WorldWideScience

Sample records for small water shift

  1. Metal balance shift induced in small fresh water fish by several environmental stresses

    International Nuclear Information System (INIS)

    Yukawa, Masae; Iso, Hiroyuki; Kodama, Kumiko; Imaseki, Hitoshi; Aoki, Kazuko; Ishikawa, Yuji

    2005-01-01

    Balance of essential elements in organisms might be changed by environmental stresses. Small fresh water fish, Medaka, was burdened with X-ray irradiation (total dose: 17 Gy), keeping in salty water (70% NaCl of sea water) and keeping in metal containing water (10 ppm of Cr and Co). These stresses are not lethal doses. Essential elements in liver, gall bladder, kidney, spleen, heart and brain in the stress-loaded fish were measured by PIXE method and compared with a control fish to determine the effect of the stresses. Various changes of the elemental contents were observed. Effect of X-ray irradiation was the smallest among the stresses. Relatively high content elements such as P, S, Cl and K were hardly affected with the stresses examined in this work. The effect of Cr on the metal balance seems to be larger than the other stresses. As PIXE method can analyze many elements in a small sample simultaneously, change of elemental distribution in small organisms induced by environmental stresses can be determined readily. (author)

  2. Determination of metal balance shift induced in small fresh water fish by X-ray irradiation using PIXE analysis

    International Nuclear Information System (INIS)

    Yukawa, M.; Aoki, K.; Iso, H.; Kodama, K.; Imaseki, H.; Ishikawa, Y.

    2005-01-01

    In the environmental pollution studies, it is very important to detect not only pollutants but also changes induced in organisms in the environment with various environmental stresses such as heavy metal toxicity radiation and agricultural chemicals. In the latter, monitoring is carried out using biological indicators to find out the changes, which have wide spectra from visible like deformity of the body to invisible such as changes in some enzyme activities. Changes of the balance of essential elements could occur in organisms to deal with the stresses. If we detect an elemental balance shift, we may see the environmental pollution in its early stages. Moreover, in the actual environment, combined effects, additive or reductive with coexistent elements or other stresses, is an important subject for investigation. Therefore, measurement of many elements in the biological indicator's simultaneously and determination of the distribution in the organisms are useful in clarifying the action of pollutants at sublethal levels. A small fresh water fish, Medaka can be used as one of the biological-indicators for determination of water quality. In the National Institute of Radiological Sciences (NIRS), an inbred strain of Medaka Orizias laptipes was established and has been maintained for the research purposes. Since the genetic background of inbred animals is almost uniform, the individual deviation among animals is very small. This characteristic is very useful to investigate the physiological effects of environmental stresses. We have continued to investigate the balance shift of essential elements induced in the bodies of Medaka by several stresses. In this paper, elemental content in various organs of the X-ray irradiated fish determined by PIXE method are reported in comparison with that of the control fish to observe the effect of the X-rays. Body size of Medaka is about 3 cm long, and the internal organs are very small (about l mm on average). PIXE is the most

  3. Water Loss in Small Settlements

    OpenAIRE

    Mindaugas Rimeika; Anželika Jurkienė

    2014-01-01

    The main performance indicators of a water supply system include the quality and safety of water, continuous work, relevant pressure and small water loss. The majority of foreign and local projects on reducing water loss have been carried out in the water supply systems of metropolitans; however, the specificity of small settlements differs from that of big cities. Differences can be observed not only in the development of infrastructure and technical indicators but also in the features of wa...

  4. Effect of algae and water on water color shift

    Science.gov (United States)

    Yang, Shengguang; Xia, Daying; Yang, Xiaolong; Zhao, Jun

    1991-03-01

    This study showed that the combined effect of absorption of planktonic algae and water on water color shift can be simulated approximately by the exponential function: Log( E {100cm/ W }+ E {100cm/ Xch1})=0.002λ-2.5 where E {100/cm W }, E {100cm/ Xchl} are, respectively, extinction coefficients of seawater and chlorophyll—a (concentration is equal to X mg/m3), and λ (nm) is wavelength. This empirical regression equation is very useful for forecasting the relation between water color and biomass in water not affected by terrigenous material. The main factor affecting water color shift in the ocean should be the absorption of blue light by planktonic algae.

  5. Urban Waters Small Grants 101

    Science.gov (United States)

    General information on Urban Waters Small Grants is provided in this document. Grantees are listed by themes, including Environmental Justice, Water Quality, Job Training and Creation, and Green Infrastructure.

  6. Changes in shifting cultivation systems on small Pacific islands

    DEFF Research Database (Denmark)

    Mertz, Ole; Birch-Thomsen, Torben; Elberling, Bo

    2012-01-01

    The limited information on change in shifting cultivation systems of small islands of the Pacific stands in contrast to increasing evidence of this farming system's demise in other parts of the tropics. Here, we assess changes in agricultural activities during the past 40 years of Bellona Island......, Solomon Islands, where shifting cultivation is still maintained in the traditional way. Fallow length has increased despite population growth due to redistribution of the cultivated area, migration-induced extensification and changes in crops. Productivity of the farming system remains high although...

  7. Spectral shift rod for the boiling water reactor

    International Nuclear Information System (INIS)

    Yokomizo, O.; Kashiwai, S.; Nishida, K.; Orii, A.; Yamashita, J.; Mochida, T.

    1993-01-01

    A Boiling Water Reactor core concept has been proposed using a new fuel component called spectral shift rod (SSR). The SSR is a new type of water rod in which a water level is formed during core operation. The water level can be controlled by the core recirculation flow rate. By using SSRs, the reactor can be operated with all control rods withdrawn through the operation cycle as well as that a much larger natural uranium saving is possible due to spectral shift operation than in current BWRs. The steady state and transient characteristics of the SSRs have been examined by experiments and analyses to certify the feasibility. In a reference design, a four times larger spectral shift width as for the current BWR has been obtained. (orig.)

  8. Risk to Water Security on Small Islands

    Science.gov (United States)

    Holding, S. T.; Allen, D. M.

    2013-12-01

    The majority of fresh water available on small islands is shallow groundwater that forms a freshwater lens. Freshwater lenses are generally limited in extent and as such are vulnerable to many stressors that impact water security. These include stressors related to climate change, such as sea level rise, as well as those related to human impacts, such as contamination. Traditionally, water security assessments have focussed on indicators that provide a snapshot of the current condition. However, recent work suggests that in order to effectively manage the water system, it is also important to consider uncertain future impacts to the system by evaluating how different stressors might impact water security. In this study, a framework for assessing risk to water security was developed and tested on Andros Island in The Bahamas. The assessment comprises two main components that characterise the water system: numerical modelling studies and a hazard survey. A baseline numerical model of the freshwater lens throughout Andros Island was developed to simulate the morphology of the freshwater lens and estimate the freshwater resources currently available. The model was prepared using SEAWAT, a density-dependent flow and solute transport code. Various stressors were simulated in the model to evaluate the response of the freshwater lens to predicted future shifts in climate patterns, sea level rise, and changes in water use. A hazard survey was also conducted on the island to collect information related to the storage of contaminants, sanitation infrastructure, waste disposal practices and groundwater abstraction rates. The results of the survey form a geo-spatial database of the location and associated hazards to the freshwater lens. The resulting risk framework provides a ranking of overall risk to water security based on information from the numerical modelling and hazard survey. The risk framework is implemented in a Geographic Information System (GIS) and provides a map

  9. Small Drinking Water Systems Communication and Outreach ...

    Science.gov (United States)

    As part of our small drinking water systems efforts, this poster highlights several communications and outreach highlights that EPA's Office of Research and Development and Office of Water have been undertaking in collaboration with states and the Association of State Drinking Water Administrators. To share information at EPA's annual small drinking water systems workshop

  10. Statistical evaluation and measuring strategy for extremely small line shifts

    International Nuclear Information System (INIS)

    Hansen, P.G.

    1978-01-01

    For a measuring situation limited by counting statistics, but where the level of precision is such that possible systematic errors are a major concern, it is proposed to determine the position of a spectral line from a measured line segment by applying a bias correction to the centre of gravity of the segment. This procedure is statistically highly efficient and not sensitive to small errors in assumptions about the line shape. The counting strategy for an instrument that takes data point by point is also considered. It is shown that an optimum (''two-point'') strategy exists; a scan of the central part of the line is 68% efficient by this standard. (Auth.)

  11. Simulation of Water Gas Shift Zeolite Membrane Reactor

    Science.gov (United States)

    Makertiharta, I. G. B. N.; Rizki, Z.; Zunita, Megawati; Dharmawijaya, P. T.

    2017-07-01

    The search of alternative energy sources keeps growing from time to time. Various alternatives have been introduced to reduce the use of fossil fuel, including hydrogen. Many pathways can be used to produce hydrogen. Among all of those, the Water Gas Shift (WGS) reaction is the most common pathway to produce high purity hydrogen. The WGS technique faces a downstream processing challenge due to the removal hydrogen from the product stream itself since it contains a mixture of hydrogen, carbon dioxide and also the excess reactants. An integrated process using zeolite membrane reactor has been introduced to improve the performance of the process by selectively separate the hydrogen whilst boosting the conversion. Furthermore, the zeolite membrane reactor can be further improved via optimizing the process condition. This paper discusses the simulation of Zeolite Membrane Water Gas Shift Reactor (ZMWGSR) with variation of process condition to achieve an optimum performance. The simulation can be simulated into two consecutive mechanisms, the reaction prior to the permeation of gases through the zeolite membrane. This paper is focused on the optimization of the process parameters (e.g. temperature, initial concentration) and also membrane properties (e.g. pore size) to achieve an optimum product specification (concentration, purity).

  12. Shifting cultivation effects on creek water quality around Barkal Upazila in Chittagong Hill Tracts, Bangladesh

    Institute of Scientific and Technical Information of China (English)

    Shyamal Karmakar; S.M.Sirajul Haque; M.Mozaffar Hossain; Sohag Miah

    2012-01-01

    We report the effects of shifting cultivation on water quality in 16 creeks investigated once in 2007 and twice in 2008 in 16 apparently similar small neighboring watersheds,each of 3 to 5 ha,at four locations around Barkal sub-district under Rangamati District of Chittagong Hill Tracts in Bangladesh.Concentrations of SO42-and K+,and pH in creek water were lower,and NO3-N and Na+ concentrations were higher in shifting-cultivation land compared to land with either plantation or natural forest or a combination of these cover types.Shifting cultivation effects on some water quality parameters were not significant due to change in land cover of the watershed between two sampling periods either through introduction of planted tree species or naturally regenerated vegetation.Conductivity and concentrations of HCO3-.PO43-,Ca2+ and Mg2+ in creek water showed no definite trend between shifting cultivation and the other land cover types.At one area near the Forest Range Office of Barkal,creek water pH was 5.8 under land cover with a combination of shifting cultivation and plantation.At this area Na+ concentration in shifting-cultivation land ranged from 32.33 to 33.00 mg·L-1 and in vegetated area from 25.00 to 30.50 mg·L-1 in 2007.At another area,Chaliatali Chara,SO42-concentration in a shifting-cultivation watershed ranged from 4.46 to 10.51 mg·L-1,lower than in a vegetated watershed that ranged from 11.69 to 19.98 mg·L-1 in 2007.SO42-concentration in this shifting-cultivation area ranged from 1.28 to 1.37 mg·L-1 and in the vegetated area from 1.37 to 3.50 mg·L-1 in 2008.

  13. Increasing Water Temperature Triggers Dominance of Small Freshwater Plankton.

    Science.gov (United States)

    Rasconi, Serena; Gall, Andrea; Winter, Katharina; Kainz, Martin J

    2015-01-01

    Climate change scenarios predict that lake water temperatures will increase up to 4°C and rainfall events will become more intense and frequent by the end of this century. Concurrently, supply of humic substances from terrestrial runoff is expected to increase, resulting in darker watercolor ("brownification") of aquatic ecosystems. Using a multi-seasonal, low trophic state mesocosm experiment, we investigated how higher water temperature and brownification affect plankton community composition, phenology, and functioning. We tested the hypothesis that higher water temperature (+3°C) and brownification will, a) cause plankton community composition to shift toward small sized phytoplankton and cyanobacteria, and, b) extend the length of the growing season entailing higher phytoplankton production later in the season. We demonstrate that the 3°C increase of water temperature favored the growth of heterotrophic bacteria and small sized autotrophic picophytoplankton cells with significantly higher primary production during warmer fall periods. However, 3X darker water (effect of brownification) caused no significant changes in the plankton community composition or functioning relative to control conditions. Our findings reveal that increased temperature change plankton community structure by favoring smaller sized species proliferation (autotrophic phytoplankton and small size cladocerans), and increase primary productivity and community turnover. Finally, results of this multi-seasonal experiment suggest that warming by 3°C in aquatic ecosystems of low trophic state may cause planktonic food web functioning to become more dominated by fast growing, r-trait species (i.e., small sizes and rapid development).

  14. WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION; A

    International Nuclear Information System (INIS)

    Maria Flytzani-Stephanopoulos; Jerry Meldon; Xiaomei Qi

    2001-01-01

    Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperature to improve reaction kinetics. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H(sub 2) removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H(sub 2)-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. In the first year of the project, we prepared a series of nanostructured Cu- and Fe-containing ceria catalysts by a special gelation/precipitation technique followed by air calcination at 650 C. Each sample was characterized by ICP for elemental composition analysis, BET-N2 desorption for surface area measurement, and by temperature-programmed reduction in H(sub 2) to evaluate catalyst reducibility. Screening WGS tests with catalyst powders were conducted in a flow microreactor at temperatures in the range of 200-550 C. On the basis of both activity and stability of catalysts in simulated coal gas, and in CO(sub 2)-rich gases, a Cu-CeO(sub 2) catalyst formulation was selected for further study in this project. Details from the catalyst development and testing work are given in this report. Also in this report, we present H(sub 2) permeation data collected with unsupported flat membranes of pure Pd and Pd-alloys over a wide temperature window

  15. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift

    Energy Technology Data Exchange (ETDEWEB)

    Dagle, Robert A.; Platon, Alexandru; Datye, Abhaya K.; Vohs, John M.; Wang, Yong; Palo, Daniel R.

    2008-03-07

    Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 3600C without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming.

  16. Ambient temperature aqueous synthesis of ultrasmall copper doped ceria nanocrystals for the water gas shift and carbon monoxide oxidation reactions

    Energy Technology Data Exchange (ETDEWEB)

    Curran, Christopher D. [Department of Chemical and Biomolecular Engineering; Lehigh University; Bethlehem; USA; Lu, Li [Department of Materials Science and Engineering; Lehigh University; Bethlehem; USA; Kiely, Christopher J. [Department of Chemical and Biomolecular Engineering; Lehigh University; Bethlehem; USA; Department of Materials Science and Engineering; McIntosh, Steven [Department of Chemical and Biomolecular Engineering; Lehigh University; Bethlehem; USA

    2018-01-01

    Ultra-small CuxCe1-xO2-δnanocrystals were prepared through a room temperature, aqueous synthesis method, achieving high copper doping and low water gas shift activation energy.

  17. Isotope shifting capacity of rock

    International Nuclear Information System (INIS)

    Blattner, P.; Department of Scientific and Industrial Research, Lower Hutt

    1980-01-01

    Any oxygen isotope shifted rock volume exactly defines a past throughput of water. An expression is derived that relates the throughput of an open system to the isotope shift of reservoir rock and present-day output. The small isotope shift of Ngawha reservoir rock and the small, high delta oxygen-18 output are best accounted for by a magmatic water source

  18. Water turbine technology for small power stations

    Science.gov (United States)

    Salovaara, T.

    1980-02-01

    The paper examines hydro-power stations and the efficiency and costs of using water turbines to run them. Attention is given to different turbine types emphasizing the use of Kaplan-turbines and runners. Hydraulic characteristics and mechanical properties of low head turbines and small turbines, constructed of fully fabricated steel plate structures, are presented.

  19. Projected Regime Shift in Arctic Cloud and Water Vapor Feedbacks

    Science.gov (United States)

    Chen, Yonghua; Miller, James R.; Francis, Jennifer; Russel, Gary L.

    2011-01-01

    The Arctic climate is changing faster than any other large-scale region on Earth. A variety of positive feedback mechanisms are responsible for the amplification, most of which are linked with changes in snow and ice cover, surface temperature (T(sub s)), atmospheric water vapor (WV), and cloud properties. As greenhouse gases continue to accumulate in the atmosphere, air temperature and water vapor content also increase, leading to a warmer surface and ice loss, which further enhance evaporation and WV. Many details of these interrelated feedbacks are poorly understood, yet are essential for understanding the pace and regional variations in future Arctic change. We use a global climate model (Goddard Institute for Space Studies, Atmosphere-Ocean Model) to examine several components of these feedbacks, how they vary by season, and how they are projected to change through the 21st century. One positive feedback begins with an increase in T(sub s) that produces an increase in WV, which in turn increases the downward longwave flux (DLF) and T(sub s), leading to further evaporation. Another associates the expected increases in cloud cover and optical thickness with increasing DLF and T(sub s). We examine the sensitivities between DLF and other climate variables in these feedbacks and find that they are strongest in the non-summer seasons, leading to the largest amplification in Ts during these months. Later in the 21st century, however, DLF becomes less sensitive to changes in WV and cloud optical thickness, as they cause the atmosphere to emit longwave radiation more nearly as a black body. This regime shift in sensitivity implies that the amplified pace of Arctic change relative to the northern hemisphere could relax in the future.

  20. Entropy Generation Minimization for Reverse Water Gas Shift (RWGS Reactors

    Directory of Open Access Journals (Sweden)

    Lei Zhang

    2018-05-01

    Full Text Available Thermal design and optimization for reverse water gas shift (RWGS reactors is particularly important to fuel synthesis in naval or commercial scenarios. The RWGS reactor with irreversibilities of heat transfer, chemical reaction and viscous flow is studied based on finite time thermodynamics or entropy generation minimization theory in this paper. The total entropy generation rate (EGR in the RWGS reactor with different boundary conditions is minimized subject to specific feed compositions and chemical conversion using optimal control theory, and the optimal configurations obtained are compared with three reference reactors with linear, constant reservoir temperature and constant heat flux operations, which are commonly used in engineering. The results show that a drastic EGR reduction of up to 23% can be achieved by optimizing the reservoir temperature profile, the inlet temperature of feed gas and the reactor length simultaneously, compared to that of the reference reactor with the linear reservoir temperature. These optimization efforts are mainly achieved by reducing the irreversibility of heat transfer. Optimal paths have subsections of relatively constant thermal force, chemical force and local EGR. A conceptual optimal design of sandwich structure for the compact modular reactor is proposed, without elaborate control tools or excessive interstage equipment. The results can provide guidelines for designing industrial RWGS reactors in naval or commercial scenarios.

  1. Status of advanced small pressurized water reactors

    International Nuclear Information System (INIS)

    Chen Peipei; Zhou Yun

    2012-01-01

    In order to expand the nuclear power in energy and desalination, increase competitiveness in global nuclear power market, many developed countries with strong nuclear energy technology have realized the importance of Small Modular Reactor (SMR) and initiated heavy R and D programs in SMR. The Advanced Small Pressurized Water Reactor (ASPWR) is characterized by great advantages in safety and economy and can be used in remote power grid and replace mid/small size fossil plant economically. This paper reviews the history and current status of SMR and ASPWR, and also discusses the design concept, safety features and other advantages of ASPWR. The purpose of this paper is to provide an overall review of ASPWR technology in western countries, and to promote the R and D in ASPWR in China. (authors)

  2. Catastrophic shifts in the aquatic primary production revealed by a small low-flow section of tropical downstream after dredging.

    Science.gov (United States)

    Marotta, H; Enrich-Prast, A

    2015-11-01

    Dredging is a catastrophic disturbance that directly affects key biological processes in aquatic ecosystems, especially in those small and shallow. In the tropics, metabolic responses could still be enhanced by the high temperatures and solar incidence. Here, we assessed changes in the aquatic primary production along a small section of low-flow tropical downstream (Imboassica Stream, Brazil) after dredging. Our results suggested that these ecosystems may show catastrophic shifts between net heterotrophy and autotrophy in waters based on three short-term stages following the dredging: (I) a strongly heterotrophic net primary production -NPP- coupled to an intense respiration -R- likely supported by high resuspended organic sediments and nutrients from the bottom; (II) a strongly autotrophic NPP coupled to an intense gross primary production -GPP- favored by the high nutrient levels and low solar light attenuation from suspended solids or aquatic macrophytes; and (III) a NPP near to the equilibrium coupled to low GPP and R rates following, respectively, the shading by aquatic macrophytes and high particulate sedimentation. In conclusion, changes in aquatic primary production could be an important threshold for controlling drastic shifts in the organic matter cycling and the subsequent silting up of small tropical streams after dredging events.

  3. Increasing Water Temperature Triggers Dominance of Small Freshwater Plankton.

    Directory of Open Access Journals (Sweden)

    Serena Rasconi

    Full Text Available Climate change scenarios predict that lake water temperatures will increase up to 4°C and rainfall events will become more intense and frequent by the end of this century. Concurrently, supply of humic substances from terrestrial runoff is expected to increase, resulting in darker watercolor ("brownification" of aquatic ecosystems. Using a multi-seasonal, low trophic state mesocosm experiment, we investigated how higher water temperature and brownification affect plankton community composition, phenology, and functioning. We tested the hypothesis that higher water temperature (+3°C and brownification will, a cause plankton community composition to shift toward small sized phytoplankton and cyanobacteria, and, b extend the length of the growing season entailing higher phytoplankton production later in the season. We demonstrate that the 3°C increase of water temperature favored the growth of heterotrophic bacteria and small sized autotrophic picophytoplankton cells with significantly higher primary production during warmer fall periods. However, 3X darker water (effect of brownification caused no significant changes in the plankton community composition or functioning relative to control conditions. Our findings reveal that increased temperature change plankton community structure by favoring smaller sized species proliferation (autotrophic phytoplankton and small size cladocerans, and increase primary productivity and community turnover. Finally, results of this multi-seasonal experiment suggest that warming by 3°C in aquatic ecosystems of low trophic state may cause planktonic food web functioning to become more dominated by fast growing, r-trait species (i.e., small sizes and rapid development.

  4. Hydrogen bonding characterization in water and small molecules

    Science.gov (United States)

    Silvestrelli, Pier Luigi

    2017-06-01

    The prototypical hydrogen bond in water dimer and hydrogen bonds in the protonated water dimer, in other small molecules, in water cyclic clusters, and in ice, covering a wide range of bond strengths, are theoretically investigated by first-principles calculations based on density functional theory, considering not only a standard generalized gradient approximation functional but also, for the water dimer, hybrid and van der Waals corrected functionals. We compute structural, energetic, and electrostatic (induced molecular dipole moments) properties. In particular, hydrogen bonds are characterized in terms of differential electron density distributions and profiles, and of the shifts of the centres of maximally localized Wannier functions. The information from the latter quantities can be conveyed to a single geometric bonding parameter that appears to be correlated with the Mayer bond order parameter and can be taken as an estimate of the covalent contribution to the hydrogen bond. By considering the water trimer, the cyclic water hexamer, and the hexagonal phase of ice, we also elucidate the importance of cooperative/anticooperative effects in hydrogen-bonding formation.

  5. Water Grabbing and the Role of Power: Shifting Water Governance in the Light of Agricultural Foreign Direct Investment

    Directory of Open Access Journals (Sweden)

    Andrea Bues

    2012-06-01

    Full Text Available In recent years, the trend for foreign actors to secure land for agricultural production in low-income countries has increased substantially. The concurrent acquisition of water resources changes the institutional arrangement for water management in the investment areas. The consequences of 'land grabbing' on the local water governance systems have not so far been adequately examined. This paper presents an institutional analysis of a small-scale irrigation scheme in Ethiopia, where foreign and national horticultural farms started to use water from an irrigation canal that was formerly managed as a user-group common-pool resource by local smallholders. The study follows a qualitative case-study approach with semi-structured interviews as the main source of data. For the analysis we employed the Common-pool Resource Theory and the Distributional Theory of Institutional Change. We found that the former management regime changed in that most of the farmers’ water rights shifted to the investment farms. We found three key characteristics responsible for the different bargaining power of the two actor groups: dependency on natural resources, education and knowledge, and dependency on government support. We conclude that not only the struggle for land but also the directly linked struggle for water is led by diverging interests, which are determined by diverging power resources.

  6. Numerical Integration of a Class of Singularly Perturbed Delay Differential Equations with Small Shift

    Directory of Open Access Journals (Sweden)

    Gemechis File

    2012-01-01

    Full Text Available We have presented a numerical integration method to solve a class of singularly perturbed delay differential equations with small shift. First, we have replaced the second-order singularly perturbed delay differential equation by an asymptotically equivalent first-order delay differential equation. Then, Simpson’s rule and linear interpolation are employed to get the three-term recurrence relation which is solved easily by discrete invariant imbedding algorithm. The method is demonstrated by implementing it on several linear and nonlinear model examples by taking various values for the delay parameter and the perturbation parameter .

  7. Water erosion and climate change in a small alpine catchment

    Science.gov (United States)

    Berteni, Francesca; Grossi, Giovanna

    2017-04-01

    WATER EROSION AND CLIMATE CHANGE IN A SMALL ALPINE CATCHMENT Francesca Berteni, Giovanna Grossi A change in the mean and variability of some variables of the climate system is expected to affect the sediment yield of mountainous areas in several ways: for example through soil temperature and precipitation peak intensity change, permafrost thawing, snow- and ice-melt time shifting. Water erosion, sediment transport and yield and the effects of climate change on these physical phenomena are the focus of this work. The study area is a small mountainous basin, the Guerna creek watershed, located in the Central Southern Alps. The sensitivity of sediment yield estimates to a change of condition of the climate system may be investigated through the application of different models, each characterized by its own features and limits. In this preliminary analysis two different empirical mathematical models are considered: RUSLE (Revised Universal Soil Loss Equation; Renard et al., 1991) and EPM (Erosion Potential Method; Gavrilovic, 1988). These models are implemented in a Geographical Information System (GIS) supporting the management of the territorial database used to estimate relevant geomorphological parameters and to create different thematic maps. From one side the geographical and geomorphological information is required (land use, slope and hydrogeological instability, resistance to erosion, lithological characterization and granulometric composition). On the other side the knowledge of the weather-climate parameters (precipitation and temperature data) is fundamental as well to evaluate the intensity and variability of the erosive processes and estimate the sediment yield at the basin outlet. Therefore different climate change scenarios were considered in order to tentatively assess the impact on the water erosion and sediment yield at the small basin scale. Keywords: water erosion, sediment yield, climate change, empirical mathematical models, EPM, RUSLE, GIS

  8. Frequency shift of the Bragg and Non-Bragg backscattering from periodic water wave

    Science.gov (United States)

    Wen, Biyang; Li, Ke

    2016-08-01

    Doppler effect is used to measure the relative speed of a moving target with respect to the radar, and is also used to interpret the frequency shift of the backscattering from the ocean wave according to the water-wave phase velocity. The widely known relationship between the Doppler shift and the water-wave phase velocity was deduced from the scattering measurements data collected from actual sea surface, and has not been verified under man-made conditions. Here we show that this ob- served frequency shift of the scattering data from the Bragg and Non-Bragg water wave is not the Doppler shift corresponding to the water-wave phase velocity as commonly believed, but is the water-wave frequency and its integral multiple frequency. The power spectrum of the backscatter from the periodic water wave consists of serials discrete peaks, which is equally spaced by water wave frequency. Only when the water-wave length is the integer multiples of the Bragg wave, and the radar range resolution is infinite, does the frequency shift of the backscattering mathematically equal the Doppler shift according to the water-wave phase velocity.

  9. Energy calibration issues in nuclear resonant vibrational spectroscopy: observing small spectral shifts and making fast calibrations.

    Science.gov (United States)

    Wang, Hongxin; Yoda, Yoshitaka; Dong, Weibing; Huang, Songping D

    2013-09-01

    The conventional energy calibration for nuclear resonant vibrational spectroscopy (NRVS) is usually long. Meanwhile, taking NRVS samples out of the cryostat increases the chance of sample damage, which makes it impossible to carry out an energy calibration during one NRVS measurement. In this study, by manipulating the 14.4 keV beam through the main measurement chamber without moving out the NRVS sample, two alternative calibration procedures have been proposed and established: (i) an in situ calibration procedure, which measures the main NRVS sample at stage A and the calibration sample at stage B simultaneously, and calibrates the energies for observing extremely small spectral shifts; for example, the 0.3 meV energy shift between the 100%-(57)Fe-enriched [Fe4S4Cl4](=) and 10%-(57)Fe and 90%-(54)Fe labeled [Fe4S4Cl4](=) has been well resolved; (ii) a quick-switching energy calibration procedure, which reduces each calibration time from 3-4 h to about 30 min. Although the quick-switching calibration is not in situ, it is suitable for normal NRVS measurements.

  10. Small fluorescence-activating and absorption-shifting tag for tunable protein imaging in vivo.

    Science.gov (United States)

    Plamont, Marie-Aude; Billon-Denis, Emmanuelle; Maurin, Sylvie; Gauron, Carole; Pimenta, Frederico M; Specht, Christian G; Shi, Jian; Quérard, Jérôme; Pan, Buyan; Rossignol, Julien; Moncoq, Karine; Morellet, Nelly; Volovitch, Michel; Lescop, Ewen; Chen, Yong; Triller, Antoine; Vriz, Sophie; Le Saux, Thomas; Jullien, Ludovic; Gautier, Arnaud

    2016-01-19

    This paper presents Yellow Fluorescence-Activating and absorption-Shifting Tag (Y-FAST), a small monomeric protein tag, half as large as the green fluorescent protein, enabling fluorescent labeling of proteins in a reversible and specific manner through the reversible binding and activation of a cell-permeant and nontoxic fluorogenic ligand (a so-called fluorogen). A unique fluorogen activation mechanism based on two spectroscopic changes, increase of fluorescence quantum yield and absorption red shift, provides high labeling selectivity. Y-FAST was engineered from the 14-kDa photoactive yellow protein by directed evolution using yeast display and fluorescence-activated cell sorting. Y-FAST is as bright as common fluorescent proteins, exhibits good photostability, and allows the efficient labeling of proteins in various organelles and hosts. Upon fluorogen binding, fluorescence appears instantaneously, allowing monitoring of rapid processes in near real time. Y-FAST distinguishes itself from other tagging systems because the fluorogen binding is highly dynamic and fully reversible, which enables rapid labeling and unlabeling of proteins by addition and withdrawal of the fluorogen, opening new exciting prospects for the development of multiplexing imaging protocols based on sequential labeling.

  11. Combined Monte Carlo and quantum mechanics study of the solvatochromism of phenol in water. The origin of the blue shift of the lowest pi-pi* transition.

    Science.gov (United States)

    Barreto, Rafael C; Coutinho, Kaline; Georg, Herbert C; Canuto, Sylvio

    2009-03-07

    A combined and sequential use of Monte Carlo simulations and quantum mechanical calculations is made to analyze the spectral shift of the lowest pi-pi* transition of phenol in water. The solute polarization is included using electrostatic embedded calculations at the MP2/aug-cc-pVDZ level giving a dipole moment of 2.25 D, corresponding to an increase of 76% compared to the calculated gas-phase value. Using statistically uncorrelated configurations sampled from the MC simulation, first-principle size-extensive calculations are performed to obtain the solvatochromic shift. Analysis is then made of the origin of the blue shift. Results both at the optimized geometry and in room-temperature liquid water show that hydrogen bonds of water with phenol promote a red shift when phenol is the proton-donor and a blue shift when phenol is the proton-acceptor. In the case of the optimized clusters the calculated shifts are in very good agreement with results obtained from mass-selected free jet expansion experiments. In the liquid case the contribution of the solute-solvent hydrogen bonds partially cancels and the total shift obtained is dominated by the contribution of the outer solvent water molecules. Our best result, including both inner and outer water molecules, is 570 +/- 35 cm(-1), in very good agreement with the small experimental shift of 460 cm(-1) for the absorption maximum.

  12. Impact of water drops on small targets

    Science.gov (United States)

    Rozhkov, A.; Prunet-Foch, B.; Vignes-Adler, M.

    2002-10-01

    The collision of water drops against small targets was studied experimentally by means of a high-speed photography technique. The drop impact velocity was about 3.5 m/s. Drop diameters were in the range of 2.8-4.0 mm. The target was a stainless steel disk of 3.9 mm diameter. The drop spread beyond the target like a central cap surrounded by a thin, slightly conical lamella bounded by a thicker rim. By mounting a small obstacle near the target, surface-tension driven Mach waves in the flowing lamella were generated, which are formally equivalent to the familiar compressibility driven Mach waves in gas dynamics. From the measurement of the Mach angle, the values of some flow parameters could be obtained as functions of time, which provided insight into the flow structure. The liquid flowed from the central cap to the liquid rim through the thin lamella at constant momentum flux. At a certain stage of the process, most of the liquid accumulated in the rim and the internal part of the lamella became metastable. In this situation, a rupture wave propagating through the metastable internal part of the lamella caused the rim to retract while forming outwardly directed secondary jets. The jets disintegrated into secondary droplets due to the Savart-Plateau-Rayleigh instability. Prior to the end of the retraction, an internal circular wave of rupture was formed. It originated at the target and then it propagated to meet the retracting rim. Their meeting resulted in a crown of tiny droplets. A theoretical analysis of the ejection process is proposed.

  13. The Integration of a Structural Water Gas Shift Catalyst with a Vanadium Alloy Hydrogen Transport Device

    Energy Technology Data Exchange (ETDEWEB)

    Barton, Thomas; Argyle, Morris; Popa, Tiberiu

    2009-06-30

    component of conventional high temperature water gas shift iron oxide based catalysts. The catalysts contained Fe-Al-Cr-Cu-O and were synthesized by co-precipitation. A series of catalysts were prepared with 5 to 50 wt% Al2O3, with 8 wt% Cr2O3, 4 wt% CuO, and the balance Fe2O3. All of the catalysts were compared to a reference WGS catalyst (88 wt% FeOx, 8 wt% Cr2O3, and 4 wt% CuO) with no alumina. Alumina addition to conventional high temperature water gas shift catalysts at concentrations of approximately 15 wt% increased CO conversion rates and increase thermal stability. A series of high temperature water gas shift catalysts containing iron, chromia, and copper oxides were prepared with small amounts of added ceria in the system Fe-Cr-Cu-Ce-O. The catalysts were also tested kinetically under WGS conditions. 2-4 wt% ceria addition (at the expense of the iron oxide content) resulted in increased reaction rates (from 22-32% higher) compared to the reference catalyst. The project goal of a 10,000 liter per day WGS-membrane reactor was achieved by a device operating on coal derived syngas containing significant amounts of carbon monoxide and hydrogen sulfide. The membrane flux was equivalent to 52 scfh/ft2 based on a 600 psi syngas inlet pressure and corresponded to membranes costing $191 per square foot. Over 40 hours of iv exposure time to syngas has been achieved for a double membrane reactor. Two modules of the Chart reactor were tested under coal syngas for over 75 hours with a single module tested for 50 hours. The permeance values for the Chart membranes were similar to the REB reactor though total flux was reduced due to significantly thicker membranes. Overall testing of membrane reactors on coal derived syngas was over 115 hours for all reactors tested. Testing of the REB double membrane device exceeded 40 hours. Performance of the double membrane reactor has been similar to the results for the single reactor with good maintenance of flux even after these long

  14. Zeolite Membrane Reactor for Water Gas Shift Reaction for Hydrogen Production

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Jerry Y.S. [Arizona State Univ., Mesa, AZ (United States)

    2013-01-29

    Gasification of biomass or heavy feedstock to produce hydrogen fuel gas using current technology is costly and energy-intensive. The technology includes water gas shift reaction in two or more reactor stages with inter-cooling to maximize conversion for a given catalyst volume. This project is focused on developing a membrane reactor for efficient conversion of water gas shift reaction to produce a hydrogen stream as a fuel and a carbon dioxide stream suitable for sequestration. The project was focused on synthesizing stable, hydrogen perm-selective MFI zeolite membranes for high temperature hydrogen separation; fabricating tubular MFI zeolite membrane reactor and stable water gas shift catalyst for membrane reactor applications, and identifying experimental conditions for water gas shift reaction in the zeolite membrane reactor that will produce a high purity hydrogen stream. The project has improved understanding of zeolite membrane synthesis, high temperature gas diffusion and separation mechanisms for zeolite membranes, synthesis and properties of sulfur resistant catalysts, fabrication and structure optimization of membrane supports, and fundamentals of coupling reaction with separation in zeolite membrane reactor for water gas shift reaction. Through the fundamental study, the research teams have developed MFI zeolite membranes with good perm-selectivity for hydrogen over carbon dioxide, carbon monoxide and water vapor, and high stability for operation in syngas mixture containing 500 part per million hydrogen sulfide at high temperatures around 500°C. The research teams also developed a sulfur resistant catalyst for water gas shift reaction. Modeling and experimental studies on the zeolite membrane reactor for water gas shift reaction have demonstrated the effective use of the zeolite membrane reactor for production of high purity hydrogen stream.

  15. Multiparametric fat-water separation method for fast chemical-shift imaging guidance of thermal therapies.

    Science.gov (United States)

    Lin, Jonathan S; Hwang, Ken-Pin; Jackson, Edward F; Hazle, John D; Stafford, R Jason; Taylor, Brian A

    2013-10-01

    A k-means-based classification algorithm is investigated to assess suitability for rapidly separating and classifying fat/water spectral peaks from a fast chemical shift imaging technique for magnetic resonance temperature imaging. Algorithm testing is performed in simulated mathematical phantoms and agar gel phantoms containing mixed fat/water regions. Proton resonance frequencies (PRFs), apparent spin-spin relaxation (T2*) times, and T1-weighted (T1-W) amplitude values were calculated for each voxel using a single-peak autoregressive moving average (ARMA) signal model. These parameters were then used as criteria for k-means sorting, with the results used to determine PRF ranges of each chemical species cluster for further classification. To detect the presence of secondary chemical species, spectral parameters were recalculated when needed using a two-peak ARMA signal model during the subsequent classification steps. Mathematical phantom simulations involved the modulation of signal-to-noise ratios (SNR), maximum PRF shift (MPS) values, analysis window sizes, and frequency expansion factor sizes in order to characterize the algorithm performance across a variety of conditions. In agar, images were collected on a 1.5T clinical MR scanner using acquisition parameters close to simulation, and algorithm performance was assessed by comparing classification results to manually segmented maps of the fat/water regions. Performance was characterized quantitatively using the Dice Similarity Coefficient (DSC), sensitivity, and specificity. The simulated mathematical phantom experiments demonstrated good fat/water separation depending on conditions, specifically high SNR, moderate MPS value, small analysis window size, and low but nonzero frequency expansion factor size. Physical phantom results demonstrated good identification for both water (0.997 ± 0.001, 0.999 ± 0.001, and 0.986 ± 0.001 for DSC, sensitivity, and specificity, respectively) and fat (0.763 ± 0.006, 0

  16. Hydraulic Network Modelling of Small Community Water Distribution ...

    African Journals Online (AJOL)

    Prof Anyata

    ... design of a small community (Sakwa) water distribution network in North Eastern geopolitical region of Nigeria using ..... self cleansing drinking water distribution system is set at 0.4m/s, .... distribution network offers advantages over manual ...

  17. WATER-GAS SHIFT KINETICS OVER IRON OXIDE CATALYSTS AT MEMBRANE REACTOR CONDITIONS; A

    International Nuclear Information System (INIS)

    Carl R.F. Lund

    2001-01-01

    This report covers the second year of a project investigating water-gas shift catalysts for use in membrane reactors. It has been established that a simple iron high temperature shift catalyst becomes ineffective in a membrane reactor because the reaction rate is severely inhibited by the build-up of the product CO(sub 2). During the past year, an improved microkinetic model for water-gas shift over iron oxide was developed. Its principal advantage over prior models is that it displays the correct asymptotic behavior at all temperatures and pressures as the composition approaches equilibrium. This model has been used to explore whether it might be possible to improve the performance of iron high temperature shift catalysts under conditions of high CO(sub 2) partial pressure. The model predicts that weakening the surface oxygen bond strength by less than 5% should lead to higher catalytic activity as well as resistance to rate inhibition at higher CO(sub 2) partial pressures. Two promoted iron high temperature shift catalysts were studied. Ceria and copper were each studied as promoters since there were indications in the literature that they might weaken the surface oxygen bond strength. Ceria was found to be ineffective as a promoter, but preliminary results with copper promoted FeCr high temperature shift catalyst show it to be much more resistant to rate inhibition by high levels of CO(sub 2). Finally, the performance of sulfided CoMo/Al(sub 2)O(sub 3) catalysts under conditions of high CO(sub 2) partial pressure was simulated using an available microkinetic model for water-gas shift over this catalyst. The model suggests that this catalyst might be quite effective in a medium temperature water-gas shift membrane reactor, provided that the membrane was resistant to the H(sub 2)S that is required in the feed

  18. FINANCING ASSISTANCE AVAILABLE FOR SMALL PUBLIC WATER SYSTEMS

    Science.gov (United States)

    Many small and very small drinking water systems require repair and upgrading if they are to comply with the Safe Drinking Water Act of 1974 and its amendments. Often, dispersed population makes infracstructure expensive on a per-capita basis. Funding shortages at the federal, ...

  19. Graphite-moderated and heavy water-moderated spectral shift controlled reactors

    International Nuclear Information System (INIS)

    Alcala Ruiz, F.

    1984-01-01

    It has been studied the physical mechanisms related with the spectral shift control method and their general positive effects on economical and non-proliferant aspects (extension of the fuel cycle length and low proliferation index). This methods has been extended to non-hydrogenous fuel cells of high moderator/fuel ratio: heavy water cells have been con- trolled by graphite rods graphite-moderated and gas-cooled cells have been controlled by berylium rods and graphite-moderated and water-cooled cells have been controlled by a changing mixture of heavy and light water. It has been carried out neutron and thermal analysis on a pre design of these types of fuel cells. We have studied its neutron optimization and their fuel cycles, temperature coefficients and proliferation indices. Finally, we have carried out a comparative analysis of the fuel cycles of conventionally controlled PWRs and graphite-moderated, water-cooled and spectral shift controlled reactors. (Author) 71 refs

  20. Application of the water gas shift reaction to fusion fuel exhaust streams

    International Nuclear Information System (INIS)

    McKay, A.M.; Cheh, C.H.; Glass, R.W.

    1983-10-01

    In a Fusion Fuel Clean Up (FCU) system, impurities will be removed from the fusion reactor exhaust and neutral beam line streams. Tritium in this impurity stream will be recovered and recycled to the fuel stream. In one flowsheet configuration of the Tritium Systems Test Assembly (TSTA), tritium is recovered from a simulated impurity stream via uranium hot metal beds and recycled to an isotope separation system. This study has shown, however, that the catalyzed water gas shift reaction, by which (H,D,T) 2 O and CO are converted to (H,D,T) 2 and CO 2 is a better method of (H,D,T) 2 O reduction than the hot metal beds. Catalytic reactors were designed, built and tested to provide data for the design of a prototype reactor to replace the hot metal beds in the FCU system. The prototype reactor contains only 10 g of catalyst and is expected to last at least 5 years. The reactor is small (1.3 cm OD x 13 cm long), operates at low temperatures (approximately 490 K) and will convert water to hydrogen, at a CO/H 2 O ratio of 1.5, with an efficiency of greater than 98 percent. Results show that the catalytic reactor is very stable even during upset conditions. Wide ranges of flow and a CO/H 2 O ratio variance from 1.3 upward have little effect on the conversion efficiency. Short term high temperature excursions do not affect the catalyst and lower temperatures will simply decrease the reaction rate resulting in lower conversions. The reactor appears to be unaffected by NO 2 , CO 2 , O 2 and N 2 in the feed stream at concentration levels expected in a fusion reactor exhaust stream

  1. Municipal water powers small hydro in California

    Energy Technology Data Exchange (ETDEWEB)

    Townsend, C.W.

    1985-07-01

    The city council of San Luis Obispo, California approved a scheme in 1984 to install a hydropower plant into an existing water distribution network. The Stenner Canyon project is under construction on the site of an abandoned water treatment plant. A 750 kW Pelton turbine will be fed via a 20 km pipeline from the Salimas Reservoir. A remote telemetry system will control turbine output. The primary objectives are to generate extra power for the area and provide additional revenue for the city. Computer simulation helped hydraulics engineers design the system. Tax-exempt industrial development bonds will finance the $1.5 million project. 2 figures.

  2. Economic study of the treatment of surface water by small ...

    African Journals Online (AJOL)

    The purpose of this work is to evaluate the possibility of utilising an ultrafiltration process for the treatment of water from the dam in the Kabylia region of Algeria and, in particular, for the provision of drinking water to people living in dispersed small villages. The water quality was determined by measuring turbidity, and ...

  3. Sulfur Poisoning of the Water Gas Shift Reaction on Anode Supported Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Hagen, Anke

    2013-01-01

    resistance increased both in the high and low frequency region, which indicates a strong poisoning of the water gas shift reaction and thus a lack of hydrogen fuel in addition to the poisoning of the electrochemical hydrogen oxidation. All poisoning effects are reversible under the applied operating...

  4. Treatment technology for removing radon from small community water supplies

    International Nuclear Information System (INIS)

    Kinner, N.E.; Quern, P.A.; Schell, G.S.; Lessard, C.E.; Clement, J.A.

    1989-01-01

    Radon contamination of drinking water primarily affects individual homeowners and small communities using ground-water supplies. Presently, three types of treatment processes have been used to remove radon: granular activated carbon adsorption (GAC), diffused-bubble aeration, and packed-tower aeration. In order to obtain data on these treatment alternatives for small communities water supplies, a field evaluation study was conducted on these three processes as well as on several modifications to aeration of water in storage tanks considered to be low cost/low technology alternatives. The paper presents the results of these field studies conducted at a small mobile home park in rural New Hampshire. The conclusion of the study was that the selection of the appropriate treatment system to remove radon from drinking water depends primarily upon: (1) precent removal of process; (2) capital operating and maintenance costs; (3) safety (radiation); and (4) raw water quality (Fe, Mn, bacteria and organics)

  5. Kyiv Small Rivers in Metropolis Water Objects System

    Science.gov (United States)

    Krelshteyn, P.; Dubnytska, M.

    2017-12-01

    The article answers the question, what really are the small underground rivers with artificial watercourses: water bodies or city engineering infrastructure objects? The place of such rivers in metropolis water objects system is identified. The ecological state and the degree of urbanization of small rivers, as well as the dynamics of change in these indicators are analysed on the Kiev city example with the help of water objects cadastre. It was found that the registration of small rivers in Kyiv city is not conducted, and the summary information on such water objects is absent and is not taken into account when making managerial decisions at the urban level. To solve this problem, we propose to create some water bodies accounting system (water cadastre).

  6. Comparison of microbial community shifts in two parallel multi-step drinking water treatment processes.

    Science.gov (United States)

    Xu, Jiajiong; Tang, Wei; Ma, Jun; Wang, Hong

    2017-07-01

    Drinking water treatment processes remove undesirable chemicals and microorganisms from source water, which is vital to public health protection. The purpose of this study was to investigate the effects of treatment processes and configuration on the microbiome by comparing microbial community shifts in two series of different treatment processes operated in parallel within a full-scale drinking water treatment plant (DWTP) in Southeast China. Illumina sequencing of 16S rRNA genes of water samples demonstrated little effect of coagulation/sedimentation and pre-oxidation steps on bacterial communities, in contrast to dramatic and concurrent microbial community shifts during ozonation, granular activated carbon treatment, sand filtration, and disinfection for both series. A large number of unique operational taxonomic units (OTUs) at these four treatment steps further illustrated their strong shaping power towards the drinking water microbial communities. Interestingly, multidimensional scaling analysis revealed tight clustering of biofilm samples collected from different treatment steps, with Nitrospira, the nitrite-oxidizing bacteria, noted at higher relative abundances in biofilm compared to water samples. Overall, this study provides a snapshot of step-to-step microbial evolvement in multi-step drinking water treatment systems, and the results provide insight to control and manipulation of the drinking water microbiome via optimization of DWTP design and operation.

  7. Cloud Water Content Sensor for Sounding Balloons and Small UAVs

    Science.gov (United States)

    Bognar, John A.

    2009-01-01

    A lightweight, battery-powered sensor was developed for measuring cloud water content, which is the amount of liquid or solid water present in a cloud, generally expressed as grams of water per cubic meter. This sensor has near-zero power consumption and can be flown on standard sounding balloons and small, unmanned aerial vehicles (UAVs). The amount of solid or liquid water is important to the study of atmospheric processes and behavior. Previous sensing techniques relied on strongly heating the incoming air, which requires a major energy input that cannot be achieved on sounding balloons or small UAVs.

  8. Containment for small pressurized water reactors

    International Nuclear Information System (INIS)

    Siler, W.C.; Marda, R.S.; Smith, W.R.

    1977-01-01

    Babcock and Wilcox Company has prepared studies under ERDA contract of small and intermediate size (313, 365 and 1200 MWt) PWR reactor plants, for industrial cogeneration or electric power generation. Studies and experience with nuclear plants in this size range indicate unfavorable economics. To offset this disadvantage, modular characteristics of an integral reactor and close-coupled vapor suppression containment have been exploited to shorten construction schedules and reduce construction costs. The resulting compact reactor/containment complex is illustrated. Economic studies to date indicate that the containment design and the innovative construction techniques developed to shorten erection schedules have been important factors in reducing estimated project costs, thus potentially making such smaller plants competetive with competing energy sources

  9. Survey of disinfection efficiency of small drinking water treatment ...

    African Journals Online (AJOL)

    A survey involving 181 water treatment plants across 7 provinces of South Africa: Mpumalanga, Limpopo, North West, Free State, KwaZulu-Natal, Eastern Cape and Western Cape was undertaken to identify the challenges facing small water treatment plants (SWTPs) in South Africa . Information gathered included ...

  10. Water Distribution Network Modelling of a Small Community using ...

    African Journals Online (AJOL)

    ... of a small community (Sakwa) water distribution network in North Eastern geopolitical region of Nigeria using WaterCAD simulator. The analysis included a review of pressures, velocities and head loss gradients under steady state average day demand, maximum day demand conditions, and fire flow under maximum day ...

  11. Small Drinking Water Systems Communication and Outreach Highlights

    Science.gov (United States)

    As part of our small drinking water systems efforts, this poster highlights several communications and outreach highlights that EPA's Office of Research and Development and Office of Water have been undertaking in collaboration with states and the Association of State Drinking Wa...

  12. Optimization of a water-gas shift reactor over a Pt/ceria/alumina monolith

    Energy Technology Data Exchange (ETDEWEB)

    Quiney, A.S.; Germani, G.; Schuurman, Y. [Institut de Recherches sur la Catalyse-CNRS, 2 Avenue A. Einstein, 69626 Villeurbanne (France)

    2006-10-06

    The water-gas shift (WGS) reaction is an important step in the purification of hydrogen for fuel cells. It lowers the carbon monoxide content and produces extra hydrogen. The constraints of automotive applications render the commercial WGS catalysts unsuitable. Pt/ceria catalysts are cited as promising catalysts for onboard applications as they are highly active and non-pyrophoric. This paper reports on a power law rate expression for a Pt/CeO{sub 2}/Al{sub 2}O{sub 3} catalyst. This rate equation is used to compare different reactor configurations for an onboard water-gas shift reactor. A one-dimensional heterogeneous model that accounts for the interfacial and intraparticle gradients has been used to optimize a dual stage adiabatic monolith reactor. (author)

  13. Estimation of bias shifts in a steam-generator water-level controller

    International Nuclear Information System (INIS)

    Tylee, J.L.

    1983-01-01

    A method for detecting and estimating the value of sudden bias shifts in a U-tube steam-generator water-level controller is described and evaluated. Generalized likelihood ratios (GLR) are used to perform both the bias detection and bias estimation. Simulation results using a seventh-order, linear, discrete steam-generator model demonstrate the capabilities of the GLR detection/estimation approach

  14. Small Water System Alternatives: Media and Membrane Filtration Alternatives for Small Communities and Households

    Science.gov (United States)

    This webinar presentation will highlight research case studies on innovative drinking water treatment alternatives for small community water systems. Emphasis will be placed on media and membrane filtration technologies capable of meeting the requirements of the Long-Term 2 Enha...

  15. Advances of zeolite based membrane for hydrogen production via water gas shift reaction

    Science.gov (United States)

    Makertihartha, I. G. B. N.; Zunita, M.; Rizki, Z.; Dharmawijaya, P. T.

    2017-07-01

    Hydrogen is considered as a promising energy vector which can be obtained from various renewable sources. However, an efficient hydrogen production technology is still challenging. One technology to produce hydrogen with very high capacity with low cost is through water gas shift (WGS) reaction. Water gas shift reaction is an equilibrium reaction that produces hydrogen from syngas mixture by the introduction of steam. Conventional WGS reaction employs two or more reactors in series with inter-cooling to maximize conversion for a given volume of catalyst. Membrane reactor as new technology can cope several drawbacks of conventional reactor by removing reaction product and the reaction will favour towards product formation. Zeolite has properties namely high temperature, chemical resistant, and low price makes it suitable for membrane reactor applications. Moreover, it has been employed for years as hydrogen selective layer. This review paper is focusing on the development of membrane reactor for efficient water gas shift reaction to produce high purity hydrogen and carbon dioxide. Development of membrane reactor is discussed further related to its modification towards efficient reaction and separation from WGS reaction mixture. Moreover, zeolite framework suitable for WGS membrane reactor will be discussed more deeply.

  16. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    Science.gov (United States)

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  17. Bacterial Community Shift Drives Antibiotic Resistance Promotion during Drinking Water Chlorination.

    Science.gov (United States)

    Jia, Shuyu; Shi, Peng; Hu, Qing; Li, Bing; Zhang, Tong; Zhang, Xu-Xiang

    2015-10-20

    For comprehensive insights into the effects of chlorination, a widely used disinfection technology, on bacterial community and antibiotic resistome in drinking water, this study applied high-throughput sequencing and metagenomic approaches to investigate the changing patterns of antibiotic resistance genes (ARGs) and bacterial community in a drinking water treatment and distribution system. At genus level, chlorination could effectively remove Methylophilus, Methylotenera, Limnobacter, and Polynucleobacter, while increase the relative abundance of Pseudomonas, Acidovorax, Sphingomonas, Pleomonas, and Undibacterium in the drinking water. A total of 151 ARGs within 15 types were detectable in the drinking water, and chlorination evidently increased their total relative abundance while reduced their diversity in the opportunistic bacteria (p < 0.05). Residual chlorine was identified as the key contributing factor driving the bacterial community shift and resistome alteration. As the dominant persistent ARGs in the treatment and distribution system, multidrug resistance genes (mainly encoding resistance-nodulation-cell division transportation system) and bacitracin resistance gene bacA were mainly carried by chlorine-resistant bacteria Pseudomonas and Acidovorax, which mainly contributed to the ARGs abundance increase. The strong correlation between bacterial community shift and antibiotic resistome alteration observed in this study may shed new light on the mechanism behind the chlorination effects on antibiotic resistance.

  18. Community shift of biofilms developed in a full-scale drinking water distribution system switching from different water sources.

    Science.gov (United States)

    Li, Weiying; Wang, Feng; Zhang, Junpeng; Qiao, Yu; Xu, Chen; Liu, Yao; Qian, Lin; Li, Wenming; Dong, Bingzhi

    2016-02-15

    The bacterial community of biofilms in drinking water distribution systems (DWDS) with various water sources has been rarely reported. In this research, biofilms were sampled at three points (A, B, and C) during the river water source phase (phase I), the interim period (phase II) and the reservoir water source phase (phase III), and the biofilm community was determined using the 454-pyrosequencing method. Results showed that microbial diversity declined in phase II but increased in phase III. The primary phylum was Proteobacteria during three phases, while the dominant class at points A and B was Betaproteobacteria (>49%) during all phases, but that changed to Holophagae in phase II (62.7%) and Actinobacteria in phase III (35.6%) for point C, which was closely related to its water quality. More remarkable community shift was found at the genus level. In addition, analysis results showed that water quality could significantly affect microbial diversity together, while the nutrient composition (e.g. C/N ration) of the water environment might determine the microbial community. Furthermore, Mycobacterium spp. and Pseudomonas spp. were detected in the biofilm, which should give rise to attention. This study revealed that water source switching produced substantial impact on the biofilm community. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Assessment of a small pressurized water reactor for industrial energy

    International Nuclear Information System (INIS)

    Klepper, O.H.; Fuller, L.C.; Myers, M.L.

    1977-01-01

    An evaluation of several recent ERDA/ORNL sponsored studies on the application of a small, 365 MW(t) pressurized water reactor for industrial energy is presented. Preliminary studies have investigated technical and reliability requirements; costs for nuclear and fossil based steam were compared, including consideration of economic inflation and financing methods. For base-load industrial steam production, small reactors appear economically attractive relative to coal fired boilers that use coal priced at $30/ton

  20. Quantifying the blue shift in the light absorption of small gold nanoparticles

    International Nuclear Information System (INIS)

    Tsekov, Roumen; Georgiev, Peter; Simeonova, Silviya; Balashev, Konstantin

    2017-01-01

    The dependence of the surface plasmons resonance (SPR) frequency on the size of gold nanoparticles (GNPs) is experimentally studied. The measured data for the SPR frequency by UV-Vis spectroscopy and GNPs diameter by Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM) and Atomic Force Microscopy (AFM) are collected in the course of classical citrate GNPs synthesis. The relationship between the GNPs size and the blue shift of the light absorption is presented. They are fitted by an equation with a single free parameter, the dielectric permittivity of the surrounding media. Thus, the refractive index of the surrounding media is determined, which characterizes the GNPs surface shell. Key words: Gold nanoparticles (GNPs), Surface plasmon resonance (SPR), Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM), Atomic Force Microscopy (AFM)

  1. Reduction and Analysis of Low Temperature Shift Heterogeneous Catalyst for Water Gas Reaction in Ammonia Production

    Directory of Open Access Journals (Sweden)

    Zečević, N.

    2013-09-01

    Full Text Available In order to obtain additional quantities of hydrogen after the reforming reactions of natural gas and protect the ammonia synthesis catalyst, it is crucial to achieve and maintain maximum possible activity, selectivity and stability of the low temperature shift catalyst for conversion of water gas reaction during its lifetime. Whereas the heterogeneous catalyst comes in oxidized form, it is of the utmost importance to conduct the reduction procedure properly. The proper reduction procedure and continuous analysis of its performance would ensure the required activity, selectivity and stability throughout the catalyst’s service time. For the proper reduction procedure ofthe low temperature shift catalyst, in addition to process equipment, also necessary is a reliable and realistic system for temperature measurements, which will be effective for monitoring the exothermal temperature curves through all catalyst bed layers. For efficiency evaluation of low shift temperature catalyst reduction and its optimization, it is necessary to determine at regular time intervals the temperature approach to equilibrium and temperature profiles of individual layers by means of "S" and "die off" temperature exothermal curves. Based on the obtained data, the optimum inlet temperature could be determined, in order to maximally extend the service life of the heterogeneous catalyst as much as possible, and achieve the optimum equilibrium for conversion of the water gas. This paper presents the methodology for in situ reduction of the low temperature shift heterogeneous catalyst and the developed system for monitoring its individual layers to achieve the minimum possible content of carbon monoxide at the exit of the reactor. The developed system for temperature monitoring through heterogeneous catalyst layers provides the proper procedure for reduction and adjustment of optimum process working conditions for the catalyst by the continuous increase of reactor inlet

  2. Seawater desalination using small and medium light water reactors

    International Nuclear Information System (INIS)

    Shimamura, Kazuo

    2000-01-01

    Water is an essential substance for sustaining human life. As Japan is an island country, surrounded by the sea and having abundant rainfall, there is no scarcity of water in daily life except during abnormally dry summers or after disasters such as earthquakes. Consequently, there is hardly any demand for seawater desalination plants except on remote islands, Okinawa and a part of Kyushu. However, the IAEA has forecast a scarcity of drinking water in developing countries at the beginning of the 21st century. Further, much more irrigation water will be required every year to prevent cultivated areas from being lost by desertification. If developing countries were to produce such water by seawater desalination using current fossil fuel energy technology, it would cause increased air pollution and global warming. This paper explains the concept of seawater desalination plants using small and medium water reactors (hereinafter called 'nuclear desalination'), as well as important matters regarding the export nuclear desalination plants to developing countries. (author)

  3. The response of wavelength shifting panels in large water Cherenkov systems

    International Nuclear Information System (INIS)

    Bakich, A.M.; Peak, L.S.

    1986-01-01

    This paper describes a series of tests performed with a panel Bicron wavelength shifting acrylic plastic (BC-480) coupled to an EMI 9623B photomultiplier tube. The aim was to effectively increase the cathode coverage and its sensitivity to incident Cherenkov radiation, so that such a system could be employed in a solar neutrino detector. Measurements of the uniformity and effective efficiency of the system have been made and compared with the results of various simulation runs. The effects of side mirrors, back reflector, water interface and possible shaping of the panel to enhance its response are also assessed. (orig.)

  4. Small Water System Management Program: 100 K Area

    International Nuclear Information System (INIS)

    Hunacek, G.S. Jr.

    1995-01-01

    Purposes of this document are: to provide an overview of the service and potable water system presently in service at the Hanford Site's 100 K Area; to provide future system forecasts based on anticipated DOE activities and programs; to delineate performance, design, and operations criteria; and to describe planned improvements. The objective of the small water system management program is to assure the water system is properly and reliably managed and operated, and continues to exist as a functional and viable entity in accordance with WAC 246-290-410

  5. Fixed field alternating gradient accelerator with small orbit shift and tune excursion

    Directory of Open Access Journals (Sweden)

    Suzanne L. Sheehy

    2010-04-01

    Full Text Available A new design principle of a nonscaling fixed field alternating gradient accelerator is proposed. It is based on optics that produce approximate scaling properties. A large field index k is chosen to squeeze the orbit shift as much as possible by setting the betatron oscillation frequency in the second stability region of Hill’s equation. Then, the lattice magnets and their alignment are simplified. To simplify the magnets, we expand the field profile of r^{k} into multipoles and keep only a few lower order terms. A rectangular-shaped magnet is assumed with lines of constant field parallel to the magnet axis. The lattice employs a triplet of rectangular magnets for focusing, which are parallel to one another to simplify alignment. These simplifications along with fringe fields introduce finite chromaticity and the fixed field alternating gradient accelerator is no longer a scaling one. However, the tune excursion of the whole ring can be within half an integer and we avoid the crossing of strong resonances.

  6. Pre-"peak water" time in the southwest Yukon: when cryospheric changes trigger hydrological regime shifts

    Science.gov (United States)

    Baraer, M.; Chesnokova, A.; Huh, K. I.; Laperriere-Robillard, T.

    2017-12-01

    Saint-Elias Mountains host numerous cryospheric systems such as glaciers, seasonal and perennial snow cover, permafrost, aufeis, and different forms of buried ice. Those systems are very sensitive to climate changes and exhibit ongoing reduction in extent and/or changes in formation/ablation times. Because they highly influence the hydrological regimes of rivers, cryospheric changes raise concerns about consequences for regional water resources and ecosystems. The present study combines historical data analysis and hydrological modeling in order to estimate how cryospheric changes impact hydrological regimes at eight watersheds of different glacier cover (0- 30%) in the southwest Yukon. Methods combine traditional hydrograph analysis techniques and more advance techniques such as Fast Fourier Transform filters used to isolate significant trends in discharge properties from noise or climatic oscillations. Measured trends in discharge variables are connected to cryospheric changes by using a water balance / peak water model (Baraer et al., 2012), here adapted to the main cryospheric systems that characterize the southwest Yukon.Results show three distinct hydrological regimes for (1) non glacierized, (2) glacierized, and (3) major lakes hosting catchments. The studied glacierized catchments have not passed the "peak water" yet and still exhibit increases in yearly and late summer discharges and a decrease in runoff variability. All watersheds show an increase in winter discharge and a snowmelt-driven shift of yearly peak discharge toward earlier in the season. The study suggests that, in a couple of decades, water resources and dependent ecosystems will face the combined effects of (A) a shift in the contribution trend from declining perennial cryospheric systems and (B) continuing alteration of the contribution from the seasonal cryospheric systems.

  7. Development and utilization of spring water in small scale supply ...

    African Journals Online (AJOL)

    Development and utilization of spring water in small scale supply scheme for the Kogi State Polytechnic, Lokoja, central Nigeria. Joseph Omada. Abstract. No Abstract. Journal of Mining and Geology 2005, Vol. 41(1): 131-135. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL ...

  8. Sustainable Water Management under Climate Change in Small ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Sustainable Water Management under Climate Change in Small Island States of the Caribbean. In the Caribbean islands, climate change is affecting freshwater availability and other ecosystem services in complex ways. For example, freshwater supply is diminished by droughts and affected by saline intrusion due to sea ...

  9. Analysis of environmental issues related to small-scale hydroelectric development. III. Water level fluctuation

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrand, S.G. (ed.)

    1980-10-01

    Potential environmental impacts in reservoirs and downstream river reaches below dams that may be caused by the water level fluctuation resulting from development and operation of small scale (under 25MW) hydroelectric projects are identified. The impacts discussed will be of potential concern at only those small-scale hydroelectric projects that are operated in a store and release (peaking) mode. Potential impacts on physical and chemical characteristics in reservoirs resulting from water level fluctuation include resuspension and redistribution of bank and bed sediment; leaching of soluble organic matter from sediment in the littoral zone; and changes in water quality resulting from changes in sediment and nutrient trap efficiency. Potential impacts on reservoir biota as a result of water level fluctuation include habitat destruction and the resulting partial or total loss of aquatic species; changes in habitat quality, which result in reduced standing crop and production of aquatic biota; and possible shifts in species diversity. The potential physical effects of water level fluctuation on downstream systems below dams are streambed and bank erosion and water quality problems related to resuspension and redistribution of these materials. Potential biological impacts of water level fluctuation on downstream systems below dams result from changes in current velocity, habitat reduction, and alteration in food supply. These alterations, either singly or in combination, can adversely affect aquatic populations below dams. The nature and potential significance of adverse impacts resulting from water level fluctuation are discussed. Recommendations for site-specific evaluation of water level fluctuation at small-scale hydroelectric projects are presented.

  10. Changes in deviation of absorbed dose to water among users by chamber calibration shift.

    Science.gov (United States)

    Katayose, Tetsurou; Saitoh, Hidetoshi; Igari, Mitsunobu; Chang, Weishan; Hashimoto, Shimpei; Morioka, Mie

    2017-07-01

    The JSMP01 dosimetry protocol had adopted the provisional 60 Co calibration coefficient [Formula: see text], namely, the product of exposure calibration coefficient N C and conversion coefficient k D,X . After that, the absorbed dose to water D w  standard was established, and the JSMP12 protocol adopted the [Formula: see text] calibration. In this study, the influence of the calibration shift on the measurement of D w among users was analyzed. The intercomparison of the D w using an ionization chamber was annually performed by visiting related hospitals. Intercomparison results before and after the calibration shift were analyzed, the deviation of D w among users was re-evaluated, and the cause of deviation was estimated. As a result, the stability of LINAC, calibration of the thermometer and barometer, and collection method of ion recombination were confirmed. The statistical significance of standard deviation of D w was not observed, but that of difference of D w among users was observed between N C and [Formula: see text] calibration. Uncertainty due to chamber-to-chamber variation was reduced by the calibration shift, consequently reducing the uncertainty among users regarding D w . The result also pointed out uncertainty might be reduced by accurate and detailed instructions on the setup of an ionization chamber.

  11. Acoustic detection for small-leak sodium-water reaction

    International Nuclear Information System (INIS)

    Nei, Hiromichi; Ohshima, Iwao; Ujihara, Kozaburo; Hori, Masao

    1977-01-01

    Characteristics of acoustic signal produced by sodium-water reaction due to steam injection and by Ar gas injection into sodium were experimentally investigated. Acoustic signal was measured by using Kistler 808A and 815A5 accelerometers. Root mean square (RMS) measurements and frequency analysis of the signal were conducted. The RMS measurements could detect a small water leakage into sodium, as small as 0.07g/sec, in the present loop. The peaks in a frequency spectrum were caused by the natural vibration of a rod on which the acoustic transducer was mounted. The RMS was approximately proportional to the one-third power of the steam leak rate and increased to some extent with the ambient sodium temperature. RMS values, both for sodium-water reaction and Ar gas injection, were about the same order of magnitude, when the data were plotted against the volumetric flow rates of steam and Argas. (auth.)

  12. Shifting species interactions in terrestrial dryland ecosystems under altered water availability and climate change

    Science.gov (United States)

    McCluney, Kevin E.; Belnap, Jayne; Collins, Scott L.; González, Angélica L.; Hagen, Elizabeth M.; Holland, J. Nathaniel; Kotler, Burt P.; Maestre, Fernando T.; Smith, Stanley D.; Wolf, Blair O.

    2012-01-01

    Species interactions play key roles in linking the responses of populations, communities, and ecosystems to environmental change. For instance, species interactions are an important determinant of the complexity of changes in trophic biomass with variation in resources. Water resources are a major driver of terrestrial ecology and climate change is expected to greatly alter the distribution of this critical resource. While previous studies have documented strong effects of global environmental change on species interactions in general, responses can vary from region to region. Dryland ecosystems occupy more than one-third of the Earth's land mass, are greatly affected by changes in water availability, and are predicted to be hotspots of climate change. Thus, it is imperative to understand the effects of environmental change on these globally significant ecosystems. Here, we review studies of the responses of population-level plant-plant, plant-herbivore, and predator-prey interactions to changes in water availability in dryland environments in order to develop new hypotheses and predictions to guide future research. To help explain patterns of interaction outcomes, we developed a conceptual model that views interaction outcomes as shifting between (1) competition and facilitation (plant-plant), (2) herbivory, neutralism, or mutualism (plant-herbivore), or (3) neutralism and predation (predator-prey), as water availability crosses physiological, behavioural, or population-density thresholds. We link our conceptual model to hypothetical scenarios of current and future water availability to make testable predictions about the influence of changes in water availability on species interactions. We also examine potential implications of our conceptual model for the relative importance of top-down effects and the linearity of patterns of change in trophic biomass with changes in water availability. Finally, we highlight key research needs and some possible broader impacts

  13. Qualification of the ALKASORB sorbent for the sorption-enhanced water-gas shift process

    Energy Technology Data Exchange (ETDEWEB)

    Van Selow, E.R.; Cobden, P.D.; Dijk, Van H.A.J.; Walspurger, S.; Verbraeken, P.A.; Jansen, D.

    2013-07-01

    For the sorption-enhanced water-gas shift (SEWGS) process, a new sorbent material has been qualified in a reactor of 2 m length under conditions close to industrial designs. The sorbent ALKASORB is a potassium-carbonate promoted hydrotalcite-based compound. ALKASORB is shown to have many favourable properties in comparison to the reference sorbent, in particular with respect to mechanical stability. The cyclic capacity of the new compound is substantially higher than the cyclic capacity of the reference sorbent, and it allows a reduction of the steam requirement of 50%. The sorbent has demonstrated catalytic activity for the water-gas shift reaction that is sufficient to omit a separate catalyst. It is demonstrated that the sorbent remains chemically and mechanically stable during operation of at least 2000 adsorption-desorption cycles, even in the presence of H2S in the feed. H2S is shown not to influence CO2 adsorption capacity and is co-captured with the CO2. In contrast to the reference material that showed mechanical degradation during extended adsorption-desorption cycles, the new material is stable and allows to obtain carbon capture levels exceeding 95% more efficiently and more economically since the required size of the vessels will be smaller.

  14. Density functional theory study on water-gas-shift reaction over molybdenum disulfide

    DEFF Research Database (Denmark)

    Shi, X. R.; Wang, Shengguang; Hu, J.

    2009-01-01

    . The pathway for water-gas-shift reaction on both terminations has been carefully studied where the most favorable reaction path precedes the redox mechanism, namely the reaction takes place as follows: CO + H2O --> CO + OH + H --> CO + O + 2H --> CO2 + H-2. The most likely reaction candidates for the formate......Density functional theory calculations have been carried out to investigate the adsorption of reaction intermediates appearing during water-gas-shift reaction at the sulfur covered MoS2 (1 0 0)surfaces, Mo-termination with 37.5% S coverage and S-termination with 50% S coverage using periodic slabs...... species HCOO formation is the surface CO2 reaction with H as a side reaction of CO2 desorption on S-termination with 50% S coverage. The formed HCOO species will react further with adsorbed hydrogen yielding H2COO followed by breaking its C-O bond to form the surface CH2O and O species....

  15. Framework for continuous performance improvement in small drinking water systems.

    Science.gov (United States)

    Bereskie, Ty; Haider, Husnain; Rodriguez, Manuel J; Sadiq, Rehan

    2017-01-01

    Continuous performance improvement (CPI) can be a useful approach to overcome water quality problems impacting small communities. Small drinking water systems (SDWSs) struggle to meet regulatory requirements and often lack the economic and human resource flexibility for immediate improvement. A CPI framework is developed to provide SDWS managers and operators an approach to gauge their current performance against similar systems and to track performance improvement from the implementation of the new technologies or innovations into the future. The proposed CPI framework incorporates the use of a water quality index (WQI) and functional performance benchmarking to evaluate and compare drinking water quality performance of an individual water utility against that of a representative benchmark. The results are then used to identify and prioritize the most vulnerable water quality indicators and subsequently identify and prioritize performance improvement strategies. The proposed CPI framework has been demonstrated using data collected from SDWSs in the province of Newfoundland and Labrador (NL), Canada and using the Canadian Council of Ministers of the Environment (CCME) WQI. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Linking marine resources to ecotonal shifts of water uptake by terrestrial dune vegetation.

    Science.gov (United States)

    Greaver, Tara L; Sternberg, Leonel L da S

    2006-09-01

    As evidence mounts that sea levels are rising, it becomes increasingly important to understand the role of ocean water within terrestrial ecosystem dynamics. Coastal sand dunes are ecosystems that occur on the interface of land and sea. They are classic ecotones characterized by zonal distribution of vegetation in response to strong gradients of environmental factors from the ocean to the inland. Despite the proximity of the dune ecosystem to the ocean, it is generally assumed that all vegetation utilizes only freshwater and that water sources do not change across the ecotone. Evidence of ocean water uptake by vegetation would redefine the traditional interpretation of plant-water relations in the dune ecosystem and offer new ideas for assessing maritime influences on function and spatial distribution of plants across the dune. The purpose of this study was to identify sources of water (ocean, ground, and rain) taken up by vegetation using isotopic analysis of stem water and to evaluate water uptake patterns at the community level based on the distribution and assemblage of species. Three coastal dune systems located in southern Florida, USA, and the Bahamian bank/platform system were investigated. Plant distributions across the dune were zonal for 61-94% of the 18 most abundant species at each site. Species with their highest frequency on the fore dune (nearest the ocean) indicate ocean water uptake as evidenced by delta 18O values of stem water. In contrast, species most frequent in the back dune show no evidence of ocean water uptake. Analysis of species not grouped by frequency, but instead sampled along a transect from the ocean toward the inland, indicates that individuals from the vegetation assemblage closest to the ocean had a mixed water-harvesting strategy characterized by plants that may utilize ocean, ground-, and/or rainwater. In contrast, the inland vegetation relies mostly on rainwater. Our results show evidence supporting ocean water use by dune

  17. Shift Verification and Validation

    Energy Technology Data Exchange (ETDEWEB)

    Pandya, Tara M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Evans, Thomas M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Davidson, Gregory G [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Johnson, Seth R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Godfrey, Andrew T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2016-09-07

    This documentation outlines the verification and validation of Shift for the Consortium for Advanced Simulation of Light Water Reactors (CASL). Five main types of problems were used for validation: small criticality benchmark problems; full-core reactor benchmarks for light water reactors; fixed-source coupled neutron-photon dosimetry benchmarks; depletion/burnup benchmarks; and full-core reactor performance benchmarks. We compared Shift results to measured data and other simulated Monte Carlo radiation transport code results, and found very good agreement in a variety of comparison measures. These include prediction of critical eigenvalue, radial and axial pin power distributions, rod worth, leakage spectra, and nuclide inventories over a burn cycle. Based on this validation of Shift, we are confident in Shift to provide reference results for CASL benchmarking.

  18. Recommendations for small water reactor development in China

    International Nuclear Information System (INIS)

    Chen Peipei; Zhou Yun

    2012-01-01

    This paper summarizes the history and features of Advanced Small Water Reactor (ASWR), and provides recommendations and strategies on ASWR research and development in China. The ASWR can be used in remote power grid and replaces mid/small size fossil plant economically, and thus can be an important part of energy saving and emission reduction policy. The safety and economy characteristics of ASWR are able to effectively expand nuclear energy market in emerging countries and developing countries. Therefore, ASWR should be considered as a critical part of China's nuclear technology and equipment export strategy. (authors)

  19. A holistic water depth simulation model for small ponds

    Science.gov (United States)

    Ali, Shakir; Ghosh, Narayan C.; Mishra, P. K.; Singh, R. K.

    2015-10-01

    Estimation of time varying water depth and time to empty of a pond is prerequisite for comprehensive and coordinated planning of water resource for its effective utilization. A holistic water depth simulation (HWDS) and time to empty (TE) model for small, shallow ephemeral ponds have been derived by employing the generalized model based on the Green-Ampt equation in the basic water balance equation. The HWDS model includes time varying rainfall, runoff, surface water evaporation, outflow and advancement of wetting front length as external inputs. The TE model includes two external inputs; surface water evaporation and advancement of wetting front length. Both the models also consider saturated hydraulic conductivity and fillable porosity of the pond's bed material as their parameters. The solution of the HWDS model involved numerical iteration in successive time intervals. The HWDS model has successfully evaluated with 3 years of field data from two small ponds located within a watershed in a semi-arid region in western India. The HWDS model simulated time varying water depth in the ponds with high accuracy as shown by correlation coefficient (R2 ⩾ 0.9765), index of agreement (d ⩾ 0.9878), root mean square errors (RMSE ⩽ 0.20 m) and percent bias (PB ⩽ 6.23%) for the pooled data sets of the measured and simulated water depth. The statistical F and t-tests also confirmed the reliability of the HWDS model at probability level, p ⩽ 0.0001. The response of the TE model showed its ability to estimate the time to empty the ponds. An additional field calibration and validation of the HWDS and TE models with observed field data in varied hydro-climatic conditions could be conducted to increase the applicability and credibility of the models.

  20. Water striders (family Gerridae): mercury sentinels in small freshwater ecosystems

    International Nuclear Information System (INIS)

    Jardine, Timothy D.; Al, Tom A.; MacQuarrie, Kerry T.B.; Ritchie, Charles D.; Arp, Paul A.; Maprani, Antu; Cunjak, Richard A.

    2005-01-01

    To circumvent some of the previous limitations associated with contaminant-monitoring programs, we tested the suitability of the water strider (Hemiptera: Gerridae) as a mercury sentinel by comparing total mercury concentrations in water striders and brook trout (Salvelinus fontinalis) from a variety of stream sites in New Brunswick, Canada. There was a strong association between the two variables across sites (r 2 = 0.81, P < 0.001) in systems where both atmospheric deposition and a point source (an abandoned gold mine) were likely contributing to ambient mercury levels. In a small stream draining the gold mine tailings pile, water striders had mercury concentrations an order of magnitude higher than those from reference locations. Temporal variation at three southern New Brunswick stream sites was non-significant. These results suggest that water strider mercury levels accurately quantify food chain entry of the element. The use of sentinel species holds great potential for expanding contaminant-monitoring programs. - Water striders accurately reflect the entry of mercury in food chains of small freshwater systems

  1. Radon-removal techniques for small community public water supplies

    International Nuclear Information System (INIS)

    Kinner, N.E.; Malley, J.P.; Clement, J.A.; Quern, P.A.; Schell, G.S.

    1990-08-01

    The report presents the results of an evaluation, performed by the University of New Hampshire--Environmental Research Group (ERG), of radon removal in small community water supplies using full-scale granular activated carbon adsorption, diffused bubble aeration and packed tower aeration. Various low technology alternatives, such as loss in a distribution system and addition of coarse bubble aeration to a pilot-scale atmospheric storage tank were also evaluated. The report discusses each of the treatment alternatives with respect to their radon removal efficiency, potential problems (i.e., waste disposal, radiation exposure and intermedia pollution), and economics in small community applications. In addition, several sampling methods, storage times, scintillation cocktails and extraction procedures currently used in the liquid scintillation technique for analysis of radon in water were compared

  2. Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

    Energy Technology Data Exchange (ETDEWEB)

    Aragao, Isaias Barbosa; Ro, Insoo; Liu, Yifei; Ball, Madelyn; Huber, George W.; Zanchet, Daniela; Dumesic, James A.

    2018-03-01

    FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. The catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.

  3. Moderate drop in water table increases peatland vulnerability to post-fire regime shift.

    Science.gov (United States)

    Kettridge, N; Turetsky, M R; Sherwood, J H; Thompson, D K; Miller, C A; Benscoter, B W; Flannigan, M D; Wotton, B M; Waddington, J M

    2015-01-27

    Northern and tropical peatlands represent a globally significant carbon reserve accumulated over thousands of years of waterlogged conditions. It is unclear whether moderate drying predicted for northern peatlands will stimulate burning and carbon losses as has occurred in their smaller tropical counterparts where the carbon legacy has been destabilized due to severe drainage and deep peat fires. Capitalizing on a unique long-term experiment, we quantify the post-wildfire recovery of a northern peatland subjected to decadal drainage. We show that the moderate drop in water table position predicted for most northern regions triggers a shift in vegetation composition previously observed within only severely disturbed tropical peatlands. The combined impact of moderate drainage followed by wildfire converted the low productivity, moss-dominated peatland to a non-carbon accumulating shrub-grass ecosystem. This new ecosystem is likely to experience a low intensity, high frequency wildfire regime, which will further deplete the legacy of stored peat carbon.

  4. Changing environments or shifting paradigms? Strategic decision making toward water protection in Helsinki, 1850-2000.

    Science.gov (United States)

    Laakkonen, Simo; Laurila, Sari

    2007-04-01

    The study examines the history of strategic decision-making concerning water protection in Helsinki, 1850-2000. We identified five major strategic decisions that occurred during the study period. The results indicate that strategic decision-making evolves in long-term policy cycles that last on average 20-30 years. New policy cycles are caused by paradigm shifts. Paradigms are shared and predominant ways of understanding reality that help when groups must act to solve common and complex environmental problems. However the internal structure and external dynamics of paradigms are contradictory. Although paradigms serve initially as means to redefine problems and find creative solutions, as time goes by each paradigm seems to become also a barrier that restricts the introduction of new ways of thinking and acting. The power of paradigms lies in the fact that they can be defined as scientific but also social, political, or cultural agreements depending on the context.

  5. Shifting species interactions in terrestrial dryland ecosystems under altered water availability and climate change.

    Science.gov (United States)

    McCluney, Kevin E; Belnap, Jayne; Collins, Scott L; González, Angélica L; Hagen, Elizabeth M; Nathaniel Holland, J; Kotler, Burt P; Maestre, Fernando T; Smith, Stanley D; Wolf, Blair O

    2012-08-01

    Species interactions play key roles in linking the responses of populations, communities, and ecosystems to environmental change. For instance, species interactions are an important determinant of the complexity of changes in trophic biomass with variation in resources. Water resources are a major driver of terrestrial ecology and climate change is expected to greatly alter the distribution of this critical resource. While previous studies have documented strong effects of global environmental change on species interactions in general, responses can vary from region to region. Dryland ecosystems occupy more than one-third of the Earth's land mass, are greatly affected by changes in water availability, and are predicted to be hotspots of climate change. Thus, it is imperative to understand the effects of environmental change on these globally significant ecosystems. Here, we review studies of the responses of population-level plant-plant, plant-herbivore, and predator-prey interactions to changes in water availability in dryland environments in order to develop new hypotheses and predictions to guide future research. To help explain patterns of interaction outcomes, we developed a conceptual model that views interaction outcomes as shifting between (1) competition and facilitation (plant-plant), (2) herbivory, neutralism, or mutualism (plant-herbivore), or (3) neutralism and predation (predator-prey), as water availability crosses physiological, behavioural, or population-density thresholds. We link our conceptual model to hypothetical scenarios of current and future water availability to make testable predictions about the influence of changes in water availability on species interactions. We also examine potential implications of our conceptual model for the relative importance of top-down effects and the linearity of patterns of change in trophic biomass with changes in water availability. Finally, we highlight key research needs and some possible broader impacts

  6. Assessment of water quality from water harvesting using small farm reservoir for irrigation

    Science.gov (United States)

    Dewi, W. S.; Komariah; Samsuri, I. Y.; Senge, M.

    2018-03-01

    This study aims to assess the quality of rainfall-runoff water harvesting using small farm reservoir (SFR) for irrigation. Water quality assessment criteria based on RI Government Regulation number 82 the year 2001 on Water Quality Management and Pollution Control, and FAO Irrigation Water Quality Guidelines 1985. The experiment was conducted in the dry land of Wonosari Village, Gondangrejo District, Karanganyar Regency. SFR size was 10 m x 3 m x 2 m. Water quality measurements are done every week, ten times. Water samples were taken at 6 points, namely: distance of 2.5 m, 5 m, and 7.5 m from the inlet, at depth 25 cm and 175 cm from surface water. In each sampling point replicated three times. Water quality parameters include dissolved oxygen (DO), Turbidity (TSS), water pH, Nitrate (NO3), and Phosphate. The results show that water harvesting that collected in SFR meets both standards quality used, so the water is feasible for agricultural irrigation. The average value of harvested water was DO 2.6 mg/l, TSS 62.7 mg/l, pH 6.6, P 5.3 mg/l and NO3 0.16 mg/l. Rainfall-runoff water harvesting using SFR prospectus for increasing save water availability for irrigation.

  7. A mesic maximum in biological water use demarcates biome sensitivity to aridity shifts.

    Science.gov (United States)

    Good, Stephen P; Moore, Georgianne W; Miralles, Diego G

    2017-12-01

    Biome function is largely governed by how efficiently available resources can be used and yet for water, the ratio of direct biological resource use (transpiration, E T ) to total supply (annual precipitation, P) at ecosystem scales remains poorly characterized. Here, we synthesize field, remote sensing and ecohydrological modelling estimates to show that the biological water use fraction (E T /P) reaches a maximum under mesic conditions; that is, when evaporative demand (potential evapotranspiration, E P ) slightly exceeds supplied precipitation. We estimate that this mesic maximum in E T /P occurs at an aridity index (defined as E P /P) between 1.3 and 1.9. The observed global average aridity of 1.8 falls within this range, suggesting that the biosphere is, on average, configured to transpire the largest possible fraction of global precipitation for the current climate. A unimodal E T /P distribution indicates that both dry regions subjected to increasing aridity and humid regions subjected to decreasing aridity will suffer declines in the fraction of precipitation that plants transpire for growth and metabolism. Given the uncertainties in the prediction of future biogeography, this framework provides a clear and concise determination of ecosystems' sensitivity to climatic shifts, as well as expected patterns in the amount of precipitation that ecosystems can effectively use.

  8. The shift from plant-plant facilitation to competition under severe water deficit is spatially explicit.

    Science.gov (United States)

    O'Brien, Michael J; Pugnaire, Francisco I; Armas, Cristina; Rodríguez-Echeverría, Susana; Schöb, Christian

    2017-04-01

    The stress-gradient hypothesis predicts a higher frequency of facilitative interactions as resource limitation increases. Under severe resource limitation, it has been suggested that facilitation may revert to competition, and identifying the presence as well as determining the magnitude of this shift is important for predicting the effect of climate change on biodiversity and plant community dynamics. In this study, we perform a meta-analysis to compare temporal differences of species diversity and productivity under a nurse plant ( Retama sphaerocarpa ) with varying annual rainfall quantity to test the effect of water limitation on facilitation. Furthermore, we assess spatial differences in the herbaceous community under nurse plants in situ during a year with below-average rainfall. We found evidence that severe rainfall deficit reduced species diversity and plant productivity under nurse plants relative to open areas. Our results indicate that the switch from facilitation to competition in response to rainfall quantity is nonlinear. The magnitude of this switch depended on the aspect around the nurse plant. Hotter south aspects under nurse plants resulted in negative effects on beneficiary species, while the north aspect still showed facilitation. Combined, these results emphasize the importance of spatial heterogeneity under nurse plants for mediating species loss under reduced precipitation, as predicted by future climate change scenarios. However, the decreased water availability expected under climate change will likely reduce overall facilitation and limit the role of nurse plants as refugia, amplifying biodiversity loss.

  9. Theoretical estimation of pnicogen bonds and hydrogen bonds in small heterocyclic complexes: Red-shifts and blue-shifts ruled by polarization effects

    International Nuclear Information System (INIS)

    Oliveira, Boaz G.

    2014-01-01

    Graphical abstract: - Highlights: • This paper definitively discusses the interaction strength. • Analyses of the red-shifts and blue-shift. • Stretch frequencies of the hydrogen bonds and pnicogen bonds in heterocyclic compounds. • Theoretical calculations derived from topological parameters of the Quantum Theory of Atoms in Molecules (QTAIM). • The analysis of the Natural Bond Orbital (NBO) in line with the Bent’s rule of the chemical bonding. - Abstract: The occurrence of pnicogen bonds (N⋯P) and hydrogen bonds (F⋯H or Cl⋯H) in heterocyclic complexes formed by C 2 H 5 N⋯PH 3 , C 2 H 5 N⋯PH 2 F and C 2 H 5 N⋯PH 2 Cl was investigated at the B3LYP/6-311++G(d,p) level of theory. Analysis of the infrared spectra revealed the appearance of both red and blue shifts for the P–H bonds. However, in the case of the P–F and P–Cl bonds only red shifts were observed. The phenomenology of these vibration modes was interpreted on the basis of the QTAIM atomic radii as well as the contributions of the s and p orbitals determined via NBO calculations. The results of this latter investigation are consistent with the rehybridization theory and the Bent rule for chemical bonding. The charge transfer between N and P was determined in order to verify whether these atoms present an acid or base profile upon the formation of the pnicogen bonds

  10. Solar water heating for small cheese factories in Peru

    Energy Technology Data Exchange (ETDEWEB)

    Oliveros Donohue, A A

    1982-03-01

    Plans are described for the implementation of 40 small plants to be used for cheese production. As a start, a demonstration plant has been built in San Juan de Chuquibambilla-Puno, Peru. Design and testing of a flat plate solar collector, to be used for water heating purposes, are described. The cheese making process is discussed. Essentially two pots are required, one at 32/sup 0/C and one at 80/sup 0/. Two flat plate collectors (1.12 m/sup 2/ each) are connected to a 150 l storage tank. Instrumentation and results are discussed. Total efficiency of the process is given as 40%. It is concluded that future installations should consider using biogas digesters and wind driven water pumps in addition to the solar collectors. A brief discussion of the climate, population distribution, and economy of Peru is given. (MJJ)

  11. Small-scale shifting mosaics of two dominant grassland species: the possible role of soil-borne pathogens.

    Science.gov (United States)

    Olff, H; Hoorens, B; de Goede, R G M; van der Putten, W H; Gleichman, J M

    2000-10-01

    We analyzed the dynamics of dominant plant species in a grazed grassland over 17 years, and investigated whether local shifts in these dominant species, leading to vegetation mosaics, could be attributed to interactions between plants and soil-borne pathogens. We found that Festuca rubra and Carex arenaria locally alternated in abundance, with different sites close together behaving out of phase, resulting in a shifting mosaic. The net effect of killing all soil biota on the growth of these two species was investigated in a greenhouse experiment using gamma radiation, controlling for possible effects of sterilization on soil chemistry. Both plant species showed a strong net positive response to soil sterilization, indicating that pathogens (e.g., nematodes, pathogenic fungi) outweighed the effect of mutualists (e.g., mycorrhizae). This positive growth response towards soil sterilization appeared not be due to effects of sterilization on soil chemistry. Growth of Carex was strongly reduced by soil-borne pathogens (86% reduction relative to its growth on sterilized soil) on soil from a site where this species decreased during the last decade (and Festuca increased), while it was reduced much less (50%) on soil from a nearby site where it increased in abundance during the last decade. Similarly, Festuca was reduced more (67%) on soil from the site where it decreased (and Carex increased) than on soil from the site where it increased (55%, the site where Carex decreased). Plant-feeding nematodes showed high small-scale variation in densities, and we related this variation to the observed growth reductions in both plant species. Carex growth on unsterilized soil was significantly more reduced at higher densities of plant-feeding nematodes, while the growth reduction in Festuca was independent of plant-feeding nematode densities. At high plant-feeding nematode densities, growth of Carex was reduced more than Festuca, while at low nematode densities the opposite was found

  12. Small-scale experimental study of vaporization flux of liquid nitrogen released on water.

    Science.gov (United States)

    Gopalaswami, Nirupama; Olewski, Tomasz; Véchot, Luc N; Mannan, M Sam

    2015-10-30

    A small-scale experimental study was conducted using liquid nitrogen to investigate the convective heat transfer behavior of cryogenic liquids released on water. The experiment was performed by spilling five different amounts of liquid nitrogen at different release rates and initial water temperatures. The vaporization mass fluxes of liquid nitrogen were determined directly from the mass loss measured during the experiment. A variation of initial vaporization fluxes and a subsequent shift in heat transfer mechanism were observed with changes in initial water temperature. The initial vaporization fluxes were directly dependent on the liquid nitrogen spill rate. The heat flux from water to liquid nitrogen determined from experimental data was validated with two theoretical correlations for convective boiling. It was also observed from validation with correlations that liquid nitrogen was found to be predominantly in the film boiling regime. The substantial results provide a suitable procedure for predicting the heat flux from water to cryogenic liquids that is required for source term modeling. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Hydrodesulphurization of Light Gas Oil using hydrogen from the Water Gas Shift Reaction

    Science.gov (United States)

    Alghamdi, Abdulaziz

    2009-12-01

    The production of clean fuel faces the challenges of high production cost and complying with stricter environmental regulations. In this research, the ability of using a novel technology of upgrading heavy oil to treat Light Gas Oil (LGO) will be investigated. The target of this project is to produce cleaner transportation fuel with much lower cost of production. Recently, a novel process for upgrading of heavy oil has been developed at University of Waterloo. It is combining the two essential processes in bitumen upgrading; emulsion breaking and hydroprocessing into one process. The water in the emulsion is used to generate in situ hydrogen from the Water Gas Shift Reaction (WGSR). This hydrogen can be used for the hydrogenation and hydrotreating reaction which includes sulfur removal instead of the expensive molecular hydrogen. This process can be carried out for the upgrading of the bitumen emulsion which would improve its quality. In this study, the hydrodesulphurization (HDS) of LGO was conducted using in situ hydrogen produced via the Water Gas Shift Reaction (WGSR). The main objective of this experimental study is to evaluate the possibility of producing clean LGO over dispersed molybdenum sulphide catalyst and to evaluate the effect of different promoters and syn-gas on the activity of the dispersed Mo catalyst. Experiments were carried out in a 300 ml Autoclave batch reactor under 600 psi (initially) at 391°C for 1 to 3 hours and different amounts of water. After the hydrotreating reaction, the gas samples were collected and the conversion of carbon monoxide to hydrogen via WGSR was determined using a refinery gas analyzer. The sulphur content in liquid sample was analyzed via X-Ray Fluorescence. Experimental results showed that using more water will enhance WGSR but at the same time inhibits the HDS reaction. It was also shown that the amount of sulfur removed depends on the reaction time. The plan is to investigate the effect of synthesis gas (syngas

  14. Status of small water supplies in the Nordic countries: Characteristics, water quality and challenges.

    Science.gov (United States)

    Gunnarsdottir, Maria J; Persson, Kenneth M; Andradottir, Hrund O; Gardarsson, Sigurdur M

    2017-11-01

    Access to safe water is essential for public health and is one of the most important prerequisites for good living and safe food production. Many studies have shown that non-compliance with drinking water quality standards in small water supply systems is much higher than in large systems. Nevertheless, people served by small water supply systems have the right to the same level of health protection. Actions are therefore needed to improve the situation. The objective of the present study was to carry out a baseline analysis of the situation in the Nordic region and provide recommendations for governmental policy and actions. Data were gathered on number of water supplies, population served, compliance with regulations and waterborne disease outbreaks from various sources in the Nordic countries. The collected data showed that there are about 12500 regulated water supplies, 9400 of which serve fewer than 500 persons. The number of unregulated and poorly regulated supplies is unknown, but it can be roughly estimated that these serve 10% of the Nordic population on a permanent basis or 2.6 million people. However, this does not tell the whole story as many of the very small water supplies serve transient populations, summerhouse dwellers and tourist sites, with many more users. Non-compliance regarding microbes is much higher in the small supplies. The population weighted average fecal contamination incidence rate in the Nordic region is eleven times higher in the smaller supplies than in the large ones, 0.76% and 0.07%, respectively. Registered waterborne disease outbreaks were also more frequent in the small supplies than in the large ones. Copyright © 2017 Elsevier GmbH. All rights reserved.

  15. Quantification of Protozoa and Viruses from Small Water Volumes

    Directory of Open Access Journals (Sweden)

    J. Alfredo Bonilla

    2015-06-01

    Full Text Available Large sample volumes are traditionally required for the analysis of waterborne pathogens. The need for large volumes greatly limits the number of samples that can be processed. The aims of this study were to compare extraction and detection procedures for quantifying protozoan parasites and viruses from small volumes of marine water. The intent was to evaluate a logistically simpler method of sample collection and processing that would facilitate direct pathogen measures as part of routine monitoring programs. Samples were collected simultaneously using a bilayer device with protozoa capture by size (top filter and viruses capture by charge (bottom filter. Protozoan detection technologies utilized for recovery of Cryptosporidium spp. and Giardia spp. were qPCR and the more traditional immunomagnetic separation—IFA-microscopy, while virus (poliovirus detection was based upon qPCR versus plaque assay. Filters were eluted using reagents consistent with the downstream detection technologies. Results showed higher mean recoveries using traditional detection methods over qPCR for Cryptosporidium (91% vs. 45% and poliovirus (67% vs. 55% whereas for Giardia the qPCR-based methods were characterized by higher mean recoveries (41% vs. 28%. Overall mean recoveries are considered high for all detection technologies. Results suggest that simultaneous filtration may be suitable for isolating different classes of pathogens from small marine water volumes. More research is needed to evaluate the suitability of this method for detecting pathogens at low ambient concentration levels.

  16. [Effect of shifting sand burial on evaporation reduction and salt restraint under saline water irrigation in extremely arid region].

    Science.gov (United States)

    Zhang, Jian-Guo; Zhao, Ying; Xu, Xin-Wen; Lei, Jia-Qiang; Li, Sheng-Yu; Wang, Yong-Dong

    2014-05-01

    The Taklimakan Desert Highway Shelterbelt is drip-irrigated with high saline groundwater (2.58-29.70 g x L(-1)), and shifting sand burial and water-salt stress are most common and serious problems in this region. So it is of great importance to study the effect of shifting sand burial on soil moisture evaporation, salt accumulation and their distribution for water saving, salinity restraint, and suitable utilization of local land and water resources. In this study, Micro-Lysimeters (MLS) were used to investigate dynamics of soil moisture and salt under different thicknesses of sand burial (1, 2, 3, 4, and 5 cm), and field control experiments of drip-irrigation were also carried out to investigate soil moisture and salt distribution under different thicknesses of shifting sand burial (5, 10, 15, 20, 25, 30, 35, and 40 cm). The soil daily and cumulative evaporation decreased with the increase of sand burial thickness in MLS, cumulative evaporation decreased by 2.5%-13.7% compared with control. And evaporative inhibiting efficiency increased with sand burial thickness, evaporative inhibiting efficiency of 1-5 cm sand burial was 16.7%-79.0%. Final soil moisture content beneath the interface of sand burial increased with sand burial thickness, and it increased by 2.5%-13.7% than control. The topsoil EC of shifting sand in MLS decreased by 1.19-6.00 mS x cm(-1) with the increasing sand burial thickness, whereas soil salt content beneath the interface in MLS increased and amplitude of the topsoil salt content was higher than that of the subsoil. Under drip-irrigation with saline groundwater, average soil moisture beneath the interface of shifting sand burial increased by 0.4% -2.0% compare with control, and the highest value of EC was 7.77 mS x cm(-1) when the sand burial thickness was 10 cm. The trend of salt accumulation content at shifting sand surface increased firstly, and then decreased with the increasing sand burial thickness. Soil salt contents beneath the

  17. REMOVING BIOMASS FROM WATER PONDS AND SMALL WATER RESERVOIRS BY USING NON-WOVEN FILTERS

    Directory of Open Access Journals (Sweden)

    Jakub Nieć

    2015-10-01

    Full Text Available Small water bodies, for example garden ponds, play many functions in the environment, including biocenotic, hydrological, climatic, sozological, landfill-creative, and aesthetic. Due to their small size, these reservoirs are sensitive to external and internal factors, they are also a common natural contaminants receivers. Nonwoven filters have been investigated for several years as a useful device for treatment of domestic wastewater pre-treated in a septic tank. The aim of this study was to verify the possibility of using this type of filters for water originating from small water body purification. The effectiveness of filters were tested on the water originating from the garden pond, contained high levels of nutrients and intensive algal bloom. Research was carried out on three filters (each filter consisted of four geotextile TS 20 layers. Basic water quality indicators: total suspended solids, turbidity, COD and BOD5, temperature, pH and dissolved oxygen were measured. The research results can be considered as satisfactory in terms of mechanical treatment (removal of turbidity and total suspended solids. An important positive effect of the filters was the oxygenation of the treated water, which is especially important for fish.

  18. Rapid shift and millennial-scale variations in Holocene North Pacific Intermediate Water ventilation.

    Science.gov (United States)

    Lembke-Jene, Lester; Tiedemann, Ralf; Nürnberg, Dirk; Gong, Xun; Lohmann, Gerrit

    2018-05-22

    The Pacific hosts the largest oxygen minimum zones (OMZs) in the world ocean, which are thought to intensify and expand under future climate change, with significant consequences for marine ecosystems, biogeochemical cycles, and fisheries. At present, no deep ventilation occurs in the North Pacific due to a persistent halocline, but relatively better-oxygenated subsurface North Pacific Intermediate Water (NPIW) mitigates OMZ development in lower latitudes. Over the past decades, instrumental data show decreasing oxygenation in NPIW; however, long-term variations in middepth ventilation are potentially large, obscuring anthropogenic influences against millennial-scale natural background shifts. Here, we use paleoceanographic proxy evidence from the Okhotsk Sea, the foremost North Pacific ventilation region, to show that its modern oxygenated pattern is a relatively recent feature, with little to no ventilation before six thousand years ago, constituting an apparent Early-Middle Holocene (EMH) threshold or "tipping point." Complementary paleomodeling results likewise indicate a warmer, saltier EMH NPIW, different from its modern conditions. During the EMH, the Okhotsk Sea switched from a modern oxygenation source to a sink, through a combination of sea ice loss, higher water temperatures, and remineralization rates, inhibiting ventilation. We estimate a strongly decreased EMH NPIW oxygenation of ∼30 to 50%, and increased middepth Pacific nutrient concentrations and carbon storage. Our results ( i ) imply that under past or future warmer-than-present conditions, oceanic biogeochemical feedback mechanisms may change or even switch direction, and ( ii ) provide constraints on the high-latitude North Pacific's influence on mesopelagic ventilation dynamics, with consequences for large oceanic regions. Copyright © 2018 the Author(s). Published by PNAS.

  19. Prolonged whole-body cold water immersion: fluid and ion shifts.

    Science.gov (United States)

    Deuster, P A; Smith, D J; Smoak, B L; Montgomery, L C; Singh, A; Doubt, T J

    1989-01-01

    To characterize fluid and ion shifts during prolonged whole-body immersion, 16 divers wearing dry suits completed four whole-body immersions in 5 degrees C water during each of two 5-day air saturation dives at 6.1 msw. One immersion was conducted at 1000 (AM) and one at 2200 (PM) so that diurnal variations could be evaluated. Fifty-four hours separated the immersions, which lasted up to 6 h; 9 days separated each air saturation dive. Blood was collected before and after immersion; urine was collected for 12 h before, during, and after immersion for a total of 24 h. Plasma volume decreased significantly and to the same extent (approximately 17%) during both AM and PM immersions. Urine flow increased by 236.1 +/- 38.7 and 296.3 +/- 52.0%, urinary excretion of Na increased by 290.4 +/- 89.0 and 329.5 +/- 77.0%, K by 245.0 +/- 73.4 and 215.5 +/- 44.6%, Ca by 211.0 +/- 31.4 and 241.1 +/- 50.4%, Mg by 201.4 +/- 45.9 and 165.3 +/- 287%, and Zn by 427.8 +/- 93.7 and 301.9 +/- 75.4% during AM and PM immersions, respectively, compared with preimmersion. Urine flow and K excretion were significantly higher during the AM than PM. In summary, when subjects are immersed in cold water for prolonged periods, combined with a slow rate of body cooling afforded by thermal protection and enforced intermittent exercise, there is diuresis, decreased plasma volume, and increased excretions of Na, K, Ca, Mg, and Zn.

  20. Assessing rural small community water supply in Limpopo, South Africa: water service benchmarks and reliability.

    Science.gov (United States)

    Majuru, Batsirai; Jagals, Paul; Hunter, Paul R

    2012-10-01

    Although a number of studies have reported on water supply improvements, few have simultaneously taken into account the reliability of the water services. The study aimed to assess whether upgrading water supply systems in small rural communities improved access, availability and potability of water by assessing the water services against selected benchmarks from the World Health Organisation and South African Department of Water Affairs, and to determine the impact of unreliability on the services. These benchmarks were applied in three rural communities in Limpopo, South Africa where rudimentary water supply services were being upgraded to basic services. Data were collected through structured interviews, observations and measurement, and multi-level linear regression models were used to assess the impact of water service upgrades on key outcome measures of distance to source, daily per capita water quantity and Escherichia coli count. When the basic system was operational, 72% of households met the minimum benchmarks for distance and water quantity, but only 8% met both enhanced benchmarks. During non-operational periods of the basic service, daily per capita water consumption decreased by 5.19l (pwater sources were 639 m further (p ≤ 0.001, 95% CI 560-718). Although both rudimentary and basic systems delivered water that met potability criteria at the sources, the quality of stored water sampled in the home was still unacceptable throughout the various service levels. These results show that basic water services can make substantial improvements to water access, availability, potability, but only if such services are reliable. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Support effects and catalytic trends for water gas shift activity of transition metals

    DEFF Research Database (Denmark)

    Boisen, Astrid; Janssens, T.V.W.; Schumacher, Nana Maria Pii

    2010-01-01

    Water gas shift activity measurements for 12 transition metals (Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Re, Ir, Pt, Au) supported on inert MgAl2O4 and Ce0.75Zr0.25O2 are presented, to elucidate the influence of the active metal and the support. The activity is related to the adsorption energy of molecular...... activity on the MgAl2O4 support and are both characterized by weak CO adsorption. For the MgAl2O4-supported catalysts a volcano-type relation between the activity and the adsorption energy of atomic oxygen on the metal is obtained. The maximum activity is found for metals with a binding energy of oxygen...... around −2.5 eV. No clear correlation exists with the adsorption energy of CO. In contrast, the activity for the Ce0.75Zr0.25O2 support increases with increasing adsorption strength for CO, and based on a relatively low activity of Cu the activity does not seem to depend on the adsorption energy of oxygen...

  2. LYAPUNOV-Based Sensor Failure Detection and Recovery for the Reverse Water Gas Shift Process

    Science.gov (United States)

    Haralambous, Michael G.

    2002-01-01

    Livingstone, a model-based AI software system, is planned for use in the autonomous fault diagnosis, reconfiguration, and control of the oxygen-producing reverse water gas shift (RWGS) process test-bed located in the Applied Chemistry Laboratory at KSC. In this report the RWGS process is first briefly described and an overview of Livingstone is given. Next, a Lyapunov-based approach for detecting and recovering from sensor failures, differing significantly from that used by Livingstone, is presented. In this new method, models used are in t e m of the defining differential equations of system components, thus differing from the qualitative, static models used by Livingstone. An easily computed scalar inequality constraint, expressed in terms of sensed system variables, is used to determine the existence of sensor failures. In the event of sensor failure, an observer/estimator is used for determining which sensors have failed. The theory underlying the new approach is developed. Finally, a recommendation is made to use the Lyapunov-based approach to complement the capability of Livingstone and to use this combination in the RWGS process.

  3. Advanced gasifier and water gas shift technologies for low cost coal conversion to high hydrogen syngas

    Energy Technology Data Exchange (ETDEWEB)

    Kramer, Andrew Kramer [Gas Technology Inst., Des Plaines, IL (United States)

    2016-09-30

    The Gas Technology Institute (GTI) and team members RTI International (RTI), Coanda Research and Development, and Nexant, are developing and maturing a portfolio of technologies to meet the United States Department of Energy (DOE) goals for lowering the cost of producing high hydrogen syngas from coal for use in carbon capture power and coal-to-liquids/chemicals. This project matured an advanced pilot-scale gasifier, with scalable and commercially traceable components, to readiness for use in a first-of-a-kind commercially-relevant demonstration plant on the scale of 500-1,000 tons per day (TPD). This was accomplished through cold flow simulation of the gasifier quench zone transition region at Coanda and through an extensive hotfire gasifier test program on highly reactive coal and high ash/high ash fusion temperature coals at GTI. RTI matured an advanced water gas shift process and catalyst to readiness for testing at pilot plant scale through catalyst development and testing, and development of a preliminary design basis for a pilot scale reactor demonstrating the catalyst. A techno-economic analysis was performed by Nexant to assess the potential benefits of the gasifier and catalyst technologies in the context of power production and methanol production. This analysis showed an 18%reduction in cost of power and a 19%reduction in cost of methanol relative to DOE reference baseline cases.

  4. Graphite-moderated and heavy water-moderated spectral shift controlled reactors; Reactores de moderador solido controlados por desplazamiento espectral

    Energy Technology Data Exchange (ETDEWEB)

    Alcala Ruiz, F

    1984-07-01

    It has been studied the physical mechanisms related with the spectral shift control method and their general positive effects on economical and non-proliferant aspects (extension of the fuel cycle length and low proliferation index). This methods has been extended to non-hydrogenous fuel cells of high moderator/fuel ratio: heavy water cells have been con- trolled by graphite rods graphite-moderated and gas-cooled cells have been controlled by berylium rods and graphite-moderated and water-cooled cells have been controlled by a changing mixture of heavy and light water. It has been carried out neutron and thermal analysis on a pre design of these types of fuel cells. We have studied its neutron optimization and their fuel cycles, temperature coefficients and proliferation indices. Finally, we have carried out a comparative analysis of the fuel cycles of conventionally controlled PWRs and graphite-moderated, water-cooled and spectral shift controlled reactors. (Author) 71 refs.

  5. Small scale lithium-lead/water-interaction studies

    International Nuclear Information System (INIS)

    Kranert, O.; Kottowski, H.

    1991-01-01

    One current concept in fusion blanket design is to utilize water as the coolant and liquid lithium-lead as the breeding/neutron multiplier material. Considering the complex design of the blanket module, it is likely that a water leakage into the liquid alloy may occur due to a tube rupture provoking an intolerable pressure increase in the blanket module. The pressure increase is caused by the combined chemical and thermohydraulic reaction of lithium-lead with water. Experiments which simulate such a transient event are necessary to obtain information which is important for the blanket module design. The interaction has been investigated by conducting small-scale experiments at various injection pressures, alloy- and coolant temperatures. Besides using eutectic Li 17 Pb 83 , Li 7 Pb 2 , lithium and lead have been used. Among other results, the experiments indicate increasing chemical reaction with increasing lithium concentration. At the same time, the chemical reaction inhibits violent thermohydaulic reactions due to the attenuating effect of the hydrogen produced. The preliminary epxerimental results from Li 17 Pb 83 and Li 7 Pb 2 reveal that the pressure- and temperature transients caused by the chemical and thermohydraulic reactions lie within technically manageable limits. (orig.)

  6. GW and Bethe-Salpeter study of small water clusters

    Energy Technology Data Exchange (ETDEWEB)

    Blase, Xavier, E-mail: xavier.blase@neel.cnrs.fr; Boulanger, Paul [CNRS, Institut NEEL, F-38042 Grenoble (France); Bruneval, Fabien [CEA, DEN, Service de Recherches de Métallurgie Physique, F-91191 Gif-sur-Yvette (France); Fernandez-Serra, Marivi [Department of Physics and Astronomy, Stony Brook University, Stony Brook, New York 11794-3800 (United States); Institute for Advanced Computational Sciences, Stony Brook University, Stony Brook, New York 11794-3800 (United States); Duchemin, Ivan [INAC, SP2M/L-Sim, CEA/UJF Cedex 09, 38054 Grenoble (France)

    2016-01-21

    We study within the GW and Bethe-Salpeter many-body perturbation theories the electronic and optical properties of small (H{sub 2}O){sub n} water clusters (n = 1-6). Comparison with high-level CCSD(T) Coupled-Cluster at the Single Double (Triple) levels and ADC(3) Green’s function third order algebraic diagrammatic construction calculations indicates that the standard non-self-consistent G{sub 0}W{sub 0}@PBE or G{sub 0}W{sub 0}@PBE0 approaches significantly underestimate the ionization energy by about 1.1 eV and 0.5 eV, respectively. Consequently, the related Bethe-Salpeter lowest optical excitations are found to be located much too low in energy when building transitions from a non-self-consistent G{sub 0}W{sub 0} description of the quasiparticle spectrum. Simple self-consistent schemes, with update of the eigenvalues only, are shown to provide a weak dependence on the Kohn-Sham starting point and a much better agreement with reference calculations. The present findings rationalize the theory to experiment possible discrepancies observed in previous G{sub 0}W{sub 0} and Bethe-Salpeter studies of bulk water. The increase of the optical gap with increasing cluster size is consistent with the evolution from gas to dense ice or water phases and results from an enhanced screening of the electron-hole interaction.

  7. Chemisorption of H2O and CO2 on hydrotalcites for sorptionenhanced water-gas-shift processes

    NARCIS (Netherlands)

    Coenen, K.T.; Gallucci, F.; Cobden, P.; van Dijk, E; Hensen, E.J.M.; van Sint Annaland, M.

    2017-01-01

    Thermogravimetric analysis and breakthrough experiments in a packed bed reactor were used to validate a developed adsorption model to describe the cyclic working capacity of CO2 and H2O on a potassium-promoted hydrotalcite, a very promising adsorbent for sorption-enhanced water-gas-shift

  8. Chemisorption of H2O and CO2 on hydrotalcites for sorptionenhanced water-gas-shift processes

    NARCIS (Netherlands)

    Coenen, K.T.; Gallucci, F.; Cobden, P.; van Dijk, E.; Hensen, E.J.M.; van Sint Annaland, M.

    2016-01-01

    Thermogravimetric analysis and breakthrough experiments in a packed bed reactor were used to validate a developed adsorption model to describe the cyclic working capacity of CO¬2 and H2O on a potassium-promoted hydrotalcite, a very promising adsorbent for sorption-enhanced water-gas-shift

  9. The production of hydrogen through the use of a 77 wt% Pd 23 wt% Ag membrane water gas shift reactor

    CSIR Research Space (South Africa)

    Baloyi, Liberty N

    2016-12-01

    Full Text Available stainless steel (PSS) is evaluated for the production of hydrogen and the potential replacement of the current two-stage Water-Gas Shift (WGS) reaction by a single stage reaction. The permeability of a 20 µm Pd–Ag membrane reactor was examined at 320 °C, 380...

  10. Investigation on the combined operation of water gas shift and preferential oxidation reactor system on the kW scale

    NARCIS (Netherlands)

    O'Connell, M.; Kolb, G.A.; Schelhaas, K.P.; Schuerer, J.; Tiemann, D.; Keller, S.; Reinhard, D.; Hessel, V.

    2010-01-01

    A 5 kWel water gas shift reactor was integrated with a 5 kWel preferential oxidation reactor for the purposes of reducing the carbon monoxide levels in a reformate exit stream to levels below 100 ppm. The integrated system worked best at partial load with CO concentrations being reduced to 40 ppm at

  11. Water-gas shift (WGS) Operation of Pre-combustion CO2 Capture Pilot Plant at the Buggenum IGCC

    NARCIS (Netherlands)

    Van Dijk, H.A.J.; Damen, K.; Makkee, M.; Trapp, C.

    2014-01-01

    In the Nuon/Vattenfall CO2 Catch-up project, a pre-combustion CO2 capture pilot plant was built and operated at the Buggenum IGCC power plant, the Netherlands. The pilot consist of sweet water-gas shift, physical CO2 absorption and CO2 compression. The technology performance was verified and

  12. Smart solar tanks for small solar domestic hot water systems

    DEFF Research Database (Denmark)

    Furbo, Simon; Andersen, Elsa; Knudsen, Søren

    2005-01-01

    Investigation of small SDHW systems based on smart solar tanks are presented. The domestic water in a smart solar tank can be heated both by solar collectors and by means of an auxiliary energy supply system. The auxiliary energy supply system – in this study electric heating elements – heats up...... systems, based on differently designed smart solar tanks and a traditional SDHW system were investigated by means of laboratory experiments and theoretical calculations. The investigations showed that the yearly thermal performance of SDHW systems with smart solar tanks is 5-35% higher than the thermal...... performance of traditional SDHW systems. Estimates indicate that the performance/cost ratio can be improved by up to 25% by using a smart solar tank instead of a traditional tank when the backup energy system is electric heating elements. Further, smart solar tanks are suitable for unknown, variable, large...

  13. Large shift and small broadening of Br2 valence band upon dimer formation with H2O: an ab initio study.

    Science.gov (United States)

    Franklin-Mergarejo, Ricardo; Rubayo-Soneira, Jesus; Halberstadt, Nadine; Ayed, Tahra; Bernal-Uruchurtu, Margarita I; Hernández-Lamoneda, Ramón; Janda, Kenneth C

    2011-06-16

    Valence electronic excitation spectra are calculated for the H(2)O···Br(2) complex using highly correlated ab initio potentials for both the ground and the valence electronic excited states and a 2-D approximation for vibrational motion. Due to the strong interaction between the O-Br and the Br-Br stretching motions, inclusion of these vibrations is the minimum necessary for the spectrum calculation. A basis set calculation is performed to determine the vibrational wave functions for the ground electronic state and a wave packet simulation is conducted for the nuclear dynamics on the excited state surfaces. The effects of both the spin-orbit interaction and temperature on the spectra are explored. The interaction of Br(2) with a single water molecule induces nearly as large a shift in the spectrum as is observed for an aqueous solution. In contrast, complex formation has a remarkably small effect on the T = 0 K width of the valence bands due to the fast dissociation of the dihalogen bond upon excitation. We therefore conclude that the widths of the spectra in aqueous solution are mostly due to inhomogeneous broadening. © 2011 American Chemical Society

  14. Prevalence of permanent hearing threshold shift among workers of Indian iron and steel small and medium enterprises: a study.

    Science.gov (United States)

    Singh, Lakhwinder Pal; Bhardwaj, Arvind; Kumar, Deepak Kishore

    2012-01-01

    Occupational noise exposure and noise-induced hearing loss (NIHL) have been recognized as a problem among workers in Indian industries. The major industries in India are based on manufacturing. There are appreciable numbers of casting and forging units spread across the country. The objective of this study is to determine the prevalence of permanent hearing threshold shift among the workers engaged in Indian iron and steel small and medium enterprises (SMEs) and compared with control group subjects. As a part of hearing protection intervention, audiometric tests were conducted at low (250-1000 Hz), medium (1500-3000 Hz), and high (4000-8000 Hz) frequencies. The occurrence of hearing loss was determined based on hearing threshold levels with a low fence of 25 dB. Comparisons were made for hearing threshold at different frequencies between the exposed and control groups using Student's t test. ANOVA was used for the comparison of hearing threshold dB at different frequencies among occupation and year of experience. A P value workers engaged in various processes of casting and forging industry showed hearing loss in the noise-sensitive medium and higher frequencies. Occupation was significantly associated with NIHL, and hearing loss was particularly high among the workers of forging section. The analyses revealed a higher prevalence of significant hearing loss among the forging workers compared to the workers associated with other activities. The study shows alarming signals of NIHL, especially in forging workers. The occupational exposure to noise could be minimized by efficient control measures through engineering controls, administrative controls, and the use of personal protective devices. Applications of engineering and/or administrative controls are frequently not feasible in the developing countries for technical and financial reasons. A complete hearing conservation programme, including training, audiometry, job rotation, and the use of hearing protection

  15. Simulation of water flows in multiple columns with small outlets

    International Nuclear Information System (INIS)

    Suh, Yong Kweon; Li, Zi Lu; Jeong, Jong Hyun; Lee, Jun Hee

    2006-01-01

    High-pressure die casting such as thixocasting and rheocasting is an effective process in the manufacturing automotive parts. Following the recent trend in the automotive manufacturing technologies, the product design subject to the die casting becomes more and more complex. Simultaneously the injection speed is also designed to be very high to establish a short cycle-time. Thus, the requirement of the die design becomes more demanding than ever before. In some cases the product's shape can have multiple slender manifolds. In such cases, design of the inlet and outlet parts of the die is very important in the whole manufacturing process. The main issues required for the qualified products are to attain gentle and uniform flow of the molten liquid within the passages of the die. To satisfy such issues, the inlet cylinder ('bed cylinder' in this paper) must be as large as possible and simultaneously the outlet opening at the end of each passage must be as small as possible. However these in turn obviously bring additional manufacturing costs caused by re-melting of the bed cylinder and increased power due to the small outlet-openings. The purpose of this paper is to develop effective simulation methods of calculation for fluid flows in multiple columns, which mimic the actual complex design, and to get some useful information which can give some contributions to the die-casting industry. We have used a commercial code CFX in the numerical simulation. The primary parameter involved is the size of the bed cylinder. We will show how the very small opening of the outlet can be treated with the aid of the porous model provided in the code. To check the validity of the numerical results we have also conducted a simple experiment by using water

  16. SiC-BASED HYDROGEN SELECTIVE MEMBRANES FOR WATER-GAS-SHIFT REACTION; F

    International Nuclear Information System (INIS)

    Paul K.T. Liu

    2001-01-01

    This technical report summarizes our activities conducted in Yr II. In Yr I we successfully demonstrated the feasibility of preparing the hydrogen selective SiC membrane with a chemical vapor deposition (CVD) technique. In addition, a SiC macroporous membrane was fabricated as a substrate candidate for the proposed SiC membrane. In Yr II we have focused on the development of a microporous SiC membrane as an intermediate layer between the substrate and the final membrane layer prepared from CVD. Powders and supported thin silicon carbide films (membranes) were prepared by a sol-gel technique using silica sol precursors as the source of silicon, and phenolic resin as the source of carbon. The powders and films were prepared by the carbothermal reduction reaction between the silica and the carbon source. The XRD analysis indicates that the powders and films consist of SiC, while the surface area measurement indicates that they contain micropores. SEM and AFM studies of the same films also validate this observation. The powders and membranes were also stable under different corrosive and harsh environments. The effects of these different treatments on the internal surface area, pore size distribution, and transport properties, were studied for both the powders and the membranes using the aforementioned techniques and XPS. Finally the SiC membrane materials are shown to have satisfactory hydrothermal stability for the proposed application. In Yr III, we will focus on the demonstration of the potential benefit using the SiC membrane developed from Yr I and II for the water-gas-shift (WGS) reaction

  17. Integrated Water Gas Shift Membrane Reactors Utilizing Novel, Non Precious Metal Mixed Matrix Membrane

    Energy Technology Data Exchange (ETDEWEB)

    Ferraris, John P. [Univ. of Texas-Dallas, Richardson, TX (United States). Dept. of Chemistry

    2013-09-30

    Nanoparticles of zeolitic imidazolate frameworks and other related hybrid materials were prepared by modifying published synthesis procedures by introducing bases, changing stoichiometric ratios, or adjusting reaction conditions. These materials were stable at temperatures >300 °C and were compatible with the polymer matrices used to prepare mixed- matrix membranes (MMMs). MMMs tested at 300 °C exhibited a >30 fold increase in permeability, compared to those measured at 35 °C, while maintaining H2/CO2 selectivity. Measurements at high pressure (up to 30 atm) and high temperature (up to 300 °C) resulted in an increase in gas flux across the membrane with retention of selectivity. No variations in permeability were observed at high pressures at either 35 or 300 °C. CO2-induced plasticization was not observed for Matrimid®, VTEC, and PBI polymers or their MMMs at 30 atm and 300 °C. Membrane surface modification by cross-linking with ethanol diamine resulted in an increase in H2/CO2 selectivity at 35 °C. Spectrometric analysis showed that the cross-linking was effective to temperatures <150 °C. At higher temperatures, the cross-linked membranes exhibit a H2/CO2 selectivity similar to the uncross-linked polymer. Performance of the polybenzimidazole (PBI) hollow fibers prepared at Santa Fe Science and Technology (SFST, Inc.) showed increased flux and selectivity at 300 °C, which is comparable to a flat PBI membrane. A water-gas shift reactor has been built and currently being optimized for testing under DOE conditions.

  18. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    Energy Technology Data Exchange (ETDEWEB)

    Barton, Tom [Western Research Inst. (WRI), Laramie, WY (United States)

    2013-09-01

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  19. Small drinking water systems under spatiotemporal water quality variability: a risk-based performance benchmarking framework.

    Science.gov (United States)

    Bereskie, Ty; Haider, Husnain; Rodriguez, Manuel J; Sadiq, Rehan

    2017-08-23

    Traditional approaches for benchmarking drinking water systems are binary, based solely on the compliance and/or non-compliance of one or more water quality performance indicators against defined regulatory guidelines/standards. The consequence of water quality failure is dependent on location within a water supply system as well as time of the year (i.e., season) with varying levels of water consumption. Conventional approaches used for water quality comparison purposes fail to incorporate spatiotemporal variability and degrees of compliance and/or non-compliance. This can lead to misleading or inaccurate performance assessment data used in the performance benchmarking process. In this research, a hierarchical risk-based water quality performance benchmarking framework is proposed to evaluate small drinking water systems (SDWSs) through cross-comparison amongst similar systems. The proposed framework (R WQI framework) is designed to quantify consequence associated with seasonal and location-specific water quality issues in a given drinking water supply system to facilitate more efficient decision-making for SDWSs striving for continuous performance improvement. Fuzzy rule-based modelling is used to address imprecision associated with measuring performance based on singular water quality guidelines/standards and the uncertainties present in SDWS operations and monitoring. This proposed R WQI framework has been demonstrated using data collected from 16 SDWSs in Newfoundland and Labrador and Quebec, Canada, and compared to the Canadian Council of Ministers of the Environment WQI, a traditional, guidelines/standard-based approach. The study found that the R WQI framework provides an in-depth state of water quality and benchmarks SDWSs more rationally based on the frequency of occurrence and consequence of failure events.

  20. How to build a small ferro-cement water tank: technical guide

    CSIR Research Space (South Africa)

    Sadzik, P

    1988-05-01

    Full Text Available This guide will assist on how to build a small water tank which can be used to store spring water, rainwater or water pumped from a stream or dam. Small water tanks can be constructed from many different materials such as corrugated iron, bricks...

  1. The Politics of Pipes: The Persistence of Small Water Networks in Post-Privatization Manila

    Science.gov (United States)

    Cheng, Deborah

    This project examines the politics of water provision in low-income areas of large, developing cities. In the last two decades, water privatization has become a global paradigm, emerging as a potential means for addressing the urban water crisis. In Manila, the site of the world's largest water privatization project, service to low-income areas has improved significantly in the post-privatization era. But whereas expansion of a water utility typically involves the replacement of informal providers, the experience in Manila demonstrates that the rapid connection of low-income areas actually hinges, in part, on the selective inclusion and exclusion of these smaller actors. Based on an ethnography of the private utilities and community-based providers, I use the persistence of small water networks as a lens for exploring the limits of water privatization in Manila. I focus on what I call micro-networks---community-built infrastructure that extends the formal, private utilities into low-income neighborhoods that the utilities do not wish to serve directly. In such a setup, the utility provides water only as far as the community boundary; beyond that, the micro-network operator constructs internal infrastructure, monitors for leakage and theft, and collects bills. But while these communities may gain access to safer water, they are also subject to higher costs and heightened disciplinary measures. By tracing the ways in which the utilities selectively use micro-networks to manage sub-populations, I show how the utilities make low-income spaces more governable. Delegating localized water management to micro-network operators depoliticizes the utilities' roles, shifting the sociopolitical difficulties of water provision to community organizations, while allowing the utilities to claim that these areas are served. This research leads to three related arguments. First, the persistence of small water networks highlights lingering inequities in access to water, for micro

  2. Analysis of the Sodium-Water Reaction Phenomena by Small Water/Steam Leaks

    International Nuclear Information System (INIS)

    Jeong, J-Y; Kim, T-J; Kim, J-M; Kim, B-H; Park, N-C

    2006-01-01

    One of the important problems to be solved in the design and construction of a sodium cooled fast reactor is to confirm the safety and reliability of the steam generator which transfers the heat from the sodium to the water. Sodium-water reaction events may occur when material faults such as a pinhole or cracks occur in the heat transfer tube wall. When such a leak occurs, evaporating water or superheated steam enters through a small leak into the sodium. The surface of this steam jet reacts with the surrounding sodium. Due to turbulence, sodium and particles of the reaction products are drawn at a high velocity into the jet. Impingement of these particles on an adjacent tube is followed by a combined process of a corrosion and erosion which results in a local weakening of the affected tube. If there is no reliable detection available in time, wastage will ultimately result in an additional leak in the adjacent tube. Therefore, it is very significant to predict these phenomena quantitatively from the view of designing a steam generator and its leak detection systems. The objective of this study is a basic investigating of the sodium-water reaction phenomena by small water/steam leaks

  3. Origin of the blue shift of the CH stretching band for 2-butoxyethanol in water.

    Science.gov (United States)

    Katsumoto, Yukiteru; Komatsu, Hiroyuki; Ohno, Keiichi

    2006-07-26

    The blue shift of the isolated CD stretching band of 2-butoxyethanol (C4E1), which is observed for the aqueous solution during the dilution process, has been investigated by infrared (IR) spectroscopy and quantum chemical calculations. Mono-deuterium-labeled C4E1's were employed to remove the severe overlapping among the CH stretching bands. The isolated CD stretching mode of the alpha-methylene in the butoxy group shows a large blue shift, while those of the beta-methylene and methyl groups are not largely shifted. The spectral simulation results for the C4E1/H2O complexes indicate that the large blue shift of the CD stretching band of the butoxy group arises mainly from the hydration of the ether oxygen atom.

  4. Water-Gas Shift and CO Methanation Reactions over Ni-CeO2(111) Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    S Senanayake; J Evans; S Agnoli; L Barrio; T Chen; J Hrbek; J Rodriguez

    2011-12-31

    X-ray and ultraviolet photoelectron spectroscopies were used to study the interaction of Ni atoms with CeO{sub 2}(111) surfaces. Upon adsorption on CeO{sub 2}(111) at 300 K, nickel remains in a metallic state. Heating to elevated temperatures (500-800 K) leads to partial reduction of the ceria substrate with the formation of Ni{sup 2+} species that exists as NiO and/or Ce{sub 1-x}Ni{sub x}O{sub 2-y}. Interactions of nickel with the oxide substrate significantly reduce the density of occupied Ni 3d states near the Fermi level. The results of core-level photoemission and near-edge X-ray absorption fine structure point to weakly bound CO species on CeO{sub 2}(111) which are clearly distinguishable from the formation of chemisorbed carbonates. In the presence of Ni, a stronger interaction is observed with chemisorption of CO on the admetal. When the Ni is in contact with Ce{sup +3} cations, CO dissociates on the surface at 300 K forming NiC{sub x} compounds that may be involved in the formation of CH{sub 4} at higher temperatures. At medium and large Ni coverages (>0.3 ML), the Ni/CeO{sub 2}(111) surfaces are able to catalyze the production of methane from CO and H{sub 2}, with an activity slightly higher than that of Ni(100) or Ni(111). On the other hand, at small coverages of Ni (<0.3 ML), the Ni/CeO{sub 2}(111) surfaces exhibit a very low activity for CO methanation but are very good catalysts for the water-gas shift reaction.

  5. Prevalence of permanent hearing threshold shift among workers of Indian iron and steel small and medium enterprises: A study

    Directory of Open Access Journals (Sweden)

    Lakhwinder Pal Singh

    2012-01-01

    Full Text Available Occupational noise exposure and noise-induced hearing loss (NIHL have been recognized as a problem among workers in Indian industries. The major industries in India are based on manufacturing. There are appreciable numbers of casting and forging units spread across the country. The objective of this study is to determine the prevalence of permanent hearing threshold shift among the workers engaged in Indian iron and steel small and medium enterprises (SMEs and compared with control group subjects. As a part of hearing protection intervention, audiometric tests were conducted at low (250-1000 Hz, medium (1500-3000 Hz, and high (4000-8000 Hz frequencies. The occurrence of hearing loss was determined based on hearing threshold levels with a low fence of 25 dB. Comparisons were made for hearing threshold at different frequencies between the exposed and control groups using Student′s t test. ANOVA was used for the comparison of hearing threshold dB at different frequencies among occupation and year of experience. A P value <0.05 was considered as statistically significant. All data were presented as mean value (SD. Over 90% of workers engaged in various processes of casting and forging industry showed hearing loss in the noise-sensitive medium and higher frequencies. Occupation was significantly associated with NIHL, and hearing loss was particularly high among the workers of forging section. The analyses revealed a higher prevalence of significant hearing loss among the forging workers compared to the workers associated with other activities. The study shows alarming signals of NIHL, especially in forging workers. The occupational exposure to noise could be minimized by efficient control measures through engineering controls, administrative controls, and the use of personal protective devices. Applications of engineering and/or administrative controls are frequently not feasible in the developing countries for technical and financial reasons. A

  6. Potential Impacts of Organic Wastes on Small Stream Water Quality

    Science.gov (United States)

    Kaushal, S. S.; Groffman, P. M.; Findlay, S. E.; Fischer, D. T.; Burke, R. A.; Molinero, J.

    2005-05-01

    We monitored concentrations of dissolved organic carbon (DOC), dissolved oxygen (DO) and other parameters in 17 small streams of the South Fork Broad River (SFBR) watershed on a monthly basis for 15 months. The subwatersheds were chosen to reflect a range of land uses including forested, pasture, mixed, and developed. The SFBR watershed is heavily impacted by organic wastes, primarily from its large poultry industry, but also from its rapidly growing human population. The poultry litter is primarily disposed of by application to pastures. Our monthly monitoring results showed a strong inverse relationship between mean DOC and mean DO and suggested that concentrations of total nitrogen (TN), DOC, and the trace gases nitrous oxide, methane and carbon dioxide are impacted by organic wastes and/or nutrients from animal manure applied to the land and/or human wastes from wastewater treatment plants or septic tanks in these watersheds. Here we estimate the organic waste loads of these watersheds and evaluate the impact of organic wastes on stream DOC and alkalinity concentrations, electrical conductivity, sediment potential denitrification rate and plant stable nitrogen isotope ratios. All of these water quality parameters are significantly correlated with watershed waste loading. DOC is most strongly correlated with total watershed waste loading whereas conductivity, alkalinity, potential denitrification rate and plant stable nitrogen isotope ratio are most strongly correlated with watershed human waste loading. These results suggest that more direct inputs (e.g., wastewater treatment plant effluents, near-stream septic tanks) have a greater relative impact on stream water quality than more dispersed inputs (land applied poultry litter, septic tanks far from streams) in the SFBR watershed. Conductivity, which is generally elevated in organic wastes, is also significantly correlated with total watershed waste loading suggesting it may be a useful indicator of overall

  7. A further step toward H2 in automobile : development of an efficient bi-functional catalyst for single stage water gas shift

    NARCIS (Netherlands)

    Azzam, K.G.H.

    2008-01-01

    The suitability of polymer electrolyte fuel (PEM) cells for stationary and vehicular applications initiated research in all areas of fuel processor (i.e. reformer, water-gas-shift, preferential oxidation of CO (PROX)) catalysts for hydrogen generation. Water gas shift (WGS) reaction is an essential

  8. Shifts in microbial community structure and function in surface waters impacted by unconventional oil and gas wastewater revealed by metagenomics

    Science.gov (United States)

    Fahrenfeld, N.L.; Reyes, Hannah Delos; Eramo, Alessia; Akob, Denise M.; Mumford, Adam; Cozzarelli, Isabelle M.

    2017-01-01

    Unconventional oil and gas (UOG) production produces large quantities of wastewater with complex geochemistry and largely uncharacterized impacts on surface waters. In this study, we assessed shifts in microbial community structure and function in sediments and waters upstream and downstream from a UOG wastewater disposal facility. To do this, quantitative PCR for 16S rRNA and antibiotic resistance genes along with metagenomic sequencing were performed. Elevated conductivity and markers of UOG wastewater characterized sites sampled downstream from the disposal facility compared to background sites. Shifts in overall high level functions and microbial community structure were observed between background sites and downstream sediments. Increases in Deltaproteobacteria and Methanomicrobia and decreases in Thaumarchaeota were observed at downstream sites. Genes related to dormancy and sporulation and methanogenic respiration were 18–86 times higher at downstream, impacted sites. The potential for these sediments to serve as reservoirs of antimicrobial resistance was investigated given frequent reports of the use of biocides to control the growth of nuisance bacteria in UOG operations. A shift in resistance profiles downstream of the UOG facility was observed including increases in acrB and mexB genes encoding for multidrug efflux pumps, but not overall abundance of resistance genes. The observed shifts in microbial community structure and potential function indicate changes in respiration, nutrient cycling, and markers of stress in a stream impacted by UOG waste disposal operations.

  9. Evaluating the energy and CO2 emissions impacts of shifts in residential water heating in the United States

    International Nuclear Information System (INIS)

    Sanders, Kelly T.; Webber, Michael E.

    2015-01-01

    Water heating represented nearly 13% of 2010 residential energy consumption making it an important target for energy conservation efforts. The objective of this work is to identify spatially-resolved strategies for energy conservation, since little analysis has been done to identify how regional characteristics affect the energy consumed for water heating. We present a first-order thermodynamic analysis, utilizing ab initio calculations and regression methods, to quantify primary energy consumption and CO 2 emissions with regional specificity by considering by considering local electricity mixes, heat rates, solar radiation profiles, heating degrees days, and water heating unit sales for 27 regions of the US. Results suggest that shifting from electric towards natural gas or solar water heating offered primary energy and CO 2 emission reductions in most US regions, but these reductions varied considerably according to regional electricity mix and solar resources. We find that regions that would benefit most from technology transitions, are often least likely to switch due to limited economic incentives. Our results suggest that federal energy factor metrics, which ignore upstream losses in power generation, are insufficient in informing consumers about the energy performance of residential end use appliances. - Highlights: • US energy factor ratings for water heaters ignore upstream losses. • Switching from electric storage water heating reduces CO 2 emissions in most US regions. • Regions with greatest potential for CO 2 avoidance are least likely to shift technologies. • Benefits vary significantly according to climate and regional electricity fuel mix

  10. Hydraulic Network Modelling of Small Community Water Distribution ...

    African Journals Online (AJOL)

    Prof Anyata

    community (Sakwa) water distribution network in North Eastern geopolitical region of Nigeria using. WaterCAD ..... Table 1: Criteria Relating Population to Water Demand (NWSP, 2000) ..... timely manner ... Department, Middle East Technical.

  11. CFD and FEM thermo-mechanical design of a recuperative-dissipative heat exchanger for a laboratory water gas shift reactor

    Energy Technology Data Exchange (ETDEWEB)

    Michele Vascellari; Stefano Sollai; Pier Francesco Orru; Giorgio Cau [University of Cagliari, Cagliari (Italy). Department of Mechanical Engineering

    2007-07-01

    A small scale test rig based on a two-stage reactor for testing water gas shift conversion processes has been set up at the Department of Mechanical Engineering at the University of Cagliari, chiefly for the purpose of supporting a pilot plant operation for high sulphur (Sulcis) coal gasification, gas cleaning and treatment, CO{sub 2} separation, hydrogen and electricity production. The laboratory test rig comprises two packed-bed reactors in series to be operated at different temperatures and has been designed for testing CO-shift conversion processes using a variety of catalysts for different syngas temperatures (up to 500{sup o}C) and compositions. One critical component of the system is a recuperative-dissipative heat exchanger placed between the two reactors. The heat exchanger, which preheats the syngas prior to entering the high temperature reactor and cools the shifted gas exiting there from, prior to its entering the low temperature reactor, is subjected to severe thermo-mechanical stress. Thus the design and analysis of this component, described herein, is a critical issue. A full 3D conjugate heat transfer CFD analysis of the tubular heat exchanger has been performed, considering different geometries. Based on the CFD results we were able to verify the preliminary design of the component, carried out using simple thermal correlations and to predict wall temperature distribution for the thermo-structural analysis. 10 refs., 10 figs., 2 tabs.

  12. In Situ UV-Visible Assessment of Iron-Based High-Temperature Water-Gas Shift Catalysts Promoted with Lanthana: An Extent of Reduction Study

    Directory of Open Access Journals (Sweden)

    Basseem B. Hallac

    2018-02-01

    Full Text Available The extent of reduction of unsupported iron-based high-temperature water-gas shift catalysts with small (<5 wt % lanthana contents was studied using UV-visible spectroscopy. Temperature- programmed reduction measurements showed that lanthana content higher than 0.5 wt % increased the extent of reduction to metallic Fe, while 0.5 wt % of lanthana facilitated the reduction to Fe3O4. In situ measurements on the iron oxide catalysts using mass and UV-visible spectroscopies permitted the quantification of the extent of reduction under temperature-programmed reduction and high-temperature water-gas shift conditions. The oxidation states were successfully calibrated against normalized absorbance spectra of visible light using the Kubelka-Munk theory. The normalized absorbance relative to the fully oxidized Fe2O3 increased as the extent of reduction increased. XANES suggested that the average bulk iron oxidation state during the water-gas shift reaction was Fe+2.57 for the catalyst with no lanthana and Fe+2.54 for the catalysts with 1 wt % lanthana. However, the UV-vis spectra suggest that the surface oxidation state of iron would be Fe+2.31 for the catalyst with 1 wt % lanthana if the oxidation state of iron in the catalyst with 0 wt % lanthana were Fe+2.57. The findings of this paper emphasize the importance of surface sensitive UV-visible spectroscopy for determining the extent of catalyst reduction during operation. The paper highlights the potential to use bench-scale UV-visible spectroscopy to study the surface chemistry of catalysts instead of less-available synchrotron X-ray radiation facilities.

  13. Irrigation Water Value at Small-scale Schemes: Evidence from the North West Province, South Africa

    NARCIS (Netherlands)

    Speelman, S.; Farolfi, S.; Perret, S.; Haese, D' L.; Haese, D' M.

    2008-01-01

    Insight into the value of water is essential to support policy decision making about investments in the water sector, efficient allocation of water and water pricing. However, information on irrigation water values at small-scale schemes is scarce and in general little attention is paid to the

  14. Pd based ultrathin membranes for the tritiated water gas shift reaction in the ITER breeder recovery system

    International Nuclear Information System (INIS)

    Tosti, S.; Bettinali, L.; Violante, V.; Basile, A.; Chiappetta, M.; Criscuoli, A.; Drioli, E.; Rizzelo, C.

    1998-01-01

    A mathematical model of a catalytic membrane reactor (CMR) for the water gas shift reaction has been carried out. Based on the model, a new closed loop process for the tritium removal system for the ITER test module of helium cooled pebble bed blanket concept has been studied. A CMR is the main equipment of the proposed process. The main advantages of the closed loop process are related to the absence of secondary wastes, low tritium inventories, moderate operating temperatures and pressures, low dilution of the stream to be processed by isotopic separation. As permeating membranes in the CMR ultra-thin metallic membranes of Pd and PdAg (50-70 μm thick) have been studied. A ceramic porous tube, containing the catalyst in the lumen, has been put in the metallic tube to obtain the CMR for the water gas shifting. Experimental tests, carried out both on ultra-thin membranes and CMRs for the water gas shift reaction, confirmed the behavior studied by the theoretical model and showed a long live of the membrane. (authors)

  15. Resilience of the Nexus of Competitive Water Consumption between Human Society and Environment Development: Regime Shifts and Early Warning Signals

    Science.gov (United States)

    Li, Z.; Liu, P.; Feng, M.; Zhang, J.

    2017-12-01

    Based on the modeling of the water supply, power generation and environment (WPE) nexus by Feng et al. (2016), a refined theoretical model of competitive water consumption between human society and environment has been presented in this study, examining the role of technology advancement and social environmental awareness growth-induced pollution mitigation to the environment as a mechanism for the establishment and maintenance of the coexistence of both higher social water consumption and improved environment condition. By coupling environmental and social dynamics, both of which are represented by water consumption quantity, this study shows the possibility of sustainable situation of the social-environmental system when the benefit of technology offsets the side effect (pollution) of social development to the environment. Additionally, regime shifts could be triggered by gradually increased pollution rate, climate change-induced natural resources reduction and breakdown of the social environmental awareness. Therefore, in order to foresee the pending abrupt regime shifts of the system, early warning signals, including increasing variance and autocorrelation, have been examined when the system is undergoing stochastic disturbance. ADDIN EN.REFLIST Feng, M. et al., 2016. Modeling the nexus across water supply, power generation and environment systems using the system dynamics approach: Hehuang Region, China. J. Hydrol., 543: 344-359.

  16. Quantification of surface energy fluxes from a small water body using scintillometry and eddy covariance

    DEFF Research Database (Denmark)

    McGloin, Ryan; McGowan, Hamish; McJannet, David

    2014-01-01

    Accurate quantification of evaporation from small water storages is essential for water management and planning, particularly in water-scarce regions. In order to ascertain suitable methods for direct measurement of evaporation from small water bodies, this study presents a comparison of eddy......% greater than eddy covariance measurements. We suggest possible reasons for this difference and provide recommendations for further research for improving measurements of surface energy fluxes over small water bodies using eddy covariance and scintillometry. Key Points Source areas for Eddy covariance...... and scintillometry were on the water surface Reasonable agreement was shown between the sensible heat flux measurements Scintillometer estimates of latent heat flux were greater than eddy covariance...

  17. Small-scale shifting mosaics of two dominant grassland species: the possible role of soil-borne pathogens

    NARCIS (Netherlands)

    Olff, H.; Hoorens, B.; De Goede, R.G.M.; Van der Putten, W.H.; Gleichman, J.M.

    2000-01-01

    We analyzed the dynamics of dominant plant species in a grazed grassland over 17 years, and investigated whether local shifts in these dominant species, leading to vegetation mosaics, could be attributed to interactions between plants and soil-borne pathogens. We found that Festuca rubra and Carer

  18. Small-scale shifting mosaics of two dominant grassland species : the possible role of soil-borne pathogens

    NARCIS (Netherlands)

    Olff, H.; Hoorens, B.; Goede, R.G.M. de; Putten, W.H. van der; Gleichman, J.M.

    2000-01-01

    We analyzed the dynamics of dominant plant species in a grazed grassland over 17 years, and investigated whether local shifts in these dominant species, leading to vegetation mosaics, could be attributed to interactions between plants and soil-borne pathogens. We found that Festuca rubra and Carex

  19. Radiological characterization for small type light water reactor

    International Nuclear Information System (INIS)

    Tanaka, Ken-ichi; Ichige, Hideaki; Tanabe, Hidenori

    2011-01-01

    In order to plan a decommissioning, amount investigation of waste materials and residual radioactivity inventory evaluation must be performed at the first stage of preparatory tasks. These tasks are called radiological characterization. Reliable information from radiological characterization is crucial for specification of decommissioning plan. With the information, we can perform radiological safety analysis and optimize decommissioning scenario. Japan Atomic Power Company (JAPC) has already started preparatory tasks for Tsuruga Nuclear Power Plant Unit 1 (TS-1) that is the first commercial Small Type Light Water Reactor in Japan. To obtain reliable information about residual radioactivity inventory, we improved radioactivity inventory evaluation procedure. The procedure consists of neutron flux distribution calculation and radioactivity distribution calculation. We need a better understanding about characteristics of neutron transport phenomena in order to obtain reliable neutron flux distribution. Neutron flux was measured in Primary Containment Vessel (PCV) at 30 locations using activation foils. We chose locations where characteristic phenomena can be observed. Three dimensional (3D) neutron flux calculation was also performed to simulate continuous changes of neutron flux distribution. By assessing both the measured values and 3D calculation results, we could perform the calculation that simulates the phenomena well. We got knowledge about how to perform an appropriate neutron flux distribution calculation and also became able to calculate a reliable neutron flux distribution. Using the neutron flux distribution, we can estimate a reliable radioactivity distribution. We applied network-parallel-computing method to the estimation. And further we developed 'flux level approximation method' which use linear or parabola fitting method to estimation. Using these new methods, radioactivity by neutron irradiation, which is radioisotope formation, was calculated at

  20. Multi-Application Small Light Water Reactor Final Report

    International Nuclear Information System (INIS)

    Modro, S.M.; Fisher, J.E.; Weaver, K.D.; Reyes, J.N.; Groome, J.T.; Babka, P.; Carlson, T.M.

    2003-01-01

    The Multi-Application Small Light Water Reactor (MASLWR) project was conducted under the auspices of the Nuclear Energy Research Initiative (NERI) of the U.S. Department of Energy (DOE). The primary project objectives were to develop the conceptual design for a safe and economic small, natural circulation light water reactor, to address the economic and safety attributes of the concept, and to demonstrate the technical feasibility by testing in an integral test facility. This report presents the results of the project. After an initial exploratory and evolutionary process, as documented in the October 2000 report, the project focused on developing a modular reactor design that consists of a self-contained assembly with a reactor vessel, steam generators, and containment. These modular units would be manufactured at a single centralized facility, transported by rail, road, and/or ship, and installed as a series of self-contained units. This approach also allows for staged construction of an NPP and ''pull and replace'' refueling and maintenance during each five-year refueling cycle. Development of the baseline design concept has been sufficiently completed to determine that it complies with the safety requirements and criteria, and satisfies the major goals already noted. The more significant features of the baseline single-unit design concept include: (1) Thermal Power--150 MWt; (2) Net Electrical Output--35 MWe; (3) Steam Generator Type--Vertical, helical tubes; (4) Fuel UO 2 , 8% enriched; (5) Refueling Intervals--5 years; (6) Life-Cycle--60 years. The economic performance was assessed by designing a power plant with an electric generation capacity in the range of current and advanced evolutionary systems. This approach allows for direct comparison of economic performance and forms a basis for further evaluation, economic and technical, of the proposed design and for the design evolution towards a more cost competitive concept. Applications such as cogeneration

  1. On the slowdown mechanism of water dynamics around small amphiphiles

    NARCIS (Netherlands)

    Homsi Brandeburgo, W.; Thijmen van der Post, S.; Meijer, E.J.; Ensing, B.

    2015-01-01

    Aqueous solvation of small amphiphilic molecules exhibits a unique and complex dynamics, that is only partially understood. A recent series of studies on the hydration of small organic compounds, such as tetramethylurea (TMU), trimethylamine N-oxide (TMAO) and urea, has provided strong evidence of a

  2. Free water transport, small pore transport and the osmotic pressure gradient

    NARCIS (Netherlands)

    Parikova, Alena; Smit, Watske; Zweers, Machteld M.; Struijk, Dirk G.; Krediet, Raymond T.

    2008-01-01

    BACKGROUND: Water transport in peritoneal dialysis (PD) patients occurs through the small pores and water channels, the latter allowing free water transport (FWT). The osmotic gradient is known to be one of the major determinants of water transport. The objective of the study was to analyse the

  3. ANALYSIS ON THE TRANSLATION OF WORDPLAYS IN “THE GOD OF SMALL THINGS” BY ARUNDHATI ROY (Studies on the Wordplay Shifts and the Translation Quality

    Directory of Open Access Journals (Sweden)

    Nur Saptaningsih

    2017-04-01

    Full Text Available Wordplay commonly appears in literary works to enrich the works themselves with certain effect and nuance, either to make a joke or to conceal anything taboo. However, problems frequently occur in translation of wordplay and this becomes an obstacle for a translator to find proper equivalent. Moreover, the translation of wordplay is closely related to different language systems (source and target languages. Novel of ―The God of Small Things‖ by Arundhati Roy is rich in the use of wordplays, but there are a number of shifts found in the translated version of the wordplays. This paper deals with descriptivequalitative research aiming at investigating the shifts of wordplays in the novel of ―The God of Small Things‖ by Arundhati Roy and in the translated version. This study also highlights the contribution of the shifts on the translation quality, in terms of accuracy and acceptability. This product-oriented study applies embedded-case method. The first data for this research are documents, consisting of source text and the translated text. The other data are obtained from informants (raters and respondents, consisting of information dealing with accuracy and acceptability. The data are collected using document analyses, questionnaire, and interview. Purposive sampling and content analysis are applied.

  4. Integrated Water, Sanitation and Solid Waste Management in Small ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Inadequate water and sanitation services are having an negative effect on human health and polluting Lake Victoria in East Africa. At the request of the governments of Kenya, Tanzania and Uganda, UN-Habitat has undertaken an initiative to provide water and sanitation services in the region and protect the Lake basin.

  5. Integrating effects of species composition and soil properties to predict shifts in montane forest carbon-water relations.

    Science.gov (United States)

    Maxwell, Toby M; Silva, Lucas C R; Horwath, William R

    2018-05-01

    This study was designed to address a major source of uncertainty pertaining to coupled carbon-water cycles in montane forest ecosystems. The Sierra Nevada of California was used as a model system to investigate connections between the physiological performance of trees and landscape patterns of forest carbon and water use. The intrinsic water-use efficiency (iWUE)-an index of CO 2 fixed per unit of potential water lost via transpiration-of nine dominant species was determined in replicated transects along an ∼1,500-m elevation gradient, spanning a broad range of climatic conditions and soils derived from three different parent materials. Stable isotope ratios of carbon and oxygen measured at the leaf level were combined with field-based and remotely sensed metrics of stand productivity, revealing that variation in iWUE depends primarily on leaf traits (∼24% of the variability), followed by stand productivity (∼16% of the variability), climatic regime (∼13% of the variability), and soil development (∼12% of the variability). Significant interactions between species composition and soil properties proved useful to predict changes in forest carbon-water relations. On the basis of observed shifts in tree species composition, ongoing since the 1950s and intensified in recent years, an increase in water loss through transpiration (ranging from 10 to 60% depending on parent material) is now expected in mixed conifer forests throughout the region. Copyright © 2018 the Author(s). Published by PNAS.

  6. Bacterial Community Structure Shifted by Geosmin in Granular Activated Carbon System of Water Treatment Plants.

    Science.gov (United States)

    Pham, Ngoc Dung; Lee, Eun-Hee; Chae, Seon-Ha; Cho, Yongdeok; Shin, Hyejin; Son, Ahjeong

    2016-01-01

    We investigated the relation between the presence of geosmin in water and the bacterial community structure within the granular activated carbon (GAC) system of water treatment plants in South Korea. GAC samples were collected in May and August of 2014 at three water treatment plants (Sungnam, Koyang, and Yeoncho in Korea). Dissolved organic carbon and geosmin were analyzed before and after GAC treatment. Geosmin was found in raw water from Sungnam and Koyang water treatment plants but not in that from Yeoncho water treatment plant. Interestingly, but not surprisingly, the 16S rRNA clone library indicated that the bacterial communities from the Sungnam and Koyang GAC systems were closely related to geosmin-degrading bacteria. Based on the phylogenetic tree and multidimensional scaling plot, bacterial clones from GAC under the influence of geosmin were clustered with Variovorax paradoxus strain DB 9b and Comamonas sp. DB mg. In other words, the presence of geosmin in water might have inevitably contributed to the growth of geosmin degraders within the respective GAC system.

  7. 77 FR 25721 - Small Entity Compliance Guide: Bottled Water: Quality Standard: Establishing an Allowable Level...

    Science.gov (United States)

    2012-05-01

    ...] Small Entity Compliance Guide: Bottled Water: Quality Standard: Establishing an Allowable Level for di(2... ``Bottled Water: Quality Standard: Establishing an Allowable Level for di(2- ethylhexyl)phthalate--Small... an allowable level for di(2- ethylhexyl)phthalate (DEHP). This final rule is effective April 16, 2012...

  8. The Impact of Small Scale Mining on Irrigation Water Quality in ...

    African Journals Online (AJOL)

    Small scale mining is a major threat to water resources and agricultural activities in most mining communities across Ghana. This study investigated the effect of small scale mining on the quality of water for irrigation from some selected sites along a river and a reservoir which was used as a control. The physical and ...

  9. (Small) Resonant non-Gaussianities: Signatures of a Discrete Shift Symmetry in the Effective Field Theory of Inflation

    Energy Technology Data Exchange (ETDEWEB)

    Behbahani, Siavosh R.; /SLAC /Stanford U., Phys. Dept. /Boston U.; Dymarsky, Anatoly; /Princeton, Inst. Advanced Study; Mirbabayi, Mehrdad; /New York U., CCPP /New York U.; Senatore, Leonardo; /Stanford U., Phys. Dept. /KIPAC, Menlo Park

    2012-06-06

    We apply the Effective Field Theory of Inflation to study the case where the continuous shift symmetry of the Goldstone boson {pi} is softly broken to a discrete subgroup. This case includes and generalizes recently proposed String Theory inspired models of Inflation based on Axion Monodromy. The models we study have the property that the 2-point function oscillates as a function of the wavenumber, leading to oscillations in the CMB power spectrum. The non-linear realization of time diffeomorphisms induces some self-interactions for the Goldstone boson that lead to a peculiar non-Gaussianity whose shape oscillates as a function of the wavenumber. We find that in the regime of validity of the effective theory, the oscillatory signal contained in the n-point correlation functions, with n > 2, is smaller than the one contained in the 2-point function, implying that the signature of oscillations, if ever detected, will be easier to find first in the 2-point function, and only then in the higher order correlation functions. Still the signal contained in higher-order correlation functions, that we study here in generality, could be detected at a subleading level, providing a very compelling consistency check for an approximate discrete shift symmetry being realized during inflation.

  10. Air and water qualities around small ruminant houses in Central Java - Indonesia

    NARCIS (Netherlands)

    Budisatria, I.G.S.; Udo, H.M.J.; Zijpp, van der A.J.; Murti, T.W.; Baliarti, E.

    2007-01-01

    There is a general concern that livestock can have a profound effect on the environment, also in smallholder production systems. This paper presented the impact of small ruminants on the quality of air and water in and around small ruminant houses. In total, 27 small ruminant houses from the three

  11. Copper-chromium compounds formed in the preparation of a low-temperature water gas shift catalyst

    Energy Technology Data Exchange (ETDEWEB)

    Sharkina, V I; Salomatin, G I; Boevskaya, E A

    1978-12-01

    IR and X-ray phase analyses of commercial water gas shift catalyst samples prepared by mixing solid chromic anhydride, basic copper carbonate (malachite), aluminum hydroxide, and water at 70/sup 0/-100/sup 0/C and 0.35:1 to 1.2:1 ratio of water to solid components (R) showed the formation of a basic copper chromate (BCC) CuCrO/sub 4/-2CuO-2H/sub 2/O at 80/sup 0/C (any R) and at 100/sup 0/C and R Vertical Bar3: 1.2:1, but at 100/sup 0/C and lower R (especially at R 0.7:1), a different, unidentified phase was formed. The samples containing these two phases had different colors; the high-temperature, low-water phase showed lower thermal stability but higher catalytic activity than the BCC. The BCC catalyst samples contained less unreacted malachite and their IR spectra contained a 3100-3200/cm band characteristic of hydroxyls associated by hydrogen bonds, and more molecular water, suggesting the formation of a hydroxo-polymeric structured system.

  12. Shift in the microbial community composition of surface water and sediment along an urban river.

    Science.gov (United States)

    Wang, Lan; Zhang, Jing; Li, Huilin; Yang, Hong; Peng, Chao; Peng, Zhengsong; Lu, Lu

    2018-06-15

    Urban rivers represent a unique ecosystem in which pollution occurs regularly, leading to significantly altered of chemical and biological characteristics of the surface water and sediments. However, the impact of urbanization on the diversity and structure of the river microbial community has not been well documented. As a major tributary of the Yangtze River, the Jialing River flows through many cities. Here, a comprehensive analysis of the spatial microbial distribution in the surface water and sediments in the Nanchong section of Jialing River and its two urban branches was conducted using 16S rRNA gene-based Illumina MiSeq sequencing. The results revealed distinct differences in surface water bacterial composition along the river with a differential distribution of Proteobacteria, Cyanobacteria, Actinobacteria, Bacteroidetes and Acidobacteria (P urban water. PICRUSt metabolic inference analysis revealed a growing number of genes associated with xenobiotic metabolism and nitrogen metabolism in the urban water, indicating that urban discharges might act as the dominant selective force to alter the microbial communities. Redundancy analysis suggested that the microbial community structure was influenced by several environmental factors. TP (P urban river. These results highlight that river microbial communities exhibit spatial variation in urban areas due to the joint influence of chemical variables associated with sewage discharging and construction of hydropower stations. Copyright © 2018 Elsevier B.V. All rights reserved.

  13. Effects of Interannual Climate Variability on Water Availability and Productivity in Capoeira and Crops Under Traditional and Alternative Shifting Cultivation

    Science.gov (United States)

    Guild, Liane S.; Sa, Tatiana D. A.; Carvalho, Claudio J. R.; Potter, Christopher S.; Wickel, Albert J.; Brienza, Silvio, Jr.; Kato, Maria doSocorro A.; Kato, Osvaldo; Brass, James (Technical Monitor)

    2002-01-01

    Regenerating forests play an important role in long-term carbon sequestration and sustainable landuse as they act as potentially important carbon and nutrient sinks during the shifting agriculture fallow period. The long-term functioning of capoeira. is increasingly threatened by a shortening fallow period during shifting cultivation due to demographic pressures and associated increased vulnerability to severe climatic events. Declining productivity and functioning of fallow forests of shifting cultivation combined with progressive loss of nutrients by successive burning and cropping activities has resulted in declining agricultural productivity. In addition to the effects of intense land use practices, droughts associated with El Nino events are becoming more frequent and severe in moist tropical forests and negative effects on capoeira productivity could be considerable. In Igarape-Acu (near Belem, Para), we hypothesize that experimental alternative landuse/clearing practices (mulching and fallow vegetation improvement by planting with fast-growing leguminous tree species) may make capoeira and agriculture more resilient to the effects of agricultural pressures and drought through (1) increased biomass, soil organic matter and associated increase in soil water storage, and nutrient retention and (2) greater rooting depth of trees planted for fallow improvement. This experimental practice (moto mechanized chop-and-mulch with fallow improvement) has resulted increased soil moisture during the cropping phase, reduced loss of nutrients and organic matter, and higher rates of secondary-forest biomass accumulation. We present preliminary data on water relations during the dry season of 2001 in capoeira and crops for both traditional slash-and-burn and alternative chop-and-mulch practices. These data will be used to test IKONOS data for the detection of moisture status differences. The principal goal of the research is to determine the extent to which capoeira and

  14. Piped water consumption in Ghana: A case study of temporal and spatial patterns of clean water demand relative to alternative water sources in rural small towns

    OpenAIRE

    Kulinkina, Alexandra V.; Kosinski, Karen C.; Liss, Alexander; Adjei, Michael N.; Ayamgah, Gilbert A.; Webb, Patrick; Gute, David M.; Plummer, Jeanine D.; Naumova, Elena N.

    2016-01-01

    Continuous access to adequate quantities of safe water is essential for human health and socioeconomic development. Piped water systems (PWSs) are an increasingly common type of water supply in rural African small towns. Despite providing the highest and most flexible level of service with better microbiological water quality to their users, these systems remain vulnerable to rural water sustainability challenges. We assessed temporal and spatial patterns in water consumption from public stan...

  15. Heat Integration of the Water-Gas Shift Reaction System for Carbon Sequestration Ready IGCC Process with Chemical Looping

    Energy Technology Data Exchange (ETDEWEB)

    Juan M. Salazara; Stephen E. Zitney; Urmila M. Diwekara

    2010-01-01

    Integrated gasification combined cycle (IGCC) technology has been considered as an important alternative for efficient power systems that can reduce fuel consumption and CO2 emissions. One of the technological schemes combines water-gas shift reaction and chemical-looping combustion as post gasification techniques in order to produce sequestration-ready CO2 and potentially reduce the size of the gas turbine. However, these schemes have not been energetically integrated and process synthesis techniques can be applied to obtain an optimal flowsheet. This work studies the heat exchange network synthesis (HENS) for the water-gas shift reaction train employing a set of alternative designs provided by Aspen energy analyzer (AEA) and combined in a process superstructure that was simulated in Aspen Plus (AP). This approach allows a rigorous evaluation of the alternative designs and their combinations avoiding all the AEA simplifications (linearized models of heat exchangers). A CAPE-OPEN compliant capability which makes use of a MINLP algorithm for sequential modular simulators was employed to obtain a heat exchange network that provided a cost of energy that was 27% lower than the base case. Highly influential parameters for the pos gasification technologies (i.e. CO/steam ratio, gasifier temperature and pressure) were calculated to obtain the minimum cost of energy while chemical looping parameters (oxidation and reduction temperature) were ensured to be satisfied.

  16. Small-angle neutron scattering studies on water soluble complexes ...

    Indian Academy of Sciences (India)

    ... by small-angle neutron scattering. SANS data showed a positive indication of the formation of RCP-SDS complexes. Even though the complete structure of the polyion complexes could not be ascertained, the results obtained give us the information on the local structure in these polymer-surfactant systems. The data were ...

  17. Regime shifts and panarchies in regional scale social-ecological water systems

    Science.gov (United States)

    In this article we summarize histories of nonlinear, complex interactions among societal, legal, and ecosystem dynamics in six North American water basins, as they respond to changing climate. These case studies were chosen to explore the conditions for emergence of adaptive gove...

  18. Field Testing of a Small Water Purification System for Non-PRASA Rural Communities

    Science.gov (United States)

    Small, rural communities typically do not have adequate water purification systems to sustain their life quality and residents are exposed to pathogens present in drinking water. In Puerto Rico (PR), approximately 4% of the population does not have access to drinking water provi...

  19. Evaluation of Small-Scale Providers of Water Supply and Sanitation Services in Peru

    OpenAIRE

    World Bank

    2007-01-01

    The Water and Sanitation Program (WSP), administered by the World Bank, helps countries find sustainable solutions to ensure efficient delivery of the quality water supply and sanitation services the population demands. The WSP is carrying out a systematic analysis in several countries to identify the role of small-scale providers (SSP) of water and sanitation services to poor populations ...

  20. Nanofiltration Membranes for Removal of Color and Pathogens in Small Public Drinking Water Sources

    Science.gov (United States)

    Small public water supplies that use surface water as a source for drinking water are frequently faced with elevated levels of color and natural organic matter (NOM) that are precursors for chlorinated disinfection byproduct (DBP) formation. Nanofiltration (NF) systems can preve...

  1. Sustainability of small reservoirs and large scale water availability under current conditions and climate change

    NARCIS (Netherlands)

    Krol, Martinus S.; de Vries, Marjella J.; van Oel, Pieter R.; Carlos de Araújo, José

    2011-01-01

    Semi-arid river basins often rely on reservoirs for water supply. Small reservoirs may impact on large-scale water availability both by enhancing availability in a distributed sense and by subtracting water for large downstream user communities, e.g. served by large reservoirs. Both of these impacts

  2. Performance of a small wind powered water pumping system

    Science.gov (United States)

    Lorentz helical pumps (Henstedt-Ulzburg, Germany) have been powered by solar energy for remote water pumping applications for many years, but from October 2005 to March 2008 a Lorentz helical pump was powered by wind energy at the USDA-ARS Conservation and Production Research Laboratory (CPRL) near ...

  3. Communications: On artificial frequency shifts in infrared spectra obtained from centroid molecular dynamics: Quantum liquid water

    Science.gov (United States)

    Ivanov, Sergei D.; Witt, Alexander; Shiga, Motoyuki; Marx, Dominik

    2010-01-01

    Centroid molecular dynamics (CMD) is a popular method to extract approximate quantum dynamics from path integral simulations. Very recently we have shown that CMD gas phase infrared spectra exhibit significant artificial redshifts of stretching peaks, due to the so-called "curvature problem" imprinted by the effective centroid potential. Here we provide evidence that for condensed phases, and in particular for liquid water, CMD produces pronounced artificial redshifts for high-frequency vibrations such as the OH stretching band. This peculiar behavior intrinsic to the CMD method explains part of the unexpectedly large quantum redshifts of the stretching band of liquid water compared to classical frequencies, which is improved after applying a simple and rough "harmonic curvature correction."

  4. Ab initio theoretical calculations of the electronic excitation energies of small water clusters.

    Science.gov (United States)

    Tachikawa, Hiroto; Yabushita, Akihiro; Kawasaki, Masahiro

    2011-12-14

    A direct ab initio molecular dynamics method has been applied to a water monomer and water clusters (H(2)O)(n) (n = 1-3) to elucidate the effects of zero-point energy (ZPE) vibration on the absorption spectra of water clusters. Static ab initio calculations without ZPE showed that the first electronic transitions of (H(2)O)(n), (1)B(1)←(1)A(1), are blue-shifted as a function of cluster size (n): 7.38 eV (n = 1), 7.58 eV (n = 2) and 8.01 eV (n = 3). The inclusion of the ZPE vibration strongly affects the excitation energies of a water dimer, and a long red-tail appears in the range of 6.42-6.90 eV due to the structural flexibility of a water dimer. The ultraviolet photodissociation of water clusters and water ice surfaces is relevant to these results.

  5. Will small energy consumers be faster in transition? Evidence from the early shift from coal to oil in Latin America

    International Nuclear Information System (INIS)

    Rubio, M.d.Mar; Folchi, Mauricio

    2012-01-01

    This paper provide evidence of the early transition from coal to oil for 20 Latin American countries over the first half of the 20th century, which does not fit the transition experiences of large energy consumers. These small energy consumers had earlier and faster transitions than leading nations. We also provide evidence for alternative sequences (inverse, revertible) in the transition from coal to oil. Furthermore, we demonstrate that ‘leapfrogging’ allowed a set of follower economies to reach the next rung of the energy ladder (oil domination) 30 years in advance of the most developed economies. We examine these follower economies, where transition took place earlier and faster than the cases historically known, in order to understand variation within the energy transitions and to expand the array of feasible pathways of future energy transitions. We find that being a small energy consumer makes a difference for the way the energy transition takes place; but also path dependence (including trade and technological partnerships), domestic energy endowment (which dictates relative prices) and policy decisions seem to be the variables that shaped past energy transitions. - Highlights: ► We provide evidence of the early transition from coal to oil for 20 Latin American. ► We find that being a small energy consumer makes a difference for the way the energy transition takes place. ► Followers had earlier and faster transitions than leading nations. ► ‘Leapfrogging’ allowed extremely fast energy transitions. ► Alternative forms (revertible, inverse) of energy transition also exist.

  6. Warm Water Bath Stimulates Phase-Shifts of the Peripheral Circadian Clocks in PER2::LUCIFERASE Mouse

    Science.gov (United States)

    Kuriki, Daisuke; Haraguchi, Atsushi; Shibata, Shigenobu

    2014-01-01

    Circadian clocks in the peripheral tissues of mice are known to be entrained by pulse stimuli such as restricted feeding, novel wheel running, and several other agents. However, there are no reports on high temperature pulse-mediated entrainment on the phase-shift of peripheral clocks in vivo. Here we show that temperature treatment of mice for two days at 41°C, instead of 37°C, for 1–2 h during the inactive period, using a temperature controlled water bath stimulated phase-advance of peripheral clocks in the kidney, liver, and submandibular gland of PER2::LUCIFERASE mice. On the other hand, treatment for 2 days at 35°C ambient room temperature for 2 h did not cause a phase-advance. Maintenance of mice at 41°C in a water bath, sustained the core body temperature at 40–41°C. However, the use of 37°C water bath or the 35°C ambient room temperature elevated the core body temperature to 38.5°C, suggesting that at least a core body temperature of 40–41°C is necessary to cause phase-advance under light-dark cycle conditions. The temperature pulse stimulation at 41°C, instead of 37°C water bath for 2 h led to the elevated expression of Per1 and Hsp70 in the peripheral tissue of mice. In summary, the present study demonstrates that transient high temperature pulse using water bath during daytime causes phase-advance in mouse peripheral clocks in vivo. The present results suggest that hot water bath may affect the phase of peripheral clocks. PMID:24933288

  7. Small-cell lung cancer patients are just ‘a little bit’ tired: response shift and self-presentation in the measurement of fatigue

    Science.gov (United States)

    The, Anne-Mei; Sprangers, Mirjam A. G.; Groen, Harry J. M.; van der Wal, Gerrit; Hak, Tony

    2007-01-01

    Background Response shift has gained increasing attention in the measurement of health-related quality of life (QoL) as it may explain counter-intuitive findings as a result of adaptation to deteriorating health. Objective To search for response shift type explanations to account for counter-intuitive findings in QoL measurement. Methods Qualitative investigation of the response behaviour of small-cell lung cancer (SCLC) patients (n = 23) in the measurement of fatigue with The European Organization for Research and Treatment of Cancer Core Quality of Life Questionnaire (EORTC QLQ-C30) question ‘were you tired’. Interviews were conducted at four points during 1st line chemotherapy: at the start of chemotherapy, 4 weeks later, at the end of chemotherapy, and 6 weeks later. Patients were asked to ‘think aloud’ when filling in the questionnaire. Results Fifteen patients showed discrepancies between their answer to the EORTC question ‘were you tired’ and their level of fatigue spontaneously reported during the interview. These patients chose the response options ‘not at all’ or ‘a little’ and explained their answers in various ways. In patients with and without discrepancies, we found indications of recalibration response shift (e.g. using a different comparison standard over time) and of change in perspective (e.g. change towards a more optimistic perspective). Patients in the discrepancy group reported spontaneously how they dealt with diagnosis and treatment, i.e. by adopting protective and assertive behaviour and by fighting the stigma. They distanced themselves from the image of the stereotypical cancer patient and presented themselves as not suffering and accepting fatigue as consequence of treatment. Conclusion In addition to response shift, this study suggests that ‘self-presentation’ might be an important mechanism affecting QoL measurement, particularly during phases when a new equilibrium needs to be found. PMID:17450423

  8. Treatment technology for removing radon from small community water supplies

    International Nuclear Information System (INIS)

    Kinner, N.E.; Quern, P.A.; Schell, G.S.; Lessard, C.E.; Clement, J.A.

    1990-01-01

    This paper reports on the selection of an appropriate treatment system to remove radon from drinking water which depends primarily upon percent removal; capital and operating and maintenance costs; safety; raw water quality with respect to parameters such as Fe, Mn, bacteria, and organics. The radon removal efficiency of the diffused bubble and packed tower aeration exceeded 99% at A:W ratios of 15:1 and 5:1, respectively; the GAC system averaged 81 ± 7.7%. Though our field evaluations indicated that GAC systems may not be as efficient as aeration systems, the system tested was operated above design requirements for most of the study period. Other researchers have found removals of greater than 99% with GAC point-of-entry applications. Therefore, each of these processes has the potential to consistently remove 99% of the radon applied. However, even this percent removal may not be sufficient to meet an MCL in the range of 200 to 1000 pCi/L if the raw water contained more than 20,000 to 100,000 pCi/L, respectively

  9. Enrichment and determination of small amounts of 90Sr/90Y in water samples

    International Nuclear Information System (INIS)

    Mundschenk, H.

    1979-01-01

    Small amounts of 90 Sr/ 90 Y can be concentrated from large volumes of surface water (100 l) by precipitation of the phosphates, using bentonite as adsorber matrix. In the case of samples containing no or nearly no suspended matter (tap water, ground water, sea water), the daughter 90 Y can be extracted directly by using filter beds impregnated with HDEHP. The applicability of both techniques is demonstrated under realistic conditions. (orig.) 891 HP/orig. 892 MKO [de

  10. Sustainability of small reservoirs and large scale water availability under current conditions and climate change

    OpenAIRE

    Krol, Martinus S.; de Vries, Marjella J.; van Oel, P.R.; Carlos de Araújo, José

    2011-01-01

    Semi-arid river basins often rely on reservoirs for water supply. Small reservoirs may impact on large-scale water availability both by enhancing availability in a distributed sense and by subtracting water for large downstream user communities, e.g. served by large reservoirs. Both of these impacts of small reservoirs are subject to climate change. Using a case-study on North-East Brazil, this paper shows that climate change impacts on water availability may be severe, and impacts on distrib...

  11. What Happens Where the Water and the Rock Touch in Small Space Bodies

    Science.gov (United States)

    Byrne, P. K.; Regensburger, P. V.; Klimczak, C.; Bohnenstiehl, D. R.; Dombard, A. J.; Hauck, S. A., II

    2017-12-01

    There are several small space bodies that go around bigger worlds that might have a layer of water under a layer of ice. Lots of study has been done to understand the outside ice layer of these small space bodies, because the ice can tells us important things about the big water layer under it. Some of these small space bodies are very interesting because the right things for life—water, hot rock, and food—might be at the bottom of the water layer, where it touches the top of the next layer down, which is made of rock. But it is very hard to understand what this rock at the bottom of the water is like, because we can't see it. So, we are imagining what this rock is like by thinking about what the rock is like under the water layer on our own world. If hot rock comes out of the rock layer through cracks under the water, the cold of the water makes the hot rock go very cold very fast, and it makes funny rolls as it does so. This might happen on some small space bodies that are hot enough on the inside to make hot rock. We know that on our own world the rock layer under the water is wet to as far down as cracks can go, so it makes sense that this is true for small space bodies, too. We did some thinking about numbers and found out that the cracks can go a few ten hundred steps into the rock layer on small space bodies, but for bigger (well, not quite so small) space bodies, the cracks can go at least tens of ten hundred steps into the rock layer. This means that water goes into the rock layer this much, too. But get this: some small bodies are not really that small—one of them is bigger than the first world from the Sun! And on a few of these big (small) bodies, the layer of water is so heavy that the bottom of that water is pushed together from all sides and turns into a type of hot ice. This means that, for these big (small) worlds, the water can't get into the rock layer through cracks (since there is a layer of hot ice in the way), and so these bodies are

  12. Diversity patterns and freshwater molluscs similarities in small water reservoirs

    Directory of Open Access Journals (Sweden)

    Tomáš Čejka

    2011-02-01

    Full Text Available The survey presents the molluscan fauna from six impoundment systems of two sides (NW and SE of the Small Carpathians. Altogether 25 species (15 gastropod and 10 bivalve species were identified in reservoirs and their subsystems (inflows and outlets. The number of species per site ranged from 2 to 12, the mean number of species per site was 7. The mean number of individuals per site ranged from 15 to 905 (mean 174 ind/m2. Radix auricularia, R. ovata, Gyraulus albus, Gyraulus parvus/laevis, Hippeutis complanatus and Pisidium casertanum were present in more than 50% of reservoirs. The most abundant and frequent species in the entire area and all subsystems were Pisidium casertanum, Pisidium subtruncatum and Gyraulus parvus/laevis. Faunistic similarity indices indicate moderate degree of beta diversity i.e., differentiation among the sites; good separation of sites by cluster analysis indicates a different composition among inflows/outlets and littoral molluscan faunas of reservoirs.

  13. Comparison of brown and white adipose tissues in infants and children with chemical-shift-encoded water-fat MRI.

    Science.gov (United States)

    Hu, Houchun H; Yin, Larry; Aggabao, Patricia C; Perkins, Thomas G; Chia, Jonathan M; Gilsanz, Vicente

    2013-10-01

    To compare fat-signal fractions (FFs) and T2* values between brown (BAT) and white (WAT) adipose tissue located within the supraclavicular fossa and subcutaneous depots, respectively. Twelve infants and 39 children were studied. Children were divided into lean and overweight/obese subgroups. Chemical-shift-encoded water-fat magnetic resonance imaging (MRI) was used to quantify FFs and T2* metrics in the supraclavicular and adjacent subcutaneous adipose tissue depots. Linear regression and t-tests were performed. Infants had lower supraclavicular FFs than children (P children exhibited lower supraclavicular FFs and T2* values than overweight children (P children, but not in infants. FFs in both depots were positively correlated with age and weight in infants (P children, they were correlated with weight and body mass index (BMI) (P children (P children, which are potentially indicative of physiological differences in adipose tissue fat content, amount, and metabolic activity. Copyright © 2013 Wiley Periodicals, Inc.

  14. Parametric Gasification of Oak and Pine Feedstocks Using the TCPDU and Slipstream Water-Gas Shift Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Hrdlicka, J.; Feik, C.; Carpenter, D.; Pomeroy, M.

    2008-12-01

    With oak and pine feedstocks, the Gasification of Biomass to Hydrogen project maximizes hydrogen production using the Full Stream Reformer during water-gas shift fixed-bed reactor testing. Results indicate that higher steam-to-biomass ratio and higher thermal cracker temperature yield higher hydrogen concentration. NREL's techno-economic models and analyses indicate hydrogen production from biomass may be viable at an estimated cost of $1.77/kg (current) and $1.47/kg (advanced in 2015). To verify these estimates, NREL used the Thermochemical Process Development Unit (TCPDU), an integrated system of unit operations that investigates biomass thermochemical conversion to gaseous and liquid fuels and chemicals.

  15. THE IMPACT OF TBILISI USED WATER ON ECOCHEMICAL STATE OF SMALL RIVERS OF THE CITY

    Directory of Open Access Journals (Sweden)

    MARIAM TABATADZE

    2016-03-01

    Full Text Available The centralized sewerage systems and wastewater treatment facilities were constructed in Tbilisi in the middle of the previous century. Nowadays only mechanical treatment stage operates in wastewater treatment facilities of Tbilisi. Moreover, collected wastewater from the sewerage systems often drains without any treatment directly into the small rivers located in Tbilisi area. These rivers feed the main water artery of our capital – river Mtkvari and play an important role in its salt balance. As a result of study of hydro-chemical parameters of Tbilisi small rivers were identified Water Pollution Index (WPI and assessment of small rivers pollution by sewage waters was carried out. It was established that small rivers of Tbilisi belong to the IV and V classes, i.e. less polluted and polluted rivers, while according to the content of fecal matter in the river water they are ranged in the class of polluted and most polluted.

  16. POLLUTION OF SMALL RESERVOIRS OF WATER IN BIALYSTOK AGGLOMERATION

    Directory of Open Access Journals (Sweden)

    Janina Piekutin

    2016-05-01

    Full Text Available The aim of the study work was to evaluate the impact of the emissions of heavy metals of roads and streets in the surface water in reservoirs located near the main roads of the Bialystok City. The analysis was conducted for a period of six weeks from March to April 2014. During the study five reservoirs were selected. Two of them, the first and the forth of them are located in Parks. One of them – the third one is a public bathing beach. The second is located near the crossroads in the center of the city and last one – the fifth object is situated within buildings and parking of trucks. Study includes an analysis of indicators such as total suspended solids, BOD5, CODCr, selected heavy metal such as, lead, nickel, copper, cobalt and chromium. All determinations were made in accordance to given methodology, and the evaluation was performed by comparing achieved results to a limit values presented in the Decree of Environment Ministry.

  17. Regime shifts and panarchies in regional scale social-ecological water systems

    Directory of Open Access Journals (Sweden)

    Lance Gunderson

    2017-03-01

    Full Text Available In this article we summarize histories of nonlinear, complex interactions among societal, legal, and ecosystem dynamics in six North American water basins, as they respond to changing climate. These case studies were chosen to explore the conditions for emergence of adaptive governance in heavily regulated and developed social-ecological systems nested within a hierarchical governmental system. We summarize resilience assessments conducted in each system to provide a synthesis and reference by the other articles in this special feature. We also present a general framework used to evaluate the interactions between society and ecosystem regimes and the governance regimes chosen to mediate those interactions. The case studies show different ways that adaptive governance may be triggered, facilitated, or constrained by ecological and/or legal processes. The resilience assessments indicate that complex interactions among the governance and ecosystem components of these systems can produce different trajectories, which include patterns of (a development and stabilization, (b cycles of crisis and recovery, which includes lurches in adaptation and learning, and (3 periods of innovation, novelty, and transformation. Exploration of cross scale (Panarchy interactions among levels and sectors of government and society illustrate that they may constrain development trajectories, but may also provide stability during crisis or innovation at smaller scales; create crises, but may also facilitate recovery; and constrain system transformation, but may also provide windows of opportunity in which transformation, and the resources to accomplish it, may occur. The framework is the starting point for our exploration of how law might play a role in enhancing the capacity of social-ecological systems to adapt to climate change.

  18. The times are changing: temporal shifts in patterns of fish invasions in central European fresh waters.

    Science.gov (United States)

    Rabitsch, W; Milasowszky, N; Nehring, S; Wiesner, C; Wolter, C; Essl, F

    2013-01-01

    This study examines the invasion history of alien fish species based on exhaustive national data sets on fish invasions of two contiguous central European countries (Germany and Austria). Fifteen alien fish species are currently established in both countries, constituting 14 and 17% of the total freshwater fish fauna of Germany and Austria, respectively. In both countries, six alien species are present, but not established. The status of five alien species in Germany and three species in Austria remains unknown. Accumulation rates of alien fish species have increased in recent decades with >50% of them reported after 1971. North America and Asia were the primary sources of alien fish species in Germany and Austria up to the 1980s, whereas European species of Ponto-Caspian origin dominate now. Fisheries (including aquaculture) and the animal trade were responsible for most earlier introductions, whereas waterways were the main pathway for recent invaders. The extent of the spatial distribution of alien species was positively correlated with residence time, i.e. the time elapsed since the first national record. Different thermal preferences of early invaders (mostly coldwater species) and new invaders (typically warmwater adapted) may benefit the latter in the face of climate change. It is concluded that new challenges for alien fish management arise and that ecosystem-based approaches as endorsed by the E.U. Water Framework Directive (maintaining or restoring good ecological status of rivers and streams) should become the centrepiece of river management in Europe. © 2012 The Authors. Journal of Fish Biology © 2012 The Fisheries Society of the British Isles.

  19. Regime shifts and panarchies in regional scale social-ecological water systems

    Science.gov (United States)

    Gunderson, Lance; Cosens, Barbara; Chaffin, Brian C.; Arnold, Craig Anthony (Tony); Fremier, Alexander K.; Garmestani, Ahjond S.; Kundis Craig, Robin; Gosnell, Hannah; Birge, Hannah E.; Allen, Craig R.; Benson, Melinda H.; Morrison, Ryan R.; Stone, Mark; Hamm, Joseph A.; Nemec, Kristine T.; Schlager, Edella; Llewellyn, Dagmar

    2017-01-01

    In this article we summarize histories of nonlinear, complex interactions among societal, legal, and ecosystem dynamics in six North American water basins, as they respond to changing climate. These case studies were chosen to explore the conditions for emergence of adaptive governance in heavily regulated and developed social-ecological systems nested within a hierarchical governmental system. We summarize resilience assessments conducted in each system to provide a synthesis and reference by the other articles in this special feature. We also present a general framework used to evaluate the interactions between society and ecosystem regimes and the governance regimes chosen to mediate those interactions. The case studies show different ways that adaptive governance may be triggered, facilitated, or constrained by ecological and/or legal processes. The resilience assessments indicate that complex interactions among the governance and ecosystem components of these systems can produce different trajectories, which include patterns of (a) development and stabilization, (b) cycles of crisis and recovery, which includes lurches in adaptation and learning, and (3) periods of innovation, novelty, and transformation. Exploration of cross scale (Panarchy) interactions among levels and sectors of government and society illustrate that they may constrain development trajectories, but may also provide stability during crisis or innovation at smaller scales; create crises, but may also facilitate recovery; and constrain system transformation, but may also provide windows of opportunity in which transformation, and the resources to accomplish it, may occur. The framework is the starting point for our exploration of how law might play a role in enhancing the capacity of social-ecological systems to adapt to climate change.

  20. A Bottom-up Vulnerability Analysis of Water Systems with Decentralized Decision Making and Demographic Shifts- the Case of Jordan.

    Science.gov (United States)

    Lachaut, T.; Yoon, J.; Klassert, C. J. A.; Talozi, S.; Mustafa, D.; Knox, S.; Selby, P. D.; Haddad, Y.; Gorelick, S.; Tilmant, A.

    2016-12-01

    Probabilistic approaches to uncertainty in water systems management can face challenges of several types: non stationary climate, sudden shocks such as conflict-driven migrations, or the internal complexity and dynamics of large systems. There has been a rising trend in the development of bottom-up methods that place focus on the decision side instead of probability distributions and climate scenarios. These approaches are based on defining acceptability thresholds for the decision makers and considering the entire range of possibilities over which such thresholds are crossed. We aim at improving the knowledge on the applicability and relevance of this approach by enlarging its scope beyond climate uncertainty and single decision makers; thus including demographic shifts, internal system dynamics, and multiple stakeholders at different scales. This vulnerability analysis is part of the Jordan Water Project and makes use of an ambitious multi-agent model developed by its teams with the extensive cooperation of the Ministry of Water and Irrigation of Jordan. The case of Jordan is a relevant example for migration spikes, rapid social changes, resource depletion and climate change impacts. The multi-agent modeling framework used provides a consistent structure to assess the vulnerability of complex water resources systems with distributed acceptability thresholds and stakeholder interaction. A proof of concept and preliminary results are presented for a non-probabilistic vulnerability analysis that involves different types of stakeholders, uncertainties other than climatic and the integration of threshold-based indicators. For each stakeholder (agent) a vulnerability matrix is constructed over a multi-dimensional domain, which includes various hydrologic and/or demographic variables.

  1. Repeated sorption of water in SBA-15 investigated by means of in situ small-angle x-ray scattering

    International Nuclear Information System (INIS)

    Erko, M; Paris, O; Wallacher, D; Findenegg, G H

    2012-01-01

    The effect of repeated cycles of water adsorption/desorption on the structural stability of ordered mesoporous silica SBA-15 is studied by small-angle x-ray scattering (SAXS). In situ sorption measurements are conducted using a custom-built sorption apparatus in connection with a laboratory SAXS setup. Two striking irreversible changes are observed in the sorption isotherms as derived from the integrated SAXS intensity. First, the capillary condensation pressure shifts progressively to lower relative pressure values with increasing number of sorption cycles. This effect is attributed to chemisorption of water at the silica walls, resulting in a change of the fluid-wall interaction. Second, the sorption cycles do not close completely at vanishing vapour pressure, suggesting that progressively more water remains trapped within the porous material after each cycle. This effect is interpreted to be the result of an irreversible collapse of parts of mesopores, originating from pore wall deformation due to the large Laplace pressure of water acting on the pore walls at capillary condensation and capillary evaporation. (paper)

  2. URANIUM REMOVAL FROM DRINKING WATER USING A SMALL FULL-SCALE SYSTEM

    Science.gov (United States)

    This report presents background and history of water quality, the basis for design and nine months of actual operating data for a small, full-scale strong-base ion exchange system that is used to remove uranium from a water supply serving a school in Jefferson County, CO. Informa...

  3. 75 FR 14607 - Small Entity Compliance Guide: Bottled Water: Total Coliform and E. coli

    Science.gov (United States)

    2010-03-26

    ...] Small Entity Compliance Guide: Bottled Water: Total Coliform and E. coli; Availability AGENCY: Food and... the availability of a guidance for industry entitled ``Bottled Water: Total Coliform and E. coli... determine whether any of the coliform organisms are Escherichia coli (E. coli), an indicator of fecal...

  4. Water Quality in Small Community Distribution Systems. A Reference Guide for Operators

    Science.gov (United States)

    The U.S. Environmental Protection Agency (EPA) has developed this reference guide to assist the operators and managers of small- and medium-sized public water systems. This compilation provides a comprehensive picture of the impact of the water distribution system network on dist...

  5. Shift Colors

    Science.gov (United States)

    Publications & News Shift Colors Pages default Sign In NPC Logo Banner : Shift Colors Search Navy Personnel Command > Reference Library > Publications & News > Shift Colors Top Link Bar Navy Personnel Library Expand Reference Library Quick Launch Shift Colors Shift Colors Archives Mailing Address How to

  6. Role of small-scale independent providers in water and sanitation

    OpenAIRE

    Dijk, Meine Pieter

    2008-01-01

    textabstractSmall-scale independent providers (SSIPs) and households are good for 10–69% of the household water supply and sometimes up to 95% of the sanitation solutions in cities in developing countries. Different types of SSIP can be distinguished. They could be allowed to make a more important contribution to drinking water and sanitation in a situation where many governments cannot be the only one to supply drinking water and sanitary services. Theoretical and practical arguments are use...

  7. Implications of small water leak reactions on sodium heated steam generator design

    Energy Technology Data Exchange (ETDEWEB)

    Smedley, J A

    1975-07-01

    Various types of sodium water reactions have been looked on as possibly causing hazard conditions in sodium heated steam generator units ranging from the very improbable boiler tube double ended guillotine fracture to the almost certain occurrence of micro-leaks. Within this range small water leaks reactions have attracted particular interest and the present paper looks at the principles of associating the reactions with detection and protection systems for Commercial Fast Reactors. A method is developed for assessing whether adequate protection has been provided against the effects of small water leak reactions in a steam generator unit. (author)

  8. Shallow water marine sediment bacterial community shifts along a natural CO2 gradient in the Mediterranean Sea off Vulcano, Italy.

    Science.gov (United States)

    Kerfahi, Dorsaf; Hall-Spencer, Jason M; Tripathi, Binu M; Milazzo, Marco; Lee, Junghoon; Adams, Jonathan M

    2014-05-01

    The effects of increasing atmospheric CO(2) on ocean ecosystems are a major environmental concern, as rapid shoaling of the carbonate saturation horizon is exposing vast areas of marine sediments to corrosive waters worldwide. Natural CO(2) gradients off Vulcano, Italy, have revealed profound ecosystem changes along rocky shore habitats as carbonate saturation levels decrease, but no investigations have yet been made of the sedimentary habitat. Here, we sampled the upper 2 cm of volcanic sand in three zones, ambient (median pCO(2) 419 μatm, minimum Ω(arag) 3.77), moderately CO(2)-enriched (median pCO(2) 592 μatm, minimum Ω(arag) 2.96), and highly CO(2)-enriched (median pCO(2) 1611 μatm, minimum Ω(arag) 0.35). We tested the hypothesis that increasing levels of seawater pCO(2) would cause significant shifts in sediment bacterial community composition, as shown recently in epilithic biofilms at the study site. In this study, 454 pyrosequencing of the V1 to V3 region of the 16S rRNA gene revealed a shift in community composition with increasing pCO(2). The relative abundances of most of the dominant genera were unaffected by the pCO(2) gradient, although there were significant differences for some 5 % of the genera present (viz. Georgenia, Lutibacter, Photobacterium, Acinetobacter, and Paenibacillus), and Shannon Diversity was greatest in sediments subject to long-term acidification (>100 years). Overall, this supports the view that globally increased ocean pCO(2) will be associated with changes in sediment bacterial community composition but that most of these organisms are resilient. However, further work is required to assess whether these results apply to other types of coastal sediments and whether the changes in relative abundance of bacterial taxa that we observed can significantly alter the biogeochemical functions of marine sediments.

  9. THE ANALYSIS OF THE TIME-SERIES FLUCTUATION OF WATER DEMAND FOR THE SMALL WATER SUPPLY BLOCK

    Science.gov (United States)

    Koizumi, Akira; Suehiro, Miki; Arai, Yasuhiro; Inakazu, Toyono; Masuko, Atushi; Tamura, Satoshi; Ashida, Hiroshi

    The purpose of this study is to define one apartment complex as "the water supply block" and to show the relationship between the amount of water supply for an apartment house and its time series fluctuation. We examined the observation data which were collected from 33 apartment houses. The water meters were installed at individual observation points for about 20 days in Tokyo. This study used Fourier analysis in order to grasp the irregularity in a time series data. As a result, this paper demonstrated that the smaller the amount of water supply became, the larger irregularity the time series fluctuation had. We also found that it was difficult to describe the daily cyclical pattern for a small apartment house using the dominant periodic components which were obtained from a Fourier spectrum. Our research give useful information about the design for a directional water supply system, as to making estimates of the hourly fluctuation and the maximum daily water demand.

  10. Study on water leak-tightness of small leaks on a 1 inch cylinder valve

    International Nuclear Information System (INIS)

    Miyazawa, T.; Kasai, Y.; Inabe, N.; Aritomi, M.

    2002-01-01

    Practical thresholds for water leak-tightness of small leaks were determined by experimentation. Measurements for small leak samples were taken of air leakage rates and water leakage rates for identical leak samples in order to identify parameters that influence water leak-tightness threshold. Four types of leaks were evaluated: a fine wire inserted in an O-ring seal, a glass capillary tube, a stainless steel orifice, and a scratched valve stem on a 1 inch UF 6 cylinder valve. Experimental results demonstrated that the key parameter for water leak-tightness is the opening size of the leak hole. The maximum allowable hole size to achieve water leak-tightness ranged from 10 to 20 μm in diameter in this study. Experimental results with 1 inch UF 6 cylinder valve samples demonstrated that the acceptance criteria for preshipment leakage test, 1x10 -3 ref-cm 3 .s -1 , as prescribed in ANSI N14.5 is an appropriate value from the point of view of water leak-tightness for enriched UF 6 packages. The mechanism of water leak-tightness is plugging by tiny particles existing in water. The water used in experiments in this study contained far fewer particles than in water assumed to be encountered under accident conditions of transport. Therefore, the water leak-tightness threshold determined in this study is a conservative value in a practical evaluation. (author)

  11. Paradigm Shift in Transboundary Water Management Policy: Linking Water Environment Energy and Food (weef) to Catchment Hydropolitics - Needs, Scope and Benefits

    Science.gov (United States)

    RAI, S.; Wolf, A.; Sharma, N.; Tiwari, H.

    2015-12-01

    The incessant use of water due to rapid growth of population, enhanced agricultural and industrial activities, degraded environment and ecology will in the coming decades constrain the socioeconomic development of humans. To add on to the precarious situation, political boundaries rarely embrace hydrological boundaries of lakes, rivers, aquifers etc. Hydropolitics relate to the ability of geopolitical institutions to manage shared water resources in a politically sustainable manner, i.e., without tensions or conflict between political entities. Riparian hydropolitics caters to differing objectives, needs and requirements of states making it difficult to administer the catchment. The diverse riparian objectives can be merged to form a holistic catchment objective of sustainable water resources development and management. It can be proposed to make a paradigm shift in the present-day transboundary water policy from riparian hydropolitics (in which the focal point of water resources use is hinged on state's need) to catchment hydropolitics (in which the interest of the basin inhabitants are accorded primacy holistically over state interests) and specifically wherein the water, environment, energy and food (WEEF) demands of the catchment are a priority and not of the states in particular. The demands of the basin pertaining to water, food and energy have to be fulfilled, keeping the environment and ecology healthy in a cooperative political framework; the need for which is overwhelming. In the present scenario, the policy for water resources development of a basin is segmented into independent uncoordinated parts controlled by various riparians; whereas in catchment hydropolitics the whole basin should be considered as a unit. The riparians should compromise a part of national interest and work in collaboration on a joint objective which works on the principle of the whole as against the part. Catchment hydropolitics may find greater interest in the more than 250

  12. Small Scale Irrigation within Water, Energy and Food Nexus Framework in Ethiopia.

    Science.gov (United States)

    Gerik, T.; Worqlul, A. W.; Yihun, D.; Bizimana, J. C.; Jeong, J.; Schmitter, P.; Srinivasan, R.; Richardson, J. W.; Clark, N.

    2017-12-01

    This study presents the nexus of food, energy and water framework in the context of small scale irrigation for vegetable production during the dry season in an irrigated agriculture system in Ethiopia. The study is based on detailed data collected in three sites of the Innovation Lab for Small Scale Irrigation (ILSSI) project in Ethiopia. The sites were Robit, Dangishta and Lemo and detailed field data was collected in 18 households in each site. The field data collected includes crop management (such as irrigation amount and dates, fertilizer rates, tillage practices, irrigation technologies, etc.) and agricultural production (crop yield, biomass, etc.) on tomato, onion and cabbage during the dry season. Four different water lifting technologies - namely rope with pulley and bucket, rope and washer pump, solar pump and motor pump - were used for water withdrawal from shallow groundwater wells. The Soil and Water Assessment Tool (SWAT) and Agricultural Policy Environmental eXtender (APEX) models were used in an integrated manner to assess water resource potential and develop water use efficiency of vegetables, which is a relationship between amount of water applied and vegetable yield. The water use efficiency for each vegetable crops were translated into energy requirement as pumping hours and potential irrigable areas for the water lifting technologies. This integrated approach was found useful to optimize water and energy use for sustainable food production using small scale irrigation. The holistic approach will not only provide a significant contribution to achieving food self-sufficiency, but will also be effective for optimizing agricultural input. Keyword: small scale irrigation, integrated modeling, water lifting technology, East Africa

  13. Tapping in synchrony with a perturbed metronome: the phase correction response to small and large phase shifts as a function of tempo.

    Science.gov (United States)

    Repp, Bruno H

    2011-01-01

    When tapping is paced by an auditory sequence containing small phase shift (PS) perturbations, the phase correction response (PCR) of the tap following a PS increases with the baseline interonset interval (IOI), leading eventually to overcorrection (B. H. Repp, 2008). Experiment 1 shows that this holds even for fixed-size PSs that become imperceptible as the IOI increases (here, from 400 to 1200 ms). Earlier research has also shown (but only for IOI=500 ms) that the PCR is proportionally smaller for large than for small PSs (B. H. Repp, 2002a, 2002b). Experiment 2 introduced large PSs and found smaller PCRs than in Experiment 1, at all of the same IOIs. In Experiments 3A and 3B, the author investigated whether the change in slope of the sigmoid function relating PCR and PS magnitudes occurs at a fixed absolute or relative PS magnitude across different IOIs (600, 1000, 1400 ms). The results suggest no clear answer; the exact shape of the function may depend on the range of PSs used in an experiment. Experiment 4 examined the PCR in the IOI range from 1000 to 2000 ms and found overcorrection throughout, but with the PCR increasing much more gradually than in Experiment 1. These results provide important new information about the phase correction process and pose challenges for models of sensorimotor synchronization, which presently cannot explain nonlinear PCR functions and overcorrection. Copyright © Taylor & Francis Group, LLC

  14. Rational design of tetraphenylethylene-based luminescent down-shifting molecules: photophysical studies and photovoltaic applications in a CdTe solar cell from small to large units.

    Science.gov (United States)

    Li, Yilin; Li, Zhipeng; Ablekim, Tursunjan; Ren, Tianhui; Dong, Wen-Ji

    2014-12-21

    A rational design strategy of novel fluorophores for luminescent down-shifting (LDS) application was proposed and tested in this paper. Three new fluorophores (1a-c) with specific intramolecular charge transfer (ICT) and aggregation-induced emission (AIE) characteristics were synthesized as LDS molecules for increasing the output short circuit current density (Jsc) of a CdTe solar cell. Photophysical studies of their solution and solid states, and photovoltaic measurements of their PMMA solid films applied on a CdTe solar cell suggested that the specific spectroscopic properties and Jsc enhancement effects of these molecules were highly related to their chemical structures. The Jsc enhancement effects of these fluorophores were measured on both a CdTe small cell and a large panel. An increase in the output Jsc by as high as 5.69% for a small cell and 8.88% for a large panel was observed. Compared to a traditional LDS molecule, Y083, these fluorophores exhibited more superior capabilities of LDS.

  15. Data gaps in evidence-based research on small water enterprises in developing countries.

    Science.gov (United States)

    Opryszko, Melissa C; Huang, Haiou; Soderlund, Kurt; Schwab, Kellogg J

    2009-12-01

    Small water enterprises (SWEs) are water delivery operations that predominantly provide water at the community level. SWEs operate beyond the reach of piped water systems, selling water to households throughout the world. Their ubiquity in the developing world and access to vulnerable populations suggests that these small-scale water vendors may prove valuable in improving potable water availability. This paper assesses the current literature on SWEs to evaluate previous studies and determine gaps in the evidence base. Piped systems and point-of-use products were not included in this assessment. Results indicate that SWES are active in urban, peri-urban and rural areas of Africa, Asia and Latin America. Benefits of SWEs include: no upfront connection fees; demand-driven and flexible to local conditions; and service to large populations without high costs of utility infrastructure. Disadvantages of SWEs include: higher charges for water per unit of volume compared with infrastructure-based utilities; lack of regulation; operation often outside legal structures; no water quality monitoring; increased potential for conflict with local utilities; and potential for extortion by local officials. No rigorous, evidence-based, peer-reviewed scientific studies that control for confounders examining the effectiveness of SWEs in providing potable water were identified.

  16. PRELIMINARY RESULTS OF QUALITY STUDY OF WATER FROM SMALL MICHALICE RESERVOIR ON WIDAWA RIVER

    Directory of Open Access Journals (Sweden)

    Mirosław Wiatkowski

    2014-10-01

    Full Text Available The paper presents an analysis of water quality of the small Michalice reservoir. A preliminary assessment of the reservoir water quality and its usability was made. The quality of water in the reservoir is particularly important as the main functions of the reservoir are agricultural irrigation, recreation and flood protection . The following physico-chemical parameters of the Widawa River were analyzed: NO3 -, NO2 -, NH4 +, PO4 3-, COD, water temperature, pH and electrolytic conductivity. Main descriptive statistical data were presented for the analyzed water quality indicators. The research results indicate that the reservoir contributed to the reduced concentrations of the following water quality indicators: nitrates, nitrites, phosphates, electrolytic conductivity and COD (in the outflowing water – St.3 in comparison to the water flowing into the reservoir – St.1. In the water flowing out of the Psurów reservoir higher values of the remaining indicators were observed if compared with the inflowing water. It was stated, as well, that analised waters are not vulnerable to nitrogen compounds pollution coming from the agricultural sources and are eutrophic. For purpose obtaining of the précised information about condition of Michalice reservoir water purity as well as river Widawa it becomes to continue the hydrological monitoring and water quality studies.

  17. Hydrogen production from water gas shift reaction in a high gravity (Higee) environment using a rotating packed bed

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Wei-Hsin; Syu, Yu-Jhih [Department of Greenergy, National University of Tainan, Tainan 700 (China)

    2010-10-15

    Hydrogen production via the water gas shift reaction (WGSR) was investigated in a high gravity environment. A rotating packed bed (RPB) reactor containing a Cu-Zn catalyst and spinning in the range of 0-1800 rpm was used to create high centrifugal force. The reaction temperature and the steam/CO ratio ranged from 250 to 350 C and 2 to 8, respectively. A dimensionless parameter, the G number, was derived to account for the effect of centrifugal force on the enhancement of the WGSR. With the rotor speed of 1800 rpm, the induced centrifugal force acting on the reactants was as high as 234 g on average in the RPB. As a result, the CO conversion from the WGSR was increased up to 70% compared to that without rotation. This clearly revealed that the centrifugal force was conducive to hydrogen production, resulting from intensifying mass transfer and elongating the path of the reactants in the catalyst bed. From Le Chatelier's principle, a higher reaction temperature or a lower steam/CO ratio disfavors CO conversion; however, under such a situation the enhancement of the centrifugal force on hydrogen production from the WGSR tended to become more significant. Accordingly, a correlation between the enhancement of CO conversion and the G number was established. As a whole, the higher the reaction temperature and the lower the steam/CO ratio, the higher the exponent of the G number function and the better the centrifugal force on the WGSR. (author)

  18. Nano-Scale Au Supported on Carbon Materials for the Low Temperature Water Gas Shift (WGS Reaction

    Directory of Open Access Journals (Sweden)

    Paula Sánchez

    2011-12-01

    Full Text Available Au-based catalysts supported on carbon materials with different structures such as graphite (G and fishbone type carbon nanofibers (CNF-F were prepared using two different methods (impregnation and gold-sol to be tested in the water gas shift (WGS reaction. Atomic absorption spectrometry, transmission electron microscopy (TEM, temperature-programmed oxidation (TPO, X-ray diffraction (XRD, Raman spectroscopy, elemental analyses (CNH, N2 adsorption-desorption analysis, temperature-programmed reduction (TPR and temperature-programmed decomposition were employed to characterize both the supports and catalysts. Both the crystalline nature of the carbon supports and the method of gold incorporation had a strong influence on the way in which Au particles were deposited on the carbon surface. The higher crystallinity and the smaller and well dispersed Au particle size were, the higher activity of the catalysts in the WGS reaction was noted. Finally, catalytic activity showed an important dependence on the reaction temperature and steam-to-CO molar ratio.

  19. Drivers and uncertainties of forecasted range shifts for warm-water fishes under climate and land cover change

    Science.gov (United States)

    Bouska, Kristen; Whitledge, Gregory W.; Lant, Christopher; Schoof, Justin

    2018-01-01

    Land cover is an important determinant of aquatic habitat and is projected to shift with climate changes, yet climate-driven land cover changes are rarely factored into climate assessments. To quantify impacts and uncertainty of coupled climate and land cover change on warm-water fish species’ distributions, we used an ensemble model approach to project distributions of 14 species. For each species, current range projections were compared to 27 scenario-based projections and aggregated to visualize uncertainty. Multiple regression and model selection techniques were used to identify drivers of range change. Novel, or no-analogue, climates were assessed to evaluate transferability of models. Changes in total probability of occurrence ranged widely across species, from a 63% increase to a 65% decrease. Distributional gains and losses were largely driven by temperature and flow variables and underscore the importance of habitat heterogeneity and connectivity to facilitate adaptation to changing conditions. Finally, novel climate conditions were driven by mean annual maximum temperature, which stresses the importance of understanding the role of temperature on fish physiology and the role of temperature-mitigating management practices.

  20. Water-Gas-Shift Membrane Reactor for High-Pressure Hydrogen Production. A comprehensive project report (FY2010 - FY2012)

    Energy Technology Data Exchange (ETDEWEB)

    Klaehn, John [Idaho National Lab. (INL), Idaho Falls, ID (United States); Peterson, Eric [Idaho National Lab. (INL), Idaho Falls, ID (United States); Orme, Christopher [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bhandari, Dhaval [General Electric Global Research, Niskayuna, New York (United States); Miller, Scott [General Electric Global Research, Niskayuna, New York (United States); Ku, Anthony [General Electric Global Research, Niskayuna, New York (United States); Polishchuk, Kimberly [General Electric Global Research, Niskayuna, New York (United States); Narang, Kristi [General Electric Global Research, Niskayuna, New York (United States); Singh, Surinder [General Electric Global Research, Niskayuna, New York (United States); Wei, Wei [General Electric Global Research, Niskayuna, New York (United States); Shisler, Roger [General Electric Global Research, Niskayuna, New York (United States); Wickersham, Paul [General Electric Global Research, Niskayuna, New York (United States); McEvoy, Kevin [General Electric Global Research, Niskayuna, New York (United States); Alberts, William [General Electric Global Research, Niskayuna, New York (United States); Howson, Paul [General Electric Global Research, Niskayuna, New York (United States); Barton, Thomas [Western Research inst., Laramie, WY (United States); Sethi, Vijay [Western Research inst., Laramie, WY (United States)

    2013-01-01

    Idaho National Laboratory (INL), GE Global Research (GEGR), and Western Research Institute (WRI) have successfully produced hydrogen-selective membranes for water-gas-shift (WGS) modules that enable high-pressure hydrogen product streams. Several high performance (HP) polymer membranes were investigated for their gas separation performance under simulated (mixed gas) and actual syngas conditions. To enable optimal module performance, membranes with high hydrogen (H2) selectivity, permeance, and stability under WGS conditions are required. The team determined that the VTEC PI 80-051 and VTEC PI 1388 (polyimide from Richard Blaine International, Inc.) are prime candidates for the H2 gas separations at operating temperatures (~200°C). VTEC PI 80-051 was thoroughly analyzed for its H2 separations under syngas processing conditions using more-complex membrane configurations, such as tube modules and hollow fibers. These membrane formats have demonstrated that the selected VTEC membrane is capable of providing highly selective H2/CO2 separation (α = 7-9) and H2/CO separation (α = 40-80) in humidified syngas streams. In addition, the VTEC polymer membranes are resilient within the syngas environment (WRI coal gasification) at 200°C for over 1000 hours. The information within this report conveys current developments of VTEC PI 80-051 as an effective H2 gas separations membrane for high-temperature syngas streams.

  1. ENVIRONMENTAL FACTORS AND CHEMICAL AND MICROBIOLOGICAL WATER QUALITY CONSTITUTENTS RELATED TO THE PRESENCE OF ENTERIC VIRUSES IN GROUND WATER FROM SMALL PUBLIC WATER SUPPLIES IN SOUTHEASTERN MICHIGAN

    Science.gov (United States)

    A study of small public ground-water-supply wells that produce water from discontinuous sand and gravel aquifers was done from July 1999 through July 2001 in southeastern Michigan. Samples were collected to determine the occurrence of viral pathogens and microbiological indicato...

  2. Drinking Water Quality and Occurrence of Giardia in Finnish Small Groundwater Supplies

    Directory of Open Access Journals (Sweden)

    Tarja Pitkänen

    2015-08-01

    Full Text Available The microbiological and chemical drinking water quality of 20 vulnerable Finnish small groundwater supplies was studied in relation to environmental risk factors associated with potential sources of contamination. The microbiological parameters analyzed included the following enteric pathogens: Giardia and Cryptosporidium, Campylobacter species, noroviruses, as well as indicator microbes (Escherichia coli, intestinal enterococci, coliform bacteria, Clostridium perfringens, Aeromonas spp. and heterotrophic bacteria. Chemical analyses included the determination of pH, conductivity, TOC, color, turbidity, and phosphorus, nitrate and nitrite nitrogen, iron, and manganese concentrations. Giardia intestinalis was detected from four of the water supplies, all of which had wastewater treatment activities in the neighborhood. Mesophilic Aeromonas salmonicida, coliform bacteria and E. coli were also detected. None of the samples were positive for both coliforms and Giardia. Low pH and high iron and manganese concentrations in some samples compromised the water quality. Giardia intestinalis was isolated for the first time in Finland in groundwater wells of public water works. In Europe, small water supplies are of great importance since they serve a significant sector of the population. In our study, the presence of fecal indicator bacteria, Aeromonas and Giardia revealed surface water access to the wells and health risks associated with small water supplies.

  3. Simulation of water-energy fluxes through small-scale reservoir systems under limited data availability

    Science.gov (United States)

    Papoulakos, Konstantinos; Pollakis, Giorgos; Moustakis, Yiannis; Markopoulos, Apostolis; Iliopoulou, Theano; Dimitriadis, Panayiotis; Koutsoyiannis, Demetris; Efstratiadis, Andreas

    2017-04-01

    Small islands are regarded as promising areas for developing hybrid water-energy systems that combine multiple sources of renewable energy with pumped-storage facilities. Essential element of such systems is the water storage component (reservoir), which implements both flow and energy regulations. Apparently, the representation of the overall water-energy management problem requires the simulation of the operation of the reservoir system, which in turn requires a faithful estimation of water inflows and demands of water and energy. Yet, in small-scale reservoir systems, this task in far from straightforward, since both the availability and accuracy of associated information is generally very poor. For, in contrast to large-scale reservoir systems, for which it is quite easy to find systematic and reliable hydrological data, in the case of small systems such data may be minor or even totally missing. The stochastic approach is the unique means to account for input data uncertainties within the combined water-energy management problem. Using as example the Livadi reservoir, which is the pumped storage component of the small Aegean island of Astypalaia, Greece, we provide a simulation framework, comprising: (a) a stochastic model for generating synthetic rainfall and temperature time series; (b) a stochastic rainfall-runoff model, whose parameters cannot be inferred through calibration and, thus, they are represented as correlated random variables; (c) a stochastic model for estimating water supply and irrigation demands, based on simulated temperature and soil moisture, and (d) a daily operation model of the reservoir system, providing stochastic forecasts of water and energy outflows. Acknowledgement: This research is conducted within the frame of the undergraduate course "Stochastic Methods in Water Resources" of the National Technical University of Athens (NTUA). The School of Civil Engineering of NTUA provided moral support for the participation of the students

  4. Study of the water-gas shift reaction on Mo2C/Mo catalytic coatings for application in microstructured fuel processors

    NARCIS (Netherlands)

    Rebrov, E.V.; Kuznetsov, S.A.; Croon, de M.H.J.M.; Schouten, J.C.

    2007-01-01

    The activity and stability of two types of molybdenum carbide coatings deposited on molybdenum substrates (Mo2C/Mo) were compared in the water-gas shift reaction at 513–631 K. The activity of the Mo2C/Mo coatings obtained by carburization of preoxidized molybdenum substrates in a CH4/H2 mixture at

  5. Role of Re in Pt-Re/TiO2 catalyst for water gas shift reaction: A mechanistic and kinetic study.

    NARCIS (Netherlands)

    Azzam, K.G.H.; Babych, Igor V.; Seshan, Kulathuiyer; Lefferts, Leonardus

    2008-01-01

    Transient kinetic studies and in situ FTIR spectroscopy were used to follow the reaction sequences that occur during water gas shift (WGS) reaction over Pt–Re/TiO2 catalyst. Results pointed to contributions of an associative formate route with redox regeneration and two classical redox routes

  6. Structure of fullerene aggregates in pyridine/water solutions by small-angle neutron scattering

    International Nuclear Information System (INIS)

    Aksenov, V.L.; Belushkin, A.V.; Avdeev, M.V.; Rosta, L.; Mihailovic, D.; Mrzel, A.; Serdyuk, I.N.; Timchenko, A.A.

    2001-01-01

    Results of small-angle neutron scattering experiments on fullerenes (C 60 ) in pyridine/water solutions are reported. They confirm conclusions of the previous studies, in particular, dynamic light scattering experiments. Aggregates with characteristic radius of about 20 nm are formed in the solutions. The contrast variation using different combinations of protonated/deuterated components (water and pyridine) of the solutions points to the small pyridine content inside the aggregates. This fact testifies that the aggregates consist of a massive fullerene core covered by a thin pyridine shell

  7. Piped water consumption in Ghana: A case study of temporal and spatial patterns of clean water demand relative to alternative water sources in rural small towns.

    Science.gov (United States)

    Kulinkina, Alexandra V; Kosinski, Karen C; Liss, Alexander; Adjei, Michael N; Ayamgah, Gilbert A; Webb, Patrick; Gute, David M; Plummer, Jeanine D; Naumova, Elena N

    2016-07-15

    Continuous access to adequate quantities of safe water is essential for human health and socioeconomic development. Piped water systems (PWSs) are an increasingly common type of water supply in rural African small towns. We assessed temporal and spatial patterns in water consumption from public standpipes of four PWSs in Ghana in order to assess clean water demand relative to other available water sources. Low water consumption was evident in all study towns, which manifested temporally and spatially. Temporal variability in water consumption that is negatively correlated with rainfall is an indicator of rainwater preference when it is available. Furthermore, our findings show that standpipes in close proximity to alternative water sources such as streams and hand-dug wells suffer further reductions in water consumption. Qualitative data suggest that consumer demand in the study towns appears to be driven more by water quantity, accessibility, and perceived aesthetic water quality, as compared to microbiological water quality or price. In settings with chronic under-utilization of improved water sources, increasing water demand through household connections, improving water quality with respect to taste and appropriateness for laundry, and educating residents about health benefits of using piped water should be prioritized. Continued consumer demand and sufficient revenue generation are important attributes of a water service that ensure its function over time. Our findings suggest that analyzing water consumption of existing metered PWSs in combination with qualitative approaches may enable more efficient planning of community-based water supplies and support sustainable development. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. The influence of small-mammal burrowing activity on water storage at the Hanford Site

    International Nuclear Information System (INIS)

    Landeen, D.S.

    1994-01-01

    This paper summarizes the activities that were conducted in support of the long-term surface barrier development program by Westinghouse Hanford Company to determine the degree that small-mammal burrow systems affect the loss or retention of water in the soils at the Hanford Site in Washington state. An animal intrusion lysimeter facility was constructed, consisting of two outer boxes buried at grade, which served as receptacles for six animal intrusion lysimeters. Small burrowing animals common the Hanford Site were introduced over a 3- to 4-month period. Supplemental precipitation was added monthly to three of the lysimeters with a rainfall simulator (rainulator). Information collected from the five tests indicated that (1) during summer months, water was lost in all the lysimeters, including the supplemental precipitation added with the rainulator; and (2) during winter months, all lysimeters gained water. The data indicate little difference in the amount of water stored between control and animal lysimeters. The overall water loss was attributed to surface evaporation, a process that occurred equally in control and treatment lysimeters. Other causes of water loss are a result of (1) constant soil turnover and subsequent drying, and (2) burrow ventilation effects. This suggests that burrow systems will not contribute to any significant water storage at depth and, in fact, may enhance the removal of water from the soil

  9. Fluid Shifts

    Science.gov (United States)

    Stenger, M. B.; Hargens, A. R.; Dulchavsky, S. A.; Arbeille, P.; Danielson, R. W.; Ebert, D. J.; Garcia, K. M.; Johnston, S. L.; Laurie, S. S.; Lee, S. M. C.; hide

    2017-01-01

    Introduction. NASA's Human Research Program is focused on addressing health risks associated with long-duration missions on the International Space Station (ISS) and future exploration-class missions beyond low Earth orbit. Visual acuity changes observed after short-duration missions were largely transient, but now more than 50 percent of ISS astronauts have experienced more profound, chronic changes with objective structural findings such as optic disc edema, globe flattening and choroidal folds. These structural and functional changes are referred to as the visual impairment and intracranial pressure (VIIP) syndrome. Development of VIIP symptoms may be related to elevated intracranial pressure (ICP) secondary to spaceflight-induced cephalad fluid shifts, but this hypothesis has not been tested. The purpose of this study is to characterize fluid distribution and compartmentalization associated with long-duration spaceflight and to determine if a relation exists with vision changes and other elements of the VIIP syndrome. We also seek to determine whether the magnitude of fluid shifts during spaceflight, as well as any VIIP-related effects of those shifts, are predicted by the crewmember's pre-flight status and responses to acute hemodynamic manipulations, specifically posture changes and lower body negative pressure. Methods. We will examine a variety of physiologic variables in 10 long-duration ISS crewmembers using the test conditions and timeline presented in the figure below. Measures include: (1) fluid compartmentalization (total body water by D2O, extracellular fluid by NaBr, intracellular fluid by calculation, plasma volume by CO rebreathe, interstitial fluid by calculation); (2) forehead/eyelids, tibia, and calcaneus tissue thickness (by ultrasound); (3) vascular dimensions by ultrasound (jugular veins, cerebral and carotid arteries, vertebral arteries and veins, portal vein); (4) vascular dynamics by MRI (head/neck blood flow, cerebrospinal fluid

  10. Shift in the Equilibrium between On and Off States of the Allosteric Switch in Ras-GppNHp Affected by Small Molecules and Bulk Solvent Composition

    Energy Technology Data Exchange (ETDEWEB)

    Holzapfel, Genevieve; Buhrman, Greg; Mattos, Carla (NCSU)

    2012-08-31

    Ras GTPase cycles between its active GTP-bound form promoted by GEFs and its inactive GDP-bound form promoted by GAPs to affect the control of various cellular functions. It is becoming increasingly apparent that subtle regulation of the GTP-bound active state may occur through promotion of substates mediated by an allosteric switch mechanism that induces a disorder to order transition in switch II upon ligand binding at an allosteric site. We show with high-resolution structures that calcium acetate and either dithioerythritol (DTE) or dithiothreitol (DTT) soaked into H-Ras-GppNHp crystals in the presence of a moderate amount of poly(ethylene glycol) (PEG) can selectively shift the equilibrium to the 'on' state, where the active site appears to be poised for catalysis (calcium acetate), or to what we call the 'ordered off' state, which is associated with an anticatalytic conformation (DTE or DTT). We also show that the equilibrium is reversible in our crystals and dependent on the nature of the small molecule present. Calcium acetate binding in the allosteric site stabilizes the conformation observed in the H-Ras-GppNHp/NOR1A complex, and PEG, DTE, and DTT stabilize the anticatalytic conformation observed in the complex between the Ras homologue Ran and Importin-{beta}. The small molecules are therefore selecting biologically relevant conformations in the crystal that are sampled by the disordered switch II in the uncomplexed GTP-bound form of H-Ras. In the presence of a large amount of PEG, the ordered off conformation predominates, whereas in solution, in the absence of PEG, switch regions appear to remain disordered in what we call the off state, unable to bind DTE.

  11. Enhancing the production of hydrogen via water-gas shift reaction using Pd-based membrane reactors

    Energy Technology Data Exchange (ETDEWEB)

    Mendes, Diogo; Chibante, Vania; Mendes, Adelio; Madeira, Luis M. [LEPAE, Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Zheng, Ju-Meng [Dutch Separation Technology Institute (DSTI), 3800 AE Amersfoort (Netherlands); Tosti, Silvano; Borgognoni, Fabio [ENEA, Unita Tecnica Fusione, C.R. ENEA Frascati, Via E. Fermi 45, Frascati (RM) I-00044 (Italy)

    2010-11-15

    In this work, it is described an experimental study regarding the performance of a Pd-Ag membrane reactor recently proposed and suitable for the production of ultra-pure hydrogen. A dense metallic permeator tube was assembled by an innovative annealing and diffusion welding technique from a commercial flat sheet membrane of Pd-Ag. A ''finger-like'' configuration of the self-supported membrane has been designed and used as a packed-bed membrane reactor (MR) for producing ultra-pure hydrogen via water-gas shift reaction (WGS). A CuO/ZnO/Al{sub 2}O{sub 3} catalyst, from REB Research and Consulting, was used for packing the WGS membrane reactor. The performance of the reactor was evaluated in terms of CO conversion and H{sub 2} recovery in a wide range of conditions: temperature from 200 C to 300 C, feed pressure from 1.0 bar to 4.0 bar, vacuum and sweep-gas modes and with a simulated reformate feed (4.70% CO, 34.78% H{sub 2}O, 28.70% H{sub 2}, 10.16% CO{sub 2} balanced in N{sub 2}). Also, the effect of the reactants feed composition was investigated and discussed. CO conversions remained in most conditions above the thermodynamic equilibrium based on feed conditions. In particular, it is worth mentioning that around 100% of CO conversion and almost complete H{sub 2} recovery was achieved when operating the MR at 300 C with a GSHV = 1200 L{sub N} kg{sub cat}{sup -1} h{sup -1}, P{sub feed} = 4 bar, P{sub perm} = 3 bar and using 1000 mL{sub N} min{sup -1} of sweep-gas. (author)

  12. Morphology-Dependent Properties of Cu/CeO2 Catalysts for the Water-Gas Shift Reaction

    Directory of Open Access Journals (Sweden)

    Zhibo Ren

    2017-02-01

    Full Text Available CeO2 nanooctahedrons, nanorods, and nanocubes were prepared by the hydrothermal method and were then used as supports of Cu-based catalysts for the water-gas shift (WGS reaction. The chemical and physical properties of these catalysts were characterized by X-ray diffraction (XRD, transmission electron microscopy (TEM, N2 adsorption/desorption, UV-Vis spectroscopy, X-ray photoelectron spectroscopy (XPS, hydrogen temperature-programmed reduction (H2-TPR and in situ diffuse reflectance infra-red fourier transform spectroscopy (DRIFTS techniques. Characterization results indicate that the morphology of the CeO2 supports, originating from the selective exposure of different crystal planes, has a distinct impact on the dispersion of Cu and the catalytic properties. The nanooctahedron CeO2 catalyst (Cu-CeO2-O showed the best dispersion of Cu, the largest amount of moderate copper oxide, and the strongest Cu-support interaction. Consequently, the Cu-CeO2-O catalyst exhibited the highest CO conversion at the temperature range of 150–250 °C when compared with the nanocube and nanorod Cu-CeO2 catalysts. The optimized Cu content of the Cu-CeO2-O catalysts is 10 wt % and the CO conversion reaches 91.3% at 300 °C. A distinctive profile assigned to the evolution of different types of carbonate species was observed in the 1000–1800 cm−1 region of the in situ DRIFTS spectra and a particular type of carbonate species was identified as a potential key reaction intermediate at low temperature.

  13. Atomic level study of water-gas shift catalysts via transmission electron microscopy and x-ray spectroscopy

    Science.gov (United States)

    Akatay, Mehmed Cem

    Water-gas shift (WGS), CO + H2O ⇆ CO2 + H2 (DeltaH° = -41 kJ mol -1), is an industrially important reaction for the production of high purity hydrogen. Commercial Cu/ZnO/Al2O3 catalysts are employed to accelerate this reaction, yet these catalysts suffer from certain drawbacks, including costly regeneration processes and sulfur poisoning. Extensive research is focused on developing new catalysts to replace the current technology. Supported noble metals stand out as promising candidates, yet comprise intricate nanostructures complicating the understanding of their working mechanism. In this study, the structure of the supported Pt catalysts is explored by transmission electron microscopy and X-ray spectroscopy. The effect of the supporting phase and the use of secondary metals on the reaction kinetics is investigated. Structural heterogeneities are quantified and correlated with the kinetic descriptors of the catalysts to develop a fundamental understanding of the catalytic mechanism. The effect of the reaction environment on catalyst structure is examined by in-situ techniques. This study benefitted greatly from the use of model catalysts that provide a convenient medium for the atomic level characterization of nanostructures. Based on these studies, Pt supported on iron oxide nano islands deposited on inert spherical alumina exhibited 48 times higher WGS turnover rate (normalized by the total Pt surface area) than Pt supported on bulk iron oxide. The rate of aqueous phase glycerol reforming reaction of Pt supported on multiwall carbon nanotubes (MWCNT) is promoted by co-impregnating with cobalt. The synthesis resulted in a variety of nanostructures among which Pt-Co bimetallic nanoparticles are found to be responsible for the observed promotion. The unprecedented WGS rate of Pt supported on Mo2C is explored by forming Mo 2C patches on top of MWCNTs and the rate promotion is found to be caused by the Pt-Mo bimetallic entities.

  14. Role of small-scale independent providers in water and sanitation

    NARCIS (Netherlands)

    M.P. van Dijk (Meine Pieter)

    2008-01-01

    textabstractSmall-scale independent providers (SSIPs) and households are good for 10–69% of the household water supply and sometimes up to 95% of the sanitation solutions in cities in developing countries. Different types of SSIP can be distinguished. They could be allowed to make a more important

  15. Influence of soil and water conservation techniques on yield of small ...

    African Journals Online (AJOL)

    The study determined the application of soil and water conservation techniques in relation to yield of small-holder swamp rice farmers in Imo State, Nigeria in 2009. Specifically, the socio-economic characteristics of the farmer were described, their influence on the application of the techniques examined and relationship of ...

  16. The Costs of Small Drinking Water Systems Removing Arsenic from Groundwater

    Science.gov (United States)

    Between 2003 and 2011, EPA conducted an Arsenic Demonstration Program whereby the Agency purchased, installed and evaluated the performance and cost of 50 small water treatment systems scattered across the USA. A major goal of the program was to collect high-quality cost data (c...

  17. Design characteristics for pressurized water small modular nuclear power reactors with focus on safety

    Energy Technology Data Exchange (ETDEWEB)

    Kani, Iraj Mahmoudzadeh [Tehran Univ. (Iran, Islamic Republic of). Civil Faculty; Zandieh, Mehdi [Tehran Univ. (Iran, Islamic Republic of). Civil Faculty; International Univ. of Imam Khomeini (Iran, Islamic Republic of). Architecture Faculty; Abadi, Saeed Kheirollahi Hossein [International Univ. of Imam Khomeini (Iran, Islamic Republic of). Architecture Faculty

    2016-05-15

    Small Modular Reactors (SMRs) are a technology, attracting attention. Light water SMR possess an upgraded design case and emphasize the significance of integral models. Beside of these advantages, SMRs has faced numerous challenges, e.g. licensing, cost/investment, safety and security observation, social and environmental issues in building new plants.

  18. 4 The Impact of Small scale Mining on Irrigation Water.cdr

    African Journals Online (AJOL)

    user

    has over the years created numerous employment, especially, in rural areas where there are limited formal sector jobs ... Small scale mining is a major threat to water resources and agricultural ..... upstream with a mean value of 49.8mg/l.

  19. Designing Decentralized Water and Electricity Supply System for Small Recreational Facilities in the South of Russia

    Science.gov (United States)

    Kasharin, D. V.

    2017-11-01

    The article tackles the issues of designing seasonal water and power supply systems for small recreational facilities in the south of Russia based on intelligent decision support systems. The paper proposes modular prefabricated shell water and power supply works (MPSW&PW) along with energy-efficient standalone water-treatment plants as the principal facilities compliant with the environmental and infrastructural requirements applied to specially protected areas and ensuring the least possible damage to the environment due to a maximum possible use of local construction materials characterized by impressive safety margins in highly seismic environments. The task of designing water and power supply systems requires the consideration of issues pertaining to the development of an intelligent GIS-based system for the selection of water intake sites that facilitate automation of data-processing systems using a priori scanning methods with a variable step and random directions. The paper duly addresses such issues and develops parameterized optimization algorithms for MPSW&PW shell facilities. It equally provides the substantiation of water-treatment plants intelligent design based on energy recovery reverse osmosis and nanofiltration plants that enhance the energy efficiency of such plants serving as the optimum solution for the decentralized water supply of small recreational facilities from renewable energy sources.

  20. Appropriate technology for rural India - solar decontamination of water for emergency settings and small communities.

    Science.gov (United States)

    Kang, Gagandeep; Roy, Sheela; Balraj, Vinohar

    2006-09-01

    A commercial solar water heating system was evaluated for its effectiveness in decontaminating drinking water with a view to use in emergency situations. A total of 18 seeding experiments carried out over 6 months with 10(5) to 10(7)Escherichia coli/ml showed that the solar heater produced 125 l of bacteriologically safe water in 4 h when the ambient temperature was above 30 degrees C, with a holding time of at least 2 h. The solar water heating system is inexpensive, easy to transport and set up and could provide safer drinking water for 50 people a day. It would be effective in the decrease and prevention of waterborne disease in emergency situations, and is appropriate for use in small communities.

  1. Environmental impacts of small dams on agriculture and ground water development: a case study of Khan pur Dam, Pakistan

    International Nuclear Information System (INIS)

    Ejaz, N.; Shahmim, M.A.; Elahi, A.; Khan, N.M.

    2012-01-01

    The water scarcity issues are increasing through out the world. Pakistan is also facing water crises and its water demands are increasing every day. During this research it is investigated that small dams are playing an important role for the sustainability of groundwater and agriculture. The main objective of this study was to assess the environmental impacts of small dam on agricultural and ground water. Proper planning and management of small dams may improve the sustainable agriculture in Pakistan. It is also concluded that small dams are significantly contributing towards economy, environment, local climate, recreational activities and crop production. Small dams can also be utilized for the production of electricity at local level. On the other hand, water management issues can be resolved by the involvement of local farmer's associations. Water losses through seepage, unlined channels and old irrigation methods are most critical in developing world. Considering the overall positive environmental impacts, construction of small dams must be promoted. (author)

  2. Analysis of change of retention capacity of a small water reservoir

    Science.gov (United States)

    Výleta, R.; Danáčová, M.; Valent, P.

    2017-10-01

    This study is focused on the analysis of the changes of retention capacity of a small water reservoir induced by intensive erosion and sedimentation processes. The water reservoir is situated near the village of Vrbovce in the Western part of Slovakia, and the analysis is carried out for a period 2008-2017. The data used to build a digital elevation model (DEM) of the reservoir’s bed came from a terrain measurement, utilizing an acoustic Doppler current profiler (ADCP) to measure the water depth in the reservoir. The DEM was used to quantify the soil loss from agricultural land situated within the basin of the reservoir. The ability of the water reservoir to transform a design flood with a return period of 100 years is evaluated for both design (2008) and current conditions (2017). The results show that the small water reservoir is a subject to siltation, with sediments comprised of fine soil particles transported from nearby agricultural land. The ability of the water reservoir to transform a 100-year flood has not changed significantly. The reduction of the reservoir’s retention capacity should be systematically and regularly monitored in order to adjust its operational manual and improve its efficiency.

  3. Effect of water purification process in radioactive content: analysis on small scale purification plants

    International Nuclear Information System (INIS)

    Lopez del Rio, H.; Quiroga S, J. C.; Davila R, J. I.; Mireles G, F.

    2009-10-01

    Water from small scale purification plants is a low cost alternative for consumers in comparison to the bottled commercial presentations. Because of its low cost per liter, the consumption of this product has increased in recent years, stimulating in turn the installation of purification systems for these small businesses. The purpose of this study was to estimate the efficiency of small scale purification systems located in the cities of Zacatecas and Guadalupe, Zacatecas, to reduce the radioactive content of water. It was measured the total alpha and beta activity in water samples of entry and exit to process, through the liquid scintillation technique. In general it was observed that the process is more efficient in removing alpha that beta activity. The fraction of total alpha activity removed varied between 27 and 100%, while between 0 and 77% of the total beta activity was removed by the analyzed plants. In all cases, the total radioactivity level was lower than the maximum permissible value settled by the official mexican standard for drinking water. (Author)

  4. Small-cell lung cancer patients are just 'a little bit' tired : response shift and self-presentation in the measurement of fatigue

    NARCIS (Netherlands)

    Westerman, Marjan J.; The, Anne-Mei; Sprangers, Mirjam A. G.; Groen, Harry J. M.; van der Wal, Gerrit; Hak, Tony

    Background Response shift has gained increasing attention in the measurement of health-related quality of life (QoL) as it may explain counter-intuitive findings as a result of adaptation to deteriorating health. Objective To search for response shift type explanations to account for

  5. Ethanol synthesis and water gas shift over bifunctional sulfide catalysts. Final technical progress report, September 12, 1991--December 11, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Klier, K.; Herman, R.G.; Deemer, M.; Richards-Babb, M.; Carr, T.

    1995-07-01

    The objective of this research was to investigate sulfur-resistant catalysts for the conversion of synthesis gas having H{sub 2}/CO {le} 1 into C{sub 1}--C{sub 4} alcohols, especially ethanol, by a highly selective and efficient pathway, while also promoting the water gas shift reaction (WGSR). The catalysts chosen are bifunctional, base-hydrogenation, sulfur-tolerant transition metal sulfides with heavy alkali, e.g. Cs{sup +}, promoter dispersed on their surfaces. The modes of activation of H{sub 2} and CO on MoS{sub 2} and alkali-doped MoS{sub 2} were considered, and computational analyses of the thermodynamic stability of transition metal sulfides and of the electronic structure of these sulfide catalysts were carried out. In the preparation of the cesium-promoted MoS{sub 2} catalysts, a variety of preparation methods using CsOOCH were examined. In all cases, doping with CsOOCH led to a lost of surface area. The undoped molybdenum disulfide catalyst only produced hydrocarbons. Cs-doped MoS{sub 2} catalysts all produced linear alcohols, along with smaller amounts of hydrocarbons. With a 20 wt% CsOOCH/MoS{sub 2} catalyst, temperature, pressure, and flow rate dependences of the synthesis reactions were investigated in the presence and absence of H{sub 2}S in the H{sub 2}/CO = 1/1 synthesis gas during short term testing experiments. It was shown that with a carefully prepared 10 wt% CsOOCH/MoS{sub 2} catalyst, reproducible and high alcohol synthesis activity could be obtained. For example, at 295 C with H{sub 2}/CO = 1 synthesis gas at 8.3 MPa and with GHSV = 7,760 l/kg cat/hr, the total alcohol space time yield was ca 300 g/kg cat/hr (accompanied with a hydrocarbon space time yield of ca 60 g/kg cat/hr). Over a testing period of ca 130 hr, no net deactivation of the catalyst was observed. 90 refs., 82 figs., 14 tabs.

  6. Measurement of evaporative water loss in small animals by dew-point hygrometry.

    Science.gov (United States)

    Bernstein, M H; Hudson, D M; Stearns, J M; Hoyt, R W

    1977-08-01

    This paper presents the procedures and equations to be utilized for measurement of evaporative water loss (mw), by use of the dew-point hygrometer, in small animals exposed to air containing water vapor in an open-flow system. The system accounted accurately for the water evaporated from a bubble flask. In addition, hygrometric measurements of pulmocutaneous mw in pigeons (Columba livia, mean mass 0.31 kg) agreed closely with simultaneous gravimetric measurements, utilizing a desiccant in the sample stream, in a manner independently of air temperature (Ta, 20 or 40 degrees C), ambient water vapor pressure (PW, 4-16 10(2) Pa), or mw (5-66 mg-min-1). Evaporation in pigeons was independent of PW at 20 degrees C, but increased with decreasing PW at 40 degrees C, suggesting differences in ventilatory adjustments to changes in PW at the two temperatures.

  7. Heat transfer with water in forced convection without boiling in small diameter tubes

    International Nuclear Information System (INIS)

    Ricque, Roger; Siboul, Roger

    1969-01-01

    This note presents the measurements performed for the establishment of an empirical heat transfer law for water in forced convection without boiling in small diameter tubes (2 and 4 mm), with high flow velocity and strong heat flux, and for relatively low fluid temperatures. A correlation of experimental points is obtained with a very small maximum dispersion: Nu fl = 0,0092 Re fl 0,88 Pr 0,5 (μ fl /μ p ) 0,14 . A correlation for the fiction coefficient is also presented [fr

  8. CHRISGAS Project. WP13: Ancillary and Novel Processes. Final Report: Separation of Hydrogen with Membranes Combined with Water Gas Shift Reaction

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Hervas, J. M.; Marono, M.; Barreiro, M. M.

    2011-05-13

    Oxygen pressurized gasification of biomass out stands as a very promising approach to obtain energy or hydrogen from renewable sources. The technical feasibility of this technology has been investigated under the scope of the VI FP CHRISGAS project, which started in September 2004 and had a duration of five and a half years. The Division of Combustion and Gasification of CIEMAT participated in this project in Work Package 13: Ancillary and novel processes, studying innovative gas separation and gas upgrading systems. Such systems include novel or available high temperature water gas shift catalysts and commercially available membranes not yet tried in this type of atmosphere. This report describes the activities carried out during the project regarding the performance of high temperature water gas shift catalysts for upgrading of synthesis gas obtained from biomass gasification, the separation of H2 with selective membranes and the combination of both processes in one by means of a catalytic membrane reactor. (Author) 20 refs.

  9. CHRISGAS Project. WP13: Ancillary and Novel Processes. Final Report: Separation of Hydrogen with Membranes Combined with Water Gas Shift Reaction

    International Nuclear Information System (INIS)

    Sanchez-Hervas, J. M.; Marono, M.; Barreiro, M. M.

    2011-01-01

    Oxygen pressurized gasification of biomass out stands as a very promising approach to obtain energy or hydrogen from renewable sources. The technical feasibility of this technology has been investigated under the scope of the VI FP CHRISGAS project, which started in September 2004 and had a duration of five and a half years. The Division of Combustion and Gasification of CIEMAT participated in this project in Work Package 13: Ancillary and novel processes, studying innovative gas separation and gas upgrading systems. Such systems include novel or available high temperature water gas shift catalysts and commercially available membranes not yet tried in this type of atmosphere. This report describes the activities carried out during the project regarding the performance of high temperature water gas shift catalysts for upgrading of synthesis gas obtained from biomass gasification, the separation of H2 with selective membranes and the combination of both processes in one by means of a catalytic membrane reactor. (Author) 20 refs.

  10. Theoretical simulation of small scale psychometric solar water desalination system in semi-arid region

    International Nuclear Information System (INIS)

    Shatat, Mahmoud; Omer, Siddig; Gillott, Mark; Riffat, Saffa

    2013-01-01

    Many countries around the world suffer from water scarcity. This is especially true in remote and semi-arid regions in the Middle East and North Africa (MENA) where per capita water supplies decline as populations increase. This paper presents the results of a theoretical simulation of an affordable small scale solar water desalination plant using the psychometric humidification and dehumidification process coupled with an evacuated tube solar collector with an area of about 2 m 2 . A mathematical model was developed to describe the system's operation. Then a computer program using Simulink Matlab software was developed to provide the governing equations for the theoretical calculations of the humidification and dehumidification processes. The experimental and theoretical values for the total daily distillate output were found to be closely correlated. After the experimental calibration of the mathematical model, a model simulating solar radiation under the climatic conditions in the Middle East region proved that the performance of the system could be improved to produce a considerably higher amount of fresh water, namely up to 17.5 kg/m 2 day. This work suggests that utilizing the concept of humidification and dehumidification, a compact water desalination unit coupled with solar collectors would significantly increase the potable water supply in remote area. It could be a unique solution of water shortages in such areas. -- Highlights: • An affordable small scale desalination system is proposed. • A mathematical model of the desalination system is developed and programmed using Matlab Simulink. • The model describes the psychometric process based on humidification and dehumidification. • The model is used in optimal selection of elements and operating conditions for solar desalination system. • The use of solar water desalination contributes significantly to reducing global warming

  11. The influence of small mammal burrowing activity on water storage at the Hanford Site

    International Nuclear Information System (INIS)

    Landeen, D.S.

    1994-09-01

    The amount and rate at which water may penetrate a protective barrier and come into contact with buried radioactive waste is a major concern. Because burrowing animals eventually will reside on the surface of any protective barrier, the effect these burrow systems may have on the loss or retention of water needs to be determined. The first section of this document summarizes the known literature relative to small mammals and the effects that burrowing activities have on water distribution, infiltration, and the overall impact of burrows on the ecosystem. Topics that are summarized include burrow air pressures, airflow, burrow humidity, microtopography, mounding, infiltration, climate, soil evaporation, and discussions of large pores relative to water distribution. The second section of this document provides the results of the study that was conducted at the Hanford Site to determine what effect small mammal burrows have on water storage. This Biointrusion task is identified in the Permanent Isolation Surface Barrier Development Plan in support of protective barriers. This particular animal intrusion task is one part of the overall animal intrusion task identified in Animal Intrusion Test Plan

  12. Linking seasonal surface water dynamics with methane emissions and export from small, forested wetlands

    Science.gov (United States)

    Hondula, K. L.; Palmer, M.

    2017-12-01

    One of the biggest uncertainties about global methane sources and sinks is attributed to uncertainties regarding wetland area and its dynamics. This is exacerbated by confusion over the role of small, shallow water bodies like Delmarva bay wetlands that could be categorized as both wetlands and ponds. These small inland water bodies are often poorly quantified due to their size, closed forest canopies, and inter- and intra-annual variability in surface water extent. We are studying wetland-rich areas on the Delmarva Peninsula in the U.S. mid-Atlantic to address this uncertainty at the scale of individual wetland ecosystems ( 1m depth). We estimated the size and temporal variability of the methane emissions source area by combining these measurements with daily estimates of the extent of surface water inundation derived from water level monitoring and a high-resolution digital elevation model. This knowledge is critical for informing land use decisions (e.g. restoring wetlands specifically for climate mitigation), the jurisdiction of environmental policies in the US, and for resolving major outstanding discrepancies in our understanding of the global methane budget.

  13. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    International Nuclear Information System (INIS)

    Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

    2008-01-01

    In this work we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations

  14. Quality Improvement of a Small Water Supply. A Practical Application of a Full System of Nanofiltration

    Directory of Open Access Journals (Sweden)

    R. Marin Galvin

    2013-04-01

    Full Text Available The THM level in the Spanish drinking water is limited to less than 0.100 mg/L, due to its potential toxicological effect on humans. This paper investigates the comparison of the results obtained in a small supply of water that historically presented THM contents out of the Spanish normative, versus the results there obtained when the treatment was modified with the inclusion of a nanofiltration system. So, the conventional treatment first applied was that of pre-oxidation with chlorine and/or KMnO4, followed by coagulation with aluminum salts directly on closed sand filter, and disinfection final by chlorination: with this system, THM levels lower than 0.100 mg/L were not always secured. Thus, to improve the water quality, a full system of nanofiltration was implemented, after the above treatment, consisting in: pre-filtration through cartridges, filtration over activated carbon, post-filtration for retaining impurities, and finally, nanofiltration and chlorination of water after nanofiltration. In this order, the new treatment scheme has usually produced water with maximum THM levels of 0.058 mg/L, and average values of 0.013 mg/L, 0.30 mg/L for organic matter concentrations, and water always microbiologically pure. Also, the contents of Fe, Mn and Al in the treated water were significantly reduced with respect to the previous situation without nanofiltration.

  15. In silico studies of the properties of water hydrating a small protein

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, Sudipta Kumar; Chakraborty, Kausik; Bandyopadhyay, Sanjoy, E-mail: sanjoy@chem.iitkgp.ernet.in [Molecular Modeling Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur - 721302 (India); Jana, Madhurima [Molecular Simulation Laboratory, Department of Chemistry, National Institute of Technology, Rourkela - 769008 (India)

    2014-12-14

    Atomistic molecular dynamics simulation of an aqueous solution of the small protein HP-36 has been carried out with explicit solvent at room temperature. Efforts have been made to explore the influence of the protein on the relative packing and ordering of water molecules around its secondary structures, namely, three α-helices. The calculations reveal that the inhomogeneous water ordering and density distributions around the helices are correlated with their relative hydrophobicity. Importantly, we have identified the existence of a narrow relatively dehydrated region containing randomly organized “quasi-free” water molecules beyond the first layer of “bound” waters at the protein surface. These water molecules with relatively weaker binding energies form the transition state separating the “bound” and “free” water molecules at the interface. Further, increased contribution of solid-like caging motions of water molecules around the protein is found to be responsible for reduced fluidity of the hydration layer. Interestingly, we notice that the hydration layer of helix-3 is more fluidic with relatively higher entropy as compared to the hydration layers of the other two helical segments. Such characteristics of helix-3 hydration layer correlate well with the activity of HP-36, as helix-3 contains the active site of the protein.

  16. In silico studies of the properties of water hydrating a small protein

    International Nuclear Information System (INIS)

    Sinha, Sudipta Kumar; Chakraborty, Kausik; Bandyopadhyay, Sanjoy; Jana, Madhurima

    2014-01-01

    Atomistic molecular dynamics simulation of an aqueous solution of the small protein HP-36 has been carried out with explicit solvent at room temperature. Efforts have been made to explore the influence of the protein on the relative packing and ordering of water molecules around its secondary structures, namely, three α-helices. The calculations reveal that the inhomogeneous water ordering and density distributions around the helices are correlated with their relative hydrophobicity. Importantly, we have identified the existence of a narrow relatively dehydrated region containing randomly organized “quasi-free” water molecules beyond the first layer of “bound” waters at the protein surface. These water molecules with relatively weaker binding energies form the transition state separating the “bound” and “free” water molecules at the interface. Further, increased contribution of solid-like caging motions of water molecules around the protein is found to be responsible for reduced fluidity of the hydration layer. Interestingly, we notice that the hydration layer of helix-3 is more fluidic with relatively higher entropy as compared to the hydration layers of the other two helical segments. Such characteristics of helix-3 hydration layer correlate well with the activity of HP-36, as helix-3 contains the active site of the protein

  17. Small Microbial Three-Electrode Cell Based Biosensor for Online Detection of Acute Water Toxicity.

    Science.gov (United States)

    Yu, Dengbin; Zhai, Junfeng; Liu, Changyu; Zhang, Xueping; Bai, Lu; Wang, Yizhe; Dong, Shaojun

    2017-11-22

    The monitoring of toxicity of water is very important to estimate the safety of drinking water and the level of water pollution. Herein, a small microbial three-electrode cell (M3C) biosensor filled with polystyrene particles was proposed for online monitoring of the acute water toxicity. The peak current of the biosensor related with the performance of the bioanode was regarded as the toxicity indicator, and thus the acute water toxicity could be determined in terms of inhibition ratio by comparing the peak current obtained with water sample to that obtained with nontoxic standard water. The incorporation of polystyrene particles in the electrochemical cell not only reduced the volume of the samples used, but also improved the sensitivity of the biosensor. Experimental conditions including washing time with PBS and the concentration of sodium acetate solution were optimized. The stability of the M3C biosensor under optimal conditions was also investigated. The M3C biosensor was further examined by formaldehyde at the concentration of 0.01%, 0.03%, and 0.05% (v/v), and the corresponding inhibition ratios were 14.6%, 21.6%, and 36.4%, respectively. This work provides a new insight into the development of an online toxicity detector based on M3C biosensor.

  18. Review of boiling water reactor small break loss of coolant accidents

    International Nuclear Information System (INIS)

    Gururaj, P.M.; Dua, S.S.; Rao, A.S.

    1981-01-01

    This paper presents a review of the analytical and the experimental work performed by the General Electric Company to determine the performance of boiling water reactors (BWR) following postulated small break accidents (SBA). This review paper addresses the following issues: (1) the response of the BWR following small loss of inventory events; (2) methods of analysis and their justification; (3) necessity, if any, of operator action and the length of time available in which such action can be performed; and (4) operator interface following the SBA event. The results from these SBA studies for different BWR product lines show that even with the multiple system failures assumed, the BWR can successfully withstand an SBA. For a typical BWR/6, it takes the failure of 13 water delivery pumps to cause any significant core heatup. The only operator actions determined to be necessary are simple ones and ample time is available to the operator to perform these actions, if needed

  19. Calculation of wastage by small water leaks in sodium heated steam generators

    International Nuclear Information System (INIS)

    Tregonning, K.

    1976-01-01

    On the basis of mechanistic arguments it is suggested that the temperature of the wasting surface would provide a single physically meaningful parameter with which to correlate wastage data. A lumped parameter model is developed which predicts reaction temperature as a function of the major variables in the small water leak situation (Leak rate, tube spacing, sodium temperature). The calculated temperatures explain much of the observed behaviour of wastage rate with these variables and compare well with the limited temperature data available. Wastage rates are correlated with predicted temperature on a total activation energy basis. The results are encouraging and a first conservative method for the calculation of wastage by small water leaks in sodium-heated steam generators is produced

  20. PHOSPHORUS CONTAMINATION AS A BARRIER TO WATER QUALITY OF SMALL RETENTION RESERVOIRS IN PODLASIE REGION

    Directory of Open Access Journals (Sweden)

    Joanna Ewa Szczykowska

    2016-06-01

    Full Text Available Dam retention reservoirs created on the rivers play a special role as an environmentally friendly forms of stopping and slowing of water runoff. The aim of this study was to evaluate the quality of water flowing into small retention reservoirs in terms of the concentration of total phosphorus and phosphates. The study involved three small retention reservoirs located in the municipalities of: Bransk, Dubicze Cerkiewne and Kleszczele in Podlasie region. Selection of the research facilities was made due to the similarity in the soil management type within catchment of the flowing watercourse, retained water utilization ways, and a small surface of reservoirs. Watercourse reaching the reservoir provides biogens along with water, which directly affect the water quality resulting in high concentrations in water, either indirectly by initiating or accelerating the process of degradation of the reservoir and the loss of its usability. Given the concentration of total phosphorus, it can be said that only in the case of 20.8% of water samples from Nurzec river feeding the Otapy-Kiersnówek reservoir, about 25% of water samples of Orlanka river feeding Bachmaty reservoir, and 17% of samples taken from the watercourse supplying Repczyce reservoir, corresponded to values specified for the second class in the current Regulation of the Minister of the Environment [Regulation 2014]. It can be assumed that this situation is caused by a long-term fertilization using manure, which in consequence led to the oversaturation of soils and phosphorus compounds penetration into the river waters in areas used for agricultural purposes. Especially in the early spring periods, rising temperature together with rainfall caused soil thawing resulting in increasing concentrations of contaminants carried along with the washed soil particles during the surface and subsurface runoff. Values of TSI(TP calculated for Otapy-Kiersnówek reservoir amounted to 112.4 in hydrological

  1. Small-scale, hydrogen-oxidizing-denitrifying bioreactor for treatment of nitrate-contaminated drinking water.

    Science.gov (United States)

    Smith, Richard L; Buckwalter, Seanne P; Repert, Deborah A; Miller, Daniel N

    2005-05-01

    Nitrate removal by hydrogen-coupled denitrification was examined using flow-through, packed-bed bioreactors to develop a small-scale, cost effective system for treating nitrate-contaminated drinking-water supplies. Nitrate removal was accomplished using a Rhodocyclus sp., strain HOD 5, isolated from a sole-source drinking-water aquifer. The autotrophic capacity of the purple non-sulfur photosynthetic bacterium made it particularly adept for this purpose. Initial tests used a commercial bioreactor filled with glass beads and countercurrent, non-sterile flow of an autotrophic, air-saturated, growth medium and hydrogen gas. Complete removal of 2 mM nitrate was achieved for more than 300 days of operation at a 2-h retention time. A low-cost hydrogen generator/bioreactor system was then constructed from readily available materials as a water treatment approach using the Rhodocyclus strain. After initial tests with the growth medium, the constructed system was tested using nitrate-amended drinking water obtained from fractured granite and sandstone aquifers, with moderate and low TDS loads, respectively. Incomplete nitrate removal was evident in both water types, with high-nitrite concentrations in the bioreactor output, due to a pH increase, which inhibited nitrite reduction. This was rectified by including carbon dioxide in the hydrogen stream. Additionally, complete nitrate removal was accomplished with wastewater-impacted surface water, with a concurrent decrease in dissolved organic carbon. The results of this study using three chemically distinct water supplies demonstrate that hydrogen-coupled denitrification can serve as the basis for small-scale remediation and that pilot-scale testing might be the next logical step.

  2. Small-angle light scattering studies of dense AOT-water-decane microemulsions

    International Nuclear Information System (INIS)

    Micali, N.; Trusso, S.; Mallamace, F.; Chen, S.H.

    1996-01-01

    It is performed extensive studies of a three-component microemulsion system composed of AOT-water-decane using small-angle light scattering (SALS). The small-angle scattering intensities are measured in the angular interval 0.001-0.1 radians, corresponding to a Bragg wave number range of 0.14 μm -1 -1 . The measurements were made by changing temperature and volume fraction φ of the dispersed phase in the range 0.65< φ < 0.75. All samples have a fixed water-to-AOT molar ratio, w [water[/[AOT[ = 40.8, in order to keep the same average droplet size in the stable one-phase region. With the SALS technique it is observed all the phase boundaries of a very complex phase diagram with a percolation line and many structural organizations within it. It is observed at the percolation transition threshold, a scaling behavior of the intensity data. In addition it is described in detail a structural transition from a droplet microemulsion to a bi continuous one a suggested by a recent small-angle neutron scattering experiment. From the data analysis it is show that both the percolation phenomenon and this novel structural transition are described from a large-scale aggregation between microemulsion droplets

  3. Small reservoir effects on headwater water quality in the rural-urban fringe, Georgia Piedmont, USA

    Directory of Open Access Journals (Sweden)

    Dr.. Amber R. Ignatius, Geographer

    2016-12-01

    Full Text Available Small reservoirs are prevalent landscape features that affect the physical, chemical, and biological characteristics of headwater streams. Tens of thousands of small reservoirs, often less than a hectare in size, were constructed over the past century within the United States. While remote-sensing and geographic-mapping technologies assist in identifying and quantifying these features, their localized influence on water quality is uncertain. We report a year-long physicochemical study of nine small reservoirs (0.15–2.17 ha within the Oconee and Broad River Watersheds in the Georgia Piedmont. Study sites were selected along an urban-rural gradient with differing amounts of agricultural, forested, and developed land covers. Sites were sampled monthly for discharge and inflow/outflow water quality parameters (temperature, specific conductance, pH, dissolved oxygen, turbidity, alkalinity, total phosphorus, total nitrogen, nitrate, ammonium. While the proportion of developed land cover within watersheds had positive correlations with reservoir specific conductivity values, agricultural and forested land covers showed correlations (positive and negative, respectively with reservoir alkalinity, total nitrogen, nitrate, and specific conductivity. The majority of outflow temperatures were warmer than inflows for all land uses throughout the year, especially in the summer. Outflows had lower nitrate concentrations, but higher ammonium. The type of outflow structure was also influential; top-release dams showed higher dissolved oxygen and pH than bottom-release dams. Water quality effects were still evident 250 m below the dam, albeit reduced.

  4. ACQUISION OF GEOMETRICAL DATA OF SMALL RIVERS WITH AN UNMANNED WATER VEHICLE

    Directory of Open Access Journals (Sweden)

    H. Sardemann

    2018-05-01

    Full Text Available Rivers with small- and medium-scaled catchments have been increasingly affected by extreme events, i.e. flash floods, in the last years. New methods to describe and predict these events are developed in the interdisciplinary research project EXTRUSO. Flash flood events happen on small temporal and spatial scales, stressing the necessity of high-resolution input data for hydrological and hydrodynamic modelling. Among others, the benefit of high-resolution digital terrain models (DTMs will be evaluated in the project. This article introduces a boat-based approach for the acquisition of geometrical and morphological data of small rivers and their banks. An unmanned water vehicle (UWV is used as a multi-sensor platform to collect 3D-point clouds of the riverbanks, as well as bathymetric measurements of water depth and river morphology. The UWV is equipped with a mobile Lidar, a panorama camera, an echo sounder and a positioning unit. Whole (sub- catchments of small rivers can be digitalized and provided for hydrological modelling when UWV-based and UAV (unmanned aerial vehicle based point clouds are fused.

  5. Simplified syntheses of the water-soluble chiral shift reagents Sm-(R)-pdta and Sm-(S)-pdta

    Czech Academy of Sciences Publication Activity Database

    Hrubá, L.; Buděšínský, Miloš; Pícha, Jan; Jiráček, Jiří; Vaněk, Václav

    2013-01-01

    Roč. 54, č. 47 (2013), s. 6296-6297 ISSN 0040-4039 Institutional support: RVO:61388963 Keywords : NMR * chiral shift reagents * Sm-pdta * PDTA * samarium * 1,2-diaminopropane Subject RIV: CC - Organic Chemistry Impact factor: 2.391, year: 2013

  6. The water equivalence of solid materials used for dosimetry with small proton beams

    International Nuclear Information System (INIS)

    Schneider, Uwe; Pemler, Peter; Besserer, Juergen; Dellert, Matthias; Moosburger, Martin; Boer, Jorrit de; Pedroni, Eros; Boehringer, Terence

    2002-01-01

    Various solid materials are used instead of water for absolute dosimetry with small proton beams. This may result in a dose measurement different to that in water, even when the range of protons in the phantom material is considered correctly. This dose difference is caused by the diverse cross sections for inelastic nuclear scattering in water and in the phantom materials respectively. To estimate the magnitude of this effect, flux and dose measurements with a 177 MeV proton pencil beam having a width of 0.6 cm (FWHM) were performed. The proton flux and the deposited dose in the beam path were determined behind water, lucite, polyethylene, teflon, and aluminum of diverse thicknesses. The number of out-scattered protons due to inelastic nuclear scattering was determined for water and the different materials. The ratios of the number of scattered protons in the materials relative to that in water were found to be 1.20 for lucite, 1.16 for polyethylene, 1.22 for teflon, and 1.03 for aluminum. The difference between the deposited dose in water and in the phantom materials taken in the center of the proton pencil beam, was estimated from the flux measurements, always taking the different ranges of protons in the materials into account. The estimated dose difference relative to water in 15 cm water equivalent thickness was -2.3% for lucite, -1.7% for polyethylene, -2.5% for teflon, and -0.4% for aluminum. The dose deviation was verified by a measurement using an ionization chamber. It should be noted that the dose error is larger when the effective point of measurement in the material is deeper or when the energy is higher

  7. Laboratory QA/QC improvements for small drinking water systems at Savannah River Site

    Energy Technology Data Exchange (ETDEWEB)

    Turner, R.D.

    1995-12-01

    The Savannah River Site (SRS), a 310 square mile facility located near Aiken, S.C., is operated by Westinghouse Savannah River Company for the US Department of Energy. SRS has 28 separate drinking water systems with average daily demands ranging from 0.0002 to 0.5 MGD. All systems utilize treated groundwater. Until recently, the water laboratories for each system operated independently. As a result, equipment, reagents, chemicals, procedures, personnel, and quality control practices differed from location to location. Due to this inconsistency, and a lack of extensive laboratory OA/QC practices at some locations, SRS auditors were not confident in the accuracy of daily water quality analyses results. The Site`s Water Services Department addressed these concerns by developing and implementing a practical laboratory QA/QC program. Basic changes were made which can be readily adopted by most small drinking water systems. Key features of the program include: Standardized and upgraded laboratory instrumentation and equipment; standardized analytical procedures based on vendor manuals and site requirements; periodic accuracy checks for all instrumentation; creation of a centralized laboratory to perform metals digestions and chlorine colorimeter accuracy checks; off-site and on-site operator training; proper storage, inventory and shelf life monitoring for reagents and chemicals. This program has enhanced the credibility and accuracy of SRS drinking water system analyses results.

  8. Small intestinal efflux mediated by MRP2 and BCRP shifts sulfasalazine intestinal permeability from high to low, enabling its colonic targeting.

    Science.gov (United States)

    Dahan, Arik; Amidon, Gordon L

    2009-08-01

    Sulfasalazine is characterized by low intestinal absorption, which essentially enables its colonic targeting and therapeutic action. The mechanisms behind this low absorption have not yet been elucidated. The purpose of this study was to investigate the role of efflux transporters in the intestinal absorption of sulfasalazine as a potential mechanism for its low small-intestinal absorption and colonic targeting following oral administration. The effects of P-glycoprotein (P-gp), multidrug resistance-associated protein 2 (MRP2), and breast cancer resistance protein (BCRP) inhibitors on sulfasalazine bidirectional permeability were studied across Caco-2 cell monolayers, including dose-response analysis. Sulfasalazine in vivo permeability was then investigated in the rat jejunum by single-pass perfusion, in the presence vs. absence of inhibitors. Sulfasalazine exhibited 19-fold higher basolateral-to-apical (BL-AP) than apical-to-basolateral (AP-BL) Caco-2 permeability, indicative of net mucosal secretion. MRP2 inhibitors (MK-571 and indomethacin) and BCRP inhibitors [fumitremorgin C (FTC) and pantoprazole] significantly increased AP-BL and decreased BL-AP sulfasalazine Caco-2 transport in a concentration-dependent manner. No effect was observed with the P-gp inhibitors verapamil and quinidine. The IC50 values of the specific MRP2 and BCRP inhibitors MK-571 and FTC on sulfasalazine secretion were 21.5 and 2.0 microM, respectively. Simultaneous inhibition of MRP2 and BCRP completely abolished sulfasalazine Caco-2 efflux. Without inhibitors, sulfasalazine displayed low (vs. metoprolol) in vivo intestinal permeability in the rat model. MK-571 or FTC significantly increased sulfasalazine permeability, bringing it to the low-high permeability boundary. With both MK-571 and FTC present, sulfasalazine displayed high permeability. In conclusion, efflux transport mediated by MRP2 and BCRP, but not P-gp, shifts sulfasalazine permeability from high to low, thereby enabling its

  9. Application of HEC-RAS water quality model to estimate contaminant spreading in small stream

    Energy Technology Data Exchange (ETDEWEB)

    Halaj, Peter; Bárek, Viliam; Halajová, Anna Báreková; Halajová, Denisa [Slovak University of Agriculture in Nitra, Nitra (Slovakia)

    2013-07-01

    The paper presents study of some aspects of HEC-RAS water quality model connected to simulation of contaminant transport in small stream. Authors mainly focused on one of the key tasks in process of pollutant transport modelling in streams - determination of the dispersion characteristics represented by longitudinal dispersion coefficient D. Different theoretical and empirical formulas have been proposed for D value determination and they have revealed that the coefficient is variable parameter that depends on hydraulic and morphometric characteristics of the stream reaches. Authors compare the results of several methods of coefficient D assessment, assuming experimental data obtained by tracer studies and compare them with results optimized by HEC-RAS water quality model. The analyses of tracer study and computation outputs allow us to outline the important aspects of longitudinal dispersion coefficient set up in process of the HEC-RAS model use. Key words: longitudinal dispersion coefficient, HEC-RAS, water quality modeling.

  10. Water balance of a small catchment with permeable soils in Ile-Ife area, southwester Nigeria

    International Nuclear Information System (INIS)

    Ogunkoya, O. O.

    2000-01-01

    Three - year and annual catchment water balances were drawn for a small l catchment (44 ha.) in southwestern Nigeria. The equation: P - Q - E T - Δs = O was not resolved. Rather, the terms on the left did not sum to zero. The residual, which are between 4% and 5% of total rainfall, were consistently negative. A probable source of error is the use of Thornthwaite's potential evaporation in estimating catchment evapotranspiration. Potential evapotranspiration is higher than actual evapotranspiration in the study area due to the limited evaporation opportunity during the approximately five - mouth dry season. Given that the study catchment had runoff patterns that are simi liar to those of larger rivers in the region the computed catchment water balance indicated that 37% of annual rainfall may be taken as the runoff coefficient for the region. This suggests that the engineer's coefficient (0.35 - 0.45) used in assessment of surface water resources in southwestern Nigeria, is reasonable

  11. Residual stress improved by water jet peening using cavitation for small-diameter pipe inner surfaces

    International Nuclear Information System (INIS)

    Yasuo, Nakamura; Toshizo, Ohya; Koji, Okimura

    2001-01-01

    As one of degradation conditions on components used in water, the overlapping effect of environment, material and stress might cause stress corrosion cracking (SCC). Especially, for the tensile residual stress produced by welding, it is particularly effective to reduce the tensile residual stress on the material surface to prevent SCC. In this paper, the residual stress improvement method using cavitation impact generated by a water jet, called Water Jet Peening (WJP), has been developed as the maintenance technology for the inner surfaces of small-diameter Ni-Cr-Fe alloy (Alloy 600) pipes. As the results, by WJP for the inner surface of Alloy 600 pipe (inner diameter; approximately 10-15 mm), we confirmed that the compressive stress generated within the range from the surface to the inner part about 0.5 mm deep and took a maximum value about 350 MPa on the surface. (author)

  12. Shifting Attention

    Science.gov (United States)

    Ingram, Jenni

    2014-01-01

    This article examines the shifts in attention and focus as one teacher introduces and explains an image that represents the processes involved in a numeric problem that his students have been working on. This paper takes a micro-analytic approach to examine how the focus of attention shifts through what the teacher and students do and say in the…

  13. Shifting Scarcities? The Energy Intensity of Water Supply Alternatives in the Mass Tourist Resort of Benidorm, Spain

    Directory of Open Access Journals (Sweden)

    Hyerim Yoon

    2018-03-01

    Full Text Available The energy intensity of water—‘energy (electricity-for-water’—is calculated for Benidorm, a mass tourism resort in the Spanish Mediterranean coast, where the urban water cycle has evolved in response to a series of episodes of water stress. The analysis is based on primary data compiled from various actors involved in the urban water cycle encompassing water extraction, end uses, and wastewater treatment, including tertiary treatment. The results provide one of the first analyses of the relations between energy and water in a mass tourist center, which may be of potential interest for other tourist areas. It is estimated that a total of 109 GWh/year of electricity is required to operate the water cycle of Benidorm. About 4% of total energy use in Benidorm is dedicated to extracting, transporting, and treating water. The most energy-intensive stage is represented by end uses, which accounts for 20% of the total energy use in Benidorm when the energy required for water pumping and hot water use is considered. Additionally, energy intensity for water extraction was estimated for normal, wet, and two dry year scenarios. In comparison with the normal scenario, energy intensity is six times larger when desalinated water is incorporated during a dry year, whereas the emergency interbasin water transfer resulted in a more moderate increase in energy intensity. While treated wastewater and emergency water transfers appear to be a more convenient solution in energy terms, the strong impulse given to desalination in Spain is forcing local water authorities towards the use of a resource that is much more energy intensive, although, on the other hand, much less dependent on the vagaries of climate. In light of recent technological and managerial developments, the Benidorm case illuminates the challenges appearing in the analysis of the water-energy nexus, especially the fact that scarcity may be transferred from water to energy.

  14. Mechanical spectral shift reactor

    International Nuclear Information System (INIS)

    Sherwood, D.G.; Wilson, J.F.; Salton, R.B.; Fensterer, H.F.

    1981-01-01

    A mechanical spectral shift reactor comprises apparatus for inserting and withdrawing water displacer elements from the reactor core for selectively changing the water-moderator volume in the core thereby changing the reactivity of the core. The apparatus includes drivemechanisms for moving the displacer elements relative to the core and guide mechanisms for guiding the displayer rods through the reactor vessel

  15. Mechanical spectral shift reactor

    International Nuclear Information System (INIS)

    Sherwood, D.G.; Wilson, J.F.; Salton, R.B.; Fensterer, H.F.

    1982-01-01

    A mechanical spectral shift reactor comprises apparatus for inserting and withdrawing water displacer elements from the reactor core for selectively changing the water-moderator volume in the core thereby changing the reactivity of the core. The apparatus includes drive mechanisms for moving the displacer elements relative to the core and guide mechanisms for guiding the displacer rods through the reactor vessel. (author)

  16. Planning and Corrupting Water Resources Development: The Case of Small Reservoirs in Ghana

    Directory of Open Access Journals (Sweden)

    Jean-Philippe Venot

    2011-10-01

    Full Text Available Agricultural (water development is once again at the fore of the development agenda of sub-Saharan Africa. Yet, corruption is seen as a major obstacle to the sustainability of future investments in the sector but there is still little empirical evidence on the ways corruption pervades development projects. This paper documents the planning and implementation processes of two specific small reservoir programmes in the north of Ghana. We specifically delve into the dynamics of corruption and interrogate the ways they add to the inherent unpredictability of development planning. We argue that operational limitations of small reservoirs such as poor infrastructure, lack of managerial and organisational capacity at the community level and weak market integration and public support are the symptoms – rather than inherent problems – of wider lapses in the planning processes that govern the development of small reservoirs in Ghana and plausibly worldwide. A suite of petty misconduct and corrupt practices during the planning, tendering, supervision, and administration of contracts for the rehabilitation and construction of small reservoirs results in delays in implementation, poor construction, escalating costs, and ultimately failures of small reservoirs vis-à-vis their intended goals and a widely shared frustration among donor agencies, civil servants, contractors, and communities. Such practices hang on and can only be addressed through a better understanding of the complex web of formal decisions and informal rules that shape the understanding and actions of the state.

  17. Uranium concentration in drinking water from small-scale water supplies in Schleswig-Holstein, Germany; Urankonzentration im Trinkwasser aus Hausbrunnen in Schleswig-Holstein

    Energy Technology Data Exchange (ETDEWEB)

    Ostendorp, G. [Landesamt fuer soziale Dienste, Kiel (Germany). Dezernat Umweltbezogener Gesundheitsschutz

    2015-07-01

    In this study the drinking water of 212 small-scale water supplies, mainly situated in areas with intensive agriculture or fruit-growing, was analysed for uranium. The median uranium concentration amounted to 0.04 μg/lL, the 95th percentile was 2.5 μg/L. The maximum level was 14 μg/L. This sample exceeded the guideline value for uranium in drinking water. The uranium concentration in small-scale water supplies was found to be slightly higher than that in central water works in Schleswig-Holstein. Water containing more than 10 mg/L nitrate showed significantly higher uranium contents. The results indicate that the uranium burden in drinking water from small wells is mainly determined by geological factors. An additional anthropogenic effect of soil management cannot be excluded. Overall uranium concentrations were low and not causing health concerns. However, in specific cases higher concentrations may occur.

  18. Impact of water-level changes to aquatic vegetation in small oligotrophic lakes

    Directory of Open Access Journals (Sweden)

    Egert VANDEL

    2016-06-01

    Full Text Available This study demonstrates the effect of drastic water-level changes to the aquatic vegetation in three small oligotrophic lakes situated in Kurtna Kame Field in north-eastern Estonia. The area holds around 40 lakes in 30 km2 of which 18 lakes are under protection as Natura Habitat lakes (Natura 2000 network. The area is under a strong human impact as it is surrounded by oil shale mines, sand quarry, peat harvesting field etc. The most severe impact comes from the groundwater intake established in 1972 in the vicinity of three studied lakes. The exploitation of groundwater led to drastic water-level drops. In 1980s the water-level drops were measured to be up to 3 to 4 meters compared to the levels of 1946. Lake Martiska and Lake Kuradijärv were severely affected and only 29% and 45% of lake area respectively and 21% of initial volume remained. Both lakes were described as oligotrophic lakes before severe human impact and held characteristic macrophytes such as Isoëtes lacustris L., Sparganium angustifolium Michx and Lobelia dortmanna L. As the water level declined the lakes lost their rare characteristic species and can now be described more as a meso- or even eutrophic lakes. When the volume of groundwater abstraction decreased in the 1990s the water levels started to recover but did not reach the natural levels of pre-industrialized era. Also the vegetation did not show any signs of recovery. In 2012 the pumping rates increased again causing a new rapid decline in water levels which almost exceed the previous minimum levels. The water-level monitoring alongside with the macrophyte monitoring data gives us a good case study on how the long term abrupt water-level changes can affect the aquatic vegetation

  19. How and Why Does Stream Water Temperature Vary at Small Spatial Scales in a Headwater Stream?

    Science.gov (United States)

    Morgan, J. C.; Gannon, J. P.; Kelleher, C.

    2017-12-01

    The temperature of stream water is controlled by climatic variables, runoff/baseflow generation, and hyporheic exchange. Hydrologic conditions such as gaining/losing reaches and sources of inflow can vary dramatically along a stream on a small spatial scale. In this work, we attempt to discern the extent that the factors of air temperature, groundwater inflow, and precipitation influence stream temperature at small spatial scales along the length of a stream. To address this question, we measured stream temperature along the perennial stream network in a 43 ha catchment with a complex land use history in Cullowhee, NC. Two water temperature sensors were placed along the stream network on opposite sides of the stream at 100-meter intervals and at several locations of interest (i.e. stream junctions). The forty total sensors recorded the temperature every 10 minutes for one month in the spring and one month in the summer. A subset of sampling locations where stream temperature was consistent or varied from one side of the stream to the other were explored with a thermal imaging camera to obtain a more detailed representation of the spatial variation in temperature at those sites. These thermal surveys were compared with descriptions of the contributing area at the sample sites in an effort to discern specific causes of differing flow paths. Preliminary results suggest that on some branches of the stream stormflow has less influence than regular hyporheic exchange, while other tributaries can change dramatically with stormflow conditions. We anticipate this work will lead to a better understanding of temperature patterns in stream water networks. A better understanding of the importance of small-scale differences in flow paths to water temperature may be able to inform watershed management decisions in the future.

  20. Effects of repeated light-dark phase shifts on voluntary ethanol and water intake in male and female Fischer and Lewis rats.

    Science.gov (United States)

    Rosenwasser, Alan M; Clark, James W; Fixaris, Michael C; Belanger, Gabriel V; Foster, James A

    2010-05-01

    Several lines of evidence implicate reciprocal interactions between excessive alcohol (ethanol) intake and dysregulation of circadian biological rhythms. Thus, chronic alcohol intake leads to widespread circadian disruption in both humans and experimental animals, while in turn, chronobiological disruption has been hypothesized to promote or sustain excessive alcohol intake. Nevertheless, the effects of circadian disruption on voluntary ethanol intake have not been investigated extensively, and prior studies have reported both increased and decreased ethanol intake in rats maintained under "shift-lag" lighting regimens mimicking those experienced by shift workers and transmeridian travelers. In the present study, male and female inbred Fischer and Lewis rats were housed in running wheel cages with continuous free-choice access to both water and 10% (vol/vol) ethanol solution and exposed to repeated 6-h phase advances of the daily light-dark (LD) cycle, whereas controls were kept under standard LD 12:12 conditions. Shift-lag lighting reduced overall ethanol and water intake, and reduced ethanol preference in Fischer rats. Although contrary to the hypothesis that circadian disruption would increase voluntary ethanol intake, these results are consistent with our previous report of reduced ethanol intake in selectively bred high-alcohol-drinking (HAD1) rats housed under a similar lighting regimen. We conclude that chronic circadian disruption is a form of chronobiological stressor that, like other stressors, can either increase or decrease ethanol intake, depending on a variety of poorly understood variables. 2010 Elsevier Inc. All rights reserved.

  1. Development of a small-sized generator of ozonated water using an electro-conductive diamond electrode.

    Science.gov (United States)

    Sekido, Kota; Kitaori, Noriyuki

    2008-12-01

    A small-sized generator of ozonated water was developed using an electro-conductive diamond. We studied the optimum conditions for producing ozonated water. As a result, we developed a small-sized generator of ozonated water driven by a dry-cell for use in the average household. This generator was easily able to produce ozonated water with an ozone concentration (over 4 mg/L) sufficient for disinfection. In addition, we verified the high disinfecting performance of the water produced in an actual hospital.

  2. 40 CFR 141.81 - Applicability of corrosion control treatment steps to small, medium-size and large water systems.

    Science.gov (United States)

    2010-07-01

    ... treatment steps to small, medium-size and large water systems. 141.81 Section 141.81 Protection of... WATER REGULATIONS Control of Lead and Copper § 141.81 Applicability of corrosion control treatment steps...). (ii) A report explaining the test methods used by the water system to evaluate the corrosion control...

  3. The contribution of free water transport and small pore transport to the total fluid removal in peritoneal dialysis

    NARCIS (Netherlands)

    Parikova, Alena; Smit, Watske; Struijk, Dirk G.; Zweers, Machteld M.; Krediet, Raymond T.

    2005-01-01

    BACKGROUND: Water transport in peritoneal dialysis (PD) patients is across the small pores and water channels, the latter allowing free water transport. The objective of the study was to investigate the contribution of each transport route on transcapillary ultrafiltration (TCUF). METHODS: Standard

  4. Shift from National Reporting to Reporting in Accordance with International Financial Reporting Standard for Small and Medium-sized Entities and Its Effect on Financial Management – the Case of the Czech Republic

    Directory of Open Access Journals (Sweden)

    Struhařová Kateřina

    2010-12-01

    Full Text Available The aim of this paper is to evaluate the effect of the shift from Financial Reporting under the Czech legislature (CZ GAAP to the International Financial Reporting Standard for financial management in Small and Medium-sized Enterprises (IFRS for SMEs. The reasons for the shift and major differences between CZ GAAP and IFRS for SMEs are mentioned, as well as the changes relevant to the shift. Not only changes in accounting departments are defined but also the changes that affect a company as a whole. Furthermore, information from Financial Reporting used in Financial Management is described. Also, the effect of the changes in Financial Reporting on this information and related modifications affecting Financial Management are evaluated.

  5. Discrete simulations of spatio-temporal dynamics of small water bodies under varied stream flow discharges

    Science.gov (United States)

    Daya Sagar, B. S.

    2005-01-01

    Spatio-temporal patterns of small water bodies (SWBs) under the influence of temporally varied stream flow discharge are simulated in discrete space by employing geomorphologically realistic expansion and contraction transformations. Cascades of expansion-contraction are systematically performed by synchronizing them with stream flow discharge simulated via the logistic map. Templates with definite characteristic information are defined from stream flow discharge pattern as the basis to model the spatio-temporal organization of randomly situated surface water bodies of various sizes and shapes. These spatio-temporal patterns under varied parameters (λs) controlling stream flow discharge patterns are characterized by estimating their fractal dimensions. At various λs, nonlinear control parameters, we show the union of boundaries of water bodies that traverse the water body and non-water body spaces as geomorphic attractors. The computed fractal dimensions of these attractors are 1.58, 1.53, 1.78, 1.76, 1.84, and 1.90, respectively, at λs of 1, 2, 3, 3.46, 3.57, and 3.99. These values are in line with general visual observations.

  6. Discrete simulations of spatio-temporal dynamics of small water bodies under varied stream flow discharges

    Directory of Open Access Journals (Sweden)

    B. S. Daya Sagar

    2005-01-01

    Full Text Available Spatio-temporal patterns of small water bodies (SWBs under the influence of temporally varied stream flow discharge are simulated in discrete space by employing geomorphologically realistic expansion and contraction transformations. Cascades of expansion-contraction are systematically performed by synchronizing them with stream flow discharge simulated via the logistic map. Templates with definite characteristic information are defined from stream flow discharge pattern as the basis to model the spatio-temporal organization of randomly situated surface water bodies of various sizes and shapes. These spatio-temporal patterns under varied parameters (λs controlling stream flow discharge patterns are characterized by estimating their fractal dimensions. At various λs, nonlinear control parameters, we show the union of boundaries of water bodies that traverse the water body and non-water body spaces as geomorphic attractors. The computed fractal dimensions of these attractors are 1.58, 1.53, 1.78, 1.76, 1.84, and 1.90, respectively, at λs of 1, 2, 3, 3.46, 3.57, and 3.99. These values are in line with general visual observations.

  7. Review of the desalinated water market in France for small units

    International Nuclear Information System (INIS)

    Dutheil, F.; Malissen, M.

    1969-01-01

    On the initiative of and in close collaboration with the Commissariat a l'Energie Atomique, the Societe pour la Conversion et le Developpement Industriel (SODIC) has carried out a very general study of the coastal regions of France in which the short, medium and long-term prospects of the demand for water, and the cost of the necessary supplies, could possibly make desalination units of 3 000 to 10 000 m3/day competitive. So far this general enquiry, which went into detail on some particular aspects, has not revealed any very clear possibilities in this respect, except in the case of the small islands, and of units of much lower capacity, as well as that of large units on the coast, which would benefit from the size effect. However the probable difference between the cost of desalinated water and the high selling price already applying in a small number of coastal regions is relatively small. It might therefore be worthwhile and relatively inexpensive to install an experimental desalination unit in the near future. (author) [fr

  8. Small-scale variability in peatland pore-water biogeochemistry, Hudson Bay Lowland, Canada.

    Science.gov (United States)

    Ulanowski, T A; Branfireun, B A

    2013-06-01

    The Hudson Bay Lowland (HBL) of northern Ontario, Manitoba and Quebec, Canada is the second largest contiguous peatland complex in the world, currently containing more than half of Canada's soil carbon. Recent concerns about the ecohydrological impacts to these large northern peatlands resulting from climate change and resource extraction have catalyzed a resurgence in scientific research into this ecologically important region. However, the sheer size, heterogeneity and elaborate landscape arrangements of this ecosystem raise important questions concerning representative sampling of environmental media for chemical or physical characterization. To begin to quantify such variability, this study assessed the small-scale spatial (1m) and short temporal (21 day) variability of surface pore-water biogeochemistry (pH, dissolved organic carbon, and major ions) in a Sphagnum spp.-dominated, ombrotrophic raised bog, and a Carex spp.-dominated intermediate fen in the HBL. In general, pore-water pH and concentrations of dissolved solutes were similar to previously reported literature values from this region. However, systematic sampling revealed consistent statistically significant differences in pore-water chemistries between the bog and fen peatland types, and large within-site spatiotemporal variability. We found that microtopography in the bog was associated with consistent differences in most biogeochemical variables. Temporal changes in dissolved solute chemistry, particularly base cations (Na(+), Ca(2+) and Mg(2+)), were statistically significant in the intermediate fen, likely a result of a dynamic connection between surficial waters and mineral-rich deep groundwater. In both the bog and fen, concentrations of SO4(2-) showed considerable spatial variability, and a significant decrease in concentrations over the study period. The observed variability in peatland pore-water biogeochemistry over such small spatial and temporal scales suggests that under-sampling in

  9. PCBs in Rain Water, Streams and a Reservoir in a Small Catchment of NW Spain

    Science.gov (United States)

    Delgado-Martín, Jordi; Cereijo-Arango, José Luis; García-Morrondo, David; Juncosa-Rivera, Ricardo; Cillero-Castro, Carmen; Muñoz-Ibáñez, Andrea

    2016-04-01

    Polychlorinated biphenyls (PCBs) constitute a significant environmental concern due to its persistence, tendency to bio-accumulate, acknowledged toxicity and ubiquity. In the present study, a small water catchment (~100 km2) inclusive of a two-tailed water supply reservoir (Abegondo-Cecebre) has been monitored between 2009 and 2014. Sampling stations include: a) one precipitation gauge used to collect monthly-integrated bulk precipitation (25 samples); b) seven streams (95 samples); c) five surface and one bottom points within the reservoir (104 samples); d) five points for sediment sampling in two surveys (spring and summer; 10 samples). All the water samples as well as the leachates of sediment washing have been analyzed for their concentration in 6 marker PCB (congeners 28, 52, 101, 138, 153 and 180) and 12 dioxin-like PCB (congeners 77, 81, 105, 114, 118, 123, 126, 156, 157, 167, 169 and 189) compounds. The average concentration of PCBtot in the bulk precipitation during the sampling period is ~406 pg/L although a very significant decrease has occurred since the end of 2011 (~800 pg/L) to the end of 2014 (~60 pg/L). Likewise, the mean concentration of PCBtot in the stream water samples is 174 pg/L and a similar reduction in the concentration of PCBtot is also acknowledged for the same period of time (~250 pg/L before the end of 2011 and ~30 pg/L after then). Reservoir surface water has a PCBtot concentration of ~234 pg/L which, according to its sampling time (2010-2011) is consistent with the measured stream waters. However, deep reservoir water reveals an average concentration which is higher than the corresponding top water (~330 pg/L) but significantly smaller than the water-leached sediments (~860 pg/L). The available data suggest that up to a 30% of PCBs associated with precipitation becomes sequestered by the soil/sediment system while no significant change takes place during the transfer of water from the stream to the reservoir system, at least in

  10. Design optimization of a vaneless ``fish-friendly'' swirl injector for small water turbines

    Science.gov (United States)

    Airody, Ajith; Peterson, Sean D.

    2015-11-01

    Small-scale hydro-electric plants are attractive options for powering remote sites, as they draw energy from local bodies of water. However, the environmental impact on the aquatic life drawn into the water turbine is a concern. To mitigate adverse consequences on the local fauna, small-scale water turbine design efforts have focused on developing ``fish-friendly'' facilities. The components of these turbines tend to have wider passages between the blades when compared to traditional turbines, and the rotors are designed to spin at much lower angular velocities, thus allowing fish to pass through safely. Galt Green Energy has proposed a vaneless casing that provides the swirl component to the flow approaching the rotor, eliminating the need for inlet guide vanes. We numerically model the flow through the casing using ANSYS CFX to assess the evolution of the axial and circumferential velocity symmetry and uniformity in various cross-sections within and downstream of the injector. The velocity distributions, as well as the pressure loss through the injector, are functions of the pitch angle and number of revolutions of the casing. Optimization of the casing design is discussed via an objective function consisting of the velocity and pressure performance measures.

  11. Seasonal Shifts in Primary Water Source Type: A Comparison of Largely Pastoral Communities in Uganda and Tanzania

    Directory of Open Access Journals (Sweden)

    Amber L. Pearson

    2016-01-01

    Full Text Available Many water-related illnesses show an increase during the wet season. This is often due to fecal contamination from runoff, yet, it is unknown whether seasonal changes in water availability may also play a role in increased illness via changes in the type of primary water source used by households. Very little is known about the dynamic aspects of access to water and changes in source type across seasons, particularly in semi-arid regions with annual water scarcity. The research questions in this study were: (1 To what degree do households in Uganda (UG and Tanzania (TZ change primary water source type between wet and dry seasons?; and (2 How might seasonal changes relate to water quality and health? Using spatial survey data from 92 households each in UG and TZ this study found that, from wet to dry season, 26% (UG and 9% (TZ of households switched from a source with higher risk of contamination to a source with lower risk. By comparison, only 20% (UG and 0% (TZ of households switched from a source with lower risk of contamination to a source with higher risk of contamination. This research suggests that one pathway through which water-related disease prevalence may differ across seasons is the use of water sources with higher risk contamination, and that households with access to sources with lower risks of contamination sometimes choose to use more contaminated sources.

  12. Optimal water allocation in small hydropower plants between traditional and non-traditional water users: merging theory and existing practices.

    Science.gov (United States)

    Gorla, Lorenzo; Crouzy, Benoît; Perona, Paolo

    2014-05-01

    Water demand for hydropower production is increasing together with the consciousness of the importance of riparian ecosystems and biodiversity. Some Cantons in Switzerland and other alpine regions in Austria and in Süd Tiröl (Italy) started replacing the inadequate concept of Minimum Flow Requirement (MFR) with a dynamic one, by releasing a fix percentage of the total inflow (e.g. 25 %) to the environment. Starting from a model proposed by Perona et al. (2013) and the need of including the environment as an actual water user, we arrived to similar qualitative results, and better quantitative performances. In this paper we explore the space of non-proportional water repartition rules analysed by Gorla and Perona (2013), and we propose new ecological indicators which are directly derived from current ecologic evaluation practices (fish habitat modelling and hydrological alteration). We demonstrate that both MFR water redistribution policy and also proportional repartition rules can be improved using nothing but available information. Furthermore, all water redistribution policies can be described by the model proposed by Perona et al. (2013) in terms of the Principle of Equal Marginal Utility (PEMU) and a suitable class of nonlinear functions. This is particularly useful to highlights implicit assumptions and choosing best-compromise solutions, providing analytical reasons explaining why efficiency cannot be attained by classic repartition rules. Each water repartition policy underlies an ecosystem monetization and a political choice always has to be taken. We explicit the value of the ecosystem health underlying each policy by means of the PEMU under a few assumptions, and discuss how the theoretic efficient redistribution law obtained by our approach is feasible and doesn't imply high costs or advanced management tools. For small run-of-river power plants, this methodology answers the question "how much water should be left to the river?" and is therefore a

  13. Analysis of the Sodium Recirculation Theory of Solute Coupled Water Transport in Small Intestine

    DEFF Research Database (Denmark)

    Larsen, E. H.; Sørensen, Jens Nørkær; Sørensen, J. B.

    2002-01-01

    Our previous mathematical model of solute-coupled water transport through the intestinal epithelium is extended for dealing with electrolytes rather than electroneutral solutes. A 3Na+-2K+ pump in the lateral membranes provides the energy-requiring step for driving transjunctional and translateral......, computations predict that the concentration differences between lis and bathing solutions are small for all three ions. Nevertheless, the diffusion fluxes of the ions out of lis significantly exceed their mass transports. It is concluded that isotonic transport requires recirculation of all three ions....... The computed sodium recirculation flux that is required for isotonic transport corresponds to that estimated in experiments on toad small intestine. This result is shown to be robust and independent of whether the apical entrance mechanism for the sodium ion is a channel, a SGLT1 transporter driving inward...

  14. Diagnosis of small capacity reverse osmosis desalination unit for domestic water

    International Nuclear Information System (INIS)

    Hillali, Z.; Hamed, A.; Elfil, Hamza; Ferjani, E.

    2009-01-01

    Tunisian norm of drinking water tolerates a maximum TDS of 1.5 g/L, and the domestic water presents usually a salinity grater than 500 mg/L. In the last years, several small capacity reverse osmosis desalination prototypes have been marketed. They are used to desalinate brackish water with TDS lower than 1.5 g/L. This RO unit, tested with tap waters during four years, was diagnosed. The RO unit produces 10-15 L/Hour with a recovery rate between 25 and 40 pour cent and salt rejection in order of 90 pour cent. The salinity of the tested domestic water is located between 0.4 and 1.4 g/L. Water pretreatment is composed of three filtration operations (cartridge filter, granulate active carbon filter and 5 =m cartridge filter). Pretreated water is pumped through RO membrane with maximum pressure of 6 bars. At the 4th year, the RO unit performances were substantial decreased. Recovery rate and salt rejection fall down more than 50 and 100% respectively and the pressure drop increase from 1 to 2.1 bar The membrane regeneration allowed only the rate recovery restoration. The membrane selectivity was not improved. The membrane seems irreversibly damaged by the tap water chlorine none retained by the deficient pretreatment. An autopsy of the used RO membrane was done by different analysis techniques as SEM/EDX, AFM, XRD and FTIR spectroscopy. The analysis of membrane (proper and used) surfaces show a deposit film on the used membrane witch evaluated to environ 2 =m, it indicates a fooling phenomenon. The SEM photos show deterioration on the active layer material of the membrane witch seems attacked by the tap water chlorine. The X Rays Diffraction and FTIR show that the deposit collected on the used membrane contains organic and mineral (Gypsum, SiO 2 and clays) materials. Silicates and clays can exist in tap waters and reach the RO membrane when the pretreatment micro-filter became deficient. The Gypsum presence is due only to germination on the membrane.

  15. Small photon beam measurements using radiochromic film and Monte Carlo simulations in a water phantom

    International Nuclear Information System (INIS)

    Garcia-Garduno, Olivia A.; Larraga-Gutierrez, Jose M.; Rodriguez-Villafuerte, Mercedes; Martinez-Davalos, Arnulfo; Celis, Miguel A.

    2010-01-01

    This work reports the use of both GafChromic EBT film immersed in a water phantom and Monte Carlo (MC) simulations for small photon beam stereotactic radiosurgery dosimetry. Circularly collimated photon beams with diameters in the 4-20 mm range of a dedicated 6 MV linear accelerator (Novalis (registered) , BrainLAB, Germany) were used to perform off-axis ratios, tissue maximum ratios and total scatter factors measurements, and MC simulations. GafChromic EBT film data show an excellent agreement with MC results (<2.7%) for all measured quantities.

  16. Analysis of a small break loss-of-coolant accident of pressurized water reactor by APROS

    Energy Technology Data Exchange (ETDEWEB)

    Al-Falahi, A. [Helsinki Univ. of Technology, Espoo (Finland); Haennine, M. [VTT Energy, Espoo (Finland); Porkholm, K. [IVO International, Ltd., Vantaa (Finland)

    1995-09-01

    The purpose of this paper is to study the capability of APROS (Advanced PROcess Simulator) code to simulate the real plant thermal-hydraulic transient of a Small Break Loss-Of-Coolant Accident (SBLOCA) of Loss-Of-Fluid Test (LOFT) facility. The LOFT is a scaled model of a Pressurized Water Reactor (PWR). This work is a part of a larger validation of the APROS thermal-hydraulic models. The results of SBLOCA transient calculated by APROS showed a reasonable agreement with the measured data.

  17. Water and oxygen induced degradation of small molecule organic solar cells

    DEFF Research Database (Denmark)

    Hermenau, Martin; Riede, Moritz; Leo, Karl

    2011-01-01

    Small molecule organic solar cells were studied with respect to water and oxygen induced degradation by mapping the spatial distribution of reaction products in order to elucidate the degradation patterns and failure mechanisms. The active layers consist of a 30 nm bulk heterojunction formed......,4′-diamine p-doped with C60F36 (MeO-TPD:C60F36), which acted as hole transporting layer. Indium-tin-oxide (ITO) and aluminum served as hole and electron collecting electrode, respectively. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) and X-ray photoelectron spectroscopy (XPS) in conjunction...... of aluminum oxide at the BPhen/Al interface, and diffusion of water into the ZnPc:C60 layer where ZnPc becomes oxidized. Finally, diffusion from the electrodes was found to have no or a negligible effect on the device lifetime....

  18. Leak Detection in Water-Filled Small-Diameter Polyethylene Pipes by Means of Acoustic Emission Measurements

    OpenAIRE

    Alberto Martini; Marco Troncossi; Alessandro Rivola

    2016-01-01

    The implementation of effective strategies to manage leaks represents an essential goal for all utilities involved with drinking water supply in order to reduce water losses affecting urban distribution networks. This study concerns the early detection of leaks occurring in small-diameter customers’ connections to water supply networks. An experimental campaign was carried out in a test bed to investigate the sensitivity of Acoustic Emission (AE) monitoring to water leaks. Damages were artifi...

  19. Estimates of ground-water recharge rates for two small basins in central Nevada

    International Nuclear Information System (INIS)

    Lichty, R.W.; McKinley, P.W.

    1995-01-01

    Estimates of ground-water recharge rates developed from hydrologic modeling studies are presented for 3-Springs and East Stewart basins, two small basins (analog sites) located in central Nevada. The analog-site studies were conducted to aid in the estimation of recharge to the paleohydrologic regime associated with ground water in the vicinity of Yucca Mountain under wetter climatic conditions. The two analog sites are located to the north and at higher elevations than Yucca Mountain, and the prevailing (current) climatic conditions at these sites is thought to be representative of the possible range of paleoclimatic conditions in the general area of Yucca Mountain during the Quaternary. Two independent modeling approaches were conducted at each of the analog sites using observed hydrologic data on precipitation, temperature, solar radiation, stream discharge, and chloride-ion water chemistry for a 6-year study period (October 1986 through September 1992). Both models quantify the hydrologic water-balance equation and yield estimates of ground-water recharge, given appropriate input data. Results of the modeling approaches support the conclusion that reasonable estimates of average-annual recharge to ground water range from about 1 to 3 centimeters per year for 3-Springs basin (the drier site), and from about 30 to 32 centimeters per year for East Stewart basin (the wetter site). The most reliable results are those derived from a reduced form of the chloride-ion model because they reflect integrated, basinwide processes in terms of only three measured variables: precipitation amount, precipitation chemistry, and streamflow chemistry

  20. Improving the ecohydrological and economic efficiency of Small Hydropower Plants with water diversion

    Science.gov (United States)

    Razurel, Pierre; Gorla, Lorenzo; Tron, Stefania; Niayifar, Amin; Crouzy, Benoît; Perona, Paolo

    2018-03-01

    Water exploitation for energy production from Small Hydropower Plant (SHP) is increasing despite human pressure on freshwater already being very intense in several countries. Preserving natural rivers thus requires deeper understanding of the global (i.e., ecological and economic) efficiency of flow-diversion practice. In this work, we show that the global efficiency of SHP river intakes can be improved by non-proportional flow-redistribution policies. This innovative dynamic water allocation defines the fraction of water released to the river as a nonlinear function of river runoff. Three swiss SHP case studies are considered to systematically test the global performance of such policies, under both present and future hydroclimatic regimes. The environmental efficiency is plotted versus the economic efficiency showing that efficient solutions align along a (Pareto) frontier, which is entirely formed by non-proportional policies. On the contrary, other commonly used distribution policies generally lie below the Pareto frontier. This confirms the existence of better policies based on non-proportional redistribution, which should be considered in relation to implementation and operational costs. Our results recommend abandoning static (e.g., constant-minimal-flow) policies in favour of non-proportional dynamic ones towards a more sustainable use of the water resource, also considering changing hydroclimatic scenarios.

  1. Gas and water permeability of concrete for reactor buildings small specimens

    International Nuclear Information System (INIS)

    Mills, R.H.

    1986-03-01

    The effect on permeability of artifical aging by drying shrinkage and by freeze-thaw was determined by observing mass transfer of gas and water under a pressure gradient. It was found that damage due to freeze-thaw was negligible but that cracking around aggregate caused by drying shrinkage resulted in significantly increased permeability to both gas and water. The absence of freeze-thaw damage was attributed to self-dessication. Since the concrete was not exposed to an external source of water, the chemical reaction was sustained by consumption of mixing water. The resulting air voids were, apparently, sufficient to absorb expansive pressures due to ice formation. The response to lateral prestress was different for cracked and uncracked concrete. Although, in all cases, increased prestress resulted in reduced leakage, the effect was stronger in cracked concrete. Mean pore diameter as determined by gas diffusion was not, however, substantially affected because the leakage in cracked concrete remained very low. Reinforcing steel did not have a great influence on permeability of small specimens. Gas transmission through concrete was strongly influenced by moisture content. Free moisture constituted a barrier to gas flow, acting as a virtual solid. This is important since aging of concrete results in reduced free moisture. Ultrasonic pulse velocity appeared to vary with moisture content and porosity of concrete in the same way as gas permeability and gave promise of being effective for in-situ monitoring of concrete in reactor buildings

  2. Removal of inorganic As5+ from a small drinking water system

    Directory of Open Access Journals (Sweden)

    MARJANA SIMONIC

    2009-01-01

    Full Text Available The drinking water from a small drinking water system contained arsenic in a concentration of about 50 μg/L. Chemical analyses showed that the pentavalent form of arsenic was present. Since the MCL value is 10 μg/L, it was necessary to implement a technological treatment to make the water suitable for drinking. In order to do so, two technologies were suggested: activated alumina and a-FeOOH (TehnoArz, TA adsorption media. Experiments using both adsorption media were performed on a laboratory scale. It was possible to remove arsenic to below 1 μg/L. The maximal adsorption capacity was found to be 12.7 mg of As5+ per gram of a-FeOOH. Moreover, all the important physico–chemical parameters of the water remained practically unchanged after the treatment. Only a slight release of iron from the media was observed. The Fe–As bond was studied by means of chemical analysis and X-ray powder diffraction. Finally, in addition to showing the capability of arsenic removal by a-FeOOH, a comprehensive optimization of the technological parameters of the selected technology is provided.

  3. Small leak detection by measuring surface oscillation during sodium-water reaction in steam generator

    International Nuclear Information System (INIS)

    Nei, Hiromichi; Hori, Masao

    1977-01-01

    Small leak sodium-water reaction tests were conducted to develop various kinds of leak detectors for the sodium-heated steam generator in FBR. The super-heated steam was injected into sodium in a reaction vessel having a sodium free surface, simulating the steam generator. The level gauge in the reaction vessel generated the most reliable signal among detectors, as long as the leak rates were relatively high. The level gauge signal was estimated to be the sodium surface oscillation caused by hydrogen bubbles produced in sodium-water reaction. Experimental correlation was derived, predicting the amplitude as a function of leak rate, hydrogen dissolution ratio, bubble rise velocity and other parameters concerned, assuming that the surface oscillation is in proportion to the gas hold-up. The noise amplitude under normal operation without water leak was increased with sodium flow rate and found to be well correlated with Froud number. These two correlations predict that a water leak in a ''MONJU'' class (300 MWe) steam generator could possibly be detected by level gauges at a leak rate above 2 g/sec. (auth.)

  4. The energies of formation and mobilities of Cu surface species on Cu and ZnO in methanol and water gas shift atmospheres studied by DFT

    DEFF Research Database (Denmark)

    Rasmussen, Dominik Bjørn; Janssens, Ton V.W.; Temel, Burcin

    2012-01-01

    Catalysts based on copper, such as the Cu/ZnO/Al2O3 system are widely used for industrial scale methanol synthesis and the low temperature water gas shift reaction. A common characteristic of these catalysts is that they deactivate quite rapidly during operation and therefore understanding...... their deactivation by sintering is highly relevant. In this work, we study the nature of the species that are responsible for transport of the Cu metal in this catalyst type using density functional theory calculations within a chemical potential formalism. The stability and mobility of Cu–X (Cu, OH, CO, CH3O, HCOO...

  5. SMALL ROV MARINE BOAT FOR BATHYMETRY SURVEYS OF SHALLOW WATERS – POTENTIAL IMPLEMENTATION IN MALAYSIA

    Directory of Open Access Journals (Sweden)

    K. T. Suhari

    2017-10-01

    Full Text Available Current practices in bathymetry survey (available method are indeed having some limitations. New technologies for bathymetry survey such as using unmanned boat has becoming popular in developed countries - filled in and served those limitations of existing survey methods. Malaysia as one of tropical country has it own river/water body characteristics and suitable approaches in conducting bathymetry survey. Thus, a study on this emerging technology should be conducted using enhanced version of small ROV boat with Malaysian rivers and best approaches so that the surveyors get benefits from the innovative surveying product. Among the available ROV boat for bathymetry surveying in the market, an Indonesian product called SHUMOO is among the promising products – economically and practically proven using a few sample areas in Indonesia. The boat was equipped and integrated with systems of remote sensing technology, GNSS, echo sounder and navigational engine. It was designed for riverbed surveys on shallow area such as small /medium river, lakes, reservoirs, oxidation/detention pond and other water bodies. This paper tries to highlight the needs and enhancement offered to Malaysian’ bathymetry surveyors/practitioners on the new ROV boat which make their task easier, faster, safer, economically effective and better riverbed modelling results. The discussion continues with a sample of Indonesia river (data collection and modelling since it is mostly similar to Malaysia’s river characteristics and suggests some improvement for Malaysia best practice.

  6. Small Rov Marine Boat for Bathymetry Surveys of Shallow Waters - Potential Implementation in Malaysia

    Science.gov (United States)

    Suhari, K. T.; Karim, H.; Gunawan, P. H.; Purwanto, H.

    2017-10-01

    Current practices in bathymetry survey (available method) are indeed having some limitations. New technologies for bathymetry survey such as using unmanned boat has becoming popular in developed countries - filled in and served those limitations of existing survey methods. Malaysia as one of tropical country has it own river/water body characteristics and suitable approaches in conducting bathymetry survey. Thus, a study on this emerging technology should be conducted using enhanced version of small ROV boat with Malaysian rivers and best approaches so that the surveyors get benefits from the innovative surveying product. Among the available ROV boat for bathymetry surveying in the market, an Indonesian product called SHUMOO is among the promising products - economically and practically proven using a few sample areas in Indonesia. The boat was equipped and integrated with systems of remote sensing technology, GNSS, echo sounder and navigational engine. It was designed for riverbed surveys on shallow area such as small /medium river, lakes, reservoirs, oxidation/detention pond and other water bodies. This paper tries to highlight the needs and enhancement offered to Malaysian' bathymetry surveyors/practitioners on the new ROV boat which make their task easier, faster, safer, economically effective and better riverbed modelling results. The discussion continues with a sample of Indonesia river (data collection and modelling) since it is mostly similar to Malaysia's river characteristics and suggests some improvement for Malaysia best practice.

  7. Testing of the multi-application small light water reactor (MASLWR) passive safety systems

    International Nuclear Information System (INIS)

    Reyes, Jose N.; Groome, John; Woods, Brian G.; Young, Eric; Abel, Kent; Yao, You; Yoo, Yeon Jong

    2007-01-01

    Experimental thermal hydraulic research has been conducted at Oregon State University for the purpose of assessing the performance of a new reactor design concept, the multi-application small light water reactor (MASLWR). The MASLWR is a pressurized light water reactor design with a net output of 35 MWe that uses natural circulation in both normal and transient operation. Due to its small size, portability and modularity, the MASLWR design is well suited to help fill the potential need for grid appropriate reactor designs for smaller electricity grids as may be found in developing or remote regions. The purpose of the OSU MASLWR test facility is to assess the operation of the MASLWR under normal full operating pressure and full temperature conditions and to assess the passive safety systems under transient conditions. The data generated by the testing program will be used to assess computer code calculations and to provide a better understanding of the thermal-hydraulic phenomena in the design of the MASLWR NSSS. During this testing program, four tests were conducted at the OSU MASLWR test facility. These tests included one design basis accident and one beyond design basis accident. During the performance of these tests, plant operations to include start up, normal operation and shut down evolutions were demonstrated successfully

  8. Life Cycle Environmental Impacts of Disinfection Technologies Used in Small Drinking Water Systems.

    Science.gov (United States)

    Jones, Christopher H; Shilling, Elizabeth G; Linden, Karl G; Cook, Sherri M

    2018-03-06

    Small drinking water systems serve a fifth of the U.S. population and rely heavily on disinfection. While chlorine disinfection is common, there is interest in minimizing chemical addition, especially due to carcinogenic disinfection byproducts and chlorine-resistant pathogens, by using ultraviolet technologies; however, the relative, broader environmental impacts of these technologies are not well established, especially in the context of small (environmental trade-offs between chlorine and ultraviolet disinfection via comparative life cycle assessment. The functional unit was the production of 1 m 3 of drinking water to U.S. Treatment included cartridge filtration followed by either chlorine disinfection or ultraviolet disinfection with chlorine residual addition. Environmental performance was evaluated for various chlorine contact zone materials (plastic, concrete, steel), ultraviolet validation factors (1.2 to 4.4), and electricity sources (renewable; U.S. average, high, and low impact grids). Performance was also evaluated when filtration and chlorine residual were not required. From a life cycle assessment perspective, replacing chlorine with UV was preferred only in a limited number of cases (i.e., high pumping pressure but filtration is not required). In all others, chlorine was environmentally preferred, although some contact zone materials and energy sources had an impact on the comparison. Utilities can use these data to inform their disinfection technology selection and operation to minimize environmental and human health impacts.

  9. Natural products phytotoxicity A bioassay suitable for small quantities of slightly water-soluble compounds.

    Science.gov (United States)

    Dornbos, D L; Spencer, G F

    1990-02-01

    A large variety of secondary metabolites that can inhibit germination and/or seedling growth are produced by plants in low quantities. The objective of this study was to develop a bioassay capable of reliably assessing reductions in germination percentage and seedling length of small-seeded plant species caused by exposure to minute quantities of these compounds. The germination and growth of alfalfa (Medicago saliva), annual ryegrass (Lolium multiflorum), and velvetleaf (Abutilon theophrasti) were evaluated against six known phytotoxins from five chemical classes; cinmethylin (a herbicidal cineole derivative) was selected as a comparison standard. Each phytotoxin, dissolved in a suitable organic solvent, was placed on water-agar in small tissue culture wells. After the solvent evaporated, imbibed seeds were placed on the agar; after three days, germination percentages and seedling lengths were measured. Compared to a commonly used filter paper procedure, this modified agar bioassay required smaller quantities of compound per seed for comparable bioassay results. This bioassay also readily permitted the measurement of seedling length, a more sensitive indicator of phytotoxicity than germination. Seedling length decreased sigmoidally as the toxin concentration increased logarithmically. Phytotoxicity was a function of both compound and plant species. Cinmethylin, a grass herbicide, reduced the length of annual ryegrass seedlings by 90-100%, whereas that of alfalfa and velvetleaf was inhibited slightly. The agar bioassay facilitated the rapid and reliable testing of slightly water-soluble compounds, requiring only minute quantities of each compound to give reproducible results.

  10. Integrated energy and waste water solutions to solve small town municipal service delivery problems in South Africa

    CSIR Research Space (South Africa)

    Du Plessis, C

    2010-02-01

    Full Text Available Providing municipal services such as electricity and waste water treatment is a major challenge for small towns that often lack the institutional capacity to manage and maintain the necessary infrastructure. High levels of poverty in these towns...

  11. Small-Signal Analysis of Single-Phase and Three-phase DC/AC and AC/DC PWM Converters with the Frequency-Shift Technique

    DEFF Research Database (Denmark)

    Blaabjerg, Frede; Aquila, A. Dell’; Liserre, Marco

    2004-01-01

    of dc/dc converters via a 50 Hz frequency-shift. The input admittance is calculated and measured for two study examples (a three-phase active rectifier and a single-phase photovoltaic inverter). These examples show that the purpose of a well designed controller for grid-connected converters......A systematic approach to study dc/ac and ac/dc converters without the use of synchronous transformation is proposed. The use of a frequency-shift technique allows a straightforward analysis of single-phase and three-phase systems. The study of dc/ac and of ac/dc converters is reported to the study...... is to minimize the input admittance in order to make the grid converter more robust to grid disturbance....

  12. Estimates of ground-water recharge rates for two small basins in central Nevada

    Science.gov (United States)

    Lichty, R.W.; McKinley, P.W.

    1995-01-01

    Estimates of ground-water recharge rates developed from hydrologic modeling studies are presented for 3-Springs and East Stewart basins. two small basins (analog sites) located in central Nevada. The analog-site studies were conducted to aid in the estimation of recharge to the paleohydrologic regime associated with ground water in the vicinity of Yucca Mountain under wetter climatic conditions. The two analog sites are located to the north and at higher elevations than Yucca Mountain, and the prevailing (current) climatic conditions at these sites is thought to be representative of the possible range of paleoclimatic conditions in the general area of Yucca Mountain during the Quaternary. Two independent modeling approaches were conducted at each of the analog sites using observed hydrologic data on precipitation, temperature, solar radiation stream discharge, and chloride-ion water chemistry for a 6-year study period (October 1986 through September 1992). Both models quantify the hydrologic water-balance equation and yield estimates of ground-water recharge, given appropriate input data. The first model uses a traditional approach to quantify watershed hydrology through a precipitation-runoff modeling system that accounts for the spatial variability of hydrologic inputs, processes, and responses (outputs) using a dailycomputational time step. The second model is based on the conservative nature of the dissolved chloride ion in selected hydrologic environments, and its use as a natural tracer allows the computation of acoupled, water and chloride-ion, mass-balance system of equations to estimate available water (sum ofsurface runoff and groundwater recharge). Results of the modeling approaches support the conclusion that reasonable estimates of average-annual recharge to ground water range from about 1 to 3 centimeters per year for 3-Springs basin (the drier site), and from about 30 to 32 centimeters per year for East Stewart basin (the wetter site). The most

  13. Water quality and small-scale land use mapping in the South-Chinese megacity Guangzhou

    Science.gov (United States)

    Strohschoen, R.; Azzam, R.; Baier, K.

    2011-12-01

    Since China adopted its "open-door" policy in 1978/ 79, the Pearl River Delta became one of the most rapid and dynamic urbanizing areas in East Asia due to migration, industrialization and globalization processes. The study area Guangzhou grew from a small town to a megacity with some 15 million inhabitants within less than 30 years. The rapid population growth and the urban and industrial expansion led to a remarkably increasing demand for freshwater, a high water consume and a rising sewage production. While economy and house constructions developed very fast, the expansion of water infrastructures could not keep pace with the urban growth. The consequences arising out of these situations are a serious deterioration of the surface and groundwater resources but also a degradation of living conditions and a threat to human health, particularly of the urban poor. In contrast to other studies that often consider the surface water quality outside Guangzhou, our focus was put on the urban Pearl River and its tributaries as well as urban groundwater and tap water. The study was conducted to spatially investigate the present status of the water quality in view of the concurrent formal and informal anthropogenic influences. Additional land use mapping was undertaken to analyze the interrelations between different land use types and water quality and to determine local pollution hotspots which should be taken into particular consideration of future city planning. Supplementing interviews were hold to find out usage patterns of groundwater and strategies to cope with both insufficient tap water quality and water infrastructures. A total of 74 surface water samples and 16 groundwater samples of privately and publicly accessible wells were taken at the beginning of the rainy season in May 2010. Those samples were partly compared to measurements carried out from 2007-2009, where adequate. Further, 15 tap water samples were taken in 2007/ 08 to draw conclusions about possible

  14. Public choice in water resource management: two case studies of the small-scale hydroelectric controversy

    Energy Technology Data Exchange (ETDEWEB)

    Soden, D.L.

    1985-01-01

    Hydroelectric issues have a long history in the Pacific Northwest, and more recently have come to focus on developing environmentally less-obtrusive means of hydroelectric generation. Small-scale hydroelectric represents perhaps the most important of these means of developing new sources of renewable resources to lessen the nation's dependence on foreign sources of energy. Each potential small-scale hydroelectric project, however, manifests a unique history which provides a highly useful opportunity to study the process of collective social choice in the area of new energy uses of water resources. Utilizing the basic concepts of public choice theory, a highly developed and increasingly widely accepted approach in the social sciences, the politicalization of small-scale hydroelectric proposals is analyzed. Through the use of secondary analysis of archival public opinion data collected from residents of the State of Idaho, and through the development of the two case studies - one on the Palouse River in Eastern Washington and the other at Elk Creek Falls in Northern Idaho, the policy relevant behavior and influence of major actors is assessed. Results provide a useful test of the utility of public-choice theory for the study of cases of natural-resources development when public involvement is high.

  15. Performance of a Small-scale Treatment Wetland for Treatment of Landscaping Wash Water

    Science.gov (United States)

    Thompson, R. J.; Fayed, E.; Fish, W.

    2011-12-01

    A large number of lawn mowers and related equipment must be cleaned each day by commercial landscaping operations and state and local highway maintenance crews. Washing these devices produces wastewater that contains high amounts of organic matter and potentially problematic nutrients, as well as oil and grease and other chemicals and metals that come from the machinery itself. Dirty water washes off the mowers, flows off the pavement and into nearby storm drains without any kind of treatment. A better idea would be to collect such wastewater, retain it in an appropriate catchment such as an engineered wetland where natural processes could break down any pollutants in the wash water, and allow the water to naturally evaporate or percolate into the soil where it could recharge ground water resources safely. This research examines the performance of a small-scale treatment wetland tailored to remove nitrogen from landscaping wash water by incorporating both aerobic and anaerobic phases. Contaminants are analyzed through physical and chemical methods. Both methods involve collection of samples, followed by standardized, validated analytical laboratory tests for measuring total solids, total kjeldahl nitrogen, nitrates, total and dissolved phosphorus, COD, BOD, oil and grease, and metals (Zn and Cu). High levels of total solids, total kjeldahl nitrogen, nitrates, total and dissolved phosphorus, COD, BOD, oil and grease are found. Zinc and copper levels are low. Wetland treatment removes 99% total solids, 77% total kjeldahl nitrogen, 100% nitrates, 94% total phosphorus, 86% dissolved phosphorus, 94% COD, 97% BOD, and 76% oil and grease. The results will be a critical step towards developing a sustainable low-energy system for treating such wastewater that could be used by private landscaping companies and government agencies.

  16. Water Dynamics and Dewetting Transitions in the Small Mechanosensitive Channel MscS

    Science.gov (United States)

    Anishkin, Andriy; Sukharev, Sergei

    2004-01-01

    The dynamics of confined water in capillaries and nanotubes suggests that gating of ion channels may involve not only changes of the pore geometry, but also transitions between water-filled and empty states in certain locations. The recently solved heptameric structure of the small mechanosensitive channel of Escherichia coli, MscS, has revealed a relatively wide (7–15 Å) yet highly hydrophobic transmembrane pore. Continuum estimations based on the properties of pore surface suggest low conductance and a thermodynamic possibility of dewetting. To test the predictions we performed molecular dynamics simulations of MscS filled with flexible TIP3P water. Irrespective to the initial conditions, several independent 6-ns simulations converged to the same stable state with the pore water-filled in the wider part, but predominantly empty in the narrow hydrophobic part, displaying intermittent vapor-liquid transitions. The polar gain-of-function substitution L109S in the constriction resulted in a stable hydration of the entire pore. Steered passages of Cl− ions through the narrow part of the pore consistently produced partial ion dehydration and required a force of 200–400 pN to overcome an estimated barrier of 10–20 kcal/mole, implying negligibly low conductance. We conclude that the crystal structure of MscS does not represent an open state. We infer that MscS gate, which is similar to that of the nicotinic ACh receptor, involves a vapor-lock mechanism where limited changes of geometry or surface polarity can locally switch the regime between water-filled (conducting) and empty (nonconducting) states. PMID:15111405

  17. Ranking of small scale proposals for water system repair using the Rapid Impact Assessment Matrix (RIAM)

    Energy Technology Data Exchange (ETDEWEB)

    Shakib-Manesh, T.E.; Hirvonen, K.O.; Jalava, K.J.; Ålander, T.; Kuitunen, M.T., E-mail: markku.kuitunen@jyu.fi

    2014-11-15

    Environmental impacts of small scale projects are often assessed poorly, or not assessed at all. This paper examines the usability of the Rapid Impact Assessment Matrix (RIAM) as a tool to prioritize project proposals for small scale water restoration projects in relation to proposals' potential to improve the environment. The RIAM scoring system was used to assess and rank the proposals based on their environmental impacts, the costs of the projects to repair the harmful impacts, and the size of human population living around the sites. A four-member assessment group (The expert panel) gave the RIAM-scores to the proposals. The assumed impacts of the studied projects at the Eastern Finland water systems were divided into the ecological and social impacts. The more detailed assessment categories of the ecological impacts in this study were impacts on landscape, natural state, and limnology. The social impact categories were impacts to recreational use of the area, fishing, industry, population, and economy. These impacts were scored according to their geographical and social significance, their magnitude of change, their character, permanence, reversibility, and cumulativeness. The RIAM method proved to be an appropriate and recommendable method for the small-scale assessment and prioritizing of project proposals. If the assessments are well documented, the RIAM can be a method for easy assessing and comparison of the various kinds of projects. In the studied project proposals there were no big surprises in the results: the best ranks were received by the projects, which were assumed to return watersheds toward their original state.

  18. Ranking of small scale proposals for water system repair using the Rapid Impact Assessment Matrix (RIAM)

    International Nuclear Information System (INIS)

    Shakib-Manesh, T.E.; Hirvonen, K.O.; Jalava, K.J.; Ålander, T.; Kuitunen, M.T.

    2014-01-01

    Environmental impacts of small scale projects are often assessed poorly, or not assessed at all. This paper examines the usability of the Rapid Impact Assessment Matrix (RIAM) as a tool to prioritize project proposals for small scale water restoration projects in relation to proposals' potential to improve the environment. The RIAM scoring system was used to assess and rank the proposals based on their environmental impacts, the costs of the projects to repair the harmful impacts, and the size of human population living around the sites. A four-member assessment group (The expert panel) gave the RIAM-scores to the proposals. The assumed impacts of the studied projects at the Eastern Finland water systems were divided into the ecological and social impacts. The more detailed assessment categories of the ecological impacts in this study were impacts on landscape, natural state, and limnology. The social impact categories were impacts to recreational use of the area, fishing, industry, population, and economy. These impacts were scored according to their geographical and social significance, their magnitude of change, their character, permanence, reversibility, and cumulativeness. The RIAM method proved to be an appropriate and recommendable method for the small-scale assessment and prioritizing of project proposals. If the assessments are well documented, the RIAM can be a method for easy assessing and comparison of the various kinds of projects. In the studied project proposals there were no big surprises in the results: the best ranks were received by the projects, which were assumed to return watersheds toward their original state

  19. Nine years of irrigation cause vegetation and fine root shifts in a water-limited pine forest.

    Directory of Open Access Journals (Sweden)

    Claude Herzog

    Full Text Available Scots pines (Pinus sylvestris L. in the inner-Alpine dry valleys of Switzerland have suffered from increased mortality during the past decades, which has been caused by longer and more frequent dry periods. In addition, a proceeding replacement of Scots pines by pubescent oaks (Quercus pubescens Willd. has been observed. In 2003, an irrigation experiment was performed to track changes by reducing drought pressure on the natural pine forest. After nine years of irrigation, we observed major adaptations in the vegetation and shifts in Scots pine fine root abundance and structure. Irrigation permitted new plant species to assemble and promote canopy closure with a subsequent loss of herb and moss coverage. Fine root dry weight increased under irrigation and fine roots had a tendency to elongate. Structural composition of fine roots remained unaffected by irrigation, expressing preserved proportions of cellulose, lignin and phenolic substances. A shift to a more negative δ13C signal in the fine root C indicates an increased photosynthetic activity in irrigated pine trees. Using radiocarbon (14C measurement, a reduced mean age of the fine roots in irrigated plots was revealed. The reason for this is either an increase in newly produced fine roots, supported by the increase in fine root biomass, or a reduced lifespan of fine roots which corresponds to an enhanced turnover rate. Overall, the responses belowground to irrigation are less conspicuous than the more rapid adaptations aboveground. Lagged and conservative adaptations of tree roots with decadal lifespans are challenging to detect, hence demanding for long-term surveys. Investigations concerning fine root turnover rate and degradation processes under a changing climate are crucial for a complete understanding of C cycling.

  20. Anthropogenic water sources and the effects on Sonoran Desert small mammal communities

    Directory of Open Access Journals (Sweden)

    Aaron B. Switalski

    2017-11-01

    Full Text Available Anthropogenic water sources (AWS are developed water sources used as a management tool for desert wildlife species. Studies documenting the effects of AWS are often focused on game species; whereas, the effects on non-target wildlife are less understood. We used live trapping techniques to investigate rodent abundance, biomass, and diversity metrics near AWS and paired control sites; we sampled vegetation to determine rodent-habitat associations in the Sauceda Mountains of the Sonoran Desert in Arizona. A total of 370 individual mammals representing three genera and eight species were captured in 4,800 trap nights from winter 2011 to spring 2012. A multi-response permutation procedure was used to identify differences in small mammal community abundance and biomass by season and treatment. Rodent abundance, biomass, and richness were greater at AWS compared to control sites. Patterns of abundance and biomass were driven by the desert pocket mouse (Chaetodipus penicillatus which was the most common capture and two times more numerous at AWS compared to controls. Vegetation characteristics, explored using principal components analysis, were similar between AWS and controls. Two species that prefer vegetation structure, Bailey’s pocket mouse (C. baileyi and white-throated woodrat (Neotoma albigula, had greater abundances and biomass near AWS and were associated with habitat having high cactus density. Although small mammals do not drink free-water, perhaps higher abundances of some species of desert rodents at AWS could be related to artificial structure associated with construction or other resources. Compared to the 30-year average of precipitation for the area, the period of our study occurred during a dry winter. During dry periods, perhaps AWS provide resources to rodents related to moisture.

  1. Anthropogenic water sources and the effects on Sonoran Desert small mammal communities.

    Science.gov (United States)

    Switalski, Aaron B; Bateman, Heather L

    2017-01-01

    Anthropogenic water sources (AWS) are developed water sources used as a management tool for desert wildlife species. Studies documenting the effects of AWS are often focused on game species; whereas, the effects on non-target wildlife are less understood. We used live trapping techniques to investigate rodent abundance, biomass, and diversity metrics near AWS and paired control sites; we sampled vegetation to determine rodent-habitat associations in the Sauceda Mountains of the Sonoran Desert in Arizona. A total of 370 individual mammals representing three genera and eight species were captured in 4,800 trap nights from winter 2011 to spring 2012. A multi-response permutation procedure was used to identify differences in small mammal community abundance and biomass by season and treatment. Rodent abundance, biomass, and richness were greater at AWS compared to control sites. Patterns of abundance and biomass were driven by the desert pocket mouse ( Chaetodipus penicillatus ) which was the most common capture and two times more numerous at AWS compared to controls. Vegetation characteristics, explored using principal components analysis, were similar between AWS and controls. Two species that prefer vegetation structure, Bailey's pocket mouse ( C. baileyi ) and white-throated woodrat ( Neotoma albigula) , had greater abundances and biomass near AWS and were associated with habitat having high cactus density. Although small mammals do not drink free-water, perhaps higher abundances of some species of desert rodents at AWS could be related to artificial structure associated with construction or other resources. Compared to the 30-year average of precipitation for the area, the period of our study occurred during a dry winter. During dry periods, perhaps AWS provide resources to rodents related to moisture.

  2. Theoretical analysis of a biogas-fed PEMFC system with different hydrogen purifications: Conventional and membrane-based water gas shift processes

    International Nuclear Information System (INIS)

    Authayanun, Suthida; Aunsup, Pounyaporn; Patcharavorachot, Yaneeporn; Arpornwichanop, Amornchai

    2014-01-01

    Highlights: • Thermodynamic analysis of the biogas-fed PEMFC system is performed. • Conventional and membrane-based WGS processes for H 2 purification are studied. • A flowsheet model of the PEMFC system is developed. • Effect of key parameters on yields of H 2 and carbon in the biogas reformer is shown. • Performance of PEMFC systems with different H 2 purification processes is analyzed. - Abstract: This study presents a thermodynamic analysis of biogas reforming and proton electrolyte membrane fuel cell (PEMFC) integrated process with different hydrogen purifications: conventional and membrane-based water gas shift processes. The aim is to determine the optimal reforming process for hydrogen production from biogas in the PEMFC system. The formation of carbon is concerned in the hydrogen production. The simulation results show that increases in the steam-to-methane ratio and reformer temperature can improve the hydrogen yield and reduce the carbon formation. From the performance analysis, it is found that when the PEMFC is operated at high temperature and fuel utilization, the overall system efficiency enhances. The performance of the PEMFC system with the installation of a water gas shift membrane unit in the hydrogen purification step is slightly increased, compared with a conventional process

  3. Magnetic susceptibility as a direct measure of oxidation state in LiFePO4 batteries and cyclic water gas shift reactors.

    Science.gov (United States)

    Kadyk, Thomas; Eikerling, Michael

    2015-08-14

    The possibility of correlating the magnetic susceptibility to the oxidation state of the porous active mass in a chemical or electrochemical reactor was analyzed. The magnetic permeability was calculated using a hierarchical model of the reactor. This model was applied to two practical examples: LiFePO4 batteries, in which the oxidation state corresponds with the state-of-charge, and cyclic water gas shift reactors, in which the oxidation state corresponds to the depletion of the catalyst. In LiFePO4 batteries phase separation of the lithiated and delithiated phases in the LiFePO4 particles in the positive electrode gives rise to a hysteresis effect, i.e. the magnetic permeability depends on the history of the electrode. During fast charge or discharge, non-uniform lithium distributionin the electrode decreases the hysteresis effect. However, the overall sensitivity of the magnetic response to the state-of-charge lies in the range of 0.03%, which makes practical measurement challenging. In cyclic water gas shift reactors, the sensitivity is 4 orders of magnitude higher and without phase separation, no hysteresis occurs. This shows that the method is suitable for such reactors, in which large changes of the magnetic permeability of the active material occurs.

  4. Water Quality Improvement through Reductions of Pollutant Loads on Small Scale of Bioretention System

    Science.gov (United States)

    Elyza Muha, Norshafa; Mohd Sidek, Lariyah; Jajarmizadeh, Milad

    2016-03-01

    Bioretention system is introduced as an important topic namely Urban Storm Water Management Manual for Malaysia (MSMA) by the Department of Irrigation and Drainage Malaysia (DID) in May 2012. The main objective of this paper is to evaluate the performance of water quality for small scale bioretention system under tropical climate via MUSIC model. Two bioretention systems 1 and 2 are observed based on the difference media depth. The result of bioretention system is compared with a reference model which has infrastructure with Urban Stormwater Improvement Conceptualisation (MUSIC) for pollutants load reduction and water quality results. Assessment of results via MUSIC software indicates a significant percentage of reduction for Total Suspended Solid (TSS), Total Phosphorus (TP) and Total Nitrogen (TN). The prediction of pollutant reduction via using MUSIC has the harmony for requirement in MSMA. TSS pollutant reduction is more than 80%, while for TP and TN more than 50%. The outcome of this study can be helpful for improvement of the existing MSMA guidelines for application of bioretention systems in Malaysia.

  5. Development and Deployment Strategy for a Small Advanced Light Water Reactor

    International Nuclear Information System (INIS)

    Modro, S. Michael; Reith, Raymond; Babka, Pierre

    2002-01-01

    This paper discusses development and deployment strategies for the modular Multi-Application Small Light Water Reactor (MASLWR). Modularity, small size, capability to transport whole modules including containment on road or by rail, simplicity and safety of this reactor allows innovative deployment strategies for a variety of applications. A larger plant may be constructed of many independent power generation units. The multi-module plant is intended to be operated as a base-load plant. Each reactor is to be operated at full load. However, in response to changes in power demand individual units can brought on line or shut down. A larger plant can be built in small increments to match the power demand balancing capital commitments with revenues from sales of electricity. Also, an unplanned shutdown of a reactor only affects a relatively small portion of the total plant capacity. Simplification of MASLWR design and extensive use of modularization coupled with factory fabrication will result in improved productivity of fieldwork and improved quality achieved in a factory environment. The initial MASLWR design concept development has been completed under the U.S. DOE (Department of Energy) Nuclear Energy Research Initiative (NERI) project. This paper discusses a strategy for developing and deploying a MASLWR plant by 2015. This schedule is realistic because the plant design relies on existing industrial experience and manufacturing capabilities. The development strategy consists of the following elements: concept confirmation through testing (under the NERI program a scaled integral test facility has been constructed and initial testing performed), design concept optimization, and design certification based on prototype testing. (authors)

  6. Market shifting

    Energy Technology Data Exchange (ETDEWEB)

    Forst, Michael

    2013-11-01

    After years of oversupply and artificially low module pricing, market analysts believe that the solar industry will begin to stabilize by 2017. While the market activities are shifting from Europe to the Asia Pacific region and the United States, the solar shakeout continues to be in full swing including solar cell and module manufacturing. (orig.)

  7. Tough Shift

    DEFF Research Database (Denmark)

    Brewer, Robert S.; Verdezoto, Nervo; Holst, Thomas

    2015-01-01

    people to change their behavior at home. Leveraging prior research on encouraging reductions in residential energy use through game play, we introduce ShareBuddy: a casual mobile game intended to encourage players not only to reduce, but also to shift their electricity use. We conducted two field studies...... real-world resource use into a game....

  8. Enhancing load-following and/or spectral shift capability in single-sparger natural circulation boiling water reactors

    International Nuclear Information System (INIS)

    Oosterkamp, W.J.

    1992-01-01

    This patent describes a method for obtaining load-following capability in a coiling water reactor (BWR) wherein housed within a reactor pressure vessel (RPV) is a nuclear core disposed within a shroud having a shroud head and which with the RPV defines an annulus region disposed beneath the nuclear core, an upper steam dome connected to a steam outlet in the RPV, a core upper plenum formed within the shroud head and disposed atop the nuclear core, a chimney mounted atop the shroud head and in fluid communication with the core upper plenum and with a steam separator having a skirt which is in fluid communication with the steam dome, the region outside of the chimney defining a downcomer region, there being a water level established therein under normal operation of the BWR, and the RPV containing a feedwater inlet. It comprises: disposing a single sparger connected to the feedwater inlet above the steam separator skirt bottom about the interior circumference of the RPV at an elevation at approximately the water level established during normal operation of the BWR; and adjusting the feedwater flow through the inlet and into the sparger to vary the water level to be above, at or below the elevational location of the sparger in response to load-following need

  9. An Experimental investigation of critical flow rates of subcooled water through short pipes with small diameters

    International Nuclear Information System (INIS)

    Park, Choon Kyung

    1997-02-01

    The primary objective of this study is to improve our understanding on critical flow phenomena in a small size leak and to develop a model which can be used to estimate the critical mass flow rates through reactor vessel or primary coolant pipe wall. For this purpose, critical two-phase flow phenomena of subcooled water through short pipes (100 ≤ L ≤ 400 mm) with small diameters (3.4 ≤ D ≤ 7.15 mm) have been experimentally investigated for wide ranges of subcooling (0∼199 .deg. C) and pressure (0.5∼2.0MPa). To examine the effects of various parameters (i.e., the location of flashing inception, the degree of subcooling, the stagnation temperature and pressure, and the pipe size) on the critical two-phase flow rates of subcooled water, a total of 135 runs were made for various combinations of test parameters using four different L/D test sections. Experimental results that show effects of various parameters on subcooled critical two-phase flow rates are presented. The measured static pressure profiles along the discharge pipe show that the critical flow rate can be strongly influenced by the flashing location. The locations of saturation pressure for different values of the stagnation subcooling have been consistently determined from the pressure profiles. Based upon the test results, two important parameters have been identified. These are cold state discharge coefficient and dimensionless subcooling, which are found to efficiently take into account the test section geometry and the stagnation conditions, respectively. A semi-empirical model has been developed to predict subcooled two-phase flow rates through small size openings. This model provides a simple and direct calculation of the critical mass flow rates with information on the initial condition and on the test section geometry. Comparisons between the mass fluxes calculated by present model and a total of 755 selected experimental data from 9 different investigators show that the agreement is

  10. A rainfall-runoff model for two small ungauged catchment using the water balance of a reservoir for calibration

    NARCIS (Netherlands)

    de Hamer, W.; Love, D.; Booij, Martijn J.; Hoekstra, Arjen Ysbert

    2007-01-01

    In semi‐arid regions, small artificial surface reservoirs are important to meet the domestic and agricultural water requirements of smallholder farmers. The research objective of the study was to determine the rainfall‐runoff relation of two ungauged rivers using the measured water levels of the

  11. Impacts of nutrients and pesticides from small- and large-scale agriculture on the water quality of Lake Ziway, Ethiopia

    NARCIS (Netherlands)

    Teklu, Berhan M.; Hailu, Amare; Wiegant, Daniel A.; Scholten, Bernice S.; Brink, van den Paul J.

    2018-01-01

    The area around Lake Ziway in Ethiopia is going through a major agricultural transformation with both small-scale farmers and large horticultural companies using pesticides and fertilisers at an increased rate. To be able to understand how this influences the water quality of Lake Ziway, water

  12. Impacts of nutrients and pesticides from small- and large-scale agriculture on the water quality of Lake Ziway, Ethiopia

    NARCIS (Netherlands)

    Teklu, Berhan M.; Hailu, Amare; Wiegant, Daniel A.; Scholten, Bernice S.; Brink, van den Paul J.

    2016-01-01

    The area around Lake Ziway in Ethiopia is going through a major agricultural transformation with both small-scale farmers and large horticultural companies using pesticides and fertilisers at an increased rate. To be able to understand how this influences the water quality of Lake Ziway, water

  13. Performance characteristics of single effect lithium bromide/ water absorption chiller for small data centers

    Science.gov (United States)

    Mysore, Abhishek Arun Babu

    A medium data center consists of servers performing operations such as file sharing, collaboration and email. There are a large number of small and medium data centers across the world which consume more energy and are less efficient when compared to large data center facilities of companies such as GOOGLE, APPLE and FACEBOOK. Such companies are making their data center facilities more environmental friendly by employing renewable energy solutions such as wind and solar to power the data center or in data center cooling. This not only reduces the carbon footprint significantly but also decreases the costs incurred over a period of time. Cooling of data center play a vital role in proper functioning of the servers. It is found that cooling consumes about 50% of the total power consumed by the data center. Traditional method of cooling includes the use of mechanical compression chillers which consume lot of power and is not desirable. In order to eliminate the use of mechanical compressor chillers renewable energy resources such as solar and wind should be employed. One such technology is solar thermal cooling by means of absorption chiller which is powered by solar energy. The absorption chiller unit can be coupled with either flat plate or evacuated tube collectors in order to achieve the required inlet temperature for the generator of the absorption chiller unit. In this study a modular data center is considered having a cooling load requirement of 23kw. The performance characteristics of a single stage Lithium Bromide/ water refrigeration is presented in this study considering the cooling load of 23kw. Performance characteristics of each of the 4 heat exchangers within the unit is discussed which helps in customizing the unit according to the users' specific needs. This analysis helps in studying the importance of different properties such as the effect of inlet temperatures of hot water for generator, inlet temperatures of cooling water for absorber and

  14. Mechanical spectral shift reactor

    International Nuclear Information System (INIS)

    Wilson, J.F.; Sherwood, D.G.

    1982-01-01

    A mechanical spectral shift reactor comprises a reactive core having fuel assemblies accommodating both water displacer elements and neutron absorbing control rods for selectively changing the volume of water-moderator in the core. The fuel assemblies with displacer and control rods are arranged in alternating fashion so that one displacer element drive mechanism may move displacer elements in more than one fuel assembly without interfering with the movement of control rods of a corresponding control rod drive mechanisms. (author)

  15. 40 CFR 142.310 - How can a person served by the public water system obtain EPA review of a State proposed small...

    Science.gov (United States)

    2010-07-01

    ... water system obtain EPA review of a State proposed small system variance? 142.310 Section 142.310... PRIMARY DRINKING WATER REGULATIONS IMPLEMENTATION Variances for Small System Public Participation § 142.310 How can a person served by the public water system obtain EPA review of a State proposed small...

  16. Tentative Study on Performance of Darriues-Type Hydroturbine Operated in Small Open Water Channel

    Science.gov (United States)

    Matsushita, D.; Moriyama, R.; Nakashima, K.; Watanabe, S.; Okuma, K.; Furukawa, A.

    2014-03-01

    The development of small hydropower is one of the realistic and preferable utilizations of renewable energy, but the extra-low head hydropower less than 2 m is almost undeveloped yet for some reasons. The authors have developed several types of Darrieus-type hydro-turbine system, and among them, the Darrieus-turbine with a wear and a nozzle installed upstream of turbine is so far in success to obtain more output power, i.e. more shaft torque, by gathering all water into the turbine. However, there can several cases exist, in which installing the wear covering all the flow channel width is unrealistic. Then, in the present study, the hydraulic performances of Darrieus-type hydro-turbine with the inlet nozzle is investigated, putting alone in a small open channel without upstream wear. In the experiment, the five-bladed Darrieus-type runner with the pitch-circle diameter of 300 mm and the blade span of 300 mm is vertically installed in the open channel with the width of 1,200 mm. The effectiveness of the shape of the inlet nozzle is also examined using two types of two-dimensional symmetric nozzle, the straight line nozzle (SL nozzle) with the converging angle of 45 degrees and the half diameter curved nozzle (HD nozzle) whose radius is a half diameter of runner pitch circle. Inlet and outlet nozzle widths are in common for the both nozzles, which are 540 mm and 240 mm respectively. All the experiments are carried out under the conditions with constant flow rate and downstream water level, and performances are evaluated by measured output torque and the measured head difference between the water levels upstream and downstream of the turbine. As a result, it is found that the output power is remarkably increased by installing the inlet nozzle, and the turbine with SL nozzle produces larger power than that with HD nozzle. However, the peak efficiency is deteriorated in both cases. The speed ratio defined by the rotor speed divided by the downstream water velocity at

  17. Tentative Study on Performance of Darriues-Type Hydroturbine Operated in Small Open Water Channel

    International Nuclear Information System (INIS)

    Matsushita, D; Watanabe, S; Okuma, K; Moriyama, R; Nakashima, K; Furukawa, A

    2014-01-01

    The development of small hydropower is one of the realistic and preferable utilizations of renewable energy, but the extra-low head hydropower less than 2 m is almost undeveloped yet for some reasons. The authors have developed several types of Darrieus-type hydro-turbine system, and among them, the Darrieus-turbine with a wear and a nozzle installed upstream of turbine is so far in success to obtain more output power, i.e. more shaft torque, by gathering all water into the turbine. However, there can several cases exist, in which installing the wear covering all the flow channel width is unrealistic. Then, in the present study, the hydraulic performances of Darrieus-type hydro-turbine with the inlet nozzle is investigated, putting alone in a small open channel without upstream wear. In the experiment, the five-bladed Darrieus-type runner with the pitch-circle diameter of 300 mm and the blade span of 300 mm is vertically installed in the open channel with the width of 1,200 mm. The effectiveness of the shape of the inlet nozzle is also examined using two types of two-dimensional symmetric nozzle, the straight line nozzle (SL nozzle) with the converging angle of 45 degrees and the half diameter curved nozzle (HD nozzle) whose radius is a half diameter of runner pitch circle. Inlet and outlet nozzle widths are in common for the both nozzles, which are 540 mm and 240 mm respectively. All the experiments are carried out under the conditions with constant flow rate and downstream water level, and performances are evaluated by measured output torque and the measured head difference between the water levels upstream and downstream of the turbine. As a result, it is found that the output power is remarkably increased by installing the inlet nozzle, and the turbine with SL nozzle produces larger power than that with HD nozzle. However, the peak efficiency is deteriorated in both cases. The speed ratio defined by the rotor speed divided by the downstream water velocity at

  18. Marine Microphytobenthic Assemblage Shift along a Natural Shallow-Water CO2 Gradient Subjected to Multiple Environmental Stressors

    OpenAIRE

    Johnson, V; Brownlee, C; Milazzo, M; Hall-Spencer, J

    2015-01-01

    Predicting the effects of anthropogenic CO2 emissions on coastal ecosystems requires an understanding of the responses of algae, since these are a vital functional component of shallow-water habitats. We investigated microphytobenthic assemblages on rock and sandy habitats along a shallow subtidal pCO2 gradient near volcanic seeps in the Mediterranean Sea. Field studies of natural pCO2 gradients help us understand the likely effects of ocean acidification because entire communities are subjec...

  19. Population Shift between the Open and Closed States Changes the Water Permeability of an Aquaporin Z Mutant

    DEFF Research Database (Denmark)

    Xin, Lin; Helix Nielsen, Claus; Su, Haibin

    2012-01-01

    gate in the triple mutant with R189 as the primary steric gate in both mutant and WT AqpZ. The double gates (R189 and W43-F183) result in a high population of the closed conformation in the mutant. Occasionally an open state, with diffusive water permeability very close to that of WT AqpZ, was observed...... be modulated and may further point to how aquaporin function can be optimized for biomimetic membrane applications....

  20. Selecting Sustainability Indicators for Small to Medium Sized Urban Water Systems Using Fuzzy-ELECTRE.

    Science.gov (United States)

    Chhipi-Shrestha, Gyan; Hewage, Kasun; Sadiq, Rehan

    2017-03-01

      Urban water systems (UWSs) are challenged by the sustainability perspective. Certain limitations of the sustainability of centralized UWSs and decentralized household level wastewater treatments can be overcome by managing UWSs at an intermediate scale, referred to as small to medium sized UWSs (SMUWSs). SMUWSs are different from large UWSs, mainly in terms of smaller infrastructure, data limitation, smaller service area, and institutional limitations. Moreover, sustainability assessment systems to evaluate the sustainability of an entire UWS are very limited and confined only to large UWSs. This research addressed the gap and has developed a set of 38 applied sustainability performance indicators (SPIs) by using fuzzy-Elimination and Choice Translating Reality (ELECTRE) I outranking method to assess the sustainability of SMUWSs. The developed set of SPIs can be applied to existing and new SMUWSs and also provides a flexibility to include additional SPIs in the future based on the same selection criteria.

  1. Productivity of Stored Water in Some Selected Multiple Use Small Reservoirs in the Upper East Region of Ghana

    Science.gov (United States)

    Annor, F. O.; Yamoah-Antwi, D.; Odai, S. N.; Adjei, K. A.; van de Giesen, N. C.

    2009-04-01

    The Upper East Region (UER) of Ghana is a water stressed area with agriculture as the main occupation of the inhabitants. The importance of small reservoirs for the sustenance of the livelihood of the people in this part of the country during the dry season cannot be over emphasized. Most of these small reservoirs were constructed, in the 1960s, mainly with the aim of providing water for domestic use and livestock watering during the dry periods of the year. Over the years, however, these small reservoirs have been put to a variety of uses, some of which accelerate the depletion of the stored water. The reservoirs are therefore most times, unable to serve the purposes for which they were constructed. To address this situation, a study was conducted to determine the productivity of stored water in small reservoirs to better inform policy makers and water managers in the allocation of water especially in the dry season. Water productivity can be thought of as the output (product) that can be obtained per unit volume of water used or applied for either crop or livestock production. Data on crops and livestock were obtained through questionnaire administration, interviews, focus group discussions, physical measurements as well as field observations from nine reservoirs in the UER. The research findings show that donkeys have the highest productivity of about US90 followed by cattle with US70. These high productivity values are as a result of the variety of products and services rendered by donkeys and cattle. For crop, tomatoes have the highest productivity value compared with pepper and leafy vegetables. Despite the fact that donkeys had the highest productivity and hence priority over all uses, it is prudent to note that, inhabitants of the study area aside the sale of livestock for money (income) keep livestock for prestige. Therefore in the allocation of stored water in small multiple use reservoirs, the allocation criteria should consider the views, values and

  2. A radical shift from soft-water to hard-water lake: palaeolimnological evidence from Lake Kooraste Kõverjärv, southern Estonia

    Directory of Open Access Journals (Sweden)

    Tiiu Alliksaar

    2012-11-01

    Full Text Available The Water Framework Directive (WFD of the European Union requires the quality of all European water bodies to be examined, and aims to achieve good status by 2015. This study was initiated to assess whether a potential reference lake for identifying lake-type specific reference conditions meets the WFD requirements, of being minimally impacted by human activity during the last centuries. The sediments of Lake Kooraste Kõverjärv were analysed for diatom assemblages and sediment composition; past changes in the lake-water pH and total phosphorus were reconstructed, using quantitative models on sedimentary diatoms. The chronology of sediments was established, using spheroidal fly-ash particles stratigraphy. Palaeolimnological investigations, supported by information from historical maps, revealed that man-made changes around the lake have severely influenced its ecological conditions. The lake, which had been oligotrophic with soft and clear water before the mid-17th century, has been trans­formed into a hard-water lake by modifications to the inflow and outflow. The lake water quality has also been altered by the infiltration of nutrients from a nearby hypertrophic lake that was used for flax retting since the 19th century. Although the ecological status of the lake has remained good despite all these changes, it is still questionable whether to nominate it as a reference lake for stratified hard-water lake types.

  3. Model Studies on the Effectiveness of MBBR Reactors for the Restoration of Small Water Reservoirs

    Science.gov (United States)

    Nowak, Agata; Mazur, Robert; Panek, Ewa; Chmist, Joanna

    2018-02-01

    The authors present the Moving Bed Biofilm Reactor (MBBR) model with a quasi-continuous flow for small water reservoir restoration, characterized by high concentrations of organic pollutants. To determine the efficiency of wastewater treatment the laboratory analysis of physic-chemical parameters were conducted for the model on a semi-technical scale of 1:3. Wastewater treatment process was carried out in 24 h for 1 m3 for raw sewage. The startup period was 2 weeks for all biofilters (biological beds). Approximately 50% reduction in COD and BOD5 was obtained on average for the studied bioreactors. Significant improvements were achieved in theclarity of the treated wastewater, with the reduction of suspension by 60%. The oxygen profile has improved significantly in 7 to 9 hours of the process, and a diametric reduction in the oxidative reduction potential was recorded. A preliminary model of biological treatment effectiveness was determined based on the conducted studies. In final stages, the operation mode was set in real conditions of polluted water reservoirs.

  4. An automated microinfiltrometer to measure small-scale soil water infiltration properties

    Directory of Open Access Journals (Sweden)

    Gordon Dennis C.

    2014-09-01

    Full Text Available We developed an automated miniature constant-head tension infiltrometer that measures very small infiltration rates at millimetre resolution with minimal demands on the operator. The infiltrometer is made of 2.9 mm internal radius glass tube, with an integrated bubbling tower to maintain constant negative head and a porous mesh tip to avoid air-entry. In the bubbling tower, bubble formation and release changes the electrical resistance between two electrodes at the air-inlet. Tests were conducted on repacked sieved sands, sandy loam soil and clay loam soil, packed to a soil bulk density ρd of 1200 kg m-3 or 1400 kg m-3 and tested either air-dried or at a water potential ψ of -50 kPa. The change in water volume in the infiltrometer had a linear relationship with the number of bubbles, allowing bubble rate to be converted to infiltration rate. Sorptivity measured with the infiltrometer was similar between replicates and showed expected differences from soil texture and ρd, varying from 0.15 ± 0.01 (s.e. mm s-1/2 for 1400 kg m-3 clay loam at ψ = -50 kPa to 0.65 ± 0.06 mm s-1/2 for 1200 kg m-3 air dry sandy loam soil. An array of infiltrometers is currently being developed so many measurements can be taken simultaneously.

  5. Impact of Catchment Area Activities on Water Quality in Small Retention Reservoirs

    Directory of Open Access Journals (Sweden)

    Oszczapińska Katarzyna

    2018-01-01

    Full Text Available The aim of the study was to evaluate catchment area impact on small water reservoirs condition in Podlasie. The researches were conducted in two different catchment areas. Topiło reservoir, located in Podlasie area in the south-east of Białowieża Forest, has typical sylvan catchment. Second reservoir, Dojlidy, is located also in Podlasie, in the south-east of Białystok as a part of Dojlidy Ponds. In contrast to Topiło, Dojlidy has agricultural catchment. Water samples collected from five sites along each reservoir were analysed for the presence of total nitrogen and phosphorus, chlorophyll “a”, reaction, turbidity and conductivity. Researches took place in spring, summer and autumn 2013 (Topiło Lake and 2014/2015 (Dojlidy. The lowest trophic state was observed in autumn and the highest in summer. Because of the high loads of phosphorus received by the reservoirs, this element did not limit primary production. Calculated TSI values based on total phosphorus were always markedly higher than calculated on chlorophyll-a and total nitrogen. Both reservoirs demonstrated TSI indexes specific to hypertrophic lakes due to large amount of total phosphorus.

  6. Impact of Catchment Area Activities on Water Quality in Small Retention Reservoirs

    Science.gov (United States)

    Oszczapińska, Katarzyna; Skoczko, Iwona; Szczykowska, Joanna

    2018-02-01

    The aim of the study was to evaluate catchment area impact on small water reservoirs condition in Podlasie. The researches were conducted in two different catchment areas. Topiło reservoir, located in Podlasie area in the south-east of Białowieża Forest, has typical sylvan catchment. Second reservoir, Dojlidy, is located also in Podlasie, in the south-east of Białystok as a part of Dojlidy Ponds. In contrast to Topiło, Dojlidy has agricultural catchment. Water samples collected from five sites along each reservoir were analysed for the presence of total nitrogen and phosphorus, chlorophyll "a", reaction, turbidity and conductivity. Researches took place in spring, summer and autumn 2013 (Topiło Lake) and 2014/2015 (Dojlidy). The lowest trophic state was observed in autumn and the highest in summer. Because of the high loads of phosphorus received by the reservoirs, this element did not limit primary production. Calculated TSI values based on total phosphorus were always markedly higher than calculated on chlorophyll-a and total nitrogen. Both reservoirs demonstrated TSI indexes specific to hypertrophic lakes due to large amount of total phosphorus.

  7. Passive safe small reactor for distributed energy supply system sited in water filled pit at seaside

    International Nuclear Information System (INIS)

    Ishida, Toshihisa; Imayoshi, Shou

    2003-01-01

    Japan Atomic Energy Research Institute has developed a Passive Safe Small Reactor for Distributed Energy Supply System (PSRD) concept. The PSRD is an integrated-type PWR with reactor thermal power of 100 to 300 MW aimed at supplying electricity, district heating, etc. In design of the PSRD, high priority is laid on enhancement of safety as well as improvement of economy. Safety is enhanced by the following means: i) Extreme reduction of pipes penetrating the reactor vessel, by limiting to only those of the steam, the feed water and the safety valves, ii) Adoption of the water filled containment and the passive safety systems with fluid driven by natural circulation force, and iii) Adoption of the in-vessel type control rod drive mechanism, accompanying a passive reactor shut-down device. For improvement of economy, simplification of the reactor system and long operation of the core over five years without refueling with low enriched UO 2 fuel rods are achieved. To avoid releasing the radioactive materials to the circumstance even if a hypothetical accident, the containment is submerged in a pit filled with seawater at a seaside. Refueling or maintenance of the reactor can be conducted using an exclusive barge instead of the reactor building. (author)

  8. Experimental investigation of single small bubble motion in linear shear flow in water

    International Nuclear Information System (INIS)

    Li, Zhongchun; Zhao, Yang; Song, Xiaoming; Yu, Hongxing; Jiang, Shengyao; Ishii, Mamoru

    2016-01-01

    Highlights: • The bubble motion in simple linear shear flow was experimentally investigated. • The bubble trajectories, bubble velocity and drag and lift force were obtained using image process routine. • The bubble trajectory was coupled with a zigzag motion and incline path. • The lift force was kept negative and it decreased when bubble diameter and shear flow magnitude increased. - Abstract: The motion of small bubble in a simple shear flow in water was experimental studied. Stable shear flow with low turbulence level was achieved with curved screen and measured using LDV. The bubbles were captured by high speed camera and the captured images were processed with digital image routine. The bubble was released from a capillary tube. The instantaneous bubble position, bubble velocity and forces were obtained based on the captured parameters. The quasi-steady lift coefficient was determined by the linear fitting of the bubble trajectory of several cycles. The results indicated that the lateral migration was coupled with the zigzag motion of bubble in the present experiment. The bubble migrated to the left side and its quasi-steady lift coefficient was negative. Good repeatable results were observed by measurements of 18 bubbles. The bubble motion in shear flow in water was first experimental studied and negative lift force was observed in the present study condition. The lift coefficient decreased when shear stress magnitude or bubble diameter increased in the present experiment condition.

  9. Simulation of small break loss of coolant accident in pressurized water reactor (PWR)

    International Nuclear Information System (INIS)

    Abass, N. M. N.

    2012-02-01

    A major safety concern in pressurized-water-reactor (PWR) design is the loss-of-coolant accident (LOCA),in which a break in the primary coolant circuit leads to depressurization, boiling of the coolant, consequent reduced cooling of the reactor core, and , unless remedial measures are taken, overheating of the fuel rods. This concern has led to the development of several simulators for safety analysis. This study demonstrates how the passive and active safety systems in conventional and advanced PWR behave during the small break loss of Coolant Accident (SBLOCA). The consequences of SBOLOCA have been simulated using IAEA Generic pressurized Water Reactor Simulator (GPWRS) and personal Computer Transient analyzer (PCTRAN) . The results were presented and discussed. The study has confirmed the major safety advantage of passive plants versus conventional PWRs is that the passive safety systems provide long-term core cooling and decay heat removal without the need for operator actions and without reliance on active safety-related system. (Author)

  10. Tuning dissociation using isoelectronically doped graphene and hexagonal boron nitride: Water and other small molecules

    Energy Technology Data Exchange (ETDEWEB)

    Al-Hamdani, Yasmine S. [Thomas Young Centre and London Centre for Nanotechnology, 17–19 Gordon Street, London WC1H 0AH (United Kingdom); Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom); Alfè, Dario [Thomas Young Centre and London Centre for Nanotechnology, 17–19 Gordon Street, London WC1H 0AH (United Kingdom); Department of Earth Sciences, University College London, Gower Street, London WC1E 6BT (United Kingdom); Lilienfeld, O. Anatole von [Institute of Physical Chemistry and National Center for Computational Design and Discovery of Novel Materials (MARVEL), Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel (Switzerland); Michaelides, Angelos, E-mail: angelos.michaelides@ucl.ac.uk [Thomas Young Centre and London Centre for Nanotechnology, 17–19 Gordon Street, London WC1H 0AH (United Kingdom); Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2016-04-21

    Novel uses for 2-dimensional materials like graphene and hexagonal boron nitride (h-BN) are being frequently discovered especially for membrane and catalysis applications. Still however, a great deal remains to be understood about the interaction of environmentally and industrially relevant molecules such as water with these materials. Taking inspiration from advances in hybridising graphene and h-BN, we explore using density functional theory, the dissociation of water, hydrogen, methane, and methanol on graphene, h-BN, and their isoelectronic doped counterparts: BN doped graphene and C doped h-BN. We find that doped surfaces are considerably more reactive than their pristine counterparts and by comparing the reactivity of several small molecules, we develop a general framework for dissociative adsorption. From this a particularly attractive consequence of isoelectronic doping emerges: substrates can be doped to enhance their reactivity specifically towards either polar or non-polar adsorbates. As such, these substrates are potentially viable candidates for selective catalysts and membranes, with the implication that a range of tuneable materials can be designed.

  11. Water quality assessment of a small peri-urban river using low and high frequency monitoring.

    Science.gov (United States)

    Ivanovsky, A; Criquet, J; Dumoulin, D; Alary, C; Prygiel, J; Duponchel, L; Billon, G

    2016-05-18

    The biogeochemical behaviors of small rivers that pass through suburban areas are difficult to understand because of the multi-origin inputs that can modify their behavior. In this context, a monitoring strategy has been designed for the Marque River, located in Lille Metropolitan area of northern France, that includes both low-frequency monitoring over a one-year period (monthly sampling) and high frequency monitoring (measurements every 10 minutes) in spring and summer. Several environmental and chemical parameters are evaluated including rainfall events, river flow, temperature, dissolved oxygen, turbidity, conductivity, nutritive salts and dissolved organic matter. Our results from the Marque River show that (i) it is impacted by both urban and agricultural inputs, and as a consequence, the concentrations of phosphate and inorganic nitrogen have degraded the water quality; (ii) the classic photosynthesis/respiration processes are disrupted by the inputs of organic matter and nutritive salts; (iii) during dry periods, the urban sewage inputs (treated or not) are more important during the day, as indicated by higher river flows and maximal concentrations of ammonium; (iv) phosphate concentrations depend on oxygen contents in the river; (v) high nutrient concentrations result in eutrophication of the Marque River with lower pH and oxygen concentrations in summer. During rainfalls, additional inputs of ammonium, biodegradable organic matter as well as sediment resuspension result in anoxic events; and finally (vi) concentrations of nitrate are approximately constant over the year, except in winter when higher inputs can be recorded. Having better identified the processes responsible for the observed water quality, a more informed remediation effort can be put forward to move this suburban river to a good status of water quality.

  12. Risk Evaluation of Multiple Hazards during Sediment and Water Related Disasters in a Small Basin

    Science.gov (United States)

    Yamanoi, Kazuki; Fujita, Masaharu

    2016-04-01

    To reduce human damage due to sediment and water related disasters induced by heavy rainfall, warning and evacuation system is very important. In Japan, the Meteorological Agency issues the sediment disaster alert when the potential of sediment disaster increases. Following the alert, local government issues evacuation advisory considering the alert and premonitory phenomena. However, it is very difficult for local people to perceive the dangerousness around them because the alert and advisory do not contain any definite information. Therefore, they sometimes misjudge the evacuation action. One reason of this is not only crucial hazards but also relatively small-scale multiple hazards take place and rise evacuation difficulties during sediment and water related disaster. Examples of small-scale hazards include: rainfall-associated hazards such as poor visibility or road submergence; landslide-associated hazards such as slope failure or sediment inflow; and flood-associated hazards such as overtopping of river dike, inundation, or destruction of bridges. The purpose of this study was to estimate the risk of multiple hazards during disaster events by numerical simulation. We applied the integrated sediment runoff model on unit channels, unit slopes, and slope units to an actual sediment and water related disaster occurred in a small basin in Tamba city, Hyogo, Japan. The maximum rainfall per hour was 91 mm (17/09/2014 2:00˜3:00) and the maximum daily precipitation was 414mm. The integrated model contains semi-physical based landslide prediction (sediment production) model, rainfall runoff model employing the kinematic wave method, model of sediment supply to channels, and bedload and suspended sediment transport model. We evaluated the risk of rainfall-associated hazards in each slope unit into 4 levels (Level I ˜ IV) using the rainfall intensity Ir [mm/hour]. The risk of flood- associated hazards were also estimated using the ratio of calculated water level and

  13. Shift in the microbial ecology of a hospital hot water system following the introduction of an on-site monochloramine disinfection system.

    Science.gov (United States)

    Baron, Julianne L; Vikram, Amit; Duda, Scott; Stout, Janet E; Bibby, Kyle

    2014-01-01

    Drinking water distribution systems, including premise plumbing, contain a diverse microbiological community that may include opportunistic pathogens. On-site supplemental disinfection systems have been proposed as a control method for opportunistic pathogens in premise plumbing. The majority of on-site disinfection systems to date have been installed in hospitals due to the high concentration of opportunistic pathogen susceptible occupants. The installation of on-site supplemental disinfection systems in hospitals allows for evaluation of the impact of on-site disinfection systems on drinking water system microbial ecology prior to widespread application. This study evaluated the impact of supplemental monochloramine on the microbial ecology of a hospital's hot water system. Samples were taken three months and immediately prior to monochloramine treatment and monthly for the first six months of treatment, and all samples were subjected to high throughput Illumina 16S rRNA region sequencing. The microbial community composition of monochloramine treated samples was dramatically different than the baseline months. There was an immediate shift towards decreased relative abundance of Betaproteobacteria, and increased relative abundance of Firmicutes, Alphaproteobacteria, Gammaproteobacteria, Cyanobacteria and Actinobacteria. Following treatment, microbial populations grouped by sampling location rather than sampling time. Over the course of treatment the relative abundance of certain genera containing opportunistic pathogens and genera containing denitrifying bacteria increased. The results demonstrate the driving influence of supplemental disinfection on premise plumbing microbial ecology and suggest the value of further investigation into the overall effects of premise plumbing disinfection strategies on microbial ecology and not solely specific target microorganisms.

  14. Integration of Methane Steam Reforming and Water Gas Shift Reaction in a Pd/Au/Pd-Based Catalytic Membrane Reactor for Process Intensification.

    Science.gov (United States)

    Castro-Dominguez, Bernardo; Mardilovich, Ivan P; Ma, Liang-Chih; Ma, Rui; Dixon, Anthony G; Kazantzis, Nikolaos K; Ma, Yi Hua

    2016-09-19

    Palladium-based catalytic membrane reactors (CMRs) effectively remove H₂ to induce higher conversions in methane steam reforming (MSR) and water-gas-shift reactions (WGS). Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H₂, CO and CO₂. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H₂O, CO₂ and H₂. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H₂ and induce higher methane and CO conversions while yielding ultrapure H₂ and compressed CO₂ ready for dehydration. Experimental results involving (i) a conventional packed bed reactor packed (PBR) for MSR, (ii) a PBR with five layers of two catalysts in series and (iii) a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD) model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H₂ permeance and purity, high CH₄ conversion levels and reduced CO yields.

  15. Water-vapor absorption line measurements in the 940-nm band by using a Raman-shifted dye laser

    Science.gov (United States)

    Chu, Zhiping; Wilkerson, Thomas D.; Singh, Upendra N.

    1993-01-01

    We report water-vapor absorption line measurements that are made by using the first Stokes radiation (930-982 nm) with HWHM 0.015/cm generated by a narrow-linewidth, tunable dye laser. Forty-five absorption line strengths are measured with an uncertainty of 6 percent and among them are fourteen strong lines that are compared with previous measurements for the assessment of spectral purity of the light source. Thirty air-broadened linewidths are measured with 8 percent uncertainty at ambient atmospheric pressure with an average of 0.101/cm. The lines are selected for the purpose of temperature-sensitive or temperature-insensitive lidar measurements. Results for these line strengths and linewidths are corrected for broadband radiation and finite laser linewidth broadening effects and compared with the high-resolution transmission molecular absorption.

  16. The effects of rare earths on activity and surface properties of Ru/γ-Al2O3 catalyst for water gas shift reaction

    Directory of Open Access Journals (Sweden)

    Laitao Luo

    2007-04-01

    Full Text Available A series of Ru-RE/γ- Al2O3 (RE = Ce, Pr, La, Sm, Tb or Gd and Ru/γ- Al2O3 catalysts were prepared by impregnation method. The influence of rare earths on the catalytic performance of Ru/γ- Al2O3 catalyst for the water gas shift reaction was studied. The catalysts were characterized by X-ray diffraction (XRD, temperature programmed reduction (TPR, temperature programmed desorption (TPD, and CO chemisorption. The results show that the addition of rare earths increases the catalytic activity of Ru based catalyst. Among these cerium is the most remarkably. The addition of cerium increases the active surface area, improves the dispersion of ruthenium, and weakens the interaction between ruthenium and the support. Cerium also affects the adsorption and reduction properties of Ru/γ-Al2O3 catalyst.

  17. Spectral shift reactor

    International Nuclear Information System (INIS)

    Carlson, W.R.; Piplica, E.J.

    1982-01-01

    A spectral shift pressurized water reactor comprising apparatus for inserting and withdrawing water displacer elements having differing neutron absorbing capabilities for selectively changing the water-moderator volume in the core thereby changing the reactivity of the core. The displacer elements comprise substantially hollow cylindrical low neutron absorbing rods and substantially hollow cylindrical thick walled stainless rods. Since the stainless steel displacer rods have greater neutron absorbing capability, they can effect greater reactivity change per rod. However, by arranging fewer stainless steel displacer rods in a cluster, the reactivity worth of the stainless steel displacer rod cluster can be less than a low neutron absorbing displacer rod cluster. (author)

  18. Scientific Symposium “Small Solution for Big Water-Related Problems: Innovative Microarrays and Small Sensors to Cope with Water Quality and Food Security”

    Directory of Open Access Journals (Sweden)

    Stefania Marcheggiani

    2015-12-01

    Full Text Available This issue presents the conclusive results of two European Commission funded Projects, namely Universal Microarrays for the Evaluation of Fresh-water Quality Based on Detection of Pathogens and their Toxins (MicroAQUA and Rationally Designed Aquatic Receptors (RADAR. These projects focused their activities on the quality of drinking water as an extremely important factor for public health of humans and animals. The MicroAQUA Project aimed at developing a universal microarray chip for the detection of various pathogens (cyanobacteria, bacteria, viruses and parasitic protozoa and their toxins in waters. In addition, the project included the detection of select species of diatoms, which represent reliable bio-indicators to assess overall water quality. Large numbers of compounds are released into the environment; some of these are toxins such as endocrine disrupting compounds (EDCs and can affect the endocrine, immune and nervous systems of a wide range of animals causing alterations such as reproductive disorders and cancer. Detection of these contaminants in water systems is important to protect sensitive environmental sites and reduce the risk of toxins entering the food chain. A modular platform for monitoring toxins in water and food production facilities, using biosensors derived from aquatic organisms, was the main goal of RADAR Project.

  19. Supercritical Carbon Dioxide turbomachinery design for water-cooled Small Modular Reactor application

    International Nuclear Information System (INIS)

    Lee, Jekyoung; Lee, Jeong Ik; Yoon, Ho Joon; Cha, Jae Eun

    2014-01-01

    Highlights: • We described the concept of coupling the S-CO 2 Brayton cycle to the water-cooled SMRs. • We describe a turbomachinery design code called KAISD T MD that can use real gases too. • We suggest changes to the S-CO 2 cycle layout with multiple-independent shafts. • KAIST T MD was used to design the turbomachinery of suggested layout. - Abstract: The Supercritical Carbon Dioxide (S-CO 2 ) Brayton cycle has been gaining attention due to its compactness and high efficiency at moderate turbine inlet temperature. Previous S-CO 2 cycle research works in the field of nuclear engineering were focused on its application to the next generation reactor with higher turbine inlet temperature than the existing conventional water-cooled nuclear power plants. However, it was shown in authors’ previous paper that the advantages of the S-CO 2 Brayton cycle can be also further applied to the water-cooled Small Modular Reactor (SMR) with a success, since SMR requires minimal overall footprint while retaining high performance. One of the major issues in the S-CO 2 Brayton cycle is the selection and design of appropriate turbomachinery for the designed cycle. Because most of the nuclear industry uses incompressible working fluids or ideal gases in the turbomachinery, a more detailed examination of the design of the turbomachinery is required for a power system that uses S-CO 2 as working fluid. This is because the S-CO 2 Brayton cycle high efficiency is the result of the non-ideal variation of properties near the CO 2 critical point. Thus, the major focus of this paper is to suggest the design of the turbomachinery necessary for the S-CO 2 Brayton cycle coupled to water cooled SMRs. For this reason, a S-CO 2 Brayton cycle turbomachinery design methodology was suggested and the suggested design methodology was first tested with the existing experimental data to verify its capability. After then, it was applied to the proposed reference system to demonstrate its

  20. Supercritical Carbon Dioxide turbomachinery design for water-cooled Small Modular Reactor application

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jekyoung, E-mail: leejaeky85@kaist.ac.kr [Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Lee, Jeong Ik, E-mail: jeongiklee@kaist.ac.kr [Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Yoon, Ho Joon, E-mail: hojoon.yoon@kustar.ac.ae [Khalifa University of Science, Technology and Research (KUSTAR), P.O. Box 127788, Abu Dhabi (United Arab Emirates); Cha, Jae Eun, E-mail: jecha@kaeri.re.kr [Korea Atomic Energy Research Institute, 1045 Daedeok-daero, Yuseong-gu, Daejeon 305-353 (Korea, Republic of)

    2014-04-01

    Highlights: • We described the concept of coupling the S-CO{sub 2} Brayton cycle to the water-cooled SMRs. • We describe a turbomachinery design code called KAISD{sub T}MD that can use real gases too. • We suggest changes to the S-CO{sub 2} cycle layout with multiple-independent shafts. • KAIST{sub T}MD was used to design the turbomachinery of suggested layout. - Abstract: The Supercritical Carbon Dioxide (S-CO{sub 2}) Brayton cycle has been gaining attention due to its compactness and high efficiency at moderate turbine inlet temperature. Previous S-CO{sub 2} cycle research works in the field of nuclear engineering were focused on its application to the next generation reactor with higher turbine inlet temperature than the existing conventional water-cooled nuclear power plants. However, it was shown in authors’ previous paper that the advantages of the S-CO{sub 2} Brayton cycle can be also further applied to the water-cooled Small Modular Reactor (SMR) with a success, since SMR requires minimal overall footprint while retaining high performance. One of the major issues in the S-CO{sub 2} Brayton cycle is the selection and design of appropriate turbomachinery for the designed cycle. Because most of the nuclear industry uses incompressible working fluids or ideal gases in the turbomachinery, a more detailed examination of the design of the turbomachinery is required for a power system that uses S-CO{sub 2} as working fluid. This is because the S-CO{sub 2} Brayton cycle high efficiency is the result of the non-ideal variation of properties near the CO{sub 2} critical point. Thus, the major focus of this paper is to suggest the design of the turbomachinery necessary for the S-CO{sub 2} Brayton cycle coupled to water cooled SMRs. For this reason, a S-CO{sub 2} Brayton cycle turbomachinery design methodology was suggested and the suggested design methodology was first tested with the existing experimental data to verify its capability. After then, it was

  1. Chemical shift imaging: a review

    International Nuclear Information System (INIS)

    Brateman, L.

    1986-01-01

    Chemical shift is the phenomenon that is seen when an isotope possessing a nuclear magnetic dipole moment resonates at a spectrum of resonance frequencies in a given magnetic field. These resonance frequencies, or chemical shifts, depend on the chemical environments of particular nuclei. Mapping the spatial distribution of nuclei associated with a particular chemical shift (e.g., hydrogen nuclei associated with water molecules or with lipid groups) is called chemical shift imaging. Several techniques of proton chemical shift imaging that have been applied in vivo are presented, and their clinical findings are reported and summarized. Acquiring high-resolution spectra for large numbers of volume elements in two or three dimensions may be prohibitive because of time constraints, but other methods of imaging lipid of water distributions (i.e., selective excitation, selective saturation, or variations in conventional magnetic resonance imaging pulse sequences) can provide chemical shift information. These techniques require less time, but they lack spectral information. Since fat deposition seen by chemical shift imaging may not be demonstrated by conventional magnetic resonance imaging, certain applications of chemical shift imaging, such as in the determination of fatty liver disease, have greater diagnostic utility than conventional magnetic resonance imaging. Furthermore, edge artifacts caused by chemical shift effects can be eliminated by certain selective methods of data acquisition employed in chemical shift imaging

  2. Small-angle neutron scattering study of micropore collapse in amorphous solid water.

    Science.gov (United States)

    Mitterdorfer, Christian; Bauer, Marion; Youngs, Tristan G A; Bowron, Daniel T; Hill, Catherine R; Fraser, Helen J; Finney, John L; Loerting, Thomas

    2014-08-14

    Vapor-deposited amorphous solid water (ASW) is the most abundant solid molecular material in space, where it plays a direct role in both the formation of more complex chemical species and the aggregation of icy materials in the earliest stages of planet formation. Nevertheless, some of its low temperature physics such as the collapse of the micropore network upon heating are still far from being understood. Here we characterize the nature of the micropores and their collapse using neutron scattering of gram-quantities of D2O-ASW of internal surface areas up to 230 ± 10 m(2) g(-1) prepared at 77 K. The model-free interpretation of the small-angle scattering data suggests micropores, which remain stable up to 120-140 K and then experience a sudden collapse. The exact onset temperature to pore collapse depends on the type of flow conditions employed in the preparation of ASW and, thus, the specific surface area of the initial deposit, whereas the onset of crystallization to cubic ice is unaffected by the flow conditions. Analysis of the small-angle neutron scattering signal using the Guinier-Porod model suggests that a sudden transition from three-dimensional cylindrical pores with 15 Å radius of gyration to two-dimensional lamellae is the mechanism underlying the pore collapse. The rather high temperature of about 120-140 K of micropore collapse and the 3D-to-2D type of the transition unraveled in this study have implications for our understanding of the processing and evolution of ices in various astrophysical environments.

  3. Water-gas shift. An examination of Pt promoted MgO and tetragonal and monoclinic ZrO2 by in situ drifts

    International Nuclear Information System (INIS)

    Chenu, Emilie; Jacobs, Gary; Crawford, Adam C.; Keogh, Robert A.; Patterson, Patricia M.; Sparks, Dennis E.; Davis, Burtron H.

    2005-01-01

    In situ DRIFTS measurements on unpromoted and Pt promoted MgO and ZrO 2 (both tetragonal and monoclinic) indicate that at high H 2 O/CO ratios, where the reaction rate has been reported to be zero order in H 2 O and first order in CO, the mechanism involved in the catalysis of water-gas shift is likely a surface formate mechanism, in agreement with Shido and Iwasawa. Pt was found to catalyze the removal of surface carbonates and to facilitate the generation of active OH groups relative to the unpromoted catalyst. Comparison with Pt/ceria revealed that the OH groups involved in the catalysis of magnesia and zirconia may be those of the bridging variety which occur at defect sites. That is, water dissociated over vacancies to produce bridging OH groups, as observed by infrared spectroscopy. The existence of such an adsorbed species is implied in the zero reaction order for water, where kinetics suggests that the surface should be saturated by an adsorbed water species. The lower extent of vacancy formation for magnesia and zirconia-based materials in comparison with ceria could explain a lower surface population of active bridging OH groups. CO was used as a probe molecule of the reduced centers, as it reacts with bridging OH groups to generate surface formates, a proposed WGS intermediate, and the decomposition of which is proposed to be the rate-limiting step. The trends in formate intensity by CO adsorption and CO conversion in WGS catalytic testing both followed the order: Pt/ceria>Pt/m-zirconia>Pt/t-zirconia>Pt/magnesia. In all cases, a normal kinetic isotope effect was observed in switching from H 2 O to D 2 O, consistent with a link between the rate-limiting step and the decomposition of surface formates, as noted previously by Shido and Iwasawa for Rh/ceria, MgO, and ZnO

  4. Soil water content, runoff and soil loss prediction in a small ungauged agricultural basin in the Mediterranean region using the Soil and Water Assessment Tool

    OpenAIRE

    Ramos Martín, Ma. C. (Ma. Concepción); Martínez Casasnovas, José Antonio

    2015-01-01

    The aim of the present work was to evaluate the possibilities of using sub-basin data for calibration of the Soil and Water Assessment Tool (SWAT) model in a small (46 ha) ungauged basin (i.e. where the water flow is not systematically measured) and its response. This small basin was located in the viticultural Anoia-Penedès region (North-east Spain), which suffers severe soil erosion. The data sources were: daily weather data from an observatory located close to the basin; a detailed soil ma...

  5. Varying the charge of small cations in liquid water: Structural, transport, and thermodynamical properties

    Science.gov (United States)

    Martelli, Fausto; Vuilleumier, Rodolphe; Simonin, Jean-Pierre; Spezia, Riccardo

    2012-10-01

    In this work, we show how increasing the charge of small cations affects the structural, thermodynamical, and dynamical properties of these ions in liquid water. We have studied the case of lanthanoid and actinoid ions, for which we have recently developed accurate polarizable force fields, and the ionic radius is in the 0.995-1.250 Å range, and explored the valency range from 0 to 4+. We found that the ion charge strongly structures the neighboring water molecules and that, in this range of charges, the hydration enthalpies exhibit a quadratic dependence with respect to the charge, in line with the Born model. The diffusion process follows two main regimes: a hydrodynamical regime for neutral or low charges, and a dielectric friction regime for high charges in which the contraction of the ionic radius along the series of elements causes a decrease of the diffusion coefficient. This latter behavior can be qualitatively described by theoretical models, such as the Zwanzig and the solvated ion models. However, these models need be modified in order to obtain agreement with the observed behavior in the full charge range. We have thus modified the solvated ion model by introducing a dependence of the bare ion radius as a function of the ionic charge. Besides agreement between theory and simulation this modification allows one to obtain an empirical unified model. Thus, by analyzing the contributions to the drag coefficient from the viscous and the dielectric terms, we are able to explain the transition from a regime in which the effect of viscosity dominates to one in which dielectric friction governs the motion of ions with radii of ca. 1 Å.

  6. Prevalence of external injuries in small cetaceans in Aruban waters, southern Caribbean.

    Directory of Open Access Journals (Sweden)

    Jolanda A Luksenburg

    Full Text Available Aruba, located close to the coasts of Colombia and Venezuela, is one of the most densely populated islands in the Caribbean and supports a wide range of marine-related socio-economic activities. However, little is known about the impacts of human activities on the marine environment. Injuries in marine mammals can be used to examine interactions with human activities and identify potential threats to the survival of populations. The prevalence of external injuries and tooth rake marks were examined in Atlantic spotted dolphin (Stenella frontalis (n = 179, bottlenose dolphin (Tursiops truncatus (n = 76 and false killer whale (Pseudorca crassidens (n = 71 in Aruban waters using photo identification techniques. Eleven injury categories were defined and linked to either human-related activities or natural causes. All injury categories were observed. In total, 18.7% of all individuals had at least one injury. Almost half (41.7% of the injuries could be attributed to human interactions, of which fishing gear was the most common cause (53.3% followed by propeller hits (13.3%. Major disfigurements were observed in all three species and could be attributed to interactions with fishing gear. The results of this study indicate that fishing gear and propeller hits may pose threats to small and medium-sized cetaceans in Aruban waters. Thus, long-term monitoring of population trends is warranted. Shark-inflicted bite wounds were observed in Atlantic spotted dolphin and bottlenose dolphin. Bite wounds of cookie cutter sharks (Isistius sp. were recorded in all three species, and include the first documented record of a cookie cutter shark bite in Atlantic spotted dolphin. This is one of the few studies which investigates the prevalence of injuries in cetaceans in the Caribbean. Further study is necessary to determine to which extent the injuries observed in Aruba affect the health and survival of local populations.

  7. The Persistence of Informality: Small-Scale Water Providers in Manila’s Post-Privatisation Era

    Directory of Open Access Journals (Sweden)

    Deborah Cheng

    2014-02-01

    Full Text Available This article troubles the notion of a formal-informal dichotomy in urban water provision. Whereas expansion of a water utility typically involves the replacement of informal providers, the experience in Manila demonstrates that the rapid connection of low-income areas actually hinges, in part, on the selective inclusion and exclusion of these smaller actors. In this sense, privatisation has not eliminated small-scale water provision, but has led to the reconfiguration of its usage, blurring the boundaries between formal and informal. By examining the spatial and temporal evolution of small-scale water provision in Manila’s post-privatisation era, I show how certain spaces are seen as less serviceable than others. Critically, small providers working in partnership with the utilities are sanctioned because they supplement the utilities’ operations. The areas in which they work are considered served, factoring into aggregate coverage statistics, even though their terms of service are often less desirable than those of households directly connected to the utilities. In contrast, small providers that operate outside of the utilities’ zones of coverage are considered inferior, to be replaced. The result is a differentiation in informality – one in which the private utilities largely determine modes of access and thus the spatialisation of informal water provision.

  8. Small angle neutron scattering study of the gemini nonionic surfactant in heavy water solutions

    International Nuclear Information System (INIS)

    Rajewska, A

    2012-01-01

    The nonionic gemini surfactant α α'-[2,4,7,9-tetramethyl-5-decyne-4,7diyl]bis[ω hydroxyl-polyoxyethylene] (S-10) was investigated in heavy water solutions only for concentrations: 2.3%, 2.5%,3%, 3.4%, 4% and 5% at temperature 25 C with small angle neutron scattering (SANS) method. All of surfactants solutions were prepared using D 2 O (99.9% deuterated, Prikladnaia Chimia, St. Petersburg, Russia) as a solvent. The nonionic gemini surfactant S-10 was obtained from Air Products and Chemicals, Inc., and used without further purification. All SANS measurements were performed on V-4 SANS spectrometer at BENSC, Berlin (Germany). Neutrons were used in wavelength range of 0.02 - 4 nm - 1. For the measurements quartz cells of were used during experiment. Up to 14 such cells were placed in a holder. Results from experiment was calculated and evaluated with PCG 2.0 program from Graz University (Austria). In the investigated solutions two axis ellipsoidal micelles was observed.

  9. Mathematical model of small water-plane area twin-hull and application in marine simulator

    Science.gov (United States)

    Zhang, Xiufeng; Lyu, Zhenwang; Yin, Yong; Jin, Yicheng

    2013-09-01

    Small water-plane area twin-hull (SWATH) has drawn the attention of many researchers due to its good sea-keeping ability. In this paper, MMG's idea of separation was used to perform SWATH movement modeling and simulation; respectively the forces and moment of SWATH were divided into bare hull, propeller, rudder at the fluid hydrodynamics, etc. Wake coefficient at the propellers which reduces thrust coefficient, and rudder mutual interference forces among the hull and propeller, for the calculation of SWATH, were all considered. The fourth-order Runge-Kutta method of integration was used by solving differential equations, in order to get SWATH's movement states. As an example, a turning test at full speed and full starboard rudder of `Seagull' craft is shown. The simulation results show the SWATH's regular pattern and trend of motion. It verifies the correctness of the mathematical model of the turning movement. The SWATH's mathematical model is applied to marine simulator in order to train the pilots or seamen, or safety assessment for ocean engineering project. Lastly, the full mission navigation simulating system (FMNSS) was determined to be a successful virtual reality technology application sample in the field of navigation simulation.

  10. Preliminary Assessment of Silting and The Quality of Bottom Sediments in A Small Water Reservoir

    Directory of Open Access Journals (Sweden)

    Bąk Łukasz

    2014-07-01

    Full Text Available The aim of this study was to assess the degree of silting and pollution of bottom sediments in a small water reservoir Lubianka situated in Starachowice, Świętokrzyskie Province, with selected heavy metals (Pb, Cr, Cd, Cu, Ni, Zn, Fe, Mn, Hg. Catchment basin of the reservoir is forested in 92%. Other parts are covered by estates of detached houses, barren lands and green areas. Bathymetric measurements and analyses of trace elements in bottom sediments were made in 2012. After 28 years of exploitation, reservoir's basin accumulated 43 thousand cubic metres of sediments i.e. 4.7% of its initial volume. Mean annual silting rate was 0.17%. Due to the content of copper and chromium, bottom sediments were classified to the II category (sediments of average pollution according to geochemical standards. Concentrations of Pb, Cd and Hg in all analysed samples were below geochemical background. In a sample collected at the inlet to the reservoir, the TEL index for chromium was exceeded by 25.6%. In other samples the threshold values of the TEL and PEL indices were not exceeded.

  11. Water and salt balance modelling to predict the effects of land-use changes in forested catchments. 1. Small catchment water balance model

    Science.gov (United States)

    Sivapalan, Murugesu; Ruprecht, John K.; Viney, Neil R.

    1996-03-01

    A long-term water balance model has been developed to predict the hydrological effects of land-use change (especially forest clearing) in small experimental catchments in the south-west of Western Australia. This small catchment model has been used as the building block for the development of a large catchment-scale model, and has also formed the basis for a coupled water and salt balance model, developed to predict the changes in stream salinity resulting from land-use and climate change. The application of the coupled salt and water balance model to predict stream salinities in two small experimental catchments, and the application of the large catchment-scale model to predict changes in water yield in a medium-sized catchment that is being mined for bauxite, are presented in Parts 2 and 3, respectively, of this series of papers.The small catchment model has been designed as a simple, robust, conceptually based model of the basic daily water balance fluxes in forested catchments. The responses of the catchment to rainfall and pan evaporation are conceptualized in terms of three interdependent subsurface stores A, B and F. Store A depicts a near-stream perched aquifer system; B represents a deeper, permanent groundwater system; and F is an intermediate, unsaturated infiltration store. The responses of these stores are characterized by a set of constitutive relations which involves a number of conceptual parameters. These parameters are estimated by calibration by comparing observed and predicted runoff. The model has performed very well in simulations carried out on Salmon and Wights, two small experimental catchments in the Collie River basin in south-west Western Australia. The results from the application of the model to these small catchments are presented in this paper.

  12. Assessment of irrigation performance: contribution to improve water management in a small catchment in the Brazilian savannas

    Science.gov (United States)

    Rodrigues, Lineu; Marioti, Juliana; Steenhuis, Tammo; Wallender, Wesley

    2010-05-01

    Irrigated agriculture is the major consumer of surface water in Brazil using over 70% of the total supply. Due to the growing competition for water among different sectors of the economy, sustainable water use can only be achieved by decreasing the portion of water used by the irrigated agriculture. Thus, in order to maintain yield, farmers need to irrigate more efficiently. There is little known on irrigation efficiency in Brazil. Therefore a study was carried out in the Buriti Vermelho basin to assess the irrigation performance of existing system. The experimental basin has a drainage area of 940 hectares and is located in the eastern part of the Federal District, in the Brazilian savanna region. Agriculture is the main activity. There is a dominance of red latosols. Several types of land use and crop cover are encountered in the basin. Conflicts among farmers for water are increasing. As water, in quality and quantity, is crucial to maintain the livelihood of the population in the basin, concern about risk of water lack due to climatic and land use change is in place. Once irrigation is the main water user in the basin, to increase water availability and reduce conflicts a water resource management plan has to be established. For this purpose, irrigation system performance has to be understood. The objective of this work was to assess the performance and the management of irrigation (small and big) that has been carried out by farmers in the Buriti Vermelho experimental watershed. A survey undertaken in 2007 was used to identify the irrigation systems in the basin. It was verified that irrigation is practiced by both small (area up to 6 hectare) and big farmers. Small farmers usually crop limes and vegetables and use micro-irrigation, drip, sprinkler, guns or furrow to irrigate them. Big farmers plant annual crops and use center pivot as irrigation system. In this first assessment 13 irrigation systems were evaluated: five conventional sprinklers, four drip

  13. Small Water Enterprise in Rural Rwanda: Business Development and Year-One Performance Evaluation of Nine Water Kiosks at Health Care Facilities

    Directory of Open Access Journals (Sweden)

    Alexandra Huttinger

    2017-12-01

    Full Text Available Small water enterprises (SWEs have lower capital expenditures than centralized systems, offering decentralized solutions for rural markets. This study evaluated SWEs in rural Rwanda, where nine health care facilities (HCF owned and operated water kiosks supplying water from onsite water treatment systems (WTS. SWEs were monitored for 12 months. Spearman’s Rank Correlation Coefficient (rs was used to evaluate correlations between demand for kiosk water and community characteristics, and between kiosk profit and factors influencing the cost model. On average, SWEs distributed 15,300 L/month. One SWE ran at a loss, four had profit margins of ≤10% and four had profit margins of 45–75%. Factors influencing SWE performance were intermittent water supply (87% of SWE closures were due to water shortage, consumer demand (demand was high where populations already used improved water sources (rs = 0.81, p = 0.02, price sensitivity (demand was lower where SWEs had high prices (rs = −0.65, p = 0.08, and production cost (water utility tariffs negatively impacted SWE profits (rs = −0.52, p < 0.01. Sustainability was more favorable in circumstances where recovery of capital expenditures was not expected, and the demand for treated water was sufficient to fund operational expenditures. Future research is needed to assess the extent to which kiosk revenue can support ongoing operational costs of WTS and kiosks both at HCF and in other contexts.

  14. Pesticide volatilization from small surface waters : rationale of a new parameterization for TOXSWA

    NARCIS (Netherlands)

    Jacobs, C.M.J.; Adriaanse, P.I.

    2012-01-01

    In the TOXSWA (TOXic substances in Surface WAters) model volatilization of pesticides from surface water is computed because it may be an important component of the mass balance of pesticides in water bodies. Here, we briefly review the physics of air-water gas exchange relevant in this context. A

  15. Thigh muscle segmentation of chemical shift encoding-based water-fat magnetic resonance images: The reference database MyoSegmenTUM.

    Directory of Open Access Journals (Sweden)

    Sarah Schlaeger

    Full Text Available Magnetic resonance imaging (MRI can non-invasively assess muscle anatomy, exercise effects and pathologies with different underlying causes such as neuromuscular diseases (NMD. Quantitative MRI including fat fraction mapping using chemical shift encoding-based water-fat MRI has emerged for reliable determination of muscle volume and fat composition. The data analysis of water-fat images requires segmentation of the different muscles which has been mainly performed manually in the past and is a very time consuming process, currently limiting the clinical applicability. An automatization of the segmentation process would lead to a more time-efficient analysis. In the present work, the manually segmented thigh magnetic resonance imaging database MyoSegmenTUM is presented. It hosts water-fat MR images of both thighs of 15 healthy subjects and 4 patients with NMD with a voxel size of 3.2x2x4 mm3 with the corresponding segmentation masks for four functional muscle groups: quadriceps femoris, sartorius, gracilis, hamstrings. The database is freely accessible online at https://osf.io/svwa7/?view_only=c2c980c17b3a40fca35d088a3cdd83e2. The database is mainly meant as ground truth which can be used as training and test dataset for automatic muscle segmentation algorithms. The segmentation allows extraction of muscle cross sectional area (CSA and volume. Proton density fat fraction (PDFF of the defined muscle groups from the corresponding images and quadriceps muscle strength measurements/neurological muscle strength rating can be used for benchmarking purposes.

  16. Shift in the microbial ecology of a hospital hot water system following the introduction of an on-site monochloramine disinfection system.

    Directory of Open Access Journals (Sweden)

    Julianne L Baron

    Full Text Available Drinking water distribution systems, including premise plumbing, contain a diverse microbiological community that may include opportunistic pathogens. On-site supplemental disinfection systems have been proposed as a control method for opportunistic pathogens in premise plumbing. The majority of on-site disinfection systems to date have been installed in hospitals due to the high concentration of opportunistic pathogen susceptible occupants. The installation of on-site supplemental disinfection systems in hospitals allows for evaluation of the impact of on-site disinfection systems on drinking water system microbial ecology prior to widespread application. This study evaluated the impact of supplemental monochloramine on the microbial ecology of a hospital's hot water system. Samples were taken three months and immediately prior to monochloramine treatment and monthly for the first six months of treatment, and all samples were subjected to high throughput Illumina 16S rRNA region sequencing. The microbial community composition of monochloramine treated samples was dramatically different than the baseline months. There was an immediate shift towards decreased relative abundance of Betaproteobacteria, and increased relative abundance of Firmicutes, Alphaproteobacteria, Gammaproteobacteria, Cyanobacteria and Actinobacteria. Following treatment, microbial populations grouped by sampling location rather than sampling time. Over the course of treatment the relative abundance of certain genera containing opportunistic pathogens and genera containing denitrifying bacteria increased. The results demonstrate the driving influence of supplemental disinfection on premise plumbing microbial ecology and suggest the value of further investigation into the overall effects of premise plumbing disinfection strategies on microbial ecology and not solely specific target microorganisms.

  17. Integration of Methane Steam Reforming and Water Gas Shift Reaction in a Pd/Au/Pd-Based Catalytic Membrane Reactor for Process Intensification

    Directory of Open Access Journals (Sweden)

    Bernardo Castro-Dominguez

    2016-09-01

    Full Text Available Palladium-based catalytic membrane reactors (CMRs effectively remove H2 to induce higher conversions in methane steam reforming (MSR and water-gas-shift reactions (WGS. Within such a context, this work evaluates the technical performance of a novel CMR, which utilizes two catalysts in series, rather than one. In the process system under consideration, the first catalyst, confined within the shell side of the reactor, reforms methane with water yielding H2, CO and CO2. After reforming is completed, a second catalyst, positioned in series, reacts with CO and water through the WGS reaction yielding pure H2O, CO2 and H2. A tubular composite asymmetric Pd/Au/Pd membrane is situated throughout the reactor to continuously remove the produced H2 and induce higher methane and CO conversions while yielding ultrapure H2 and compressed CO2 ready for dehydration. Experimental results involving (i a conventional packed bed reactor packed (PBR for MSR, (ii a PBR with five layers of two catalysts in series and (iii a CMR with two layers of two catalysts in series are comparatively assessed and thoroughly characterized. Furthermore, a comprehensive 2D computational fluid dynamics (CFD model was developed to explore further the features of the proposed configuration. The reaction was studied at different process intensification-relevant conditions, such as space velocities, temperatures, pressures and initial feed gas composition. Finally, it is demonstrated that the above CMR module, which was operated for 600 h, displays quite high H2 permeance and purity, high CH4 conversion levels and reduced CO yields.

  18. Workshop in a Box: Sustainable Management of Rural and Small Water and Wastewater Systems Workshops

    Science.gov (United States)

    A resource to help rural and small systems and communities to conduct workshops, either for an individual system or for a group of systems, based on the Rural and Small Systems Guidebook to Sustainable Utility Management.

  19. A closed cabinet system with water flushers and a blender for breeding small animal administered 3HHO

    International Nuclear Information System (INIS)

    Yamamoto, O.; Takeoka, S.; Tsujimura, T.; Kuroda, T.; Iwashita, T.; Amme, T.

    1984-01-01

    A closed cabinet system was developed for breeding small animals administered 3 HHO. 3 HHO vapor released from the animals in the chamber was absorbed with water in a water bubbler. Feces and urine which were washed out with water were ground in a blender, diluted, and then released. With this cabinet system we were successful in safely breeding mice even given a total single injection of 15.5 GBq (420 mCi) of 3 HHO without storing the 3 H-slops for a long time and without any significant leakage of 3 H from the cabinet. (author)

  20. Assessment of small-scale integrated water vapour variability during HOPE

    Science.gov (United States)

    Steinke, S.; Eikenberg, S.; Löhnert, U.; Dick, G.; Klocke, D.; Di Girolamo, P.; Crewell, S.

    2015-03-01

    The spatio-temporal variability of integrated water vapour (IWV) on small scales of less than 10 km and hours is assessed with data from the 2 months of the High Definition Clouds and Precipitation for advancing Climate Prediction (HD(CP)2) Observational Prototype Experiment (HOPE). The statistical intercomparison of the unique set of observations during HOPE (microwave radiometer (MWR), Global Positioning System (GPS), sun photometer, radiosondes, Raman lidar, infrared and near-infrared Moderate Resolution Imaging Spectroradiometer (MODIS) on the satellites Aqua and Terra) measuring close together reveals a good agreement in terms of random differences (standard deviation ≤1 kg m-2) and correlation coefficient (≥ 0.98). The exception is MODIS, which appears to suffer from insufficient cloud filtering. For a case study during HOPE featuring a typical boundary layer development, the IWV variability in time and space on scales of less than 10 km and less than 1 h is investigated in detail. For this purpose, the measurements are complemented by simulations with the novel ICOsahedral Nonhydrostatic modelling framework (ICON), which for this study has a horizontal resolution of 156 m. These runs show that differences in space of 3-4 km or time of 10-15 min induce IWV variabilities on the order of 0.4 kg m-2. This model finding is confirmed by observed time series from two MWRs approximately 3 km apart with a comparable temporal resolution of a few seconds. Standard deviations of IWV derived from MWR measurements reveal a high variability (> 1 kg m-2) even at very short time scales of a few minutes. These cannot be captured by the temporally lower-resolved instruments and by operational numerical weather prediction models such as COSMO-DE (an application of the Consortium for Small-scale Modelling covering Germany) of Deutscher Wetterdienst, which is included in the comparison. However, for time scales larger than 1 h, a sampling resolution of 15 min is

  1. Shifting Sugars and Shifting Paradigms

    Science.gov (United States)

    Siegal, Mark L.

    2015-01-01

    No organism lives in a constant environment. Based on classical studies in molecular biology, many have viewed microbes as following strict rules for shifting their metabolic activities when prevailing conditions change. For example, students learn that the bacterium Escherichia coli makes proteins for digesting lactose only when lactose is available and glucose, a better sugar, is not. However, recent studies, including three PLOS Biology papers examining sugar utilization in the budding yeast Saccharomyces cerevisiae, show that considerable heterogeneity in response to complex environments exists within and between populations. These results join similar recent results in other organisms that suggest that microbial populations anticipate predictable environmental changes and hedge their bets against unpredictable ones. The classical view therefore represents but one special case in a range of evolutionary adaptations to environmental changes that all organisms face. PMID:25688600

  2. Shifting sugars and shifting paradigms.

    Directory of Open Access Journals (Sweden)

    Mark L Siegal

    2015-02-01

    Full Text Available No organism lives in a constant environment. Based on classical studies in molecular biology, many have viewed microbes as following strict rules for shifting their metabolic activities when prevailing conditions change. For example, students learn that the bacterium Escherichia coli makes proteins for digesting lactose only when lactose is available and glucose, a better sugar, is not. However, recent studies, including three PLOS Biology papers examining sugar utilization in the budding yeast Saccharomyces cerevisiae, show that considerable heterogeneity in response to complex environments exists within and between populations. These results join similar recent results in other organisms that suggest that microbial populations anticipate predictable environmental changes and hedge their bets against unpredictable ones. The classical view therefore represents but one special case in a range of evolutionary adaptations to environmental changes that all organisms face.

  3. Thermal performance of small solar domestic hot water systems in theory, in the laboratory and in practice

    DEFF Research Database (Denmark)

    Andersen, Elsa

    1998-01-01

    for poor thermal performances of systems tested in practice are given. Based on theoretical calculations the negative impact on the thermal performance, due to a large number of different parameter variations are given. Recommendations for future developments of small solar domestic hot water systems...

  4. Using System Dynamics to Explore the Water Supply and Demand Dilemmas of a Small South African Municipality

    NARCIS (Netherlands)

    Clifford Holmes, J.K.; Slinger, J.H.; Musango, J.K.; Brent, A.C.; Palmer, C.G.

    2014-01-01

    This paper explores the challenges faced by small municipalities in providing water services in a developing-world context of increasing urban demand. The paper uses a case study of the Sundays River Valley Municipality (SRVM) in South Africa. The municipality faces multiple dilemmas in reconciling

  5. 40 CFR 122.30 - What are the objectives of the storm water regulations for small MS4s?

    Science.gov (United States)

    2010-07-01

    ... DISCHARGE ELIMINATION SYSTEM Permit Application and Special NPDES Program Requirements § 122.30 What are the... 40 Protection of Environment 21 2010-07-01 2010-07-01 false What are the objectives of the storm water regulations for small MS4s? 122.30 Section 122.30 Protection of Environment ENVIRONMENTAL...

  6. Ceramic Filter for Small System Drinking Water Treatment: Evaluation of Membrane Pore Size and Importance of Integrity Monitoring

    Science.gov (United States)

    Ceramic filtration has recently been identified as a promising technology for drinking water treatment in households and small communities. This paper summarizes the results of a pilot-scale study conducted at the U.S. Environmental Protection Agency’s (EPA’s) Test & Evaluation ...

  7. Dealing with water deficit in Atta ant colonies: large ants scout for water while small ants transport it

    Directory of Open Access Journals (Sweden)

    Antonio Carlos Da-Silva

    2012-07-01

    Leafcutter ants (Atta sexdens rubropilosa (Forel 1908 have an elaborate social organization, complete with caste divisions. Activities carried out by specialist groups contribute to the overall success and survival of the colony when it is confronted with environmental challenges such as dehydration. Ants detect variations in humidity inside the nest and react by activating several types of behavior that enhance water uptake and decrease water loss, but it is not clear whether or not a single caste collects water regardless of the cost of bringing this resource back to the colony. Accordingly, we investigated water collection activities in three colonies of Atta sexdens rubropilosa experimentally exposed to water stress. Specifically, we analyzed whether or not the same ant caste foraged for water, regardless of the absolute energetic cost (distance of transporting this resource back to the colony. Our experimental design offered water sources at 0 m, 1 m and 10 m from the nest. We studied the body size of ants near the water sources from the initial offer of water (time  =  0 to 120 min, and tested for specialization. We observed a reduction in the average size and variance of ants that corroborated the specialization hypothesis. Although the temporal course of specialization changed with distance, the final outcome was similar among distances. Thus, we conclude that, for this species, a specialist (our use of the word “specialist” does not mean exclusive task force is responsible for collecting water, regardless of the cost of transporting water back to the colony.

  8. Small drains, big problems: the impact of dry weather runoff on shoreline water quality at enclosed beaches.

    Science.gov (United States)

    Rippy, Megan A; Stein, Robert; Sanders, Brett F; Davis, Kristen; McLaughlin, Karen; Skinner, John F; Kappeler, John; Grant, Stanley B

    2014-12-16

    Enclosed beaches along urban coastlines are frequent hot spots of fecal indicator bacteria (FIB) pollution. In this paper we present field measurements and modeling studies aimed at evaluating the impact of small storm drains on FIB pollution at enclosed beaches in Newport Bay, the second largest tidal embayment in Southern California. Our results suggest that small drains have a disproportionate impact on enclosed beach water quality for five reasons: (1) dry weather surface flows (primarily from overirrigation of lawns and ornamental plants) harbor FIB at concentrations exceeding recreational water quality criteria; (2) small drains can trap dry weather runoff during high tide, and then release it in a bolus during the falling tide when drainpipe outlets are exposed; (3) nearshore turbulence is low (turbulent diffusivities approximately 10(-3) m(2) s(-1)), limiting dilution of FIB and other runoff-associated pollutants once they enter the bay; (4) once in the bay, runoff can form buoyant plumes that further limit vertical mixing and dilution; and (5) local winds can force buoyant runoff plumes back against the shoreline, where water depth is minimal and human contact likely. Outdoor water conservation and urban retrofits that minimize the volume of dry and wet weather runoff entering the local storm drain system may be the best option for improving beach water quality in Newport Bay and other urban-impacted enclosed beaches.

  9. Small Water Enterprise in Rural Rwanda: Business Development and Year-One Performance Evaluation of Nine Water Kiosks at Health Care Facilities.

    Science.gov (United States)

    Huttinger, Alexandra; Brunson, Laura; Moe, Christine L; Roha, Kristin; Ngirimpuhwe, Providence; Mfura, Leodomir; Kayigamba, Felix; Ciza, Philbert; Dreibelbis, Robert

    2017-12-16

    Small water enterprises (SWEs) have lower capital expenditures than centralized systems, offering decentralized solutions for rural markets. This study evaluated SWEs in rural Rwanda, where nine health care facilities (HCF) owned and operated water kiosks supplying water from onsite water treatment systems (WTS). SWEs were monitored for 12 months. Spearman's Rank Correlation Coefficient (r s ) was used to evaluate correlations between demand for kiosk water and community characteristics, and between kiosk profit and factors influencing the cost model. On average, SWEs distributed 15,300 L/month. One SWE ran at a loss, four had profit margins of ≤10% and four had profit margins of 45-75%. Factors influencing SWE performance were intermittent water supply (87% of SWE closures were due to water shortage), consumer demand (demand was high where populations already used improved water sources (r s = 0.81, p = 0.02)), price sensitivity (demand was lower where SWEs had high prices (r s = -0.65, p = 0.08)), and production cost (water utility tariffs negatively impacted SWE profits (r s = -0.52, p Future research is needed to assess the extent to which kiosk revenue can support ongoing operational costs of WTS and kiosks both at HCF and in other contexts.

  10. Assessment of water consumptions in small mediterranean islands' primary schools by means of a long-term online monitoring

    Science.gov (United States)

    Ferraris, Marco; De Gisi, Sabino; Farina, Roberto

    2017-10-01

    A key challenge of our society is improving schools through the sustainable use of resources especially in countries at risk of desertification. The estimation of water consumption is the starting point for the correct dimensioning of water recovery systems. To date, unlike the energy sector, there is a lack of scientific information regarding water consumption in school buildings. Available data refer roughly to indirect estimates by means of utility bills and therefore no information on the role of water leakage in the internal network of the school is provided. In this context, the aim of the work was to define and implement an on-line monitoring system for the assessment of water consumptions in a small Mediterranean island primary school to achieve the following sub-goals: (1) definition of water consumption profile considering teaching activities and secretarial work; (2) direct assessment of water consumptions and leakages and, (3) quantification of the behaviour parameters. The installed monitoring system consisted of 33 water metres (3.24 persons per water metre) equipped with sensors set on 1-L impulse signal and connected to a data logging system. Results showed consumptions in the range 13.6-14.2 L/student/day and leakage equal to 54.8 % of the total water consumptions. Considering the behavioural parameters, the consumptions related to toilet flushing, personal, and building cleaning were, respectively, 54, 43 and 3 % of the total water ones. Finally, the obtained results could be used for dimensioning the most suitable water recovery strategies at school level such as grey water or rainwater recovery systems.

  11. A Small-Scale and Low-Cost Apparatus for the Electrolysis of Water

    Science.gov (United States)

    Eggeen, Per-Odd; Kvittingen, Lise

    2004-01-01

    The construction of two simple, inexpensive apparatuses that clearly show the electrolysis of water are described. Traditionally the electrolysis of water is conducted in a Hofmann apparatus which is expensive and fragile.

  12. The Volta Basin Water Allocation System: assessing the impact of small-scale reservoir development on the water resources of the Volta basin, West Africa

    Directory of Open Access Journals (Sweden)

    R. Kasei

    2009-08-01

    Full Text Available In the Volta Basin, infrastructure watershed development with respect to the impact of climate conditions is hotly debated due to the lack of adequate tools to model the consequences of such development. There is an ongoing debate on the impact of further development of small and medium scale reservoirs on the water level of Lake Volta, which is essential for hydropower generation at the Akosombo power plant. The GLOWA Volta Project (GVP has developed a Volta Basin Water Allocation System (VB-WAS, a decision support tool that allows assessing the impact of infrastructure development in the basin on the availability of current and future water resources, given the current or future climate conditions. The simulated historic and future discharge time series of the joint climate-hydrological modeling approach (MM5/WaSiM-ETH serve as input data for a river basin management model (MIKE BASIN. MIKE BASIN uses a network approach, and allows fast simulations of water allocation and of the consequences of different development scenarios on the available water resources. The impact of the expansion of small and medium scale reservoirs on the stored volume of Lake Volta has been quantified and assessed in comparison with the impact of climate variability on the water resources of the basin.

  13. Recovery of water from cacti for use in small farming communities

    African Journals Online (AJOL)

    sunny t

    2013-10-02

    Oct 2, 2013 ... Full Length Research Paper. Recovery of water ... 35°C and a pH of 5.5. This relates to a yield of 550 L of water per ton of cacti, making chemical water .... recovery of juice from pineapples by up to 14%. Demir et al. (2001) did ...

  14. Virus contamination from operation and maintenance practices in small drinking water distribution systems

    Science.gov (United States)

    We tested the association of common events in drinking water distribution systems with contamination of household tap water with human enteric viruses. Viruses were enumerated by qPCR in the tap water of 14 municipal systems that use non-disinfected groundwater. Ultra-violet disinfection was install...

  15. Changes in vegetative communities and water table dynamics following timber harvesting in small headwater streams

    Science.gov (United States)

    B. Choi; J.C. Dewey; J. A. Hatten; A.W. Ezell; Z. Fan

    2012-01-01

    In order to better understand the relationship between vegetation communities and water table in the uppermost portions (ephemeral–intermittent streams) of headwater systems, seasonal plot-based field characterizations of vegetation were used in conjunction with monthly water table measurements. Vegetation, soils, and water table data were examined to determine...

  16. Shift of the circumstances in effluent pollutant loads and water pollution in the Seto Inland Sea; Setonaikai ni okeru odaku fukaryo to suishitsu no hensen

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, T. [Hiroshima Prefectural Institute of Public Health and Environment, Hiroshima (Japan); Komai, Y. [Hyogo Prefectural Institute of Environmental Science, Kobe (Japan); Koyama, T. [Wakayama Prefectural Research Center of Environment and Public Health, Wakayama (Japan); Nagafuchi, O. [Fukuoka Institute of Health and Environment Science, Fukuoka (Japan); Hino, Y. [Kagawa Prefecture Environmental Research Center, Kagawa (Japan); Murakami, K. [Okayama Prefectural Institute for Environmental and Public Health, Okayama (Japan)

    1998-11-10

    The relationship between the shift of the amount of effluent pollutant loads and the quality of water in and after the 1970s is studied for the verification of the effect of wastewater control and pollution measures for the Seto Inland Sea. The pollution loads are analyzed using the population, sewerage system diffusion rate, industrial production amount, number of farm animals, etc., gathered from existing data, and the quality of water is analyzed using the surface layer data collected at 124 sites. Although population as the source of pollutant loads has enlarged, the enlargement does not bring about a significant change in the loads, this partly due to the diffusion of sewerage systems. The rates of reduction in the 1979-1994 period of COD (chemical oxygen demand), T-N (total nitrogen), and T-P (total phosphorus) are 25.2%, 5.3%, and 30.3%, respectively. COD has returned to the previous level, but transparency has turned poorer. T-N and T-P worsened in the 1985-1989 period, and have not yet returned to the levels of 1980-1984. Pollution is in progress in Osaka Bay, Hiroshima Bay, and some others. In some sea areas, transparency is improving, with COD and Chl.a on the increase. From the nutrient salt and Chl.a scatter diagrams, the potential of algal growth relative to the concentration of nutrient salts may be estimated. Organic pollution is affected by algal growth. The organic matters produced in the inland sea are approximately 20 times as much as the organic matters produced on land. 18 refs., 11 figs., 2 tabs.

  17. Influence of convection on the diffusive transport and sieving of water and small solutes across the peritoneal membrane.

    Science.gov (United States)

    Asghar, Ramzana B; Diskin, Ann M; Spanel, Patrik; Smith, David; Davies, Simon J

    2005-02-01

    The three-pore model of peritoneal membrane physiology predicts sieving of small solutes as a result of the presence of a water-exclusive pathway. The purpose of this study was to measure the diffusive and convective components of small solute transport, including water, under differing convection. Triplicate studies were performed in eight stable individuals using 2-L exchanges of bicarbonate buffered 1.36 or 3.86% glucose and icodextrin. Diffusion of water was estimated by establishing an artificial gradient of deuterated water (HDO) between blood/body water and the dialysate. (125)RISA (radio-iodinated serum albumin) was used as an intraperitoneal volume marker to determine the net ultrafiltration and reabsorption of fluid. The mass transfer area coefficient (MTAC) for HDO and solutes was estimated using the Garred and Waniewski equations. The MTAC of HDO calculated for 1.36% glucose and icodextrin were similar (36.8 versus 39.7 ml/min; P = 0.3), whereas for other solutes, values obtained using icodextrin were consistently higher (P solutes is a reflection of their sieving. The increase in the MTAC of water and urea associated with an increase in convection is most likely due to increased mixing within the interstitium.

  18. [Monitoring microbiological safety of small systems of water distribution. Comparison of two sampling programs in a town in central Italy].

    Science.gov (United States)

    Papini, Paolo; Faustini, Annunziata; Manganello, Rosa; Borzacchi, Giancarlo; Spera, Domenico; Perucci, Carlo A

    2005-01-01

    To determine the frequency of sampling in small water distribution systems (distribution. We carried out two sampling programs to monitor the water distribution system in a town in Central Italy between July and September 1992; the Poisson distribution assumption implied 4 water samples, the assumption of negative binomial distribution implied 21 samples. Coliform organisms were used as indicators of water safety. The network consisted of two pipe rings and two wells fed by the same water source. The number of summer customers varied considerably from 3,000 to 20,000. The mean density was 2.33 coliforms/100 ml (sd= 5.29) for 21 samples and 3 coliforms/100 ml (sd= 6) for four samples. However the hypothesis of homogeneity was rejected (p-value samples (beta= 0.24) than with 21 (beta= 0.05). For this small network, determining the samples' size according to heterogeneity hypothesis strengthens the statement that water is drinkable compared with homogeneity assumption.

  19. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gokhan [TDA Research, Inc., Wheat Ridge, CO (United States)

    2013-02-15

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H2S, NH3, HCN, AsH3, PH3, HCl, NaCl, KCl, AS3, NH4NO3, NH4OH, KNO3, HBr, HF, and HNO3) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts.

  20. Synthesis of oxocarbon-encapsulated gold nanoparticles with blue-shifted localized surface plasmon resonance by pulsed laser ablation in water with CO2 absorbers

    Science.gov (United States)

    Del Rosso, T.; Rey, N. A.; Rosado, T.; Landi, S.; Larrude, D. G.; Romani, E. C.; Freire Junior, F. L.; Quinteiro, S. M.; Cremona, M.; Aucelio, R. Q.; Margheri, G.; Pandoli, O.

    2016-06-01

    Colloidal suspensions of oxocarbon-encapsulated gold nanoparticles have been synthesized in a one-step procedure by pulsed-laser ablation (PLA) at 532 nm of a solid gold target placed in aqueous solution containing CO2 absorbers, but without any stabilizing agent. Multi-wavelength surface enhanced Raman spectroscopy allows the identification of adsorbed amorphous carbon and graphite, Au-carbonyl, Au coordinated CO2-derived bicarbonates/carbonates and hydroxyl groups around the AuNPs core. Scanning electron microscopy, energy dispersive x-ray analysis and high resolution transmission electron microscopy highlight the organic shell structure around the crystalline metal core. The stability of the colloidal solution of nanocomposites (NCs) seems to be driven by solvation forces and is achieved only in neutral or basic pH using monovalent hydroxide counter-ions (NaOH, KOH). The NCs are characterized by a blue shift of the localized surface plasmon resonance (LSPR) band typical of metal-ligand stabilization by terminal π-back bonding, attributed to a core charging effect caused by Au-carbonyls. Total organic carbon measurements detect the final content of organic carbon in the colloidal solution of NCs that is about six times higher than the value of the water solution used to perform PLA. The colloidal dispersions of NCs are stable for months and are applied as analytical probes in amino glycoside antibiotic LSPR based sensing.

  1. Multi isotopic characterization (Li-Cu-Zn-Pb) of waste waters pollution in a small watershed (Loire River basin, France)

    Science.gov (United States)

    Millot, R.; Desaulty, A. M.; Perret, S.; Bourrain, X.

    2016-12-01

    The goal of this study is to use multi-isotopic signature to track the pollution in surface waters, and to understand the complex processes causing the metals mobilization and transport in the environment. In the present study, we investigate waste water releases from a hospital water treatment plant and its potential impact in a small river basin near Orléans in France (Egoutier watershed: 15 km²and 5 km long). We decided to monitor this small watershed which is poorly urbanized in the Loire river basin. Its spring is located in a pristine area (forested area), while it is only impacted some kilometers further by the releases rich in metals coming from a hospital water treatment plant. A sampling of these liquid effluents as well as dissolved load and sediment from upstream to downstream was realized and their concentrations and isotopic data were determined. Isotopic ratios were measured using a MC-ICP-MS at BRGM, after a specific protocol of purification for each isotopic systematics. Lithium isotopic compositions are rather homogeneous in river waters along the main course of the stream. The waste water signal is very different from the natural background with significant heavy lithium contribution (high δ7Li). Lead isotopic compositions are rather homogenous in river waters and sediments with values close to geologic background. For Zn, the sediments with high concentrations and depleted isotopic compositions (low δ66Zn), typical of an anthropic pollution, are strongly impacted. The analyses of Cu isotopes in sediments show the impact of waster waters, but also isotopic fractionations due to redox processes in the watershed. To better understand these processes controlling the release of metals in water, sequential extractions on sediments are in progress under laboratory conditions and will provide important constraints for metal distribution in this river basin.

  2. Counterion influence on chemical shifts in strychnine salts

    Energy Technology Data Exchange (ETDEWEB)

    Metaxas, Athena E.; Cort, John R.

    2013-05-01

    The highly toxic plant alkaloid strychnine is often isolated in the form of the anion salt of its protonated tertiary amine. Here we characterize the relative influence of different counterions on 1H and 13C chemical shifts in several strychnine salts in D2O, methanol-d4 (CD3OD) and chloroform-d (CDCl3) solvents. In organic solvents, but not in water, substantial variation in chemical shifts of protons near the tertiary amine was observed among different salts. These secondary shifts reveal differences in the way each anion influences electronic structure within the protonated amine. The distributions of secondary shifts allow salts to be easily distinguished from each other as well as from the free base form. The observed effects are much greater in organic solvents than in water. Slight concentration-dependence in chemical shifts of some protons near the amine was observed for two salts in CDCl3, but this effect is small compared to the influence of the counterion. Distinct chemical shifts in different salt forms of the same compound may be useful as chemical forensic signatures for source attribution and sample matching of alkaloids such as strychnine and possibly other organic acid and base salts.

  3. Establishment of sustainable water supply system in small islands through rainwater harvesting (RWH): case study of Guja-do.

    Science.gov (United States)

    Han, Mooyoung; Ki, Jaehong

    2010-01-01

    Many islands in Korea have problems related to water source security and supply. In particular, the water supply condition is worse in small islands which are remote from the mainland. A couple of alternatives are developed and suggested to supply water to islands including water hauling, groundwater extraction, and desalination. However, these alternatives require much energy, cost, and concern in installation and operation. Rainwater harvesting is a sustainable option that supplies water with low energy and cost. However, lack of practical or comprehensive studies on rainwater harvesting systems in these regions hinders the promotion of the system. Therefore, this research examines defects of current RWH systems on an existing island, Guja-do, and provides technical suggestions in quantitative and qualitative aspects. A simple system design modification and expansion of system capacity using empty space such as a wharf structure can satisfy both the qualitative and the quantitative water demand of the island. Since rainwater harvesting is estimated to be a feasible water supply option under the Korean climate, which is an unfavorable condition for rainwater harvesting, implies a high potential applicability of rainwater harvesting technology to other regions over the world suffering from water shortage.

  4. Modeling Air Temperature/Water Temperature Relations Along a Small Mountain Stream Under Increasing Urban Influence

    Science.gov (United States)

    Fedders, E. R.; Anderson, W. P., Jr.; Hengst, A. M.; Gu, C.

    2017-12-01

    Boone Creek is a headwater stream of low to moderate gradient located in Boone, North Carolina, USA. Total impervious surface coverage in the 5.2 km2 catchment drained by the 1.9 km study reach increases from 13.4% in the upstream half of the reach to 24.3% in the downstream half. Other markers of urbanization, including culverting, lack of riparian shade vegetation, and bank armoring also increase downstream. Previous studies have shown the stream to be prone to temperature surges on short timescales (minutes to hours) caused by summer runoff from the urban hardscaping. This study investigates the effects of urbanization on the stream's thermal regime at daily to yearly timescales. To do this, we developed an analytical model of daily average stream temperatures based on daily average air temperatures. We utilized a two-part model comprising annual and biannual components and a daily component consisting of a 3rd-order Markov process in order to fit the thermal dynamics of our small, gaining stream. Optimizing this model at each of our study sites in each studied year (78 total site-years of data) yielded annual thermal exchange coefficients (K) for each site. These K values quantify the strength of the relationship between stream and air temperature, or inverse thermal stability. In a uniform, pristine catchment environment, K values are expected to decrease downstream as the stream gains discharge volume and, therefore, thermal inertia. Interannual average K values for our study reach, however, show an overall increase from 0.112 furthest upstream to 0.149 furthest downstream, despite a near doubling of stream discharge between these monitoring points. K values increase only slightly in the upstream, less urban, half of the reach. A line of best fit through these points on a plot of reach distance versus K value has a slope of 2E-6. But the K values of downstream, more urbanized sites increase at a rate of 2E-5 per meter of reach distance, an order of magnitude

  5. Challenges for implementing water quality monitoring and analysis on a small Costa Rican catchment

    Science.gov (United States)

    Golcher, Christian; Cernesson, Flavie; Tournoud, Marie-George; Bonin, Muriel; Suarez, Andrea

    2016-04-01

    The Costa Rican water regulatory framework (WRF) (2007), expresses the national concern about the degradation of surface water quality observed in the country since several years. Given the urgency of preserving and restoring the surface water bodies, and facing the need of defining a monitoring tool to classify surface water pollution, the Costa-Rican WRF relies on two water quality indexes: the so-called "Dutch Index" (D.I) and the Biological Monitoring Working Party adapted to Costa Rica (BMWP'CR), allowing an "easy" physicochemical and biological appraisal of the water quality and the ecological integrity of water bodies. Herein, we intend to evaluate whether the compound of water quality indexes imposed by Costa Rican legislation, is suitable to assess rivers local and global anthropogenic pressure and environmental conditions. We monitor water quality for 7 points of Liberia River (northern pacific region - Costa Rica) from March 2013 to July 2015. Anthropogenic pressures are characterized by catchment land use and riparian conditions. Environmental conditions are built from rainfall daily series. Our results show (i) the difficulties to monitor new sites following the recent implementation of the WRF; (ii) the statistical characteristics of each index; and (iii) a modelling tentative of relationships between water quality indexes and explanatory factors (land-use, riparian characteristics and climate conditions).

  6. Leak Detection in Water-Filled Small-Diameter Polyethylene Pipes by Means of Acoustic Emission Measurements

    Directory of Open Access Journals (Sweden)

    Alberto Martini

    2016-12-01

    Full Text Available The implementation of effective strategies to manage leaks represents an essential goal for all utilities involved with drinking water supply in order to reduce water losses affecting urban distribution networks. This study concerns the early detection of leaks occurring in small-diameter customers’ connections to water supply networks. An experimental campaign was carried out in a test bed to investigate the sensitivity of Acoustic Emission (AE monitoring to water leaks. Damages were artificially induced on a polyethylene pipe (length 28 m, outer diameter 32 mm at different distances from an AE transducer. Measurements were performed in both unburied and buried pipe conditions. The analysis permitted the identification of a clear correlation between three monitored parameters (namely total Hits, Cumulative Counts and Cumulative Amplitude and the characteristics of the examined leaks.

  7. Bottom friction models for shallow water equations: Manning’s roughness coefficient and small-scale bottom heterogeneity

    Science.gov (United States)

    Dyakonova, Tatyana; Khoperskov, Alexander

    2018-03-01

    The correct description of the surface water dynamics in the model of shallow water requires accounting for friction. To simulate a channel flow in the Chezy model the constant Manning roughness coefficient is frequently used. The Manning coefficient nM is an integral parameter which accounts for a large number of physical factors determining the flow braking. We used computational simulations in a shallow water model to determine the relationship between the Manning coefficient and the parameters of small-scale perturbations of a bottom in a long channel. Comparing the transverse water velocity profiles in the channel obtained in the models with a perturbed bottom without bottom friction and with bottom friction on a smooth bottom, we constructed the dependence of nM on the amplitude and spatial scale of perturbation of the bottom relief.

  8. When good practices by water committees are not relevant: Sustainability of small water infrastructures in semi-arid mozambique

    Science.gov (United States)

    Ducrot, Raphaëlle

    2017-12-01

    This paper explores the contradiction between the need for large scale interventions in rural water supplies and the need for flexibility when providing support for community institutions, by investigating the implementation of the Mozambique - National Rural Water Supply and Sanitation Program in a semi-arid district of the Limpopo Basin. Our results showed that coordinated leadership by key committee members, and the level of village governance was more important for borehole sustainability than the normative functioning of the committee. In a context in which the centrality of leadership prevails over collective action the sustainability of rural water infrastructure derives from the ability of leaders to motivate the community to provide supplementary funding. This, in turn, depends on the added value to the community of the water points and on village politics. Any interventions that increased community conflicts, for example because of lack of transparency or unequitable access to the benefit of the intervention, weakened the coordination and the collective action capacity of the community and hence the sustainability of the infrastructures even if the intervention was not directly related to water access. These results stress the importance of the project/program implementation pathway.

  9. Renewable synthesis-gas-production. Do hydrocarbons in the reactant flow of the reverse water-gas shift reaction cause coke formation?

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, A.; Kern, C.; Jess, A. [Bayreuth Univ. (Germany). Dept. of Chemical Engineering

    2013-11-01

    In a two-step synthetic fuel production process based on carbon dioxide and renewable hydrogen, the best possible selectivity towards liquid hydrocarbons (Hc) shall be implemented. The process consists of a combination of the Reverse Water-Gas Shift reaction and the Fischer-Tropsch synthesis. To achieve this goal, gaseous short-chained Hc from the FTS reactor are recycled in the RWGS unit. In this paper, challenges coming up with the implementation of a recycle loop are discussed. First of all, it has to be examined whether Hc are converted under conditions present in the RWGS reactor. The coking caused by the recycle of Hc is regarded, including thermal coking in the heating zone of the reactor and catalytic coking in the catalyst bed. Coking of course is unwanted, as it deactivates the catalyst. The scope of this work is to find out to which extent and under which conditions gaseous Hc can be recycled. Therefore, experiments were carried out in both, a quartz glass reactor using a commercial Ni-catalyst at ambient pressure and in a pressurized steel reactor (without catalyst) to examine coking during the thermal decomposition of Hc. The catalytic experiments at atmospheric pressure showed that a recycle of CH{sub 4} did not cause coking up to a ratio of CH{sub 4}/CO{sub 2} below one. For these conditions, long term stability was proved. The reaction rates of the CH{sub 4} conversion were below those of the RWGS reaction. However, replacing CH{sub 4} by C{sub 3}H{sub 8} leads to thermal and catalytic coking. Catalytic coking hits the maximum level at about 700 C and decreases for higher temperatures and, thus is not regarded as a problem for the RWGS reactor. In contrast to that, thermal coking raises with higher temperatures, but it can be supressed efficiently with additional injection of H{sub 2}O, which of course shifts the equilibrium towards the undesired reactant side. (orig.)

  10. Community-specific hydraulic conductance potential of soil water decomposed for two Alpine grasslands by small-scale lysimetry

    Science.gov (United States)

    Frenck, Georg; Leitinger, Georg; Obojes, Nikolaus; Hofmann, Magdalena; Newesely, Christian; Deutschmann, Mario; Tappeiner, Ulrike; Tasser, Erich

    2018-02-01

    For central Europe in addition to rising temperatures an increasing variability in precipitation is predicted. This will increase the probability of drought periods in the Alps, where water supply has been sufficient in most areas so far. For Alpine grasslands, community-specific imprints on drought responses are poorly analyzed so far due to the sufficient natural water supply. In a replicated mesocosm experiment we compared evapotranspiration (ET) and biomass productivity of two differently drought-adapted Alpine grassland communities during two artificial drought periods divided by extreme precipitation events using high-precision small lysimeters. The drought-adapted vegetation type showed a high potential to utilize even scarce water resources. This is combined with a low potential to translate atmospheric deficits into higher water conductance and a lower biomass production as those measured for the non-drought-adapted type. The non-drought-adapted type, in contrast, showed high water conductance potential and a strong increase in ET rates when environmental conditions became less constraining. With high rates even at dry conditions, this community appears not to be optimized to save water and might experience drought effects earlier and probably more strongly. As a result, the water use efficiency of the drought-adapted plant community is with 2.6 gDW kg-1 of water much higher than that of the non-drought-adapted plant community (0.16 gDW kg-1). In summary, the vegetation's reaction to two covarying gradients of potential evapotranspiration and soil water content revealed a clear difference in vegetation development and between water-saving and water-spending strategies regarding evapotranspiration.

  11. A study on sustainable urban water management in small and medium sized cities in China

    OpenAIRE

    Liu, Guang

    2012-01-01

    Along with the implementation of national urbanization and modernization strategy in China, the urban scale and quantity are increasing systematically. In this process, the role of water is irreplaceable. Urban water system is a multipurpose and integrated system. Considering China's economic and social development requirements, there are many rigorous problems in exploitation, utilization, operation and management of urban water resources comparing with some developed cities in the world. Cu...

  12. An experimental study on the excitation of large volume airguns in a small volume body of water

    International Nuclear Information System (INIS)

    Wang, Baoshan; Yang, Wei; Yuan, Songyong; Ge, Hongkui; Chen, Yong; Guo, Shijun; Xu, Ping

    2010-01-01

    A large volume airgun array is effective in generating seismic waves, which is extensively used in large volume bodies of water such as oceans, lakes and reservoirs. So far, the application of large volume airguns is subject to the distribution of large volume bodies of water. This paper reports an attempt to utilize large volume airguns in a small body of water as a seismic source for seismotectonic studies. We carried out a field experiment in Mapaoquan pond, Fangshan district, Beijing, during the period 25–30 May 2009. Bolt LL1500 airguns, each with volumes of 2000 in 3 , the largest commercial airguns available today, were used in this experiment. We tested the excitation of the airgun array with one or two guns. The airgun array was placed 7–11 m below the water's surface. The near- and far-field seismic motions induced by the airgun source were recorded by a 100 km long seismic profile composed of 16 portable seismometers and a 100 m long strong motion seismograph profile, respectively. The following conclusions can be drawn from this experiment. First, it is feasible to excite large volume airguns in a small volume body of water. Second, seismic signals from a single shot of one airgun can be recognized at the offset up to 15 km. Taking advantage of high source repeatability, we stacked records from 128 shots to enhance the signal-to-noise ratio, and direct P-waves can be easily identified at the offset ∼50 km in stacked records. Third, no detectable damage to fish or near-field constructions was caused by the airgun shots. Those results suggest that large volume airguns excited in small bodies of water can be used as a routinely operated seismic source for mid-scale (tens of kilometres) subsurface explorations and monitoring under various running conditions

  13. Analysis of water application techniques for growing tomatoes in small pots on different substrates. Note 2

    Directory of Open Access Journals (Sweden)

    Luigi Cavazza

    Full Text Available The response of the tomato plants to the irrigation regimes compared in the previous study, particularly when compared with the response to the peat fraction in the mixture, was modest, often irregular and subject to complex interactions with the former factor. This result could depend partially on the fact that the parameters for the water regime applied during the trials were chosen to prevent exposing the plants to excessive stress through lack of water or excess water. This note analyses the technique used to apply the water. Two main water application parameters were identified parameter a expressing the mean moisture level of the pot during growing, and parameter b expressing the amplitude of the variation in moisture level between the irrigation threshold and the level to which the water was topped up at each watering. The actual mean volume of irrigation during the cultivation period was compared with the theoretically predicted value and the discrepancy explained. The role of parameter a and b are proposed to define the irrigation regime applied and the water regime as such can be defined by these two parameters a and b, as a general composite index. Furthermore the effect on the biological performance of both parameters a and b were studied obtaining a clearer picture of the effect of the water regime. The role of both parameters, a and b were synthesized in a specific composite index for each individual characteristic of the plant after taking in account the principal causes of their variations.

  14. THE PRESENT CONDITION OF SMALL WATER RETENTION AND THE PROSPECTS OF ITS DEVELOPMENT USING THE EXAMPLE OF THE PODLASKIE VOIVODESHIP

    Directory of Open Access Journals (Sweden)

    Joanna Szczykowska

    2014-07-01

    Full Text Available The necessity and purposefulness of the investments related to water retention are justified mostly due to the preservation of the environment equilibrium as well as due to its farming, anti-flood, landscape and recreation aspects. Reasonable water management where various forms of retention are used gives large chances for the mitigation of the effects of unfavorable phenomena related to its insufficient amount. The creation of plans regarding the formation of reservoirs accumulating water is not necessarily synonymous with their realization. The reason of problems connected with the implementation of plans regarding the formation of new reservoirs lies mainly in financial measures and in problems with obtaining them. Water deficit in Poland is the reason for which the principles of its national usage need to be complied with. Realization of plans at both Voivodeship and municipality level that are focused on small retention will contribute to considerable increase in the retention capacity and will enable considerable increase in available resources in hydrographic catchments of both the characterized area and the entire country. The paper presents the characteristics of the present state and assumes the perspective development of small water retention in the Podlaskie Voivodeship using the example of the Podlaskie Voivodeship.

  15. Morphological, physical and pedogenetic attributes related to water yield in small watersheds in Guarapari/ES, Brazil

    Directory of Open Access Journals (Sweden)

    Alexson de Mello Cunha

    2011-08-01

    Full Text Available Soil characteristics related to the genesis, land use and management are important factors in water dynamics in watersheds. This study evaluated physical, morphological and pedogenetic attributes related to water yield potential in small watersheds in Guarapari, ES, Brazil. The following representative profiles were selected, morphologically described and sampled in area of Atlantic Forest domain: Lithic Udifolists, Oxyaquic Udifluventes, Typic Paleudults, Typic Hapludults, Typic Hapludox, Oxic Dystrudepts and Typic Endoaquents. Samples were collected in the soil profiles for physical analysis. Measurements of field-saturated hydraulic conductivity and soil penetration resistance were perfomed in some profiles, which were under different uses. The Endoaquents of Limão Creek can be considered efficient as temporary water reservoirs. However, the use of artificial drainage tends to reduce this effect. Differential erosion was detected by the sand texture on the surface of the Typic Paleudults due to the low degree of clay flocculation, slope, high resistance to the penetration and low hydraulic conductivity of the Bt horizon, making it necessary to adopt soil management practices to increase the water infiltration. Under pasture, mainly in the cattle trails where the trampling is more intense, there was high resistance to penetration in the superficial layers of the Typic Hapludults. The Typic Hapludox have the greatest potential for water yield in the small watersheds because of its greater extent in the headwaters and their morphological and physical characteristics, which can result in increased aquifer recharge.

  16. Local Water Management of Small Reservoirs: Lessons from Two Case Studies in Burkina Faso

    Directory of Open Access Journals (Sweden)

    Hilmy Sally

    2011-10-01

    Full Text Available Burkina Faso is actively pursuing the implementation of Integrated Water Resources Management (IWRM in its development plans. Several policy and institutional mechanisms have been put in place, including the adoption of a national IWRM action plan (PAGIRE and the establishment so far of 30 local water management committees (Comités Locaux de l’Eau, or CLE. The stated purpose of the CLE is to take responsibility for managing water at sub-basin level. The two case studies discussed in this paper illustrate gaps between the policy objective of promoting IWRM on the one hand, and the realities associated with its practical on-the-ground implementation on the other. A significant adjustment that occurred in practice is the fact that the two CLE studied have been set up as entities focused on reservoir management, whereas it is envisioned that a CLE would constitute a platform for sub-basin management. This reflects a concern to minimise conflict and optimally manage the country’s primary water resource and illustrates the type of pragmatic actions that have to be taken to make IWRM a reality. It is also observed that the local water management committees have not been able to satisfactorily address questions regarding access to, and allocation of, water, which are crucial for the satisfactory functioning of the reservoirs. Water resources in the reservoirs appear to be controlled by the dominant user. In order to correct this trend, measures to build mutual trust and confidence among water users 'condemned' to work together to manage their common resource are suggested, foremost of which is the need to collect and share reliable data. Awareness of power relationships among water user groups and building on functioning, already existing formal or informal arrangements for water sharing are key determinants for successful implementation of the water reform process underway.

  17. Comparative Assessment of Heavy Metals in Drinking Water Sources in Two Small-Scale Mining Communities in Northern Ghana

    Science.gov (United States)

    Cobbina, Samuel J.; Duwiejuah, Abudu B.; Quansah, Reginald; Obiri, Samuel; Bakobie, Noel

    2015-01-01

    The study assessed levels of heavy metals in drinking water sources in two small-scale mining communities (Nangodi and Tinga) in northern Ghana. Seventy-two (72) water samples were collected from boreholes, hand dug wells, dug-out, and a stream in the two mining communities. The levels of mercury (Hg), arsenic (As), lead (Pb), zinc (Zn), and cadmium (Cd) were determined using an atomic absorption spectrophotometer (AAS). Mean levels (mg/l) of heavy metals in water samples from Nangodi and Tinga communities were 0.038 and 0.064 (Hg), 0.031 and 0.002 (As), 0.250 and 0.031 (Pb), 0.034 and 0.002 (Zn), and 0.534 and 0.023 (Cd), respectively, for each community. Generally, levels of Hg, As, Pb, Zn, and Cd in water from Nangodi exceeded the World Health Organisation (WHO) stipulated limits of 0.010 for Hg, As, and Pb, 3.0 for Zn and 0.003 for Cd for drinking water, and levels of Hg, Pb, and Cd recorded in Tinga, exceeded the stipulated WHO limits. Ingestion of water, containing elevated levels of Hg, As, and Cd by residents in these mining communities may pose significant health risks. Continuous monitoring of the quality of drinking water sources in these two communities is recommended. PMID:26343702

  18. Comparative Assessment of Heavy Metals in Drinking Water Sources in Two Small-Scale Mining Communities in Northern Ghana

    Directory of Open Access Journals (Sweden)

    Samuel J. Cobbina

    2015-08-01

    Full Text Available The study assessed levels of heavy metals in drinking water sources in two small-scale mining communities (Nangodi and Tinga in northern Ghana. Seventy-two (72 water samples were collected from boreholes, hand dug wells, dug-out, and a stream in the two mining communities. The levels of mercury (Hg, arsenic (As, lead (Pb, zinc (Zn, and cadmium (Cd were determined using an atomic absorption spectrophotometer (AAS. Mean levels (mg/l of heavy metals in water samples from Nangodi and Tinga communities were 0.038 and 0.064 (Hg, 0.031 and 0.002 (As, 0.250 and 0.031 (Pb, 0.034 and 0.002 (Zn, and 0.534 and 0.023 (Cd, respectively, for each community. Generally, levels of Hg, As, Pb, Zn, and Cd in water from Nangodi exceeded the World Health Organisation (WHO stipulated limits of 0.010 for Hg, As, and Pb, 3.0 for Zn and 0.003 for Cd for drinking water, and levels of Hg, Pb, and Cd recorded in Tinga, exceeded the stipulated WHO limits. Ingestion of water, containing elevated levels of Hg, As, and Cd by residents in these mining communities may pose significant health risks. Continuous monitoring of the quality of drinking water sources in these two communities is recommended.

  19. Integration of Cleaner Production and Waste Water Treatment on Tofu Small Industry for Biogas Production using AnSBR Reactor

    Science.gov (United States)

    Rahayu, Suparni Setyowati; Budiyono; Purwanto

    2018-02-01

    A research on developing a system that integrates clean production and waste water treatment for biogas production in tofu small industry has been conducted. In this research, tofu waste water was turned into biogas using an AnSBR reactor. Mud from the sewage system serves as the inoculums. This research involved: (1) workshop; (2) supervising; (3) technical meeting; (4) network meeting, and (5) technical application. Implementation of clean production integrated with waste water treatment reduced the amount of waste water to be treated in a treatment plant. This means less cost for construction and operation of waste water treatment plants, as inherent limitations associated with such plants like lack of fund, limited area, and technological issues are inevitable. Implementation of clean production prior to waste water treatment reduces pollution figures down to certain levels that limitations in waste water treatment plants can be covered. Results show that biogas in 16 days HRT in an AnSBR reactor contains CH4(78.26 %) and CO2 (20.16 %). Meanwhile, treatments using a conventional bio-digester result in biogas with 72.16 % CH4 and 18.12 % CO2. Hence, biogas efficiency for the AnSBR system is 2.14 times greater than that of a conventional bio-digester.

  20. Comparative Assessment of Heavy Metals in Drinking Water Sources in Two Small-Scale Mining Communities in Northern Ghana.

    Science.gov (United States)

    Cobbina, Samuel J; Duwiejuah, Abudu B; Quansah, Reginald; Obiri, Samuel; Bakobie, Noel

    2015-08-28

    The study assessed levels of heavy metals in drinking water sources in two small-scale mining communities (Nangodi and Tinga) in northern Ghana. Seventy-two (72) water samples were collected from boreholes, hand dug wells, dug-out, and a stream in the two mining communities. The levels of mercury (Hg), arsenic (As), lead (Pb), zinc (Zn), and cadmium (Cd) were determined using an atomic absorption spectrophotometer (AAS). Mean levels (mg/l) of heavy metals in water samples from Nangodi and Tinga communities were 0.038 and 0.064 (Hg), 0.031 and 0.002 (As), 0.250 and 0.031 (Pb), 0.034 and 0.002 (Zn), and 0.534 and 0.023 (Cd), respectively, for each community. Generally, levels of Hg, As, Pb, Zn, and Cd in water from Nangodi exceeded the World Health Organisation (WHO) stipulated limits of 0.010 for Hg, As, and Pb, 3.0 for Zn and 0.003 for Cd for drinking water, and levels of Hg, Pb, and Cd recorded in Tinga, exceeded the stipulated WHO limits. Ingestion of water, containing elevated levels of Hg, As, and Cd by residents in these mining communities may pose significant health risks. Continuous monitoring of the quality of drinking water sources in these two communities is recommended.

  1. Impacts of nutrients and pesticides from small- and large-scale agriculture on the water quality of Lake Ziway, Ethiopia.

    Science.gov (United States)

    Teklu, Berhan M; Hailu, Amare; Wiegant, Daniel A; Scholten, Bernice S; Van den Brink, Paul J

    2018-05-01

    The area around Lake Ziway in Ethiopia is going through a major agricultural transformation with both small-scale farmers and large horticultural companies using pesticides and fertilisers at an increased rate. To be able to understand how this influences the water quality of Lake Ziway, water quality data was gathered to study the dynamics of pesticide concentrations and physicochemical parameters for the years from 2009 to 2015. Results indicate that for some physicochemical parameters, including pH, potassium and iron, over 50 % of the values were above the maximum permissible limit of the Ethiopian standard for drinking water. The fungicide spiroxamine poses a high chronic risk when the water is used for drinking water, while the estimated intake of diazinon was approximately 50 % of the acceptable daily intake. Higher-tier risk assessment indicated that the fungicide spiroxamine poses a high acute risk to aquatic organisms, while possible acute risks were indicated for the insecticides deltamethrin and endosulfan. Longer-term monitoring needs to be established to show the water quality changes across time and space, and the current study can be used as a baseline measurement for further research in the area as well as an example for other surface water systems in Ethiopia and Africa.

  2. Drinking water quality in six small tea gardens of Sonitpur District of Assam, India, with special reference to heavy metals.

    Science.gov (United States)

    Dutta, Joydev; Chetia, Mridul; Misra, A K

    2011-10-01

    Contamination of drinking water by arsenic and other heavy metals and their related toxicology is a serious concern now-a-days. Millions of individual world-wide are suffering from the arsenic and other heavy metal related diseases due to the consumption of contaminated groundwater. 60 water samples from different sources of 6 small tea gardens of Sonitpur district were collected to study the potability of water for drinking purposes. The water samples collected from sources like tube wells, ring wells and ponds were analyzed for arsenic, heavy metals like iron, manganese and mercury with sodium, potassium, calcium, magnesium, pH, total hardness, chloride, fluoride and sulphate. Some drain water samples of the tea garden areas were also collected to analyze the above mentioned water parameters to see the contamination level. Experiments revealed that 78% samples of total collection had arsenic content above the permissible limit (0.01 ppm) of WHO guideline value for drinking water. The highest arsenic was observed 0.09 ppm at one sample of Gobindra Dahal tea garden of Gohpur sub division of Sonitpur district. 94% samples had contamination due to manganese 39% samples had iron and 44% samples had Hg. The water quality data was subjected to some statistical treatments like NDA, cluster analysis and pearson correlation to observe the distribution pattern of the different water quality parameters. A strong pearson correlation coefficient was observed between parameters-arsenic and manganese (0.865) and arsenic and mercury (0.837) at 0.01 level, indicated the same sources of drinking water contamination.

  3. Potential water supply of a small reservoir and alluvial aquifer system in southern Zimbabwe

    NARCIS (Netherlands)

    de Hamer, W.; Love, D.; Owen, R.; Booij, Martijn J.; Hoekstra, Arjen Ysbert

    2008-01-01

    Groundwater use by accessing alluvial aquifers of non-perennial rivers can be an important additional water resource in the semi-arid region of southern Zimbabwe. The research objective of the study was to calculate the potential water supply for the upper-Mnyabezi catchment under current conditions

  4. Potential water supply of a small reservoir and alluvial aquifer system in southern Zimbabwe

    NARCIS (Netherlands)

    de Hamer, W.; Love, D.; Owen, R.; Booij, Martijn J.; Hoekstra, Arjen Ysbert

    2007-01-01

    Groundwater use by accessing alluvial aquifers of non‐perennial rivers can be an important additional water resource in the semi‐arid region of southern Zimbabwe. The research objective of the study was to calculate the potential water supply for the upper‐Mnyabezi catchment under current conditions

  5. Solar Energy and Other Appropriate Technologies for Small Potable Water Systems in Puerto Rico

    Science.gov (United States)

    This Region 2 research demonstration project presentation studied the efficacy of sustainable solar-powered water delivery and monitoring systems to reduce the economic burden of operating and maintaining Non-PRASA drinking water systems and to reduce the impact of climate change...

  6. Recovery of water from cacti for use in small farming communities ...

    African Journals Online (AJOL)

    In this study, an extensive investigation was conducted to determine if declared weeds could be used as a source of water for agricultural practices in dry areas. The objective of this study was to determineif declared weeds could successfully be used as a source of water for agricultural practices in dry areas by extracting ...

  7. Effects of Small-Scale Gold Mining on Surface and Ground Water ...

    African Journals Online (AJOL)

    / Prestea mining area in the Western Region of Ghana were conducted with the aim of assessing the possible effects of mining on water quality. Water samples were collected for 6 consecutive months at ten sampling sites within the study area ...

  8. Spectral reflectance is a reliable water-quality estimator for small, highly turbid wetlands

    Czech Academy of Sciences Publication Activity Database

    Vinciková, H.; Hanuš, Jan; Pechar, L.

    2015-01-01

    Roč. 23, č. 5 (2015), s. 933-946 ISSN 0923-4861 R&D Projects: GA MŠk(CZ) LM2010007; GA MŠk 2B06068 Institutional support: RVO:67179843 Keywords : remote sensing * water quality * hyperspectral reflectance * turbid inland waters * chlorophyll * TSS Subject RIV: DA - Hydrology ; Limnology Impact factor: 1.407, year: 2015

  9. Development of an improved compact package plant for small community waste-water treatment

    CSIR Research Space (South Africa)

    Hulsman, A

    1993-01-01

    Full Text Available The challenges facing the design and operation of small community wastewater treatment plants are discussed. The package plant concept is considered and the consequent development of a compact intermittently aerated activated sludge package plant...

  10. Emerging and Innovative Techniques for Arsenic Removal Applied to a Small Water Supply System

    Directory of Open Access Journals (Sweden)

    António J. Alçada

    2009-12-01

    Full Text Available The impact of arsenic on human health has led its drinking water MCL to be drastically reduced from 50 to 10 ppb. Consequently, arsenic levels in many water supply sources have become critical. This has resulted in technical and operational impacts on many drinking water treatment plants that have required onerous upgrading to meet the new standard. This becomes a very sensitive issue in the context of water scarcity and climate change, given the expected increasing demand on groundwater sources. This work presents a case study that describes the development of low-cost techniques for efficient arsenic control in drinking water. The results obtained at the Manteigas WTP (Portugal demonstrate the successful implementation of an effective and flexible process of reactive filtration using iron oxide. At real-scale, very high removal efficiencies of over 95% were obtained.

  11. Remediation of antimony-rich mine waters: Assessment of antimony removal and shifts in the microbial community of an onsite field-scale bioreactor.

    Science.gov (United States)

    Sun, Weimin; Xiao, Enzong; Kalin, Margarete; Krumins, Valdis; Dong, Yiran; Ning, Zengping; Liu, Tong; Sun, Min; Zhao, Yanlong; Wu, Shiliang; Mao, Jianzhong; Xiao, Tangfu

    2016-08-01

    An on-site field-scale bioreactor for passive treatment of antimony (Sb) contamination was installed downstream of an active Sb mine in Southwest China, and operated for one year (including a six month monitoring period). This bioreactor consisted of five treatment units, including one pre-aerobic cell, two aerobic cells, and two microaerobic cells. With the aerobic cells inoculated with indigenous mine water microflora, the bioreactor removed more than 90% of total soluble Sb and 80% of soluble antimonite (Sb(III)). An increase in pH and decrease of oxidation-reduction potential (Eh) was also observed along the flow direction. High-throughput sequencing of the small subunit ribosomal RNA (SSU rRNA) gene variable (V4) region revealed that taxonomically diverse microbial communities developed in the bioreactor. Metal (loid)-oxidizing bacteria including Ferrovum, Thiomonas, Gallionella, and Leptospirillum, were highly enriched in the bioreactor cells where the highest total Sb and Sb(III) removal occurred. Canonical correspondence analysis (CCA) indicated that a suite of in situ physicochemical parameters including pH and Eh were substantially correlated with the overall microbial communities. Based on an UPGMA (Unweighted Pair Group Method with Arithmetic Mean) tree and PCoA (Principal Coordinates Analysis), the microbial composition of each cell was distinct, indicating these in situ physicochemical parameters had an effect in shaping the indigenous microbial communities. Overall, this study was the first to employ a field-scale bioreactor to treat Sb-rich mine water onsite and, moreover, the findings suggest the feasibility of the bioreactor in removing elevated Sb from mine waters. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. The production of hydrogen through the use of a 77 wt% Pd 23 wt% Ag membrane water gas shift reactor

    Directory of Open Access Journals (Sweden)

    Liberty N. Baloyi

    2016-12-01

    Full Text Available Hydrogen as an energy carrier has the potential to decarbonize the energy sector. This work presents the application of a palladium-silver (Pd–Ag membrane-based reactor. The membrane reactor which is made from Pd–Ag film supported by porous stainless steel (PSS is evaluated for the production of hydrogen and the potential replacement of the current two-stage Water-Gas Shift (WGS reaction by a single stage reaction. The permeability of a 20 μm Pd–Ag membrane reactor was examined at 320 °C, 380 °C and 430 °C. The effect of continuous hydrogen exposure on the Pd–Ag membrane at high temperature and low temperature was examined to investigate the thermal stability and durability of the membrane. During continuous operation to determine thermal stability, the membrane reactor exhibited stable hydrogen permeation at 320 °C for 120 h and unstable hydrogen permeation at 430 °C was observed. For the WGS reaction, the reactor was loaded with Ferrochrome catalyst. The membrane showed the ability to produce high purity hydrogen, with a CO conversion and an H2 recovery of 84% and 88%, respectively. The membrane suffered from hydrogen embrittlement due to desorption and adsorption of hydrogen on the membrane surface. SEM analysis revealed cracks that occurred on the surface of the membrane after hydrogen exposure. XRD analysis revealed lattice expansion after hydrogen loading which suggests the occurrence of phase change from α-phase to the more brittle β-phase.

  13. Finding Structure in Diversity: A Stepwise Small-N/Medium-N Qualitative Comparative Analysis Approach for Water Resources Management Research

    Directory of Open Access Journals (Sweden)

    Peter P. Mollinga

    2014-02-01

    Full Text Available Drawing particularly on recent debates on, and development of, comparative methods in the field of comparative politics, the paper argues that stepwise small-N/medium-N qualitative comparative analysis (QCA is a particularly suitable methodological approach for water resources studies because it can make use of the rich but fragmented water resources studies literature for accumulation of knowledge and development of theory. It is suggested that taking an explicit critical realist ontological and epistemological stance allows expansion of the scope of stepwise small-N/medium-N QCA beyond what is claimed for it in Ragin’s 'configurational comparative methods (CCM' perspective for analysing the complexity of causality as 'multiple conjunctural causation'. In addition to explanation of certain sets of 'outcomes' as in CCM’s combinatorial, set-theoretic approach, embedding stepwise small-N/medium-N QCA in a critical realist ontology allows the method to contribute to development of theory on (qualitative differences between the structures in society that shape water resources use, management and governance.

  14. A measure for the efficiency of water use and its determinants, a case study of small-scale irrigation schemes in North-West Province, South Africa

    NARCIS (Netherlands)

    Speelman, S.; Haese, D' M.F.C.; Buysse, J.; Haese, D' L.

    2008-01-01

    This paper analyses the efficiency with which water is used in small-scale irrigation schemes in North-West Province in South Africa and studies its determinants. In the study area, small-scale irrigation schemes play an important role in rural development, but the increasing pressure on water

  15. Characteristics and Propagation of Airgun Pulses in Shallow Water with Implications for Effects on Small Marine Mammals.

    Directory of Open Access Journals (Sweden)

    Line Hermannsen

    Full Text Available Airguns used in seismic surveys are among the most prevalent and powerful anthropogenic noise sources in marine habitats. They are designed to produce most energy below 100 Hz, but the pulses have also been reported to contain medium-to-high frequency components with the potential to affect small marine mammals, which have their best hearing sensitivity at higher frequencies. In shallow water environments, inhabited by many of such species, the impact of airgun noise may be particularly challenging to assess due to complex propagation conditions. To alleviate the current lack of knowledge on the characteristics and propagation of airgun pulses in shallow water with implications for effects on small marine mammals, we recorded pulses from a single airgun with three operating volumes (10 in3, 25 in3 and 40 in3 at six ranges (6, 120, 200, 400, 800 and 1300 m in a uniform shallow water habitat using two calibrated Reson 4014 hydrophones and four DSG-Ocean acoustic data recorders. We show that airgun pulses in this shallow habitat propagated out to 1300 meters in a way that can be approximated by a 18log(r geometric transmission loss model, but with a high pass filter effect from the shallow water depth. Source levels were back-calculated to 192 dB re µPa2s (sound exposure level and 200 dB re 1 µPa dB Leq-fast (rms over 125 ms duration, and the pulses contained substantial energy up to 10 kHz, even at the furthest recording station at 1300 meters. We conclude that the risk of causing hearing damage when using single airguns in shallow waters is small for both pinnipeds and porpoises. However, there is substantial potential for significant behavioral responses out to several km from the airgun, well beyond the commonly used shut-down zone of 500 meters.

  16. Characteristics and Propagation of Airgun Pulses in Shallow Water with Implications for Effects on Small Marine Mammals.

    Science.gov (United States)

    Hermannsen, Line; Tougaard, Jakob; Beedholm, Kristian; Nabe-Nielsen, Jacob; Madsen, Peter Teglberg

    2015-01-01

    Airguns used in seismic surveys are among the most prevalent and powerful anthropogenic noise sources in marine habitats. They are designed to produce most energy below 100 Hz, but the pulses have also been reported to contain medium-to-high frequency components with the potential to affect small marine mammals, which have their best hearing sensitivity at higher frequencies. In shallow water environments, inhabited by many of such species, the impact of airgun noise may be particularly challenging to assess due to complex propagation conditions. To alleviate the current lack of knowledge on the characteristics and propagation of airgun pulses in shallow water with implications for effects on small marine mammals, we recorded pulses from a single airgun with three operating volumes (10 in3, 25 in3 and 40 in3) at six ranges (6, 120, 200, 400, 800 and 1300 m) in a uniform shallow water habitat using two calibrated Reson 4014 hydrophones and four DSG-Ocean acoustic data recorders. We show that airgun pulses in this shallow habitat propagated out to 1300 meters in a way that can be approximated by a 18log(r) geometric transmission loss model, but with a high pass filter effect from the shallow water depth. Source levels were back-calculated to 192 dB re µPa2s (sound exposure level) and 200 dB re 1 µPa dB Leq-fast (rms over 125 ms duration), and the pulses contained substantial energy up to 10 kHz, even at the furthest recording station at 1300 meters. We conclude that the risk of causing hearing damage when using single airguns in shallow waters is small for both pinnipeds and porpoises. However, there is substantial potential for significant behavioral responses out to several km from the airgun, well beyond the commonly used shut-down zone of 500 meters.

  17. Creatinine and creatininium cation in water solution. Tautomerism and quantitative interpretation of the solution acidity effect on 1H, 13C and 1:4N NMR chemical shifts

    International Nuclear Information System (INIS)

    Kotsyubynskyy, D.; Molchanov, S.; Gryff-Keller, A.

    2004-01-01

    1 H, 13 C and 1 :4N NMR chemical shifts for creatinine in water solution of various acidity have been measured. Analysis of these data enabled determination of the acidity constant of creatininium cation and the chemical shifts of the neutral and protonated forms of creatinine. Molecular energies and carbon and nitrogen magnetic shielding constants for various tautomeric structures of the investigated species have been calculated using the quantum chemistry method GIAO DFT B3LYP/6-311++G(2d,p). Compilation of the available experimental and theoretical results has provided additional information on the problem of tautomerism of this important biological molecule. (author)

  18. Evasion of CO2 and dissolved carbon in river waters of three small catchments in an area occupied by small family farms in the eastern Amazon

    Directory of Open Access Journals (Sweden)

    Maria Beatriz Silva da Rosa

    2017-08-01

    Full Text Available CO2 effluxes from streams and rivers have been hypothesized to be a critical pathway of carbon flow from the biosphere back to the atmosphere. This study was conducted in three small Amazonian catchments to evaluate carbon evasion and dynamics, where land-use change has occurred on small family-farms. Monthly field campaigns were conducted from June 2006 to May 2007 in the Cumaru (CM, Pachibá (PB and São João (SJ streams. Electrical conductivity, pH, temperature, and dissolved oxygen measurements were done in situ, while water samples were collected to determine dissolved organic carbon (DOC and dissolved inorganic carbon (DIC concentrations, as well as carbon dioxide partial pressures (pCO2 and CO2 evasion fluxes. Instantaneous discharge measured by a current meter was used to calculate DOC fluxes. Considering all the sites, DOC, DIC, pCO2, and CO2 flux measurements ranged as follows, respectively: 0.27 - 12.13 mg L-1; 3.5 - 38.9 mg L-1; 2,265 - 26,974 ppm; and 3.39 - 75.35 μmol m-2 s-1. DOC annual flux estimates for CM, SJ and PB were, respectively, 281, 245, and 169 kg C ha-1. CO2 evasion fluxes had an average of 22.70 ± 1.67 μmol m-2 s-1. These CO2 evasion fluxes per unit area were similar to those measured for major Amazonian rivers, thus confirming our hypothesis that small streams can evade substantial quantities of CO2. As secondary vegetation is abundant as a result of family farming management in the region, we conclude that this vegetation can be a major driver of an abundant carbon cycle.

  19. Fishery intensification in small water bodies: a review for North America

    National Research Council Canada - National Science Library

    Moehl, John Frederic; Davies, William D

    1993-01-01

    .... Intensification is also achieved by enhancing water fertility through liming and fertilization. Case studies are presented representing contrasting climatic regions of North America while demonstrating similarities in management style...

  20. Characterization of the Water Quality Status on a Stretch of River Lérez around a Small Hydroelectric Power Station

    Directory of Open Access Journals (Sweden)

    Enrique Valero

    2012-10-01

    Full Text Available The renewable energy emerged as a solution to the environmental problems caused by the conventional sources of energy. Small hydropower (SHP is claimed to cause negligible effects on the ecosystem, although some environmental values are threatened and maintenance of an adequate water quality should be ensured. This work provides a characterization of the water quality status in a river stretch around a SHP plant on river Lérez, northwest Spain, for four years after its construction. The ecological and chemical status of the water as well as the ecological quality of the riparian habitat, were used as measures of quality. Data were compared with the water quality requirements. The variations in the quality parameters were analyzed over time and over the river sections with respect to the SHP plant elements. Two years after construction, the temperature and dissolved oxygen values achieved conditions for salmonid water and close to the reference condition, while pH values were low. The Iberian Biological Monitoring Working Party (IBMWP index showed a positive trend from two years after the construction and stabilized at “unpolluted or not considerably altered water”. Quality parameters did not present significant differences between sampling points. The SHP plant construction momentarily altered the quality characteristics of the water.

  1. Distribution of Fe in waters and bottom sediments of a small estuarine catchment, Pumicestone Region, southeast Queensland, Australia

    International Nuclear Information System (INIS)

    Liaghati, Tania; Cox, Malcolm E.; Preda, Micaela

    2005-01-01

    Dissolved and extractable iron concentrations in surface water, groundwater and bottom sediments were determined for Halls Creek, a small subtropical tidally influenced creek. Dissolved iron concentrations were much higher in fresh surface waters and groundwater compared to the estuarine water. In bottom sediments, iron minerals were determined by X-ray diffraction (XRD); of these, hematite (up to 11%) has formed by precipitation from iron-rich water in the freshwater section of the catchment. Pyrite was only identified in the estuarine reach and demonstrated several morphologies [identified by scanning electron microscopy (SEM)] including loosely and closely packed framboids, and the euhedral form. The forms of pyrite found in bottom sediments indicate in situ production and recrystallisation. In surface waters, pyrite was detected in suspended sediment; due to oxygen concentrations well above 50 μmol/l, it was concluded that framboids do not form in the water column, but are within resuspended bottom sediments or eroded from creek banks. The persistence of framboids in suspended sediments, where oxygen levels are relatively high, could be due to their silica and clay-rich coatings, which prevent a rapid oxidation of the pyrite. In addition to identifying processes of formation and transport of pyrite, this study has environmental significance, as this mineral is a potential source of bioavailable forms of iron, which can be a major nutrient supporting algal growth

  2. Anthropogenic water sources and the effects on Sonoran Desert small mammal communities

    OpenAIRE

    Aaron B. Switalski; Heather L. Bateman

    2017-01-01

    Anthropogenic water sources (AWS) are developed water sources used as a management tool for desert wildlife species. Studies documenting the effects of AWS are often focused on game species; whereas, the effects on non-target wildlife are less understood. We used live trapping techniques to investigate rodent abundance, biomass, and diversity metrics near AWS and paired control sites; we sampled vegetation to determine rodent-habitat associations in the Sauceda Mountains of the Sonoran Desert...

  3. Water table tests of proposed heat transfer tunnels for small turbine vanes

    Science.gov (United States)

    Meitner, P. L.

    1974-01-01

    Water-table flow tests were conducted for proposed heat-transfer tunnels which were designed to provide uniform flow into their respective test sections of a single core engine turbine vane and a full annular ring of helicopter turbine vanes. Water-table tests were also performed for the single-vane test section of the core engine tunnel. The flow in the heat-transfer tunnels was shown to be acceptable.

  4. A New Small Drifter for Shallow Water Basins: Application to the Study of Surface Currents in the Muggia Bay (Italy

    Directory of Open Access Journals (Sweden)

    Carmelo Nasello

    2016-01-01

    Full Text Available A new small drifter prototype for measuring current immediately below the free surface in a water basin is proposed in this paper. The drifter dimensions make it useful for shallow water applications. The drifter transmits its GPS location via GSM phone network. The drifter was used to study the trajectory of the surface current in the Muggia bay, the latter containing the industrial harbor of the city of Trieste (Italy. The analysis has been carried out under a wide variety of wind conditions. As regards the behavior of the drifter, the analysis has shown that it is well suited to detect the water current since its motion is marginally affected by the wind. The study has allowed detecting the main features of the surface circulation within the Muggia bay under different meteorological conditions. Also, the study has shown that the trajectory of the surface current within the bay is weakly affected by the Coriolis force.

  5. Economic assessments of small-scale drinking-water interventions in pursuit of MDG target 7C.

    Science.gov (United States)

    Cameron, John; Jagals, Paul; Hunter, Paul R; Pedley, Steve; Pond, Katherine

    2011-12-01

    This paper uses an applied rural case study of a safer water intervention in South Africa to illustrate how three levels of economic assessment can be used to understand the impact of the intervention on people's well-being. It is set in the context of Millennium Development Goal 7 which sets a target (7C) for safe drinking-water provision and the challenges of reaching people in remote rural areas with relatively small-scale schemes. The assessment moves from cost efficiency to cost effectiveness to a full social cost-benefit analysis (SCBA) with an associated sensitivity test. In addition to demonstrating techniques of analysis, the paper brings out many of the challenges in understanding how safer drinking-water impacts on people's livelihoods. The SCBA shows the case study intervention is justified economically, though the sensitivity test suggests 'downside' vulnerability. Copyright © 2011 Elsevier B.V. All rights reserved.

  6. Micro and small enterprises, water and developing countries: a challenge for sustainability in Colombia

    NARCIS (Netherlands)

    Sanz Galindo, G.A.M.M.

    2015-01-01

    The relationship between environmental agencies and polluters is especially challenging in the context of micro and small sized enterprises (McSEs) in developing countries. The focus is mainly at end-of-pipe solutions that are usually unaffordable for McSEs. In order to engage them in achieving

  7. Combination of methanogenesis and denitrification in a UASB reactor for water reclamation applied to small agglomerations

    NARCIS (Netherlands)

    Davila, J.M.S.; Khassab, G.; Klapwijk, A.; Lier, van J.B.

    2009-01-01

    A two-step system combining an anaerobic/anoxic UASB reactor followed by a low energy consuming rotating biological contactor might be a sustainable option for wastewater treatment and reuse in small agglomerations. This article focuses on the UASB stage. The performance of a lab-scale UASB fed with

  8. Development of natural circulation small and medium sized boiling water reactor: HSBWR-600

    International Nuclear Information System (INIS)

    Miki, Minoru; Horiuchi, Tetsuo; Yoshimoto, Yuichiro; Sumida, Isao; Murase, Michio; Akita, Minoru; Niino, Tsuyoshi

    1988-01-01

    In nuclear power generation, the development of large reactors has been promoted as the main energy source in Japan. However, world economy entered low growth age, and the growth of electric power demand slowed down. Accordingly, attention has been paid to the medium and small reactors that can cope with whatever needs by serializing their types in addition to the nuclear power plants of medium output matching to electric power demand. In order to cope with these new needs, the economical efficiency of medium and small reactors must be as close as possible to that of large reactors, and as the countermeasures to the demerits due to small size, those must be made into the plants having simplified systems and the safety easily acceptable to public. Hitachi Ltd. plans to develop the natural circulation type medium and small BWRs of 600 NWe output class, HSBWR-600, on the basis of the nuclear power plant technology based on the rich results of design and operation of BWRs obtained so far, and to rank them as one of the BWR series. The target of their development design, the circumstance of their development, the core design and the thermo-hydraulic characteristics, the reactor pressure vessel and in-core structures, the safety design, system design, building layout and the evaluation are reported. (Kako, I.)

  9. Water Reform and the Resilience of Small Business People in Drought-Affected Agricultural Communities

    Science.gov (United States)

    Schwarz, Imogen; Williams, Pam McRae

    2009-01-01

    The impact of drought on rural communities in Australia has been the subject of considerable research. Less well understood are the impacts of drought on rural small businesses and the mechanisms they use to adapt or cope through extended dry periods. In this study, strategies these businesses draw upon to manage this adversity are identified and…

  10. EVALUATION OF WATER RETENTION CAPABILITY IN WETLANDS AT SMALL FOREST CATCHMENT

    Directory of Open Access Journals (Sweden)

    Daniel Liberacki

    2015-07-01

    Full Text Available The paper presents the results of researches carried out in the middle part of Pizza Zielonka forest complex. The aim was the evaluation of retention changes at wetlands and mid-forest ponds. The object of the study was the catchment of the Trojanka watercourse, considering from the origin to the cross-section of Zielonka Lake. The catchment is located in in the central part of the Wielkopolska region, approximatelly 20 km on the North-East of Poznań. The area of this forestall catchment is about 223 ha. In the paper an analysis of the results from three hydrological years was presented. The results of the years 1987 (wet year, 2003 (dry year and 2009 (medium year were analysed against meteorological conditions. Retention capacity in each wetlands, as well as the possibility of water retention in the Trojanka watercourse was calculated. The researches confirmed significant meteorological conditions influence the amount of retentioned water. The calculated capacity of retentioned water was 15 852 m3 considering the total area of wetland and swamp (8,58 ha and precipitation sum of 555 mm. 18% increase of water capacity was observed in wet year (1987 In this year the sum of precipitation was 100 mm higher than multiyear average sum. Meanwhile 62% decrease of water capacity was observed in dry year (2003, when the precipitation sum was 208 mm lower than multiyear average one.

  11. Wastage-resistant characteristics of 12Cr steel tube material. Small leak sodium-water reaction test

    International Nuclear Information System (INIS)

    Shimoyama, Kazuhito

    2004-03-01

    In the water leak accident of a steam generator designed for a sodium cooled reactor in the Feasibility Study, the localization of tube failure propagation by using an advanced water leak detector will be required from the viewpoints of the safety and economical efficiency of the plant. So far, the conventional knowledge and analytical tools have been used in the investigation and evaluation of water leak phenomenon; nevertheless, there was neither test data nor the study of quantitative evaluation on the corrosion behavior, so-called wastage-resistant characteristics, of 12Cr steel tube material in sodium-water reactions. Wastage tests for the 12Cr steel tube material were conducted in small water leaks by use of the Sodium-Water Reaction Test Rig (SWAT-1R), and the data of wastage rate were obtained in the parameter of water leak rate under the constant sodium temperature and distance between leak and target tubes. The test results lead to the following conclusions: (1) The wastage-resistibility of 12Cr steel is 1.6 times greater than that of 9Cr steel and is 2.7 times greater than that of 2.25Cr-1Mo steel. (2)The wastage-resistibility of 12Cr steel increases in smaller water leaks; especially in water leak rates of 1 g/sec or less, it is more excellent than that of SUS321 stainless steel used as Monju superheater tube material. (3) Based on the correlation of wastage rate for the 9Cr steel, the correlation for the 12Cr steel has been obtained to be used for the evaluation of tube failure propagation. As the correlation of wastage rate for the 12Cr steel is based on the correlation for the 9Cr steel, it gives enough conservatism in smaller water leaks. To serve in accurately evaluating the tube failure propagation in smaller water leaks, it is necessary to obtain new correlation of wastage rate for the 12Cr steel based on the data in the wide range of water leak rates. (author)

  12. A study on the performance valuation of small size water storage electric boiler

    International Nuclear Information System (INIS)

    Mo, Joung Gun; Shin, Jae Ho; Bae, Chul Whan; Suh, Jeong Se; Chung, Han Shik; Jeong, Hyo Min

    2003-01-01

    We was made 150L a water storage electric boiler and obtained various performances of the storage, radiant and keeping by experimentation. The storage performance is that the heat were off about 50 minutes after heating start. Then the temperature of outlet was arrived the stead state at 91 deg. C and the storage performance was appeared 93.64%. In the radiant performance, the water temperature was decreased from 90 .deg. C to 44.8 deg. C after 960 minutes. Then the calorific value changed from 675kcal/h to 72kcal/h and the temperature decreased about 50%. The keeping performance showed mean temperature, 67.06 .deg. C according to progress 800 minutes and the maximum temperature drop were 0.2 .deg. C. By the results of the performance valuation, the water storage electric boiler was verified fitted quality on the test prescription of KERI (Korea Electrotechnology Research Institute.)

  13. New Module to Simulate Groundwater-Surface Water Interactions in Small-Scale Alluvial Aquifer System.

    Science.gov (United States)

    Flores, L.

    2017-12-01

    Streamflow depletion can occur when groundwater pumping wells lower water table elevations adjacent to a nearby stream. Being able to accurately model the severity of this process is of critical importance in semi-arid regions where groundwater-surface water interactions affect water rights and the sustainability of water resource practices. The finite-difference flow model MODFLOW is currently the standard for estimating groundwater-surface water interactions in many regions in the western United States. However, certain limitations of the model persist when highly-resolved spatial scales are used to represent the stream-aquifer system, e.g. when the size of computational grid cells is much less than the river width. In this study, an external module is developed and linked with MODFLOW that (1) allows for multiple computational grid cells over the width of the river; (2) computes streamflow and stream stage along the length of the river using the one-dimensional (1D) steady (over a stress period) shallow water equations, which allows for more accurate stream stages when normal flow cannot be assumed or a rating curve is not available; and (3) incorporates a process for computing streamflow loss when an unsaturated zone develops under the streambed. Use of the module not only provides highly-resolved estimates of streamflow depletion, but also of streambed hydraulic conductivity. The new module is applied to the stream-aquifer alluvial system along the South Platte River south of Denver, Colorado, with results tested against field-measured groundwater levels, streamflow, and streamflow depletion.

  14. Practical guidelines for small-volume additions of uninhibited water to waste storage tanks

    International Nuclear Information System (INIS)

    Hsu, T.C.; Wiersma, B.J.; Zapp, P.E.; Pike, J.A.

    1994-01-01

    Allowable volumes of uninhibited water additions to waste tanks are limited to volumes in which hydroxide and nitrite inhibitors reach required concentrations by diffusion from the bulk waste within five days. This diffusion process was modeled conservatively by Fick's second law of diffusion. The solution to the model was applied to all applicable conditions which exist in the waste tanks. Plant engineers adapted and incorporated the results into a practical working procedure for controlling and monitoring the addition of uninhibited water. Research, technical support, and field engineers worked together to produce an effective solution to a potential waste tank corrosion problem

  15. Smart polyelectrolyte microcapsules as carriers for water-soluble small molecular drug.

    Science.gov (United States)

    Song, Weixing; He, Qiang; Möhwald, Helmuth; Yang, Yang; Li, Junbai

    2009-10-15

    Heat treatment is introduced as a simple method for the encapsulation of low molecular weight water-soluble drugs within layer-by-layer assembled microcapsules. A water-soluble drug, procainamide hydrochloride, could thus be encapsulated in large amount and enriched by more than 2 orders of magnitude in the assembled PDADMAC/PSS capsules. The shrunk capsules could control the unloading rate of drugs, and the drugs could be easily unloaded using ultrasonic treatment. The encapsulated amount could be quantitatively controlled via the drug concentration in the bulk. We also found that smaller capsules possess higher encapsulation capability.

  16. Radiation-induced decomposition of small amounts of trichloroethylene in drinking water

    International Nuclear Information System (INIS)

    Proksch, E.; Gehringer, P.; Szinovatz, W.; Eschweiler, H.

    1989-01-01

    Solutions of 10 ppm trichloroethylene in air-saturated drinking waters are decomposed by γ radiation with initial G-values, G 0 , around 3-5 molecules per 100 eV. At lower concentrations, the G 0 -values decrease with decreasing trichloroethylene concentration and with increasing amounts of inorganic (especially HCO 3 - ) and organic solutes. From the results, a semi-empirical formula is derived which allows an estimation of G 0 -values for the trichloroethylene decomposition in drinking waters of given composition. (author)

  17. When land breezes collide: Converging diurnal winds over small bodies of water

    OpenAIRE

    Gille, ST; Llewellyn Smith, SG

    2014-01-01

    © 2013 Royal Meteorological Society. Over enclosed and semi-enclosed bodies of water, the land-breeze/sea-breeze circulation is expected to be modified by the presence of opposing coastlines. These effects are studied using satellite scatterometer surface wind observations from the QuikSCAT and ADEOS-2 tandem mission from April-October 2003. Winds are studied for six bodies of water: the Red Sea, the Gulf of California, the Mediterranean, the Adriatic Sea, the Black Sea and the Caspian Sea. T...

  18. COMPARISON OF MEMBRANE FILTER, MULTIPLE-FERMENTATION-TUBE, AND PRESENCE-ABSENCE TECHNIQUES FOR DETECTING TOTAL COLIFORMS IN SMALL COMMUNITY WATER SYSTEMS

    Science.gov (United States)

    Methods for detecting total coliform bacteria in drinking water were compared using 1483 different drinking water samples from 15 small community water systems in Vermont and New Hampshire. The methods included the membrane filter (MF) technique, a ten tube fermentation tube tech...

  19. Simulation of efficiency impact of drainage water reuse: case of small-scale vegetable growers in North West Province, South Africa

    NARCIS (Netherlands)

    Speelman, S.; Haese, D' M.F.C.; Haese, D' L.

    2011-01-01

    This paper focuses on estimating the effect of drainage water reuse on the technical efficiency of small-scale vegetable growers in South Africa applying a data envelopment analysis (DEA). In the semi-arid North West Province of South Africa water scarcity and the soon to be implemented water

  20. The role of land use and soils in regulating water flow in small headwater catchments of the Andes

    Science.gov (United States)

    Roa-GarcíA, M. C.; Brown, S.; Schreier, H.; Lavkulich, L. M.

    2011-05-01

    Land use changes can have a significant impact on the terrestrial component of the water cycle. This study provides a comparison of three small headwater catchments in the Andean mountains of Colombia with different composition of land use. Several methods were used to quantify differences in the hydrological behavior of these catchments such as flow duration curves, stormflow analysis, and the linear reservoir concept. They were combined with an analysis of the characteristics of soils that contribute to understanding the aggregate catchment hydrological behavior. Andisols, which are soils formed in volcanic areas and with a large capacity to hold water, amplify differences in land use and limit the potential impact of land use management activities (conservation or restoration) on the water regulation function of catchments. Of the three studied catchments, less variability of flows was observed from the catchment with a larger percentage of area in forest, and a slower decrease of flows in the dry season was observed for the catchment with a relatively higher percentage of area in wetlands. Evidence is provided for the infiltration trade-off hypothesis for tropical environments, which states that after forest removal, soil infiltration rates are smaller and the water losses through quick flow are larger than the gains by reduced evapotranspiration; this is compatible with the results of the application of the linear reservoir concept showing a faster release of water for the least forested catchment.

  1. Acoustic Leak Detection under Micro and Small Water Steam Leaks into Sodium for a Protection of the SFR Steam Generator

    International Nuclear Information System (INIS)

    Kim, Tae-Joon; Jeong, Ji-Young; Kim, Jong-Man; Kim, Byung-Ho; Hahn, Do-Hee; Yugay, Valeriy S.

    2008-01-01

    The results of an experimental study of water in a sodium leak noise spectrum formation related with a leak noise attenuation and absorption, and at various rates of water into a sodium leak, smaller than 1.0 g/s, are presented. We focused on studying the micro leak dynamics with an increasing rate of water into sodium owing to a self-development from 0.005 till 0.27 g/s. Conditions and ranges for the existence of bubbling and jetting modes in a water steam outflow into circulating sodium through an injector device, for simulating a defect in a wall of a heat-transmitting tube of a sodium water steam generator were determined. On the basis of the experimental leak noise data the simple dependency of an acoustic signal level from the rate of a micro and small leak at different frequency bands is presented to understand the principal analysis for the development of an acoustic leak detection methodology used in a K- 600 steam generator, with the operational experiences for the noise analysis and measurements in BN-600

  2. Mercury content in wetland rice soil and water of two different seasons at small-scale gold mine processing areas

    Directory of Open Access Journals (Sweden)

    T. Sugianti

    2016-04-01

    Full Text Available This study was aimed to identify the impact of small-scale gold processing activities on mercury content in wetland rice soil and water during the rainy and first dry seasons in Central Lombok and West Lombok Districts. The method used for this study was survey method. Measurement of mercury levels in water samples was conducted at Agro Bogor Centre using SNI 6989.77: 2011 methods. The data was collected and processed in a simple statistic presented descriptively, in order to obtain information. Results of the study showed that mercury content soils in the rainy season exceeded the threshold of 0.005 ppm, while in the first dry season the mercury content in soil decreased, but it was still above the threshold value permitted. The contents of mercury in water samples in the rainy season and the first dry season were still at a safe point that was less than 0.05 ppm. The wetland rice soil and water had been polluted with mercury, although the mercury content in the water was still below the threshold, but the accumulation of mercury that could have been absorbed by the plants are of particular concerns. The decrease of mercury content in soil in dry season was due to lack of gold processing activities.

  3. Assessment of water quality based on diatom indices in a small ...

    African Journals Online (AJOL)

    2016-04-02

    Apr 2, 2016 ... single metric which is used to indicate the degree of impact. (Taylor et al. ... comparison of diatom-based water quality results, and are an additional reason for ...... establishing a framework for Community action in the field of.

  4. Interlaboratory validation of small-scale solubility and dissolution measurements of poorly water-soluble drugs

    DEFF Research Database (Denmark)

    Andersson, Sara B. E.; Alvebratt, Caroline; Bevernage, Jan

    2016-01-01

    The purpose of this study was to investigate the interlaboratory variability in determination of apparent solubility (Sapp) and intrinsic dissolution rate (IDR) using a miniaturized dissolution instrument. Three poorly water-soluble compounds were selected as reference compounds and measured at m...

  5. Effect of Strip Mining on Water Quality in Small Streams in Eastern Kentucky, 1967-1975

    Science.gov (United States)

    Kenneth L. Dyer; Willie R. Curtis

    1977-01-01

    Eight years of streamflow data are analyzed to show the effects of strip mining on chemical quality of water in six first-order streams in Breathitt County, Kentucky. All these watersheds were unmined in August, 1967, but five have since been strip mined. The accumulated data from this case history study indicate that strip mining causes large increases in the...

  6. Adoption patterns and constraints pertaining to small-scale water lifting technologies in Ghana

    NARCIS (Netherlands)

    Namara, R.E.; Hope, L.; Sarpong, E.; Fraiture, de C.M.S.; Owusu, D.

    2014-01-01

    Irrigation is a priority development agenda item in Ghana and other countries in sub-Saharan Africa. There is a genuine endeavor to increase public and large-scale private investment in the sector. The on-going smallholder-driven private irrigation development that is largely based on water lifting

  7. USEPA'S SMALL DRINKING WATER TREATMENT TECHNOLOGY DEMONSTRATIONS IN ECUADOR AND MEXICO

    Science.gov (United States)

    In order to support and help in the struggle to improve the quality of drinking water in the United States and abroad, the United States Environmental Protection Agency (USEPA) conducts research studies for the demonstration and evaluation of alternative and innovative drinking w...

  8. A spreadsheet tool for the analysis of flows in small-scale water piping networks

    CSIR Research Space (South Africa)

    Adedeji, KB

    2017-07-01

    Full Text Available and the hybrid method to mention but a few, to solve a system of partly linear, and partly non-linear hydraulic equations. In this paper, the authors demonstrate the use of Excel solver to verify the Hardy Cross method for the analysis of flow in water piping...

  9. The protonation state of small carboxylic acids at the water surface from photoelectron spectroscopy

    Czech Academy of Sciences Publication Activity Database

    Ottosson, N.; Wernersson, Erik; Söderström, J.; Pokapanich, W.; Kaufmann, S.; Svensson, S.; Persson, I.; Öhrwall, G.; Björneholm, O.

    2011-01-01

    Roč. 13, č. 26 (2011), s. 12261-12267 ISSN 1463-9076 Institutional research plan: CEZ:AV0Z40550506 Keywords : water surface * carboxylic acids * photoelectron spectroscopy Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.573, year: 2011

  10. HYDROMORPHOLOGICAL EFFECT OF INTRODUCING SMALL WATER STRUCTURES IN RIVER RESTORATION – THE EXAMPLE OF PBHS IMPLEMENTATION

    Directory of Open Access Journals (Sweden)

    Tomasz Kałuża

    2016-04-01

    Full Text Available The work attempts to determine the impact of small hydrotechnical structures on channel hydromorphology as a measure of river restoration. The experiment was set up in Flinta River in Polish lowland where extensive hydromorphological survey was competed. At the first stage of restoration project containers filled with plant clumps working as sediment traps (plant basket hydraulic structures – PBHS were introduced. Those structures were relatively small but at the same time, large enough to change the river flow efficiently – working like low crested weirs. Two year monitoring program provided information about the impact of introducing such structures on river morphology and explained the PBHS impact on flow pattern of the river.

  11. Small water courses for electric power generation; Mit wenig Wasser zum Fliessen bringen

    Energy Technology Data Exchange (ETDEWEB)

    Ossberger, K.F.; Wirth, D. [Ossberger Turbinenfabrik GmbH und Co, Weissenburg (Germany)

    1997-12-31

    In principle, no one nowadays doubts the usefulness of small hydroelectric installations. Hydro power is a renewable energy source. Contrary to oil, gas or coal, the energy source is not consumed. Hydroelectric power generation neither gives rise to atmospheric pollution nor does it cause residual products; it is environment-friendly. Moreover, the energy used is a native one. These arguments no doubt advocate the broadest possible use of hydro power, especially also in the form of small hydroelectric installations. (orig.) [Deutsch] Grundsaetzlich gibt es heutzutage keinen Zweifel am Nutzen von Kleinkraftwerken. Die Wasserkraft ist eine regenerierbare Energiequelle. Im Gegensatz etwa zu Oel, Gas oder Kohle wird der Energietraeger Wasser beim Nutzungsvorgang nicht aufgebraucht. Die Stromerzeugung aus Wasserkraft belastet die Umwelt weder durch Luftschadstoffe noch Rueckstaende, sie ist umweltfreundlich. Und man nutzt damit einheimische Energie. Gewichtige Argumente zweifellos, die fuer eine moeglichst weitgehende Wasserkraftnutzung, gerade auch in Kleinkraftwerken, sprechen. (orig.)

  12. Challenge to the model of lake charr evolution: Shallow- and deep-water morphs exist within a small postglacial lake

    Science.gov (United States)

    Chavarie, Louise; Muir, Andrew M.; Zimmerman, Mara S.; Baillie, Shauna M.; Hansen, Michael J.; Nate, Nancy A.; Yule, Daniel L.; Middel, Trevor; Bentzen, Paul; Krueger, Charles C.

    2016-01-01

    All examples of lake charr (Salvelinus namaycush) diversity occur within the largest, deepest lakes of North America (i.e. > 2000 km2). We report here Rush Lake (1.3 km2) as the first example of a small lake with two lake charr morphs (lean and huronicus). Morphology, diet, life history, and genetics were examined to demonstrate the existence of morphs and determine the potential influence of evolutionary processes that led to their formation or maintenance. Results showed that the huronicus morph, caught in deep-water, had a deeper body, smaller head and jaws, higher eye position, greater buoyancy, and deeper peduncle than the shallow-water lean morph. Huronicus grew slower to a smaller adult size, and had an older mean age than the lean morph. Genetic comparisons showed low genetic divergence between morphs, indicating incomplete reproductive isolation. Phenotypic plasticity and differences in habitat use between deep and shallow waters associated with variation in foraging opportunities seems to have been sufficient to maintain the two morphs, demonstrating their important roles in resource polymorphism. Rush Lake expands previous explanations for lake charr intraspecific diversity, from large to small lakes and from reproductive isolation to the presence of gene flow associated with strong ecological drivers.

  13. Pore water pressure response to small and large openings in argillaceous rocks

    International Nuclear Information System (INIS)

    Garitte, B.; Gens, A.; Vaunat, J.; Armand, G.; Conil, N.

    2012-01-01

    Document available in extended abstract form only. In the last decade an important amount of piezometers have been installed in the Bure Underground Rock Laboratory (URL) in the vicinity of ongoing works involving gallery excavations and drilling of boreholes and alveoles both in the major and minor stress directions. Relatively far field piezometers (placed one to four diameters from the excavation wall) showed a qualitatively consistent response at different scales. Here, we investigate whether the pore water pressure response around openings of different scales may be up-scaled. An attempt is made to find a common set of parameters that explains quantitatively the rock response at the different scales. The mechanisms underlying the pore water pressure response around an underground opening are twofold. The first class of mechanisms is usually associated with nearly undrained behaviour and the related pore water pressure changes are induced by the stress redistribution triggered by the creation of the tunnel opening causing a reorientation of the principal stresses and influenced by the initial stress anisotropy. These pore water pressure changes are closely linked to the mechanical constitutive law of the rock and to the damage zone around the opening. The second class of mechanisms is related to the drainage of excess pore water pressure relative to a state governed by the atmospheric water pressure condition prescribed at gallery wall and the water flow law, usually Darcy's. Strong anisotropy effects on the hydraulic response of Callovo-Oxfordian Clay can be observed with reference to Figure 1 that shows the pore pressure response to the drilling of a 150 mm-diameter borehole performed to install a heater for the TER thermal experiment. The borehole is aligned with the major horizontal principal stress. Therefore, in principle, the stress state should be approximately isotropic in a cross section of the borehole. As a matter of fact, however, a degree of

  14. Outline for Compiling Precipitation, Runoff, and Ground Water Data from Small Watersheds

    Science.gov (United States)

    Edward A. Johnson; Robert E. Dils

    1956-01-01

    This is a revision of Technical Note No. 34, first.issued in 1938 by C. R. Hursh. Reissues in 1939 and 1940 included numerous valuable suggestions for improvements from co-workers in the field of small drainage-area studies. Since the last issue in 1940, additions and deletions in both procedures and forms have been effected. In the present edition these changes have...

  15. Characterization of atmospheric deposition and runoff water on a small suburban catchment

    OpenAIRE

    LAMPREA, Diana Katerine; RUBAN, Véronique

    2011-01-01

    A study of air quality and atmospheric deposition on a small urban catchment (Pin Sec catchment) has been carried out in Nantes, France, in 2007 and 2008 in the frame of a federative project aimed at understanding the origin of pollution in urban environments. Carbon monoxide, nitrogen monoxide, nitrogen dioxide, ozone, sulphur dioxide and particles less than 10 µm (PM 10) were monitored for air quality, whereas heavy metals, Polycyclic aromatic hydrocarbons (PAHs) and pesticides were analyze...

  16. Synthesis of underreported small-scale fisheries catch in Pacific island waters

    Science.gov (United States)

    Zeller, D.; Harper, S.; Zylich, K.; Pauly, D.

    2015-03-01

    We synthesize fisheries catch reconstruction studies for 25 Pacific island countries, states and territories, which compare estimates of total domestic catches with officially reported catch data. We exclude data for the large-scale tuna fleets, which have largely foreign beneficial ownership, even when flying Pacific flags. However, we recognize the considerable financial contributions derived from foreign access or charter fees for Pacific host countries. The reconstructions for the 25 entities from 1950 to 2010 suggested that total domestic catches were 2.5 times the data reported to FAO. This discrepancy was largest in early periods (1950: 6.4 times), while for 2010, total catches were 1.7 times the reported data. There was a significant difference in trend between reported and reconstructed catches since 2000, with reconstructed catches declining strongly since their peak in 2000. Total catches increased from 110,000 t yr-1 in 1950 (of which 17,400 t were reported) to a peak of over 250,000 t yr-1 in 2000, before declining to around 200,000 t yr-1 by 2010. This decrease is driven by a declining artisanal (small-scale commercial) catch, which was not compensated for by increasing domestic industrial (large-scale commercial) catches. The artisanal fisheries appear to be declining from a peak of 97,000 t yr-1 in 1992 to less than 50,000 t yr-1 by 2010. However, total catches were dominated by subsistence (small-scale, non-commercial) fisheries, which accounted for 69 % of total catches, with the majority missing from the reported data. Artisanal catches accounted for 22 %, while truly domestic industrial fisheries accounted for only 6 % of total catches. The smallest component is the recreational (small-scale, non-commercial and largely for leisure) sector (2 %), which, although small in catch, is likely of economic importance in some areas due to its direct link to tourism income.

  17. Small, mobile, persistent: Trifluoroacetate in the water cycle - Overlooked sources, pathways, and consequences for drinking water supply.

    Science.gov (United States)

    Scheurer, Marco; Nödler, Karsten; Freeling, Finnian; Janda, Joachim; Happel, Oliver; Riegel, Marcel; Müller, Uwe; Storck, Florian Rüdiger; Fleig, Michael; Lange, Frank Thomas; Brunsch, Andrea; Brauch, Heinz-Jürgen

    2017-12-01

    Elevated concentrations of trifluoroacetate (TFA) of more than 100 μg/L in a major German river led to the occurrence of more than 20 μg/L TFA in bank filtration based tap waters. Several spatially resolved monitoring programs were conducted and discharges from an industrial company were identified as the point source of TFA contamination. Treatment options for TFA removal were investigated at full-scale waterworks and in laboratory batch tests. Commonly applied techniques like ozonation or granulated activated carbon filtration are inappropriate for TFA removal, whereas TFA was partly removed by ion exchange and completely retained by reverse osmosis. Further investigations identified wastewater treatment plants (WWTPs) as additional TFA dischargers into the aquatic environment. TFA was neither removed by biological wastewater treatment, nor by a retention soil filter used for the treatment of combined sewer overflows. WWTP influents can even bear a TFA formation potential, when appropriate CF 3 -containing precursors are present. Biological degradation and ozonation batch experiments with chemicals of different classes (flurtamone, fluopyram, tembotrione, flufenacet, fluoxetine, sitagliptine and 4:2 fluorotelomer sulfonate) proved that there are yet overlooked sources and pathways of TFA, which need to be addressed in the future. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Surface fluxes and water balance of spatially varying vegetation within a small mountainous headwater catchment

    Directory of Open Access Journals (Sweden)

    G. N. Flerchinger

    2010-06-01

    Full Text Available Precipitation variability and complex topography often create a mosaic of vegetation communities in mountainous headwater catchments, creating a challenge for measuring and interpreting energy and mass fluxes. Understanding the role of these communities in modulating energy, water and carbon fluxes is critical to quantifying the variability in energy, carbon, and water balances across landscapes. The focus of this paper was: (1 to demonstrate the utility of eddy covariance (EC systems in estimating the evapotranspiration component of the water balance of complex headwater mountain catchments; and (2 to compare and contrast the seasonal surface energy and carbon fluxes across a headwater catchment characterized by large variability in precipitation and vegetation cover. Eddy covariance systems were used to measure surface fluxes over sagebrush (Artemesia arbuscula and Artemesia tridentada vaseyana, aspen (Populus tremuloides and the understory of grasses and forbs beneath the aspen canopy. Peak leaf area index of the sagebrush, aspen, and aspen understory was 0.77, 1.35, and 1.20, respectively. The sagebrush and aspen canopies were subject to similar meteorological forces, while the understory of the aspen was sheltered from the wind. Missing periods of measured data were common and made it necessary to extrapolate measured fluxes to the missing periods using a combination of measured and simulated data. Estimated cumulative evapotranspiratation from the sagebrush, aspen trees, and aspen understory were 384 mm, 314 mm and 185 mm. A water balance of the catchment indicated that of the 699 mm of areal average precipitation, 421 mm was lost to evapotranspiration, and 254 mm of streamflow was measured from the catchment; water balance closure for the catchment was within 22 mm. Fluxes of latent heat and carbon for all sites were minimal through the winter. Growing season fluxes of latent heat and carbon were consistently higher

  19. Contingency power for small turboshaft engines using water injection into turbine cooling air

    Science.gov (United States)

    Biesiadny, Thomas J.; Berger, Brett; Klann, Gary A.; Clark, David A.

    1987-01-01

    Because of one engine inoperative requirements, together with hot-gas reingestion and hot day, high altitude takeoff situations, power augmentation for multiengine rotorcraft has always been of critical interest. However, power augmentation using overtemperature at the turbine inlet will shorten turbine life unless a method of limiting thermal and mechanical stresses is found. A possible solution involves allowing the turbine inlet temperature to rise to augment power while injecting water into the turbine cooling air to limit hot-section metal temperatures. An experimental water injection device was installed in an engine and successfully tested. Although concern for unprotected subcomponents in the engine hot section prevented demonstration of the technique's maximum potential, it was still possible to demonstrate increases in power while maintaining nearly constant turbine rotor blade temperature.

  20. Contingency power for a small turboshaft engine by using water injection into turbine cooling air

    Science.gov (United States)

    Biesiadny, Thomas J.; Klann, Gary A.

    1992-01-01

    Because of one-engine-inoperative (OEI) requirements, together with hot-gas reingestion and hot-day, high-altitude take-off situations, power augmentation for multiengine rotorcraft has always been of critical interest. However, power augmentation by using overtemperature at the turbine inlet will shorten turbine life unless a method of limiting thermal and mechanical stress is found. A possible solution involves allowing the turbine inlet temperature to rise to augment power while injecting water into the turbine cooling air to limit hot-section metal temperatures. An experimental water injection device was installed in an engine and successfully tested. Although concern for unprotected subcomponents in the engine hot section prevented demonstration of the technique's maximum potential, it was still possible to demonstrate increases in power while maintaining nearly constant turbine rotor blade temperature.

  1. Small zeolite column tests for removal of cesium from high radioactive contaminated water in Fukushima Daiichi Nuclear Power Station

    International Nuclear Information System (INIS)

    Hijikata, Takatoshi; Uozumi, Koichi; Tukada, Takeshi; Koyama, Tadafumi; Ishikawa, Keiji; Ono, Shoichi; Suzuki, Shunichi; Denton, Mark; Raymont, John

    2011-01-01

    After the earthquake on March 11th 2011, a large amount (more than 0.12 million m 3 ) of highly radioactive contaminated water had pooled in Fukushima Daiichi nuclear power station. As an urgent issue, highly radioactive nuclides should be removed from this contaminated water to reduce radioactivity in the turbine buildings and nuclear reactor buildings. Removal of Cs from this contaminated water is a key issue, because 134 Cs and 137 Cs are highly radioactive γ-emitting nuclides. The zeolite column system was used for Cs and Sr removal from the radioactive water of Three-Mile Island Unit 2, and modified columns were then developed as a Cs removal method for high-level radioactive water in US national laboratories (WRSC, ORNL, PNNL, Hanford, etc.). In order to treat Fukushima's highly contaminated water with a similar system, it was necessary to understand the properties of zeolite to remove Cs from sea salt as well as the applicability of the column system to a high throughput of around 1200 m 3 /d. The kinetic characteristics of the column were another property to be understood before actual operation. Hence, a functional small-scale zeolite column system was installed in CRIEPI for conducting the experiments to understand decontamination behaviors. Each column has a 2- or 3-cm inner diameter and a 12-cm height, and 12 g of zeolite-type media was packed into the column. The column experiments were carried out with Kurion-zeolite, Herschelite, at different feed rates of simulated water with different concentrations of Cs and sea salt. As for the water with 4 ppm Cs and 0 ppm sea salt, only a 10% Cs concentration was observed in the effluent after 20,000 bed volumes were fed at a rate of 33 cm/min, which corresponds to the actual system. On the other hand, a 40% Cs concentration was observed in the effluent after only 50 bed volumes were passed for water with 2 ppm Cs and 3.4 wt.% sea salt at a feed rate of 34 cm/min. As the absorption of Cs is hampered by the

  2. Interstitial water studies on small core samples, Deep Sea Drilling Project, Leg 5

    Science.gov (United States)

    Manheim, F. T.; Chan, K.M.; Sayles, F.L.

    1970-01-01

    Leg 5 samples fall into two categories with respect to interstitial water composition: 1) rapidly deposited terrigenous or appreciably terrigenous deposits, such as in Hole 35 (western Escanaba trough, off Cape Mendocino, California); and, 2) slowly deposited pelagic clays and biogenic muds and oozes. Interstitial waters in the former show modest to slight variations in chloride and sodium, but drastic changes in non-conservative ions such as magnesium and sulfate. The pelagic deposits show only relatively minor changes in both conservative and non-conservative pore fluid constituents. As was pointed out in earlier Leg Reports, it is believed that much of the variation in chloride in pore fluids within individual holes is attributable to the manipulation of samples on board ship and in the laboratory. On the other hand, the scatter in sodium is due in part to analytical error (on the order of 2 to 3 per cent, in terms of a standard deviation), and it probably accounts for most of the discrepancies in total anion and cation balance. All constituents reported here, with the exception of bulk water content, were analyzed on water samples which were sealed in plastic tubes aboard ship and were subsequently opened and divided into weighed aliquots in the laboratory. Analytical methods follow the atomic absorption, wet chemical and emission spectrochemical techniques briefly summarized in previous reports, e.g. Manheim et al., 1969, and Chan and Manheim, 1970. The authors acknowledge assistance from W. Sunda, D. Kerr, C. Lawson and H. Richards, and thank D. Spencer, P. Brewer and E. Degens for allowing the use of equipment and laboratory facilities.

  3. Development of hot water supply system for a small district heating reactor

    International Nuclear Information System (INIS)

    Murase, Toshihiko; Narabayashi, Tadashi; Shimazu, Yoichiro

    2007-01-01

    On the earth, there are many environmental problems. For example, rapid increase of world population causes the enormous consumption of fossil fuel and emission of CO 2 into the global air. Now, mankaind faced to deal with these serious problems. One solution for these problems is utilization of nuclear reactors. Currently, about 65% of thermal output of a nuclear reactor is thrown away to the sea or the atmosphere through a turbine condenser. When a hot-water pipeline from a nuclear plant will be constructed, the exhaust heat from nuclear reactor will able to be utilized. Therefore, authors began to study nuclear power plant system for district heating. This reactor is based on a PWR plant. Its thermal output is 10 MWth and its electrical output is 3.4 MW. The nuclear plant supply electricity and heat for 2000 to 3000 houses. The plant aim to supply all the energy for the adjacent pepole's life, for example, heat, electricity and hydrogen for fuel battery car. This total-energy supply system assumed to be built in Northern area such as Hokkaido in Japan. In order to develop an optimum thermal design method for the system, heat transport experiments and thermal-hydraulic calculations were carried out. Using a metal pipe covered with foam-polyurethane thermal insulator, feed-water temperature and return-water temperature was measured to evaluate heat loss. As the result, the heat loss from the hot-water temperature was very little. The thermal-hydraulic calculation method was verified and applied to actual pipeline size calculation. The result of heat loss calculation will be 0.2degC/5 km. considering these results, the best pipe specification was obtained. (author)

  4. On the physicochemical states of heavy metals of very small amounts in river water

    International Nuclear Information System (INIS)

    Aoyama, Isao; Inoue, Yoriteru; Hashimoto, Noriaki.

    1976-01-01

    The physicochemical existence states of the heavy metals in river water were experimentally studied, with radioactive nuclides as tracers. The experimental samples taken from Kamo-river in the city of Kyoto were filtered through a membrane filter of 0.45 μm pore diameter. The radioactive nuclides of heavy metal tracers were added into the sample water, and pH was adjusted to the given value with hydrochloric solution on the acidic side and with sodium hydroxide solution on the alkaline side. After two days aging, the radioactivity ratios of the sediments on membrane filters to that of total passed samples were measured. The variation in the course of time of the concentrations of ionic tracers dialysed with cellulose tubes (24 angstrom pore diameter) was traced until the equilibrium condition was reached. The radioactivity of the supernatant of 20 ml of sample water added with 0.5 g of anion or cation exchange resin, and the concentrations of tracers in the upper layer of liquid in a centrifuge were measured. The existing conditions of elements such as zinc, cadmium, cobalt, strontium-yttrium were examined. In conclusion, the adsorption of all nuclides on the membrane filters increased with the increase of pH, but the significant difference was not recognized owing to the pore diameter (1.2 μm - 0.05 μm) excepting some experimental results. (Iwakiri, K.)

  5. Development of a water recirculating system for bullfrog production: technological innovation for small farmers

    Directory of Open Access Journals (Sweden)

    Sílvia Conceição Reis Pereira Mello

    2016-02-01

    Full Text Available ABSTRACT Despite the technological progress in frog farming, issues related to the environment, biosafety, and the use of technologies that minimise environmental impacts are frequently neglected by farmers. With the goal of developing a low-cost technology for reuse and preservation of water quality, an anaerobic filtering system combined with an aerobic filtering system was implemented in the grow-out sector in the Frog Culture Research Unit at Fundação Instituto de Pesca do Estado do Rio de Janeiro (FIPERJ. The filtering system received the effluent from six pens of frogs that were populated with 362 frogs in different development phases. The efficiency of the filtering system was evaluated by an analysis of the water before and after passing through the filters. In addition to the standards of water quality, the animals' performance was also observed through monitoring rates of survival, weight gain and feed conversion ratio. The results showed the effectiveness of the filtering system by removing organic matter, on average 87%. The values of total ammonia and non-ionisable reached 1.04 and 0.004 mg/L, respectively. Also, frogs subjected to the system presented satisfactory rates of weight gain and a high survival rate (97%.

  6. Preliminary Study of Feasibility of Acoustic Detection of Small Sodium-Water Reactions in Lmfbr Steam Generators.

    Energy Technology Data Exchange (ETDEWEB)

    Chamberlain, H. V.

    1970-06-01

    An evaluation of acoustic techniques for the detection of sound resulting from water leaks into liquid sodium was conducted. Acoustic spectra over the range of 100Hz to 80kHz were detected. A leak as small as 0.00008 lb/ sec was detected by the acoustic instrumentation. The indicated leak rate was the smallest that was injected into the liquid sodium, and is not to be interpreted as the smallest leak rate that might be detected by the acoustic method. Detection time was found to be essentially instantaneous.

  7. Multi-stage-flash desalination plants of relative small performance with integrated pressurized water reactors as a nuclear heat source

    International Nuclear Information System (INIS)

    Petersen, G.; Peltzer, M.

    1977-01-01

    In the Krupp-GKSS joint study MINIPLEX the requirements for seawater-desalination plants with a performance in the range of 10 000 to 80 000 m 3 distillate per day heated by a nuclear reactor are investigated. The reactor concept is similar to the Integrated Pressurized Water Reactor (IPWR) of the nuclear ship OTTO HAHN. The design study shows that IPWR systems have specific advantages up to 200 MWth compared to other reactor types at least being adapted for single- and dual-purpose desalination plants. The calculated costs of the desalinated water show that due to fuel cost advantages of reactors small and medium nuclear desalination plants are economically competetive with oil-fired plants since the steep rise of oil price in autumn 1973. (author)

  8. Small hydropower plant in Ruetenen - Drainage water utilization from the Alpine motor way tunnel 'Seelisberg' in Switzerland

    International Nuclear Information System (INIS)

    Odermatt, K.; Ettlin, M.

    2001-01-01

    This report for the Swiss Federal Office of Energy (SFOE) describes a project that uses the drainage water from the Seelisberg motor way tunnel in central Switzerland to drive a small turbine that uses the fall distance between the collection point near the tunnel portal and the lake of Lucerne, which lies 48 meters below, to generate more than 100 kW of electrical power. The operation of the hydraulic power station and the experience gained during initial operation are described and the somewhat erratic amounts of water - depending on rainfall, snow-melting etc. - are discussed. Figures are given on the building and operational costs, electricity production and the price of the electricity produced. The report is illustrated with technical drawings and photos of the installation

  9. Iodine-131 in sewage sludge from a small water pollution control plant serving a thyroid cancer treatment facility.

    Science.gov (United States)

    Rose, Paula S; Swanson, R Lawrence

    2013-08-01

    Iodine-131 (half-life = 8.04 d) is the most widely used radionuclide in medicine for therapeutic purposes. It is excreted by patients and is discharged directly to sewer systems. Despite considerable dilution in waste water and the relatively short half-life of I, it is readily measured in sewage. This work presents I concentrations in sewage sludge from three water pollution control plants (WPCPs) on Long Island, NY. Iodine-131 concentrations ranged from 0.027 ± 0.002 to 148 ± 4 Bq g dry weight. The highest concentrations were measured in the Stony Brook WPCP, a relatively small plant (average flow = 6.8 × 10 L d) serving a regional thyroid cancer treatment facility in Stony Brook, NY. Preliminary radiation dose calculations suggested further evaluation of dose to treatment plant workers in the Stony Brook WPCP based on the recommendations of the Interagency Steering Committee on Radiation Standards.

  10. Potential for Small Unmanned Aircraft Systems Applications for Identifying Groundwater-Surface Water Exchange in a Meandering River Reach

    Science.gov (United States)

    Pai, H.; Malenda, H. F.; Briggs, M. A.; Singha, K.; González-Pinzón, R.; Gooseff, M. N.; Tyler, S. W.

    2017-12-01

    The exchange of groundwater and surface water (GW-SW), including dissolved constituents and energy, represents a critical yet challenging characterization problem for hydrogeologists and stream ecologists. Here we describe the use of a suite of high spatial resolution remote sensing techniques, collected using a small unmanned aircraft system (sUAS), to provide novel and complementary data to analyze GW-SW exchange. sUAS provided centimeter-scale resolution topography and water surface elevations, which are often drivers of exchange along the river corridor. Additionally, sUAS-based vegetation imagery, vegetation-top elevation, and normalized difference vegetation index mapping indicated GW-SW exchange patterns that are difficult to characterize from the land surface and may not be resolved from coarser satellite-based imagery. We combined these data with estimates of sediment hydraulic conductivity to provide a direct estimate of GW "shortcutting" through meander necks, which was corroborated by temperature data at the riverbed interface.

  11. Sea-water/groundwater interactions along a small catchment of the European Atlantic coast

    International Nuclear Information System (INIS)

    Einsiedl, Florian

    2012-01-01

    The geochemistry and isotopic composition of a karstic coastal aquifer in western Ireland has shed light on the effect of sea-water/groundwater interactions on the water quality of Ireland’s Atlantic coastal zone. The use of stable isotope data from the IAEA precipitation station in Valentia, located in SW Ireland has facilitated the characterization of groundwater recharge conditions in the western part of Ireland and suggests that groundwater is mostly replenished by the isotopically light winter precipitation. The dissolved SO 4 2- in the karstic groundwater that was collected during baseflow conditions with δ 34 S values between 4.6‰ and 18‰ may be composed of S stemming from three principal sources: SO 4 2- derived from precipitation which is composed of both sea-spray S (δ 34 S: 20‰) and an isotopically light anthropogenic source (δ 34 S: 1–5‰), SO 4 2- stemming from animal slurries (δ 34 S: ∼5‰), and intruding sea-water SO 4 2- (δ 34 S: 20.2‰). The isotopic composition of δ 18 O in dissolved groundwater SO 4 2- collected during baseflow conditions is interpreted as reflecting sea-water intrusion to the karstic coastal groundwater system. The highest δ 18 O values in dissolved groundwater SO 4 2- were in samples collected near the coast (4.8 ± 0.4‰) and the lowest (2 ± 0.5‰) were collected further inland. The δ 15 N and δ 18 O values of groundwater NO 3 - were between 3.4‰ and 11.4‰ and approximately 7.7‰, respectively, and reflect geochemical conditions in the aquifer that do not promote attenuation of NO 3 - through denitrification. As a result N loading to Kinvara Bay that is controlled by submarine groundwater discharge (SGD) was calculated as 5 tons/day on average compared to an estimated N-input that derives from precipitation of approximately 2.5 tons/a. SGD into the bay may result in near coastal sea-water quality changes. These results represent one of the first studies addressing the effect of groundwater

  12. Water quality of small seasonal wetlands in the Piedmont ecoregion, South Carolina, USA: Effects of land use and hydrological connectivity.

    Science.gov (United States)

    Yu, Xubiao; Hawley-Howard, Joanna; Pitt, Amber L; Wang, Jun-Jian; Baldwin, Robert F; Chow, Alex T

    2015-04-15

    Small, shallow, seasonal wetlands with short hydroperiod (2-4 months) play an important role in the entrapment of organic matter and nutrients and, due to their wide distribution, in determining the water quality of watersheds. In order to explain the temporal, spatial and compositional variation of water quality of seasonal wetlands, we collected water quality data from forty seasonal wetlands in the lower Blue Ridge and upper Piedmont ecoregions of South Carolina, USA during the wet season of February to April 2011. Results indicated that the surficial hydrological connectivity and surrounding land-use were two key factors controlling variation in dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) in these seasonal wetlands. In the sites without obvious land use changes (average developed area land use changes. The connected wetlands in more urbanized areas (average developed area = 12.3%) showed higher concentrations of dissolved organic matter (DOM) (DOC: 11.76 ± 6.09 mg L(-1), TDN: 0.74 ± 0.22 mg L(-1), mean ± standard error) compared to those in isolated wetlands (DOC: 7.20 ± 0.62 mg L(-1), TDN: 0.20 ± 0.08 mg L(-1)). The optical parameters derived from UV and fluorescence also confirmed significant portions of protein-like fractions likely originating from land use changes such as wastewater treatment and livestock pastures. The average of C/N molar ratios of all the wetlands decreased from 77.82 ± 6.72 (mean ± standard error) in February to 15.14 ± 1.58 in April, indicating that the decomposition of organic matter increased with the temperature. Results of this study demonstrate that the water quality of small, seasonal wetlands has a direct and close association with the surrounding environment. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Combined stable isotope trajectories for water-rock interaction

    International Nuclear Information System (INIS)

    Blattner, P.; Department of Scientific and Industrial Research, Lower Hutt

    1981-01-01

    The 'mixed' model of water-rock interaction (1980 Workshop) is explained in detail. Based on the magnitude of the oxygen isotope shifts of their recharge water, different geothermal systems can be placed in an evolutionary series, from incipient (large shift of water) to mature (small shift of water). Isotopes of different chemical elements may be combined, to yield a stringent test of whether or not a given change in rock composition may be ascribed to interaction with water (L-shaped trajectories). For the acidic eruptives of the Taupo Volcanic Zone, available strontium and oxygen isotope data practically rule out an origin by partial melting of greywacke basement

  14. Phosphorus and nitrogen removal in waste water at small factory. Shokibo jigyosho ni okeru haisuichu no rin chisso shori gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Hirai, M. (National Institute for Resources and Environment, Tsukuba (Japan))

    1994-05-25

    For the purpose of preventing closed waters from eutrophicating, COD regulations and nitrogen and phosphorus waste water regulations are executed in Japan, but practically applicable techniques for this purpose are a few. Concerning technology for removing nitrogen and phosphorus in waste water, this paper describes the actual situation of two industries, electroplating and alumite processing, and applicable techniques. Among various nitrogen removal methods, the biological treatment method has been used practically in many cases and is applicable to practical use. While there are many kinds of physical and chemical treatment methods, applicable methods are limited. In removing nitrogen, the coagulating sedimentation method with Ca salt, Al salt and Fe salt is effective generally for orthophosphate. At electroplating factories, various forms of phosphorus and nitrogen compounds are used as plating chemicals. In treating waste water containing phosphorus, the coagulating sedimentation method is used most frequently. The oxidation + coagulating sedimentation method, the autolysis + oxidation coagulation method, and the evaporation method are effected, though the examples of their implementation are small in number. 15 tabs.

  15. Models for estimation of the presence of non-regulated disinfection by-products in small drinking water systems.

    Science.gov (United States)

    Guilherme, Stéphanie; Rodriguez, Manuel J

    2017-10-23

    Among all the organic disinfection by-products (DBPs), only trihalomethanes (THMs) and haloacetic acids (HAAs) are regulated in drinking water, while most DBPs are not. Very little information exists on the occurrence of non-regulated DBPs, particularly in small water systems (SWS). Paradoxically, SWS are more vulnerable to DBPs because of a low capacity to implement adequate treatment technologies to remove DBP precursors. Since DBP analyses are expensive, usually SWS have difficulties to implement a rigorous characterization of these contaminants. The purpose of this study was to estimate non-regulated DBP levels in SWS from easy measurements of relevant parameters regularly monitored. Since no information on non-regulated DBPs in SWS was available, a sampling program was carried out in 25 SWS in two provinces of Canada. Five DBP families were investigated: THMs, HAAs, haloacetonitriles (HANs), halonitromethanes (HNMs), and haloketones (HKs). Multivariate linear mixed regression models were developed to estimate HAN, HK, and HNM levels from water quality characteristics in the water treatment plant, concentrations of regulated DBPs, and residual disinfectant levels. The models obtained have a good explanatory capacity since R 2 varies from 0.77 to 0.91 according to compounds and conditions for application (season and type of treatment). Model validation with an independent database suggested their ability for generalization in similar SWS in North America.

  16. Investigating the significance of zero-point motion in small molecular clusters of sulphuric acid and water

    International Nuclear Information System (INIS)

    Stinson, Jake L.; Ford, Ian J.; Kathmann, Shawn M.

    2014-01-01

    The nucleation of particles from trace gases in the atmosphere is an important source of cloud condensation nuclei, and these are vital for the formation of clouds in view of the high supersaturations required for homogeneous water droplet nucleation. The methods of quantum chemistry have increasingly been employed to model nucleation due to their high accuracy and efficiency in calculating configurational energies; and nucleation rates can be obtained from the associated free energies of particle formation. However, even in such advanced approaches, it is typically assumed that the nuclei have a classical nature, which is questionable for some systems. The importance of zero-point motion (also known as quantum nuclear dynamics) in modelling small clusters of sulphuric acid and water is tested here using the path integral molecular dynamics method at the density functional level of theory. The general effect of zero-point motion is to distort the mean structure slightly, and to promote the extent of proton transfer with respect to classical behaviour. In a particular configuration of one sulphuric acid molecule with three waters, the range of positions explored by a proton between a sulphuric acid and a water molecule at 300 K (a broad range in contrast to the confinement suggested by geometry optimisation at 0 K) is clearly affected by the inclusion of zero point motion, and similar effects are observed for other configurations

  17. Time evolution simulation of heat removal in a small water tank by natural convection

    Energy Technology Data Exchange (ETDEWEB)

    Freitas, Carlos Alberto de, E-mail: carlos.freitas1950@hotmail.com [Instituto Federal do Rio de Janeiro (IFRJ), Nilopolis, RJ (Brazil); Jachic, Joao; Moreira, Maria de Lourdes, E-mail: jjachic@ien.gov.br, E-mail: malu@ien.gov.br [Instituto de Engenharia Nuclear (IEN/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2013-07-01

    One of the cooling modes for any source of heat such as in a shutdown nuclear core is the natural convection. The design specifications of any cooling pool can only be done when the removal heat rate and the corresponding mass flow rate is reasonably established. In our simulation scheme, we assumed that the body forces acting in the cubic water cell are: the weight, the drag force and the integrated pressure forces on the horizontal surfaces, the viscosity shear forces on the vertical surfaces and also a special viscosity drag force due to the mass dislocation along a Bernoulli type current tube outside the motive region. For a suitable time step, the uprising convection velocity is determined by an implicit and also by an explicit solution algorithm. The resulting differential equation depends on updating specific mass, dynamic viscosity and constant pressure heat coefficient with the last known temperature in the cell that absorbed heat. Numerical calculation software was performed using MATLAB’s technical computing language and then applied for a heat generation plate simulating a spent fuel assembler from a shutdown nuclear core. The results show time evolution of convection, terminal velocity and water temperature distribution. Pool dimension as well as pool level decrement are also determined for various air exhausting system conditions and heat rate of the spent fuel plate being cooled. (author)

  18. Time evolution simulation of heat removal in a small water tank by natural convection

    International Nuclear Information System (INIS)

    Freitas, Carlos Alberto de; Jachic, Joao; Moreira, Maria de Lourdes

    2013-01-01

    One of the cooling modes for any source of heat such as in a shutdown nuclear core is the natural convection. The design specifications of any cooling pool can only be done when the removal heat rate and the corresponding mass flow rate is reasonably established. In our simulation scheme, we assumed that the body forces acting in the cubic water cell are: the weight, the drag force and the integrated pressure forces on the horizontal surfaces, the viscosity shear forces on the vertical surfaces and also a special viscosity drag force due to the mass dislocation along a Bernoulli type current tube outside the motive region. For a suitable time step, the uprising convection velocity is determined by an implicit and also by an explicit solution algorithm. The resulting differential equation depends on updating specific mass, dynamic viscosity and constant pressure heat coefficient with the last known temperature in the cell that absorbed heat. Numerical calculation software was performed using MATLAB’s technical computing language and then applied for a heat generation plate simulating a spent fuel assembler from a shutdown nuclear core. The results show time evolution of convection, terminal velocity and water temperature distribution. Pool dimension as well as pool level decrement are also determined for various air exhausting system conditions and heat rate of the spent fuel plate being cooled. (author)

  19. IRIS - Generation IV Advanced Light Water Reactor for Countries with Small and Medium Electricity Grids

    International Nuclear Information System (INIS)

    Carelli, M. D.

    2002-01-01

    An international consortium of industry, laboratory, university and utility establishments, led by Westinghouse, is developing a Generation IV Reactor, International Reactor Innovative and Secure (IRIS). IRIS is a modular, integral, light water cooled, low-to-medium power (100-350 MWe) reactor which addresses the requirements defined by the US DOE for Generation IV reactors, i.e., fuel cycle sustainability, enhanced reliability and safety, and improved economics. It features innovative, advanced engineering, but it does not require new technology development since it relies on the proven technology of light water reactors. This paper presents the current reference IRIS design, which features a 1000 MWt thermal core with proven 5%-enriched uranium oxide fuel and four-year long straight burn fuel cycle, integral reactor vessel housing helical tube steam generators and immersed spool pumps. Other major contributors to the high level of safety and economic attractiveness are the safety by design and optimized maintenance approaches, which allow elimination of some classes of accidents, lower capital cost, long operating cycle, and high capacity factors. The path forward for possible future extension to a eight-year cycle will be also discussed. IRIS has a large potential worldwide market because of its proven technology, modularity, low financing, compatibility with existing grids and very limited infrastructure requirements. It is especially appealing to developing countries because of ease of operation and because its medium power is more adaptable to smaller grids. (author)

  20. High sensitive determination of zinc with novel water-soluble small molecular fluorescent sensor

    International Nuclear Information System (INIS)

    Weng Ying; Chen Zilin; Wang Fang; Xue Lin; Jiang Hua

    2009-01-01

    A high sensitive method of quantitative analysis for the determination of zinc in the nutrition supplements has been developed by using a novel water-soluble fluorescent sensor HQ3: (8-pyridylmethyloxy-2-methyl-quinoline). Under the optimized condition of 67 mM phosphate buffer, pH 7.4, and 5% (v/v) DMSO, the zinc concentration showed good linear relationship with fluorescence intensity in the range of 7.5 x 10 -8 to 2.5 x 10 -5 M with the detection limit of 1.5 x 10 -8 M. HQ3 exhibited high selectivity to zinc comparing with other metal ions except for cadmium. The developed analytical method was successfully used for determining the content of zinc in a real sample of zinc gluconate solution of Sanchine.

  1. Radium removal for a small community water-supply system. Research report, 1 October 1985-30 September 1987

    International Nuclear Information System (INIS)

    Mangelson, K.A.

    1988-07-01

    In 1984, a radium-removal treatment plant was constructed for the small community of Redhill Forest located in the central mountains of Colorado. The treatment plant consists of a process for removing iron and manganese ahead of an ion-exchange process for the removal of radium. The raw water comes from deep wells and has naturally occurring radium and iron concentrations of about 30-40 pCi/L and 7-10 mg/L, respectively. Before the raw water enters the main treatment plant, the raw water is aerated to remove radon gas and carbon dioxide. The unique features of the Redhill Forest Treatment Plant are related to the ways in which the radium removed from the raw water is further treated and eventually disposed of as treatment plant waste. A separate system removes only radium from the backwash/regeneration water of the ion exchange process and the radium is permanently complexed on a Radium Selective Complexer (RSC) resin made by Dow Chemical. The RSC resin containing radium is replaced with virgin resin as needed and the resin waste transported to a permanent final disposal site in Beatty, NV. This report presents a detailed description of the Redhill Forest treatment system and the results of in-depth monitoring of the processes and other factors relating to the overall operation of the radium-removal system. Included are descriptions of modifications made in the plant operation to improve the overall system operation and of the procedures for final disposal of the RSC resin-containing radium

  2. Remediation of sediment and water contaminated by copper in small-scaled constructed wetlands: effect of bioaugmentation and phytoextraction.

    Science.gov (United States)

    Huguenot, D; Bois, P; Cornu, J Y; Jezequel, K; Lollier, M; Lebeau, T

    2015-01-01

    The use of plants and microorganisms to mitigate sediment contaminated by copper was studied in microcosms that mimic the functioning of a stormwater basin (SWB) connected to vineyard watershed. The impact of phytoremediation and bioaugmentation with siderophore-producing bacteria on the fate of Cu was studied in two contrasted (batch vs. semi-continuous) hydraulic regimes. The fate of copper was characterised following its discharge at the outlet of the microcosms, its pore water concentration in the sediment, the assessment of its bioaccessible fraction in the rhizosphere and the measurement of its content in plant tissues. Physico-chemical (pH, redox potential) and biological parameters (total heterotrophic bacteria) were also monitored. As expected, the results showed a clear impact of the hydraulic regime on the redox potential and thus on the pore water concentration of Cu. Copper in pore water was also dependent on the frequency of Cu-polluted water discharges. Repeated bioaugmentation increased the total heterotrophic microflora as well as the Cu bioaccessibility in the rhizosphere and increased the amount of Cu extracted by Phragmites australis by a factor of ~2. Sugar beet pulp, used as a filter to avoid copper flushing, retained 20% of outcoming Cu and led to an overall retention of Cu higher than 94% when arranged at the outlet of microcosms. Bioaugmentation clearly improved the phytoextraction rate of Cu in a small-scaled SWB designed to mimic the functioning of a full-size SWB connected to vineyard watershed. Highlights: Cu phytoextraction in constructed wetlands much depends on the hydraulic regime and on the frequency of Cu-polluted water discharges. Cu phytoextraction increases with time and plant density. Cu bioaccessibility can be increased by bioaugmentation with siderophore-producing bacteria.

  3. Interactions between small cetaceans and the purse-seine fishery in western Portuguese waters

    Directory of Open Access Journals (Sweden)

    Laura Wise

    2007-06-01

    Full Text Available Marine mammal interactions with Portuguese purse-seine fisheries operating in four different ports (Figueira da Foz, Sesimbra, Setúbal, Sines were studied (July-October 2003. Observers accompanied commercial fishing vessels and monitored 48 fishing trips. An interview survey of skippers was also carried out (n = 36. Three species of marine mammals were observed in 31 sightings during the commercials trips but only the species Delphinus delphis and the category Delphinidae were observed to interact with fishing activities. Small cetaceans were observed to sink, gather or disperse school fishes and damage gear. Mean CPUE and fishing effort values did not change significantly in the presence of dolphins (H = 0.06 and H = 0, both p>0.05. Results from Figueira da Foz indicate that cetaceans are attracted to fishing grounds with a high abundance of their prey-species. Fishermen reported three by-catch events off Figueira da Foz. Compared with other fisheries, purse-seine fishing does not seem to be among the most damaging to marine mammals.

  4. Comparison of Heavy Water Reactor Thermalhydraulic Code Predictions with Small Break LOCA Experimental Data

    International Nuclear Information System (INIS)

    2012-08-01

    Activities within the frame of the IAEA's Technical Working Group on Advanced Technologies for HWRs (TWG-HWR) are conducted in a project within the IAEA's subprogramme on nuclear power reactor technology development. The objective of the activities on HWRs is to foster, within the frame of the TWG-HWR, information exchange and cooperative research on technology development for current and future HWRs, with an emphasis on safety, economics and fuel resource sustainability. One of the activities recommended by the TWG-HWR was an international standard problem exercise entitled Intercomparison and Validation of Computer Codes for Thermalhydraulics Safety Analyses. Intercomparison and validation of computer codes used in different countries for thermalhydraulics safety analyses will enhance the confidence in the predictions made by these codes. However, the intercomparison and validation exercise needs a set of reliable experimental data. Two RD-14M small break loss of coolant accident (SBLOCA) tests, simulating HWR LOCA behaviour, conducted by Atomic Energy of Canada Ltd (AECL), were selected for this validation project. This report provides a comparison of the results obtained from eight participating organizations from six countries (Argentina, Canada, China, India, Republic of Korea, and Romania), utilizing four different computer codes (ATMIKA, CATHENA, MARS-KS, and RELAP5). General conclusions are reached and recommendations made.

  5. Wind variability and sheltering effects on measurements and modeling of air-water exchange for a small lake

    Science.gov (United States)

    Markfort, Corey D.; Resseger, Emily; Porté-Agel, Fernando; Stefan, Heinz

    2014-05-01

    Lakes with a surface area of less than 10 km2 account for over 50% of the global cumulative lake surface water area, and make up more than 99% of the total number of global lakes, ponds, and wetlands. Within the boreal regions as well as some temperate and tropical areas, a significant proportion of land cover is characterized by lakes or wetlands, which can have a dramatic effect on land-atmosphere fluxes as well as the local and regional energy budget. Many of these small water bodies are surrounded by complex terrain and forest, which cause the wind blowing over a small lake or wetland to be highly variable. Wind mixing of the lake surface layer affects thermal stratification, surface temperature and air-water gas transfer, e.g. O2, CO2, and CH4. As the wind blows from the land to the lake, wake turbulence behind trees and other shoreline obstacles leads to a recirculation zone and enhanced turbulence. This wake flow results in the delay of the development of wind shear stress on the lake surface, and the fetch required for surface shear stress to fully develop may be ~O(1 km). Interpretation of wind measurements made on the lake is hampered by the unknown effect of wake turbulence. We present field measurements designed to quantify wind variability over a sheltered lake. The wind data and water column temperature profiles are used to evaluate a new method to quantify wind sheltering of lakes that takes into account lake size, shape and the surrounding landscape features. The model is validated against field data for 36 Minnesota lakes. Effects of non-uniform sheltering and lake shape are also demonstrated. The effects of wind sheltering must be included in lake models to determine the effect of wind-derived energy inputs on lake stratification, surface gas transfer, lake water quality, and fish habitat. These effects are also important for correctly modeling momentum, heat, moisture and trace gas flux to the atmosphere.

  6. Properties of surfactant films in water-in-CO2 microemulsions obtained by small-angle neutron scattering.

    Science.gov (United States)

    Yan, Ci; Sagisaka, Masanobu; James, Craig; Rogers, Sarah; Alexander, Shirin; Eastoe, Julian

    2014-12-01

    The formation, stability and structural properties of normal liquid phase microemulsions, stabilized by hydrocarbon surfactants, comprising water and hydrocarbon oils can be interpreted in terms of the film bending rigidity (energy) model. Here, this model is tested for unusual water-in-CO2 (w/c) microemulsions, formed at high pressure with supercritical CO2 (sc-CO2) as a solvent and fluorinated surfactants as stabilizers. Hence, it is possible to explore the generality of this model for other types of microemulsions. High Pressure Small-Angle Neutron Scattering (HP-SANS) has been used to study w/c microemulsions, using contrast variation to highlight scattering from the stabilizing fluorinated surfactant films: these data show clear evidence for spherical core-shell structures for the microemulsion droplets. The results extend understanding of w/c microemulsions since previous SANS studies are based only on scattering from water core droplets. Here, detailed structural parameters for the surfactant films, such as thickness and film bending energy, have been extracted from the core-shell SANS profiles revealed by controlled contrast variation. Furthermore, at reduced CO2 densities (∼0.7gcm(-3)), elongated cylindrical droplet structures have been observed, which are uncommon for CO2 microemulsions/emulsions. The implications of the presence of cylindrical micelles and droplets for applications of CO2, and viscosity enhancements are discussed. Copyright © 2014 Elsevier Inc. All rights reserved.

  7. Pollutant source identification model for water pollution incidents in small straight rivers based on genetic algorithm

    Science.gov (United States)

    Zhang, Shou-ping; Xin, Xiao-kang

    2017-07-01

    Identification of pollutant sources for river pollution incidents is an important and difficult task in the emergency rescue, and an intelligent optimization method can effectively compensate for the weakness of traditional methods. An intelligent model for pollutant source identification has been established using the basic genetic algorithm (BGA) as an optimization search tool and applying an analytic solution formula of one-dimensional unsteady water quality equation to construct the objective function. Experimental tests show that the identification model is effective and efficient: the model can accurately figure out the pollutant amounts or positions no matter single pollution source or multiple sources. Especially when the population size of BGA is set as 10, the computing results are sound agree with analytic results for a single source amount and position identification, the relative errors are no more than 5 %. For cases of multi-point sources and multi-variable, there are some errors in computing results for the reasons that there exist many possible combinations of the pollution sources. But, with the help of previous experience to narrow the search scope, the relative errors of the identification results are less than 5 %, which proves the established source identification model can be used to direct emergency responses.

  8. On small things in water moving around: Purcell's contributions to biology

    Science.gov (United States)

    Berg, Howard

    2012-02-01

    I went to see Purcell after finishing my course work for the Ph.D. (1961) to ask whether I might join his group. ``But I don't have any graduate students,`` he said. ``Why is that?'' I asked. ``I can't think of anything to do,'' he replied. That was a wipe out. After I had finished my Ph.D. with Ramsey on the hydrogen maser (1964), Ed and I came up with an idea that led to work on sedimentation field-flow fractionation (PNAS 1967). We had hoped this method would be useful for biology, but problems of adsorption of proteins to surfaces stood in the way. Then I moved over to the biology department and got interested in the motile behavior of bacteria (1968). Here was a subject that I thought Ed would really enjoy. There were wonderful movies made by Norbert Pfennig of experiments done by Theodor Engelmann in the 1880's. We found a 16-mm projector and looked at these movies on Ed's office wall. Ed's first comment proved seminal, ''How can such a small cell swim in a straight line?'' We thought about how cells count molecules in their environment and wrote ``Physics of chemoreception,'' (Biophys. J.,1977). In the meantime, Ed gave a memorable lecture at Viki Weisskopf's retirement symposium, his classic ``Life at low Reynolds number'' (Am. J. Phys. 1977). Ed really wanted to understand what it would be like to swim like a bacterium! He wasn't very interested in what the literature had to say about such a problem, he wanted to think it through for himself. My role was straight man. I very much enjoyed the ride.

  9. A Paradigm Shift in Water Quality Governance in a Transitional Context: A Critical Study about the Empowerment of Local Governance in Georgia

    Directory of Open Access Journals (Sweden)

    Sisira S. Withanachchi

    2018-01-01

    Full Text Available The management of water quality is an important part of natural resource governance. Assurance of water quality therefore requires formulation of the regulatory framework and institutional process. Water quality-related problems and their management are mainly recognized as local responsibilities in Integrated Water Resources Management (IWRM. The politics of environmental policy-making should consider the political economic dynamics and socio-ecological patterns. Decentralization by providing more power to the local level and moving to a new spatial management system that is based on water basins are the two strong entreaties in the new water governance paradigm. Transitional countries facing rapid institutional adjustment, restructuring of regulations, and political-economic changes are encountering these demands internally and externally in their policy formulations. In this context, this study critically examines the case of Georgia, a transitional country. In particular, the focus is on how local governance entities can be empowered and what obstacles water quality governance encounters in Georgia. Qualitative research design is the main research method implemented in this study. The key findings from the research analysis are as follows: the existing regulations and governance system do not facilitate the active engagement of local entities in water quality governance. The application of new water polices may fail again if a top-down governance model is put in place that only creates a narrow space for local governance entities to effectively govern water quality.

  10. Contrasting residence times and fluxes of water and sulfate in two small forested watersheds in Virginia, USA.

    Science.gov (United States)

    Böhlke, John Karl; Michel, Robert L

    2009-07-01

    Watershed mass balances for solutes of atmospheric origin may be complicated by the residence times of water and solutes at various time scales. In two small forested headwater catchments in the Appalachian Mountains of Virginia, USA, mean annual export rates of SO(4)(=) differ by a factor of 2, and seasonal variations in SO(4)(=) concentrations in atmospheric deposition and stream water are out of phase. These features were investigated by comparing (3)H, (35)S, delta(34)S, delta(2)H, delta(18)O, delta(3)He, CFC-12, SF(6), and chemical analyses of open deposition, throughfall, stream water, and spring water. The concentrations of SO(4)(=) and radioactive (35)S were about twice as high in throughfall as in open deposition, but the weighted composite values of (35)S/S (11.1 and 12.1x10(-15)) and delta(34)S (+3.8 and +4.1 per thousand) were similar. In both streams (Shelter Run, Mill Run), (3)H concentrations and delta(34)S values during high flow were similar to those of modern deposition, delta(2)H and delta(18)O values exhibited damped seasonal variations, and (35)S/S ratios (0-3x10(-15)) were low throughout the year, indicating inter-seasonal to inter-annual storage and release of atmospheric SO(4)(=) in both watersheds. In the Mill Run watershed, (3)H concentrations in stream base flow (10-13 TU) were consistent with relatively young groundwater discharge, most delta(34)S values were approximately the same as the modern atmospheric deposition values, and the annual export rate of SO(4)(=) was equal to or slightly greater than the modern deposition rate. In the Shelter Run watershed, (3)H concentrations in stream base flow (1-3 TU) indicate that much of the discharging ground water had been deposited prior to the onset of atmospheric nuclear bomb testing in the 1950s, base flow delta(34)S values (+1.6 per thousand) were significantly lower than the modern deposition values, and the annual export rate of SO(4)(=) was less than the modern deposition rate

  11. Analysis on small long life reactor using thorium fuel for water cooled and metal cooled reactor types

    International Nuclear Information System (INIS)

    Permana, Sidik

    2009-01-01

    Long-life reactor operation can be adopted for some special purposes which have been proposed by IAEA as the small and medium reactor (SMR) program. Thermal reactor and fast reactor types can be used for SMR and in addition to that program the utilization of thorium fuel as one of the candidate as a 'partner' fuel with uranium fuel which can be considered for optimizing the nuclear fuel utilization as well as recycling spent fuel. Fissile U-233 as the main fissile material for thorium fuel shows higher eta-value for wider energy range compared with other fissile materials of U-235 and Pu-239. However, it less than Pu-239 for fast energy region, but it still shows high eta-value. This eta-value gives the reactor has higher capability for obtaining breeding condition or high conversion capability. In the present study, the comparative analysis on small long life reactor fueled by thorium for different reactor types (water cooled and metal cooled reactor types). Light water and heavy water have been used as representative of water-cooled reactor types, and for liquid metal-cooled reactor types, sodium-cooled and lead-bismuth-cooled have been adopted. Core blanket arrangement as general design configuration, has been adopted which consist of inner blanket region fueled by thorium oxide, and two core regions (inner and out regions) fueled by fissile U-233 and thorium oxide with different percentages of fissile content. SRAC-CITATION and JENDL-33 have been used as core optimization analysis and nuclear data library for this analysis. Reactor operation time can reaches more than 10 years operation without refueling and shuffling for different reactor types and several power outputs. As can be expected, liquid metal cooled reactor types can be used more effective for obtaining long life reactor with higher burnup, higher power density, higher breeding capability and lower excess reactivity compared with water-cooled reactors. Water cooled obtains long life core operation

  12. The Distribution of Capture Fisheries Based Small Pelagic - Mackerel Fish Species In Balikpapan Waters, East Kalimantan

    Directory of Open Access Journals (Sweden)

    Said Abdusysyahid

    2014-04-01

    Full Text Available Normal 0 false false false IN X-NONE X-NONE In the utilization of common property resource, long term balance in aquaculture is difficult to maintain as people trying to maximize their profit leading to considerable extensification. The objective of this research was to analyze the number of stock, production, and effort of Mackerel fish (Scomberomorus commersonii resource based on bio-economic approach. Primary data was collected based on purposive sampling method where the respondents in this research were Small Pelagic fishers which determined deliberately due to specific consideration. Secondary data used in this research was obtained from several sources. Data production and effort (input or effort was arranged in a time sequence according to the type of fishing gears and their targets of fishery resource being studied and then determined the value of CPUE (catch per unit effort. Mathematically, the input gear to be standardized is calculated from fishing power index multiplies with input (effort of standardized gear. The result shows that the renewable capacity begins to decrease leading to a condition of biologically over fishing. Aside from that, the Mackerel fish resource in this area also experiences economically over fishing condition which indicated by higher economic calculation value and lower capture yield. /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New

  13. 40 CFR 122.32 - As an operator of a small MS4, am I regulated under the NPDES storm water program?

    Science.gov (United States)

    2010-07-01

    ... regulated under the NPDES storm water program? 122.32 Section 122.32 Protection of Environment ENVIRONMENTAL... operator of a small MS4, am I regulated under the NPDES storm water program? (a) Unless you qualify for a... a petition to the NPDES permitting authority to require an NPDES permit for your discharge of storm...

  14. Experimental investigation of small diameter two-phase closed thermosyphons charged with water, FC-84, FC-77 and FC-3283

    International Nuclear Information System (INIS)

    Jouhara, Hussam; Robinson, Anthony J.

    2010-01-01

    An experimental investigation of the performance of thermosyphons charged with water as well as the dielectric heat transfer liquids FC-84, FC-77 and FC-3283 has been carried out. The copper thermosyphon was 200 mm long with an inner diameter of 6 mm, which can be considered quite small compared with the vast majority of thermosyphons reported in the open literature. The evaporator length was 40 mm and the condenser length was 60 mm which corresponds with what might be expected in compact heat exchangers. With water as the working fluid two fluid loadings were investigated, that being 0.6 ml and 1.8 ml, corresponding to approximately half filled and overfilled evaporator section in order to ensure combined pool boiling and thin film evaporation/boiling and pool boiling only conditions, respectively. For the Fluorinert TM liquids, only the higher fill volume was tested as the aim was to investigate pool boiling opposed to thin film evaporation. Generally, the water-charged thermosyphon evaporator and condenser heat transfer characteristics compared well with available predictive correlations and theories. The thermal performance of the water-charged thermosyphon also outperformed the other three working fluids in both the effective thermal resistance as well as maximum heat transport capabilities. Even so, FC-84, the lowest saturation temperature fluid tested, shows marginal improvement in the heat transfer at low operating temperatures. All of the tested Fluorinert TM liquids offer the advantage of being dielectric fluids, which may be better suited for sensitive electronics cooling applications and were all found to provide adequate thermal performance up to approximately 30-50 W after which liquid entrainment compromised their performance.<