realistic heterogeneous aquifers and to investigate its detailed fate. The simulations were used to analyze (1) the effects of physical aquifer heterogeneities on spatiotemporal patterns of contaminant concentrations and isotope signatures, (2) the performance of the commonly applied Rayleigh equation and (3) the applicability of an extension of the Rayleigh equation for complex hydrogeological conditions. The results indicate that if field-derived enrichment factors are applied without corrections for dilution, the conventional Rayleigh equation is inaccurate and estimates for biodegradation are typically overestimated and unreliable in heterogeneous aquifers. Underestimations can occur due to the partial source zone depletion. In contrast, if dilution can be accurately accounted for, field-derived enrichment factors comprise a suitable alternative to laboratory-derived and redox-specific enrichment factors. The study also examines to what extent variations in monitoring/sampling strategies influence the obtained results. Especially measurements from long-screened wells (> 1 m) reveal to be inappropriate for the application of the Rayleigh equation in the investigated aquifer

  15. Regional water quality patterns in an alluvial aquifer: direct and indirect influences of rivers.

    Baillieux, A; Campisi, D; Jammet, N; Bucher, S; Hunkeler, D


    The influence of rivers on the groundwater quality in alluvial aquifers can be twofold: direct and indirect. Rivers can have a direct influence via recharge and an indirect one by controlling the distribution of fine-grained, organic-carbon rich flood deposits that induce reducing conditions. These direct and indirect influences were quantified for a large alluvial aquifer on the Swiss Plateau (50km(2)) in interaction with an Alpine river using nitrate as an example. The hydrochemistry and stable isotope composition of water were characterized using a network of 115 piezometers and pumping stations covering the entire aquifer. Aquifer properties, land use and recharge zones were evaluated as well. This information provided detailed insight into the factors that control the spatial variability of groundwater quality. Three main factors were identified: (1) diffuse agricultural pollution sources; (2) dilution processes resulting from river water infiltrations, revealed by the δ(18)OH2O and δ(2)HH2O contents of groundwater; and (3) denitrification processes, controlled by the spatial variability of flood deposits governed by fluvial depositional processes. It was possible to quantify the dependence of the nitrate concentration on these three factors at any sampling point of the aquifer using an end-member mixing model, where the average nitrate concentration in recharge from the agricultural area was evaluated at 52mg/L, and the nitrate concentration of infiltrating river at approximately 6mg/L. The study shows the importance of considering the indirect and direct impacts of rivers on alluvial aquifers and provides a methodological framework to evaluate aquifer scale water quality patterns.

  16. Groundwater quality in the Northern Atlantic Coastal Plain aquifer system, eastern United States

    Lindsey, Bruce; Belitz, Kenneth


    Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Northern Atlantic Coastal Plain aquifer system constitutes one of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 15 percent of the study area and at moderate concentrations in about 17 percent. Organic constituents were not detected at high concentrations in the study area.

  17. Hydrogeology and water quality of the Nanticoke Creek stratified-drift aquifer, near Endicott, New York

    Kreitinger, Elizabeth A.; Kappel, William M.


    The Village of Endicott, New York, is seeking an alternate source of public drinking water with the potential to supplement their current supply, which requires treatment due to legacy contamination. The southerly-draining Nanticoke Creek valley, located north of the village, was identified as a potential water source and the local stratified-drift (valley fill) aquifer was investigated to determine its hydrogeologic and water-quality characteristics. Nanticoke Creek and its aquifer extend from the hamlet of Glen Aubrey, N.Y., to the village of Endicott, a distance of about 15 miles, where it joins the Susquehanna River and its aquifer. The glacial sediments that comprise the stratified-drift aquifer vary in thickness and are generally underlain by glacial till over Devonian-aged shale and siltstone. Groundwater is more plentiful in the northern part of the aquifer where sand and gravel deposits are generally more permeable than in the southern part of the aquifer where less-permeable unconsolidated deposits are found. Generally there is enough groundwater to supply most homeowner wells and in some cases, supply small public-water systems such as schools, mobile-home parks, and small commercial/industrial facilities. The aquifer is recharged by precipitation, runoff, and tributary streams. Most tributary streams flowing across alluvial deposits lose water to the aquifer as they flow off of their bedrock-lined channels and into the more permeable alluvial deposits at the edges of the valley. The quality of both surface water and groundwater is generally good. Some water wells do have water-quality issues related to natural constituents (manganese and iron) and several homeowners noted either the smell and (or) taste of hydrogen sulfide in their drinking water. Dissolved methane concentrations from five drinking-water wells were well below the potentially explosive value of 28 milligrams per liter. Samples from surface and groundwater met nearly all State and Federal

  18. Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Texas

    Clark, Allan K.; Golab, James A.; Morris, Robert R.


    During 2014–16, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, documented the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Texas. The Edwards and Trinity aquifers are major sources of water for agriculture, industry, and urban and rural communities in south-central Texas. Both the Edwards and Trinity are classified as major aquifers by the State of Texas.The purpose of this report is to present the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Tex. The report includes a detailed 1:24,000-scale hydrostratigraphic map, names, and descriptions of the geology and hydrostratigraphic units (HSUs) in the study area.The scope of the report is focused on geologic framework and hydrostratigraphy of the outcrops and hydrostratigraphy of the Edwards and Trinity aquifers within northern Bexar and Comal Counties, Tex. In addition, parts of the adjacent upper confining unit to the Edwards aquifer are included.The study area, approximately 866 square miles, is within the outcrops of the Edwards and Trinity aquifers and overlying confining units (Washita, Eagle Ford, Austin, and Taylor Groups) in northern Bexar and Comal Counties, Tex. The rocks within the study area are sedimentary and range in age from Early to Late Cretaceous. The Miocene-age Balcones fault zone is the primary structural feature within the study area. The fault zone is an extensional system of faults that generally trends southwest to northeast in south-central Texas. The faults have normal throw, are en echelon, and are mostly downthrown to the southeast.The Early Cretaceous Edwards Group rocks were deposited in an open marine to supratidal flats environment during two marine transgressions. The Edwards Group is composed of the Kainer and Person Formations. Following tectonic uplift, subaerial exposure, and erosion near the end of

  19. A semi-quantitative technique for mapping potential aquifer productivity on the national scale: example of England and Wales (UK)

    Abesser, Corinna; Lewis, Melinda


    The development and validation of aquifer productivity and depth-to-source maps for England and Wales are described. Aquifer productivity maps can provide valuable support for the assessment, planning and management of groundwater and renewable heat energy resources. Aquifer productivity is often mapped using geostatistical interpolation techniques such as kriging, but these techniques tend to be unsuitable for mapping at the national scale due to the high data (and time) demands. A methodology is outlined for mapping aquifer productivity at the national scale using existing national-scale data sets. Pumping test data are used to characterise the potential borehole yields that different geological formations of varying lithologies and ages can provide. Based on this analysis and using expert knowledge, the corresponding map codes on the geological map are assigned to potential productivity classes. The subsurface (concealed) extent of aquifer units is mapped from geophysical data, and together with the attributed geological map, provide the bedrock-aquifer productivity map. Drilling and pumping costs can be an important consideration when evaluating the feasibility of developing a groundwater source. Thus, a map of the approximate depth to source is developed alongside the aquifer productivity map. The maps are validated using independent data sets, and map performance is compared against performance from maps derived by random and uniform attribution. The results show that the maps successfully predict potential productivity and approximate depth to the water source, although utility of the depth-to-source map could be improved by increasing the vertical discretisation at which depth intervals are mapped.

  20. Zoning and contamination rate of magnesium and heavy metals of iron, zinc and copper in the north and northwest aquifer of Khoy (Zourabad based on GIS and determining the contaminated source

    Fariborz Khodadadi


    Full Text Available Introduction Heavy metals are the most toxic pollutants in aquatic ecosystems. This contamination can result from the release of heavy metal elements during alteration and weathering of ultramafic and mafic rocks (ophiolite zones. Among the important metals and pollutants in the ophiolite; chromium, cobalt, nickel, iron, magnesium, manganese, zinc and copper could be noted. Basically, a mass of serpentine consists of serpentine, amphibole, talc, chlorite, magnetite, and the remainder of olivine, pyroxene and spinel (Kil et al., 2010. In such areas, the prevailing cold climate, during the serpentinization, chloritization and epidotiization, the activity of the solvent, such as chloride, fluoride, carbonates, sulfide, sulfosalt would be able to import the elements such as magnesium and iron, copper and zinc into the soil and groundwater. The study area is located in northwestern Iran. This area is located in the northwest of the city of Khoy. Because of the proximity to the north and northwest Khoy plains with ophiolite rocks, the soil of this region could possibly show the potential of contamination with heavy metals. Due to the toxicity and disease of unauthorized grades of these elements in groundwater in the study area, this study is focused on the more contaminated groundwater of the areas. Materials and methods In this study, over a period of 5 days, sampling from 42 water sources, including fountains, aqueducts, wells, piezometers and wells in operation, was performed. The container was washed with acid and then rinsed 3 times with the water sample. The pH and temperature of the water in the samples was measured in the field. Then to each of the samples was taken from 2 to 5 ml of concentrated nitric acid (This causes that the metal elements would not adsorbed or precipitated by these particles and pH of the samples was measured with litmus paper to reach level 2. This was done to ensure the consolidation of the water samples. Analysis of

  1. 26 CFR 1.1081-3 - Exchanges of stock or securities solely for stock or securities.


    ... 26 Internal Revenue 11 2010-04-01 2010-04-01 true Exchanges of stock or securities solely for stock or securities. 1.1081-3 Section 1.1081-3 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF... § 1.1081-3 Exchanges of stock or securities solely for stock or securities. The exchange, without...

  2. Transport of nonlinearly biodegradable contaminants in aquifers

    Keijzer, H.


    This thesis deals with the transport behavior of nonlinearly biodegradable contaminants in aquifers. Such transport occurs during in situ bioremediation which is based on the injection of an electron acceptor or electron donor. The main interests in this thesis are the mutual influences of underlying processes, i.e. transport, adsorption and biodegradation, and their influence on in situ bioremediation performance. To gain insight in these influences, the processes in a homogeneous aquifer ar...

  3. The Maryland Coastal Plain Aquifer Information System: A GIS-based tool for assessing groundwater resources

    Andreasen, David C.; Nardi, Mark R.; Staley, Andrew W.; Achmad, Grufron; Grace, John W.


    Groundwater is the source of drinking water for ∼1.4 million people in the Coastal Plain Province of Maryland (USA). In addition, groundwater is essential for commercial, industrial, and agricultural uses. Approximately 0.757 × 109 L d–1 (200 million gallons/d) were withdrawn in 2010. As a result of decades of withdrawals from the coastal plain confined aquifers, groundwater levels have declined by as much as 70 m (230 ft) from estimated prepumping levels. Other issues posing challenges to long-term groundwater sustainability include degraded water quality from both man-made and natural sources, reduced stream base flow, land subsidence, and changing recharge patterns (drought) caused by climate change. In Maryland, groundwater supply is managed primarily by the Maryland Department of the Environment, which seeks to balance reasonable use of the resource with long-term sustainability. The chief goal of groundwater management in Maryland is to ensure safe and adequate supplies for all current and future users through the implementation of appropriate usage, planning, and conservation policies. To assist in that effort, the geographic information system (GIS)–based Maryland Coastal Plain Aquifer Information System was developed as a tool to help water managers access and visualize groundwater data for use in the evaluation of groundwater allocation and use permits. The system, contained within an ESRI ArcMap desktop environment, includes both interpreted and basic data for 16 aquifers and 14 confining units. Data map layers include aquifer and ­confining unit layer surfaces, aquifer extents, borehole information, hydraulic properties, time-series groundwater-level data, well records, and geophysical and lithologic logs. The aquifer and confining unit layer surfaces were generated specifically for the GIS system. The system also contains select groundwater-quality data and map layers that quantify groundwater and surface-water withdrawals. The aquifer

  4. The comparison of nitrogen use and leaching in sole cropped versus intercropped pea and barley

    Hauggaard-Nielsen, H.; Ambus, P.; Jensen, E.S.


    The effect of sole and intercropping of field pea (Pisum sativum L.) and spring barley (Hordeum vulgare L.) and of crop residue management on crop yield, NO3- leaching and N balance in the cropping system was tested in a 2-year lysimeter experiment on a temperate sandy loam soil. The crop rotation...... was pea and barley sole and intercrops followed by winter-rye and a fallow period. The Land Equivalent Ratio (LER), which is defined as the relative land area under sole crops that is required to produce the yields achieved in intercropping, was used to compare intercropping performance relative to sole...... from the sole cropped pea and barley lysimeters. Soil N balances indicated depletion of N in the soil-plant system during the experimental period, independent of cropping system and residue management. N complementarity in the cropping system and the synchrony between residual N availability and crop N...

  5. Aquifer performance under the Mactaquac Dam

    Tawil, A.H. [Acres International, Niagara Falls, ON (Canada); Harriman, F.B. [New Brunswick Power, Fredericton, NB (Canada)


    The highest dam in the whole of the Maritimes and New Brunswick in particular is the Mactaquac Dam, with a height of 58 m above the foundation. It forms an integral part of the Mactaquac Hydroelectric Development and the construction of the dam was completed in 1967. Composed of a central core of clay till and external shells of rockfill, it is a zoned embankment. The high artesian pressure rising 6 m above the Saint John River dominates, and the foundation under the dam is composed of a stratum of stiff glacial till underlain with a thick, water bearing aquifer. The aquifer needed to be depressurized during the construction phase and in the long term, and special measures were required to accomplish this. Measurements obtained over a period exceeding 30 years were used to describe the performance of the aquifer, which is discussed in this presentation. A continuous reduction in the yield from the six permanent relief wells in the aquifer was indicated by the instrumentation data. The outflow from the wells diminished by two-thirds over the thirty-four years since first filling the reservoir. The piezometric pressure in the aquifer remained constant over the same period. The sparse results of a two-hour pump test had formed the basis for the design decision not to install a costly foundation seepage cut-off to bedrock, as the conclusions drawn from the pump test were that the aquifer was hydrogeologically confined. 3 refs., 4 tabs., 9 figs.

  6. Digital data sets that describe aquifer characteristics of the Elk City Aquifer in western Oklahoma

    Becker, C.J.; Runkle, D.L.; Rea, Alan


    ARC/INFO export and nonproprietary format files This diskette contains digitized aquifer boundaries and maps of hydraulic conductivity, recharge, and ground-water level elevation contours for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately 193,000 acres and supplies ground water for irrigation, domestic, and industrial purposes in Beckham, Custer, Roger Mills, and Washita Counties along the divide between the Washita and Red River basins. The Elk City aquifer consists of the Elk City Sandstone and overlying terrace deposits, made up of clay, silt, sand and gravel, and dune sands in the eastern part and sand and gravel of the Ogallala Formation (or High Plains aquifer) in the western part of the aquifer. The Elk City aquifer is unconfined and composed of very friable sandstone, lightly cemented with clay, calcite, gypsum, or iron oxide. Most of the grains are fine-sized quartz but the grain size ranges from clay to cobble in the aquifer. The Doxey Shale underlies the Elk City aquifer and acts as a confining unit, restricting the downward movement of ground water. All of the data sets were digitized and created from information and maps in a ground-water modeling thesis and report of the Elk City aquifer. The maps digitized were published at a scale of 1:63,360. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data.

  7. Strontium Isotopes and Major and Minor Elements in Groundwater from the Shallow Aquifers of Southeastern North Carolina

    Woods, T. L.; Hedges, E. L.; McCorkle, D. C.; Gramling, C. M.; Mulligan, A. E.; Fullagar, P. D.


    Following sampling in July, 2000, analyses of water samples from aquifers, tidal creeks, rivers, and springs in southeastern NC were added to a growing database as part of an effort to develop geochemical methods to: 1) characterize water from various groundwater and surface water reservoirs, 2) quantify groundwater discharge into estuaries and the coastal ocean, and 3) investigate saltwater intrusion into coastal aquifers. Communities in the rapidly developing region already rely heavily on groundwater from shallow limestone and calcareous sandstone aquifers like the Tertiary Castle Hayne (CH) and Cretaceous Peedee (PD). Groundwater in both aquifers is Ca- and HCO3-rich. Although major element chemistries of groundwater from different aquifers vary, strontium isotopic signatures, which change systematically with the age of aquifer materials, may prove particularly distinctive.87Sr/86Sr values for water from the CH and PD in the study area range from 0.70874-0.70909 and 0.70806 - 0.70944, respectively. 87Sr/86Sr values in the Surficial aquifer (0.70844-0.71049) show the greatest variation. Ratios of spring waters (0.70878-0.70887) suggest flow through limestones. Water from the Northeast Cape Fear River is generally characterized by decreasing 87Sr/86Sr ratios (0.70916-0.70984) and increasing strontium concentrations (0.0360-2.632) downstream. Downgradient changes in Sr-isotopes in groundwater in the study area are not yet well-constrained. However, north of the study area previous data indicate that 87Sr/86Sr for CH groundwater decreases downdip; deviations from this pattern seem to indicate intermixing of surface water or groundwater from other aquifers. Chemical characterization of water from various sources, combined with geochemical modeling and statistical analysis should permit estimation of volumes of water moving in and out of important aquifers.

  8. Contribution of the aquitard to the regional groundwater hydrochemistry of the underlying confined aquifer in the Pearl River Delta, China.

    Wang, Ya; Jiao, Jiu Jimmy; Cherry, John A; Lee, Chun Ming


    Aquitards are capable of generating and preserving large amounts of chemicals. The release of the chemicals from the aquitards poses a potential contamination risk to groundwater that may be used as a drinking water source. This work aimed to identify the contribution of hydrogeochemical processes in the aquitards to groundwater hydrochemistry in the underlying confined basal aquifer by studying the coastal Quaternary aquifer-aquitard system of the Pearl River Delta, China. The system was submerged by paleo-seawater in the early Holocene and mainly receives infiltration of precipitation at present, as indicated by investigations on stable isotopes (δ(2)H, δ(18)O), water chemistry (SO4(2-) and Cl(-)) and salinity. Significant correlations between total dissolved solids in the basal aquifer and the thickness of the overlying aquitard further suggested the contribution of the aquitard to the groundwater hydrochemistry in the aquifer. Significant correlations between the chloride concentrations in aquitard porewater and that in groundwater in the aquifer, and between the thickness of the aquitard and the chloride concentrations in groundwater indicated the strong influence of the aquitard on the chloride in the aquifer. This is probably because the low-permeability aquitard is capable of preserving the paleo-seawater in the aquifer and releasing the salinity from the aquitard down to the aquifer via downward flow or diffusion. Isotopic and geochemical studies revealed that the aquitard is also responsible for generating and preserving large amounts of naturally occurring ammonium. Analysis between the concentrations of ammonium in groundwater in the basal aquifer and the total available ammonium in aquitard sediments suggested that the former is significantly controlled by the latter.

  9. Status of Groundwater Levels and Storage Volume in the Equus Beds Aquifer Near Wichita, Kansas, January 2009

    Hansen, Cristi V.


    Beginning in the 1940s, the Wichita well field was developed in the Equus Beds aquifer in southwestern Harvey County and northwestern Sedgwick County to supply water to the city of Wichita (Williams and Lohman, 1949). In addition to supplying drinking water to the largest city in Kansas, the other primary use of water from the Equus Beds aquifer is to irrigate crops in this agriculture-dominated part of south-central Kansas (Rich Eubank, Kansas Department of Agriculture, Division of Water Resources, oral commun., 2008). The decline of water levels in the aquifer were noted soon after the development of the Wichita well field began (Williams and Lohman, 1949). As water levels in the aquifer decline, the volume of water stored in the aquifer decreases and less water is available to supply future needs. For many years the U.S. Geological Survey (USGS), in cooperation with the city of Wichita, has monitored these changes in water levels and the resulting changes in storage volume in the Equus Beds aquifer as part of Wichita's effort to effectively manage this resource. In 2007, the city of Wichita began using Phase I of the Equus Beds Aquifer Storage and Recovery (ASR) project for large-scale artificial recharge of the Equus Beds aquifer. The ASR project uses water from the Little Arkansas River - either pumped from the river directly or from wells in the riverbank that obtain their water from the river by induced infiltration - as the source of artificial recharge to the Equus Beds aquifer (City of Wichita, 2009).

  10. Natural attenuation of inorganic pollutants (copper, sulfate) in the aquifer below an industrial site

    Bourg, A. C. M.; Kedziorek, M. A. M.


    The contamination of soils and aquifers by inorganic pollutants is so widespread in industrial sites that it does not seem economically feasible to decontaminate the large areas or soil volumes involved. It is therefore interesting to investigate whether the local environment is capable to attenuate this contamination. Natural attenuation by degradation seems realistic for many organic pollutants. Here we show that it can take place also for inorganic pollutants. The phreatic fill aquifer underlying an industrial plant located on the river banks of the Garonne River is contaminated by acidic water (pH down to 1) and high concentrations of sulfate (up to 50 g/L) and copper (up to 30 g/L). As acid water, rich in Cu and sulfate. migrates away from the contamination source, pH increases due to buffering of aquifer solids, dissolved Cu concentrations decrease by 6 orders of magnitude, while sulfate concentrations decrease little.

  11. Distribution of arsenic concentrations in groundwater of the Seymour Aquifer, Texas, USA.

    Hudak, Paul F


    The purpose of this study was to investigate arsenic concentrations in the Seymour Aquifer. Discontinuous alluvium of the aquifer occupies a broad, semi-arid region of northern Texas, USA. Throughout the formation's outcrop, permeable deposits and unconfined conditions may facilitate downward travel of contaminants applied to the land surface. Past agricultural practices are a potential source of arsenic to the aquifer. However, of 64 water samples analyzed from 2001-2004, only one exceeded the maximum contaminant level (MCL) of 10 microg/l for arsenic in drinking water. The median arsenic concentration was 2.7 microg/l, and 34% of samples had arsenic concentrations less than 2 microg/l. No relationship between arsenic concentration and well depth was observed.

  12. Hydrogeochemical processes in the Plio-Quaternary Remila aquifer (Khenchela, Algeria)

    Aouidane, Laiche; Belhamra, Mohamed


    The Remila Plain is a synclinal structure in northeast Algeria, situated within a semi-arid climate zone and composed of Mio-Pliocene-Quaternary deposits. Within the syncline, the Plio-Quaternary aquifer is the main source of drinking water for cattle and for agricultural irrigation water. This work aims to investigate the origin of groundwater mineralization and to identify the primary hydrogeochemical processes controlling groundwater evolution in the Remila aquifer. A total of 86 water samples from boreholes were analyzed for major, minor and stable isotopes (18O, 2H) over three seasons: first during low water levels in 2013, second during high water levels in 2014 and third for stable isotopes during low water levels in 2015. The analysis showed that the aquifer is controlled by five principal geochemical processes: (I) the dissolution of evaporite rocks, (II) cation exchange and reverse exchange reactions, (III) congruent dissolution of carbonates (calcite, dolomite) coupled with the dissolution of gypsum and calcite precipitation, (IV) sulfate reduction under anaerobic conditions, and (V) saltwater intrusion in the northeastern Sabkha plains. The 18O and deuterium concentrations in groundwater are very low, indicating that the aquifer is recharged by evaporated rainfall originating from the north slope of the Aurès Mountains which confirms that the aquifer is recharged in the southern part of the plain.

  13. The complete mitochondrial genome of the Senegal sole, Solea senegalensis Kaup. Comparative analysis of tandem repeats in the control region among soles.

    Manchado, Manuel; Catanese, Gaetano; Ponce, Marian; Funes, Victoria; Infante, Carlos


    The complete nucleotide sequence of the mitochondrial genome for the Senegal sole Solea senegalensis Kaup was determined. The mitochondrial DNA was 16,659 base pairs (bp) in length. Sequence features of the 13 protein-coding genes, two ribosomal RNAs and 22 transfer RNAs are described. The non-coding control region (1017 bp) was compared with those of the closely related soles Solea solea and Solea lascaris. The typical conservative blocks were identified. A cluster of 42 and 22 tandemly arrayed repeats was detected near the 3' end of control region in S. solea and S. lascaris, respectively. On the contrary, only two (93.8% of haplotypes) or three copies (6.2%) of an 8-bp repeated sequence motif was found in S. senegalensis. Phylogenetic analysis showed that 7 out of 9 of haplotypes bearing three copies grouped in a separate cluster. Possible mechanisms influencing the evolution of control region among soles are discussed.

  14. Characterisation of organic matter associated with groundwater arsenic in reducing aquifers of southwestern Taiwan.

    Al Lawati, Wafa M; Jean, Jiin-Shuh; Kulp, Thomas R; Lee, Ming-Kuo; Polya, David A; Liu, Chia-Chuan; van Dongen, Bart E


    Arsenic (As) in groundwaters extensively used by people across the world constitutes a serious public health threat. The importance of organic matter (OM) as an electron donor in microbially-mediated reduction of As(V) or Fe(III)-bearing As-host minerals leading to mobilisation of solid-phase arsenic is widely recognised. Notwithstanding this, there are few studies characterising OM in such aquifers and, in particular, there is a dearth of data from the classic arsenic bearing aquifers in southwestern Taiwan. Organic geochemical analyses of sediments from a known groundwater arsenic hot-spot in southwestern Taiwan revealed contributions of thermally mature and plant derived origin, consistent with OM sources in all other Asian groundwater aquifer sediments analysed to date, indicating comparable sources and routes of OM transfer. The combined results of amended As(V) reduction assays with the organic geochemical analysis revealed that the microbiological process of dissimilatory As(V) reduction is active in this aquifer, but it is not controlled by a specific source of analysed OM. These indicate that (i) part of the OM that was considered to be less bio-available could still be used as an electron donor or (ii) other electron donors, not analysed in present study, could be controlling the rate of As release.

  15. Vertical Gradients in Water Chemistry and Age in the Northern High Plains Aquifer, Nebraska, 2003

    McMahon, P.B.; Böhlke, J.K.; Carney, C.P.


    The northern High Plains aquifer is the primary source of water used for domestic, industrial, and irrigation purposes in parts of Colorado, Kansas, Nebraska, South Dakota, and Wyoming. Despite the aquifer's importance to the regional economy, fundamental ground-water characteristics, such as vertical gradients in water chemistry and age, remain poorly defined. As part of the U.S. Geological Survey's National Water-Quality Assessment Program, water samples from nested, short-screen monitoring wells installed in the northern High Plains aquifer were analyzed for major ions, nutrients, trace elements, dissolved organic carbon, pesticides, stable and radioactive isotopes, dissolved gases, and other parameters to evaluate vertical gradients in water chemistry and age in the aquifer. Chemical data and tritium and radiocarbon ages show that water in the aquifer was chemically and temporally stratified in the study area, with a relatively thin zone of recently recharged water (less than 50 years) near the water table overlying a thicker zone of older water (1,800 to 15,600 radiocarbon years). In areas where irrigated agriculture was an important land use, the recently recharged ground water was characterized by elevated concentrations of major ions and nitrate and the detection of pesticide compounds. Below the zone of agricultural influence, major-ion concentrations exhibited small increases with depth and distance along flow paths because of rock/water interactions. The concentration increases were accounted for primarily by dissolved calcium, sodium, bicarbonate, sulfate, and silica. In general, the chemistry of ground water throughout the aquifer was of high quality. None of the approximately 90 chemical constituents analyzed in each sample exceeded primary drinking-water standards. Mass-balance models indicate that changes in ground-water chemistry along flow paths in the aquifer can be accounted for by small amounts of feldspar and calcite dissolution; goethite and

  16. Radial Dupuit interface flow to assess the aquifer storage and recovery potential of saltwater aquifers

    Bakker, M.


    A new accurate numerical solution is presented for aquifer storage and recovery (ASR) systems in coastal aquifers; flow is approximated as radial Dupuit interface flow. The radial velocities of points on the interface are a function of time, the vertical coordinate, and the dimensionless parameter D

  17. Mexicali aquifer and its relation with the Colorado river and the Cerro Prieto geothermal reservoir

    Ramirez-Hernandez, J.; Reyes-Lopez, J. A.; Carreon-Diazconti, C.; Lazaro-Mancilla, O.


    Until some years ago the Colorado River has been the main recharge source of the Mexicali and the Imperial Valley aquifers. River discharge interruption after the constructions of dams upstream (i.e. Parker, Davis and Hoover) and the creation of great irrigation systems in both Valleys have modified their dynamics. Currently, the distribution of water recharge is the network of irrigation and drainage channels that distribute water to more than 500.000 ha. The chemical quality of the recharge water also has changed because the irrigation run-off water has become more mineralized. On the other hand, the intense steam exploitation of the Cerro Prieto geothermal reservoir has inverted the flow direction from the Volcano Lagoon area that until the 60s constituted the discharge zone of the aquifer and the geothermal reservoir. In this work, changes in the aquifer water recharge regime, the phreatic level and the water chemical quality are analyzed. It was found that after the reduction of the annual water extraction from aquifer up to 750X106 m3, the static levels have reached a dynamic balance that could be altered if water seepage from the irrigation channels, specially from the All American Channel, is reduced. The total dissolved solids (TDS) concentration has increased from 1000 ppm in 1970 to 1800 ppm in 2005. The water of recent infiltration, the gradual cooling of the shallowest strata of the geothermal reservoir, and the almost total disappearance of the hydrothermal surface manifestations are evidences of groundwater flow inversion. The new source of groundwater recharge due to seepage of evaporation disposal geothermal brine pond is documented. This pond incorporates water with a very different chemical composition to the groundwater system. Therefore, mineralization of the shallow aquifer layers and the soil contamination process are identified. It was concluded that the aquifer hydrodynamics in the Valley of Mexicali depends on the irrigation system more

  18. Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

    Fram, Miranda S.; Maurer, Douglas K.; Lico, Michael S.


    Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest

  19. Monitoring induced denitrification in an artificial aquifer recharge system.

    Grau-Martinez, Alba; Torrentó, Clara; Folch, Albert; Domènech, Cristina; Otero, Neus; Soler, Albert


    As demands on groundwater increase, artificial recharge is becoming a common method for enhancing groundwater supply. The Llobregat River is a strategic water supply resource to the Barcelona metropolitan area (Catalonia, NE Spain). Aquifer overexploitation has leaded to both a decrease of groundwater level and seawater intrusion, with the consequent deterioration of water quality. In the middle section of the aquifer, in Sant Vicenç del Horts, decantation and infiltration ponds recharged by water from the Llobregat River (highly affected from wastewater treatment plant effluents), were installed in 2007, in the framework of the ENSAT Life+ project. At the bottom of the infiltration pond, a vegetal compost layer was installed to promote the growth of bacteria, to induce denitrification and to create favourable conditions for contaminant biodegradation. This layer consists on a mixture of compost, aquifer material, clay and iron oxide. Understanding the fate of contaminants, such as nitrate, during artificial aquifer recharge is required to evaluate the impact of artificial recharge in groundwater quality. In order to distinguish the source of nitrate and to evaluate the capability of the organic reactive layer to induce denitrification, a multi-isotopic approach coupled with hydrogeochemical data was performed. Groundwater samples, as well as river samples, were sampled during artificial and natural recharge periods. The isotopic analysis included: δ15N and δ18O of dissolved nitrate, δ34S and δ18O of dissolved sulphate, δ13C of dissolved inorganic carbon, and δ2H and δ18O of water. Dissolved nitrate isotopic composition (δ15NNO3 from +9 to +21 o and δ18ONO3 from +3 to +16 ) demonstrated that heterotrophic denitrification induced by the reactive layer was taking place during the artificial recharge periods. An approximation to the extent of nitrate attenuation was calculated, showing a range between 95 and 99% or between 35 and 45%, by using the extreme

  20. Water-level trends and potentiometric surfaces in the Nacatoch Aquifer in northeastern and southwestern Arkansas and in the Tokio Aquifer in southwestern Arkansas, 2014–15

    Rodgers, Kirk D.


    The Nacatoch Sand in northeastern and southwestern Arkansas and the Tokio Formation in southwestern Arkansas are sources of groundwater for agricultural, domestic, industrial, and public use. Water-level altitudes measured in 51 wells completed in the Nacatoch Sand and 42 wells completed in the Tokio Formation during 2014 and 2015 were used to create potentiometric-surface maps of the two areas. Aquifers in the Nacatoch Sand and Tokio Formation are hereafter referred to as the Nacatoch aquifer and the Tokio aquifer, respectively.Potentiometric surfaces show that groundwater in the Nacatoch aquifer flows southeast toward the Mississippi River in northeastern Arkansas. Groundwater flow direction is towards the south and southeast in Hempstead, Little River, and Nevada Counties in southwestern Arkansas. An apparent cone of depression exists in southern Clark County and likely alters groundwater flow from a regional direction toward the depression.In southwestern Arkansas, potentiometric surfaces indicate that groundwater flow in the Tokio aquifer is towards the city of Hope. Northwest of Hope, an apparent cone of depression exists. In southwestern Pike, northwestern Nevada, and northeastern Hempstead Counties, an area of artesian flow (water levels are at or above land surface) exists.Water-level changes in wells were identified using two methods: (1) linear regression analysis of hydrographs from select wells with a minimum of 20 years of water-level data, and (2) a direct comparison between water-level measurements from 2008 and 2014–15 at each well. Of the six hydrographs analyzed in the Nacatoch aquifer, four indicated a decline in water levels. Compared to 2008 measurements, the largest rise in water levels was 35.14 feet (ft) in a well in Clark County, whereas the largest decline was 14.76 ft in a well in Nevada County, both located in southwestern Arkansas.Of the four hydrographs analyzed in the Tokio aquifer, one indicated a decline in water levels, while

  1. Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

    Izbicki, John A.; Petersen, Christen E.; Glotzbach, Kenneth J.; Metzger, Loren F.; Christensen, Allen H.; Smith, Gregory A.; O'Leary, David R.; Fram, Miranda S.; Joseph, Trevor; Shannon, Heather


    About 1.02 x 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94-137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 x 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with freechlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction

  2. A dynamic perennial firn aquifer

    Kohler, J.; Christianson, K.; van Pelt, W. J. J.


    Ice-penetrating radar and GPS observations are used to reveal a perennial firn aquifer (PFA) on a high icefield in Svalbard. This PFA appears to be fully analogous to those found in Greenland. A bright, widespread radar reflector separates relatively dry and water-saturated firn. This surface, the phreatic firn water table, is deeper beneath local surface elevation maxima, shallower in surface lows, and steeper where the surface is steep. The PFA is recharged by downward percolation of near-surface meltwater, and drained by flow subparallel to ice flow and the glacier surface. The water table of the PFA rises with increasing meltwater supply during summer, especially during warm years, and drops during winter. The reflector cross-cuts snow stratigraphy; we use the apparent deflection of accumulation layers due to the higher dielectric permittivity below the water table to infer that the firn pore space becomes progressively more saturated as depth increases. Radar data collected over several years indicate that the PFA responds rapidly (sub-annually) to the surface melt forcing. We use a coupled surface energy-balance and firn model, forced with from regional climate model data for the years 1961-2012, to estimate the amount of retained surface melt available to recharge the PFA. Results suggest that the water amount flowing into and out of the PFA is substantial, such that the PFA is capable of providing significant input to the englacial hydrology system.

  3. Review of Aquifer Storage and Recovery Performance in the Upper Floridan Aquifer in Southern Florida

    Reese, Ronald S.


    Introduction: Interest and activity in aquifer storage and recovery (ASR) in southern Florida has increased greatly during the past 10 to 15 years. ASR wells have been drilled to the carbonate Floridan aquifer system at 30 sites in southern Florida, mostly by local municipalities or counties located in coastal areas. The primary storage zone at these sites is contained within the brackish to saline Upper Floridan aquifer of the Floridan aquifer system. The strategy for use of ASR in southern Florida is to store excess freshwater available during the wet season in an aquifer and recover it during the dry season when needed for supplemental water supply. Each ASR cycle is defined by three periods: recharge, storage, and recovery. This fact sheet summarizes some of the findings of a second phase retrospective assessment of existing ASR facilities and sites.

  4. Effects of redox conditions on the control of arsenic mobility in shallow alluvial aquifers on the Venetian Plain (Italy).

    Carraro, A; Fabbri, P; Giaretta, A; Peruzzo, L; Tateo, F; Tellini, F


    The Venetian Plain is known for the occurrence of areas with high concentrations of arsenic in groundwater (greater than 400 μg/L). The study area represents the typical residential, industrial and agricultural features of most Western countries and is devoid of hydrothermal, volcanic or anthropogenic sources of arsenic. The aim of the study is to model the arsenic mobilization and the water-rock interaction by a complete hydrogeochemical investigation (analyses of filtered and unfiltered groundwater sediment mineralogy and geochemistry). The groundwater arsenic contamination and redox conditions are highly variable. Groundwaters with oxidizing and strongly reducing potentials have much lower arsenic concentrations than do mildly reducing waters. The grain size of the aquifer sediments includes gravels, sands and silty-clays. A continuous range of organic material concentrations is observed (from zero to 40%). The amount of sedimentary organic matter is highly correlated with the arsenic content of the sediments (up to 300 mg/kg), whereas no relationships are detectable between arsenic and other chemical parameters. The occurrence of arsenic minerals was observed as a peculiar feature under the scanning electron microscope. Arsenic and sulfur are the sole constituents of small tufts or thin crystals concentrated in small masses. These arsenic minerals were clearly observed in the peat sediments, in agreement with the geochemical modeling that requires very reducing conditions for their precipitation from the groundwater. The modeling suggests that, under oxidizing conditions, arsenic is adsorbed; moreover, a continuous decrease in the redox potential causes increasing desorption of arsenic. If the reducing conditions become more intense, the formation of As-S minerals would explain the lower concentration of arsenic measured in the strongly reducing groundwater. Even if As-sulfides are rare under low-temperature conditions, the anomalous abundance of reductants

  5. Bacterial diversity and community structure of a sub-surface aquifer exposed to realistic low herbicide concentrations

    Lipthay, Julia R. de; Johnsen, Kaare; Albrechtsen, H.-J.;


    contaminants. We examined the effect of in situ exposure to realistic low concentrations of herbicides on the microbial diversity and community structure of sub-surface sediments from a shallow aquifer near Vejen (Denmark). Three different community analyses were performed: colony morphology typing, sole......-surface aquifers to realistic low concentrations of herbicides may alter the overall structure of a natural bacterial community, although significant effects on the genetic diversity and carbon substrate usage cannot be detected. The observed impact was probably due to indirect effects. In future investigations......An increasing number of herbicides are found in our groundwater environments. This underlines the need for examining the effects of herbicide exposure on the indigenous groundwater microbial communities, as microbial degradation is the major process responsible for the complete removal of most...

  6. Sole means navigation and integrity through hybrid Loran-C and NAVSTAR GPS

    Vangraas, Frank


    A sole means navigation system does not only call for integrity, but also for coverage, reliability, availability and accuracy. Even though ground monitored GPS will provide integrity, availability is still not sufficient. One satellite outage can affect a large service area for several hours per day. The same holds for differential GPS; a total satellite outage cannot be corrected for. To obtain sufficient coverage, extra measurements are needed, either in the form of extra GPS satellites (expensive) or through redundant measurements from other systems. LORAN-C is available and will, hybridized with GPS, result in a system that has the potential to satisfy the requirements for a sole means navigation system for use in the continental United States. Assumptions are made about the qualification sole means, mainly based on current sole means systems such as VOR/DME. In order to allow for system design that will satisfy sole means requirements, it is recommended that a definition of a sole means navigation system be established. This definition must include requirements for availability, reliability, and integrity currently not specified. In addition to the definition of a sole means navigation system, certification requirements must be established for hybrid navigation systems. This will allow for design and production of a new generation of airborne navigation systems that will reduce overall system costs and simplify training procedures.

  7. Modelling Contributions of the Local and Regional Groundwater Flow of Managed Aquifer Recharge Activities at Querença-Silves Aquifer System.

    Costa, Luís; Monteiro, José Paulo; Oliveira, Manuel; Mota, Rogério; Lobo-Ferreira, João Paulo; Martins de Carvalho, José; Martins de Carvalho, Tiago; Agostinho, Rui; Hugman, Rui


    The Querença-Silves (QS) aquifer system is one of the most important natural groundwater reservoirs in the Algarve region of southern Portugal. With a surface area of 324 km2, this karst aquifer system is the main source of supply for irrigation as well as an important source of water for the urban supply. Due to the importance given to QS aquifer system by both governmental actors and end users, ongoing research during the last two decades at the University of Algarve has attempted to provide a better understanding of the hydrogeology and hydraulic behavior, which has resulted in the development of regional scale numerical models. The most recent hydrogeological data has been acquired during the ongoing MARSOL project (MARSOL-GA-2013-619120) which aims to demonstrate that Managed Aquifer Recharge (MAR) is a sound, safe and sustainable strategy that can be applied with great confidence in finding solutions to water scarcity in Southern Europe. Within the scope of the project large diameter well injection tests (with and without tracers) as well as geophysical surveys have been carried out in order to determine the infiltration capacity and aquifer properties. The results of which allowed the use of analytical methods to determine local scale values of hydraulic parameters (e.g. hydraulic conductivity and storage coefficient). These values will be compared with results from pre-existing numerical flow and transport models in order to obtain complementary solutions to the problem at local and regional scales. This analysis will contribute to the selection of the most appropriate methods to interpret, reproduce and model the impacts of MAR activities planned within the scope of the MARSOL project. Subsequent to the planned injection tests and, with the support of modelling efforts, the capacity of infiltration of rejected water from water treatment plants or surface storage dams in the large diameter well will be assessed.

  8. Tracing of Recharge Sources of Deep Aquifers in the Concealed Type Colliery of North China by Hydrochemistry and Isotopes%华北隐伏型煤矿深部含水层补给源水化学与同位素示踪

    陈陆望; 殷晓曦; 刘鑫


    为了阐明华北隐伏型煤矿深部含水层补给条件,以淮北煤田临涣矿区任楼煤矿为例,采用水化学系统聚类分析与氢氧同位素示踪技术,结合采矿活动影响,分析与探讨煤矿深部含水层中的地下水补给源及其变化机制.研究表明:矿区深层地下水形成机制为大气降水直接但不均匀入渗、滞留入渗以及古地下水混合.矿区深层地下水当总溶解固体(TDS)小于1 000 mg/L时,氢氧稳定同位素组成(δ值)随着TDS的增大而减小;当TDS大于1 000 mg/L时,δ值在平均值线附近.矿区深层地下水平均δD与δ18O分别为-67.4‰与-8.68‰,小于大气降水年平均δD与δ18O(δD=-52.4‰,δ18O=-7.80‰).在未经采矿活动影响下,矿区深层地下水主要来源于大气降水直接但不均匀入渗补给形成的;经采矿活动影响后深部含水层长期向采空区充水,原地下水循环条件已被打破,在补给区水力交替加快,滞留于地表或土壤层的大气降水补给深部含水层.%In order to find out the recharge condition in deep aquifers in the concealed type colliery in the north of China,taking Renlou colliery and the local Linhuan coal-mining district for example,hydrochemical systemic cluster analysis and hydrogen and oxygen isotopes tracing were carried out to discuss and analyze the recharge sources and its changing mechanism in the deep aquifers under the influence of mining activities.The deep groundwater of the coal-mining district was composed of direct but nonuniform infiltration and retention infiltration of precipitation and ancient underground water.In the case of TDS of deep groundwater at less than 1 000 mg/L,the δ values of stable hydrogen (D) and oxygen isotopes (18O) decreased with the increase of TDS in the coal-mining district.However,in the case of TDS of deep groundwater at higher than 1 000 mg/L,the δ values were around the average ones.In addition,the average δ values of D and 18O were-67.4‰ and

  9. Multidepth pumping tests in deep aquifers.

    Alam, N; Olsthoorn, T N


    Multidepth pumping tests (MDPTs), in which different sections of a screen are pumped in sequence, are not being used by hydrogeologists, despite the capability of such tests to resolve uncertainties in the estimation of aquifer characteristics. MDPTs can be used to discern the effects of partial penetration and vertical anisotropy. This article demonstrates the use of MDPTs for a deep and vertically anisotropic aquifer, based on a real and unique series of pumping tests conducted in the Indus Basin. Traditional single-layer methods, which incorporate partial penetration and vertical scaling, were employed to evaluate these tests. However, the drawdowns of the 19 piezometers at different depths for which times series data were available could not be matched, presumably because of the layered structure of the aquifer. Numerical (MODFLOW) and multilayer analytical (Hemker and Maas 1987; Hemker 1999) approaches were used to assess the benefits of using MDPTs in the analysis of deep layered and anisotropic aquifers. The multilayer analytical solution results are consistent with the measured and numerically computed drawdowns. The original step-drawdown data were used to verify the model independently. The results of statistical analyses indicate that the parameters for a three-layer system are uniquely estimated. A sensitivity analysis showed that aquifer depths greater than 900 m do not affect the drawdown. The multilayer analytical solution was implemented in MATLAB and can be found in the online version of this article. This multilayer analytical approach was implemented in MLU by Hemker and Randall (2013) for up to 40 layers. The results of this study will be useful in groundwater management, exploration, and optimal well depth estimation for the Indus Basin aquifer and other vertically heterogeneous aquifers.

  10. Stochastic analysis of virus transport in aquifers

    Campbell, Rehmann L.L.; Welty, C.; Harvey, R.W.


    A large-scale model of virus transport in aquifers is derived using spectral perturbation analysis. The effects of spatial variability in aquifer hydraulic conductivity and virus transport (attachment, detachment, and inactivation) parameters on large-scale virus transport are evaluated. A stochastic mean model of virus transport is developed by linking a simple system of local-scale free-virus transport and attached-virus conservation equations from the current literature with a random-field representation of aquifer and virus transport properties. The resultant mean equations for free and attached viruses are found to differ considerably from the local-scale equations on which they are based and include effects such as a free-virus effective velocity that is a function of aquifer heterogeneity as well as virus transport parameters. Stochastic mean free-virus breakthrough curves are compared with local model output in order to observe the effects of spatial variability on mean one-dimensional virus transport in three-dimensionally heterogeneous porous media. Significant findings from this theoretical analysis include the following: (1) Stochastic model breakthrough occurs earlier than local model breakthrough, and this effect is most pronounced for the least conductive aquifers studied. (2) A high degree of aquifer heterogeneity can lead to virus breakthrough actually preceding that of a conservative tracer. (3) As the mean hydraulic conductivity is increased, the mean model shows less sensitivity to the variance of the natural-logarithm hydraulic conductivity and mean virus diameter. (4) Incorporation of a heterogeneous colloid filtration term results in higher predicted concentrations than a simple first-order adsorption term for a given mean attachment rate. (5) Incorporation of aquifer heterogeneity leads to a greater range of virus diameters for which significant breakthrough occurs. (6) The mean model is more sensitive to the inactivation rate of viruses

  11. Contribution of the aquitard to the regional groundwater hydrochemistry of the underlying confined aquifer in the Pearl River Delta, China

    Wang, Ya [Department of Earth Sciences, The University of Hong Kong, Hong Kong (China); Jiao, Jiu Jimmy, E-mail: [Department of Earth Sciences, The University of Hong Kong, Hong Kong (China); Cherry, John A. [School of Engineering, University of Guelph, Guelph, ON N1G 2W1 (Canada); Lee, Chun Ming [Department of Earth Sciences, The University of Hong Kong, Hong Kong (China)


    Aquitards are capable of generating and preserving large amounts of chemicals. The release of the chemicals from the aquitards poses a potential contamination risk to groundwater that may be used as a drinking water source. This work aimed to identify the contribution of hydrogeochemical processes in the aquitards to groundwater hydrochemistry in the underlying confined basal aquifer by studying the coastal Quaternary aquifer–aquitard system of the Pearl River Delta, China. The system was submerged by paleo-seawater in the early Holocene and mainly receives infiltration of precipitation at present, as indicated by investigations on stable isotopes (δ{sup 2}H, δ{sup 18}O), water chemistry (SO{sub 4}{sup 2−} and Cl{sup −}) and salinity. Significant correlations between total dissolved solids in the basal aquifer and the thickness of the overlying aquitard further suggested the contribution of the aquitard to the groundwater hydrochemistry in the aquifer. Significant correlations between the chloride concentrations in aquitard porewater and that in groundwater in the aquifer, and between the thickness of the aquitard and the chloride concentrations in groundwater indicated the strong influence of the aquitard on the chloride in the aquifer. This is probably because the low-permeability aquitard is capable of preserving the paleo-seawater in the aquifer and releasing the salinity from the aquitard down to the aquifer via downward flow or diffusion. Isotopic and geochemical studies revealed that the aquitard is also responsible for generating and preserving large amounts of naturally occurring ammonium. Analysis between the concentrations of ammonium in groundwater in the basal aquifer and the total available ammonium in aquitard sediments suggested that the former is significantly controlled by the latter. - Highlights: • Aquitard porewater components are similar to that of groundwater in the aquifer. • Influence of the aquitard on Cl{sup

  12. Science for informed decision: A 3D unified conceptual model of the Milk River Transboundary Aquifer (Alberta-Montana)

    Rivera, A.; Pétré, M.


    The Milk River transboundary aquifer straddles southern Alberta (Canada) and northern Montana (United States), in a semi-arid region considered water short. This confined sandstone aquifer is a source for municipal supply and agricultural uses on the Canadian side, as well as for secondary oil recovery on the US-side of the border. The extensive use of this resource since the mid 1950's has led to a dramatic drop in the water level in some places and concerns about the durability of the resource have risen. The Milk River aquifer has been the object of many studies during the 20th century; however most of them were limited by the USCanada border, preventing a sound understanding of the global dynamics of the aquifer. The objectives of this transboundary study are to better understand the dynamics of the Milk River aquifer, following its natural limits, in order to make recommendations for a sustainable management and its good governance by the two international jurisdictions, as recommended in the UNGA resolution 63/124 on the Law of Transboundary Aquifers. Since 2009, the Milk River transboundary aquifer is part of the inventory of UNESCO ISARM-Americas initiative, which encourages riparian states to work cooperatively toward mutually beneficial and sustainable aquifer development However, the use of this shared resource is not ruled by any international agreement or convention between the USA and the Canada. Stakeholders from the two countries have been involved, at various levels of jurisdictions (municipal, provincial, state, federal) to establish a strong cooperation. In these contexts, models can constitute useful tools for informed decisions. In the case of the Milk River aquifer, models could support scientists and managers from both countries in avoiding potential tensions linked to the water shortage context in this region. Models can determine the conditions of overexploitation and provide an assessment of a sustainable yield. A unified conceptual model

  13. Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system.

    Choung, Sungwook; Zimmerman, Lisa R; Allen-King, Richelle M; Ligouis, Bertrand; Feenstra, Stanley


    This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc=0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen+black carbon was the dominant CM fraction extracted from the sediments and accounted for >60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that >80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.

  14. Heterogeneous carbonaceous matter in sedimentary rock lithocomponents causes significant trichloroethylene (TCE) sorption in a low organic carbon content aquifer/aquitard system

    Choung, Sungwook; Zimmerman, Lisa R.; Allen-King, Richelle M.; Ligouis, Bertrand; Feenstra, Stanley


    This study evaluated the effects of heterogeneous thermally altered carbonaceous matter (CM) on trichloroethylene (TCE) sorption for a low fraction organic carbon content (foc) alluvial sedimentary aquifer and aquitard system (foc = 0.046-0.105%). The equilibrium TCE sorption isotherms were highly nonlinear with Freundlich exponents of 0.46-0.58. Kerogen + black carbon was the dominant CM fraction extracted from the sediments and accounted for > 60% and 99% of the total in the sands and silt, respectively. Organic petrological examination determined that the kerogen included abundant amorphous organic matter (bituminite), likely of marine origin. The dark calcareous siltstone exhibited the greatest TCE sorption among aquifer lithocomponents and accounted for most sorption in the aquifer. The results suggest that the source of the thermally altered CM, which causes nonlinear sorption, was derived from parent Paleozoic marine carbonate rocks that outcrop throughout much of New York State. A synthetic aquifer-aquitard unit system (10% aquitard) was used to illustrate the effect of the observed nonlinear sorption on mass storage potential at equilibrium. The calculation showed that > 80% of TCE mass contained in the aquifer was sorbed on the aquifer sediment at aqueous concentration < 1000 μg L- 1. These results show that sorption is likely a significant contributor to the persistence of a TCE groundwater plume in the aquifer studied. It is implied that sorption may similarly contribute to TCE persistence in other glacial alluvial aquifers with similar geologic characteristics, i.e., comprised of sedimentary rock lithocomponents that contain thermally altered CM.

  15. Water Quality in the Equus Beds Aquifer and the Little Arkansas River Before Implementation of Large-Scale Artificial Recharge, South-Central Kansas, 1995-2005

    Ziegler, Andrew C.; Hansen, Cristi V.; Finn, Daniel A.


    Artificial recharge of the Equus Beds aquifer using runoff from the Little Arkansas River in south-central Kansas was first proposed in 1956 and was one of many options considered by the city of Wichita to preserve its water supply. Declining aquifer water levels of as much as 50 feet exacerbated concerns about future water availability and enhanced migration of saltwater into the aquifer from past oil and gas activities near Burrton and from the Arkansas River. Because Wichita changed water-management strategies and decreased pumping from the Equus Beds aquifer in 1992, water storage in the aquifer recovered by about 50 percent. This recovery is the result of increased reliance on Cheney Reservoir for Wichita water supply, decreased aquifer pumping, and larger than normal precipitation. Accompanying the water-level recovery, the average water-level gradient in the aquifer decreased from about 12 feet per mile in 1992 to about 8 feet per mile in January 2006. An important component of artificial recharge is the water quality of the receiving aquifer and the water being recharged (source water). Water quality within the Little Arkansas River was defined using data from two real-time surface-water-quality sites and discrete samples. Water quality in the Equus Beds aquifer was defined using sample analyses collected at 38 index sites, each with a well completed in the shallow and deep parts of the Equus Beds aquifer. In addition, data were collected at diversion well sites, recharge sites, background wells, and prototype wells for the aquifer storage and recovery project. Samples were analyzed for major ions, nutrients, trace metals, radionuclides, organic compounds, and bacterial and viral indicators. Water-quality constituents of concern for artificial recharge are those constituents that frequently (more than 5 percent of samples) may exceed Federal [U.S. Environmental Protection Agency (USEPA)] and State drinking-water criteria in water samples from the receiving

  16. Aquifer geometry, lithology, and water levels in the Anza–Terwilliger area—2013, Riverside and San Diego Counties, California

    Landon, Matthew K.; Morita, Andrew Y.; Nawikas, Joseph M.; Christensen, Allen H.; Faunt, Claudia C.; Langenheim, Victoria E.


    The population of the Anza–Terwilliger area relies solely on groundwater pumped from the alluvial deposits and surrounding bedrock formations for water supply. The size, characteristics, and current conditions of the aquifer system in the Anza–Terwilliger area are poorly understood, however. In response to these concerns, the U.S. Geological Survey, in cooperation with the High Country Conservancy and Rancho California Water District, undertook a study to (1) improve mapping of groundwater basin geometry and lithology and (2) to resume groundwater-level monitoring last done during 2004–07 in the Anza–Terwilliger area. 

  17. 29 CFR 500.73 - Required purchase of goods or services solely from any person prohibited.


    ... DIVISION, DEPARTMENT OF LABOR REGULATIONS MIGRANT AND SEASONAL AGRICULTURAL WORKER PROTECTION Worker... migrant or seasonal agricultural worker to purchase goods or services solely from such farm labor... any person subject to this prohibition. Recruiting, Hiring and Providing Information to...

  18. AFSC/RACE/GAP/Nichol: Archival tag depth and temperature data from northern rock sole

    National Oceanic and Atmospheric Administration, Department of Commerce — Depth data from archival tags on northern rock sole (Lepidopsetta polyxystra) were examined to assess whether fish used tidal currents to aid horizontal migration....

  19. Effects of de-oiled palm kernel cake based fertilizers on sole maize ...



    Mar 8, 2012 ... formulations on the yield of sole maize and cassava crops. Two de-oiled palm ... cake, urea, muriate of potash and single super phosphate. Two separate ..... establishment of nitrogen fixing bacteria in the rhizosphere. Microb.

  20. Aquifers of Alluvial and Glacial Origin - Direct Download

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the alluvial and glacial aquifers north of the southern-most line of glaciation. Aquifers are shown in the States of Maine,...

  1. Snake River Plain Basin-fill aquifer system

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Snake River Plain aquifer system, which includes both the basaltic and basin-fill aquifers. This dataset does not...

  2. Water-level change, High Plains aquifer, 1980 to 1995

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 1980 to 1995, in feet. The High Plains aquifer underlies...

  3. Water-level change, High Plains aquifer, 1995 to 2000

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 1995 to 2000, in feet. The High Plains aquifer underlies...

  4. Water-level change, High Plains aquifer, 2005 to 2009

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 2005 to 2009, in feet. The High Plains aquifer underlies...

  5. Water-level change, High Plains aquifer, 2000 to 2005

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 2000 to 2005, in feet. The High Plains aquifer underlies...

  6. Effects of highway-deicer application on ground-water quality in a part of the Calumet Aquifer, northwestern Indiana

    Watson, Lee R.; Bayless, E. Randall; Buszka, Paul M.; Wilson, John T.


    The effects of highway-deicer application on ground-water quality were studied at a site in northwestern Indiana using a variety of geochemical indicators. Site characteristics such as high snowfall rates; large quantities of applied deicers; presence of a high-traffic highway; a homogeneous, permeable, and unconfined aquifer; a shallow water table; a known ground-water-flow direction; and minimal potential for other sources of chloride and sodium to complicate source interpretation were used to select a study area where ground water was likely to be affected by deicer application. Forty-three monitoring wells were installed in an unconfined sand aquifer (the Calumet aquifer) near Beverly Shores in northwestern Indiana. Wells were installed along two transects that approximately paralleled groundwater flow in the Calumet aquifer and crossed US?12. US?12 is a highway that receives Indiana?s highest level of maintenance to maintain safe driving conditions. Ground-water quality and water-level data were collected from the monitoring wells, and precipitation and salt-application data were compiled from 1994 through 1997. The water-quality data indicated that chloride was the most easily traced indicator of highway deicers in ground water. Concentration ratios of chloride to iodide and chloride to bromide and Stiff diagrams of major element concentrations indicated that the principal source of chloride and sodium in ground water from the uppermost one-third to one-half of the Calumet relative electromagnetic conductivity defined a distinct plume of deicer-affected water in the uppermost 8 feet of aquifer at about 9 feet horizontally from the paved roadway edge and a zone of higher conductivity than background in the lower one-third of the aquifer. Chloride and sodium in the deep parts of the aquifer originated from natural sources. Chloride and sodium from highway deicers were present in the aquifer throughout the year. The highest concentrations of chloride and sodium

  7. Amyotrophic Lateral Sclerosis Presenting Respiratory Failure as the Sole Initial Manifestation

    Fuyuki Tateno


    Full Text Available It is rare that amyotrophic lateral sclerosis (ALS presents with respiratory failure as the sole initial manifestation. A 72-year-old man with mild chronic obstructive pulmonary disease developed exertional dyspnea for 13 months. He then progressed to limb weakness that led to the diagnosis of ALS. Although rare, ALS can present with respiratory failure as the sole initial manifestation more than 1 year prior to limb weakness.

  8. Activation of peripheral nerve fibers by electrical stimulation in the sole of the foot

    Frahm, Ken Steffen; Mørch, Carsten Dahl; Grill, Warren M; Lubock, Nathan B; Hennings, Kristian; Andersen, Ole Kæseler


    Background Human nociceptive withdrawal reflexes (NWR) can be evoked by electrical stimulation applied to the sole of the foot. However, elicitation of NWRs is highly site dependent, and NWRs are especially difficult to elicit at the heel. The aim of the present study was to investigate potential peripheral mechanisms for any site dependent differences in reflex thresholds. Results The first part of the study investigated the neural innervation in different sites of the sole of the foot using...

  9. Genetic algorithms and aquifer parameter identification

    LI Jing-sheng(李竞生); YAO Lei-hua(姚磊华); LI Yang(李杨)


    In order to identify aquifer parameter,authors develops an improved combinatorial method called best chromosome clone plus younger generation chromosome prepotency genetic algorithm (BCC-YGCP-GA), based on a decimal system simple genetic algorithm (SGA). The paper takes unsteady state flows in a two-dimensional, inhomogeneous, confined aquifer for a ideal model, and utilizes SGA and BCC-YGCP-GA coupled to finite element method for identifying aquifer hydraulic conductivity K1,K2,K3 and storage S1,S2,S3, respectively. It is shown from the result that GSA does not reach convergence with 100 generations, whereas convergence rate of BCC-YGCD-GA is very fast. Objective function value calculated by BCC-YGCD-GA is 0.001 29 with 100 generations, and hydraulic conductivity and storage of three zones are almost equal to the "true" values of ideal model.

  10. Multi-tracer investigation of groundwater residence time in a karstic aquifer: Bitter Lakes National Wildlife Refuge, New Mexico, USA

    Land, Lewis; Huff, G. F.


    Several natural and anthropogenic tracers have been used to evaluate groundwater residence time within a karstic limestone aquifer in southeastern New Mexico, USA. Natural groundwater discharge occurs in the lower Pecos Valley from a region of karst springs, wetlands and sinkhole lakes at Bitter Lakes National Wildlife Refuge, on the northeast margin of the Roswell Artesian Basin. The springs and sinkholes are formed in gypsum bedrock that serves as a leaky confining unit for an artesian aquifer in the underlying San Andres limestone. Because wetlands on the Refuge provide habitat for threatened and endangered species, there is concern about the potential for contamination by anthropogenic activity in the aquifer recharge area. Estimates of the time required for groundwater to travel through the artesian aquifer vary widely because of uncertainties regarding karst conduit flow. A better understanding of groundwater residence time is required to make informed decisions about management of water resources and wildlife habitat at Bitter Lakes. Results indicate that the artesian aquifer contains a significant component of water recharged within the last 10-50 years, combined with pre-modern groundwater originating from deeper underlying aquifers, some of which may be indirectly sourced from the high Sacramento Mountains to the west.

  11. Analytical solutions of three-dimensional groundwater flow to a well in a leaky sloping fault-zone aquifer

    Zhao, Yuqing; Zhang, You-Kuan; Liang, Xiuyu


    A semi-analytical solution was presented for groundwater flow due to pumping in a leaky sloping fault-zone aquifer surrounded by permeable matrices. The flow in the aquifer was descried by a three-dimensional flow equation, and the flow in the upper and lower matrix blocks are described by a one-dimensional flow equation. A first-order free-water surface equation at the outcrop of the fault-zone aquifer was used to describe the water table condition. The Laplace domain solution was derived using Laplace transform and finite Fourier transform techniques and the semi-analytical solutions in the real time domain were evaluated using the numerical inverse Laplace transform method. The solution was in excellent agreement with Theis solution combined with superposition principle as well as the solution of Huang et al. (2014). It was found that the drawdown increases as the sloping angle of the aquifer increases in early time and the impact of the angle is insignificant after pumping for a long time. The free-water surface boundary as additional source recharges the fault aquifer and significantly affect the drawdown at later time. The surrounding permeable matrices have a strong influence on drawdown but this influence can be neglected when the ratio of the specific storage and the ratio of the hydraulic conductivity of the matrices to those of the fault aquifer are less than 0.001.

  12. Spatial and temporal changes in sulphate-reducing groundwater bacterial community structure in response to Managed Aquifer Recharge.

    Reed, D A; Toze, S; Chang, B


    The population dynamics of bacterial able to be cultured under sulphate reducing condition was studied in conjunction with changes in aquifer geochemistry using multivariate statistics for two contrasting Managed Aquifer Recharge (MAR) techniques at two different geographical locations (Perth, Western Australia and Adelaide, South Australia). Principal component analysis (PCA) was used to investigate spatial and temporal changes in the overall chemical signature of the aquifers using an array of chemical analytes which demonstrated a migrating geochemical plume. Denaturing Gradient Gel Electrophoresis (DGGE) using DNA from sulphate-reducing bacteria cultures was used to detect spatial and temporal changes in population dynamics. Bacterial and geochemical evidence suggested that groundwater at greatest distance from the nutrient source was least affected by treated effluent recharge. The results suggested that bacterial populations that were able to be cultured in sulphate reducing media responded to the migrating chemical gradient and to the changes in aquifer geochemistry. Most noticeably, sulphate-reducing bacterial populations associated with the infiltration galleries were stable in community structure over time. Additionally, the biodiversity of these culturable bacteria was restored when aquifer geochemistry returned to ambient conditions during the recovery phase at the Adelaide Aquifer Storage and Recovery site.

  13. Review of the general geology and solid-phase geochemical studies in the vicinity of the Central Oklahoma aquifer

    Mosier, Elwin L.; Bullock, John H.


    The Central Oklahoma aquifer is the principal source of ground water for municipal, industrial, and rural use in central Oklahoma. Ground water in the aquifer is contained in consolidated sedimentary rocks consisting of the Admire, Council Grove, and Chase Groups, Wellington Formation, and Garber Sandstone and in the unconsolidated Quaternary alluvium and terrace deposits that occur along the major stream systems in the study area. The Garber Sandstone and the Wellington Formation comprise the main flow system and, as such, the aquifer is often referred to as the 'Garber-Wellington aquifer.' The consolidated sedimentary rocks consist of interbedded lenticular sandstone, shale, and siltstone beds deposited in similar deltaic environments in early Permian time. Arsenic, chromium, and selenium are found in the ground water of the Central Oklahoma aquifer in concentrations that, in places, exceed the primary drinking-water standards of the Environmental Protection Agency. Gross-alpha concentrations also exceed the primary standards in some wells, and uranium concentrations are uncommonly high in places. As a prerequisite to a surface and subsurface solid-phase geochemical study, this report summarizes the general geology of the Central Oklahoma study area. Summaries of results from certain previously reported solid-phase geochemical studies that relate to the vicinity of the Central Oklahoma aquifer are also given; including a summary of the analytical results and distribution plots for arsenic, selenium, chromium, thorium, uranium, copper, and barium from the U.S. Department of Energy's National Uranium Resource Evaluation (NURE) Program.

  14. Hydrogeology of a zone of secondary permeability in the surficial aquifer of eastern Palm Beach County, Florida

    Swayze, L.J.; Miller, W.L.


    The surficial aquifer is the primary source of freshwater for the heavily developed coastal area in eastern Palm Beach County, Florida. Well fields are generally located in a discontinuous zone of higher secondary permeability, the northernmost extension of the Biscayne aquifer in the surficial aquifer, that extends from the Juno Beach area south to Broward County and varies in width from about 4 to 15 miles. The zone was formed by varying dissolution of aquifer limestone materials during Pleistocene age changes in sea level, and ranges in depth from about sea level to 220 feet below sea level. Because of proximity to the Atlantic Ocean and saltwater estuaries, the aquifer is susceptible to saltwater intrusion. Ground water to the west of the zone of higher secondary permeability is of poor quality. The ground water is calcium bicarbonate dominant. Dissolved solids, calcium carbonate hardness, and chloride are greatest along the saltwater intruded coastline and in the western part of the study area where diluted residual seawater exists. Total organic carbon increases inland due to infiltration of rainwater through thicker layers of organic soils. Ground-water levels in the surficial aquifer in eastern Palm Beach County are strongly influenced by controlled levels in canals. In March 1981, after 12 months of below average rainfall, ground-water levels ranged from about 2 feet above sea level along the coast to nearly 21 feet above sea level 15 miles inland in the northwest section of the study area. (USGS)

  15. Evaluation of long-term water-level declines in basalt aquifers near Mosier, Oregon

    Burns, Erick R.; Morgan, David S.; Lee, Karl K.; Haynes, Jonathan V.; Conlon, Terrence D.


    The Mosier area lies along the Columbia River in northwestern Wasco County between the cities of Hood River and The Dalles, Oregon. Major water uses in the area are irrigation, municipal supply for the city of Mosier, and domestic supply for rural residents. The primary source of water is groundwater from the Columbia River Basalt Group (CRBG) aquifers that underlie the area. Concerns regarding this supply of water arose in the mid-1970s, when groundwater levels in the orchard tract area began to steadily decline. In the 1980s, the Oregon Water Resources Department (OWRD) conducted a study of the aquifer system, which resulted in delineation of an administrative area where parts of the Pomona and Priest Rapids aquifers were withdrawn from further appropriations for any use other than domestic supply. Despite this action, water levels continued to drop at approximately the same, nearly constant annual rate of about 4 feet per year, resulting in a current total decline of between 150 and 200 feet in many wells with continued downward trends. In 2005, the Mosier Watershed Council and the Wasco Soil and Water Conservation District began a cooperative investigation of the groundwater system with the U.S. Geological Survey. The objectives of the study were to advance the scientific understanding of the hydrology of the basin, to assess the sustainability of the water supply, to evaluate the causes of persistent groundwater-level declines, and to evaluate potential management strategies. An additional U.S. Geological Survey objective was to advance the understanding of CRBG aquifers, which are the primary source of water across a large part of Oregon, Washington, and Idaho. In many areas, significant groundwater level declines have resulted as these aquifers were heavily developed for agricultural, municipal, and domestic water supplies. Three major factors were identified as possible contributors to the water-level declines in the study area: (1) pumping at rates that


    IONESCU Cozmin


    Full Text Available The classical moulds which are currently used for forming the soles directly on the uppers, allow obtaining one sole model. One mould for each foot is made, and at least one mould for each size number in the size number series. To manufacture one single sole model in the sizes series an average set of 16 moulds are needed. Changing the model implies the entire production of a new set of moulds. Therefore, a large diversification of the soles requires the manufacturing a quantity of moulds sets equal with the quantity of sole models. In this paper are presented solutions to obtain more cavity shapes in the same mould, through the use of modular interchangeable pieces. The moulds with versatile cavities have the same functional characteristics as the moulds with unique cavities, are usable on the same type of machines and can be used independently or together with the classical moulds. A brief analysis on the technological processes for manufacturing moulds with versatile cavities reveals a significant lowering of the manufacturing time for moulds in which will be obtained other sole models. This is due to the fact that some of the mould parts are reused. In conclusion, the producers that chose this type of moulds can launch on the market new models in a shorter time and at lower prices.

  17. Modelling growth and bioaccumulation of Polychlorinated biphenyls in common sole ( Solea solea)

    Eichinger, M.; Loizeau, V.; Roupsard, F.; Le Guellec, A. M.; Bacher, C.


    Experiments were performed on juvenile sole in controlled conditions in the aim of understanding how the biology of common sole may affect the accumulation and dilution of Polychlorinated biphenyls (PCBs). The fish were raised in optimal conditions and divided into two tanks: one control tank and one PCB tank. 4 PCB congeners were added to food for 3 months in the PCB tank; the soles were subsequently fed unspiked food for 3 months. Growth (length and weight) and PCB concentrations were monitored in both tanks and juvenile sole growth was not significantly affected by PCBs in our experimental conditions. We used the Dynamic Energy Budget (DEB) theory to model sole biology and paid special attention to model calibration through the wide use of data from the literature. The model accurately reproduced fish growth in both tanks. We coupled a bioaccumulation model to reproduce the concentration dynamics of the 4 PCB congeners used. This model did not require additional calibration and was dependent solely on the growth model and PCB concentrations in food. The bioaccumulation model accurately simulated PCB accumulation in fish, but overestimated PCB concentrations in fish during the dilution phase. This may suggest that in addition to PCB dilution due to growth, PCB concentrations decreased due to other PCB elimination mechanisms. Finally, we discussed potential improvements to the model and its future applications.

  18. Effects of shoe sole hardness on plantar pressure and comfort in older people with forefoot pain.

    Lane, Tamara J; Landorf, Karl B; Bonanno, Daniel R; Raspovic, Anita; Menz, Hylton B


    Plantar forefoot pain is common in older people and is related to increased peak pressures under the foot during gait. Variations in the hardness of the shoe sole may therefore influence both the magnitude of loading under the foot and the perceived comfort of the shoe in this population. The aim of this investigation was to determine the effect of varying shoe sole hardness on plantar pressures and comfort in older people with forefoot pain. In-shoe plantar pressures under the forefoot, midfoot and rearfoot were recorded from 35 older people (mean age 73.2, SD 4.5 years) with current or previous forefoot pain using the pedar-X(®) system. Participants walked at their normal comfortable speed along an 8m walkway in shoes with three different levels of sole hardness: soft (Shore A25), medium (Shore A40) and hard (Shore A58). Shoe comfort was measured on a 100mm visual analogue scale. There were statistically significant differences in peak pressure of between 5% and 23% across the forefoot, midfoot and rearfoot (phard-soled shoe registered the highest peak pressures and the soft-soled shoe the lowest peak pressures. However, no differences in comfort scores across the three shoe conditions were observed. These findings demonstrate that as shoe sole hardness increases, plantar pressure increases, however this does not appear to have a significant effect on shoe comfort.


    LUCA Cornelia


    Full Text Available The moulds stock necessary for realization in rhythmically conditions, a certain volume of footwear soles depends on some criterions such as: the range of soles for footwear volume daily realized, the sizes structure of those soles for footwear and, respectively, the sizes tally, the technological cycle for an used mould depending on the equipment efficiency, the provide necessity of spare moulds, the using and fixing conditions etc. From the efficiency point of view, the equipments may have two working posts, or more working posts (always, an even number, as 6, 12, 24, 40 posts. Footwear soles manufacturing takes into account the percentage distribution of the size numbers of the size series. When o portative assembly is used for the manufacturing of the footwear soles using the injection with “n” working posts, it is very important an optimum distribution of the working posts. The disadvantages of these equipments are the situations of the no equilibrium programming of the moulds, so that, in one time, some working posts spread out of the work. The paper presents some practical and theoretical solutions for moulds stock programming in portative assembly for footwear soles injection, so that an optimum equilibrium degree of the working posts will obtain

  20. Microbial community response to the CO2 injection and storage in the saline aquifer, Ketzin, Germany

    Morozova, Daria; Zettlitzer, Michael; Vieth, Andrea; Würdemann, Hilke


    The concept of CO2 capture and storage in the deep underground is currently receiving great attention as a consequence of the effects of global warming due to the accumulation of carbon dioxide gas in the atmosphere. The EU funded CO2SINK project is aimed as a pilot storage of CO2 in a saline aquifer located near Ketzin, Germany. One of the main aims of the project is to develop efficient monitoring procedures for assessing the processes that are triggered in the reservoir by CO2 injection. This study reveals analyses of the composition and activity of the microbial community of a saline CO2 storage aquifer and its response to CO2 injection. The availability of CO2 has an influence on the metabolism of both heterotrophic microorganisms, which are involved in carbon cycle, and lithoautotrophic microorganisms, which are able to use CO2 as the sole carbon source and electron acceptor. Injection of CO2 in the supercritical state (temperature above 31.1 °C, pressure above 72.9 atm) may induce metabolic shifts in the microbial communities. Furthermore, bacterial population and activity can be strongly influenced by changes in pH value, pressure, temperature, salinity and other abiotic factors, which will be all influenced by CO2 injection into the deep subsurface. Analyses of the composition of microbial communities and its changes should contribute to an evaluation of the effectiveness and reliability of the long-term CO2 storage technique. The interactions between microorganisms and the minerals of both the reservoir and the cap rock may cause major changes to the structure and chemical composition of the rock formations, which would influence the permeability within the reservoir. In addition, precipitation and corrosion may occur around the well affecting the casing and the casing cement. By using Fluorescence in situ Hybridisation (FISH) and molecular fingerprinting such as Polymerase-Chain-Reaction Single-Strand-Conformation Polymorphism (PCR-SSCP) and Denaturing

  1. Karst Aquifer Recharge: A Case History of over Simplification from the Uley South Basin, South Australia

    Nara Somaratne


    Full Text Available The article “Karst aquifer recharge: Comments on ‘Characteristics of Point Recharge in Karst Aquifers’, by Adrian D. Werner, 2014, Water 6, doi:10.3390/w6123727” provides misrepresentation in some parts of Somaratne [1]. The description of Uley South Quaternary Limestone (QL as unconsolidated or poorly consolidated aeolianite sediments with the presence of well-mixed groundwater in Uley South [2] appears unsubstantiated. Examination of 98 lithological descriptions with corresponding drillers’ logs show only two wells containing bands of unconsolidated sediments. In Uley South basin, about 70% of salinity profiles obtained by electrical conductivity (EC logging from monitoring wells show stratification. The central and north central areas of the basin receive leakage from the Tertiary Sand (TS aquifer thereby influencing QL groundwater characteristics, such as chemistry, age and isotope composition. The presence of conduit pathways is evident in salinity profiles taken away from TS water affected areas. Pumping tests derived aquifer parameters show strong heterogeneity, a typical characteristic of karst aquifers. Uley South QL aquifer recharge is derived from three sources; diffuse recharge, point recharge from sinkholes and continuous leakage of TS water. This limits application of recharge estimation methods, such as the conventional chloride mass balance (CMB as the basic premise of the CMB is violated. The conventional CMB is not suitable for accounting chloride mass balance in groundwater systems displaying extreme range of chloride concentrations and complex mixing [3]. Over simplification of karst aquifer systems to suit application of the conventional CMB or 1-D unsaturated modelling as described in Werner [2], is not suitable use of these recharge estimation methods.

  2. Stimulating in situ denitrification in an aerobic, highly permeable municipal drinking water aquifer

    Critchley, K.; Rudolph, D. L.; Devlin, J. F.; Schillig, P. C.


    A preliminary trial of a cross-injection system (CIS) was designed to stimulate in situ denitrification in an aquifer servicing an urban community in southern Ontario. It was hypothesized that this remedial strategy could be used to reduce groundwater nitrate in the aquifer such that it could remain in use as a municipal supply until the beneficial effects of local reduced nutrient loadings lead to long-term water quality improvement at the wellfield. The CIS application involved injecting a carbon source (acetate) into the subsurface using an injection-extraction well pair positioned perpendicular to the regional flow direction, up-gradient of the water supply wells, with the objective of stimulating native denitrifying bacteria. The pilot remedial strategy was targeted in a high nitrate flux zone within an aerobic and heterogeneous section of the glacial sand and gravel aquifer. Acetate injections were performed at intervals ranging from daily to bi-daily. The carbon additions led to general declines in dissolved oxygen concentrations; decreases in nitrate concentration were localized in aquifer layers where velocities were estimated to be less than 0.5 m/day. NO3-15N and NO3-18O isotope data indicated the nitrate losses were due to denitrification. Relatively little nitrate was removed from groundwater in the more permeable strata, where velocities were estimated to be on the order of 18 m/day or greater. Overall, about 11 percent of the nitrate mass passing through the treatment zone was removed. This work demonstrates that stimulating in situ denitrification in an aerobic, highly conductive aquifer is challenging but achievable. Further work is needed to increase rates of denitrification in the most permeable units of the aquifer.

  3. Groundwater quality in the alluvial aquifer system of northwest India: New evidence of the extent of anthropogenic and geogenic contamination.

    Lapworth, D J; Krishan, G; MacDonald, A M; Rao, M S


    Groundwater depletion has been widely studied in northwest India, but water quality concerns are still poorly constrained. In this study, we explore the hydrochemistry of the top 160m of the aquifer system, through detailed field studies in the Bist-Doab region, considering both anthropogenic and geogenic controls. A detailed comparison is made between sites dominated by urban and agricultural landuse. Salinity, nitrate, chloride and lead concentrations are significantly higher in the shallow (0-50m) groundwater system due to surface anthropogenic contaminant loading from agricultural and urban sources. The widespread occurrence of oxic groundwater within the aquifer system means that denitrification potential is limited and also enhances the mobility of selenium and uranium in groundwater. Geogenic trace elements (e.g. As, Se, F), are generally found at concentrations below WHO guideline drinking water values, however elevated U concentrations (50-70μg/L) are found within the deeper part of the aquifer and shallow urban aquifers associated with higher bicarbonate waters. Higher concentration of Se (10-40μg/L) are found exclusively in the shallow groundwater system where Se is mobilised from soils and transported to depth in the shallow aquifer due to the prevailing oxidising aquifer conditions. New evidence from a range of environmental tracers shows elevated concentrations of anthropogenic contaminants in the deeper part of the aquifer (50-160m deep) and demonstrates vulnerability to vertical migration of contaminants. Continued intensive groundwater abstraction from >100m deep means that water quality risks to the deep aquifer system need to be considered together with water quantity constraints. Copyright © 2017. Published by Elsevier B.V.

  4. Ground-water-quality assessment of the Central Oklahoma Aquifer, Oklahoma; geochemical and geohydrologic investigations

    Parkhurst, D.L.; Christenson, S.C.; Breit, G.N.


    The National Water-Quality Assessment pilot project for the Central Oklahoma aquifer examined the chemical and isotopic composition of ground water, the abundances and textures of minerals in core samples, and water levels and hydraulic properties in the flow system to identify geochemical reactions occurring in the aquifer and rates and directions of ground-water flow. The aquifer underlies 3,000\\x11square miles of central Oklahoma and consists of Permian red beds, including parts of the Permian Garber Sandstone, Wellington Formation, and Chase, Council Grove, and Admire Groups, and Quaternary alluvium and terrace deposits. In the part of the Garber Sandstone and Wellington Formation that is not confined by the Permian Hennessey Group, calcium, magnesium, and bicarbonate are the dominant ions in ground water; in the confined part of the Garber Sandstone and Wellington Formation and in the Chase, Council Grove, and Admire Groups, sodium and bicarbonate are the dominant ions in ground water. Nearly all of the Central Oklahoma aquifer has an oxic or post-oxic environment as indicated by the large dissolved concentrations of oxygen, nitrate, arsenic (V), chromium (VI), selenium (VI), vanadium, and uranium. Sulfidic and methanic environments are virtually absent. Petrographic textures indicate dolomite, calcite, sodic plagioclase, potassium feldspars, chlorite, rock fragments, and micas are dissolving, and iron oxides, manganese oxides, kaolinite, and quartz are precipitating. Variations in the quantity of exchangeable sodium in clays indicate that cation exchange is occurring within the aquifer. Gypsum may dissolve locally within the aquifer, as indicated by ground water with large concentrations of sulfate, but gypsum was not observed in core samples. Rainwater is not a major source for most elements in ground water, but evapotranspiration could cause rainwater to be a significant source of potassium, sulfate, phosphate and nitrogen species. Brines derived from

  5. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer...

  6. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer is an important...

  7. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Vamoosa-Ada aquifer, in east-central Oklahoma. The Vamoosa-Ada aquifer is an...

  8. Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwest Principal Aquifers study area

    U.S. Geological Survey, Department of the Interior — This product "Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwest Principal Aquifers study area" is a 1:250,000-scale vector dataset...

  9. Review: The Yucatán Peninsula karst aquifer, Mexico

    Bauer-Gottwein, Peter; Gondwe, Bibi Ruth Neuman; Charvet, Guillaume


    The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000 km2 in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located...

  10. Cold water aquifer storage. [air conditioning

    Reddell, D. L.; Davison, R. R.; Harris, W. B.


    A working prototype system is described in which water is pumped from an aquifer at 70 F in the winter time, chilled to a temperature of less than 50 F, injected into a ground-water aquifer, stored for a period of several months, pumped back to the surface in the summer time. A total of 8.1 million gallons of chilled water at an average temperature of 48 F were injected. This was followed by a storage period of 100 days. The recovery cycle was completed a year later with a total of 8.1 million gallons recovered. Approximately 20 percent of the chill energy was recovered.

  11. In situ microcosms in aquifer bioremediation studies.

    Mandelbaum, R T; Shati, M R; Ronen, D


    The extent to which aquifer microbiota can be studied under laboratory or simulated conditions is limited by our inability to authentically duplicate natural conditions in the laboratory. Therefore, extrapolation of laboratory results to real aquifer situations is often criticized, unless validation of the data is performed in situ. Reliable data acquisition is critical for the estimation of chemical and biological reaction rates of biodegradation processes in groundwater and as input data for mathematical models. Typically, in situ geobiochemical studies relied on the injection of groundwater spiked with compounds or bacteria of interest into the aquifer, followed by monitoring the changes over time and space. In situ microcosms provide a more confined study site for measurements of microbial reactions, yet closer to natural conditions than laboratory microcosms. Two basic types of in situ aquifer microcosm have been described in recent years, and both originated from in situ instruments initially designed for geochemical measurements. Gillham et al. [Ground Water 28 (1990) 858-862] constructed an instrument that isolates a portion of an aquifer for in situ biochemical rate measurements. More recently Shati et al. [Environ. Sci. Technol. 30 (1996) 2646-2653] modified a multilayer sampler for studying the activity of inoculated bacteria in a contaminated aquifer Keeping in mind recent advances in environmental microbiology methodologies such as immunofluorescence direct counts, oligonucleotide and PCR probes, fatty acid methyl esther analysis for the detection and characterization of bacterial communities, measurement of mRNA and expression of proteins, it is evident that much new information can now be gained from in situ work. Using in situ microcosms to study bioremediation efficiencies, the fate of introduced microorganisms and general geobiochemical aquifer processes can shed more realistic light on the microbial underworld. The aim of this paper is to

  12. Aquifer Thermal Energy Storage for Seasonal Thermal Energy Balance

    Rostampour, Vahab; Bloemendal, Martin; Keviczky, Tamas


    Aquifer Thermal Energy Storage (ATES) systems allow storing large quantities of thermal energy in subsurface aquifers enabling significant energy savings and greenhouse gas reductions. This is achieved by injection and extraction of water into and from saturated underground aquifers, simultaneously. An ATES system consists of two wells and operates in a seasonal mode. One well is used for the storage of cold water, the other one for the storage of heat. In warm seasons, cold water is extracted from the cold well to provide cooling to a building. The temperature of the extracted cold water increases as it passes through the building climate control systems and then gets simultaneously, injected back into the warm well. This procedure is reversed during cold seasons where the flow direction is reversed such that the warmer water is extracted from the warm well to provide heating to a building. From the perspective of building climate comfort systems, an ATES system is considered as a seasonal storage system that can be a heat source or sink, or as a storage for thermal energy. This leads to an interesting and challenging optimal control problem of the building climate comfort system that can be used to develop a seasonal-based energy management strategy. In [1] we develop a control-oriented model to predict thermal energy balance in a building climate control system integrated with ATES. Such a model however cannot cope with off-nominal but realistic situations such as when the wells are completely depleted, or the start-up phase of newly installed wells, etc., leading to direct usage of aquifer ambient temperature. Building upon our previous work in [1], we here extend the mathematical model for ATES system to handle the above mentioned more realistic situations. Using our improved models, one can more precisely predict system behavior and apply optimal control strategies to manage the building climate comfort along with energy savings and greenhouse gas reductions

  13. Craniofacial Pain as the Sole Sign of Prodromal Angina and Acute Coronary Syndrome: A Review and Report of a Rare Case

    Fazlyab, Mahta; Esnaashari, Ehsan; Saleh, Mojgan; Shakerian, Farshad; Akhlagh Moayed, Davood; Asgary, Saeed


    Orofacial pain can arise from different regions and etiologies. Some of the most debilitating pain conditions arise from the structures innervated by the trigeminal system (head, face, masticatory musculature, temporomandibular joint and associated structures). The problem with referred pain is the misdiagnosis and unnecessary therapy directed to the pain location instead of its origin. When craniofacial pain is the sole sign of myocardial ischemia, failure to recognize its cardiac source can...

  14. Water quality of the Little Arkansas River and Equus Beds Aquifer before and concurrent with large-scale artificial recharge, south-central Kansas, 1995-2012

    Tappa, Daniel J.; Lanning-Rush, Jennifer L.; Klager, Brian J.; Hansen, Cristi V.; Ziegler, Andrew C.


    The city of Wichita artificially recharged about 1 billion gallons of water into the Equus Beds aquifer during 2007–2012 as part of Phase I recharge of the Artificial Storage and Recovery project. This report, prepared in cooperation by the U.S. Geological Survey and the city of Wichita, Kansas, summarizes Little Arkansas River (source-water for artificial recharge) andEquus Beds aquifer water quality before (1995–2006) and during (2007–2012) Artificial Storage and Recovery Phase I recharge. Additionally, aquifer water-quality distribution maps are presented and water-quality changes associated with Phase I recharge timing are described.

  15. Sole Searching


    China wants the European Union to kick its anti-dumping measures on footwear to the curb Among all the advanced countries and regions, the European Union (EU) is China's most stable and mature trading partner. Since China established diplomatic ties with the European Economic Community in 1975, especially after the EU published its first policy paper on China in 1995, Sino-EU relations have developed rapidly, from an all-round partnership to an all-round strategic one. In addition to working together on ...

  16. Feed deprivation in Senegalese sole (Solea senegalensis Kaup, 1858) juveniles: effects on blood plasma metabolites and free amino acid levels.

    Costas, Benjamín; Aragão, Cláudia; Ruiz-Jarabo, Ignacio; Vargas-Chacoff, Luis; Arjona, Francisco Jesús; Dinis, Maria Teresa; Mancera, Juan Miguel; Conceição, Luís E C


    The effects of prolonged feed deprivation were assessed on blood plasma metabolites and free amino acid levels in Solea senegalensis. Juvenile specimens were maintained at two experimental conditions (24 h fasted and 21 days feed-deprived). In feed-deprived fish, relative growth rate and hepatosomatic index as well as plasma triglycerides and proteins levels were significantly lower. However, plasma cortisol levels were higher in feed-deprived fish, while plasma glucose and lactate values were not significantly different between treatments. Furthermore, feed-deprived fish showed higher levels of total plasma free amino acids than 24 h fasted fish. In 21 days feed-deprived sole, an increase in plasma cortisol levels may suggest a functional role in mobilizing energy due to the catabolic action of this hormone in teleosts. Higher levels of glutamine, arginine and ornithine in 21 days feed-deprived fish may be indicative of a dual role for these amino acids: ammonia detoxification and carbon source for gluconeogenesis. The increased plasma glucogenic and branched-chain amino acid levels, together with the maintenance of plasma glucose in 21 days feed-deprived sole, suggest active liver gluconeogenic processes supported by tissue proteolysis.

  17. Aquifer geochemistry at potential aquifer storage and recovery sites in coastal plain aquifers in the New York city area, USA

    Brown, C.J.; Misut, P.E.


    The effects of injecting oxic water from the New York city (NYC) drinking-water supply and distribution system into a nearby anoxic coastal plain aquifer for later recovery during periods of water shortage (aquifer storage and recovery, or ASR) were simulated by a 3-dimensional, reactive-solute transport model. The Cretaceous aquifer system in the NYC area of New York and New Jersey, USA contains pyrite, goethite, locally occurring siderite, lignite, and locally varying amounts of dissolved Fe and salinity. Sediment from cores drilled on Staten Island and western Long Island had high extractable concentrations of Fe, Mn, and acid volatile sulfides (AVS) plus chromium-reducible sulfides (CRS) and low concentrations of As, Pb, Cd, Cr, Cu and U. Similarly, water samples from the Lloyd aquifer (Cretaceous) in western Long Island generally contained high concentrations of Fe and Mn and low concentrations of other trace elements such as As, Pb, Cd, Cr, Cu and U, all of which were below US Environmental Protection Agency (USEPA) and NY maximum contaminant levels (MCLs). In such aquifer settings, ASR operations can be complicated by the oxidative dissolution of pyrite, low pH, and high concentrations of dissolved Fe in extracted water.The simulated injection of buffered, oxic city water into a hypothetical ASR well increased the hydraulic head at the well, displaced the ambient groundwater, and formed a spheroid of injected water with lower concentrations of Fe, Mn and major ions in water surrounding the ASR well, than in ambient water. Both the dissolved O2 concentrations and the pH of water near the well generally increased in magnitude during the simulated 5-a injection phase. The resultant oxidation of Fe2+ and attendant precipitation of goethite during injection provided a substrate for sorption of dissolved Fe during the 8-a extraction phase. The baseline scenario with a low (0.001M) concentration of pyrite in aquifer sediments, indicated that nearly 190% more water

  18. Assessment of natural recharges of the Plio-Plistocene shallow aquifer system in Al Uja area /Lower Jordan Valley / Occupied Palestinian Territories

    Manasra, Kayan; Marei, Amer; Sbiah, Mohamed; Uter, Hussam; Abu Thaher, Ayman


    Al Uja area locates in the Lower Jordan Valley/West Bank at 250 m below sea level. The availability of ground water, fertile soil, and warm climate during winter months make it remarkable for its agricultural activities where 600 hectares are under irrigation. Al Uja karstic spring that drain water from the Mountain carbonate aquifer system with a discharge rate between 0.5 and 8 MCM/a , and nine groundwater boreholes that tape water from the shallow Plio-Plistocene aquifer system, with an annual abstraction of 3.5 MCM are the water sources. The south-north fault system of the Jordan Rift Valley separates the two aquifer system. The shallow aquifer system locates to the east of the fault, where the Mountain aquifer system locates to the west. The Mountain aquifer consists of high fractured and karstified limestone and dolomite of Upper Cretaceous age, and the shallow aquifer system consists of gravel, sand, silt, and clay layers of the Dead Sea group. Groundwater recharge of the Mountain aquifer system takes place in the highland area in the West with an annual precipitation of about 550 mm. Formations of the shallow aquifer system crop out in the Jordan Valley where rainfall does not exceed 250 mm/a . Due to the high evaporation rate, direct recharge is neglected. Only small portion of flooding water about 0.4MCM/a infiltrate through wadi Al Uja drainage system in to the Alluvial deposits to the shallow aquifer system. In the other hand, and since more than 40 years, the nine groundwater boreholes are taping about 3 MCM/a, water table decline of about 5 m. Currently, water table locates between -290 m in the west and decrease to - 311 m in the east. Groundwater flows from the Mountain aquifer in the west to the Shallow aquifer in the east through the major fault system. The permeability of the Mountain carbonate layers is 2.49E-1 m/min and decrease to 1.6 E-2 m/min in the layers of the Shallow aquifer system, this decrease of Kf-value east wards cause a semi

  19. Origins and processes of groundwater salinization in the urban coastal aquifers of Recife (Pernambuco, Brazil): A multi-isotope approach.

    Cary, Lise; Petelet-Giraud, Emmanuelle; Bertrand, Guillaume; Kloppmann, Wolfram; Aquilina, Luc; Martins, Veridiana; Hirata, Ricardo; Montenegro, Suzana; Pauwels, Hélène; Chatton, Eliot; Franzen, Melissa; Aurouet, Axel


    In the coastal multilayer aquifer system of a highly urbanized southern city (Recife, Brazil), where groundwaters are affected by salinization, a multi-isotope approach (Sr, B, O, H) was used to investigate the sources and processes of salinization. The high diversity of the geological bodies, built since the Atlantic opening during the Cretaceous, highly constrains the heterogeneity of the groundwater chemistry, e.g. Sr isotope ratios, and needs to be integrated to explain the salinization processes and groundwater pathways. A paleoseawater intrusion, most probably the 120 kyB.P. Pleistocene marine transgression, and cationic exchange are clearly evidenced in the most salinized parts of the Cabo and Beberibe aquifers. All (87)Sr/(86)Sr values are above the past and present-day seawater signatures, meaning that the Sr isotopic signature is altered due to additional Sr inputs from dilution with different freshwaters, and water-rock interactions. Only the Cabo aquifer presents a well-delimitated area of Na-HCO3 water typical of a freshening process. The two deep aquifers also display a broad range of B concentrations and B isotope ratios with values among the highest known to date (63-68.5‰). This suggests multiple sources and processes affecting B behavior, among which mixing with saline water, B sorption on clays and mixing with wastewater. The highly fractionated B isotopic values were explained by infiltration of relatively salty water with B interacting with clays, pointing out the major role played by (palaeo)-channels for the deep Beberibe aquifer recharge. Based on an increase of salinity at the end of the dry season, a present-day seawater intrusion is identified in the surficial Boa Viagem aquifer. Our conceptual model presents a comprehensive understanding of the major groundwater salinization pathways and processes, and should be of benefit for other southern Atlantic coastal aquifers to better address groundwater management issues.

  20. Evaluation of methods for delineating areas that contribute water to wells completed in valley-fill aquifers in Pennsylvania

    Risser, Dennis W.; Madden, Thomas M.


    Valley-fill aquifers in Pennsylvania are the source of drinking water for many wells in the glaciated parts of the State and along major river valleys. These aquifers area subject to contamination because of their shallow water-table depth and highly transmissive sediments. The possibility for contamination of water-supply wells in valley-fill aquifers can be minimized by excluding activities that could contaminate areas that contribute water to supply wells. An area that contributes water to a well is identified in this report as either an area of diversion, time-of-travel area, or contributing area. The area of diversion is a projection to land surface of the valley-fill aquifer volume through which water is diverted to a well and the time-of travel area is that fraction of the area of diversion through which water moves to the well in a specified time. The contributing area, the largest of three areas, includes the area of diversion but also incorporates bedrock uplands and other area that contribute water. Methods for delineating areas of diversion and contributing areas in valley-fill aquifers, described and compared in order of increasing complexity, include fixed radius, uniform flow, analytical, semianalytical, and numerical modeling. Delineated areas are considered approximations because the hydraulic properties and boundary conditions of the real ground-water system are simplified even in the most complex numerical methods. Successful application of any of these methods depends on the investigator's understanding of the hydrologic system in and near the well field, and the limitations of the method. The hydrologic system includes not only the valley-fill aquifer but also the regional surface-water and ground-water flow systems within which the valley is situated. As shown by numerical flow simulations of a well field in the valley-fill aquifer along Marsh Creek Valley near Asaph, Pa., water from upland bedrock sources can provide nearly all the water

  1. Simulated effects of projected withdrawals from the Wenonah-Mount Laurel Aquifer on ground-water levels in the Camden, New Jersey, area and vicinity

    Navoy, A.S.


    The Wenonah-Mount Laurel aquifer is being considered as a potential source of future water supply for the Camden, New Jersey, area. The deeper Potomac- Raritan-Magothy aquifer system is currently the major major source of water supply for the area, but its use may be curtailed or reduced by 35 percent of 1983 withdrawals through its designation by the New Jersey Department of Environmental Protection and Energy as "Water Supply Critical Area#2." Withdrawals from the Wenonah-Mount Laurel aquifer currently (1989) total about 7 million gallons per day. The anticipated use of this aquifer by communities with access to it, as an alternative supply, could increase to more than 14 million gallons per day by 2020. If the communities of Clayton and Glassboro decrease their withdrawals from the Potomac-Raritan-Magothy aquifer system by 50 percent or cease them entirely because of their proximity to saline water, the use of Wenonah-Mount Laurel aquifer could increase to greater than 15 million gallons per day by 2020. Simulation of the ground-water system indicates that the projected increase in withdrawals will cause cones of depression in the potentiometric surface of the Wenonah-Mount Laurel aquifer in the Camden metro- politan area by 2020 that extend to depths ranging from 10 feet above sea level to 60 feet below sea level. This represents a secline of about 40 to 100 feet thr 1990 conditions. Withdrawals in northeastern Burlington County will cause a large cone of depression that, by 2020, will extend to depths of about 220 feet below sea level, represent- ing a decline of about 140 feet from 1990 conditions. Simulation results indicate that water levels in the Wenonah-Mount Laurel aquifer near the Salem Nuclear Power Plant are somewhat insensitive to withdrawals elsewhere in the aquifer. In some areas, especially in Burlington County, the cones of depression have developed in proximity to the aquifer-outcrop area and could induce infiltration from streams crossing the

  2. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant hydraulic conductivity value for the Central Oklahoma aquifer in central Oklahoma. This area encompasses...

  3. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Central Oklahoma aquifer in central Oklahoma. This area encompasses all or part of...

  4. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant recharge value for the Central Oklahoma aquifer in central Oklahoma. This area encompasses all or part of...

  5. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of a digitized polygon of a constant recharge value for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace...

  6. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Rush Springs aquifer in western Oklahoma. This area encompasses all or...

  7. Aquifer Boundary of the Wood River Valley Aquifer System, South-Central Idaho

    U.S. Geological Survey, Department of the Interior — This dataset contains the boundary of the Wood River Valley aquifer system as modified and expanded from that defined by Skinner and others (2007): It has been...

  8. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone...

  9. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of constant hydraulic conductivity values for the High Plains aquifer in Oklahoma. This area encompasses the panhandle...

  10. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of constant recharge rates for the High Plains aquifer in Oklahoma. This area encompasses the panhandle counties of...

  11. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid...

  12. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the High Plains aquifer in western Oklahoma. This area encompasses the panhandle counties of...

  13. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant hydraulic conductivity value for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age...

  14. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone is an...

  15. Can Remote Sensing Detect Aquifer Characteristics?: A Case Study in the Guarani Aquifer System

    Richey, A. S.; Thomas, B.; Famiglietti, J. S.


    Global water supply resiliency depends on groundwater, especially regions threatened by population growth and climate change. Aquifer characteristics, even as basic as confined versus unconfined, are necessary to prescribe regulations to sustainably manage groundwater supplies. A significant barrier to sustainable groundwater management exists in the difficulties associated with mapping groundwater resources and characteristics at a large spatial scale. This study addresses this challenge by investigating if remote sensing, including with NASA's Gravity Recovery and Climate Experiment (GRACE), can detect and quantify key aquifer parameters and characteristics. We explore this through a case study in the Guarani Aquifer System (GAS) of South America, validating our remote sensing-based findings against the best available regional estimates. The use of remote sensing to advance the understanding of large aquifers is beneficial to sustainable groundwater management, especially in a trans-boundary system, where consistent information exchange can occur within hydrologic boundaries instead of political boundaries.

  16. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of...

  17. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of Blaine,...

  18. State Aquifer Recharge Atlas Plates, Geographic NAD83, LDEQ (1999) [aquifer_recharge_potential_LDEQ_1988

    Louisiana Geographic Information Center — This is a polygon dataset depicting the boundaries of aquifer systems in the state of Louisiana and adjacent areas of Texas, Arkansas and a portion of Mississippi....

  19. Ground-water quality assessment of the central Oklahoma Aquifer, Oklahoma; project description

    Christenson, S.C.; Parkhurst, D.L.


    In April 1986, the U.S. Geological Survey began a pilot program to assess the quality of the Nation's surface-water and ground-water resources. The program, known as the National Water-Quality Assessment (NAWQA) program, is designed to acquire and interpret information about a variety of water-quality issues. The Central Oklahoma aquifer project is one of three ground-water pilot projects that have been started. The NAWQA program also incudes four surface-water pilot projects. The Central Oklahoma aquifer project, as part of the pilot NAWQA program, will develop and test methods for performing assessments of ground-water quality. The objectives of the Central Oklahoma aquifer assessment are: (1) To investigate regional ground-water quality throughout the aquifer in the manner consistent with the other pilot ground-water projects, emphasizing the occurrence and distribution of potentially toxic substances in ground water, including trace elements, organic compounds, and radioactive constituents; (2) to describe relations between ground-water quality, land use, hydrogeology, and other pertinent factors; and (3) to provide a general description of the location, nature, and possible causes of selected prevalent water-quality problems within the study unit; and (4) to describe the potential for water-quality degradation of ground-water zones within the study unit. The Central Oklahoma aquifer, which includes in descending order the Garber Sandstone and Wellington Formation, the Chase Group, the Council Grove Group, the Admire Group, and overlying alluvium and terrace deposits, underlies about 3,000 square miles of central Oklahoma and is used extensively for municipal, industrial, commercial, and domestic water supplies. The aquifer was selected for study by the NAWQA program because it is a major source for water supplies in central Oklahoma and because it has several known or suspected water-quality problems. Known problems include concentrations of arsenic, chromium

  20. Groundwater quality of the Gulf Coast aquifer system, Houston, Texas, 2010

    Oden, Jeannette H.; Brown, Dexter W.; Oden, Timothy D.


    During March–December 2010, the U.S. Geological Survey, in cooperation with the city of Houston, collected source-water samples from 60 municipal supply wells in the Houston area. These data were collected as part of an ongoing study to determine concentrations, spatial extent, and associated geochemical conditions that might be conducive for mobility and transport of selected naturally occurring contaminants (selected trace elements and radionuclides) in the Gulf Coast aquifer system in the Houston area. In the summers of 2007 and 2008, a reconnaissance-level survey of these constituents in untreated water from 28 municipal supply wells was completed in the Houston area. Included in this report are the complete analytical results for 47 of the 60 samples collected in 2010—those results which were received from the laboratories and reviewed by the authors as of December 31, 2010. All of the wells sampled were screened in the Gulf Coast aquifer system; 22 were screened entirely in the Evangeline aquifer, and the remaining 25 wells contained screened intervals that intersected both Evangeline and Chicot aquifers. The data documented in this report were collected as part of an ongoing study to characterize source-water-quality conditions in untreated groundwater prior to drinking-water treatment. An evaluation of contaminant occurrence in source water provides background information regarding the presence of a contaminant in the environment. Because source-water samples were collected prior to any treatment or blending that potentially could alter contaminant concentrations, the water-quality results documented by this report represent the quality of the source water, not the quality of finished drinking water provided to the public.

  1. Planning an aquifer storage and recovery scheme in the Sherwood Sandstone aquifer

    Pindoria-Nandha, Mital


    Aquifer Storage and Recovery (ASR) involves the injection of water into an aquifer for subsequent recovery from the same well. Whilst ASR provides a competitive alternative to reservoir storage, a lack of precedence of successful schemes and uncertainties with respect to regulatory requirements, and abstracted water quality and quantity have limited its implementation in the UK. The ambition of this research is to improve understanding of these impediments with particular refer...

  2. Hydrochemistry and energy storage in aquifers

    Andersson, O.; Appelo, C.A.J.; Brons, H.J.; Dufour, F.C.; Griffioen, J.; Jenne, E.A.; Lyklema, J.W.; Mourik, G.J. van; Snijders, A.L.; Willemsen, A.; Zehnder, A.J.B.


    This volume of the series Proceedings and Information of the TNO Committee on Hydrological Research (CHO-TNO) contains the contributions as presented on the 48th technical meeting of the CHO-TNO, "Hydrochemistry and energy storage in aquifers". During this symposium recent results have been presente

  3. Transport of nonlinearly biodegradable contaminants in aquifers

    Keijzer, H.


    This thesis deals with the transport behavior of nonlinearly biodegradable contaminants in aquifers. Such transport occurs during in situ bioremediation which is based on the injection of an electron acceptor or electron donor. The main interests in this thesis are the mutual influences of underlyin

  4. Biogeochemical aspects of aquifer thermal energy storage.

    Brons, H.J.


    During the process of aquifer thermal energy storage the in situ temperature of the groundwater- sediment system may fluctuate significantly. As a result the groundwater characteristics can be considerably affected by a variety of chemical, biogeochemical and microbiological reactions. The inter

  5. Identifying turbulent flow in carbonate aquifers

    Worthington, Stephen R. H.; Soley, Robert W. N.


    Turbulent flow has a different hydraulic response compared to laminar flow and so it is important to be able to identify its occurrence in an aquifer, and to predict where it is likely to be found. Turbulent flow is associated with large apertures and rapid velocities, and these occur most frequently in carbonate aquifers. Methods for identifying turbulent flow include correlating spring discharge with head variation, calculating Reynolds numbers from spring discharge and tracer velocity, and plotting the spatial variation of head differences between high flow and low flow. The probability of turbulent flow increases as a function of permeability and of spring discharge, and the probability increases in a downgradient direction in an aquifer. Spring discharge is a key parameter for evaluating the presence of turbulent flow, which is likely to occur where a spring with a discharge > 1 L/s is fed by a single channel. Turbulent flow appears to be a major contributing factor to the occurrence of groundwater flooding in carbonate aquifers.

  6. Hydrochemistry and energy storage in aquifers

    Andersson, O.; Appelo, C.A.J.; Brons, H.J.; Dufour, F.C.; Griffioen, J.; Jenne, E.A.; Lyklema, J.W.; Mourik, G.J. van; Snijders, A.L.; Willemsen, A.; Zehnder, A.J.B.


    This volume of the series Proceedings and Information of the TNO Committee on Hydrological Research (CHO-TNO) contains the contributions as presented on the 48th technical meeting of the CHO-TNO, "Hydrochemistry and energy storage in aquifers". During this symposium recent results have been

  7. INEEL Source Water Assessment

    Sehlke, Gerald


    The Idaho National Engineering and Environmental Laboratory (INEEL) covers approximately 890 mi2 and includes 12 public water systems that must be evaluated for Source water protection purposes under the Safe Drinking Water Act. Because of its size and location, six watersheds and five aquifers could potentially affect the INEEL’s drinking water sources. Based on a preliminary evaluation of the available information, it was determined that the Big Lost River, Birch Creek, and Little Lost River Watersheds and the eastern Snake River Plain Aquifer needed to be assessed. These watersheds were delineated using the United States Geologic Survey’s Hydrological Unit scheme. Well capture zones were originally estimated using the RESSQC module of the Environmental Protection Agency’s Well Head Protection Area model, and the initial modeling assumptions and results were checked by running several scenarios using Modflow modeling. After a technical review, the resulting capture zones were expanded to account for the uncertainties associated with changing groundwater flow directions, a thick vadose zone, and other data uncertainties. Finally, all well capture zones at a given facility were merged to a single wellhead protection area at each facility. A contaminant source inventory was conducted, and the results were integrated with the well capture zones, watershed and aquifer information, and facility information using geographic information system technology to complete the INEEL’s Source Water Assessment. Of the INEEL’s 12 public water systems, three systems rated as low susceptibility (EBR-I, Main Gate, and Gun Range), and the remainder rated as moderate susceptibility. No INEEL public water system rated as high susceptibility. We are using this information to develop a source water management plan from which we will subsequently implement an INEEL-wide source water management program. The results are a very robust set of wellhead protection areas that will

  8. Controls on {sup 222}Rn variations in a fractured crystalline rock aquifer evaluated using aquifer tests and geophysical logging

    Folger, P.F. [Office of Senator Pete V. Domenici, Washington, DC (United States)]|[Colorado School of Mines, Golden, CO (United States). Dept. of Geology and Geologic Engineering; Poeter, E. [Colorado School of Mines, Golden, CO (United States). Dept. of Geology and Geologic Engineering; Wanty, R.B.; Frishman, D.; Day, W.


    Concentrations of {sup 222}Rn in ground water may vary considerably within megascopically homogeneous rocks over relatively short distances. Calculations indicate that different hydraulic apertures of water-bearing fractures may account for variations in dissolved {sup 222}Rn concentration measured in domestic water wells completed in fractured Pikes Peak Granite, assuming that all other factors influencing dissolved {sup 222}Rn concentrations are constant. Concentrations of dissolved {sup 222}Rn range from 124 to 840 kBq/m{sup 3} [3,360 to 22,700 picocuries/liter] within a 2.5 km{sup 2} well field. Aquifer tests show that transmissivities range from 0.072 to 160 m{sup 2}/day within the well field. Acoustic televiewer and heat-pulse flow meter logging of four wells reveals that, despite tens to hundreds of fractures that intersect each well, a single fracture supplies all the flow to three wells, and one fracture provides 65% of the flow to the fourth well. Type-curve interpretation of early-time data from aquifer tests reveals classic half-slope behavior on log-log plots of drawdown versus time for two wells, suggesting linear flow to a single fracture. Drawdown versus time for the other two wells indicates radial or pseudo-radial flow, which suggests a higher degree of fracture interconnectivity near those boreholes. Hydraulic apertures calculated using the cubic law are 0.024 and 0.038 cm for producing fractures in the first hydraulically connected well pair and 0.011 and 0.020 cm for flowing fractures in the second well pair. Assuming uniform distribution of {sup 226}Ra along fracture walls and long residence time of water relative to {sup 222}Rn decay, the ratio of fracture apertures should equal the inverse ratio of {sup 222}Rn concentration in each well. Differences in {sup 222}Rn concentration between wells in the hydraulically connected pairs can be attributed solely to differences in hydraulic aperture.

  9. Clay Mineralogy of AN Alluvial Aquifer in a Mountainous, Semiarid Terrain, AN Example from Rifle, Colorado

    Elliott, W. C.; Lim, D.; Zaunbrecher, L. K.; Pickering, R. A.; Williams, K. H.; Navarre-Sitchler, A.; Long, P. E.; Noel, V.; Bargar, J.; Qafoku, N. P.


    Alluvial sediments deposited along the Colorado River corridor in the semi-arid regions of central to western Colorado can be important hosts for legacy contamination including U, V, As and Se. These alluvial sediments host aquifers which are thought to provide important "hot spots" and "hot moments" for microbiological activity controlling organic carbon processing and fluxes in the subsurface. Relatively little is known about the clay mineralogy of these alluvial aquifers and the parent alluvial sediments in spite of the fact that they commonly include lenses of silt-clay materials. These lenses are typically more reduced than coarser grained materials, but zones of reduced and more oxidized materials are present in these alluvial aquifer sediments. The clay mineralogy of the non-reduced parent alluvial sediments of the alluvial aquifer located in Rifle, CO (USA) is composed of chlorite, smectite, illite, kaolinite and quartz. The clay mineralogy of non-reduced fine-grained materials at Rifle are composed of the same suite of minerals found in the sediments plus a vermiculite-smectite intergrade that occurs near the bottom of the aquifer near the top of the Wasatch Formation. The clay mineral assemblages of the system reflect the mineralogically immature character of the source sediments. These assemblages are consistent with sediments and soils that formed in a moderately low rainfall climate and suggestive of minimal transport of the alluvial sediments from their source areas. Chlorite, smectite, smectite-vermiculite intergrade, and illite are the likely phases involved in the sorption of organic carbon and related microbial redox transformations of metals in these sediments. Both the occurrence and abundance of chlorite, smectite-vermiculite, illite and smectite can therefore exert an important control on the contaminant fluxes and are important determinants of biogeofacies in mountainous, semiarid terrains.

  10. Sediment distribution and hydrologic conditions of the Potomac aquifer in Virginia and parts of Maryland and North Carolina

    McFarland, E. Randolph


    Sediments of the heavily used Potomac aquifer broadly contrast across major structural features of the Atlantic Coastal Plain Physiographic Province in eastern Virginia and adjacent parts of Maryland and North Carolina. Thicknesses and relative dominance of the highly interbedded fluvial sediments vary regionally. Vertical intervals in boreholes of coarse-grained sediment commonly targeted for completion of water-supply wells are thickest and most widespread across the central and southern parts of the Virginia Coastal Plain. Designated as the Norfolk arch depositional subarea, the entire sediment thickness here functions hydraulically as a single interconnected aquifer. By contrast, coarse-grained sediment intervals are thinner and less widespread across the northern part of the Virginia Coastal Plain and into southern Maryland, designated as the Salisbury embayment depositional subarea. Fine-grained intervals that are generally avoided for completion of water-supply wells are increasingly thick and widespread northward. Fine-grained intervals collectively as thick as several hundred feet comprise two continuous confining units that hydraulically separate three vertically spaced subaquifers. The subaquifers are continuous northward but merge southward into the single undivided Potomac aquifer. Lastly, far southeastern Virginia and northeastern North Carolina are designated as the Albemarle embayment depositional subarea, where both coarse- and fine-grained intervals are of only moderate thickness. The entire sediment thickness functions hydraulically as a single interconnected aquifer. A substantial hydrologic separation from overlying aquifers is imposed by the upper Cenomanian confining unit. Potomac aquifer sediments were deposited by a fluvial depositional complex spanning the Virginia Coastal Plain approximately 100 to 145 million years ago. Westward, persistently uplifted granite and gneiss source rocks sustained a supply of coarse-grained sand and gravel

  11. Unprotected karst resources in western Iran: the environmental impacts of intensive agricultural pumping on the covered karstic aquifer, a case in Kermanshah province

    Taheri, Kamal; Taheri, Milad; Parise, Mario


    Bare and covered karst areas, with developed karstic aquifers, cover 35 percent of the Kermanshah province in western Iran. These aquifers are the vital sources for drinking and agricultural water supplies. Over the past decade, intensive groundwater use (exploitation) for irrigation imposed a significant impact on the carbonate environments. The huge amount of groundwater over-exploitations has been carried out and still goes on by local farmers in the absence of appropriate governance monitoring control. Increasing in water demands, for more intense crop production, is an important driving force toward groundwater depletion in alluvial aquifers. Progressive groundwater over-exploitations from underlying carbonate rocks have led to dramatic drawdown in alluvial aquifers and deep karst water tables. Detecting new sources of groundwater extractions and prohibiting the karst water utilization for agricultural use could be the most effective strategy to manage the sustainability of covered karst aquifers. Anthropogenic pressures on covered karst aquifers have magnified the drought impacts and caused dryness of most of the karst springs and deep wells. In this study, the combination of geophysical and geological studies was used to estimate the most intensively exploited agricultural zones of Islam Abad plain in the southwestern Kermanshah province using GIS. The results show that in the past decade a great number of deep wells were drilled through the overburden alluvial aquifer and reached the deep karst water resources. However, the difficulties involved in monitoring deep wells in covered karst aquifer were the main cause of karst water depletion. Overexploitation from both alluvial and karst aquifers is the main reason for drying out the Arkawazi, Sharafshah, Gawrawani karst springs, and the karst drinking water wells 1, 3 and 5 of Islam Abad city. Karst spring landscape destructions, fresh water supply deficit for inhabitants, decreasing of tourism and

  12. A potential groundwater aquifer for palaeoclimate reconstruction: Turonian aquifer, Tadla basin, Morocco

    Saadi, Radouan; Túri, Marianna; Palcsu, László; Marah, Hamid; Hakam, Oum Keltoum; Rinyu, László; Molnár, Mihály; Futó, István


    We undertook an environmental isotope investigation of groundwater from the Turonian Aquifer of Tadla Basin in Morocco in order to confirm that this aquifer could be a potential site for palaeoclimate reconstruction. The collected groundwater samples were examined for stable oxygen, hydrogen and carbon isotope ratio, as well as noble gases (He, Ne, Ar, Kr, Xe), 14C and 3H concentration. The measured stable oxygen and hydrogen isotope values show that the Turonian aquifer has two recharge areas, one with a heavier isotopic signature from the unconfined aquifer in the northern region (the area of Boujad), while the other is characterised by lighter isotopic composition in the north-eastern to the south-western part of the basin (to the North from Kasba Tadla). The calculated noble-gas solubility temperatures of the confined part of the aquifer are 2 °C higher than the recent mean annual air temperature (19 °C). Radiocarbon ages obtained from running different versions of Ingerson-Pearson models indicated that the recharge of this water occurred during the Holocene. We conclude that the Turonian aquifer might be a potential place for Late-Pleistocene palaeoclimate reconstruction if the research area were extended in the direct of flow path towards the western part of the basin and towards the foothills of the Phosphates Plateau.

  13. Digital Map Of Base of Aquifer for High Plains Aquifer in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming

    U.S. Geological Survey, Department of the Interior — This data set consists of digital base of aquifer elevation contours for the High Plains aquifer in the central United States. The High Plains aquifer extends from...

  14. Digital map of aquifer boundary for the High Plains aquifer in parts of Colorado, Kansas, Nebraska, New Mexico, Oklahoma, South Dakota, Texas, and Wyoming

    U.S. Geological Survey, Department of the Interior — This digital data set consists of aquifer boundaries for the High Plains aquifer in the central United States. The High Plains aquifer extends from south of 32...

  15. Habitat selection of juvenile sole (Solea solea L.): Consequences for shoreface nourishment

    Post, Marjolein H. M.; Blom, Ewout; Chen, Chun; Bolle, Loes J.; Baptist, Martin J.


    The shallow coastal zone is an essential nursery habitat for juvenile flatfish species such as sole (Solea solea L.). The increased frequency of shoreface nourishments along the coast is likely to affect this nursery function by altering important habitat conditions, including sediment grain size. Sediment preference of juvenile sole (41-91 mm) was studied in a circular preference chamber in order to understand the relationship between grain size and sole distribution. The preference tests were carried out at 11 °C and 20 °C to reflect seasonal influences. The juveniles showed a significant preference for finer sediments. This preference was not length dependent (within the length range tested) nor affected by either temperatures. Juvenile sole have a small home range and are not expected to move in response to unfavourable conditions. As a result, habitat alterations may have consequences for juvenile survival and subsequently for recruitment to adult populations. It is therefore important to carefully consider nourishment grain size characteristics to safeguard suitable nursery habitats for juvenile sole.

  16. Reductive dissolution of Mn oxides in river-recharged aquifers: a laboratory column study

    Petrunic, B. M.; MacQuarrie, K. T. B.; Al, T. A.


    River-recharged aquifers are developed for drinking water supplies in many parts of the world. Often, however, dissolved organic carbon (DOC) present in the infiltrating river water causes biogeochemical reactions to occur in the adjacent aquifer that create elevated Mn and Fe. Mn concentrations in groundwater from some of the production wells installed in the aquifer at Fredericton, New Brunswick exceed the Canadian Drinking Water Guideline of 9.1×10 -4 mmol/l by up to 5.5×10 -2 mmol/l. It has previously been hypothesized that the influx of DOC from the Saint John River is causing bacterially mediated reductive dissolution of Mn oxides in the aquifer system, leading to elevated aqueous Mn concentrations. Previous work was limited to the collection of water samples from production wells and several observation wells installed in the glacial outwash aquifer. The objective of this study was to investigate the biogeochemical controls on Mn concentrations using sand-filled columns. One column was inoculated with bacteria while a second column was treated with ethanol in order to decrease the microbial population initially present in the system. Both columns received the same influent solution that contained acetate as a source of DOC. The results of the experiments suggested that the two main controls on Mn concentrations in the columns were microbially mediated reductive dissolution of Mn oxides and cation exchange. The conceptual model that was developed based on the experimental data was supported by the results obtained using a one-dimensional reactive-transport model. The reductive dissolution of Mn oxides in the aquifer sands could be adequately simulated using dual-Monod kinetics. Similar trends are observed in the experimental data and field data collected from Production Well 5, located in the Fredericton Aquifer. From the experiments, it is evident that cation-exchange reactions may be an important geochemical control on Mn concentrations during the initial

  17. Stable groundwater quality in deep aquifers of Southern Bangladesh: The case against sustainable abstraction

    Ravenscroft, P., E-mail: [UNICEF, BSL Office Complex, Minto Road, Dhaka 1000 (Bangladesh); McArthur, J.M.; Hoque, M.A. [Earth Sciences, University College London, Gower Street, London WC1E 6BT (United Kingdom)


    In forty six wells > 150 m deep, from across the arsenic-polluted area of south-central Bangladesh, groundwater composition remained unchanged between 1998 and 2011. No evidence of deteriorating water quality was found in terms of arsenic, iron, manganese, boron, barium or salinity over this period of 13 years. These deep tubewells have achieved operating lives of more than 20 years with minimal institutional support. These findings confirm that tubewells tapping the deep aquifers in the Bengal Basin provide a safe, popular, and economic, means of arsenic mitigation and are likely to do so for decades to come. Nevertheless, concerns remain about the sustainability of a resource that could serve as a source of As-safe water to mitigate As-pollution in shallower aquifers in an area where tens of millions of people are exposed to dangerous levels of arsenic in well water. The conjunction of the stable composition in deep groundwater and the severe adverse health effects of arsenic in shallow groundwater lead us to challenge the notion that strong sustainability principles should be applied to the management of deep aquifer abstraction in Bangladesh is, the notion that the deep groundwater resource should be preserved for future generations by protecting it from adverse impacts, probably of a minor nature, that could occur after a long time and might not happen at all. Instead, we advocate an ethical approach to development of the deep aquifer, based on adaptive abstraction management, which allows possibly unsustainable exploitation now in order to alleviate crippling disease and death from arsenic today while also benefiting future generations by improving the health, education and economy of living children. - Highlights: • Tens of millions of people in Bangladesh are affected by arsenic pollution of groundwater. • Deep wells in potentially non-renewable aquifers are the dominant form of mitigation. • Water quality in these aquifers has remained stable for 13

  18. Tracer mass recovery in fractured aquifers estimated from multiple well tests.

    Sanford, William E; Cook, Peter G; Robinson, Neville I; Weatherill, Douglas


    Forced-gradient tracer tests in fractured aquifers often report low mass recoveries. In fractured aquifers, fractures intersected by one borehole may not be intersected by another. As a result (1) injected tracer can follow pathways away from the withdrawal well causing low mass recovery and (2) recovered water can follow pathways not connected to the injection well causing significant tracer dilution. These two effects occur along with other forms of apparent mass loss. If the strength of the connection between wells and the amount of dilution can be predicted ahead of time, tracer tests can be designed to optimize mass recovery and dilution. A technique is developed to use hydraulic tests in fractured aquifers to calculate the conductance (strength of connection) between well pairs and to predict mass recovery and amount of dilution during forced gradient tracer tests. Flow is considered to take place through conduits, which connect the wells to each other and to distant sources or sinks. Mass recovery is related to the proportion of flow leaving the injection well and arriving at the withdrawal well, and dilution is related to the proportion of the flow from the withdrawal well that is derived from the injection well. The technique can be used to choose well pairs for tracer tests, what injection and withdrawal rates to use, and which direction to establish the hydraulic gradient to maximize mass recovery and/or minimize dilution. The method is applied to several tracer tests in fractured aquifers in the Clare Valley, South Australia.

  19. Design and Installation of a Groundwater Monitoring-Well Network in the High Plains Aquifer, Colorado

    Arnold, L.R.; Flynn, J.L.; Paschke, S.S.


    The High Plains aquifer is an important water source for irrigated agriculture and domestic supplies in northeastern Colorado. To address the needs of Colorado's Groundwater Protection Program, the U.S. Geological Survey designed and installed a groundwater monitoring-well network in cooperation with the Colorado Department of Agriculture in 2008 to characterize water quality in the High Plains aquifer underlying areas of irrigated agriculture in eastern Colorado. A 30-well network was designed to provide for statistical representation of water-quality conditions by using a computerized technique to generate randomly distributed potential groundwater sampling sites based on aquifer extent, extent of irrigated agricultural land, depth to water from land surface, and saturated thickness. Twenty of the 30 sites were selected for well installation, and wells were drilled and installed during the period June-September 2008. Lithologic logs and well-construction reports were prepared for each well, and wells were developed after drilling to remove mud and foreign material to provide for good hydraulic connection between the well and aquifer. Documentation of the well-network design, site selection, lithologic logs, well-construction diagrams, and well-development records is presented in this report.

  20. Evaluation of hydrochemical changes due to intensive aquifer exploitation: case studies from Mexico.

    Esteller, M V; Rodríguez, R; Cardona, A; Padilla-Sánchez, L


    The impact of intensive aquifer exploitation has been observed in numerous places around the world. Mexico is a representative example of this problem. In 2010, 101 out of the 653 aquifers recognized in the country, showed negative social, economic, and environmental effects related to intensive exploitation. The environmental effects include, among others, groundwater level decline, subsidence, attenuation, and drying up of springs, decreased river flow, and deterioration of water quality. This study aimed at determining the hydrochemical changes produced by intensive aquifer exploitation and highlighting water quality modifications, taking as example the Valle de Toluca, Salamanca, and San Luis Potosi aquifers in Mexico's highlands. There, elements such as fluoride, arsenic, iron, and manganese have been detected, resulting from the introduction of older groundwater with longer residence times and distinctive chemical composition (regional flows). High concentrations of other elements such as chloride, sulfate, nitrate, and vanadium, as well as pathogens, all related to anthropogenic pollution sources (wastewater infiltration, irrigation return flow, and atmospheric pollutants, among others) were also observed. Some of these elements (nitrate, fluoride, arsenic, iron, and manganese) have shown concentrations above Mexican and World Health Organization drinking water standards.

  1. Geophysical techniques to aquifer locating and monitoring for industrial zones in North Hanoi, Vietnam

    Giang, Nguyen; Duan, Nguyen; Thanh, Le; Hida, Noboru


    Geophysical methods were applied for hydrogeological targets in many countries including Vietnam. This paper presents results of using complex geophysical techniques as well as 2D electrical resistivity imaging (ERI), vertical electrical sounding (VES), very low frequency (VLF), and seismic refraction for geological structure investigation for locating the aquifers and assessing the hydrogeological conditions for groundwater potential in industrial zones of North Hanoi, Vietnam. The locations of two aquifers are determined by their depth and thickness on the basis of resistivity and seismic velocity values which were proved by stratifications of three boreholes to 40-60 m of depth on the study area. There are connections from surface water to shallow aquifer by hydraulic windows, as follows from VLF data. The deeper aquifer can be considered as a potential groundwater supply, but the water level is descending in time, as shown by hydrological monitoring. However, with careful use and by reducing sources of pollution, groundwater can continue to be an important natural resource for future.

  2. Ultramafic-derived arsenic in a fractured bedrock aquifer

    Ryan, P.C.; Kim, J.; Wall, A.J.; Moen, J.C.; Corenthal, L.G.; Chow, D.R.; Sullivan, C.M.; Bright, K.S.


    In the fractured bedrock aquifer of northern Vermont, USA, As concentrations in groundwater range from elements, indicating that As was introduced to the ultramafic rocks during metasomatism by fluids derived from the subducting slab. Evidence from sequential chemical extraction, X-ray diffraction (XRD) and stoichiometric analysis indicates that the majority of the As is located in antigorite and magnesite (MgCO3) with lesser amounts in magnetite (Fe3O4). Hydrochemistry of monitoring wells drilled into fractured ultramafic rock in a groundwater recharge area with no anthropogenic As source reveals above background As (2-9??g/L) and an Mg-HCO3 hydrochemical signature that reflects dissolution of antigorite and magnesite, confirming that As in groundwater can be derived from ultramafic rock dissolution. Arsenic mobility in groundwater affected by ultramafic rock dissolution may be enhanced by alkaline pH values and relatively high HCO3- concentrations. ?? 2011 Elsevier Ltd.

  3. Geochemical implications of brine leakage into freshwater aquifers.

    Wunsch, Assaf; Navarre-Sitchler, Alexis K; McCray, John E


    CO(2) injection into deep saline formations as a way to mitigate climate change raises concerns that leakage of saline waters from the injection formations will impact water quality of overlying aquifers, especially underground sources of drinking water (USDWs). This paper aims to characterize the geochemical composition of deep brines, with a focus on constituents that pose a human health risk and are regulated by the U.S. Environmental Protection Agency (USEPA). A statistical analysis of the NATCARB brine database, combined with simple mixing model calculations, show total dissolved solids and concentrations of chloride, boron, arsenic, sulfate, nitrate, iron and manganese may exceed plant tolerance or regulatory levels. Twelve agricultural crops evaluated for decreased productivity in the event of brine leakage would experience some yield reduction due to increased TDS at brine-USDW ratios of United States are almost three times higher than public and domestic withdrawals.

  4. Stable isotope hydrology in fractured and detritic aquifers at both sides of the South Atlantic Ocean: Mar del Plata (Argentina) and the Rawsonville and Sandspruit river catchment areas (South Africa)

    Glok Galli, Melisa; Damons, Matthew E.; Siwawa, Sitembiso; Bocanegra, Emilia M.; Nel, Jacobus M.; Mazvimavi, Dominic; Martínez, Daniel E.


    The aim of this work is to characterize the isotope composition of water (2H and 18O) in order to establish the relationship between fractured and detritic aquifers in similar hydrological environments located at both sides of the Atlantic Ocean. The Mar del Plata zone, placed in the Argentine Buenos Aires province in South America, and the Rawsonville and Sandspruit river catchment areas, situated in the Western Cape province in South Africa were compared. Rainwater and groundwater samples from fractured and detritic aquifers were analyzed through laser spectroscopy. In both Argentina and South African study sites, stable isotopes data demonstrate an aquifers recharge source from rainfall. For the Mar del Plata region, two different groups of detritic aquifer's samples with distinct recharge processes can be identified due to the close relationship existing between the present hydrogeological environments, the aquifer's grain size sediments and the isotopes contents: one representing rapid infiltration in aquifer sediments of the creeks' palaeobeds and hills zones (sandy or silt sandy sediments) and the other with slow infiltration of evaporated water in plain zones with an aquitard behavior. In the last group, the evaporation process occurs previous infiltration or in the aquifer's non-saturated zone, because of the existence of very low topographic gradients and fine-grained sediments. The evaporation phenomenon is not evident in the Sandspruit river catchment site's detritic aquifer, because its sandy composition allows a faster infiltration rate than in the loess that compounds the Pampeano aquifer in the interfluves zones of the Argentinian study area.

  5. Sensory bases and the mode of feeding behavior of tongue sole Cynoglossus semilaevis

    WANG Xinan; MA Aijun


    We conducted behavior experiments on the roles of vision, olfaction, and the lateral line in feeding in tongue sole Cynoglossus semilaevis Günter. Chemical cues from the prey alone could not elicit any searching or attacking behavior by the fish; only when moving foods were presented, the chemical nature of the foods affected feeding. In addition, we found that normal tongue sole did not accurately recognize moving artificial prey of different shapes. Neither chemosense nor vision plays an important role in prey detection. Reactions to moving objects and the response of the oropharyngeal cavity to different foods showed that the (eyeless) tongue sole use mainly the lateral line for prey detection and capture. Gustation in the oropharyngeal cavity is essential for the fish to swallow its prey.

  6. A marked bounding box method for image data reduction and reconstruction of sole patterns

    Wang, Xingyue; Wu, Jianhua; Zhao, Qingmin; Cheng, Jian; Zhu, Yican


    A novel and efficient method called marked bounding box method based on marching cubes is presented for the point cloud data reduction of sole patterns. This method is characterized in that each bounding box is marked with an index during the process of data reduction and later for use of data reconstruction. The data reconstruction is implemented from the simplified data set by using triangular meshes, the indices being used to search the nearest points from adjacent bounding boxes. Afterwards, the normal vectors are estimated to determine the strength and direction of the surface reflected light. The proposed method is used in a sole pattern classification and query system which uses OpenGL under Visual C++ to render the image of sole patterns. Digital results are given to demonstrate the efficiency and novelty of our method. Finally, conclusion and discussions are made.

  7. Child adjustment in joint-custody versus sole-custody arrangements: a meta-analytic review.

    Bauserman, Robert


    The author meta-analyzed studies comparing child adjustment in joint physical or joint legal custody with sole-custody settings, including comparisons with paternal custody and intact families where possible. Children in joint physical or legal custody were better adjusted than children in sole-custody settings, but no different from those in intact families. More positive adjustment of joint-custody children held for separate comparisons of general adjustment, family relationships, self-esteem, emotional and behavioral adjustment, and divorce-specific adjustment. Joint-custody parents reported less current and past conflict than did sole-custody parents, but this did not explain the better adjustment of joint-custody children. The results are consistent with the hypothesis that joint custody can be advantageous for children in some cases, possibly by facilitating ongoing positive involvement with both parents.

  8. Monitoring Aquifer Depletion from Space: Case Studies from the Saharan and Arabian Aquifers

    Ahmed, M.; Sultan, M.; Wahr, J. M.; Yan, E.


    Access to potable fresh water resources is a human right and a basic requirement for economic development in any society. In arid and semi-arid areas, the characterization and understanding of the geologic and hydrologic settings of, and the controlling factors affecting, these resources is gaining increasing importance due to the challenges posed by increasing population. In these areas, there is immense natural fossil fresh water resources stored in large extensive aquifers, the transboundary aquifers. Yet, natural phenomena (e.g., rainfall patterns and climate change) together with human-related factors (e.g., population growth, unsustainable over-exploitation, and pollution) are threatening the sustainability of these resources. In this study, we are developing and applying an integrated cost-effective approach to investigate the nature (i.e., natural and anthropogenic) and the controlling factors affecting the hydrologic settings of the Saharan (i.e., Nubian Sandstone Aquifer System [NSAS], Northwest Sahara Aquifer System [NWSA]) and Arabian (i.e., Arabian Peninsula Aquifer System [APAS]) aquifer systems. Analysis of the Gravity Recovery and Climate Experiment (GRACE)-derived Terrestrial Water Storage (TWS) inter-annual trends over the NSAS and the APAS revealed two areas of significant TWS depletions; the first correlated with the Dakhla Aquifer System (DAS) in the NSAS and second with the Saq Aquifer System (SAS) in the APAS. Annual depletion rates were estimated at 1.3 × 0.66 × 109 m3/yr and 6.95 × 0.68 × 109 m3/yr for DAS and SAS, respectively. Findings include (1) excessive groundwater extraction, not climatic changes, is responsible for the observed TWS depletions ;(2) the DAS could be consumed in 350 years if extraction rates continue to double every 50 years and the APAS available reserves could be consumed within 60-140 years at present extraction (7.08 × 109 m3/yr) and depletion rates; and (3) observed depletions over DAS and SAS and their

  9. Hydro-geological properties of the Savian aquifer in the county Obrenovac

    Stojadinović Dušan D.


    Full Text Available The paper presents a description of hydrogeological researches of alluvial layers of the Sava River in the area of the source "Vić Bare" near Obrenovac. This source supplies groundwater to that town. The depth of these layers amounts to 25 m. With regard to collecting capacity, the most significant are gravel-sand sediments of high filtration properties. Their average depth amounts to about 13 m with the underlying layer made of Pleistocene clays. Compact aquifer is formed within these sediments and it refills partly from the Sava River at places where river cuts its channel into the gravel-sand layer. The analysis of the groundwater regime in the riparian area points out that groundwater levels follow stages of the Sava River. Such an influence lessens with the distance. Established hydraulic connection between the river and the aquifer enables its permanent replenishment. On the other hand, due to certain pollutions this river flow might bring along, it represents a potential danger. Those pollutions could enter water-bearing layer of the aquifer as well as the exploitation well of the source. Such presumptions have been confirmed in the experiment of pollution transport carried out in the water-bearing layer. Unabsorbable chloride was used as a tracer whose movement velocity through exploitation well proved that there were real possibilities of intrusion of aggressive pollutants into the water-bearing layer and into the aquifer as well. Therefore, the protection of the source must be in the function of the protection of surface waters.

  10. Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

    Kresse, Timothy M.; Hays, Phillip D.; Merriman, Katherine R.; Gillip, Jonathan A.; Fugitt, D. Todd; Spellman, Jane L.; Nottmeier, Anna M.; Westerman, Drew A.; Blackstock, Joshua M.; Battreal, James L.


    Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State.

  11. Metamorphic sole formation, emplacement and blueschist overprint: early obduction dynamics witnessed by W. Turkey ophiolites

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Soret, Mathieu; Okay, Aral; Whitechurch, Hubert


    Western Turkey, with a >200 km long-belt of unmetamorphosed ophiolite overlying continental lithosphere is one or even the largest obducted ophiolite on Earth and therefore a key example to study obduction and early subduction dynamics. All Western Turkish ophiolite fragments are considered as part of the same Neotethyan branch resulting of a long-lived continental subduction (or underthrusting). Synchronous (ca. ~ 93 Ma) metamorphic sole formation and preservation at the base of most of the Turkish ophiolite fragments support this single event and place a strong constraint on the age of subduction initiation. Metamorphic soles are indeed generally considered to have formed during the early and hot subduction zone at 25 ± 10 km depths and welded to the overriding oceanic lithosphere. In Western Turkey however (as for most places worldwide) a systematic study of the pressure-temperature conditions with modern thermobarometric tools is generally lacking, and fundamental mechanisms of formation or accretion to the upper plate are poorly (if at all) constrained. We herein reappraise Western Turkish metamorphic soles focusing on the following points and issues: (i) detailed structures of metamorphic sole and other subduction derived units, petrological evolution and refined pressure-temperature conditions; peak pressure-temperature conditions of metamorphic sole were estimated using garnet, clinopyroxene, amphibole and plagioclase as the peak paragenesis at 10.5 ± 2 kbar and 800 ± 50°C based on pseudosections using the Theriak/Domino package (ii) the rather unique (and enigmatic) blueschist facies overprint found in places was investigated in terms of structural position and pressure-temperature conditions. Conditions of overprint were estimated around 12 kbar and 425 °C from the presence of glaucophane, lawsonite, jadeite and garnet overgrowing the amphibolite-facies assemblage. This field-based study provides clues to mechanisms of metamorphic sole underplating

  12. Evaluation of water-quality characteristics of part of the Spokane Aquifer, Washington and Idaho, using a solute-transport digital model

    Vaccaro, J.J.; Bolke, E.L.


    The principal dissolved constituents in water in the Spokane aquifer are calcium and bicarbonate. These constituents (as well as dissolved solids, hardness, and magnesium) each correlate well with specific conductance, whereas chloride, sodium, and nitrate each do not. Specific conductance ranges from 73 to 820 micromhos per centimeter throughout the study area. Short-term variations in water quality in the Spokane aquifer are generally greater than long-term variations. Vertical variations in concentration of chemical constituents occurred in four of 15 wells used to sample the upper 50 feet of the aquifer along several cross sections. Changes in water quality from one cross section to another could not be directly related to land-use activities. A digital model was developed and used to simulate solute transport of conservative ions in the Spokane aquifer. Specifically, the model was used to estimate the impact of the chloride ion from recharge through septic tanks and from irrigation on the water quality of the aquifer. Analysis shows that the estimated impact on the aquifer from these two source loadings was less than a 1-milligram-per-liter increase throughout approximately 80 percent of the aquifer, but increases averaging about 3 milligrams per liter occurred in some peripheral areas. Various water-quality-management schemes based on manmade or natural stresses can be tested with the model.


    Cationic surfactants can be used to modify surfaces of soils and subsurface materials to promote sorption of hydrophobic organic compounds (HOC) and retard their migration. For example, cationic surfactants could be injected into an aquifer downgradient from a source of HOC conta...

  14. In-situ metal precipitation in a zinc-aerobic, sandy aquifer by means of biological sulfate reduction

    Janssen, G.M.C.M.; Temminghoff, E.J.M.


    The applicability of in situ metal precipitation (ISMP) based on bacterial sulfate reduction (BSR) with molasses as carbon source was tested for the immobilization of a zinc plume in an aquifer with highly unsuitable initial conditions (high Eh, low pH, low organic matter content, and low sulfate co

  15. Robust design in generelaised linear models for improving the quality of polyurethane soles

    Castro, Armando Mares


    Full Text Available In a process that manufactures polyurethane soles by casting, a number of problems lead to different types of defects on the sole, causing significant economic losses for the company. In order to improve the product quality and decrease the number of defects, this study conducts an experimental design in the context of robust design. Since the response variable is binary, the statistical analysis was performed using generalised linear models. The operational methodology reduced the percentage of defects, while combining the experimental technique and control systems to achieve superior quality and a consequent reduction in costs.

  16. SOLE: Applying Semantics and Social Web to Support Technology Enhanced Learning in Software Engineering

    Colomo-Palacios, Ricardo; Jiménez-López, Diego; García-Crespo, Ángel; Blanco-Iglesias, Borja

    eLearning educative processes are a challenge for educative institutions and education professionals. In an environment in which learning resources are being produced, catalogued and stored using innovative ways, SOLE provides a platform in which exam questions can be produced supported by Web 2.0 tools, catalogued and labeled via semantic web and stored and distributed using eLearning standards. This paper presents, SOLE, a social network of exam questions sharing particularized for Software Engineering domain, based on semantics and built using semantic web and eLearning standards, such as IMS Question and Test Interoperability specification 2.1.

  17. Status of groundwater levels and storage volume in the Equus Beds aquifer near Wichita, Kansas, January 2016

    Klager, Brian J.


    The Equus Beds aquifer in south-central Kansas, which is part of the High Plains aquifer, serves as a source of water for municipal and agricultural users in the area. The city of Wichita has used the Equus Beds aquifer as one of its primary water sources since the 1940s. The aquifer in and around Wichita’s well field reached historically low water levels in 1993, prompting the city to adopt new water-use and conservation strategies to ensure future water supply needs were met. Part of the plan was to initiate a managed aquifer recharge program called the Equus Beds Aquifer Storage and Recovery project. The goal of the managed aquifer recharge program is to artificially recharge the Equus Beds aquifer with treated water from the Little Arkansas River. As part of the Equus Beds Aquifer Storage and Recovery project, the city of Wichita and the U.S. Geological Survey have partnered in a long-term cooperative study to monitor and describe the quantity and quality of the water in the Equus Beds aquifer and the Little Arkansas River.The city of Wichita, the Equus Beds Groundwater Management District No. 2, the Kansas Department of Agriculture–Division of Water Resources, and the U.S. Geological Survey collected groundwater levels in numerous wells screened in the Equus Beds aquifer in the area in and around Wichita’s well field in January 2016. The measurements were used to interpolate potentiometric surfaces for shallow and deep parts of the aquifer in the study area. These potentiometric surfaces were compared with potentiometric surfaces from previous years to estimate changes in water levels and storage volume in the study area.Groundwater levels were generally higher in January 2016 than they were in January 2015. On average, in January 2016, groundwater levels in the shallow part of the aquifer were about 3.4 feet higher and groundwater levels in the deep part of the aquifer were about 3.8 feet higher than in January 2015. The volume of water stored in the

  18. Borehole Geophysical, Water-Level, and Water-Quality Investigation of a Monitoring Well Completed in the St. Francois Aquifer in Oregon County, Missouri, 2005-08

    Schumacher, John G.; Kleeschulte, Michael J.


    A deep (more than 2,000 feet) monitoring well was installed in an area being explored for lead and zinc deposits within the Mark Twain National Forest in southern Missouri. The area is a mature karst terrain where rocks of the Ozark aquifer, a primary source of water for private and public supplies and major springs in the nearby Eleven Point National Wild and Scenic River and the Ozark National Scenic Riverways, are exposed at the surface. The potential lead deposits lie about 2,000 feet below the surface within a deeper aquifer, called the St. Francois aquifer. The two aquifers are separated by the St. Francois confining unit. The monitoring well was installed as part of a series of investigations to examine potentiometric head relations and water-quality differences between the two aquifers. Results of borehole flowmeter measurements in the open borehole and water-level measurements from the completed monitoring well USGS-D1 indicate that a seasonal upward gradient exists between the St. Francois aquifer and the overlying Ozark aquifer from about September through February. The upward potentiometric heads across the St. Francois confining unit that separates the two aquifers averaged 13.40 feet. Large reversals in this upward gradient occurred during the late winter through summer (about February through August) when water levels in the Ozark aquifer were as much as 138.47 feet higher (average of 53.84 feet) than water levels in the St. Francois aquifer. Most of the fluctuation of potentiometric gradient is caused by precipitation and rapid recharge that cause large and rapid increases in water levels in the Ozark aquifer. Analysis of water-quality samples collected from the St. Francois aquifer interval of the monitoring well indicated a sodium-chloride type water containing dissolved-solids concentrations as large as 1,300 milligrams per liter and large concentrations of sodium, chloride, sulfate, boron, and lithium. In contrast, water in the overlying Ozark

  19. Development of a process-oriented vulnerability concept for water travel time in karst aquifers-case study of Tanour and Rasoun springs catchment area.

    Hamdan, Ibraheem; Sauter, Martin; Ptak, Thomas; Wiegand, Bettina; Margane, Armin; Toll, Mathias


    Key words: Karst aquifer, water travel time, vulnerability assessment, Jordan. The understanding of the groundwater pathways and movement through karst aquifers, and the karst aquifer response to precipitation events especially in the arid to semi-arid areas is fundamental to evaluate pollution risks from point and non-point sources. In spite of the great importance of the karst aquifer for drinking purposes, karst aquifers are highly sensitive to contamination events due to the fast connections between the land-surface and the groundwater (through the karst features) which is makes groundwater quality issues within karst systems very complicated. Within this study, different methods and approaches were developed and applied in order to characterise the karst aquifer system of the Tanour and Rasoun springs (NW-Jordan) and the flow dynamics within the aquifer, and to develop a process-oriented method for vulnerability assessment based on the monitoring of different multi-spatially variable parameters of water travel time in karst aquifer. In general, this study aims to achieve two main objectives: 1. Characterization of the karst aquifer system and flow dynamics. 2. Development of a process-oriented method for vulnerability assessment based on spatially variable parameters of travel time. In order to achieve these aims, different approaches and methods were applied starting from the understanding of the geological and hydrogeological characteristics of the karst aquifer and its vulnerability against pollutants, to using different methods, procedures and monitored parameters in order to determine the water travel time within the aquifer and investigate its response to precipitation event and, finally, with the study of the aquifer response to pollution events. The integrated breakthrough signal obtained from the applied methods and procedures including the using of stable isotopes of oxygen and hydrogen, the monitoring of multi qualitative and quantitative parameters

  20. Accepting managed aquifer recharge of urban storm water reuse: The role of policy-related factors

    Mankad, Aditi; Walton, Andrea


    A between-groups experimental design examined public acceptance for managed aquifer recharge of storm water for indirect potable and nonpotable reuse; acceptance was based on five policy-related variables (fairness, effectiveness, trust, importance of safety assurances, and importance of communication activities). Results showed that public acceptance (N = 408) for managed aquifer recharge of storm water was higher for nonpotable applications, as was the importance of safety assurances. Analyses of variance also showed that perceptions of fairness and effectiveness were higher for a nonpotable scheme, but not trust. A three-step hierarchical regression (Step 1: age, gender, education, and income; Step 2: type of use; Step 3: fairness, effectiveness, trust, safety assurance, and communication activities) demonstrated that type of storm water use and the policy-related factors accounted for 73% of the variance in acceptance of storm water (R2 = 0.74, adjusted R2 = 0.74, F (10, 397) = 113.919, p related factors were also significant individual predictors of acceptance. The most important predictors were perceptions of trust in water authorities, perceptions of effectiveness, and perceptions of fairness. Interestingly, while safety assurance was important in attitudinal acceptance of managed