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Sample records for soil screening levels

  1. Sensitivity of ecological soil-screening levels for metals to exposure model parameterization and toxicity reference values.

    Science.gov (United States)

    Sample, Bradley E; Fairbrother, Anne; Kaiser, Ashley; Law, Sheryl; Adams, Bill

    2014-10-01

    Ecological soil-screening levels (Eco-SSLs) were developed by the United States Environmental Protection Agency (USEPA) for the purposes of setting conservative soil screening values that can be used to eliminate the need for further ecological assessment for specific analytes at a given site. Ecological soil-screening levels for wildlife represent a simplified dietary exposure model solved in terms of soil concentrations to produce exposure equal to a no-observed-adverse-effect toxicity reference value (TRV). Sensitivity analyses were performed for 6 avian and mammalian model species, and 16 metals/metalloids for which Eco-SSLs have been developed. The relative influence of model parameters was expressed as the absolute value of the range of variation observed in the resulting soil concentration when exposure is equal to the TRV. Rank analysis of variance was used to identify parameters with greatest influence on model output. For both birds and mammals, soil ingestion displayed the broadest overall range (variability), although TRVs consistently had the greatest influence on calculated soil concentrations; bioavailability in food was consistently the least influential parameter, although an important site-specific variable. Relative importance of parameters differed by trophic group. Soil ingestion ranked 2nd for carnivores and herbivores, but was 4th for invertivores. Different patterns were exhibited, depending on which parameter, trophic group, and analyte combination was considered. The approach for TRV selection was also examined in detail, with Cu as the representative analyte. The underlying assumption that generic body-weight-normalized TRVs can be used to derive protective levels for any species is not supported by the data. Whereas the use of site-, species-, and analyte-specific exposure parameters is recommended to reduce variation in exposure estimates (soil protection level), improvement of TRVs is more problematic. © 2014 The Authors

  2. 'Becquerel screening' device to automatically measure activity level of contaminated soil in flexible containers

    International Nuclear Information System (INIS)

    Okada, Hisashi; Yamaguchi, Yoshihisa; Yamamoto, Shuji

    2014-01-01

    Contaminated soil and incineration ash collected during offsite decontamination work following the accident at the Fukushima Daiichi Nuclear Power Station of Tokyo Electric Power Co., Inc. is being stored in flexible containers. These containers are managed taking their activity level into account in accordance with the Decontamination Guidelines issued by the Ministry of the Environment. Toshiba has developed the 'Becquerel Screening' device that can automatically measure the activity level of the contents of each flexible container simply by placing the container on a palette, without the need to take samples for analysis from the container. The Becquerel Screening device is expected to contribute not only to improved operational efficiency but also to reduced exposure of operators to radiation, because it eliminates the need for direct contact with contaminated soil and ash. (author)

  3. Initial screening of thermal desorption for soil remediation

    International Nuclear Information System (INIS)

    Yezzi, J.J. Jr.; Tafuri, A.N.; Rosenthal, S.; Troxler, W.L.

    1994-01-01

    Petroleum-contaminated soils--caused by spills, leaks, and accidental discharges--exist at many sites throughout the United States. Thermal desorption technologies which are increasingly being employed to treat these soils, have met soil cleanup criteria for a variety of petroleum products. Currently the United States Environmental Protection Agency is finalizing a technical report entitled Use of Thermal Desorption for Treating Petroleum-Contaminated Soils to assist remedial project managers, site owners, remediation contractors, and equipment vendors in evaluating the use of thermal desorption technologies for petroleum-contaminated soil applications. The report will present a three-level screening method to help a reader predict the success of applying thermal desorption at a specific site. The objective of screening level one is to determine the likelihood of success in a specific application of thermal desorption. It will take into account procedures for collecting and evaluating data on site characteristics, contaminant characteristics, soil characteristics, and regulatory requirements. This level will establish whether or not thermal desorption should be evaluated further for site remediation, whether treatment should occur on-site or off-site, and if on-site is a viable option, what system size will be most cost-effective. The scope of this paper addresses only screening level one which provides a preliminary assessment of the applicability of thermal desorption to a particular site. This topic encompasses worksheets that are an integral part of the ''user friendly'' screening process. Level one screening provides a foundation for the subsequent two levels which follow a similar ''user friendly'' worksheet approach to evaluating thermal desorption technologies and establishing costs for thermal desorption in an overall remediation project

  4. Determination of soil screening levels for natural radionuclides in Minas Gerais state, Brazil

    International Nuclear Information System (INIS)

    Peixoto, Claudia Marques; Jacomino, Vanusa Maria Feliciano; Balaine, Fernando; Taddei, Maria Helena

    2013-01-01

    Soil screening levels express the levels of contaminant concentration in the soil, which guide the actions to be taken following investigation to confirm contamination. The list of toxic substances or elements under Brazilian legislation includes organics, volatile organics and metals but does not consider radioactive elements. Radioactive elements are all potentially carcinogenic and therefore need to be subject to legal control. The National Nuclear Energy Commission, the federal agency currently responsible for legislation regarding the control of Naturally-Occurring Radioactive Material (NORM) facilities does not establish guiding values for intervention in terms of soil activity concentration in the case of contamination with radioactive elements. In mining, the processing and treating of ores such as cassiterite, uranium, phosphate, niobium, and rare earths contribute to the generation of large amounts of NORM residues. Obviously, the improper disposal of these materials may lead to situations that result in soil and groundwater contamination and unnecessary exposure of the population in general. In order to establish guiding values for soil quality for natural radionuclides in the state of Minas Gerais, the study area included the entire state, which has unique characteristics related to the lithology, genesis, and morphology of the soils. These characteristics have tremendous influence on the petrogeochemistry of elements and radionuclides. A total of 110 soil samples were collected and analyzed in order to determine the activity concentration of U, Th, 226Ra, 228Ra e 210Pb. In general, it was possible to verify that the activity concentrations of U are higher than those of Th. This fact can be explained by the intense weathering that most of the state's soil has undergone and the chemical and geochemical characteristics of the two elements. The values obtained up to the present are higher than the reference values for soil quality adopted in other parts of

  5. 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE). Screening-Level Feasibility Assessment and Design Tool in Support of 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE) ESTCP Project ER 201326

    Science.gov (United States)

    2017-10-01

    USER GUIDE 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE) Screening-Level Feasibility Assessment and Design Tool in...Support of 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE) ESTCP Project ER-201326 OCTOBER 2017 Rob Hinchee Integrated Science...Technology, Inc. 1509 Coastal Highway Panacea, FL 32346 8/8/2013 - 8/8/2018 10-2017 1,4-Dioxane Remediation by Extreme Soil Vapor Extraction (XSVE) Screening

  6. Screening-level risk assessment for styrene-acrylonitrile (SAN) trimer detected in soil and groundwater.

    Science.gov (United States)

    Kirman, C R; Gargas, M L; Collins, J J; Rowlands, J C

    2012-01-01

    A screening-level risk assessment was conducted for styrene-acrylonitrile (SAN) Trimer detected at the Reich Farm Superfund site in Toms River, NJ. Consistent with a screening-level approach, on-site and off-site exposure scenarios were evaluated using assumptions that are expected to overestimate actual exposures and hazards at the site. Environmental sampling data collected for soil and groundwater were used to estimate exposure point concentrations. Several exposure scenarios were evaluated to assess potential on-site and off-site exposures, using parameter values for exposures to soil (oral, inhalation of particulates, and dermal contact) and groundwater (oral, dermal contact) to reflect central tendency exposure (CTE) and reasonable maximum exposure (RME) conditions. Three reference dose (RfD) values were derived for SAN Trimer for short-term, subchronic, and chronic exposures, based upon its effects on the liver in exposed rats. Benchmark (BMD) methods were used to assess the relationship between exposure and response, and to characterize appropriate points of departure (POD) for each RfD. An uncertainty factor of 300 was applied to each POD to yield RfD values of 0.1, 0.04, and 0.03 mg/kg-d for short-term, subchronic, and chronic exposures, respectively. Because a chronic cancer bioassay for SAN Trimer in rats (NTP 2011a) does not provide evidence of carcinogenicity, a cancer risk assessment is not appropriate for this chemical. Potential health hazards to human health were assessed using a hazard index (HI) approach, which considers the ratio of exposure dose (i.e., average daily dose, mg/kg-d) to toxicity dose (RfD, mg/kg-d) for each scenario. All CTE and RME HI values are well below 1 (where the average daily dose is equivalent to the RfD), indicating that there is no concern for potential noncancer effects in exposed populations even under the conservative assumptions of this screening-level assessment.

  7. Screening-Level Risk Assessment for Styrene-Acrylonitrile (SAN) Trimer Detected in Soil and Groundwater

    Science.gov (United States)

    Kirman, C. R.; Gargas, M. L.; Collins, J. J.; Rowlands, J. C.

    2012-01-01

    A screening-level risk assessment was conducted for styrene-acrylonitrile (SAN) Trimer detected at the Reich Farm Superfund site in Toms River, NJ. Consistent with a screening-level approach, on-site and off-site exposure scenarios were evaluated using assumptions that are expected to overestimate actual exposures and hazards at the site. Environmental sampling data collected for soil and groundwater were used to estimate exposure point concentrations. Several exposure scenarios were evaluated to assess potential on-site and off-site exposures, using parameter values for exposures to soil (oral, inhalation of particulates, and dermal contact) and groundwater (oral, dermal contact) to reflect central tendency exposure (CTE) and reasonable maximum exposure (RME) conditions. Three reference dose (RfD) values were derived for SAN Trimer for short-term, subchronic, and chronic exposures, based upon its effects on the liver in exposed rats. Benchmark (BMD) methods were used to assess the relationship between exposure and response, and to characterize appropriate points of departure (POD) for each RfD. An uncertainty factor of 300 was applied to each POD to yield RfD values of 0.1, 0.04, and 0.03 mg/kg-d for short-term, subchronic, and chronic exposures, respectively. Because a chronic cancer bioassay for SAN Trimer in rats (NTP 2011a) does not provide evidence of carcinogenicity, a cancer risk assessment is not appropriate for this chemical. Potential health hazards to human health were assessed using a hazard index (HI) approach, which considers the ratio of exposure dose (i.e., average daily dose, mg/kg-d) to toxicity dose (RfD, mg/kg-d) for each scenario. All CTE and RME HI values are well below 1 (where the average daily dose is equivalent to the RfD), indicating that there is no concern for potential noncancer effects in exposed populations even under the conservative assumptions of this screening-level assessment. PMID:23030654

  8. A Model for determination of screening levels for radioactive elements in soil

    International Nuclear Information System (INIS)

    Peres, Ana C.; Hiromoto, Goro

    2008-01-01

    Full text: At the present, decision about clean-up of Brazilian sites contaminated with radioactive isotopes is addressed on a case-by-case basis, since there is no general guidance or recommendation to support actions in early phases of the problem identification. For chemicals, CETESB - the governmental organization responsible for preventing and controlling environmental pollution in Sao Paulo State - established quality reference values for prevention and intervention, as the first step to implement a remediation policy based on human health risk assessment. The aim of this study is to develop a methodology for the establishment of target values for radioactive soil contamination, as far as possible consistent and compatible with the approach adopted by CETESB for sites contaminated with chemicals. The following steps have been addressed in this study: conceptual scenario and model development; codification of the equations in an electronic spreadsheet; selection of proper input values; derivation of the intervention levels for selected radionuclides using Monte Carlo methods. The mathematical model developed was mainly based on the equations used by the U.S. Environmental Protection Agency and by the National Council on Radiation Protection and Measurements for soil screening purposes. Results are presented for selected natural and man-made radioactive isotopes. (author)

  9. Assessment of soil screening levels due to ingestion and dermal absorption of chrysene and benzo[k]fluoranthene and appropriate remediation method for Dorson Abad.

    Science.gov (United States)

    Gitipour, Saeid; Firouzbakht, Saeid; Mirzaee, Ehsan; Alimohammadi, Masoumeh

    2014-06-01

    For years, the Dorson Abad region has been extremely polluted by Tehran Oil Refinery due to leaking from its underground pipelines, storage tanks, and evaporation ponds. To assess the concentrations of hazardous polycyclic aromatic hydrocarbon (PAH) compounds, soil samples were collected from the grounds at and adjacent to a polluted stream located in the study area. The samples were then analyzed, and the results revealed that 12 of the 16 USEPA PAHs were noticeably present in the soil, which, among them, benzo[k]fluoranthene and chrysene had the highest concentrations with averages of 357.17 and 173.38 mg/kg, respectively. A comparison of the obtained concentrations with the soil screening levels indicated that both benzo[k]fluoranthene and chrysene concentrations were substantially higher than EPA screening level values, signifying the necessity of soil remediation for these contaminants in the area. Techniques such as soil washing/flushing, high temperature thermal desorption, and solidification/stabilization were investigated for treatment of the contaminated soil; solidification/stabilization is recommended as an applicable and cost-effective remediation method for Dorson Abad due to the size of the region, relatively low cost of the binder (cement), and low volatility of benzo[k]fluoranthene and chrysene.

  10. A BENCHMARKING ANALYSIS FOR FIVE RADIONUCLIDE VADOSE ZONE MODELS (CHAIN, MULTIMED_DP, FECTUZ, HYDRUS, AND CHAIN 2D) IN SOIL SCREENING LEVEL CALCULATIONS

    Science.gov (United States)

    Five radionuclide vadose zone models with different degrees of complexity (CHAIN, MULTIMED_DP, FECTUZ, HYDRUS, and CHAIN 2D) were selected for use in soil screening level (SSL) calculations. A benchmarking analysis between the models was conducted for a radionuclide (99Tc) rele...

  11. Surfactant screening of diesel-contaminated soil

    International Nuclear Information System (INIS)

    Peters, R.W.; Shem, L.; Montemagno, C.D.; Lewis, B.

    1991-01-01

    At one installation, approximately 60,000 gal of No. 2 diesel fuel leaked into the subsurface environment, with contamination at depths of 6 to 34 m below the surface. Argonne National Laboratory was contracted to perform treatability studies for site remediation. The treatability studies focused on four separate phases: (1) leachability studies on the various contaminated soil borings, (2) air stripping studies, (3) bioremediation studies, and (4) surfactant screening/surfactant flooding studies. This paper summarizes the fourth phase of the research program in which 21 surfactants were screened for possible use to mobilize the organics from the contaminated soil prior to bioremediation. Anionic surfactants resulted in the greatest degree of diesel mobilization. The most promising surfactants will be employed on actual contaminated soil samples obtained from the site

  12. Surfactant screening of diesel-contaminated soil

    International Nuclear Information System (INIS)

    Peters, R.W.; Montemagno, C.D.; Shem, L.; Lewis, B.-A.

    1992-01-01

    At one installation in California, approximately 60,000 gal of No. 2 diesel fuel leaked into the subsurface environment, resulting in contamination at depths from 6 to 34 m below the surface. Argonne National Laboratory was contracted to perform treatability studies for site remediation. This paper summarizes a surfactant screening/surfactant flooding research program in which 22 surfactants were screened for their effectiveness in mobilizing the organics from the contaminated soil prior to bioremediation. Anionic surfactants resulted in the greatest degree of diesel mobilization. The most promising surfactants will be employed on contaminated soil samples obtained from the site

  13. Ecological Screening Values for Surface Water, Sediment, and Soil: 2005 Update

    Energy Technology Data Exchange (ETDEWEB)

    Friday, G. P.

    2005-07-18

    One of the principal components of the environmental remediation program at the Savannah River Site (SRS) is the assessment of ecological risk. Used to support CERCLA, RCRA, and DOE orders, the ecological risk assessment (ERA) can identify environmental hazards and evaluate remedial action alternatives. Ecological risk assessment is also an essential means for achieving DOE's risk based end state vision for the disposition of nuclear material and waste hazards, the decommissioning of facilities, and the remediation of inactive waste units at SRS. The complexity of an ERA ranges from a screening level ERA (SLERA) to a full baseline ERA. A screening level ecological risk assessments, although abbreviated from a baseline risk assessment, is nonetheless considered a complete risk assessment (EPA, 2001a). One of the initial tasks of any ERA is to identify constituents that potentially or adversely affect the environment. Typically, this is accomplished by comparing a constituent's maximum concentration in surface water, sediment, or soil with an ecological screening value (ESV). The screening process can eliminate many constituents from further consideration in the risk assessment, but it also identifies those that require additional evaluation. This document is an update of a previous compilation (Friday, 1998) and provides a comprehensive listing of ecological screening values for surface water, sediment, and soil. It describes how the screening values were derived and recommends benchmarks that can be used for ecological risk assessment. The sources of these updated benchmarks include the U.S. Environmental Protection Agency (EPA), U.S. Fish and Wildlife Service (USFWS), U.S. Geological Survey (USGS), National Oceanic and Atmospheric Administration (NOAA), Oak Ridge National Laboratory (ORNL), the State of Florida, the Canadian Council of Ministers of the Environment (CCME), the Dutch Ministry of the Environment (RIVM), and the scientific literature. It

  14. Comparison of field screening techniques with fuel-contaminated soils

    International Nuclear Information System (INIS)

    Klopp, C.; Turriff, D.

    1995-01-01

    This paper presents the results of a comparison of four field screening techniques. Field screenings, is an important part of conducting cost-effective and comprehensive site investigations. Regulators limit the use of field screening in lieu of laboratory analyses, in part, because there is little information on the accuracy and precision of field screening techniques. The results here represent a step forward towards a better understanding of the accuracy and practicality of field screening methods. The authors hope that the role of field screening in site investigation will increase as this type of information becomes more available. Innovative techniques for homogenizing soils were used to allow simultaneous analysis of hydrocarbon contaminated soils using field GCs, immunoassays, ''jar headspace'' and ''Lab in a Bag.'' The results shown here illustrate the variability of field screening results and the importance of good method development and operator competency. Certainly more work in this area is needed to truly characterize field screening techniques

  15. Reevaluation of 1999 Health-Based Environmental Screening Levels (HBESLs) for Chemical Warfare Agents

    Energy Technology Data Exchange (ETDEWEB)

    Watson, Annetta Paule [ORNL; Dolislager, Fredrick G [ORNL

    2007-05-01

    This report evaluates whether new information and updated scientific models require that changes be made to previously published health-based environmental soil screening levels (HBESLs) and associated environmental fate/breakdown information for chemical warfare agents (USACHPPM 1999). Specifically, the present evaluation describes and compares changes that have been made since 1999 to U.S. Environmental Protection Agency (EPA) risk assessment models, EPA exposure assumptions, as well as to specific chemical warfare agent parameters (e.g., toxicity values). Comparison was made between screening value estimates recalculated with current assumptions and earlier health-based environmental screening levels presented in 1999. The chemical warfare agents evaluated include the G-series and VX nerve agents and the vesicants sulfur mustard (agent HD) and Lewisite (agent L). In addition, key degradation products of these agents were also evaluated. Study findings indicate that the combined effect of updates and/or changes to EPA risk models, EPA default exposure parameters, and certain chemical warfare agent toxicity criteria does not result in significant alteration to the USACHPPM (1999) health-based environmental screening level estimates for the G-series and VX nerve agents or the vesicant agents HD and L. Given that EPA's final position on separate Tier 1 screening levels for indoor and outdoor worker screening assessments has not yet been released as of May 2007, the study authors find that the 1999 screening level estimates (see Table ES.1) are still appropriate and protective for screening residential as well as nonresidential sites. As such, risk management decisions made on the basis of USACHPPM (1999) recommendations do not require reconsideration. While the 1999 HBESL values are appropriate for continued use as general screening criteria, the updated '2007' estimates (presented below) that follow the new EPA protocols currently under development

  16. A model for determination of screening level for radioactive elements in soil

    International Nuclear Information System (INIS)

    Peres, Ana Claudia

    2007-01-01

    At the present, decision about clean-up of Brazilian sites contaminated with radioactive isotopes is addressed on a case-by-case basis, since there is no general guidance or recommendation to support actions in early phases of the problem identification. For chemicals, CETESB - the governmental organization responsible for preventing and controlling environmental pollution in Sao Paulo State - established background values, prevention and intervention, as the first step to implement a remediation actions based on human health risk assessment. The aim of this study was to develop a methodology for the establishment of target values for radioactive soil contamination, as far as possible consistent and compatible with the approach adopted by CETESB for sites contaminated with chemicals. The following steps have been addressed in this study: conceptual scenario and model development; codification of the equations in an electronic spreadsheet; selection of proper range and statistical distribution of the input values; derivation of the intervention levels for selected radionuclides using Monte Carlo methods. The mathematical model developed was mainly based on the equations used by the U.S. Environmental Protection Agency (EPA) and by the National Council on Radiation Protection and Measurements (NCRP) for soil screening purposes. Intervention and prevention values are presented for adult and 10 years old child, for each 3 exposure scenarios: agricultural, residential and industrial; the following radionuclides were considered: 3 H, 14 C, 32 P, 35 S, 45 Ca, 51 Cr, 90 Sr, 125 I, 131 I, 134 Cs, 137 Cs, 210 Pb, 226 Ra, 228 Ra, 232 Th, 238 U, 239 Pu and 241 Am. Quality reference values were determined for 40 K, 137 Cs, 210 Pb, 226 Ra, 228 Ra, 228 Th, Th-nat e U-nat. Results obtained in this study showed a good agreement with those reported by NCRP, considering that the equations and the input data used in both models are not the same ones.(author)

  17. Terrestrial avoidance behaviour tests as screening tool to assess soil contamination

    International Nuclear Information System (INIS)

    Loureiro, Susana; Soares, Amadeu M.V.M.; Nogueira, Antonio J.A.

    2005-01-01

    To assess soil quality and risk assessment, bioassays can be useful tools to gauge the potential toxicity of contaminants focusing on their bioavailable fraction. A rapid and sublethal avoidance behaviour test was used as a screening tool with the earthworm Eisenia andrei and the isopod Porcellionides pruinosus, where organisms were exposed during 48 h to several chemicals (lindane, dimethoate and copper sulphate, for isopods and carbendazim, benomyl, dimethoate and copper sulphate for earthworms). Both species were also exposed to soils from an abandoned mine. For all bioassays a statistical approach was used to derive EC 50 values. Isopods and earthworms were able to perceive the presence of toxic compounds and escaping from contaminated to clean soil. Furthermore the behaviour parameter was equally or more sensitive then other sublethal parameters (e.g. reproduction or growth), expressing the advantages of Avoidance Behaviour Tests as screening tools in ERA. - Avoidance Behaviour Tests with earthworms and isopods can be used as screening tools in the evaluation of soil contamination

  18. Improved exposure estimation in soil screening and cleanup criteria for volatile organic chemicals.

    Science.gov (United States)

    DeVaull, George E

    2017-09-01

    Soil cleanup criteria define acceptable concentrations of organic chemical constituents for exposed humans. These criteria sum the estimated soil exposure over multiple pathways. Assumptions for ingestion, dermal contact, and dust exposure generally presume a chemical persists in surface soils at a constant concentration level for the entire exposure duration. For volatile chemicals, this is an unrealistic assumption. A calculation method is presented for surficial soil criteria that include volatile depletion of chemical for these uptake pathways. The depletion estimates compare favorably with measured concentration profiles and with field measurements of soil concentration. Corresponding volatilization estimates compare favorably with measured data for a wide range of volatile and semivolatile chemicals, including instances with and without the presence of a mixed-chemical residual phase. Selected examples show application of the revised factors in estimating screening levels for benzene in surficial soils. Integr Environ Assess Manag 2017;13:861-869. © 2017 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC). © 2017 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

  19. Derivation of soil screening thresholds to protect chisel-toothed kangaroo rat from uranium mine waste in northern Arizona

    Science.gov (United States)

    Hinck, Jo E.; Linder, Greg L.; Otton, James K.; Finger, Susan E.; Little, Edward E.; Tillitt, Donald E.

    2013-01-01

    Chemical data from soil and weathered waste material samples collected from five uranium mines north of the Grand Canyon (three reclaimed, one mined but not reclaimed, and one never mined) were used in a screening-level risk analysis for the Arizona chisel-toothed kangaroo rat (Dipodomys microps leucotis); risks from radiation exposure were not evaluated. Dietary toxicity reference values were used to estimate soil-screening thresholds presenting risk to kangaroo rats. Sensitivity analyses indicated that body weight critically affected outcomes of exposed-dose calculations; juvenile kangaroo rats were more sensitive to the inorganic constituent toxicities than adult kangaroo rats. Species-specific soil-screening thresholds were derived for arsenic (137 mg/kg), cadmium (16 mg/kg), copper (1,461 mg/kg), lead (1,143 mg/kg), nickel (771 mg/kg), thallium (1.3 mg/kg), uranium (1,513 mg/kg), and zinc (731 mg/kg) using toxicity reference values that incorporate expected chronic field exposures. Inorganic contaminants in soils within and near the mine areas generally posed minimal risk to kangaroo rats. Most exceedances of soil thresholds were for arsenic and thallium and were associated with weathered mine wastes.

  20. Field screening procedures for determining the presence of volatile organic compounds in soil

    International Nuclear Information System (INIS)

    Crockett, A.B.; DeHaan, M.S.

    1991-01-01

    Many field screening procedures have been used to detect the presence of volatile organic compounds (VOC) in soils but almost none have been documented and verified. Users of these procedures have not really known whether their objectives in screening were met. A reliable VOC screening procedure could significantly reduce the number of samples currently being submitted to laboratories, thereby reducing costs and improving site characterization. The Environmental Protection Agency's Environmental Monitoring Systems Laboratory in Las Vegas (EMSL-LV) has therefore sponsored a research effort to evaluate and improve headspace methods for screening soils for VOC in the field. The research involved comparing several extraction procedures using soils from actual waste sites, and determining the agitation and mixing necessary to achieve equilibrium. Headspace was analyzed using a relatively simple portable gas chromatograph with a short column. The results were variable and show that several procedures should be attempted and the results evaluated before selecting a screening procedure. 10 refs., 6 tabs

  1. Soil-based screening for iron toxicity tolerance in rice using pots

    Directory of Open Access Journals (Sweden)

    Mouritala Sikirou

    2016-10-01

    Full Text Available The objective of this study was to assess the reliability of pot-based screening method for iron (Fe toxicity tolerance in rice using soils from hot spots. Five lowland rice varieties with known reaction to Fe toxicity were grown in pots in a screen house for three seasons. Fe-toxic soils from two hot spot fields – Edozighi, Nigeria and Niaouli, Benin were used and soil from Africa Rice Center (AfricaRice experimental farm, Cotonou, Benin was included as control. Leaf bronzing score (LBS was determined at different stages, and grain yield was determined at maturity. Heritability was estimated using data across the three seasons. High heritability was recorded for LBS and grain yield. Grain yield reduction in stress treatment relative to control varied from 15 to 56% depending on the variety and soil. Bao Thai, Suakoko 8, and WITA 4 had better performance under Fe toxicity in terms of LBS, yield and relative yield reduction, whereas Bouake 189 and IR64 had poorer performance. Grain yield and LBS were significantly correlated but negatively at 60 days after sowing (DAS. Overall, the results found in this experiment were consistent with previous field studies. Therefore, pot screening using soils from hot spots can be used by rice breeding programs to reliably assess Fe toxicity tolerance ex situ.

  2. Soil-plant transfer models for metals to improve soil screening value guidelines valid for São Paulo, Brazil.

    Science.gov (United States)

    Dos Santos-Araujo, Sabrina N; Swartjes, Frank A; Versluijs, Kees W; Moreno, Fabio Netto; Alleoni, Luís R F

    2017-11-07

    In Brazil, there is a lack of combined soil-plant data attempting to explain the influence of specific climate, soil conditions, and crop management on heavy metal uptake and accumulation by plants. As a consequence, soil-plant relationships to be used in risk assessments or for derivation of soil screening values are not available. Our objective in this study was to develop empirical soil-plant models for Cd, Cu, Pb, Ni, and Zn, in order to derive appropriate soil screening values representative of humid tropical regions such as the state of São Paulo (SP), Brazil. Soil and plant samples from 25 vegetable species in the production areas of SP were collected. The concentrations of metals found in these soil samples were relatively low. Therefore, data from temperate regions were included in our study. The soil-plant relations derived had a good performance for SP conditions for 8 out of 10 combinations of metal and vegetable species. The bioconcentration factor (BCF) values for Cd, Cu, Ni, Pb, and Zn in lettuce and for Cd, Cu, Pb, and Zn in carrot were determined under three exposure scenarios at pH 5 and 6. The application of soil-plant models and the BCFs proposed in this study can be an important tool to derive national soil quality criteria. However, this methodological approach includes data assessed under different climatic conditions and soil types and need to be carefully considered.

  3. Screening of anthropogenic compounds in polluted sediments and soils

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Leeuw, J.W. de; Leer, E.W.B. de; Schuyl, P.J.W.

    1986-01-01

    The use of flash evaporation and pyrolysis gas chromatography- mass spectrometry as a fast screening procedure for anthropogenic substances In environmental samples is demonstrated by the analysis of polluted soil and sediment samples. Polycyclic aromatic hydrocarbons, haloorganics,

  4. Use of ecotoxicological screening action levels in ecological risk assessment at Los Alamos National Laboratory

    International Nuclear Information System (INIS)

    Ferenbauah, R.; Ebinger, M.; Gallegos, A.; Hansen, W.; Myers, O.; Wenzel, W.

    1995-01-01

    Regulatory drivers found in several environmental statutes require that ecological risk assessment and Natural Resource Damage Assessment be performed to assess potential environmental impact from contaminated sites and from proposed remedial alternatives. At Los Alamos National Laboratory, the initial phase of the ecological risk assessment process required preliminary evaluation of contaminated sites to determine whether potential for ecological impact exists. The preliminary evaluations were made using Ecotoxicological Screening Action Levels (ESALS) calculated as a function of reference toxicity dose, body weight, food/water/air intake, and fraction of soil intake with food. Reference toxicity doses were derived from the Environmental Protection Agency Integrated Risk Information System (IRIS) and Health Effects Assessment Summary Tables (HEAST) toxicology databases. Other parameters required for ESAL calculations were derived from physiological, metabolic, and behavioral data available in the literature. The Los Alamos ESALs were derived for guilds of animals with similar behavioral patterns, which were identified from natural resource survey data collected at Los Alamos. Subsequent to development of Ecotoxicological Screening Action Levels, Hazard Quotients, which are ratios of soil concentrations to Ecotoxicological Screening Action Levels, were calculated for potential contaminants of concern. The Hazard Quotients were used to identify which potential contaminants of concern should be evaluated further for ecological impact. There is potential for ecological impact when the Hazard Quotient is equal to or greater than one

  5. Sensitivity of screening-level toxicity tests using soils from a former petroleum refinery

    International Nuclear Information System (INIS)

    Pauwels, S.; Bureau, J.; Roy, Y.; Allen, B.; Robidoux, P.Y.; Soucy, M.

    1995-01-01

    The authors tested five composite soil samples from a former refinery. The samples included a reference soil (Mineral Oil and Grease, MO and G < 40 ppm), thermally-treated soil, biotreated soil, and two untreated soils. They evaluated toxicity using the earthworm E. foetida, lettuce, cress, barley, Microtox, green algae, fathead minnow, and D. magna. The endpoints measured were lethality, seed germination, root elongation, growth, and bioluminescence. Toxicity, as measured by the number of positive responses, increased as follows: biotreated soil < untreated soil No. 1 < reference soil < thermally-treated soil and untreated soil No. 2. The biotreated soil generated only one positive response, whereas the thermally-treated soil and untreated soil No. 2 generated five positive responses. The most sensitive and discriminant terrestrial endpoint was lettuce root elongation which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was barley seed germination for which no toxicity was detected. The most sensitive and discriminant aquatic endpoint was green algae growth which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was D. magna for which no toxicity was detected. Overall, soil and aqueous extract toxicity was spotty and no consistent patterns emerged to differentiate the five soils. Biotreatment significantly reduced the effects of the contamination. Aqueous toxicity was measured in the reference soil, probably because of the presence of unknown dissolved compounds in the aqueous extract. Finally, clear differences in sensitivity existed among the test species

  6. Identification of Alternative Vapor Intrusion Pathways Using Controlled Pressure Testing, Soil Gas Monitoring, and Screening Model Calculations.

    Science.gov (United States)

    Guo, Yuanming; Holton, Chase; Luo, Hong; Dahlen, Paul; Gorder, Kyle; Dettenmaier, Erik; Johnson, Paul C

    2015-11-17

    Vapor intrusion (VI) pathway assessment and data interpretation have been guided by an historical conceptual model in which vapors originating from contaminated soil or groundwater diffuse upward through soil and are swept into a building by soil gas flow induced by building underpressurization. Recent studies reveal that alternative VI pathways involving neighborhood sewers, land drains, and other major underground piping can also be significant VI contributors, even to buildings beyond the delineated footprint of soil and groundwater contamination. This work illustrates how controlled-pressure-method testing (CPM), soil gas sampling, and screening-level emissions calculations can be used to identify significant alternative VI pathways that might go undetected by conventional sampling under natural conditions at some sites. The combined utility of these tools is shown through data collected at a long-term study house, where a significant alternative VI pathway was discovered and altered so that it could be manipulated to be on or off. Data collected during periods of natural and CPM conditions show that the alternative pathway was significant, but its presence was not identifiable under natural conditions; it was identified under CPM conditions when measured emission rates were 2 orders of magnitude greater than screening-model estimates and subfoundation vertical soil gas profiles changed and were no longer consistent with the conventional VI conceptual model.

  7. Screening of a new cadmium hyperaccumulator, Galinsoga parviflora, from winter farmland weeds using the artificially high soil cadmium concentration method.

    Science.gov (United States)

    Lin, Lijin; Jin, Qian; Liu, Yingjie; Ning, Bo; Liao, Ming'an; Luo, Li

    2014-11-01

    A new method, the artificially high soil cadmium (Cd) concentration method, was used to screen for Cd hyperaccumulators among winter farmland weeds. Galinsoga parviflora was the most promising remedial plant among 5 Cd accumulators or hyperaccumulators. In Cd concentration gradient experiments, as soil Cd concentration increased, root and shoot biomass decreased, and their Cd contents increased. In additional concentration gradient experiments, superoxide dismutase and peroxidase activities increased with soil Cd concentrations up to 75 mg kg(-1) , while expression of their isoenzymes strengthened. Catalase (CAT) activity declined and CAT isoenzyme expression weakened at soil Cd concentrations less than 50 mg kg(-1) . The maxima of Cd contents in shoots and roots were 137.63 mg kg(-1) and 105.70 mg kg(-1) , respectively, at 100 mg kg(-1) Cd in soil. The root and shoot bioconcentration factors exceeded 1.0, as did the translocation factor. In a field experiment, total extraction of Cd by shoots was 1.35 mg m(-2) to 1.43 mg m(-2) at soil Cd levels of 2.04 mg kg(-1) to 2.89 mg kg(-1) . Therefore, the artificially high soil Cd concentration method was effective for screening Cd hyperaccumulators. Galinsoga parviflora is a Cd hyperaccumulator that could be used to efficiently remediate Cd-contaminated farmland soil. © 2014 SETAC.

  8. Radionuclide Concentration in Soils and Vegetation at Low-Level Radioactive Waste Disposal Area G during 2005

    International Nuclear Information System (INIS)

    Fresquez, P.R.; McNaughton, M.W.; Winch, M.J.

    2005-01-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected from up to nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). Soil and plant samples were also collected from the proposed expansion area west of Area G for the purpose of gaining preoperational baseline data. Soil and plant samples were analyzed for radionuclides that have shown a history of detection in past years; these included 3 H, 238 Pu, 239,240 Pu, 241 Am, 234 U, 235 U, and 238 U for soils and 3 H, 238 Pu, and 239,240 Pu for plants. As in previous years, the highest levels of 3 H in soils and vegetation were detected at the south portion of Area G near the 3 H shafts; whereas, the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions near the pads for transuranic waste. All concentrations of radionuclides in soils and vegetation, however, were still very low (pCi range) and far below LANL screening levels and regulatory standards

  9. Sugarcane trash levels in soil affects the fungi but not bacteria in a short-term field experiment

    Directory of Open Access Journals (Sweden)

    C.T.C.C Rachid

    2016-06-01

    Full Text Available Abstract The sugarcane in Brazil is passing through a management transition that is leading to the abolition of pre-harvest burning. Without burning, large amounts of sugarcane trash is generated, and there is a discussion regarding the utilization of this biomass in the industry versus keeping it in the field to improve soil quality. To study the effects of the trash removal on soil quality, we established an experimental sugarcane plantation with different levels of trash over the soil (0%, 50% and 100% of the original trash deposition and analyzed the structure of the bacterial and fungal community as the bioindicators of impacts. The soil DNA was extracted, and the microbial community was screened by denaturing gradient gel electrophoresis in two different seasons. Our results suggest that there are no effects from the different levels of trash on the soil chemistry and soil bacterial community. However, the fungal community was significantly impacted, and after twelve months, the community presented different structures among the treatments.

  10. Comparison of tree coring and soil gas sampling for screening of contaminated sites

    DEFF Research Database (Denmark)

    Nielsen, Mette Algreen; Stalder, Marcel; Riis, Charlotte

    and then identify high risk areas. The uptake of BTEX into trees varies to a greater extent with the tree species and the site conditions than chlorinated solvents, which lead to greater uncertainty. Both methods have their advantages and disadvantages. Hence, the methods supplement each other. Based on results......Site characterization is often time consuming and a financial burden for the site owners, which raises a demand for rapid and inexpensive (pre)screening methods. Phytoscreening by tree coring has shown to be a useful tool to detect subsurface contamination, especially of chlorinated solvents...... suitable as initial screening methods for site characterization. The aim of this study is to compare tree coring and soil gas sampling to evaluate to which extent tree coring may supplement or substitute soil gas sampling as a site contaminant screening tool. And where both methods are feasible, evaluate...

  11. Correlations of soil-gas and indoor radon with geology in glacially derived soils of the northern Great Plains

    International Nuclear Information System (INIS)

    Schumann, R.R.; Owen, D.E.; Peake, R.T.; Schmidt, K.M.

    1990-01-01

    This paper reports that a higher percentage of homes in parts of the northern Great Plains underlain by soils derived from continental glacial deposits have elevated indoor radon levels (greater than 4 pCi/L) than any other area in the country. Soil-gas radon concentrations, surface radioactivity, indoor radon levels, and soil characteristics were studied in areas underlain by glacially-derived soils in North Dakota and Minnesota to examine the factors responsible for these elevated levels. Clay-rich till soils in North Dakota have generally higher soil-gas radon levels, and correspondingly higher indoor radon levels, than the sandy till soils common to west-central Minnesota. Although the proportions of homes with indoor radon levels greater than 4 pCi/L are similar in both areas, relatively few homes underlain by sandy tills have screening indoor radon levels greater than 20 pCi/L, whereas a relatively large proportion of homes underlain by clayey tills have screening indoor radon levels exceeding 20 pCi/L. The higher radon levels in North Dakota are likely due to enhanced emanation from the smaller grains and to relatively higher soil radium concentrations in the clay-rich soils, whereas the generally higher permeability of the sandy till soils in Minnesota allows soil gas to be drawn into structures from a larger source volume, increasing indoor radon levels in these areas

  12. Screening plant species native to Taiwan for remediation of 137Cs-contaminated soil and the effects of K addition and soil amendment on the transfer of 137Cs from soil to plants

    International Nuclear Information System (INIS)

    Chou, F.-I.; Chung, H.-P.; Teng, S.-P.; Sheu, S.-T.

    2005-01-01

    This study aims to screen plant species native to Taiwan that could be used to eliminate 137 Cs radionuclides from contaminated soil. Four kinds of vegetables and two kinds of plants known as green manures were used for the screening. The test plants were cultivated in 137 Cs-contaminated soil and amended soil which is a mixture of the contaminated one with a horticultural soil. The plant with the highest 137 Cs transfer factor was used for further examination on the effects of K addition on the transfer of 137 Cs from the soils to the plant. Experimental results revealed that plants cultivated in the amended soil produced more biomass than those in the contaminated soil. Rape exhibited the highest production of aboveground parts, and had the highest 137 Cs transfer factor among all the tested plants. The transfer of 137 Cs to the rape grown in the soil to which 100 ppm KCl commonly used in local fertilizers had been added, were restrained. Results of this study indicated that rape, a popular green manure in Taiwan, could remedy 137 Cs-contaminated soil

  13. Radionuclide Concentration in Soils and Vegetation at Low-Level Radioactive Waste Disposal Area G during 2005

    Energy Technology Data Exchange (ETDEWEB)

    P.R. Fresquez; M.W. McNaughton; M.J. Winch

    2005-10-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected from up to nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). Soil and plant samples were also collected from the proposed expansion area west of Area G for the purpose of gaining preoperational baseline data. Soil and plant samples were analyzed for radionuclides that have shown a history of detection in past years; these included {sup 3}H, {sup 238}Pu, {sup 239,240}Pu, {sup 241}Am, {sup 234}U, {sup 235}U, and {sup 238}U for soils and {sup 3}H, {sup 238}Pu, and {sup 239,240}Pu for plants. As in previous years, the highest levels of {sup 3}H in soils and vegetation were detected at the south portion of Area G near the {sup 3}H shafts; whereas, the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions near the pads for transuranic waste. All concentrations of radionuclides in soils and vegetation, however, were still very low (pCi range) and far below LANL screening levels and regulatory standards.

  14. A comparison of hydroponic and soil-based screening methods to identify salt tolerance in the field in barley

    Science.gov (United States)

    Tavakkoli, Ehsan; Fatehi, Foad; Rengasamy, Pichu; McDonald, Glenn K.

    2012-01-01

    Success in breeding crops for yield and other quantitative traits depends on the use of methods to evaluate genotypes accurately under field conditions. Although many screening criteria have been suggested to distinguish between genotypes for their salt tolerance under controlled environmental conditions, there is a need to test these criteria in the field. In this study, the salt tolerance, ion concentrations, and accumulation of compatible solutes of genotypes of barley with a range of putative salt tolerance were investigated using three growing conditions (hydroponics, soil in pots, and natural saline field). Initially, 60 genotypes of barley were screened for their salt tolerance and uptake of Na+, Cl–, and K+ at 150 mM NaCl and, based on this, a subset of 15 genotypes was selected for testing in pots and in the field. Expression of salt tolerance in saline solution culture was not a reliable indicator of the differences in salt tolerance between barley plants that were evident in saline soil-based comparisons. Significant correlations were observed in the rankings of genotypes on the basis of their grain yield production at a moderately saline field site and their relative shoot growth in pots at ECe 7.2 [Spearman’s rank correlation (rs)=0.79] and ECe 15.3 (rs=0.82) and the crucial parameter of leaf Na+ (rs=0.72) and Cl– (rs=0.82) concentrations at ECe 7.2 dS m−1. This work has established screening procedures that correlated well with grain yield at sites with moderate levels of soil salinity. This study also showed that both salt exclusion and osmotic tolerance are involved in salt tolerance and that the relative importance of these traits may differ with the severity of the salt stress. In soil, ion exclusion tended to be more important at low to moderate levels of stress but osmotic stress became more important at higher stress levels. Salt exclusion coupled with a synthesis of organic solutes were shown to be important components of salt

  15. Biosurfactant Producing Microbes from Oil Contaminated Soil - Isolation, Screening and Characterization

    OpenAIRE

    , A Pandey; , D Nandi; , N Prasad; , S Arora

    2016-01-01

    Th1s paper bas1cally deals W1th 1solat10n, productıon and characterızatıon of biosurfactant producing microbes from oil contaminated soil sample. In this paper, we are comparing and discussing different methods to screen & characterize microbes from soil which can degrade oil due to their biosurfactant producing activity which helps in reduction of surface tension of oil. Oils used to check the biosurfactant activity of microbes, were engine oil and vegetable oil. Further isolation of...

  16. Isolation of xylose isomerases by sequence- and function-based screening from a soil metagenomic library

    Directory of Open Access Journals (Sweden)

    Parachin Nádia

    2011-05-01

    Full Text Available Abstract Background Xylose isomerase (XI catalyses the isomerisation of xylose to xylulose in bacteria and some fungi. Currently, only a limited number of XI genes have been functionally expressed in Saccharomyces cerevisiae, the microorganism of choice for lignocellulosic ethanol production. The objective of the present study was to search for novel XI genes in the vastly diverse microbial habitat present in soil. As the exploitation of microbial diversity is impaired by the ability to cultivate soil microorganisms under standard laboratory conditions, a metagenomic approach, consisting of total DNA extraction from a given environment followed by cloning of DNA into suitable vectors, was undertaken. Results A soil metagenomic library was constructed and two screening methods based on protein sequence similarity and enzyme activity were investigated to isolate novel XI encoding genes. These two screening approaches identified the xym1 and xym2 genes, respectively. Sequence and phylogenetic analyses revealed that the genes shared 67% similarity and belonged to different bacterial groups. When xym1 and xym2 were overexpressed in a xylA-deficient Escherichia coli strain, similar growth rates to those in which the Piromyces XI gene was expressed were obtained. However, expression in S. cerevisiae resulted in only one-fourth the growth rate of that obtained for the strain expressing the Piromyces XI gene. Conclusions For the first time, the screening of a soil metagenomic library in E. coli resulted in the successful isolation of two active XIs. However, the discrepancy between XI enzyme performance in E. coli and S. cerevisiae suggests that future screening for XI activity from soil should be pursued directly using yeast as a host.

  17. Sugarcane trash levels in soil affects the fungi but not bacteria in a short-term field experiment.

    Science.gov (United States)

    Rachid, C T C C; Pires, C A; Leite, D C A; Coutinho, H L C; Peixoto, R S; Rosado, A S; Salton, J; Zanatta, J A; Mercante, F M; Angelini, G A R; Balieiro, Fabiano de Carvalho

    2016-01-01

    The sugarcane in Brazil is passing through a management transition that is leading to the abolition of pre-harvest burning. Without burning, large amounts of sugarcane trash is generated, and there is a discussion regarding the utilization of this biomass in the industry versus keeping it in the field to improve soil quality. To study the effects of the trash removal on soil quality, we established an experimental sugarcane plantation with different levels of trash over the soil (0%, 50% and 100% of the original trash deposition) and analyzed the structure of the bacterial and fungal community as the bioindicators of impacts. The soil DNA was extracted, and the microbial community was screened by denaturing gradient gel electrophoresis in two different seasons. Our results suggest that there are no effects from the different levels of trash on the soil chemistry and soil bacterial community. However, the fungal community was significantly impacted, and after twelve months, the community presented different structures among the treatments. Copyright © 2016. Published by Elsevier Editora Ltda.

  18. Cost comparison of laboratory methods and four field screening technologies for uranium-contaminated soil

    International Nuclear Information System (INIS)

    Douthat, D.M.; Armstrong, A.Q.

    1994-01-01

    To address the problem of characterizing uranium-contaminated surface soil at federal facilities, the Department of Energy has the development of four uranium field screening technologies, under the direction of the Uranium-in-Soils Integrated Demonstration (USID) Program. These four technologies include: a long-range alpha detector a beta scintillation detector, an in situ gamma detector, and a mobile laser ablation-inductively coupled plasma/atomic emission spectrometry (LA-ICP/AES) laboratory. As part of the performance assessment for these field screening technologies, cost estimates for the development and operation of each technology were created. A cost study was conducted to compare three of the USID field screening technologies to the use of traditional field surveying equipment to adequately characterize surface soils of a one-acre site. The results indicate that the use of traditional equipment costs more than the in situ gamma detector, but less than the beta scintillation detector and LRAD. The use of traditional field surveying equipment results in cost savings of 4% and 34% over the use of the beta scintillation and LRAD technologies, respectively. A study of single-point surface soil sampling and laboratory analysis costs was also conducted. Operational costs of the mobile LA-ICP/AES laboratory were compared with operational costs of traditional sampling and analysis, which consists of collecting soil samples and conducting analysis in a radiochemical laboratory. The cost study indicates that the use of the mobile LA-ICP/AES laboratory results in cost savings of 23% and 40% over traditional field sampling and laboratory analysis conducted by characterization groups at two DOE facilities

  19. Mercury baseline levels in Flemish soils (Belgium)

    International Nuclear Information System (INIS)

    Tack, Filip M.G.; Vanhaesebroeck, Thomas; Verloo, Marc G.; Van Rompaey, Kurt; Ranst, Eric van

    2005-01-01

    It is important to establish contaminant levels that are normally present in soils to provide baseline data for pollution studies. Mercury is a toxic element of concern. This study was aimed at assessing baseline mercury levels in soils in Flanders. In a previous study, mercury contents in soils in Oost-Vlaanderen were found to be significantly above levels reported elsewhere. For the current study, observations were extended over two more provinces, West-Vlaanderen and Antwerpen. Ranges of soil Hg contents were distinctly higher in the province Oost-Vlaanderen (interquartile range from 0.09 to 0.43 mg/kg) than in the other provinces (interquartile ranges from 0.7 to 0.13 and 0.7 to 0.15 mg/kg for West-Vlaanderen and Antwerpen, respectively). The standard threshold method was applied to separate soils containing baseline levels of Hg from the data. Baseline concentrations for Hg were characterised by a median of 0.10 mg Hg/kg dry soil, an interquartile range from 0.07 to 0.14 mg/kg and a 90% percentile value of 0.30 mg/kg. The influence of soil properties such as clay and organic carbon contents, and pH on baseline Hg concentrations was not important. Maps of the spatial distribution of Hg levels showed that the province Oost-Vlaanderen exhibited zones with systematically higher Hg soil contents. This may be related to the former presence of many small-scale industries employing mercury in that region. - Increased mercury levels may reflect human activity

  20. Reconnaissance soil geochemistry at the Riverton Uranium Mill Tailings Remedial Action Site, Fremont County, Wyoming

    Science.gov (United States)

    Smith, David B.; Sweat, Michael J.

    2012-01-01

    Soil samples were collected and chemically analyzed from the Riverton Uranium Mill Tailings Remedial Action Site, which lies within the Wind River Indian Reservation in Fremont County, Wyoming. Nineteen soil samples from a depth of 0 to 5 centimeters were collected in August 2011 from the site. The samples were sieved to less than 2 millimeters and analyzed for 44 major and trace elements following a near-total multi-acid extraction. Soil pH was also determined. The geochemical data were compared to a background dataset consisting of 160 soil samples previously collected from the same depth throughout the State of Wyoming as part of another ongoing study by the U.S. Geological Survey. Risk from potentially toxic elements in soil from the site to biologic receptors and humans was estimated by comparing the concentration of these elements with soil screening values established by the U.S. Environmental Protection Agency. All 19 samples exceeded the carcinogenic human health screening level for arsenic in residential soils of 0.39 milligrams per kilogram (mg/kg), which represents a one-in-one-million cancer risk (median arsenic concentration in the study area is 2.7 mg/kg). All 19 samples also exceeded the lead and vanadium screening levels for birds. Eighteen of the 19 samples exceeded the manganese screening level for plants, 13 of the 19 samples exceeded the antimony screening level for mammals, and 10 of 19 samples exceeded the zinc screening level for birds. However, these exceedances are also found in soils at most locations in the Wyoming Statewide soil database, and elevated concentrations alone are not necessarily cause for alarm. Uranium and thorium, two other elements of environmental concern, are elevated in soils at the site as compared to the Wyoming dataset, but no human or ecological soil screening levels have been established for these elements.

  1. Radionuclide Concentrations in soils an Vegetation at Low-Level Radioactive Waste Disposal Area G During 2004

    International Nuclear Information System (INIS)

    Fresquez, P.R.; Lopez, E.A.

    2004-01-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected at nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). These samples were analyzed for 3 H, 238 Pu, 239,240 Pu, 90 Sr, 241 Am, 137 Cs, 234 U, 235 U, and 238 U. Soil samples collected at Area G contained detectable concentrations of 3H (27%), 239,240 Pu (60%), 238 Pu (40%), and 241 Am (47%) above regional statistical reference levels (RSRLs). In contrast, the levels of 137 Cs, 90 Sr, and U in all of the soil samples at Area G were either nondetectable or within RSRLs. The highest levels of 3 H in soils were detected in the southwestern portion of Area G near the 3 H shafts, whereas the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions. All concentrations of 3 H and Pu in soils, however, were far below LANL screening action levels. As for vegetation, most radionuclides in/on plants were either nondetectable or within RSRLs. The exceptions were 3 H in overstory and some understory vegetation, particularly in the southwestern portion of Area G, which correlated very well with the soils data in that area. Also, there was some foliar contamination from 241 Am and Pu isotopes in/on a few plant samples--the highest concentrations occurring in the northern section of Area G

  2. Terrestrial Eco-Toxicological Tests as Screening Tool to Assess Soil Contamination in Krompachy Area

    Science.gov (United States)

    Ol'ga, Šestinová; Findoráková, Lenka; Hančuľák, Jozef; Fedorová, Erika; Tomislav, Špaldon

    2016-10-01

    In this study, we present screening tool of heavy metal inputs to agricultural and permanent grass vegetation of the soils in Krompachy. This study is devoted to Ecotoxicity tests, Terrestrial Plant Test (modification of OECD 208, Phytotoxkit microbiotest on Sinapis Alba) and chronic tests of Earthworm (Dendrobaena veneta, modification of OECD Guidelines for the testing of chemicals 317, Bioaccumulation in Terrestrial Oligochaetes) as practical and sensitive screening method for assessing the effects of heavy metals in Krompachy soils. The total Cu, Zn, As, Pb and Hg concentrations and eco-toxicological tests of soils from the Krompachy area were determined of 4 sampling sites in 2015. An influence of the sampling sites distance from the copper smeltery on the absolutely concentrations of metals were recorded for copper, lead, zinc, arsenic and mercury. The highest concentrations of these metals were detected on the sampling sites up to 3 km from the copper smeltery. The samples of soil were used to assess of phytotoxic effect. Total mortality was established at earthworms using chronic toxicity test after 7 exposure days. The results of our study confirmed that no mortality was observed in any of the study soils. Based on the phytotoxicity testing, phytotoxic effects of the metals contaminated soils from the samples 3KR (7-9) S.alba seeds was observed.

  3. Characterization of Soil Organic Matter in Peat Soil with Different Humification Levels using FTIR

    Science.gov (United States)

    Teong, I. T.; Felix, N. L. L.; Mohd, S.; Sulaeman, A.

    2016-07-01

    Peat soil is defined as an accumulation of the debris and vegetative under the water logging condition. Soil organic matter of peat soil was affected by the environmental, weather, types of vegetative. Peat soil was normally classified based on its level of humification. Humification can be defined as the transformation of numerous group of substances (proteins, carbohydrates, lipids, etc.) and individual molecules present in living organic matter into group of substances with similar properties (humic substances). During the peat transformation process, content of soil organic matter also will change. Hence, that is important to determine out the types of the organic compound. FTIR (Fourier Transform Infrared) is a machine which is used to differential soil organic matter by using infrared. Infrared is a types of low energy which can determine the organic minerals. Hence, FTIR can be suitable as an indicator on its level of humification. The main objective of this study is to identify an optimized method to characterization of the soil organic content in different level of humification. The case study areas which had been chosen for this study are Parit Sulong, Batu Pahat and UCTS, Sibu. Peat soil samples were taken by every 0.5 m depth until it reached the clay layer. However, the soil organic matter in different humification levels is not significant. FTIR is an indicator which is used to determine the types of soil, but it is unable to differentiate the soil organic matter in peat soil FTIR can determine different types of the soil based on different wave length. Generally, soil organic matter was found that it is not significant to the level of humification.

  4. The critical soil P levels for crop yield, soil fertility and environmental safety in different soil types

    NARCIS (Netherlands)

    Bai, Z.H.; Li, H.G.; Yang, X.Y.; Zhou, B.K.; Shi, X.J.; Wang, B.R.; Li, D.C.; Shen, J.B.; Chen, Q.; Qin, W.; Oenema, O.; Zhang, F.S.

    2013-01-01

    Sufficient soil phosphorus (P) is important for achieving optimal crop production, but excessive soil P levels may create a risk of P losses and associated eutrophication of surface waters. The aim of this study was to determine critical soil P levels for achieving optimal crop yields and minimal P

  5. Impacts of land leveling on lowland soil physical properties

    Directory of Open Access Journals (Sweden)

    José Maria Barbat Parfitt

    2014-02-01

    Full Text Available The practice of land leveling alters the soil surface to create a uniform slope to improve land conditions for the application of all agricultural practices. The aims of this study were to evaluate the impacts of land leveling through the magnitudes, variances and spatial distributions of selected soil physical properties of a lowland area in the State of Rio Grande do Sul, Brazil; the relationships between the magnitude of cuts and/or fills and soil physical properties after the leveling process; and evaluation of the effect of leveling on the spatial distribution of the top of the B horizon in relation to the soil surface. In the 0-0.20 m layer, a 100-point geo-referenced grid covering two taxonomic soil classes was used in assessment of the following soil properties: soil particle density (Pd and bulk density (Bd; total porosity (Tp, macroporosity (Macro and microporosity (Micro; available water capacity (AWC; sand, silt, clay, and dispersed clay in water (Disp clay contents; electrical conductivity (EC; and weighted average diameter of aggregates (WAD. Soil depth to the top of the B horizon was also measured before leveling. The overall effect of leveling on selected soil physical properties was evaluated by paired "t" tests. The effect on the variability of each property was evaluated through the homogeneity of variance test. The thematic maps constructed by kriging or by the inverse of the square of the distances were visually analyzed to evaluate the effect of leveling on the spatial distribution of the properties and of the top of the B horizon in relation to the soil surface. Linear regression models were fitted with the aim of evaluating the relationship between soil properties and the magnitude of cuts and fills. Leveling altered the mean value of several soil properties and the agronomic effect was negative. The mean values of Bd and Disp clay increased and Tp, Macro and Micro, WAD, AWC and EC decreased. Spatial distributions of all

  6. Radionuclide Concentrations in soils an Vegetation at Low-Level Radioactive Waste Disposal Area G During 2004

    Energy Technology Data Exchange (ETDEWEB)

    P.R. Fresquez; E.A. Lopez

    2004-11-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected at nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). These samples were analyzed for {sup 3}H, {sup 238}Pu, {sup 239,240}Pu, {sup 90}Sr, {sup 241}Am, {sup 137}Cs, {sup 234}U, {sup 235}U, and {sup 238}U. Soil samples collected at Area G contained detectable concentrations of 3H (27%), {sup 239,240}Pu (60%), {sup 238}Pu (40%), and {sup 241}Am (47%) above regional statistical reference levels (RSRLs). In contrast, the levels of {sup 137}Cs, {sup 90}Sr, and U in all of the soil samples at Area G were either nondetectable or within RSRLs. The highest levels of {sup 3}H in soils were detected in the southwestern portion of Area G near the {sup 3}H shafts, whereas the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions. All concentrations of {sup 3}H and Pu in soils, however, were far below LANL screening action levels. As for vegetation, most radionuclides in/on plants were either nondetectable or within RSRLs. The exceptions were {sup 3}H in overstory and some understory vegetation, particularly in the southwestern portion of Area G, which correlated very well with the soils data in that area. Also, there was some foliar contamination from {sup 241}Am and Pu isotopes in/on a few plant samples--the highest concentrations occurring in the northern section of Area G.

  7. Decontamination by replacing soil and soil cover with deep-level soil in flower beds and vacant places in Northern Fukushima Prefecture

    International Nuclear Information System (INIS)

    Sugiura, Hiroyuki; Kawano, Keisuke; Kayama, Yukihiko; Koube, Nobuyuki

    2012-01-01

    Radioactivity decontamination by replacing soil and soil cover with deep-level soil and soil cover in flower beds and a vacant place in Northern Fukushima Prefecture were studied, which experienced radioactive contamination due to the accident at the TEPCO's Fukushima Daiichi Nuclear Power Plant. Radioactivity counting rate 1 cm above the soil surface after replacing surface soil with uncontaminated deep-level soil decreased to 13.7% of the control in gardens. The concentration of radioactive cesium in the cover soil increased after 132 days; however, it decreased in the old surface soil under the cover soil in flower beds. A 10 cm deep-level soil cover placed by heavy machinery decreased the radiation dose rate to 70.8% of the control and radioactivity counting rate to 24.6% in the vacant place. Replacing the radioactively contaminated surface soil and soil cover with a deep-level soil was a reasonable decontamination method for the garden and vacant place because it is quick, cost effective and labour efficient. (author)

  8. Screening and Characterization of Potentially Suppressive Soils against Gaeumannomyces graminis under Extensive Wheat Cropping by Chilean Indigenous Communities.

    Science.gov (United States)

    Durán, Paola; Jorquera, Milko; Viscardi, Sharon; Carrion, Victor J; Mora, María de la Luz; Pozo, María J

    2017-01-01

    Wheat production around the world is severely compromised by the occurrence of "take-all" disease, which is caused by the soil-borne pathogen Gaeumannomyces graminis var. tritici (Ggt). In this context, suppressive soils are those environments in which plants comparatively suffer less soil-borne pathogen diseases than expected, owing to native soil microorganism activities. In southern Chile, where 85% of the national cereal production takes place, several studies have suggested the existence of suppressive soils under extensive wheat cropping. Thus, this study aimed to screen Ggt-suppressive soil occurrence in 16 locations managed by indigenous "Mapuche" communities, using extensive wheat cropping for more than 10 years. Ggt growth inhibition in vitro screenings allowed the identification of nine putative suppressive soils. Six of these soils, including Andisols and Ultisols, were confirmed to be suppressive, since they reduced take-all disease in wheat plants growing under greenhouse conditions. Suppressiveness was lost upon soil sterilization, and recovered by adding 1% of the natural soil, hence confirming that suppressiveness was closely associated to the soil microbiome community composition. Our results demonstrate that long-term extensive wheat cropping, established by small Mapuche communities, can generate suppressive soils that can be used as effective microorganism sources for take-all disease biocontrol. Accordingly, suppressive soil identification and characterization are key steps for the development of environmentally-friendly and efficient biotechnological applications for soil-borne disease control.

  9. Screening and Characterization of Potentially Suppressive Soils against Gaeumannomyces graminis under Extensive Wheat Cropping by Chilean Indigenous Communities

    Directory of Open Access Journals (Sweden)

    Paola Durán

    2017-08-01

    Full Text Available Wheat production around the world is severely compromised by the occurrence of “take-all” disease, which is caused by the soil-borne pathogen Gaeumannomyces graminis var. tritici (Ggt. In this context, suppressive soils are those environments in which plants comparatively suffer less soil-borne pathogen diseases than expected, owing to native soil microorganism activities. In southern Chile, where 85% of the national cereal production takes place, several studies have suggested the existence of suppressive soils under extensive wheat cropping. Thus, this study aimed to screen Ggt-suppressive soil occurrence in 16 locations managed by indigenous “Mapuche” communities, using extensive wheat cropping for more than 10 years. Ggt growth inhibition in vitro screenings allowed the identification of nine putative suppressive soils. Six of these soils, including Andisols and Ultisols, were confirmed to be suppressive, since they reduced take-all disease in wheat plants growing under greenhouse conditions. Suppressiveness was lost upon soil sterilization, and recovered by adding 1% of the natural soil, hence confirming that suppressiveness was closely associated to the soil microbiome community composition. Our results demonstrate that long-term extensive wheat cropping, established by small Mapuche communities, can generate suppressive soils that can be used as effective microorganism sources for take-all disease biocontrol. Accordingly, suppressive soil identification and characterization are key steps for the development of environmentally-friendly and efficient biotechnological applications for soil-borne disease control.

  10. Esterase screening using whole cells of Brazilian soil microorganisms

    Energy Technology Data Exchange (ETDEWEB)

    Mantovani, Simone M.; Oliveira, Luciana G. de; Marsaioli, Anita J., E-mail: anita@iqm.unicamp.b [Universidade Estadual de Campinas (IQ/UNICAMP), SP (Brazil). Inst. de Quimica

    2010-07-01

    A miniaturized enzymatic assay using fluorescent probes to reveal esterase producing microorganisms was optimized and applied to screen 64 soil bacterial strains. The best results were validated using traditional non-fluorogenic assays with acetyl and propanoyl phenylethanol to confirm the miniaturized results. The most active microorganisms belong to the genus Bacillus showing esterase activity and good enantiomeric ratios for the resolution of phenylethanol derivatives (E > 30). Part of the microorganisms are kept in our laboratory in glycerol or freezedried and the best microorganisms will be deposited in the CBMAI/CPQBA/UNICAMP culture collection. (author)

  11. A review of metal (Pb and Zn) sensitive and pH tolerant bioassay organisms for risk screening of metal-contaminated acidic soils

    International Nuclear Information System (INIS)

    Chapman, E.Emily V.; Dave, Göran; Murimboh, John D.

    2013-01-01

    To improve risk estimates at the screening stage of Ecological Risk Assessment (ERA), short duration bioassays tailored to undisturbed soil cores from the contaminated site could be useful. However, existing standardized bioassays use disturbed soil samples and often pH sensitive organisms. This is a problem as naturally acidic soils are widespread. Changing soil properties to suit the test organism may change metal bioavailability, leading to erroneous risk estimates. For bioassays in undisturbed soil cores to be effective, species able to withstand natural soil properties must be identified. This review presents a critical examination of bioassay species' tolerance of acidic soils and sensitivity to metal contaminants such as Pb and Zn. Promising organisms include; Dendrobaena octaedra, Folsomia candida, Caenorhabditis elegans, Oppia nitens, Brassica rapa, Trifolium pratense, Allium cepa, Quercus rubra and Acer rubrum. The MetSTICK test and the Bait lamina test were also identified as suitable microorganism tests. -- Highlights: •Risk screening of metal contaminated soils should consider metal bioavailability. •Metal bioavailability is dependent on soil properties such as pH. •Many standardized bioassay organisms are sensitive to acidic soils. •This review identifies acid tolerant and metal sensitive bioassays and species. •The identified tests can improve risk screening of acidic metal contaminated soil. -- This review identifies bioassay species able to withstand naturally acidic soils while being sensitive to metal contaminants

  12. SOIL ORGANIC CARBON LEVELS IN SOILS OF CONTRASTING LAND USES IN SOUTHEASTERN NIGERIA

    Directory of Open Access Journals (Sweden)

    Chinyere Blessing Okebalama

    2017-12-01

    Full Text Available Land use change affects soil organic carbon (SOC storage in tropical soils, but information on the influence of land use change on segmental topsoil organic carbon stock is lacking. The study investigated SOC levels in Awgu (L, Okigwe (CL, Nsukka I (SL, and Nsukka II (SCL locations in southeastern Nigeria. Land uses considered in each location were the cultivated (manually-tilled and the adjacent uncultivated (4-5 year bush-fallow soils from which samples at 0-10, 10-20, and 20-30 cm topsoil depth were assessed. The SOC level decreased with topsoil depth in both land uses. Overall, the SOC level at 0-30 cm was between 285.44 and 805.05 Mg ha-1 amongst the soils.  The uncultivated sites stored more SOC than its adjacent cultivated counterpart at 0-10 and 10-20 cm depth, except in Nsukka II soils, which had significantly higher SOC levels in the cultivated than the uncultivated site. Nonetheless, at 20-30 cm depth, the SOC pool across the fallowed soils was statistically similar when parts of the same soil utilization type were tilled and cultivated. Therefore, while 4 to 5 years fallow may be a useful strategy for SOC stabilization within 20-30 cm topsoil depth in the geographical domain, segmental computation of topsoil organic carbon pool is critical.

  13. Screening-Level Ecological Risk Assessment Methods, Revision 3

    Energy Technology Data Exchange (ETDEWEB)

    Mirenda, Richard J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2012-08-16

    This document provides guidance for screening-level assessments of potential adverse impacts to ecological resources from release of environmental contaminants at the Los Alamos National Laboratory (LANL or the Laboratory). The methods presented are based on two objectives, namely: to provide a basis for reaching consensus with regulators, managers, and other interested parties on how to conduct screening-level ecological risk investigations at the Laboratory; and to provide guidance for ecological risk assessors under the Environmental Programs (EP) Directorate. This guidance promotes consistency, rigor, and defensibility in ecological screening investigations and in reporting those investigation results. The purpose of the screening assessment is to provide information to the risk managers so informed riskmanagement decisions can be made. This document provides examples of recommendations and possible risk-management strategies.

  14. Toxicological benchmarks for screening potential contaminants of concern for effects on soil and litter invertebrates and heterotrophic process

    International Nuclear Information System (INIS)

    Will, M.E.; Suter, G.W. II.

    1994-09-01

    One of the initial stages in ecological risk assessments for hazardous waste sites is the screening of contaminants to determine which of them are worthy of further consideration as open-quotes contaminants of potential concern.close quotes This process is termed open-quotes contaminant screening.close quotes It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to soil- and litter-dwelling invertebrates, including earthworms, other micro- and macroinvertebrates, or heterotrophic bacteria and fungi. This report presents a standard method for deriving benchmarks for this purpose, sets of data concerning effects of chemicals in soil on invertebrates and soil microbial processes, and benchmarks for chemicals potentially associated with United States Department of Energy sites. In addition, literature describing the experiments from which data were drawn for benchmark derivation. Chemicals that are found in soil at concentrations exceeding both the benchmarks and the background concentration for the soil type should be considered contaminants of potential concern

  15. Toxicological benchmarks for screening potential contaminants of concern for effects on soil and litter invertebrates and heterotrophic process

    Energy Technology Data Exchange (ETDEWEB)

    Will, M.E.; Suter, G.W. II

    1994-09-01

    One of the initial stages in ecological risk assessments for hazardous waste sites is the screening of contaminants to determine which of them are worthy of further consideration as {open_quotes}contaminants of potential concern.{close_quotes} This process is termed {open_quotes}contaminant screening.{close_quotes} It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to soil- and litter-dwelling invertebrates, including earthworms, other micro- and macroinvertebrates, or heterotrophic bacteria and fungi. This report presents a standard method for deriving benchmarks for this purpose, sets of data concerning effects of chemicals in soil on invertebrates and soil microbial processes, and benchmarks for chemicals potentially associated with United States Department of Energy sites. In addition, literature describing the experiments from which data were drawn for benchmark derivation. Chemicals that are found in soil at concentrations exceeding both the benchmarks and the background concentration for the soil type should be considered contaminants of potential concern.

  16. Do recommended doses of glyphosate-based herbicides affect soil invertebrates? Field and laboratory screening tests to risk assessment.

    Science.gov (United States)

    Niemeyer, Júlia Carina; de Santo, Fernanda Benedet; Guerra, Naiara; Ricardo Filho, Altair Maçaneiro; Pech, Tatiani Maria

    2018-05-01

    Despite glyphosate-based herbicides are widely used in agriculture, forestry and gardens, little is known about its effects on non-target organisms. The present work evaluated the ecotoxicity of four formulated products (Roundup ® Original, Trop ® , Zapp ® Qi 620 and Crucial ® ) on soil invertebrates. Screening ecotoxicity tests were carried out with soil and oat straw collected in a field experiment, besides laboratory-spiked soils. Screening tests included avoidance behaviour of earthworms (Eisenia andrei), collembolans (Folsomia candida) and isopods (Porcellio dilatatus) in single and multispecies tests; reproduction of collembolans (F. candida), and bait lamina in field. Non-avoidance behaviour was observed in standard tests (earthworms) in soil, neither in multispecies tests (earthworm + isopods) using oat straw, while for collembolans it occurred for the product Zapp ® Qi 620 even at the recommended dose. Reproduction of F. candida was not impaired even at high doses in laboratory-spiked soils. Feeding activity on bait lamina test was impaired in treatment corresponding to the red label product, Crucial ® . Results showed the relevance of bait lamina test on screening the impact of herbicides in the field. The findings highlight the importance of considering different formulations for the same active ingredient in risk assessment of pesticides. Copyright © 2018 Elsevier Ltd. All rights reserved.

  17. Assessing toxic levels of hydrocarbons on microbial degrader communities in vadose zone fill soils

    International Nuclear Information System (INIS)

    Schoenberg, T.H.; Long, S.C.

    1995-01-01

    Authentic fill samples were collected from the vadose zone at a highway travel plaza. The contamination at the site is a combination of gasoline, diesel, and waste oil resulting from leaking underground storage tanks. Microbial assessments including plate counts and specific-degrader enumerations were performed to establish the presence of degrader microbial communities, and thus bioremediation potential. Contaminant levels were estimated in samples by quantifying headspace VOCs in collection jars. Physical soil characteristics including soil grain size distribution and moisture content were measured to evaluate the potential ecological variables that would affect implementation of a bioremediation technology. Toxicity screening using the Microtox trademark acute toxicity assay was used to compare the level of toxicity present among samples. These analyses were used to assess the potential for using in situ bioventing remediation to clean-up the leaking underground storage tank spill study site. High contaminant levels appear to have exerted a toxic effect and resulted in smaller total microbial community sizes in highly contaminated areas (thousands of ppmv) of the site. Microtox trademark EC50 results generally corroborated with the trends of the enumeration experiments. Microbial characterization results indicate that in situ bioremediation would be possible at the study site. Soil heterogeneity appears to pose the greatest challenges to the design and implementation of bioremediation at this site

  18. Geographic variation and effect of area-level poverty rate on colorectal cancer screening

    Directory of Open Access Journals (Sweden)

    Schootman Mario

    2008-10-01

    Full Text Available Abstract Background With a secular trend of increasing colorectal cancer (CRC screening, concerns about disparities in CRC screening also have been rising. It is unclear if CRC screening varies geographically, if area-level poverty rate affects CRC screening, and if individual-level characteristics mediate the area-level effects on CRC screening. Methods Using 2006 Missouri Behavioral Risk Factor Surveillance System (BRFSS data, a multilevel study was conducted to examine geographic variation and the effect of area-level poverty rate on CRC screening use among persons age 50 or older. Individuals were nested within ZIP codes (ZIP5 areas, which in turn, were nested within aggregations of ZIP codes (ZIP3 areas. Six groups of individual-level covariates were considered as potential mediators. Results An estimated 51.8% of Missourians aged 50 or older adhered to CRC screening recommendations. Nearly 15% of the total variation in CRC screening lay between ZIP5 areas. Persons residing in ZIP5 areas with ≥ 10% of poverty rate had lower odds of CRC screening use than those residing in ZIP5 areas with Conclusion Large geographic variation of CRC screening exists in Missouri. Area-level poverty rate, independent of individual-level characteristics, is a significant predictor of CRC screening, but it only explains a small portion of the geographic heterogeneity of CRC screening. Individual-level factors we examined do not mediate the effect of the area-level poverty rate on CRC screening. Future studies should identify other area- and individual-level characteristics associated with CRC screening in Missouri.

  19. Statistical methods for determination of background levels for naturally occuring radionuclides in soil at a RCRA facility

    International Nuclear Information System (INIS)

    Guha, S.; Taylor, J.H.

    1996-01-01

    It is critical that summary statistics on background data, or background levels, be computed based on standardized and defensible statistical methods because background levels are frequently used in subsequent analyses and comparisons performed by separate analysts over time. The final background for naturally occurring radionuclide concentrations in soil at a RCRA facility, and the associated statistical methods used to estimate these concentrations, are presented. The primary objective is to describe, via a case study, the statistical methods used to estimate 95% upper tolerance limits (UTL) on radionuclide background soil data sets. A 95% UTL on background samples can be used as a screening level concentration in the absence of definitive soil cleanup criteria for naturally occurring radionuclides. The statistical methods are based exclusively on EPA guidance. This paper includes an introduction, a discussion of the analytical results for the radionuclides and a detailed description of the statistical analyses leading to the determination of 95% UTLs. Soil concentrations reported are based on validated data. Data sets are categorized as surficial soil; samples collected at depths from zero to one-half foot; and deep soil, samples collected from 3 to 5 feet. These data sets were tested for statistical outliers and underlying distributions were determined by using the chi-squared test for goodness-of-fit. UTLs for the data sets were then computed based on the percentage of non-detects and the appropriate best-fit distribution (lognormal, normal, or non-parametric). For data sets containing greater than approximately 50% nondetects, nonparametric UTLs were computed

  20. Soil radon levels across the Amer fault

    International Nuclear Information System (INIS)

    Font, Ll.; Baixeras, C.; Moreno, V.; Bach, J.

    2008-01-01

    Soil radon levels have been measured across the Amer fault, which is located near the volcanic region of La Garrotxa, Spain. Both passive (LR-115, time-integrating) and active (Clipperton II, time-resolved) detectors have been used in a survey in which 27 measurement points were selected in five lines perpendicular to the Amer fault in the village area of Amer. The averaged results show an influence of the distance to the fault on the mean soil radon values. The dynamic results show a very clear seasonal effect on the soil radon levels. The results obtained support the hypothesis that the fault is still active

  1. Geographic variation and effect of area-level poverty rate on colorectal cancer screening.

    Science.gov (United States)

    Lian, Min; Schootman, Mario; Yun, Shumei

    2008-10-16

    With a secular trend of increasing colorectal cancer (CRC) screening, concerns about disparities in CRC screening also have been rising. It is unclear if CRC screening varies geographically, if area-level poverty rate affects CRC screening, and if individual-level characteristics mediate the area-level effects on CRC screening. Using 2006 Missouri Behavioral Risk Factor Surveillance System (BRFSS) data, a multilevel study was conducted to examine geographic variation and the effect of area-level poverty rate on CRC screening use among persons age 50 or older. Individuals were nested within ZIP codes (ZIP5 areas), which in turn, were nested within aggregations of ZIP codes (ZIP3 areas). Six groups of individual-level covariates were considered as potential mediators. An estimated 51.8% of Missourians aged 50 or older adhered to CRC screening recommendations. Nearly 15% of the total variation in CRC screening lay between ZIP5 areas. Persons residing in ZIP5 areas with > or = 10% of poverty rate had lower odds of CRC screening use than those residing in ZIP5 areas with poverty rate (unadjusted odds ratio [OR], 0.69; 95% confidence interval [95% CI], 0.58-0.81; adjusted OR, 0.81; 95% CI, 0.67-0.98). Persons who resided in ZIP3 areas with > or = 20% poverty rate also had lower odds of following CRC screening guidelines than those residing in ZIP3 areas with poverty rate (unadjusted OR, 0.66; 95% CI, 0.52-0.83; adjusted OR, 0.64; 95% CI, 0.50-0.83). Obesity, history of depression/anxiety and access to care were associated with CRC screening, but did not mediate the effect of area-level poverty on CRC screening. Large geographic variation of CRC screening exists in Missouri. Area-level poverty rate, independent of individual-level characteristics, is a significant predictor of CRC screening, but it only explains a small portion of the geographic heterogeneity of CRC screening. Individual-level factors we examined do not mediate the effect of the area-level poverty rate on

  2. Characterization and screening of antimicrobial activity of Micromonospora strains from Thai soils

    Directory of Open Access Journals (Sweden)

    Songsumanus, A.

    2013-01-01

    Full Text Available Aims: Rare actinomycete strains were isolated from mountain soils and island soil collected in Thailand. They were screened for antimicrobial activity and characterized for their secondary metabolites.Methodology and results: The strains were isolated by the standard dilution technique using starch casein nitrate agar. They were identified and characterized based on the phenotypic, chemotaxonomic and genotypic characteristics. The chemotaxonomic characteristics of ten isolates coincided with those of the genus Micromonospora. On the basis of phylogenetic analysis using 16S rRNA gene sequences and DNA-DNA relatedness, they were divided into 6 Groups, ASC19-2-1 (Group A was identified as Micromonospora marina; AL8-8 and AL10-3 (Group B were M. aurantiaca; AL7-5 (Group C was M. chalcea; AL3-16 and AL9-20 (Group D were identified as M. chokoriensis; AL9-13 and AL9-22 (Group E were M. tulbaghiae; and AL1-15-2 and AL1-16B (Group F were M. chersina. On the primary screening, only the isolate AL7-5 (Group C could inhibit Kocuria rhizophila ATCC 9341. This isolate produced rakicidin when cultivated on A3M, A11M and A16 media and produced compound BU4664L only on A16 medium.Conclusion, significance and impact of study: The isolation and characterization of the rare actinomycetes from Thai soils will be useful for the taxonomic study and for the discovery of bioactive metabolites that are active against microorganisms.

  3. Are There Dangerous Levels of Lead in Local Soil?

    Science.gov (United States)

    Pita, I.

    2017-12-01

    The purpose of this experiment was to show that comparing random soil samples from areas in New Orleans; the Garden District will have the highest levels of lead in soil. My Independent variable was the soil samples collected from locations in the Garden District area of New Orleans, and other locations throughout New Orleans. The control was the soil samples collected from the local playground in the New Orleans area. My dependent variable was the lead soil test kit, using ppm (parts per million) of lead to show concentration. 400 ppm + in bare soil where children play is considered dangerous hazard levels. 1,000 + ppm in all other areas is considered dangerous hazard levels. The first step to my experiment, I collected soil samples from different locations throughout the Garden District area of New Orleans. The second step to my experiment, I conducted the lead soil testing in a controlled area at home in a well ventilated room, using all the necessary safety equipment needed, I began testing a 24 hour test period and a 48 hour test period. I then collected the data from both test. The results showed that soil samples from the Garden District area compared to the other sample locations had higher lead concentrations in the soil. This backed my hypothesis when comparing soil samples from areas in New Orleans, the Garden District will have the highest lead levels. In conclusion these experiments showed that with the soil samples collected, there were higher concentrations of lead in the soil from the Garden District area compared to the other areas where soil was collected. Reconstruction and renovations, from the devastation that Hurricane Katrina created, are evident of the lead in paint of older homes which now show the lead concentration in the soil. Lead is a lethal element if consumed or inhaled in high doses, which can damage key organs in our body, which can be deadly. Better awareness through social media, television, radio, doctors, studies, pamphlets

  4. Qualitative vs. quantitative data: Controls on the accuracy of PID field screening in petroleum contamination assessment applications

    International Nuclear Information System (INIS)

    Luessen, M.J.; Allex, M.K.; Holzel, F.R.

    1995-01-01

    The use of photoionization detectors (PIDs) for field screening of soils for volatile organic contaminants has become a standard industry practice. PID screening data is generally utilized as a qualitative basis for selection of samples for laboratory analysis to quantify concentrations of specific contaminants of concern. Both qualitative field screening data and quantitative laboratory analytical data were reviewed for more than 100 hydrogeologic assessment sites in Ohio to evaluate controls on the effectiveness of field screening data. Assessment data evaluated was limited to sites at which the suspected contaminant source was a gasoline underground storage tanks system. In each case, a 10.0 eV (or greater) PID calibrated for benzene was used to screen soils which were analyzed for benzene, toluene, ethylbenzene and xylene (BTEX) by SW 846 method 8020. Controls on field screening which were evaluated for each site included (1) soil classification, (2) soil moisture, (3) weather conditions, (4) background levels, (5) equipment quality, (6) screening methodology, and (7) laboratory QA/QC. Statistical data analysis predictably indicated a general overestimate of total BTEX levels based on field screening (gasoline is approximately 25 weight percent BTEX). However, data locally indicated cases of both significant (i.e., more than an order of magnitude difference) over- and under-estimation of actual BTEX concentrations (i.e., quantitative laboratory data) by field screening data

  5. Multilevel soil-vapor extraction test for heterogeneous soil

    International Nuclear Information System (INIS)

    Widdowson, M.A.; Haney, O.R.; Reeves, H.W.

    1997-01-01

    The design, performance, and analysis of a field method for quantifying contaminant mass-extraction rates and air-phase permeability at discrete vertical locations of the vadose zones are presented. The test configuration consists of a multiscreen extraction well and multilevel observation probes located in soil layers adjacent to the extraction well. For each level tested an inflatable packer system is used to pneumatically isolate a single screen in the extraction well, and a vacuum is applied to induce air flow through the screen. Test data include contaminant concentration and flow characteristics at the extraction well, and transient or steady-state pressure drawdown data at observation probes located at variable radii from the extraction well. The test method is applicable to the design of soil-vapor extraction (SVE) and bioventing remediation systems in a variety of geologic settings, particularly stratified soils. Application of the test method at a gasoline-polluted site located in the Piedmont physiographic region is described. Contaminant mass-extraction rates, expressed in terms of volatile hydrocarbons, varied from 0.16 to 14 kg/d

  6. Levels of concern for radioactive contaminations in soil according to soil protection standards

    International Nuclear Information System (INIS)

    Gellermann, R.; Barkowski, D.; Machtolf, M.

    2016-01-01

    In the paper the question is examined whether the established soil protection standards for carcinogenic substances are also applicable to the assessment of radioactive soil contamination. Referring to the methods applied in soil protection for evaluation of dose-effectrelations and estimations of carcinogenic risks as well as the calculation methods for test values in soil protection ''levels of concern'' for soil contamination by artificial radionuclides are derived. The values obtained are significantly larger than the values for unrestricted clearance of ground according to the German Radiation Protection Ordinance (StrlSchV). The thesis that soil is protected according to environmental standards provided that radiation protection requirements are met needs further checks but can be probably confirmed if the radiation protection requirements are clearly defined.

  7. Development of Tier 1 screening tool for soil and groundwater vulnerability assessment in Korea using classification algorithm in a neural network

    Science.gov (United States)

    Shin, K. H.; Kim, K. H.; Ki, S. J.; Lee, H. G.

    2017-12-01

    The vulnerability assessment tool at a Tier 1 level, although not often used for regulatory purposes, helps establish pollution prevention and management strategies in the areas of potential environmental concern such as soil and ground water. In this study, the Neural Network Pattern Recognition Tool embedded in MATLAB was used to allow the initial screening of soil and groundwater pollution based on data compiled across about 1000 previously contaminated sites in Korea. The input variables included a series of parameters which were tightly related to downward movement of water and contaminants through soil and ground water, whereas multiple classes were assigned to the sum of concentrations of major pollutants detected. Results showed that in accordance with diverse pollution indices for soil and ground water, pollution levels in both media were strongly modulated by site-specific characteristics such as intrinsic soil and other geologic properties, in addition to pollution sources and rainfall. However, classification accuracy was very sensitive to the number of classes defined as well as the types of the variables incorporated, requiring careful selection of input variables and output categories. Therefore, we believe that the proposed methodology is used not only to modify existing pollution indices so that they are more suitable for addressing local vulnerability, but also to develop a unique assessment tool to support decision making based on locally or nationally available data. This study was funded by a grant from the GAIA project(2016000560002), Korea Environmental Industry & Technology Institute, Republic of Korea.

  8. Ecological risk assessment of agricultural soils for the definition of soil screening values: A comparison between substance-based and matrix-based approaches.

    Science.gov (United States)

    Pivato, Alberto; Lavagnolo, Maria Cristina; Manachini, Barbara; Vanin, Stefano; Raga, Roberto; Beggio, Giovanni

    2017-04-01

    The Italian legislation on contaminated soils does not include the Ecological Risk Assessment (ERA) and this deficiency has important consequences for the sustainable management of agricultural soils. The present research compares the results of two ERA procedures applied to agriculture (i) one based on the "substance-based" approach and (ii) a second based on the "matrix-based" approach. In the former the soil screening values (SVs) for individual substances were derived according to institutional foreign guidelines. In the latter, the SVs characterizing the whole-matrix were derived originally by the authors by means of experimental activity. The results indicate that the "matrix-based" approach can be efficiently implemented in the Italian legislation for the ERA of agricultural soils. This method, if compared to the institutionalized "substance based" approach is (i) comparable in economic terms and in testing time, (ii) is site specific and assesses the real effect of the investigated soil on a battery of bioassays, (iii) accounts for phenomena that may radically modify the exposure of the organisms to the totality of contaminants and (iv) can be considered sufficiently conservative.

  9. EFFECT OF DIFFERENT LEVELS AGROECOLOGICAL LOADS ON BIOCHEMICAL CHARACTERISTICS OF SOIL

    OpenAIRE

    A. V. Shchur; D. V. Vinogradov; V. P. Valckho

    2016-01-01

    Aim. To study the effect of different levels of agri-environmental loads on the enzymatic activity of the soil.Methods. Isolation of soil fauna was conducted by thermogradient. Ecological characteristics of soil biota community was determined by ecological indices. The enzymatic activity of soil under different crops and at different levels of agri-environmental loads in our experiments was determined by methods proven in the laboratory soil enzymology Institute of Experimental Botany name V....

  10. Effect of Verticillium dahliae soil inoculum levels on spinach seed infection

    DEFF Research Database (Denmark)

    Sapkota, Rumakanta; Olesen, Merete Halkjær; Deleuran, Lise Christina

    2016-01-01

    Verticillium dahliae is a soilborne pathogen and a threat to spinach seed production. The aim of this study was to understand the relation between V. dahliae soil inoculum and infection in harvested seed. Quantitative polymerase chain reaction was used for quantification of the pathogen. Semifield...... experiments in which spinach was grown in soils with different inoculum levels enabled us to determine a threshold level for V. dahliae DNA of 0.003 ng/g of soil for seed infection to occur. Soils from production fields were sampled in 2013 and 2014 during and before planting, as well as the harvested seed....... Seed from plants grown in infested soils were infected with V. dahliae in samples from both the semifield and open-field experiments. Lower levels of pathogen were found in seed from spinach grown in soils with a scattered distribution of V. dahliae (one or two positive of three soil subsamples) than...

  11. Determining Childhood Blood Lead Level Screening Compliance Among Physicians.

    Science.gov (United States)

    Haboush-Deloye, Amanda; Marquez, Erika R; Gerstenberger, Shawn L

    2017-08-01

    Childhood Lead Poisoning Prevention Programs throughout the U.S. have addressed childhood lead poisoning by implementing primary and secondary prevention efforts. While many programs have helped increase screening rates, in some states children under the age of six still have not been tested for lead. This study aims to identify the barriers to childhood blood lead testing and develop a strategy to increase the number of children tested. Clark County physicians who work with children six and under were surveyed about blood lead level (BLL) testing practices, particularly, adherence to Centers for Disease Control and Prevention (CDC) guidelines, and parental compliance with orders to have their children tested to determine their blood lead levels. In addition, select in-person interviews were conducted with physicians who reported high parental compliance to identify best practices and barriers. Of the 77 physicians that provided data, 48% indicated they did not follow CDC guideline compared to 52% who follow guidelines. 18 of the 30 (or 60%) physicians reported more than 80% of parents complied with doctor recommended BLL testing. Twelve physicians identified cost, lack of insurance, and absence of symptomology as persistent barriers to lead screening. This study identified barriers to childhood lead screening including inadequate parental adherence to physician-ordered screenings and physician non-compliance with screening recommendations are two primary contributors. Addressing these issues could increase screening in children and reduce the risk of lead poisoning.

  12. Determination of total and electrolabile copper in agricultural soil by using disposable modified-carbon screen-printed electrodes.

    Science.gov (United States)

    Faucher, Stéphane; Cugnet, Cyril; Authier, Laurent; Lespes, Gaëtane

    2014-02-01

    The objective of the study is to evaluate modified-carbon screen-printed working electrodes (SPE) combined with square wave anodic stripping voltammetry (SWASV) to determine electrolabile and total copper in soils with the perspective to assess the environmental hazard resulting from copper anthropogenic contamination. The voltammetric method was investigated using a mineralized certified reference soil such that it can be assumed that the copper was totally under electrolabile form in the solution of mineralized soil. In optimal conditions, a copper recovery of 97% and a relative standard deviation (RSD) of 9% were found. The limits of detection and quantification for copper were 0.4 and 1.3 μg L(-1), respectively. Finally, the method was applied on soil leachates, which allowed evaluating the cupric transfer from the soil to the leachates and quantifying the electrolabile copper part in leachates.

  13. Screening variability and change of soil moisture under wide-ranging climate conditions: Snow dynamics effects.

    Science.gov (United States)

    Verrot, Lucile; Destouni, Georgia

    2015-01-01

    Soil moisture influences and is influenced by water, climate, and ecosystem conditions, affecting associated ecosystem services in the landscape. This paper couples snow storage-melting dynamics with an analytical modeling approach to screening basin-scale, long-term soil moisture variability and change in a changing climate. This coupling enables assessment of both spatial differences and temporal changes across a wide range of hydro-climatic conditions. Model application is exemplified for two major Swedish hydrological basins, Norrström and Piteälven. These are located along a steep temperature gradient and have experienced different hydro-climatic changes over the time period of study, 1950-2009. Spatially, average intra-annual variability of soil moisture differs considerably between the basins due to their temperature-related differences in snow dynamics. With regard to temporal change, the long-term average state and intra-annual variability of soil moisture have not changed much, while inter-annual variability has changed considerably in response to hydro-climatic changes experienced so far in each basin.

  14. Review of State Soil Cleanup Levels for Dioxin (December 2009)

    Science.gov (United States)

    This final report summarizes a survey of state soil cleanup levels for dioxin and characterizes the science underlying these values. The objective of this project was to summarize existing state cleanup levels for dioxin in soil, together with their scientific bases where availa...

  15. Ecological risk assessment of agricultural soils for the definition of soil screening values: A comparison between substance-based and matrix-based approaches

    Directory of Open Access Journals (Sweden)

    Alberto Pivato

    2017-04-01

    Full Text Available The Italian legislation on contaminated soils does not include the Ecological Risk Assessment (ERA and this deficiency has important consequences for the sustainable management of agricultural soils. The present research compares the results of two ERA procedures applied to agriculture (i one based on the “substance-based” approach and (ii a second based on the “matrix-based” approach. In the former the soil screening values (SVs for individual substances were derived according to institutional foreign guidelines. In the latter, the SVs characterizing the whole-matrix were derived originally by the authors by means of experimental activity.The results indicate that the “matrix-based” approach can be efficiently implemented in the Italian legislation for the ERA of agricultural soils. This method, if compared to the institutionalized “substance based” approach is (i comparable in economic terms and in testing time, (ii is site specific and assesses the real effect of the investigated soil on a battery of bioassays, (iii accounts for phenomena that may radically modify the exposure of the organisms to the totality of contaminants and (iv can be considered sufficiently conservative. Keyword: Environmental science

  16. Radium - 226 levels in some sudanese plants and soils

    International Nuclear Information System (INIS)

    Sam, A.K.

    1993-01-01

    The natural levels of 226 Ra in plant and soil samples have been studied. The field study was mainly conducted in western Sudan (Darfur and Kurdofan) where areas of high natural background radiation have been identified and Khartoum area was taken as a control to (i) assess in natural setting the soil-to-plant concentration ratios (concentration in dry sample / concentration in dry soil) of the naturally occurring radionuclide 226 Ra, (ii) establish base-line data on Radium activity concentration levels in environmental materials and (iii) explore the area of high natural radiation background in western Sudan.Low level gamma spectrometry, employing high purity germanium detector (HPGe) of relative efficiency 12%, has been used for the determination of 226 Ra activity concentrations in plant and soil samples. The mean Radium activity concentration found in soil ranged from 14.41 Bq/Kg to 79.08 Bq/Kg, the values correspond to the reported normal background levels of 226 Ra in soils worldwide. Radium activity concentrations found in Sudanese plants were significantly higher compared to those related to plants from normal background regions and significantly lower than those reported for plants from high background regions in other countries. The mean soil/plant concentration ratios (CRs) found in this study were 0.12, 0.15, 0.17 and 0.08 for whole plants, fruits and leafy vegetables, root vegetables and grains, respectively. These ranges of CR values are comparable with overall range of CR where environmental conditions are normal. The estimated daily intakes by individuals consuming foods of local origin were 1.00, 10.4 and 7.91 Bq/Day of radium Khour Abu Habil, Arkuri and Dumpir, respectively. Since the dietary habits were different, as it was noticed, these results have been much lower in comparison with those obtained from some European countries and United States. (author), 44 refs., 18 tabs., 13 figs

  17. Chemical and biological attributes of a lowland soil affected by land leveling

    Directory of Open Access Journals (Sweden)

    José Maria Barbat Parfitt

    2013-11-01

    Full Text Available The objective of this work was to evaluate the relationship between soil chemical and biological attributes and the magnitude of cuts and fills after the land leveling process of a lowland soil. Soil samples were collected from the 0 - 0.20 m layer, before and after leveling, on a 100 point grid established in the experimental area, to evaluate chemical attributes and soil microbial biomass carbon (MBC. Leveling operations altered the magnitude of soil chemical and biological attributes. Values of Ca, Mg, S, cation exchange capacity, Mn, P, Zn, and soil organic matter (SOM decreased in the soil profile, whereas Al, K, and MBC increased after leveling. Land leveling decreased in 20% SOM average content in the 0 - 0.20 m layer. The great majority of the chemical attributes did not show relations between their values and the magnitude of cuts and fills. The relation was quadratic for SOM, P, and total N, and was linear for K, showing a positive slope and indicating increase in the magnitude of these attributes in cut areas and stability in fill areas. The relationships between these chemical attributes and the magnitude of cuts and fills indicate that the land leveling map may be a useful tool for degraded soil recuperation through amendments and organic fertilizers.

  18. Phytoextraction of low level U-contaminated soil

    International Nuclear Information System (INIS)

    Vandenhove, H.A.; Hees, M. van

    2002-01-01

    The nuclear fuel cycle may be a source of environmental contamination. Uranium exploitation produces large quantities of wastes but also accidental spills at nuclear fuel production, reprocessing or waste treatment plants have led to soil contamination with uranium. U-contaminated soil is generally excavated, packaged and removed which is a costly enterprise. Soil washing has also shown promising in removing U from contaminated soil, but results in the generation of liquid wastes and the deterioration of soil properties. In contrast, phytoextraction, the use of plants to remove contaminants from polluted soil, allows for in situ treatment and does not generate liquid wastes. Furthermore, the contaminated site is covered by plants during phytoextraction and wind and water erosion will be reduced. The phytoextraction potential depends on the amount of radionuclides extracted and the biomass produced. Hyper-accumulating plants often have a low biomass production. Moreover, uranium soil-to-plant transfer factors (TF: ratio of U concentration in dry plant tissue to concentration in soil) rarely exceed a value of 0.1 gg -1 . With a TF of 0.1 gg -1 and a biomass yield of 15t dry weigh ha -1 only 0.1% of the soil uranium will be annually immobilised in the plant biomass. These figures clearly show that the phytoextraction option is not a feasible remediation option, unless the uranium bioavailability could be drastically increased. It was shown that citric acid addition to highly contaminated U contaminated soil increased the U-accumulation of Brassica juncea 1000-fold. The objective of the present paper is to find out if low level U contaminated soil can be phytoextracted in order to achieve proposed release limits

  19. Leveling and thixotropic characteristics of concentrated zirconia inks for screen-printing

    DEFF Research Database (Denmark)

    Phair, John; Lundberg, Mats; Kaiser, Andreas

    2009-01-01

    of ethyl cellulose (binder) content upon the thixotropic and leveling characteristics of zirconia inks. While the yield stress (τ 0), extent of recovery R(%), and rate of recovery (K) increase with increasing binder content, so did the surface roughness and thickness of the screen-printed films. Increasing...... the binder content not only increases the network strength of the thick films but also leads to increased leveling time. As a result, rheological modifiers are proposed to be necessary to improve the leveling characteristics of zirconia inks without losing the green strength of the thick films......Screen-printing is a cost-effective method for the mass manufacture of zirconia-based solid oxide fuel cells (SOFCs) and oxygen separation membranes. The present work outlines an investigation into the leveling, thixotropic, and screen-printing characteristics of concentrated zirconia inks...

  20. Physicochemical Characteristics and Heavy Metal Levels in Soil ...

    African Journals Online (AJOL)

    ADOWIE PERE

    weathering of mineral; the anthropogenic sources are associated mainly with ... al., 2013 reported high levels of Cd, Zn, Ni, Cr and. Pb from soil .... Determination of trace elements (Zn and Mn): 5 g of the dried ..... vehicles constitute principal source of Pb. Lead ..... Interaction between metals and soil organic matter in various.

  1. Spatial distribution of metals in soils in Baltimore, Maryland: Role of native parent material, proximity to major roads, housing age and screening guidelines

    International Nuclear Information System (INIS)

    Yesilonis, I.D.; Pouyat, R.V.; Neerchal, N.K.

    2008-01-01

    We investigated the spatial distribution of heavy metal above-background (anthropic) contents of Cd, Co, Cu, Cr, Fe, Mn, Ni, Pb, Ti, V, and Zn in Baltimore City surface soils and related these levels to potential contaminating sources. Composite soil samples (0-10 cm depth) were digested using a nitric and hydrochloric extraction technique. Slightly more than 10% of plots exceeded United States Environmental Protection Agency screening guidelines for Pb. In a principal component analysis, the first component corresponded to Co, Cr, and Fe, which are constituents of local mafic rocks. The second component corresponded to Cu, Pb, and Zn which were significantly higher within than beyond a 100 m buffer of the major roads within the city; furthermore, Pb and Zn were higher in older residential lots. - Spatial distribution of metals in soils of an older US city (Baltimore) was affected by parent material, proximity to major roads, and housing age

  2. Determination of spatial continuity of soil lead levels in an urban residential neighborhood

    Energy Technology Data Exchange (ETDEWEB)

    Shinn, N.J.; Bing-Canar, J.; Cailas, M.; Peneff, N.; Binns, H.J.

    2000-01-01

    This study uses geostatistical techniques to model and estimate soil lead levels in an urban, residential neighborhood. Sixty-two composite soil samples in a four-block area of brick and stone homes were obtained. The spatial continuity of soil lead levels was modeled with a semi-variogram, which was then used to estimate lead levels at unsampled locations, a process called kriging. Because soil lead levels were spatially correlated, it is likely that a nonrandom process generated the lead distribution found. This finding signifies the existence of lead sources which were tentatively identified on historical maps of the area and from past traffic volume patterns. The distribution of kriged estimates of soil lead levels provides an explanatory tool for exploring and identifying potential sources and may be useful for targeting urban soil abatement efforts.

  3. Levels of 137Cs and 40K in wood ash-amended soils

    International Nuclear Information System (INIS)

    Ohno, Tsutomu; Hess, C.T.

    1994-01-01

    Wood ash is a residual material produced at an annual rate of 1.5-3.0 million tons by wood burning power plants in the USA. Up to 80% of the wood ash generated in northeastern USA is landspread on agricultural soils. Recently, concern has arisen regarding the 137 Cs content of wood ash and levels of 137 Cs of wood ash-amended soils. The 137 Cs originated primarily from above ground nuclear weapons testing in the 1950s and 1960s. This study examined the total and pH 3, NH 4 OAc extractable levels of 137 Cs and 40 K in three soils incubated in the laboratory with 0, 3 and 9 g of wood ash on a calcium carbonate equivalence basis kg -1 soil. The wood ash contained 137 Cs and 40 K at 3920 and 21'700 pCi kg -1 , respectively. At the regulated wood ash application rate limit, 3 g wood ash (calcium carbonate equivalent basis) kg -1 of soil, there was no statistical difference from the control treatment in both total and soluble 137 Cs and 40 K levels. For one soil, there was an increase in the 137 Cs level when wood ash was amended at 9 g wood ash (calcium carbonate equivalent basis) kg -1 soil. The 137 Cs was strongly bound to the cation exchange sites of the soils with the average fraction soluble in pH 3, NH 4 OAc solution at 4.8% in the mineral soils and 0.9% in the organic soil. Considering the current limits on permitted wood ash application rates to soils, there was no statistically significant effect on the levels of 137 Cs or 40 K found in wood ash-amended soils

  4. Phytoextraction for clean-up of low-level uranium contaminated soil evaluated

    International Nuclear Information System (INIS)

    Vandenhove, H.; Hees, M. van

    2004-01-01

    Spills in the nuclear fuel cycle have led to soil contamination with uranium. In case of small contamination just above release levels, low-cost yet sufficiently efficient remedial measures are recommended. This study was executed to test if low-level U contaminated sandy soil from a nuclear fuel processing site could be phytoextracted in order to attain the required release limits. Two soils were tested: a control soil (317 Bq 238 U kg -1 ) and the same soil washed with bicarbonate (69 Bq 238 U kg -1 ). Ryegrass (Lolium perenne cv. Melvina) and Indian mustard (Brassica juncea cv. Vitasso) were used as test plants. The annual removal of soil activity by the biomass was less than 0.1%. The addition of citric acid (25 mmol kg -1 ) 1 week before the harvest increased U uptake up to 500-fold. With a ryegrass and mustard yield of 15,000 and 10,000 kg ha -1 , respectively, up to 3.5% and 4.6% of the soil activity could be removed annually by the biomass. With a desired activity reduction level of 1.5 and 5 for the bicarbonate-washed and control soil, respectively, it would take 10-50 years to attain the release limit. However, citric acid addition resulted in a decreased dry weight production

  5. EFFECT OF DIFFERENT LEVELS AGROECOLOGICAL LOADS ON BIOCHEMICAL CHARACTERISTICS OF SOIL

    Directory of Open Access Journals (Sweden)

    A. V. Shchur

    2016-01-01

    Full Text Available Aim. To study the effect of different levels of agri-environmental loads on the enzymatic activity of the soil.Methods. Isolation of soil fauna was conducted by thermogradient. Ecological characteristics of soil biota community was determined by ecological indices. The enzymatic activity of soil under different crops and at different levels of agri-environmental loads in our experiments was determined by methods proven in the laboratory soil enzymology Institute of Experimental Botany name V.F. Kuprevich and Belorussian Research Institute for Soil Science and Agricultural Chemistry.Results. Community soil biota is polydominant character, as evidenced by the values of environmental indices. It does not set a significant impact on the community agrotechnological loads of soil micro and mesofauna. Absolute figures soil phosphatase activity averaged over all embodiments without recourse formation were higher by 63% compared with plowing. Invertase and catalase activity was much higher in stubble on all variants of the experiment and selection of terms. The content of peroxidase lower under pure steam. The laws have taken place in respect of peroxidase activity, marked for polifenoloksidase activity.Main conclusion. There was no major change in the ecological characteristics of soil biota. In the enzymatic activity of soil influenced by sampling time, fertilizer system, soil tillage methods and cultivated crops.

  6. Determinants of gastric cancer screening attendance in Korea: a multi-level analysis

    OpenAIRE

    Chang, Yunryong; Cho, Belong; Son, Ki Young; Shin, Dong Wook; Shin, Hosung; Yang, Hyung-Kook; Shin, Aesun; Yoo, Keun-Young

    2015-01-01

    Background We aimed to assess individual and area-level determinants of gastric cancer screening participation. Method Data on gastric cancer screening and individual-level characteristics were obtained from the 2007?2009 Fourth Korea National Health and Nutrition Examination Survey. The area-level variables were collected from the 2005 National Population Census, 2008 Korea Medical Association, and 2010 National Health Insurance Corporation. The data were analyzed using multilevel logistic r...

  7. Relationship between soil contents and plasma levels of selenium ...

    African Journals Online (AJOL)

    The soil contents of trace elements selenium, chromium and manganese were measured to determine their impact on the plasma levels of 160 healthy adult Nigerians in five different experimental locations in Cross River and Akwa Ibom States, South - South Nigeria. The mean (±SD) soil selenium, chromium and ...

  8. A rapid screening-level method to optimize location of infiltration ponds.

    Science.gov (United States)

    Fennemore, G G; Davis, A; Goss, L; Warrick, A W

    2001-01-01

    A rapid-screening technique was developed to identify lithologies that best disperse artificial recharge via surface infiltration and minimize effects on ground water chemistry. The technique prospectively evaluates basin infiltration rates and water chemistry influences by integrating geotechnical, hydraulic, and water quality data with column test data and numerical modeling. The technique was validated using field data collected from surface infiltration basins designed to recharge ground water pumped from the Pipeline pit gold mine in Nevada. Observed recharge rates at these infiltration sites correlated most significantly with depth to groundwater, with basins in coarse-grained lithologies performing better (0.45 to 0.85 m/day) than those with fine-grained layers ( 2000 mg/L) than coarse-grained soils (infiltration basins for a variety of lithologies. Sites for infiltration basins can be rapidly screened to include areas with greatest depth to groundwater and in coarsest alluvial sediments, and impact to ground water chemistry can be reliably predicted using computer modeling and column test results.

  9. Thermopiles - a new thermal desorption technology for recycling highly organic contaminated soils down to natural levels

    International Nuclear Information System (INIS)

    Haemers, J.; Cardot, J.; Falcinelli, U.; Zwaan, H.

    2005-01-01

    The Thermopile R technology, developed by Deep Green, provides an implementation system allowing to treat hydrocarbon and PAH contaminated materials down to natural levels or down to levels where they are treatable with a traditional thermal desorption unit, in a controlled batch system. The materials are indirectly heated while a substantial part of the energy is reused to heat the pile of soil. The system differs from most of the indirect thermal desorption systems by its very high energetic efficiency as well as its ability to be set -up remotely. The system does not face preferential path problems, since the heating medium is only conduction, which is very indifferent with regard to soil type (clay, sand, silt, etc.). That property is critical to an in-depth clean-up with a batch system. Other systems, based on heat, are mostly sending heat vectors (gases, hot air, steam, etc.) through the soil, which implies preferential paths, which are the main cause for not completely cleaning the soil with most batch technologies (down to natural levels). The soil to treat is placed in a pile or in a modular container in which perforated steel pipes are installed along a hexagonal pattern. During treatment those pipes are heated by hot gases (about 600 deg. C) coming from the afterburner. Consequently the soil reaches the contaminant's desorption temperature. The desorbed pollutants are then drawn by convection and diffusion into the heating pipes via the perforations. Once in the pipes the desorbed gases are mixed with the heating gases. They are sucked by the ID fan and sent to the afterburner. The hydrocarbons in gaseous phase are then oxidized in the afterburner. In this manner, they provide a part of the energy needed to heat the soil itself. The pilot unit is also equipped with a purge that allows the evacuation of a part of the gases circulating in the system; Different additional gas treatments can be applied as required by the type of contaminants and the

  10. Estimating Soil Organic Carbon of Cropland Soil at Different Levels of Soil Moisture Using VIS-NIR Spectroscopy

    Directory of Open Access Journals (Sweden)

    Qinghu Jiang

    2016-09-01

    Full Text Available Soil organic carbon (SOC is an essential property for soil function, fertility and sustainability of agricultural systems. It can be measured with visible and near-infrared reflectance (VIS-NIR spectroscopy efficiently based on empirical equations and spectra data for air/oven-dried samples. However, the spectral signal is interfered with by soil moisture content (MC under in situ conditions, which will affect the accuracy of measurements and calibration transfer among different areas. This study aimed to (1 quantify the influences of MC on SOC prediction by VIS-NIR spectroscopy; and (2 explore the potentials of orthogonal signal correction (OSC and generalized least squares weighting (GLSW methods in the removal of moisture interference. Ninety-eight samples were collected from the Jianghan plain, China, and eight MCs were obtained for each sample by a rewetting process. The VIS-NIR spectra of the rewetted soil samples were measured in the laboratory. Partial least squares regression (PLSR was used to develop SOC prediction models. Specifically, three validation strategies, namely moisture level validation, transferability validation and mixed-moisture validation, were designed to test the potentials of OSC and GLSW in removing the MC effect. Results showed that all of the PLSR models generated at different moisture levels (e.g., 50–100, 250–300 g·kg−1 were moderately successful in SOC predictions (r2pre = 0.58–0.85, RPD = 1.55–2.55. These models, however, could not be transferred to soil samples with different moisture levels. OSC and GLSW methods are useful filter transformations improving model transferability. The GLSW-PLSR model (mean of r2pre = 0.77, root mean square error for prediction (RMSEP = 3.08 g·kg−1, and residual prediction deviations (RPD = 2.09 outperforms the OSC-PLSR model (mean of r2pre = 0.67, RMSEP = 3.67 g·kg−1, and RPD = 1.76 when the moisture-mixed protocol is used. Results demonstrated the use of OSC

  11. Development of a matrix approach to estimate soil clean-up levels for BTEX compounds

    International Nuclear Information System (INIS)

    Erbas-White, I.; San Juan, C.

    1993-01-01

    A draft state-of-the-art matrix approach has been developed for the State of Washington to estimate clean-up levels for benzene, toluene, ethylbenzene and xylene (BTEX) in deep soils based on an endangerment approach to groundwater. Derived soil clean-up levels are estimated using a combination of two computer models, MULTIMED and VLEACH. The matrix uses a simple scoring system that is used to assign a score at a given site based on the parameters such as depth to groundwater, mean annual precipitation, type of soil, distance to potential groundwater receptor and the volume of contaminated soil. The total score is then used to obtain a soil clean-up level from a table. The general approach used involves the utilization of computer models to back-calculate soil contaminant levels in the vadose zone that would create that particular contaminant concentration in groundwater at a given receptor. This usually takes a few iterations of trial runs to estimate the clean-up levels since the models use the soil clean-up levels as ''input'' and the groundwater levels as ''output.'' The selected contaminant levels in groundwater are Model Toxic control Act (MTCA) values used in the State of Washington

  12. Modelling soil water dynamics and crop water uptake at the field level

    NARCIS (Netherlands)

    Kabat, P.; Feddes, R.A.

    1995-01-01

    Parametrization approaches to model soil water dynamics and crop water uptake at field level were analysed. Averaging and numerical difficulties in applying numerical soil water flow models to heterogeneous soils are highlighted. Simplified parametrization approaches to the soil water flow, such as

  13. Tolerance of soil flagellates to increased NaCl levels

    DEFF Research Database (Denmark)

    Ekelund, Flemming

    2002-01-01

    The ability of heterotrophic flagellates to survive and adapt to increasing salinities was investigated in this study. Whole soil samples were subjected to salinities corresponding to marine conditions and clonal cultures were used to perform growth and adaptation experiments at a wide range...... of different salinities (0-50 ppm). More morphotypes tolerant to elevated NaCl levels were found in road verge soil that was heavily exposed to de-icing salt than in less exposed soils, though there were fewer tolerant than intolerant morphotypes in all soils examined. Heterotrophic flagellates isolated...... on a freshwater medium from a non-exposed soil were unable to thrive at salinities above 15 ppt, and showed reduced growth rates even at low salt salinities (1-5 ppt). The findings suggest that heterotrophic soil flagellates are less tolerant to NaCl than their aquatic relatives, possibly due to their long...

  14. An investigation into the use of a mixture model for simulating the electrical properties of soil with varying effective saturation levels for sub-soil imaging using ECT

    International Nuclear Information System (INIS)

    Hayes, R R; Newill, P A; Podd, F J W; York, T A; Grieve, B D; Dorn, O

    2010-01-01

    A new visualisation tool is being developed for seed breeders, providing on-line data for each individual plant in a screening programme. It will be used to indicate how efficiently each plant utilises the water and nutrients available in the surrounding soil. This will facilitate early detection of desirable genetic traits with the aim of increased efficiency in identification and delivery of tomorrow's drought tolerant food crops. Visualisation takes the form of Electrical Capacitance Tomography (ECT), a non-destructive and non-intrusive imaging technique. Measurements are to be obtained for an individual plant thus allowing water and nutrient absorption levels for an individual specimen to be inferred. This paper presents the inverse problem, discusses the inherent challenges and presents the early experimental results. Two mixture models are evaluated for the prediction of electrical capacitance measurement data for varying effective soil saturation levels using a finite element model implemented in COMSOL Multiphysics. These early studies have given the research team an understanding of the technical challenges that must now be addressed to take the current research into the world of agri-science and food supply.

  15. The organic contamination level based on the total soil mass is not a proper index of the soil contamination intensity

    Science.gov (United States)

    Hung, H.-W.; Daniel, Sheng G.; Lin, T.-F.; Su, Y.; Chiou, C.T.

    2009-01-01

    Concentrations of organic contaminants in common productive soils based on the total soil mass give a misleading account of actual contamination effects. This is attributed to the fact that productive soils are essentially water-saturated, with the result that the soil uptake of organic compounds occurs principally by partition into the soil organic matter (SOM). This report illustrates that the soil contamination intensity of a compound is governed by the concentration in the SOM (Com) rather than by the concentration in whole soil (Cs). Supporting data consist of the measured levels and toxicities of many pesticides in soils of widely differing SOM contents and the related levels in in-situ crops that defy explanation by the Cs values. This SOM-based index is timely needed for evaluating the contamination effects of food crops grown in different soils and for establishing a dependable priority ranking for intended remediation of numerous contamination sites.

  16. Assessment of Soil-Gas and Soil Contamination at the Former Military Police Range, Fort Gordon, Georgia, 2009-2010

    Science.gov (United States)

    Falls, W. Fred; Caldwell, Andral W.; Guimaraes, Wladmir B.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2011-01-01

    Soil gas and soil were assessed for organic and inorganic contaminants at the former military police range at Fort Gordon, Georgia, from May to September 2010. The assessment evaluated organic contaminants in soil-gas samplers and inorganic contaminants in soil samples. This assessment was conducted to provide environmental contamination data to Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. Soil-gas samplers deployed and collected from May 20 to 24, 2010, identified masses above method detection level for total petroleum hydrocarbons, gasoline-related and diesel-related compounds, and chloroform. Most of these detections were in the southwestern quarter of the study area and adjacent to the road on the eastern boundary of the site. Nine of the 11 chloroform detections were in the southern half of the study area. One soil-gas sampler deployed adjacent to the road on the southern boundary of the site detected a mass of tetrachloroethene greater than, but close to, the method detection level of 0.02 microgram. For soil-gas samplers deployed and collected from September 15 to 22, 2010, none of the selected organic compounds classified as chemical agents and explosives were detected above method detection levels. Inorganic concentrations in the five soil samples collected at the site did not exceed the U.S. Environmental Protection Agency regional screening levels for industrial soil and were at or below background levels for similar rocks and strata in South Carolina.

  17. A model for determination of screening level for radioactive elements in soil; Modelo para o estabelecimento de valores orientadores para elementos radioativos no solo

    Energy Technology Data Exchange (ETDEWEB)

    Peres, Ana Claudia

    2007-07-01

    At the present, decision about clean-up of Brazilian sites contaminated with radioactive isotopes is addressed on a case-by-case basis, since there is no general guidance or recommendation to support actions in early phases of the problem identification. For chemicals, CETESB - the governmental organization responsible for preventing and controlling environmental pollution in Sao Paulo State - established background values, prevention and intervention, as the first step to implement a remediation actions based on human health risk assessment. The aim of this study was to develop a methodology for the establishment of target values for radioactive soil contamination, as far as possible consistent and compatible with the approach adopted by CETESB for sites contaminated with chemicals. The following steps have been addressed in this study: conceptual scenario and model development; codification of the equations in an electronic spreadsheet; selection of proper range and statistical distribution of the input values; derivation of the intervention levels for selected radionuclides using Monte Carlo methods. The mathematical model developed was mainly based on the equations used by the U.S. Environmental Protection Agency (EPA) and by the National Council on Radiation Protection and Measurements (NCRP) for soil screening purposes. Intervention and prevention values are presented for adult and 10 years old child, for each 3 exposure scenarios: agricultural, residential and industrial; the following radionuclides were considered: {sup 3}H, {sup 14}C, {sup 32}P, {sup 35}S, {sup 45}Ca, {sup 51}Cr, {sup 90}Sr, {sup 125}I, {sup 131}I, {sup 134}Cs, {sup 137}Cs, {sup 210}Pb, {sup 226}Ra, {sup 228}Ra, {sup 232}Th, {sup 238}U, {sup 239}Pu and {sup 241} Am. Quality reference values were determined for {sup 40}K, {sup 137}Cs, {sup 210}Pb, {sup 226}Ra, {sup 228}Ra, {sup 228}Th, Th-nat e U-nat. Results obtained in this study showed a good agreement with those reported by NCRP

  18. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Soil and Litter Invertebrates and Heterotrophic Process

    Energy Technology Data Exchange (ETDEWEB)

    Will, M.E.

    1994-01-01

    This report presents a standard method for deriving benchmarks for the purpose of ''contaminant screening,'' performed by comparing measured ambient concentrations of chemicals. The work was performed under Work Breakdown Structure 1.4.12.2.3.04.07.02 (Activity Data Sheet 8304). In addition, this report presents sets of data concerning the effects of chemicals in soil on invertebrates and soil microbial processes, benchmarks for chemicals potentially associated with United States Department of Energy sites, and literature describing the experiments from which data were drawn for benchmark derivation.

  19. Boron levels in soils cropped to coffee and their relationships to ...

    African Journals Online (AJOL)

    Studies on boron levels in soils cropped to coffee were carried out in Ghana due to widespread reports on boron deficiency in soils of some coffee producing countries. Leaves and soils were sampled from Cocobod coffee plantations at Bogoso, Suhuma, Manso-Mim, Bunso and Bepong, which represent the main coffee ...

  20. Sorption behavior of cesium on various soils under different pH levels

    International Nuclear Information System (INIS)

    Giannakopoulou, F.; Haidouti, C.; Chronopoulou, A.; Gasparatos, D.

    2007-01-01

    In the present study we investigated the sorption behavior of Cs in four different soils (sandyloam, loam, clayloam and clay) by using batch experiment. Cs sorption characteristics of the studied soils were examined at 4 mg L -1 Cs concentration, at various pH levels, at room temperature and with 0.01 M CaCl 2 as a background electrolyte. Among different soils the decrease of k d (distribution coefficient) of cesium, at all pH levels, followed the sequence sandyloam > loam > clayloam > clay, indicating that the particle size fractions and especially the clay content plays predominant role on sorption of Cs. The effect of pH on cesium sorption displays a similar pattern for all soils, depending on soil type. At acid pH levels less cesium was sorbed, due to a greater competition with other cations for available sorption sites. The maximum sorption of Cs was observed at pH 8, where the negative charge density on the surface of the absorbents was the highest. For all soils was observed significantly lower Cs sorption at pH 10

  1. Soil criteria to protect terrestrial wildlife and open-range livestock from metal toxicity at mining sites.

    Science.gov (United States)

    Ford, Karl L; Beyer, W Nelson

    2014-03-01

    Thousands of hard rock mines exist in the western USA and in other parts of the world as a result of historic and current gold, silver, lead, and mercury mining. Many of these sites in the USA are on public lands. Typical mine waste associated with these sites are tailings and waste rock dumps that may be used by wildlife and open-range livestock. This report provides wildlife screening criteria levels for metals in soil and mine waste to evaluate risk and to determine the need for site-specific risk assessment, remediation, or a change in management practices. The screening levels are calculated from toxicity reference values based on maximum tolerable levels of metals in feed, on soil and plant ingestion rates, and on soil to plant uptake factors for a variety of receptors. The metals chosen for this report are common toxic metals found at mining sites: arsenic, cadmium, copper, lead, mercury, and zinc. The resulting soil screening values are well above those developed by the US Environmental Protection Agency. The difference in values was mainly a result of using toxicity reference values that were more specific to the receptors addressed rather than the most sensitive receptor.

  2. Determination of levels of polycyclic aromatic hydrocarbons in soil ...

    African Journals Online (AJOL)

    MICHAEL HORSFALL

    mishandling, deliberate disposal, spilling and leakage of petroleum products ... and eventually seeps into water bodies (Olugboji and ... solubility in water and are highly lipophilic. In water .... detect levels of PAHs in soils even at low levels and.

  3. Influence of Acacia trees on soil nutrient levels in arid lands

    Science.gov (United States)

    De Boever, Maarten; Gabriels, Donald; Ouessar, Mohamed; Cornelis, Wim

    2014-05-01

    The potential of scattered trees as keystone structures in restoring degraded environments is gaining importance. Scattered trees have strong influence on their abiotic environment, mainly causing changes in microclimate, water budget and soil properties. They often function as 'nursing trees', facilitating the recruitment of other plants. Acacia raddiana is such a keystone species which persists on the edge of the Sahara desert. The study was conducted in a forest-steppe ecosystem in central Tunisia where several reforestation campaigns with Acacia took place. To indentify the impact of those trees on soil nutrients, changes in nutrient levels under scattered trees of three age stages were examined for the upper soil layer (0-10 cm) at five microsites with increasing distance from the trunk. In addition, changes in soil nutrient levels with depth underneath and outside the canopy were determined for the 0-30 cm soil layer. Higher concentrations of organic matter (OM) were found along the gradient from underneath to outside the canopy for large trees compared to medium and small trees, especially at microsites close to the trunk. Levels of soluble K, electrical conductivity (EC), available P, OM, total C and N decreased whereas pH and levels of soluble Mg increased with increasing distance from tree. Levels of soluble Ca and Na remained unchanged along the gradient. At the microsite closest to the trunk a significant decrease in levels of soluble K, EC, OM, available P, total C and N, while a significant increase in pH was found with increasing depth. The concentration of other nutrients remained unchanged or declined not differently underneath compared to outside the canopy with increasing depth. Differences in nutrient levels were largely driven by greater inputs of organic matter under trees. Hence, Acacia trees can affect the productivity and reproduction of understory species with the latter in term an important source of organic matter. This positive feedback

  4. A novel salt-tolerant chitobiosidase discovered by genetic screening of a metagenomic library derived from chitin-amended agricultural soil

    NARCIS (Netherlands)

    Cretoiu, Mariana Silvia; Berini, Francesca; Kielak, Anna Maria; Marinelli, Flavia; van Elsas, Jan Dirk

    2015-01-01

    Here, we report on the construction of a metagenomic library from a chitin-amended disease-suppressive agricultural soil and its screening for genes that encode novel chitinolytic enzymes. The library, constructed in fosmids in an Escherichia coli host, comprised 145,000 clones containing inserts of

  5. Survey of radioactivity levels of soil in Shanghai

    International Nuclear Information System (INIS)

    Ren Lihua

    1993-01-01

    The gross α and β activities on soil were measured by a mode FJ-2600 air-flow type alpha and beta counter. 204 sampling points including 173 grid points and 31 special points were set in the whole city. The ranges of the gross α and β activities in soil at the grid points are 816.5-2056.1 Bq/kg and 633.2-896.4 Bq/kg respectively. All these values are within the normal range of background activities. Only few special points are beyond the normal range. The results of statistical test indicate that the gross α and β activities show a normal distribution and that the levels of gross activity correlate with the sampling point, soil type and the geomorphology. It seems that the wide range of background values is related to the differences in natural conditions, such as the terrestrial formation, the soil-forming parent materials, etc., and the human activity

  6. Lead levels in roadside soils and vegetation of Damascus city

    International Nuclear Information System (INIS)

    Othman, I.; Al-Oudat, M.; Al-Masri, M.S.

    1999-01-01

    Seasonal variations of lead concentration in roadside soils and plants in 12 sites in Damascus city have been investigated. Lead concentrations in soil were found to be varied from 78.4 ppm to 832 ppm; lower levels in the wet period than in the dry period were observed. While lead levels in roadside plants varied between 3.39 ppm to 13.28 ppm. The results have also shown that most of the vegetables grown on the roadside of Damascus city have high concentrations of lead and the normal washing does not decrease it to An acceptable level. (author)

  7. Evaluation of a biodegradation screening protocol for contaminated soil from manufactured gas plant sites

    International Nuclear Information System (INIS)

    Morgan, D.J.; Battaglia, A.; Smith, J.R.; Middleton, A.C.; Nakles, D.V.; Linz, D.G.

    1991-01-01

    Bioremediation has been demonstrated to be a viable alternative for treating soils contaminated with PAHs. however, given the variability encountered in soils characteristics and contamination level, their susceptibility to biological treatment must be assessed on a case-by-case basis. This paper discusses a new treatability protocol, the GRI Accelerated Treatability Protocol. The mainstay of the protocol, which is designed to quickly provide treatability data for a given contaminated soil is a bioslurry experiment, in which the contaminated soil is continuously stirred and provided with abundant oxygen, nutrients and water, to maximize biological activity and thus contaminant removal. The results of using such protocol on four soils, widely differing in physical characteristics and contamination levels, are compared to the results of traditional pan studies, and an empirical equation, describing the observed soil concentrations as a function of time in both slurry and pans, is presented. Similarities and differences between achievable endpoints and biodegradation rates are discussed, and the applicability of the GRI Accelerated Treatability Protocol to full-scale engineered systems is addressed. Results to date indicate that, for soils with less than 10% fines slurry and pan experiments yield approximately the same endpoint, so that for those soils the GRI Accelerated Treatability Protocol can be used to assess the viability of an unsaturated bioremediation system. For soils with more than 10% fines, the slurry treatment endpoints are better than the pans. For those soils a traditional pan study experiment should be performed to evaluate the potential capabilities of unsaturated bioremediation

  8. Deriving site-specific clean-up criteria to protect ecological receptors (plants and soil invertebrates) exposed to metal or metalloid soil contaminants via the direct contact exposure pathway

    Science.gov (United States)

    Checkai, Ron; Van Genderen, Eric; Sousa, José Paulo; Stephenson, Gladys; Smolders, Erik

    2014-01-01

    Soil contaminant concentration limits for the protection of terrestrial plants and soil invertebrates are commonly based on thresholds derived using data from laboratory ecotoxicity tests. A comprehensive assessment has been made for the derivation of ecological soil screening levels (Eco-SSL) in the United States; however, these limits are conservative because of their focus on high bioavailability scenarios. Here, we explain and evaluate approaches to soil limit derivation taken by 4 jurisdictions, 2 of which allow for correction of data for factors affecting bioavailability among soils, and between spiked and field-contaminated soils (Registration Evaluation Authorisation and Restriction of Chemicals [REACH] Regulation, European Union [EU], and the National Environment Protection Council [NEPC], Australia). Scientifically advanced features from these methods have been integrated into a newly developed method for deriving soil clean-up values (SCVs) within the context of site-specific baseline ecological risk assessment. Resulting site-specific SCVs that account for bioavailability may permit a greater residual concentration in soil when compared to generic screening limit concentrations (e.g., Eco-SSL), while still affording acceptable protection. Two choices for selecting the level of protection are compared (i.e., allowing higher effect levels per species, or allowing a higher percentile of species that are potentially unprotected). Implementation of this new method is presented for the jurisdiction of the United States, with a focus on metal and metalloid contaminants; however, the new method can be used in any jurisdiction. A case study for molybdate shows the large effect of bioavailability corrections and smaller effects of protection level choices when deriving SCVs. Integr Environ Assess Manag 2014;10:346–357. PMID:24470189

  9. Screening of chelating ligands to enhance mercury accumulation from historically mercury-contaminated soils for phytoextraction.

    Science.gov (United States)

    Wang, Jianxu; Xia, Jicheng; Feng, Xinbin

    2017-01-15

    Screening of optimal chelating ligands which not only have high capacities to enhance plant uptake of mercury (Hg) from soil but also can decrease bioavailable Hg concentration in soil is necessary to establish a viable chemically-assisted phytoextraction. Therefore, Brassica juncea was exposed to historically Hg-contaminated soil (total Hg, 90 mg kg -1 ) to investigate the efficiency of seven chelating agents [ammonium thiosulphate, sodium thiosulphate, ammonium sulfate, ammonium chloride, sodium nitrate, ethylenediaminetetraacetic acid (EDTA), and sodium sulfite] at enhancing Hg phytoextraction; the leaching of bioavailable Hg caused by these chelating agents was also investigated. The Hg concentration in control (treated with double-distilled water) plant tissues was below 1 mg kg -1 . The remarkably higher Hg concentration was found in plants receiving ammonium thiosulphate and sodium sulfite treatments. The bioaccumulation factors and translocation factors of ammonium thiosulphate and sodium sulfite treatments were significantly higher than those of the other treatments. The more efficient uptake of Hg by plants upon treatment with ammonium thiosulphate and sodium sulfite compared to the other treatments might be explained by the formation of special Hg-thiosulphate complexes that could be preferentially taken up by the roots and transported in plant tissues. The application of sulfite significantly increased bioavailable Hg concentration in soil compared with that in initial soil and control soil, whereas ammonium thiosulphate significantly decreased bioavailable Hg concentration. The apparent decrease of bioavailable Hg in ammonium thiosulphate-treated soil compared with that in sodium sulfite-treated soil might be attributable to the unstable Hg-thiosulphate complexes formed between thiosulphate and Hg; they could react to produce less bioavailable Hg in the soil. The results of this study indicate that ammonium thiosulphate may be an optimal chelating

  10. Soil dioxins levels at agriculture sites and natural preserve areas of Taiwan.

    Science.gov (United States)

    Jou, Jin-juh; Lin, Kae-Long; Chung, Jen-Chir; Liaw, Shu-Liang

    2007-08-17

    In this study, agriculture soil in Taiwan has been sampled and analyzed to determine the background level of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/DF) in the agricultural and nature preserve areas. Another objective is to investigate relationship between soil characteristics and air deposition in Taiwan. The results indicate that in nature preserve areas the topsoil shows an extraordinary profile of PCDD/DF compared to that in the air deposition. The PCDD/DF levels of the low-contaminated agricultural soils are compatible with those of the nature preserves soils. However, in the highly-contaminated agricultural soils, there is an abrupt jump in their concentrations, 10-100 times higher. The overall I-TEQ values of the background topsoils range from 0.101 to 15.2 ng I-TEQ/kg. Near industrial/urban areas in Taiwan the PCDD/DF are slightly higher compared to those in the low concentration group. Typically, the PCDD/DF background values found in this survey fall in the 90% confidence interval and can thus, be deemed the background levels in Taiwan. Ninety-five percent of these data are below the European and American soil standard of 10 ng I-TEQ/kg d.w. The PCDD/DF profile with one neighborhood soil sample was shown no significant difference.

  11. Isolation and screening of antibiotic producing actinomycetes from soils in Gondar town, North West Ethiopia

    Directory of Open Access Journals (Sweden)

    Abebe Bizuye

    2013-10-01

    Full Text Available Objective: To isolate and screen antibiotic producing actinomycetes from potential soil samples of Gondar town, Ethiopia. Methods: Fifteen soil samples were collected, serially diluted and spread on starch casein and oat meal agar supplemented with amoxicillin and cyclohexamide for inhibition of bacteria and fungi, respectively. Cross streak method was used to check antagonistic activity of isolated actinomycetes against test organisms. Solid state fermentation and crude extraction were used for the production of antibiotics from isolates. Agar well diffusion was used for antimicrobial activity of crude extracts against test organisms. Results: Three isolates (Ab18, Ab28 and Ab43 have been shown high antagonistic activity during primary screening. Inhibition zones obtained from crude extracts showed significance differences when compared with standard antibiotics tested against test organisms (P<0.05. Inhibition zone of crude extracts from isolate Ab18 against Klebsiella pneumonia ATCC7000603 and Escherichia coli ATCC25922 were (14依1 mm and (35依1 mm, respectively which were strong active when compared to amoxicillin (0 mm and tetracycline [(13依1 mm for Klebsiella pneumonia ATCC7000603 and (33依 1 mm for Escherichia coli ATCC25922]. Crude extracts from isolate Ab18 showed (20依1 mm and (15 依1 mm inhibition zones against methicillin resistant Staphylococcus aureus strains 2 (MRSA2 and MRSA4, respectively. Crude extract from isolate Ab43 has shown inhibition zones of (16依1 mm and (17依1 mm against MRSA2 and MRSA4, respectively. Combination of Ab18 and Ab43 has shown high antimicrobial activity (18依1 mm against MRSA2 and MRSA4. Conclusions: There was not any scientific report on soil actinomycetes producing antibiotic in the study areas. Therefore, isolation and screening of actinomycetes from such areas in optimum condition may contribute the discovery of new antibiotics. Potent antibiotics from these actinomycetes could contribute a

  12. Radionuclides, Heavy Metals, and Polychlorinated Biphenyls in Soils Collected Around the Perimeter of Low-Level Radioactive Waste Disposal Area G during 2006

    International Nuclear Information System (INIS)

    P. R. Fresquez

    2007-01-01

    Pueblo de San Ildefonso fence line show that most contained concentrations of 241 Am, 238 Pu, and 239,240 Pu above the RSRLs. Overall, all concentrations of radionuclides, heavy metals, and PCBs that were detected above background levels in soils collected around the perimeter of Area G and towards the Pueblo de San Ildefonso boundary were still very low and far below LANL screening levels and regulatory standards

  13. Temporal and spatial dynamics of mineral levels of forage, soil and ...

    African Journals Online (AJOL)

    Temporal and spatial dynamics of mineral levels of forage, soil and cattle blood ... In the plain lands, local variations occurred for soil phosphorus and magnesium. ... Rangeland improvement and supplementation strategies are suggested to ...

  14. Application of a visual soil examination and evaluation technique at site and farm level

    NARCIS (Netherlands)

    Sonneveld, M.P.W.; Heuvelink, G.B.M.; Moolenaar, S.W.

    2014-01-01

    Visual soil examination and evaluation (VSEE) techniques are semi-quantitative methods that provide rapid and cost-effective information on soil quality. These are mostly applied at site or field level, but there is an increased need for soil quality indicators at farm level to allow integration

  15. Biological Treatment of Petroleum in Radiologically Contaminated Soil

    Energy Technology Data Exchange (ETDEWEB)

    BERRY, CHRISTOPHER

    2005-11-14

    This chapter describes ex situ bioremediation of the petroleum portion of radiologically co-contaminated soils using microorganisms isolated from a waste site and innovative bioreactor technology. Microorganisms first isolated and screened in the laboratory for bioremediation of petroleum were eventually used to treat soils in a bioreactor. The bioreactor treated soils contaminated with over 20,000 mg/kg total petroleum hydrocarbon and reduced the levels to less than 100 mg/kg in 22 months. After treatment, the soils were permanently disposed as low-level radiological waste. The petroleum and radiologically contaminated soil (PRCS) bioreactor operated using bioventing to control the supply of oxygen (air) to the soil being treated. The system treated 3.67 tons of PCRS amended with weathered compost, ammonium nitrate, fertilizer, and water. In addition, a consortium of microbes (patent pending) isolated at the Savannah River National Laboratory from a petroleum-contaminated site was added to the PRCS system. During operation, degradation of petroleum waste was accounted for through monitoring of carbon dioxide levels in the system effluent. The project demonstrated that co-contaminated soils could be successfully treated through bioventing and bioaugmentation to remove petroleum contamination to levels below 100 mg/kg while protecting workers and the environment from radiological contamination.

  16. Sea level and turbidity controls on mangrove soil surface elevation change

    Science.gov (United States)

    Lovelock, Catherine E.; Fernanda Adame, Maria; Bennion, Vicki; Hayes, Matthew; Reef, Ruth; Santini, Nadia; Cahoon, Donald R.

    2015-01-01

    Increases in sea level are a threat to seaward fringing mangrove forests if levels of inundation exceed the physiological tolerance of the trees; however, tidal wetlands can keep pace with sea level rise if soil surface elevations can increase at the same pace as sea level rise. Sediment accretion on the soil surface and belowground production of roots are proposed to increase with increasing sea level, enabling intertidal habitats to maintain their position relative to mean sea level, but there are few tests of these predictions in mangrove forests. Here we used variation in sea level and the availability of sediments caused by seasonal and inter-annual variation in the intensity of La Nina-El Nino to assess the effects of increasing sea level on surface elevation gains and contributing processes (accretion on the surface, subsidence and root growth) in mangrove forests. We found that soil surface elevation increased with mean sea level (which varied over 250 mm during the study) and with turbidity at sites where fine sediment in the water column is abundant. In contrast, where sediments were sandy, rates of surface elevation gain were high, but not significantly related to variation in turbidity, and were likely to be influenced by other factors that deliver sand to the mangrove forest. Root growth was not linked to soil surface elevation gains, although it was associated with reduced shallow subsidence, and therefore may contribute to the capacity of mangroves to keep pace with sea level rise. Our results indicate both surface (sedimentation) and subsurface (root growth) processes can influence mangrove capacity to keep pace with sea level rise within the same geographic location, and that current models of tidal marsh responses to sea level rise capture the major feature of the response of mangroves where fine, but not coarse, sediments are abundant.

  17. Summary report : 2001 Sudbury soils data

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    As one of the largest metal producing regions in the world, the Sudbury Basin has been the subject of a comprehensive soil sampling and analysis program to determine the levels of metal in soils close to mining, smelting and refining operations. Mining the region's rich mineral deposits has resulted in atmospheric emissions of sulphur and the release of other chemicals of concern (COC) such as nickel, copper, arsenic and cobalt. This study described the nature and distribution of metals and metal-rich fallout particles on regional soils as well as the regional impact of smelter emissions on metal distribution. The results of 3 separate sampling programs conducted in 2001 were presented. These include the urban soil survey of residential properties, schools and parks; the regional soil survey of rural and undisturbed sites; and, a soil survey in the community of Falconbridge. The objectives of the soil survey were to provide a screening level assessment of metal concentrations in the upper 20 cm of soil and to determine if there are localized areas of higher metal levels in the upper 20 cm of soil. The change in metal concentrations with depth were identified along with the relationship between metal concentrations and smelter emissions. Metal concentrations in vegetables and fruit grown within the city limits were also identified. The soil surveys helped document the concentrations of 20 inorganic elements in soils in the Sudbury region. The results indicate that localized areas contain elevated soil levels of 6 arsenic, cobalt, copper, nickel, lead and selenium. These are typically centred within city limits in the vicinity of 3 smelting centres of Copper Cliff, Coniston and Falconbridge. The data has provided the basis for a human health and ecological risk assessment currently underway for the Sudbury region. 3 refs., 11 tabs., 3 figs.

  18. Summary report : 2001 Sudbury soils data

    International Nuclear Information System (INIS)

    2004-01-01

    As one of the largest metal producing regions in the world, the Sudbury Basin has been the subject of a comprehensive soil sampling and analysis program to determine the levels of metal in soils close to mining, smelting and refining operations. Mining the region's rich mineral deposits has resulted in atmospheric emissions of sulphur and the release of other chemicals of concern (COC) such as nickel, copper, arsenic and cobalt. This study described the nature and distribution of metals and metal-rich fallout particles on regional soils as well as the regional impact of smelter emissions on metal distribution. The results of 3 separate sampling programs conducted in 2001 were presented. These include the urban soil survey of residential properties, schools and parks; the regional soil survey of rural and undisturbed sites; and, a soil survey in the community of Falconbridge. The objectives of the soil survey were to provide a screening level assessment of metal concentrations in the upper 20 cm of soil and to determine if there are localized areas of higher metal levels in the upper 20 cm of soil. The change in metal concentrations with depth were identified along with the relationship between metal concentrations and smelter emissions. Metal concentrations in vegetables and fruit grown within the city limits were also identified. The soil surveys helped document the concentrations of 20 inorganic elements in soils in the Sudbury region. The results indicate that localized areas contain elevated soil levels of 6 arsenic, cobalt, copper, nickel, lead and selenium. These are typically centred within city limits in the vicinity of 3 smelting centres of Copper Cliff, Coniston and Falconbridge. The data has provided the basis for a human health and ecological risk assessment currently underway for the Sudbury region. 3 refs., 11 tabs., 3 figs

  19. Level of Fluoride in Soil, Grain and Water in Jalgaon District, Maharashtra, India.

    Science.gov (United States)

    Naik, Rahul Gaybarao; Dodamani, Arun Suresh; Vishwakarma, Prashanth; Jadhav, Harish Chaitram; Khairnar, Mahesh Ravindra; Deshmukh, Manjiri Abhay; Wadgave, Umesh

    2017-02-01

    Fluoride has an influence on both oral as well as systemic health. The major source of fluoride to body is through drinking water as well as through diet. Staple diet mainly depends on local environmental factors, food grains grown locally, its availability etc. Determination of fluoride level in these food grains is important. So, estimation of the amount of fluoride in grains and its relation to the sources of fluoride used for their cultivation viz., soil and water is important. To estimate the relation of fluoride concentration in grains (Jowar) with respect to that of soil and water used for their cultivation. Fifteen samples each of soil, water and grains were collected using standardized method from the same farm fields of randomly selected villages of Jalgaon district. Fluoride ion concentration was determined in laboratory using SPADNS technique. Mean difference in fluoride levels in between the groups were analyzed using ANOVA and Post-Hoc Tukey test. Linear regression method was applied to analyse the association of the fluoride content of grain with water and soil. There was a significant difference in between mean fluoride levels of soil and water (pwater and grain was found to be non significant (p=0.591). Also fluoride levels in all the three groups showed significant association with each other. Fluoride level of soil, grains and water should be adjusted to an optimum level. Soil has positive correlation with respect to uptake of fluoride by Jowar grains. So, Jowar grains with optimum fluoride content should be made available in the commercial markets so that oral and general health can be benefitted.

  20. Degradation of kresoxim-methyl in soil: impact of varying moisture, organic matter, soil sterilization, soil type, light and atmospheric CO2 level.

    Science.gov (United States)

    Khandelwal, Ashish; Gupta, Suman; Gajbhiye, Vijay T; Varghese, Eldho

    2014-09-01

    In the present investigation, persistence of kresoxim-methyl (a broad spectrum strobilurin fungicide) was studied in two different soil types of India namely Inceptisol and Ultisol. Results revealed that kresoxim-methyl readily form acid metabolite in soil. Therefore, residues of kresoxim-methyl were quantified on the basis of parent molecule alone and sum total of kresoxim-methyl and its acid metabolite. Among the two soil types, kresoxim-methyl and total residues dissipated at a faster rate in Inceptisol (T1/2 0.9 and 33.8d) than in Ultisol (T1/2 1.5 and 43.6d). Faster dissipation of kresoxim-methyl and total residues was observed in submerged soil conditions (T1/2 0.5 and 5.2d) followed by field capacity (T1/2 0.9 and 33.8d) and air dry (T1/2 2.3 and 51.0d) conditions. Residues also dissipated faster in 5% sludge amended soil (T1/2 0.7 and 21.1d) and on Xenon-light exposure (T1/2 0.5 and 8.0d). Total residues of kresoxim-methyl dissipated at a faster rate under elevated CO2 condition (∼550μLL(-)(1)) than ambient condition (∼385μLL(-)(1)). The study suggests that kresoxim-methyl alone has low persistence in soil. Because of the slow dissipation of acid metabolite, the total residues (kresoxim-methyl+acid metabolite) persist for a longer period in soil. Statistical analysis using SAS 9.3 software and Duncan's Multiple Range Test (DMRT) revealed the significant effect of moisture regime, organic matter, microbial population, soil type, light exposure and atmospheric CO2 level on the dissipation of kresoxim-methyl from soil (at 95% confidence level p<0.0001). Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Screening and assessment of solidification/stabilization amendments suitable for soils of lead-acid battery contaminated site.

    Science.gov (United States)

    Zhang, Zhuo; Guo, Guanlin; Teng, Yanguo; Wang, Jinsheng; Rhee, Jae Seong; Wang, Sen; Li, Fasheng

    2015-05-15

    Lead exposure via ingestion of soil and dust generally occurs at lead-acid battery manufacturing and recycling sites. Screening solidification/stabilization (S/S) amendments suitable for lead contaminated soil in an abandoned lead-acid battery factory site was conducted based on its chemical forms and environmental risks. Twelve amendments were used to immobilize the Pb in soil and assess the solidification/stabilization efficiency by toxicity leaching tests. The results indicated that three amendments, KH₂PO₄ (KP), KH₂PO₄:oyster shell power=1:1 (by mass ratio; SPP), and KH₂PO₄:sintered magnesia=1:1 (by mass ratio; KPM) had higher remediation efficiencies that led to a 92% reduction in leachable Pb with the addition of 5% amendments, while the acid soluble fraction of Pb (AS-Pb) decreased by 41-46% and the residual fraction (RS-Pb) increased by 16-25%. The S/S costs of the three selected amendments KP, SPP, and KPM could be controlled to $22.3 per ton of soil when the Pb concentration in soil ranged from 2000 to 3000 mg/kg. The results of this study demonstrated that KP, SPP, and KPM can effectively decrease bioavailability of Pb. These findings could provide basis for decision-making of S/S remediation of lead-acid battery contaminated sites. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Determination of Lead(II), Cadmium(II) and Copper(II) in Waste-Water and Soil Extracts on Mercury Film Screen-Printed Carbon Electrodes Sensor

    International Nuclear Information System (INIS)

    Mohd Fairulnizal Md Noh; Tothill, I.E.

    2011-01-01

    A sensor incorporating a three electrodes configuration have been fabricated using low cost screen-printing technology. These electrodes couples with Square Wave Stripping Voltammetry (SWSV) has provided a convenient screening tool for on-site detection of trace levels of Pb(II), Cd(II) and Cu(II). Modification of the graphite carbon surface based on in situ deposition of mercury film has been carried out. By appropriate choice of supporting medium and optimized parameters setting such as amount of mercury used the deposition potential, deposition time, frequency and scan rate, well resolved and reproducible response for Pb(II), Cd(II) and Cu(II) were obtained. The performance characteristics of the developed mercury film screen printed carbon electrode (MFSPCE) for 120 s deposition time showed that the linear range for Cd(II), Pb(II) and Cu(II) were 10 to 200 μg L -1 . The detection limit recorded for Cd(II), Pb(II) and Cu(II) were 2, 1 and 5 μg L -1 with relative standard deviation (RSD) of 6.5 %, 6.9 % and 7.5 %, respectively. Successful applications of the sensing device to waste-water and extracted soil samples were demonstrated. (author)

  3. Screening Level Risk Assessment for the New Waste Calcining Facility

    Energy Technology Data Exchange (ETDEWEB)

    M. L. Abbott; K. N. Keck; R. E. Schindler; R. L. VanHorn; N. L. Hampton; M. B. Heiser

    1999-05-01

    This screening level risk assessment evaluates potential adverse human health and ecological impacts resulting from continued operations of the calciner at the New Waste Calcining Facility (NWCF) at the Idaho Nuclear Technology and Engineering Center (INTEC), Idaho National Engineering and Environmental Laboratory (INEEL). The assessment was conducted in accordance with the Environmental Protection Agency (EPA) report, Guidance for Performing Screening Level Risk Analyses at Combustion Facilities Burning Hazardous Waste. This screening guidance is intended to give a conservative estimate of the potential risks to determine whether a more refined assessment is warranted. The NWCF uses a fluidized-bed combustor to solidify (calcine) liquid radioactive mixed waste from the INTEC Tank Farm facility. Calciner off volatilized metal species, trace organic compounds, and low-levels of radionuclides. Conservative stack emission rates were calculated based on maximum waste solution feed samples, conservative assumptions for off gas partitioning of metals and organics, stack gas sampling for mercury, and conservative measurements of contaminant removal (decontamination factors) in the off gas treatment system. Stack emissions were modeled using the ISC3 air dispersion model to predict maximum particulate and vapor air concentrations and ground deposition rates. Results demonstrate that NWCF emissions calculated from best-available process knowledge would result in maximum onsite and offsite health and ecological impacts that are less then EPA-established criteria for operation of a combustion facility.

  4. The effect of soilagrochemical properties on level of available phosphate in soil

    International Nuclear Information System (INIS)

    Zhang Yumei

    1985-01-01

    Superphosphate labelled with 32 P and 15 typies of soil were used to study the effect of various soil-agrochemical properties on the availability of phosphate. The level was figured with A value. The relations of A to soybean yield and soil-agro-chemical properties were analysed through Multiple regression

  5. The rocky flats controversy on radionuclide soil action levels

    International Nuclear Information System (INIS)

    Earle, T.C.

    2004-01-01

    This report describes the Rocky Flats radionuclide soil action level controversy as a case study for the purpose of understanding the nature and value of stakeholder involvement in the management of radiological hazards. The report consists of three main sections. The first section outlines the Rocky Flats story, including the Cold War era, the post-Cold War era, and the transition between the two. This provides the context necessary to understand the radionuclide soil action level controversy, the main events of which are described in the second section. In the final section, the Rocky Flats case is briefly discussed within the framework of a general model of stakeholder involvement and the lessons learned from the case are identified. (author)

  6. Identification and characterization of tebuconazole transformation products in soil by combining suspect screening and molecular typology

    International Nuclear Information System (INIS)

    Storck, Veronika; Lucini, Luigi; Mamy, Laure; Ferrari, Federico; Papadopoulou, Evangelia S.; Nikolaki, Sofia; Karas, Panagiotis A.; Servien, Remi; Karpouzas, Dimitrios G.; Trevisan, Marco; Benoit, Pierre; Martin-Laurent, Fabrice

    2016-01-01

    Pesticides generate transformation products (TPs) when they are released into the environment. These TPs may be of ecotoxicological importance. Past studies have demonstrated how difficult it is to predict the occurrence of pesticide TPs and their environmental risk. The monitoring approaches mostly used in current regulatory frameworks target only known ecotoxicologically relevant TPs. Here, we present a novel combined approach which identifies and categorizes known and unknown pesticide TPs in soil by combining suspect screening time-of-flight mass spectrometry with in silico molecular typology. We used an empirical and theoretical pesticide TP library for compound identification by both non-target and target time-of-flight (tandem) mass spectrometry, followed by structural proposition through a molecular structure correlation program. In silico molecular typology was then used to group TPs according to common molecular descriptors and to indirectly elucidate their environmental parameters by analogy to known pesticide compounds with similar molecular descriptors. This approach was evaluated via the identification of TPs of the triazole fungicide tebuconazole occurring in soil during a field dissipation study. Overall, 22 empirical and 12 yet unknown TPs were detected, and categorized into three groups with defined environmental properties. This approach combining suspect screening time-of-flight mass spectrometry with molecular typology could be extended to other organic pollutants and used to rationalize the choice of TPs to be investigated towards a more comprehensive environmental risk assessment scheme. - Highlights: • Combined method to detect and categorize pesticide transformation products in soil. • Detection by QTOF-MS of new tebuconazole transformation products without standards. • Estimation by in silico molecular typology of their environmental parameters. • Method to rationally choose relevant transformation products to be studied. • The

  7. Influence of Ceiling Suspended Screen Positioning to the Scatter Radiation Levels in Interventional Cardiology

    International Nuclear Information System (INIS)

    Arandjic, D.; Bozovic, P.; Ciraj-Bjelac, O.; Antic, V.

    2013-01-01

    The objective of this paper is to identify the effects of the ceiling suspended screen position to the scatter radiation levels in the interventional cardiology. The scatter radiation in terms of ambient dose equivalent H * (10) was measured for various positions of protective screen in the positions of the first operator, nurse and radiographer, at elevations 100-190 cm and in four different angulations of the x-ray tube. To assess the effectiveness of the protective screen, the scattered dose was also measured in the absence of any protection in all four angulations and elevations. To simulate real clinical situation the measurements were performed in the presence of 30 cm PMMA phantom using standard clinical protocol. The utility of protective screen varied for different positions and angulations. Scatter radiation levels varied in the range 70 - 3400 μSv/h for the first operator, 140 - 3200 μSv/h for the nurse and 50 - 560 μSv/h for radiographer. Ceiling suspended screens can provide a substantial level of protection (up to factor 18) in interventional cardiology, but they have to be properly managed and positioned to achieve sufficient level of protection. The guidance for optimal protection is provided in the paper.(author)

  8. Transfer mechanisms in cultivated soils of waste radionuclides from electronuclear power plants in the system river--irrigated soil--underground water level

    Energy Technology Data Exchange (ETDEWEB)

    Saas, A; Grauby, A

    1974-12-31

    From symposinm on environmentl behavior of radionuclides released in the nuclear industry; Aix-en-Provence, France (14 May 1973). The location of nuclear power plants by rivers whose waters are used for irrigation and industrial and domestic consumption necessities a profound study of the river-irrigated soil- ground water system. Mechanisms of radionuclide transport in cultivated soil are considered under three principal aspects: the effect of the quality of the river water, of the irrigation channels, and of the ground water level on the mobility of the radionuclides in the soil; the influence of the type of soil (the four types of soils considered are acid brown soil, calcic brown soil, chalky brown soil, and chalky alluvial soil); and the distribution of radionuclides in the soil (hydrosoluble forms can contminate the ground water level and these are the forms in which they are taken up by plants. A study was made on the following nuclides: /sup 22/Na, /sup 137/Cs, /sup 85/Sr, /Sup 54/Mn, /Sup 59/Fe, /Sup 60/ Co, /sup 65/Zn, /sup 124/Sb, /sup 141 in the cultivated soils permit the evaluation of the risks of contmination of the food chain and of the underground water. This study also showed new perspectives of the behavior of radionuclides as a function of their contmination of the organo-mineral wastes of industrial and domestic origin. This pollution interfers largely with the formation of stble complexes carried by the river to irrigated soils. The quality of the water determines the distribution of the radionuclides in the profile. The hydrosoluble complex persists in the soil and migrates toward the underground water level if they are not biodegradable. The stability of these forms as a function of the soil pH and of its physicochemical characteristics, as well as that of the radionuclides considered, permit the formulation of a new balance of the radionuclides in soils. The formulation of new proposals for the contml of nuclear sites is discussed. (tr-auth)

  9. The levels of uranium and thorium in soils and vegetables from Cornwall and Sutherland

    International Nuclear Information System (INIS)

    Nicholson, S.; Long, S.E.; McEwen, I.

    1990-02-01

    Soils from Sutherland and Cornwall may contain high natural levels of uranium and thorium. Samples of soil and vegetables were taken from agricultural land in these regions, and the levels of uranium and thorium were determined by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Delayed Neutron Activation Analysis (DNAA). Mean levels of uranium and thorium in the soils were, respectively, 3.5 times and 1.5 times greater than the British average. Uptake factors were calculated from these data and found to be of the order 10 -4 to 10 -3 which is in agreement with published literature. The Tessier extraction scheme was applied to some of the soils and the low levels present in the ''exchangeables'' fraction are consistent with the uptake factors. (author)

  10. Chemically modified carbon paste electrode for fast screening of oxalic acid levels in soil solutions

    Czech Academy of Sciences Publication Activity Database

    Šestáková, Ivana; Jakl, M.; Jaklová Dytrtová, J.

    2008-01-01

    Roč. 102, - (2008), s. 140-140 E-ISSN 1213-7103. [International Conference on Electroanalysis /12./. 16.06.2008-19.06.2008, Prague] R&D Projects: GA ČR GA521/06/0496 Institutional research plan: CEZ:AV0Z40400503 Keywords : oxalic acid * carbon paste electrodes * soil solutions Subject RIV: CG - Electrochemistry

  11. Radiation levels from computer monitor screens within Benue State ...

    African Journals Online (AJOL)

    Investigation of possible presence of soft X-ray levels from Computer Screens at distances of 0.5m and 1.0m was carried out within Benue State University, Makurdi, using ten different monitor models. Radiation measurement was carried out using a portable digital radiation meter, INSPECTOR 06250 (SE international Inc.

  12. An estimate of potential threats levels to soil biodiversity in EU

    NARCIS (Netherlands)

    Gardi, C.; Jeffery, S.L.; Saltelli, A.

    2013-01-01

    Life within the soil is vital for maintaining life on Earth due to the numerous ecosystem services that it provides. However, there is evidence that pressures on the soil biota are increasing which may undermine some of these ecosystem services. Current levels of belowground biodiversity are

  13. INJECTION TECHNOLOGY RESEARCH OF THE PROTECTIVE SCREEN

    Directory of Open Access Journals (Sweden)

    MENEJLYUK A. I.

    2016-12-01

    Full Text Available Formulation of the problem. This article contains information about the methods and the planning principles used in experimental research study of the injection technology of impervious screen. Today, there are ways to create impervious screens and curtains solve soil protection issues in the field impermeable layer arrangement at a shallow depth. However, for Ukraine, in the burial sites of radiation and other wastes is urgent issue of protection of underground space in places with deep impermeable layer. Classical methods can not fully solve such problems. To solve them, you need to develop innovative technology to create such a screen, which will lie authentic sole object to be protected, at the project depth. For the experiments, it is necessary to choose the most important indicator, and technological factors affecting it. This is due to the fact that the proposed technology provides for lesser known technical solutions, the use of which should ultimately result in impervious screens with desired properties. Goal. The aim of this study is the selection of technological parameters of injection, design of experiments and the selection of indicators characterizing the efficient operation of the screen. Such constructs must first have almost zero permeability. In this paper, it was of interest to study the influence of process parameters on the filtration rate of the protective screen. Conclusion. As a result of the design of experiments, the basic technological factors that have a significant effect on the studied parameters. varying levels of these factors are also identified, which in turn makes it possible to determine the optimum process parameters creating a screen that meets all the desired properties and characteristics. Based on a series of experiments it is possible to obtain optimal formulations for different types of soils.

  14. Stripping chronopotentiometric measurements of lead(II) and cadmium(II) in soils extracts and wastewaters using a bismuth film screen-printed electrode assembly

    Energy Technology Data Exchange (ETDEWEB)

    Kadara, Rashid O.; Tothill, Ibtisam E. [Cranfield Biotechnology Centre, Cranfield University, MK45 4DT, Silsoe, Bedfordshire (United Kingdom)

    2004-02-01

    The key to remediative processes is the ability to measure toxic contaminants on-site using simple and cheap sensing devices, which are field-portable and can facilitate more rapid decision-making. A three-electrode configuration system has been fabricated using low-cost screen-printing (thick-film) technology and this coupled with a portable electrochemical instrument has provided a a relatively inexpensive on-site detector for trace levels of toxic metals. The carbon surface of the screen-printed working electrode is used as a substrate for in situ deposition of a metallic film of bismuth, which allows the electrochemical preconcentration of metal ions. Lead and cadmium were simultaneously detected using stripping chronopotentiometry at the bismuth film electrode. Detection limits of 8 and 10 ppb were obtained for cadmium(II) and lead(II), respectively, for a deposition time of 120 s. The developed method was applied to the determination of lead and cadmium in soils extracts and wastewaters obtained from polluted sites. For comparison purposes, a mercury film electrode and ICP-MS were also used for validation. (orig.)

  15. Assessment of cobalt levels in wastewater, soil and vegetable ...

    African Journals Online (AJOL)

    User

    Key words: Cobalt level, Kubanni River, soil, vegetable, wastewater. INTRODUCTION. Cobalt is ... metals released into the environment from a variety of anthropogenic activities ..... Heavy Metal Stress in Plants, 2nd Edition,. Springer,. United.

  16. Proposal of a simple screening method for a rapid preliminary evaluation of ''heavy metals'' mobility in soils of contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    Pinto, Valentina; Chiusolo, Francesca; Cremisini, Carlo [ENEA - Italian Agency for New Technologies, Energy and Environment, Rome (Italy). Section PROTCHIM

    2010-09-15

    Risks associated to ''heavy metals'' (HM) soil contamination depend not only on their total content but, mostly, on their mobility. Many extraction procedures have been developed to evaluate HM mobility in contaminated soils, but they are generally time consuming (especially the sequential extraction procedures (SEPs)) and consequently applicable on a limited number of samples. For this reason, a simple screening method, applicable even ''in field'', has been proposed in order to obtain a rapid evaluation of HM mobility in polluted soils, mainly focused on the fraction associated to Fe and Mn oxide/hydroxides. A buffer solution of trisodium citrate and hydroxylamine hydrochloride was used as extractant for a single-step leaching test. The choice of this buffered solution was strictly related to the possibility of directly determining, via titration with dithizone (DZ), the content of Zn, Cu, Pb and Cd, which are among the most representative contaminants in highly mineralised soils. Moreover, the extraction solution is similar, aside from for the pH value, which is the one used in the BCR SEP second step. The analysis of bivalents ions through DZ titration was exploited in order to further simplify and quicken the whole procedure. The proposed method generically measures, in few minutes, the concentration of total extractable ''heavy metals'' expressed as molL{sup -1} without distinguishing between elements. The proposed screening method has been developed and applied on soil samples collected from rural, urban and mining areas, representing different situation of soil contamination. Results were compared with data obtained from the BCR procedure. The screening method demonstrated to be a reliable tool for a rapid evaluation of metals mobility. Therefore, it could be very useful, even ''in field'', both to guide the sampling activity on site and to monitor the efficacy of the subsequent

  17. Cervical cancer risk levels in Turkey and compliance to the national cervical cancer screening standard.

    Science.gov (United States)

    Açikgöz, Ayla; Ergör, Gül

    2011-01-01

    Cervical cancer screening with Pap smear test is a cost-effective method. The Ministry of Health in Turkey recommends that it be performed once every five years after age 35. The purpose of this study was to determine the cervical cancer risk levels of women between 35 and 69, and the intervals they have the Pap smear test, and to investigate the relation between the two. This study was performed on 227 women aged between 35 and 69 living in Balçova District of İzmir province. Using the cervical cancer risk index program of Harvard School of Public Health, the cervical cancer risk level of 70% of the women was found below average, 22.1% average, and 7.9% above average. Only 52% of the women have had Pap smear test at least once in their lives. The percentage screening regularly in conformity with the national screening standard was 39.2%. Women in the 40-49 age group, were married, conformed significantly more (pducation and decreased with the cervical cancer risk level (pducation level, menstruation state of the women and the economic level of the family. Not having the Pap smear test in conformity with the national cervical cancer screening standard in 35-39 age group was 2.52 times more than 40-49 age group, while it was 3.26 times more in 60-69 age group (pducation level might cause not having Pap smear test. Under these circumstances, the cervical cancer risk levels should be determined and the individuals should be informed. Providing Pap smear test screening service to individuals in the target group of national screening standard, as a public service may resolve the inequalities due to age and educational differences.

  18. Community- and family-level factors influence care-giver choice to screen blood lead levels of children in a mining community.

    Science.gov (United States)

    Moodie, S M; Tsui, E K; Silbergeld, E K

    2010-07-01

    Bunker Hill, in Kellogg, Idaho, formerly a lead mine (1884-1981) and smelter (1917-1981), is now a Superfund site listed on the Environmental Protection Agency's (EPA) National Priorities List. Lead contamination from the site is widespread due to past smelter discharges to land, water, and air, placing children at risk for both exposure to lead and resultant health effects of lead. Since 1983, the EPA has used child blood lead levels to inform the clean-up standards for the Bunker Hill Superfund site. This study was undertaken to examine factors that have contributed to the significant fall-off in the rates and numbers of children being screened for blood lead in Kellogg (number screened decreased from 195 to 8 from 2002 to 2007). The goal of this research project was to define community- and family-level factors which influence care-giver choice to screen blood lead levels of their children in this environment. This formative research study used mixed methods and was comprised of three research components: (1) preliminary interviews using community-based participatory research methods to define key research questions of relevance to community members, government and NGOs working in relation to the Bunker Hill clean-up; (2) a quantitative analysis of a cross-sectional household survey conducted with adult care-givers about child blood lead screening in Kellogg; and (3) ethnographic community rapid assessment methods formed the in-depth interview process and qualitative analysis. The survey showed the likelihood of blood lead screening that for children under the age of 18 years increases 34% with each one-year increase in current age of the child (95% CI, 1.08-1.67, p-value=0.009), and decreases 45% with annual household income greater than $10,000 (95% CI, 0.35-0.88, p-value=0.013). Sibling birth order increased the likelihood of blood lead screening by 61% (95% CI, 1.04-2.48, p-value=0.032) for each successive child. Female children were rated by their care

  19. Field demonstrations of passive detectors for screening of alpha contaminated soils

    International Nuclear Information System (INIS)

    Meyer, K.E.; Gammage, R.B.; Dudney, C.S.

    1994-01-01

    There are numerous sites around the country, DOE and otherwise, that are faced with the daunting task of remediating radiologically contaminated soils and groundwaters. Some of these sites, such as the Nevada Test Site and the Rocky Flats Plant, have contaminants that have been dispersed over wide areas. The costs of the characterization phase alone for such remediation programs can be prohibitive. Therefore there are pressing needs for testing and evaluation of new technologies for screening for radiological contaminants that may offer significant advantages in capital costs, ease of use, sensitivity, ruggedness, and/or reliability. This work reports on laboratory and Field tests of two types of passive alpha detectors, electret ionization chambers (EIC's) and alpha track detectors (ATD's), that have been commercially developed for indoor radon measurements. Previous work documented calibration and measurement protocols developed for these detectors for indoor surface contamination measurements

  20. Revised soil parameter estimates for the soil types of the world

    NARCIS (Netherlands)

    Batjes, N.H.

    2002-01-01

    A revised set of physical and chemical parameter estimates is presented for the soil units of the world, as described by the two FAO soil legends (version 1974 and 1988). The study is based on 9607 soil profiles, which include profiles held in version 1.0 of the WISE database. Upon a screening of

  1. Characterization of Soil Moisture Level for Rice and Maize Crops using GSM Shield and Arduino Microcontroller

    Science.gov (United States)

    Gines, G. A.; Bea, J. G.; Palaoag, T. D.

    2018-03-01

    Soil serves a medium for plants growth. One factor that affects soil moisture is drought. Drought has been a major cause of agricultural disaster. Agricultural drought is said to occur when soil moisture is insufficient to meet crop water requirements, resulting in yield losses. In this research, it aimed to characterize soil moisture level for Rice and Maize Crops using Arduino and applying fuzzy logic. System architecture for soil moisture sensor and water pump were the basis in developing the equipment. The data gathered was characterized by applying fuzzy logic. Based on the results, applying fuzzy logic in validating the characterization of soil moisture level for Rice and Maize crops is accurate as attested by the experts. This will help the farmers in monitoring the soil moisture level of the Rice and Maize crops.

  2. Airborne exposure and soil levels associated with lead abatement of a steel tank.

    Science.gov (United States)

    Lange, John H

    2002-02-01

    This study reports on airborne exposure levels and soil concentrations of lead in regard to abatement of a steel structure (water tank). The tank was de-leaded by abrasive sand blasting. The ball of the tank had a lead surface level that exceeded the Environmental Protection Agency (EPA) definition of lead-based paint (LBP) (0.5% lead), but paint on stem and base was below this criterion. Personal and area airborne samples were collected during different activities of lead abatement of the tank. Summary results suggest during abrasive blasting of ball and stem/base personal exposure levels, as reported with arithmetic and geometric means, exceed the Occupational Safety and Health Administration (OSHA) permissible exposure limit (50 microg/m3). Highest personal exposure (occupational exposure) was associated with blasting of ball. Distribution of airborne and soil samples suggest non-normality and is best represented by a logarithmic form. Geometric standard deviations for air and soil lead support a non-normal distribution. Outlying values were found for personal and area air samples. Exposure levels associated with blasting stem/base section of tank support OSHA's policy requiring air monitoring of work at levels below the criterion established by EPA in identifying LBP. Area samples were statistically lower than personal samples associated with blasting ball and stem/base of tank. Exposure data suggest that workers performing abatement on steel structures have elevated lead exposure from surface lead. Respirator protection requirements are discussed. Soil lead concentration was suggested to decrease as distance increased from tank. Soil lead is suggested to be a result of deposition from LBP on tank surface. Minimal efforts were required to reduce average lead soil levels below EPA's upper acceptable criterion (1200 ppm Pb).

  3. Assessment of human health risk of reported soil levels of metals and radionuclides in Port Hope

    International Nuclear Information System (INIS)

    1991-11-01

    Risk assessment methods are applied to the question of health implications of contaminated soil in the Port Hope area. Soil-related as well as other pathways of exposure are considered. Exposures to the reported levels of uranium, antimony, chromium, copper, nickel, cadmium, cobalt, selenium, and zinc in Port Hope soils are not expected to result in adverse health consequences. Oral exposure to arsenic in soil at the reported levels is estimated to result in incremental cancer risk levels in the negligible range (10 -5 ). Estimated exposures also fall well below suggested toxic thresholds for arsenic. For the two small areas within the >50 μg/g isopleth, assessment of exposure is difficult without more definitive data on soil concentrations in these zones. Contamination of soils with lead is overall quite limited. In general, the reported soil levels of lead are not anticipated to pose a hazard. The site with the highest concentrations of lead is located on the west bank of the Ganaraska River, a popular fishing area. Depending on the level and extent of contamination, as well as degree of contact with the site, potential exposures could exceed tolerable intakes for children. Exposures to the radionuclides Ra(226), Pb(210), and U(238) in soil at the reported levels are estimated to fall well within recommended population limits

  4. Critical level of radionuclides pollution estimation for different soil type of Ukrainian Polessye

    International Nuclear Information System (INIS)

    Kravets, A.; Pavlenko, Y.

    1996-01-01

    The successive development and adaptation of general algorithm of calculation of doses from intake 137 Cs and 90 Sr as a function of pollution level and a type of soil as a source of the human trophycal chains and its use in solution of reverse problem, namely- estimation of the critical level of radionuclides pollution for the main type of soil of Ukrainian Polessye has been proposed. Calculation was realized as a combination of dynamic model of migration of radionuclides in soil and spreadsheet form with Quattro Pro, version 4.0. (author)

  5. Spectral reflectance characteristics of soils in northeastern Brazil as influenced by salinity levels.

    Science.gov (United States)

    Pessoa, Luiz Guilherme Medeiros; Freire, Maria Betânia Galvão Dos Santos; Wilcox, Bradford Paul; Green, Colleen Heather Machado; De Araújo, Rômulo José Tolêdo; De Araújo Filho, José Coelho

    2016-11-01

    In northeastern Brazil, large swaths of once-productive soils have been severely degraded by soil salinization, but the true extent of the damage has not been assessed. Emerging remote sensing technology based on hyperspectral analysis offers one possibility for large-scale assessment, but it has been unclear to what extent the spectral properties of soils are related to salinity characteristics. The purpose of this study was to characterize the spectral properties of degraded (saline) and non-degraded agricultural soils in northeastern Brazil and determine the extent to which these properties correspond to soil salinity. We took soil samples from 78 locations within a 45,000-km 2 site in Pernambuco State. We used cluster analysis to group the soil samples on the basis of similarities in salinity and sodicity levels, and then obtained spectral data for each group. The physical properties analysis indicated a predominance of the coarse sand fraction in almost all the soil groups, and total porosity was similar for all the groups. The chemical analysis revealed different levels of degradation among the groups, ranging from non-degraded to strongly degraded conditions, as defined by the degree of salinity and sodicity. The soil properties showing the highest correlation with spectral reflectance were the exchangeable sodium percentage followed by fine sand. Differences in the reflectance curves for the various soil groups were relatively small and were not significant. These results suggest that, where soil crusts are not present, significant challenges remain for using hyperspectral remote sensing to assess soil salinity in northeastern Brazil.

  6. Do soil organic carbon levels affect potential yields and nitrogen use efficiency?

    DEFF Research Database (Denmark)

    Oelofse, Myles; Markussen, Bo; Knudsen, Leif

    2015-01-01

    Soil organic carbon (SOC) is broadly recognised as an important parameter affecting soil quality, and can therefore contribute to improving a number of soil properties that influence crop yield. Previous research generally indicates that soil organic carbon has positive effects on crop yields......, the yield with no fertiliser N application and the N use efficiency would be positively affected by SOC level. A statistical model was developed to explore relationships between SOC and potential yield, yields at zero N application and N use efficiency (NUE). The model included a variety of variables...

  7. Risk assessment of soil contamination criteria

    International Nuclear Information System (INIS)

    King, C.M.; Marter, W.L.; Montaque, D.F.; Holton, G.A.

    1987-06-01

    Criteria have been developed to select radioactive and nonradioactive contaminants at waste sites detailed analysis and risk assessment. These criteria were based on soil and water quality guidelines developed by various government agencies to determine if the criteria were appropriate. We performed a risk assessment of a hypothetical site which contained radioactive and nonradioactive contaminants at levels equal to the criteria values. Risks to the public from atmospheric, surface water, and groundwater exposure pathways were examined. Health risks to the public from atmospheric releases of radioactive and nonradioactive materials from a waste at soil criteria contamination levels are low. Health risks to the maximally exposed individual to chemical carcinogens are considerably below traditional EPA action levels. And health risks to the maximally exposed individual to atmospherically released radioactive contaminants is 1.88 x 10 -7 , more than a factor of 5 less than 10 -6 . Based on our atmospheric exposure pathways analysis and risk assessment, the applied soil criteria are appropriate for screening out unimportant risk contributors to human health from atmospheric exposure pathways. 13 refs., 3 figs., 7 tabs

  8. Isolation and Screening of Potential Cellulolytic and Xylanolytic Bacteria from Soil Sample for Degradation of Lignocellulosic Biomass

    Directory of Open Access Journals (Sweden)

    Bhupal Govinda Shrestha

    2016-11-01

    them with the aptitude to produce stable enzymes, little emphasis has been given to cellulose/xylanase production from bacteria. Seven soil samples were collected from eastern hilly districts of Nepal viz. Taplejung, Panchthar and Sankhuwasabha districts, from soil surface and at depth of 10cm to 20cm, and were isolated separately. From the seven soil samples, four bacterial isolates were obtained. Isolates (PSS, P1D, TLC, SNK were then screened for cellulolytic/xylanolytic activity using Congo red assay on Carboxymethylcellulose (CMC/xylan agar plates. The enzyme activity obtained from isolates was dependent on substrate concentration. The activity of enzymes produced by isolates were also measured and compared on pretreated sugarcane bagasse. Among those samples, the greatest zone of inhibition in both CMC (1.3 cm and xylan (1.0 cm agar media was seen in isolate P1D. It also produced the highest activity of endoglucanase and xylanase i.e. activity 0.035 U/mL and 0.050 U/mL respectively at 0.010 mg mL-1 standard substrate concentration of CMC and xylan.

  9. A study of radon levels in the soil of Nasir's College of Agriculture - Yemen

    International Nuclear Information System (INIS)

    Ali, Taher M.; Ahmed, Hayel A.; Zumalian, Abubaker A.

    2000-01-01

    The radon diffusion in the atmosphere and dwelling interior comes from one source, it is the soil. Emitting alpha particles, radon daughters may be deposited in to the lungs and cause health hazards, so for this reason, estimation of radon levels in soil and dwelling were done in may countries. in the present work, we have used the passive dosimeters (SSNTD s ) containing (Cr-39) detectors. The dosimeters were distributed at the surface of the ground, in the soil horizontally (at depth 50 cm) and in soil with depth. The overall mean for radon levels in soil horizontally was (1.28 ± 0.05) KBq/m 3 and the mean radon concentration at the surface of the ground was (0.42 ± 0.03) KBq/m 3 . It is found that radon concentration increases as the depth increases up to (90 cm) depth after that radon levels decrease as the depth increases. (author)

  10. Wetland Ecohydrology: stochastic description of water level fluctuations across the soil surface

    Science.gov (United States)

    Tamea, S.; Muneepeerakul, R.; Laio, F.; Ridolfi, L.; Rodriguez-Iturbe, I.

    2009-12-01

    Wetlands provide a suite of social and ecological critical functions such as being habitats of disease-carrying vectors, providing buffer zones against hurricanes, controlling sediment transport, filtering nutrients and contaminants, and a repository of great biological diversity. More recently, wetlands have also been recognized as crucial for carbon storage in the context of global climate change. Despite such importance, quantitative approaches to many aspects of wetlands are far from adequate. Therefore, improving our quantitative understanding of wetlands is necessary to our ability to maintain, manage, and restore these invaluable environments. In wetlands, hydrologic factors and ecosystem processes interplay and generate unique characteristics and a delicate balance between biotic and abiotic elements. The main hydrologic driver of wetland ecosystems is the position of the water level that, being above or below ground, determines the submergence or exposure of soil. When the water level is above the soil surface, soil saturation and lack of oxygen causes hypoxia, anaerobic functioning of microorganisms and anoxic stress in plants, that might lead to the death of non-adapted organisms. When the water level lies below the soil surface, the ecosystem becomes groundwater-dependent, and pedological and physiological aspects play their role in the soil water balance. We propose here a quantitative description of wetland ecohydrology, through a stochastic process-based water balance, driven by a marked compound Poisson noise representing rainfall events. The model includes processes such as rainfall infiltration, evapotranspiration, capillary rise, and the contribution of external water bodies, which are quantified in a simple yet realistic way. The semi-analytical steady-state probability distributions of water level spanning across the soil surface are validated with data from the Everglades (Florida, USA). The model and its results allow for a quantitative

  11. Responses of Water and Salt Parameters to Groundwater Levels for Soil Columns Planted with Tamarix chinensis

    Science.gov (United States)

    Xia, Jiangbao; Zhao, Ximei; Chen, Yinping; Fang, Ying; Zhao, Ziguo

    2016-01-01

    Groundwater is the main water resource for plant growth and development in the saline soil of the Yellow River Delta in China. To investigate the variabilities and distributions of soil water and salt contents at various groundwater level (GL), soil columns with planting Tamarix chinensis Lour were established at six different GL. The results demonstrated the following: With increasing GL, the relative soil water content (RWC) declined significantly, whereas the salt content (SC) and absolute soil solution concentration (CS) decreased after the initial increase in the different soil profiles. A GL of 1.2 m was the turning point for variations in the soil water and salt contents, and it represented the highest GL that could maintain the soil surface moist within the soil columns. Both the SC and CS reached the maximum levels in these different soil profiles at a GL of 1.2 m. With the raise of soil depth, the RWC increased significantly, whereas the SC increased after an initial decrease. The mean SC values reached 0.96% in the top soil layer; however, the rates at which the CS and RWC decreased with the GL were significantly reduced. The RWC and SC presented the greatest variations at the medium (0.9–1.2 m) and shallow water levels (0.6 m) respectively, whereas the CS presented the greatest variation at the deep water level (1.5–1.8 m).The RWC, SC and CS in the soil columns were all closely related to the GL. However, the correlations among the parameters varied greatly within different soil profiles, and the most accurate predictions of the GL were derived from the RWC in the shallow soil layer or the SC in the top soil layer. A GL at 1.5–1.8 m was moderate for planting T. chinensis seedlings under saline groundwater conditions. PMID:26730602

  12. Responses of Water and Salt Parameters to Groundwater Levels for Soil Columns Planted with Tamarix chinensis.

    Science.gov (United States)

    Xia, Jiangbao; Zhao, Ximei; Chen, Yinping; Fang, Ying; Zhao, Ziguo

    2016-01-01

    Groundwater is the main water resource for plant growth and development in the saline soil of the Yellow River Delta in China. To investigate the variabilities and distributions of soil water and salt contents at various groundwater level (GL), soil columns with planting Tamarix chinensis Lour were established at six different GL. The results demonstrated the following: With increasing GL, the relative soil water content (RWC) declined significantly, whereas the salt content (SC) and absolute soil solution concentration (CS) decreased after the initial increase in the different soil profiles. A GL of 1.2 m was the turning point for variations in the soil water and salt contents, and it represented the highest GL that could maintain the soil surface moist within the soil columns. Both the SC and CS reached the maximum levels in these different soil profiles at a GL of 1.2 m. With the raise of soil depth, the RWC increased significantly, whereas the SC increased after an initial decrease. The mean SC values reached 0.96% in the top soil layer; however, the rates at which the CS and RWC decreased with the GL were significantly reduced. The RWC and SC presented the greatest variations at the medium (0.9-1.2 m) and shallow water levels (0.6 m) respectively, whereas the CS presented the greatest variation at the deep water level (1.5-1.8 m).The RWC, SC and CS in the soil columns were all closely related to the GL. However, the correlations among the parameters varied greatly within different soil profiles, and the most accurate predictions of the GL were derived from the RWC in the shallow soil layer or the SC in the top soil layer. A GL at 1.5-1.8 m was moderate for planting T. chinensis seedlings under saline groundwater conditions.

  13. Responses of Water and Salt Parameters to Groundwater Levels for Soil Columns Planted with Tamarix chinensis.

    Directory of Open Access Journals (Sweden)

    Jiangbao Xia

    Full Text Available Groundwater is the main water resource for plant growth and development in the saline soil of the Yellow River Delta in China. To investigate the variabilities and distributions of soil water and salt contents at various groundwater level (GL, soil columns with planting Tamarix chinensis Lour were established at six different GL. The results demonstrated the following: With increasing GL, the relative soil water content (RWC declined significantly, whereas the salt content (SC and absolute soil solution concentration (CS decreased after the initial increase in the different soil profiles. A GL of 1.2 m was the turning point for variations in the soil water and salt contents, and it represented the highest GL that could maintain the soil surface moist within the soil columns. Both the SC and CS reached the maximum levels in these different soil profiles at a GL of 1.2 m. With the raise of soil depth, the RWC increased significantly, whereas the SC increased after an initial decrease. The mean SC values reached 0.96% in the top soil layer; however, the rates at which the CS and RWC decreased with the GL were significantly reduced. The RWC and SC presented the greatest variations at the medium (0.9-1.2 m and shallow water levels (0.6 m respectively, whereas the CS presented the greatest variation at the deep water level (1.5-1.8 m.The RWC, SC and CS in the soil columns were all closely related to the GL. However, the correlations among the parameters varied greatly within different soil profiles, and the most accurate predictions of the GL were derived from the RWC in the shallow soil layer or the SC in the top soil layer. A GL at 1.5-1.8 m was moderate for planting T. chinensis seedlings under saline groundwater conditions.

  14. Statewide screening for low-level radioactive waste shallow land burial sites

    International Nuclear Information System (INIS)

    Staub, W.P.; Cannon, J.B.; Stratton, L.E.

    1984-01-01

    A methodology was developed for statewide low-level waste site screening based on NRC site selection criteria. The methodology and criteria were tested in Tennessee to determine their effectiveness in narrowing the choice of sites for more intensive localized site screening. The statewide screening methodology entailed two steps. The first step was to select one or more physiographic provinces wherein sites meeting the criteria were most likely to be found. The second step was to select one or more suitable outcrop bands from within the most favorable physiographic provinces. These selections were based entirely on examination of existing literature and maps at scales no larger than 1:250,000. The statewide screening project identified only one suitable physiographic province (the Mississippi Embayment region) and one favorable outcrop band (the Coon Creek Formation) within a three county area of western Tennessee. Ground water monitoring and predictability proved to be the most difficult criterion to meet. This criterion alone eliminated other outcrop bands in the Mississippi Embayment as well as the Eastern Highland Rim and Western Highland Rim physiographic provinces. Other provinces failed to meet several screening criteria. 3 references, 3 figures, 1 table

  15. Role of extrinsic arbuscular mycorrhizal fungi in heavy metal-contaminated wetlands with various soil moisture levels.

    Science.gov (United States)

    Zheng, S; Wang, C; Shen, Z; Quan, Y; Liu, X

    2015-01-01

    This study presents an efficient heavy metal (HM) control method in HM-contaminated wetlands with varied soil moisture levels through the introduction of extrinsic arbuscular mycorrhizal fungi (AMF) into natural wetland soil containing indigenous AMF species. A pot culture experiment was designed to determine the effect of two soil water contents (5-8% and 25-30%), five extrinsic AMF inoculants (Glomus mosseae, G. clarum, G. claroideum, G. etunicatum, and G. intraradices), and HM contamination on root colonization, plant growth, and element uptake of common reed (Phragmites australis (Cav.) Trin. ex Steudel) plantlets in wetland soils. This study showed the prevalence of mycorrhizae in the roots of all P. australis plantlets, regardless of extrinsic AMF inoculations, varied soil moisture or HM levels. It seems that different extrinsic AMF inoculations effectively lowered HM concentrations in the aboveground tissues of P. australis at two soil moisture levels. However, metal species, metal concentrations, and soil moisture should also be very important factors influencing the elemental uptake performance of plants in wetland ecosystems. Besides, the soil moisture level significantly influenced plant growth (including height, and shoot and root dry weight (DW)), and extrinsic AMF inoculations differently affected shoot DW.

  16. Optimal screening interval for men with low baseline prostate-specific antigen levels (≤1.0 ng/mL) in a prostate cancer screening program.

    Science.gov (United States)

    Urata, Satoko; Kitagawa, Yasuhide; Matsuyama, Satoko; Naito, Renato; Yasuda, Kenji; Mizokami, Atsushi; Namiki, Mikio

    2017-04-01

    To optimize the rescreening schedule for men with low baseline prostate-specific antigen (PSA) levels, we evaluated men with baseline PSA levels of ≤1.0 ng/mL in PSA-based population screening. We enrolled 8086 men aged 55-69 years with baseline PSA levels of ≤1.0 ng/mL, who were screened annually. The relationships of baseline PSA and age with the cumulative risks and clinicopathological features of screening-detected cancer were investigated. Among the 8086 participants, 28 (0.35 %) and 18 (0.22 %) were diagnosed with prostate cancer and cancer with a Gleason score (GS) of ≥7 during the observation period, respectively. The cumulative probabilities of prostate cancer at 12 years were 0.42, 1.0, 3.4, and 4.3 % in men with baseline PSA levels of 0.0-0.4, 0.5-0.6, 0.7-0.8, and 0.9-1.0 ng/mL, respectively. Those with GS of ≥7 had cumulative probabilities of 0.42, 0.73, 2.8, and 1.9 %, respectively. The cumulative probabilities of prostate cancer were significantly lower when baseline PSA levels were 0.0-0.6 ng/mL compared with 0.7-1.0 ng/mL. Prostate cancer with a GS of ≥7 was not detected during the first 10 years of screening when baseline PSA levels were 0.0-0.6 ng/mL and was not detected during the first 2 years when baseline PSA levels were 0.7-1.0 ng/mL. Our study demonstrated that men with baseline PSA levels of 0.0-0.6 ng/mL might benefit from longer screening intervals than those recommended in the guidelines of the Japanese Urological Association. Further investigation is needed to confirm the optimal screening interval for men with low baseline PSA levels.

  17. Phosphorus critical levels and availability in lowland soils cultivated with flooded rice

    Directory of Open Access Journals (Sweden)

    Mariano Isabela Orlando dos Santos

    2002-01-01

    Full Text Available Lowland soils present a great potential for the flooded rice crop. This work aimed to estimate critical levels of P in waterlogged soils cultivated with rice using Mehlich 1 and anion exchange resin as soil-P extractors, compare the performance of these extractors as for the evaluation of the P availability, and study the soil-P fractions involved in the P nutrition of the rice crop. Studied soils consisted of four Histosols: Low Humic Gley (GP, Aluvial (A, Humic Gley (GH and Bog Soil (O which were previously cultivated with beans. The experimental design was completely randomized, in a factorial scheme, using four soils, five P rates (75, 150, 300, 500 and 800 mg dm-3 and two liming treatments (with and without liming, with three replicates. After 60 days of flooding, soil samples were submitted to P extraction by Mehlich 1 and resin, and phosphorous fractionation. Two rice plants were cultivated in pots containing 3 dm³ of waterlogged soils. The labile P and the moderately labile P of the soils contributed for rice nutrition. The two tested extractors presented efficiency in the evaluation of P availability for the rice cultivated in lowland waterlogged soils.

  18. Determination of lead levels in roadside soil and plants in Damascus city

    International Nuclear Information System (INIS)

    Othman, I; Al-Oudat, M.; Al-Masri, M.S.

    1997-04-01

    Seasonal variations of lead concentration in roadside soils and plants in 12 sites in Damascus city have been investigated. Lead concentrations in soil were found to be varied from 78.4 ppm to 832 ppm; lower levels in the wet period than in the dry period were observed. While lead levels in roadside plants varied between 3.39 ppm to 13.28 ppm. The results have also shown that most of the vegetables grown on the roadside of Damascus city have high concentrations of lead and the normal washing does not decrease it to unacceptable level. (author). 15 refs., 9 tabs

  19. Scenario-targeted toxicity assessment through multiple endpoint bioassays in a soil posing unacceptable environmental risk according to regulatory screening values.

    Science.gov (United States)

    Rodriguez-Ruiz, A; Etxebarria, J; Boatti, L; Marigómez, I

    2015-09-01

    Lanestosa is a chronically polluted site (derelict mine) where the soil (Lanestosa (LA) soil) exceeds screening values (SVs) of regulatory policies in force (Basque Country; Europe) for Zn, Pb and Cd. A scenario-targeted toxicity assessment was carried out on the basis of a multi-endpoint bioassay approach. Acute and chronic toxicity bioassays were conducted with selected test species (Vibrio fischeri, Dictyostelium discoideum, Lactuca sativa, Raphanus sativus and Eisenia fetida) in combination with chemical analysis of soils and elutriates and with bioaccumulation studies in earthworms. Besides, the toxicity profile was compared with that of the mine runoff (RO) soil and of a fresh artificially polluted soil (LAAPS) resembling LA soil pollutant profile. Extractability studies in LA soil revealed that Pb, Zn and Cd were highly available for exchange and/or release into the environment. Indeed, Pb and Zn were accumulated in earthworms and LA soil resulted to be toxic. Soil respiration, V. fischeri, vegetative and developmental cycles of D. discoideum and survival and juvenile production of E. fetida were severely affected. These results confirmed that LA soil had unacceptable environmental risk and demanded intervention. In contrast, although Pb and Zn concentrations in RO soil revealed also unacceptable risk, both metal extractability and toxicity were much lower than in LA soil. Thus, within the polluted site, the need for intervention varied between areas that posed dissimilar risk. Besides, since LAAPS, with a high exchangeable metal fraction, was the most toxic, ageing under in situ natural conditions seemingly contributed to attenuate LA soil risk. As a whole, combining multi-endpoint bioassays with scenario-targeted analysis (including leaching and ageing) provides reliable risk assessment in soils posing unacceptable environmental risk according to SVs, which is useful to optimise the required intervention measures.

  20. Use of screening action levels in risk management at Los Alamos National Laboratory

    International Nuclear Information System (INIS)

    Beck, J.R.; Hueske, K.L.; Dorries, A.M.

    1994-01-01

    The screening assessment approach used at Los Alamos National Laboratory has proved to be a valuable risk management tool in making decisions that are cost-effective, efficient, and defensible. Los Alamos has successfully used screening action levels to prioritize RFI activities, streamline data evaluation, and insure analytical methods are adequately sensitive to be protective of human health

  1. Radioactivity level of soil around Baqiao coal-fired power plant in China

    International Nuclear Information System (INIS)

    Lu, Xinwei; Zhao, Caifeng; Chen, Cancan; Liu, Wen

    2012-01-01

    Natural radioactivity level of soil around Baqiao coal-fired power plant in China was determined using gamma ray spectrometry. The concentrations of 226 Ra, 232 Th and 40 K in the studied soil samples range from 27.6 to 48.8, 44.4 to 61.4 and 640.2 to 992.2 Bq kg −1 with an average of 36.1, 51.1 and 733.9 Bq kg −1 , respectively, which are slightly higher than the average values of Shaanxi soil. The radium equivalent activity, the air absorbed dose rate and the annual effective dose rate were calculated and compared with the internationally reported or reference values. The radium equivalent activities of the studied samples are below the internationally accepted values. The air absorbed dose rate and the annual effective dose rate received by the local residents due to the natural radionuclides in soil are slightly higher than the mean value of Xi'an and worldwide. - Highlights: ► Natural radioactivity in soil around the coal-fired power plant was determined. ► Radiological parameters were used to assess radiation hazard. ► The coal-fired power plant has affected the local radioactivity level.

  2. Copper and lead levels in crops and soils of the Holland Marsh Area-Ontario

    Energy Technology Data Exchange (ETDEWEB)

    Czuba, M.; Hutchinson, T.C.

    1980-01-01

    A study was made of the occurrence, distribution, and concentrations of the heavy metals copper (Cu) and lead (Pb) in the soils and crops of the important horticultural area north of Toronto known as the Holland Marsh. The soils are deep organic mucks (> 85% organic matter), derived by the drainage of black marshland soils, which has been carried out over the past 40 years. A comparison is made between the Pb and Cu concentrations in undrained, uncultivated areas of the marsh and in the intensively used horticultural area. Analyses show a marked accumulation of Cu in surface layers of cultivated soils, with a mean surface concentration of 130 ppM, declining to 20 ppM at a 32-cm depth. Undrained (virgin) soils of the same marshes had < 20 ppM at all depths. Lead concentrations also declined through the profile, from concentrations of 22 to 10 ppM. In comparison, undrained areas had elevated Pb levels. Cultivation appeared to have increased Cu, but lowered Pb in the marsh. Copper and lead levels found in the crops were generally higher in the young spring vegetables than in the mature fall ones. Leafy crops, especially lettuce (Lactuca L.) and celery (Apium graveolens), accumulated higher Pb levels in their foliage compared with levels in root crops. Cultivation procedures, including past pesticide applications and fertilizer additions, appeared to be principal sources of Cu. Mobility from the soil and into the plant for these elements in the marsh muck soils is discussed.

  3. State-level differences in breast and cervical cancer screening by disability status: United States, 2008.

    Science.gov (United States)

    Armour, Brian S; Thierry, JoAnn M; Wolf, Lesley A

    2009-01-01

    Despite reported disparities in the use of preventive services by disability status, there has been no national surveillance of breast and cervical cancer screening among women with disabilities in the United States. To address this, we used state-level surveillance data to identify disparities in breast and cervical cancer screening among women by disability status. Data from the 2008 Behavioral Risk Factor Surveillance System were used to estimate disability prevalence and state-level differences in breast and cervical cancer screening among women by disability status. Overall, modest differences in breast cancer screening were found; women with a disability were less likely than those without to report receiving a mammogram during the past 2 years (72.2% vs. 77.8%; p < .001). However, disparities in breast cancer screening were more pronounced at the state level. Furthermore, women with a disability were less likely than those without a disability to report receiving a Pap test during the past 3 years (78.9% vs. 83.4%; p < .001). This epidemiologic evidence identifies an opportunity for federal and state programs, as well as other stakeholders, to form partnerships to align disability and women's health policies. Furthermore, it identifies the need for increased public awareness and resource allocation to reduce barriers to breast and cervical cancer screening experienced by women with disabilities.

  4. Levels and patterns of polycyclic aromatic hydrocarbons (PAHs) in soils after forest fires in South Korea.

    Science.gov (United States)

    Kim, Eun Jung; Choi, Sung-Deuk; Chang, Yoon-Seok

    2011-11-01

    To investigate the influence of biomass burning on the levels of polycyclic aromatic hydrocarbons (PAHs) in soils, temporal trends and profiles of 16 US Environmental Protection Agency priority PAHs were studied in soil and ash samples collected 1, 5, and 9 months after forest fires in South Korea. The levels of PAHs in the burnt soils 1 month after the forest fires (mean, 1,200 ng/g dry weight) were comparable with those of contaminated urban soils. However, 5 and 9 months after the forest fires, these levels decreased considerably to those of general forest soils (206 and 302 ng/g, respectively). The burnt soils and ash were characterized by higher levels of light PAHs with two to four rings, reflecting direct emissions from biomass burning. Five and 9 months after the forest fires, the presence of naphthalene decreased considerably, which indicates that light PAHs were rapidly volatilized or degraded from the burnt soils. The temporal trend and pattern of PAHs clearly suggests that soils in the forest-fire region can be contaminated by PAHs directly emitted from biomass burning. However, the fire-affected soils can return to the pre-fire conditions over time through the washout and wind dissipation of the ash with high content of PAHs as well as vaporization or degradation of light PAHs.

  5. Toxicity of Selenium, Weathered and Aged in Soil, to the Collembolan Folsomia candida

    Science.gov (United States)

    2016-07-01

    Roman G. Kuperman Ronald T. Checkai Michael Simini Carlton T. Phillips RESEARCH AND TECHNOLOGY DIRECTORATE Richard M. Higashi Teresa W...ecotoxicological benchmarks for developing the ecological soil screening levels ( Eco -SSLs) for risk assessments of contaminated soils. For this study, we...benchmarks established in this study were submitted to the U.S. Environmental Protection Agency Eco -SSL Workgroup, and the EC20 value was used in

  6. A Population-Level Data Analytics Portal for Self-Administered Lifestyle and Mental Health Screening.

    Science.gov (United States)

    Zhang, Xindi; Warren, Jim; Corter, Arden; Goodyear-Smith, Felicity

    2016-01-01

    This paper describes development of a prototype data analytics portal for analysis of accumulated screening results from eCHAT (electronic Case-finding and Help Assessment Tool). eCHAT allows individuals to conduct a self-administered lifestyle and mental health screening assessment, with usage to date chiefly in the context of primary care waiting rooms. The intention is for wide roll-out to primary care clinics, including secondary school based clinics, resulting in the accumulation of population-level data. Data from a field trial of eCHAT with sexual health questions tailored to youth were used to support design of a data analytics portal for population-level data. The design process included user personas and scenarios, screen prototyping and a simulator for generating large-scale data sets. The prototype demonstrates the promise of wide-scale self-administered screening data to support a range of users including practice managers, clinical directors and health policy analysts.

  7. Air-soil exchange of PCBs: levels and temporal variations at two sites in Turkey.

    Science.gov (United States)

    Yolsal, Didem; Salihoglu, Güray; Tasdemir, Yücel

    2014-03-01

    Seasonal distribution of polychlorinated biphenyls (PCBs) at the air-soil intersection was determined for two regions: one with urban characteristics where traffic is dense (BUTAL) and the other representing the coastal zone (Mudanya). Fifty-one air and soil samples were simultaneously collected. Total PCB (Σ82 PCB) levels in the soil samples collected during a 1-year period ranged between 105 and 7,060 pg/g dry matter (dm) (BUTAL) and 110 and 2,320 pg/g dm (Mudanya). Total PCB levels in the gaseous phase were measured to be between 100 and 910 pg/m(3) (BUTAL) and 75 and 1,025 pg/m(3) (Mudanya). Variations in the concentrations were observed depending on the season. Though the PCB concentrations measured in the atmospheres of both regions in the summer months were high, they were found to be lower in winter. However, while soil PCB levels were measured to be high at BUTAL during summer months, they were found to be high during winter months in Mudanya. The direction and amount of the PCB movement were determined by calculating the gaseous phase change fluxes at air-soil intersection. While a general PCB movement from soil to air was found for BUTAL, the PCB movement from air to soil was calculated for the Mudanya region in most of the sampling events. During the warmer seasons PCB movement towards the atmosphere was observed due to evaporation from the soil. With decreases in the temperature, both decreases in the number of PCB congeners occurring in the air and a change in the direction of some congeners were observed, possibly caused by deposition from the atmosphere to the soil. 3-CB and 4-CB congeners were found to be dominant in the atmosphere, and 4-, 5-, and 6-CBs were found to dominate in the surface soils.

  8. Radon-in-soil concentration levels in Mexico

    International Nuclear Information System (INIS)

    Segovia, N.; Tamez, E.; Mena, M.

    1992-01-01

    Radon-in-soil surveys in Mexico have been carried out since 1974 both for uranium prospecting and to correlate mean values of the gas emanation with local telluric behaviour. The mapping covers the northern uranium mining region, the Mexican Neovolcanic Belt, the coastal areas adjacent to the zone of subduction of the Cocos Plate under the North American Plate, some of the active volcanoes of Southern Mexico and several sedimentary valleys in Central Mexico. Recording of 222 Rn alpha decay is systematically performed with LR115 track detectors. Using mean values averaged over different observation periods at fixed monitoring stations, a radon-in-soil map covering one third of the territory of Mexico is presented. The lowest mean values occur in areas associated with active volcanoes. The highest levels are found in uranium ore zones. Intermediate values are obtained in regions with enhanced hydrothermal activity and stations associated with intrusive rocks. (author)

  9. Radon in soil concentration levels in Mexico

    International Nuclear Information System (INIS)

    Segovia, N.; Tamez, E.; Mena, M.

    1991-09-01

    Radon in soil surveys in Mexico have been carried out since 1974 both for uranium prospectus and to correlate mean values of the gas emanation with local telluric behaviour. The mapping includes the northern uranium mining region, the Mexican Neo volcanic Belt, the coastal areas adjacent to the zone of subduction of the Cocos Plate under the North American Plate, some of the active volcanoes of Southern Mexico and several sedimentary valleys in Central Mexico. Recording of 222 Rn alpha decay is systematically performed with LR115 track detectors. Using mean values averaged over different observation periods at fixed monitoring stations, a radon in soil map covering one third of the Mexican territory is presented. The lowest mean values have been found in areas associated with active volcanoes. The highest levels are found in uranium ore zones. Intermediate values are obtained in regions with enhanced hydrothermal activity and stations associated with intrusive rocks. (Author)

  10. Plasma-screening effects upon energy levels and electron scattering from neutral and ionized caesium

    International Nuclear Information System (INIS)

    Chin, Y.J.; Radtke, R.; Zimmermann, R.

    1988-01-01

    Using interaction potentials screened with the Debye-Hueckel length, the effects of plasma shielding on energy levels and electrons scattering from neutral and ionized caesium are estimated. Both energy levels and atomic scattering cross-sections are found to be sensitive to the inclusion of screening. Relating to the scattering by the Cs + ion, a low-energy resonance near E = 0.3 Ryd is found which arises from the f-wave phase shift and reflects the individual behaviour of the scattering ion. (author)

  11. Plasma-screening effects upon energy levels and electron scattering from neutral and ionized caesium

    Energy Technology Data Exchange (ETDEWEB)

    Chin, Y J; Radtke, R; Zimmermann, R

    1988-01-01

    Using interaction potentials screened with the Debye-Hueckel length, the effects of plasma shielding on energy levels and electrons scattering from neutral and ionized caesium are estimated. Both energy levels and atomic scattering cross-sections are found to be sensitive to the inclusion of screening. Relating to the scattering by the Cs/sup +/ ion, a low-energy resonance near E = 0.3 Ryd is found which arises from the f-wave phase shift and reflects the individual behaviour of the scattering ion.

  12. Bioremediation of petroleum contaminated soil

    International Nuclear Information System (INIS)

    Autry, A.R.; Ellis, G.M.

    1992-01-01

    This paper reports on bioremediation, which offers a cost-competitive, effective remediation alternative for soil contaminated with petroleum products. These technologies involve using microorganisms to biologically degrade organic constituents in contaminated soil. All bioremediation applications must mitigate various environmental rate limiting factors so that the biodegradation rates for petroleum hydrocarbons are optimized in field-relevant situations. Traditional bioremediation applications include landfarming, bioreactors, and composting. A more recent bioremediation application that has proven successful involves excavation of contaminated soil. The process involves the placement of the soils into a powerscreen, where it is screened to remove rocks and larger debris. The screened soil is then conveyed to a ribbon blender, where it is mixed in batch with nutrient solution containing nitrogen, phosphorus, water, and surfactants. Each mixed soil batch is then placed in a curing pile, where it remains undisturbed for the remainder of the treatment process, during which time biodegradation by naturally occurring microorganisms, utilizing biochemical pathways mediated by enzymes, will occur

  13. First results on enzymatic activities in two salt marsh soils under different hydromorphic level and vegetation

    Directory of Open Access Journals (Sweden)

    Carmen Trasar-Cepeda

    2015-12-01

    Full Text Available Salt-marsh soils are soils characterized by non-permanent hydric saturation that, depending on factors like duration of submersion periods, are dominated by different salt-tolerant plant species. The composition of microbial communities is an essential component in trophic dynamics and biogeochemical processes in salt marshes, and determines the level of enzymatic activities, which catalyze the conversion of complex molecules into simpler ones. Despite of this, the enzymatic activities in marsh-soils has not yet been investigated. The aim of this study was to analyze the enzymatic activities in two soil profiles of marsh-soils under different water saturation level and dominated by different plant species [Juncus maritimus Lam and Spartina maritima (Curtis Fernald (Sp]. In both soils, the enzymatic activities were much lower than the levels typically found in terrestrial ecosystems. The enzymatic activities were measured both in air-dried and in re-moistened and incubated soil samples. In air-dried samples, the enzymatic activities were higher in Juncus than in Spartina soil and tended to decrease with depth, being sharper the decrease in Juncus than in Spartina soil. Re-moistened and pre-incubated soils showed a general increase in all the enzymatic activities and throughout the whole soil profile, especially in Spartina soils. Hydrolase activities showed a strong and positive relationship with organic matter content both in air-dried and in re-moistened soil samples, higher in these latter. In general, oxidoreductase activities only showed this relationship in re-moistened soil samples. More studies, preferably using freshly collected soil samples, are needed to understand the relationship between enzymatic activities and these environmental conditions.

  14. Some physico-chemical and Heavy metal levels in soils of waste ...

    African Journals Online (AJOL)

    The results show that the soils are moderately acidic with a mean pH value of 5.5 for the 1m subsoil and 5.8 for 30cm soil depth in the various dumpsites, while the total organic carbon (TOC) levels show that it was low with 3.41% and 2.90% for depths 30cm and 1m respectively. The cation exchange capacity (CEC) of the ...

  15. Study of Effects of Sorghum Cultivation on Some Soil Biological Indicators at Different Zinc Levels

    Directory of Open Access Journals (Sweden)

    S. Bagheri

    2015-06-01

    Full Text Available Zinc is an essential element for plant growth which its high concentrations can cause pollution and toxicity in plant. In this study, the effects of sorghum cultivation on some indicators of microbial activity and its association with increased zinc concentrations in two soils with relatively similar physical and chemical properties, but different in concentration of heavy metals were investigated. In both soils zinc levels were added to obtain 250, 375 and 500 mg kg-1 (based on the initial nitric acid extractable content. Using plastic boxes containing 8 kg of soil, growth boxes (Rhizobox were prepared. The box interior was divided into three sections S1 (the rhizosphere, S2 (adjacent to the rhizosphere and S3 (bulk soil using nylon net plates. The results showed that at all levels of zinc in both soil types, BCF were bigger than units, so using this indicator, sorghum can be considered as a plant for accumulation of zinc. Microbial respiration and dehydrogenase activity was reduced in all sections adjacent to root in the polluted soil. It is generally understood that substrates and inhibitors (heavy metals compete in the formation of substrate-enzyme and inhibitor-enzyme complexes, but the effects of sorghum cultivation in increasing biological and enzyme activity indexes in soil 1 (non-polluted was higher than soil 2 (polluted, perhaps due to improvements in microbial activity in the vicinity of the roots, even in concentration higher than stress condition levels for zinc in soil.

  16. Determination of pesticide residue levels in omani and UAE vegetable farm soils

    International Nuclear Information System (INIS)

    Talukder, F.A.; Dahmani, J.H.A.; Kaakeh, W.; Deadman, M.L.

    2008-01-01

    In the investigation of 40 different vegetable growing farms of Al-Batinah (Oman) and Al - Ain (UAE) regions different pesticide residues were found to be present on all soil samples which varied in their types and levels according to the region. In Omani soil samples, cypermethrin was the most frequent pesticide, followed by chlorpyrifos, malathion, phenthoate, triazophos and deltamethrin. In UAE farm soil samples, chlorpyrifos, cypermethrin and deltamethrin were detected in all the regions, while phenthoate was detected in the Eastern and Northern regions only. (author)

  17. Efficiency evaluation for remediating paddy soil contaminated with cadmium and arsenic using water management, variety screening and foliage dressing technologies.

    Science.gov (United States)

    Liao, Guojian; Wu, Qianhua; Feng, Renwei; Guo, Junkang; Wang, Ruigang; Xu, Yingming; Ding, Yongzhen; Fan, Zhilian; Mo, Liangyu

    2016-04-01

    Paddy soils in many regions of China have been seriously polluted by multiple heavy metals or metalloids, such as arsenic (As), cadmium (Cd) and lead (Pb). In order to ensure the safety of food and take full advantage of the limited farmland resources of China, exploring an effective technology to repair contaminated soils is urgent and necessary. In this study, three technologies were employed, including variety screening, water management and foliage dressing, to assess their abilities to reduce the accumulation of Cd and As in the grains of different rice varieties, and meanwhile monitor the related yields. The results of variety screening under insufficient field drying condition showed that the As and Cd contents in the grains of only four varieties [Fengliangyouxiang 1 (P6), Zhongzheyou 8 (P7), Guangliangyou 1128 (P10), Y-liangyou 696 (P11)] did not exceed their individual national standard. P6 gained a relatively high grain yield but accumulated less As and Cd in the grains despite of the relatively high As and Cd concentrations in the rhizosphere soil. However, long-playing field drying in water management trial significantly increased Cd but decreased As content in the grains of all tested three varieties including P6, suggesting an important role of water supply in controlling the accumulation of grain As and Cd. Selenium (Se) showed a stronger ability than silicon (Si) to reduce As and Cd accumulation in the grains of Fengliangyou 4 (P2) and Teyou 524 (P13), and keep the yields. The results of this study suggest that combined application of water management and foliage dressing may be an efficient way to control As and Cd accumulation in the grains of paddy rice exposing to As- and Cd-contaminated soils. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Bioavailability of caesium-137 from chernozem soils with high and low levels of radioactive contamination

    Science.gov (United States)

    Paramonova, Tatiana; Shamshurina, Eugenia; Machaeva, Ekaterina; Belyaev, Vladimir

    2014-05-01

    Bioavailability of Cs-137 in "soil-plant" system of radioactively contaminated terrestrial ecosystems is the most important factor in the understanding of ecological situation. There are many factors affecting the features of Cs-137 biogeochemical cycle: period since an accident, type and intensity of radioactive fallout, general properties of landscape and the specifics of soil and plant covers, etc. In order to evaluate the importance of soil contamination level for the process of Cs-137 translocation from soil to plant the research in forest-steppe areas of Russia with similar natural properties, but contrasting high (Tula region) and low (Kursk region) levels of radioactive Chernobyl fallout (about 25 years after accident) was conducted. Soil cover of both sites is presented by chernozems with bulk density 1.1-1.2 g/cm3, 6-7% humus and neutral pH 6.5-7.2; plant cover under investigation consist of dry and wet meadows with bioproductivity 1.6-2.5 kg/m2 and 85-90% of biomass concentrated underground, that is typical for Russian forest-steppe landscapes. At the same time levels of soil regional contamination with Cs-137 differ by an order - 620-710 Bq/kg (210-250 kBq/m2) in Tula region and 30-55 Bq/kg (10-20 kBq/m2) in Kursk region. At a higher level of soil radioactive contamination specific activity of Cs-137 in vegetation of meadows is noticeably increased (103-160 Bq/kg in Tula region versus 12-14 Bq/kg in Kursk region) with correlation coefficient r 0.87. Increasing of Cs-137 in the underground parts of plants plays a decisive role in this process, while the specific radionuclide's activity in the aboveground parts of different sites is almost invariant (and ubiquitously roots contain 2-5 times more Cs-137 than shoots). The values of transfer factors for Cs-137 (the ratio of the specific Cs-137 activities in the plant tissue and in the soil) at various levels of soil radioactive contamination vary within a relatively narrow range 0.1-0.4, that confirms the

  19. Poly-use multi-level sampling system for soil-gas transport analysis in the vadose zone.

    Science.gov (United States)

    Nauer, Philipp A; Chiri, Eleonora; Schroth, Martin H

    2013-10-01

    Soil-gas turnover is important in the global cycling of greenhouse gases. The analysis of soil-gas profiles provides quantitative information on below-ground turnover and fluxes. We developed a poly-use multi-level sampling system (PMLS) for soil-gas sampling, water-content and temperature measurement with high depth resolution and minimal soil disturbance. It is based on perforated access tubes (ATs) permanently installed in the soil. A multi-level sampler allows extraction of soil-gas samples from 20 locations within 1 m depth, while a capacitance probe is used to measure volumetric water contents. During idle times, the ATs are sealed and can be equipped with temperature sensors. Proof-of-concept experiments in a field lysimeter showed good agreement of soil-gas samples and water-content measurements compared with conventional techniques, while a successfully performed gas-tracer test demonstrated the feasibility of the PMLS to determine soil-gas diffusion coefficients in situ. A field application of the PMLS to quantify oxidation of atmospheric CH4 in a field lysimeter and in the forefield of a receding glacier yielded activity coefficients and soil-atmosphere fluxes well in agreement with previous studies. With numerous options for customization, the presented tool extends the methodological choices to investigate soil-gas transport in the vadose zone.

  20. Screening of plants for phytoremediation of oil-contaminated soil.

    Science.gov (United States)

    Ikeura, Hiromi; Kawasaki, Yu; Kaimi, Etsuko; Nishiwaki, Junko; Noborio, Kosuke; Tamaki, Masahiko

    2016-01-01

    Several species of ornamental flowering plants were evaluated regarding their phytoremediation ability for the cleanup of oil-contaminated soil in Japanese environmental conditions. Thirty-three species of plants were grown in oil-contaminated soil, and Mimosa, Zinnia, Gazania, and cypress vine were selected for further assessment on the basis of their favorable initial growth. No significant difference was observed in the above-ground and under-ground dry matter weight of Gazania 180 days after sowing between contaminated and non-contaminated plots. However, the other 3 species of plants died by the 180th day, indicating that Gazania has an especially strong tolerance for oil-contaminated soil. The total petroleum hydrocarbon concentration of the soils in which the 4 species of plants were grown decreased by 45-49% by the 180th day. Compared to an irrigated plot, the dehydrogenase activity of the contaminated soil also increased significantly, indicating a phytoremediation effect by the 4 tested plants. Mimosa, Zinnia, and cypress vine all died by the 180th day after seeding, but the roots themselves became a source of nutrients for the soil microorganisms, which led to a phytoremediation effect by increase in the oil degradation activity. It has been indicated that Gazania is most appropriate for phytoremediation of oil-contaminated soil.

  1. Does water-level fluctuation affect mercury methylation in wetland soils?

    Energy Technology Data Exchange (ETDEWEB)

    Branfireun, B.A.; Mitchell, C.P.J.; Iraci, J.M. [Toronto Univ., ON (Canada). Dept. of Geography; Krabbenhoft, D.P. [United States Geological Survey, Middleton, WI (United States); Fowle, D.A. [Kansas Univ., Lawrence, KS (United States). Dept. of Geology; Neudahl, L. [Minnesota Power, Duluth, MN (United States)

    2006-07-01

    Mercury (Hg) concentrations in fish vary considerably in freshwater lakes and reservoirs. However, the variations are not generally consistent with physical factors such as basin characteristics, wetland cover or lake chemistry. Pronounced differences in Hg concentrations in fish have been noted in the reservoirs of the St. Louis River system near Duluth Minnesota. The differences were observed between headwater reservoir systems with seasonal flooding and drawdown, and a peaking reservoir with approximately daily water level fluctuations during seasonal lower flow periods. It was suggested that these differences could be attributed to water level fluctuations in the reservoir which influenced the actual production of methylmercury (MeHg) in the surrounding wetland soils. In response to this hypothesis, the authors investigated the role of water level fluctuation in the production and mobilization of MeHg in sediments from wetlands that lie adjacent to a headwater reservoir, a peaking reservoir, and a nearby natural flowage lake used as a control. Preliminary field surveys of the wetland soils revealed that although the average MeHg concentrations in the headwater and peaking reservoir wetlands were not considerably different, both were much higher than the natural lake. Each site demonstrated high variability, but maximum MeHg concentrations ranged from 29.2 ng/g for the peaking reservoir to 4.44 ng/g at the natural lake. A laboratory experiment was therefore performed in which sediments from each wetland were subjected to different water level regimes. The purpose was to assess Hg methylation potential. Stable Hg isotopes were used at the beginning and end of the experiment. In order to determine if water level fluctuation can significantly change the methylation potential of wetland soils on its own, the microbial consortia will also be assessed during the laboratory experiment.

  2. Influence of sample quality on phenylalanine and 17-hydroxyprogesterone levels in neonatal screening

    OpenAIRE

    del Río Fabre, Lesley; González, Ernesto C; Frómeta, Amarilys; Castells, Elisa M; Tejeda, Yileidis

    2010-01-01

    Quality of the sample and phenylalanine and 17-hydroxyprogesterone levels in neonatal screening. In the programs for neonatal screening many different analytes are quantified from dried blood on filter paper cards. Several factors affect the quality of the samples invalidating their employment in the laboratory: inadequate collection procedures, quality of the filter paper, the drying, storage and transportation under extreme environmental conditions. This article aims to show how the quality...

  3. Use of engineered soils beneath low-level radioactive waste disposal facilities

    Energy Technology Data Exchange (ETDEWEB)

    Sandford, T.C.; Humphrey, D.N.; DeMascio, F.A. [Univ. of Maine, Orono, ME (United States). Dept. of Civil Engineering

    1993-03-01

    Current regulations are oriented toward locating low-level radioactive waste disposal facilities on sites that have a substantial natural soil barrier and are above the groundwater table. In some of the northern states, like Maine, the overburden soils are glacially derived and in most places provide a thin cover over bedrock with a high groundwater table. Thus, the orientation of current regulations can severely limit the availability of suitable sites. A common characteristic of many locations in glaciated regions is the rapid change of soil types that may occur and the heterogeneity within a given soil type. In addition, the bedrock may be fractured, providing avenues for water movement. A reliable characterization of these sites can be difficult, even with a detailed subsurface exploration program. Moreover, fluctuating groundwater and frost as well as the natural deposition processes have introduced macro features such as cracks, fissures, sand and silt seams, and root holes. The significant effect that these macro features have on the permeability and adsorptive capacity of a large mass is often ignored or poorly accounted for in the analyses. This paper will examine an alternate approach, which is to use engineered soils as a substitute for some or all of the natural soil and to treat the fractures in the underlying bedrock. The site selection would no longer be primarily determined by the natural soil and rock and could even be placed in locations with no existing soils. Engineered soils can be used for below- or aboveground facilities.

  4. Levels of concern for radioactive contaminations in soil according to soil protection standards; Besorgniswerte fuer Radionuklide in Boeden nach bodenschutzrechtlichen Massstaeben

    Energy Technology Data Exchange (ETDEWEB)

    Gellermann, R. [Nuclear Control and Consulting GmbH, Braunschweig (Germany); Barkowski, D.; Machtolf, M. [IFUA-Projekt-GmbH Bielefeld (Germany)

    2016-07-01

    In the paper the question is examined whether the established soil protection standards for carcinogenic substances are also applicable to the assessment of radioactive soil contamination. Referring to the methods applied in soil protection for evaluation of dose-effectrelations and estimations of carcinogenic risks as well as the calculation methods for test values in soil protection ''levels of concern'' for soil contamination by artificial radionuclides are derived. The values obtained are significantly larger than the values for unrestricted clearance of ground according to the German Radiation Protection Ordinance (StrlSchV). The thesis that soil is protected according to environmental standards provided that radiation protection requirements are met needs further checks but can be probably confirmed if the radiation protection requirements are clearly defined.

  5. Effects of apple branch biochar on soil C mineralization and nutrient cycling under two levels of N.

    Science.gov (United States)

    Li, Shuailin; Liang, Chutao; Shangguan, Zhouping

    2017-12-31

    The incorporation of biochar into soil has been proposed as a strategy for enhancing soil fertility and crop productivity. However, there is limited information regarding the responses of soil respiration and the C, N and P cycles to the addition of apple branch biochar at different rates to soil with different levels of N. A 108-day incubation experiment was conducted to investigate the effects of the rate of biochar addition (0, 1, 2 and 4% by mass) on soil respiration and nutrients and the activities of enzymes involved in C, N and P cycling under two levels of N. Our results showed that the application of apple branch biochar at rates of 2% and 4% increased the C-mineralization rate, while biochar amendment at 1% decreased the C-mineralization rate, regardless of the N level. The soil organic C and microbial biomass C and P contents increased as the rate of biochar addition was increased to 2%. The biochar had negative effects on β-glucosidase, N-acetyl-β-glucosaminidase and urease activity in N-poor soil but exerted a positive effect on all of these factors in N-rich soil. Alkaline phosphatase activity increased with an increase in the rate of biochar addition, but the available P contents after all biochar addition treatments were lower than those obtained in the treatments without biochar. Biochar application at rates of 2% and 4% reduced the soil nitrate content, particularly in N-rich soil. Thus, apple branch biochar has the potential to sequester C and improve soil fertility, but the responses of soil C mineralization and nutrient cycling depend on the rate of addition and soil N levels. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. Effect of moisture, organic matter, microbial population and fortification level on dissipation of pyraclostrobin in soils.

    Science.gov (United States)

    Reddy, S Navakishore; Gupta, Suman; Gajbhiye, Vijay T

    2013-09-01

    The dissipation of pyraclostrobin, a strobilurin fungicide, in soil was found to be influenced by soil moisture, organic matter content and microbial population. Among the different moisture regimes, dissipation was faster under submerged condition (T1/2 10 days) followed by field capacity (T1/2 28.7 days) and in dry soil (T1/2 41.8 days). Use of sludge at 5 % level to Inceptisol favoured a faster dissipation of pyraclostrobin, whereas a slower rate of dissipation was observed in partial organic matter removed soil as compared to normal soil. Slower rate of dissipation was also observed in sterile soil (T1/2 47 days) compared to normal soil. Pyraclostrobin dissipated faster in Vertisol (T1/2 21.8 days) than in Inceptisol (T1/2 28.7 days). No significant difference in the dissipation rate was observed at 1 and 10 μg g(-1) fortification levels.

  7. EFFECT OF RICE STRAW AND NITRATE LEVELS IN SOIL SOLUTION ON NITROUS OXIDE EMISSION

    Directory of Open Access Journals (Sweden)

    André Carlos Cruz Copetti

    2015-04-01

    Full Text Available Among the greenhouse gases, nitrous oxide (N2O is considered important, in view of a global warming potential 296 times greater than that of carbon dioxide (CO2 and its dynamics strongly depend on the availability of C and mineral N in the soil. The understanding of the factors that define emissions is essential to develop mitigation strategies. This study evaluated the dynamics of N2O emissions after the application of different rice straw amounts and nitrate levels in soil solution. Pots containing soil treated with sodium nitrate rates (0, 50 and 100 g kg-1 of NO−3-N and rice straw levels (0, 5 and 10 Mg ha-1, i.e., nine treatments, were subjected to anaerobic conditions. The results showed that N2O emissions were increased by the addition of greater NO−3 amounts and reduced by large straw quantities applied to the soil. On the 1st day after flooding (DAF, significantly different N2O emissions were observed between the treatments with and without NO−3 addition, when straw had no significant influence on N2O levels. Emissions peaked on the 4th DAF in the treatments with highest NO−3-N addition. At this moment, straw application negatively affected N2O emissions, probably due to NO−3 immobilization. There were also alterations in other soil electrochemical characteristics, e.g., higher straw levels raised the Fe, Mn and dissolved C contents. These results indicate that a lowering of NO−3 concentration in the soil and the increase of straw incorporation can decrease N2O emissions.

  8. Natural radioactivity levels in soils of Fiji

    International Nuclear Information System (INIS)

    Garimella, S.; Kumar, A.; Prasad, U.; Jafar, M.

    1998-01-01

    A 10 cm (diameter) x 7.5 cm NaI(Tl) gamma-ray spectrometer with a low background shield has been used to measure the natural radioactivity levels in soils of Viti Levu, the main island of Fiji. From this, the external gamma-dose which is likely to be delivered to the local population in this region is computed and found to be 99 μGy a -1 . This is well below the world average, but it is comparable to that observed in Marshall Islands and the Micronesia

  9. Natural radioactivity levels in soils of Fiji

    International Nuclear Information System (INIS)

    Garimella, S.; Kumar, A.; Prasad, U.; Jafar, M.

    1998-01-01

    A 10 cm (diameter) x 7.5 cm NaI(TI) gamma-ray spectrometer with a low background shield has been used to measure the natural radioactivity levels in soils of Viti Levu, the main island of Fiji. From this, the external gamma-dose which is likely to be delivered to the local population in this region is computed and found to be 99 microG a -1 . This is well below the world average, but it is comparable to that observed in Marshall Islands and the Micronesia. (author). 17 refs., 3 figs., 5 tabs

  10. Continuous soil maps - a fuzzy set approach to bridge the gap between aggregation levels of process and distribution models

    NARCIS (Netherlands)

    Gruijter, de J.J.; Walvoort, D.J.J.; Gaans, van P.F.M.

    1997-01-01

    Soil maps as multi-purpose models of spatial soil distribution have a much higher level of aggregation (map units) than the models of soil processes and land-use effects that need input from soil maps. This mismatch between aggregation levels is particularly detrimental in the context of precision

  11. Heavy metals pollution levels and children health risk assessment of Yerevan kindergartens soils.

    Science.gov (United States)

    Tepanosyan, Gevorg; Maghakyan, Nairuhi; Sahakyan, Lilit; Saghatelyan, Armen

    2017-08-01

    Children, the most vulnerable urban population group, are exceptionally sensitive to polluted environments, particularly urban soils, which can lead to adverse health effects upon exposure. In this study, the total concentrations of Ag, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Ti, V, and Zn were determined in 111 topsoil samples collected from kindergartens in Yerevan. The objectives of this study were to evaluate heavy metal pollution levels of kindergarten's soils in Yerevan, compare with national legal and international requirements on heavy metal contents in kindergarten soil, and assess related child health risk. Multivariate geostatistical analyses suggested that the concentrations of Ag, As, Ba, Cd, Cu, Hg, Mo, Pb, and Zn observed in the kindergarten's topsoil may have originated from anthropogenic sources, while Co, Cr, Fe, Mn, Ni, Ti, and V mostly come from natural sources. According to the Summary pollution index (Zc), 102 kindergartens belong to the low pollution level, 7 to the moderate and only 2 to the high level of pollution. Summary concentration index (SCI) showed that 109 kindergartens were in the allowable level, while 2 featured in the low level of pollution. The health risk assessment showed that in all kindergartens except for seven, non-carcinogenic risk for children was detected (HI>1), while carcinogenic risk from arsenic belongs to the very low (allowable) level. Cr and multi-element carcinogenic risk (RI) exceeded the safety level (1.0E- 06) in all kindergartens and showed that the potential of developing cancer, albeit small, does exist. Therefore, city's kindergartens require necessary remedial actions to eliminate or reduce soil pollution and heavy metal-induced health risks. Copyright © 2017 Elsevier Inc. All rights reserved.

  12. Performance study and influence of radiation emission energy and soil contamination level on γ-radiation shielding of stabilised/solidified radionuclide-polluted soils

    International Nuclear Information System (INIS)

    Falciglia, Pietro P.; Puccio, Valentina; Romano, Stefano; Vagliasindi, Federico G.A.

    2015-01-01

    This work focuses on the stabilisation/solidification (S/S) of radionuclide-polluted soils at different 232 Th levels using Portland cement alone and with barite aggregates. The potential of S/S was assessed applying a full testing protocol and calculating γ-radiation shielding (γRS) index, that included the measurement of soil radioactivity before and after the S/S as a function of the emission energy and soil contamination level. The results indicate that setting processes are strongly dependent on the contaminant concentration, and for contamination level higher than 5%, setting time values longer than 72 h. The addition of barite aggregates to the cement gout leads to a slight improvement of the S/S performance in terms of durability and contaminant leaching but reduces the mechanical resistance of the treated soils samples. Barite addition also causes an increase in the γ-rays shielding properties of the S/S treatment up to about 20%. Gamma-ray measurements show that γRS strongly depends on the energy, and that the radioactivity with the contamination level was governed by a linear trend, while, γRS index does not depend on the radionuclide concentration. Results allow the calculated γRS values and those available from other experiments to be applied to hazard radioactive soil contaminations. - Highlights: • We assess the effects of 232 Th contamination on performance of S/S treated soil. • We assess the γ-radiation shielding of the S/S materials as a function of energy. • We report a full testing protocol for assessing S/S resistance performance. • Emission energy influences the γ radiation shielding of the S/S. • Barite gives high γ-radiation shielding and low contaminant leaching

  13. [Composition and Density of Soil Fauna in the Region with Enhanced Radioactivity Level (Komi Republic, Vodnyi)].

    Science.gov (United States)

    Kolesnikova, A A; Kudrin, A A; Konakova, T N; Taskaeva, A A

    2015-01-01

    Studies on the influence of high levels of radiation on soil fauna were carried out in 2012 in the territory formed as a result of the activity of the enterprise for extraction and production of radium from reservoir water and waste of uranium ore from 1931 to 1956. At present the local radioactive pollution in this area is caused by the presence of heavy natural radionuclides 226Ra, 238U and products of their disintegration in soils. The oppression of soil invertebrate.fauna in pine forests and meadows with high levels of radionuclides and heavy metals is revealed. Also shown is the decrease in the number and density of different taxonomic groups of invertebrates, reduction of the diversity and spectrum of trophic groups and vital forms in the area with a high content of radionuclides in soil. Our results are in agreement with the results obtained by the similar studies showing negative influence of high-level ionizing radiation on soil fauna.

  14. Characterizing Soil Lead Contamination Near Streams in Oakland, California

    Science.gov (United States)

    Tanouye, D.

    2017-12-01

    Lead (Pb) contamination of soils, groundwater, and surface waters is a major concern because of the potential health risks related to accumulation of high levels of lead in blood. This is a pervasive issue in many low-income neighborhoods throughout the United States, and is documented to be particularly acute in West Oakland, California. The fate and transport of lead in the environment is largely dependent on how it will bind to various solids and compounds in solution. These adsorption mechanisms are a principal aspect of metal dissolution and chemical speciation. Stream channels are natural drainage areas for urban runoff, and may represent a hot spot for increased levels of lead. This study evaluates the environmental conditions at 15 sites near streams in West Oakland using in-situ soil sampling with the handheld X-Ray Fluorescence (XRF) analyzer to measure concentrations of lead in soil. Results from this study suggest that the levels of lead in soils near stream channels are generally lower than the regional regulatory screening level of 80 milligrams per kilogram (mg/kg), but the highest concentrations are found near stream banks. The spatial distribution can be explained by a contaminant transport process related to the presence of fluvial channels.

  15. Radon gas. A review with emphasis on site investigations and measurements of soil gas and indoor house levels

    International Nuclear Information System (INIS)

    Mitchell, Seamus.

    1992-09-01

    A review of radon gas, with particular reference to its source and transport through soils and into buildings is examined. The principal parameters affecting the movement of radon has been discussed. The levels of radon gas in soils and in dwelling houses has been examined. Radon levels in the soil gas were highest in mineral soils with pear soils giving low readings but there was no significant differences between the results. Houses situated over granite and limestone bedrock gave similar results for indoor radon concentrations, with no significant differences being recorded. Results were expected to be much higher in houses over granite areas, in view of the higher uranium series activity in granites. It is concluded that high radon gas levels in soils under and in he vicinity of houses is the probable explanation for the indoor radon levels found. The influence of the underlying bedrock is not the most important parameter as was surmised before the study. (author)

  16. Background levels of some major, trace, and rare earth elements in indigenous plant species growing in Norway and the influence of soil acidification, soil parent material, and seasonal variation on these levels.

    Science.gov (United States)

    Gjengedal, Elin; Martinsen, Thomas; Steinnes, Eiliv

    2015-06-01

    Baseline levels of 43 elements, including major, trace, and rare earth elements (REEs) in several native plant species growing in boreal and alpine areas, are presented. Focus is placed on species metal levels at different soil conditions, temporal variations in plant tissue metal concentrations, and interspecies variation in metal concentrations. Vegetation samples were collected at Sogndal, a pristine site in western Norway, and at Risdalsheia, an acidified site in southernmost Norway. Metal concentrations in the different species sampled in western Norway are compared with relevant literature data from Norway, Finland, and northwest Russia, assumed to represent natural conditions. Except for aluminium (Al) and macronutrients, the levels of metals were generally lower in western Norway than in southern Norway and may be considered close to natural background levels. In southern Norway, the levels of cadmium (Cd) and lead (Pb) in particular appear to be affected by air pollution, either by direct atmospheric supply or through soil acidification. Levels of some elements show considerable variability between as well as within plant species. Calcium (Ca), magnesium (Mg), and potassium (K) are higher in most species at Sogndal compared to Risdalsheia, despite increased extractable concentrations in surface soil in the south, probably attributed to different buffer mechanisms in surface soil. Antagonism on plant uptake is suggested between Ca, Mg, and K on one hand and Al on the other. Tolerance among calcifuges to acid conditions and a particular ability to detoxify or avoid uptake of Al ions are noticeable for Vaccinium vitis-idaea.

  17. Low-level gamma spectrometry of forest and moor soils from exposed mountain regions in Saxony (Erzgebirge)

    Energy Technology Data Exchange (ETDEWEB)

    Schleich, N [Technische Univ. Bergakademie Freiberg (Germany). Inst. of Applied Physics; Preusse, W [Technische Univ. Bergakademie Freiberg (Germany). Inst. of Applied Physics; Degering, D [Technische Univ. Bergakademie Freiberg (Germany). Inst. of Applied Physics; Unterricker, S [Technische Univ. Bergakademie Freiberg (Germany). Inst. of Applied Physics

    1997-03-01

    In soils with distinct organic and mineral horizons, radionuclides (RN) can be used to understand geochemical migration processes. In the study presented here high sensitivity HPGe-detectors with active and passive shielding were employed to determine the low activity levels of various natural, cosmogenic and artificial RN. Soils of a spruce forest and a moor from exposed mountain regions in Saxony (Erzgebirge) were investigated as they provide a good example of layered soil systems with vertical transfer of chemical elements. Different soil horizons were sub-sampled as thin slices and analysed to examine the migration processes at sub-horizon level. The depth distributions of chemically different RN were studied considering the geochemical and pedological soil characteristics of the profiles. (orig.)

  18. Carbon dioxide emission from maize straw incubated with soil under various moisture and nitrogen levels

    International Nuclear Information System (INIS)

    Abro, S.A.; Tian, X.; Hussain, Q.; Talpur, M.; Singh, U.

    2012-01-01

    A laboratory incubation experiment was conducted to investigate the decomposition of maize straw incorporated into soil amended with nitrogen (N) and moisture (M) levels. Clay loam topsoil amended with maize straw was adjusted to four initial nitrogen treatments (C/N ratios of 72, 36, 18, and 9) and four moisture levels (60%, 70%, 80% and 90 % of field capacity) for the total of 16 treatments and incubated at 20 deg. C for 51 days. CO/sub 2/-C evolved was regularly recorded for all treatments during entire incubation period. Results showed that the mixing of straw with soil accelerated decomposition rates and enhanced cumulative CO/sub 2/-C production. The incorporation of straw brought about 50% increase in the cumulative CO/sub 2/-C production as compared with controls. About 45% of added maize straw C was mineralized to CO/sub 2/-C in 51 days. We conclude that incorporation of straw into soil along with the addition of N and moisture levels significantly affected CO/sub 2/-C evolution, cumulative CO/sub 2-C/, C mineralization and soil organic carbon deposition. The CO/sub 2/ emission was in positive correlation with (R2=0.99) N, moisture and incubation time (days). The straw returning into soil may enhance carbon pools and, thus will improve soil and environmental quality. (author)

  19. Levels of trace metals in soil and vegetation along major and minor ...

    African Journals Online (AJOL)

    ... emission couple with waste dispose along the roads remain a threat. The findings in general indicate the levels of metals in soil and plant samples were within the EU limits with the exception of Cd. In addition, the high level of Cd appears to reach pollution levels and metal dynamics up the food chain is highly possible.

  20. Waste reduction by separation of contaminated soils during environmental restoration

    International Nuclear Information System (INIS)

    Roybal, J.A.; Conway, R.; Galloway, B.; Vinsant, E.; Slavin, P.; Guerin, D.

    1998-06-01

    During cleanup of contaminated sites, Sandia National Laboratories, New Mexico (SNL/NM) frequently encounters soils with low-level radioactive contamination. The contamination is not uniformly distributed, but occurs within areas of clean soil. Because it is difficult to characterize heterogeneously contaminated soils in detail and to excavate such soils precisely using heavy equipment, it is common for large quantities of uncontaminated soil to be removed during excavation of contaminated sites. This practice results in the commingling and disposal of clean and contaminated material as low-level waste (LLW), or possibly low-level mixed waste (LLMW). Until recently, volume reduction of radioactively contaminated soil depended on manual screening and analysis of samples, which is a costly and impractical approach and does not uphold As Low As Reasonably Achievable (ALARA) principles. To reduce the amount of LLW and LLMW generated during the excavation process, SNL/NM is evaluating two alternative technologies. The first of these, the Segmented Gate System (SGS), is an automated system that located and removes gamma-ray emitting radionuclides from a host matrix (soil, sand, dry sludge). The matrix materials is transported by a conveyor to an analyzer/separation system, which segregates the clean and contaminated material based on radionuclide activity level. The SGS was used to process radioactively contaminated soil from the excavation of the Radioactive Waste Landfill. The second technology, Large Area Gamma Spectroscopy (LAGS), utilizes a gamma spec analyzer suspended over a slab upon which soil is spread out to a uniform depth. A counting period of approximately 30 minutes is used to obtain a full-spectrum analysis for the isotopes of interest. The LAGS is being tested on the soil that is being excavated from the Classified Waste Landfill

  1. The grey areas in soil pollution risk mapping : The distinction between cases of soil pollution and increased background levels

    NARCIS (Netherlands)

    Gaast, N. van der; Leenaers, H.; Zegwaard, J.

    1998-01-01

    The progress of soil clean up in the Netherlands is severely hindered by the lack of common agreement on how to describe the grey areas of increased background levels of pollutants. In this study practical methods are proposed in which background levels are described as distribution functions within

  2. Polycyclic aromatic hydrocarbons (PAHs) in wetland soils under different land uses in a coastal estuary: toxic levels, sources and relationships with soil organic matter and water-stable aggregates.

    Science.gov (United States)

    Xiao, Rong; Bai, Junhong; Wang, Junjing; Lu, Qiongqiong; Zhao, Qingqing; Cui, Baoshan; Liu, Xinhui

    2014-09-01

    The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the soils from industrial, wharf, cropland, milldam and natural wetland sites to characterize their distributions, toxic levels and possible sources in the Pearl River Estuary and identify their relationships with soil organic matter (SOM) and water-stable aggregates (WSAs). Our results indicate that the average concentration of total PAHs in this region reached a moderate pollution level, which was higher than that in other larger estuaries in Asia. The average level of total PAHs in industrial soils was 1.2, 1.5, 1.6 and 2.3 times higher than those in soils from wharf, cropland, milldam and natural wetland sites, respectively. Greater accumulation of PAHs occurred in the middle and/or bottom soil layers where 3-ring PAHs were dominant. Industrial soils also exhibited the highest toxic levels with the highest toxic equivalent concentrations of PAHs, followed by wharf and milldam soils, and the cropland and wetland soils had the lowest toxicity. The diagnostic ratios suggested that PAHs primarily originated from biomass and coal combustion at industrial and milldam sites, and petroleum combustion was determined to be the primary source of PAHs at the wharf, cropland and wetland sites. Both 3-ring and 4-ring PAHs in the milldam and wharf soils were significantly positively correlated with the SOM, whereas the 4,5,6-ring PAHs and total PAHs in industrial soils and the 2-ring PAHs in cropland soils were significantly negatively correlated with the SOM. In addition, large WSAs also exhibited a significant positive correlation with PAHs. Copyright © 2014 Elsevier Ltd. All rights reserved.

  3. The impact of groundwater level on soil seed bank survival

    NARCIS (Netherlands)

    Bekker, RM; Oomes, MJM; Bakker, JP

    Seed longevity of plant species is an important topic in restoration management, and little is known about the effects of environmental conditions on seed survival and longevity under natural conditions. Therefore, the effect of groundwater level on the survival of seeds in the soil seed bank of a

  4. Screening crops for efficient phosphorus acquisition in a low phosphorus soil using radiotracer technique

    International Nuclear Information System (INIS)

    Meena, S.; Malarvizhi, P.; Rajeswari, R.

    2017-01-01

    Deficiency of phosphorus (P) is the major limitation to agricultural production. Identification of cultivars with greater capacity to grow in soils having low P availability (phosphorus efficiency) will help in P management in a sustainable way. Green house experiment with maize (CO 6) and cotton (MCU 13) as test crops with four levels of phosphorus (0, 3.75, 7.50 and 15 mg P kg -1 soil) was conducted in a P deficient soil (7.2 kg ha -1 ) to study the phosphorus acquisition characteristics and to select efficient crop using 32 P radiotracer technique. Carrier free 32 P obtained as orthophosphoric acid in dilute hydrochloric acid medium from the Board of Radiation and Isotope Technology, Mumbai was used for labeling the soil @ 3200 kBq pot -1 . After 60 days the crops were harvested and the radioactivity was measured in the plant samples using Liquid scintillation counter (PerkinElmer - Tricarb 2810 TR). Different values of specific radioactivity and Isotopically Exchangeable Phosphorus for maize and cotton indicated that chemically different pools of soil P were utilized and maize accessing a larger pool than cotton. Maize having recorded high Phosphorus Use Efficiency, Phosphorus Efficiency and low Phosphorus Stress Factor values, it is a better choice for P deficient soils. Higher Phosphorus Acquisition Efficiency of maize (59 %) than cotton (48%) can be related to the ability of maize to take up P from insoluble inorganic P forms. (author)

  5. The Interaction Features of the Multi-Level Retaining Walls with Soil Mass

    Science.gov (United States)

    Boyko, Igor; Skochko, Liudmyla; Zhuk, Veronica

    2017-09-01

    The interaction features of multi-level retaining walls with soil base were researched by changing their geometric parameters and locality at the plan. During excavation of deep foundation pits it is important to choose the type of constructions which influences on the horizontal displacements. The distance between the levels of retaining walls should be based on the results of numerical modelling. The objective of this paper is to present a comparison between the data of numerical simulations and the results of the in-situ lateral tests of couple piles. The problems have been solved by using the following soil models: Coulomb-Mohr model; model, which is based on the dilatation theory; elastic-plastic model with variable stiffness parameters.

  6. Radioactivity level and soil radon measurement of a volcanic area in Cameroon

    International Nuclear Information System (INIS)

    Ngachin, M.; Garavaglia, M.; Giovani, C.; Kwato Njock, M.G.; Nourreddine, A.

    2008-01-01

    The radioactivity level of soils in a volcanic area in Cameroon was determined and discussed. Thirty soils samples were collected from Buea and Limbe cities located in the south-western Cameroon. These two regions are known for theirs volcanic grounds due to the presence of Mount Cameroon Mountain. The activity concentrations of natural radionuclides as well as that of the fission product were evaluated by gamma-ray spectrometry using a hyper-purity germanium detector (HPGe). The ranges of concentrations in the surveyed soils were 11-17 Bq kg -1 , 22-36 Bq kg -1 and 43-201 Bq kg -1 for 226 Ra, 232 Th and 40 K, respectively. The radioisotope 137 Cs was also found but in a very small amount. The outdoor absorbed dose rate 1 m above ground with the corresponding annual effective dose rate, assuming a 20% occupancy factor was estimated. The radium equivalent and the external hazard index were also evaluated and results are compared with available data from other studies and with the world average value [United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), 1988. Sources, Effects and Risks of Ionizing Radiation. Report to the General Assembly on the Effects of Atomic Radiation. United Nations, New York; UNSCEAR, 2000. Sources and Effects of Ionizing Radiations. Report to the General Assembly with Scientific Annexes. United Nations, New York]. A solid state nuclear track detector (SSNTD), LR-115 was used for soil radon measurements at a depth of 50 cm. The ranges of soil radon concentrations were 6.7-10.8 kBq m -3 and 5.5-8.7 kBq m -3 in Buea and Limbe, respectively. A positive correlation was found between concentrations of radium measured with γ-spectrometry and the soil radon concentrations measured with the nitrate cellulose detectors. The results of this study provide the radioactivity level in soil of a volcanic area, which has been found to be within the safety limits. The south-western Cameroon can be considered as having normal

  7. Uncertainty of mass discharge estimation from contaminated sites at screening level

    DEFF Research Database (Denmark)

    Thomsen, Nanna Isbak; Troldborg, M.; McKnight, Ursula S.

    Contaminated sites threaten groundwater resources worldwide. The number of contaminated sites is large and there are too few economic resources available to ensure a thorough investigation and remediation of them all. Risk assessment must already be done at a screening level in order to ensure...... consider possible source and hydrogeological descriptions, where each model is believed to be a realistic representation of the given site, based on the current level of information. Parameter uncertainty is quantified using Monte Carlo simulations. For each conceptual model we calculate a transient mass...

  8. The level of 137Cs concentration in Greek soils one decade after the Chernobyl accident

    International Nuclear Information System (INIS)

    Vosniakos, F.K.; Zoumakis, N.M.; Diomou, C.S.

    1997-01-01

    One of the most serious consequences of the Chernobyl accident was the greatest radioactive contamination of the biosphere including the soil cover. It is well known that a soil analysis is a principal systematic method to estimate the radioactivity level in the particular area since deposition pattern is determined by measuring activity in grass and soil. The aim of the present work is first to identify the level of the existing 137 Cs contamination over Greece ten years after the Chernobyl accident. Secondly, a comparison between the 1986 137 Cs - distribution and the present measured one in more - less the same areas of Greece, has been attempted. The 40 k (0.0118% of natural K) concentration in soils as ratio 137 Cs/ 40 k has been, examined, even this ratio is not as constant in biological systems as the ratio Sr/Ca

  9. Exploration of Bacillus thuringiensis Berl. from soil and screening test its toxicity on insects of Lepidoptera order

    Science.gov (United States)

    Astuti, DT; Pujiastuti, Y.; Suparman, SHK; Damiri, N.; Nugraha, S.; Sembiring, ER; Mulawarman

    2018-01-01

    Bacillus thuringiensis is a gram-positive bacterium that produces crystal proteins toxic (ᴕ-endotoxin) specific to the target insect, but is not toxic to humans and non-target organisms. This study aims to explore the origin of the soil bacterium B. thuringiensis sub-district Sekayu, Banyuasin, South Sumatra and toxicity to larvae of lepidoptera. Fifty soil samples were taken from Musi Banyuasin District, namely 15 from Kayuare strip 2, 20 from Kayuare and 15 from Lumpatan. Isolation, characterization, identification and screening test were conducted in the laboratorium of Pest and Disease, Agricultural Faculty, Sriwijaya University. Isolat codes were given based on the area origin of the samples. Results of the study showed that from 50 isolates of bacteria that had been isolated, there were 15 bacterial isolates, characterized by morphology and physiology the same as B. thuringiensis, which has round colonies, white, wrinkled edges, slippery, elevation arise, aerobic and gram-positive. Of the 15 codes that contain positive isolates of B. thuringiensis, we have obtained several isolates of the following codes: KJ2D5, KJ2N1, KJ2N4, KJ2B3, KJ3R1, KJ3R2, KJ3R3, KJ3R5, KJ3J3, KJ3J4, KJ3P1, DLM5, DLKK12, and DLKK23. Results of screening tests on insects of the Lepidoptera Order showed that there were six isolates that had toxic to Plutella xylostella and Spodoptera litura insects, ie bacterial isolate codes DLM5, KJ3R3, KJ3R5, KJ3J4, KJ3P1, and DLKK23.

  10. Environmental radioactivity level and soil radon measurement of a volcanic region in Cameroon

    International Nuclear Information System (INIS)

    Ngachin, M.; Garavaglia, M.; Giovani, C.; Kwato Njock, M.G.

    2007-02-01

    A part of the survey programme on the evaluation of environmental radioactivity in Cameroon has just been initiated. The radioactivity level of soils in a volcanic area in Cameroon was determined and discussed. 30 soils samples were collected from Buea and Limbe cities located in the south-western Cameroon. These two regions are known for theirs volcanic grounds due to the presence of Mount Cameroon mountain. The activity concentrations of natural radionuclides as well as that of the fission product were evaluated by gamma-ray spectrometry using a hyper purity germanium detector (HPGe). The ranges of concentrations in the surveyed soils were 11 - 17 Bq kg -1 , 22 - 36 Bq kg -1 and 43 - 201 Bq kg -1 for 226 Ra, 232 Th and 40 K, respectively. The radioisotope 137 Cs was also found but in a very small amount. The outdoor absorbed dose rate 1 m above ground with the corresponding annual effective dose rate, assuming a 20% occupancy factor were estimated. The radium equivalent and the external hazard index were also evaluated and results are compared with available data from other studies and with the world average value (UNSCEAR, 1988, 2000). A solid state nuclear track detector (SSNTDs), LR-115 was used for soil radon measurements at a depth of 50 cm. The ranges of soil radon concentrations were 6.7 - 10.8 kBq m -3 and 5.5 - 8.7 kBq m -3 in Buea and Limbe, respectively. A positive correlation was found between concentrations of radium measured with γ-spectrometry and the soil radon concentrations measured with the nitrate cellulose detectors. The results of this study provide the radioactivity level in soil of a volcanic area, which has been found to be within the safety limits. The south-western Cameroon can be considered as having normal natural background radiation in normal living conditions. (author)

  11. Absorption of technetium by plants in relation to soil type contamination level and time

    Energy Technology Data Exchange (ETDEWEB)

    Mousny, J.M.; Myttenaere, C. (Louvain Univ. (Belgium). Lab. de Physiologie Vegetale)

    1981-01-01

    Plants of Pisum sativum (var. Merveille de Kelvedon) were grown on seven typical european soils contaminated with different levels of /sup 99/Tc(0.17; 1.7 and 17 ..mu..Ci/kg). Added initially as pertechnetate, the technetium absorption has been studied for three successive cultures. The translocation of technetium from soil to plant leaves is high, but its transfer is reduced in soils rich in organic matter (Fen) or poorly drained (Braunerde). Aging reduces the technetium transfer and modify its relative distribution in plant (relatively more technetium is found in fruits); these results let suppose some modification of the technetium chemical form in soils with time.

  12. Approaching the Hard-to-Reach in Organized Colorectal Cancer Screening: an Overview of Individual, Provider and System Level Coping Strategies

    Directory of Open Access Journals (Sweden)

    Jason Liwen Huang

    2017-06-01

    Full Text Available Background: Despite the proven effectiveness of colorectal cancer (CRC screening on reduction of CRC mortality, the uptake of CRC screening remains low. Participation rate is one of determinants for the success of organized population-based screening program. This review aims to identify those who are hard-to-reach, and summarize the strategies to increase their screening rate from individual, provider and system levels. Methods: A systematic search of electronic English databases was conducted on the factors and strategies of uptake in CRC screening for the hard-to-reach population up to May 2017. Discussion: The coverage rate and participation rate are two indexes to identify the hard-to-reach population in organized CRC screening program. However, the homeless, new immigrants, people with severe mental illness, the jail intimates, and people with characteristics including lower education levels and/or low socioeconomic status, living in rural/remote areas, without insurance, and racial minorities are usually recognized as hard-to-reach populations. For them, organized screening programs offer a better coverage, while novel invitation approaches for eligible individuals and multiple strategies from primary care physicians are still needed to enhance screening rates among subjects who are hard-to-reach. Suggestions implied the effectiveness of interventions at the system level, including linkages to general practice; use of decision making tools; enlisting supports from coalition; and the continuum from screening to diagnosis and treatment. Conclusion: Organized CRC screening offers a system access to approach the hard-to-reach populations. To increase their uptake, multiple and novel strategies from individual, provider and system levels should be applied. For policymakers, public healthcare providers and community stakeholders, it is a test to tailor their potential needs and increase their participation rates through continuous efforts to

  13. The Interaction Features of the Multi-Level Retaining Walls with Soil Mass

    Directory of Open Access Journals (Sweden)

    Boyko Igor

    2017-09-01

    Full Text Available The interaction features of multi-level retaining walls with soil base were researched by changing their geometric parameters and locality at the plan. During excavation of deep foundation pits it is important to choose the type of constructions which influences on the horizontal displacements. The distance between the levels of retaining walls should be based on the results of numerical modelling. The objective of this paper is to present a comparison between the data of numerical simulations and the results of the in-situ lateral tests of couple piles. The problems have been solved by using the following soil models: Coulomb-Mohr model; model, which is based on the dilatation theory; elastic-plastic model with variable stiffness parameters.

  14. Assessment of groundwater, soil-gas, and soil contamination at the Vietnam Armor Training Facility, Fort Gordon, Georgia, 2009-2010

    Science.gov (United States)

    Guimaraes, Wladmir B.; Falls, W. Fred; Caldwell, Andral W.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2011-01-01

    respective method detection levels were found at any of the sampling locations. The same four locations that were sampled for explosives and chemical agents were selected for the collection of soil samples. A fifth location also was selected on the basis of the elevated contaminant mass of the soil-gas survey. No metals that exceeded the Regional Screening Levels for Industrial Soils as classified by the U.S. Environmental Protection Agency were detected at any of the five VATF locations. The soil samples also were compared to values from the ambient, uncontaminated (background) levels for soils in South Carolina, as classified by the South Carolina Department of Health and Environmental Control. Because South Carolina is adjacent to Georgia and the soils in the coastal plain are similar, these comparisons are valid. No similar values are available for Georgia to use for comparison purposes. The metals that were detected above the ambient background levels for South Carolina, as classified by the South Carolina Department of Health and Environmental Control, include aluminum, arsenic, barium, beryllium, calcium, chromium, copper, iron, lead, magnesium, manganese, nickel, potassium, sodium, and zinc.

  15. SMOS/SMAP Synergy for SMAP Level 2 Soil Moisture Algorithm Evaluation

    Science.gov (United States)

    Bindlish, Rajat; Jackson, Thomas J.; Zhao, Tianjie; Cosh, Michael; Chan, Steven; O'Neill, Peggy; Njoku, Eni; Colliander, Andreas; Kerr, Yann

    2011-01-01

    ancillary data) were used to correct for surface temperature effects and to derive microwave emissivity. ECMWF data were also used for precipitation forecasts, presence of snow, and frozen ground. Vegetation options are described below. One year of soil moisture observations from a set of four watersheds in the U.S. were used to evaluate four different retrieval methodologies: (1) SMOS soil moisture estimates (version 400), (2) SeA soil moisture estimates using the SMOS/SMAP data with SMOS estimated vegetation optical depth, which is part of the SMOS level 2 product, (3) SeA soil moisture estimates using the SMOS/SMAP data and the MODIS-based vegetation climatology data, and (4) SeA soil moisture estimates using the SMOS/SMAP data and actual MODIS observations. The use of SMOS real-world global microwave observations and the analyses described here will help in the development and selection of different land surface parameters and ancillary observations needed for the SMAP soil moisture algorithms. These investigations will greatly improve the quality and reliability of this SMAP product at launch.

  16. Bacterial Communities in Malagasy Soils with Differing Levels of Disturbance Affecting Botanical Diversity

    Science.gov (United States)

    Blasiak, Leah C.; Schmidt, Alex W.; Andriamiarinoro, Honoré; Mulaw, Temesgen; Rasolomampianina, Rado; Applequist, Wendy L.; Birkinshaw, Chris; Rejo-Fienena, Félicitée; Lowry, Porter P.; Schmidt, Thomas M.; Hill, Russell T.

    2014-01-01

    Madagascar is well-known for the exceptional biodiversity of its macro-flora and fauna, but the biodiversity of Malagasy microbial communities remains relatively unexplored. Understanding patterns of bacterial diversity in soil and their correlations with above-ground botanical diversity could influence conservation planning as well as sampling strategies to maximize access to bacterially derived natural products. We present the first detailed description of Malagasy soil bacterial communities from a targeted 16S rRNA gene survey of greater than 290,000 sequences generated using 454 pyrosequencing. Two sampling plots in each of three forest conservation areas were established to represent different levels of disturbance resulting from human impact through agriculture and selective exploitation of trees, as well as from natural impacts of cyclones. In parallel, we performed an in-depth characterization of the total vascular plant morphospecies richness within each plot. The plots representing different levels of disturbance within each forest did not differ significantly in bacterial diversity or richness. Changes in bacterial community composition were largest between forests rather than between different levels of impact within a forest. The largest difference in bacterial community composition with disturbance was observed at the Vohibe forest conservation area, and this difference was correlated with changes in both vascular plant richness and soil pH. These results provide the first survey of Malagasy soil bacterial diversity and establish a baseline of botanical diversity within important conservation areas. PMID:24465484

  17. APC-PCI complex levels for screening of AAA in patients with peripheral atherosclerosis.

    Science.gov (United States)

    Zarrouk, Moncef; Keshavarz, Kave; Lindblad, Bengt; Gottsäter, Anders

    2013-11-01

    To evaluate the use of activated protein C-protein C inhibitor (APC-PCI) complex levels for detection of abdominal aortic aneurysm (AAA) in patients with peripheral atherosclerotic disease (PAD). APC-PCI levels and aortic diameter evaluated in 511 PAD patients without previously known AAA followed-up concerning survival for 4.8(0.5) years. AAA was found in 13% of patients. Aortic diameter correlated (r = 0.138; p = 0.002) with APC-PCI levels which were higher (0.40[0.45] vs. 0.30[0.49] μg/l; p = 0.004) in patients with AAA. This difference persisted in multivariate analysis (p = 0.029). A threshold value of APC-PCI ≥0.15 μg/L showed a specificity of 11%, a sensitivity of 97% and a negative predictive value of 96% for an AAA diagnosis. APC-PCI levels were higher in patients with AAA, and showed high sensitivity but low specificity for the diagnosis and can therefore not be considered as a screening tool in PAD patients. An AAA prevalence of 13% in patients with PAD indicates a need for AAA screening within this population.

  18. Soil Gas Sampling

    Science.gov (United States)

    Field Branches Quality System and Technical Procedures: This document describes general and specific procedures, methods and considerations to be used and observed when collecting soil gas samples for field screening or laboratory analysis.

  19. Childhood lead poisoning investigations: evaluating a portable instrument for testing soil lead.

    Science.gov (United States)

    Reames, Ginger; Lance, Larrie L

    2002-04-01

    The Childhood Lead Poisoning Prevention Branch of the California Department of Health Services evaluated a portable X-ray fluorescence (XRF) instrument for use as a soil lead-testing tool during environmental investigations of lead-poisoned children's homes. A Niton XRF was used to test soil at 119 sampling locations in the yards of 11 San Francisco Bay Area houses. Niton XRF readings were highly correlated with laboratory results and met the study criteria for an acceptable screening method. The data suggest that the most health-protective and time-efficient approach to testing for soil lead above regulatory levels is to take either surface readings or readings of a test cup of soil prepared by grinding with a mortar and pestle. The advantage of the test cup method is that the test cup with soil may be submitted to a laboratory for confirmatory analysis.

  20. Improving Polycyclic Aromatic Hydrocarbon Biodegradation in Contaminated Soil Through Low-Level Surfactant Addition After Conventional Bioremediation.

    Science.gov (United States)

    Adrion, Alden C; Singleton, David R; Nakamura, Jun; Shea, Damian; Aitken, Michael D

    2016-09-01

    Efficacy of bioremediation for soil contaminated with polycyclic aromatic hydrocarbons (PAHs) may be limited by the fractions of soil-bound PAHs that are less accessible to PAH-degrading microorganisms. In previous test-tube-scale work, submicellar doses of nonionic surfactants were screened for their ability to enhance the desorption and biodegradation of residual PAHs in soil after conventional bioremediation in a laboratory-scale, slurry-phase bioreactor. Polyoxyethylene sorbitol hexaoleate (POESH) was the optimum surfactant for enhancing PAH removal, especially the high-molecular weight PAHs. This work extends that concept by treating the effluent from the slurry-phase bioreactor in a second-stage batch reactor, to which POESH was added, for an additional 7 or 12 days. Surfactant amendment removed substantial amounts of the PAHs and oxy-PAHs remaining after conventional slurry-phase bioremediation, including more than 80% of residual 4-ring PAHs. Surfactant-amended treatment decreased soil cytotoxicity, but often increased the genotoxicity of the soil as measured using the DT-40 chicken lymphocyte DNA damage response assay. Potential ecotoxicity, measured using a seed germination assay, was reduced by bioreactor treatment and was reduced further after second-stage treatment with POESH. Of bacteria previously implicated as potential PAH degraders under POESH-amended conditions in a prior study, members of the Terrimonas genus were associated with differences in high-molecular weight PAH removal in the current study. Research using submicellar doses of surfactant as a second-stage treatment step is limited and these findings can inform the design of bioremediation systems at field sites treating soil contaminated with PAHs and other hydrophobic contaminants that have low bioaccessibility.

  1. Operational assimilation of ASCAT surface soil wetness at the Met Office

    Directory of Open Access Journals (Sweden)

    I. Dharssi

    2011-08-01

    Full Text Available Currently, no extensive, near real time, global soil moisture observation network exists. Therefore, the Met Office global soil moisture analysis scheme has instead used observations of screen temperature and humidity. A number of new space-borne remote sensing systems, operating at microwave frequencies, have been developed that provide a more direct retrieval of surface soil moisture. These systems are attractive since they provide global data coverage and the horizontal resolution is similar to weather forecasting models. Several studies show that measurements of normalised backscatter (surface soil wetness from the Advanced Scatterometer (ASCAT on the meteorological operational (MetOp satellite contain good quality information about surface soil moisture. This study describes methods to convert ASCAT surface soil wetness measurements to volumetric surface soil moisture together with bias correction and quality control. A computationally efficient nudging scheme is used to assimilate the ASCAT volumetric surface soil moisture data into the Met Office global soil moisture analysis. This ASCAT nudging scheme works alongside a soil moisture nudging scheme that uses observations of screen temperature and humidity. Trials, using the Met Office global Unified Model, of the ASCAT nudging scheme show a positive impact on forecasts of screen temperature and humidity for the tropics, North America and Australia. A comparison with in-situ soil moisture measurements from the US also indicates that assimilation of ASCAT surface soil wetness improves the soil moisture analysis. Assimilation of ASCAT surface soil wetness measurements became operational during July 2010.

  2. Building and environmental factors associated with elevated radon levels in rural Iowa homes

    International Nuclear Information System (INIS)

    Weih, L.M.B.

    1993-01-01

    This work examined the relationships between home construction, soil, and climatic factors with radon concentration in 585 rural Iowa homes, screened in winter of 1989. The specific goals of this work were to evaluate the utility of Soil Conservation data in describing radon occurrence in Iowa, and to assess the joint influence of construction and environmental characteristics on predicting radon concentration in homes. A follow-up study in a subset of homes evaluated the variability of radon screening measurements over time. The first part found that the relationship between radon concentration and home construction factors was dependent on location of the radon test in homes. In basements, wall construction and degree of energy efficiency predominated in predicting radon concentration. On upper floors, age of home predominated in predicting radon concentration, with a general decrease in radon concentration with age of home. The second part found that texture of the soil on which the home is located was the most important predictor of radon concentration for homes tested in basements, but the explanatory power was low. Precipitation in the year preceding screening was negatively correlated with radon concentration in homes, but the relationship was only apparent when basement wall type and soil texture were accounted for. Regional trends were not apparent except in describing the relative distribution of soil texture classes across the state. Radon concentration on upper floors of homes was not well described by either soil factors or precipitation. In 1992 a decrease of 36% and 51% from 1989 radon screening levels was found for homes tested in basements and upper floors, respectively. This data set included pair measurements of the same testing location in homes tested in winter 1989. Temperature differences were positively correlated with radon concentration and precipitation differences were not significantly associated with change in radon concentration

  3. Trace metal levels in soils and vegetation from some tin mining ...

    African Journals Online (AJOL)

    Samples of soil and vegetation from some tin mining areas of Nigeria were analysed for lead, zinc, copper and cadmium content. The levels of Pb and Zn were found to be high in some samples. The mean levels of metal in the vegetation were: 86.6+ 36.0, 49.6+ 28.3, 12.6+4.8 and 1.4+0.8 µgg-1 dry weight for Pb, Zn, Cu ...

  4. The rocky flats controversy on radionuclide soil action levels

    International Nuclear Information System (INIS)

    Earle, T.C.

    2004-01-01

    An account of the Rocky Flats radionuclide soil action level controversy is presented as: a case study for the purpose of understanding the nature and value of stakeholder involvement in the management of radiological hazards. The report consists of three main sections. The first section outlines the Rocky Flats story, including the Cold War era, which was characterised by secrecy and distrust, the post-Cold War era, in which trust and co-operation between risk managers and the public began to develop. This contrast between these two historical periods provides the context necessary to understand the radionuclide soil action level controversy, the main events of which are described in the second section. In the final section, the Rocky Flats case is briefly discussed within the framework of a general model of stakeholder involvement and the lessons learned from the case are identified: (1) without a basis in shared values, collaborative public involvement in the management of radiological hazards is not possible; (2) given a basis in shared values, collaborative public involvement can lead to improved solutions to the management of radiological hazards; and (3) risk managers should therefore seek to understand the values of public stakeholders and to identify ways, through stakeholder involvement, that those values can be incorporated in management practice. (author)

  5. Radioactivity level and soil radon measurement of a volcanic area in Cameroon

    Energy Technology Data Exchange (ETDEWEB)

    Ngachin, M. [Center for Atomic, Molecular Physics and Quantum Optics, University of Douala, P.O. Box 8580, Douala (Cameroon); Abdus Salam International Center for Theoretical Physics, Strada Costiera 11, 34014 Trieste (Italy); Institut Pluridisciplinaire Hubert-Curien, UMR7178 CNRS-IN2P3 and Universite Louis Pasteur, 23 rue de Loess, BP 28, F-67037 Strasbourg cedex 02 (France)], E-mail: mngachin@yahoo.com; Garavaglia, M.; Giovani, C. [Regional Agency for Environmental Protection (ARPA), 91 via Tavagnacco, 33100 Udine (Italy); Kwato Njock, M.G. [Center for Atomic, Molecular Physics and Quantum Optics, University of Douala, P.O. Box 8580, Douala (Cameroon); Nourreddine, A. [Institut Pluridisciplinaire Hubert-Curien, UMR7178 CNRS-IN2P3 and Universite Louis Pasteur, 23 rue de Loess, BP 28, F-67037 Strasbourg cedex 02 (France)

    2008-07-15

    The radioactivity level of soils in a volcanic area in Cameroon was determined and discussed. Thirty soils samples were collected from Buea and Limbe cities located in the south-western Cameroon. These two regions are known for theirs volcanic grounds due to the presence of Mount Cameroon Mountain. The activity concentrations of natural radionuclides as well as that of the fission product were evaluated by gamma-ray spectrometry using a hyper-purity germanium detector (HPGe). The ranges of concentrations in the surveyed soils were 11-17 Bq kg{sup -1}, 22-36 Bq kg{sup -1} and 43-201 Bq kg{sup -1} for {sup 226}Ra, {sup 232}Th and {sup 40}K, respectively. The radioisotope {sup 137}Cs was also found but in a very small amount. The outdoor absorbed dose rate 1 m above ground with the corresponding annual effective dose rate, assuming a 20% occupancy factor was estimated. The radium equivalent and the external hazard index were also evaluated and results are compared with available data from other studies and with the world average value [United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), 1988. Sources, Effects and Risks of Ionizing Radiation. Report to the General Assembly on the Effects of Atomic Radiation. United Nations, New York; UNSCEAR, 2000. Sources and Effects of Ionizing Radiations. Report to the General Assembly with Scientific Annexes. United Nations, New York]. A solid state nuclear track detector (SSNTD), LR-115 was used for soil radon measurements at a depth of 50 cm. The ranges of soil radon concentrations were 6.7-10.8 kBq m{sup -3} and 5.5-8.7 kBq m{sup -3} in Buea and Limbe, respectively. A positive correlation was found between concentrations of radium measured with {gamma}-spectrometry and the soil radon concentrations measured with the nitrate cellulose detectors. The results of this study provide the radioactivity level in soil of a volcanic area, which has been found to be within the safety limits. The south

  6. Soil decontamination at Rocky Flats

    International Nuclear Information System (INIS)

    Olsen, R.L.; Hayden, J.A.; Alford, C.E.; Kochen, R.L.; Stevens, J.R.

    1979-01-01

    A soils decontamination project was initiated, to remove actinides from soils at Rocky Flats. Wet screening, attrition scrubbing with Calgon at high pH, attrition scrubbing at low pH, and cationic flotation were investigated. Pilot plant studies were carried out. Conceptual designs have been generated for mounting the process in semi-trailers

  7. Silicide Schottky Contacts to Silicon: Screened Pinning at Defect Levels

    Energy Technology Data Exchange (ETDEWEB)

    Drummond, T.J.

    1999-03-11

    Silicide Schottky contacts can be as large as 0.955 eV (E{sub v} + 0.165 eV) on n-type silicon and as large as 1.05 eV (E{sub c} {minus} 0.07 eV) on p-type silicon. Current models of Schottky barrier formation do not provide a satisfactory explanation of occurrence of this wide variation. A model for understanding Schottky contacts via screened pinning at defect levels is presented. In the present paper it is shown that most transition metal silicides are pinned approximately 0.48 eV above the valence band by interstitial Si clusters. Rare earth disilicides pin close to the divacancy acceptor level 0.41 eV below the conduction band edge while high work function silicides of Ir and Pt pin close to the divacancy donor level 0.21 eV above the valence band edge. Selection of a particular defect pinning level depends strongly on the relative positions of the silicide work function and the defect energy level on an absolute energy scale.

  8. Effect of different soil water available levels on the development of young plants of “erva-mate”

    OpenAIRE

    Pintro, Jose Carlos; UEM; Flores, Feliciano Edi Vieira; UFRGS

    2008-01-01

    The influence of different levels of soil water availability on the development of young plants of “erva-mate” (Ilex paraguariensis St. Hil.) was studied under controlled conditions. The plants were cultivated during the period from January to November, a total of 45 weeks. The foreseen treatments corresponded to 3 water available levels for plants: treatment 1 (T-1): soil moisture at 0.3 atm of tension, treatment 2 (T-2): soil moisture at 80% of water quantity used in T-1, and treatment 3 (T...

  9. Metal concentrations in schoolyard soils from New Orleans, Louisiana before and after Hurricanes Katrina and Rita.

    Science.gov (United States)

    Presley, Steven M; Abel, Michael T; Austin, Galen P; Rainwater, Thomas R; Brown, Ray W; McDaniel, Les N; Marsland, Eric J; Fornerette, Ashley M; Dillard, Melvin L; Rigdon, Richard W; Kendall, Ronald J; Cobb, George P

    2010-06-01

    The long-term environmental impact and potential human health hazards resulting from Hurricanes Katrina and Rita throughout much of the United States Gulf Coast, particularly in the New Orleans, Louisiana, USA area are still being assessed and realized after more than four years. Numerous government agencies and private entities have collected environmental samples from throughout New Orleans and found concentrations of contaminants exceeding human health screening values as established by the United States Environmental Protection Agency (USEPA) for air, soil, and water. To further assess risks of exposure to toxic concentrations of soil contaminants for citizens, particularly children, returning to live in New Orleans following the storms, soils collected from schoolyards prior to Hurricane Katrina and after Hurricane Rita were screened for 26 metals. Concentrations exceeding USEPA Regional Screening Levels (USEPA-RSL), total exposure, non-cancer endpoints, for residential soils for arsenic (As), iron (Fe), lead (Pb), and thallium (Tl) were detected in soil samples collected from schoolyards both prior to Hurricane Katrina and after Hurricane Rita. Approximately 43% (9/21) of schoolyard soils collected prior to Hurricane Katrina contained Pb concentrations greater than 400mgkg(-1), and samples from four schoolyards collected after Hurricane Rita contained detectable Pb concentrations, with two exceeding 1700mgkg(-1). Thallium concentrations exceeded USEPA-RSL in samples collected from five schoolyards after Hurricane Rita. Based upon these findings and the known increased susceptibility of children to the effects of Pb exposure, a more extensive assessment of the soils in schoolyards, public parks and other residential areas of New Orleans for metal contaminants is warranted. 2010 Elsevier Ltd. All rights reserved.

  10. Monitoring soil bacteria with community-level physiological profiles using Biolog™ ECO-plates in the Netherlands and Europe

    DEFF Research Database (Denmark)

    Rutgers, Michiel; Wouterse, Marja; Drost, Sytske M.

    2016-01-01

    Soil samples were analyzed with community-level physiological profiles (CLPP) using Biolog™ ECO-plates in the Netherlands Soil Monitoring Network (NSMN; 704 samples) and in a European-wide transect (73 samples). The selection of sites was based on a representative sample of major soil texture types...... of the bacterial inoculum. The CLPP in Dutch and European soil samples appeared to be reproducible and sensitive to land use and/or soil texture. Although the method is selective, CLPP based parameters correlated well with other microbial parameters and soil characteristics. Consistent patterns in CLPP and soil...... habitat characteristics are emerging, as brought about by environmental disturbances, land management and soil texture. The applicability of CLPP analysis in monitoring systems is discussed....

  11. Bioavailability-Based In Situ Remediation To Meet Future Lead (Pb) Standards in Urban Soils and Gardens.

    Science.gov (United States)

    Henry, Heather; Naujokas, Marisa F; Attanayake, Chammi; Basta, Nicholas T; Cheng, Zhongqi; Hettiarachchi, Ganga M; Maddaloni, Mark; Schadt, Christopher; Scheckel, Kirk G

    2015-08-04

    Recently the Centers for Disease Control and Prevention lowered the blood Pb reference value to 5 μg/dL. The lower reference value combined with increased repurposing of postindustrial lands are heightening concerns and driving interest in reducing soil Pb exposures. As a result, regulatory decision makers may lower residential soil screening levels (SSLs), used in setting Pb cleanup levels, to levels that may be difficult to achieve, especially in urban areas. This paper discusses challenges in remediation and bioavailability assessments of Pb in urban soils in the context of lower SSLs and identifies research needs to better address those challenges. Although in situ remediation with phosphate amendments is a viable option, the scope of the problem and conditions in urban settings may necessitate that SSLs be based on bioavailable rather than total Pb concentrations. However, variability in soil composition can influence bioavailability testing and soil amendment effectiveness. More data are urgently needed to better understand this variability and increase confidence in using these approaches in risk-based decision making, particularly in urban areas.

  12. Soil Sampling Operating Procedure

    Science.gov (United States)

    EPA Region 4 Science and Ecosystem Support Division (SESD) document that describes general and specific procedures, methods, and considerations when collecting soil samples for field screening or laboratory analysis.

  13. The DSM-5 Self-Rated Level 1 Cross-Cutting Symptom Measure as a Screening Tool.

    Science.gov (United States)

    Bastiaens, Leo; Galus, James

    2018-03-01

    The DSM-5 Self-Rated Level 1 Cross-Cutting Symptom Measure was developed to aid clinicians with a dimensional assessment of psychopathology; however, this measure resembles a screening tool for several symptomatic domains. The objective of the current study was to examine the basic parameters of sensitivity, specificity, positive and negative predictive power of the measure as a screening tool. One hundred and fifty patients in a correctional community center filled out the measure prior to a psychiatric evaluation, including the Mini International Neuropsychiatric Interview screen. The above parameters were calculated for the domains of depression, mania, anxiety, and psychosis. The results showed that the sensitivity and positive predictive power of the studied domains was poor because of a high rate of false positive answers on the measure. However, when the lowest threshold on the Cross-Cutting Symptom Measure was used, the sensitivity of the anxiety and psychosis domains and the negative predictive values for mania, anxiety and psychosis were good. In conclusion, while it is foreseeable that some clinicians may use the DSM-5 Self-Rated Level 1 Cross-Cutting Symptom Measure as a screening tool, it should not be relied on to identify positive findings. It functioned well in the negative prediction of mania, anxiety and psychosis symptoms.

  14. The mediating role of the home environment in relation to parental educational level and preschool children's screen time: a cross-sectional study.

    Science.gov (United States)

    Määttä, Suvi; Kaukonen, Riikka; Vepsäläinen, Henna; Lehto, Elviira; Ylönen, Anna; Ray, Carola; Erkkola, Maijaliisa; Roos, Eva

    2017-09-02

    Previous studies suggest that preschoolers from low socioeconomic backgrounds engage in more screen time. Still, the factors in the social and physical home environment driving these differences in preschool children's screen time are poorly understood. This study examines potential home environment mediators in the associations between parental educational level and preschoolers' screen time. A total of 864 children aged 3-6 years and their parents participated in a cross-sectional DAGIS study in 2015-2016. Parents recorded their children's screen time in a diary (N = 823). For the analyses, the daily average screen time at home was calculated. Parental questionnaires (N = 808) assessed educational level and eight social and physical environment factors in the home (i.e., descriptive norm for children's screen time, parental screen use in front of children, parental importance for limiting children's screen time, parental attitude toward societal pressures for children's screen time, access to screens at home, parental self-efficacy for limiting children's screen time, satisfaction of children's screen time, and rules for limiting children's screen time). Parental education was grouped into low, middle, and high education. The associations were tested by conducting mediation analyses adjusted by season and children's sex and age. The significant mediators in the single-mediator models were included in the final multiple-mediator models. Of the potential eight mediators, the following four had a significant indirect association: descriptive norm for children's screen time, parental screen use in front of children, parental importance for limiting children's screen time, and parental attitude toward societal pressures for children's screen time. Parents with high education had lower descriptive norm and used fewer screens in front of children compared to parents with middle or low education, and in turn, these factors were associated with less screen time among

  15. Ecohydrological role of biological soil crusts across a gradient in levels of development

    Science.gov (United States)

    Whitney, Kristen M.; Vivoni, Enrique R.; Duniway, Michael C.; Bradford, John B.; Reed, Sasha C.; Belnap, Jayne

    2017-01-01

    Though biological soil crusts (biocrusts) form abundant covers in arid and semiarid regions, their competing effects on soil hydrologic conditions are rarely accounted for in models. This study presents the modification of a soil water balance model to account for the presence of biocrusts at different levels of development (LOD) and their impact on one-dimensional hydrologic processes during warm and cold seasons. The model is developed, tested, and applied to study the hydrologic controls of biocrusts in context of a long-term manipulative experiment equipped with meteorological and soil moisture measurements in a Colorado Plateau ecosystem near Moab, Utah. The climate manipulation treatments resulted in distinct biocrust communities, and model performance with respect to soil moisture was assessed in experimental plots with varying LOD as quantified through a field-based roughness index (RI). Model calibration and testing yielded excellent comparisons to observations and smooth variations of biocrust parameters with RI approximated through simple regressions. The model was then used to quantify how LOD affects soil infiltration, evapotranspiration, and runoff under calibrated conditions and in simulation experiments with gradual modifications in biocrust porosity and hydraulic conductivity. Simulation results show that highly developed biocrusts modulate soil moisture nonlinearly with LOD by altering soil infiltration and buffering against evapotranspiration losses, with small impacts on runoff. The nonlinear and threshold variations of the soil water balance in the presence of biocrusts of varying LOD helps explain conflicting outcomes of various field studies and sheds light on the ecohydrological role of biocrusts in arid and semiarid ecosystems.

  16. Diverse Soil Carbon Dynamics Expressed at the Molecular Level

    Science.gov (United States)

    van der Voort, T. S.; Zell, C. I.; Hagedorn, F.; Feng, X.; McIntyre, C. P.; Haghipour, N.; Graf Pannatier, E.; Eglinton, T. I.

    2017-12-01

    The stability and potential vulnerability of soil organic matter (SOM) to global change remain incompletely understood due to the complex processes involved in its formation and turnover. Here we combine compound-specific radiocarbon analysis with fraction-specific and bulk-level radiocarbon measurements in order to further elucidate controls on SOM dynamics in a temperate and subalpine forested ecosystem. Radiocarbon contents of individual organic compounds isolated from the same soil interval generally exhibit greater variation than those among corresponding operationally defined fractions. Notably, markedly older ages of long-chain plant leaf wax lipids (n-alkanoic acids) imply that they reflect a highly stable carbon pool. Furthermore, marked 14C variations among shorter- and longer-chain n-alkanoic acid homologues suggest that they track different SOM pools. Extremes in SOM dynamics thus manifest themselves within a single compound class. This exploratory study highlights the potential of compound-specific radiocarbon analysis for understanding SOM dynamics in ecosystems potentially vulnerable to global change.

  17. Soil-plant transfer models for metals to improve soil screening value guidelines valid for São Paulo, Brazil.

    NARCIS (Netherlands)

    Dos Santos-Araujo, Sabrina N; Swartjes, Frank A; Versluijs, Kees W; Moreno, Fabio Netto; Alleoni, Luís R F

    2017-01-01

    In Brazil, there is a lack of combined soil-plant data attempting to explain the influence of specific climate, soil conditions, and crop management on heavy metal uptake and accumulation by plants. As a consequence, soil-plant relationships to be used in risk assessments or for derivation of soil

  18. Soil-structure interaction effects on high level waste tanks

    International Nuclear Information System (INIS)

    Miller, C.A.; Costantino, C.J.; Heymsfeld, E.

    1991-01-01

    High Level Waste Tanks consist of steel tanks located in concrete vaults which are usually completely embedded in the soil. Many of these tanks are old and were designed to seismic standards which are not compatible with current requirements. The objective if this paper is to develop simple methods of modeling SSI effects for such structures and to obtain solutions for a range of parameters that can be used to identify significant aspects of the problem

  19. Assessment of groundwater, soil-gas, and soil contamination at the Vietnam Armor Training Facility, Fort Gordon, Georgia, 2009-2011

    Science.gov (United States)

    Guimaraes, Wladmir B.; Falls, W. Fred; Caldwell, Andral W.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2012-01-01

    detected above their respective method detection levels were naphthalene, 2-methyl-naphthalene, tridecane, 1,2,4-trimethylbenzene, and perchloroethylene. After the results of the 71 soil-gas samplers were received, 31 additional passive soil-gas samplers were deployed on July 14, 2011, and retrieved on July 18, 2011. These 31 samplers were deployed on a larger areal scale to better define the extent of the contamination. Total petroleum hydrocarbons were detected above their method detection level at all 31 samplers, whereas BTEX was detected above its method detection level at 17 of the 31 samplers. Other organic compounds detected above their method detection levels were naphthalene, 2-methyl-naphthalene, octane, undecane, tridecane, pentadecane, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, chloroform, and perchloroethylene. Subsequent to the 2010 soil-gas survey, four areas determined to have elevated contaminant mass were selected and sampled for explosives and chemical agents. No detections of explosives or chemical agents above their respective method detection levels were found at any of the sampling locations. The same four locations that were sampled for explosives and chemical agents were selected for the collection of soil samples. A fifth location also was selected on the basis of the elevated contaminant mass of the soil-gas survey. No metals that exceeded the Regional Screening Levels for Industrial Soils, as classified by the U.S. Environmental Protection Agency, were detected at any of the five VATF locations. The soil samples also were compared to values from the ambient, uncontaminated (background) levels for soils in South Carolina, as classified by the South Carolina Department of Health and Environmental Control. Because South Carolina is adjacent to Georgia and the soils in the Coastal Plain are similar, these comparisons are valid. No similar values are available for Georgia to use for comparison purposes. The metals that were detected above the

  20. Availability of polycyclic aromatic hydrocarbons to earthworms in urban soils and its implications for risk assessment.

    Science.gov (United States)

    Cachada, A; Coelho, C; Gavina, A; Dias, A C; Patinha, C; Reis, A P; da Silva, E Ferreira; Duarte, A C; Pereira, R

    2018-01-01

    Polycyclic aromatic hydrocarbons (PAHs) are a global problem, and in urban soils they can be found at potentially hazard levels. Nevertheless, the real risks that these contaminants pose to the environment are not well known, since the bioavailability of PAHs in urban soils has been poorly studied. Therefore, the bioavailability of PAHs in some selected urban soils from Lisbon (Portugal) was evaluated. Moreover, the applicability of a first screening phase based on total contents of PAHs was assessed. Results show that bioavailability of PAHs is reduced (low levels in earthworms, low accumulation percentages, and low biota-to-soil accumulation factors values), especially in more contaminated soils. The aging of these compounds explains this low availability, and confirms the generally accepted assumption that accumulation of PAHs in urban areas is mostly related with a long-term deposition of contaminated particles. The comparison of measured PAHs concentrations in earthworm tissues with the ones predicted based on theoretical models, reinforce that risks based on total levels are overestimated, but it can be a good initial approach for urban soils. This study also highlights the need of more reliable ecotoxicological data. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. The Effect of Maternal Body Composition and Triglyceride Levels on Newborn Weight in Non-Diabetic Women with Positive Diabetic Screens

    OpenAIRE

    Cüneyt Eftal Taner; Seçil Kurtulmuş; Ümit Nayki; Ayşen Kızılyar; Yasemin Baskın

    2008-01-01

    OBJECTIVE: To determine the effect of maternal body composition and triglyceride levels on newborn weight in nondiabetic women with positive diabetic screening. STUDY DESIGN : 40 pregnant women with positive diabetic screenings and negative glucose tolerance tests were enrolled as the study group. 72 pregnant women with negative diabetic screenings were enrolled as the control group. 50-gram glucose challenge tests were performed at 24-32 weeks of gestations and serum lipid levels were mea...

  2. Estimation of Soil Nitrate (NO3) Level Using Laser-Induced Breakdown Spectroscopy (LIBS)

    Science.gov (United States)

    Angkat, A. R.; Seminar, K. B.; Rahmat, M.; Sutandi, A.

    2018-05-01

    Laser-Induced Breakdown Spectroscopy (LIBS) is a method for measuring level of nitrogen (N) in the soil in the form of N-nitrate (NO3) rapidly without going through the process of sieving and drying. The sample soil in the form of pellets subjected to laser pulses using a wavelength of 532 nm, pulse duration 5.5 ns, repetition rate of 10 Hz, and Q-switch delay of 150 μs. Emissions are captured by the spectrometer with the wavelength range of 190-1130 nm. Spectrum characterization was processed through the second derivative in order to obtain a wavelength identity that could be rapidly used to estimate the nitrate content of the soil with a determination coefficient of (R2) 0.9254 and a coefficient of variation (CV) of 8.41%. The results of this study are very potential to be applied for rapid measurement of soil nitrate.

  3. Lipase assay in soils by copper soap colorimetry.

    Science.gov (United States)

    Saisuburamaniyan, N; Krithika, L; Dileena, K P; Sivasubramanian, S; Puvanakrishnan, R

    2004-07-01

    A simple and sensitive method for the estimation of lipase activity in soils is reported. In this method, 50mg of soil is incubated with emulsified substrate, the fatty acids liberated are treated with cupric acetate-pyridine reagent, and the color developed is measured at 715 nm. Use of olive oil in this protocol leads to an estimation of true lipase activity in soils. The problem of released fatty acids getting adsorbed onto the soil colloids is obviated by the use of isooctane, and separate standards for different soils need not be developed. Among the various surfactants used for emulsification, polyvinyl alcohol is found to be the most effective. Incubation time of 20 min, soil concentration of 50 mg, pH 6.5, and incubation temperature of 37 degrees C were found to be the most suitable conditions for this assay. During the process of enrichment of the soils with oil, interference by the added oil is avoided by the maintenance of a suitable control, wherein 50 mg of soil is added after stopping the reaction. This assay is sensitive and it could be adopted to screen for lipase producers from enriched soils and oil-contaminated soils before resorting to isolation of the microbes by classical screening methods.

  4. Plant-uptake of uranium: Hydroponic and soil system studies

    Science.gov (United States)

    Ramaswami, A.; Carr, P.; Burkhardt, M.

    2001-01-01

    Limited information is available on screening and selection of terrestrial plants for uptake and translocation of uranium from soil. This article evaluates the removal of uranium from water and soil by selected plants, comparing plant performance in hydroponic systems with that in two soil systems (a sandy-loam soil and an organic-rich soil). Plants selected for this study were Sunflower (Helianthus giganteus), Spring Vetch (Vicia sativa), Hairy Vetch (Vicia villosa), Juniper (Juniperus monosperma), Indian Mustard (Brassica juncea), and Bush Bean (Phaseolus nanus). Plant performance was evaluated both in terms of the percent uranium extracted from the three systems, as well as the biological absorption coefficient (BAC) that normalized uranium uptake to plant biomass. Study results indicate that uranium extraction efficiency decreased sharply across hydroponic, sandy and organic soil systems, indicating that soil organic matter sequestered uranium, rendering it largely unavailable for plant uptake. These results indicate that site-specific soils must be used to screen plants for uranium extraction capability; plant behavior in hydroponic systems does not correlate well with that in soil systems. One plant species, Juniper, exhibited consistent uranium extraction efficiencies and BACs in both sandy and organic soils, suggesting unique uranium extraction capabilities.

  5. Levels of /sup 137/Cs in soils and vegetation of West Malaysia

    Energy Technology Data Exchange (ETDEWEB)

    Lowe, B G [Link Systems Ltd., High Wycombe (UK)

    1978-05-01

    Samples of topsoils and vegetation from a wide distribution of sites in West Malaysia have been analysed for their /sup 137/Cs content by gross gamma-ray spectrometry using a Ge(Li) detector. The levels of contamination ranged up to 6.7 nCi/m/sup 2/ in soils from peak locations and up to 24 nCi/m/sup 2/ in one nonpeak location. There was an indication of a possible preferential scavenging effect by rainfall during the south west monsoon period (May to September) making levels in the western rainfall zone slightly higher than in the eastern rainfall zone. The levels in canopy leaves were shown to be strongly correlated with the presence of epiphyllae colonies on their surfaces, causing an enhanced interception of aerosols. The highest level recorded in canopy leaves was 3.7 pCi/g and corresponded to 70% of the leaves harboring epiphyllae colonies. Levels from epiphytic lichens and mosses ranged from 0.23 to 1.3 pCi/g and up to 4.2 pCi/g for ferns. The data on soil samples suggest that West Malaysia has intercepted a minimum of 522 Ci of /sup 137/Cs from past nuclear weapons testing as of March 1974.

  6. Factors influencing U(VI adsorption onto soil from a candidate very low level radioactive waste disposal site in China

    Directory of Open Access Journals (Sweden)

    Zuo Rui

    2016-01-01

    Full Text Available The properties of soil at disposal sites are very important for geological disposal of very low level radioactive waste in terms of U(VI. In this study, soil from a candidate very low level radioactive waste disposal site in China was evaluated for its capacity on uranium sorption. Specifically, the equilibrium time, initial concentration, soil particle, pH, temperature, and carbonate were evaluated. The results indicated that after 15-20 days of sorption, the Kd value fluctuated and stabilized at 355-360 mL/g. The adsorptive capacity of uranium was increased as the initial uranium concentration increased, while it decreased as the soil particle size increased. The pH value played an important role in the U(VI sorption onto soil, especially under alkaline conditions, and had a great effect on the sorption capacity of soil for uranium. Moreover, the presence of carbonate decreased the sorption of U(VI onto soil because of the role of the strong complexation of carbonate with U(VI in the groundwater. Overall, this study assessed the behavior of U(VI sorption onto natural soil, which would be an important factor in the geological barrier of the repository, has contribution on mastering the characteristic of the adsorption of uranium in the particular soil media for the process of very low level radioactive waste disposal.

  7. Functional and community-level soil microbial responses to zinc addition may depend on test system biocomplexity.

    NARCIS (Netherlands)

    Sverdrup, L.E.; Linjordet, R.; Stomman, G.; Hagen, S.B.; van Gestel, C.A.M.; Frostegard, A.; Sorheim, R.

    2006-01-01

    The effect of zinc on soil nitrification and composition of the microbial community in soil was investigated using a full factorial experiment with five zinc concentrations and four levels of biological complexity (microbes only, microbes and earthworms (Eisenia fetida), microbes and Italian

  8. Screening identification of aerobic denitrification bacteria with high soil desalinization capacity

    Science.gov (United States)

    Jin, H.; Chen, H.; Jin, H.; Qian, Y.; Zhang, K.

    2017-08-01

    In order to study the mechanism of bacteria used in the saline soil remediation process, the aerobic denitrification bacteria were isolated from an agricultural greenhouse soil in a farm in East China’s Zhejiang Province. The identification, nitrogen reducing characteristics and the denitrification effect of bacteria from different soils at various locations were investigated. The results showed that the NO3- removal rate was 91% with bacteria from the greenhouse soil under aerobic conditions in 52 h, and the bacteria were identified as Gram-positive Castellaniella denitrification bacteria.

  9. Effects of water level on three wetlands soil seed banks on the Tibetan Plateau.

    Directory of Open Access Journals (Sweden)

    Miaojun Ma

    Full Text Available BACKGROUND: Although the effect of water level on germination in soil seed banks has been documented in many ecosystems, the mechanism is not fully understood, and to date no empirical studies on this subject exist. Further, no work has been done on the effect of water level on seed banks of drying and saline-alkaline wetlands in alpine areas on the Tibetan Plateau. METHODOLOGY: We examined the effects of water level (0 cm, 5 cm and 10 cm on seed germination and seedling establishment from soil seed banks at 0-5 cm and 5-10 cm depths in typical, drying, and saline-alkaline wetlands. We also explore the potential role of soil seed bank in restoration of drying and saline-alkaline wetlands. PRINCIPAL FINDINGS: Species richness decreased with increase in water level, but there almost no change in seed density. A huge difference exists in species composition of the seed bank among different water levels in all three wetlands, especially between 0 cm and 5 cm and 0 cm and 10 cm. Similarity of species composition between seed bank and plant community was higher in 0 cm water level in drying wetland than in the other two wetlands. The similarity was much higher in 0 cm water level than in 5 cm and 10 cm water levels in all three wetlands. Species composition of the alpine wetland plant community changed significantly after drying and salinization, however, species composition of the seed bank was unchanged regardless of the environment change. CONCLUSIONS/SIGNIFICANCE: Water level greatly affects seed bank recruitment and plant community establishment. Further, different water levels in restored habitats are likely to determine its species composition of the plant community. The seed bank is important in restoration of degraded wetlands. Successful restoration of drying and salinization wetlands could depend on the seed bank.

  10. An approximate-reasoning-based method for screening high-level waste tanks for flammable gas

    International Nuclear Information System (INIS)

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    1998-01-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at Hanford have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop an improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. AR models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. The authors performed a pilot study to investigate the utility of AR for flammable gas screening. They found that the effort to implement such a model was acceptable and that computational requirements were reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts

  11. An Approximate Reasoning-Based Method for Screening High-Level-Waste Tanks for Flammable Gas

    International Nuclear Information System (INIS)

    Eisenhawer, Stephen W.; Bott, Terry F.; Smith, Ronald E.

    2000-01-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at the Hanford site have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop an improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. Approximate-reasoning models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. In a pilot study to investigate the utility of AR for flammable gas screening, the effort to implement such a model was found to be acceptable, and computational requirements were found to be reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts

  12. An approximate reasoning-based method for screening high-level-waste tanks for flammable gas

    International Nuclear Information System (INIS)

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    2000-01-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at the Hanford site have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop and improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. Approximate-reasoning models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. In a pilot study to investigate the utility of AR for flammable gas screening, the effort to implement such a model was found to be acceptable, and computational requirements were found to be reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts

  13. An approximate reasoning-based method for screening high-level-waste tanks for flammable gas

    Energy Technology Data Exchange (ETDEWEB)

    Eisenhawer, S.W.; Bott, T.F.; Smith, R.E.

    2000-06-01

    The in situ retention of flammable gas produced by radiolysis and thermal decomposition in high-level waste can pose a safety problem if the gases are released episodically into the dome space of a storage tank. Screening efforts at the Hanford site have been directed at identifying tanks in which this situation could exist. Problems encountered in screening motivated an effort to develop and improved screening methodology. Approximate reasoning (AR) is a formalism designed to emulate the kinds of complex judgments made by subject matter experts. It uses inductive logic structures to build a sequence of forward-chaining inferences about a subject. Approximate-reasoning models incorporate natural language expressions known as linguistic variables to represent evidence. The use of fuzzy sets to represent these variables mathematically makes it practical to evaluate quantitative and qualitative information consistently. In a pilot study to investigate the utility of AR for flammable gas screening, the effort to implement such a model was found to be acceptable, and computational requirements were found to be reasonable. The preliminary results showed that important judgments about the validity of observational data and the predictive power of models could be made. These results give new insights into the problems observed in previous screening efforts.

  14. Chemical evolution of leaked high-level liquid wastes in Hanford soils

    Energy Technology Data Exchange (ETDEWEB)

    NYMAN,MAY D.; KRUMHANSL,JAMES L.; ZHANG,PENGCHU; ANDERSON,HOWARD L.; NENOFF,TINA M.

    2000-05-19

    A number of Hanford tanks have leaked high level radioactive wastes (HLW) into the surrounding unconsolidated sediments. The disequilibrium between atmospheric C0{sub 2} or silica-rich soils and the highly caustic (pH > 13) fluids is a driving force for numerous reactions. Hazardous dissolved components such as {sup 133}Cs, {sup 79}Se, {sup 99}Tc may be adsorbed or sequestered by alteration phases, or released in the vadose zone for further transport by surface water. Additionally, it is likely that precipitation and alteration reactions will change the soil permeability and consequently the fluid flow path in the sediments. In order to ascertain the location and mobility/immobility of the radionuclides from leaked solutions within the vadose zone, the authors are currently studying the chemical reactions between: (1) tank simulant solutions and Hanford soil fill minerals; and (2) tank simulant solutions and C0{sub 2}. The authors are investigating soil-solution reactions at: (1) elevated temperatures (60--200 C) to simulate reactions which occur immediately adjacent a radiogenically heated tank; and (2) ambient temperature (25 C) to simulate reactions which take place further from the tanks. The authors studies show that reactions at elevated temperature result in dissolution of silicate minerals and precipitation of zeolitic phases. At 25 C, silicate dissolution is not significant except where smectite clays are involved. However, at this temperature CO{sub 2} uptake by the solution results in precipitation of Al(OH){sub 3} (bayerite). In these studies, radionuclide analogues (Cs, Se and Re--for Tc) were partially removed from the test solutions both during high-temperature fluid-soil interactions and during room temperature bayerite precipitation. Altered soils would permanently retain a fraction of the Cs but essentially all of the Se and Re would be released once the plume was past and normal groundwater came in contact with the contaminated soil. Bayerite

  15. Chemical evolution of leaked high-level liquid wastes in Hanford soils

    International Nuclear Information System (INIS)

    NYMAN, MAY D.; KRUMHANSL, JAMES L.; ZHANG, PENGCHU; ANDERSON, HOWARD L.; NENOFF, TINA M.

    2000-01-01

    A number of Hanford tanks have leaked high level radioactive wastes (HLW) into the surrounding unconsolidated sediments. The disequilibrium between atmospheric C0 2 or silica-rich soils and the highly caustic (pH > 13) fluids is a driving force for numerous reactions. Hazardous dissolved components such as 133 Cs, 79 Se, 99 Tc may be adsorbed or sequestered by alteration phases, or released in the vadose zone for further transport by surface water. Additionally, it is likely that precipitation and alteration reactions will change the soil permeability and consequently the fluid flow path in the sediments. In order to ascertain the location and mobility/immobility of the radionuclides from leaked solutions within the vadose zone, the authors are currently studying the chemical reactions between: (1) tank simulant solutions and Hanford soil fill minerals; and (2) tank simulant solutions and C0 2 . The authors are investigating soil-solution reactions at: (1) elevated temperatures (60--200 C) to simulate reactions which occur immediately adjacent a radiogenically heated tank; and (2) ambient temperature (25 C) to simulate reactions which take place further from the tanks. The authors studies show that reactions at elevated temperature result in dissolution of silicate minerals and precipitation of zeolitic phases. At 25 C, silicate dissolution is not significant except where smectite clays are involved. However, at this temperature CO 2 uptake by the solution results in precipitation of Al(OH) 3 (bayerite). In these studies, radionuclide analogues (Cs, Se and Re--for Tc) were partially removed from the test solutions both during high-temperature fluid-soil interactions and during room temperature bayerite precipitation. Altered soils would permanently retain a fraction of the Cs but essentially all of the Se and Re would be released once the plume was past and normal groundwater came in contact with the contaminated soil. Bayerite, however, will retain significant

  16. Determination of Tetracycline and Fluoroquinolone Antibiotics at Trace Levels in Sludge and Soil

    Directory of Open Access Journals (Sweden)

    Marie-Virginie Salvia

    2015-01-01

    Full Text Available This work describes the development of a sensitive analytical method to determine simultaneously traces of tetracycline and fluoroquinolone antibiotics in sludge and soil, based on PLE extraction, followed by SPE purification and finally an analysis by LC-MS/MS. Recoveries were greater than 87% in the case of fluoroquinolones and between 25.4 and 41.7% for tetracyclines. Low relative standard deviations (<15% were obtained in both matrices. The limits of quantification were comprised between 1.1 and 4.6 ng/g and between 5 and 20 ng/g in soil and sludge, respectively. The method was then successfully applied to the analysis of the target antibiotics in sludge as well as soil that received spreading. The substances most frequently found and with the highest levels were fluoroquinolones with concentrations exceeding 1,000 ng/g in several samples of sludge and up to 16 ng/g in soil.

  17. Screening of soil corrosivity by field testing: Results and design of an electrochemical soil corrosion probe

    DEFF Research Database (Denmark)

    Nielsen, Lars vendelbo; Bruun, Niels Kåre

    1996-01-01

    The corrosivity of different types of soil have been assessed by exposing carbon-steel plates at 50 different locations in Denmark for an extended period of time. The investigations included weight loss measurements and analysis of the chemical compositions of the corrosion products formed...... on the plates during exposure. An electrochemical soil corrosion probe has been designed and manufactured allowing for simultaneous measurements of several qauntities to predict corrosion. The probe consists of individual sections capable of measuring redox-potential, corrosion potential, soil resistivity...

  18. Impact of groundwater levels on evaporation and water-vapor fluxes in highly saline soils

    Science.gov (United States)

    Munoz, J. F.; Hernández, M. F.; Braud, I.; Gironas, J. A.; Suarez, F. I.

    2012-12-01

    In aquifers of arid and hyper-arid zones, such as those occurring in the Chilean Andes high plateau, it is important to determine both the quantity and location of water discharges at the temporal scales of interest to close the basin's water budget and thus, to manage the water resource properly. In zones where shallow aquifers are the main source of water, overexploitation of the water resource changes the dynamics of water, heat and solute transport in the vadose zone. As aquifers are exploited, fluctuations in depth to groundwater are exacerbated. These fluctuations modify both soil structure and evaporation from the ground, which is typically the most important discharge from the water budget and is very difficult to estimate. Therefore, a correct quantification of evaporation from these soils is essential to improve the accuracy of the water balance estimation. The objective of this study was to investigate the evaporation processes and water-vapor fluxes in a soil column filled with a saline soil from the Salar del Huasco basin, Chile. Water content, electrical conductivity and temperature at different depths in the soil profile were monitored to determine the liquid and vapor fluxes within the soil column. The results showed that evaporation is negligible when the groundwater table is deeper than 1 m. For shallower groundwater levels, evaporation increases in an exponential fashion reaching a value of 3 mm/day when the groundwater table is near the surface of the ground. These evaporation rates are on the same order of magnitude than the field measurements, but slightly lower due to the controlled conditions maintained in the laboratory. Isothermal fluid fluxes were predominant over the non-isothermal fluid and water vapor fluxes. The net flux for all the phreatic levels tested in the laboratory showed different behaviors, with ascending or descending flows as a consequence of changes in water content and temperature distribution within the soil. It was

  19. LOSS OF ORGANIC CHEMICALS IN SOIL: PURE COMPOUND TREATABILITY STUDIES

    Science.gov (United States)

    Comprehensive screening data on the treatability of 32 organic chemicals in soil were developed. Of the evaluated chemicals, 22 were phenolic compounds. Aerobic batch laboratory microcosm experiments were conducted using two soils: an acidic clay soil with <1% organic matter and ...

  20. Phosphorus levels in soil and lettuce production due to phosphorus fertilization

    Directory of Open Access Journals (Sweden)

    José Ricardo Mantovani

    2014-09-01

    Full Text Available The leafy vegetables are considered nutrient-demanding, but are scarce in the literature works about phosphorus fertilization. This study aimed to evaluate the effect of phosphate on the production of lettuce, content and amount of P accumulated in leaf plants, and to relate levels of P in the clayey soil with plant production. The experiment was conducted in a greenhouse in pots in a randomized block design with ten treatments and four replications. The treatments were made up of P, corresponding to 0, 50, 100, 150, 200, 300, 400, 500, 600 and 700 mg dm-3, as triple superphosphate powder. Portions of 6 dm3 of the clay soil (420 g kg-1 clay received lime, aimed at raising the V % soil to 70 %, equivalent to 20 t ha-1 of cattle manure, and the phosphate fertilizer according to the treatments, remaining incubated for about 30 days. At the end of incubation, each pot received a change of lettuce cultivar Verônica. The plant harvesting was performed 39 days after transplanting the seedlings. O P gave large increases in growth and production of lettuce, and culture responded positively to the application of high doses of the nutrient. A dose of 350 mg dm-3, equivalent to 800 kg ha-1 P2O5, was the most suitable for growing lettuce in the clay soil. In this work conditions, the phosphorus fertilizations it was necessary when the P-Mehlich contents in the clay soil were less than 75 mg dm-3.

  1. Ecological and health risk-based characterization of agricultural soils contaminated with polycyclic aromatic hydrocarbons in the vicinity of a chemical plant in China.

    Science.gov (United States)

    Liu, Geng; Niu, Junjie; Guo, Wenjiong; An, Xiangsheng; Zhao, Long

    2016-11-01

    Polycyclic aromatic hydrocarbons (PAHs) from chemical plants can cause serious pollution of surrounding agricultural soils. A comprehensive study of agricultural soils was conducted in the vicinity of a chemical plant in China to characterize the soil PAH concentration, as well as their composition and sources. Human health and a screening-level ecological risk assessment were conducted for PAH contamination in agricultural soils. The results showed that the total concentrations of 16 priority PAHs ranged from 250.49 to 9387.26 ng g(-1), with an average of 2780.42 ng g(-1). High molecular weight PAHs (four to six rings) were the dominant component, accounting for more than 60% of all PAHs. Principal component analysis (PCA) and positive matrix factorization model (PMF) suggested that diesel emissions, coal combustion, coke ovens, and fuel combustion and gasoline emissions were the main sources of PAHs in agricultural soils. The ecological risk assessment results based on the effects range-low (ERL), the effects range-median (ERM), and the ecological screening levels (ESL) indicated that the exposure to ∑PAH16 was >ERL, >ERM, and ≥ERL and ESL at 78.1% of the soil sampling stations, and could induce biological effects in mammals. The Bapeq concentrations posed a potential carcinogenic risk to humans. Further risk management and control of soil PAHs in these agricultural soils is required to ensure the safety of the biocoenosis and human health. Copyright © 2016 Elsevier Ltd. All rights reserved.

  2. The contrasting responses of soil microorganisms in two rice cultivars to elevated ground-level ozone

    International Nuclear Information System (INIS)

    Feng, Youzhi; Yu, Yongjie; Tang, Haoye; Zu, Qianhui; Zhu, Jianguo; Lin, Xiangui

    2015-01-01

    Although elevated ground-level O 3 has a species–specific impact on plant growth, the differences in soil biota responses to O 3 pollution among rice cultivars are rarely reported. Using O 3 Free-Air Concentration Enrichment, the responses of the rhizospheric bacterial communities in the O 3 -tolerant (YD6) and the O 3 -sensitive (IIY084) rice cultivars to O 3 pollution and their differences were assessed by pyrosequencing at rice tillering and anthesis stages. Elevated ground-level O 3 negatively influenced the bacterial community in cultivar YD6 at both rice growth stages by decreasing the bacterial phylogenetic diversities and response ratios. In contrast, in cultivar IIY084, the bacterial community responded positively at the rice tillering stage under O 3 pollution. However, several keystone bacterial guilds were consistently negatively affected by O 3 pollution in two rice cultivars. These findings indicate that continuously O 3 pollution would negatively influence rice agroecosystem and the crop cultivar is important in determining the soil biota responses to elevated O 3 . - Highlights: • We investigated the soil biota in two rice cultivars in presence of elevated O 3 . • The contrasting responses of soil biota were found between two rice cultivars. • Some keystone bacterial guilds were consistently negatively affected by O 3 pollution. • The crop cultivar is important in determining soil biota responses to elevated O 3 . - The crop cultivar is important in determining the soil biota responses to elevated O 3

  3. Soil contamination studies

    International Nuclear Information System (INIS)

    1997-06-01

    The objective of this project was to develop a quick screening method that accurately identifies and quantifies the amount of alpha-emitting radionuclides in infinitely-thick soil samples using a Frisch grid ionization chamber. An additional objective of the work was to provide the US Department of Energy, Nevada Operations Office and its contractors with information on the theoretical and actual measured results of atmospheric testing contamination of soil and water at the Nevada Test Site through a comprehensive search of existing literature

  4. Soil and water nitrate levels in relation to fertilizer utilization in Yugoslavia

    International Nuclear Information System (INIS)

    Filipovic, R.; Stevanovic, D.

    1980-01-01

    The results of a number of field experiments and monitoring of drainage canals close to intensive agricultural production involving the application of mineral fertilizers are reported. The object was to determine whether the pollution potential of underground and derived surface waters by nitrates and phosphates could be expressed as a function of the applied doses of fertilizer, method of application, climate, soil, etc. Analytical data indicated that, in surface waters adjacent to fertilized land, nitrate levels were higher than those of surface waters adjacent to unfertilized land. Preliminary results on the distribution of NO 3 down the soil profile following the application of 15 N-labelled ammonium nitrate to maize indicated downward movement of the labelled nitrate below the 100-cm depth. Application of organic matter with the fertilizer apparently retarded the leaching process. Soil-surface drainage water was characterized by high P/N ratios. (author)

  5. Background levels of some trace elements in sandy soil of Abou-Zabal, and its variation with soil depth determines by neutron activation analysis. Vol. 4

    International Nuclear Information System (INIS)

    Abdel-Sabour, M.F.; Sanad, W.; Flex, H.; Abdel-Haleem, A.S.; Zohny, E.

    1996-01-01

    The variation in soil total heavy metal contents (horizontally and vertically) in small land area (about one acre) was investigated using neutron activities analysis technique. The background levels found in the sandy soil of Abou-Zabal are also discussed in relation to the findings of other workers. 5 tabs

  6. Background levels of some trace elements in sandy soil of Abou-Zabal, and its variation with soil depth determines by neutron activation analysis. Vol. 4.

    Energy Technology Data Exchange (ETDEWEB)

    Abdel-Sabour, M F [Soil Pollution Unit, Soil and Water Department. Nuclear Research Center, Atomic energy Authority, Cairo, (Egypt); Sanad, W; Flex, H; Abdel-Haleem, A S [Hot Lab. Center, Atomic Energy Authority, Cairo (Egypt); Zohny, E [Physics Department, Faculty of Science, Cairo Univ., Beni-Sweif Branch, Cairo, (Egypt)

    1996-03-01

    The variation in soil total heavy metal contents (horizontally and vertically) in small land area (about one acre) was investigated using neutron activities analysis technique. The background levels found in the sandy soil of Abou-Zabal are also discussed in relation to the findings of other workers. 5 tabs.

  7. Remediation of uranium-contaminated soil using the Segmented Gate System and containerized vat leaching techniques: a cost effectiveness study

    International Nuclear Information System (INIS)

    Cummings, M.; Booth, S.R.

    1996-01-01

    Because it is difficult to characterize heterogeneously contaminated soils in detail and to excavate such soils precisely using heavy equipment, it is common for large quantities of uncontaminated soil to be removed during excavation of contaminated sites. Until now, volume reduction of radioactively contaminated soil depended upon manual screening and analysis of samples, a costly and impractical approach, particularly with large volumes of heterogeneously contaminated soil. The baseline approach for the remediation of soils containing radioactive waste is excavation, pretreatment, containerization, and disposal at a federally permitted landfill. However, disposal of low-level radioactive waste is expensive and storage capacity is limited. ThermoNuclean's Segmented Gate System (SGS) removes only the radioactively contaminated soil, in turn greatly reducing the volume of soils that requires disposal. After processing using the SGS, the fraction of contaminated soil is processed using the containerized vat leaching (CVL) system developed at LANL. Uranium is leached out of the soil in solution. The uranium is recovered with an ion exchange resin, leaving only a small volume of liquid low-level waste requiring disposal. The reclaimed soil can be returned to its original location after treatment with CVL

  8. ENZYME-LINKED IMMUNOSORBENT ASSAY FOR SCREENING DIOXIN SOIL CONTAMINATION BY UNCONTROLLED COMBUSTION DURING INFORMAL RECYCLING IN SLUMS

    Science.gov (United States)

    Trindade, Mirta; Nording, Malin; Nichkova, Mikaela; Spinnel, Erik; Haglund, Peter; Last, Michael S.; Gee, Shirley; Hammock, Bruce; Last, Jerold A.; González-Sapienza, Gualberto; Brena, Beatriz M.

    2010-01-01

    Uncontrolled combustion due to garbage recycling is a widespread activity among slum dwellers in distressed economy countries and has been indicated as a major source of dioxin contamination. However, because of the high cost and complexity of gas chromatography/high-resolution mass spectrometry (GC-HRMS) analysis, the magnitude of the problem remains largely unknown. The present study describes a first approach toward the use of a dioxin antibody-based enzyme-linked immunosorbent assay (ELISA) as the basis for a sustainable, simple, and low-cost monitoring program to assess the toxicological impact of uncontrolled combustion in slums. A panel of 16 samples was analyzed by GC-HRMS and ELISA on split extracts. Close to 20% of the analyzed samples showed dioxin concentrations up to almost twice the guidance level for residential soil in several countries, pointing out the need for performing a large-scale monitoring program. Despite the potential for variations in dioxin congener distribution due to the mixed nature of the incinerated material, there was a good correlation between the toxic equivalents as determined by GC-HRMS and ELISA. Furthermore, an interlaboratory ELISA validation showed that the capacity to perform the dioxin ELISA was successfully transferred between laboratories. It was concluded that the ELISA method performed very well as a screening tool to prioritize samples for instrumental analysis, which allows cutting down costs significantly. PMID:18522475

  9. Degradation of a chiral nonylphenol isomer in two agricultural soils

    International Nuclear Information System (INIS)

    Zhang Haifeng; Spiteller, Michael; Guenther, Klaus; Boehmler, Gabriele; Zuehlke, Sebastian

    2009-01-01

    The degradation of a chiral nonylphenol isomer, 4-(1-ethyl-1,4-dimethylpentyl)phenol (NP 112 ), in two agricultural soils from Monheim and Dortmund, Germany has been studied. The degradation of NP 112 and the formation of a nitro-nonylphenol metabolite were determined by means of GC-MS analysis. The degradation followed bi-exponential order kinetics, with half-life of less than 5 days in both soils. The nitro-metabolite was found at different concentration levels in the two soils. The nitro-metabolite of NP 112 was more persistent than its parent compound. After 150 days about 13% of the initially applied NP 112 remained in the Monheim soil as its nitro-metabolite. Results of the E-screen assay revealed that the nitro-NP 112 has oestrogenic potency of 85% of that of NP 112 . Furthermore, the results of chiral GC-MS analysis revealed that no chiral degradation of NP 112 occurred in this study. - The degradation of a chiral nonylphenol isomer in agricultural soils followed bi-exponential order kinetics resulting in a more persistent nitro-metabolite.

  10. Deriving site-specific soil clean-up values for metals and metalloids: rationale for including protection of soil microbial processes.

    Science.gov (United States)

    Kuperman, Roman G; Siciliano, Steven D; Römbke, Jörg; Oorts, Koen

    2014-07-01

    Although it is widely recognized that microorganisms are essential for sustaining soil fertility, structure, nutrient cycling, groundwater purification, and other soil functions, soil microbial toxicity data were excluded from the derivation of Ecological Soil Screening Levels (Eco-SSL) in the United States. Among the reasons for such exclusion were claims that microbial toxicity tests were too difficult to interpret because of the high variability of microbial responses, uncertainty regarding the relevance of the various endpoints, and functional redundancy. Since the release of the first draft of the Eco-SSL Guidance document by the US Environmental Protection Agency in 2003, soil microbial toxicity testing and its use in ecological risk assessments have substantially improved. A wide range of standardized and nonstandardized methods became available for testing chemical toxicity to microbial functions in soil. Regulatory frameworks in the European Union and Australia have successfully incorporated microbial toxicity data into the derivation of soil threshold concentrations for ecological risk assessments. This article provides the 3-part rationale for including soil microbial processes in the development of soil clean-up values (SCVs): 1) presenting a brief overview of relevant test methods for assessing microbial functions in soil, 2) examining data sets for Cu, Ni, Zn, and Mo that incorporated soil microbial toxicity data into regulatory frameworks, and 3) offering recommendations on how to integrate the best available science into the method development for deriving site-specific SCVs that account for bioavailability of metals and metalloids in soil. Although the primary focus of this article is on the development of the approach for deriving SCVs for metals and metalloids in the United States, the recommendations provided in this article may also be applicable in other jurisdictions that aim at developing ecological soil threshold values for protection of

  11. Multimedia approach to estimating target cleanup levels for soils at hazardous waste sites

    International Nuclear Information System (INIS)

    Hwang, S.T.

    1990-04-01

    Contaminated soils at hazardous and nuclear waste sites pose a potential threat to human health via transport through environmental media and subsequent human intake. To minimize health risks, it is necessary to identify those risks and ensure that appropriate actions are taken to protect public health. The regulatory process may typically include identification of target cleanup levels and evaluation of the effectiveness of remedial alternatives and the corresponding reduction in risks at a site. The US Environmental Protection Agency (EPA) recommends that exposure assessments be combined with toxicity information to quantify the health risk posed by a specific site. This recommendation then forms the basis for establishing target cleanup levels. An exposure assessment must first identify the chemical concentration in a specific medium (soil, water, air, or food), estimate the exposure potential based on human intake from that media, and then combined with health criteria to estimate the upperbound health risks for noncarcinogens and carcinogens. Estimation of target cleanup levels involves the use of these same principles but can occur in reverse order. The procedure starts from establishing a permissible health effect level and ends with an estimated target cleanup level through an exposure assessment process. 17 refs

  12. Global Assessment of the SMAP Level-4 Soil Moisture Product Using Assimilation Diagnostics

    Science.gov (United States)

    Reichle, Rolf; Liu, Qing; De Lannoy, Gabrielle; Crow, Wade; Kimball, John; Koster, Randy; Ardizzone, Joe

    2018-01-01

    The Soil Moisture Active Passive (SMAP) mission Level-4 Soil Moisture (L4_SM) product provides 3-hourly, 9-km resolution, global estimates of surface (0-5 cm) and root-zone (0-100 cm) soil moisture and related land surface variables from 31 March 2015 to present with approx. 2.5-day latency. The ensemble-based L4_SM algorithm assimilates SMAP brightness temperature (Tb) observations into the Catchment land surface model. This study describes the spatially distributed L4_SM analysis and assesses the observation-minus-forecast (O-F) Tb residuals and the soil moisture and temperature analysis increments. Owing to the climatological rescaling of the Tb observations prior to assimilation, the analysis is essentially unbiased, with global mean values of approx. 0.37 K for the O-F Tb residuals and practically zero for the soil moisture and temperature increments. There are, however, modest regional (absolute) biases in the O-F residuals (under approx. 3 K), the soil moisture increments (under approx. 0.01 cu m/cu m), and the surface soil temperature increments (under approx. 1 K). Typical instantaneous values are approx. 6 K for O-F residuals, approx. 0.01 (approx. 0.003) cu m/cu m for surface (root-zone) soil moisture increments, and approx. 0.6 K for surface soil temperature increments. The O-F diagnostics indicate that the actual errors in the system are overestimated in deserts and densely vegetated regions and underestimated in agricultural regions and transition zones between dry and wet climates. The O-F auto-correlations suggest that the SMAP observations are used efficiently in western North America, the Sahel, and Australia, but not in many forested regions and the high northern latitudes. A case study in Australia demonstrates that assimilating SMAP observations successfully corrects short-term errors in the L4_SM rainfall forcing.

  13. Using Data Assimilation Diagnostics to Assess the SMAP Level-4 Soil Moisture Product

    Science.gov (United States)

    Reichle, Rolf; Liu, Qing; De Lannoy, Gabrielle; Crow, Wade; Kimball, John; Koster, Randy; Ardizzone, Joe

    2018-01-01

    The Soil Moisture Active Passive (SMAP) mission Level-4 Soil Moisture (L4_SM) product provides 3-hourly, 9-km resolution, global estimates of surface (0-5 cm) and root-zone (0-100 cm) soil moisture and related land surface variables from 31 March 2015 to present with approx.2.5-day latency. The ensemble-based L4_SM algorithm assimilates SMAP brightness temperature (Tb) observations into the Catchment land surface model. This study describes the spatially distributed L4_SM analysis and assesses the observation-minus-forecast (O-F) Tb residuals and the soil moisture and temperature analysis increments. Owing to the climatological rescaling of the Tb observations prior to assimilation, the analysis is essentially unbiased, with global mean values of approx. 0.37 K for the O-F Tb residuals and practically zero for the soil moisture and temperature increments. There are, however, modest regional (absolute) biases in the O-F residuals (under approx. 3 K), the soil moisture increments (under approx. 0.01 cu m/cu m), and the surface soil temperature increments (under approx. 1 K). Typical instantaneous values are approx. 6 K for O-F residuals, approx. 0.01 (approx. 0.003) cu m/cu m for surface (root-zone) soil moisture increments, and approx. 0.6 K for surface soil temperature increments. The O-F diagnostics indicate that the actual errors in the system are overestimated in deserts and densely vegetated regions and underestimated in agricultural regions and transition zones between dry and wet climates. The O-F auto-correlations suggest that the SMAP observations are used efficiently in western North America, the Sahel, and Australia, but not in many forested regions and the high northern latitudes. A case study in Australia demonstrates that assimilating SMAP observations successfully corrects short-term errors in the L4_SM rainfall forcing.

  14. Hardware cloth seed-spot screens reduce high surface soil temperature

    Science.gov (United States)

    H.A. Fowells; R.K. Arnold

    1939-01-01

    Screens made of hardware cloth are commonly used to protect seed-spots in forest plantations from the depredations of birds and rodents. It is important to know whether or not the screens influence germination and survival of seedlings in addition to furnishing protection against animals.

  15. Assessment of hyporheic zone, flood-plain, soil-gas, soil, and surface-water contamination at the Old Incinerator Area, Fort Gordon, Georgia, 2009-2010

    Science.gov (United States)

    Guimaraes, Wladmir B.; Falls, W. Fred; Caldwell, Andral W.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2011-01-01

    their method detection levels, but those that were detected were above the nondetection level. The same six locations that were sampled for explosives and chemical agents were selected for the collection of soil samples. No metals that exceeded the Regional Screening Levels for Industrial Soils as classified by the U.S. Environmental Protection Agency were detected at any of the six Old Incinerator Area locations. The soil samples also were compared to values from the ambient, uncontaminated (background) levels for soils in South Carolina. Because South Carolina is adjacent to Georgia and the soils in the coastal plain are similar, these comparisons are valid. No similar values are available for Georgia to use for comparison purposes. The only metal detected above the ambient background levels for South Carolina was barium. A surface-water sample collected from a tributary west and north of the Old Incinerator Area was analyzed for volatile organic compounds, semivolatile organic compounds, and inorganic compounds (metals). The only volatile organic and (or) semivolatile organic compound that was detected above the laboratory reporting level was toluene. The compounds 4-isopropyl-1-methylbenzene and isophorone were detected above the nondetection level but below the laboratory reporting level and were estimated. These compounds were detected at levels below the maximum contaminant levels set by the U.S. Environmental Protection Agency National Primary Drinking Water Standard. Iron was the only inorganic compound detected in the surface-water sample that exceeded the maximum contaminant level set by the U.S. Environmental Protection Agency National Secondary Drinking Water Standard. No other inorganic compounds exceeded the maximum contaminant levels for the U.S. Environmental Protection Agency National Primary Drinking Water Standard, National Secondary Drinking Water Standard, or the Georgia In-Stream Water Quality Standard.

  16. Association between risk of birth defects occurring level and arsenic concentrations in soils of Lvliang, Shanxi province of China

    International Nuclear Information System (INIS)

    Wu, Jilei; Zhang, Chaosheng; Pei, Lijun; Chen, Gong; Zheng, Xiaoying

    2014-01-01

    The risk of birth defects is generally accredited with genetic factors, environmental causes, but the contribution of environmental factors to birth defects is still inconclusive. With the hypothesis of associations of geochemical features distribution and birth defects risk, we collected birth records and measured the chemical components in soil samples from a high prevalence area of birth defects in Shanxi province, China. The relative risk levels among villages were estimated with conditional spatial autoregressive model and the relationships between the risk levels of the villages and the 15 types of chemical elements concentration in the cropland and woodland soils were explored. The results revealed that the arsenic levels in cropland soil showed a significant association with birth defects occurring risk in this area, which is consistent with existing evidences of arsenic as a teratogen and warrants further investigation on arsenic exposure routine to birth defect occurring risk. - Highlights: • Association between soil geochemical components and birth defects risk was proposed. • The relative risk difference among villages were estimated with CAR model. • Arsenic levels in cropland showed a significant association to birth defect risk. • The finding warrants further investigation on arsenic as a teratogen. - The difference of risk levels estimate by spatial statistics to birth defect significantly associated with arsenic levels in cropland soils warrants further investigation

  17. Breast Cancer Screening Programmes across the WHO European Region: Differences among Countries Based on National Income Level.

    Science.gov (United States)

    Altobelli, Emma; Rapacchietta, Leonardo; Angeletti, Paolo Matteo; Barbante, Luca; Profeta, Filippo Valerio; Fagnano, Roberto

    2017-04-23

    Breast cancer (BC) is the most frequent tumour affecting women all over the world. In low- and middle-income countries, where its incidence is expected to rise further, BC seems set to become a public health emergency. The aim of the present study is to provide a systematic review of current BC screening programmes in WHO European Region to identify possible patterns. Multiple correspondence analysis was performed to evaluate the association among: measures of occurrence; GNI level; type of BC screening programme; organization of public information and awareness campaigns regarding primary prevention of modifiable risk factors; type of BC screening services; year of screening institution; screening coverage and data quality. A key difference between High Income (HI) and Low and Middle Income (LMI) States, emerging from the present data, is that in the former screening programmes are well organized, with approved screening centres, the presence of mobile units to increase coverage, the offer of screening tests free of charge; the fairly high quality of occurrence data based on high-quality sources, and the adoption of accurate methods to estimate incidence and mortality. In conclusion, the governments of LMI countries should allocate sufficient resources to increase screening participation and they should improve the accuracy of incidence and mortality rates.

  18. General well function for soil vapor extraction

    Science.gov (United States)

    Perina, Tomas

    2014-04-01

    This paper develops a well function applicable to extraction of groundwater or soil vapor from a well under the most common field test conditions. The general well function (Perina and Lee, 2006) [12] is adapted to soil vapor extraction and constant head boundary at the top. For groundwater flow, the general well function now applies to an extraction well of finite diameter with uniform drawdown along the screen, finite-thickness skin, and partially penetrating an unconfined, confined, and leaky aquifer, or an aquifer underneath a reservoir. With a change of arguments, the model applies to soil vapor extraction from a vadose zone with no cover or with leaky cover at the ground surface. The extraction well can operate in specified drawdown (pressure for soil vapor) or specified flowrate mode. Frictional well loss is computed as flow-only dependent component of the drawdown inside the extraction well. In general case, the calculated flow distribution is not proportional to screen length for a multiscreen well.

  19. Ecotoxicological screen of Potential Release Site 50-006(d) of Operable Unit 1147 of Mortandad Canyon and relationship to the Radioactive Liquid Waste Treatment Facilities project

    International Nuclear Information System (INIS)

    Gonzales, G.J.; Newell, P.G.

    1996-04-01

    Potential ecological risk associated with soil contaminants in Potential Release Site (PRS) 50-006(d) of Mortandad Canyon at the Los Alamos National Laboratory was assessed by performing an ecotoxicological risk screen. The PRS surrounds Outfall 051, which discharges treated effluent from the Radioactive Liquid Waste Treatment Facility. Discharge at the outfall is permitted under the Clean Water Act National Pollution Discharge Elimination System. Radionuclide discharge is regulated by US Department of Energy (DOE) Order 5400.5. Ecotoxicological Screening Action Levels (ESALSs) were computed for nonradionuclide constituents in the soil, and human risk SALs for radionuclides were used as ESALs. Within the PRS and beginning at Outfall 051, soil was sampled at three points along each of nine linear transects at 100-ft intervals. Soil samples from 3 depths for each sampling point were analyzed for the concentration of a total of 121 constituents. Only the results of the surface sampling are reported in this report

  20. Relationship Between Total and Bioaccessible Lead on Children’s Blood Lead Levels in Urban Residential Philadelphia Soils

    Science.gov (United States)

    Relationships between total soil or bioaccessible lead (Pb), measured using an in vitro bioaccessibility assay, and children’s blood lead levels (BLL) were investigated in an urban neighborhood in Philadelphia, Pennsylvania, USA, with a history of soil Pb contamination....

  1. Screening of fungi for soil remediation potential

    Science.gov (United States)

    Richard T. Lamar; Laura M. Main; Diane M. Dietrich; John A. Glaser

    1999-01-01

    The purpose of the present investigation was to determine if physiological and/or biochemical factors such as growth rate, tolerance to and ability to degrade PCP or creosote have use for predicting the potential bioremediation performance of fungi. Because we have focused the initial development of a fungal-based soil remediation technology on PCP- and/or creosote-...

  2. [Distribution and risk assessment of mercury species in soil of the water-level-fluctuating zone in the Three Gorges Reservoir].

    Science.gov (United States)

    Zhang, Cheng; Chen, Hong; Wang, Ding-Yong; Sun, Rong-Guo; Zhang, Jin-Yang

    2014-03-01

    To investigate pollution level and ecological risk of mercury in soils of the water-level-fluctuating zone in the Three Gorges Reservoir Region, 192 surface soil samples from 14 counties (districts) in Chongqing were obtained. Concentrations of THg and Hg species, bioavailable Hg were analyzed and discussed. Geoaccumulation index (I(geo)) and Håkanson potential ecological risk index (E(r)) were applied to assess the pollution status and potential ecological risk of THg and Hg species, respectively. The results showed that significant differences in the concentration of THg were found in soils of water-level-fluctuating zone in the Three Gorges Reservoir. The THg concentration ranged from 22.4 to 393.5 microg x kg(-1), with an average of (84.2 +/- 54.3) microg x kg(-1). 76.6% of the samples' THg content was higher than the soil background value in the Three Gorges Reservoir Region. The percentage of five mercury species (water-soluble Hg, HCl-soluble Hg, KOH-soluble Hg, H2O2-soluble Hg, residue Hg) in soils were 4.1%, 15.5%, 18.3%, 10.9%, 51.3%, respectively. The average concentrations of bioavailable mercury varied between 19.7-36.6 microg x kg(-1), and the percentage of bioavailable Hg was 22.1%-51.6% of THg. According to the geoaccumulation index, the soils were lightly polluted by Hg. Håkanson single potential ecological risk index evaluation showed that Hg species had a low potential ecological risk, moreover, soils of water-level-fluctuating zone in the Three Gorges Reservoir were at low ecological risk levels as evaluated by bioavailable Hg. While, the assessment results based on THg of soils was much higher than that based on the Hg species. Two methods of evaluation showed that the I(geo) and E(r) values calculated based on the Hg species better reflected the actual pollution levels of soils and its hazard to aquatic organisms.

  3. Sorption-desorption dynamics of radiocaesium in organic matter soils

    International Nuclear Information System (INIS)

    Valcke, E.; Cremers, A.

    1994-01-01

    A systematic study has been carried out on the radiocaesium sorption properties of 25 soils (forest, peat) covering organic matter (OM) contents in the range of 10-97%. Predictions are made for radiocaesium partitioning between micaceous Frayed Edge Sites (FES) and regular exchange sites (RES) on the basis of specific radiocaesium interception potentials of the soil and overall exchange capacity. It is shown that for soils with a very high OM content (>80%), significant fractions are present in a readily reversible form in the OM phase. In soils of low-medium OM content (<40%), only a very minor fraction is present in the OM exchange complex. Experimental findings, based on a desorption screening with a variety of desorption agents are in agreement with these predictions. On the basis of a study of sorption kinetics, some additional tools are available for identifying problem soils. In cases of very high OM content, radiocaesium adsorption is completed within hours demonstrating the involvement of the OM sites. In soils for which interception occurs in the FES, sorption continues to proceed for periods of 2-3 weeks. In conclusion, some examples are presented on radiocaesium desorption using ion exchangers as radiocaesium sinks in promoting desorption. For a peaty soil, near quantitative desorption is accomplished. For forest soils with OM contents in a range of 10-40%, fixation levels of 30-50% are demonstrated

  4. Screening-Level Safety Assessment of Personal Care Product Constituents Using Publicly Available Data

    Directory of Open Access Journals (Sweden)

    Ernest S. Fung

    2018-06-01

    Full Text Available Organizations recommend evaluating individual ingredients when assessing the safety of personal care or cosmetic products. The goal of this study was to present a screening-level safety assessment methodology to evaluate the safety of a product by identifying individual ingredients, determining their frequency of use in on-market products, and examining published safe-level-of-use information for each ingredient. As a case study, we evaluated WEN by Chaz Dean (WCD cleansing conditioners since there have been claims of adverse health effects associated with product use. We evaluated 30 ingredients in three on-market WCD cleansing conditioners. We then analyzed the National Library of Medicine’s Household Products Database and the Environmental Working Group’s (EWG Skin Deep Cosmetic Database, two of the largest publicly available databases, for other on-market personal care and cosmetic products that contained these ingredients. Safe-level-of-use information for each ingredient was obtained by reviewing peer-reviewed literature, the Food and Drug Administration’s (FDA generally recognized as safe (GRAS database, available Cosmetic Ingredient Review (CIR publications, and available product safety publications. The results of this analysis showed that more than 20,000 personal care and cosmetic products contained one or more of the evaluated ingredients used in WCD cleaning conditioners. Published safety information was available for 21 of the 30 evaluated ingredients: seven identified ingredients were designated as GRAS by the FDA and 16 ingredients had safe-level-of-use information available from the CIR. This study presents a screening-level safety assessment methodology that can serve as an initial screening tool to evaluate the safety of an ingredient intended for use in personal care and cosmetic products before a product is launched onto the market. This study provides evidence that the evaluated WCD cleansing conditioner ingredients

  5. The mediating role of the home environment in relation to parental educational level and preschool children’s screen time: a cross-sectional study

    Directory of Open Access Journals (Sweden)

    Suvi Määttä

    2017-09-01

    Full Text Available Abstract Background Previous studies suggest that preschoolers from low socioeconomic backgrounds engage in more screen time. Still, the factors in the social and physical home environment driving these differences in preschool children’s screen time are poorly understood. This study examines potential home environment mediators in the associations between parental educational level and preschoolers’ screen time. Methods A total of 864 children aged 3–6 years and their parents participated in a cross-sectional DAGIS study in 2015–2016. Parents recorded their children’s screen time in a diary (N = 823. For the analyses, the daily average screen time at home was calculated. Parental questionnaires (N = 808 assessed educational level and eight social and physical environment factors in the home (i.e., descriptive norm for children’s screen time, parental screen use in front of children, parental importance for limiting children’s screen time, parental attitude toward societal pressures for children’s screen time, access to screens at home, parental self-efficacy for limiting children’s screen time, satisfaction of children’s screen time, and rules for limiting children’s screen time. Parental education was grouped into low, middle, and high education. The associations were tested by conducting mediation analyses adjusted by season and children’s sex and age. The significant mediators in the single-mediator models were included in the final multiple-mediator models. Results Of the potential eight mediators, the following four had a significant indirect association: descriptive norm for children’s screen time, parental screen use in front of children, parental importance for limiting children’s screen time, and parental attitude toward societal pressures for children’s screen time. Parents with high education had lower descriptive norm and used fewer screens in front of children compared to parents with middle or

  6. Cadmium accumulation in soils caused by contaminated irrigation water in relation to safety level of enviromental water

    Energy Technology Data Exchange (ETDEWEB)

    Ito, H; Iimura, K

    1974-01-01

    Adsorption of cadmium on the soil from irrigation water contaminated by human production activites were investigated. Both in the equilibrium and column experiments, the soils adsorbed more than 90 per cent of cadmium from the water containing 0.01 ppm cadmium and 18 or 300 ppm calcium. The amounts of cadmium adsorbed by the soils in the equilibrium experiments increased with the increasing concentrations (0.001-10 ppm) in accordance with the Freundlich's adsorption formula, the indices of which were near unity. In column experiments, the proportions of cadmium adsorbed by the soils from the water containing 0.01 ppm cadmium and 18 ppm calcium were equal to or more than those of calcium. It was estimated that if the water containing 0.01 ppm cadmium, that is the safety level of environmental water for human health by WHO and adopted as the permissible concentration by the Japanese Government, were irrigated in paddy fields, cadmium contents of the soils would exceed 1 ppm within a few years. Furthermore, on some of those contaminated soils, brown rice containing more than 1 ppm cadmium, that is the permissible concentration in brown rice authorised by the Japanese Government, will be produced. From the viewpoint of soil conservation from contamination, it is suggested that the permissible concentration of cadmium in the environment water should be lowered to at least one tenth of the present level. The exchange equilibriums in the soils between Cd and Ca and Cd and Na were discussed.

  7. Radiometric assessment of natural radioactivity levels of agricultural soil samples collected in Dakahlia, Egypt.

    Science.gov (United States)

    Issa, Shams A M

    2013-01-01

    Determination of the natural radioactivity has been carried out, by using a gamma-ray spectrometry [NaI (Tl) 3″ × 3″] system, in surface soil samples collected from various locations in Dakahlia governorate, Egypt. These locations form the agriculturally important regions of Egypt. The study area has many industries such as chemical, paper, organic fertilisers and construction materials, and the soils of the study region are used as a construction material. Therefore, it becomes necessary to study the natural radioactivity levels in soil to assess the dose for the population in order to know the health risks. The activity concentrations of (226)Ra, (232)Th and (40)K in the soil ranged from 5.7 ± 0.3 to 140 ± 7, from 9.0 ± 0.4 to 139 ± 7 and from 22 ± 1 to 319 ± 16 Bq kg(-1), respectively. The absorbed dose rate, annual effective dose rate, radium equivalent (Req), excess lifetime cancer risk, hazard indices (Hex and Hin) and annual gonadal dose equivalent, which resulted from the natural radionuclides in the soil were calculated.

  8. Evaluating 239Pu levels using field detectors

    International Nuclear Information System (INIS)

    Wahl, L.E.; Smith, W.J. II; Martin, B.

    1996-01-01

    At Los Alamos National Laboratory, cleanup was planned at three septic tanks where surface soil in the outfall drainage areas was found to be contaminated with 239 Pu. To meet budget and deadline constraints, a technique was developed that used field instruments to verify 239 Pu soil contamination at levels less than 2.8 Bq g -1 , the established cleanup level. The drainage areas were surveyed using a low-energy gamma probe to identify likely areas of 239 Pu contamination. Between 40 and 135 0.1-min gamma radiation measurements were obtained from each drainage area. From these data, locations were identified for subsequent screening for alpha radioactivity. Soil samples from between 11 and 18 locations at each drainage area were placed in petri dishes, dried, and counted for 10 minutes using an alpha probe. Alpha counts were then related to 239 Pu concentrations using a curve developed from local soils containing known concentrations of 239 Pu. Up to six soil samples from each drainage area, representing a range of alpha radioactivity levels, were sent for laboratory analysis of isotopic plutonium to confirm field measurement results. Analytical and field results correlated well at all but one outfall area. At this area, field measurements predicted more 239 Pu than was measured in the laboratory, indicating the presence of another alpha-emitting radionuclide that might have been missed if only laboratory analyses for plutonium had been used. This technique, which combined a large number of gamma radioactivity measurements, a moderate number of alpha radioactivity measurements, and a few isotopic plutonium measurements, allowed quick and inexpensive comparison of 239 Pu with the cleanup level

  9. Soil Gas Sampling Operating Procedure

    Science.gov (United States)

    EPA Region 4 Science and Ecosystem Support Division (SESD) document that describes general and specific procedures, methods, and considerations when collecting soil gas samples for field screening or laboratory analysis.

  10. X-231B technology demonstration for in situ treatment of contaminated soil: Technology evaluation and screening

    International Nuclear Information System (INIS)

    Siegrist, R.L.; Morris, M.I.; Donaldson, T.L.; Palumbo, A.V.; Herbes, S.E.; Jenkins, R.A.; Morrissey, C.M.; Harris, M.T.

    1993-08-01

    The Portsmouth Gaseous Diffusion Plant (Ports) is located approximately 70 miles south of Columbus in southern Ohio. Among the several waste management units on the facility, the X-231B unit consists of two adjacent oil biodegradation plots. The plots encompass ∼ 0.8 acres and were reportedly used from 1976 to 1983 for the treatment and disposal of waste oils and degreasing solvents, some containing uranium-235 and technetium-99. The X-231B unit is a regulated solid waste management unit (SWMU) under the Resource Conservation and Recovery Act (RCRA). The X-231B unit is also a designated SWMU located within Quadrant I of the site as defined in an ongoing RCRA Facilities Investigation and Corrective Measures Study (RFI/CMS). Before implementing one or more Technology Demonstration Project must be completed. The principal goal of this project was to elect and successfully demonstrate one ore more technologies for effective treatment of the contaminated soils associated with the X-231B unit at PORTS. The project was divided into two major phases. Phase 1 involved a technology evaluation and screening process. The second phase (i.e., Phase 2) was to involve field demonstration, testing and evaluation of the technology(s) selected during Phase 1. This report presents the methods, results, and conclusions of the technology evaluation and screening portion of the project

  11. Ecotoxicity monitoring and bioindicator screening of oil-contaminated soil during bioremediation.

    Science.gov (United States)

    Shen, Weihang; Zhu, Nengwu; Cui, Jiaying; Wang, Huajin; Dang, Zhi; Wu, Pingxiao; Luo, Yidan; Shi, Chaohong

    2016-02-01

    A series of toxicity bioassays was conducted to monitor the ecotoxicity of soils in the different phases of bioremediation. Artificially oil-contaminated soil was inoculated with a petroleum hydrocarbon-degrading bacterial consortium containing Burkholderia cepacia GS3C, Sphingomonas GY2B and Pandoraea pnomenusa GP3B strains adapted to crude oil. Soil ecotoxicity in different phases of bioremediation was examined by monitoring total petroleum hydrocarbons, soil enzyme activities, phytotoxicity (inhibition of seed germination and plant growth), malonaldehyde content, superoxide dismutase activity and bacterial luminescence. Although the total petroleum hydrocarbon (TPH) concentration in soil was reduced by 64.4%, forty days after bioremediation, the phytotoxicity and Photobacterium phosphoreum ecotoxicity test results indicated an initial increase in ecotoxicity, suggesting the formation of intermediate metabolites characterized by high toxicity and low bioavailability during bioremediation. The ecotoxicity values are a more valid indicator for evaluating the effectiveness of bioremediation techniques compared with only using the total petroleum hydrocarbon concentrations. Among all of the potential indicators that could be used to evaluate the effectiveness of bioremediation techniques, soil enzyme activities, phytotoxicity (inhibition of plant height, shoot weight and root fresh weight), malonaldehyde content, superoxide dismutase activity and luminescence of P. phosphoreum were the most sensitive. Copyright © 2015 Elsevier Inc. All rights reserved.

  12. Determination of polonium-210 levels in some syrian soils and crops

    International Nuclear Information System (INIS)

    Othman, I.; Al-Masri, M.S.; Aba, A.A.; Mukhallaty, H.; Al-Hamwy, A.; Khalili, H.

    1997-04-01

    Polonium 210 levels in the edible port of 19 agricultural crops collected from ten locations in Syria have been determined. Results have been shown that the highest concentrations were found to be in parsley (10.49 Bq/Kg) and this due to high area of its levels. Moreover, the concentrations were low in some vegetables such as tomatoes (0.2 Bq/Kg). In addition, polonium 210 was also determined in Syria soil where it was found to vary between 20 Bq/Kg and 68.8 Bq/Kg). (author). 11 refs., 17 tabs

  13. Racial and Ethnic Variation in Time to Prostate Biopsy After an Elevated Screening Level of Serum Prostate-specific Antigen.

    Science.gov (United States)

    Reading, Stephanie R; Porter, Kimberly R; Hsu, Jin-Wen Y; Wallner, Lauren P; Loo, Ronald K; Jacobsen, Steven J

    2016-10-01

    To examine the racial and ethnic variation in time to prostate biopsy after an elevated screening level of serum prostate-specific antigen (PSA). Male members of the Kaiser Permanente of Southern California health plan, 45 years of age or older, with no history of prostate cancer or a prostate biopsy, and at least 1 elevated screening level of serum PSA between January 1, 1998 and December 31, 2007 were retrospectively identified (n = 59,506). All participants were passively followed via electronic health records until their time of prostate biopsy, death, membership disenrollment, or study conclusion (December 31, 2014), whichever was the initial event. Proportional hazard regression analyses were used to estimate the association between time from an elevated screening level of serum PSA to prostate biopsy, adjusting for age, benign prostatic hyperplasia, prostatitis, type 2 diabetes mellitus, hypertension, and Charlson Comorbidity Index score. Median time until biopsy was 0.6 years (214 days), with approximately 41% of participants receiving a prostate biopsy within the study period. Results from the fully adjusted analysis indicated that the non-Hispanic Asian or Pacific Islanders (hazard ratio: 1.10, 95% confidence interval: [1.04, 1.15]) and the non-Hispanic blacks (hazard ratio: 1.04, 95% confidence interval: [1.00, 1.08]) had a slightly shorter time to prostate biopsy after an elevated screening level of serum PSA compared to the non-Hispanic whites. These data suggest that, within an integrated healthcare organization, minimal differences exist between racial and ethnic subgroups in their time to prostate biopsy after an elevated screening level of serum PSA. Copyright © 2016. Published by Elsevier Inc.

  14. Toxicological benchmarks for screening potential contaminants of concern for effects on terrestrial plants

    International Nuclear Information System (INIS)

    Suter, G.W. II; Will, M.E.; Evans, C.

    1993-09-01

    One of the initial stages in ecological risk assessment for hazardous waste sites is the screening of contaminants to determine which of them are worthy of further consideration as ''contaminants of potential concern.'' This process is termed ''contaminant screening.'' It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to plants. This report presents a standard method for deriving benchmarks for this purpose (phytotoxicity benchmarks), a set of data concerning effects of chemicals in soil or soil solution on plants, and a set of phytotoxicity benchmarks for 34 chemicals potentially associated with US Department of Energy (DOE) sites. Chemicals that are found in soil at concentrations exceeding both the phytotoxicity benchmark and the background concentration for the soil type should be considered contaminants of potential concern. The purpose of this report is to present plant toxicity data and discuss their utility as benchmarks for determining the hazard to terrestrial plants caused by contaminants in soil. Benchmarks are provided for soils and solutions

  15. Preclinical screening for retinopathy of prematurity risk using IGF1 levels at 3 weeks post-partum.

    Science.gov (United States)

    Pérez-Muñuzuri, Alejandro; Couce-Pico, Maria Luz; Baña-Souto, Ana; López-Suárez, Olalla; Iglesias-Deus, Alicia; Blanco-Teijeiro, José; Fernández-Lorenzo, José Ramón; Fraga-Bermúdez, José María

    2014-01-01

    Following current recommendations for preventing retinopathy of prematurity (ROP) involves screening a large number of patients. We performed a prospective study to establish a useful screening system for ROP prediction and we have determined that measuring serum levels of IGF1 at week three and the presence of sepsis have a high predictive value for the subsequent development of ROP. A total of 145 premature newborn, with birthweight <1500 g and/or <32 weeks gestational age, were enrolled. 26.9% of them showed some form of retinopathy. A significant association was found between the development of retinopathy and each of the following variables: early gestational age, low birthweight, requiring mechanical ventilation, oxygen treatment, intracranial haemorrhage, sepsis during the first three weeks, bronchopulmonary dysplasia, the need for erythrocyte transfusion, erythropoietin treatment, and low levels of serum IGF1 in the third week. A multiple logistic regression analysis was used to obtain curves for the probability of developing ROP, based on the main factors linked with ROP, namely serum levels of IGF1 and presence of sepsis. Such preclinical screening has the ability to identify patients with high-risk of developing retinopathy and should lead to better prediction for ROP, while at the same time optimising the use of clinical resources, both human and material.

  16. Retention of low-level radioacrive waste material by soil

    International Nuclear Information System (INIS)

    Essington, E.H.; Fowler, E.B.; Polzer, W.L.

    1979-01-01

    Beacuse of the wide variations in soil and waste characteristics, the degree of radionuclide retention would be expected to vary; knowledge of that variation may be of value in predicting radionuclde mobility. This report discusses results of investigations of radioactive waste/soil interactions as they relate to radionucldie retention and its variability among soils and radionuclides. In soil column leaching studies, radioactive waste solutions were applied to four different soil types; 241 Am, 88 Y, and 172 Hf were retained in the top four cm of soil with better than 90% retained by a protective surface sand layer. Less than 50% of the 85 Sr, 137 Cs, and 83 Rb was retained by the surface sand. No 88 Y, 172 Hf, 85 Sr, 137 Cs, or 83 Rb was detected by gamma counting in the leachate solutions, however, using a more sensitive analytical technique small amounts of 238 Pu, 239 240 Pu and 241 Am were found in leachates from all soils. It appears that release of this small fraction of mobile radionuclide may have a significant long-term impact on the environment. It aslo appears that reliance for attenuation of some radionuclides can not be placed solely on characteristics of the soil matrix

  17. Feasibility of large-scale screening using N-ERC/mesothelin levels in the blood for the early diagnosis of malignant mesothelioma.

    Science.gov (United States)

    Imashimizu, Kohta; Shiomi, Kazu; Maeda, Masahiro; Aoki, Naoko; Igarashi, Kiyoko; Suzuki, Fumio; Koizumi, Mitsuru; Suzuki, Kenji; Hino, Okio

    2011-05-01

    A large-scale screening involving the measurement of N-ERC/mesothelin levels in blood using an ELISA system for the early diagnosis of malignant mesothelioma (MM) was carried out in individuals with a history of employment at construction sites. Approximately 30,000 subjects were screened. Of the 80 subjects with high-risk values, one male patient was diagnosed as having MM based on a PET study and histopathology. This is the first report of the pre-clinical diagnosis of MM based on blood test screening. In addition, plasma levels of N-ERC/mesothelin may be effectively used for monitoring relapse after surgery.

  18. Ecological approach of macrolide-lincosamides-streptogramin producing actinomyces from Cuban soils.

    Science.gov (United States)

    González, I; Niebla, A; Lemus, M; González, L; Iznaga, I O; Pérez, M E; Vallin, C

    1999-09-01

    We report in this study the frequency of Streptomyces strains to produce macrolide-lincosamide-streptogramin (MLS) antibiotics isolated from Cuban soils. The screening assay is based on the induction of MLS-resistance phenotype in a clinical isolated strain of Staphylococcus aureus S-18. Our results suggest that of 800 Streptomyces strains isolated from different soil samples, 6% were positives in the screening test used. The ferralitic red soil from Pinar del Río (north) provided the major percentage (3.6%) of MLS producing strains. The other soil samples tested belonging to Guira de Melena and Bauta in Havana, Matanzas City, Topes De Collantes (Villa Clara), and Soroa Mountains (Pinar del Rio) hill reached very low percentages.

  19. Effect of spatial resolution of soil data on predictions of eggshell trace element levels in the Rook Corvus frugilegus.

    Science.gov (United States)

    Orłowski, Grzegorz; Siebielec, Grzegorz; Kasprzykowski, Zbigniew; Dobicki, Wojciech; Pokorny, Przemysław; Wuczyński, Andrzej; Polechoński, Ryszard; Mazgajski, Tomasz D

    2016-12-01

    Although a considerable research effort has gone into studying the dietary pathways of metals to the bodies of laying female birds and their eggs in recent years, no detailed investigations have yet been carried out relating the properties of the biogeochemical environment at large spatial scales to eggshell trace element levels in typical soil-invertebrate feeding birds under natural conditions. We used data from a large-scale nationwide monitoring survey of soil quality in Poland (3724 sampling points from the 43 792 available) to predict levels of five trace elements (copper [Cu], cadmium [Cd], nickel [Ni], zinc [Zn] and lead [Pb]) in Rook Corvus frugilegus eggshells from 42 breeding colonies. Our major aim was to test whether differences exist in the explanatory power of soil data (acidity, content of elements and organic matter, and particle size) used as a correlate of concentrations of eggshell trace elements among four different distances (5, 10, 15 and 20 km) around rookeries. Over all four distances around the rookeries only the concentrations of Cu and Cd in eggshells were positively correlated with those in soil, while eggshell Pb was correlated with the soil Pb level at the two longest distances (15 and 20 km) around the rookeries. The physical properties of soil (primarily the increase in pH) adversely affected eggshell Cd and Pb concentrations. The patterns and factors governing metal bioaccumulation in soil invertebrates and eggshells appear to be coincident, which strongly suggests a general similarity in the biochemical pathways of elements at different levels of the food web. The increasing acidification of arable soil as a result of excessive fertilisation and over-nitrification can enhance the bioavailability of toxic elements to laying females and their eggs. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Effects of telephone follow-up on blood glucose levels and postpartum screening in mothers with Gestational Diabetes Mellitus.

    Science.gov (United States)

    Khorshidi Roozbahani, Rezvan; Geranmayeh, Mehrnaz; Hantoushzadeh, Sedigheh; Mehran, Abbas

    2015-01-01

    Gestational diabetes mellitus (GDM) is a form of diabetes that occurs in pregnancy. GDM, defined as glucose intolerance, first diagnosed or initiated during pregnancy affects 1-14% of pregnancies based on various studies. Screening and early diagnosis and appropriate glycemic control can improve prenatal outcomes. Telephone follow-up seems to be a reasonable way for pregnant women follow-up. The present study evaluated the effects of telephone follow-up on blood glucose level during pregnancy and postpartum screening. Eighty mothers with GDM were enrolled in this clinical trial and randomly divided into intervention and control groups. All mothers were asked to check their blood sugar levels fivetimes daily. In intervention group, telephone intervention was performed for 10 weeks. In each follow-up, individuals were followed for insulin injections, diet, clinical tests and reminding the next visit. In control group, three times of telephone call was established to record blood sugar levels. Another telephone call was established at 6 weeks of postpartum in both study groups to evaluate the performance of the screening test for blood sugar. The mean age of mothers was 30.9±5 years in the control and 30.7±5.1 years in the intervention groups In intervention group, mean level of blood glucose, 2 hours after lunch at 28 weeks of pregnancy was significantly lower than the control group (Pmothers with gestational diabetes and also increased the rate of postpartum screening test.

  1. The development of Operational Intervention Levels (OILs) for Soils - A decision support tool in nuclear and radiological emergency response

    Science.gov (United States)

    Lee Zhi Yi, Amelia; Dercon, Gerd; Blackburn, Carl; Kheng, Heng Lee

    2017-04-01

    In the event of a large-scale nuclear accident, the swift implementation of response actions is imperative. For food and agriculture, it is important to restrict contaminated food from being produced or gathered, and to put in place systems to prevent contaminated produce from entering the food chain. Emergency tools and response protocols exist to assist food control and health authorities but they tend to focus on radioactivity concentrations in food products as a means of restricting the distribution and sale of contaminated produce. Few, if any, emergency tools or protocols focus on the food production environment, for example radioactivity concentrations in soils. Here we present the Operational Intervention Levels for Soils (OIL for Soils) concept, an optimization tool developed at the IAEA to facilitate agricultural decision making and to improve nuclear emergency preparedness and response capabilities. Effective intervention relies on the prompt availability of radioactivity concentration data and the ability to implement countermeasures. Sampling in food and agriculture can be demanding because it may involve large areas and many sample types. In addition, there are finite resources available in terms of manpower and laboratory support. Consequently, there is a risk that timely decision making will be hindered and food safety compromised due to time taken to sample and analyse produce. However, the OILs for Soils concept developed based on experience in Japan can help in this situation and greatly assist authorities responsible for agricultural production. OILs for Soils - pre-determined reference levels of air dose rates linked to radionuclide concentrations in soils - can be used to trigger response actions particularly important for agricultural and food protection. Key considerations in the development of the OILs for Soils are: (1) establishing a pragmatic sampling approach to prioritize and optimize available resources and data requirements for

  2. Stability numerical analysis of soil cave in karst area to drawdown of underground water level

    Science.gov (United States)

    Mo, Yizheng; Xiao, Rencheng; Deng, Zongwei

    2018-05-01

    With the underground water level falling, the reliable estimates of the stability and deformation characteristics of soil caves in karst region area are required for analysis used for engineering design. Aimed at this goal, combined with practical engineering and field geotechnical test, detail analysis on vertical maximum displacement of top, vertical maximum displacement of surface, maximum principal stress and maximum shear stress were conducted by finite element software, with an emphasis on two varying factors: the size and the depth of soil cave. The calculations on the soil cave show that, its stability of soil cave is affected by both the size and depth, and only when extending a certain limit, the collapse occurred along with the falling of underground water; Additionally, its maximum shear stress is in arch toes, and its deformation curve trend of maximum displacement is similar to the maximum shear stress, which further verified that the collapse of soil cave was mainly due to shear-failure.

  3. Total and Bioaccessible Soil Arsenic and Lead Levels and Plant Uptake in Three Urban Community Gardens in Puerto Rico

    Science.gov (United States)

    Arsenic (As) and lead (Pb) are two contaminants of concern associated with urban gardening. In Puerto Rico, data currently is limited on As and Pb levels in urban garden soils, soil metal (loid) bioaccessibility, and uptake of As and Pb in soil by edible plants grown in the regio...

  4. Electrokinetics for removal of low-level radioactivity from soil

    Energy Technology Data Exchange (ETDEWEB)

    Pamukcu, S. [Lehigh Univ., Bethlehem, PA (United States); Wittle, J.K. [Electro-Petroleum, Inc., Wayne, PA (United States)

    1993-03-01

    The electrokinetic process is an emerging technology for in situ soil decontamination in which chemical species, both ionic and nonionic, are transported to an electrode site in soil. These products are subsequently removed from the ground via collection systems engineered for each specific application. The work presented here describes part of the effort undertaken to investigate electrokinetically enhanced transport of soil contaminants in synthetic systems. These systems consisted of clay or clay-sand mixtures containing known concentrations of a selected heavy-metal salt solution. These metals included surrogate radionuclides such as Sr, Cs and U, and an anionic species of Cr. Degree of removal of these metals from soil by the electrokinetic treatment process was assessed through the metal concentration profiles generated across the soil between the electrodes. Removals of some metal species up to 99% were achieved at the anode or cathode end of the soil upon 24 to 48 hours of treatment or a maximum of 1 pore volume of water displacement toward the cathode compartment. Transient pH change through the soil had an effect on the metal movement, as evidenced by accumulation of the metals at the discharge ends of the soil specimens. This accumulation was attributed to the precipitation of the metal and increased cation retention capacity of the clay in high pH environment at the cathode end. In general, the reduced mobility and dissociation of the ionic species as they encounter areas of higher ionic concentration in their path of migration resulted in the accumulation of the metals at the discharge ends of the soil specimens.

  5. Application of biodegradation screening protocol to contaminated soils from manufactured gas plant sites

    International Nuclear Information System (INIS)

    Smith, J.R.; Nakles, D.V.; Cushey, M.A.; Morgan, D.J.; Linz, D.G.

    1990-01-01

    Bioremediation (i.e., land treatment) has been demonstrated to be a viable option for treating a variety of soils contamianted with organics. Conventional treatability studies utilize soil microcosm experiments to evaluate the potential for bioremediation of specific contaminated soils. Unfortunately, soil microcosms take from 4- to 6-months to complete and do not fully exploit the current understanding of the bioremediation process. This paper describes a treatability protocol that investigates underlying mechanisms and can be completed in 2- to 3-months. It is believed that soil bioremediation is governed by the sequential processes of contanate desorption from the soil into the aqueous phase and subsequent oxidation by microorganisms. The relative importance of each process depends upon the contaminant and soil. Accordingly, the treatability protocol has three steps. In the first step, tests are performed to determine soil characteristics. In the second step, tests are performed to characterize the desorption of contaminants from the soil. In the third step, the potential for biological oxidaiton is evaluated with a soil-water slurry reactor that maximizes desorption and provides an optimum environment for microbial growth. This paper provides a thorough discussion of the laboratory protocol including the primary theoretical tenets which serve as its basis. Preliminary procedures and results are presented for soils contaminated with manufactured gas plant (MGP) wastes. Particular attention is focused on biodegradation of polynuclear aromatic hydrocarbons (PAHs)

  6. A study for natural radioactivity levels in some soil samples using gamma spectrometry

    International Nuclear Information System (INIS)

    Mohamed, Yousif Hassab El Rasoul

    1997-05-01

    The purpose of this study was to investigate a few selected soil samples and to study their natural radioactivity using gamma spectrometry. The first sample was a rock phosphate from Nuba mountains region which is being considered as a low cost fertilizer. Another sample came from Miri lake area (Nuba mountains) which is known to have elevated natural radioactivity level. The other four samples came from different other regions in Sudan for comparison. The idea was to identify the radioactive nuclides present in these soil samples, to trace their sources and to determine the activity present in them. (Author)

  7. Inter- and Intra- Field variations in soil compaction levels and subsequent impacts on hydrological extremes

    Science.gov (United States)

    Pattison, Ian; Coates, Victoria

    2015-04-01

    The rural landscape in the UK is dominated by pastoral agriculture, with about 40% of land cover classified as either improved or semi-natural grassland according to the Land Cover Map 2007. Intensification has resulted in greater levels of compaction associated with higher stocking densities. However, there is likely to be a great amount of variability in compaction levels within and between fields due to multiple controlling factors. This research focusses in on two of these factors; firstly animal species, namely sheep, cattle and horses; and secondly field zonation e.g. feeding areas, field gates, open field. Field experiments have been conducted in multiple fields in the River Skell catchment, in Yorkshire, UK, which has an area of 140km2. The effect on physical and hydrologic soil characteristics such as bulk density and moisture contents have been quantified using a wide range of field and laboratory based experiments. Results have highlighted statistically different properties between heavily compacted areas where animals congregate and less-trampled open areas. Furthermore, soil compaction has been hypothesised to contribute to increased flood risk at larger spatial scales. Previous research (Pattison, 2011) on a ~40km2 catchment (Dacre Beck, Lake District, UK) has shown that when soil characteristics are homogeneously parameterised in a hydrological model, downstream peak discharges can be 65% higher for a heavy compacted soil than for a lightly compacted soil. Here we report results from spatially distributed hydrological modelling using soil parameters gained from the field experimentation. Results highlight the importance of both the percentage of the catchment which is heavily compacted and also the spatial distribution of these fields.

  8. [Transfer characteristic and source identification of soil heavy metals from water-level-fluctuating zone along Xiangxi River, three-Gorges Reservoir area].

    Science.gov (United States)

    Xu, Tao; Wang, Fei; Guo, Qiang; Nie, Xiao-Qian; Huang, Ying-Ping; Chen, Jun

    2014-04-01

    Transfer characteristics of heavy metals and their evaluation of potential risk were studied based on determining concentration of heavy metal in soils from water-level-fluctuating zone (altitude:145-175 m) and bank (altitude: 175-185 m) along Xiangxi River, Three Gorges Reservoir area. Factor analysis-multiple linear regression (FA-MLR) was employed for heavy metal source identification and source apportionment. Results demonstrate that, during exposing season, the concentration of soil heavy metals in water-level-fluctuation zone and bank showed the variation, and the concentration of soil heavy metals reduced in shallow soil, but increased in deep soil at water-level-fluctuation zone. However, the concentration of soil heavy metals reduced in both shallow and deep soil at bank during the same period. According to the geoaccumulation index,the pollution extent of heavy metals followed the order: Cd > Pb > Cu > Cr, Cd is the primary pollutant. FA and FA-MLR reveal that in soils from water-level-fluctuation zone, 75.60% of Pb originates from traffic, 62.03% of Cd is from agriculture, 64.71% of Cu and 75.36% of Cr are from natural rock. In soils from bank, 82.26% of Pb originates from traffic, 68.63% of Cd is from agriculture, 65.72% of Cu and 69.33% of Cr are from natural rock. In conclusion, FA-MLR can successfully identify source of heavy metal and compute source apportionment of heavy metals, meanwhile the transfer characteristic is revealed. All these information can be a reference for heavy metal pollution control.

  9. The use of comprehensive two-dimensional gas chromatography and structure-activity modeling for screening and preliminary risk assessment of organic contaminants in soil, sediment, and surface water

    Energy Technology Data Exchange (ETDEWEB)

    Moreira Bastos, Patricia; Haglund, Peter [Umeaa Univ. (Sweden). Dept. of Chemistry

    2012-08-15

    Purpose: This article aims to investigate the use and benefits of using comprehensive two-dimensional gas chromatography (GC x GC) and structure-activity relationship modeling for screening and prioritization of organic contaminants in complex matrices. The benefit of applying comprehensive screening techniques to samples with high organic contaminant content is primarily that compounds with diverse physicochemical properties can be analyzed simultaneously. Here, a heavily contaminated industrial area was surveyed for organic pollutants by analyzing soil, sediment, and surface water samples. The hazard of the pollutants were ranked using SARs. Material and methods: The water samples were liquid-liquid extracted using dichloromethane and directly analyzed by GC x GC-time-of-flight mass spectrometry (GC x GC-TofMS). Soil and sediment samples were extracted with dichloromethane in an ultrasonic bath and subjected to gel permeation chromatography to eliminate lipids and humic matter. The low molecular weight fraction was then analyzed with GC x GC-TofMS. Results and discussion: More than 10,000 components were found in each sample, of which ca. 300 individual compounds were unambiguously identified using the National Institute of Standards and Technology mass spectra library and authentic reference standards. Alkanes, polycyclic aromatic hydrocarbons, and phthalates were generally the most abundant and were found in all matrices. In contrast, chlorinated compounds such as chlorophenols, biphenyls, and chlorinated pesticides were only detected in samples from a few hotspot regions. The toxicities of the most frequently detected compounds and of the compounds detected at the highest concentrations in samples from hotspot regions were estimated by ecological structure-activity relationships. The ratio of the measured concentration to the predicted toxicity level was then calculated for each compound and used for an initial risk assessment in order to prioritize compounds

  10. The level of 137Cs concentration in Lebanese soils decade after the Chernobyl accident

    International Nuclear Information System (INIS)

    El Samad, Omar

    1999-01-01

    Full text.This paper concerns the effects of fallout from the Chernobyl reactor accident on the environment in Lebanon. On 1 and 2 May 1986, part of the radioactive cloud from Chernobyl was over Lebanon. A description given of the distribution and movement of fallout as well as the type of contamination. As a result of rainfall on those two days, measurable amounts of several radionuclides were deposited on ground surfaces, predominantly by wet deposition. Not much information for the deposition rates of caesium radionuclides in soil is available. However generally, the deposit caesium was quickly fixed in the top soil. The aim of the present work is to identify the level of the 137 Cs contamination twelve years after the Chernobyl accident. Actinides activity levels in soil were measured. The non destructive Gamma-Spectroscopy measurements were performed by using coaxial high sensitivity HPGe-detectors with active and passive shielding to determine the low activity of various radionuclides. More than 60 soil samples were collected from points uniformly distributed throughout the geography of the zone in order to evaluate their activity. The data showed a relatively high 137 Cs concentration, up to 9000 Bq/m 2 in the superficial (0-3 cm) calcium carbonate soil (CaCo3). The average activity of 137 Cs was 50 Bq/Kg dry mass. The horizontal variation was found to be about 40% in the samples, which is in accordance with results found for similar investigations on Turkey and Greece. The depth distribution of total 137 Cs activity was found by fitting the experimental points to a modified exponential function

  11. Levels of Sulfur as an Essential Nutrient Element in the Soil-Crop-Food System in Austria

    Directory of Open Access Journals (Sweden)

    Manfred Sager

    2012-01-01

    Full Text Available Total sulfur data of various agricultural and food items from the lab of the author, have been compiled to develop an understanding of sulfur levels and ecological cycling in Austria. As sulfur level is not an included factor among the quality criteria of soil and fertilizer composition, the database is rather small. Problems in analytical determinations of total sulfur, in particular digestions, are outlined. As a protein component, sulfur is enriched in matrices of animal origin, in particular in egg white. There is substantial excretion from animals and man via urine. Organic fertilizers (manures, composts might contribute significantly to the sulfur budget of soils, which is important for organic farming of crops with high sulfur needs. For soils, drainage is a main route of loss of soluble sulfate, thus pot experiments may yield unrealistic sulfur budgets.

  12. Baseline concentrations of radionuclides and heavy metals in soils and vegetation around the DARHT facility: Construction phase (1997). Progress report

    International Nuclear Information System (INIS)

    Fresquez, P.R.; Haagenstad, H.T.; Naranjo, L. Jr.

    1998-06-01

    As part of the Department of Energy's Mitigation Action Plan for the Dual Axis Radiographic Hydrodynamic Test (DARHT) facility at Los Alamos National Laboratory (LANL), baseline concentrations of radionuclides ( 3 H, 137 Cs, 90 Sr, 238 Pu, 239,240 Pu, 241 Am, and tot U) and heavy metals (Ag, As, Ba, Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Se, and Tl) in soil, sediment, and vegetation (overstory and understory) around the DARHT facility during the construction phase in 1997 were determined. Most radionuclides and heavy metals in soils, sediments, and vegetation, with the exception of 90 Sr in soils and sediments, were within upper (95%) limit background concentrations. Although the levels of 90 Sr in soils and sediments around the DARHT facility were higher than background, they were below LANL screening action levels ( -1 dry) and are of no concern

  13. Participants, Physicians or Programmes: Participants' educational level and initiative in cancer screening.

    Science.gov (United States)

    Willems, Barbara; Bracke, Piet

    2018-04-01

    This study is an in-depth examination of at whose initiative (participant, physician or screening programme) individuals participate in cervical, breast and colorectal cancer screening across the EU-28. Special attention is paid to (1) the association with educational attainment and (2) the country's cancer screening strategy (organised, pilot/regional or opportunistic) for each type of cancer screened. Data were obtained from Eurobarometer 66.2 'Health in the European Union' (2006). Final samples consisted of 10,186; 5443 and 9851 individuals for cervical, breast, and colorectal cancer, respectively. Multinomial logistic regressions were performed. Surprisingly, even in countries with organised screening programmes, participation in screenings for cervical, breast and colorectal cancer was most likely to be initiated by the general practitioner (GP) or the participant. In general, GPs were found to play a crucial role in making referrals to screenings, regardless of the country's screening strategy. The results also revealed differences between educational groups with regard to their incentive to participate in cervical and breast cancer screening and, to a lesser extent, in colorectal cancer screening. People with high education are more likely to participate in cancer screening at their own initiative, while people with less education are more likely to participate at the initiative of a physician or a screening programme. Albeit, the results varied according to type of cancer screening and national screening strategy. Copyright © 2018 Elsevier B.V. All rights reserved.

  14. The global SMOS Level 3 daily soil moisture and brightness temperature maps

    Directory of Open Access Journals (Sweden)

    A. Al Bitar

    2017-06-01

    Full Text Available The objective of this paper is to present the multi-orbit (MO surface soil moisture (SM and angle-binned brightness temperature (TB products for the SMOS (Soil Moisture and Ocean Salinity mission based on a new multi-orbit algorithm. The Level 3 algorithm at CATDS (Centre Aval de Traitement des Données SMOS makes use of MO retrieval to enhance the robustness and quality of SM retrievals. The motivation of the approach is to make use of the longer temporal autocorrelation length of the vegetation optical depth (VOD compared to the corresponding SM autocorrelation in order to enhance the retrievals when an acquisition occurs at the border of the swath. The retrieval algorithm is implemented in a unique operational processor delivering multiple parameters (e.g. SM and VOD using multi-angular dual-polarisation TB from MO. A subsidiary angle-binned TB product is provided. In this study the Level 3 TB V310 product is showcased and compared to SMAP (Soil Moisture Active Passive TB. The Level 3 SM V300 product is compared to the single-orbit (SO retrievals from the Level 2 SM processor from ESA with aligned configuration. The advantages and drawbacks of the Level 3 SM product (L3SM are discussed. The comparison is done on a global scale between the two datasets and on the local scale with respect to in situ data from AMMA-CATCH and USDA ARS Watershed networks. The results obtained from the global analysis show that the MO implementation enhances the number of retrievals: up to 9 % over certain areas. The comparison with the in situ data shows that the increase in the number of retrievals does not come with a decrease in quality, but rather at the expense of an increased time lag in product availability from 6 h to 3.5 days, which can be a limiting factor for applications like flood forecast but reasonable for drought monitoring and climate change studies. The SMOS L3 soil moisture and L3 brightness temperature products are delivered using an

  15. Toward standardizing and reporting colorectal cancer screening indicators on an international level: The International Colorectal Cancer Screening Network

    NARCIS (Netherlands)

    Benson, Victoria S.; Atkin, Wendy S.; Green, Jane; Nadel, Marion R.; Patnick, Julietta; Smith, Robert A.; Villain, Patricia; Patnick, J.; Atkin, W. S.; Altenhofen, L.; Ancelle-Park, R.; Benson, V. S.; Green, J.; Levin, T. R.; Moss, S. M.; Nadel, M.; Ransohoff, D.; Segnan, N.; Smith, R. A.; Villain, P.; Weller, D.; Koukari, A.; Young, G.; López-Kostner, F.; Antoljak, N.; Suchánek, S.; Zavoral, M.; Holten, I.; Malila, N.; Salines, E.; Brenner, G.; Herszényi, L.; Tulassay, Z.; Rennert, G.; Senore, C.; Zappa, M.; Zorzi, M.; Saito, H.; Leja, M.; Dekker, E.; Jansen, J.; Hol, L.; Kuipers, E.; Kaminski, M. F.; Regula, J.; Sfarti, C.; Trifan, A.; Tang, C.-L.; Hrcka, R.; Binefa, G.; Espinàs, J. A.; Peris, M.; Chen, T. H.; Steele, R.; Pou, G.; Bisges, D.; Dwyer, D.; Groves, C.; Courteau, S.; Kramer, R.; Siegenthaler, K.; Lane, D.; Herrera, C.; Rogers, J.; Rojewski, M.; Wolf, Holly; Sung, J. J.; Ling, K.; Bryant, H.; Rabeneck, L.; Dale, J.; Sware, L.; Yang, H.; Viguier, J.; Von Karsa, L.; Kupcinskas, L.; Deutekom, M.; Törnberg, S.; Austoker, J.; Beral, V.; Monk, C.; Valori, R.; Watson, J.; Kobrin, S.; Pignone, M.; Taplin, S.

    2012-01-01

    The International Colorectal Cancer Screening Network was established in 2003 to promote best practice in the delivery of organized colorectal cancer screening programs. To facilitate evaluation of such programs, we defined a set of universally applicable colorectal cancer screening measures and

  16. Adsorption and desorption of Cu2+ on paddy soil aggregates pretreated with different levels of phosphate.

    Science.gov (United States)

    Dai, Jun; Wang, Wenqin; Wu, Wenchen; Gao, Jianbo; Dong, Changxun

    2017-05-01

    Interactions between anions and cations are important for understanding the behaviors of chemical pollutants and their potential risks in the environment. Here we prepared soil aggregates of a yellow paddy soil from the Taihu Lake region, and investigated the effects of phosphate (P) pretreatment on adsorption-desorption of Cu 2+ of soil aggregates, free iron oxyhydrates-removed soil aggregates, goethite, and kaolinite with batch adsorption method. The results showed that Cu 2+ adsorption was reduced on the aggregates pretreated with low concentrations of P, and promoted with high concentrations of P, showing a V-shaped change. Compared with the untreated aggregates, the adsorption capacity of Cu 2+ was reduced when P application rates were lower than 260, 220, 130 and 110mg/kg for coarse, clay, silt and fine sand fractions, respectively. On the contrary, the adsorption capacity of Cu 2+ was higher on P-pretreated soil aggregates than on the control ones when P application rates were greater than those values. However, the desorption of Cu 2+ was enhanced at low levels of P, but suppressed at high levels of P, displaying an inverted V-shaped change over P adsorption. The Cu 2+ adsorption by the aggregate particles with and without P pretreatments was well described by the Freundlich equation. Similar results were obtained on P-pretreated goethite. However, such P effects on Cu 2+ adsorption-desorption were not observed on kaolinite and free iron oxyhydrates-removed soil aggregates. The present results indicate that goethite is one of the main soil substances responsible for the P-induced promotion and inhibition of Cu 2+ adsorption. Copyright © 2016. Published by Elsevier B.V.

  17. Suitability of a Saccharomyces cerevisiae-based assay to assess the toxicity of pyrimethanil sprayed soils via surface runoff: comparison with standard aquatic and soil toxicity assays.

    Science.gov (United States)

    Gil, Fátima N; Moreira-Santos, Matilde; Chelinho, Sónia; Pereira, Carla; Feliciano, Joana R; Leitão, Jorge H; Sousa, José P; Ribeiro, Rui; Viegas, Cristina A

    2015-02-01

    The present study is aimed at evaluating whether a gene expression assay with the microbial eukaryotic model Saccharomyces cerevisiae could be used as a suitable warning tool for the rapid preliminary screening of potential toxic effects on organisms due to scenarios of soil and water contamination with pyrimethanil. The assay consisted of measuring changes in the expression of the selected pyrimethanil-responsive genes ARG3 and ARG5,6 in a standardized yeast population. Evaluation was held by assessing the toxicity of surface runoff, a major route of pesticide exposure in aquatic systems due to non-point-source pollution, which was simulated with a pyrimethanil formulation at a semifield scale mimicking worst-case scenarios of soil contamination (e.g. accident or improper disposal). Yeast cells 2-h exposure to the runoff samples led to a significant 2-fold increase in the expression of both indicator genes. These results were compared with those from assays with organisms relevant for the aquatic and soil compartments, namely the nematode Caenorhabditis elegans (reproduction), the freshwater cladoceran Daphnia magna (survival and reproduction), the benthic midge Chironomus riparius (growth), and the soil invertebrates Folsomia candida and Enchytraeus crypticus (survival and reproduction). Under the experimental conditions used to simulate accidental discharges into soil, runoff waters were highly toxic to the standard test organisms, except for C. elegans. Overall, results point out the usefulness of the yeast assay to provide a rapid preview of the toxicity level in preliminary screenings of environmental samples in situations of inadvertent high pesticide contamination. Advantages and limitations of this novel method are discussed. Copyright © 2014 Elsevier B.V. All rights reserved.

  18. Soil washing treatability study

    International Nuclear Information System (INIS)

    Krstich, M.

    1995-12-01

    Soil washing was identified as a viable treatment process option for remediating soil at the FEMP Environmental Management Project (FEMP). Little information relative to the specific application and potential effectiveness of the soil washing process exists that applies to the types of soil at the FEMP. To properly evaluate this process option in conjunction with the ongoing FEMP Remedial Investigation/Feasibility Study (RI/FS), a treatability testing program was necessary to provide a foundation for a detailed technical evaluation of the viability of the process. In August 1991, efforts were initiated to develop a work plan and experimental design for investigating the effectiveness of soil washing on FEMP soil. In August 1992, the final Treatability Study Work Plan for Operable Unit 5: Soil Washing (DOE 1992) was issued. This document shall be referenced throughout the remainder of this report as the Treatability Study Work Plan (TSWP). The purpose of this treatability study was to generate data to support initial screening and the detailed analysis of alternatives for the Operable Unit 5 FS

  19. Geochemical analysis of leachates from cement/low-level radioactive waste/soil systems

    International Nuclear Information System (INIS)

    Criscenti, L.J.; Serne, R.J.

    1988-09-01

    Laboratory experiments were conducted as part of the Special Waste Form Lysimeters/endash/Arid Program. These experiments were conducted to investigate the performance of solidified low-level nuclear waste in a typical arid, near-surface disposal site, and to evaluate the ability of laboratory tests to predict leaching in actual field conditions. Batch leaching, soil adsorption column, and soil/waste form column experiments were conducted using Portland III cement waste forms containing boiling-water reactor evaporator concentrate and ion-exchange resin waste. In order to understand the reaction chemistry of the cement waste form/soil/ground-water system, the compositions of the leachates from the laboratory experiments were studied with the aid of the MINTEQ ion speciation/solubility and mass transfer computer code. The purpose of this report is to describe the changes in leachate composition that occur during the course of the experiments, to discuss the geochemical modeling results, and to explore the factors controlling the major element chemistry of these leachates. 18 refs., 84 figs., 14 tabs

  20. Guidance Manual for Conducting Screening Level Ecological Risk Assessments at the INEL

    Energy Technology Data Exchange (ETDEWEB)

    R. L. VanHorn; N. L. Hampton; R. C. Morris

    1995-06-01

    This document presents reference material for conducting screening level ecological risk assessments (SLERAs)for the waste area groups (WAGs) at the Idaho National Engineering Laboratory. Included in this document are discussions of the objectives of and processes for conducting SLERAs. The Environmental Protection Agency ecological risk assessment framework is closely followed. Guidance for site characterization, stressor characterization, ecological effects, pathways of contaminant migration, the conceptual site model, assessment endpoints, measurement endpoints, analysis guidance, and risk characterization are included.

  1. On the derivation of specific yield and soil water retention characteristics in peatlands from rainfall, microrelief and water level data - Theory and Practice

    Science.gov (United States)

    Dettmann, Ullrich; Bechtold, Michel

    2016-04-01

    Water level depth is one of the crucial state variables controlling the biogeochemical processes in peatlands. For flat soil surfaces, water level depth dynamics as response to boundary fluxes are primarily controlled by the water retention characteristics of the soil in and above the range of the water level fluctuations. For changing water levels, the difference of the integrals of two soil moisture profiles (ΔAsoil), of a lower and a upper water level, is equal to the amount of water received or released by the soil. Dividing ΔAsoil by the water level change, results into a variable that is known as specific yield (Sy). For water level changes approaching the soil surface, changes in soil water storage are small due to the thin unsaturated zone that remains. Consequentially, Sy values approach zero with an abrupt transition to 1 in case of inundation. However, on contrary, observed water level rises due to precipitation events at various locations showed increasing Sy values for water level changes at shallow depths (Sy = precipitation/water level change; Logsdon et al., 2010). The increase of Sy values can be attributed in large parts to the influence of the microrelief on water level changes in these wet landscapes that are characterized by a mosaic of inundated and non-inundated areas. Consequentially, water level changes are dampened by partial inundation. In this situation, total Sy is composed of a spatially-integrated below ground and above ground contribution. We provide a general one-dimensional expression that correctly represents the effect of a microrelief on the total Sy. The one-dimensional expression can be applied for any soil hydraulic parameterizations and soil surface elevation frequency distributions. We demonstrate that Sy is influenced by the microrelief not only when surface storage directly contributes to Sy by (partial) inundation but also when water levels are lower than the minimum surface elevation. With the derived one

  2. Indications for the tracking of elevated nitrogen levels through the fungal route in a soil food web

    International Nuclear Information System (INIS)

    Hogervorst, R.F.; Dijkhuis, M.A.J.; Schaar, M.A. van der; Berg, M.P.; Verhoef, H.A.

    2003-01-01

    Elevated levels of N in soil can be tracked via fungi in the soil food web. - The objective of the present study was to determine the effects of elevated N in dead organic matter on the growth of fungi and to establish the consequences for the development of microbivores. Therefore, three fungal species were cultured on Scots pine litter differing in N content. The growth of the soil fungal species Trichoderma koningii, Penicillium glabrum and Cladosporium cladosporioides was directly influenced by the N content (ranging from 1.25 to 2.19% N) of the substrate. For all three fungal species maximum growth was highest at intermediate N content (1.55%) of the substrate. The fungivorous collembolan Orchesella cincta reached highest asymptotic body mass when fed with C. cladosporioides, grown on litter medium with intermediate N content (1.55%). The growth of O. cincta was lower when fed with C. cladosporioides from litter medium with the highest N content (2.19%). Similar results were obtained in mesocosm experiments in which pine litter with three levels of N (1.11, 1.78, 2.03% N) was used as substrate for the fungi. On litter with the highest N content (2.03%) hyphal length and asymptotic body mass of O. cincta were reduced. The results show that the N content of the substrate determines the growth of both fungi and fungivores, and suggest that elevated levels of N in soil track through the fungal part of the soil food web

  3. Indications for the tracking of elevated nitrogen levels through the fungal route in a soil food web

    Energy Technology Data Exchange (ETDEWEB)

    Hogervorst, R.F.; Dijkhuis, M.A.J.; Schaar, M.A. van der; Berg, M.P.; Verhoef, H.A

    2003-11-01

    Elevated levels of N in soil can be tracked via fungi in the soil food web. - The objective of the present study was to determine the effects of elevated N in dead organic matter on the growth of fungi and to establish the consequences for the development of microbivores. Therefore, three fungal species were cultured on Scots pine litter differing in N content. The growth of the soil fungal species Trichoderma koningii, Penicillium glabrum and Cladosporium cladosporioides was directly influenced by the N content (ranging from 1.25 to 2.19% N) of the substrate. For all three fungal species maximum growth was highest at intermediate N content (1.55%) of the substrate. The fungivorous collembolan Orchesella cincta reached highest asymptotic body mass when fed with C. cladosporioides, grown on litter medium with intermediate N content (1.55%). The growth of O. cincta was lower when fed with C. cladosporioides from litter medium with the highest N content (2.19%). Similar results were obtained in mesocosm experiments in which pine litter with three levels of N (1.11, 1.78, 2.03% N) was used as substrate for the fungi. On litter with the highest N content (2.03%) hyphal length and asymptotic body mass of O. cincta were reduced. The results show that the N content of the substrate determines the growth of both fungi and fungivores, and suggest that elevated levels of N in soil track through the fungal part of the soil food web.

  4. Allelopatic potential of weeds under the minimalization of soil treatment

    Directory of Open Access Journals (Sweden)

    Mikhail A. Mazirov

    2014-01-01

    Full Text Available The content of water-dispersible phenol substances in rhizosphere both of annual and perennial species of weeds (Cirsium arvense, Sonchus arvensis increases under soil treatment minimalization. The higher content of phenol substances of researched weeds is defined in rhizosphere of Common Couch (Agropyrum repens. The absence of intensive anthropogenic treatment of plowing layer which accumulates the significant mass of weed’s roots in the cause of much more higher allelopathic potential of some species’ of weeds. The high level of saturation by weeds in agrophytocoenosis under non-tillage soil treatment is defines the competitiveness between certain sepsis’ of weeds, especially, at the beginning of the vegetation. In this case, increasing the secretion of phenol substances is one of the physiological screenings of such competitiveness.

  5. FARM LEVEL DYNAMIC ANALYSIS OF SOIL CONSERVATION: AN APPLICATION TO THE PIEDMONT AREA OF VIRGINIA

    OpenAIRE

    Segarra, Eduardo; Taylor, Daniel B.

    1987-01-01

    A conceptual optimal control theory model which considers farm level decision making with respect to soil management is developed. A simplified version of the theoretical model is applied to the Piedmont area of Virginia. The model includes the productivity impacts of both soil erosion and technological progress. Both the theoretical model and its empirical application are improvements over previous efforts. Results suggest that farmers in the study area can achieve substantial reductions in ...

  6. Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Terrestrial Plants

    Energy Technology Data Exchange (ETDEWEB)

    Suter, G.W. II

    1993-01-01

    One of the initial stages in ecological risk assessment for hazardous waste sites is screening contaminants to determine which of them are worthy of further consideration as contaminants of potential concern. This process is termed contaminant screening. It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to plants. This report presents a standard method for deriving benchmarks for this purpose (phytotoxicity benchmarks), a set of data concerning effects of chemicals in soil or soil solution on plants, and a set of phytotoxicity benchmarks for 38 chemicals potentially associated with United States Department of Energy (DOE) sites. In addition, background information on the phytotoxicity and occurrence of the chemicals in soils is presented, and literature describing the experiments from which data were drawn for benchmark derivation is reviewed. Chemicals that are found in soil at concentrations exceeding both the phytotoxicity benchmark and the background concentration for the soil type should be considered contaminants of potential concern.

  7. Desirable levels of exchangeable K and Ca and their concentration in the soil solution to reduce uptake of radioactive Cs by rice plants

    International Nuclear Information System (INIS)

    Sekimoto, Hitoshi; Yamada, Takashi; Hotsuki, Tomoe; Matsuzaki, Akio; Mimura, Tetsuro

    2014-01-01

    K in the soil solution can control the uptake of radioactive Cs by rice plants, but this control is not accomplished only by K; it is affected by other ionic species. It is therefore important to investigate uptake of radioactive Cs from the perspective of the concentration of major cations such as Ca in the soil solution and the levels of exchangeable cations in the soil. To clarify the effects of K and Ca in the soil solution and of the levels of soil exchangeable cations to prevent uptake of radioactive Cs, we conducted a pot experiment and field experiments in a paddy soil in 2011 and 2012. To reduce the uptake of radioactive Cs, it was necessary to achieve a K concentration in the soil solution of 0.5 mmol L"-"1, and a Ca concentration higher than 2 mmol L"-"1 based on the results of the pot experiment. In addition, we obtained the desirable levels of exchangeable cations and the cation exchange capacity (CEC) in the soil from previous reports and the results of our field experiments. On this basis, we propose the following threshold levels for exchangeable cations and CEC in the soil as a standard: 0.53 K cmol_c kg"-"1, 18.0 Ca cmol_c kg"-"1, 2.0 Mg cmol_c kg"-"1, i.e. 25 mg K_2O 100 g"-"1, 505 mg CaO 100 g"-"1, 40 Mg O mg 100 g"-"1, and a CEC of 30 cmol_c kg"-"1. Converting these values into the corresponding levels in the soil solution, we obtained concentrations of 0.71 mmol K L"-"1, 4.22 mmol Ca L"-"1, and 1.35 mmol Mg L"-"1. These levels are within the improving standard for fertility of paddy soils in Japan. Consequently, it will be necessary to improve the fertility of paddy soils to control the uptake of radioactive Cs by rice plants. (author)

  8. Preclinical screening for retinopathy of prematurity risk using IGF1 levels at 3 weeks post-partum.

    Directory of Open Access Journals (Sweden)

    Alejandro Pérez-Muñuzuri

    Full Text Available Following current recommendations for preventing retinopathy of prematurity (ROP involves screening a large number of patients. We performed a prospective study to establish a useful screening system for ROP prediction and we have determined that measuring serum levels of IGF1 at week three and the presence of sepsis have a high predictive value for the subsequent development of ROP. A total of 145 premature newborn, with birthweight <1500 g and/or <32 weeks gestational age, were enrolled. 26.9% of them showed some form of retinopathy. A significant association was found between the development of retinopathy and each of the following variables: early gestational age, low birthweight, requiring mechanical ventilation, oxygen treatment, intracranial haemorrhage, sepsis during the first three weeks, bronchopulmonary dysplasia, the need for erythrocyte transfusion, erythropoietin treatment, and low levels of serum IGF1 in the third week. A multiple logistic regression analysis was used to obtain curves for the probability of developing ROP, based on the main factors linked with ROP, namely serum levels of IGF1 and presence of sepsis. Such preclinical screening has the ability to identify patients with high-risk of developing retinopathy and should lead to better prediction for ROP, while at the same time optimising the use of clinical resources, both human and material.

  9. The future of soil protection strategy at the level of European Union at the filed of soil monitoring

    Directory of Open Access Journals (Sweden)

    Ladislav Kubík

    2005-01-01

    Full Text Available European Union deals long with problems of the two components of environment the air and the water. So far soil wasnęt in the main scope of the European Union. The European Union deal now with problems of soil, where we can find question of the soil monitoring. This issue was solve in the framework of the Working group on soil monitoring (WG. The recommendations from the WG are base for deciding of the European Commission, which will have interest to formulate new soil directive. The main tasks of the WG were to review of existing soil monitoring systems, to specify basic soil parameters, indicators, to define soil parameters for each soil threats and to harmonize future soil monitoring activity and soil data.

  10. Assessment of the SMAP Level-4 Surface and Root-Zone Soil Moisture Product Using In Situ Measurements

    NARCIS (Netherlands)

    Reichle, Rolf H.; De Lannoy, Gabrielle J. M.; Liu, Qing; Ardizzone, Joseph V.; Colliander, Andreas; Conaty, Austin; Crow, Wade; Jackson, Thomas J.; Jones, Lucas A.; Kimball, John S.; Koster, Randal D.; Mahanama, Sarith P.; Smith, Edmond B.; Berg, Aaron; Bircher, Simone; Bosch, David; Caldwell, Todd G.; Cosh, Michael; Holifield Collins, Chandra D.; Jensen, Karsten H.; Livingston, Stan; Lopez-baeza, Ernesto; Martínez-fernández, José; Mcnairn, Heather; Moghaddam, Mahta; Pacheco, Anna; Pellarin, Thierry; Prueger, John; Rowlandson, Tracy; Seyfried, Mark; Starks, Patrick; Su, Bob; Thibeault, Marc; Van Der Velde, Rogier; Walker, Jeffrey; Wu, Xiaoling; Zeng, Yijian

    2017-01-01

    The Soil Moisture Active Passive (SMAP) mission Level-4 Surface and Root-Zone Soil Moisture (L4_SM) data product is generated by assimilating SMAP L-band brightness temperature observations into the NASA Catchment land surface model. The L4_SM product is available from 31 March 2015 to present

  11. A brief review and evaluation of earthworm biomarkers in soil pollution assessment.

    Science.gov (United States)

    Shi, Zhiming; Tang, Zhiwen; Wang, Congying

    2017-05-01

    Earthworm biomarker response to pollutants has been widely investigated in the assessment of soil pollution. However, whether and how the earthworm biomarker-approach can be actually applied to soil pollution assessment is still a controversial issue. This review is concerned about the following points: 1. Despite much debate, biomarker is valuable to ecotoxicology and biomarker approach has been properly used in different fields. Earthworm biomarker might be used in different scenarios such as large-scale soil pollution survey and soil pollution risk assessment. Compared with physicochemical analysis, they can provide more comprehensive and straightforward information about soil pollution at low cost. 2. Although many earthworm species from different ecological categories have been tested, Eisenia fetida/andrei is commonly used. Many earthworm biomarkers have been screened from the molecular to the individual level, while only a few biomarkers, such as avoidance behavior and lysosomal membrane stability, have been focused on. Other aspects of the experimental design were critically reviewed. 3. More studies should focus on determining the reliability of various earthworm biomarkers in soil pollution assessment in future research. Besides, establishing a database of a basal level of each biomarker, exploring biomarker response in different region/section/part of earthworm, and other issues are also proposed. 4. A set of research guideline for earthworm biomarker studies was recommended, and the suitability of several earthworm biomarkers was briefly evaluated with respect to their application in soil pollution assessment. This review will help to promote further studies and practical application of earthworm biomarker in soil pollution assessment.

  12. Dialogic and integrated approach to promote soils at different school levels: a Brazilian experience

    Science.gov (United States)

    Muggler, Cristine Carole

    2017-04-01

    From ancient civilizations to present technological societies, soil is the material and immaterial ground of our existence. Soil is essential to life as are water, air and sun light. Nevertheless, it is overlooked and has its functions and importance not known and recognized by people. In formal education and in most school curricula, soil contents are not approached in the same way and intensity other environmental components are. In its essence, soils are an interdisciplinary subject, crossing over different disciplines. It has a great potential as unifying theme that links and synthesizes different contents and areas of knowledge, especially hard sciences as physics, chemistry and biology. Furthermore, soils are familiar and tangible to everyone, making them a meaningful subject that helps to build an efficient learning process. The challenge remains on how to bring such teaching-learning possibilities to formal education at all levels. Soil education deals with the significance of soil to people. What makes soil meaningful? What are the bases for effective learning about soil? The answers are very much related with subjective perceptions and life experiences carried by each individual. Those dimensions have been considered by the pedagogical approach based on Paulo Freire's socio constructivism which considers social inclusion, knowledge building, horizontal learning and collective action. This approach has been applied within the soil (science) education spaces of the Federal University of Viçosa, Minas Gerais, Brazil, both with university students and basic education pupils. At the university an average of 200 students per semester follow a 60 hours Soil Genesis course. With primary and secondary schools the activities are developed through the Soil Education Programme (PES) of the Earth Sciences Museum. In the classes and activities, materials, methods and learning strategies are developed to stimulate involvement, dialogues and exchange of experiences and

  13. Levels of natural radionuclides in soil samples around a phosphate fertilizer plant

    International Nuclear Information System (INIS)

    Ajmal, P.Y.; Sahu, S.K.; Bhangare, R.C.; Pandit, G.G.; Puranik, V.D.

    2010-01-01

    The present study is aimed at the determination of the activity levels of primordial radionuclides in soil from various locations around a phosphate fertilizer plant and also to figure out the external dose rate due to natural gamma background in the area by mapping the dose rates with the geographical co-ordinates within the plant premises

  14. Radon levels and transport parameters in Atlantic Forest soils

    International Nuclear Information System (INIS)

    Farias, E.E.G. de; Silva Neto, P.C. da; Souza, E.M. de; De Franca, E.J.; Hazin, C.A.

    2016-01-01

    In natural forest soils, the radon transport processes can be significantly intensified due to the contribution of living organism activities to soil porosity. In this paper, the first results of the radon concentrations were obtained for soil gas from the Atlantic Forest, particularly in the Refugio Ecologico Charles Darwin, Brazil. The estimation of permeability and radon exhalation rate were carried out in this conservation unit. For forested soils, radon concentrations as high as 40 kBq m -3 were found. Based on the radon concentrations and on the permeability parameter, the results indicated considerable radon hazard for human occupation in the neighborhood. (author)

  15. Recovery of soil unicellular eukaryotes: an efficiency and activity analysis on the single cell level.

    Science.gov (United States)

    Lentendu, Guillaume; Hübschmann, Thomas; Müller, Susann; Dunker, Susanne; Buscot, François; Wilhelm, Christian

    2013-12-01

    Eukaryotic unicellular organisms are an important part of the soil microbial community, but they are often neglected in soil functional microbial diversity analysis, principally due to the absence of specific investigation methods in the special soil environment. In this study we used a method based on high-density centrifugation to specifically isolate intact algal and yeast cells, with the aim to analyze them with flow cytometry and sort them for further molecular analysis such as deep sequencing. Recovery efficiency was tested at low abundance levels that fit those in natural environments (10(4) to 10(6) cells per g soil). Five algae and five yeast morphospecies isolated from soil were used for the testing. Recovery efficiency was between 1.5 to 43.16% and 2 to 30.2%, respectively, and was dependent on soil type for three of the algae. Control treatments without soil showed that the majority of cells were lost due to the method itself (58% and 55.8% respectively). However, the cell extraction technique did not much compromise cell vitality because a fluorescein di-acetate assay indicated high viability percentages (73.3% and 97.2% of cells, respectively). The low abundant algae and yeast morphospecies recovered from soil were cytometrically analyzed and sorted. Following, their DNA was isolated and amplified using specific primers. The developed workflow enables isolation and enrichment of intact autotrophic and heterotrophic soil unicellular eukaryotes from natural environments for subsequent application of deep sequencing technologies. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Interaction of Peat Soil and Sulphidic Material Substratum: Role of Peat Layer and Groundwater Level Fluctuations on Phosphorus Concentration

    Directory of Open Access Journals (Sweden)

    Benito Heru Purwanto

    2014-09-01

    Full Text Available Phosphorus (P often becomes limiting factor for plants growth. Phosphorus geochemistry in peatland soil is associated with the presence of peat layer and groundwater level fluctuations. The research was conducted to study the role of peat layer and groundwater level fluctuations on P concentration in peatland. The research was conducted on deep, moderate and shallow peat with sulphidic material as substratum, peaty acid sulphate soil, and potential acid sulphate soil. While P concentration was observed in wet season, in transition from wet to dry season, and in dry season. Soil samples were collected by using peat borer according to interlayer and soil horizon. The results showed that peat layer might act as the main source of P in peatland with sulphidic material substratum. The upper peat layer on sulphidic material caused by groundwater level fluctuations had no directly effect on P concentration in the peat layers. Increased of P concentration in the lowest sulphidic layer might relate to redox reaction of iron in the sulphidic layer and precipitation process. Phosphorus concentration in peatland with sulphidic material as substratum was not influenced by peat thickness. However, depletion or disappearance of peat layer decreased P concentration in soil solution. Disappearance of peat layer means loss of a natural source of P for peatland with sulphidic material as substratum, therefore peat layer must be kept in order to maintain of peatlands.

  17. Arbuscular mycorrhizal fungi can decrease the uptake of uranium by subterranean clover grown at high levels of uranium in soil

    International Nuclear Information System (INIS)

    Rufyikiri, Gervais; Huysmans, Lien; Wannijn, Jean; Hees, May van; Leyval, Corinne; Jakobsen, Iver

    2004-01-01

    Subterranean clover inoculated or not with the arbuscular mycorrhizal (AM) fungus Glomus intraradices was grown on soil containing six levels of 238 U in the range 0-87 mg kg -1 . Increasing U concentration in soil enhanced the U concentration in roots and shoots of both mycorrhizal and nonmycorrhizal plants but had no significant effects on plant dry matter production or root AM colonization. Mycorrhizas increased the shoot dry matter and P concentration in roots and shoots, while in most cases, it decreased the Ca, Mg and K concentrations in plants. The AM fungus influenced U concentration in plants only in the treatment receiving 87 mg U kg -1 soil. In this case, U concentration in shoots of nonmycorrhizal plants was 1.7 times that of shoots of mycorrhizal plants. These results suggested that mycorrhizal fungi can limit U accumulation by plants exposed to high levels of U in soil. - Plant mycorrhization may decrease U concentration in shoots of plants grown at high level of U in soil

  18. Central interstate low-level radioactive waste compact region site exclusionary screening study. Phase I. Final report

    International Nuclear Information System (INIS)

    1985-06-01

    The Low-Level Radioactive Waste Policy Act of 1980 assigns to the states the responsibility for disposal of the low-level radioactive waste generated within their boundaries. It also provides for regional compacts among states to address their needs on a broader basis and permits restriction of the use of regional disposal facilities after January 1, 1986, to generators of low-level waste within the region. Each state, either individually or as a member of a compact, must therefore consider the establishment of a low-level radioactive waste disposal facility within its borders. The states of Arkansas, Kansas, Louisiana, Nebraska, and Oklahoma adopted the Central Interstate Low-Level Waste Compact (CILLWC) and legislation was submitted to Congress for consent in June of 1983 legislation is being reintroduced in the 99th Congress. In August of 1984, the CILLWC selected and contracted Dames and Moore to conduct a Phase I-Site Suitability Screening Study for a low-level radioactive waste disposal facility in the five-state region. This report presents the results of the Phase I Screening Study. Dames and Moore reported to the Technical Advisory Committee (TAC) of the CILLWC which provided guidance and comment on work progress and direction

  19. Site Screening and Technical Guidance for Monitored Natural Attenuation at DOE Sites

    Energy Technology Data Exchange (ETDEWEB)

    Borns, D.J.; Brady, P.V.; Brady, W.D.; Krupka, K.M.; Spalding, B.P.; Waters, R.D.; Zhang, P.

    1999-03-01

    Site Screening and Technical Guidance for Monitored Natural Attenuation at DOE Sites briefly outlines the biological and geochemical origins of natural attenuation, the tendency for natural processes in soils to mitigate contaminant transport and availability, and the means for relying on monitored natural attenuation (MNA) for remediation of contaminated soils and groundwaters. This report contains a step-by-step guide for (1) screening contaminated soils and groundwaters on the basis of their potential for remediation by natural attenuation and (2) implementing MNA consistent with EPA OSWER Directive 9200.4-17. The screening and implementation procedures are set up as a web-based tool (http://www.sandia.gov/eesector/gs/gc/na/mnahome.html) to assist US Department of Energy (DOE) site environmental managers and their staff and contractors to adhere to EPA guidelines for implementing MNA. This document is intended to support the Decision Maker's Framework Guide and Monitoring Guide both to be issued from DOE EM-40. Further technical advances may cause some of the approach outlined in this document to change over time.

  20. Natural radioactivity levels and estimation of radiation exposure from soils in Bahi and Manyoni Districts in Tanzania

    International Nuclear Information System (INIS)

    Nkuba, Leonid L.; Nyanda, Pendo B.

    2017-01-01

    Soils from Bahi and Manyoni districts in Tanzania were analyzed for radioactivity. The radioactivity levels of 226 Ra, 232 Th and 40 K were measured by direct γ‐ray spectrometry using HPGe detector by Compton suppression method. The radioactivity concentration in soil were computed in arithmetic mean. The results from this study have been compared with those from other areas in Tanzania, different countries of the world and the world average radioactivity in the soil. To assess the radiological effects and hazards indices from natural radionuclides ( 226 Ra, 232 Th and 40 K), the absorbed dose rate (DR), the annual effective dose equivalent (AEDE), Excess Lifetime Cancer Risk (ELCR), the radium equivalent activity (Raeq), the external (Hex), the alpha index (Iα) and the radioactivity level index (Iγ) were calculated. Except for DR in all the soil samples; Raeq, Hex and Iα exceeds the recommended limits due to high activity of 226 Ra in Membeta soils. Also Iγ was above the limits due to higher 226 Ra in soils from Membeta and 232 Th in Ilindi and Nala. Whilst the other radiological parameters (AEDE and ELCR) as well as the Raeq, Hex, Iα and Iγ in same areas were far below the recommended limits. However, this does not guarantee the safety. Therefore the probability of occurrence of the health effects from radiation is significant. The study recommends that the soils from Membeta should not be used as building material because they might expose the population to radiation. (author)

  1. Natural radioactivity levels and estimation of radiation exposure from soils in Bahi and Manyoni Districts in Tanzania

    Energy Technology Data Exchange (ETDEWEB)

    Nkuba, Leonid L.; Nyanda, Pendo B., E-mail: leonid_nkuba@yahoo.co.uk [Tanzania Atomic Energy Commission, Directorate of Radiation Control, Dar es Salaam (Tanzania, United Republic of)

    2017-07-01

    Soils from Bahi and Manyoni districts in Tanzania were analyzed for radioactivity. The radioactivity levels of {sup 226}Ra, {sup 232}Th and {sup 40}K were measured by direct γ‐ray spectrometry using HPGe detector by Compton suppression method. The radioactivity concentration in soil were computed in arithmetic mean. The results from this study have been compared with those from other areas in Tanzania, different countries of the world and the world average radioactivity in the soil. To assess the radiological effects and hazards indices from natural radionuclides ({sup 226}Ra, {sup 232}Th and {sup 40}K), the absorbed dose rate (DR), the annual effective dose equivalent (AEDE), Excess Lifetime Cancer Risk (ELCR), the radium equivalent activity (Raeq), the external (Hex), the alpha index (Iα) and the radioactivity level index (Iγ) were calculated. Except for DR in all the soil samples; Raeq, Hex and Iα exceeds the recommended limits due to high activity of {sup 226}Ra in Membeta soils. Also Iγ was above the limits due to higher {sup 226}Ra in soils from Membeta and {sup 232}Th in Ilindi and Nala. Whilst the other radiological parameters (AEDE and ELCR) as well as the Raeq, Hex, Iα and Iγ in same areas were far below the recommended limits. However, this does not guarantee the safety. Therefore the probability of occurrence of the health effects from radiation is significant. The study recommends that the soils from Membeta should not be used as building material because they might expose the population to radiation. (author)

  2. Effect of organic complexants on the mobility of low-level waste radionuclides in soils: status report

    International Nuclear Information System (INIS)

    Swanson, J.L.

    1981-09-01

    The effects of some organic complexants on the sorption by soil of some elements typical of those present in low-level wastes are being evaluated and procedures are being developed to efficiently obtain valid sorption data. Data have been obtained with Hanford soil and the elements europium, nickel, cobalt, cesium, and strontium. Complexants studied to date include ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), and humic acid. The sorption of cesium and strontium has been found to be affected very little by EDTA or DTPA, as expected. However, these complexants have been found to greatly reduce the sorption of europium, nickel, or cobalt by the soil. The Eu/EDTA system was found to be well behaved, and the effect of the complexant on the sorption by soil was quantified. With nickel and cobalt, however, kinetic problems have been encountered, and the effects of complexants on the sorption by soil have not yet been quantified. The problems encountered in the nickel and cobalt systems have further emphasized the need for the development of methods to assure the general validity of the data obtained in the experiments. Series of experimental results that looked very good within themselves were found by additional procedures to be artifacts of the conditions used. One procedure that has been of great value in identifying invalid data is that of contacting the equilibrated solution from a soil contact with a second batch of soil. Unless the sorption coefficient in the second contact is equivalent to that in the first contact, the data are likely invalid. Efforts are continuing to develop procedures that will allow generally valid data to be obtained in an efficient manner and to employ such procedures to obtain data in a variety of systems pertinent to low-level waste disposal

  3. Persistent Organic Pollutants and Heavy Metal Concentrations in Soil from the Metropolitan Area of Monterrey, Nuevo Leon, Mexico.

    Science.gov (United States)

    Orta-García, Sandra Teresa; Ochoa-Martinez, Angeles Catalina; Carrizalez-Yáñez, Leticia; Varela-Silva, José Antonio; Pérez-Vázquez, Francisco Javier; Pruneda-Álvarez, Lucia Guadalupe; Torres-Dosal, Arturo; Guzmán-Mar, Jorge Luis; Pérez-Maldonado, Iván N

    2016-04-01

    The purpose of this study was to assess the levels of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethane (DDE), and four heavy metals (arsenic, cadmium, and lead) in outdoor surface soils (50 samples) collected from the metropolitan area of Monterrey in Mexico. Total PBDEs levels ranged from 1.80 to 127 µg/kg, with mean total PBDEs level of 14.2 ± 21.5 µg/kg (geometric mean ± standard deviation). For PCBs, the mean total level in the studied soils was 23.5 ± 20.2 µg/kg (range 4.0-65.5 µg/kg). An important finding in our study was that all soil samples (100%) had detectable levels of the metabolite p,p'-DDE. Moreover, the mean total DDT level (∑p'p-DDT and p'p-DDE) was approximately 132 ± 175 µg/kg. The mean levels for arsenic, cadmium, and lead in soil were 5.30 ± 1.35 (range 1.55-7.85) mg/kg, 2.20 ± 1.20 (range 0.65-6.40) mg/kg, and 455 ± 204 (range 224-1230) mg/kg, respectively. Our study has several limitations, the most notable of which is the small sample of soils evaluated. However, this screening study provided concentration data for the occurrence of POPs and four heavy metals in soil from the metropolitan area of Monterrey, Nuevo Leon, Mexico, and taking into consideration that soil is an important pathway of exposure for people, a biomonitoring program for the surveillance of the general population in the metropolitan area of Monterrey, Nuevo Leon is deemed necessary.

  4. Screening for Genes Coding for Putative Antitumor Compounds, Antimicrobial and Enzymatic Activities from Haloalkalitolerant and Haloalkaliphilic Bacteria Strains of Algerian Sahara Soils

    Directory of Open Access Journals (Sweden)

    Okba Selama

    2014-01-01

    Full Text Available Extreme environments may often contain unusual bacterial groups whose physiology is distinct from those of normal environments. To satisfy the need for new bioactive pharmaceuticals compounds and enzymes, we report here the isolation of novel bacteria from an extreme environment. Thirteen selected haloalkalitolerant and haloalkaliphilic bacteria were isolated from Algerian Sahara Desert soils. These isolates were screened for the presence of genes coding for putative antitumor compounds using PCR based methods. Enzymatic, antibacterial, and antifungal activities were determined by using cultural dependant methods. Several of these isolates are typical of desert and alkaline saline soils, but, in addition, we report for the first time the presence of a potential new member of the genus Nocardia with particular activity against the yeast Saccharomyces cerevisiae. In addition to their haloalkali character, the presence of genes coding for putative antitumor compounds, combined with the antimicrobial activity against a broad range of indicator strains and their enzymatic potential, makes them suitable for biotechnology applications.

  5. Cadmium accumulation in different rice cultivars and screening for pollution-safe cultivars of rice.

    Science.gov (United States)

    Yu, Hui; Wang, Junli; Fang, Wei; Yuan, Jiangang; Yang, Zhongyi

    2006-11-01

    Large areas of contaminated land are being used for agricultural production in some countries due to the high demand for food. To minimize the influx of pollutants to the human food chain through consumption of agricultural products, we propose the concept of pollution-safe cultivars (PSCs), i.e. cultivars whose edible parts accumulate a specific pollutant at a level low enough for safe consumption, even when grown in contaminated soil. We tested the feasibility of the PSC concept by growing 43 cultivars of paddy rice (Oryza sativa L., including 20 normal and 23 hybrid cultivars) under a high (75.69-77.55 mg kg(-1)) and a low (1.75-1.85 mg kg(-1)) cadmium (Cd) exposure. These pot experiments took place in the spring and summer of 2004. At the low level of Cd exposure, 30 out of the 43 tested cultivars were found to be Cd-PSCs. Grain Cd concentrations were highly correlated (price grain is genotype-dependent and that the selection of PSCs is possible, at least at a certain level of soil contamination. No Cd-PSCs were found under the high level of Cd exposure. Yield was enhanced in some cultivars and depressed in others in response to elevated soil Cd, indicating that farmers cannot rely on yield depression as an indicator of toxicity of the grains. It is therefore important and feasible to screen for PSCs and to establish PSC breeding programs to effectively and efficiently reduce the risk of human exposure to soil pollutants, such as Cd, through crop consumption.

  6. Effects of biopores on the growth and N-uptake of wheat at three levels of soil moisture

    International Nuclear Information System (INIS)

    Volkmar, K.M.

    1996-01-01

    Roots grow more rapidly through soil spaces such as vacated root channels than through undisturbed soil. This experiment was conducted to determine the extent to which transfer of nutrients is compromised by gaps between the pore wall and the root. Undisturbed cores were obtained from a no-till Dark Brown Chernozemic soil. The cores were divided into three 2.5-cm-thick segments (3.8-6.3 cm, 7.8-10.3 cm, and 11.75-14.25 cm soil layers). The density 200-500 μm (P200) and 500-1000 μm (P500) diameter pores was visually assessed in each segment. The cores were adjusted to water potentials of -0.01, -0.1 and -1.5 MPa by adding K 15 NO 3 -labelled water. Pots containing wheat (Triticum aestivum) plants were placed on top of the cores and the number of roots that appeared at the bottom of the cores, the root length within the cores, and shoot 15 N content were measured after 72 h. Small pore (P200) density had no effect on root number at any moisture level. Large pore (P500) density correlated positively with root number at 0.10 MPa (r 2 0.57) and -1.5 Mpa (r 2 = 0.68). The equation relating shoot 15 N content and root number had a common slope across all moisture treatments, suggesting that the rates of N-uptake per unit root were not compromised by macropore-assisted root growth at the investigated moisture levels. It is unclear if uptake is directly across the pore or via laterals growing outside the pore wall. N-uptake per unit root length of roots growing through soil pores may be compromised at moderate levels of soil moisture. (author). 14 refs., 1 tab., 3 figs

  7. Assessment of soil-gas, soil, and water contamination at the former 19th Street landfill, Fort Gordon, Georgia, 2009-2010

    Science.gov (United States)

    Falls, W. Fred; Caldwell, Andral W.; Guimaraes, Wladmir B.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2011-01-01

    the creek. However, most TPH detections were located in and immediately adjacent to a debris field located within the former landfill and in areas where debris was not visible, including the northwestern and southeastern parts of the study area. Two of the four soil-gas samplers installed within a former military training area adjacent to the landfill also had TPH detections above the method detection level. Benzene, toluene, ethylbenzene, and xylene (as combined BTEX mass) were detected at 0.02 microgram or greater in three soil-gas samplers installed at the northwestern boundary and in five samplers installed in the southeastern part of the study area. There was no BTEX mass detected above the method detection level in samplers installed in the debris field. Toluene was the most frequently detected BTEX compound. Compounds indicative of diesel-range organics were detected above 0.04 microgram in 12 soil-gas samplers and had a distribution similar to that of TPH, including being detected in the debris field. Undecane was the most frequently detected diesel compound. Chloroform and naphthalene were detected in eight and two soil-gas samplers, respectively. Five soil-gas samplers deployed during September 2010 were analyzed for organic compounds classified as chemical agents and explosives, but none exceeded the method detection levels. Five composite soil samples collected from within the estimated boundaries of the former landfill were analyzed for 35 inorganic constituents, but none of the constituents detected exceeded regional screening levels for industrial soils. The sample collected in the debris field exceeded background levels for aluminum, barium, calcium, chromium, lead, nickel, potassium, sodium, and zinc. Three surface-water samples were collected in September 2010 from a stormwater outfall culvert that drains to the creek and from the open channel of the creek at upstream and downstream locations relative to the outfall. Toluene was detected at 0.661 mi

  8. Prevalence of coronary heart disease risk factors and screening for high cholesterol levels among young adults, United States, 1999-2006.

    Science.gov (United States)

    Kuklina, Elena V; Yoon, Paula W; Keenan, Nora L

    2010-01-01

    Previous studies have reported low rates of screening for high cholesterol levels among young adults in the United States. Although recommendations for screening young adults without risk factors for coronary heart disease (CHD) differ, all guidelines recommend screening adults with CHD, CHD equivalents, or 1 or more CHD risk factors. This study examined national prevalence of CHD risk factors and compliance with the cholesterol screening guidelines among young adults. National estimates were obtained using results for 2,587 young adults (men aged 20 to 35 years; women aged 20 to 45 years) from the 1999-2006 National Health and Nutrition Examination Surveys. We defined high low-density lipoprotein cholesterol (LDL-C) as levels higher than the goal specific for each CHD risk category outlined in the National Cholesterol Education Program Adult Treatment Panel III guidelines. About 59% of young adults had CHD or CHD equivalents, or 1 or more of the following CHD risk factors: family history of early CHD, smoking, hypertension, or obesity. In our study, the overall screening rate in this population was less than 50%. Moreover, no significant difference in screening rates between young adults with no risk factors and their counterparts with 1 or more risk factors was found even after adjustment for sociodemographic and health care factors. Approximately 65% of young adults with CHD or CHD equivalents, 26% of young adults with 2 or more risk factors, 12% of young adults with 1 risk factor, and 7% with no risk factor had a high level of LDL-C. CHD risk factors are common in young adults but do not appear to alter screening rates. Improvement of risk assessment and management for cardiovascular disease among young adults is warranted.

  9. Isolation and screening of proangiogenic and antiangiogenic metabolites producing rare actinobacteria from soil.

    Science.gov (United States)

    Azarakhsh, Y; Mohammadipanah, F; Nassiri, S M; Siavashi, V; Hamedi, J

    2017-06-01

    Angiogenesis is a physiological process that has important impacts on the pathology and healing of various diseases, and its induction or inhibition by bioactive actinobacterial metabolites can help the treatment of some diseases. In this study, the effects of actinobacterial extract in the process of angiogenesis have been explored. In this research, proangiogenic and antiangiogenic metabolites producing actinobacteria were isolated from soil samples and their fermentation broth were extracted and after evaluation of their toxicity by MTT assay, antiangiogenic and proangiogenic activities were screened against human umbilical vein endothelial cells (HUVECs) by in vitro tube formation and migration assay. Isolated strains were identified through molecular techniques. The results showed that Nocardiopsis arvandica UTMC 103 and Nonomuraea sp. UTMC 2180 extracts had a high potential of anti-angiogenic activity on HUVECs. For the first time proangiogenic potency of a rare actinobacterium, Kribbella sp. UTMC 522, was reported, and N. arvandica UTMC 103 and Nonomuraea sp. UTMC 2180 extracts inhibits the proliferation, migration and angiogenesis activity of HUVECs with reasonable potency. Metabolites of the introduced rare actinobacteria are potent proangiogenic and angiogenic inhibitors. Identification of angiogenic-antiangiogenic mechanisms and purification of the extracts would be useful in therapeutic angiogenesis. © 2017 The Society for Applied Microbiology.

  10. Organochlorine pesticides in surface soils from obsolete pesticide dumping ground in Hyderabad City, Pakistan: contamination levels and their potential for air-soil exchange.

    Science.gov (United States)

    Alamdar, Ambreen; Syed, Jabir Hussain; Malik, Riffat Naseem; Katsoyiannis, Athanasios; Liu, Junwen; Li, Jun; Zhang, Gan; Jones, Kevin C

    2014-02-01

    This study was conducted to examine organochlorine pesticides (OCPs) contamination levels in the surface soil and air samples together with air-soil exchange fluxes at an obsolete pesticide dumping ground and the associated areas from Hyderabad City, Pakistan. Among all the sampling sites, concentrations of OCPs in the soil and air samples were found highest in obsolete pesticide dumping ground, whereas dominant contaminants were dichlorodiphenyltrichloroethane (DDTs) (soil: 77-212,200 ng g(-1); air: 90,700 pg m(-3)) and hexachlorocyclohexane (HCHs) (soil: 43-4,090 ng g(-1); air: 97,400 pg m(-3)) followed by chlordane, heptachlor and hexachlorobenzene (HCB). OCPs diagnostic indicative ratios reflect historical use as well as fresh input in the study area. Moreover, the air and soil fugacity ratios (0.9-1.0) at the dumping ground reflecting a tendency towards net volatilization of OCPs, while at the other sampling sites, the fugacity ratios indicate in some cases deposition and in other cases volatilization. Elevated concentrations of DDTs and HCHs at pesticide dumping ground and its surroundings pose potential exposure risk to biological organisms, to the safety of agricultural products and to the human health. Our study thus emphasizes the need of spatio-temporal monitoring of OCPs at local and regional scale to assess and remediate the future adverse implications. © 2013.

  11. Criterions for recognition of soil contamination for testing of soil extracts by means of biological testing - determination of ``baseline responses`` of noncontaminated soils; Kriterien zur Erkennung von Bodenkontaminationen bei der Testung von Bodenextrakten mit Hilfe biologischer Wirktests - Ermittlung der ``Grundlevel-Antworten`` unkontaminierter Boeden

    Energy Technology Data Exchange (ETDEWEB)

    Schuphan, I.; Gaipl, S.; Herlitz, E.; Schreiner, J.; Tietz, U. [Technische Hochschule Aachen (Germany). Lehrstuhl fuer Biologie 5

    1997-07-01

    One way to discover contaminations of soil in future is to use biological testing of soil extracts. For this purpose the baseline responses of the biological test systems have to be determined as a basis to distinguish between effects of natural soil components and those of contaminates. These basic level responses have been collected using water and organic extracts of 15 `uncontaminated` soils from different areas of Germany. The use of extracts for testing requires references between the soil extract, the soil itself and the test system. Starting values and the window of competence for testing are proposed. The starting value 1 SE is realized by equivalence of extract aliqouts of a defined soil amount (gramm soil equivalent, g SE) and the amount of test-(cultur)medium in g. The effect limits should be at least the double standard deviation of the blank (extract without soil components). In some test systems higher effect levels have to be fixed according to screening values of `uncontaminated` soils. If no relation can be found to the test-(culture)medium the so called window of competence has to be defined. This is necessary e.g. for the Salmonella mutagenicity test using agar as test medium. In this case screening results of `uncontaminated` soil extracts lead to a gramm Se range, the window of competence, inbetween which no natural response will be found. Extracts giving a mutation ratio (number of revertant colonies from sample extracts/number colonies from the blank) of {>=}2 were considered positively mutagenic. (orig.) [Deutsch] Es sollen kuenftig Bodenkontaminationen durch Testung der entsprechenden Bodenextrakte mit biologischen Wirktests aufgedeckt werden. Dazu muss als Voraussetzung der Grundlevel biologischer Antworten `unbelasteter` Boeden in Testsystemen bestimmt werden. Dieser wurde mit waessrigen und organischen Extrakten von ueber 15 `unbelasteten` Boeden aus verschiedenen Gegenden Deutschlands ermittelt. Die Verwendung von Extrakten fuer die

  12. Examination plan for the soils and low-level radioactive waste forms of the NRC field testing lysimeters

    International Nuclear Information System (INIS)

    McConnell, J.W. Jr.; Rogers, R.D.; Jastrow, J.D.

    1996-01-01

    The Field Lysimeter Investigations: Low-Level Waste Data Base Development Program is obtaining information on the performance of radioactive waste forms. These experiments were recently shut down and have been examined in accordance with a detailed waste form and soil sampling plan. Ion-exchange resins from a commercial nuclear power station were solidified into waste forms using portland cement and vinyl ester-styrene. These waste forms were tested to (a) obtain information on performance of waste forms in typical disposal environments, (b) compare field results with bench leach studies, (c) develop a low-level waste data base for use in performance assessment source term calculations, and (d) apply the DUST computer code to compare predicted cumulative release to actual field data. The program, funded by the Nuclear Regulatory Commission (NRC), includes observed radionuclide releases from waste forms at two test sites over 10 years of successful operation. Lysimeters are ideal systems for obtaining actual field test data because, when properly designed and operated, they can be used to isolate soil and waste systems under actual environmental conditions. The purpose of this paper is to present the experimental plan for the examination of the waste forms and soils of the two lysimeter arrays, which have now been shut down. Vertical soil cores have been taken from the soil columns and will be analyzed with radiochemistry to define movement of radionuclides after release from the waste forms. A comparison is made of the DUST-predicted releases to those previously determined and reported from the lysimeter leachate analyses. That comparison uses new partition coefficients (Kd) recently obtained from laboratory analysis of the lysimeter soils and sand. Those DUST code results also will be compared to actual radionuclide movements through the soil columns as determined from soil core analysis

  13. Assessment of changes of some functions of Ukrainian acid soils after chemical amelioration

    Directory of Open Access Journals (Sweden)

    Zapko Yurij

    2014-09-01

    Full Text Available The objective of the article was to determine the effectiveness of lime of different origin for chemical amelioration of soils and examine its impact on soil functions such as productivity, habitat, regulation of water quality, and the protective buffer biogeocenotic screen. Limy ameliorants were applied in small local field experiment on Luvic Chernozem, and experiment with lysimeter columns was carried out on Albic Luvisol. The number of the main groups of microflora and enzymatic activity of soil was determined in soil samples taken for the analysis from the root zone. Research concerning the influence of natural and industrial origin ameliorants on soil as habitat showed the correlation of sugar beets productivity with soil biogenic. The increase of biomultiplicity of soil microbiota after addition of a cement dust and negative influence of red sludge on soil as habitat for living organisms was observed. Research involving the influence of ameliorants on soil by lime as the protective buffer biogeocenotic screen was carried out using lysimeter columns. It was stated that the addition of limy ameliorants reduces mobility of heavy metals.

  14. Effect of Calcium Levels on Strontium Uptake by Canola Plants Grown on Different Texture Soils

    International Nuclear Information System (INIS)

    El-Shazly, A.A.; Rezk, M. A.; Abdel-Sabour, M.F.; Mousa, E.A.; Mostafa, M.A.Z.; Lotfy, S.M.; Farid, I.M.; Abbas, M.H.H.; Abbas, H.H.

    2016-01-01

    Canola is considered aphytoremediator where, it can remove adequate quantities of heavy metals when grown on polluted soils.This study aimed to investigate growth performance of canola plants grown on clayey non-calcareous, sandy non-calcareous and sandy clay loam calcareous soils with different CaCO 3 contents. These soils were artificially contaminated with 100 mg Sr kg -1 and cultivated with canola plants under three levels of applied calcium i.e. 0, 60 and 85 mg Ca kg -1 in the form of CaCl 2 . The grown plants were kept under the green house conditions until (pot experiment) maturity. Afterwards, plants were harvested, separated into shoots, roots and seeds, and analyzed for their contents of calcium and strontium. Application of calcium to the sandy soil increased Ca uptake by canola plants whereas, Sr uptake, plant growth and seed yield were reduced. In the other soils, Ca and Sr uptake values were increased with minimized Ca rate. Such increases were associated with significant increases in the plant biomass and crop yield in the clayey soil; whereas, in the sandy clay loam calcareous soil, such increases were insignificant. Increasing the dose of the applied Ca (its higher rate) was associated with significant reduction in the plant growth and seed yield in these two soils. Both the biological concentration factor and the biological accumulation factors were relatively high (>1). The biological transfer factor was also high indicating high translocation of Sr from root to shoot. However, Sr translocation decreased with Ca applications. Accordingly canola plants are highly recommended for phytoextraction of Sr from polluted soils

  15. Comparison of radionuclide levels in soil, sagebrush, plant litter, cryptogams, and small mammals

    International Nuclear Information System (INIS)

    Landeen, D.S.

    1994-09-01

    Soil, sagebrush, plant litter, cryptogam, and small mammal samples were collected and analyzed for cesium-137, strontium-90, plutonium-238, plutonium 239/240, technetium-99, and iodine-129 from 1981 to 1986 at the US Department of Energy Hanford Site in southeastern Washington State as part of site characterization and environmental monitoring activities. Samples were collected on the 200 Areas Plateau, downwind from ongoing waste management activities. Plant litter, cryptogams, and small mammals are media that are not routinely utilized in monitoring or characterization efforts for determination of radionuclide concentrations. Studies at Hanford, other US Department of Energy sites, and in eastern Europe have indicated that plant litter and cryptogams may serve as effective ''natural'' monitors of air quality. Plant litter in this study consists of fallen leaves from sagebrush and ''cryptogams'' describes that portion of the soil crust composed of mosses, lichens, algae, and fungi. Comparisons of cesium-137 and strontium-90 concentrations in the soil, sagebrush, litter, and cryptogams revealed significantly higher (p<0.05) levels in plant litter and cryptogams. Technetium-99 values were the highest in sagebrush and litter. Plutonium-238 and 239/40 and iodine-129 concentrations never exceeded 0.8 pCi/gm in all media. No evidence of any significant amounts of any radionuclides being incorporated into the small mammal community was discovered. The data indicate that plant litter and cryptogams may be better, indicators of environmental quality than soil or vegetation samples. Augmenting a monitoring program with samples of litter and cryptogams may provide a more accurate representation of radionuclide environmental uptake and/or contamination levels in surrounding ecosystems. The results of this study may be applied directly to other radioecological monitoring conducted at other nuclear sites and to the monitoring of other pollutants

  16. Growth and physiological response of lemongrass (Cymbopogon citratus (D.C.) Stapf.) under different levels of fly ash-amended soil.

    Science.gov (United States)

    Panda, Debabrata; Panda, Dibyajyoti; Padhan, Bandana; Biswas, Meghali

    2018-05-12

    Revegetation with metal tolerant plants for management of fly ash deposits is an important environmental perspective nowadays. Growth performance, photosynthesis, and antioxidant defense of lemongrass (Cymbopogon citratus (D.C.) Stapf.) were evaluated under various combination of fly ash amended with garden soil in order to assess its fly ash tolerance potential. Under low level of fly ash (25%) amended soil, the plant growth parameters such as shoot, root, and total plant biomass as well as metal tolerance index were increased compared to the control plants grown on garden soil, followed by decline under higher concentration of fly ash (50%, 75% and 100%). In addition, leaf photosynthetic rate, stomatal conductance, and photosystem (PS) II activity were not significantly changed under low level of fly ash (25%) amended soil compared to the garden soil but these parameters were significantly decreased further with increase of fly ash concentrations. Furthermore, increase of activities of some antioxidant enzymes such as superoxide dismutase, ascorbate peroxidase, and guaiacol peroxidase over control were noticed in lemongrass under all fly ash treatments. Taken together, the study suggests that lemongrass can be used for phytoremediation of fly ash at 25% amended soil.

  17. Migrant screening: Lessons learned from the migrant holding level at the Greek-Turkish borders.

    Science.gov (United States)

    Eonomopoulou, Assimoula; Pavli, Androula; Stasinopoulou, Panagiota; Giannopoulos, Lambros A; Tsiodras, Sotirios

    In March 2011, a migrant health project became operational that aimed to provide medical and psychosocial support to migrants at the Greek-Turkish border. The aim of this study is to describe common syndromes, the communicable disease profile and vaccination patterns in newly arrived migrants through a surveillance system that was based on medical records data as well as screening procedures. Data were collected prospectively using one standardized form per patient including demographic information, civil status, and medical and vaccination history. A tuberculin screening test (TST) and serological testing for HIV, hepatitis B and hepatitis C were performed after obtaining informed consent. A total of 6899 migrants were screened, the majority of whom were male (91%) and 18-31 years old (85%), with a mean age of 25.3 years. Of all patients, 2.5% received secondary care. Common complaints and diagnoses included respiratory infections (23%) and myalgia (18%). The tuberculin screening test (TST) was positive in 7.8% out of 1132 patients tested. Out of 632 migrants, 0.3%, 3.2% and 0.8% tested positive for HIV, hepatitis B and hepatitis C, respectively. Overall, 22.3% of adults were vaccinated against poliomyelitis. Irregular migrants that enter Greek borders are generally in good health. Nevertheless, the risk of spreading communicable diseases is an important issue to consider among migrants at the holding level due to severe overcrowding conditions. Therefore, there is a need to strengthen surveillance and implement harmonized screening procedures with the aim of providing sustainable and good quality services that are focused on prevention and early treatment. Copyright © 2016 King Saud Bin Abdulaziz University for Health Sciences. Published by Elsevier Ltd. All rights reserved.

  18. Use of engineered soils and other site modifications for low-level radioactive waste disposal

    International Nuclear Information System (INIS)

    1994-08-01

    The U.S. Nuclear Regulatory Commission requires that low-level radioactive waste (LLW) disposal facilities be designed to minimize contact between waste and infiltrating water through the use of site design features. The purpose of this investigation is to identify engineered barriers and evaluate their ability to enhance the long-term performance of an LLW disposal facility. Previously used barriers such as concrete overpacks, vaults, backfill, and engineered soil covers, are evaluated as well as state-of-the-art barriers, including an engineered sorptive soil layer underlying a facility and an advanced design soil cover incorporating a double-capillary layer. The purpose of this investigation is also to provide information in incorporating or excluding specific engineered barriers as part of new disposal facility designs. Evaluations are performed using performance assessment modeling techniques. A generic reference disposal facility design is used as a baseline for comparing the improvements in long-term performance offered by designs incorporating engineered barriers in generic and humid environments. These evaluations simulate water infiltration through the facility, waste leaching, radionuclide transport through the facility, and decay and ingrowth. They also calculate a maximum (peak annual) dose for each disposal system design. A relative dose reduction factor is calculated for each design evaluated. The results of this investigation are presented for concrete overpacks, concrete vaults, sorptive backfill, sorptive engineered soil underlying the facility, and sloped engineered soil covers using a single-capillary barrier and a double-capillary barrier. Designs using combinations of barriers are also evaluated. These designs include a vault plus overpacks, sorptive backfill plus overpacks, and overpack with vault plus sorptive backfill, underlying sorptive soil, and engineered soil cover

  19. Screening and comparison of remedial alternatives for the South Field and flyash piles at the Fernald site

    International Nuclear Information System (INIS)

    Bumb, A.C.; Jones, G.N.

    1996-05-01

    The South Field, the Inactive Flyash Pile, and the Active Flyash Pile are in close proximity to each other and are part of Operable Unit 2 (OU2) at the Fernald Environmental Management Project (FEMP). The baseline risk assessment indicated that the exposure pathways which pose the most significant risk are external radiation from radionuclides in surface soils and use of uranium contaminated groundwater. This paper presents screening and comparison of various remedial alternatives considered to mitigate risks from the groundwater pathway. Eight remedial alternatives were developed which consisted of consolidation and capping, excavation and off-site disposal with or without treatment, excavation and on-site disposal with or without treatment and combinations of these. Risk-based source (soil) preliminary remediation levels (PRLs) and waste acceptance criteria (WACs) were developed for consolidation and capping, excavation, and on-site disposal cell. The PRLs and WACs were developed using an integrated modeling tool consisting of an infiltration model, a surface water model, a vadose zone model, and a three-dimensional contaminant migration model in saturated media. The PRLs and WACs were then used to determine need for soil treatment, determine excavation volumes, and screen remedial alternatives. The selected remedial alternative consisted of excavation and on-site disposal with off-site disposal of the fraction exceeding the WAC

  20. [Soil seed bank and its correlations with aboveground vegetation and environmental factors in water level fluctuating zone of Danjiangkou Reservoir, Central China].

    Science.gov (United States)

    Liu, Rui-Xue; Zhan, Juan; Shi, Zhi-Hua; Chen, Long-qing

    2013-03-01

    Taking the water level fluctuating zone of the Danjiangkou Reservoir as a case, and by the method of hierarchical cluster analysis, the soil seed banks at 37 sampling plots within the areas of 140-145 m elevation were divided into 6 groups, and the species composition, density, and diversity of the soil seed banks among the groups were compared. The differences between the soil seed banks and the aboveground vegetations were analyzed by S0rensen similarity coefficient, and the correlations among the soil seed banks, aboveground vegetations, and environmental factors were explored by principal component analysis (PCA) and multivariable regression analysis. At the same altitudes of the water level fluctuating zone, the species composition of the soil seed banks had obvious heterogeneity, and the density and diversity indices of the soil seed banks among different groups were great. The similarity coefficient between the soil seed banks and aboveground vegetations was low, and the species number in the soil seed banks was obviously lesser than that in the aboveground vegetations. The density of the soil seed banks was highly positively correlated with the aboveground vegetations coverage and species number and the soil texture, but highly negatively correlated with the soil water-holding capacity and soil porosity.

  1. Infiltration properties of covering soil into the void of buried concrete waste due to fluctuation of ground water level and its prevention

    International Nuclear Information System (INIS)

    Takatsu, Tadashi; Tadano, Hideki; Abe, Satoshi; Imai, Jun; Yanagisawa, Eiji; Mitachi, Toshiyuki

    1999-01-01

    Low level radioactive concrete waste will be produced in future by breaking up the nuclear facilities, and the waste will be disposed in shallow depth of ground. In order to prepare for those situation, it is needed to clarify the infiltration properties of the covering soil into the void of buried concrete waste due to the fluctuation of ground water level and to develop the prevention methods against the infiltration of the covering soil. In this study, full-scale concrete structure specimens were broken up, and were compacted in large scale testing boxes and a series tests changing water level up and down in the concrete waste and covering soil were performed. From the test results, it was found that the appropriate filter installed between the covering soil and the concrete waste, enable us to prevent the infiltration of covering soil into the void of concrete waste. (author)

  2. Soil Characterization by Large Scale Sampling of Soil Mixed with Buried Construction Debris at a Former Uranium Fuel Fabrication Facility

    International Nuclear Information System (INIS)

    Nardi, A.J.; Lamantia, L.

    2009-01-01

    Recent soil excavation activities on a site identified the presence of buried uranium contaminated building construction debris. The site previously was the location of a low enriched uranium fuel fabrication facility. This resulted in the collection of excavated materials from the two locations where contaminated subsurface debris was identified. The excavated material was temporarily stored in two piles on the site until a determination could be made as to the appropriate disposition of the material. Characterization of the excavated material was undertaken in a manner that involved the collection of large scale samples of the excavated material in 1 cubic meter Super Sacks. Twenty bags were filled with excavated material that consisted of the mixture of both the construction debris and the associated soil. In order to obtain information on the level of activity associated with the construction debris, ten additional bags were filled with construction debris that had been separated, to the extent possible, from the associated soil. Radiological surveys were conducted of the resulting bags of collected materials and the soil associated with the waste mixture. The 30 large samples, collected as bags, were counted using an In-Situ Object Counting System (ISOCS) unit to determine the average concentration of U-235 present in each bag. The soil fraction was sampled by the collection of 40 samples of soil for analysis in an on-site laboratory. A fraction of these samples were also sent to an off-site laboratory for additional analysis. This project provided the necessary soil characterization information to allow consideration of alternate options for disposition of the material. The identified contaminant was verified to be low enriched uranium. Concentrations of uranium in the waste were found to be lower than the calculated site specific derived concentration guideline levels (DCGLs) but higher than the NRC's screening values. The methods and results are presented

  3. Nutrient critical levels and availability in soils cultivated with peach palm (Bactris gasipaes Kunth. in Santo Domingo de Los Tsáchilas, Ecuador

    Directory of Open Access Journals (Sweden)

    Carlos Julio Quezada Crespo

    2017-04-01

    Full Text Available Ecuador is the most important exporter of canned peach palm, however, to date ideal soil fertility characteristics for peach palm growers remain unknown. The aim of this research was to determine optimal levels of soil nutrients for the cultivation of peach palm, specifically with regards to soil cation exchange capacity in order to obtain higher yields. We worked with 20 farmsteads and their soils from the province of Santo Domingo de los Tsáchilas during the second half of 2014. Fields were evaluated based on a relative yield and extractable (modified Olsen nutrient contents in each soil were determined using regression modeling to determine critical levels of each nutrient and specifically to determine the ideal soil cation exchange capacity under peach palm cultivation. Our analysis established critical levels of soil pH (6.3; OM 6.5%; P 12.3 mg.dm-3; K 0.67 cmol.dm-3 K; Ca 5.1 cmol.dm-3 ; Mg 0.97 cmol.dm-3; and S 7.5 mg.dm-3. The ideal Ca: Mg: K soil cation exchange capacity was determined to be 76:14:10.

  4. Urban Adolescents’ Physical Activity Experience, Physical Activity Levels, and Use of Screen-Based Media during Leisure Time: A Structural Model

    Directory of Open Access Journals (Sweden)

    Hui Xie

    2018-01-01

    Full Text Available There is limited understanding of the relationship between physical activity and use of screen-based media, two important behaviors associated with adolescents’ health outcomes. To understand this relationship, researchers may need to consider not only physical activity level but also physical activity experience (i.e., affective experience obtained from doing physical activity. Using a sample predominantly consisting of African and Latino American urban adolescents, this study examined the interrelationships between physical activity experience, physical activity level, and use of screen-based media during leisure time. Data collected using self-report, paper and pencil surveys was analyzed using structural equation modeling. Results showed that physical activity experience was positively associated with physical activity level and had a direct negative relationship with use of non-active video games for males and a direct negative relationship with use of computer/Internet for both genders, after controlling for physical activity level. Physical activity level did not have a direct relationship with use of non-active video games or computer/Internet. However, physical activity level had a direct negative association with use of TV/movies. This study suggests that physical activity experience may play an important role in promoting physical activity and thwarting use of screen-based media among adolescents.

  5. Urban Adolescents’ Physical Activity Experience, Physical Activity Levels, and Use of Screen-Based Media during Leisure Time: A Structural Model

    Science.gov (United States)

    Xie, Hui; Scott, Jason L.; Caldwell, Linda L.

    2018-01-01

    There is limited understanding of the relationship between physical activity and use of screen-based media, two important behaviors associated with adolescents’ health outcomes. To understand this relationship, researchers may need to consider not only physical activity level but also physical activity experience (i.e., affective experience obtained from doing physical activity). Using a sample predominantly consisting of African and Latino American urban adolescents, this study examined the interrelationships between physical activity experience, physical activity level, and use of screen-based media during leisure time. Data collected using self-report, paper and pencil surveys was analyzed using structural equation modeling. Results showed that physical activity experience was positively associated with physical activity level and had a direct negative relationship with use of non-active video games for males and a direct negative relationship with use of computer/Internet for both genders, after controlling for physical activity level. Physical activity level did not have a direct relationship with use of non-active video games or computer/Internet. However, physical activity level had a direct negative association with use of TV/movies. This study suggests that physical activity experience may play an important role in promoting physical activity and thwarting use of screen-based media among adolescents. PMID:29410634

  6. Determination of hydraulic properties of unsaturated soil via inverse modeling

    International Nuclear Information System (INIS)

    Kodesova, R.

    2004-01-01

    The method for determining the hydraulic properties of unsaturated soil with inverse modeling is presented. A modified cone penetrometer has been designed to inject water into the soil through a screen, and measure the progress of the wetting front with two tensiometer rings positioned above the screen. Cumulative inflow and pressure head readings are analyzed to obtain estimates of the hydraulic parameters describing K(h) and θ(h). Optimization results for tests at one side are used to demonstrate the possibility to evaluate either the wetting branches of the soil hydraulic properties, or the wetting and drying curves simultaneously, via analysis of different parts of the experiment. The optimization results are compared to the results of standard laboratory and field methods. (author)

  7. Level of heavy metals in soils and lemon grass in Jos, Bukuru and ...

    African Journals Online (AJOL)

    Level of heavy metals in soils and lemon grass in Jos, Bukuru and environs, Nigeria. SJ Salami, EA Akande, DM Zachariah. Abstract. No Abstract. Global Journal of Pure and Applied Sciences Vol. 13 (2) 2007: pp. 193-196. Full Text: EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT · DOWNLOAD FULL TEXT ...

  8. Targeting the environmental assessment of veterinary drugs with the multi-species-soil system (MS{center_dot}3) agricultural soil microcosms: the ivermectin case study

    Energy Technology Data Exchange (ETDEWEB)

    Carbonell-Martin, G.; Pro-Gonzalez, J.; Aragones-Grunert, P.; Babib-Vich, M. M.; Fernandez-Rorija, C.; Tarazona-Lafarga, J. V.

    2011-07-01

    The environmental risk assessment of the veterinary pharmaceutical ivermectin is receiving significant attention. This paper assesses the capacity of the MS{center_dot}3 soil microcosm as a tool for targeting the environmental impact assessment of veterinary drugs, using ivermectin as model. Two screening MS{center_dot}3 were performed using different European soils; one with a soil collected in an agricultural station near to Madrid, Spain and a second with a soil collected in a farm area close to York, UK. Soils were fortified with ivermectin at the following ranges: 0.01-10 mg kg{sup -}1 and 0.1-100 mg kg{sup -}1 in the Madrid and York studies, respectively. The effects on earthworms, plants and soil microorganisms were assessed in the Madrid soil. Toxicity tests on aquatic organisms (algae, cladocerans and in vitro fish cell line RTLW1) were also conducted with the leachates. No effects were observed in earthworms and plants at any tested concentration; reduction in the respiration rate (< 5%) of soil microorganisms was detected. Earthworm/soil bioconcentration factors decreased with the increase in soil concentrations and were higher for the York soil. Effects on daphnids were observed in tested leachates; based on measured levels of ivermectin in the leachates an EC50 of about 0.5{mu}gL{sup -}1 can be estimated. Comparisons based on toxicity data and equilibrium partitioning confirmed that the main risk is expected to be related to the high sensitivity of cladocerans. The results confirm that MS{center_dot}3 systems are cost-effective tools for assessing the impact of veterinary pharmaceuticals when applied to agricultural land, as previously demonstrated for antimicrobials. (Author) 39 refs.

  9. Intrinsic and induced isoproturon catabolic activity in dissimilar soils and soils under dissimilar land use

    International Nuclear Information System (INIS)

    Reid, Brian J.; Papanikolaou, Niki D.; Wilcox, Ronah K.

    2005-01-01

    The catabolic activity with respect to the systemic herbicide isoproturon was determined in soil samples by 14 C-radiorespirometry. The first experiment assessed levels of intrinsic catabolic activity in soil samples that represented three dissimilar soil series under arable cultivation. Results showed average extents of isoproturon mineralisation (after 240 h assay time) in the three soil series to be low. A second experiment assessed the impact of addition of isoproturon (0.05 μg kg -1 ) into these soils on the levels of catabolic activity following 28 days of incubation. Increased catabolic activity was observed in all three soils. A third experiment assessed levels of intrinsic catabolic activity in soil samples representing a single soil series managed under either conventional agricultural practice (including the use of isoproturon) or organic farming practice (with no use of isoproturon). Results showed higher (and more consistent) levels of isoproturon mineralisation in the soil samples collected from conventional land use. The final experiment assessed the impact of isoproturon addition on the levels of inducible catabolic activity in these soils. The results showed no significant difference in the case of the conventional farm soil samples while the induction of catabolic activity in the organic farm soil samples was significant. - Dissimilar levels of isoproturon catabolic activity in dissimilar soils and soils under dissimilar land use influence inferred risk

  10. Intrinsic and induced isoproturon catabolic activity in dissimilar soils and soils under dissimilar land use

    Energy Technology Data Exchange (ETDEWEB)

    Reid, Brian J. [School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ (United Kingdom)]. E-mail: b.reid@uea.ac.uk; Papanikolaou, Niki D. [School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ (United Kingdom); Wilcox, Ronah K. [School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ (United Kingdom)

    2005-02-01

    The catabolic activity with respect to the systemic herbicide isoproturon was determined in soil samples by {sup 14}C-radiorespirometry. The first experiment assessed levels of intrinsic catabolic activity in soil samples that represented three dissimilar soil series under arable cultivation. Results showed average extents of isoproturon mineralisation (after 240 h assay time) in the three soil series to be low. A second experiment assessed the impact of addition of isoproturon (0.05 {mu}g kg{sup -1}) into these soils on the levels of catabolic activity following 28 days of incubation. Increased catabolic activity was observed in all three soils. A third experiment assessed levels of intrinsic catabolic activity in soil samples representing a single soil series managed under either conventional agricultural practice (including the use of isoproturon) or organic farming practice (with no use of isoproturon). Results showed higher (and more consistent) levels of isoproturon mineralisation in the soil samples collected from conventional land use. The final experiment assessed the impact of isoproturon addition on the levels of inducible catabolic activity in these soils. The results showed no significant difference in the case of the conventional farm soil samples while the induction of catabolic activity in the organic farm soil samples was significant. - Dissimilar levels of isoproturon catabolic activity in dissimilar soils and soils under dissimilar land use influence inferred risk.

  11. Macro and micro nutrient uptake parameters and use efficiency in cacao genotypes influenced by deficient to excess levels of soil K

    Science.gov (United States)

    Cacao (Theobroma cacao L.) is an important economic crop for many of the tropical countries. Adequate levels of soil K are essential for good growth and achieving high cocoa bean yields. Soils under cacao invariably have low levels of plant available K to support good cacao growth. Growth chamber ex...

  12. 100 Area soil washing treatability test plan

    International Nuclear Information System (INIS)

    1993-03-01

    This test plan describes specifications, responsibilities, and general methodology for conducting a soil washing treatability study as applied to source unit contamination in the 100 Area. The objective ofthis treatability study is to evaluate the use of physical separation systems and chemical extraction methods as a means of separating chemically and radioactively contaminated soil fractions from uncontaminated soil fractions. The purpose of separating these fractions is to minimize the volume of soil requiring permanent disposal. It is anticipated that this treatability study will be performed in two phases of testing, a remedy screening phase and a remedy selection phase. The remedy screening phase consists of laboratory- and bench-scale studies performed by Battelle Pacific Northwest laboratories (PNL) under a work order issued by Westinghouse Hanford Company (Westinghouse Hanford). This phase will be used to provide qualitative evaluation of the potential effectiveness of the soil washing technology. The remedy selection phase, consists of pilot-scale testing performed under a separate service contract to be competitively bid under Westinghouse Hanford direction. The remedy selection phase will provide data to support evaluation of the soil washing technology in future feasibility studies for Interim Remedial Measures (IRMs) or final operable unit (OU) remedies. Performance data from these tests will indicate whether applicable or relevant and appropriate requirements (ARARs) or cleanup goals can be met at the site(s) by application of soil washing. The remedy selection tests wig also allow estimation of costs associated with implementation to the accuracy required for the Feasibility Study

  13. Derivation of Soil Ecological Criteria for Copper in Chinese Soils.

    Science.gov (United States)

    Wang, Xiaoqing; Wei, Dongpu; Ma, Yibing; McLaughlin, Mike J

    2015-01-01

    Considerable information on copper (Cu) ecotoxicity as affected by biological species and abiotic properties of soils has been collected from the last decade in the present study. The information on bioavailability/ecotoxicity, species sensitivity and differences in laboratory and field ecotoxicity of Cu in different soils was collated and integrated to derive soil ecological criteria for Cu in Chinese soils, which were expressed as predicted no effect concentrations (PNEC). First, all ecotoxicity data of Cu from bioassays based on Chinese soils were collected and screened with given criteria to compile a database. Second, the compiled data were corrected with leaching and aging factors to minimize the differences between laboratory and field conditions. Before Cu ecotoxicity data were entered into a species sensitivity distribution (SSD), they were normalized with Cu ecotoxicity predictive models to modify the effects of soil properties on Cu ecotoxicity. The PNEC value was set equal to the hazardous concentration for x% of the species (HCx), which could be calculated from the SSD curves, without an additional assessment factor. Finally, predictive models for HCx based on soil properties were developed. The soil properties had a significant effect on the magnitude of HCx, with HC5 varying from 13.1 mg/kg in acidic soils to 51.9 mg/kg in alkaline non-calcareous soils. The two-factor predictive models based on soil pH and cation exchange capacity could predict HCx with determination coefficients (R2) of 0.82-0.91. The three-factor predictive models--that took into account the effect of soil organic carbon--were more accurate than two-factor models, with R2 of 0.85-0.99. The predictive models obtained here could be used to calculate soil-specific criteria. All results obtained here could provide a scientific basis for revision of current Chinese soil environmental quality standards, and the approach adopted in this study could be used as a pragmatic framework for

  14. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    International Nuclear Information System (INIS)

    Prata, Fabio; Cardinali, Vanessa Camponez do Brasil; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges; Lavorenti, Arquimedes

    2003-01-01

    The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with Kh 2 PO 4 at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha -1 of P 2 O 5 , which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L -1 ), with a 14 C radioactivity of 0.233 kBq mL -1 . Four steps of the desorption procedures withCaCl 2 0.01 mol L -1 and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L -1 ). Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm -3 . Moreover, a small amount of applied glyphosate was extracted (<10%), and the extraction increased with increasing soil phosphorus content. (author)

  15. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    Directory of Open Access Journals (Sweden)

    Prata Fábio

    2003-01-01

    Full Text Available The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with KH2PO4 at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha-1 of P2O5, which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L-1, with a 14C radioactivity of 0.233 kBq mL-1. Four steps of the desorption procedure with CaCl2 0.01 mol L-1 and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L-1. Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm-3. Moreover, a small amount of applied glyphosate was extracted (<10%, and the extraction increased with increasing soil phosphorus content.

  16. Effect of population breast screening on breast cancer mortality up to 2005 in England and Wales: an individual-level cohort study.

    Science.gov (United States)

    Johns, Louise E; Coleman, Derek A; Swerdlow, Anthony J; Moss, Susan M

    2017-01-17

    Population breast screening has been implemented in the UK for over 25 years, but the size of benefit attributable to such programmes remains controversial. We have conducted the first individual-based cohort evaluation of population breast screening in the UK, to estimate the impact of the NHS breast screening programme (NHSBSP) on breast cancer mortality. We followed 988 090 women aged 49-64 years in 1991 resident in England and Wales, who because of the staggered implementation of the NHSBSP, included both invited subjects and an uninvited control group. Individual-level breast screening histories were linked to individual-level mortality and breast cancer incidence data from national registers. Risk of death from breast cancer was investigated by incidence-based mortality analyses in relation to intention to screen and first round attendance. Overdiagnosis of breast cancer following a single screening round was also investigated. Invitation to NHSBSP screening was associated with a reduction in breast cancer mortality in 1991-2005 of 21% (RR=0.79, 95% CI: 0.73-0.84, PBreast cancer deaths among first invitation attenders were 46% lower than among non-attenders (RR=0.54, 95% CI: 0.51-0·57, Pscreen. The results indicate a substantial, statistically significant reduction in breast cancer mortality between 1991 and 2005 associated with NHSBSP activity. This is important in public health terms.

  17. Total and Bioaccessible Soil Arsenic and Lead Levels and Plant Uptake in Three Urban Community Gardens in Puerto Rico

    Directory of Open Access Journals (Sweden)

    John Misenheimer

    2018-01-01

    Full Text Available Arsenic (As and lead (Pb are two contaminants of concern associated with urban gardening. In Puerto Rico, data currently is limited on As and Pb levels in urban garden soils, soil metal (loid bioaccessibility, and uptake of As and Pb in soil by edible plants grown in the region. This study examined total and bioaccessible soil As and Pb concentrations and accumulation in 10 commonly grown garden plants collected from three urban community gardens in Puerto Rico. Bioavailability values were predicted using bioaccessibility data to compare site-specific bioavailability estimates to commonly used default exposure assumptions. Total and bioaccessible As levels in study soils ranged from 2 to 55 mg/kg and 1 to 18 mg/kg, respectively. Total and bioaccessible Pb levels ranged from 19 to 172 mg/kg and 17 to 97 mg/kg, respectively. Measured bioaccessibility values corresponded to 19% to 42% bioaccessible As and 61% to 100% bioaccessible Pb when expressed as a percent of total As and Pb respectively. Predicted relative percent bioavailability of soil As and Pb based on measured bioaccessibility values ranged from 18% to 36% and 51% to 85% for As and Pb respectively. Transfer factors (TFs measuring uptake of As in plants from soil ranged from 0 to 0.073 in the edible flesh (fruit or vegetable of plant tissues analyzed and 0.073 to 0.444 in edible leaves. Pb TFs ranged from 0.002 to 0.012 in flesh and 0.023 to 0.204 in leaves. Consistent with TF values, leaves accumulated higher concentrations of As and Pb than the flesh, with the highest tissue concentrations observed in the culantro leaf (3.2 mg/kg dw of As and 8.9 mg/kg dw of Pb. Leaves showed a general but not statistically-significant (α = 0.05 trend of increased As and Pb concentration with increased soil levels, while no trend was observed for flesh tissues. These findings provide critical data that can improve accuracy and reduce uncertainty when conducting site-specific risk determination of

  18. Influence of heavy metals in non-anthropized soils with high levels of primordial radionuclides

    International Nuclear Information System (INIS)

    Bezerra, Jairo Dias; Amaral, Romilton dos Santos; Santos Junior, Jose Araujo dos; Rocha, Edilson Accioly; Oliveira, Jose Valdez Monterazo de; Bispo, Rodrigo Cesar Bezerra

    2011-01-01

    High concentrations of heavy metals in the ecosystem depend naturally geological formation in each area of the planet and of anthropic activities that contribute to contamination of soil, water sources and food produced in these areas. In this context, we highlight the importance in the study of As, Cr and Ba because of the level of toxicity, availability and chemical speciation that have. The study area was chosen to present agricultural activity and milk production on a large scale. This area is located in the rugged region of the state of Pernambuco, in the town of stone, where the arable soil was monitored aiming to determine the levels of these metals. Analyses were performed by the technique of neutron activation analysis coupled with the high-resolution gamma spectrometry. Were analyzed twenty-three soil samples collected from the horizon C. The results obtained varied from values smaller that (0.2 to 6.7) mg.kg -1 for As; (12.1 to 65.5) mg.kg -1 for Cr and (443 a 1,497) mg.kg -1 for Ba. Comparing them with the values established by CONAMA Resolution 420/2009, it was found that the concentrations of Ba are 100% above the value of prevention, and approximately 91% of values above the intervention value. The As and Cr showed 100% of results below the value of prevention. Whereas the study area has no industrial activity, high concentrations are determined for the Ba from natural processes. For the levels found evidence of a possible contamination of water sources and food produced in this region. (author)

  19. An electronic screen for triaging adolescent substance use by risk levels.

    Science.gov (United States)

    Levy, Sharon; Weiss, Roger; Sherritt, Lon; Ziemnik, Rosemary; Spalding, Allegra; Van Hook, Shari; Shrier, Lydia A

    2014-09-01

    Screening adolescents for substance use and intervening immediately can reduce the burden of addiction and substance-related morbidity. Several screening tools have been developed to identify problem substance use for adolescents, but none have been calibrated to triage adolescents into clinically relevant risk categories to guide interventions. To describe the psychometric properties of an electronic screen and brief assessment tool that triages adolescents into 4 actionable categories regarding their experience with nontobacco substance use. Adolescent patients (age range, 12-17 years) arriving for routine medical care at 2 outpatient primary care centers and 1 outpatient center for substance use treatment at a pediatric hospital completed an electronic screening tool from June 1, 2012, through March 31, 2013, that consisted of a question on the frequency of using 8 types of drugs in the past year (Screening to Brief Intervention). Additional questions assessed severity of any past-year substance use. Patients completed a structured diagnostic interview (Composite International Diagnostic Interview-Substance Abuse Module), yielding Diagnostic and Statistical Manual of Mental Disorders (Fifth Edition) substance use diagnoses. For the entire screen and the Screening to Brief Intervention, sensitivity and specificity for identifying nontobacco substance use, substance use disorders, severe substance use disorders, and tobacco dependence were calculated using the Composite International Diagnostic Interview-Substance Abuse Module as the criterion standard. Of 340 patients invited to participate, 216 (63.5%) enrolled in the study. Sensitivity and specificity were 100% and 84% (95% CI, 76%-89%) for identifying nontobacco substance use, 90% (95% CI, 77%-96%) and 94% (95% CI, 89%-96%) for substance use disorders, 100% and 94% (95% CI, 90%-96%) for severe substance use disorders, and 75% (95% CI, 52%-89%) and 98% (95% CI, 95%-100%) for nicotine dependence. No significant

  20. The effect of biofertilizer fungi on Ciherang rice growth at some level of soil salinity

    Directory of Open Access Journals (Sweden)

    Y B Subowo

    2014-04-01

    Full Text Available A research about the effect of fungus contained biofertilizer on Ciherang rice that was growth on different level of soil salinity was conducted. One of the effect of global climate changes is the increase of sea water level. It leads to the expansion of sea water submerged land for agriculture. Salt intrution to the agriculture area considerably decrease soil fertility because of the high salinity. Some of microbes especially soil fungi such as Aspergillus sp and Penicillium sp. are able to grow at high salinity environment. Those fungi were also able to degrade lignocellulose, sollubilize in organic phosphate and provide organic phosphat and produce plant growth hormon especially IAA. Such activities benefit to improve soil fertility in high salinity land as a bio-fertilizer.The objective of this research was to know the growth of rice plant that treated with fungus contained bio-fertilizer on land with different level of salinity. The rice were planted in Green house of Cibinong Science Centre, Cibinong.The research was set up as complete random design with five replication. The rice were watered by 5 conditions: 50% of sea water, 100% of sea water, 100% sea water + 2 % NaCl , fresh water + 5 % NaCl and 100% fresh water as the control. Fertilizer was added to the medium twice. Ten grams of fertilizer were used per polybag (10g/7 Kg, 2 weeks after planting and before flowering subsequently. The observed parameters were plant height, number of tiller, leaves colour, biomass dry weight, soil organic carbon content, cellulosic and lignin degrading activities of the fungus, fungus phosphate-solubilizing potency and fungus production of IAA.The watering treatment lead to 5 level of salinity i.e. : 5,93 dS/m (50% sea water, 9,15 dS/m (100% sea water, 10,42 dS/m (sea water + 2% NaCl, 12,43 dS/m (fresh water + 5% NaCl and 0,74 dS/m (fresh water. The result showed that among those 5 watering condition, the rice grew best on 5,93 dS/m (watering 50% of

  1. Effects of vegetation and soil-surface cover treatments on the hydrologic behavior of low-level waste trench caps

    International Nuclear Information System (INIS)

    Lopez, E.A.; Barnes, F.J.; Antonio, E.J.

    1988-01-01

    Preliminary results are presented on a three-year field study at Los Alamos National Laboratory to evaluate the influence of different low-level radioactive waste trench cap designs on water balance under natural precipitation. Erosion plots having two different vegetative covers (shrubs and grasses) and with either gravel-mulched or unmulched soil surface treatments have been established on three different soil profiles on a decommissioned waste site. Total runoff and soil loss from each plot is measured after each precipitation event. Soil moisture is measured biweekly while plant canopy cover is measured seasonally. Preliminary results from the first year show that the application of a gravel mulch reduced runoff by 73 to 90%. Total soil loss was reduced by 83 to 93% by the mulch treatment. On unmulched plots, grass cover reduced both runoff and soil loss by about 50% compared to the shrub plots. Continued monitoring of the study site will provide data that will be used to analyze complex interactions between independent variables such rainfall amount and intensity, antecedent soil moisture, and soil and vegetation factors, as they influence water balance, and soil erosion. 18 refs., 2 figs., 3 tabs

  2. Waste management of actinide contaminated soil

    International Nuclear Information System (INIS)

    Navratil, J.D.; Thompson, G.H.; Kochen, R.L.

    1978-01-01

    Waste management processes have been developed to reduce the volume of Rocky Flats soil contaminated with plutonium and americium and to prepare the contaminated fraction for terminal storage. The primary process consists of wet-screening. The secondary process uses attrition scrubbing and wet screening with additives. The tertiary process involves volume reduction of the contaminated fraction by calcination, or fixation by conversion to glass. The results of laboratory scale testing of the processes are described

  3. Heavy Metal Concentration and Risk Assessment of Soil and Rice in and around an Open Dumpsite in Thailand

    Directory of Open Access Journals (Sweden)

    Tanjira Klinsawathom

    2017-07-01

    Full Text Available This study aimed to determine the heavy metal concentration in the soil and rice in and around Nakhonluang district open dumpsite in Phra Nakhon Si Ayutthaya province of Thailand and to assess the human health risk of these metals. The soil samples demonstrated heavy metal concentrations in the following order: Fe > Mn >Zn > Cu > Cr > Ni > Pb (Cd was not detected, and the average concentrations of each metal in soil from the dumpsite area were higher than those in the surrounding area. The average concentrations of Mn in the soils exceeded the screening level for higher plant protection of the USEPA’s Eco-SSL while the average Zn and Cu concentrations in the soil samples from the dumpsite exceeded the level for good soil and safety to life recommended by LDD. The rice exhibited metal concentrations in the following order: root > straw > grain. A carcinogenic human health risk assessment (RTotal indicated that the values from the soil samples and the rice were at safe levels. The sum of noncarcinogenic hazard values (Cr, Cu, Mn, Ni, Pb, and Zn indicated that exposure to the soils around the dumpsite area may pose adverse health effects (HI < 1 while exposure to the soils in the dumpsite area carries a high risk of causing adverse health effects both in children (HI = 10.5 and adults (HI = 2.18. It is suggested that suitable management measures should be applied to prevent or reduce heavy metal contamination in and around the dumpsite area.

  4. Soil Survey Geographic (SSURGO) - Kinds and Distribution of Soils

    Data.gov (United States)

    California Natural Resource Agency — This data set is a digital soil survey and generally is the most detailed level of soil geographic data developed by the National Cooperative Soil Survey. The...

  5. Uranium in soil and gamma dose rate as proxies for the indoor radon risk: situation in Belgium

    International Nuclear Information System (INIS)

    Tondeur, F.; Cinelli, G.; Dehandschutter, B.

    2017-01-01

    Radon risk maps are usually based either on indoor radon data, or on measurements of soil gas radon and soil permeability. If these data are not available or not sufficient, it was suggested that other data could be used as an approximate substitute (a proxy) to the missing information, like the concentration of 238 U or 226 Ra in soils or the terrestrial gamma dose rate (TGDR). We examine here the correlation between airborne measurements of soil U and indoor radon, and between airborne U and TGDR, and their link with affected/unaffected areas. No clear correlation is found between airborne U and affected areas, as strongly affected areas are not characterised by a higher U level. Only the moderately affected area of Condroz can be connected to a higher U level, related to a few U anomalies. TGDR shows a rather good correlation with airborne U, but its relation with radon risk is less clear. Soil uranium and TGDR may help to screen out areas with very low U and very low TGDR, which have a low indoor radon risk, but they cannot be considered as good proxies for predicting radon-affected areas in Belgium. (authors)

  6. Toxicological benchmarks for screening potential contaminants of concern for effects on terrestrial plants. Environmental Restoration Program

    Energy Technology Data Exchange (ETDEWEB)

    Suter, G.W. II; Will, M.E.; Evans, C.

    1993-09-01

    One of the initial stages in ecological risk assessment for hazardous waste sites is the screening of contaminants to determine which of them are worthy of further consideration as ``contaminants of potential concern.`` This process is termed ``contaminant screening.`` It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to plants. This report presents a standard method for deriving benchmarks for this purpose (phytotoxicity benchmarks), a set of data concerning effects of chemicals in soil or soil solution on plants, and a set of phytotoxicity benchmarks for 34 chemicals potentially associated with US Department of Energy (DOE) sites. Chemicals that are found in soil at concentrations exceeding both the phytotoxicity benchmark and the background concentration for the soil type should be considered contaminants of potential concern. The purpose of this report is to present plant toxicity data and discuss their utility as benchmarks for determining the hazard to terrestrial plants caused by contaminants in soil. Benchmarks are provided for soils and solutions.

  7. Quantifying the heterogeneity of soil compaction, physical soil properties and soil moisture across multiple spatial scales

    Science.gov (United States)

    Coates, Victoria; Pattison, Ian; Sander, Graham

    2016-04-01

    England's rural landscape is dominated by pastoral agriculture, with 40% of land cover classified as either improved or semi-natural grassland according to the Land Cover Map 2007. Since the Second World War the intensification of agriculture has resulted in greater levels of soil compaction, associated with higher stocking densities in fields. Locally compaction has led to loss of soil storage and an increased in levels of ponding in fields. At the catchment scale soil compaction has been hypothesised to contribute to increased flood risk. Previous research (Pattison, 2011) on a 40km2 catchment (Dacre Beck, Lake District, UK) has shown that when soil characteristics are homogeneously parameterised in a hydrological model, downstream peak discharges can be 65% higher for a heavy compacted soil than for a lightly compacted soil. However, at the catchment scale there is likely to be a significant amount of variability in compaction levels within and between fields, due to multiple controlling factors. This research focusses in on one specific type of land use (permanent pasture with cattle grazing) and areas of activity within the field (feeding area, field gate, tree shelter, open field area). The aim was to determine if the soil characteristics and soil compaction levels are homogeneous in the four areas of the field. Also, to determine if these levels stayed the same over the course of the year, or if there were differences at the end of the dry (October) and wet (April) periods. Field experiments were conducted in the River Skell catchment, in Yorkshire, UK, which has an area of 120km2. The dynamic cone penetrometer was used to determine the structural properties of the soil, soil samples were collected to assess the bulk density, organic matter content and permeability in the laboratory and the Hydrosense II was used to determine the soil moisture content in the topsoil. Penetration results show that the tree shelter is the most compacted and the open field area

  8. Baseline concentrations of radionuclides and heavy metals in soils and vegetation around the DARHT facility: Construction phase (1997). Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Fresquez, P.R.; Haagenstad, H.T.; Naranjo, L. Jr.

    1998-06-01

    As part of the Department of Energy`s Mitigation Action Plan for the Dual Axis Radiographic Hydrodynamic Test (DARHT) facility at Los Alamos National Laboratory (LANL), baseline concentrations of radionuclides ({sup 3}H, {sup 137}Cs, {sup 90}Sr, {sup 238}Pu, {sup 239,240}Pu, {sup 241}Am, and {sup tot}U) and heavy metals (Ag, As, Ba, Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Se, and Tl) in soil, sediment, and vegetation (overstory and understory) around the DARHT facility during the construction phase in 1997 were determined. Most radionuclides and heavy metals in soils, sediments, and vegetation, with the exception of {sup 90}Sr in soils and sediments, were within upper (95%) limit background concentrations. Although the levels of {sup 90}Sr in soils and sediments around the DARHT facility were higher than background, they were below LANL screening action levels (<4.4 pCi g{sup {minus}1} dry) and are of no concern.

  9. Uptake and utilization of soil and fertilizer phosphorus by wheat in medium black soils

    International Nuclear Information System (INIS)

    Mahajan, J.P.

    1980-01-01

    A field experiment was conducted using labelled superphosphate to study the uptake and utilization of soil and fertilizer phosphorus by wheat under different soil fertility gradients and phosphorus levels. Grain, straw and total dry matter yield and total P uptake in wheat increased significantly with increasing soil fertility status and P levels (P 0 to P 90 kg P 2 O 5 /ha). Percent P derived from fertilizer increased significantly with increase in P levels but decreased with increasing fertility status of soil. Similar trend was observed in fertilizer P uptake in grain, straw and total dry matter, however, percent utilization of applied P decreased significantly with increasing P levels and fertility status of soil. Soil P uptake increased with increasing fertility status of soil. (author)

  10. Watershed soil Cd loss after long-term agricultural practice and biochar amendment under four rainfall levels.

    Science.gov (United States)

    Ouyang, Wei; Huang, Weijia; Hao, Xin; Tysklind, Mats; Haglund, Peter; Hao, Fanghua

    2017-10-01

    Some heavy metals in farmland soil can be transported into the waterbody, affecting the water quality and sediment at the watershed outlet, which can be used to determine the historical loss pattern. Cd is a typical heavy metal leached from farmland that is related to phosphate fertilizers and carries serious environmental risk. The spatial-vertical pattern of Cd in soil and the vertical trend of Cd in the river sediment core were analyzed, which showed the migration and accumulation of Cd in the watershed. To prevent watershed Cd loss, biochar was employed, and leaching experiments were conducted to investigate the Cd loss from soil depending on the initial concentration. Four rainfall intensities, 1.25 mm/h, 2.50 mm/h, 5.00 mm/h, and 10.00 mm/h, were used to simulate typical rainfall scenarios for the study area. Biochar was prepared from corn straw after pretreatment with ammonium dihydrogen phosphate (ADP) and pyrolysis at 400 °C under anoxic conditions. To identify the effects of biochar amendment on Cd migration, the biochar was mixed with soil for 90 days at concentrations of 0%, 0.5%, 1.0%, 3.0%, and 5.0% soil by weight. The results showed that the Cd leaching load increased as the initial load and rainfall intensity increased and that eluviation caused surface Cd to diffuse to the deep soils. The biochar application caused more of the heavy metals to be immobilized in the amended soil rather than transported into the waterbody. The sorption efficiency of the biochar for Cd increased as the addition level increased to 3%, which showed better performance than the 5% addition level under some initial concentration and rainfall conditions. The research indicated that biochar is a potential material to prevent diffuse heavy metal pollution and that a lower addition makes the application more feasible. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. High-throughput screening for compounds that modulate the cellular c-di-GMP level in bacteria

    DEFF Research Database (Denmark)

    Groizeleau, Julie; Andersen, Jens Bo; Givskov, Michael

    2017-01-01

    . The secondary messenger c-di-GMP is a positive regulator of biofilm formation in many clinically relevant bacteria, and it is assumed that drugs that lower the intracellular level of c-di-GMP will force biofilm bacteria into a more treatable planktonic lifestyle. We describe a protocol for high......-throughput screening of chemical libraries for compounds that lower the c-di-GMP level in bacteria, and potentially can serve as lead compounds in the development of novel biofilm dismantling drugs....

  12. Soil Moisture Active Passive (SMAP) Mission Level 4 Carbon (L4_C) Product Specification Document

    Science.gov (United States)

    Glassy, Joe; Kimball, John S.; Jones, Lucas; Reichle, Rolf H.; Ardizzone, Joseph V.; Kim, Gi-Kong; Lucchesi, Robert A.; Smith, Edmond B.; Weiss, Barry H.

    2015-01-01

    This is the Product Specification Document (PSD) for Level 4 Surface and Root Zone Soil Moisture (L4_SM) data for the Science Data System (SDS) of the Soil Moisture Active Passive (SMAP) project. The L4_SM data product provides estimates of land surface conditions based on the assimilation of SMAP observations into a customized version of the NASA Goddard Earth Observing System, Version 5 (GEOS-5) land data assimilation system (LDAS). This document applies to any standard L4_SM data product generated by the SMAP Project.

  13. Microbiological evaluation on toxicity amelioration of soil samples contaminated with petroleum-based products

    International Nuclear Information System (INIS)

    Khairuddin Abdul Rahim; Pauline Liew Woan Ying; Ahmad Nazrul Abd Wahid; Shamsiah Abdul Rahman; Mohd Suhaimi Hamzah; Abdul Khalik Wood; Muhamat Omar

    2004-01-01

    Samples of soil materials from oil sludge landfarm in Melaka and petroleum sludge ready for disposal were analysed on their potentially toxic elements and compounds and their microbial population. These were compared against uncontaminated soil samples from agricultural plots and fresh crude petroleum samples obtained from an oil refinery in Kerteh, Terengganu. Enumeration and isolation of culturable microbial populations in the above samples were conducted using standard plate counts and screening methods. Populations of microorganisms from uncontaminated soils were tested on its potential to degrade petroleum derived products on contaminated soil samples and crude petroleum samples in a laboratory experiment. Microorganisms with great potential to degrade petroleum sludge will be further screened in further bioremediation studies in the field. (Author)

  14. Soil gas radon response to environmental and soil physics variables

    International Nuclear Information System (INIS)

    Thomas, D.M.; Chen, C.; Holford, D.

    1991-01-01

    During the last three years a field study of soil gas radon activities conducted at Poamoho, Oahu, has shown that the primary environmental variables that control radon transport in shallow tropical soils are synoptic and diurnal barometric pressure changes and soil moisture levels. Barometric pressure changes drive advective transport and mixing of soil gas with atmospheric air; soil moisture appears to control soil porosity and permeability to enhance or inhibit advective and diffusive radon transport. An advective barrier test/control experiment has shown that advective exchange of soil gas and air may account for a substantial proportion of the radon loss from shallow soils but does not significantly affect radon activities at depths greater than 2.3 m. An irrigation test/control experiment also suggests that, at soil moisture levels approaching field capacity, saturation of soil macroporosity can halt all advective transport of radon and limit diffusive mobility to that occurring in the liquid phase. The results of the authors field study have been used to further refine and extend a numerical model, RN3D, that has been developed by Pacific Northwest Laboratories to simulate subsurface transport of radon. The field data have allowed them to accurately simulate the steady state soil gas radon profile at their field site and to track transient radon activities under the influence of barometric pressure changes and in response to changes in soil permeability that result from variations in soil moisture levels. Further work is continuing on the model to enable it to properly account for the relative effects of advective transport of soil gas through cracks and diffusive mobility in the bulk soils

  15. Glyphosate sorption and desorption in soils with distinct phosphorus levels

    Energy Technology Data Exchange (ETDEWEB)

    Prata, Fabio [BIOAGRI Labs., Piracicaba, SP (Brazil). Div. de Quimica. Lab. de Radioquimica; Cardinali, Vanessa Camponez do Brasil; Tornisielo, Valdemar Luiz; Regitano, Jussara Borges [Sao Paulo Univ., Piracicaba, SP (Brazil). Escola Superior de Agricultura Luiz de Queiroz. Dept. de Ciencias Exatas; Lavorenti, Arquimedes [Centro de Energia Nuclear na Agricultura (CENA), Piracicaba, SP (Brazil). Secao de Toxicologia

    2003-03-01

    The sorption of glyphosate by soils occurs due to the inner sphere complex formation with metals of soil oxides, which are related to the soil phosphate adsorption capacity. The aim of this study was to evaluate the effects of increasing rates of phosphorus on sorption and desorption of glyphosate in three soils with different mineralogical attributes. Soils were a Rhodic Kandiudalf, an Anionic Acrudox and a Typic Humaquept. Soil samples were amended with Kh{sub 2}PO{sub 4} at equivalent rates of 0; 1,000; 5,000; 20,000 and 50,000 kg ha{sup -1} of P{sub 2}O{sub 5}, which are high from the agricultural point of view, but necessary in order to perform sorption and desorption studies. The experimental design consisted of a completely randomized factorial: 2 soils x 5 phosphorus rates and 3 replicates. For the sorption experiments, five glyphosate solutions were employed (0.42; 0.84; 1.68; 3.36 and 6.72 mg L{sup -1}), with a {sup 14}C radioactivity of 0.233 kBq mL{sup -1}. Four steps of the desorption procedures withCaCl{sub 2} 0.01 mol L{sup -1} and one extraction with Mehlich 3 were performed only at one concentration (0.84 mol L{sup -1}). Soil samples were afterwards biologically oxidized to establish the radioactive balance. Glyphosate competes with phosphorus for specific sorption sites, but this competition becomes important when phosphorus is present at rates higher than 1,000 mg dm{sup -3}. Moreover, a small amount of applied glyphosate was extracted (<10%), and the extraction increased with increasing soil phosphorus content. (author)

  16. Toxicological benchmarks for screening potential contaminants of concern for effects on terrestrial plants: 1994 revision

    International Nuclear Information System (INIS)

    Will, M.E.; Suter, G.W. II.

    1994-09-01

    One of the initial stages in ecological risk assessment for hazardous waste sites is screening contaminants to determine which of them are worthy of further consideration as contaminants of potential concern. This process is termed contaminant screening. It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to plants. This report presents a standard method for deriving benchmarks for this purpose (phytotoxicity benchmarks), a set of data concerning effects of chemicals in soil or soil solution on plants, and a set of phytotoxicity benchmarks for 38 chemicals potentially associated with United States Department of Energy (DOE) sites. In addition, background information on the phytotoxicity and occurrence of the chemicals in soils is presented, and literature describing the experiments from which data were drawn for benchmark derivation is reviewed. Chemicals that are found in soil at concentrations exceeding both the phytotoxicity benchmark and the background concentration for the soil type should be considered contaminants of potential concern

  17. Toxicological benchmarks for screening potential contaminants of concern for effects on terrestrial plants: 1994 revision

    Energy Technology Data Exchange (ETDEWEB)

    Will, M.E.; Suter, G.W. II

    1994-09-01

    One of the initial stages in ecological risk assessment for hazardous waste sites is screening contaminants to determine which of them are worthy of further consideration as contaminants of potential concern. This process is termed contaminant screening. It is performed by comparing measured ambient concentrations of chemicals to benchmark concentrations. Currently, no standard benchmark concentrations exist for assessing contaminants in soil with respect to their toxicity to plants. This report presents a standard method for deriving benchmarks for this purpose (phytotoxicity benchmarks), a set of data concerning effects of chemicals in soil or soil solution on plants, and a set of phytotoxicity benchmarks for 38 chemicals potentially associated with United States Department of Energy (DOE) sites. In addition, background information on the phytotoxicity and occurrence of the chemicals in soils is presented, and literature describing the experiments from which data were drawn for benchmark derivation is reviewed. Chemicals that are found in soil at concentrations exceeding both the phytotoxicity benchmark and the background concentration for the soil type should be considered contaminants of potential concern.

  18. A comparison of mean glandular dose diagnostic reference levels within the all-digital irish national breast screening programme and the Irish symptomatic breast services

    International Nuclear Information System (INIS)

    O'Leary, D.; Rainford, L.

    2013-01-01

    Data on image quality, compression and radiation dose were collected from symptomatic breast units within the Republic of Ireland. Quantitative and qualitative data were analysed using SPSS. Recommendations of mean glandular dose (MGD) diagnostic reference levels were made at various levels for film-screen and full field digital mammography units to match levels published worldwide. MGDs received by symptomatic breast patients within Ireland are higher than those received in the all-digital Irish Breast Screening service; 55-65 mm breast: 1.75 mGy (screening) vs. 2.4 mGy (symptomatic) at the 95. percentile; various reasons are proposed for the differences. MGDs achieved in the screening service may be lower because of the exacting requirements for radiographer training, characteristics of the patients and equipment quality assurance levels. More precise imaging guidelines, standards and training of symptomatic radiographers performing mammography are suggested to remediate MGDs delivered to the breasts of Irish women attending the symptomatic breast services. (authors)

  19. THE BNL ASTD FIELD LAB - NEAR - REAL - TIME CHARACTERIZATION OF BNL STOCKPILED SOILS TO ACCELERATE COMPLETION OF THE EM CHEMICAL HOLES PROJECT

    International Nuclear Information System (INIS)

    BOWERMAN, B.S.; ADAMS, J.W.; HEISER, J.; KALB, P.D.; LOCKWOOD, A.

    2003-01-01

    As of October 2001, approximately 7,000 yd 3 of stockpiled soil remained at Brookhaven National Laboratory (BNL) after the remediation of the BNL Chemical/Animal/Glass Pits disposal area. The soils were originally contaminated with radioactive materials and heavy metals, depending on what materials had been interred in the pits, and how the pits were excavated. During the 1997 removal action, the more hazardous/radioactive materials were segregated, along with, chemical liquids and solids, animal carcasses, intact gas cylinders, and a large quantity of metal and glass debris. Nearly all of these materials have been disposed of. In order to ensure that all debris was removed and to characterize the large quantity of heterogeneous soil, BNL initiated an extended sorting, segregation, and characterization project directed at the remaining soil stockpiles. The project was co-funded by the Department of Energy Environmental Management Office (DOE EM) through the BNL Environmental Restoration program and through the DOE EM Office of Science and Technology Accelerated Site Technology Deployment (ASTD) program. The focus was to remove any non-conforming items, and to assure that mercury and radioactive contaminant levels were within acceptable limits for disposal as low-level radioactive waste. Soils with mercury concentrations above allowable levels would be separated for disposal as mixed waste. Sorting and segregation were conducted simultaneously. Large stockpiles (ranging from 150 to 1,200 yd 3 ) were subdivided into manageable 20 yd 3 units after powered vibratory screening. The 1/2-inch screen removed almost all non-conforming items (plus some gravel). Non-conforming items were separated for further characterization. Soil that passed through the screen was also visually inspected before being moved to a 20 yd 3 ''subpile.'' Eight samples from each subpile were collected after establishing a grid of four quadrants: north, east, south and west, and two layers: top and

  20. Heavy metal levels in soil samples from highly industrialized Lagos ...

    African Journals Online (AJOL)

    Anyakora

    2013-09-05

    Sep 5, 2013 ... The effect of heavy metals on the environment is of serious concern and threatens life in all forms. Environmental ... have affected the quality of soil due to contamination of soil with heavy metals and the consequent effects on the ..... tested for remediation of chromium-contaminated soils. (Collen, 2003).

  1. Screening for Cd-Safe Cultivars of Chinese Cabbage and a Preliminary Study on the Mechanisms of Cd Accumulation

    Directory of Open Access Journals (Sweden)

    Jingjie Wang

    2017-04-01

    Full Text Available With the rapid progress of industrialization, the effects of environmental contamination on plant toxicity, and subsequently on human health, is a growing concern. For example, the heavy metal pollution of soil such as that caused by cadmium (Cd is a serious threat. Therefore, screening for pollution-safe edible plants is an essential approach for growing plants under heavy metal-contaminated soils. In the current study, 35 Chinese cabbage (Brassica pekinensis L. cultivars were selected with the aim of screening for Cd-safe cultivars (CSCs, analyzing their safety, and exploring the mechanism of Cd accumulation. Our field-culture experiments revealed that the Cd content in the edible parts of the cultivars were varied and were determined to possibly be CSCs. Hydroponics experiments were used to simulate six different degrees of soil contamination (high and low Cd concentrations on possible CSCs. The results indicated a significant difference (p < 0.05 in Cd concentration in the cultivars, and verified the safety of these possible CSCs. The analyses of the transport coefficient and expression levels showed that the differences in Cd accumulation among the Chinese cabbage cultivars were related to the expression of genes involved in absorption and transport rather than a root-to-shoot translocation limitation.

  2. Elevated CO2 levels affects the concentrations of copper and cadmium in crops grown in soil contaminated with heavy metals under fully open-air field conditions.

    Science.gov (United States)

    Guo, Hongyan; Zhu, Jianguo; Zhou, Hui; Sun, Yuanyuan; Yin, Ying; Pei, Daping; Ji, Rong; Wu, Jichun; Wang, Xiaorong

    2011-08-15

    Elevated CO(2) levels and the increase in heavy metals in soils through pollution are serious problems worldwide. Whether elevated CO(2) levels will affect plants grown in heavy-metal-polluted soil and thereby influence food quality and safety is not clear. Using a free-air CO(2) enrichment (FACE) system, we investigated the impacts of elevated atmospheric CO(2) on the concentrations of copper (Cu) or cadmium (Cd) in rice and wheat grown in soil with different concentrations of the metals in the soil. In the two-year study, elevated CO(2) levels led to lower Cu concentrations and higher Cd concentrations in shoots and grain of both rice and wheat grown in the respective contaminated soil. Elevated CO(2) levels slightly but significantly lowered the pH of the soil and led to changes in Cu and Cd fractionation in the soil. Our study indicates that elevated CO(2) alters the distribution of contaminant elements in soil and plants, thereby probably affecting food quality and safety.

  3. Bulk monitoring of soil for low level transuranic contamination

    International Nuclear Information System (INIS)

    Mandler, J.W.; Randolph, P.D.

    1976-01-01

    A system using γ-ray analysis was developed to survey the soil surrounding retrieval barrels for liquid radioactive waste containing 239 Pu and 241 Am. The performance of scintillation detectors of various sizes for monitoring soil samples was evaluated

  4. Organic amendments for risk mitigation of organochlorine pesticide residues in old orchard soils

    Science.gov (United States)

    Centofantia, Tiziana; McConnell, Laura L.; Chaney, Rufus L.; Beyer, W. Nelson; Andradea, Natasha A.; Hapeman, Cathleen J.; Torrents, Alba; Nguyen, Anh; Anderson, Marya O.; Novak, J. M.; Jackson, Dana

    2015-01-01

    Performance of compost and biochar amendments for in situ risk mitigation of aged DDT, DDE and dieldrin residues in an old orchard soil was examined. The change in bioavailability of pesticide residues to Lumbricus terrestris L. relative to the unamended control soil was assessed using 4-L soil microcosms with and without plant cover in a 48-day experiment. The use of aged dairy manure compost and biosolids compost was found to be effective, especially in the planted treatments, at lowering the bioavailability factor (BAF) by 18–39%; however, BAF results for DDT in the unplanted soil treatments were unaffected or increased. The pine chip biochar utilized in this experiment was ineffective at lower the BAF of pesticides in the soil. The US EPA Soil Screening Level approach was used with our measured values. Addition of 10% of the aged dairy manure compost reduced the average hazard quotient values to below 1.0 for DDT + DDE and dieldrin. Results indicate this sustainable approach is appropriate to minimize risks to wildlife in areas of marginal organochlorine pesticide contamination. Application of this remediation approach has potential for use internationally in areas where historical pesticide contamination of soils remains a threat to wildlife populations.

  5. Comparison of Capability of Digitizing Methods to Predict Soil classification According to the Soil Taxonomy and World Reference Base for Soil Resources

    Directory of Open Access Journals (Sweden)

    zohreh mosleh

    2017-02-01

    Full Text Available Introduction: Soil classification generally aims to establish a taxonomy based on breaking the soil continuum into homogeneous groups that can highlight the essential differences in soil properties and functions between classes.The two most widely used modern soil classification schemes are Soil Taxonomy (ST and World Reference Base for Soil Resources (WRB.With the development of computers and technology, digital and quantitative approaches have been developed. These new techniques that include the spatial prediction of soil properties or classes, relies on finding the relationships between soil and the auxiliary information that explain the soil forming factors or processes and finally predict soil patterns on the landscape. These approaches are commonly referred to as digital soil mapping (DSM (14. A key component of any DSM mapping activity is the method used to define the relationship between soil observation and auxiliary information (4. Several types of machine learning approaches have been applied for digital soil mapping of soil classes, such as logistic and multinomial logistic regressions (10,12, random forests (15, neural networks (3,13 and classification trees (22,4. Many decisions about the soil use and management are based on the soil differences that cannot be captured by higher taxonomic levels (i.e., order, suborder and great group (4. In low relief areas such as plains, it is expected that the soil forming factors are more homogenous and auxiliary information explaining soil forming factors may have low variation and cannot show the soil variability. Materials and Methods: The study area is located in the Shahrekord plain of Chaharmahal-Va-Bakhtiari province. According tothe semi-detailed soil survey (16, 120 pedons with approximate distance of 750 m were excavated and described according to the “field book for describing and sampling soils” (19. Soil samples were taken from different genetic horizons, air dried and

  6. Nitrogen balance and dynamics in corn under different soil fertility levels using “1“5N isotope tracer technique

    International Nuclear Information System (INIS)

    Rallos, R.V.; Rivera, F.G.; Samar, E.D.; Rojales, J.S.; Anida, A.H.

    2015-01-01

    Nitrogen (N) Fertilizer plays a vital role on the growth and development of any crop. The inefficient N fertilizer utilization contributes to poor crop productivity and environment pollution. This study used the 15N isotope tracer technique to understand the nitrogen balance and dynamics in corn grown during the wet and dry season for low, medium and high N soils in Northern Luzon. The experiments were laid out following the randomized complete block design (RCBD) potassium requirements were applied at optimum level on solid chemical analysis and fertilizer recommendation. The study was able to separate the source of N from applied fertilizer and from the soils, traced using 15N during the 30 days after planting (DAP), 60 DAP and at harvest. Result show that, more than half of N in the plant came directly from added fertilizer during the early stage, which decreased towards harvest period. Fertilizer N yield use efficiency showed negative relationship with the rate of N application and soil fertility levels. Of N fertilization in different soil fertility levels were also established using isotope tracer technique. (author)

  7. Correlation between gamma radiation levels and soil radium concentrations at the Edgemont uranium mill site

    International Nuclear Information System (INIS)

    Wallace, R.G.; Reed, R.P.; Polehn, J.L.; Wilson, G.T.

    1985-01-01

    The Tennessee Valley Authority's uranium mill in Edgemont, South Dakota, is being decommissioned. Approximately 4 million tons of contaminated tailings, building equipment, and contaminated soil and debris on the mill site will be removed to the disposal site located approximately 3 kilometers to the southeast. To minimize recontamination of cleaned areas, tailings removal will progress from the northwest corner to the southeast corner of the mill site. As specific areas are cleaned, surveys will be conducted to determine if the concentrations of radium-226 in soil are within the limits outlined in 40 CFR, Part 192. Conformance with the criteria will be demonstrated by a gamma survey of the area employing the differential, or delta-measurement, technique. This technique involves fitting the detector with a base and a receptacle for a removable high-density filter. By making measurements with and without the filter in place, a gamma radiation level proportional to the radium-226 concentration in soil can be determined. This paper describes the results obtained in the development of the correlation between the gamma survey measurements and the soil radium concentrations

  8. Correlation between gamma radiation levels and soil radium concentrations at the Edgemont uranium mill site

    International Nuclear Information System (INIS)

    Wallace, R.G.; Reed, R.P.; Polehn, J.L.; Wilson, G.T.

    1986-01-01

    The Tennessee Valley Authority's uranium mill in Edgemont, South Dakota is being decommissioned. Approximately 4 million tons of contaminated tailings, building equipment, and contaminated soil and debris on the mill site will be removed to the disposal site located approximately 3 kilometers to the southeast. To minimize recontamination of cleaned areas, tailings removal will progress from the northwest corner to the southeast corner of the mill site. As specific areas are cleaned, surveys will be conducted to determine if the concentrations of radium-226 in soil are within the limits outlined in 40 CFR, Part 192. Conformance with the criteria will be demonstrated by a gamma survey of the area employing the differential, or delta-measurement, technique. This technique involves fitting the detector with a base and a receptacle for a removable high-density filter. By making measurements with and without the filter in place, a gamma radiation level proportional to the radium-226 concentration in soil can be determined. This paper describes the results obtained in the development of the correlation between the gamma survey measurements and the soil radium concentrations

  9. Recommendations to the NRC for soil cover systems over uranium mill tailings and low-level radioactive wastes

    International Nuclear Information System (INIS)

    Bennett, R.D.; Kimbrell, A.F.

    1991-02-01

    The US Army Engineer Waterways Experiment Station (WES) has provided recommendations to the US Nuclear Regulatory Commission (NRC) for the selection placement, compaction, testing, and acceptance of soils proposed to be placed in cover systems over uranium mill tailings and low-level radioactive wastes. The recommendations from WES are contained in three volumes of NUREG/CR-5432. Volume 1 identifies the various soil types and engineering properties that are needed to fulfill important soil cover functions. The identified soils are then ranked according to their capability to perform the low-permeability and filter and drainage functions. Volume 2 provides recommendations for conducting pertinent laboratory and field tests to ensure acceptable soil cover performance. Volume 3 covers recommendations from WES on proper field construction methods including guidance on quality control testing and inspections. Recommendations are given for sealing penetrations (e.g., observation wells) that are required to penetrate covers for environmental monitoring of disposal facility performance. 30 refs., 6 figs., 9 tabs

  10. Assessment of soil-gas, soil, and water contamination at the former hospital landfill, Fort Gordon, Georgia, 2009-2010

    Science.gov (United States)

    Falls, Fred W.; Caldwell, Andral W.; Guimaraes, Wladmir B.; Ratliff, W. Hagan; Wellborn, John B.; Landmeyer, James E.

    2011-01-01

    were in the southern part of the study area to the west of the debris field. However, all other detections of total petroleum hydrocarbons greater than 10 micrograms and diesel greater than 0.04 micrograms, and all detections of the combined mass of benzene, toluene, ethylbenzene, and xylene were found down slope from the debris field in the central and northern parts of the study area. Five soil-gas samplers were deployed and recovered from September 16 to 22, 2010, and were analyzed for organic compounds classified as chemical agents or explosives. Chloroacetophenones (a tear gas component) were the only compounds detected above a method detection level and were detected at the same location as the highest total petroleum hydrocarbons and diesel detections in the southern part of the 14-acre study area. Composite soil samples collected at five locations were analyzed for 35 inorganic constituents. None of the inorganic constituents exceeded the regional screening levels. One surface-water sample collected in the western end of the hyporheic-zone study area had a trichlorofluoromethane concentration above the laboratory reporting level and estimated concentrations of chloroform, fluoranthene, and isophorone below laboratory reporting levels.

  11. Initializing numerical weather prediction models with satellite-derived surface soil moisture: Data assimilation experiments with ECMWF's Integrated Forecast System and the TMI soil moisture data set

    Science.gov (United States)

    Drusch, M.

    2007-02-01

    Satellite-derived surface soil moisture data sets are readily available and have been used successfully in hydrological applications. In many operational numerical weather prediction systems the initial soil moisture conditions are analyzed from the modeled background and 2 m temperature and relative humidity. This approach has proven its efficiency to improve surface latent and sensible heat fluxes and consequently the forecast on large geographical domains. However, since soil moisture is not always related to screen level variables, model errors and uncertainties in the forcing data can accumulate in root zone soil moisture. Remotely sensed surface soil moisture is directly linked to the model's uppermost soil layer and therefore is a stronger constraint for the soil moisture analysis. For this study, three data assimilation experiments with the Integrated Forecast System (IFS) of the European Centre for Medium-Range Weather Forecasts (ECMWF) have been performed for the 2-month period of June and July 2002: a control run based on the operational soil moisture analysis, an open loop run with freely evolving soil moisture, and an experimental run incorporating TMI (TRMM Microwave Imager) derived soil moisture over the southern United States. In this experimental run the satellite-derived soil moisture product is introduced through a nudging scheme using 6-hourly increments. Apart from the soil moisture analysis, the system setup reflects the operational forecast configuration including the atmospheric 4D-Var analysis. Soil moisture analyzed in the nudging experiment is the most accurate estimate when compared against in situ observations from the Oklahoma Mesonet. The corresponding forecast for 2 m temperature and relative humidity is almost as accurate as in the control experiment. Furthermore, it is shown that the soil moisture analysis influences local weather parameters including the planetary boundary layer height and cloud coverage.

  12. Validity of a New Kit Measuring Salivary Lactate Dehydrogenase Level for Screening Gingivitis.

    Science.gov (United States)

    Ekuni, Daisuke; Yamane-Takeuchi, Mayu; Kataoka, Kota; Yokoi, Aya; Taniguchi-Tabata, Ayano; Mizuno, Hirofumi; Miyai, Hisataka; Uchida, Yoko; Fukuhara, Daiki; Sugiura, Yoshio; Tomofuji, Takaaki; Morita, Manabu

    2017-01-01

    Aim . The aim of this study was to determine the usefulness of a new kit that can evaluate salivary lactate dehydrogenase (LD) level in real time for screening gingivitis. Materials and Methods . The study included 70 systemic healthy volunteers [29 males and 41 females; mean age ± SD: 24.1 ± 2.6 years]. Resting saliva was collected from each participant and LD level was evaluated in real time using the kit (a color-changing sheet with an integer scale ranging from 1 to 10). A dentist measured probing pocket depth, clinical attachment level, and the proportion of sites with bleeding on probing (% BOP) at six sites on all teeth. Gingivitis was diagnosed when the BOP value was ≥20%. Results . Salivary LD level was positively correlated with mean % BOP (odds ratio: 1.47, 95% confidence interval: 1.132-1.916, and P gingivitis in young adults, which contributes to early detection of future periodontitis.

  13. Intrinsic and induced isoproturon catabolic activity in dissimilar soils and soils under dissimilar land use.

    Science.gov (United States)

    Reid, Brian J; Papanikolaou, Niki D; Wilcox, Ronah K

    2005-02-01

    The catabolic activity with respect to the systemic herbicide isoproturon was determined in soil samples by (14)C-radiorespirometry. The first experiment assessed levels of intrinsic catabolic activity in soil samples that represented three dissimilar soil series under arable cultivation. Results showed average extents of isoproturon mineralisation (after 240 h assay time) in the three soil series to be low. A second experiment assessed the impact of addition of isoproturon (0.05 microg kg(-1)) into these soils on the levels of catabolic activity following 28 days of incubation. Increased catabolic activity was observed in all three soils. A third experiment assessed levels of intrinsic catabolic activity in soil samples representing a single soil series managed under either conventional agricultural practice (including the use of isoproturon) or organic farming practice (with no use of isoproturon). Results showed higher (and more consistent) levels of isoproturon mineralisation in the soil samples collected from conventional land use. The final experiment assessed the impact of isoproturon addition on the levels of inducible catabolic activity in these soils. The results showed no significant difference in the case of the conventional farm soil samples while the induction of catabolic activity in the organic farm soil samples was significant.

  14. Soil! Get the Scoop - The Soil Science Society of America's International Year of Soils Campaign

    Science.gov (United States)

    Lindbo, David L.; Hopmans, Jan; Olson, Carolyn; Fisk, Susan; Chapman, Susan; van Es, Harold

    2015-04-01

    Soils are a finite natural resource and are nonrenewable on a human time scale. Soils are the foundation for food, animal feed, fuel and natural fiber production, the supply of clean water, nutrient cycling and a range of ecosystem functions. The area of fertile soils covering the world's surface is limited and increasingly subject to degradation, poor management and loss to urbanization. Increased awareness of the life-supporting functions of soil is called for if this trend is to be reversed and so enable the levels of food production necessary to meet the demands of population levels predicted for 2050. The Soil Science Society of America is coordinating with the Global Soil Partnership and other organizations around the world to celebrate the 2015 International Year of Soils and raise awareness and promote the sustainability of our limited soil resources. We all have a valuable role in communicating vital information on soils, a life sustaining natural resource. Therefore, we will provide resources to learn about soils and help us tell the story of soils. We will promote IYS on social media by sharing our posts from Facebook and Twitter. Additionally SSSA developed 12 monthly themes that reflect the diverse value of soils to our natural environment and society. Each month has information on the theme, a lesson plan, and other outreach activities. All information is available on a dedicated website www.soil.org/IYS. The site will be updated constantly throughout the year.

  15. Laboratory scale vitrification of low-level radioactive nitrate salts and soils from the Idaho National Engineering Laboratory

    International Nuclear Information System (INIS)

    Shaw, P.; Anderson, B.

    1993-07-01

    INEL has radiologically contaminated nitrate salt and soil waste stored above and below ground in Pad A and the Acid Pit at the Radioactive Waste Management Complex. Pad A contain uranium and transuranic contaminated potassium and sodium nitrate salts generated from dewatered waste solutions at the Rocky Flats Plant. The Acid Pit was used to dispose of liquids containing waste mineral acids, uranium, nitrate, chlorinated solvents, and some mercury. Ex situ vitrification is a high temperature destruction of nitrates and organics and immobilizes hazardous and radioactive metals. Laboratory scale melting of actual radionuclides containing INEL Pad A nitrate salts and Acid Pit soils was performed. The salt/soil/additive ratios were varied to determine the range of glass compositions (resulted from melting different wastes); maximize mass and volume reduction, durability, and immobilization of hazardous and radioactive metals; and minimize viscosity and offgas generation for wastes prevalent at INEL and other DOE sites. Some mixtures were spiked with additional hazardous and radioactive metals. Representative glasses were leach tested and showed none. Samples spiked with transuranic showed low nuclide leaching. Wasteforms were two to three times bulk densities of the salt and soil. Thermally co-processing soils and salts is an effective remediation method for destroying nitrate salts while stabilizing the radiological and hazardous metals they contain. The measured durability of these low-level waste glasses approached those of high-level waste glasses. Lab scale vitrification of actual INEL contaminated salts and soils was performed at General Atomics Laboratory as part of the INEL Waste Technology Development and Environmental Restoration within the Buried Waste Integrated Demonstration Program

  16. Soil radioactivity levels, radiological maps and risk assessment for the state of Kuwait.

    Science.gov (United States)

    Alazemi, N; Bajoga, A D; Bradley, D A; Regan, P H; Shams, H

    2016-07-01

    An evaluation of the radioactivity levels associated with naturally occurring radioactive materials has been undertaken as part of a systematic study to provide a surface radiological map of the State of Kuwait. Soil samples from across Kuwait were collected, measured and analysed in the current work. These evaluations provided soil activity concentration levels for primordial radionuclides, specifically members of the (238)U and (232)Th decay chains and (40)K which. The (238)U and (232)Th chain radionuclides and (40)K activity concentration values ranged between 5.9 ↔ 32.3, 3.5 ↔ 27.3, and 74 ↔ 698 Bq/kg respectively. The evaluated average specific activity concentrations of (238)U, (232)Th and (40)K across all of the soil samples have mean values of 18, 15 and 385 Bq/kg respectively, all falling below the worldwide mean values of 35, 40 and 400 Bq/kg respectively. The radiological risk factors are associated with a mean of 33.16 ± 2.46 nG/h and 68.5 ± 5.09 Bq/kg for the external dose rate and Radium equivalent respectively. The measured annual dose rates for all samples gives rise to a mean value of 40.8 ± 3.0 μSv/y while the internal and internal hazard indices have been found to be 0.23 ± 0.02 and 0.19 ± 0.01 respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. Emission of Carbon Dioxide Influenced by Different Water Levels from Soil Incubated Organic Residues

    Science.gov (United States)

    Hossain, M. B.; Puteh, A. B.

    2013-01-01

    We studied the influence of different organic residues and water levels on decomposition rate and carbon sequestration in soil. Organic residues (rice straw, rice root, cow dung, and poultry litter) including control were tested under moistened and flooding systems. An experiment was laid out as a complete randomized design at 25°C for 120 days. Higher CO2-C (265.45 mg) emission was observed in moistened condition than in flooding condition from 7 to 120 days. Among the organic residues, poultry litter produced the highest CO2-C emission. Poultry litter with soil mixture increased 121% cumulative CO2-C compared to control. On average, about 38% of added poultry litter C was mineralized to CO2-C. Maximum CO2-C was found in 7 days after incubation and thereafter CO2-C emission was decreased with the increase of time. Control produced the lowest CO2-C (158.23 mg). Poultry litter produced maximum cumulative CO2-C (349.91 mg). Maximum organic carbon was obtained in cow dung which followed by other organic residues. Organic residues along with flooding condition decreased cumulative CO2-C, k value and increased organic C in soil. Maximum k value was found in poultry litter and control. Incorpored rice straw increased organic carbon and decreased k value (0.003 g d−1) in soil. In conclusion, rice straw and poultry litter were suitable for improving soil carbon. PMID:24163626

  18. Validation of site-specific soil Ni toxicity thresholds with independent ecotoxicity and biogeochemistry data for elevated soil Ni

    International Nuclear Information System (INIS)

    Hale, Beverley; Gopalapillai, Yamini; Pellegrino, Amanda; Jennett, Tyson; Kikkert, Julie; Lau, Wilson; Schlekat, Christian; McLaughlin, Mike J.

    2017-01-01

    The Existing Substances Regulation Risk Assessments by the European Union (EU RA) generated new toxicity data for soil organisms exposed to Ni added to sixteen field-collected soils with low background concentration of metals and varying physico-chemical soil characteristics. Using only effective cation exchange capacity (eCEC) as a bioavailability correction, chronic toxicity of Ni in soils with a wide range of characteristics could be predicted within a factor of two. The objective of the present study was to determine whether this was also the case for three independent data sets of Ni toxicity thresholds. Two of the data sets were from Community Based Risk Assessments in Port Colborne ON, and Sudbury ON (Canada) for soils containing elevated concentrations of Ni, Co and Cu arising from many decades of Ni mining, smelting and refining. The third data set was the Metals in Asia study of soluble Ni added to field soils in China. These data yielded 72 leached and aged EC 10 /NOEC values for soil Ni, for arthropods, higher plants and woodlot structure and function. These were reduced to nine most sensitive single or geometric mean species/function endpoints, none of which were lower than the HC 5 predicted for a soil with an eCEC of 20 cmol/kg. Most of these leached and aged EC 10 /NOEC values were from soils co-contaminated with Cu, in some cases at its median HC 5 as predicted by the EU RA from soil characteristics. We conclude that the EU RA is protective of Ni toxicity to higher-tier ecological endpoints, including in mixture with Cu, before the assessment factor of 2 is applied. We suggest that for prospective risk assessment, the bioavailability based PNEC (HC 5 /2) be used as a conservative screen, but for retrospective and site-specific risk assessment, the bioavailability based HC 5 is sufficient. - Highlights: • Higher-tier ecotoxicity thresholds calculated for field soils with elevated Ni. • Adjusted for Ni bioavailability using soil eCEC and species

  19. Low level measurements of natural radionuclides in soil samples around a coal-fired power plant

    International Nuclear Information System (INIS)

    Rosner, G.; Bunzl, K.; Hoetzl, H.; Winkler, R.

    1984-01-01

    To detect a possible contribution of airborne radioactivity from stack effluents to the soil radioactivity, several radionuclides in the soil around a coal-fired power plant have been determined. A plant situated in a rural region of Bavaria was selected to minimize contributions from other civilisatory sources. The soil sampling network consisted of 5 concentric circles with diameters between 0.4 and 5.2 km around the plant, 16 sampling points being distributed regularly on each circle. Radiochemical analysis techniques for 210 Pb and 210 Po in soil samples of several grams has to be developed. They include a wet dissolution procedure, simultaneous precipitation of lead and polonium as the sulfides, purification via lead sulfate, counting of the lead as the chromate in a low-level beta counter and alpha spectrometric determination of the 210 Po in a gridded ionization chamber. The 238 U, 226 Ra, 232 Th and 40 K were counted by low level gamma spectrometry. Specific activities found were in the range of 0.7 to 2.0 pCi g -1 for 210 Pb and 0.3 to 1.6 pCi g -1 for 226 Ra. The distribution patterns of 210 Po and 210 Pb around the plant were found to be similar. They were different, however, from that of 226 Ra. The highest 210 Pb/ 226 Ra activity ratio was 3.9 at a distance of 0.76 km SSE from the plant. Nevertheless, the evidence is not considered to be sufficient to attribute these observations unambiguously to plant release. (orig.)

  20. Variation and distribution of metals and metalloids in soil/ash mixtures from Agbogbloshie e-waste recycling site in Accra, Ghana

    Energy Technology Data Exchange (ETDEWEB)

    Itai, Takaaki, E-mail: itai@sci.ehime-u.ac.jp [Center for Marine Environmental Studies, Ehime University, Bunkyo-cho 2-5, Matsuyama, Ehime 790-8577 (Japan); Otsuka, Masanari [Center for Marine Environmental Studies, Ehime University, Bunkyo-cho 2-5, Matsuyama, Ehime 790-8577 (Japan); Asante, Kwadwo Ansong [Center for Marine Environmental Studies, Ehime University, Bunkyo-cho 2-5, Matsuyama, Ehime 790-8577 (Japan); CSIR Water Research Institute, P. O. Box AH 38, Achimota, Accra (Ghana); Muto, Mamoru [Center for Marine Environmental Studies, Ehime University, Bunkyo-cho 2-5, Matsuyama, Ehime 790-8577 (Japan); Opoku-Ankomah, Yaw; Ansa-Asare, Osmund Duodu [CSIR Water Research Institute, P. O. Box AH 38, Achimota, Accra (Ghana); Tanabe, Shinsuke [Center for Marine Environmental Studies, Ehime University, Bunkyo-cho 2-5, Matsuyama, Ehime 790-8577 (Japan)

    2014-02-01

    Illegal import and improper recycling of electronic waste (e-waste) are an environmental issue in developing countries around the world. African countries are no exception to this problem and the Agbogbloshie market in Accra, Ghana is a well-known e-waste recycling site. We have studied the levels of metal(loid)s in the mixtures of residual ash, formed by the burning of e-waste, and the cover soil, obtained using a portable X-ray fluorescence spectrometer (P-XRF) coupled with determination of the 1 M HCl-extractable fraction by an inductively coupled plasma mass spectrometer. The accuracy and precision of the P-XRF measurements were evaluated by measuring 18 standard reference materials; this indicated the acceptable but limited quality of this method as a screening tool. The HCl-extractable levels of Al, Co, Cu, Zn, Cd, In, Sb, Ba, and Pb in 10 soil/ash mixtures varied by more than one order of magnitude. The levels of these metal(loid)s were found to be correlated with the color (i.e., soil/ash ratio), suggesting that they are being released from disposed e-waste via open burning. The source of rare elements could be constrained using correlation to the predominant metals. Human hazard quotient values based on ingestion of soil/ash mixtures exceeded unity for Pb, As, Sb, and Cu in a high-exposure scenario. This study showed that along with common metals, rare metal(loid)s are also enriched in the e-waste burning site. We suggest that risk assessment considering exposure to multiple metal(loid)s should be addressed in studies of e-waste recycling sites. - Highlights: • Contamination on the largest e-waste recycling site in Africa was investigated. • Portable X-ray Fluorescence analyzer useful for first screening • High levels of Cu, Zn, Pb, and Al in soil/ash mixtures • Hazards for workers are significant.

  1. Variation and distribution of metals and metalloids in soil/ash mixtures from Agbogbloshie e-waste recycling site in Accra, Ghana

    International Nuclear Information System (INIS)

    Itai, Takaaki; Otsuka, Masanari; Asante, Kwadwo Ansong; Muto, Mamoru; Opoku-Ankomah, Yaw; Ansa-Asare, Osmund Duodu; Tanabe, Shinsuke

    2014-01-01

    Illegal import and improper recycling of electronic waste (e-waste) are an environmental issue in developing countries around the world. African countries are no exception to this problem and the Agbogbloshie market in Accra, Ghana is a well-known e-waste recycling site. We have studied the levels of metal(loid)s in the mixtures of residual ash, formed by the burning of e-waste, and the cover soil, obtained using a portable X-ray fluorescence spectrometer (P-XRF) coupled with determination of the 1 M HCl-extractable fraction by an inductively coupled plasma mass spectrometer. The accuracy and precision of the P-XRF measurements were evaluated by measuring 18 standard reference materials; this indicated the acceptable but limited quality of this method as a screening tool. The HCl-extractable levels of Al, Co, Cu, Zn, Cd, In, Sb, Ba, and Pb in 10 soil/ash mixtures varied by more than one order of magnitude. The levels of these metal(loid)s were found to be correlated with the color (i.e., soil/ash ratio), suggesting that they are being released from disposed e-waste via open burning. The source of rare elements could be constrained using correlation to the predominant metals. Human hazard quotient values based on ingestion of soil/ash mixtures exceeded unity for Pb, As, Sb, and Cu in a high-exposure scenario. This study showed that along with common metals, rare metal(loid)s are also enriched in the e-waste burning site. We suggest that risk assessment considering exposure to multiple metal(loid)s should be addressed in studies of e-waste recycling sites. - Highlights: • Contamination on the largest e-waste recycling site in Africa was investigated. • Portable X-ray Fluorescence analyzer useful for first screening • High levels of Cu, Zn, Pb, and Al in soil/ash mixtures • Hazards for workers are significant

  2. Symbiotic efficiency of autochthonous arbuscular mycorrhizal fungus (G. mosseae) and Brevibacillus sp. isolated from cadmium polluted soil under increasing cadmium levels

    International Nuclear Information System (INIS)

    Vivas, A.; Voeroes, I.; Biro, B.; Campos, E.; Barea, J.M.; Azcon, R.

    2003-01-01

    Selected ubiquitous microorganisms are important components of Cd tolerance in plants. - The effect of inoculation with indigenous naturally occurring microorganisms [an arbuscular mycorrhizal (AM) fungus and rhizosphere bacteria] isolated from a Cd polluted soil was assayed on Trifolium repens growing in soil contaminated with a range of Cd. One of the bacterial isolate showed a marked PGPR effect and was identified as a Brevibacillus sp. Mycorrhizal colonization also enhanced Trifolium growth and N, P, Zn and Ni content and the dually inoculated (AM fungus plus Brevibacillus sp.) plants achieved further growth and nutrition and less Cd concentration, particularly at the highest Cd level. Increasing Cd level in the soil decreased Zn and Pb shoot accumulation. Coinoculation of Brevibacillus sp. and AM fungus increased shoot biomass over single mycorrhizal plants by 18% (at 13.6 mg Cd kg -1 ), 26% (at 33.0 mg Cd kg -1 ) and 35% (at 85.1 mg Cd kg -1 ). In contract, Cd transfer from soil to plants was substantially reduced and at the highest Cd level Brevibacillus sp. lowered this value by 37.5% in AM plants. Increasing Cd level highly reduced plant mycorrhization and nodulation. Strong positive effect of the bacterium on nodule formation was observed in all treatments. Results show that selected ubiquitous microorganisms, applied as enriched inocula, are important in plant Cd tolerance and development in Cd polluted soils

  3. The screen character of the Whitetiger mountain filling to radioactivity waste disposal

    International Nuclear Information System (INIS)

    Shi Jianfang

    2003-01-01

    Safety disposal of radioactivity waste depends on geology protective screen and artificial protective screen. After disposal site is chosen, the effect of artificial protective screen appears very important. The smashing material of Whitetiger Mountain clay rock is selected as researching object. The method of combining soil mechanics with radiochemistry is adopted on the basis of many experiment of laboratory. The screen effect and mechanism of filling layer to radioactivity nuclide 90 Sr are discussed. Under the circumstance of filling layer composition, control effect of soil body construction to permeability and adsorption of filling protective screen layer are analysed. Synthesis evaluation model of filling protective screen layer is established. It is found that the filling belongs to high-liquids-clay. For filling with diameter equal or smaller than 2 millimeter, when the ρ d equal 1.73 g/cm 3 , the most equitable moving speed of 90 Sr in compaction filling is 4.5 x 10 -5 cm/min, the k equals 2.68 x10 -8 cm/s. For filling with diameter equal or smaller than 5 mm, when the ρ d equal 1.74 g/cm 3 , the most equitable moving speed of 90 Sr in compaction filling is 4.3 x 10 -5 cm/min, the k equals 6.1 x 10 -8 cm/s. (author)

  4. Soil Moisture Active Passive (SMAP) Mission Level 4 Surface and Root Zone Soil Moisture (L4_SM) Product Specification Document

    Science.gov (United States)

    Reichle, Rolf H.; Ardizzone, Joseph V.; Kim, Gi-Kong; Lucchesi, Robert A.; Smith, Edmond B.; Weiss, Barry H.

    2015-01-01

    This is the Product Specification Document (PSD) for Level 4 Surface and Root Zone Soil Moisture (L4_SM) data for the Science Data System (SDS) of the Soil Moisture Active Passive (SMAP) project. The L4_SM data product provides estimates of land surface conditions based on the assimilation of SMAP observations into a customized version of the NASA Goddard Earth Observing System, Version 5 (GEOS-5) land data assimilation system (LDAS). This document applies to any standard L4_SM data product generated by the SMAP Project. The Soil Moisture Active Passive (SMAP) mission will enhance the accuracy and the resolution of space-based measurements of terrestrial soil moisture and freeze-thaw state. SMAP data products will have a noteworthy impact on multiple relevant and current Earth Science endeavors. These include: Understanding of the processes that link the terrestrial water, the energy and the carbon cycles, Estimations of global water and energy fluxes over the land surfaces, Quantification of the net carbon flux in boreal landscapes Forecast skill of both weather and climate, Predictions and monitoring of natural disasters including floods, landslides and droughts, and Predictions of agricultural productivity. To provide these data, the SMAP mission will deploy a satellite observatory in a near polar, sun synchronous orbit. The observatory will house an L-band radiometer that operates at 1.40 GHz and an L-band radar that operates at 1.26 GHz. The instruments will share a rotating reflector antenna with a 6 meter aperture that scans over a 1000 km swath.

  5. Effects of low-level radioactive soil contamination and sterilization on the degradation of radiolabeled wheat straw

    International Nuclear Information System (INIS)

    Niedrée, Bastian; Vereecken, Harry; Burauel, Peter

    2012-01-01

    After the explosion of reactor 4 in the nuclear power plant near Chernobyl, huge agricultural areas became contaminated with radionuclides. In this study, we want to elucidate whether 137 Cs and 90 Sr affect microorganisms and their community structure and functions in agricultural soil. For this purpose, the mineralization of radiolabeled wheat straw was examined in lab-scale microcosms. Native soils and autoclaved and reinoculated soils were incubated for 70 days at 20 °C. After incubation, the microbial community structure was compared via 16S and 18S rDNA denaturing gradient gel electrophoresis (DGGE). The radioactive contamination with 137 Cs and 90 Sr was found to have little effect on community structure and no effect on the straw mineralization. The autoclaving and reinoculation of soil had a strong influence on the mineralization and the community structure. Additionally we analyzed the effect of soil treatment on mineralization and community composition. It can be concluded that other environmental factors (such as changing content of dissolved organic carbon) are much stronger regulating factors in the mineralization of wheat straw and that low-level radiation only plays a minor role. - Highlights: ► We observed the impact of contamination with Cs-137 and Sr-90 on soil functions. ► Microbial community was altered slightly. ► Mineralization of wheat straw was not affected. ► Microbes growing on applied straw compete for nutrients with soil microbes.

  6. Combination of soil classification and some selected soil properties ...

    African Journals Online (AJOL)

    The advantage in the combined use of soil classification and top soil analysis for explaining crop yield variation was examined. Soil properties and yields of maize (Zea mays L) on different soil types were measured on farmers' fields for 2 years. Yield prediction improved from 2 per cent at the Order and Association levels to ...

  7. Soil Organic Carbon in the Soil Scapes of Southeastern Tanzania

    OpenAIRE

    Rossi, Joni

    2009-01-01

    Soil organic carbon (SOC) is well known to maintain several functions. On the one hand, being the major component of soil organic matter (SOM),it is a determinant of soil physical and chemical properties, an important proxy for soil biological activity and a measure of soil productivity. Land use management that will enhance soil carbon (C) levels is therefore important for farmers and land use planners, particularly in semiarid and sub-humid Africa where severe soil degradation and desertifi...

  8. Dihydrotestosterone and testosterone levels in men screened for prostate cancer: a study of a randomized population.

    Science.gov (United States)

    Gustafsson, O; Norming, U; Gustafsson, S; Eneroth, P; Aström, G; Nyman, C R

    1996-03-01

    To investigate the possible relationship between serum levels of prostate specific antigen (PSA), dihydrotestosterone (DHT), testosterone, sexual-hormone binding globulin (SHBG) and tumour stage, grade and ploidy in 65 cases of prostate cancer diagnosed in a screening study compared to 130 controls from the same population. From a population of 26,602 men between the ages of 55 and 70 years, 2400 were selected randomly and invited to undergo screening for prostate cancer using a digital rectal examination, transrectal ultrasonography and PSA analysis. Among the 1782 attendees, 65 cases of prostate cancer were diagnosed. Each case was matched with two control subjects of similar age and prostate volume from the screening population. Frozen serum samples were analysed for PSA, DHT, testosterone and SHBG, and compared to the diagnosis and tumour stage, grade and ploidy. Comparisons between these variables, and multivariate and regression analyses were performed. There were significant differences in PSA level with all variables except tumour ploidy. DHT levels were slightly lower in patients with prostate cancer but the difference was not statistically significant. There was a trend towards lower DHT values in more advanced tumours and the difference for T-stages was close to statistical significance (P = 0.059). Testosterone levels were lower in patients with cancer than in the control group, but the differences were not significant. There was no correlation between testosterone levels, tumour stage and ploidy, but the differences in testosterone level in tumours of a low grade of differentiation compared to those with intermediate and high grade was nearly significant (P = 0.058). The testosterone/DHT ratio tended to be higher in patients with more advanced tumours. SHBG levels were lower in patients with cancer than in controls but the differences were not statistically significant. There were no systematic variations of tumour stage, grade and ploidy. Multivariate

  9. Mitigation of soiling losses in solar collectors: Removal of surface-adhered dust particles using an electrodynamic screen

    Science.gov (United States)

    Sayyah, Arash

    Particulate contamination of the optical surfaces of solar collectors, often called "soiling", can have a significant deteriorating impact on energy yield due to the absorption and scattering of incident light. Soiling has more destructive effect on concentrated solar systems than on flat-plate photovoltaic panels, as the former are incapable of converting scattered sunlight. The first part of this thesis deals with the soiling losses of flat-plate photovoltaic (PV), concentrated solar power (CSP), and concentrated photovoltaic (CPV) systems in operation in several regions of the world. Influential parameters in dust accumulation losses, as well as different cleaning mechanisms in pursuit of restoring the efficiency of soiled systems, have been thoroughly investigated. In lieu of the most commonly-practiced manual cleaning method of using high-pressure water jets, the concept of automatic dust removal using the electrostatic forces of electrodynamic screen (EDS) technology is in a developmental stage and on its way toward commercialization. This thesis provides comprehensive analytical solutions for the electric potential and electric field distribution in EDS devices having different configurations. Numerical simulations developed using finite element analysis (FEA) software have corroborated the analytical solutions which can easily be embedded into software programs for particle trajectory simulations while also providing flexibility and generality in the study on the effect of different parameters of the EDS on the electric field and ensuing dust-removal performance. Evaluation and comparison of different repelling and attracting forces exerted on dust particles is of utmost importance to a detailed analysis of EDS performance in dust removal. Hence, the balance of electrostatic and adhesion forces, including van der Waals and capillary forces, have received significant attention in this dissertation. Furthermore, different numerical analyses have been

  10. Allowable residual contamination levels of radionuclides in soil from pathway analysis

    International Nuclear Information System (INIS)

    Nyquist, J.E.; Baes, C.F. III

    1987-01-01

    The Remedial Action Program (RAP) at Oak Ridge National Laboratory will include well drilling, facility upgrades, and other waste management operations likely to involve soils contaminated with radionuclides. A preliminary protocol and generalized criteria for handling contaminated soils is needed to coordinate and plan RAP activities, but there exists only limited information on contaminate nature and distribution at ORNL RAP sites. Furthermore, projections of long-term decommissioning and closure options for these sites are preliminary. They have adapted a pathway analysis model, DECOM, to quantify risks to human health from radionuclides in soil and used it to outline preliminary criteria for determining the fate of contaminated soil produced during RAP activities. They assumed that the site could be available for unrestricted use immediately upon decontamination. The pathways considered are consumption of food grown on the contaminated soil, including direct ingestion of soil from poorly washed vegetables, direct radiation from the ground surface, inhalation of resuspended radioactive soil, and drinking water from a well drilled through or near the contaminated soil. We will discuss the assumptions and simplifications implicit in DECOM, the site-specific data required, and the results of initial calculations for the Oak Ridge Reservation

  11. Bioaccessibility and Human Exposure Assessment of Cadmium and Arsenic in Pakchoi Genotypes Grown in Co-Contaminated Soils

    Science.gov (United States)

    Wei, Yanyan; Zheng, Xiaoman; Shohag, Md. Jahidul Islam; Gu, Minghua

    2017-01-01

    In many countries cadmium (Cd) and arsenic (As) commonly coexist in soils contaminated by mining activities, and can easily enter the human body via consumption of leafy vegetables, like the popularly consumed pakchoi (Brassica chinensis L.), causing major health concerns. In the present study, bioaccessibility and human exposure of Cd and As were assessed in twenty genotypes of pakchoi cultured at two different levels of co-contamination to identify low health risk genotypes. The bioaccessibilities of Cd and As represent a fraction of the total metals content could be bioaccessible for human, in the present study, significant differences in pakchoi Cd and As bioaccessibility were observed among all tested genotypes and co-contaminated levels. Cd and As bioaccessibility of pakchoi were in the ranges of 24.0–87.6% and 20.1–82.5%, respectively, for in the high level co-contaminated soils, which was significantly higher than for low level co-contaminated soils with 7.9–71.8% for Cd bioaccessibility and 16.1–59.0% for As bioaccessibility. The values of bioaccessible established daily intakes (BEDI) and the total bioaccessible target hazard quotients (TBTHQ) of Cd and As were also considerably higher in high level co-contaminated soils than in low level co-contaminated soils. Two genotypes (Meiguanqinggengcai and Zhenqing60F1) contained relatively low concentrations and bioaccessible Cd and As and, their BEDI and TBTHQ for Cd and As ranged below the tolerable limits set by the FAO/WHO (BEDI of Cd contaminated soils for adults and children. Consequently, these findings suggest identification of safe genotypes in leafy vegetable with low health risk via genotypic screening and breeding methods could be a useful strategy to ensure the safety of food crops grown in those Cd and As co-contaminated fields due to mining activities. PMID:28850097

  12. Performance assessment for low-level radioactive waste disposal

    International Nuclear Information System (INIS)

    Cook, J.R.; Hsu, R.H.; Wilhite, E.L.; Yu, A.D.

    1996-01-01

    In October 1994 the Savannah River Site became the first US DOE complex to use concrete vaults to dispose of low-level radioactive solid waste and better prevent soil and groundwater contamination. This article describes the design and gives a performance assessment of the vaults. Topics include the following: Performance objectives; scope; the performance assessment process-assemble a multidisciplinary working group; collect available data; define credible pathways/scenarios; develop conceptual models; conduct screening and detailed model calculations; assess sensitivity/uncertainty; integrate and interpret results; report. 9 figs., 3 tabs

  13. Development of disposable bulk-modified screen-printed electrode based on bismuth oxide for stripping chronopotentiometric analysis of lead (II) and cadmium (II) in soil and water samples

    International Nuclear Information System (INIS)

    Kadara, Rashid O.; Tothill, Ibtisam E.

    2008-01-01

    A bulk-modified screen-printed carbon electrode characterised for metal ion detection is presented. Bismuth oxide (Bi 2 O 3 ) was mixed with graphite-carbon ink to obtain the modified electrode. The best composition was 2% Bi 2 O 3 (wt%) in the graphite-carbon ink. The modified electrode with onboard screen-printed carbon counter and silver-silver chloride pseudo-reference electrodes exhibited good performance in the electrochemical measurement of lead (II) and cadmium (II). The electrode displayed excellent linear behaviour in the concentration range examined (20-300 μg L -1 ) with limits of detection of 8 and 16 μg L -1 for both lead (II) and cadmium (II), respectively. The analytical utility of the modified electrode was illustrated by the stripping chronopotentiometric determinations of lead (II) in soil extracts and wastewater samples

  14. Residue determination and levels of glyphosate in surface waters, sediments and soils associated with oil palm plantation in Tasik Chini, Pahang, Malaysia

    Science.gov (United States)

    Mardiana-Jansar, K.; Ismail, B. S.

    2014-09-01

    Levels of glyphosate and its main metabolite were determined in surface water, soil and sediment samples from an oil palm plantation area located at Tasik Chini, Pahang, Malaysia. The optimization analytical method has been developed for the determination of glyphosate herbicide and its metabolite amino-methyl-phosphonic acid (AMPA) in surface waters to a level of 0.1μg/L, while in sediments and soils to a level of 0.5μg/g with a good linearity in the calibration range of 1-100μg/L. The procedure involves a pre-columnderivatization step with 9-fluorenyl-methyl-chloroformate (FMOC-Cl) yielding highly fluorescent derivatives of the analytes which can be determined by HPLC with fluorescence detection. In the field, levels of glyphosate in surface waters ranges from not detected to 1.0mg/L, while in soils and sediments were from not detected to 6.0mg/kg. For AMPA, the residues in surface waters were between not detected to 2.0mg/L, while in soil and sediment samples were from not detected to 5mg/kg. This variation of glyphosate and AMPA levels depended directly on time of pesticide application and the season.

  15. Toxicity Assessments of Antimony, Barium, Beryllium, and Manganese for Development of Ecological Soil Screening Levels (ECO-SSL) Using Earthworm (Eisenia Fetida) Benchmark Values

    National Research Council Canada - National Science Library

    Simini, Michael

    2002-01-01

    ... soil that supports relatively high bioavailability of barium (Ba), beryllium (Be), manganese (Mn), and antimony (Sb). For the metals tested, cocoon production was a more sensitive endpoint than was survival...

  16. Ammonia Volatilization in Cocoa Farm as Affected by Sugarcane Filter Cake Supply at Different Urea and Soil Moisture Levels

    Directory of Open Access Journals (Sweden)

    Erwin Prastowo

    2015-02-01

    Full Text Available Ammonia  (NH3  volatilization  is  a  crucial  mechanism  in  soil  nitrogen  (N cycle. It accounts for main loss  of N in cocoa  farms  when  environment is  suitable to  promote  the  emission.  A  research  to  locate  a  link  of  several  factors,  namely, sugarcane filter cake  (SFC, urea  and soil moisture content  to NH 3 volatilization,  and  to reveal  cocoa  N  uptake  and  urea  fertilizer  efficiency  was  taken  place  both  in  a laboratory  with  the  incubation  technique,  and  in  a  greenhouse  as  a  pot  trial. The design was completely randomized design in factorial. The soil was Inceptisol from Kaliwining Experimental Station, Jember, East Java, collected from top soil of  a  productive  cocoa  farm.  A  closed  trap  system  was  designed  to  measurevolatilized  NH 3 from  soil  and  SFC  mixture  incubated  for  14  days.  For  the  pot experiment,  cocoa  clone  of  Scavina  6  seedlings  were  grown  for  six  months  withtreatments  involving  series  level  of  SFC  and  series  level  of  urea.  Soil  moisture content influenced volatilized NH3 by reducing 50% emission in where it was more obvious in higher level of urea applied. It was more than 90% in average for the increase in volatilized NH 3roduced by increasing in level of urea from 0 to 0.4 g kg -1 in  overall  level  of  combinations. An increase in urea  level  had  resulted in increase in  soil  pH, and  Parson correlation suggested a direct  link  with  volatilized  NH 3  We found  a  relationship  between  SFC  and volatilized  NH 3 and  their combinations  with soil  moisture  and  urea  content  were  able  to  inhibit  the  emission.  Emission decrease  up  to  28%  was  observed  from  0  to  100  g  SFC  kg-1.  This  inhibition may  have contributed to  the increase in  N cocoa  plant uptake

  17. Primary care colorectal cancer screening correlates with breast cancer screening: implications for colorectal cancer screening improvement interventions.

    Science.gov (United States)

    Weiss, Jennifer M; Pandhi, Nancy; Kraft, Sally; Potvien, Aaron; Carayon, Pascale; Smith, Maureen A

    2018-04-25

    National colorectal cancer (CRC) screening rates have plateaued. To optimize interventions targeting those unscreened, a better understanding is needed of how this preventive service fits in with multiple preventive and chronic care needs managed by primary care providers (PCPs). This study examines whether PCP practices of other preventive and chronic care needs correlate with CRC screening. We performed a retrospective cohort study of 90 PCPs and 33,137 CRC screening-eligible patients. Five PCP quality metrics (breast cancer screening, cervical cancer screening, HgbA1c and LDL testing, and blood pressure control) were measured. A baseline correlation test was performed between these metrics and PCP CRC screening rates. Multivariable logistic regression with clustering at the clinic-level estimated odds ratios and 95% confidence intervals for these PCP quality metrics, patient and PCP characteristics, and their relationship to CRC screening. PCP CRC screening rates have a strong correlation with breast cancer screening rates (r = 0.7414, p < 0.001) and a weak correlation with the other quality metrics. In the final adjusted model, the only PCP quality metric that significantly predicted CRC screening was breast cancer screening (OR 1.25; 95% CI 1.11-1.42; p < 0.001). PCP CRC screening rates are highly concordant with breast cancer screening. CRC screening is weakly concordant with cervical cancer screening and chronic disease management metrics. Efforts targeting PCPs to increase CRC screening rates could be bundled with breast cancer screening improvement interventions to increase their impact and success.

  18. Assessment of gamma radiation levels and natural radioactivity in soils along a subtropical river basin, China

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Dekun; Yu, Tao [Third Institute of Oceanography, Xiamen (China). Lab. of Marine Isotopic Technology and Environmental Risk Assessment

    2017-07-01

    The activities of natural radionuclides in the environment can be used to assess radiological effects. Monitoring the radiation level in soils is important for public health. It also has important geochemical implications as most of the sediment eroded from river basins is from soil. Therefore, we carried out a soil sampling campaign along a subtropical river basin in southeastern China (Jiulong River). Surface and depth profile soils were collected, and the natural radionuclide activities were measured. The activities of the natural radionuclides {sup 238}U, {sup 232}Th, and {sup 40}K in the surface soils varied from 31.6 to 132.1 Bq kg-dry{sup -1}, 37.8 to 174.0 Bq kg-dry{sup -1}, and 52.3 to 596.2 Bq kg-dry{sup -1}, with average values of 56.7±30.3 Bq kg-dry{sup -1}, 86.7±41.3 Bq kg-dry{sup -1}, and 352.8±190.6 Bq kg-dry{sup -1}, respectively. The absorbed gamma dose in air and the annual effective dose equivalent (AEDE) in surface soils along the river basin were both higher than the world average. In the depth profiles, excess {sup 210}Pb ({sup 210}Pbex) decreased with depth and significant correlation between {sup 210}Pbex and TOC was observed, suggesting that they are affected by similar processes (leaching and sorption).

  19. The rocky flats controversy on radionuclide soil action levels

    International Nuclear Information System (INIS)

    Earle, T.C.

    2004-01-01

    This report describes how stakeholder involvement processes led to the successful resolution of a dispute over radionuclide soil action levels at the Rocky Flats Site near Denver, Colorado. During the Cold War Era, Rocky Flats, a plutonium fabrication plant, was part of the American government's multi-site nuclear weapons production facilities. Although the Rocky Flats plant had significant positive effects on the local economy, it became a target of public protest due to concerns over both public safety in the area surrounding the site and global nuclear proliferation. In the late 1980's, local safety concerns led to investigations by state and federal agencies. In 1992, with the Cold War ended, the Department of Energy decided to decommission the Rocky Flats site and to begin the long process of decontamination. (author)

  20. Levels of toxic elements in soils of abandoned waste dump site

    African Journals Online (AJOL)

    GRACE

    2006-07-03

    Jul 3, 2006 ... Correlation coefficient (r value) between heavy metals in soils and some soil factor. Factor. Pb. Ni. Cr ... Isirimah NO, Igwe C, Iwegbue CMA (2003). Important Ions in ... Laboratory Manual for the Analysis of. Soils, Plants and ...

  1. Spatial distribution of metals in soils in Baltimore, Maryland: role of native parent material, proximity to major roads, housing age and screening guidelines

    Science.gov (United States)

    I.D. Yesilonis; R.V. Pouyat; N.K. Neerchal

    2008-01-01

    We investigated the spatial distribution of heavy metal above-background (anthropic) contents of Cd, Co, Cu, Cr, Fe, Mn, Ni, Pb, Ti, V, and Zn in Baltimore City surface soils and related these levels to potential contaminating sources. Composite soil samples (0?10 cm depth) were digested using a nitric and hydrochloric extraction technique. Slightly more than 10% of...

  2. Low level measurements of natural radionuclides in soil samples around a coal-fired power plant

    Energy Technology Data Exchange (ETDEWEB)

    Rosner, G.; Bunzl, K.; Hoetzl, H.; Winkler, R. (Gesellschaft fuer Strahlen- und Umweltforschung m.b.H. Muenchen, Neuherberg (Germany, F.R.). Inst. fuer Strahlenschutz)

    1984-06-15

    To detect a possible contribution of airborne radioactivity from stack effluents to the soil radioactivity, several radionuclides in the soil around a coal-fired power plant have been determined. A plant situated in a rural region of Bavaria was selected to minimize contributions from other civilisatory sources. The soil sampling network consisted of 5 concentric circles with diameters between 0.4 and 5.2 km around the plant, 16 sampling points being distributed regularly on each circle. Radiochemical analysis techniques for /sup 210/Pb and /sup 210/Po in soil samples of several grams has to be developed. They include a wet dissolution procedure, simultaneous precipitation of lead and polonium as the sulfides, purification via lead sulfate, counting of the lead as the chromate in a low-level beta counter and alpha spectrometric determination of the /sup 210/Po in a gridded ionization chamber. The /sup 238/U, /sup 226/Ra, /sup 232/Th and /sup 40/K were counted by low level gamma spectrometry. Specific activities found were in the range of 0.7 to 2.0 pCi g/sup -1/ for /sup 210/Pb and 0.3 to 1.6 pCi g/sup -1/ for /sup 226/Ra. The distribution patterns of /sup 210/Po and /sup 210/Pb around the plant were found to be similar. They were different, however, from that of /sup 226/Ra. The highest /sup 210/Pb//sup 226/Ra activity ratio was 3.9 at a distance of 0.76 km SSE from the plant. Nevertheless, the evidence is not considered to be sufficient to attribute these observations unambiguously to plant release.

  3. Interconnection between precipitation density, soil contamination levels and 90Sr and 137Cs content in food stuffs

    International Nuclear Information System (INIS)

    Knizhnikov, V.A.; Petukhova, Eh.V.

    1980-01-01

    Presented are the data dynamically characterizing the density of radioactive fallout, contamination of soil and the main kinds of food stuffs with 137 Cs and 90 Sr. It is shown that 90 Sr contamination of bakery products in the country within the whole period of observation is in direct dependence on the density of atmospheric fallouts as a whole in the northern hemisphere. In the reverse, 90 Sr potato contamination primarily correlates with nuclide content in the soil. The dependence between milk contamination and fallout density has an intermediate character as compared with the above types of food stuffs. The same is true for 137 Cs, but a clear tendency to a faster decrease in the level of food stuffs contamination is observed. The importance of the soil way in food stuffs contamination and peculiarities of nuclide migration in food stuffs from various types of soil are considered

  4. A two-stage extraction procedure for insensitive munition (IM) explosive compounds in soils.

    Science.gov (United States)

    Felt, Deborah; Gurtowski, Luke; Nestler, Catherine C; Johnson, Jared; Larson, Steven

    2016-12-01

    The Department of Defense (DoD) is developing a new category of insensitive munitions (IMs) that are more resistant to detonation or promulgation from external stimuli than traditional munition formulations. The new explosive constituent compounds are 2,4-dinitroanisole (DNAN), nitroguanidine (NQ), and nitrotriazolone (NTO). The production and use of IM formulations may result in interaction of IM component compounds with soil. The chemical properties of these IM compounds present unique challenges for extraction from environmental matrices such as soil. A two-stage extraction procedure was developed and tested using several soil types amended with known concentrations of IM compounds. This procedure incorporates both an acidified phase and an organic phase to account for the chemical properties of the IM compounds. The method detection limits (MDLs) for all IM compounds in all soil types were regulatory risk-based Regional Screening Level (RSL) criteria for soil proposed by the U.S. Army Public Health Center. At defined environmentally relevant concentrations, the average recovery of each IM compound in each soil type was consistent and greater than 85%. The two-stage extraction method decreased the influence of soil composition on IM compound recovery. UV analysis of NTO established an isosbestic point based on varied pH at a detection wavelength of 341 nm. The two-stage soil extraction method is equally effective for traditional munition compounds, a potentially important point when examining soils exposed to both traditional and insensitive munitions. Copyright © 2016 Elsevier Ltd. All rights reserved.

  5. Impact of mine tailings on surrounding soils: Case

    African Journals Online (AJOL)

    H. ABDURAHMAN

    metals concentration was done by atomic absorption spectroscopy (AAS). ... its effects causing a progressive pollution of soil with heavy metal emissions in ... MATERIALS AND METHODS ..... Validation of avoidance assays for the screening.

  6. Grey water treatment by the slanted soil system with unsorted soil media.

    Science.gov (United States)

    Ushijima, Ken; Tanaka, Erina; Suzuki, Laís Yuko; Hijikata, Nowaki; Funamizu, Naoyuki; Ito, Ryusei

    2015-01-01

    This study evaluated the performance of unsorted soil media in the slanted soil treatment system, in terms of removal efficiency in suspended solids (SS), chemical oxygen demand (COD), linear alkylbenzene sulphonate (LAS) and Escherichia coli, and lifetime until clogging occurs. Unsorted soil performed longer lifetime until clogging than sorted fine soil. Removal of SS, COD, and LAS also performed same or better level in unsorted soil than fine soil. As reaction coefficients of COD and LAS were described as a function of the hydraulic loading rate, we can design a slanted soil system according to the expected hydraulic loading rate and the targeted level of COD or LAS in effluent. Regarding bacteria removal, unsorted soil performed sufficient reduction of E. coli for 5 weeks; however, the removal process occurred throughout all four chambers, while that of fine soil occurred in one to two chambers.

  7. Seasonal and spatial variations in Rn-222 and Rn-220 in soil gas, and implications for indoor radon levels

    International Nuclear Information System (INIS)

    Sharman, G.

    1992-01-01

    Rn-222 enters dwellings as a component of soil gas drawn from the soil by mass flow driven by the pressure difference between the house and soil beneath. In a site on Northampton Sand Ironstone (Aalenian), a preferred path of emanation (hotspot) was found. A difference of 63 Bq L -1 Rn-222 was recorded in July between this point and another 3 m away. Rn-222 in this hotspot shows 12% less variation annually than the surrounding rock. During winter, Rn-222 values within 1.6 m of the house were 44% lower than those at more than 4 m away. Rn-222 showed a 99.5% negative correlation with wind run, showing that on this soil wind pressure can significantly reduce radon in the soil at 500 mm depth. Rn-220 in soil gas correlated positively at the 99.5% level with grass and air temperatures. Rn-220 was not associated with the hotspot. (Author)

  8. Development of Soil Derived Concentration Guidance Levels for Decommissioning at Overseas Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, Wook; Yoon, Suk Bon; Kim, Jeongju [KHNP CRI, Daejeon (Korea, Republic of)

    2016-10-15

    In Korea, the criteria are expected to be given in terms of dose as in US and Spain. However, since dose cannot be measured, corresponding measurable concentration limits, so-called Derived Concentration Guidance Levels (DCGLs), should be developed for each radionuclide which is expected to be present in the site. Also, as they serve as a goal of decommissioning and direct dismantling and decontamination methods applicable to the site, DCGLs should be developed in the early phase of decommissioning. This paper describes how each overseas nuclear power plant developed its site-specific Soil DCGLs: what kind of post closure use of the site (scenario) was assumed and how the site-specific Soil DCGLs were calculated based on the scenario assumed for each plant. Through this, it is intended to derive lessons learned which will be instructive for future decommissioning of domestic nuclear power plants including Kori Unit 1. It is very important to have as good under-standing as possible of characteristics of the site by collection of relevant information and data in order to apply a scenario which is most foreseeable and plausible for a site to be decommissioned and to provide site-specific inputs to the calculation of the Soil DCGLs. These efforts will help to have not-overly conservative values for the Soil DCGLs, thus thereby reducing the costs and time needed for performing the decommissioning.

  9. Low levels of neurocognitive impairment detected in screening HIV-infected men who have sex with men: The MSM Neurocog Study.

    Science.gov (United States)

    Barber, T J; Bansi, L; Pozniak, A; Asboe, D; Nelson, M; Moyle, G; Davies, N; Margetts, A; Ratcliffe, D; Catalan, J; Boffito, M; Gazzard, B

    2017-06-01

    This study aimed to determine the prevalence of HIV neurocognitive impairment in HIV-infected men who have sex with men aged 18-50 years, using a simple battery of screening tests in routine clinical appointments. Those with suspected abnormalities were referred on for further assessment. The cohort was also followed up over time to look at evolving changes. HIV-infected participants were recruited at three clinical sites in London during from routine clinical visits. They could be clinician or self-referred and did not need to be symptomatic. They completed questionnaires on anxiety, depression, and memory. They were then screened using the Brief Neurocognitive Screen (BNCS) and International HIV Dementia Scale (IHDS). Two hundred and five HIV-infected subjects were recruited. Of these, 59 patients were excluded as having a mood disorder and two patients were excluded due to insufficient data, leaving 144 patients for analysis. One hundred and twenty-four (86.1%) had a normal composite z score (within 1 SD of mean) calculated for their scores on the three component tests of the BNCS. Twenty (13.9%) had an abnormal z score, of which seven (35%) were symptomatic and 13 (65%) asymptomatic. Current employment and previous educational level were significantly associated with BNCS scores. Of those referred onwards for diagnostic testing, only one participant was found to have impairment likely related to HIV infection. We were able to easily screen for mood disorders and cognitive impairment in routine clinical practice. We identified a high level of depression and anxiety in our cohort. Using simple screening tests in clinic and an onward referral process for further testing, we were not able to identify neurocognitive impairment in this cohort at levels consistent with published data.

  10. Effectiveness of the GAEC standard of cross compliance Prohibition of performing unauthorized land levelling on soil erosion control

    Directory of Open Access Journals (Sweden)

    Paolo Bazzoffi

    2011-08-01

    Full Text Available The GAEC standard land levelling under authorization of cross compliance prohibits farmers from levelling land through bulldozing without a specific permission issued by the proper territorial authority. The aim of the standard is to ensure the protection of soil from accelerated erosion that almost always occurs when land is levelled without conservative criteria. Land levelling prior to planting or replanting specialized crops, especially orchards, is indicated by agronomists as essential to the full mechanization of cultivation and harvesting operations and the success of economic investment. Land levelling leads to a deep modification of the hill slopes, so it may produce serious damage to the environment if carried out in the absence of a carefully planned design. In other words, a design that takes the aspects of soil conservation into account, especially for steep hill slopes where the insite and offsite environmental impacts of soil erosion may be more pronounced. With regard to the areas involved, land levelling plays a key role on a national scale, one only needs to think of the vineyards planted on the country’s hill slopes, which in 1970 covered an area of 793,000 hectares. Moreover, despite the continued reduction in areas planted with vines, from 1990 to 2002 the area devoted to DOC and DOCG wines increased by about 29% and the average size of vineyards has also increased. This is a clear sign of the current trend, with the transition from the family model to the industrial model of orchard management, with extensive use of machinery and thus the use of bulldozers for levelling. The authorization topic, on which the standard of compliance is based, is analysed in detail. In summary we can say that, according to law, the permit required by the GAEC standard is currently mandatory only for those areas subject to the Hydrogeological constraint (Royal decree 30 December 1923 No. 3267 and for parks or other areas for which the

  11. Ultrasonographic views for the screening of congenital heart defects in the first level of care

    International Nuclear Information System (INIS)

    Garcia Guevara, Carlos; Arenciabia Faife, Jakeline; Ley Vega, Lisset

    2009-01-01

    Congenital heart diseases are the main cause of infant mortality for congenital malformations in our country and they are the defects that more usually escape diagnosis in ultrasonographic screening, especially if we consider that associated risk factors call for a fetal echocardiogram are not identified in most pregnant women with fetuses affected with a heart disease. With this paper, we intend to bring within reach of both the specialists dedicated to this activity in primary care and the Masters in Genetic Counseling a review article about the principal aspects to be evaluated in each of the three echocardiography views that are used in Cuba as part of screening these defects, as well as the main signs of suspicion of congenital heart diseases that give reason for having a pregnant woman referred to the immediately higher level of care

  12. STUDY OF HORIZONTAL SCREEN STRENGTH CREATED BY INJECTION TECHNOLOGY CEMENT BINDER BASED

    Directory of Open Access Journals (Sweden)

    BORISOV A. A.

    2016-09-01

    Full Text Available Annotation. Formulation of the problem. An important indicator in the planning of injection works is a particle size distribution of the soil and the very composition of injection. The ideal case is to comply with the injection optimum ratio between the size of particles in solution and injectable medium. This ratio corresponds to complete impregnation of the environment. Today in the field of building technologies known classical methods of grouting with the injection process [9]. This may be a cementation or silicification with different chemical compositions. Due to the fact that we have proposed an innovative technology of impervious curtain device, special attention should be paid to the performance and physical and mechanical properties of the resulting soil-injection. This is due to the fact that the proposed technology provides for lesser known technical solutions, the use of which should ultimately result in impervious screens with desired properties. Goal. The aim of this study is to investigate the properties of the resulting soil-concrete impervious screen. Such structures should have defined a number of physical and mechanical properties. In this paper, it was of interest to study the compressive strength of the resulting soil-concrete structure. Conclusion. As a result of experimentation and implementation of complex obtained experimentally-statistical models that describe the main soil-quality indicators. Based on these data is possible optimal selection of formulation and technological structure for sandy soils with different modules size of its particles.

  13. Soil Porewater Salinity Response to Sea-level Rise in Tidal Freshwater Forested Wetlands: A Modeling Study

    Science.gov (United States)

    Stagg, C. L.; Wang, H.; Krauss, K.; Conrads, P. A.; Swarzenski, C.; Duberstein, J. A.; DeAngelis, D.

    2017-12-01

    There is a growing concern about the adverse effects of salt water intrusion via tidal rivers and creeks into tidal freshwater forested wetlands (TFFWs) due to rising sea levels and reduction of freshwater flow. The distribution and composition of plant species, vegetation productivity, and biogeochemical functions including carbon sequestration capacity and flux rates in TFFWs have been found to be affected by increasing river and soil porewater salinities, with significant shifts occurring at a porewater salinity threshold of 3 PSU. However, the drivers of soil porewater salinity, which impact the health and ecological functions of TFFWs remains unclear, limiting our capability of predicting the future impacts of saltwater intrusion on ecosystem services provided by TFFWs. In this study, we developed a soil porewater salinity model for TFFWs based on an existing salt and water balance model with modifications to several key features such as the feedback mechanisms of soil salinity on evapotranspiration reduction and hydraulic conductivity. We selected sites along the floodplains of two rivers, the Waccamaw River (SC, USA) and the Savannah River (GA and SC, USA) that represent landscape salinity gradients of both surface water and soil porewater from tidal influence of the Atlantic Ocean. These sites represent healthy, moderately and highly salt-impacted forests, and oligohaline marshes. The soil porewater salinity model was calibrated and validated using field data collected at these sites throughout 2008-2016. The model results agreed well with field measurements. Analyses of the preliminary simulation results indicate that the magnitude, seasonal and annual variability, and duration of threshold salinities (e.g., 3 PSU) tend to vary significantly with vegetation status and type (i.e., healthy, degraded forests, and oligohaline marshes), especially during drought conditions. The soil porewater salinity model could be coupled with a wetland soil biogeochemistry

  14. Testing of multistep soil washing for radiocesium-contaminated soil containing plant matter

    International Nuclear Information System (INIS)

    Funakawa, Masafumi; Tagawa, Akihiro; Okuda, Nobuyasu

    2012-01-01

    Decontamination work following radiocesium exposure requires a vast reduction in the amount of contaminated soil generated. The current study subjected 4 types of contaminated soil with different properties to multistep soil washing under the same conditions. This study also determined the effectiveness of radiocesium decontamination and the extent to which the amount of contaminated soil was reduced. In addition, the effectiveness of plant matter separation, adsorbent addition, and grinding as part of multistep soil washing was determined using the same contaminated soil. Results of testing indicated that the rate of radiocesium decontamination ranged from 73.6 to 89.2% and the recovery rate ranged from 51.5 to 84.2% for twice-treated soil, regardless of the soil properties or cesium level. Plant matter in soil had a high radiocesium level. However, there was little plant matter in our soil sample. Therefore, plant matter separation had little effect on the improvement in the percentage of radiocesium decontamination of twice-treated soil. Soil surface grinding improved the rate of radiocesium decontamination of twice-treated soil. However, radiocesium in soil tightly bound with minerals in the soil; thus, the addition of an adsorbent also failed to improve the rate of radiocesium decontamination. (author)

  15. Prediction of blood lead levels in children before and after remediation of soil samples in the upper Meza Valley, Slovenia.

    Science.gov (United States)

    Jez, Erika; Lestan, Domen

    2015-10-15

    The Meza Valley, Slovenia, has been contaminated by Pb smelting, resulting in an epidemic of lead poisoning in childhood. The potential of remediation with EDTA soil washing to mitigate the risk from Pb poisoning was investigated by applying the Integrated Exposure Uptake Bio-kinetic (IEUBK) model. Soils from 79 locations were collected and the total and bio-accessible Pb concentrations were determined before and after extraction with 60 mmol kg(-1) EDTA. Extraction reduced the soil Pb concentration in towns of Mezica, Zerjav and Crna by 53, 67 and 62%, respectively, and the concentration of in vitro bio-accessible Pb in the simulated human gastric phase by 2.6-, 3.2- and 2.9-times, respectively. The predictions of the IEUBK model based on Pb contamination data were verified with data on blood Pb levels in children. The IEUBK model predicted that, after soil remediation, the number of locations at which the expected blood Pb level in children was higher than the stipulated 10 μg d L(-1) would decrease by 90, 38 and 91% in the towns of Mezica, Zerjav and Crna, respectively. The results confirmed the feasibility of soil washing with EDTA as an efficient remediation measure in Mezica and Crna and advice for soil capping/removal for the most polluted town of Zerjav. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. The design of disengaging mechanism of radix pseudostellariae and soil

    Science.gov (United States)

    Xiao, Shungen; Song, Mengmeng; Chen, Chanwei

    2017-12-01

    With the continuous development of the scale of the cultivation of the radix pseudostellariae, the traditional separation mode cannot adapt to the mass production of the crown prince, and the existing manual separation mode is of great labor intensity and low degree of mechanization. Therefore, it is necessary to design a disengaging mechanism of radix pseudostellariae and soil on the basis of the design principle of modern agricultural machinery. According to the physical characteristics and growing environment of radix pseudostellariae, a drum-type separating component is presented, and the drum screen separating mechanism and vibration mechanism of the disengaging mechanism are designed. In this paper, the movement rule and time of the mixture of radix pseudostellariae and soil are determined in the drum screen. Rotation speed of the drum screen is calculated, and the operation rules of the eccentric wheel in the vibration mechanism are summarized.

  17. Development of disposable bulk-modified screen-printed electrode based on bismuth oxide for stripping chronopotentiometric analysis of lead (II) and cadmium (II) in soil and water samples

    Energy Technology Data Exchange (ETDEWEB)

    Kadara, Rashid O. [Cranfield Health, Cranfield University, Silsoe, Bedfordshire MK45 4DT (United Kingdom); School of Science and Technology, Nottingham Trent University, Clifton Campus, Nottinghamshire NG11 8NS (United Kingdom)], E-mail: kayusee2001@yahoo.co.uk; Tothill, Ibtisam E. [Cranfield Health, Cranfield University, Silsoe, Bedfordshire MK45 4DT (United Kingdom)

    2008-08-08

    A bulk-modified screen-printed carbon electrode characterised for metal ion detection is presented. Bismuth oxide (Bi{sub 2}O{sub 3}) was mixed with graphite-carbon ink to obtain the modified electrode. The best composition was 2% Bi{sub 2}O{sub 3} (wt%) in the graphite-carbon ink. The modified electrode with onboard screen-printed carbon counter and silver-silver chloride pseudo-reference electrodes exhibited good performance in the electrochemical measurement of lead (II) and cadmium (II). The electrode displayed excellent linear behaviour in the concentration range examined (20-300 {mu}g L{sup -1}) with limits of detection of 8 and 16 {mu}g L{sup -1} for both lead (II) and cadmium (II), respectively. The analytical utility of the modified electrode was illustrated by the stripping chronopotentiometric determinations of lead (II) in soil extracts and wastewater samples.

  18. Seasonal and inter-annual variations of leaf-level photosynthesis and soil respiration in the representative ecosystems of the Okavango Delta, Botswana

    NARCIS (Netherlands)

    Mantlana, K.B.

    2008-01-01

    Seasonal and inter-annual leaf-level photosynthesis and soil respiration measurements were conducted in representative ecosystems of the Okavango Delta, Botswana, that differ in their long-term soil water content: the permanent swamp, the seasonal floodplain, the rain-fed grassland and the mopane

  19. Novel Technology for Wide-Area Screening of ERC-Contaminated Soils

    National Research Council Canada - National Science Library

    Fisher, Mark

    2005-01-01

    Long-term use of high explosives (HE) on DoD training ranges and other defense installations has in some cases resulted in contamination of soil and groundwater with residues of HE and explosive-related compounds (ERCs...

  20. Ultra-low level plutonium isotopes in the NIST SRM 4355A (Peruvian Soil-1)

    International Nuclear Information System (INIS)

    Inn, Kenneth G.W.; LaRosa, Jerome; Nour, Svetlana; Brooks, George; LaMont, Steve; Steiner, Rob; Williams, Ross; Patton, Brad; Bostick, Debbie; Eiden, Gregory; Petersen, Steve; Douglas, Matthew; Beals, Donna; Cadieux, James; Hall, Greg; Goldberg, Steve; Vogt, Stephan

    2009-01-01

    For more than 20 years, countries and their agencies which monitor radionuclide discharge sites and storage facilities have relied on the National Institute of Standards and Technology (NIST) Standard Reference Material (SRM) 4355 Peruvian Soil. Its low fallout contamination makes it an ideal soil blank for measurements associated with terrestrial-pathway-to-man studies. Presently, SRM 4355 is out of stock, and a new batch of the Peruvian soil is currently under development as future NIST SRM 4355A. Both environmental radioanalytical laboratories and mass spectrometry communities will benefit from the use of this SRM. The former must assess their laboratory procedural contamination and measurement detection limits by measurement of blank sample material. The Peruvian Soil is so low in anthropogenic radionuclide content that it is a suitable virtual blank. On the other hand, mass spectrometric laboratories have high sensitivity instruments that are capable of quantitative isotopic measurements at low plutonium levels in the SRM 4355 (first Peruvian Soil SRM) that provided the mass spectrometric community with the calibration, quality control, and testing material needed for methods development and legal defensibility. The quantification of the ultra-low plutonium content in the SRM 4355A was a considerable challenge for the mass spectrometric laboratories. Careful blank control and correction, isobaric interferences, instrument stability, peak assessment, and detection assessment were necessary. Furthermore, a systematic statistical evaluation of the measurement results and considerable discussions with the mass spectroscopy metrologists were needed to derive the certified values and uncertainties. The one sided upper limit of the 95% tolerance with 95% confidence for the massic 239 Pu content in SRM 4355A is estimated to be 54,000 atoms/g.

  1. Natural radioactivity in soils of the state of Rio de Janeiro (Brazil): Radiological characterization and relationships to geological formation, soil types and soil properties.

    Science.gov (United States)

    Ribeiro, F C A; Silva, J I R; Lima, E S A; do Amaral Sobrinho, N M B; Perez, D V; Lauria, D C

    2018-02-01

    Located in the south-western part of Brazil, the state of Rio de Janeiro is geotectonically contained within a complex structural province that resulted in the amalgamation of the Western Gondwana Paleocontinent. To undertake an extensive radiological characterization of this complex geological province and investigate the influence of bedrock, soil type and soil chemical-physical characteristics on natural radionuclide levels in soils, 259 surface soil samples were collected that encompassed the main soil types and geological formations throughout the state. Gamma spectrometry analysis of the samples resulted in median values of 114 Bq.kg -1 for 40 K, 32 Bq.kg -1 for 226 Ra and 74 Bq.kg -1 for 228 Ra. The median value for 226 Ra was similar to the world median value for soils, the 40 K value was well below the worldwide value, and that for 228 Ra exceeded the world median value. The intense weathering caused by the high rainfall rates and high temperatures may be responsible for the low levels of 40 K in the soils, of which the strongly acidic and clayey soils are markedly K-depleted. A soil from a high-grade metamorphic rock (granulite) presented the lowest 226 Ra (18 Bq.kg -1 ) content, whereas the highest levels for 226 Ra (92 Bq.kg -1 ) and 228 Ra (139 Bq.kg - 1) were observed in a young soil enriched in primary minerals (Leptsol). A lowland soil (Gleysol) showed the highest median of 40 K (301 Bq.kg -1 ). Strongly acidic soils tended to present high amounts of 226 Ra, and sandy soils tended to contain low levels of 228 Ra. The external radiation dose indicates that the state has a background radiation level within the natural range. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. [PHAHs levels in soil samples from the E-waste disassembly sites and their sources allocation].

    Science.gov (United States)

    Zhao, Gao-Feng; Wang, Zi-Jian

    2009-06-15

    Soil samples (each with 3 replicates of - 1 kg, at the top 0-5 cm layer) were collected from each of the e-waste disassembly sites and the control site. Also obtained from each disassembly site were samples (each weighing - 0.2 kg) of cable coating,stuffing powder, and circuit boards chipping. The contents of 23 PBB congeners, 12 PBDE congeners, and 27 PCB congeners in soil and in their potential sources, including e-waste residues, were measured using the GC-MS5975B technique. The highest level of PBBs was found in the cable coating among the three e-waste residues, with a concentration of 35.25 ng x g(-1). The contents of low-brominated PBBs (including monobromobiphenyls and dibromobiphenyls) accounted for 38% of the total PBBs concentration observed in cable coating sample. The highest levels of PBDEs and PBDE209 were found in the stuffing powder for electronic component among the collected e-waste residues, with a concentration of 29.71 and 4.19 x 10(3) ng x g(-1). PBDE153 and PBDE183 were the most predominant PBDE congeners, with their concentration accounting for 43% and 24% of the total PBDEs concentration observed in the stuffing powder sample, respectively. Levels of PCBs in cable coating were the highest in these e-waste residues, with a concentration of 680.02 ngx g(-1). The observed values of the three PHAHs in soils from the disassembly site were considerably higher than their corresponding values observed in the control site (p < 0.05), which indicates that these PHAHs from e-waste is the pollution source of local environment.

  3. Phytoextraction of excess soil phosphorus

    International Nuclear Information System (INIS)

    Sharma, Nilesh C.; Starnes, Daniel L.; Sahi, Shivendra V.

    2007-01-01

    In the search for a suitable plant to be used in P phytoremediation, several species belonging to legume, vegetable and herb crops were grown in P-enriched soils, and screened for P accumulation potentials. A large variation in P concentrations of different plant species was observed. Some vegetable species such as cucumber (Cucumis sativus) and yellow squash (Cucurbita pepo var. melopepo) were identified as potential P accumulators with >1% (dry weight) P in their shoots. These plants also displayed a satisfactory biomass accumulation while growing on a high concentration of soil P. The elevated activities of phosphomonoesterase and phytase were observed when plants were grown in P-enriched soils, this possibly contributing to high P acquisition in these species. Sunflower plants also demonstrated an increased shoot P accumulation. This study shows that the phytoextraction of phosphorus can be effective using appropriate plant species. - Crop plants such as cucumber, squash and sunflower accumulate phosphorus and thus can be used in the phytoextraction of excess phosphorus from soils

  4. Phytoextraction of excess soil phosphorus

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Nilesh C. [Department of Biology, Western Kentucky University, 1906 College Heights Boulevard 11080, Bowling Green, KY 42101-1080 (United States); Starnes, Daniel L. [Department of Biology, Western Kentucky University, 1906 College Heights Boulevard 11080, Bowling Green, KY 42101-1080 (United States); Sahi, Shivendra V. [Department of Biology, Western Kentucky University, 1906 College Heights Boulevard 11080, Bowling Green, KY 42101-1080 (United States)]. E-mail: shiv.sahi@wku.edu

    2007-03-15

    In the search for a suitable plant to be used in P phytoremediation, several species belonging to legume, vegetable and herb crops were grown in P-enriched soils, and screened for P accumulation potentials. A large variation in P concentrations of different plant species was observed. Some vegetable species such as cucumber (Cucumis sativus) and yellow squash (Cucurbita pepo var. melopepo) were identified as potential P accumulators with >1% (dry weight) P in their shoots. These plants also displayed a satisfactory biomass accumulation while growing on a high concentration of soil P. The elevated activities of phosphomonoesterase and phytase were observed when plants were grown in P-enriched soils, this possibly contributing to high P acquisition in these species. Sunflower plants also demonstrated an increased shoot P accumulation. This study shows that the phytoextraction of phosphorus can be effective using appropriate plant species. - Crop plants such as cucumber, squash and sunflower accumulate phosphorus and thus can be used in the phytoextraction of excess phosphorus from soils.

  5. Isolation, screening and partial purification of antimicrobial antibiotics from soil Streptomyces sp. SCA 7

    Directory of Open Access Journals (Sweden)

    P. Saravana Kumar

    2014-09-01

    Full Text Available Thirty-seven actinomycetes strains were isolated from soil samples collected from an agriculture field in Vengodu, Thiruvannamalai District, Tamil Nadu, India (latitude: 12° 54′ 0033″, North; longitude: 79° 78′ 5216″, East; elevation: 228.6/70.0 ft/m. The isolates were assessed for antagonistic activity against five Gram-positive bacteria, seven Gram-negative bacteria, and two pathogenic fungi. During the initial screening, 43% of the strains showed weak activity, 16% showed moderate activity, 5% showed good activity, and 35% showed no antagonistic activity. Among the strains tested, SCA 7 showed strong antimicrobial activity. Maximum biological activity was obtained on modified nutrient glucose agar (MNGA medium. The mycelia of SCA 7 were extracted with methanol and tested against microbial pathogens using the disc diffusion method. The crude extract was purified partially using column chromatography and assessed for antimicrobial activity. Fraction 10 showed good activity against Staphylococcus epidermidis (31.25 μg/mL and Malassezia pachydermatis (500 μg/mL and the active principle (fraction 10 was identified as 2,4-bis (1,1-dimethylethyl phenol. Based on morphological, physiological, biochemical, cultural, and molecular characteristics (16S rDNA sequencing, this strain was identified as Streptomyces sp. SCA 7. It could be used in the development of new substances for pharmaceutical or agricultural purposes.

  6. Effect of soil solarization on soil-borne pathogens

    International Nuclear Information System (INIS)

    Sobh, Hana

    1995-01-01

    Author.Soil solarization was conducted at three locations on the Lebanese coast. Maximum soil temperatures recorded were 53 and 48 celsius degrees at Jiyeh, 48.9, 46 and 43 celsius degrees at Naameh and 48, 45 and 43.5 celsius degrees at Khaldeh at 5, 15 and 25cm soil depths respectively. Mean soil temperatures recorded at 3pm were at Jiyeh 51.6, 47 and 46 celsius degrees compared to Naameh 47, 45 and 41 celsius degrees and Khaldeh 44, 42 and 41 celsius degrees at 5, 15 and 25 cm respectively. The mean temperature in solarized soils were 7.3 to 15 celsius degrees higher than those of the nonsolarized soils indicating a sustained increase of soil temperature in the solarized soils. The effect of soil solarization on artificially introduced fungal pathogens in the soil at Khaldeh, resulted in complete destruction of sclerotia of Sclerotinia spp. at three depths studied. However, with respect to the two other pathogens tested, solarization resulted in reduction of the viability of microsclerotia of Verticillium spp. by 99-79% and of Fusarium oxysporum f. sp. melonis inoculum by 88-54% at 5 and 15 cm respectively, but only by 45% and 14% reduction at 25 cm. This level of control is significant when it is compared to the percentage of control where the level of reduction of inoculum viability did not exceed 10% at any soil depth. As there were contradicting reports in the literature on nematodes, two field trials in greenhouses were conducted to study the possibility of integrating 2 methods for management on nematodes. Soil solarization alone or in combination with biological control of nematodes using Arthrobotrys spp. and Dactyl ella brocophaga to control the root-knot nematodes on two crops, tomato at Naameh and cucumber at Jiyeh were compared to Methyl Bromide treatment. It was evident that, even on a very susceptible crop like cucumber, the integration of biological control and soil solarization gave a good level of control similar to methyl bromide. Neither root

  7. Hysteresis of soil temperature under different soil moisture and ...

    African Journals Online (AJOL)

    ... in a solar greenhouse. The objective of this study was to find a simple method to estimate the hysteresis of soil temperature under three soil moisture and two fertilizer levels in solar greenhouse conditions with tomato crop (Lycopersicon esculentum Mill). The results show that the soil moisture had no significant effects on ...

  8. Lead in residential soil and dust in a mining and smelting district in northern Armenia: a pilot study

    International Nuclear Information System (INIS)

    Petrosyan, Varduhi; Orlova, Anna; Dunlap, Charles E.; Babayan, Emil; Farfel, Mark; Braun, Margrit von

    2004-01-01

    This pilot study of sources of lead exposure in residential settings was conducted in a mining and smelting district in northern Armenia. Samples of exterior soil and dust and interior house dust were collected in and around apartment buildings in Alaverdi where the country's largest polymetallic smelter is located, and in nearby mining towns of Aghtala and Shamlugh. The NITON XL-723 Multi-Element XRF analyzer was used for lead testing. Lead levels in samples from Alaverdi were higher than those in Shamlugh and Aghtala. In all three towns, the highest lead levels were found in loose exterior dust samples, and lead concentrations in yard soil were higher than those in garden soil. Many soil samples (34%) and the majority of loose dust samples (77%) in Alaverdi exceeded the US Environmental Protection Agency standard of 400 mg/kg for bare soil in children's play areas. In addition, 36% of floor dust samples from apartments in Alaverdi exceeded the US Environmental Protection Agency standard of 40 μg/ft 2 for lead loading in residential floor dust. The Armenian Ministry of Health and other interested agencies are being informed about the findings of the study so that they can consider and develop educational and preventive programs including blood lead screening among sensitive populations

  9. Heat impact caused molecular level changes in solid and dissolved soil organic matter

    Science.gov (United States)

    Hofmann, Diana; Steffen, Bernhard; Eckhardt, Kai-Uwe; Leinweber, Peter

    2015-04-01

    resolution (used 400.000 at m/z 400 Da) and mass accuracy (≤ 1 ppm), simultaneously providing molecular level details of thousands of compounds. The characteristics and differences of the FTICR-MS spectra with as many as ten or more peaks at each nominal mass are discussed: heated samples showed considerable higher intensities of even numbered peaks. An in-house developed, automated post processing was used for further exploitation of the data with the aim of an unambiguous assignment of as many peaks as possible. Obtained mass lists were transformed for sorting and preparation/ interpretation of graphics like Kendrick and van Krevelen plots. The heat-treated solid samples show decreasing C/N ratios and the formation cyclic and N-heterocyclic compounds in good agreement among the various methods (Py-FIMS and C- and N-XANES). Detailed insight into the hot-water extracts by FTICR-MS showed clear qualitative as well as quantitative changes in the number and the intensity of nitrogen and nitrogen + sulfur containing compounds, respectively, which generally became enriched under soil heating. This demonstrates for the first time, that not only the bulk SOM is affected in structure by heat impact but also the more mobile DOM. We assume, that heat impact volatilizes and oxidizes parts of the organic substances is as expected but another part of the substances incorporates (further) nitrogen atom(s) similar to the generation of new compounds under the conditions of plasma etching in nitrogen atmosphere. This would explain to some extent, why soils are e.g. after fire clearing of vegetation are highly fertile for a short period (better plant acceptable compounds) but become more infertile in the long run, especially under tropical conditions with frequently heavy rain that would lead to an increased leaching of compounds with higher polarity.

  10. Soil-gas phase transport and structure parameters for soils under different management regimes and at two moisture levels

    DEFF Research Database (Denmark)

    Eden, Marie; Møldrup, Per; Schjønning, Per

    2012-01-01

    Measurements of diffusive and convective gas transport parameters can be used to describe soil functional architecture and reveal key factors for soil structure development. Undisturbed 100-cm(3) soil samples were sampled at the Long-term Research on Agricultural Systems experiment located...... displayed markedly lower D-P/D-0 values at similar air-filled porosity, illustrating soil structure effects on D-P/D-0. The Currie tortuosity-connectivity parameter, X=Log(D-P/D-0)/Log(epsilon), decreased with increasing bulk density in the intact samples at both moisture conditions, suggesting less...

  11. Soil diagnosis of an urban settlement with low levels of anthropogenic pollution (Stepnoe, Saratov region)

    Science.gov (United States)

    Ngun, C. T.; Pleshakova, Ye V.; Reshetnikov, M. V.

    2018-01-01

    A soil diagnosis of an urban territory Stepnoe (Saratov region) was conducted within the framework of soil research monitoring of inhabited localities with low levels of anthropogenic impact using chemical and microbiological analysis. Excess over maximum permissible concentration (MPC) of mobile forms of Cr, Zn and Cd were not observed within the researched territory. A universal excess over MPC of mobile forms of Ni, Cu and Pb was established which is most likely connected with anthropogenic contamination. It was discovered that, at the territory of the Stepnoe settlement, mobile forms of heavy metals compounds (HM) in most cases formed paragenetic associations with high correlation coefficient and despite this, an excess over MPC was not significant. This point to a common mineralogical origin of the elements inherited from the parent rock. The values of the total index of chemical contamination were not above 16, which puts the researched samples in a category with permissible contamination. The indices of the total number of heterotrophic bacteria, iron-oxidizing and hydrocarbon-oxidizing bacteria in most samples corresponded to normal indices for chestnut solonetsous and saline soils. In some samples, a deviation from the normal indices was observed justifying the impact of specific contaminants on the soil.

  12. Earthworm Comet Assay for Assessing the Risk of Weathered Petroleum Hydrocarbon Contaminated Soils: Need to Look Further than Target Contaminants.

    Science.gov (United States)

    Ramadass, Kavitha; Palanisami, Thavamani; Smith, Euan; Mayilswami, Srinithi; Megharaj, Mallavarapu; Naidu, Ravi

    2016-11-01

    Earthworm toxicity assays contribute to ecological risk assessment and consequently standard toxicological endpoints, such as mortality and reproduction, are regularly estimated. These endpoints are not enough to better understand the mechanism of toxic pollutants. We employed an additional endpoint in the earthworm Eisenia andrei to estimate the pollutant-induced stress. In this study, comet assay was used as an additional endpoint to evaluate the genotoxicity of weathered hydrocarbon contaminated soils containing 520 to 1450 mg hydrocarbons kg -1 soil. Results showed that significantly higher DNA damage levels (two to sixfold higher) in earthworms exposed to hydrocarbon impacted soils. Interestingly, hydrocarbons levels in the tested soils were well below site-specific screening guideline values. In order to explore the reasons for observed toxicity, the contaminated soils were leached with rainwater and subjected to earthworm tests, including the comet assay, which showed no DNA damage. Soluble hydrocarbon fractions were not found originally in the soils and hence no hydrocarbons leached out during soil leaching. The soil leachate's Electrical Conductivity (EC) decreased from an average of 1665 ± 147 to 204 ± 20 µS cm -1 . Decreased EC is due to the loss of sodium, magnesium, calcium, and sulphate. The leachate experiment demonstrated that elevated salinity might cause the toxicity and not the weathered hydrocarbons. Soil leaching removed the toxicity, which is substantiated by the comet assay and soil leachate analysis data. The implication is that earthworm comet assay can be included in future eco (geno) toxicology studies to assess accurately the risk of contaminated soils.

  13. The SMAP Level 4 Surface and Root-zone Soil Moisture (L4_SM) Product

    Science.gov (United States)

    Reichle, Rolf; Crow, Wade; Koster, Randal; Kimball, John

    2010-01-01

    The Soil Moisture Active and Passive (SMAP) mission is being developed by NASA for launch in 2013 as one of four first-tier missions recommended by the U.S. National Research Council Committee on Earth Science and Applications from Space in 2007. The primary science objectives of SMAP are to enhance understanding of land surface controls on the water, energy and carbon cycles, and to determine their linkages. Moreover, the high resolution soil moisture mapping provided by SMAP has practical applications in weather and seasonal climate prediction, agriculture, human health, drought and flood decision support. In this paper we describe the assimilation of SMAP observations for the generation of the planned SMAP Level 4 Surface and Root-zone Soil Moisture (L4_SM) product. The SMAP mission makes simultaneous active (radar) and passive (radiometer) measurements in the 1.26-1.43 GHz range (L-band) from a sun-synchronous low-earth orbit. Measurements will be obtained across a 1000 km wide swath using conical scanning at a constant incidence angle (40 deg). The radar resolution varies from 1-3 km over the outer 70% of the swath to about 30 km near the center of the swath. The radiometer resolution is 40 km across the entire swath. The radiometer measurements will allow high-accuracy but coarse resolution (40 km) measurements. The radar measurements will add significantly higher resolution information. The radar is however very sensitive to surface roughness and vegetation structure. The combination of the two measurements allows optimal blending of the advantages of each instrument. SMAP directly observes only surface soil moisture (in the top 5 cm of the soil column). Several of the key applications targeted by SMAP, however, require knowledge of root zone soil moisture (approximately top 1 m of the soil column), which is not directly measured by SMAP. The foremost objective of the SMAP L4_SM product is to fill this gap and provide estimates of root zone soil moisture

  14. Modeling state-level soil carbon emission factors under various scenarios for direct land use change associated with United States biofuel feedstock production

    International Nuclear Information System (INIS)

    Kwon, Ho-Young; Mueller, Steffen; Dunn, Jennifer B.; Wander, Michelle M.

    2013-01-01

    Current estimates of life cycle greenhouse gas emissions of biofuels produced in the US can be improved by refining soil C emission factors (EF; C emissions per land area per year) for direct land use change associated with different biofuel feedstock scenarios. We developed a modeling framework to estimate these EFs at the state-level by utilizing remote sensing data, national statistics databases, and a surrogate model for CENTURY's soil organic C dynamics submodel (SCSOC). We estimated the forward change in soil C concentration within the 0–30 cm depth and computed the associated EFs for the 2011 to 2040 period for croplands, grasslands or pasture/hay, croplands/conservation reserve, and forests that were suited to produce any of four possible biofuel feedstock systems [corn (Zea Mays L)-corn, corn–corn with stover harvest, switchgrass (Panicum virgatum L), and miscanthus (Miscanthus × giganteus Greef et Deuter)]. Our results predict smaller losses or even modest gains in sequestration for corn based systems, particularly on existing croplands, than previous efforts and support assertions that production of perennial grasses will lead to negative emissions in most situations and that conversion of forest or established grasslands to biofuel production would likely produce net emissions. The proposed framework and use of the SCSOC provide transparency and relative simplicity that permit users to easily modify model inputs to inform biofuel feedstock production targets set forth by policy. -- Highlights: ► We model regionalized feedstock-specific United States soil C emission factors. ► We simulate soil C changes from direct land use change associated with biofuel feedstock production. ► Corn, corn-stover, and perennial grass biofuel feedstocks grown in croplands maintain soil C levels. ► Converting grasslands to bioenergy crops risks soil C loss. ► This modeling framework yields more refined soil C emissions than national-level emissions

  15. Soils, surficial geology, and geomorphology of the Bear Creek Valley Low-Level Waste Disposal Development and Demonstration Program site

    International Nuclear Information System (INIS)

    Lietzke, D.A.; Lee, S.Y.; Lambert, R.E.

    1988-04-01

    An intensive soil survey was conducted on the proposed Low-Level Waste Disposal Development and Demonstration Program site (LLWDDD) in Bear Creek Valley. Soils on the site were related to the underlying residuum and to the surficial colluvium and alluvium. Within any particular geologic formation, soils were subdivided based mostly on the degree of weathering, as reflected by saprolite weathering and morphologic features of the soils. Degree of weathering was related both to slope shape and gradient and to the joint-fracture system. Erosion classes were also used to make further subdivisions of any particular soil. Deep pits were dug in each of the major Conasauga Group formations (Pumpkin Valley, Rogersville, Maryville, and Nolichucky) for soil and saprolite characterization. Because of the widespread presence of alluvium and colluvium, which are potential sources of fill and final cover material, pits and trenches were dug to characterize the properties of these soils and to try to understand the past geomorphic history of the site. The results of the soil survey investigation indicated that the deeply weathered Pumpkin Valley residuum has good potential for the construction of tumuli or other types of belowground or aboveground burial of prepackaged compacted waste. 11 refs., 30 figs., 3 tabs

  16. Particle Separation of Non-Decontamination Soil using Attrition and Washing

    International Nuclear Information System (INIS)

    Koo, Daeseo; Sung, Hyun-Hee; Kim, Seung-Soo; Hong, Sang Bum; Seo, Bum Kyoung; Choi, Jong-Won

    2017-01-01

    In this study, to improve the decontamination efficiency of uranium soil, a preliminary experiment on the particle separation of non-decontamination soil was carried out using attrition and washing. The characteristics of the attrition and washing system are investigated. A conditional experiment on particle separation of non-decontamination soil will be performed. A preliminary experiment on the particle separation of non-decontamination soil was carried out to improve the decontamination efficiency of uranium soil. This experiment was performed with the ratio of soil to water (1:4) for the particle separation of non-decontamination soil. The operations of all equipment such as attrition scrubber, ultrasonic reaction, vibrating screen, and hydro-cyclone were conducted and confirmed. In the future, the additional experiments will be conducted for optimal experimental condition.

  17. Nuclide, metal and non metal levels in percolated water from soils fertilized with phosphogypsum

    International Nuclear Information System (INIS)

    Silva, Camilla Bof; Knupp, Eliana Aparecida Nonato; Palmieri, Helena E.L.; Jacomino, Vanusa Maria Feliciano; Taddei, Maria Helena; Ciqueira, Maria Celia

    2009-01-01

    Systematic generation of residues is more and more worrying in today.s world; adequate storage and reutilization are of great importance. Since generation of residues has become impossible to avoid, the possibility of reuse must be studied and researched. An example of these residues is phosphogypsum, which is generated in phosphoric acid production at the rate of around 4.8 tons for each ton of phosphoric acid produced. Many studies seek to reuse phosphogypsum in agriculture as a source of calcium and sulfur, potassium or aluminum, especially in soils from Brazil's cerrado regions. Though phosphogypsum is mainly composed of dehydrated calcium sulfate, it can have high levels of heavy metals, non metals (As and Se), fluorides and natural radionuclides. Thus, its uncontrolled use as a soil conditioner can lead to contamination of underground water. (author)

  18. Interactions of low-level, liquid radioactive wastes with soils. 1. Behavior of radionuclides in soil-waste systems

    International Nuclear Information System (INIS)

    Fowler, E.B.; Essington, E.H.; Polzer, W.L.

    1981-01-01

    The characteristics of radioactive wastes and soils vary over a wide range. Liquid radioactive waste entering the environment will eventually contact the soil or geological matrix; interactions will be determined by the chemical and physical nature of the liquid, as well as the soil matrix. We report here the results from an investigation of certain of those characteristics as they relate to retention of radionuclides by soils. Three fractions were demonstrated in the waste as filterable, soluble-sorbable, and soluble-nonsorbable; the physical nature of each fraction was demonstrated using autoradiographic techniques. Isotopes of plutonium and uranium and americium-241 in the soluble fraction of the waste were shown to have a negative charge as determined by ion exchange techniques. In the soil-waste systems, the net charge for those radionuclides was shown to change from predominantly negative to predominantly positive. Nevertheless, cesium-137 was shown to be predominantly positited by TVA and approved by NRC (formerly AEC) since June 1973. This report is based upon the revisions, approved through the end of this reporting period

  19. The assumption of heterogeneous or homogeneous radioactive contamination in soil/sediment: does it matter in terms of the external exposure of fauna?

    International Nuclear Information System (INIS)

    Beaugelin-Seiller, K.

    2014-01-01

    The classical approach to environmental radioprotection is based on the assumption of homogeneously contaminated media. However, in soils and sediments there may be a significant variation of radioactivity with depth. The effect of this heterogeneity was investigated by examining the external exposure of various sediment and soil organisms, and determining the resulting dose rates, assuming a realistic combination of locations and radionuclides. The results were dependent on the exposure situation, i.e., the organism, its location, and the quality and quantity of radionuclides. The dose rates ranged over three orders of magnitude. The assumption of homogeneous contamination was not consistently conservative (if associated with a level of radioactivity averaged over the full thickness of soil or sediment that was sampled). Dose assessment for screening purposes requires consideration of the highest activity concentration measured in a soil/sediment that is considered to be homogeneously contaminated. A more refined assessment (e.g., higher tier of a graded approach) should take into consideration a more realistic contamination profile, and apply different dosimetric approaches. - Highlights: • Defining contamination as homogeneous may not be conservative for dose assessment. • The impact of source heterogeneity on dose is closely linked to the exposure scenario. • Dosimetric calculations (method and tool) should differ from screening to higher tiers

  20. Polybrominated Diphenyl Ethers (PBDEs) in Surface Soils across Five Asian Countries: Levels, Spatial Distribution, and Source Contribution.

    Science.gov (United States)

    Li, Wen-Long; Ma, Wan-Li; Jia, Hong-Liang; Hong, Wen-Jun; Moon, Hyo-Bang; Nakata, Haruhiko; Minh, Nguyen Hung; Sinha, Ravindra Kumar; Chi, Kai Hsien; Kannan, Kurunthachalam; Sverko, Ed; Li, Yi-Fan

    2016-12-06

    A total of 23 polybrominated diphenyl ether (PBDE) congeners were measured in soil samples collected in areas with no known point source [urban/rural/background (U/R/B) sites] and in areas with known point source [brominated flame retardant (BFR)-related industrial sites (F sites) and e-waste recycling sites (E sites)] across five Asian countries. The highest PBDE concentrations were found in BFR-related industrial and e-waste recycling sites. The concentrations of PBDEs in U/R/B sites decreased in the following order: urban > rural > background sites. Total PBDE concentrations were dominated by BDE-209, while BDE-17, -85, -138, -191, -204, and -205 were the least abundant compounds. In both urban sites and rural sites, the mean concentrations of total PBDEs (∑ 23 BDEs) in soils decreased in the following order: Japan > China > South Korea > India > Vietnam. The concentrations of PBDEs in soils were comparable with those reported in other studies. Among the three commercial PBDE mixtures, relatively large contributions of commercial penta-BDE were observed in Vietnam, whereas deca-BDE was the dominant form in mixtures contributing from 55.8 ± 2.5 to 100.0 ± 1.2% of the total PBDEs in soils collected from other four countries. Regression analysis suggested that local population density (PD) is a good indicator of PBDEs in soils of each country. Significant and positive correlation between soil organic content and PBDE level was observed in Chinese soil for most nondeca-BDE homologues with their usage stopped 10 years ago, indicating its important role in controlling the revolatilization of PBDEs from soil and changing the spatial trend of PBDE in soil from the primary distribution pattern to the secondary distribution pattern, especially when primary emission is ceased.

  1. Effects of manure and mineral fertilization strategies on soil antibiotic resistance gene levels and microbial community in a paddy–upland rotation system

    International Nuclear Information System (INIS)

    Lin, Hui; Sun, Wanchun; Zhang, Zulin; Chapman, Stephen J.; Freitag, Thomas E.; Fu, Jianrong; Zhang, Xin; Ma, Junwei

    2016-01-01

    This work investigated the responses of antibiotic resistance genes (ARGs) and the soil microbial community in a paddy–upland rotation system to mineral fertilizer (NPK) and different application dosages of manure combined with NPK. The occurrence of five tetracycline ARGs (tetA, tetB, tetC, tetG and tetW), two sulfonamide ARGs (sul1 and sul2) and one genetic element (IntI1) was quantified. NPK application showed only slight or no impact on soil ARGs abundances compared with the control without fertilizer. Soil ARGs abundances could be increased by manure-NPK application but was related to manure dosage (2250–9000 kg ha"−"1). Principal component analysis (PCA) showed that the soil ARG profile of the treatment with 9000 kg ha"−"1 manure separated clearly from the other treatments; the ARGs that contributed most to the discrimination of this treatment were tetA, tetG, tetW, sul1, sul2 and IntI1. Community level physiological profile (CLPP) analysis showed that increasing manure dosage from 4500 kg ha"−"1 to 9000 kg ha"−"1 induced a sharp increase in almost all of the detected ARGs but would not change the microbial community at large. However, 9000 kg ha"−"1 manure application produced a decline in soil microbial activity. Determination of antibiotics and heavy metals in soils suggested that the observed bloom of soil ARGs might associate closely with the accumulation of copper and zinc in soil. - Highlights: • The occurrence of ten ARGs in a manure and a paddy soil from China was tested. • The fate of ARGs in soil varied between ARG types and fertilization strategies. • The increase in soil ARG caused by manure-NPK fertilization was manure dosage-related. • Excessive manure greatly increased soil ARGs and inhibited soil microbial activity. • Cu and Zn levels in soils associated closely with the observed soil ARGs bloom. - The elevation of soil ARGs abundances in soil caused by manure application combined with NPK in a paddy

  2. SOIL WASHING TREATABILITY TESTS FOR PESTICIDE- CONTAMINATED SOIL

    Science.gov (United States)

    The 1987 Sand Creek Operable Unit 5 record of decision (ROD) identified soil washing as the selected technology to remediate soils contaminated with high levels of organochlorine pesticides, herbicides, and metals. Initial treatability tests conducted to assess the applicability...

  3. Bioaccessibility and Human Exposure Assessment of Cadmium and Arsenic in Pakchoi Genotypes Grown in Co-Contaminated Soils.

    Science.gov (United States)

    Wei, Yanyan; Zheng, Xiaoman; Shohag, Md Jahidul Islam; Gu, Minghua

    2017-08-29

    In many countries cadmium (Cd) and arsenic (As) commonly coexist in soils contaminated by mining activities, and can easily enter the human body via consumption of leafy vegetables, like the popularly consumed pakchoi ( Brassica chinensis L.), causing major health concerns. In the present study, bioaccessibility and human exposure of Cd and As were assessed in twenty genotypes of pakchoi cultured at two different levels of co-contamination to identify low health risk genotypes. The bioaccessibilities of Cd and As represent a fraction of the total metals content could be bioaccessible for human, in the present study, significant differences in pakchoi Cd and As bioaccessibility were observed among all tested genotypes and co-contaminated levels. Cd and As bioaccessibility of pakchoi were in the ranges of 24.0-87.6% and 20.1-82.5%, respectively, for in the high level co-contaminated soils, which was significantly higher than for low level co-contaminated soils with 7.9-71.8% for Cd bioaccessibility and 16.1-59.0% for As bioaccessibility. The values of bioaccessible established daily intakes (BEDI) and the total bioaccessible target hazard quotients (TBTHQ) of Cd and As were also considerably higher in high level co-contaminated soils than in low level co-contaminated soils. Two genotypes (Meiguanqinggengcai and Zhenqing60F1) contained relatively low concentrations and bioaccessible Cd and As and, their BEDI and TBTHQ for Cd and As ranged below the tolerable limits set by the FAO/WHO (BEDI of Cd < 0.83 μg kg -1 bw day -1 , BEDI of As < 3 μg kg -1 bw day -1 ) and United States Environmental Protection Agency (TBTHQ for Cd and As < 1), this applied for both levels of co-contaminated soils for adults and children. Consequently, these findings suggest identification of safe genotypes in leafy vegetable with low health risk via genotypic screening and breeding methods could be a useful strategy to ensure the safety of food crops grown in those Cd and As co

  4. Subtask 1.11 - Spectroscopic field screening of hazardous waste and toxic spills. Final report

    International Nuclear Information System (INIS)

    Grisanti, A.A.

    1997-10-01

    Techniques for the field characterization of soil contamination due to spillage of hazardous waste or toxic chemicals are time-consuming and expensive. Thus more economical, less time-intensive methods are needed to facilitate rapid field screening of contaminated sites. The overall objective of this project is to study the feasibility of using an evanescent field absorbance sensor Fourier transform infrared spectroscopic sensor coupled with cone penetrometry as a field screening method. The specific objectives of this project are as follows: design an accessory for use with FT-IR that interfaces the spectrometer to a cone penetrometer; characterize the response of the FT-IR accessory to selected hydrocarbons in a laboratory-simulated field environment; and determine the ability of the FT-IR-CPT instrument to measure hydrocarbon contamination in soil by direct comparison with a reference method (e.g., Soxhlet extraction followed by gas chromatography) to quantify hydrocarbons from the same soil

  5. An efficient method for qualitative screening of phosphate-solubilizing bacteria.

    Science.gov (United States)

    Mehta, S; Nautiyal, C S

    2001-07-01

    An efficient protocol was developed for qualitative screening of phosphate-solubilizing bacteria, based upon visual observation. Our results indicate that, by using our formulation containing bromophenol blue, it is possible to quickly screen on a qualitative basis the phosphate-solubilizing bacteria. Qualitative analysis of the phosphate solubilized by various groups correlated well with grouping based upon quantitative analysis of bacteria isolated from soil, effect of carbon, nitrogen, salts, and phosphate solubilization-defective transposon mutants. However, unlike quantitative analysis methods that involve time-consuming biochemical procedures, the time for screening phosphate-solubilizing bacteria is significantly reduced by using our simple protocol. Therefore, it is envisaged that usage of this formulation based upon qualitative analysis will be salutary for the quick screening of phosphate-solubilizing bacteria. Our results indicate that the formulation can also be used as a quality control test for expeditiously screening the commercial bioinoculant preparations, based on phosphate solubilizers.

  6. Allowable Residual Contamination Levels in soil for decommissioning the Shippingport Atomic Power Station site

    International Nuclear Information System (INIS)

    Kennedy, W.E. Jr.; Napier, B.A.; Soldat, J.K.

    1983-09-01

    As part of decommissioning the Shippingport Atomic Power Station, a fundamental concern is the determination of Allowable Residual Contamination Levels (ARCL) for radionuclides in the soil at the site. The ARCL method described in this report is based on a scenario/exposure-pathway analysis and compliance with an annual dose limit for unrestricted use of the land after decommissioning. In addition to naturally occurring radionuclides and fallout from weapons testing, soil contamination could potentially come from five other sources. These include operation of the Shippingport Station as a pressurized water reactor, operations of the Shippingport Station as a light-water breeder, operation of the nearby Beaver Valley reactors, releases during decommissioning, and operation of other nearby industries, including the Bruce-Mansfield coal-fired power plants. ARCL values are presented for 29 individual radionculides and a worksheet is provided so that ARCL values can be determined for any mixture of the individual radionuclides for any annual dose limit selected. In addition, a worksheet is provided for calculating present time soil concentration value that will decay to the ARCL values after any selected period of time, such as would occur during a period of restricted access. The ARCL results are presented for both unconfined (surface) and confined (subsurface) soil contamination. The ARCL method and results described in this report provide a flexible means of determining unrestricted-use site release conditions after decommissioning the Shippingport Atomic Power Station

  7. Evaluation of TSH Levels in the Program of Congenital Hypothyroidism Newborn Screening in a Pilot Study of Preterm Newborns in Bogotá, Colombia

    Directory of Open Access Journals (Sweden)

    Gustavo Adolfo Giraldo

    2015-07-01

    Full Text Available Introduction: Preterm infants (<37 weeks of gestation have low levels of thyroid hormones due to multiple factors. Objective: To evaluate levels of thyroid-stimulation hormone (TSH in the program congenital hypothyroidism (CH newborn screening in a sample of preterm infants in the city of Bogotá, Colombia. Methods: The Secretaría de Salud Distrital screening protocol for CH (blood sample is collected from the umbilical cord in all the newborns remeasured the serum TSH and heel TSH when preterm infants completed 37 weeks of gestation. Results: A total of 59 preterm neonates were rescreened, of which 2 neonates had elevated levels of TSH and 1 neonate had transient hypothyroxinemia. The Kolmogorov-Smirnov 2-sample/bilateral statistical test was used to compare the neonatal TSH levels of preterm and full-term newborns, which do not follow the same distribution. Conclusion: In our pilot study, 2 of the rescreened infants presented high levels of TSH and 1 had transient hyperthyrotropinemia, suggesting the need for rescreening of preterm infants. Additionally, a larger study should be performed to determine the screening cutoff values for preterm newborns.

  8. On the assimilation of satellite derived soil moisture in numerical weather prediction models

    Science.gov (United States)

    Drusch, M.

    2006-12-01

    Satellite derived surface soil moisture data sets are readily available and have been used successfully in hydrological applications. In many operational numerical weather prediction systems the initial soil moisture conditions are analysed from the modelled background and 2 m temperature and relative humidity. This approach has proven its efficiency to improve surface latent and sensible heat fluxes and consequently the forecast on large geographical domains. However, since soil moisture is not always related to screen level variables, model errors and uncertainties in the forcing data can accumulate in root zone soil moisture. Remotely sensed surface soil moisture is directly linked to the model's uppermost soil layer and therefore is a stronger constraint for the soil moisture analysis. Three data assimilation experiments with the Integrated Forecast System (IFS) of the European Centre for Medium-range Weather Forecasts (ECMWF) have been performed for the two months period of June and July 2002: A control run based on the operational soil moisture analysis, an open loop run with freely evolving soil moisture, and an experimental run incorporating bias corrected TMI (TRMM Microwave Imager) derived soil moisture over the southern United States through a nudging scheme using 6-hourly departures. Apart from the soil moisture analysis, the system setup reflects the operational forecast configuration including the atmospheric 4D-Var analysis. Soil moisture analysed in the nudging experiment is the most accurate estimate when compared against in-situ observations from the Oklahoma Mesonet. The corresponding forecast for 2 m temperature and relative humidity is almost as accurate as in the control experiment. Furthermore, it is shown that the soil moisture analysis influences local weather parameters including the planetary boundary layer height and cloud coverage. The transferability of the results to other satellite derived soil moisture data sets will be discussed.

  9. Simulation of Zinc Release Affected by Microbial Inoculation and Salinity Levels in a non-sterile Calcareous Soil Using kinetic Models

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    hamidreza boostani

    2017-02-01

    Full Text Available Introduction: Zinc (Zn is an important nutrient element for humans and plants that controls many biochemical and physiological functions of living organisms. Zinc deficiency is common in high pH, low organic matter, carbonatic, saline and sodic soils. Salinity is a major abiotic environmental stresses that limits growth and production in arid and semi-arid regions of the world. Bioavailability of Zn is low in calcareous and saline soils having high levels of pH and calcium. Desorption of Zinc (Zn from soil as influenced by biological activities is one of the important factors that control Zn bioavailability. Few reports on the effects of salinity on the availability and desorption kinetics of Zn are available. Rupa et al. (2000 reported that increasing the salt concentration led to increase Zn desorption from soil due to ion competition on soil exchangeable sites. Different kinetic equations have been used to describe the release kinetics of nutrients. Reyhanitabar and Gilkes (2010 found that the power function model was the best equation to describe the release of Zn from some calcareous soil of Iran, whereas Baranimotlagh and Gholami (2013 stated that the best model for describing Zn desorption from 15 calcareous soils of Iran was the first-order equation.less attention has been paid to kinetics of Zn release by DTPA extractant over time by inoculation of plant growth promoting rhizobacteria and mycorrhizae fungi in comination with soil salinity.The objective of this study was to evaluate the effect of plant growth promoting rhizobacteria (PGPR and mycorrhizae fungi (MF inoculation on release kinetic of Zn in a calcareous soil at different salinity levels after in cornplantation Materials and Methods: A composite sample of bulk soil from the surface horizon (0-30 cm of a calcareous soil from southern part of Iran was collected, air dried, passed through 2 mm sieve, and thoroughly mixed. Routine soil analysis was performed to determine some

  10. A soil mechanics approach to study soil compaction and traffic effect on the preconsolidation pressure of tropical soils

    International Nuclear Information System (INIS)

    Dias Junior, Moacir de Souza

    2004-01-01

    Several researchers have already demonstrated the causes and the effects of soil compaction. These studies showed that the soil compaction is a limiting factor in the agricultural production. The attributes of the soil conventionally monitored has not been capable to quantify the load support capacity of the soil, not allowing to foresee the levels of pressures that can be applied to the soils at different moisture conditions without additional soil compaction (structure degradation) happens. The researches done in the soil compressive behaviour of some tropical soils indicate that the pre-compression stress may be used as an alternative measure of the load support capacity and as a quantitative indicator of the structure sustainability of the tropical soils

  11. Factors Influencing Colorectal Cancer Screening Participation

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    Antonio Z. Gimeno García

    2012-01-01

    Full Text Available Colorectal cancer (CRC is a major health problem worldwide. Although population-based CRC screening is strongly recommended in average-risk population, compliance rates are still far from the desirable rates. High levels of screening uptake are necessary for the success of any screening program. Therefore, the investigation of factors influencing participation is crucial prior to design and launches a population-based organized screening campaign. Several studies have identified screening behaviour factors related to potential participants, providers, or health care system. These influencing factors can also be classified in non-modifiable (i.e., demographic factors, education, health insurance, or income and modifiable factors (i.e., knowledge about CRC and screening, patient and provider attitudes or structural barriers for screening. Modifiable determinants are of great interest as they are plausible targets for interventions. Interventions at different levels (patient, providers or health care system have been tested across the studies with different results. This paper analyzes factors related to CRC screening behaviour and potential interventions designed to improve screening uptake.

  12. Functional and community-level soil microbial responses to zinc addition may depend on test system biocomplexity.

    Science.gov (United States)

    Sverdrup, Line E; Linjordet, Roar; Strømman, Gjermund; Hagen, Snorre B; van Gestel, Cornelis A M; Frostegård, Sa; Sørheim, Roald

    2006-12-01

    The effect of zinc on soil nitrification and composition of the microbial community in soil was investigated using a full factorial experiment with five zinc concentrations and four levels of biological complexity (microbes only, microbes and earthworms (Eisenia fetida), microbes and Italian ryegrass (Lolium multiflorum var. Macho), and microbes, ryegrass and earthworms). After 6 weeks of exposure, the activity of soil nitrifying bacteria was measured and the microbial community structure was characterized by phospholipid fatty acid (PLFA) analysis. Soil nitrification and several PLFA markers were significantly influenced by either zinc addition and/or the presence of earthworms or ryegrass, and one of the most pronounced changes was the increase of fungi and decrease of bacteria with increasing concentrations of zinc. Of particular interest, however, was the potential interaction between the presence of plants and/or earthworms and the effect of zinc, which the factorial study design allowed us to explore. Such an effect was observed in two cases: Earthworms reduced the positive effect of zinc on the fungal biomass (ANOVA, p=0.03), and the effect of earthworms on the soil nitrification activity depended on zinc concentration (ANOVA, p<0.05). The effect of earthworm presence was not very large, but it does show that multispecies tests might give information about metal toxicity or bioavailability that cannot be predicted from single-species tests.

  13. Effect of gentamicin and levels of ambient sound on hearing screening outcomes in the neonatal intensive care unit: A pilot study.

    Science.gov (United States)

    Garinis, Angela C; Liao, Selena; Cross, Campbell P; Galati, Johnathan; Middaugh, Jessica L; Mace, Jess C; Wood, Anna-Marie; McEvoy, Lindsey; Moneta, Lauren; Lubianski, Troy; Coopersmith, Noe; Vigo, Nicholas; Hart, Christopher; Riddle, Artur; Ettinger, Olivia; Nold, Casey; Durham, Heather; MacArthur, Carol; McEvoy, Cynthia; Steyger, Peter S

    2017-06-01

    Hearing loss rates in infants admitted to neonatal intensive care units (NICU) run at 2-15%, compared to 0.3% in full-term births. The etiology of this difference remains poorly understood. We examined whether the level of ambient sound and/or cumulative gentamicin (an aminoglycoside) exposure affect NICU hearing screening results, as either exposure can cause acquired, permanent hearing loss. We hypothesized that higher levels of ambient sound in the NICU, and/or gentamicin dosing, increase the risk of referral on the distortion product otoacoustic emission (DPOAE) assessments and/or automated auditory brainstem response (AABR) screens. This was a prospective pilot outcomes study of 82 infants (4172 Hz) was 44%. DPOAE referrals were significantly greater for infants receiving >2 days of gentamicin dosing compared to fewer doses (p = 0.004). The effect of sound exposure and gentamicin treatment on hearing could not be determined due to the low number of NICU infants without gentamicin exposure (for control comparisons). All infants were exposed to higher levels of ambient sound that substantially exceed AAP guidelines. More referrals were generated by DPOAE assessments than with AABR screens, with significantly more DPOAE referrals with a high-frequency F2 range, consistent with sound- and/or gentamicin-induced cochlear dysfunction. Adding higher frequency DPOAE assessments to existing NICU hearing screening protocols could better identify infants at-risk for ototoxicity. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. Radioactivity in Soil Samples Collected in Southern Serbia

    International Nuclear Information System (INIS)

    Jankovic, M.; Nikolic, J.; Pantelic, G.; Rajacic, M.; Sarap, N.; Todorovic, D.

    2013-01-01

    In the attack on the Federal Republic of Yugoslavia (the focus effect was of Kosovo and Metohija and southern Serbia) in 1999, NATO forces used ammunition containing depleted uranium. Cleaning action of depleted uranium was performed by Radiation and Environmental Protection Department of the Vinca Institute of Nuclear Science, during 2002?2007 at locations: Pljackovica, Bratoselce, Borovac and Reljan. At all locations underwent detailed dosimetric screening and decontamination was performed. Because of the loose soil, DU projectils were found to a depth of 1 m. Found missiles, contaminated soil and radioactive material has been collected and stored on radioactive waste. After cleaning the ground is leveled and another dosimetric prospecting was performed. Monitoring of radioactivity in southern Serbia included determination of gamma emitters as well as determination of gross alpha and beta activities in soil, water and plant. Sampling was carried out at Pljackovica, Borovac, Bratoselce and Reljan in July 2011. This paper presents only the results of measurement of gamma emitters in soil samples and showed the presence of natural radionuclides: 226Ra, 232Th, 40K, 235U, 238U and the produced radionuclide 137Cs (from the Chernobyl accident). Also, the ratio between the 235U and 238U is given. In order to evaluate the radiological hazard of the natural radioactivity, the radium equivalent activity, the gamma-absorbed dose rate and the external hazard index have been calculated. (author)

  15. Measurement of radiation levels in soil samples by γ-ray spectrometry

    International Nuclear Information System (INIS)

    Sontakke, C.V.; Thamke, A.N.; Devika, K.; Srikanth, S.; Jayachandran, N.; Chander, Harish

    2016-01-01

    The natural terrestrial gamma radiation dose rate is an important contribution to the average dose rate received by the world's population. Estimation of the radiation dose distribution is important in assessing the health risk to a population and serve as the reference in documenting changes to environmental radioactivity in soil due to anthropogenic activities. Human beings are exposed outdoors to the natural terrestrial radiation that originates predominantly from the upper 30 cm of the soil. Only radionuclides with half-lives comparable with the age of the earth or their corresponding decay products existing in terrestrial material such as 238 U, 232 Th and 40 K are of great interest. Since these radionuclides are not uniformly distributed, the knowledge of their distribution in soil and rock play an important role in radiation protection and measurement. Gamma radiation from these represents the main external source of irradiation to the human body and the concentrations of these radionuclides in soil are determined by the radioactivity of the rock and also nature of the process of the formation of the soils. Therefore, radionuclides in soil generate a significant component of the background radiation exposure to the population

  16. Correlation of indoor radon levels with physical properties of local soil in Khammam district, Andhra Pradesh, India

    International Nuclear Information System (INIS)

    Sreenivasa Reddy, B.; Bhaskar Reddy, G.; Sreenath Reddy, M.; Gopal Reddy, Ch; Yadagiri Reddy, P.; Rama Reddy, K.

    2006-01-01

    Indoor radon contributes significantly to the total radiation exposure caused to human beings. As might be expected, the physical characteristics of soil play key roles in determining the radon concentration in nearby buildings. The physical characteristics of soil, such as density, specific gravity and porosity in the vicinity of the dwellings of Khammam district, Andhra Pradesh, India, have been determined using core cutter and specific gravity bottle. In the present paper, these parameters are correlated with the average indoor radon levels estimated for a year using solid state nuclear track detectors. (author)

  17. Comparing the Ability of Conventional and Digital Soil Maps to Explain Soil Variability using Diversity Indices

    Directory of Open Access Journals (Sweden)

    zohreh mosleh

    2017-06-01

    Chaharmahal-Va- Bakhtiari province. Materials and Methods: The soils in the study area have been formed on Quaternary shale and foliated clayey limestone deposits. Irrigated crops such as wheat, barley and alfalfa are the main land uses in the area. According to the semi-detailed soil survey, 120 pedons with approximate distance of 750 m were excavated and described according to the “field book for describing and sampling soils”. Soil samples were taken from different genetic horizons and soil physicochemical properties were determined. Based on the pedons description and soil analytical data, pedons were classified according to the Soil Taxonomy (ST up to subgroup level. Using aerial photo interpretation, geology map, google earth image and field observations primary soil map was created. With considering the taxonomic level, the representative pedons were determined and soil map was prepared. Multinomial logistic regression was used to predict soil classes at great group and subgroup levels. The map units that have the highest frequency were selected as indicator to calculate diversity indices in the conventional soil map at each taxonomic level. The selected map units were overlay to digital soil map and further diversity indices were calculated. Diversity indices including the Shannon’s diversity, evenness and richness index. In order to know whether the means of Shannon’s diversity for two approaches are significantly different, means comparison was done. Results and Discussion: The results confirmed that the Shannon's diversity index was higher in the digital soil map than the conventional soil map for most soil map units. At great group and subgroup levels, a significant difference was observed for the Shannon's diversity index at 0.05 and 0.001 probability levels, respectively. Comparing the conventional and the digital soil maps showed the numbers of soil map units with significant difference regarding the Shannon's diversity index decreased from great group

  18. Soil degradation in Pakistan

    International Nuclear Information System (INIS)

    Khan, M.R.

    2005-01-01

    This paper diagnoses the issues involved behind the current state, usage, interactions and linkages in the soils in Pakistan. The condition of soils is deteriorating due to developmental and environmental factors such as soil degradation, water pollution, fauna degeneration etc. Issues, problems and constraints faced in the management and usage of soils are diagnosed at different levels in the ecosystems predominant in Pakistan. The research questions propose effective solutions, types of instruments, methods or processes to resolve the issues within the various areas or ecosystems in the most sustainable and effective manner [23]. Biological solutions and methods can be applied at the sub-system level by private individuals or communities at a lower cost, and at a more localized level than engineering methods. Engineering methods may be suited for interventions at a system level rather than at a sub-system level; but even at this level they will be complementary with biological methods. (author)

  19. Radionuclide Concentrations in Soils and Vegetation at Low-Level Radioactive Waste Disposal Area G during the 1997 Growing Season

    Energy Technology Data Exchange (ETDEWEB)

    L. Naranjo, Jr.; P. R. Fresquez; R. J. Wechsler

    1998-08-01

    Soil and overstory and understory vegetation (washed and unwashed) collected at eight locations within and around Area G-a low-level radioactive solid-waste disposal facility at Los Alamos National Laboratory-were analyzed for 3H, 238Pu, 239Pu, 137CS, 234U, 235U, 228AC, Be, 214Bi, 60Co, 40& 54Mn, 22Na, 214Pb and 208Tl. In general, most radionuclide concentrations, with the exception of 3Ef and ~9Pu, in soils and overstory and understory vegetation collected from within and around Area G were within upper (95'%) level background concentrations. Although 3H concentrations in vegetation from most sites were significantly higher than background (>2 pCi mL-l), concentrations decreased markedly in comparison to last year's results. The highest `H concentration in vegetation was detected from a juniper tree that was growing over tritium shaft /+150; it contained 530,000 pCi 3H mL-l. Also, as in the pas~ the transuranic waste pad area contained the highest levels of 239Pu in soils and in understory vegetation as compared to other areas at Area G.

  20. Plant species richness sustains higher trophic levels of soil nematode communities after consecutive environmental perturbations.

    Science.gov (United States)

    Cesarz, Simone; Ciobanu, Marcel; Wright, Alexandra J; Ebeling, Anne; Vogel, Anja; Weisser, Wolfgang W; Eisenhauer, Nico

    2017-07-01

    The magnitude and frequency of extreme weather events are predicted to increase in the future due to ongoing climate change. In particular, floods and droughts resulting from climate change are thought to alter the ecosystem functions and stability. However, knowledge of the effects of these weather events on soil fauna is scarce, although they are key towards functioning of terrestrial ecosystems. Plant species richness has been shown to affect the stability of ecosystem functions and food webs. Here, we used the occurrence of a natural flood in a biodiversity grassland experiment that was followed by a simulated summer drought experiment, to investigate the interactive effects of plant species richness, a natural flood, and a subsequent summer drought on nematode communities. Three and five months after the natural flooding, effects of flooding severity were still detectable in the belowground system. We found that flooding severity decreased soil nematode food-web structure (loss of K-strategists) and the abundance of plant feeding nematodes. However, high plant species richness maintained higher diversity and abundance of higher trophic levels compared to monocultures throughout the flood. The subsequent summer drought seemed to be of lower importance but reversed negative flooding effects in some cases. This probably occurred because the studied grassland system is well adapted to drought, or because drought conditions alleviated the negative impact of long-term soil waterlogging. Using soil nematodes as indicator taxa, this study suggests that high plant species richness can maintain soil food web complexity after consecutive environmental perturbations.