Zircon U-Pb chronology, geochemistry and Sr-Nd-Pb isotopic compositions of the Volcanic Rocks in the Elashan area, NW China: petrogenesis and tectonic implications

Science.gov (United States)

Zhou, H.; Wei, J.; Shi, W.; Li, P.; Chen, M.; Zhao, X.

2017-12-01

Elashan area is located in the intersection of the East Kunlun Orogenic Belt (EKOB) and the West Qinling Orogenic (WQOB). We present petrology, zircon U-Pb ages, whole-rock geochemistry and Sr-Nd-Pb isotopic compositions from the andesite and felsic volcanic rocks (rhyolite and rhyolitic tuffs) in Elashan group volcanic rock. The LA-ICP-MS zircon U-Pb age data indicate that the volcanic rocks are emplaced at 250 247 Ma. The volcanic rocks have high -K and aluminum - peraluminous characteristics, A/CNK = 1.07 1.82, δ ranges from 1.56 2.95, the main body is calc-alkaline rock. They are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in some high field strength elements (HFSEs, e.g., Nb, Ta, P and Ti), while having a flat heavy REE (HREEs) pattern. The ∑REE values of 178.68 to 298.11 ppm, average 230.50 ppm. The LREE/HREE values of 4.39 to 11.78 ppm, average 6.77 ppm. REE fractionation is obvious, REE distribution curve was right smooth, and have slightly negative Eu anomalies (Eu/Eu*=0.44-0.80, average 0.60), which as similar to the island arc volcanic rocks. The volcanic rocks have initial 87Sr/86Sr ratios of 0.71028-0.71232, ɛNd(t) values of -6.7 to -7.6, with T2DM-Nd ranging from 1561 to 1640 Ma. Pb isotopic composition (206 Pb / 204 Pb)t = 18.055 18.330, (207 Pb / 204 Pb)t = 15.586 15.618, (208 Pb / 204 Pb)t = 37.677 38.332. Geochemical and Sr-Nd-Pb isotopes indicates that Elashan group volcanic magma derived mainly from the lower crust. Elashan group volcanic rocks is the productive East Kunlun block and West Qinling block collision, which makes the thicken crust caused partial melting in the study area. The source rocks is probably from metamorphic sandstone of Bayankala. But with Y-Nb and Rb-(Y+Nb), R1-R2 and Rb/10-Hf-Ta*3 diagrams showing that intermediate-acid rocks mainly formed in volcanic arc-collision environment, probably the collision event is short , therefore rocks retain the original island

Recognition of the Kaweka Terrane in northern South Island, New Zealand : preliminary evidence from Rb-Sr metamorphic and U-Pb detrital zircon ages

International Nuclear Information System (INIS)

Adams, C.J.; Mortimer, N.; Campbell, H.J.; Griffin, W.L.

2011-01-01

Detrital zircon U-Pb ages and Rb-Sr metamorphic ages from low-grade Torlesse Supergroup metasedimentary rocks from North Canterbury and Marlborough provide preliminary evidence for a continuation of the Kaweka Terrane of the central North Island into the Torlesse Composite Terrane of the South Island. This would extend from the south side of the Wairau Fault in the upper Wairau River valley southwards to the Lake Tennyson and Lake Sumner areas, and as far as Hawarden. Rb-Sr ages indicate Jurassic metamorphism, 170±24 Ma, with initial 87 Sr/ 86 Sr ratios at that time 0.7073 ± 0.0007 i.e. similar to their North Island counterparts. These Kaweka Terrane rocks have detrital zircon ages that follow the distinctive pattern of the Torlesse rocks in general, i.e. substantial (>30%) Permian-Triassic and Precambrian-Early Palaeozoic groupings, but they also have minor youngest age components c. 175-165 Ma which constrain a maximum Early-Middle Jurassic depositional age. In detail, significant, older zircon components are Late Permian-Early Triassic (260-240 Ma) and Late Triassic (220-210 Ma), but the Precambrian-Early Palaeozoic detrital zircon ages are more scattered. The Kaweka Terrane thus forms a linear belt (c. 500 km) along the length of the Torlesse Composite Terrane in both North and South Islands. In the South Island it coincides with the Esk Head Belt, i.e. east of the Rakaia Terrane (Triassic-Late Permian) and west of the Pahau Terrane (Early Cretaceous-Late Jurassic). (author). 61 refs., 4 figs., 2 tabs.

Devonian alkaline magmatism in the northern North China Craton: Geochemistry, SHRIMP zircon U-Pb geochronology and Sr-Nd-Hf isotopes

Directory of Open Access Journals (Sweden)

Dingling Huang

2017-01-01

Full Text Available The Wulanhada pluton is among the rare suite of Devonian alkaline plutons occurring along the northern margin of the North China Craton (NCC. The intrusion is mainly composed of quartz-monzonite. Here we report zircon SHRIMP U-Pb data from this intrusion which shows emplacement age of ca. 381.5 Ma. The rock is metaluminous with high (Na2O + K2O values ranging from 8.46 to 9.66 wt.%. The REE patterns of the rocks do not show any Eu anomaly whereas the primitive-mantle-normalized spider diagram shows strong positive Sr and Ba anomalies. The Wulanhada rocks exhibit high initial values of (87Sr/86Srt = 0.70762–0.70809, low ɛNd(t = −12.76 to −12.15 values and negative values of ɛHf(t = −23.49 to −17.02 with small variations in (176Hf/177Hft (0.281873–0.282049. These geochemical features and quantitative isotopic modeling results suggest that the rocks might have been formed through the partial melting of Neoarchean basic rocks in the lower crust of the NCC. The Wulanhada rocks, together with the Devonian alkaline rocks and mafic-ultramafic complex from neighboring regions, constitute a post-collisional magmatic belt along the northern NCC.

Cooling age of the Birimian juvenile crust in West Africa. U-Pb, Rb-Sr and K-Ar data on the 2.1 Ga granite-greenstone terrains from SW-Niger

International Nuclear Information System (INIS)

Lama, C.; Dautel, D.; Zimmermann, J.L.; Cheilletz, A.; Pons, J.

1994-01-01

A comparison between zircon U-Pb, whole-rock Rb-Sr and biotite-amphibole K-Ar data on Birimian granite-greenstone terrains from SW-Niger indicates that the youngest granitic plutons were emplaced at 2.115 ± 5 Ma and that both the plutons and the surrounding greenstones yield cooling ages around 2.118 Ma. The age similarity between the end of the plutonism and the cooling of plutons and surrounding greenstone further suggests rapid cooling at the end of the plutonic event and, thus, corroborates a model of greenstone metamorphism linked to the thermal effect of the plutons. (authors)

Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China

Science.gov (United States)

Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu

2012-10-01

The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

Forty years of 9Sr in situ migration: importance of soil characterization in modeling transport phenomena

International Nuclear Information System (INIS)

Fernandez, J.M.; Piault, E.; Macouillard, D.; Juncos, C.

2006-01-01

In 1960 experiments were carried out on the transfer of 9 Sr between soil, grapes and wine. The experiments were conducted in situ on a piece of land limited by two control strips. The 9 Sr migration over the last 40 years was studied by performing radiological and physico-chemical characterizations of the soil on eight 70 cm deep cores. The vertical migration modeling of 9 Sr required the definition of a triple layer conceptual model integrating the rainwater infiltration at constant flux as the only external factor of influence. Afterwards the importance of a detailed soil characterization for modeling was discussed and satisfactory simulation of the 9 Sr vertical transport was obtained and showed a calculated migration rate of about 1.0 cm year -1 in full agreement with the in situ measured values. The discussion was regarding some of the key parameters such as granulometry, organic matter content (in the Van Genuchten parameter determination), Kd and the efficient rainwater infiltration. Besides the experimental data, simplifying assumptions in modeling such as water-soil redistribution calculation and factual discontinuities in conceptual model were examined

Structural and chemical reactivity modifications of a cobalt perovskite induced by Sr-substitution. An in situ XAS study

International Nuclear Information System (INIS)

Hueso, Jose L.; Holgado, Juan P.; Pereñíguez, Rosa; Gonzalez-DelaCruz, V.M.; Caballero, Alfonso

2015-01-01

LaCoO 3 and La 0.5 Sr 0.5 CoO 3−δ perovskites have been studied by in situ Co K-edge XAS. Although the partial substitution of La(III) by Sr(II) species induces an important increase in the catalytic oxidation activity and modifies the electronic state of the perovskite, no changes could be detected in the oxidation state of cobalt atoms. So, maintaining the electroneutrality of the perovskite requires the generation of oxygen vacancies in the network. The presence of these vacancies explains that the substituted perovskite is now much more reducible than the original LaCoO 3 perovskite. As detected by in situ XAS, after a consecutive reduction and oxidation treatment, the original crystalline structure of the LaCoO 3 perovskite is maintained, although in a more disordered state, which is not the case for the Sr doped perovskite. So, the La 0.5 Sr 0.5 CoO 3−δ perovskite submitted to the same hydrogen reduction treatment produces metallic cobalt, while as determined by in situ XAS spectroscopy the subsequent oxidation treatment yields a Co(III) oxide phase with spinel structure. Surprisingly, no Co(II) species are detected in this new spinel phase. - Highlights: • A Sr-substituted lanthanum cobalt perovskite has been prepared by spray pyrolysis. • It has been established that Co(III) cations are present in both perovskites. • LaCoO 3 is a less reducible phase than the substituted La 0.5 Sr 0.5 CoO 3−δ . • After reoxidation of reduced La 0.5 Sr 0.5 CoO 3−δ , a 100% Co(III) spinel is obtained

Isotopegeochemical investigations and dating on minerals and fossils from sedimentary rocks: 1. Glauconites from Jura, Molasse and Helveticum (K-Ar, Rb-Sr), 2. 87Sr/86Sr-Isotope stratigraphy on marine and limnetic micro- and macro-fossils, 3. Primary minerals from tertiary bentonites and tuffs (U-Pb, K-Ar)

International Nuclear Information System (INIS)

Fischer, H.

1988-01-01

Glauconite investigations: the main problem in dating glauconites lies in the identification of authigenic minerals which have not been influenced by post-sedimentary processes. The age determination on glauconites from the three different tectonic units: the Jura mountains, the molasse basin and the Helvetic nappes, yield inconsistent results. Up to 35% too young K-Ar ''ages'' of glauconites from limestones from the Helvetic nappes can be traced to partial Ar loss caused by sediment-lithification and tectonic events. Sr-isotope stratigraphy: multiple analyses of recent samples from the Mediterranean Sea and from the North Atlantic show that the 87 Sr/ 86 Sr isotope ratios correspond well. In a stratigraphic ideal section from the Upper marine molasse a resolution of 206 Pb/ 238 U method zircons from the Fish Canyon Tuff were measured and yielded ages of 28.49±0.10, 24.46±0.11 and 28.46±0.13 Ma. These values correspond well with the published mean value of zircon and apatite fission track age of 28.4±0.7 Ma. Thus, the U-Pb method for dating young volcanic minerals seems to be suitable. However, the published mean value (''solid state age'') of Naeser et al. (1981) is higher than the published (''gas age'') mean value of 27.2±0.7 Ma based on biotite, sanidine, hornblende and plagioclase. (author) figs., tabs., refs

U-Pb and Rb-Sr geochronology of the Wedgeport granitoid pluton, southwestern Nova Scotia

International Nuclear Information System (INIS)

Cormier, R.F.; Keppie, J.D.; Odom, A.L.

1988-01-01

Zircons from biotite monzogranite of the Wedgeport Pluton, intrusive into deformed metasediments of the Cambrian(?) Goldenville formation in the southwestern Meguma Terrane of Nova Scotia, yield concordant U-Pb ages of 316 ± 5 Ma. This is interpreted as the time of intrusion and crystallization. Within the error limits, the 323 ± 0.0056 Rb-Sr analyses of mineral separates of biotite, potassium feldspar, and quartz-plagioclase from several samples yield subparallel, internal isochrons with an average age of 257 ± 8 Ma. Initial ratios of the internal isochrons range from 0.716 to 0.759. A slow-cooling model for the latter data is discarded because the mineral data fall on straight lines. Instead, a reheating event related to plutonism ca 257 Ma ago, which was sufficient to cause local grain-to-grain migration and reequilibration of strontium and rubidium but not large-scale redistribution, is invoked. This reheating is also inferred to be responsible for the hydrothermal alteration and Sn-U mineralization concentrated along the northwestern margin of the pluton. A dextral northeast-southeast shear zone cutting the pluton is also inferred to be ca. 257 Ma old. It may be related to the last stages of westward abduction of the Meguma Terrane. These results provide a clear example of Permo-Carboniferous plutonism in the southwestern Meguma Terrane and suggest a similar interpretation may apply to other anomalously young ages recorded in this area. In light of these results, the Permo-Carboniferous age of the large East Kemptville tin deposit and its location in a dextral shear zone suggest that the association of younger plutonism and shear zones may be a significant factor for economic mineralization. (22 refs., 4 tabs., 3 figs.)

High-Precision In Situ 87Sr/86Sr Analyses through Microsampling on Solid Samples: Applications to Earth and Life Sciences

Directory of Open Access Journals (Sweden)

Sara Di Salvo

2018-01-01

Full Text Available An analytical protocol for high-precision, in situ microscale isotopic investigations is presented here, which combines the use of a high-performing mechanical microsampling device and high-precision TIMS measurements on micro-Sr samples, allowing for excellent results both in accuracy and precision. The present paper is a detailed methodological description of the whole analytical procedure from sampling to elemental purification and Sr-isotope measurements. The method offers the potential to attain isotope data at the microscale on a wide range of solid materials with the use of minimally invasive sampling. In addition, we present three significant case studies for geological and life sciences, as examples of the various applications of microscale 87Sr/86Sr isotope ratios, concerning (i the pre-eruptive mechanisms triggering recent eruptions at Nisyros volcano (Greece, (ii the dynamics involved with the initial magma ascent during Eyjafjallajökull volcano’s (Iceland 2010 eruption, which are usually related to the precursory signals of the eruption, and (iii the environmental context of a MIS 3 cave bear, Ursus spelaeus. The studied cases show the robustness of the methods, which can be also be applied in other areas, such as cultural heritage, archaeology, petrology, and forensic sciences.

Calorimetric investigations of UPb{sub 3} compound

Energy Technology Data Exchange (ETDEWEB)

Agarwal, Renu, E-mail: arenu@barc.gov.in; Samui, Pradeep; Mukerjee, S.K.

2016-08-10

Highlights: • First time reporting of enthalpy increment and heat capacity data of UPb{sub 3} compound. • First time reporting of high temperature calorimetric determination of enthalpy of formation of UPb{sub 3} compound. • Miedema model was used to calculate enthalpies of formation of UPb{sub 3} and UPb. • Thermodynamic table of the compound UPb{sub 3} was generated. - Abstract: Interaction of uranium based metallic fuels and lead coolant can lead to formation of intermetallic compounds of U-Pb system. To understand U-Pb interactions, it is important to know thermodynamic properties of intermetallic compounds present in this system, UPb{sub 3} and UPb. In the present work, enthalpy increment, heat capacity and enthalpy of formation of UPb{sub 3} intermetallic compound were determined. The enthalpy increment was determined by high temperature Calvet calorimeter and heat capacity was determined using DSC. The heat capacity data was used to calculate thermodynamic parameters of the compound as a function of temperature. The enthalpy of formation at 843 K was determined using successive precipitation method, by direct reaction calorimetry. The enthalpy of formation at 843 K, from Pb(l) and U(l), was −28.9 kJ at-mol{sup −1} and after adjusting enthalpy increments of pure elements and compound, the enthalpy of formation of the compound at 298 K, from Pb(s) and U(α) was found to be −20.0 kJ at-mol{sup −1}.

Advantages of conducting in-situ U-Pb age dating of multiple U-bearing minerals from a single complex: Case in point - the Oka Carbonatite Complex

Science.gov (United States)

Chen, W.; Simonetti, A.

2012-12-01

A detailed radiometric investigation is currently underway focusing on U-bearing accessory minerals apatite, perovskite, and niocalite from the Oka Carbonatite Complex (Canada). One of the main objectives is to obtain a comparative chronology of melt crystallization for the complex. Unlike other commonly adopted U-bearing minerals (e.g., zircon, monazite) for in-situ dating investigations, apatite, perovskite, and niocalite contain relatively high contents of common Pb. Hence, careful assessment of the proportion and composition of the common Pb, and usage of appropriate matrix-matched external standards are imperative. The Madagascar apatite was utilized as the external standard for apatite dating, and the Emerald Lake and Durango apatites were adopted as secondary standards; the latter yield ages of 92.6 ±1.8 and 32.2 ±1.1 Ma, respectively, and these are identical to their accepted ages. Pb/U ages for apatite from Oka were obtained for different rock types, including 8 carbonatites, 4 okaites, 3 ijolites and 3 alnoites, and these define a range of ages between ~105 and ~135 Ma; this result suggests a protracted crystallization history. In total, 266 individual analyses define two peaks at ~115 and ~125Ma. For perovskite dating, the Ice River perovskite standard was utilized as the external standard. The perovskites from one okaite sample yield an age of 112.2 ±1.9 Ma, and is much younger than the previously reported U-Pb perovskite age of 131 ±7 Ma. Hence, the combined U-Pb perovskite ages also suggest a rather prolonged time of melt crystallization. Niocalite is a rare, accessory silicate mineral that occurs within the carbonatites at Oka. The international zircon standard BR266 was selected for use as the external standard and rastering was employed to minimize the Pb-U fractionation. Two niocalite samples give young ages at 110.6 ±1.2 and 115.0 ±1.9 Ma, and are identical to their respective apatite ages (given associated uncertainties) from the same

Solid-state reactivity explored in situ by synchrotron radiation on single crystals: from SrFeO2.5 to SrFeO3 via electrochemical oxygen intercalation

International Nuclear Information System (INIS)

Maity, A; Dutta, R; Penkala, B; Ceretti, M; Letrouit-Lebranchu, A; Perichon, A; Paulus, W; Chernyshov, D; Piovano, A; Bossak, A; Meven, M

2015-01-01

In this study we demonstrate the feasibility of following up a chemical reaction by single crystal x-ray (synchrotron) diffraction under operando conditions, carried out in a specially designed electrochemical cell mounted on the BM01A at the European Synchrotron Radiation Facility (ESRF). We investigated in detail the electrochemical oxidation of SrFeO 2.5 to SrFeO 3 on a spherical single crystal of 70 µm diameter by in situ diffraction at an ambient temperature. Complete data sets were obtained by scanning the whole reciprocal space using a 2M Pilatus detector, resulting in 3600 frames with a resolution of 0.1° per data set, each obtained in 18 min. The crystal was mounted in a specially designed electrochemical cell with 1N KOH used as the electrolyte. During the electrochemical oxidation, the reaction proceeds following the phase sequence SrFeO 2.5 /SrFeO 2.75 /SrFeO 2.875 /SrFeO 3 , structurally accompanied by establishing a complex series of long-range oxygen vacancy ordering, which gets instantly organized at ambient temperature. The topotactic reaction pathway is discussed in terms of the evolution of the twin domain structure. The formation of SrFeO 2.875 is accompanied by the formation of diffuse streaks along the [1 0 0]-direction of the perovskite cell, reaching high d-spacings. The diffuse streaks are discussed and are thought to originate from a modified twin structure induced by the SrFeO 2.75 to SrFeO 2.875 transition, and the associated changes in the domain structure, developed during the oxygen intercalation. We equally analysed and discussed in detail the twin structure of all the title compounds. We confirm the ground state of SrFeO 2.5 is able to adopt the Imma space group symmetry, showing stacking faults of the tetrahedral layers along the stacking axis of the brownmillerite unit cell, indicated by the 1D diffuse rods. We showed that in situ single crystal diffraction has huge potential in the study of non-stoichiometric compounds

Solid-state reactivity explored in situ by synchrotron radiation on single crystals: from SrFeO2.5 to SrFeO3 via electrochemical oxygen intercalation

Science.gov (United States)

Maity, A.; Dutta, R.; Penkala, B.; Ceretti, M.; Letrouit-Lebranchu, A.; Chernyshov, D.; Perichon, A.; Piovano, A.; Bossak, A.; Meven, M.; Paulus, W.

2015-12-01

In this study we demonstrate the feasibility of following up a chemical reaction by single crystal x-ray (synchrotron) diffraction under operando conditions, carried out in a specially designed electrochemical cell mounted on the BM01A at the European Synchrotron Radiation Facility (ESRF). We investigated in detail the electrochemical oxidation of SrFeO2.5 to SrFeO3 on a spherical single crystal of 70 µm diameter by in situ diffraction at an ambient temperature. Complete data sets were obtained by scanning the whole reciprocal space using a 2M Pilatus detector, resulting in 3600 frames with a resolution of 0.1° per data set, each obtained in 18 min. The crystal was mounted in a specially designed electrochemical cell with 1N KOH used as the electrolyte. During the electrochemical oxidation, the reaction proceeds following the phase sequence SrFeO2.5/SrFeO2.75/SrFeO2.875/SrFeO3, structurally accompanied by establishing a complex series of long-range oxygen vacancy ordering, which gets instantly organized at ambient temperature. The topotactic reaction pathway is discussed in terms of the evolution of the twin domain structure. The formation of SrFeO2.875 is accompanied by the formation of diffuse streaks along the [1 0 0]-direction of the perovskite cell, reaching high d-spacings. The diffuse streaks are discussed and are thought to originate from a modified twin structure induced by the SrFeO2.75 to SrFeO2.875 transition, and the associated changes in the domain structure, developed during the oxygen intercalation. We equally analysed and discussed in detail the twin structure of all the title compounds. We confirm the ground state of SrFeO2.5 is able to adopt the Imma space group symmetry, showing stacking faults of the tetrahedral layers along the stacking axis of the brownmillerite unit cell, indicated by the 1D diffuse rods. We showed that in situ single crystal diffraction has huge potential in the study of non-stoichiometric compounds under operando

U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration

Energy Technology Data Exchange (ETDEWEB)

Chemale Junior, Farid, E-mail: fchemale@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Kawashita, Koji; Dussin, Ivo A. [Universidade de Sao Paulo (USP), SP (Brazil). Centro de Pesquisas Geocronologicas; Avila, Janaina N. [Australian National University, Canberra, (Australia). Research School of Earth Sciences; Justino, Dayvisson; Bertotti, Anelise [Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, RS (Brazil). Curso de Pos-Graduacao em Geociencias

2012-06-15

The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 {mu}m and, in some cases, of 15 and 40 {mu}m. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion factors and the highly suitable GJ-1 standard zircon for external calibrations were of paramount importance for obtaining reliable results. All age results were concordant within the experimental errors. The assigned age errors using the LA-MC-ICP-MS technique were, in most cases, higher than those obtained by SHRIMP, but if we are not faced with a high resolution stratigraphy, the laser technique has certain advantages. (author)

In-situ U-Pb, Hf and Re-Os isotopic analyses of the Xiangshan Ni-Cu-Co deposit in Eastern Tianshan (Xinjiang), Central Asia Orogenic Belt: Constraints on the timing and genesis of the mineralization

Science.gov (United States)

Han, Chunming; Xiao, Wenjiao; Zhao, Guochun; Ao, Songjian; Zhang, Jien; Qu, Wenjun; Du, Andao

2010-12-01

The timing and genesis of the major Ni-Cu-Co sulfide deposit in the Xiangshan intrusion have been studied based on newly obtained in-situ U-Pb, Hf and Re-Os isotopic analyses. The SIMS U-Pb zircon ages of the gabbro hosting the Ni-Cu-Co sulfide deposit indicate that the Xiangshan intrusion was emplaced at 279.6 ± 1.1 Ma (95% confidence level, MSWD = 1.30, n = 15). On the basis of combined geological and geochronological evidence, we suggest that the Xiangshan and other adjacent Ni-Cu deposits were formed in the same period. Sulphides have low common Os concentrations and high Re/Os ratios, similar to sulphide ores from the Duluth, Sally Malay and Voisey Bay complexes. The Re-Os isotopic data from the disseminated and massive ores from the Xiangshan intrusion do not form a single isochron, as they have different initial Os ratios. The Hf and Os isotopic data suggest that the Xiangshan intrusion and associated Ni-Cu-Co mineralization were derived from crustally contaminated mantle melts. The geochemical data show a tholeiitic affinity and a strong suprasubduction zone signature with negative Nb, Sr, and Ti anomalies similar to N-MORB and E-MORB. We suggest that the mafic-ultramafic rocks and associated Ni-Cu mineralization of the Eastern Tianshan orogen formed in an Alaska-type subduction zone-arc setting. Some diagnostic features of ridge-trench interaction are present in the Chinese East Tianshan orogen (e.g. granites, adakites, high-Mg andesites, near-trench magmatism, Alaskan-type mafic-ultramafic complexes, high-temperature metamorphic belts that prograde rapidly from low-grade belts, and orogenic gold deposits). The above distinctive rock groups are probably related to the same thermal event, ridge subduction, as in the Cenozoic orogen of Alaska. We suggest that ridge subduction is the most plausible mechanism to provide the necessary heat. Ridge subduction provides an important promising model for understanding many aspects of the evolution of the Chinese

Evolution of the SrTiO3/MoO3 interface electronic structure: An in situ photoelectron spectroscopy study

KAUST Repository

Du, Yuanmin; Peng, Haiyang; Mao, Hongying; Jin, Kexin; Wang, Hong; Li, Feng; Gao, Xingyu; Chen, Wei; Wu, Tao

2015-01-01

Modifying the surface energetics, particularly the work function, of advanced materials is of critical importance for a wide range of surface- and interface-based devices. In this work, using in situ photoelectron spectroscopy, we investigated the evolution of electronic structure at the SrTiO3 surface during the growth of ultrathin MoO3 layers. Thanks to the large work function difference between SrTiO3 and MoO3, the energy band alignment on the SrTiO3 surface is significantly modified. The charge transfer and dipole formation at the SrTiO3/MoO3 interface leads to a large modulation of work function and an apparent doping in SrTiO3. The measured evolution of electronic structure and upward band bending suggest that the growth of ultrathin MoO3 layers is a powerful tool to modulate the surface energetics of SrTiO3, and this surface-engineering approach could be generalized to other functional oxides.

Evolution of the SrTiO3/MoO3 interface electronic structure: An in situ photoelectron spectroscopy study

KAUST Repository

Du, Yuanmin

2015-05-12

Modifying the surface energetics, particularly the work function, of advanced materials is of critical importance for a wide range of surface- and interface-based devices. In this work, using in situ photoelectron spectroscopy, we investigated the evolution of electronic structure at the SrTiO3 surface during the growth of ultrathin MoO3 layers. Thanks to the large work function difference between SrTiO3 and MoO3, the energy band alignment on the SrTiO3 surface is significantly modified. The charge transfer and dipole formation at the SrTiO3/MoO3 interface leads to a large modulation of work function and an apparent doping in SrTiO3. The measured evolution of electronic structure and upward band bending suggest that the growth of ultrathin MoO3 layers is a powerful tool to modulate the surface energetics of SrTiO3, and this surface-engineering approach could be generalized to other functional oxides.

U-Pb dating by zircon dissolution method using chemical abrasion

Energy Technology Data Exchange (ETDEWEB)

Takehara, Lucy, E-mail: lucytakehara@gmail.com.br [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil); Chemale Junior, Farid [Universidade de Brasilia (UnB), Brasilia, DF (Brazil). Inst. de Geociencias. Lab. de Geocronologia; Hartmann, Leo A. [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Inst. de Geociencias; Dussin, Ivo A.; Kawashita, Koji [Universidade de Sao Paulo (USP), SP, (Brazil). Centro de Pesquisa Geocronologicas

2012-06-15

Chemical abrasion was carried out on zircons grains of the Temora II standard for U-Pb dating prior to analyses using in situ Laser Ablation-Multi Collector Ion Coupled Plasma Mass Spectrometer (LA-ICPMS) followed by the Isotope Dissolution Thermal Ionization Mass Spectrometer (ID-TIMS) method. The proposed methodology was herein applied in order to reduce primarily the effects of secondary Pb loss, the presence of common lead and/or silicate impurities. Nine Temora II zircon grains were analyzed by the laser ablation method yielding an age of 418.3 +- 4.3 Ma. Zircon grains of a same population were separated for chemical abrasion before dissolution and mass spectrometry analyses. Six fractions of them were separated for isotope dissolution using {sup 235}U-{sup 205}Pb mixed spike after we have checked and assured the laboratory conditions of low blank values for total Pb of less than 2 pg/g. The obtained U-Pb zircon age by the ID-TIMS method was 415.7 +- 1.8 Ma (error 0.43 %) based on four successful determinations. The results are consistent with the published ages for the Temora diorite (Temora I - 416.75 +- 1.3 Ma; Temora II - 416.78 +- 0.33 Ma) and established as 416 +- 0.33 Ma. The technique is thus recommended for high precision U-Pb zircon analyses (error < 1 %), mainly for high resolution stratigraphic studies of Phanerozoic sequences. (author)

Dating the Indo-Asia collision in NW Himalaya: constraints from Sr-Nd isotopes and detrital zircon (U-Pb) and Hf isotopes of Paleogene-Neogene rocks in the Katawaz basin, NW Pakistan

Science.gov (United States)

Zhuang, Guangsheng; Najman, Yani; Millar, Ian; Chauvel, Catherine; Guillot, Stephane; Carter, Andrew

2015-04-01

The time of collision between the Indian and Asian plates is key for understanding the convergence history and the impact on climatic systems and marine geochemistry. Despite much active research, the fundamental questions still remain elusive regarding when and where the Indian plate collided with the Asian plate. Especially in the west Himalaya, the questions become more complex due to disputes on the amalgamation history of interoceanic Kohistan-Ladakh arcs (KLA) with Karakoram of the Asian plate and the Indian plate. Here, we present a result of multiple-isotopic geochemistry and geochronology study in the Katawaz Basin in NW Pakistan, a remnant oceanic basin on the western Indian plate which was the repository for the sediments eroded from the west Himalaya ( Qayyum et al., 1996, 1997a, 1997b, 2001; Carter et al., 2010), to evaluate the time and character of collision in this region. In this study, we analyzed 22 bulk mudstone samples for Sr-Nd isotopes and 11 medium-grained sandstones for detrital zircon (U-Pb) geochronology and Hf isotopes. We constructed the Cenozoic chronology in the Katawaz Basin based on our newly collected detrital zircon U-Pb ages and fission track ages. We present the first record of Katawaz chronology that constrained the Khojak Formation to be current study revealed that the Katawaz sedimentary sequence ranges in age from Eocene to the earliest Miocene. The samples from the Nisai Formation show the 87Sr/86Sr - ɛNd values overlapping those of the end member of the Karakoram of Asian origin, revealing the arrival of Asian detritus on the Indian plate prior to 50 Ma. There are two parallel lines of evidence supporting this conclusion: (1) young zircon grains (Journal of the Geological Society 154, 753-756. Qayyum, M., Lawrence, R.D., Niem, A.R., 1997b. Molasse-Delta-flysch continuum of the Himalayan orogeny and closure of the Paleogene Katawaz Remnant Ocean, Pakistan. International geology review 39, 861-875. Qayyum, M., Niem, A

U-Pb zircon and monazite geochronology of the Hercynian two-mica granite composite pluton of Cabeceiras de Basto (Northern Portugal); Geochronologie U-Pb sur zircon et monazite du massif composite de granite a deux micas hercynien de Cabeceiras de Basto (Nord-Portugal)

Energy Technology Data Exchange (ETDEWEB)

Almeida, A.; Noronha, F. [Universidade do Porto (Portugal). Centro de Geologia; Leterrier, J. [Centre de Recherches Petrographiques et Geochimiques, 54 - Vandoeuvre-les-Nancy (France); Bertrand, J.M. [Universite de Savoie, 73 - Le-Bourget-du-Lac (France). Laboratoire de geodynamique des Chaines alpines

1998-06-01

The zircon and monazite U-Pb minimum age of the Hercynian peraluminous two-mica composite granite pluton of Cabeceiras de Basto (Northern Portugal) is 311 {+-} 1 Ma (2 {sigma}). This age, well constrained by a concordant monazite of 311{+-}4 Ma (2{sigma}), is in good agreement with the age suggested for the syn-kinematic, syn-D3, Iberian granites of the Hercynian orogeny (315-305; Pinto et al., 1987). The ({sup 87}Sr/{sup 86}Sr){sub i} and {xi}{sub Nd} isotopic ratios, calculated for 311 Ma, suggest that the three granite units which constitute the massif may derive from an heterogeneous crustal source dated (upper intercept of the discordance) around 1200 Ma. (authors) 21 refs.

Controlling the conductivity of amorphous LaAlO3/SrTiO3 interfaces by in-situ application of an electric field during fabrication

DEFF Research Database (Denmark)

Trier, Felix; Amoruso, S.; Christensen, Dennis Valbjørn

2013-01-01

Amorphous-LaAlO3/SrTiO3 interfaces present metallic conductivity similar to those found in their all-crystalline counterparts. Here, the conductivity of amorphous-LaAlO3/SrTiO3 interfaces is modified by an external electric field applied in-situ with a biased truncated cone electrode (−10 V ≤ Vbias...

U/Pb dating: brioverian age of the Erquy series (Armorican massif, France)

International Nuclear Information System (INIS)

Cocherie, A.; Chantraine, J.; Egal, E.; Fanning, C.M.; Dabard, M.P.; Paris, F.; Le Herisse, A.

2001-01-01

New U/Pb analyses obtained with a high-resolution ion microprobe (SHRIMP) fix an age of 608 ± 7 Ma for spilites of the Erquy series, in Cadomian rocks of the Armorican massif, France. This Neo-proterozoic age re-integrates this unit into the Brioverian, the age it was initially assigned to. A Rb/sr whole-rock dating in the 1970's had undermined the regional Cadomian model, by suggesting an Ordovician age for these rocks; this was apparently further supported by the discovery of organic remains, interpreted as Paleozoic micro-fossils. The reassessment of this paleontologic attribution and the new isotope dating are a final confirmation of the age of this series. (authors)

Modelling of 90Sr in-situ migration: models comparison and coupled soil characterisation

International Nuclear Information System (INIS)

Piault, E.; van Dorpe, F.; Cartalade, A.; Beaucaire, C.; Fernandez, J.M.

2005-01-01

Full text of publication follows: In 1960, the Institute of Nuclear Protection and Safety of the French Atomic Energy Commission (CEA/IPSN) had launched a research program to quantify the soil-plant transfer of 90 Sr (transfer between soils, grapes and wine). The studies were conducted in-situ with the help of the National Institute for Agronomic Research (INRA) on an experimental site of Mediterranean type. The experiments consisted in contaminating with soluble strontium salt solutions (SrCl 2 ) a 400 m 2 (10 m x 40 m) piece of land bordered by two uncontaminated strip used as blanks. Prior to planting, the superficial layer of the contaminated plot had then been ploughed in order to homogenize the contamination on a depth of about 10 cm. Over time, the radionuclide was transported from the surface layer to the underground layers of the plot due to climatic factors. The 90 Sr migration over the last 40 years was studied owing eight 70 cm deep cores to perform a radiological and physico-chemical characterization of the soil. The vertical migration modelling of 90 Sr required the definition of a triple layers model whose the only external factor of influence considered is the rainwater infiltration at constant flux. Simulations were made using the code PORFLOW and also the code CAST3M, developed by CEA. These codes solve calculations of flows in unsaturated porous media taking into account the sorption/desorption phenomena of chemical species and radioactive decay. To complete the study an estimation of 90 Sr K d sorption coefficient (used by transfer models) using ion-exchange model was carried out for each layers. The dependence of 90 Sr K d on competitor cations present in fluids is analysed. The study shows that the agreement between the experimental and simulated results is acceptable if the characterization steps, including sampling are properly undertaken. The necessity to characterize the site according to needs of numerical modelling, in an iterative cycle

Permian A-type rhyolites of the Muráň Nappe, Inner Western Carpathians, Slovakia: in-situ zircon U-Pb SIMS ages and tectonic setting

Science.gov (United States)

Ondrejka, Martin; Li, Xian-Hua; Vojtko, Rastislav; Putis, Marian; Uher, Pavel; Sobocký, Tomas

2018-04-01

Three representative A-type rhyolitic rock samples from the Muráň Nappe of the inferred Silicic Unit of the Inner Western Carpathians (Slovakia) were dated using the high-precision SIMS U-Pb isotope technique on zircons. The geochronological data presented in this paper is the first in-situ isotopic dating of these volcanic rocks. Oscillatory zoned zircon crystals mostly revealed concordant Permian (Guadalupian) ages: 266.6 ± 2.4 Ma in Tisovec-Rejkovo (TIS-1), 263.3 ± 1.9 Ma in Telgárt-Gregová Hill (TEL-1) and 269.5 ± 1.8 Ma in Veľká Stožka-Dudlavka (SD-2) rhyolites. The results indicate that the formation of A-type rhyolites and their plutonic equivalents are connected to magmatic activity during the Permian extensional tectonics and most likely related to the Pangea supercontinent break-up.

Morphology and U-Pb ages of zircons from the high-grade metamorphic Precambrian in the Sirdal-Oersdal area, SW Norway

International Nuclear Information System (INIS)

Wielens, J.B.W.

1979-01-01

The U-Pb systematics of seven suites of zircons and two apatites were investigated in an attempt to obtain data about the pre-Sveconorwegian geochronology. Very little was known about this earlier history, as previous studies have shown that the high-grade metamorphism has obliterated most of the older Rb-Sr record. Three samples were investigated from the augengneisses, two from the pyroxene syenites, one garnetiferous migmatite and one magnetite-ilmenite-zircon veinlet cross-cutting the charnockitic migmatites. (Auth.)

New zircon U-Pb LA-ICP-MS ages and Hf isotope data from the Central Pontides (Turkey): Geological and geodynamic constraints

Science.gov (United States)

Çimen, Okay; Göncüoğlu, M. Cemal; Simonetti, Antonio; Sayit, Kaan

2018-05-01

The Central Pontides in northern Anatolia is located on the accretionary complex formed by the closure of Neotethyan Intra-Pontide Ocean between the southern Eurasian margin (Istanbul-Zonguldak Terrane) and the Cimmerian Sakarya Composite Terrane. Among other components of the oceanic lithosphere, it comprises not yet well-dated felsic igneous rocks formed in arc-basin as well as continent margin settings. In-situ U-Pb age results for zircons from the arc-basin system (öangaldağ Metamorphic Complex) and the continental arc (Devrekani Metadiorite and Granitoid) yield ages of 176 ± 6 Ma, 163 ± 9 Ma and 165 ± 3 Ma, respectively. Corresponding in-situ average (initial) 176Hf/177Hf initial ratios are 0.28261 ± 0.00003, 0.28267 ± 0.00002 and 0.28290 ± 0.00004 for these units and indicative of a subduction-modified mantle source. The new U-Pb ages and Hf isotope data from these oceanic and continental arc units together with regional geological constraints support the presence of a multiple subduction system within the Intra-Pontide Ocean during the Middle Jurassic.

Zircon Geochronology (U-Pb, Petrography, Geochemistry and Radioisotopes of Bornaward Metarhyolites (Central Taknar Zone-Northwest of Bardaskan

Directory of Open Access Journals (Sweden)

Reza Monazzami Bagherzadeh

2016-07-01

Full Text Available Introduction The Bornaward area is located in the Northeastern Iran (in the Khorasan Razavi province 28 km northwest of the city of Bardaskan at 57˚ 46΄ to 57˚ 52΄ N latitude and 35˚ 21΄ to 35˚ 24΄E longitude. The Taknar structural zone, situated in the North central Iranian micro continent, is part of the Lut block (Forster, 1978. The Taknar zone is an allochthonous block bounded by the Darouneh and Taknar major faults. Much of this zone consists of metarhyolite-rhyodacite volcanic rocks, and rhyolitic tuff with interlayers of sandstone and dolomite (Taknar Formation. Analytical Results ICP-MS analysis of REE and minor elements of samples of the Bornaward metarhyolites was carried out at the ACME Laboratory in Vancouver, Canada. U-Pb dating of the metarhyolites was performed on isolated zircons in Crohn's Laser Lab, in Arizona (Gehrels et al., 2008. Measurement of Rb, Sr, Sm and Nd isotopes and (143Nd/144Ndi and (87Sr/86Sri ratios took place in the radioisotope laboratory of the University of Aveiro in Portugal. Petrography The volcanic rocks are porphyritic, commonly containing phenocrysts of orthoclase and rarely sanidine, quartz and intermediate plagioclase in a groundmass of fine-grained quartz and feldspar. An alteration has produced oriented needles of sericite and clay minerals, clusters of fine-grained green biotite and clots of epidote and chlorite. Geochemistry The compositions of the volcanic rocks are calc alkaline and high K- calc alkaline. The obtained Shand index (Al2O3/( CaO+Na2O+K2O is above 1.1, in the peraluminous S-type granite field (Chappell and White, 2001. Plotted on the TAS diagram (Middlemost, 1994, all the metarhyolite-rhyodacite samples are located in the sub-alkaline field and the majority fall into the rhyolite group. The metarhyolite-rhyodacites show enrichment of LREE with a moderately ascending pattern ((La/YbN=2.51-10.11 and La=46.45-145.48. Europium shows a negative anomaly (Eu/Eu*=0.23-0.71. U-Pb

Atomic layer epitaxy of Ruddlesden-Popper SrO(SrTiO3)n films by means of metalorganic aerosol deposition

International Nuclear Information System (INIS)

Jungbauer, M.; Hühn, S.; Moshnyaga, V.; Egoavil, R.; Tan, H.; Verbeeck, J.; Van Tendeloo, G.

2014-01-01

We report an atomic layer epitaxial growth of Ruddlesden-Popper (RP) thin films of SrO(SrTiO 3 ) n (n = ∞, 2, 3, 4) by means of metalorganic aerosol deposition (MAD). The films are grown on SrTiO 3 (001) substrates by means of a sequential deposition of Sr-O/Ti-O 2 atomic monolayers, monitored in-situ by optical ellipsometry. X-ray diffraction and transmission electron microscopy (TEM) reveal the RP structure with n = 2–4 in accordance with the growth recipe. RP defects, observed by TEM in a good correlation with the in-situ ellipsometry, mainly result from the excess of SrO. Being maximal at the film/substrate interface, the SrO excess rapidly decreases and saturates after 5–6 repetitions of the SrO(SrTiO 3 ) 4 block at the level of 2.4%. This identifies the SrTiO 3 substrate surface as a source of RP defects under oxidizing conditions within MAD. Advantages and limitations of MAD as a solution-based and vacuum-free chemical deposition route were discussed in comparison with molecular beam epitaxy

In Situ Studies of the Temperature-Dependent Surface Structure and Chemistry of Single-Crystalline (001)-Oriented La 0.8 Sr 0.2 CoO 3−δ Perovskite Thin Films

KAUST Repository

Feng, Zhenxing; Crumlin, Ethan J.; Hong, Wesley T.; Lee, Dongkyu; Mutoro, Eva; Biegalski, Michael D.; Zhou, Hua; Bluhm, Hendrik; Christen, Hans M.; Shao-Horn, Yang

2013-01-01

Perovskites are used to promote the kinetics of oxygen electrocatalysis in solid oxide fuel cells and oxygen permeation membranes. Little is known about the surface structure and chemistry of perovskites at high temperatures and partial oxygen pressures. Combining in situ X-ray reflectivity (XRR) and in situ ambient pressure X-ray photoelectron spectroscopy (APXPS), we report, for the first time, the evolution of the surface structure and chemistry of (001)-oriented perovskite La0.8Sr0.2CoO 3-δ (LSC113) and (La0.5Sr 0.5)2CoO4+δ (LSC214)-decorated LSC113 (LSC113/214) thin films as a function of temperature. Heating the (001)-oriented LSC113 surface leads to the formation of surface LSC214-like particles, which is further confirmed by ex situ Auger electron spectroscopy (AES). In contrast, the LSC113/214 surface, with activities much higher than that of LSC 113, is stable upon heating. Combined in situ XRR and APXPS measurements support that Sr enrichment may occur at the LSC113 and LSC214 interface, which can be responsible for its markedly enhanced activities. © 2013 American Chemical Society.

In Situ Studies of the Temperature-Dependent Surface Structure and Chemistry of Single-Crystalline (001)-Oriented La 0.8 Sr 0.2 CoO 3−δ Perovskite Thin Films

KAUST Repository

Feng, Zhenxing

2013-05-02

Perovskites are used to promote the kinetics of oxygen electrocatalysis in solid oxide fuel cells and oxygen permeation membranes. Little is known about the surface structure and chemistry of perovskites at high temperatures and partial oxygen pressures. Combining in situ X-ray reflectivity (XRR) and in situ ambient pressure X-ray photoelectron spectroscopy (APXPS), we report, for the first time, the evolution of the surface structure and chemistry of (001)-oriented perovskite La0.8Sr0.2CoO 3-δ (LSC113) and (La0.5Sr 0.5)2CoO4+δ (LSC214)-decorated LSC113 (LSC113/214) thin films as a function of temperature. Heating the (001)-oriented LSC113 surface leads to the formation of surface LSC214-like particles, which is further confirmed by ex situ Auger electron spectroscopy (AES). In contrast, the LSC113/214 surface, with activities much higher than that of LSC 113, is stable upon heating. Combined in situ XRR and APXPS measurements support that Sr enrichment may occur at the LSC113 and LSC214 interface, which can be responsible for its markedly enhanced activities. © 2013 American Chemical Society.

Atomic layer epitaxy of Ruddlesden-Popper SrO(SrTiO{sub 3}){sub n} films by means of metalorganic aerosol deposition

Energy Technology Data Exchange (ETDEWEB)

Jungbauer, M.; Hühn, S.; Moshnyaga, V. [Erstes Physikalisches Institut, Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Egoavil, R.; Tan, H.; Verbeeck, J.; Van Tendeloo, G. [EMAT, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp (Belgium)

2014-12-22

We report an atomic layer epitaxial growth of Ruddlesden-Popper (RP) thin films of SrO(SrTiO{sub 3}){sub n} (n = ∞, 2, 3, 4) by means of metalorganic aerosol deposition (MAD). The films are grown on SrTiO{sub 3}(001) substrates by means of a sequential deposition of Sr-O/Ti-O{sub 2} atomic monolayers, monitored in-situ by optical ellipsometry. X-ray diffraction and transmission electron microscopy (TEM) reveal the RP structure with n = 2–4 in accordance with the growth recipe. RP defects, observed by TEM in a good correlation with the in-situ ellipsometry, mainly result from the excess of SrO. Being maximal at the film/substrate interface, the SrO excess rapidly decreases and saturates after 5–6 repetitions of the SrO(SrTiO{sub 3}){sub 4} block at the level of 2.4%. This identifies the SrTiO{sub 3} substrate surface as a source of RP defects under oxidizing conditions within MAD. Advantages and limitations of MAD as a solution-based and vacuum-free chemical deposition route were discussed in comparison with molecular beam epitaxy.

A rapid in situ method for determining the ages of uranium oxide minerals: Evolution of the Cigar Lake deposit, Athabasca Basin

International Nuclear Information System (INIS)

Fayek, M.; Harrison, T.M.; Grove, M.; Coath, C.D.

2000-01-01

The authors present a rapid and accurate technique for making in situ U-Pb isotopic measurements of uranium oxide minerals that utilizes both electron and ion microprobes. U and Pb concentrations are determined using an electron microprobe, whereas the isotopic composition of Pb for the same area is measured using a high-resolution ion microprobe. The advantages of this approach are: mineral separation and chemical digestion are unnecessary; homogeneous uranium oxide standards, which are difficult to obtain, are not required; and precise and accurate U-Pb ages on ∼10 microm spots can be obtained in a matter of hours. The authors have applied their method to study the distribution of U-Pb ages in complexly intergrown uranium oxides from the unconformity-type Cigar Lake uranium deposit, Saskatchewan, Canada. In situ U-Pb results from early formed uraninite define a well-correlated array on concordia with upper and lower intercepts of 1,467 ± 63 Ma and 443 ± 96 Ma (±1σ), respectively. The 1,467 Ma age is interpreted as the minimum age of mineralization and is consistent with the age of clay-mineral alteration (approximately1477 Ma) and magnetization of diagenetic hematite (1,650 to 1,450 Ma) that is associated with these unconformity-type uranium deposits and early diagenesis of the Athabasca Basin sediments. In situ U-Pb isotopic analysis of uraninite and coffinite can document the Pb*/U heterogeneities that can occur on a scale of 15 to 30 microm, thus providing relatively accurate information regarding the timing of fluid interactions associated with the evolution of these deposits

Geotectonic structural interpretation of the basement complex at the eastern border of the Espinhaco ridge, in Guanhaes and Gouveia region, based on an integration of their U/Pb and K/Ar geochronology united

International Nuclear Information System (INIS)

Teixeira, W.; Salvador, E.D.; Siga Junior, O.; Sato, K.; Dossin, I.A.; Dossin, T.M.

1990-01-01

The basement complex at the eastern border of the Espinhaco ridge is composed of predominantly gneissic rocks which were subjected to migmatization and granitization. Overall the area shows complex tectonic evolution with recurrence of tectonomagmatic and metamorphic events as supported by geological, geochronological and structural studies. The Rb/Sr geochronology carried out on the basement rocks and metavolcanics from the Espinhaco interpreted together with the published U-Pb, Rb-Sr and K-Ar data defines the following scenario for the Precambrian crustal evolution. 1. Primary origin of a sialic crust at 2.97-2.84 Ga. ago as supported by U-Pb zircon ages. 2. Crustal reworking of the Archean crust and subordinate juvenile accretion from upper mantle during the 2.2-2.OGa. period, as suggested by the isochrons. 3. Recurrence of Middle Proterozoic events over the basement rocks (gneisses and charnockites) and metavolcanics of the Espinhaco as showed by isochrons. 4. Development of Late Proterozoic migmatization over the basement rocks (0.75 Ga., R.I.= 0.787) is association with Collisional tectonics and resetting of K-Ar mineral systems. (author)

In-situ YBa2Cu3O7/SrTiO3/YBa2Cu3O7 a-b plane Josephson edge junctions

International Nuclear Information System (INIS)

Aharoni, E.; Koren, G.; Polturak, E.; Cohen, D.; Iskevitch, E.

1992-01-01

YBCO/SrTiO 3 /YBCO thin film edge junctions were prepared in-situ and characterized. The epitaxial growth of SrTiO 3 on YBCO led to a sharp and well defined junction edge with a very high yield. Typical junctions showed critical currents up to 83 K, with I c ∝ (1 - T/Tc) 2 temperature dependence. Sharp Shapiro steps were observed under microwave radiation at temperatures up to 82 K. A typical diffraction pattern was found in the voltage response of the junctions to transverse magnetic field. (orig.)

Voltage-Controlled Topotactic Phase Transition in Thin-Film SrCoOx Monitored by In Situ X-ray Diffraction.

Science.gov (United States)

Lu, Qiyang; Yildiz, Bilge

2016-02-10

Topotactic phase transition of functional oxides induced by changes in oxygen nonstoichiometry can largely alter multiple physical and chemical properties, including electrical conductivity, magnetic state, oxygen diffusivity, and electrocatalytic reactivity. For tuning these properties reversibly, feasible means to control oxygen nonstoichiometry-dependent phase transitions in functional oxides are needed. This paper describes the use of electrochemical potential to induce phase transition in strontium cobaltites, SrCoOx (SCO) between the brownmillerite (BM) phase, SrCoO₂.₅, and the perovskite (P) phase, SrCoO₃₋δ. To monitor the structural evolution of SCO, in situ X-ray diffraction (XRD) was performed on an electrochemical cell having (001) oriented thin-film SrCoOx as the working electrode on a single crystal (001) yttria-stabilized zirconia electrolyte in air. In order to change the effective pO₂ in SCO and trigger the phase transition from BM to P, external electrical biases of up to 200 mV were applied across the SCO film. The phase transition from BM to P phase could be triggered at a bias as low as 30 mV, corresponding to an effective pO₂ of 1 atm at 500 °C. The phase transition was fully reversible and the epitaxial film quality was maintained after reversible phase transitions. These results demonstrate the use of electrical bias to obtain fast and easily accessible switching between different phases as well as distinct physical and chemical properties of functional oxides as exemplified here for SCO.

U-Pb, Sm-Nd and Rb-Sr systematics of mid-ocean ridge basalt glasses

Energy Technology Data Exchange (ETDEWEB)

Cohen, R S; Evensen, N M; Hamilton, P J; O' Nions, R K [Columbia Univ., Palisades, NY (USA). Lamont-Doherty Geological Observatory

1980-01-10

The measurement of Pb, Nd and Sr isotopes in basalt glasses from mid-ocean ridges reveals correlations in isotope parameters which have important implications for the differentiation history of the mantle.

The Pan-African Kekem gabbro-norite (West-Cameroon), U-Pb zircon age, geochemistry and Sr-Nd isotopes: Geodynamical implication for the evolution of the Central African fold belt

Science.gov (United States)

Kwékam, Maurice; Affaton, Pascal; Bruguier, Olivier; Liégeois, Jean-Paul; Hartmann, Gerald; Njonfang, Emmanuel

2013-08-01

The Kekem shoshonitic gabbro-norite association is part of the high-K calc-alkaline (HKCA) post-collisional magmatism, a major feature of the Pan-African Belt in Cameroon. LA-ICP-MS U-Pb zircon analyses provide an age of 576 ± 4 Ma for the Kekem complex. This age is interpreted as dating the emplacement of the massif during the waning stage of the Pan-African orogeny. The latter is related to dextral movements along the Central Cameroon Shear Zone (CCSZ). The REE patterns display enriched LREE (LaN/YbN = 14.2-23.5) while HREE present a nearly flat profile (DyN/YbN = 1.3-1.7), and the La/Sm and Sm/Yb ratios led to propose that the Kekem gabbro-norites have been derived from the partial melting of a garnet-spinel lherzolite mantle source. The negative Nb-Ta and Ti anomalies and the positive Pb anomalies indicate that this mantle source was modified by contribution of a subduction-related material. The low Ce/Pb (2.6-10.4) and Th/Yb ratios associated to high Ba/La ratios, indicate that source enrichment could be related to slab derived fluids. As a whole, the Kekem geochemical features suggest that primary gabbro-noritic magmas derived from a subduction-modified mantle source (metasomatised lithospheric mantle). Moderately high 86Sr/87Sr initial ratios (0.7068-0.7082), low ɛNd (-5 to -9) and old Nd TDM model ages (1.6-1.8 Ga) are interpreted to result from contamination of Neoproterozoic mantle by the Paleoproterozoic crust. The ca. 576 Ma movements along the CCSZ are related to a Neoproterozoic metacratonization of the northern margin of the Congo craton during the Pan-African orogeny. This metacratonization led to vertical planar lithospheric delamination along lithospheric transcurrent faults, asthenospheric uprise and partial melting of the Paleoproterozoic lithospheric mantle.

From opening to subduction of an oceanic domain constrained by LA-ICP-MS U-Pb zircon dating (Variscan belt, Southern Armorican Massif, France)

Science.gov (United States)

Paquette, J.-L.; Ballèvre, M.; Peucat, J.-J.; Cornen, G.

2017-12-01

In the Variscan belt of Western Europe, the lifetime and evolution of the oceanic domain is poorly constrained by sparse, outdated and unreliable multigrain ID-TIMS U-Pb zircon dating. In this article, we present a complete in situ LA-ICP-MS dataset of about 300 U-Pb zircon analyses obtained on most of the ophiolitic and eclogitic outcrops of Southern Brittany, comprising new dating of previously published zircon populations and newly discovered rock samples. In situ dating and cathodo-luminescence imaging of each zircon grain yields new absolute time-constraints on the evolution of the Galicia-Moldanubian Ocean. The new results confirm that the opening of this oceanic domain is well defined at about 490 Ma. In contrast, the generally-quoted 400-410 Ma-age for the high-pressure event related to the subduction of the oceanic crust is definitely not recorded in the zircons of the eclogites. In light of these new data, we propose that the obduction of oceanic rocks occurred at about 370-380 Ma while the high-pressure event is recorded at 355 Ma in only a few zircon grains of some eclogite samples. Additionally, this large scale dating project demonstrates that the zircons from eclogites do not systematically recrystallise during the high pressure event and consequently their U-Pb systems do not record that metamorphism systematically. These zircons rather preserve the isotopic memory of the magmatic crystallization of their igneous protolith. Another example of an eclogite sample from the French Massif Central illustrates the frequent mistake in the interpretation of the ages of the early hydrothermal alteration of zircons in the oceanic crust versus partial or complete recrystallization during eclogite facies metamorphism.

U-Pb dating of two granite types from Soultz (Rhine Graben, France); Datation U-Pb des deux facies du granite de Soultz (fosse rhenan, France)

Energy Technology Data Exchange (ETDEWEB)

Cocherie, A.; Guerrot, C.; Genter, A. [Bureau de Recherches Geologiques et Minieres (BRGM), 45 - Orleans (France); Fanning, C.M. [Research School of Earth Sciences, ANU, Canberra, (Australia)

2004-07-01

Deep boreholes drilled in the basement of the Rhine Graben at Soultz-sous-Forets have shown the presence of an ubiquitous monzogranite. Borehole GPK-2, with a total depth of 5090 m, also intersected a more leucocratic fine-grained two-mica granite, locally present below 4860 m depth and continuously found between 5047 and 5090 m. Thanks to trace elements and in particular to REE (rare-earth elements), it could be shown that the leucocratic rock is a differentiated expression of the potassic magma that was at the origin of the monzogranite pluton. This model agrees with Sr-Nd isotope data, even though a slight contribution from the pre-existing basement should be considered as well. Use of the U-Pb method on monzogranite from EPS-1 - after zircon dissolution - has yielded an emplacement age of 334.0 + 3.8/-3.5 Ma (2 {sigma}). Point dates obtained by SHRIMP II on the rare zircons from the fine-grained granite showed that it was emplaced in a basement with very heterogeneous ages, ranging from Early Proterozoic to Silurian. (author)

Possible zircon U-Pb evidence for Pan-African granulite-facies metamorphism in the Mozambique belt of southern Tanzania

International Nuclear Information System (INIS)

Coolen, J.J.M.M.M.

1982-01-01

Four zircon fractions of garnet-bearing two-pyroxene granulite, from the Furua granulite complex of southern Tanzania, plot very close to concordia. A discordia yields a lower intercept at 652 +- 10 Ma, an age slightly higher than the Rb-Sr whole-rock and mineral ages reported from the surrounding amphibolite-facies rocks. The U-Pb systematics indicate the presence of a very small amount of older (2-3 Ga) radiogenic lead. The zircon data may be interpreted as indicating an event of granulite-facies metamorphism during the Pan-African thermotectonic episode. This interpretation is at variance with current models postulating that the granulite complexes in the Mozambique belt are relicts of older, possibly Archaean events of metamorphism. (Auth.)

Field demonstration of in situ treatment of buried low-level radioactive solid waste with caustic soda and soda ash to immobilize 90Sr

International Nuclear Information System (INIS)

Spalding, B.P.

1984-02-01

A low-level radioactive solid waste disposal trench was injected on four occasions with solutions of caustic soda, soda ash, caustic soda, and lime/soda ash, respectively. Because investigations had indicated that 90 Sr could be coprecipitated with soil calcium carbonate by treatment with soda ash, this demonstration was undertaken as a test of its technical feasibility. After concentrations of 90 Sr and water hardness decreased within the intratrench monitoring wells; one well at the foot of the trench decreased from over 100 to a persistent level of less than 10 kBq of 90 Sr per liter. Recharge of 90 Sr from the trench to a sump immediately below was reduced by about 90%. Water hardness and 90 Sr concentrations were strongly correlated through time within each monitoring well, indicating that 90 Sr behaved as a tracer for soil calcium and magnesium. The disappearance of 90 Sr from the trench water, therefore, was an in situ water softening. Soil samples retrieved from the trench indicated that as much as 98% of the total 90 Sr was present as a coprecipitate with calcium carbonate. The hydrologic characterization of this trench indicated an average void space of 41% and an average trench-wall hydraulic conductivity of 3.4 x 10 -7 m/s. Sampling of the trench's discharge contamination plume indicated that it had resulted from a combination of subsurface seepage and bathtub overflow during infrequent periods of intense precipitation. A generic assessment of soda ash treatment indicated that treatment would be most effective for soils of high cation exchange capacity with either low ( 80%) basic cation saturation of that cation exchange capacity

Epitaxial growth and thermodynamic stability of SrIrO3/SrTiO3 heterostructures

Science.gov (United States)

Groenendijk, D. J.; Manca, N.; Mattoni, G.; Kootstra, L.; Gariglio, S.; Huang, Y.; van Heumen, E.; Caviglia, A. D.

2016-07-01

Obtaining high-quality thin films of 5d transition metal oxides is essential to explore the exotic semimetallic and topological phases predicted to arise from the combination of strong electron correlations and spin-orbit coupling. Here, we show that the transport properties of SrIrO3 thin films, grown by pulsed laser deposition, can be optimized by considering the effect of laser-induced modification of the SrIrO3 target surface. We further demonstrate that bare SrIrO3 thin films are subject to degradation in air and are highly sensitive to lithographic processing. A crystalline SrTiO3 cap layer deposited in-situ is effective in preserving the film quality, allowing us to measure metallic transport behavior in films with thicknesses down to 4 unit cells. In addition, the SrTiO3 encapsulation enables the fabrication of devices such as Hall bars without altering the film properties, allowing precise (magneto)transport measurements on micro- and nanoscale devices.

Carboniferous climate teleconnections archived in coupled bioapatite δ18OPO4 and 87Sr/86Sr records from the epicontinental Donets Basin, Ukraine

Science.gov (United States)

Montañez, Isabel P.; Osleger, Dillon J.; Chen, Jitao; Wortham, Barbara E.; Stamm, Robert G.; Nemyrovska, Tamara I.; Griffin, Julie M.; Poletaev, Vladislav I.; Wardlaw, Bruce R.

2018-06-01

Reconstructions of paleo-seawater chemistry are largely inferred from biogenic records of epicontinental seas. Recent studies provide considerable evidence for large-scale spatial and temporal variability in the environmental dynamics of these semi-restricted seas that leads to the decoupling of epicontinental isotopic records from those of the open ocean. We present conodont apatite δ18OPO4 and 87Sr/86Sr records spanning 24 Myr of the late Mississippian through Pennsylvanian derived from the U-Pb calibrated cyclothemic succession of the Donets Basin, eastern Ukraine. On a 2 to 6 Myr-scale, systematic fluctuations in bioapatite δ18OPO4 and 87Sr/86Sr broadly follow major shifts in the Donets onlap-offlap history and inferred regional climate, but are distinct from contemporaneous more open-water δ18OPO4 and global seawater Sr isotope trends. A -1 to -6‰ offset in Donets δ18OPO4 values from those of more open-water conodonts and greater temporal variability in δ18OPO4 and 87Sr/86Sr records are interpreted to primarily record climatically driven changes in local environmental processes in the Donets sea. Systematic isotopic shifts associated with Myr-scale sea-level fluctuations, however, indicate an extrabasinal driver. We propose a mechanistic link to glacioeustasy through a teleconnection between high-latitude ice changes and atmospheric pCO2 and regional monsoonal circulation in the Donets region. Inferred large-magnitude changes in Donets seawater salinity and temperature, not archived in the more open-water or global contemporaneous records, indicate a modification of the global climate signal in the epicontinental sea through amplification or dampening of the climate signal by local and regional environmental processes. This finding of global climate change filtered through local processes has implications for the use of conodont δ18OPO4 and 87Sr/86Sr values as proxies of paleo-seawater composition, mean temperature, and glacioeustasy.

Phase stability and oxygen non-stoichiometry of SrCo0.8Fe0.2O3-d measured by in-situ neutron diffraction

NARCIS (Netherlands)

McIntosh, Steven; McIntosh, S.; Vente, Jaap F.; Haije, Wim G.; Blank, David H.A.; Bouwmeester, Henricus J.M.

2006-01-01

The phase stability, oxygen stoichiometry and expansion properties of SrCo0.8Fe0.2O3−δ (SCF) were determined by in situ neutron diffraction between 873 and 1173 K and oxygen partial pressures of 5×10−4 to 1 atm. At a pO2 of 1 atm, SCF adopts a cubic perovskite structure, space group Pm3¯m, across

Electron microscopic in situ study of phase and defect formation in Bi2Sr2CaCu2Oy single crystals in heating

International Nuclear Information System (INIS)

Goncharov, V.A.; Ignat'eva, E.Yu.; Osip'yan, Yu.A.; Suvorov, Eh.V.

1997-01-01

The nonthermal effect of electron irradiation on generating of new phases and structural defects has been uncovered during the investigation of structural variations of monocrystals Bi 2 Sr 2 CaCu 2 O y on heating in situ. The stability of the modulated structure and the package defects to heating under the electron beam action and in the absence of the irradiation has been studied

U-Pb Dating of Zircons and Phosphates in Lunar Meteorites, Acapulcoites and Angrites

Science.gov (United States)

Zhou, Q.; Zeigler, R. A.; Yin, Q. Z.; Korotev, R. L.; Joliff, B. L.; Amelin, Y.; Marti, K.; Wu, F. Y.; Li, X. H.; Li, Q. L.;

The effect of secondary apatite on the initial 87Sr/86Sr ratio determination in granitic rocks: a case study of the Tadamigawa pluton, northeastern Japan

Science.gov (United States)

Wakasugi, Y.; Ichino, K.; Tanioka, Y.; Wakaki, S.; Tsuboi, M.; Ishikawa, T.

2017-12-01

Apatite is a major accessory mineral in igneous rocks. Because Rb contents in apatite are very low, 87Sr/86Sr ratios of magmatic apatite are useful to estimate the initial 87Sr/86Sr ratio (SrI) of igneous rocks. Secondary post-magmatic event such as hydrothermal alteration may also crystallize secondary apatite, which may inhibit the estimation of SrI of igneous rocks. In this study, we examine the effects of secondary apatite on the initial 87Sr/86Sr ratio determination of granitic rocks by using acid leaching technique. Leached apatite samples were first separated from the whole rock powder as a heavy mineral fraction by heavy liquid technique, and the heavy mineral fraction was then leached by 3 M HNO3. The isotopic ratios of Sr and the concentrations of Rb and Sr were analyzed by TIMS and ICP-MS at Kochi Core Center, respectively. The Tadamigawa Older-stage granites, which locate in the Taishaku Mountains at the northeastern part of Japan, intrude into the Ashio Jurassic complex, and the ages of these rocks are late Cretaceous to Paleogene. The U-Pb ages of zircon and the K-Ar ages of biotite for these rocks are c. 100 Ma [1, 2]. Rb-Sr whole-rock isochron age of the pluton is 96.5 ± 1.3 Ma (SrI = 0.70534 ± 0.00003) and it is concordant with other radiometric ages. Rb-Sr mineral isochron ages range from 84.4 to 97.3 Ma and these ages are relatively younger than the Rb-Sr whole-rock isochron age. The difference among radiometric ages may reflect the difference of the closure temperature in each isotopic system. The Tadamigawa Older-stage granites have SrI for Rb-Sr mineral isochron range from 0.7053 to 0.7061 and are very similar to that (0.70534) for Rb-Sr whole-rock isochron. These may suggest that the Tadamigawa Older-stage granites are generated from same parental magma. However, 87Sr/86Sr ratios of the leached apatite samples were 0.70544-0.70856 and are relatively higher than SrI obtained from the Rb-Sr mineral isochrons (0.7053-0.7061). This result

Long-lasting Cadomian magmatic activity along an active northern Gondwana margin: U-Pb zircon and Sr-Nd isotopic evidence from the Brunovistulian Domain, eastern Bohemian Massif

Science.gov (United States)

Soejono, Igor; Janoušek, Vojtěch; Žáčková, Eliška; Sláma, Jiří; Konopásek, Jiří; Machek, Matěj; Hanžl, Pavel

2017-09-01

Cadomian magmatic complexes of the Brunovistulian Domain crop out at the eastern termination of the Bohemian Massif. However, the age, nature and geotectonic affinity of some of pre-Variscan (meta-)igneous rock complexes from this domain are still unknown. Geochronological and geochemical study of the granitic rocks across the Brunovistulian Domain reveals new information about the timing and nature of this magmatic activity originally situated along the northern margin of Gondwana. Zircon U-Pb data (601 ± 3 Ma, Brno Massif; 634 ± 6 Ma, paraautochtonous core of the Svratka Dome; 568 ± 3 Ma, Bíteš orthogneiss) from the allochtonous Moravicum indicate the prolonged magmatic activity within the Brunovistulian Domain during the Ediacaran. The major- and trace-element and Sr-Nd isotopic signatures show heterogeneous geochemical characteristics of the granitic rocks and suggest a magmatic-arc geotectonic setting. The two-stage Depleted Mantle Nd model ages ( c. 1.3-2.0 Ga) indicate derivation of the granitic rocks from a relatively primitive crustal source, as well as from an ancient and evolved continental crust of the Brunovistulian Domain. These results constrain the magmatic-arc activity to c. 635-570 Ma and provide a further evidence for a long-lived (at least c. 65 Myr) and likely episodic subduction-related magmatism at the northern margin of Gondwana. The presence of granitic intrusions derived from variously mature crustal sources at different times suggests heterogeneous crustal segments to having been involved in the magmatic-arc system during its multistage evolution.

Conventional U-Pb dating versus SHRIMP of the Santa Barbara Granite Massif, Rondonia, Brazil

Science.gov (United States)

Sparrenberger, I.; Bettencourt, Jorge S.; Tosdal, R.M.; Wooden, J.L.

2002-01-01

The Santa Ba??rbara Granite Massif is part of the Younger Granites of Rondo??nia (998 - 974 Ma) and is included in the Rondo??nia Tin Province (SW Amazonian Craton). It comprises three highly fractionated metaluminous to peraluminous within-plate A-type granite units emplaced in older medium-grade metamorphic rocks. Sn-mineralization is closely associated with the late-stage unit. U-Pb monazite conventional dating of the early-stage Serra do Cicero facies and late-stage Serra Azul facies yielded ages of 993 ?? 5 Ma and 989 ?? 13 Ma, respectively. Conventional multigrain U-Pb isotope analyses of zircon demonstrate isotopic disturbance (discordance) and the preservation of inherited older zircons of several different ages and thus yield little about the ages of Sn-granite magmatism. SHRIMP U-Pb ages for the Santa Ba??rbara facies association yielded a 207Pb/206Pb weighted-mean age of 978 ?? 13 Ma. The textural complexity of the zircon crystals of the Santa Ba??rbara facies association, the variable concentrations of U, Th and Pb, as well as the mixed inheritance of zircon populations are major obstacles to using conventional multigrain U-Pb isotopic analyses. Sm-Nd model ages and ??Nd (T) values reveal anomalous isotopic data, attesting to the complex isotopic behaviour within these highly fractionated granites. Thus, SHRIMP U-Pb zircon and conventional U-Pb monazite dating methods are the most appropriate to constrain the crystallization age of the Sn-bearing granite systems in the Rondo??nia Tin Province.

A study of U-Pb isotopic evolutionary system in Chanziping uranium deposit

International Nuclear Information System (INIS)

Xu Weichang; Huang Shijie; Xia Yuliang.

1988-01-01

Chanziping uranium deposit occurred in the black siliceous slate of Lower cambrian. The uranium mineralization was controlled by both interstratified fault belt and the ore-bearing beds. Based on the study of the U-Pb isotopic system of the various rocks, ores and minerals in the ore-bearing beds, the authors find out the obvious disequilibrium of U-Pb isotopic composition in most rock samples which indicates the loss of uranium form the ore-bearing beds and surrounding granite. Its counting loss ranges from 30 to 80%. The age of rich ores of the U-Pb concordance diagram and the U-Pb three stage model are t 1 = 523 ± 19M. Y. , t 2 = 22 ± 2 M.Y.. The isochronal ages for pitchblend are 75 ± 4 M.Y., 43 ± 7 M.Y., and for rock is 416 M.y.. These data shows that the uranium in ore-bearing beds was mainly derived from the ore-bearing beds itself and partly from the surrounding granite. The ore deposit can be considered to be of stratabound uranium deposit of sedimentation and late transformation type

U-Pb age of the Anuri dyke: paleoproterozoic potassic alkaline magmatism and implications for the Transamazonic orogeny in the Sao Francisco Craton

International Nuclear Information System (INIS)

Conceicao, Herbet; Rios, Debora Correia; Oberli, Felix

2007-01-01

The Anuri Syenitic Dyke (72 km 2 ) is the south representative of a 1000 km N-S alignment of syenitic dykes which occur at the East Bahia. As the others bodies, Anuri is essentially composed of hypersolvus ultrapotassic syenites, which show the records of its differentiation by the presence of mafic-ultramafic apatite-rich cumulates. Its crystallization age of 2095- 4 Ma (U-Pb zircao ) is quite similar with results obtained for the other syenitic dykes, which suggest that their intrusions occur almost at the same time, sincronically, after the Transamazonic Orogeny climax. The geochemical data reveal that Anuri syenites are Ba, Sr, P, LREE enriched and show negative anomalies of Ti and Nb, suggesting a mantelic source subduction related. The initial Sr ratio and ε Nd values confirms the presence of this anomalous mantle. These data suggest that at the end of Transamazonic Orogeny, at the Sao Francisco Craton, there were particular conditions which allow the generation of alkaline magmas through the melting of an EMI reservoir. (author)

Age and origin of anorthosites, charnockites, and granulites in the Central Virginia Blue Ridge: Nd and Sr isotopic evidence

Science.gov (United States)

Pettingill, H.S.; Sinha, A.K.; Tatsumoto, M.

1984-01-01

Rb-Sr isotopic data for anorthosites, charnockites, ferrodioritic to quartz monzonitic plutons, and high-grade gneisses of the Blue Ridge of central Virginia show evidence of post-emplacement metamorphism, but in some cases retain Grenville ages. The Pedlar River Charnockite Suite yields an isochron age of 1021 +/-36 Ma, (initial 87Sr/86Sr ratio of 0.7047 +/-6), which agrees with published U-Pb zircon ages. Five samples of that unit which contain Paleozoic mylonitic fabrics define a regression line of 683 Ma, interpreted as a mixing line with no age significance. Samples of the Roseland Anorthosite Complex show excessive scatter on a Rb-Sr evolution diagram probably due to Paleozoic (475 m.y.) metamorphism. Data from the ferrodioritic to quartz monzonitic plutons of the area yield an age of 1009 +/-26 Ma (inital ratio=0.7058 +/-4), which is in the range of the U-Pb zircon ages of 1000-1100 Ma. The Stage Road Layered Gneiss yields an age of 1147 +/-34 Ma (initial ratio of 0.7047 +/- 5). Sm-Nd data for the Pedlar River Charnockite Suite reflect a pre-Grenville age of 1489 +/-118 Ma (e{open}Nd=+6.7 +/-1.2). Data for the Roseland Anorthosite Complex and the ferrodioritic to quartz monzonitic plutons yield Grenville isochron ages of 1045 +/44 Ma (e{open}Nd=+1.0 +/-0.3) and 1027 +/-101 Ma (e{open}Nd=+1.4 +/-1.0), respectively. Two Roseland Anorthosite samples plot far above the isochron, demonstrating the effects of post-emplacement disturbance of Sm-Nd systematics, while mylonitized Pedlar River Charnockite Suite samples show no evidence of Sm-Nd redistribution. The disparity of the Sm-Nd age and other isotopic ages for the Pedlar River Charnockite Suite probably reflects a Sm-Nd "source" age, suggesting the presence of an older crust within this portion of the ca. 1 Ga old basement. ?? 1984 Springer-Verlag.

Geology, mineralization, U-Pb dating and Sr-Nd isotope geochemistry of intrusive bodies in northeast of Kashmar

Directory of Open Access Journals (Sweden)

Alireza Almasi

2015-04-01

Full Text Available Alireza Almasi1, Mohammad Hassan Karimpour1*, Khosrow Ebrahimi Nasrabadi1, Behnam Rahimi1, Urs KlÖtzli2 and Jose Francisco Santos3 Introduction The study area is located in central part of the Khaf- Kashmar-Bardeskan belt which is volcano-plutonic belt at the north of the Dorouneh fault in the north of Lut block. The north of the Lut block is affected by tectonic rotation and subduction processes which occur in the east of Iran (Tirrul et al., 1983. The magmatism of Lut block begins in Jurassic and continues in Tertiary (Aghanabati, 1995. Karimpour (Karimpour, 2006 pointed out the Khaf-Kashmar-Bardeskan belt has significant potential for IOCG type mineralization such as Kuh-e-Zar, Tannurjeh, and Sangan (Karimpour, 2006; Mazloumi, 2009. The data gathered on the I-type intrusive rocks include their field geology, petrography, U–Pb zircon dating and Sr–Nd isotope and also alteration and mineralization in the study area. Materials and methods - Preparation of 150 thin sections of rock samples for study of petrography and alteration of the intrusive rocks. - Magnetic susceptibility measuring of intrusive rocks. - U-Pb dating in zircon of I-type intrusive rocks by Laser-Ablation Multi Collector ICP-MS method. - Sr-Nd analysis on 5 samples of I-type intrusive rocks by Multi-Collector Thermal Ionization Mass Spectrometer (TIMS VG Sector 54 instrument. - Mineralography and paragenetic studies of ore-bearing quartz veins and geochemical analysis for 28 samples. - Production of the geology, alteration and mineralization maps by scale: 1:20000 in GIS. Results Oblique subduction in southern America initiated an arc-parallel fault and shear zones in the back of continental magmatic arc (Sillitoe, 2003. Because of this event, pull-apart basins were formed and high-K to shoshonitic calc-alkalineI- and A-type magmatism occur (Sillitoe, 2003. Most important deposits accompany with this magmatism are Au-Cu deposits types and Fe-Skarns (Sillitoe, 2003. We have

Reactive Coevaporation Synthesis and Characterization of SrTiO3 Thin Films

Science.gov (United States)

Yamaguchi, Hiromu; Matsubara, Shogo; Miyasaka, Yoichi

1991-09-01

SrTiO3 thin films were prepared by the reactive coevaporation method, where the Ti and Sr metals were evaporated in oxygen ambient with an E-gun and K-cell, respectively. A uniform depth profile in composition was achieved by altering the Ti evaporation rate according to the Sr evaporation rate change. A typical dielectric constant of 170 was measured on films of 75 nm in thickness. The in-situ annealing in oxygen plasma reduced the leakage current.

A feasibility study of U-Pb and Pb-Pb dating of kimberlites using groundmass mineral fractions and whole-rock samples

International Nuclear Information System (INIS)

Kramers, J.D.; Smith, C.B.

1983-01-01

This paper describes partly successful attempts to determine emplacement ages of kimberlites by U-Pb and Pb-Pb methods involving groundmass minerals with high U content (notably perovskite) and whole-rock kimberlite samples. U/Pb ratios in perovskite in the matrix of kimberlites can be two orders of magnitude larger than in the rest of the kimberlite material, and with simple mineral separation techniques moderate success was achieved in U-Pb dating of fresh samples of younger kimberlites (around 100 Ma). The differences in U/Pb ratios between kimberlite samples from different parts of the same pipe have also been found to be large enough, in some cases, to allow reasonably accurate U-Pb age determination. In older kimberlites the U-Pb ages obtained were mostly imcompatible with geological constraints and results obtained by other methods. However, for such pipes use of Pb-Pb systematics yields realistic age limits in some cases

Geochemistry and zircon U-Pb geochronology of the Pulang complex, Yunnan province, China

International Nuclear Information System (INIS)

Pang, Zhenshan; Du, Yangsong; Cao, Yi; Gao, Fuping; Wang, Gongwen; Dong, Qian

2014-01-01

The Pulang complex is located tectonically at the southern margin of the Yidun-Zhongdian island arc belt in Yunnan province, China, and is closely related to formation of the Pulang copper deposit, which is the largest copper deposit in Asia. The Pulang complex can be divided into three intrusion stages based on contact relationships and petrological characteristics: (1) a first stage of quartz dioritic porphyry; (2) a second stage of quartz monzonitic porphyry; and (3) a third stage of granodioritic porphyry. The crystallization ages of these intrusion stages were determined by single-zircon U-Pb dating, yielding ages of 221.0 ± 1.0, 211.8 ± 0.5, and 206.3 ± 0.7 Ma for the first, second, and third stages, respectively. These dates, integrated with previous geochronological data and field investigations, indicate that the second-stage quartz monzonitic porphyry has a close spatial and temporal relationship with the large Pulang porphyry copper deposit. These age data, geochemical and Sr-Nd isotopic results suggest that the Pulang complex formed in the Indo-Chinese epoch (257∼ 205 Ma) by multiphase intrusion of a mixture of mantle- and crust-derived magmas. (author)

In situ LA-ICPMS U–Pb dating of cassiterite without a known-age matrix-matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary

Science.gov (United States)

Neymark, Leonid; Holm-Denoma, Christopher S.; Moscati, Richard J.

2018-01-01

Cassiterite (SnO2), a main ore mineral in tin deposits, is suitable for U–Pb isotopic dating because of its relatively high U/Pb ratios and typically low common Pb. We report a LA-ICPMS analytical procedure for U–Pb dating of this mineral with no need for an independently dated matrix-matched cassiterite standard. LA-ICPMS U-Th-Pb data were acquired while using NIST 612 glass as a primary non-matrix-matched standard. Raw data are reduced using a combination of Iolite™ and other off-line data reduction methods. Cassiterite is extremely difficult to digest, so traditional approaches in LA-ICPMS U-Pb geochronology that utilize well-characterized matrix-matched reference materials (e.g., age values determined by ID-TIMS) cannot be easily implemented. We propose a new approach for in situ LA-ICPMS dating of cassiterite, which benefits from the unique chemistry of cassiterite with extremely low Th concentrations (Th/U ratio of 10−4 or lower) in some cassiterite samples. Accordingly, it is assumed that 208Pb measured in cassiterite is mostly of non-radiogenic origin—it was initially incorporated in cassiterite during mineral formation, and can be used as a proxy for common Pb. Using 208Pb as a common Pb proxy instead of 204Pb is preferred as 204Pb is much less abundant and is also compromised by 204Hg interference during the LA-ICPMS analyses.Our procedure relies on 208Pb/206Pb vs 207Pb/206Pb (Pb-Pb) and Tera-Wasserburg 207Pb/206Pb vs 238U/206Pb (U-Pb) isochron dates that are calculated for a ~1.54 Ga low-Th cassiterite reference material with varying amounts of common Pb that we assume remained a closed U-Pb system. The difference between the NIST 612 glass normalized biased U-Pb date and the Pb-Pb age of the reference material is used to calculate a correction factor (F) for instrumental U-Pb fractionation. The correction factor (F) is then applied to measured U/Pb ratios and Tera-Wasserburg isochron dates are obtained for the unknown

Geochronology and Genesis of the Xitian W-Sn Polymetallic Deposit in Eastern Hunan Province, South China: Evidence from Zircon U-Pb and Muscovite Ar-Ar Dating, Petrochemistry, and Wolframite Sr-Nd-Pb Isotopes

Directory of Open Access Journals (Sweden)

Jingya Cao

2018-03-01

Full Text Available The recently explored Xitian tungsten-tin (W-Sn polymetallic ore field, located in Hunan province, South China, is one of the largest ore fields in the Nanling Range (NLR. Two major metallogenic types appeared in this ore field, skarn- and quartz vein-type. They are distributed within Longshang, Heshuxia, Shaiheling, Hejiangkou, Goudalan, and so on. Hydrothermal zircons from two altered granites yielded U-Pb ages of 152.8 ± 1.1 Ma, and 226.0 ± 2.8 Ma, respectively. Two muscovite samples from ore-bearing quartz vein yielded 40Ar/39Ar plateau ages of 156.6 ± 0.7 Ma, 149.5 ± 0.8 Ma, respectively. Combined with the geological evidence, two metallogenic events are proposed in the Xitian ore field, with skarn-type W-Sn mineralization in Late Triassic (Indosinian and quartz vein/greisen type W-Sn mineralization in Late Jurassic (Yanshanian. The relatively low Ce/Ce* ratios and high Y/Ho ratios in zircons from two altered granites indicate that the hydrothermal fluids of two metallogenic events are characterized by low oxygen fugacities and enrichment in F. The similar chondrite-normalized patterns between the skarn and Xitian Indosinian granites and Sr-Nd-Pb isotopic compositions of wolframite suggest that the metal sources for both types W-Sn mineralization are derived from a crustal source.

In situ photoelectron spectroscopy of LaMnO3 and La0.6Sr0.4MnO3 thin films grown by laser molecular beam expitaxy

International Nuclear Information System (INIS)

Oshima, M.; Kobayashi, D.; Horiba, K.; Ohguchi, H.; Kumigashira, H.; Ono, K.; Nakagawa, N.; Lippmaa, M.; Kawasaki, M.; Koinuma, H.

2004-01-01

We have constructed a high-resolution photoelectron spectroscopy system combined with a laser molecular beam epitaxy (laser-MBE) chamber and have characterized composition-controlled La 1-x Sr x MnO 3 (LSMO) thin films. The importance of atomically flat surfaces by in situ photoelectron spectroscopy for revealing the intrinsic electronic structures has been demonstrated by comparing O1s, O2s and valence band spectra from the laser-MBE-grown LaMnO 3 and LSMO films with those from the scraped samples. Even for the laser-MBE-grown LSMO films, core levels and band structure exhibit strong dependence on surface morphology. For atomically flat LSMO films, we have also elucidated the hole-doping features into Mn3d e g band by substituting La with Sr by resonant photoelectron spectra

Evolution of the European region

International Nuclear Information System (INIS)

Jeger, Eh.

1984-01-01

The problem on geochronological study of the European region is covered. The most ancient age values are determined by U-Pb methods by zircones from paragneisses. The model of evolution, being in agreement with the data obtained by U-Pb and Rb-Sr methods, is considered. The history of the Schwarzwald development is typical for the continent as a whole. The diagram of evolution of primary 87 Sr/ 86 Sr for orthogneisses and granites in France is given

Combined U-Pb and Lu-Hf isotope analyses by laser ablation MC-ICP-MS: methodology and applications

Energy Technology Data Exchange (ETDEWEB)

Matteini, Massimo; Dantas, Elton L.; Pimentel, Marcio M.; Bühn, Bernhard, E-mail: massimo@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Instituto de Geociencias

2010-06-15

The Lutetium-Hafnium isotopic system represents one of the most innovative and powerful tools for geochronology and isotopic studies. Combined U-Pb and Lu-Hf in situ analyses on zircon by LA-MC-ICP-MS permit to characterize isotopically the host magma from which it crystallized furnishing significant information for sediment provenance and crustal evolution studies. In this paper e describe the Lu-Hf systematic by LA-MC-ICP-MS developed in the laboratory of Geochronology of the University of Brasilia and report the results obtained by repeated analyses of {sup 176}Hf/{sup 177}Hf isotopic ratio of three zircon standards: GJ-1 = 0.282022 ± 11 (n=56), Temora 2 = 0.282693 ± 14 (n=25) and UQZ = 0.282127 ± 33 (n=11). The {sup 176}Hf/{sup 177}Hf ratio (0.282352 ± 22, n=14) of gem quality zircon used as in-house standard have been also characterized. As a geological application, we analyzed two complex zircons selected from a migmatitic rocks from the Borborema Province, NE Brazil. On the basis of U-Pb and Lu-Hf data, two main crystallization events have been identified in both studied zircons. An older event at ca. 2.05 Ga recognized in the inherited cores represents a well-characterized paleoproterozoic magmatic event that affected the whole Borborema Province. A second crystallization event at ∼ 575 Ma, recognized at the rims, represents a Neoproterozoic (Brazilian) high grade metamorphic-magmatic event. (author)

Petrogenesis of the Yaochong granite and Mo deposit, Western Dabie orogen, eastern-central China: Constraints from zircon U-Pb and molybdenite Re-Os ages, whole-rock geochemistry and Sr-Nd-Pb-Hf isotopes

Science.gov (United States)

Chen, Wei; Xu, Zhaowen; Qiu, Wenhong; Li, Chao; Yu, Yang; Wang, Hao; Su, Yang

2015-05-01

The Dabie orogen is among the most famous continent-continent collisional orogenic belts in the world, and is characterized by intensive post-collisional extension, magmatism and Mo mineralization. However, the genetic links between the mineralization and the geodynamic evolution of the orogen remain unresolved. In this paper, the Yaochong Mo deposit and its associated granitic stocks were investigated to elucidate this issue. Our new zircon U-Pb ages yielded an Early Cretaceous age (133.3 ± 1.3 Ma) for the Yaochong granite, and our molybdenite Re-Os dating gave a similar age (135 ± 1 Ma) for the Mo deposit. The Yaochong stock is characterized by high silica and alkali but low Mg, Fe and Ca. It is enriched in light rare earth elements (LREEs) and large ion lithophile elements (LILEs: Rb, K, Th and U), but strongly depleted in heavy REEs, and high field strength elements (HFSEs: Nb, Ta, Ti and Y). The Yaochong granite has initial 87Sr/86Sr ratios of 0.7087-0.7096, and Pb isotopic ratios of (206Pb/204Pb)i = 16.599-16.704, (207Pb/204Pb)i = 15.170-15.618 and (208Pb/204Pb)i = 36.376-38.248. The granite has εNd(t) of -18.0 to -16.3 and εHf(t) values of -26.5 to -20.0. All these data indicate that the Yaochong granite is a high-K calc-alkaline fractionated I-type granite, and may have originated from partial melting of the thickened Yangtze continental crust. The Mo ores also show low radiogenic Pb isotopes similar to the Yaochong stock. Medium Re content in molybdenite (21.8-74.8 ppm) also suggests that the ore-forming materials were derived from the thickened lower crust with possibly minor mixing with the mantle. Similar to the Eastern Dabie orogen, the thickened crust beneath the Western Dabie orogen may also have experienced tectonic collapse, which may have exerted fundamental geodynamic controls on the two-stage Mo mineralization in the region.

Nd isotopes, U-Pb single grain and SHRIMP zircon ages from basement rocks of the Tocantin Province

International Nuclear Information System (INIS)

Fuck, R.A.; Dantas, E.L.; Pimentel, M.M.; Junges, S.L.; Moraes, R

2001-01-01

Large areas of the northern part of the Brasilia Belt, Tocantins Province, central Brazil, are underlain by basement granite-gneiss terrain and associated volcano-sedimentary sequences, as well as felsic and mafic-ultramafic intrusions. The basement rocks are covered by the late Paleoproterozoic-Mesoproterozoic rift-related Arai and Natividade groups and intruded by 1.77 to 1.58 Ga an orogenic granites of the Goias Tin Province (Pimentel and Botelho, 2001). To the southwest they are un conformably overlain by the low-grade late Proterozoic Paranoa Group, whereas to the east they are in faulted contact with the Neoproterozoic Bambui Group at the western edge of the Sao Francisco Craton. To the north they are covered by Phanerozoic sediments of the Parnaiba and Sanfranciscana basins. Despite their large extension, granite-gneiss and associated supracrustals of SE Tocantins and NE Goias are still poorly known. Previous regional Rb-Sr and K-Ar isotopic studies indicated dominant early Proterozoic ages and late Proterozoic cooling ages (Hasui, et al. 1980, Fernandes et al. 1982). More detailed studies in the Almas-Dianopolis area (Costa, 1984) came up with similar results, although the region was interpreted as underlain by Archean granite-greenstone terrain, following previous suggestions by Costa et al. (1976). Recent work recognized the presence of two suites of deformed granitoids (Cruz and Kuyumjian, 1996, 1998). The oldest suite intruded the supracrustals and comprises hornblende-bearing tonalite gneiss, with minor trondhjemite, granodiorite, and quartz diorite. The younger suite comprises oval shaped biotite-bearing tonalite, trondhjemite, and granodiorite intrusions. Both suites display low-K calc-alkaline affinity, the younger being more Al-rich. Both are interpreted as TTG suites and were dated at 2,2 Ga using U-Pb SHRIMP (Cruz et al 2000). In the Porto Nacional area, Gorayeb et al. (2000) determined single zircon Pb-evaporation ages of 2.15 Ga in granulites

Gibbs free energy of formation of UPb(s) compound

International Nuclear Information System (INIS)

Samui, Pradeep; Agarwal, Renu; Mishra, Ratikanta

2012-01-01

Liquid lead and lead-bismuth eutectic (LBE) are being explored as primary candidates for coolants in accelerator driven systems and in advanced nuclear reactors due to their favorable thermo-physical and chemical properties. They are also proposed to be used as spallation neutron source in ADS Reactor Systems. However, corrosion of structural materials (i.e. steel) presents a critical challenge for the use of liquid lead or LBE in advanced nuclear reactors. The interactions of liquid lead or LBE with clad and fuel is of great scientific and technological importance in the development of advanced nuclear reactors. Clad failure/breach can lead to reaction of coolant elements with fuel components. Thus the study of fuel-coolant interaction of U with Pb/Bi is important. The paper deals with the determination of Gibbs free energy of formation of U-rich phase i.e. UPb in Pb-U system, employing Knudsen effusion mass loss technique

Dating the Martian meteorite Zagami by the ⁸⁷Rb-⁸⁷Sr isochron method with a prototype in situ resonance ionization mass spectrometer.

Science.gov (United States)

Anderson, F Scott; Levine, Jonathan; Whitaker, Tom J

2015-01-30

The geologic history of the Solar System builds on an extensive record of impact flux models, crater counts, and ~270 kg of lunar samples analyzed in terrestrial laboratories. However, estimates of impactor flux may be biased by the fact that most of the dated Apollo samples were only tenuously connected to an assumed geologic context. Moreover, uncertainties in the modeled cratering rates are significant enough to lead to estimated errors for dates on Mars and the Moon of ~1 Ga. Given the great cost of sample return missions, combined with the need to sample multiple terrains on multiple planets, we have developed a prototype instrument that can be used for in situ dating to better constrain the age of planetary samples. We demonstrate the first use of laser ablation resonance ionization mass spectrometry for (87)Rb-(87)Sr isochron dating of geological specimens. The demands of accuracy and precision have required us to meet challenges including regulation of the ambient temperature, measurement of appropriate backgrounds, sufficient ablation laser intensity, avoidance of the defocusing effect of the plasma created by ablation pulses, and shielding of our detector from atoms and ions of other elements. To test whether we could meaningfully date planetary materials, we have analyzed a piece of the Martian meteorite Zagami. In each of four separate measurements we obtained (87)Rb-(87)Sr isochron ages for Zagami consistent with its published age, and, in both of two measurements that reached completion, we obtained better than 200 Ma precision. Combining all our data into a single isochron with 581 spot analyses gives an (87)Rb-(87)Sr age for this specimen of 360 ±90 Ma. Our analyses of the Zagami meteorite represent the first successful application of resonance ionization mass spectrometry to isochron geochronology. Furthermore, the technique is miniaturizable for spaceflight and in situ dating on other planetary bodies. © 2014 The Authors. Rapid Communications in

Thermal infrared and microwave absorbing properties of SrTiO3/SrFe12O19/polyaniline nanocomposites

International Nuclear Information System (INIS)

Hosseini, Seyed Hossein; Zamani, Parisa; Mousavi, S.Y.

2015-01-01

Graphical abstract: We have developed a new perspective of applications and properties of conducting polymers. The combination of absorption ability prepared nanocomposites in the present of PANI display a great potential in organization of shielding structures into thermal IR and microwave. Further investigations using other conducting polymers to demonstrate their capability for advance thermal IR and microwave shielding devices is under way. The application of these samples may improve the IR thermographic detection, catalysis, sensors, magnetic data storage, electromagnetic resonance wave absorption, photonic crystals, and microelectronic devices and military aspects. - Highlights: • The SrTiO 3 /SrFe 12 O 19 /PANI exhibited electric and electromagnetic properties. • The SrTiO 3 /SrFe 12 O 19 /PANI has shielding structures into thermal IR and microwave. • Increasing weight ratios and thicknesses will increase thermal IR ability. • Increasing weight ratios and thicknesses will increase microwave absorption ability. - Abstract: Polyaniline (PANI) as a unique polymer that also has electromagnetic absorption used as the substrate. In this research, SrTiO 3 was synthesized as IR absorbent and core and then SrFe 12 O 19 as microwave absorbent was prepared on SrTiO 3 via co-precipitation method as the first shell. As the next step, PANI was coated on SrTiO 3 /SrFe 12 O 19 nanoparticles via in situ polymerization by multi core–shell structures (SrTiO 3 /SrFe 12 O 19 /PANI). Nanometer size and structures of samples were measured by TEM, XRD and FTIR. Morphology of nanocomposite was showed by SEM images. The magnetic and electric properties were also performed by VSM and four probe techniques. Thermal infrared (IR) absorption and microwave reflection loss of nanocomposites were investigated at 10–40 μm and 8–12 GHz, IR and microwave frequencies, respectively. The results showed that the SrTiO 3 /SrFe 12 O 19 /PANI nanocomposites have good compatible

Evaluation of the effect of Bi, Sb, Sr and cooling condition on eutectic phases in an Al–Si–Cu alloy (ADC12) by in situ thermal analysis

International Nuclear Information System (INIS)

Farahany, S.; Ourdjini, A.; Idrsi, M.H.; Shabestari, S.G.

2013-01-01

Highlights: • Combined effect of Bi, Sb and Sr additions, and cooling condition was evaluated. • Two different scenarios of recalecense in response to cooling rate were observed. • Fraction solid increased in the order of Sr > Bi > Sb, corresponds to Si morphologies. • Only Bi decreased the nucleation temperature of Al 2 Cu eutectic phase. - Abstract: Al–Si and Al–Cu eutectic phases strongly affect the properties of Al–Si–Cu cast alloys. The characteristic parameters of these two eutectic phases with addition of bismuth, antimony and strontium under different cooling rates (0.6–2 °C/s) were investigated in ADC12 alloy using in situ thermal analysis. Results show that additives affect the Al–Si phase more than the Al–Cu (Al 2 Cu) phase. Addition elements showed two different scenarios in response to cooling rate in terms of recalescence of the Al–Si eutectic phase. Both Bi and Sb caused an increase in recalescence with increased cooling rate but Sr addition reduced the recalescence. Additions of Sb and Sr increased the nucleation temperature of Al 2 Cu, but addition of Bi produced an opposite effect. There seems to be relationship between the solidification temperature range and fraction solid of Al–Si and Al 2 Cu eutectic phases. As the cooling rate increases the fraction solid of Al–Si decreased and that of Al 2 Cu increased

U-Pb ages related to uranium mineralization of Lagoa Real, Bahia - Brazil: tectonic implications

Energy Technology Data Exchange (ETDEWEB)

Chaves, Alexandre O.; Rios, Francisco J.; Oliveira, Lucilia A.R.; Alves, James V.; Fuzikawa, Kazuo; Neves, Jose M.C.; Chaves, Adriana M.D.V.; Prates, Sonia P. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)]. E-mail: aoc@cdtn.br; Tubrett, Michael [Memorial University of Newfoundland, NL (Canada). Inco Innovation Centre. MicroAnalysis Facility; Matos, Evando C. [Industrias Nucleares do Brasil S.A. (INB), Rio de Janeiro, RJ (Brazil)

2007-07-01

The uranium from Lagoa Real (Bahia/Brazil) is associated with syenitic magmatism (1904 {+-}44 Ma minimum age from upper intercept of zircon U-Pb discordia by LA-ICP-MS) belonging to a mafic/ felsic lithologic association linked to the final stages of 2.05-1.80 Ga Orosirian Orogeny, which acted in the Paramirim Block. These syenitic rocks are rich not only in albite, but also in U-rich titanite (source of uranium). In association with the development of the Orosirian ductile shear zones, the syenites were crystallized and deformed. The metamorphic reactions, which include intense recrystallization of magmatic minerals, led uraninite to precipitate (1868 {+-} 69 Ma; U-Pb by LA-ICP MS) under Redox control. A second population of uraninites was also generated by shear zones reactivation during 0.6-0.5 Ga Brasiliano Orogeny (605 {+-} 170 Ma; U-Pb by LA-ICP-MS). The geotectonic implications are: a) the importance of the Orosirian event in the Paramirim Block during paleoproterozoic Sao Francisco/Congo Craton edification and b) the influence of the Brasiliano event in the Paramirim Block during the West-Gondwana assembly processes, indicated by the 605 {+-} 170 Ma uraninite (second population) age and by the 483 {+-} 100 Ma lower intercept of the metamorphosed syenite U-Pb discordia. (author)

Nd-Sr isotopic geochemistry and U-Pb geochronology of the Fe granitic gneiss and Lajedo Granodiorite: implications for paleoproterozoic evolution of the Mineiro Belt, southern Sao Francisco craton, Brazil

Energy Technology Data Exchange (ETDEWEB)

Teixeira, Wilson [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas]. E-mail: wteixeir@usp.br; Avila, Ciro Alexandre [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Museu Nacional. Dept. de Geologia e Paleontologia]. E-mail: avila@mn.ufrj.br; Nunes, Luciana Cabral [Universidade de Sao Paulo (USP), SP (Brazil). Inst. de Geociencias]. E-mail: luciana@igc.usp.br

2008-07-01

The Fe granitic gneiss and Lajedo granodiorite belong to a voluminous felsic-mafic plutonism, tectonically linked to Paleoproterozoic magmatic evolution of the Mineiro Belt, southern portion of the Sao Francisco Craton, central-eastern Brazil. The Fe pluton is located north of the Lenheiros shear zone and is intrusive with respect to the Rio das Mortes greenstone belt and pyroxenite - gabbroic bodies, as indicated by xenoliths of gneiss and amphibolite, in the first case, and pyroxenite in the latter. The Lajedo granodiorite is located south of the Lenheiros shear zone and cuts the metamafic rocks of the Forro peridotite - pyroxenite and mafic and intermediate rocks of the Nazareno greenstone belt, as evidenced by xenoliths from the latter unit. The modal composition of the Fe granitic gneiss lies within the ranges of monzogranite and syenogranite. It is peraluminous and shows a large variation in K{sub 2}O content, which implies a middle-K calc-alkaline to high-K calc-alkaline tendency. The Lajedo modal composition is consistent with granodioritic and tonalitic compositions. It indicates a predominantly peraluminous composition and calc-alkaline character. The U-Pb zircon crystallization age of the Fe granitic gneiss is 2191 {+-} 9 Ma, whereas the Lajedo granodiorite yields 2208 {+-} 26 Ma. The Nd/Sr characteristics of the Fe and Lajedo plutons are consistent with mixtures of enriched mantle (EMI-type), DMM and crustal components during magma genesis in a plutonic arc setting, while the low {sup 87}Sr/{sup 86}Sri ratios point to contribution of mafic rock protoliths during magma genesis. This is also in accordance with the characteristic xenoliths observed within the investigated plutons from the Nazareno and Rio das Mortes greenstone belts. The Fe granitic gneiss and Lajedo granodiorite show tectonic characteristics which are comparable to those of nearby coeval plutons: Brito quartz-diorite (2221 +- 2 Ma), Brumado de Cima granodiorite (2219 {+-} 2 Ma), Brumado

Nd-Sr isotopic geochemistry and U-Pb geochronology of the Fe granitic gneiss and Lajedo Granodiorite: implications for paleoproterozoic evolution of the Mineiro Belt, southern Sao Francisco craton, Brazil

International Nuclear Information System (INIS)

Teixeira, Wilson; Avila, Ciro Alexandre; Nunes, Luciana Cabral

2008-01-01

The Fe granitic gneiss and Lajedo granodiorite belong to a voluminous felsic-mafic plutonism, tectonically linked to Paleoproterozoic magmatic evolution of the Mineiro Belt, southern portion of the Sao Francisco Craton, central-eastern Brazil. The Fe pluton is located north of the Lenheiros shear zone and is intrusive with respect to the Rio das Mortes greenstone belt and pyroxenite - gabbroic bodies, as indicated by xenoliths of gneiss and amphibolite, in the first case, and pyroxenite in the latter. The Lajedo granodiorite is located south of the Lenheiros shear zone and cuts the metamafic rocks of the Forro peridotite - pyroxenite and mafic and intermediate rocks of the Nazareno greenstone belt, as evidenced by xenoliths from the latter unit. The modal composition of the Fe granitic gneiss lies within the ranges of monzogranite and syenogranite. It is peraluminous and shows a large variation in K 2 O content, which implies a middle-K calc-alkaline to high-K calc-alkaline tendency. The Lajedo modal composition is consistent with granodioritic and tonalitic compositions. It indicates a predominantly peraluminous composition and calc-alkaline character. The U-Pb zircon crystallization age of the Fe granitic gneiss is 2191 ± 9 Ma, whereas the Lajedo granodiorite yields 2208 ± 26 Ma. The Nd/Sr characteristics of the Fe and Lajedo plutons are consistent with mixtures of enriched mantle (EMI-type), DMM and crustal components during magma genesis in a plutonic arc setting, while the low 87 Sr/ 86 Sri ratios point to contribution of mafic rock protoliths during magma genesis. This is also in accordance with the characteristic xenoliths observed within the investigated plutons from the Nazareno and Rio das Mortes greenstone belts. The Fe granitic gneiss and Lajedo granodiorite show tectonic characteristics which are comparable to those of nearby coeval plutons: Brito quartz-diorite (2221 +- 2 Ma), Brumado de Cima granodiorite (2219 ± 2 Ma), Brumado de Baixo

Whole-rock U-Pb dating of the Shuijingtuo formation sedimentary rocks in the Yangtze Gorge

International Nuclear Information System (INIS)

Zheng, Y.F.; Huang, B.

1990-01-01

Black shale and enclosed limestone lenticule from Lower Cambrian Shuijingtuo Formation in the Yangtze Gorge is successfully dated by whole-rock U-Pb method. The results yield a concordant age of about 573±14 Ma, in excellent agreement with both stratigraphic and palaeontologic evidence. The whole-rock U-Pb method can provide a reliable approach for age determination of sedimentary stratum. (orig.) [de

Constraining the relationships between anaerobic oxidation of methane and sulfate reduction under in situ methane concentrations

Science.gov (United States)

Zhuang, G.; Wegener, G.; Joye, S. B.

2017-12-01

The anaerobic oxidation of methane (AOM) is an important microbial metabolism in the global carbon cycle. In marine methane seeps sediment, this process is mediated by syntrophic consortium that includes anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Stoichiometrically in AOM methane oxidation should be coupled to sulfate reduction (SR) in a 1:1 ratio. However, weak coupling of AOM and SR in seep sediments was frequently observed from the ex situ rate measurements, and the metabolic dynamics of AOM and SR under in situ conditions remain poorly understood. Here we investigated the metabolic activity of AOM and SR with radiotracers by restoring in situ methane concentrations under pressure to constrain the in situ relationships between AOM and SR in the cold seep sediments of Gulf of Mexico as well as the sediment-free AOM enrichments cultivated from cold seep of Italian Island Elba or hydrothermal vent of Guaymas Basin5. Surprisingly, we found that AOM rates strongly exceeded those of SR when high pressures and methane concentrations were applied at seep sites of GC600 and GC767 in Gulf of Mexico. With the addition of molybdate, SR was inhibited but AOM was not affected, suggesting the potential coupling of AOM with other terminal processes. Amendments of nitrate, iron, manganese and AQDS to the SR-inhibited slurries did not stimulate or inhibit the AOM activity, indicating either those electron acceptors were not limiting for AOM in the sediments or AOM was coupled to other process (e.g., organic matter). In the ANME enrichments, higher AOM rates were also observed with the addition of high concentrations of methane (10mM and 50 mM). The tracer transfer of CO2 to methane, i.e., the back reaction of AOM, increased with increasing methane concentrations and accounted for 1%-5% of the AOM rates. AOM rates at 10 mM and 50 mM methane concentration were much higher than the SR rates, suggesting those two processes were not tightly coupled

Relict zircon U-Pb age and O isotope evidence for reworking of Neoproterozoic crustal rocks in the origin of Triassic S-type granites in South China

Science.gov (United States)

Gao, Peng; Zheng, Yong-Fei; Chen, Yi-Xiang; Zhao, Zi-Fu; Xia, Xiao-Ping

2018-02-01

Granites derived from partial melting of sedimentary rocks are generally characterized by high δ18O values and abundant relict zircons. Such relict zircons are valuable in tracing the source rocks of granites and the history of crustal anatexis. Here we report in-situ U-Pb ages, O isotopes and trace elements in zircons from Triassic granites in the Zhuguangshan and Jiuzhou regions, which are located in the Nanling Range and the Darongshan area, respectively, in South China. Zircon U-Pb dating yields magma crystallization ages of 236 ± 2 Ma for the Zhuguangshan granites and 246 ± 2 Ma to 252 ± 3 Ma for the Jiuzhou granites. The Triassic syn-magmatic zircons are characterized by high δ18O values of 10.1-11.9‰ in Zhuguangshan and 8.5-13.5‰ in Jiuzhou. The relict zircons show a wide range of U-Pb ages from 315 to 2185 Ma in Zhuguangshan and from 304 to 3121 Ma in Jiuzhou. Nevertheless, a dominant age peak of 700-1000 Ma is prominent in both occurrences, demonstrating that their source rocks were dominated by detrital sediments weathered from Neoproterozoic magmatic rocks. Taking previous results for regional granites together, Neoproterozoic relict zircons show δ18O values in a small range from 5 to 8‰ for the Nanling granites but a large range from 5 to 11‰ for the Darongshan granites. In addition, relict zircons of Paleozoic U-Pb age occur in the two granitic plutons. They exhibit consistently high δ18O values similar to the Triassic syn-magmatic zircons in the host granites. These Paleozoic relict zircons are interpreted as the peritectic product during transient melting of the metasedimentary rocks in response to the intracontinental orogenesis in South China. Therefore, the relict zircons of Neoproterozoic age are directly inherited from the source rocks of S-type granites, and those of Paleozoic age record the transient melting of metasedimentary rocks before intensive melting for granitic magmatism in the Triassic.

Preliminary results of U/Pb geochronology in Meridional Espinhaco Mountain

International Nuclear Information System (INIS)

Machado, N.; Schrank, A.; Abreu, F.R. de; Knauer, L.G.; Abreu, P.A.A.

1989-01-01

Some samples of the constituent unities from Meridional Espinhaco Mountain for geochronology determining by U/Pb method are presented. The analytical techniques described by Krogh and the Davis linear regression program are used for treating these samples. (author)

Evaluation of the effect of Bi, Sb, Sr and cooling condition on eutectic phases in an Al–Si–Cu alloy (ADC12) by in situ thermal analysis

Energy Technology Data Exchange (ETDEWEB)

Farahany, S., E-mail: saeedfarahany@gmail.com [Department of Materials Engineering, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia (UTM), 81310 Johor Bahru (Malaysia); Ourdjini, A.; Idrsi, M.H. [Department of Materials Engineering, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia (UTM), 81310 Johor Bahru (Malaysia); Shabestari, S.G. [Center of Excellence for High Strength Alloys Technology (CEHSAT), School of Metallurgy and Materials Engineering, Iran University of Science and Technology (IUST), 16846-13114 Tehran (Iran, Islamic Republic of)

2013-05-10

Highlights: • Combined effect of Bi, Sb and Sr additions, and cooling condition was evaluated. • Two different scenarios of recalecense in response to cooling rate were observed. • Fraction solid increased in the order of Sr > Bi > Sb, corresponds to Si morphologies. • Only Bi decreased the nucleation temperature of Al{sub 2}Cu eutectic phase. - Abstract: Al–Si and Al–Cu eutectic phases strongly affect the properties of Al–Si–Cu cast alloys. The characteristic parameters of these two eutectic phases with addition of bismuth, antimony and strontium under different cooling rates (0.6–2 °C/s) were investigated in ADC12 alloy using in situ thermal analysis. Results show that additives affect the Al–Si phase more than the Al–Cu (Al{sub 2}Cu) phase. Addition elements showed two different scenarios in response to cooling rate in terms of recalescence of the Al–Si eutectic phase. Both Bi and Sb caused an increase in recalescence with increased cooling rate but Sr addition reduced the recalescence. Additions of Sb and Sr increased the nucleation temperature of Al{sub 2}Cu, but addition of Bi produced an opposite effect. There seems to be relationship between the solidification temperature range and fraction solid of Al–Si and Al{sub 2}Cu eutectic phases. As the cooling rate increases the fraction solid of Al–Si decreased and that of Al{sub 2}Cu increased.

Reactivity, structure and physical properties of SrCo{sub 2.5+{delta}} and La{sub 2}CoO{sub 4.0+{delta}}. In situ X-ray diffraction and neutrons study; Reactivite, structure et proprietes physiques de SrCoO{sub 2.5+{delta}} et La{sub 2}CoO{sub 4.0+{delta}}. Etude par diffraction des rayons X et des neutrons in situ

Energy Technology Data Exchange (ETDEWEB)

Le Toquin, R.

2003-11-15

This work was devoted to the study of the reactivity and more specifically the influence of the intercalated oxygen amount {delta} on the structure and physical properties of SrCoO{sub 2.5+{delta}} et La{sub 2}CoO{sub 4.0+{delta}} We controlled the oxidation level by means of reversible electrochemical red ox reaction at room temperature. Structural modifications, especially disorder, and electronic properties were studied for the first time on large orientated single crystal. In the SrCoO{sub 2.5+{delta}} system, after structural and electronic characterisation of the end phases, we studied the real structure of the brownmillerite SrCoO{sub 2.5} phase using single crystal. Moreover, we investigated structural and magnetic evolution upon red ox cycle using X-ray diffraction on 6 times twinned single crystal and in situ neutron powder diffraction. Two intermediate SrCoO{sub 2.75} and SrCoO{sub 2.82} phases have been observed. The reaction on single crystal has evidenced the evolution of domain structure. For the La{sub 2}CoO{sub 4+{delta}} system, we synthesised a large variety of single crystal with stoichiometry {delta} 0.0, 0.09, 0.12, 0.16, 0.20 and 0.25. Using single crystal X-ray and neutron diffraction, we showed a disorder-order transition of the apical and interstitial oxygen for the higher {delta} values. (author)

U-Pb studies of the Appley Bridge meteorite

International Nuclear Information System (INIS)

Gale, N.H.; Arden, J.W.; Hutchinson, R.

1979-01-01

The U and Pb concentration in samples from the interior of the 10.9 kg stone BM 1920, 40 (British Museum), the isotopic composition of lead, a lead-lead diagram for whole meteorite samples of Appley Bridge, and a U-Pb concordia diagram for whole meteorite samples of Appley Bridge from different measurements are treated. (HK) 891 HK/HK 892 MB [de

Epitaxial properties of ZnO thin films on SrTiO3 substrates grown by laser molecular beam epitaxy

International Nuclear Information System (INIS)

Wei, X. H.; Li, Y. R.; Zhu, J.; Huang, W.; Zhang, Y.; Luo, W. B.; Ji, H.

2007-01-01

Epitaxial ZnO thin films with different orientations have been grown by laser molecular beam epitaxy on (001)- (011)-, and (111)-orientated SrTiO 3 single-crystal substrates. The growth behavior was in situ monitored by reflection high-energy electron diffraction, and the epitaxial orientation relations were reconfirmed by ex situ x-ray diffraction measurements. In the case of ZnO on SrTiO 3 (001), four orthogonal domains coexisted in the ZnO epilayer, i.e., ZnO(110) parallel SrTiO 3 (001) and ZnO[-111] parallel SrTiO 3 . For (011)- and (111)-orientated substrates, single-domain epitaxy with c axial orientation was observed, in which the in-plane relationship was ZnO[110] parallel SrTiO 3 [110] irrespective of the substrate orientations. Additionally, the crystalline quality of ZnO on SrTiO 3 (111) was better than that of ZnO on SrTiO 3 (011) because of the same symmetry between the (111) substrates and (001) films. The obtained results can be attributed to the difference of the in-plane crystallographic symmetry. Furthermore, those alignments can be explained by the interface stress between the substrates and the films

Molybdenum mineralization at Alpeiner Scharte, Tyrol (Austria): results of in-situ U-Pb zircon and Re-Os molybdenite dating

International Nuclear Information System (INIS)

Langthaler, K.J.; Raith, J.G.; Cornell, D.H.; Stein, H.J.; Melcher, F.

2004-01-01

Vein-type Mo mineralization at Alpeiner Scharte occurs in the Penninic units of the western Tauern Window in the Eastern Alps. Three types of previously undated metagranitoids (central gneisses) are distinguished and preserve intrusive contacts with pre-Alpine metamorphosed supracrustal rocks. The granitic protoliths represent fractionated late to post-orogenic, calc-alkaline, I-type magmas with minor S-type components. The Mo veins are restricted to a biotite and alkali feldspar-rich gneiss variety and occur in E-W trending normally sub-vertical quartz veins with adjacent thin discontinuous garnet- and biotite-rich zones; the latter are interpreted as metamorphosed vein selvages. Prior to this work the age of the intrusive host rocks as well as the age of Mo mineralization were unknown. The pre-Alpine Mo deposit and its host rocks were affected by four Alpine deformation events (D 1 -D 4 ) and Young-Alpine regional metamorphism. The P-T conditions of this metamorphic event were ∼ 550 o C and ∼ 8 kbar and are in agreement with results of previous regional studies. Zircon grains from two orthogneiss samples were dated with the U-Pb method using ion probe techniques. Zircons from the metagranitic host rock of the Mo-veins yielded an emplacement age of 306.8 ± 3.8 Ma (2σ). A second sample from a more leucocratic gneiss lacking Mo-veins gave 305.0 ± 6.6 Ma (2 σ). Re-Os dating of molybdenite from the veins yielded an age of 306.8 ± 3.1 Ma in good agreement with the U-Pb zircon ages. This study confirms one of two alternative hypotheses discussed in the literature. lt supports the idea that vein-type Mo-mineralization in the western Tauern Window is genetically related to Late Carboniferous (Westphalian) granitoids that were emplaced during the late to post-orogenic stage of the Variscan orogeny. They do not constitute an Alpine metamorphic-hydrothermal deposit. This study further confirms the strength of the Re-Os molybdenite chronometer, in that it was

Geodynamics of rift-plume interaction in Iceland as constrained by new 40Ar/ 39Ar and in situ U-Pb zircon ages

Science.gov (United States)

Martin, E.; Paquette, J. L.; Bosse, V.; Ruffet, G.; Tiepolo, M.; Sigmarsson, O.

2011-11-01

The interaction between a rift zone and a mantle plume leads to exceptional situations in Iceland where the island is 1.5 wider than expected, given the North-Atlantic spreading rate. In order to give a better idea of the timeframe of this evolution, we present 32 new 40Ar/ 39Ar and in-situ U-Pb dating on zircon from 16 volcanic systems located from the west to east coasts of Iceland. The North Iceland Rift Zone (NIRZ) was initiated at least 12 Ma ago. Furthermore, during these last 12 Ma, the NIRZ half spreading rate was between 0.7 and 1.2 cm/yr and it propagated to the south at a rate of 1.0-1.2 cm/yr. The excess width of Iceland can thus not be explained by faster spreading rate in the past. Here we discuss a model that explains the ~ 200 km 'excess' of crust, taking into account the eastward relocation of the rift zone and corresponding older crustal capture over the course of Iceland's geological history. The most recent rift relocation is dated at approximately 6 Ma at Snæfellsnes Peninsula in the west, whereas the oldest volcanic systems (15-13 Ma) from the extreme north east of Iceland were most likely generated at the Kolbeinsey ridge north of Iceland rather than in the NIRZ itself. The need for rift relocations and crustal capture to explain the width of Iceland strongly suggests that during rift-plume interaction the mantle plume plays an active role. It forces the active rift zone to be frequently relocated by rift jumps above its center leaving inactive rift zones as older synclines in the geological record. This result in an eastward position of the rift zone in Iceland relative to the North Atlantic ridge, and it can be predicted that in a few tens of millions of years the Mid-Atlantic ridge and the Icelandic plume may become decoupled.

Direct formation of gasoline hydrocarbons from cellulose by hydrothermal conversion with in situ hydrogen

International Nuclear Information System (INIS)

Yin, Sudong; Mehrotra, Anil Kumar; Tan, Zhongchao

2012-01-01

A new process based on aqueous-phase dehydration/hydrogenation (APD/H) has been developed to directly produce liquid alkanes (C 7–9 ), which are the main components of fossil gasoline, from cellulose in one single batch reactor without the consumption of external hydrogen (H 2 ). In this new process, part of the cellulose is first converted to in situ H 2 by steam reforming (SR) in the steam gas phase mainly; and, in the liquid water phase, cellulose is converted to an alkane precursor, such as 5-(hydroxymethyl)furfural (HMF). In the final reaction step, in situ H 2 reacts with HMF to form liquid alkanes through APD/H. Accordingly, this new process has been named SR(H 2 )-APD/H. Experimental results show that the volumetric ratio of the reactor headspace to the reactor (H/R) and an initial weakly alkaline condition are the two key parameters for SR(H 2 )-APD/H. With proper H/R ratios (e.g., 0.84) and initial weakly alkaline conditions (e.g., pH = 7.5), liquid alkanes are directly formed from the SR(H 2 )-APD/H of cellulose using in situ H 2 instead of external H 2 . In this study, compared with pyrolysis and hydrothermal liquefaction of cellulose at the same temperatures with same retetion time, SR(H 2 )-APD/H greatly increased the liquid alkane yields, by approximately 700 times and 35 times, respectively. Based on this process, direct formation of fossil gasoline from renewable biomass resources without using external H 2 becomes possible. -- Highlights: ► A process of producing gasoline alkanes from cellulose was proposed and studied. ► Alkane precursors and in situ H 2 were formed simultaneously in a single reactor. ► Alkanes subsequently formed by reactions between in situ H 2 and alkane precursors. ► The yields were 700 and 35 times higher than pyrolysis and hydrothermal conversion.

Zircon growth in a granitic pluton with specific mechanisms, crystallization temperatures and U-Pb ages. Implication to the 'spatiotemporal' formation process of the Toki granite, central Japan

International Nuclear Information System (INIS)

Yuguchi, Takashi; Ishibashi, Masayuki; Sasao, Eiji; Iwano, Hideki; Danhara, Tohru; Kato, Takenori; Sakata, Shuhei; Hattori, Kentaro; Hirata, Takafumi; Sueoka, Shigeru; Nishiyama, Tadao

2016-01-01

Zircons collected from a granitic pluton provide evidence of serial growth events with specific mechanisms, crystallization temperatures and U-Pb ages, revealing details of the sequential formation process from intrusion through emplacement to crystallization/solidification. The events have been identified by: 1) the study of the internal structure of zircon using cathodoluminescence, 2) deriving crystallization temperatures using Ti-in-zircon thermometry of the internal structure and 3) U-Pb age dating of the internal structure. The magmatic zircons from the Toki granite, central Japan, show two kinds in their internal structure: a low luminescence core (LLC) and oscillatory zonation (OZ). The LLC was produced by interfacial reaction-controlled growth in the granitic magma with cooling from about 910 to 760°C. The formation of OZ occurred by diffusion-controlled growth in a cooling magma chamber from about 850 to 690°C. The U-Pb ages derived from the LLC ranges from 74.7 ± 4.2 to 70.5 ± 1.3 Ma, indicating the incipient intrusion timing of the magma into the shallow crust. The OZ ages distribute from 72.7 ± 0.6 to 70.4 ± 1.7 Ma, which mean the timing from emplacement to crystallization/solidification of the granite pluton. Thus, the serial processes from intrusion through emplacement to crystallization/solidification occurred within a few million years. The old LLC and OZ ages are recognized in the western margins of the Toki granite, implying that the magma forming the western margins was the first to intrude, emplace and crystallize/solidify. The western margins with initial intrusion may accompany the crustal assimilation in order to create sufficient magma reservoir space, which is consistent with larger SrI and ASI values found in the western margins of the granite. (author)

Zircon U-Pb dating of Maherabad porphyry copper-gold prospect area: evidence for a late Eocene porphyry-related metallogenic epoch in east of Iran

Directory of Open Access Journals (Sweden)

Azadeh Malekzadeh Shafaroudi

2011-04-01

Full Text Available Eastern Iran has great potential for porphyry copper deposits, as a result of its past subduction zone tectonic setting that lead to extensive alkaline to calc-alkaline magmatic activity in Tertiary time. Maherabad is the first porphyry Cu-Au prospecting area which is discovered in eastern Iran. This is related to a succession o f monzonitic to dioritic porphyries stocks that were emplaced within volcanic rocks. Monzonitic porphyries have basic role in mineralization. Hydrothermal alteration zones are well developed including potassic, sericitic-potassic, quartz-sericite-carbonate-pyrite, quartz-carbonate-pyrite, silicified-propylitic, propylitic, carbonate and silicified zones. Mineralization occurs as Disseminated, stockwork and hydrothermal breccia. Based on early stage of exploration, Cu is between 179- 6830 ppm (ave. 3200 ppm and Au is up to 1000 ppb (ave. 570 ppb. This prospect is gold- rich porphyry copper deposit. Laser-ablation U-Pb dating of two samples from ore-related intrusive rocks indicate that these two monzonitic porphyries crystallized at 39.0 ± 0.8 Ma to 38.2 ± 0.8 Ma, within a short time span of less than ca. 1 Ma during the middle Eocene. This provides the first precise ages for metallogenic episode of porphyry-type mineralization. Also, the initial 87Sr/86Sr and (143Nd/144Ndi was recalculated to an age of 39 Ma. Initial 87Sr/86Sr ratios for monzonitic rocks are 0.7047-0.7048. The (143Nd/144Ndi isotope composition are 0.512694-0.512713. Initial ε Nd isotope values 1.45-1.81. Based on isotopic data the magma had originated beyond the continental crust. The study will be used for tectonic-magmatic setting and evolution of eastern Iran. Keywords: Lut block, Middle Eocene, Zircon, Geochronology, Laser ablation ICP-MS,

New SHRIMP U-Pb zircon ages of the metapelitic granulites from NW of Madurai, Southern India

International Nuclear Information System (INIS)

Prakash, D.

2010-01-01

Zircon cathodoluminescent imaging and SHRIMP U-Pb dating were carried out for metapelitic rocks (sapphirine-hearing granulites and garnet-cordierite gneisses) from the NW of Madurai, Southern India. The cathodoluminescence images reveal the complex, inhomogeneous internal structure having irregular-shaped core and overgrowths. Zircon grains have obliterated oscillatory zoning. SHRIMP U-Pb chronological results yield ages of 550 ± 15 Ma and 530 ± 50 Ma as a time of metamorphic overprint, and the age of 2509 ± 12 Ma and 2509 ± 30 Ma corresponding to a timing of protolith formation for sapphirine-bearing granulites and garnet-cordierite gneisses respectively. Zircon ages reflect that continental crust in the NW of Madurai region resulted from the recycling of Archaean protolith of an igneous origin similar to the preserved crust in the southern part of Dharwar craton. The present SHRIMP U-Pb zircon ages are in close agreement with earlier published Nd isotopic data which suggest an extended precrustal history of their protoliths. The abraded zircon grains indicate multiple recycling and repeated metamorphism that has ultimately resulted in present day continental crust exposed in Madurai region. These SHRIMP U-Pb zircon ages from metapelitic UHT granulites are also significant to understanding the architecture of the SGT during the amalgamation of Gondwana in Neoproterozoic time. (author)

A review of the statistical principles of geochronometry. II. Additional concepts pertinent to radiogenic U-Pb studies

International Nuclear Information System (INIS)

Eglington, B.M.; Harmer, R.E.

1993-01-01

A summary is provided of statistical regression techniques as applied to radiogenic uranium-lead data. The model-dependent nature of U-Pb regression calculations, both for isochrons and errorchrons, is emphasized throughout. Near concordant U-Pb radiogenic data preserve better information about the original age of the samples than do more discordant data, yet most conventional regression techniques assign more importance to the discordant data than to those near concordia. The links between mathematical techniques for regression and conceptual models are highlighted and critically examined and methods illustrated to deal with the discordant data. Comparison of dates from different laboratories or researchers requires that the techniques applied be statistically valid and, in most cases, that the model-dependent assumptions be compatible. This is particularly important for U-Pb radiogenic data where the influence of model-dependent assumptions may have a greater influence than in the case of whole-rock techniques. A consistent approach is proposed for treating data at South African laboratories in order ro facilitate comparison of results. Recommendations are presented as regards the minimum requirements to be met when reporting radiogenic U-Pb isotope data so that future geochronologists may benefit. 35 refs., 2 tabs., 6 figs

The U-Pb System in Schorlomite from Calcite-Amphobole-Pyroxene Pegmatite of the Afrikanda Complex (Kola Peninsula)

Science.gov (United States)

Salnikova, E. B.; Stifeeva, M. V.; Chakhmouradian, A. R.; Glebovitsky, V. A.; Reguir, E. P.

2018-02-01

The geochronological U-Pb study of shorlomite from igneous rocks of the alkali-ultramafic Afrikanda massif (Kola Peninsula) was performed. The results demonstrate the reliability of calcium garnet as a mineral for the U-Pb geochronology of a wide range of igneous rocks, i.e., carbonatite, syenite, foidolite, foidite, melilitolite, melilitite, lamprophyres, micaceous kimberlites, etc., and associated rare earth and trace elements (REE, Nb, Zr) mineralization.

Thermal infrared and microwave absorbing properties of SrTiO{sub 3}/SrFe{sub 12}O{sub 19}/polyaniline nanocomposites

Energy Technology Data Exchange (ETDEWEB)

Hosseini, Seyed Hossein, E-mail: shhosseini@iiau.ac.ir [Department of Chemistry, Faculty of Science, Islamshahr Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Zamani, Parisa [Department of Applied Chemistry, Faculty of Pharmaceutical Chemistry, Pharmaceutical Sciences Branch, Islamic Azad University, Tehran (Iran, Islamic Republic of); Mousavi, S.Y. [Faculty of Passive Defense, Imam Hossein University, Tehran (Iran, Islamic Republic of)

2015-09-25

Graphical abstract: We have developed a new perspective of applications and properties of conducting polymers. The combination of absorption ability prepared nanocomposites in the present of PANI display a great potential in organization of shielding structures into thermal IR and microwave. Further investigations using other conducting polymers to demonstrate their capability for advance thermal IR and microwave shielding devices is under way. The application of these samples may improve the IR thermographic detection, catalysis, sensors, magnetic data storage, electromagnetic resonance wave absorption, photonic crystals, and microelectronic devices and military aspects. - Highlights: • The SrTiO{sub 3}/SrFe{sub 12}O{sub 19}/PANI exhibited electric and electromagnetic properties. • The SrTiO{sub 3}/SrFe{sub 12}O{sub 19}/PANI has shielding structures into thermal IR and microwave. • Increasing weight ratios and thicknesses will increase thermal IR ability. • Increasing weight ratios and thicknesses will increase microwave absorption ability. - Abstract: Polyaniline (PANI) as a unique polymer that also has electromagnetic absorption used as the substrate. In this research, SrTiO{sub 3} was synthesized as IR absorbent and core and then SrFe{sub 12}O{sub 19} as microwave absorbent was prepared on SrTiO{sub 3} via co-precipitation method as the first shell. As the next step, PANI was coated on SrTiO{sub 3}/SrFe{sub 12}O{sub 19} nanoparticles via in situ polymerization by multi core–shell structures (SrTiO{sub 3}/SrFe{sub 12}O{sub 19}/PANI). Nanometer size and structures of samples were measured by TEM, XRD and FTIR. Morphology of nanocomposite was showed by SEM images. The magnetic and electric properties were also performed by VSM and four probe techniques. Thermal infrared (IR) absorption and microwave reflection loss of nanocomposites were investigated at 10–40 μm and 8–12 GHz, IR and microwave frequencies, respectively. The results showed that the Sr

Breaking through the uncertainty ceiling in LA-ICP-MS U-Pb geochronology

Science.gov (United States)

Horstwood, M.

2016-12-01

Sources of systematic uncertainty associated with session-to-session bias are the dominant contributor to the 2% (2s) uncertainty ceiling that currently limits the accuracy of LA-ICP-MS U-Pb geochronology. Sources include differential downhole fractionation (LIEF), `matrix effects' and ablation volume differences, which result in irreproducibility of the same reference material across sessions. Current mitigation methods include correcting for LIEF mathematically, using matrix-matched reference materials, annealing material to reduce or eliminate radiation damage effects and tuning for robust plasma conditions. Reducing the depth and volume of ablation can also mitigate these problems and should contribute to the reduction of the uncertainty ceiling. Reducing analysed volume leads to increased detection efficiency, reduced matrix-effects, eliminates LIEF, obviates ablation rate differences and reduces the likelihood of intercepting complex growth zones with depth, thereby apparently improving material homogeneity. High detection efficiencies (% level) and low sampling volumes (20um box, 1-2um deep) can now be achieved using MC-ICP-MS such that low volume ablations should be considered part of the toolbox of methods targeted at improving the reproducibility of LA-ICP-MS U-Pb geochronology. In combination with other strategies these improvements should be feasible on any ICP platform. However, reducing the volume of analysis reduces detected counts and requires a change of analytical approach in order to mitigate this. Appropriate strategies may include the use of high efficiency cell and torch technologies and the optimisation of acquisition protocols and data handling techniques such as condensing signal peaks, using log ratios and total signal integration. The tools required to break the 2% (2s) uncertainty ceiling in LA-ICP-MS U-Pb geochronology are likely now known but require a coherent strategy and change of approach to combine their implementation and realise

Zircon U-Pb ages and Sr-Nd-Hf isotopes of the highly fractionated granite with tetrad REE patterns in the Shamai tungsten deposit in eastern Inner Mongolia, China: Implications for the timing of mineralization and ore genesis

Science.gov (United States)

Jiang, Si-Hong; Bagas, Leon; Hu, Peng; Han, Ning; Chen, Chun-Liang; Liu, Yuan; Kang, Huan

2016-09-01

The Shamai tungsten deposit is located in the eastern part of the Central Asian Orogenic Belt (CAOB). Tungsten mineralization is closely related to the emplacement of fine- to medium-grained biotite monzogranite (G1) and porphyritic biotite monzogranite (G2) in the Shamai Granite. NW-trending joints and faults host orebodies in the Shamai Granite and Devonian hornfels. The mineralization is characterized by a basal veinlet zone progressing upwards to a thick vein zone followed by a mixed zone, a veinlet zone, and a thread vein zone at the top. The ore-related alteration typically consists of muscovite, greisen, and hornfels. In order to constrain the timing of the Shamai mineralization and discuss the ore genesis, muscovite Ar-Ar, molybdenite Re-Os, and zircon U-Pb geochronological, geochemical, and Sr-Nd-Hf isotopic studies were completed on the deposit. The U-Pb zircon dating yielded weighted mean ages of 153 ± 1 Ma for G1 and 146 ± 1 Ma for G2. Muscovite from a wolframite-bearing quartz vein yielded an Ar-Ar plateau age of 140 ± 1 Ma, whereas two molybdenite samples yielded identical Re-Os model ages of 137 ± 2 Ma. These two ages are younger than the two monzogranites, suggesting a prolonged magmatic-hydrothermal interaction during tungsten mineralization. Major and trace element geochemistry shows that both G1 and G2 are characterized by high SiO2 and K2O contents, high A/CNK values (1.08-1.40), a spectacular tetrad effect in their REE distribution patterns, and non-CHARAC (charge-and-radius-controlled) trace element behavior. This suggests that both G1 and G2 are highly differentiated peraluminous rocks with strong hydrothermal interaction. The Nd-Hf isotope data for the Shamai Granite (εNd(t) between - 1.9 and + 7.4, ɛHf(t) from 5.2 to 12.8) are largely compatible with the general scenario for much of the Phanerozoic granite emplaced in the CAOB. It is here suggested that the Shamai Granite originated from partial melting of a juvenile lower crust with

Vadose Zone Infiltration Rate at Hanford, Washington, Inferred from Sr Isotope Measurements

International Nuclear Information System (INIS)

Maher, Katharine; DePaolo, Donald J.; Conrad, Mark E.; Serne, R. Jeffrey

2003-01-01

Sr isotope ratios were measured in the pore water, acid extracts, and sediments of a 70-m vadose zone core to obtain estimates of the long-term infiltration flux for a site in the Hanford/DOE complex in eastern Washington State. The 87Sr/86Sr values of the pore waters decrease systematically with depth, from a high value of 0.721 near the surface toward the bulk sediment average value of 0.711. Estimates of the bulk weathering rate combined with Sr isotopic data were used to constrain the long-term (century to millenial scale) natural diffuse infiltration flux for the site given both steady state and nonsteady state conditions. The models suggest that the infiltration fluc for the site is 7+- 3 mm/yr. The method shows potential for providing long-term in situ estimates of infiltration rates for deep heterogeneous vadose zones

Time-scale calibration by U-Pb geochronology: Examples from the Triassic Period

Science.gov (United States)

Mundil, R.

2009-05-01

U-Pb zircon geochronology, pioneered by Tom Krogh, is a cornerstone for the calibration of the time scale. Before Krogh's innovations, U-Pb geochronology was essentially limited by laboratory blank Pb (typically hundreds of nanograms) inherent in the then existing zircon dissolution and purification methods. The introduction of high pressure HF dissolution combined with miniature ion exchange columns (1) reduced the blank by orders of magnitude and allowed mass-spectrometric analyses of minute amounts of material (picograms of Pb and U). Krogh also recognized the need for minimizing the effects of Pb loss, and the introduction of the air-abrasion technique was the method of choice for two decades (2), until the development of the combined annealing and chemical abrasion technique resulted in essentially closed system zircons (3). These are the prerequisite for obtaining precise (permil-level) and accurate radio-isotopic ages of individual zircons contained in primary volcanic ash deposits, which are primary targets for the calibration of the time scale if they occur within fossil bearing sediments. A prime example is the calibration of the Triassic time scale which improved significantly using these techniques. The ages for the base and the top of the Triassic are constrained by U-Pb ages to 252.3 (4) and 201.5 Ma (5), respectively. These dates also constrain the ages of major extinction events at the Permian-Triassic and Triassic-Jurassic boundaries, and are statistically indistinguishable from ages obtained for the Siberian Traps and volcanic products from the Central Atlantic Magmatic Province, respectively, suggesting a causal link. Ages for these continental volcanics, however, are mostly from the K-Ar (40Ar/39Ar) system which requires accounting and correcting for a systematic bias of ca 1 % between U-Pb and 40Ar/39Ar isotopic ages (the 40Ar/39Ar ages being younger) (6). Robust U-Pb age constraints also exist for the Induan- Olenekian boundary (251.2 Ma, (7

Study of atomic and molecular emission spectra of Sr by laser induced breakdown spectroscopy (LIBS).

Science.gov (United States)

Bhatt, Chet R; Alfarraj, Bader; Ayyalasomayajula, Krishna K; Ghany, Charles; Yueh, Fang Y; Singh, Jagdish P

2015-12-01

Laser Induced Breakdown Spectroscopy (LIBS) is an ideal analytical technique for in situ analysis of elemental composition. We have performed a comparative study of the quantitative and qualitative analysis of atomic and molecular emission from LIBS spectra. In our experiments, a mixture of SrCl2 and Al2O3 in powder form was used as a sample. The atomic emission from Sr and molecular emission from SrCl and SrO observed in LIBS spectra were analyzed. The optimum laser energies, gate delays, and gate widths for selected atomic lines and molecular bands were determined from spectra recorded at various experimental parameters. These optimum experimental conditions were used to collect calibration data, and the calibration curves were used to predict the Sr concentration. Limits of detection (LODs) for selected atomic and molecular emission spectra were determined.

Air abrasion experiments in U-Pb dating of zircon

Science.gov (United States)

Goldich, S.S.; Fischer, L.B.

1986-01-01

Air abrasion of zircon grains can remove metamict material that has lost radiogenic Pb and zircon overgrowths that were added during younger events and thereby improve the precision of the age measurements and permit closer estimates of the original age. Age discordance that resulted from a single disturbance of the U-Pb isotopic decay systems, as had been demonstrated by T.E. Krogh, can be considerably reduced, and, under favorable conditions, the ages brought into concordancy. Two or more events complicate the U-Pb systematics, but a series of abrasion experiments can be helpful in deciphering the geologic history and in arriving at a useful interpretation of the probable times of origin and disturbances. In east-central Minnesota, U.S.A., Penokean tonalite gneiss is dated at 1869 ?? 5 Ma, and sheared granite gneiss is shown to have been a high-level granite intrusion at 1982 ?? 5 Ma in the McGrath Gneiss precursor. Tonalite gneiss and a mafic granodiorite in the Rainy Lake area, Ontario, Canada, are dated at 2736 ?? 16 and 2682 ?? 4 Ma, respectively. The tonalitic phase of the Morton Gneiss, southwestern Minnesota, is dated at 3662 ?? 42 Ma. ?? 1986.

U-Pb thermochronology of the lower crust: producing a long-term record of craton thermal evolution

Science.gov (United States)

Blackburn, T.; Bowring, S. A.; Mahan, K. H.; Perron, T.; Schoene, B.; Dudas, F. O.

2010-12-01

The EarthScope initiative is focused on providing an enhanced view of the North American lithosphere and the present day stress field of the North American continent. Of key interest is the interaction between convecting asthenosphere and the conducting lithospheric mantle that underlie the continents, especially the cold ‘keels’ that underlie Archean domains. Cratonic regions are in general characterized by minimal erosion and or sediment accumulation. The Integration of seismic tomography, and mantle xenolith studies reveal a keel of seismically fast and relatively buoyant and viscous mantle; physical properties that are intimately linked with the long-term stability and topographic expression of the region. Missing from this model of the continental lithosphere is the 4th dimension--time--and along with it our understanding of the long-term evolution of these stable continental interiors. Here we present a thermal record from the North American craton using U-Pb thermochronology of lower crustal xenoliths. The use of temperature sensitive dates on lower crustal samples can produce a unique time-temperature record for a well-insulated and slowly cooling lithosphere. The base of the crust is insulated enough to remain unperturbed by any plausible changes to surface topography, yet unlike the subadjacent lithospheric mantle, contains accessory phases amenable to U-Pb dating (rutile, apatite, titanite). With near steady state temperatures in the lower crust between 400-600 °C, U-Pb thermochronometers with similar average closure temperatures for Pb are perfectly suited to record the long-term cooling of the lithosphere. Xenoliths from multiple depths, and across the craton yield time-temperature paths produced from U-Pb thermochronometers that record extremely slow cooling (<0.25 °C/Ma) over time scales of billions of years. Combining these data with numerical thermal modeling allow constraints to be placed on the dominant heat transfer mechanisms operating

Strain dependence of interfacial antiferromagnetic coupling in La0.7Sr0.3MnO3/SrRuO3 superlattices

Science.gov (United States)

Das, Sujit; Herklotz, Andreas; Pippel, Eckhard; Guo, Er-Jia; Rata, Diana; Dörr, Kathrin

2015-03-01

We have investigated the magnetic response of La0.7Sr0.3MnO3/SrRuO3 superlattices to biaxial in-plane strain applied in-situ. Superlattices grown on piezoelectric substrates of 0.72PbMg1/3Nb2/3O3-0.28PbTiO3(001) (PMN-PT) show strong antiferromagnetic coupling of the two ferromagnetic components. The coupling field of μ0HAF = 1.8 T is found to change by μ0 ΔHAF / Δɛ ~ -520 mT %-1 under reversible biaxial strain (Δɛ) at 80 K in a [La0.7Sr0.3MnO3(22 Å)/SrRuO3(55 Å)]15 superlattice. This reveals a significant strain effect on interfacial coupling. The applied in-plane compression enhances the ferromagnetic order in the manganite layers which are under as-grown tensile strain. It is thus difficult to disentangle the contributions from strain-dependent antiferromagnetic Mn-O-Ru interface coupling and Mn-O-Mn ferromagnetic double exchange near the interface, since the enhanced magnetic order of Mn spins leads to a larger net coupling of SrRuO3 layers at the interface. We discuss our experimental findings taken into account both the strain-dependent orbital occupation in a single-ion picture and the enhanced Mn order at the interface. This work was supported by the DFG within the Collaborative Research Center SFB 762 ``Functionality of Oxide Interfaces.''

IMPORTANCE OF IN SITU MONITORS IN THE PREPARATION OF LAYERED OXIDE HETEROSTRUCTURES BY REACTIVE MBE.

Energy Technology Data Exchange (ETDEWEB)

Schlom, Darrell G.; Haeni, J. H.; Theis, C. D. (Christopher); Tian, W.; Pan, X. Q.; Brown, G. W. (Geoffrey W.); Hawley, M. E. (Marilyn E.)

2001-01-01

Using a variety of in situ monitors and when possible adsorption-controlled growth conditions, layered oxide heterostructures including new compounds and metastable superlattices have been grown by reactive molecular beam epitaxy (MBE). The heteroepitaxial layers grown include Bi{sub 4}Ti{sub 3}O{sub 12}-SrTiO{sub 3} and Bi{sub 4}Ti{sub 3}O{sub 12}-PbTiO{sub 3} Aurivillius phases, Sr{sub n+1}Ti{sub n}O{sub 3n+1} Ruddlesden-Popper phases, and metastable PbTiO{sub 3}/SrTiO{sub 3} and BaTiO{sub 3}/SrTiO{sub 3} superlattices. Accurate composition control is key to the controlled growth of such structures, and to this end combinations of reflection high-energy electron diffraction (RHEED), atomic absorption spectroscopy (AA), a quartz crystal microbalance (QCM), and adsorption-controlled growth conditions were employed during growth. The structural perfection of the films has been investigated using in situ RHEED, four-circle x-ray diffraction, atomic force microscopy (AFM), and high-resolution transmission electron microscopy (TEM).

U-Pb age for some base-metal sulfide deposits in Ireland: genetic implications for Mississippi Valley-type mineralization

International Nuclear Information System (INIS)

Duane, M.J.; Welke, H.J.; Allsopp, H.L.

1986-01-01

Evidence is presented that links the timing of vein-type (Cu-Ag(U)) to stratiform Mississippi Valley-type (MVT, Pb-Zn) ore events in Ireland. The rare occurrence of pitchblende, coffinite(?), and brannerite mineralization, which is regarded as a precursor component to the sulfide mineralization in the Gortdrum deposit (Ireland), provides the first direct radiometric dating tool for these carbonate-hosted deposits. The U-Pb (340 +25/-20 Ma) and Pb-Pb (359 +/- 26 Ma) whole-rock ages constrain the uranium and base-metal mineralizing events to the Early Carboniferous. The data support a model according to which MVT and earlier uranium mineralization stages of some major ore bodies resulted from fracturing coincident with large basin-dewatering events. The Pb-Pb and concordia data are consistent with an Early Carboniferous age for the mineralization at Gortdrum and agree closely with a previously published Rb-Sr age of 359 +/- 22 Ma, obtained for Missouri glauconites. Furthermore, other comparative geologic data from Ireland and from North American MVT mineral provinces support a model of Pb-Zn-Cu(U) mobilization on a regional scale that implicates the later closing stages of the proto-Atlantic. 40 references, 3 figures, 1 table

High-precision ID-TIMS zircon U-Pb geochronology using new 1013 Ohm resistors

Science.gov (United States)

Von Quadt, A.; Buret, Y.; Large, S.; Peytcheva, I.; Trinquier, A.; Wotzlaw, J. F.

2015-12-01

Faraday cups equipped with high gain amplifiers provide a means to measure small ion beams in static mode without the limited linear range of ion counting systems. We tested the application of newly available 1013 Ohm resistors to ID-TIMS zircon U-Pb geochronology using a range of natural and synthetic reference materials. The TritonPlus-RPQ at the Institute of Geochemistry and Petrology, ETH Zurich, is equipped with five new 1013 Ohm resistors and one MasCom secondary electron multiplier, allowing to measure the 202-204-205-206-207-208Pb masses in static mode. U is measured subsequently as U-oxide (265-267-270UO2) during a second step, also in static Faraday mode. The gain calibration of the 1013 Ohm resistors was performed using the procedure of Trinquier (2014), with 144Nd-146Nd being measured using 1011 Ohm resistor and 142-143-145-148-150Nd being measured using 1013 Ohm resitors (Trinquier, 2014; Koornneef et al., 2014). Standard deviations of the noise in all five new 1013 Ohm resistors are lower than 5.0 x 10-6 over a 6 month period, with no shift occurring over this time interval. This new detector set-up was tested by analyzing natural zircon standard materials and synthetic U/Pb solutions (www.earthime.org), ranging in age from ~2 Ma to ~600 Ma. All natural zircon standards were chemically abraded (Mattinson, 2005) and all samples were spiked with the ET2535 tracer solution. U-Pb dates obtained using the static measurement routine are compared to measurements employing dynamic peak jumping routines on the MasCom multiplier. This study illustrates the benefits and current limitations of using high gain amplifiers to measure small ion beams for zircon U-Pb geochronology compared to conventional dynamic ion counting techniques. Mattinson, J.M. (2005) Chemical Geology 220:47-66; Trinquier, A. (2014) Application Note 30281; Koornneef, J. et al (2014) Analytica Chimica Acta 819:49-55.

Petrogenesis and zircon U-Pb dating of skarnified pyroxene-bearing dioritic rocks in Bisheh area, south of Birjand, eastern Iran

Directory of Open Access Journals (Sweden)

Malihe Nakhaei

2014-10-01

Full Text Available Introduction The study area is located 196 km south of Birjand in eastern border of the Lut block Berberian and King, 1981 in eastern Iran between 59°05′35" and 59°09′12" E longitude and 31°42′29" and 31°44′13" N latitude. The magmatic activity in the Lut block began in the middle Jurassic such as Kalateh Ahani, Shah Kuh and Surkh Kuh granitoids that are among the oldest rocks exposed within the Lut block (Esmaeily et al., 2005; Tarkian et al., 1983; Moradi Noghondar et al., 2011-2012. Eastern Iran, and particularly the Lut block, has great potential for different types of mineralization as skarnification in Bisheh area which has been studied in this paper. The goal of this study is to highlight the geochronology, geochemistry of major and trace elements, Rb-Sr, Sm-Nd isotopes for skarnified pyroxene-bearing diorites. Materials and methods Major element compositions of thirteen samples were determined by wavelength-dispersive X-ray fluorescence (XRF spectrometry, using fused discs and the Phillips PW 1410 XRF spectrometer at Ferdowsi University, Mashhad, Iran. These samples were analysed for trace elements using inductively coupled plasma-mass spectrometry (ICP-MS in the Acme Analytical Laboratories, Vancouver, British Columbia, Canada. Zircon grains were separated from pyroxene diorite porphyrys using heavy liquid and magnetic techniques at the Institute of Earth Sciences, Academia Sinica, Taipei, Taiwan. Zircon U-Pb dating was performed by laser ablation-inductively-coupled plasma-mass spectrometry (LA-ICP-MS, using an Agilent 7500 s machine and a New Wave UP213 laser ablation system, equipped at the Dr Shen-Su Sun memorial laboratory in the Department of Geosciences, National Taiwan University, Taiwan. Strontium and Nd isotopic analyses were performed on a six-collector Finnigan MAT 261 thermal-ionization mass spectrometer at the University of Colorado, Boulder, Colorado, United States. 87Sr/86Sr ratios were determined using four

U-Pb zircon geochronology, Sr-Nd isotope geochemistry, and petrogenesis of oxidant granitoids at Keybarkuh, southwest of Khaf

Directory of Open Access Journals (Sweden)

Ehsan Salati

2012-10-01

Full Text Available Keybarkuh area is located 70 km southwest of Khaf, Khorasan Razavi province. The study area is situated in northeastern Lut block. The rock units in the area are Paleozoic metamorphic rocks and Cretaceous to Tertiary subvolcanic intrusions intruded as dike, stock and batholith; their composition varies from granite to diorite. Based on magnetic susceptibility, the intrusive rocks are divided into oxidant and reduced series. In this study, the oxidant intrusions are discussed. These intrusions are mostly high-K to shoshonitic and also meta-aluminous type. Their magma formed in subduction magmatic arc and they belong to I-type granitoid series. Enrichment of Large Ion Lithophile Elements (LILE such as Rb, Cs, K, Ba, and Th relative to High Field Stength Elements (HFSE such as Nb, Zr, and Ti supported the idea. Enrichment of Light Rare Earth Elements (LREE and depletion of Heavy Rare Earth Elements (HREE are also typical of subduction magmatism. Negative anomalies of Eu/Eu* can be attributed to the presence of residual plagioclase in a mantle source and contamination of magma by reduced continental crust. The amount of Nb > 11 ppm, lower ratio of Zr/Nb 0.706, initial 143Nd/144Nd (> 0.512 and εNd (< -3.5 indicate that magma contaminated by reduced continental crust. Hornblende biotite granodiorite porphyry dated using U-Pb zircon geochronology at 43.44 Ma (Middle Eocene. Based on calculated TDM, magma derived from ancient slab with 820 Ma age in the Keybarkuh area, was affected by the highest continental crust contamination during its ascent.

Sr, Mg cosubstituted HA porous macro-granules: potentialities as resorbable bone filler with antiosteoporotic functions.

Science.gov (United States)

Landi, Elena; Uggeri, Jacopo; Medri, Valentina; Guizzardi, Stefano

2013-09-01

Porous macro-granules of nanostructured apatite with Ca ions partially cosubstituted with Mg and Sr ions in different ratios (SrMgHAs), were synthesized at 37°C and compared with Mg and/or Sr free apatites (MgHAs and HA). Strontium improved the Mg substitution extent in the apatite and the chemical-physical and thermal stability of the resulting cosubstituted apatite. Porous macro-granules of 400-600 micron with selected composition were tested for the ionic release in synthetic body fluid and the data were related with the results of preliminary cell investigation in vitro. As compared to the corresponding Sr-free granulate, the SrMgHA could be exploited to prolong the beneficial Mg release during the bone regeneration process. In addition the contemporary in situ supply of Sr, an antiosteoporotic and anticarie ion, could influence the quality of new hard tissues. The ionic multirelease created a more favorable environment for human osteoblasts, demonstrated by a proliferative effect for each dose tested in the range 0.1-10 mg/mL. Copyright © 2013 Wiley Periodicals, Inc.

Geologic evolution of the Paraiba do Sul complex, in the central part of the Ribeira belt, based on the geochemistry and U-Pb geochronology studies; Evolucao geologica do complexo Paraiba do Sul, no segmento central da faixa Ribeira, com base em estudos de geoquimica e geocronologia U-Pb

Energy Technology Data Exchange (ETDEWEB)

Valladares, Claudia Sayao

1996-12-31

Aiming the definition of the Complexo Paraiba do Sul evolution, the work presents a geochronological approach by the U-Pb method, considered appropriate to study polideformed terrains. The minerals used to the U-Pb dating (zircon, titanite and monazite) provides information about the ages of rock generation and the successive geological events the rocks were submitted. The U-Pb geochronological approach is pioneer in the investigated area and two questions referent to the Complexo Paraiba do Sul evolution in the central part of the Ribeira belt, were the aim of this approach. The first of them refers to the crystallization epoch and the gneisses metamorphism, interpreted here like orthogneisses, called Unidade Quirino of the Complexo Paraiba do Sul. The second refers to the metamorphism ages and meta sedimentary unit deformation. Looking for the contribution to the Complexo Paraiba do Sul evolution understanding, this work presents the data based on the geologic map of this area, comprising part of the Folha Volta Redonda (1:50.000), including petrographic, structural and microtectonic studies. It also presents and discusses the results of: 17 U-Pb analysis in zircon and titanite of the Complexo Paraiba do Sul orthogneisses collection; 24 geochemical analysis of major, minor, trace elements and ETR of the same collection; an U-Pb analysis in titanite of the Unidade Sao Joao, 5 U-Pb analysis in titanites and/or monazites of granites and granitoids; 12 geochemical analysis including major, minor and trace elements and ETR, in granites and sills of leucogranites. Finally, the data achieved were integrated with the objective to elaborate an evolutive view of the Complexo Paraiba do Sul 157 refs., 54 figs., 17 tabs.

Geologic evolution of the Paraiba do Sul complex, in the central part of the Ribeira belt, based on the geochemistry and U-Pb geochronology studies; Evolucao geologica do complexo Paraiba do Sul, no segmento central da faixa Ribeira, com base em estudos de geoquimica e geocronologia U-Pb

Energy Technology Data Exchange (ETDEWEB)

Valladares, Claudia Sayao

1997-12-31

Aiming the definition of the Complexo Paraiba do Sul evolution, the work presents a geochronological approach by the U-Pb method, considered appropriate to study polideformed terrains. The minerals used to the U-Pb dating (zircon, titanite and monazite) provides information about the ages of rock generation and the successive geological events the rocks were submitted. The U-Pb geochronological approach is pioneer in the investigated area and two questions referent to the Complexo Paraiba do Sul evolution in the central part of the Ribeira belt, were the aim of this approach. The first of them refers to the crystallization epoch and the gneisses metamorphism, interpreted here like orthogneisses, called Unidade Quirino of the Complexo Paraiba do Sul. The second refers to the metamorphism ages and meta sedimentary unit deformation. Looking for the contribution to the Complexo Paraiba do Sul evolution understanding, this work presents the data based on the geologic map of this area, comprising part of the Folha Volta Redonda (1:50.000), including petrographic, structural and microtectonic studies. It also presents and discusses the results of: 17 U-Pb analysis in zircon and titanite of the Complexo Paraiba do Sul orthogneisses collection; 24 geochemical analysis of major, minor, trace elements and ETR of the same collection; an U-Pb analysis in titanite of the Unidade Sao Joao, 5 U-Pb analysis in titanites and/or monazites of granites and granitoids; 12 geochemical analysis including major, minor and trace elements and ETR, in granites and sills of leucogranites. Finally, the data achieved were integrated with the objective to elaborate an evolutive view of the Complexo Paraiba do Sul 157 refs., 54 figs., 17 tabs.

Petrogenesis of Malaysian tin granites: geochemistry, fractional crystallization, U-Pb zircon geochronology and tectonic setting

Science.gov (United States)

Wai-Pan Ng, Samuel; Searle, Mike; Whitehouse, Martin; Chung, Sun-Lin; Ghani, Azman; Robb, Laurence; Sone, Masatoshi; Oliver, Grahame; Gardiner, Nick; Roselee, Mohammad

2014-05-01

The Malaysian tin granites forming the backbone of the Thai-Malay Peninsula has been long recognized with two distinct granitic provinces:- 1. Early Permian to Late Triassic Eastern Province with mainly "I-type" (Hbl)-Bt granites with associated Cu-Au deposits, with subordinate Bt granites hosting limited Sn-W deposits, and 2. Late Triassic Main Range Province with mainly "S-type" Bt granites with associated Sn-W deposits, and subordinate (Hbl)-Bt granites. New geochemical data show that Chappell and White's (1974) I-S granite classification adopted in the existing model does not adequately distinguish the granites from one another as previously implied. Trace element geochemistry and Sr-Nd isotopic compositions show that the Malaysian tin granites in both provinces have transitional I-S characteristics. In addition, they inherited within-plate signature from Cambro-Ordovician Gondwana-related source rocks. Previous ages were obtained by whole rock Rb-Sr and biotite K-Ar geochronology in the 70s and 80s, dating methods that may not accurately represent the crystallization age of granites. We re-sampled the entire Malaysian Peninsula and 40 samples were collected for high-precision U-Pb SIMS dating on extracted zircon grains in order to better constrain the magmatic and tectonic evolution of Southeast Asia. The crystallization ages of the Eastern Province granitoids have been constrained ranging from 220 to 290 Ma, while the Main Range (Western) Province granitoids have ages ranging from 200 to 230 Ma. A progressive westward younging trend is apparent across the Eastern Province, but becomes less obvious in the Main Range Province. Our model suggests two east dipping subduction zones. We suggest that subduction roll-back along the Bentong-Raub suture might account for the westward younging trend, in the Eastern province. A second Late Triassic east-dipping subduction zone beneath western Malaysia is proposed in order to explain the "I-type" components to the Main

Optimization of 90Sr/89Sr measurements

Directory of Open Access Journals (Sweden)

Legarda F.

2012-04-01

Full Text Available One of the key points in the double measurement method for the measurement of both, 89Sr and 90Sr, by using a proportional counter is the choice of the times at which the measurements should be done. In this paper, the formulae to calculate the 89Sr and 90Sr detection limits in conditions of radioactive equilibrium between 90Y and 90Sr are derived, and an analysis of them as a function of the time between the two measurements is done. The choice for the time of the second measurement is going to depend on the desired quality of the results to be obtained.

Did the Kiruna iron ores form as a result of a metasomatic or igneous process? New U-Pb and Nd data for the iron oxide apatite ores and their host rocks in the Norrbotten region of northern Sweden

Science.gov (United States)

Westhues, A.; Hanchar, J. M.; Whitehouse, M. J.; Fisher, C. M.

2012-12-01

A number of iron deposits near Kiruna in the Norrbotten region of northern Sweden are of the iron oxide apatite (IOA) type of deposits; also referred to as Kiruna-type deposits. They are commonly considered a subgroup or end-member of iron oxide copper gold (IOCG) deposits, containing no economic grades of copper or gold. Both IOCG and IOA deposits are characterized by abundant low-Ti Fe oxides, an enrichment in REE, and intense sodium and potassium wall-rock alteration adjacent to the ores. Deposits of these types are of a great economic importance, not only for iron, but also for other elements such as rare earth elements (REE) or uranium. Kiruna, the type locality of the IOA type of mineral deposits, is the focus of this study. Despite a century-long mining history and 2500 Mt of iron ore produced in the region to date (with grades of 30 to 70 wt.% Fe), the genesis of these deposits is poorly understood: theories of a magmatic vs. a hydrothermal or metasomatic origin have been debated, and the timing of mineralization of the ores in the Norbotten region has never been directly dated. The results anticipated from this study will provide a better understanding of the nature of the IOA type of mineral deposits and their relation to IOCG deposits such as Olympic Dam in Australia. An array of geochemical methods is used in order to gain insights on the emplacement history of the host rocks, their subsequent alteration, and the ore genesis of these deposits. This includes in situ U/Pb geochronology of zircon, monazite, and titanite to constrain the timing between host rock emplacement, alteration and mineralization. Isotopic data from whole rocks and in situ at mineral scale will provide constraints on the involvement of hydrothermal fluids and their possible sources, as well as on the sources of Fe, U, and the REE. Newly obtained Sm-Nd isotopic data points to distinct source differences between host rocks, ore and alteration related samples. Preliminary in situ U-Pb

Late Archaean-early Proterozoic source ages of zircons in rocks from the Paleozoic orogen of western Galicia, NW Spain

Energy Technology Data Exchange (ETDEWEB)

Kuijper, R P; Priem, H N.A. [Laboratorium voor Isotopen-Geologie, Amsterdam (Netherlands); Den Tex, E [Rijksuniversiteit Utrecht (Netherlands). Inst. voor Aardwetenschappen

1982-08-01

U-Pb data are reported for nine suites of zircons and three monazites from the Paleozoic orogen in western Galicia: one paragneiss and six orthogneisses from the early Paleozoic basement, and two Carboniferous (ca. 310 Ma old) intrusions of two-mica granite. New whole-rock Rb-Sr analyses, along with earlier data, indicate an age of ca. 470-440 Ma (Ordovician) for the emplacement of the granitic precursors of the orthogneisses. Monazite from the paragneiss also yields an U-Pb age of ca. 470 Ma. From the high initial /sup 87/Sr//sup 86/Sr ratios an involvement of Precambrian continental crust material is evident in the generation of the early Paleozoic suite of granites, while the zircon U-Pb data give evidence of the presence of about 3.0-2.0 Ga old (late Archaean-early Proterozoic) components in the source material. Zircons from the oldest sedimentary rocks in the area, now present as catazonal paragneisses and a likely source for the granites, likewise reveal a provenance age of 3.0-2.0 Ga.

Control of growth mode in SrTiO3 homoepitaxy under 500 deg. C

International Nuclear Information System (INIS)

Li Yanrong; Li Jinlong; Zhang Ying; Wei Xianhua; Deng Xinwu; Liu Xingzhao

2004-01-01

Homoepitaxial SrTiO 3 thin films were grown by laser molecular beam epitaxy. The growth mode was determined by in-situ reflective high energy electron diffraction, and the surface of the films was studied by ex-situ atomic force microscopy. At the deposition rate of 0.16A ring /sec and the laser energy density of 6J/cm 2 , layer-by-layer growth was observed above 460 deg. C substrate temperature, while the Stranski-Krastanov growth mode, that is layer-by-layer growth plus island growth mode, prevailed between 460 deg. C and 410 deg. C. On further decreasing the substrate temperature, the island growth was determined under 410 deg. C. With the optimization of deposition process in terms of laser energy density and deposition rate, the lowest crystallization temperatures of SrTiO 3 films grown in layer-by-layer growth mode were obtained as low as 280 deg. C. The effects of laser energy density on growth temperature were studied

Electronic properties and surface reactivity of SrO-terminated SrTiO3 and SrO-terminated iron-doped SrTiO3.

Science.gov (United States)

Staykov, Aleksandar; Tellez, Helena; Druce, John; Wu, Ji; Ishihara, Tatsumi; Kilner, John

2018-01-01

Surface reactivity and near-surface electronic properties of SrO-terminated SrTiO 3 and iron doped SrTiO 3 were studied with first principle methods. We have investigated the density of states (DOS) of bulk SrTiO 3 and compared it to DOS of iron-doped SrTiO 3 with different oxidation states of iron corresponding to varying oxygen vacancy content within the bulk material. The obtained bulk DOS was compared to near-surface DOS, i.e. surface states, for both SrO-terminated surface of SrTiO 3 and iron-doped SrTiO 3 . Electron density plots and electron density distribution through the entire slab models were investigated in order to understand the origin of surface electrons that can participate in oxygen reduction reaction. Furthermore, we have compared oxygen reduction reactions at elevated temperatures for SrO surfaces with and without oxygen vacancies. Our calculations demonstrate that the conduction band, which is formed mainly by the d-states of Ti, and Fe-induced states within the band gap of SrTiO 3 , are accessible only on TiO 2 terminated SrTiO 3 surface while the SrO-terminated surface introduces a tunneling barrier for the electrons populating the conductance band. First principle molecular dynamics demonstrated that at elevated temperatures the surface oxygen vacancies are essential for the oxygen reduction reaction.

Critical evaluation and thermodynamic optimization of the U-Pb and U-Sb binary systems

International Nuclear Information System (INIS)

Wang, Jian; Jin, Liling; Chen, Chuchu; Rao, Weifeng; Wang, Cuiping; Liu, Xingjun

2016-01-01

A complete literature review, critical evaluation and thermodynamic optimization of the phase diagrams and thermodynamic properties of U-Pb and U-Sb binary systems are presented. The CALculation of PHAse Diagrams (CALPHAD) method was used for the thermodynamic optimization, the results of which can reproduce all available reliable experimental phase equilibria and thermodynamic data. The modified quasi-chemical model in the pair approximation (MQMPA) was used for modeling the liquid solution. The Gibbs energies of all terminal solid solutions and intermetallic compounds were described by the compound energy formalism (CEF) model. All reliable experimental data of the U-Pb and U-Sb systems have been reproduced. A self-consistent thermodynamic database has been constructed for these binary systems; this database can be used in liquid-metal fuel reactor (LMFR) research.

In situ study of interface reactions of ion beam sputter deposited (Ba0.5Sr0.5)TiO3 films on Si, SiO2, and Ir

International Nuclear Information System (INIS)

Gao, Y.; Mueller, A.H.; Irene, E.A.; Auciello, O.; Krauss, A.; Schultz, J.A.

1999-01-01

(Ba 0.5 ,Sr 0.5 )TiO 3 (BST) thin films were deposited on MgO, Si, SiO 2 and Ir surfaces by ion beam sputter deposition in oxygen at 700 degree C. In situ spectroscopic ellipsometry (SE) has been used to investigate the evolution of the BST films on different surfaces during both deposition and postannealing processes. First, the optical constants of the BST films in the photon energy range of 1.5 - 4.5 eV were determined by SE analysis on crystallized BST films deposited on MgO single crystal substrates. The interfaces in BST/Si and BST/SiO 2 /Si structure were examined by SE and Auger electron spectroscopy depth profiles. Subcutaneous oxidation in the BST/Ir structure was observed by in situ SE during both ion beam sputter deposition and postdeposition annealing in oxygen at 700 degree C. A study of the thermal stability of the Ir/TiN/SiO 2 /Si structure in oxygen at 700 degree C was carried out using in situ SE. The oxidation of Ir was confirmed by x-ray diffraction. The surface composition and morphology evolution after oxidation were investigated by time of flight mass spectroscopy of recoiled ions (TOF-MSRI) and atomic force microscopy. It has been found that Ti from the underlying TiN barrier layer diffused through the Ir layer onto the surface and thereupon became oxidized. It was also shown that the surface roughness increases with increasing oxidation time. The implications of the instability of Ir/TiN/SiO 2 /Si structure on the performance of capacitor devices based on this substrate are discussed. It has been shown that a combination of in situ SE and TOF-MSRI provides a powerful methodology for in situ monitoring of complex oxide film growth and postannealing processes. copyright 1999 American Vacuum Society

Oxide ion diffusion mechanism related to Co and Fe ions in (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-δ using in-situ X-ray absorption spectroscopy

Science.gov (United States)

Itoh, Takanori; Imai, Hideto

2018-03-01

The time changes of the white line and pre-edge intensities of Co and Fe K-edge in (Ba0.5Sr0.5)(Co0.8Fe0.2)O3-δ (BSCF) were observed to estimate the oxide ion diffusion related to Co and Fe ions by using in - situ X-ray absorption spectroscopy (XAS) during oxidation. The 20 μm self-standing BSCF film was prepared for in - situ XAS measurements. The time changes of absorption were fitted to the exponential decay function with two terms. The longer relaxation time (τ), related to the oxide ion diffusion during the oxidation of BSCF, is dependent on temperature. The oxide ion diffusion coefficients (D) were calculated from the τ s estimated by in - situ XAS. The values of the activation energy (Ea) for D related to Co K-edge white line, Co pre-edge, and Fe pre-edge were 1.8-2.0 eV. The value of Ea for D related to Fe K-edge white line, however, was higher than other absorption values at approximately 2.3 eV. We discussed the oxide ion diffusion mechanism related to Co and Fe ions in BSCF using in - situ XAS.

Chemical abrasion-SIMS (CA-SIMS) U-Pb dating of zircon from the late Eocene Caetano caldera, Nevada

Science.gov (United States)

Watts, Kathryn E.; Coble, Matthew A.; Vazquez, Jorge A.; Henry, Christopher D.; Colgan, Joseph P.; John, David A.

2016-01-01

Zircon geochronology is a critical tool for establishing geologic ages and time scales of processes in the Earth's crust. However, for zircons compromised by open system behavior, achieving robust dates can be difficult. Chemical abrasion (CA) is a routine step prior to thermal ionization mass spectrometry (TIMS) dating of zircon to remove radiation-damaged parts of grains that may have experienced open system behavior and loss of radiogenic Pb. While this technique has been shown to improve the accuracy and precision of TIMS dating, its application to high-spatial resolution dating methods, such as secondary ion mass spectrometry (SIMS), is relatively uncommon. In our efforts to U-Pb date zircons from the late Eocene Caetano caldera by SIMS (SHRIMP-RG: sensitive high resolution ion microprobe, reverse geometry), some grains yielded anomalously young U-Pb ages that implicated Pb-loss and motivated us to investigate with a comparative CA and non-CA dating study. We present CA and non-CA 206Pb/238U ages and trace elements determined by SHRIMP-RG for zircons from three Caetano samples (Caetano Tuff, Redrock Canyon porphyry, and a silicic ring-fracture intrusion) and for R33 and TEMORA-2 reference zircons. We find that non-CA Caetano zircons have weighted mean or bimodal U-Pb ages that are 2–4% younger than CA zircons for the same samples. CA Caetano zircons have mean U-Pb ages that are 0.4–0.6 Myr older than the 40Ar/39Ar sanidine eruption age (34.00 ± 0.03 Ma; error-weighted mean, 2σ), whereas non-CA zircons have ages that are 0.7–1.3 Myr younger. U-Pb ages do not correlate with U (~ 100–800 ppm), Th (~ 50–300 ppm) or any other measured zircon trace elements (Y, Hf, REE), and CA and non-CA Caetano zircons define identical trace element ranges. No statistically significant difference in U-Pb age is observed for CA versus non-CA R33 or TEMORA-2 zircons. Optical profiler measurements of ion microprobe pits demonstrate consistent depths of ~ 1.6�

Augen gneisses versus Augen gneisses from the Jaguaribeana Belt, northeastern region from Brazil: stratigraphy, geochemistry and U-Pb ages

International Nuclear Information System (INIS)

Sa, Jaziel Martins; Silva, Elvis Roberto da; Bertrand, Jean Michel; Leterrier, Jacques

1997-01-01

The Jaguaribeana Belt is located at Borborema Province, Ceara State, Brazil and this study aims to present Uranium-Lead (U-Pb) data and the augen gneisses petrographic and geochemical study of the Jaguaribe Belt, and to realize comparisons between these and the augen gneisses from the Oros Belt. It describes the geological characteristics of this region, the augen gneisses petrography and geochemical data and the U-Pb method results for a discussion about the augen gneisses from the Oros and Jaguaribe Belt

Isotopic (U-Pb, Nd) and geochemical constraints on the origins of the Aileu and Gondwana sequences of Timor

Science.gov (United States)

Boger, S. D.; Spelbrink, L. G.; Lee, R. I.; Sandiford, M.; Maas, R.; Woodhead, J. D.

2017-02-01

Detrital zircon U-Pb age data collected from the argillitic sedimentary rocks of the Timorese Aileu Complex and Gondwana Sequence indicate that both units were derived from a common source containing 200-600 Ma, 900-1250 Ma and 1450-1900 Ma zircon. The modally most significant age population within this range of ages dates to c. 260 Ma. The observed spectrum of ages can be traced to the eastern active margin of Pangaea and its immediate foreland, which today is best exposed along the northeast coast of Australia. Compared to the relative homogeneity of the detrital zircon age data, geochemical and Nd isotopic data show that the mudstones of the Aileu Complex are on average more siliceous, have higher K2O/Na2O, Rb/Sr, Th/Sc and yield notably older Nd TDM model ages when compared to those from the Gondwana Sequence. These data are interpreted to suggest that, although both sequences share a common east Pangaea provenance, they were eroded from different sections of this active margin and deposited in spatially separated basins. The present proximity of these units is a result of their tectonic juxtaposition during the Pliocene to Recent collision between the northern edge of the Indo-Australia plate and the Banda Arc.

Polycyclic evolution of the Quadrilatero Ferrifero: an analysis based on the actual knowledge of the U-Pb geochronology and Sm-Nd isotopic geochemistry

International Nuclear Information System (INIS)

Carneiro, Mauricio Antonio; Noce, Carlos Mauricio; Teixeira, Wilson

1995-01-01

The tectonic evolution of the Quadrilatero Ferrifero region, based on geochronological U-Pb, Pb-Pb, Sm-Nd, Rb-Sr e K-Ar data, is characterized by several processes of crustal growth, which began in Middle Archean. The Lower Archean geological evolution of the Quadrilatero Ferrifero was finished by the Rio de Velhas tectono-thermal event around 2,78 Ga. After this, during the proterozoic era, three tectono-sedimentary cycles took place on this Lower Archean crustal fragment, whose products are represented by the meta sedimentary sequences of the Minas Supergroup, Itacolomi Group and Espinhaco Supergroup. The Transamazonico Event (ca. 2,0 Ga) ended the geological evolution of Minas Supergroup, but its geological records did not have the same size imprints throughout region. Many places, such as the Bonfim Metamorphic Complex, were not affected by this tectonic event. Later tectonic event. Later tectonic events (e.g. Brasiliano) had even more discrete geological occurred during the Proterozoic era, when many sedimentary basins developed (e.g. Espinhaco and Sao Francisco basins). (author)

Direct U-Pb dating of Cretaceous and Paleocene dinosaur bones, San Juan Basin, New Mexico: COMMENT

Science.gov (United States)

Koenig, Alan E.; Lucas, Spencer G.; Neymark, Leonid A.; Heckert, Andrew B.; Sullivan, Robert M.; Jasinski, Steven E.; Fowler, Denver W.

2012-01-01

Based on U-Pb dating of two dinosaur bones from the San Juan Basin of New Mexico (United States), Fassett et al. (2011) claim to provide the first successful direct dating of fossil bones and to establish the presence of Paleocene dinosaurs. Fassett et al. ignore previously published work that directly questions their stratigraphic interpretations (Lucas et al., 2009), and fail to provide sufficient descriptions of instrumental, geochronological, and statistical treatments of the data to allow evaluation of the potentially complex diagenetic and recrystallization history of bone. These shortcomings lead us to question the validity of the U-Pb dates published by Fassett et al. and their conclusions regarding the existence of Paleocene dinosaurs.

Feasibility of in situ beta ray measurements in underwater environment.

Science.gov (United States)

Park, Hye Min; Park, Ki Hyun; Kang, Sung Won; Joo, Koan Sik

2017-09-01

We describe an attempt at the development of an in situ detector for beta ray measurements in underwater environment. The prototype of the in situ detector is based on a CaF2: Eu scintillator using crystal light guide and Si photomultiplier. Tests were conducted using various reference sources for evaluating the linearity and stability of the detector in underwater environment. The system is simple and stable for long-term monitoring, and consumes low power. We show here an effective detection distance of 7 mm and a 2.273 MeV end-point energy spectrum of 90 Sr/ 90 Y when using the system underwater. The results demonstrate the feasibility of in situ beta ray measurements in underwater environment and can be applied for designing an in situ detector for radioactivity measurement in underwater environment. The in situ detector can also have other applications such as installation on the marine monitoring platform and quantitative analysis of radionuclides. Copyright © 2017 Elsevier Ltd. All rights reserved.

Precise U-Pb Zircon Dating of the Syenite Phase from the Ditrau Alkaline Igneous Complex

Directory of Open Access Journals (Sweden)

Pană Dinu

2000-04-01

Full Text Available The Ditrău igneous complex represents the largest alkaline intrusion in the Carpathian-Pannonian region consisting of a plethora of rock types formed by complicated magmatic and metasomatic processes. A detailed U-Pb zircon age study is currently underway and the results for the syenite intrusion phase is reported herein. The U-Pb zircon emplacement age of the syenite of 229.6 +1.7/-1.2 Ma documents the quasi-contemporaneous production and emplacement of the gabbro and syenite magmas. We suggest that the syenite and associated granite formed by crustal melting during the emplacement of the mantle derived gabbroic magma around 230 Ma. The thermal contact aureole produced by the Ditrău alkaline igneous complex constrains the main tectonism recorded by surrounding metamorphic lithotectonic assemblages to be pre-Ladinian.

Magmatic Longevity Constrained by ID-TIMS U-Pb Dating of Zircon and Titanite

Science.gov (United States)

Szymanowski, D.; Wotzlaw, J. F.; Ellis, B. S.; Bachmann, O.; Von Quadt, A.

2016-12-01

Clues about the timescales and thermal conditions associated with the growth and evacuation of large silicic magma reservoirs are frequently drawn from radiometric dating, diffusion modelling, or thermomechanical modelling. A growing amount of petrological and geochronological evidence, supported by thermal modelling, suggests that many silicic magma reservoirs may exist for some 104-106 years in the form of high-crystallinity mushes at relatively low temperatures ( 700-750°C; [1-3]). Geochronological studies addressing this issue typically utilise the U-Pb system in zircon capable of recording extended periods of crystallisation, particularly in evolved calc-alkaline systems that spend most of their lifetime zircon-saturated. In this study, we integrate U-Pb dating of zircon and titanite to investigate the longevity of the magma reservoir that produced the Kneeling Nun Tuff, a 35 Ma, >900 km3 crystal-rich rhyolitic super-eruption from the Mogollon-Datil volcanic field in New Mexico (USA). High-precision ID-TIMS U-Pb dates of single crystals of both zircon and titanite independently record a continuous crystallisation history over >400,000 years. We combine the dating of both accessory phases with textural, major, trace element and isotopic studies of single crystals, placing tight constraints on the thermal conditions of magma accumulation and storage while recording differentiation and rejuvenation processes within the magma reservoir. The results suggest a protracted `cool' upper-crustal storage of magma prior to the Kneeling Nun Tuff eruption followed by a melting event which reduced the magma crystallinity and conditioned it for eruption. [1] Bachmann & Bergantz (2004), J. Petrol. 45, 1565-1582. [2] Gelman et al. (2013), Geology 41, 759-762. [3] Cooper & Kent (2014), Nature 506, 480-483.

Dating in the Montagne Noire of a remnant of a major phase of crustal thinning characteristic of Prevariscan Europe

International Nuclear Information System (INIS)

Ducrot, Jean; Lancelot, J.R.; Reille, J.-L.

1979-01-01

U-Pb analysis on zircons has pointed out that the alkaline orthogneiss of Plaisance in the axial zone of the 'Montagne Noire', dates from 532+-13 m.y. this corresponds closely to previous data of Rb-Sr analysis (515+-11 m.y.). Although as a recent petrographical work has shown that this orthogneiss presents characters of an alkaline granite complex, the observed initial ratio 87 Sr/ 86 Sr which equals to 0.710, does not necessarily imply the partial melting of an old Precambrian basement in this area. Besides, the datation found from U-Pb analysis confirms the existence of a major episod of crustal thinning, characterized by the occurrence of an alkaline magmatism (530 m.y.) followed by one which is bimodal (500-480 m.y.) [fr

Molybdenite Re-Os, zircon U-Pb dating and Lu-Hf isotopic analysis of the Xiaerchulu Au deposit, Inner Mongolia Province, China

Science.gov (United States)

Wang, Jia-xin; Nie, Feng-Jun; Zhang, Xue-ni; Jiang, Si-hong

2016-09-01

The Xiaerchulu Au deposit, located in the Southern Orogenic Belt (SOB) of Western Inner Mongolia (WIM), is hosted in an Early Permian (271-261 Ma) volcanic-plutonic sequence. Mineralization took place in silicified biotite granites or along the contact zone between the Neoproterozoic Baiyinbaolage Group and the biotite granite. In order to constrain the timing of the Xiaerchulu mineralization and discuss the petrogenesis of the hosting granites, molybdenite Re-Os, and zircon U-Pb and, Lu-Hf, and REE, geochemical, and Sr-Nd isotopic studies were completed in this study. We measured Re-Os isotopes of six molybdenite samples from the main ore body, which yielded a weighted average model age of 261.7 ± 1.5 Ma with a MSWD of 0.55, indicating that the time of mineralization was at ca. 262 Ma. High precision U-Pb dating for the studied granites yields Permian 206Pb/238U ages ranging from 271 to 269 Ma. These age data confirm that both the intrusion and related mineralization were initiated in Early Permian period. These granites are strongly peraluminous with A/CNK = 1.11-1.12, high SiO2-K2O contents, as well as containing biotite and muscovite, indicating a petrogenesis of typical S-type granites, the above consideration is also consistent with the result of discrimination diagrams. The Re contents of molybdenite, εNd(t), and zircon εHf(t), as well as the 176Hf/177Hf values of the granites, fall into the ranges from 1.153 to 2.740 μg/g, - 11.1 to - 9.3, - 8.8 to - 0.9, and 0.282358 to 0.282688, respectively. All of this evidence suggests that the metals were derived from a predominantly crustal source, the granites originated from crust in an extensional setting, and the rejuvenation of the continent may have play an important role during the ore-forming processes of the Early Permian epoch.

Surface characterization, in vitro and in vivo biocompatibility of Mg-0.3Sr-0.3Ca for temporary cardiovascular implant

Energy Technology Data Exchange (ETDEWEB)

Bornapour, M., E-mail: mandana.bornapour@mail.mcgill.ca [Light Metals and Advanced Magnesium Materials, Mining and Materials Engineering, McGill University, Montreal, Qc, H3A 0C5 (Canada); Biointerface Lab, Mining and Materials Engineering, McGill University, Montreal, Qc H3A 0C5 (Canada); Mahjoubi, H. [Biointerface Lab, Mining and Materials Engineering, McGill University, Montreal, Qc H3A 0C5 (Canada); Vali, H. [Department of Anatomy and Cell Biology, McGill University, Montreal, Qc, H3A 0C7 (Canada); Shum-Tim, D. [Department of Cardiac Surgery and Surgical Research, McGill University, Montreal, Qc H3G 1A1 (Canada); Cerruti, M. [Biointerface Lab, Mining and Materials Engineering, McGill University, Montreal, Qc H3A 0C5 (Canada); Pekguleryuz, M. [Light Metals and Advanced Magnesium Materials, Mining and Materials Engineering, McGill University, Montreal, Qc, H3A 0C5 (Canada)

2016-10-01

Magnesium-based alloys are attractive candidate materials for medical applications. Our earlier work showed that the ternary Mg-0.3Sr-0.3Ca alloy exhibits slower degradation rates than both binary Mg-Sr and Mg-Ca alloys. The ternary alloy immersed in simulated body fluid (SBF) forms a compact surface layer of corrosion products that we hypothesized to be a Sr-substituted hydroxyapatite (HA). The main objectives of the current work are to understand the bio-degradation mechanism of Mg-0.3Sr-0.3Ca, to identify the exact nature of its protective layer and to evaluate the in vitro and in vivo biocompatibility of the alloy for cardiovascular applications. To better simulate the physiological environment, the alloy was immersed in SBF which was daily refreshed. Raman spectroscopy and X-Ray photoelectron spectroscopy (XPS) confirmed the formation of a thin, Sr-substituted HA layer at the interface between the alloy and the corrosion products. In vitro biocompatibility evaluated via indirect cytotoxicity assays using HUVECs showed no toxicity effect and ions extracted from Mg-0.3Sr-0.3Ca in fact increased the viability of HUVECs after one week. In vivo tests were performed by implanting a tubular Mg-0.3Sr-0.3Ca stent along with a WE43 control stent into the right and left femoral artery of a dog. Post implantation and histological analyses showed no thrombosis in the artery with Mg-0.3Sr-0.3Ca stent after 5 weeks of implantation while the artery implanted with WE43 stent was extensively occluded and thrombosed. Microscopic observation of the Mg-0.3Sr-0.3Ca implant-tissue interface confirmed the in situ formation of Sr-substituted HA on the surface during in vivo test. These results show that the interfacial layer protects the surface of the Mg-0.3Sr-0.3Ca alloy both in vitro and in vivo, and is the key factor in the bio-corrosion resistance of the alloy. - Highlights: • The surface active elements of Sr and Ca alter the corrosion of Mg alloy in SBF • Sr

Surface characterization, in vitro and in vivo biocompatibility of Mg-0.3Sr-0.3Ca for temporary cardiovascular implant

International Nuclear Information System (INIS)

Bornapour, M.; Mahjoubi, H.; Vali, H.; Shum-Tim, D.; Cerruti, M.; Pekguleryuz, M.

2016-01-01

Magnesium-based alloys are attractive candidate materials for medical applications. Our earlier work showed that the ternary Mg-0.3Sr-0.3Ca alloy exhibits slower degradation rates than both binary Mg-Sr and Mg-Ca alloys. The ternary alloy immersed in simulated body fluid (SBF) forms a compact surface layer of corrosion products that we hypothesized to be a Sr-substituted hydroxyapatite (HA). The main objectives of the current work are to understand the bio-degradation mechanism of Mg-0.3Sr-0.3Ca, to identify the exact nature of its protective layer and to evaluate the in vitro and in vivo biocompatibility of the alloy for cardiovascular applications. To better simulate the physiological environment, the alloy was immersed in SBF which was daily refreshed. Raman spectroscopy and X-Ray photoelectron spectroscopy (XPS) confirmed the formation of a thin, Sr-substituted HA layer at the interface between the alloy and the corrosion products. In vitro biocompatibility evaluated via indirect cytotoxicity assays using HUVECs showed no toxicity effect and ions extracted from Mg-0.3Sr-0.3Ca in fact increased the viability of HUVECs after one week. In vivo tests were performed by implanting a tubular Mg-0.3Sr-0.3Ca stent along with a WE43 control stent into the right and left femoral artery of a dog. Post implantation and histological analyses showed no thrombosis in the artery with Mg-0.3Sr-0.3Ca stent after 5 weeks of implantation while the artery implanted with WE43 stent was extensively occluded and thrombosed. Microscopic observation of the Mg-0.3Sr-0.3Ca implant-tissue interface confirmed the in situ formation of Sr-substituted HA on the surface during in vivo test. These results show that the interfacial layer protects the surface of the Mg-0.3Sr-0.3Ca alloy both in vitro and in vivo, and is the key factor in the bio-corrosion resistance of the alloy. - Highlights: • The surface active elements of Sr and Ca alter the corrosion of Mg alloy in SBF • Sr

High spatial resolution U-Pb geochronology and Pb isotope geochemistry of magnetite-apatite ore from the Pea Ridge iron oxide-apatite deposit, St. Francois Mountains, southeast Missouri, USA

Science.gov (United States)

Neymark, Leonid; Holm-Denoma, Christopher S.; Pietruszka, Aaron; Aleinikoff, John N.; Fanning, C. Mark; Pillers, Renee M.; Moscati, Richard J.

2016-01-01

The Pea Ridge iron oxide-apatite (IOA) deposit is one of the major rhyolite-hosted magnetite deposits of the St. Francois Mountains terrane, which is located within the Mesoproterozoic (1.5–1.3 Ga) Granite-Rhyolite province in the U.S. Midcontinent. Precise and accurate determination of the timing and duration of oreforming processes in this deposit is crucial for understanding its origin and placing it within a deposit-scale and regional geologic context. Apatite and monazite, well-established U-Pb mineral geochronometers, are abundant in the Pea Ridge orebody. However, the potential presence of multiple generations of dateable minerals, processes of dissolution-reprecipitation, and occurrence of micrometer-sized intergrowths and inclusions complicate measurements and interpretations of the geochronological results. Here, we employ a combination of several techniques, including ID-TIMS and high spatial resolution geochronology of apatite and monazite using LA-SC-ICPMS and SHRIMP, and Pb isotope geochemistry of pyrite and magnetite to obtain the first direct age constraints on the formation and alteration history of the Pea Ridge IOA deposit. The oldest apatite TIMS 207Pb*/206Pb* dates are 1471 ± 1 and 1468 ± 1 Ma, slightly younger than (but within error of) the ~1474 to ~1473 Ma U-Pb zircon ages of the host rhyolites. Dating of apatite and monazite inclusions within apatite provides evidence for at least one younger metasomatic event at ~1.44 Ga, and possibly multiple superimposed metasomatic events between 1.47 and 1.44 Ga. Lead isotop analyses of pyrite show extremely radiogenic 206Pb/204Pb ratios up to ~80 unsupported by in situ U decay. This excess radiogenic Pb in pyrite may have been derived from the spatially associated apatite as apatite recrystallized several tens of million years after its formation. The low initial 206Pb/204Pb ratio of ~16.5 and 207Pb/204Pb ratio of ~15.4 for individual magnetite grains indicate closed U-Pb system behavior in

Hydrothermal titanite from the Chengchao iron skarn deposit: temporal constraints on iron mineralization, and its potential as a reference material for titanite U-Pb dating

Science.gov (United States)

Hu, Hao; Li, Jian-Wei; McFarlane, Christopher R. M.

2017-09-01

Uranium-lead isotopes and trace elements of titanite from the Chengchao iron skarn deposit (Daye district, Eastern China), located along the contact zones between Triassic marine carbonates and an early Cretaceous intrusive complex consisting of granite and quartz diorite, were analyzed using laser ablation inductively coupled plasma mass spectrometry to provide temporal constraints on iron mineralization and to evaluate its potential as a reference material for titanite U-Pb geochronology. Titanite grains from mineralized endoskarn have simple growth zoning patterns, exhibit intergrowth with magnetite, diopside, K-feldspar, albite and actinolite, and typically contain abundant primary two-phase fluid inclusions. These paragenetic and textural features suggest that these titanite grains are of hydrothermal origin. Hydrothermal titanite is distinct from the magmatic variety from the ore-related granitic intrusion in that it contains unusually high concentrations of U (up to 2995 ppm), low levels of Th (12.5-453 ppm), and virtually no common Pb. The REE concentrations are much lower, as are the Th/U and Lu/Hf ratios. The hydrothermal titanite grains yield reproducible uncorrected U-Pb ages ranging from 129.7 ± 0.7 to 132.1 ± 2.7 Ma (2σ), with a weighted mean of 131.2 ± 0.2 Ma [mean standard weighted deviation (MSWD) = 1.7] that is interpreted as the timing of iron skarn mineralization. This age closely corresponds to the zircon U-Pb age of 130.9 ± 0.7 Ma (MSWD = 0.7) determined for the quartz diorite, and the U-Pb ages for zircon and titanite (130.1 ± 1.0 Ma and 131.3 ± 0.3 Ma) in the granite, confirming a close temporal and likely genetic relationship between granitic magmatism and iron mineralization. Different hydrothermal titanite grains have virtually identical uncorrected U-Pb ratios suggestive of negligible common Pb in the mineral. The homogeneous textures and U-Pb characteristics of Chengchao hydrothermal titanite suggest that the mineral might be a

Evidence of early Archean crust in northwest Gondwana, from U-Pb and Hf isotope analysis of detrital zircon, in Ediacaran surpacrustal rocks of northern Spain

Science.gov (United States)

Naidoo, Thanusha; Zimmermann, Udo; Vervoort, Jeff; Tait, Jenny

2018-03-01

The Mora Formation (Narcea Group) is one of the oldest Precambrian supracrustal successions in northern Spain. Here, we use U-Pb and in situ Hf isotope analysis on detrital zircon to determine its age and provenance. The youngest U-Pb dates constrain the maximum depositional age of the Mora Formation at 565 ± 11 Ma. Results indicate: (1) a dominant Ediacaran zircon population (33%; 565-633 Ma, Cadomian) within a spectrum of Neoproterozoic ages (40%; 636-996 Ma); and (2) smaller Mesoproterozoic (5%; 1004-1240 Ma), Palaeoproterozoic (11%; 1890-2476 Ma) and Archean (11%; 2519-3550 Ma) populations. Results here do not point to one specific cratonic source area; instead, detritus may have been derived from the West African craton and Amazonia, or even the concealed Iberian basement. The lack of 1.3-1.8 Ga grains suggests exclusion of the Sahara Craton as a major source, but this is not certain. This mixed composition favours a complex source history with reworking of detritus across terrane/craton boundaries. Hafnium isotope compositions indicate a range of crustal and juvenile sources, with initial ɛHf values between -15.8 and 11.1, and Hf model ages from 0.8 to 3.7 Ga. For Neoproterozoic zircons (80%), juvenile components (ɛHf(i) +10) may be related to Rodinia fragmentation and the onset of an active margin setting leading to the Cadomian orogeny. Palaeoproterozoic to Paleoarchean grains (20%) all have negative ɛHf values and Meso- to Eoarchean Hf model ages. This indicates an early (Archean) sialic crustal component for northwestern Gondwana.

In situ deposition of thallium-containing oxides

International Nuclear Information System (INIS)

Myers, K.E.

1996-01-01

The number and variety of thallium based materials that can be made by in situ methods have grown consistently since the first report of successful thallium cuprate deposition by Face and Nestlerode in 1992. Processes for the deposition of superconductors, normal metals, and insulators have been developed. Most work to date has been done on the Tl-1212 phases, TlBa 2 CaCu 2 O 7 and (Tl,Pb)Sr 2 CaCu 2 O 7 . Recently however, the in situ thallium technique has been extended to other materials. For example, epitaxial thin films of thallium tantalate, an insulator of the pyrochlore structure and a potential buffer layer for thallium cuprate films, have been grown. Multilayers, important in the fabrication of Josephson junctions, have been demonstrated with the thallium lead cuprates. This paper reviews progress in the area of in situ thallium deposition technology which will make more complex thallium cuprate multilayer structures and devices possible

Geologic evolution of the Paraiba do Sul complex, in the central part of the Ribeira belt, based on the geochemistry and U-Pb geochronology studies

International Nuclear Information System (INIS)

Valladares, Claudia Sayao

1996-01-01

Aiming the definition of the Complexo Paraiba do Sul evolution, the work presents a geochronological approach by the U-Pb method, considered appropriate to study polideformed terrains. The minerals used to the U-Pb dating (zircon, titanite and monazite) provides information about the ages of rock generation and the successive geological events the rocks were submitted. The U-Pb geochronological approach is pioneer in the investigated area and two questions referent to the Complexo Paraiba do Sul evolution in the central part of the Ribeira belt, were the aim of this approach. The first of them refers to the crystallization epoch and the gneisses metamorphism, interpreted here like orthogneisses, called Unidade Quirino of the Complexo Paraiba do Sul. The second refers to the metamorphism ages and meta sedimentary unit deformation. Looking for the contribution to the Complexo Paraiba do Sul evolution understanding, this work presents the data based on the geologic map of this area, comprising part of the Folha Volta Redonda (1:50.000), including petrographic, structural and microtectonic studies. It also presents and discusses the results of: 17 U-Pb analysis in zircon and titanite of the Complexo Paraiba do Sul orthogneisses collection; 24 geochemical analysis of major, minor, trace elements and ETR of the same collection; an U-Pb analysis in titanite of the Unidade Sao Joao, 5 U-Pb analysis in titanites and/or monazites of granites and granitoids; 12 geochemical analysis including major, minor and trace elements and ETR, in granites and sills of leucogranites. Finally, the data achieved were integrated with the objective to elaborate an evolutive view of the Complexo Paraiba do Sul

Isotope geochronology study of the Baiyigou group in west Qinling

International Nuclear Information System (INIS)

Yang Junlong; Dong Yibao; Yuan Haihua; Mao Yunian; Min Yongming

1989-01-01

Rb-Sr isochron and U-Pb zircon dating shows that the Baiyigou Group in western Qinling belongs to Lower Sinian with an age 734+/-63 Ma. The underlying granophyre gravels carry an U-Pb zircon age 1008.9 Ma (Jinning Qrogeny). The overlying silicious rock, i.e. the lower part of the Taiyangding Formation has Rb-Sr isochron age 535+/- 11 Ma. Lithologic characteristics of the Paiyigou Group voleano-sedimentary rock suite are well comparable with the Wusidaqiao Group in West Sichan, both belonging to products of incipient continental rifting environment. An apparent Early Devonian (400 Ma+/-) tectono-magmatic and metamorphic event was the firstly discovered in this area

Archean evolution of Enderby Land (Antarctica) and isotope-geochronological evidences for its ancient history

International Nuclear Information System (INIS)

Krylov, D.P.; Belyatskij, B.V.

1987-01-01

Revew of published isotope-geochronological data on Ender by Land (Antarctica), which is the region of highly metamorphic formations predominant development which includes ancient rock relicts, is presented. Three tectonic-thermal events present the Archeau evolution in the region. Correlation of isotope-geochronological (U-Pb, Rb-Sr, Sm-Nd) data with micro textural processing allows to estimate tectonic-thermal events age: 3000-3100 about 2900 and about 2500 million years. Metamorphism of 3000-3100 million years age has essentially modified all the isotope systems, while model calculations for evolution of U-Pb, Rb-Sr, Sm-Nd systems have shown that rocks primary formation accurred 3500-3900 million years ago

In situ study of radionuclide diffusion into clays with specific device: Autolab probe

International Nuclear Information System (INIS)

Porcheron, J.

1993-01-01

The aim of this shared cost contract between the French Atomic Energy Commissariat, Nuclear Safety and Protection Institute and the Commission of the European Communities was to build and use an experimental drilling probe, the AUTOLAB prob, which was designed to measure the diffusion into clay of radioactive pollutants originating from a high activity waste storage. The measurement was carried out in-situ during drilling. The probe is equipped a new operating mode which involves using the pressure of the drilling water as its source of energy. The probe is autonomous and can stay in the bore hole for an extensive period of time without requiring any monitoring and without introducing any pollution. The diffusion experiment was carried out in a bore-hole at the JRC in ISPRA (ITALY). Two diffusion experiments were carried out in identical conditions (clay, 85Sr tracer, water samples), one in Laboratory, (ISPRA JRC Radiochemistry Laboratory, ITALY), and the other in-situ. The results displayed that 85Sr diffusion was considerably faster in the in-situ experiment than in that conducted in Laboratory. The explanation for this phenomenon, which could be due to the balance of carbonates, has not yet been clearly established. This test shows the value of comparing laboratory tests with in-situ tests conducted accurately using well adapted equipment. 9 refs., 10 figs

Provenance analysis of the Late Triassic Yichuan Basin: constraints from zircon U-Pb geochronology

Directory of Open Access Journals (Sweden)

Meng Xianghong

2018-03-01

Full Text Available Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS U-Pb dating has been performed on detrital zircons from the Chunshuyao Formation sandstone of Yichuan Basin. The ages of 85 detrital zircon grains are divided into three groups: 252-290 Ma, 1740-2000 Ma, and 2400-2600 Ma. The lack of Early Paleozoic and Neoproterozoic U-Pb ages indicates that there is no input from the Qinling Orogen, because the Qinling Orogen is characterized by Paleozoic and Neoproterozoic material. In combination with previous research, we suggest that the source of the Chunshuyao Formation is most likely recycled from previous sedimentary rocks from the North China Craton. In the Late Triassic, the Funiu ancient land was uplifted which prevented source material from the Qinling Orogen. Owing to the Indosinian orogeny, the strata to the east of the North China Craton were uplifted and eroded. The Yichuan Basin received detrital material from the North China Craton.

Late cenozoic magmatism in the South Patagonian batholith: SHRIMP U-Pb zircon age evidence

International Nuclear Information System (INIS)

Fanning, C.M; Herve, F; Pankhurst, R.J; Thomson, S; Faundez, V

2001-01-01

The North Patagonian Batholith (NPB) has a zonal age pattern which includes a well defined belt of Miocene and Mio-Pliocene plutons in its central portion (Pankhurst et al., 1999) which are spatially, and probably genetically related to the Liquine-Ofqui Fault Zone. Previous geochronological studies in the Southern Patagonian Batholith (SPB), as summarized by Bruce et al. (1991), have yielded 9 late Cenozoic K-Ar or Ar-Ar ages out of a total of 116 age determinations. None of these young ages correspond to U-Pb determinations on zircons, and some of the young ages correspond to satellite plutons east of the SPB proper, such as the Torres del Paine intrusion. In this paper we present the first late Cenozoic SHRIMP U-Pb zircon ages in the area of the SPB. The morphology of the analysed zircon crystals is described and leads to some inferences on the methodology and on the geological interpretation of the obtained ages (au)

Integrated Laser Ablation U/Pb and (U-Th)/He Dating of Detrital Accessory Minerals from the Naryani River, Central Nepal

Science.gov (United States)

Horne, A.; Hodges, K. V.; Van Soest, M. C.

2015-12-01

The newly developed 'laser ablation double dating' (LADD) technique, an integrated laser microprobe U/Pb and (U-Th)/He dating method, could be an exceptionally valuable tool in detrital thermochronology for identifying sedimentary provenance and evaluating the exhumation history of a source region. A recent proof-of-concept study has used LADD to successfully date both zircon and titanite crystals from the well-characterized Fish Canyon tuff, but we also believe that another accessory mineral, rutile, could be amenable to dating via the LADD technique. To continue the development of the method, we present an application of LADD to detrital zircon, titanite, and rutile from a sample collected on the lower Naryani River of central Nepal. Preliminary analyses of the sample have yielded zircon U/Pb dates ranging from 31.4 to 2405 Ma; zircon (U-Th)/He from 1.8 to 15.4 Ma; titanite U/Pb between 18 and 110 Ma; titanite (U-Th)/He between 1 and 16 Ma; rutile U/Pb from 6 to 45 Ma; and rutile (U-Th)/He from 2 to 25 Ma. In addition to the initial data, we can use Ti-in-zircon, Zr-in-titanite, and Zr-in-rutile thermometers to determine the range of possible long-term cooling rates from grains with U/Pb ages younger than collision. Thus far our results from zircon analyses imply a cooling rate of approximately 15°C/Myr; titanite analyses imply between 10 and 67°C/Myr; and rutile between 9 and 267°C/Myr. This spread in potential cooling rates, especially in the order of magnitude differences of cooling rates calculated from the rutile grains, suggests that the hinterland source regions of the Naryani river experienced dramatically different exhumation histories during Himalayan orogenisis. Ongoing analyses will expand the dataset such that we can more adequately characterize the range of possibilities represented in the sample.

A 615 m.y. age of the Bleida granodiorite, and its implications to the chronology of Panafrican tectonic, metamorphic and magmatic phases in the Moroccan Anti-Atlas

International Nuclear Information System (INIS)

Ducrot, Jean

1979-01-01

A 615+-12 m.y. age is obtained by U-Pb method on zircons extracted from the granodiorite of Bleida (Anti-Atlas, Morocco). This age which is in good agreement with U-Pb and Rb-Sr previous data, argues for the occurrence of the panafrican orogeny in the Anti-Atlas and contributes to define the chronology of the typical features of this orogenic belt [fr

SR-Can. Data and uncertainty assessment. Matrix diffusivity and porosity in situ

International Nuclear Information System (INIS)

Jinsong Liu; Loefgren, Martin; Neretnieks, Ivars

2006-12-01

and show beyond doubt that the electrical conductivity method using AC gives the expected information on transport properties (diffusivities) of the pores of crystalline rocks. The electrical conductivity method is much faster and can be used to measure large samples. It has recently been adopted for use in deep boreholes. Tens of thousands of measurements have been made at Simpevarp, Laxemar and Forsmark (Swedish sites) at depths of more than 1,000 m. The results of these measurements form the basis for our proposed diffusion values to be used in Performance Assessment (PA) for the candidate sites (Performance Assessment (PA) used in this report is synonymous to Safety Assessment (SA) sometimes used by other authors). The in situ data are obtained essentially in undisturbed rock and have not been subject to either stress release or disturbances due to sample preparation. The small disturbance nearest the borehole is negligible because the electrical conductivity method samples rock extending to more than a metre from the borehole. A large number of laboratory measurements have been analysed in order to ensure that other effects that cannot be controlled in the in situ measurements do not influence the down-hole data. No unexpected effects have been found. Rock matrix porosity in situ measurements are extremely scarce. However, it has been possible to use some of the in situ measurements to estimate the increase in porosity when taking up rock from its natural environment to the laboratory. One example of such an investigation is briefly discussed to show how this was done. In one in situ diffusion experiment performed at a depth of 60 m in granitic rock in Sweden the experimental conditions were such that it was ensured that any rock stress changes due to the presence of the drift and the presence of the borehole were avoided. The rock was thus subject to 'virgin stress'. Over-coring after exposure to tracers for three and a half years and detailed sampling and

SR-Can. Data and uncertainty assessment. Matrix diffusivity and porosity in situ

Energy Technology Data Exchange (ETDEWEB)

Jinsong Liu; Loefgren, Martin; Neretnieks, Ivars [Dept. of Chemical Engineering and Technology, Royal Inst. of Technology, Stockholm (Sweden)

2006-12-15

and show beyond doubt that the electrical conductivity method using AC gives the expected information on transport properties (diffusivities) of the pores of crystalline rocks. The electrical conductivity method is much faster and can be used to measure large samples. It has recently been adopted for use in deep boreholes. Tens of thousands of measurements have been made at Simpevarp, Laxemar and Forsmark (Swedish sites) at depths of more than 1,000 m. The results of these measurements form the basis for our proposed diffusion values to be used in Performance Assessment (PA) for the candidate sites (Performance Assessment (PA) used in this report is synonymous to Safety Assessment (SA) sometimes used by other authors). The in situ data are obtained essentially in undisturbed rock and have not been subject to either stress release or disturbances due to sample preparation. The small disturbance nearest the borehole is negligible because the electrical conductivity method samples rock extending to more than a metre from the borehole. A large number of laboratory measurements have been analysed in order to ensure that other effects that cannot be controlled in the in situ measurements do not influence the down-hole data. No unexpected effects have been found. Rock matrix porosity in situ measurements are extremely scarce. However, it has been possible to use some of the in situ measurements to estimate the increase in porosity when taking up rock from its natural environment to the laboratory. One example of such an investigation is briefly discussed to show how this was done. In one in situ diffusion experiment performed at a depth of 60 m in granitic rock in Sweden the experimental conditions were such that it was ensured that any rock stress changes due to the presence of the drift and the presence of the borehole were avoided. The rock was thus subject to 'virgin stress'. Over-coring after exposure to tracers for three and a half years and detailed sampling

New Sm/Nd and U/Pb geochronological constraints of the Archean to neoproterozoic evolution of the Amparo basement complex of the Central Ribeira Belt, Southeastern Brazil

International Nuclear Information System (INIS)

Fetter, A.H.; Hackspacher, P.C.; Ebbert, H.D; Dantas, E.L; Costa, A.C.D. da

2001-01-01

The Amparo Basement Complex is a distinctive collage of migmatitic tronjhemitetonalite- granodiorite (TTG) orthogneisses that represents the older basement exposures within the Central Ribeira Belt, a Late Neoproterozoic (ca. 600 Ma) collisional belt in southeastern Brazil. These basement gneisses are overlain by Mesoproterozoic to Neoproterozoic supracrustal sequences, and intruded by Neoproterozoic collisional granitoids. Pioneering Rb/Sr, Pb/Pb and K/Ar geochronological studies of the Amparo Complex, e.g. (Wernick et al., 1981; Wernick and Oliveira, 1986; Arthur, 1988; Tassinari, 1988; Campos Neto, 1991) provided some initial insights into the antiquity and geologic evolution of the complex, but little about the crustal evolution of the constituent gneisses. Furthermore, the susceptibility of these systems to partial isotopic resetting, left some doubt about the timing and true number of geologic events recorded by these polydeformed rocks. Recent Sm/Nd whole rock (Dantas et al., 2000) and new U/Pb single crystal zircon and monazite data obtained from the Amparo Complex, however, now furnish information on the crustal growth history of the basement and provide precise age constraints on the timing of events related to the geologic evolution of the complex. Based on these new data, it appears that the oldest rocks within the complex are polymigmatized tronjhemitic gneisses located near the town of Amparo. The oldest phase of this migmatite yields a U/Pb zircon age of 3,024 +/- 9 Ma. Sm/Nd data from this locale yields a Nd T(DM) model age of 3.28 Ga suggesting that the genesis of this crustal unit involved some input from yet older crust. Data from banded tonalitic gneisses collected ca. 50 km south of Amparo indicate that subsequent Archean crustal growth around the older core occurred around 2.77 Ga (U/Pb zircon age of 2,772 +/- 26 Ma. A Nd T(DM) model age of 3.02 Ga obtained from these tonalites also indicate enrichment from older crustal sources during their

Metastable honeycomb SrTiO_3/SrIrO_3 heterostructures

International Nuclear Information System (INIS)

Anderson, T. J.; Ryu, S.; Podkaminer, J. P.; Ma, Y.; Eom, C. B.; Zhou, H.; Xie, L.; Irwin, J.; Rzchowski, M. S.; Pan, X. Q.

2016-01-01

Recent theory predictions of exotic band topologies in (111) honeycomb perovskite SrIrO_3 layers sandwiched between SrTiO_3 have garnered much attention in the condensed matter physics and materials communities. However, perovskite SrIrO_3 film growth in the (111) direction remains unreported, as efforts to synthesize pure SrIrO_3 on (111) perovskite substrates have yielded films with monoclinic symmetry rather than the perovskite structure required by theory predictions. In this study, we report the synthesis of ultra-thin metastable perovskite SrIrO_3 films capped with SrTiO_3 grown on (111) SrTiO_3 substrates by pulsed laser deposition. The atomic structure of the ultra-thin films was examined with scanning transmission electron microscopy (STEM), which suggests a perovskite layering distinct from the bulk SrIrO_3 monoclinic phase. In-plane 3-fold symmetry for the entire heterostructure was confirmed using synchrotron surface X-ray diffraction to measure symmetry equivalent crystal truncation rods. Our findings demonstrate the ability to stabilize (111) honeycomb perovskite SrIrO_3, which provides an experimental avenue to probe the phenomena predicted for this material system.

Geochronological, geochemical and geothermal constraints on petrogenesis of the Indosinian peraluminous granites in the South China Block: A case study in the Hunan Province

Science.gov (United States)

Wang, Yuejun; Fan, Weiming; Sun, Min; Liang, Xinquan; Zhang, Yanhua; Peng, Touping

2007-07-01

The Indosinian granites in the South China Block (SCB) have important tectonic significance for the evolution of East Asia. Samples collected from Hunan Province can be geochemically classified into two groups. Group 1 is strongly peraluminous (A/CNK > 1.1), similar to S-type granites, and Group 2 has A/CNK = 1.0-1.1, with an affinity to I-type granites. Group 1 has lower FeOt, Al 2O 3, MgO, CaO, TiO 2 and ɛNd( t) values but higher K 2O + Na 2O, Rb/Sr, Rb/Ba and 87Sr/ 86Sr( t) than those of Group 2. Samples of both groups have similar LREE enriched pattern, with (Eu/Eu *) = 0.19-0.69, and strongly negative Ba, Sr, Nb, P and Ti anomalies. Geothermobarometry study indicates that the precursor magmas were emplaced at high-level depth with relatively low temperature (734-827 °C). Geochemical data suggest that Group 1 was originated from a source dominated by pelitic composition and Group 2 was from a mixing source of pelitic and basaltic rocks with insignificant addition of newly mantle-derived magma. Eight granitic samples in Hunan Province are dated at the cluster of 243-235 and 218-210 Ma by zircon U-Pb geochronology. Together with recent zircon U-Pb ages for other areas in the SCB, two age-clusters, including 243-228 Ma just after peak-metamorphism (˜ 246-252 Ma) and 220-206 Ma shortly after magma underplating event (˜224 Ma), are observed. It is proposed that in-situ radiogenic heating from the over-thickened crust induced dehydrated reaction of muscovite and epidote/zoisite to form the early Indosinian granites in response to the isostatic readjustments of tectonically thickened crust. Conductive heating from the underplating magma in the postcollisional setting triggered the formation of late Indosinian granites. Such a consideration is supported by the results from FLAC numerical simulation.

Petrogenesis of Early Cretaceous granitoids from southwest Zhejiang, NE South China Block and its geodynamic implication

Science.gov (United States)

Pan, Fa-Bin; Liu, Rong; Jin, Chong; Jia, Bao-Jian; He, Xiaobo; Gao, Zhong; Tao, Lu; Zhou, Xiao-Chun; Zhang, Li-Qi

2018-05-01

In situ zircon U-Pb ages, whole-rock major and trace elements, and Sr-Nd isotopic compositions of the Sucun, Yunfeng, and Jingning intrusions from southwest Zhejiang, NE South China Block, are presented to trace their petrogenesis and shed light on its lithosphere evolution. LA-ICP-MS U-Pb zircon dating shows that the Sucun quartz monzonite and Jingning monzogranite were emplaced at 135 Ma, and the Yunfeng quartz monzonite and Jingning granite were emplaced at 104 and 112 Ma, respectively. All these intrusions are metaluminous to weakly peraluminous and lie within high-K calc-alkaline to shoshonite series field (SiO2 = 66-76 wt%, A/CNK = 0.95-1.09, K2O/Na2O = 0.78-1.77). The Yunfeng quartz monzonite clearly have lower K2O and total REE contents, and higher CaO, Na2O, Al2O3, P2O5, MgO, and TiO2 contents, and relatively less enriched Sr-Nd isotopic compositions than those of the Sucun quartz monzonite, indicating that the Yunfeng quartz monzonite were derived from partial melting of a more juvenile lower crust sources compared with the magma source of the Sucun quartz monzonite. The Jingning monzogranite exhibit similar major elements covariations and Nd isotopic compositions, but higher Ba, Sr, and Eu contents and lower Rb, Th, and U contents than those of the Jingning granite. The geochemical features imply that the Jingning monzogranite and granite were fluid-present and fluid-absent anatexis products of the same Paleoproterozoic crustal source, respectively. Whole-rock Sr-Nd isotopic data imply that the estimated amounts of juvenile mantle-derived melts input into the mature crust show southeastward decreasing trend away from the Jiangshan-Shaoxing fault. We propose that roll-back and retreat of the Paleo-Pacific subducting plate might cause extensive asthenosphere mantle upwelling in East China, and the mantle-derived melts tend to rise through the regional main fault zones and preferentially modify the lithosphere nearby these faults.

Experiences with the determination of Sr-89 and Sr-90 using fast methods; Erfahrungen bei der Bestimmung von {sup 89}Sr und {sup 90}Sr mittels Schnellmethoden

Energy Technology Data Exchange (ETDEWEB)

Kowalik, C.; Fueger, J. [Thueringer Landesanstalt fuer Umwelt und Geologie, Jena (Germany). Landesmessstelle fuer Umweltradioaktivaet

2014-01-20

Quick methods of the measurement of {sup 89}Sr and {sup 90}Sr have a great importance in the supervision of the environmental radioactivity. It is necessary to receive in short time dependable analytical data to be able to carry out suitable assessments or to give recommendations. The aim of the investigations was to be guaranteed the demands for these methods (test preparation, measurement and evaluation). The use of the solid phase extraction by means of commercial Sr Resin trademark columns (4.4' (5')-Di-tert-butylcyclohexanol-18-kronen-6-aether) (Triskem) to the radiochemical separation of the Sr isotopes was suitable. The measurements occurred to the FHT 770 T12 - Multi Low Level Alpha/Beta Sample Counter (Thermo Scientific). The results contain the summary activities of all available Sr isotopes, as for example {sup 89}Sr and {sup 90}Sr. The calculations of the single activities occur about the mathematical algorithm of the linear development on the basis of the works of G. Kanisch. The first results show, this method is suitable for the analysis of {sup 89}Sr and {sup 90}Sr and is used therefore in future in Thuringia.

A flow cell for transient voltammetry and in situ grazing incidence X-ray diffraction characterization of electrocrystallized cadmium(II) tetracyanoquinodimethane

Energy Technology Data Exchange (ETDEWEB)

Veder, Jean-Pierre [Nanochemistry Research Institute, Department of Chemistry, Curtin University, GPO Box U1987, Perth, Western Australia 6845 (Australia); Nafady, Ayman [School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia); Clarke, Graeme [Nanochemistry Research Institute, Department of Chemistry, Curtin University, GPO Box U1987, Perth, Western Australia 6845 (Australia); Williams, Ross P. [Centre for Materials Research, Department of Imaging and Applied Physics, Curtin University, GPO Box U1987, Perth, Western Australia 6845 (Australia); De Marco, Roland, E-mail: r.demarco@curtin.edu.a [Nanochemistry Research Institute, Department of Chemistry, Curtin University, GPO Box U1987, Perth, Western Australia 6845 (Australia); Bond, Alan M. [School of Chemistry, Monash University, Clayton, Victoria 3800 (Australia)

2011-01-01

An easy to fabricate and versatile cell that can be used with a variety of electrochemical techniques, also meeting the stringent requirement for undertaking cyclic voltammetry under transient conditions in in situ electrocrystallization studies and total external reflection X-ray analysis, has been developed. Application is demonstrated through an in situ synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) characterization of electrocrystallized cadmium (II)-tetracyanoquinodimethane material, Cd(TCNQ){sub 2}, from acetonitrile (0.1 mol dm{sup -3} [NBu{sub 4}][PF{sub 6}]). Importantly, this versatile cell design makes SR-GIXRD suitable for almost any combination of total external reflection X-ray analysis (e.g., GIXRF and GIXRD) and electrochemical perturbation, also allowing its application in acidic, basic, aqueous, non-aqueous, low and high flow pressure conditions. Nevertheless, the cell design separates the functions of transient voltammetry and SR-GIXRD measurements, viz., voltammetry is performed at high flow rates with a substantially distended window to minimize the IR (Ohmic) drop of the electrolyte, while SR-GIXRD is undertaken using stop-flow conditions with a very thin layer of electrolyte to minimize X-ray absorption and scattering by the solution.

An Early Permian epithermal gold system in the Tulasu Basin in North Xinjiang, NW China: Constraints from in situ oxygen-sulfur isotopes and geochronology

Science.gov (United States)

Dong, Leilei; Wan, Bo; Deng, Chen; Cai, Keda; Xiao, Wenjiao

2018-03-01

The Axi and Jingxi-Yelmand gold deposits, being the largest gold deposits in the Chinese North Tianshan, NW China, are located ca. l0 km apart in the Tulasu Basin, and are hosted by the Late Devonian - Early Carboniferous Dahalajunshan Formation. In situ LA-ICP-MS titanium analyses on quartz from the Axi and Jingxi-Yelmand deposits are broadly identical. Accordingly, the calculated ore-forming temperatures by Ti-in-quartz thermometer give average temperatures of 279 °C and 294 °C, respectively. Results of in situ SIMS analyses of oxygen and sulfur isotopes on quartz and pyrite from these two deposits are similar. Temperature-corrected fluids of the Axi deposit have δ18O values of 2.6-8.1‰ and δ34S values of 0.8-2.4‰, whereas the fluids of the Jingxi-Yelmand deposit have δ18O of 6.4-8.9‰ and δ34S of -0.4 to 4.0‰. The oxygen and sulfur isotopes from the two deposits indicate a magmatic origin. LA-ICP-MS zircon U-Pb ages of Aqialehe Formation sandstone provided a lower limit for the mineralization timing of the Axi deposit (288 Ma). In situ SIMS U-Pb analyses on entrapped zircon (297 Ma) and newly recognized 284.5 Ma columnar rhyolite implies that the Jingxi-Yelmand deposit formed in the Early Permian. Based on the magmatic affinity of the ore fluids, similar age and ore-formation temperatures, we propose that the Axi and Jingxi-Yelmand deposits comprise an epithermal gold system, which was driven by the same Permian magma in the Tulasu Basin. The ore geological features together with our new results indicate that the Axi and Jingxi-Yelmand deposits are intermediate and high sulfidation type epithermal deposits, respectively.

Reactive molecular beam epitaxial growth and in situ photoemission spectroscopy study of iridate superlattices

Directory of Open Access Journals (Sweden)

C. C. Fan

2017-08-01

Full Text Available High-quality (001-oriented perovskite [(SrIrO3m/(SrTiO3] superlattices (m=1/2, 1, 2, 3 and ∞ films have been grown on SrTiO3(001 epitaxially using reactive molecular beam epitaxy. Compared to previously reported superlattices synthesized by pulsed laser deposition, our superlattices exhibit superior crystalline, interface and surface structure, which have been confirmed by high-resolution X-ray diffraction, scanning transmission electron microscopy and atomic force microscopy, respectively. The transport measurements confirm a novel insulator-metal transition with the change of dimensionality in these superlattices, and our first systematic in situ photoemission spectroscopy study indicates that the increasing strength of effective correlations induced by reducing dimensionality would be the dominating origin of this transition.

U-Pb detrital zircon geochronology from the basement of the Central Qilian Terrane: implications for tectonic evolution of northeastern Tibetan Plateau

Science.gov (United States)

Liu, Changfeng; Wu, Chen; Zhou, Zhiguang; Yan, Zhu; Jiang, Tian; Song, Zhijie; Liu, Wencan; Yang, Xin; Zhang, Hongyuan

2018-03-01

The Tuolai Group dominates the Central Qilian Terrane, and there are different opinions on the age and tectonic attribute of the Tuolai Group. Based on large-scale geologic mapping and zircon dating, the Tuolai Group is divided into four parts: metamorphic supracrustal rocks, Neoproterozoic acid intrusive rocks, early-middle Ordovician acid intrusive rocks and middle Ordovician basic intrusive rocks. The metamorphic supracrustal rocks are the redefined Tuolai complex-group and include gneiss and schist assemblage by faulting contact. Zircon U-Pb LA-MC-ICP-MS dating was conducted on these samples of gneiss and migmatite from the gneiss assemblage, quartzite, two-mica schist and slate from the schist assemblage. The five detrital samples possess similar age spectra; have detrital zircon U-Pb main peak ages of 1.7 Ga with youngest U-Pb ages of 1150 Ma. They are intruded by Neoproterozoic acid intrusive rocks. Therefore, the Tuolai Group belonging to late Mesoproterozoic and early Neoproterozoic. With this caveat in mind, we believe that U-Pb detrital zircon dating, together with the geologic constraints obtained from this study and early work in the neighboring regions. We suggest that the formation age of the entire crystalline basement rocks of metasedimentary sequence from the Central Qilian Terrane should be constrained between the Late Mesoproterozoic and the Late Neoproterozoic, but not the previous Paleoproterozoic. The basement of the Central Qilian Terrane contains the typical Grenville ages, which indicates the Centre Qilian Terrane have been experienced the Grenville orogeny event.

New data for paleoprotherozoic PGE-bearing anorthosite of Kandalaksha massif (Baltic shield): U-Pb and Sm-Nd ages

Science.gov (United States)

Steshenko, Ekaterina; Bayanova, Tamara; Serov, Pavel

2015-04-01

The aims of this researches were to study the isotope U-Pb age of zircon and rutile and Sm-Nd (rock forming and sulphide minerals) on Kandalaksha anorthosite massif due to study of polimetamorphic history. In marginal zone firstly have been obtained the presence of sulphide mineralization with PGE (Chashchin, Petrov , 2013). Kandalaksha massif is located in the N-E part of Baltic shield and consists of three parts. Marginal zone (mesocratic metanorite) lies at the base of the massif. Main zone is composed of leucocratic metagabbro. The upper zone is alteration of mataanorthosite and leucocratic metagabbro. All rocks were subjected to granulate polymetamorphism. Two fractions of single grains from anorthosite of the massif gave precise U-Pb age, which is equal to 2450± 3 Ma. Leucocratic gabbro-norite were dated by U-Pb method, with age up to 2230 ± 10 Ma. This age reflects the time of granulite metamorphism according to data of (Mitrofanov, Nirovich, 2003). Two fractions of rutile have been analyzed by U-Pb method and reflect age of 1700 ± 10 Ma. It is known that the closure temperature of U-Pb system rutile is 400-450 ° C (Mezger et.al., 1989), thus cooling processes of massif rocks to these temperatures was about 1.7 Ga. These data reflect one of the stages of metamorphic alteration of the massif. Three stages of metamorphism are distinguished by Sm-Nd method. Isotope Sm-Nd dating on Cpx-WR line gives the age of 2311 Ma which suggested of high pressure granulite metamorphism. Moreover Cpx-Pl line reflect the age 1908 Ma of low pressure granulite metamorphism. Also two-points (Grt-Rt) Sm-Nd isochrone yield the age 1687 Ma of the last metamorphic alterations in Kandalaksha anorthosite massif. Model Sm-Nd age of the leucocratic gabbro-norite is 2796 Ma with positive ɛNd (+0.32). It means that the source of gabbro-norite was mantle reservoir. All investigations are devoted to memory of academician PAS F. MItrofanov which was a leader of scientific school for

In situ examination of oxygen non-stoichiometry in La0.80Sr0.20CoO3−δ thin films at intermediate and low temperatures by x-ray diffraction

KAUST Repository

Biegalski, M. D.

2014-04-21

Structural evolution of epitaxial La0.80Sr 0.20CoO3-δ thin films under chemical and voltage stimuli was examined in situ using X-ray diffraction. The changes in lattice parameter (chemical expansivity) were used to quantify oxygen reduction reaction processes and vacancy concentration changes in lanthanum strontium cobaltite. At 550 °C, the observed lattice parameter reduction at an applied bias of -0.6 V was equivalent to that from the reducing condition of a 2% carbon monoxide atmosphere with an oxygen non-stoichiometry δ of 0.24. At lower temperatures (200 °C), the application of bias reduced the sample much more effectively than a carbon monoxide atmosphere and induced an oxygen non-stoichiometry δ of 0.47. Despite these large changes in oxygen concentration, the epitaxial thin film was completely re-oxidized and no signs of crystallinity loss or film amorphization were observed. This work demonstrates that the effects of oxygen evolution and reduction can be examined with applied bias at low temperatures, extending the ability to probe these processes with in-situ analytical techniques. © 2014 AIP Publishing LLC.

Rapid method for determining Sr-89 and Sr-90 using Cherenkov and proportional counting; Schnellmethode zur Bestimmung von SR-89 und SR-90 durch Cerenkov- und Proportionalzaehlermessungen

Energy Technology Data Exchange (ETDEWEB)

Lange, S.; Wende, C.; Schwokowski, R.; Alisch-Mark, M.; Abraham, A.; Heinrich, T. [Staatliche Betriebsgesellschaft fuer Umwelt und Landwirtschaft, Radebeul (Germany)

2016-07-01

A rapid method for determining Sr-89 and Sr-90 in water, milk and biological samples has been developed and tested. After sample preparation strontium is separated by extraction chromatography using Sr resin. Eluate is divided and transfered to LSC vial and filter paper by SrCO{sub 3} precipitation. A Hidex 300 SL TDCR liquid scintillation counter and Thermo Fisher low level proportional counter have been used. Chemical yield of Sr-85 tracer is determined by Gamma spectroscopy. Uncertainty budget, decision threshold and detection limit are calculated in accordance with GUM and ISO 11929.

U-Pb geochronology of zircons form lunar Breccia 73217 using a sensitive high mass-resolution ion microprobe

International Nuclear Information System (INIS)

Compston, W.; Williams, I.S.

1984-01-01

U-Pb age determinations on four lunar zircons from existing thin-sections of one highland breccia, 73217, using the recently constructed ion microprobe SHRIMP, are reported. The analytical reproducibility of SHRIMP is demonstrated, and procedures for measuring Pb/U, Th/U, and corecting for initial Pb are explained. Electron microprobe analyses for the zircons are also reported. The results show that the four zircons survived the lunar cataclysm without any identifiable effects on their U-Pb systematics. All four indicate a single age of 4356 +23 or -14 m.y. The zircons have experienced small variable amounts of Pb loss since crystallization, from almost zero up to about 10 percent. If this occurred during one later event, then age of the latter is between 1100 and 2300 m.y. 18 references

Stoichiometry control of SrVO{sub 3} thin films grown by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Scheiderer, Philipp; Schmitt, Matthias; Sing, Michael; Claessen, Ralph [Universitaet Wuerzburg, Physikalisches Institut and Roentgen Center for Complex Material Systems (RCCM), 97074 Wuerzburg (Germany)

2016-07-01

Oxide heterostructures exhibit fascinating properties, e.g., the coexistence of superconductivity and ferromagnetism at the interface of LaAlO{sub 3}/SrTiO{sub 3}, but the extraordinary electronic properties of transition metal oxides caused by electron correlation yet wait to be fully harnessed. One suitable candidate for future device applications is the correlated metal SrVO{sub 3}, which can be prepared by pulsed laser deposition (PLD) on commonly used substrates such as SrTiO{sub 3}. Sample fabrication by PLD offers a wide variety of possibilities to manipulate the structural and electronic properties of the grown films in a controlled way. Here we report on the manipulation of the cation and oxygen stoichiometry of SrVO{sub 3} thin films by tuning the laser flux density of the PLD-ablation process and the oxygen background pressure during growth, respectively. In situ photoemission, x-ray diffraction, and temperature dependent resistivity measurements enable us to monitor the structural and electronic changes: Cation off-stoichiometry causes a strong increase of the out-of-plane lattice constant as well as a lower residual resistivity ratio, while excess oxygen is found to induce a shift to higher vanadium valences. After exposure to air a similar shift is detected, indicating an overoxidation of the SrVO{sub 3} film.

Environmental 90Sr measurements

Science.gov (United States)

Paul, M.; Berkovits, D.; Cecil, L.D.; Feldstein, H.; Hershkowitz, A.; Kashiv, Y.; Vogt, S.

1997-01-01

90Sr (T1/2 = 28.5 years) is a long-lived radionuclide produced in nuclear fission. Fast radiochemical detection of 90Sr in environmental samples is not feasible using current analytical methods. Accelerator Mass Spectrometry (AMS) measurements of 90Sr were made with the Rehovot 14UD Pelletron accelerator at a terminal voltage of 11 or 12 MV using our standard detection system. Injection of hydride ions (SrH3-) was chosen owing to high beam intensity and low Coulomb explosion effects. 90Sr ions were identified and discriminated from isobaric 90Zr by measuring time of flight, total energy and three independent energy-loss signals in an ionization chamber. A reference sample and a ground-water sample were successfully measured. The detection limit determined for a laboratory blank by the residual counts in the 90Sr region is 90Sr/Sr = 3 ?? 10-13, corresponding in practice to (2-4) ?? 10790Sr atoms or about 0.5-1 pCi/L in environmental water samples.

Maxdose-SR and popdose-SR routine release atmospheric dose models used at SRS

Energy Technology Data Exchange (ETDEWEB)

Jannik, G. T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Trimor, P. P. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-07-28

MAXDOSE-SR and POPDOSE-SR are used to calculate dose to the offsite Reference Person and to the surrounding Savannah River Site (SRS) population respectively following routine releases of atmospheric radioactivity. These models are currently accessed through the Dose Model Version 2014 graphical user interface (GUI). MAXDOSE-SR and POPDOSE-SR are personal computer (PC) versions of MAXIGASP and POPGASP, which both resided on the SRS IBM Mainframe. These two codes follow U.S. Nuclear Regulatory Commission (USNRC) Regulatory Guides 1.109 and 1.111 (1977a, 1977b). The basis for MAXDOSE-SR and POPDOSE-SR are USNRC developed codes XOQDOQ (Sagendorf et. al 1982) and GASPAR (Eckerman et. al 1980). Both of these codes have previously been verified for use at SRS (Simpkins 1999 and 2000). The revisions incorporated into MAXDOSE-SR and POPDOSE-SR Version 2014 (hereafter referred to as MAXDOSE-SR and POPDOSE-SR unless otherwise noted) were made per Computer Program Modification Tracker (CPMT) number Q-CMT-A-00016 (Appendix D). Version 2014 was verified for use at SRS in Dixon (2014).

Neodymium-doped Sr5(PO4)3F and Sr5(VO4)3F

International Nuclear Information System (INIS)

Corker, D.L.; Nicholls, J.; Loutts, G.B.

1995-01-01

Neodymium-doped Sr 5 (PO 4 ) 3 F [neodymium strontium fluoride phosphate, (Nd,Sr) 5 (PO 4 ) 3 F] and neodymium-doped Sr 5 (VO 4 ) 3 F [neodymium strontium fluoride vanadate, (Nd,Sr) 5 (VO 4 ) 3 F] crystallize in space group P6 3 /m and are isostructural with calcium fluorophosphate, Ca 5 (PO 4 ) 3 F. There are two different Sr sites in Sr 5 (XO 4 ) 3 F, denoted Sr(1) and Sr(2). Using single-crystal X-ray diffraction the two structures were refined to R factors of 2.3 and 2.2%, respectively, showing that Nd is present at both Sr sites in (Sr,Nd) 5 (VO 4 ) 3 F but only at the Sr(2) site in (Sr,Nd) 5 (PO 4 ) 3 F. (orig.)

Is the Modern Marine 87Sr/86Sr Cycle Balanced?

Science.gov (United States)

Peucker-Ehrenbrink, B.

2017-12-01

The marine 87Sr/86Sr record is one of the best-reconstructed isotope records with thousands of high quality measurements spanning the past 800 million years. It records a global signal of tectonic, biotic and climatic processes on Earth. Yet despite decades of research we still do not know whether the current marine Sr budget is in steady state. Studies of the marine 88Sr/86Sr record indicate that sources and sinks do not balance. The magnitude and isotope composition of the terrestrial inputs are being debated, and the magnitude and temporal variability of unradiogenic contributions are not well constrained. Here I provide a revised assessment of all continental sources of Sr to the ocean, including river runoff, submarine groundwater discharge (Beck et al., 2013), dissolution of riverine suspended matter in seawater and dissolution of volcanic ash deposited on the ocean (Jones et al., 2012). I contrast continental sources of Sr with estimates of marine sources of Sr to seawater, specifically high- and low-temperature submarine hydrothermal fluids, as well as diffusive diagenetic fluxes. Best current data imply that unradiogenic submarine hydrothermal inputs to seawater are insufficient to balance the flux of radiogenic continental Sr. The revised assessment of riverine contributions is based on Sr data for almost 230 rivers, an increasing amount of time-series data for such rivers, as well as river discharge and sediment flux data for more than 2000 rivers. Regional sampling biases have been corrected with the aid of digital bedrock maps, specifically along the western margin of North America, East Africa and the large drainage region of Arabia, India and SE Asia. Significant uncertainty in the chemical and isotopic compositions of runoff from Greenland and East Africa remains. The main uncertainty in the budget, however, is related to the possibility that modern rivers do not represent the pre-anthropogenic (natural) state of continental runoff (e.g. Ganges

A new approach to assess the effects of Sr and Bi interaction in ADC12 Al–Si die casting alloy

International Nuclear Information System (INIS)

Farahany, Saeed; Ourdjini, Ali; Abu Bakar, Tuty Asma; Idris, Mohd Hasbullah

2014-01-01

Highlights: • Interactive effect between Bi and Sr has been invesitigated comprehensively. • Sequence of addition did not affect thermal and microscopical characteristics. • A new map has been established to assess the final microstructure of castings. - Abstract: In the present paper, the possible interaction between bismuth and strontium in ADC12 die casting alloy was investigated comprehensively by using in situ thermal analysis technique. The characteristic temperatures including nucleation, minimum and growth temperatures of eutectic Al–Si were also analyzed. The results show that with Bi present in the Al–Si alloy melt the efficiency of Sr in modifying the eutectic Si is reduced. A threshold Sr/Bi ratio of at least 0.5 is required for a fully modified Si structure to form. A new map based on the characteristic temperatures, Sr/Bi ratio and microstructure, was established to assess the microstructure of fully solidified Al–Si castings

A new approach to assess the effects of Sr and Bi interaction in ADC12 Al–Si die casting alloy

Energy Technology Data Exchange (ETDEWEB)

Farahany, Saeed, E-mail: saeedfarahany@gmail.com; Ourdjini, Ali; Abu Bakar, Tuty Asma; Idris, Mohd Hasbullah

2014-01-10

Highlights: • Interactive effect between Bi and Sr has been invesitigated comprehensively. • Sequence of addition did not affect thermal and microscopical characteristics. • A new map has been established to assess the final microstructure of castings. - Abstract: In the present paper, the possible interaction between bismuth and strontium in ADC12 die casting alloy was investigated comprehensively by using in situ thermal analysis technique. The characteristic temperatures including nucleation, minimum and growth temperatures of eutectic Al–Si were also analyzed. The results show that with Bi present in the Al–Si alloy melt the efficiency of Sr in modifying the eutectic Si is reduced. A threshold Sr/Bi ratio of at least 0.5 is required for a fully modified Si structure to form. A new map based on the characteristic temperatures, Sr/Bi ratio and microstructure, was established to assess the microstructure of fully solidified Al–Si castings.

Experimental autoabsorption curve 90Sr in SrCO3. Efficiency calculation to detection of 90Sr, 90Y and 90Sr + 90Y in a beta gas proportional counter

International Nuclear Information System (INIS)

Gasco, C.; Alvarez, A.

1987-01-01

Strontium-90 has been determined by radiochemical separation techniques in environmental samples. These techniques, of course, cannot separate the two strontium radionuclides from each other of from stable strontium. Consequently the end product of the chemical separation contains all strontium isotopes in SrCO 3 . The beta particules emitted by 90 Sr are absorbed by the SrCO 3 precipitate. This is the main source of error in the activity measurement. It has been prepared sources of 90 Sr in SrCO 3 in order to determinate the counting efficiency and autoabsorption curve. Also detection efficiencies have been calibrated using known activities of 90 Y and equilibrium mixture of 90 Sr+ 90 Y in the same geometry than our samples. The activity of 90 Sr by ingrowth of 90 Y has been calculated by our computer program. (author). 2 figs., 3 refs

Zircon U-Pb geochronology and emplacement history of intrusive rocks in the Ardestan section, central Iran

Energy Technology Data Exchange (ETDEWEB)

Sarjoughian, F.; Kananian, A.

2017-11-01

The Urumieh-Dokhtar Magmatic Arc (UDMA) is part of the Alpine–Himalayan orogenic belt and interpreted to be a subduction-related Andean-type magmatic arc. Along this belt, Eocene volcanics and some gabbroic to granitic bodies crop out. The main rock types of the studied intrusion are granite, granodiorite, and diorite. They have geochemical features typical of magnesian, calc-alkaline, metaluminous to slightly peraluminous granites and I-type intrusive rock that have a strong enrichment in Large-Ion Lithophile (LIL) elements (e.g. Rb, Ba, Sr), and a depletion in High Field Strength (HFS) elements (e.g. Nb, Ti, P), typical of subduction-related magmas. Zircon U-Pb dating was applied to determine the emplacement ages of the different intrusions in the Ardestan area. Among them the Kuh-e Dom diorite is 53.9±0.4Ma old; the Kuh-e Dom granodiorite is 51.10±0.4Ma old; the Mehrabad granodiorite is 36.8±0.5Ma old, the Nasrand granodiorite is 36.5±0.5Ma old, the Zafarghand granodiorite is 24.6±1.0Ma old, and the Feshark granodiorite is 20.5±0.8Ma old. These results delineate more accurately the magmatic evolution related to the Neotethyan subduction from the Lower Eocene to Lower Miocene, and the subsequent Zagros orogeny that resulted from the Arabia-Eurasia collision. The emplacement of these intrusive rocks inside the UDMA, which has a close relationship with the collisional orogeny, is transitional from a subduction-related setting to post-collisional setting in the Ardestan area.

Zircon U-Pb geochronology and emplacement history of intrusive rocks in the Ardestan section, central Iran

International Nuclear Information System (INIS)

Sarjoughian, F.; Kananian, A.

2017-01-01

The Urumieh-Dokhtar Magmatic Arc (UDMA) is part of the Alpine–Himalayan orogenic belt and interpreted to be a subduction-related Andean-type magmatic arc. Along this belt, Eocene volcanics and some gabbroic to granitic bodies crop out. The main rock types of the studied intrusion are granite, granodiorite, and diorite. They have geochemical features typical of magnesian, calc-alkaline, metaluminous to slightly peraluminous granites and I-type intrusive rock that have a strong enrichment in Large-Ion Lithophile (LIL) elements (e.g. Rb, Ba, Sr), and a depletion in High Field Strength (HFS) elements (e.g. Nb, Ti, P), typical of subduction-related magmas. Zircon U-Pb dating was applied to determine the emplacement ages of the different intrusions in the Ardestan area. Among them the Kuh-e Dom diorite is 53.9±0.4Ma old; the Kuh-e Dom granodiorite is 51.10±0.4Ma old; the Mehrabad granodiorite is 36.8±0.5Ma old, the Nasrand granodiorite is 36.5±0.5Ma old, the Zafarghand granodiorite is 24.6±1.0Ma old, and the Feshark granodiorite is 20.5±0.8Ma old. These results delineate more accurately the magmatic evolution related to the Neotethyan subduction from the Lower Eocene to Lower Miocene, and the subsequent Zagros orogeny that resulted from the Arabia-Eurasia collision. The emplacement of these intrusive rocks inside the UDMA, which has a close relationship with the collisional orogeny, is transitional from a subduction-related setting to post-collisional setting in the Ardestan area.

In situ migration experiment in argillaceous formation

International Nuclear Information System (INIS)

Yoshida, Hidekazu

1990-01-01

International cooperative R and D has been performed within the five years framework of the bilateral agreement between PNC (Power Reactor and Nuclear Fuel Development Corporation) and SCK/CEN (Studiecentrum voor Kernergie/Centre D'etude de L'energie Nucleaire, Mol, Belgium) which is focused on 'The Migration Experiment in argillaceous formation.' This Tertiary argillaceous formation, called Boom clay, is located at about 230m depth in Mol-Dessel area, Belgium. The argillaceous rock is considered to have a high capability for retardation to radionuclides when they migrate in geosphere because of a high content of clay minerals and dissolved carbon-rich pore water. The main purpose of this collaboration work is to characterize the migration phenomena in sedimentary rock through understanding of the behaviour of radionuclides migration in the argillaceous formation. The present report describes the preliminary results of in situ one-dimensional migration experiment with labelled clay core emplaced in borehole under advective condition. In the experiment, radioactive tracer Sr-85 and Eu-152+154 have been used in order to determine the apparent dispersion coefficient and retardation factor of Boom clay. Finally, the following conclusions were obtained by in situ measurement and calculation based on a appropriate migration model; a) From the Sr-85 experiment, diffusive behavior is interpreted to be a dominant phenomena on radionuclides transportation. b) From the Eu-152+154 experiment, very small non-retarded fraction is observed. (author)

U-Pb zircon age for a volcanic suite in the Rankin Inlet Group, Rankin Inlet map area, District of Keewatin, Northwest Territories

International Nuclear Information System (INIS)

Tella, S.; Roddick, J.C.; VanBreemen, O.

1996-01-01

U-Pb zircon analyses from a felsic band within dominantly mafic volcanics of the Rankin Inlet Group yields a U-Pb upper concordia intercept age of 2663 ± 3 Ma. These supracrustals at Rankin Inlet appear to be 15-20 Ma younger than volcanics of the Kaminak Group in the Tavani area, 70 km to the southwest. The 2.68-2.66 Ga volcanism in the Tavani and Rankin Inlet areas coincided with the last stage of the main phase of magmatism in the Slave Structural Province. (author). 16 refs., 1 tab., 3 figs

U-Pb zircon age for a volcanic suite in the Rankin Inlet Group, Rankin Inlet map area, District of Keewatin, Northwest Territories

Energy Technology Data Exchange (ETDEWEB)

Tella, S; Roddick, J C; VanBreemen, O [Geological Survey of Canada, Ottawa, ON (Canada)

1997-12-31

U-Pb zircon analyses from a felsic band within dominantly mafic volcanics of the Rankin Inlet Group yields a U-Pb upper concordia intercept age of 2663 {+-} 3 Ma. These supracrustals at Rankin Inlet appear to be 15-20 Ma younger than volcanics of the Kaminak Group in the Tavani area, 70 km to the southwest. The 2.68-2.66 Ga volcanism in the Tavani and Rankin Inlet areas coincided with the last stage of the main phase of magmatism in the Slave Structural Province. (author). 16 refs., 1 tab., 3 figs.

Microstructure of epitaxial SrRuO 3 thin films on MgO substrates

Science.gov (United States)

Ai, Wan Yong; Zhu, Jun; Zhang, Ying; Li, Yan Rong; Liu, Xing Zhao; Wei, Xian Hua; Li, Jin Long; Zheng, Liang; Qin, Wen Feng; Liang, Zhu

2006-09-01

SrRuO 3 thin films have been grown on singular (1 0 0) MgO substrates using pulsed laser deposition (PLD) in 30 Pa oxygen ambient and at a temperature of 400-700 °C. Ex situ reflection high-energy electron diffraction (RHEED) as well as X-ray diffraction (XRD) θ/2 θ scan indicated that the films deposited above 650 °C were well crystallized though they had a rough surface as shown by atom force microscopy (AFM). XRD Φ scans revealed that these films were composed of all three different types of orientation domains, which was further confirmed by the RHEED patterns. The heteroepitaxial relationship between SrRuO 3 and MgO was found to be [1 1 0] SRO//[1 0 0] MgO and 45°-rotated cube-on-cube [0 0 1] SRO//[1 0 0] MgO. These domain structures and surface morphology are similar to that of ever-reported SrRuO 3 thin films deposited on the (0 0 1) LaAlO 3 substrates, and different from those deposited on (0 0 1) SrTiO 3 substrates that have an atomically flat surface and are composed of only the [1 1 0]-type domains. The reason for this difference was ascribed to the effect of lattice mismatch across the film/substrate interface. The room temperature resistivity of SrRuO 3 films fabricated at 700 °C was 300 μΩ cm. Therefore, epitaxial SrRuO 3 films on MgO substrate could serve as a promising candidate of electrode materials for the fabrication of ferroelectric or dielectric films.

Thermal and exhumation history of Sakhalin Island (Russia) constrained by apatite U-Pb and fission track thermochronology

Science.gov (United States)

Glorie, Stijn; Alexandrov, Igor; Nixon, Angus; Jepson, Gilby; Gillespie, Jack; Jahn, Bor-Ming

2017-08-01

Sakhalin Island represents a key locality to study the tectonic evolution of the western Pacific. The island is located at the Amur-Okhotsk plate margin and records a complex thermotectonic history. Apatite double dating (U-Pb and fission track) and thermal history modelling were applied to three late Eocene granitoid massifs within central and southern Sakhalin: the Aniva, Okhotsk and Langeri complexes. Apatite U-Pb results yield consistent late Eocene (∼40-37 Ma) ages, suggesting rapid post-magmatic cooling. Apatite fission track results reveal bimodal age distributions with late Eocene - early Oligocene (∼38-33 Ma) and early Miocene (∼20-17 Ma) age populations that can be correlated with variations in Uranium and Chlorine concentrations. Thermal history modelling translates the AFT age bimodality into two-phase cooling histories. The timing of the early cooling phase (∼38-33 Ma) corresponds with the apatite U-Pb ages, indicating rapid cooling to at least ∼100 °C during the late Oligocene. The second cooling phase at ∼20-17 Ma cooled the samples to near-surface temperatures. Both cooling phases correspond with regional unconformities and subsequent accelerations in sedimentation rate, suggesting that cooling was a response to rapid exhumation. In addition, our data suggests that the studied terranes record differential exhumation with respect to the structural architecture. The Miocene exhumation pulse is coeval with the timing of transpressional fault displacement and the subsequent opening of the Kuril Basin.

U-Pb ages of detrital zircon from Pegasus Group, Stewart Island

International Nuclear Information System (INIS)

Walker, N.; Tulloch, A.J.; Allibone, A.

1998-01-01

Stewart Island (New Zealand) is relatively unaffected by Cenozoic deformation related to the present-day plate boundary and has thus been a locale of investigations that focus on the relationship between Mesozoic continental margin magmatic rocks and the Western Province (WP) of NZ. Pegasus Group metasedimentary rocks represent the only candidate for WP equivalents on Stewart Island. We measured U-Pb and 207 Pb / 206 Pb ages of detrital zircons from the Pegasus Group in an effort to validate the correlation with the WP. On SI, Pegasus Group is exposed over a small area in the southern Tin Range where it forms amphibolite facies roof pendants and screens among plutons of mid Paleozoic to mid Cretaceous age. Mica schists predominate, with lesser amounts of psammite and metaquartzite and rare calcareous schist and amphibolite. Zircons were extracted from metaquarzite and 24 grains were chosen on the basis of morphology for geochronologic investigation. Sixteen single crystals were dated by U-Pb TIMS; 8 additional grains were studied by the total evaporation method described by Kober. Despite vigorous air abrasion prior to processing, the 16 grains measured by conventional U-Pb TIMS yielded slightly normally discordant ages that we interpret to reflect minor Pb-loss. The 8 grains studied by the total evaporation method yielded more than four analytically identical /sup 207 Pb / 206 Pb ages within each grain at progressively higher temperatures (1515-1580 degrees C) of evaporation. The results permit the following general conclusions: 1) the age range of 420-2700 Ma is grossly similar to that reported from the Greenland Group/Victoria Paragneiss (Ireland 1992) of the Buller Terrane, WP; 2) the zircon population is dominantly 530-680 Ma but a subsidiary population is 900-1100 Ma; 3) no zircons with ages that match the timing of the Ross Orogen (530-480 Ma) were identified; 4) two grains of 420 Ma and a 453 Ma are probably too young for the paleontogically

Synthesis of Bi2Sr2CaCu2O8+δ whiskers and cross-whisker intrinsic Josephson junction

International Nuclear Information System (INIS)

Hatano, T.; Takano, Y.; Arisawa, S.; Ishii, A.; Togano, K.; Fukuyo, A.

2001-01-01

A synthesis technique of Bi 2 Sr 2 CaCu 2 O 8+δ single-crystal whiskers was studied. The whiskers were synthesized by heating glassy melt-quenched Bi-Sr-Ca-Cu-O (3:2:2:4 in cationic ratio) plates. The atmospheric condition of the whisker growth, especially oxygen partial pressure and gas flow, was investigated. It was found out that the whisker growth rate shows a maximum at P O2 =2/3 bar. For the crystalline quality of the whiskers, the airtight condition was found to be useful as compared to the conventional oxygen stream condition. The crystalline quality, especially the straightness and morphology of the surface, could be improved by keeping the growing whiskers under the equilibrium P Bi condition. Over 20-mm-long whisker crystals have been successfully synthesized by choosing optimum oxygen partial pressure around the P O2 =2/3 bar in the airtight condition. The growth condition and mechanism of the Bi 2 Sr 2 CaCu 2 O 8+δ whiskers were investigated by an in-situ high-temperature x-ray diffraction analysis and an in-situ high-temperature microscope observation. It was found that the whiskers grow in a partially melted state at a temperature of 10-40 degrees below the melting point. The result obtained demonstrates that Bi 2 Sr 2 CaCu 2 O 8+δ whiskers grow at their bottom by the conventional liquid-phase growth mechanism, as was proposed by Matsubara et al. (author)

Isotope ratio 87Sr/86Sr in limestones from Bambui group, Brazil (MG)

International Nuclear Information System (INIS)

Kawashita, K.; Mizusaki, A.M.P.; Kiang, C.H.

1987-01-01

The Sr composition of ancient seawater can be estimated from the analysis of carbonate rocks and, in some cases, used to estimate the age of the analyzed carbonate. The normalized 87Sr/86Sr ratios in calcium carbonate fractions from 14 core samples in the Bambui Group near Montalvania, MG, were found to range between .7077 and .7280. The higher values are attributable to Sr isotopic exchange between silicate and carbonate phases during diagenesis. The ratio of .7077 obtained in two pure calcium carbonate samples is here suggested as the best aproximation for the 87Sr/86Sr value for the Bambui sea. This ratio is compatible with an age of about 700 Ma., estimated from the published 87Sr/86Sr curve of Veizer and others, an age in accordance with Quadros recent (1987, in preparation) identification of marine acritarchs from the latest Precambrian (Vendian). (author) [pt

Structural and compositional characterization of synthetic (Ca,Sr)-tremolite and (Ca,Sr)-diopside solid solutions

Science.gov (United States)

Gottschalk, M.; Najorka, J.; Andrut, M.

Tremolite (CaxSr1-x)2Mg5[Si8O22/(OH)2] and diopside (CaxSr1-x)Mg[Si2O6] solid solutions have been synthesized hydrothermally in equilibrium with a 1 molar (Ca,Sr)Cl2 aqueous solution at 750°C and 200 MPa. The solid run products have been investigated by optical, electron scanning and high resolution transmission electron microscopy, electron microprobe, X-ray-powder diffraction and Fourier-transform infrared spectroscopy. The synthesized (Ca,Sr)-tremolites are up to 2000 µm long and 30 µm wide, the (Ca,Sr)-diopsides are up to 150 µm long and 20 µm wide. In most runs the tremolites and diopsides are well ordered and chain multiplicity faults are rare. Nearly pure Sr-tremolite (tr0.02Sr-tr0.98) and Sr-diopside (di0.01Sr-di0.99) have been synthesized. A continuous solid solution series, i.e. complete substitution of Sr2+ for Ca2+ on M4-sites exists for (Ca,Sr)-tremolite. Total substitution of Sr2+ for Ca2+ on M2-sites can be assumed for (Ca,Sr)-diopsides. For (Ca,Sr)-tremolites the lattice parameters a, b and β are linear functions of composition and increase with Sr-content whereas c is constant. For the diopside series all 4 lattice parameters are a linear function of composition; a, b, c increase and β decreases with rising Sr-content. The unit cell volume for tremolite increases 3.47% from 906.68 Å3 for tremolite to 938.21 Å3 for Sr-tremolite. For diopside the unit cell volume increases 4.87 % from 439.91 Å3 for diopside to 461.30 Å3 for Sr-diopside. The observed splitting of the OH stretching band in tremolite is caused by different configurations of the next nearest neighbors (multi mode behavior). Resolved single bands can be attributed to the following configurations on the M4-sites: SrSr, SrCa, CaCa and CaMg. The peak positions of these 4 absorption bands are a linear function of composition. They are shifted to lower wavenumbers with increasing Sr-content. No absorption band due to the SrMg configuration on the M4-site is observed. This indicates

Extinction-to-Backscatter Ratios of Saharan Dust Layers Derived from In-Situ Measurements and CALIPSO Overflights During NAMMA

Science.gov (United States)

Omar, Ali H.; Liu, Zhaoyan; Vaughan, Mark A.; Hu, Yongxiang; Ismail, Syed; Powell, Kathleen A.; Winker, David M.; Trepte, Charles R.; Anderson, Bruce E.

2010-01-01

We determine the aerosol extinction-to-backscatter (Sa) ratios of dust using airborne in-situ measurements of microphysical properties, and CALIPSO observations during the NASA African Monsoon Multidisciplinary Analyses (NAMMA). The NAMMA field experiment was conducted from Sal, Cape Verde during Aug-Sept 2006. Using CALIPSO measurements of the attenuated backscatter of lofted Saharan dust layers, we apply the transmittance technique to estimate dust Sa ratios at 532 nm and a 2-color method to determine the corresponding 1064 nm Sa. Using this method, we found dust Sa ratios of 39.8 plus or minus 1.4 sr and 51.8 plus or minus 3.6 sr at 532 nm and 1064 nm, respectively. Secondly, Sa ratios at both wavelengths is independently calculated using size distributions measured aboard the NASA DC-8 and estimates of Saharan dust complex refractive indices applied in a T-Matrix scheme. We found Sa ratios of 39.1 plus or minus 3.5 sr and 50.0 plus or minus 4 sr at 532 nm and 1064 nm, respectively, using the T-Matrix calculations applied to measured size spectra. Finally, in situ measurements of the total scattering (550 nm) and absorption coefficients (532 nm) are used to generate an extinction profile that is used to constrain the CALIPSO 532 nm extinction profile.

Origin of the Early Sial Crust and U-Pb Isotope-Geochemical Heterogeneity of the Earth's Mantle

Science.gov (United States)

Mishkin, M. A.; Nozhkin, A. D.; Vovna, G. M.; Sakhno, V. G.; Veldemar, A. A.

2018-02-01

It is shown that presence of the Early Precambrian sial crust in the Indo-Atlantic segment of the Earth and its absence in the Pacific has been caused by geochemical differences in the mantle underlying these segments. These differences were examined on the basis of Nd-Hf and U-Pb isotopes in modern basalts. The U-Pb isotope system is of particular interest, since uranium is a member of a group of heat-generating radioactive elements providing heat for plumes. It is shown that in the Indo-Atlantic segment, a distribution of areas of the modern HIMU type mantle is typical, while it is almost completely absent in the Pacific segment. In the Archean, in the upper HIMU type paleo-mantle areas, plume generation and formation of the primordial basic crust occurred; this was followed by its remelting resulting in the appearance of an early sial crust forming cratons of the Indo-Atlantic segment.

Detrital U-Pb zircon analysis of an Eocene McMurdo Erratic sandstone, McMurdo Sound, Antarctica

International Nuclear Information System (INIS)

Paulsen, T.; Encarnacion, J.; Valencia, V.A.; Roti Roti, J.M.; Rasoazanamparany, C.

2011-01-01

Some of the most important Cenozoic sedimentary rocks in Antarctica are glacial erratics of fossiliferous Palaeogene to Neogene siliclastic rocks known as the McMurdo Erratics. Detrital zircon U-Pb isotopic data reported herein provide new information on the provenance of these siliciclastic rocks. The U-Pb age data from a sandstone glacial erratic that is likely of Eocene age show a dominant age cluster that ranges from 488 to 635 Ma, accompanied by subsidiary Neoproterozoic-Archaean peaks. The dominant Neoproterozoic-Ordovician age cluster, in conjunction with the arkosic lithologies of some erratics and the local presence of granitic and metasedimentary clasts, indicates that the Neoproterozoic-Ordovician basement complex of the Transantarctic Mountains likely served as a major source for the Eocene siliciclastic sediments. This is consistent with derivation of the McMurdo Erratics from locations proximal to the Transantarctic Mountains such as the Discovery Deep and/or major mountain outlet glacier areas. (author). 19 refs., 3 figs., 1 tab.

Cenozoic mantle composition evolution of southern Tibet indicated by Paleocene ( 64 Ma) pseudoleucite phonolitic rocks in central Lhasa terrane

Science.gov (United States)

Qi, Yue; Gou, Guo-Ning; Wang, Qiang; Wyman, Derek A.; Jiang, Zi-Qi; Li, Qiu-Li; Zhang, Le

2018-03-01

The question of whether continental subduction processes in collisional orogenic belts can trigger wide-spread mantle metesomatism and crustal material recycling remains unresolved. Miocene (25-8 Ma) ultrapotassic rocks in southern Tibet are the only mantle-derived magmatic rocks emplaced after the collision between India and Asia and they have been linked to the onset of east-west extensional stresses as the surface uplift of the Tibetan Plateau reached near-maximum elevation. However, their petrogenesis remains highly controversial, particularly the issue of whether their extremely enriched Sr-Nd isotopic characteristics were related to metasomatism derived from subducted Indian continental materials during the Cenozoic. Here we report on a Paleocene silicate-unsaturated, pseudoleucite phonolitic dike, in the Rongniduo area of central Lhasa terrane. In-situ SIMS (secondary ion mass spectrometry) apatite U-Pb age indicates the dike was generated at 64.1 ± 4.2 Ma, which slightly predates the age of initial India and Asia collision (about 55-50 Ma). This is the oldest age yet reported for ultrapotassic rocks in southern Tibet. Samples from this dike have distinctly more depleted Sr-Nd (whole rock: (87Sr/86Sr)i = 0.7064 to 0.7062, εNd(t) = - 1.5 to 0.4; in situ apitite: (87Sr/86Sr)i = 0.7059 to 0.7060, εNd(t) = - 2.0 to 0.4) isotopic compositions, than those of Miocene (25-8 Ma) ultrapotassic rocks in the central Lhasa terrane ((87Sr/86Sr)i = 0.7106 to 0.7399, εNd(t) = - 10.6 to - 18.5). Our new data provides important constraints on pre-collisional mantle characteristics beneath the Lhasa terrane. We suggest that these 64 Ma pseudoleucite phonolitic rocks were derived from the enriched lithospheric mantle metasomatized by subducted Tethyan oceanic materials in response to Neo-Tethyan slab roll-back. As a consequence, the younger Miocene ultrapotassic rocks, which display different geochemical compositions from the pre-collisional ultrapotassic rocks, were most

Complex titanates Sr_1_-_xPb_xLi_2Ti_6O_1_4 (0≤x≤1) as anode materials for high-performance lithium-ion batteries

International Nuclear Information System (INIS)

Qian, Shangshu; Yu, Haoxiang; Yan, Lei; Li, Peng; Lin, Xiaoting; Wu, Yaoyao; Long, Nengbing; Shui, Miao; Shu, Jie

2016-01-01

Highlights: • Sr_1_-_xPb_xLi_2Ti_6O_1_4 (0≤x≤1) is prepared by a simple solid state reaction. • Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 exhibits enhanced lithium storage capability. • Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 can deliver a capacity of 141.8 mAh g"−"1 at 700 mA g"−"1. • In-situ XRD is performed to study the reversibility of Sr_1_-_xPb_xLi_2Ti_6O_1_4. - Abstract: With the Pb doping content at Sr-site increasing, a series of Sr_1_-_xPb_xLi_2Ti_6O_1_4 (x = 0, 0.25, 0.50, 0.75, 1.0) are synthesized by a simple solid-state reaction. It is found that the reversible capacity and rate capability experience a parabolic course from SrLi_2Ti_6O_1_4 to PbLi_2Ti_6O_1_4. Among all the as-prepared samples, Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 shows the best cycling and rate properties. It delivers an initial charge capacity of 163.2 mAh g"−"1 at 100 mA g"−"1 with the capacity retention of 96.08% after 100 cycles. In addition, it can also deliver a reversible capacity of 141.8 mAh g"−"1 at 700 mA g"−"1. The superior electrochemical properties of Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 are attributed to the reduced charge transfer resistance and increased lithium-ion diffusion coefficient after doping. Besides, in-situ X-ray diffraction is also performed to investigate the lithium-ion insertion/extraction behaviors of SrLi_2Ti_6O_1_4, Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 and PbLi_2Ti_6O_1_4. The observed results confirm that Sr_0_._5Pb_0_._5Li_2Ti_6O_1_4 has good structural stability and reversibility for repeated lithium storage.

U-Pb ages in zircon of some classic granites from the Borborema province

International Nuclear Information System (INIS)

Neves, Benjamin Bley de Brito; Basei, Miguel Angelo Stipp; Passarelli, Claudia Regina; Santos, Edilton Jose dos

2003-01-01

The Neoproterozoic evolution of the Borborema Province in the east-northeast part of the South American platform exhibits remarkable, much studied granitic plutonism. In 1967 F. F. Almeida and co-workers discriminated a series of granitic typologies as 'Conceicao type', 'Itaporanga type' etc, mostly based upon general geological features and petrographic grounds. This preliminary classification has somehow been maintained in all subsequent papers up to now, despite all the newly observed plutons and the newly generated tectonic, geochemical and isotopic data since then. Samples of these classical types of granites from their type-localities were analyzed geo chronologically using the U-Pb method in zircons in response to the felt needs of the geological community, because previous age-determinations involved less accurate methods. The new data have been added to all other preexisting U-Pb data (from other granitic bodies) obtained over the last decade, making it possible to recognize three main stages of granitic magmatism for the Borborema Province: 650-625 Ma, 580-570 Ma and 545-520 Ma. The last group of dates is closely association with the escape tectonics of the Brasiliano-Pan African collage, which preceded the assembly of the super continental landmass of Western Gondwana. (author)

The U-Pb age of the Posselandia Diorite, Hidrolina, Goias State, Brazil

International Nuclear Information System (INIS)

Jost, Hardy; Pimentel, Marcio M.; Fuck, Reinhard A.; Danni, Jose C.M.

1993-01-01

The Posselandia Diorite intrudes Archean granite-greenstone terrains of the region of Hidrolina, Central Goias, Brazil. U-Pb radiometric determinations in two fractions of zircon crystals from the diorite yield an age of 2,146 ± 1,6 Ma, interpreted as the crystallization age of the intrusion. The lack of deformation in the intrusion demonstrates that consolidation of the granite-greenstone terrains in the Hidrolina-Pilar de Goias-Crixas area took place before 2,146 Ma. (author). 3 figs., 2 tabs

Origin and evolution of multi-stage felsic melts in eastern Gangdese belt: Constraints from U-Pb zircon dating and Hf isotopic composition

Science.gov (United States)

Guo, Liang; Zhang, Hong-Fei; Harris, Nigel; Pan, Fa-Bin; Xu, Wang-Chun

2011-11-01

This integrated study of whole rock geochemistry, zircon U-Pb dating and Hf isotope composition for seven felsic rocks from the Nyingchi Complex in eastern Himalayan syntaxis has revealed a complex magmatic history for the eastern Gangdese belt. This involves multiple melt sources and mechanisms that uniquely identify the tectonic evolution of this part of the Himalayan orogen. Our U-Pb zircon dating reveals five stages of magmatic or anatectic events: 165, 81, 61, 50 and 25 Ma. The Jurassic granitic gneiss (165 Ma) exhibits εHf(t) values of + 1.4 to + 3.5. The late Cretaceous granite (81 Ma) shows variable εHf(t) values from - 0.9 to + 6.2, indicating a binary mixing between juvenile and old crustal materials. The Paleocene granodioritic gneiss (61 Ma) has εHf(t) values of + 5.4 to + 8.0, suggesting that it originated from partial melting of a juvenile crustal material. The Eocene anatexis is recorded in the leucosome, which has Hf isotopic composition similar to that of the Jurassic granite, indicating that the leucosome could be derived from partial melting of the Jurassic granite. The late Oligocene biotite granite (25 Ma) shows adakitic geochemical characteristics, with Sr/Y = 49.3-56.6. The presence of a large number of inherited zircons and negative εHf(t) values suggest that it sourced from anatexis of crustal materials. In contrast to the Gangdese batholiths that are mainly derived from juvenile crustal source in central Tibet, the old crustal materials play an important role for the magma generation of the felsic rocks, suggesting the existence of a crustal basement in the eastern Gangdese belt. These correspond to specific magmatic evolution stages during the convergence between India and Asia. The middle Jurassic granitic gneiss resulted from the northward subduction of the Neo-Tethyan oceanic slab. The late Cretaceous magmatism is probably related to the ocean ridge subduction. The Paleocene-Eocene magmatism, metamorphism and anatexis are

In Situ Foaming of Porous (La _0.6 Sr _0.4 ) _0.98 (Co _0.2 Fe _0.8 ) O _3-δ (LSCF) Cathodes for Solid Oxide Fuel Cell Applications

Energy Technology Data Exchange (ETDEWEB)

Gandavarapu, Sodith [US DOE-National Energy Technology Laboratory, 3610 Collins Ferry Road P.O.Box.880 Morgantown West Virginia 26507; Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown West Virginia 26506; Sabolsky, Edward [US DOE-National Energy Technology Laboratory, 3610 Collins Ferry Road P.O.Box.880 Morgantown West Virginia 26507; Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown West Virginia 26506; Sabolsky, Katarzyna [Department of Mechanical and Aerospace Engineering, West Virginia University, Morgantown West Virginia 26506; Gerdes, Kirk [US DOE-National Energy Technology Laboratory, 3610 Collins Ferry Road P.O.Box.880 Morgantown West Virginia 26507

2013-07-18

A binder system containing polyurethane precursors was used to in situ foam (direct foam) a (La{sub 0.6}Sr{sub 0.4}){sub 0.98} (Co{sub 0.2} Fe{sub 0.8}) O{sub 3-{ delta}} (LSCF) composition for solid oxide fuel cell (SOFC) cathode applications. The relation between in situ foaming parameters on the final microstructure and electrochemical properties was characterized by microscopy and electrochemical impedance spectroscopy (EIS), respectively. The optimal porous cathode architecture was formed with a 70 vol% solids loading within a polymer precursor composition with a volume ratio of 8:4:1 (isocyanate: PEG: surfactant) in a terpineol-based ink vehicle. The resultant microstructure displayed a broad pore size distribution with highly elongated pore structure.

High temperature (>350 °C) thermal histories of the long lived (>500 Ma) active margin of Ecuador and Colombia: Apatite, titanite and rutile U-Pb thermochronology

Science.gov (United States)

Paul, Andre N.; Spikings, Richard A.; Ulianov, Alexey; Ovtcharova, Maria

2018-05-01

Quantitative reconstruction of thermal histories can be a powerful tool to study numerous natural processes such as tectonic plate interaction, cratonic stability and extra-terrestrial phenomena such as asteroid ejection. A majority of thermochronological studies have focused on temperatures lower than 300 °C. Few previous studies have demonstrated that U-Pb data from apatite and other accessory phases can be used to recover thermal history information at T > 350 °C. We present U-Pb data from apatite, to constrain the thermal histories of Triassic peralluminous anatectites from the Northern Andes between the temperatures of ∼350-550 °C. The accuracy of the thermal history models is assessed by comparisons with previous geological models, and comparisons with pre-existing and newly acquired U/Pb (titanite and rutile), 40Ar/39Ar (muscovite) and low temperature thermochronological data. This study also examines the feasibility of using a large, regionally dispersed apatite U-Pb data set to obtain continuous thermal history paths along a long-lived (>500 Ma) active margin. A second aim of this study is to further test the hypothesis that the dominant mechanism for Pb displacement through apatite is volume diffusion, as opposed to aqueous fluid interaction. The thermal history models derived from the Triassic anatectites exposed in the Andes of Colombia and Ecuador are entirely consistent with lower temperature thermochronological constraints, and previously established geochronological and geochemical constraints. They reveal and quantify trench parallel changes in the amount of Jurassic - Early Cretaceous extension, significantly bolstering and adding to previous tectonic interpretations. Confirmation of the utility of U-Pb thermochronology provides geologists with a powerful tool for investigating the high-temperature thermal evolution of accessory minerals.

Effect of Wood Aging on Wine Mineral Composition and 87Sr/86Sr Isotopic Ratio.

Science.gov (United States)

Kaya, Ayse D; Bruno de Sousa, Raúl; Curvelo-Garcia, António S; Ricardo-da-Silva, Jorge M; Catarino, Sofia

2017-06-14

The evolution of mineral composition and wine strontium isotopic ratio 87 Sr/ 86 Sr (Sr IR) during wood aging were investigated. A red wine was aged in stainless steel tanks with French oak staves (Quercus sessiliflora Salisb.), with three industrial scale replicates. Sampling was carried out after 30, 60, and 90 days of aging, and the wines were evaluated in terms of general analysis, phenolic composition, total polysaccharides, multielement composition, and Sr IR. Li, Be, Mg, Al, Sc, Ti, V, Mn, Co, Ni, Cu, Zn, Ga, Ge, As, Rb, Sr, Y, Zr, Mo, Sb, Cs, Ba, Pr, Nd, Sm, Eu, Dy, Ho, Er, Yb, Lu, Tl, and Pb elements and 87 Sr/ 86 Sr were determined by quadrupole inductively coupled plasma mass spectrometry (Q-ICP-MS) and Na, K, Ca, and Fe by flame atomic absorption spectrometry (FAAS). Two-way ANOVA was applied to assess wood aging and time effect on Sr IR and mineral composition. Wood aging resulted in significantly higher concentrations of Mg, V, Co, Ni, and Sr. At the end of the aging period, wine exhibited statistically identical Sr IR compared to control. Study suggests that wood aging does not affect 87 Sr/ 86 Sr, not precluding the use of this parameter for wine traceability purposes.

Significance of zircon U-Pb ages from the Pescadero felsite, west-central California coast ranges

Science.gov (United States)

McLaughlin, Robert J.; Moore, Diane E.; ,; Martens, UWE C.; Clark, J.C.

2011-01-01

Weathered felsite is associated with the late Campanian–Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio–Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ∼185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ± prehnite ± laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe–reverse geometry (SHRIMP-RG) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefly Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86–90 Ma. Reflecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio–Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ∼100 km to the east in the Diablo Range–San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper

Effect of organic matrices on the determination of the trace element chemistry (Mg, Sr, Mg/Ca, Sr/Ca) of aragonitic bivalve shells (Arctica islandica). Comparison of ICP-OES and LA-ICP-MS data

International Nuclear Information System (INIS)

Schoene, Bernd R.; Zhang, Zengjie; Jacob, Dorrit; Soldate, Analia; Gillikin, David P.; Tuetken, Thomas; Garbe-Shoenberg, Dieter; McConnaughey, Ted

2010-01-01

The element chemistry of biogenic carbonates can provide important data on past environments. However, the Sr/Ca and Mg/Ca ratios as well as the Mg and Sr concentrations of biological carbonates, especially aragonitic bivalves often depart from apparent thermodynamic equilibrium. When measured in situ by means of LA-ICP-MS, the Mg concentration is often substantially enriched (two- to threefold) near the organic-rich, annual growth lines. To test the hypothesis that some organic components exert a major influence on the skeletal metal content, the element chemistry of different shell components (insoluble organic matrix, IOM; dissolved CaCO 3 and soluble organics, SOM) of Arctica islandica was measured by means of ICP-OES and LA-ICP-MS. The ICP-OES data indicate that the IOM is strongly enriched in Mg (130 ppm) and depleted in Sr and Ca (10 ppm and 0.22 wt%, respectively) when compared to the whole biomineral (Mg: 68 to 99 ppm, Sr: 860 to 1,060 ppm, Ca: ∼35.72 wt%). Although the average relative abundance of the IOM barely exceeds 0.46 wt%, its chemical composition in combination with its heterogeneous distribution across the shell can significantly increase estimates of the Mg concentration if measured in situ by LA-ICP-MS. Depending on the distribution of the IOM, the Ca concentration may be significantly lower locally than the average Ca concentration of the whole shell (35.72 wt%). If this remains undetected, the Mg concentration of shell portions with higher than average IOM content is overestimated by LA-ICP-MS and, conversely, the Mg concentration is underestimated in shell portions with lower than average IOM content. Removal of the IOM prior to the chemical analysis by LA-ICP-MS or mathematical correction for the IOM-derived magnesium concentrations is therefore strongly advised. The different chemistry of the IOM may also exert a major control on the trace element to calcium ratios. Shell portions enriched in IOM will show up to 200 times higher Mg

Pan-African U-Pb zircon age from apatite-magnetite veins of eastern ghats granulite belt, India

International Nuclear Information System (INIS)

Kovach, V.P.; Salnikova, E.B.; Kotov, A.B.; Yakovleva, S.Z.; Rao, A.T.

1997-01-01

206 Pb/ 238 U ages of zircon correspond to 502±3 Ma and 207 Pb/ 206 Pb ages are equal to 508±14 Ma. U-Pb isotopic study of the Kasipatnam zircon has led to the recognition of pan-African thermal event in the eastern ghats granulite belt, India. (author)

Geochronological synthesis of Bahia state and the crustal evolution, based in evolution diagram of Sr and initial rate of Sr87/Sr86

International Nuclear Information System (INIS)

Sato, K.

1986-01-01

The crustal evolution of the ancient terrains of the State of Bahia, Brazil, is attempted with the aid of Sr isotopic results as natural tracers. Some Nd and Pb isotopic data are also available, and support the main conclusions based on Sr evolution diagrams. The analysis of the Sr evolution diagrams shows that the Archean Terrains are mainly formed by accretion from mantle-derived material, but crustal reworking is indicated by the high initial 87 Sr/ 86 Sr value of the Jequie Complex. The Transamazonian mobile belt include both types of materials, but the 87 Sr/ 86 Sr value, generally lower than those of the Jequie Complex, markes improbable a direct derivation. During Middle and Late Proterozoic, the continental crust was already well consolidated, and reworking of crustal material predominated within the Espinhaco and Brasiliano folded systems [pt

U-Pb Ages of Secondary Silica at Yucca Mountain, Nevada: Implications for the Paleohydrology of the Unsaturated Zone

International Nuclear Information System (INIS)

L.A. Neymark; Y. Amelin; J.B. Paces; Z.E. Peterman

2001-01-01

U, Th, and Pb isotopes were analyzed in layers of opal and chalcedony from individual millimeter- to centimeter-thick calcite and silica coatings at Yucca Mountain, Nevada, USA, a site that is being evaluated for a potential high-level nuclear waste repository. These calcite and silica coatings on fractures and in lithophysal cavities in Miocene-age tuffs in the unsaturated zone (UZ) precipitated from descending water and record a long history of percolation through the UZ. Opal and chalcedony have high concentrations of U (10 to 780 ppm) and low concentrations of common Pb as indicated by large values of 206 Pb/ 204 Pb (up to 53,806), thus making them suitable for U-Pb age determinations. Interpretations of U-Pb isotopes in opal samples at Yucca Mountain are complicated by the incorporation of excess 234 U at the time of mineral formation, resulting in reverse discordance of U-Pb ages. However, the 207 Pb/ 235 U ages are much less affected by deviation from initial secular equilibrium and provide reliable ages of most silica deposits between 0.6 and 9.8 Ma. For chalcedony subsamples showing normal age discordance, these ages may represent minimum times of deposition. Typically, 207 Pb/ 235 U ages are consistent with the microstratigraphy in the mineral coating samples, such that the youngest ages are for subsamples from outer layers, intermediate ages are from inner layers, and oldest ages are from innermost layers. 234 U and 230 Th in most silica layers deeper in the coatings are in secular equilibrium with 238 U, which is consistent with their old age and closed system behavior during the past 0.5 m.y. U-Pb ages for subsamples of silica layers from different microstratigraphic positions in individual calcite and silica coating samples collected from lithophysal cavities in the welded part of the Topopah Spring Tuff yield slow long-term average depositional rates of 1 to 5 mm/m.y. These data imply that the deeper parts of the UZ at Yucca Mountain maintained long

Results of field studies on 90SR and stable SR soil-to-plant transfer

International Nuclear Information System (INIS)

Gerzabek, M.H.; Artner, C.; Horak, O.; Mueck, K.

1992-01-01

In 1987 and 1988 at 35 sites plants ready to harvest and the corresponding soils (0 - 20 cm) were collected for 90 Sr and stable strontium analyses. Sample preparation and measurement led to a detection limit of 0.008 Bq 90 Sr kg -1 . The 90 Sr-contamination of Austrian soils ranged from 396 to 1998 Bq m -2 . Known from literature the contribution of the Chernobyl fallout amounted to app. 25 % of the total contamination. Stable strontium contents of the soils were between 6 and 62.5 mg kg -1 . Bariumtriethanolamine extracted 17.7 to 62.3 % of the total stable Sr in soil. 90 Sr-concentrations in cereal grains ranged from 0.03 to 0.67 Bq kg -1 (fresh wight) for maize and barley, respectively. The values for other foodstuff were between 0.15 (white cabbage) and 0.91 Bq kg -1 (spinach). Stable strontium contents were between 0.079 mg kg -1 (maize) and 72.5 mg kg -1 (celery shoot). The following mean 90 Sr soil-to-plant transfer factors for cereal grains were obtained: 0.010 (maize), 0.097 (rye), 0.049 (wheat), 0.095 (barley). Transfer factors for straw were up to 50 times higher (maize). The transfer of 90 Sr into vegetables and potatoes reached the same order of magnitude compared to the cereals. In all cases soil-to-plant transfer of stable Sr was clearly lower up to 60 % of the respective values for 90 Sr. Thus natural stable strontium is less plant available than 90 Sr. The influence of soil parameters on the 90 Sr transfer into plants was examinated by correlation analyses. Increasing exchangeable calcium contents of the soils resulted in a significant reduction of Sr soil-to-barley straw transfer. (authors)

Enhanced photocatalytic activity of SrTiO3 photocatalyst by topotactic preparation

Science.gov (United States)

Cao, Jiafeng; Huang, Xianshan; Liu, Yi; Wu, Jianguang; Ji, Yuexia

2016-11-01

Novel SrTiO3 (ST) photocatalysts with different shapes such as plates, rods and cubes were successfully synthesized based on a topotactic approach. The rod-like ST particles formed in situ at the plates show superior photocatalytic activities towards the decomposition of Rhodamine B than the plate-like and the cubic particles under visible-light irradiation, which could be attributed to the crystal orientation exposing highly active sites accompanied by the crystallite growth in molten salt. The results reveal an effective approach for fabrication of novel photocatalysts of perovskite structure with enhanced photocatalytic activities.

Internal bremsstrahlung from 89Sr and 90Sr

International Nuclear Information System (INIS)

Sayibaba, T.; Narasimha Murity, K.; Rao, C.R.; Satyaprakash; Gubbi, G.K.

1987-01-01

The internal bremsstrahlung (IB) spectra emitted in the beta-decays of 89 Sr and 90 Sr were measured with a HPGe detector and a multichannel analyser along with a standard geometrical set-up. Sufficient care has been taken to avoid spurious effects. After making all the necessary corrections, the experimental results were compared with the corresponding theoretical distributions due to Knipp and Uhlenbeck and Bloch (KUB), Lewis and Ford, Nilsson, and also due to Ford and Martin (detour theory). The total IB yields of intensity and energy from each of the isotopes in the investigated energy regions are also determined and compared with the corresponding theoretical values. The present results of IB from 89 Sr are satisfactorily accounted for by the KUB theory. In the case of 90 Sr the experimental results of IB coincide with the Coulomb-corrected theoretical distibution due to Nilsson in the energy range from 60 keV to 110 keV and Beyond 110 keV, they are found to be in excess over Nilsson's theory as well as the detour theory due to Ford and Martin up to the maximum photon energy studied, namely 350 keV

Oxygen Electrode Kinetics and Surface Composition of Dense (La0.75Sr0.25)0.95MnO3 on YSZ

DEFF Research Database (Denmark)

Wu, Yuehua; Hansen, Karin Vels; Norrman, Kion

2013-01-01

in situ at temperatures from 660 to 860 C using a controlled atmosphere high temperature scanning probe microscope (CAHT-SPM) setup for measurements of impedance spectroscopy and potential sweep. The oxygen partial pressure, pO2, was varied. Further, ex situ surface analysis by time of flight secondary...... ion mass spectrometry (TOF-SIMS) and structure examination by scanning electron microscopy (SEM) were performed. Segregation of Sr and La oxides to LSM surfaces and Mn rich oxide to the three phase boundary (TPB) was observed. YSZ and LSM attract different oxides/impurities. The oxygen electrode...

Effect of Sr/Ti Ratio on the Photocatalytic Properties of SrTiO3

International Nuclear Information System (INIS)

Sulaeman, U; Yin, S; Sato, T

2011-01-01

Since strontium titanate is a wide gap semiconductor, it requires UV light to generate the photocatalytic activities. Modification of strontium titanate to show photocatalytic activity under visible light irradiation is the essential work to efficiently utilize the sun light energy for environmental application. It is expected that the synthesis of SrTiO 3 with variation of Sr/Ti atomic ratio could induce the defect crystals having unique photocatalytic properties. The SrTiO 3 with various Sr/Ti atomic ratios were synthesized by microwave-assisted solvothermal reaction of SrCl 2 .6H 2 O and Ti(OC 3 H 7 ) 4 in KOH aqueous solutions with different atomic ratios of Sr/Ti. The products were characterized by TG-DTA, XRD and DRS. The photocatalytic activity was determined by DeNO x ability using LED lamps with the wavelengths of 627 nm (red), 530 nm (green), 445 nm (blue) and 390 nm (UV). The nanoparticles of perovskite type SrTiO 3 with the particle size of 30-40 nm were successfully synthesized. The visible light responsive photocatalytic activity was generated by adding excess amount of Sr. The photocatalytic activity in visible light could be enhanced by an increase in the Sr/Ti atomic ratio up to 1.25, indicating that the visible light responsive photocatalytic activity is due to the generation of new band gap between the conduction band and valence band of SrTiO 3 by the formation of oxygen vacancy.

In-situ Strontium Isotopes Analysis on Single Conodont Apatite by LA-MC-ICP-MS

Science.gov (United States)

Zhao, L.; Zhang, L.; Chen, Z. Q.; Ma, D.; Qiu, H.; Lv, Z.; Hu, Z.; Wang, F.

2014-12-01

Strontium isotope played an important role in stratigraphic chronology and sedimentary geochemistry research (McArthur et al., 2001). Conodonts is a kind of extinct species of marine animals and widely distributed in marine sediments all over the world. Rich in radiogenic Sr contents and difficulty to be affected during diagenesis alteration makes conodonts a good choice in seawater Sr isotope composition studies (John et al., 2008). Conodont samples were collected from 24th to 39th layer across Permian-Triassic boundary at Meishan D section (GSSP), Zhejiang Province, South China (Yin et al., 2001). Conodonts was originated from fresh limestone and only conodont elements with CAIextinction events during the Permian-Triassic transition. Our study also makes is possible for high resolution 87Sr/ 86Sr ratio testing on the single conodont apatite and riched the in-situ studies on the conodont apatite, which of great significance for the future conodont Sr isotope research (Zhao et al., 2009; Zhao et al., 2013). Keywords: Conodonts, Strontium isotope, LA-MC-ICP-MS, Permian-Triassic transition, Meishan D section [1] John et al., 2008 3P[2] McArthur et al., 2001 J. of Geology [3] Yin et al., 2001 Episodes [4] Zhao et al., 2009 Earth Science J. of CUG [5] Zhao et al., 2013 GPC.

U-Pb thermochronology of rutile from Alpine Corsica: constraints on the thermal evolution of the European margin during Jurassic continental breakup

Science.gov (United States)

Ewing, T. A.; Beltrando, M.; Müntener, O.

2017-12-01

U-Pb thermochronology of rutile can provide valuable temporal constraints on the exhumation history of the lower crust, given its moderate closure temperature and the occurrence of rutile in appropriate lithologies. We present an example from Alpine Corsica, in which we investigate the thermal evolution of the distal European margin during Jurassic continental rifting that culminated in the opening of the Alpine Tethys ocean. The Belli Piani unit of the Santa Lucia nappe (Corsica) experienced minimal Alpine overprint and bears a striking resemblance to the renowned Ivrea Zone lower crustal section (Italy). At its base, a 2-4 km thick gabbroic complex contains slivers of granulite facies metapelites that represent Permian lower crust. Zr-in-rutile temperatures and U-Pb ages were determined for rutile from three metapelitic slivers from throughout the Mafic Complex. High Zr-in-rutile temperatures of 850-950 °C corroborate textural evidence for rutile formation during Permian granulite facies metamorphism. Lower Zr-in-rutile temperatures of 750-800 °C in a few grains are partly associated with elongate strings of rutile within quartz ribbons, which record recrystallisation of some rutile during high-temperature shearing. Zr thermometry documents that both crystallisation and re-crystallisation of rutile occurred above the closure temperature of Pb in rutile, such that the U-Pb system can be expected to record cooling ages uncomplicated by re-crystallisation. Our new high-precision single-spot LA-ICPMS U-Pb dates are highly consistent between and within samples. The three samples gave ages from 160 ± 1 Ma to 161 ± 2 Ma, with no other age populations detected. The new data indicate that the Santa Lucia lower crust last cooled through 550-650 °C at 160 Ma, coeval with the first formation of oceanic crust in the Tethys. The new data are compared to previous depth profiling rutile U-Pb data for the Belli Piani unit1, and exploited to cast light on the tectonothermal

Regional and interspecific variation in Sr, Ca, and Sr/Ca ratios in avian eggshells from the USA.

Science.gov (United States)

Mora, Miguel A; Brattin, Bryan; Baxter, Catherine; Rivers, James W

2011-08-01

To examine regional variation in strontium (Sr), which at high concentrations may reduce eggshell quality, increase egg breakage and reproductive failure, we analyzed Sr, and calcium (Ca) concentrations and Sr/Ca ratios in eggshells from 20 avian species from California, Texas, Idaho, Kansas, and Michigan. In addition, we included data previously reported from Arizona to expand the regional comparisons and to better establish patterns of Sr, and Sr/Ca ratios in bird species across the United States. We found Sr concentrations varied significantly among regions, among species, and among foraging guilds; this variability is strongly influenced by the Sr/Ca ratios in surface water from locations close to the region where the eggshells were collected. Sr concentrations and Sr/Ca ratios were significantly higher in bird eggshells from the Volta wildlife region in the San Joaquin Valley, California and in various locales from Arizona. Sr concentrations and Sr/Ca ratios in bird eggshells from other locations in the USA were lower than those detected in these two regions. Among foraging guilds, invertivores had the highest Sr concentrations and Sr/Ca ratios and carnivores had the lowest. In general, the Sr/Ca ratio increased strongly with increasing Sr concentrations (R(2) = 0.99, P eggshells suggesting that these values could be determined from Sr/Ca ratios in water. Eggshell thickness was poorly correlated with Sr (R(2) = 0.03) but had a significant and positive correlation with Ca and was more properly correlated by a quadratic equation (R(2) = 0.50, Thickness = 2.13 - 0.02Ca - 3.07 * 10(-5)Ca(2)). Our study provides further evidence that Sr accumulates significantly in the avian eggshell, in some regions at concentrations which could be of concern for potential negative effects on reproduction. We suggest that when assessing the effects of metals on avian reproduction in regions with high Sr deposits in rock and soil, Sr concentrations in the eggshell also should be

Morphology versus U-Pb systematics in zircon: A high-resolution isotopic study of a zircon population from a Variscan dike in the Central Alps

International Nuclear Information System (INIS)

Bossart, P.J.; Meier, M.; Oberli, F.; Steiger, R.H.

1986-01-01

U/Pb isotopic measurements on individual zircon crystals combined with morphological analyses permit the identification of three distinct components within the zircon population of the Saedelhorn diorite, a Variscan dike from the western Gotthard (Central Alps, Switzerland): (i) 94% of the grains in the zircon population are elongate crystals with pronounced skeletal morphology indicative of rapid growth from a supercooled melt. (ii) 5% of the population consist of turbid, mostly subhedral zircons frequently showing D-type morphology and elevated uranium contents compared to the skeletal variety. Single-crystal and multi-grain U-Pb isotopic data of group (i) and (ii) zircons define an intrusion age of 293 + 5/ -4 m.y. for the dike. (iii) Rare, transparent zircon crystals (< 1% of the zircons population) yield apparent U-Pb ages in the range of 370-490 m.y. and display morphological and isotopic characteristics closely resembling those of a Caledonian orthogneiss intruded by the dike. This implies presence of assimilated wall-rock components in the macroscopically homogeneous dike sample. (orig./WB)

Facile Synthesis of SrCO3-Sr(OH2/PPy Nanocomposite with Enhanced Photocatalytic Activity under Visible Light

Directory of Open Access Journals (Sweden)

Alfredo Márquez-Herrera

2016-01-01

Full Text Available Pyrrole monomer was chemically polymerized onto SrCO3-Sr(OH2 powders to obtain SrCO3-Sr(OH2/polypyrrole nanocomposite to be used as a candidate for photocatalytic degradation of methylene blue dye (MB. The material was characterized by Fourier transform infrared (FTIR spectroscopy, UV/Vis spectroscopy, and X-ray diffraction (XRD. It was observed from transmission electronic microscopy (TEM analysis that the reported synthesis route allows the production of SrCO3-Sr(OH2 nanoparticles with particle size below 100 nm which were embedded within a semiconducting polypyrrole matrix (PPy. The SrCO3-Sr(OH2 and SrCO3-Sr(OH2/PPy nanocomposites were tested in the photodegradation of MB dye under visible light irradiation. Also, the effects of MB dye initial concentration and the catalyst load on photodegradation efficiency were studied and discussed. Under the same conditions, the efficiency of photodegradation of MB employing the SrCO3-Sr(OH2/PPy nanocomposite increases as compared with that obtained employing the SrCO3-Sr(OH2 nanocomposite.

SrTiO3 Nanocube-Doped Polyaniline Nanocomposites with Enhanced Photocatalytic Degradation of Methylene Blue under Visible Light

Directory of Open Access Journals (Sweden)

Syed Shahabuddin

2016-02-01

Full Text Available The present study highlights the facile synthesis of polyaniline (PANI-based nanocomposites doped with SrTiO3 nanocubes synthesized via the in situ oxidative polymerization technique using ammonium persulfate (APS as an oxidant in acidic medium for the photocatalytic degradation of methylene blue dye. Field emission scanning electron microscopy (FESEM, transmission electron microscopy (TEM, thermogravimetric analysis (TGA, X-ray diffraction (XRD, UV–Vis spectroscopy, Brunauer–Emmett–Teller analysis (BET and Fourier transform infrared spectroscopy (FTIR measurements were used to characterize the prepared nanocomposite photocatalysts. The photocatalytic efficiencies of the photocatalysts were examined by degrading methylene blue (MB under visible light irradiation. The results showed that the degradation efficiency of the composite photocatalysts that were doped with SrTiO3 nanocubes was higher than that of the undoped polyaniline. In this study, the effects of the weight ratio of polyaniline to SrTiO3 on the photocatalytic activities were investigated. The results revealed that the nanocomposite P-Sr500 was found to be an optimum photocatalyst, with a 97% degradation efficiency after 90 min of irradiation under solar light.

High-spatial resolution SIMS U-Pb zircon dating on Malay tin granites: New insights to crustal evolution of the Malaysian Peninsula

Science.gov (United States)

Ng, S.; Searle, M. P.; Whitehouse, M. J.; Chung, S.; Robb, L. J.; Ghani, A. A.; Sone, M.

2012-12-01

The Southeast Asian tin granite province has previously been recognized as comprising three distinct granitic belt (Cobbing et al., 1986): (1) Middle Permian - Late Triassic Eastern Province with mainly subduction-related I-type granites associated with Cu-Au deposits, (2) Late Permian - Early Jurassic Main Range Province with mainly S-type granites associated with Sn-W deposits, and (3) Late Triassic - Cretaceous Western Province with mixed I- and S-type granites associated with Sn-W deposits. These ages were obtained mainly using whole rock Rb-Sr and K-Ar geochronology in the 70s and 80s, methods that are no longer considered suitable for obtaining crystallization ages of granites due to unstable behaviour of these isotopes in hydrothermal systems. During 2011 we collected over 50 samples of granites across all three zones in Northern Malaysia for U-Pb dating using high-spatial resolution precision SIMS at the Swedish Museum of Natural History. The results reveal a westward younging trend across the Malay Peninsula. The Eastern Province hornblende- and biotite-granites in Eastern Malaysia formed by subduction-related processes have ages lying between 220-285 Ma. The Main Range Province dominantly S-type granites in west and central Malaysia have ages lying between 206-226 Ma. These include dominantly biotite granites with less common tourmaline+biotite leucocratic granites related to crustal thickening processes following collision of Sibumasu with Indochina and closing of the Palaeo-Tethyan Bentong-Raub suture zone. Some enigmatic young Cretaceous zircon rim ages (c. 81-80 Ma) may indicate a young hydrothermal - metasomatic origin for some tin mineralization from both the Eastern Province (Tioman Island) and the Western province (Phuket, Thailand) (Searle et al., 2012). Granites in Malaysia cannot be simply categorized as I-, S- or A-type as most of them failed to show distinctive minerals for classification and there is considerable overlap in geochemical

The high-pressure structural configurations of Ca_0.2Sr_0.8Al₂Si ₂O₈ feldspar

DEFF Research Database (Denmark)

Benna, Piera; Nestola, Fabrizio; Boffa Ballaran, Tiziana

2007-01-01

Single-crystal in situ high-P X-ray diffraction was performed at P = 0.0001, 3.2, 4.4, 6.2, and 7.4 GPa on synthetic Ca0.2Sr0.8Al2Si2O8 feldspar (An20SrF80). Data collections conÞ rmed the displacive Þ rst-order triclinic I1-monoclinic I2/c phase transition at P ~4.3 GPa found in a previous high-...

Barren Miocene granitoids in the Central Andean metallogenic belt, Chile: Geochemistry and Nd-Hf and U-Pb isotope systematics

International Nuclear Information System (INIS)

Deckart, Katja; Godoy, Estanislao; Bertens, Alfredo; Jerez, Daniela; Saeed, Ayesha

2010-01-01

Four Middle-to-Late Miocene barren plutonic complexes that occur between the giant porphyry copper deposits of the central Chilean Andes were selected for U-Pb LA-ICPMS geochronology and Hf-isotope systematics on single zircon grains. Major and trace elements and Sr-Nd-Hf isotope whole rock geochemical studies were undertaken to compare with slightly younger or coeval barren and fertile intrusive rocks between 32 o and 34 o S. The studied granitoids yield resolvable crystallization ages of 11.3±0.1 Ma (Cerro Meson Alto massif), 10.3±0.2 Ma (La Gloria pluton), 14.9±0.2 Ma/14.9±0.1 Ma (Yerba Loca stock) and 11.2±0.1 Ma/14.7±0.1 Ma (San Francisco Batholith). Major and trace elements discard an adakitic signature as suggested for coeval porphyric intrusions at 32 o S, slightly younger mineralized porphyries at Rio Blanco-Los Bronces deposit and other Cenozoic adakites. Volcanic host rocks are less fractionated than the intrusive rock units. The same observation can be made for the unmineralized northern plutons compared to the southern ones. Initial Sr-Nd isotope data show insignificant variation (0.703761-0.704118 and 0.512758- 0.512882), plotting in the mantle array. Trace element enrichment can be explained by addition of subducted-slab fluids and/or terrigenous sediments to the mantle wedge prior to and/or slight crustal input during magma ascent. Zircon grains separated from these barren intrusives share a similar initial εHf-data variation for the younger age group (10-12 Ma; 7.04-9.54) and show a more scattered range for the older one (14-15 Ma; 8.50-15.34); both sets plot between the DM and CHUR evolution lines. There is evidence that magma evolution was slightly distinct through time from older to younger barren magmatism, compared to a few fertile porphyritic rocks from Rio Blanco-Los Bronces porphyry copper deposit. It is suggested that chronological inconsistencies within these complexes might be related to differential shortening across the NE

Coral Sr-U Thermometry

Science.gov (United States)

DeCarlo, T. M.; Gaetani, G. A.; Cohen, A. L.; Foster, G. L.; Alpert, A.; Stewart, J.

2016-12-01

Coral skeletons archive the past two millennia of climate variability in the oceans with unrivaled temporal resolution. However, extracting accurate temperature information from coral skeletons is confounded by "vital effects", which often override the temperature dependence of geochemical proxies. Here, we present a new approach to coral paleothermometry based on results of abiogenic precipitation experiments interpreted within a framework provided by a quantitative model of the coral biomineralization process. We conducted laboratory experiments to test the temperature and carbonate chemistry controls on abiogenic partitioning of Sr/Ca and U/Ca between aragonite and seawater, and we modeled the sensitivity of skeletal composition to processes occurring at the site of calcification. The model predicts that temperature can be accurately reconstructed from coral skeleton by combining Sr/Ca and U/Ca ratios into a new proxy, Sr-U. We tested the model predictions with measured Sr/Ca and U/Ca ratios of fourteen Porites sp. corals collected from the tropical Pacific Ocean and the Red Sea, with a subset also analyzed using the boron isotope (δ11B) pH proxy. Observed relationships among Sr/Ca, U/Ca, and δ11B agree with model predictions, indicating that the model accounts for the key features of the coral biomineralization process. We calibrated Sr-U to instrumental temperature records and found that it captures 93% of mean annual variability (26-30 °C) and predicts temperature within 0.5 °C (1 σ). Conversely, Sr/Ca alone has an error of prediction of 1 °C and often diverges from observed temperature by 3 °C or more. Many of the problems afflicting Sr/Ca - including offsets among neighboring corals and decouplings from temperature during coral stress events - are reconciled by Sr-U. By accounting for the influence of the coral biomineralization process, the Sr-U thermometer may offer significantly improved reliability for reconstructing ocean temperatures from coral

Solar Thermochemical Energy Storage Through Carbonation Cycles of SrCO3/SrO Supported on SrZrO3.

Science.gov (United States)

Rhodes, Nathan R; Barde, Amey; Randhir, Kelvin; Li, Like; Hahn, David W; Mei, Renwei; Klausner, James F; AuYeung, Nick

2015-11-01

Solar thermochemical energy storage has enormous potential for enabling cost-effective concentrated solar power (CSP). A thermochemical storage system based on a SrO/SrCO3 carbonation cycle offers the ability to store and release high temperature (≈1200 °C) heat. The energy density of SrCO3/SrO systems supported by zirconia-based sintering inhibitors was investigated for 15 cycles of exothermic carbonation at 1150 °C followed by decomposition at 1235 °C. A sample with 40 wt % of SrO supported by yttria-stabilized zirconia (YSZ) shows good energy storage stability at 1450 MJ m(-3) over fifteen cycles at the same cycling temperatures. After further testing over 45 cycles, a decrease in energy storage capacity to 1260 MJ m(-3) is observed during the final cycle. The decrease is due to slowing carbonation kinetics, and the original value of energy density may be obtained by lengthening the carbonation steps. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Impact of cation stoichiometry on the early stage of growth of SrTiO{sub 3} deposited by pulsed laser deposition

Energy Technology Data Exchange (ETDEWEB)

Xu, Chencheng, E-mail: c.xu@fz-juelich.de; Moors, Marco; Dittmann, Regina

2015-12-30

Highlights: • Stoichiometry dependence of SrTiO{sub 3} sub-monolayer growth monitored by RHEED/AFM. • Reduced surface diffusion of non-stoichiometric SrTiO{sub 3} was detected. • A modified step density model correlates surface diffusion and RHEED minimum. - Abstract: By performing in situ growth studies during pulsed laser deposition, we observed a strong reduction of the surface diffusion coefficients for slightly non-stoichiometric SrTiO{sub 3}. Both, stoichiometric and non-stoichiometric thin films exhibit 2D layer by layer growth. However, in the non-stoichiometric case the 2D island coalescence is significantly delayed, which goes along with a shift of the reflection high electron energy diffraction (RHEED) minimum. We could explain this shift of the RHEED minimum by developing a model for the step density evolution taking into account finite surface diffusion.

CHARACTERIZATION OF THE PARTIALLY PURIFIED PLANTARCIN SR18 PRODUCED BY LACTOBACILLUS PLANTARUM SR18

Directory of Open Access Journals (Sweden)

Wagih El-Shouny

2013-04-01

Full Text Available The bacteriocin bound to the cells and that secreted into the culture filtrate of Lactobacillus plantarum SR18 were precipitated by 75% ammomium sulphate, dialysed and further purified by Gel filtration on Sephadex G-100. Bacteriocins were purified from proteins bound to the cell of L. plantarum SR18 (plantarcin SR18 a and culture filtrate proteins (plantarcin SR18 b, respectively. The SDS-PAGE of partially purified Plantarcin SR18a showed a molecular weight of 3.5 KDa. While, plantarcin SR18 b had a molecular weight of 10.3 KDa. The antibacterial activity of the tested plantarcin SR18 preparations suffered no measurable loss after 45 min at 80ºC. Whereas, At 100ºC, significant decrease in the activity of bacteriocin preparations (60- 80 % took place by the end of 45 min. At pH ranged from 5-8, the activity of the plantarcin SR18 preparations suffered no measurable loss. Dissociating agents significantly affected the bacteriocin activity. Thus, tween 80 and mercaptoethanol increased the activity of bacteriocin preparations to 1.2-1.4 fold. Sodium dodecyl sulphate (SDS increased the activity of the tested bacteriocin preparations by about 20%.The lowest residual activity (60% was recorded after treatment with Triton X100 for 45 min. Protease completely inhibited the activities of all forms of plantarcin SR18 after 45 min at 37ºC.

SHRIMP zircon U-Pb age and its significances of volcanic rocks from banshi basin in south jiangxi province

International Nuclear Information System (INIS)

Wang Baofeng; Wu Jianhua

2011-01-01

SHRIMP zircon U-Pb dating is applied to geochronological study for tuff of original Jilongzhang formation and rhyolite of original Banshi formation in Banshi basin, located in the Sannan (Longnan, Dingnan, Quannan) -Xunwu volcanic rocks belts in the south of Jiangxi. The result shows that zircon SHRIMP U-Pb age of the tuff is (142.5 ± 1.3) Ma and the age of the rhyolite is (131.4 ± 1.3) Ma. According to the latest international stratigraphic chart, the boundary between Jurassic and Cretaceous is (145.4 ± 4.0) Ma. So original Jilongzhang Formation and original Banshi Formation in Banshi basin were formed during early Early Cretaceous. The volcanic series in Banshi basin belongs to only one volcanic cycle. The features of the rock associations consistent with Wuyi group on the Xiajiang-Guangfeng volcanic rocks belts in the north of Jiangxi, so original Jilongzhang formation falls under E'huling formation and original Banshi formation falls under Shixi formation. (authors)

Magnetism in the p-type Monolayer II-VI semiconductors SrS and SrSe

Science.gov (United States)

Lin, Heng-Fu; Lau, Woon-Ming; Zhao, Jijun

2017-01-01

Using density functional theory calculations, we study the electronic and magnetic properties of the p-type monolayer II-VI semiconductors SrX (X = S,Se). The pristine SrS and SrSe monolayers are large band gap semiconductor with a very flat band in the top valence band. Upon injecting hole uniformly, ferromagnetism emerges in those system in a large range of hole density. By varying hole density, the systems also show complicated phases transition among nonmagnetic semiconductor, half metal, magnetic semiconductor, and nonmagnetic metal. Furthermore, after introducing p-type dopants in SrS and SrSe via substitutionary inserting P (or As) dopants at the S (or Se) sites, local magnetic moments are formed around the substitutional sites. The local magnetic moments are stable with the ferromagnetic order with appreciable Curie temperature. The ferromagnetism originates from the instability of the electronic states in SrS and SrSe with the large density of states at the valence band edge, which demonstrates a useful strategy for realizing the ferromagnetism in the two dimensional semiconductors. PMID:28378761

Electronic parameters of Sr2M2O7 (M = V, Nb, Ta) and Sr-O chemical bonding

DEFF Research Database (Denmark)

Atuchin, Victor V.; Grivel, Jean-Claude; Zhang, Zhaoming

2010-01-01

XPS measurements were carried out on Sr2Nb2O7 and Sr2Ta2O7 powder samples, which were synthesized using standard solid state method. The binding energy differences between the O 1s and cation core level, Δ(O-Sr) = BE(O 1s) - BE(Sr 3d5/2), was used to characterize the valence electron transfer...... on the formation of the Sr-O bonds. The chemical bonding effects were considered on the basis of our XPS results for Sr2Nb2O7 and Sr2Ta2O7 and the previously published structural and XPS data for other Sr-oxide compounds. A new empirical relationship between Δ(O-Sr) and L(Sr-O) was obtained. Possible applications...

Age and Isotopic Studies of Some Pan-African Granite from North-Central Nigeria

International Nuclear Information System (INIS)

Breemen, O. van; Pidgeon, R.T.; Bowden, P.

1977-01-01

Twenty-nine Rb-Sr whole-rock isotopic analyses and three U-Pb zircon analyses on foliated granites and largely unfoliated charnockitic rocks indicate that the central part of the Pan-African belt in west Africa was characterised by intense orogenic plutonism. These data and Rb-Sr analyses on muscovite books from late cross-cutting pegmatites indicate that the peak of magmatic activity occurred 610 +- 10 m.y.ago. Initial 87 Sr/ 86 Sr ratios for the granitic and charnockitic rocks are in the range 0.7065-0.7125, and indicate a significantly older crustal component in the magmas

CHEMLAB. A probe for in-situ radionuclide experiments. Diffusion studies

International Nuclear Information System (INIS)

Jansson, Mats; Eriksen, Trygve E.

2001-06-01

CHEMLAB is a borehole laboratory built into a probe, in which in situ experiments can be carried out under ambient conditions with respect to pressure and temperature with the use of natural groundwater from the surrounding rock. The first CHEMLAB experiments, diffusion of cations and anions in compacted bentonite clay, have been carried out in borehole KA2512A at a depth of 320 m in Aespoe Hard Rock Laboratory. Diffusant solutions of Co 2+ , Sr 2+ , Cs + , I - and TcO 4- with 57 Co, 85 Sr, 134 Cs, 131 I and 99 Tc as tracers were used. measured profiles for the radionuclides in the bentonite are in good agreement with profiles predicted from modelling based on apparent diffusivities and sorption coefficients obtained in laboratory experiments with clay compacted to corresponding dry density and synthetic ground water with the same composition as in borehole KA2512A

Systematic variations of 87Sr/56Sr ratios, Sr compositions, selected major-oxide concentrations, and mineral abundances in piston cores from the Red Sea

International Nuclear Information System (INIS)

Boger, P.D.; Boger, J.L.; Faure, G.

1980-01-01

A mixing model is presented which relates the concentrations of Sr to the 87 Sr/ 86 Sr ratios and concentrations of other elements contained in a mixture of two components. The model is applied to the measured 87 Sr/ 86 Sr ratios, Sr, CaO, Fe 2 O 3 and SiO 2 concentrations of the detrital fractions of sediment from three piston cores representing different depositional environments in the Red Sea. The sediment is shown to be a mixture of two components derived from old sialic rocks and young volcanic rocks of the surrounding land masses. One of the cores contained a third component which is identified as authigenic Fe 2 O 3 . Removal of this contaminant is shown to return the system to its original detrital constituents. (Auth.)

Synthesis of Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} whiskers and cross-whisker intrinsic Josephson junction

Energy Technology Data Exchange (ETDEWEB)

Hatano, T.; Takano, Y.; Arisawa, S.; Ishii, A.; Togano, K. [National Research Inst. for Metals, Tsukuba, Ibaraki (Japan); Fukuyo, A. [Science Univ. of Tokyo (Japan)

2001-03-01

A synthesis technique of Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} single-crystal whiskers was studied. The whiskers were synthesized by heating glassy melt-quenched Bi-Sr-Ca-Cu-O (3:2:2:4 in cationic ratio) plates. The atmospheric condition of the whisker growth, especially oxygen partial pressure and gas flow, was investigated. It was found out that the whisker growth rate shows a maximum at P{sub O2}=2/3 bar. For the crystalline quality of the whiskers, the airtight condition was found to be useful as compared to the conventional oxygen stream condition. The crystalline quality, especially the straightness and morphology of the surface, could be improved by keeping the growing whiskers under the equilibrium P{sub Bi} condition. Over 20-mm-long whisker crystals have been successfully synthesized by choosing optimum oxygen partial pressure around the P{sub O2}=2/3 bar in the airtight condition. The growth condition and mechanism of the Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} whiskers were investigated by an in-situ high-temperature x-ray diffraction analysis and an in-situ high-temperature microscope observation. It was found that the whiskers grow in a partially melted state at a temperature of 10-40 degrees below the melting point. The result obtained demonstrates that Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8+{delta}} whiskers grow at their bottom by the conventional liquid-phase growth mechanism, as was proposed by Matsubara et al. (author)

Addition to the analysis of the Sr VI and Sr VII spectra

International Nuclear Information System (INIS)

Wyart, J.F.

1989-01-01

Fifty-six lines of multicharged strontium are measured with an improved wavelength accuracy, or interpreted for the first time. They are 4p-4s, 4p-5s and 4p-4d transitions in Sr VII and 4p-5s transitions in Sr VI. The revision of the singlet-triplet connection in Sr VII is supported by theoretical survey of the ground configuration in Ge-like ions. (orig.)

Cenomanian-? early Turonian minimum age of the Chubut Group, Argentina: SHRIMP U-Pb geochronology

Science.gov (United States)

Suárez, Manuel; Márquez, Marcelo; De La Cruz, Rita; Navarrete, César; Fanning, Mark

2014-03-01

Four new SHRIMP U-Pb zircon ages older than 93 Ma from samples of the two uppermost formations accumulated in two different depocenters (Golfo de San Jorge and Cañadón Asfalto basins) of the Chubut Group in central Argentinean Patagonia, establish a pre-late Cenomanian-? early Turonian age for the group. It also confirms a coeval and comparable evolution of the two depocenters, where distal pyroclastic material was deposited together with fluvial and lacustrine facies.

Síntese in situ pelo método hidrotérmico de heteroestruturas de titanato-ferritas e sua atividade fotocatalítica

Directory of Open Access Journals (Sweden)

B. F. Troque

Full Text Available Resumo A aplicação de fotocatalisadores na forma de heteroestruturas tem se destacado através da propriedade de degradação de diversos compostos orgânicos no tratamento de efluentes. Neste contexto, o objetivo deste trabalho foi sintetizar compostos heteroestruturados à base de titanato-ferritas pelo método hidrotérmico in situ para aplicação em processo foto-Fenton. Os materiais sintetizados in situ foram caracterizados por difratometria de raios X, espectroscopia de infravermelho, espectroscopia de reflectância difusa, área específica superficial por BET e microscopia eletrônica de transmissão. A síntese in situ de SrTiO3-CoFe2O4 e SrTiO3-NiFe2O4 foi desenvolvida de forma inédita neste trabalho, resultando com sucesso em sistemas heteroestruturados sem presença de fases secundárias, distribuição altamente homogênea das fases constituintes com tamanho médio de partículas nanométrico e garantia de reprodutibilidade do método. A atividade fotocatalítica dos compostos sintetizados foi investigada por meio da degradação do corante Rodamina B, utilizando luz visível, onde o sistema SrTiO3-CoFe2O4 apresentou a melhor atividade fotocatalítica degradando 82% do corante.

Contribution on the Northeastern Minas Gerais geologic-geochronologic study, Brazil

International Nuclear Information System (INIS)

Siga Junior, O.; Cordani, U.G.; Basei, M.A.S.; Teixeira, W.; Kawashita, K.

1987-01-01

This work demonstrates the potential of integrated Rb-Sr, K-Ar, and U-Pb determinations, when applied to basic regional geology. The different interpretative values of these methodologies contribute to the understanding of the tectonic processes developed in the south-eastern border of the Sao Francisco Craton (northeastern Minas Gerais). The Brazilian Orogenic Cycle is characterized in the area by the Salinas metasediments and the gneissic-migmatitic rocks of the eastern sector. Rb-Sr and U-Pb data indicate the generation of most or even all of these rocks in the 660-570 Ma, interval. No indications of ancient terrains were obtained, and previous ideas of a pervasive reworking of an Archean or Lower Proterozoic crust must be discarded. The K-Ar analyses indicate a crustal level in which temperature remained above 250 O C until at least 480 Ma. (author)

Strontium (Sr) separation from seawater using titanate adsorbents: Effects of seawater matrix ions on Sr sorption behavior

Science.gov (United States)

Ryu, Jungho; Hong, Hye-jin; Ryu, Taegong; Park, In-Su

2017-04-01

Strontium (Sr) which has many industrial applications such as ferrite magnet, ceramic, and fire works exists in seawater with the concentration of approximately 7 mg/L. In previous report estimating economic potential on recovery of various elements from seawater in terms of their commercial values and concentrations in seawater, Sr locates upper than approximate break-even line, which implies Sr recovery from seawater can be potentially profitable. Recently, Sr separation from seawater has received great attention in the environmental aspect after Fukushima Nuclear Power Plant (NPP) accident which released much amount of radioactive Sr and Cs. Accordingly, the efficient separation of radioactive elements released to seawater has become critical as an important technological need as well as their removal from radioactive wastes. So far, it has been introduced to separate Sr from aqueous media by various methods including solvent extraction, adsorption by solid materials, and ion exchange. Among them, the adsorption technique using solid adsorbents is of great interest for selectively separating Sr from seawater with respect to low concentration level of Sr. In this study, we synthesized titanate nanotube (TiNT) by simple hydrothermal reaction, characterized its physicochemical properties, and systematically evaluated Sr sorption behavior under various reaction conditions corresponding to seawater environment. The synthesized TiNT exhibited the fibril-type nanotube structure with high specific surface area of 260 m2/g. The adsorption of Sr on TiNT rapidly occurred following pseudo-second-order kinetic model, and was in good agreement with Langmuir isotherm model, indicating maximum adsorption capacity of 97 mg/g. Based on Sr uptake and Na release with stoichiometric balance, sorption mechanism of Sr on TiNT was found to be ion-exchange between Na in TiNT lattice and Sr in solution phase, which was also confirmed by XRD and Raman analysis. Among competitive ions, Ca

Input of 87Sr/86Sr ratios and Sr geochemical signatures to update knowledge on thermal and mineral waters flow paths in fractured rocks (N-Portugal)

International Nuclear Information System (INIS)

Marques, J.M.; Carreira, P.M.; Goff, F.; Eggenkamp, H.G.M.; Antunes da Silva, M.

2012-01-01

Strontium isotopes and other geochemical signatures are used to determine the relationships between CO 2 -rich thermal (Chaves: 76 °C) and mineral (Vilarelho da Raia, Vidago and Pedras Salgadas: 17 °C) waters discharging along one of the major NNE–SSW trending faults in the northern part of mainland Portugal. The regional geology consists of Hercynian granites (syn-tectonic-310 Ma and post-tectonic-290 Ma) intruding Silurian metasediments (quartzites, phyllites and carbonaceous slates). Thermal and mineral waters have 87 Sr/ 86 Sr isotopic ratios between 0.716713 and 0.728035. 87 Sr/ 86 Sr vs. 1/Sr define three end-members (Vilarelho da Raia/Chaves, Vidago and Pedras Salgadas thermal and mineral waters) trending from rainfall composition towards that of the CO 2 -rich thermal and mineral waters, indicating different underground flow paths. Local granitic rocks have 87 Sr/ 86 Sr ratios of 0.735697–0.789683. There is no indication that equilibrium was reached between the CO 2 -rich thermal and mineral waters and the granitic rocks. The mean 87 Sr/ 86 Sr ratio of the thermal and mineral waters (0.722419) is similar to the Sr isotopic ratios of the plagioclases of the granitic rocks (0.71261–0.72087). The spatial distribution of Sr isotope and geochemical signatures of waters and the host rocks suggests that the thermal and mineral waters circulate in similar but not the same hydrogeological system. Results from this study could be used to evaluate the applicability of this isotope approach in other hydrogeologic investigations.

A high 87Sr 86Sr mantle source for low alkali tholeiite, northern Great Basin

Science.gov (United States)

Mark, R.K.; Lee, Hu C.; Bowman, H.R.; Asaro, F.; McKee, E.H.; Coats, R.R.

1975-01-01

Olivine tholeiites, the youngest Tertiary units (about 8-11 m.y. old) at five widely spaced localities in northeastern Nevada, are geologically related to the basalts of the Snake River Plain, Idaho, to the north and are similar in major element and alkali chemistry to mid-ocean ridge basalts (MORB) and island arc tholeiites. The measured K (1250-3350 ppm), Rb (1??9-6??2 ppm) and Sr (140-240 ppm) concentrations overlap the range reported for MORB. Three of the five samples have low, unfractionated rare earth element (REE) patterns, the other two show moderate light-REE enrichment. Barium concentration is high and variable (100-780 ppm) and does not correlate with the other LIL elements. The rocks have 87Sr/86Sr = 0??7052-0??7076, considerably higher than MORB (~0??702-0??703). These samples are chemically distinct (i.e. less alkalic) from the olivine tholeiites from the adjacent Snake River Plain, but their Sr isotopic compositions are similar. They contain Sr that is distinctly more radiogenic than the basalts from the adjacent Great Basin. About 10 b.y. would be required for the mean measured Rb/Sr (~ 0??02) of these samples to generate, in a closed system, the radiogenic Sr they contain. The low alkali content of these basalts makes crustal contamination an unlikely mechanism. If the magma is uncontaminated, the time-averaged Rb/Sr of the source material must have been ~0??04. A significant decrease in Rb/Sr of the source material (a factor 2??) thus most probably occurred in the relatively recent (1??09 yr) past. Such a decrease of Rb/Sr in the mantle could accompany alkali depletion produced by an episode of partial melting and magma extraction. In contrast, low 87Sr 86Sr ratios indicate that the source material of the mid-ocean ridge basalts may have been depleted early in the Earth's history. ?? 1975.

Magmatic tempo of Earth's youngest exposed plutons as revealed by detrital zircon U-Pb geochronology.

Science.gov (United States)

Ito, Hisatoshi; Spencer, Christopher J; Danišík, Martin; Hoiland, Carl W

2017-09-29

Plutons are formed by protracted crystallization of magma bodies several kilometers deep within the crust. The temporal frequency (i.e. episodicity or 'tempo') of pluton formation is often poorly constrained as timescales of pluton formation are largely variable and may be difficult to resolve by traditional dating methods. The Hida Mountain Range of central Japan hosts the youngest exposed plutons on Earth and provides a unique opportunity to assess the temporal and spatial characteristics of pluton emplacement at high temporal resolution. Here we apply U-Pb geochronology to zircon from the Quaternary Kurobegawa Granite and Takidani Granodiorite in the Hida Mountain Range, and from modern river sediments whose fluvial catchments include these plutons in order to reconstruct their formation. The U-Pb data demonstrate that the Kurobegawa pluton experienced two magmatic pulses at ~2.3 Ma and ~0.9 Ma; whereas, to the south, the Takidani pluton experienced only one magmatic pulse at ~1.6 Ma. These data imply that each of these magmatic systems were both spatially and temporally distinct. The apparent ~0.7 Myr age gap between each of the three magmatic pulses potentially constrains the recharge duration of a single pluton within a larger arc plutonic complex.

Contributions to the petrography, geochemistry and geochronology (U-Pb and Sm-Nd) of the Paleoproterozoic effusive rocks from Iricoume Group, Amazonian Craton, Brazil

Energy Technology Data Exchange (ETDEWEB)

Marques, Suelen Nonata de Souza; Nascimento, Rielva Solimairy Campelo do, E-mail: suelen-marques@hotmail.com, E-mail: rielva@ufam.edu.br [Universidade Federal do Amazonas (UFAM), Manaus, AM (Brazil). Inst. de Geociencias; Souza, Valmir da Silva; Dantas, Elton Luiz, E-mail: vsouza@unb.br, E-mail: elton@unb.br [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Valerio, Cristovao da Silva, E-mail: cristovao@igeo.ufrr.br [Universidade Federal de Roraima (UFRR), Boa Vista, RR (Brazil). Inst. de Geociencias

2014-07-01

The southernmost region of the Guyana shield, Amazonian craton, hosts large record of Paleoproterozoic effusive rocks of the Iricoume Group. They present remarkably well-preserved igneous textures and structures. The SiO{sub 2} contents reveal a bimodal association marked by a compositional gap between acid (SiO{sub 2} > 67 wt%) and intermediate (SiO{sub 2} < 57.7 wt%) rocks. The acid effusive rocks are rhyolites to rhyodacites with high SiO{sub 2}, alkali, Rb, Zr, Nb + Ta, La + Ce and 104 Ga/Al content and low Fe{sub 2}O{sub 3tot}, TiO{sub 2}, CaO, Sr and Co content. They exhibit subalkaline, metaluminous-to-peraluminous compositions, and geochemically compatible to A-type magmatism emplaced in post-collisional to within-plate tectonic settings. The intermediate rocks are andesitic/basalt to andesite relatively high contents of TiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3total}, MgO, CaO, Sr and Co; low SiO{sub 2}, K{sub 2}O, Rb, Zr, Nb + Ta, La + Ce. They have subalkaline and metaluminous geochemical composition and plot on within-plate basalt field. The acid rocks crystallized at 1882 ± 11 Ma in U-Pb analyses for LA-MC-ICPMS zircon data. The Sm-Nd isotopic data on all rocks reveal a Nd TDM model ages between 2.59 and 2.16 Ga and ε{sub Nd}(t) values between -5.78 and 0.03, indicate that the magmatic evolution was related to the reworking of older Paleoproterozoic at the Rhyacian-Siderian period, continental crust (Transamazonian crust-forming event) with some mixing with a limited amount mantle-derived magmas or with contamination by Archean crust. The petrographic, geochemical and geochronological data presented in this paper suggest a within-plate to post-collisional tectonic setting for the Iricoume volcanism, involving lower crust uplift and generation of basalt magma in an extensional regime. (author)

Small Business Administration (SBA) Loan Program Performance- Charge Off Rates as a Percent of Unpaid Principal Balance (UPB) Amount by Program

Data.gov (United States)

Small Business Administration — Reflects charge off rates, as a percent of the UPB amounts, at the end of the fiscal year for the major loan programs and aggregate totals for the small direct and...

Effects of interaction between ultramafic tectonite and mafic magma on Nd-Pb-Sr isotopic systems in the Neoproterozoic Chaya Massif, Baikal-Muya ophiolite belt

Science.gov (United States)

Amelin, Yuri V.; Ritsk, Eugeni Yu.; Neymark, Leonid A.

1997-04-01

Sm-Nd, Rb-Sr and U-Pb isotopic systems have been studied in minerals and whole rocks of harzburgites and mafic cumulates from the Chaya Massif, Baikal-Muya ophiolite belt, eastern Siberia, in order to determine the relationship between mantle ultramafic and crustal mafic sections. Geological relations in the Chaya Massif indicate that the mafic magmas were emplaced into, and interacted with older solid peridotite. Hand picked, acid-leached, primary rock-forming and accessory minerals (olivine, orthopyroxene, clinopyroxene and plagioclase) from the two harzburgite samples show coherent behavior and yield 147Sm/ 144Nd- 143Nd/ 144Nd and 238U/ 204Pb- 206Pb/ 204Pb mineral isochrons, corresponding to ages of 640 ± 58 Ma (95% confidence level) and 620 ± 71 Ma, respectively. These values are indistinguishable from the crystallization age of the Chaya mafic units of 627 ± 25 Ma (a weighted average of internal isochron Sm-Nd ages of four mafic cumulates). The Rb-Sr and Sm-Nd isotopic systems in the harzburgite whole-rock samples were disturbed by hydrothermal alteration. These alteration-related isotopic shifts mimic the trend of variations in primary isotopic compositions in the mafic sequence, thus emphasizing that isotopic data for ultramafic rocks should be interpreted with great caution. On the basis of initial Sr and Nd values, ultramafic and mafic rocks of the Chaya Massif can be divided into two groups: (1) harzburgites and the lower mafic unit gabbronorites withɛ Nd = +6.6 to +7.1 andɛ Sr = -11 to -16; and (2) websterite of the lower unit and gabbronorites of the upper mafic unit:ɛ Nd = +4.6 to +6.1 andɛ Sr = -8 to -9. Initial Pb isotopic ratios are identical in all rocks studied, with mean values of 206Pb/ 204Pb= 16.994 ± 0.023 and 207Pb/ 204Pb= 15.363 ± 0.015. The similarity of ages and initial isotopic ratios within the first group indicates that the isotopic systems in the pre-existing depleted peridotite were reset by extensive interaction with

Surface characterization, in vitro and in vivo biocompatibility of Mg-0.3Sr-0.3Ca for temporary cardiovascular implant.

Science.gov (United States)

Bornapour, M; Mahjoubi, H; Vali, H; Shum-Tim, D; Cerruti, M; Pekguleryuz, M

2016-10-01

Magnesium-based alloys are attractive candidate materials for medical applications. Our earlier work showed that the ternary Mg-0.3Sr-0.3Ca alloy exhibits slower degradation rates than both binary Mg-Sr and Mg-Ca alloys. The ternary alloy immersed in simulated body fluid (SBF) forms a compact surface layer of corrosion products that we hypothesized to be a Sr-substituted hydroxyapatite (HA). The main objectives of the current work are to understand the bio-degradation mechanism of Mg-0.3Sr-0.3Ca, to identify the exact nature of its protective layer and to evaluate the in vitro and in vivo biocompatibility of the alloy for cardiovascular applications. To better simulate the physiological environment, the alloy was immersed in SBF which was daily refreshed. Raman spectroscopy and X-Ray photoelectron spectroscopy (XPS) confirmed the formation of a thin, Sr-substituted HA layer at the interface between the alloy and the corrosion products. In vitro biocompatibility evaluated via indirect cytotoxicity assays using HUVECs showed no toxicity effect and ions extracted from Mg-0.3Sr-0.3Ca in fact increased the viability of HUVECs after one week. In vivo tests were performed by implanting a tubular Mg-0.3Sr-0.3Ca stent along with a WE43 control stent into the right and left femoral artery of a dog. Post implantation and histological analyses showed no thrombosis in the artery with Mg-0.3Sr-0.3Ca stent after 5weeks of implantation while the artery implanted with WE43 stent was extensively occluded and thrombosed. Microscopic observation of the Mg-0.3Sr-0.3Ca implant-tissue interface confirmed the in situ formation of Sr-substituted HA on the surface during in vivo test. These results show that the interfacial layer protects the surface of the Mg-0.3Sr-0.3Ca alloy both in vitro and in vivo, and is the key factor in the bio-corrosion resistance of the alloy. Copyright © 2016 Elsevier B.V. All rights reserved.

Community-based Approaches to Improving Accuracy, Precision, and Reproducibility in U-Pb and U-Th Geochronology

Science.gov (United States)

McLean, N. M.; Condon, D. J.; Bowring, S. A.; Schoene, B.; Dutton, A.; Rubin, K. H.

2015-12-01

The last two decades have seen a grassroots effort by the international geochronology community to "calibrate Earth history through teamwork and cooperation," both as part of the EARTHTIME initiative and though several daughter projects with similar goals. Its mission originally challenged laboratories "to produce temporal constraints with uncertainties approaching 0.1% of the radioisotopic ages," but EARTHTIME has since exceeded its charge in many ways. Both the U-Pb and Ar-Ar chronometers first considered for high-precision timescale calibration now regularly produce dates at the sub-per mil level thanks to instrumentation, laboratory, and software advances. At the same time new isotope systems, including U-Th dating of carbonates, have developed comparable precision. But the larger, inter-related scientific challenges envisioned at EARTHTIME's inception remain - for instance, precisely calibrating the global geologic timescale, estimating rates of change around major climatic perturbations, and understanding evolutionary rates through time - and increasingly require that data from multiple geochronometers be combined. To solve these problems, the next two decades of uranium-daughter geochronology will require further advances in accuracy, precision, and reproducibility. The U-Th system has much in common with U-Pb, in that both parent and daughter isotopes are solids that can easily be weighed and dissolved in acid, and have well-characterized reference materials certified for isotopic composition and/or purity. For U-Pb, improving lab-to-lab reproducibility has entailed dissolving precisely weighed U and Pb metals of known purity and isotopic composition together to make gravimetric solutions, then using these to calibrate widely distributed tracers composed of artificial U and Pb isotopes. To mimic laboratory measurements, naturally occurring U and Pb isotopes were also mixed in proportions to mimic samples of three different ages, to be run as internal

87Sr/86Sr isotope fingerprinting of Scottish and Icelandic migratory shorebirds

International Nuclear Information System (INIS)

Evans, Jane; Bullman, Rhys

2009-01-01

Biosphere Sr isotope composition data from Iceland and Scotland suggest that terrestrially feeding birds from these two countries will have significantly different 87 Sr/ 86 Sr isotope composition in their tissues. The aim of this study is to test if these differences can be measured within the bone and feather of migratory wading birds, who feed terrestrially as juveniles, thus providing a provenance tool for these birds. The study shows that birds can be distinguished on the basis of the Sr isotope composition of their bone. The field for Icelandic birds is defined by data from juvenile common redshank (Tringa totanus) and whimbrel (Numenius phaeopus) which give 0.7056 ± 0.0012, (2σ, n = 7). The majority of Scottish birds in this study are from coastal regions and have a signature close to that of seawater of 0.7095 ± 0.0006 (2σ, n = 9). The Sr ratios in the body tissue of these two populations of all Icelandic and Scottish adult and juvenile birds analysed are significantly different (p 87 Sr/ 86 Sr values as high as 0.7194 which reflect their non-marine diet. Icelandic redshank (Tringa totanus robusta) that have flown to Scotland and returned to Iceland show the effect of the Scottish contribution to their diet with elevated values of 0.7086 ± 0.0004, (2σ, n = 6). Redshank found in Scotland that cannot be classified on the basis biometric analysis are shown to be of Icelandic origin and analysis of the primary feathers from two birds demonstrates that isotope variation between feathers could be used to track changes in diet related to the timing of individual feather growth.

Geochemie a zirkonové U-Pb stáří derflického granodioritu z dyjského masivu

Czech Academy of Sciences Publication Activity Database

Svojtka, Martin; Breiter, Karel; Ďurišová, Jana; Ackerman, Lukáš; Veselovský, F.; Šmerda, J.

2017-01-01

Roč. 50, č. 1 (2017), s. 17-24 ISSN 0514-8057 R&D Projects: GA ČR GA13-15390S Institutional support: RVO:67985831 Keywords : Bohemian Massif * Cadomian granitoids * Thaya (Dyje) Massif * zircon U-Pb dating Subject RIV: DB - Geology ; Mineralogy OBOR OECD: Geology

Transport of Sr 2+ and SrEDTA 2- in partially-saturated and heterogeneous sediments

Science.gov (United States)

Pace, M. N.; Mayes, M. A.; Jardine, P. M.; McKay, L. D.; Yin, X. L.; Mehlhorn, T. L.; Liu, Q.; Gürleyük, H.

2007-05-01

Strontium-90 has migrated deep into the unsaturated subsurface beneath leaking storage tanks in the Waste Management Areas (WMA) at the U.S. Department of Energy's (DOE) Hanford Reservation. Faster than expected transport of contaminants in the vadose zone is typically attributed to either physical hydrologic processes such as development of preferential flow pathways, or to geochemical processes such as the formation of stable, anionic complexes with organic chelates, e.g., ethylenediaminetetraacetic acid (EDTA). The goal of this paper is to determine whether hydrological processes in the Hanford sediments can influence the geochemistry of the system and hence control transport of Sr 2+ and SrEDTA 2-. The study used batch isotherms, saturated packed column experiments, and an unsaturated transport experiment in an undisturbed core. Isotherms and repacked column experiments suggested that the SrEDTA 2- complex was unstable in the presence of Hanford sediments, resulting in dissociation and transport of Sr 2+ as a divalent cation. A decrease in sorption with increasing solid:solution ratio for Sr 2+ and SrEDTA 2- suggested mineral dissolution resulted in competition for sorption sites and the formation of stable aqueous complexes. This was confirmed by detection of MgEDTA 2-, MnEDTA 2-, PbEDTA 2-, and unidentified Sr and Ca complexes. Displacement of Sr 2+ through a partially-saturated undisturbed core resulted in less retardation and more irreversible sorption than was observed in the saturated repacked columns, and model results suggested a significant reservoir (49%) of immobile water was present during transport through the heterogeneous layered sediments. The undisturbed core was subsequently disassembled along distinct bedding planes and subjected to sequential extractions. Strontium was unequally distributed between carbonates (49%), ion exchange sites (37%), and the oxide (14%) fraction. An inverse relationship between mass wetness and Sr suggested that

U-Pb geochronology documents out-of-sequence emplacement of ultramafic layers in the Bushveld Igneous Complex of South Africa.

Science.gov (United States)

Mungall, James E; Kamo, Sandra L; McQuade, Stewart

2016-11-14

Layered intrusions represent part of the plumbing systems that deliver vast quantities of magma through the Earth's crust during the formation of large igneous provinces, which disrupt global ecosystems and host most of the Earth's endowment of Pt, Ni and Cr deposits. The Rustenburg Layered Suite of the enormous Bushveld Igneous Complex of South Africa has been presumed to have formed by deposition of crystals at the floor of a subterranean sea of magma several km deep and hundreds of km wide called a magma chamber. Here we show, using U-Pb isotopic dating of zircon and baddeleyite, that individual chromitite layers of the Rustenburg Layered Suite formed within a stack of discrete sheet-like intrusions emplaced and solidified as separate bodies beneath older layers. Our U-Pb ages and modelling necessitate reassessment of the genesis of layered intrusions and their ore deposits, and challenge even the venerable concept of the magma chamber itself.

CHEMLAB. A probe for in-situ radionuclide experiments. Diffusion studies

Energy Technology Data Exchange (ETDEWEB)

Jansson, Mats; Eriksen, Trygve E. [Royal Inst. of Technology, Stockholm (Sweden). Dept. of Chemistry

2001-06-01

CHEMLAB is a borehole laboratory built into a probe, in which in situ experiments can be carried out under ambient conditions with respect to pressure and temperature with the use of natural groundwater from the surrounding rock. The first CHEMLAB experiments, diffusion of cations and anions in compacted bentonite clay, have been carried out in borehole KA2512A at a depth of 320 m in Aespoe Hard Rock Laboratory. Diffusant solutions of Co{sup 2+}, Sr{sup 2+}, Cs{sup +}, I{sup -} and TcO{sup 4-} with {sup 57}Co, {sup 85}Sr, {sup 134}Cs, {sup 131}I and {sup 99}Tc as tracers were used. measured profiles for the radionuclides in the bentonite are in good agreement with profiles predicted from modelling based on apparent diffusivities and sorption coefficients obtained in laboratory experiments with clay compacted to corresponding dry density and synthetic ground water with the same composition as in borehole KA2512A.

U-Pb ages for two tonalitic gneisses, pegmatitic granites, and K-feldspar porphyries, Olkiluoto study site, Eurajoki, SW Finland

International Nuclear Information System (INIS)

Maenttaeri, I.; Lindberg, A.; Aaltonen, I.

2007-08-01

Secondary ion microprobe zircon U-Pb ages have been determined for two tonalitic gneisses, two pegmatitic granites, and two potassium feldspar porphyry samples from the Olkiluoto study site, Eurajoki, S-W Finland. Moreover, monazites from the Kfeldspar porphyries were dated using TIMS U-Pb method. The tonalitic gneiss A1879 TTG 1 reveals bimodal zircon population and for A1880 TTG it is homogeneous. The samples yield similar overlapping concordia ages of 1851 ± 5 Ma and 1856 ± 5 Ma, respectively. The pegmatitic granite samples A1881 PGR 1 and A1883 PGR 2 have mostly zircons resembling those of the TTG's. The supposed pegmatitic zircons with high U and low Th are strongly altered. The zircon U-Pb data of A1881 PGR 1 plot roughly in two separate lines on a concordia diagram. The apparently younger ∼1.79 Ga data are all from the high U and low Th/U zircons and therefore certainly set the minimum age for the A1881 PGR 1. It is suggested, that the ∼1.85 Ga data comprise analyses from inherited zircons as it include both lower and higher Th/U zircons and 1.85 Ga coevals with age of the tonalitic gneisses. Thus, the apparent age for the A1881 PGR 1 is ∼1.79 Ga. The U-Pb data of sample A1883 PGR 2 also divide into two groups. The higher Th/U, inherited zircons determine an age of 1852 ± 9 Ma which is the same as that of the TTG's. The low Th/U zircon data scatter and the age of 1.83 Ga for A1883 PGR 2 is only poorly determined. The both potassium feldspar porphyry samples A1882 KFP 1 and A1884 KFP 2 reveal heterogeneous zircon populations. The A1882 KFP 1 zircons showing magmatic zoning in BSE images conceivably determine a concordia age of 1842± 6 Ma for the rock. In addition to that a few ∼1.9 Ga inherited zircon and metamorphic low Th/U rims with ages between 1.88 Ga and 1.83 Ga were detected. The age for the youngest metamorphic zircon rims overlaps with that of the magmatic zircons. The zircons in the other KFP sample A1884 show a wide range of ages

Outline of Upper Precambrian and Lower Paleozoic evolution of the Iberian Peninsula according to U-Pb dating of zircons

International Nuclear Information System (INIS)

Lancelot, J.R.; Allegret, A.; Iglesias Ponce de Leon, M.

1985-01-01

In the northwestern part of the Iberian Peninsula, recent geological studies have defined the following stratigraphic sequence from bottom to top: basal orthogneiss of Miranda do Douro is overlain by a complex of schist and greywacke which have been assigned to the Cambrian or late Precambrian; these are followed by the Ollo de Sapo gneisses of volcanic-sedimentary origin which in turn are overlain by the fossiliferous layers of the lower Ordovician. The schist and greywacke complex and the lower part of the Ollo de Sapo Formation are transected by granitic dikes (Viana del Bollo orthogneiss). All these rocks were folded, faulted, metamorphosed, and intruded by granite plutons during Variscan times. The emplacement of the Miranda do Douro and Viana del Bollo orthogneisses have been respectively dated at 618+-9 Ma and 465+-10 Ma by the U-Pb method on zircons. These data yield lower and upper limits for the deposition of the Ollo de Sapo Formation and demonstrate the occurrence of a Precambrian basement (''Pan-African'' or ''Cadomian'' orogeny) in the Variscan belt in the northwestern part of the Iberian Peninsula. The emplacement of Viana del Bollo orthogneiss could be genetically related to the main phase of crustal thinning (470-520 Ma) characteristic of the Prevariscan evolution of western Europe. Typology and U-Pb data of the Ollo de Sapo zircons indicate the occurrence of inherited old Precambrian zircons and yield an age of 325+-3 Ma for the Variscan main thermal event in the area considered. Four possible evolutionary models for the U-Pb system of the Ollo de Sapo zircons are discussed. (orig.)

New U-Pb zircon ages and the duration and division of Devonian time

Science.gov (United States)

Tucker, R.D.; Bradley, D.C.; Ver Straeten, C.A.; Harris, A.G.; Ebert, J.R.; McCutcheon, S.R.

1998-01-01

Newly determined U-Pb zircon ages of volcanic ashes closely tied to biostratigraphic zones are used to revise the Devonian time-scale. They are: 1) 417.6 ?? 1.0 Ma for an ash within the conodont zone of Icriodus woschmidti/I. w. hesperius Lochkovian); 2) 408.3 ?? 1.9 Ma for an ash of early Emsian age correlated with the conodont zones of Po. dehiscens--Lower Po. inversus; 3) 391.4 ?? 1.8 Ma for an ash within the Po. c. costatus Zone and probably within the upper half of the zone (Eifelian); and 4) 381.1 ?? 1.3 Ma for an ash within the range of the Frasnian conodont Palmatolepis punctata (Pa. punctata Zone to Upper Pa. hassi Zone). U-Pb zircon ages for two rhyolites bracketing a palyniferous bed of the pusillites-lepidophyta spore zone, are dated at 363.8 ?? 2.2 Ma and 363 ?? 2.2 Ma and 363.4 ?? 1.8 Ma, respectively, suggesting an age of ~363 Ma for a level within the late Famennian Pa. g. expansa Zone. These data, together with other published zircon ages, suggest that the base and top of the Devonian lie close to 418 Ma and 362 Ma, respectively, thus lengthening the period of ~20% over current estimates. We suggest that the duration of the Middle Devonian (Eifelian and Givitian) is rather brief, perhaps no longer than 11.5 Myr (394 Ma-382.5 Ma), and that the Emsian and Famennian are the longest stages in the period with estimated durations of ~15.5 Myr and 14.5 Myr, respectively.

U-Pb geochronology of Gangdese (Transhimalaya) plutonism in the Lhasa-Xigaze region, Tibet

International Nuclear Information System (INIS)

Schaerer, U.; Allegre, C.J.; Paris-6 Univ., 75; Paris-7 Univ., 75; Xu, R.H.

1984-01-01

A series of different plutons from the Lhasa-Xigaze segment of the Gangdese (Transhimalaya) belt has been studied by high-resolution U-Pb analyses of zircon (using zircon fractions of 5-100 grains each, selected upon specific grain characteristics). For two diorites, located east of Xigaze (Dazhuka), the zircons yield concordant ages of 93.4 +- 1.0 and 94.2 +- 1.0 m.y., respectively. Also concordant ages of 41.1 +- 0.4 and 41.7 +- 0.4 m.y. have been obtained for two granodiorites, collected southwest of Lhasa (Qushui). The precision on the ages of two granites from the Xigaze and Lhasa area, is limited by two factors: the presence of inherited radiogenic lead and the occurrence of subsequent lead loss. However, some concordant zircons, detected in both granites, define approximate ages of about 67 and 53 m.y., respectively. The inherited lead components show the melting of Precambrian material was involved in magma genesis. The U-Pb ages substantiate a magmatic activity lasting from mid-Cretaceous (Cenomanian) to Eocene (Lutetian) time. Such a period of plutonism at the southern margin of Eurasia, as well as the occurrence of magma generation from continental crust, suggest that the Gangdese range results from the subduction of Tethys oceanic lithosphere (Indian plate) underneath Eurasia (Eurasian plate). If this model is true, the collision of India with Eurasia (Along the Lhasa-Xigaze sector) postdates the emplacement of the 41 m.y. old Gangdese granodiorites, i.e. the collision occurred after Lutetian time. (orig.)

AN INNOVATIVE APPROACH FOR CONSTRUCTING AN IN-SITU BARRIER FOR STRONTIUM-90 AT THE HANFORD SITE WASHINGTON

Energy Technology Data Exchange (ETDEWEB)

FABRE RJ

2008-12-08

Efforts to reduce the flux of Sr-90 to the Columbia River from Hanford Site 100-N Area past-practice liquid waste disposal sites have been underway since the early 1990s. Termination of all liquid discharges to the ground in 1993 was a major step toward meeting this goal. However, Sr-90 adsorbed on aquifer solids beneath liquid waste disposal sites and extending beneath the near-shore riverbed remains a continuing contaminant source to groundwater and the Columbia River. The initial pump-and-treat system proved to be ineffective as a long-term solution because of the geochemical characteristics of Sr-90. Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100-NR-2 Operable Unit hydrogeologic conditions, the U.S. Department of Energy and the Washington State Department of Ecology agreed to evaluate apatite sequestration as the primary remedial technology, combined with a secondary polishing step utilizing phytoextraction if necessary. Aqueous injection was initiated in July 2005 to assess the efficacy of in-situ apatite along the 100 m of shoreline where Sr-90 concentrations are highest. The remedial technology is being developed by Pacific Northwest National Laboratory. CH2M Hill Plateau Remediation Company is implementing this technology in the field with support from PNNL.

Isotopic constraints on contamination processes in the Tonian Goiás Stratiform Complex

Science.gov (United States)

Giovanardi, Tommaso; Mazzucchelli, Maurizio; Lugli, Federico; Girardi, Vicente A. V.; Correia, Ciro T.; Tassinari, Colombo C. G.; Cipriani, Anna

2018-06-01

The Tonian Goiás Stratiform Complex (TGSC, Goiás, central Brazil), is one of the largest mafic-ultramafic layered complexes in the world, emplaced during the geotectonic events that led to the Gondwana accretion. In this study, we present trace elements and in-situ U/Pb-Lu-Hf analyses of zircons and 87Sr/86Sr ratios of plagioclases from anorthosites and gabbros of the TGSC. Although formed by three isolated bodies (Cana Brava, Niquelândia and Barro Alto), and characterized by a Lower and Upper Sequence (LS and US), our new U/Pb zircon data confirm recent geochemical, geochronological, and structural evidences that the TGSC has originated from a single intrusive body in the Neoproterozoic. New Hf and Sr isotope ratios construe a complex contamination history for the TGSC, with different geochemical signatures in the two sequences. The low Hf and high Sr isotope ratios of the Lower Sequence (εHf(t) from -4.2 down to -27.5; 87Sr/86Sr = 0.706605-0.729226), suggest the presence of a crustal component and are consistent with contamination from meta-pelitic and calc-silicate rocks found as xenoliths within the Sequence. The more radiogenic Hf isotope ratios and low Sr isotope composition of the Upper Sequence (εHf(t) from 11.3 down to -8.4; 87Sr/86Sr = 0.702368-0.702452), suggest a contamination from mantle-derived metabasalts in agreement with the occurrences of amphibolite xenoliths in the US stratigraphy. The differential contamination of the two sequences is explained by the intrusion of the TGSC in a stratified crust dominated by metasedimentary rocks in its deeper part and metavolcanics at shallower levels. Moreover, the differential thermal gradient in the two crystallizing sequences might have contributed to the preservation and recrystallization of inherited zircon grains in the US and total dissolution or magmatic overgrowth of the LS zircons via melt/rock reaction processes.

Arc-continent collision of the Coastal Range in Taiwan: Geochronological constraints from U-Pb ages of zircons

Science.gov (United States)

Geng, Wei; Zhang, Xun-Hua; Huang, Long

2018-04-01

The oblique arc-continent collision between the Luzon arc and the southeastern margin of the Eurasian continent caused the uplift of Taiwan. The Coastal Range in eastern Taiwan is the northern section of the Luzon arc in the collision zone and thus records important information about the arc-continent collision. In this paper, we determine and analyze the U-Pb ages of magmatic zircons from the volcanic arc and clastic zircons from the fore-arc basin in the Coastal Range. For the volcanic arc in the Coastal Range, the eruption ages range from 16.8-5 Ma. Given that the initial subduction of the South China Sea oceanic crust (17 Ma) occurred before the Luzon arc formed, we conclude that the volcanic activity of the Coastal Range began at 16.8 ± 1.3 Ma; it was most active from 14 to 8 Ma and continued until approximately 5 Ma. The U-Pb chronology also indicates that the initial stage of arc-continent collision of the Coastal Range started at approximately 5 Ma, when the northern section of the Luzon arc moved away from the magmatic chamber because of the kinematics of the Philippine Sea Plate.

Tithonian age of dinosaur fossils in central Patagonian, Chile: U-Pb SHRIMP geochronology

Science.gov (United States)

Suárez, Manuel; De La Cruz, Rita; Fanning, Mark; Novas, Fernando; Salgado, Leonardo

2016-11-01

Three Tithonian concordant U-Pb SHRIMP zircon ages of 148.7 ± 1.4, 147.9 ± 1.5 and 147.0 ± 1.0 from tuffs intercalated in a clastic sedimentary succession with exceptional dinosaur bones including the new taxon Chilesaurus diegosuarezi gen. et sp. nov. exposed in central Chilean Patagonia (ca. 46°30'S) are reported herein. The fossiliferous beds accumulated in a synvolcanic fan delta reaching a shallow marine basin as indicated by glauconite present in some of the beds, and coeval with the beginning of the transgression of the Aysén Basin.

Permo-Triassic arc-like granitoids along the northern Lancangjiang zone, eastern Tibet: Age, geochemistry, Sr-Nd-Hf isotopes, and tectonic implications

Science.gov (United States)

Wang, Xinyu; Wang, Shifeng; Wang, Chao; Tang, Wenkun

2018-05-01

Large volumes of Permo-Triassic granitoids are exposed along the Northern Lancangjiang zone, eastern Tibet, and these rocks provide insights into the tectonic evolution of the Paleo-Tethys Ocean. We conducted detailed geological fieldwork and geochemical analysis of the Xiaochangdu and Kagong plutons that crop out along the Northern Lancangjiang magmatic belt. Zircon U-Pb data constrain the emplacement of the Xiaochangdu quartz diotites to between 263 and 257 Ma, and the Kagong granites and diorites to between 234 and 232 Ma. The Xiaochangdu quartz diorites are enriched in light rare earth (LREE) and large ion lithophile elements (LILE), depleted in high field strength elements (HFSE), have low (87Sr/86Sr)i ratios, and near-positive εNd(t) (-0.26 to 1.58) and εHf(t) (0.68-8.83) values, similar to typical subduction- related mantle-derived arc magmas. They are also characterized by high Al2O3 concentrations and low Nb/U (3.48-7.59) and Ce/Pb (3.22-4.86) ratios, indicating that their mantle source was modified by subducted pelagic sediments; Coeval granites and diorites from the Kagong pluton exhibit low A/CNK values, high LREE/HREE (heavy rare earth element) ratios, enrichment in LILE, and depletion in HFSE, also characteristic of typical arc magmas. Their variable SiO2 contents (57%- 75%), (87Sr/86Sr)i ratios, and εNd(t) (1.02-4.49) and εHf(t) (2.52-6.93) values, and relatively high zircon saturation temperatures (721-827 °C), suggest underplating of mantle-derived mafic melts beneath the lower crust. Their magmatic evolution can be explained using a MASH model. In combination with regional geological studies, our geochemical and geochronological results suggest that the late Permian Xiaochangdu and Late Triassic Kagong arc-like granitoids represent a section of a Permo-Triassic magmatic arc that was associated with the eastward subduction of the Paleo-Tethys oceanic slab beneath the Northern Qiangtang-Changdu terrane. Combined with other geological evidence

SHRIMP U-Pb zircon dating of Pedras Grandes Suite, southern Santa Catarina State, Brazil

Directory of Open Access Journals (Sweden)

Andréa R. Jelinek

2005-03-01

Full Text Available Two major magmatic pulses of the granitic Florianópolis Batholith in Santa Catarina State, southern Brazil, occurred between 613±5Ma and 595±5 Ma, during the Neoproterozoic Brasiliano Cycle. These ages were obtained by U-Pb isotopic determinations with the sensitive high mass-resolution ion microprobe on igneous zircons from Pedras Grandes Suite in Santa Catarina State. Euhedral zircons remained unaltered close to a fluorite vein deposited at 180?C or more. These ages suggest a northern limit for the Pedras Grandes Suite, explaining the spatial relationship between the fluorite veins and the source rock.Dois dos principais pulsos da atividade granítica no Batólito Florianópolis em Santa Catarina ocorreram entre 613 ±5 Ma e 595 ±5 Ma, durante o Neoproterozóico do Ciclo Brasiliano. Estas idades foram obtidas a partir dedeterminações isotópicas U-Pb em cristais de zircão da Suite Pedras Grandes por "Sensitive high-resolution íon microprobe" - SHRIMP II. Os cristais de zircão permaneceram inalterados mesmo mediante condições hidrotermais com temperaturas iguais e, até mesmo, superiores a 180ºC. Estas idades sugerem a delimitação norte do Maciço Pedras Grandes, explicando a relação espacial existente entre os filões de fluorita e a rocha fonte destas mineralizações.

In situ growth and characterization of La{sub 0.8}Sr{sub 0.2}CoO{sub 3} perovskite mixed conductor films

Energy Technology Data Exchange (ETDEWEB)

Brosha, E.L.; Chung, B.W.; Garzon, F.H.; Raistrick, I.D.; Houlton, R.J.; Hawley, M.E. [Los Alamos National Lab., NM (United States)

1995-05-01

The authors have grown thin films of La{sub 0.8}Sr{sub 0.2}CoO{sub 3} on SrTiO{sub 3} [100], MgO [100], yttrium-stabilized zirconia YSZ [100], and CeO{sub 2} [100]/Al{sub 2}O{sub 3} substrates by using a 90{degree} off-axis RF magnetron sputtering deposition. X-ray diffraction analysis reveals that, depending on substrate, the deposited films grew either epitaxially or highly textured. Scanning tunneling microscopy reveals that the thin films grow with a smooth surface and with different growth mechanisms according to substrate. For La{sub 0.8}Sr{sub 0.2}CoO{sub 3} thin films grown on MgO [100], the low values of the channeling minimum yield from Rutherford backscattering spectroscopy indicated excellent epitaxy with the substrate. Thin films of perovskite materials are among the major focal research areas for optical, sensor, electronic, and superconducting applications.

Thermodynamic assessment of the Pb-Sr system

Directory of Open Access Journals (Sweden)

Zhang H.

2017-01-01

Full Text Available The Pb-Sr system has been critically reviewed and modeled by means of the CALPHAD (CALculation of PHAse Diagrams approach. It contains seven stoichiometric compounds, i.e. SrPb3, Sr3Pb5, Sr2Pb3, SrPb, Sr5Pb4, Sr5Pb3 and Sr2Pb, in which the SrPb3 and Sr2Pb phases melt congruently, and the other five phases form via peritectic reactions. The enthalpies of formation for the intermetallic compounds at 0 K are provided by first-principles calculations. The liquid, fcc and bcc phases are modeled as substitutional solution phases. Both Redlich-Kister and exponential polynomials are used to describe the excess Gibbs energy of the liquid. Two sets of self-consistent thermodynamic parameters are obtained by considering reliable experimental data and the computed enthalpies of formation. Comprehensive comparisons between the calculated and measured phase diagram and thermodynamic data show that the experimental information is satisfactorily accounted for by the present thermodynamic description.

System of Sr(NO2)2-Sr(OH)2-H2O at 25 deg C

International Nuclear Information System (INIS)

Popova, T.B.; Berdyukova, V.A.; Khutsistova, F.M.

1990-01-01

Sr(NO 2 ) 2 -Sr(OH) 2 -H 2 O system was investigated by the methods of solubility, density, viscosity, electric conductivity and refractometry. It was established that its compoments form the compound 4Sr(NO 2 ) 2 xSr(OH) 2 x8H 2 O. The compound was separated from solution; its density, decomposition temperature were determined; IR spectra and X-ray patterns of prepared and initial compounds were obtained

C, Sr and Sr isotopic composition on probable vendian- tommotian carbonate sequences in Nw Argentina

International Nuclear Information System (INIS)

Sial, A. N.; Ferreira, V.P; Toselli, A.J.; Acenolaza, F.G; Pimentel, M.M; Parada, M.A; Alonso, R.N

2001-01-01

C-isotope stratigraphy is one of the most powerfool tools in Precambrian chronostratigraphy, especially when sediments lack recognizable animal fossils. The δ 13 C secular variation curves for marine carbonates in the Neoproterozoic-Cambrian interval show strong positive-negative excursions, several of them interpreted as the stratigraphic position of ancient ice ages (Hoffman et al. 1998). The Sr isotope composition of the seawater for this age interval is characterized by a continuous increase of 87 Sr/ 86 Sr that is interrupted, several times, by sharp rises, which represent important changes in the Earth history (Montanez et al. 2000). Only limited data on the behavior of C and Sr isotopes in carbonates are available in South America. We examine here carbonate sequences from the Argentine Precordillera, San Juan province, and from other carbonate sequences in NW Argentina that could be, potentially, proxies for the Precambrian-Cambrian transition. We have studied their δ 13 C and 87 Sr/ 86 Sr chemostratigraphy and compare it to global C and Sr isotope secular variation curves for this time span. This study aims to improve the relatively coarse stratigraphic resolution provided only by the study of the fossil record in some of the carbonate successions under consideration (au)

Zircon U-Pb ages of Guyana greenstone-gneiss terrane

Energy Technology Data Exchange (ETDEWEB)

Gibbs, A.K. (Cornell Univ., Ithaca, NY (USA)); Olszewski, W.J. Jr. (New Hampshire Univ., Durham (USA))

1982-04-01

Isotopic U-Pb studies of zircons collected from weathered metagreywackes of the Barama-Mazaruni Supergroup of northern Guyana, South America, demonstrate an age of origin of ca. 2250 Ma. This is the best estimate for the age of the associated metavolcanic rocks. Zircons from weathered gneiss of the Bartica complex, adjacent to the volcanic-sedimentary belts, yield a similar age. The contiguous greenstone-gneiss terrane of eastern Venezuela is also of similar age and comparable greenstone-gneiss terranes of eastern Suriname and French Guiana are probably also of this age. Continental crust formation of a style closely comparable to that of the Canadian Archean occurred on a very widespread scale in the Lower Proterozoic of the Guiana shield. The lead losses from the weathered zircons are comparable to those from zircons from fresh rock from the adjacent terrane of Venezuela, and the advantages of field concentration from numerous saprolite exposures warrant use of such material in future geochronological studies of the region.

Measurement of resonance integral of the 90Sr(n,γ)91Sr reaction

International Nuclear Information System (INIS)

Nakamura, Shoji; Furutaka, Kazuyoshi; Wada, Hiroaki; Katoh, Toshio; Harada, Hideo; Fujii, Toshiyuki; Yamana, Hajimu

2001-01-01

To obtain fundamental data for research on nuclear transmutation method of radioactive wastes, the resonance integral (I 0 ) of the 90 Sr(n,γ) 91 Sr reaction was measured with an activation method. (author)

Maurim intrusive suite: a calc-alkacic batholite zoned of catarinense shield

International Nuclear Information System (INIS)

Wildner, W.; Ramgrab, G.E.; Zanini, L.F.P.; Branco, P.M.; Camozzato, E.

1990-01-01

The geological survey of the Florianopolis Sheet (SG.22-Z-D-V) identified and characterized a calc-alkacic multi-intrusive and polydiapiric suite that occurs as a granitic batholite roughly concentric in texture and composition. This co-magmatic plutonic sequence is intrusive in the granite-gneissic basement of amphibolite facies, with which it was formerly confounded. The initial magmatic terms, put-in-place at the marginal portions of the batholite, are represented by quartz-diorites and tonalites (Forquilha Tonalites), followed by granodiorites (alto da Varginha Granodiorite), granodiorites to monzonites (Rio das Antas Granite) and completed by an inner portions of porphyritic monzonites (Sao Pedro de Alcantara Granite). The identifications of the compositional zoning that results from the development of the magmatic chamber is based on the examination of 74 rock samples that were analysed for major and minor oxides and trace elements (Ba, F, Li, Mo, Sn, W, Y, Rb, Nb, Zr and Sr). The treatment of these data shows the portions where mantle fractions predominate as well as the others where crustal meltings dominate, what demonstrates an origin by in situ differentiation processes, fractioning and different degrees of magmatic mixing. Geochronologic dating by Rb/Sr, K/Ar and U/Pb methods show isochronic and conventional ages of 600 to 700 m.y. that roughly are in accord with the temporal progress towards the younger felsic phases, putting this suite in the Upper Proterozoic age. The initial Sr sup(87) / Sr sup(86) ratios, around 0.710, point to a crustal origin with variable mantle contribution to these rocks. (author)

U-Pb dating of large zircons in low-temperature jadeitite from the Osayama serpentinite melange, southwest Japan: insights into the timing of serpentinization

Science.gov (United States)

Tsujimori, T.; Liou, J.G.; Wooden, J.; Miyamoto, T.

2005-01-01

Crystals of zircon up to 3 mm in length occur in jadeitite veins in the Osayama serpentinite mélange, Southwest Japan. The zircon porphyroblasts show pronounced zoning, and are characterized by both low Th/U ratios (0.2-0.8) and low Th and U abundances (Th = 1-81 ppm; U = 6-149 ppm). They contain inclusions of high-pressure minerals, including jadeite and rutile; such an occurrence indicates that the zircon crystallized during subduction-zone metamorphism. Phase equilibria and the existing fluid-inclusion data constrain P-T conditions to P > 1.2 GPa at T > 350°C for formation of the jadeitite. Most U/Pb ages obtained by SHRIMP-RG are concordant, with a weighted mean 206Pb/238U age of 472 ± 8.5 Ma (MSWD = 2.7, n = 25). Because zircon porphyroblasts contain inclusions of high-pressure minerals, the SHRIMP U-Pb age represents the timing of jadeitite formation, i.e., the timing of interaction between alkaline fluid and ultramafic rocks in a subduction zone. Although this dating does not provide a direct time constraint for serpentinization, U-Pb ages of zircon in jadeitite associated with serpentinite result in new insights into the timing of fluid-rock interaction of ultramafic rocks at a subduction zone and the minimum age for serpentinization.

High-Resolution Zircon U-Pb CA-TIMS Dating of the Carboniferous—Permian Successions, Paraná Basin, Brazil

Science.gov (United States)

Griffis, N. P.; Mundil, R.; Montanez, I. P.; Isbell, J.; Fedorchuk, N.; Lopes, R.; Vesely, F.; Iannuzzi, R.

2015-12-01

The late Paleozoic Ice Age (LPIA) is Earth's only record of a CO2-forced climatic transition from an icehouse to greenhouse state in a vegetated world. Despite a refined framework of Gondwanan ice distribution, questions remain about the timing, volume, and synchronicity of high-latitude continental ice and the subsequent deglaciation. These questions ultimately preclude our understanding of linkages between ice volume, sea level, and high- and low-latitude climate. Poor constraints on the timing and synchronicity of glacial and interglacial transitions reflect a lack of high-resolution radioisotopic dates from high-latitude, ice-proximal Carboniferous-Permian successions. The Rio Bonito Fm in Rio Grande do Sul State of southern Brazil hosts the oldest non-glaciogenic Carboniferous- Permian deposits of the Paraná Basin, thus recording the icehouse-to-greenhouse transition. Despite a widespread effort over the last two decades to constrain these deposits in time by means of U-Pb zircon geochronology, published data sets of the Candiota and Faxinal coals of the Rio Bonito Fm host discrepancies that may reflect post- eruptive open system behavior of zircon and analytical artifacts. These discrepancies have hindered the correlation of the Candiota and Faxinal sediments within the larger Gondwanan framework. Here we present the first U-Pb ages on closed system single zircons using CA-TIMS techniques on Permo-Carboniferous ash deposits of the Paraná Basin. Preliminary results indicate two major and distinct coal-forming periods that are separated by ca 10 Ma. Our results and conclusions are not in agreement with multi- crystal U-Pb TIMS and SIMS ages that suggest coeval deposition of the Candiota and Faxinal coals. CA-TIMS analyses applied to zircons from additional ash deposits are aimed at constructing a robust chronostratigraphic framework for the Carboniferous- Permian succession of the Paraná Basin, which will facilitate a better understanding of the timing and

Allogenic and Autogenic Signals in the Detrital Zircon U-Pb Record of the Deep-Sea Bengal Fan

Science.gov (United States)

Blum, M. D.; Rogers, K. G.; Gleason, J. D.; Najman, Y.

2017-12-01

The Himalayan-sourced Ganges-Brahmaputra river system and the deep-sea Bengal Fan represent Earth's largest sediment-dispersal system. This presentation summarizes a new detrital zircon U-Pb (DZ) provenance record from the Bengal Fan from cores collected during IODP Expedition 354, with coring sites located 1350 km downdip from the shelf margin. Each of our 15 samples were collected from medium- to fine-grained turbidite sand and, based on shipboard biostratigraphic analyses, our samples are late Miocene to late Pleistocene in age. Each sample was analyzed by LA-ICPMS at the Arizona Laserchron facility, with an average of n=270 concordant U-Pb ages per sample. Our goals are to use these data to evaluate the influence of allogenic controls vs. autogenic processes on signal propagation from source-to-sink. At the first order, large-scale sediment transfer to the Bengal Fan clearly records the strong tectonic and climatic forcing associated with the Himalayas and Ganges-Brahmaputra system: after up to 2500 km of river transport, and 1350 km of transport in turbidity currents, the DZ record faithfully represents Himalayan source terrains. The sand-rich turbidite part of the record is nevertheless biased towards glacial periods when rivers extended across the shelf in response to climate-forced sea-level fall, and discharged directly to slope canyons. However, only part of the Bengal Fan DZ record represents either the Ganges or the Brahmaputra, with most samples representing varying degrees of mixing of sediments from the two systems: this mixing, or the lack thereof, represents the signal of autogenic avulsions on the delta plain that result in the two river systems delivering sediment separately to the shelf margin, or together as they do today. Within the allogenic framework established by tectonic processes, the climatic system, and global climate-forced sea-level change, the DZ U-Pb record of sediment mixing or the lack thereof provides a fingerprint of autogenic

FEP report for the safety assessment SR-Site

Energy Technology Data Exchange (ETDEWEB)

2010-12-15

This report documents the analysis and processing of features, events and processes, FEPs, that has been carried out within the safety assessment SR-Site, and forms an important part of the reporting of the project. The main part of the work was conducted within the earlier safety assessment SR-Can, which was a preparatory stage for the SR-Site assessment. The overall objective of the FEP analysis and processing in both SR-Can and SR-Site included development of a database of features, events and processes, an SKB FEP database, in a format that facilitates both a systematic analysis of FEPs and documentation of that FEP analysis, as well as facilitating revisions and updates to be made in connection with new safety assessments. The primary objective in SR-Site was to establish an SR-Site FEP catalogue within the framework of the SKB FEP database. This FEP catalogue was required to contain all FEPs that needed to be handled in SR-Site and is an update of the corresponding SR-Can FEP catalogue that was established for the SR-Can assessment. The starting point for the handling of FEPs in SR-Site was the SR-Can version of the SKB FEP database and associated SR-Can reports. The SR-Can version of the SKB FEP database includes the SR-Can FEP catalogue, as well as the sources for the identification of FEPs in SR-Can, namely the SR 97 processes and variables, Project FEPs in the NEA International FEP database version 1.2 and matrix interactions in the Interaction matrices developed for a deep repository of the KBS-3 type. Since the completion of the FEP work within SR-Can, an updated electronic version, version 2.1, of the NEA FEP database has become available. Compared with version 1.2 of the NEA FEP database, version 2.1 contains FEPs from two more projects. As part of SR-Site, all new Project FEPs in version 2.1 of the NEA FEP database have been mapped according to the methodology adopted in SR-Can resulting in an SR-Site version of the SKB FEP database. The SKB FEP

FEP report for the safety assessment SR-Site

International Nuclear Information System (INIS)

2010-12-01

This report documents the analysis and processing of features, events and processes, FEPs, that has been carried out within the safety assessment SR-Site, and forms an important part of the reporting of the project. The main part of the work was conducted within the earlier safety assessment SR-Can, which was a preparatory stage for the SR-Site assessment. The overall objective of the FEP analysis and processing in both SR-Can and SR-Site included development of a database of features, events and processes, an SKB FEP database, in a format that facilitates both a systematic analysis of FEPs and documentation of that FEP analysis, as well as facilitating revisions and updates to be made in connection with new safety assessments. The primary objective in SR-Site was to establish an SR-Site FEP catalogue within the framework of the SKB FEP database. This FEP catalogue was required to contain all FEPs that needed to be handled in SR-Site and is an update of the corresponding SR-Can FEP catalogue that was established for the SR-Can assessment. The starting point for the handling of FEPs in SR-Site was the SR-Can version of the SKB FEP database and associated SR-Can reports. The SR-Can version of the SKB FEP database includes the SR-Can FEP catalogue, as well as the sources for the identification of FEPs in SR-Can, namely the SR 97 processes and variables, Project FEPs in the NEA International FEP database version 1.2 and matrix interactions in the Interaction matrices developed for a deep repository of the KBS-3 type. Since the completion of the FEP work within SR-Can, an updated electronic version, version 2.1, of the NEA FEP database has become available. Compared with version 1.2 of the NEA FEP database, version 2.1 contains FEPs from two more projects. As part of SR-Site, all new Project FEPs in version 2.1 of the NEA FEP database have been mapped according to the methodology adopted in SR-Can resulting in an SR-Site version of the SKB FEP database. The SKB FEP

Changes in local surface structure and Sr depletion in Fe-implanted SrTiO{sub 3} (001)

Energy Technology Data Exchange (ETDEWEB)

Lobacheva, O., E-mail: olobache@gmail.com [Department of Physics and Astronomy, Western University, London, ON N6A 5B7 (Canada); Yiu, Y.M. [Department of Chemistry, Western University, London, ON N6A 5B7 (Canada); Chen, N. [Canadian Light Source, Saskatoon, SK S7N 0X4 (Canada); Sham, T.K.; Goncharova, L.V. [Department of Physics and Astronomy, Western University, London, ON N6A 5B7 (Canada); Department of Chemistry, Western University, London, ON N6A 5B7 (Canada)

2017-01-30

Highlights: • Fe ion implantation of SrTiO{sub 3} and post-implantation results in formation of Sr{sub 1-y}Ti{sub 1-x}Fe{sub x+y}O{sub 3-δ} phase. • In Sr{sub 1-y}Ti{sub 1-x}Fe{sub x+y}O{sub 3-δ} phase, Fe assumes Fe{sup 3+} oxidation state in the bulk and Fe{sup 2+} oxidation state in the near surface area. • FEFF9 calculations indicate that Fe ions can substitute both Ti and Sr sites. • Formation of Sr{sub 1-y}Ti{sub 1-x}Fe{sub x+y}O{sub 3-δ} phase is accompanied by Sr depletion in the near surface region. - Abstract: Local surface structure of single crystal strontium titanate SrTiO{sub 3} (001) samples implanted with Fe in the range of concentrations between 2 × 10{sup 14} to 2 × 10{sup 16} Fe/cm{sup 2} at 30 keV has been investigated. In order to facilitate Fe substitution (doping), implanted samples were annealed in oxygen at 350 °C. Sr depletion was observed from the near-surface layers impacted by the ion-implantation process, as revealed by Rutherford Backscattering Spectrometry (RBS), X-ray photoelectron spectroscopy (XPS), X-ray Absorption Near Edge Spectroscopy (XANES), and Atomic Force Microscopy (AFM). Hydrocarbon contaminations on the surface may contribute to the mechanisms of Sr depletion, which have important implications for Sr(Ti{sub 1-x}Fe{sub x})O{sub 3-δ} materials in gas sensing applications.

In situ X-ray and neutron diffraction of the Ruddlesden-Popper compounds (RE2-xSrx)0.98(Fe0.8Co0.2)1-yMgyO4-δ (RE=La, Pr): Structure and CO2 stability

DEFF Research Database (Denmark)

Chatzichristodoulou, Christodoulos; Hauback, B.C.; Hendriksen, Peter Vang

2013-01-01

The crystal structure of the Ruddlesden-Popper compounds (La 1.0Sr1.0)0.98Fe0.8Co 0.2O4-δ and (La1.2Sr0.8) 0.98(Fe0.8Co0.2)0.8Mg 0.2O4-δ was investigated at 1000 °C in N 2 (aO2=1×10-4) by in-situ powder neutron diffraction. In-situ powder X-ray diffraction (PXD) was also employed to investigate....... The equivalent pseudo-cubic thermal and chemical expansion coefficients are in agreement with values determined by dilatometry. The chemical stability in CO2 containing environments of various Ruddlesden-Popper compounds with chemical formula (RE2-xSr x)0.98(Fe0.8Co0.2) 1-yMgyO4-δ (RE=La, Pr), as well...

Isotopic strontium, carbon and oxygen study on neoproterozoic marbles from Sierra de Umango, Andean Foreland, Argentina

International Nuclear Information System (INIS)

Varela, R; Valencio, S.; Ramos, A; Sato, K; Gonzalez, P; Panarello, H; Roverano, D

2001-01-01

The Umango Hill (La Rioja Province, 29 o 00'S-68 o 40'W) is one of the mountain blocks of Sierras Pampeanas Occidentales (Caminos, 1979), bounded by thrust faults and surrounded by Upper Devonian to Tertiary marine and continental sedimentites. The exposed crystalline basement is composed of basic igneous rocks and a siliciclastic-limestone sequence, both affected by amphibolite facies metamorphic peak. In the southern area (Juchi creek), the metamorphic complex carries relics of granitic orthogneisses, with Rb/Sr and U/Pb dates of ∼1000 Ma (Varela et al., 1996). These ancient inliers were asigned to a Mesoproterozoic Grenville Orogenic Cycle. Granitic bodies, intrusives at different ages in the Metamorphic Complex, have also been distinguished. The most ancient is El Penon Granite, with 469±9 Ma Rb/Sr age (Varela et al., 2000) and 523±26 Ma U/Pb zircon age (unpublished data). In this way it is possible to point out broadly that the siliciclastic-limestone sequence belongs to the Neoproterozoic-Early Palaeozoic times. It was a platform cover over grenvillian cratonic basement. The metamorphism and deformation, we understand, took place in the Early Palaeozoic, related to the Pampean-Famatinian Orogenic Cycle. In this work, compositional and isotopic data of Strontium ( 87 Sr/ 86 Sr), Carbon (δ 13 Cv PDB ) and Oxygen (δ 18 Ov PDB ) of the marbles derived from the siliciclastic-limestone sequence are presented. The results are interpreted and correlated with the temporal variation curves of 87 Sr/ 86 Sr and δ 13 C from Neoproterozoic marine carbonates (Jacobsen and Kaufman, 1999) (au)

New aragonite 87Sr/86Sr records of Mesozoic ammonoids and approach to the problem of N, O, C and Sr isotope cycles in the evolution of the Earth

Science.gov (United States)

Zakharov, Yuri D.; Dril, Sergei I.; Shigeta, Yasunari; Popov, Alexander M.; Baraboshkin, Eugenij Y.; Michailova, Irina A.; Safronov, Peter P.

2018-02-01

New Sr isotope data from well-preserved aragonite ammonoid shell material from the Mesozoic are compared with that from a living Nautilus shell. The prominent negative Sr isotope excursions known from the Middle Permian, Jurassic and Cretaceous probably have their origins in intensive plate tectonic activity, followed by enhanced hydrothermal activity at the mid-ocean ridges (mantle volcanism) which supplied low radiogenic Sr to seawater. The maximum positive (radiogenic) shift in the lower Mesozoic Sr isotope curve (Lower Triassic peak) was likely caused by a significant expansion of dry land surfaces (Dabie-Sulu Triassic orogeny) and their intensive silicate weathering in conditions of extreme warming and aridity in the very end of the Smithian, followed by warm and humid conditions in the late Spathian, which apparently resulted in a significant oceanic input of radiogenic Sr through riverine flux. The comparatively high 87Sr/86Sr ratio obtained from the living Nautilus shell is probably a function of both the Alpine orogeny, which was accompanied by significant continental weathering and input of radiogenic Sr to the oceans, and the weakening of mantle volcanism.

LA-ICP-MS U-Pb apatite dating of Lower Cretaceous rocks from teschenite-picrite association in the Silesian Unit (southern Poland

Directory of Open Access Journals (Sweden)

Szopa Krzysztof

2014-08-01

Full Text Available The main products of volcanic activity in the teschenite-picrite association (TPA are shallow, sub-volcanic intrusions, which predominate over extrusive volcanic rocks. They comprise a wide range of intrusive rocks which fall into two main groups: alkaline (teschenite, picrite, syenite, lamprophyre and subalkaline (dolerite. Previous 40Ar/39Ar and 40K/40Ar dating of these rocks in the Polish Outer Western Carpathians, performed on kaersutite, sub-silicic diopside, phlogopite/biotite as well as on whole rock samples has yielded Early Cretaceous ages. Fluorapatite crystals were dated by the U-Pb LA-ICP-MS method to obtain the age of selected magmatic rocks (teschenite, lamprophyre from the Cieszyn igneous province. Apatite-bearing samples from Boguszowice, Puńców and Lipowa yield U-Pb ages of 103± 20 Ma, 119.6 ± 3.2 Ma and 126.5 ± 8.8 Ma, respectively. The weighted average age for all three samples is 117.8 ± 7.3 Ma (MSWD = 2.7. The considerably smaller dispersion in the apatite ages compared to the published amphibole and biotite ages is probably caused by the U-Pb system in apatite being less susceptible to the effects of hydrothermal alternation than the 40Ar/39Ar or 40K/40Ar system in amphibole and/or biotite. Available data suggest that volcanic activity in the Silesian Basin took place from 128 to 103 Ma with the the main magmatic phase constrained to 128-120 Ma.

Over-expression of SR-cyclophilin, an interaction partner of nuclear pinin, releases SR family splicing factors from nuclear speckles

International Nuclear Information System (INIS)

Lin, C.-L.; Leu, Steve; Lu, M.-C.; Ouyang Pin

2004-01-01

Pre-mRNA splicing takes place within a dynamic ribonucleoprotein particle called the spliceosome and occurs in an ordered pathway. Although it is known that spliceosome consists of five small nuclear RNAs and at least 50 proteins, little is known about how the interaction among the proteins changes during splicing. Here we identify that SR-cyp, a Moca family of nuclear cyclophilin, interacts and colocalizes with nuclear pinin (pnn), a SR-related protein involving in pre-mRNA splicing. Nuclear pnn interacts with SR-cyp via its C-terminal RS domain. Upon SR-cyp over-expression, however, the subnuclear distribution of nuclear pnn is altered, resulting in its redistribution from nuclear speckles to a diffuse nucleoplasmic form. The diffuse subnuclear distribution of nuclear pnn is not due to epitope masking, accelerated protein turnover or post-translational modification. Furthermore, we find that SR-cyp regulates the subnuclear distribution of other SR family proteins, including SC35 and SRm300, in a similar manner as it does on nuclear pnn. This result is significant because it suggests that SR-cyp plays a general role in modulating the distribution pattern of SR-like and SR proteins, similar to that of Clk (cdc2-like kinase)/STY on SR family splicing factors. SR-cyp might direct its effect via either alteration of protein folding/conformation or of protein-protein interaction and thus may add another control level of regulation of SR family proteins and modification of their functions

An Innovative Approach for Constructing an In-Situ Barrier for Strontium-90 at the Hanford Site, Washington - 9325

Energy Technology Data Exchange (ETDEWEB)

Thompson, K. M.; Fabre, Russel J.; Vermeul, Vincent R.; Szecsody, James E.; Fellows, Robert J.; Williams, Mark D.; Fruchter, Jonathan S.

2008-12-10

Efforts to reduce the flux of Sr-90 to the Columbia River from Hanford Site 100-N Area past-practice liquid waste disposal sites have been underway since the early 1990s. Termination of all liquid discharges to the ground in 1993 was a major step toward meeting this goal. However, Sr 90 adsorbed on aquifer solids beneath liquid waste disposal sites and extending beneath the near-shore riverbed remains a continuing contaminant source to groundwater and the Columbia River. The initial pump-and treat system proved to be ineffective as a long-term solution because of the geochemical characteristics of Sr-90. Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100 NR-2 Operable Unit hydrogeologic conditions, the U.S. Department of Energy and the Washington State Department of Ecology agreed to evaluate apatite sequestration as the primary remedial technology, combined with a secondary polishing step utilizing phytoextraction if necessary. Aqueous injection was initiated in July 2005 to assess the efficacy of in-situ apatite along the 100 m of shoreline where Sr-90 concentrations are highest. The remedial technology is being developed by Pacific Northwest National Laboratory. CH2M Hill Plateau Remediation Company is implementing this technology in the field with support from PNNL.

89Sr and 90Sr in atmospheric precipitations in May 1986 in Bucharest-Magurele area

International Nuclear Information System (INIS)

Paunescu, N.; Vata, I.

1987-08-01

Sr-89 and Sr-90 were determined in the fallout of May 1986. The maximum values of 335 Bq/(m 2 * 6 hours) and 110 Bq/(m 2 * 6 hours) were observed at May 2 and 5. Throughout May 1986 a quantity of 860 Bq/m 2 of Sr-90 deposited from the fallout in the Bucharest -Magurele area was determined. (authors)

87Sr/86Sr ratios in hydrothermal waters and deposits from the east pacific rise at 210N

International Nuclear Information System (INIS)

Albarede, F.; Michard, A.; Minster, J.F.; Michard, G.

1981-01-01

87 Sr/ 86 Sr ratios of three hydrothermal waters collected on the East Pacific Rise at 21 0 N define a mixing line between seawater and a hydrothermal end-member at 0.7030 which is derived by seawater-basalt interaction at ca. 350 0 C and water/rock ratio of about 1.5. Sr concentrations are not affected in the process while Mg uptake from seawater is almost complete. Up to 2/3 of this hydrothermal component is involved in anhydrite precipitation while the Sr isotopic ratio in sulfides (chalcopyrite + sphalerite) cannot be distinguished from that of sulfate. It is estimated that ca. 1 x 10 10 moles of strontium are yearly cycled in the hydrothermal systems of mid-oceanic ridges, thereby affecting the 87 Sr/ 86 Sr budget of seawater. Mass balance between river runoff, limestone precipitation and ridge basalt alteration suggests that the 87 Sr/ 86 Sr ratios of the river runoff are in the range 0.7097-0.7113, and are largely dominated by limestone alteration. (orig.)

Synthetic clay excels in 90Sr removal

International Nuclear Information System (INIS)

Komarneni, Sridhar; Kodama, Tatsuya; Paulus, William J.; Carlson, C.

2000-01-01

Tests with actual ground water from Hanford site, and fundamental studies of 2Na + →Sr 2+ exchange equilibria revealed that a synthetic clay is extremely selective for 90 Sr with a high capacity for uptake. Comparative studies with existing Sr selective ion exchangers clearly revealed that the present synthetic clay exhibited the best performance for 90 Sr removal from actual ground water collected from three different locations at Hanford. This novel Sr ion sieve is expected to be useful for the decontamination of the environment after accidental release and contamination with 90 Sr. (c) 2000 Materials Research Society

The influence of Sr on the microstructure, degradation and stress corrosion cracking of the Mg alloys - ZK40xSr.

Science.gov (United States)

Chen, Lianxi; Bin, Yuanhong; Zou, Wenqi; Wang, Xiaojian; Li, Wei

2017-02-01

In the present work, new magnesium (Mg) alloys (Mg-4Zn-0.6Zr-xSr, x=0, 0.4, 0.8, 1.2, 1.6wt%; ZK40xSr) were prepared and studied as potential biodegradable materials. The influence of strontium (Sr) addition on the properties of the new Mg alloys was investigated, which included microstructure, corrosion degradation, and the stress corrosion cracking (SCC) susceptibility. The average grain size of the ZK40Sr was approximately 100µm, which was significantly smaller than that of ZK40 alloy without Sr (402.3±40.2µm). The size of grain boundaries precipitates in the ZK40xSr alloys gradually increased with the increase of Sr content. The grain boundaries finally showed a continuously distribution and net-like shape. The degradation test showed that the average degradation rate of the ZK40xSr alloys increased with the increase of Sr addition. In the case of Mg-4Zn-0.6Zr, the degradation rate was 2.2mgcm -2 day -1 , which was lower than that of Mg-4Zn-0.6Zr-1.6Sr (4.93mgcm -2 day -1 ). When the ZK40xSr alloys were immersed in m-SBF, the rod-like Sr-contained hydroxyapatite (HA) substance was detected, which was known to enhance cell growth around bone implants. The fracture surfaces of the as-cast Mg-4Zn-0.6Zr-1.6Sr were shown intergranular stress corrosion cracking (IGSCC) patterns. The increase of SCC susceptibility of the higher Sr ZK40xSr alloys was attributed to the increase of micro-galvanic corrosion between the α-Mg and the grain boundaries precipitates. The SCC susceptibility values were ≈0.13 and ≈0.41 for the Mg-4Zn-0.6Zr-0.4Sr and the Mg-4Zn-0.6Zr-1.6Sr, respectively. Copyright © 2016 Elsevier Ltd. All rights reserved.

New zircon (U-Th)/He and U/Pb eruption age for the Rockland tephra, western USA

Science.gov (United States)

Coble, Matthew A.; Burgess, Seth D.; Klemetti, Erik W.

2017-09-01

Eruption ages of a number of prominent Quaternary volcanic deposits remain inaccurately and/or imprecisely constrained, despite their importance as regional stratigraphic markers in paleo-environment reconstruction and as evidence of climate-altering eruptions. Accurately dating volcanic deposits presents challenging analytical considerations, including poor radiogenic yield, scarcity of datable minerals, and contamination of crystal populations by magma, eruption, and transport processes. One prominent example is the Rockland tephra, which erupted from the Lassen Volcanic Center in the southern Cascade arc. Despite a range in published eruption ages from 0.40 to 0.63 Ma, the Rockland tephra is extensively used as a marker bed across the western United States. To more accurately and precisely constrain the age of the Rockland tephra-producing eruption, we report U/Pb crystallization dates from the outermost ∼2 μm of zircon crystal faces (surfaces) using secondary ion mass spectrometry (SIMS). Our new weighted mean 238U/206Pb age for Rockland tephra zircon surfaces is 0.598 ± 0.013 Ma (2σ) and MSWD = 1.11 (mean square weighted deviation). As an independent test of the accuracy of this age, we obtained new (U-Th)/He dates from individual zircon grains from the Rockland tephra, which yielded a weighted mean age of 0.599 ± 0.012 Ma (2σ, MSWD = 5.13). We also obtained a (U-Th)/He age of 0.628 ± 0.014 Ma (MSWD = 1.19) for the Lava Creek Tuff member B, which was analyzed as a secondary standard to test the accuracy of the (U-Th)/He technique for Quaternary tephras, and to evaluate assumptions made in the model-age calculation. Concordance of new U/Pb and (U-Th)/He zircon ages reinforces the accuracy of our preferred Rockland tephra eruption age, and confirms that zircon surface dates sample zircon growth up to the time of eruption. We demonstrate the broad applicability of coupled U/Pb zircon-surface and single-grain zircon (U-Th)/He geochronology to accurate

Surface modeling and chemical solution deposition of SrO(SrTiO3)n Ruddlesden-Popper phases

International Nuclear Information System (INIS)

Zschornak, M.; Gemming, S.; Gutmann, E.; Weissbach, T.; Stoecker, H.; Leisegang, T.; Riedl, T.; Traenkner, M.; Gemming, T.; Meyer, D.C.

2010-01-01

Strontium titanate (STO) is a preferred substrate material for functional oxide growth, whose surface properties can be adjusted through the presence of Ruddlesden-Popper (RP) phases. Here, density functional theory (DFT) is used to model the (1 0 0) and (0 0 1) surfaces of SrO(SrTiO 3 ) n RP phases. Relaxed surface structures, electronic properties and stability relations have been determined. In contrast to pure STO, the near-surface SrO-OSr stacking fault can be employed to control surface roughness by adjusting SrO and TiO 2 surface rumpling, to stabilize SrO termination in an SrO-rich surrounding or to increase the band gap in the case of TiO 2 termination. RP thin films have been epitaxially grown on (0 0 1) STO substrates by chemical solution deposition. In agreement with DFT results, the fraction of particular RP phases n = 1-3 changes with varying heating rate and molar ratio Sr:Ti. This is discussed in terms of bulk formation energy.

Construction of the seawater 87Sr/86Sr curve for the Cenozoic and Cretaceous: supporting data

International Nuclear Information System (INIS)

Koepnick, R.B.; Burke, W.H.; Denison, R.E.; Hetherington, E.A.; Nelson, H.F.; Otto, J.B.; Waite, L.E.

1985-01-01

We present the data used to construct the Cenozoic and Cretaceous portion of the Phanerozoic curve of seawater 87 Sr/ 86 Sr that had been given in summary form by W.H. Burke and coworkers. All Cenozoic samples (128) and 22 Cretaceous samples are foram-nannofossil oozes and limestones from DSDP cores distributed among 13 sites in the Atlantic, Pacific and Indian Oceans, and the Caribbean Sea. Non-DSDP Cretaceous samples (126) include limestone, anhydrite and phosphate samples from North America, Europe and Asia. Determination of the 87 Sr/ 86 Sr value of seawater at particular times in the past is based on comparison of ratios derived from coeval marine samples from widely separated geographic areas. The general configuration of the Cenozoic and Cretaceous curve appears to be strongly influenced by the history of plate interactions and sea-floor spreading. Specific rises and falls in the 87 Sr/ 86 Sr of seawater, however, may be caused by a variety of factors such as variation in lithologic composition of the crust exposed to weathering, configuration and topographic relief of continents, volcanic activity, rate of sea-floor spreading, extent of continental inundation by epeiric seas, and variations in both climate and paleo-oceanographic conditions. Many or all of these factors are probably related to global tectonic processes, yet their combined effect on the temporal variation of seawater 87 Sr/ 86 Sr can complicate a direct plate-tectonic interpretation for portions of the seawater curve. (Auth.)

Phase stability study of Bi0.15Sr0.85-xAexCoO3-δ (x = 0 and Ae = Ba0.28; Ca0.17) perovskites by in-situ neutron diffraction

International Nuclear Information System (INIS)

Eriksson, A.K.; Eriksson, S.G.; Chapon, L.C.; Knee, C.S.

2010-01-01

The oxygen deficient perovskites, Bi 0.15 Sr 0.85-x Ae x CoO 3-δ , x = 0 and Ae x = Ba 0.28 , Ca 0.17 , were studied with in-situ neutron powder diffraction and combined TGA/DSC in order to investigate their behaviour at elevated temperatures in oxidising conditions. The phase stability of the I4/mmm supercell structure adopted by Bi 0.15 Sr 0.85 CoO 3-δ is shown to be dependent on temperature and the oxygen content of the phase, with three structural events, at T ∼ 250, 590 and 880 o C, detected. The first transition occurs as the perovskite supercell vanishes due to oxygen absorption; the second transition is also associated with oxidation and involves the decomposition of the perovskite phase via an exothermic process to yield a dominant hexagonal phase. Finally, at T ∼ 900 o C the perovskite phase re-forms. For the Ba and Ca containing materials the decomposition to the hexagonal phase occurs at T ∼ 600 o C and ∼ 650 o C respectively. The presence of Ca at the A-site is found to stabilise the I4/mmm supercell structure in the range RT - 650 o C. The antiferromagnetic to paramagnetic transitions occur at T N ∼ 250 o C, T N ∼ 175 o C and T N ∼ 145 o C for the samples with Ae x = Ba 0.28 , x = 0 and Ae x = Ca 0.17 , respectively.

Precambrian-Cambrian provenance of Matinde Formation, Karoo Supergroup, northwestern Mozambique, constrained from detrital zircon U-Pb age and Lu-Hf isotope data

Science.gov (United States)

Bicca, Marcos Müller; Jelinek, Andrea Ritter; Philipp, Ruy Paulo; de Carvalho Lana, Cristiano; Alkmim, Ana Ramalho

2018-02-01

The Permian-Triassic time interval was a period of high sedimentation rates in the intracontinental Karoo rift basin of northwestern Mozambique, reflecting high exhumation rates in the surrounding high ground Precambrian-Cambrian basement and juxtaposed nappes. U-Pb LA-MC-ICPMS dating and Lu-Hf isotopic analysis of detrital zircons from the Late Permian-Early Triassic Matinde Formation of the Karoo Supergroup is used as a reliable proxy to map denudation patterns of source regions. Data allow discrimination of U-Pb age populations of ca. 1250-900 Ma, a secondary population between ca. 900-700 and a major contribution of ages around ca. 700-490 Ma. Zircon grains of the Mesoproterozoic age population present Mesoproterozoic (1000-1500 Ma) to Paleoproterozoic (1800-2300 Ma) Hf TDM ages, with positive (0 to +11) and negative εHf values (-3 to -15), respectively. The younger U-Pb age population also presents two different groups of zircon grains according to Lu-Hf isotopes. The first group comprise Paleoproterozoic (1800-2300 Ma) ages, with highly negative εHf values, between -10 and -22, and the second group exhibits Mesoproterozoic ages (1200-1500 Ma), with increased juvenile εHf values (ca. 0 to -5). These Hf isotopes reinforce the presence of unexposed ancient crust in this region. The oldest U-Pb age population resembles the late stages of Grenville Orogeny and the Rodinia Supercontinent geotectonic activity mostly represented by magmatic rocks, which are widely present in the basement of northern Mozambique. The juvenile Hf-isotope signature with an older age component is associated to rocks generated from subduction processes with crust assimilation by continental arcs, which we correlate to rocks of the Nampula Complex, south and east of the Moatize-Minjova Basin. The U-Pb ages between 900 and 700 Ma were correlated to the calc-alkaline magmatism registered in the Guro Suite, related to the breakup phase of Rodinia, and mark the western limit of the Moatize

Enthalpies of formation of Cd0.917Sr0.083, Cd0.857Sr0.143 and Cd0.667Sr0.333 intermetallic compounds

International Nuclear Information System (INIS)

Agarwal, Renu; Singh, Ziley

2008-01-01

Cadmium is expected to be the solvent for pyrochemical processing of the metallic nuclear fuel. Therefore, thermodynamic properties of cadmium with various fuel and clad elements are of interest. Enthalpies of formation of the intermetallic compounds of Cd-Sr system, Cd 0.917 Sr 0.083 , Cd 0.857 Sr 0.143 and Cd 0.667 Sr 0.333 were determined by precipitation using Calvet calorimeter. Enthalpies of formation of the compounds were found to be -3.05 ± 0.5 kJ mol -1 at 723 K, -14.2 ± 0.7 kJ mol -1 at 843 K and -28.4 ± 0.8 kJ mol -1 at 863 K, respectively. Enthalpies of formation of Cd 0.917 Sr 0.083 and Cd 0.857 Sr 0.143 were also determined by partial enthalpy of formation measurements and the values were found to be -3.9 ± 1.1 kJ mol -1 at 723 K and -13.42 ± 1.2 kJ mol -1 at 843 K, respectively. Miedema model was used to estimate the enthalpies of formation of these compounds and the estimated values were compared with the experimentally determined values

Thermodynamic Modeling of Sr/TRU Removal

International Nuclear Information System (INIS)

Felmy, A.R.

2000-01-01

This report summarizes the development and application of a thermodynamic modeling capability designed to treat the Envelope C wastes containing organic complexants. A complete description of the model development is presented. In addition, the model was utilized to help gain insight into the chemical processes responsible for the observed levels of Sr, TRU, Fe, and Cr removal from the diluted feed from tank 241-AN-107 which had been treated with Sr and permanganate. Modeling results are presented for Sr, Nd(III)/Eu(III), Fe, Cr, Mn, and the major electrolyte components of the waste (i.e. NO 3 , NO 2 , F,...). On an overall basis the added Sr is predicted to precipitate as SrCO 3 (c) and the MnO 4 - reduced by the NO 2 - and precipitated as a Mn oxide. These effects result in only minor changes to the bulk electrolyte chemistry, specifically, decreases in NO 2 - and CO 3 2- , and increases in NO 3 - and OH - . All of these predictions are in agreement with the experimental observations. The modeling also indicates that the majority of the Sr, TRU's (or Nd(III)/Eu(III)) analogs, and Fe are tied up with the organic complexants. The Sr and permanganate additions are not predicted to effect these chelate complexes significantly owing to the precipitation of insoluble Mn oxides or SrCO 3 . These insoluble phases maintain low dissolved concentrations of Mn and Sr which do not affect any of the other components tied up with the complexants. It appears that the removal of the Fe and TRU'S during the treatment process is most likely as a result of adsorption or occlusion on/into the Mn oxides or SrCO 3 , not as direct displacement from the complexants into precipitates. Recommendations are made for further studies that are needed to help resolve these issues

Using 87Sr/86Sr ratios to investigate changes in stream chemistry during snowmelt in the Provo River, Utah, USA

Science.gov (United States)

Hale, C. A.; Carling, G. T.; Fernandez, D. P.; Nelson, S.; Aanderud, Z.; Tingey, D. G.; Dastrup, D.

2017-12-01

Water chemistry in mountain streams is variable during spring snowmelt as shallow groundwater flow paths are activated in the watershed, introducing solutes derived from soil water. Sr isotopes and other tracers can be used to differentiate waters that have interacted with soils and dust (shallow groundwater) and bedrock (deep groundwater). To investigate processes controlling water chemistry during snowmelt, we analyzed 87Sr/86Sr ratios, Sr and other trace element concentrations in bulk snowpack, dust, soil, soil water, ephemeral channels, and river water during snowmelt runoff in the upper Provo River watershed in northern Utah, USA, over four years (2014-2017). Strontium concentrations in the river averaged 20 ppb during base flow and decreased to 10 ppb during snowmelt runoff. 87Sr/86Sr ratios were around 0.717 during base flow and decreased to 0.715 in 2014 and 0.713 in 2015 and 2016 during snowmelt, trending towards less radiogenic values of mineral dust inputs in the Uinta Mountain soils. Ephemeral channels, representing shallow flow paths with soil water inputs, had Sr concentrations between 7-20 ppb and 87Sr/86Sr ratios between 0.713-0.716. Snowpack Sr concentrations were generally soils that contain accumulated dust deposits with a less radiogenic 87Sr/86Sr ratio. These results suggest that flow paths and atmospheric dust are important to consider when investigating variable solute loads in mountain streams.

Detrital zircon typology and U/Pb geochronology for the Miocene Ladrilleros-Juanchaco sedimentary sequence, Equatorial Pacific (Colombia): New constraints on provenance and paleogeography in northwestern South America

Energy Technology Data Exchange (ETDEWEB)

Osorio-Granada, E.; RESTREPO-MORENO, S.A.; MUÑOZ-VALENCIA, J.A.; TREJOS-TAMAYO, R.A.; PARDO-TRUJILLO, A.; BARBOSA-ESPITIA, A.A.

2017-11-01

Typology and internal texture analyses were performed on detrital zircons obtained from the Miocene sandstones of the Ladrilleros-Juanchaco sedimentary sequence (Colombia, Equatorial Pacific). This analysis was complemented with zircon U/Pb dating to identify typology-age associations as indicators of sediment provenance. Our results show that zircons with S and P dominant typologies have internal structures/zoning indicative of igneous, and potentially also metamorphic, origins. Morphometric results suggest limited transport from source areas. Both typology and U/Pb data point to the western Cordillera as the principal source of detrital materials for this sedimentary sequence. A paleogeographic reconstruction shows that, during the Late Miocene, significant portions of the western Cordillera were uplifted and actively eroding, thereby forming a fluvio-topographic barrier that prevented sediments from the central Cordillera reaching the Pacific basins. Exhumed Miocene plutons located along the axis of the western Cordillera may also have played a role as geomorphologically active massifs. This study demonstrates that typologic analysis on detrital zircon grains is a useful tool for establishing provenance and paleogeography in complex litho-tectonic areas where overlapping U/Pb signatures can lead to contradictory results.

Preparation and crystal structure of SrCu/sub 2/Sb/sub 2/ and SrZnBi/sub 2/

Energy Technology Data Exchange (ETDEWEB)

Cordier, G; Eisenmann, B; Schaefer, H [Technische Hochschule Darmstadt (Germany, F.R.). Fachbereich Anorganische Chemie und Kernchemie

1976-10-01

SrCu/sub 2/Sb/sub 2/ and SrZnBi/sub 2/ have been prepared and analytically and structurally characterized. SrCu/sub 2/Sb/sub 2/ crystallizes tetragonal in the CaBe/sub 2/Ge/sub 2/ structure type. SrZnBi/sub 2/ has its own structure type. In both structures the transition metal atoms form with the semimetal atoms tetragonal pyramids, which are connected by common edges of the basis to twodimensional sheets. These sheets are separated in the case of SrCu/sub 2/Sb/sub 2/ by single sheets of strontium atoms, in the case of SrZnBi/sub 2/ by double sheets of strontium atoms in which fourfold nets of Bi atoms are located.

Testing the fidelity of the Sr/Ca proxy in recording ocean temperature in a western Atlantic coral

Science.gov (United States)

Kuffner, I. B.; Roberts, K.; Flannery, J. A.; Richey, J. N.; Morrison, J. M.

2017-12-01

Massive corals provide a useful archive of environmental variability, but careful testing of geochemical proxies in corals is necessary to validate the relationship between each proxy and environmental parameter throughout the full range of conditions experienced by the recording organisms. Here we use samples from a field-based coral-growth study to test the hypothesis that Sr/Ca in the coral Siderastrea siderea accurately records sea-surface temperature (SST) in the subtropics (Florida, USA) along 350 km of reef tract. We test calcification rate, measured via buoyant weight, and linear extension (LE) rate, estimated with Alizarin Red-S staining, as predictors of variance in the Sr/Ca records of 39 individual S. siderea corals grown at four outer-reef locations next to in-situ temperature loggers during two, year-long periods. We found that corals with calcification rates less than 1.7 mg cm-2 d-1 or LE rates less than 1.7 mm yr-1 returned spuriously high Sr/Ca values, leading to a cold bias in Sr/Ca-based SST estimates. The threshold-type response curves suggest that LE rate can be used as a quality-control indicator during sample and microdrill-path selection when using long cores for SST paleoreconstruction. For our corals that passed this quality control step, the Sr/Ca-SST proxy performed well in estimating mean annual SST across three sites spanning 350 km of the Florida reef tract. However, there was some evidence that extreme temperature stress in 2010 (cold snap) and 2011 (SST above coral-bleaching threshold) may have caused the corals not to record the temperature extremes. Known stress events could be avoided during modern calibrations of paleoproxies.

Spectroscopic and electric dipole properties of Sr+Ar and SrAr systems including high excited states

Science.gov (United States)

Hamdi, Rafika; Abdessalem, Kawther; Dardouri, Riadh; Al-Ghamdi, Attieh A.; Oujia, Brahim; Gadéa, Florent Xavier

2018-01-01

The spectroscopic properties of the fundamental and several excited states of Sr+Ar and SrAr, Van der Waals systems are investigated by employing an ab initio method in a pseudo-potential approach. The potential energy curves and the spectroscopic parameters are displayed for the 1-10 2Σ+, 1-6 2Π and 1-3 2Δ electronic states of the Sr+Ar molecule and for the 1-6 1Σ+, 1-4 3Σ+, 1-3 1,3Π and 1-3 1,3Δ states of the neutral molecule SrAr. In addition, from these curves, the vibrational levels and their energy spacing are deduced for Σ+, Π and Δ symmetries. The spectra of the permanent and transition dipole moments are studied for the 1,3Σ+ states of SrAr, which are considered to be two-electron systems and 2Σ+ states of the single electron Sr+Ar ion. The spectroscopic parameters obtained for each molecular system are compared with previous theoretical and experimental works. A significant correlation revealed the accuracy of our results.

Sr - an element shows the way - Applications of Sr isotopes for provenance, tracing and migration (Invited)

Science.gov (United States)

Prohaska, T.; Irrgeher, J.; Zitek, A.; Teschler Nicola, M.

2010-12-01

Strontium - named after the small Scottish town Strontian - as such is an element with little popularity. Firstly described by Martin Heinrich Klaproth in 1798, the metal is used in metallurgy to some extent whereas its compounds are interesting in glass industries, electronics and pyrotechnics. The element has chemical similarity to Ca and makes up 1/60 of the earth’s amount of the latter. Nonetheless, it is its isotopic composition which makes Sr so interesting for a large number of scientists. The natural composition of the four naturally occurring isotopes (84Sr, 86Sr 87Sr and 88Sr) varies in nature due to the radioactive decay of 87Rb to 87Sr. Thus, it was early recognized as geochronometer especially in Ca rich matrices. With increasing precision of applied methodology, the natural variation of the 87Sr/86Sr isotope ratio (analyzed at first mainly by thermal ionization mass spectrometry (TIMS)) became more and more popular in provenance studies. The natural variation of the ratio is mainly determined by the geological age and the original composition of the rock and can be used therefore as fingerprint of the local geology. The ratio is transferred with no significant fractionation via the water into plants and finally via the food chain into animal and human tissues (especially bones and teeth). As the element is chemically similar to Ca, it appears in most matrices. The use for provenance studies is supported by the fact that the long half life (4.8 x 1010 years) does not lead to an alteration during the time scales which are investigated (from recent samples to human or animal skeletal remains which date back up to 30.000 BC). The uniqueness of the system besides the natural variation is defined by the ubiquity in nature and the relatively high (and thus measurable) elemental concentration in most tissues. It was finally the advent of multiple collector inductively coupled plasma mass spectrometry (MC-ICP-MS) which augmented the number of applications

Evidences of a transamazonic cycle in Cabo Frio region, RJ, Brazil and its correlation with the craton of Angola, Africa

International Nuclear Information System (INIS)

Zimbres, E.; Kawashita, K.; Van Schmus, W.R.

1990-01-01

The U-Pb dating in zircon based on air-abrasion method, whole rock Rb-Sr one, and K-Ar ones in biotite and amphibole of the samples collected from the Cabo Frio Region, Ribeira Orogenic Belt, have been carried out. The concordia diagram of the U-Pb dating indicates 2 different ages: 1981 ± 18 Ma for the upper intersect corresponding to the Transamazonic Cycle, and 488 ± 55 Ma for the lower one, Brazilian Cycle. The former is interpreted as age of zircon formation and the latter, as the time elapsed since epsodic lead loss. The whole rock Rb-Sr dating also shows Transamazonic age: 1799 ± 62 Ma, IR=0.706, and MSWD+0.570. The K-Ar age in amphibole is 571 ± 44 Ma and that in biotite is 474 ± 6 Ma. These data lead to the conclusion that the rocks of this region was formed in the Trasamazonic Cycle and remetamorphosed in the Brazilian Cycle. (author)

Data Reduction of Laser Ablation Split-Stream (LASS) Analyses Using Newly Developed Features Within Iolite: With Applications to Lu-Hf + U-Pb in Detrital Zircon and Sm-Nd +U-Pb in Igneous Monazite

Science.gov (United States)

Fisher, Christopher M.; Paton, Chad; Pearson, D. Graham; Sarkar, Chiranjeeb; Luo, Yan; Tersmette, Daniel B.; Chacko, Thomas

2017-12-01

A robust platform to view and integrate multiple data sets collected simultaneously is required to realize the utility and potential of the Laser Ablation Split-Stream (LASS) method. This capability, until now, has been unavailable and practitioners have had to laboriously process each data set separately, making it challenging to take full advantage of the benefits of LASS. We describe a new program for handling multiple mass spectrometric data sets collected simultaneously, designed specifically for the LASS technique, by which a laser aerosol is been split into two or more separate "streams" to be measured on separate mass spectrometers. New features within Iolite (https://iolite-software.com) enable the capability of loading, synchronizing, viewing, and reducing two or more data sets acquired simultaneously, as multiple DRSs (data reduction schemes) can be run concurrently. While this version of Iolite accommodates any combination of simultaneously collected mass spectrometer data, we demonstrate the utility using case studies where U-Pb and Lu-Hf isotope composition of zircon, and U-Pb and Sm-Nd isotope composition of monazite were analyzed simultaneously, in crystals showing complex isotopic zonation. These studies demonstrate the importance of being able to view and integrate simultaneously acquired data sets, especially for samples with complicated zoning and decoupled isotope systematics, in order to extract accurate and geologically meaningful isotopic and compositional data. This contribution provides instructions and examples for handling simultaneously collected laser ablation data. An instructional video is also provided. The updated Iolite software will help to fully develop the applications of both LASS and multi-instrument mass spectrometric measurement capabilities.

87Sr/86Sr ratios in permo-carboniferous sea water from the analyses of well-preserved brachiopod shells

International Nuclear Information System (INIS)

Popp, B.N.; Anderson, T.F.

1986-01-01

Sr isotopic analyses of well-preserved portions of Permo-Carboniferous brachiopods distributed globally confirm the general shape of the Sr isotope age curve established by previous workers for this time interval. There is little variation between the SR isotopic composition of unaltered portions of brachiopods and that of portions of the same shell interpreted to be diagenetically altered (based on cathodoluminescence, elemental, and stable isotopic data). However, the Sr isotopic composition in diagenetically altered micritic matrix adjacent to the shell is more radiogenic. The Sr isotopic composition in the unaltered portions of calcitic megafossils has potential as a stratigraphic tool. (author)

Reaction of Rb and oxygen overlayers with single-crystalline Bi2Sr2CaCu2O/sub 8+//sub δ/ superconductors

International Nuclear Information System (INIS)

Lindberg, P.A.P.; Shen, Z.; Wells, B.O.; Dessau, D.S.; Mitzi, D.B.; Lindau, I.; Spicer, W.E.; Kapitulnik, A.

1989-01-01

Single crystals of Bi 2 Sr 2 CaCu 2 O/sub 8+//sub δ/ superconductors, in situ cleaved and modified by Rb and oxygen overlayers, have been studied using ultraviolet and x-ray photoemission spectroscopy. The core-level results show that Rb strongly reacts with the Bi and O states, while the Cu and Sr states are left unchanged. This observation strongly indicates that the Bi-O plane forms the surface layer. Subsequent exposure to oxygen results in new oxygen states at the surface as monitored by the O 1s core-level data. For both Rb and oxygen overlayers the valence-band spectra are severely altered. In particular, new valence-band states, presumably of oxygen character, are formed

Review of SR 97 performance assessment

International Nuclear Information System (INIS)

Glynn, P.D.

2000-01-01

This review has identified many technical problems in the SR 97 performance assessment. The general impression of this reviewer is that SKB has been disingenuous in its performance assessment effort. It has not cited important differences of opinion with its own views. Furthermore, there are many inconsistencies in the SR 97 report that all together leave the impression that there are many more uncertainties in the SR 97 performance assessment than SKB would perhaps care to admit. Additionally, despite SKB's statements to the contrary, many of the analyses conducted for the SR 97 performance assessment can be clearly shown not to have been based on 'conservative' assumptions. Finally, SKB has made little effort to consider possible coupling effects between their different scenarios in SR 97. This is a serious flaw in the SR 97 performance assessment. The comments in this review should not be taken to imply that the KBS-3 nuclear waste disposal method will not be able to meet the safety and radiation protection requirements which SKI and SSI have specified in recent years. Instead, my conclusion is simply that the SR 97 performance assessment of the KBS-3 method would have been more believable had it been based on a forthright and comprehensive discussion of facts, uncertainties and opinions, and on a more conservative choice of assumptions. As it stands, the SR 97 performance assessment is not very credible

87Sr/86Sr isotopes in grapes of different cultivars: A geochemical tool for geographic traceability of agriculture products.

Science.gov (United States)

Tescione, Ines; Marchionni, Sara; Casalini, Martina; Vignozzi, Nadia; Mattei, Massimo; Conticelli, Sandro

2018-08-30

87 Sr/ 86 Sr was determined on fresh red and white grapes, soils and rocks from three selected vineyards to verify the isotopic relationships between the fruit of the vine and geologic substrata of vineyards. 87 Sr/ 86 Sr were determined on sampled grapes of four different harvest years and different grape varieties, on bioavailable fraction of soils, on whole soils, and on bedrocks from the geo-pedological substratum of the vineyards. The vineyards chosen for the experimental works belong to an organic farming winery and thus cultivation procedures were strictly controlled. Grapes were sampled during the harvests of four different but consecutive years with 87 Sr/ 86 Sr that does not change reflecting the values of the soil bioavailable fraction. No variations among grapes from different vine cultivars were observed. A strict isotope relationship with soil bio-available fraction was observed. These findings demonstrate the reliability of 87 Sr/ 86 Sr, even at a very small scale, for food products geographic origin assessment. Copyright © 2018 Elsevier Ltd. All rights reserved.

Development of 87Sr/86Sr maps as targeted strategy to support wine quality.

Science.gov (United States)

Durante, Caterina; Bertacchini, Lucia; Cocchi, Marina; Manzini, Daniela; Marchetti, Andrea; Rossi, Maria Cecilia; Sighinolfi, Simona; Tassi, Lorenzo

2018-07-30

This study summarizes the results obtained from a systematic and long-term project aimed at the development of tools to assess the provenance of food in the oenological sector. In particular, 87 Sr/ 86 Sr isotope ratios were measured on statistically representative set of soils, vine branches and wines sampled in the production district of Modena, worldwide known for the Lambrusco wines production. The obtained data were used to build strontium isotopic maps able to objectively support the Lambrusco PDO wines origin as well as other products of the Modena district. Finally, a strong relationship was found between the 87 Sr/ 86 Sr isotope ratios of soils and vine branches on a large scale, highlighting and confirming once more the idea that plants can also represent an optimal sampling device to support geographical traceability. Copyright © 2018 Elsevier Ltd. All rights reserved.

REE, Sm-Nd and U-Pb zircon study of eclogites from the Alpine External Massifs (Western Alps): Evidence for crustal contamination

International Nuclear Information System (INIS)

Paquette, J.L.; Eidgenoessische Technische Hochschule, Zurich; Menot, R.P.; Peucat, J.J.

1989-01-01

A geochemical and geochronological study of the Alpine External Crystalline Massifs (AECM) of Aiguilles Rouges, Belledonne and Argentera was undertaken in order to constrain the geodynamic evolution of this segment of the Variscan foldbelt. Another aim of the study is to characterize the behaviour of isotopic markers, in particular the U-Pb zircon system, under high-grade metamorphic conditions. The whole-rock geochemistry of eclogites and amphibolites was investigated using major and trace element (including the REE) analytical techniques; isotopic studies were performed by application of the Sm-Nd whole-rock and U-Pb zircon methods. In terms of regional geological history, the early development of metamorphic and magmatic activity in the AECM is typical of the extensional tectonic regime observed throughout the Variscan foldbelt during the Cambro-Ordovician (i.e. basic magmatism dated at 475-450 Ma). The composition of the metabasic rocks is closely similar to tholeiites emplaced into thinned continental crust which are generally associated with the initial stages of oceanic rifting. The source regions for these metabasics are characterized by initial ε Nd values between +6 and +8, suggesting depleted mantle sources influenced by a weak crustal component and/or the existence of a metasomatised lithosphere. The multi-stage eclogite-facies metamorphism is dated at 425-395 Ma (i.e. Silurian). An application of the U-Pb method, associated with the artificial abrasion of zircon grains, has led to the recognition of a weak crustal contamination in the metabasic protoliths. This is implied by the Archaean and Lower Proterozoic upper intercepts on Concordia - devoid of geological significance - which reflect the presence of a pre-existing basement to the AECM. (orig./WL)

SHRIMP U-Pb zircon dating of Archean core complex formatio and pancratonic strike-slip deformation in the East Pilbara Granite-Greenstone Terrain

NARCIS (Netherlands)

Zegers, T.E.; Nelson, D.R.; Wijbrans, J.R.; White, S.H.

2001-01-01

Sensitive high-resolution ion microprobe (SHRIMP) U-Pb dating of zircons from granitic rocks in the East Pilbara Granite-Greenstone Terrain has provided time constraints for main tectonic events in the Shaw Granitoid Complex and has shown that deformation was intricately related to granitoid

Rubidium-strontium and uranium-lead isotopic age studies

International Nuclear Information System (INIS)

Loveridge, W.D.

1981-01-01

The results of five Rb-Sr isotopic age studies predominantly on whole-rock samples, and six U-Pb studies on zircon monazite concentrates are presented. Descriptions of the geological problems and interpretations of the measured ages are included. Laboratory age determination methods and techniques are described or referenced

Enhanced provenance interpretation using combined U-Pb and (U-Th)/He double dating of detrital zircon grains from lower Miocene strata, proximal Gulf of Mexico Basin, North America

Science.gov (United States)

Xu, Jie; Stockli, Daniel F.; Snedden, John W.

2017-10-01

Detrital zircon U-Pb analysis is an effective approach for investigating sediment provenance by relating crystallization age to potential crystalline source terranes. Studies of large passive margin basins, such as the Gulf of Mexico Basin, that have received sediment from multiple terranes with non-unique crystallization ages or sedimentary strata, benefit from additional constraints to better elucidate provenance interpretation. In this study, U-Pb and (U-Th)/He double dating analyses on single zircons from the lower Miocene sandstones in the northern Gulf of Mexico Basin reveal a detailed history of sediment source evolution. U-Pb age data indicate that most zircon originated from five major crystalline provinces, including the Western Cordillera Arc (1800 Ma) terranes. Zircon (U-Th)/He ages record tectonic cooling and exhumation in the U.S. since the Mesoproterozoic related to the Grenville to Laramide Orogenies. The combined crystallization and cooling information from single zircon double dating can differentiate volcanic and plutonic zircons. Importantly, the U-Pb-He double dating approach allows for the differentiation between multiple possible crystallization-age sources on the basis of their subsequent tectonic evolution. In particular, for Grenville zircons that are present in all of lower Miocene samples, four distinct zircon U-Pb-He age combinations are recognizable that can be traced back to four different possible sources. The integrated U-Pb and (U-Th)/He data eliminate some ambiguities and improves the provenance interpretation for the lower Miocene strata in the northern Gulf of Mexico Basin and illustrate the applicability of this approach for other large-scale basins to reconstruct sediment provenance and dispersal patterns.

Review of SR 97

International Nuclear Information System (INIS)

Voss, C.I.

2000-01-01

The safety analysis conducted by SKB for SR 97 is impressive in terms of both scale and content. In addition to an eventual solution to Sweden's nuclear waste isolation question, much general scientific knowledge of real value in other applications will be created as a by-product of SKB's efforts. This review focuses on those geoscience aspects of SR 97 that have the most important effects on radionuclide release from each barrier. Indeed, SR 97 elucidates the most important geoscience parameters that control releases from the near field and the far field; these comprise mainly the transport resistance parameter, and the sorption coefficients for each nuclide, the matrix diffusion coefficient, and the Darcy flux. The Main Report is the most important document in SR 97 inasmuch as it is the only one that brings together all of the supporting work to answer the question of safety. Unfortunately pervading the good supporting work done is the impression that the Main Report is not balanced, that it emphasizes optimistic aspects and downplays the negative. SKB specifies 3 main requirements to guarantee proper repository function: a non-oxidizing subsurface environment, temperatures less than 100 C, and a mechanically stable low-permeability buffer surrounding the canisters. The first and third requirements are not thoroughly proven by SKB. One source of near-field doubt stems from the consequences of combinations of scenarios in which several negative events are linked, while the effect of each scenario is mainly evaluated only independently in SR 97. More pertinently, disastrous breakdown of complex systems may occur due to a chain of linked failures. For example, in the glacial scenario: high ground-water flow (possible ablation of buffer and high fluid transport), change in ground-water chemistry (even the possibility of oxidizing conditions), new flow paths, significant changes in mechanical stress and possible motion along faults (which may also generate new flow

Synthesis of Polyaniline-Coated Graphene Oxide@SrTiO3 Nanocube Nanocomposites for Enhanced Removal of Carcinogenic Dyes from Aqueous Solution

Directory of Open Access Journals (Sweden)

Syed Shahabuddin

2016-09-01

Full Text Available The present investigation highlights the synthesis of polyaniline (PANI-coated graphene oxide doped with SrTiO3 nanocube nanocomposites through facile in situ oxidative polymerization method for the efficient removal of carcinogenic dyes, namely, the cationic dye methylene blue (MB and the anionic dye methyl orange (MO. The presence of oxygenated functional groups comprised of hydroxyl and epoxy groups in graphene oxide (GO and nitrogen-containing functionalities such as imine groups and amine groups in polyaniline work synergistically to impart cationic and anionic nature to the synthesised nanocomposite, whereas SrTiO3 nanocubes act as spacers aiding in segregation of GO sheets, thereby increasing the effective surface area of nanocomposite. The synthesised nanocomposites were characterised by field emission scanning electron microscopy (FESEM, transmission electron microscopy (TEM, thermogravimetric analysis (TGA, X-ray diffraction (XRD, and Fourier transform infrared spectroscopy (FTIR. The adsorption efficiencies of graphene oxide (GO, PANI homopolymer, and SrTiO3 nanocubes-doped nanocomposites were assessed by monitoring the adsorption of methylene blue and methyl orange dyes from aqueous solution. The adsorption efficiency of nanocomposites doped with SrTiO3 nanocubes were found to be of higher magnitude as compared with undoped nanocomposite. Moreover, the nanocomposite with 2 wt % SrTiO3 with respect to graphene oxide demonstrated excellent adsorption behaviour with 99% and 91% removal of MB and MO, respectively, in a very short duration of time.

Preparation of Sr adsorptive fiber by impregnating with crown ether derivative for 90Sr measurement

International Nuclear Information System (INIS)

Horita, Takuma; Asai, Shiho; Hanzawa, Yukiko; Kitatsuji, Yoshihiro; Konda, Miki; Saito, Kyoichi; Fujiwara, Kunio; Sugo, Takanobu

2017-01-01

A Sr adsorption fiber was prepared for rapid analysis of 90 Sr content in the fiber using radiation-induced emulsion graft polymerization and subsequent chemical modification. A polyethylene fiber with a diameter of 13 μm was first immersed in a methanol solution of an epoxy-group-containing vinyl monomer, glycidyl methacrylate (GMA), and polyoxyethylene sorbitol ester (Tween20) as a surfactant for the graft-polymerization of GMA. Octadecylamine was then bound to a polymer chain extending from the fiber surface, providing hydrophobicity to the polymer chain. Dicyclohexano-18-crown-6 (DCH18C6) was finally impregnated onto the polymer chain via a hydrophobic interaction between the octadecyl moiety of the polymer chain and the cyclohexyl moiety of DCH18C6. The fiber surface structure, characterized by DCH18C6 molecules loosely entangled with polymer chains, allowed for the rapid adsorption of Sr ions at an adsorption rate of approximately 100-times higher than that of a commercially available Sr-selective resin (Sr Resin ® ). (author)

Preparation of 90Sr-90Y generator

International Nuclear Information System (INIS)

Jin Xiaohai; Yu Haibin; Zhang Jinming; Zhang Peixin; Lin Qiongfang

1990-01-01

In recent years, 90 Y has been considered as one of the best radionuclides for tumor radioimmunotherapy when chelated to tumor-associated antibodies. This evaluation is based on the superior properties of this radionuclide (suitable half-life, pure β-ray emitter of intermediate energy, stable daughters, and suitable chemical properties) and because it is available as a radionuclide generator product by decay of its 28a parent 90 Sr. The experimental conditions of 90 Sr- 90 Y generator are described. The elution efficiency of 90 Sr- 90 Y generator reaches 98%. One of the most important problems is the 90 Sr contamination breakthrough from the generator. The level of 90 Sr contamination must be controlled to the clinical standard. The cation exchange resin 732 (100-150 mesh) was successfully used for the separation of 90 Y from 90 Sr. The method used by the authors provides a 90 Y-HAc solution which is very simple and safe for administration to the patients. 90 Y was separated from 90 Sr almost completely, the level of the 90 Sr contamination per 740 MBq 90 Y product was only 0.74 kBq. However the toxicity of 90 Sr is extremely high, the human life-time permissible dose is 74 kBq, then 740 MBq of 90 Y is allowed to be administrated to a patient for 50-100 times

U-Pb systematics in iron meteorites: uniformity of primordial lead

International Nuclear Information System (INIS)

Goepel, C.; Manhes, G.; Allegre, C.J.

1985-01-01

Pb isotopic compositions and U-Pb abundances were determined in the metal phase of six iron meteorites: Canyon Diablo IA, Toluca IA, Odessa IA, Youndegin IA, Deport IA and Mundrabilla An. Prior to complete dissolution, samples were subjected to a series of leachings and partial dissolutions. Isotopic compositions and abundances of the etched Pb indicate a contamination by terrestrial Pb which is attributable to previous cutting of the meteorite. Pb isotopic compositions measured in the decontaminated samples are identical within 0.2% and essentially confirm the primordial Pb value defined by Tatsumoto et al. (1973). These data invalidate more radiogenic Pb isotopic compositions published for iron meteorites, which are the result of terrestrial Pb contamination introduced mainly by analytical procedure. Our results support the idea of a solar nebula which was isotopically homogeneous for Pb 4.55 Ga ago. The new upper limit for U-abundance in iron meteorites, 0.001 ppb, is in agreement with its expected thermodynamic solubility in the metal phase. (author)

90Sr- 90Y and 89Sr beta radioactivity measurement in milk samples using a proportional counter

International Nuclear Information System (INIS)

Mananes, A.; Perez Santos, C.; Martinez Churiaque, F.

1987-01-01

A thin window glas flow proportional counter is used to measure the 90 Sr- 90 Y and 89 Sr beta radioactivity in milk samples. A chemical procedure is used to separate strontium-yttrium from the other radionuclides present in milk. A calculation of the total efficiency of the system is performed which includes an empirical estimation of the backscattering factor. The calibration of the whole process allows the determination of the 90 Sr activity within 10% relative error in spite of uncertainties in the recovery yields of strontium and yttrium. No 89 Sr activity has been detected, and the mean value obtained for the 90 Sr activity in nine milk samples of Cantabria is 0.115 Bq/1 with a minimum detectable activity of 0.0105 Bq. (author) 18 refs

U-Pb zircon and biostratigraphic data of high-pressure/low-temperature metamorphic rocks of the Talea Ori: tracking the Paleotethys suture in central Crete, Greece

Science.gov (United States)

Zulauf, G.; Dörr, W.; Krahl, J.; Lahaye, Y.; Chatzaras, V.; Xypolias, P.

2016-10-01

Inherited deformation microfabrics of detrital quartz grains and U-Pb (Laser ablation (LA)-ICPMS and ID TIMS) ages of detrital zircons separated from the Phyllite-Quartzite Unit s.l. of the Talea Ori, central Crete, suggest strikingly different source rocks. Albite gneiss of the lower Rogdia Beds includes Cambrian and Neoproterozoic rounded zircons with main U-Pb age peaks at 628 and 988 Ma. These and minor Paleoproterozoic and Archean peaks, together with the lack of Variscan-aged and Mesoproterozoic zircons, are similar to the age spectra obtained from the Phyllite-Quartzite Unit s.str. of the Peloponnesus and eastern Crete and from the Taurides. All of these zircons should be derived from the northeastern passive margin of Gondwana (Cimmeria). Metatuffites of the uppermost Rogdia Beds and metasandstone of Bali beach, on the other hand, include euhedral detrital zircons displaying a Variscan U-Pb age spectra at ca. 300 Ma with concordia ages at 291 ± 3, 300 ± 1 Ma (Rogdia) and 286 ± 3, 300 ± 3, 313 ± 2 Ma (Bali). Both types of metasediments and their zircons are similar to those of the pre-Alpine basement and overlying Tyros Beds of eastern Crete, revealing a provenance at the southern active margin of Laurasia. Thus, in central Crete the Paleotethys suture should be situated inside the Rogdia Beds. Magmatic zircons separated from a rhyolite boulder of the lower Achlada Beds yielded a concordant U-Pb zircon age at 242 ± 2 Ma placing a maximum age for the deposition of the (meta)conglomerate from which the boulder was collected. This age is compatible with an Olenekian-early Anisian age of the underlying Vasilikon marble suggested by new findings of the foraminifera Meandrospira aff. pusilla. Both the Achlada Beds and the Vasilikon marble can be attributed to the lower Tyros Beds of eastern Crete. The Alpine deformation led to a pervasive mylonitic foliation, which is affecting most of the studied rocks. This foliation results from D2 top

Similar sediment provenance of low and high arsenic aquifers in Bangladesh

Science.gov (United States)

Zheng, Y.; Yang, Q.; Li, S.; Hemming, S. R.; Zhang, Y.; Rasbury, T.; Hemming, G.

2017-12-01

Geogenic arsenic (As) in drinking water, especially in groundwater, is estimated to have affected the health of over 100 million people worldwide, with nearly half of the total at risk population in Bangladesh. Sluggish flow and reducing biogeochemical environment in sedimentary aquifers have been shown as the primary controls for the release of As from sediment to the shallower groundwater in the Holocene aquifer. In contrast, deeper groundwater in the Pleistocene aquifer is depleted in groundwater As and sediment-extractable As. This study assesses the origin of the sediment in two aquifers of Bangladesh that contain distinctly different As levels to ascertain whether the source of the sediment is a factor in this difference through measurements of detrital mica Ar-Ar age, detrital zircon U-Pb age, as well as sediment silicate Sr and Nd isotopes. Whole rock geochemical data were also used to illuminate the extent of chemical weathering. Detrital mica 40Ar/39Ar cooling ages and detrital zircon U-Pb ages show no statistical difference between high-As Holocene sediment and low-As Pleistocene sediment, but suggest an aquifer sediment source of both the Brahmaputra and the Ganges rivers. Silicate 87Sr/86Sr and 143Nd/144Nd further depict a major sediment source from the Brahmaputra river, which is supported by a two end member mixing model using 87Sr/86Sr and Sr concentrations. Pleistocene and Holocene sediments show little difference in weathering of mobile elements including As, while coarser sediments and a longer history of the Pleistocene aquifer suggest that sorting and flushing play more important roles in regulating the contrast of As occurrence between these two aquifers.

Peculiarities of Sr-90 migration in the environment

International Nuclear Information System (INIS)

Romanov, G.N.; Stukin, D.A.; Aleksakhin, R.M.

1991-01-01

The Eastern Urals radioactive track which formed as a result of the Kyshtym accident constituted a natural experimental base for studying the dynamics of Sr-90 behaviour and migration in the environment. Sr-90 behaviour in soil depends on the processes involved in its physical migration horizontally (water runoff, wind transport) and vertically (effective diffusion), on the intensity with which the physico-chemical forms of strontium change, and primarily on Sr-90 incorporation into the soil-absorptive complex. Over 30 years the effective diffusion processes led to downward displacement of Sr-90 in undisturbed soil to a depth of 30 to 50 cm. In 1988 84-94% of the Sr-90 was located in the 10 cm layer as against 90% in the 2 cm layer in the initial 1 or 2 years. The amount of Sr-90 in mobile forms in leached chernozem and grey forest soil hardly changed over time, amounting to between 76 and 90%. In the first 5-10 years Sr-90 surface water runoff was about 0.2% (and Sr-90 wind resuspension 0.1-1.0%) per year of the Sr-90 inventory per unit area. Due to Sr-90 loss from the top soil layer the water runoff and wind resuspension processes decreased exponentially, halving every 4 to 5 years. In most cases, Sr-90 transfer from soil to plants via the roots does not involve discrimination of Sr-90 with regard to calcium, and therefore the Sr-90 accumulation level in various species of natural and agricultural plants depends on their calcium requirements and the amount of exchangeable calcium in the soil. This made it possible to work out quantitative indices for forecasting Sr-90 accumulation in various species of plants for given types of soil. As Sr-90 moves through the trophic chains (including the agricultural one) we find - depending on whether two adjoining links discriminate against it or not as regards calcium - that some organisms reject it while others concentrate it. When restoring farming on the contaminated territory the fact that cattle discriminated against Sr

Operando and in situ X-ray spectroscopies of degradation in La0.6Sr0.4Co0.2Fe0.8O(3-δ) thin film cathodes in fuel cells.

Science.gov (United States)

Lai, Samson Y; Ding, Dong; Liu, Mingfei; Liu, Meilin; Alamgir, Faisal M

2014-11-01

Information from ex situ characterization can fall short in describing complex materials systems simultaneously exposed to multiple external stimuli. Operando X-ray absorption spectroscopy (XAS) was used to probe the local atomistic and electronic structure of specific elements in a La0.6Sr0.4Co0.2Fe0.8O(3-δ) (LSCF) thin film cathode exposed to air contaminated with H2O and CO2 under operating conditions. While impedance spectroscopy showed that the polarization resistance of the LSCF cathode increased upon exposure to both contaminants at 750 °C, XAS near-edge and extended fine structure showed that the degree of oxidation for Fe and Co decreases with increasing temperature. Synchrotron-based X-ray photoelectron spectroscopy tracked the formation and removal of a carbonate species, a Co phase, and different oxygen moieties as functions of temperature and gas. The combined information provides insight into the fundamental mechanism by which H2O and CO2 cause degradation in the cathode of solid oxide fuel cells. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Geology and U-Pb geochronology of the Banabuiu granite, Northeastern Ceara, Brazil; Geologia y geocronologia U-Pb del granito de Banabuiu, Noreste de Ceara, Brasil

Energy Technology Data Exchange (ETDEWEB)

Lima, M. N.; Nogueira Neto, J. A.; Azevedo, M. R.; Valle Aguado,

2010-07-01

The Banabuiu massif crops out in the Central Ceara Domain (DCC) of the Borborema Province (NE Brasil), as an N-S elongate granite intrusion, concordant with the regional structures. It was emplaced into basement rocks of Paleoproterozoic age, extensively transformed into gneisses and migmatites during the Brasilian orogeny ({approx}600 Ma). Using U-Pb zircon dating, the crystallization age of the Banabuiu syn-kinematic two-mica granite was estimated at 578.6 {+-} 6.5 Ma. The granite is strongly peraluminous (A/CNK 1,098 - 1,134) and shows a typical S-type geochemical signature. The {epsilon}Nd{sub 5}80 values are strongly negative ({epsilon}Nd{sub 5}80 = -19 a - 23) and partially overlap with those of the Paleoproterozoic gneissmigmatite complex ({epsilon}Nd{sub 5}80 = -12 to -26), suggesting that the parental magmas of the Banabuiu granite could have been produced by partial melting of similar crustal materials. (Author) 21 refs.

Joining and interface characterization of in situ reinforced silicon nitride

Energy Technology Data Exchange (ETDEWEB)

Asthana, R., E-mail: asthanar@uwstout.edu [Department of Engineering and Technology, 326 FH, University of Wisconsin-Stout, Menomonie, WI 54751 (United States); Singh, M., E-mail: Mrityunjay.Singh@nasa.gov [Ohio Aerospace Institute, NASA Glenn Research Center, Cleveland, OH 44135 (United States); Martinez-Fernandez, J., E-mail: Martinez@us.es [Dpto. Física de la Materia Condensada-ICMSE, Universidad de Sevilla-CSIC, Avda. Reina Mercedes, s/n, 41012 Sevilla (Spain)

2013-03-05

Highlights: ► AS800 Si{sub 3}N{sub 4} brazed using oxidation-resistant, high use-temperature braze Cu-ABA. ► Interface enriched in Ti and Si but not in Y, La, and Sr (from Y{sub 2}O{sub 3}, La{sub 2}O{sub 3} and SrO). ► Rapid early-stage kinetic evident in constant layer thickness, composition with time. ► Highly textured large grains of Cu and features associated with plastic deformation. -- Abstract: Copper-base active metal interlayers were used to bond in situ reinforced silicon nitride (Honeywell AS800) at 1317 K for 5 and 30 min in vacuum. The joints were characterized using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), electron back scattered diffraction (EBSD), and transmission electron microscopy (TEM). A Ti-rich interaction zone (∼3.0–3.5 μm thick) formed at the Si{sub 3}N{sub 4}/braze interface. This reaction layer grew toward the inner part of the joint with a featureless microstructure, creating a strong bond. Regions of a Ti-rich phase were frequently found next to the reaction layer but surrounded by the Cu alloy. Extensive Ti and Si enrichments were noted at the interface but there was no evidence of interfacial segregation of Y, La, and Sr (from Y{sub 2}O{sub 3}, La{sub 2}O{sub 3} and SrO, added as sintering aids). The reaction layer thickness and composition did not change when brazing time increased from 5 min to 30 min suggesting rapid growth kinetics in the early stages of reaction. The joints were crack-free and showed features associated with plastic deformation, which indicated that the metal interlayer accommodated strain associated with CTE mismatch. The inner part of the joint consisted of highly textured large grains of the braze alloy.

Applicability of 87Sr/86Sr in examining return flow of irrigation water in highly agricultural watersheds in Japan

Science.gov (United States)

Yoshida, T.; Nakano, T.; Shin, K. C.; Tsuchihara, T.; Miyazu, S.; Kubota, T.

2017-12-01

Water flows in watersheds containing extensive areas of irrigated paddies are complex because of the substantial volumes involved and the repeated cycles of water diversion from, and return to, streams. For better management of low-flow conditions, numerous studies have attempted to quantify the return flow using the stable isotopes of water; however, the temporal variation in these isotopic compositions due to fractionation during evaporation from water surfaces hinders their application to watersheds with extensive irrigated paddies. In this study, we tested the applicability of the strontium isotopes (87Sr/86Sr, hereafter Sr ratio) for studying hydrological processes in a typical agricultural watershed located on the alluvial fan of the Kinu River, namely the Gogyo River, in central Japan. The Sr ratio of water changes only because of interactions with the porous media it flows through, or because of mixing with water that has different Sr ratios. We sampled water both at a single rice paddy, and on the watershed scale in the irrigated and non-irrigated periods. The soil water under the paddy decreased as sampling depth increased, and the soil water at a depth of 1.5 m showed a similar Sr ratio to the spring. The water sampled in the drainage channel with a concrete lined bottom showed a similar Sr ratio to the irrigation water, whereas that with a soil bottom was plotted between the plots of the irrigation water and shallow aquifer. These results suggest the Sr ratio decreases as it mixes with the soil water through percolation; whereas the Sr ratio will be less likely to change when water drains from paddies via surface pathways. The streamflow samples were plotted linearly on the Sr ratio and 1/Sr plot, indicating that the streamflow was composed of two end-members; the irrigation water and the shallow aquifer. The continuous decline in the Sr ratio along the stream suggests an exfiltration of water from the shallow aquifers. The stream water during the non

Extrapolation of tectonic boundaries across the Labrador shelf: U-Pb geochronology of well samples

International Nuclear Information System (INIS)

Wasteneys, H.A.; Krogh, T.E.

1996-01-01

Near Saglek Fiord, a northerly trending boundary between the early Archean Saglek block and the middle Archean Hopedale block extends between drill sites which, respectively, sampled Uivak amphibolite gneiss with U-Pb zircon intercept ages of 3742 ± 12 and 2752 ± 42 Ma, and migmatitic Lister gneiss with concordant ages of 3213 -4 +21 Ma for restite and 2552 -21 +4 Ma for leucosome. Titanite ages of ca. 2508 Ma are common to both rocks. A nearby metapsammitic gneiss has detrital zircon and monazite ages of 2681 ± 5, 2700 ± 4, ca. 2730, and 2750 ± 2 Ma representing high-grade metamorphism related to the Hopedale-Saglek collision and metamorphic monazite of ca. 2560 Ma age representing metamorphism of the sediment during reactivation of the Saglek-Hopedale suture. Two hundred kilometres southeast, a gneissic granite records a protolith age of 3170 Ma and Late Proterozoic Pb loss. Near the Nain-Makkovik boundary, 1269 ± 4 Ma zircons indicate a significant extension of the Nain Plutonic Suite. South of the Makkovik boundary, a foliated granite yielded an upper intercept age defining intrusion at 1895 ± 8 Ma and concordant 1872 ± 5 Ma titanite ages that date subsequent metamorphism. Discordant U-Pb ages from an alkali-feldspar granite also constrain crystallization to ca. 1890 Ma and together with the gneiss represent the previously defined Iggiuk event in the Kaipokok domain. Wells near the southerly end of the transect record 1801 ± 5, 1813 ± 3, and 1806 ± 8 Ma ages, respectively, that are typical of the synorogenic granitoid suite representing the Cape Harrison domain of southern Makkovik Province. (author). 46 refs., 1 tab., 5 figs

U-Pb Data On Apatites With Common Lead Correction : Exemples From The Scottish Caledonides

Science.gov (United States)

Jewison, E.; Deloule, E.; Villeneuve, J.; Bellahsen, N.; Labrousse, L.; Rosenberg, C.; Pik, R.; Chew, D.

2017-12-01

Apatite is a widely used mineral in low-temperature thermochronology (U-Th/He and AFT). The use of apatite in U-Pb geochronology has a great potential, given its closure temperature around 450°C, for orogen thermostructural evolution studies. However, since apatite can accumulate significant amount of initial Pb in its structure, its use can be hindered by the lack of 204 Pb estimations. To work around this, two options are commonly used : either use a ploting sytem that does not require corrected ratios, or use a proxy to estimate 204Pb and use it to correct the ratios. In this study we use a SIMS to mesure 204Pb in order to compare Tera-Wasserburg diagram and corrected ages to examine the cooling pattern in the northern Highlands of Scotland. The Highlands is an extensively studied caledonian collision wedge which results from the closure of the Iapétus Ocean during the Orodivician-Silurian. Two orogenic events are related to this closing, the grampian event (480-460Ma) and the scandian event (435-415 Ma) that culminated in the stacking of major ductile thrusts. The thermal history of thoses nappes are hence complex and the cooling pattern poorly constrained. Corrected apatite U-Pb ages provide new constrains on ductile wedge building and improve our understanding of mid to lower-crustal deformation and orogenic exhumation. Thoses corrected ages yield equivalent errors and mean ages from the classic method. Those data suggest a global cooling younger than previously thought and a sequence departing from a simple forward sequence. We thus present a refined thermal evolution and conceptualize a model of ductile wedge evolution.

U-Pb and Lu-Hf systematics of zircons from Sargur metasediments, Dharwar Craton, Southern India: new insights on the provenance and crustal evolution

International Nuclear Information System (INIS)

Maibam, Bidyananda; Gerdes, Axel; Srinivasan, R.; Goswami, J.N.

2017-01-01

A study of U-Pb and Lu-Hf-Yb isotope data in zircons from metamorphosed psammopelite and quartzite from the type area of Archaean Sargur Group, Dharwar Craton, India is carried out. Two age populations are observed: an older population with concordant U-Pb ages between 2.7 and 2.8 Ga, and a younger population with ages in the 2.4 - 2.6 Ga age range. The εHf values of 0 to + 2.0 for the older zircon population suggest that they were derived from juvenile crust formed at 2.7- 2.8 Ga. Sub-chondritic εHf values for the younger population indicate metamorphism and/or crustal reworking at ∼2.5 Ga. Meta-sedimentary enclaves in the Sargur type area are therefore part of the gneiss-supracrustal complex of different antiquities and may not have an independent stratigraphic status. (author)

A Low-Temperature Electron Microscopy and Electron Diffraction Study of La1.84Sr0.16CuO4

Science.gov (United States)

Onozuka, Takashi; Omori, Mamoru; Hirabayashi, Makoto; Syono, Yasuhiko

1987-10-01

A high-Tc superconducting compound, La1.84Sr0.16CuO4, has been investigated by electron microscopy and electron diffraction in the range from 10 K to ambient temperature. The tetragonal K2NiF4-type structure undergoes an orthorhombic distortion below about 130 K. In the low-temperature phase, extra diffraction spots and twin lamellae are observed reversibly on cooling and heating in situ. Based on the observed results, a plausible structure model with orthorhombic distortion is proposed.

Detrital zircon U-Pb geochronological and sedimentological study of the Simao Basin, Yunnan: Implications for the Early Cenozoic evolution of the Red River

Science.gov (United States)

Chen, Yi; Yan, Maodu; Fang, Xiaomin; Song, Chunhui; Zhang, Weilin; Zan, Jinbo; Zhang, Zhiguo; Li, Bingshuai; Yang, Yongpeng; Zhang, Dawen

2017-10-01

The paleo-Red River is suggested to have been a continental-scale drainage system connecting the Tibetan Plateau to the South China Sea. However, the evolution of the paleo-Red River is still under debate. This study presents new results from sedimentological analyses and detrital zircon U-Pb geochronologic data from fluvial sedimentary rocks of Paleocene to Oligocene age of the Simao Basin to constrain the nature of the paleo-drainage system of the Red River. The detrital zircon U-Pb results reveal multiple age groups at 190-240 Ma, 260-280 Ma, 450-540 Ma, 1700-1900 Ma and 2400-2600 Ma for the Paleocene to late Eocene Denghei Formation (Fm.), but only one conspicuous peak at 220-240 Ma for the late Eocene-Oligocene Mengla Fm. Provenance analyses illustrate that the former likely had source areas that included the Hoh-Xil, Songpan-Ganzi, northern Qiangtang, Yidun and western Yangtze Terranes, which are consistent with the catchments of the Upper and Lower Jinshajiang Segments, whereas the latter mainly transported material from a limited number of sources, such as the Lincang granitic intrusions west of the Simao Basin. Integrated with available detrital zircon U-Pb geochronologic and paleogeographic data, our study suggests the existence of a paleo-Red River during the Paleocene to late Eocene that was truncated and lost its northern sources after approximately 35 Ma, due to left-lateral strike-slip faulting of the Ailao Shan-Red River and clockwise rotation of the Lanping-Simao Terrane.

Elemental and Sr-Nd isotopic geochemistry of Cretaceous to Early Paleogene granites and volcanic rocks in the Sikhote-Alin Orogenic Belt (Russian Far East): implications for the regional tectonic evolution

Science.gov (United States)

Zhao, Pan; Jahn, Bor-ming; Xu, Bei

2017-09-01

The Sikhote-Alin Orogenic Belt in Russian Far East is an important Late Mesozoic to Early Cenozoic accretionary orogen related to the subduction of the Paleo-Pacific Plate. This belt was generated by successive accretion of terranes made of accretionary prisms, turbidite basins and island arcs to the continental margin of northeastern Asia (represented by the Bureya-Jiamusi-Khanka Block) from Jurassic to Late Cretaceous. In order to study the tectonic and crustal evolution of this orogenic belt, we carried out zircon U-Pb dating, and whole-rock elemental and Sr-Nd isotopic analyses on granites and volcanic rocks from the Primorye region of southern Sikhote-Alin. Zircon dating revealed three episodes of granitoid emplacement: Permian, Early Cretaceous and Late Cretaceous to Early Paleogene. Felsic volcanic rocks (mainly rhyolite, dacite and ignimbrite) that overlay all tectonostratigraphic terranes were erupted during 80-57 Ma, postdating the accretionary process in the Sikhote-Alin belt. The Cretaceous-Paleogene magmatism represents the most intense tectonothermal event in the Sikhote-Alin belt. Whole-rock major and trace elemental data show arc-like affinity for granitoids and volcanic rocks, indicating that they were likely generated in a supra-subduction setting. Their initial 87Sr/86Sr ratios range from 0.7048 to 0.7114, and εNd(t) values vary from +1.7 to -3.8 (mostly < 0). Thus, the elemental and Sr-Nd isotopic data suggest that the felsic magmas were generated by partial melting of source rocks comprising mantle-derived juvenile component and recycled crustal component. In addition to the occurrence in the Sikhote-Alin orogenic belt, Cretaceous to Early Paleogene magmatic rocks are also widespread in NE China, southern Korean peninsula, Japanese islands and other areas of Russian Far East, particularly along the coastal regions of the Okhotsk and Bering Seas. These rocks constitute an extended magmatic belt along the continental margin of NE Asia. The

Re-appraisal of the stratigraphy and determination of new U-Pb dates for the Sterkfontein hominin site, South Africa.

Science.gov (United States)

Pickering, Robyn; Kramers, Jan D

2010-07-01

Sterkfontein Caves is the single richest early hominin site in the world with deposits yielding one or more species of Australopithecus and possible early Homo, as well as an extensive faunal collection. The inability to date the southern African cave sites accurately or precisely has hindered attempts to integrate the hominin fossil evidence into pan-African scenarios about human evolutionary history, and especially hominin biogeography. We have used U-Pb and U-Th techniques to date sheets of calcium carbonate flowstone inter-bedded between the fossiliferous sediments. For the first time, absolute age ranges can be assigned to the fossil-bearing deposits: Member 2 is between 2.8 +/- 0.28 and 2.6 +/- 0.30 Ma and Member 4 between 2.65 +/- 0.30 and 2.01 +/- 0.05 Ma. The age of 2.01 +/- 0.05 Ma for the top of Member 4 constrains the last appearance of Australopithecus africanus to 2 Ma. In the Silberberg Grotto we have reproduced the U-Pb age of approximately 2.2 Ma of for the flowstones associated with StW573. We believe that these deposits, including the fossil and the flowstones, accumulated rapidly around 2.2 Ma. The stratigraphy of the site is complex as sediments are exposed both in the underground chambers and at surface. We present a new interpretation of the stratigraphy based on surface mapping, boreholes logs and U-Pb ages. Every effort was made to retain the Member system, however, only Members 2 and 4 are recognized in the boreholes. We propose that the deposits formally known as Member 3 are in fact the distal equivalents of Member 4. The sediments of Members 2 and 4 consisted of cone-like deposits and probably never filled up the cave. The U-Th ages show that there are substantial deposits younger than 400 ka in the underground cave, underlying the older deposits, highlighting again that these cave fills are not simple layer-cakes.

U-Pb systematics of zircon and titanite from the Gardnos impact structure, Norway: Evidence for impact at 546 Ma?

Science.gov (United States)

Kalleson, E.; Corfu, F.; Dypvik, H.

2009-05-01

Zircon and titanite were investigated in impactites of the Gardnos structure, a crater formed in Sveconorwegian (ca. 1 Ga) crust, which was then overridden in the Devonian by Caledonian nappes. Observed deformation features in zircons are granular texture, planar microstructures, and likely the incorporation of organic carbon during impact causing black staining of the zircon grains. The grains were studied by scanning electron microscopy (SEM) and cathode luminescence (CL) and dated by U-Pb isotope dilution - thermo-ionization mass spectrometry (ID-TIMS). Zircon grains without impact related features have U-Pb data showing moderate discordance (5-13%) and indicating formation ages mostly in the range of 1600-1000 Ma, except detrital zircon ages as old as >2481 Ma, reflecting the diversity of target rocks in the area. Titanite with concordant ages of 995-999 Ma dates metamorphism during final juxtaposition of the Telemarkia on the Idefjorden terrane to the east. Zircon grains with demonstrated or presumed shock features yield highly discordant (14-40%) U-Pb data, with a majority of them plotting along an array with a lower intercept of about 340 Ma reflecting the influence of the Caledonian orogeny and recent Pb-loss. One zircon grain was totally reset at 379 Ma during late Caledonian metamorphism, which also caused local growth of new titanite. A specific group of zircon grains yields data with relatively high discordance for moderate U contents, and five of these analyses, including that of a grain with proven granular or aggregate texture, fit a discordia line with an upper intercept of 546 ± 5 Ma. These features are interpreted as indicating zircon break-down to an amorphous state during impact, with subsequent recrystallization into microcrystalline aggregates causing extensive to complete Pb loss. We further suggest that their crystallinity prevented Pb loss during the Caledonian orogeny, while the small subgrain size and increasing metamictisation allowed

Preparation and characterization of Sr-Ti-hardystonite (Sr-Ti-HT nanocomposite for bone repair application

Directory of Open Access Journals (Sweden)

Hossein Mohammadi

2015-07-01

Full Text Available Objective(s: Hardystonite (HT is Zn-modified silicate bioceramics with promising results for bone tissue regeneration. However, HT possesses no obvious apatite formation. Thus, in this study we incorporated Sr and Ti into HT to prepare Sr-Ti-hardystonite (Sr-Ti-HT nanocomposite and evaluated its in vitro bioactivity with the purpose of developing a more bioactive bone substitute material. Materials and methods:The HT and Sr-Ti-HT were prepared by mechanical milling and subsequent heat treatment. Calcium oxide (CaO, zinc oxide (ZnO and silicon dioxide (SiO2 (all from Merck were mixed with molar ratio of 2:1:2. The mixture of powders mixture was then milled in a planetary ball mill for 20 h. In the milling run, the ball-to-powder weight ratio was 10:1 and the rotational speed was 200 rpm. After synthesis of HT, 3% nanotitanium dioxide (TiO2, Degussa and 3% strontium carbonate (SrCO3, Merck were added to HT and then the mixture was ball milled and calcined at 1150°C for 6 h. Simultaneous thermal analysis (STA, X-ray diffraction (XRD, Transmission electron microscopy (TEM and Fourier transform infra-red spectroscopy (FT-IR performed to characterize the powders. Results:XRD and FT-IR confirmed the crystal phase and silicate structure of HT and TEM images demonstrated the nanostructure of powders. Further, Sr-Ti-HT induced apatite formation and showed a higher human mesenchymal stem cell (hMSCs adhesion and proliferation compared to HT. Conclusion:Our study revealed that Sr-Ti-HT with a nanostructured crystal structure of 50 nm, can be prepared by mechanical activation to use as biomaterials for orthopedic applications.

The influence of Sr content in calcium phosphate coatings

International Nuclear Information System (INIS)

Lindahl, Carl; Pujari-Palmer, Shiuli; Hoess, Andreas; Ott, Marjam; Engqvist, Håkan; Xia, Wei

2015-01-01

In this study calcium phosphate coatings with different amounts of strontium (Sr) were prepared using a biomineralization method. The incorporation of Sr changed the composition and morphology of coatings from plate-like to sphere-like morphology. Dissolution testing indicated that the solubility of the coatings increased with increased Sr concentration. Evaluation of extracts (with Sr concentrations ranging from 0 to 2.37 μg/mL) from the HA, 0.06Sr, 0.6Sr, and 1.2Sr coatings during in vitro cell cultures showed that Sr incorporation into coatings significantly enhanced the ALP activity in comparison to cells treated with control and HA eluted media. These findings show that calcium phosphate coatings could promote osteogenic differentiation even in a low amount of strontium. - Highlights: • Calcium phosphate coating doping with low Sr contents was prepared via a biomineralization process. • The solubility of the coatings increased with increased Sr concentration. • Present findings show the potential that Sr has on promoting osteogenic differentiation even in a low amount

Early paleozoic granitoids in the southern Vanoise basement: U-Pb geochronology of the Arpont meta-granite (Savoy, French Alps); Granitoides d`age paleozoique inferieur dans le socle de Vanoise meridionale: geochronologie U-Pb du metagranite de l`Arpont (Alpes de Savoir, France)

Energy Technology Data Exchange (ETDEWEB)

Bertrand, J.M. [Laboratoire de geodynamique des chaines alpines, LGCA-CISM, 73 - Le Bourget-du-Lac (France); Leterrier, J. [Centre de recherches petrographiques et geochimique, 54 - Vandoeuvre-les-Nancy (France)

1997-12-01

The U-Pb age of a meta-granite from southern Vanoise (Brianconnais` domain) at 479{+-} 4 Ma confirms hat the micaschists which dominate this pre-alpine basement are, at least, of Early Paleozoic age. The rare magmatic rocks occurring in Vanoise and showing alkaline affinities, may be compared to the orthogneisses belonging to the Cambrian-Ordovician extensional event well known in other parts of the Varican belt. (authors) 27 refs.

The inverse F-BAR domain protein srGAP2 acts through srGAP3 to modulate neuronal differentiation and neurite outgrowth of mouse neuroblastoma cells.

Directory of Open Access Journals (Sweden)

Yue Ma

Full Text Available The inverse F-BAR (IF-BAR domain proteins srGAP1, srGAP2 and srGAP3 are implicated in neuronal development and may be linked to mental retardation, schizophrenia and seizure. A partially overlapping expression pattern and highly similar protein structures indicate a functional redundancy of srGAPs in neuronal development. Our previous study suggests that srGAP3 negatively regulates neuronal differentiation in a Rac1-dependent manner in mouse Neuro2a cells. Here we show that exogenously expressed srGAP1 and srGAP2 are sufficient to inhibit valporic acid (VPA-induced neurite initiation and growth in the mouse Neuro2a cells. While ectopic- or over-expression of RhoGAP-defective mutants, srGAP1(R542A and srGAP2(R527A exert a visible inhibitory effect on neuronal differentiation. Unexpectedly, knockdown of endogenous srGAP2 fails to facilitate the neuronal differentiation induced by VPA, but promotes neurite outgrowth of differentiated cells. All three IF-BAR domains from srGAP1-3 can induce filopodia formation in Neuro2a, but the isolated IF-BAR domain from srGAP2, not from srGAP1 and srGAP3, can promote VPA-induced neurite initiation and neuronal differentiation. We identify biochemical and functional interactions of the three srGAPs family members. We propose that srGAP3-Rac1 signaling may be required for the effect of srGAP1 and srGAP2 on attenuating neuronal differentiation. Furthermore, inhibition of Slit-Robo interaction can phenocopy a loss-of-function of srGAP3, indicating that srGAP3 may be dedicated to the Slit-Robo pathway. Our results demonstrate the interplay between srGAP1, srGAP2 and srGAP3 regulates neuronal differentiation and neurite outgrowth. These findings may provide us new insights into the possible roles of srGAPs in neuronal development and a potential mechanism for neurodevelopmental diseases.

Studies of metallic species incorporation during growth of SrBi2Ta2O9 films on YBa2Cu3O7-x substrates using mass spectroscopy of recoiled ions

International Nuclear Information System (INIS)

Dhote, A. M.

1999-01-01

The incorporation of metallic species (Bi, Sr and Ta) during the growth of layered perovskite SrBi 2 Ta 2 O 9 (SBT) on a-axis oriented YBa 2 Cu 3 O 7-x (YBCO) conducting oxide substrates has been investigated using in situ low energy mass spectroscopy of recoiled ions (MSRI). This technique is capable of providing monolayer-specific surface information relevant to the growth of single and multi-component thin films and layered heterostructures. The data show a temperature dependence of metallic species incorporation during co-deposition of Sr, Bi and Ta on YBCO surfaces. At high temperatures (400 400 C. SBT films grown at temperatures ≤ 400 C and annealed in oxygen or air at 800 C exhibit a polycrystalline structure with partial a-axis orientation

U-Pb isotopic evidence pertaining to the age and genesis of uranium mineralisation in Karoo sediments

International Nuclear Information System (INIS)

Allsopp, H.L.; Welke, H.J.; Armstrong, R.A.; Clough, W.; Evans, I.B.

1984-01-01

Preliminary investigations have been carried out, using the uranium-lead isotopic method, on the uranium mineralisation that occurs within the Karoo sediments. Two occurences were studied, namely the lower Beaufort sediments (Adelaide Subgroup) in the Beaufort West area and the Molteno Formation sediments in the Ficksburg area. The objective were to determine the age of the mineralisation and to study the mode of formation of the ores. The pattern of U-Pb apparent ages for all the Karoo samples is 207 Pb/ 206 Pb age >> 207 Pb* 235 U age > 206 Pb* 238 U age

Refinement of Mg2Si reinforcement in a commercial Al–20%Mg2Si in-situ composite with bismuth, antimony and strontium

International Nuclear Information System (INIS)

Nordin, Nur Azmah; Farahany, Saeed; Ourdjini, Ali; Abu Bakar, Tuty Asma; Hamzah, Esah

2013-01-01

Refinement by addition elements of Al–Mg 2 Si alloys is known to result in a change of primary Mg 2 Si morphology. In this paper, the effects of Bi, Sb and Sr on the characteristic parameters of Al–20%Mg 2 Si in-situ composite have been investigated by computer aided cooling curve thermal analysis and microstructural inspection. Size, density and aspect ratio measurements showed that additions of 0.4 wt.% Bi, 0.8 wt.% Sb and 0.01 wt.% Sr refined the Mg 2 Si reinforcement. Exceeding these concentrations, however, resulted in coarsening of Mg 2 Si particles with no change in the morphology. The results also showed that addition elements caused a decrease in the nucleation and growth temperatures of Mg 2 Si particles. The refining effect of Bi, Sb and Sr is likely to be related to the effect of oxide bifilms suspended in the composite melt as favored nucleation substrates for Mg 2 Si particles. - Highlight: • 0.4 wt.%, 0.8 wt.% and 0.01 wt.% is the optimum content for Bi, Sb and Sr addition. • Exceeding optimum concentration resulted in the coarsening of reinforcements. • Nucleation and growth temperatures decrease with addition of Bi, Sb and Sr. • The refining effect of Bi, Sb and Sr is likely to be related to the oxide bifilms

Mapping and characterization of wheat stem rust resistance genes SrTm5 and Sr60 from Triticum monococcum.

Science.gov (United States)

Chen, Shisheng; Guo, Yan; Briggs, Jordan; Dubach, Felix; Chao, Shiaoman; Zhang, Wenjun; Rouse, Matthew N; Dubcovsky, Jorge

2018-03-01

The new stem rust resistance gene Sr60 was fine-mapped to the distal region of chromosome arm 5A m S, and the TTKSK-effective gene SrTm5 could be a new allele of Sr22. The emergence and spread of new virulent races of the wheat stem rust pathogen (Puccinia graminis f. sp. tritici; Pgt), including the Ug99 race group, is a serious threat to global wheat production. In this study, we mapped and characterized two stem rust resistance genes from diploid wheat Triticum monococcum accession PI 306540. We mapped SrTm5, a previously postulated gene effective to Ug99, on chromosome arm 7A m L, completely linked to Sr22. SrTm5 displayed a different race specificity compared to Sr22 indicating that they are distinct. Sequencing of the Sr22 homolog in PI 306540 revealed a novel haplotype. Characterization of the segregating populations with Pgt race QFCSC revealed an additional resistance gene on chromosome arm 5A m S that was assigned the official name Sr60. This gene was also effective against races QTHJC and SCCSC but not against TTKSK (a Ug99 group race). Using two large mapping populations (4046 gametes), we mapped Sr60 within a 0.44 cM interval flanked by sequenced-based markers GH724575 and CJ942731. These two markers delimit a 54.6-kb region in Brachypodium distachyon chromosome 4 and a 430-kb region in the Chinese Spring reference genome. Both regions include a leucine-rich repeat protein kinase (LRRK123.1) that represents a potential candidate gene. Three CC-NBS-LRR genes were found in the colinear Brachypodium region but not in the wheat genome. We are currently developing a Bacterial Artificial Chromosome library of PI 306540 to determine which of these candidate genes are present in the T. monococcum genome and to complete the cloning of Sr60.

Chernobyl 90Sr in bilberries from Poland

International Nuclear Information System (INIS)

Mietelski, J.W.; Vajda, N.

1997-01-01

As part of a detailed survey on the contamination of Polish forests 90 Sr activity concentrations were determined in bilberries. Elevated 90 Sr levels were found in several samples from north-eastern Poland. The calculated maximum 90 Sr surface contamination was 2 kBq*m -2 . The correlation between 90 Sr and 137 Cs concentrations in bilberries was good for two sets of samples originating from two geographical areas of Poland indicating the local differences in radionuclide depositions from Chernobyl fallout. (author)

Rb-Sr whole-rock and mineral ages, K-Ar, 40Ar/39Ar, and U-Pb mineral ages, and strontium, lead, neodymium, and oxygen isotopic compositions for granitic rocks from the Salinian Composite Terrane, California:

Science.gov (United States)

Kistler, R.W.; Champion, D.E.

2001-01-01

This report summarizes new and published age and isotopic data for whole-rocks and minerals from granitic rocks in the Salinian composite terrane, California. Rubidium-strontium whole-rock ages of plutons are in two groups, Early Cretaceous (122 to 100 Ma) and Late Cretaceous (95 to 82 Ma). Early Cretaceous plutons occur in all granitic rock exposures from Bodega Head in the north to those from the Santa Lucia and Gabilan Ranges in the central part of the terrane. Late Cretaceous plutons have been identified in the Point Reyes Peninsula, the Santa Lucia and the Gabilan Ranges, and in the La Panza Range in the southern part of the terrane. Ranges of initial values of isotopic compositions are 87Sr/86Sr, 0.7046-0.7147, δ18O, +8.5 to +12.5 per mil, 206Pb/204Pb, 18.901-19.860, 207Pb/204Pb, 15.618-15.814, 208Pb/204Pb, 38.569- 39.493, and εNd, +0.9 to -8.6. The initial 87Sr/86Sr=0.706 isopleth is identified in the northern Gabilan Range and in the Ben Lomond area of the Santa Cruz Mountains, in Montara Mountain, in Bodega Head, and to the west of the Farallon Islands on the Cordell Bank. This isotopic boundary is offset about 95 miles (160km) by right-lateral displacements along the San Gregorio-Hosgri and San Andreas fault systems.

Modification of Sr on 4004 Aluminum Alloy

Science.gov (United States)

Guo, Erjun; Cao, Guojian; Feng, Yicheng; Wang, Liping; Wang, Guojun; Lv, Xinyu

2013-05-01

As a brazing foil, 4004 Al alloy has good welding performance. However, the high Si content decreases the plasticity of the alloy. To improve the plasticity of 4004 Al alloy and subsequently improve the productivity of 4004 Al foil or 434 composite foil, 4004 Al alloy was modified by Al-10%Sr master alloy. Modification effects of an additional amount of Sr, modification temperature, and holding time on 4004 aluminum alloy were studied by orthogonal design. The results showed that the greatest impact parameter of 4004 aluminum alloy modification was the additional amount of Sr, followed by holding time and modification temperature. The optimum modification parameters obtained by orthogonal design were as follows: Sr addition of 0.04%, holding time of 60 min, and modification temperature of 760°C. The effect of Sr addition on modification was analyzed in detail based on orthogonal results. With increasing of Sr addition, elongation of 4004 alloy increased at first, and decreased after reaching the maximum value.

Losses of Sr/sup 90/, Sr/sup 89/, and I/sup 131/ from fallout-contaminated plants

Energy Technology Data Exchange (ETDEWEB)

Martin, W E

1964-11-01

During the early period following local fallout, and during periods of maximal worldwide fallout, the entry of radionuclides into terrestrial food-chains is due primarily to the external contamination of plants and secondarily to the uptake of radionuclides from contaminated soil. Studies were undertaken to estimate the rates of radionuclide loss from fallout-contaminated vegetation and hence from the diets of herbivores living in a fallout field. On the fifth, fifteenth, thirtieth, and sixtieth days after an underground nuclear explosion (Operation Sedan) at the Nevada Test Site, plant samples were collected from twenty representative locations in the fallout field and analyzed to determined the concentrations (pc/g dry wt) of /sup 90/Sr, /sup 89/Sr, and /sup 131/I at the times of collections. While the radioactive half lives of /sup 90/Sr, /sup 89/Sr, and /sup 131/I are approximately 27.7 years, 53 days, and 8.04 days respectively, their average effective half-lives on fallout-contaminated plants, during the period from 5 to 30 days after the detonation, were 27.8 days, 17.8 days, and 5.0 days respectively. Losses of /sup 90/Sr were attributed to radioactive decay and to the removal of fallout particles and foliage by wind and/or other mechanical disturbances. Losses of /sup 90/Sr and /sup 89/Sr were attributed to radioactive decay and to the removal of fallout particles and foliage by wind and/or other mechanical disturbances. Losses of /sup 131/I were attributed to radioactive decay, to mechanical disturbance, and to the vaporization of /sup 131/I from the fallout particles retained on foliage.

Experimental evidence shows no fractionation of strontium isotopes ((87)Sr/(86)Sr) among soil, plants, and herbivores: implications for tracking wildlife and forensic science.

Science.gov (United States)

Flockhart, D T Tyler; Kyser, T Kurt; Chipley, Don; Miller, Nathan G; Norris, D Ryan

2015-01-01

Strontium isotopes ((87)Sr/(86)Sr) can be useful biological markers for a wide range of forensic science applications, including wildlife tracking. However, one of the main advantages of using (87)Sr/(86)Sr values, that there is no fractionation from geological bedrock sources through the food web, also happens to be a critical assumption that has never been tested experimentally. We test this assumption by measuring (87)Sr/(86)Sr values across three trophic levels in a controlled greenhouse experiment. Adult monarch butterflies were raised on obligate larval host milkweed plants that were, in turn, grown on seven different soil types collected across Canada. We found no significant differences between (87)Sr/(86)Sr values in leachable Sr from soil minerals, organic soil, milkweed leaves, and monarch butterfly wings. Our results suggest that strontium isoscapes developed from (87)Sr/(86)Sr values in bedrock or soil may serve as a reliable biological marker in forensic science for a range of taxa and across large geographic areas.

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy of Cobalt Perovskite Surfaces under Cathodic Polarization at High Temperatures

KAUST Repository

Crumlin, Ethan J.; Mutoro, Eva; Hong, Wesley T.; Biegalski, Michael D.; Christen, Hans M.; Liu, Zhi; Bluhm, Hendrik; Shao-Horn, Yang

2013-01-01

Heterostructured oxide interfaces have demonstrated enhanced oxygen reduction reaction rates at elevated temperatures (∼500-800 C); however, the physical origin underlying this enhancement is not well understood. By using synchrotron-based in situ ambient pressure X-ray photoelectron spectroscopy (APXPS), we focus on understanding the surface electronic structure, elemental composition, and chemical nature of epitaxial La0.8Sr 0.2CoO3-δ (LSC113), (La 0.5Sr0.5)2CoO4±δ (LSC214), and LSC214-decorated LSC113 (LSC 113/214) thin films as a function of applied electrical potentials (0 to -800 mV) at 520 C and p(O2) of 1 × 10-3 atm. Shifts in the top of the valence band binding energy and changes in the Sr 3d and O 1s spectral components under applied bias reveal key differences among the film chemistries, most notably in the degree of Sr segregation to the surface and quantity of active oxygen sites in the perovskite termination layer. These differences help to identify important factors governing the enhanced activity of oxygen electrocatalysis observed for the LSC113/214 heterostructured surface. © 2013 American Chemical Society.

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy of Cobalt Perovskite Surfaces under Cathodic Polarization at High Temperatures

KAUST Repository

Crumlin, Ethan J.

2013-08-08

Heterostructured oxide interfaces have demonstrated enhanced oxygen reduction reaction rates at elevated temperatures (∼500-800 C); however, the physical origin underlying this enhancement is not well understood. By using synchrotron-based in situ ambient pressure X-ray photoelectron spectroscopy (APXPS), we focus on understanding the surface electronic structure, elemental composition, and chemical nature of epitaxial La0.8Sr 0.2CoO3-δ (LSC113), (La 0.5Sr0.5)2CoO4±δ (LSC214), and LSC214-decorated LSC113 (LSC 113/214) thin films as a function of applied electrical potentials (0 to -800 mV) at 520 C and p(O2) of 1 × 10-3 atm. Shifts in the top of the valence band binding energy and changes in the Sr 3d and O 1s spectral components under applied bias reveal key differences among the film chemistries, most notably in the degree of Sr segregation to the surface and quantity of active oxygen sites in the perovskite termination layer. These differences help to identify important factors governing the enhanced activity of oxygen electrocatalysis observed for the LSC113/214 heterostructured surface. © 2013 American Chemical Society.

Real-time {sup 90}Sr Counter

Energy Technology Data Exchange (ETDEWEB)

Kaneko, Naomi; Kawai, Hideyuki; Kodama, Satoshi; Kobayashi, Atsushi; Tabata, Makoto; Ito, Hiroshi [Graduate School of Science, Chiba University, Chiba, (Japan); Han, Soorim [Graduate School of Science, Chiba University, Chiba, (Japan); National Institute of Radiological Science, Chiba, (Japan)

2015-07-01

Radioisotopes have been emitted around Japan due to a nuclear accident at the Fukushima Daiichi nuclear power station in March 2011. A problem is the contaminated water including the atomic nucleus which relatively has a long half- life time and soluble such as {sup 90}Sr, {sup 137}Cs. Internal exposures by {sup 90}Sr are more dangerous than {sup 137}Cs's because Sr has effective half-life time of 18 years and property of accumulation in a born. We have developed real-time {sup 90}Sr counter which is sensitive beta-ray of maximum kinematic energy of 2.28 MeV from {sup 90}Sr and insensitive of beta-ray of maximum kinematic energy of 1.17 MeV and gamma-ray from {sup 90}Sr by Cherenkov detection. This counter composes of Cerenkov counter, trigger scintillation counter and veto counter. Silica aerogel for Cherenkov counter can obtain refractive index between 1.017 and 1.049 easily. And wavelength shifting fiber (WLSF) is used as a light guide for extending effective area and producing lower cost. A mechanism of the identification of {sup 90}Sr is explained in following. In case of {sup 90}Sr, when the trigger counter reacts on the beta-ray from {sup 90}Sr, aerogel emits the Cherenkov light and WLSF reacts and read the Cherenkov light. On the other hand, in case of {sup 137}Cs, the trigger counter reacts on the beta-ray, aerogel stops the beta- ray and Cherenkov light is not emitted. Therefore, aerogel has a function as a radiator and shielding material. the gamma-ray is not reacted on the lower density detector. Cosmic rays would be also reacted by the veto counter. A prototype counter whose the effective area is 30 cm x 10 cm was obtained (2.0±1.2){sup 3} of mis-identification as {sup 137}Cs/{sup 90}Sr. Detection limit in the surface contamination inspection depends on measurement time and effective area mainly. The sensitivity of wide range, 10{sup -2} - 10{sup 4} Bq/cm{sup 2}, is obtained by adjustment of detection level in circuit of this counter. A lower

Melting of subducted continental crust: Geochemical evidence from Mesozoic granitoids in the Dabie-Sulu orogenic belt, east-central China

Science.gov (United States)

Zhao, Zi-Fu; Liu, Zhi-Bin; Chen, Qi

2017-09-01

Syn-collisional and postcollisional granitoids are common in collisional orogens, and they were primarily produced by partial melting of subducted continental crust. This is exemplified by Mesozoic granitoids from the Dabie-Sulu orogenic belt in east-central China. These granitoids were emplaced in small volumes in the Late Triassic (200-206 Ma) and the Late Jurassic (146-167 Ma) but massively in the Early Cretaceous (111-143 Ma). Nevertheless, all of them exhibit arc-like trace element distribution patterns and are enriched in Sr-Nd-Hf isotope compositions, indicating their origination from the ancient continental crust. They commonly contain relict zircons with Neoproterozoic and Triassic U-Pb ages, respectively, consistent with the protolith and metamorphic ages for ultrahigh-pressure (UHP) metaigneous rocks in the Dabie-Sulu orogenic belt. Some granitoids show low zircon δ18O values, and SIMS in-situ O isotope analysis reveals that the relict zircons with Neoproterozoic and Triassic U-Pb ages also commonly exhibit low δ18O values. Neoproterozoic U-Pb ages and low δ18O values are the two diagnostic features that distinguish the subducted South China Block from the obducted North China Block. Thus, the magma source of these Mesozoic granitoids has a genetic link to the subducted continental crust of the South China Block. On the other hand, these granitoids contain relict zircons with Paleoproterozoic and Archean U-Pb ages, which are present in both the South and North China Blocks. Taken together, the Mesozoic granitoids in the Dabie-Sulu orogenic belt and its hanging wall have their magma sources that are predominated by the continental crust of the South China Block with minor contributions from the continental crust of the North China Block. The Triassic continental collision between the South and North China Blocks brought the continental crust into the thickened orogen, where they underwent the three episodes of partial melting in the Late Triassic, Late

A low-temperature electron microscopy and electron diffraction study of La1.84Sr0.16CuO4

International Nuclear Information System (INIS)

Onozuka, Takashi; Omori, Mamoru; Hirabayashi, Makoto; Syono, Yasuhiko

1987-01-01

A high-T c superconducting compound, La 1.84 Sr 0.16 CuO 4 , has been investigated by electron microscopy and electron diffraction in the range from 10 K to ambient temperature. The tetragonal K 2 NiF 4 -type structure undergoes an orthorhombic distortion below about 130 K. In the low-temperature phase, extra diffraction spots and twin lamellae are observed reversibly on cooling and heating in situ. Based on the observed results, a plausible structure model with orthorhombic distortion is proposed. (author)

In situ and laboratory migration experiments through boom clay at Mol

International Nuclear Information System (INIS)

Preter, P. de; Put, M.; Canniere, P. de

1993-01-01

Physico-chemical characterization and migration studies in the Boom clay, envisaged as a potential host sediment for high level waste disposal in Belgium, were started some 15 years ago. A synthesis study of this experimental work has recently been conducted to compile all available data. From a comparison of the available migration data and the data requirements as derived from the performance assessment studies PAGIS (1988) and PACOMA (1991) the new migration programme (1991-1995) was defined. The critical radionuclides, both with relation to dose rates to man and to missing or unreliable migration data, turned out to be 14 C, 99 Tc. 135 Cs and 237 Np. A second group of radionuclides was found to be possibly critical: 79 Se, 93 Zr, 107 Pd, U - , Am - , Cm - , and Pu-isotopes. This report concentrates on the experimental results as obtained from the migration experiments started in the previous migration programme. Some of the reported radionuclides e.g. 90 Sr) have lost their critical character and will not be further studied within the new programme. New experimental data from laboratory tests have become available for Np, Cs, Sr and C (as HC0 3 - ) and the first results on the migration of organic molecules dissolved in the interstitial Boom clay water are reported. The hydraulic parameters (the hydraulic conductivity K and the storage coefficient S o ) were calculated from both laboratory percolation experiments and in situ piezometric measurements. Conclusions concerning Boom clay anisotropy are drawn. Finally, a short description of the ongoing in situ HTO injection experiment is given and the experimental data are analyzed and discussed. 10 refs., 4 figs., 1 tab

Insight into the structure and functional application of the Sr0.95Ce0.05CoO3-δ cathode for solid oxide fuel cells.

Science.gov (United States)

Yang, Wei; Zhang, Huairuo; Sun, Chunwen; Liu, Lilu; Alonso, J A; Fernández-Díaz, M T; Chen, Liquan

2015-04-06

A new perovskite cathode, Sr0.95Ce0.05CoO3-δ, performs well for oxygen-reduction reactions in solid oxide fuel cells (SOFCs). We gain insight into the crystal structure of Sr1-xCexCoO3-δ (x = 0.05, 0.1) and temperature-dependent structural evolution of Sr0.95Ce0.05CoO3-δ by X-ray diffraction, neutron powder diffraction, and scanning transmission electron microscopy experiments. Sr0.9Ce0.1CoO3-δ shows a perfectly cubic structure (a = a0), with a large oxygen deficiency in a single oxygen site; however, Sr0.95Ce0.05CoO3-δ exhibits a tetragonal perovskite superstructure with a double c axis, defined in the P4/mmm space group, that contains two crystallographically different cobalt positions, with distinct oxygen environments. The structural evolution of Sr0.95Ce0.05CoO3-δ at high temperatures was further studied by in situ temperature-dependent NPD experiments. At 1100 K, the oxygen atoms in Sr0.95Ce0.05CoO3-δ show large and highly anisotropic displacement factors, suggesting a significant ionic mobility. The test cell with a La0.8Sr0.2Ga0.83Mg0.17O3-δ-electrolyte-supported (∼300 μm thickness) configuration yields peak power densities of 0.25 and 0.48 W cm(-2) at temperatures of 1023 and 1073 K, respectively, with pure H2 as the fuel and ambient air as the oxidant. The electrochemical impedance spectra evolution with time of the symmetric cathode fuel cell measured at 1073 K shows that the Sr0.95Ce0.05CoO3-δ cathode possesses superior ORR catalytic activity and long-term stability. Mixed ionic-electronic conduction properties of Sr0.95Ce0.05CoO3-δ account for its good performance as an oxygen-reduction catalyst.

Report on nuclear energy in SR Slovenia; Porocilo o uporabi jedrske energije v SR Sloveniji

Energy Technology Data Exchange (ETDEWEB)

NONE

1987-07-01

Currently Yugoslavia has one 632 MWe nuclear power plant (NPP) of PWR design, located at Krsko in the Socialist Republic (SR) of Slovenia. Krsko NPP, which is a two-loop plant, started power operation in 1981. In general, reactor safety activities in the SR of Slovenia are mostly related to upgrading the safety of our Krsko NPP and to developing capabilities for use in future units. This report presents the nuclear safety related legislation and organization of the corresponding regulatory body, and the activities related to nuclear safety of the participating organizations in the SR of Slovenia in 1987.

U-Pb (LA-ICPMS) zircon ages and Nd isotopes for granitoids of the Tamboril-Santa Quiteria Complex, Ceara Central Domain: implication for neoproterozoic syncollisional magmatism in north Borborema Province, Brazil

Energy Technology Data Exchange (ETDEWEB)

Costa, Felipe Grandjean da; Araujo, Carlos Eduardo Ganade de; Vasconcelos, Antonio Maurilio, E-mail: felipe.costa@cprm.gov.br, E-mail: caegeo@gmail.com, E-mail: maurilio.vasconcelos@cprm.gov.br [Servico Geologico do Brasil (CPRM), Fortaleza, CE (Brazil); Amaral, Wagner da Silva, E-mail: wamaral@ufc.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Geologia; Rodrigues, Joseneusa Brilhante, E-mail: joseneusa.rodrigues@cprm.gov.br [Servico Geologico do Brasil (CPRM), Brasilia, DF (Brazil)

2013-06-15

The Tamboril-Santa Quiteria Complex (TSQC) is one of the largest Neoproterozoic plutonic manifestations in the north Borborema Province (NE Brazil). It represents an anatectic/igneous association characterized by a number of magmatic pulses that occurred in the 650-610 Ma interval. In this paper, we present U-Pb (LA-MC-ICP-MS) zircon ages and Nd isotopes for quartz monzonite and quartz diorites of the southern part of TSQC. The quartz monzonite belong to a hybrid granitoid association, including monzonite, syenites and quartz syenites, all with abundant mafic magmatic enclaves. A quartz monzonite sample yielded a U-Pb zircon age of 634 {+-} 10 Ma and a TDM age of 2.69 Ga. The quartz diorites are much more homogeneous in composition and yielded a U-Pb zircon age of 618 {+-} 23 Ma and a TDM age of 2.19 Ga. The presence of coeval mantle-derived magmatism and diatexites (crustal anatexis) post-dating high-pressure metamorphism (ca. 650 Ma), and together with high-temperature metamorphism (ca. 630-610 Ma), suggests that this large magmatic manifestation evolved in a collisional setting, probably related to slab break off during the Western Gondwana amalgamation. (author)

Tectonic implications of U-Pb (zircon) Geochronology of Chor Granitoids of the Lesser Himalaya, Himachal Pradesh, NW Himalaya

Science.gov (United States)

Singh, P.; Bhakuni, S. S.

2017-12-01

Granitoids of various ages ranging from Proterozoic to Tertiary occur throughout the Himalayan fold-thrust belt. The occurrence of the Neoproterozoic granitoids are very less in the Himalayan orogen. One of the best example of Neoproterozoic granitoids is Chor granitoids, which are the intrusive granite bodies in the Paleoproterozoic of the Lesser Himalayan Crystallines of the Jutogh Group. In the central part these granites are non-foliated homogeneous that are porphyritic and peraluminous in nature (Singh et al., 2002; Bhargava et al., 2014, 2016), whereas in the peripheral part these are foliated showing south directed shear sense of movement. In this work we present the U-Pb (zircon) geochronology of two different granites samples of the Chor granitoids of Himachal Pradesh, NW Himalaya. The Jutogh Group of rocks is thrust over the Lesser Himalayan Sequence along the Jutogh Thrust or MCT. The geochronology of the Chor Granitoids and Lesser Himalayan Crystallines and their relationship with each other, including with the Indian shield are sparsely obscure. U-Pb zircon geochrnological age populations from these granitoids yield ages between 780 and 980 Ma. One sample gives the prominent age spectra for 206Pb/238U with weighted mean age of 908.3 ± 6.7 Ma (2σ) MSWD = 2.4 (n = 18). Similarly another sample gives the age of crystallization with weight mean age of 917 ± 17 Ma (2σ) MSWD = 3 (n = 11) and Th/U ratios of both samples are >0.1, indicating their magmatic origin. As a result of ductile shearing of granites along the MCT during the Cenozoic Himalayan Orogeny, the age has reduced to 780 Ma. The Neoproterozoic age of Chor granite matches with the Neoproterozoic detrital zircon age (800 to 1000 Ma by Parrish and Hodges 1996, Decelles et al., 2000) of the HHC. On the basis of U-Pb (zircon) geochronological ages, it is revealed that the source of zircons of the Chor granite and HHC rocks was the northern margin of the Pan-African orogen. The Chor granitoids was

Geochronology and geochemistry of the Badaguan porphyry Cu-Mo deposit in Derbugan metallogenic belt of the NE China, and their geological significances

Science.gov (United States)

Gao, Bingyu; Zhang, Lianchang; Jin, Xindi; Li, Wenjun; Chen, Zhiguang; Zhu, Mingtian

2016-03-01

The Badaguan porphyry Cu-Mo deposit belongs to the Derbugan metallogenic belt, which is located in the Ergun block, NE China. In the mining area, the Cu-Mo mineralization mainly occurs in quartz diorite porphyry and is hosted within silicified-sericitized and sericite alteration zone. Geochemical results of the host porphyry is characterized by high SiO2, high Al2O3, low MgO, weak positive Eu anomalies and clearly HREE depletion, high Sr, low Y and low Yb, similar to those of adakite. The Sr-Nd isotopic composition of the host porphyry displays an initial (87Sr/86Sr)i ratio of 0.7036-0.7055 and positive Nd( t) values of +0.1 to +0.6, which are similar to the OIB, reflecting the source of the host porphyry may derive from subducted ocean slab, and the new lower crust also had some contribution to the magma sources. The SIMS zircon U-Pb age from the host porphyry is 229 ± 2 Ma. The Re-Os isochron age for the molybdenite in the deposit is 225 ± 2 Ma closed to zircon U-Pb age of the host porphyry, indicating that Cu-Mo mineralization event occurred in Triassic. Combining the geology-geochemistry of the host porphyry and the regional tectonic evolution, we infer that the subduction processes of Mongol-Okhotsk oceanic slab under the Ergun block led to the formation of the Badaguan porphyry Cu-Mo deposit during the Triassic.

Sr isotopic tracer study of the Samail ophiolite, Oman

International Nuclear Information System (INIS)

Lanphere, M.A.; Coleman, R.G.; Hopson, C.A.

1981-01-01

We have measured Rb and Sr concentrations and Sr isotopic compositions in 41 whole-rock samples and 12 mineral separates from units of the Samail ophiolite, including peridotite, gabbro, plagiogranite diabase dikes, and gabbro and websterite dikes within the metamorphic peridotite. Ten samples of cummulate gabbro from the Wadir Kadir section and nine samples from the Wadi Khafifah section have mean 87 Sr/ 86 Sr ratios and standard deviations of 0.70314 +- 0.00030 and 0.70306 +- 0.00034, respectively. The dispersion in Sr isotopic composition may reflect real heterogeneities in the magma source region. The average Sr isotopic composition of cumulate gabbro falls in the range of isotopic compositions of modern midocean ridge basalt. The 87 Sr/ 86 Sr ratios of noncumulate gabbro, plagiogranite, and diabase dikes range from 0.7034 to 0.7047, 0.7038 to 0.7046, and 0.7037 to 0.7061, respectively. These higher 87 Sr/ 86 Sr ratios are due to alteration of initial magmatic compositions by hydrothermal exchange with seawater. Mineral separates from dikes that cut harzburgite tectonite have Sr isotopic compositions which agree with that of cumulate gabbro. These data indicate that the cumulate gabbro and the different dikes were derived from partial melting of source regions that had similar long-term histories and chemical compositions

Development of in situ two-coil mutual inductance technique in a multifunctional scanning tunneling microscope.

Science.gov (United States)

Duan, Ming-Chao; Liu, Zhi-Long; Ge, Jian-Feng; Tang, Zhi-Jun; Wang, Guan-Yong; Wang, Zi-Xin; Guan, Dandan; Li, Yao-Yi; Qian, Dong; Liu, Canhua; Jia, Jin-Feng

2017-07-01

Superconducting thin films have been a focal point for intensive research efforts since their reduced dimension allows for a wide variety of quantum phenomena. Many of these films, fabricated in UHV chambers, are highly vulnerable to air exposure, making it difficult to measure intrinsic superconducting properties such as zero resistance and perfect diamagnetism with ex situ experimental techniques. Previously, we developed a multifunctional scanning tunneling microscope (MSTM) containing in situ four-point probe (4PP) electrical transport measurement capability in addition to the usual STM capabilities [Ge et al., Rev. Sci. Instrum. 86, 053903 (2015)]. Here we improve this MSTM via development of both transmission and reflection two-coil mutual inductance techniques for in situ measurement of the diamagnetic response of a superconductor. This addition does not alter the original STM and 4PP functions of the MSTM. We demonstrate the performance of the two-coil mutual inductance setup on a 10-nm-thick NbN thin film grown on a Nb-doped SrTiO 3 (111) substrate.

Zircon U-Pb age of the Pescadero felsite: A late Cretaceous igneous event in the forearc, west-central California Coast Ranges

Science.gov (United States)

Ernst, W.G.; Martens, U.C.; McLaughlin, R.J.; Clark, J.C.; Moore, Diane E.

2011-01-01

Weathered felsite is associated with the late Campanian-Maastrichtian Pigeon Point Formation near Pescadero, California. Poorly exposed, its age and correlation are uncertain. Is it part of the Pigeon Point section west of the San Gregorio-Hosgri fault? Does it rest on Nacimiento block basement? Is it dextrally offset from the Oligocene Cambria Felsite, ~185 km to the southeast? Why is a calc-alkaline hypabyssal igneous rock intrusive into the outboard accretionary prism? To address these questions, we analyzed 43 oscillatory-zoned zircon crystals from three incipiently recrystallized pumpellyite ?? prehnite ?? laumontite-bearing Pescadero felsite samples by sensitive high-resolution ion microprobe-reverse geometry (SHRIMPRG) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) techniques. Thirty-three zircons gave late Mesozoic U-Pb ages, with single-grain values ranging from 81 to 167 Ma; ten have pre-Mesozoic, chiefl y Proterozoic ages. A group of the four youngest Pescadero zircons yielded an apparent maximum igneous age of ca. 86-90 Ma. Refl ecting broad age scatter and presence of partly digested sandstone inclusions, we interpret the rest of the zircons (perhaps all) as xenocrysts. Twenty-three zircons were separated and analyzed from two samples of the similar Cambria Felsite, yielding a unimodal 27 Ma U-Pb age. Clearly, the origin of the Upper Oligocene Cambria Felsite is different from that of the Upper Cretaceous Pescadero felsite; these rocks are not correlated, and do not constrain displacement along the San Gregorio-Hosgri fault. Peak ages differ slightly, but relative probability curves for Mesozoic and pre-Mesozoic Pescadero zircons compare well, for example, with abundant U-Pb age data for detrital zircons from Franciscan metaclastic strata ~100 km to the east in the Diablo Range- San Francisco Bay area, San Joaquin Great Valley Group turbidites, Upper Cretaceous Nacimiento block Franciscan strata, and Upper Cretaceous

U-Pb geochronologic constraints on Paleoproterozoic orogenesis in the northwestern Makkovik Province, Labrador, Canada

International Nuclear Information System (INIS)

Ketchum, J.W.F.; Dunning, G.R.; Dunning, G.R.

1997-01-01

A 45 km wide, shear-zone-bounded segment of the northwestern Makkovik Province, Labrador, is underlain by Archean gneisses derived from the adjacent Nain craton. This lithotectonic block (Kaipokok domain) was reworked at high metamorphic grade, overthrust by supracrustal sequences (Lower Aillik and Moran Lake groups), and intruded by granitoid plutons during the Paleoproterozoic. Initial amphibolite-facies reworking of the Kaipokok domain at 1896 ± 6 Ma is indicated by U-Pb ages of metamorphic zircon from a foliated Kikkertavak metadiabase dyke. This is one of the oldest Paleoproterozoic tectonic events dated thus far in northeast Laurentia and may be linked with ca. 1890 Ma plutonism documented elsewhere in the Kaipokok domain. Intrusion of granitoid plutons at 1882 -6 +10 , 1877 ± 5, and 1871 -3 +4 Ma in the Kaipokok Bay area postdates early thick- and thin-skinned thrusting (possibly east to northeast directed) that involved Lower Aillik Group strata. U-Pb titanite ages of 1866 - 1847 Ma in part record a metamorphic event that followed this plutonic-tectonic activity. These early events are temporally and kinematically difficult to reconcile with accretion of juvenile Makkovikian terranes in the southeast and may instead be related to early stages of the ca. 1.91 - 1.72 Ga Torngat orogeny along the western margin of the Nain craton. In contrast, high-grade metamorphism, dextral shearing, and northwestward thrusting between 1841 and 1784 Ma, including crystallization of an Iggiuk granitic vein at 1811 ± 8 Ma, are in accord with accretion of Makkovikian terranes in a dextral transpressional regime (Makkovikian orogeny sensu stricto). Coeval sinistral transpression in the Torngat orogen suggests that both orogenic belts accommodated relative northward tectonic escape of the Nain craton during this interval. (author)

Petrochemistry and zircon U-Pb geochronology of granitic rocks in the Wang Nam Khiao area, Nakhon Ratchasima, Thailand: Implications for petrogenesis and tectonic setting

Science.gov (United States)

Fanka, Alongkot; Tsunogae, Toshiaki; Daorerk, Veerote; Tsutsumi, Yukiyasu; Takamura, Yusuke; Sutthirat, Chakkaphan

2018-05-01

Carboniferous biotite granite, Late Permian hornblende granite, and Triassic biotite-hornblende granite, all of which belong to the Eastern Granite Belt, expose in the Wang Nam Khiao area, Nakhon Ratchasima, northeastern Thailand. The Carboniferous biotite granite is dominated by quartz, K-feldspar, plagioclase, and biotite. The Late Permian hornblende granite contains dominant assemblages of plagioclase, quartz, K-feldspar, hornblende, and minor amount of biotite, while the Triassic biotite-hornblende granite consists of quartz, plagioclase, K-feldspar with small amounts of biotite, and hornblende. The REE patterns with steep decrease from light to heavy REE together with the LILE (e.g. K, Sr) enrichment and depletion of some particular HFSE (e.g. Nb, Ti) indicate low degree of partial melting. Mineral chemistry of biotite and hornblende in the granites reflects crystallization from hydrous calc-alkaline arc-derived magmas possibly formed by subduction. Amphibole-plagioclase thermometry and Al-in-hornblende barometry indicate that the Late Permian hornblende granite and the Triassic biotite-hornblende granite may have equilibrated at 3.0-5.8 kbar/700-820 °C and 2.0-3.2 kbar/600-750 °C, respectively, in the middle-upper crust (about 10-15 km depth). Zircon U-Pb geochronology of the Carboniferous biotite granite, Late Permian hornblende granite and Triassic biotite-hornblende granite yielded intrusion ages of 314.6-284.9 Ma, 253.4 Ma, and 237.8 Ma, respectively, which implies multiple episodes of arc-magmatism formed by Palaeo-Tethys subduction beneath Indochina Terrane during Late Carboniferous/Early Permian, Late Permian and Middle Triassic.

82Sr--82Rb radioisotope generator

International Nuclear Information System (INIS)

Grant, P.M.; Erdal, B.R.; O'Brien, H.A.

1976-01-01

An improved 82 Sr- 82 Rb radioisotope generator system, based upon the complexing ion exchange resin Chelex-100, has been developed. Columns of this material can be easily and rapidly milked, and the Rb-Sr separation factor for a fresh generator was found to be greater than 10 7 . Approximately 80 percent of the 82 Rb present was delivered in a 15-ml volume of aqueous 0.2 M NH 4 Cl solution. After more than 6 liters of eluant had been put through the generator, the Rb-Sr separation factor was still observed to be greater than 10 5 , and no unusual strontium breakthrough behavior was seen in the system over nearly three 82 Sr half lives. 2 claims, no drawings

Autoradiography of 90Sr in developing rats

International Nuclear Information System (INIS)

Olsen, I.; Jonsen, J.

1979-01-01

The distribution patterns of 90 Sr in five littermate, 8-day-old Wistar rats were studied by whole body autoradiography. Rats were killed 15 min, 1, 4, 24, and 72 h after a single intraperitoneal injection of the isotope. Immediately after administration, 90 Sr was distributed throughout most of the soft tissues of the body. The soft tissue deposits had practically disappeared after 4 h. In the hard tissues of the body 90 Sr accumulated up to 24-72 h. Fifteen minutes after injection the uptake of 90 Sr in the enamel of the teeth was highest in the occlusal and incisal regions. 90 Sr gradually accumulated throughout the enamel and after 72 h its distribution in this layer was fairly uniform. Immediately after injection a narrow zone of radioactivity appeared in the dentin near the pulp. This zone broadened with time towards the dentinoenamel junction and included the intire dentin layer 72 h after injection. Initially, the uptake of 90 Sr was higher in the dentin than in the enamel, particularly in the cervical areas of the crown. This difference became less apparent with time. There was good correlation between the uptake in the teeth and bones, supporting the use of teeth as indicators of the 90 Sr body burden. (author)

Determination of 90Sr by liquid scintillation counting

International Nuclear Information System (INIS)

Cerchetti, Maria L.; Aghazarian, V.P.

2006-01-01

99m Tc, the result of the radioactive decay of 99 Mo, is one of the most applied radioisotopes in nuclear medicine and is used in nuclear medicine as a radiopharmaceutical product. It is important to ensure 99 Mo quality in order to fit the 99m Tc quality specifications. The main objective was to obtain a technique for 90 Sr determination in 99 Mo and environmental samples. The purification of 90 Sr is performed by extraction chromatography where crown-ether resin (Sr-Spec, Eichrom) was used. The measurement of the 90 Sr activity is performed by Liquid Scintillation Counting (LSC) using the double windows method. This method permits the 90 Sr determination without waiting until radiochemical equilibrium 90 Sr / 90 Y has been reached. The recovery factor was determined by gamma spectrometry with 85 Sr, and by gravimetry with stable strontium carrier solution. The minimum detectable activity was 0,05 Bq. The recovery factor was the major contribution in the total uncertainty. (author)

The lower Mesozoic record of detrital zircon U-Pb geochronology of Sonora, Mexico, and its paleogeographic implications

OpenAIRE

González-León, Carlos M.; Valencia, Víctor A.; Lawton, Timothy F.; Amato, Jeffrey M.; Gehrels, George E.; Leggett, William J.; Montijo-Contreras, Óscar; Fernández, Miguel A.

2009-01-01

Detrital zircon U-Pb geochronology from each of the formations of the Triassic-Lower Jurassic Barranca and El Antimonio groups of central and northwestern Sonora and from the Lower Jurassic Basomari and Middle Jurassic Lily formations of northern Sonora indicate they contain distinctive zircon populations. A Proterozoic population has peak ages near 1.8, 1.7, 1.6, 1.4, and 1.1 Ga. A population of Permo-Triassic grains with important peak ages near 269, 254, 245, 234 and 227 Ma. A third popula...

Test for the determination of 90Sr in soil

International Nuclear Information System (INIS)

1980-01-01

The standardized method is based on the chemical separation (extraction, precipitation, etc.) of 90 Sr from other fission products. After long-term storage for 90 Sr- 90 Y equilibrium the activity of the sample precipitated in the form of Y(COO) 2 is measured. The Sr yield coefficient is determined by 85 Sr tracer or by gravimetry. The test is applicable for the determination of 90 Sr contamination originating from fallout or from other sources in soil, when the concentration of 90 Sr is higher than 0.2-0.4 Bqg -1 (5-10 pCig -1 ). The error of the method is less than +-2% of the amount of the 90 Sr present. (Sz.J.)

In-situ temperature calibration below 1 K using the μ+ Knight shift in CMN

International Nuclear Information System (INIS)

Heffner, R.H.; Le, L.P.; Amato, A.; Baines, C.

1996-01-01

The authors present μ + paramagnetic shift measurements between 12 K and about 65 mK in cerium magnesium nitrate (CMN) to investigate its utility as an in-situ temperature calibration source for low temperature μSR experiments. CMN is a salt which exhibits Curie-law susceptibility to temperatures as low as 5 mK. The μ + Knight shift is measured to be (1.46 ± 0.03) x 10 -3 /T + (0.004 ± 0.02) x 10 -3 , corresponding to a transferred hyperfine field of -28.5 kOe/μ B

Effect of low temperature in-situ sintering on the impedance and the performance of intermediate temperature solid oxide fuel cell cathodes

DEFF Research Database (Denmark)

Nielsen, Jimmi; Hjalmarsson, Per; Hansen, Martin Hangaard

2014-01-01

The effect of in-situ sintering temperature and time on the electronic conductivity, impedance and performance of IT-SOFC cathodes were studied. The studied cathodes were for comparison (La0.6Sr0.4)0.99CoO3 (LSC), (La0.6Sr0.4)0.99CoO3:Ce0.9Gd0.1O1.95 (LSC:CGO), La0.58Sr0.4Co0.2Fe0.8O3 (LSCF) and La......0.58Sr0.4Co0.2Fe0.8O3:Ce0.9Gd0.1O1.95 (LSCF:CGO). The LSCF-based cathodes showed poor sintering capabilities compared to the LSC-based cathodes in the studied temperature range of 650–950 °C. The poor necking between individual LSCF grains lower the electronic conductivity. Furthermore, poor cathode....../electrolyte adhesion was seen as an additional high frequency impedance arc, which gradually disappeared as the LSCF cathodes were sintered at increasing temperature. Effects on the impedance shape from poor cathode grain connectivity was shown through impedance simulations to result in a possible increase in the high...

Ca. 890 Ma magmatism in the northwest Yangtze block, South China: SIMS U-Pb dating, in-situ Hf-O isotopes, and tectonic implications

Science.gov (United States)

Zhou, Jiu-Long; Li, Xian-Hua; Tang, Guo-Qiang; Gao, Bing-Yu; Bao, Zhi-An; Ling, Xiao-Xiao; Wu, Li-Guang; Lu, Kai; Zhu, Yu-Sheng; Liao, Xin

2018-01-01

Early Neoproterozoic tectonics of the Yangtze block remains poorly understood because very limited igneous records are available from the time interval of ∼1000-870 Ma. In this paper, our new SIMS U-Pb dating results demonstrate that the Liushudian mafic intrusion and Pinghe alkaline complex in the northwest Yangtze block were emplaced at 888 ± 6 Ma and 891 ± 7 Ma, respectively, representing the products of a ∼890 Ma igneous event. Gabbros from the Liushudian intrusion have rather depleted zircon ɛHf(t) (mean = 10.4) and normal mantle-like zircon δ18O (mean = 5.97‰). Their parental magma was thus probably derived from asthenospheric mantle. Geochemically, these mafic rocks have an affinity to continental flood tholeiitic basalts rather than ocean island basalts, as previously thought. In contrast, an ijolite sample from the Pinghe complex has less depleted zircon ɛHf(t) (mean = 5.7) and anomalously high zircon and apatite δ18O (mean = 13.76‰ and 13.80‰, respectively). Such a characteristic δ18O signal, among the highest yet known for igneous zircons, could be either inherited from a magma source in metasomatized lithospheric mantle or acquired by assimilation of high-δ18O supracrustal materials (e.g., limestone, chert) during magma evolution. An intra-plate extensional environment is suggested for the ∼890 Ma igneous event in the northwest Yangtze block, although it is as yet unclear whether this igneous event is related to a mantle plume or not. It could be concluded that magmatism on the western periphery of the Yangtze block was not shut down between ∼1000 and ∼870 Ma, and the ∼890 Ma intra-plate igneous event may mark either the onset of Neoproterozoic continental rifting or the ending of Late Mesoproterozoic to Early Neoproterozoic lithospheric extension.

High precision time calibration of the Permo-Triassic boundary mass extinction by U-Pb geochronology

Science.gov (United States)

Baresel, Björn; Bucher, Hugo; Brosse, Morgane; Schaltegger, Urs

2014-05-01

U-Pb dating using Chemical Abrasion, Isotope Dilution Thermal Ionization Mass Spectrometry (CA-ID-TIMS) is the analytical method of choice for geochronologists, who are seeking highest temporal resolution and a high degree of accuracy for single grains of zircon. The use of double-isotope tracer solutions, cross-calibrated and assessed in different EARTHTIME labs, coinciding with the reassessment of the uranium decay constants and further improvements in ion counting technology led to unprecedented precision better than 0.1% for single grain, and 0.05% for population ages, respectively. These analytical innovations now allow calibrating magmatic and biological timescales at resolution adequate for both groups of processes. To construct a revised and high resolution calibrated time scale for the Permian-Triassic boundary (PTB) we use (i) high-precision U-Pb zircon age determinations of a unique succession of volcanic ash beds interbedded with shallow to deep water fossiliferous sediments in the Nanpanjiang Basin (South China) combined with (ii) accurate quantitative biochronology based on ammonoids and conodonts and (iii) carbon isotope excursions across the PTB. Using these alignments allows (i) positioning the PTB in different depositional environments and (ii) solving age/stratigraphic contradictions generated by the index, water depth-controlled conodont Hindeodus parvus, whose diachronous first occurrences are arbitrarily used for placing the base of the Triassic. This new age framework provides the basis for a combined calibration of chemostratigraphic records with high-resolution biochronozones of the Late Permian and Early Triassic. Besides the general improvement of the radio-isotopic calibration of the PTB at the ±100 ka level, this will also lead to a better understanding of cause and effect relations involved in this mass extinction.

Interplay between HIV Entry and Transportin-SR2 Dependency

Directory of Open Access Journals (Sweden)

Gijsbers Rik

2011-01-01

Full Text Available Abstract Background Transportin-SR2 (TRN-SR2, TNPO3, transportin 3 was previously identified as an interaction partner of human immunodeficiency virus type 1 (HIV-1 integrase and functions as a nuclear import factor of HIV-1. A possible role of capsid in transportin-SR2-mediated nuclear import was recently suggested by the findings that a chimeric HIV virus, carrying the murine leukemia virus (MLV capsid and matrix proteins, displayed a transportin-SR2 independent phenotype, and that the HIV-1 N74D capsid mutant proved insensitive to transportin-SR2 knockdown. Results Our present analysis of viral specificity reveals that TRN-SR2 is not used to the same extent by all lentiviruses. The DNA flap does not determine the TRN-SR2 requirement of HIV-1. We corroborate the TRN-SR2 independent phenotype of the chimeric HIV virus carrying the MLV capsid and matrix proteins. We reanalyzed the HIV-1 N74D capsid mutant in cells transiently or stably depleted of transportin-SR2 and confirm that the N74D capsid mutant is independent of TRN-SR2 when pseudotyped with the vesicular stomatitis virus glycoprotein (VSV-G. Remarkably, although somewhat less dependent on TRN-SR2 than wild type virus, the N74D capsid mutant carrying the wild type HIV-1 envelope required TRN-SR2 for efficient replication. By pseudotyping with envelopes that mediate pH-independent viral uptake including HIV-1, measles virus and amphotropic MLV envelopes, we demonstrate that HIV-1 N74D capsid mutant viruses retain partial dependency on TRN-SR2. However, this dependency on TRN-SR2 is lost when the HIV N74D capsid mutant is pseudotyped with envelopes mediating pH-dependent endocytosis, such as the VSV-G and Ebola virus envelopes. Conclusion Here we discover a link between the viral entry of HIV and its interaction with TRN-SR2. Our data confirm the importance of TRN-SR2 in HIV-1 replication and argue for careful interpretation of experiments performed with VSV-G pseudotyped viruses in

Lifetime of an ocean island volcano feeder zone: constraints from U-Pb dating on coexisting zircon and baddeleyite, and 40/39Ar age determinations, Fuerteventura, Canary Islands

Science.gov (United States)

Allibon, James; Ovtcharova, Maria; Bussy, Francois; Cosca, Michael; Schaltegger, Urs; Bussien, Denise; Lewin, Eric

2011-01-01

High-precision isotope dilution - thermal ionization mass spectrometry (ID-TIMS) U-Pb zircon and baddeleyite ages from the PX1 vertically layered mafic intrusion Fuerteventura, Canary Islands, indicate initiation of magma crystallization at 22.10 ± 0.07 Ma. The magmatic activity lasted a minimum of 0.52 Ma. 40Ar/39Ar amphibole dating yielded ages from 21.9 ± 0.6 to 21.8 ± 0.3, identical within errors to the U-Pb ages, despite the expected 1% theoretical bias between 40Ar/39Ar and U-Pb dates. This overlap could result from (i) rapid cooling of the intrusion (i.e., less than the 0.3 to 0.6 Ma 40Ar/39Ar age uncertainties) from closure temperatures (Tc) of zircon (699-988 °C) to amphibole (500-600 °C); (ii) lead loss affecting the youngest zircons; or (iii) excess argon shifting the plateau ages towards older values. The combination of the 40Ar/39Ar and U/Pb datasets implies that the maximum amount of time PX1 intrusion took to cool below amphibole Tc is 0.8 Ma, suggesting PX1 lifetime of 520,000 to 800,000 Ma. Age disparities among coexisting baddeleyite and zircon (22.10 ± 0.07/0.08/0.15 Ma and 21.58 ± 0.15/0.16/0.31 Ma) in a gabbro sample from the pluton margin suggest complex genetic relationships between phases. Baddeleyite is found preserved in plagioclase cores and crystallized early from low silica activity magma. Zircon crystallized later in a higher silica activity environment and is found in secondary scapolite and is found close to calcite veins, in secondary scapolite that recrystallised from plagioclase. close to calcite veins. Oxygen isotope δ18O values of altered plagioclase are high (+7.7), indicating interaction with fluids derived from host-rock carbonatites. The coexistence of baddeleyite and zircon is ascribed to interaction of the PX1 gabbro with CO2-rich carbonatite-derived fluids released during contact metamorphism.

44/40Ca and 87Sr/86Sr isotopes as tracers of silicate weathering in small catchments of the Massif Central, France

Science.gov (United States)

Négrel, Philippe; Guerrot, Catherine; Millot, Romain; Petelet-Giraud, Emmanuelle; Bullen, Thomas

2013-04-01

We present calcium stable isotope and strontium radiogenic isotope data for soils and sediments developed on volcanic and igneous rocks forming small catchments in the Massif Central (France). Measurements of 44/40Ca isotope ratios (44/40Ca measured by the double spike method on TIMS and normalized to the value for seawater Ca in delta units) in rocks, sediments and soils from silicate catchments (e.g. granite and basalts) together with 87Sr/86Sr isotope ratios permit an examination of the relationships of these isotope systematics during weathering of silicate rocks. We have analysed the granite, weathered granite (arene) and saprolite, sediment and soil overlying the granite on one hand and the basanite, sediment and soil overlying the basanite on the other. The main bedrock in the volcanic zone (e.g. Allanche catchment) is 11 to 2.5 Ma basanite (nephelinitic to leucitic basalts) having SiO2 between 41-45 wt. %, Na2O + K2O bank have 87Sr/86Sr ratios greater than that of the arene with values increasing in the sediment from the surface down to soil. The 87Sr/86Sr vs. Rb/Sr variation observed in the volcanic area likewise confirms the weathering of low 87Sr/86Sr, low Rb/Sr phases in the bedrock, and there is a linear increase in 87Sr/86Sr and Rb/Sr ratios from those in the sediment up to the values observed in the soils. In the volcanic area, the basanite bedrock has 44/40Ca = -0.94 ± 0.05‰ (n = 7), while the soils and sediments have 44/40Ca of -0.75 to -1.13‰ and -0.79 to -1.01‰, respectively. These results suggest that Ca isotopes are not strongly fractionated during weathering of the basalt. The granite whole-rock has 44/40Ca of -1.29‰, while the soil and sediments have 44/40Ca of -1.93 to -2.07‰ and -1.98 to -2.81‰, respectively, with values decreasing as the Ca content decreases. The 44/40Ca ratios of arene, soil and sediment are similar to or less than that of K- feldspar, reflecting complete loss of the relatively heavy Ca from plagioclase and

Oxygen dosing the surface of SrTiO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Dudy, L.; Scheiderer, P.; Schuetz, P.; Gabel, J.; Buchwald, M.; Sing, M.; Claessen, R. [Physikalisches Institut, Universitaet Wuerzburg (Germany); Denlinger, J.D. [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, 94270 (United States); Schlueter, C.; Lee, T.L. [Diamond Light Source Ltd., Didcot, Oxfordshire (United Kingdom)

2015-07-01

The highly mobile two-dimensional electron system (2DES) on the surface of the insulating SrTiO{sub 3}(STO) offers exciting perspectives for advanced material design. This 2DES resides in a depletion layer caused by oxygen deficiency of the surface. With photoemission spectroscopy, we monitor the appearance of quasi-particle weight (QP) at the Fermi energy and oxygen vacancy induced states in the band gap (IG). Both, QP and IG weight, increase and decrease respectively upon exposure to extreme ultraviolet (XUV) light and in-situ oxygen dosing. By a proper adjustment of oxygen dosing, any intermediate state can be stabilized providing full control over the charge carrier density. From a comparison of the charge carrier concentrations obtained from an analysis of core-level spectra and the Fermi-surface volume, we conclude on a spatially inhomogeneous surface electronic structure with at least two different phases.

Nano-SIMS analysis of Mg, Sr, Ba and U in natural calcium carbonate

International Nuclear Information System (INIS)

Sano, Yuji; Shirai, Kotaro; Takahata, Naoto; Hirata, Takafumi; Sturchio, Neil C.

2005-01-01

Concentrations of minor (Mg and Sr) and trace (Ba and U) elements in four natural calcium carbonate samples were first analyzed by inductively coupled plasma mass spectrometry (ICP-MS) after chemical dissolution and calibrated against a standard dolomite. Their homogeneities were checked by in situ laser ablation (LA) ICP-MS with 10-20 spots. The carbonate samples were measured by using a high lateral resolution secondary ion mass spectrometer (Nano-SIMS NS50). A ∼4 nA O - primary beam was used to sputter a 5 - 6-μm diameter crater on the sample surface, and secondary positive ions were extracted for mass analysis using an accelerating voltage of 8 kV and a Mattauch-Herzog geometry. A multi-collector system was adjusted to detect 26 Mg + , 43 Ca + , 88 Sr + , 138 Ba + , 238 U 16 O 2 + ions at the same time. A resolving power of 2500 - 5000 at 10% peak height was attained by an entrance slit set at 40 μm, and each exit slit at 50 μm with adequate flat-topped peaks. The observed 26 Mg/ 43 Ca, 88 Sr/ 43 Ca, 138 Ba/ 43 Ca and 238 U 16 O 2 / 43 Ca ratios agreed well with those measured by LA-ICP-MS. Foraminifera shells were analyzed at 5 - 6 μm scale by Nano-SIMS. There was a large variation of the Mg/Ca ratios, up to ±38%, even in a single fragment of the shell, suggesting that although the ratios provide a useful paleoceanographic proxy at bulk scale, they may reflect a more complex pattern at <10 μm scale. (author)

Age determination of Precambrian rocks from Greenland: past and present

International Nuclear Information System (INIS)

Karlsbeek, F.

1997-01-01

For Precambrian rocks as well as for younger igneous intrusions, precise ages can only be obtained by isotopic analysis of minerals or rocks. Isotopic (radiometric) age determination of Greenland rocks began in the early 1960s and has continued since with gradually improving methods. In this contribution, the development of geochronological knowledge of the Precambrian of Greenland is described in historical perspective, and an outline of new results is given. The history of geochronology can be roughly divided into three periods: 1) a period of single-sample K-Ar and Rb-Sr mineral or whole-rock age determinations; 2) a time when most ages were determined with the help of Rb-Sr and Pb-Pb whole-rock isochrones and multi-grain zircon U-Pb isotope data; 3) the present, where 'single' zircon U-Pb data are the preferred method to obtain rock ages. These stages in the development of radiometric dating methods partly overlap in time, and each has yielded very significant contributions to the knowledge of Precambiran evolution in Greenland. (EG)

Detrital zircon U-Pb and (U-Th)/He double-dating of Upper Cretaceous-Cenozoic Zagros foreland basin strata in the Kurdistan Region of northern Iraq

Science.gov (United States)

Barber, D. E.; Stockli, D. F.; Koshnaw, R. I.; Horton, B. K.; Tamar-Agha, M. Y.; Kendall, J. J.

2014-12-01

The NW Zagros orogen is the result of the multistage collisional history associated with Late Cretaceous-Cenozoic convergence of the Arabian and Eurasian continents and final closure of Neotethys. Siliciclastic strata preserved within a ~400 km segment of the NW Zagros fold-thrust belt and foreland basin in the Iraqi Kurdistan Region (IKR) provide a widespread record of exhumation and sedimentation. As a means of assessing NW Zagros foreland basin evolution and chronostratigraphy, we present coupled detrital zircon (DZ) U-Pb and (U-Th)/He geo-thermochronometric data of Upper Cretaceous to Pliocene siliciclastic strata from the Duhok, Erbil, and Suleimaniyah provinces of IKR. LA-ICP-MS U-Pb age analyses reveal that the foreland basin fill in IKR in general was dominantly derived from Pan-African/Arabian-Nubian, Peri-Gondwandan, Eurasian, and Cretaceous volcanic arc terrenes. However, the provenance of these strata varies systematically along strike and through time, with an overall increase in complexity upsection. DZ age distribution of Paleocene-Eocene strata is dominated by a ~95 Ma grain age population, likely sourced from the Late Cretaceous Hassanbag-Bitlis volcanic arc complex along the northern margin of Arabia. In contrast, DZ U-Pb age distributions of Neogene strata show a major contribution derived from various Eurasian (e.g., Iranian, Tauride, Pontide; ~45, 150, 300 Ma) and Pan-African (~550, 950 Ma) sources. The introduction of Eurasian DZ ages at the Paleogene-Neogene transition likely records the onset of Arabian-Eurasian collision. Along strike to the southeast, the DZ U-Pb spectra of Neogene strata show a decreased percentage of Pan-African, Peri-Gondwandan, Tauride, and Ordovician ages, coupled with a dramatic increase in 40-50 Ma DZ ages that correspond to Urumieh-Dokhtar magmatic rocks in Iran. Combined with paleocurrent data, this suggests that Neogene sediments were transported longitudinally southeastward through an unbroken foreland basin

U-Pb age constraints for the La Tuna Granite and Montevideo Formation (Paleoproterozoic, Uruguay): Unravelling the structure of the Río de la Plata Craton

Science.gov (United States)

Pamoukaghlián, Karina; Gaucher, Claudio; Frei, Robert; Poiré, Daniel G.; Chemale, Farid; Frei, Dirk; Will, Thomas M.

2017-11-01

The Río de la Plata Craton is a continental block that crops out in Uruguay, eastern Argentina, southernmost Brazil and Paraguay. It comprises in Uruguay the Piedra Alta, Tandilia and Nico Pérez terranes, separated by the Colonia and the Sarandí del Yí megashears. The La Tuna Granite, which intrudes the Araminda metasandstones in the Tandilia Terrane, was considered Cambrian in age and the intruded sandstones were assigned to the Neoproterozoic Piedras de Afilar Formation. We show that the granite is Paleoproterozoic in age and that the host metasandstones do not belong to the Piedras de Afilar Formation, but to the Paleoproterozoic Montevideo Formation. U-Pb LA ICP-MS of zircon ages for the La Tuna Granite yielded a concordant crystallization age of 2156 ± 26 Ma. Furthermore a metamorphic event at 2010 ± 9 Ma is revealed by Pb stepwise leaching dating of monazites. U-Pb detrital zircon ages of the host Araminda metasandstone yield an upper intercept discordia age of 2152 ± 29 Ma, which marks the intrusion of the La Tuna pluton, and which is in accordance with the zircon U-Pb LA ICP MS constraints. A concordant U-Pb detrital zircon age of 2465 ± 40 Ma provides a maximum depositional age constraint for the metapsammites. Comparing quartz arenites of the Ediacaran Piedras de Afilar Formation with the Araminda metaquartzites, we conclude that they are very similar regarding petrology but they differ in age and metamorphic overprint. Detrital zircons in quartz arenites of the Piedras de Afilar Formation show youngest ages of 1.0 Ga. On the other hand, detrital zircons recovered from the Araminda metasandstones and the age of the intruding granite allow interpreting a depositional age between 2465 and 2150 Ma. Nd model ages show crustal residence times in average more than 200 myr older for the Tandilia Terrane both in Uruguay and Argentina, with a significant Neoarchean component, which is lacking in the Piedra Alta Terrane. Whereas the Piedra Alta Terrane was

Hybrid HF-DFT comparative study of SrZrO{sub 3} and SrTiO{sub 3}(001) surface properties

Energy Technology Data Exchange (ETDEWEB)

Evarestov, R.A.; Bandura, A.V.; Alexandrov, V.E. [Department of Quantum Chemistry, St. Petersburg State University, 26 Universitetskii Prospekt, Stary Petergof, 198504 St. Petersburg (Russian Federation)

2006-10-15

Hybrid HF-DFT LCAO simulations of SrZrO{sub 3} and SrTiO{sub 3}(001) surface properties are performed in a single-slab model framework. The SrZrO{sub 3}(001) surface was studied by an ab initio method for the first time. Three slab models with different surface terminations including up to 8 atomic planes were used for calculation of the various surface characteristics (surface energies, atomic charges, density of electronic states). The dependence of the results on the chosen model and on the kind of d-element is analyzed. The dissimilarity in the surface oxygen atom contributions to the total density of states of two crystals is attributed to the more ionic nature of Zr-O bonds compared to Ti-O bonds. It is found that in the case of SrZrO{sub 3} the electronic density is biased towards the SrO-terminated surface and this surface should be more basic in nature than the SrO surface of SrTiO{sub 3} crystal. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Determination of the electrostatic potential distribution in Pt/Fe:SrTiO₃/Nb:SrTiO₃ thin-film structures by electron holography.

Science.gov (United States)

Marchewka, Astrid; Cooper, David; Lenser, Christian; Menzel, Stephan; Du, Hongchu; Dittmann, Regina; Dunin-Borkowski, Rafal E; Waser, Rainer

2014-11-10

We determined the electrostatic potential distribution in pristine Pt/Fe:SrTiO3/Nb:SrTiO3 structures by electron holography experiments, revealing the existence of a depletion layer extending into the Nb-doped bottom electrode. Simulations of potential profiles in metal-insulator-metal structures were conducted assuming different types and distributions of dopants. It is found that the presence of acceptor-type dopant concentrations at the Fe:SrTiO3/Nb:SrTiO3 interface with a donor-doped insulating layer provides a good match to the measured profile. Such acceptor-type interface concentrations may be associated with Sr vacancies on the Nb:SrTiO3 side of the bottom interface.

Using noble gases and 87Sr/86Sr to constrain heat sources and fluid evolution at the Los Azufres Geothermal Field, Mexico

Science.gov (United States)

Wen, T.; Pinti, D. L.; Castro, M. C.; Lopez Hernandez, A.; Hall, C. M.; Shouakar-Stash, O.; Sandoval-Medina, F.

2017-12-01

Geothermal wells and hot springs were sampled for noble gases' volume fraction and isotopic measurements and 87Sr/86Sr in the Los Azufres Geothermal Field (LAGF), Mexico, to understand the evolution of fluid circulation following three decades of exploitation and re-injection of used brines. The LAGF, divided into the Southern Production Zone (SPZ) and the Northern Production Zone (NPZ), is hosted in a Miocene to Pliocene andesitic volcanic complex covered by Quaternary rhyolitic-dacitic units. Air contamination corrected 3He/4He ratios (Rc) normalized to the atmospheric ratio (Ra=1.384 x 10-6), show a median value of 6.58 indicating a dominant mantle helium component. Contributions of crustal helium up to 53% and 18% are observed in NPZ and SPZ, respectively. Observations based on Rc/Ra and 87Sr/86Sr ratios points to the mixing of three magmatic sources supplying mantle helium to the LAGF: (1) a pure mantle He (Rc/Ra = 8) and Sr (87Sr/86Sr = 0.7035) source; (2) a pure mantle helium (Rc/Ra = 8) with some radiogenic Sr (87Sr/86Sr = 0.7049) source possibly resulting from Quaternary rhyolitic volcanism; and (3) a fossil mantle He component (Rc/Ra = 3.8) with some radiogenic Sr (87Sr/86Sr = 0.7038), corresponding possibly to the Miocene andesite reservoir. Intrusions within the last 50 kyrs from sources (1) and (2) are likely responsible for the addition of mantle volatiles and heat to the hydrothermal system of Los Azufres. He and Ar isotopes indicate that heat flow is transported by both convection and conduction. Atmospheric noble gas elemental ratios suggest that geothermal wells located closer to the western re-injection zone are beginning to be dominated by re-injection of used brines (injectate). The area affected by boiling in LAGF has further extended to the north and west since the last noble gas sampling campaign in 2009.

Thermodynamic modeling of the Sr-Co-Fe-O system

DEFF Research Database (Denmark)

Zhang, Wei Wei; Povoden-Karadeniz, Erwin; Chen, Ming

2016-01-01

This paper reviews and assesses phase equilibria and thermodynamic properties of phases in the Sr-Co-Fe-O system, with a focus on oxides, especially the SrCo1 - xFexO3 - δ perovskite. In our work, the SrCo1 - xFexO3 - δ perovskite was modeled with a three-sublattice model, where the three...... sublattices correspond to the A, B and oxygen sites in an ABO3 perovskite, respectively. A number of other important ternary oxide phases in Sr-Co-O and Sr-Co-Fe-O were also considered. Available thermodynamic and phase diagram data were carefully assessed. A thermodynamic description of Sr-Co-O was derived...... using the CALPHAD approach and was further extrapolated to that of Sr-Co-Fe-O. The thermodynamic database of Sr-Co-Fe-O established in this work allows for calculating phase diagrams, thermodynamic properties, cation distribution and defect chemistry properties, and therefore enables material...

Factors affecting 90Sr uptake from the ration

International Nuclear Information System (INIS)

Knizhnikov, V.A.; Marej, A.N.; Borisov, B.K.; Petukhova, Eh.V.

1980-01-01

The dependence of 90 Sr uptake in the human organism on nutrition peculiarities is shown. Strontium-90 polluting vegetable products due to particle sorption from the air is less available for the uptake than 90 Sr resorbed from the soil with vegetation. Therefore, this nuclide is uptaken more completely from milk which containes 90 Sr in a soluble form than from grain and bakery products which are polluted by 90 Sr largely by air

Refinement of Mg{sub 2}Si reinforcement in a commercial Al–20%Mg{sub 2}Si in-situ composite with bismuth, antimony and strontium

Energy Technology Data Exchange (ETDEWEB)

Nordin, Nur Azmah; Farahany, Saeed, E-mail: saeedfarahany@gmail.com; Ourdjini, Ali; Abu Bakar, Tuty Asma; Hamzah, Esah

2013-12-15

Refinement by addition elements of Al–Mg{sub 2}Si alloys is known to result in a change of primary Mg{sub 2}Si morphology. In this paper, the effects of Bi, Sb and Sr on the characteristic parameters of Al–20%Mg{sub 2}Si in-situ composite have been investigated by computer aided cooling curve thermal analysis and microstructural inspection. Size, density and aspect ratio measurements showed that additions of 0.4 wt.% Bi, 0.8 wt.% Sb and 0.01 wt.% Sr refined the Mg{sub 2}Si reinforcement. Exceeding these concentrations, however, resulted in coarsening of Mg{sub 2}Si particles with no change in the morphology. The results also showed that addition elements caused a decrease in the nucleation and growth temperatures of Mg{sub 2}Si particles. The refining effect of Bi, Sb and Sr is likely to be related to the effect of oxide bifilms suspended in the composite melt as favored nucleation substrates for Mg{sub 2}Si particles. - Highlight: • 0.4 wt.%, 0.8 wt.% and 0.01 wt.% is the optimum content for Bi, Sb and Sr addition. • Exceeding optimum concentration resulted in the coarsening of reinforcements. • Nucleation and growth temperatures decrease with addition of Bi, Sb and Sr. • The refining effect of Bi, Sb and Sr is likely to be related to the oxide bifilms.

Decoupling of unpolluted temperate forests from rock nutrient sources revealed by natural 87Sr/86Sr and 84Sr tracer addition

Science.gov (United States)

Kennedy, Martin J.; Hedin, Lars O.; Derry, Louis A.

2002-01-01

An experimental tracer addition of 84Sr to an unpolluted temperate forest site in southern Chile, as well as the natural variation of 87Sr/86Sr within plants and soils, indicates that mechanisms in shallow soil organic horizons are of key importance for retaining and recycling atmospheric cation inputs at scales of decades or less. The dominant tree species Nothofagus nitida feeds nearly exclusively (>90%) on cations of atmospheric origin, despite strong variations in tree size and location in the forest landscape. Our results illustrate that (i) unpolluted temperate forests can become nutritionally decoupled from deeper weathering processes, virtually functioning as atmospherically fed ecosystems, and (ii) base cation turnover times are considerably more rapid than previously recognized in the plant available pool of soil. These results challenge the prevalent paradigm that plants largely feed on rock-derived cations and have important implications for understanding sensitivity of forests to air pollution. PMID:12119394

Size exclusion chromatography for semipreparative scale separation of Au38(SR)24 and Au40(SR)24 and larger clusters.

Science.gov (United States)

Knoppe, Stefan; Boudon, Julien; Dolamic, Igor; Dass, Amala; Bürgi, Thomas

2011-07-01

Size exclusion chromatography (SEC) on a semipreparative scale (10 mg and more) was used to size-select ultrasmall gold nanoclusters (<2 nm) from polydisperse mixtures. In particular, the ubiquitous byproducts of the etching process toward Au(38)(SR)(24) (SR, thiolate) clusters were separated and gained in high monodispersity (based on mass spectrometry). The isolated fractions were characterized by UV-vis spectroscopy, MALDI mass spectrometry, HPLC, and electron microscopy. Most notably, the separation of Au(38)(SR)(24) and Au(40)(SR)(24) clusters is demonstrated.

Thermodynamic modeling of the Sr-Co-Fe-O system

DEFF Research Database (Denmark)

Zhang, Wei Wei; Povoden-Karadeniz, Erwin; Chen, Ming

2016-01-01

This paper reviews and assesses phase equilibria and thermodynamic properties of phases in the Sr-Co-Fe-O system, with a focus on oxides, especially the SrCo1 - xFexO3 - δ perovskite. In our work, the SrCo1 - xFexO3 - δ perovskite was modeled with a three-sublattice model, where the three...... sublattices correspond to the A, B and oxygen sites in an ABO3 perovskite, respectively. A number of other important ternary oxide phases in Sr-Co-O and Sr-Co-Fe-O were also considered. Available thermodynamic and phase diagram data were carefully assessed. A thermodynamic description of Sr-Co-O was derived...

U-Pb zircon geochronology of Late Devonian to Early Carboniferous extension-related silicic volcanism in the northern New England Fold Belt

International Nuclear Information System (INIS)

Bryan, S.E.; Holcombe, R.J.; Fielding, C.R.; Allen, C.M.

2004-01-01

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis of zircons confirm a Late Devonian to Early Carboniferous age (ca 360-350 Ma) for silicic volcanic rocks of the Campwyn Volcanics and Yarrol terrane of the northern New England Fold Belt (Queensland). These rocks are coeval with silicic volcanism recorded elsewhere in the fold belt at this time (Connors Arch, Drummond Basin). The new U-Pb zircon ages, in combination with those from previous studies, show that silicic magmatism was both widespread across the northern New England Fold Belt (>250 000 km 2 and >500 km inboard of plate margin) and protracted, occurring over a period of -15 million years. Zircon inheritance is commonplace in the Late Devonian - Early Carboniferous volcanics, reflecting anatectic melting and considerable reworking of continental crust. Inherited zircon components range from ca 370 to ca 2050 Ma, with Middle Devonian (385-370 Ma) zircons being common to almost all dated units. Precambrian zircon components record either Precambrian crystalline crust or sedimentary accumulations that were present above or within the zone of magma formation This contrasts with a lack of significant zircon inheritance in younger Permo-Carboniferous igneous rocks intruded through,and emplaced on top of, the Devonian-Carboniferous successions. The inheritance data and location of these volcanic rocks at the eastern margins of the northern New England Fold Belt, coupled with Sr-Nd, Pb isotopic data and depleted mantle model ages for Late Palaeozoic and Mesozoic magmatism, imply that Precambrian mafic and felsic crustal materials (potentially as old as 2050 Ma), or at the very least Lower Palaeozoic rocks derived from the reworking of Precambrian rocks, comprise basement to the eastern parts of the fold belt. This crustal basement architecture may be a relict from the Late Proterozoic breakup of the Rodinian supercontinent. Copyright (2004) Geological Society of Australia

Zircon U-Pb geochronology and geochemistry of granites in the Zhuguangshan complex, South China: Implications for uranium mineralization

Science.gov (United States)

Zhang, Long; Chen, Zhenyu; Li, Xiaofeng; Li, Shengrong; Santosh, M.; Huang, Guolong

2018-05-01

The Zhuguangshan complex, composed of Caledonian, Indosinian, and Yanshanian granites, and Cretaceous mafic dykes, is one of the most important granite-hosted uranium producers in South China. Here we present LA-ICP-MS zircon U-Pb and hornblende 40Ar/39Ar geochronology and whole-rock and biotite geochemistry for the granites in this complex to evaluate the magmatism and its constraints on uranium mineralization. Samples collected from the Fuxi, Youdong, Longhuashan, Chikeng, Qiling, and Sanjiangkou intrusions yield zircon weighted 206Pb/238U ages of 426.7 ± 5.4 Ma, 226.4 ± 3.5 Ma, 225.0 ± 2.7 Ma, 152.2 ± 3.0 Ma, 153.9 ± 2.1 Ma, and 155.2 ± 2.1 Ma, respectively. A new Ar-Ar dating of the hornblende of the diabase from the Changjiang uranium ore field yields a plateau age of 145.1 ± 1.5 Ma. These results coupled with published geochronological data indicate that six major magmatic events occurred in the study area at 420-435 Ma, 225-240 Ma, 150-165 Ma, 140 Ma, 105 Ma, and 90 Ma. Both U-bearing and barren granites occur in this complex, and they display differences in whole-rock and biotite geochemistry. The barren granites show higher Al2O3, CaO, TFMM, Rb, Zr, Ba, SI, Mg#, (La/Yb)N, and Eu/Eu*, but lower SiO2, ALK, Rb, DI, Rb/Sr, and TiO2/MgO than those of the U-bearing granites. Biotites in the U-bearing granites are close to the Fe-rich siderophyllite-annite end member with Fe/(Fe + Mg) ratios higher than 0.66, whereas those in the barren granites are relatively close to the Mg-rich eastonite-phlogopite end member with Fe/(Fe + Mg) ratios uranium ore potential of the granites in the Zhuguangshan complex. The geochemical variations of U-bearing and barren granites can serve as a potential detector for granite-hosted uranium deposits.

Timing of the Permian-Triassic biotic crisis: implications from new zircon U/Pb age data (and their limitations)

Science.gov (United States)

Mundil, Roland; Metcalfe, Ian; Ludwig, Kenneth R.; Renne, Paul R.; Oberli, Felix; Nicoll, Robert S.

2001-04-01

The most profound biotic crisis in the Earth's history, causing the near extinction of both terrestrial and marine life, occurred at the end of the Permian period about 253 Myr ago and marks the Paleozoic-Mesozoic era boundary. The cause of this event is still a matter of vigorous debate, with both brief and catastrophic as well as gradual mechanisms having been proposed. Similar to a recent landmark study, this study uses the U-Pb method on zircons from the uppermost Permian/lowermost Triassic ash fall deposits at Meishan (Zhejiang Province, SE China) in order to examine time and rate constraints for these events. The results of both this study and previous work show that for these ash layers, the effects of Pb loss are combined with varying amounts and sources of inheritance, resulting in an age scatter which prohibits the extraction of a statistically robust age in many cases. Though the effects of Pb loss on the zircons analyzed in this study were reduced by leaching the grains in hydrofluoric acid (as opposed to commonly applied air abrasion) prior to analysis, the presence within a single ash layer of multiple generations of older xenocrysts (in many cases only slightly older than the depositional age) has made quantitative interpretation even more difficult. When these combined phenomena bias individual zircon ages by less than a percent, they are extremely difficult to deconvolute, and, if multi-grain analyses are used, can become impossible to recognize (because of the resulting age averaging). Monte Carlo simulations using actual measurements of individual zircon crystals show that age excursions due to Pb loss and xenocrystic contamination for the Meishan bentonites are easily homogenized to the point of undetectability when replicate analyses of multi-grain zircon samples are compared. Thus this study uses only high-precision analyses of single crystals, whether from our work or that of previous studies. Three main conclusions have emerged. First, our

The 87Sr/86Sr aquatic isoscape of the Danube catchment from the source to the mouth as tool for studying fish migrations

Science.gov (United States)

Zitek, Andreas; Tchaikovsky, Anastassiya; Irrgeher, Johanna; Waidbacher, Herwig; Prohaska, Thomas

2014-05-01

Isoscapes - spatially distributed isotope patterns across landscapes - are increasingly used as important basis for ecological studies. The natural variation of the isotopic abundances in a studied area bears the potential to be used as natural tracer for studying e.g. migrations of animals or prey-predator relations. The 87Sr/86Sr ratio is one important tracer, since it is known to provide a direct relation of biological samples to geologically distinct regions, as Sr isotopes are incorporated into living tissues as a proxy for calcium and taken up from the environment without any significant fractionation. Although until now the focus has been mainly set on terrestrial systems, maps for aquatic systems are increasingly being established. Here we present the first 87Sr/86Sr aquatic isoscape of the Danube catchment, the second largest river catchment in Europe, from near its source starting at river km 2581 in Germany down to its mouth to river km 107 in Romania. The total length of the river Danube is 2780 km draining a catchment area 801 463 km2 (10 % of the European continent). The major purpose of this study was to assess the potential of the 87Sr/86Sr isotope ratio to be used as tool for studying fish migrations at different scales in the entire Danube catchment. Within the Joint Danube Research 3 (JDS 3), the biggest scientific multi-disciplinary river expedition of the World in 2013 aiming at the assessment of the ecological status and degree of human alterations along the river Danube, water samples were taken at 68 pre-defined sites along the course of the river Danube including the major tributaries as a basis to create the so called 'Isoscape of the Danube catchment'. The determination of 87Sr/86Sr isotope ratio in river water was performed by multicollector-sector field-inductively coupled plasma-mass spectrometry (MC-SF-ICP-MS). The JDS 3 data were combined with existing data from prior studies conducted within the Austrian part of the Danube catchment

Rapid determination of 90Sr in seawater

International Nuclear Information System (INIS)

Pavlotskaya, F.I.; Moskin, A.I.

1994-01-01

A method for determining 90 Sr in seawater that is based on direct isolation and radiochemical purification of daughter 90 Y is proposed. The analysis time is 6-8 h. The chemical yield of the Y-carrier during the 90 Sr determination from 35 liters of seawater varies in the range 37-69%. The analysis uncertainty is 90 Sr from seawater and subsequent isolation of 90 Y

Detail AR2-PR1 geochronological scale of the Baltic Shield

International Nuclear Information System (INIS)

Balashov, Yu.A.

1995-01-01

The version of the detail scale of the Precambrian Baltic Shield, based on selection of new crust increment through mantel genesis material is presented. The AR 2 -PR 1 -scale of the Baltic Shield is based through U-Pb, Rb-Sr and Sm-Nd-methods for the Cord Peninsula on the Precambrian period of the other Baltic Shield regions

Rocks age and metamorphic occurrence from the southeastern part of Sao Paulo State and their crustal evaluation

International Nuclear Information System (INIS)

Tassinari, C.C.G.

1988-01-01

Pb-Pb and Rb-Sr whole rock isotope systematics and U-Pb on zircons method analyses are reported for rocks from the southeastern part of Sao Paulo state Brazil. The isotopic studies on granitic intrusions, orthogneissic rocks and migmatitic terranes, in this area, provides an important indication of the age and nature of the continental crust. (author) [pt

PRODUCTION OF PLANTARCIN BY LACTOBACILLUS PLANTARUM SR18

Directory of Open Access Journals (Sweden)

Wagih El-Shouny

2012-06-01

Full Text Available Out of 86 lactobacilli previously screened in our laboratory, Lactobacillus plantarum SR18 isolated from yoghurt revealed the largest detected inhibition zone against the selected indicator Streptococcus salivarius 5. The obtained electrophoretic patterns revealed that L. plantarum SR18 was free from plasmids. Exposure of 6 h growing L. plantarum culture to T-8M, 3B ultraviolet B lamp (8w, 220v & 312 nm for 2 h and subsequent growth for further 24 h resulted in an increase of cell-bound bacteriocin titer reached 2 fold at 12 h. Whereas bacteriocin secreted in the culture filtrate was not affected by UV irradiation. Plantarcin SR18 production was maximal (12800 AU/ml between 12 and 18 h by incubation of the culture at 37°C and pH 5-7 in candle jar (CO2. The bacteriocin bound to the cells and that secreted into the culture filtrate of L. plantarum SR18 were precipitated by 75% ammomium sulphate, dialysed and further purified by Gel filtration on Sephadex G-100. The specific activities (AU/mg protein were increased by a factor of about 5.3 and 2.35 for plantarcins purified from proteins bound to the cell of L. plantarum SR18 (plantarcin SR18 a and that secreted into the culture filtrate (plantarcin SR18 b, respectively. Gel filtration of plantarcin SR18a resulted in moderate antibacterial activity (3200 AU/ml and very high activity (25600 AU/ml of plantarcin SR18b.

90Sr and 89Sr in seawater off Japan as a consequence of the Fukushima Dai-ichi nuclear accident

Directory of Open Access Journals (Sweden)

N. Casacuberta

2013-06-01

Full Text Available The impact of the earthquake and tsunami on the east coast of Japan on 11 March 2011 caused a loss of power at the Fukushima Dai-ichi nuclear power plant (NPP that resulted in one of the most important releases of artificial radioactivity into the environment. Although several works were devoted to evaluating the atmospheric dispersion of radionuclides, the impact of the discharges to the ocean has been less investigated. Here we evaluate the distribution of Fukushima-derived 90Sr (n = 57 and 89Sr (n = 19 throughout waters 30–600 km offshore in June 2011. Concentrations of 90Sr and 89Sr in both surface waters and shallow profiles ranged from 0.8 ± 0.2 to 85 ± 3 Bq m−3 and from 19 ± 6 to 265 ± 74 Bq m−3, respectively. Because of its short half-life, all measured 89Sr was due to the accident, while the 90Sr concentrations can be compared to the background levels in the Pacific Ocean of about 1.2 Bq m−3. Fukushima-derived radiostrontium was mainly detected north of Kuroshio Current, as this was acting as a southern boundary for transport. The highest activities were associated with near-shore eddies, and larger inventories were found in the closest stations to Fukushima NPP. The data evidence a major influence of direct liquid discharges of radiostrontium compared to the atmospheric deposition. Existing 137Cs data reported from the same samples allowed us to establish a 90Sr / 137Cs ratio of 0.0256 ± 0.0006 in seawater off Fukushima, being significantly different than that of the global atmospheric fallout (i.e., 0.63 and may be used in future studies to track waters coming from the east coast of Japan. Liquid discharges of 90Sr to the ocean were estimated, resulting in an inventory of 53 ± 1 TBq of 90Sr in the inshore study area in June 2011 and total releases of 90Sr ranging from 90 to 900 TBq, depending upon the reported estimates of 137Cs releases that are considered.

Crystal structures of KM(AsF6)3 (M2+ = Mg, Co, Mn, Zn), KCu(SbF6)3 and [Co(HF)2]Sr[Sr(HF)]2-[Sr(HF)2]2[AsF6]12

International Nuclear Information System (INIS)

Mazej, Zoran; Goreshnik, Evgeny

2015-01-01

The KM(AsF 6 ) 3 (M 2+ = Mg, Co, Mn, Zn) and KCu(SbF 6 ) 3 compounds crystallize isotypically to previously known KNi(AsF 6 ) 3 . The main features of the structure of these compounds are rings of MF 6 octahedra sharing apexes with AsF 6 octahedra connected into infinite tri-dimensional frameworks. In this arrangement cavities are formed where K + cations are placed. Single crystals of CoSr 5 (AsF 6 ) 12 .8HF were obtained as one of the products after the crystallization of 3KF/CoF 2 /SrF 2 mixture in the presence of AsF 5 in anhydrous HF. The CoSr 5 (AsF 6 ) 12 .8HF is monoclinic, C/2c (No.15), with a = 26.773(5) Aa, b = 10.087(2) Aa, c = 21.141(5) Aa, β = 93.296(13) circle , V = 5699.9(19) Aa 3 at 200 K, and Z = 4. There are three crystallographically non-equivalent Sr 2+ cations in the crystal structure of CoSr 5 (AsF 6 ) 12 .8HF. The Sr1 is coordinated by ten fluorine atoms from eight different [AsF 6 ]- anions, meanwhile Sr2 and Sr3 are bound to nine fluorine atoms provided by one HF and eight AsF 6 units or by two HF and six AsF 6 units, respectively. The Co 2+ is coordinated distorted-octahedrally by six fluorine atoms from two HF molecules and four different AsF 6 units. All those moieties in the crystal structure of [Co(HF) 2 ]Sr[Sr(HF)] 2 [Sr(HF) 2 ] 2 [AsF 6 ] 12 are connected into tridimensional framework. The CoSr 5 (AsF 6 ) 12 .8HF is a unique example of compound where HF molecules are directly bound via fluorine atoms to two different metal centres.

Geographical distribution of 90Sr contamination in Poland

International Nuclear Information System (INIS)

Gaca, P.; Mietelski, J.W.; Skwarzec, B.

2006-01-01

The paper presents results on determination of 90 Sr in bilberry and cowberry leaves (Vaccinium myrtillus and Vaccinium vitis-idaea) and the use of these plants as bio-monitors of radiostrontium contamination in Poland. Radiostrontium was determined by mean of liquid scintillation spectrometry preceded by radiochemical separation using Sr-resin and 85 Sr tracer. The approximate map of 90 Sr contamination of Poland is presented. The activity ratio between 90 Sr and obtained earlier data for 137 Cs in the same samples is discussed. The enhancement of radiostrontium content observed in northeastern Poland seems to be the trace of hot-particles fallout from initial Chernobyl cloud, which passed over Polish territory toward Scandinavia. (orig.)

In-Situ Catalytic Surface Modification of Micro-Structured La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF Oxygen Permeable Membrane Using Vacuum-Assisted technique

Directory of Open Access Journals (Sweden)

Othman Nur Hidayati

2016-01-01

Full Text Available This paper aims at investigating the means to carry out in-situ surface modification of La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF oxygen permeable membrane by using vacuum assisted technique. The unique structure of the LSCF hollow fibre membrane used in this study, which consists of an outer dense oxygen separation layer and conical-shaped microchannels open at the inner surface has allowed the membrane to be used as oxygen separation membrane and as a structured substrate for where catalyst can be deposited. A catalyst solution of similar material, LSCF was prepared using sol-gel technique. Effects of calcination temperature and heating rate were investigated using XRD and TGA to ensure pure perovskites structure of LSCF was obtained. It was found that a lower calcination temperature can be used to obtain pure perovskite phase if slower heating rate is used. The SEM photograph shows that the distribution of catalyst onto the membrane microchannels using in-situ deposition technique was strongly related to the viscosity of LSCF catalytic sol. Interestingly, it was found that the amount of catalyst deposited using viscous solution was slightly higher than the less viscous sol. This might be due to the difficulty of catalyst sol to infiltrate the membrane and as a result, thicker catalyst layer was observed at the lumen rather than onto the conical-shaped microchannels. Therefore, the viscosity of catalyst solution and calcination process should be precisely controlled to ensure homogeneous catalyst layer deposition. Analysis of the elemental composition will be studied in the future using energy dispersive X-ray Spectroscopy (EDX to determine the elements deposited onto the membranes. Once the elemental analysis is confirmed, oxygen permeation analysis will be carried out.

Contrasting pressure effects in Sr2VFeAsO3 and Sr2ScFePO3

International Nuclear Information System (INIS)

Kotegawa, Hisashi; Kawazoe, Takayuki; Tou, Hideki; Murata, Keizo; Ogino, Hiraku; Kishio, Kohji; Shimoyama, Jun-ichi

2009-01-01

We report the resistivity measurements under pressure of two Fe-based superconductors with a thick perovskite oxide layer, Sr 2 VFeAsO 3 and Sr 2 ScFePO 3 . The superconducting transition temperature T c of Sr 2 VFeAsO 3 markedly increases with increasing pressure. Its onset value, which was T c onset =36.4 K at ambient pressure, increases to T c onset =46.0 K at ∼4 GPa, ensuring the potential of the '21113' system as a high-T c material. However, the superconductivity of Sr 2 ScFePO 3 is strongly suppressed under pressure. The T c onset of ∼16 K decreases to ∼5 K at ∼4 GPa, and the zero-resistance state is almost lost. We discuss the factor that induces this contrasting pressure effect. (author)

Rb-Sr ages and initial 87Sr/86Sr ratios of late paleozoic granitic rocks from northern Chile

International Nuclear Information System (INIS)

Shibata, Ken; Ishihara, Shunso; Ulriksen, C.E.

1984-01-01

Rb-Sr whole-rock isochron ages were determined on three suites of so-called Paleozoic granitic rocks from northern coastal Chile. The granitic rocks from the Valparaiso and Ci Funcho areas are dated as 296.3 +- 5.4 Ma and 262.2 +- 4.6 Ma, respectively, which are in accord with geologically estimated age. The rocks from the Chanaral area is dated as 212.8 +- 8.6 Ma, which is correlated close to the Triassic-Jurassic boundary age. A K-Ar age of 196 +- 6 Ma was obtained on biotite in granite from Esmeralda between Ci Funcho and Chanaral. These age results demonstrate that no Precambrian plutonism occurred in the studied area, and that so-called Paleozoic granitic rocks in the Ci Funcho-Chanaral area are divided into Permian and early Mesozoic in age. Initial 87 Sr/ 86 Sr ratios of the ilmenite-series granitic rocks from the coastal region are 0.70641 (Valparaiso), 0.70635 (Ci Funcho) and 0.70455 (Chanaral). These relatively low ratios deny substantial crustal contribution to the granitoids. The initial ratios of magnetite-series granitoids from porphyry- and manto-type mineralized areas (Chiquicamata, El Salvador and Tocopilla) are as low as 0.70344 to 0.70464. (author)

87Sr/86Sr variations in basalts of Late Eocene-Early Miocene series in Eastern Sikhoteh-Alin

International Nuclear Information System (INIS)

Esin, S.V.; Ponomarchuk, V.A.; Shipitsyn, Yu.G.; Palesskij, Yu.G.

1993-01-01

Late Eocene high-alumina and Oligocene high-alumina and magnesian basalts of the Neogene calc-alkaline series from the Eastern Sikhoteh-Alin are shown to have the following 87 Sr/ 86 Sr ratios: 0.70390-0.70465; 0.70347-0.70401, and the 0.70330-0.70347. Analysis of variations of Sr ratios, REE, HFSE, and LILE suggests that they are the products of successive melting of a multicomponent source containing the peridotite material of OIB- and MORB-types altered by fluids to a different degree and the pelagic sediments

Phase equilibria in the system As2-O5 - SrO

International Nuclear Information System (INIS)

Kasenov, B.K.; Ashlyaeva, I.V.

1993-01-01

T-x phase state diagram of As 2 O 5 -SrO system was investigated by the methods of physicochemical analysis. It was established that incongruently melting Sr(AsO 3 ) 2 (t mel 900 deg C), Sr 2 As 2 O 4 (t mel = 1140 deg C), Sr 4 As 2 O 9 (t mel = 1390 deg C) and congruently melting at 1635 deg C Sr 3 (AsO 4 ) 2 formed in the system. Eutectic points were revealed in the system: As 2 O 5 -Sr(AsO 3 ) 2 (15.0 mol % SrO, 700 deg C) and Sr 3 (AsO 4 ) 2 -Sr 4 As 2 O 9 (78 mol % SrO, 1370 deg C)

Low Thermal Conductivity of RE-Doped SrO(SrTiO3)1 Ruddlesden Popper Phase Bulk Materials Prepared by Molten Salt Method

Science.gov (United States)

Putri, Yulia Eka; Said, Suhana Mohd; Refinel, Refinel; Ohtaki, Michitaka; Syukri, Syukri

2018-04-01

The SrO(SrTiO3)1 (Sr2TiO4) Ruddlesden Popper (RP) phase is a natural superlattice comprising of alternately stacking perovskite-type SrTiO3 layers and rock salt SrO layers along the crystallographic c direction. This paper discusses the properties of the Sr2TiO4 and (La, Sm)-doped Sr2TiO4 RP phase synthesized via molten salt method, within the context of thermoelectric applications. A good thermoelectric material requires high electrical conductivity, high Seebeck coefficient and low thermal conductivity. All three conditions have the potential to be fulfilled by the Sr2TiO4 RP phase, in particular, the superlattice structure allows a higher degree of phonon scattering hence resulting in lowered thermal conductivity. In this work, the Sr2TiO4 RP phase is doped with Sm and La respectively, which allows injection of charge carriers, modification of its electronic structure for improvement of the Seebeck coefficient, and most significantly, reduction of thermal conductivity. The particles with submicron size allows excessive phonon scattering along the boundaries, thus reduces the thermal conductivity by fourfold. In particular, the Sm-doped sample exhibited even lower lattice thermal conductivity, which is believed to be due to the mismatch in the ionic radius of Sr and Sm. This finding is useful as a strategy to reduce thermal conductivity of Sr2TiO4 RP phase materials as thermoelectric candidates, by employing dopants of differing ionic radius.

Preparation of highly stable zeolite-alginate foam composite for strontium(90Sr) removal from seawater and evaluation of Sr adsorption performance.

Science.gov (United States)

Hong, Hye-Jin; Kim, Byoung-Gyu; Ryu, Jungho; Park, In-Su; Chung, Kang-Sup; Lee, Sang Moon; Lee, Jin-Bae; Jeong, Hyeon Su; Kim, Hyunchul; Ryu, Taegong

2018-01-01

Alginate bead is a promising strontium (Sr) adsorbent in seawater, but highly concentrated Na ions caused over-swelling and damaged the hydrogel bead. To improve the mechanical stability of alginate bead, flexible foam-type zeolite-alginate composite was synthesized and Sr adsorption performance was evaluated in seawater; 1-10% zeolite immobilized alginate foams were prepared by freeze-dry technique. Immobilization of zeolite into alginate foam converted macro-pores to meso-pores which lead to more compact structure. It resulted in less swollen composite in seawater medium and exhibited highly improved mechanical stability compared with alginate bead. Besides, Sr adsorption efficiency and selectivity were enhanced by immobilization of zeolite in alginate foam due to the increase of Sr binding sites (zeolite). In particular, Sr selectivity against Na was highly improved. The 10% zeolite-alginate foam exhibited a higher log K d of 3.3, while the pure alginate foam exhibited 2.7 in the presence of 0.1 M Na. Finally, in the real seawater, the 10% zeolite-alginate foam exhibited 1.5 times higher Sr adsorption efficiency than the pure alginate foam. This result reveals that zeolite-alginate foam composite is appropriate material for Sr removal in seawater due to its swelling resistance as well as improved Sr adsorption performance in complex media. Copyright © 2017 Elsevier Ltd. All rights reserved.

Geographical traceability based on 87Sr/86Sr indicator: a first approach for PDO Lambrusco wines from Modena.

Science.gov (United States)

Durante, Caterina; Baschieri, Carlo; Bertacchini, Lucia; Cocchi, Marina; Sighinolfi, Simona; Silvestri, Michele; Marchetti, Andrea

2013-12-01

The main goal of this study was to evaluate (87)Sr/(86)Sr ratio in different matrices, namely soils, branches, and grape juices, of an oenological food chain in order to develop a robust analytical strategy able to link the investigated food to its territory of origin. The (87)Sr/(86)Sr has been used as traceability marker and several aspects, affected its variability, i.e. geological features of the investigated area, the bio-available fraction of elements in the soils and the up-take of the plant, have been taken into account. Optimisation of an analytical procedure for the separation of Sr from its interferences and investigation of the analytical performances in terms of precision of used methodology have been carried out as well. This work highlighted a good match between the isotopic values monitored in the bio-available fraction of soils and their respective grape juices for almost all the investigated areas. The correlation with food satisfyingly improves when isotopic relative abundance values of branches vine are considered. Copyright © 2013 Elsevier Ltd. All rights reserved.

FEP report for the safety assessment SR-Can

International Nuclear Information System (INIS)

Skagius, Kristina

2006-11-01

This report documents the analysis and processing of features, events and processes, FEPs, that has been carried out within the safety assessment SR-Can, and forms an important part of the reporting of the project. The SR-Can project is a preparatory stage for the SR-Site assessment, and the report from that project will be used in support of SKB's application to build a final repository. The overall objective of the FEP analysis and processing included development of a database of features, events and processes, an SKB FEP database, in a format that facilitates both a systematic analysis of FEPs and documentation of that FEP analysis, as well as facilitating revisions and updates to be made in connection with new safety assessments. The overall objective also extended to the development of procedures for such a systematic FEP analysis as well as the application of those procedures in order to establish an SR-Can FEP catalogue within the framework of the SKB FEP database. The work started by implementing the content of the SR 97 Process Report into a database format suitable for import and processing of FEP information from other sources. The SR 97 version of the database was systematically audited against the NEA database with Project FEPs, version 1.2. In addition, an earlier audit of the SR 97 process report against the interaction matrices developed for a deep repository of the KBS-3 type was revisited and updated. Relevant FEPs identified through the audit process were sorted into three main categories i) FEPs related to the initial states of the repository system, ii) FEPs related to internal processes of the repository system, and iii) FEPs related to external impacts on the repository system. This resulted in additions to the SR 97 list of processes and to the lists of initial state FEPs and external factors to be addressed in further processing. The further processing of the initial state FEPs revealed that those FEPs that are not covered by the

Layered perovskitic structures in pure and doped LaTiO3.5-x and SrNbO3.5-x

International Nuclear Information System (INIS)

Williams, T.; Lichtenberg, F.; Widmer, D.; Bednorz, J.G.; Reller, A.

1993-01-01

The effect of careful control over metal and oxygen stoichiometry on the structures of various M n+1 M' n+1 O 3n+5 phases (M = La and/or Sr, M' = Ti and/or Nb) has been studied by transmission electron microscopy. In addition to the previously reported n = 3 and 4 layered phases and the n = ∞ parent perovskite, ordered and disordered intergrowth structures comprising the n = 2, 3, 4, and ∞ members have been characterized. The effects of in situ reduction in the electron microscope were studied. 18 refs., 8 figs

The 40Ar/39Ar and U/Pb dating of young rhyolites in the Kos-Nisyros volcanic complex, Eastern Aegean Arc, Greece: Age discordance due to excess 40Ar in biotite

Science.gov (United States)

Bachmann, O.; Schoene, B.; Schnyder, C.; Spikings, R.

2010-08-01

High-precision dating of Quaternary silicic magmas in the active Kos-Nisyros volcanic center (Aegean Arc, Greece) by both 40Ar/39Ar on biotite and U/Pb on zircon reveals a complex geochronological story. U/Pb ID-TIMS multi and single-grain zircon analyses from 3 different units (Agios Mammas and Zini domes, Kefalos Serie pyroclasts) range in age from 0.3 to 0.5 to 10-20 Ma. The youngest dates provide the maximum eruption age, while the oldest zircons indicate inheritance from local continental crust (Miocene and older). Step-heating 40Ar/39Ar experiments on 1-3 crystals of fresh biotite yielded highly disturbed Ar-release patterns with plateau ages typically older than most U/Pb ages. These old plateau ages are probably not a consequence of inheritance from xenocrystic biotites because Ar diffuses extremely fast at magmatic temperatures and ratios are reset within a few days. On the basis of (1) elevated and/or imprecise 40Ar/36Ar ratios, (2) shapes of the Ar release spectra, and (3) a high mantle 3He flux in the Kos-Nisyros area, we suggest that biotite crystals retained some mantle 40Ar that led to the observed, anomalously old ages. In contrast, sanidine crystals from the only sanidine-bearing unit in the Kos-Nisyros volcanic center (the caldera-forming Kos Plateau Tuff) do not appear to store any excess 40Ar relative to atmospheric composition. The eastern edge of the Aegean Arc is tectonically complex, undergoing rapid extension and located close to a major structural boundary. In such regions, which are characterized by high fluxes of mantle volatiles, 40Ar/39Ar geochronology on biotite can lead to erroneous results due to the presence of excess 40Ar and should be checked either against 40Ar/39Ar sanidine or U/Pb zircon ages.

A method for determination of 90Sr in vegetation

International Nuclear Information System (INIS)

Nygren, U.

1998-12-01

This report describes a method for determination of 90 Sr in vegetation. The method consists of wet-ashing the samples and separating Sr from the sample matrix by oxalate precipitation and extraction chromatography. 90 Y ingrowth is awaited after which Y is separated from Sr and 90 Y measured in a proportional counter. The method has been applied on two reference materials and the 90 Sr results agree well with the recommended values. The method has also been used on 20 samples of blueberry twigs and the mean recovery of Sr was 74%

Migration and distribution of 90Sr in soil

International Nuclear Information System (INIS)

Yang Juncheng; Zhu Yongyi; Chen Jingjian

1993-01-01

The migration and distribution of radionuclide 90 Sr were conducted by the analysis of 97 soil longitudinal sections under natural conditions and by pot experiments with fallout and 90 Sr solution, respectively. Spring wheat and rice were employed in the pot experiments. The result showed that the radionuclide 90 Sr was mainly accumulated in the topsoil 0-10 cm under both of the natural and laboratory conditions. The vertical distribution of 90 Sr in soil agreed with the power function, which obtained was Y = 75.78 X -0.527 ; r = -0.986; n = 97. The existing forms of 90 Sr from fallout in soil, only 0.02-0.03% was in a soluble form and 0.06-0.07% in non-replaceable form

OpenNebula KVM SR-IOV driver

CSIR Research Space (South Africa)

Macleod, D

2013-05-01

Full Text Available With the recent release of an OFED which supports SR-IOV on Infiniband HCAs it is now possible to use verbs from inside a VM. This VMM driver supports these Infiniband HCAs, and any other SR-IOV network device, in OpenNebula....

Abscisic Acid (ABA) Regulation of Arabidopsis SR Protein Gene Expression

Science.gov (United States)

Cruz, Tiago M. D.; Carvalho, Raquel F.; Richardson, Dale N.; Duque, Paula

2014-01-01

Serine/arginine-rich (SR) proteins are major modulators of alternative splicing, a key generator of proteomic diversity and flexible means of regulating gene expression likely to be crucial in plant environmental responses. Indeed, mounting evidence implicates splicing factors in signal transduction of the abscisic acid (ABA) phytohormone, which plays pivotal roles in the response to various abiotic stresses. Using real-time RT-qPCR, we analyzed total steady-state transcript levels of the 18 SR and two SR-like genes from Arabidopsis thaliana in seedlings treated with ABA and in genetic backgrounds with altered expression of the ABA-biosynthesis ABA2 and the ABA-signaling ABI1 and ABI4 genes. We also searched for ABA-responsive cis elements in the upstream regions of the 20 genes. We found that members of the plant-specific SC35-Like (SCL) Arabidopsis SR protein subfamily are distinctively responsive to exogenous ABA, while the expression of seven SR and SR-related genes is affected by alterations in key components of the ABA pathway. Finally, despite pervasiveness of established ABA-responsive promoter elements in Arabidopsis SR and SR-like genes, their expression is likely governed by additional, yet unidentified cis-acting elements. Overall, this study pinpoints SR34, SR34b, SCL30a, SCL28, SCL33, RS40, SR45 and SR45a as promising candidates for involvement in ABA-mediated stress responses. PMID:25268622

SR-71 Pilot Stephen (Steve) D. Ishmael

Science.gov (United States)

1992-01-01

NASA research pilot Stephen D. Ishmael is pictured here in front of an SR-71 Blackbird on the ramp at the Dryden Flight Research Center, Edwards, California. Ishmael was one of two NASA research pilots assigned to the SR-71 high speed research program in the early 1990s at NASA's Dryden Flight Research Facility (redesignated the Dryden Flight Research Center in 1994), Edwards, California. Ishmael became a NASA research pilot in 1977. Data from the SR-71 program will be used to aid designers of future supersonic aircraft and propulsion systems. Two SR-71 aircraft have been used by NASA as testbeds for high-speed and high-altitude aeronautical research. The aircraft, an SR-71A and an SR-71B pilot trainer aircraft, have been based here at NASA's Dryden Flight Research Center, Edwards, California. They were transferred to NASA after the U.S. Air Force program was cancelled. As research platforms, the aircraft can cruise at Mach 3 for more than one hour. For thermal experiments, this can produce heat soak temperatures of over 600 degrees Fahrenheit (F). This operating environment makes these aircraft excellent platforms to carry out research and experiments in a variety of areas -- aerodynamics, propulsion, structures, thermal protection materials, high-speed and high-temperature instrumentation, atmospheric studies, and sonic boom characterization. The SR-71 was used in a program to study ways of reducing sonic booms or over pressures that are heard on the ground, much like sharp thunderclaps, when an aircraft exceeds the speed of sound. Data from this Sonic Boom Mitigation Study could eventually lead to aircraft designs that would reduce the 'peak' overpressures of sonic booms and minimize the startling affect they produce on the ground. One of the first major experiments to be flown in the NASA SR-71 program was a laser air data collection system. It used laser light instead of air pressure to produce airspeed and attitude reference data, such as angle of attack and

Strontium isotope systematics of scheelite and apatite from the Felbertal tungsten deposit, Austria - results of in-situ LA-MC-ICP-MS analysis

Science.gov (United States)

Kozlik, Michael; Gerdes, Axel; Raith, Johann G.

2016-02-01

The in-situ Sr isotopic systematics of scheelite and apatite from the Felbertal W deposit and a few regional Variscan orthogneisses ("Zentralgneise") have been determined by LA-MC-ICP-MS. The 87Sr/86Sr ratios of scheelite and apatite from the deposit are highly radiogenic and remarkably scattering. In the early magmatic-hydrothermal scheelite generations (Scheelite 1 and 2) the 87Sr/86Sr ratios range from 0.72078 to 0.76417 and from 0.70724 to 0.76832, respectively. Metamorphic Scheelite 3, formed by recrystallisation and local mobilisation of older scheelite, is characterised by even higher 87Sr/86Sr values between 0.74331 and 0.80689. Statistics allows discriminating the three scheelite generations although there is considerable overlap between Scheelite 1 and 2; they could be mixtures of the same isotopic reservoirs. The heterogeneous and scattering 87Sr/86Sr ratios of the two primary scheelite generations suggest modification of the Sr isotope system due to fluid-rock interaction and isotopic disequilibrium. Incongruent release of 87Sr from micas in the Early Palaeozoic host rocks of the Habach Complex contributed to the solute budget of the hydrothermal fluids and may explain the radiogenic Sr isotope signature of scheelite. Spatially resolved analyses revealed isotopic disequilibrium even on a sub-mm scale within zoned Scheelite 2 crystals indicating scheelite growth in an isotopic dynamical hydrothermal system. Zoned apatite from the W mineralised Early Carboniferous K1-K3 orthogneiss in the western ore field yielded 87Sr/86Sr of 0.72044-0.74514 for the cores and 0.74535-0.77937 for the rims. Values of magmatic apatite cores from the K1-K3 orthogneiss are comparable to those of primary Scheelite 1; they are too radiogenic to be magmatic. The Sr isotopic composition of apatite cores was therefore equally modified during the hydrothermal mineralisation processes, therefore supporting the single-stage genetic model in which W mineralisation is associated with

(Ba+Sr)/Ti ratio dependence of the dielectric properties for (Ba0.5Sr0.5)TiO3 thin films prepared by ion beam sputtering

Science.gov (United States)

Yamamichi, Shintaro; Yabuta, Hisato; Sakuma, Toshiyuki; Miyasaka, Yoichi

1994-03-01

(Ba0.5Sr0.5)TiO3 thin films were prepared by ion beam sputtering from powder targets with (Ba+Sr)/Ti ratios ranging from 0.80 to 1.50. All of the perovskite (Ba,Sr)TiO3 films were single phase except for the film with a (Ba+Sr)/Ti ratio of 1.41. The dielectric constant values notably depended on the (Ba+Sr)/Ti ratio for films thicker than 70 nm. The highest dielectric constant of 580 was achieved for the 5% (Ba+Sr) rich film. This (Ba+Sr)/Ti ratio dependence was diminished by the thickness dependence for thinner films. The grain sizes for the 9% (Ba+Sr) rich film and for the 6% (Ba+Sr) poor film ranged from 70 to 100 nm and from 30 to 60 nm, respectively. This grain size difference could explain why slightly A-site rich (Ba,Sr)TiO3 films have a larger dielectric constant than A-site poor films.

Barren Miocene granitoids in the Central Andean metallogenic belt, Chile: Geochemistry and Nd-Hf and U-Pb isotope systematics Granitoides estériles del Mioceno en la franja metalogénica de los Andes Centrales, Chile: geoquímica e isotopía de Nd-Hf y U-Pb

Directory of Open Access Journals (Sweden)

Katja Deckart

2010-01-01

Full Text Available Four Middle-to-Late Miocene barren plutonic complexes that occur between the giant porphyry copper deposits of the central Chilean Andes were selected for U-Pb LA-ICPMS geochronology and Hf-isotope systematics on single zircon grains. Major and trace elements and Sr-Nd-Hf isotope whole rock geochemical studies were under-taken to compare with slightly younger or coeval barren and fertile intrusive rocks between 32° and 34°S. The studied granitoids yield resolvable crystallization ages of 11.3±0.1 Ma (Cerro Mesón Alto massif, 10.3±0.2 Ma (La Gloria pluton, 14.9±0.2 Ma/14.9±0.1 Ma (Yerba Loca stock and 11.2±0.1 Ma/14.7±0.1 Ma (San Francisco Batholith. Major and trace elements discard an adakitic signature as suggested for coeval porphyric intrusions at 32°S, slightly younger mineralized porphyries at Río Blanco-Los Bronces deposit and other Cenozoic adakites. Volcanic host rocks are less fractionated than the intrusive rock units. The same observation can be made for the unmineralized northern plutons compared to the southern ones. Initial Sr-Nd isotope data show insignificant variation (0.703761-0.704118 and 0.512758-0.512882, plotting in the mantle array. Trace element enrichment can be explained by addition of subducted-slab fluids and/or terrigenous sediments to the mantle wedge prior to and/or slight crustal input during magma ascent. Zircon grains separated from these barren intrusives share a similar initial εHf i-data variation for the younger age group (10-12 Ma; 7.04-9.54 and show a more scattered range for the older one (14-15 Ma; 8.50-15.34; both sets plot between the DM and CLTUR evolution lines. There is evidence that magma evolution was slightly distinct through time from older to younger barren magmatism, compared to a few fertile porphyritic rocks from Río Blanco-Los Bronces porphyry copper deposit. It is suggested that chronological inconsistencies within these complexes might be related to differential shortening

Sr and Nd isotope systematics in fish teeth

International Nuclear Information System (INIS)

Staudigel, H.; Zindler, A.

1985-01-01

High concentrations of Sr and Nd in fish teeth apatite (up to 2000 and 3800 ppm, respectively) make them relatively impervious to diagenetic overprints and allow high-precision analysis of 87 Sr/ 86 Sr and 143 Nd/ 144 Nd of very small amounts of material. 87 Sr/ 86 Sr ratios of 14 Cenozoic samples ( 87 Sr/ 86 Sr stratigraphic dating. A compilation of published 143 Nd/ 144 Nd data from recent Mn-nodules and marine Fe/Mn deposits shows that the North-Central Pacific Ocean and the major portion of the Atlantic Ocean display distinctly different, narrow ranges in isotopic compositions. Between these two areas, the 143 Nd/ 144 Nd of Mn-nodules vary systematically towards intermediate compositions in the Southern Oceans, reflecting the communication between the Atlantic and Pacific Oceans through the eastward moving Antarctic Circumpolar Current. The 143 Nd/ 144 Nd of the 2-55 Ma old fish teeth analyzed are typically close to the range of 143 Nd/ 144 Nd in Recent Mn-nodules and seawater for the respective ocean and, thus, indicate no significant change through this time period. The 143 Nd/ 144 Nd of fish teeth from the North Pacific Ocean are highest during periods of high aeolian sedimentation. (orig.)

SR-XRD in situ monitoring of copper-IUD corrosion in simulated uterine fluid using a portable spectroelectrochemical cell.

Science.gov (United States)

Grayburn, Rosie A; Dowsett, Mark G; Sabbe, Pieter-Jan; Wermeille, Didier; Anjos, Jorge Alves; Flexer, Victoria; De Keersmaecker, Michel; Wildermeersch, Dirk; Adriaens, Annemie

2016-08-01

The objective of this work is to study the initial corrosion of copper in the presence of gold when placed in simulated uterine fluid in order to better understand the evolution of active components of copper-IUDs. In order to carry out this study, a portable cell was designed to partially simulate the uterine environment and provide a way of tracking the chemical changes occurring in the samples in situ within a controlled environment over a long period of time using synchrotron spectroelectrochemistry. The dynamically forming crystalline corrosion products are determined in situ for a range of copper-gold surface ratios over the course of a 10-day experiment in the cell. It is concluded that the insoluble deposits forming over this time are not the origin of the anticonception mechanism. Copyright © 2016 Elsevier B.V. All rights reserved.

Dynamical observation of lithium insertion/extraction reaction during charge-discharge processes in Li-ion batteries by in situ spatially resolved electron energy-loss spectroscopy.

Science.gov (United States)

Shimoyamada, Atsushi; Yamamoto, Kazuo; Yoshida, Ryuji; Kato, Takehisa; Iriyama, Yasutoshi; Hirayama, Tsukasa

2015-12-01

All-solid-state Li-ion batteries (LIBs) with solid electrolytes are expected to be the next generation devices to overcome serious issues facing conventional LIBs with liquid electrolytes. However, the large Li-ion transfer resistance at the electrode/solid-electrolyte interfaces causes low power density and prevents practical use. In-situ-formed negative electrodes prepared by decomposing the solid electrolyte Li(1+x+3z)Alx(Ti,Ge)(2-x)Si(3z)P(3-z)O12 (LASGTP) with an excess Li-ion insertion reaction are effective electrodes providing low Li-ion transfer resistance at the interfaces. Prior to our work, however, it had still been unclear how the negative electrodes were formed in the parent solid electrolytes. Here, we succeeded in dynamically visualizing the formation by in situ spatially resolved electron energy-loss spectroscopy in a transmission electron microscope mode (SR-TEM-EELS). The Li-ions were gradually inserted into the solid electrolyte region around 400 nm from the negative current-collector/solid-electrolyte interface in the charge process. Some of the ions were then extracted in the discharge process, and the rest were diffused such that the distribution was almost flat, resulting in the negative electrodes. The redox reaction of Ti(4+)/Ti(3+) in the solid electrolyte was also observed in situ during the Li insertion/extraction processes. The in situ SR-TEM-EELS revealed the mechanism of the electrochemical reaction in solid-state batteries. © The Author 2015. Published by Oxford University Press on behalf of The Japanese Society of Microscopy. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

A flexible gas flow reaction cell for in situ x-ray absorption spectroscopy studies

Energy Technology Data Exchange (ETDEWEB)

Kroner, Anna B., E-mail: anna.kroner@diamond.ac.uk; Gilbert, Martin; Duller, Graham; Cahill, Leo; Leicester, Peter; Woolliscroft, Richard; Shotton, Elizabeth J. [Diamond Light Source Ltd., Diamond House, Harwell Science and Innovation Campus, Chilton, Oxfordshire, OX110DE (United Kingdom); Mohammed, Khaled M. H. [UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Chilton, Oxfordshire, OX110FA (United Kingdom); School of Chemistry, University of Southampton, Southampton, SO17 1BJ (United Kingdom)

2016-07-27

A capillary-based sample environment with hot air blower and integrated gas system was developed at Diamond to conduct X-ray absorption spectroscopy (XAS) studies of materials under time-resolved, in situ conditions. The use of a hot air blower, operating in the temperature range of 298-1173 K, allows introduction of other techniques e.g. X-ray diffraction (XRD), Raman spectroscopy for combined techniques studies. The flexibility to use either quartz or Kapton capillaries allows users to perform XAS measurement at energies as low as 5600 eV. To demonstrate performance, time-resolved, in situ XAS results of Rh catalysts during the process of activation (Rh K-edge, Ce L{sub 3}-edge and Cr K-edge) and the study of mixed oxide membrane (La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3−δ}) under various partial oxygen pressure conditions are described.

Tracing sediment sources in upstream agricultural catchments: contribution of elemental geochemistry, 87Sr/86Sr ratio and radionuclides measurements

International Nuclear Information System (INIS)

Le-Gall, Marion

2016-01-01

Soil erosion is recognized as one of the main processes of land degradation in agricultural environments. This study develops an original fingerprinting method to examine sediment source contributions in two contrasted agricultural catchments. Several properties were used to trace sediment lithological sources ( 87 Sr/ 86 Sr ratios, elemental concentrations), soil surface and subsurface sources ( 137 Cs) and to quantify their temporal dynamics ( 7 Be, 210 Pb xs ). In the Louroux catchment (24 km 2 , France), representative of drained areas of Northwestern Europe, results showed the dominant contribution of very fine particles (≤2 μm) transiting through the tile drainage system to suspended sediment. Sediment accumulated in the river channel was mainly exported during the two first floods investigated in 2013 whereas the next event was characterized by the transport of sediment eroded from the cultivated soil surface. Mixing models were used, and results indicated that surface sources contributed the majority of sediment deposited in the pond, at the outlet of the catchment. The two lithological sources, discriminated using 87 Sr/ 86 Sr ratios, contributed in similar proportions to downstream pond sediment. In contrast, significant variations were observed since the 1950's. These changes may be related to the progressive implementation of land consolidation schemes within the catchment. Results obtained in the Louroux catchment revealed the potential of 87 Sr/ 86 Sr ratios to trace sediment lithological sources. The methodology was then applied to the larger and steeper Guapore catchment (2000 km 2 , Brazil), exposed to a more erosive climate and characterized by contrasted laterite soils. 87 Sr/ 86 Sr ratios and elements that discriminated the five soil types found in the catchment were incorporated in mixing models. Results showed that the major part of sediment was supplied by soils located in lower catchment parts. This result suggests the higher

Test plan for in situ bioremediation demonstration of the Savannah River Integrated Demonstration Project DOE/OTD TTP No.: SR 0566-01. Revision 3

Energy Technology Data Exchange (ETDEWEB)

Hazen, T.C.

1991-09-18

This project is designed to demonstrate in situ bioremediation of groundwater and sediment contaminated with chlorinated solvents. Indigenous microorganisms will be simulated to degrade trichloroethylene (TCE), tetrachloroethylene (PCE) and their daughter products in situ by addition of nutrients to the contaminated zone. in situ biodegradation is a highly attractive technology for remediation because contaminants are destroyed, not simply moved to another location or immobilized, thus decreasing costs, risks, and time, while increasing efficiency and public and regulatory acceptability. Bioremediation has been found to be among the least costly technologies in applications where it will work.

Kinetics of distribution of 90Sr in Beijing-white layers

International Nuclear Information System (INIS)

Shang Zhaorong; Xu Shiming; Zhao Wenhu; Hou Lanxin

1993-08-01

The experiment feeding 90 Sr(NO 3 ) 2 in the range of 1.85 x 10 2 to 1.85 x 10 5 Bq/chicken was carried out with 45 Beijing-white layers to observe the regular pattern of absorption and distribution of 90 Sr in organs and tissues. The results are summarized as follows: the uptake rate of 90 Sr by layer through oral feeding is very low. Most part of 90 Sr drains away from body with daily excreta and egg. The accumulation of 90 Sr in the body is low and about 70% is in the bone. About 99% of 90 Sr in egg is concentrated in the eggshell. The order of absorptivity of 90 Sr in tissues is bone>feather>muscle>blood>viscera. The absorption coefficient of 90 Sr in organs and tissues in different stages with different feeding volumes has been calculated

The accumulation and elimination of 89Sr in tea leaves

International Nuclear Information System (INIS)

Zhang Yongxi; Wang Shouxiang; Chen Chuanqun; Sun Zhiming; Hu Bingmin; Huang Dan

1995-01-01

The 89 Sr was added to the tea tree-soil system by different ways. The 89 Sr in the system through the over-ground part of tea tree, was much more than that through soil. The 89 Sr concentration in older leaves was higher than in shoot for a definite treatment. The accumulation elimination law of 89 Sr in leaves varied with the treatments. For the treatment through the over-ground part, the 89 Sr concentration in older leaves and shoot was monotonously decreased with time increasing. But for the treatment through soil the 89 Sr concentration in shoot was increased to reach a peak value, and then decreased slowly; while the 89 Sr concentration in older leaves increased quickly in a period, then increased slowly to attain a saturated value. In addition, the concentration factor of 89 Sr in older leaves and shoot were determined

Provenance and depositional age of metavolcano-sedimentary sequences of the Santa Terezinha de Goias, based on Sm-Nd and U-Pb zircon single grain; Proveniencia e idade deposicional de sequencias metavulcano-sedimentares da regiao de Santa Terezinha de Goias, baseada em dados isotopicos Sm-Nd e U-Pb em monocristal de zircao

Energy Technology Data Exchange (ETDEWEB)

Dantas, Ellton Luiz; Jost, Hardy; Fuck, Reinhardt A.; Brod, Jose Afonso; Pimentel, Marcio Martins; Meneses, Paulo Roberto [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail: elton@unb.br

2001-09-01

Supracrustal rocks of the Santa Terezinha de Goias region, Central Brazil, presumably represent a southern extension of the Mara Rosa magmatic arc tectonically juxtaposed to Archean terrains and consist of a meta volcanic unit and a meta sedimentary unit. The aim of the paper is to present and discuss the first U-Pb and Sm-Nd data of rocks belonging to both units of that region. U-Pb data of zircons from a felsic meta volcanic rock inter layered with chlorite-rich schists (metandesites?) yield a concordant age of of 660 My, while the Sm-Nd model age of a variety of chlorite-schists indicate a juvenile age between 1.1 and 1.3 Ga. These data indicate that the meta volcanic rocks are Neo proterozoic in age and may be correlated with rocks of the Mara Rosa magmatic arc. On the other hand, the prevailing provenance of rocks belonging to the meta sedimentary unit indicate a Paleoproterozoic, or older, source. Thus, the deposition of both units are explained by means of the erosion of source-areas of variable age. (author)

Interim FEP report for the safety assessment SR-Can

Energy Technology Data Exchange (ETDEWEB)

Skagius, Kristina (ed.) [Kemakta Konsult AB, Stockholm (Sweden)

2004-08-01

This report describes the work with identification and structuring of features, events and processes (FEPs) that has been carried out within the scope of the SR-Can safety assessment up to the time of the interim reporting of the project. The overall objective of the work is to develop a database of features, events and processes in a format that would facilitate both a systematic analysis of FEPs and documentation of the FEP analysis as well as facilitate revisions and updates to be made in connection with new safety assessments. This overall objective also includes the development of procedures for a systematic FEP analysis as well as to apply these procedures in order to arrive at an SR-Can version of the FEP database. The work started by implementing the content of the SR 97 Process report into a database format suitable for import and processing of FEP information from other sources. The SR 97 version of the database was systematically audited against the NEA database with Project FEPs, version 1.2. In addition, an earlier audit of the SR 97 process report against the interaction matrices developed for a deep repository of the KBS-3 type was revisited and updated. Relevant FEPs from the audit were sorted into three main categories in the SR-Can database i) FEPs related to the initial states of the repository system, ii) FEPs related to internal processes of the repository system, and iii) FEPs related to external impacts on the repository system. These groups of FEPs were further processed for making decisions on how to handle these FEPs in the assessment. Biosphere processes were not included in the SR 97 Process report and there is thus not the same basis for updating these descriptions as for the engineered barriers and the geosphere. All biosphere FEPs from the audit have therefore been compiled in a single category in the database, but remain to be further handled. FEPs were also categorised as irrelevant or as being related to methodology on a general

Interim FEP report for the safety assessment SR-Can

International Nuclear Information System (INIS)

Skagius, Kristina

2004-08-01

This report describes the work with identification and structuring of features, events and processes (FEPs) that has been carried out within the scope of the SR-Can safety assessment up to the time of the interim reporting of the project. The overall objective of the work is to develop a database of features, events and processes in a format that would facilitate both a systematic analysis of FEPs and documentation of the FEP analysis as well as facilitate revisions and updates to be made in connection with new safety assessments. This overall objective also includes the development of procedures for a systematic FEP analysis as well as to apply these procedures in order to arrive at an SR-Can version of the FEP database. The work started by implementing the content of the SR 97 Process report into a database format suitable for import and processing of FEP information from other sources. The SR 97 version of the database was systematically audited against the NEA database with Project FEPs, version 1.2. In addition, an earlier audit of the SR 97 process report against the interaction matrices developed for a deep repository of the KBS-3 type was revisited and updated. Relevant FEPs from the audit were sorted into three main categories in the SR-Can database i) FEPs related to the initial states of the repository system, ii) FEPs related to internal processes of the repository system, and iii) FEPs related to external impacts on the repository system. These groups of FEPs were further processed for making decisions on how to handle these FEPs in the assessment. Biosphere processes were not included in the SR 97 Process report and there is thus not the same basis for updating these descriptions as for the engineered barriers and the geosphere. All biosphere FEPs from the audit have therefore been compiled in a single category in the database, but remain to be further handled. FEPs were also categorised as irrelevant or as being related to methodology on a general

Igneous Consequence Modeling for the TSPA-SR

International Nuclear Information System (INIS)

McCord, John

2001-01-01

The purpose of this technical report is to develop credible, defendable, substantiated models for the consequences of igneous activity for the TSPA-SR Model. The effort will build on the TSPA-VA and improve the quality of scenarios and depth of the technical basis underlying disruptive events modeling. Computational models for both volcanic eruptive releases (this is an event that results in ash containing waste being ejected from Yucca Mountain) and igneous intrusion groundwater releases (this is an event that reaches the repository level, impacts the waste packages, and produces releases from waste packages damaged by igneous activity) will be included directly in the TSPA calculations as part of the TSPA-SR Model. This Analysis Model Report (AMR) is limited to development of the conceptual models for these two scenarios. The mathematical implementation of these conceptual models will be done within the TSPA-SR Model. Thus, this AMR will not include any model results or sensitivity analyses. Calculation of any doses resulting from igneous releases will also be done within the TSPA-SR model, as will the probabilistic weighting of these doses. Calculation and analysis of the TSPA-SR Model results for igneous disruption are, therefore, outside the scope of this activity. The reason for not running the mathematical models as part of this AMR is that the models are integrated within the TSPA-SR model and, thus, any model simulations and the corresponding results are out of the scope of this AMR. The scope of this work as defined in the development plan (CRWMS M and O 2000j) involves using data that has been extracted from existing sources to design and support the TSPA-SR models for the transport of radionuclides following igneous disruption of the repository. The development plan states ''applications of the code in this analysis will be limited to testing of the code and sensitivity analyses during analysis design.'' In contrast to the development plan, the ASHPLUME

Separation of 90Sr from Purex high level waste and development of a 90Sr-90Y generator

International Nuclear Information System (INIS)

Ramanujam, A.; Dhami, P.S.; Chitnis, R.R.; Achuthan, P.V.; Kannan, R.; Gopalakrishnan, V.; Balu, K.

2000-04-01

90 Y (T 1/2 =64.2 h) finds several applications in nuclear medicine. It is formed from the decay of 90 Sr which has a long half-life of 28.8 years. 90 Sr can be used as a long-lasting source for the production of carrier-free 90 Y. 90 Sr itself is abundantly available in high level waste (HLW) of PUREX origin. The present studies deal with the separation of pure 90 Sr from HLW and the subsequent separation of 90 Y from 90 Sr. Actinides and some of the fission products like lanthanides, zirconium, molybdenum and cesium were first removed from the HLW using methods based on solvent extraction and ion-exchange studied earlier in our laboratory. The resulting waste solution was used as a feed for the present process. The separation of 90 Sr from HLW was based on radiochemical method which involved a repeated scavenging with ferric hydroxide followed by strontium carbonate precipitation. The separation of 90 Y from 90 Sr was achieved by membrane separation technique. A compact generator is developed for this separation using a commercially available polytetrafluoroethylene (PTFE) membrane, impregnated with indigenously synthesised 2-ethylhexyl 2-ethylhexyl phosphonic acid (KSM-17). Generator system overcomes the drawbacks associated with conventional solvent extraction and ion-exchange based generators. The product is in chloride form and is suitable for complexation studies. After gaining an operating experience of ∼3 years in generating carrier-free 90 Y at 2 mCi level for initial studies in radiotherapeutic applications, the process was scaled up for the production of about 12 mCi of 90 Y to be used for animal studies before its application to patients. Radiochemical and chemical purity of the product was critically assayed by radiometry, ICP-AES, etc. The process is amenable for further scaling up. (author)

FEP report for the safety assessment SR-Can

Energy Technology Data Exchange (ETDEWEB)

Skagius, Kristina [Kemakta Konsult AB, Stockholm (Sweden)

2006-11-15

This report documents the analysis and processing of features, events and processes, FEPs, that has been carried out within the safety assessment SR-Can, and forms an important part of the reporting of the project. The SR-Can project is a preparatory stage for the SR-Site assessment, and the report from that project will be used in support of SKB's application to build a final repository. The overall objective of the FEP analysis and processing included development of a database of features, events and processes, an SKB FEP database, in a format that facilitates both a systematic analysis of FEPs and documentation of that FEP analysis, as well as facilitating revisions and updates to be made in connection with new safety assessments. The overall objective also extended to the development of procedures for such a systematic FEP analysis as well as the application of those procedures in order to establish an SR-Can FEP catalogue within the framework of the SKB FEP database. The work started by implementing the content of the SR 97 Process Report into a database format suitable for import and processing of FEP information from other sources. The SR 97 version of the database was systematically audited against the NEA database with Project FEPs, version 1.2. In addition, an earlier audit of the SR 97 process report against the interaction matrices developed for a deep repository of the KBS-3 type was revisited and updated. Relevant FEPs identified through the audit process were sorted into three main categories i) FEPs related to the initial states of the repository system, ii) FEPs related to internal processes of the repository system, and iii) FEPs related to external impacts on the repository system. This resulted in additions to the SR 97 list of processes and to the lists of initial state FEPs and external factors to be addressed in further processing. The further processing of the initial state FEPs revealed that those FEPs that are not covered by the

Comparative study of potentially J{sub eff} = 0 ground state iridium(V) in SrLaNiIrO{sub 6}, SrLaMgIrO{sub 6}, and SrLaZnIrO{sub 6}

Energy Technology Data Exchange (ETDEWEB)

Wolff, Klaus K.; Agrestini, Stefano; Tjeng, Liu Hao [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Tanaka, Arata [Department of Quantum Matter, AdSM, Hiroshima University, Higashi-Hiroshima (Japan); Jansen, Martin [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Max Planck Institute for Solid State Research, Stuttgart (Germany)

2017-12-13

A series of polycrystalline double perovskites SrLaBIrO{sub 6} (B = Ni, Mg, Zn) containing Ir{sup 5+} (5d{sup 4}) was synthesized by solid state reactions, and structural, magnetic and electronic properties were investigated. The isotypic fully ordered double perovskites crystallize in space group P2{sub 1}/n and show semiconducting behavior with estimated bandgaps of approximately 0.2 eV for SrLaNiIrO{sub 6} and SrLaZnIrO{sub 6}, and 0.4 eV for SrLaMgIrO{sub 6}. SrLaNiIrO{sub 6} is an antiferromagnet with a Neel temperature of 74 K (μ{sub eff} = 3.3 μ{sub B}, θ{sub W} = -90 K), whereas SrLaMgIrO{sub 6} and SrLaZnIrO{sub 6} are weakly paramagnetic. All title compounds exhibit a temperature-independent contribution to the measured magnetic susceptibility, which supports the notion for a van-Vleck-type response originating from the Ir{sup 5+} (5d{sup 4}, J{sub eff} = 0) ions. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

System of Sr(NO sub 2 ) sub 2 -Sr(OH) sub 2 -H sub 2 O at 25 deg C. Sistema Sr(NO sub 2 ) sub 2 -H sub 2 O pri 25 grad C

Energy Technology Data Exchange (ETDEWEB)

Popova, T B; Berdyukova, V A; Khutsistova, F M [Kalmytskij Gosudarstvennyj Univ., Ehlista (USSR) Rostovskij-na-Donu Gosudarstvennyj Univ., Rostov-na-Donu (USSR)

1990-02-01

Sr(NO{sub 2}){sub 2}-Sr(OH){sub 2}-H{sub 2}O system was investigated by the methods of solubility, density, viscosity, electric conductivity and refractometry. It was established that its compoments form the compound 4Sr(NO{sub 2}){sub 2}xSr(OH){sub 2}x8H{sub 2}O. The compound was separated from solution; its density, decomposition temperature were determined; IR spectra and X-ray patterns of prepared and initial compounds were obtained.

Interim Report: 100-NR-2 Apatite Treatability Test: Low Concentration Calcium Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization

Energy Technology Data Exchange (ETDEWEB)

Williams, Mark D.; Fritz, Brad G.; Mendoza, Donaldo P.; Rockhold, Mark L.; Thorne, Paul D.; Xie, YuLong; Bjornstad, Bruce N.; Mackley, Rob D.; Newcomer, Darrell R.; Szecsody, James E.; Vermeul, Vincent R.

2008-07-11

Following an evaluation of potential Sr-90 treatment technologies and their applicability under 100-NR-2 hydrogeologic conditions, U.S. Department of Energy, Fluor Hanford, Inc., Pacific Northwest National Laboratory, and the Washington Department of Ecology agreed that the long-term strategy for groundwater remediation at 100-N Area will include apatite sequestration as the primary treatment, followed by a secondary treatment if necessary (most likely phytoremediation). Since then, the agencies have worked together to agree on which apatite sequestration technology has the greatest chance of reducing Sr-90 flux to the river at a reasonable cost. In July 2005, aqueous injection, (i.e., the introduction of apatite-forming chemicals into the subsurface) was endorsed as the interim remedy and selected for field testing. Studies are in progress to assess the efficacy of in situ apatite formation by aqueous solution injection to address both the vadose zone and the shallow aquifer along the 300 ft of shoreline where Sr-90 concentrations are highest. This report describes the field testing of the shallow aquifer treatment.

ELNES study of chemical solution deposited SrO(SrTiO3)n Ruddlesden-Popper films: Experiment and simulation

International Nuclear Information System (INIS)

Riedl, T.; Gemming, T.; Weissbach, T.; Seifert, G.; Gutmann, E.; Zschornak, M.; Meyer, D.C.; Gemming, S.

2009-01-01

This article analyzes electron energy-loss near-edge fine structures of the SrO(SrTiO 3 ) n=1 Ruddlesden-Popper system and of the parent compounds SrTiO 3 and SrO by comparison with first principles calculations. For that, the fine structures of chemical solution deposited Ruddlesden-Popper films have been experimentally recorded by means of transmission electron microscopy. Moreover, density of states computations using an all-electron density-functional code have been performed. It is shown that the appearance and shape of the experimental O-K and Ti-L 2,3 fine structure features result from the crystallography-dependent electronic structure of the investigated oxides, which display technologically interesting dielectric as well as lattice-structural properties.

In situ ToF-SIMS monitoring of SOFC cathodes - A case study of La0.74Sr0.17Mn1.01O2.9 model electrodes

Science.gov (United States)

Rohnke, M.; Schaepe, K.; Bachmann, A.-K.; Laenger, M.; Janek, J.

2017-11-01

The modelling of electrode kinetics of solid oxide fuel cells is challenging, as the electrodes can change their composition and microstructure during operation at high temperature. Here we present results from in situ studies, applying time of flight secondary ion mass spectrometry (ToF-SIMS) to investigate compositional surface changes of lanthanum strontium manganate (LSM) model electrodes. Geometrically well-defined LSM electrodes with the composition La0.74Sr0.17Mn1.01O2.9 were deposited as thin films on yttria stabilised zirconia (YSZ) single crystals by pulsed laser deposition. As counter electrode, a porous platinum electrode was applied on the backside of the solid electrolyte. The electrochemical polarisation experiments were carried out inside the ToF-SIMS analysis chamber at 430 °C, and the ToF-SIMS measurements were performed - in contrast to former work - for the first time during electrical polarisation at elevated temperatures. By applying either a cathodic or anodic potential to the LSM cathode, enrichment or depletion of the different metallic constituents on both, the LSM and free YSZ surface, and within the LSM near surface region, were observed. After polarisation, the system relaxes towards the thermodynamic equilibrium state. Already after the first heat treatment, diffusion of manganese and strontium from the LSM electrode onto the free YSZ surface is observed. The concomitant spreading of the three-phase boundary seems to be one reason for electrode activation after polarisation.

Development of 90Sr-90Y generators

International Nuclear Information System (INIS)

Barrio, Graciela

2007-01-01

Yttrium-90 is a radioisotope of great interest in the field of Nuclear Medicine. It is considered one of the most important and most used radionuclides for radioimmunotherapeutical applications, especially promising for the treatment of certain types of cancer. Another important application of 90 Y is radio synovectomy. This radionuclide has a half-life of 64 hours, emits long range beta particles (maximum energy of 2.3 MeV) and decays, without intermediate nuclides, to a stable daughter. 90 Y may be obtained carrier-free, generated by the decay of its parent 90 Sr (half-life=28 years). 90 Sr is a product from uranium fission, and due to its long half-life, can be indefinitely used, which is certainly advantageous. It is present in great amounts, and needs to be processed and purified in order to be used as raw material for the generators. Generators of 90 Sr- 90 Y may thus be used during various months, due to 90 Sr long half-life. Several methods for the separation of 90 Y from 90 Sr by solvent extraction and ion exchange have been reported in literature. Thanks to its simplicity, ion exchange techniques have been more commonly used for this generator system. The main objective of this work was to develop a methodology for the preparation of 90 Sr- 90 Y generators, using cationic exchange resins. In such method, 90 Sr is strongly adsorbed in the resin and 90 Y is eluted by a 0.003 M EDTA solution. According to the quality control carried out, results showed that elution yields are greater than 65%, thus confirming the efficiency of the separation method used.

U-Pb zircon geochronology and evolution of some Adirondack meta-igneous rocks

Science.gov (United States)

Mclelland, J. M.

1988-01-01

An update was presented of the recent U-Pb isotope geochronology and models for evolution of some of the meta-igneous rocks of the Adirondacks, New York. Uranium-lead zircon data from charnockites and mangerites and on baddeleyite from anorthosite suggest that the emplacement of these rocks into a stable crust took place in the range 1160 to 1130 Ma. Granulite facies metamorphism was approximately 1050 Ma as indicated by metamorphic zircon and sphene ages of the anorthosite and by development of magmatitic alaskitic gneiss. The concentric isotherms that are observed in this area are due to later doming. However, an older contact metamorphic aureole associated with anorthosite intrusion is observed where wollastonite develops in metacarbonates. Zenoliths found in the anorthosite indicate a metamorphic event prior to anorthosite emplacement. The most probable mechanism for anorthosite genesis is thought to be ponding of gabbroic magmas at the Moho. The emplacement of the anorogenic anorthosite-mangerite-charnockite suite was apparently bracketed by compressional orogenies.

Possible two-stage 87Sr evolution in the Stockdale Rhyolite

International Nuclear Information System (INIS)

Compston, W.; McDougall, I.; Wyborn, D.

1982-01-01

The Rb-Sr total-rock data for the Stockdale Rhyolite, of significance for the Palaeozoic time scale, are more scattered about a single-stage isochron than expected from experimental error. Two-stage 87 Sr evolution for several of the samples is explored to explain this, as an alternative to variation in the initial 87 Sr/ 86 Sr which is customarily used in single-stage dating models. The deletion of certain samples having very high Rb/Sr removes most of the excess scatter and leads to an estimate of 430 +- 7 m.y. for the age of extrusion. There is a younger alignment of Rb-Sr data within each sampling site at 412 +- 7 m.y. We suggest that the Stockdale Rhyolite is at least 430 m.y. old, that its original range in Rb/Sr was smaller than now observed, and that it experienced a net loss in Sr during later hydrothermal alteration at ca. 412 m.y. (orig.)

Determination of the electrostatic potential distribution in Pt/Fe:SrTiO3/Nb:SrTiO3 thin-film structures by electron holography

Science.gov (United States)

Marchewka, Astrid; Cooper, David; Lenser, Christian; Menzel, Stephan; Du, Hongchu; Dittmann, Regina; Dunin-Borkowski, Rafal E.; Waser, Rainer

2014-11-01

We determined the electrostatic potential distribution in pristine Pt/Fe:SrTiO3/Nb:SrTiO3 structures by electron holography experiments, revealing the existence of a depletion layer extending into the Nb-doped bottom electrode. Simulations of potential profiles in metal-insulator-metal structures were conducted assuming different types and distributions of dopants. It is found that the presence of acceptor-type dopant concentrations at the Fe:SrTiO3/Nb:SrTiO3 interface with a donor-doped insulating layer provides a good match to the measured profile. Such acceptor-type interface concentrations may be associated with Sr vacancies on the Nb:SrTiO3 side of the bottom interface.

Reassessment of the geologic evolution of selected precambrian terranes in Brazil, based on SHRIMP U-Pb data, part 2: mineiro and Aracuai orogens and Southern Sao Francisco craton; Reavaliacao da evolucao geologica em terrenos pre-cambrianos brasileiros com base em novos dados U-Pb SHRIMP, parte 2: orogeno Aracuai, cinturao mineiro e craton Sao Francisco Meridional

Energy Technology Data Exchange (ETDEWEB)

Silva, Luiz Carlos da; Pimentel, Marcio [Brasilia Univ., DF (Brazil). Inst. de Geociencias]. E-mail: luizcarlos@aneel.gov.br; Leite, Carlos Augusto; Vieira, Valter Salino; Silva, Marcio Antonio da; Paes, Vinicius Jose de Castro; Cardoso Filho, Joao Moraes [Companhia de Pesquisas de Recursos Minerais (CPRM), Belo Horizonte, MG (Brazil); Armstrong, Richard [Australian National Univ., Canberra (Australia). Research School of Earth Sciences; Noce, Carlos Mauricio; Pedrosa-Soares, Antonio Carlos [Minas Gerais Univ., Belo Horizonte (Brazil). Inst. de Geociencias. Centro de Pesquisa Manuel Teixeira da Costa; Carneiro, Mauricio Antonio [Ouro Preto Univ., MG (Brazil). Dept. de Geologia

2002-12-15

This paper discusses new zircon SHRIMP (Sensitive High Resolution Ion Microprobe) U-Pb geochronological data for 19 key-exposures of several geological units exposed at the eastern border of the Southern Sao Francisco Craton and at the adjacent Proterozoic Mineiro and Aracuai orogens. Samples were collected along several E-W tran sects, aiming at tracing the precise limit of the Sao Francisco Craton Archean basement, as well as assessing the extension of the successive proterozoic orogenic collages. Due to the complex geologic history and/or high grade metamorphism which most of the rock units investigated have undergone, zircon morphology and the U-Pb analytical data exhibit very complex patterns. These are characterized by a combination of inheritance, partial resetting and new zircon growth during high-grade metamorphism. As a consequence, very careful and detailed analyses of cathodoluminescence imagery were required to allow distinction between inheritance, newly melt-precipitated zircon and partially reset zircons, as well as between the ages of magmatic and metamorphic events. In the southeastern border of the craton 5 units yielded Archean crystallization ages ranging from ca. 3000-2700 Ma, with poorly constrained metamorphic ages ranging from ca. 2850 to 550 Ma. The TTG gneissic complex exposed to the east and south of the Quadrilatero Ferrifero, formerly ascribed to the Archean basement, have crystallization ages from ca. 2210 Ma to 2050 Ma, and can now be interpreted as representing pre- to syn-collisional magmatic phases of the Mineiro Belt. Metamorphic ages of ca. 2100 Ma and 560 Ma are also well constrained in zircon populations from these gneisses. The crystallization age of ca 1740 Ma observed for an alkaline granite of the Borrachudos Suite (intrusive into the Archean basement east of the Southern Espinhaco Range) confirmed previous conventional U-Pb data for this Paleoproterozoic rift-related magmatism. One of the major basement inliers within the

Assessing Covariation of Holocene Monsoon Intensity and Local Moisture Conditions in Eastern and Southwestern Amazon Basin Using Speleothem δ18O and 87Sr/86Sr Values

Science.gov (United States)

Ward, B. M.; Wong, C. I.; Novello, V. F.; Silva, L.; McGee, D.; Cheng, H.; Wang, X.; Edwards, R. L.; Cruz, F. W., Sr.; Santos, R. V.

2017-12-01

δ18O records from South America offer insight into past variability of the South American Monsoon System (SAMS). Potential, however, for understanding local moisture conditions is limited as precipitation δ18O is strongly influenced by regional climate dynamics. Here we create Holocene speleothem 87Sr/86Sr records at 200-yr resolution using TIMS methods in the Center for Isotope Geochemistry at Boston College to complement existing Holocene δ18O speleothem records and investigate local moisture conditions above caves located in the eastern Amazon Basin (PAR - 4°S, 55°W) and southwestern Brazil (JAR - 21°S, 56°W). Speleothem 87Sr/86Sr variability is interpreted to reflect differences in the extent of water-rock interaction due to differences in infiltration rates under wet and dry conditions. Drier conditions promote longer residence time, enhanced water-rock interaction, and greater evolution of dripwater 87Sr/86Sr values from an initial isotopic signature acquired from the soil to the signature of the cave host rock. PAR speleothem 87Sr/86Sr values range from 0.71024 to 0.71067 and are bracketed by soil (0.71710 to 0.70956) and bedrock (0.70852 to 0.70899) values. JAR speleothem 87Sr/86Sr values range from 0.71216 to 0.71539 and are greater than bedrock values (0.70825 to 0.71219), although some speleothem values exceed the single analysis conducted of the soil isotopic composition (0.71473). JAR speleothem 87Sr/86Sr values increase from the early to mid Holocene, consistent with increase in local moisture availability associated with intensification of the SAMS suggested by decreasing δ18O values in many records from the region. Speleothem 87Sr/86Sr values at JAR decrease from the mid to late Holocene, consistent with an increase in δ18O values at PAR that suggest a decline in monsoon intensity. 87Sr/86Sr variability at JAR, however, is positively correlated with the δ18O record. Preliminary 87Sr/86Sr results from PAR are only broadly consistent with

Low-temperature electron microscopy and electron diffraction study of La/sub 1. 84/Sr/sub 0. 16/CuO/sub 4/

Energy Technology Data Exchange (ETDEWEB)

Onozuka, Takashi; Omori, Mamoru; Hirabayashi, Makoto; Syono, Yasuhiko

1987-10-01

A high-T/sub c/ superconducting compound, La/sub 1.84/Sr/sub 0.16/CuO/sub 4/, has been investigated by electron microscopy and electron diffraction in the range from 10 K to ambient temperature. The tetragonal K/sub 2/NiF/sub 4/-type structure undergoes an orthorhombic distortion below about 130 K. In the low-temperature phase, extra diffraction spots and twin lamellae are observed reversibly on cooling and heating in situ. Based on the observed results, a plausible structure model with orthorhombic distortion is proposed

Provenance and depositional age of metavolcano-sedimentary sequences of the Santa Terezinha de Goias, based on Sm-Nd and U-Pb zircon single grain

International Nuclear Information System (INIS)

Dantas, Ellton Luiz; Jost, Hardy; Fuck, Reinhardt A.; Brod, Jose Afonso; Pimentel, Marcio Martins; Meneses, Paulo Roberto

2001-01-01

Supracrustal rocks of the Santa Terezinha de Goias region, Central Brazil, presumably represent a southern extension of the Mara Rosa magmatic arc tectonically juxtaposed to Archean terrains and consist of a meta volcanic unit and a meta sedimentary unit. The aim of the paper is to present and discuss the first U-Pb and Sm-Nd data of rocks belonging to both units of that region. U-Pb data of zircons from a felsic meta volcanic rock inter layered with chlorite-rich schists (metandesites?) yield a concordant age of of 660 My, while the Sm-Nd model age of a variety of chlorite-schists indicate a juvenile age between 1.1 and 1.3 Ga. These data indicate that the meta volcanic rocks are Neo proterozoic in age and may be correlated with rocks of the Mara Rosa magmatic arc. On the other hand, the prevailing provenance of rocks belonging to the meta sedimentary unit indicate a Paleoproterozoic, or older, source. Thus, the deposition of both units are explained by means of the erosion of source-areas of variable age. (author)

ACTH Regulation of Adrenal SR-B1

Directory of Open Access Journals (Sweden)

Wen-Jun eShen

2016-05-01

Full Text Available The adrenal gland is one of the prominent sites for steroid hormone synthesis. Lipoprotein-derived cholesterol esters delivered via scavenger receptor, class B type 1 (SR-B1 constitute the dominant source of cholesterol for steroidogenesis, particularly in rodents. ACTH stimulates steroidogenesis through downstream actions on multiple components involved in steroidogenesis. Both acute and chronic ACTH treatment can modulate SR-B1 function including its transcription, its post transcriptional stability, its phosphorylation and dimerization status, as well as its interaction with other protein partners; all of which result in changes in the ability of SR-B1 to mediate HDL-cholesterol ester uptake and the supply of cholesterol for conversion to steroids. Here we provide a review of the recent findings on the regulation of adrenal SR-B1 function by ACTH.

U-Pb (SHRIMP) and Sm-Nd geochronology of basaltic green schists of the Aracuai orogen: implications for the age of the Macaubas group; Geocronologia U-Pb (SHRIMP) e Sm-Nd de xistos verdes basalticos do orogeno Aracuai: implicacoes para a idade do grupo Macaubas

Energy Technology Data Exchange (ETDEWEB)

Babinski, Marly [Universidade de Sao Paulo, SP (Brazil). Inst. de Geociencias. Centro de Pesquisas Geocronologicas]. E-mail: babinski@usp.br; Gradim, Rafael Jaude; Alkmim, Fernando Flecha de [Universidade Federal de Ouro Preto, MG (Brazil). Escola de Minas. Dept. de Geologia]. E-mails: rafaelgradim@gmail.com; alkmim@degeo.ufop.br; Pedrosa-Soares, Antonio Carlos; Noce, Carlos Mauricio [Minas Gerais Univ., Belo Horizonte (Brazil). Inst. de Geociencias; Liu, Dunyi [Chinese Academy of Geological Sciences, Beijing (China). Beijing SHRIMP Lab.

2005-12-15

The age and stratigraphic position of the basaltic green schists of the Rio Preto valley, located in the western part of the Aracuai Belt (ca. 60 km north of Diamantina, Minas Gerais) were a matter of controversy in the geologic literature, because several authors correlated them to the Neo proterozoic Macaubas Group but others to the lower Espinhaco Supergroup (ca. 1.7 Ga). However, detailed studies demonstrate that these green schists represent an interplay of submarine basaltic volcanism, volcanoclastic sedimentation and fire fountaining, and that they belong to the Chapada Acaua Formation of the Macaubas Group (Gradim et al., 2005). Geochemical studies indicate that the green schist protoliths evolved in a continental intra plate environment. Zircon crystals were separated from a green schist sample and analyzed by the U-Pb SHRIMP method. A Sm-Nd whole-rock isotopic analysis was obtained from the same sample. The Sm- Nd model age of ca. 1.52 Ga suggests that the green schist protoliths are younger than the magmatism of the Espinhaco rift. Most analyzed zircon crystals show features of detrital grains. The older ages indicate zircon grains inherited from the Archean- Paleoproterozoic basement and from magmatic rocks of the Espinhaco rift. The younger U-Pb values constrain the maximum age of the green schist protoliths at ca. 1,16 Ga. (author)

Rapid determination of {sup 90}Sr in urine samples using AnaLig Sr-01

Energy Technology Data Exchange (ETDEWEB)

Bilohuscin, J.; Dulanska, S.; Gardonova, V. [Univerzita Komenskeho, Prirodovedecka fakulta, Katedra jadrovej chemie, 84215 Bratislava (Slovakia)

2013-04-16

This work describes the use of IBC's AnaLig Sr-01 molecular recognition technology product to effectively and selectively pre-concentrate, separate and recover strontium from urine samples. This method uses two-stage columns separation consisting of two different commercial products Eichrom's Pre-filter Material and AnaLig Sr-01 column from IBC Advanced Technologies. This method does not involve co-precipitation of strontium as phosphates and oxalates from urine samples. The new rapid method separates strontium-90 with high chemical recovery (authors)

New isotope data from the Koperberg Suite and some associated rocks, Okiep district, Namaqualand, South Africa

International Nuclear Information System (INIS)

Clifford, T.N.; Barton, E.S.; Retief, E.A.; Rex, D.C.

1990-01-01

The Koperberg Suite is an anorthosite-charnockite kindred and 1500 bodies of these rocks have been recognised in the Okiep district and 30 of them have been mined for copper since 1852. The suite is intrusive into country rocks. New isotope data presented includes U-Pb zircon and whole-rock Pb-Pb, Rb-Sr, Sm-Nd and Ar-Ar analyses. 10 refs

The tectonic evolution of Southern part of the Sao Francisco Craton

International Nuclear Information System (INIS)

Teixeira, W.

1986-01-01

The potentiality of geochronology when it is applied to the geologic context of craton basement of archean areas is shown. Samples from southern part of the Sao Francisco Craton, in Brazil, were collected for petrographic analysis and geochronological data interpretation. The set of radiometric determinations was obtained by K-Ar, Rb-Sr, Pb-Pb and U-Pb methods. (M.C.K.) [pt

Development of an on-line flow injection Sr/matrix separation method for accurate, high-throughput determination of Sr isotope ratios by multiple collector-inductively coupled plasma-mass spectrometry.

Science.gov (United States)

Galler, Patrick; Limbeck, Andreas; Boulyga, Sergei F; Stingeder, Gerhard; Hirata, Takafumi; Prohaska, Thomas

2007-07-01

This work introduces a newly developed on-line flow injection (FI) Sr/Rb separation method as an alternative to the common, manual Sr/matrix batch separation procedure, since total analysis time is often limited by sample preparation despite the fast rate of data acquisition possible by inductively coupled plasma-mass spectrometers (ICPMS). Separation columns containing approximately 100 muL of Sr-specific resin were used for on-line FI Sr/matrix separation with subsequent determination of (87)Sr/(86)Sr isotope ratios by multiple collector ICPMS. The occurrence of memory effects exhibited by the Sr-specific resin, a major restriction to the repetitive use of this costly material, could successfully be overcome. The method was fully validated by means of certified reference materials. A set of two biological and six geological Sr- and Rb-bearing samples was successfully characterized for its (87)Sr/(86)Sr isotope ratios with precisions of 0.01-0.04% 2 RSD (n = 5-10). Based on our measurements we suggest (87)Sr/(86)Sr isotope ratios of 0.713 15 +/- 0.000 16 (2 SD) and 0.709 31 +/- 0.000 06 (2 SD) for the NIST SRM 1400 bone ash and the NIST SRM 1486 bone meal, respectively. Measured (87)Sr/(86)Sr isotope ratios for five basalt samples are in excellent agreement with published data with deviations from the published value ranging from 0 to 0.03%. A mica sample with a Rb/Sr ratio of approximately 1 was successfully characterized for its (87)Sr/(86)Sr isotope signature to be 0.718 24 +/- 0.000 29 (2 SD) by the proposed method. Synthetic samples with Rb/Sr ratios of up to 10/1 could successfully be measured without significant interferences on mass 87, which would otherwise bias the accuracy and uncertainty of the obtained data.

Effect of Flowing Water on Sr Sorption Changes of Hydrous Sodium Titanate

Directory of Open Access Journals (Sweden)

Youko Takahatake

2017-12-01

Full Text Available Radioactive contaminated water has been generated at the Fukushima Daiichi Nuclear Power station (F1NPS. Hydrous sodium titanate (SrTreat® is able to remove radioactive Strontium (Sr from this water. Knowing the amount of radioactive nuclides in the used as-received SrTreat® is important for effective disposal and deposition of the F1NPS waste. This study investigated changes in the ability of SrTreat® to sorb Sr, and to understand the causes of changes in the sorbing. An investigation of the Sr sorption ability of SrTreat® is important for calculating the initial radioactive inventory of used SrTreat®. This study carries out Sr sorption studies with acid-base titrations and X-ray photoelectron spectroscopy (XPS to characterize the properties. After exposure to simulated treated water for 99 h, the surface structure of the SrTreat® was changed, and the percentage of sorbed Sr and the buffer capacity for protons decreased. When the amount of radioactive nuclides contained in the used SrTreat® is calculated from the sorption data of the as-received SrTreat®, the radioactive Sr content will be overestimated with a concomitant increase in the deposition and disposal costs of the used SrTreat®.

Sr-containing hydroxyapatite: morphologies of HA crystals and bioactivity on osteoblast cells

Energy Technology Data Exchange (ETDEWEB)

Aina, Valentina [Department of Chemistry, Università degli Studi di Torino, Via P. Giuria 7, 10125 Torino (Italy); Centre of Excellence NIS (Nanostructured Interfaces and Surface) Università degli Studi di Torino (Italy); INSTM (Italian National Consortium for Materials Science and Technology), UdR Università di Torino (Italy); Bergandi, Loredana, E-mail: loredana.bergandi@unito.it [Department of Oncology, Università degli Studi di Torino, Via Santena 5/bis, 10126 Torino (Italy); Lusvardi, Gigliola; Malavasi, Gianluca [Department of Chemical and Geological Sciences, Università di Modena and Reggio Emilia, Via Campi 183, 41125 Modena (Italy); Imrie, Flora E.; Gibson, Iain R. [School of Medical Sciences, Institute of Medical Sciences, University of Aberdeen, Foresterhill, Aberdeen, AB25 2ZD (United Kingdom); Cerrato, Giuseppina [Department of Chemistry, Università degli Studi di Torino, Via P. Giuria 7, 10125 Torino (Italy); Centre of Excellence NIS (Nanostructured Interfaces and Surface) Università degli Studi di Torino (Italy); INSTM (Italian National Consortium for Materials Science and Technology), UdR Università di Torino (Italy); Ghigo, Dario [Department of Oncology, Università degli Studi di Torino, Via Santena 5/bis, 10126 Torino (Italy)

2013-04-01

A series of Sr-substituted hydroxyapatites (HA), of general formula Ca{sub (10−x)}Sr{sub x}(PO{sub 4}){sub 6}(OH){sub 2}, where x = 2 and 4, were synthesized by solid state methods and characterized extensively. The reactivity of these materials in cell culture medium was evaluated, and the behavior towards MG-63 osteoblast cells (in terms of cytotoxicity and proliferation assays) was studied. Future in vivo studies will give further insights into the behavior of the materials. A paper by Lagergren et al. (1975), concerning Sr-substituted HA prepared by a solid state method, reports that the presence of Sr in the apatite composition strongly influences the apatite diffraction patterns. Zeglinsky et al. (2012) investigated Sr-substituted HA by ab initio methods and Rietveld analyses and reported changes in the HA unit cell volume and shape due to the Sr addition. To further clarify the role played by the addition of Sr on the physico-chemical properties of these materials we prepared Sr-substituted HA compositions by a solid state method, using different reagents, thermal treatments and a multi-technique approach. Our results indicated that the introduction of Sr at the levels considered here does influence the structure of HA. There is also evidence of a decrease in the crystallinity degree of the materials upon Sr addition. The introduction of increasing amounts of Sr into the HA composition causes a decrease in the specific surface area and an enrichment of Sr-apatite phase at the surface of the samples. Bioactivity tests show that the presence of Sr causes changes in particle size and/or morphology during soaking in MEM solution; on the contrary the morphology of pure HA does not change after 14 days of reaction. The presence of Sr, as Sr-substituted HA and SrCl{sub 2,} in cultures of human MG-63 osteoblasts did not produce any cytotoxic effect. In fact, Sr-substituted HA increased the proliferation of osteoblast cells and enhanced cell differentiation: Sr in